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Note: This page contains sample records for the topic "hydrofluorocarbons hfcs perfluorocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


The greenhouse gases HFCs, PFCs Danish consumption and emissions, 2007  

E-Print Network (OSTI)

The greenhouse gases HFCs, PFCs and SF6 Danish consumption and emissions, 2007 Tomas Sander Poulsen AND EMISSION OF F-GASES 7 1.1.1 Consumption 7 1.1.2 Emission 7 1.1.3 Trends in total GWP contribution from F 21 4 EMISSION OF F-GASES 23 4.1.1 Emissions of HFCs from refrigerants 23 4.1.2 Emissions of HFCs from


Perfluorocarbons in the global atmosphere: tetrafluoromethane, hexafluoroethane, and octafluoropropane  

E-Print Network (OSTI)

We present atmospheric baseline growth rates from the 1970s to the present for the long-lived, strongly infrared-absorbing perfluorocarbons (PFCs) tetrafluoromethane (CF4), hexafluoroethane (C2F6), and octafluoropropane ...

Muhle, J.


Trends and inferred emissions of atmospheric high molecular weight perfluorocarbons  

E-Print Network (OSTI)

Atmospheric observations and atmospheric observation-based global emission estimates are presented for the five high molecular weight perfluorocarbons (PFCs): decafluorobutane (C 4 F 1 0 ), dodecafluoropentane (C5 F1 2 ), ...

Ivy, Diane Jean



Method for enhancing microbial utilization rates of gases using perfluorocarbons  

DOE Patents (OSTI)

A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

Turick, Charles E. (Idaho Falls, ID)



Atmospheric chemistry of hydrofluorocarbon 134a. Fate of the alkoxy radical CF{sub 3}O  

SciTech Connect

The atmospheric chemistry of the alkoxy radical CF{sub 3}O produced in the photooxidation of hydrofluorocarbon (HFC) 134a has been investigated using Fourier transform infrared spectroscopy. CF{sub 3}O radicals are shown to react with methane and CF{sub 3}CFH{sub 2} to give CF{sub 3}OH. CF{sub 3}OH decomposes to give COF{sub 2} and HF. The rate constant for the reaction CF{sub 3}O + CF{sub 3}CFH{sub 2} (HFC-134a) {r_arrow} CF{sub 3}OH + CF{sub 3}CFH was determined to be k{sup 19} = (1.1 {plus_minus} 0.7) x 10{sup -15} cm{sup 3} molecule{sup -1}s{sup -1} at 297 K. The implications of our results for the atmospheric chemistry of CF{sub 3}O radicals and HFC-134a are discussed. 26 refs., 4 figs., 2 tabs.

Sehested, J. [Riso National Lab. (Denmark); Wallington, T.J. [Ford Motor Company, Dearborn, MI (United States)



EIA - Greenhouse Gas Emissions - High-GWP gases  

Gasoline and Diesel Fuel Update (EIA)

5. High-GWP gases 5. High-GWP gases 5.1. Total emissions Greenhouse gases with high global warming potential (high-GWP gases) are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which together represented 3 percent of U.S. greenhouse gas emissions in 2009. Emissions estimates for the high-GWP gases are provided to EIA by the EPA's Office of Air and Radiation. The estimates for emissions of HFCs not related to industrial processes or electric transmission are derived from the EPA Vintaging Model. Emissions from manufacturing and utilities are derived by the EPA from a mix of public and proprietary data, including from the EPA's voluntary emission reduction partnership programs. For this year's EIA inventory, 2008 values for HFC-23 from HCFC-22



E-Print Network (OSTI)

USING LIDAR TO MEASURE PERFLUOROCARBON TRACERS FOR THE VERIFICATION AND MONITORING OF CAP AND COVER to detect PMCH (perfluoromethylcyclohexane, one of a group of PFTs used at BNL). Laboratory measurements then measured down to 1 ppb-m. These results are very promising and show great potential for monitoring



E-Print Network (OSTI)

of the perfluorocarbons (PFCs) CF4 and C2F6 (1). Owing to the high global warming potentials of these gases (2 that trace levels of CF4 are present in the anode off-gas during #12;periods of normal operation (5

Sadoway, Donald Robert


EIA-Voluntary Reporting of Greenhouse Gases Program - What are...  

U.S. Energy Information Administration (EIA) Indexed Site

gases such as hydrofluorocarbons, perfluorocarbons, and sulfur hexafluoride). The Greenhouse Effect Concentrations of several important greenhouse gases have increased by about 33...


Word Pro - S12  

U.S. Energy Information Administration (EIA) Indexed Site

Note 1. Emissions of Carbon Dioxide and Other Green- Note 1. Emissions of Carbon Dioxide and Other Green- house Gases. Greenhouse gases are those gases-such as water vapor, carbon dioxide (CO 2 ), methane, nitrous oxide, hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride-that are transparent to solar (short- wave) radiation but opaque to long-wave (infrared) radiation, thus preventing long-wave radiant energy from leaving Earth's atmosphere. The net effect is a trapping of absorbed radiation and a tendency to warm the planet's surface. Energy-related carbon dioxide emissions account for about 98 percent of U.S. CO 2 emissions. The vast majority of CO 2 emissions come from fossil fuel combustion, with smaller amounts from the nonfuel use of fossil fuels, as well as from electricity generation using geothermal energy and non-


Using CO2 Lidar for Standoff Detection of a Perfluorocarbon Tracer in Air  

SciTech Connect

The Tag, Track and Location System Program (TTL) is investigating the use of PFTs as tracers for tagging and tracking items of interest or fallen soldiers. In order for the tagging and tracking to be valuable there must be a location system that can detect the PFTs. This report details the development of an infrared lidar platform for standoff detection of PFTs released into the air from a tagged object or person. Furthering work performed using a table top lidar system in an indoor environment; a mobile mini lidar platform was assembled using an existing Raman lidar platform, a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was then successfully demonstrated at an outdoor test. The lidar system was able to detect PFTs released into a vehicle from a distance of 100 meters. In its final, fully optimized configuration the lidar was capable of repeatedly detecting PFTs in the air released from tagged vehicles. Responses were immediate and clear. This report details the results of a proof-of-concept demonstration for standoff detection of a perfluorocarbon tracer (PFT) using infrared lidar. The project is part of the Tag, Track and Location System Program and was performed under a contract with Tracer Detection Technology Corp. with funding from the Office of Naval Research. A lidar capable of detecting PFT releases at distance was assembled by modifying an existing Raman lidar platform by incorporating a grating tunable CO{sub 2} IR laser, Judson HgCdTe detector and miscellaneous folding optics and electronics. The lidar achieved {approx}200 ppb-m sensitivity in laboratory and indoor testing and was successfully demonstrated at an outdoor test. The demonstration test (scripted by the sponsor) consisted of three parked cars, two of which were tagged with the PFT. The cars were located 70 (closest) to 100 meters (farthest) from the lidar (the lidar beam path was limited by site constraints and was {approx}100 meters). When one door of each of the cars was opened (sequentially), the lidar was clearly able to determine which vehicles had been tagged and which one was not. The lidar is probably capable of greater than 0.5 kilometer standoff distances based on the extreme amount of signal return achieved (so much that the system had to be de-tuned). The BNL lidar system, while optimized to the extent possible with available parts and budget, was not as sensitive as it could be. Steps to improve the lidar are detailed in this report and include using a better laser system (for more stable power output), dual wavelengths (to improve the sensitivity and allow common mode noise reduction and to allow the use of the lidar in a scanning configuration), heterodyning (for range resolved PFT detection) and an off-axis optical configuration (for improved near field sensitivity).

Heiser,J.H.; Smith, S.; Sedlacek, A.



Climate Change 2001: The Scientific Basis  

Office of Scientific and Technical Information (OSTI)

Climate Change 2001: Climate Change 2001: Working Group I: The Scientific Basis Get Javascript Other reports in this collection 4. Atmospheric Chemistry and Greenhouse Gases Contents Executive Summary 4.1 Introduction 4.1.1 Sources of Greenhouse Gases 4.1.2 Atmospheric Chemistry and Feedbacks 4.1.3 Trace Gas Budgets and Trends 4.1.4 Atmospheric Lifetimes and Time-Scales 4.2 Trace Gases: Current Observations, Trends and Budgets 4.2.1 Non-CO2 Kyoto Gases Methane (CH4) Nitrous oxide (N2O) Hydrofluorocarbons (HFCs) Perfluorocarbons (PFCs) and sulphur hexafluoride (SF6) 4.2.2 Montreal Protocol Gases and Stratospheric Ozone (O3) 4.2.3 Reactive Gases Carbon monoxide (CO) and hydrogen (H2) Volatile organic compounds (VOC) Nitrogen oxides (NOx)


Honeywell developing low-GWP liquid blowing agent for foam insulation  

Science Journals Connector (OSTI)

Honeywell reports that it is developing a new blowing agent with low global warming potential (GWP) for energy-efficient polyurethane foam insulation. The non-flammable liquid blowing agent will provide customers with an alternative to hydrocarbons and traditional hydrofluorocarbons (HFCs) and assist customers in reducing the overall environmental impact of foam, the company says.



Chapter 10: Biological Impacts of ClimateChange 1.Nature of Climate Change  

E-Print Network (OSTI)

enters the atmosphere through the burning of fossil fuels (oil, natural gas, and coal), solid waste and by the decay of organic waste in municipal solid waste landfills. · Nitrous Oxide (N2O): Nitrous oxide and solid waste. · Fluorinated Gases: Hydrofluorocarbons, perfluorocarbons, and sulfur hexafluoride

Gottgens, Hans


Greenhouse Gas Management Program Overview (Fact Sheet)  

SciTech Connect

Program fact sheet highlighting federal requirements for GHG emissions management, FEMP services to help agencies reduce emissions, and additional resources. The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) assists Federal agencies with managing their greenhouse gas (GHG) emissions. GHG management entails measuring emissions and understanding their sources, setting a goal for reducing emissions, developing a plan to meet this goal, and implementing the plan to achieve reductions in emissions. FEMP provides the following services to help Federal agencies meet the requirements of inventorying and reducing their GHG emissions: (1) FEMP offers one-on-one technical assistance to help agencies understand and implement the Federal Greenhouse Gas Accounting and Reporting Guidance and fulfill their inventory reporting requirements. (2) FEMP provides training, tools, and resources on FedCenter to help agencies complete their annual inventories. (3) FEMP serves a leadership role in the interagency Federal Working Group on Greenhouse Gas Accounting and Reporting that develops recommendations to the Council on Environmental Quality (CEQ) for the Federal Greenhouse Gas Accounting and Reporting Guidance. (4) As the focus continues to shift from measuring emissions (completing inventories) to mitigating emissions (achieving reductions), FEMP is developing a strategic planning framework and resources for agencies to prioritize among a variety of options for mitigating their GHG emissions, so that they achieve their reduction goals in the most cost-effective manner. These resources will help agencies analyze their high-quality inventories to make strategic decisions about where to use limited resources to have the greatest impact on reducing emissions. Greenhouse gases trap heat in the lower atmosphere, warming the earth's surface temperature in a natural process known as the 'greenhouse effect.' GHGs include carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), perfluorocarbons (PFCs), hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF{sub 6}). Human activities have caused a rapid increase in GHG concentrations. This rising level contributes to global climate change, which contributes to environmental and public health problems.

