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Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production DELIVERY FUEL CELLS STORAGE PRODUCTION TECHNOLOGY VALIDATION CODES & STANDARDS SYSTEMS INTEGRATION ANALYSES SAFETY EDUCATION RESEARCH & DEVELOPMENT Economy...

2

Hydrogen Production  

Office of Scientific and Technical Information (OSTI)

Hydrogen Production Hydrogen Research in DOE Databases Energy Citations Database Information Bridge Science.gov WorldWideScience.org Increase your H2IQ More information Making...

3

Hydrogen production  

SciTech Connect

The production of hydrogen by reacting an ash containing material with water and at least one halogen selected from the group consisting of chlorine, bromine and iodine to form reaction products including carbon dioxide and a corresponding hydrogen halide is claimed. The hydrogen halide is decomposed to separately release the hydrogen and the halogen. The halogen is recovered for reaction with additional carbonaceous materials and water, and the hydrogen is recovered as a salable product. In a preferred embodiment the carbonaceous material, water and halogen are reacted at an elevated temperature. In accordance with another embodiment, a continuous method for the production of hydrogen is provided wherein the carbonaceous material, water and at least one selected halogen are reacted in one zone, and the hydrogen halide produced from the reaction is decomposed in a second zone, preferably by electrolytic decomposition, to release the hydrogen for recovery and the halogen for recycle to the first zone. There also is provided a method for recovering any halogen which reacts with or is retained in the ash constituents of the carbonaceous material.

Darnell, A.J.; Parkins, W.E.

1978-08-08T23:59:59.000Z

4

Hydrogen Production  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

5

FCT Hydrogen Production: Contacts  

NLE Websites -- All DOE Office Websites (Extended Search)

Contacts to someone by E-mail Share FCT Hydrogen Production: Contacts on Facebook Tweet about FCT Hydrogen Production: Contacts on Twitter Bookmark FCT Hydrogen Production:...

6

Hydrogen & Fuel Cells - Hydrogen - Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Center Working With Argonne Contact TTRDC Thermochemical Cycles for Hydrogen Production Argonne researchers are studying thermochemical cycles to determine their potential...

7

FCT Hydrogen Production: Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics to someone by E-mail Basics to someone by E-mail Share FCT Hydrogen Production: Basics on Facebook Tweet about FCT Hydrogen Production: Basics on Twitter Bookmark FCT Hydrogen Production: Basics on Google Bookmark FCT Hydrogen Production: Basics on Delicious Rank FCT Hydrogen Production: Basics on Digg Find More places to share FCT Hydrogen Production: Basics on AddThis.com... Home Basics Central Versus Distributed Production Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Basics Photo of hydrogen production in photobioreactor Hydrogen, chemical symbol "H", is the simplest element on earth. An atom of hydrogen has only one proton and one electron. Hydrogen gas is a diatomic

8

DOE Hydrogen Analysis Repository: Electrolytic Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

by Principal Investigator Projects by Date U.S. Department of Energy Electrolytic Hydrogen Production Project Summary Full Title: Summary of Electrolytic Hydrogen Production:...

9

FCT Hydrogen Production: Hydrogen Production R&D Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production R&D Hydrogen Production R&D Activities to someone by E-mail Share FCT Hydrogen Production: Hydrogen Production R&D Activities on Facebook Tweet about FCT Hydrogen Production: Hydrogen Production R&D Activities on Twitter Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Google Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Delicious Rank FCT Hydrogen Production: Hydrogen Production R&D Activities on Digg Find More places to share FCT Hydrogen Production: Hydrogen Production R&D Activities on AddThis.com... Home Basics Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts

10

Sustainable hydrogen production  

SciTech Connect

This report describes the Sustainable Hydrogen Production research conducted at the Florida Solar Energy Center (FSEC) for the past year. The report presents the work done on the following four tasks: Task 1--production of hydrogen by photovoltaic-powered electrolysis; Task 2--solar photocatalytic hydrogen production from water using a dual-bed photosystem; Task 3--development of solid electrolytes for water electrolysis at intermediate temperatures; and Task 4--production of hydrogen by thermocatalytic cracking of natural gas. For each task, this report presents a summary, introduction/description of project, and results.

Block, D.L.; Linkous, C.; Muradov, N.

1996-01-01T23:59:59.000Z

11

DOE Hydrogen Analysis Repository: Distributed Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

government interests, a variety of vendors, and numerous utilities. Keywords: Hydrogen production, natural gas, costs Purpose Assess progress toward the 2005 DOE Hydrogen...

12

FCT Hydrogen Production: Current Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Current Technology to Current Technology to someone by E-mail Share FCT Hydrogen Production: Current Technology on Facebook Tweet about FCT Hydrogen Production: Current Technology on Twitter Bookmark FCT Hydrogen Production: Current Technology on Google Bookmark FCT Hydrogen Production: Current Technology on Delicious Rank FCT Hydrogen Production: Current Technology on Digg Find More places to share FCT Hydrogen Production: Current Technology on AddThis.com... Home Basics Current Technology Thermal Processes Electrolytic Processes Photolytic Processes R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Current Technology The development of clean, sustainable, and cost-competitive hydrogen

13

NREL: Learning - Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Production Production The simplest and most common element, hydrogen is all around us, but always as a compound with other elements. To make it usable in fuel cells or otherwise provide energy, we must expend energy or modify another energy source to extract it from the fossil fuel, biomass, water, or other compound in which it is found. Nearly all hydrogen production in the United States today is by steam reformation of natural gas. This, however, releases carbon dioxide in the process and trades one relatively clean fuel for another, with associated energy loss, so it does little to meet national energy needs. Hydrogen can also be produced by electrolysis-passing an electrical current through water to break it into hydrogen and oxygen-but electrolysis is inefficient and is only as clean

14

DOE Hydrogen Analysis Repository: Distributed Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Projects by Date U.S. Department of Energy Distributed Hydrogen Production via Steam Methane Reforming Project Summary Full Title: Well-to-Wheels Case Study: Distributed...

15

DOE Hydrogen Analysis Repository: Centralized Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal Gasification with Sequestration Project Summary Full Title: Well-to-Wheels Case Study: Centralized Hydrogen Production from Coal Gasification with Sequestration Project ID:...

16

DOE Hydrogen Analysis Repository: Hydrogen Production by  

NLE Websites -- All DOE Office Websites (Extended Search)

Production by Photovoltaic-powered Electrolysis Production by Photovoltaic-powered Electrolysis Project Summary Full Title: Production of Hydrogen by Photovoltaic-powered Electrolysis Project ID: 91 Principal Investigator: D.L. Block Keywords: Hydrogen production; electrolysis; photovoltaic (PV) Purpose To evaluate hydrogen production from photovoltaic (PV)-powered electrolysis. Performer Principal Investigator: D.L. Block Organization: Florida Solar Energy Center Address: 1679 Clearlake Road Cocoa, FL 32922 Telephone: 321-638-1001 Email: block@fsec.ucf.edu Sponsor(s) Name: Michael Ashworth Organization: Florida Energy Office Name: Neil Rossmeissl Organization: DOE/Advanced Utilities Concepts Division Name: H.T. Everett Organization: NASA/Kennedy Space Center Project Description Type of Project: Analysis Category: Hydrogen Fuel Pathways

17

Hydrogen Production: Overview of Technology Options  

NLE Websites -- All DOE Office Websites (Extended Search)

Table of Contents Producing Hydrogen...1 Hydrogen Production Technologies ...3 Challenges and Research Needs...4 Technology...

18

Economics of hydrogen production  

DOE Green Energy (OSTI)

Much of the current interest in hydrogen (H/sub 2/) centers around its potential to displace oil and gas as a fuel. The results of this study should be useful to research and development managers making funding decisions, and they should also be of interest to energy analysts, economists, and proponents of a hydrogen economy. We examined the current costs of H/sub 2/ produced by commercially available technologies (from fossil fuels and by electrolysis) and projected these costs to 2010, to set cost goals for H/sub 2/ produced via new technologies. We also examined the sensitivity of H/sub 2/ costs to varying energy price forecasts, capital costs and the required rate of return on investment, and by-product credits. We find that conventionally produced H/sub 2/ will not break into the fuel market before 2010. 23 references, 19 figures, 12 tables.

Gaines, L.L.; Wolsky, A.M.

1984-01-01T23:59:59.000Z

19

DOE Hydrogen Analysis Repository: Hydrogen Production from Renewables...  

NLE Websites -- All DOE Office Websites (Extended Search)

at the 1998 DOE Hydrogen Program Review. Keywords: Technoeconomic analysis; hydrogen production; costs; hydrogen storage; renewable Purpose To determine technical and economic...

20

Waste/By-Product Hydrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

WASTE/BY-PRODUCT HYDROGEN WASTE/BY-PRODUCT HYDROGEN Ruth Cox DOE/DOD Workshop January 13, 2011 January 13, 2011 Fuel Cell and Hydrogen Energy Association The Fuel Cell and Hydrogen Energy Association FCHEA ƒ Trade Association for the industry ƒ Member driven - Market focused ƒ Developers, suppliers, customers, nonprofits, government Ad ƒ Advocacy ƒ Safety and standardization ƒ Education ƒ Strategic Alliances Fuel Cell and Hydrogen Energy Association O M b Our Members 5 W t /B d t H d Waste/By-product Hydrogen Overview Overview ƒ Growing populations, rising standards of living, and increased urbanization leads to a escalating volume of waste leads to a escalating volume of waste. ƒ Huge volumes of waste are collected in dumps, creating a major environmental issue. ƒ ƒ Wastewater treatment plants generate noxious gasses that are released in Wastewater treatment plants generate noxious gasses that are released in

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Hydrogen production from biomass .  

E-Print Network (OSTI)

??Biomass energy encompasses a broad category of energy derived from plants and animals as well as the residual materials from each. Hydrogen gas is an (more)

Hahn, John J.

2006-01-01T23:59:59.000Z

22

NREL: Hydrogen and Fuel Cells Research - Hydrogen Production and Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production and Delivery Hydrogen Production and Delivery Most of the hydrogen in the United States is produced by steam reforming of natural gas. For the near term, this production method will continue to dominate. Researchers at NREL are developing advanced processes to produce hydrogen economically from sustainable resources. NREL's hydrogen production and delivery R&D efforts, which are led by Huyen Dinh, focus on the following topics: Biological Water Splitting Fermentation Conversion of Biomass and Wastes Photoelectrochemical Water Splitting Solar Thermal Water Splitting Renewable Electrolysis Hydrogen Dispenser Hose Reliability Hydrogen Production and Delivery Pathway Analysis. Biological Water Splitting Certain photosynthetic microbes use light energy to produce hydrogen from

23

Fusion energy for hydrogen production  

SciTech Connect

The decreasing availability of fossil fuels emphasizes the need to develop systems which will produce synthetic fuel to substitute for and supplement the natural supply. An important first step in the synthesis of liquid and gaseous fuels is the production of hydrogen. Thermonuclear fusion offers an inexhaustible source of energy for the production of hydrogen from water. Depending on design, electric generation efficiencies of approximately 40 to 60% and hydrogen production efficiencies by high temperature electrolysis of approximately 50 to 70% are projected for fusion reactors using high temperature blankets.

Fillo, J.A.; Powell, J.R.; Steinberg, M.

1978-01-01T23:59:59.000Z

24

Hydrogen production costs -- A survey  

SciTech Connect

Hydrogen, produced using renewable resources, is an environmentally benign energy carrier that will play a vital role in sustainable energy systems. The US Department of Energy (DOE) supports the development of cost-effective technologies for hydrogen production, storage, and utilization to facilitate the introduction of hydrogen in the energy infrastructure. International interest in hydrogen as an energy carrier is high. Research, development, and demonstration (RD and D) of hydrogen energy systems are in progress in many countries. Annex 11 of the International Energy Agency (IEA) facilitates member countries to collaborate on hydrogen RD and D projects. The United States is a member of Annex 11, and the US representative is the Program Manager of the DOE Hydrogen R and D Program. The Executive Committee of the Hydrogen Implementing Agreement in its June 1997 meeting decided to review the production costs of hydrogen via the currently commercially available processes. This report compiles that data. The methods of production are steam reforming, partial oxidation, gasification, pyrolysis, electrolysis, photochemical, photobiological, and photoelectrochemical reactions.

Basye, L.; Swaminathan, S.

1997-12-04T23:59:59.000Z

25

DOE Hydrogen Analysis Repository: Impact of Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

U.S. Energy Markets Project ID: 99 Principal Investigator: Harry Vidas Keywords: Hydrogen production; hydrogen supply; infrastructure; costs Purpose This project addresses the...

26

DOE Hydrogen and Fuel Cells Program: Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production Hydrogen Production Hydrogen Delivery Hydrogen Storage Hydrogen Manufacturing Fuel Cells Applications/Technology Validation Safety Codes and Standards Education Basic Research Systems Analysis Systems Integration U.S. Department of Energy Search help Home > Hydrogen Production Printable Version Hydrogen Production Hydrogen can be produced from diverse domestic feedstocks using a variety of process technologies. Hydrogen-containing compounds such as fossil fuels, biomass or even water can be a source of hydrogen. Thermochemical processes can be used to produce hydrogen from biomass and from fossil fuels such as coal, natural gas and petroleum. Power generated from sunlight, wind and nuclear sources can be used to produce hydrogen electrolytically. Sunlight alone can also drive photolytic production of

27

Technical Analysis of Hydrogen Production  

SciTech Connect

The aim of this work was to assess issues of cost, and performance associated with the production and storage of hydrogen via following three feedstocks: sub-quality natural gas (SQNG), ammonia (NH{sub 3}), and water. Three technology areas were considered: (1) Hydrogen production utilizing SQNG resources, (2) Hydrogen storage in ammonia and amine-borane complexes for fuel cell applications, and (3) Hydrogen from solar thermochemical cycles for splitting water. This report summarizes our findings with the following objectives: Technoeconomic analysis of the feasibility of the technology areas 1-3; Evaluation of the hydrogen production cost by technology areas 1; and Feasibility of ammonia and/or amine-borane complexes (technology areas 2) as a means of hydrogen storage on-board fuel cell powered vehicles. For each technology area, we reviewed the open literature with respect to the following criteria: process efficiency, cost, safety, and ease of implementation and impact of the latest materials innovations, if any. We employed various process analysis platforms including FactSage chemical equilibrium software and Aspen Technologies AspenPlus and HYSYS chemical process simulation programs for determining the performance of the prospective hydrogen production processes.

Ali T-Raissi

2005-01-14T23:59:59.000Z

28

Air Products Hydrogen Energy Systems | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Air Products Hydrogen Energy Systems Air Products Hydrogen Energy Systems Hydrogen Infrastructure Air Products Hydrogen Energy Systems More Documents & Publications Quadrennial...

29

Nuclear-Renewables Energy System for Hydrogen and Electricity Production  

Science Conference Proceedings (OSTI)

Technical Paper / Safety and Technology of Nuclear Hydrogen Production, Control, and Management / Nuclear Hydrogen Production

Geoffrey Haratyk; Charles W. Forsberg

30

DOE Hydrogen Analysis Repository: Centralized Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Biomass feedstock price Units: million Btu Supporting Information: LHV Description: Electricity price Units: kWh Description: Hydrogen fill pressure Units: psi Description:...

31

DOE Hydrogen Analysis Repository: Production of Hydrogen from Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

Production of Hydrogen from Coal Production of Hydrogen from Coal Project Summary Full Title: Production of High Purity Hydrogen from Domestic Coal: Assessing the Techno-Economic Impact of Emerging Technologies Project ID: 265 Principal Investigator: Kristin Gerdes Brief Description: This report assesses the improvements in cost and performance of hydrogen production from domestic coal when employing emerging technologies funded by DOE. Keywords: Hydrogen production; Coal Purpose This analysis specifically evaluates replacing conventional acid gas removal (AGR) and hydrogen purification with warm gas cleanup (WGCU) and a high-temperature hydrogen membrane (HTHM) that meets DOE's 2010 and 2015 performance and cost research and development (R&D) targets. Performer Principal Investigator: Kristin Gerdes

32

Hydrogen Production Sub-Program Overview - DOE Hydrogen and Fuel...  

NLE Websites -- All DOE Office Websites (Extended Search)

(FCT) Program, within the Office of Energy Efficiency and Renewable Energy * (EERE), is developing technologies for distributed and centralized renewable production of hydrogen....

33

DOE Hydrogen Analysis Repository: Hydrogen (H2) Co-Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated with Stationary Fuel Cell Systems Project Summary Full Title: Thermodynamic, Economic, and Environmental Modeling of Hydrogen (H2) Co-Production Integrated...

34

Low Cost Hydrogen Production Platform  

DOE Green Energy (OSTI)

A technology and design evaluation was carried out for the development of a turnkey hydrogen production system in the range of 2.4 - 12 kg/h of hydrogen. The design is based on existing SMR technology and existing chemical processes and technologies to meet the design objectives. Consequently, the system design consists of a steam methane reformer, PSA system for hydrogen purification, natural gas compression, steam generation and all components and heat exchangers required for the production of hydrogen. The focus of the program is on packaging, system integration and an overall step change in the cost of capital required for the production of hydrogen at small scale. To assist in this effort, subcontractors were brought in to evaluate the design concepts and to assist in meeting the overall goals of the program. Praxair supplied the overall system and process design and the subcontractors were used to evaluate the components and system from a manufacturing and overall design optimization viewpoint. Design for manufacturing and assembly (DFMA) techniques, computer models and laboratory/full-scale testing of components were utilized to optimize the design during all phases of the design development. Early in the program evaluation, a review of existing Praxair hydrogen facilities showed that over 50% of the installed cost of a SMR based hydrogen plant is associated with the high temperature components (reformer, shift, steam generation, and various high temperature heat exchange). The main effort of the initial phase of the program was to develop an integrated high temperature component for these related functions. Initially, six independent concepts were developed and the processes were modeled to determine overall feasibility. The six concepts were eventually narrowed down to the highest potential concept. A US patent was awarded in February 2009 for the Praxair integrated high temperature component design. A risk analysis of the high temperature component was conducted to identify any potential design deficiency related to the concept. The analysis showed that no fundamental design flaw existed with the concept, but additional simulations and prototypes would be required to verify the design prior to fabricating a production unit. These identified risks were addressed in detail during Phase II of the development program. Along with the models of the high temperature components, a detailed process and 3D design model of the remainder of system, including PSA, compression, controls, water treatment and instrumentation was developed and evaluated. Also, in Phase II of the program, laboratory/fullscale testing of the high temperature components was completed and stable operation/control of the system was verified. The overall design specifications and test results were then used to develop accurate hydrogen costs for the optimized system. Praxair continued development and testing of the system beyond the Phase II funding provided by the DOE through the end of 2008. This additional testing is not documented in this report, but did provide significant additional data for development of a prototype system as detailed in the Phase III proposal. The estimated hydrogen product costs were developed (2007 basis) for the 4.8 kg/h system at production rates of 1, 5, 10, 100 and 1,000 units built per year. With the low cost SMR approach, the product hydrogen costs for the 4.8 kg/h units at 50 units produced per year were approximately $3.02 per kg. With increasing the volume production to 1,000 units per year, the hydrogen costs are reduced by about 12% to $2.67 per kg. The cost reduction of only 12% is a result of significant design and fabrication efficiencies being realized in all levels of production runs through utilizing the DFMA principles. A simplified and easily manufactured design does not require large production volumes to show significant cost benefits. These costs represent a significant improvement and a new benchmark in the cost to produce small volume on-site hydrogen using existing process technologies. The cost mo

Timothy M. Aaron, Jerome T. Jankowiak

2009-10-16T23:59:59.000Z

35

Hydrogen Production: Fundamentals and Case Study Summaries (Presentation)  

DOE Green Energy (OSTI)

This presentation summarizes hydrogen production fundamentals and case studies, including hydrogen to wind case studies.

Harrison, K.; Remick, R.; Hoskin, A.; Martin, G.

2010-05-19T23:59:59.000Z

36

Hydrogen Production Technical Team Roadmap  

NLE Websites -- All DOE Office Websites (Extended Search)

Production Production Technical Team Roadmap June 2013 This roadmap is a document of the U.S. DRIVE Partnership. U.S. DRIVE (Driving Research and Innovation for Vehicle efficiency and Energy sustainability) is a voluntary, non-binding, and nonlegal partnership among the U.S. Department of Energy; USCAR, representing Chrysler Group LLC, Ford Motor Company, and General Motors; Tesla Motors; five energy companies -BP America, Chevron Corporation, Phillips 66 Company, ExxonMobil Corporation, and Shell Oil Products US; two utilities - Southern California Edison and DTE Energy; and the Electric Power Research Institute (EPRI). The Hydrogen Production Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose mission is to accelerate the development of pre-competitive and innovative technologies to enable

37

ECONOMIC FEASIBILITY ANALYSIS OF HYDROGEN PRODUCTION BY  

E-Print Network (OSTI)

steps (syngas generation, shift conversion and hydrogen purification) necessary for hydrogen production for this process option. O2 H2 air N.G. + Steam Hydrogen H2-depleted syngas OTM Reactor HTM Reactor syngas Figure 1- gas. A portion of natural gas also reacts with steam to form syngas. Additional hydrogen is formed

38

Air Products Hydrogen Energy Systems  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Kiczek,Edward F. [KICZEKEF@airproducts.com] Kiczek,Edward F. [KICZEKEF@airproducts.com] Sent: Monday, April 18, 2011 7:40 PM To: Gopstein, Avi (S4) Subject: Hydrogen Infrastructure Latest Advancements Attachments: Air Products Written Comments to 2011 2012 AB118 Investment Plan.pdf Follow Up Flag: Follow up Flag Status: Flagged Categories: QTR Transparency Avi, You may recall we met in DC when the McKinsey team from Germany came to discuss the EU study on hydrogen infrastructure. At that time I mention a significant advance in infrastructure that would be announced soon. Attached is our testimony to the California Energy Commission on deploying that technology. We were awarded the project to build 9 stations in southern California with the backing of

39

DOE Hydrogen Analysis Repository: Photobiological Hydrogen Production from  

NLE Websites -- All DOE Office Websites (Extended Search)

Photobiological Hydrogen Production from Green Algae Cost Analysis Photobiological Hydrogen Production from Green Algae Cost Analysis Project Summary Full Title: Updated Cost Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report Project ID: 110 Principal Investigator: Wade Amos Purpose This report updates the 1999 economic analysis of NREL's photobiological hydrogen production from Chlamydomonas reinhardtii. The previous study had looked mainly at incident light intensities, batch cycles and light adsorption without directly attempting to model the saturation effects seen in algal cultures. This study takes a more detailed look at the effects that cell density, light adsorption and light saturation have on algal hydrogen production. Performance estimates based on actual solar data are

40

System for thermochemical hydrogen production  

DOE Patents (OSTI)

Method and apparatus are described for joule boosting a SO/sub 3/ decomposer using electrical instead of thermal energy to heat the reactants of the high temperature SO/sub 3/ decomposition step of a thermochemical hydrogen production process driven by a tandem mirror reactor. Joule boosting the decomposer to a sufficiently high temperature from a lower temperature heat source eliminates the need for expensive catalysts and reduces the temperature and consequent materials requirements for the reactor blanket. A particular decomposer design utilizes electrically heated silicon carbide rods, at a temperature of 1250/sup 0/K, to decompose a cross flow of SO/sub 3/ gas.

Werner, R.W.; Galloway, T.R.; Krikorian, O.H.

1981-05-22T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Materials for Hydrogen Production, Separation, and Storage  

Science Conference Proceedings (OSTI)

Mar 13, 2012 ... Materials in Clean Power Systems VII: Clean Coal-, Hydrogen ... and Fuel Cells: Materials for Hydrogen Production, Separation, and Storage .... Mixed Conducting Molten Salt Electrolyte for Na/NiCl2 Cell: Tannaz Javadi1;...

42

Renewable hydrogen production for fossil fuel processing  

DOE Green Energy (OSTI)

The objective of this mission-oriented research program is the production of renewable hydrogen for fossil fuel processing. This program will build upon promising results that have been obtained in the Chemical Technology Division of Oak Ridge National Laboratory on the utilization of intact microalgae for photosynthetic water splitting. In this process, specially adapted algae are used to perform the light-activated cleavage of water into its elemental constituents, molecular hydrogen and oxygen. The great potential of hydrogen production by microalgal water splitting is predicated on quantitative measurement of their hydrogen-producing capability. These are: (1) the photosynthetic unit size of hydrogen production; (2) the turnover time of photosynthetic hydrogen production; (3) thermodynamic efficiencies of conversion of light energy into the Gibbs free energy of molecular hydrogen; (4) photosynthetic hydrogen production from sea water using marine algae; (5) the original development of an evacuated photobiological reactor for real-world engineering applications; (6) the potential for using modern methods of molecular biology and genetic engineering to maximize hydrogen production. The significance of each of these points in the context of a practical system for hydrogen production is discussed. This program will be enhanced by collaborative research between Oak Ridge National Laboratory and senior faculty members at Duke University, the University of Chicago, and Iowa State University. The special contribution that these organizations and faculty members will make is access to strains and mutants of unicellular algae that will potentially have useful properties for hydrogen production by microalgal water splitting.

Greenbaum, E.

1994-09-01T23:59:59.000Z

43

DOE Hydrogen Analysis Repository: Centralized Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

thermochemical water splitting; fuel cell vehicles Inputs: Description: Nuclear Fuel Cycle Cost Units: kWh Models Used: GREET Version 1.7; H2A Production Model Version...

44

Fuel Cell Technologies Office: Hydrogen Production  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

nuclear; biomass; and other renewable energy technologies, such as wind, solar, geothermal, and hydro-electric power. The overall challenge to hydrogen production is cost...

45

Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production  

Fuel Cell Technologies Publication and Product Library (EERE)

This report documents the engineering and cost characteristics of four PEC hydrogen production systems selected by DOE to represent canonical embodiments of future systems.

46

Materials for Hydrogen Production, Storage, and Distribution  

Science Conference Proceedings (OSTI)

Feb 16, 2010 ... Co-Production of Pure Hydrogen and Electricity from Coal Syngas via the .... and plastic deformations in the crack tip energy rate formulate.

47

Hydrogen Production Cost Estimate Using Biomass Gasification...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production Cost Estimate Using Biomass Gasification National Renewable Energy Laboratory 1617 Cole Boulevard * Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov...

48

Hydrogen production from microbial strains  

SciTech Connect

The present invention is directed to a method of screening microbe strains capable of generating hydrogen. This method involves inoculating one or more microbes in a sample containing cell culture medium to form an inoculated culture medium. The inoculated culture medium is then incubated under hydrogen producing conditions. Once incubating causes the inoculated culture medium to produce hydrogen, microbes in the culture medium are identified as candidate microbe strains capable of generating hydrogen. Methods of producing hydrogen using one or more of the microbial strains identified as well as the hydrogen producing strains themselves are also disclosed.

Harwood, Caroline S; Rey, Federico E

2012-09-18T23:59:59.000Z

49

Production of Hydrogen from Peanut Shells  

NLE Websites -- All DOE Office Websites (Extended Search)

Production of Hydrogen from Peanut Shells Production of Hydrogen from Peanut Shells The goal of this project is the production of renewable hydrogen from agricultural residues, in the near-term time frame (~three years) and at a comparable cost to existing methane reforming technologies. The hydrogen produced will be blended with CNG and used to power a bus in Albany, GA. Our strategy is to produce hydrogen from biomass pyrolysis oils in conjunction with high value co-products. Activated carbon can be made from agricultural residues in a two- stage process: (1) slow pyrolysis of biomass to produce charcoal, and (2) high temperature processing to form activated carbon. The vapor by-products from the first step can be steam reformed into hydrogen. NREL has developed the technology for bio-

50

Fuel Cell Technologies Office: Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Production Production Photo of hydrogen researcher. Hydrogen can be produced using diverse, domestic resources including fossil fuels, such as natural gas and coal (with carbon sequestration); nuclear; biomass; and other renewable energy technologies, such as wind, solar, geothermal, and hydro-electric power. The overall challenge to hydrogen production is cost reduction. For cost-competitive transportation, a key driver for energy independence, hydrogen must be comparable to conventional fuels and technologies on a per-mile basis in order to succeed in the commercial marketplace. Learn more about DOE's hydrogen cost goal and the analysis used in projecting the future cost of hydrogen. The U.S. Department of Energy supports the research and development of a wide range of technologies to produce hydrogen economically and in environmentally friendly ways.

51

Redirection of metabolism for hydrogen production  

SciTech Connect

This project is to develop and apply techniques in metabolic engineering to improve the biocatalytic potential of the bacterium Rhodopseudomonas palustris for nitrogenase-catalyzed hydrogen gas production. R. palustris, is an ideal platform to develop as a biocatalyst for hydrogen gas production because it is an extremely versatile microbe that produces copious amounts of hydrogen by drawing on abundant natural resources of sunlight and biomass. Anoxygenic photosynthetic bacteria, such as R. palustris, generate hydrogen and ammonia during a process known as biological nitrogen fixation. This reaction is catalyzed by the enzyme nitrogenase and normally consumes nitrogen gas, ATP and electrons. The applied use of nitrogenase for hydrogen production is attractive because hydrogen is an obligatory product of this enzyme and is formed as the only product when nitrogen gas is not supplied. Our challenge is to understand the systems biology of R. palustris sufficiently well to be able to engineer cells to produce hydrogen continuously, as fast as possible and with as high a conversion efficiency as possible of light and electron donating substrates. For many experiments we started with a strain of R. palustris that produces hydrogen constitutively under all growth conditions. We then identified metabolic pathways and enzymes important for removal of electrons from electron-donating organic compounds and for their delivery to nitrogenase in whole R. palustris cells. For this we developed and applied improved techniques in 13C metabolic flux analysis. We identified reactions that are important for generating electrons for nitrogenase and that are yield-limiting for hydrogen production. We then increased hydrogen production by blocking alternative electron-utilizing metabolic pathways by mutagenesis. In addition we found that use of non-growing cells as biocatalysts for hydrogen gas production is an attractive option, because cells divert all resources away from growth and to hydrogen. Also R. palustris cells remain viable in a non-growing state for long periods of time.

Harwood, Caroline S.

2011-11-28T23:59:59.000Z

52

DOE Hydrogen Analysis Repository: Resource Analysis for Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Resource Analysis for Hydrogen Production Resource Analysis for Hydrogen Production Project Summary Full Title: Resource Analysis for Hydrogen Production Project ID: 282 Principal Investigator: Marc Melaina Brief Description: Analysis involves estimating energy resources required to support part of the demand generated by 100 million fuel cell electric vehicles in 2040. Performer Principal Investigator: Marc Melaina Organization: National Renewable Energy Laboratory (NREL) Address: 15013 Denver West Parkway Golden, CO 80401 Telephone: 303-275-3836 Email: marc.melaina@nrel.gov Website: http://www.nrel.gov/ Sponsor(s) Name: Fred Joseck Organization: DOE/EERE/FCTO Telephone: 202-586-7932 Email: Fred.Joseck@ee.doe.gov Website: http://www.hydrogen.energy.gov/ Period of Performance Start: October 2009 Project Description

53

Dynamic simulation of nuclear hydrogen production systems  

E-Print Network (OSTI)

Nuclear hydrogen production processes have been proposed as a solution to rising CO 2 emissions and low fuel yields in the production of liquid transportation fuels. In these processes, the heat of a nuclear reactor is ...

Ramrez Muoz, Patricio D. (Patricio Dario)

2011-01-01T23:59:59.000Z

54

Photosynthesis for Hydrogen and Fuels Production Webinar  

NLE Websites -- All DOE Office Websites (Extended Search)

Photosynthesis for Hydrogen and Fuels Production Tasios Melis, UC Berkeley 24-Jan-2011 1 UCB-Melis 2 CO 2 H 2 O Photosynthesis Photons H 2 HC O 2 , Biomass Feedstock and products...

55

Hydrogen and Sulfur Production from Hydrogen Sulfide Wastes  

E-Print Network (OSTI)

A new hydrogen sulfide waste-treatment process that uses microwave plasma-chemical technology is currently under development in the Soviet Union and in the United States. Whereas the present waste treatment process only recovers sulfur at best, this novel process recovers both hydrogen and sulfur. The plasma process involves dissociating hydrogen sulfide in a "nonequilibrium" plasma in a microwave or radio-frequency reactor. After the dissociation process, sulfur is condensed and sold just as is currently done. The remaining gases are purified and separated into streams containing the product hydrogen, the hydrogen sulfide to be recycled to the plasma reactor, and the process purge containing carbon dioxide and water. This process has particular implications for petroleum refining industry, in which hydrogen is a widely used reagent and must be produced from increasingly scarce hydrocarbon resources. The modular nature of the new process may also offer economic advantages over small-scale waste treatment technologies widely used in the natural-gas industry. Laboratory-scale experiments with pure hydrogen sulfide indicate that conversions exceeding 90% are possible with appropriate reactor design and that the energy required to dissociate hydrogen sulfide is low enough for the plasma process to be economically competitive. In addition, the experiments show-that typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology.

Harkness, J.; Doctor, R. D.

1993-03-01T23:59:59.000Z

56

Hydrogen and sulfur production from hydrogen sulfide wastes  

DOE Green Energy (OSTI)

A new hydrogen sulfide waste-treatment process that uses microwave plasma-chemical technology is currently under development in the Soviet Union and in the United States. Whereas the present waste treatment process only recovers sulfur at best, this novel process recovers both hydrogen and sulfur. The plasma process involves dissociating hydrogen sulfide in a nonequilibrium'' plasma in a microwave or radio-frequency reactor. After the dissociation process, sulfur is condensed and sold just as is currently done. The remaining gases are purified and separated into streams containing the product hydrogen, the hydrogen sulfide to be recycled to the plasma reactor, and the process purge containing carbon dioxide and water. This process has particular implications for the petroleum refining industry, in which hydrogen is a widely used reagent and must be produced from increasingly scarce hydrocarbon resources. The modular nature of the new process may also offer economic advantages over small-scale waste treatment technologies widely used in the natural-gas industry. Laboratory-scale experiments with pure hydrogen sulfide indicate that conversions exceeding 90% are possible with appropriate reactor design and that the energy required to dissociate hydrogen sulfide is low enough for the plasma process to be economically competitive. In addition, the experiments show that typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology.

Harkness, J.B.L.; Doctor, R.D.

1993-01-01T23:59:59.000Z

57

Hydrogen and sulfur production from hydrogen sulfide wastes  

DOE Green Energy (OSTI)

A new hydrogen sulfide waste-treatment process that uses microwave plasma-chemical technology is currently under development in the Soviet Union and in the United States. Whereas the present waste treatment process only recovers sulfur at best, this novel process recovers both hydrogen and sulfur. The plasma process involves dissociating hydrogen sulfide in a ``nonequilibrium`` plasma in a microwave or radio-frequency reactor. After the dissociation process, sulfur is condensed and sold just as is currently done. The remaining gases are purified and separated into streams containing the product hydrogen, the hydrogen sulfide to be recycled to the plasma reactor, and the process purge containing carbon dioxide and water. This process has particular implications for the petroleum refining industry, in which hydrogen is a widely used reagent and must be produced from increasingly scarce hydrocarbon resources. The modular nature of the new process may also offer economic advantages over small-scale waste treatment technologies widely used in the natural-gas industry. Laboratory-scale experiments with pure hydrogen sulfide indicate that conversions exceeding 90% are possible with appropriate reactor design and that the energy required to dissociate hydrogen sulfide is low enough for the plasma process to be economically competitive. In addition, the experiments show that typical refinery acid-gas streams are compatible with the plasma process and that all by-products can be treated with existing technology.

Harkness, J.B.L.; Doctor, R.D.

1993-03-01T23:59:59.000Z

58

Hydrogen energy for tomorrow: Advanced hydrogen production technologies  

SciTech Connect

The future vision for hydrogen is that it will be cost-effectively produced from renewable energy sources and made available for widespread use as an energy carrier and a fuel. Hydrogen can be produced from water and when burned as a fuel, or converted to electricity, joins with oxygen to again form water. It is a clean, sustainable resource with many potential applications, including generating electricity, heating homes and offices, and fueling surface and air transportation. To achieve this vision, researchers must develop advanced technologies to produce hydrogen at costs competitive with fossil fuels, using sustainable sources. Hydrogen is now produced primarily by steam reforming of natural gas. For applications requiring extremely pure hydrogen, production is done by electrolysis. This is a relatively expensive process that uses electric current to dissociate, or split, water into its hydrogen and oxygen components. Technologies with the best potential for producing hydrogen to meet future demand fall into three general process categories: photobiological, photoelectrochemical, and thermochemical. Photobiological and photoelectrochemical processes generally use sunlight to split water into hydrogen and oxygen. Thermochemical processes, including gasification and pyrolysis systems, use heat to produce hydrogen from sources such as biomass and solid waste.

1995-08-01T23:59:59.000Z

59

Economics and market potential of hydrogen production  

DOE Green Energy (OSTI)

A study was undertaken to evaluate the economics of producing hydrogen from coal and from water and to assess the market potential for this hydrogen in chemical and fuel applications. Results of this study are summarized. Current chemical applications of hydrogen in manufacturing ammonia and methanol, in refining petroleum and in specialty uses provide a base market for penetration by new hydrogen production technologies, although prospects for the use of hydrogen in fuel applications remain unclear. Electrolysis and coal gasification will be complementary, not competitive, technologies for producing hydrogen. Coal gasification plants are better suited to production of large quantities of hydrogen, while electrolyzers are better suited to the production of hydrogen for small-scale uses. Hydrogen produced through coal gasification may be economical in chemical applications (e.g., ammonia production) by the late 1990's. Development programs now underway are expected to provide new coal gasification technologies with lower first costs and higher efficiencies than current technologies. An on-site coal gasification plant supplying hydrogen in the quantities usually required in chemical applications (from 10 to 100 million cubic feet per day) will be smaller than is generally proposed for syngas plants. Growth in smaller scale specialty uses of hydrogen and improvements in the technology for electrolysis will create conditions favorable to expanded use of hydrogen produced through water electrolysis. The major constraint on use of electrolysis will be the availability of low cost electricity. Shortages of natural gas caused by declining domestic production could induce shifts to producing hydrogen through electrolysis or through coal gasification earlier in time (i.e., the late 1980's or early 1990's) than is suggested by comparative cost calculations alone.

Not Available

1978-09-01T23:59:59.000Z

60

Economics and market potential of hydrogen production  

SciTech Connect

A study was undertaken to evaluate the economics of producing hydrogen from coal and from water and to assess the market potential for this hydrogen in chemical and fuel applications. Results of this study are summarized. Current chemical applications of hydrogen in manufacturing ammonia and methanol, in refining petroleum and in specialty uses provide a base market for penetration by new hydrogen production technologies, although prospects for the use of hydrogen in fuel applications remain unclear. Electrolysis and coal gasification will be complementary, not competitive, technologies for producing hydrogen. Coal gasification plants are better suited to production of large quantities of hydrogen, while electrolyzers are better suited to the production of hydrogen for small-scale uses. Hydrogen produced through coal gasification may be economical in chemical applications (e.g., ammonia production) by the late 1990's. Development programs now underway are expected to provide new coal gasification technologies with lower first costs and higher efficiencies than current technologies. An on-site coal gasification plant supplying hydrogen in the quantities usually required in chemical applications (from 10 to 100 million cubic feet per day) will be smaller than is generally proposed for syngas plants. Growth in smaller scale specialty uses of hydrogen and improvements in the technology for electrolysis will create conditions favorable to expanded use of hydrogen produced through water electrolysis. The major constraint on use of electrolysis will be the availability of low cost electricity. Shortages of natural gas caused by declining domestic production could induce shifts to producing hydrogen through electrolysis or through coal gasification earlier in time (i.e., the late 1980's or early 1990's) than is suggested by comparative cost calculations alone.

1978-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Alternative Fuels Data Center: Hydrogen Production and Retail Requirements  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen Production Hydrogen Production and Retail Requirements to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Production and Retail Requirements on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Production and Retail Requirements on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Production and Retail Requirements on Google Bookmark Alternative Fuels Data Center: Hydrogen Production and Retail Requirements on Delicious Rank Alternative Fuels Data Center: Hydrogen Production and Retail Requirements on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Production and Retail Requirements on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Hydrogen Production and Retail Requirements

62

Ceramic Membranes for Hydrogen/Oxygen Production - Energy ...  

Hydrogen separation technology is integral to successful fossil-based hydrogen production ... a mixture of hydrogen and carbon monoxide made by ...

63

Cathode for electrolytic production of hydrogen  

SciTech Connect

A cathode for use in the electrochemical production of hydrogen and a process for making it which involves direct electrochemical cathodic action on a thermally produced adherent oxide on a nickel cathode surface are disclosed. Examples include a nickel sheet thermally oxidized in air at 600/sup 0/ C. for one hour and used directly in the production of electrolytic hydrogen and an iron sheet plasma sprayed with nickel to provide a surface containing thermal oxidation product of nickel and again used directly in the electrolytic production of hydrogen.

Hall, D.E.

1983-10-18T23:59:59.000Z

64

Hydrogen Production and Delivery Research  

DOE Green Energy (OSTI)

In response to DOE's Solicitation for Grant Applications DE-PS36-03GO93007, 'Hydrogen Production and Delivery Research', SRI International (SRI) proposed to conduct work under Technical Topic Area 5, Advanced Electrolysis Systems; Sub-Topic 5B, High-Temperature Steam Electrolysis. We proposed to develop a prototype of a modular industrial system for low-cost generation of H{sub 2} (<$2/kg) by steam electrolysis with anodic depolarization by CO. Water will be decomposed electrochemically into H{sub 2} and O{sub 2} on the cathode side of a high-temperature electrolyzer. Oxygen ions will migrate through an oxygen-ion-conductive solid oxide electrolyte. Gas mixtures on the cathode side (H{sub 2} + H{sub 2}O) and on the anode side (CO + CO{sub 2}) will be reliably separated by the solid electrolyte. Depolarization of the anodic process will decrease the electrolysis voltage, and thus the electricity required for H{sub 2} generation and the cost of produced H{sub 2}. The process is expected to be at least 10 times more energy-efficient than low-temperature electrolysis and will generate H{sub 2} at a cost of approximately $1-$1.5/kg. The operating economics of the system can be made even more attractive by deploying it at locations where waste heat is available; using waste heat would reduce the electricity required for heating the system. Two critical targets must be achieved: an H{sub 2} production cost below $2/kg, and scalable design of the pilot H{sub 2} generation system. The project deliverables would be (1) a pilot electrolysis system for H{sub 2} generation, (2) an economic analysis, (3) a market analysis, and (4) recommendations and technical documentation for field deployment. DOE was able to provide only 200K out of 1.8M (or about 10% of awarded budget), so project was stopped abruptly.

