Sample records for hydrogen analysis h2a

  1. H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional...

    Energy Savers [EERE]

    H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results - Interim Report H2A Hydrogen Delivery Infrastructure Analysis Models and...

  2. Critical Updates to the Hydrogen Analysis Production Model (H2A...

    Broader source: Energy.gov (indexed) [DOE]

    Fuel Cell Technologies Program webinar, "Critical Updates to the Hydrogen Analysis Production Model (H2A v3)." Critical Updates to the Hydrogen Analysis Production Model (H2A v3)...

  3. H2A: Hydrogen Analysis Margaret K. Mann

    E-Print Network [OSTI]

    , Eastman Chemical, Entergy, Exxon Mobil, FERCO, GE, Praxair, Shell, Stuart Energy, Thermochem #12;H2A Skill

  4. H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To: CongestionDevelopment ofofthePerformanceofPathway Options Analysis

  5. Hydrogen Production Analysis Using the H2A v3 Model (Text Version...

    Broader source: Energy.gov (indexed) [DOE]

    25 years of professional experience working on high technology projects and alternative energy analysis. Particular specialties include fuel cell power systems, hydrogen reformer...

  6. Analyzing the Levelized Cost of Centralized and Distributed Hydrogen Production Using the H2A Production Model, Version 2

    SciTech Connect (OSTI)

    Ramsden, T.; Steward, D.; Zuboy, J.

    2009-09-01T23:59:59.000Z

    Analysis of the levelized cost of producing hydrogen via different pathways using the National Renewable Energy Laboratory's H2A Hydrogen Production Model, Version 2.

  7. Hydrogen Analysis

    Broader source: Energy.gov (indexed) [DOE]

    A H2A: Hydrogen Analysis Margaret K. Mann DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29, 2004 Washington, D.C. H2A Charter...

  8. DOE H2A Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube| Department of Energy -StateOffshoreFuelCleanup10 AllDOE H2A Analysis DOE

  9. H2A Delivery: Forecourt Compression & Storage Optimization (Part...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    H2A Delivery: H2A Delivery: Forecourt Compression & Forecourt Compression & Storage Optimization (Part II) Storage Optimization (Part II) Hydrogen Delivery Analysis Meeting May...

  10. H2A Delivery Components Model and Analysis

    Broader source: Energy.gov (indexed) [DOE]

    forms Storage Components Delivery Components -Compressed Gas Tube System -Bulk Liquid Hydrogen System -Geologic -Forecourt -Truck - Tube Trailer -Truck - LH2 -Pipeline...

  11. Hydrogen Analysis (H2A) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetecGtel JumpCounty, Texas: EnergyHy9 CorporationHydraA) Jump to: navigation,

  12. Hydrogen Analysis (H2A) Production Component Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar PowerCommercialEnergySandy-Nor'easterHybrid

  13. H2A Delivery Scenario Model and Analyses

    Broader source: Energy.gov (indexed) [DOE]

    H2A Delivery Scenario Model and Analyses Marianne Mintz and Jerry Gillette DOE Hydrogen Delivery Analysis and High Pressure Tanks R&D Project Review Meeting February 8, 2005 2...

  14. Solar-thermal Water Splitting Using the Sodium Manganese Oxide Process & Preliminary H2A Analysis

    SciTech Connect (OSTI)

    Todd M. Francis, Paul R. Lichty, Christopher Perkins, Melinda Tucker, Peter B. Kreider, Hans H. Funke, Allan Lewandowski, and Alan W. Weimer

    2012-10-24T23:59:59.000Z

    There are three primary reactions in the sodium manganese oxide high temperature water splitting cycle. In the first reaction, Mn2O3 is decomposed to MnO at 1,500°C and 50 psig. This reaction occurs in a high temperature solar reactor and has a heat of reaction of 173,212 J/mol. Hydrogen is produced in the next step of this cycle. This step occurs at 700°C and 1 atm in the presence of sodium hydroxide. Finally, water is added in the hydrolysis step, which removes NaOH and regenerates the original reactant, Mn2O3. The high temperature solar?driven step for decomposing Mn2O3 to MnO can be carried out to high conversion without major complication in an inert environment. The second step to produce H2 in the presence of sodium hydroxide is also straightforward and can be completed. The third step, the low temperature step to recover the sodium hydroxide is the most difficult. The amount of energy required to essentially distill water to recover sodium hydroxide is prohibitive and too costly. Methods must be found for lower cost recovery. This report provides information on the use of ZnO as an additive to improve the recovery of sodium hydroxide.

  15. Hydrogen Analysis Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    NREL factsheet that describes the general activites of the Hydrogen Analysis Group within NREL's Hydrogen Technologies and Systems Center.

  16. H2A Delivery: H2A Delivery

    E-Print Network [OSTI]

    forecourt Number of dispensers Capacity of hydrogen storage Size of hydrogen compressor or pump Optimize (Part II) Storage Optimization (Part II) Hydrogen Delivery Analysis Meeting May 8-9, 2007 Columbia. 408-517-1550 Reference: D0348 © 2007 TIAX LLC #12;Objectives Define the attributes of a hydrogen

  17. H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results

    E-Print Network [OSTI]

    and Distribution Pipeline Pressures 2.1.7 .........................................................2-13 Gaseous Technology Venture, Gas Technology Institute, National Renewable Energy Laboratory, Pacific Northwest

  18. Critical Updates to the Hydrogen Analysis Production Model (H2A...

    Broader source: Energy.gov (indexed) [DOE]

    of information. There are fuel prices that have been downloaded from the AEO (Annual Energy Outlook) website. There are fuel properties that were taken from the HyARC...

  19. Critical Updates to the Hydrogen Analysis Production Model (H2A v3) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platformBuildingCoalComplex(GC-72)Columbia Government |Energyl n t liA

  20. Critical Updates to the Hydrogen Analysis Production Model (H2A v3)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave theJuly 30,Crafty Gifts for theof Energy 1:Department

  1. Webinar: Critical Updates to the Hydrogen Analysis Production Model (H2A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: SinceDevelopment | Department ofPartnerships ToolkitWaste Heatv3) | Department of Energy

  2. H2A Hydrogen Production Analysis Tool (Presentation) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-TankModels

  3. H2A Production Model, Version 2 User Guide

    SciTech Connect (OSTI)

    Steward, D.; Ramsden, T.; Zuboy, J.

    2008-09-01T23:59:59.000Z

    The H2A Production Model analyzes the technical and economic aspects of central and forecourt hydrogen production technologies. Using a standard discounted cash flow rate of return methodology, it determines the minimum hydrogen selling price, including a specified after-tax internal rate of return from the production technology. Users have the option of accepting default technology input values--such as capital costs, operating costs, and capacity factor--from established H2A production technology cases or entering custom values. Users can also modify the model's financial inputs. This new version of the H2A Production Model features enhanced usability and functionality. Input fields are consolidated and simplified. New capabilities include performing sensitivity analyses and scaling analyses to various plant sizes. This User Guide helps users already familiar with the basic tenets of H2A hydrogen production cost analysis get started using the new version of the model. It introduces the basic elements of the model then describes the function and use of each of its worksheets.

  4. Joint Meeting on Hydrogen Delivery Modeling and Analysis FreedomCAR and Fuels Partnership Hydrogen Delivery, Storage and

    E-Print Network [OSTI]

    . ­ The current capital costs for the hydrogen pipelines in the model are based on 1.1X the price of steel naturalJoint Meeting on Hydrogen Delivery Modeling and Analysis FreedomCAR and Fuels Partnership Hydrogen be prioritized) by mid-2008 H2A Delivery Model: Discussion Items, Comments, and Follow-up Actions 1. Pipeline

  5. Hydrogen Analysis | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Analysis Hydrogen Analysis Presentation on Hydrogen Analysis to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of...

  6. Hydrogen Delivery Infrastructure Option Analysis

    Broader source: Energy.gov (indexed) [DOE]

    Infrastructure Hydrogen Delivery Infrastructure Option Analysis Option Analysis DOE and FreedomCAR & Fuel Partnership Hydrogen Delivery and On-Board Storage Analysis Workshop...

  7. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  8. 2H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results - Interim Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of BadTHEEnergyReliability2015 Peer Review. d r a m a1, in:

  9. Hydrogen Transition Infrastructure Analysis

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2005-05-01T23:59:59.000Z

    Presentation for the 2005 U.S. Department of Energy Hydrogen Program review analyzes the hydrogen infrastructure needed to accommodate a transitional hydrogen fuel cell vehicle demand.

  10. Hydrogen Delivery Analysis Models

    Broader source: Energy.gov (indexed) [DOE]

    insert our Research Targets to see the impact List of Delivery Components Compressed Hydrogen Gas Truck (Tube trailer) Compressed Hydrogen Gas Truck Terminal Liquid Hydrogen Truck...

  11. H2A Delivery: H2A Delivery

    E-Print Network [OSTI]

    and surroundings 5/8/2007 3 #12;Setback Distances Setback distances specified by NFPA 55 Compressed Hydrogen: 75ft. Public Way: 50 ft. Lot Line: 50 ft. The large setback distances associated with LH2 have

  12. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis of Photoelectrochemical (PEC) Hydrogen Production Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production This report documents the engineering and cost...

  13. Hydrogen Production Infrastructure Options Analysis | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Infrastructure Options Analysis Hydrogen Production Infrastructure Options Analysis Presentation on hydrogen production and infrastructure options presented at the DOE Transition...

  14. Updated Cost Analysis of Photobiological Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report Updated Cost Analysis of Photobiological Hydrogen...

  15. Hydrogen Delivery Infrastructure Options Analysis

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report, by the Nexant team, documents an in-depth analysis of seven hydrogen delivery options to identify the most cost-effective hydrogen infrastructure for the transition and long term. The pro

  16. Geographically Based Hydrogen Demand and Infrastructure Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis Geographically Based Hydrogen Demand and Infrastructure Analysis Presentation by NREL's Margo Melendez at the 2010 - 2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles...

  17. Final Report - Hydrogen Delivery Infrastructure Options Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Hydrogen Delivery Infrastructure Options Analysis Final Report - Hydrogen Delivery Infrastructure Options Analysis This report, by the Nexant team, documents an in-depth analysis...

  18. Hydrogen Data Book from the Hydrogen Analysis Resource Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Hydrogen Data Book contains a wide range of factual information on hydrogen and fuel cells (e.g., hydrogen properties, hydrogen production and delivery data, and information on fuel cells and fuel cell vehicles), and it also provides other data that might be useful in analyses of hydrogen infrastructure in the United States (e.g., demographic data and data on energy supply and/or infrastructure). Its made available from the Hydrogen Analysis Resource Center along with a wealth of related information. The related information includes guidelines for DOE Hydrogen Program Analysis, various calculator tools, a hydrogen glossary, related websites, and analysis tools relevant to hydrogen and fuel cells. [From http://hydrogen.pnl.gov/cocoon/morf/hydrogen

  19. Hydrogen Delivery Infrastructure Analysis, Options and Trade...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis, Options and Trade-offs, Transition and Long-term Hydrogen Delivery Infrastructure Analysis, Options and Trade-offs, Transition and Long-term Presentation on Hydrogen...

  20. Controlled Hydrogen Fleet and Infrastructure Analysis (Presentation)

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.

    2010-06-10T23:59:59.000Z

    This presentation summarizes controlled hydrogen fleet & infrastructure analysis undertaken for the DOE Fuel Cell Technologies Program.

  1. Hydrogen Strategies: an Integrated Resource Planning Analysis for the Development of Hydrogen Energy Infrastructures

    E-Print Network [OSTI]

    Pigneri, Attilio

    2005-01-01T23:59:59.000Z

    analysis of hydrogen infrastructure development strategiesalso presented. Keywords: Hydrogen Infrastructure, Renewableof a Tasmanian hydrogen infrastructure is performed

  2. Hydrogen for Energy Storage Analysis Overview (Presentation)

    SciTech Connect (OSTI)

    Steward, D. M.; Ramsden, T.; Harrison, K.

    2010-06-01T23:59:59.000Z

    Overview of hydrogen for energy storage analysis presented at the National Hydrogen Association Conference & Expo, May 3-6, 2010, Long Beach, CA.

  3. Controlled Hydrogen Fleet and Infrastructure Analysis (Presentation)

    SciTech Connect (OSTI)

    Wipke, K.

    2007-05-17T23:59:59.000Z

    This presentation by Keith Wipke at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's Controlled Hydrogen Fleet and Infrastructure Analysis Project.

  4. Technical Analysis of Hydrogen Production

    SciTech Connect (OSTI)

    Ali T-Raissi

    2005-01-14T23:59:59.000Z

    The aim of this work was to assess issues of cost, and performance associated with the production and storage of hydrogen via following three feedstocks: sub-quality natural gas (SQNG), ammonia (NH{sub 3}), and water. Three technology areas were considered: (1) Hydrogen production utilizing SQNG resources, (2) Hydrogen storage in ammonia and amine-borane complexes for fuel cell applications, and (3) Hydrogen from solar thermochemical cycles for splitting water. This report summarizes our findings with the following objectives: Technoeconomic analysis of the feasibility of the technology areas 1-3; Evaluation of the hydrogen production cost by technology areas 1; and Feasibility of ammonia and/or amine-borane complexes (technology areas 2) as a means of hydrogen storage on-board fuel cell powered vehicles. For each technology area, we reviewed the open literature with respect to the following criteria: process efficiency, cost, safety, and ease of implementation and impact of the latest materials innovations, if any. We employed various process analysis platforms including FactSage chemical equilibrium software and Aspen Technologies AspenPlus and HYSYS chemical process simulation programs for determining the performance of the prospective hydrogen production processes.

  5. Cost Analysis of Hydrogen Storage Systems

    Broader source: Energy.gov (indexed) [DOE]

    Cost Analysis of Hydrogen Cost Analysis of Hydrogen Storage Systems Storage Systems TIAX LLC 15 Acorn Park Cambridge, MA 02140-2390 Tel. 617- 498-5000 Fax 617-498-7200...

  6. Thermochemical Analysis of Hydrogen Absorption in Welding

    E-Print Network [OSTI]

    Eagar, Thomas W.

    '' .' j I ~l Thermochemical Analysis of Hydrogen Absorption in Welding A new model that addresses the shortcomings of Sievert's law for predicting hydrogen absorption is proposed ABSTRACT. A systematic review of diatomic hydrogen) to calcu· late the hydrogen absorption reaction temperature in the weld pool is invalid

  7. Agenda for the Hydrogen Delivery and Onboard Storage Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage Analysis Workshop Agenda for the Hydrogen Delivery and Onboard Storage...

  8. H2A Delivery: Forecourt Compression & Storage Optimization (Part...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    H2A Delivery: Forecourt Compression & Storage Optimization (Part II) H2A Delivery: Forecourt Compression & Storage Optimization (Part II) Presentation by Matthew Hooks of TIAX at...

  9. H2A Delivery Models and Results

    Broader source: Energy.gov (indexed) [DOE]

    Single delivery mode - 100 kgd or 1500 kgd forecourts * Delivery mode defined by user - Pipeline with geologic storage - Liquid hydrogen (LH2) via terminal and truck - Compressed...

  10. Analysis Models and Tools: Systems Analysis of Hydrogen and Fuel...

    Office of Environmental Management (EM)

    and Fuel Cells Analysis Models and Tools: Systems Analysis of Hydrogen and Fuel Cells The Fuel Cell Technologies Office's systems analysis program uses a consistent set of models...

  11. DOE Hydrogen Transition Analysis Workshop Discussion Comments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop Discussion Comments, Questions, and Action Items DOE Hydrogen Transition Analysis Workshop Discussion Comments, Questions, and Action Items Discussion comments, questions,...

  12. DOE Hydrogen Transition Analysis Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis Workshop DOE Hydrogen Transition Analysis Workshop The U.S. Department of Energy sponsored a Hydrogen Transition Analysis Workshop in Washington, DC, on January 26,...

  13. Hydrogen and Water: An Engineering, Economic and Environmental Analysis

    SciTech Connect (OSTI)

    Simon, A J; Daily, W; White, R G

    2010-01-06T23:59:59.000Z

    The multi-year program plan for the Department of Energy's Hydrogen and Fuel Cells Technology Program (USDOE, 2007a) calls for the development of system models to determine economic, environmental and cross-cutting impacts of the transition to a hydrogen economy. One component of the hydrogen production and delivery chain is water; water's use and disposal can incur costs and environmental consequences for almost any industrial product. It has become increasingly clear that due to factors such as competing water demands and climate change, the potential for a water-constrained world is real. Thus, any future hydrogen economy will need to be constructed so that any associated water impacts are minimized. This, in turn, requires the analysis and comparison of specific hydrogen production schemes in terms of their water use. Broadly speaking, two types of water are used in hydrogen production: process water and cooling water. In the production plant, process water is used as a direct input for the conversion processes (e.g. steam for Steam Methane Reforming {l_brace}SMR{r_brace}, water for electrolysis). Cooling water, by distinction, is used indirectly to cool related fluids or equipment, and is an important factor in making plant processes efficient and reliable. Hydrogen production further relies on water used indirectly to generate other feedstocks required by a hydrogen plant. This second order indirect water is referred to here as 'embedded' water. For example, electricity production uses significant quantities of water; this 'thermoelectric cooling' contributes significantly to the total water footprint of the hydrogen production chain. A comprehensive systems analysis of the hydrogen economy includes the aggregate of the water intensities from every step in the production chain including direct, indirect, and embedded water. Process and cooling waters have distinct technical quality requirements. Process water, which is typically high purity (limited dissolved solids) is used inside boilers, reactors or electrolyzers because as it changes phase or is consumed, it leaves very little residue behind. Pre-treatment of 'raw' source water to remove impurities not only enables efficient hydrogen production, but also reduces maintenance costs associated with component degradation due to those impurities. Cooling water has lower overall quality specifications, though it is required in larger volumes. Cooling water has distinct quality requirements aimed at preserving the cooling equipment by reducing scaling and fouling from untreated water. At least as important as the quantity, quality and cost of water inputs to a process are the quantity, quality and cost of water discharge. In many parts of the world, contamination from wastewater streams is a far greater threat to water supply than scarcity or drought (Brooks, 2002). Wastewater can be produced during the pre-treatment processes for process and cooling water, and is also sometimes generated during the hydrogen production and cooling operations themselves. Wastewater is, by definition, lower quality than supply water. Municipal wastewater treatment facilities can handle some industrial wastewaters; others must be treated on-site or recycled. Any of these options can incur additional cost and/or complexity. DOE's 'H2A' studies have developed cost and energy intensity estimates for a variety of hydrogen production pathways. These assessments, however, have not focused on the details of water use, treatment and disposal. As a result, relatively coarse consumption numbers have been used to estimate water intensities. The water intensity for hydrogen production ranges between 1.5-40 gallons per kilogram of hydrogen, including the embedded water due to electricity consumption and considering the wide variety of hydrogen production, water treatment, and cooling options. Understanding the consequences of water management choices enables stakeholders to make informed decisions regarding water use. Water is a fundamentally regional commodity. Water resources vary in quality and qu

  14. Lifecycle Cost Analysis of Hydrogen Versus Other Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy...

  15. Agent-Based Modeling and Simulation for Hydrogen Transition Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agent-Based Modeling and Simulation for Hydrogen Transition Analysis Agent-Based Modeling and Simulation for Hydrogen Transition Analysis Presentation on Agent-Based Modeling and...

  16. Techno-Economic Boundary Analysis of Biological Pathways to Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techno-Economic Boundary Analysis of Biological Pathways to Hydrogen Production (2009) Techno-Economic Boundary Analysis of Biological Pathways to Hydrogen Production (2009)...

  17. Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM...

    Office of Environmental Management (EM)

    Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM) and Results Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM) and Results This presentation by...

  18. DOE Hydrogen Transition Analysis Workshop: Final Attendees List...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Attendees List DOE Hydrogen Transition Analysis Workshop: Final Attendees List Attendee list for the DOE Hydrogen Transition Analysis Workshop on January 26, 2006....

  19. DOE Hydrogen Transition Analysis Workshop: Final Agenda | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agenda DOE Hydrogen Transition Analysis Workshop: Final Agenda Agenda for the DOE Hydrogen Transition Analysis Workshop on January 26, 2006. transitionwkshpagenda.pdf More...

  20. Improvements to Hydrogen Delivery Scenario Analysis

    E-Print Network [OSTI]

    Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM) and Results May 8, 2007 Amgad and storage are at or adjacent to Liquid Hydrogen (LH) TruckH2 Production 100 or 1500 kg/d Compressed H2 (CH) Truck H2 Production 3 or 7 kpsi 100 or 1500 kg/d H2 Production Gaseous H2 Pipeline 100 or 1500 kg

  1. Hydrogen Delivery Analysis Amgad Elgowainy (ANL), Marianne Mintz

    E-Print Network [OSTI]

    Hydrogen Truck Liquid Hydrogen Truck Terminal H2 Transmission Compressor H2 Forecourt Compressor HydrogenHydrogen Delivery Analysis Models Amgad Elgowainy (ANL), Marianne Mintz (ANL), Jerry Gillette (ANL Components Compressed Hydrogen Gas Truck (Tube trailer) Compressed Hydrogen Gas Truck Terminal Liquid

  2. ANALYSIS OF POWER BALANCING WITH FUEL CELLS & HYDROGEN

    E-Print Network [OSTI]

    ANALYSIS OF POWER BALANCING WITH FUEL CELLS & HYDROGEN PRODUCTION PLANTS IN DENMARK Support program;"Analysis of power balancing with fuel cells & hydrogen production plants in Denmark" March 2009 Project-TO-TANK..........................................................................................................26 C.1 Hydrogen production from electrolysis

  3. Economic Analysis of a Nuclear Reactor Powered High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    E. A. Harvego; M. G. McKellar; M. S. Sohal; J. E. O'Brien; J. S. Herring

    2008-08-01T23:59:59.000Z

    A reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production was developed to provide a basis for comparing the HTE concept with other hydrogen production concepts. The reference plant design is driven by a high-temperature helium-cooled nuclear reactor coupled to a direct Brayton power cycle. The reference design reactor power is 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 540C and 900C, respectively. The electrolysis unit used to produce hydrogen includes 4,009,177 cells with a per-cell active area of 225 cm2. The optimized design for the reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes an air-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The inlet air for the air-sweep system is compressed to the system operating pressure of 5.0 MPa in a four-stage compressor with intercooling. The alternating-current, AC, to direct-current, DC, conversion efficiency is 96%. The overall system thermal-to-hydrogen production efficiency (based on the lower heating value of the produced hydrogen) is 47.12% at a hydrogen production rate of 2.356 kg/s. An economic analysis of this plant was performed using the standardized H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program, and using realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.23/kg of hydrogen was calculated assuming an internal rate of return of 10%.

  4. Geographically-Based Hydrogen Demand & Infrastructure Rollout Scenario Analysis (Presentation)

    SciTech Connect (OSTI)

    Melendez, M.

    2007-05-17T23:59:59.000Z

    This presentation by Margo Melendez at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's Hydrogen Demand & Infrastructure Rollout Scenario Analysis.

  5. Joint Meeting on Hydrogen Delivery Modeling and Analysis Meeting...

    Broader source: Energy.gov (indexed) [DOE]

    Meeting on Hydrogen Delivery Modeling and Analysis FreedomCAR and Fuels Partnership Hydrogen Delivery, Storage and Fuel Pathway Integration Tech Teams May 8-9, 2007 Energetics...

  6. Controlled Hydrogen Fleet and Infrastructure Analysis (2008 Presentation)

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.

    2008-06-10T23:59:59.000Z

    This presentation by Keith Wipke at the 2008 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's Controlled Hydrogen Fleet and Infrastructure Analysis Project.

  7. Analysis of a Cluster Strategy for Near Term Hydrogen Infrastructure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Cluster Strategy for Near Term Hydrogen Infrastructure Rollout in Southern California Analysis of a Cluster Strategy for Near Term Hydrogen Infrastructure Rollout in Southern...

  8. Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report Proceedings of the 2001 U.S. DOE Hydrogen Program Review...

  9. H2A Biomethane Model Documentation and a Case Study for Biogas From Dairy Farms

    SciTech Connect (OSTI)

    Saur, G.; Jalalzadeh, A.

    2010-12-01T23:59:59.000Z

    The new H2A Biomethane model was developed to estimate the levelized cost of biomethane by using the framework of the vetted original H2A models for hydrogen production and delivery. For biomethane production, biogas from sources such as dairy farms and landfills is upgraded by a cleanup process. The model also estimates the cost to compress and transport the product gas via the pipeline to export it to the natural gas grid or any other potential end-use site. Inputs include feed biogas composition and cost, required biomethane quality, cleanup equipment capital and operations and maintenance costs, process electricity usage and costs, and pipeline delivery specifications.

  10. Hydrogen Storage Systems Analysis Working Group Meeting 2007 Hydrogen Program Annual Review

    E-Print Network [OSTI]

    applications. The IPHE (International Partnership for the Hydrogen Economy) safety program to assess storageHydrogen Storage Systems Analysis Working Group Meeting 2007 Hydrogen Program Annual Review Crystal Laboratory and Elvin Yuzugullu Sentech, Inc. June 28, 2007 #12;SUMMARY REPORT Hydrogen Storage

  11. Screening analysis of solar thermochemical hydrogen concepts.

    SciTech Connect (OSTI)

    Diver, Richard B., Jr.; Kolb, Gregory J.

    2008-03-01T23:59:59.000Z

    A screening analysis was performed to identify concentrating solar power (CSP) concepts that produce hydrogen with the highest efficiency. Several CSP concepts were identified that have the potential to be much more efficient than today's low-temperature electrolysis technology. They combine a central receiver or dish with either a thermochemical cycle or high-temperature electrolyzer that operate at temperatures >600 C. The solar-to-hydrogen efficiencies of the best central receiver concepts exceed 20%, significantly better than the 14% value predicted for low-temperature electrolysis.

  12. Agent-Based Modeling and Simulation for Hydrogen Transition Analysis

    Broader source: Energy.gov [DOE]

    Presentation on Agent-Based Modeling and Simulation for Hydrogen Transition Analysis given by Marianne Mintz of ANL during the DOE Hydrogen Transition Analysis Workshop on January 26, 2006.

  13. Analysis of C H...O hydrogen bonds

    E-Print Network [OSTI]

    Babu, M. Madan

    1 Analysis of C H...O hydrogen bonds in high resolution protein crystal structures from the PDB 1.4 Identification of C-H...O hydrogen bonds............................................. 1.4.1 The definition of a C-H...O hydrogen bond.................................... 1.4.2 Fixing the hydrogen and measuring the parameters

  14. System Evaluation and Life-Cycle Cost Analysis of a Commercial-Scale High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Edwin A. Harvego; James E. O'Brien; Michael G. McKellar

    2012-11-01T23:59:59.000Z

    Results of a system evaluation and lifecycle cost analysis are presented for a commercial-scale high-temperature electrolysis (HTE) central hydrogen production plant. The plant design relies on grid electricity to power the electrolysis process and system components, and industrial natural gas to provide process heat. The HYSYS process analysis software was used to evaluate the reference central plant design capable of producing 50,000 kg/day of hydrogen. The HYSYS software performs mass and energy balances across all components to allow optimization of the design using a detailed process flow sheet and realistic operating conditions specified by the analyst. The lifecycle cost analysis was performed using the H2A analysis methodology developed by the Department of Energy (DOE) Hydrogen Program. This methodology utilizes Microsoft Excel spreadsheet analysis tools that require detailed plant performance information (obtained from HYSYS), along with financial and cost information to calculate lifecycle costs. The results of the lifecycle analyses indicate that for a 10% internal rate of return, a large central commercial-scale hydrogen production plant can produce 50,000 kg/day of hydrogen at an average cost of $2.68/kg. When the cost of carbon sequestration is taken into account, the average cost of hydrogen production increases by $0.40/kg to $3.08/kg.

  15. Hydrogen Storage Systems Analysis Meeting: Summary Report, March...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting: Summary Report, March 29, 2005 Hydrogen Storage Systems Analysis Meeting: Summary Report, March 29, 2005 This report highlights DOE's systems analysis work related to...

  16. Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Wind Turbine Towers: Cost Analysis and Conceptual Design Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual Design Preprint 34851.pdf More Documents &...

  17. Hydrogen Fueling Station in Honolulu, Hawaii Feasibility Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fueling Station in Honolulu, Hawaii Feasibility Analysis Hydrogen Fueling Station in Honolulu, Hawaii Feasibility Analysis This feasibility report assesses the technical and...

  18. Analysis of Hydrogen Production from Renewable Electricity Sources: Preprint

    SciTech Connect (OSTI)

    Levene, J. I.; Mann, M. K.; Margolis, R.; Milbrandt, A.

    2005-09-01T23:59:59.000Z

    To determine the potential for hydrogen production via renewable electricity sources, three aspects of the system are analyzed: a renewable hydrogen resource assessment, a cost analysis of hydrogen production via electrolysis, and the annual energy requirements of producing hydrogen for refueling. The results indicate that ample resources exist to produce transportation fuel from wind and solar power. However, hydrogen prices are highly dependent on electricity prices.

  19. Economic Analysis of Hydrogen Energy Station Concepts: Are "H 2E-Stations" a Key Link to a Hydrogen Fuel Cell Vehicle Infrastructure?

    E-Print Network [OSTI]

    Lipman, Timothy E.; Edwards, Jennifer L.; Kammen, Daniel M.

    2002-01-01T23:59:59.000Z

    in the analysis of hydrogen energy stations, additionalattractiveness of the hydrogen energy station scheme in bothECONOMIC ANALYSIS OF HYDROGEN ENERGY STATION CONCEPTS: ARE '

  20. Hydrogen Delivery Scenario Analysis Model (HDSAM)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe SolarContamination Detector Workshop HydrogenScenario Analysis

  1. ECONOMIC FEASIBILITY ANALYSIS OF HYDROGEN PRODUCTION BY

    E-Print Network [OSTI]

    steps (syngas generation, shift conversion and hydrogen purification) necessary for hydrogen production for this process option. O2 H2 air N.G. + Steam Hydrogen H2-depleted syngas OTM Reactor HTM Reactor syngas Figure 1- gas. A portion of natural gas also reacts with steam to form syngas. Additional hydrogen is formed

  2. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    2008. Analysis of the Transition to Hydrogen Fuel CellVehicles & the Potential Hydrogen Energy InfrastructureH. Mooiewek, (2007) Hydrogen Infrastructure Fueling

  3. Hydrogen Storage Systems Analysis Working Group Meeting: Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Summary of June 11, 2008, biannual meeting of the Hydrogen Storage Systems Analysis Working Group. ssawgsummaryreport0608.pdf More Documents & Publications Hydrgoen Storage...

  4. Hydrogen Storage Systems Analysis Working Group Meeting: Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to bring together the DOE research community involved in systems analysis of hydrogen storage materials and processes. ssawgsummaryreport.pdf More Documents & Publications...

  5. Hydrogen Storage Systems Analysis Working Group Meeting: Summary...

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Storage Systems Analysis Working Group Meeting Argonne DC Offices L'Enfant Plaza, Washington, DC December 4, 2007 SUMMARY REPORT Compiled by Romesh Kumar Argonne National...

  6. Potential Role of Exergy in Analysis of Hydrogen Infrastructure

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A. A.

    2008-01-01T23:59:59.000Z

    The objective of this paper is to demonstrate the potential role of exergy (second-law) analysis, as a complementary tool for economic assessments of hydrogen infrastructures.

  7. 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and...

    Office of Environmental Management (EM)

    Systems Analysis 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and Infrastructure 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and Infrastructure...

  8. DOE H2A Analysis | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,Office of Policy, OAPM |TRU Waste Cleanup at1450.5B 2010 MEMORANDUM FORSystems

  9. Analysis of a supercritical hydrogen liquefaction cycle

    E-Print Network [OSTI]

    Staats, Wayne Lawrence

    2008-01-01T23:59:59.000Z

    In this work, a supercritical hydrogen liquefaction cycle is proposed and analyzed numerically. If hydrogen is to be used as an energy carrier, the efficiency of liquefaction will become increasingly important. By examining ...

  10. Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReview |Panel HydrogenM M aDesignJanuary

  11. Systems analysis of hydrogen supplementation in natural gas pipelines

    SciTech Connect (OSTI)

    Hermelee, A.; Beller, M.; D'Acierno, J.

    1981-11-01T23:59:59.000Z

    The potential for hydrogen supplementation in natural gas pipelines is analyzed for a specific site from both mid-term (1985) and long-term perspectives. The concept of supplementing natural gas with the addition of hydrogen in the existing gas pipeline system serves to provide a transport and storage medium for hydrogen while eliminating the high investment costs associated with constructing separate hydrogen pipelines. This paper examines incentives and barriers to the implementation of this concept. The analysis is performed with the assumption that current developmental programs will achieve a process for cost-effectively separating pure hydrogen from natural gas/hydrogen mixtures to produce a separable and versatile chemical and fuel commodity. The energy systems formulation used to evaluate the role of hydrogen in the energy infrastructure is the Reference Energy System (RES). The RES is a network diagram that provides an analytic framework for incorporating all resources, technologies, and uses of energy in a uniform manner. A major aspect of the study is to perform a market analysis of traditional uses of resources in the various consuming sectors and the potential for hydrogen substitution in these sectors. The market analysis will focus on areas of industry where hydrogen is used as a feedstock rather than for its fuel-use opportunities to replace oil and natural gas. The sectors of industry where hydrogen is currently used and where its use can be expanded or substituted for other resources include petroleum refining, chemicals, iron and steel, and other minor uses.

  12. Hydrogen Storage Testing and Analysis R&D | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    DOE R&D Activities Hydrogen Storage Testing and Analysis R&D Hydrogen Storage Testing and Analysis R&D DOE's hydrogen storage R&D activities include testing, analysis, and...

  13. H2A Delivery Models and Results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-TankModels and Results H2A

  14. Economic Analysis of the Reference Design for a Nuclear-Driven High-Temperature-Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    E. A. Harvego; M. G. McKellar; M. S. Sohal; J. E. O'Brien; J. S. Herring

    2008-01-01T23:59:59.000Z

    A reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production was developed to provide a basis for comparing the HTE concept with other hydrogen production concepts. The reference plant design is driven by a high-temperature helium-cooled reactor coupled to a direct Brayton power cycle. The reference design reactor power is 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 540C and 900C, respectively. The electrolysis unit used to produce hydrogen consists of 4,009,177 cells with a per-cell active area of 225 cm2. A nominal cell area-specific resistance, ASR, value of 0.4 Ohmcm2 with a current density of 0.25 A/cm2 was used, and isothermal boundary conditions were assumed. The optimized design for the reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes an air-sweep system to remove the excess oxygen that is evolved on the anode side of the electrolyzer. The inlet air for the air-sweep system is compressed to the system operating pressure of 5.0 MPa in a four-stage compressor with intercooling. The alternating current, AC, to direct current, DC, conversion is 96%. The overall system thermal-to-hydrogen production efficiency (based on the low heating value of the produced hydrogen) is 47.12% at a hydrogen production rate of 2.356 kg/s. An economic analysis of the plant was also performed using the H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost using realistic financial and cost estimating assumptions. A required cost of $3.23 per kg of hydrogen produced was calculated assuming an internal rate of return of 10%. Approximately 73% of this cost ($2.36/kg) is the result of capital costs associated with the construction of the combined nuclear plant and hydrogen production facility. Operation and maintenance costs represent about 18% of the total cost ($0.57/kg). Variable costs (including the cost of nuclear fuel) contribute about 8.7% ($0.28/kg) to the total cost of hydrogen production, and decommissioning and raw material costs make up the remaining fractional cost.