Not Available



Perfluorocarbon Nanoparticles for Molecular Imaging and  

E-Print Network (OSTI)

was confined to the field of nuclear imaging; however, advances in nanotechnology have extended this research computed tomography (SPECT), and ultrasound (US), among others. The application of nanotechnology to MR, G. Lanza, and S. Wickline are with the Department of Medicine, Washington University School

McCarthy, John E.



E-Print Network (OSTI)

National Laboratory, Hanford, Fernald, and Rocky Flats. Barriers are also considered an important reme


Trifluoroacetic acid from degradation of HCFCs and HFCs: A three-dimensional modeling study  

E-Print Network (OSTI)

Diego, Calif. , 1977. Wallington, T. J. , M.D. Hurley, J. C.26, 1318-1324, 1992. Wallington, T. J. , M.D. Hurley, J. M.data reported by Wallington et al. [1996] indicate that the

Kotamarthi, V. R; Rodriguez, J. M; Ko, M. K. W; Tromp, T. K; Sze, N. D; Prather, Michael J



September/October 2006 Out of the Ivory Tower Safety of HFCS GM plants: GM-less Pollen  

E-Print Network (OSTI)

printed in the article was a little more information that I shared on Imperial Valley beekeeping. I also on to say that honey bee colonies survived in Imperial County where temperatures reached 120 degrees F in the Imperial County area, at least one beekeeper said that if they wanted to know what went on in deep

Ferrara, Katherine W.


Towards Elimination of the Anode Effect and Perfluorocarbon Emissions  

E-Print Network (OSTI)

on anode effect Hall-H�roult cell produces CF4 and C2F6 (PFCs) p PFCs have high GWP p in US, Al smelting & Sadoway (1997) r CF4 = a exp (b E ), where b = 0.331 V�1 #12;Sadoway, MIT ECS Meeting, Philadelphia, May

Sadoway, Donald Robert

Note: This page contains sample records for the topic "hydrofluorocarbons hfcs perfluorocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.



E-Print Network (OSTI)

to ground water movement, meteorological water infiltration, vapor- and gas-phase transport, transpiration). Introduction One of the more promising remediation options available to the DOE waste management community contaminant plumes and to restrict remediation methods, such as vacuum extraction, to a limited area


Trends and Inferred Emissions of Atmospheric High Molecular Weight Perfluorocarbons  

E-Print Network (OSTI)

) and octadecafluorooctane (C8F18). Their atmospheric histories are based on measurements of 36 Northern Hemisphere and 468F18. Based on our observations, the 2011 globally averaged dry air mole fractions of these high12, 0.27 ppt for C6F14, 0.12 ppt for C7F16 and 0.09 ppt for C8F18. Newly measured infrared absorption


Super Building Insulation by CO2 Foaming Process Research Project |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Emerging Technologies » Super Building Insulation by CO2 Foaming Emerging Technologies » Super Building Insulation by CO2 Foaming Process Research Project Super Building Insulation by CO2 Foaming Process Research Project The Department of Energy is currently researching the development of building superinsulation through a carbon dioxide (CO2) foaming process. Project Description This project seeks to develop building super insulation through a carbon dioxide foaming process that does not use hydrofluorocarbons (HFCs), and which produces insulation with a high R-value. Project Partners Research is being undertaken between the Department of Energy and The Industrial Science & Technology Network. Project Goals The goal of this project is to develop advanced insulation without HFC, and to achieve a competitive processing cost for CO2 foaming technology.


Atmospheric Measurements of Climate-Relevant Species  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Measurements of Climate-Relevant Species Atmospheric Measurements of Climate-Relevant Species CDIAC's data collection includes measurements of the following climate-relevant chemical species. A summary of recent greenhouse gas concentrations is also available. To determine how compounds are named, see the CDIAC "Name that compound" page. Butane (C4H10) Carbon Dioxide (CO2) Carbon Isotopes Carbon Monoxide (CO) Carbon Tetrachloride (CCl4) Chlorofluorocarbons Chloroform (CHCl3) Deuterium (2H) Ethane (C2H6) Ethyl Nitrate (C2H5ONO2) Ethyne (C2H2) Fluoroform (CHF3) Halogenated Compounds (modern records) Halons (fluorocarbons) Hydrogen (H2) Hydrochlorofluorocarbons (HCFCs) Hydrofluorocarbons (HFCs) i-Propyl Nitrate (C3H7ONO2) Methane (CH4) Methyl Bromide (CH3Br) Methyl Chloride (CH3Cl) Methyl Chloroform (CH3CCl3)


Synopsis of residential refrigerator/freezer alternative refrigerants evaluation  

SciTech Connect

The experimental testing on residential refrigerator/freezers (R/Fs) is summarized in this paper. R/F testing focused on two areas: alternative refrigerants and equipment configurations. The refrigerants evaluated consisted of single components, azeotropes, and zeotropes derived from hydrofluorocarbons (HFCs) and hydrocarbons (HCs). These refrigerants were evaluated in conventional and unconventional R/F designs. Major and minor design modifications were studied. Minor modifications consisted of various capillary tube lengths, door insulations, and compressors, while major modifications included two-evaporator and two-cycle R/F systems. Results obtained from testing the two-cycle system will be discussed in a later paper. This paper presents the experimental results of alternative technologies evaluated as replacements for ozone depleting chemicals.

Baskin, E. [Environmental Protection Agency, Research Triangle Park, NC (United States)



Demonstration of high efficiency elastocaloric cooling with large ?T using NiTi wires  

Science Journals Connector (OSTI)

Vapor compression (VC) is by far the most dominant technology for meeting all cooling and refrigeration needs around the world. It is a mature technology with the efficiency of modern compressors approaching the theoretical limit but its environmental footprint remains a global problem. VC refrigerants such as hydrochloroflurocarbons (HCFCs) and hydrofluorocarbons (HFCs) are a significant source of green house gas emissions and their global warming potential (GWP) is as high as 1000 times that of CO2 [Buildings Energy Data Book (Building Technologies Program Department of Energy 2009)]. There is an urgent need to develop an alternative high-efficiency cooling technology that is affordable and environmentally friendly [A. D. Little Report For Office of Building Technology State and Community Programs Department of Energy 2001]. Here we demonstrate that elastocaloric cooling (EC) a type of solid-state cooling mechanism based on the latent heat of reversible martensitic transformation can have the coefficient of performance as high as ?11 with a directly measured ?T of 17?C. The solid-state refrigerant of EC completely eliminates the use of any GWP refrigerants including HCFCs/HFCs.

Jun Cui; Yiming Wu; Jan Muehlbauer; Yunho Hwang; Reinhard Radermacher; Sean Fackler; Manfred Wuttig; Ichiro Takeuchi



Demonstration of High Efficiency Elastocaloric Cooling with Large Delta- T Using NiTi Wires  

SciTech Connect

Vapor compression (VC) is by far the most dominant technology for meeting all cooling and refrigeration needs around the world. It is a mature technology with the efficiency of modern compressors approaching the theoretical limit, but its envi-ronmental footprint remains a global problem. VC refrigerants such as hydrochlo-roflurocarbons (HCFCs) and hydrofluorocarbons (HFCs) are a significant source of green house gas (GHG) emissions, and their global warming potential (GWP) is as high as 1000 times that of CO2. It is expected that building space cooling and re-frigeration alone will amount to {approx} 5% of primary energy consumption and {approx}5% of all CO2 emission in U.S. in 2030 . As such, there is an urgent need to develop an al-ternative high-efficiency cooling technology that is affordable and environmentally friendly. Among the proposed candidates, magnetocaloric cooling (MC) is currently received a lot of attention because of its high efficiency. However, MC is inherently expensive because of the requirement of large magnetic field and rare earth materi-als. Here, we demonstrate an entirely new type of solid-state cooling mechanism based on the latent heat of reversible martensitic transformation. We call it elasto-caloric cooling (EC) after the superelastic transformation of austenite it utilizes. The solid-state refrigerant of EC is cost-effective, and it completely eliminates the use of any refrigerants including HCFCs/HFCs. We show that the COP (coefficient of per-formance) of a jugular EC with optimized materials can be as high as > 10 with measured {Delta}T of 17 C.

Cui, Jun; Wu, Yiming; Muehlbauer, Jan; Hwang, Yunho; Radermacher, Reinhard; Fackler, Sean; Wuttig, Manfred; Takeuchi, Ichiro




E-Print Network (OSTI)

- amperometry and chronopotentiometry. Anode gases have been analyzed by gas chromatography on-line during results, the following hypothesis is offered in explanation of the mechanism of the anodic process of PFC the initial stages of the anode effect. Introduction One of the undesirable consequences of the anode effect

Sadoway, Donald Robert


Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems  

SciTech Connect

The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

Reimus, Paul W [Los Alamos National Laboratory



An Improved Gas Chromatographic Method for the Determination of Perfluorocarbon Tracers in the Atmosphere  

Science Journals Connector (OSTI)

......U.S. Department of Energy, New York, New York...U.S. Department of Energy, New York, New York...quantity, hence the cost, of the tracer required...experiments in the geysers geothermal area. RH. Gudiksen...U. S. Department of Energy, New York, NY(1991......