Iouri Balachov, PhD

2007-10-15T23:59:59.000Z

65

DOE Hydrogen Analysis Repository: Distributed Hydrogen Production from Wind  

NLE Websites -- All DOE Office Websites (Extended Search)

from Wind from Wind Project Summary Full Title: Well-to-Wheels Case Study: Distributed Hydrogen Production from Wind Project ID: 216 Principal Investigator: Fred Joseck Keywords: Wind; hydrogen production; well-to-wheels (WTW); fuel cell vehicles (FCV); electrolysis Purpose Provide well-to-wheels energy use and emissions data on a potential pathway for producing hydrogen from wind via distributed water electrolysis. This data was used in developing the U.S. Department of Energy Hydrogen Posture Plan. Performer Principal Investigator: Fred Joseck Organization: DOE/EERE/HFCIT Address: 1000 Independence Avenue, SW Washington, DC 20585 Telephone: 202-586-7932 Email: Fred.Joseck@ee.doe.gov Additional Performers: Margaret Mann, National Renewable Energy Laboratory; Michael Wang, Argonne National Laboratory

66

DOE Hydrogen Analysis Repository: Centralized Hydrogen Production from Wind  

NLE Websites -- All DOE Office Websites (Extended Search)

Wind Wind Project Summary Full Title: Well-to-Wheels Case Study: Centralized Hydrogen Production from Wind Project ID: 214 Principal Investigator: Fred Joseck Keywords: Wind; hydrogen production; well-to-wheels (WTW); fuel cell vehicles (FCV); electrolysis Purpose Provide well-to-wheels energy use and emissions data on a potential pathway for producing hydrogen from wind via centralized water electrolysis. This data was used in developing the U.S. Department of Energy Hydrogen Posture Plan. Performer Principal Investigator: Fred Joseck Organization: DOE/EERE/HFCIT Address: 1000 Independence Avenue, SW Washington, DC 20585 Telephone: 202-586-7932 Email: Fred.Joseck@ee.doe.gov Additional Performers: Margaret Mann, National Renewable Energy Laboratory; Michael Wang, Argonne National Laboratory

67

Table H1. Estimated Hydrogen Production by Business Sector Business Sector Annual Hydrogen Production  

E-Print Network (OSTI)

In 2007, roughly 9 million metric tons per year of hydrogen was produced in the U.S. 1 in a variety of ways. This production results in about 60 million metric tons of CO2 emissions each year. Table H1 provides estimates of U.S. hydrogen production for the various business sectors. Merchant hydrogen is consumed at sites other than where it is produced. Captive hydrogen (e.g., hydrogen produced at oil refineries, ammonia, and methanol plants) is consumed at the site where it is produced. This technical support document assumes that CO2 emissions associated with captive hydrogen production facilities are included as part of the GHG emissions from the industry producing those other chemical products (e.g., ammonia, petroleum products, and methanol), and therefore this document is focused on merchant hydrogen production.

unknown authors

2008-01-01T23:59:59.000Z

68

Production of Hydrogen from Underground Coal Gasification  

DOE Patents (OSTI)

A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

Upadhye, Ravindra S. (Pleasanton, CA)

2008-10-07T23:59:59.000Z

69

Fusion reactors for hydrogen production via electrolysis  

DOE Green Energy (OSTI)

The decreasing availability of fossil fuels emphasizes the need to develop systems which will produce synthetic fuel to substitute for and supplement the natural supply. An important first step in the synthesis of liquid and gaseous fuels is the production of hydrogen. Thermonuclear fusion offers an inexhaustible source of energy for the production of hydrogen from water. Depending on design, electric generation efficiencies of approx. 40 to 60% and hydrogen production efficiencies by high temperature electrolysis of approx. 50 to 70% are projected for fusion reactors using high temperature blankets.

Fillo, J A; Powell, J R; Steinberg, M

1979-01-01T23:59:59.000Z

70

Production of hydrogen from alcohols  

DOE Patents (OSTI)

A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

Deluga, Gregg A. (St. Paul, MN); Schmidt, Lanny D. (Minneapolis, MN)

2007-08-14T23:59:59.000Z

71

NETL: Coal & Coal Biomass to Liquids - Alternate Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal and CoalBiomass to Liquids Alternate Hydrogen Production In the Alternate Production technology pathway, clean syngas from coal is converted to high-hydrogen-content liquid...

72

Maximizing Light Utilization Efficiency and Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cells Program II.G Hydrogen Production and Delivery Biological Melis - University of California, Berkeley G G G G G Introduction The goal of the research is to generate green...

73

Solar Thermochemical Hydrogen Production Research (STCH)  

Fuel Cell Technologies Publication and Product Library (EERE)

Eight cycles in a coordinated set of projects for Solar Thermochemical Cycles for Hydrogen production (STCH) were self-evaluated for the DOE-EERE Fuel Cell Technologies Program at a Working Group Meet

74

Improving Photosynthesis for Hydrogen and Fuels Production -...  

NLE Websites -- All DOE Office Websites (Extended Search)

Improving Photosynthesis for Hydrogen and Fuels Production January 24, 2011 Webinar Q&A Q: How do you induce hypoxic photosynthesis? I imagine you N-stress, to accumulate starch...

75

Fuel Cell Technologies Office: Biological Hydrogen Production Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Hydrogen Biological Hydrogen Production Workshop to someone by E-mail Share Fuel Cell Technologies Office: Biological Hydrogen Production Workshop on Facebook Tweet about Fuel Cell Technologies Office: Biological Hydrogen Production Workshop on Twitter Bookmark Fuel Cell Technologies Office: Biological Hydrogen Production Workshop on Google Bookmark Fuel Cell Technologies Office: Biological Hydrogen Production Workshop on Delicious Rank Fuel Cell Technologies Office: Biological Hydrogen Production Workshop on Digg Find More places to share Fuel Cell Technologies Office: Biological Hydrogen Production Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings

76

Hydrogen Production Using the Modular Helium Reactor  

DOE Green Energy (OSTI)

The high-temperature characteristics of the Modular Helium Reactor (MHR) make it a strong candidate for the production of hydrogen using either thermochemical or high-temperature electrolysis (HTE) processes. Using heat from the MHR to drive a Sulfur-Iodine (S-I) thermochemical hydrogen process has been the subject of a DOE sponsored Nuclear Engineering Research Initiative (NERI) project lead by General Atomics, with participation from the Idaho National Engineering and Environmental Laboratory (INEEL) and Texas A&M University. While the focus of much of the initial work was on the S-I thermochemical production of hydrogen, recent activities have also included development of a preconceptual design for an integral HTE hydrogen production plant driven by the process heat and electricity produced by a 600 MWt MHR. This paper describes RELAP5-3D analyses performed to evaluate alternative primary system cooling configurations for the MHR to minimize peak reactor vessel and core temperatures while achieving core helium outlet temperatures in the range of 900 oC to 1000 oC, needed for the efficient production of hydrogen using either the S-I thermochemical or HTE process. The cooling schemes investigated are intended to ensure peak fuel temperatures do not exceed specified limits under normal or transient upset conditions, and that reactor vessel temperatures do not exceed ASME code limits for steady-state or transient conditions using standard LWR vessel materials. Preconceptual designs for both an S-I thermochemical and HTE hydrogen production plant driven by a 600 MWt MHR at helium outlet temperatures in the range of 900 oC to 1000 oC are described and compared. An initial SAPHIRE model to evaluate the reliability, maintainablility, and availability of the S-I hydrogen production plant is also discussed, and plans for future assessments of conceptual designs for both a S-I thermochemical and HTE hydrogen production plant coupled to a 600 MWt modular helium reactor are described.

E. A. Harvego; S. M. Reza; M. Richards; A. Shenoy

2005-05-01T23:59:59.000Z

77

Hydrogen production using ammonia borane  

SciTech Connect

Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.

Hamilton, Charles W; Baker, R. Thomas; Semelsberger, Troy A; Shrestha, Roshan P

2013-12-24T23:59:59.000Z

78

Alternative Fuels Data Center: Hydrogen Production and Distribution  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Production Production and Distribution to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Production and Distribution on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Production and Distribution on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Production and Distribution on Google Bookmark Alternative Fuels Data Center: Hydrogen Production and Distribution on Delicious Rank Alternative Fuels Data Center: Hydrogen Production and Distribution on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Production and Distribution on AddThis.com... More in this section... Hydrogen Basics Production & Distribution Research & Development Related Links Benefits & Considerations Stations Vehicles Laws & Incentives

79

Hydrolysis reactor for hydrogen production  

SciTech Connect

In accordance with certain embodiments of the present disclosure, a method for hydrolysis of a chemical hydride is provided. The method includes adding a chemical hydride to a reaction chamber and exposing the chemical hydride in the reaction chamber to a temperature of at least about 100.degree. C. in the presence of water and in the absence of an acid or a heterogeneous catalyst, wherein the chemical hydride undergoes hydrolysis to form hydrogen gas and a byproduct material.

Davis, Thomas A.; Matthews, Michael A.

2012-12-04T23:59:59.000Z

80

Hydrogen Production: Overview of Technology Options, January 2009  

Fuel Cell Technologies Publication and Product Library (EERE)

Overview of technology options for hydrogen production, its challenges and reserach needs and next steps

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Low-cost process for hydrogen production  

DOE Patents (OSTI)

A method is provided for producing hydrogen and carbon black from hydrocarbon gases comprising mixing the hydrocarbon gases with a source of carbon and applying radiofrequency energy to the mixture. The hydrocarbon gases and the carbon can both be the products of gasification of coal, particularly the mild gasification of coal. A method is also provided for producing hydrogen an carbon monoxide by treating a mixture of hydrocarbon gases and steam with radio-frequency energy.

Cha, Chang Y. (Golden, CO); Bauer, Hans F. (Morgantown, WV); Grimes, Robert W. (Laramie, WY)

1993-01-01T23:59:59.000Z

82

Low-cost process for hydrogen production  

DOE Patents (OSTI)

A method is provided for producing hydrogen and carbon black from hydrocarbon gases comprising mixing the hydrocarbon gases with a source of carbon and applying radiofrequency energy to the mixture. The hydrocarbon gases and the carbon can both be the products of gasification of coal, particularly the mild gasification of coal. A method is also provided for producing hydrogen and carbon monoxide by treating a mixture of hydrocarbon gases and steam with radio-frequency energy.

Cha, C.H.; Bauer, H.F.; Grimes, R.W.

1993-03-30T23:59:59.000Z

83

Fuel Cell Technologies Office: Biological Hydrogen Production Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Biological Hydrogen Production Workshop Biological Hydrogen Production Workshop The U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory (NREL) held a Biological Hydrogen Production Workshop on September 24-25, 2013, in Golden, Colorado. The workshop featured 29 participants representing academia, government, and national laboratories with expertise in the relevant fields. The objective of the Biological Hydrogen Production Workshop was to share information and identify issues, barriers, and research and development needs for biological hydrogen production to enable hydrogen production that meets cost goals. Proceedings 2013 Biological Hydrogen Production Workshop Final Report Presentations Introductory Session Fuel Cell Technologies Office Overview, Sara Dillich, DOE Fuel Cell Technologies Office

84

Photoelectrochemical Hydrogen Production - Final Report  

DOE Green Energy (OSTI)

The scope of this photoelectrochemical hydrogen research project is defined by multijunction photoelectrode concepts for solar-powered water splitting, with the goal of efficient, stable, and economic operation. From an initial selection of several planar photoelectrode designs, the Hybrid Photoelectrode (HPE) has been identified as the most promising candidate technology. This photoelectrode consists of a photoelectrochemical (PEC) junction and a solid-state photovoltaic (PV) junction. Immersed in aqueous electrolyte and exposed to sunlight, these two junctions provide the necessary voltage to split water into hydrogen and oxygen gas. The efficiency of the conversion process is determined by the performance of the PEC- and the PV-junctions and on their spectral match. Based on their stability and cost effectiveness, iron oxide (Fe2O3) and tungsten oxide (WO3) films have been studied and developed as candidate semiconductor materials for the PEC junction (photoanode). High-temperature synthesis methods, as reported for some high-performance metal oxides, have been found incompatible with multijunction device fabrication. A low-temperature reactive sputtering process has been developed instead. In the parameter space investigated so far, the optoelectronic properties of WO3 films were superior to those of Fe2O3 films, which showed high recombination of photo-generated carriers. For the PV-junction, amorphous-silicon-based multijunction devices have been studied. Tandem junctions were preferred over triple junctions for better stability and spectral matching with the PEC junction. Based on a tandem a-SiGe/a-SiGe device and a tungsten trioxide film, a prototype hybrid photoelectrode has been demonstrated at 0.7% solar-to-hydrogen (STH) conversion efficiency. The PEC junction performance has been identified as the most critical element for higher-efficiency devices. Research into sputter-deposited tungsten trioxide films has yielded samples with higher photocurrents of up to 1.3 mA/cm2. An improved a-Si/aSi tandem device has been demonstrated that would provide a better voltage match to the recently improved WO3 films. For a hybrid photoelectrode based on these component devices the projected STH efficiency is 1.3%. For significant efficiency enhancements, metal oxide films with increased optical absorption, thus lower bandgap, are necessary. Initial experiments were successful in lowering the WO3 bandgap by nitrogen doping, from 3.0 eV to 2.1 eV. Optimizing the electronic properties of these compounds, or other reduced-bandgap materials such as Fe2O3, is the most immediate challenge. As the photocurrent levels of the PEC junction are improved, increasing attention will have to be paid to the matching PV junction.

Miller, E.L.; Marsen, B.; Paluselli, D.; Rocheleau, R.

2004-11-17T23:59:59.000Z

85

Systematic Discrimination of Advanced Hydrogen Production Technologies  

SciTech Connect

The U.S. Department of Energy, in concert with industry, is developing a high-temperature gas-cooled reactor at the Idaho National Laboratory (INL) to demonstrate high temperature heat applications to produce hydrogen and electricity or to support other industrial applications. A key part of this program is the production of hydrogen from water that would significantly reduce carbon emissions compared to current production using natural gas. In 2009 the INL led the methodical evaluation of promising advanced hydrogen production technologies in order to focus future resources on the most viable processes. This paper describes how the evaluation process was systematically planned and executed. As a result, High-Temperature Steam Electrolysis was selected as the most viable near-term technology to deploy as a part of the Next Generation Nuclear Plant Project.

Charles V. Park; Michael W. Patterson

2010-07-01T23:59:59.000Z

86

Hydrogen Production Infrastructure Options Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

Production Production Infrastructure Options Analysis January 26, 2006 Brian D. James Julie Perez Peter Schmidt (703) 243 - 3383 Brian_James@DirectedTechnologies.com Directed Technologies, Inc. Page 1 of 39 26 January 2006 2006-1-26 DOE Transition Workshop Agenda 1. Project Description and Objective 2. Team Members 3. Approach 4. Model Theory, Structure and Assumptions 5. Model Description 1. Logic 2. Features 3. Cost Components (Production, Delivery & Dispensing) 6. Los Angeles Transitional Example 7. Model Flexibility Page 2 of 39 26 January 2006 2006-1-26 DOE Transition Workshop Team Members & Interactions Start: May 2005 (effective) End: Summer 2007 * Directed Technologies, Inc.- Prime * Sentech, Inc., Research Partner * Air Products, Industrial Gas Supplier * Advisory Board * Graham Moore, Chevron Technology Ventures

87

Method for the enzymatic production of hydrogen  

DOE Green Energy (OSTI)

The present invention is an enzymatic method for producing hydrogen comprising the steps of: a) forming a reaction mixture within a reaction vessel comprising a substrate capable of undergoing oxidation within a catabolic reaction, such as glucose, galactose, xylose, mannose, sucrose, lactose, cellulose, xylan and starch. The reaction mixture further comprises an amount of glucose dehydrogenase in an amount sufficient to catalyze the oxidation of the substrate, an amount of hydrogenase sufficient to catalyze an electron-requiring reaction wherein a stoichiometric yield of hydrogen is produced, an amount of pH buffer in an amount sufficient to provide an environment that allows the hydrogenase and the glucose dehydrogenase to retain sufficient activity for the production of hydrogen to occur and also comprising an amount of nicotinamide adenine dinucleotide phosphate sufficient to transfer electrons from the catabolic reaction to the electron-requiring reaction; b) heating the reaction mixture at a temperature sufficient for glucose dehydrogenase and the hydrogenase to retain sufficient activity and sufficient for the production of hydrogen to occur, and heating for a period of time that continues until the hydrogen is no longer produced by the reaction mixture, wherein the catabolic reaction and the electron-requiring reactions have rates of reaction dependent upon the temperature; and c) detecting the hydrogen produced from the reaction mixture.

Woodward, Jonathan (Kingston, TN); Mattingly, Susan M. (State College, PA)

1999-01-01T23:59:59.000Z

88

Measurement of Hydrogen Production Rate Based on Dew Point Temperature...  

NLE Websites -- All DOE Office Websites (Extended Search)

MP-150-42237 U. S. Department of Energy Hydrogen Program Measurement of Hydrogen Production Rate Based on Dew Point Temperatures National Renewable Energy Laboratory 1617 Cole...

89

Enzymatic production of hydrogen from glucose  

DOE Green Energy (OSTI)

The objective of this research is to optimize conditions for the enzymatic production of hydrogen gas from biomass-derived glucose. This new project is funded at 0.5 PY level of effort for FY 1995. The rationale for the work is that cellulose is, potentially, a vast source of hydrogen and that enzymes offer a specific and efficient method for its extraction with minimal environmental impact. This work is related to the overall hydrogen program goal of technology development and validation. The approach is based on knowledge that glucose is oxidized by the NADP{sup +} requiring enzyme glucose dehydrogenase (GDH) and that the resulting NADPH can donate its electrons to hydrogenase (H{sub 2}ase) which catalyzes the evolution of H{sub 2}. Thus hydrogen production from glucose was achieved using calf liver GDH and Pyrococcus furiosus H{sub 2}ase yielding 17% of theoretical maximum expected. The cofactor NADP{sup +} for this reaction was regenerated and recycled. Current and future work includes understanding the rate limiting steps of this process and the stabilization/immobilization of the enzymes for long term hydrogen production. Cooperative interactions with the Universities of Georgia and Bath for obtaining thermally stable enzymes are underway.

Woodward, J. [Oak Ridge National Lab., TN (United States); Mattingly, S.M.

1995-06-01T23:59:59.000Z

90

Water electrolysis vs. thermochemical production of hydrogen: a parametric assessment  

SciTech Connect

A general discussion of hydrogen production by electrolytic and thermochemical processes is presented. A hydrogen production cost computation and cost sensitivity data for the various production methods are reported. (LK)

Salzano, F.J.; Braun, C.

1976-01-01T23:59:59.000Z

91

Method for the continuous production of hydrogen  

DOE Green Energy (OSTI)

The present invention is a method for the continuous production of hydrogen. The present method comprises reacting a metal catalyst with a degassed aqueous organic acid solution within a reaction vessel under anaerobic conditions at a constant temperature of .ltoreq.80.degree. C. and at a pH ranging from about 4 to about 9. The reaction forms a metal oxide when the metal catalyst reacts with the water component of the organic acid solution while generating hydrogen, then the organic acid solution reduces the metal oxide thereby regenerating the metal catalyst and producing water, thus permitting the oxidation and reduction to reoccur in a continual reaction cycle. The present method also allows the continuous production of hydrogen to be sustained by feeding the reaction with a continuous supply of degassed aqueous organic acid solution.

Getty, John Paul (Knoxville, TN); Orr, Mark T. (Kingsport, TN); Woodward, Jonathan (Kingston, TN)

2002-01-01T23:59:59.000Z

92

Optical pumping production of spin polarized hydrogen  

DOE Green Energy (OSTI)

There has been much interest recently in the production of large quantities of spin polarized hydrogen in various fields, including controlled fusion, quantum fluids, high energy, and nuclear physics. One promising method for the development of large quantities of spin polarized hydrogen is the utilization of optical pumping with a laser. Optical pumping is a process in which photon angular momentum is converted into electron and nuclear spin. The advent of tunable CW dye lasers (approx. 1 watt) allows the production of greater than 10/sup 18/ polarized atoms/sec. We have begun a program at Princeton to investigate the physics and technology of using optical pumping to produce large quantities of spin polarized hydrogen. Initial experiments have been done in small closed glass cells. Eventually, a flowing system, open target, or polarized ion source could be constructed.

Knize, R.J.; Happer, W.; Cecchi, J.L.

1984-09-01T23:59:59.000Z

93

Catalytic carbon membranes for hydrogen production  

DOE Green Energy (OSTI)

Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC)

Damle, A.S.; Gangwal, S.K.

1992-01-01T23:59:59.000Z

94

Thermochemical production of hydrogen: reality, not myth  

SciTech Connect

An economic analysis of the hybrid sulfuric acid cycle shows that a specific thermochemical process for hydrogen production from water can compete successfully with conventional and advanced electrolytic processes. A generalization to the contrary, based on computer-generated thermochemical cycles, is misleading and erroneous.

Cox, K.E.

1978-09-01T23:59:59.000Z

95

Cathode for the electrolytic production of hydrogen  

SciTech Connect

The invention relates to a cathode for the electrolytic production of hydrogen. The cathode comprises an active surface consisting of a metal oxide obtained by the thermal decomposition of a thermally decomposable compound of a metal chosen from amongst cobalt, iron, manganese or nickel. The cathode is particularly suitable for the electrolysis of aqueous sodium chloride solutions in cells with a permeable diaphragm.

Nicolas, E.

1983-07-19T23:59:59.000Z

96

Synfuel (hydrogen) production from fusion power  

DOE Green Energy (OSTI)

A potential use of fusion energy for the production of synthetic fuel (hydrogen) is described. The hybrid-thermochemical bismuth-sulfate cycle is used as a vehicle to assess the technological and economic merits of this potential nonelectric application of fusion power.

Krakowski, R.A.; Cox, K.E.; Pendergrass, J.H.; Booth, L.A.

1979-01-01T23:59:59.000Z

97

IONICALLY CONDUCTING MEMBRANES FOR HYDROGEN PRODUCTION AND  

E-Print Network (OSTI)

SEQUESTRATION Oxygen Transport Membrane Hydrogen Transport Membrane Natural Gas Coal Biomass Syngas CO/H2 WGS H2 operating experience. #12;ELTRON RESEARCH INC. Syngas Production Rate ­ 60 mL/min cm2 @ 900°C Equivalent O2 Operational Experience Under High Pressure Differential SUMMARY OF ELTRON OXYGEN TRANSPORT MEMBRANE SYNGAS

98

Integrated Hydrogen Production, Purification and Compression System  

DOE Green Energy (OSTI)

The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of <$1.50/gge, which was later revised by DOE to $2-$3/gge range for hydrogen to be competitive with gasoline as a fuel for vehicles. For small, on-site hydrogen plants being evaluated at the time for refueling stations (the 'forecourt'), it was determined that capital cost is the main contributor to the high cost of delivered hydrogen. The concept of this project was to reduce the cost by combining unit operations for the entire generation, purification, and compression system (refer to Figure 1). To accomplish this, the Fluid Bed Membrane Reactor (FBMR) developed by MRT was used. The FBMR has hydrogen selective, palladium-alloy membrane modules immersed in the reformer vessel, thereby directly producing high purity hydrogen in a single step. The continuous removal of pure hydrogen from the reformer pushes the equilibrium 'forward', thereby maximizing the productivity with an associated reduction in the cost of product hydrogen. Additional gains were envisaged by the integration of the novel Metal Hydride Hydrogen Compressor (MHC) developed by Ergenics, which compresses hydrogen from 0.5 bar (7 psia) to 350 bar (5,076 psia) or higher in a single unit using thermal energy. Excess energy from the reformer provides up to 25% of the power used for driving the hydride compressor so that system integration improved efficiency. Hydrogen from the membrane reformer is of very high, fuel cell vehicle (FCV) quality (purity over 99.99%), eliminating the need for a separate purification step. The hydride compressor maintains hydrogen purity because it does not have dynamic seals or lubricating oil. The project team set out to integrate the membrane reformer developed by MRT and the hydride compression system developed by Ergenics in a single package. This was expected to result in lower cost and higher efficiency compared to conventional hydrogen production technologies. The overall objective was to develop an integrated system to directly produce high pressure, high-purity hydrogen from a single unit, which can meet the DOE cost H2 cost target of $2 - $3/gge when mass produced. The project was divided into two phases with the following tasks and corresponding milestones, targets and decision points. Phase 1 - Task 1 - Verify feasibility of the concept, perform a detailed techno-economic analysis, and develop a test plan; and Task 2: Build and experimentally test a Proof of Concept (POC) integrated membrane reformer/metal hydride compressor system. Phase 2 - Task 3: Build an Advanced Prototype (AP) system with modifications based on POC learning and demonstrate at a commercial site; and Task 4: Complete final product design for mass manufacturing units capable of achieving DOE 2010 H2 cost and performance targets.

Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

2011-06-30T23:59:59.000Z

99

DOE Hydrogen Analysis Repository: H2A Production Model  

NLE Websites -- All DOE Office Websites (Extended Search)

Production Model Project Summary Full Title: H2A Hydrogen Production Cost Analysis Model Project ID: 219 Principal Investigator: Todd Ramsden Brief Description: The H2A Production...

100

Fuel Cell Technologies Office: Electrolysis Production of Hydrogen from  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrolysis Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings to someone by E-mail Share Fuel Cell Technologies Office: Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings on Facebook Tweet about Fuel Cell Technologies Office: Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings on Twitter Bookmark Fuel Cell Technologies Office: Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings on Google Bookmark Fuel Cell Technologies Office: Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings on Delicious Rank Fuel Cell Technologies Office: Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings on Digg Find More places to share Fuel Cell Technologies Office:

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Chemical Looping for Combustion and Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

ChemiCal looping for Combustion and ChemiCal looping for Combustion and hydrogen produCtion Objective The objective of this project is to determine the benefits of chemical looping technology used with coal to reduce CO 2 emissions. Background Chemical looping is a new method to convert coal or gasified coal to energy. In chemical looping, there is no direct contact between air and fuel. The chemical looping process utilizes oxygen from metal oxide oxygen carrier for fuel combustion, or for making hydrogen by "reducing" water. In combustion applications, the products of chemical looping are CO 2 and H 2 O. Thus, once the steam is condensed, a relatively pure stream of CO 2 is produced ready for sequestration. The production of a sequestration ready CO 2 stream does not require any additional separation units

102

DOE Hydrogen Analysis Repository: Production of Hydrogen byPhotovolta...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrolysis Project ID: 132 Principal Investigator: DL Block Purpose Compare the cost of hydrogen produced using photo electric chemical systems to the cost of hydrogen...

103

Renewable hydrogen production by photosynthetic water splitting  

SciTech Connect

This mission-oriented research project is focused on the production of renewable hydrogen. The authors have demonstrated that certain unicellular green algae are capable of sustained simultaneous photoproduction of hydrogen and oxygen by light-activated photosynthetic water splitting. It is the goal of this project to develop a practical chemical engineering system for the development of an economic process that can be used to produce renewable hydrogen. There are several fundamental problems that need to be solved before the application of this scientific knowledge can be applied to the development a practical process: (I) maximizing net thermodynamic conversion efficiency of light energy into hydrogen energy, (2) development of oxygen-sensitive hydrogenase-containing mutants, and (3) development of bioreactors that can be used in a real-world chemical engineering process. The authors are addressing each of these problems here at ORNL and in collaboration with their research colleagues at the National Renewable Energy Laboratory, the University of California, Berkeley, and the University of Hawaii. This year the authors have focused on item 1 above. In particular, they have focused on the question of how many light reactions are required to split water to molecular hydrogen and oxygen.

Greenbaum, E.; Lee, J.W.

1998-06-01T23:59:59.000Z

104

Thermochemical hydrogen production based on magnetic fusion  

DOE Green Energy (OSTI)

Conceptual design studies have been carried out on an integrated fusion/chemical plant system using a Tandem Mirror Reactor fusion energy source to drive the General Atomic Sulfur-Iodine Water-Splitting Cycle and produce hydrogen as a future feedstock for synthetic fuels. Blanket design studies for the Tandem Mirror Reactor show that several design alternatives are available for providing heat at sufficiently high temperatures to drive the General Atomic Cycle. The concept of a Joule-boosted decomposer is introduced in one of the systems investigated to provide heat electrically for the highest temperature step in the cycle (the SO/sub 3/ decomposition step), and thus lower blanket design requirements and costs. Flowsheeting and conceptual process designs have been developed for a complete fusion-driven hydrogen plant, and the information has been used to develop a plot plan for the plant and to estimate hydrogen production costs. Both public and private utility financing approaches have been used to obtain hydrogen production costs of $12-14/GJ based on July 1980 dollars.

Krikorian, O.H.; Brown, L.C.

1982-06-10T23:59:59.000Z

105

Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings  

Fuel Cell Technologies Publication and Product Library (EERE)

This document summarizes the opportunities and challenges for low-cost renewable hydrogen production from wind and hydropower. The Workshop on Electrolysis Production of Hydrogen from Wind and Hydropo

106

Solar and Wind Technologies for Hydrogen Production Report to Congress  

Fuel Cell Technologies Publication and Product Library (EERE)

DOE's Solar and Wind Technologies for Hydrogen Production Report to Congress summarizes the technology roadmaps for solar- and wind-based hydrogen production. Published in December 2005, it fulfills t

107

Hydrogen Production Roadmap: Technology Pathways to the Future, January 2009  

Fuel Cell Technologies Publication and Product Library (EERE)

Roadmap to identify key challenges and priority R&D needs associated with various hydrogen fuel production technologies.

108

Hydrogen Production from Nuclear Energy via High Temperature Electrolysis  

DOE Green Energy (OSTI)

This paper presents the technical case for high-temperature nuclear hydrogen production. A general thermodynamic analysis of hydrogen production based on high-temperature thermal water splitting processes is presented. Specific details of hydrogen production based on high-temperature electrolysis are also provided, including results of recent experiments performed at the Idaho National Laboratory. Based on these results, high-temperature electrolysis appears to be a promising technology for efficient large-scale hydrogen production.

James E. O'Brien; Carl M. Stoots; J. Stephen Herring; Grant L. Hawkes

2006-04-01T23:59:59.000Z

109

Startech Hydrogen Production Final Technical Report  

SciTech Connect

The assigned work scope includes the modification and utilization of the Plasma Converter System, Integration of a StarCell{trademark} Multistage Ceramic Membrane System (StarCell), and testing of the integrated systems towards DOE targets for gasification and membrane separation. Testing and evaluation was performed at the Startech Engineering and Demonstration Test Center in Bristol, CT. The Objectives of the program are as follows: (1) Characterize the performance of the integrated Plasma Converter and StarCell{trademark} Systems for hydrogen production and purification from abundant and inexpensive feedstocks; (2) Compare integrated hydrogen production performance to conventional technologies and DOE benchmarks; (3) Run pressure and temperature testing to baseline StarCell's performance; and (4) Determine the effect of process contaminants on the StarCell{trademark} system.

Startech Engineering Department

2007-11-27T23:59:59.000Z

110

Apparatus for production of hydrogen peroxide  

SciTech Connect

An apparatus for the production of hydrogen peroxide is described, the apparatus comprising: (A) an electrolytic cell comprising; (I) a chamber filled with an electrolyte solution; (II) an anode; (III) a cathode; (IV) means for generating a current between the anode and cathode; and (V) a barrier separating the cell into an anodic and a cathodic compartment; (B) high surface area elements carrying a surface derivatized quinone catalyst which is capable of undergoing reduction upon immersion in the cathodic compartment of the electrolytic cell; (C) means for separating the elements from the electrolytic cell upon reduction; and (D) a production chamber wherein the separated reduced elements can react with oxygen in an aqueous environment to produce hydrogen peroxide.

Wrighton, M.S.; Buchanan, R.M.; Calabrese, G.S.

1986-02-25T23:59:59.000Z

111

Alternative Fuels Data Center: Ethanol and Hydrogen Production Facility  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Ethanol and Hydrogen Ethanol and Hydrogen Production Facility Permits to someone by E-mail Share Alternative Fuels Data Center: Ethanol and Hydrogen Production Facility Permits on Facebook Tweet about Alternative Fuels Data Center: Ethanol and Hydrogen Production Facility Permits on Twitter Bookmark Alternative Fuels Data Center: Ethanol and Hydrogen Production Facility Permits on Google Bookmark Alternative Fuels Data Center: Ethanol and Hydrogen Production Facility Permits on Delicious Rank Alternative Fuels Data Center: Ethanol and Hydrogen Production Facility Permits on Digg Find More places to share Alternative Fuels Data Center: Ethanol and Hydrogen Production Facility Permits on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type

112

NETL: News Release - DOE Advances Production of Hydrogen from Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

6 , 2006 6 , 2006 DOE Advances Production of Hydrogen from Coal Projects Selected to Address Technological Challenges of Hydrogen Production in Large-Scale Facilities WASHINGTON, DC - The Department of Energy today announced the selection of six research and development projects that will promote the production of hydrogen from coal at large-scale facilities. This central approach will combat climate change by allowing for the capture - and subsequent sequestration - of carbon dioxide generated during hydrogen production. The selections support President Bush's Hydrogen Fuel Initiative, which provides funding for research and technology development to realize a future hydrogen economy that minimizes America's dependence on foreign oil and reduces greenhouse gas emissions.

113

Analysis of Hydrogen Production from Renewable Electricity Sources: Preprint  

DOE Green Energy (OSTI)

To determine the potential for hydrogen production via renewable electricity sources, three aspects of the system are analyzed: a renewable hydrogen resource assessment, a cost analysis of hydrogen production via electrolysis, and the annual energy requirements of producing hydrogen for refueling. The results indicate that ample resources exist to produce transportation fuel from wind and solar power. However, hydrogen prices are highly dependent on electricity prices.

Levene, J. I.; Mann, M. K.; Margolis, R.; Milbrandt, A.

2005-09-01T23:59:59.000Z

114

Increasing Efficiency in Photoelectrochemical Hydrogen Production  

DOE Green Energy (OSTI)

Photoelectrochemical hydrogen production promises to be a renewable, clean, and efficient way of storing the sun's energy for use in hydrogen-powered fuel cells. We use p-type Ga.51In.49P semiconductor (henceforth as GaInP2) to absorb solar energy and produce a photocurrent. When the semiconductor is immersed in water, the photocurrent can break down water into hydrogen and oxygen. However, before the GaInP2 can produce hydrogen and oxygen, the conduction band and the Fermi level of the semiconductor must overlap the water redox potentials. In an unmodified system, the conduction band and Fermi level of GaInP2 do not overlap the water redox potentials. When light shines on the semiconductor, electrons build up on the surface, shifting the bandedges and Fermi level further away from overlap of the water redox potentials. We report on surface treatments with metallated porphyrins and transition metals that suppress bandedge migration and allow bandedge overlap to occur. Coating ruthenium octaethylporphyrin carbonyl (RuOEP CO) on the GaInP2 surface shifted bandedges in the positive direction by 270 mV on average, allowing the bandedges to frequently overlap the water redox potentials. Coating the GaInP2 surface with RuCl3 catalyzed charge transfer from the semiconductor to the water, lessening bandedge migration under light irradiation. Future work will focus on the long-term surface stability of these new treatments and quantitative applications of porphyrins.

Warren, S.; Turner, J.

2002-01-01T23:59:59.000Z

115

DOE Hydrogen Analysis Repository: Transition Analysis - H2 Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Transition Analysis - H2 Production and Delivery Infrastructure Project Summary Full Title: Transition Analysis of the Hydrogen Production and Delivery Infrastructure as a Complex...

116

Method of Production of Pure Hydrogen Near Room Temperature ...  

Energy Storage ... The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous h ...

117

Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Feasibility Study of Hydrogen Production at Existing Nuclear Power Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants A funding opportunity announcement of the cost shared feasibility studies of nuclear energy based production of hydrogen using available technology. The objective of this activity is to select and conduct project(s) that will utilize hydrogen production equipment and nuclear energy as necessary to produce data and analysis on the economics of hydrogen production with nuclear energy. Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants More Documents & Publications https://e-center.doe.gov/iips/faopor.nsf/UNID/E67E46185A67EBE68 Microsoft Word - FOA cover sheet.doc Microsoft Word - hDE-FOA-0000092.rtf

118

Impact of Hydrogen Production on U.S. Energy Markets  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production on Impact of Hydrogen Production on Hydrogen Production on Impact of Hydrogen Production on U.S. Energy Markets U.S. Energy Markets Presented to: Presented to: DOE Hydrogen Transition DOE Hydrogen Transition Analysis Workshop Analysis Workshop Washington DC Washington DC January 26, 2006 January 26, 2006 Prepared by: Prepared by: E. Harry Vidas, Energy and Environmental Analysis, Inc. E. Harry Vidas, Energy and Environmental Analysis, Inc. Paul Friley, Brookhaven National Laboratory Paul Friley, Brookhaven National Laboratory AZ CA Project Scope Project Scope * Focus will be on competition between hydrogen production and distribution technologies with respect to hydrogen fuel demand, technology cost, regional mix, and impact on feedstock prices. * Evaluate impacts on U.S. energy markets including price

119

Production of low-cost hydrogen  

DOE Green Energy (OSTI)

The overall objective of the proposed effort is to verify at the laboratory scale, the ability of the MTCI indirectly heated fluid-bed gasifier to economically produce a hydrogen-rich product gas from liquefaction by-product streams and from char produced in mild gasification processes. Specifically, the proposed effort is aimed at developing an experimental technology data base by defining the process characteristics that would be required for process integration into an overall liquefaction system. This would result in substantial decreases in the cost of hydrogen for the production of competitively priced coal-derived liquid fuels. During this quarter, shakedown tests of the reactor were completed. Subbituminous coals from Black Thunder mine and Eagle Butte mine were obtained for use in mild gasification to produce char. During the initial shakedown tests, it was determined that a new pulse combustor was needed. A pulse combustor with a large aerovalve was fabricated and tested. Three shakedown tests with limestone as the fluid-bed medium were carried out at temperature from 1450{degree}F to 1550{degree}F.

Not Available

1990-01-01T23:59:59.000Z

120

Hydrogen  

U.S. Energy Information Administration (EIA)

-No Data Reported; --= Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: Hydrogen production ...

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The economics of biological methods of hydrogen production  

E-Print Network (OSTI)

The costs to produce and utilize hydrogen are extremely high per unit of energy when compared to fossil fuel energy sources such as natural gas or gasoline. The cheapest hydrogen production approaches today are also the ...

Resnick, Richard J. (Richard Jay), 1971-

2004-01-01T23:59:59.000Z

122

2013 Biological Hydrogen Production Workshop Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

that improved hydrogen evolution rates. Photo courtesy of Philip D. Weyman, J. Craig Venter Institute Bacteria break down biomass to produce hydrogen in a fermentation...

123

Nanolipoprotein Particles for Hydrogen Production - Energy ...  

Hydrogen is a renewable energy carrier that has the potential to replace fossil fuels in our economy. The majority of hydrogen produced today is from natural gas, ...

124

Fuel Cell Technologies Office: Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems...

125

Basic Research for Hydrogen Production, Storage and Use  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Hydrogen and Fuel Cells DOE Hydrogen and Fuel Cells Coordination Meeting 6/2/2003 DOE DOE - - BES Sponsored Workshop on BES Sponsored Workshop on Basic Research for Hydrogen Basic Research for Hydrogen Production, Storage and Use Production, Storage and Use Walter J. Stevens Walter J. Stevens Director Director Chemical Sciences, Geosciences, and Biosciences Division Chemical Sciences, Geosciences, and Biosciences Division Office of Basic Energy Sciences Office of Basic Energy Sciences Workshop dates: May 13-15, 2003 A follow-on workshop to BESAC-sponsored workshop on "Basic Research Needs to Assure a Secure Energy Future" Basic Energy Sciences Basic Energy Sciences Workshop on Hydrogen Production, Storage, and Use Workshop on Hydrogen Production, Storage, and Use DOE Hydrogen and Fuel Cells

126

Nuclear Hydrogen for Peak Electricity Production and Spinning Reserve  

Science Conference Proceedings (OSTI)

Nuclear energy can be used to produce hydrogen. The key strategic question is this: ''What are the early markets for nuclear hydrogen?'' The answer determines (1) whether there are incentives to implement nuclear hydrogen technology today or whether the development of such a technology could be delayed by decades until a hydrogen economy has evolved, (2) the industrial partners required to develop such a technology, and (3) the technological requirements for the hydrogen production system (rate of production, steady-state or variable production, hydrogen purity, etc.). Understanding ''early'' markets for any new product is difficult because the customer may not even recognize that the product could exist. This study is an initial examination of how nuclear hydrogen could be used in two interconnected early markets: the production of electricity for peak and intermediate electrical loads and spinning reserve for the electrical grid. The study is intended to provide an initial description that can then be used to consult with potential customers (utilities, the Electric Power Research Institute, etc.) to better determine the potential real-world viability of this early market for nuclear hydrogen and provide the starting point for a more definitive assessment of the concept. If this set of applications is economically viable, it offers several unique advantages: (1) the market is approximately equivalent in size to the existing nuclear electric enterprise in the United States, (2) the entire market is within the utility industry and does not require development of an external market for hydrogen or a significant hydrogen infrastructure beyond the utility site, (3) the technology and scale match those of nuclear hydrogen production, (4) the market exists today, and (5) the market is sufficient in size to justify development of nuclear hydrogen production techniques independent of the development of any other market for hydrogen. These characteristics make it an ideal early market for nuclear hydrogen.

Forsberg, C.W.

2005-01-20T23:59:59.000Z

127

Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen Production  

DOE Green Energy (OSTI)

Report documenting the biological and engineering characteristics of five algal and bacterial hydrogen production systems selected by DOE and NREL for evaluation.

James, B. D.; Baum, G. N.; Perez, J.; Baum, K. N.

2009-09-01T23:59:59.000Z

128

Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen Production  

Fuel Cell Technologies Publication and Product Library (EERE)

Report documenting the biological and engineering characteristics of five algal and bacterial hydrogen production systems selected by DOE and NREL for evaluation.

129

Investigation of sustainable hydrogen production from steam biomass gasification.  