  15. Analysis of Hybrid Hydrogen Systems: Final Report

    SciTech Connect (OSTI)

    Dean, J.; Braun, R.; Munoz, D.; Penev, M.; Kinchin, C.

    2010-01-01T23:59:59.000Z

    Report on biomass pathways for hydrogen production and how they can be hybridized to support renewable electricity generation. Two hybrid systems were studied in detail for process feasibility and economic performance. The best-performing system was estimated to produce hydrogen at costs ($1.67/kg) within Department of Energy targets ($2.10/kg) for central biomass-derived hydrogen production while also providing value-added energy services to the electric grid.

  16. Hydrogen Infrastructure Transition Analysis: Milestone Report

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2006-01-01T23:59:59.000Z

    This milestone report identifies a minimum infrastructure that could support the introduction of hydrogen vehicles and develops and evaluates transition scenarios supported by this infrastructure.

  17. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report documents the engineering and cost characteristics of four PEC hydrogen production systems selected by DOE to represent canonical embodiments of future systems.

  18. Sandia National Laboratories: Hydrogen Financial Analysis Tool

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the National Renewable Energy Laboratory (NREL) announce the publication of two new Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) reports on...

  19. TECHNOECONOMIC ANALYSIS OF AREA II HYDROGEN PRODUCTION -PART II

    E-Print Network [OSTI]

    storage medium for hydrogen produced by the ocean thermal energy conversion (OTEC) plantships [16 Florida Solar Energy Center Cocoa, FL 32922-5703, ali@fsec.ucf.edu Abstract The aim of this analysis power interface, 3) Ammonia and ammonia adducts as hydrogen energy storers for fuel cell applications

  20. Final Report - Hydrogen Delivery Infrastructure Options Analysis

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen from Wind and Competing Sources", Conference Paper NRELCP-620-38138, May 2005 7 Smith, Steven J., et.a., (Battelle Memorial Institute, College Park, Maryland), "Near-Term...

  1. DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project...

    Broader source: Energy.gov (indexed) [DOE]

    the DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project Review Meeting at Argonne National Laboratory. The purpose of the meeting was to review the progress and plans...

  2. Analysis of Hydrogen and Competing Technologies for Utility-Scale Energy Storage (Presentation)

    SciTech Connect (OSTI)

    Steward, D.

    2010-02-11T23:59:59.000Z

    Presentation about the National Renewable Energy Laboratory's analysis of hydrogen energy storage scenarios, including analysis framework, levelized cost comparison of hydrogen and competing technologies, analysis results, and conclusions drawn from the analysis.

  3. Hydrogen Technical Analysis -- Dissemination of Information

    SciTech Connect (OSTI)

    George Kervitsky, Jr.

    2006-03-20T23:59:59.000Z

    SENTECH is a small energy and environmental consulting firm providing technical, analytical, and communications solutions to technology management issues. The activities proposed by SENTECH focused on gathering and developing communications materials and information, and various dissemination activities to present the benefits of hydrogen energy to a broad audience while at the same time establishing permanent communications channels to enable continued two-way dialog with these audiences in future years. Effective communications and information dissemination is critical to the acceptance of new technology. Hydrogen technologies face the additional challenge of safety preconceptions formed primarily as a result of the crash of the Hindenburg. Effective communications play a key role in all aspects of human interaction, and will help to overcome the perceptual barriers, whether of safety, economics, or benefits. As originally proposed SENTECH identified three distinct information dissemination activities to address three distinct but important audiences; these formed the basis for the task structure used in phases 1 and 2. The tasks were: (1) Print information--Brochures that target the certain segment of the population and will be distributed via relevant technical conferences and traditional distribution channels. (2) Face-to-face meetings--With industries identified to have a stake in hydrogen energy. The three industry audiences are architect/engineering firms, renewable energy firms, and energy companies that have not made a commitment to hydrogen (3) Educational Forums--The final audience is students--the future engineers, technicians, and energy consumers. SENTECH will expand on its previous educational work in this area. The communications activities proposed by SENTECH and completed as a result of this cooperative agreement was designed to compliment the research and development work funded by the DOE by presenting the technical achievements and validations of hydrogen energy technologies to non-traditional audiences. These activities were also designed to raise the visibility of the DOE Hydrogen Program to new audiences and to help the program continue to advance its mission and vision. We believe that the work conducted under this cooperative agreement was successful at meeting the objectives presented and funded over the period of performance. During Phase 1, SENTECHs activities resulted in the development and distribution of two glossy brochures that target the on-site distributed generation and public transit markets for hydrogen energy technologies; face-to-face industry outreach meetings with various firms with an interest in hydrogen energy, but who may not have made a commitment to be involved; and implementation of two educational forums on hydrogen for students - the future engineers, technicians, and energy consumers. The educational forums were conducted with in-kind cost-shared contributions from NHA and Dr. Robert Reeves, Professor Emeritus, Rensealler During Phase 2, SENTECH activities initially were focused on the development of additional brochures and the development of a series of training modules. This set of information dissemination activities built on the experience demonstrated in our phase one activities, and focused the effort within two critical issue areas facing the development of hydrogen as an energy carrier--effective communications and information dissemination on codes and standards. SENTECH joined with the National Fire Protection Association (NFPA) to scope out the training modules and identified a series of 12 that could be used to train a variety of audiences. The NFPA is an international nonprofit corporation, which has developed a reputation as a worldwide leader in providing fire, electrical, and life safety to the public since 1896. Its membership totals more than 75,000 individuals from around the world and in more than 80 national trade and professional organizations.

  4. DOE Hydrogen Program Systems Analysis Workshop

    E-Print Network [OSTI]

    ) Define analysis scenarios NREL SYSTEMS INTEGRATION Accountable for analysis activities Provide inputs Coordinate and provide ideas/recommendations to SI on cross-cutting analysis Manage analysis tasks internal to DOE (Labs/FFRDCs only) Perform analysis of technoeconomic topics for TA and SI Perform subprogram

  5. Hydrogen Infrastructure Transition Analysis: Milestone Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogen and Fuel CellFew-Layer

  6. Hydrogen Strategies: an Integrated Resource Planning Analysis for the Development of Hydrogen Energy Infrastructures

    E-Print Network [OSTI]

    Pigneri, Attilio

    2005-01-01T23:59:59.000Z

    concepts and knowledge in hydrogen energy systems and theirdevelop alternative hydrogen-energy scenarios. The scenariosof alternative hydrogen energy pathways to characterize an

  7. Hydrogen Strategies: an Integrated Resource Planning Analysis for the Development of Hydrogen Energy Infrastructures

    E-Print Network [OSTI]

    Pigneri, Attilio

    2005-01-01T23:59:59.000Z

    concepts and knowledge in hydrogen energy systems and theirInternational Hydrogen Energy Congress and Exhibition IHECthe Development of Hydrogen Energy Infrastructures Attilio

  8. Hydrogen Storage Systems Analysis Working Group Meeting Argonne DC Offices

    E-Print Network [OSTI]

    Hydrogen Storage Systems Analysis Working Group Meeting Argonne DC Offices L'Enfant Plaza, Washington, DC December 4, 2007 SUMMARY REPORT Compiled by Romesh Kumar Argonne National Laboratory Working Group Meeting December 4, 2007 Argonne DC Offices, L'Enfant Plaza, Washington, DC Meeting

  9. Fuel-Cycle Analysis of Hydrogen-Powered Fuel-Cell Systems with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel-Cycle Analysis of Hydrogen-Powered Fuel-Cell Systems with the GREET Model Fuel-Cycle Analysis of Hydrogen-Powered Fuel-Cell Systems with the GREET Model This presentation by...

  10. 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final List of Attendees 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and Infrastructure Final List of Attendees 2010-2025 Scenario Analysis for Hydrogen Fuel Cell...

  11. Agenda for the 2010-2025 Scenario Analysis for Hydrogen Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agenda for the 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and Infrastructure Meeting Agenda for the 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and...

  12. U.S. Department of Energy Hydrogen Storage Cost Analysis

    SciTech Connect (OSTI)

    Law, Karen; Rosenfeld, Jeffrey; Han, Vickie; Chan, Michael; Chiang, Helena; Leonard, Jon

    2013-03-11T23:59:59.000Z

    The overall objective of this project is to conduct cost analyses and estimate costs for on- and off-board hydrogen storage technologies under development by the U.S. Department of Energy (DOE) on a consistent, independent basis. This can help guide DOE and stakeholders toward the most-promising research, development and commercialization pathways for hydrogen-fueled vehicles. A specific focus of the project is to estimate hydrogen storage system cost in high-volume production scenarios relative to the DOE target that was in place when this cost analysis was initiated. This report and its results reflect work conducted by TIAX between 2004 and 2012, including recent refinements and updates. The report provides a system-level evaluation of costs and performance for four broad categories of on-board hydrogen storage: (1) reversible on-board metal hydrides (e.g., magnesium hydride, sodium alanate); (2) regenerable off-board chemical hydrogen storage materials(e.g., hydrolysis of sodium borohydride, ammonia borane); (3) high surface area sorbents (e.g., carbon-based materials); and 4) advanced physical storage (e.g., 700-bar compressed, cryo-compressed and liquid hydrogen). Additionally, the off-board efficiency and processing costs of several hydrogen storage systems were evaluated and reported, including: (1) liquid carrier, (2) sodium borohydride, (3) ammonia borane, and (4) magnesium hydride. TIAX applied a â??bottom-upâ? costing methodology customized to analyze and quantify the processes used in the manufacture of hydrogen storage systems. This methodology, used in conjunction with DFMA?® software and other tools, developed costs for all major tank components, balance-of-tank, tank assembly, and system assembly. Based on this methodology, the figure below shows the projected on-board high-volume factory costs of the various analyzed hydrogen storage systems, as designed. Reductions in the key cost drivers may bring hydrogen storage system costs closer to this DOE target. In general, tank costs are the largest component of system cost, responsible for at least 30 percent of total system cost, in all but two of the 12 systems. Purchased BOP cost also drives system cost, accounting for 10 to 50 percent of total system cost across the various storage systems. Potential improvements in these cost drivers for all storage systems may come from new manufacturing processes and higher production volumes for BOP components. In addition, advances in the production of storage media may help drive down overall costs for the sodium alanate, SBH, LCH2, MOF, and AX-21 systems.

  13. Quantitative analysis of the diffusion of hydrogen peroxide through teeth

    E-Print Network [OSTI]

    Petersen, Brenden Kyle

    2012-01-01T23:59:59.000Z

    activation properties of hydrogen peroxide diffusion the transport properties of hydrogen peroxide Hydrogen peroxide has been shown to readily diffuse through both enamel and dentin, with transport properties

  14. Webinar: Guidance for Filling Out a Detailed H2A Production Case Study

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Guidance for Filling Out a Detailed H2A Production Case Study, originally presented on July 9, 2013.

  15. Hydrogen Scenario Analysis Summary Report: Analysis of the Transition to Hydrogen Fuel Cell Vehicles and the Potential Hydrogen Energy Infrastructure Requirements

    SciTech Connect (OSTI)

    Greene, David L [ORNL; Leiby, Paul Newsome [ORNL; James, Brian [Directed Technologies, Inc.; Perez, Julie [Directed Technologies, Inc.; Melendez, Margo [National Renewable Energy Laboratory (NREL); Milbrandt, Anelia [National Renewable Energy Laboratory (NREL); Unnasch, Stefan [Life Cycle Associates; Rutherford, Daniel [TIAX, LLC; Hooks, Matthew [TIAX, LLC

    2008-03-01T23:59:59.000Z

    Achieving a successful transition to hydrogen-powered vehicles in the U.S. automotive market will require strong and sustained commitment by hydrogen producers, vehicle manufacturers, transporters and retailers, consumers, and governments. The interaction of these agents in the marketplace will determine the real costs and benefits of early market transformation policies, and ultimately the success of the transition itself. The transition to hydrogen-powered transportation faces imposing economic barriers. The challenges include developing and refining a new and different power-train technology, building a supporting fuel infrastructure, creating a market for new and unfamiliar vehicles, and achieving economies of scale in vehicle production while providing an attractive selection of vehicle makes and models for car-buyers. The upfront costs will be high and could persist for a decade or more, delaying profitability until an adequate number of vehicles can be produced and moved into consumer markets. However, the potential rewards to the economy, environment, and national security are immense. Such a profound market transformation will require careful planning and strong, consistent policy incentives. Section 811 of the Energy Policy Act (EPACT) of 2005, Public Law 109-59 (U.S. House, 2005), calls for a report from the Secretary of Energy on measures to support the transition to a hydrogen economy. The report was to specifically address production and deployment of hydrogen-fueled vehicles and the hydrogen production and delivery infrastructure needed to support those vehicles. In addition, the 2004 report of the National Academy of Sciences (NAS, 2004), The Hydrogen Economy, contained two recommendations for analyses to be conducted by the U.S. Department of Energy (DOE) to strengthen hydrogen energy transition and infrastructure planning for the hydrogen economy. In response to the EPACT requirement and NAS recommendations, DOE's Hydrogen, Fuel Cells and Infrastructure Technologies Program (HFCIT) has supported a series of analyses to evaluate alternative scenarios for deployment of millions of hydrogen fueled vehicles and supporting infrastructure. To ensure that these alternative market penetration scenarios took into consideration the thinking of the automobile manufacturers, energy companies, industrial hydrogen suppliers, and others from the private sector, DOE held several stakeholder meetings to explain the analyses, describe the models, and solicit comments about the methods, assumptions, and preliminary results (U.S. DOE, 2006a). The first stakeholder meeting was held on January 26, 2006, to solicit guidance during the initial phases of the analysis; this was followed by a second meeting on August 9-10, 2006, to review the preliminary results. A third and final meeting was held on January 31, 2007, to discuss the final analysis results. More than 60 hydrogen energy experts from industry, government, national laboratories, and universities attended these meetings and provided their comments to help guide DOE's analysis. The final scenarios attempt to reflect the collective judgment of the participants in these meetings. However, they should not be interpreted as having been explicitly endorsed by DOE or any of the stakeholders participating. The DOE analysis examined three vehicle penetration scenarios: Scenario 1--Production of thousands of vehicles per year by 2015 and hundreds of thousands per year by 2019. This option is expected to lead to a market penetration of 2.0 million fuel cell vehicles (FCV) by 2025. Scenario 2--Production of thousands of FCVs by 2013 and hundreds of thousands by 2018. This option is expected to lead to a market penetration of 5.0 million FCVs by 2025. Scenario 3--Production of thousands of FCVs by 2013, hundreds of thousands by 2018, and millions by 2021 such that market penetration is 10 million by 2025. Scenario 3 was formulated to comply with the NAS recommendation: 'DOE should map out and evaluate a transition plan consistent with developing the infrastructure and hydrogen res

  16. The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis

    E-Print Network [OSTI]

    Williams, Loren

    The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis of the Molecular of hydrogen-bondformation between guanine (G) and cytusine (C) in o-dichloro- benzene and in chloroformat 25°C forming hydrogen bonds. Consequently, hydrogen-bond formation in our system is primarily between the bases

  17. 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Summary Presentation 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and Infrastructure Meeting Discussion Group 2 Summary Presentation 2010-2025 Senario Analysis...

  18. 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Summary Presentation 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and Infrastructure Meeting Discussion Group 1 Summary Presentation 2010-2025 Scenario Analysis...

  19. HYDROGEN TECHNICAL ANALYSIS ON MATTERS BEING CONSIDERED BY THE INTERNATIONAL ENERGY AGENCY -

    E-Print Network [OSTI]

    when demand exceeds existing supply · Upstream costs of new hydrogen pipelines · Delivery distance of bulk hydrogen by truck or pipeline The end-use analysis addressed tailpipe emissions of various vehicleHYDROGEN TECHNICAL ANALYSIS ON MATTERS BEING CONSIDERED BY THE INTERNATIONAL ENERGY AGENCY

  20. Macro-System Model for Hydrogen Energy Systems Analysis in Transportation: Preprint

    SciTech Connect (OSTI)

    Diakov, V.; Ruth, M.; Sa, T. J.; Goldsby, M. E.

    2012-06-01T23:59:59.000Z

    The Hydrogen Macro System Model (MSM) is a simulation tool that links existing and emerging hydrogen-related models to perform rapid, cross-cutting analysis. It allows analysis of the economics, primary energy-source requirements, and emissions of hydrogen production and delivery pathways.

  1. Accurate hydrogen depth profiling by reflection elastic recoil detection analysis

    SciTech Connect (OSTI)

    Verda, R. D. (Raymond D.); Tesmer, Joseph R.; Nastasi, Michael Anthony,; Bower, R. W. (Robert W.)

    2001-01-01T23:59:59.000Z

    A technique to convert reflection elastic recoil detection analysis spectra to depth profiles, the channel-depth conversion, was introduced by Verda, et al [1]. But the channel-depth conversion does not correct for energy spread, the unwanted broadening in the energy of the spectra, which can lead to errors in depth profiling. A work in progress introduces a technique that corrects for energy spread in elastic recoil detection analysis spectra, the energy spread correction [2]. Together, the energy spread correction and the channel-depth conversion comprise an accurate and convenient hydrogen depth profiling method.

  2. A theoretical analysis of interstitial hydrogen : pressure-composition-temperature, chemical potential, enthalpy and entropy

    E-Print Network [OSTI]

    Orondo, Peter Omondi

    2012-01-01T23:59:59.000Z

    We provide a first principles analysis of the physics and thermodynamics of interstitial hydrogen in metal. By utilizing recent advances in Density Functional Theory (DFT) to get state energies of the metal-hydrogen system, ...

  3. Hydrogen Storage Systems Analysis Meeting: Summary Report, March...

    Broader source: Energy.gov (indexed) [DOE]

    (W. Luo, SNL), chemical hydrogen storage (C. Aardahl, PNNL), and carbon-based materials and sorbents (M. Ringer, NREL) approaches for hydrogen storage. These discussions...

  4. Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate

    E-Print Network [OSTI]

    Goddard III, William A.

    Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

  5. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    SciTech Connect (OSTI)

    Francis Lau

    2002-12-01T23:59:59.000Z

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

  6. A Near-Term Economic Analysis of Hydrogen Fueling Stations

    E-Print Network [OSTI]

    Weinert, Jonathan X.

    2005-01-01T23:59:59.000Z

    Photovoltaic System Additional Equipment $/yr Installation Costs Contingency Electricity Fixed Operating Costs Total Annual Cost ($/yr) Hydrogen Price (

  7. A Near-term Economic Analysis of Hydrogen Fueling Stations

    E-Print Network [OSTI]

    Weinert, Jonathan X.

    2005-01-01T23:59:59.000Z

    Photovoltaic System Additional Equipment $/yr Installation Costs Contingency Electricity Fixed Operating Costs Total Annual Cost ($/yr) Hydrogen Price (

  8. HYDROGEN TECHNICAL ANALYSIS S. Lasher, M. Stratonova, and J. Thijssen

    E-Print Network [OSTI]

    as an autothermal reformer or hydrogen production from renewables such as biomass), while small-scale PSA

  9. Techno-economic and behavioural analysis of battery electric, hydrogen

    E-Print Network [OSTI]

    conducts a techno-economic study on hydrogen fuel cell electric vehicles (FCV), battery electric vehicles (BEV) and hydrogen fuel cell plug-in hybrid electric vehicles (FCHEV) in the UK using cost predictions reforming methane in 2030. Keywords: Fuel cell vehicle; electric vehicle; hybrid vehicle; hydrogen

  10. A Techno-Economic Analysis of Decentralized Electrolytic Hydrogen Production for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Victoria, University of

    A Techno-Economic Analysis of Decentralized Electrolytic Hydrogen Production for Fuel Cell Vehicles-Economic Analysis of Decentralized Electrolytic Hydrogen Production for Fuel Cell Vehicles by Sbastien Prince options considered for future fuel cell vehicles. In this thesis, a model is developed to determine

  11. Technical Analysis of Hydrogen Production: Evaluation of H2 Mini-Grids

    SciTech Connect (OSTI)

    Lasher, Stephen; Sinha, Jayanti

    2005-05-03T23:59:59.000Z

    We have assessed the transportation of hydrogen as a metal hydride slurry through pipelines over a short distance from a neighborhood hydrogen production facility to local points of use. The assessment was conducted in the context of a hydrogen "mini-grid" serving both vehicle fueling and stationary fuel cell power systems for local building heat and power. The concept was compared to a compressed gaseous hydrogen mini-grid option and to a stand-alone hydrogen fueling station. Based on our analysis results we have concluded that the metal hydride slurry concept has potential to provide significant reductions in overall energy use compared to liquid or chemical hydride delivery, but only modest reductions in overall energy use, hydrogen cost, and GHG emissions compared to a compressed gaseous hydrogen delivery. However, given the inherent (and perceived) safety and reasonable cost/efficiency of the metal hydride slurry systems, additional research and analysis is warranted. The concept could potentially overcome the public acceptance barrier associated with the perceptions about hydrogen delivery (including liquid hydrogen tanker trucks and high-pressure gaseous hydrogen pipelines or tube trailers) and facilitate the development of a near-term hydrogen infrastructure.

  12. Manufacturing Cost Analysis of 10 kW and 25 kW Direct Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis of 10 kW and 25 kW Direct Hydrogen Polymer Electrolyte Membrane (PEM) Fuel Cell for Material Handling Applications Manufacturing Cost Analysis of 10 kW and 25 kW...

  13. Hydrogen Storage Systems Analysis Working Group Meeting: Summary...

    Broader source: Energy.gov (indexed) [DOE]

    Held in Conjunction with the DOE Hydrogen Program Annual Merit Review Crystal Gateway Marriott, Arlington, VA June 11, 2008 SUMMARY REPORT Compiled by Romesh Kumar Argonne...

  14. Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen Production

    SciTech Connect (OSTI)

    James, B. D.; Baum, G. N.; Perez, J.; Baum, K. N.

    2009-09-01T23:59:59.000Z

    Report documenting the biological and engineering characteristics of five algal and bacterial hydrogen production systems selected by DOE and NREL for evaluation.

  15. Analysis of combined hydrogen, heat, and power as a bridge to a hydrogen transition.

    SciTech Connect (OSTI)

    Mahalik, M.; Stephan, C. (Decision and Information Sciences)

    2011-01-18T23:59:59.000Z

    Combined hydrogen, heat, and power (CHHP) technology is envisioned as a means to providing heat and electricity, generated on-site, to large end users, such as hospitals, hotels, and distribution centers, while simultaneously producing hydrogen as a by-product. The hydrogen can be stored for later conversion to electricity, used on-site (e.g., in forklifts), or dispensed to hydrogen-powered vehicles. Argonne has developed a complex-adaptive-system model, H2CAS, to simulate how vehicles and infrastructure can evolve in a transition to hydrogen. This study applies the H2CAS model to examine how CHHP technology can be used to aid the transition to hydrogen. It does not attempt to predict the future or provide one forecast of system development. Rather, the purpose of the model is to understand how the system works. The model uses a 50- by 100-mile rectangular grid of 1-square-mile cells centered on the Los Angeles metropolitan area. The major expressways are incorporated into the model, and local streets are considered to be ubiquitous, except where there are natural barriers. The model has two types of agents. Driver agents are characterized by a number of parameters: home and job locations, income, various types of 'personalities' reflective of marketing distinctions (e.g., innovators, early adopters), willingness to spend extra money on 'green' vehicles, etc. At the beginning of the simulations, almost all driver agents own conventional vehicles. They drive around the metropolitan area, commuting to and from work and traveling to various other destinations. As they do so, they observe the presence or absence of facilities selling hydrogen. If they find such facilities conveniently located along their routes, they are motivated to purchase a hydrogen-powered vehicle when it becomes time to replace their present vehicle. Conversely, if they find that they would be inconvenienced by having to purchase hydrogen earlier than necessary or if they become worried that they would run out of fuel before encountering a facility, their motivation to purchase a hydrogen-powered vehicle decreases. At vehicle purchase time, they weigh this experience, as well as other factors such as social influence by their peers, fuel cost, and capital cost of a hydrogen vehicle. Investor agents build full-service hydrogen fueling stations (HFSs) at different locations along the highway network. They base their decision to build or not build a station on their (imperfect) estimates of the sales the station would immediately generate (based on hydrogen-powered vehicle traffic past the location and other factors), as well as the growth in hydrogen sales they could expect throughout their investment horizon. The interaction between driver and investor agents provides the basis for growth in both the number of hydrogen vehicles and number of hydrogen stations. For the present report, we have added to this mix smaller, 'bare-bones' hydrogen dispensing facilities (HDFs) of the type that owners of CHHP facilities could provide to the public. The locations of these stations were chosen to match existing facilities that might reasonably incorporate CHHP plants in the future. Unlike the larger commercial stations, these facilities are built according to exogenously supplied timetables, and no attempt has been made to model the financial basis for the facilities. Rather, our objective is to understand how the presence of these additional stations might facilitate the petroleum-to-hydrogen transition. We discuss a base case in which the HDFs are not present, and then investigate the effects of introducing HDFs in various numbers; according to different timetables; with various production capacities; and with hydrogen selling at prices above, equal to, and below the commercial stations selling price. We conclude that HDFs can indeed be helpful in accelerating a petroleum-to-hydrogen transition. Placed in areas where investors might not be willing to install large for-profit HFSs, HDFs can serve as a bridge until demand for hydrogen increases to the point where l

  16. U.S. Geographic Analysis of the Cost of Hydrogen from Electrolysis

    SciTech Connect (OSTI)

    Saur, G.; Ainscough, C.

    2011-12-01T23:59:59.000Z

    This report summarizes U.S. geographic analysis of the cost of hydrogen from electrolysis. Wind-based water electrolysis represents a viable path to renewably-produced hydrogen production. It might be used for hydrogen-based transportation fuels, energy storage to augment electricity grid services, or as a supplement for other industrial hydrogen uses. This analysis focuses on the levelized production, costs of producing green hydrogen, rather than market prices which would require more extensive knowledge of an hourly or daily hydrogen market. However, the costs of hydrogen presented here do include a small profit from an internal rate of return on the system. The cost of renewable wind-based hydrogen production is very sensitive to the cost of the wind electricity. Using differently priced grid electricity to supplement the system had only a small effect on the cost of hydrogen; because wind electricity was always used either directly or indirectly to fully generate the hydrogen. Wind classes 3-6 across the U.S. were examined and the costs of hydrogen ranged from $3.74kg to $5.86/kg. These costs do not quite meet the 2015 DOE targets for central or distributed hydrogen production ($3.10/kg and $3.70/kg, respectively), so more work is needed on reducing the cost of wind electricity and the electrolyzers. If the PTC and ITC are claimed, however, many of the sites will meet both targets. For a subset of distributed refueling stations where there is also inexpensive, open space nearby this could be an alternative to central hydrogen production and distribution.

  17. PROCESS ANALYSIS WORK FOR THE DOE HYDROGEN PROGRAM -2001

    E-Print Network [OSTI]

    . For the power production scenario, the hydrogen is co-fired in a turbine at a natural gas combined-cycle (NGCC) plant. 1 Proceedings of the 2002 U.S. DOE Hydrogen Program Review NREL/CP-610-32405 #12;Material of the reactor. The material and energy balances along with hourly solar data from Phoenix, Arizona were used

  18. Hydrogen Fueling Station in Honolulu, Hawaii Feasibility Analysis

    SciTech Connect (OSTI)

    Porter Hill; Michael Penev

    2014-08-01T23:59:59.000Z

    The Department of Energy Hydrogen & Fuel Cells Program Plan (September 2011) identifies the use of hydrogen for government and fleet electric vehicles as a key step for achieving reduced greenhouse gas emissions; reduced oil consumption; expanded use of renewable power ; highly efficient energy conversion; fuel flexibility ; reduced air pollution; and highly reliable grid-support. This report synthesizes several pieces of existing information that can inform a decision regarding the viability of deploying a hydrogen (H2) fueling station at the Fort Armstrong site in Honolulu, Hawaii.

  19. System Evaluation and Economic Analysis of a HTGR Powered High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego; Anastasia A. Gandrik

    2010-10-01T23:59:59.000Z

    A design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322C and 750C, respectively. The power conversion unit will be a Rankine steam cycle with a power conversion efficiency of 40%. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 40.4% at a hydrogen production rate of 1.75 kg/s and an oxygen production rate of 13.8 kg/s. An economic analysis of this plant was performed with realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.67/kg of hydrogen assuming an internal rate of return, IRR, of 12% and a debt to equity ratio of 80%/20%. A second analysis shows that if the power cycle efficiency increases to 44.4%, the hydrogen production efficiency increases to 42.8% and the hydrogen and oxygen production rates are 1.85 kg/s and 14.6 kg/s respectively. At the higher power cycle efficiency and an IRR of 12% the cost of hydrogen production is $3.50/kg.

  20. Thermal Hydraulic Analysis of HTGR Coupled with Hydrogen Plant

    SciTech Connect (OSTI)

    Chang Oh; Cliff Davis; Robert Barner; Paul Pickard

    2006-06-01T23:59:59.000Z

    The US Department of Energy is investigating the use of high-temperature gas-cooled reactors (HTGR) to produce electricity and hydrogen. Although the hydrogen production processes using the nuclear energy are in an early stage of development, coupling hydrogen plant to HTGR requires both efficient heat transfer and adequate separation of the facilities to assure that off-normal events in the production facility do not impact the nuclear plant. In anticipation of the design, development and procurement of an advanced power conversion system for HTGR, this study was initiated to identify the major design and technology options and their tradeoffs in the evaluation of power conversion system (PCS) coupled to hydrogen plant. In this study, we investigated a number of design configurations and performed thermal hydraulic analyses using various working fluids and various conditions. This paper includes a portion of thermal hydraulic results based on a direct cycle and a parallel intermediate heat exchanger (IHX) configuration option.

  1. Hydrogen Delivery Analysis Plus Meeting: DTT, STT, HPTT, Other...

    Broader source: Energy.gov (indexed) [DOE]

    Assumes 2005 delivery technologies * We can insert our Research Targets to see the impact Hydrogen Plants can be Located Relatively Near the Market demand Nearly all areas East of...

  2. Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM...

    Broader source: Energy.gov (indexed) [DOE]

    for 3 pathways with single mode. conditioning and storage are at or adjacent to Liquid Hydrogen (LH) Truck H2 Production 100 or 1500 kgd Compressed H2 (CH) Truck H2 Production...

  3. Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage

    SciTech Connect (OSTI)

    Steward, D.; Saur, G.; Penev, M.; Ramsden, T.

    2009-11-01T23:59:59.000Z

    This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage technologies: batteries, pumped hydro, and compressed air energy storage (CAES).

  4. Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage techno

  5. Participant List for the 2010-2025 Scenario Analysis for Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Participant List for the 2010-2025 Scenario Analysis for Hydrogen Fuel Cell Vehicles and Infrastructure Meeting on January 31, 2007 Participant List for the 2010-2025 Scenario...

  6. Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis

    E-Print Network [OSTI]

    Tomas Roubicek; Giuseppe Tomassetti

    2013-09-12T23:59:59.000Z

    A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

  7. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    Water High-pressure hydrogen compressor Compressed hydrogenWater High-pressure hydrogen compressor Compressed hydrogenReciprocating gas compressor Figure 13 Hydrogen refueling

  8. Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping...

    Broader source: Energy.gov (indexed) [DOE]

    Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22, 2002-July 22, 2002 Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22,...

  9. Technical Analysis of the Hydrogen Energy Station Concept, Phase I and Phase II

    SciTech Connect (OSTI)

    TIAX, LLC

    2005-05-04T23:59:59.000Z

    Phase I Due to the growing interest in establishing a domestic hydrogen infrastructure, several hydrogen fueling stations already have been established around the country as demonstration units. While these stations help build familiarity with hydrogen fuel in their respective communities, hydrogen vehicles are still several years from mass production. This limited number of hydrogen vehicles translates to a limited demand for hydrogen fuel, a significant hurdle for the near-term establishment of commercially viable hydrogen fueling stations. By incorporating a fuel cell and cogeneration system with a hydrogen fueling station, the resulting energy station can compensate for low hydrogen demand by providing both hydrogen dispensing and combined heat and power (CHP) generation. The electrical power generated by the energy station can be fed back into the power grid or a nearby facility, which in turn helps offset station costs. Hydrogen production capacity not used by vehicles can be used to support building heat and power loads. In this way, an energy station can experience greater station utility while more rapidly recovering capital costs, providing an increased market potential relative to a hydrogen fueling station. At an energy station, hydrogen is generated on-site. Part of the hydrogen is used for vehicle refueling and part of the hydrogen is consumed by a fuel cell. As the fuel cell generates electricity and sends it to the power grid, excess heat is reclaimed through a cogeneration system for use in a nearby facility. Both the electrical generation and heat reclamation serve to offset the cost of purchasing the equivalent amount of energy for nearby facilities and the energy station itself. This two-phase project assessed the costs and feasibility of developing a hydrogen vehicle fueling station in conjunction with electricity and cogenerative heat generation for nearby Federal buildings. In order to determine which system configurations and operational patterns would be most viable for an energy station, TIAX developed several criteria for selecting a representative set of technology configurations. TIAX applied these criteria to all possible technology configurations to determine an optimized set for further analysis, as shown in Table ES-1. This analysis also considered potential energy station operational scenarios and their impact upon hydrogen and power production. For example, an energy station with a 50-kWe reformer could generate enough hydrogen to serve up to 12 vehicles/day (at 5 kg/fill) or generate up to 1,200 kWh/day, as shown in Figure ES-1. Buildings that would be well suited for an energy station would utilize both the thermal and electrical output of the station. Optimizing the generation and utilization of thermal energy, hydrogen, and electricity requires a detailed look at the energy transfer within the energy station and the transfer between the station and nearby facilities. TIAX selected the Baseline configuration given in Table ES-1 for an initial analysis of the energy and mass transfer expected from an operating energy station. Phase II The purpose of this technical analysis was to analyze the development of a hydrogen-dispensing infrastructure for transportation applications through the installation of a 50-75 kW stationary fuel cell-based energy station at federal building sites. The various scenarios, costs, designs and impacts of such a station were quantified for a hypothetical cost-shared program that utilizes a natural gas reformer to provide hydrogen fuel for both the stack(s) and a limited number of fuel cell powered vehicles, with the possibility of using cogeneration to support the building heat load.