Raymond J. Lagomarsino



Buildings Energy Data Book: 7.1 National Legislation  

Buildings Energy Data Book (EERE)

5 5 Phase Out Schedule of Halocarbons in the U.S. (1) Gas % By % By Chlorofluorocarbons 75% 1994 75% 1994 (CFCs) 100% 1996 (4) 100% 1996 Bromofluorocarbons 100% 1994 (4) 100% 1994 (Halons) Hydrochlorofluorocarbons 35.0% 2004 35% 2003 (HCFCs) 75.0% 2010 75% 2010 90.0% 2015 90% 2015 99.5% 2020 99.5% 2020 100% 2030 (4) 100% 2030 Hydrofluorocarbons N.A. N.A. N.A. N.A. (HFCs) Note(s): Source(s): 1989 HCFC consumption + 2.8 % of 1989 CFC consumption 1996 N.A. N.A. 1) The phase out of halocarbons is consistent with Title VI of the Clean Air Act and is in accordance with the Montreal Protocol and Amendments. 2) The amount of gas produced and consumed in this year is established and defined as the base level. To meet basic domestic needs, levels of production are allowed to exceed the base level by up to 10%. 3) After this year, levels of production are no longer


Energy and global warming impacts of next generation refrigeration and air conditioning technologies  

SciTech Connect

Significant developments have occurred in hydrofluorocarbon (HFC) and the application of ammonia and hydrocarbons as refrigerant working fluids since the original TEWI (Total Equivalent Warming Impact) report in 1991. System operating and performance data on alternative refrigerants and refrigeration technologies justify and updated evaluation of these new alternative refrigerants and competing technologies in well-characterized applications. Analytical and experimental results are used to show quantitative comparisons between HFCS, HFC blends, hydrocarbons, and ammonia, used as refrigerants. An objective evaluation is presented for commercial and near commercial non-CFC refrigerants/blowing agents and alternative refrigeration technologies. This information is needed for objective and quantitative decisions on policies addressing greenhouse gas emissions from refrigeration and air conditioning equipment. The evaluation assesses the energy use and global warming impacts of refrigeration and air conditioning technologies that could be commercialized during the phase out of HCFCS. Quantitative comparison TEWI for two application areas are presented. Opportunities for significant reductions in TEWI are seen with currently known refrigerants through improved maintenance and servicing practices and improved product designs.

Sand, J.R.; Fischer, S.K.; Baxter, V.D.



Feasibility of a Perfluorocarbon tracer based network to support Monitoring, Verification, and Accounting of Sequestered CO2  

Science Journals Connector (OSTI)

Carbon capture and sequestration (CCS) will act as a bridging technology necessary to facilitate a transition from fossil fuels to a sustainable energy based economy. The Department of Energy (DOE) target leak rate for sequestration reservoirs is 1% of ...

Thomas B. Watson; Terrence Sullivan



Global warming impacts of ozone-safe refrigerants and refrigeration, heating, and air-conditioning technologies  

SciTech Connect

International agreements mandate the phase-out of many chlorine containing compounds that are used as the working fluid in refrigeration, air-conditioning, and heating equipment. Many of the chemical compounds that have been proposed, and are being used in place of the class of refrigerants eliminated by the Montreal Protocol are now being questioned because of their possible contributions to global warming. Natural refrigerants are put forth as inherently superior to manufactured refrigerants because they have very low or zero global warming potentials (GWPs). Questions are being raised about whether or not these manufactured refrigerants, primarily hydrofluorocarbons (HFCs), should be regulated and perhaps phased out in much the same manner as CFCs and HCFCs. Several of the major applications of refrigerants are examined in this paper and the results of an analysis of their contributions to greenhouse warming are presented. Supermarket refrigeration is shown to be an application where alternative technologies have the potential to reduce emissions of greenhouse gases (GHG) significantly with no clear advantage to either natural or HFC refrigerants. Mixed results are presented for automobile air conditioners with opportunities to reduce GHG emissions dependent on climate and comfort criteria. GHG emissions for hermetic and factory built systems (i.e. household refrigerators/freezers, unitary equipment, chillers) are shown to be dominated by energy use with much greater potential for reduction through efficiency improvements than by selection of refrigerant. The results for refrigerators also illustrate that hydrocarbon and carbon dioxide blown foam insulation have lower overall effects on GHG emissions than HFC blown foams at the cost of increased energy use.

Fischer, S.; Sand, J.; Baxter, V.



Molecular Design Using Quantum Chemical Calculations for Property Estimation  

E-Print Network (OSTI)

techniques for molecular design. A simple hydrofluorocarbon refrigerant design example and a solvent design level information about any system can be predicted (e.g., molecular energies, electronic charge as the target property, motivated by an interest in chemically stable hydrofluorocarbon refrigerants. The second

Maranas, Costas


Albany, OR * Anchorage, AK * Morgantown...  

NLE Websites -- All DOE Office Websites (Extended Search)

GEOSEQ: Monitoring of Geological CO2 Sequestration Using Isotopes and Perfluorocarbon Tracers (PFTs) Background The purpose of this project is to develop monitoring, verification,...


ITP Aluminum: Energy and Environmental Profile of the U.S. Aluminum...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and particulate), perfluorocarbons (CF 4 , C 2 F 6 ), polycyclic organic matter Wet air pollution control (APC) effluents (if applicable) Spent potlining (RCRA- listed K088),...


Supplement 1. PFC emissions from UNFCCC data1086 Perfluorocarbon (PFC) emission are reported to UNFCCC by 34 Annex I countries as part of their obligations as signatories to the1087  

E-Print Network (OSTI)

(UNFCCC, 2009). Emissions are reported for CF4, C2F6, C3F8, c-C4F8, C4F10, C5F12 and C6F14 in Gg) 6500 (CF4), 9200 (C2F6), 7000 (C3F8), 8700 (c-1089 C4F8), 7000 (C4F10), 7500 (C5F12), and 7400 (C6F14 2001 2002 2003 2004 2005 2006 CF4 S 8.58 7.86 7.16 6.77 6.19 6.16 6.31 6.04 5.87 5.74 5.59 4.63 4.47 4

Meskhidze, Nicholas


Wind Power and the Clean Development Mechanism  

E-Print Network (OSTI)

Biogas Cement HFCs Geothermal EE Households Solar N2O Fugitive Tidal EE Service Transport Energy distrib 200 300 400 500 600 700 Lara Landfill (10 MW) Korat Biogas (3 MW) Rukmani Rice Husk (10 MW) Palestina


Enhanced naphthenic refrigeration oils for household refrigerator systems  

SciTech Connect

Due to industry concerns about the successful employment of hydrofluorocarbon-immiscible hydrocarbon oils in refrigeration systems, enhanced naphthenic refrigeration oils have been developed. These products have been designed to be more dispersible with hydrofluorocarbon (HFC) refrigerants, such as R-134a, in order to facilitate lubricant return to the compressor and to ensure proper energy efficiency of the system. Bench tests and system performance evaluations indicate the feasibility of these oils for use in household refrigeration applications. Results of these evaluations are compared with those obtained with polyol esters and typical naphthenic mineral oils employed in chlorofluorocarbon (CFC) and hydrochlorofluorocarbon (HCFC) refrigeration applications.

Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R. [Witco Corp., Oakland, NJ (United States); Barbour, C.B. [Americold, Cullman, AL (United States)


Note: This page contains sample records for the topic "hydrofluorocarbons hfcs perfluorocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


Primary aluminum production : climate policy, emissions and costs  

E-Print Network (OSTI)

Climate policy regarding perfluorocarbons (PFCs) may have a significant influence on investment decisions in the production of primary aluminum. This work demonstrates an integrated analysis of the effectiveness and likely ...

Harnisch, Jochen.; Sue Wing, Ian.; Jacoby, Henry D.; Prinn, Ronald G.


Global emission estimates and radiative impact of C[subscript 4]F[subscript 10], C[subscript 5]F[subscript 12], C[subscript 6]F[subscript 14], C[subscript 7]F[subscript 16] and C[subscript 8]F[subscript 18  

E-Print Network (OSTI)

Global emission estimates based on new atmospheric observations are presented for the acylic high molecular weight perfluorocarbons (PFCs): decafluorobutane (C[subscript 4]F[subscript 10]), dodecafluoropentane (C[subscript ...

Ivy, Diane J.


published in Light Metals 2001, J.L. Anjier, editor, TMS, Warrendale, PA, 2001, pp. 303-307. TOWARDS ELIMINATION OF ANODE EFFECT AND PFC EMISSIONS VIA CURRENT SHUNTING  

E-Print Network (OSTI)

) results in the generation of the perfluorocarbons (PFCs) CF4 and C2F6 [1]. Owing to the high global with AE, recent measurements made on industrial cells indicate that trace levels of CF4 are present

Sadoway, Donald Robert


Environmental Data Sheet ENVIRONMENTAL DATA SHEET Dell Inc.  

E-Print Network (OSTI)

, the customer should not rely upon this information in making decisions about electrical tolerances or otherwise) other than in cables and interconnect parts · CFCs (chlorofluorocarbons), HCFCs (hydrofluorocarbons in the Montreal Protocol annex A, B, or C is used in Dell's manufacturing plants. Additional Materials Information

Fiebig, Peter


Atmos. Chem. Phys., 8, 31413147, 2008 www.atmos-chem-phys.net/8/3141/2008/  

E-Print Network (OSTI)

. Wallington2 1Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen catalytic ozone destruc- tion cycles (Wallington et al., 1994). The atmospheric life- time of HFCs is determined by their reactivity towards OH Correspondence to: T. J. Wallington (twalling@ford.com) radicals

Meskhidze, Nicholas


Transportation and Greenhouse Gas Emissions: Measurement, Causation and Mitigation  

E-Print Network (OSTI)

% of the carbon dioxide we produce. As such it is a leading candidate for greenhouse gas ((GHG) (CO2, NH4, HFCs.S. CO2 emissions sources. U.S. CO2 transportation emissions sources by mode. #12;CenterTransportation and Greenhouse Gas Emissions: Measurement, Causation and Mitigation Oak Ridge


Atmos. Chem. Phys., 10, 51455164, 2010 www.atmos-chem-phys.net/10/5145/2010/  

E-Print Network (OSTI)

-absorbing perfluorocarbons (PFCs) tetrafluoromethane (CF4), hexafluoroethane (C2F6), and octafluoropropane (C3F8) in both dry air mole fraction), for CF4; the Advanced Global Atmospheric Gases Experiment (AGAGE). Pre-industrial background values of 34.7±0.2 ppt CF4

Meskhidze, Nicholas


A Carbon Arc Process for Treatment of CF4 Emissions  

Science Journals Connector (OSTI)

Grand canonical Monte Carlo simulations are reported for low molecular weight perfluorocarbons (C2F6 and CF4) and their dilute (10% molar) mixtures in N2 adsorbing unto slitlike graphite pores. ... The technological feasibility and chemical kinetics of carbon tetrafluoride (CF4) decomposition with tandem packed-bed plasmas (TPBPs) are investigated in this study. ...