E-Print Network (OSTI)

??Hydrogen is a by-product of the gasification process and it is environmentally friendly with respect to pollution and emission issues when it is derived from (more)

Abuadala, Abdussalam Goma

2010-01-01T23:59:59.000Z

130

Life Cycle Assessment of Hydrogen Production via Natural Gas...  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessment of Hydrogen Production via Natural Gas Steam Reforming Revised February 2001 * NRELTP-570-27637 Pamela L. Spath Margaret K. Mann National Renewable Energy Laboratory...

131

Renewable Hydrogen Production at Hickam Air Force Base  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production at Hickam Air Force Base November 2009 Hawaii Center for Advanced Transportation Technologies *&1; Established by the High Technology Development Corporation (a...

132

Sulfur-Iodine thermochemical cycle for hydrogen production.  

E-Print Network (OSTI)

??The aim of the thesis was to study the Sulfur-Iodine thermochemical cycle for hydrogen production. There were three reactions in this cycle: Bunsen reaction, sulfuric (more)

Dan, Huang

2009-01-01T23:59:59.000Z

133

H2A Hydrogen Production Analysis Tool (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Cost Analyses Darlene Steward, NREL H2A Overview * Discounted cash flow analysis tool for production of hydrogen from various feedstocks - Inputs are; * Capital costs * Operating...

134

A Continuous Solar Thermochemical Hydrogen Production Plant Design  

E-Print Network (OSTI)

powered by solar thermal energy for hydrogen production. TheHigh Temperature Thermal Energy Storage an Experimental21 2.5 Solar Thermal Energy and Solar

Luc, Wesley Wai

135

Chemical Looping Gasification for Hydrogen Enhanced Syngas Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Chemical Looping Gasification for Hydrogen Enhanced Syngas Production with In-Situ CO2 Capture The Ohio State University (OSU) Project Number: FE0012136 Project Description The...

136

Hybrid Molten Bed Gasifier for High Hydrogen Syngas Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Hybrid Molten Bed Gasifier for High Hydrogen (H2) Syngas Production Gas Technology Institute (GTI) Project Number: FE0012122 Project Description The research team will evaluate and...

137

Carbonate Thermochemical Cycle for the Production of Hydrogen ...  

Carbonate Thermochemical Cycle for the Production of Hydrogen (Supplemental to ID 1435) Note: The technology described above is an early stage opportunity.

138

Methane Decomposition: Production of Hydrogen and Carbon Filaments  

E-Print Network (OSTI)

) is an obvious source for hydrogen. Steam reforming of methane represents the current trend for hydrogen. The process required to eliminate CO from the hydrogen produced in the steam reformer is briefly described below. The steam reformer products containing B10% CO (depending on the feedstock and conditions

Goodman, Wayne

139

Fermentation and Electrohydrogenic Approaches to Hydrogen Production (Presentation)  

DOE Green Energy (OSTI)

This work describes the development of a waste biomass fermentation process using cellulose-degrading bacteria for hydrogen production. This process is then integrated with an electrohydrogenesis process via the development of a microbial electrolysis cell reactor, during which fermentation waste effluent is further converted to hydrogen to increase the total output of hydrogen from biomass.

Maness, P. C.; Thammannagowda, S.; Magnusson, L.; Logan, B.

2010-06-01T23:59:59.000Z

140

Hydrogen Gas Production from Nuclear Power Plant in Relation to Hydrogen Fuel Cell Technologies Nowadays  

Science Conference Proceedings (OSTI)

Recently, world has been confused by issues of energy resourcing, including fossil fuel use, global warming, and sustainable energy generation. Hydrogen may become the choice for future fuel of combustion engine. Hydrogen is an environmentally clean source of energy to end-users, particularly in transportation applications because without release of pollutants at the point of end use. Hydrogen may be produced from water using the process of electrolysis. One of the GEN-IV reactors nuclear projects (HTGRs, HTR, VHTR) is also can produce hydrogen from the process. In the present study, hydrogen gas production from nuclear power plant is reviewed in relation to commercialization of hydrogen fuel cell technologies nowadays.

Yusibani, Elin [Research Center for Hydrogen Industrial Use and Storage, AIST (Japan); Department of Physics, Universitas Syiah Kuala (Indonesia); Kamil, Insan; Suud, Zaki [Department of Physics, Institut Teknologi Bandung (Indonesia)

2010-06-22T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Methods and systems for the production of hydrogen  

DOE Patents (OSTI)

Methods and systems are disclosed for the production of hydrogen and the use of high-temperature heat sources in energy conversion. In one embodiment, a primary loop may include a nuclear reactor utilizing a molten salt or helium as a coolant. The nuclear reactor may provide heat energy to a power generation loop for production of electrical energy. For example, a supercritical carbon dioxide fluid may be heated by the nuclear reactor via the molten salt and then expanded in a turbine to drive a generator. An intermediate heat exchange loop may also be thermally coupled with the primary loop and provide heat energy to one or more hydrogen production facilities. A portion of the hydrogen produced by the hydrogen production facility may be diverted to a combustor to elevate the temperature of water being split into hydrogen and oxygen by the hydrogen production facility.

Oh, Chang H. (Idaho Falls, ID); Kim, Eung S. (Ammon, ID); Sherman, Steven R. (Augusta, GA)

2012-03-13T23:59:59.000Z

142

DOE Science Showcase - Hydrogen Production | OSTI, US Dept of Energy,  

Office of Scientific and Technical Information (OSTI)

Hydrogen Production Hydrogen Production Hydrogen Research in DOE Databases Energy Citations Database Information Bridge Science.gov WorldWideScience.org More information Making molecular hydrogen more efficiently Breaking Up (Hydrogen) No Longer As Hard To Do Hydrogen and Our Energy Future Fuel Cell Animation Hydrogen & Fuel Cells Increase your Hydrogen IQ Visit the Science Showcase homepage. OSTI Homepage Mobile Gallery Subscribe to RSS OSTI Blog Get Widgets Get Alert Services OSTI Facebook OSTI Twitter OSTI Google+ Bookmark and Share (Link will open in a new window) Go to Videos Loading... Stop news scroll Most Visited Adopt-A-Doc DOE Data Explorer DOE Green Energy DOepatents DOE R&D Accomplishments .EDUconnections Energy Science and Technology Software Center E-print Network

143

Photo-electrolytic production of hydrogen  

SciTech Connect

Hydrogen and oxygen are produced from water in a process involving the photodissociation of molecular bromine with radiant energy at wavelengths within the visible light region and a subsequent electrolytic dissociation of hydrogen halides.

Meyerand, R.G. Jr.; Krascella, N.L.; McMahon, D.G.

1978-01-17T23:59:59.000Z

144

Hydrogen Production From Metal-Water Reactions  

E-Print Network (OSTI)

. Current methods of hydrogen storage in automobiles are either too bulky (large storage space for gas phase) or require a high input energy (cooling or pressurization systems for liquid hydrogen), making widespread use abundance, high- energy content, and large surface area, is able to combine with water to produce hydrogen

Barthelat, Francois

145

Production of Hydrogen from Peanut Shells The goal of this project is the production of renewable hydrogen from agricultural  

E-Print Network (OSTI)

to existing methane reforming technologies. The hydrogen produced will be blended with CNG and used to power activated carbon. The vapor by-products from the first step can be steam reformed into hydrogen. NREL has developed the technology for bio- oil to hydrogen via catalytic steam reforming and shift conversion

146

Hydrogen Production from Hydrogen Sulfide in IGCC Power Plants  

SciTech Connect

IGCC power plants are the cleanest coal-based power generation facilities in the world. Technical improvements are needed to help make them cost competitive. Sulfur recovery is one procedure in which improvement is possible. This project has developed and demonstrated an electrochemical process that could provide such an improvement. IGCC power plants now in operation extract the sulfur from the synthesis gas as hydrogen sulfide. In this project H{sub 2}S has been electrolyzed to yield sulfur and hydrogen (instead of sulfur and water as is the present practice). The value of the byproduct hydrogen makes this process more cost effective. The electrolysis has exploited some recent developments in solid state electrolytes. The proof of principal for the project concept has been accomplished.

Elias Stefanakos; Burton Krakow; Jonathan Mbah

2007-07-31T23:59:59.000Z

147

Nuclear hydrogen : an assessment of product flexibility and market viability.  

DOE Green Energy (OSTI)

Nuclear energy has the potential to play an important role in the future energy system as a large-scale source of hydrogen without greenhouse gas emissions. Thus far, economic studies of nuclear hydrogen tend to focus on the levelized cost of hydrogen without accounting for the risks and uncertainties that potential investors would face. We present a financial model based on real options theory to assess the profitability of different nuclear hydrogen production technologies in evolving electricity and hydrogen markets. The model uses Monte Carlo simulations to represent uncertainty in future hydrogen and electricity prices. It computes the expected value and the distribution of discounted profits from nuclear hydrogen production plants. Moreover, the model quantifies the value of the option to switch between hydrogen and electricity production, depending on what is more profitable to sell. We use the model to analyze the market viability of four potential nuclear hydrogen technologies and conclude that flexibility in output product is likely to add significant economic value for an investor in nuclear hydrogen. This should be taken into account in the development phase of nuclear hydrogen technologies.

Botterud, A.; Yildiz, B.; Conzelmann, G.; Petri, M.; Massachusetts Inst. of Tech.

2008-01-01T23:59:59.000Z

148

Renewable Hydrogen Production Using Sugars and Sugar Alcohols (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Working Group Meeting Working Group Meeting 11/06/2007 Renewable Hydrogen Production Using Renewable Hydrogen Production Using Sugars and Sugar Alcohols Sugars and Sugar Alcohols * * Problem: Problem: Need Need to develop renewable to develop renewable hydrogen production technologies using hydrogen production technologies using diverse diverse feedstocks feedstocks 10 15 20 CH 4 : C 6 H 14 ln(P) * * Description: Description: The BioForming The BioForming TM TM process uses process uses aqueous phase reforming to cost effectively aqueous phase reforming to cost effectively produce hydrogen from a range of feedstocks, produce hydrogen from a range of feedstocks, including glycerol and sugars. The key including glycerol and sugars. The key breakthrough is a proprietary catalyst that breakthrough is a proprietary catalyst that

149

Hydrogen Production and Dispensing Facility Opens at W. Va. Airport |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrogen Production and Dispensing Facility Opens at W. Va. Airport Hydrogen Production and Dispensing Facility Opens at W. Va. Airport Hydrogen Production and Dispensing Facility Opens at W. Va. Airport August 19, 2009 - 1:00pm Addthis Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Washington, D.C. -- A hydrogen production and dispensing station constructed and operated with support from the Office of Fossil Energy's National Energy Technology Laboratory (NETL) was officially opened Monday at the Yeager Airport in Charleston, W.Va. The facility is an example of how domestically produced fuels may be used to power a variety of vehicles

150

Market Potential of Electrolytic Hydrogen Production in Three Northeastern Utilities' Service Territories  

Science Conference Proceedings (OSTI)

Hydrogen produced by water electrolysis can be potentially cheaper than bottled industrial hydrogen. But in the Northeast, expensive electrolyzers, costly electricity, high interest rates, and excess hydrogen production capacity at existing plants make electrolytic hydrogen less attractive than bottled hydrogen.

1984-05-01T23:59:59.000Z

151

Autofermentative Biological Hydrogen Production by Cyanobacteria  

NLE Websites -- All DOE Office Websites (Extended Search)

BioSolarH BioSolarH 2  Autofermentative biological hydrogen production by cyanobacteria G.C. Dismukes Rutgers University Waksman Institute and Department of Chemistry & Chemical Biology DOE Biohydrogen Production Workshop NREL October, 2013 -BioSolarH 2  Ghirardi et al., 2007 Tamagnini et al., 2007 Soluble NiFe hydrogenase (SH) Group 5 AH in Ralstonia eutropha H16 Schäfer et al., 2013 Formate dehydrogenase Hydrogenase Bagramyan et al., 2003 Ferredoxin Km (MV) = 16.1µM Kcat (MV) = 1242 s -1 (Francis et al., 1990) K i (O 2 ) = 1% (McIntosh et al., 2011) Km (C 2 H 2 ) = 1.8*10 -3 atms (Hallenbeck et al. 1979) Km (H 2 ) =6.1µM Kcat (H 2 ) = 238 s -1 ( Schäfer et al., 2013) K i (O 2 ) = 47.5% (Lenz et al., 2010) Km (H 2 ) =3.5µM Kcat (H 2 ) = 0.5 s -1 ( Oxygen insensitive (Schäfer et al., 2013)

152

Hydrogen production from municipal solid waste  

DOE Green Energy (OSTI)

We have modified a Municipal Solid Waste (MSW) hydrothermal pretreatment pilot plant for batch operation and blowdown of the treated batch to low pressure. We have also assembled a slurry shearing pilot plant for particle size reduction. Waste paper and a mixture of waste paper/polyethylene plastic have been run in the pilot plant with a treatment temperature of 275{degrees}C. The pilot-plant products have been used for laboratory studies at LLNL. The hydrothermal/shearing pilot plants have produced acceptable slurries for gasification tests from a waste paper feedstock. Work is currently underway with combined paper/plastic feedstocks. When the assembly of the Research Gasification Unit at Texaco (feed capacity approximately 3/4-ton/day) is complete (4th quarter of FY96), gasification test runs will commence. Laboratory work on slurry samples during FY96 has provided correlations between slurry viscosity and hydrothermal treatment temperature, degree of shearing, and the presence of surfactants and admixed plastics. To date, pumpable slurries obtained from an MSW surrogate mixture of treated paper and plastic have shown heating values in the range 13-15 MJ/kg. Our process modeling has quantified the relationship between slurry heating value and hydrogen yield. LLNL has also performed a preliminary cost analysis of the process with the slurry heating value and the MSW tipping fee as parameters. This analysis has shown that the overall process with a 15 MJ/kg slurry gasifier feed can compete with coal-derived hydrogen with the assumption that the tipping fee is of the order $50/ton.

Wallman, P.H.; Richardson, J.H.; Thorsness, C.B. [and others

1996-06-28T23:59:59.000Z

153

NETL: News Release - Hydrogen Production and Dispensing Facility Opens at  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production and Dispensing Facility Opens at West Virginia Airport Hydrogen Production and Dispensing Facility Opens at West Virginia Airport Station Provides Transportation Fuel from Domestic Resources for Hydrogen-Fueled Vehicles Washington, D.C. - A hydrogen production and dispensing station constructed and operated with support from the Office of Fossil Energy's National Energy Technology Laboratory (NETL) was officially opened Monday at the Yeager Airport in Charleston, W.Va. The facility is an example of how domestically produced fuels may be used to power a variety of vehicles and equipment, lessening U.S. dependence on foreign oil. The facility will produce, compress, store and dispense hydrogen as a fuel source for vehicles that have been converted to run on hydrogen, as well as other types of ground equipment at the airport.

154

Process for the thermochemical production of hydrogen  

DOE Patents (OSTI)

Hydrogen is thermochemically produced from water in a cycle wherein a first reaction produces hydrogen iodide and H.sub.2 SO.sub.4 by the reaction of iodine, sulfur dioxide and water under conditions which cause two distinct aqueous phases to be formed, i.e., a lighter sulfuric acid-bearing phase and a heavier hydrogen iodide-bearing phase. After separation of the two phases, the heavier phase containing most of the hydrogen iodide is treated, e.g., at a high temperature, to decompose the hydrogen iodide and recover hydrogen and iodine. The H.sub.2 SO.sub.4 is pyrolyzed to recover sulfur dioxide and produce oxygen.

Norman, John H. (La Jolla, CA); Russell, Jr., John L. (La Jolla, CA); Porter, II, John T. (Del Mar, CA); McCorkle, Kenneth H. (Del Mar, CA); Roemer, Thomas S. (Cardiff, CA); Sharp, Robert (Del Mar, CA)

1978-01-01T23:59:59.000Z

155

PRODUCTION OF HYDROGEN BY SUPERADIABATIC DECOMPOSITION OF HYDROGEN SULFIDE  

E-Print Network (OSTI)

and the membrane systems selected, additional equipment such as knockout drums, coalescing filters, and guard beds far and modeling predictions is quite reasonable. Methane 20% H2S/ 80%N2 Air MFC MFC MFC Proceedings of the 2002 U.S. DOE Hydrogen Program Review NREL/CP-610-32405 #12;MFC-3 MFC-1 MFC-2 N2 H2S O2

156

Assessing Strategies for Fuel and Electricity Production in a California Hydrogen Economy  

E-Print Network (OSTI)

production of hydrogen, electricity and CO 2 from coal withproduction of hydrogen, electricity, and CO 2 from coal withDecarbonized hydrogen and electricity from natural gas.

McCarthy, Ryan; Yang, Christopher; Ogden, Joan M.

2008-01-01T23:59:59.000Z

157

Fermentative Approaches to Hydrogen Production (Presentation)  

DOE Green Energy (OSTI)

A PowerPoint presentation given as part of the 2005 Hydrogen Program Review, May 23-26, 2005, in Washington, D.C.

Maness, P. C.; Czernik, S.; Smolinski, S.

2005-05-01T23:59:59.000Z

158

Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review  

DOE Green Energy (OSTI)

This independent review is the conclusion arrived at from data collection, document reviews, interviews and deliberation from December 2010 through April 2011 and the technical potential of Hydrogen Production Cost Estimate Using Biomass Gasification. The Panel reviewed the current H2A case (Version 2.12, Case 01D) for hydrogen production via biomass gasification and identified four principal components of hydrogen levelized cost: CapEx; feedstock costs; project financing structure; efficiency/hydrogen yield. The panel reexamined the assumptions around these components and arrived at new estimates and approaches that better reflect the current technology and business environments.

Ruth, M.

2011-10-01T23:59:59.000Z

159

LARGE-SCALE PRODUCTION OF HYDROGEN BY NUCLEAR ENERGY FOR THE HYDROGEN ECONOMY  

DOE Green Energy (OSTI)

OAK B202 LARGE-SCALE PRODUCTION OF HYDROGEN BY NUCLEAR ENERGY FOR THE HYDROGEN ECONOMY. The ''Hydrogen Economy'' will reduce petroleum imports and greenhouse gas emissions. However, current commercial hydrogen production processes use fossil fuels and releases carbon dioxide. Hydrogen produced from nuclear energy could avoid these concerns. The authors have recently completed a three-year project for the US Department of Energy whose objective was to ''define an economically feasible concept for production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the energy source''. Thermochemical water-splitting, a chemical process that accomplishes the decomposition of water into hydrogen and oxygen, met this objective. The goal of the first phase of this study was to evaluate thermochemical processes which offer the potential for efficient, cost-effective, large-scale production of hydrogen and to select one for further detailed consideration. The authors selected the Sulfur-Iodine cycle, In the second phase, they reviewed all the basic reactor types for suitability to provide the high temperature heat needed by the selected thermochemical water splitting cycle and chose the helium gas-cooled reactor. In the third phase they designed the chemical flowsheet for the thermochemical process and estimated the efficiency and cost of the process and the projected cost of producing hydrogen. These results are summarized in this paper.

SCHULTZ,KR; BROWN,LC; BESENBRUCH,GE; HAMILTON,CJ

2003-02-01T23:59:59.000Z

160

Electrolytic production of hydrogen utilizing photovoltaic cells  

DOE Green Energy (OSTI)

Hydrogen has the potential to serve as both an energy storage means and an energy carrier in renewable energy systems. When renewable energy sources such as solar or wind power are used to produce electrical power, the output can vary depending on weather conditions. By using renewable sources to produce hydrogen, a fuel which can be stored and transported, a reliable and continuously available energy supply with a predictable long-term average output is created. Electrolysis is one method of converting renewable energy into hydrogen fuel. In this experiment we examine the use of an electrolyzer based on polymer-electrolyte membrane technology to separate water into hydrogen and oxygen. The oxygen is vented to the atmosphere and the hydrogen is stored in a small pressure vessel.

Daugherty, M.A.

1996-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Ionically Conducting Membranes for Hydrogen Production and Separation  

NLE Websites -- All DOE Office Websites (Extended Search)

IONICALLY CONDUCTING MEMBRANES IONICALLY CONDUCTING MEMBRANES FOR HYDROGEN PRODUCTION AND SEPARATION Presented by Tony Sammells Eltron Research Inc. Boulder, Colorado www.eltronresearch.com Presented at DOE Hydrogen Separations Workshop Arlington, Virginia September 8, 2004 ELTRON RESEARCH INC. TO BE DISCUSSED * Membranes for Hydrogen Production - Compositions - Feedstocks - Performance - Key Technical Hurdles * Membranes for Hydrogen Separation - Compositions - Ex Situ vs. In Situ WGS - Performance - Key Technical Hurdles ELTRON RESEARCH INC. OVERALL SCHEME FOR CONVERTING FEEDSTOCK TO HYDROGEN WITH SIMULTANEOUS CARBON DIOXIDE SEQUESTRATION Oxygen Transport Membrane Hydrogen Transport Membrane Natural Gas Coal Biomass Syngas CO/H 2 WGS H 2 O CO 2 /H 2 1618afs.dsf H 2 CO 2 ELTRON RESEARCH INC. INCENTIVES FOR OXYGEN TRANSPORT MEMBRANES FOR

162

NETL: News Release - NETL Building Hydrogen Production and Dispensing  

NLE Websites -- All DOE Office Websites (Extended Search)

5, 2009 5, 2009 NETL Building Hydrogen Production and Dispensing Facility at Yeager Airport Morgantown, WV- The Department of Energy's National Energy Technology Laboratory (NETL) today announced its plans to construct and operate a hydrogen fuel production-and-dispensing facility at the Yeager Airport in Charleston, W.Va. According to U.S. Senator Robert C. Byrd, D-W.Va., "This project is a great example of the wonderful potential of coal. Coal can produce hydrogen fuel, which can greatly reduce greenhouse gases and our need to import foreign oil. Coal is abundant and remarkably versatile - particularly hydrogen produced from coal through gasification or coal-based power used to split water that provides a secure source of hydrogen fuel that will compete with imported petroleum. I am very pleased to be involved in helping this new hydrogen facility in West Virginia become a reality."

163

Hydrogen production with coal using a pulverization device  

DOE Patents (OSTI)

A method for producing hydrogen from coal is described wherein high temperature steam is brought into contact with coal in a pulverizer or fluid energy mill for effecting a steam-carbon reaction to provide for the generation of gaseous hydrogen. The high temperature steam is utilized to drive the coal particles into violent particle-to-particle contact for comminuting the particulates and thereby increasing the surface area of the coal particles for enhancing the productivity of the hydrogen.

Paulson, Leland E. (Morgantown, WV)

1989-01-01T23:59:59.000Z

164

Process for the production of hydrogen from water  

DOE Patents (OSTI)

A method and device for the production of hydrogen from water and electricity using an active metal alloy. The active metal alloy reacts with water producing hydrogen and a metal hydroxide. The metal hydroxide is consumed, restoring the active metal alloy, by applying a voltage between the active metal alloy and the metal hydroxide. As the process is sustainable, only water and electricity is required to sustain the reaction generating hydrogen.

Miller, William E. (Naperville, IL); Maroni, Victor A. (Naperville, IL); Willit, James L. (Batavia, IL)

2010-05-25T23:59:59.000Z

165

Cost Analysis of a Concentrator Photovoltaic Hydrogen Production System  

SciTech Connect

The development of efficient, renewable methods of producing hydrogen are essential for the success of the hydrogen economy. Since the feedstock for electrolysis is water, there are no harmful pollutants emitted during the use of the fuel. Furthermore, it has become evident that concentrator photovoltaic (CPV) systems have a number of unique attributes that could shortcut the development process, and increase the efficiency of hydrogen production to a point where economics will then drive the commercial development to mass scale.

Thompson, J. R.; McConnell, R. D.; Mosleh, M.

2005-08-01T23:59:59.000Z

166

Electrolytic cells for hydrogen gas production  

SciTech Connect

An electrolytic cell bank is described comprising two end plate electrodes, a plurality of intermediate electrodes, a plurality of dielectric separators spaced between the electrodes to form electrolytic cell chambers, a plurality of gas separator diaphragms, alkaline electrolyte, manifolds for allowing off-gas withdrawal of hydrogen and oxygen and means for back-pressuring the exterior walls of each end plate to counter-balance pressures developed within the electrolytic cell chambers. The cell bank is utilized to convert water into its constituent gases of oxygen and hydrogen, and the cell bank is sufficiently large to commercially produce hydrogen at pressures equal to the pressures utilized in commercial gas transmission lines.

Hall, F.F.

1980-11-25T23:59:59.000Z

167

On-Board Hydrogen Gas Production System For Stirling Engines  

DOE Patents (OSTI)

A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated Stirling engine. The hydrogen gas may be generated by various techniques including electrolysis and stored by various means including the use of a metal hydride absorbing material. By controlling the temperature of the absorbing material, the stored hydrogen gas may be provided to the Stirling engine as needed. A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated Stirling engine. The hydrogen gas may be generated by various techniques including electrolysis and stored by various means including the use of a metal hydride absorbing material. By controlling the temperature of the absorbing material, the stored hydrogen gas may be provided to the Stirling engine as needed.

Johansson, Lennart N. (Ann Arbor, MI)

2004-06-29T23:59:59.000Z

168

Hydrogen production with coal using a pulverization device  

DOE Patents (OSTI)

The present invention relates generally to the production of gaseous hydrogen with carbonous materials in the presence of steam by the steam-carbon reaction, and more particularly to such generation of hydrogen by rapidly comminuting coal in the presence of high-temperature steam.

Paulson, L.E.

1986-12-12T23:59:59.000Z

169

Carbonate thermochemical cycle for the production of hydrogen  

DOE Patents (OSTI)

The present invention is directed to a thermochemical method for the production of hydrogen from water. The method includes reacting a multi-valent metal oxide, water and a carbonate to produce an alkali metal-multi-valent metal oxide compound, carbon dioxide, and hydrogen.

Collins, Jack L (Knoxville, TN); Dole, Leslie R (Knoxville, TN); Ferrada, Juan J (Knoxville, TN); Forsberg, Charles W (Oak Ridge, TN); Haire, Marvin J (Oak Ridge, TN); Hunt, Rodney D (Oak Ridge, TN); Lewis Jr., Benjamin E (Knoxville, TN); Wymer, Raymond G (Oak Ridge, TN)

2010-02-23T23:59:59.000Z

170

Evidence For The Production Of Slow Antiprotonic Hydrogen In Vacuum  

E-Print Network (OSTI)

We present evidence showing how antiprotonic hydrogen, the quasistable antiproton-proton (pbar-p) bound system, has been synthesized following the interaction of antiprotons with the hydrogen molecular ion (H2+) in a nested Penning trap environment. From a careful analysis of the spatial distributions of antiproton annihilation events, evidence is presented for antiprotonic hydrogen production with sub-eV kinetic energies in states around n=70, and with low angular momenta. The slow antiprotonic hydrogen may be studied using laser spectroscopic techniques.

N. Zurlo; M. Amoretti; C. Amsler; G. Bonomi; C. Carraro; C. L. Cesar; M. Charlton; M. Doser; A. Fontana; R. Funakoshi; P. Genova; R. S. Hayano; L. V. Jorgensen; A. Kellerbauer; V. Lagomarsino; R. Landua; E. Lodi Rizzini; M. Macr; N. Madsen; G. Manuzio; D. Mitchard; P. Montagna; L. G. Posada; H. Pruys; C. Regenfus; A. Rotondi; G. Testera; D. P. Van der Werf; A. Variola; L. Venturelli; Y. Yamazaki

2007-08-28T23:59:59.000Z

171

Hydrogen production from fusion reactors coupled with high temperature electrolysis  

DOE Green Energy (OSTI)

The decreasing availability of fossil fuels emphasizes the need to develop systems which will produce synthetic fuel to substitute for and complement the natural supply. An important first step in the synthesis of liquid and gaseous fuels is the production of hydrogen. Thermonuclear fusion offers an inexhaustible source of energy for the production of hydrogen from water. Processes which may be considered for this purpose include electrolysis, thermochemical decomposition or thermochemical-electrochemical hybrid cycles. Preliminary studies at Brookhaven indicate that high temperature electrolysis has the highest potential efficiency for production of hydrogen from fusion. Depending on design electric generation efficiencies of approximately 40 to 60 percent and hydrogen production efficiencies of approximately 50 to 70 percent are projected for fusion reactors using high temperature blankets.

Fillo, J A; Powell, J R; Steinberg, M

172

Technoeconomic Evaluation of Large-Scale Electrolytic Hydrogen Production Technologies  

Science Conference Proceedings (OSTI)

Large-scale production of electrolytic hydrogen and oxygen could increase use of baseload and off-peak surplus power. To be competitive, however, water electrolysis will require low-cost electricity.

1985-09-20T23:59:59.000Z

173

NGNP Process Heat Applications: Hydrogen Production Accomplishments for FY2010  

DOE Green Energy (OSTI)

This report summarizes FY10 accomplishments of the Next Generation Nuclear Plant (NGNP) Engineering Process Heat Applications group in support of hydrogen production technology development. This organization is responsible for systems needed to transfer high temperature heat from a high temperature gas-cooled reactor (HTGR) reactor (being developed by the INL NGNP Project) to electric power generation and to potential industrial applications including the production of hydrogen.

Charles V Park

2011-01-01T23:59:59.000Z

174

DOE Hydrogen and Fuel Cells Program Record 12014: Current U.S. Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

12014 Date: June 18, 2012 12014 Date: June 18, 2012 Title: Current U.S. Hydrogen Production Originator: Fred Joseck Approved by: Sunita Satyapal Date: June 26, 2012 Item: The United States currently produces about 9 million metric tons of hydrogen per year, enough to power approximately ~36-41 million FCEVs. References/Calculations:  "...9 million metric tons of hydrogen per year" The United States produces about 9 million metric tons per year for the captive and merchant markets. U.S. Hydrogen Production By Merchant & Captive Types 2009-2016 (Thousand Metric Tons) 1 Source: MarketsandMarkets, GLOBAL HYDROGEN GENERATION MARKET BY MERCHANT & CAPTIVE TYPE, DISTRIBUTED & CENTRALIZED GENERATION, APPLICATION & TECHNOLOGY - TRENDS &

175

Anode depolarizers in electrolytic hydrogen production  

SciTech Connect

Brookhaven National Laboratory manages an extensive program in the areas of hydrogen and energy storage potentials. As part of an ongoing portfolio analysis of projects, the prospects for applications for anode depolarizers are presented. The system requirements are outlined, and economic criteria are developed. It is concluded that moderate incentives exist for successful development. Research and Development priorities are formulated.

Beller, M.

1982-06-01T23:59:59.000Z

176

Electrolytic production of hydrogen. [from carbonaceous materials  

SciTech Connect

A cyclic electrolytic process is claimed for the manufacture of hydrogen from carbonaceous material such as coal, agricultural wastes and garbage to produce commercial hydrogen. An alakli metal sulfate is reduced to an alkali metal sulfide by reaction of the sulfate and carbonaceous fuel at an elevated temperature. The sulfide and impurities derived from the fuel are digested with an aqueous solution to dissolve the sulfide and separate out the impurities. The solution of the alkali sulfide is added to electrolytic cells in which an electric current is utilized to generate hydrogen at the cathode while oxidizing the sulfide substantially to sulfate at the anode. The cell electrolyte temperature is greater than 150/sup 0/C and less than 350/sup 0/C. Under these conditions the polarization problem encountered in hydrogen/oxygen cells is substantially avoided. The alkali sulfate is then separated from the electrolyte stream exiting from the electrolytic cells, reduced again by burning with fuel and recycled to the electrolytic cell.

Spitzer, R.

1978-03-28T23:59:59.000Z

177

Synergistic Hydrogen Production in a Biorefinery via Bioelectrochemical Systems  

Science Conference Proceedings (OSTI)

Microbial electrolysis cells are devices that use biocatalysis and electrolysis for production of hydrogen from organic matter. Biorefinery process streams contain fermentation by products and inhibitors which accumulate in the process stream if the water is recycled. These molecules also affect biomass to biofuel yields if not removed from the recycle water. The presence of sugar- and lignin- degradation products such as furfural, vanillic acid and 4-hydroxybenzaldehyde has been shown to reduce fermentation yields. In this work, we calculate the potential for hydrogen production using microbial electrolysis cells from these molecules as substrates. Conversion of these substrates to electricity is demonstrated in microbial fuel cells and will also be presented.

Borole, A. P.; Hamilton, C. Y.; Schell, D. J.

2012-01-01T23:59:59.000Z

178

Hydrogen: Production and marketing. Proceedings of the Symposium, Honolulu, Hawaii, April 2-6, 1979  

SciTech Connect

The studies included in this volume provide an overview of hydrogen research and development and examine the problems of industrial technology and economics of hydrogen production, commercial distribution and safety, the potential of advanced hydrogen technologies, and applications. Papers are presented on the hydrogen production from partial oxidation of residual fuel oil, coal gasification for hydrogen manufacture, production and application of electrolytic hydrogen, and hydrogen from fuel desulfurization.

Smith, W.N. (General Electric Co., Philadelphia, Pa.); Santangelo, J.G. (Air Products and Chemicals, Inc., Allentown, Pa.)

1980-01-01T23:59:59.000Z

179

Electrolytic hydrogen production infrastructure options evaluation. Final subcontract report  

DOE Green Energy (OSTI)

Fuel-cell electric vehicles have the potential to provide the range, acceleration, rapid refueling times, and other creature comforts associated with gasoline-powered vehicles, but with virtually no environmental degradation. To achieve this potential, society will have to develop the necessary infrastructure to supply hydrogen to the fuel-cell vehicles. Hydrogen could be stored directly on the vehicle, or it could be derived from methanol or other hydrocarbon fuels by on-board chemical reformation. This infrastructure analysis assumes high-pressure (5,000 psi) hydrogen on-board storage. This study evaluates one approach to providing hydrogen fuel: the electrolysis of water using off-peak electricity. Other contractors at Princeton University and Oak Ridge National Laboratory are investigating the feasibility of producing hydrogen by steam reforming natural gas, probably the least expensive hydrogen infrastructure alternative for large markets. Electrolytic hydrogen is a possible short-term transition strategy to provide relatively inexpensive hydrogen before there are enough fuel-cell vehicles to justify building large natural gas reforming facilities. In this study, the authors estimate the necessary price of off-peak electricity that would make electrolytic hydrogen costs competitive with gasoline on a per-mile basis, assuming that the electrolyzer systems are manufactured in relatively high volumes compared to current production. They then compare this off-peak electricity price goal with actual current utility residential prices across the US.

Thomas, C.E.; Kuhn, I.F. Jr. [Directed Technologies, Inc., Arlington, VA (United States)

1995-09-01T23:59:59.000Z

180

USE OF THE MODULAR HELIUM REACTOR FOR HYDROGEN PRODUCTION  

DOE Green Energy (OSTI)

OAK-B135 A significant ''Hydrogen Economy'' is predicted that will reduce our dependence on petroleum imports and reduce pollution and greenhouse gas emissions. Hydrogen is an environmentally attractive fuel that has the potential to displace fossil fuels, but contemporary hydrogen production is primarily based on fossil fuels. The author has recently completed a three-year project for the US Department of Energy (DOE) whose objective was to ''define an economically feasible concept for production of hydrogen, using an advanced high-temperature nuclear reactor as the energy source''. Thermochemical water-slitting, a chemical process that accomplishes the decomposition of water into hydrogen and oxygen, met this objective. The goal of the first phase of this study was to evaluate thermochemical processes which offer the potential for efficient, cost-effective, large-scale production of hydrogen, and to select one for further detailed consideration. They selected the Sulfur-Iodine cycle. In the second phase, they reviewed all the basic reactor types for suitability to provide the high temperature heat needed by the selected thermochemical water splitting cycle and chose the helium gas-cooled reactor. In the third phase they designed the chemical flowsheet for the thermochemical process and estimated the efficiency and cost of the process and the projected cost of producing hydrogen. These results are summarized in this report.

SCHULTZ,KR

2003-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Hydrogen production by the decomposition of water  

DOE Patents (OSTI)

How to produce hydrogen from water was a problem addressed by this invention. The solution employs a combined electrolytical-thermochemical sulfuric acid process. Additionally, high purity sulfuric acid can be produced in the process. Water and SO.sub.2 react in electrolyzer (12) so that hydrogen is produced at the cathode and sulfuric acid is produced at the anode. Then the sulfuric acid is reacted with a particular compound M.sub.r X.sub.s so as to form at least one water insoluble sulfate and at least one water insoluble oxide of molybdenum, tungsten, or boron. Water is removed by filtration; and the sulfate is decomposed in the presence of the oxide in sulfate decomposition zone (21), thus forming SO.sub.3 and reforming M.sub.r X.sub.s. The M.sub.r X.sub.s is recycled to sulfate formation zone (16). If desired, the SO.sub.3 can be decomposed to SO.sub.2 and O.sub.2 ; and the SO.sub.2 can be recycled to electrolyzer (12) to provide a cycle for producing hydrogen.

Hollabaugh, Charles M. (Los Alamos, NM); Bowman, Melvin G. (Los Alamos, NM)

1981-01-01T23:59:59.000Z

182

CERAMIC MEMBRANES FOR HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

The objective of this project is to develop ceramic membranes for hydrogen separation from fuel gas or synthesis gas at temperatures 400-500 C. The membrane chosen for this purpose consists of a dense silica layer coated on a porous support by chemical vapor depositrion (CVD). The support used during the reporting period was zeolite silicalite grown on macroporous alumina tubes. Chemical vapor deposition was carried out using alternating exposure of the support to silicon tetrachloride (SiCl{sub 4}) and water vapor at 400-500 C. Under these conditions it takes about twenty-five reaction cycles to narrow down the pores of the zeolite support sufficiently for separation of hydrogen from other gases. The membranes were characterized by gas adsorption for pore size distribution, scanning electron microscopy, and EDAX for elemental composition. The permeance of H{sub 2}, N{sub 2}, CO{sub 2}, n-C{sub 4}H{sub 10}, and i-C{sub 4}H{sub 10} was measured in the temperature range 100-250 C. At 150 C, the H{sub 2}:N{sub 2} permeance ratio was in the range 100-200 at a hydrogen permeance of 5-10x10{sup -8} mol/m{sub 2}-s-Pa.

George R. Gavalas

2003-03-18T23:59:59.000Z

183

NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation  

NLE Websites -- All DOE Office Websites (Extended Search)

Wind to Hydrogen Project: Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Hydrogen Technologies and Systems Center Todd Ramsden, Kevin Harrison, Darlene Steward November 16, 2009 NREL/PR-560-47432 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. NREL Wind2H2 RD&D Project * The National Renewable Energy Laboratory in partnership with Xcel Energy and DOE has designed, operates, and continues to perform testing on the wind-to-hydrogen (Wind2H2) project at the National Wind Technology Center in Boulder * The Wind2H2 project integrates wind turbines, PV arrays and electrolyzers to produce from renewable energy

184

Onboard Plasmatron Hydrogen Production for Improved Vehicles  

SciTech Connect

A plasmatron fuel reformer has been developed for onboard hydrogen generation for vehicular applications. These applications include hydrogen addition to spark-ignition internal combustion engines, NOx trap and diesel particulate filter (DPF) regeneration, and emissions reduction from spark ignition internal combustion engines First, a thermal plasmatron fuel reformer was developed. This plasmatron used an electric arc with relatively high power to reform fuels such as gasoline, diesel and biofuels at an oxygen to carbon ratio close to 1. The draw back of this device was that it has a high electric consumption and limited electrode lifetime due to the high temperature electric arc. A second generation plasmatron fuel reformer was developed. It used a low-current high-voltage electric discharge with a completely new electrode continuation. This design uses two cylindrical electrodes with a rotating discharge that produced low temperature volumetric cold plasma., The lifetime of the electrodes was no longer an issue and the device was tested on several fuels such as gasoline, diesel, and biofuels at different flow rates and different oxygen to carbon ratios. Hydrogen concentration and yields were measured for both the thermal and non-thermal plasmatron reformers for homogeneous (non-catalytic) and catalytic reforming of several fuels. The technology was licensed to an industrial auto part supplier (ArvinMeritor) and is being implemented for some of the applications listed above. The Plasmatron reformer has been successfully tested on a bus for NOx trap regeneration. The successful development of the plasmatron reformer and its implementation in commercial applications including transportation will bring several benefits to the nation. These benefits include the reduction of NOx emissions, improving engine efficiency and reducing the nation's oil consumption. The objective of this program has been to develop attractive applications of plasmatron fuel reformer technology for onboard applications in internal combustion engine vehicles using diesel, gasoline and biofuels. This included the reduction of NOx and particulate matter emissions from diesel engines using plasmatron reformer generated hydrogen-rich gas, conversion of ethanol and bio-oils into hydrogen rich gas, and the development of new concepts for the use of plasmatron fuel reformers for enablement of HCCI engines.

Daniel R. Cohn; Leslie Bromberg; Kamal Hadidi

2005-12-31T23:59:59.000Z

185

Onboard Plasmatron Hydrogen Production for Improved Vehicles  

DOE Green Energy (OSTI)

A plasmatron fuel reformer has been developed for onboard hydrogen generation for vehicular applications. These applications include hydrogen addition to spark-ignition internal combustion engines, NOx trap and diesel particulate filter (DPF) regeneration, and emissions reduction from spark ignition internal combustion engines First, a thermal plasmatron fuel reformer was developed. This plasmatron used an electric arc with relatively high power to reform fuels such as gasoline, diesel and biofuels at an oxygen to carbon ratio close to 1. The draw back of this device was that it has a high electric consumption and limited electrode lifetime due to the high temperature electric arc. A second generation plasmatron fuel reformer was developed. It used a low-current high-voltage electric discharge with a completely new electrode continuation. This design uses two cylindrical electrodes with a rotating discharge that produced low temperature volumetric cold plasma., The lifetime of the electrodes was no longer an issue and the device was tested on several fuels such as gasoline, diesel, and biofuels at different flow rates and different oxygen to carbon ratios. Hydrogen concentration and yields were measured for both the thermal and non-thermal plasmatron reformers for homogeneous (non-catalytic) and catalytic reforming of several fuels. The technology was licensed to an industrial auto part supplier (ArvinMeritor) and is being implemented for some of the applications listed above. The Plasmatron reformer has been successfully tested on a bus for NOx trap regeneration. The successful development of the plasmatron reformer and its implementation in commercial applications including transportation will bring several benefits to the nation. These benefits include the reduction of NOx emissions, improving engine efficiency and reducing the nation's oil consumption. The objective of this program has been to develop attractive applications of plasmatron fuel reformer technology for onboard applications in internal combustion engine vehicles using diesel, gasoline and biofuels. This included the reduction of NOx and particulate matter emissions from diesel engines using plasmatron reformer generated hydrogen-rich gas, conversion of ethanol and bio-oils into hydrogen rich gas, and the development of new concepts for the use of plasmatron fuel reformers for enablement of HCCI engines.