  10. A life cycle cost analysis framework for geologic storage of hydrogen : a scenario analysis.

    SciTech Connect (OSTI)

    Kobos, Peter Holmes; Lord, Anna Snider; Borns, David James

    2010-10-01T23:59:59.000Z

    The U.S. Department of Energy has an interest in large scale hydrogen geostorage, which would offer substantial buffer capacity to meet possible disruptions in supply. Geostorage options being considered are salt caverns, depleted oil/gas reservoirs, aquifers and potentially hard rock cavrns. DOE has an interest in assessing the geological, geomechanical and economic viability for these types of hydrogen storage options. This study has developed an ecocomic analysis methodology to address costs entailed in developing and operating an underground geologic storage facility. This year the tool was updated specifically to (1) a version that is fully arrayed such that all four types of geologic storage options can be assessed at the same time, (2) incorporate specific scenarios illustrating the model's capability, and (3) incorporate more accurate model input assumptions for the wells and storage site modules. Drawing from the knowledge gained in the underground large scale geostorage options for natural gas and petroleum in the U.S. and from the potential to store relatively large volumes of CO{sub 2} in geological formations, the hydrogen storage assessment modeling will continue to build on these strengths while maintaining modeling transparency such that other modeling efforts may draw from this project.

  11. Global Assessment of Hydrogen Technologies Tasks 3 & 4 Report Economic, Energy, and Environmental Analysis of Hydrogen Production and Delivery Options in Select Alabama Markets: Preliminary Case Studies

    SciTech Connect (OSTI)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Gillette, Jerry; Elgowainy, Amgad; Mintz, Marianne

    2007-12-01T23:59:59.000Z

    This report documents a set of case studies developed to estimate the cost of producing, storing, delivering, and dispensing hydrogen for light-duty vehicles for several scenarios involving metropolitan areas in Alabama. While the majority of the scenarios focused on centralized hydrogen production and pipeline delivery, alternative delivery modes were also examined. Although Alabama was used as the case study for this analysis, the results provide insights into the unique requirements for deploying hydrogen infrastructure in smaller urban and rural environments that lie outside the DOEs high priority hydrogen deployment regions. Hydrogen production costs were estimated for three technologies steam-methane reforming (SMR), coal gasification, and thermochemical water-splitting using advanced nuclear reactors. In all cases examined, SMR has the lowest production cost for the demands associated with metropolitan areas in Alabama. Although other production options may be less costly for larger hydrogen markets, these were not examined within the context of the case studies.

  12. H2A Delivery Components Model and Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-Tank

  13. Covalent features in the hydrogen bond of a water dimer: molecular orbital analysis

    E-Print Network [OSTI]

    Wang, Bo; Dai, Xing; Gao, Yang; Wang, Zhigang; Zhang, Rui-Qin

    2015-01-01T23:59:59.000Z

    The covalent-like characteristics of hydrogen bonds offer a new perspective on intermolecular interactions. Here, using density functional theory and post-Hartree-Fock methods, we reveal that there are two bonding molecular orbitals (MOs) crossing the O and H atoms of the hydrogen-bond in water dimer. Energy decomposition analysis also shows a non-negligible contribution of the induction term. These results illustrate the covalent-like character of the hydrogen bond between water molecules, which contributes to the essential understanding of ice, liquid water, related materials, and life sciences.

  14. Analysis of Improved Reference Design for a Nuclear-Driven High Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Edwin A. Harvego; James E. O'Brien; Michael G. McKellar

    2010-06-01T23:59:59.000Z

    The use of High Temperature Electrolysis (HTE) for the efficient production of hydrogen without the greenhouse gas emissions associated with conventional fossil-fuel hydrogen production techniques has been under investigation at the Idaho National Engineering Laboratory (INL) for the last several years. The activities at the INL have included the development, testing and analysis of large numbers of solid oxide electrolysis cells, and the analyses of potential plant designs for large scale production of hydrogen using an advanced Very-High Temperature Reactor (VHTR) to provide the process heat and electricity to drive the electrolysis process. The results of these system analyses, using the UniSim process analysis software, have shown that the HTE process, when coupled to a VHTR capable of operating at reactor outlet temperatures of 800 C to 950 C, has the potential to produce the large quantities of hydrogen needed to meet future energy and transportation needs with hydrogen production efficiencies in excess of 50%. In addition, economic analyses performed on the INL reference plant design, optimized to maximize the hydrogen production rate for a 600 MWt VHTR, have shown that a large nuclear-driven HTE hydrogen production plant can to be economically competitive with conventional hydrogen production processes, particularly when the penalties associated with greenhouse gas emissions are considered. The results of this research led to the selection in 2009 of HTE as the preferred concept in the U.S. Department of Energy (DOE) hydrogen technology down-selection process. However, the down-selection process, along with continued technical assessments at the INL, has resulted in a number of proposed modifications and refinements to improve the original INL reference HTE design. These modifications include changes in plant configuration, operating conditions and individual component designs. This paper describes the resulting new INL reference design and presents results of system analyses performed to optimize the design and to determine required plant performance and operating conditions.

  15. Lifecycle Analysis of Air Quality Impacts of Hydrogen and Gasoline Transportation Fuel Pathways

    E-Print Network [OSTI]

    Wang, Guihua

    2008-01-01T23:59:59.000Z

    SMR production with gaseous hydrogen pipeline delivery, andhydrogen: gaseous hydrogen pipeline vs. liquid hydrogenproduction with gaseous hydrogen pipeline delivery systems;

  16. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    H. Mooiewek, (2007) Hydrogen Infrastructure Fuelingfor Building an Early Hydrogen Infrastructure in Southernfacing early hydrogen infrastructure is cost. In this

  17. Hydrogen Fuel Cell Analysis: Lessons Learned from Stationary Power Generation Final Report

    SciTech Connect (OSTI)

    Scott E. Grasman; John W. Sheffield; Fatih Dogan; Sunggyu Lee; Umit O. Koylu; Angie Rolufs

    2010-04-30T23:59:59.000Z

    This study considered opportunities for hydrogen in stationary applications in order to make recommendations related to RD&D strategies that incorporate lessons learned and best practices from relevant national and international stationary power efforts, as well as cost and environmental modeling of pathways. The study analyzed the different strategies utilized in power generation systems and identified the different challenges and opportunities for producing and using hydrogen as an energy carrier. Specific objectives included both a synopsis/critical analysis of lessons learned from previous stationary power programs and recommendations for a strategy for hydrogen infrastructure deployment. This strategy incorporates all hydrogen pathways and a combination of distributed power generating stations, and provides an overview of stationary power markets, benefits of hydrogen-based stationary power systems, and competitive and technological challenges. The motivation for this project was to identify the lessons learned from prior stationary power programs, including the most significant obstacles, how these obstacles have been approached, outcomes of the programs, and how this information can be used by the Hydrogen, Fuel Cells & Infrastructure Technologies Program to meet program objectives primarily related to hydrogen pathway technologies (production, storage, and delivery) and implementation of fuel cell technologies for distributed stationary power. In addition, the lessons learned address environmental and safety concerns, including codes and standards, and education of key stakeholders.

  18. NREL: Dynamic Maps, GIS Data, and Analysis Tools - Hydrogen Maps

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency Visit | National Nuclear13Summer 2015GeothermalHydrogen

  19. Cost Analysis of Hydrogen Storage Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave theJuly 30, 2013Department of EnergyCoreHydrogen Storage

  20. NREL: Dynamic Maps, GIS Data, and Analysis Tools - Hydrogen Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Saleshttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gifNREL NRELChemicalIndustryIssuePhoto of threeHydrogen

  1. Hydrogen Demand and Resource Analysis (HyDRA) Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe SolarContamination Detector Workshop HydrogenScenario

  2. Hydrogen Storage Testing and Analysis Research and Development | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe SolarContaminationCurrent Technology » HydrogenHydrogenof

  3. Hydrogen Financial Analysis Scenario Tool (H2FAST)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogen and Fuel CellFew-Layer Graphene |Vehicles

  4. Hydrogen Storage Systems Analysis Meeting: Summary Report, March 29, 2005 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReview |Panel HydrogenM M a a r r

  5. Hydrogen Storage Systems Analysis Working Group Meeting: Summary Report |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReview |Panel HydrogenM M a a r

  6. Hydrogen Storage Systems Analysis Working Group Meeting: Summary Report |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReview |Panel HydrogenM M a a rDepartment

  7. Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReview |Panel HydrogenM M aDesign |

  8. Hydrogen Systems Analysis Workshop (SAW) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReview |Panel HydrogenM M

  9. Collaborative research on amine borane regeneration and market analysis of hydrogen storage materials.

    SciTech Connect (OSTI)

    David Schubert

    2010-12-06T23:59:59.000Z

    Amine borane (AB) is a very high capacity hydrogen storage material that meets DOE gravimetric and volumetric targets for on-board delivery of hydrogen for fuel cell vehicles (FCVs). This research helped make process toward the ultimate goal of practical generation of spent AB and added to the understanding of materials and processes required to utilize AB in practical applications. In addition, this work helped to enhance our fundamental understanding of the properties of boron materials now being pursued for new frustrated Lewis pair catalyst systems for activation of hydrogen and carbon dioxide, of interest for carbon capture and fuels production. This project included four primary areas of investigation: (1) synthesis of borate esters for use as amine borane regeneration intermediates, (2) spent ammonia borane fuel generation and analysis, (3) spent fuel digestion for production of borate esters, and (4) worldwide borate resource analysis. Significant progress was made in each of these areas during the two-year course of this project, which involved extensive collaborations with partners in the Center of Excellence for Chemical Hydrogen Storage, and particularly with partners at the Pacific Northwest National Laboratory. Results of the boron resource analysis studies indicate that sufficient boron reserves exist within the United States to meet forecast requirements for a U.S. fleet of hydrogen FCVs and sufficient resources are available worldwide for a global fleet of FCVs.

  10. Analysis of the Transition to Hydrogen Fuel Cell Vehicles and the Potential Hydrogen Energy Infrastructure Requirements, March 2008

    Fuel Cell Technologies Publication and Product Library (EERE)

    Achieving a successful transition to hydrogen-powered vehicles in the U.S. automotive market will require strong and sustained commitment by hydrogen producers, vehicle manufacturers, transporters and

  11. Hydrogen Storage Systems Analysis Working Group Meeting Held in Conjunction with the

    E-Print Network [OSTI]

    an autothermal hydrogen storage and delivery concept using an organic liquid carrier for hydrogen. Joe Reiter

  12. Entropy and complexity analysis of hydrogenic Rydberg atoms

    SciTech Connect (OSTI)

    Lopez-Rosa, S. [Instituto Carlos I de Fisica Teorica y Computacional, Universidad de Granada, 18071-Granada (Spain) [Instituto Carlos I de Fisica Teorica y Computacional, Universidad de Granada, 18071-Granada (Spain); Departamento de Fisica Aplicada II, Universidad de Sevilla, 41012-Sevilla (Spain); Toranzo, I. V.; Dehesa, J. S. [Instituto Carlos I de Fisica Teorica y Computacional, Universidad de Granada, 18071-Granada (Spain) [Instituto Carlos I de Fisica Teorica y Computacional, Universidad de Granada, 18071-Granada (Spain); Departamento de Fisica Atomica, Molecular y Nuclear, Universidad de Granada, 18071-Granada (Spain); Sanchez-Moreno, P. [Instituto Carlos I de Fisica Teorica y Computacional, Universidad de Granada, 18071-Granada (Spain) [Instituto Carlos I de Fisica Teorica y Computacional, Universidad de Granada, 18071-Granada (Spain); Departamento de Matematica Aplicada, Universidad de Granada, 18071-Granada (Spain)

    2013-05-15T23:59:59.000Z

    The internal disorder of hydrogenic Rydberg atoms as contained in their position and momentum probability densities is examined by means of the following information-theoretic spreading quantities: the radial and logarithmic expectation values, the Shannon entropy, and the Fisher information. As well, the complexity measures of Cramer-Rao, Fisher-Shannon, and Lopez Ruiz-Mancini-Calvet types are investigated in both reciprocal spaces. The leading term of these quantities is rigorously calculated by use of the asymptotic properties of the concomitant entropic functionals of the Laguerre and Gegenbauer orthogonal polynomials which control the wavefunctions of the Rydberg states in both position and momentum spaces. The associated generalized Heisenberg-like, logarithmic and entropic uncertainty relations are also given. Finally, application to linear (l= 0), circular (l=n- 1), and quasicircular (l=n- 2) states is explicitly done.

  13. ANALYSIS OF A HIGH TEMPERATURE GAS-COOLED REACTOR POWERED HIGH TEMPERATURE ELECTROLYSIS HYDROGEN PLANT

    SciTech Connect (OSTI)

    M. G. McKellar; E. A. Harvego; A. M. Gandrik

    2010-11-01T23:59:59.000Z

    An updated reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322C and 750C, respectively. The reactor heat is used to produce heat and electric power to the HTE plant. A Rankine steam cycle with a power conversion efficiency of 44.4% was used to provide the electric power. The electrolysis unit used to produce hydrogen includes 1.1 million cells with a per-cell active area of 225 cm2. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 42.8% at a hydrogen production rate of 1.85 kg/s (66 million SCFD) and an oxygen production rate of 14.6 kg/s (33 million SCFD). An economic analysis of this plant was performed with realistic financial and cost estimating The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.03/kg of hydrogen was calculated assuming an internal rate of return of 10% and a debt to equity ratio of 80%/20% for a reactor cost of $2000/kWt and $2.41/kg of hydrogen for a reactor cost of $1400/kWt.

  14. Analysis of the Hydrogen Infrastructure Needed to Enable Commercial Introduction of Hydrogen-Fueled Vehicles: Preprint

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative FuelsSanta FeAuthorization|EnergyAnalysisHeatConference

  15. Hydrogen Storage Systems Analysis Working Group Meeting Argonne National Laboratory DC Offices

    E-Print Network [OSTI]

    at Savannah River National Laboratory (Don Anton and Bruce Hardy, SRNL) Based on the operating conditionsHydrogen Storage Systems Analysis Working Group Meeting Argonne National Laboratory DC Offices 955 by Romesh Kumar Argonne National Laboratory and Laura Verduzco Sentech, Inc. February 28, 2007 #12;SUMMARY

  16. Analysis of Heat Transfer in Metal Hydride Based Hydrogen Separation

    SciTech Connect (OSTI)

    Fleming, W.H. Jr.

    1999-10-20T23:59:59.000Z

    This thesis presents a transient heat transfer analysis to model the heat transfer in the Pd/k packed column, and the impact of adding metallic foam.

  17. Economic Analysis of Hydrogen Energy Station Concepts: Are "H 2E-Stations" a Key Link to a Hydrogen Fuel Cell Vehicle Infrastructure?

    E-Print Network [OSTI]

    Lipman, Timothy E.; Edwards, Jennifer L.; Kammen, Daniel M.

    2002-01-01T23:59:59.000Z

    Ideally a robust hydrogen infrastructure would rapidlya serviceable hydrogen infrastructure that is extensiveadding hydrogen dispensing infrastructure to a gasoline

  18. A comparative analysis of the cryo-compression and cryo-adsorption hydrogen storage methods

    SciTech Connect (OSTI)

    Petitpas, G [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Benard, P [Universite du Quebec a Trois-Rivieres (Canada); Klebanoff, L E [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Xiao, J [Universite du Quebec a Trois-Rivieres (Canada); Aceves, S M [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2014-07-01T23:59:59.000Z

    While conventional low-pressure LH? dewars have existed for decades, advanced methods of cryogenic hydrogen storage have recently been developed. These advanced methods are cryo-compression and cryo-adsorption hydrogen storage, which operate best in the temperature range 30100 K. We present a comparative analysis of both approaches for cryogenic hydrogen storage, examining how pressure and/or sorbent materials are used to effectively increase onboard H? density and dormancy. We start by reviewing some basic aspects of LH? properties and conventional means of storing it. From there we describe the cryo-compression and cryo-adsorption hydrogen storage methods, and then explore the relationship between them, clarifying the materials science and physics of the two approaches in trying to solve the same hydrogen storage task (~58 kg H?, typical of light duty vehicles). Assuming that the balance of plant and the available volume for the storage system in the vehicle are identical for both approaches, the comparison focuses on how the respective storage capacities, vessel weight and dormancy vary as a function of temperature, pressure and type of cryo-adsorption material (especially, powder MOF-5 and MIL-101). By performing a comparative analysis, we clarify the science of each approach individually, identify the regimes where the attributes of each can be maximized, elucidate the properties of these systems during refueling, and probe the possible benefits of a combined hybrid system with both cryo-adsorption and cryo-compression phenomena operating at the same time. In addition the relationships found between onboard H? capacity, pressure vessel and/or sorbent mass and dormancy as a function of rated pressure, type of sorbent material and fueling conditions are useful as general designing guidelines in future engineering efforts using these two hydrogen storage approaches.

  19. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    systems. Although hydrogen and fuel cell vehicles are notkg/day). Although hydrogen and fuel cell vehicles are notof the Transition to Hydrogen Fuel Cell Vehicles & the

  20. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    Pressure Relief Device (PRD) Liquid Hydrogen Storage TankCompressed hydrogen storage Ambient-air vaporizer Liquidreactor (PSA) Compressed hydrogen storage Feed water pump

  1. Detailed Analysis of Urban Station Siting for California Hydrogen Highway Network

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, Joan M

    2007-01-01T23:59:59.000Z

    of a Fossil Fuel-Based Hydrogen Infrastructure with Carbonexpensive, then a hydrogen infrastructure would be postponedto the future hydrogen infrastructure. People will refuel at

  2. Lifecycle Analysis of Air Quality Impacts of Hydrogen and Gasoline Transportation Fuel Pathways

    E-Print Network [OSTI]

    Wang, Guihua

    2008-01-01T23:59:59.000Z

    emissions factors and hydrogen infrastructure engineering/consumption of hydrogen infrastructure such as the hydrogenspatial layouts of hydrogen infrastructure were determined.

  3. A life cycle cost analysis framework for geologic storage of hydrogen : a user's tool.

    SciTech Connect (OSTI)

    Kobos, Peter Holmes; Lord, Anna Snider; Borns, David James; Klise, Geoffrey T.

    2011-09-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) has an interest in large scale hydrogen geostorage, which could offer substantial buffer capacity to meet possible disruptions in supply or changing seasonal demands. The geostorage site options being considered are salt caverns, depleted oil/gas reservoirs, aquifers and hard rock caverns. The DOE has an interest in assessing the geological, geomechanical and economic viability for these types of geologic hydrogen storage options. This study has developed an economic analysis methodology and subsequent spreadsheet analysis to address costs entailed in developing and operating an underground geologic storage facility. This year the tool was updated specifically to (1) incorporate more site-specific model input assumptions for the wells and storage site modules, (2) develop a version that matches the general format of the HDSAM model developed and maintained by Argonne National Laboratory, and (3) incorporate specific demand scenarios illustrating the model's capability. Four general types of underground storage were analyzed: salt caverns, depleted oil/gas reservoirs, aquifers, and hard rock caverns/other custom sites. Due to the substantial lessons learned from the geological storage of natural gas already employed, these options present a potentially sizable storage option. Understanding and including these various geologic storage types in the analysis physical and economic framework will help identify what geologic option would be best suited for the storage of hydrogen. It is important to note, however, that existing natural gas options may not translate to a hydrogen system where substantial engineering obstacles may be encountered. There are only three locations worldwide that currently store hydrogen underground and they are all in salt caverns. Two locations are in the U.S. (Texas), and are managed by ConocoPhillips and Praxair (Leighty, 2007). The third is in Teeside, U.K., managed by Sabic Petrochemicals (Crotogino et al., 2008; Panfilov et al., 2006). These existing H{sub 2} facilities are quite small by natural gas storage standards. The second stage of the analysis involved providing ANL with estimated geostorage costs of hydrogen within salt caverns for various market penetrations for four representative cities (Houston, Detroit, Pittsburgh and Los Angeles). Using these demand levels, the scale and cost of hydrogen storage necessary to meet 10%, 25% and 100% of vehicle summer demands was calculated.

  4. DOE Annual Progress Report: Water Needs and Constraints for Hydrogen Pathways

    SciTech Connect (OSTI)

    Simon, A; Daily, W

    2009-07-02T23:59:59.000Z

    Water is a critical feedstock in the production of hydrogen. In fact, water and many of the energy transformations upon which society depends are inextricably linked. Approximately 39% of freshwater withdrawals are used for cooling of power plants, and another 8% are used in industry and mining (including oil and gas extraction and refining). Major changes in the energy infrastructure (as envisioned in a transformation to a hydrogen economy) will necessarily result in changes to the water infrastructure. Depending on the manner in which a hydrogen economy evolves, these changes could be large or small, detrimental or benign. Water is used as a chemical feedstock for hydrogen production and as a coolant for the production process. Process and cooling water must meet minimum quality specifications (limits on mineral and organic contaminants) at both the inlet to the process and at the point of discharge. If these specifications are not met, then the water must be treated, which involves extra expenditure on equipment and energy. There are multiple options for water treatment and cooling systems, each of which has a different profile of equipment cost and operational requirements. The engineering decisions that are made when building out the hydrogen infrastructure will play an important role in the cost of producing hydrogen, and those decisions will be influenced by the regional and national policies that help to manage water resources. In order to evaluate the impacts of water on hydrogen production and of a hydrogen economy on water resources, this project takes a narrowly-scoped lifecycle analysis approach. We begin with a process model of hydrogen production and calculate the process water, cooling, electricity and energy feedstock demands. We expand beyond the production process itself by analyzing the details of the cooling system and water treatment system. At a regional scale, we also consider the water use associated with the electricity and fuel that feed hydrogen production and distribution. The narrow scope of the lifecycle analysis enables economic optimization at the plant level with respect to cooling and water treatment technologies. As water withdrawal and disposal costs increase, more expensive, but more water-efficient technologies become more attractive. Some of the benefits of these technologies are offset by their increased energy usage. We use the H2A hydrogen production model to determine the overall cost of hydrogen under a range of water cost and technology scenarios. At the regional level, we are planning on following the hydrogen roll-out scenarios envisioned by Greene and Leiby (2008) to determine the impact of hydrogen market penetration on various watersheds. The economics of various water technologies will eventually be incorporated into the temporal and geographic Macro System Model via a water module that automates the spreadsheet models described. At the time of this progress report, the major achievement for FY2009 has been the completion of the framework and analytical results of the economic optimization of water technology for hydrogen production. This accomplishment required the collection of cost and performance data for multiple cooling and water treatment technologies, as well as the integration of a water and energy balance model with the H2A framework. 22 (twenty-two) different combinations of production method (SMR, electrolysis), scale (centralized, forecourt), cooling (evaporative tower, dry) and water treatment (reverse osmosis, ion exchange) were evaluated. The following data were collected: water withdrawal, water discharge, electricity consumption, equipment footprint, equipment cost, installation cost, annual equipment and material costs and annual labor costs. These data, when consolidated, fit into a small number of input cells in H2A. Items such as capital cost end up as line-items for which there is space in the existing H2A spreadsheets. Items such as electricity use are added to the values that already exist in H2A. Table 1 lists eight potential technology combina

  5. An economic analysis of the production of hydrogen from wind-generated electricity for use in transport

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    in transport applications Paper published in : Energy Policy, vol. 39, n 5, May 2011, pp. 2957-2965 Authors P in the framework of the HyFrance 3 project concerns hydrogen for transport applications. Different technical-generation biofuels production which present contrasted hydrogen use characteristics. This analysis reveals

  6. Analysis of Reference Design for Nuclear-Assisted Hydrogen Production at 750C Reactor Outlet Temperature

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego

    2010-05-01T23:59:59.000Z

    The use of High Temperature Electrolysis (HTE) for the efficient production of hydrogen without the greenhouse gas emissions associated with conventional fossil-fuel hydrogen production techniques has been under investigation at the Idaho National Engineering Laboratory (INL) for the last several years. The activities at the INL have included the development, testing and analysis of large numbers of solid oxide electrolysis cells, and the analyses of potential plant designs for large scale production of hydrogen using a high-temperature gas-cooled reactor (HTGR) to provide the process heat and electricity to drive the electrolysis process. The results of this research led to the selection in 2009 of HTE as the preferred concept in the U.S. Department of Energy (DOE) hydrogen technology down-selection process. However, the down-selection process, along with continued technical assessments at the INL, has resulted in a number of proposed modifications and refinements to improve the original INL reference HTE design. These modifications include changes in plant configuration, operating conditions and individual component designs. This report describes the resulting new INL reference design coupled to two alternative HTGR power conversion systems, a Steam Rankine Cycle and a Combined Cycle (a Helium Brayton Cycle with a Steam Rankine Bottoming Cycle). Results of system analyses performed to optimize the design and to determine required plant performance and operating conditions when coupled to the two different power cycles are also presented. A 600 MWt high temperature gas reactor coupled with a Rankine steam power cycle at a thermal efficiency of 44.4% can produce 1.85 kg/s of hydrogen and 14.6 kg/s of oxygen. The same capacity reactor coupled with a combined cycle at a thermal efficiency of 42.5% can produce 1.78 kg/s of hydrogen and 14.0 kg/s of oxygen.

  7. Protein Arginine Methyltransferase Prmt5-Mep50 Methylates Histones H2A and H4 and the Histone Chaperone

    E-Print Network [OSTI]

    Chait, Brian T.

    that nucleoplasmin (Npm), an exceedingly abundant maternally deposited protein, is a potent substrate for Prmt5-Mep50 and is monomethylated and symmetrically dimethylated at Arg-187. Furthermore, Npm modulates Prmt5-Mep50 activity directed toward histones, consistent with a regulatory role for Npm in vivo. We show that H2A

  8. NREL: Hydrogen and Fuel Cells Research - Energy Analysis and Tools

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for Renewable Energy: Grid Integration NREL isData and ResourcesEnergy Analysis and Tools

  9. Fuel Cell Tri-Generation System Case Study using the H2A Stationary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Economics and Performance Analysis Tri-Generation Success Story: World's First Tri-Gen Energy Station-Fountain Valley Expanding the Use of Biogas with Fuel Cell Technologies...

  10. Evaluation of hydrogen pressure vessels using slow strain rate testing and fracture mechanics analysis

    SciTech Connect (OSTI)

    Murray, S.H. [National Aeronautics and Space Administration, Kennedy Space Center, FL (United States). Materials Science Div.; Desai, V.H. [Univ. of Central Florida, Orlando, FL (United States)

    1998-12-31T23:59:59.000Z

    A total of 108 seamless, forged pressure vessels, fabricated from ASTM A372 type IV (UNS K14508) and type V low alloy steel, are currently in 4,200 psi (29 MPa) gaseous hydrogen (GH{sub 2}) service at the Kennedy Space Center`s (KSC) Space Shuttle Launch Complex 39 (LC-39). The vessels were originally used in 6,000 psi (41 MPa) GH{sub 2} service during the Apollo program. NASA recently received a letter of warning from the manufacturer of the vessels stating that the subject vessels should be now be removed from GH{sub 2} service due to the fact that the ultimate tensile strength (UTS) of many of the vessels exceeds the maximum limit of 126 ksi (869 MPa) now imposed on A372 steel intended for GH{sub 2} service, and therefore are susceptible to hydrogen environment embrittlement. Due to the expense associated with vessel replacement, it was decided to determine by testing and analysis whether or not the vessels needed to be removed from GH{sub 2} service. Slow strain rate testing was performed under hydrogen charging conditions to determine the value of the threshold fracture toughness for sustained loading crack growth in GH{sub 2}, (K{sub H}) for the vessel material, this value was then used in a fracture mechanics safe-life analysis (a 20-year service life was modeled) that indicated the vessels are safe for continued use.

  11. Lifecycle Analysis of Air Quality Impacts of Hydrogen and Gasoline Transportation Fuel Pathways

    E-Print Network [OSTI]

    Wang, Guihua

    2008-01-01T23:59:59.000Z

    2004. Fuel economy of hydrogen fuel cell vehicles. JournalSwitching to a U.S. hydrogen fuel cell vehicle fleet: TheImproving Health with Hydrogen Fuel-Cell Vehicles. SCIENCE

  12. Technical Analysis of Projects Being Funded by the DOE Hydrogen Program

    SciTech Connect (OSTI)

    Edward G. Skolnik

    2006-02-10T23:59:59.000Z

    In July 2000, Energetics began a project in which we performed site-visit based technical analyses or evaluations on hydrogen R&D projects for the purpose of providing in-depth information on the status and accomplishments of these projects to the public, and especially to hydrogen stakeholders. Over a three year period, 32 site-visit analyses were performed. In addition two concepts gleaned from the site visits became subjects of in depth techno-economic analyses. Finally, Energetics produced a compilation document that contains each site-visit analysis that we have performed, starting in 1996 on other contracts through the end of Year One of the current project (July 2001). This included 21 projects evaluated on previous contracts, and 10 additional ones from Year One. Reports on projects visited in Years One and Two were included in their respective Annual Reports. The Year Two Report also includes the two In-depth Analyses and the Compilation document. Reports in Year three began an attempt to perform reviews more geared to hydrogen safety. This Final Report contains a summary of the overall project, all of the 32 site-visit analyses and the two In-depth Analyses.

  13. Hydrogen refueling station costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, Joan M; Jianxin, Ma

    2007-01-01T23:59:59.000Z

    exposure for hydrogen and fuel cell vehicle technologies.10 gasoline hybrids or 20 hydrogen fuel cell vehicles (eachwheels analysis of hydrogen based fuel-cell vehicle pathways

  14. Hydrogen Refueling Station Costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, J; Jianxin, Ma

    2006-01-01T23:59:59.000Z

    exposure for hydrogen and fuel cell vehicle technologies10 gasoline hybrids or 20 hydrogen fuel cell vehicles (eachwheels analysis of hydrogen based fuel-cell vehicle pathways

  15. Techno-Economic Analysis of Hydrogen Production by Gasification of Biomass

    E-Print Network [OSTI]

    the cost of the production of hydrogen from three candidate biomass feedstocks and identify the barriers

  16. Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy

    E-Print Network [OSTI]

    Lipman, Timothy; Brooks, Cameron

    2006-01-01T23:59:59.000Z

    Partnership Finalizes Hydrogen Energy Roadmap, World WideCommercialization Strategy for Hydrogen Energy Technologies,Economic Analysis of Hydrogen Energy Station Concepts: Are

  17. Life-Cycle Cost Analysis Highlights Hydrogen's Potential for Electrical Energy Storage (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-11-01T23:59:59.000Z

    This fact sheet describes NREL's accomplishments in analyzing life-cycle costs for hydrogen storage in comparison with other energy storage technologies. Work was performed by the Hydrogen Technologies and Systems Center.

  18. Characterization and High Throughput Analysis of Metal Hydrides for Hydrogen Storage

    E-Print Network [OSTI]

    Barcelo, Steven James

    2009-01-01T23:59:59.000Z

    Hydrides for Energy Storage. A.F. Andresen and A.J. Maeland,Metal Hydrides for Hydrogen Storage by Steven James BarceloMetal Hydrides for Hydrogen Storage by Steven James Barcelo

  19. Community Energy: Analysis of Hydrogen Distributed Energy Systems with Photovoltaics for Load Leveling and Vehicle Refueling

    SciTech Connect (OSTI)

    Steward, D.; Zuboy, J.

    2014-10-01T23:59:59.000Z

    Energy storage could complement PV electricity generation at the community level. Because PV generation is intermittent, strategies must be implemented to integrate it into the electricity system. Hydrogen and fuel cell technologies offer possible PV integration strategies, including the community-level approaches analyzed in this report: (1) using hydrogen production, storage, and reconversion to electricity to level PV generation and grid loads (reconversion scenario); (2) using hydrogen production and storage to capture peak PV generation and refuel hydrogen fuel cell electric vehicles (FCEVs) (hydrogen fueling scenario); and (3) a comparison scenario using a battery system to store electricity for EV nighttime charging (electric charging scenario).

  20. Polymers for hydrogen infrastructure and vehicle fuel systems : applications, properties, and gap analysis.

    SciTech Connect (OSTI)

    Barth, Rachel Reina; Simmons, Kevin L. [Pacific Northwest National Laboratory, Richland, WA; San Marchi, Christopher W.

    2013-10-01T23:59:59.000Z

    This document addresses polymer materials for use in hydrogen service. Section 1 summarizes the applications of polymers in hydrogen infrastructure and vehicle fuel systems and identifies polymers used in these applications. Section 2 reviews the properties of polymer materials exposed to hydrogen and/or high-pressure environments, using information obtained from published, peer-reviewed literature. The effect of high pressure on physical and mechanical properties of polymers is emphasized in this section along with a summary of hydrogen transport through polymers. Section 3 identifies areas in which fuller characterization is needed in order to assess material suitability for hydrogen service.

  1. Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants

    SciTech Connect (OSTI)

    Stephen Schey

    2009-07-01T23:59:59.000Z

    Cooperative Agreement DE-FC07-06ID14788 was executed between the U.S. Department of Energy, Electric Transportation Applications, and Idaho National Laboratory to investigate the economics of producing hydrogen by electrolysis using electricity generated by nuclear power. The work under this agreement is divided into the following four tasks: Task 1 Produce Data and Analyses Task 2 Economic Analysis of Large-Scale Alkaline Electrolysis Task 3 Commercial-Scale Hydrogen Production Task 4 Disseminate Data and Analyses. Reports exist on the prospect that utility companies may benefit from having the option to produce electricity or produce hydrogen, depending on market conditions for both. This study advances that discussion in the affirmative by providing data and suggesting further areas of study. While some reports have identified issues related to licensing hydrogen plants with nuclear plants, this study provides more specifics and could be a resource guide for further study and clarifications. At the same time, this report identifies other area of risks and uncertainties associated with hydrogen production on this scale. Suggestions for further study in some of these topics, including water availability, are included in the report. The goals and objectives of the original project description have been met. Lack of industry design for proton exchange membrane electrolysis hydrogen production facilities of this magnitude was a roadblock for a significant period. However, recent design breakthroughs have made costing this facility much more accurate. In fact, the new design information on proton exchange membrane electrolyzers scaled to the 1 kg of hydrogen per second electrolyzer reduced the model costs from $500 to $100 million. Task 1 was delayed when the original electrolyzer failed at the end of its economic life. However, additional valuable information was obtained when the new electrolyzer was installed. Products developed during this study include a process model and a N2H2 economic assessment model (both developed by the Idaho National Laboratory). Both models are described in this report. The N2H2 model closely tracked and provided similar results as the H2A model and was instrumental in assessing the effects of plant availability on price when operated in the shoulder mode for electrical pricing. Differences between the H2A and N2H2 model are included in this report.