Daniel T. Chen; Moses M. David; George V. D. Tiers; Joseph N. Schroepfer



Atmos. Chem. Phys., 12, 261269, 2012 www.atmos-chem-phys.net/12/261/2012/  

E-Print Network (OSTI)

abundant perfluorocarbon (PFC) in the present day atmosphere, behind CF4 (75 ppt) and C2F6 (4 ppt in the atmosphere is CF4. The first atmospheric measurements were reported in the late 1970s (Rasmussen et al., 1979-day abundances of these compounds are much lower than CF4, being typically in the range of a few ppt or less

Meskhidze, Nicholas


Pressure-dependent Resonance Frequency for Lipid-coated Microbubbles at Low Acoustic  

E-Print Network (OSTI)

with diameters ranging from 1-10m, filled with gas of low water solubility (e.g. perfluorocarbon, nitrogen in this device, one for gas inlet flow, two for liquid inlet flow, and the last one for microbubbles outlet flow channel and gas channel were 50 m and 35 m, respectively, while the width of the orifice was 7 m. Figure 1


NOAA Air Resources Laboratory Monthly Activity Report  

E-Print Network (OSTI)

. Perfluorocarbon Tracer Analysis Development 11. Radar Wind Profiler 12. Transport and Dispersion Modeling 13. Coordination with BEA Emergency Management Group 14. SORD Review 15. WRF Model 16. Mesoscale Modeling 17. Air of the local NOX sources within the watershed on N deposition to the watershed and bay, supplemented


Environment International, Vol. 8, pp. 419-433, 1982 0160-4120/82/070419-15503.00/0 Printed in the USA. All rights reserved. Copyright 1982 Pergamon Press Ltd.  

E-Print Network (OSTI)

perfluorocarbon tracer (PFT) sources and miniature passive samplers, both about the size of a cigarette, tests of passive adsorption tube samplers performed reproducibly and identically (to within + 2%-3%) in laboratory-story house. Multiple location sampling, as well as sampling in rooms with and without a miniature source


Evaluation of performance and composition shift of zeotropic mixtures in a Lorenz-Meutzner refrigerator/freezer  

SciTech Connect

Results from previous testing of this refrigerator/freezer using a 750 Btu/h compressor and several zeotropic mixtures revealed a performance enhancement up to 16% above that of hydrofluorocarbon R-134a. In the study presented in this paper, the Lorenz-Meutzner (LM) refrigerator/freezer equipped with a 1060 Btu/h compressor, two evaporators, and two intercoolers was experimentally tested in an environmental chamber according to the Association of Home Appliance Manufacturers/Department of Energy (AHAM/DOE) testing standards using several hydrofluoropropane-based zeotropic mixtures. The results are compared to baseline testing with R-134a and results obtained using the 750 Btu/h compressor. Hydrofluorocarbons R-245ca/R-152a performed comparably to R-134a. R-245ca/hydrocarbon R-270 (cyclopropane C{sub 3}H{sub 6}) outperformed all zeotropic mixtures and R-134a by at least 12.2 {+-} 0.7%. All refrigerants performed better using the larger compressor due to its inherently better efficiency. Refrigerant samples taken during refrigerator/freezer operation revealed substantial composition shifts (e.g., a 30% running composition shift of R-134a in the R-245ca/R-134a mixture). Sand et al. (1993) obtained an approximately 20% energy reduction using steady-state on-cycle energy consumption results; a comparison was made between chlorofluorocarbon R-12 and a hydrofluorocarbon R-32/hydrochlorofluorocarbon R-124 mixture. Lorenz and Meutzner (1975), originators of the Lorenz-Meutzner refrigerator/freezer design, state that the following parameters influence the optimum performance of the design: (1) heat exchanger size, (2) capillary tube length, (3) refrigerant charge, and (4) compressor size. This work investigates three of these parameters--capillary tube length, compressor size, and refrigerant charge.

Baskin, E.; Smith, N.D.; Delafield, F.R.; Tufts, M.W.



Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems  

Energy.gov (U.S. Department of Energy (DOE))

This case study documents one year of operating experience with a transcritical carbon dioxide (TC CO2) booster refrigeration system at Delhaize Americas Hannaford supermarket location in Turner, Maine. This supermarket, which began operation in June 2013, is the first supermarket installation in the U.S. of a TC CO2 booster refrigeration system. We compare refrigeration system performance to that for a supermarket having nearly identical layout and refrigeration loads, in a similar climate and of similar vintage, that uses a conventional hydrofluorocarbon (HFC) refrigerant. Delhaize provided the submetered and utility data used to generate the performance summaries herein.


Empirical correlations for the modeling of R-134a flow through adiabatic capillary tubes  

SciTech Connect

This paper presents the results of an experimental study on capillary tubes commonly used as an expansion device in household refrigerators and freezers. The experiments were performed with the hydrofluorocarbon R-134a at different condensing pressures and levels of subcooling. The pressure and temperature profiles along the capillary tubes were measured in each test run. The data set was then used to evaluate the suitability of some equations previously reported in the literature for the single-phase friction factor, the underpressure of vaporization, and the entrance contraction loss factor. Correlations for the average and local two-phase friction factors were also developed based on the measured data.

Melo, C.; Neto, C.B.; Silva Ferreira, R.T. da



Microsoft PowerPoint - Proceedings Cover Sheets  

NLE Websites -- All DOE Office Websites (Extended Search)

Geological CO Geological CO 2 Sequestration using Perfluorocarbon Gas Tracers and Isotopes Phelps, T.J., McCallum, S.D., Cole, D.R., Kharaka, Y.K., and Hovorka, S.D. ABSTRACT The Frio Brine Field Test, Phase I, demonstrated the relatively straight forward method of CO 2 injection and its rapid transport to the monitoring well. Our field monitoring methodologies, especially measurements of conservative perfluorocarbon gas tracers (PFTs), pH, alkalinity, gas compositions and stable isotopes proved to be sensitive for tracking the injected CO 2 . Multiple PFT tracer suites were introduced via an injection well at three separate times during the Frio Test. The use of PFT suites provided data for identification of multiple breakthroughs at a monitoring well 30 meters up-dip. Travel times for each



NLE Websites -- All DOE Office Websites (Extended Search)

Monitoring Geologically Sequestered Monitoring Geologically Sequestered CO 2 during the Frio Brine Pilot Test using Perfluorocarbon Tracers 1 McCallum, S.D., 1 Riestenberg, D.E., 1 Cole, D.R., 2 Freifeld, B.M., 2 Trautz, R.C., 3 Hovorka, S.D., and 1 Phelps*, T.J. 1 Oak Ridge National Laboratory, 1505 Bethel Valley Road, Oak Ridge, TN, 37831- 6036 USA 2 Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720- 90R1116, USA 3 Texas Bureau of Economic Geology, The University of Texas at Austin, University Station, Box X, Austin, Texas 78713-8924, USA *Corresponding author and presenter (phelpstj@ornl.gov) Abstract A suite of gaseous perfluorocarbon (PFT) conservative tracers were successfully employed to monitor migration of the CO 2 plume during the Frio Brine Pilot Test. The conservative tracers enabled


PFT Air Infiltration Measurement Technique | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

PFT Air Infiltration Measurement Technique PFT Air Infiltration Measurement Technique PFT Air Infiltration Measurement Technique April 2, 2012 - 3:11pm Addthis The Brookhaven National Laboratory developed the PFT (PerFluorocarbon tracer gas) technique to measure changes over time when determining a building's air-infiltration rate. The Brookhaven National Laboratory developed the PFT (PerFluorocarbon tracer gas) technique to measure changes over time when determining a building's air-infiltration rate. What does this mean for me? You can save 5%-30% on your energy bill by making upgrades following a home energy assessment. A professional energy auditor may use the PFT air infiltration measurement technique to find out where your home has air leaks, though a blower door test is more commonly used.


Software/firmware design specification for 10 MW/sub e/ Solar Thermal Central Receiver Pilot Plant  

SciTech Connect

This Collector Subsystem Software/Firmware Design Specification exists as a stand-alone document to provide a complete description of the software and firmware employed for the operation of the 10 MWe Solar Thermal Central Receiver Pilot Plant Collector Subsystem. The software/firmware systems have the capability to allow operator control of up to 2048 heliostats in the operation of the 10 MWe Solar Thermal Central Receiver Pilot Plant at Barstow, California. This function includes the capability of operator-commanded mode control, graphic displays, status displays, alarm generation, system redundancy and interfaces to the Operational Control System (OCS), the Data Acquisition System (DAS), and the Beam Characterization System (BCS) through the OCS. The operational commands will provide for the following: (a) safe beam movement whenever automatic beam movement is required; (b) single and multiple heliostat addressing; (c) emergency heliostat movement for high-wind conditions and receiver problems; and (d) recovery for full or partial power-loss conditions. The control hardware consists of a host computer, the Heliostat Array Controller (HAC), interfaced to a group of communication controllers, the Heliostat Field Controllers (HFCs), communicating with individual processors, the Heliostat Controllers (HCs), which monitor and command a single heliostat. The system consists of two HACs and 64 HFCs with up to 32 HCs per HFC.

Ladewig, T.D.



Gunnar I. Senum | BNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Gunnar I. Senum Gunnar I. Senum Chemist Education State University of New York at Stony Brook, Ph.D., Chemistry Brooklyn College of the City University of New York, B.S., Chemistry Professional Affiliations American Chemical Society American Physical Society American Association for the Advancement of Science Areas of Interest Application and modeling of chromatographic systems for the development of techniques for the detection and quantification of trace components with the consequent application to geophysical trace gases, indoor pollution and various industrial applications Development of chemicalcompounds as atmospheric, hydrological or aerosol tracers Experience Presently responsible for the development and applications of new techniques using perfluorocarbon tracers in the Tracer Technology Center,

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Climate VISION: Private Sector Initiatives: Aluminum: Resources and Links -  

Office of Scientific and Technical Information (OSTI)

Federal/State Programs Federal/State Programs DOE Aluminum Industry of the Future Collaborative R&D partnerships between DOE Industrial Technologies Program and industry to maximize technology investments. EPA Voluntary Aluminum Industrial Partnership The Voluntary Aluminum Industrial Partnership (VAIP) is an innovative pollution prevention program developed jointly by the U.S. Environmental Protection Agency (EPA) and the primary aluminum industry. Participating companies (Partners) work with EPA to improve aluminum production efficiency while reducing perfluorocarbon (PFC) emissions, potent greenhouse gases that may remain in the atmosphere for thousands of years. See all Federal/State Programs DOE State Activities For information on activities, financial assistance, and solicitations


Method for inducing hypothermia  

DOE Patents (OSTI)

Systems for phase-change particulate slurry cooling equipment and methods to induce hypothermia in a patient through internal and external cooling are provided. Subcutaneous, intravascular, intraperitoneal, gastrointestinal, and lung methods of cooling are carried out using saline ice slurries or other phase-change slurries compatible with human tissue. Perfluorocarbon slurries or other slurry types compatible with human tissue are used for pulmonary cooling. And traditional external cooling methods are improved by utilizing phase-change slurry materials in cooling caps and torso blankets.

Becker, Lance B. (Chicago, IL); Hoek, Terry Vanden (Chicago, IL); Kasza, Kenneth E. (Palos Park, IL)




SciTech Connect

Brookhaven National Laboratory has been funded since October of 2000 to provide assistance to the University of Georgia in conducting footprint analyses of individual towers based on meteorology and trace gas measurements. Brookhaven researchers conducted air flow measurements using perfluorocarbon tracers and meteorological instrumentation for three experimental campaigns at an AmeriFlux research site maintained by Dr. Monique Leclerc near Gainesville, FL. In addition, BNL provided assistance with remote data collection and distribution from remote field sites operated by Dr. John Hom of the US Forest Service in the Pine Barrens of New Jersey and at FACE research sites in North Carolina and Wisconsin.