Daniel R. Cohn; Leslie Bromberg; Kamal Hadidi

2005-12-31T23:59:59.000Z

186

Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms  

DOE Patents (OSTI)

A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

2006-01-24T23:59:59.000Z

187

Hydrogen Production from Carbohydrates: A Mini-Review  

NLE Websites -- All DOE Office Websites (Extended Search)

8 8 Hydrogen Production from Carbohydrates: A Mini-Review Y.-H. Percival Zhang *,1,2,3 1 Department of Biological Systems Engineering, Virginia Tech, 210-A Seitz Hall, Blacksburg, VA 24061, USA 2 Institute for Critical Technology and Applied Science (ICTAS), Virginia Tech, Blacksburg, VA 24061, USA 3 DOE BioEnergy Science Center (BESC), Oak Ridge, TN 37831, USA * Tel: 540-231-7414. Fax: 540-231-7414. Email: ypzhang@vt.edu. The hydrogen economy promises a clean energy future featuring higher energy utilization ef ciency and fewer pollutants compared to liquid fuel/internal combustion engines. Hydrogen production from the enriched low-cost biomass carbohydrates would achieve nearly zero carbon emissions in a whole life cycle. In this book chapter, we present latest advances of hydrogen generation from biomass carbohydrates by chemical catalysis (e.g., gasi cation,

188

Analyzing the Levelized Cost of Centralized and Distributed Hydrogen Production Using the H2A Production Model, Version 2  

DOE Green Energy (OSTI)

Analysis of the levelized cost of producing hydrogen via different pathways using the National Renewable Energy Laboratory's H2A Hydrogen Production Model, Version 2.

Ramsden, T.; Steward, D.; Zuboy, J.

2009-09-01T23:59:59.000Z

189

Photosynthetic hydrogen and oxygen production by green algae  

SciTech Connect

An overview of photosynthetic hydrogen and oxygen production by green algae in the context of its potential as a renewable chemical feed stock and energy carrier is presented. Beginning with its discovery by Gaffron and Rubin in 1942, motivated by curiosity-driven laboratory research, studies were initiated in the early 1970s that focused on photosynthetic hydrogen production from an applied perspective. From a scientific and technical point of view, current research is focused on optimizing net thermodynamic conversion efficiencies represented by the Gibbs Free Energy of molecular hydrogen. The key research questions of maximizing hydrogen and oxygen production by light-activated water splitting in green algae are (1) removing the oxygen sensitivity of algal hydrogenases; (2) linearizing the light saturation curves of photosynthesis throughout the entire range of terrestrial solar irradiance--including the role of bicarbonate and carbon dioxide in optimization of photosynthetic electron transport and (3) the minimum number of light reactions that are required to split water to elemental hydrogen and oxygen. Each of these research topics is being actively addressed by the photobiological hydrogen research community.

Greenbaum, E.; Lee, J.W.

1997-12-31T23:59:59.000Z

190

EVermont Renewable Hydrogen Production and Transportation Fueling System  

DOE Green Energy (OSTI)

A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable transportation energy capable system. The prime energy for this project comes from an agreement with a wind turbine operator.

Garabedian, Harold T.

2008-03-30T23:59:59.000Z

191

Fuel Cell Technologies Office: Electrolysis Production of Hydrogen from  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings Wind and hydropower are currently being evaluated in the U.S. and abroad as electricity sources that could enable large volume production of renewable hydrogen for use in transportation and distributed power applications. To further explore this prospect the Fuel Cell Technologies Office, and the Wind and Hydropower Technologies Program at the Department of Energy held a workshop to bring together stakeholders from wind, hydropower, and the electrolysis industries on September 9-10, 2003. The main objectives of the workshop were to: 1) discuss with stakeholders their current activities related to hydrogen, 2) explore with industry opportunities for low-cost hydrogen production through integration between wind and hydropower, water electrolysis and the electricity grid, and 3) review and provide feedback on a current Department of Energy/National Renewable Energy Laboratory analysis efforts to study opportunities for wind electrolysis and other renewable electricity sources.

192

Engineering aspects of hydrogen production from photosynthetic bacteria  

DOE Green Energy (OSTI)

Certain photosynthetic bacteria (PSB), for example, Rhodopseudomonas capsulata, evolve hydrogen when placed in an anaerobic environment with light and a suitable organic substrate. An engineering effort to use such bacteria for large-scale hydrogen production from sunlight is described. A system to produce 28,000 m/sup 3//day (1 x 10/sup 6/ ft/sup 3//day) of hydrogen has been designed on a conceptual level and includes hydrogen cleanup, substrate storage, and waste disposal. The most critical component in the design is the solar bacterial reactor. Several designs were developed and analyzed. A large covered pond concept appears most attractive. Cost estimates for the designs show favorable economics.

Herlevich, A.; Karpuk, M.

1982-02-01T23:59:59.000Z

193

Hydrogen Production from the Next Generation Nuclear Plant  

DOE Green Energy (OSTI)

The Next Generation Nuclear Plant (NGNP) is a high temperature gas-cooled reactor that will be capable of producing hydrogen, electricity and/or high temperature process heat for industrial use. The project has initiated the conceptual design phase and when completed will demonstrate the viability of hydrogen generation using nuclear produced process heat. This paper explains how industry and the U.S. Government are cooperating to advance nuclear hydrogen technology. It also describes the issues being explored and the results of recent R&D including materials development and testing, thermal-fluids research, and systems analysis. The paper also describes the hydrogen production technologies being considered (including various thermochemical processes and high-temperature electrolysis).

M. Patterson; C. Park

2008-03-01T23:59:59.000Z

194

Designer proton-channel transgenic algae for photobiological hydrogen production  

DOE Patents (OSTI)

A designer proton-channel transgenic alga for photobiological hydrogen production that is specifically designed for production of molecular hydrogen (H.sub.2) through photosynthetic water splitting. The designer transgenic alga includes proton-conductive channels that are expressed to produce such uncoupler proteins in an amount sufficient to increase the algal H.sub.2 productivity. In one embodiment the designer proton-channel transgene is a nucleic acid construct (300) including a PCR forward primer (302), an externally inducible promoter (304), a transit targeting sequence (306), a designer proton-channel encoding sequence (308), a transcription and translation terminator (310), and a PCR reverse primer (312). In various embodiments, the designer proton-channel transgenic algae are used with a gas-separation system (500) and a gas-products-separation and utilization system (600) for photobiological H.sub.2 production.

Lee, James Weifu (Knoxville, TN)

2011-04-26T23:59:59.000Z

195

CERAMIC MEMBRANES FOR HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

The present project is devoted to developing hydrogen permselective silica membranes supported on composite supports to achieve high flux and selectivity. The supports consist of a thin zeolite silicalite layer coated on {alpha}-Al{sub 2}O{sub 3} tubes of mean pore size 1 {micro}m. The zeolite layer is grown by reaction in a suitable silicate solution at 95 C. After two or three reaction periods a layer of silicalite crystals about 20 {micro}m thick grows inside the pores of alumina. In addition to the zeolitic pores, this layer contains voids of a few nanometer diameter that remain between the crystals or between the crystals and the pore walls. The quality of the silicalite/alumina composites was evaluated by gas permeation measurements and by nitrogen adsorption and it was found that the residual voids were below 5 nm in diameter. Three techniques were investigated for chemical vapor deposition (CVD) of the silica layer on the silicalite/alumina composite support. The first was TEOS pyrolysis at approximately one millibar partial pressure and 650 C. After 8 h reaction the fluxes of hydrogen and nitrogen at ambient temperature had declined by a factor of approximately 100 indicating sealing of defects and zeolitic pores alike. The second CVD technique investigated was SiCl{sub 4} hydrolysis at 90 C. Deposition in this case was conducted in a series of cycles, each cycle comprising two half reactions, i.e. exposure to SiCl{sub 4} followed by exposure to water vapor. The deposition was interrupted every five cycles to measure the permeation properties of the nascent membrane at 120 C. After a few cycles the membrane pores were sealed, but the silica layer was not thermally stable when the temperature was raised to 400 C. In the third technique investigated, silica deposition was carried out by SiCl{sub 4} hydrolysis at 400 C, again in a sequence of half reaction cycles. After 15 cycles the membrane pores were well sealed by a layer stable to at least 400 C.

George R. Gavalas

2001-11-27T23:59:59.000Z

196

Status Production Energy Efficiency % 72 70 Storage, Compression, Dispensing Efficiency Total Hydrogen Costs Hydrogen Production Costs  

E-Print Network (OSTI)

By 2012, develop and demonstrate distributed reforming technology for producing hydrogen from bio-oil at $3.80/kilogram (kg) purified hydrogen. By 2011, develop a prototype that incorporates the key operations: bio-oil injection, catalytic autothermal reforming, water-gas shift, and hydrogen isolation. Develop the necessary understanding of process chemistry, bio-oil compositional effects, catalyst chemistry, and deactivation and regeneration strategy to form a basis for process definition for automated distributed reforming to meet the DOE targets. In Fiscal Year (FY) 2010, demonstrate the process of auto-thermal reforming of bio-oil including a longterm catalyst performance, yields of hydrogen, and mass balances. Using a bench-scale reactor system, demonstrate catalytic conversion consistent with $3.80/kg hydrogen.

Richard French; Michael Penev; Rick Farmer

2010-01-01T23:59:59.000Z

197

Photosynthetic Hydrogen and Oxygen Production by Green Algae  

SciTech Connect

Photosynthesis research at Oak Ridge National Laboratory is focused on hydrogen and oxygen production by green algae in the context of its potential as a renewable fuel and chemical feed stock. Beginning with its discovery by Gaffron and Rubin in 1942, motivated by curiosity-driven laboratory research, studies were initiated in the early 1970s that focused on photosynthetic hydrogen production from an applied perspective. From a scientific and technical point of view, current research is focused on optimizing net thermodynamic conversion efficiencies represented by the Gibbs Free Energy of molecular hydrogen. The key research questions of maximizing hydrogen and oxygen production by light-activated water splitting in green algae are: (1) removing the oxygen sensitivity of algal hydrogenases; (2) linearizing the light saturation curves of hotosynthesis throughout the entire range of terrestrial solar irradiance-including the role of bicarbonate and carbon dioxide in optimization of photosynthetic electron transpor;t and (3) constructing real-world bioreactors, including the generation of hydrogen and oxygen against workable back pressures of the photoproduced gases.

Greenbaum, E.; Lee, J.W.

1999-08-22T23:59:59.000Z

198

Hydrogen (H2) Production by Oxygenic Phototrophs  

NLE Websites -- All DOE Office Websites (Extended Search)

Production by Oxygenic Phototrophs Eric L. Hegg Michigan State University Great Lakes Bioenergy Research Center Bioresour. Technol. 2011, 102, 8589-8604 Major Challenges to H 2 Photoproduction Biological Challenges * Poor efficiency of H 2 production * Poor heterologous expression of H 2 -forming enzymes * Low quantum yields * Competition for reducing equivalents; poor electron coupling * Sensitivity of H 2 -forming enzymes to O 2 M. Ghirardi, Abstract #1751, Honolulu PRiME 2012 Technical Challenges * Mixture of H 2 and O 2 ; H 2 separation and storage * CO 2 addition and overall reactor design Overcoming Low Efficiency: Improving ET * Eliminate or down-regulate pathways competing for ele * Production of organic acids * Formation of NADPH/carbon fixation

199

Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production Cost Estimate Hydrogen Production Cost Estimate Using Biomass Gasification National Renewable Energy Laboratory 1617 Cole Boulevard * Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Contract No. DE-AC36-08GO28308 Independent Review Published for the U.S. Department of Energy Hydrogen and Fuel Cells Program NREL/BK-6A10-51726 October 2011 NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or

200

Catalytic carbon membranes for hydrogen production. Final report  

DOE Green Energy (OSTI)

Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC)

Damle, A.S.; Gangwal, S.K.

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

CAPITAL AND OPERATING COST OF HYDROGEN PRODUCTION FROM COAL GASIFICATION  

NLE Websites -- All DOE Office Websites (Extended Search)

CAPITAL AND OPERATING COST OF HYDROGEN CAPITAL AND OPERATING COST OF HYDROGEN PRODUCTION FROM COAL GASIFICATION Final Report April 2003 Prepared for: The United States Department of Energy National Energy Technology Laboratory (NETL) under: Contract No. DE-AM26-99FT40465 between the NETL and Concurrent Technologies Corporation (CTC) Subcontract No. 990700362 between CTC and Parsons Infrastructure & Technology Group Inc. Task 50611 DOE Task Managers: James R. Longanbach Gary J. Stiegel Parsons Project Manager: Michael D. Rutkowski Principal Investigators: Thomas L. Buchanan Michael G. Klett Ronald L. Schoff PARSONS Capital and Operating Cost of Hydrogen Production from Coal Gasification Page i April 2003 TABLE OF CONTENTS Section Title Page List of Tables iii List of Figures iii

202

CERAMIC MEMBRANES FOR HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

The preparation and performance of membranes for application to hydrogen separation from coal-derived gas is described. The membrane material investigated was dense amorphous silica deposited on a suitable support by chemical vapor deposition (CVD). Two types of support materials were pursued. One type consisted of a two-layer composite, zeolite silicalite/{alpha}-Al{sub 2}O{sub 3}, in the form of tubes approximately 0.7 cm in diameter. The other type was porous glass tubes of diameter below 0.2 cm. The first type of support was prepared starting from {alpha}-Al{sub 2}O{sub 3} tubes of 1{micro}m mean pore diameter and growing by hydrothermal reaction a zeolite silicalite layer inside the pores of the alumina at the OD side. After calcination to remove the organic template used in the hydrothermal reaction, CVD was carried out to deposit the final silica layer. CVD was carried out by alternating exposure of the surface with silicon tetrachloride and water vapor. SEM and N2 adsorption measurements were employed to characterize the membranes at several stages during their preparation. Permeation measurements of several gases yielded H{sub 2}:N{sub 2} ideal selectivity of 150-200 at room temperature declining to 110 at 250 C. The second type of support pursued was porous glass tubes prepared by a novel extrusion technique. A thick suspension of borosilicate glass powder in a polyethersulfone solution was extruded through a spinneret and after gelation the glass-polymer tube was heat treated to obtain a gas-tight glass tube. Leaching of the glass tube in hot water yielded connected pores with diameter on the order of 100 nm. CVD of the final silica layer was not carried out on these tubes on account of their large pore size.

George R. Gavalas

2004-04-01T23:59:59.000Z

203

Bio-hydrogen production from renewable organic wastes  

DOE Green Energy (OSTI)

Methane fermentation has been in practice over a century for the stabilization of high strength organic waste/wastewater. Although methanogenesis is a well established process and methane--the end-product of methanogenesis is a useful energy source; it is a low value end product with relatively less energy content (about 56 kJ energy/g CH{sub 4}). Besides, methane and its combustion by-product are powerful greenhouse gases, and responsible for global climate change. So there is a pressing need to explore alternative environmental technologies that not only stabilize the waste/wastewater but also generate benign high value end products. From this perspective, anaerobic bioconversion of organic wastes to hydrogen gas is an attractive option that achieves both goals. From energy security stand point, generation of hydrogen energy from renewable organic waste/wastewater could substitute non-renewable fossil fuels, over two-third of which is imported from politically unstable countries. Thus, biological hydrogen production from renewable organic waste through dark fermentation represents a critically important area of bioenergy production. This study evaluated both process engineering and microbial physiology of biohydrogen production.

Shihwu Sung

2004-04-30T23:59:59.000Z

204

DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program Integrated Hydrogen Production, Purification and Compression System  

Science Conference Proceedings (OSTI)

The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of learning and demonstrate at a commercial site; and Task 4: Complete final product design for mass manufacturing units capable of achieving DOE 2010 H2 cost and performance targets.

Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

2011-06-30T23:59:59.000Z

205

Hydrogen production from high temperature electrolysis and fusion reactor  

SciTech Connect

Production of hydrogen from high temperature electrolysis of steam coupled with a fusion reactor is studied. The process includes three major components: the fusion reactor, the high temperature electrolyzer and the power conversion cycle each of which is discussed in the paper. Detailed process design and analysis of the system is examined. A parametric study on the effect of process efficiency is presented.

Dang, V.D.; Steinberg, J.F.; Issacs, H.S.; Lazareth, O.; Powell, J.R.; Salzano, F.J.

1978-01-01T23:59:59.000Z

206

Simulation of Hydrogen Production from Biomass Catalytic Gasification  

Science Conference Proceedings (OSTI)

In this study, biomass catalytic gasification process for producing H2-rich gas was presented. The process consists of mainly two fluidized bedsa gasifier and a CaO regenerator. The objective of this research is to develop a computer model of ... Keywords: biomass gasification, hydrogen production, Aspen Plus

Shan Cheng; Qian Wang; Hengsong Ji

2010-12-01T23:59:59.000Z

207

DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program Integrated Hydrogen Production, Purification and Compression System  

SciTech Connect

The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of <$1.50/gge, which was later revised by DOE to $2-$3/gge range for hydrogen to be competitive with gasoline as a fuel for vehicles. For small, on-site hydrogen plants being evaluated at the time for refueling stations (the 'forecourt'), it was determined that capital cost is the main contributor to the high cost of delivered hydrogen. The concept of this project was to reduce the cost by combining unit operations for the entire generation, purification, and compression system (refer to Figure 1). To accomplish this, the Fluid Bed Membrane Reactor (FBMR) developed by MRT was used. The FBMR has hydrogen selective, palladium-alloy membrane modules immersed in the reformer vessel, thereby directly producing high purity hydrogen in a single step. The continuous removal of pure hydrogen from the reformer pushes the equilibrium 'forward', thereby maximizing the productivity with an associated reduction in the cost of product hydrogen. Additional gains were envisaged by the integration of the novel Metal Hydride Hydrogen Compressor (MHC) developed by Ergenics, which compresses hydrogen from 0.5 bar (7 psia) to 350 bar (5,076 psia) or higher in a single unit using thermal energy. Excess energy from the reformer provides up to 25% of the power used for driving the hydride compressor so that system integration improved efficiency. Hydrogen from the membrane reformer is of very high, fuel cell vehicle (FCV) quality (purity over 99.99%), eliminating the need for a separate purification step. The hydride compressor maintains hydrogen purity because it does not have dynamic seals or lubricating oil. The project team set out to integrate the membrane reformer developed by MRT and the hydride compression system developed by Ergenics in a single package. This was expected to result in lower cost and higher efficiency compared to conventional hydrogen production technologies. The overall objective was to develop an integrated system to directly produce high pressure, high-purity hydrogen from a single unit, which can meet the DOE cost H2 cost target of $2 - $3/gge when mass produced. The project was divided into two phases with the following tasks and corresponding milestones, targets and decision points. Phase 1 - Task 1 - Verify feasibility of the concept, perform a detailed techno-economic analysis, and develop a test plan; and Task 2: Build and experimentally test a Proof of Concept (POC) integrated membrane reformer/metal hydride compressor system. Phase 2 - Task 3: Build an Advanced Prototype (AP) system with modifications based on POC learning and demonstrate at a commercial site; and Task 4: Complete final product design for mass manufacturing units capable of achieving DOE 2010 H2 cost and performance targets.

Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

2011-06-30T23:59:59.000Z

208

A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

Gas Technology Institute is developing a novel concept of membrane gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying the potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. To evaluate the candidate membrane performance under the gasification conditions, a high temperature/high pressure hydrogen permeation unit will be constructed in this project. During this reporting period, the design of this unit was completed. The unit will be capable of operating at temperatures up to 1100 C and pressures to 60 atm for evaluation of ceramic membranes such as mixed ionic conducting membrane. The membranes to be tested will be in disc form with a diameter of about 3 cm. By operating at higher temperatures and higher hydrogen partial pressures, we expect to demonstrate commercially relevant hydrogen flux, 10 {approx} 50 cc/min/cm{sup 2}, from the membranes made of the perovskite type of ceramic material. The construction of the unit is planned to be completed by the end of the next reporting period.

Shain Doong; Estela Ong; Mike Atroshenko; Francis Lau; Mike Roberts

2004-01-22T23:59:59.000Z

209

Lighting Up Enzymes for Solar Hydrogen Production (Fact Sheet)  

DOE Green Energy (OSTI)

Scientists at the National Renewable Energy Laboratory (NREL) have combined quantum dots, which are spherical nanoparticles that possess unique size-tunable photophysical properties, with the high substrate selectivity and fast turnover of hydrogenase enzymes to achieve light-driven hydrogen (H2) production. They found that quantum dots of cadmium telluride coated in carboxylic acids easily formed highly stable complexes with the hydrogenase and that these hybrid assemblies functioned to catalyze H2 production using the energy of sunlight.

Not Available

2011-02-01T23:59:59.000Z

210

Hydrogen production from fusion reactors coupled with high temperature electrolysis  

SciTech Connect

An initial study was conducted on a fusion reactor and high temperature electrolyzer system for the production of synthetic fuel. The design temperatures in the fusion reactor blanket were above 1380/sup 0/C. Electrolytic hydrogen production at the high temperatures consumes a high ratio of thermal to electric energy and increases the efficiency of the plant and an overall efficiency of approximately 50% appeared possible. The concepts of the system and the design considerations of the high temperature electrolyzer will be presented.

Isaacs, H.S.; Fillo, J.A.; Dang, V.; Powell, J.R.; Steinberg, M.; Salzano, F.; Benenati, R.

1978-01-01T23:59:59.000Z

211

Photobiological production of hydrogen: a solar energy conversion option  

DOE Green Energy (OSTI)

This literature survey of photobiological hydrogen production covers the period from its discovery in relatively pure cultures during the early 1930s to the present. The focus is hydrogen production by phototrophic organisms (and their components) which occurs at the expense of light energy and electron-donating substrates. The survey covers the major contributions in the area; however, in many cases, space has limited the degree of detail provided. Among the topics included is a brief historical overview of hydrogen metabolism in photosynthetic bacteria, eucaryotic algae, and cyanobacteria (blue--green algae). The primary enzyme systems, including hydrogenase and nitrogenase, are discussed along with the manner in which they are coupled to electron transport and the primary photochemistry of photosynthesis. A number of in vivo and in vitro photobiological hydrogen evolving schemes including photosynthetic bacterial, green algal, cyanobacterial, two-stage, and cell-free systems are examined in some detail. The remainder of the review discusses specific technical problem areas that currently limit the yield and duration of many of the systems and research that might lead to progress in these specific areas. The final section outlines, in broadest terms, future research directions necessary to develop practical photobiological hydrogen-producing systems. Both whole cell (near- to mid-term) and cell-free (long-term) systems should be emphasized. Photosynthetic bacteria currently show the most promise for near-term applied systems.

Weaver, P.; Lien, S.; Seibert, M.

1979-01-01T23:59:59.000Z

212

A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

Gas Technology Institute is developing a novel concept of membrane gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal-derived synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. To evaluate the performances of the candidate membranes under the gasification conditions, a high temperature/high pressure hydrogen permeation unit has been constructed in this project. During this reporting period, the unit has been fully commissioned and is operational. The unit is capable of operating at temperatures up to 1100 C and pressures to 60 atm for evaluation of ceramic membranes such as mixed ionic conducting membrane. A double-seal technique has been developed and tested successfully to achieve leak-tight seal for the membranes. Initial data for a commercial Palladium-Gold membrane were obtained at temperatures to 450 C and pressures to 13 atm. Tests for the perovskite membranes are being performed and the results will be reported in the next quarter. A membrane gasification reactor model was developed to consider the H{sub 2} permeability of the membrane, the kinetics and the equilibriums of the gas phase reactions in the gasifier, the operating conditions and the configurations of the membrane reactor. The results show that the hydrogen production efficiency using the novel membrane gasification reactor concept can be increased by about 50% versus the conventional gasification process. This confirms the previous evaluation results from the thermodynamic equilibrium calculation. A rigorous model for hydrogen permeation through mixed proton-electron conducting ceramic membranes was also developed based on non-equilibrium thermodynamics. The results from the simulation work confirm that the hydrogen flux increases with increasing partial pressure of hydrogen. The presence of steam in the permeate side can have a small negative effect on the hydrogen flux, in the order of 10%. When the steam partial pressure is greater than 1 atm, the hydrogen flux becomes independent of the steam pressure.

Shain Doong; Estela Ong; Mike Atroshenko; Francis Lau; Mike Roberts

2004-07-29T23:59:59.000Z

213

Co-production of Hydrogen and Electricity (A Developer's Perspective)  

NLE Websites -- All DOE Office Websites (Extended Search)

Co-production of Hydrogen and Electricity (A Developer's Perspective) Pinakin Patel FuelCell Energy, Inc. Transportation and Stationary Power Integration Workshop Fuel Cell Seminar 2008 Phoenix, AZ October 27, 2008 reliable, efficient, ultra-clean Presentation Outline * FuelCell Energy Overview * Direct Fuel Cell (DFC) Technology Status * Hydrogen Co-production Technology, Benefits and Status * Strategic Input for the DOE Workshop FCE Overview * Leading fuel cell developer for over 30 years - MCFC, SOFC, PAFC and PEM (up to 2 MW size products) - Over 230 million kWh of clean power produced world-wide (>60 installations) - Renewable fuels: over two dozen sites with ADG fuel - Ultra-clean technology: CARB-2007 certified Danbury, CT * Highly innovative approach to fuel cell development

214

Radiolytic hydrogen production from process vessels in HB line - production rates compared to evolution rates and discussion of LASL reviews  

DOE Green Energy (OSTI)

Hydrogen production from radiolysis of aqueous solutions can create a safety hazard since hydrogen is flammable. At times this production can be significant, especially in HB line where nitric acid solutions containing high concentrations of Pu-238, an intense alpha emitter, are processed. The hydrogen production rates from these solutions are necessary for safety analyses of these process systems. The methods and conclusions of hydrogen production rate tests are provided in this report.

Bibler, N.E.

1992-11-12T23:59:59.000Z

215

Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels  

DOE Green Energy (OSTI)

The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

University of Central Florida

2004-01-30T23:59:59.000Z

216

Solar-thermochemical production of hydrogen from water  

SciTech Connect

There is a widespread interest in the development of a ''hydrogen economy'' as an eventual solution to many of the problems associated with the growing energy crisis. Hydrogen is also valuable as a chemical intermediate. As fossil sources become inadequate, large scale hydrogen production must utilize energy sources such as solar energy for the decomposition of water by thermochemical cycles, electrolysis or perhaps, by a hybrid combination of these methods. The potential higher efficiency and lower cost for thermochemical methods, versus the overall electrolysis path has been rather widely recognized. The criteria for the selection of an appropriate thermochemical cycle for matching with a high temperature solar heat source are detailed. Advantages of a thermochemical cycle based on a solid sulfate decomposition that makes use of isothrmal high temperature energy is detailed and a plan for the implementation of such a cycle on a central tower solar receiver is given.

Cox, K.E.; Bowman, M.G.

1978-01-01T23:59:59.000Z

217

Dynamic Simulation and Optimization of Nuclear Hydrogen Production Systems  

DOE Green Energy (OSTI)

This project is part of a research effort to design a hydrogen plant and its interface with a nuclear reactor. This project developed a dynamic modeling, simulation and optimization environment for nuclear hydrogen production systems. A hybrid discrete/continuous model captures both the continuous dynamics of the nuclear plant, the hydrogen plant, and their interface, along with discrete events such as major upsets. This hybrid model makes us of accurate thermodynamic sub-models for the description of phase and reaction equilibria in the thermochemical reactor. Use of the detailed thermodynamic models will allow researchers to examine the process in detail and have confidence in the accurary of the property package they use.

Paul I. Barton; Mujid S. Kaximi; Georgios Bollas; Patricio Ramirez Munoz

2009-07-31T23:59:59.000Z

218

Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants  

DOE Green Energy (OSTI)

Cooperative Agreement DE-FC07-06ID14788 was executed between the U.S. Department of Energy, Electric Transportation Applications, and Idaho National Laboratory to investigate the economics of producing hydrogen by electrolysis using electricity generated by nuclear power. The work under this agreement is divided into the following four tasks: Task 1 Produce Data and Analyses Task 2 Economic Analysis of Large-Scale Alkaline Electrolysis Task 3 Commercial-Scale Hydrogen Production Task 4 Disseminate Data and Analyses. Reports exist on the prospect that utility companies may benefit from having the option to produce electricity or produce hydrogen, depending on market conditions for both. This study advances that discussion in the affirmative by providing data and suggesting further areas of study. While some reports have identified issues related to licensing hydrogen plants with nuclear plants, this study provides more specifics and could be a resource guide for further study and clarifications. At the same time, this report identifies other area of risks and uncertainties associated with hydrogen production on this scale. Suggestions for further study in some of these topics, including water availability, are included in the report. The goals and objectives of the original project description have been met. Lack of industry design for proton exchange membrane electrolysis hydrogen production facilities of this magnitude was a roadblock for a significant period. However, recent design breakthroughs have made costing this facility much more accurate. In fact, the new design information on proton exchange membrane electrolyzers scaled to the 1 kg of hydrogen per second electrolyzer reduced the model costs from $500 to $100 million. Task 1 was delayed when the original electrolyzer failed at the end of its economic life. However, additional valuable information was obtained when the new electrolyzer was installed. Products developed during this study include a process model and a N2H2 economic assessment model (both developed by the Idaho National Laboratory). Both models are described in this report. The N2H2 model closely tracked and provided similar results as the H2A model and was instrumental in assessing the effects of plant availability on price when operated in the shoulder mode for electrical pricing. Differences between the H2A and N2H2 model are included in this report.

Stephen Schey

2009-07-01T23:59:59.000Z

219

Photoelectrochemical Hydrogen Production Using New Combinatorial Chemistry Derived Materials  

DOE Green Energy (OSTI)

Solar photoelectrochemical water-splitting has long been viewed as one of the holy grails of chemistry because of its potential impact as a clean, renewable method of fuel production. Several known photocatalytic semiconductors can be used; however, the fundamental mechanisms of the process remain poorly understood and no known material has the required properties for cost effective hydrogen production. In order to investigate morphological and compositional variations in metal oxides as they relate to opto-electrochemical properties, we have employed a combinatorial methodology using automated, high-throughput, electrochemical synthesis and screening together with conventional solid-state methods. This report discusses a number of novel, high-throughput instruments developed during this project for the expeditious discovery of improved materials for photoelectrochemical hydrogen production. Also described within this report are results from a variety of materials (primarily tungsten oxide, zinc oxide, molybdenum oxide, copper oxide and titanium dioxide) whose properties were modified and improved by either layering, inter-mixing, or doping with one or more transition metals. Furthermore, the morphologies of certain materials were also modified through the use of structure directing agents (SDA) during synthesis to create mesostructures (features 2-50 nm) that increased surface area and improved rates of hydrogen production.

Jaramillo, Thomas F.; Baeck, Sung-Hyeon; Kleiman-Shwarsctein, Alan; Stucky, Galen D. (PI); McFarland, Eric W. (PI)

2004-10-25T23:59:59.000Z

220

The Hybrid Sulfur Cycle for Nuclear Hydrogen Production  

DOE Green Energy (OSTI)

Two Sulfur-based cycles--the Sulfur-Iodine (SI) and the Hybrid Sulfur (HyS)--have emerged as the leading thermochemical water-splitting processes for producing hydrogen utilizing the heat from advanced nuclear reactors. Numerous international efforts have been underway for several years to develop the SI Cycle, but development of the HyS Cycle has lagged. The purpose of this paper is to discuss the background, current status, recent development results, and the future potential for this thermochemical process. Savannah River National Laboratory (SRNL) has been supported by the U.S. Department of Energy Office of Nuclear Energy, Science, and Technology since 2004 to evaluate and to conduct research and development for the HyS Cycle. Process design studies and flowsheet optimization have shown that an overall plant efficiency (based on nuclear heat converted to hydrogen product, higher heating value basis) of over 50% is possible with this cycle. Economic studies indicate that a nuclear hydrogen plant based on this process can be economically competitive, assuming that the key component, the sulfur dioxide-depolarized electrolyzer, can be successfully developed. SRNL has recently demonstrated the use of a proton-exchange-membrane electrochemical cell to perform this function, thus holding promise for economical and efficient hydrogen production.

Summers, William A.; Gorensek, Maximilian B.; Buckner, Melvin R.

2005-09-08T23:59:59.000Z

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221

Assessment of methods for hydrogen production using concentrated solar energy  

DOE Green Energy (OSTI)

The purpose of this work was to assess methods for hydrogen production using concentrated solar energy. The results of this work can be used to guide future work in the application of concentrated solar energy to hydrogen production. Specifically, the objectives were to: (1) determine the cost of hydrogen produced from methods that use concentrated solar thermal energy, (2) compare these costs to those of hydrogen produced by electrolysis using photovoltaics and wind energy as the electricity source. This project had the following scope of work: (1) perform cost analysis on ambient temperature electrolysis using the 10 MWe dish-Stirling and 200 MWe power tower technologies; for each technology, sue two cases for projected costs, years 2010 and 2020 the dish-Stirling system, years 2010 and 2020 for the power tower, (2) perform cost analysis on high temperature electrolysis using the 200 MWe power tower technology and projected costs for the year 2020, and (3) identify and describe the key technical issues for high temperature thermal dissociation and the thermochemical cycles.

Glatzmaier, G. [Peak Design, Evergreen, CO (United States); Blake, D. [National Renewable Energy Lab., Golden, CO (United States); Showalter, S. [Sandia National Lab., Albuquerque, NM (United States)

1998-01-01T23:59:59.000Z

222

Low-Cost Hydrogen Distributed Production System Development  

DOE Green Energy (OSTI)

H{sub 2}Gen, with the support of the Department of Energy, successfully designed, built and field-tested two steam methane reformers with 578 kg/day capacity, which has now become a standard commercial product serving customers in the specialty metals and PV manufacturing businesses. We demonstrated that this reformer/PSA system, when combined with compression, storage and dispensing (CSD) equipment could produce hydrogen that is already cost-competitive with gasoline per mile driven in a conventional (non-hybrid) vehicle. We further showed that mass producing this 578 kg/day system in quantities of just 100 units would reduce hydrogen cost per mile approximately 13% below the cost of untaxed gasoline per mile used in a hybrid electric vehicle. If mass produced in quantities of 500 units, hydrogen cost per mile in a FCEV would be 20% below the cost of untaxed gasoline in an HEV in the 2015-2020 time period using EIA fuel cost projections for natural gas and untaxed gasoline, and 45% below the cost of untaxed gasoline in a conventional car. This 20% to 45% reduction in fuel cost per mile would accrue even though hydrogen from this 578 kg/day system would cost approximately $4.14/kg, well above the DOE hydrogen cost targets of $2.50/kg by 2010 and $2.00/kg by 2015. We also estimated the cost of a larger, 1,500 kg/day SMR/PSA fueling system based on engineering cost scaling factors derived from the two H{sub 2}Gen products, a commercial 115 kg/day system and the 578 kg/day system developed under this DOE contract. This proposed system could support 200 to 250 cars per day, similar to a medium gasoline station. We estimate that the cost per mile from this larger 1,500 kg/day hydrogen fueling system would be 26% to 40% below the cost per mile of untaxed gasoline in an HEV and ICV respectively, even without any mass production cost reductions. In quantities of 500 units, we are projecting per mile cost reductions between 45% (vs. HEVs) and 62% (vs ICVs), with hydrogen costing approximately $2.87/kg, still above the DOE's 2010 $2.50/kg target. We also began laboratory testing of reforming ethanol, which we showed is currently the least expensive approach to making renewable hydrogen. Extended testing of neat ethanol in micro-reactors was successful, and we also were able to reform E-85 acquired from a local fueling station for 2,700 hours, although some modifications were required to handle the 15% gasoline present in E-85. We began initial tests of a catalyst-coated wall reformer tube that showed some promise in reducing the propensity to coke with E-85. These coated-wall tests ran for 350 hours. Additional resources would be required to commercialize an ethanol reformer operating on E-85, but there is no market for such a product at this time, so this ethanol reformer project was moth-balled pending future government or industry support. The two main objectives of this project were: (1) to design, build and test a steam methane reformer and pressure swing adsorption system that, if scaled up and mass produced, could potentially meet the DOE 2015 cost and efficiency targets for on-site distributed hydrogen generation, and (2) to demonstrate the efficacy of a low-cost renewable hydrogen generation system based on reforming ethanol to hydrogen at the fueling station.

C.E. (Sandy) Thomas, Ph.D., President; Principal Investigator, and

2011-03-10T23:59:59.000Z

223

Hydrogen Production via a Commerically Ready Inorganic membrane Reactor  

DOE Green Energy (OSTI)

It has been known that use of the hydrogen selective membrane as a reactor (MR) could potentially improve the efficiency of the water shift reaction (WGS), one of the least efficient unit operations for production of high purity hydrogen from syngas. However, no membrane reactor technology has been reduced to industrial practice thus far, in particular for a large-scale operation. This implementation and commercialization barrier is attributed to the lack of a commercially viable hydrogen selective membrane with (1) material stability under the application environment and (2) suitability for large-scale operation. Thus, in this project, we have focused on (1) the deposition of the hydrogen selective carbon molecular sieve (CMS) membrane we have developed on commercially available membranes as substrate, and (2) the demonstration of the economic viability of the proposed WGS-MR for hydrogen production from coal-based syngas. The commercial stainless steel (SS) porous substrate (i.e., ZrO{sub 2}/SS from Pall Corp.) was evaluated comprehensively as the 1st choice for the deposition of the CMS membrane for hydrogen separation. The CMS membrane synthesis protocol we developed previously for the ceramic substrate was adapted here for the stainless steel substrate. Unfortunately no successful hydrogen selective membranes had been prepared during Yr I of this project. The characterization results indicated two major sources of defect present in the SS substrate, which may have contributed to the poor CMS membrane quality. Near the end of the project period, an improved batch of the SS substrate (as the 2nd generation product) was received from the supplier. Our characterization results confirm that leaking of the crimp boundary no longer exists. However, the thermal stability of the ZrO{sub 2}/SS substrate through the CMS membrane preparation condition must be re-evaluated in the future. In parallel with the SS membrane activity, the preparation of the CMS membranes supported on our commercial ceramic membrane for large-scale applications, such as coal-based power generation/hydrogen production, was also continued. A significant number (i.e., 98) of full-scale membrane tubes have been produced with an on-spec ratio of >76% during the first production trial. In addition, we have verified the functional performance and material stability of this hydrogen selective CMS membrane with a hydrocracker purge gas stream at a refinery pilot testing facility. No change in membrane performance was noted over the >100 hrs of testing conducted in the presence of >30% H{sub 2}S, >5,000 ppm NH{sub 3} (estimated), and heavy hydrocarbons on the order of 25%. The excellent stability of our hydrogen selective CMS membrane opens the door for its use in WGS-MR with a significantly reduced requirement of the feedstock pretreatment.

Paul Liu

2007-06-30T23:59:59.000Z

224

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

Electricity, Hydrogen, and Thermal Energy Timothy E. LipmanElectricity, Hydrogen, and Thermal Energy Timothy E. Lipmanof electricity, hydrogen, and thermal energy; 2) a survey of

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

225

Measurement of Hydrogen Production Rate Based on Dew Point Temperatures: Independent Review  

DOE Green Energy (OSTI)

This independent review verified Idaho National Labotory's approach of measuring the rate of hydrogen production using dew point temperatures.

Duffy, M.; Harrison, K.; Sheahen, T.

2007-11-01T23:59:59.000Z

226

Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis  

Fuel Cell Technologies Publication and Product Library (EERE)

This independent review examines DOE cost targets for state-of-the art hydrogen production using water electrolysis.

227

Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis: Independent Review  

DOE Green Energy (OSTI)

This independent review examines DOE cost targets for state-of-the art hydrogen production using water electrolysis.

Not Available

2009-09-01T23:59:59.000Z

228

Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

60-46674 60-46674 September 2009 Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen Production March 27, 2008 - August 31, 2009 B.D. James, G.N. Baum, J. Perez, and K.N. Baum Directed Technologies, Inc. Arlington, Virginia National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Operated by the Alliance for Sustainable Energy, LLC Contract No. DE-AC36-08-GO28308 Subcontract Report NREL/SR-560-46674 September 2009 Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen Production March 27, 2008 - August 31, 2009 B.D. James, G.N. Baum, J. Perez, and K.N. Baum

229

A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

Gas Technology Institute is developing a novel concept of membrane reactor coupled with a gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal-derived synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. Hydrogen permeation data for several perovskite membranes BCN (BaCe{sub 0.9}Nd{sub 0.1}O{sub 3-x}), SCE (SrCe{sub 0.9}Eu{sub 0.1}O{sub 3}) and SCTm (SrCe{sub 0.95}Tm{sub 0.05}O{sub 3}) have been successfully obtained for temperatures between 800 and 950 C and pressures from 1 to 12 bar in this project. However, it is known that the cerate-based perovskite materials can react with CO{sub 2}. Therefore, the stability issue of the proton conducting perovskite materials under CO{sub 2} or H{sub 2}S environments was examined. Tests were conducted in the Thermo Gravimetric Analyzer (TGA) unit for powder and disk forms of BCN and SCE. Perovskite materials doped with zirconium (Zr) are known to be resistant to CO{sub 2}. The results from the evaluation of the chemical stability for the Zr doped perovskite membranes are presented. During this reporting period, flowsheet simulation was also performed to calculate material and energy balance based on several hydrogen production processes from coal using high temperature membrane reactor (1000 C), low temperature membrane reactor (250 C), or conventional technologies. The results show that the coal to hydrogen process employing both the high temperature and the low temperature membrane reactors can increase the hydrogen production efficiency (cold gas efficiency) by more than 50% compared to the conventional process. Using either high temperature or low temperature membrane reactor process also results in an increase of the cold gas efficiencies as well as the thermal efficiencies of the overall process.