  2. Multiphysics Thermal-Fluid Design Analysis of a Non-Nuclear Tester for Hot-Hydrogen Materials and Component Development

    SciTech Connect (OSTI)

    Wang, T.-S.; Foote, John; Litchford, Ron [NASA Marshall Space Flight Center, Huntsville, Alabama, 35812 (United States)

    2006-01-20T23:59:59.000Z

    The objective of this effort is to perform design analyses for a non-nuclear hot-hydrogen materials tester, as a first step towards developing efficient and accurate multiphysics, thermo-fluid computational methodology to predict environments for hypothetical solid-core, nuclear thermal engine thrust chamber design and analysis. The computational methodology is based on a multidimensional, finite-volume, turbulent, chemically reacting, thermally radiating, unstructured-grid, and pressure-based formulation. The multiphysics invoked in this study include hydrogen dissociation kinetics and thermodynamics, turbulent flow, convective, and thermal radiative heat transfers. The goals of the design analyses are to maintain maximum hot-hydrogen jet impingement energy and to minimize chamber wall heating. The results of analyses on three test fixture configurations and the rationale for final selection are presented. The interrogation of physics revealed that reactions of hydrogen dissociation and recombination are highly correlated with local temperature and are necessary for accurate prediction of the hot-hydrogen jet temperature.

  3. An analysis of quantum effects on the thermodynamic properties of cryogenic hydrogen using the path integral method

    SciTech Connect (OSTI)

    Nagashima, H., E-mail: nagashima@nanoint.ifs.tohoku.ac.jp [School of Engineering, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Tsuda, S. [Department of Mechanical Systems Engineering, Shinshu University, Nagano 380-8553 (Japan)] [Department of Mechanical Systems Engineering, Shinshu University, Nagano 380-8553 (Japan); Tsuboi, N. [Department of Mechanical and Control Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550 (Japan)] [Department of Mechanical and Control Engineering, Kyushu Institute of Technology, Kitakyushu 804-8550 (Japan); Koshi, M. [Graduate School of Environment and Information Science, Yokohama National University, Yokohama 240-8501 (Japan)] [Graduate School of Environment and Information Science, Yokohama National University, Yokohama 240-8501 (Japan); Hayashi, K. A. [Department of Mechanical Engineering, Aoyama Gakuin University, Sagamihara 229-8558 (Japan)] [Department of Mechanical Engineering, Aoyama Gakuin University, Sagamihara 229-8558 (Japan); Tokumasu, T. [Institute of Fluid Science, Tohoku University, Sendai 980-8577 (Japan)] [Institute of Fluid Science, Tohoku University, Sendai 980-8577 (Japan)

    2014-04-07T23:59:59.000Z

    In this paper, we describe the analysis of the thermodynamic properties of cryogenic hydrogen using classical molecular dynamics (MD) and path integral MD (PIMD) method to understand the effects of the quantum nature of hydrogen molecules. We performed constant NVE MD simulations across a wide densitytemperature region to establish an equation of state (EOS). Moreover, the quantum effect on the difference of molecular mechanism of pressurevolumetemperature relationship was addressed. The EOS was derived based on the classical mechanism idea only using the MD simulation results. Simulation results were compared with each MD method and experimental data. As a result, it was confirmed that although the EOS on the basis of classical MD cannot reproduce the experimental data of saturation property of hydrogen in the high-density region, the EOS on the basis of PIMD well reproduces those thermodynamic properties of hydrogen. Moreover, it was clarified that taking quantum effects into account makes the repulsion force larger and the potential well shallower. Because of this mechanism, the intermolecular interaction of hydrogen molecules diminishes and the virial pressure increases.

  4. Economic analysis of large-scale hydrogen storage for renewable utility applications.

    SciTech Connect (OSTI)

    Schoenung, Susan M.

    2011-08-01T23:59:59.000Z

    The work reported here supports the efforts of the Market Transformation element of the DOE Fuel Cell Technology Program. The portfolio includes hydrogen technologies, as well as fuel cell technologies. The objective of this work is to model the use of bulk hydrogen storage, integrated with intermittent renewable energy production of hydrogen via electrolysis, used to generate grid-quality electricity. In addition the work determines cost-effective scale and design characteristics and explores potential attractive business models.

  5. Behavioral Response to Hydrogen Fuel Cell Vehicles and Refueling: A Comparative Analysis of Short- and Long-Term Exposure

    E-Print Network [OSTI]

    Martin, Elliot; Shaheen, Susan; Lipman, Timothy; Lidicker, Jeffery

    2008-01-01T23:59:59.000Z

    on the attitude towards hydrogen fuel cell buses in the CUTEBEHAVIORAL RESPONSE TO HYDROGEN FUEL CELL VEHICLES ANDBEHAVIORAL RESPONSE TO HYDROGEN FUEL CELL VEHICLES AND

  6. Survey Results and Analysis of the Cost and Efficiency of Various Operating Hydrogen Fueling Stations

    SciTech Connect (OSTI)

    Cornish, John

    2011-03-05T23:59:59.000Z

    Existing Hydrogen Fueling Stations were surveyed to determine capital and operational costs. Recommendations for cost reduction in future stations and for research were developed.

  7. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    onsite SMRs. Hydrogen from 100% solar photovoltaic poweredphotovoltaic (PV) electricity. Oxygen exhaust stream 12 x 6,250-psi compressed hydrogenphotovoltaic (PV) electricity Alkaline Electrolyzer Reverse osmosis and deionizer water purification Oxygen exhaust stream 12 x 6,250-psi compressed hydrogen

  8. Mechanism for high hydrogen storage capacity on metal-coated carbon nanotubes: A first principle analysis

    SciTech Connect (OSTI)

    Lu, Jinlian; Xiao, Hong [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)] [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China); Cao, Juexian, E-mail: jxcao@xtu.edu.cn [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)] [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)

    2012-12-15T23:59:59.000Z

    The hydrogen adsorption and binding mechanism on metals (Ca, Sc, Ti and V) decorated single walled carbon nanotubes (SWCNTs) are investigated using first principle calculations. Our results show that those metals coated on SWCNTs can uptake over 8 wt% hydrogen molecules with binding energy range -0.2--0.6 eV, promising potential high density hydrogen storage material. The binding mechanism is originated from the electrostatic Coulomb attraction, which is induced by the electric field due to the charge transfer from metal 4s to 3d. Moreover, we found that the interaction between the H{sub 2}-H{sub 2} further lowers the binding energy. - Graphical abstract: Five hydrogen molecules bound to individual Ca decorated (8, 0) SWCNT : a potential hydrogen-storage material. Highlights: Black-Right-Pointing-Pointer Each transition metal atom can adsorb more than four hydrogen molecules. Black-Right-Pointing-Pointer The interation between metal and hydrogen molecule is electrostatic coulomb attraction. Black-Right-Pointing-Pointer The electric field is induced by the charge transfer from metal 4s to metal 3d. Black-Right-Pointing-Pointer The adsorbed hydrogen molecules which form supermolecule can further lower the binding energy.

  9. Technical Analysis: Integrating a Hydrogen Energy Station into a Federal Building

    E-Print Network [OSTI]

    heat losses from the stack, and possibly results in higher reliability. A convenient way of providing potentially lead to lower costs for hydrogen production because the equipment used for hydrogen generation, comply with safety requirements, and develop equipment that is suitable for commercial applications

  10. Hydrogen Refueling Station Costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, Joan M; Jianxin, Ma

    2006-01-01T23:59:59.000Z

    Well-to-wheels analysis of hydrogen based fuel-cell vehicleJP, et al. Distributed Hydrogen Fueling Systems Analysis,Year 2006 UCDITSRR0604 Hydrogen Refueling Station Costs

  11. Behavioral Response to Hydrogen Fuel Cell Vehicles and Refueling: A Comparative Analysis of Short- and Long-Term Exposure

    E-Print Network [OSTI]

    Martin, Elliot; Shaheen, Susan; Lipman, Timothy; Lidicker, Jeffery

    2008-01-01T23:59:59.000Z

    combustion engine transit bus demonstration and hydrogenHydrogen FCVs have some important differences from gasoline internal combustion engine (

  12. Manufacturing Cost Analysis of Novel Steel/Concrete Composite Vessel for Stationary Storage of High-Pressure Hydrogen

    SciTech Connect (OSTI)

    Feng, Zhili [ORNL; Zhang, Wei [ORNL; Wang, Jy-An John [ORNL; Ren, Fei [ORNL

    2012-09-01T23:59:59.000Z

    A novel, low-cost, high-pressure, steel/concrete composite vessel (SCCV) technology for stationary storage of compressed gaseous hydrogen (CGH2) is currently under development at Oak Ridge National Laboratory (ORNL) sponsored by DOE s Fuel Cell Technologies (FCT) Program. The SCCV technology uses commodity materials including structural steels and concretes for achieving cost, durability and safety requirements. In particular, the hydrogen embrittlement of high-strength low-alloy steels, a major safety and durability issue for current industry-standard pressure vessel technology, is mitigated through the use of a unique layered steel shell structure. This report presents the cost analysis results of the novel SCCV technology. A high-fidelity cost analysis tool is developed, based on a detailed, bottom-up approach which takes into account the material and labor costs involved in each of the vessel manufacturing steps. A thorough cost study is performed to understand the SCCV cost as a function of the key vessel design parameters, including hydrogen pressure, vessel dimensions, and load-carrying ratio. The major conclusions include: The SCCV technology can meet the technical/cost targets set forth by DOE s FCT Program for FY2015 and FY2020 for all three pressure levels (i.e., 160, 430 and 860 bar) relevant to the hydrogen production and delivery infrastructure. Further vessel cost reduction can benefit from the development of advanced vessel fabrication technologies such as the highly automated friction stir welding (FSW). The ORNL-patented multi-layer, multi-pass FSW can not only reduce the amount of labor needed for assembling and welding the layered steel vessel, but also make it possible to use even higher strength steels for further cost reductions and improvement of vessel structural integrity. It is noted the cost analysis results demonstrate the significant cost advantage attainable by the SCCV technology for different pressure levels when compared to the industry-standard pressure vessel technology. The real-world performance data of SCCV under actual operating conditions is imperative for this new technology to be adopted by the hydrogen industry for stationary storage of CGH2. Therefore, the key technology development effort in FY13 and subsequent years will be focused on the fabrication and testing of SCCV mock-ups. The static loading and fatigue data will be generated in rigorous testing of these mock-ups. Successful tests are crucial to enabling the near-term impact of the developed storage technology on the CGH2 storage market, a critical component of the hydrogen production and delivery infrastructure. In particular, the SCCV has high potential for widespread deployment in hydrogen fueling stations.

  13. DATA COLLECTION, QUALITY ASSURANCE, AND ANALYSIS PLAN FOR THE 2008/2009 HYDROGEN AND FUEL CELLS KNOWLEDGE AND OPINIONS SURVEYS

    SciTech Connect (OSTI)

    Schmoyer, Richard L [ORNL; Truett, Lorena Faith [ORNL; Diegel, Susan W [ORNL

    2008-09-01T23:59:59.000Z

    The 2008/2009 Knowledge and Opinions Survey, conducted for the Department of Energy's Hydrogen Program will measure the levels of awareness and understanding of hydrogen and fuel cell technologies within five target populations: (1) the general public, (2) students, (3) personnel in state and local governments, (4) potential end users of hydrogen fuel and fuel cell technologies in business and industry, and (5) safety and code officials. The ultimate goal of the surveys is a statistically valid, nationally based assessment. Distinct information collections are required for each of the target populations. Each instrument for assessing baseline knowledge is targeted to the corresponding population group. While many questions are identical across all populations, some questions are unique to each respondent group. The biggest data quality limitation of the hydrogen survey data (at least of the general public and student components) will be nonresponse bias. To ensure as high a response rate as possible, various measures will be taken to minimize nonresponse, including automated callbacks, cycling callbacks throughout the weekdays, and availability of Spanish speaking interviewers. Statistical adjustments (i.e., sampling weights) will also be used to account for nonresponse and noncoverage. The primary objective of the data analysis is to estimate the proportions of target population individuals who would respond to the questions in the various possible ways. Data analysis will incorporate necessary adjustments for the sampling design and sampling weights (i.e., probability sampling). Otherwise, however, the analysis will involve standard estimates of proportions of the interviewees responding in various ways to the questions. Sample-weight-adjusted contingency table chi-square tests will also be computed to identify differences between demographic groups The first round of Knowledge and Opinions Surveys was conducted in 2004. Analysis of these surveys produced a baseline assessment of technical knowledge about hydrogen and fuel cells and a statistically valid description of opinions about safety and potential usage in the United States. The current surveys will repeat the process used in 2004. In addition the 2008/2009 survey results will be compared with the 2004 baseline results to assess changes in knowledge levels and opinions. In 2011/2012, the surveys will be repeated, and changes in knowledge and opinions will again be assessed. The information gained from these surveys will be used to enhance and update the DOE Hydrogen Program's education efforts.

  14. Turn of the century refueling: A review of innovations in early gasoline refueling methods and analogies for hydrogen

    E-Print Network [OSTI]

    Melaina, Marc W

    2007-01-01T23:59:59.000Z

    survey: automotive hydrogen infrastructure. Fuel Cell Today.2003. Initiating hydrogen infrastructures: preliminary2005. Initiating hydrogen infrastructures: analysis of

  15. Metabolic flux analysis of the hydrogen production potential in Synechocystis sp. PCC6803

    E-Print Network [OSTI]

    Fernndez de Crdoba, Pedro

    ). At the present time, steam reforming of natural gas is the best established system to produce hydrogen replacement by renewable sources. Despite the fact that some biofuels, like biodiesel or ethanol have been

  16. Feasibility Analysis of Steam Reforming of Biodiesel by-product Glycerol to Make Hydrogen

    E-Print Network [OSTI]

    Joshi, Manoj

    2009-06-09T23:59:59.000Z

    68% of waste glycerol is converted into gaseous mixture. The excess glycerol is recycled back as a feedstock. Water gas shift (WGS) reaction, further convert carbon monoxide into hydrogen and carbon dioxide which is further subjected to separation...

  17. Analysis of NOx Formation in a Hydrogen-Fueled Gas Turbine Engine

    E-Print Network [OSTI]

    Samuelsen, GS; Therkelsen, P; Werts, T; McDonell, V

    2009-01-01T23:59:59.000Z

    Turbine Fuel J. Engr. Gas Turbines and Power, Vol. 127, pp,Test in a Small Gas Turbine, International Journal ofof Hydrogen in a Small Gas Turbine Combustor, International

  18. Analysis of the cyanobacterial hydrogen photoproduction process via model identification and process simulation

    E-Print Network [OSTI]

    Zhang, Dongda; Dechatiwongse, Pongsathorn; Del-Rio-Chanona, Ehecatl Antonio; Hellgardt, Klaus; Maitland, Geoffrey C.; Vassiliadis, Vassilios S.

    2015-02-02T23:59:59.000Z

    February 2015 Keywords: Biohydrogen Cyanobacteria Photoproduction Kinetic models Process simulation Bioreactor design a b s t r a c t Cyanothece sp. ATCC 51142 is considered a microorganism with the potential to generate sustainable hydrogen in the future... the direction of culture movement, the overall hydrogen production rate in a PFR may be lower than that in a CSTR. Finally, in this study fed-batch photoproduction processes are proposed containing only one photo- bioreactor based on the current simulation...

  19. Hydrogen Cryomagnetics

    E-Print Network [OSTI]

    Glowacki, B. A.; Hanely, E.; Nuttall, W. J.

    2014-01-01T23:59:59.000Z

    in our current approach. The liquefaction of hydrogen allows also for its use in transport applications for example BMW developed a car that utilises liquid hydrogen instead of compressed gas hydrogen making the use of cryogenic hydrogen even more... efficient. 11 Figure 13. Decentralised production of hydrogen pathways for Energy and Hydrogen Cryomagnetic solutions for a hospital environment. The shaded region in the figure represents the decentralised production of hydrogen using renewable...

  20. Scenario Development and Analysis of Hydrogen as a Large-Scale Energy Storage Medium (Presentation)

    SciTech Connect (OSTI)

    Steward, D. M.

    2009-06-10T23:59:59.000Z

    The conclusions from this report are: (1) hydrogen has several important advantages over competing technologies, including - very high storage energy density (170 kWh/m{sup 3} vs. 2.4 for CAES and 0.7 for pumped hydro) which allows for potential economic viability of above-ground storage and relatively low environmental impact in comparison with other technologies; and (2) the major disadvantage of hydrogen energy storage is cost but research and deployment of electrolyzers and fuel cells may reduce cost significantly.

  1. Batch methods for enriching trace impurities in hydrogen gas for their further analysis

    DOE Patents [OSTI]

    Ahmed, Shabbir; Lee, Sheldon H.D.; Kumar, Romesh; Papdias, Dionissios D.

    2014-07-15T23:59:59.000Z

    Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio P.sub.hi/P.sub.lo and the volume ratio V.sub.1/V.sub.2, with following detection of the impurities using commonly-available detection methods.

  2. Experimental determination of the distribution of tail states of hydrogenated amorphous silicon: A transient photocurrent analysis

    SciTech Connect (OSTI)

    Webb, D.P.; Chan, F.Y.M.; Zou, X.C.; Chan, Y.C.; Lam, Y.W.; Lin, S.H.; O'Leary, S.K.; Lim, P.K.

    1997-07-01T23:59:59.000Z

    Recent experimental developments have cast doubt on the validity of the common assumption that the distribution of tail states of hydrogenated amorphous silicon exhibits a single exponential functional form. The authors employ transient photocurrent decay measurements to determine this distribution of tail states. In their approach, however, they determine the distribution of tail states directly from the experimental data, without assuming, a priori, a specific functional form. It is found that these experimental results are consistent with other more recent experimental determinations of the distribution of tail states, suggesting the possibility of deviations from a single exponential distribution of tail states in hydrogenated amorphous silicon.

  3. Helioseismic analysis of the hydrogen partition function in the solar interior

    E-Print Network [OSTI]

    S. Basu; W. Dappen; A. Nayfonov

    1998-12-17T23:59:59.000Z

    The difference in the adiabatic gradient gamma_1 between inverted solar data and solar models is analyzed. To obtain deeper insight into the issues of plasma physics, the so-called ``intrinsic'' difference in gamma_1 is extracted, that is, the difference due to the change in the equation of state alone. Our method uses reference models based on two equations of state currently used in solar modeling, the Mihalas-Hummer-Dappen (MHD) equation of state, and the OPAL equation of state (developed at Livermore). Solar oscillation frequencies from the SOI/MDI instrument on board the SOHO spacecraft during its first 144 days in operation are used. Our results confirm the existence of a subtle effect of the excited states in hydrogen that was previously studied only theoretically (Nayfonov & Dappen 1998). The effect stems from internal partition function of hydrogen, as used in the MHD equation of state. Although it is a pure-hydrogen effect, it takes place in somewhat deeper layers of the Sun, where more than 90% of hydrogen is ionized, and where the second ionization zone of helium is located. Therefore, the effect will have to be taken into account in reliable helioseismic determinations of the astrophysically relevant helium-abundance of the solar convection zone.

  4. Analysis of Cost-Effective Off-Board Hydrogen Storage and Refueling Stations

    SciTech Connect (OSTI)

    Ted Barnes; William Liss

    2008-11-14T23:59:59.000Z

    This report highlights design and component selection considerations for compressed gas hydrogen fueling stations operating at 5000 psig or 350 bar. The primary focus is on options for compression and storage in terms of practical equipment options as well as various system configurations and how they influence delivery performance and station economics.

  5. Hydrogen Storage Systems Analysis Meeting 955 L'Enfant Plaza North, SW, Suite 6000

    E-Print Network [OSTI]

    , engineering, and optimization of reactors, including consideration of hybrid approaches, materials properties of a hybrid (elevated pressure, lowered temperature) activated carbon hydrogen storage system. Representatives, and thermal management; and life-cycle analyses, including energy balances, life-cycle costs, environmental

  6. Fuel-Cycle Analysis of Hydrogen-Powered Fuel-Cell Systems with the GREET Model

    E-Print Network [OSTI]

    and storage (CCS) Brazilian sugarcane ethanol Corn to butanol Soybeans to renewable diesel via hydrogenation Coal/biomass co-feeding for FT diesel production Various corn ethanol plant types with different and electric forklifts FC distributed power generation vs. conventional distributed power generation

  7. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review

    SciTech Connect (OSTI)

    Ruth, M.

    2011-10-01T23:59:59.000Z

    This independent review is the conclusion arrived at from data collection, document reviews, interviews and deliberation from December 2010 through April 2011 and the technical potential of Hydrogen Production Cost Estimate Using Biomass Gasification. The Panel reviewed the current H2A case (Version 2.12, Case 01D) for hydrogen production via biomass gasification and identified four principal components of hydrogen levelized cost: CapEx; feedstock costs; project financing structure; efficiency/hydrogen yield. The panel reexamined the assumptions around these components and arrived at new estimates and approaches that better reflect the current technology and business environments.

  8. Hydrogen sensor

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Cao, Wenqing (Katy, TX)

    2010-11-23T23:59:59.000Z

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  9. Lamb Shift in Muonic Hydrogen. II. Analysis of the Discrepancy of Theory and Experiment

    E-Print Network [OSTI]

    U. D. Jentschura

    2010-11-24T23:59:59.000Z

    Currently, both the g factor measurement of the muon as well as the Lamb shift 2S-2P measurement in muonic hydrogen are in disagreement with theory. Here, we investigate possible theoretical explanations, including proton structure effects and small modifications of the vacuum polarization potential. In particular, we investigate a conceivable small modification of the spectral function of vacuum polarization in between the electron and muon energy scales due to a virtual millicharged particle and due to an unstable vector boson originating from a hidden sector of an extended standard model. We find that a virtual millicharged particle which could explain the muonic Lamb shift discrepancy alters theoretical predictions for the muon anomalous magnetic moment by many standard deviations and therefore is in conflict with experiment. Also, we find no parameterizations of an unstable virtual vector boson which could simultaneously explain both "muonic" discrepancies without significantly altering theoretical predictions for electronic hydrogen, where theory and experiment currently are in excellent agreement. A process-dependent correction involving electron screening is evaluated to have the right sign and order-of-magnitude to explain the observed effect in muonic hydrogen. Additional experimental evidence from light muonic atoms and ions is needed in order to reach further clarification.

  10. NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)

    SciTech Connect (OSTI)

    Ramsden, T.; Harrison, K.; Steward, D.

    2009-11-16T23:59:59.000Z

    Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

  11. HyDIVE (Hydrogen Dynamic Infrastructure and Vehicle Evolution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HyDIVE (Hydrogen Dynamic Infrastructure and Vehicle Evolution) Model Analysis HyDIVE (Hydrogen Dynamic Infrastructure and Vehicle Evolution) Model Analysis Presentation by NREL's...

  12. Phase shift analysis of low energy pi+/- p scattering data and a comparison with pionic hydrogen data

    E-Print Network [OSTI]

    A. Gashi; E. Matsinos; G. C. Oades; G. Rasche; W. S. Woolcock

    2007-10-18T23:59:59.000Z

    Using newly calculated electromagnetic corrections, we have made a phase shift analysis of experimental data on pi+/- p elastic scattering up to 100 MeV, assuming the effective hadronic interaction to be isospin invariant. The output consists of parametrised s and p-wave hadronic phases for isospin 1/2 and 3/2. It is not possible to fit the charge exchange data satisfactorily. We give values for the s-wave scattering lengths and effective ranges and for the p-wave scattering volumes. The combinations 2a_1 + a_3 and a_1 - a_3 of s-wave scattering lengths extracted from pionic hydrogen data are compared with those obtained from our analysis.

  13. HIGH-TEMPERATURE ELECTROLYSIS FOR LARGE-SCALE HYDROGEN AND SYNGAS PRODUCTION FROM NUCLEAR ENERGY SYSTEM SIMULATION AND ECONOMICS

    SciTech Connect (OSTI)

    J. E. O'Brien; M. G. McKellar; E. A. Harvego; C. M. Stoots

    2009-05-01T23:59:59.000Z

    A research and development program is under way at the Idaho National Laboratory (INL) to assess the technological and scale-up issues associated with the implementation of solid-oxide electrolysis cell technology for efficient high-temperature hydrogen production from steam. This work is supported by the US Department of Energy, Office of Nuclear Energy, under the Nuclear Hydrogen Initiative. This paper will provide an overview of large-scale system modeling results and economic analyses that have been completed to date. System analysis results have been obtained using the commercial code UniSim, augmented with a custom high-temperature electrolyzer module. Economic analysis results were based on the DOE H2A analysis methodology. The process flow diagrams for the system simulations include an advanced nuclear reactor as a source of high-temperature process heat, a power cycle and a coupled steam electrolysis loop. Several reactor types and power cycles have been considered, over a range of reactor outlet temperatures. Pure steam electrolysis for hydrogen production as well as coelectrolysis for syngas production from steam/carbon dioxide mixtures have both been considered. In addition, the feasibility of coupling the high-temperature electrolysis process to biomass and coal-based synthetic fuels production has been considered. These simulations demonstrate that the addition of supplementary nuclear hydrogen to synthetic fuels production from any carbon source minimizes emissions of carbon dioxide during the production process.

  14. Cost Analysis of Fuel Cell Systems for Transportation Compressed Hydrogen and PEM Fuel Cell System

    SciTech Connect (OSTI)

    Eric J. Carlson

    2004-10-20T23:59:59.000Z

    PEMFC technology for transportation must be competitive with internal combustion engine powertrains in a number of key metrics, including performance, life, reliability, and cost. Demonstration of PEMFC cost competitiveness has its own challenges because the technology has not been applied to high volume automotive markets. The key stack materials including membranes, electrodes, bipolar plates, and gas diffusion layers have not been produced in automotive volumes to the exacting quality requirements that will be needed for high stack yields and to the evolving property specifications of high performance automotive stacks. Additionally, balance-of-plant components for air, water, and thermal management are being developed to meet the unique requirements of fuel cell systems. To address the question of whether fuel cells will be cost competitive in automotive markets, the DOE has funded this project to assess the high volume production cost of PEM fuel cell systems. In this report a historical perspective of our efforts in assessment of PEMFC cost for DOE is provided along with a more in-depth assessment of the cost of compressed hydrogen storage is provided. Additionally, the hydrogen storage costs were incorporated into a system cost update for 2004. Assessment of cost involves understanding not only material and production costs, but also critical performance metrics, i.e., stack power density and associated catalyst loadings that scale the system components. We will discuss the factors influencing the selection of the system specification (i.e., efficiency, reformate versus direct hydrogen, and power output) and how these have evolved over time. The reported costs reflect internal estimates and feedback from component developers and the car companies. Uncertainty in the cost projection was addressed through sensitivity analyses.

  15. System Evaluations and Life-Cycle Cost Analyses for High-Temperature Electrolysis Hydrogen Production Facilities

    SciTech Connect (OSTI)

    Edwin A. Harvego; James E. O'Brien; Michael G. McKellar

    2012-05-01T23:59:59.000Z

    This report presents results of system evaluations and lifecycle cost analyses performed for several different commercial-scale high-temperature electrolysis (HTE) hydrogen production concepts. The concepts presented in this report rely on grid electricity and non-nuclear high-temperature process heat sources for the required energy inputs. The HYSYS process analysis software was used to evaluate both central plant designs for large-scale hydrogen production (50,000 kg/day or larger) and forecourt plant designs for distributed production and delivery at about 1,500 kg/day. The HYSYS software inherently ensures mass and energy balances across all components and it includes thermodynamic data for all chemical species. The optimized designs described in this report are based on analyses of process flow diagrams that included realistic representations of fluid conditions and component efficiencies and operating parameters for each of the HTE hydrogen production configurations analyzed. As with previous HTE system analyses performed at the INL, a custom electrolyzer model was incorporated into the overall process flow sheet. This electrolyzer model allows for the determination of the average Nernst potential, cell operating voltage, gas outlet temperatures, and electrolyzer efficiency for any specified inlet steam, hydrogen, and sweep-gas flow rates, current density, cell active area, and external heat loss or gain. The lifecycle cost analyses were performed using the H2A analysis methodology developed by the Department of Energy (DOE) Hydrogen Program. This methodology utilizes spreadsheet analysis tools that require detailed plant performance information (obtained from HYSYS), along with financial and cost information to calculate lifecycle costs. There are standard default sets of assumptions that the methodology uses to ensure consistency when comparing the cost of different production or plant design options. However, these assumptions may also be varied within the spreadsheets when better information is available or to allow the performance of sensitivity studies. The selected reference plant design for this study was a 1500 kg/day forecourt hydrogen production plant operating in the thermal-neutral mode. The plant utilized industrial natural gas-fired heaters to provide process heat, and grid electricity to supply power to the electrolyzer modules and system components. Modifications to the reference design included replacing the gas-fired heaters with electric resistance heaters, changing the operating mode of the electrolyzer (to operate below the thermal-neutral voltage), and considering a larger 50,000 kg/day central hydrogen production plant design. Total H2A-calculated hydrogen production costs for the reference 1,500 kg/day forecourt hydrogen production plant were $3.42/kg. The all-electric plant design using electric resistance heaters for process heat, and the reference design operating below the thermal-neutral voltage had calculated lifecycle hydrogen productions costs of $3.55/kg and $5.29/kg, respectively. Because of its larger size and associated economies of scale, the 50,000 kg/day central hydrogen production plant was able to produce hydrogen at a cost of only $2.89/kg.

  16. Geographically Based Hydrogen Demand and Infrastructure Rollout...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rollout Scenario Analysis Geographically Based Hydrogen Demand and Infrastructure Rollout Scenario Analysis Presentation by Margo Melendez at the 2010-2025 Scenario Analysis for...

  17. Code for Hydrogen Hydrogen Pipeline

    E-Print Network [OSTI]

    #12;2 Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop Augusta, Georgia August development · Charge from BPTCS to B31 Standards Committee for Hydrogen Piping/Pipeline code development · B31.12 Status & Structure · Hydrogen Pipeline issues · Research Needs · Where Do We Go From Here? #12;4 Code

  18. Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  19. Hydrogen energy systems studies

    SciTech Connect (OSTI)

    Ogden, J.M.; Steinbugler, M.; Dennis, E. [Princeton Univ., NJ (United States)] [and others

    1995-09-01T23:59:59.000Z

    For several years, researchers at Princeton University`s Center for Energy and Environmental Studies have carried out technical and economic assessments of hydrogen energy systems. Initially, we focussed on the long term potential of renewable hydrogen. More recently we have explored how a transition to renewable hydrogen might begin. The goal of our current work is to identify promising strategies leading from near term hydrogen markets and technologies toward eventual large scale use of renewable hydrogen as an energy carrier. Our approach has been to assess the entire hydrogen energy system from production through end-use considering technical performance, economics, infrastructure and environmental issues. This work is part of the systems analysis activity of the DOE Hydrogen Program. In this paper we first summarize the results of three tasks which were completed during the past year under NREL Contract No. XR-11265-2: in Task 1, we carried out assessments of near term options for supplying hydrogen transportation fuel from natural gas; in Task 2, we assessed the feasibility of using the existing natural gas system with hydrogen and hydrogen blends; and in Task 3, we carried out a study of PEM fuel cells for residential cogeneration applications, a market which might have less stringent cost requirements than transportation. We then give preliminary results for two other tasks which are ongoing under DOE Contract No. DE-FG04-94AL85803: In Task 1 we are assessing the technical options for low cost small scale production of hydrogen from natural gas, considering (a) steam reforming, (b) partial oxidation and (c) autothermal reforming, and in Task 2 we are assessing potential markets for hydrogen in Southern California.

  20. An Integrated Hydrogen Vision for California

    E-Print Network [OSTI]

    2004-01-01T23:59:59.000Z

    Techno-economic Analysis of Different Options for the Production of Hydrogen from Sunlight, Wind, and Biomass,

  1. Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

  2. Hydrogen Safety

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

  3. Hydrogen Storage Workshop Argonne National Laboratory

    E-Print Network [OSTI]

    hydrogen, fuel cells, and distribution..." #12;1. Hydrogen Storage 2. Hydrogen Production 3. Fuel Cell Cost barriers Assist Suppliers Independent T&E Advanced Concepts Analysis & Modeling SUPPLIERS PEM fuel cell, Stationary Fuel Cells 5,440 5,500 7,500 2,000 (+36%) HYDROGEN RESEARCH Core Research and Development 14

  4. CH spectroscopy for carbon chemical erosion analysis in high density low temperature hydrogen plasma

    SciTech Connect (OSTI)

    Westerhout, J.; Rooij, G. J. van [FOM Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, P. O. Box 1207, 3430 BE Nieuwegein (Netherlands); Lopes Cardozo, N. J. [FOM Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, P. O. Box 1207, 3430 BE Nieuwegein (Netherlands); Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven (Netherlands); Rapp, J. [FOM Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, P. O. Box 1207, 3430 BE Nieuwegein (Netherlands); Institut fuer Energieforschung--Plasmaphysik, Forschungszentrum Juelich, Association EURATOM-FZJ, Trilateral Euregio Cluster, D-52425 Juelich (Germany)

    2009-10-12T23:59:59.000Z

    The CH A-X molecular band is measured upon seeding the hydrogen plasma in the linear plasma generator Pilot-PSI [electron temperature T{sub e}=0.1-2.5 eV and electron density n{sub e}=(0.5-5)x10{sup 20} m{sup -3}] with methane. Calculated inverse photon efficiencies for these conditions range from 3 up to >10{sup 6} due to a steeply decreasing electron excitation cross section. The experiments contradict the calculations and show a constant effective inverse photon efficiency of {approx}100 for T{sub e}<1 eV. The discrepancy is explained as the CH A level is populated through dissociative recombination of the molecular ions formed by charge exchange. Collisional de-excitation is observed for n{sub e}>5x10{sup 20} m{sup -3} and 0.1 eV

  5. FUNDAMENTAL ENVIRONMENTAL REACTIVITY TESTING AND ANALYSIS OF THE HYDROGEN STORAGE MATERIAL 2LIBH4 MGH2

    SciTech Connect (OSTI)

    James, C.; Anton, D.; Cortes-Concepcion, J.; Brinkman, K.; Gray, J.

    2012-01-10T23:59:59.000Z

    While the storage of hydrogen for portable and stationary applications is regarded as critical in bringing PEM fuel cells to commercial acceptance, little is known of the environmental exposure risks posed in utilizing condensed phase chemical storage options as in complex hydrides. It is thus important to understand the effect of environmental exposure of metal hydrides in the case of accident scenarios. Simulated tests were performed following the United Nations standards to test for flammability and water reactivity in air for a destabilized lithium borohydride and magnesium hydride system in a 2 to 1 molar ratio respectively. It was determined that the mixture acted similarly to the parent, lithium borohydride, but at slower rate of reaction seen in magnesium hydride. To quantify environmental exposure kinetics, isothermal calorimetry was utilized to measure the enthalpy of reaction as a function of exposure time to dry and humid air, and liquid water. The reaction with liquid water was found to increase the heat flow significantly during exposure compared to exposure in dry or humid air environments. Calorimetric results showed the maximum normalized heat flow the fully charged material was 6 mW/mg under liquid phase hydrolysis; and 14 mW/mg for the fully discharged material also occurring under liquid phase hydrolysis conditions.