Metal buildings study: performance of materials and field validation  

SciTech Connect

A 5000 square-foot metal building located at Brookhaven National Laboratory has been monitored over a winter season. Energy flows through wall sections were monitored using portable calorimeters. Air infiltration was measured using perfluorocarbon tracers, and the associated heat losses were calculated. Slab losses were assessed through a comparison of measured temperature gradients with results obtained through the use of heat-flow meters. The effect of thermal bridges and compressed insulation in locations where support beams are joined to the exterior skin was found to increase heat losses significantly. A retrofit strategy including spray insulation of beams is projected to save 30% on heating energy.

Loss, W.



Advanced Insulation for High Performance Cost-effective Wall, Roof, and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Insulation for High Performance Advanced Insulation for High Performance Cost-effective Wall, Roof, and Foundation Systems Research Project Advanced Insulation for High Performance Cost-effective Wall, Roof, and Foundation Systems Research Project The U.S. Department of Energy (DOE) is currently conducting research into advanced insulation for high performance wall, roof, and foundation systems. Heat flows from hotter to colder spaces, and insulation is designed to resist this flow by keeping hot air out in the summer and in during the winter. Project Description This project seeks to develop high performing, durable, hydrofluorocarbon and hydrochlorofluorocarbons -free insulation with an R-value greater than 7.5-per-inch and a Class A fire performance. Project Partners Research is being undertaken between DOE and Dow Chemical.


Lubricant return comparison of naphthenic and polyol ester oils in R-134a household refrigeration applications  

SciTech Connect

This paper presents mineral oils and polyol esters as possible lubricant options for domestic refrigeration applications employing R-134a as the heat exchange fluid. A performance comparison, based on data presented, is made between the mineral oils and polyol esters evaluated. To more closely examine lubricant return with N-70 and R-134a and ensure that the oil is not contributing to any deterioration in efficiency due to its accumulation in evaporators, a special test unit was designed with a difficult oil return configuration and its performance carefully monitored. Oil return with a hydrofluorocarbon-miscible polyol ester, R-133-O was also evaluated in this setup and its performance results compared to those obtained with the naphthenic refrigeration oil.

Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R. [Witco Corp., Oakland, NJ (United States)



Reducing the Carbon Footprint of Commercial Refrigeration Systems Using Life Cycle Climate Performance Analysis: From System Design to Refrigerant Options  

SciTech Connect

In this paper, Life Cycle Climate Performance (LCCP) analysis is used to estimate lifetime direct and indirect carbon dioxide equivalent gas emissions of various refrigerant options and commercial refrigeration system designs, including the multiplex DX system with various hydrofluorocarbon (HFC) refrigerants, the HFC/R744 cascade system incorporating a medium-temperature R744 secondary loop, and the transcritical R744 booster system. The results of the LCCP analysis are presented, including the direct and indirect carbon dioxide equivalent emissions for each refrigeration system and refrigerant option. Based on the results of the LCCP analysis, recommendations are given for the selection of low GWP replacement refrigerants for use in existing commercial refrigeration systems, as well as for the selection of commercial refrigeration system designs with low carbon dioxide equivalent emissions, suitable for new installations.

Fricke, Brian A [ORNL] [ORNL; Abdelaziz, Omar [ORNL] [ORNL; Vineyard, Edward Allan [ORNL] [ORNL



Carbon Sequestration 101  

NLE Websites -- All DOE Office Websites (Extended Search)

Field Efforts Field Efforts Sequestering CO 2 in Geologic Formations SPE 2003 Eastern Section Meeting of AAPG September 6 - 10, 2003 Pittsburgh, Pennsylvania Scott M. Klara - National Energy Technology Laboratory What's All The Fuss About? CO 2 Concentrations On The Rise (~280 ppm to 370 ppm over last 100 years) Temperature Change from Present ( o C) CO 2 Concentration (ppmv) 200 150 50 350 300 250 200 100 0 ∆T atm (Vostok) CO 2 (Vostok) 2 0 -2 -4 Time Before Present (kyr) CO 2 & CH 4 - The Primary GHG Contributors Methane 9% Nitrous Oxide 5% HFCs, PFCs, SF 6 2% CO 2 from Energy 81% Other CO 2 3% "EIA Emissions of Greenhouse Gases in the U.S.: 2000" United States Greenhouse Gas Emissions (Equivalent Global Warming Basis) All Fossil Fuels & Energy Sectors Contribute CO 2 Emissions Industry 32% Industry 32% Commercial


Microsoft PowerPoint - Sequestration Briefing - October-07.ppt  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Sequestration R&D Overview Carbon Sequestration R&D Overview Office of Fossil Energy Carbon Sequestration Briefing October 2007 Sean Plasynski, PhD Sequestration Technology Manager Office of Fossil Energy R&D Focus is on Coal & Electricity Oil 43% Oil 43% Coal 36% Coal 36% Natural Gas 21% Electricity 39% Electricity 39% Other 30% Other 30% Transportation 32% Transportation 32% United States CO2 Emissions 36% Emissions From Coal 39% Emissions From Electricity Office of Fossil Energy R&D Focus is on CO 2 Methane 9% Nitrous Oxide 5% HFCs, PFCs, SF 6 2% CO 2 from Energy 81% Other CO 2 3% "EIA Emissions of Greenhouse Gases in the U.S.: 2000" United States Greenhouse Gas Emissions (Equivalent Global Warming Basis) Office of Fossil Energy Annual CO 2 Emissions Extremely Large 6,300,000,000 Carbon Dioxide (CO


The ALE/GAGE/AGAGE Network (DB1001)  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases » ALE/GAGE/AGAGE Network Atmospheric Trace Gases » ALE/GAGE/AGAGE Network The ALE / GAGE / AGAGE Network (DB1001) DOI: 10.3334/CDIAC/atg.db1001 Links to Additional Sources Advanced Global Atmospheric Gases Experiment (AGAGE) home page How halocarbons (CFCs, HFCs, HCFCs, and halons) are named CDIAC data base including some of the same compounds, and a tabulation of their uses and atmospheric lifetimes Investigators R.G. Prinn, R.F. Weiss, P.J. Fraser, P.G. Simmonds, S. O'Doherty, P. Salameh, L. Porter, P. Krummel, R.H.J. Wang, B. Miller, C. Harth, B. Greally, F.A. Van Woy, L.P. Steele, J. Müehle, G. Sturrock, F.N. Alyea, J. Huang, and D.E. Hartley Description In the ALE/GAGE/AGAGE global network program, continuous high frequency gas chromatographic measurements of four biogenic/anthropogenic gases (methane,


Sandeman-012113 - Argonne National Laboratories, Materials Sicence Division  

NLE Websites -- All DOE Office Websites (Extended Search)

Sandeman-012113 Sandeman-012113 JOINT PSE/MSD SEMINAR SPEAKER: Karl G. Sandeman Department of Physics TITLE: "(Tri)critical Phase Transitions in Magnetocaloric Materials " DATE: Monday, January 21, 2013 TIME: 3:00 p.m. PLACE: Building 223 / S-105 HOST: Seungbum Hong ABSTRACT: Much of today's research in so-called functional materials is driven by the quest for technologies that use energy more efficiently and reduce our impact on the environment. Such pressures drive a renewed investigation of some of the most fundamental properties of condensed matter. Solid-state phase transitions are one good example. In order to find an energy efficient solution to the problem of reducing our use of HFCs in a variety of cooling applications, a new field has been defined.


Kyoto Protocol | Open Energy Information  

Open Energy Info (EERE)

Kyoto Protocol Kyoto Protocol Jump to: navigation, search http://www.wired.com/thisdayintech/tag/climate-change/ Kyoto protocol negotiation The Kyoto Protocol, negotiated in 1997 and into force in 2005, is a binding agreement in which industrialized nations will seek emission-reducing strategies for the future years to come. "The Kyoto Protocol is a legally binding agreement under which industrialized countries will reduce their collective emissions of greenhouse gases by 5.2% compared to the year 1990 (but note that, compared to the emissions levels that would be expected by 2010 without the Protocol, this target represents a 29% cut). The goal is to lower overall emissions from six greenhouse gases - carbon dioxide, methane, nitrous oxide, sulfur hexafluoride, HFCs, and PFCs - calculated as an average over


Research in chemical kinetics. Annual report, 1993  

SciTech Connect

Progress on the seven projects under this contract is reported. The projects are: (1) Chlorine atom reactions with vinyl bromide. Mass spectrometric investigations of the anti-Markownikoff rule. (2) Chlorine atom reactions with CF{sub 2}{double_bond}CFBr. (3) Gas phase thermal {sup 38}Cl reactions with (CH{sub 2}{double_bond}CH){sub n}M (M=Sn, Si, n=4; M=Sb, n=3; M=Hg, n=2). (4) Gas phase reactions of thermal chlorine atoms with (CH{sub 3}){sub 4}M (M=C, Si, Ge, Sn, Pb). (5) Hydrogen abstraction reactions by thermal chlorine atoms with HFCs, HCFCs, and halomethanes. (6) Half-stabilization pressure of chlorine atoms plus ethylene in a nitrogen bath. (7) {sup 14}C content of atmospheric OCS, C{sub 2}H{sub 6} and C{sub 3}H{sub 8}.

Rowland, F.S.



Determination of properties of PVE lubricants with HFC refrigerants[PolyVinylEther  

SciTech Connect

Polyalkyleneglycol (PAG) and polyol ester (POE) have been developed as refrigeration lubricants, used with HFC134a. PAG is used for automotive air conditioning systems and POE is used for domestic reciprocating refrigerators and for A/C systems. Although PAG exhibits good lubricity performance, it is difficult to use for domestic reciprocating refrigerators due to its low dielectric property. POE is difficult to use for automotive A/C systems, due to hydrolysis and poor lubricity performance. Polyvinylether (PVE) can be used in place of PAG and POE with HFC refrigerants. PVE is used for A/C systems as well as refrigerator and freezer applications. PVE is an ideal lubricant for use with HFCs.

Kaneko, Masato; Sakanoue, Shuichi; Tazaki, Toshihiro; Tominaga, Shoichi; Takagi, Minoru; Goodin, M.