Shain Doong; Estela Ong; Mike Atroshenko; Francis Lau; Mike Roberts

2005-07-29T23:59:59.000Z

230

A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

Gas Technology Institute is developing a novel concept of membrane gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. To evaluate the performances of the candidate membranes under the gasification conditions, a high temperature/high pressure hydrogen permeation unit will be constructed in this project. During this reporting period, the mechanical construction of the permeation unit was completed. Commissioning and shake down tests are being conducted. The unit is capable of operation at temperatures up to 1100 C and pressures to 60 atm for evaluation of ceramic membranes such as mixed ionic conducting membrane. The membranes to be tested will be in disc form with a diameter of about 3 cm. Operation at these high temperatures and high hydrogen partial pressures will demonstrate commercially relevant hydrogen flux, 10{approx}50 cc/min/cm{sup 2}, from the membranes made of the perovskite type of ceramic material. Preliminary modeling was also performed for a tubular membrane reactor within a gasifier to estimate the required membrane area for a given gasification condition. The modeling results will be used to support the conceptual design of the membrane reactor.

Shain Doong; Estela Ong; Mike Atroshenko; Mike Roberts; Francis Lau

2004-04-26T23:59:59.000Z

231

A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

Gas Technology Institute is developing a novel concept of membrane gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal-derived synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. To evaluate the performances of the candidate membranes under the gasification conditions, a high temperature/high pressure hydrogen permeation unit has been constructed in this project. The unit is designed to operate at temperatures up to 1100 C and pressures to 60 atm for evaluation of ceramic membranes such as mixed ionic conducting membrane. The unit was fully commissioned and is operational. Several perovskite membranes based on the formulations of BCN (BaCe{sub 0.8}Nd{sub 0.2}O{sub 3-x}) and BCY (BaCe{sub 0.8}Y{sub 0.2}O{sub 3-x}) were prepared by GTI and tested in the new permeation unit. These membranes were fabricated by either uniaxial pressing or tape casting technique with thickness ranging from 0.2 mm to 0.7 mm. Hydrogen permeation data for the BCN perovskite membrane have been successfully obtained for temperatures between 800 and 950 C and pressures from 1 to 12 bar. The highest hydrogen flux was measured at 1.6 STPcc/min/cm{sup 2} at a hydrogen feed pressure of 12 bar and 950 C with a membrane thickness of 0.22 mm. A membrane gasification reactor model was developed to consider the H{sub 2} permeability of the membrane, the kinetics and the equilibriums of the gas phase reactions in the gasifier, the operating conditions and the configurations of the membrane reactor. The results show that the hydrogen production efficiency using the novel membrane gasification reactor concept can be increased by about 50% versus the conventional gasification process. This confirms the previous evaluation results from the thermodynamic equilibrium calculation. A rigorous model for hydrogen permeation through mixed proton-electron conducting ceramic membranes was also developed based on non-equilibrium thermodynamics. The hydrogen flux predicted from the modeling results are in line with the data from the experimental measurement. The simulation also shows that the presence of steam in the permeate side or the feed side of the membrane can have a small negative effect on the hydrogen flux, in the order of 10%.

Shain Doong; Estela Ong; Mike Atroshenko; Francis Lau; Mike Roberts

2004-10-26T23:59:59.000Z

232

Chemical Hydride Slurry for Hydrogen Production and Storage  

Science Conference Proceedings (OSTI)

The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: Magnesium hydride slurry is stable for months and pumpable. The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (Milk of Magnesia) and magnesium oxide. We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

McClaine, Andrew W.

2008-09-30T23:59:59.000Z

233

Techno Economic Analysis of Hydrogen Production by gasification of biomass  

SciTech Connect

Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

Francis Lau

2002-12-01T23:59:59.000Z

234

Techno Economic Analysis of Hydrogen Production by gasification of biomass  

DOE Green Energy (OSTI)

Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

Francis Lau

2002-12-01T23:59:59.000Z

235

A Novel Membrane Reactor for Direct Hydrogen Production from Coal  

DOE Green Energy (OSTI)

Gas Technology Institute is developing a novel concept of membrane gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal-derived synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. To evaluate the performances of the candidate membranes under the gasification conditions, a high temperature/high pressure hydrogen permeation unit has been constructed in this project. The unit is designed to operate at temperatures up to 1100 C and pressures to 60 atm for evaluation of ceramic membranes such as mixed ionic conducting membrane. Several perovskite membranes based on the formulations of BCN (BaCe{sub 0.8}Nd{sub 0.2}O{sub 3-x}) and BCY (BaCe{sub 0.8}Y{sub 0.2}O{sub 3-x}) were prepared by GTI and successfully tested in the new permeation unit. During this reporting period, two different types of membranes, Eu-doped SrCeO{sub 3} (SCE) and SrCe{sub 0.95}Tm{sub 0.05}O{sub 3} (SCTm) provided by the University of Florida and the University of Cincinnati, respectively were tested in the high pressure permeation unit. The SCTm membrane, with a thickness of 1.7 mm, showed the highest hydrogen permeability among the perovskite membranes tested in this project so far. The hydrogen flux measured for the SCTm membrane was close to 0.8 cc/min/cm{sup 2} at a hydrogen feed pressure of about 4 bar at 950 C. SEM and EDX analysis for the tested SCTm membrane showed a separate Ce-rich phase deposited along the grain boundaries in the region towards the feed side of the membrane. No such phase separation was observed towards the permeate side. Partial reduction of the SCTm perovskite material by the high pressure hydrogen, especially in the feed side of the membrane, was postulated to be the possible reason for the phase separation. Further investigation of the stability issue of the perovskite membrane is needed.

Shain Doong, Estela Ong; Mike Atroshenko; Francis Lau; Mike Robers

2004-12-31T23:59:59.000Z

236

Development of efficient photoreactors for solar hydrogen production  

Science Conference Proceedings (OSTI)

The rate of hydrogen evolution from a photocatalytic process depends not only on the activity of a photocatalyst, but also on photoreactor design. Ideally, a photoreactor should be able to absorb the incident light, promoting photocatalytic reactions in an effective manner with minimal photonic losses. There are numerous technical challenges and cost related issues when designing a large-scale photoreactor for hydrogen production. Active stirring of the photocatalyst slurry within a photoreactor is not practical in large-scale applications due to cost related issues. Rather, the design should allow facile self-mixing of the flow field within the photoreactor. In this paper two types of photocatalytic reactor configurations are studied: a batch type design and another involving passive self-mixing of the photolyte. Results show that energy loss from a properly designed photoreactor is mainly due to reflection losses from the photoreactor window. We describe the interplay between the reaction and the photoreactor design parameters as well as effects on the rate of hydrogen evolution. We found that a passive self-mixing of the photolyte is possible. Furthermore, the use of certain engineering polymer films as photoreactor window materials has the potential for substantial cost savings in large-scale applications, with minimal reduction of photon energy utilization efficiency. Eight window materials were tested and the results indicate that Aclar trademark polymer film used as the photoreactor window provides a substantial cost saving over other engineering polymers, especially with respect to fused silica glass at modest hydrogen evolution rates. (author)

Huang, Cunping; Yao, Weifeng; T-Raissi, Ali; Muradov, Nazim [University of Central Florida, Florida Solar Energy Center, 1679 Clearlake Road, Cocoa, Fl 32922-5703 (United States)

2011-01-15T23:59:59.000Z

237

DOE Hydrogen Analysis Repository: H2 Production by Fermentation  

NLE Websites -- All DOE Office Websites (Extended Search)

H2 Production by Fermentation H2 Production by Fermentation Project Summary Full Title: Boundary Analysis for H2 Production by Fermentation Project ID: 70 Principal Investigator: Tim Eggeman Keywords: Hydrogen production; pressure swing adsorption (PSA); glucose; costs; fermentation Performer Principal Investigator: Tim Eggeman Organization: Neoterics International Address: 2319 S. Ellis Ct. Lakewood, CO 80228 Telephone: 303-358-6390 Email: time@NeotericsInt.com Sponsor(s) Name: Roxanne Garland Organization: DOE/EERE/HFCIT Telephone: 202-586-7260 Email: Roxanne.Garland@ee.doe.gov Name: Margaret Mann Organization: National Renewable Energy Laboratory Telephone: 303-275-2921 Email: Margaret_mann@nrel.gov Period of Performance Start: July 2001 End: September 2004 Project Description Type of Project: Analysis

238

Process analysis and aspen plus simulation of nuclear-based hydrogen production with a copper-chlorine cycle.  

E-Print Network (OSTI)

??Thermochemical processes for hydrogen production driven by nuclear energy are promising alternatives to existing technologies for large-scale commercial production of hydrogen, without dependence on fossil (more)

Chukwu, Cletus

2008-01-01T23:59:59.000Z

239

Technology status of hydrogen road vehicles. IEA technical report from the IEA Agreement of the production and utilization of hydrogen  

DOE Green Energy (OSTI)

The report was commissioned under the Hydrogen Implementing Agreement of the International Energy Agency (IEA) and examines the state of the art in the evolving field of hydrogen-fueled vehicles for road transport. The first phase surveys and analyzes developments since 1989, when a comprehensive review was last published. The report emphasizes the following: problems, especially backfiring, with internal combustion engines (ICEs); operational safety; hydrogen handling and on-board storage; and ongoing demonstration projects. Hydrogen vehicles are receiving much attention, especially at the research and development level. However, there has been a steady move during the past 5 years toward integral demonstrations of operable vehicles intended for public roads. Because they emit few, or no greenhouse gases, hydrogen vehicles are beginning to be taken seriously as a promising solution to the problems of urban air quality. Since the time the first draft of the report was prepared (mid-19 96), the 11th World Hydrogen Energy Conference took place in Stuttgart, Germany. This biennial conference can be regarded as a valid updating of the state of the art; therefore, the 1996 results are included in the current version. Sections of the report include: hydrogen production and distribution to urban users; on-board storage and refilling; vehicle power units and drives, and four appendices titled: 'Safety questions of hydrogen storage and use in vehicles', 'Performance of hydrogen fuel in internal production engines for road vehicles, 'Fuel cells for hydrogen vehicles', and 'Summaries of papers on hydrogen vehicles'. (refs., tabs.)

Doyle, T.A.

1998-01-31T23:59:59.000Z

240

Overview of High-Temperature Electrolysis for Hydrogen Production  

SciTech Connect

Over the last five years there has been a growing interest in the use of hydrogen as an energy carrier, particularly to augment transportation fuels and thus reduce our dependence on imported petroleum. Hydrogen is now produced primarily via steam reforming of methane. However, in the long term, methane reforming is not a viable process for the large-scale hydrogen production since such fossil fuel conversion processes consume non-renewable resources and emit greenhouse gases. Nuclear energy can be used to produce hydrogen without consuming fossil fuels and without emitting greenhouse gases through the splitting of water into hydrogen and oxygen. The Nuclear Hydrogen Initiative of the DOE Office of Nuclear Energy is developing three general categories of high temperature processes for hydrogen production: thermochemical, electrolytic and hybrid thermo-electrolytic. This paper introduces the work being done in the development of high temperature electrolysis of steam. High Temperature Electrolysis (HTE) is built on the technology of solid oxide fuel cells (SOFCs), which were invented over a century ago, but which have been most vigorously developed during the last twenty years. SOFCs consume hydrogen and oxygen and produce steam and electricity. Solid Oxide Electrolytic Cells (SOECs) consume electricity and steam and produce hydrogen and oxygen. The purpose of the HTE research is to solve those problems unique to the electrolytic mode of operation, while building further on continuing fuel cell development. ORGANIZATION Experiments have been conducted for the last three years at the Idaho National Laboratory and at Ceramatec, Inc. on the operation of button cells and of progressively larger stacks of planar cells. In addition, the INL has been performing analyses of the cell-scale fluid dynamics and plant-scale flowsheets in order to determine optimum operating conditions and plant configurations. Argonne National Laboratory has been performing experiments for the development of new electrode materials, as well as modeling of the fluid dynamics and flowsheets for comparison with the work being done at the INL. ANL has also been performing diagnostic measures on components form long-duration tests at the INL and Ceramatec to determine the causes for the slow degradation in cell performance. Oak Ridge National Laboratory has been developing high temperature porous membranes for the separation of hydrogen from the residual steam, thus avoiding the need to condense and reheat the steam. The University of Nevada at Las Vegas has been collaborating with ANL on the development of electrode and electrolyte materials and will soon begin to investigate the causes of cell degradation. HTE research also includes NERI projects at the Virginia Polytechnic Institute on the development of toughened SOEC composite seals and at the Georgia Institute of Technology on the microstructural design of SOEC materials. EXPERIMENTAL RESULTS The most recent large-scale test of HTE was performed from June 28 through Sept 22, 2006 at the Ceramatec plant in Salt Lake City. The test apparatus consists of two stacks of 60 cells each in a configuration that will be used in the Integrated Laboratory Scale (ILS) experiment during FY-07. The ILS will contain three modules of four stacks each. The Half-Module initially produced 1.2 normal m3of H2/hour and 0.65 Nm3/hr at the end of the 2040-hour continuous test.

Herring, J. S.; O' Brien, J. E.; Stoots, C. M.; Hartvigsen, J. J.; Petri, M. C.; Carter, J. D.; Bischoff, B. L.

2007-06-01T23:59:59.000Z

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241

A Novel Membrane Reactor for Direct Hydrogen Production From Coal  

DOE Green Energy (OSTI)

Gas Technology Institute has developed a novel concept of a membrane reactor closely coupled with a coal gasifier for direct extraction of hydrogen from coal-derived syngas. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under the coal gasification conditions. The best performing membranes were selected for preliminary reactor design and cost estimate. The overall economics of hydrogen production from this new process was assessed and compared with conventional hydrogen production technologies from coal. Several proton-conducting perovskite membranes based on the formulations of BCN (BaCe{sub 0.8}Nd{sub 0.2}O{sub 3-x}), BCY (BaCe{sub 0.8}Y{sub 0.2}O{sub 3-x}), SCE (Eu-doped SrCeO{sub 3}) and SCTm (SrCe{sub 0.95}Tm{sub 0.05}O{sub 3}) were successfully tested in a new permeation unit at temperatures between 800 and 1040 C and pressures from 1 to 12 bars. The experimental data confirm that the hydrogen flux increases with increasing hydrogen partial pressure at the feed side. The highest hydrogen flux measured was 1.0 cc/min/cm{sup 2} (STP) for the SCTm membrane at 3 bars and 1040 C. The chemical stability of the perovskite membranes with respect to CO{sub 2} and H{sub 2}S can be improved by doping with Zr, as demonstrated from the TGA (Thermal Gravimetric Analysis) tests in this project. A conceptual design, using the measured hydrogen flux data and a modeling approach, for a 1000 tons-per-day (TPD) coal gasifier shows that a membrane module can be configured within a fluidized bed gasifier without a substantial increase of the gasifier dimensions. Flowsheet simulations show that the coal to hydrogen process employing the proposed membrane reactor concept can increase the hydrogen production efficiency by more than 50% compared to the conventional process. Preliminary economic analysis also shows a 30% cost reduction for the proposed membrane reactor process, assuming membrane materials meeting DOE's flux and cost target. Although this study shows that a membrane module can be configured within a fluidized bed gasifier, placing the membrane module outside the gasifier in a closely coupled way in terms of temperature and pressure can still offer the same performance advantage. This could also avoid the complicated fluid dynamics and heat transfer issues when the membrane module is installed inside the gasifier. Future work should be focused on improving the permeability and stability for the proton-conducting membranes, testing the membranes with real syngas from a gasifier and scaling up the membrane size.

Shain Doong; Estela Ong; Mike Atrosphenko; Francis Lau; Mike Roberts

2006-01-20T23:59:59.000Z

242

Hydrogen production plants using electrolytic cells with low cost electrodes built into pressure tanks  

SciTech Connect

Electrolytic production method of generating hydrogen gas is briefly reviewed and critical components of electrolytic hydrogen production plants are listed. These components are then discussed and recommended approaches and arrangements cited. Recommended arrangement would be operated at moderate temperatures and gas pipe line pressures. A hypothetical 150 MW Hydrogen Plant is described, including estimates of cost and performance. Comments are made in regard to several possible generating systems which might be used to power hydrogen production plants. A comprehensive energy policy is appended.

Hall, F.F.

1978-02-01T23:59:59.000Z

243

Resource Analysis for Hydrogen Production - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Marc W. Melaina (Primary Contact), Michael Penev and Donna Heimiller National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 Phone: (303) 275-3836 Email: Marc.Melaina@nrel.gov DOE Manager HQ: Fred Joseck Phone: (202) 586-7932 Email: Fred.Joseck@hq.doe.gov Project Start Date: October 1, 2009 Project End Date: September 28, 2012 Fiscal Year (FY) 2012 Objectives Understand the hydrogen production requirements for a * future demand scenario Estimate low-carbon energy resources required to meet * the future scenario demand Compare resource requirements to current consumption * and projected future consumption Determine resource availability geographically and on a *

244

Photoelectrochemical Hydrogen Production - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Arun Madan MVSystems, Incorporated (MVS) 500 Corporate Circle, Suite L Golden, CO 80401 Phone: (303) 271-9907 Email: ArunMadan@aol.com or amadan@mvsystemsinc.com DOE Managers HQ: Eric Miller Phone: (202) 287-5829 Email: Eric.Miller@ee.doe.gov GO: David Peterson Phone: (720) 356-1747 Email: David.Peterson@go.doe.gov Contract Number: DE-FC36-07GO17105, A00 Subcontractor: University of Hawaii at Manoa (UH), Honolulu, HI Project Start Date: September 1, 2007 Project End Date: December 31, 2012 Fiscal Year (FY) 2012 Objectives Work closely with the DOE Working Group on * Photoelectrochemical (PEC) Hydrogen Production for optimizing PEC materials and devices. Develop new PEC film materials compatible with high- *

245

Economic Analysis of Hydrogen Production from Wind: Preprint  

DOE Green Energy (OSTI)

The purpose of this analysis is to determine the cost of using wind energy to produce hydrogen for use as a transportation fuel. This analysis assumes that a market exists for 50,000 kg of hydrogen per day produced from wind at the wind site; only production costs to the front gate are included, no delivery or dispensing costs are included. Three different scenarios are examined: near term, which represents 2005 currently available technology; mid term, which represents technological improvements and price reductions in the next 5-10 years; and long term, which is representative of the best technology gains and price reductions surmised by industry at this point, and represents the next 10-25 years.

Levene, J. I.

2005-05-01T23:59:59.000Z

246

An Analysis of Hydrogen Production from Renewable Electricity Sources: Preprint  

NLE Websites -- All DOE Office Websites (Extended Search)

An Analysis of Hydrogen An Analysis of Hydrogen Production from Renewable Electricity Sources Preprint J.I. Levene, M.K. Mann, R. Margolis, and A. Milbrandt National Renewable Energy Laboratory Prepared for ISES 2005 Solar World Congress Orlando, Florida August 6-12, 2005 Conference Paper NREL/CP-560-37612 September 2005 NOTICE The submitted manuscript has been offered by an employee of the Midwest Research Institute (MRI), a contractor of the US Government under Contract No. DE-AC36-99GO10337. Accordingly, the US Government and MRI retain a nonexclusive royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for US Government purposes. This report was prepared as an account of work sponsored by an agency of the United States government.

247

Hydrogen Production Via a Commercially Ready Inorganic Membrane Reactor  

DOE Green Energy (OSTI)

In the last report, we covered the experimental verification of the mathematical model we developed for WGS-MR, specifically in the aspect of CO conversion ratio, and the effect of the permeate sweep. Bench-top experimental study has been continuing in this period to verify the remaining aspects of the reactor performance, including hydrogen recovery ratio, hydrogen purity and CO contaminant level. Based upon the comparison of experimental vs simulated results in this period along with the results reported in the last period, we conclude that our mathematical model can predict reliably all aspects of the membrane reactor performance for WGS using typical coal gasifier off-gas as feed under the proposed operating condition. In addition to 250 C, the experimental study at 225 C was performed. As obtained at 250 C, the predicted values match well with the experimental results at this lower temperature. The pretreatment requirement in our proposed WGS-MR process can be streamlined to the particulate removal only. No excess water beyond the stoichiometric requirement for CO conversion is necessary; thus, power generation efficiency can be maximized. PROX will be employed as post-treatment for the elimination of trace CO. Since the CO contaminant level from our WGS-MR is projected to be 20-30 ppm, PROX can be implemented economically and reliably to deliver hydrogen with <10 ppm CO to meet the spec for PEM fuel cell. This would be a more cost effective solution than the production of on-spec hydrogen without the use of prost treatment. WGS reaction in the presence of sulfur can be accomplished with the use of the Co/MoS{sub 2} catalyst. This catalyst has been employed industrially as a sour gas shift catalyst. Our mathematical simulation on WGS-MR based upon the suggested pre- and post-treatment has demonstrated that a nearly complete CO conversion (i.e., 99+%) can be accomplished. Although conversion vs production cost may play an important role in an overall process optimization, no cost optimization has been taken into consideration presently. We estimate that {approx}90% of the hydrogen produced from the H{sub 2}+CO in the coal gasifier off-gas can be recovered via our proposed WGS-MR process. Its purity level ranges from 80 to 92% depending upon the H{sub 2}/CO{sub 2} selectivity of 10 to 25 respectively. If the purity of 95% is required, the hydrogen recovery ratio will drop to {approx}80% level for the membrane with H{sub 2}/CO{sub 2} = 25.

Paul K. T. Liu

2006-09-30T23:59:59.000Z

248

Summary of Electrolytic Hydrogen Production: Milestone Completion Report  

SciTech Connect

This report provides an overview of the current state of electrolytic hydrogen production technologies and an economic analysis of the processes and systems available as of December 2003. The operating specifications of commercially available electrolyzers from five manufacturers, i.e., Stuart, Teledyne, Proton, Norsk Hydro, and Avalence, are summarized. Detailed economic analyses of three systems for which cost and economic data were available were completed. The contributions of the cost of electricity, system efficiency, and capital costs to the total cost of electrolysis are discussed.

Ivy, J.

2004-09-01T23:59:59.000Z

249

Summary of Electrolytic Hydrogen Production: Milestone Completion Report  

SciTech Connect

This report provides an overview of the current state of electrolytic hydrogen production technologies and an economic analysis of the processes and systems available as of December 2003. The operating specifications of commercially available electrolyzers from five manufacturers, i.e., Stuart, Teledyne, Proton, Norsk Hydro, and Avalence, are summarized. Detailed economic analyses of three systems for which cost and economic data were available were completed. The contributions of the cost of electricity, system efficiency, and capital costs to the total cost of electrolysis are discussed.

Ivy, J.

2004-04-01T23:59:59.000Z

250

Hydrogen production by gasification of municipal solid waste  

DOE Green Energy (OSTI)

As fossil fuel reserves run lower and lower, and as their continued widespread use leads toward numerous environmental problems, the need for clean and sustainable energy alternatives becomes ever clearer. Hydrogen fuel holds promise as such as energy source, as it burns cleanly and can be extracted from a number of renewable materials such as municipal solid waste (MSW), which can be considered largely renewable because of its high content of paper and biomass-derived products. A computer model is being developed using ASPEN Plus flow sheeting software to simulate a process which produces hydrogen gas from MSW; the model will later be used in studying the economics of this process and is based on an actual Texaco coal gasification plant design. This paper gives an overview of the complete MSW gasification process, and describes in detail the way in which MSW is modeled by the computer as a process material. In addition, details of the gasifier unit model are described; in this unit modified MSW reacts under pressure with oxygen and steam to form a mixture of gases which include hydrogen.

Rogers, R. III

1994-05-20T23:59:59.000Z

251

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

500/kW Anode tail gas Hydrogen Engine Gen-Set ICE/GeneratorFuel Cell Deployment and Hydrogen Infrastructure, WorldwideOffice (2005), Florida Hydrogen Business Partnership,

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

252

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

refueling and compressed natural gas (CNG) for CNG vehicles,Natural Gas Reformer Reformate Hydrogen Hydrogen CompressedNatural gas Air Recycled Reformate MCFC or SOFC Fuel Cell Reformate Hydrogen Compressed

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

253

Fuel Cell Technologies Office: Hydrogen Production Analysis Using the H2A  

NLE Websites -- All DOE Office Websites (Extended Search)

Production Production Analysis Using the H2A v3 Model (Text Version) to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Production Analysis Using the H2A v3 Model (Text Version) on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Production Analysis Using the H2A v3 Model (Text Version) on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Production Analysis Using the H2A v3 Model (Text Version) on Google Bookmark Fuel Cell Technologies Office: Hydrogen Production Analysis Using the H2A v3 Model (Text Version) on Delicious Rank Fuel Cell Technologies Office: Hydrogen Production Analysis Using the H2A v3 Model (Text Version) on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Production Analysis Using the H2A v3 Model (Text Version) on AddThis.com...

254

The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen  

E-Print Network (OSTI)

The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming - the most prevalent method of hydrogen ...

Miu, Kevin (Kevin K.)

2006-01-01T23:59:59.000Z

255

Production of Hydrogen at the Forecourt Using Off-Peak Electricity: June 2005 (Milestone Report)  

DOE Green Energy (OSTI)

This milestone report provides information about the production of hydrogen at the forecourt using off-peak electricity as well as the Hydrogen Off-Peak Electricity (HOPE) model.

Levene, J. I.

2007-02-01T23:59:59.000Z

256

Optimal design and observation of counter-current autothermal reactors for the production of hydrogen  

Science Conference Proceedings (OSTI)

Autothermal reactors, coupling endothermic and exothermic reactions in parallel channels, represent one of the most promising technologies for hydrogen production. Building our prior results, the present work focuses on hydrogen generation in counter-current ...

Michael Baldea; Monica Zanfir; Prodromos Daoutidis

2009-06-01T23:59:59.000Z

257

Method for direct production of carbon disulfide and hydrogen from hydrocarbons and hydrogen sulfide feedstock  

DOE Patents (OSTI)

A method for converting hydrocarbons and hydrogen sulfide to carbon disulfide and hydrogen is provided comprising contacting the hydrocarbons and hydrogen sulfide to a bi-functional catalyst residing in a controlled atmosphere for a time and at a temperature sufficient to produce carbon disulfide and hydrogen. Also provided is a catalyst for converting carbon sulfides and hydrogen sulfides to gasoline range hydrocarbons comprising a mixture containing a zeolite catalyst and a hydrogenating catalyst.

Miao, Frank Q.; Erekson, Erek James

1998-12-01T23:59:59.000Z

258

NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)  

DOE Green Energy (OSTI)

Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

Ramsden, T.; Harrison, K.; Steward, D.

2009-11-16T23:59:59.000Z

259

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

Strategy for Hydrogen Energy Technologies, Florida HydrogenEdition, National Energy Technology Laboratory, DOE/NETL-Incentives: Advanced energy technologies require advanced

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

260

Wind Energy and Production of Hydrogen and Electricity -- Opportunities for Renewable Hydrogen: Preprint  

DOE Green Energy (OSTI)

An assessment of options for wind/hydrogen/electricity systems at both central and distributed scales provides insight into opportunities for renewable hydrogen.

Levene, J.; Kroposki, B.; Sverdrup, G.

2006-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Large-Scale Production of Hydrogen by Nuclear Energy for the Hydrogen Economy (A24265)  

E-Print Network (OSTI)

In Proc. Of 2003 National Hydrogen Association Annual Conference, Washington, DC, 2003; To Be PublishedNational Hydrogen Association Annual Conference(2003) Washington DC, US, 2003999608585

Schultz, K.R.

2003-03-20T23:59:59.000Z

262

Hydrogen Technology Analysis: H2A Production Model Update (Presentation)  

DOE Green Energy (OSTI)

This presentation by Todd Ramsden at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's hydrogen technology analysis activities.

Ramsden, T.

2007-05-15T23:59:59.000Z

263

Utilization of solar thermal sources for thermochemical hydrogen production  

DOE Green Energy (OSTI)

The utilization of high temperature solar heat for the production of electricity and/or fuels is a popular concept. However, since solar concentrator systems are expensive and solar radiation intermittent, practical utilization requires processes that exhibit high conversion efficiencies and also incorporate energy storage. The production of hydrogen fulfills the requirement for energy storage and can fulfill the requirement for efficient heat utilization if thermochemical cycles are developed where the temperature and heat requirements of the process match the heat delivery characteristics of the solar receiver system. Cycles based on solid sulfate decomposition reactions may lead to efficient utilization of solar heat at practical temperatures. Higher temperature cycles involving oxide decomposition may also become feasible.

Bowman, M.G.

1980-01-01T23:59:59.000Z

264

Natural Gas Used as Feedstock for Hydrogen Production  

U.S. Energy Information Administration (EIA) Indexed Site

Used as Feedstock for Hydrogen Production Used as Feedstock for Hydrogen Production (Million Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Area 2008 2009 2010 2011 2012 View History U.S. 188,075 143,004 154,503 169,465 183,051 2008-2012 East Coast (PADD 1) 5,149 4,178 3,346 4,815 6,313 2008-2012 Midwest (PADD 2) 37,044 36,936 45,452 44,623 46,640 2008-2012 Gulf Coast (PADD 3) 80,291 41,049 43,170 50,968 62,829 2008-2012 Rocky Mountain (PADD 4) 12,747 11,904 12,047 12,896 12,595 2008-2012 West Coast (PADD 5) 52,844 48,937 50,488 56,163 54,674 2008-2012 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

265

ENHANCED HYDROGEN ECONOMICS VIA COPRODUCTION OF FUELS AND CARBON PRODUCTS  

SciTech Connect

This Department of Energy National Energy Technology Laboratory sponsored research effort to develop environmentally cleaner projects as a spin-off of the FutureGen project, which seeks to reduce or eliminate emissions from plants that utilize coal for power or hydrogen production. New clean coal conversion processes were designed and tested for coproducing clean pitches and cokes used in the metals industry as well as a heavy crude oil. These new processes were based on direct liquefaction and pyrolysis techniques that liberate volatile liquids from coal without the need for high pressure or on-site gaseous hydrogen. As a result of the research, a commercial scale plant for the production of synthetic foundry coke has broken ground near Wise, Virginia under the auspices of Carbonite Inc. This plant will produce foundry coke by pyrolyzing a blend of steam coal feedstocks. A second plant is planned by Quantex Energy Inc (in Texas) which will use solvent extraction to coproduce a coke residue as well as crude oil. A third plant is being actively considered for Kingsport, Tennessee, pending a favorable resolution of regulatory issues.

Kennel, Elliot B; Bhagavatula, Abhijit; Dadyburjor, Dady; Dixit, Santhoshi; Garlapalli, Ravinder; Magean, Liviu; Mukkha, Mayuri; Olajide, Olufemi A; Stiller, Alfred H; Yurchick, Christopher L

2011-03-31T23:59:59.000Z

266

Assessment of Natural Gas Splitting with a Concentrating Solar Reactor for Hydrogen Production  

DOE Green Energy (OSTI)

Hydrogen production via thermal decomposition of methane using a solar reactor is analyzed for two different applications: (1) for a fueling station and (2) for power production. For the fueling station, the selling price of hydrogen is controlled by the high cost of hydrogen storage and compression, combined with storage limitations of the system, which prevents maximum hydrogen production. Two alternate scenarios to lower the hydrogen production cost are evaluated: (1) sending the hydrogen directly to a pipeline network and (2) adding a small electric heater, which provides heat to the solar reactor when the hydrogen supply is low. For power production, the economics of two options for the carbon produced from the solar process are evaluated: (1) selling the carbon black and (2) burning the carbon to produce more power.

Spath, P. L.; Amos, W. A.

2002-04-01T23:59:59.000Z

267

A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL  

DOE Green Energy (OSTI)

Gas Technology Institute is developing a novel concept of membrane reactor coupled with a gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal-derived synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. To evaluate the performances of the candidate membranes under the gasification conditions, a high temperature/high pressure hydrogen permeation unit has been constructed in this project. The unit is designed to operate at temperatures up to 1100 C and pressures to 60 atm for evaluation of ceramic membranes such as mixed protonic-electronic conducting membrane. Several perovskite membranes based on the formulations of BCN (BaCe{sub 0.8}Nd{sub 0.2}O{sub 3-x}), BCY (BaCe{sub 0.8}Y{sub 0.2}O{sub 3-x}), Eu-doped SrCeO{sub 3} (SCE) and SrCe{sub 0.95}Tm{sub 0.05}O{sub 3} (SCTm) were successfully tested in the new permeation unit. During this reporting period, a thin BCN membrane supported on a porous BCN layer was fabricated. The objective was to increase the hydrogen flux with a further reduction of the thickness of the active membrane layer. The thinnest dense layer that could be achieved in our laboratory currently was about 0.2 mm. Nevertheless, the membrane was tested in the permeation unit and showed reasonable flux compared to the previous BCN samples of the same thickness. A long term durability test was conducted for a SCTm membrane with pure hydrogen in the feed side and nitrogen in the sweep side. The pressure was 1 bar and the temperature was around 1010 C. No decline of hydrogen flux was observed after continuous running of over 250 hours. This long term test indicates that the perovskite membrane has good thermal stability under the reducing conditions of the hydrogen atmosphere. A conceptual design of the membrane reactor configuration for a 1000 tons-per-day (TPD) coal gasifier was completed. The design considered a tubular membrane module located within the freeboard area of a fluidized bed gasifier. The membrane ambipolar conductivity was based on the value calculated from the measured permeation data. A membrane thickness of 25 micron was assumed in the calculation. The GTI's gasification model combined with a membrane reactor model were used to determine the dimensions of the membrane module. It appears that a membrane module can be configured within a fluidized bed gasifier without substantial increase of the gasifier dimensions.

Shain Doong; Estela Ong; Mike Atroshenko; Francis Lau; Mike Roberts

2005-04-28T23:59:59.000Z

268

DOE Hydrogen and Fuel Cells Program Record 5012a: Well-to-Wheels Analyses for Solar and Wind Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Hydrogen and Fuel Cells Program Record DOE Hydrogen and Fuel Cells Program Record Record #: 5012a Date: December 21, 2005 Title: Well-to-Wheels Analyses for Solar & Wind Hydrogen Production Originator: Roxanne Garland Approved by: JoAnn Milliken Date: January 6, 2006 Item: This record explains the basis for the differences between the analyses of well-to-wheels energy use and greenhouse gas emissions conducted via Argonne National Laboratory's GREET Model, cited in the U.S. Department of Energy's Solar and Wind Technologies for Hydrogen Production Report to Congress, 1 and those conducted by the National Research Council, cited in the report The Hydrogen Economy: Opportunities, Costs, Barriers, and R&D Needs. 2 Well-to-Wheels Energy Use and Greenhouse Gas Emissions - Argonne National

269

Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review  

NLE Websites -- All DOE Office Websites (Extended Search)

& Hydrogen Production Technical Team Research Review Agenda for Tuesday, November 6, 2007 Location: BCS Incorporated, 8929 Stephens Road, Laurel, MD. 20723 410-997-7778 8:30 - 9:00 Continental Breakfast 9:00 DOE Targets, Tools and Technology o Bio-Derived Liquids to Hydrogen Distributed Reforming Targets DOE, Arlene Anderson o H2A Overview, NREL, Darlene Steward o Bio-Derived Liquids to Hydrogen Distributed Reforming Cost Analysis DTI, Brian James 10:00 Research Review o Low-Cost Hydrogen Distributed Production Systems, H2Gen, Sandy Thomas o Integrated Short Contact Time Hydrogen Generator, GE Global Research, Wei Wei o Distributed Bio-Oil Reforming, NREL, Darlene Steward o High Pressure Steam Ethanol Reforming, ANL, Romesh Kumar

270

DOE Hydrogen and Fuel Cells Program Record 12024: Hydrogen Production Cost Using Low-Cost Natural Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

2024 Date: September 19, 2012 2024 Date: September 19, 2012 Title: Hydrogen Production Cost Using Low-Cost Natural Gas Originator: Sara Dillich, Todd Ramsden & Marc Melaina Approved by: Sunita Satyapal Date: September 24, 2012 Item: Hydrogen produced and dispensed in distributed facilities at high-volume refueling stations using current technology and DOE's Annual Energy Outlook (AEO) 2009 projected prices for industrial natural gas result in a hydrogen levelized cost of $4.49 per gallon-gasoline-equivalent (gge) (untaxed) including compression, storage and dispensing costs. The hydrogen production portion of this cost is $2.03/gge. In comparison, current analyses using low-cost natural gas with a price of $2.00 per MMBtu can decrease the hydrogen levelized cost to $3.68 per gge (untaxed) including

271

Ice method for production of hydrogen clathrate hydrates  

DOE Patents (OSTI)

The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

Lokshin, Konstantin (Santa Fe, NM); Zhao, Yusheng (Los Alamos, NM)

2008-05-13T23:59:59.000Z

272

Switchable photosystem-II designer algae for photobiological hydrogen production  

DOE Patents (OSTI)

A switchable photosystem-II designer algae for photobiological hydrogen production. The designer transgenic algae includes at least two transgenes for enhanced photobiological H.sub.2 production wherein a first transgene serves as a genetic switch that can controls photosystem II (PSII) oxygen evolution and a second transgene encodes for creation of free proton channels in the algal photosynthetic membrane. In one embodiment, the algae includes a DNA construct having polymerase chain reaction forward primer (302), a inducible promoter (304), a PSII-iRNA sequence (306), a terminator (308), and a PCR reverse primer (310). In other embodiments, the PSII-iRNA sequence (306) is replaced with a CF.sub.1-iRNA sequence (312), a streptomycin-production gene (314), a targeting sequence (316) followed by a proton-channel producing gene (318), or a PSII-producing gene (320). In one embodiment, a photo-bioreactor and gas-product separation and utilization system produce photobiological H.sub.2 from the switchable PSII designer alga.

Lee, James Weifu (Knoxville, TN)

2010-01-05T23:59:59.000Z

273

From Waste to Hydrogen: An Optimal Design of Energy Production and Distribution Network  

E-Print Network (OSTI)

1 From Waste to Hydrogen: An Optimal Design of Energy Production and Distribution Network Nathan and distribution systems for hydrogen production from agricultural residues, which is a representative green energy of producing clean energy from renewable resources. This paper focuses on the optimal design of the production

Fan, Yueyue

274

Technology status of hydrogen road vehicles. IEA technical report from the IEA Agreement of the production and utilization of hydrogen  

SciTech Connect

The report was commissioned under the Hydrogen Implementing Agreement of the International Energy Agency (IEA) and examines the state of the art in the evolving field of hydrogen-fueled vehicles for road transport. The first phase surveys and analyzes developments since 1989, when a comprehensive review was last published. The report emphasizes the following: problems, especially backfiring, with internal combustion engines (ICEs); operational safety; hydrogen handling and on-board storage; and ongoing demonstration projects. Hydrogen vehicles are receiving much attention, especially at the research and development level. However, there has been a steady move during the past 5 years toward integral demonstrations of operable vehicles intended for public roads. Because they emit few, or no greenhouse gases, hydrogen vehicles are beginning to be taken seriously as a promising solution to the problems of urban air quality. Since the time the first draft of the report was prepared (mid-19 96), the 11th World Hydrogen Energy Conference took place in Stuttgart, Germany. This biennial conference can be regarded as a valid updating of the state of the art; therefore, the 1996 results are included in the current version. Sections of the report include: hydrogen production and distribution to urban users; on-board storage and refilling; vehicle power units and drives, and four appendices titled: 'Safety questions of hydrogen storage and use in vehicles', 'Performance of hydrogen fuel in internal production engines for road vehicles, 'Fuel cells for hydrogen vehicles', and 'Summaries of papers on hydrogen vehicles'. (refs., tabs.)

Doyle, T.A.

1998-01-31T23:59:59.000Z

275

NREL Melds Nature with Nanotech for Solar-Powered Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Melds Nature with Nanotech for Solar-Powered Hydrogen Production NREL researchers are finding ways to mimic photosynthesis by combining enzymes with nanoparticles-particles on the...

276

Co-Production of Pure Hydrogen and Electricity from Coal Syngas ...  

Science Conference Proceedings (OSTI)

Presentation Title, Co-Production of Pure Hydrogen and Electricity from Coal Syngas via the Steam-Iron Process Using Promoted Iron-Based Catalysts Sub-

277

DOE Hydrogen and Fuel Cells Program: DOE H2A Production Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

filling-station) facilities. Required input to the models includes capital and operating costs for the hydrogen production process, fuel type and use, and financial parameters...

278

Heat Transfer Limitations in Hydrogen Production Via Steam Reformation: The Effect of Reactor Geometry  

E-Print Network (OSTI)

Hydrogen production Reactors, M.S. Thesis, University ofREFORMATION: THE EFFECT OF REACTOR GEOMETRY David, R. ,have been manifest with reactors of different geometries. In

Vernon, David R.; Davieau, David D.; Dudgeon, Bryce A.; Erickson, Paul A.

2006-01-01T23:59:59.000Z

279

Hydrogen Production from Biomass via Indirect Gasification: The Impact of NREL Process Development Unit Gasifier Correlations  

DOE Green Energy (OSTI)

This report describes a set of updated gasifier correlations developed by NREL to predict biomass gasification products and Minimum Hydrogen Selling Price.

Kinchin, C. M.; Bain, R. L.

2009-05-01T23:59:59.000Z

280

Next Generation Hydrogen Stations: All Composite Data Products through Fall 2012  

DOE Green Energy (OSTI)

This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes 14 composite data products (CDPs) for next generation hydrogen stations.

Sprik, S.; Wipke, K.; Ramsden, T.; Ainscough, C.; Kurtz, J.

2012-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Anaerobic digestion for methane generation and ammonia reforming for hydrogen production  

E-Print Network (OSTI)

Anaerobic digestion for methane generation and ammonia reforming for hydrogen production Accepted 24 May 2013 Available online Keywords: Anaerobic digestion Ammonia Bioenergy Bioammonia Hydrogen Anaerobic digestion-bioammonia to hydrogen (ADBH) a b s t r a c t During anaerobic digestion, organic matter

282

Hydrogen Production by PEM Electrolysis: Spotlight on Giner and Proton  

NLE Websites -- All DOE Office Websites (Extended Search)

BY BY PEM ELECTROLYSIS: SPOTLIGHT ON GINER AND PROTON US DOE WEBINAR (May 23, 2011) 2 Webinar Outline *Water Electrolysis H 2 Production Overview DOE-EERE-FCT: Eric L. Miller *Spotlight: PEM Electrolysis R&D at Giner Giner Electrochemical Systems: Monjid Hamdan *Spotlight: PEM Electrolysis R&D at Proton Proton OnSite: Kathy Ayers *Q&A 3 DOE EERE-FCT Goals and Objectives Develop technologies to produce hydrogen from clean, domestic resources at a delivered and dispensed cost of $2-$4/gge Capacity (kg/day) Distributed Central 100,000,000 100,000 50,000 10,000 1,000 10 Natural Gas Reforming Photo- electro- chemical Biological Water Electrolysis (Solar) 2015-2020 Today-2015 2020-2030 Coal Gasification (No Carbon Capture) Electrolysis Water (Grid) Coal Gasification (Carbon Capture)

283

Interfacing primary heat sources and cycles for thermochemical hydrogen production  

DOE Green Energy (OSTI)

Advantages cited for hydrogen production from water by coupling thermochemical cycles with primary heat include the possibility of high efficiencies. These can be realized only if the cycle approximates the criteria required to match the characteristics of the heat source. Different types of cycles may be necessary for fission reactors, for fusion reactors or for solar furnaces. Very high temperature processes based on decomposition of gaseous H/sub 2/O or CO/sub 2/ appear impractical even for projected solar technology. Cycles based on CdO decomposition are potentially quite efficient and require isothermal heat at temperatures that may be available from solar furnaces of fusion reactors. Sulfuric acid and solid sulfate cycles are potentially useful at temperatures available from each heat source. Solid sulfate cycles offer advantages for isothermal heat sources. All cycles under development include concentration and drying steps. Novel methods for improving such operations would be beneficial.