  6. High Performance, Low Cost Hydrogen Generation from

    E-Print Network [OSTI]

    Alternate deposition techniques and engineered nanostructures Supplier qualification, near term cost Qualification · Task 7.0: H2A Model Cost Analysis ­ Input design parameters ­ Assess impact of changes #12% 5 Bipolar Plate Manufacturing Development 06/30/13 0% 6 Bipolar Plate Manufacturing Qualification 09

  7. Hydrogen Storage Technologies Hydrogen Delivery

    E-Print Network [OSTI]

    Hydrogen Storage Technologies Roadmap Hydrogen Delivery Technical Team Roadmap June 2013 #12;This). The Hydrogen Delivery Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose mission and clean advanced lightduty vehicles, as well as related energy infrastructure. For more information about

  8. Sandia National Laboratories: Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Materials & Components Compatibility Hydrogen Behavior Quantitative Risk Assessment Hydrogen Infrastructure Solar Thermochemical Hydrogen Production Market Transformation...

  9. Hydrogen Economy: Opportunities and Challenges *

    E-Print Network [OSTI]

    A hydrogen economy, the long-term goal of many nations, can potentially provide energy security, along with environmental and economic benefits. However, the transition from a conventional petroleum-based energy system to a hydrogen economy involves many uncertainties, such as the development of efficient fuel cell technologies, problems in hydrogen production and distribution infrastructure, and the response of petroleum markets. This study uses the U.S. MARKAL model to simulate the impacts of hydrogen technologies on the U.S. energy system and identify potential impediments to a successful transition. Preliminary findings identify potential market barriers facing the hydrogen economy, as well as opportunities in new R&D and product markets for bioproducts. Quantitative analysis also offers insights on policy options for promoting hydrogen technologies. The objective of this paper is to study the transition from a petroleum-based energy system to a hydrogen economy, and ascertain the consequent opportunities and

  10. A Continuous Solar Thermochemical Hydrogen Production Plant Design

    E-Print Network [OSTI]

    Luc, Wesley Wai

    Overview of Hydrogen and Fuel Cell Research." Energy, v.34,Quantum Boost, DOE Hydrogen and Fuel Cells Program: FY 2012Analysis. DOE Hydrogen and Fuel Cells Program, Web. 22

  11. DOE Hydrogen Program Overview

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Program A Prospectus for Biological H 2 Production The Hydrogen Economy The hydrogen economy pertains to a world fundamentally different from the one we now know. Hydrogen...

  12. Potential Carriers andPotential Carriers and Approaches for HydrogenApproaches for Hydrogen

    E-Print Network [OSTI]

    Refueling Type On-Board Storage Type Compressed Gaseous Hydrogen · Pipeline · Low-P Tube Trailer · HighPotential Carriers andPotential Carriers and Approaches for HydrogenApproaches for Hydrogen © 2007 TIAX LLC Hydrogen Delivery Analysis Meeting May 8-9, 2007 Columbia, Maryland Matthew Hooks Stefan

  13. Macro-System Model: A Federated Object Model for Cross-Cutting Analysis of Hydrogen Production, Delivery, Consumption and Associated Emissions; Preprint

    SciTech Connect (OSTI)

    Ruth, M.; Diakov, V.; Goldsby, M. E.; Sa, T. J.

    2010-12-01T23:59:59.000Z

    It is commonly accepted that the introduction of hydrogen as an energy carrier for light-duty vehicles involves concomitant technological development of infrastructure elements, such as production, delivery, and consumption, all associated with certain emission levels. To analyze these at a system level, the suite of corresponding models developed by the United States Department of Energy and involving several national laboratories is combined in one macro-system model (MSM). The macro-system model is being developed as a cross-cutting analysis tool that combines a set of hydrogen technology analysis models. Within the MSM, a federated simulation framework is used for consistent data transfer between the component models. The framework is built to suit cross-model as well as cross-platform data exchange and involves features of 'over-the-net' computation.

  14. An In-situ materials analysis particle probe (MAPP) diagnostic to study particle density control and hydrogenic fuel retention in NSTX

    SciTech Connect (OSTI)

    Allain, Jean Paul [University of Illinois at Urbana-Champaign] (ORCID:000000031348262X)

    2014-09-05T23:59:59.000Z

    A new materials analysis particle probe (MAPP) was designed, constructed and tested to develop understanding of particle control and hydrogenic fuel retention in lithium-based plasma-facing surfaces in NSTX. The novel feature of MAPP is an in-situ tool to probe the divertor NSTX floor during LLD and lithium-coating shots with subsequent transport to a post-exposure in-vacuo surface analysis chamber to measure D retention. In addition, the implications of a lithiated graphite-dominated plasma-surface environment in NSTX on LLD performance, operation and ultimately hydrogenic pumping and particle control capability are investigated in this proposal. MAPP will be an invaluable tool for erosion/redeposition simulation code validation.

  15. Demonstration and System Analysis of High Temperature Steam Electrolysis for Large-Scale Hydrogen Production Using SOFCs

    SciTech Connect (OSTI)

    Michael G. McKellar; James E. O'Brien; Carl M. Stoots; J. Stephen Herring

    2008-07-01T23:59:59.000Z

    At the Idaho National Engineering Laboratory, an integrated laboratory scale (ILS), 15 kW high-temperature electrolysis (HTE) facility has been developed under the U.S. Department of Energy Nuclear Hydrogen Initiative. Initial operation of this facility resulted in over 400 hours of operation with an average hydrogen production rate of approximately 0.9 Nm3/hr. The integrated laboratory scale facility is designed to address larger-scale issues such as thermal management (feed-stock heating, high-temperature gas handling), multiple-stack hot-zone design, multiple-stack electrical configurations, and other integral issues. Additionally, a reference process model of a commercial-scale high-temperature electrolysis plant for hydrogen production has been developed. The reference plant design is driven by a 600 megawatt thermal high-temperature helium-cooled reactor coupled to a direct Brayton power cycle. The electrolysis unit used to produce hydrogen consists of 4.01106 cells with a per-cell active area of 225 cm2. A nominal cell area-specific resistance, ASR, value of 0.4 Ohmcm2 with a current density of 0.25 A/cm2 was used, and isothermal boundary conditions were assumed. The overall system thermal-to-hydrogen production efficiency (based on the low heating value of the produced hydrogen) is 47.1% at a hydrogen production rate of 2.36 kg/s with the high-temperature helium-cooled reactor concept. This paper documents the initial operation of the ILS, with experimental details about heat-up, initial stack performance, as well as long-term operation and stack degradation. The paper will also present the optimized design for the reference nuclear-driven HTE hydrogen production plant which may be compared with other hydrogen production methods and power cycles to evaluate relative performance characteristics and plant economics.

  16. Molecular Hydrogen in Infrared Cirrus

    E-Print Network [OSTI]

    Kristen Gillmon; J. Michael Shull

    2005-07-25T23:59:59.000Z

    We combine data from our recent FUSE survey of interstellar molecular hydrogen absorption toward 50 high-latitude AGN with COBE-corrected IRAS 100 micron emission maps to study the correlation of infrared cirrus with H2. A plot of the H2 column density vs. IR cirrus intensity shows the same transition in molecular fraction, f_H2, as seen with total hydrogen column density, N_H. This transition is usually attributed to H2 self-shielding, and it suggests that many diffuse cirrus clouds contain H2 in significant fractions, f_H2 = 1-30%. These clouds cover approximately 50% of the northern sky at latitudes b > 30 degrees, at temperature-corrected 100 micron intensities D_100 > 1.5 MJy/sr. The sheetlike cirrus clouds, with hydrogen densities n_H > 30 cm^-3, may be compressed by dynamical processes at the disk-halo interface, and they are conducive to H2 formation on grain surfaces. Exploiting the correlation between N(H2) and 100 micron intensity, we estimate that cirrus clouds at b > 30 contain approximately 3000 M_sun in H2. Extrapolated over the inner Milky Way, the cirrus may contain 10^7 M_sun of H2 and 10^8 M_sun in total gas mass. If elevated to 100 pc, their gravitational potential energy is ~10^53 erg.

  17. Bridging the Gap Between Transportation and Stationary Power: Hydrogen Energy Stations and their Implications for the Transportation Sector

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Lipman, Timothy; Unnasch, Stephen

    2005-01-01T23:59:59.000Z

    Economic Analysis of Hydrogen Energy Station Concepts,E 2 Four Potential Types of Hydrogen Energy Stations VehicleOperational Toronto Hydrogen Energy Station Stationary PEMFC

  18. Hydrogen Fueling Systems and Infrastructure

    E-Print Network [OSTI]

    ;Projects Hydrogen Infrastructure Development Turnkey Commercial Hydrogen Fueling Station Autothermal

  19. High Performance, Low Cost Hydrogen Generation from Renewable Energy

    SciTech Connect (OSTI)

    Ayers, Katherine [Proton OnSite] [Proton OnSite; Dalton, Luke [Proton OnSite] [Proton OnSite; Roemer, Andy [Proton OnSite] [Proton OnSite; Carter, Blake [Proton OnSite] [Proton OnSite; Niedzwiecki, Mike [Proton OnSite] [Proton OnSite; Manco, Judith [Proton OnSite] [Proton OnSite; Anderson, Everett [Proton OnSite] [Proton OnSite; Capuano, Chris [Proton OnSite] [Proton OnSite; Wang, Chao-Yang [Penn State University] [Penn State University; Zhao, Wei [Penn State University] [Penn State University

    2014-02-05T23:59:59.000Z

    Renewable hydrogen from proton exchange membrane (PEM) electrolysis is gaining strong interest in Europe, especially in Germany where wind penetration is already at critical levels for grid stability. For this application as well as biogas conversion and vehicle fueling, megawatt (MW) scale electrolysis is required. Proton has established a technology roadmap to achieve the necessary cost reductions and manufacturing scale up to maintain U.S. competitiveness in these markets. This project represents a highly successful example of the potential for cost reduction in PEM electrolysis, and provides the initial stack design and manufacturing development for Protons MW scale product launch. The majority of the program focused on the bipolar assembly, from electrochemical modeling to subscale stack development through prototyping and manufacturing qualification for a large active area cell platform. Feasibility for an advanced membrane electrode assembly (MEA) with 50% reduction in catalyst loading was also demonstrated. Based on the progress in this program and other parallel efforts, H2A analysis shows the status of PEM electrolysis technology dropping below $3.50/kg production costs, exceeding the 2015 target.

  20. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  1. Reactions of Methylene Hydrogen

    E-Print Network [OSTI]

    Griffin, E. L.

    1912-05-15T23:59:59.000Z

    was orystallized out as a yellow solid from aloohol and then from ethyl aostate. Melting point 170C Analysis: Calculated for C17H14O2U s - 10.10$ Found I = 10.00$ SUMMARY 0 It was found that the methods given in the literature for the preparation... following* 1. Metallic sodium replaces either one, or both of the hydrogens, the latter being given off as a free gas. 2. Sodium hydroxide replaces the hydrogen by the metal, with a splitting off of water. 3. Sodium ethylate reacts, giving the metal 3...

  2. Bonding Structure of Phenylacetylene on Hydrogen-Terminated Si(111) and Si(100): Surface Photoelectron Spectroscopy Analysis and Ab Initio Calculations

    SciTech Connect (OSTI)

    M Kondo; T Mates; D Fischer; F Wudl; E Kramer

    2011-12-31T23:59:59.000Z

    Interfaces between phenylacetylene (PA) monolayers and two silicon surfaces, Si(111) and Si(100), are probed by X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, and the results are analyzed using ab initio molecular orbital calculations. The monolayer systems are prepared via the surface hydrosilylation reaction between PA and hydrogen-terminated silicon surfaces. The following spectral features are obtained for both of the PA-Si(111) and PA-Si(100) systems: a broad {pi}-{pi}* shakeup peak at 292 eV (XPS), a broad first ionization peak at 3.8 eV (UPS), and a low-energy C 1s {yields} {pi}* resonance peak at 284.3 eV (NEXAFS). These findings are ascribed to a styrene-like {pi}-conjugated molecular structure at the PA-Si interface by comparing the experimental data with theoretical analysis results. A conclusion is drawn that the vinyl group can keep its {pi}-conjugation character on the hydrogen-terminated Si(100) [H:Si(100)] surface composed of the dihydride (SiH{sub 2}) groups as well as on hydrogen-terminated Si(111) having the monohydride (SiH) group. The formation mechanism of the PA-Si(100) interface is investigated within cluster ab initio calculations, and the possible structure of the H:Si(100) surface is discussed based on available data.

  3. Hydrogen from Biomass for Urban Transportation

    SciTech Connect (OSTI)

    Boone, William

    2008-02-18T23:59:59.000Z

    The objective of this project was to develop a method, at the pilot scale, for the economical production of hydrogen from peanut shells. During the project period a pilot scale process, based on the bench scale process developed at NREL (National Renewable Energy Lab), was developed and successfully operated to produce hydrogen from peanut shells. The technoeconomic analysis of the process suggests that the production of hydrogen via this method is cost-competitive with conventional means of hydrogen production.

  4. Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2003 Progress Report I. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .I-1

    E-Print Network [OSTI]

    -Derived Hydrogen from a Thermally Ballasted Gasifier, Iowa State University. . . . II-73 5. Techno-Economic Analysis of Hydrogen Production by Gasification of Biomass, Gas Technology Institute-34 8. Hydrogen Technical Analysis: Evaluation of Metal Hydride Slurries, TIAX LLC

  5. Hydrogen program overview

    SciTech Connect (OSTI)

    Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

    1997-12-31T23:59:59.000Z

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  6. The Hype About Hydrogen

    E-Print Network [OSTI]

    Mirza, Umar Karim

    2006-01-01T23:59:59.000Z

    economy based on the hydrogen fuel cell, but this cannot beus to look toward hydrogen. Fuel cell basics, simplifiedthe path to fuel cell commercialization. Hydrogen production

  7. Hydrogen Technologies Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    The Hydrogen Technologies Group at the National Renewable Energy Laboratory advances the Hydrogen Technologies and Systems Center's mission by researching a variety of hydrogen technologies.

  8. National Renewable Energy Laboratory DOE Hydrogen, Fuel Cells, and Infrastructure

    E-Print Network [OSTI]

    National Renewable Energy Laboratory DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29, 2004 Washington, D.C. Margaret K. Mann Hydrogen Analysis to address the nation's energy and environmental goals. The NREL Hydrogen Analysis Group provides

  9. HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM

    E-Print Network [OSTI]

    HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM date November 23, 2004 Contract end date March 31, 2006 #12;Hydrogen Regional Infrastructure Program in Pennsylvania Hydrogen Regional Infrastructure Program in Pennsylvania Objectives Capture

  10. Proceedings of the 1992 DOE/NREL hydrogen program review

    SciTech Connect (OSTI)

    Rocheleau, R.E.; Gao, Q.H.; Miller, E. [Univ. of Hawaii, Honolulu, HI (United States). Hawaii Natural Energy Inst.

    1992-07-01T23:59:59.000Z

    These proceedings contain 18 papers presented at the meeting. While the majority of the papers (11) had to do with specific hydrogen production methods, other papers were related to hydrogen storage systems, evaluations of and systems analysis for a hydrogen economy, and environmental transport of hydrogen from a pipeline leak.

  11. Hydrogen Technology Validation

    Fuel Cell Technologies Publication and Product Library (EERE)

    This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

  12. Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrogen Vehicles and Fuels in China Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen Vehicles and Fuels in China Presentation given by Jinyang Zheng of...

  13. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bonded Arrays: The Power of Multiple Hydrogen Bonds. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. Abstract: Hydrogen bond interactions in small covalent model...

  14. Hydrogen permeability and Integrity of hydrogen transfer pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    permeability and Integrity of hydrogen transfer pipelines Hydrogen permeability and Integrity of hydrogen transfer pipelines Presentation by 03-Babu for the DOE Hydrogen Pipeline...

  15. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Environmental Management (EM)

    CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay...

  16. NREL Wind to Hydrogen Project: Renewable Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage &...

  17. Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...

    Broader source: Energy.gov (indexed) [DOE]

    Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  18. An Analysis of Methanol and Hydrogen Production via High-Temperature Electrolysis Using the Sodium Cooled Advanced Fast Reactor

    SciTech Connect (OSTI)

    Shannon M. Bragg-Sitton; Richard D. Boardman; Robert S. Cherry; Wesley R. Deason; Michael G. McKellar

    2014-03-01T23:59:59.000Z

    Integration of an advanced, sodium-cooled fast spectrum reactor into nuclear hybrid energy system (NHES) architectures is the focus of the present study. A techno-economic evaluation of several conceptual system designs was performed for the integration of a sodium-cooled Advanced Fast Reactor (AFR) with the electric grid in conjunction with wind-generated electricity. Cases in which excess thermal and electrical energy would be reapportioned within an integrated energy system to a chemical plant are presented. The process applications evaluated include hydrogen production via high temperature steam electrolysis and methanol production via steam methane reforming to produce carbon monoxide and hydrogen which feed a methanol synthesis reactor. Three power cycles were considered for integration with the AFR, including subcritical and supercritical Rankine cycles and a modified supercritical carbon dioxide modified Brayton cycle. The thermal efficiencies of all of the modeled power conversions units were greater than 40%. A thermal efficiency of 42% was adopted in economic studies because two of the cycles either performed at that level or could potentially do so (subcritical Rankine and S-CO2 Brayton). Each of the evaluated hybrid architectures would be technically feasible but would demonstrate a different internal rate of return (IRR) as a function of multiple parameters; all evaluated configurations showed a positive IRR. As expected, integration of an AFR with a chemical plant increases the IRR when must-take wind-generated electricity is added to the energy system. Additional dynamic system analyses are recommended to draw detailed conclusions on the feasibility and economic benefits associated with AFR-hybrid energy system operation.

  19. Hydrogen Delivery Mark Paster

    E-Print Network [OSTI]

    Liquids (e.g. ethanol etc.) ­ Truck: HP Gas & Liquid Hydrogen ­ Regional Pipelines ­ Breakthrough Hydrogen;Delivery Key Challenges · Pipelines ­ Retro-fitting existing NG pipeline for hydrogen ­ Utilizing existing NG pipeline for Hythane with cost effective hydrogen separation technology ­ New hydrogen pipeline

  20. A new hydrogen-bonding potential for the design of proteinRNA interactions predicts specific

    E-Print Network [OSTI]

    Baker, David

    A new hydrogen-bonding potential for the design of protein­RNA interactions predicts specific-dependent hydrogen-bonding potential based on the statistical analysis of hydrogen-bonding geometries of hydrogen-bonding atom pairs at protein­ nucleic acid interfaces. A scoring function based on the hydrogen

  1. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01T23:59:59.000Z

    Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would becost than both. Solar-hydrogen fuel- cell vehicles would be

  2. HYDROGEN IN GERMANIUM

    E-Print Network [OSTI]

    Haller, E.E.

    2011-01-01T23:59:59.000Z

    •^f-1? c^4--^ LBL-7996 HYDROGEN IN GERMANIUM E. E. HallerW-7405-ENG-48 LBL-7996 HYDROGEN IN GERMANIUM* E. E. Haller48. LBL-7996 Abstract Hydrogen is shown to form molecular

  3. President's Hydrogen Fuel Initiative

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Fuel Initiative Workshop on Manufacturing R&D for the Hydrogen Economy Washington, DC July 13, 2005 JoAnn Milliken DOE Hydrogen Program Planning U.S. Energy Dependence is...

  4. Workshop National Renewable Energy Laboratory DOE Hydrogen ProgramDOE Hydrogen Program

    E-Print Network [OSTI]

    1 Systems Analysis Workshop National Renewable Energy Laboratory DOE Hydrogen ProgramDOE Hydrogen Washington D.C. 28-29 Jul 04 Dale Gardner Systems Integration Operated for the U.S. Department of Energy by Midwest Research Institute Battelle #12;2 Systems Analysis Workshop Topics Meeting Goals Systems

  5. Sandia Hydrogen Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Combustion Research Sandia Hydrogen Combustion Research Sebastian A. Kaiser (PI) Sandia National Laboratories Christopher M. White University of New Hampshire Sponsor: DoE...

  6. Sandia National Laboratories: Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Solar Thermochemical Hydrogen Production On June 13, 2014, in SNL maintains the equipment, experts, and partnerships required to develop technology for solar...

  7. Hydrogen Permeation Barrier Coatings

    SciTech Connect (OSTI)

    Henager, Charles H.

    2008-01-01T23:59:59.000Z

    Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

  8. Hydrogen Program Overview

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to the DOE Hydrogen Program. It describes the program mission and answers the question: Why Hydrogen?

  9. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Sources Hydrogen Hydrogen September 30, 2014 Developed by Sandia National Laboratories and several industry partners, the fuel cell mobile light (H2LT) offers a cleaner, quieter...

  10. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    for clean energy technology manufacturers. March 28, 2014 Sales Tax Exemption for Hydrogen Generation Facilities In North Dakota, the sale of hydrogen used to power an internal...

  11. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately...

  12. Why Hydrogen? Hydrogen from Diverse Domestic Resources

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Pipelines * Nuclear Energy * Office of Science Extending Collaborations * Other Federal Agencies - DOT, EPA, Others * International Collaborations Hydrogen from Diverse...

  13. Global Assessment of Hydrogen Technologies - Executive Summary

    SciTech Connect (OSTI)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan, Andrew J.

    2007-12-01T23:59:59.000Z

    This project was a collaborative effort involving researchers from the University of Alabama at Birmingham (UAB) and Argonne National Laboratory (ANL), drawing on the experience and expertise of both research organizations. The goal of this study was to assess selected hydrogen technologies for potential application to transportation and power generation. Specifically, this study evaluated scenarios for deploying hydrogen technologies and infrastructure in the Southeast. One study objective was to identify the most promising near-term and long-term hydrogen vehicle technologies based on performance, efficiency, and emissions profiles and compare them to traditional vehicle technologies. Hydrogen vehicle propulsion may take many forms, ranging from hydrogen or hythane fueled internal combustion engines (ICEs) to fuel cells and fuel cell hybrid systems. This study attempted to developed performance and emissions profiles for each type (assuming a light duty truck platform) so that effective deployment strategies can be developed. A second study objective was to perform similar cost, efficiency, and emissions analysis related to hydrogen infrastructure deployment in the Southeast. There will be many alternative approaches for the deployment of hydrogen fueling infrastructure, ranging from distributed hydrogen production to centralized production, with a similar range of delivery options. This study attempted to assess the costs and potential emissions associated with each scenario. A third objective was to assess the feasibility of using hydrogen fuel cell technologies for stationary power generation and to identify the advantages and limits of different technologies. Specific attention was given to evaluating different fuel cell membrane types. A final objective was to promote the use and deployment of hydrogen technologies in the Southeast. This effort was to include establishing partnerships with industry as well promoting educational and outreach efforts to public service providers. To accomplish these goals and objectives a work plan was developed comprising 6 primary tasks: Task 1 - Technology Evaluation of Hydrogen Light-Duty Vehicles The PSAT powertrain simulation software was used to evaluate candidate hydrogen-fueled vehicle technologies for near-term and long-term deployment in the Southeastern U.S. Task 2 - Comparison of Performance and Emissions from Near-Term Hydrogen Fueled Light Duty Vehicles - An investigation was conducted into the emissions and efficiency of light-duty internal combustion engines fueled with hydrogen and compressed natural gas (CNG) blends. The different fuel blends used in this investigation were 0%, 15%, 30%, 50%, 80%, 95%, and ~100% hydrogen, the remainder being compressed natural gas. Task 3 - Economic and Energy Analysis of Hydrogen Production and Delivery Options - Expertise in engineering cost estimation, hydrogen production and delivery analysis, and transportation infrastructure systems was used to develop regional estimates of resource requirements and costs for the infrastructure needed to deliver hydrogen fuels to advanced-technology vehicles. Task 4 Emissions Analysis for Hydrogen Production and Delivery Options - The hydrogen production and delivery scenarios developed in Task 3 were expanded to include analysis of energy and greenhouse gas emissions associated with each specific case studies. Task 5 Use of Fuel Cell Technology in Power Generation - The purpose of this task was to assess the performance of different fuel cell types (specifically low-temperature and high temperature membranes) for use in stationary power generation. Task 6 Establishment of a Southeastern Hydrogen Consortium - The goal of this task was to establish a Southeastern Hydrogen Technology Consortium (SHTC) whose purpose would be to promote the deployment of hydrogen technologies and infrastructure in the Southeast.

  14. Gaseous Hydrogen Delivery Breakout - Strategic Directions for...

    Broader source: Energy.gov (indexed) [DOE]

    Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop...

  15. NATIONAL HYDROGEN ENERGY ROADMAP

    E-Print Network [OSTI]

    NATIONAL HYDROGEN ENERGY ROADMAP NATIONAL HYDROGEN ENERGY ROADMAP . . Toward a More Secure and Cleaner Energy Future for America Based on the results of the National Hydrogen Energy Roadmap Workshop to make it a reality. This Roadmap provides a framework that can make a hydrogen economy a reality

  16. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  17. PHOTOELECTROCHEMICAL SYSTEMS FOR HYDROGEN PRODUCTION

    E-Print Network [OSTI]

    to allow the overlap of the bandedges with the water redox potentials in the dark. Charge transfer analysis A photoelectrochemical (PEC) system combines the harvesting of solar energy with the electrolysis of water. When, the energy can be sufficient to split water into hydrogen and oxygen. Depending on the type of semiconductor

  18. Wind Electrolysis: Hydrogen Cost Optimization

    SciTech Connect (OSTI)

    Saur, G.; Ramsden, T.

    2011-05-01T23:59:59.000Z

    This report describes a hydrogen production cost analysis of a collection of optimized central wind based water electrolysis production facilities. The basic modeled wind electrolysis facility includes a number of low temperature electrolyzers and a co-located wind farm encompassing a number of 3MW wind turbines that provide electricity for the electrolyzer units.

  19. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films

    SciTech Connect (OSTI)

    Alvine, Kyle J.; Shutthanandan, V.; Bennett, Wendy D.; Bonham, Charles C.; Skorski, Daniel C.; Pitman, Stan G.; Dahl, Michael E.; Henager, Charles H.

    2010-12-02T23:59:59.000Z

    Abstract: Hydrogen is being considered as a next-generation clean burning fuel. However, hydrogen has well known materials issues, including blistering and embrittlement in metals. Piezoelectric materials are used as actuators in hydrogen fuel technology. We present studies of materials compatibility of piezoelectric films in a high pressure hydrogen environment. Absorption of high pressure hydrogen was studied with Elastic Recoil Detection Analysis (ERDA) and Rutherford Back Scattering (RBS) in lead zirconate titanate (PZT) and barium titanate (BTO) thin films. Hydrogen surface degradation in the form of blistering and Pb mixing was also observed.

  20. 2009 Annual Progress Report: DOE Hydrogen Program, November 2009 (Book)

    SciTech Connect (OSTI)

    Not Available

    2009-11-01T23:59:59.000Z

    This report summarizes the hydrogen and fuel cell R&D activities and accomplishments of the DOE Hydrogen Program for FY2009. It covers the program areas of hydrogen production and delivery; fuel cells; manufacturing; technology validation; safety, codes and standards; education; and systems analysis.

  1. Hydrogen: Adding Value and Flexibility to the Nuclear Power Industry

    SciTech Connect (OSTI)

    Lee, J.; Bhatt, V.; Friley, P.; Horak, W.; Reisman, A.

    2004-10-04T23:59:59.000Z

    The objective of this study was to assess potential synergies between the hydrogen economy and nuclear energy options. Specifically: to provide a market analysis of advanced nuclear energy options for hydrogen production in growing hydrogen demand; to conduct an impact evaluation of nuclear-based hydrogen production on the economics of the energy system, environmental emissions, and energy supply security; and to identify competing technologies & challenges to nuclear options.

  2. Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Permeability and Integrity of Hydrogen Delivery Pipelines Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Project Objectives: To gain basic understanding of...

  3. Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

  4. Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bus Evaluation: Report for the 2001 Hydrogen Program Review Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen Program Review This paper, presented at the 2001 DOE...

  5. DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...

    Broader source: Energy.gov (indexed) [DOE]

    5037: Hydrogen Storage Materials - 2004 vs. 2006 DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials - 2004 vs. 2006 This program record from the Department...

  6. Wind to Hydrogen in California: Case Study

    SciTech Connect (OSTI)

    Antonia, O.; Saur, G.

    2012-08-01T23:59:59.000Z

    This analysis presents a case study in California for a large scale, standalone wind electrolysis site. This is a techno-economic analysis of the 40,000 kg/day renewable production of hydrogen and subsequent delivery by truck to a fueling station in the Los Angeles area. This quantity of hydrogen represents about 1% vehicle market penetration for a city such as Los Angeles (assuming 0.62 kg/day/vehicle and 0.69 vehicles/person) [8]. A wind site near the Mojave Desert was selected for proximity to the LA area where hydrogen refueling stations are already built.

  7. Sandia National Laboratories: Portable Hydrogen Fuel-Cell Unit...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Green, Sustainable Power to Honolulu Port Portable Hydrogen Fuel-Cell Unit to Provide Green, Sustainable Power to Honolulu Port Solar Glare Hazard Analysis Tool Available for...

  8. Redirection of metabolism for hydrogen production

    SciTech Connect (OSTI)

    Harwood, Caroline S.

    2011-11-28T23:59:59.000Z

    This project is to develop and apply techniques in metabolic engineering to improve the biocatalytic potential of the bacterium Rhodopseudomonas palustris for nitrogenase-catalyzed hydrogen gas production. R. palustris, is an ideal platform to develop as a biocatalyst for hydrogen gas production because it is an extremely versatile microbe that produces copious amounts of hydrogen by drawing on abundant natural resources of sunlight and biomass. Anoxygenic photosynthetic bacteria, such as R. palustris, generate hydrogen and ammonia during a process known as biological nitrogen fixation. This reaction is catalyzed by the enzyme nitrogenase and normally consumes nitrogen gas, ATP and electrons. The applied use of nitrogenase for hydrogen production is attractive because hydrogen is an obligatory product of this enzyme and is formed as the only product when nitrogen gas is not supplied. Our challenge is to understand the systems biology of R. palustris sufficiently well to be able to engineer cells to produce hydrogen continuously, as fast as possible and with as high a conversion efficiency as possible of light and electron donating substrates. For many experiments we started with a strain of R. palustris that produces hydrogen constitutively under all growth conditions. We then identified metabolic pathways and enzymes important for removal of electrons from electron-donating organic compounds and for their delivery to nitrogenase in whole R. palustris cells. For this we developed and applied improved techniques in 13C metabolic flux analysis. We identified reactions that are important for generating electrons for nitrogenase and that are yield-limiting for hydrogen production. We then increased hydrogen production by blocking alternative electron-utilizing metabolic pathways by mutagenesis. In addition we found that use of non-growing cells as biocatalysts for hydrogen gas production is an attractive option, because cells divert all resources away from growth and to hydrogen. Also R. palustris cells remain viable in a non-growing state for long periods of time.

  9. Hydrogen energy systems studies

    SciTech Connect (OSTI)

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M. [Princeton Univ., NJ (United States)] [and others

    1996-10-01T23:59:59.000Z

    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  10. US DOE Hydrgoen Program- HyDRA (Hydrogen Demand and Resource...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    US DOE Hydrgoen Program- HyDRA (Hydrogen Demand and Resource Analysis Tool US DOE Hydrgoen Program- HyDRA (Hydrogen Demand and Resource Analysis Tool HYDRA Program hydrajoseck.pdf...

  11. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    will trump hydrogen and fuel cell vehicles. Advocates ofbenefits sooner than hydrogen and fuel cells ever could.emissions from a hydrogen fuel cell vehicle will be about

  12. Liquid Hydrogen Absorber for MICE

    E-Print Network [OSTI]

    Ishimoto, S.

    2010-01-01T23:59:59.000Z

    REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

  13. Hydrogen Bus Technology Validation Program

    E-Print Network [OSTI]

    Burke, Andy; McCaffrey, Zach; Miller, Marshall; Collier, Kirk; Mulligan, Neal

    2005-01-01T23:59:59.000Z

    and evaluate hydrogen enriched natural gas (HCNG) enginewas to demonstrate that hydrogen enriched natural gas (HCNG)characteristics of hydrogen enriched natural gas combustion,

  14. Hydrogen in semiconductors and insulators

    E-Print Network [OSTI]

    Van de Walle, Chris G.

    2007-01-01T23:59:59.000Z

    the electronic level of hydrogen (thick red bar) was notdescribing the behavior of hydrogen atoms as impuritiesenergy of interstitial hydrogen as a function of Fermi level

  15. Technology Validation of Fuel Cell Vehicles and Their Hydrogen Infrastructure (Presentation)

    SciTech Connect (OSTI)

    Sprik, S.; Kurtz, J.; Wipke, K.; Saur, G.; Ainscough, C.

    2013-10-22T23:59:59.000Z

    This presentation summarizes NREL's analysis and validation of fuel cell electric vehicles and hydrogen fueling infrastructure technologies.

  16. Renewable Hydrogen: Technology Review and Policy Recommendations for State-Level Sustainable Energy Futures

    E-Print Network [OSTI]

    Lipman, Timothy; Edwards, Jennifer Lynn; Brooks, Cameron

    2006-01-01T23:59:59.000Z

    Techno-economic Analysis of Different Options for the Production of Hydrogen from Sunlight, Wind, and Biomass,

  17. Hydrogen Delivery Technologies and Pipeline Transmission of Hydrogen

    E-Print Network [OSTI]

    Hydrogen Delivery Technologies and Systems Pipeline Transmission of Hydrogen Strategic Initiatives, and Infrastructure Technologies Program #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Design & Operation development) #12;Pipeline Transmission of Hydrogen --- 3 Copyright: Future H2 Infrastructure Wind Powered

  18. Gaseous Hydrogen Delivery Breakout- Strategic Directions for Hydrogen Delivery Workshop

    Broader source: Energy.gov [DOE]

    Targets, barriers and research and development priorities for gaseous delivery of hydrogen through hydrogen and natural gas pipelines.

  19. The market viability of nuclear hydrogen technologies.

    SciTech Connect (OSTI)

    Botterud, A.; Conzelmann, G.; Petri, M. C.; Yildiz, B.