Project Title  

NLE Websites -- All DOE Office Websites (Extended Search)

Monitoring Geological CO Monitoring Geological CO 2 Sequestration using Perfluorocarbon and Stable Isotope Tracers Project Number FEAA-045 Tommy J. Phelps and David R. Cole* Oak Ridge National Laboratory Phone: 865-574-7290 email: phelpstj@ornl.gov (*The Ohio State University) U.S. Department of Energy National Energy Technology Laboratory Carbon Storage R&D Project Review Developing the Technologies and Building the Infrastructure for CO 2 Storage August 22, 2013 2 Project Overview: Goals and Objectives Goal: Develop methods to interrogate subsurface for improved CO 2 sequestration, field test characterization and MVA, demonstrate CO 2 remains in zone, and tech transfer. Objectives: 1. Assessment of injections in field. PFT gas tracers are analyzed by GC-ECD to



NLE Websites -- All DOE Office Websites (Extended Search)

0 0 NETL Accomplishments 2 Advancing energy options to fuel our economy, strengthen our security, and improve our environment. Our Mission 3 2010 NETL Accomplishments 86 66 54 52 28 8 6 4 CONTENTS NETL Mission Message from the Director NETL Powers the Future of Energy Advanced Power Systems 10 Gasification 14 Fuel Cells 16 SECA Reaches 2010 Program Goal 18 Turbines 22 Turbine Program Develops Prototypes for Reducing Emissions 24 Materials Clean Energy 30 Carbon Capture 34 Carbon Storage 36 Perfluorocarbon Tracers Go with the Flow 38 Carbon Sequestration Partnerships 44 Demand-Side Efficiency 48 Air, Water, Land A Century of Science Reliable Supply 56 Energy Infrastructure 60 Methane Hydrates 62 Natural Gas and Oil Production


Climate VISION: Private Sector Initiatives: Semiconductors  

Office of Scientific and Technical Information (OSTI)

Letters of Intent/Agreements Letters of Intent/Agreements The U.S. semiconductor industry, represented by the members of the Environmental Protection Agency's PFC Reduction/Climate Partnership for the Semiconductor Industry, has committed to reduce absolute perfluorocompound (PFC) emissions by 10% below the 1995 baseline level by the year 2010. Perfluorocompounds include the most potent and long-lived greenhouse gases such as perfluorocarbons (e.g., CF4, C2F6, C3F8), trifluoromethane (CHF3), nitrogen trifluoride (NF3), and sulfur hexafluoride (SF6). The Environmental Protection Agency's (EPA) voluntary semiconductor industry partnership was developed collaboratively with the Semiconductor Industry Association (SIA). EPA, SIA, and the Partner companies (listed below) are working to reduce industry greenhouse gas (GHG) emissions. EPA's


Climate VISION: Private Sector Initiatives: Aluminum  

Office of Scientific and Technical Information (OSTI)

Letters of Intent/Agreements Letters of Intent/Agreements Aluminum Association Logo The Aluminum Association and its members participating in the Voluntary Aluminum Industry Partnership (VAIP), representing 98% of primary aluminum production in the United States, have committed under the Climate VISION program to a direct carbon intensity reduction of emissions of perfluorocarbons (PFCs) and of emissions of CO2 from the consumption of the carbon anode from the primary aluminum reduction process. The Climate VISION target is a 53% total carbon equivalent reduction from these sources by 2010 from 1990 levels. The industry has been working to reduce greenhouse gas emissions for over a decade and this new commitment equates to an additional direct carbon-intensity reduction of 65% since 2000. As a


Home Energy Audits | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

April 4, 2012 April 4, 2012 This Month on Energy Savers: March 2012 We also covered some driving tips to help save money at the pump, ideas for new parents, and unveiled how you can connect with energy savings tips on the go. April 2, 2012 Energy 101: Home Energy Checkup (Text Version) The text version for the Home Energy Checkup 101 video. April 2, 2012 Blower door test during a home energy audit. Credit: Holtkamp Heating & A/C, Inc. Blower Door Tests Professional energy auditors use blower door tests to help determine a home's airtightness. April 2, 2012 The Brookhaven National Laboratory developed the PFT (PerFluorocarbon tracer gas) technique to measure changes over time when determining a building's air-infiltration rate. PFT Air Infiltration Measurement Technique


Climate VISION: Private Sector Initiatives: Aluminum: Resources and Links -  

Office of Scientific and Technical Information (OSTI)

Resources & Links Resources & Links Technical Information Publications Case Studies Publications Some of the following publications are available for download as Adobe PDF documents. Download Acrobat Reader Factors Affecting Emissions from Commercial Aluminum Reduction Cells (PDF 316 KB) The U.S. EPA and the Aluminum Association sponsored measurements of two perfluorocarbon (PFC) gases: tetrafluoromethane and hexafluoroethane. The measurements at six primary aluminum production facilities provided data on emissions of these compounds during normal aluminum smelting operations. Technology and Economics of Reducing PFC Emissions from Aluminium Production (PDF 139 KB) The paper, presented in 2002 at the Third International Symposium on Non-CO2 Greenhouse Gases (NCGG-3), provides an overview of global efforts

Note: This page contains sample records for the topic "hydrofluorocarbons hfcs perfluorocarbons" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


BNL | Tracer Technology Group | BNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Tracer Technology Group Tracer Technology Group Tracer Technology Image The Tracer Technology Group (TTG) developed the use of perfluorocarbon tracers (PFTs) as tools for studying long range atmospheric transport and dispersion in the early 1980s.We are world leaders in the use of PFTs for solving diverse research and engineering problems in the atmospheric sciences, the energy production and utility industries, and building characterization. The unique capabilities of the TTG are derived from our analytical expertise, infrastructure, and experience. We have developed PFT analytical methods that have detection limits at the femtogram level. We can measure global background levels of PFTS at the parts per quadrillion levels. Our scientists and technical staff have extensive experience in


Vibrational Spectroscopy at High Pressure in CF4: Implications to the Phase Diagram  

SciTech Connect

The molecular analogue of methane, CF{sub 4} is the most fundamental saturated perfluorocarbon, exhibiting complex optical behavior that is highly unusual for such a simple molecular system. We present Raman measurements in solid CF{sub 4} over a wide range in pressure from 1.6 to over 30 GPa at room temperature. The Raman spectra exhibit polarization-dependent intensity variations and history-dependent absence or presence of high pressure modes. Our results compellingly demonstrate that previously identified phase transitions in CF{sub 4} based on Raman signatures need to be reconsidered. Though our data suggest possible new high-pressure transitions, we do not identify new phases because of spectral complexity. Finally, we used the measured longitudinal and transverse optical mode splitting to estimate the dipole moment derivative at high pressures and find it close to that of gaseous CF{sub 4}.

Lorenzana, H E; Magnus, J L; Evans, W J; Hemmi, N



Metal Surface Decontamination by the PFC Solution  

SciTech Connect

PFC (per-fluorocarbon) spray decontamination equipment was fabricated and its decontamination behavior was investigated. Europium oxide powder was mixed with the isotope solution which contains Co-60 and Cs-137. The different shape of metal specimens artificially contaminated with europium oxide powder was used as the surrogate contaminants. Before and after the application of the PFC spray decontamination method, the radioactivity of the metal specimens was measured by MCA. The decontamination factors were in the range from 9.6 to 62.4. The spent PFC solution was recycled by distillation. Before and after distillation, the turbidity of PFC solution was also measured. From the test results, it was found that more than 98% of the PFC solution could be recycled by a distillation. (authors)

Hui-Jun Won; Gye-Nam Kim; Wang-Kyu Choi; Chong-Hun Jung; Won-Zin Oh [Korea Atomic Energy Research Institute - KAERI, P.O.Box 105, Yuseong, Daejeon, Korea, 305-353 (Korea, Republic of)



Buildings Energy Data Book: 5.3 Heating, Cooling, and Ventilation Equipment  

Buildings Energy Data Book (EERE)

4 4 Halocarbon Environmental Coefficients and Principal Uses 100-Year Global Ozone Depletion Warming Potential Potential (ODP) Compound (CO2 = 1) (Relative to CFC-11) Principal Uses Chlorofluorocarbons CFC-11 1.00 Blowing Agent, Chillers CFC-12 (1) 1.00 Auto A/C, Chillers, & Blowing Agent CFC-113 0.80 Solvent CFC-114 1.00 Solvent CFC-115 (2) 0.60 Solvent, Refrigerant Hydrochlorofluorocarbons HCFC-22 (2) 0.06 Residential A/C HCFC-123 0.02 Refrigerant HCFC-124 0.02 Sterilant HCFC-141b 0.11 CFC Replacement HCFC-142b 0.07 CFC Replacement Bromofluorocarbons Halon-1211 3.00 Fire Extinguishers Halon-1301 10.00 Fire Extinguishers Hydrofluorocarbons HFC-23 0.00 HCFC Byproduct HFC-125 0.00 CFC/HCFC Replacement HFC-134a 0.00 Auto A/C, Refrigeration HFC-152a (1) 0.00 Aerosol Propellant HFC-227ea 0.00 CFC Replacement


California's new mandatory greenhouse gas reporting regulation  

SciTech Connect

Beginning in early 2009, approximately 1000 California businesses will begin reporting their greenhouse gas (GHG) emissions based on the requirements of a new regulation adopted by the California Air Resources Board (CARB) in December 2007. California's mandatory GHG reporting regulation is the first rule adopted as a requirement of the Global Warming Solutions Act of 2006, passed by the California Legislature as Assembly Bill 32 (AB 32; Nunez, Chapter 488, Statutes of 2006) and signed by Governor Arnold Schwarzenegger in September 2006. The regulation is the first of its kind in the United States to require facilities to report annual GHG emissions. In general, all facilities subject to reporting are required to report their on-site stationary source combustion emissions of CO{sub 2}, nitrous oxide (N{sub 2}O), and methane (CH{sub 4}). Some industrial sectors, such as cement producers and oil refineries, also must report their process emissions, which occur from chemical or other noncombustion activities. Fugitive emissions from facilities are required to be reported when specified in the regulation. Sulfur hexafluoride (SF{sub 6}) and hydrofluorocarbon (HFC) use is prevalent in electricity facilities and must be reported. CO{sub 2} emissions from biomass-derived fuels must be separately identified during reporting, and reporters must also provide their consumption of purchased or acquired electricity and thermal energy; these requirements will assist facilities in evaluating changes in their fossil fuel carbon footprints. 1 tab.