Bowman, M.G.

1980-01-01T23:59:59.000Z

284

Hydrogen Production via a Commercially Ready Inorganic membrane Reactor  

DOE Green Energy (OSTI)

Single stage low-temperature-shift water-gas-shift (WGS-LTS) via a membrane reactor (MR) process was studied through both mathematical simulation and experimental verification in this quarter. Our proposed MR yields a reactor size that is 10 to >55% smaller than the comparable conventional reactor for a CO conversion of 80 to 90%. In addition, the CO contaminant level in the hydrogen produced via MR ranges from 1,000 to 4,000 ppm vs 40,000 to >70,000 ppm via the conventional reactor. The advantages of the reduced WGS reactor size and the reduced CO contaminant level provide an excellent opportunity for intensification of the hydrogen production process by the proposed MR. To prepare for the field test planned in Yr III, a significant number (i.e., 98) of full-scale membrane tubes have been produced with an on-spec ratio of >76% during this first production trial. In addition, an innovative full-scale membrane module has been designed, which can potentially deliver >20 to 30 m{sup 2}/module making it suitable for large-scale applications, such as power generation. Finally, we have verified our membrane performance and stability in a refinery pilot testing facility on a hydrocracker purge gas. No change in membrane performance was noted over the >100 hrs of testing conducted in the presence of >30% H{sub 2}S, >5,000 ppm NH{sub 3} (estimated), and heavy hydrocarbons on the order of 25%. The high stability of these membranes opens the door for the use of our membrane in the WGS environment with significantly reduced pretreatment burden.

Paul K.T. Liu

2005-08-23T23:59:59.000Z

285

IEA Agreement on the production and utilization of hydrogen: 1999 annual report  

DOE Green Energy (OSTI)

The annual report begins with an overview of the IEA Hydrogen Agreement, including guiding principles and their strategic plan followed by the Chairman's report providing the year's highlights. Annex reports included are: the final report for Task 11, Integrated Systems; task updates for Task 12, Metal Hydrides and Carbon for Hydrogen Storage, Task 13, Design and Optimization of Integrated Systems, Task 14, Photoelectrolytic Production of Hydrogen, and Task 15, Photobiological Production of Hydrogen; and a feature article by Karsten Wurr titled 'Large-Scale Industrial Uses of Hydrogen: Final Development Report'.

Elam, Carolyn C. (National Renewable Energy Lab, Golden, CO (US)) (ed.)

2000-01-31T23:59:59.000Z

286

IEA agreement on the production and utilization of hydrogen: 2000 annual report  

DOE Green Energy (OSTI)

The 2000 annual report of the IEA Hydrogen Agreement contains an overview of the agreement, including its guiding principles, latest strategic plan, and a report from the Chairman, Mr. Neil P. Rossmeissl, U.S. Department of Energy. Overviews of the National Hydrogen Programs of nine member countries are given: Canada, Japan, Lithuania, the Netherlands, Norway, Spain, Sweden, Switzerland, and the United States. Task updates are provided on the following annexes: Annex 12 - Metal Hydrides and Carbon for Hydrogen Storage, Annex 13 - Design and Optimization of Integrated Systems, Annex 14 - Photoelectrolytic Production of Hydrogen, and, Annex 15 - Photobiological Production of Hydrogen.

Elam, Carolyn C. [National Renewable Energy Lab., Golden, CO (US)] (ed.)

2001-12-01T23:59:59.000Z

287

IEA Agreement on the production and utilization of hydrogen: 1999 annual report  

SciTech Connect

The annual report begins with an overview of the IEA Hydrogen Agreement, including guiding principles and their strategic plan followed by the Chairman's report providing the year's highlights. Annex reports included are: the final report for Task 11, Integrated Systems; task updates for Task 12, Metal Hydrides and Carbon for Hydrogen Storage, Task 13, Design and Optimization of Integrated Systems, Task 14, Photoelectrolytic Production of Hydrogen, and Task 15, Photobiological Production of Hydrogen; and a feature article by Karsten Wurr titled 'Large-Scale Industrial Uses of Hydrogen: Final Development Report'.

Elam, Carolyn C. (National Renewable Energy Lab, Golden, CO (US)) (ed.)

2000-01-31T23:59:59.000Z

288

Market potential of electrolytic hydrogen production in three northeastern utilities' service territories. Final report  

SciTech Connect

The study develops a method for exploring the market potential for electrolytic hydrogen. The service areas of three northeastern utilities - Public Service Electric and Gas, Niagara Mohawk, and Northeast Utilities - are examined, and results reported on the effort to locate specialty hydrogen users, determine patterns of hydrogen utilization, and assess the possibility of satisfying this hydrogen demand by electrolytic hydrogen from advanced electrolyzers. Hydrogen users were sought in six major product categories: chemicals, pharmaceuticals, oils, metals, electronics and float glass. Identification of users through appropriate standard industrial classification codes served as a basis for locating possible users in each of the service areas. Mailed questionnaires sought information on hydrogen demand, characteristics of hydrogen use, present hydrogen supply costs, and factors that would influence the purchase of an electrolyzer. In the three utility service areas examined, electrolytic hydrogen can be expected to have limited success competing with merchant hydrogen. Specific hydrogen users may be found whose location with respect to the source of merchant hydrogen may put electrolytic hydrogen at an economic advantage. Reduction in electrolyzer plant costs may be necessary to expand the possibilities for electrolysis. Annual power requirements for current potential demand for electrolytic hydrogen in three utilities was estimated at 140 x 10/sup 6/ kWh, which could expand to 240 x 10/sup 6/ kWh in ten years.

Fein, E.; Edwards, K.

1984-05-01T23:59:59.000Z

289

Hydrogen demand, production, and cost by region to 2050.  

DOE Green Energy (OSTI)

This report presents an analysis of potential hydrogen (H{sub 2}) demand, production, and cost by region to 2050. The analysis was conducted to (1) address the Energy Information Administration's (EIA's) request for regional H{sub 2} cost estimates that will be input to its energy modeling system and (2) identify key regional issues associated with the use of H{sub 2} that need further study. Hydrogen costs may vary substantially by region. Many feedstocks may be used to produce H{sub 2}, and the use of these feedstocks is likely to vary by region. For the same feedstock, regional variation exists in capital and energy costs. Furthermore, delivery costs are likely to vary by region: some regions are more rural than others, and so delivery costs will be higher. However, to date, efforts to comprehensively and consistently estimate future H{sub 2} costs have not yet assessed regional variation in these costs. To develop the regional cost estimates and identify regional issues requiring further study, we developed a H{sub 2} demand scenario (called 'Go Your Own Way' [GYOW]) that reflects fuel cell vehicle (FCV) market success to 2050 and allocated H{sub 2} demand by region and within regions by metropolitan versus non-metropolitan areas. Because we lacked regional resource supply curves to develop our H{sub 2} production estimates, we instead developed regional H{sub 2} production estimates by feedstock by (1) evaluating region-specific resource availability for centralized production of H{sub 2} and (2) estimating the amount of FCV travel in the nonmetropolitan areas of each region that might need to be served by distributed production of H{sub 2}. Using a comprehensive H{sub 2} cost analysis developed by SFA Pacific, Inc., as a starting point, we then developed cost estimates for each H{sub 2} production and delivery method by region and over time (SFA Pacific, Inc. 2002). We assumed technological improvements over time to 2050 and regional variation in energy and capital costs. Although we estimate substantial reductions in H{sub 2} costs over time, our cost estimates are generally higher than the cost goals of the U.S. Department of Energy's (DOE's) hydrogen program. The result of our analysis, in particular, demonstrates that there may be substantial variation in H{sub 2} costs between regions: as much as $2.04/gallon gasoline equivalent (GGE) by the time FCVs make up one-half of all light-vehicle sales in the GYOW scenario (2035-2040) and $1.85/GGE by 2050 (excluding Alaska). Given the assumptions we have made, our analysis also shows that there could be as much as a $4.82/GGE difference in H{sub 2} cost between metropolitan and non-metropolitan areas by 2050 (national average). Our national average cost estimate by 2050 is $3.68/GGE, but the average H{sub 2} cost in metropolitan areas in that year is $2.55/GGE and that in non-metropolitan areas is $7.37/GGE. For these estimates, we assume that the use of natural gas to produce H{sub 2} is phased out. This phase-out reflects the desire of DOE's Office of Hydrogen, Fuel Cells and Infrastructure Technologies (OHFCIT) to eliminate reliance on natural gas for H{sub 2} production. We conducted a sensitivity run in which we allowed natural gas to continue to be used through 2050 for distributed production of H{sub 2} to see what effect changing that assumption had on costs. In effect, natural gas is used for 66% of all distributed production of H{sub 2} in this run. The national average cost is reduced to $3.10/GGE, and the cost in non-metropolitan areas is reduced from $7.37/GGE to $4.90, thereby reducing the difference between metropolitan and non-metropolitan areas to $2.35/GGE. Although the cost difference is reduced, it is still substantial. Regional differences are similarly reduced, but they also remain substantial. We also conducted a sensitivity run in which we cut in half our estimate of the cost of distributed production of H{sub 2} from electrolysis (our highest-cost production method). In this run, our national average cost estimate is reduced even further, to

Singh, M.; Moore, J.; Shadis, W.; Energy Systems; TA Engineering, Inc.

2005-10-31T23:59:59.000Z

290

Hydrogen demand, production, and cost by region to 2050.  

SciTech Connect

This report presents an analysis of potential hydrogen (H{sub 2}) demand, production, and cost by region to 2050. The analysis was conducted to (1) address the Energy Information Administration's (EIA's) request for regional H{sub 2} cost estimates that will be input to its energy modeling system and (2) identify key regional issues associated with the use of H{sub 2} that need further study. Hydrogen costs may vary substantially by region. Many feedstocks may be used to produce H{sub 2}, and the use of these feedstocks is likely to vary by region. For the same feedstock, regional variation exists in capital and energy costs. Furthermore, delivery costs are likely to vary by region: some regions are more rural than others, and so delivery costs will be higher. However, to date, efforts to comprehensively and consistently estimate future H{sub 2} costs have not yet assessed regional variation in these costs. To develop the regional cost estimates and identify regional issues requiring further study, we developed a H{sub 2} demand scenario (called 'Go Your Own Way' [GYOW]) that reflects fuel cell vehicle (FCV) market success to 2050 and allocated H{sub 2} demand by region and within regions by metropolitan versus non-metropolitan areas. Because we lacked regional resource supply curves to develop our H{sub 2} production estimates, we instead developed regional H{sub 2} production estimates by feedstock by (1) evaluating region-specific resource availability for centralized production of H{sub 2} and (2) estimating the amount of FCV travel in the nonmetropolitan areas of each region that might need to be served by distributed production of H{sub 2}. Using a comprehensive H{sub 2} cost analysis developed by SFA Pacific, Inc., as a starting point, we then developed cost estimates for each H{sub 2} production and delivery method by region and over time (SFA Pacific, Inc. 2002). We assumed technological improvements over time to 2050 and regional variation in energy and capital costs. Although we estimate substantial reductions in H{sub 2} costs over time, our cost estimates are generally higher than the cost goals of the U.S. Department of Energy's (DOE's) hydrogen program. The result of our analysis, in particular, demonstrates that there may be substantial variation in H{sub 2} costs between regions: as much as $2.04/gallon gasoline equivalent (GGE) by the time FCVs make up one-half of all light-vehicle sales in the GYOW scenario (2035-2040) and $1.85/GGE by 2050 (excluding Alaska). Given the assumptions we have made, our analysis also shows that there could be as much as a $4.82/GGE difference in H{sub 2} cost between metropolitan and non-metropolitan areas by 2050 (national average). Our national average cost estimate by 2050 is $3.68/GGE, but the average H{sub 2} cost in metropolitan areas in that year is $2.55/GGE and that in non-metropolitan areas is $7.37/GGE. For these estimates, we assume that the use of natural gas to produce H{sub 2} is phased out. This phase-out reflects the desire of DOE's Office of Hydrogen, Fuel Cells and Infrastructure Technologies (OHFCIT) to eliminate reliance on natural gas for H{sub 2} production. We conducted a sensitivity run in which we allowed natural gas to continue to be used through 2050 for distributed production of H{sub 2} to see what effect changing that assumption had on costs. In effect, natural gas is used for 66% of all distributed production of H{sub 2} in this run. The national average cost is reduced to $3.10/GGE, and the cost in non-metropolitan areas is reduced from $7.37/GGE to $4.90, thereby reducing the difference between metropolitan and non-metropolitan areas to $2.35/GGE. Although the cost difference is reduced, it is still substantial. Regional differences are similarly reduced, but they also remain substantial. We also conducted a sensitivity run in which we cut in half our estimate of the cost of distributed production of H{sub 2} from electrolysis (our highest-cost production method). In this run, our national average cost es

Singh, M.; Moore, J.; Shadis, W.; Energy Systems; TA Engineering, Inc.

2005-10-31T23:59:59.000Z

291

Conceptual design of nuclear systems for hydrogen production  

E-Print Network (OSTI)

Demand for hydrogen in the transportation energy sector is expected to keep growing in the coming decades; in the short term for refining heavy oils and in the long term for powering fuel cells. However, hydrogen cannot ...

Hohnholt, Katherine J

2006-01-01T23:59:59.000Z

292

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

Level Hydrogen and Distributed Generation Initiativesscale adoption of clean distributed generation and limit thebarriers to distributed generation facilities. Clean Energy

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

293

Analysis of hydrogen production during a BWR6 core heatup transient  

DOE Green Energy (OSTI)

An extensive study was performed for the prediction of hydrogen production during a BWR6 core heatup transient. Hydrogen production was found to be strongly affected by the transient core heat transfer and vessel hydrodynamics. Various sources important for steam generation and hydrogen production were identified. The results of the study were used by the NRC staff in their evaluation of the adequacy of the H/sub 2/ release histories suggested by the Hydrogen Control Owner's Group (HCOG). The owners group are sponsoring a 1/4 scale test program to investigate the adequacy of H/sub 2/ control during a degraded event. 1 ref., 2 figs.

Yang, J.W.; Pratt, W.T.

1986-01-01T23:59:59.000Z

294

High-temperature nuclear reactors as an energy source for hydrogen production  

SciTech Connect

From hydrogen economy Miami energy conference; Miami Beach, Florida, USA (18 Mar 1974). Application of current high-temperature reactor technology to hydrogen production is reviewed. The requirements and problems of matching a thermochemical hydrogen production cycle to a nuclear heat source are discussed. Possibilities for extending the temperature of reactors upward are outlined. The major engineering problem is identified as the development of a high-temperature process heat exchanger separating the nuclear heat source from the chemical process. (auth)

Balcomb, J.D.; Booth, L.A.

1974-01-01T23:59:59.000Z

295

Final technical report [Molecular genetic analysis of biophotolytic hydrogen production in green algae  

DOE Green Energy (OSTI)

The principal objective of this project was to identify genes necessary for biophotolytic hydrogen production in green algae, using Chlamydomonas reinhardtii as an experimental organism. The main strategy was to isolate mutants that are selectively deficient in hydrogen production and to genetically map, physically isolate, and ultimately sequence the affected genes.

Mets, Laurens

2000-12-31T23:59:59.000Z

296

System Evaluation and Economic Analysis of a HTGR Powered High-Temperature Electrolysis Hydrogen Production Plant  

DOE Green Energy (OSTI)

A design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322C and 750C, respectively. The power conversion unit will be a Rankine steam cycle with a power conversion efficiency of 40%. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 40.4% at a hydrogen production rate of 1.75 kg/s and an oxygen production rate of 13.8 kg/s. An economic analysis of this plant was performed with realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.67/kg of hydrogen assuming an internal rate of return, IRR, of 12% and a debt to equity ratio of 80%/20%. A second analysis shows that if the power cycle efficiency increases to 44.4%, the hydrogen production efficiency increases to 42.8% and the hydrogen and oxygen production rates are 1.85 kg/s and 14.6 kg/s respectively. At the higher power cycle efficiency and an IRR of 12% the cost of hydrogen production is $3.50/kg.

Michael G. McKellar; Edwin A. Harvego; Anastasia A. Gandrik

2010-10-01T23:59:59.000Z

297

Hydrogen production by water dissociation using ceramic membranes - annual report for FY 2008.  

DOE Green Energy (OSTI)

The objective of this project is to develop dense ceramic membranes that, without using an external power supply or circuitry, can produce hydrogen via coal/coal gas-assisted water dissociation. This project grew from an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen production by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen by means of OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J.; Energy Systems

2009-03-25T23:59:59.000Z

298

Hydrogen production by water dissociation using ceramic membranes - annual report for FY 2010.  

DOE Green Energy (OSTI)

The objective of this project is to develop dense ceramic membranes that can produce hydrogen via coal/coal gas-assisted water dissociation without using an external power supply or circuitry. This project grew from an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen production by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen using OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J. (Energy Systems)

2011-03-14T23:59:59.000Z

299

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

for distributed power generation and/or hydrogen. Inpro- mote distributed power generation and stationary fuelthermal effi- ciency of power generation. Typical uses of

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

300

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

for vehicle refueling and compressed natural gas (CNG)for CNG vehicles, aswell as CNG/hydrogen blends (City of Las Vegas, 2002). Clean

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Methods and Systems for the Production of Hydrogen - Energy ...  

INL has developed a novel process for producing hydrogen using a reduced outlet temperature of Very High Temperature Gas Cooled Reactor. This process uses a ...

302

Hydrogen and Elemental Carbon Production from Natural Gas and ...  

... hydrogen fuel Applications and Industries Transportation and/or manufacturing industries; Industrial gas producers and/or oil and gas industry. ...

303

Increased Hydrogen Production by Genetic Engineering of Escherichia coli  

E-Print Network (OSTI)

Escherichia coli is capable of producing hydrogen under anaerobic growth conditions. Formate is converted to hydrogen in the fermenting cell by the formate hydrogenlyase enzyme system. The specific hydrogen yield from glucose was improved by the modification of transcriptional regulators and metabolic enzymes involved in the dissimilation of pyruvate and formate. The engineered E. coli strains ZF1 (DfocA; disrupted in a formate transporter gene) and ZF3 (DnarL; disrupted in a global transcriptional regulator gene) produced 14.9, and 14.4 mmols of hydrogen/mg of dry cell weight, respectively, compared to 9.8 mmols of hydrogen/mg of dry cell weight generated by wild-type E. coli strain W3110. The molar yield of hydrogen for strain ZF3 was 0.96 mols of hydrogen/mol of glucose, compared to 0.54 mols of hydrogen/mol of glucose for the wild-type E. coli strain. The expression of the global transcriptional regulator protein FNR at levels above natural abundance had a synergistic effect on increasing the hydrogen yield in the DfocA genetic background. The modification of global transcriptional regulators to modulate the expression of multiple operons required for the biosynthesis of formate

Zhanmin Fan; Ling Yuan; Ranjini Chatterjee

2008-01-01T23:59:59.000Z

304

Distributed Hydrogen Production from Natural Gas: Independent Review  

DOE Green Energy (OSTI)

Independent review report on the available information concerning the technologies needed for forecourts producing 150 kg/day of hydrogen from natural gas.

Fletcher, J.; Callaghan, V.

2006-10-01T23:59:59.000Z

305

Ceramic Membranes for Hydrogen/Oxygen Production - Energy ...  

Ceramic Membranes Developed at Argonne May Bring Fuel-Cell Cars Closer to Reality ... pure hydrogen for transportation and power applications from fossil fuels.

306

Method of production of pure hydrogen near room temperature from ...  

The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is ...

307

Sorption enhanced reaction process for production of hydrogen. Phase 1 final report  

SciTech Connect

Hydrogen is one of the most suitable energy sources from both technological and environmental perspectives for the next century, especially in the context of a sustainable global energy economy. The most common industrial process to produce high-purity (99.99+ mol%) hydrogen is to reform natural gas by a catalytic reaction with steam at a high temperature. Conventional steam-methane reforming (SMR) contributed to approximately 2.4 billion standard cubic feet per day (SCFD) of hydrogen production in the US. By 1998, the growth of SMR-produced hydrogen in the US is expected to reach 3.4 billion SCFD, with the increased demand attributed to hydrogen`s use in reformulated gasolines required by the Clean Air Act. The goal of this work is to develop an even more efficient process for reforming steam and methane to hydrogen product than the conventional SMR process. The application of Sorption Enhanced Reaction (SER) technology to SMR has the potential to markedly reduce the cost of hydrogen through lower capital and energy requirements. The development of a more cost-effective route to hydrogen production based on natural gas as the primary energy source will accelerate the transition to a more hydrogen-based economy in the future. The paper describes the process, which includes a sorbent for CO{sub 2} removal, and the various tasks involved in its development.

Mayorga, S.G.; Hufton, J.R.; Sircar, S.; Gaffney, T.R.

1997-07-01T23:59:59.000Z

308

Overview of US contributions to IEA hydrogen technology Task IV electrolytic hydrogen production  

SciTech Connect

US contributions derive largely from the US Department of Energy Chemical/Hydrogen Energy Storage Systems Program. The programmatic rationale, goals and focus, which reflect current US R and D policy and perceptions, are discussed as they influence the substance and pace of the R and D program in Hydrogen Technology. Contributions and future prospects are discussed briefly.

Mezzina, A.

1985-06-01T23:59:59.000Z

309

System for the co-production of electricity and hydrogen  

DOE Patents (OSTI)

Described herein is a system for the co-generation of hydrogen gas and electricity, wherein the proportion of hydrogen to electricity can be adjusted from 0% to 100%. The system integrates fuel cell technology for power generation with fuel-assisted steam-electrolysis. A hydrocarbon fuel, a reformed hydrocarbon fuel, or a partially reformed hydrocarbon fuel can be fed into the system.

Pham, Ai Quoc (San Jose, CA); Anderson, Brian Lee (Lodi, CA)

2007-10-02T23:59:59.000Z

310

Sustainable Energy Science and Engineering Center Hydrogen Production  

E-Print Network (OSTI)

component parts of hydrogen (H2) and oxygen (O). The most common method involves steam reforming of methane (from natural gas), although there are several other methods. · Steam reforming converts methane (and other hydrocarbons in natural gas) into hydrogen and carbon monoxide by reaction with steam over

Krothapalli, Anjaneyulu

311

On-site production of electrolytic hydrogen for generator cooling  

SciTech Connect

Hydrogen produced by water electrolysis could be cost effective over the merchant hydrogen used for generator cooling. Advanced water electrolyzers are being developed specifically for this utility application. These designs are based on solid-polymer-electrolyte and alkaline water electrolysis technologies. This paper describes the status of electrolyzer development and demonstration projects.

Mehta, B.

1982-08-01T23:59:59.000Z

312

Management of Leaks in Hydrogen Production, Delivery, and Storage Systems  

DOE Green Energy (OSTI)

A systematic approach to manage hydrogen leakage from components is presented. Methods to evaluate the quantity of hydrogen leakage and permeation from a system are provided by calculation and testing sensitivities. The following technology components of a leak management program are described: (1) Methods to evaluate hydrogen gas loss through leaks; (2) Methods to calculate opening areas of crack like defects; (3) Permeation of hydrogen through metallic piping; (4) Code requirements for acceptable flammability limits; (5) Methods to detect flammable gas; (6) Requirements for adequate ventilation in the vicinity of the hydrogen system; (7) Methods to calculate dilution air requirements for flammable gas mixtures; and (8) Concepts for reduced leakage component selection and permeation barriers.

Rawls, G

2006-04-27T23:59:59.000Z

313

Economic Analysis of a Nuclear Reactor Powered High-Temperature Electrolysis Hydrogen Production Plant  

DOE Green Energy (OSTI)

A reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production was developed to provide a basis for comparing the HTE concept with other hydrogen production concepts. The reference plant design is driven by a high-temperature helium-cooled nuclear reactor coupled to a direct Brayton power cycle. The reference design reactor power is 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 540C and 900C, respectively. The electrolysis unit used to produce hydrogen includes 4,009,177 cells with a per-cell active area of 225 cm2. The optimized design for the reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes an air-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The inlet air for the air-sweep system is compressed to the system operating pressure of 5.0 MPa in a four-stage compressor with intercooling. The alternating-current, AC, to direct-current, DC, conversion efficiency is 96%. The overall system thermal-to-hydrogen production efficiency (based on the lower heating value of the produced hydrogen) is 47.12% at a hydrogen production rate of 2.356 kg/s. An economic analysis of this plant was performed using the standardized H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program, and using realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.23/kg of hydrogen was calculated assuming an internal rate of return of 10%.

E. A. Harvego; M. G. McKellar; M. S. Sohal; J. E. O'Brien; J. S. Herring

2008-08-01T23:59:59.000Z

314

Economic comparison of hydrogen production using sulfuric acid electrolysis and sulfur cycle water decomposition. Final report  

SciTech Connect

An evaluation of the relative economics of hydrogen production using two advanced techniques was performed. The hydrogen production systems considered were the Westinghouse Sulfur Cycle Water Decomposition System and a water electrolysis system employing a sulfuric acid electrolyte. The former is a hybrid system in which hydrogen is produced in an electrolyzer which uses sulfur dioxide to depolarize the anode. The electrolyte is sulfuric acid. Development and demonstration efforts have shown that extremely low cell voltages can be achieved. The second system uses a similar sulfuric acid electrolyte technology in water electrolysis cells. The comparative technoeconomics of hydrogen produced by the hybrid Sulfur Cycle and by water electrolysis using a sulfuric acid electrolyte were determined by assessing the performance and economics of 380 million SCFD plants, each energized by a very high temperature nuclear reactor (VHTR). The evaluation concluded that the overall efficiencies of hydrogen production, for operating parameters that appear reasonable for both systems, are approximately 41% for the sulfuric acid electrolysis and 47% for the hybrid Sulfur Cycle. The economic evaluation of hydrogen production, based on a 1976 cost basis and assuming a developed technology for both hydrogen production systems and the VHTRs, indicated that the hybrid Sulfur Cycle could generate hydrogen for a total cost approximately 6 to 7% less than the cost from the sulfuric acid electrolysis plant.

Farbman, G.H.; Krasicki, B.R.; Hardman, C.C.; Lin, S.S.; Parker, G.H.

1978-06-01T23:59:59.000Z

315

Estimating Hydrogen Production Potential in Biorefineries Using Microbial Electrolysis Cell Technology  

Science Conference Proceedings (OSTI)

Microbial electrolysis cells (MECs) are devices that use a hybrid biocatalysis-electrolysis process for production of hydrogen from organic matter. Future biofuel and bioproducts industries are expected to generate significant volumes of waste streams containing easily degradable organic matter. The emerging MEC technology has potential to derive added- value from these waste streams via production of hydrogen. Biorefinery process streams, particularly the stillage or distillation bottoms contain underutilized sugars as well as fermentation and pretreatment byproducts. In a lignocellulosic biorefinery designed for producing 70 million gallons of ethanol per year, up to 7200 m3/hr of hydrogen can be generated. The hydrogen can either be used as an energy source or a chemical reagent for upgrading and other reactions. The energy content of the hydrogen generated is sufficient to meet 57% of the distillation energy needs. We also report on the potential for hydrogen production in existing corn mills and sugar-based biorefineries. Removal of the organics from stillage has potential to facilitate water recycle. Pretreatment and fermentation byproducts generated in lignocellulosic biorefinery processes can accumulate to highly inhibitory levels in the process streams, if water is recycled. The byproducts of concern including sugar- and lignin- degradation products such as furans and phenolics can also be converted to hydrogen in MECs. We evaluate hydrogen production from various inhibitory byproducts generated during pretreatment of various types of biomass. Finally, the research needs for development of the MEC technology and aspects particularly relevant to the biorefineries are discussed.

Borole, Abhijeet P [ORNL; Mielenz, Jonathan R [ORNL

2011-01-01T23:59:59.000Z

316

Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: Spring 2009; Composite Data Products, Final Version March 19, 2009  

DOE Green Energy (OSTI)

Graphs of composite data products produced by DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation project through March 2009.

Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.

2009-03-01T23:59:59.000Z

317

Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project; Spring 2008 Composite Data Products, Final Version: February 29, 2008  

DOE Green Energy (OSTI)

Graphs of composite data products produced by DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation project through February 2008.

Wipke, K.; Sprik, S.; Kurtz J.

2008-04-01T23:59:59.000Z

318

Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: Fall 2009; Composite Data Products, Final Version September 11, 2009  

DOE Green Energy (OSTI)

Graphs of composite data products produced by DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation project through September 2009.

Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.

2009-09-01T23:59:59.000Z

319

Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: Spring 2010; Composite Data Products, Final Version March 29, 2010  

SciTech Connect

Graphs of composite data products produced by DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation project through March 2010.

Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.

2010-05-01T23:59:59.000Z

320

Analytical approaches to photobiological hydrogen production in unicellular green algae  

E-Print Network (OSTI)

photosynthesis in renewable energy production. This articlebe applied in renewable energy production. In addition, the

Hemschemeier, Anja; Melis, Anastasios; Happe, Thomas

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

HYDROGEN PRODUCTION AND DELIVERY INFRASTRUCTURE AS A COMPLEX ADAPTIVE SYSTEM  

Science Conference Proceedings (OSTI)

An agent-based model of the transition to a hydrogen transportation economy explores influences on adoption of hydrogen vehicles and fueling infrastructure. Attention is given to whether significant penetration occurs and, if so, to the length of time required for it to occur. Estimates are provided of sensitivity to numerical values of model parameters and to effects of alternative market and policy scenarios. The model is applied to the Los Angeles metropolitan area In the benchmark simulation, the prices of hydrogen and non-hydrogen vehicles are comparable. Due to fuel efficiency, hydrogen vehicles have a fuel savings advantage of 9.8 cents per mile over non-hydrogen vehicles. Hydrogen vehicles account for 60% of new vehicle sales in 20 years from the initial entry of hydrogen vehicles into show rooms, going on to 86% in 40 years and reaching still higher values after that. If the fuel savings is 20.7 cents per mile for a hydrogen vehicle, penetration reaches 86% of new car sales by the 20th year. If the fuel savings is 0.5 cents per mile, market penetration reaches only 10% by the 20th year. To turn to vehicle price difference, if a hydrogen vehicle costs $2,000 less than a non-hydrogen vehicle, new car sales penetration reaches 92% by the 20th year. If a hydrogen vehicle costs $6,500 more than a non-hydrogen vehicle, market penetration is only 6% by the 20th year. Results from other sensitivity runs are presented. Policies that could affect hydrogen vehicle adoption are investigated. A tax credit for the purchase of a hydrogen vehicle of $2,500 tax credit results in 88% penetration by the 20th year, as compared with 60% in the benchmark case. If the tax credit is $6,000, penetration is 99% by the 20th year. Under a more modest approach, the tax credit would be available only for the first 10 years. Hydrogen sales penetration then reach 69% of sales by the 20th year with the $2,500 credit and 79% with the $6,000 credit. A carbon tax of $38 per metric ton is not large enough to noticeably affect sales penetration. A tax of $116 per metric ton makes centrally produced hydrogen profitable in the very first year but results in only 64% penetration by year 20 as opposed to the 60% penetration in the benchmark case. Provision of 15 seed stations publicly provided at the beginning of the simulation, in addition to the 15 existing stations in the benchmark case, gives sales penetration rates very close to the benchmark after 20 years, namely, 63% and 59% depending on where they are placed.

Tolley, George S

2010-06-29T23:59:59.000Z

322

Production economics for hydrogen, ammonia, and methanol during the 1980--2000 period  

SciTech Connect

Refinery hydrogen, ammonia, and methanol, the principal industrial hydrogen products, are now manufactured mainly by catalytic steam reforming of natural gas or some alternative light-hydrocarbon feed stock. Anticipated increases in the prices of hydrocarbons are expected to exceed those for coal, thus gradually increasing the incentive to use coal gasification as a source of industrial hydrogen during the 1980 to 2000 period. Although the investment in industrial hydrogen plants will exceed those for reforming by a factor of 2 or more, coal gasification will provide lower production costs (including 20%/y before tax return) for methanol manufacture in the early 1980's and for ammonia 5 years or so later. However, high costs for transporting coal to major refining centers will make it difficult to justify coal gasification for refinery hydrogen production during the 1980 to 2000 period. By the year 2000, 40 to 50% of the U.S. industrial hydrogen requirements will be provided by coal gasification thus conserving natural gas and light hydrocarbon feed stocks equivalent to about 600,000 B/D of crude oil. Electrolytic hydrogen production costs will be reduced by improved electrolysis technology such as the solid-polymer-electrolyte process. These improved processes will reduce electrolysis plant investments by a factor of 2 or more and reduce electricity requirements by about 20%. Although the production cost, including return for electrolytic hydrogen, will continue to exceed those for reforming and coal gasification, the use of electrolytic hydrogen will be attractive for many small users when the new technology is available in the early 1980's. Electrolytic hydrogen now about 0.7% of total U.S. industrial hydrogen requirements will probably increase to about 1.2% of the total by the year 2000.

Corneil, H G; Heinzelmann, F J; Nicholson, E W.S.

1977-04-01T23:59:59.000Z

323

High-yield hydrogen production by catalytic gasification of coal or biomass  

DOE Green Energy (OSTI)

Gasification of coal or wood, catalyzed by soluble metallic cations to maximize reaction rates and hydrogen yields, offers a potential for large-scale, economical hydrogen production with near-commercial technology. With optimum reaction conditions and catalysts, product gas rich in both hydrogen and methane can be used in fuel cells to produce electricity at efficiencies nearly double those of conventional power plant. If plantation silvaculture techniques can produce wood at a raw energy cost competitive with coal, further enhancement of product gas yields may be possible, with zero net contribution of CO{sub 2} to the atmosphere.

Hauserman, W.B.

1992-01-01T23:59:59.000Z

324

Enhanced Hydrogen Production Integrated with CO2 Separation in a Single-Stage Reactor  

NLE Websites -- All DOE Office Websites (Extended Search)

EnhancEd hydrogEn Production EnhancEd hydrogEn Production intEgratEd with co 2 SEParation in a SinglE-StagE rEactor Description One alternative for the United States to establish independence from foreign energy sources is to utilize the nation's abundant domestic reserves of coal. Gasification provides a route to produce liquid fuels, chemical feedstocks, and hydrogen from coal. Coal continues to be viewed as the fuel source for the 21st century. Products from coal gasification, however, contain other gases, particularly carbon dioxide, as well as other contaminants that must be removed to produce the pure stream of hydrogen needed to operate fuel cells and other devices. This project seeks to demonstrate a technology to efficiently produce a pure hydrogen stream from

325

Performance requirements of an inertial-fusion-energy source for hydrogen production  

DOE Green Energy (OSTI)

Performance of an inertial fusion system for the production of hydrogen is compared to a tandem-mirror-system hydrogen producer. Both systems use the General Atomic sulfur-iodine hydrogen-production cycle and produce no net electric power to the grid. An ICF-driven hydrogen producer will have higher system gains and lower electrical-consumption ratios than the design point for the tandem-mirror system if the inertial-fusion-energy gain eta Q > 8.8. For the ICF system to have a higher hydrogen production rate per unit fusion power than the tandem-mirror system requires that eta Q > 17. These can be achieved utilizing realistic laser and pellet performances.

Hovingh, J.

1983-01-01T23:59:59.000Z

326

Solar photoproduction of hydrogen. IEA technical report of the IEA Agreement of the Production and Utilization of Hydrogen  

DOE Green Energy (OSTI)

The report was prepared for the International Energy Agency (IEA) Hydrogen Program and represents the result of subtask C, Annex 10 - Photoproduction of Hydrogen. The concept of using solar energy to drive the conversion of water into hydrogen and oxygen has been examined, from the standpoints of potential and ideal efficiencies, measurement of (and how to calculate) solar hydrogen production efficiencies, a survey of the state-of-the-art, and a technological assessment of various solar hydrogen options. The analysis demonstrates that the ideal limit of the conversion efficiency for 1 sun irradiance is {approximately}31% for a single photosystem scheme and {approximately}42% for a dual photosystem scheme. However, practical considerations indicate that real efficiencies will not likely exceed {approximately}10% and {approximately}16% for single and dual photosystem schemes, respectively. Four types of solar photochemical hydrogen systems have been identified: photochemical systems, semiconductor systems, photobiological systems, and hybrid and other systems. A survey of the state-of-the-art of these four types is presented. The four types (and their subtypes) have also been examined in a technological assessment, where each has been examined as to efficiency, potential for improvement, and long-term functionality. Four solar hydrogen systems have been selected as showing sufficient promise for further research and development: (1) Photovoltaic cells plus an electrolyzer; (2) Photoelectrochemical cells with one or more semiconductor electrodes; (3) Photobiological systems; and (4) Photodegradation systems. The following recommendations were presented for consideration of the IEA: (1) Define and measure solar hydrogen conversion efficiencies as the ratio of the rate of generation of Gibbs energy of dry hydrogen gas (with appropriate corrections for any bias power) to the incident solar power (solar irradiance times the irradiated area); (2) Expand support for pilot-plant studies of the PV cells plus electrolyzer option with a view to improving the overall efficiency and long-term stability of the system. Consideration should be given, at an appropriate time, to a full-scale installation as part of a solar hydrogen-based model community; (3) Accelerate support, at a more fundamental level for the development of photoelectrochemical cells, with a view to improving efficiency, long-term performance and multi-cell systems for non-biased solar water splitting; (4) Maintain and increase support for fundamental photobiological research with the aim of improving long-term stability, increasing efficiencies and engineering genetic changes to allow operation at normal solar irradiances; and (5) Initiate a research program to examine the feasibility of coupling hydrogen evolution to the photodegradation of waste or polluting organic substances.

Bolton, J.R. [Dept. of Chemistry, Univ. of Western Ontario, London, Ontario (CA) N6A 5B7

1996-09-30T23:59:59.000Z

327

Hydrogen production by water electrolysis: present status and future prospects  

SciTech Connect

Development of advanced alkaline water electrolysis cells operating at 120-150/sup 0/C, electrocatalysis of the hydrogen and oxygen evolution reactions, and development of solid polymer electrolyte water electrolysis cell are discussed. (LK)

Srinivasan, S.

1976-01-01T23:59:59.000Z

328

Technical Analysis of Hydrogen Production: Evaluation of H2 Mini-Grids  

SciTech Connect

We have assessed the transportation of hydrogen as a metal hydride slurry through pipelines over a short distance from a neighborhood hydrogen production facility to local points of use. The assessment was conducted in the context of a hydrogen "mini-grid" serving both vehicle fueling and stationary fuel cell power systems for local building heat and power. The concept was compared to a compressed gaseous hydrogen mini-grid option and to a stand-alone hydrogen fueling station. Based on our analysis results we have concluded that the metal hydride slurry concept has potential to provide significant reductions in overall energy use compared to liquid or chemical hydride delivery, but only modest reductions in overall energy use, hydrogen cost, and GHG emissions compared to a compressed gaseous hydrogen delivery. However, given the inherent (and perceived) safety and reasonable cost/efficiency of the metal hydride slurry systems, additional research and analysis is warranted. The concept could potentially overcome the public acceptance barrier associated with the perceptions about hydrogen delivery (including liquid hydrogen tanker trucks and high-pressure gaseous hydrogen pipelines or tube trailers) and facilitate the development of a near-term hydrogen infrastructure.

Lasher, Stephen; Sinha, Jayanti

2005-05-03T23:59:59.000Z

329

Chemical Hydride Slurry for Hydrogen Production and Storage  

DOE Green Energy (OSTI)

?\tDuring the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

McClaine, Andrew W.

2008-09-30T23:59:59.000Z

330

Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios  

DOE Green Energy (OSTI)

Report of levelized cost in 2005 U.S. dollars, energy use, and GHG emission benefits of seven hydrogen production, delivery, and distribution pathways.

Ruth, M.; Laffen, M.; Timbario, T. A.

2009-09-01T23:59:59.000Z

331

Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios  

Fuel Cell Technologies Publication and Product Library (EERE)

Report of levelized cost in 2005 U.S. dollars, energy use, and GHG emission benefits of seven hydrogen production, delivery, and distribution pathways.

332

Catalysts for hydrogen production by steam reforming of dimethyl ether (DME)  

Science Conference Proceedings (OSTI)

Dimethyl ether (DME) is expected as one of clean fuels. We have been studying on DME steam reforming for hydrogen production. Copper alumina catalysts prepared by a sol-gel method produced large quantities of H2 with DME steam reforming. The reason was ... Keywords: DME, alumina, catalyst, clean fuel, copper, dimethyl ether, hydrogen, sol-gel method, steam reforming

Kaoru Takeishi

2010-02-01T23:59:59.000Z

333

Development of single type copper alumina catalysts for hydrogen production from dimethyl ether (DME)  

Science Conference Proceedings (OSTI)

Dimethyl ether (DME) is expected as one of clean fuels. We have been studying on DME steam reforming for hydrogen production. Copper alumina catalysts prepared by the sol-gel method produced large quantities of H2 with DME steam reforming. Aiming at ... Keywords: DME, alumina, catalyst, clean fuel, copper, dimethyl ether, hydrogen, sol-gel method, steam reforming

Kaoru Takeishi; Atsushi Ban

2010-02-01T23:59:59.000Z

334

Production of hydrogen in non oxygen-evolving systems: co-produced hydrogen as a bonus in the photodegradation of organic pollutants and hydrogen sulfide  

DOE Green Energy (OSTI)

This report was prepared as part of the documentation of Annex 10 (Photoproduction of Hydrogen) of the IEA Hydrogen Agreement. Subtask A of this Annex concerned photo-electrochemical hydrogen production, with an emphasis on direct water splitting. However, studies of non oxygen-evolving systems were also included in view of their interesting potential for combined hydrogen production and waste degradation. Annex 10 was operative from 1 March 1995 until 1 October 1998. One of the collaborative projects involved scientists from the Universities of Geneva and Bern, and the Federal Institute of Technology in Laussane, Switzerland. A device consisting of a photoelectrochemical cell (PEC) with a WO{sub 3} photoanode connected in series with a so-called Grazel cell (a dye sensitized liquid junction photovoltaic cell) was developed and studied in this project. Part of these studies concerned the combination of hydrogen production with degradation of organic pollutants, as described in Chapter 3 of this report. For completeness, a review of the state of the art of organic waste treatment is included in Chapter 2. Most of the work at the University of Geneva, under the supervision of Prof. J. Augustynski, was focused on the development and testing of efficient WO{sub 3} photoanodes for the photoelectrochemical degradation of organic waste solutions. Two types of WO{sub 3} anodes were developed: non transparent bulk photoanodes and non-particle-based transparent film photoanodes. Both types were tested for degradation and proved to be very efficient in dilute solutions. For instance, a solar-to-chemical energy conversion efficiency of 9% was obtained by operating the device in a 0.01M solution of methanol (as compared to about 4% obtained for direct water splitting with the same device). These organic compounds are oxidized to CO{sub 2} by the photocurrent produced by the photoanode. The advantages of this procedure over conventional electrolytic degradation are that much (an order of magnitude) less energy is required and that sunlight can be used directly. In the case of photoproduction of hydrogen, as compared to water splitting, feeding the anodic compartment of the PEC with an organic pollutant, instead of the usual supporting electrolyte, will bring about a substantial increase of the photocurrent at a given illumination. Thus, the replacement of the photo-oxidation of water by the photodegradation of organic waste will be accompanied by a gain in solar-to-chemical conversion efficiency and hence by a decrease in the cost of the photoproduced hydrogen. Taking into account the benefits and possible revenues obtainable by the waste degradation, this would seem to be a promising approach to the photoproduction of hydrogen. Hydrogen sulfide (H{sub 2}S) is another waste effluent requiring extensive treatment, especially in petroleum refineries. The so-called Claus process is normally used to convert the H{sub 2}S to elemental sulfur. A sulfur recovery process developed at the Florida Solar Energy Center is described briefly in Chapter 4 by Dr. C. Linkous as a typical example of the photoproduction of hydrogen in a non oxygen-evolving system. The encouraging results obtained in these investigations of photoelectrochemical hydrogen production combined with organic waste degradation, have prompted a decision to continue the work under the new IEA Hydrogen Agreement Annex 14, Photoelectrolytic Hydrogen Production.

Sartoretti, C. Jorand; Ulmann, M.; Augustynski, J. (Electrochemistry Laboratory, Department of Chemistry, University of Geneva (CH)); Linkous, C.A. (Florida Solar Energy Center, University of Central Florida (US))

2000-01-01T23:59:59.000Z

335

Analysis of Improved Reference Design for a Nuclear-Driven High Temperature Electrolysis Hydrogen Production Plant  

SciTech Connect

The use of High Temperature Electrolysis (HTE) for the efficient production of hydrogen without the greenhouse gas emissions associated with conventional fossil-fuel hydrogen production techniques has been under investigation at the Idaho National Engineering Laboratory (INL) for the last several years. The activities at the INL have included the development, testing and analysis of large numbers of solid oxide electrolysis cells, and the analyses of potential plant designs for large scale production of hydrogen using an advanced Very-High Temperature Reactor (VHTR) to provide the process heat and electricity to drive the electrolysis process. The results of these system analyses, using the UniSim process analysis software, have shown that the HTE process, when coupled to a VHTR capable of operating at reactor outlet temperatures of 800 C to 950 C, has the potential to produce the large quantities of hydrogen needed to meet future energy and transportation needs with hydrogen production efficiencies in excess of 50%. In addition, economic analyses performed on the INL reference plant design, optimized to maximize the hydrogen production rate for a 600 MWt VHTR, have shown that a large nuclear-driven HTE hydrogen production plant can to be economically competitive with conventional hydrogen production processes, particularly when the penalties associated with greenhouse gas emissions are considered. The results of this research led to the selection in 2009 of HTE as the preferred concept in the U.S. Department of Energy (DOE) hydrogen technology down-selection process. However, the down-selection process, along with continued technical assessments at the INL, has resulted in a number of proposed modifications and refinements to improve the original INL reference HTE design. These modifications include changes in plant configuration, operating conditions and individual component designs. This paper describes the resulting new INL reference design and presents results of system analyses performed to optimize the design and to determine required plant performance and operating conditions.

Edwin A. Harvego; James E. O' Brien; Michael G. McKellar

2010-06-01T23:59:59.000Z

336

Ni-Si Alloys for the S-I Reactor-Hydrogen Production Process Interface  

DOE Green Energy (OSTI)

The overall goal of this project was to develop Ni-Si alloys for use in vessels to contain hot, pressurized sulfuric acid. The application was to be in the decomposition loop of the thermochemical cycle for production of hydrogen.

Joseph W. Newkirk; Richard K. Brow

2010-01-21T23:59:59.000Z

337

Modelling and Experimental Study of Methane Catalytic Cracking as a Hydrogen Production Technology.  

E-Print Network (OSTI)

??Production of hydrogen is primarily achieved via catalytic steam reforming, partial oxidation,and auto-thermal reforming of natural gas. Although these processes are mature technologies, they are (more)

Amin, Ashraf Mukhtar Lotfi

2011-01-01T23:59:59.000Z

338

PLUTONIUM-HYDROGEN REACTION PRODUCT, METHOD OF PREPARING SAME AND PLUTONIUM POWDER THEREFROM  

DOE Patents (OSTI)

A process is described for forming plutonlum hydride powder by reacting hydrogen with massive plutonium metal at room temperature and the product obtained. The plutonium hydride powder can be converted to plutonium powder by heating to above 200 deg C.

Fried, S.; Baumbach, H.L.

1959-12-01T23:59:59.000Z

339

Analyzing Natural Gas Based Hydrogen Infrastructure - Optimizing Transitions from Distributed to Centralized H2 Production  

E-Print Network (OSTI)

Station Storage Storage Cost $500/kg Natural gas feedstocknatural gas steam methane reforming (SMR) includes hydrogen production and storagefor storage, distribution or use H 2 Natural gas Figure 3

Yang, Christopher; Ogden, Joan M

2005-01-01T23:59:59.000Z

340

U.S. Refinery Hydrogen Production Capacity as of January 1 ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Hydrogen Production Capacity as of January 1 (Million Cubic Feet per Day) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 ...

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Hydrogen production during processing of radioactive sludge containing noble metals  

DOE Green Energy (OSTI)

Hydrogen was produced when radioactive sludge from Savannah River Site radioactive waste containing noble metals was reacted with formic acid. This will occur in a process tank in the Defense Waste Facility at SRS when waste is vitrified. Radioactive sludges from four tanks were tested in a lab-scale apparatus. Maximum hydrogen generation rates varied from 5 {times}10{sup {minus}7} g H{sub 2}/hr/g of sludge from the least reactive sludge (from Waste Tank 51) to 2 {times}10{sup {minus}4} g H{sub 2}/hr/g of sludge from the most reactive sludge (from Waste Tank 11). The time required for the hydrogen generation to reach a maximum varied from 4.1 to 25 hours. In addition to hydrogen, carbon dioxide and nitrous oxide were produced and the pH of the reaction slurry increased. In all cases, the carbon dioxide and nitrous oxide were generated before the hydrogen. The results are in agreement with large-scale studies using simulated sludges.

Ha, B.C.; Ferrara, D.M.; Bibler, N.E.

1992-01-01T23:59:59.000Z

342

Hydrogen production during processing of radioactive sludge containing noble metals  

DOE Green Energy (OSTI)

Hydrogen was produced when radioactive sludge from Savannah River Site radioactive waste containing noble metals was reacted with formic acid. This will occur in a process tank in the Defense Waste Facility at SRS when waste is vitrified. Radioactive sludges from four tanks were tested in a lab-scale apparatus. Maximum hydrogen generation rates varied from 5 {times}10{sup {minus}7} g H{sub 2}/hr/g of sludge from the least reactive sludge (from Waste Tank 51) to 2 {times}10{sup {minus}4} g H{sub 2}/hr/g of sludge from the most reactive sludge (from Waste Tank 11). The time required for the hydrogen generation to reach a maximum varied from 4.1 to 25 hours. In addition to hydrogen, carbon dioxide and nitrous oxide were produced and the pH of the reaction slurry increased. In all cases, the carbon dioxide and nitrous oxide were generated before the hydrogen. The results are in agreement with large-scale studies using simulated sludges.

Ha, B.C.; Ferrara, D.M.; Bibler, N.E.

1992-09-01T23:59:59.000Z

343

Thermochemical production of hydrogen from water, a critical review  

DOE Green Energy (OSTI)

The current status of thermochemical hydrogen technology as regards process chemistry, preliminary chemical engineering design and techno-economics for a number of cycles undergoing active research and development efforts throughout the world at this time is assessed. Three cycles are receiving the bulk of the total effort and most of the funding: the hybrid sulfuric acid cycle; the sulfuric acid-hydrogen iodide cycle; and the hybrid sulfuric acid-hydrogen bromide cycle (Mark 13) . All three cycles are at the stage where a laboratory scale continuous plant can be or is in operation. The only plant in operation is at Ispra, Italy on the Mark 13 cycle. Materials problems are endemic to all cycles. In most cases reference materials for the sulfuric acid vaporization stages and the sulfuric acid or sulfur trioxide decomposition vessels have not yet been defined. A prime difficulty is the need for the vessel walls to transmit heat to interior fluids as well as withstand their corrosive effects. Serious efforts must be undertaken in the materials area prior to demonstration of any of the sulfuric acid-based cycles on a pilot plant scale under realistic pressure (30 atm) and temperature conditions. Improvements are being made in estimating the cost and efficiency of hydrogen produced from water and a thermal energy source either by thermochemical cycle technology or by water electrolysis. These include the heat penalty analysis and the OPTIMO computer code. Costs of thermochemical hydrogen have been found to fall in the $7 to $10/10/sup 16/ Btu range with efficiencies in the 35 to 45% bracket. A 10 to 15 year developmental effort with increased funding of both options (thermochemical and water electrolysis) should find a clear-cut solution and resolve the situation of the ''best'' option to use for producing synthetic hydrogen from water.

Cox, K.

1978-01-01T23:59:59.000Z

344

LARGE-SCALE HYDROGEN PRODUCTION FROM NUCLEAR ENERGY USING HIGH TEMPERATURE ELECTROLYSIS  

DOE Green Energy (OSTI)

Hydrogen can be produced from water splitting with relatively high efficiency using high-temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high-temperature process heat. When coupled to an advanced high temperature nuclear reactor, the overall thermal-to-hydrogen efficiency for high-temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. Demand for hydrogen is increasing rapidly for refining of increasingly low-grade petroleum resources, such as the Athabasca oil sands and for ammonia-based fertilizer production. Large quantities of hydrogen are also required for carbon-efficient conversion of biomass to liquid fuels. With supplemental nuclear hydrogen, almost all of the carbon in the biomass can be converted to liquid fuels in a nearly carbon-neutral fashion. Ultimately, hydrogen may be employed as a direct transportation fuel in a hydrogen economy. The large quantity of hydrogen that would be required for this concept should be produced without consuming fossil fuels or emitting greenhouse gases. An overview of the high-temperature electrolysis technology will be presented, including basic theory, modeling, and experimental activities. Modeling activities include both computational fluid dynamics and large-scale systems analysis. We have also demonstrated high-temperature electrolysis in our laboratory at the 15 kW scale, achieving a hydrogen production rate in excess of 5500 L/hr.

James E. O'Brien

2010-08-01T23:59:59.000Z

345

Global Assessment of Hydrogen Technologies Tasks 3 & 4 Report Economic, Energy, and Environmental Analysis of Hydrogen Production and Delivery Options in Select Alabama Markets: Preliminary Case Studies  

Science Conference Proceedings (OSTI)

This report documents a set of case studies developed to estimate the cost of producing, storing, delivering, and dispensing hydrogen for light-duty vehicles for several scenarios involving metropolitan areas in Alabama. While the majority of the scenarios focused on centralized hydrogen production and pipeline delivery, alternative delivery modes were also examined. Although Alabama was used as the case study for this analysis, the results provide insights into the unique requirements for deploying hydrogen infrastructure in smaller urban and rural environments that lie outside the DOEs high priority hydrogen deployment regions. Hydrogen production costs were estimated for three technologies steam-methane reforming (SMR), coal gasification, and thermochemical water-splitting using advanced nuclear reactors. In all cases examined, SMR has the lowest production cost for the demands associated with metropolitan areas in Alabama. Although other production options may be less costly for larger hydrogen markets, these were not examined within the context of the case studies.

Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Gillette, Jerry; Elgowainy, Amgad; Mintz, Marianne

2007-12-01T23:59:59.000Z

346

Methane-methanol cycle for the thermochemical production of hydrogen  

DOE Patents (OSTI)

A thermochemical reaction cycle for the generation of hydrogen from water comprising the following sequence of reactions wherein M represents a metal: CH.sub.4 + H.sub.2 O .fwdarw. CO + 3H.sub.2 (1) co + 2h.sub.2 .fwdarw. ch.sub.3 oh (2) ch.sub.3 oh + so.sub.2 + mo .fwdarw. mso.sub.4 + ch.sub.4 (3) mso.sub.4 .fwdarw. mo + so.sub.2 + 1/2o.sub.2 (4) the net reaction is the decomposition of water into hydrogen and oxygen.

Dreyfuss, Robert M. (Mount Vernon, NY); Hickman, Robert G. (Livermore, CA)

1976-01-01T23:59:59.000Z

347

Updated Cost Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report  

DOE Green Energy (OSTI)

This report updates the 1999 economic analysis of NREL's photobiological hydrogen production from Chlamydomonas reinhardtii. The previous study had looked mainly at incident light intensities, batch cycles and light adsorption without directly attempting to model the saturation effects seen in algal cultures. This study takes a more detailed look at the effects that cell density, light adsorption and light saturation have on algal hydrogen production. Performance estimates based on actual solar data are also included in this study. Based on this analysis, the estimated future selling price of hydrogen produced from algae ranges $0.57/kg to $13.53/kg.

Amos, W. A.

2004-01-01T23:59:59.000Z

348

Hydrogen and elemental carbon production from natural gas and other hydrocarbons  

DOE Patents (OSTI)

Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

349

FEASIBILITY OF HYDROGEN PRODUCTION USING LASER INERTIAL FUSION AS THE PRIMARY ENERGY SOURCE  

DOE Green Energy (OSTI)

The High Average Power Laser (HAPL) program is developing technology for Laser IFE with the goal of producing electricity from the heat generated by the implosion of deuterium-tritium (DT) targets. Alternatively, the Laser IFE device could be coupled to a hydrogen generation system where the heat would be used as input to a water-splitting process to produce hydrogen and oxygen. The production of hydrogen in addition to electricity would allow fusion energy plants to address a much wider segment of energy needs, including transportation. Water-splitting processes involving direct and hybrid thermochemical cycles and high temperature electrolysis are currently being developed as means to produce hydrogen from high temperature nuclear fission reactors and solar central receivers. This paper explores the feasibility of this concept for integration with a Laser IFE plant, and it looks at potential modifications to make this approach more attractive. Of particular interest are: (1) the determination of the advantages of Laser IFE hydrogen production compared to other hydrogen production concepts, and (2) whether a facility of the size of FTF would be suitable for hydrogen production.

Gorensek, M

2006-11-03T23:59:59.000Z

350

Production of low-cost hydrogen. Final report, September 1989--August 1993  

DOE Green Energy (OSTI)

Significant technical progress has been made over the last decade to develop efficient processes for upgrading coal resources to distillable hydrocarbons which may be used to displace petroleum-derived fuels. While several different direct coal liquefaction routes are under investigation, each of them have in common the need for large quantities of hydrogen to convert the aromatic coal matrix to liquid products in the normal distillation range, and for hydrotreating to improve liquid product quality. In fact, it has been estimated that the production, recovery, and efficient use of hydrogen accounts for over 50 percent of the capital cost of the liquefaction facility. For this reason, improved methods for producing low-cost hydrogen are essential to the operating economics of the liquefaction process. This Final Report provides an assessment of the application of the MTCI indirect gasification technology for the production of low-cost hydrogen from coal feedstocks. The MTCI gasification technology is unique in that it overcomes many of the problems and issues associated with direct and other indirectly heated coal gasification systems. Although the MTCI technology can be utilized for producing hydrogen from almost any carbonaceous feedstock (fossil, biomass and waste), this report presents the results of an experimental program sponsored by the Department of Energy, Morgantown Energy Research Center, to demonstrate the production of hydrogen from coal, mild gasification chars, and liquefaction bottoms.

Not Available

1993-06-01T23:59:59.000Z

351

Hydrogen production by water dissociation using ceramic membranes. Annual report for FY 2007.  

DOE Green Energy (OSTI)

The objective of this project is to develop dense ceramic membranes that, without using an external power supply or circuitry, can produce hydrogen via coal/coal gas-assisted water dissociation. This project grew out of an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions [1]. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen to be produced by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting [1, 2]. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen by means of OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

Balachandran, U.; Chen, L.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Park, C. Y.; Picciolo, J. J.; Song, S. J.; Energy Systems

2008-03-04T23:59:59.000Z

352

Process modeling of hydrogen production from municipal solid waste  

DOE Green Energy (OSTI)

The ASPEN PLUS commercial simulation software has been used to develop a process model for a conceptual process to convert municipal solid waste (MSW) to hydrogen. The process consists of hydrothermal treatment of the MSW in water to create a slurry suitable as feedstock for an oxygen blown Texaco gasifier. A method of reducing the complicated MSW feed material to a manageable set of components is outlined along with a framework for modeling the stoichiometric changes associated with the hydrothermal treatment process. Model results indicate that 0.672 kmol/s of hydrogen can be produced from the processing of 30 kg/s (2600 tonne/day) of raw MSW. A number of variations on the basic processing parameters are explored and indicate that there is a clear incentive to reduce the inert fraction in the processed slurry feed and that cofeeding a low value heavy oil may be economically attractive.

Thorsness, C.B.

1995-01-01T23:59:59.000Z

353

Hydrogen Production via a Commercially Ready Inorganic membrane Reactor  

DOE Green Energy (OSTI)

One of the technical barriers for ceramic membranes is its scale up potential. The conventional ceramic membranes/modules originally developed for liquid phase applications are costly and not suitable for high temperature applications. One of the objectives under this project is the development of a ceramic membrane/module, which is economical and suitable for high temperature applications proposed under this project (200-300 C). During this period, we initiated the fabrication of a prototype ceramic membrane module which can be (1) qualified for the proposed application temperature, and (2) cost acceptable for large scale applications. A prototype ceramic membrane bundle (3-inch diameter and 35-inch L) has been prepared, which passes the temperature stability requirement. It also meets the low end of the burst pressure requirement, i.e., 500-750 psi. In the next period, we will continue the improvement of this prototype module to upgrade its burst pressure to 1000 to 1500 psi range. In addition, bench-top experimental study has been conducted in this period to verify satisfactorily the simulated results for the process scheme developed in the last report, which took into the consideration of streamlining the pre- and post-treatment. The sensitivity analysis indicates that membrane surface area requirement is a key operating parameter based upon the criteria of the CO conversion, hydrogen recovery and CO impurity level. A preliminary optimization study has been performed in this period based upon the key operating parameters determined above. Our result shows that at 40 bar feed pressure a nearly complete CO conversion and >95% hydrogen recovery can be achieved with the CO impurity level at {approx}3500 ppm. If the hydrogen recovery ratio is lowered, the CO impurity level can be reduced further. More comprehensive optimization study will be performed in the 2nd half of Yr III to focus on the reduction of the CO impurity level with a reasonable hydrogen recovery ratio.

Paul K.T. Liu

2006-05-31T23:59:59.000Z

354

Hydrogen Production by PEM Electrolysis: Spotlight on Giner and...  

NLE Websites -- All DOE Office Websites (Extended Search)

PRODUCTION BY PEM ELECTROLYSIS: SPOTLIGHT ON GINER AND PROTON US DOE WEBINAR (May 23, 2011) 2 Webinar Outline *Water Electrolysis H 2 Production Overview DOE-EERE-FCT: Eric L....

355

Hydrogen production and delivery analysis in US markets : cost, energy and greenhouse gas emissions.  

DOE Green Energy (OSTI)

Hydrogen production cost conclusions are: (1) Steam Methane Reforming (SMR) is the least-cost production option at current natural gas prices and for initial hydrogen vehicle penetration rates, at high production rates, SMR may not be the least-cost option; (2) Unlike coal and nuclear technologies, the cost of natural gas feedstock is the largest contributor to SMR production cost; (3) Coal- and nuclear-based hydrogen production have significant penalties at small production rates (and benefits at large rates); (4) Nuclear production of hydrogen is likely to have large economies of scale, but because fixed O&M costs are uncertain, the magnitude of these effects may be understated; and (5) Given H2A default assumptions for fuel prices, process efficiencies and labor costs, nuclear-based hydrogen is likely to be more expensive to produce than coal-based hydrogen. Carbon taxes and caps can narrow the gap. Hydrogen delivery cost conclusions are: (1) For smaller urban markets, compressed gas delivery appears most economic, although cost inputs for high-pressure gas trucks are uncertain; (2) For larger urban markets, pipeline delivery is least costly; (3) Distance from hydrogen production plant to city gate may change relative costs (all results shown assume 100 km); (4) Pipeline costs may be reduced with system 'rationalization', primarily reductions in service pipeline mileage; and (5) Liquefier and pipeline capital costs are a hurdle, particularly at small market sizes. Some energy and greenhouse gas Observations: (1) Energy use (per kg of H2) declines slightly with increasing production or delivery rate for most components (unless energy efficiency varies appreciably with scale, e.g., liquefaction); (2) Energy use is a strong function of production technology and delivery mode; (3) GHG emissions reflect the energy efficiency and carbon content of each component in a production-delivery pathway; (4) Coal and natural gas production pathways have high energy consumption and significant GHG emissions (in the absence of carbon caps, taxes or sequestration); (5) Nuclear pathway is most favorable from energy use and GHG emissions perspective; (6) GH2 Truck and Pipeline delivery have much lower energy use and GHG emissions than LH2 Truck delivery; and (7) For LH2 Truck delivery, the liquefier accounts for most of the energy and GHG emissions.

Mintz, M.; Gillette, J.; Elgowainy, A. (Decision and Information Sciences); ( ES)

2009-01-01T23:59:59.000Z

356

Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons  

SciTech Connect

A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

Muradov, Nazim Z. (Melbourne, FL)

2011-08-23T23:59:59.000Z

357

Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic  

Science Conference Proceedings (OSTI)

A new bis(diphosphine) nickel(II) complex, [Ni(PPh2NR2)2](BF4)2, 1, (R = CH2CH2OCH3) is described. A {Delta}G{sup o} of 0.84 kcal/mol{sup -1} for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displays reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, a characteristic most commonly associated with hydrogenase enzymes.

Smith, Stuart E.; Yang, Jenny Y.; DuBois, Daniel L.; Bullock, Morris

2012-03-26T23:59:59.000Z

358

Capabilities to Support Thermochemical Hydrogen Production Technology Development  

DOE Green Energy (OSTI)

This report presents the results of a study to determine if Idaho National Laboratory (INL) has the skilled staff, instrumentation, specialized equipment, and facilities required to take on work in thermochemical research, development, and demonstration currently being performed by the Nuclear Hydrogen Initiative (NHI). This study outlines the beneficial collaborations between INL and other national laboratories, universities, and industries to strengthen INL's thermochemical efforts, which should be developed to achieve the goals of the NHI in the most expeditious, cost effective manner. Taking on this work supports INL's long-term strategy to maintain leadership in thermochemical cycle development. This report suggests a logical path forward to accomplish this transition.

Daniel M. Ginosar

2009-05-01T23:59:59.000Z

359

Evidence of catalytic production of hot hydrogen in rf generated hydrogen/argon plasmas  

E-Print Network (OSTI)

In this paper the selective broadening of the atomic hydrogen lines in pure H2 and Ar/H2 mixtures in a large 'GEC' cell (36 cm length_ 14 cm ID) was mapped as a function of position, H2/Ar ratio, time, power, and pressure. Several observations regarding the selective line broadening were particularly notable as they are unanticipated on the basis of earlier models. First, the anomalous broadening of the Balmer lines was found to exist throughout the plasma, and not just in the region between the electrodes. Second, the broadening was consistently a complex function of the operating parameters particularly gas composition (highest in pure H2), position, power, time and pressure. Clearly not anticipated by earlier models were the findings that under some conditions the highest concentration of 'hot' (>10 eV) hydrogen was found at the entry end, and not in the high field region between the electrodes and that in other conditions, the hottest H was at the (exit) pump (also grounded electrode) end. Third, excitati...

Phillips, J; Akhtar, K; Dhandapani, B; Mills, R; Phillips, Jonathan; Chen, Chun-Ku; Akhtar, Kamran; Dhandapani, Bala; Mills, Randell

2005-01-01T23:59:59.000Z

360

Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy  

E-Print Network (OSTI)

generation (DG) of electrical power with a hydrogenthese options for the electrical power production and wasteInc. bition Place. Electrical power generated by a Hydro-

Lipman, Timothy; Brooks, Cameron

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Enhanced Hydrogen Production in Escherichia coli Through Chemical Mutagenesis, Gene Deletion, and Transposon Mutagenesis  

E-Print Network (OSTI)

We demonstrate that hydrogen production can be increased by random mutagenesis using N-methyl-N'-nitro-N-nitrosoguanidine (MNNG) and that hydrogen production can be further increased in the chemically-mutagenized strain by targeted gene deletion and overexpression of genes related to formate metabolism. Chemical mutagenesis of Escherichia coli BW25113 hyaB hybC hycE::kan/pBS(Kan)-HycE to form strain 3/86 resulted in 109 +/- 0.5- fold more hydrogen; 3/86 lacks functional hydrogen uptake hydrogenases 1 and 2, has hydrogenproducing hydrogenase 3 inactivated from the chromosome, and has constitutively active hydrogenase 3 based on expression of the large subunit of hydrogenase 3 from a high copy number plasmid. Deleting fdoG, which encodes formate dehydrogenase O, (that diverts formate from hydrogen), from chemical mutagen 3/86 increased hydrogen production 188 +/- 0.50-fold (relative to the unmutagenized strain), and deletion of hycA, which encodes the repressor of formate hydrogen lyase (FHL), increased hydrogen production 232 +/- 0.50-fold. Deleting both fdoG and hycA increased hydrogen production 257 +/- 0.50-fold, and overexpressing fhlA along with the fdoG hycA mutations increased hydrogen 308 +/- 0.52-fold. Whole-transcriptome analysis of chemical mutagen 3/86 revealed 89 genes were induced and 31 genes were repressed. In an effort to identify chromosomal mutations in chemical mutagen 3/86, we performed comparative genome sequencing and identified two chromosomal loci with mutations in coding regions of ftnA and yebJ; however, neither gene was related to the increased hydrogen production as determined by the close vial (short) hydrogen assay. In addition, transposon mutagenesis, which is one of the most efficient strategies for creating random mutations in the genomic DNA, was performed in two different strains: E. coli BW25113 hyaB hybC hycA fdoG::kan/pCA24N-FhlA and E. coli MG1655 to identify beneficial mutations for hydrogen production. As a result of screening 461 E. coli BW25113 hyaB hybC hycA fdoG::kan/pCA24N-FhlA transformants and 1000 E. coli MG1655 transformants, three interesting mutations have been discovered in E. coli BW25113 hyaB hybC hycA fdoG::kan/pCA24N-FhlA transformants (gpsA, dipZ, glgP) and 1 beneficial mutation in E. coli MG1655 transformants (malT). When any of these genes gpsA, dipZ, or glgP is disrupted by Tn5 insertion, hydrogen production decreases 17, 3 and 8-fold, respectively. Additionally, when malT gene is disrupted by Tn5 insertion, hydrogen increases 3.4-fold.

Garzon Sanabria, Andrea Juliana

2010-05-01T23:59:59.000Z

362

An Assessment of Reactor Types for Thermochemical Hydrogen Production  

DOE Green Energy (OSTI)

Nuclear energy has been proposed as a heat source for producing hydrogen from water using a sulfur-iodine thermochemical cycle. This document presents an assessment of the suitability of various reactor types for this application. The basic requirement for the reactor is the delivery of 900 C heat to a process interface heat exchanger. Ideally, the reactor heat source should not in itself present any significant design, safety, operational, or economic issues. This study found that Pressurized and Boiling Water Reactors, Organic-Cooled Reactors, and Gas-Core Reactors were unsuitable for the intended application. Although Alkali Metal-Cooled and Liquid-Core Reactors are possible candidates, they present significant development risks for the required conditions. Heavy Metal-Cooled Reactors and Molten Salt-Cooled Reactors have the potential to meet requirements, however, the cost and time required for their development may be appreciable. Gas-Cooled Reactors (GCRs) have been successfully operated in the required 900 C coolant temperature range, and do not present any obvious design, safety, operational, or economic issues. Altogether, the GCRs approach appears to be very well suited as a heat source for the intended application, and no major development work is identified. This study recommends using the Gas-Cooled Reactor as the baseline reactor concept for a sulfur-iodine cycle for hydrogen generation.

MARSHALL, ALBERT C.

2002-02-01T23:59:59.000Z

363

Lighting Up Enzymes for Solar Hydrogen Production (Fact Sheet...  

NLE Websites -- All DOE Office Websites (Extended Search)

plexes with the hydrogenase and that these hybrid assemblies functioned to catalyze H 2 production using the energy of sunlight. During biological photosynthesis, ferredoxin...

364

DOE Hydrogen Analysis Repository: Water Implications of Biofuels Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Water Implications of Biofuels Production Water Implications of Biofuels Production Project Summary Full Title: Water Implications of Biofuels Production in the United States Project ID: 227 Principal Investigator: William S. Logan Brief Description: The National Research Council conducted a workshop and wrote a report examining the potential effects of biofuels production in the U.S. on water and related land resources. Purpose Examine the possible effects of biofuel development on water and related land resources. The central questions are how water use and water quality are expected to change as the U.S. agricultural portfolio shifts to include more energy crops and as overall agricultural production potentially increases. Such questions are considered within the context of U.S. policy and also the expected advances in technology and agricultural practices

365

Development of Hydrogen Selective Membranes/Modules as Reactors/Separators for Distributed Hydrogen Production - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Paul KT Liu Media and Process Technology Inc. (M&P) 1155 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-3711 Email: pliu@mediaandprocess.com DOE Managers HQ: Sara Dillich Phone: (202) 586-7925 Email: Sara.Dillich@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FG36-05GO15092 Subcontractor: University of Southern California Project Start Date: July 1, 2005 Projected End Date: December 31, 2012 Fiscal Year (FY) 2012 Objectives The water-gas shift (WGS) reaction becomes less efficient when high CO conversion is required, such as for distributed hydrogen production applications. Our project

366

Potential for Hydrogen Production from Key Renewable Resources in the United States  

NLE Websites -- All DOE Office Websites (Extended Search)

Potential for Hydrogen Production Potential for Hydrogen Production from Key Renewable Resources in the United States A. Milbrandt and M. Mann Technical Report NREL/TP-640-41134 February 2007 NREL is operated by Midwest Research Institute ● Battelle Contract No. DE-AC36-99-GO10337 Potential for Hydrogen Production from Key Renewable Resources in the United States A. Milbrandt and M. Mann Prepared under Task No. H278.2100 Technical Report NREL/TP-640-41134 February 2007 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov Operated for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy by Midwest Research Institute * Battelle Contract No. DE-AC36-99-GO10337 NOTICE This report was prepared as an account of work sponsored by an agency of the United States government.

367

MEASUREMENT AND PREDICTION OF RADIOLYTIC HYDROGEN PRODUCTION IN DEFENSE WASTE PROCESSING SLURRIES AT SAVANNAH RIVER SITE  

DOE Green Energy (OSTI)

This paper presents results of measurements and predictions of radiolytic hydrogen production rates from two actual process slurries in the Defense Waste Processing Facility (DWPF) at Savannah River Site (SRS). Hydrogen is a flammable gas and its production in nuclear facilities can be a safety hazard if not mitigated. Measurements were made in the Shielded Cells of Savannah River National Laboratory (SRNL) using a sample of Sludge Batch 3 (SB3) currently being processed by the DWPF. Predictions were made using published values for rates of radiolytic reactions producing H{sub 2} in aqueous solutions and the measured radionuclide and chemical compositions of the two slurries. The agreement between measured and predicted results for nine experiments ranged from complete agreement to 24% difference. This agreement indicates that if the composition of the slurry being processed is known, the rate of radiolytic hydrogen production can be reasonably estimated.

Bibler, N; John Pareizs, J; Terri Fellinger, T; Cj Bannochie, C

2007-01-10T23:59:59.000Z

368

A new perspective on hydrogen production by photosynthetic water-splitting  

DOE Green Energy (OSTI)

Present energy systems are heavily dependent on fossil fuels. This will eventually lead to the foreseeable depletion of fossil energy resources and, according to some reports, global climate changes due to the emission of carbon dioxide. In principle, hydrogen production by biophotolysis of water can be an ideal solar energy conversion system for sustainable development of human activities in harmony with the global environment. In photosynthetic hydrogen production research, there are currently two main efforts: (1) Direct photoevolution of hydrogen and oxygen by photosynthetic water splitting using the ferredoxin/hydrogenase pathway; (2) Dark hydrogen production by fermentation of organic reserves such as starch that are generated by photosynthesis during the light period. In this chapter, the advantages and challenges of the two approaches for hydrogen production will be discussed, in relation to a new opportunity brought by our recent discovery of a new photosynthetic water-splitting reaction which, potentially, has twice the energy efficiency of conventional watersplitting via the two light reaction Z-scheme of photosynthesis.

Lee, J.W.; Greenbaum, E.

1996-05-01T23:59:59.000Z

369

DOE Workshop on Hydrogen Production via Direct Fermentation  

NLE Websites -- All DOE Office Websites (Extended Search)

Workshop on Workshop on H H Y Y D D R R O O G G E E N N P P R R O O D D U U C C T T I I O O N N V V I I A A D D I I R R E E C C T T F F E E R R M M E E N N T T A A T T I I O O N N June 9, 2004 Baltimore, Maryland DOE-OFFICE OF HYDROGEN, FUEL CELLS AND INFRASTRUCTURE TECHNOLOGIES TABLE OF CONTENTS Introduction................................................................................................................1 Workshop Format ......................................................................................................1 Workshop Results ......................................................................................................2 TABLES Table 1. Results of Group Discussion on Neoterics/NREL Boundary Analysis Report .................................................................................................................

370

DOE Hydrogen Analysis Repository: Water Use for Power Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Water Use for Power Production Water Use for Power Production Project Summary Full Title: Consumptive Water Use for U.S. Power Production Project ID: 205 Principal Investigator: Paul Torcellini Keywords: Water, energy use, electricity generation Purpose Estimate the water consumption at power plants to provide a metric for determining water efficiency in building cooling systems. Performer Principal Investigator: Paul Torcellini Organization: National Renewable Energy Laboratory (NREL) Address: 1617 Cole Blvd. Golden, CO 80401 Telephone: 303-384-7528 Email: paul_torcellini@nrel.gov Additional Performers: R. Judkoff, National Renewable Energy Laboratory; N. Long, National Renewable Energy Laboratory Period of Performance End: December 2003 Project Description Type of Project: Analysis

371

System Evaluations and Life-Cycle Cost Analyses for High-Temperature Electrolysis Hydrogen Production Facilities  

DOE Green Energy (OSTI)

This report presents results of system evaluations and lifecycle cost analyses performed for several different commercial-scale high-temperature electrolysis (HTE) hydrogen production concepts. The concepts presented in this report rely on grid electricity and non-nuclear high-temperature process heat sources for the required energy inputs. The HYSYS process analysis software was used to evaluate both central plant designs for large-scale hydrogen production (50,000 kg/day or larger) and forecourt plant designs for distributed production and delivery at about 1,500 kg/day. The HYSYS software inherently ensures mass and energy balances across all components and it includes thermodynamic data for all chemical species. The optimized designs described in this report are based on analyses of process flow diagrams that included realistic representations of fluid conditions and component efficiencies and operating parameters for each of the HTE hydrogen production configurations analyzed. As with previous HTE system analyses performed at the INL, a custom electrolyzer model was incorporated into the overall process flow sheet. This electrolyzer model allows for the determination of the average Nernst potential, cell operating voltage, gas outlet temperatures, and electrolyzer efficiency for any specified inlet steam, hydrogen, and sweep-gas flow rates, current density, cell active area, and external heat loss or gain. The lifecycle cost analyses were performed using the H2A analysis methodology developed by the Department of Energy (DOE) Hydrogen Program. This methodology utilizes spreadsheet analysis tools that require detailed plant performance information (obtained from HYSYS), along with financial and cost information to calculate lifecycle costs. There are standard default sets of assumptions that the methodology uses to ensure consistency when comparing the cost of different production or plant design options. However, these assumptions may also be varied within the spreadsheets when better information is available or to allow the performance of sensitivity studies. The selected reference plant design for this study was a 1500 kg/day forecourt hydrogen production plant operating in the thermal-neutral mode. The plant utilized industrial natural gas-fired heaters to provide process heat, and grid electricity to supply power to the electrolyzer modules and system components. Modifications to the reference design included replacing the gas-fired heaters with electric resistance heaters, changing the operating mode of the electrolyzer (to operate below the thermal-neutral voltage), and considering a larger 50,000 kg/day central hydrogen production plant design. Total H2A-calculated hydrogen production costs for the reference 1,500 kg/day forecourt hydrogen production plant were $3.42/kg. The all-electric plant design using electric resistance heaters for process heat, and the reference design operating below the thermal-neutral voltage had calculated lifecycle hydrogen productions costs of $3.55/kg and $5.29/kg, respectively. Because of its larger size and associated economies of scale, the 50,000 kg/day central hydrogen production plant was able to produce hydrogen at a cost of only $2.89/kg.

Edwin A. Harvego; James E. O'Brien; Michael G. McKellar

2012-05-01T23:59:59.000Z

372

CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY  

DOE Green Energy (OSTI)

Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

Zhen Fan

2006-05-30T23:59:59.000Z

373

Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: First Set of Composite Data Products for Publication - March 1, 2006  

DOE Green Energy (OSTI)

This presentation provides the initial composite data products available for publication from NREL's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project.

Wipke, K.; Welch, C.; Thomas, H.; Sprik, S.

2007-02-01T23:59:59.000Z

374

Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: Spring 2007 Composite Data Products; March 8, 2007  

DOE Green Energy (OSTI)

This presentation provides the composite data products from Spring 2007 from NREL's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project.

Wipke, K.; Sprik, S.; Thomas, H.; Welch, C.

2007-04-01T23:59:59.000Z

375

Interim report Assessment of Baseline and Advanced Hydrogen Production...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cycle Cases The IGCC design cases analyzed in this report are based on the power production from dual advanced F-class combined cycle gas turbines. The plants are nominally...

376

Durability of Solid Oxide Electrolysis Cells for Hydrogen Production  

E-Print Network (OSTI)

to be 71 US¢/kg H2, equivalent to 30 $/barrel crude oil using the higher heating value (HHV) [1]. The CO production cost was found to be 5.6 US¢/kg equivalent to 34 $/barrel crude oil using the HHV. Figure 1 of the SOEC technology i.e. issues such as a potential H2 production price as low as 0.71 US$/kg H2 using

377

An Integrated Hydrogen Production-CO2 Capture Process from Fossil Fuel  

DOE Green Energy (OSTI)

The new technology concept integrates two significant complementary hydrogen production and CO{sub 2}-sequestration approaches that have been developed at Oak Ridge National Laboratory (ORNL) and Clark Atlanta University. The process can convert biomass into hydrogen and char. Hydrogen can be efficiently used for stationary power and mobile applications, or it can be synthesized into Ammonia which can be used for CO{sub 2}-sequestration, while char can be used for making time-release fertilizers (NH{sub 4}HCO{sub 3}) by absorption of CO{sub 2} and other acid gases from exhaust flows. Fertilizers are then used for the growth of biomass back to fields. This project includes bench scale experiments and pilot scale tests. The Combustion and Emission Lab at Clark Atlanta University has conducted the bench scale experiments. The facility used for pilot scale tests was built in Athens, GA. The overall yield from this process is 7 wt% hydrogen and 32 wt% charcoal/activated carbon of feedstock (peanut shell). The value of co-product activated carbon is about $1.1/GJ and this coproduct reduced the selling price of hydrogen. And the selling price of hydrogen is estimated to be $6.95/GJ. The green house experimental results show that the samples added carbon-fertilizers have effectively growth increase of three different types of plants and improvement ability of keeping fertilizer in soil to avoid the fertilizer leaching with water.

Zhicheng Wang

2007-03-15T23:59:59.000Z

378

Trends in Selective Hydrogen Peroxide Production on Transition Metal Surfaces from First Principles  

Science Conference Proceedings (OSTI)

We present a comprehensive, Density Functional Theory-based analysis of the direct synthesis of hydrogen peroxide, H2O2, on twelve transition metal surfaces. We determine the full thermodynamics and selected kinetics of the reaction network on these metals, and we analyze these energetics with simple, microkinetically motivated rate theories to assess the activity and selectivity of hydrogen peroxide production on the surfaces of interest. By further exploiting Brnsted-Evans-Polanyi relationships and scaling relationships between the binding energies of different adsorbates, we express the results in the form of a two dimensional contour volcano plot, with the activity and selectivity being determined as functions of two independent descriptors, the atomic hydrogen and oxygen adsorption free energies. We identify both a region of maximum predicted catalytic activity, which is near Pt and Pd in descriptor space, and a region of selective hydrogen peroxide production, which includes Au. The optimal catalysts represent a compromise between activity and selectivity and are predicted to fall approximately between Au and Pd in descriptor space, providing a compact explanation for the experimentally known performance of Au-Pd alloys for hydrogen peroxide synthesis, and suggesting a target for future computational screening efforts to identify improved direct hydrogen peroxide synthesis catalysts. Related methods of combining activity and selectivity analysis into a single volcano plot may be applicable to, and useful for, other aqueous phase heterogeneous catalytic reactions where selectivity is a key catalytic criterion.

Rankin, Rees B.; Greeley, Jeffrey P.

2012-10-19T23:59:59.000Z

379

Sensitivity Studies of Advanced Reactors Coupled to High Temperature Electrolysis (HTE) Hydrogen Production Processes  

DOE Green Energy (OSTI)

High Temperature Electrolysis (HTE), when coupled to an advanced nuclear reactor capable of operating at reactor outlet temperatures of 800 C to 950 C, has the potential to efficiently produce the large quantities of hydrogen needed to meet future energy and transportation needs. To evaluate the potential benefits of nuclear-driven hydrogen production, the UniSim process analysis software was used to evaluate different reactor concepts coupled to a reference HTE process design concept. The reference HTE concept included an Intermediate Heat Exchanger and intermediate helium loop to separate the reactor primary system from the HTE process loops and additional heat exchangers to transfer reactor heat from the intermediate loop to the HTE process loops. The two process loops consisted of the water/steam loop feeding the cathode side of a HTE electrolysis stack, and the steam or air sweep loop used to remove oxygen from the anode side. The UniSim model of the process loops included pumps to circulate the working fluids and heat exchangers to recover heat from the oxygen and hydrogen product streams to improve the overall hydrogen production efficiencies. The reference HTE process loop model was coupled to separate UniSim models developed for three different advanced reactor concepts (a high-temperature helium cooled reactor concept and two different supercritical CO2 reactor concepts). Sensitivity studies were then performed to evaluate the affect of reactor outlet temperature on the power cycle efficiency and overall hydrogen production efficiency for each of the reactor power cycles. The results of these sensitivity studies showed that overall power cycle and hydrogen production efficiencies increased with reactor outlet temperature, but the power cycle producing the highest efficiencies varied depending on the temperature range considered.

Edwin A. Harvego; Michael G. McKellar; James E. O'Brien; J. Stephen Herring

2007-04-01T23:59:59.000Z

380

A Process Model for the Production of Hydrogen Using High Temperature Electrolysis  

DOE Green Energy (OSTI)

High temperature electrolysis (HTE) involves the splitting of stream into hydrogen and oxygen at high temperatures. The primary advantage of HTE over conventional low temperature electrolysis is that considerably higher hydrogen production efficiencies can be achieved. Performing the electrolysis process at high temperatures results in more favorable thermodynamics for electrolysis, more efficient production of electricity, and allows direct use of process heat to generate steam. This paper presents the results of process analyses performed to evaluate the hydrogen production efficiencies of an HTE plant coupled to a 600 MWt Modular Helium Reactor (MHR) that supplies both the electricity and process heat needed to drive the process. The MHR operates with a coolant outlet temperature of 950 C. Approximately 87% of the high-temperature heat is used to generate electricity at high efficiency using a direct, Brayton-cycle power conversion system. The remaining high-temperature heat is used to generate a superheated steam / hydrogen mixture that is supplied to the electrolyzers. The analyses were performed using the HYSYS process modeling software. The model used to perform the analyses consisted of three loops; a primary high temperature helium loop, a secondary helium loop and the HTE process loop. The detailed model included realistic representations of all major components in the system, including pumps, compressors, heat exchange equipment, and the electrolysis stack. The design of the hydrogen production process loop also included a steam-sweep gas system to remove oxygen from the electrolysis stack so that it can be recovered and used for other applications. Results of the process analyses showed that hydrogen production efficiencies in the range of 45% to 50% are achievable with this system.

M. G. Mc Kellar; E. A. Harvego; M. Richards; A. Shenoy

2006-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Production of hydrogen by photovoltaic-powered electrolysis. Task 1 report  

DOE Green Energy (OSTI)

The report presents results of a cooperative effort among the Florida Energy Office, NASA/Kennedy Space Center, the US Department of Energy and the Florida Solar Energy Center (FSEC). It reports on a task to evaluate hydrogen production from photovoltaic (PV)-powered electrolysis. The resulting activities covered five years of effort funded at a total of $216,809. The results represent a successful, coordinated effort among two state agencies and two federal agencies. Results are reported on two separate investigations. The first investigation looked at the use of line focus concentrating photovoltaics coupled with single-cell electrolyzers to produce gaseous hydrogen. The concept, and its design, construction and operation, are presented. The objectives of the line focusing PV system are to reduce overall system cost under the assumptions that lenses and mirrors are cheaper to deploy than are PV cells, and that low-voltage, high-current dc electricity can efficiently power a single-cell elctrolyzer to produce hydrogen. The second investigation evaluated a base case cost of PV electrolysis hydrogen production based on present-day PV and electrolyzer costs and efficiencies. A second step analyzed the hydrogen costs based on a best prediction of where PV costs and efficiencies will be in 10 years. These results set the minimum cost standards that other renewable production technologies must meet or better.

Block, D.L.

1995-12-01T23:59:59.000Z

382

High Temperature Electrolysis for Hydrogen Production from Nuclear Energy TechnologySummary  

DOE Green Energy (OSTI)

The Department of Energy, Office of Nuclear Energy, has requested that a Hydrogen Technology Down-Selection be performed to identify the hydrogen production technology that has the best potential for timely commercial demonstration and for ultimate deployment with the Next Generation Nuclear Plant (NGNP). An Independent Review Team has been assembled to execute the down-selection. This report has been prepared to provide the members of the Independent Review Team with detailed background information on the High Temperature Electrolysis (HTE) process, hardware, and state of the art. The Idaho National Laboratory has been serving as the lead lab for HTE research and development under the Nuclear Hydrogen Initiative. The INL HTE program has included small-scale experiments, detailed computational modeling, system modeling, and technology demonstration. Aspects of all of these activities are included in this report. In terms of technology demonstration, the INL successfully completed a 1000-hour test of the HTE Integrated Laboratory Scale (ILS) technology demonstration experiment during the fall of 2008. The HTE ILS achieved a hydrogen production rate in excess of 5.7 Nm3/hr, with a power consumption of 18 kW. This hydrogen production rate is far larger than has been demonstrated by any of the thermochemical or hybrid processes to date.

J. E. O'Brien; C. M. Stoots; J. S. Herring; M. G. McKellar; E. A. Harvego; M. S. Sohal; K. G. Condie

2010-02-01T23:59:59.000Z

383

Anti-hydrogen production with positron beam ion trap  

Science Conference Proceedings (OSTI)

In low-energy antiproton physics, it is advantageous to be able to manipulate anti-particles as freely as normal particles. A robust production and storage system for high-quality positrons and antiprotons would be a substantial advance for the development of anti-matter science. The idea of electron beam ion trap could be applied for storage of anti-particle when the electron beam could be replaced by the positron beam. The bright positron beam would be brought about using synchrotron radiation source with a superconducting wiggler. The new scheme for production of anti-particles is proposed by using new accelerator technologies.

Itahashi, Takahisa [Department of Physics, Graduate School of Science, Osaka University 1-1 Machikaneyama, Toyonaka, Osaka 560-0043 (Japan)

2008-08-08T23:59:59.000Z

384

Advanced Intermediate Heat Transport Loop Design Configurations for Hydrogen Production Using High Temperature Nuclear Reactors  

DOE Green Energy (OSTI)

The US Department of Energy is investigating the use of high-temperature nuclear reactors to produce hydrogen using either thermochemical cycles or high-temperature electrolysis. Although the hydrogen production processes are in an early stage of development, coupling either of these processes to the high-temperature reactor requires both efficient heat transfer and adequate separation of the facilities to assure that off-normal events in the production facility do not impact the nuclear power plant. An intermediate heat transport loop will be required to separate the operations and safety functions of the nuclear and hydrogen plants. A next generation high-temperature reactor could be envisioned as a single-purpose facility that produces hydrogen or a dual-purpose facility that produces hydrogen and electricity. Early plants, such as the proposed Next Generation Nuclear Plant (NGNP), may be dual-purpose facilities that demonstrate both hydrogen and efficient electrical generation. Later plants could be single-purpose facilities. At this stage of development, both single- and dual-purpose facilities need to be understood. A number of possible configurations for a system that transfers heat between the nuclear reactor and the hydrogen and/or electrical generation plants were identified. These configurations included both direct and indirect cycles for the production of electricity. Both helium and liquid salts were considered as the working fluid in the intermediate heat transport loop. Methods were developed to perform thermal-hydraulic evaluations and cycle-efficiency evaluations of the different configurations and coolants. The thermal-hydraulic evaluations estimated the sizes of various components in the intermediate heat transport loop for the different configurations. The relative sizes of components provide a relative indication of the capital cost associated with the various configurations. Estimates of the overall cycle efficiency of the various configurations were also determined. The evaluations determined which configurations and coolants are the most promising from thermal-hydraulic and efficiency points of view.

Chang Oh; Cliff Davis; Rober Barner; Paul Pickard

2005-11-01T23:59:59.000Z

385

Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report Section II. Hydrogen Production and Delivery  

E-Print Network (OSTI)

energy products is thermochemical gasification. The focus here is on gas de- rived from biomass via applications. Many biomass gasifier designs exist, but the most promising today for village-scale trigeneration) in a central- ized village gasifier. Some of the gas so generated would be distributed via PVC pipes

386

CAPITAL AND OPERATING COST OF HYDROGEN PRODUCTION FROM COAL GASIFICATI...  

NLE Websites -- All DOE Office Websites (Extended Search)

8 Coal Using Preliminary Assumptions 2-15 2.5.1 Approach to Cost Estimating 2-16 2.5.2 Production Costs (Operation and Maintenance) 2-16 2.5.3 Consumables 2-17 2.5.4 Byproduct...

387

Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Pathways: Cost, Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios Mark Ruth National Renewable Energy Laboratory Melissa Laffen and Thomas A. Timbario Alliance Technical Services, Inc. Technical Report NREL/TP-6A1-46612 September 2009 Technical Report Hydrogen Pathways: Cost, NREL/TP-6A1-46612 Well-to-Wheels Energy Use, September 2009 and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios Mark Ruth National Renewable Energy Laboratory Melissa Laffen and Thomas A. Timbario Alliance Technical Services, Inc. Prepared under Task No. HS07.1002 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393

388

DOE Hydrogen and Fuel Cells Program Record 12001: H2 Production and Delivery Cost Apportionment  

NLE Websites -- All DOE Office Websites (Extended Search)

01 Date: May 14, 2012 01 Date: May 14, 2012 Title: H 2 Production and Delivery Cost Apportionment Originator: Scott Weil, Sara Dillich, Fred Joseck, and Mark Ruth Approved by: Sunita Satyapal and Rick Farmer Date: December 14, 2012 Item: The hydrogen threshold cost is defined as the untaxed cost of hydrogen (H 2 ) (produced, delivered, and dispensed) at which hydrogen fuel cell electric vehicles (FCEVs) are projected to become competitive on a $/mile basis with competing vehicles [gasoline in hybrid-electric vehicles (HEVs)] in 2020. As established in Record 11007 [1], this cost ranges from $2.00-$4.00/gge a of H 2 (based on $2007). The threshold cost can be apportioned into its constituent H 2 production and delivery costs, which can then serve as the respective cost targets for multi-year planning of the Fuel Cell Technologies (FCT)

389

Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Mark Paster Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technology Program Hydrogen Production and Delivery Team Hydrogen Delivery Goal Hydrogen Delivery Goal Liquid H 2 & Chem. Carriers Gaseous Pipeline Truck Hydrides Liquid H 2 - Truck - Rail Other Carriers Onsite reforming Develop Develop hydrogen fuel hydrogen fuel delivery delivery technologies that technologies that enable the introduction and enable the introduction and long long - - term viability of term viability of hydrogen as an energy hydrogen as an energy carrier for transportation carrier for transportation and stationary power. and stationary power. Delivery Options * End Game - Pipelines - Other as needed * Breakthrough Hydrogen Carriers * Truck: HP Gas & Liquid Hydrogen

390

Distributed Hydrogen Production from Natural Gas: Independent Review Panel Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Reference herein to any specific commercial product, process, or service by Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States government or any agency thereof. Available electronically at http://www.osti.gov/bridge Available for a processing fee to U.S. Department of Energy and its contractors, in paper, from: U.S. Department of Energy Office of Scientific and Technical Information P.O. Box 62 Oak Ridge, TN 37831-0062 phone: 865.576.8401 fax: 865.576.5728 email: mailto:reports@adonis.osti.gov

391

Assessement of Codes and Standards Applicable to a Hydrogen Production Plant Coupled to a Nuclear Reactor  

DOE Green Energy (OSTI)

This is an assessment of codes and standards applicable to a hydrogen production plant to be coupled to a nuclear reactor. The result of the assessment is a list of codes and standards that are expected to be applicable to the plant during its design and construction.

M. J. Russell

2006-06-01T23:59:59.000Z

392

Hydrogen and electricity production using microbial fuel cell-based technologies  

E-Print Network (OSTI)

­ Anaerobic digesters · Electrogenesis ­ Generation of electricity ­ Exoelectrogens ­ Microbial fuel cells1 Hydrogen and electricity production using microbial fuel cell-based technologies Bruce E. Logan · US electricity generation: 13 quad ·Electricity needed for H2 transportation: · Via water

Lee, Dongwon

393

Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming  

DOE Green Energy (OSTI)

A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental consequences. LCA is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes.

Spath, P. L.; Mann, M. K.

2000-09-28T23:59:59.000Z

394

Method and System for the Production of Hydrogen at Reduced VHTR Outlet Temperatures  

DOE Green Energy (OSTI)

The Department of Energy and the Idaho National Laboratory are developing a Next Generation Nuclear Plant (NGNP) to serve as a demonstration of state-of-the-art nuclear technology. The purpose of the demonstration is two fold 1) efficient low cost energy generation and 2) hydrogen production. Although a next generation plant could be developed as a single-purpose facility dedicated to hydrogen production, early designs are expected to be dual purpose. While hydrogen production and advanced energy cycles are still in its early stages of development, research towards coupling a high temperature reactor with electrical generation and hydrogen production is under way. Many aspects of the NGNP must be researched and developed in order to make recommendations on the final design of the plant. Parameters such as working conditions, cycle components, working fluids, and power conversion unit configurations must be understood. The integrated system of a Very High Temperature Reactor (VHTR) and a High Temperature Steam Electrolysis (HTSE) hydrogen production plant is being investigated and this system, as it is currently envisioned, will produce hydrogen by utilizing a highly efficient VHTR with a VHTR outlet temperature of 900C to supply the necessary energy and electricity to the HTSE unit. Though the combined system may produce hydrogen and electricity with high efficiency, the choices of materials that are suitable for use at 900C are limited due to high-temperature strength, corrosion, and durability (creep) considerations. The lack of materials that are ASME (American Society of Mechanical Engineers) code-certified at these temperatures is also a problem, and is a barrier to commercial deployment. If the current system concept can be modified to produce hydrogen with comparable efficiency at lower temperatures, then the technical barriers related to materials selection and use might be eliminated, and the integrated system may have a much greater probability of succeeding at the commercial scale. This paper describes a means to reduce the outlet temperature of the VHTR to approximately 700C while still maintaining plant high efficiency.

Chang H. Oh; Eung S. Kim

2009-10-01T23:59:59.000Z

395

Feasibility Analysis of Steam Reforming of Biodiesel by-product Glycerol to Make Hydrogen  

E-Print Network (OSTI)

Crude glycerol is the major byproduct from biodiesel industry. In general, for every 100 pounds of biodiesel produced, approximately 10 pounds of crude glycerol are produced as a by-product. As the biodiesel industry rapidly expands in the U.S., the market is being flooded with this low quality waste glycerol. Due to its high impurities, it is expensive to purify and use in food, pharmaceutical, and cosmetics industries. Biodiesel producers should seek an alternative method which is economically and environmentally friendly. This research contains reforming process to covert waste glycerol from a biodiesel industry into sellable hydrogen. This process consists of 850oC reformer, 350oC and 210oC shift reactors for water gas shift reaction, flash tanks, and a separator. It is considered to be the least expensive method. At 850oC and 1 atm pressure, glycerol reacts with superheated steam to produce gaseous mixture of hydrogen, carbon dioxide, carbon monoxide, and methane. Reformer is a batch process where only 68% of waste glycerol is converted into gaseous mixture. The excess glycerol is recycled back as a feedstock. Water gas shift (WGS) reaction, further convert carbon monoxide into hydrogen and carbon dioxide which is further subjected to separation process to isolate hydrogen from CO2 and any other impurities. The final product stream consists of 68% of hydrogen, and 27% of CO2 based on molar flow rate.

Joshi, Manoj

2009-06-09T23:59:59.000Z

396

Production of Hydrogen for Clean and Renewable Source of Energy for Fuel Cell Vehicles  

Science Conference Proceedings (OSTI)

This was a two-year project that had two major components: 1) the demonstration of a PV-electrolysis system that has separate PV system and electrolysis unit and the hydrogen generated is to be used to power a fuel cell based vehicle; 2) the development of technologies for generation of hydrogen through photoelectrochemical process and bio-mass derived resources. Development under this project could lead to the achievement of DOE technical target related to PEC hydrogen production at low cost. The PEC part of the project is focused on the development of photoelectrochemical hydrogen generation devices and systems using thin-film silicon based solar cells. Two approaches are taken for the development of efficient and durable photoelectrochemical cells; 1) An immersion-type photoelectrochemical cells (Task 3) where the photoelectrode is immersed in electrolyte, and 2) A substrate-type photoelectrochemical cell (Task 2) where the photoelectrode is not in direct contact with electrolyte. Four tasks are being carried out: Task 1: Design and analysis of DC voltage regulation system for direct PV-to-electrolyzer power feed Task 2: Development of advanced materials for substrate-type PEC cells Task 3: Development of advanced materials for immersion-type PEC cells Task 4: Hydrogen production through conversion of biomass-derived wastes

Deng, Xunming; Ingler, William B, Jr.; Abraham, Martin; Castellano, Felix; Coleman, Maria; Collins, Robert; Compaan, Alvin; Giolando, Dean; Jayatissa, Ahalapitiya. H.; Stuart, Thomas; Vonderembse, Mark

2008-10-31T23:59:59.000Z

397

Production of hydrogen. [metals oxidation/carbon reduction process; and cyyclic electrolytic; carbon reduction  

SciTech Connect

Hydrogen is produced in a cyclic metals oxidation/carbon reduction process. In particular, elemental iron or cobalt is oxidized in an aqueous solution of an alkali metal hydroxide with the simultaneous generation of hydrogen. The iron or cobalt oxidation products of the reaction are thereafter reduced to elemental iron or cobalt by contact with a carbonaceous reducing agent at elevated temperatures and the reduced material recycled for reoxidation. In an alternate operation, hydrogen is produced in a cyclic electrolytic/carbon reduction process wherein elemental iron or cobalt is electrolytically converted to corresponding oxidation products with the simultaneous generation of hydrogen. The electrolytic cell used in this process comprises a cathode, a magnetic anode that is adapted to attract and retain iron and/or cobalt particles and an aqueous electrolyte. In the electrolytic cell, hydrogen is produced at the cathode and metal particles contained on the magnetic electrode are oxidized to a non-ferromagnetic specie, such as ferrous hydroxide. The nonferromagnetic species are recovered from the electrolytic cell and thereafter reconverted to particulate elemental iron and/or cobalt by treating the material with a carbonaceous reductant at an elevated temperature.

Batzold, J.S.; Pan, Y.

1980-05-13T23:59:59.000Z

398

Hydrogen production by high-temperature steam gasification of biomass and coal  

Science Conference Proceedings (OSTI)

High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

2009-04-15T23:59:59.000Z

399

Separation Requirements for a Hydrogen Production Plant and High-Temperature Nuclear Reactor  

Science Conference Proceedings (OSTI)

This paper presents an overview of the engineering methods, models, and results used in an evaluation for locating a hydrogen production facility near a proposed next-generation nuclear power plant. Standard probabilistic safety assessment methodologies were used to answer the risk-related questions for a combined nuclear and chemical facility: what can go wrong? how likely is it to happen? and what are the consequences of it happening? As part of answering these questions, a model was developed suitable for determining the distances separating a hydrogen-production process and nuclear plant structures. The objective of the model-development and analysis is to answer key safety questions relating to the placement of one or more hydrogen production plants in the vicinity of a high-temperature nuclear reactor. From a thermal-hydraulic efficiency standpoint, close proximity of the two facilities is beneficial. Safety and regulatory implications, however, force the separation to be increased, perhaps substantially. The likelihood of obtaining a permit to construct and build such as facility in the United States without answering these safety questions is uncertain. The quantitative analysis performed and described in this paper offers a scoping mechanism to determine key parameters relating to the development of a nuclear-based hydrogen production facility. The calculations indicate that when the facilities are less than 100 m apart, the core damage frequency is large enough (greater than 1E-6/yr) to become problematic in a risk-informed environment. However, a variety of design modifications (blast-deflection barriers, for example) could significantly reduce risk and should be further explored as design of the hydrogen production facility evolves.

Curtis Smith; Scott Beck; William Galyean

2006-06-01T23:59:59.000Z

400

Analysis of Reference Design for Nuclear-Assisted Hydrogen Production at 750C Reactor Outlet Temperature  

SciTech Connect

The use of High Temperature Electrolysis (HTE) for the efficient production of hydrogen without the greenhouse gas emissions associated with conventional fossil-fuel hydrogen production techniques has been under investigation at the Idaho National Engineering Laboratory (INL) for the last several years. The activities at the INL have included the development, testing and analysis of large numbers of solid oxide electrolysis cells, and the analyses of potential plant designs for large scale production of hydrogen using a high-temperature gas-cooled reactor (HTGR) to provide the process heat and electricity to drive the electrolysis process. The results of this research led to the selection in 2009 of HTE as the preferred concept in the U.S. Department of Energy (DOE) hydrogen technology down-selection process. However, the down-selection process, along with continued technical assessments at the INL, has resulted in a number of proposed modifications and refinements to improve the original INL reference HTE design. These modifications include changes in plant configuration, operating conditions and individual component designs. This report describes the resulting new INL reference design coupled to two alternative HTGR power conversion systems, a Steam Rankine Cycle and a Combined Cycle (a Helium Brayton Cycle with a Steam Rankine Bottoming Cycle). Results of system analyses performed to optimize the design and to determine required plant performance and operating conditions when coupled to the two different power cycles are also presented. A 600 MWt high temperature gas reactor coupled with a Rankine steam power cycle at a thermal efficiency of 44.4% can produce 1.85 kg/s of hydrogen and 14.6 kg/s of oxygen. The same capacity reactor coupled with a combined cycle at a thermal efficiency of 42.5% can produce 1.78 kg/s of hydrogen and 14.0 kg/s of oxygen.

Michael G. McKellar; Edwin A. Harvego

2010-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrogen production cxs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

SIMULTANEOUS PRODUCTION OF HIGH-PURITY HYDROGEN AND SEQUESTRATION-READY CO2 FROM SYNGAS  

DOE Green Energy (OSTI)

This final report summarizes the progress made on the program ''Simultaneous Production of High-Purity Hydrogen and Sequestration-Ready CO{sub 2} from Syngas (contract number DE-FG26-99FT40682)'', during October 2000 through September of 2003. GE Energy and Environmental Research (GE-EER) and Southern Illinois University (SIU) at Carbondale conducted the research work for this program. This program addresses improved methods to efficiently produce simultaneous streams of high-purity hydrogen and separated carbon dioxide from synthesis gas (syngas). The syngas may be produced through either gasification of coal or reforming of natural gas. The process of production of H{sub 2} and separated CO{sub 2} utilizes a dual-bed reactor and regenerator system. The reactor produces hydrogen and the regenerator produces separated CO{sub 2}. The dual-bed system can be operated under either a circulating fluidized-bed configuration or a cyclic fixed-bed configuration. Both configurations were evaluated in this project. The experimental effort was divided into lab-scale work at SIU and bench-scale work at GE-EER. Tests in a lab-scale fluidized bed system demonstrated the process for the conversion of syngas to high purity H{sub 2} and separated CO{sub 2}. The lab-scale system generated up to 95% H{sub 2} (on a dry basis). Extensive thermodynamic analysis of chemical reactions between the syngas and the fluidized solids determined an optimum range of temperature and pressure operation, where the extent of the undesirable reactions is minimum. The cycling of the process between hydrogen generation and oxygen regeneration has been demonstrated. The fluidized solids did not regenerate completely and the hydrogen purity in the reuse cycle dropped to 70% from 95% (on a dry basis). Changes in morphology and particle size may be the most dominant factor affecting the efficiency of the repeated cycling between hydrogen production and oxygen regeneration. The concept of simultaneous production of hydrogen and separated stream of CO{sub 2} was proved using a fixed bed 2 reactor system at GE-EER. This bench-scale cyclic fixed-bed reactor system designed to reform natural gas to syngas has been fabricated in another coordinated DOE project. This system was modified to reform natural gas to syngas and then convert syngas to H{sub 2} and separated CO{sub 2}. The system produced 85% hydrogen (dry basis).

Linda Denton; Hana Lorethova; Tomasz Wiltowski; Court Moorefield; Parag Kulkarni; Vladimir Zamansky; Ravi Kumar

2003-12-01T23:59:59.000Z

402

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

DOE Green Energy (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2005-04-01T23:59:59.000Z

403

Assessment Hydrogen Production with CO2 Capture, Volume 1: Baseline State of the Art Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Hydrogen Production with CO 2 Capture Volume 1: Baseline State-of- the-Art Plants August 30, 2010 DOE/NETL-2010/1434 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States

404

Separation Requirements for a Hydrogen Production Plant and High-Temperature Nuclear Reactor  

DOE Green Energy (OSTI)

This report provides the methods, models, and results of an evaluation for locating a hydrogen production facility near a nuclear power plant. In order to answer the risk-related questions for this combined nuclear and chemical facility, we utilized standard probabilistic safety assessment methodologies to answer three questions: what can happen, how likely is it, and what are the consequences? As part of answering these questions, we developed a model suitable to determine separation distances for hydrogen process structures and the nuclear plant structures. Our objective of the model-development and analysis is to answer key safety questions related to the placement of one or more hydrogen production plants in the vicinity of a high-temperature nuclear reactor. From a thermal-hydraulic standpoint we would like the two facilities to be quite close. However, safety and regulatory implications force the separation distance to be increased, perhaps substantially. Without answering these safety questions, the likelihood for obtaining a permit to construct and build such as facility in the U.S. would be questionable. The quantitative analysis performed for this report provides us with a scoping mechanism to determine key parameters related to the development of a nuclear-based hydrogen production facility. From our calculations, we estimate that when the separation distance is less than 100m, the core damage frequency is large enough (greater than 1E-6/yr) to become problematic in a risk-informed environment. However, a variety of design modifications, for example blast-deflection barriers, were explored to determine the impact of potential mitigating strategies. We found that these mitigating cases may significantly reduce risk and should be explored as the design for the hydrogen production facility evolves.

Curtis Smith; Scott Beck; Bill Galyean

2005-09-01T23:59:59.000Z

405

Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen-from- Hydrogen-from- Ethanol: A Distributed Production System Presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting Laurel, Maryland Tuesday, November 6, 2007 H 2 Gen Innovations, Inc. Alexandria, Virginia www.h2gen.com 2 Topics * H 2 Gen Reformer System Innovation * Natural Gas Reformer - Key performance metrics - Summary unique H2A inputs * Ethanol Reformer - Key performance metrics - Summary unique H2A inputs * Questions from 2007 Merit Review 3 H 2 Gen Innovations' Commercial SMR * Compact, low-cost 115 kg/day natural gas reformer proven in commercial practice [13 US Patents granted] * Built-in, unique, low-cost PSA system * Unique sulfur-tolerant catalyst developed with Süd Chemie 4 DOE Program Results * Task 1- Natural Gas Reformer Scaling:

406

C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen  

DOE Green Energy (OSTI)

Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

Gerald P. Huffman

2006-03-30T23:59:59.000Z

407

Hydrogen production from liquid hydrocarbons demonstration program. Final report, 26 August 1985-1 September 1986  

SciTech Connect

The Air Force now uses diesel-engine generators as sources of heat and electricity at selected remotes sites. Simultaneously, it has investigated alternative cogeneration candidates that offer improved reliability, maintain ability, and economics. One system that shows high potential is a phosphoric acid fuel cell (PAFC) power plant consisting of a fuel conditioner to convert logistic fuels such as DEF-2, DF-a and JP-4 to a hydrogen-rich gas, and a power conditioner to convert the direct-current power to alternating current. The objective of the project work was to define, and demonstrate, a fuel conditioner to meet performance criteria established for the Air Force Remote Site Fuel Cell Power Plant program. Key criteria included high fuel-to-hydrogen conversion efficiency, rapid startup and load-following capability, and minimum water consumption during operations. A process configuration which has the potential to produce a minimum of 0.365 pound of hydrogen per pound of feed diesel consumed is described. The hydrogen-containing product is a suitable fuel for phosphoric-acid fuel-cell power plant. A 2 mole per hour (hydrogen) demonstration plant was designed, constructed and started up. Results are summarized.

O'Hara, J.B.; Chow, T.K.; Ling, J.K.

1986-09-01T23:59:59.000Z

408

Hydrogen Pathways: Updated Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Ten Hydrogen Production, Delivery, and Distribution Scenarios  

DOE Green Energy (OSTI)

This report describes a life-cycle assessment conducted by the National Renewable Energy Laboratory (NREL) of 10 hydrogen production, delivery, dispensing, and use pathways that were evaluated for cost, energy use, and greenhouse gas (GHG) emissions. This evaluation updates and expands on a previous assessment of seven pathways conducted in 2009. This study summarizes key results, parameters, and sensitivities to those parameters for the 10 hydrogen pathways, reporting on the levelized cost of hydrogen in 2007 U.S. dollars as well as life-cycle well-to-wheels energy use and GHG emissions associated with the pathways.

Ramsden, T.; Ruth, M.; Diakov, V.; Laffen, M.; Timbario, T. A.

2013-03-01T23:59:59.000Z

409

ENHANCED HYDROGEN PRODUCTION INTEGRATED WITH CO2 SEPARATION IN A SINGLE-STAGE REACTOR  

DOE Green Energy (OSTI)

The water gas shift reaction (WGSR) plays a major role in increasing the hydrogen production from fossil fuels. However, the enhanced hydrogen production is limited by thermodynamic constrains posed by equilibrium limitations of WGSR. This project aims at using a mesoporous, tailored, highly reactive calcium based sorbent system for incessantly removing the CO{sub 2} product which drives the equilibrium limited WGSR forward. In addition, a pure sequestration ready CO{sub 2} stream is produced simultaneously. A detailed project vision with the description of integration of this concept with an existing coal gasification process for hydrogen production is presented. Conceptual reactor designs for investigating the simultaneous water gas shift and the CaO carbonation reactions are presented. In addition, the options for conducting in-situ sorbent regeneration under vacuum or steam are also reported. Preliminary, water gas shift reactions using high temperature shift catalyst and without any sorbent confirmed the equilibrium limitation beyond 600 C demonstrating a carbon monoxide conversion of about 80%. From detailed thermodynamic analyses performed for fuel gas streams from typical gasifiers the optimal operating temperature range to prevent CaO hydration and to effect its carbonation is between 575-830 C.

Himanshu Gupta; Mahesh Iyer; Bartev Sakadjian; Liang-Shih Fan

2005-03-10T23:59:59.000Z

410

ENHANCED HYDROGEN PRODUCTION INTEGRATED WITH CO2 SEPARATION IN A SINGLE-STAGE REACTOR  

DOE Green Energy (OSTI)

Hydrogen production by the water gas shift reaction (WGSR) is equilibrium limited due to thermodynamic constrains. However, this can be overcome by continuously removing the product CO{sub 2}, thereby driving the WGSR in the forward direction to enhance hydrogen production. This project aims at using a high reactivity, mesoporous calcium based sorbent (PCC-CaO) for removing CO{sub 2} using reactive separation scheme. Preliminary results have shown that PCC-CaO dominates in its performance over naturally occurring limestone towards enhanced hydrogen production. However, maintenance of high reactivity of the sorbent over several reaction-regeneration cycles warrants effective regeneration methods. We have identified sub-atmospheric calcination (vacuum) as vital regeneration technique that helps preserve the sorbent morphology. Sub-atmospheric calcination studies reveal the significance of vacuum level, diluent gas flow rate, thermal properties of diluent gas, and sorbent loading on the kinetics of calcination and the morphology of the resultant CaO sorbent. Steam, which can be easily separated from CO{sub 2}, has been envisioned as a potential diluent gas due to its better thermal properties resulting in effective heat transfer. A novel multi-fixed bed reactor was designed which isolates the catalyst bed from the sorbent bed during the calcination step. This should prevent any potential catalyst deactivation due to oxidation by CO{sub 2} during the regeneration phase.

Himanshu Gupta; Mahesh Iyer; Bartev Sakadjian; Liang-Shih Fan

2005-04-01T23:59:59.000Z

411

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

412

Development of HyPEP, A Hydrogen Production Plant Efficiency Calculation Program  

DOE Green Energy (OSTI)

The Department of Energy envisions the next generation very high temperature gas-cooled reactor (VHTR) as a single-purpose or dual-purpose facility that produces hydrogen and electricity. The Ministry of Science and Technology (MOST) of the Republic of Korea also selected VHTR for the Nuclear Hydrogen Development and Demonstration (NHDD) Project. The report will address the evaluation of hydrogen and electricity production cycle efficiencies for such systems as the VHTR and NHDD, and the optimization of system configurations. Optimization of such complex systems as VHTR and NHDD will require a large number of calculations involving a large number of operating parameter variations and many different system configurations. The research will produce (a) the HyPEP which is specifically designed to be an easy-to-use and fast running tool for the hydrogen and electricity production evaluation with flexible system layout, (b) thermal hydraulic calculations using reference design, (c) verification and validation of numerical tools used in this study, (d) transient analyses during start-up operation and off-normal operation. This project will also produce preliminary cost estimates of the major components.

C. H. Oh; C. B. Davis; S. R. Sherman; S. Vilim; Y. J. Lee; W. J. Lee

2006-03-01T23:59:59.000Z

413

Nuclear Energy - Hydrogen Production - Fuel Cell: A Road Towards Future China's Sustainable Energy Strategy  

Science Conference Proceedings (OSTI)

Sustainable development of Chinese economy in 21. century will mainly rely on self-supply of clean energy with indigenous natural resources. The burden of current coal-dominant energy mix and the environmental stress due to energy consumptions has led nuclear power to be an indispensable choice for further expanding electricity generation capacity in China and for reducing greenhouse effect gases emission. The application of nuclear energy in producing substitutive fuels for road transportation vehicles will also be of importance in future China's sustainable energy strategy. This paper illustrates the current status of China's energy supply and the energy demand required for establishing a harmonic and prosperous society in China. In fact China's energy market faces following three major challenges, namely (1) gaps between energy supply and demand; (2) low efficiency in energy utilization, and (3) severe environmental pollution. This study emphasizes that China should implement sustainable energy development policy and pay great attention to the construction of energy saving recycle economy. Based on current forecast, the nuclear energy development in China will encounter a high-speed track. The demand for crude oil will reach 400-450 million tons in 2020 in which Chinese indigenous production will remain 180 million tons. The increase of the expected crude oil will be about 150 million tons on the basis of 117 million tons of imported oil in 2004 with the time span of 15 years. This demand increase of crude oil certainly will influence China's energy supply security and to find the substitution will be a big challenge to Chinese energy industry. This study illustrates an analysis of the market demands to future hydrogen economy of China. Based on current status of technology development of HTGR in China, this study describes a road of hydrogen production with nuclear energy. The possible technology choices in relation to a number of types of nuclear reactors are compared and assessed. The analysis shows that only high temperature gas cooled reactor (HTGR) and sodium fast breed reactor might be available in China in 2020 for hydrogen production. Further development of very high temperature gas cooled reactor (VHTR) and gas-cooled fast reactor (GCFR) is necessary to ensure China's future capability of hydrogen production with nuclear energy as the primary energy. It is obvious that hydrogen production with high efficient nuclear energy will be a suitable strategic technology road, through which future clean vehicles burning hydrogen fuel cells will become dominant in future Chinese transportation industry and will play sound role in ensuring future energy security of China and the sustainable prosperity of Chinese people. (author)

Zhiwei Zhou [Tsinghua University, Beijing, 100084 (China)

2006-07-01T23:59:59.000Z

414

Analyzing Natural Gas Based Hydrogen Infrastructure - Optimizing Transitions from Distributed to Centralized H2 Production  

E-Print Network (OSTI)

Developing a Refueling Infrastructure for Hydrogen Vehicles:Building a Hydrogen Energy Infrastructure. Annu. Rev. Energybuilding up hydrogen infrastructure that are guided by the

Yang, Christopher; Ogden, Joan M

2005-01-01T23:59:59.000Z

415

Assessing Strategies for Fuel and Electricity Production in a California Hydrogen Economy  

E-Print Network (OSTI)

for hydrogen and electricity demand and supply in Californiademands from hydrogen, electricity demand is projected to0.2% annually. Electricity demands ( excluding hydrogen

McCarthy, Ryan; Yang, Christopher; Ogden, Joan M.

2008-01-01T23:59:59.000Z

416

Metabolic engineering of Caldicellulosiruptor bescii yields increased hydrogen production from lignocellulosic biomass  

NLE Websites -- All DOE Office Websites (Extended Search)

Metabolic Metabolic engineering of Caldicellulosiruptor bescii yields increased hydrogen production from lignocellulosic biomass Minseok Cha 1,3 , Daehwan Chung 1,3 , James G Elkins 2,3 , Adam M Guss 2,3 and Janet Westpheling 1,3* Abstract Background: Members of the anaerobic thermophilic bacterial genus Caldicellulosiruptor are emerging candidates for consolidated bioprocessing (CBP) because they are capable of efficiently growing on biomass without conventional pretreatment. C. bescii produces primarily lactate, acetate and hydrogen as fermentation products, and while some Caldicellulosiruptor strains produce small amounts of ethanol C. bescii does not, making it an attractive background to examine the effects of metabolic engineering. The recent development of methods for genetic manipulation has set the stage for rational engineering of this genus for improved biofuel

417

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

DOE Green Energy (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

Paul A. Erickson

2006-01-01T23:59:59.000Z

418

FutureGen Technologies for Carbon Capture and Storage and Hydrogen and Electricity Production  

NLE Websites -- All DOE Office Websites (Extended Search)

FutureGen FutureGen Technologies for Carbon Capture and Storage and Hydrogen and Electricity Production Office of Fossil Energy U. S. Department of Energy Washington, DC June 2, 2003 Lowell Miller, Director, Office of Coal & Power Systems 24-Jun-03 Slide 2 Office of Fossil Energy Presentation Agenda * FE Hydrogen Program * FutureGen * Carbon Sequestration Leadership Forum (CSLF) 24-Jun-03 Slide 3 Office of Fossil Energy Key Drivers * Decreasing domestic supply will lead to increased imports from less stable regions * Conventional petroleum is finite; production will peak and irreversibly decline due to continually increasing demand * Improving environmental quality - Meeting air emission regulations - Greenhouse gas emissions 0 2 4 6 8 10 12 14 16 18 20 1970 1975 1980 1985 1990 1995 2000 2005

419

Carbonaceous material for production of hydrogen from low heating value fuel gases  

DOE Patents (OSTI)

A process for the catalytic production of hydrogen, from a wide variety of low heating value fuel gases containing carbon monoxide, comprises circulating a carbonaceous material between two reactors--a carbon deposition reactor and a steaming reactor. In the carbon deposition reactor, carbon monoxide is removed from a fuel gas and is deposited on the carbonaceous material as an active carbon. In the steaming reactor, the reactive carbon reacts with steam to give hydrogen and carbon dioxide. The carbonaceous material contains a metal component comprising from about 75% to about 95% cobalt, from about 5% to about 15% iron, and up to about 10% chromium, and is effective in suppressing the production of methane in the steaming reactor.

Koutsoukos, Elias P. (Los Angeles, CA)

1989-01-01T23:59:59.000Z

420

Thermodynamic modeling of hydrogen fluoride production relevant to actinide residue treatment  

Science Conference Proceedings (OSTI)

This report addresses issues specific to generation of hydrogen fluoride via reaction of calcium fluoride with sulfuric acid. This process has been established on a commercial scale and is under consideration for treatment of calcium fluoride residues from uranium processing. Magnesium fluoride slags are also available as a product of uranium processing. The technique of using sulfuric acid for the production of hydrogen fluoride from magnesium fluoride is also under consideration as a residue processing scheme. In the current study, thermodynamic modeling was used to investigate these chemical processing systems. Results presented herein reveal information relevant to selection of processing temperatures and conditions. Details include predicted effects in system composition based on operating temperatures for both the calcium fluoride and the magnesium fluoride systems.

West, M.H.; Axler, K.M.

1995-02-01T23:59:59.000Z

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421

C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN  

DOE Green Energy (OSTI)

The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

Gerald P. Huffman

2004-09-30T23:59:59.000Z

422

Two fluid model using kinetic theory for modeling of one-step hydrogen production gasifier  

SciTech Connect

A Two Fluid Model (TFM) using kinetic theory of granular flow has been developed to describe an innovative process of hydrogen production in a single step. An extended Multi-species of Solid Phase (MSP) method is proposed to simulate the gas-solid heterogeneous reactions in an entrained flow gasifier, as opposed to Single-species of Solid Phase (SSP) in previous studies. The intrinsic equations of methane steam reforming and water-gas shift reactions are used for a good understanding of the reaction mechanism for high concentration of hydrogen production under higher pressure. On the basis of the results of computing, the main feature of core-annular reaction zone is predicted in the fully developed flow region. And the similar flame-like structure for velocity and temperature is observed to emerge from the feed injection zone at the bottom of gasifier. The model well illustrates the effects of CaO on enhancing the concentration of hydrogen and sequestering CO{sub 2} in the process of coal gasification. The advantages of pressure gasification are also shown that coal conversion increases with increasing pressure while H{sub 2}S concentration and tar content decreases. Moreover, there is a steep increase in H{sub 2}S and tar species initiated from the entrance of gasifier and then a decrease at the next section. The model shows good agreement with the measurements of flow field and gas products concentration in laboratory-scale plants.

Yu, L.; Lu, J.; Zhang, X.P.; Zhang, S.J.; Wang, X.L. [Chinese Academy of Sciences, Beijing (China)

2008-11-15T23:59:59.000Z