    2007-04-06T23:59:59.000Z

    The Department of Energy Office of Nuclear Energy is supporting system studies to gain a better understanding of nuclear power's potential role in a hydrogen economy and what hydrogen production technologies show the most promise. This assessment includes identifying commercial hydrogen applications and their requirements, comparing the characteristics of nuclear hydrogen systems to those market requirements, evaluating nuclear hydrogen configuration options within a given market, and identifying the key drivers and thresholds for market viability of nuclear hydrogen options. One of the objectives of the current analysis phase is to determine how nuclear hydrogen technologies could evolve under a number of different futures. The outputs of our work will eventually be used in a larger hydrogen infrastructure and market analysis conducted for DOE-EE using a system-level market simulation tool now underway. This report expands on our previous work by moving beyond simple levelized cost calculations and looking at profitability, risk, and uncertainty from an investor's perspective. We analyze a number of technologies and quantify the value of certain technology and operating characteristics. Our model to assess the profitability of the above technologies is based on Real Options Theory and calculates the discounted profits from investing in each of the production facilities. We use Monte-Carlo simulations to represent the uncertainty in hydrogen and electricity prices. The model computes both the expected value and the distribution of discounted profits from a production plant. We also quantify the value of the option to switch between hydrogen and electricity production in order to maximize investor profits. Uncertainty in electricity and hydrogen prices can be represented with two different stochastic processes: Geometric Brownian Motion (GBM) and Mean Reversion (MR). Our analysis finds that the flexibility to switch between hydrogen and electricity leads to significantly different results in regards to the relative profitability of the different technologies and configurations. This is the case both with a deterministic and a stochastic analysis, as shown in the tables below. The flexibility in output products clearly adds substantial value to the HPE-ALWR and HTE-HTGR plants. In fact, under the GBM assumption for prices, the HTE-HTGR plant becomes more profitable than the SI-HTGR configuration, although SI-HTGR has a much lower levelized cost. For the HTE-HTGR plant it is also profitable to invest in additional electric turbine capacity (Case b) in order to fully utilize the heat from the nuclear reactor for electricity production when this is more profitable than producing hydrogen. The technologies are all at the research and development stage, so there are significant uncertainties regarding the technology cost and performance assumptions used in this analysis. As the technologies advance, the designers need to refine the cost and performance evaluation to provide a more reliable set of input for a more rigorous analysis. In addition, the durability of the catalytic activity of the materials at the hydrogen plant during repetitive price cycling is of prime importance concerning the flexibility of switching from hydrogen to electricity production. However, given the potential significant economic benefit that can be brought from cogeneration with the flexibility to quickly react to market signals, DOE should consider R&D efforts towards developing durable materials and processes that can enable this type of operation. Our future work will focus on analyzing a range of hydrogen production technologies associated with an extension of the financial analysis framework presented here. We are planning to address a variety of additional risks and options, such as the value of modular expansion in addition to the co-generation capability (i.e., a modular increase in the hydrogen production capacity of a plant in a given market with rising hydrogen demand), and contrast that with economies-of-scale of large-unit designs.

  20. Gaseous Hydrogen Delivery Breakout

    E-Print Network [OSTI]

    Gaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7 detection Pipeline Safety: odorants, flame visibility Compression: cost, reliability #12;Breakout Session goal of a realistic, multi-energy distribution network model Pipeline Technology Improved field

  1. Hydrogen transport membranes

    DOE Patents [OSTI]

    Mundschau, Michael V.

    2005-05-31T23:59:59.000Z

    Composite hydrogen transport membranes, which are used for extraction of hydrogen from gas mixtures are provided. Methods are described for supporting metals and metal alloys which have high hydrogen permeability, but which are either too thin to be self supporting, too weak to resist differential pressures across the membrane, or which become embrittled by hydrogen. Support materials are chosen to be lattice matched to the metals and metal alloys. Preferred metals with high permeability for hydrogen include vanadium, niobium, tantalum, zirconium, palladium, and alloys thereof. Hydrogen-permeable membranes include those in which the pores of a porous support matrix are blocked by hydrogen-permeable metals and metal alloys, those in which the pores of a porous metal matrix are blocked with materials which make the membrane impervious to gases other than hydrogen, and cermets fabricated by sintering powders of metals with powders of lattice-matched ceramic.

  2. Hydrogen Fuel Quality (Presentation)

    SciTech Connect (OSTI)

    Ohi, J.

    2007-05-17T23:59:59.000Z

    Jim Ohi of NREL's presentation on Hydrogen Fuel Quality at the 2007 DOE Hydrogen Program Annual Merit Review and Peer Evaluation on May 15-18, 2007 in Arlington, Virginia.

  3. Questions and Issues on Hydrogen Pipeline Transmission of Hydrogen

    E-Print Network [OSTI]

    Questions and Issues on Hydrogen Pipelines Pipeline Transmission of Hydrogen Doe Hydrogen Pipeline Working Group Meeting August 31, 2005 #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Air Liquide Transmission of Hydrogen --- 3 Copyright: #12;Pipeline Transmission of Hydrogen --- 4 Copyright: 3. Special

  4. Webinar: Hydrogen Refueling Protocols

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Hydrogen Refueling Protocols, originally presented on February 22, 2013.

  5. Hydrogen Technologies Safety Guide

    SciTech Connect (OSTI)

    Rivkin, C.; Burgess, R.; Buttner, W.

    2015-01-01T23:59:59.000Z

    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  6. Hydrogen exchange studies of protein structure Tanya M Raschke and Susan Marqusee*

    E-Print Network [OSTI]

    Raschke, Tanya M.

    80 Hydrogen exchange studies of protein structure Tanya M Raschke and Susan Marqusee* Hydrogen partially folded ensembles present at equilibrium. Analysis of hydrogen exchange mechanisms has revealed intrinsicexchangerate kobs observedexchangerate NH amide hydrogen AGHx free energy of the opening reaction Introduction

  7. Sensitive hydrogen leak detector

    DOE Patents [OSTI]

    Myneni, Ganapati Rao (Yorktown, VA)

    1999-01-01T23:59:59.000Z

    A sensitive hydrogen leak detector system using passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor.

  8. Hydrogen Delivery Liquefaction and Compression

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Liquefaction and Compression - Overview of commercial hydrogen liquefaction and compression and opportunities to improve efficiencies and reduce cost.

  9. Anti-Hydrogen Jonny Martinez

    E-Print Network [OSTI]

    Budker, Dmitry

    Anti-Hydrogen Jonny Martinez University of California, Berkeley #12;OUTLINE WHAT IS ANTI-HYDROGEN? HISTORY IMPORTANCE THEORY HOW TO MAKE ANTI-HYDROGEN OTHER ANTI-MATTER EXPERIMENTS CONCLUSION #12;WHAT IS ANTI-HYDROGEN? Anti-hydrogen is composed of a Positron(anti-electron) and anti-Proton. Anti-Hydrogen

  10. Partitioning of hydrogen in the vanadium-lithium-hydrogen system at elevated temperatures

    SciTech Connect (OSTI)

    Hull, A.B.; Chopra, O.K.; Loomis, B.A.; Smith, D.L.

    1988-09-01T23:59:59.000Z

    Equilibrium concentrations of hydrogen in vanadium-base alloys exposed to flowing lithium at temperatures from 350 to 550/degree/C in a forced-circulation loop were measured by residual gas analysis and the vacuum fusion method. Residual gas analysis and removal of material from the surface allowed a determination of the spatial hydrogen distribution in the alloys. These experimental results were compared with calculated thermodynamic distribution coefficients for hydrogen in the vanadium/lithium system. Small amounts of other solutes in the molten lithium and in the alloys affected the solubility, diffusivity, and resultant distribution of hydrogen. Thermodynamic calculations demonstrated the importance of major alloying elements to the partitioning of hydrogen. 12 refs., 5 figs., 2 tabs.

  11. Hydrogen separation process

    DOE Patents [OSTI]

    Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

    2011-05-24T23:59:59.000Z

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  12. Method for producing hydrogen

    SciTech Connect (OSTI)

    Preston, J.L.

    1980-02-26T23:59:59.000Z

    In a method for producing high quality hydrogen, the carbon monoxide level of a hydrogen stream which also contains hydrogen sulfide is shifted in a bed of iron oxide shift catalyst to a desired low level of carbon monoxide using less catalyst than the minimum amount of catalyst which would otherwise be required if there were no hydrogen sulfide in the gas stream. Under normal operating conditions the presence of even relatively small amounts of hydrogen sulfide can double the activity of the catalyst such that much less catalyst may be used to do the same job.

  13. Hydrogen Delivery Infrastructure Option Analysis

    E-Print Network [OSTI]

    , vehicles can still drive with gasoline/diesel derived from tar sand, oil shale, and coal derived liquids

  14. Hydrogen Technical Analysis: Energy Station

    E-Print Network [OSTI]

    , which represents approximately 50% of the energy supplied by the fuel. More efficient heat recovery approximately 50% of the energy supplied by the fuel. More efficient heat recovery systems and improved system with buildings and potential for cogeneration Analyze potential for heat recovery from fuel cell

  15. Hydrogen Production Infrastructure Options Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e

  16. HYDROGEN USAGE AND STORAGE

    E-Print Network [OSTI]

    It is thought that it will be useful to inform society and people who are interested in hydrogen energy. The study below has been prepared due to this aim can be accepted as an article to exchange of information between people working on this subject. This study has been presented to reader to be utilized as a technical note. Main Energy sources coal, petroleum and natural gas are the fossil fuels we use today. They are going to be exhausted since careless usage in last decades through out the world, and human being is going to face the lack of energy sources in the near future. On the other hand as the fossil fuels pollute the environment makes the hydrogen important for an alternative energy source against to the fossil fuels. Due to the slow progress in hydrogens production, storage and converting into electrical energy experience, extensive usage of Hydrogen can not find chance for applications in wide technological practices. Hydrogen storage stands on an important point in the development of Hydrogen energy Technologies. Hydrogen is volumetrically low energy concentration fuel. Hydrogen energy, to meet the energy quantity necessary for the nowadays technologies and to be accepted economically and physically against fossil fuels, Hydrogen storage technologies have to be developed in this manner. Today the most common method in hydrogen storage may be accepted as the high pressurized composite tanks. Hydrogen is stored as liquid or gaseous phases. Liquid hydrogen phase can be stored by using composite tanks under very high pressure conditions. High technology composite material products which are durable to high pressures, which should not be affected by hydrogen embrittlement and chemical conditions.[1

  17. Low-Cost Precursors to Novel Hydrogen Storage Materials

    SciTech Connect (OSTI)

    Suzanne W. Linehan; Arthur A. Chin; Nathan T. Allen; Robert Butterick; Nathan T. Kendall; I. Leo Klawiter; Francis J. Lipiecki; Dean M. Millar; David C. Molzahn; Samuel J. November; Puja Jain; Sara Nadeau; Scott Mancroni

    2010-12-31T23:59:59.000Z

    From 2005 to 2010, The Dow Chemical Company (formerly Rohm and Haas Company) was a member of the Department of Energy Center of Excellence on Chemical Hydrogen Storage, which conducted research to identify and develop chemical hydrogen storage materials having the potential to achieve DOE performance targets established for on-board vehicular application. In collaboration with Center co-leads Los Alamos National Laboratory (LANL) and Pacific Northwest National Laboratory (PNNL), and other Center partners, Dow's efforts were directed towards defining and evaluating novel chemistries for producing chemical hydrides and processes for spent fuel regeneration. In Phase 1 of this project, emphasis was placed on sodium borohydride (NaBH{sub 4}), long considered a strong candidate for hydrogen storage because of its high hydrogen storage capacity, well characterized hydrogen release chemistry, safety, and functionality. Various chemical pathways for regenerating NaBH{sub 4} from spent sodium borate solution were investigated, with the objective of meeting the 2010/2015 DOE targets of $2-3/gal gasoline equivalent at the pump ($2-3/kg H{sub 2}) for on-board hydrogen storage systems and an overall 60% energy efficiency. With the September 2007 No-Go decision for NaBH{sub 4} as an on-board hydrogen storage medium, focus was shifted to ammonia borane (AB) for on-board hydrogen storage and delivery. However, NaBH{sub 4} is a key building block to most boron-based fuels, and the ability to produce NaBH{sub 4} in an energy-efficient, cost-effective, and environmentally sound manner is critical to the viability of AB, as well as many leading materials under consideration by the Metal Hydride Center of Excellence. Therefore, in Phase 2, research continued towards identifying and developing a single low-cost NaBH4 synthetic route for cost-efficient AB first fill, and conducting baseline cost estimates for first fill and regenerated AB using a variety of synthetic routes. This project utilized an engineering-guided R&D approach, which involved the rapid down-selection of a large number of options (chemical pathways to NaBH{sub 4}) to a smaller, more manageable number. The research began by conducting an extensive review of the technical and patent literature to identify all possible options. The down-selection was based on evaluation of the options against a set of metrics, and to a large extent occurred before experimentation was initiated. Given the vast amount of literature and patents that has evolved over the years, this approach helped to focus efforts and resources on the options with the highest technical and commercial probability of success. Additionally, a detailed engineering analysis methodology was developed for conducting the cost and energy-efficiency calculations. The methodology utilized a number of inputs and tools (Aspen PEA{trademark}, FCHTool, and H2A). The down-selection of chemical pathways to NaBH{sub 4} identified three options that were subsequently pursued experimentally. Metal reduction of borate was investigated in Dow's laboratories, research on electrochemical routes to NaBH{sub 4} was conducted at Pennsylvania State University, and Idaho National Laboratory researchers examined various carbothermal routes for producing NaBH{sub 4} from borate. The electrochemical and carbothermal studies did not yield sufficiently positive results. However, NaBH{sub 4} was produced in high yields and purities by an aluminum-based metal reduction pathway. Solid-solid reactive milling, slurry milling, and solution-phase approaches to metal reduction were investigated, and while both reactive milling and solution-phase routes point to fully recyclable processes, the scale-up of reactive milling processes to produce NaBH{sub 4} is expected to be difficult. Alternatively, a low-cost solution-phase approach to NaBH{sub 4} has been identified that is based on conventional process unit operations and should be amenable to scale-up. Numerous advances in AB synthesis have been made in recent years to improve AB yields and purities

  18. Electrochemical Hydrogen Compressor

    SciTech Connect (OSTI)

    David P. Bloomfield; Brian S. MacKenzie

    2006-05-01T23:59:59.000Z

    The Electrochemical Hydrogen Compressor EHC was evaluated against DOE applications for compressing hydrogen at automobile filling stations, in future hydrogen pipelines and as a commercial replacement for conventional diaphragm hydrogen compressors. It was also evaluated as a modular replacement for the compressors used in petrochemical refineries. If the EHC can be made inexpensive, reliable and long lived then it can satisfy all these applications save pipelines where the requirements for platinum catalyst exceeds the annual world production. The research performed did not completely investigate Molybdenum as a hydrogen anode or cathode, it did show that photoetched 316 stainless steel is inadequate for an EHC. It also showed that: molybdenum bipolar plates, photochemical etching processes, and Gortex Teflon seals are too costly for a commercial EHC. The use of carbon paper in combination with a perforated thin metal electrode demonstrated adequate anode support strength, but is suspect in promoting galvanic corrosion. The nature of the corrosion mechanisms are not well understood, but locally high potentials within the unit cell package are probably involved. The program produced a design with an extraordinary high cell pitch, and a very low part count. This is one of the promising aspects of the redesigned EHC. The development and successful demonstration of the hydraulic cathode is also important. The problem of corrosion resistant metal bipolar plates is vital to the development of an inexpensive, commercial PEM fuel cell. Our research suggests that there is more to the corrosion process in fuel cells and electrochemical compressors than simple, steady state, galvanic stability. It is an important area for scientific investigation. The experiments and analysis conducted lead to several recommended future research directions. First, we need a better understanding of the corrosion mechanisms involved. The diagnosis of experimental cells with titration to determine the loss of membrane active sites is recommended. We suspect that the corrosion includes more than simple galvanic mechanisms. The mechanisms involved in this phenomenon are poorly understood. Shunt currents at hydraulic cathode ports were problematic, but are not difficult to cure. In addition to corrosion there is evidence of high component resistivity. This may be due to the deposition of organic compounds, which may be produced electrochemically on the surface of the metal support screens that contact carbon gas diffusion layers (GDLs) or catalyst supports. An investigation of possible electro-organic sythesis mechanisms with emphasis on oxalates formation is warranted. The contaminated cell parts can be placed in an oxidizing atmosphere at high temperature and the weight loss can be observed. This would reveal the existence of organic compounds. Investigation into the effects of conductivity enhancers such as carbon microlayers on supporting carbon paper is also needed. Corrosion solutions should be investigated such as surface passivation of 316 SS parts using nitric acid. Ultra thin silane/siloxane polymer coatings should be tried. These may be especially useful in conjunction with metal felt replacement of carbon paper. A simple cure for the very high, localized corrosion of the anode might be to diffusion bond the metal electrode support screen to bipolar plate. This will insure uniform resistance perpendicular to the plane of the cell and eliminate some of the dependence of the resistance on high stack compression. Alternative materials should be explored. Alternatives to carbon in the cell may be helpful in any context. In particular, alternatives to carbon paper GDLs such as metal felts and alternatives to carbon supports for Pt such as TiC and TiB2 might also be worthwhile and would be helpful to fuel cells as well. Some alternative to the metals we used in the cell, Mo and 316 SS, are potentially useful. These include Al/Mg/Si alloys. Corrosion resistant materials such as Nb and Mo might prove useful as cladding materials that can be hot stamp

  19. Solar hydrogen energy system. Annual report, 1995--1996

    SciTech Connect (OSTI)

    Veziroglu, T.N.

    1996-12-31T23:59:59.000Z

    The paper reports progress on three tasks. Task A, System comparison of hydrogen with other alternative fuels in terms of EPACT requirements, investigates the feasibility of several alternative fuels, namely, natural gas, methanol, ethanol, hydrogen and electricity, to replace 10% of gasoline by the year 2000. The analysis was divided into two parts: analysis of vehicle technologies and analysis of fuel production, storage and distribution. Task B, Photovoltaic hydrogen production, involves this fuel production method for the future. The process uses hybrid solar collectors to generate dc electricity, as well as high temperature steam for input to the electrolyzer. During the first year, solar to hydrogen conversion efficiencies have been considered. The third task, Hydrogen safety studies, covers two topics: a review of codes, standards, regulations, recommendations, certifications, and pamphlets which address safety of gaseous fuels; and an experimental investigation of hydrogen flame impingement.

  20. Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy

    E-Print Network [OSTI]

    Lipman, Timothy; Brooks, Cameron

    2006-01-01T23:59:59.000Z

    psi) High-pressure hydrogen compressor Compressed hydrogen2005 High-pressure hydrogen compressor Compressed hydrogenthe hydrogen, a hydrogen compressor, high-pressure tank

  1. Hydrogen Filling Station

    SciTech Connect (OSTI)

    Boehm, Robert F; Sabacky, Bruce; Anderson II, Everett B; Haberman, David; Al-Hassin, Mowafak; He, Xiaoming; Morriseau, Brian

    2010-02-24T23:59:59.000Z

    Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. The Freedom CAR and Freedom FUEL initiatives emphasize the importance of hydrogen as a future transportation fuel. Presently, Las Vegas has one hydrogen fueling station powered by natural gas. However, the use of traditional sources of energy to produce hydrogen does not maximize the benefit. The hydrogen fueling station developed under this grant used electrolysis units and solar energy to produce hydrogen fuel. Water and electricity are furnished to the unit and the output is hydrogen and oxygen. Three vehicles were converted to utilize the hydrogen produced at the station. The vehicles were all equipped with different types of technologies. The vehicles were used in the day-to-day operation of the Las Vegas Valley Water District and monitoring was performed on efficiency, reliability and maintenance requirements. The research and demonstration utilized for the reconfiguration of these vehicles could lead to new technologies in vehicle development that could make hydrogen-fueled vehicles more cost effective, economical, efficient and more widely used. In order to advance the development of a hydrogen future in Southern Nevada, project partners recognized a need to bring various entities involved in hydrogen development and deployment together as a means of sharing knowledge and eliminating duplication of efforts. A road-mapping session was held in Las Vegas in June 2006. The Nevada State Energy Office, representatives from DOE, DOE contractors and LANL, NETL, NREL were present. Leadership from the National hydrogen Association Board of Directors also attended. As a result of this session, a roadmap for hydrogen development was created. This roadmap has the ability to become a tool for use by other road-mapping efforts in the hydrogen community. It could also become a standard template for other states or even countries to approach planning for a hydrogen future. Project partners also conducted a workshop on hydrogen safety and permitting. This provided an opportunity for the various permitting agencies and end users to gather to share experiences and knowledge. As a result of this workshop, the permitting process for the hydrogen filling station on the Las Vegas Valley Water Districts land was done more efficiently and those who would be responsible for the operation were better educated on the safety and reliability of hydrogen production and storage. The lessons learned in permitting the filling station and conducting this workshop provided a basis for future hydrogen projects in the region. Continuing efforts to increase the working pressure of electrolysis and efficiency have been pursued. Research was also performed on improving the cost, efficiency and durability of Proton Exchange Membrane (PEM) hydrogen technology. Research elements focused upon PEM membranes, electrodes/catalysts, membrane-electrode assemblies, seals, bipolar plates, utilization of renewable power, reliability issues, scale, and advanced conversion topics. Additionally, direct solar-to-hydrogen conversion research to demonstrate stable and efficient photoelectrochemistry (PEC) hydrogen production systems based on a number of optional concepts was performed. Candidate PEC concepts included technical obstacles such as inefficient photocatalysis, inadequate photocurrent due to non-optimal material band gap energies, rapid electron-hole recombination, reduced hole mobility and diminished operational lifetimes of surface materials exposed to electrolytes. Project Objective 1: Design, build, operate hydrogen filling station Project Objective 2: Perform research and development for utilizing solar technologies on the hydrogen filling station and convert two utility vehicles for use by the station operators Project Objective 3: Increase capacity of hydrogen filling station; add additional vehicle; conduct safety workshop; develop a roadmap for hydrogen development; accelerate the development of photovoltaic components Project Objective 4:

  2. Ultrafine hydrogen storage powders

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Ellis, Timothy W. (Doylestown, PA); Pecharsky, Vitalij K. (Ames, IA); Ting, Jason (Ames, IA); Terpstra, Robert (Ames, IA); Bowman, Robert C. (La Mesa, CA); Witham, Charles K. (Pasadena, CA); Fultz, Brent T. (Pasadena, CA); Bugga, Ratnakumar V. (Arcadia, CA)

    2000-06-13T23:59:59.000Z

    A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

  3. High Pressure Hydrogen Materials Compatibility of Piezoelectric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressure Hydrogen Materials Compatibility of Piezoelectric Films. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films. Abstract: Abstract: Hydrogen is being...

  4. Sandia National Laboratories: Solar Thermochemical Hydrogen Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Materials & Components Compatibility Hydrogen Behavior Quantitative Risk Assessment Hydrogen Infrastructure Solar Thermochemical Hydrogen Production Market Transformation...

  5. Hydrogen Permeation Resistant Coatings

    SciTech Connect (OSTI)

    KORINKO, PAUL; ADAMS, THAD; CREECH, GREGGORY

    2005-06-15T23:59:59.000Z

    As the National Hydrogen Economy continues to develop and evolve the need for structural materials that can resist hydrogen assisted degradation will become critical. To date austenitic stainless steel materials have been shown to be mildly susceptible to hydrogen attack which results in lower mechanical and fracture strengths. As a result, hydrogen permeation barrier coatings may be applied to these ferrous alloys to retard hydrogen ingress. Hydrogen is known to be very mobile in materials of construction. In this study, the permeation resistance of bare stainless steel samples and coated stainless steel samples was tested. The permeation resistance was measured using a modular permeation rig using a pressure rise technique. The coating microstructure and permeation results will be discussed in this document as will some additional testing.

  6. Safety Issues with Hydrogen as a Vehicle Fuel

    SciTech Connect (OSTI)

    Cadwallader, Lee Charles; Herring, James Stephen

    1999-10-01T23:59:59.000Z

    This report is an initial effort to identify and evaluate safety issues associated with the use of hydrogen as a vehicle fuel in automobiles. Several forms of hydrogen have been considered: gas, liquid, slush, and hydrides. The safety issues have been discussed, beginning with properties of hydrogen and the phenomenology of hydrogen combustion. Safety-related operating experiences with hydrogen vehicles have been summarized to identify concerns that must be addressed in future design activities and to support probabilistic risk assessment. Also, applicable codes, standards, and regulations pertaining to hydrogen usage and refueling have been identified and are briefly discussed. This report serves as a safety foundation for any future hydrogen safety work, such as a safety analysis or a probabilistic risk assessment.

  7. Safety Issues with Hydrogen as a Vehicle Fuel

    SciTech Connect (OSTI)

    L. C. Cadwallader; J. S. Herring

    1999-09-01T23:59:59.000Z

    This report is an initial effort to identify and evaluate safety issues associated with the use of hydrogen as a vehicle fuel in automobiles. Several forms of hydrogen have been considered: gas, liquid, slush, and hydrides. The safety issues have been discussed, beginning with properties of hydrogen and the phenomenology of hydrogen combustion. Safety-related operating experiences with hydrogen vehicles have been summarized to identify concerns that must be addressed in future design activities and to support probabilistic risk assessment. Also, applicable codes, standards, and regulations pertaining to hydrogen usage and refueling have been identified and are briefly discussed. This report serves as a safety foundation for any future hydrogen safety work, such as a safety analysis or a probabilistic risk assessment.

  8. Hydrogen Macro System Model User Guide, Version 1.2.1

    SciTech Connect (OSTI)

    Ruth, M.; Diakov, V.; Sa, T.; Goldsby, M.; Genung, K.; Hoseley, R.; Smith, A.; Yuzugullu, E.

    2009-07-01T23:59:59.000Z

    The Hydrogen Macro System Model (MSM) is a simulation tool that links existing and emerging hydrogen-related models to perform rapid, cross-cutting analysis. It allows analysis of the economics, primary energy-source requirements, and emissions of hydrogen production and delivery pathways.

  9. Hydrogen powered bus

    ScienceCinema (OSTI)

    None

    2013-11-22T23:59:59.000Z

    Take a ride on a new type of bus, fueled by hydrogen. These hydrogen taxis are part of a Department of Energy-funded deployment of hydrogen powered vehicles and fueling infrastructure at nine federal facilities across the country to demonstrate this market-ready advanced technology. Produced and leased by Ford Motor Company , they consist of one 12- passenger bus and one nine-passenger bus. More information at: http://go.usa.gov/Tgr

  10. Hydrogen Delivery - Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Delivery Hydrogen Delivery - Basics Hydrogen Delivery - Basics Photo of light-duty vehicle at hydrogen refueling station. Infrastructure is required to move hydrogen from the...

  11. Department of Energy - Hydrogen

    Broader source: Energy.gov (indexed) [DOE]

    Goes to.... Lighting Up Operations with Hydrogen and Fuel Cell Technology http:energy.goveerearticlesand-oscar-sustainable-mobile-lighting-goes-lighting-operations-hydro...

  12. Hydrogen Industrial Trucks

    Broader source: Energy.gov [DOE]

    Slides from the U.S. Department of Energy Hydrogen Component and System Qualification Workshop held November 4, 2010 in Livermore, CA.

  13. Hydrogen purification system

    DOE Patents [OSTI]

    Golben, Peter Mark

    2010-06-15T23:59:59.000Z

    The present invention provides a system to purify hydrogen involving the use of a hydride compressor and catalytic converters combined with a process controller.

  14. Renewable Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Remick, R. J.

    2009-11-16T23:59:59.000Z

    Presentation about the United State's dependence on oil, how energy solutions are challenging, and why hydrogen should be considered as a long-term alternative for transportation fuel.

  15. Hydrogen Storage Related Links

    Broader source: Energy.gov [DOE]

    The following resources provide details about DOE-funded hydrogen storage activities, research plans and roadmaps, models and tools, and additional related links.

  16. Sustainable hydrogen production

    SciTech Connect (OSTI)

    Block, D.L.; Linkous, C.; Muradov, N.

    1996-01-01T23:59:59.000Z

    This report describes the Sustainable Hydrogen Production research conducted at the Florida Solar Energy Center (FSEC) for the past year. The report presents the work done on the following four tasks: Task 1--production of hydrogen by photovoltaic-powered electrolysis; Task 2--solar photocatalytic hydrogen production from water using a dual-bed photosystem; Task 3--development of solid electrolytes for water electrolysis at intermediate temperatures; and Task 4--production of hydrogen by thermocatalytic cracking of natural gas. For each task, this report presents a summary, introduction/description of project, and results.

  17. DOE Hydrogen Program Overview

    Broader source: Energy.gov (indexed) [DOE]

    CO 2 emissions & energy consumption International Partnership for the Hydrogen Economy Norway An IPHE Vision: "... consumers will have the practical option of purchasing a...

  18. Hydrogen Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    The fuel cell an energy conversion device that can efficiently capture and use the power of hydrogen is the key to making it happen.

  19. Hydrogen permeation resistant barrier

    DOE Patents [OSTI]

    McGuire, J.C.; Brehm, W.F.

    1980-02-08T23:59:59.000Z

    A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

  20. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

    2013-02-12T23:59:59.000Z

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  1. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T. (Ann Arbor, MI); Li, Yingwel (Ann Arbor, MI); Lachawiec, Jr., Anthony J. (Ann Arbor, MI)

    2011-05-31T23:59:59.000Z

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  2. Hydrogen Energy Technology Geoff Dutton

    E-Print Network [OSTI]

    Watson, Andrew

    Hydrogen-fuelled internal combustion engines Hydrogen-fuelled turbines Fuel cells Hydrogen systems OverallHydrogen Energy Technology Geoff Dutton April 2002 Tyndall Centre for Climate Change Research Tyndall°Centre for Climate Change Research Working Paper 17 #12;Hydrogen Energy Technology Dr Geoff Dutton

  3. Combination moisture and hydrogen getter

    DOE Patents [OSTI]

    Not Available

    1982-04-29T23:59:59.000Z

    A combination moisture and hydrogen getter comprises (a) a moisture getter comprising a readily oxidizable metal; and (b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the reusltant hydrogen.

  4. DOE and FreedomCAR and Fuel Partnership Hydrogen Delivery and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE and FreedomCAR and Fuel Partnership Hydrogen Delivery and On-Board Storage Analysis Workshop DOE and FreedomCAR and Fuel Partnership Hydrogen Delivery and On-Board Storage...

  5. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

    1980-08-12T23:59:59.000Z

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  6. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-05-08T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

  7. Findings of Hydrogen Internal Combustion Engine Durability

    SciTech Connect (OSTI)

    Garrett Beauregard

    2010-12-31T23:59:59.000Z

    Hydrogen Internal Combustion Engine (HICE) technology takes advantage of existing knowledge of combustion engines to provide a means to power passenger vehicle with hydrogen, perhaps as an interim measure while fuel cell technology continues to mature. This project seeks to provide data to determine the reliability of these engines. Data were collected from an engine operated on a dynamometer for 1000 hours of continuous use. Data were also collected from a fleet of eight (8) full-size pickup trucks powered with hydrogen-fueled engines. In this particular application, the data show that HICE technology provided reliable service during the operating period of the project. Analyses of engine components showed little sign of wear or stress except for cylinder head valves and seats. Material analysis showed signs of hydrogen embrittlement in intake valves.

  8. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1993-01-01T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  9. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-03-30T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  10. Electrochemical hydrogen Storage Systems

    SciTech Connect (OSTI)

    Dr. Digby Macdonald

    2010-08-09T23:59:59.000Z

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

  11. Florida Hydrogen Initiative

    SciTech Connect (OSTI)

    Block, David L

    2013-06-30T23:59:59.000Z

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cel

  12. Membrane for hydrogen recovery from streams containing hydrogen sulfide

    DOE Patents [OSTI]

    Agarwal, Pradeep K.

    2007-01-16T23:59:59.000Z

    A membrane for hydrogen recovery from streams containing hydrogen sulfide is provided. The membrane comprises a substrate, a hydrogen permeable first membrane layer deposited on the substrate, and a second membrane layer deposited on the first layer. The second layer contains sulfides of transition metals and positioned on the on a feed side of the hydrogen sulfide stream. The present invention also includes a method for the direct decomposition of hydrogen sulfide to hydrogen and sulfur.

  13. Gaseous and Liquid Hydrogen Storage

    Broader source: Energy.gov [DOE]

    Today's state of the art for hydrogen storage includes 5,000- and 10,000-psi compressed gas tanks and cryogenic liquid hydrogen tanks for on-board hydrogen storage.

  14. Renewable Resources for Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A. A.

    2010-05-03T23:59:59.000Z

    This presentation provides an overview of renewable resources for hydrogen. It was presented at the National Hydrogen Association Hydrogen Conference & Expo in Long Beach, CA, May 3-6, 2010.

  15. Hydrogen from Coal Edward Schmetz

    E-Print Network [OSTI]

    Turbines Carbon Capture & Sequestration Carbon Capture & Sequestration The Hydrogen from Coal Program Cells, Turbines, and Carbon Capture & Sequestration #12;Production Goal for Hydrogen from Coal Central Separation System PSA Membrane Membrane Carbon Sequestration Yes (87%) Yes (100%) Yes (100%) Hydrogen

  16. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    It appears to us that hydrogen is a highly promising option0616 The Bumpy Road to Hydrogen Daniel Sperling Joan OgdenThe Bumpy Road to Hydrogen 1 Daniel Sperling and Joan Ogden

  17. Hydrogen Delivery- Current Technology

    Broader source: Energy.gov [DOE]

    Hydrogen is transported from the point of production to the point of use via pipeline, over the road in cryogenic liquid trucks or gaseous tube trailers, or by rail or barge. Read on to learn more about current hydrogen delivery and storage technologies.

  18. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, Barbara S. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1995-01-01T23:59:59.000Z

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

  19. August 2006 Hydrogen Program

    E-Print Network [OSTI]

    after the date of enactment of this Act, the Secretary shall submit to Congress a report evaluating's primary transportation fuel from petroleum, which is increasingly imported, to hydrogen, which can the energy, environmental and economic benefits of a hydrogen economy. The goals and milestones

  20. Hydrogen Storage CODES & STANDARDS

    E-Print Network [OSTI]

    automotive start-up. · Air/Thermal/Water Management ­ improved air systems, high temperature membranes, heat to pump Hydrogen Fuel/ Storage/ Infrastructure $45/kW (2010) $30kW (2015) 325 W/kg 220 W/L 60% (hydrogen system Component Air management, sensors, MEA's, membranes, Bipolar Plates, fuel processor reactor zones

  1. Hydrogen Fuel Quality

    SciTech Connect (OSTI)

    Rockward, Tommy [Los Alamos National Laboratory

    2012-07-16T23:59:59.000Z

    For the past 6 years, open discussions and/or meetings have been held and are still on-going with OEM, Hydrogen Suppliers, other test facilities from the North America Team and International collaborators regarding experimental results, fuel clean-up cost, modeling, and analytical techniques to help determine levels of constituents for the development of an international standard for hydrogen fuel quality (ISO TC197 WG-12). Significant progress has been made. The process for the fuel standard is entering final stages as a result of the technical accomplishments. The objectives are to: (1) Determine the allowable levels of hydrogen fuel contaminants in support of the development of science-based international standards for hydrogen fuel quality (ISO TC197 WG-12); and (2) Validate the ASTM test method for determining low levels of non-hydrogen constituents.

  2. Sandia National Laboratories: Hydrogen Infrastructure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Infrastructure Widespread Hydrogen Fueling Infrastructure Is the Goal of H2FIRST Project On June 4, 2014, in Capabilities, Center for Infrastructure Research and...

  3. Sandia National Laboratories: Hydrogen Safety

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Safety Solar Thermochemical Hydrogen Production On June 13, 2014, in SNL maintains the equipment, experts, and partnerships required to develop technology for solar...

  4. Hydrogen Storage Technical Team Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and technology pathways are impacted by their analyses. These technical teams include Fuel Cells, Fuel Pathway Integration, Hydrogen Delivery, Hydrogen Production, Materials,...