Patrick Gaffney; Doug Thompson; Richard Bode [California Air Resources Board, CA (United States)



Passive Two-Phase Cooling of Automotive Power Electronics: Preprint  

SciTech Connect

Experiments were conducted to evaluate the use of a passive two-phase cooling strategy as a means of cooling automotive power electronics. The proposed cooling approach utilizes an indirect cooling configuration to alleviate some reliability concerns and to allow the use of conventional power modules. An inverter-scale proof-of-concept cooling system was fabricated, and tests were conducted using the refrigerants hydrofluoroolefin HFO-1234yf and hydrofluorocarbon HFC-245fa. Results demonstrated that the system can dissipate at least 3.5 kW of heat with 250 cm3 of HFC-245fa. An advanced evaporator design that incorporates features to improve performance and reduce size was conceived. Simulation results indicate its thermal resistance can be 37% to 48% lower than automotive dual side cooled power modules. Tests were also conducted to measure the thermal performance of two air-cooled condensers--plain and rifled finned tube designs. The results combined with some analysis were then used to estimate the required condenser size per operating conditions and maximum allowable system (i.e., vapor and liquid) temperatures.

Moreno, G.; Jeffers, J. R.; Narumanchi, S.; Bennion, K.



Global warming implications of non-fluorocarbon technologies as CFC replacements  

SciTech Connect

Many technologies could be developed for use in place of conventional compression systems for refrigeration and air conditioning. Comparisons of the global warming impacts using TEWI (Total Equivalent Warming Impact) can be used to identify alternatives that have the potential for lower environmental impacts than electric-driven vapor compression systems using HCFCs and HFCs. Some options, such as secondary heat transfer loops in commercial refrigeration systems to reduce refrigerant charge and emission rates, could be useful in reducing the losses of refrigerants to the atmosphere. Use of ammonia instead of a fluorocarbon in a system with a secondary loop offers only a small potential for decreasing TEWI, and this may not warrant the increased complexity and risks of using ammonia in a retail sales environment. A few technologies, such as adsorption heat pumps, have efficiency levels that show reduced TEWI levels compared to conventional and state of the art compression systems, and further development could lead to an even more favorable comparison. Health and safety risks of the alternative technologies and the materials they employ must also be considered.

Fischer, S.K.; Tomlinson, J.J.



Global warming and end-use efficiency implications of replacing CFCs  

SciTech Connect

The direct contribution of CFCs to calculated global warming has been recognized for some time. As a result of the international agreement to phase out CFCs due to stratospheric ozone and the ensuing search for suitable alternatives, there has recently been increased attention on the DIRECT global warming potential (GWP) of the fluorocarbon alternatives as greenhouse gases. However, to date there has been little focus on the INDIRECT global warming effect arising from end-use efficiency changes and associated CO{sub 2} emissions. A study being conducted at Oak Ridge National Laboratory (ORNL) addresses this combined or total global warming impact of viable options to replace CFCs in their major energy-related applications. This paper reviews selected results for air-conditioning, refrigeration, and heat pump applications. The analysis indicates that the CFC user industries have made substantial progress in approaching near-equal energy efficiency with the HCFC/HFC alternative refrigerants. The findings also bring into question the relative importance of the DIRECT (chemical-related) effect in many applications. Replacing CFCs is an important step in reducing the total global warming impact, and at present the HCFC and HFCS appear to offer the best efficiency and lowest total impact of options available in the relatively short time period required for the transition away from CFCs.

Fairchild, P.D.; Fischer, S.K.



Final report on activities and findings under DOE grant Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases  

SciTech Connect

Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

Prather, Michael J. [UCI



Buildings Energy Data Book: 5.3 Heating, Cooling, and Ventilation Equipment  

Buildings Energy Data Book (EERE)

6 6 Estimated U.S. Emissions of Halocarbons, 1987-2001 (MMT CO2 Equivalent) Gas 1987 1990 1992 1995 1998 2000 2001 Chlorofluorocarbons CFC-11 391 246 207 167 115 105 105 CFC-12 1,166 1,194 853 549 223 182 226 CFC-113 498 158 103 52 0 0 0 CFC-114 N.A. 46 29 16 1 N.A. N.A. CFC-115 N.A. 30 27 22 19 N.A. N.A. Bromofluorocarbons Halon-1211 N.A. 1 1 1 1 N.A. N.A. Halon-1301 N.A. 12 12 12 13 N.A. N.A. Hydrochlorofluorocarbons HCFC-22 116 136 135 123 128 134 137 HCFC-123 N.A. 0 0 0 0 N.A. N.A. HCFC-124 0 0 0 3 4 N.A. N.A. HCFC-141b N.A. 0 0 14 19 4 4 HCFC-142b N.A. 0 2 18 22 26 26 Hydrofluorocarbons HFC-23 48 36 36 28 41 31 22 HFC-125 N.A. 0 1 2 4 5 6 HFC-134a N.A. 1 1 19 35 44 41 Total 2,219 1,861 1,408 1,024 624 532 566 Source(s): Intergovernmental Panel for Climate Change, Climate Change 2001: The Scientific Basis, Jan. 2001, Table 3, p. 47 for GWPs; EIA, Emissions of Greenhouse Gases in the U.S. 2001, Dec. 2002, Table 29, p. 71 and Table D2, p. D-5 for 1990-2001 emissions; EPA, Inventory of U.S. Greenhouse Gas Emissions and


Atmospheric chemistry of FO[sub 2] radicals. Reaction with Ch[sub 4], O[sub 3], NO, NO[sub 2], and CO at 295 K  

SciTech Connect

Using pulse radiolysis combined with UV absorption spectroscopy, upper limits for the rate constants of the reaction of the FO[sub 2] radical with O[sub 3], CH[sub 4], and CO were determined to be <3.4 x 10[sup [minus]16], <4.1 x 10[sup [minus]15], and <5.1 x 10[sup [minus]16] cm[sup 3] molecule[sup [minus]1] s[sup [minus]1], respectively. The rate constants for the reactions of FO[sub 2] radicals with NO and NO[sub 2] were measured: FO[sub 2] + NO [yields] FNO + O[sub 2] (10a); FO[sub 2] + NO[sub 2] [yields] products (11). The rate constants for reactions 10 and 11 were determined to be (1.47 [+-] 0.08) x 10[sup [minus]12] and (1.05 [+-] 0.15) x 10[sup [minus]13] cm[sup 3] molecule[sup [minus]1] s[sup [minus]1], respectively. Reaction 10a was found to give FNO in a yield of 100 [+-] 14%. As a part of this work, an upper limit of the reaction of FO radicals with O[sub 3] was determined to be <1.2 x 10[sup [minus]12] cm[sup 3] molecule[sup [minus]1] s[sup [minus]1]. Results are discussed in the context of the atmospheric chemistry of the FO[sub 2] radical and hydrofluorocarbons. 23 refs., 12 figs., 2 tabs.

Sehested, J.; Sehested, K.; Nielsen, O.J. (Riso National Lab., Roskilde (Denmark)); Wallington, T.J. (Ford Motor Company, Dearborn, MI (United States))



An Evaluation of the Environmental Impact of Different Commercial Supermarket Refrigeration Systems Using Low Global Warming Potential Refrigerants  

SciTech Connect

Commercial refrigeration systems consumed 1.21 Quads of primary energy in 2010 and are known to be a major source for refrigerant charge leakage into the environment. Thus, it is important to study the environmental impact of commercial supermarket refrigeration systems and improve their design to minimize any adverse impacts. The system s Life Cycle Climate Performance (LCCP) was presented as a comprehensive metric with the aim of calculating the equivalent mass of carbon dioxide released into the atmosphere throughout its lifetime, from construction to operation and destruction. In this paper, an open source tool for the evaluation of the LCCP of different air-conditioning and refrigeration systems is presented and used to compare the environmental impact of a typical multiplex direct expansion (DX) supermarket refrigeration systems based on three different refrigerants as follows: two hydrofluorocarbon (HFC) refrigerants (R-404A, and R-407F), and a low global warming potential (GWP) refrigerant (N-40). The comparison is performed in 8 US cities representing different climates. The hourly energy consumption of the refrigeration system, required for the calculation of the indirect emissions, is calculated using a widely used building energy modeling tool (EnergyPlus). A sensitivity analysis is performed to determine the impact of system charge and power plant emission factor on the LCCP results. Finally, we performed an uncertainty analysis to determine the uncertainty in total emissions for both R-404A and N-40 operated systems. We found that using low GWP refrigerants causes a considerable drop in the impact of uncertainty in the inputs related to direct emissions on the uncertainty of the total emissions of the system.

Beshr, Mohamed [University of Maryland, College Park; Aute, Vikrant [University of Maryland, College Park; Abdelaziz, Omar [ORNL; Fricke, Brian A [ORNL; Radermacher, Reinhard [University of Maryland, College Park



TheU-Tube: A Novel System for Acquiring Borehole Fluid Samplesfrom a Deep Geologic CO2 Sequestration Experiment  

SciTech Connect

A novel system has been deployed to obtain geochemical samples of water and gas, at in situ pressure, during a geologic CO2 sequestration experiment conducted in the Frio brine aquifer in Liberty County, Texas. Project goals required high-frequency recovery of representative and uncontaminated aliquots of a rapidly changing two-phase (supercritical CO2-brine) fluid from 1.5 km depth. The datasets collected, using both the liquid and gas portions of the downhole samples, provide insights into the coupled hydro-geochemical issues affecting CO2 sequestration in brine-filled formations. While the basic premise underlying the U-Tube sampler is not new, the system is unique because careful consideration was given to the processing of the recovered two-phase fluids. In particular, strain gauges mounted beneath the high-pressure surface sample cylinders measured the ratio of recovered brine to supercritical CO2. A quadrupole mass spectrometer provided real-time gas analysis for perfluorocarbon and noble gas tracers that were injected along with the CO2. The U-Tube successfully acquired frequent samples, facilitating accurate delineation of the arrival of the CO2 plume, and on-site analysis revealed rapid changes in geochemical conditions.

Freifeld, Barry M.; Trautz, Robert C.; Kharaka, Yousif K.; Phelps, Tommy J.; Myer, Larry R.; Hovorka, Susan D.; Collins, Daniel J.



Taggants, method for forming a taggant, and a method for detecting an object  

DOE Patents (OSTI)

A taggant comprising at least one perfluorocarbon compound surrounded by a polyphosphazene compound. The polyphosphazene compound has the chemical structure: ##STR00001## wherein G.sub.1 and G.sub.2 are pendant groups having different polarities, m is an integer greater than or equal to 100, and each of A and B is independently selected from hydrogen, an alkyl, an alkene, an alkoxide, a polyether, a polythioether, a siloxane, and --X(CH.sub.2).sub.nY.sup.1(CH.sub.2)p.sub.1Y.sup.2(CH.sub.2)p.sub.2 . . . Y.sup.i(CH.sub.2)p.sub.iCH.sub.3, where n ranges from 1 to 6, X and Y are independently selected from oxygen, sulfur, selenium, tellurium, and polonium, and p.sub.1 through p.sub.i range from 1 to 6. Cyclic polyphosphazene compounds lacking the A and B groups are also disclosed, as are methods of forming the taggant and of detecting an object.