  5. Turing Water into Hydrogen Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Water into Hydrogen Fuel Turning Water into Hydrogen Fuel New method creates highly reactive catalytic surface, packed with hydroxyl species May 15, 2012 | Tags: Franklin,...

  6. CAN HYDROGEN WIN?: EXPLORING SCENARIOS FOR HYDROGEN

    E-Print Network [OSTI]

    -constrained world. Long-run simulations were created using CIMS, a hybrid energy-economy model supply submodel was built to simulate economies of scale in infrastructure. Capital costs, technology such as biofuel plug-in hybrids, but did well when biofuels were removed or priced excessively. Hydrogen fuel

  7. The development of a fullerene based hydrogen storage system

    SciTech Connect (OSTI)

    Brosha, E.L.; Davey, J.R.; Garzon, F.H.; Gottesfeld, S.

    1998-11-01T23:59:59.000Z

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The project objective was to evaluate hydrogen uptake by fullerene substrates and to probe the potential of the hydrogen/fullerene system for hydrogen fuel storage. As part of this project, the authors have completed and tested a fully automated, computer controlled system for measuring hydrogen uptake that is capable of handling both a vacuum of 1 x 10{sup -6} torr and pressures greater than 200 bars. The authors have first established conditions for significant uptake of hydrogen by fullerenes. Subsequently, hydrogenation and dehydrogenation of pure and catalyst-doped C60 was further studied to probe suitability for hydrogen storage applications. C60 {center_dot} H18.7 was prepared at 100 bar H2 and 400 C, corresponding to hydrogen uptake of 2.6 wt%. Dehydrogenation of C60 {center_dot} H18.7 was studied using thermogravimetric and powder x-ray diffraction analysis. The C60 {center_dot} H18.7 molecule was found to be stable up to 430 C in Ar, at which point the release of hydrogen took place simultaneously with the collapse of the fullerene structure. X-ray diffraction analysis performed on C60 {center_dot} H18.7 samples dehydrogenated at 454 C, 475 C, and 600 C showed an increasing volume fraction of amorphous material due to randomly oriented, single-layer graphine sheets. Evolved gas analysis using gas chromatography and mass spectroscopy confirmed the presence of both H{sub 2} and methane upon dehydrogenation, indicating decomposition of the fullerene. The remaining carbon could not be re-hydrogenated. These results provide the first complete evidence for the irreversible nature of fullerene hydrogenation and for limitations imposed on the hydrogenation/dehydrogenation cycle by the limited thermal stability of the molecular crystal of fullerene.

  8. Advancing the Hydrogen Safety Knowledge Base

    SciTech Connect (OSTI)

    Weiner, Steven C.

    2014-12-01T23:59:59.000Z

    A White Paper of the International Energy Agency Hydrogen Implementing Agreement Task 31 - Hydrogen Safety

  9. Planning, Budget, and Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis (Revised) Philip Patterson (Economist) and Jeff Dowd (Economist) DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29,...

  10. Hydrogen Generation From Electrolysis

    SciTech Connect (OSTI)

    Steven Cohen; Stephen Porter; Oscar Chow; David Henderson

    2009-03-06T23:59:59.000Z

    Small-scale (100-500 kg H2/day) electrolysis is an important step in increasing the use of hydrogen as fuel. Until there is a large population of hydrogen fueled vehicles, the smaller production systems will be the most cost-effective. Performing conceptual designs and analyses in this size range enables identification of issues and/or opportunities for improvement in approach on the path to 1500 kg H2/day and larger systems. The objectives of this program are to establish the possible pathways to cost effective larger Proton Exchange Membrane (PEM) water electrolysis systems and to identify areas where future research and development efforts have the opportunity for the greatest impact in terms of capital cost reduction and efficiency improvements. System design and analysis was conducted to determine the overall electrolysis system component architecture and develop a life cycle cost estimate. A design trade study identified subsystem components and configurations based on the trade-offs between system efficiency, cost and lifetime. Laboratory testing of components was conducted to optimize performance and decrease cost, and this data was used as input to modeling of system performance and cost. PEM electrolysis has historically been burdened by high capital costs and lower efficiency than required for large-scale hydrogen production. This was known going into the program and solutions to these issues were the focus of the work. The program provided insights to significant cost reduction and efficiency improvement opportunities for PEM electrolysis. The work performed revealed many improvement ideas that when utilized together can make significant progress towards the technical and cost targets of the DOE program. The cell stack capital cost requires reduction to approximately 25% of todays technology. The pathway to achieve this is through part count reduction, use of thinner membranes, and catalyst loading reduction. Large-scale power supplies are available today that perform in a range of efficiencies, >95%, that are suitable for the overall operational goals. The balance of plant scales well both operationally and in terms of cost becoming a smaller portion of the overall cost equation as the systems get larger. Capital cost reduction of the cell stack power supplies is achievable by modifying the system configuration to have the cell stacks in electrical series driving up the DC bus voltage, thereby allowing the use of large-scale DC power supply technologies. The single power supply approach reduces cost. Elements of the cell stack cost reduction and efficiency improvement work performed in the early stage of the program is being continued in subsequent DOE sponsored programs and through internal investment by Proton. The results of the trade study of the 100 kg H2/day system have established a conceptual platform for design and development of a next generation electrolyzer for Proton. The advancements started by this program have the possibility of being realized in systems for the developing fueling markets in 2010 period.

  11. Evidence For The Production Of Slow Antiprotonic Hydrogen In Vacuum

    E-Print Network [OSTI]

    N. Zurlo; M. Amoretti; C. Amsler; G. Bonomi; C. Carraro; C. L. Cesar; M. Charlton; M. Doser; A. Fontana; R. Funakoshi; P. Genova; R. S. Hayano; L. V. Jorgensen; A. Kellerbauer; V. Lagomarsino; R. Landua; E. Lodi Rizzini; M. Macr; N. Madsen; G. Manuzio; D. Mitchard; P. Montagna; L. G. Posada; H. Pruys; C. Regenfus; A. Rotondi; G. Testera; D. P. Van der Werf; A. Variola; L. Venturelli; Y. Yamazaki

    2007-08-28T23:59:59.000Z

    We present evidence showing how antiprotonic hydrogen, the quasistable antiproton-proton (pbar-p) bound system, has been synthesized following the interaction of antiprotons with the hydrogen molecular ion (H2+) in a nested Penning trap environment. From a careful analysis of the spatial distributions of antiproton annihilation events, evidence is presented for antiprotonic hydrogen production with sub-eV kinetic energies in states around n=70, and with low angular momenta. The slow antiprotonic hydrogen may be studied using laser spectroscopic techniques.

  12. Hydrogen plasma enhanced crystallization of hydrogenated amorphous silicon films

    E-Print Network [OSTI]

    Hydrogen plasma enhanced crystallization of hydrogenated amorphous silicon films K. Pangal,a) J. C August 1998; accepted for publication 21 October 1998 We report that a room temperature hydrogen plasma thermal crystallization of amorphous silicon time by a factor of five. Exposure to hydrogen plasma reduces

  13. BP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop

    E-Print Network [OSTI]

    efforts were undertaken Conversion took place during a period of less regulation on pipeline activityBP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop August 30-31, 2005 Gary P UK partnership opened the first hydrogen demonstration refueling station Two hydrogen pipelines

  14. NREL's Hydrogen Program

    SciTech Connect (OSTI)

    None

    2011-01-01T23:59:59.000Z

    The research and development taking place today at the National Renewable Energy Laboratory (NREL) is paving the way for nature's most plentiful elementhydrogento power the next generation. NREL researchers are working to unlock the potential of hydrogen and to advance the fuel cell technologies that will power the automobiles, equipment, and buildings of tomorrow. Hydrogen and fuel cells are a fundamental part of the broader portfolio of renewable technologies that are moving our nation toward its goals of energy independence and sustainability.

  15. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T. (Livermore, CA)

    1981-01-01T23:59:59.000Z

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  16. BILIWG Meeting: DOE Hydrogen Quality Working Group

    E-Print Network [OSTI]

    natural gas and ethanol are similar Product gas composition from steam reforming Species Natural Gas: distributed (forecourt) production reforming of natural gas (autothermal & steam reforming) reforming the H2A Argonne is modeling a steam reformer + PSA process Results will be incorporated into H2A

  17. Nanostructured materials for hydrogen storage

    DOE Patents [OSTI]

    Williamson, Andrew J. (Pleasanton, CA); Reboredo, Fernando A. (Pleasanton, CA)

    2007-12-04T23:59:59.000Z

    A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

  18. Hybrid & Hydrogen Vehicle Research Laboratory

    E-Print Network [OSTI]

    Lee, Dongwon

    Hybrid & Hydrogen Vehicle Research Laboratory www.vss.psu.edu/hhvrl Joel R. Anstrom, Director 201 The Pennsylvania Transportation Institute Hybrid and Hydrogen Vehicle Research Laboratory will contribute to the advancement of hybrid and hydrogen vehicle technology to promote the emerging hydrogen economy by providing

  19. Webinar: Hydrogen Compatibility of Materials

    Broader source: Energy.gov [DOE]

    Video recording of the webinar titled, Hydrogen Compatibility of Materials, originally presented on August 13, 2013.

  20. Hydrogen Production & Delivery Sara Dillich

    E-Print Network [OSTI]

    ). 15% solar-to-chemical energy efficiency by microalgae Biomass Gasification Hydrogen Production Cost

  1. Hydrogen storage compositions

    SciTech Connect (OSTI)

    Li, Wen; Vajo, John J.; Cumberland, Robert W.; Liu, Ping

    2011-04-19T23:59:59.000Z

    Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH4- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH4- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

  2. Hydrogen storage compositions

    DOE Patents [OSTI]

    Li, Wen; Vajo, John J.; Cumberland, Robert W.; Liu, Ping

    2011-04-19T23:59:59.000Z

    Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

  3. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    biomass, landfill gas, bio-oil or biodiesel. CHP systems that use natural gas, wood pellets, hydrogen, propane or heating oil are also eligible.* March 28, 2014 Net Metering The...

  4. National Hydrogen Energy Roadmap

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy developme

  5. The Hydrogen Connection

    SciTech Connect (OSTI)

    Barilo, Nick F.

    2014-05-01T23:59:59.000Z

    As the world seeks to identify alternative energy sources, hydrogen and fuel cell technologies will offer a broad range of benefits for the environment, the economy and energy security.

  6. SunLine Test Drives Hydrogen Bus: Hydrogen Fuel Cell & Infrastructure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Test Drives Hydrogen Bus: Hydrogen Fuel Cell & Infrastructure Technologies Program, Fuel Cell Bus Demonstration Projects Fact Sheet. SunLine Test Drives Hydrogen Bus: Hydrogen Fuel...

  7. Low Cost Hydrogen Production Platform

    SciTech Connect (OSTI)

    Timothy M. Aaron, Jerome T. Jankowiak

    2009-10-16T23:59:59.000Z

    A technology and design evaluation was carried out for the development of a turnkey hydrogen production system in the range of 2.4 - 12 kg/h of hydrogen. The design is based on existing SMR technology and existing chemical processes and technologies to meet the design objectives. Consequently, the system design consists of a steam methane reformer, PSA system for hydrogen purification, natural gas compression, steam generation and all components and heat exchangers required for the production of hydrogen. The focus of the program is on packaging, system integration and an overall step change in the cost of capital required for the production of hydrogen at small scale. To assist in this effort, subcontractors were brought in to evaluate the design concepts and to assist in meeting the overall goals of the program. Praxair supplied the overall system and process design and the subcontractors were used to evaluate the components and system from a manufacturing and overall design optimization viewpoint. Design for manufacturing and assembly (DFMA) techniques, computer models and laboratory/full-scale testing of components were utilized to optimize the design during all phases of the design development. Early in the program evaluation, a review of existing Praxair hydrogen facilities showed that over 50% of the installed cost of a SMR based hydrogen plant is associated with the high temperature components (reformer, shift, steam generation, and various high temperature heat exchange). The main effort of the initial phase of the program was to develop an integrated high temperature component for these related functions. Initially, six independent concepts were developed and the processes were modeled to determine overall feasibility. The six concepts were eventually narrowed down to the highest potential concept. A US patent was awarded in February 2009 for the Praxair integrated high temperature component design. A risk analysis of the high temperature component was conducted to identify any potential design deficiency related to the concept. The analysis showed that no fundamental design flaw existed with the concept, but additional simulations and prototypes would be required to verify the design prior to fabricating a production unit. These identified risks were addressed in detail during Phase II of the development program. Along with the models of the high temperature components, a detailed process and 3D design model of the remainder of system, including PSA, compression, controls, water treatment and instrumentation was developed and evaluated. Also, in Phase II of the program, laboratory/fullscale testing of the high temperature components was completed and stable operation/control of the system was verified. The overall design specifications and test results were then used to develop accurate hydrogen costs for the optimized system. Praxair continued development and testing of the system beyond the Phase II funding provided by the DOE through the end of 2008. This additional testing is not documented in this report, but did provide significant additional data for development of a prototype system as detailed in the Phase III proposal. The estimated hydrogen product costs were developed (2007 basis) for the 4.8 kg/h system at production rates of 1, 5, 10, 100 and 1,000 units built per year. With the low cost SMR approach, the product hydrogen costs for the 4.8 kg/h units at 50 units produced per year were approximately $3.02 per kg. With increasing the volume production to 1,000 units per year, the hydrogen costs are reduced by about 12% to $2.67 per kg. The cost reduction of only 12% is a result of significant design and fabrication efficiencies being realized in all levels of production runs through utilizing the DFMA principles. A simplified and easily manufactured design does not require large production volumes to show significant cost benefits. These costs represent a significant improvement and a new benchmark in the cost to produce small volume on-site hydrogen using existing process technologies. The cost mo

  8. Hydrogen recovery process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

    2000-01-01T23:59:59.000Z

    A treatment process for a hydrogen-containing off-gas stream from a refinery, petrochemical plant or the like. The process includes three separation steps: condensation, membrane separation and hydrocarbon fraction separation. The membrane separation step is characterized in that it is carried out under conditions at which the membrane exhibits a selectivity in favor of methane over hydrogen of at least about 2.5.

  9. Purdue Hydrogen Systems Laboratory

    SciTech Connect (OSTI)

    Jay P Gore; Robert Kramer; Timothee L Pourpoint; P. V. Ramachandran; Arvind Varma; Yuan Zheng

    2011-12-28T23:59:59.000Z

    The Hydrogen Systems Laboratory in a unique partnership between Purdue University's main campus in West Lafayette and the Calumet campus was established and its capabilities were enhanced towards technology demonstrators. The laboratory engaged in basic research in hydrogen production and storage and initiated engineering systems research with performance goals established as per the USDOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program. In the chemical storage and recycling part of the project, we worked towards maximum recycling yield via novel chemical selection and novel recycling pathways. With the basic potential of a large hydrogen yield from AB, we used it as an example chemical but have also discovered its limitations. Further, we discovered alternate storage chemicals that appear to have advantages over AB. We improved the slurry hydrolysis approach by using advanced slurry/solution mixing techniques. We demonstrated vehicle scale aqueous and non-aqueous slurry reactors to address various engineering issues in on-board chemical hydrogen storage systems. We measured the thermal properties of raw and spent AB. Further, we conducted experiments to determine reaction mechanisms and kinetics of hydrothermolysis in hydride-rich solutions and slurries. We also developed a continuous flow reactor and a laboratory scale fuel cell power generation system. The biological hydrogen production work summarized as Task 4.0 below, included investigating optimal hydrogen production cultures for different substrates, reducing the water content in the substrate, and integrating results from vacuum tube solar collector based pre and post processing tests into an enhanced energy system model. An automated testing device was used to finalize optimal hydrogen production conditions using statistical procedures. A 3 L commercial fermentor (New Brunswick, BioFlo 115) was used to finalize testing of larger samples and to consider issues related to scale up. Efforts continued to explore existing catalytic methods involving nano catalysts for capture of CO2 from the fermentation process.

  10. Wind-To-Hydrogen Energy Pilot Project

    SciTech Connect (OSTI)

    Ron Rebenitsch; Randall Bush; Allen Boushee; Brad G. Stevens; Kirk D. Williams; Jeremy Woeste; Ronda Peters; Keith Bennett

    2009-04-24T23:59:59.000Z

    WIND-TO-HYDROGEN ENERGY PILOT PROJECT: BASIN ELECTRIC POWER COOPERATIVE In an effort to address the hurdles of wind-generated electricity (specifically wind's intermittency and transmission capacity limitations) and support development of electrolysis technology, Basin Electric Power Cooperative (BEPC) conducted a research project involving a wind-to-hydrogen system. Through this effort, BEPC, with the support of the Energy & Environmental Research Center at the University of North Dakota, evaluated the feasibility of dynamically scheduling wind energy to power an electrolysis-based hydrogen production system. The goal of this project was to research the application of hydrogen production from wind energy, allowing for continued wind energy development in remote wind-rich areas and mitigating the necessity for electrical transmission expansion. Prior to expending significant funding on equipment and site development, a feasibility study was performed. The primary objective of the feasibility study was to provide BEPC and The U.S. Department of Energy (DOE) with sufficient information to make a determination whether or not to proceed with Phase II of the project, which was equipment procurement, installation, and operation. Four modes of operation were considered in the feasibility report to evaluate technical and economic merits. Mode 1 - scaled wind, Mode 2 - scaled wind with off-peak, Mode 3 - full wind, and Mode 4 - full wind with off-peak In summary, the feasibility report, completed on August 11, 2005, found that the proposed hydrogen production system would produce between 8000 and 20,000 kg of hydrogen annually depending on the mode of operation. This estimate was based on actual wind energy production from one of the North Dakota (ND) wind farms of which BEPC is the electrical off-taker. The cost of the hydrogen produced ranged from $20 to $10 per kg (depending on the mode of operation). The economic sensitivity analysis performed as part of the feasibility study showed that several factors can greatly affect, both positively and negatively, the "per kg" cost of hydrogen. After a September 15, 2005, meeting to evaluate the advisability of funding Phase II of the project DOE concurred with BEPC that Phase I results did warrant a "go" recommendation to proceed with Phase II activities. The hydrogen production system was built by Hydrogenics and consisted of several main components: hydrogen production system, gas control panel, hydrogen storage assembly and hydrogen-fueling dispenser The hydrogen production system utilizes a bipolar alkaline electrolyzer nominally capable of producing 30 Nm3/h (2.7 kg/h). The hydrogen is compressed to 6000 psi and delivered to an on-site three-bank cascading storage assembly with 80 kg of storage capacity. Vehicle fueling is made possible through a Hydrogenics-provided gas control panel and dispenser able to fuel vehicles to 5000 psi. A key component of this project was the development of a dynamic scheduling system to control the wind energy's variable output to the electrolyzer cell stacks. The dynamic scheduling system received an output signal from the wind farm, processed this signal based on the operational mode, and dispatched the appropriate signal to the electrolyzer cell stacks. For the study BEPC chose to utilize output from the Wilton wind farm located in central ND. Site design was performed from May 2006 through August 2006. Site construction activities were from August to November 2006 which involved earthwork, infrastructure installation, and concrete slab construction. From April - October 2007, the system components were installed and connected. Beginning in November 2007, the system was operated in a start-up/shakedown mode. Because of numerous issues, the start-up/shakedown period essentially lasted until the end of January 2008, at which time a site acceptance test was performed. Official system operation began on February 14, 2008, and continued through the end of December 2008. Several issues continued to prevent consistent operation, resulting in operation o

  11. Examining hydrogen transitions.

    SciTech Connect (OSTI)

    Plotkin, S. E.; Energy Systems

    2007-03-01T23:59:59.000Z

    This report describes the results of an effort to identify key analytic issues associated with modeling a transition to hydrogen as a fuel for light duty vehicles, and using insights gained from this effort to suggest ways to improve ongoing modeling efforts. The study reported on here examined multiple hydrogen scenarios reported in the literature, identified modeling issues associated with those scenario analyses, and examined three DOE-sponsored hydrogen transition models in the context of those modeling issues. The three hydrogen transition models are HyTrans (contractor: Oak Ridge National Laboratory), MARKAL/DOE* (Brookhaven National Laboratory), and NEMS-H2 (OnLocation, Inc). The goals of these models are (1) to help DOE improve its R&D effort by identifying key technology and other roadblocks to a transition and testing its technical program goals to determine whether they are likely to lead to the market success of hydrogen technologies, (2) to evaluate alternative policies to promote a transition, and (3) to estimate the costs and benefits of alternative pathways to hydrogen development.

  12. Atomic hydrogen interactions with amorphous carbon thin films Bhavin N. Jariwala,1

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Atomic hydrogen interactions with amorphous carbon thin films Bhavin N. Jariwala,1 Cristian V-scale interactions of H atoms with hydrogenated amorphous carbon a-C:H films were identified using molecular dynamics through a detailed analysis of the MD trajectories. The MD simulations showed that hydrogenation occurs

  13. Hydrogen storage and generation system

    DOE Patents [OSTI]

    Dentinger, Paul M. (Sunol, CA); Crowell, Jeffrey A. W. (Castro Valley, CA)

    2010-08-24T23:59:59.000Z

    A system for storing and generating hydrogen generally and, in particular, a system for storing and generating hydrogen for use in an H.sub.2/O.sub.2 fuel cell. The hydrogen storage system uses the beta particles from a beta particle emitting material to degrade an organic polymer material to release substantially pure hydrogen. In a preferred embodiment of the invention, beta particles from .sup.63Ni are used to release hydrogen from linear polyethylene.

  14. Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes &

    E-Print Network [OSTI]

    : Facilitate the creation and adoption of model building codes and equipment standards for hydrogen systems of hydrogen building codes for NFPA's hearing cycle. Facilitate in the adoption of the ICC codes in three key for hydrogen refueling and storage, by 2006; Complete and adopt the revised NFPA 55 standard for hydrogen

  15. DOE Hydrogen Program: 2006 Annual Merit Review and Peer Evaluation Report

    SciTech Connect (OSTI)

    Milliken, J.

    2006-09-01T23:59:59.000Z

    This report summarizes comments from the Peer Review Panel at the FY 2006 DOE Hydrogen Program Annual Merit Review, held on May 16-19, 2006, in Arlington, Virginia. The projects evaluated support the Department of Energy and President Bush's Hydrogen Initiative. The results of this merit review and peer evaluation are major inputs used by DOE to make funding decisions. Project areas include hydrogen production and delivery; hydrogen storage; fuel cells; technology validation; safety, codes and standards; education; and systems analysis.

  16. DOE Hydrogen Program: 2005 Annual Merit Review and Peer Evaluation Report

    SciTech Connect (OSTI)

    Chalk, S. G.

    2005-09-01T23:59:59.000Z

    This report summarizes comments from the Peer Review Panel at the FY 2005 DOE Hydrogen Program Annual Merit Review, held on May 23-26, 2005, in Arlington, Virginia. The projects evaluated support the Department of Energy and President Bush's Hydrogen Initiative. The results of this merit review and peer evaluation are major inputs used by DOE to make funding decisions. Project areas include hydrogen production and delivery; hydrogen storage; fuel cells; technology validation; safety, codes and standards; education; and systems analysis.

  17. Electrolytic hydrogen production infrastructure options evaluation. Final subcontract report

    SciTech Connect (OSTI)

    Thomas, C.E.; Kuhn, I.F. Jr. [Directed Technologies, Inc., Arlington, VA (United States)

    1995-09-01T23:59:59.000Z

    Fuel-cell electric vehicles have the potential to provide the range, acceleration, rapid refueling times, and other creature comforts associated with gasoline-powered vehicles, but with virtually no environmental degradation. To achieve this potential, society will have to develop the necessary infrastructure to supply hydrogen to the fuel-cell vehicles. Hydrogen could be stored directly on the vehicle, or it could be derived from methanol or other hydrocarbon fuels by on-board chemical reformation. This infrastructure analysis assumes high-pressure (5,000 psi) hydrogen on-board storage. This study evaluates one approach to providing hydrogen fuel: the electrolysis of water using off-peak electricity. Other contractors at Princeton University and Oak Ridge National Laboratory are investigating the feasibility of producing hydrogen by steam reforming natural gas, probably the least expensive hydrogen infrastructure alternative for large markets. Electrolytic hydrogen is a possible short-term transition strategy to provide relatively inexpensive hydrogen before there are enough fuel-cell vehicles to justify building large natural gas reforming facilities. In this study, the authors estimate the necessary price of off-peak electricity that would make electrolytic hydrogen costs competitive with gasoline on a per-mile basis, assuming that the electrolyzer systems are manufactured in relatively high volumes compared to current production. They then compare this off-peak electricity price goal with actual current utility residential prices across the US.

  18. Hydrogen production from carbonaceous material

    DOE Patents [OSTI]

    Lackner, Klaus S.; Ziock, Hans J.; Harrison, Douglas P.

    2004-09-14T23:59:59.000Z

    Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.

  19. Hydrogen Infrastructure Expansion: Consumer Demand and Cost-Reduction Potential (Presentation)

    SciTech Connect (OSTI)

    Melaina, M.

    2014-04-01T23:59:59.000Z

    The presentation summarizes key challenges in financing hydrogen infrastructure and reviews analysis tools available to inform investment decisions and reduce financial risks.

  20. DOE hydrogen program. Monthly progress report, February 2, 1996--February 29, 1996

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    The objective of this program is to conduct program planning, systems analysis and stakeholder outreach activities for the DOE Hydrogen Program. Progress is described.

  1. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Martin Chaplin

    2007-06-10T23:59:59.000Z

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

  2. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1995-09-19T23:59:59.000Z

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2}s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  3. Hydrogen-selective membrane

    DOE Patents [OSTI]

    Collins, J.P.; Way, J.D.

    1997-07-29T23:59:59.000Z

    A hydrogen-selective membrane comprises a tubular porous ceramic support having a palladium metal layer deposited on an inside surface of the ceramic support. The thickness of the palladium layer is greater than about 10 {micro}m but typically less than about 20 {micro}m. The hydrogen permeation rate of the membrane is greater than about 1.0 moles/m{sup 2} s at a temperature of greater than about 500 C and a transmembrane pressure difference of about 1,500 kPa. Moreover, the hydrogen-to-nitrogen selectivity is greater than about 600 at a temperature of greater than about 500 C and a transmembrane pressure of about 700 kPa. Hydrogen can be separated from a mixture of gases using the membrane. The method may include the step of heating the mixture of gases to a temperature of greater than about 400 C and less than about 1000 C before the step of flowing the mixture of gases past the membrane. The mixture of gases may include ammonia. The ammonia typically is decomposed to provide nitrogen and hydrogen using a catalyst such as nickel. The catalyst may be placed inside the tubular ceramic support. The mixture of gases may be supplied by an industrial process such as the mixture of exhaust gases from the IGCC process. 9 figs.

  4. Analysis of Class 8 Hybrid-Electric Truck Technologies Using Diesel, LNG, Electricity, and Hydrogen, as the Fuel for Various Applications

    E-Print Network [OSTI]

    Zhao, Hengbing

    2013-01-01T23:59:59.000Z

    in Table 11. For the hybrid vehicle economic comparisons,aspects of electric and hybrid vehicle design, analysis, andfuel cells and hybrid vehicle design. Dr. Burke has authored

  5. Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation

    SciTech Connect (OSTI)

    Sofronis, Petros [University of Illinois at Urbana-Champaign] [University of Illinois at Urbana-Champaign; Robertson, Ian M [University of Wisconsin-Madison] [University of Wisconsin-Madison

    2013-08-01T23:59:59.000Z

    Fundamental studies of hydrogen embrittlement of materials using both experimental observations and numerical simulations of the hydrogen/deformation interactions have been conducted. Our approach integrates mechanical property testing at the macro-scale, microstructural analyses and TEM observations of the deformation processes at the micro- and nano-scale, first-principles calculations of interfacial cohesion at the atomic scale, and finite element simulation and modeling at the micro- and macro-level. Focused Ion Beam machining in conjunction with Transmission Electron Microscopy were used to identify the salient micro-mechanisms of failure in the presence of hydrogen. Our analysis of low strength ferritic steels led to the discovery that quasi-cleavage is a dislocation plasticity controlled failure mode in agreement with the hydrogen enhanced plasticity mechanism. The microstructure underneath the fracture surface of 304 and 316 stainless steels was found to be significantly more complex than would have been predicted by the traditional models of fatigue. The general refinement of the microstructure that occurred near the fracture surface in the presence of hydrogen was such that one may argue that hydrogen stabilizes microstructural configurations to an extent not achievable in its absence. Finite element studies of hydrogen and deformation field similitude for cracks in real-life pipelines and laboratory fracture specimens yielded that the Single Edge Notch Tension specimen can be used to reliably study hydrogen material compatibility for pipeline structures. In addition, simulation of onset of crack propagation in low strength ferritic systems by void growth indicated that hydrogen can reduce the fracture toughness of the material by as much as 30%. Both experimental observations and numerical studies of hydrogen transport on hydrogen accumulations ahead of a crack tip yielded that dislocation transport can markedly enhance hydrogen populations which in turn can trigger fracture initiation.

  6. Hydrogen refueling station costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, Joan M; Jianxin, Ma

    2007-01-01T23:59:59.000Z

    High-pressure hydrogen compressor Compressed hydrogenapplies to hydrogen storage vessels and compressors. 2.4.4.vehicles. 3. Compressor: compresses hydrogen gas to achieve

  7. Hydrogen Refueling Station Costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, J; Jianxin, Ma

    2006-01-01T23:59:59.000Z

    High-pressure hydrogen compressor Compressed hydrogento hydrogen storage vessels and compressors. Feedstock Costvehicles 3. Compressor: compresses hydrogen gas to achieve

  8. 2013 Biological Hydrogen Production Workshop Summary Report ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Hydrogen Production Workshop Summary Report 2013 Biological Hydrogen Production Workshop Summary Report November 2013 summary report for the 2013 Biological Hydrogen...

  9. Hydrogen Production & Delivery | Department of Energy

    Energy Savers [EERE]

    Hydrogen Production & Delivery Hydrogen Production & Delivery "2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation H2...

  10. Hydrogen Refueling Station Costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, Joan M; Jianxin, Ma

    2006-01-01T23:59:59.000Z

    in planning a new hydrogen infrastructure: 1) the lack ofon the Costs of Hydrogen Infrastructure for Transportstudy. Studies of Hydrogen Infrastructure in China There

  11. Hydrogen refueling station costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, Joan M; Jianxin, Ma

    2007-01-01T23:59:59.000Z

    in planning a new hydrogen infrastructure: (1) the lack of1.3.3. Studies of hydrogen infrastructure in China Thereon the costs of hydrogen Infrastructure for transport

  12. Hydrogen Fuel Quality - Focus: Analytical Methods Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results Hydrogen Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results...

  13. Hydrogen production from microbial strains

    DOE Patents [OSTI]

    Harwood, Caroline S; Rey, Federico E

    2012-09-18T23:59:59.000Z

    The present invention is directed to a method of screening microbe strains capable of generating hydrogen. This method involves inoculating one or more microbes in a sample containing cell culture medium to form an inoculated culture medium. The inoculated culture medium is then incubated under hydrogen producing conditions. Once incubating causes the inoculated culture medium to produce hydrogen, microbes in the culture medium are identified as candidate microbe strains capable of generating hydrogen. Methods of producing hydrogen using one or more of the microbial strains identified as well as the hydrogen producing strains themselves are also disclosed.

  14. Validation of an Integrated Hydrogen Energy Station

    SciTech Connect (OSTI)

    Edward C. Heydorn

    2012-10-26T23:59:59.000Z

    This report presents the results of a 10-year project conducted by Air Products and Chemicals, Inc. (Air Products) to determine the feasibility of coproducing hydrogen with electricity. The primary objective was to demonstrate the technical and economic viability of a hydrogen energy station using a high-temperature fuel cell designed to produce power and hydrogen. This four-phase project had intermediate go/no-go decisions and the following specific goals: ?¢???¢ Complete a technical assessment and economic analysis of the use of high-temperature fuel cells, including solid oxide and molten carbonate, for the co-production of power and hydrogen (energy park concept). ?¢???¢ Build on the experience gained at the Las Vegas H2 Energy Station and compare/contrast the two approaches for co-production. ?¢???¢ Determine the applicability of co-production from a high-temperature fuel cell for the existing merchant hydrogen market and for the emerging hydrogen economy. ?¢???¢ Demonstrate the concept on natural gas for six months at a suitable site with demand for both hydrogen and electricity. ?¢???¢ Maintain safety as the top priority in the system design and operation. ?¢???¢ Obtain adequate operational data to provide the basis for future commercial activities, including hydrogen fueling stations. Work began with the execution of the cooperative agreement with DOE on 30 September 2001. During Phase 1, Air Products identified high-temperature fuel cells as having the potential to meet the coproduction targets, and the molten carbonate fuel cell system from FuelCell Energy, Inc. (FuelCell Energy) was selected by Air Products and DOE following the feasibility assessment performed during Phase 2. Detailed design, construction and shop validation testing of a system to produce 250 kW of electricity and 100 kilograms per day of hydrogen, along with site selection to include a renewable feedstock for the fuel cell, were completed in Phase 3. The system also completed six months of demonstration operation at the wastewater treatment facility operated by Orange County Sanitation District (OCSD, Fountain Valley, CA). As part of achieving the objective of operating on a renewable feedstock, Air Products secured additional funding via an award from the California Air Resources Board. The South Coast Air Quality Management District also provided cost share which supported the objectives of this project. System operation at OCSD confirmed the results from shop validation testing performed during Phase 3. Hydrogen was produced at rates and purity that met the targets from the system design basis, and coproduction efficiency exceeded the 50% target set in conjunction with input from the DOE. Hydrogen production economics, updated from the Phase 2 analysis, showed pricing of $5 to $6 per kilogram of hydrogen using current gas purification systems. Hydrogen costs under $3 per kilogram are achievable if next-generation electrochemical separation technologies become available.

  15. Hydrogen vehicle fueling station

    SciTech Connect (OSTI)

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A.; Prenger, F.C.; Hill, D.D.

    1995-09-01T23:59:59.000Z

    The authors describe a hydrogen vehicle fueling station that receives and stores hydrogen in liquid form and dispenses it either as a liquid or compressed gas. The economics that accrue from the favorable weight and volume advantages of liquid hydrogen support this concept both now and probably for some time to come. The model for liquid transfer to a 120-liter vehicle tank shows that transfer times under five minutes are feasible with pump-assisted transfer, or for pressure transfer with subcooling greater than 1 K. The model for compressed gas transfer shows that underfilling of nearly 30% can occur during rapid filling. Cooling the fill gas to 214 K completely eliminates underfilling.

  16. The JET Hydrogen-Oxygen Recombination Sensor A Safety Device for Hydrogen Isotope Processing Systems

    E-Print Network [OSTI]

    The JET Hydrogen-Oxygen Recombination Sensor A Safety Device for Hydrogen Isotope Processing Systems

  17. Hydrogen Storage -Overview George Thomas, Hydrogen Consultant to SNL*

    E-Print Network [OSTI]

    aspects of hydrogen utilization. production distribution utilization How do we achieve safe, efficient Forecourt storage (refueling stations) requirements being developed (IHIG) Distribution storage (delivery 75 100 125 hydrogen m ethane ethane propane butane pentane hexane heptane octane (gasoline) cetane

  18. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W.

    2008-09-30T23:59:59.000Z

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: Magnesium hydride slurry is stable for months and pumpable. The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (Milk of Magnesia) and magnesium oxide. We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

  19. Hawaii hydrogen power park Hawaii Hydrogen Power Park

    E-Print Network [OSTI]

    energy source. (Barrier V-Renewable Integration) Hydrogen storage & distribution system. (Barrier V Vent AC Power Reformer Low Pressure H2 Storage Propane Hydrogen Optional Reformer System Optional Wind. Low pressure hydrogen storage utilizing propane tanks. High pressure storage using lightweight

  20. Oxidation resistant organic hydrogen getters

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Buffleben, George M. (Tracy, CA)

    2008-09-09T23:59:59.000Z

    A composition for removing hydrogen from an atmosphere, comprising a mixture of a polyphenyl ether and a hydrogenation catalyst, preferably a precious metal catalyst, and most preferably Pt. This composition is stable in the presence of oxygen, will not polymerize or degrade upon exposure to temperatures in excess of 200.degree. C., or prolonged exposure to temperatures in the range of 100-300.degree. C. Moreover, these novel hydrogen getter materials can be used to efficiently removing hydrogen from mixtures of hydrogen/inert gas (e.g., He, Ar, N.sub.2), hydrogen/ammonia atmospheres, such as may be encountered in heat exchangers, and hydrogen/carbon dioxide atmospheres. Water vapor and common atmospheric gases have no adverse effect on the ability of these getter materials to absorb hydrogen.

  1. Sandia National Laboratories: Hydrogen Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Behavior Protected: Hydrogen and Fuel Cells Program On April 28, 2014, in There is no excerpt because this is a protected post. Hydrogen and Fuel Cells Program On November 9, 2010,...

  2. Hydrogen,Fuel Cells & Infrastructure

    E-Print Network [OSTI]

    ;The President's FY04 Budget Request for FreedomCAR and Hydrogen Fuel Initiatives 4.0Office of Nuclear commercialization decision by 2015. Fuel Cell Vehicles in the Showroom and Hydrogen at Fueling Stations by 2020 #12

  3. Hydrogen Distribution and Delivery Infrastructure

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen delivery technologies. Intended for a non-technical audience, it explains how hydrogen is transported and delivered today, the challen

  4. Hydrogen Delivery Options and Issues

    Broader source: Energy.gov (indexed) [DOE]

    stationary power site - GH2 Pipelines and Trucks, LH2 Trucks, Carriers <1.00kg of Hydrogen by 2017 Hydrogen Delivery H2 Delivery Current Status * Technology - GH2 Tube...

  5. Wind-To-Hydrogen Project: Electrolyzer Capital Cost Study

    SciTech Connect (OSTI)

    Saur, G.

    2008-12-01T23:59:59.000Z

    This study is being performed as part of the U.S. Department of Energy and Xcel Energy's Wind-to-Hydrogen Project (Wind2H2) at the National Renewable Energy Laboratory. The general aim of the project is to identify areas for improving the production of hydrogen from renewable energy sources. These areas include both technical development and cost analysis of systems that convert renewable energy to hydrogen via water electrolysis. Increased efficiency and reduced cost will bring about greater market penetration for hydrogen production and application. There are different issues for isolated versus grid-connected systems, however, and these issues must be considered. The manner in which hydrogen production is integrated in the larger energy system will determine its cost feasibility and energy efficiency.

  6. Webinar: Hydrogen Storage Materials Requirements

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Hydrogen Storage Materials Requirements, originally presented on June 25, 2013.

  7. Resistive hydrogen sensing element

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN)

    2000-01-01T23:59:59.000Z

    Systems and methods are described for providing a hydrogen sensing element with a more robust exposed metallization by application of a discontinuous or porous overlay to hold the metallization firmly on the substrate. An apparatus includes: a substantially inert, electrically-insulating substrate; a first Pd containing metallization deposited upon the substrate and completely covered by a substantially hydrogen-impermeable layer so as to form a reference resistor on the substrate; a second Pd containing metallization deposited upon the substrate and at least a partially accessible to a gas to be tested, so as to form a hydrogen-sensing resistor; a protective structure disposed upon at least a portion of the second Pd containing metallization and at least a portion of the substrate to improve the attachment of the second Pd containing metallization to the substrate while allowing the gas to contact said the second Pd containing metallization; and a resistance bridge circuit coupled to both the first and second Pd containing metallizations. The circuit determines the difference in electrical resistance between the first and second Pd containing metallizations. The hydrogen concentration in the gas may be determined. The systems and methods provide advantages because adhesion is improved without adversely effecting measurement speed or sensitivity.

  8. Hydrogen isotope separation

    DOE Patents [OSTI]

    Bartlit, John R. (Los Alamos, NM); Denton, William H. (Abingdon, GB3); Sherman, Robert H. (Los Alamos, NM)

    1982-01-01T23:59:59.000Z

    A system of four cryogenic fractional distillation columns interlinked with two equilibrators for separating a DT and hydrogen feed stream into four product streams, consisting of a stream of high purity D.sub.2, DT, T.sub.2, and a tritium-free stream of HD for waste disposal.

  9. Hydrogen, Fuel Infrastructure

    E-Print Network [OSTI]

    be powered by hydrogen, and pollution-free." "Join me in this important innovation to make our air for the foreseeable future. Even with the significant energy efficiency benefits that gasoline- electric hybrid - fossil fuels like natural gas and coal; renewable energy sources such as solar radiation, wind

  10. California Hydrogen Infrastructure Project

    SciTech Connect (OSTI)

    Edward C. Heydorn

    2013-03-12T23:59:59.000Z

    Air Products and Chemicals, Inc. has completed a comprehensive, multiyear project to demonstrate a hydrogen infrastructure in California. The specific primary objective of the project was to demonstrate a model of a ???¢????????real-world???¢??????? retail hydrogen infrastructure and acquire sufficient data within the project to assess the feasibility of achieving the nation???¢????????s hydrogen infrastructure goals. The project helped to advance hydrogen station technology, including the vehicle-to-station fueling interface, through consumer experiences and feedback. By encompassing a variety of fuel cell vehicles, customer profiles and fueling experiences, this project was able to obtain a complete portrait of real market needs. The project also opened its stations to other qualified vehicle providers at the appropriate time to promote widespread use and gain even broader public understanding of a hydrogen infrastructure. The project engaged major energy companies to provide a fueling experience similar to traditional gasoline station sites to foster public acceptance of hydrogen. Work over the course of the project was focused in multiple areas. With respect to the equipment needed, technical design specifications (including both safety and operational considerations) were written, reviewed, and finalized. After finalizing individual equipment designs, complete station designs were started including process flow diagrams and systems safety reviews. Material quotes were obtained, and in some cases, depending on the project status and the lead time, equipment was placed on order and fabrication began. Consideration was given for expected vehicle usage and station capacity, standard features needed, and the ability to upgrade the station at a later date. In parallel with work on the equipment, discussions were started with various vehicle manufacturers to identify vehicle demand (short- and long-term needs). Discussions included identifying potential areas most suited for hydrogen fueling stations with a focus on safe, convenient, fast-fills. These potential areas were then compared to and overlaid with suitable sites from various energy companies and other potential station operators. Work continues to match vehicle needs with suitable fueling station locations. Once a specific site was identified, the necessary agreements could be completed with the station operator and expected station users. Detailed work could then begin on the site drawings, permits, safety procedures and training needs. Permanent stations were successfully installed in Irvine (delivered liquid hydrogen), Torrance (delivered pipeline hydrogen) and Fountain Valley (renewable hydrogen from anaerobic digester gas). Mobile fueling stations were also deployed to meet short-term fueling needs in Long Beach and Placerville. Once these stations were brought online, infrastructure data was collected and reported to DOE using Air Products???¢???????? Enterprise Remote Access Monitoring system. Feedback from station operators was incorporated to improve the station user???¢????????s fueling experience.

  11. Detroit Commuter Hydrogen Project

    SciTech Connect (OSTI)

    Brooks, Jerry; Prebo, Brendan

    2010-07-31T23:59:59.000Z

    This project was undertaken to demonstrate the viability of using hydrogen as a fuel in an internal combustion engine vehicle for use as a part of a mass transit system. The advantages of hydrogen as a fuel include renew-ability, minimal environmental impact on air quality and the environment, and potential to reduce dependence on foreign energy sources for the transportation sector. Recognizing the potential for the hydrogen fuel concept, the Southeast Michigan Congress of Governments (SEMCOG) determined to consider it in the study of a proposed regional mass transit rail system for southeast Michigan. SEMCOG wanted to evaluate the feasibility of using hydrogen fueled internal combustion engine (H2ICE) vehicles in shuttle buses to connect the Detroit Metro Airport to a proposed, nearby rail station. Shuttle buses are in current use on the airport for passenger parking and inter-terminal transport. This duty cycle is well suited to the application of hydrogen fuel at this time because of the ability to re-fuel vehicles at a single nearby facility, overcoming the challenge of restricted fuel availability in the undeveloped hydrogen fuel infrastructure. A cooperative agreement between SEMCOG and the DOE was initiated and two H2ICE buses were placed in regular passenger service on March 29, 2009 and operated for six months in regular passenger service. The buses were developed and built by the Ford Motor Company. Wayne County Airport Authority provided the location for the demonstration with the airport transportation contractor, Metro Cars Inc. operating the buses. The buses were built on Ford E450 chassis and incorporated a modified a 6.8L V-10 engine with specially designed supercharger, fuel rails and injectors among other sophisticated control systems. Up to 30 kg of on-board gaseous hydrogen were stored in a modular six tank, 350 bar (5000 psi) system to provide a 150 mile driving range. The bus chassis and body were configured to carry nine passengers with luggage. By collecting fuel use data for the two H2ICE buses, with both written driver logs and onboard telemetry devices, and for two conventional propane-gasoline powered buses in the same service, comparisons of operating efficiency and maintenance requirements were completed. Public opinion about the concept of hydrogen fuel was sampled with a rider survey throughout the demonstration. The demonstration was very effective in adding to the understanding of the application of hydrogen as a transportation fuel. The two 9 passenger H2ICE buses accumulated nearly 50,000 miles and carried 14,285 passengers. Data indicated the H2ICE bus fuel economy to be 9.4 miles/ gallon of gasoline equivalent (m/GGE) compared to the 10 passenger propane-gasoline bus average of 9.8 m/GGE over 32,400 miles. The 23- passenger bus averaged 7.4 m/GGE over 40,700 miles. Rider feedback from 1050 on-board survey cards was overwhelmingly positive with 99.6% indicating they would ride again on a hydrogen powered vehicle. Minimal maintenance was required for theses buses during the demonstration project, but a longer duration demonstration would be required to more adequately assess this aspect of the concept.

  12. Hydrogen Piping Experience in Chevron

    E-Print Network [OSTI]

    Hydrogen Piping Experience in Chevron Refining Ned Niccolls Materials Engineer Chevron Energy Technology Company Hydrogen Pipeline Working Group Workshop August 30-31, 2005 #12;Outline 2 Overall perspectives from long term use of hydrogen piping in refining. Piping specifications and practices. The (few

  13. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    in combustion engines, or converted into hydrogen at fuelengines are now nearly zero-emitting. What do these lessons imply for hydrogen?Hydrogen will find it difficult to compete with the century-long investment in petroleum fuels and internal combustion engines.

  14. Proceedings NATIONAL HYDROGEN VISION MEETING

    E-Print Network [OSTI]

    's Plan directs us to explore the possibility of a hydrogen economy..." Spencer Abraham, Secretary be found at the end of this document.) The intent was to identify a common vision of a "hydrogen economy of the Group: Which factors are most likely to support/inhibit the development of a "hydrogen economy

  15. January 2005 HYDROGEN EMBRITTLEMENT OF

    E-Print Network [OSTI]

    1 January 2005 HYDROGEN EMBRITTLEMENT OF PIPELINE STEELS: CAUSES AND REMEDIATION P. Sofronis, I. Robertson, D. Johnson University of Illinois at Urbana-Champaign Hydrogen Pipeline R&D Project Review Meeting Oak Ridge National Laboratory, Oak Ridge TN January 5-6, 2005 #12;2 January 2005 Hydrogen

  16. Composites Technology for Hydrogen Pipelines

    E-Print Network [OSTI]

    Composites Technology for Hydrogen Pipelines Barton Smith, Barbara Frame, Larry Anovitz and Cliff;Composites Technology for Hydrogen Pipelines Fiber-reinforced polymer pipe Project Overview: Investigate of pipeline per day. · $190k/mile capital cost for distribution pipelines · Hydrogen delivery cost below $1

  17. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

    1993-01-01T23:59:59.000Z

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  18. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18T23:59:59.000Z

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  19. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Energy Savers [EERE]

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop: Agenda and Objectives Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop:...

  20. Ultraviolet stimulation of hydrogen peroxide production using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultraviolet stimulation of hydrogen peroxide production using aminoindazole, diaminopyridine, and phenylenediamine solid polymer Ultraviolet stimulation of hydrogen peroxide...

  1. Controlled Hydrogen Fleet and Infrastructure Demonstration and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project Solicitation Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project...

  2. Controlled Hydrogen Fleet and Infrastructure Demonstration and...

    Office of Environmental Management (EM)

    Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project 2009 DOE...

  3. Solar Thermochemical Hydrogen Production Research (STCH): Thermochemic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Thermochemical Hydrogen Production Research (STCH): Thermochemical Cycle Selection and Investment Priority Solar Thermochemical Hydrogen Production Research (STCH):...

  4. Autofermentative Biological Hydrogen Production by Cyanobacteria...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Autofermentative Biological Hydrogen Production by Cyanobacteria Autofermentative Biological Hydrogen Production by Cyanobacteria Presentation by Charles Dismukes, Rutgers...

  5. A Photosynthetic Hydrogel for Catalytic Hydrogen Production ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production...

  6. Hydrogenases and Barriers for Biotechnological Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogenases and Barriers for Biotechnological Hydrogen Production Technologies Hydrogenases and Barriers for Biotechnological Hydrogen Production Technologies Presentation by John...

  7. Combinatorial Approaches for Hydrogen Storage Materials (presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Approaches for Hydrogen Storage Materials (presentation) Combinatorial Approaches for Hydrogen Storage Materials (presentation) Presentation on NIST Combinatorial Methods at the...

  8. Hydrogen Infrastructure Market Readiness Workshop: Preliminary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop: Preliminary Results Hydrogen Infrastructure Market Readiness Workshop: Preliminary Results Preliminary results from the Hydrogen Infrastructure Market Readiness Workshop...

  9. Upcoming Webinar December 16: International Hydrogen Infrastructure...

    Energy Savers [EERE]

    Upcoming Webinar December 16: International Hydrogen Infrastructure Challenges NOW, DOE, and NEDO Upcoming Webinar December 16: International Hydrogen Infrastructure Challenges...

  10. PURIWG Meeting: DOE Hydrogen Quality Working Group

    E-Print Network [OSTI]

    ) production by reforming of natural gas (ATR & SMR) reforming of renewable fuels, e.g., ethanol (i.e., E are being developed to support the H2A Argonne is modeling a steam reformer + PSA process Results

  11. Solid evacuated microspheres of hydrogen

    DOE Patents [OSTI]

    Turnbull, Robert J. (Urbana, IL); Foster, Christopher A. (Champaign, IL); Hendricks, Charles D. (Livermore, CA)

    1982-01-01T23:59:59.000Z

    A method is provided for producing solid, evacuated microspheres comprised of hydrogen. The spheres are produced by forming a jet of liquid hydrogen and exciting mechanical waves on the jet of appropriate frequency so that the jet breaks up into drops with a bubble formed in each drop by cavitation. The drops are exposed to a pressure less than the vapor pressure of the liquid hydrogen so that the bubble which is formed within each drop expands. The drops which contain bubbles are exposed to an environment having a pressure just below the triple point of liquid hydrogen and they thereby freeze giving solid, evacuated spheres of hydrogen.

  12. A smooth transition to hydrogen transportation fuel

    SciTech Connect (OSTI)

    Berry, G.D.; Smith, J.R.; Schock, R.N.

    1995-04-14T23:59:59.000Z

    The goal of this work is to examine viable near-term infrastructure options for a transition to hydrogen fueled vehicles and to suggest profitable directions for technology development. The authors have focused in particular on the contrasting options of decentralized production using the existing energy distribution network, and centralized production of hydrogen with a large-scale infrastructure. Delivered costs have been estimated using best available industry cost and deliberately conservative economic assumptions. The sensitivities of these costs have then been examined for three small-scale scenarios: (1) electrolysis at the home for one car, and production at the small station scale (300 cars/day), (2) conventional alkaline electrolysis and (3) steam reforming of natural gas. All scenarios assume fueling a 300 mile range vehicle with 3.75 kg. They conclude that a transition appears plausible, using existing energy distribution systems, with home electrolysis providing fuel costing 7.5 to 10.5{cents}/mile, station electrolysis 4.7 to 7.1{cents}/mile, and steam reforming 3.7 to 4.7{cents}/mile. The average car today costs about 6{cents}/mile to fuel. Furthermore, analysis of liquid hydrogen delivered locally by truck from central processing plants can also be competitive at costs as low as 4{cents}/mile. These delivered costs are equal to $30 to $70 per GJ, LHV. Preliminary analysis indicates that electricity transmission costs favor this method of distributing energy, until very large (10 GW) hydrogen pipelines are installed. This indicates that significant hydrogen pipeline distribution will be established only when significant markets have developed.

  13. Energy level displacement of excited np states of kaonic hydrogen

    E-Print Network [OSTI]

    A. N. Ivanov; M. Cargnelli; M. Faber; H. Fuhrmann; V. A. Ivanova; J. Marton; N. I. Troitskaya; J. Zmeskal

    2005-04-09T23:59:59.000Z

    We compute the energy level displacement of the excited np states of kaonic hydrogen within the quantum field theoretic and relativistic covariant model of strong low-energy bar-KN interactions suggested in EPJA21, 11 (2004). For the width of the energy level of the excited 2p state of kaonic hydrogen, caused by strong low-energy interactions, we find Gamma_2p = 2 meV. This result is important for the theoretical analysis of the X-ray yields in kaonic hydrogen.

  14. Polymer system for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy Jon (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Whinnery, LeRoy L. (4929 Julie St., Livermore, Alameda County, CA 94550)

    2000-01-01T23:59:59.000Z

    A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

  15. Geothermal hydrogen sulfide removal

    SciTech Connect (OSTI)

    Urban, P.

    1981-04-01T23:59:59.000Z

    UOP Sulfox technology successfully removed 500 ppM hydrogen sulfide from simulated mixed phase geothermal waters. The Sulfox process involves air oxidation of hydrogen sulfide using a fixed catalyst bed. The catalyst activity remained stable throughout the life of the program. The product stream composition was selected by controlling pH; low pH favored elemental sulfur, while high pH favored water soluble sulfate and thiosulfate. Operation with liquid water present assured full catalytic activity. Dissolved salts reduced catalyst activity somewhat. Application of Sulfox technology to geothermal waters resulted in a straightforward process. There were no requirements for auxiliary processes such as a chemical plant. Application of the process to various types of geothermal waters is discussed and plans for a field test pilot plant and a schedule for commercialization are outlined.

  16. Reversible hydrogen storage materials

    DOE Patents [OSTI]

    Ritter, James A. (Lexington, SC); Wang, Tao (Columbia, SC); Ebner, Armin D. (Lexington, SC); Holland, Charles E. (Cayce, SC)

    2012-04-10T23:59:59.000Z

    In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

  17. Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy

    E-Print Network [OSTI]

    Lipman, Timothy; Brooks, Cameron

    2006-01-01T23:59:59.000Z

    Other State Hydrogen and Fuel Cell Programs Regional Levelrelated to hydrogen and fuel cell tech- nologies. Otherapplications of hydrogen and fuel cell technologies. They

  18. Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy

    E-Print Network [OSTI]

    Lipman, Timothy; Brooks, Cameron

    2006-01-01T23:59:59.000Z

    Cell Deployment and Hydrogen Infrastructure, Worldwide Web,of deploying hydrogen infrastructure. stream of hydrogenfeasibility of a hydrogen infrastructure is enhanced by

  19. DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    9017: On-Board Hydrogen Storage Systems - Projected Performance and Cost Parameters DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen Storage Systems - Projected...

  20. Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy

    E-Print Network [OSTI]

    Lipman, Timothy; Brooks, Cameron

    2006-01-01T23:59:59.000Z

    Electricity, Hydrogen, and Thermal Energy Timothy E. LipmanElectricity, Hydrogen, and Thermal Energy Timothy E. Lipmanof electricity, hydrogen, and thermal energy; 2) a survey of

  1. Hydrogen Fuel Pilot Plant and Hydrogen ICE Vehicle Testing

    SciTech Connect (OSTI)

    J. Francfort (INEEL)

    2005-03-01T23:59:59.000Z

    The U.S. Department Energy's Advanced Vehicle Testing Activity (AVTA) teamed with Electric Transportation Applications (ETA) and Arizona Public Service (APS) to develop the APS Alternative Fuel (Hydrogen) Pilot Plant that produces and compresses hydrogen on site through an electrolysis process by operating a PEM fuel cell in reverse; natural gas is also compressed onsite. The Pilot Plant dispenses 100% hydrogen, 15 to 50% blends of hydrogen and compressed natural gas (H/CNG), and 100% CNG via a credit card billing system at pressures up to 5,000 psi. Thirty internal combustion engine (ICE) vehicles (including Daimler Chrysler, Ford and General Motors vehicles) are operating on 100% hydrogen and 15 to 50% H/CNG blends. Since the Pilot Plant started operating in June 2002, they hydrogen and H/CNG ICE vehicels have accumulated 250,000 test miles.

  2. DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program Integrated Hydrogen Production, Purification and Compression System

    SciTech Connect (OSTI)

    Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

    2011-06-30T23:59:59.000Z

    The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of <$1.50/gge, which was later revised by DOE to $2-$3/gge range for hydrogen to be competitive with gasoline as a fuel for vehicles. For small, on-site hydrogen plants being evaluated at the time for refueling stations (the 'forecourt'), it was determined that capital cost is the main contributor to the high cost of delivered hydrogen. The concept of this project was to reduce the cost by combining unit operations for the entire generation, purification, and compression system (refer to Figure 1). To accomplish this, the Fluid Bed Membrane Reactor (FBMR) developed by MRT was used. The FBMR has hydrogen selective, palladium-alloy membrane modules immersed in the reformer vessel, thereby directly producing high purity hydrogen in a single step. The continuous removal of pure hydrogen from the reformer pushes the equilibrium 'forward', thereby maximizing the productivity with an associated reduction in the cost of product hydrogen. Additional gains were envisaged by the integration of the novel Metal Hydride Hydrogen Compressor (MHC) developed by Ergenics, which compresses hydrogen from 0.5 bar (7 psia) to 350 bar (5,076 psia) or higher in a single unit using thermal energy. Excess energy from the reformer provides up to 25% of the power used for driving the hydride compressor so that system integration improved efficiency. Hydrogen from the membrane reformer is of very high, fuel cell vehicle (FCV) quality (purity over 99.99%), eliminating the need for a separate purification step. The hydride compressor maintains hydrogen purity because it does not have dynamic seals or lubricating oil. The project team set out to integrate the membrane reformer developed by MRT and the hydride compression system developed by Ergenics in a single package. This was expected to result in lower cost and higher efficiency compared to conventional hydrogen production technologies. The overall objective was to develop an integrated system to directly produce high pressure, high-purity hydrogen from a single unit, which can meet the DOE cost H2 cost target of $2 - $3/gge when mass produced. The project was divided into two phases with the following tasks and corresponding milestones, targets and decision points. Phase 1 - Task 1 - Verify feasibility of the concept, perform a detailed techno-economic analysis, and develop a test plan; and Task 2: Build and experimentally test a Proof of Concept (POC) integrated membrane reformer/metal hydride compressor system. Phase 2 - Task 3: Build an Advanced Prototype (AP) system with modifications based on POC learning and demonstrate at a commercial site; and Task 4: Complete final product design for mass manufacturing units capable of achieving DOE 2010 H2 cost and performance targets.

  3. Development of a Turnkey Hydrogen Fueling Station Final Report

    SciTech Connect (OSTI)

    David E. Guro; Edward Kiczek; Kendral Gill; Othniel Brown

    2010-07-29T23:59:59.000Z

    The transition to hydrogen as a fuel source presents several challenges. One of the major hurdles is the cost-effective production of hydrogen in small quantities (less than 1MMscf/month). In the early demonstration phase, hydrogen can be provided by bulk distribution of liquid or compressed gas from central production plants; however, the next phase to fostering the hydrogen economy will likely include onsite generation and extensive pipeline networks to help effect a pervasive infrastructure. Providing inexpensive hydrogen at a fleet operators garage or local fueling station is a key enabling technology for direct hydrogen Fuel Cell Vehicles (FCVs). The objective of this project was to develop a comprehensive, turnkey, stand-alone, commercial hydrogen fueling station for FCVs with state-of-the-art technology that is cost-competitive with current hydrocarbon fuels. Such a station would promote the advent of the hydrogen fuel economy for buses, fleet vehicles, and ultimately personal vehicles. Air Products, partnering with the U.S. Department of Energy (DOE), The Pennsylvania State University, Harvest Energy Technology, and QuestAir, developed a turnkey hydrogen fueling station on the Penn State campus. Air Products aimed at designing a station that would have 65% overall station efficiency, 82% PSA (pressure swing adsorption) efficiency, and the capability of producing hydrogen at $3.00/kg (gge) H2 at mass production rates. Air Products designed a fueling station at Penn State from the ground up. This project was implemented in three phases. The first phase evaluated the various technologies available in hydrogen generation, compression, storage, and gas dispensing. In the second phase, Air Products designed the components chosen from the technologies examined. Finally, phase three entailed a several-month period of data collection, full-scale operation, maintenance of the station, and optimization of system reliability and performance. Based on field data analysis, it was determined by a proprietary hydrogen-analysis model that hydrogen produced from the station at a rate of 1500 kg/day and when produced at 1000 stations per year would be able to deliver hydrogen at a price of $3.03/kg (gge) H2. The stations efficiency was measured to be 65.1%, and the PSA was tested and ran at an efficiency of 82.1%, thus meeting the project targets. From the study, it was determined that more research was needed in the area of hydrogen fueling. The overall cost of the hydrogen energy station, when combined with the required plot size for scaled-up hydrogen demands, demonstrated that a station using steam methane reforming technology as a means to produce onsite hydrogen would have limited utility in the marketplace. Alternative hydrogen supplies, such as liquid or pipeline delivery to a refueling station, need to be included in the exploration of alternative energy site layouts. These avenues need to be explored before a definitive refueling station configuration and commercialization pathway can be determined.

  4. Integrated Ceramic Membrane System for Hydrogen Production

    SciTech Connect (OSTI)

    Schwartz, Joseph; Lim, Hankwon; Drnevich, Raymond

    2010-08-05T23:59:59.000Z

    Phase I was a technoeconomic feasibility study that defined the process scheme for the integrated ceramic membrane system for hydrogen production and determined the plan for Phase II. The hydrogen production system is comprised of an oxygen transport membrane (OTM) and a hydrogen transport membrane (HTM). Two process options were evaluated: 1) Integrated OTM-HTM reactor in this configuration, the HTM was a ceramic proton conductor operating at temperatures up to 900C, and 2) Sequential OTM and HTM reactors in this configuration, the HTM was assumed to be a Pd alloy operating at less than 600C. The analysis suggested that there are no technical issues related to either system that cannot be managed. The process with the sequential reactors was found to be more efficient, less expensive, and more likely to be commercialized in a shorter time than the single reactor. Therefore, Phase II focused on the sequential reactor system, specifically, the second stage, or the HTM portion. Work on the OTM portion was conducted in a separate program. Phase IIA began in February 2003. Candidate substrate materials and alloys were identified and porous ceramic tubes were produced and coated with Pd. Much effort was made to develop porous substrates with reasonable pore sizes suitable for Pd alloy coating. The second generation of tubes showed some improvement in pore size control, but this was not enough to get a viable membrane. Further improvements were made to the porous ceramic tube manufacturing process. When a support tube was successfully coated, the membrane was tested to determine the hydrogen flux. The results from all these tests were used to update the technoeconomic analysis from Phase I to confirm that the sequential membrane reactor system can potentially be a low-cost hydrogen supply option when using an existing membrane on a larger scale. Phase IIB began in October 2004 and focused on demonstrating an integrated HTM/water gas shift (WGS) reactor to increase CO conversion and produce more hydrogen than a standard water gas shift reactor would. Substantial improvements in substrate and membrane performance were achieved in another DOE project (DE-FC26-07NT43054). These improved membranes were used for testing in a water gas shift environment in this program. The amount of net H2 generated (defined as the difference of hydrogen produced and fed) was greater than would be produced at equilibrium using conventional water gas shift reactors up to 75 psig because of the shift in equilibrium caused by continuous hydrogen removal. However, methanation happened at higher pressures, 100 and 125 psig, and resulted in less net H2 generated than would be expected by equilibrium conversion alone. An effort to avoid methanation by testing in more oxidizing conditions (by increasing CO2/CO ratio in a feed gas) was successful and net H2 generated was higher (40-60%) than a conventional reactor at equilibrium at all pressures tested (up to 125 psig). A model was developed to predict reactor performance in both cases with and without methanation. The required membrane area depends on conditions, but the required membrane area is about 10 ft2 to produce about 2000 scfh of hydrogen. The maximum amount of hydrogen that can be produced in a membrane reactor decreased significantly due to methanation from about 2600 scfh to about 2400 scfh. Therefore, it is critical to eliminate methanation to fully benefit from the use of a membrane in the reaction. Other modeling work showed that operating a membrane reactor at higher temperature provides an opportunity to make the reactor smaller and potentially provides a significant capital cost savings compared to a shift reactor/PSA combination.

  5. Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmission and Distribution Workshop American Society of Mechanical EngineersSavannah River National Laboratory (ASMESRNL) Materials and Components for Hydrogen Infrastructure...

  6. DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold...

    Broader source: Energy.gov (indexed) [DOE]

    vehicles) in 2020. This record from the U.S. Department of Energy Hydrogen and Fuel Cells Program documents the methodology and assumptions used to calculate that...

  7. Hydrogen Supply: Cost Estimate for Hydrogen Pathways?Scoping...

    Broader source: Energy.gov (indexed) [DOE]

    Central Methanol Methanol Forecourt Gasoline Gasoline Forecourt H 2 from ethylene or refinery Residuepitch Central The by-product source of hydrogen defined by IHIG in the...

  8. Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN. Citation: Shokri A, Y Wang, GA...

  9. amide hydrogen exchange: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Economics of Hydrogen Technologies Renewable Energy Websites Summary: Internal Combustion Engine Transportation Applications Hydrogen Fuel Cell Vehicles Hydrogen Internal Power...

  10. ammonium hydrogen carbonate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Economics of Hydrogen Technologies Renewable Energy Websites Summary: Internal Combustion Engine Transportation Applications Hydrogen Fuel Cell Vehicles Hydrogen Internal Power...

  11. Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design

    E-Print Network [OSTI]

    Ogden, Joan M; Yang, Christopher

    2005-01-01T23:59:59.000Z

    Natural Gas Based Hydrogen Infrastructure Optimizingdevelopment of a hydrogen infrastructure has been identifiedrecent studies of hydrogen infrastructure have assessed

  12. Hydrogen ICE Vehicle Testing Activities

    SciTech Connect (OSTI)

    J. Francfort; D. Karner

    2006-04-01T23:59:59.000Z

    The Advanced Vehicle Testing Activity teamed with Electric Transportation Applications and Arizona Public Service to develop and monitor the operations of the APS Alternative Fuel (Hydrogen) Pilot Plant. The Pilot Plant provides 100% hydrogen, and hydrogen and compressed natural gas (H/CNG)-blended fuels for the evaluation of hydrogen and H/CNG internal combustion engine (ICE) vehicles in controlled and fleet testing environments. Since June 2002, twenty hydrogen and H/CNG vehicles have accumulated 300,000 test miles and 5,700 fueling events. The AVTA is part of the Department of Energys FreedomCAR and Vehicle Technologies Program. These testing activities are managed by the Idaho National Laboratory. This paper discusses the Pilot Plant design and monitoring, and hydrogen ICE vehicle testing methods and results.

  13. Quantum Confinement in Hydrogen Bond

    E-Print Network [OSTI]

    Santos, Carlos da Silva dos; Ricotta, Regina Maria

    2015-01-01T23:59:59.000Z

    In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

  14. Nancy Garland DOE Hydrogen Program

    E-Print Network [OSTI]

    commercialization decision by 2015 Fuel cell vehicles in showroom and hydrogen at fuel stations by 2020 #12;Hydrogen, and distributed combined heat and power applications. #12;DOE Hydrogen Program Budget $544DOT $37,301Earmarks (EE,830$30,000$29,432Storage R&D (EE) $14,363$25,325$22,564Production & Delivery R&D (EE) FY 05 Appropriations* ($000) FY 05

  15. Complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2006-08-22T23:59:59.000Z

    A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50.degree. C. and 90.degree. C.

  16. Determining the lowest-cost hydrogen delivery mode

    E-Print Network [OSTI]

    Yang, Christopher; Ogden, Joan M

    2007-01-01T23:59:59.000Z

    costs to estimate hydrogen pipeline costs. Davis, CA: ITS-hydrogen. The cost of hydrogen pipeline delivery de- pendshydrogen trucks, and hydrogen pipelines, were devel- oped

  17. Determining the lowest-cost hydrogen delivery mode

    E-Print Network [OSTI]

    Yang, Christopher; Ogden, Joan M

    2007-01-01T23:59:59.000Z

    costs to estimate hydrogen pipeline costs. Davis, CA: ITS-hydrogen trucks, and hydrogen pipelines, were devel- opedFor large amounts of hydrogen, pipeline transmission is pre-

  18. Determining the lowest-cost hydrogen delivery mode

    E-Print Network [OSTI]

    Yang, Christopher; Ogden, Joan M

    2007-01-01T23:59:59.000Z

    current lack of hydrogen infrastructure. Hydrogen fuel isof developing hydrogen infrastructure systems. This analysisa refueling infrastructure for hydrogen vehicles: a southern

  19. Determining the Lowest-Cost Hydrogen Delivery Mode

    E-Print Network [OSTI]

    Yang, Christopher; Ogden, Joan M

    2008-01-01T23:59:59.000Z

    current lack of hydrogen infrastructure. Hydrogen fuel isof developing hydrogen infrastructure systems. This analysisa Refueling Infrastructure for Hydrogen Vehicles: A Southern

  20. Sandia National Laboratories: hydrogen storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    storage Energy Department Awards 7M to Advance Hydrogen Storage Systems On June 12, 2014, in CRF, Energy, Energy Storage, Energy Storage Systems, Facilities, Infrastructure...