Harrup, Mason K. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID)




SciTech Connect

The Florida Footprint experiments were a series of field programs in which perfluorocarbon tracers were released in different configurations centered on a flux tower to generate a data set that can be used to test transport and dispersion models. These models are used to determine the sources of the CO{sub 2} that cause the fluxes measured at eddy covariance towers. Experiments were conducted in a managed slash pine forest, 10 km northeast of Gainesville, Florida, in 2002, 2004, and 2006 and in atmospheric conditions that ranged from well mixed, to very stable, including the transition period between convective conditions at midday to stable conditions after sun set. There were a total of 15 experiments. The characteristics of the PFTs, details of sampling and analysis methods, quality control measures, and analytical statistics including confidence limits are presented. Details of the field programs including tracer release rates, tracer source configurations, and configuration of the samplers are discussed. The result of this experiment is a high quality, well documented tracer and meteorological data set that can be used to improve and validate canopy dispersion models.




Uncertainties in Air Exchange using Continuous-Injection, Long-Term Sampling Tracer-Gas Methods  

SciTech Connect

The PerFluorocarbon Tracer (PFT) method is a low-cost approach commonly used for measuring air exchange in buildings using tracer gases. It is a specific application of the more general Continuous-Injection, Long-Term Sampling (CILTS) method. The technique is widely used but there has been little work on understanding the uncertainties (both precision and bias) associated with its use, particularly given that it is typically deployed by untrained or lightly trained people to minimize experimental costs. In this article we will conduct a first-principles error analysis to estimate the uncertainties and then compare that analysis to CILTS measurements that were over-sampled, through the use of multiple tracers and emitter and sampler distribution patterns, in three houses. We find that the CILTS method can have an overall uncertainty of 10-15percent in ideal circumstances, but that even in highly controlled field experiments done by trained experimenters expected uncertainties are about 20percent. In addition, there are many field conditions (such as open windows) where CILTS is not likely to provide any quantitative data. Even avoiding the worst situations of assumption violations CILTS should be considered as having a something like a ?factor of two? uncertainty for the broad field trials that it is typically used in. We provide guidance on how to deploy CILTS and design the experiment to minimize uncertainties.

Sherman, Max H.; Walker, Iain S.; Lunden, Melissa M.



Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water  

SciTech Connect

The isomerization of glucose into fructose is a large-scale reaction for the production of high-fructose corn syrup (HFCS; reaction performed by enzyme catalysts) and recently is being considered as an intermediate step in the possible route of biomass to fuels and chemicals. Here, it is shown that a large-pore zeolite that contains tin (Sn-Beta) is able to isomerize glucose to fructose in aqueous media with high activity and selectivity. Specifically, a 10% (wt/wt) glucose solution containing a catalytic amount of Sn-Beta (1?50 Sn:glucose molar ratio) gives product yields of approximately 46% (wt/wt) glucose, 31% (wt/wt) fructose, and 9% (wt/wt) mannose after 30 min and 12 min of reaction at 383 K and 413 K, respectively. This reactivity is achieved also when a 45 wt% glucose solution is used. The properties of the large-pore zeolite greatly influence the reaction behavior because the reaction does not proceed with a medium-pore zeolite, and the isomerization activity is considerably lower when the metal centers are incorporated in ordered mesoporous silica (MCM-41). The Sn-Beta catalyst can be used for multiple cycles, and the reaction stops when the solid is removed, clearly indicating that the catalysis is occurring heterogeneously. Most importantly, the Sn-Beta catalyst is able to perform the isomerization reaction in highly acidic, aqueous environments with equivalent activity and product distribution as in media without added acid. This enables Sn-Beta to couple isomerizations with other acid-catalyzed reactions, including hydrolysis/isomerization or isomerization/dehydration reaction sequences [starch to fructose and glucose to 5-hydroxymethylfurfural (HMF) demonstrated here].

Moliner, Manuel; Roman-Leshkov, Yuriy; Davis, Mark E.



Carbothermal reduction of alumina: Thermochemical equilibrium calculations and experimental investigation  

Science Journals Connector (OSTI)

The production of aluminum by the electrolytic HallHroult process suffers from high energy requirements, the release of perfluorocarbons, and vast greenhouse gas emissions. The alternative carbothermic reduction of alumina, while significantly less energy-intensive, is complicated by the formation of aluminum carbide and oxycarbides. In the present work, the formation of Al, as well as Al2OC, Al4O4C, and Al4C3 was proven by experiments on mixtures of Al2O3 and activated carbon in an Ar atmosphere submitted to heat pulses by an induction furnace. Thermochemical equilibrium calculations indicate that the Al2O3-reduction using carbon as reducing agent is favored in the presence of limited amounts of oxygen. The temperature threshold for the onset of aluminum production is lowered, the formation of Al4C3 is decreased, and the yield of aluminum is improved. Significant further enhancement in the carbothermic reduction of Al2O3 is predicted by using CH4 as the reducing agent, again in the presence of limited amounts of oxygen. In this case, an important by-product is syngas, with a H2/CO molar ratio of about 2, suitable for methanol or FischerTropsch syntheses. Under appropriate temperature and stoichiometry of reactants, the process can be designed to be thermo-neutral. Using alumina, methane, and oxygen as reagents, the co-production of aluminum with syngas, to be converted to methanol, predicts fuel savings of about 68% and CO2 emission avoidance of about 91%, vis--vis the conventional production of Al by electrolysis and of methanol by steam reforming of CH4. When using carbon (such as coke or petcoke) as reducing agent, fuel savings of 66% and CO2 emission avoidance of 15% are predicted. Preliminary evaluation for the proposed process indicates favorable economics, and the required high temperatures process heat is readily attainable using concentrated solar energy.

M. Halmann; A. Frei; A. Steinfeld



Bubble departure in the direct-contact boiling field with a continuous liquid-liquid interface  

SciTech Connect

Behavior of vapor bubbles was experimentally investigated in the boiling field where a volatile liquid layer of per-fluorocarbon PF5050 (boiling point 306K) was directly in contact with an immiscible hot liquid layer of water above it. Heat was supplied to the continuous liquid-liquid interface by the impingement of the downward hot water jet. Vapor bubbles were generated not only from this continuous interface but from a large number of PF5050 droplets floating on it. According to precise observation, incipience of boiling did not occur at the liquid-liquid interface but in the PF5050 liquid close to the interface in both cases of continuous and dispersed interfaces. As a result, the bubbles broke up the thin PF5050 liquid film above them and rose up into the water layer. This bubble departure phenomenon, which does not occur in the ordinary pool boiling field on the solid heating wall, is very important to evaluate the heat transfer performance in the present direct-contact boiling system. For modeling this behavior, sizes of the bubbles were measured at the moment just after they were released into the water pool. Volumes of the bubbles were larger in the case of departing from the continuous liquid-liquid interface than from the droplets. This tendency could be explained by taking into account the buoyancy force acting on unit area of the thin PF5050 liquid film above the bubble before departure, which was one of the most important parameters for the liquid film breakdown. (author)

Kadoguchi, Katsuhiko [Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki 305-8569 (Japan)



Evaluation of metrics and baselines for tracking greenhouse gas emissions trends: Recommendations for the California climate action registry  

SciTech Connect

Executive Summary: The California Climate Action Registry, which was initially established in 2000 and began operation in Fall 2002, is a voluntary registry for recording annual greenhouse gas (GHG) emissions. The purpose of the Registry is to assist California businesses and organizations in their efforts to inventory and document emissions in order to establish a baseline and to document early actions to increase energy efficiency and decrease GHG emissions. The State of California has committed to use its ''best efforts'' to ensure that entities that establish GHG emissions baselines and register their emissions will receive ''appropriate consideration under any future international, federal, or state regulatory scheme relating to greenhouse gas emissions.'' Reporting of GHG emissions involves documentation of both ''direct'' emissions from sources that are under the entity's control and indirect emissions controlled by others. Electricity generated by an off-site power source is consider ed to be an indirect GHG emission and is required to be included in the entity's report. Registry participants include businesses, non-profit organizations, municipalities, state agencies, and other entities. Participants are required to register the GHG emissions of all operations in California, and are encouraged to report nationwide. For the first three years of participation, the Registry only requires the reporting of carbon dioxide (CO2) emissions, although participants are encouraged to report the remaining five Kyoto Protocol GHGs (CH4, N2O, HFCs, PFCs, and SF6). After three years, reporting of all six Kyoto GHG emissions is required. The enabling legislation for the Registry (SB 527) requires total GHG emissions to be registered and requires reporting of ''industry-specific metrics'' once such metrics have been adopted by the Registry. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) was asked to provide technical assistance to the California Energy Commission (Energy Commission) related to the Registry in three areas: (1) assessing the availability and usefulness of industry-specific metrics, (2) evaluating various methods for establishing baselines for calculating GHG emissions reductions related to specific actions taken by Registry participants, and (3) establishing methods for calculating electricity CO2 emission factors. The third area of research was completed in 2002 and is documented in Estimating Carbon Dioxide Emissions Factors for the California Electric Power Sector (Marnay et al., 2002). This report documents our findings related to the first areas of research. For the first area of research, the overall objective was to evaluate the metrics, such as emissions per economic unit or emissions per unit of production that can be used to report GHG emissions trends for potential Registry participants. This research began with an effort to identify methodologies, benchmarking programs, inventories, protocols, and registries that u se industry-specific metrics to track trends in energy use or GHG emissions in order to determine what types of metrics have already been developed. The next step in developing industry-specific metrics was to assess the availability of data needed to determine metric development priorities. Berkeley Lab also determined the relative importance of different potential Registry participant categories in order to asses s the availability of sectoral or industry-specific metrics and then identified industry-specific metrics in use around the world. While a plethora of metrics was identified, no one metric that adequately tracks trends in GHG emissions while maintaining confidentiality of data was identified. As a result of this review, Berkeley Lab recommends the development of a GHG intensity index as a new metric for reporting and tracking GHG emissions trends.Such an index could provide an industry-specific metric for reporting and tracking GHG emissions trends to accurately reflect year to year changes while protecting proprietary data. This GHG intensity index changes

Price, Lynn; Murtishaw, Scott; Worrell, Ernst


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SciTech Connect

This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of industrial mitigation for sustainable development is discussed in Section 7.7. Section 7.8 discusses the sector's vulnerability to climate change and options for adaptation. A number of policies have been designed either to encourage voluntary GHG emission reductions from the industrial sector or to mandate such reductions. Section 7.9 describes these policies and the experience gained to date. Co-benefits of reducing GHG emissions from the industrial sector are discussed in Section 7.10. Development of new technology is key to the cost-effective control of industrial GHG emissions. Section 7.11 discusses research, development, deployment and diffusion in the industrial sector and Section 7.12, the long-term (post-2030) technologies for GHG emissions reduction from the industrial sector. Section 7.13 summarizes gaps in knowledge.

Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia