Sample records for hydrocarbons unfinished oils

  1. HYDROCARBONS FROM AUSTRALIAN OIL, 200 MILLION YEARS OLD

    E-Print Network [OSTI]

    Van Hoeven, William; Haug, Pat; Burlingame, A.L.; Calvin, Kelvin.

    1966-01-01T23:59:59.000Z

    of Moonie Oil "Branched- Cyclic" Hydrocarbon FractionNo. W -7405 -eng -48 HYDROCARBONS FROM AUSTRALIAN OIL, 200and Melvin Calvin July HYDROCARBONS FROM AUSTRALIAN OIL, 200

  2. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  3. Oil & Chemical Pollution 6 (19'X)} 81-Hydrocarbon Pollution of

    E-Print Network [OSTI]

    Canberra, University of

    distribution offuel distillates is evident with only a small contribution from lubricating and heavier oilOil & Chemical Pollution 6 (19'X)} 81- pollution as all oils contain aromatic hydrocarbons while few, if any, biogenic aromatic hydrocarbons

  4. BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons

    E-Print Network [OSTI]

    Toohey, Darin W.

    BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons NOAA and CIRES here at CU went to the oil spill in an aircraft that was equipped with instruments to measure the air quality. 1/3 of the oil dissolved into the water column (methane completely, benzene and ethane almost completely) Showed

  5. Hydrocarbon analysis of shrimp from oil polluted waters

    E-Print Network [OSTI]

    DeWitt, Bernard John

    1982-01-01T23:59:59.000Z

    is unaccounted for (Anon. , 1980b). This oil, plus oil from other sources, could become a potential threat to the Gulf shrimp industry. One problem concerning shrimp is that all Gulf shrimp are harvested using a bottom trawl. Tar, or weathered oil, collects...HYDROCARBON ANALYSIS OF SHRIMP FROM OIL POLLUTED WATERS A Thesis by BERNARD JOHN DEWITT III Submitted to the Graduate College of Texas A&M University in partial fulfilment of the requirement for the degree of MASTER OF SCIENCE May 1982...

  6. Removal of particulate solids from a hot hydrocarbon slurry oil

    SciTech Connect (OSTI)

    Rush, J.B.

    1991-12-31T23:59:59.000Z

    This patent describes a method of treating a hot, refractory hydrocarbon slurry oil having an initial boiling point at atmospheric pressure at least as high as 500{degrees} F and having a gravity of from about 5{degrees} API to about 15{degrees} API, to remove solid particulate material the slurry oil. It comprises mixing with the hot slurry oil, a hot vacuum reduced crude oil having an initial boiling point at atmospheric pressure which is higher than the initial boiling plant at atmospheric pressure of the slurry oil, and having an end point at atmospheric pressure which is higher than the end point at atmospheric pressure of the slurry oil; charging the mixture of hot vacuum reduced crude oil and hot slurry oil to a vacuum flash zone having a pressure of from 1.0 mm Hg to about 10.0 mm Hg and at the selected temperature of less than 700{degrees} F and more than 300{degrees} F to thereby vaporize a major portion of the slurry oil in the mixture, and to thereby transfer substantially all of the solid particulate material into the bottoms liquid remaining in the flash zone following the completion of the vaporization; recovering the overhead; and recovering the liquid bottoms containing the solid particulate material.

  7. Production of valuable hydrocarbons by flash pyrolysis of oil shale

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.T.

    1985-04-01T23:59:59.000Z

    A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

  8. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Luyendyk, Bruce

    geology and gas-phase (methane) seepage for the Coal Oil Point (COP) seep field, one of the worldORIGINAL Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field's largest and best-studied marine oil and gas seep fields, located over a producing hydrocarbon reservoir

  9. Oil and Gas CDT Quantifying the role of groundwater in hydrocarbon systems using noble gas

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Quantifying the role of groundwater in hydrocarbon systems using noble gas isotopes by groundwater (or oil) degassing. Other natural gas fields may have been produced in-situ or migrated as a free expert academics from across the CDT and also experienced oil and gas industry professionals

  10. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  11. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  12. The effect of chemical dispersants on the solution of volatile liquid hydrocarbons from spilled crude oil

    E-Print Network [OSTI]

    McDonald, Thomas Joseph

    1982-01-01T23:59:59.000Z

    THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1982 Major Subject: Oceanography THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Approved as to style and content by...

  13. The effect of chemical dispersants on the solution of volatile liquid hydrocarbons from spilled crude oil 

    E-Print Network [OSTI]

    McDonald, Thomas Joseph

    1982-01-01T23:59:59.000Z

    THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1982 Major Subject: Oceanography THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Approved as to style and content by...

  14. Hydrocarbon accumulation on rifted Continental Margin - examples of oil migration pathways, west African salt basins

    SciTech Connect (OSTI)

    Blackwelder, B.W.

    1989-03-01T23:59:59.000Z

    Examination of the oil fields in the Gabon, Lower Congo, and Cuanza basins allows modeling of oil migration and a more accurate ranking of prospects using geologic risk factors. Oil accumulations in these basins are in strata deposited during Cretaceous rift and drift phases, thus providing a diversity of geologic settings to examine. Oil accumulations in rift deposits are located on large faulted anticlines or in truncated units atop horst features. Many of these oil fields were sourced from adjacent organic shales along short direct migration paths. In Areas where source rock is more remote to fields or to prospective structures, faulting and continuity of reservoir rock are important to the migration of hydrocarbons. Because Aptian salts separate rift-related deposits from those of the drift stage, salt evacuation and faulting of the salt residuum are necessary for oil migration from the pre-salt sequences into the post-salt section. Oil migration within post-salt strata is complicated by the presence of salt walls and faulted carbonate platforms. Hydrocarbon shows in wells drilled throughout this area provide critical data for evaluating hydrocarbon migration pathways. Such evaluation in combination with modeling and mapping of the organic-rich units, maturation, reservoir facies, structural configurations, and seals in existing fields allows assessment of different plays. Based on this information, new play types and prospective structures can be ranked with respect to geologic risk.

  15. Hydrocarbon analysis of shrimp from oil polluted waters 

    E-Print Network [OSTI]

    DeWitt, Bernard John

    1982-01-01T23:59:59.000Z

    and approximately 2, 000 barrels per day until it was finally capped (Anon, , 1980a). Ixtoc I, the worlds' largest oil spill, was fi- nally capped on March 24, 1980, after spilling over 2. 6 million barrels of oil into the Gulf of Mexico, most of which... in the transoceanic shipment of crude oil, as well as increased offshore exploratory drilling. This demand has led to several major oil spills such as the wreck of the "Torrey Can- yon" off the coast of England which released 100, 000 tons of crude oil (Blumer...

  16. BIOTIGER, A NATURAL MICROBIAL PRODUCT FOR ENHANCED HYDROCARBON RECOVERY FROM OIL SANDS.

    SciTech Connect (OSTI)

    Brigmon, R; Topher Berry, T; Whitney Jones, W; Charles Milliken, C

    2008-05-27T23:59:59.000Z

    BioTiger{trademark} is a unique microbial consortia that resulted from over 8 years of extensive microbiology screening and characterization of samples collected from a century-old Polish waste lagoon. BioTiger{trademark} shows rapid and complete degradation of aliphatic and aromatic hydrocarbons, produces novel surfactants, is tolerant of both chemical and metal toxicity and shows good activity at temperature and pH extremes. Although originally developed and used by the U.S. Department of Energy for bioremediation of oil-contaminated soils, recent efforts have proven that BioTiger{trademark} can also be used to increase hydrocarbon recovery from oil sands. This enhanced ex situ oil recovery process utilizes BioTiger{trademark} to optimize bitumen separation. A floatation test protocol with oil sands from Ft. McMurray, Canada was used for the BioTiger{trademark} evaluation. A comparison of hot water extraction/floatation test of the oil sands performed with BioTiger{trademark} demonstrated a 50% improvement in separation as measured by gravimetric analysis in 4 h and a five-fold increase at 25 hr. Since BioTiger{trademark} performs well at high temperatures and process engineering can enhance and sustain metabolic activity, it can be applied to enhance recovery of hydrocarbons from oil sands or other complex recalcitrant matrices.

  17. In situ method for recovering hydrocarbon from subterranean oil shale deposits

    SciTech Connect (OSTI)

    Friedman, R.H.

    1987-11-03T23:59:59.000Z

    This patent describes in situ method for recovering hydrocarbons from subterranean oil shale deposits, the deposits comprising mineral rock and kerogen, comprising (a) penetrating the oil shale deposit with at least one well; (b) forming a zone of fractured and/or rubbilized oil shale material adjacent the well by hydraulic or explosive fracturing; (c) introducing a hydrogen donor solvent including tetralin into the portion of the oil shale formation treated in step (b) in a volume sufficient to fill substantially all of the void space created by the fracturing and rubbilizing treatment; (d) applying hydrogen to the tetralin and maintaining a predetermined pressure for a predetermined period of time sufficient to cause disintegration of the oil shale material; (e) thereafter introducing an oxidative environment into the portion of the oil shale deposit (f) producing the solvent in organic fragments to the surface of the earth, and (g) separating the organic fragments from the solvent.

  18. Process for recovering uranium from waste hydrocarbon oils containing the same. [Uranium contaminated lubricating oils from gaseous diffusion compressors

    DOE Patents [OSTI]

    Conrad, M.C.; Getz, P.A.; Hickman, J.E.; Payne, L.D.

    1982-06-29T23:59:59.000Z

    The invention is a process for the recovery of uranium from uranium-bearing hydrocarbon oils containing carboxylic acid as a degradation product. In one aspect, the invention comprises providing an emulsion of water and the oil, heating the same to a temperature effecting conversion of the emulsion to an organic phase and to an acidic aqueous phase containing uranium carboxylate, and recovering the uranium from the aqueous phase. The process is effective, simple and comparatively inexpensive. It avoids the use of toxic reagents and the formation of undesirable intermediates.

  19. Effectiveness of in site biodegradation for the remediation of polycyclic aromatic hydrocarbons at a contaminated oil refinery, Port Arthur, Texas

    E-Print Network [OSTI]

    Moffit, Alfred Edward

    2000-01-01T23:59:59.000Z

    The effectiveness of bioremediation for the removal of polycyclic aromatic hydrocarbons (PAHs) from sediments contaminated with highly weathered petroleum was evaluated at a contaminated oil refinery. The sediments were chronically contaminated...

  20. Hydrocarbon biomarkers, thermal maturity, and depositional setting of tasmanite oil shales from Tasmania, Australia

    SciTech Connect (OSTI)

    Revill, A.T.; Volkman, J.K.; O'Leary, T. (CSIRO Division of Oceanography, Tasmania (Australia)); Summons, R.E.; Boreham, C.J. (Australian Geological Survey Organisation, Canberra (Australia)); Banks, M.R.; Denwer, K. (Univ. of Tasmania (Australia))

    1994-09-01T23:59:59.000Z

    This study represents the first geological and organic geochemical investigation of samples of tasmanite oil shale representing different thermal maturities from three separate locations in Tasmania, Australia. The most abundant aliphatic hydrocarbon in the immature oil shale from Latrobe is a C[sub 19] tricyclic alkane, whereas in the more mature samples from Oonah and Douglas River low molecular weight n-alkanes dominate the extractable hydrocarbon distribution. The aromatic hydrocarbons are predominantly derivatives of tricyclic compounds, with 1,2,8-trimethylphenanthrene increasing in relative abundance with increasing maturity. Geological and geochemical evidence suggests that the sediments were deposited in a marine environment of high latitude with associated cold waters and seasonal sea-ice. It is proposed that the organism contributing the bulk of the kerogen, Tasmanites, occupied an environmental niche similar to that of modern sea-ice diatoms and that bloom conditions coupled with physical isolation from atmospheric CO[sub 2] led to the distinctive [open quotes]isotopically heavy[close quotes] [delta][sup 13]C values for the kerogen. [delta][sup 13]C data from modern sea-ice diatoms supports this hypothesis. Isotopic analysis of n-alkanes in the bitumen suggests a multiple source from bacteria and algae. On the other hand, the n-alkanes generated from closed-system pyrolysis of the kerogen are mainly derived from the preserved Tasmanites biopolymer algaenan. The tricyclic compounds (mean -8[per thousand]) both in the bitumen and pyrolysate, have a common precursor. They are consistently enriched in [sup 13]C compared with the kerogen and probably have a different source from the n-alkanes. The identification of a location where the maturity of the tasmanite oil shale approaches the [open quotes]oil window[close quotes] raises the possibility that it may be a viable petroleum source rock.

  1. A three-phase K-value study for pure hydrocarbons/water and crude oil/water systems

    E-Print Network [OSTI]

    Lanclos, Ritchie Paul

    1990-01-01T23:59:59.000Z

    A THREE-PHASE K-VALUE STUDY FOR PURE HYDROCARBONS/WATER AND CRUDE OIL/WATER SYSTEMS A Thesis by RITCHIE PAUL LANCLOS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... of Committee) P. T. Eubank (Member) R. A. Wattenbar (Member) W. D. Von Gonten (Member) December 1990 ABSTRACT A Three-Phase K-Value Study for Pure Hydrocarbons/Water and Crude Oil/Water Systems Ritchie Paul Lanclos, B. S. , University...

  2. DAPRPA Grand Challenge, Unfinished Business, November 1, 2005 Back & Forth

    E-Print Network [OSTI]

    Singh, Jaswinder Pal

    DAPRPA Grand Challenge, Unfinished Business, November 1, 2005 Back & Forth Return to Beer Bottle Pass Route to/from Beer Bottle Pass from Start of 2005 GC Course #12;DAPRPA Grand Challenge, Unfinished Business, November 1, 2005 Return to Beer Bottle Pass GPS tracks of route to/from Beer Bottle Pass #12

  3. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    molecular weights of various hydrocarbon materials for fuelof oil and alcohol from hydrocarbon-producing plants. Into Die Naturwissenschaften HYDROCARBONS FROM PLANTS: METHODS

  4. Relationship between hydrocarbon measurements and toxicity to a chironomid, fish larva and daphnid for oils and oil spill chemical

    E-Print Network [OSTI]

    Nyman, John

    the extent to which various common hydrocarbon measures can be used to predict toxicity to fresh- water microcosms using two water- column species and a benthic species, were described earlier. The hydrocarbon, and aromatics; specific individual polycyclic aromatic hydrocarbons (PAHs), and the sum of various PAH subsets

  5. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-05-04T23:59:59.000Z

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreatingmore »the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.« less

  6. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Douglas C. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Wang, Huamin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Rover, Majorie [Iowa State University, Ames, IA (United States); Whitmer, Lysle [Iowa State University, Ames, IA (United States); Smith, Ryan [Iowa State University, Ames, IA (United States); Brown, Robert C. [Iowa State University, Ames, IA (United States)

    2015-05-04T23:59:59.000Z

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreating the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.

  7. Third-Party Evaluation of Petro Tex Hydrocarbons, LLC, ReGen Lubricating Oil Re-refining Process

    SciTech Connect (OSTI)

    Compere, A L [ORNL; Griffith, William {Bill} L [ORNL

    2009-04-01T23:59:59.000Z

    This report presents an assessment of market, energy impact, and utility of the PetroTex Hydrocarbons, LLC., ReGen process for re-refining used lubricating oil to produce Group I, II, and III base oils, diesel fuel, and asphalt. PetroTex Hydrocarbons, LLC., has performed extensive pilot scale evaluations, computer simulations, and market studies of this process and is presently evaluating construction of a 23 million gallon per year industrial-scale plant. PetroTex has obtained a 30 acre site in the Texas Industries RailPark in Midlothian Texas. The environmental and civil engineering assessments of the site are completed, and the company has been granted a special use permit from the City of Midlothian and air emissions permits for the Texas Commission on Environmental Quality.

  8. Experimental and analytical modeling studies of steam injection with hydrocarbon additives to enhance recovery of San Ardo heavy oil

    E-Print Network [OSTI]

    Simangunsong, Roly

    2006-10-30T23:59:59.000Z

    thanks also go to my good friend, Zuher Syihab, who, possibly without realizing it, taught me that learning is more than just a grade. This research was conducted under the Ramey Laboratory Research Program (2004) and the Crisman Institute...-Garnica (2004)16 performed distillation experiments on synthetic oil, showing that propane effectively reduces the boiling point of hydrocarbons. Thus, yields are higher with steam-propane, followed by that of pure steam injection, and lowest under dry...

  9. Pattern of explosive reaction between uranium hexafluoride and hydrocarbon oils. Revision 1

    SciTech Connect (OSTI)

    Rapp, K.E.

    1986-03-21T23:59:59.000Z

    Examination of uranium hexafluoride release incidents occurring over the past three decades of ORGDP experience has identified only four which apparently involved an explosion of a container resulting from reaction between uranium hexafluoride and an impurity. These four incidents exhibit a certain degree of commonality. Each has involved: (1) condensed phase uranium hexafluoride, (2) a moderately elevated temperature, (3) a sufficient quantity of uranium hexafluoride for a significant partial pressure to be maintained independently above that which can be consumed by chemical reaction, and (4) an organic liquid (probably hydrocarbon oil) accidentally present in the container as a contaminant. The purpose of this investigative search was to establish some conditional pattern for these four incidents to which their violent consequences could be attributed. Fortunately, the number of such incidents is relatively small, which emphasizes even more pointedly the unfortunate fact that documentation ranges from thorough to very limited. Documented sources of information are given in the bibliography. Copies of those which are not readily available are contained in six appendices. 8 refs.

  10. UK Oil and Gas Collaborative Doctoral Training Centre (2014 start) Project Title: Quantifying the role of groundwater in hydrocarbon systems using noble gas

    E-Print Network [OSTI]

    Henderson, Gideon

    UK Oil and Gas Collaborative Doctoral Training Centre (2014 start) Project Title: Quantifying the role of groundwater in hydrocarbon systems using noble gas isotopes (EARTH-15-CB1) Host institution biodegradation of oil can remove its value ­ but what controls the biodegradation? The deep biosphere plays a key

  11. Advanced emission-speciation methodologies for the Auto/Oil Air Quality Improvement Research Program. 1. Hydrocarbons and ethers

    SciTech Connect (OSTI)

    Jensen, T.E.; Siegl, W.O.; Lipari, F.; Loo, J.F.; Sigsby, J.E.

    1992-01-01T23:59:59.000Z

    An analytical method for the determination of hydrocarbon and ether emissions from gasoline-, methanol-, and flexible-fueled vehicles is described. This method was used in Phase I of the Auto/Oil Air Quality Improvement Research Program to provide emissions data for various vehicles using individual reformulated gasolines and alternate fuels. These data would then be used for air modeling studies. Emission samples for tailpipe, evaporative, and running loss were collected in Tedlar bags. Gas chromatographic analysis of the emissions samples included 140 components (hydrocarbons, ethers, alcohols and aldehydes) between C1 and C12 in a single analysis of 54-minutes duration. Standardization, quality control procedures, and inter-laboratory comparisons developed and completed as part of this program are also described. (Copyright (c) 1992 Society of Automotive Engineers, Inc.).

  12. Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; French, Richard; Deutch, Steve; Iisa, Kristiina

    2014-08-14T23:59:59.000Z

    Hot-vapor filtered bio-oils were produced from two different biomass feedstocks, oak and switchgrass, and the oils were evaluated in hydroprocessing tests for production of liquid hydrocarbon products. Hot-vapor filtering reduced bio-oil yields and increased gas yields. The yields of fuel carbon as bio-oil were reduced by ten percentage points by hot-vapor filtering for both feedstocks. The unfiltered bio-oils were evaluated alongside the filtered bio-oils using a fixed bed catalytic hydrotreating test. These tests showed good processing results using a two-stage catalytic hydroprocessing strategy. Equal-sized catalyst beds, a sulfided Ru on carbon catalyst bed operated at 220°C and a sulfided CoMo on alumina catalyst bed operated at 400°C were used with the entire reactor at 100 atm operating pressure. The products from the four tests were similar. The light oil phase product was fully hydrotreated so that nitrogen and sulfur were below the level of detection, while the residual oxygen ranged from 0.3 to 2.0%. The density of the products varied from 0.80 g/ml up to 0.86 g/ml over the period of the test with a correlated change of the hydrogen to carbon atomic ratio from 1.79 down to 1.57, suggesting some loss of catalyst activity through the test. These tests provided the data needed to assess the suite of liquid fuel products from the process and the activity of the catalyst in relationship to the existing catalyst lifetime barrier for the technology.

  13. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    the subsurface geology and the gas bubble (with oil) plumesgeology and gas-phase (methane) seepage for the Coal Oilwith offshore oil production. Geology 27:1047–1050 Shindell

  14. Effects of the Shell Oil spill on hydrocarbon metabolism in the staghorn sculpin Leptocottus armatus: Pilot and reconnaissance study for the Shell Oil spill assessment and recovery monitoring environmental effects program

    SciTech Connect (OSTI)

    Spies, R.B.

    1989-06-01T23:59:59.000Z

    On 23 April 1988, about 400,000 gallons of San Joaquin Valley crude oil (SJVC) were released from Shell Oil into Peyton Slough. The oil flowed down Peyton Slough, and some of it reached Suisun Bay where winds and tidal currents distributed it over much of the water surface of eastern Carquinez Strait and western and southern Suisun Bay. To determine if the Shell Oil spill had a sublethal effect on fish in Peyton Slough and the nearby areas of Carquinez Strait and Suisun Bay that were exposed to the oil, we measured the capacity of the staghorn sculpin Leptocottus armatus to metabolize hydrocarbons. This species was collected from a series of sites that were most likely to be affected by the spill: within Peyton Slough, offshore of the mouth of Peyton Slough, and at the West Martinez mudflat. Collection sites that were somewhat further from the spill, but may have been affected by the spill included the following stations: near the Mothball Fleet, near Point Edith, and in Southampton Bay. A collection site in northern San Francisco Bay near several ship-refueling docks, contaminated by hydrocarbons from local activities, served as a comparison to the stations near the oil spill. Tomales Bay, minimally impacted by man's activities, served as a reference collection site for the urbanized San Francisco Bay system. The enhancement of hydrocarbon-metabolizing capacity in fish exposed to petroleum hydrocarbons, including those at the spill site, demonstrate a biologically detectable effect of such exposure.

  15. Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons

    SciTech Connect (OSTI)

    Continental Shelf Associates, Inc.

    1999-08-16T23:59:59.000Z

    This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. Concentrations in produced water discharge plume/receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentrations of metals and hydrocarbons determined in the samples.

  16. Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons.

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. concentrations in produced water discharge plume / receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentration of metals and hydrocarbons determined in the samples.

  17. Recent hydrocarbon developments in Latin America: Key issues in the downstream oil sector

    SciTech Connect (OSTI)

    Wu, K.; Pezeshki, S.

    1995-03-01T23:59:59.000Z

    This report discusses the following: (1) An overview of major issues in the downstream oil sector, including oil demand and product export availability, the changing product consumption pattern, and refineries being due for major investment; (2) Recent upstream developments in the oil and gas sector in Argentina, Bolivia, Brazil, Chile, Colombia, Ecuador, Mexico, Peru, Trinidad and Tobago, and Venezuela; (3) Recent downstream developments in the oil and gas sector in Argentina, Chile, Colombia, Ecuador, Mexico, Peru, Cuba, and Venezuela; (4) Pipelines in Argentina, Bolivia, Brazil, Chile, and Mexico; and (5) Regional energy balance. 4 figs., 5 tabs.

  18. Study of hydrocarbon miscible solvent slug injection process for improved recovery of heavy oil from Schrader Bluff Pool, Milne Point Unit, Alaska. Final report

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    The National Energy Strategy Plan (NES) has called for 900,000 barrels/day production of heavy oil in the mid-1990s to meet our national needs. To achieve this goal, it is important that the Alaskan heavy oil fields be brought to production. Alaska has more than 25 billion barrels of heavy oil deposits. Conoco, and now BP Exploration have been producing from Schrader Bluff Pool, which is part of the super heavy oil field known as West Sak Field. Schrader Bluff reservoir, located in the Milne Point Unit, North Slope of Alaska, is estimated to contain up to 1.5 billion barrels of (14 to 21{degrees}API) oil in place. The field is currently under production by primary depletion; however, the primary recovery will be much smaller than expected. Hence, waterflooding will be implemented earlier than anticipated. The eventual use of enhanced oil recovery (EOR) techniques, such as hydrocarbon miscible solvent slug injection process, is vital for recovery of additional oil from this reservoir. The purpose of this research project was to determine the nature of miscible solvent slug which would be commercially feasible, to evaluate the performance of the hydrocarbon miscible solvent slug process, and to assess the feasibility of this process for improved recovery of heavy oil from Schrader Bluff reservoir. The laboratory experimental work includes: slim tube displacement experiments and coreflood experiments. The components of solvent slug includes only those which are available on the North Slope of Alaska.

  19. Dynamics of the Oil Transition: Modeling Capacity, Costs, and Emissions

    E-Print Network [OSTI]

    Brandt, Adam R.; Farrell, Alexander E.

    2008-01-01T23:59:59.000Z

    oil-like hydrocarbon fuels from non-conventional petroleumto hydrocarbon-based substitutes for conventional petroleum.liquid hydrocarbons, avail- ability of conventional oil, the

  20. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    Oil Point, California. Mar Petrol Geol 22:569–578 Whelan J,S transect of the Gulf of Mexico. Mar Petrol Geol 22:479–497of gas origin: Mar Petrol Geol 26:333–344 Finkbeiner T,

  1. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R. (Littleton, CO); Weimer, Carl S. (Littleton, CO); Nelson, Loren D. (Evergreen, CO); O'Brien, Martin J. (Pine, CO)

    2003-01-01T23:59:59.000Z

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  2. Catalytic Hydroprocessing of Biomass Fast Pyrolysis Bio-oil to Produce Hydrocarbon Products

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Zacher, Alan H.

    2009-10-01T23:59:59.000Z

    Catalytic hydroprocessing has been applied to biomass fast pyrolysis liquid product (bio-oil) in a bench-scale continuous-flow fixed-bed reactor system. The intent of the research was to develop process technology to convert the bio-oil into a petroleum refinery feedstock to supplement fossil energy resources and to displace imported feedstock. The project was a cooperative research and development agreement among UOP LLC, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory (PNNL). This paper is focused on the process experimentation and product analysis undertaken at PNNL. The paper describes the experimental methods used and relates the results of the product analyses. A range of catalyst formulations were tested over a range of operating parameters including temperature, pressure, and flow-rate with bio-oil derived from several different biomass feedstocks. Effects of liquid hourly space velocity and catalyst bed temperature were assessed. Details of the process results were presented including mass and elemental balances. Detailed analysis of the products were provided including elemental composition, chemical functional type determined by mass spectrometry, and product descriptors such as density, viscosity and Total Acid Number (TAN). In summation, the paper provides an understanding of the efficacy of hydroprocessing as applied to bio-oil.

  3. Oil from Tobacco Leaves: FOLIUM - Installation of Hydrocarbon Accumulating Pathways in Tobacco Leaves

    SciTech Connect (OSTI)

    None

    2012-01-01T23:59:59.000Z

    PETRO Project: LBNL is modifying tobacco to enable it to directly produce fuel molecules in its leaves for use as a biofuel. Tobacco is a good crop for biofuels production because it is an outstanding biomass crop, has a long history of cultivation, does not compete with the national food supply, and is highly responsive to genetic manipulation. LBNL will incorporate traits for hydrocarbon biosynthesis from cyanobacteria and algae, and enhance light utilization and carbon uptake in tobacco, improving the efficiency of photosynthesis so more fuel can be produced in the leaves. The tobacco-generated biofuels can be processed for gasoline, jet fuel or diesel alternatives. LBNL is also working to optimize methods for planting, cultivating and harvesting tobacco to increase biomass production several-fold over the level of traditional growing techniques.

  4. Study of hydrocarbon miscible solvent slug injection process for improved recovery of heavy oil from Schrader Bluff Pool, Milne Point Unit, Alaska. Annual report, January 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Sharma, G.D.

    1995-07-01T23:59:59.000Z

    Alaska is the second largest oil producing state in the nation and currently contributes nearly 24% of the nations oil production. It is imperative that Alaskan heavy oil fields be brought into production. Schrader Bluff reservoir, located in the Milne Point Unit, which is part of the heavy oil field known as West Sak is estimated to contain 1.5 billion barrels of (14 to 21 degree API) oil-in-place. The field is currently under production by primary depletion. The eventual implementation of enhanced oil recovery (EOR) techniques will be vital for the recovery of additional oil from this reservoir. The availability of hydrocarbon gases (solvents) on the Alaska North Slope make the hydrocarbon miscible solvent injection process an important consideration for the EOR project in Schrader Bluff reservoir. Since Schrader Bluff oil is heavy and viscous, a water-alternating-gas (WAG) type of process for oil recovery is appropriate since such a process tends to derive synergetic benefits from both water injection (which provides mobility control and improvement in sweep efficiency) and miscible gas injection (which provides improved displacement efficiency). A miscible solvent slug injection process rather than continuous solvent injection is considered appropriate. Slim tube displacement studies, PVT data and asphaltene precipitation studies are needed for Schrader bluff heavy oil to define possible hydrocarbon solvent suitable for miscible solvent slug displacement process. Coreflood experiments are also needed to determine the effect of solvent slug size, WAG ratio and solvent composition on the recovery and solvent breakthrough. A compositional reservoir simulation study will be conducted later to evaluate the complete performance of the hydrocarbon solvent slug process and to assess the feasibility of this process for improving recovery of heavy oil from Schrader Bluff reservoir.

  5. UNFINISHED JOURNEY Project. Quarterly report, April 1995--June 1995

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    In September, 1994, the U.S. Department of Energy (Nevada Operations Office) made a $199,708 grant (through the Mathematics, Science, and Technology Education Program), to the UNFINISHED JOURNEY Project. The Project began in April, 1994 to develop and implement an innovative model of student outreach by San Jose State University (SJSU) to underserved, underrepresented student populations of the East Side Union High School District (ESUHSD). The Project was formed by a consortium involving SJSU, ESUHSD, some 20 private sector organizations (foundations/corporations), numerous local community/professional organizations, and approximately 100 private funders. This proposal to the U.S. Department of Energy was to have the Department join this unique partnership to focus University outreach to underserved student populations to pursue careers in mathematics, science, and technology.

  6. UNFINISHED JOURNEY Project. Quarterly report, July 1995--September 1995

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    In September, 1994, the U.S. Department of Energy (Nevada Operations Office) made a $199,708 grant (through the Mathematics, Science, and Technology Education Program), to the UNFINISHED JOURNEY Project. The Project began in April, 1994, to develop and implement an innovative model of student outreach by San Jose State University (SJSU) to underserved, underrepresented student populations of the East Side Union High School District (ESUHSD). The Project was formed by a consortium involving SJSU, ESUHSD, some 20 private sector organizations (foundations/corporations), numerous local community/professional organizations, and approximately 100 private funders. This proposal to the U.S. Department of Energy was to have the Department join this unique partnership to focus University outreach to underserved student populations to pursue careers in mathematics, science, and technology.

  7. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14T23:59:59.000Z

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  8. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01T23:59:59.000Z

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  9. Biological enhancement of hydrocarbon extraction

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

    2009-01-06T23:59:59.000Z

    A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

  10. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

    1986-01-01T23:59:59.000Z

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

  11. Crude oil and shale oil

    SciTech Connect (OSTI)

    Mehrotra, A.K. [Univ. of Calgary (Canada)

    1995-06-15T23:59:59.000Z

    This year`s review on crude oil and shale oil has been prepared by classifying the references into the following main headings: Hydrocarbon Identification and Characterization, Trace Element Determination, Physical and Thermodynamic Properties, Viscosity, and Miscellaneous Topics. In the two-year review period, the references on shale oils were considerably less in number than those dealing with crude oils. Several new analytical methodologies and applications were reported for hydrocarbon characterization and trace element determination of crude oils and shale oils. Also included in this review are nine U.S., Canadian British and European patents. 12 refs.

  12. ORGANIC GEOCHEMISTRY, DEPOSITIONAL ENVIRONMENT AND HYDROCARBON POTENTIAL OF THE TERTIARY OIL SHALE DEPOSITS IN NW ANATOLIA, TURKEY

    E-Print Network [OSTI]

    R. Kara Gülbay; S. Korkmaz

    In this study, organic geochemical characteristics and depositional environ-ment of the Tertiary-aged oil shale deposits in Northwest Anatolia have been examined. Oil shales in all the studied areas are typically characterized by high hydrogen index and low oxygen index values. Beypazar?

  13. Vertical composition gradient effects on original hydrocarbon in place volumes and liquid recovery for volatile oil and gas condensate reservoirs

    E-Print Network [OSTI]

    Jaramillo Arias, Juan Manuel

    2000-01-01T23:59:59.000Z

    Around the world, volatile oil and retrograde gas reservoirs are considered as complex thermodynamic systems and even more when they exhibit vertical composition variations. Those systems must be characterized by an equation of state (EOS...

  14. Experimental and analytical modeling studies of steam injection with hydrocarbon additives to enhance recovery of San Ardo heavy oil 

    E-Print Network [OSTI]

    Simangunsong, Roly

    2006-10-30T23:59:59.000Z

    Experimental and analytical studies have been carried out to better understand production mechanisms of heavy oil under steam injection with propane and petroleum distillate as steam additives. The studies have been conducted ...

  15. E-Print Network 3.0 - aromatic hydrocarbons resulting Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Summary: fuel. (d) Lubricating oil. - 300 400 Wavelength (nm) Results Concentrations of aromatic hydrocarbons... Aust. J....

  16. E-Print Network 3.0 - aromatic hydrocarbon concentrations Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Summary: fuel. (d) Lubricating oil. - 300 400 Wavelength (nm) Results Concentrations of aromatic hydrocarbons... Bay...

  17. E-Print Network 3.0 - aromatic hydrocarbons concentrations Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Summary: fuel. (d) Lubricating oil. - 300 400 Wavelength (nm) Results Concentrations of aromatic hydrocarbons... Bay...

  18. Bio-crude transcriptomics: Gene discovery and metabolic network reconstruction for the biosynthesis of the terpenome of the hydrocarbon oil-producing green alga, Botryococcus braunii race B (Showa)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Molnár, István; Lopez, David; Wisecaver, Jennifer H.; Devarenne, Timothy P.; Weiss, Taylor L.; Pellegrini, Matteo; Hackett, Jeremiah D.

    2012-01-01T23:59:59.000Z

    Microalgae hold promise for yielding a biofuel feedstock that is sustainable, carbon-neutral, distributed, and only minimally disruptive for the production of food and feed by traditional agriculture. Amongst oleaginous eukaryotic algae, the B race of Botryococcus braunii is unique in that it produces large amounts of liquid hydrocarbons of terpenoid origin. These are comparable to fossil crude oil, and are sequestered outside the cells in a communal extracellular polymeric matrix material. Biosynthetic engineering of terpenoid bio-crude production requires identification of genes and reconstruction of metabolic pathways responsible for production of both hydrocarbons and other metabolites of the alga that competemore »for photosynthetic carbon and energy.« less

  19. Bio-crude transcriptomics: Gene discovery and metabolic network reconstruction for the biosynthesis of the terpenome of the hydrocarbon oil-producing green alga, Botryococcus braunii race B (Showa)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Molnár, István [Univ. of Arizona, Tucson, AZ (United States). Natural Products Center and Bio5 Institute; Lopez, David [Univ. of California, Los Angeles, CA (United States). Dept. of Molecular, Cell and Developmental Biology; Wisecaver, Jennifer H. [Univ. of Arizona, Tucson, AZ (United States). Dept. of Ecology and Evolutionary Biology; Devarenne, Timothy P. [Texas A & M Univ., College Station, TX (United States). Dept. of Biochemistry and Biophysics; Weiss, Taylor L. [Texas A & M Univ., College Station, TX (United States). Dept. of Biochemistry and Biophysics; Pellegrini, Matteo [Univ. of California, Los Angeles, CA (United States). Dept. of Molecular, Cell and Developmental Biology; Hackett, Jeremiah D. [Univ. of Arizona, Tucson, AZ (United States). Bio5 Institute and Dept. of Ecology and Evolutionary Biology

    2012-01-01T23:59:59.000Z

    Microalgae hold promise for yielding a biofuel feedstock that is sustainable, carbon-neutral, distributed, and only minimally disruptive for the production of food and feed by traditional agriculture. Amongst oleaginous eukaryotic algae, the B race of Botryococcus braunii is unique in that it produces large amounts of liquid hydrocarbons of terpenoid origin. These are comparable to fossil crude oil, and are sequestered outside the cells in a communal extracellular polymeric matrix material. Biosynthetic engineering of terpenoid bio-crude production requires identification of genes and reconstruction of metabolic pathways responsible for production of both hydrocarbons and other metabolites of the alga that compete for photosynthetic carbon and energy.

  20. Comparative Summer Thermal Performance of Finished and Unfinished Metal Roofing Products with Composition Shingles

    E-Print Network [OSTI]

    Parker, D. S.; Sherwin, J.; Sonne, J.

    2004-01-01T23:59:59.000Z

    , both finished and unfinished, might compare with other more traditional roofing types. All of the test cells had R-19 insulation installed on the attic floor except in the double roof configuration which had R-19 of open cell foam blown onto...

  1. Oil

    E-Print Network [OSTI]

    unknown authors

    Waste oils offer a tremendous recycling potential. An important, dwindling natural resource of great economic and industrial value, oil products are a cornerstone of our modern industrial society. Petroleum is processed into a wide variety of products: gasoline, fuel oil, diesel oil, synthetic rubber, solvents, pesticides, synthetic fibres, lubricating oil, drugs and many more ' (see Figure 1 1. The boilers of Amercian industries presently consume about 40 % of the used lubricating oils collected. In Ontario, the percentage varies from 20 to 30%. Road oiling is the other major use of collected waste oils. Five to seven million gallons (50-70 % of the waste oil col1ected)is spread on dusty Ontario roads each summer. The practice is both a wasteful use of a dwindling resource and an environmental hazard. The waste oil, with its load of heavy metals, particularly lead, additives including dangerous polynuclear aromatics and PCBs, is carried into the natural environment by runoff and dust to contaminate soils and water courses.2 The largest portion of used oils is never collected, but disappears into sewers, landfill sites and backyards. In Ontario alone, approximately 22 million gallons of potentially recyclable lube oil simply vanish each year. While oil recycling has ad-114 Oil

  2. Poverty of stimulus : some unfinished business The core problem of the theory of language is to discover the

    E-Print Network [OSTI]

    van Tiggelen, Bart

    Poverty of stimulus : some unfinished business The core problem of the theory of language systematically in the 1950s. It quickly became evident how little was understood. Problems of "poverty

  3. Sustainable treatment of hydrocarbon-contaminated industrial land 

    E-Print Network [OSTI]

    Cunningham, Colin John

    2012-06-25T23:59:59.000Z

    Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

  4. Variability of gas composition and flux intensity in natural marine hydrocarbon seeps

    E-Print Network [OSTI]

    Clark, Jordan F.; Washburn, Libe; Schwager Emery, Katherine

    2010-01-01T23:59:59.000Z

    and the fallout plume of heavy oil from strong petroleumCH 4 ) and other heavy hydrocarbons including oil, to the

  5. aromatic hydrocarbon carcinogenesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Ecology Websites Summary: ), and there are oil refineries on the shore. In this environment, input of aromatic hydrocarbons from petroleum and the Yarra River Estuary J. David...

  6. aromatic hydrocarbon tracers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Ecology Websites Summary: ), and there are oil refineries on the shore. In this environment, input of aromatic hydrocarbons from petroleum and the Yarra River Estuary J. David...

  7. Hydrocarbon habitat of the west Netherlands basin

    SciTech Connect (OSTI)

    De Jager, J. (Nederlandse Aardolie Maatschappij, Assen (Netherlands)); Doyle, M. (Petroleum Development Oman, Muscat (Oman)); Grantham, P. (KSEPL/Shell Research, Rijswijk (Netherlands)); Mabillard, J. (Shell Nigeria, Port Harcourt (Nigeria))

    1993-09-01T23:59:59.000Z

    The complex West Netherlands Basin contains oil and gas in Triassic and Upper Jurassic to Cretaceous clastic reservoir sequences. The understanding has always been that the Carboniferous coal measures have generated only gas and the Jurassic marine Posidonia Shale only oil. However, detailed geochemical analyses show that both source rocks have generated oil and gas. Geochemical fingerprinting established a correlation of the hydrocarbons with the main source rocks. The occurrence of these different hydrocarbons is consistent with migration routes. Map-based charge modeling shows that the main phase of hydrocarbon generation occurred prior to the Late Cretaceous inversion of the West Netherlands Basin. However, along the southwest flank of the basin and in lows between the inversion highs, significant charge continued during the Tertiary. Biodegradation of oils in Jurassic and Cretaceous reservoirs occurred during the earliest Tertiary, but only in reservoirs that were at that time at temperatures of less then 70 to 80[degrees]C, where bacteria could survive. This study shows that also in a mature hydrocarbon province an integrated hydrocarbon habitat study with modern analyses and state-of-the-art technology can lead to a much improved understanding of the distribution of oil and gas in the subsurface. The results of this study will allow a better risk assessment for remaining prospects, and an improved prediction of the type of trapped hydrocarbons in terms of gas, oil, and biodegraded oil.

  8. Solubilization of petroleum hydrocarbons using biosurfactants

    E-Print Network [OSTI]

    Kanga, Shahrukh

    1995-01-01T23:59:59.000Z

    that bioavailability of the crude oil to the microorganisms limited the degradation rates (Mills, 1994). Preliminary experiments at our laboratories have also indicated enhanced solubilities of petroleum hydrocarbons due to the effects of biosurfactants (Kanga et al...

  9. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

    1986-01-01T23:59:59.000Z

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

  10. 31443,"AECTRA REFG & MKTG",1,840,"UNFINISHED OILS, HEAVY GAS...

    U.S. Energy Information Administration (EIA) Indexed Site

    FUEL, TOTAL",0901,"BUFF-NIAG FL, NY","NEW YORK",1,260,"CANADA",1,0,0,,,,, 31443,"SMITH H G",1,231,"PROPANENGL",3802,"PORT HURON, MI","MICHIGAN",2,260,"CANADA",8,0,0,,,,,...

  11. Measurement of Oil and Gas Emissions from a Marine Seep

    E-Print Network [OSTI]

    Leifer, Ira; Boles, J R; Luyendyk, B P

    2007-01-01T23:59:59.000Z

    hydrocarbon seeps near Coal Oil Point, California, Marineet al. , 2007, Measurement of Oil and Gas Emissions from aand P.G. Mikolaj, Natural oil seepage at Coal Oil Point,

  12. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1999-01-12T23:59:59.000Z

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  13. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1999-01-12T23:59:59.000Z

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing in organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed.

  14. Apparatus for hydrocarbon extraction

    DOE Patents [OSTI]

    Bohnert, George W.; Verhulst, Galen G.

    2013-03-19T23:59:59.000Z

    Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

  15. Evaluation of biological treatment for the degradation of petroleum hydrocarbons in a wastewater treatment plant 

    E-Print Network [OSTI]

    Basu, Pradipta Ranjan

    2005-08-29T23:59:59.000Z

    Biodegradation of petroleum hydrocarbon can be an effective treatment method applied to control oil pollution in both fresh water and marine environments. Hydrocarbon degraders, both indigenous and exogenous, are responsible for utilizing petroleum...

  16. Hydrocarbon conversion catalysts

    SciTech Connect (OSTI)

    Hoek, A.; Huizinga, T.; Maxwell, I.E.

    1989-08-15T23:59:59.000Z

    This patent describes a process for hydrocracking hydrocarbon oils into products of lower average molecular weight and lower average boiling point. It comprises contacting a hydrocarbon oil at a temperature between 250{sup 0}C and 500{sup 0}C and a pressure up to 300 bar in the presence of hydrogen with a catalyst consisting essentially of a Y zeolite modified to have a unit cell size below 24.35A, a water absorption capacity (at 25{sup 0}C and a rho/rho/sub o/ value of 0.2) of at least 8% by weight of the zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm; an alumina binder and at least one hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal and mixtures thereof.

  17. UNFINISHED JOURNEY Project. Final report, September 30, 1994--September 29, 1995

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    In late 1994, the U.S. Department of Energy (Nevada Operations Office) made a $199,708 grant (through the Mathematics, Science, and Technology Education Program), to the UNFINISHED JOURNEY Project. The Project began in April, 1994, to develop and implement an innovative model of student outreach by San Jose State University (SJSU) to underserved, underrepresented student populations of the East Side Union High School District (ESUHSD). The Project was formed by a consortium involving SJSU, ESUHSD, some 20 private sector organizations (foundations/corporations), numerous local community/professional organizations, and approximately 100 private funders. This proposal to the U.S. Department of Energy was to have the Department join this unique partnership to focus University outreach to underserved student populations to pursue careers in mathematics, science, and technology.

  18. No Oil: The coming Utopia/Dystopia and Communal Possibilities

    E-Print Network [OSTI]

    Miller, Timothy

    2006-03-01T23:59:59.000Z

    supplies of conventional oil, and exploitable supplies of alternative forms of oil and related hydrocarbons, including tar sands and oil shale. Because new supplies of conventional oil are declining steadily, there is quite a lot of activity in the oil... to exploit the huge deposits of oil sands in Canada. Oil sands and oil shale look good because they contain vast amounts of oil. The problem is that of turning the reserves, locked into other geological formations, into useful oil. According to current...

  19. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01T23:59:59.000Z

    LBL-8596 itr-t C,d.. HYDROCARBONS & ENERGY FROM PLANTS jmethods of isolating the hydrocarbon-like material from I.privatelyownedrights. HYDROCARBONS AND ENERGY FROM PLANTS

  20. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01T23:59:59.000Z

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  1. Complex conductivity tensor of anisotropic hydrocarbon-1 bearing shales and mudrocks2

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    to describe seismic and electromagnetic (EM) measurements in these anisotropic54 materials.55 Oil-shale to release their hydrocarbons. Hence, oil shales and58 mudrocks are typically water-wet, single- or dual

  2. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway

    SciTech Connect (OSTI)

    Jones, Susanne B.; Meyer, Pimphan A.; Snowden-Swan, Lesley J.; Padmaperuma, Asanga B.; Tan, Eric; Dutta, Abhijit; Jacobson, Jacob; Cafferty, Kara

    2013-11-01T23:59:59.000Z

    This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

  3. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-oil Pathway

    SciTech Connect (OSTI)

    Jones, S.; Meyer, P.; Snowden-Swan, L.; Padmaperuma, A.; Tan, E.; Dutta, A.; Jacobson, J.; Cafferty, K.

    2013-11-01T23:59:59.000Z

    This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

  4. Hydrocarbon conversion process

    SciTech Connect (OSTI)

    Buss, W.C.; Field, L.A.; Robinson, R.C.

    1984-06-26T23:59:59.000Z

    A hydrocarbon conversion process is disclosed having a very high selectivity for dehydrocyclization. In one aspect of this process, a hydrocarbon feed is subjected to hydrotreating, then the hydrocarbon feed is passed through a sulfur removal system which reduces the sulfur concentration of the hydrocarbon feed to below 500 ppb, and then the hydrocarbon feed is reformed over a dehydrocyclization catalyst comprising a large pore zeolite containing at least one Group VIII metal to produce aromatics and hydrogen.

  5. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25T23:59:59.000Z

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  6. Method of dispersing a hydrocarbon using bacteria

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1996-01-01T23:59:59.000Z

    New protozoan derived microbial consortia and method for their isolation are provided. Consortia and bacteria isolated therefrom are useful for treating wastes such as trichloroethylene and trinitrotoluene. Consortia, bacteria isolated therefrom, and dispersants isolated therefrom are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

  7. Method of dispersing a hydrocarbon using bacteria

    DOE Patents [OSTI]

    Tyndall, R.L.

    1996-09-24T23:59:59.000Z

    A new protozoan derived microbial consortia and method for their isolation are provided. The isolated consortia and bacteria are useful for treating wastes such as trichloroethylene and trinitrotoluene. The isolated consortia, bacteria, and dispersants are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

  8. Experimental study of lube oil characteristics in the PCV system and effects on engine oil consumption

    E-Print Network [OSTI]

    Lopez, Oscar, 1980-

    2004-01-01T23:59:59.000Z

    Engine oil consumption is an important source of hydrocarbon and particulate emissions in modem automobile engines. Great efforts have been made by automotive manufacturers to minimize the impact of oil consumption on ...

  9. Geology and hydrocarbon prospects of Latvia

    SciTech Connect (OSTI)

    Freimanis, A. (Latvian Dept. of Geology, Riga (Latvia)); Margulis, L.; Brangulis, A.; Kanev, S.; Pomerantseva, R. (Inst. of Marine Geology and Geophysics, Riga (Latvia))

    1993-12-06T23:59:59.000Z

    Oil prospects in Latvia are associated with the Baltic syneclise. Latvia occupies about one fourth of that large tectonic depression; zones of oil accumulation continue there from adjacent areas: the Telshai rampart (Lithuania) and the Leba nose (Polish offshore). The oil prospects in separate areas are determined by their position regarding the sources of oil generation--the Gdansk-Kura and Liepaya depressions. The most prospective areas are the Liepaya-Saldus zone of highs and the Pape-Barta trough. The Liepaya-Saldus zone was situated so that the hydrocarbon migration path crossed it. It probably is an important oil accumulation zone. The paper describes the geology of Latvia and the one oil field in Latvia.

  10. 1 What is Oil ? General information

    E-Print Network [OSTI]

    Kammen, Daniel M.

    such as shale oil or synthetic crude oil from tar sands (see Table 4.1). A whole range of petroleum products69 1 What is Oil ? General information Petroleum is a complex mixture of liquid hydrocarbons in sedimentary rock. Coming from the Latin petra, meaning rock, and oleum, meaning oil, the word "petroleum

  11. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    Gas, Crude Oil and Distillates NGLs consumption in CALEBConsumption Weekly Refinery and Fractionator Report Weekly Bulk Terminal Report Weekly Product Pipeline Report Weekly Crude OilCrude Oil Butane Isobutane Other Hydrocarbons, Hydrogen and Oxygenates 10,718 Unfinished Oils Source: CEC 2006a The energy sector shows the consumption

  12. Carbon and oxygen stable isotopes in the Toa Baja Well, Puerto Rico: implications for burial diagenesis and hydrocarbon generation

    E-Print Network [OSTI]

    Gonzalez, Luis A.

    1991-03-01T23:59:59.000Z

    that the bulk of the sediment pile has not been exposed to temperatures above the oil window and possibly hydrocarbons have been generated deeper in the basin....

  13. Preliminary investigation of the nature of hydrocarbon migration and entrapment 

    E-Print Network [OSTI]

    Bai, Jianyong

    2004-09-30T23:59:59.000Z

    hydrocarbon accumulation is much longer in oil-water systems than in oil-gas-water systems. Faults are classified into charging faults and 'back doors' faults other than charging faults in stacked fault-bounded reservoirs. The lower the displacement pressure...

  14. Nineteenth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1986-01-01T23:59:59.000Z

    This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

  15. Hydrocarbon in Catalyst in

    E-Print Network [OSTI]

    Ladkin, Peter B.

    Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure #12;#12;#12;#12;#12;#12;#12;#12;Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure controller Computer operator

  16. Hydrocarbon in Catalyst in

    E-Print Network [OSTI]

    Ladkin, Peter B.

    #12;Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure controller Computer;#12;Vent 1 Vent 2 Product outHydrocarbon in Steam in Catalyst in light Warning Computer controller Tank

  17. 2, 16451664, 2005 Hydrocarbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 2, 1645­1664, 2005 Hydrocarbon emissions from a boreal fen S. Haapanala et al. Title Page Discussions is the access reviewed discussion forum of Biogeosciences Measurements of hydrocarbon emissions Hydrocarbon emissions from a boreal fen S. Haapanala et al. Title Page Abstract Introduction Conclusions

  18. Anaerobic Hydrocarbon Degradation in

    E-Print Network [OSTI]

    California at Berkeley, University of

    Anaerobic Hydrocarbon Degradation in Petroleum-Contaminated Harbor Sediments under Sulfate of iron(III) oxide to stimulate in- situ hydrocarbon degradation in anaerobic petroleum- contaminated did not stimulate anaerobic hydrocarbon oxidation. Exposure of the sediment to air [to reoxidize Fe

  19. Is cyclobutane a hydrocarbon?

    E-Print Network [OSTI]

    Martin, Ralph R.

    Is cyclobutane a hydrocarbon? Biologically interesting entities possibly > 1,000,000 Does cyclobutane have a four- membered ring? Is cyclobutane a hydrocarbon? Expressive and decidable formalism needs to be classified under chemical classes: Is dinitrogen inorganic? Is acetylene a hydrocarbon

  20. Preliminary investigation of the nature of hydrocarbon migration and entrapment

    E-Print Network [OSTI]

    Bai, Jianyong

    2004-09-30T23:59:59.000Z

    production while another half sealed among them. The Ship Shoal 274 reservoirs have exhibited a complex history of migration and entrapment. An early stage of oil and gas charge was followed and disturbed by late stage gas migration, mainly 8 through growth... structures. The charge time for commercial hydrocarbon accumulation is much longer in oil-water systems than in oil-gas-water systems. Faults are classified into charging faults and ?back doors? ? faults other than charging faults in stacked fault...

  1. Hydrocarbon conversion process and catalysts

    SciTech Connect (OSTI)

    Hoek, A.; Huizinga, T.; Maxwell, I.E.

    1989-08-15T23:59:59.000Z

    This patent describes a process for hydrocracking hydrocarbon oils into products of lower average molecular weight and lower average boiling point. It comprises contacting hydrocarbon oil at a temperature between 250{sup 0}C and 500{sup 0}C and a pressure up to 300 bar in the presence of hydrogen with a catalyst consisting essentially of a Y zeolite modified to have a unit cell size below 24.40 A, a water adsorption capacity (at 25{sup 0}C and a rho/rho/sub o/ value of 0.2) of between 10% and 15% by weight of the zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm; am amorphous cracking component, a binder and at least one hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal and mixtures thereof.

  2. Production Forecast, Analysis and Simulation of Eagle Ford Shale Oil 

    E-Print Network [OSTI]

    Alotaibi, Basel Z S Z J

    2014-12-02T23:59:59.000Z

    fracturing to liberate the recoverable hydrocarbon reserves. Thousands of wells that have been drilled in the major oil shale formations: Bakken, Permian Basin and Eagle Ford, where oil production peaked in the first few weeks and then showed a sharp...

  3. Production Forecast, Analysis and Simulation of Eagle Ford Shale Oil

    E-Print Network [OSTI]

    Alotaibi, Basel Z S Z J

    2014-12-02T23:59:59.000Z

    fracturing to liberate the recoverable hydrocarbon reserves. Thousands of wells that have been drilled in the major oil shale formations: Bakken, Permian Basin and Eagle Ford, where oil production peaked in the first few weeks and then showed a sharp...

  4. Algeria's New Oil Strategy Lahouari ADDI

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    · Economic Reforms and Liberalization in the Oil Industry · Oil Strategy and the Rentier State · Conclusion industrial base in the areas of hydrocarbons (condensates, liquefied natural gas, refined products, liquidAlgeria's New Oil Strategy Lahouari ADDI Professor of Political Sociology to the IEP of Lyon In H

  5. Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources

    SciTech Connect (OSTI)

    Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

    2008-10-01T23:59:59.000Z

    Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

  6. Direct conversion of light hydrocarbon gases to liquid fuel

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  7. Comparison of Heating Methods for In-Situ Oil Shale Extraction 

    E-Print Network [OSTI]

    Hazra, Kaushik Gaurav

    2014-04-29T23:59:59.000Z

    Oil shales are lamellar, non-porous, impermeable hydrocarbon bearing rocks that contain organic matter called kerogen which, when heated at pyrolysis temperature of approximately 600-800 ?, thermo-chemically decomposes to liberate hydrocarbons...

  8. Comparison of Heating Methods for In-Situ Oil Shale Extraction

    E-Print Network [OSTI]

    Hazra, Kaushik Gaurav

    2014-04-29T23:59:59.000Z

    Oil shales are lamellar, non-porous, impermeable hydrocarbon bearing rocks that contain organic matter called kerogen which, when heated at pyrolysis temperature of approximately 600-800 ?, thermo-chemically decomposes to liberate hydrocarbons...

  9. USED MINERAL-BASED CRANKCASE OIL

    E-Print Network [OSTI]

    Used Mineral-Based Crankcase

    based crankcase oil vary depending on the brand and type of oil, whether gasoline or diesel fuel was used, the mechanical condition of the engine that the oil came from, and the amount of use between oil changes. Used oil is not naturally found in the environment. What happens to used mineral-based crankcase oil when it enters the environment? q Used mineral-based crankcase oil enters the air through the exhaust system during engine use. q It may enter water or soil when disposed of improperly. q The hydrocarbon components of the oil generally stick to the soil surface. q Some hydrocarbons evaporate into the air very quickly, and others evaporate more slowly. q Hydrocarbon components of the oil that enter surface water bind to small particles in the water and eventually settle to the bottom. q Hydrocarbons from used mineral-based crankcase oil may build up in shellfish or other organisms. q Some metals in used mineral-based crankcase oil dissolve in water and move through the s

  10. Engineering Chlorinated hydrocarbons such as

    E-Print Network [OSTI]

    Chemical Engineering Abstract Chlorinated hydrocarbons such as trichloroethylene (TCE) form a class carriers/supports for NZVI particles to address the in situ remediation of chlorinated hydrocarbons. We

  11. Recovering hydrocarbons from hydrocarbon-containing vapors

    DOE Patents [OSTI]

    Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

    1980-09-30T23:59:59.000Z

    Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

  12. Bacterial mutagenicity of polycyclic aromatic hydrocarbons in reconstituted mixtures and crude coal tar extracts and fractions

    E-Print Network [OSTI]

    Onufrock, Amy Mildred

    1994-01-01T23:59:59.000Z

    , coal, and oil shale vary widely in the amount and nature of potentially carcinogenic polycyclic aromatic hydrocarbons. Thus, potential carcinogenicity varies widely between representative PAH fractions derived from complex mixtures. PAH fractions...

  13. Crude Oil Analysis Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shay, Johanna Y.

    The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

  14. Hydrocarbon desulfurization process

    SciTech Connect (OSTI)

    Plummer, M.A.; Zimmerman, C.C. Jr.

    1986-04-08T23:59:59.000Z

    A process is described for converting a sour hydrocarbon feedstock having a relatively high sulfur content to a hydrocarbon product having a relatively low sulfur content comprising the steps of: (a) hydrodesulfurizing the feedstock having a relatively high sulfur contact with hydrogen to produce the hydrocarbon product having a relatively low sulfur content and hydrogen sulfide gas; (b) contacting the hydrogen sulfide gas with an anthraquinone dissolved in a polar organic solvent having a polarity greater than about 3 Debye units to produce sulfur and an anthrahydroquinone in the solvent; (c) regenerating the anthraquinone from the anthrahydroquinone upon contact with air to produce the anthraquinone and hydrogen peroxide; (d) recycling the anthraquinone to step (b); (e) reducing the hydrogen peroxide to oxygen and water; (f) partially oxidizing a hydrocarbon fuel with the oxygen to produce carbon dioxide and hydrogen; and (g) recycling the hydrogen to step (a).

  15. NATURAL MARINE HYDROCARBON SEEPAGE

    E-Print Network [OSTI]

    Luyendyk, Bruce

    affects ocean chemistry (Dando and Hovland, 1992) and provides a natural source of petroleum pollution the water column above submarine vents, plumes of hydrocarbon gas bubbles act as acoustic scattering targets

  16. 2004-01-2299 Elevated Carbon Dioxide Alters Hydrocarbon

    E-Print Network [OSTI]

    Paré, Paul W.

    the enzymatic conversion of alk(en)yl cysteine sulphoxides contribute to flavor differences detected between, unique essential oils, secondary metabolites, and phytochemicals not found in other crop plants1 of low-molecular-weight hydrocarbons and sulfur derivatives. Odd-chain ketones are emitted from onion

  17. Chlorinated Hydrocarbon Levels in Fishes and Shellfishes of the

    E-Print Network [OSTI]

    the utilization by humans of the vast protein resources in the sea. Chlorinated hydrocarbons from both agricultural and industrial chemicals have been found repeatedly in marine organisms throughout the world also analyzed a few samples of fish eggs, liver. oil. and meal. Finfishes from the northeastern Pacific

  18. A 4D synchrotron X-ray tomography study of the formation of hydrocarbon migration pathways in heated organic-rich shale

    E-Print Network [OSTI]

    Panahi, Hamed; Renard, Francois; Mazzini, Adriano; Scheibert, Julien; Dysthe, Dag Kristian; Jamtveit, Bjorn; Malthe-Sřrenssen, Anders; Meakin, Paul

    2014-01-01T23:59:59.000Z

    Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes that have received renewed interests in recent years because of the ever tightening supply of conventional hydrocarbons and the growing production of hydrocarbons from low permeability tight rocks. Quantitative models for conversion of kerogen into oil and gas and the timing of hydrocarbon generation have been well documented. However, lack of consensus about the kinetics of hydrocarbon formation in source rocks, expulsion timing and how the resulting hydrocarbons escape from or are retained in the source rocks motivates further investigation. In particular, many mechanisms for the transport of hydrocarbons from the source rocks in which they are generated into adjacent rocks with higher permeabilities and smaller capillary entry pressures have been proposed, and a better understanding of this complex process (primary migration) is needed. To characterize these processes it is imperative to use the ...

  19. Carbo-metallic oil conversion

    SciTech Connect (OSTI)

    Myers, G.D.

    1987-11-24T23:59:59.000Z

    This patent describes a method for catalytically cracking reduced crude oil feeds comprising Conradson carbon in the presence of a premised catalyst temperature of about 760/sup 0/C (1400/sup 0/F). The cracking is carried out to form hydrocarbon products comprising gasoline, which method comprises maintaining the functions of oil feed, Conradson carbon, hydrogen in deposited carbonaceous material, and water addition to the oil feed to be converted in accordance with the relationship of operating parameters for a catalyst to oil ratio in the range of about 4.5 to 7.5.

  20. Hydrocarbon provinces and productive trends in Libya and adjacent areas

    SciTech Connect (OSTI)

    Missallati, A.A. (Agip (N.A.M.E.)Ltd., Tripoli (Libya))

    1988-08-01T23:59:59.000Z

    According to the age of major reservoirs, hydrocarbon occurrences in Libya and adjacent areas can be grouped into six major systems which, according to their geographic locations, can be classified into two major hydrocarbon provinces: (1) Sirte-Pelagian basins province, with major reservoirs ranging from middle-late Mesozoic to early Tertiary, and (2) Murzog-Ghadames basins province, with major reservoirs ranging from early Paleozoic to early Mesozoic. In the Sirte-Pelagian basins province, hydrocarbons have been trapped in structural highs or in stratigraphic wedge-out against structural highs and in carbonate buildups. Here, hydrocarbon generation is characterized by the combined effect of abundant structural relief and reservoir development in the same hydrocarbon systems of the same age, providing an excellent example of hydrocarbon traps in sedimentary basins that have undergone extensive tensional fracturing in a shallow marine environment. In the Murzog-Ghadames basins province, hydrocarbons have been trapped mainly in structural highs controlled by paleostructural trends as basement arches which acted as focal points for oil migration and accumulation.

  1. Rigorous Simulation Model of Kerogen Pyrolysis for the In-situ Upgrading of Oil Shales 

    E-Print Network [OSTI]

    Lee, Kyung Jae

    2014-10-09T23:59:59.000Z

    Oil shale is a vast, yet untapped energy source, and the pyrolysis of kerogen in the oil shales releases recoverable hydrocarbons. In this dissertation, we investigate how to increase process efficiency and decrease the costs of in-situ upgrading...

  2. Rigorous Simulation Model of Kerogen Pyrolysis for the In-situ Upgrading of Oil Shales

    E-Print Network [OSTI]

    Lee, Kyung Jae

    2014-10-09T23:59:59.000Z

    Oil shale is a vast, yet untapped energy source, and the pyrolysis of kerogen in the oil shales releases recoverable hydrocarbons. In this dissertation, we investigate how to increase process efficiency and decrease the costs of in-situ upgrading...

  3. Evaluating separator performance for hydrocarbon streams

    SciTech Connect (OSTI)

    Barker, W.F.

    1982-12-27T23:59:59.000Z

    The goal for ideal separator selection and design is to separate the hydrocarbon stream into liquid-free gas and gasfree liquid. Separators are mechanical devices for removing and collecting liquids from natural gas. Verticle, horizontal, and spherical separators and their respective capabilities are described. Coalescing gas separators are designed specifically for the removal of mists, oil fogs, rust, and dust from the gas stream. A table lists estimated fabrication and installation cost, performance rating, and time requirements for each filter-coalescer liquid separator based on gas pressure (psig) and gas volumes (MMcfd).

  4. Development of specialized electronic bibliographic databases for deep ocean hydrocarbon production and transportation 

    E-Print Network [OSTI]

    Mahendran, Joseph Anthony

    1992-01-01T23:59:59.000Z

    information in a manageable form. The developed specialized bibliographic databases contain information located under different headings and present the information under those particular headings chronologically. Subjects include oil spills of various... origins; geological hazards; naturally occurring hydrocarbon seeps; fates and effects of oil spills; major results of pertinent engineering, physical, chemical, ecological, geophysical studies, and satellite oceanographic research. A microcomputer...

  5. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Energy Savers [EERE]

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop: Agenda and Objectives Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop:...

  6. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1997-01-01T23:59:59.000Z

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  7. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, R.L.

    1997-03-11T23:59:59.000Z

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  8. Method and apparatus for production of subsea hydrocarbon formations

    DOE Patents [OSTI]

    Blandford, J.W.

    1995-01-17T23:59:59.000Z

    A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

  9. Method and apparatus for production of subsea hydrocarbon formations

    DOE Patents [OSTI]

    Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

    1995-01-01T23:59:59.000Z

    A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

  10. Hydrocarbon cracking catalyst

    SciTech Connect (OSTI)

    Lochow, C.F.; Kovacs, D.B.

    1988-12-27T23:59:59.000Z

    This patent describes a catalyst composition for cracking hydrocarbons to maximize gasoline comprising: rare earth exchanged ''Y'' crystalline faujasite dispersed in a clay containing matrix material; and which has been subsequently further ion exchanged to contain 0.20 to 3.0 wt% yttrium, calculated as the oxide, whereby the yttrium is chemically combined in the catalyst composition.

  11. Optrode for sensing hydrocarbons

    DOE Patents [OSTI]

    Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

    1988-09-13T23:59:59.000Z

    A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 5 figs.

  12. Deep-sea oil plume enriches psychrophilic oil-degrading bacteria

    SciTech Connect (OSTI)

    Hazen, T.C.; Dubinsky, E.A.; DeSantis, T.Z.; Andersen, G.L.; Piceno, Y.M.; Singh, N.; Jansson, J.K.; Probst, A.; Borglin, S.E.; Fortney, J.L.; Stringfellow, W.T.; Bill, M.; Conrad, M.S.; Tom, L.M.; Chavarria, K.L.; Alusi, T.R.; Lamendella, R.; Joyner, D.C.; Spier, C.; Auer, M.; Zemla, M.L.; Chakraborty, R.; Sonnenthal, E.L.; D'haeseleer, P.; Holman, H.-Y. N.; Osman, S.; Lu, Z.; Van Nostrand, J.D.; Deng, Y.; Zhou, J.; Mason, O.U.

    2010-09-01T23:59:59.000Z

    The biological effects and expected fate of the vast amount of oil in the Gulf of Mexico from the Deepwater Horizon blowout are unknown owing to the depth and magnitude of this event. Here, we report that the dispersed hydrocarbon plume stimulated deep-sea indigenous {gamma}-Proteobacteria that are closely related to known petroleum degraders. Hydrocarbon-degrading genes coincided with the concentration of various oil contaminants. Changes in hydrocarbon composition with distance from the source and incubation experiments with environmental isolates demonstrated faster-than-expected hydrocarbon biodegradation rates at 5 C. Based on these results, the potential exists for intrinsic bioremediation of the oil plume in the deep-water column without substantial oxygen drawdown.

  13. Fluorescent growth bands in irradiated-bitumen nodules: Evidence of episodic hydrocarbon migration

    SciTech Connect (OSTI)

    Rasmussen, B. [Univ. of Western Australia, Nedlands (Australia)

    1997-01-01T23:59:59.000Z

    Minute rims of solid bitumen ({approximately}40-50 {mu}m thick) surround detrital radioactive grains in the Permian-Triassic sandstones and Arranoo Member of the Kockatea Shale from the northern Perth basin, Australia. The bitumen formed as Th- and U-bearing minerals (monazite, xenotime, zircon, thorite) irradiated and immobilized fluid hydrocarbons coming within range of alpha-particle emissions. using transmitted light and scanning electron microscopy and rims appear compositionally homogeneous, but under blue/violet epifluorescent illumination the bitumen displays complex concentric and contorted banding. These fluorescent textures indicate that multiple influxes of hydrocarbons passed through the reservoir sandstones. Following radiation-induced immobilization of hydrocarbons from the first oil influx, the bitumen nodules grew through a process of swelling and expansion outward form the mineral core during subsequent oil influxes, producing graded fluorescent growth bands. Oil droplets and lamellae also were adsorbed onto the outer portion of the nodules. Such bitumen nodules are a new and potentially important source of data for understanding the movement of hydrocarbons in sedimentary basins, specifically for identifying hydrocarbon pathways, the number of discrete hydrocarbon pulses, and the relative timing of oil migration.

  14. Application of Multivariable Control to Oil and Coal Fired Boilers

    E-Print Network [OSTI]

    Swanson, K.

    1981-01-01T23:59:59.000Z

    Increased visibility provided by advanced measurement and control techniques has shown that control of oil and coal fired boilers is a complex problem involving simultaneous determination of flue gas carbon monoxide, hydrocarbon, opacity...

  15. Outsourcing Logistics in the Oil and Gas Industry 

    E-Print Network [OSTI]

    Herrera, Cristina 1988-

    2012-04-30T23:59:59.000Z

    The supply chain challenges that the Oil and Gas industry faces in material logistics have enlarged in the last few decades owing to an increased hydro-carbon demand. Many reasons justify the challenges, such as exploration activities which have...

  16. Outsourcing Logistics in the Oil and Gas Industry

    E-Print Network [OSTI]

    Herrera, Cristina 1988-

    2012-04-30T23:59:59.000Z

    The supply chain challenges that the Oil and Gas industry faces in material logistics have enlarged in the last few decades owing to an increased hydro-carbon demand. Many reasons justify the challenges, such as exploration activities which have...

  17. Performance evaluation of starch based polymer for enhanced oil recovery 

    E-Print Network [OSTI]

    Skurner, James Andrew

    1997-01-01T23:59:59.000Z

    Ever since the first petroleum well was drilled, water production has been a deterring force in maximizing an oilfield's hydrocarbon reserves. To satisfy the ever increasing global demand for petroleum, many different techniques for enhancing oil...

  18. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04T23:59:59.000Z

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  19. From upstream to downstream: Megatrends and latest developments in Latin America`s hydrocarbons sector

    SciTech Connect (OSTI)

    Wu, Kang; Pezeshki, S.; McMahon, J.

    1995-08-01T23:59:59.000Z

    In recent years, Latin America`s hydrocarbons sector has been characterized by reorganization, revitalization, regional cooperation, environmental awakening, and steady expansion. The pattern of these changes, which appear to be the megatrends of the region`s hydrocarbons sector development, will continue during the rest of the 1990s. To further study the current situation and future prospects of Latin America`s hydrocarbons sector, we critically summarize in this short article the key issues in the region`s oil and gas development. These megatrends in Latin America`s hydrocarbons sector development will impact not only the future energy demand and supply in the region, but also global oil flows in the North American market and across the Pacific Ocean. Each country is individually discussed; pipelines to be constructed are discussed also.

  20. Process for oil shale retorting

    DOE Patents [OSTI]

    Jones, John B. (300 Enterprise Bldg., Grand Junction, CO 80501); Kunchal, S. Kumar (300 Enterprise Bldg., Grand Junction, CO 80501)

    1981-10-27T23:59:59.000Z

    Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

  1. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, P.C.

    1997-05-06T23:59:59.000Z

    A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

  2. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

  3. Process for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture

    SciTech Connect (OSTI)

    vanEijl, A.T.

    1986-06-24T23:59:59.000Z

    A process is described for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture characterized by: (a) distilling a hydrocarbon mixture containing the unsaturated hydrocarbon with an N-(aminoalkyl) piperazine; and (b) separating the amine/hydrocarbon mixture into at least two factions, one of which contains the amine and the unsaturated hydrocarbon.

  4. ASSESSMENT OF GENOTOXIC ACTIVITY OF PETROLEUM HYDROCARBON-BIOREMEDIATED SOIL

    SciTech Connect (OSTI)

    BRIGMON, ROBIN

    2004-10-20T23:59:59.000Z

    The relationship between toxicity and soil contamination must be understood to develop reliable indicators of environmental restoration for bioremediation. Two bacterial rapid bioassays: SOS chromotest and umu-test with and without metabolic activation (S-9 mixture) were used to evaluate genotoxicity of petroleum hydrocarbon-contaminated soil following bioremediation treatment. The soil was taken from an engineered biopile at the Czor Polish oil refinery. The bioremediation process in the biopile lasted 4 years, and the toxicity measurements were done after this treatment. Carcinogens detected in the soil, polyaromatic hydrocarbons (PAHs), were reduced to low concentrations (2 mg/kg dry wt) by the bioremediation process. Genotoxicity was not observed for soils tested with and without metabolic activation by a liver homogenate (S-9 mixture). However, umu-test was more sensitive than SOS-chromotest in the analysis of petroleum hydrocarbon-bioremediated soil. Analytical results of soil used in the bioassays confirmed that the bioremediation process reduced 81 percent of the petroleum hydrocarbons including PAHs. We conclude that the combined test systems employed in this study are useful tools for the genotoxic examination of remediated petroleum hydrocarbon-contaminated soil.

  5. Direct conversion of light hydrocarbon gases to liquid fuel. Final report No. 33

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  6. Unconventional Oil and Gas Resources

    SciTech Connect (OSTI)

    none

    2006-09-15T23:59:59.000Z

    World oil use is projected to grow to 98 million b/d in 2015 and 118 million b/d in 2030. Total world natural gas consumption is projected to rise to 134 Tcf in 2015 and 182 Tcf in 2030. In an era of declining production and increasing demand, economically producing oil and gas from unconventional sources is a key challenge to maintaining global economic growth. Some unconventional hydrocarbon sources are already being developed, including gas shales, tight gas sands, heavy oil, oil sands, and coal bed methane. Roughly 20 years ago, gas production from tight sands, shales, and coals was considered uneconomic. Today, these resources provide 25% of the U.S. gas supply and that number is likely to increase. Venezuela has over 300 billion barrels of unproven extra-heavy oil reserves which would give it the largest reserves of any country in the world. It is currently producing over 550,000 b/d of heavy oil. Unconventional oil is also being produced in Canada from the Athabasca oil sands. 1.6 trillion barrels of oil are locked in the sands of which 175 billion barrels are proven reserves that can be recovered using current technology. Production from 29 companies now operating there exceeds 1 million barrels per day. The report provides an overview of continuous petroleum sources and gives a concise overview of the current status of varying types of unconventional oil and gas resources. Topics covered in the report include: an overview of the history of Oil and Natural Gas; an analysis of the Oil and Natural Gas industries, including current and future production, consumption, and reserves; a detailed description of the different types of unconventional oil and gas resources; an analysis of the key business factors that are driving the increased interest in unconventional resources; an analysis of the barriers that are hindering the development of unconventional resources; profiles of key producing regions; and, profiles of key unconventional oil and gas producers.

  7. Engineering Chlorinated hydrocarbons such as trichloroethylene

    E-Print Network [OSTI]

    Chemical Engineering Abstract Chlorinated hydrocarbons such as trichloroethylene (TCE) form a class carriers/supports for NZVI particles to address the in situ remediation of chlorinated hydrocarbons. We Remediation of Chlorinated Hydrocarbons Dr. Vijay John Department of Chemical & Biomolecular Engineering

  8. HYDROCARBON CONSTITUENTS OF ICELAND LEAF FOSSIL

    E-Print Network [OSTI]

    Han, Jerry; Calvin, Melvin.

    2008-01-01T23:59:59.000Z

    L.S. (1962) Isoprenoid hydrocarbons in petroleum. Anal.and EVANS E. D. (1965) Hydrocarbons in non-reservo; r-rockVI. Distribution of wax hydrocarbons in plants at different

  9. HYDROCARBON FORMATION ON POLYMER-SUPPORTED COBALT

    E-Print Network [OSTI]

    Benner, Linda S.

    2013-01-01T23:59:59.000Z

    NV~ August 25-29, 1980 HYDROCARBON FORMATION ON POLYMER-catalyzed reduction of CO to hydrocarbons Tropscb. Among theof CO to saturated linear hydrocarbons and appears to retain

  10. Definition of heavy oil and natural bitumen

    SciTech Connect (OSTI)

    Meyer, R.F.

    1988-08-01T23:59:59.000Z

    Definition and categorization of heavy oils and natural bitumens are generally based on physical or chemical attributes or on methods of extraction. Ultimately, the hydrocarbon's chemical composition will govern both its physical state and the extraction technique applicable. These oils and bitumens closely resemble the residuum from wholecrude distillation to about 1,000/degree/F; if the residuum constitutes at least 15% of the crude, it is considered to be heavy. In this material is concentrated most of the trace elements, such as sulfur, oxygen, and nitrogen, and metals, such as nickel and vanadium. A widely used definition separates heavy oil from natural bitumen by viscosity, crude oil being less, and bitumen more viscous than 10,000 cp. Heavy crude then falls in the range 10/degree/-20/degree/ API inclusive and extra-heavy oil less than 10/degree/ API. Most natural bitumen is natural asphalt (tar sands, oil sands) and has been defined as rock containing hydrocarbons more viscous than 10,000 cp or else hydrocarbons that may be extracted from mined or quarried rock. Other natural bitumens are solids, such as gilsonite, grahamite, and ozokerite, which are distinguished by streak, fusibility, and solubility. The upper limit for heavy oil may also be set at 18/degree/ API, the approximate limit for recovery by waterflood.

  11. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop March 18, 2015 8:00AM EDT to...

  12. MULTIPHOTON DISSOCIATION PRODUCTS FROM HALOGENATED HYDROCARBONS

    E-Print Network [OSTI]

    Sudbo, Aa. S.

    2011-01-01T23:59:59.000Z

    FROM HALOGENATED HYDROCARBONS RECE1VED Aa. S. Sudbo, P. A.FROM HALOGENATED HYDROCARBONS LBL-6966 Aa. S. Sudbo, t P. A.

  13. Of the estimated 5 million barrels of crude oil released into the Gulf of Mexico from the Deepwater Horizon oil spill, a

    E-Print Network [OSTI]

    Weston, Ken

    Of the estimated 5 million barrels of crude oil released into the Gulf of Mexico from the Deepwater Horizon oil spill, a fraction washed ashore onto sandy beaches from Louisiana to the Florida panhandle. Researchers at the MagLab compare the detailed molecular analysis of hydrocarbons in oiled sands from

  14. Hydrocarbon sensors and materials therefor

    DOE Patents [OSTI]

    Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

  15. Microbial hydrocarbons: back to the future

    SciTech Connect (OSTI)

    Work, Victoria H.; Beliaev, Alex S.; Konopka, Allan; Posewitz, Matthew C.

    2012-03-01T23:59:59.000Z

    The defining challenge of energy research in the 21st century is the development and deployment of technologies for large-scale reconfiguration of global energy infrastructure. Modern society is built upon a concentrated yet finite reservoir of diverse hydrocarbons formed through the photosynthetic transformation of several hundred million years of solar energy. In human history, the fossil energy era will be short lived and never repeated. Although the timing of peak oil is extensively debated, it is an eventuality. It is, therefore, imperative that projections for both when it will occur and the degree to which supply will fall short of demand be taken into serious consideration, especially in the sectors of energy technology development, political and economic decision making, and societal energy usage. The requirement for renewable energy systems is no longer a point for discussion, and swift advances on many fronts are vital to counteract current and impending crises in both energy and the environment.

  16. Seismic interpretation and regional geologic correlation established for offshore Togo, West Africa: a preliminary evaluation of hydrocarbon potential in deep water

    E-Print Network [OSTI]

    Gray, Max Daniel

    2001-01-01T23:59:59.000Z

    of the major fault systems and unconformities. Proven source and reservoir formations from existing oil and gas fields in neighboring countries are analogous to formations identified on seismic for offshore Togo. Structures suitable for hydrocarbon...

  17. Biomarkers of polycyclic aromatic hydrocarbon (PAH) exposure in northwest Gulf of Mexico marine fish and invertebrates: indicators of offshore petroleum contamination

    E-Print Network [OSTI]

    Erickson, Cynthia Marie

    1994-01-01T23:59:59.000Z

    Higher molecular weight Polycyclic aromatic hydrocarbons (PAHS) associated with crude oil induce CYPIAI gene expression, and this response has been utilized as a biomarker of exposure to PAHs in aquatic and marine environments. Several benthic...

  18. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    growth. For data on world oil consumption and long- term oilOil Production Domestic Oil Consumption a variety of

  19. The influence of impregnation by hydrocarbons on coal structure during its thermal evolution

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    structure (hydrocarbon/oil-like substances) on the thermal evolution of the coal. The transformation ratio of the resultant products was performed. Changes in textural and microtextural properties associated and other hydrogenated products. This is, therefore, related to coals with high liptinite contents [6, 7, 8

  20. Influence of Hydrocarbons Exposure on Survival, Growth and Condition of Juvenile Flatfish: A Mesocosm Experiment

    E-Print Network [OSTI]

    Boyer, Edmond

    Biogéochimie et Ecotoxicologie (BE), Ifremer,BP70 29280 Plouzané, France KEYWORDS PAHs. Solea solea. Nursery/1000 v: v water: fuel), similar to what happened after an oil spill on coastal areas, affects survival to petroleum hydro- carbons and in particular Polycyclic Aromatic Hydrocarbons (PAHs). PAHs are regarded

  1. Effect of Temperature on Carbon-Black Agglomeration in Hydrocarbon Liquid with Adsorbed Dispersant

    E-Print Network [OSTI]

    can agglomerate, increasing the viscosity of the oil and significantly diminishing its lubrication performance. The soot can also form a high-viscosity sludge which can also degrade lubricant effectivenessEffect of Temperature on Carbon-Black Agglomeration in Hydrocarbon Liquid with Adsorbed Dispersant

  2. Origin of gaseous hydrocarbons from Upper Cretaceous and Tertiary strata in the Piceance basin, western Colorado

    E-Print Network [OSTI]

    Katz, David Jonathan

    1997-01-01T23:59:59.000Z

    by the Douglas Creek arch. The Piceance basin contains commercial quantities of both liquid and gaseous hydrocarbons in Tertiary-age oil shales and in tight Cretaceous-age sandstone reservoirs (Rice, 1993). Iles and Williams Fork strata deeper in the basin...

  3. Solution mining and heating by oxidation for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Stegemeier, George Leo (Houston, TX)

    2009-06-23T23:59:59.000Z

    A method for treating an oil shale formation comprising nahcolite includes providing a first fluid to a portion of the formation. A second fluid is produced from the portion. The second fluid includes at least some nahcolite dissolved in the first fluid. A controlled amount of oxidant is provided to the portion of the formation. Hydrocarbon fluids are produced from the formation.

  4. Have We Run Out of Oil Yet? Oil Peaking Analysis from an Optimist's Perspective

    SciTech Connect (OSTI)

    Greene, David L [ORNL; Hopson, Dr Janet L [University of Tennessee, Knoxville (UTK); Li, Jia [University of Tennessee, Knoxville (UTK)

    2005-01-01T23:59:59.000Z

    This study addresses several questions concerning the peaking of conventional oil production from an optimist's perspective. Is the oil peak imminent? What is the range of uncertainty? What are the key determining factors? Will a transition to unconventional oil undermine or strengthen OPEC's influence over world oil markets? These issues are explored using a model combining alternative world energy scenarios with an accounting of resource depletion and a market-based simulation of transition to unconventional oil resources. No political or environmental constraints are allowed to hinder oil production, geological constraints on the rates at which oil can be produced are not represented, and when USGS resource estimates are used, more than the mean estimate of ultimately recoverable resources is assumed to exist. The issue is framed not as a question of "running out" of conventional oil, but in terms of the timing and rate of transition from conventional to unconventional oil resources. Unconventional oil is chosen because production from Venezuela's heavy-oil fields and Canada's Athabascan oil sands is already underway on a significant scale and unconventional oil is most consistent with the existing infrastructure for producing, refining, distributing and consuming petroleum. However, natural gas or even coal might also prove to be economical sources of liquid hydrocarbon fuels. These results indicate a high probability that production of conventional oil from outside of the Middle East region will peak, or that the rate of increase of production will become highly constrained before 2025. If world consumption of hydrocarbon fuels is to continue growing, massive development of unconventional resources will be required. While there are grounds for pessimism and optimism, it is certainly not too soon for extensive, detailed analysis of transitions to alternative energy sources.

  5. Gas-assisted gravity drainage (GAGD) process for improved oil recovery

    DOE Patents [OSTI]

    Rao, Dandina N. (Baton Rouge, LA)

    2012-07-10T23:59:59.000Z

    A rapid and inexpensive process for increasing the amount of hydrocarbons (e.g., oil) produced and the rate of production from subterranean hydrocarbon-bearing reservoirs by displacing oil downwards within the oil reservoir and into an oil recovery apparatus is disclosed. The process is referred to as "gas-assisted gravity drainage" and comprises the steps of placing one or more horizontal producer wells near the bottom of a payzone (i.e., rock in which oil and gas are found in exploitable quantities) of a subterranean hydrocarbon-bearing reservoir and injecting a fluid displacer (e.g., CO.sub.2) through one or more vertical wells or horizontal wells. Pre-existing vertical wells may be used to inject the fluid displacer into the reservoir. As the fluid displacer is injected into the top portion of the reservoir, it forms a gas zone, which displaces oil and water downward towards the horizontal producer well(s).

  6. Barnett Shale Municipal Oil and Gas Ordinance Dynamics: A Spatial Perspective 

    E-Print Network [OSTI]

    Murphy, Trey Daniel-Aaron

    2013-09-27T23:59:59.000Z

    with the recent optimization of horizontal drilling, has substantially increased United States oil and gas production. Hydrocarbon firms perfected and use hydraulic fracturing on the Barnett Shale in North Texas; due to the nature of the formation, gas companies...

  7. Barnett Shale Municipal Oil and Gas Ordinance Dynamics: A Spatial Perspective

    E-Print Network [OSTI]

    Murphy, Trey Daniel-Aaron

    2013-09-27T23:59:59.000Z

    with the recent optimization of horizontal drilling, has substantially increased United States oil and gas production. Hydrocarbon firms perfected and use hydraulic fracturing on the Barnett Shale in North Texas; due to the nature of the formation, gas companies...

  8. Combination process for upgrading residual oils

    SciTech Connect (OSTI)

    Busch, L.E.; Walters, P.W.; Zandona, O.

    1990-01-16T23:59:59.000Z

    This patent describes a method for upgrading high boiling residual portions of crude oils comprising metal contaminants, porphyrins, asphaltenes and high molecular weight multi-ring hydrocarbon material. It comprises: charging a high boiling residual portion of crude oil admixed with diluent in contact with suspended upflowing substantially inert fluidizable solids particulate material at an elevated thermal visbreaking temperature in a riser contact zone for a time sufficient to recover therefrom a vaporous hydrocarbon product higher boiling than gasoline partially decarbonized and demetallized to a lower contaminating metals level, quenching the vaporous product of thermal visbreaking below its dew point after separation from solids, charging quenched thermally modified high boiling hydrocarbon product with a crystalline zeolite cracking catalyst under cracking conditions for a hydrocarbon residence time in a riser cracking zone; recovering a hydrocarbon conversion product; separating a combined C{sub 4} minus wet gas product stream of the visbreaking and zeolite catalyst cracking operating to recover a C{sub 3}-C{sub 4} rich fraction separately from a C{sub 2} minus dry gas product fraction, and regenerating the crystalline zeolite contcontaining catalyst.

  9. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

    2011-03-15T23:59:59.000Z

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  10. Enrichment of light hydrocarbon mixture

    DOE Patents [OSTI]

    Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2010-08-10T23:59:59.000Z

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  11. Enrichment of light hydrocarbon mixture

    DOE Patents [OSTI]

    Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2011-11-29T23:59:59.000Z

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  12. Method for producing viscous hydrocarbons

    DOE Patents [OSTI]

    Poston, Robert S. (Winter Park, FL)

    1982-01-01T23:59:59.000Z

    A method for recovering viscous hydrocarbons and synthetic fuels from a subterranean formation by drilling a well bore through the formation and completing the well by cementing a casing means in the upper part of the pay zone. The well is completed as an open hole completion and a superheated thermal vapor stream comprised of steam and combustion gases is injected into the lower part of the pay zone. The combustion gases migrate to the top of the pay zone and form a gas cap which provides formation pressure to produce the viscous hydrocarbons and synthetic fuels.

  13. Analysis, including estimation of water influx, and prediction of performance of volatile-oil reservoirs

    E-Print Network [OSTI]

    Ridings, Robert Lewis

    1958-01-01T23:59:59.000Z

    . Calculation of Apparent Hydrocarbon Pore Volume ~ 40 Illu. stration of Method to Calculate Pore Voluxne and Water Influx Coefficient ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 42 5. Calculation of Gas-Oil Relative Perxneability Ratio . 48 Prediction of Reservoir Performance... of Recombined Oil Sample at 249oF. , Reser- voir?A?, 63 0 Diffex ential Gas-Liberation Data at 250 F ?Syn- thetic Oil-Sample to Simulate Reservoir?A? Fluid, 64 12. Gas and Oil Viscosities . . . . . . . ~. . . . . . . 65 Equilibrium Ratios for Reservoir...

  14. aromatic hydrocarbon components: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AROMATIC HYDROCARBONS 2005 April 19 ABSTRACT Interstellar polycyclic aromatic hydrocarbon (PAH) infrared emission features 26 Dehydrogenation of polycyclic aromatic...

  15. Fuel Cell Technologies Office Overview: 2015 Hydrogen, Hydrocarbons...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overview: 2015 Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop Fuel Cell Technologies Office Overview: 2015 Hydrogen, Hydrocarbons, and Bioproduct...

  16. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

  17. Anomalous pH Dependent Stability Behavior of Surfactant-Free Nonpolar Oil Drops in Aqueous Electrolyte Solutions

    E-Print Network [OSTI]

    Chan, Derek Y C

    . In this study, we investigated the interaction across an aqueous thin film between fluorocarbon with a higher refractive index than water, and a fluorocarbon oil (perfluoropentane, C5F12), a liquid will be attractive for the hydrocarbon oil and repulsive for the fluorocarbon oil. Traditional methods

  18. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi KlavŸzar a,# , Petra Ÿ Zigert a , Ivan hydrocarbon: CL is equal to the minimum number of straight lines required to intersect all hexagons theory; Clar formula; Clar number; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within

  19. Aromaticity of Polycyclic Conjugated Hydrocarbons Milan Randic*

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    Aromaticity of Polycyclic Conjugated Hydrocarbons Milan Randic´* National Institute of Chemistry Chemistry 3462 G. Clar 6n Rule versus Hu¨ckel 4n + 2 Rule 3464 H. Hydrocarbons versus Heteroatomic Systems Ordering 3476 VI. On Enumeration of Benzenoid Hydrocarbons 3477 VII. Kekule´ Valence Structures Count 3479

  20. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi Klavzara, , Petra Zigerta , Ivan Gutmanb sextets in any of the Clar formulae) of a catacondensed benzenoid hydrocarbon: CL is equal to the minimum; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within the theory that was formulated [1, 2

  1. Cuticular Hydrocarbon Research1 Marion Page2

    E-Print Network [OSTI]

    Standiford, Richard B.

    Cuticular Hydrocarbon Research1 Marion Page2 We have been studying existing taxonomies of forest in the utility of cuticular (surface) hydrocarbons as taxonomic characters (Haverty and others 1988, 1989, Page to be genetically fixed. Because the insects studied so far synthesize all or most of their hydrocarbon components

  2. Federal Environmental Regulations Impacting Hydrocarbon Exploration, Drilling, and Production Operations

    SciTech Connect (OSTI)

    Carroll, Herbert B.; Johnson, William I.

    1999-04-27T23:59:59.000Z

    Waste handling and disposal from hydrocarbon exploration, drilling, and production are regulated by the US Environmental Protection Agency (EPA) through federal and state regulations and/or through implementation of federal regulations. Some wastes generated in these operations are exempt under the Resource Conservation and Recovery Act (RCRA) but are not exempt under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendments and Reauthorization Act (SARA), and other federal environmental laws. Exempt wastes remain exempt only if they are not mixed with hazardous wastes or hazardous substances. Once mixture occurs, the waste must be disposed as a hazardous material in an approved hazardous waste disposal facility. Before the Clean Air Act as amended in 1990, air emissions from production, storage, steam generation, and compression facilities associated with hydrocarbon exploration, drilling, and production industry were not regulated. A critical proposed regulatory change which will significantly effect Class II injection wells for disposal of produced brine and injection for enhanced oil recovery is imminent. Federal regulations affecting hydrocarbon exploration, drilling and production, proposed EPA regulatory changes, and a recent significant US Court of Appeals decision are covered in this report. It appears that this industry will, in the future, fall under more stringent environmental regulations leading to increased costs for operators.

  3. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    or natural gas or even oil shale (which represents anotherto transform the coal or oil shale or gaseous, fuel. There

  4. Tailoring hydrocarbon streams for asphaltene removal

    SciTech Connect (OSTI)

    Del Bianco, A.; Stroppa, F.; Bertero, L.

    1995-11-01T23:59:59.000Z

    Oilfield production is often hindered by asphaltene precipitation which tends to fill the pores of the reservoir rocks and plug the wellbore tubing as well as the other auxiliary equipment used during crude oil recovery. Several remedies to remove these deposits have been proposed and patented but the injection of aromatic solvents such as toluene and light petroleum distillates is normally preferred. Previous studies with a number of pure aromatic hydrocarbons have shown that the solvent capacity of these molecules may be very different and that the degree of condensation plays an important role. In this regard, tetralins and naphthalenes are superior to alkylbenzenes. However, because the use of pure compounds is not economically feasible, the authors examined various industrial streams and the authors correlated their chemical composition to the solvent capacity. This work allowed the identification of the pseudo-components whose relative concentration is crucial for evaluating the solvent performances. Based on these data, the authors were able to find new products with ideal characteristics. The efficiency of one of these products was confirmed by the analysis of the data obtained when using this new solvent to remove asphaltene in damaged wells of an Italian field.

  5. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

  6. Enhanced oil recovery system

    DOE Patents [OSTI]

    Goldsberry, Fred L. (Spring, TX)

    1989-01-01T23:59:59.000Z

    All energy resources available from a geopressured geothermal reservoir are used for the production of pipeline quality gas using a high pressure separator/heat exchanger and a membrane separator, and recovering waste gas from both the membrane separator and a low pressure separator in tandem with the high pressure separator for use in enhanced oil recovery, or in powering a gas engine and turbine set. Liquid hydrocarbons are skimmed off the top of geothermal brine in the low pressure separator. High pressure brine from the geothermal well is used to drive a turbine/generator set before recovering waste gas in the first separator. Another turbine/generator set is provided in a supercritical binary power plant that uses propane as a working fluid in a closed cycle, and uses exhaust heat from the combustion engine and geothermal energy of the brine in the separator/heat exchanger to heat the propane.

  7. Energy Management by Recycling of Vehicle Waste Oil in Pakistan

    E-Print Network [OSTI]

    Hassan Ali Durrani

    Abstract: Pakistan has been suffering from an energy crisis for about half a decade now. The power crisis is proving to be unbearable, so importing huge amount of hydrocarbons from abroad to meet its energy needs. This study therefore focuses on the analysis of energy and environmental benefits for vehicle waste lubricant oil pertaining to its reuse by means of: (i) regain the heating value of used oils in a combustion process and (ii) recycling of waste oil to make fresh oil products. The waste oil samples were tested by ICP method and the test results were compared with standard requirements. It was found that the matter could effectively be solved by means of waste oil management practices together with collection centers, transports and processors by encouraging and financial help for the recycling industry. The importance and worth of this work concludes minor levels of hazardous elements when regained the heating value from the waste lubricating oil.

  8. Origin and migration of hydrocarbons in the Paleozoic system of Saudi Arabia

    SciTech Connect (OSTI)

    Franz, U.A. (Mobil Exploration and Producing Services, Dallas, TX (United States))

    1991-08-01T23:59:59.000Z

    This paper is a progress report on geochemical studies of the sub-Khuff Paleozoic rocks in Saudi Arabia, summarizing current laboratory results from both Saudi Aramco and American companies and their preliminary interpretations. From oil/oil and oil/rock correlations as well as maturity modeling, it may be concluded that sweet sub-Khuff oils, condensates, and gases are closely related to each other, and are derived from a common source: the hot shales of the basal Qusaiba Formation (Lower Silurian). The hydrocarbons that have been discovered in the Hawtah trend must have migrated updip from the presently overmature Rub-Al-Khali depocenter, where oil generation was initiated as early as 160 Ma. The oil window in the Rub-Al-Khali embayment, where active oil and condensate generation is taking place at present, is at depths between approximately 10,000 and 14,000 ft. Oil accumulation housed at depths more than approximately 14,000 {plus minus} 500 ft are being cracked into gas and condensate depending on variations in the generally low geothermal gradients of 1.5 {plus minus} 0.1F/100 ft. The residue of this natural refinery process is pyrobitumen, or deal oil, that is a pore plugging agent in many reservoirs at these depths. All products have very low-sulfur kerogen. The economic impact of these findings is very significant.

  9. DEVELOPMENT OF BIOSURFACTANT-MEDIATED OIL RECOVERY IN MODEL POROUS SYSTEMS AND COMPUTER SIMULATIONS OF BIOSURFACTANT-MEDIATED OIL RECOVERY

    SciTech Connect (OSTI)

    M.J. McInerney; S.K. Maudgalya; R. Knapp; M. Folmsbee

    2004-05-31T23:59:59.000Z

    Current technology recovers only one-third to one-half of the oil that is originally present in an oil reservoir. Entrapment of petroleum hydrocarbons by capillary forces is a major factor that limits oil recovery (1, 3, 4). Hydrocarbon displacement can occur if interfacial tension (IFT) between the hydrocarbon and aqueous phases is reduced by several orders of magnitude. Microbially-produced biosurfactants may be an economical method to recover residual hydrocarbons since they are effective at low concentrations. Previously, we showed that substantial mobilization of residual hydrocarbon from a model porous system occurs at biosurfactant concentrations made naturally by B. mojavensis strain JF-1 if a polymer and 2,3-butanediol were present (2). In this report, we include data on oil recovery from Berea sandstone experiments along with our previous data from sand pack columns in order to relate biosurfactant concentration to the fraction of oil recovered. We also investigate the effect that the JF-2 biosurfactant has on interfacial tension (IFT). The presence of a co-surfactant, 2,3-butanediol, was shown to improve oil recoveries possibly by changing the optimal salinity concentration of the formulation. The JF-2 biosurfactant lowered IFT by nearly 2 orders of magnitude compared to typical values of 28-29 mN/m. Increasing the salinity increased the IFT with or without 2,3-butanediol present. The lowest interfacial tension observed was 0.1 mN/m. Tertiary oil recovery experiments showed that biosurfactant solutions with concentrations ranging from 10 to 60 mg/l in the presence of 0.1 mM 2,3-butanediol and 1 g/l of partially hydrolyzed polyacrylamide (PHPA) recovered 10-40% of the residual oil present in Berea sandstone cores. When PHPA was used alone, about 10% of the residual oil was recovered. Thus, about 10% of the residual oil recovered in these experiments was due to the increase in viscosity of the displacing fluid. Little or no oil was recovered at biosurfactant concentrations below the critical micelle concentration (about 10 mg/l). Below this concentration, the IFT values were high. At biosurfactant concentrations from 10 to 40 mg/l, the IFT was 1 mN/m. As the biosurfactant concentration increased beyond 40 mg/l, IFT decreased to about 0.1 mN/m. At biosurfactant concentrations in excess of 10 mg/l, residual oil recovery was linearly related to biosurfactant concentration. A modified mathematical model that relates oil recovery to biosurfactant concentration adequately predicted the experimentally observed changes in IFT as a function of biosurfactant concentration.

  10. Study of net soot formation in hydrocarbon reforming for hydrogen fuel cells. Final report

    SciTech Connect (OSTI)

    Edelman, R. B.; Farmer, R. C.; Wang, T. S.

    1982-08-01T23:59:59.000Z

    The hydrogen fuel cell is expected to be a valuable addition to the electric utility industry; however, the current fuel supply availability requires that conventional heavier hydrocarbon fuels also be considered as primary fuels. Typical heavier fuels would be No. 2 fuel oil with its accompanying sulfur impurities, compared with the currently used light hydrocarbon gases. The potential future use of alternate fuels which are rich in aromatics would exacerbate the problems associated with hydrogen production. Among the more severe of these problems, is the greater tendency of heavier hydrocarbons to form soot. The development of a quasi-global kinetics model to represent the homogeneous and heterogeneous reactions which control the autothermal hydrogen reforming process and the accompanying soot formation and gasification was the objective of this study.

  11. Underground caverns for hydrocarbon storage

    SciTech Connect (OSTI)

    Barron, T.F. [Exeter Energy Services, Houston, TX (United States)

    1998-12-31T23:59:59.000Z

    Large, international gas processing projects and growing LPG imports in developing countries are driving the need to store large quantities of hydrocarbon liquids. Even though underground storage is common in the US, many people outside the domestic industry are not familiar with the technology and the benefits underground storage can offer. The latter include lower construction and operating costs than surface storage, added safety, security and greater environmental acceptance.

  12. Deep desulfurization of hydrocarbon fuels

    DOE Patents [OSTI]

    Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

    2012-04-17T23:59:59.000Z

    The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

  13. Topical viscosity control for light hydrocarbon displacing fluids in petroleum recovery and in fracturing fluids for well stimulation

    DOE Patents [OSTI]

    Heller, John P. (Socorro, NM); Dandge, Dileep K. (Socorro, NM)

    1986-01-01T23:59:59.000Z

    Solvent-type flooding fluids comprising light hydrocarbons in the range of ethane to hexane (and mixtures thereof) are used to displace crude oil in formations having temperatures of about 20 degrees to about 150 degrees Centigrade and pressures above about 650 psi, the light hydrocarbons having dissolved therein from about 0.05% to about 3% of an organotin compound of the formula R.sub.3 SnF where each R is independently an alkyl, aryl or alkyaryl group from 3 to 12 carbon atoms. Under the pressures and temperatures described, the organotin compounds become pentacoordinated and linked through the electronegative bridges, forming polymers within the light hydrocarbon flooding media to render them highly viscous. Under ambient conditions, the viscosity control agents will not readily be produced from the formation with either crude oil or water, since they are insoluble in the former and only sparingly soluble in the latter.

  14. Mixed surfactant systems for enhanced oil recovery

    SciTech Connect (OSTI)

    Llave, F.M.; Gall, B.L.; Noll, L.A.

    1990-12-01T23:59:59.000Z

    The results of an evaluation of mixed surfactant systems for enhanced oil recovery are described. Several surfactant combinations have been studied. These include alkyl aryl sulfonates as primary surfactants and carboxymethylated ethoxylated (CME) surfactants and ethoxylated sulfonates (ES) as secondary surfactants. The ethoxylated surfactants increase the salinity tolerance of the primary surfactants and, in theory, allow tailoring of the surfactant system to match selected reservoir conditions. The experiments conducted included interfacial tension (IFT) measurements, phase behavior measurements, adsorption and/or chromatographic separation of mixed surfactant systems, measurements of solution properties such as the critical micelle concentration (CMC) of surfactant mixtures, and crude oil displacement experiments. The effects of temperature, surfactant concentration, salinity, presence of divalent ions, hydrocarbon type, and component proportions in the mixed surfactant combinations, and injection strategies on the performance potential of the targeted surfactant/hydrocarbon systems were studied. 40 refs., 37 figs., 8 tabs.

  15. OFFICE OF RESPONSE AND RESTORATION ! EMERGENCY RESPONSE DIVISION Deepwater Horizon Oil

    E-Print Network [OSTI]

    generally because it is relatively much lower in polyaromatic hydrocarbons (PAHs). PAHs are highly toxic reaches the surface and spreads out across the water, its lighter components, including VOCs, soon, or rainbow-colored. MS252 oil will also mix with water to form a sticky, pudding-like water-in-oil emulsion

  16. Arabian crude-oil residues evaluated

    SciTech Connect (OSTI)

    Ali, M.F.; Bukhari, A.; Hasan, M.; Saleem, M.

    1985-08-12T23:59:59.000Z

    This article evaluates detailed physical and chemical characteristics for four important Saudi Arabian resids. Petroleum residues are composed of a mixture of large and complex hydrocarbon molecules along with one or more heteroatoms such as sulfur, oxygen, nitrogen, vanadium, and nickel. The amount of residue and its physical and chemical composition depend on the source of the crude oil and methods of processing. Residues from four Saudi Arabian crude oils produced by the Arabian American Oil Co. (Aramco) were evaluated. The crude oils are 38.5 degrees API Arabian Extra Light, 33.8 degrees API Arabian Light, 30.4 degrees Api Arabian Medium, and 28.03 degrees API Arabian Heavy. Results are presented and residue preparation, and physical and chemical characteristics are analyzed.

  17. The MS-Q Force Field for Clay Minerals: Application to Oil Production Sungu Hwang, Mario Blanco, Ersan Demiralp, Tahir Cagin, and William A. Goddard, III*

    E-Print Network [OSTI]

    Çagin, Tahir

    The MS-Q Force Field for Clay Minerals: Application to Oil Production Sungu Hwang, Mario Blanco inhibitor oil production chemical. 1. Introduction Molecular modeling studies of clay and related zeolite of water, hydrocarbons, and polar organic compounds such as oil field production chemicals on clay mineral

  18. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01T23:59:59.000Z

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  19. Hydrocarbon-bearing fluid inclusions in fluorite associated with the Windy Knoll bitumen deposit, UK

    SciTech Connect (OSTI)

    Moser, M.R. (Imperial College, London (United Kingdom) University College, London (United Kingdom)); Rankin, A.H. (Imperial College, London (United Kingdom)); Milledge, H.J. (University College, London (United Kingdom))

    1992-01-01T23:59:59.000Z

    Hydrocarbon-bearing fluid inclusions in fluorite, associated with an outcropping bitumen deposit at Windy Knoll, Derbyshire, have been analyzed in situ using a combination of microthermometry, Fourier transform infrared (FTIR) microspectrometry, and ultraviolet (UV) microscopy. The inclusions in these samples can be considered as a series with two end members: aqueous inclusions containing a low-density vapor phase and inclusions containing liquid oil' with no detectable aqueous phase. The majority of the inclusions are mixed types containing both aqueous and liquid hydrocarbon phases. Although microthermometry distinguishes at least two different aqueous fluids with varying homogenization temperatures and salinities, the oil fraction is cogenetic and trapped together with just one fluid, a low-salinity, low-calcium brine with an average homogenization temperature of 134C. The majority of the liquid hydrocarbon-bearing inclusions fluoresce bright blue under UV illumination with peaks around 475 nm, characteristic of paraffinic oils. The FTIR spectra of these inclusions are dominated by peaks assigned to aliphatic C-H bonding. However, inclusions have also been found which display a fluorescence typical of the red-shift associated with less mature oils. The FTIR spectra display peaks assigned to C{double bond}O, C-O, and O-CH{sub 2} bonding. This study presents new data on the in-situ analysis of hydrocarbon-bearing fluid inclusion from this important area of natural petroleum seepage and ore mineralization. The results suggest a direct link between the fluid inclusion populations, the outcropping bitumens, and fluorite deposition.

  20. Solution mining dawsonite from hydrocarbon containing formations with a chelating agent

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX)

    2009-07-07T23:59:59.000Z

    A method for treating an oil shale formation comprising dawsonite includes providing heat from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation. At least some dawsonite in the formation is decomposed with the provided heat. A chelating agent is provided to the formation to dissolve at least some dawsonite decomposition products. The dissolved dawsonite decomposition products are produced from the formation.

  1. Nox reduction system utilizing pulsed hydrocarbon injection

    DOE Patents [OSTI]

    Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

  2. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Digestion and Hydrocarbon Precursor Production Presentation by Meltem Urgun-Demirtas, Argonne National Laboratory, during the "Targeting High-Value Challenges" panel at the...

  3. Hydrocarbon Technologies | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEIHesperia, California:Project JumpHyEnergyHydrocarbon Technologies

  4. Hydrocarbon-free resonance transition 795 nm rubidium laser

    E-Print Network [OSTI]

    Wu, Sheldon Shao Quan

    2009-01-01T23:59:59.000Z

    and R. J. Beach, "Hydrocarbon-free resonance transition 795-a Reliable Diode-Pumped Hydrocarbon-Free 795-nm Rubidiumand R. J. Beach, "Hydrocarbon-free resonance transition 795-

  5. Alteration, HFSE mineralisation and hydrocarbon formation in peralkaline igneous systems

    E-Print Network [OSTI]

    Long, Bernard

    hydrothermal alteration to produce hydrocarbons via a Fischer­Tropsch synthesis. As a result, hydrocarbons alteration; Abiogenic hydrocarbons; Fischer­Tropsch; HFSE mineralization; Strange Lake Lithos 91 (2006) 19

  6. Research on improved and enhanced oil recovery in Illinois through reservoir characterization

    SciTech Connect (OSTI)

    Oltz, D.F.

    1992-01-01T23:59:59.000Z

    This project will provide information that can maximize hydrocarbon production minimize formation damage and stimulate new production in Illinois. Such information includes definition of hydrocarbon resources, characterization of hydrocarbon reservoirs, and the implementation of methods that will improve hydrocarbon extractive technology. Increased understanding of reservoir heterogeneities that affect oil recovery can aid in identifying producible resources. The transfer of technology to industry and the general public is a significant component of the program. The project is designed to examine selected subsurface oil reservoirs in Illinois. Scientists use advanced scientific techniques to gain a better understanding of reservoir components and behavior and address ways of potentially increasing the amount of recoverable oil. Initial production rates for wells in the Illinois Basin commonly decline quite rapidly and as much as 60 percent of the oil in place can be unrecoverable using standard operating procedures. Heterogeneities (geological differences in reservoir make-up) affect a reservoir's capability to release fluids. By-passed mobile and immobile oil remain in the reservoir. To learn how to get more of the oil out of reservoirs, the ISGS is studying the nature of reservoir rock heterogeneities and their control on the distribution and production of by-passed, mobile oil.

  7. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    the Oil Industry . . . . . . . . . . . . . . . . . . . . . .in the Venezuelan Oil Industry . . . . . . . . . . . . .and Productivity: Evidence from the Oil Industry . .

  8. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production . . . . . . . . . . . . . . . . . . . . . . . . . . .Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and

  9. Polynuclear aromatic hydrocarbons for fullerene synthesis in flames

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D.

    2006-12-19T23:59:59.000Z

    This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

  10. Investigation and development of alternative methods for shale oil processing and analysis. Final technical report, October 1979--April 1983

    SciTech Connect (OSTI)

    Evans, R.A.

    1998-06-01T23:59:59.000Z

    Oil shale, a carbonaceous rock which occurs abundantly in the earth`s crust, has been investigated for many years as an alternate source of fuel oil. The insoluble organic matter contained in such shales is termed {open_quotes}Kerogen{close_quotes} from the Greek meaning oil or oil forming. The kerogen in oil shale breaks down into oil-like products when subjected to conditions simulating destructive distillation. These products have been the subject of extensive investigations by several researchers and many of the constituents of shale oil have been identified. (1) Forsman (2) estimates that the kerogen content of the earth is roughly 3 {times} 10{sup 15} tons as compared to total coal reserves of about 5 {times} 10{sup 12}. Although the current cost per barrel estimate for commercial production of shale oil is higher than that of fossil oil, as our oil reserves continue to dwindle, shale oil technology will become more and more important. When oil shale is heated, kerogen is said to undergo chemical transformation to usable oil in two steps (3): Kerogen (in oil shale) 300-500{degrees}C bitumen. Crude shale oil and other products. The crude shale oil so obtained differs from fossil oil in that: (1) kerogen is thought to have been produced from the aging of plant matter over many years; (2) shale oil has a higher nitrogen content than fossil oil; (3) non-hydrocarbons are present to a much greater extent in shale oil; and (4) the hydrocarbons in shale oil are much more unsaturated than those in fossil oil (petroleum).

  11. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, Elias (Oak Ridge, TN)

    1995-01-01T23:59:59.000Z

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

  12. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, E.

    1995-05-23T23:59:59.000Z

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

  13. Commercialization of IH2® Biomass Direct-to-Hydrocarbon Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and...

  14. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

  15. Biological Conversion of Sugars to Hydrocarbons Technology Pathway...

    Broader source: Energy.gov (indexed) [DOE]

    for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Biological Conversion of Sugars to Hydrocarbons...

  16. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, J.D.; Harak, A.E.

    1988-05-04T23:59:59.000Z

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

  17. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, James D. (Laramie, WY); Harak, Arnold E. (Laramie, WY)

    1989-01-01T23:59:59.000Z

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

  18. Hydrocarbon cracking with yttrium exchanged zeolite y catalyst

    SciTech Connect (OSTI)

    Lochow, C.F.; Kovacs, D.B.

    1987-05-12T23:59:59.000Z

    A process is described for cracking a gas oil boiling range hydrocarbon feedstock comprising the step of contacting the feedstock in a catalytic cracking zone under catalytic cracking conditions to produce convulsion products comprising gasoline with a catalyst composition. The process comprises: a Y crystalline aluminosilicate zeolite, having the structure of faujasite and having uniform pore diameters and a silica to alumina mole ratio of at least about 5; an inorganic oxide matrix; and the zeolite having been ion exchanged with a mixture of rare earths prior to compositing with the matrix; and the zeolite having been subsequently further ion exchanged with yttrium following compositing with the matrix, whereby the catalyst composition contains 0.30 to 3.0 wt% yttrium.

  19. Solution mining systems and methods for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); de Rouffignac, Eric Pierre (Rijswijk, NL); Schoeling, Lanny Gene (Katy, TX)

    2009-07-14T23:59:59.000Z

    A method for treating an oil shale formation comprising nahcolite is disclosed. The method includes providing a first fluid to a portion of the formation through at least two injection wells. A second fluid is produced from the portion through at least one injection well until at least two injection wells are interconnected such that fluid can flow between the two injection wells. The second fluid includes at least some nahcolite dissolved in the first fluid. The first fluid is injected through one of the interconnected injection wells. The second fluid is produced from at least one of the interconnected injection wells. Heat is provided from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation.

  20. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    Reports and Publications (EIA)

    2014-01-01T23:59:59.000Z

    Over the past five years, rapid growth in U.S. onshore natural gas and oil production has led to increased volumes of natural gas plant liquids (NGPL) and liquefied refinery gases (LRG). The increasing economic importance of these volumes, as a result of their significant growth in production, has revealed the need for better data accuracy and transparency to improve the quality of historical data and projections for supply, demand, and prices of these liquids, co-products, and competing products. To reduce confusion in terminology and improve its presentation of data, EIA has worked with industry and federal and state governments to clarify gas liquid terminology and has developed the term Hydrocarbon Gas Liquids, or HGL.

  1. Tectonics and hydrocarbon potential of the Barents Megatrough

    SciTech Connect (OSTI)

    Baturin, D.; Vinogradov, A.; Yunov, A. (LARGE International, Moscow (USSR))

    1991-08-01T23:59:59.000Z

    Interpretation of geophysical data shows that the geological structure of the Eastern Barents Shelf, named Barents Megatrough (BM), extends sublongitudinally almost from the Baltic shield to the Franz Josef Land archipelago. The earth crust within the axis part of the BM is attenuated up to 28-30 km, whereas in adjacent areas its thickness exceeds 35 km. The depression is filled with of more than 15 km of Upper Paleozoic, Mesozoic, and Cenozoic sediments overlying a folded basement of probable Caledonian age. Paleozoic sediments, with exception of the Upper Permian, are composed mainly of carbonates and evaporites. Mesozoic-Cenozoic sediments are mostly terrigenous. The major force in the development of the BM was due to extensional tectonics. Three rifting phases are recognizable: Late Devonian-Early Carboniferous, Early Triassic, and Jurassic-Early Cretaceous. The principal features of the geologic structure and evolution of the BM during the late Paleozoic-Mesozoic correlate well with those of the Sverdup basin, Canadian Arctic. Significant quantity of Late Jurassic-Early Cretaceous basaltic dikes and sills were intruded within Triassic sequence during the third rifting phase. This was probably the main reason for trap disruption and hydrocarbon loss from Triassic structures. Lower Jurassic and Lower Cretaceous reservoir sandstones are most probably the main future objects for oil and gas discoveries within the BM. Upper Jurassic black shales are probably the main source rocks of the BM basin, as well as excellent structural traps for hydrocarbon fluids from the underlying sediments.

  2. Thermal response of process equipment to hydrocarbon fires

    SciTech Connect (OSTI)

    Solberg, D.M.; Borgnes, O.

    1983-01-01T23:59:59.000Z

    Requirements for active fire-fighting equipment such as fixed and portable powder extinguishers, foam generators, water guns, and deluge systems, are given in various codes and standards. However, very little is to be found about fire design conditions and passive fire protection. For safety verification of process plants and for designing adequate passive fire protection it is necessary to know the total incident heat fluxes which can occur under realistic conditions and the effects that such heat fluxes may have on process equipment and structures. During the last few years, Det Norske Veritas has been invloved in investigations aimed at estimating realistic fire loads from different types of hydrocarbon fires and the thermal response of process equipment and structures exposed to such fires. These investigations are still in progress and are especially focused on the conditions on off-shore oil and gas production platforms. However, many fire problems will be the same in the land-based process industry. The present paper concentrates on the thermal response of pipes and vessels exposed to a severe hydrocarbon fire with a defined thermal load. (JMT)

  3. Geochemical Prospecting of Hydrocarbons in Frontier Basins of India* By

    E-Print Network [OSTI]

    B. Kumar; D. J. Patil; G. Kalpana; C. Vishnu Vardhan

    India has 26 sedimentary basins with a basinal area of approximately 1.8x 10 6 km 2 (excluding deep waters), out of which seven are producing basins and two have proven potential. Exploration efforts in other basins, called “frontier basins ” are in progress. These basins are characterized by varied geology, age, tectonics, and depositional environments. Hydrocarbon shows in many of these basins are known, and in few basins oil and gas have flowed in commercial /non-commercial quantities. Within the framework of India Hydrocarbon Vision – 2025 and New Exploration Licensing Policy, there is a continuous increase in area under active exploration. The asset management concept with multi-disciplinary teams has created a demand for synergic application of risk-reduction technologies, including surface geochemical surveys. National Geophysical Research Institute (NGRI), Hyderabad, India has initiated/planned surface geochemical surveys composed of gas chromatographic and carbon isotopic analyses in few of the frontier basins of India. The adsorbed soil gas data in one of the basins (Saurashtra basin, Gujarat) has shown varied concentrations of CH4 to C4H10. The C1 concentration varies between 3 to 766 ppb and ??C2+, 1 to 543 ppb. This basin has thin soil cover and the Mesozoic sediments (probable source rocks) are overlain by thick cover of Deccan Traps. The scope and perspective of geochemical surveys in frontier basins of India are presented here.

  4. Libyan Paleozoic: A review of the factors limiting hydrocarbon potential

    SciTech Connect (OSTI)

    Kanes, W.H.; Mairn, A.E.M.; Aburawi, R.M.

    1988-08-01T23:59:59.000Z

    Of the three main Paleozoic basins - Ghadames, Murquz, and Kufra - only the Ghadames and its continuation into Algeria, the Illizi (or Fort Polignac) basin, has yielded hydrocarbons in significant quantity. The Paleozoic on the Cyrenaica platform and basement of the Sirte basin has a potential not fully considered. The paleogeography of the Paleozoic system is reviewed to illustrate the extent to which inherited and reactivated basement-controlled structures have influenced later Paleozoic sedimentation and hence the distribution of source rocks, reservoirs, and seals. In all instances, the source rocks are restricted to shales of the Tanezufft Formation or occur in the Upper Devonian Aouinet Oeunine Formation. Multiple fine-grained sequences serve as seals in all the fields. The reservoirs range from the well-cemented but highly fractured Cambrian-Ordovician Gargaf sandstones to the Acacus-Tadrart clastics to the fine-grained Lower Carboniferous Tahara Sandstone. The principal plays are associated with minor structures, and stratigraphic trapping mechanisms play a minor role. The average field size (excluding the Sirte basin) is approximately 80 million bbl of recoverable oil. Paleozoic structural plays in the Sirte basin and the Cyrenaica platform include reactivated infra-Cambrian faults. The lower Paleozoic accumulations of the Murzuq basin are tied to large structures. With the exception of local areas in the Ghadames basin, the Paleozoic succession remains a stratigraphic frontier province - still incompletely explored but with several interesting possibilities for large amounts of stratigraphically trapped hydrocarbons.

  5. Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars

    SciTech Connect (OSTI)

    Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

    2014-05-18T23:59:59.000Z

    Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

  6. Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient air

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient of polycyclic aromatic hydrocarbons (PAHs) and of their oxidation products, such as nitrated and oxygenated PAHs hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons; Sampling

  7. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two aromatic hydrocarbons, 17 nitrated PAHs (NPAHs) and 8 oxygenated PAHs (OPAHs) were carried out during hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons

  8. Syntectonic hydrocarbon migration and accumulation in Miley Reservoir, Rincon field, Ventura County, California

    SciTech Connect (OSTI)

    Nelson, D.E.; Harrison, R.A.

    1987-05-01T23:59:59.000Z

    The Miley reservoir of the Rincon field is located in the Central Transverse Ranges of southern California on a structural high that borders the Santa Barbara Channel. The east-west-trending Rincon and Ventura anticlines are part of a major oil-productive trend containing the Rincon, San Miguelito, and Ventura Avenue fields, which have estimated ultimate recovery of 1.7 billion BOE. Hydrocarbon accumulations in the multiple and stacked reservoirs within these three fields are controlled by the complex interplay of late Pleistocene folding and reverse fault development. The detailed interpretation reported here combines reservoir performance data with subsurface structural geology and sequential tectonic development to provide a new understanding of the relationship of migration barriers to oil accumulation and production. The Miley reservoir is an axial- and fault-controlled accumulation on the eastern terminus of the Rincon anticline. It is located in a structural saddle formed by the doubly plunging Rincon and Ventura anticlinal trend. Three operative trapping mechanisms confine oil pools: (1) axial accumulations associated with reverse fault closures; (2) traps on the hanging wall of dip-slip reverse faults; and (3) a permeability barrier developed in response to flexural slip folding. Oil trapped within the Rincon-Miley reservoir was primarily generated beneath the Santa Barbara Channel and migrated up the south flank of the anticlinal trend. Four stages of structural development and hydrocarbon migration, encompassing the last 700,000 years, have implications for the enhanced development of reservoirs on this anticlinal trend.

  9. Effective Viscosity of Confined Hydrocarbons

    E-Print Network [OSTI]

    I. M. Sivebaek; V. N. Samoilov; B. N. J. Persson

    2012-01-24T23:59:59.000Z

    We present molecular dynamics friction calculations for confined hydrocarbon films with molecular lengths from 20 to 1400 carbon atoms. We find that the logarithm of the effective viscosity \\mu eff for nanometer-thin films depends linearly on the logarithm of the shear rate: log(effective viscosity) = C - n log (shear rate), where n varies from 1 (solidlike friction) at very low temperatures to 0 (Newtonian liquid) at very high temperatures, following an inverse sigmoidal curve. Only the shortest chain molecules melt, whereas the longer ones only show a softening in the studied temperature interval 0 < T < 900 K. The results are important for the frictional properties of very thin (nanometer) films and to estimate their thermal durability.

  10. What are Tar Balls and How Do They Form? Tar balls, the little, dark-colored pieces of oil that

    E-Print Network [OSTI]

    a heavier refined product) floats on the ocean surface, its physical characteristics change. During crude oils mix with water to form an emulsion that often looks like chocolate pudding. This emulsion to chemicals, including the hydrocarbons found in crude oil and petroleum products. They may have an allergic

  11. Research on improved and enhanced oil recovery in Illinois through reservoir characterization, March 28, 1992--June 28, 1992

    SciTech Connect (OSTI)

    Oltz, D.F.

    1992-01-01T23:59:59.000Z

    This project will provide information that can maximize hydrocarbon production, minimize formation damage and stimulate new production in Illinois. Such information includes definition of hydrocarbon resources, characterization of hydrocarbon reservoirs, and the implementation of methods that will improve hydrocarbon extractive technology. Increased understanding of reservoir heterogeneities that affect oil recovery can aid in identifying producible resources. The transfer of technology to industry and the general public is a significant component of the program. The project is designed to examine selected subsurface oil reservoirs in Illinois. Scientists use advanced scientific techniques to gain a better understanding of reservoir components and behavior and address ways of potentially increasing the amount of recoverable oil. Initial production rates for wells in the Illinois Basin commonly decline quite rapidly and as much as 60 percent of the oil in place can be unrecoverable using standard operating procedures. Heterogeneities (geological differences in reservoir make-up) affect a reservoir's capability to release fluids. By-passed mobile and immobile oil remain in the reservoir. To learn how to get more of the oil out of reservoirs, the ISGS is studying the nature of reservoir rock heterogeneities and their control on the distribution and production of bypassed, mobile oil. Accomplishment for this period are summarized for the following tasks: mapping, cross-sections; subsurface depo-systems; outcrop studies; oil and gas development maps; engineering work; SEM/EDX; and clay minerals.

  12. Research on improved and enhanced oil recovery in Illinois through reservoir characterization, March 28, 1992--June 28, 1992

    SciTech Connect (OSTI)

    Oltz, D.F.

    1992-09-01T23:59:59.000Z

    This project will provide information that can maximize hydrocarbon production, minimize formation damage and stimulate new production in Illinois. Such information includes definition of hydrocarbon resources, characterization of hydrocarbon reservoirs, and the implementation of methods that will improve hydrocarbon extractive technology. Increased understanding of reservoir heterogeneities that affect oil recovery can aid in identifying producible resources. The transfer of technology to industry and the general public is a significant component of the program. The project is designed to examine selected subsurface oil reservoirs in Illinois. Scientists use advanced scientific techniques to gain a better understanding of reservoir components and behavior and address ways of potentially increasing the amount of recoverable oil. Initial production rates for wells in the Illinois Basin commonly decline quite rapidly and as much as 60 percent of the oil in place can be unrecoverable using standard operating procedures. Heterogeneities (geological differences in reservoir make-up) affect a reservoir`s capability to release fluids. By-passed mobile and immobile oil remain in the reservoir. To learn how to get more of the oil out of reservoirs, the ISGS is studying the nature of reservoir rock heterogeneities and their control on the distribution and production of bypassed, mobile oil. Accomplishment for this period are summarized for the following tasks: mapping, cross-sections; subsurface depo-systems; outcrop studies; oil and gas development maps; engineering work; SEM/EDX; and clay minerals.

  13. Enhanced Oil Recovery: Aqueous Flow Tracer Measurement

    SciTech Connect (OSTI)

    Joseph Rovani; John Schabron

    2009-02-01T23:59:59.000Z

    A low detection limit analytical method was developed to measure a suite of benzoic acid and fluorinated benzoic acid compounds intended for use as tracers for enhanced oil recovery operations. Although the new high performance liquid chromatography separation successfully measured the tracers in an aqueous matrix at low part per billion levels, the low detection limits could not be achieved in oil field water due to interference problems with the hydrocarbon-saturated water using the system's UV detector. Commercial instrument vendors were contacted in an effort to determine if mass spectrometry could be used as an alternate detection technique. The results of their work demonstrate that low part per billion analysis of the tracer compounds in oil field water could be achieved using ultra performance liquid chromatography mass spectrometry.

  14. Expectations for Oil Shale Production (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01T23:59:59.000Z

    Oil shales are fine-grained sedimentary rocks that contain relatively large amounts of kerogen, which can be converted into liquid and gaseous hydrocarbons (petroleum liquids, natural gas liquids, and methane) by heating the rock, usually in the absence of oxygen, to 650 to 700 degrees Fahrenheit (in situ retorting) or 900 to 950 degrees Fahrenheit (surface retorting). (Oil shale is, strictly speaking, a misnomer in that the rock is not necessarily a shale and contains no crude oil.) The richest U.S. oil shale deposits are located in Northwest Colorado, Northeast Utah, and Southwest Wyoming. Currently, those deposits are the focus of petroleum industry research and potential future production. Among the three states, the richest oil shale deposits are on federal lands in northwest Colorado.

  15. Exploring for hydrocarbons in geothermally and hydrothermally complex areas -- a southern Nevada example

    SciTech Connect (OSTI)

    Harris, A.G.; Repetski, J.E. [Geological Survey, Reston, VA (United States); Grow, J.A. [Geological Survey, Denver, CO (United States)

    1995-06-01T23:59:59.000Z

    Time-based isograd maps using conodont color alteration indices (CAI) have been compiled and interpreted for a large area in southern Nevada that includes Yucca Mountain, the Nevada Test Site, and the Nellis Air Force Bombing and Gunnery Range. These maps were produced to evaluate the controversy about possible important mineral and (or) energy resources near Yucca Mountain, the potential burial site for high-level nuclear waste. The hydrocarbon potential of the Yucca Mountain area has been likened to that of the Railroad and Pine Valley areas, 200 km to the northeast where 35 million barrels of oil have been produced from Paleozoic and lower Tertiary strata. In 1991, two companies with no previous drilling experience in Nevada drilled three oil exploration wells within 20 km of Yucca Mountain and within or close to the Timber Mountain caldera system. No shows of oil or gas were found in these wells. The deepest well was drilled to 5,000 feet and penetrated 2,200 feet of upper Tertiary valley-fill deposits and volcanic rocks overlying an overturned sequence of Upper Cambrian and Lower Ordovician rocks having conodonts with CAI values of 5. Our new conodont sampling, however, has targeted some thermally favorable areas for hydrocarbons east of Yucca mountain, but their maturation history suggests that the potential for oil is substantially lower than in the Railroad and Pine Valley areas. Cambrian through Triassic rocks in the vicinity of Yucca Mountain have experienced temperatures too high for oil to be preserved, except for a narrow zone (20 x 100 km) northeast of Yucca Mountain, where Mississippian through Triassic rocks are just within the upper limit of the oil generating window. Most of this zone, however, lies on Federal lands that are, for now, inaccessible for a variety of security and environmental reasons.

  16. Comparisons of hydrocarbon and nitrogen distributions in geologically diverse tar sand bitumen

    SciTech Connect (OSTI)

    Holmes, S.A.

    1988-06-01T23:59:59.000Z

    The characteristics of bitumens from different tar sand deposits are generally significantly different and affect the utilization of the resource. The chemical and physical properties of bitumen are a result of maturation reactions on the varied organic sediments. For example, saturated hydrocarbon distributions have been related to the geochemical history of organic matter. Very paraffinic or sometimes paraffinic-naphthenic distributions in organic matter are derived from a nonmarine depositional environment. More aromatic and paraffinic-naphthenic hydrocarbon distributions are derived from organic matter deposited in a marine environment. The characteristics of the bitumen also influence the potential for recovery and subsequent processing of the material. For example, saturated hydrocarbons contribute to the high pour points of recovered oils. The origin and composition of an oil influence its viscosity, API gravity, and coke formation during processing, particularly under low-temperature oxidation conditions. The objective of this work is to determine the chemical and physical properties of several samples of bitumen from geologically diverse tar sand deposits. The compound-type distributions and LTD properties of these bitumens are discussed relative to the depositional environment and processing potential of the organic matter.

  17. Water solubility data for 151 hydrocarbons

    SciTech Connect (OSTI)

    Yaws, C.L.; Pan, Xiang; Lin, Xiaoyin (Lamar Univ., Beaumont, TX (United States))

    1993-02-01T23:59:59.000Z

    The solubility of a hydrocarbon in water is important from both an environmental and a safety perspective. This information is required by engineers who design or operate stripping processes that remove hydrocarbons from air or water, or who must determine the amount of a hydrocarbon that has dissolved in water following a chemical spill. In particular, the water solubilities of paraffins are increasingly important because of more-stringent government regulations. Paraffins, along with naphthenes and aromatics, are the three major components of unrefined fuels. The water solubilities of 151 paraffins are listed in tables. The data are valid between 25 and 121 C, typical temperature in air- and steam-stripping operations. Also included is a correlation equation that allows users to estimate hydrocarbon solubilities above the given temperature range.

  18. Toxicity Analysis of Polycyclic Aromatic Hydrocarbon Mixtures

    E-Print Network [OSTI]

    Naspinski, Christine S.

    2010-01-16T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are widely distributed in the environment and are generated by many sources. Though the potential of PAH-rich mixtures to cause health effects has been known for almost a century, there are still unanswered...

  19. Solubilization of petroleum hydrocarbons using biosurfactants 

    E-Print Network [OSTI]

    Kanga, Shahrukh

    1995-01-01T23:59:59.000Z

    Low solubility of petroleum hydrocarbons in water is the major factor limiting the degradation rates of these compounds (Zhang and Miller, 1994). The fraction that is more soluble in the aqueous phase is degraded at higher rates, while less soluble...

  20. Running Out of and Into Oil: Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, D.L.

    2003-11-14T23:59:59.000Z

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value. Probability distributions are produced for the year in which conventional oil production peaks for the world as a whole and the year of peak production from regions outside the Middle East. Recent estimates of world oil resources by the United States Geological Survey (USGS), the International Institute of Applied Systems Analysis (IIASA), the World Energy Council (WEC) and Dr. C. Campbell provide alternative views of the extent of ultimate world oil resources. A model of oil resource depletion and expansion for twelve world regions is combined with a market equilibrium model of conventional and unconventional oil supply and demand to create a World Energy Scenarios Model (WESM). The model does not make use of Hubbert curves but instead relies on target reserve-to-production ratios to determine when regional output will begin to decline. The authors believe that their analysis has a bias toward optimism about oil resource availability because it does not attempt to incorporate political or environmental constraints on production, nor does it explicitly include geologic constraints on production rates. Global energy scenarios created by IIASA and WEC provide the context for the risk analysis. Key variables such as the quantity of undiscovered oil and rates of technological progress are treated as probability distributions, rather than constants. Analyses based on the USGS and IIASA resource assessments indicate that conventional oil production outside the Middle East is likely to peak sometime between 2010 and 2030. The most important determinants of the date are the quantity of undiscovered oil, the rate at which unconventional oil production can be expanded, and the rate of growth of reserves and enhanced recovery. Analysis based on data produced by Campbell indicates that the peak of non-Middle East production will occur before 2010. For total world conventional oil production, the results indicate a peak somewhere between 2020 and 2050. Key determinants of the peak in world oil production are the rate at which the Middle East region expands its output and the minimum reserves-to-production ratios producers will tolerate. Once world conventional oil production peaks, first oil sands and heavy oil from Canada, Venezuela and Russia, and later some other source such as shale oil from the United States must expand if total world oil consumption is to continue to increase. Alternative sources of liquid hydrocarbon fuels, such as coal or natural gas are also possible resources but not considered in this analysis nor is the possibility of transition to a hydrogen economy. These limitations were adopted to simplify the transition analysis. Inspection of the paths of conventional oil production indicates that even if world oil production does not peak before 2020, output of conventional oil is likely to increase at a substantially slower rate after that date. The implication is that there will have to be increased production of unconventional oil after that date if world petroleum consumption is to grow.

  1. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    DOE Patents [OSTI]

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27T23:59:59.000Z

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  2. Pre-Mississippian hydrocarbon potential of Illinois basin

    SciTech Connect (OSTI)

    Davis, H.G.

    1987-05-01T23:59:59.000Z

    The Illinois basin is primarily a Paleozoic epeirogenic basin located in the east-central US. Taken at its broadest possible definition, this basin contains a maximum of 20,000 ft of sedimentary rocks. These represent every Phanerozoic system except the Triassic and Jurassic. Seven important tectonic episodes are recognized. These begin with the establishment of Eocambrian basement rift faults, followed by six rejuvenation events of varying magnitude. More than 3.5 billion bbl of oil have been produced from the Illinois basin, mainly from Pennsylvanian and Mississippian rocks. These rocks represent only 20% of the total basin sedimentary volume. Source rock maturation studies suggest that none of this oil is indigenous to the Pennsylvanian or Mississippian, but all has migrated upward from at least three pre-Mississippian sources. If basin sedimentary volume is taken to be roughly proportional to hydrocarbon reserves, there may be as much as 12 billion BOE remaining to be found in the largely untested pre-Mississippian of the Illinois basin. A thermal history model and Lopatin analysis suggest that oil generation began in Ordovician time and continued through the Jurassic in the deepest part of the basin. At the present stage of exploration, the Hunton Megagroup (Silurian-Devonian) is recommended as the primary pre-Mississippian drilling target. However, understanding the interplay of the pre-Middle Devonian unconformity with contemporaneous paleotopographic-paleobathymetric expression of prospective features is critical to successful Hunton porosity prediction. This interplay is demonstrated at Centralia and Sandoval fields, Clinton and Marion counties, Illinois.

  3. Development of Extraction Techniques for the Detection of Signature Lipids from Oil

    SciTech Connect (OSTI)

    Borglin, Sharon; Geller, Jil; Chakraborty, Romy; Hazen, Terry; Mason, Olivia

    2010-05-17T23:59:59.000Z

    Pure cultures, including Desulfovibrio vulgaris and Methanococcus maripaludus, were combined with model oil samples and oil/diesel mixtures to optimize extraction techniques of signature lipids from oil in support of investigation of microbial communities in oil deposit samples targets for microbial enhanced hydrocarbon recovery. Several techniques were evaluated, including standard phospholipid extraction, ether linked lipid for Archaeal bacterial detection, and high pressure extractiontechniques. Recovery of lipids ranged from 50-80percent as compared to extraction of the pure culture. Extraction efficiency was evaluated by the use of internal standards. Field samples will also be tested for recovery of signature lipids with optimized extraction techniques.

  4. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01T23:59:59.000Z

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  5. Isolation, Determination of Absolute Stereochemistry, and Asymmetric Synthesis of Insect Methyl-Branched Hydrocarbons

    E-Print Network [OSTI]

    Bello, Jan Edgar

    2014-01-01T23:59:59.000Z

    d’Ettore, P. In Insect Hydrocarbons: Biology, Biochemistry,A.G. In Insect Hydrocarbons: Biology, Biochemistry, ChemicalMillar, J.G. In Insect Hydrocarbons: Biology, Biochemistry,

  6. Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    CONDUCTIVITY IMAGING OF HYDROCARBONS USING THE BLUE GENE/Lidentification of hydrocarbon filled layers in deepwater,”Remote sensing of hydrocarbon layers by seabed logging (

  7. Innocuous oil as an additive for reductive reactions involving zero valence iron

    SciTech Connect (OSTI)

    Cary, J.W.; Cantrell, K.J.

    1994-11-01T23:59:59.000Z

    Reductive reactions involving zero valence iron appear to hold promise for in situ remediation of sites containing chlorinated hydrocarbon solvents and certain reducible metals and radionuclides. Treatment involves the injection of metallic iron and the creation of low levels of dissolved oxygen in the aqueous phase through oxidation of the metallic iron. The use of a biodegradable immiscible and innocuous organic liquid such as vegetable oil as an additive offers several intriguing possibilities. The oil phase creates a large oil-water interface that is immobile with respect to flow in the aqueous phase. This phase will act as a trap for chlorinated hydrocarbons and could potentially increase the reaction efficiency of reductive dehalogenation of chlorinated hydrocarbons by the metallic iron. When iron particles are suspended in the oil before injection they are preferentially held in the oil phase and tend to accumulate at the oil-water interface. Thus oil injection can serve as a mechanism for creating a stable porous curtain of metallic iron in the vadose to maintain a low oxygen environment which will minimize the consumption of the iron by molecular oxygen.

  8. Use of thermal desorption/gas chromatography as a performance-based screening method for petroleum hydrocarbons

    SciTech Connect (OSTI)

    Slavin, P.J. [GRAM, Inc., Albuquerque, NM (United States)]|[Sandia National Labs., Albuquerque, NM (United States); Crandall, K. [Brown and Root Environmental, Albuquerque, NM (United States); Dawson, L.; Kottenstette, R. [Sandia National Labs., Albuquerque, NM (United States); Wade, M. [INTERA, Inc., Albuquerque, NM (United States)]|[Sandia National Labs., Albuquerque, NM (United States)

    1996-08-01T23:59:59.000Z

    Thermal desorption/gas chromatography (TD/GC) was used to screen soil samples on site for total petroleum hydrocarbon (TPH) content during a RCRA Facility Investigation (RFI). It proved to be a rapid, cost- effective tool for detecting non-aromatic mineral oil in soil. The on- site TD/GC results correlated well with those generated at an off- site laboratory for samples analyzed in accordance with EPA Method 418.1.

  9. Northeast Home Heating Oil Reserve System Heating Oil, PIA Office...

    Energy Savers [EERE]

    Northeast Home Heating Oil Reserve System Heating Oil, PIA Office of Fossil Energy Headquaters Northeast Home Heating Oil Reserve System Heating Oil, PIA Office of Fossil Energy...

  10. Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

    2012-08-19T23:59:59.000Z

    The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

  11. The evolution and hydrocarbon habitat of the Papuan fold belt, PNG

    SciTech Connect (OSTI)

    Dalton, D.G.; Smith, R.I.; Cawley, S.J. (BP Australia Ltd., Melbourne, Victoria (Australia))

    1990-05-01T23:59:59.000Z

    After over 70 years of hydrocarbon exploration in the Papuan fold belt of PNG (Papua New Guinea) there have been a number of hydrocarbon discoveries over recent years that have confirmed its potential as a significant producing province. The Papuan basin developed during the early Mesozoic as part of the northeast corner of the Australian passive margin. The basin's tertiary evolution and the development of the Papuan fold belt within the Papuan basin has evolved in response to oblique convergence between the northerly moving Australian plate and westerly moving Pacific plate. Restacking of the Mesozoic passive margin sequence within the Papuan Basin was initiated in the early miocene by southward abduction of the Solomon Sea plate and the subsequent collision, in the late Miocene, of the Melanesian Island arc along the northeastern margin of PNG. This later collision provided the driving mechanism for the development of the papuan thrust belt. To date, all the significant hydrocarbon discoveries made within the Papuan fold belt have been located within the frontal zone of the fold belt, which is characterized by relatively simple ramp anticlines and thick-skinned inversion structures. The primary proven reservoir fairway is the Jurassic Toro formation, which is a sequence of stacked submarine bars prograding out across a shallow-marine low-gradient shelf. Geochemical analysis of produced hydrocarbons and samples collected from the many surface seeps found in the fold belt indicate two main families of oil. A model explains the distribution of hydrocarbons discovered to date, which involves Jurassic and Cretaceous source intervals and a complex history of secondary migration and entrapment. The unique technical problems associated with exploration of the Papuan fold belt leave many elements of the proven play systems uncertain, but in so doing, they present many challenges and opportunities for the future.

  12. Oil migration pattern in the Sirte Basin

    SciTech Connect (OSTI)

    Roohi, M.; Aburawi, R.M. [Waha Oil Co., Tripoli (Libyan Arab Jamahiriya)

    1995-08-01T23:59:59.000Z

    Sirte Basin is an asymmetrical cratonic basin, situated in the north-central part of Libya. It covers an area of over 350,000km{sup 2} and is one of the most prolific oil-producing basins in the world. Sirte Basin is divided into large NW-SE trending sub-parallel platforms and troughs bounded by deep seated syndepositional normal faults. A very unique combination of thick sediments with rich source rocks in the troughs vs. thinner sediments with prolific reservoir rocks on the platforms accounts for the productivity of the basin. Analysis of oil migration pattern in the Sirte Basin will certainly help to discover the remaining reserves, and this can only be achieved if the important parameter of structural configuration of the basin at the time of oil migration is known. The present paper is an attempt to analyse the time of oil migration, to define the structural picture of the 4 Basin during the time of migration and to delineate the most probable connecting routes between the hydrocarbon kitchens and the oil fields.

  13. The Stimulation of Hydrocarbon Reservoirs with Subsurface Nuclear Explosions

    SciTech Connect (OSTI)

    LORENZ,JOHN C.

    2000-12-08T23:59:59.000Z

    Between 1965 and 1979 there were five documented and one or more inferred attempts to stimulate the production from hydrocarbon reservoirs by detonating nuclear devices in reservoir strata. Of the five documented tests, three were carried out by the US in low-permeability, natural-gas bearing, sandstone-shale formations, and two were done in the USSR within oil-bearing carbonates. The objectives of the US stimulation efforts were to increase porosity and permeability in a reservoir around a specific well by creating a chimney of rock rubble with fractures extending beyond it, and to connect superimposed reservoir layers. In the USSR, the intent was to extensively fracture an existing reservoir in the more general vicinity of producing wells, again increasing overall permeability and porosity. In both countries, the ultimate goals were to increase production rates and ultimate recovery from the reservoirs. Subsurface explosive devices ranging from 2.3 to about 100 kilotons were used at depths ranging from 1208 m (3963 ft) to 2568 m (8427 ft). Post-shot problems were encountered, including smaller-than-calculated fracture zones, formation damage, radioactivity of the product, and dilution of the BTU value of tie natural gas with inflammable gases created by the explosion. Reports also suggest that production-enhancement factors from these tests fell short of expectations. Ultimately, the enhanced-production benefits of the tests were insufficient to support continuation of the pro-grams within increasingly adversarial political, economic, and social climates, and attempts to stimulate hydrocarbon reservoirs with nuclear devices have been terminated in both countries.

  14. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (‘syngas’) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  15. Methods for dispersing hydrocarbons using autoclaved bacteria

    DOE Patents [OSTI]

    Tyndall, R.L.

    1996-11-26T23:59:59.000Z

    A method of dispersing a hydrocarbon includes the following steps: providing a bacterium selected from the following group: ATCC 85527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures; autoclaving the bacterium to derive a dispersant solution; and contacting the dispersant solution with a hydrocarbon to disperse the hydrocarbon. Moreover, a method for preparing a dispersant solution includes the following steps: providing a bacterium selected from the following group: ATCC 75527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures; and autoclaving the bacterium to derive a dispersant solution.

  16. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two;2 Abstract The size distribution of polycyclic aromatic hydrocarbons (PAHs) and PAH derivatives of compounds. Keywords: Polycyclic aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated

  17. Destructive-condensation transformations of resinous crude oil by the action of light

    SciTech Connect (OSTI)

    Melikadze, L.D.; Kuprashvili, B.G.; Barabadze, S.S.; Bakhturidze, G.S.; Shatakishvili, T.N.

    1987-08-01T23:59:59.000Z

    The effect of radiation from a mercury-quartz lamp PRK-2 upon native resin-asphaltene substances of Norian, Samgore and Supsin crude oils is examined. Irradiated resin substances from crude oil undergo marked changes - photochemical breakdown to form gaseous hydrocarbons (methane, ethane and propane) and photochemical condensation. During the condensation step molar mass increases and three-dimensional structures are formed, these have a high softening point (above 400/sup 0/C) and do not dissolve in organic solvents.

  18. Oil recovery by carbon dioxide injection into consolidated and unconsolidated sandstone 

    E-Print Network [OSTI]

    Lin, Fwu-Jin Frank

    1975-01-01T23:59:59.000Z

    a displacement effic1ency approaching 100 percent. (3) Carbon Dioxide neither achieves direct miscible displacement at practical reservoir pressures, like LPG, nor depend upon the presence of light hydrocarbons in the reservoir oil. A f1eld... strong function of pore size dis- tribution, probably contributed a great effect on the oil displacement effic1enc1es between the consolidated sandstone core and the unconsolidated sand pack. 4. No significant over-riding effect of carbon dioxide...

  19. Bioremediation of Petroleum Hydrocarbon Contaminated Sites

    SciTech Connect (OSTI)

    Paul Fallgren

    2009-03-30T23:59:59.000Z

    Bioremediation has been widely applied in the restoration of petroleum hydrocarbon-contaminated. Parameters that may affect the rate and efficiency of biodegradation include temperature, moisture, salinity, nutrient availability, microbial species, and type and concentration of contaminants. Other factors can also affect the success of the bioremediation treatment of contaminants, such as climatic conditions, soil type, soil permeability, contaminant distribution and concentration, and drainage. Western Research Institute in conjunction with TechLink Environmental, Inc. and the U.S. Department of Energy conducted laboratory studies to evaluate major parameters that contribute to the bioremediation of petroleum-contaminated drill cuttings using land farming and to develop a biotreatment cell to expedite biodegradation of hydrocarbons. Physical characteristics such as soil texture, hydraulic conductivity, and water retention were determined for the petroleum hydrocarbon contaminated soil. Soil texture was determined to be loamy sand to sand, and high hydraulic conductivity and low water retention was observed. Temperature appeared to have the greatest influence on biodegradation rates where high temperatures (>50 C) favored biodegradation. High nitrogen content in the form of ammonium enhanced biodegradation as well did the presence of water near field water holding capacity. Urea was not a good source of nitrogen and has detrimental effects for bioremediation for this site soil. Artificial sea water had little effect on biodegradation rates, but biodegradation rates decreased after increasing the concentrations of salts. Biotreatment cell (biocell) tests demonstrated hydrocarbon biodegradation can be enhanced substantially when utilizing a leachate recirculation design where a 72% reduction of hydrocarbon concentration was observed with a 72-h period at a treatment temperature of 50 C. Overall, this study demonstrates the investigation of the effects of environmental parameters on bioremediation is important in designing a bioremediation system to reduce petroleum hydrocarbon concentrations in impacted soils.

  20. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01T23:59:59.000Z

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  1. Paleo-highs may be key to deeper oil production

    SciTech Connect (OSTI)

    Davis, H.G.

    1989-03-01T23:59:59.000Z

    The Illinois basin is primarily a Paleozoic epeirogenic and epicratonic basin located in the east-central United States. Hydrocarbons have been commercially produced from this basin for more than a century, having reached cumulative production of more than 3.2 billion bbl of oil, with relatively little gas. Pursuing this production, more than 72 million feet of exploratory footage, a considerable sum, have been drilled. Taken at face value, these facts have created a commonly held impression throughout the oil and gas industry that the Illinois basin is in a very mature stage of exploration, In other words, the prejudice is that not many reserves remain to be found.

  2. Separation of the unsaponifiable matter from cottonseed oil by adsorption

    E-Print Network [OSTI]

    Zeitoun, Mohamed Ali

    1955-01-01T23:59:59.000Z

    quantity of oil, melted at 13$ C. This compares with P -sltosterol of melting point 136-137o C. The adsorbents, activated alumina, activated carbon and bleaching clay were compared and found much less effective than silica CONTENTS INTRODUCTION... lipids cn alumina columns, and J'ound the order of increasing adsorbability to be: hydrocarbons, sterol es tez s, triglycerides, free s terols, fatty acids, and phosphatices. Winterstein and Stein (40) have mentioned tne successful application...

  3. Catalysts for synthesizing various short chain hydrocarbons

    DOE Patents [OSTI]

    Colmenares, Carlos (Alamo, CA)

    1991-01-01T23:59:59.000Z

    Method and apparatus (10), including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO.sub.2 aerogels doped with photochemically active uranyl ions (18) are fluidized in a fluidized-bed reactor (12) having a transparent window (16), by hydrogen and CO, C.sub.2 H.sub.4 or C.sub.2 H.sub.6 gas mixtures (20), and exposed to radiation (34) from a light source (32) external to the reactor (12), to produce the short chain hydrocarbons (36).

  4. Calculating the hyperWiener index of benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Calculating the hyper­Wiener index of benzenoid hydrocarbons Petra Zigert1 , Sandi Klavzar1) is not easy, especially in the case of large polycyclic molecules, such as benzenoid hydrocarbons. Some time

  5. Calculating the hyper--Wiener index of benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Calculating the hyper--Wiener index of benzenoid hydrocarbons Petra Ÿ Zigert 1 , Sandi KlavŸ zar 1. (1) is not easy, especially in the case of large polycyclic molecules, such as benzenoid hydrocarbons

  6. Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection

    E-Print Network [OSTI]

    Cai, Rui

    2012-02-14T23:59:59.000Z

    result in successful hydrocarbon finds because abnormal seismic amplitude variations can sometimes be caused by other factors, such as alternative lithology and residual hydrocarbons in certain depositional environments. Furthermore, not all gas fields...

  7. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. acep03rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO...

  8. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (OFCVT). deer07rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO...

  9. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Broader source: Energy.gov (indexed) [DOE]

    rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in...

  10. Effect of surface derived hydrocarbon impurities on Ar plasma properties

    SciTech Connect (OSTI)

    Fox-Lyon, Nick; Oehrlein, Gottlieb S., E-mail: Oehrlein@umd.edu [Department of Materials Science and Engineering and the Institute for Research and Applied Physics, University of Maryland, College Park, MD 20742 (United States); Godyak, Valery [Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, MI 48109-2122 (United States)

    2014-05-15T23:59:59.000Z

    The authors report on Langmuir probe measurements that show that hydrocarbon surfaces in contact with Ar plasma cause changes of electron energy distribution functions due to the flux of hydrogen and carbon atoms released by the surfaces. The authors compare the impact on plasma properties of hydrocarbon species gasified from an etching hydrocarbon surface with injection of gaseous hydrocarbons into Ar plasma. They find that both kinds of hydrocarbon injections decrease electron density and slightly increase electron temperatures of low pressure Ar plasma. For low percentages of impurities (?1% impurity in Ar plasma explored here), surface-derived hydrocarbon species and gas phase injected hydrocarbon molecules cause similar changes of plasma properties for the same number of hydrocarbon molecules injected into Ar with a decrease in electron density of ?4%.

  11. Bitumen and heavy-oil resources of the United States

    SciTech Connect (OSTI)

    Crysdale, B.L.; Schenk, C.J.

    1987-05-01T23:59:59.000Z

    Bitumen and heavy-oil deposits represent a significant hydrocarbon resource in the US. Bitumen deposits (10/sup 0/ API) are located in sandstone reservoirs at or near the surface along the margins of sedimentary basins. Heavy oils (10/sup 0/-20/sup 0/ API) are found predominantly in geologically young (Tertiary age and younger) shallow sandstone reservoirs and along the margins of sedimentary basins. Bitumen and heavy oil have high viscosities (10,000 cp for bitumen, 100-10,000 cp for heavy oil) and cannot be recovered by conventional recovery methods. Bitumen deposits have been evaluated in 17 states. The total bitumen resource for the conterminous US is estimated to be 57 billion bbl. Utah contains the largest resource, estimated to be 29 billion bbl, followed by California with 9 billion bbl, Alabama with 6 billion, Texas with 5 billion, and Kentucky with 3 billion. Heavy-oil deposits have been evaluated in 16 states, but most heavy oil is in California, Texas, and Arkansas. Total heavy oil in place for the conterminous US is estimated to be approximately 45 billion bbl; greater than 80% of this amount is in California. The giant Kuparuk deposit on the North Slope of Alaska contains a heavy oil-bitumen resource estimated as high as 40 billion bbl.

  12. Method and apparatus for low temperature destruction of halogenated hydrocarbons

    DOE Patents [OSTI]

    Reagen, William Kevin (Stillwater, MN); Janikowski, Stuart Kevin (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    A method and apparatus for decomposing halogenated hydrocarbons are provided. The halogenated hydrocarbon is mixed with solvating agents and maintained in a predetermined atmosphere and at a predetermined temperature. The mixture is contacted with recyclable reactive material for chemically reacting with the recyclable material to create dehalogenated hydrocarbons and halogenated inorganic compounds. A feature of the invention is that the process enables low temperature destruction of halogenated hydrocarbons.

  13. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    over time even if the oil market were perfectly competitive.a big role in world oil markets, that era is long past.and re?ning oil and delivering it to the market. We could

  14. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    appeared in the world oil market in the last fifteen years.have on the world oil markets and international relationsthe stability of the oil markets. 11 This literature,

  15. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    China made an Iranian oil investment valued at $70 billion.across Iran, China’s oil investment may exceed $100 billionthese involving investment in oil and gas, really undermine

  16. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    and Income on Energy and Oil Demand,” Energy Journal 23(1),the faster its growth in oil demand over the last half ofthe income elasticity of oil demand to fall signi?cantly.

  17. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    current pace of growth in oil demand as staying consistentthis point, China’s demand Oil Demand vs. Domestic Supply inand predictions of oil supply and demand affected foreign

  18. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    nations began to seek out oil reserves around the world. 3on the limited global oil reserves and spiking prices. Manyto the largest proven oil reserves, making up 61 percent of

  19. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crudein predicting quarterly real oil price change. variable real

  20. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    per day. Monthly crude oil production Iran Iraq KuwaitEIA Table 1.2, “OPEC Crude Oil Production (Excluding Lease2008, from EIA, “Crude Oil Production. ” Figure 16. U.S.

  1. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    unfettered access to oil resources including the possibleChina’s search for oil resources around the world. However,a survey of China’s oil resources, while others focus

  2. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crude023 Understanding Crude Oil Prices James D. Hamilton June

  3. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    Natural Gas, Heating Oil and Gasoline,” NBER Working Paper.2006. “China’s Growing Demand for Oil and Its Impact on U.S.and Income on Energy and Oil Demand,” Energy Journal 23(1),

  4. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    Michael T. Klare, Blood and Oil: The Dangers of America’sDowns and Jeffrey A. Bader, “Oil-Hungry China Belongs at BigChina, Africa, and Oil,” (Council on Foreign Relations,

  5. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    in U.S. real GDP and oil consumption, 1949-2006. slope =Historical Chinese oil consumption and projection of trend.1991-2006: Chinese oil consumption in millions of barrels

  6. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    Figure 5. Monthly oil production for Iran, Iraq, and Kuwait,day. Monthly crude oil production Iran Iraq Kuwait Figure 6.and the peak in U.S. oil production account for the broad

  7. Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process

    SciTech Connect (OSTI)

    Oguejiofor, G.C. [Nnamdi Azikiwe University, Awka (Nigeria). Dept. of Chemical Engineering

    2008-07-01T23:59:59.000Z

    Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phase distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.

  8. Conversion of hydrocarbons for fuel-cell applications. Part I. Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids. Part II. Steam reforming of n-hexane on pellet and monolithic catalyst beds. Final report

    SciTech Connect (OSTI)

    Flytzani-Stephanopoulos, M.; Voecks, G.E.

    1981-10-01T23:59:59.000Z

    Experimental autothermal reforming (ATR) results obtained in the previous phase of this work with sulfur-free pure hydrocarbon liquids are summarized. Catalyst types and configuration used were the same as in earlier tests with No. 2 fuel oil to facilitate comparisons. Fuel oil has been found to form carbon in ATR at conditions much milder than those predicted by equilibrium. Reactive differences between paraffins and aromatics in ATR, and thus the formation of different carbon precursors, have been shown to be responsible for the observed carbon formation characteristics (fuel-specific). From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation in ATR. Effects of olefin (propylene) addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics (n-tetradecane and benzene) synergistic effects on conversion characteristics were identified. Comparisons of the No. 2 fuel oil data with the experimental results from this work with pure (and mixed) sulfur-free hydrocarbons indicate that the sulfur content of the fuel may be the limiting factor for efficient ATR operation. Steam reforming of hydrocarbons in conventional reformers is heat transfer limited. Steam reforming tasks performed have included performance comparisons between conventional pellet beds and honeycomb monolith catalysts. Metal-supported monoliths offer higher structural stability than ceramic supports, and have a higher thermal conductivity. Data from two metal monoliths of different catalyst (nickel) loading were compared to pellets under the same operating conditions.

  9. Hydrocarbon Formation in Metallic Iron/Water Systems

    E-Print Network [OSTI]

    Deng, Baolin

    Hydrocarbon Formation in Metallic Iron/Water Systems B A O L I N D E N G , , § T I M O T H Y J . C-labeled hydrocarbons are produced. In the absence of chlorinated ethenes, however, lower con- centrations of many of the same hydrocarbons (methane and C2-C6 alkanes and alkenes) are also produced. Hardy and Gillham (1996

  10. RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE developed in our laboratory for the reactions of C3-C4 unsaturated hydrocarbons. The main reaction pathways2007 #12;3 INTRODUCTION Soots and polyaromatic hydrocarbons (PAH), which are present in the exhaust gas

  11. The Production of Non-Methane Hydrocarbons by Marine Plankton

    E-Print Network [OSTI]

    The Production of Non-Methane Hydrocarbons by Marine Plankton Stephanie Lyn Shaw Center for Global://web.mit.edu/cgcs/ Printed on recycled paper #12;1 The Production of Non-Methane Hydrocarbons by Marine Plankton by Stephanie of Non-Methane Hydrocarbons by Marine Plankton by Stephanie Lyn Shaw Submitted to the Department of Earth

  12. Binary coding of Kekule structures of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Binary coding of Kekul´e structures of catacondensed benzenoid hydrocarbons Sandi Klavzar of benzenoids Key words: benzenoid hydrocarbons, benzenoid graph, resonance graph, Kekul´e structure, algorithm easily be recovered from its binary code. Key words: benzenoid hydrocarbons, benzenoid graph, resonance

  13. Atomic displacements due to spinspin repulsion in conjugated alternant hydrocarbons

    E-Print Network [OSTI]

    Benzi, Michele

    Atomic displacements due to spin­spin repulsion in conjugated alternant hydrocarbons Ernesto-induced atomic displacements in conjugated alt- ernant hydrocarbons. It appears to be responsible alternant hydrocarbons (CAHs) have played a fun- damental role in the development of theoretical chemistry

  14. Wiener Numbers of Pericondensed Benzenoid Hydrocarbons Sandi Klav zar

    E-Print Network [OSTI]

    Klavzar, Sandi

    Wiener Numbers of Pericondensed Benzenoid Hydrocarbons Sandi Klav#20;zar Department of Mathematics expressions for W for several homologous series of pericondensed benzenoid hydrocarbons. An elementary proof polycyclic systems studied were catacondensed benzenoid hydrocarbons. 11{14 Few years ago the situation

  15. Original article Hydrocarbons and monoesters of propolis waxes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Hydrocarbons and monoesters of propolis waxes from Brazil Giuseppina Negri* Maria yielded mono- esters as main constituents, followed by hydrocarbons. The methyl and acetyl esters of the car- boxylic acids and alcohols, respectively, derived from the monoesters, and the hydrocarbons were

  16. Aryl hydrocarbon receptor-dependent liver development and hepatotoxicity are

    E-Print Network [OSTI]

    Bradfield, Christopher A.

    Aryl hydrocarbon receptor-dependent liver development and hepatotoxicity are mediated by different for review June 7, 2005) The aryl hydrocarbon receptor (AHR) plays a role in three areas of biology recombinase ductus venosus endothelial cell hepatocyte dioxin The aryl hydrocarbon receptor (AHR) is a basic

  17. Binary coding of Kekule structures of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Binary coding of Kekulâ??e structures of catacondensed benzenoid hydrocarbons Sandi KlavŸzar, aâ??e structures of benzenoids Key words: benzenoid hydrocarbons, benzenoid graph, resonance graph, Kekul easily be recovered from its binary code. Key words: benzenoid hydrocarbons, benzenoid graph, resonance

  18. Method for removing chlorine compounds from hydrocarbon mixtures

    DOE Patents [OSTI]

    Janoski, E.J.; Hollstein, E.J.

    1984-09-29T23:59:59.000Z

    A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

  19. Production of hydrocarbons from hydrates. [DOE patent application

    DOE Patents [OSTI]

    McGuire, P.L.

    1981-09-08T23:59:59.000Z

    An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

  20. Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard reference material 1649a (urban dust) and

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard nitrated polycylic aromatic hydrocarbons (NPAHs) and 9 oxygenated polycylic aromatic hydrocarbons (OPAHs aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic

  1. Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

    1981-02-19T23:59:59.000Z

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  2. Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

    1983-01-01T23:59:59.000Z

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  3. Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

    1984-01-01T23:59:59.000Z

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  4. Review Paper/ Crude Oil at the Bemidji Site: 25 Years of

    E-Print Network [OSTI]

    and water flow, vapor diffusion, and the progression of biodegradation. Pore-scale capillary pressure large residual oil saturations. Hydrocarbon attenuation and plume extent was a function of groundwater of ground- water contamination by benzene, toluene, ethylbenzene, and xylenes (BTEX) (Council

  5. Transport and Phase Equilibria Properties for Steam Flooding of Heavy Oils

    SciTech Connect (OSTI)

    Gabitto, Jorge; Barufet, Maria

    2002-11-20T23:59:59.000Z

    The objectives of this research included experimental determination and rigorous modeling and computation of phase equilibrium diagrams, volumetric, and transport properties of hydrocarbon/CO2/water mixtures at pressures and temperatures typical of steam injection processes for thermal recovery of heavy oils.

  6. Transport and Phase Equilibria Properties for Steam Flooding of Heavy Oils

    SciTech Connect (OSTI)

    Gabitto, Jorge; Barrufet, Maria

    2001-12-18T23:59:59.000Z

    The objectives of this research included experimental determination and rigorous modeling and computation of phase equilibria, volumetric, and transport properties of hydrocarbon/CO2/water mixtures at pressures and temperatures typical of steam injection processes for thermal recovery of heavy oils.

  7. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    China’s domestic oil supply will peak, and demand Robertpeak will come around 2020, 24 and that by this point, China’s demand Oil

  8. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    historical data for claiming to be able to predict oil pricehistorical data. The second is to look at the predictions of economic theory as to how oil prices

  9. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    2007”. comparison, Mexico used 6.6— Chinese oil consumption17. Oil production from the North Sea, Mexico’s Cantarell,

  10. Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs) in snow and ice sampled at Colle designed, built and tested. Melt water from inner part of ice core section was pumped to an ICP-SFMS and ICP-OES. Melt water from outer section was on-line extracted by solid-phase cartridges for semi

  11. Determination of hydrocarbons in sea water via UV-induced total fluorescence spectroscopy

    SciTech Connect (OSTI)

    Muroski, A.R.; Booksh, K.S.; Myrick, M.L. [Univ. of South Carolina, Columbia, SC (United States)

    1995-12-31T23:59:59.000Z

    The increasingly ubiquitous presence of anthropogenic hydrocarbons in oceans, lakes, and rivers necessitates the development of practical means of determining such pollutants in natural waters. Monitoring the subsurface progression and eventual fate of hydrocarbons from a particular source in the marine environment requires a technique amenable to rapid data acquisition and evaluation. Total UV fluorescence spectroscopy meets this requirement, while providing sufficient information in the excitation/emission matrix (EEM) for resolution of individual compounds in a complex aqueous mixture. The large amount of information available in an EEM can be made practical, however, only through the use of third-order statistical spectral analysis. Simultaneous excitation and collection of fluorescence at multiple wavelengths was accomplished using an imaging spectrofluorometer. Application of principal component analysis (PCA) to the resulting EEMs reveals the number of spectrally-distinct substances in oil/water mixtures. The contribution of each of these fluorophores to the matrix can then be determined by means of parallel factor analysis (PARAFAC), providing a solution which is unique for a particular component. Individual hydrocarbons, such as naphthalene - a major UV-fluorescent component of gasoline, have been determined at low ppb levels in sea water characterized by a fluorescence background produced by petroleum and humic acids.

  12. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1994-03-29T23:59:59.000Z

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  13. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow (Rocky Point, NY)

    1994-01-01T23:59:59.000Z

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  14. Research on improved and enhanced oil recovery in Illinois through reservoir characterization. [Quarterly technical report], December 28, 1991--March 28, 1992

    SciTech Connect (OSTI)

    Oltz, D.F.

    1992-04-01T23:59:59.000Z

    This project will provide information that can maximize hydrocarbon production minimize formation damage and stimulate new production in Illinois. Such information includes definition of hydrocarbon resources, characterization of hydrocarbon reservoirs, and the implementation of methods that will improve hydrocarbon extractive technology. Increased understanding of reservoir heterogeneities that affect oil recovery can aid in identifying producible resources. The transfer of technology to industry and the general public is a significant component of the program. The project is designed to examine selected subsurface oil reservoirs in Illinois. Scientists use advanced scientific techniques to gain a better understanding of reservoir components and behavior and address ways of potentially increasing the amount of recoverable oil. Initial production rates for wells in the Illinois Basin commonly decline quite rapidly and as much as 60 percent of the oil in place can be unrecoverable using standard operating procedures. Heterogeneities (geological differences in reservoir make-up) affect a reservoir`s capability to release fluids. By-passed mobile and immobile oil remain in the reservoir. To learn how to get more of the oil out of reservoirs, the ISGS is studying the nature of reservoir rock heterogeneities and their control on the distribution and production of by-passed, mobile oil.

  15. Plasma-assisted conversion of solid hydrocarbon to diamond

    DOE Patents [OSTI]

    Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

    1996-01-01T23:59:59.000Z

    A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

  16. Hydrocarbon/CO{sub 2}/water multiphase equilibrium separations. Final report, July 1, 1993--September 30, 1995

    SciTech Connect (OSTI)

    Wu, C.H.; Eubank, P.T.; Barrufet, M.A. [Texas A and M Univ., College Station, TX (United States)

    1995-12-31T23:59:59.000Z

    Hydrocarbon (HC)/water and HC/CO{sub 2}/water systems are frequently found in petroleum recovery processes, petroleum refining, and gasification of coals, lignites and tar sands. Objective is to provide techniques for analyzing these mixtures at pressures up to 10,000 psia and temperatures up to 500 F; two laboratory apparatus were developed for this purpose. Three-phase separation data are obtained for mixtures of pure n-alkanes (C{sub 3} to C{sub 20}), CO{sub 2}, and water; and for mixtures of pseudocomponents of crude oils and water. Crude oils are characterized using a modified Whitson`s method. Rigorous equation-of-state computer simulators were developed and validated with experimental data; they are essential for reservoir engineering and enhanced oil recovery.

  17. Application of Landsat imagery to hydrocarbon exploration in Niobrara Formation, Denver basin

    SciTech Connect (OSTI)

    Merin, I.S.; Moore, W.R.

    1985-02-01T23:59:59.000Z

    The Niobrara Formation produces commercial quantities of oil from fractures in several places in the Denver basin. The Niobrara in this basin is an oil-prone, mature source rock having as much as 3.4% TOC, and has been in the generating window since early Eocene. This implies that hydrocarbon generation from the Niobrara is partly contemporaneous with the Laramide orogeny. The Laramide was a multiple-phase orogenic event that began with compression directed to the east-northeast during the Late Cretaceous to Paleocene and ended with compression directed to the northeast during the Eocene. The authors believe the Eocene phase activated northeast-trending extension fractures that may have acted as loci for storage and migration of hydrocarbons, locally generated in the Niobrara. The auto-fracing pressures related to hydrocarbon generation in the Niobrara theoretically would preferentially open and fill this northeast-trending fracture system. Examination of Landsat imagery shows that zones of northeast-trending lineaments are present throughout the basin. Numerous northeast-trending faults are present in the basin, and many overlie older zones that were reactivated during the Laramide. This suggests that these lineaments are previously unrecognized fracture zones. The authors have defined an exploration fairway within the basin based on subsurface isopach and resistivity mapping. The authors believe that mapping of northeast-trending fractures can help identify leads (within this fairway) prospective for Niobrara production. Support of this concept is the location of several apparently productive Niobrara wells along a zone of northeast-trending lineaments.

  18. Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil

    DOE Patents [OSTI]

    Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

  19. Monitoring hydrocarbons and trace metals in Beaufort Sea sediments and organisms. Final report

    SciTech Connect (OSTI)

    Boehm, P.; LeBlanc, L.; Trefry, J.; Marajh-Whittemore, P.; Brown, J.

    1990-10-01T23:59:59.000Z

    As part of the Minerals Management Service's environmental studies of oil and gas exploration and production activities in the Alaskan Beaufort Sea, a study was conducted in 1989 to monitor the marine environment for inputs of chemicals related to drilling and exploration. The 1989 Beaufort Sea Monitoring Program (BSMP) was designed to monitor sediments and selected benthic organisms for trace metals and hydrocarbons so as to infer any changes that might have resulted from drilling and production activities. A series of 49 stations were sampled during the program. The study area extended from Cape Halkett on the western end of Harrison Bay to Griffin Point, east of Barter Island. The sampling design combined an area-wide approach in which stations were treated as replicates of 8 specific geographic regions, with an activity-specific approach, which focused on the potential establishment of metal or hydrocarbon concentration gradients with distance from the Endicott Production Field in Prudhoe Bay. The analytical program focused on the analysis of the fine-fraction of the sediment for a series of trace metals and elements and the analysis of a suite of saturated and aromatic hydrocarbons in the bulk sediment. The total organic carbon (TOB) content and the grain size distribution in the sediments were determined as well. Benthic bivalve molluscs, representative of several feeding types were collected from those stations for which data previously existed from the 1984-1986 BSMP, and were analyzed for metals and saturated and aromatic hydrocarbons. The benthic amphipods were collected, pooled by station or region, and analyzed as well.

  20. Eco Oil 4

    SciTech Connect (OSTI)

    Brett Earl; Brenda Clark

    2009-10-26T23:59:59.000Z

    This article describes the processes, challenges, and achievements of researching and developing a biobased motor oil.

  1. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    consumption would be reduced and incentives for production increased whenever the price of crude oil

  2. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Mottram, Nigel

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  3. Geochemical and carbon isotopic studies of crude oil destruction, bitumen precipitation, and sulfate reduction in the deep Smackover Formation

    SciTech Connect (OSTI)

    Sassen, R. (Louisiana State Univ., Baton Rouge (USA))

    1988-01-01T23:59:59.000Z

    Crude oil generated by the Lower Smackover source facies migrated to Upper Smackover reservoirs where slow thermal cracking of crude oil resulted in the formation of gas-condensate and late solid bitumen. Ultimately, only pyrobitumen, methane, and nonhydrocarbon gases including hydrogen sulfide persist in the deepest Smackover reservoirs. The carbon isotopic compositions of crude oils became heavier during crude oil destruction. The carbon isotopic compositions of asphaltenes, NSO-compounds, and saturated hydrocarbons in late solid bitumen and the Lower Smackover source facies became isotopically lighter during crude oil destruction. It is suggested that some isotopically-light components from crude oils were incorporated in late solid bitumen by reactions involving thermochemical sulfate reduction. Thermochemical sulfate reduction and crude oil destruction occurred over a long span of geologic time at temperatures in the 120-150C range.

  4. Upper Jurassic Norphlet formation: new frontier for hydrocarbon prospecting in the central and eastern Gulf of Mexico regions

    SciTech Connect (OSTI)

    Mancini, E.A.; Mink, R.M.; Bearden, B.L.

    1984-04-01T23:59:59.000Z

    Since the discovery of oil in 1967 from the Smackover Formation at Toxey field, Choctaw County, Alabama, and of condensate in 1968 from the Norphlet Formation at Flomaton field, Escambia County, Alabama, the Upper Jurassic has become the primary exploration target in southwestern Alabama. Norphlet petroleum traps in the region are principally combination traps involving favorable stratigraphy and salt anticlines (Copeland field), extensional fault traps associated with salt movement (Flomaton field), and faulted salt anticlines (Hatter's Pond and Lower Mobile Bay-Mary Ann fields). Reservoir rocks include marine, dune, and fluvial sandstone lithofacies. Sandstone porosity involves both primary intergranular and secondary dissolution and fracture. Smackover algal carbonate mudstone is probably the source for much of the Norphlet hydrocarbon, but downdip Norphlet marine shales may also be source rocks. The central and eastern Gulf of Mexico regions should continue to be excellent areas to explore for hydrocarbons in the years ahead. Successful Norphlet petroleum prospecting in the area has involved the identification of favorable sandstone lithofacies and structural hydrocarbon traps by using geologic and geophysical methods. Future Norphlet discoveries will require the delineation of stratigraphic and structural/stratigraphic combination hydrocarbon traps using seismic-stratigraphic techniques.

  5. Upper Jurassic Norphlet formation: new frontier for hydrocarbon prospecting in the central and eastern Gulf of Mexico regions

    SciTech Connect (OSTI)

    Mancini, E.A.; Mink, R.M.; Bearden, B.L.

    1984-04-01T23:59:59.000Z

    Since the discovery of oil in 1967 from the Smackover Formation at Toxey field, Choctaw County, Alabama, and of condensate in 1968 from the Norphlet Formation at Flomaton field, Escambia County, Alabama, the Upper Jurassic has become the primary exploration target in southwestern Alabama. Norphlet petroleum traps in the region are principally combination traps involving favorable stratigraphy and salt anticlines (Copeland field), exensional fault traps associated with salt movement (Flomaton field), and faulted salt anticlines (Hatter's Pond and Lower Mobile Bay-Mary Ann fields). Reservoir rocks include marine, dune, and fluvial sandstone lithofacies. Sandstone porosity involves both primary intergranular and secondary dissolution and fracture. Smackover algal carbonate mudstone is probably the source for much of the Norphlet hydrocarbon, but downdip Norphlet marine shales may also be source rocks. The central and eastern Gulf of Mexico regions should continue to be excellent areas to explore for hydrocarbons in the years ahead. Successful Norphlet petroleum prospecting in the area has involved the identification of favorable sandstone lithofacies and structural hydrocarbon traps by using geologic and geophysical methods. Future Norphlet discoveries will require the delineation of stratigraphic and structural/stratigraphic combination hydrocarbon traps using seismic-stratigraphic techniques.

  6. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1983-06-21T23:59:59.000Z

    A method and apparatus for synthesizing a mixture of hydrocarbons having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further includes Na present as a substitutional cation in an amount of about 5 to 10 atom %. At a temperature of about 340 to 360/sup 0/C, and at pressures of about 20 to 50 atm, CH/sub 3/OH is produced in an amount of about 90 wt % of the total hydrocarbon mixture, and comprised 1 mole % of the effluent gas.

  7. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01T23:59:59.000Z

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  8. Behavioral toxicology, risk assessment, and chlorinated hydrocarbons

    SciTech Connect (OSTI)

    Evangelista de Duffard, A.M.; Duffard, R. [Laboratorio de Toxicologia Experimental, Santa Fe (Argentina)

    1996-04-01T23:59:59.000Z

    Behavioral end points are being used with greater frequency in neurotoxicology to detect and characterize the adverse effects of chemicals on the nervous system. Behavioral measures are particularly important for neurotoxicity risk assessment since many known neurotoxicants do not result in neuropathology. The chlorinated hydrocarbon class consists of a wide variety of chemicals including polychlorinated biphenyls, clioquinol, trichloroethylene, hexachlorophene, organochlorine insecticides (DDT, dicofol, chlordecone, dieldrin, and lindane), and phenoxyherbicides. Each of these chemicals has effects on motor, sensory, or cognitive function that are detectable using functional measures such as behavior. Furthermore, there is evidence that if exposure occurs during critical periods of development, many of the chlorinated hydrocarbons are developmental neurotoxicants. Developmental neurotoxicity is frequently expressed as alterations in motor function or cognitive abilities or charges in the ontogeny of sensorimotor reflexes. Neurotoxicity risk assessment should include assessments of the full range of possible neurotoxicological effects, including both structural and functional indicators of neurotoxicity. 121 refs., 1 tab.

  9. Conversion method for gas streams containing hydrocarbons

    DOE Patents [OSTI]

    Mallinson, Richard G. (Norman, OK); Lobban, Lance (Norman, OK); Liu, Chang-jun (Tianjin, CN)

    2000-01-01T23:59:59.000Z

    An apparatus and a method of using the apparatus are provided for converting a gas stream containing hydrocarbons to a reaction product containing effluent molecules having at least one carbon atom, having at least one interior surface and at least one exterior surface, a first electrode and a second electrode with the first and second electrodes being selectively movable in relation to each other and positioned within the housing so as to be spatially disposed a predetermined distance from each other, a plasma discharge generator between the first and second electrodes, gas stream introducer and a collector for collecting the reaction product effluent produced by the reaction of the gas stream containing hydrocarbons with the plasma discharge between the first and second electrodes.

  10. Natural Oil Production from Microorganisms: Bioprocess and Microbe Engineering for Total Carbon Utilization in Biofuel Production

    SciTech Connect (OSTI)

    None

    2010-07-15T23:59:59.000Z

    Electrofuels Project: MIT is using carbon dioxide (CO2) and hydrogen generated from electricity to produce natural oils that can be upgraded to hydrocarbon fuels. MIT has designed a 2-stage biofuel production system. In the first stage, hydrogen and CO2 are fed to a microorganism capable of converting these feedstocks to a 2-carbon compound called acetate. In the second stage, acetate is delivered to a different microorganism that can use the acetate to grow and produce oil. The oil can be removed from the reactor tank and chemically converted to various hydrocarbons. The electricity for the process could be supplied from novel means currently in development, or more proven methods such as the combustion of municipal waste, which would also generate the required CO2 and enhance the overall efficiency of MIT’s biofuel-production system.

  11. Particles of spilled oil-absorbing carbon in contact with water

    DOE Patents [OSTI]

    Muradov, Nazim (Melbourne, FL)

    2011-03-29T23:59:59.000Z

    Hydrogen generator coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. Carbon particles with surface filaments having a hydrophobic property of oil film absorption, compositions of matter containing those particles, and a system for using the carbon particles for cleaning oil spills.

  12. Getter pump for hydrogen and hydrocarbon gases

    DOE Patents [OSTI]

    Hsu, Wen Ling

    1987-10-14T23:59:59.000Z

    A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

  13. Production of synthetic hydrocarbon fuels from peat

    SciTech Connect (OSTI)

    Bodle, W.W.; Punwani, D.; Weil, S.A.

    1982-06-22T23:59:59.000Z

    A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.

  14. Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

    DOE Patents [OSTI]

    Kung, H.H.; Chaar, M.A.

    1988-10-11T23:59:59.000Z

    Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

  15. Costs of aggregate hydrocarbon reserve additions

    E-Print Network [OSTI]

    Adelman, Morris Albert

    2002-01-01T23:59:59.000Z

    In what follows, we highlight problems created by aggregation using fixed conversion coefficients (Section 1). We then offer an economic index approach as an alternative, one that recognizes changing relative values of oil ...

  16. Enhanced solubility of petroleum hydrocarbons using biosurfactants 

    E-Print Network [OSTI]

    Page, Cheryl Ann

    1997-01-01T23:59:59.000Z

    the control reactors contained distilled-deionized water and the crude oil. Using a temporal-monitoring scheme, the reactors were sacrificially sampled to determine the water-accommodated fraction (WAF). The phenanthrenes, fluorenes, pyrenes, and chrysenes...

  17. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Venezuelan Oil Industry Total Wells Drilled and InvestmentWells Drilled and Investment in the Venezuelan Oil Industryopenness of the oil sector to foreign investment contributes

  18. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    is described below. Data Crude oil production data is fromproductivity measure is crude oil production per worker, andwhich is measured as crude oil production per worker, is

  19. Oil and Gas Supply Module

    Gasoline and Diesel Fuel Update (EIA)

    and sources. Crude oil recovery includes improved oil recovery processes such as water flooding, infill drilling, and horizontal drilling, as well as enhanced oil recovery...

  20. Oil and Gas Supply Module

    Gasoline and Diesel Fuel Update (EIA)

    and sources. Crude oil recovery includes improved oil recovery processes such as water flooding, infill drilling, and horizontal continuity, as well as enhanced oil recovery...

  1. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and Mexico . . . . . . . .2.6: Oil Production in Venezuela and Mexico 350 Productivity

  2. Unitizing and waterflooding the California Yowlumne Oil Field

    SciTech Connect (OSTI)

    Burzlaff, A.A.

    1983-03-01T23:59:59.000Z

    The Yowlumne field, located at the southern end of the San Joaquin Valley of California, is one of the largest new onshore oil fields discovered in California in the past twenty years. The field, at an average depth of 12,200', has produced over 42 million barrels of oil since its discovery in 1974. In May, 1982, a portion of the Yowlumne field was unitized and called Yowlumne Unit ''B''. Nine operators and about 160 royalty owners cooperated to form this unit. A two phase unitization formula based on remaining primary and initial hydrocarbon pore volume was used to form Unit ''B''. A secondary waterflood project is being implemented which is estimated to increase oil recovery by some 25 million barrels.

  3. Pathways of migration of oil and gas in south Mississippi salt basin

    SciTech Connect (OSTI)

    Evans, R.

    1987-09-01T23:59:59.000Z

    The South Mississippi salt basin is one of three interior basins characterized by structures formed by movement of the Late Jurassic Louann Salt. An analysis of pathways of migration within the basin has revealed that it is possible to explain why hydrocarbons have accumulated in some structures, yet are absent from others that would appear to be favorable. Seventy-four of the more than 840 fields within the basin, including the largest known accumulations, have hydrocarbons in stacked reservoirs belonging in more than one formation. These stacked reservoirs result from vertical migration facilitated by faulting. In more than 750 fields, hydrocarbons are confined to a single formation in traps associated with four distinct trends of production that decrease in age systematically from the margin of the basin into the interior. The hydrocarbons in these trends have accumulated by intrastratal migration (without the agency of faulting) from a nearby source in the same unit as the reservoir. On the northwest side of the basin, migration between units brought into contact along unconformities has resulted in 10 fields. Vertical migration brought about by faulting around shallow salt diapirs has allowed hydrocarbons to escape, so that only 5 of 56 such structures have produced oil or gas. These conclusions, derived from geologic deductions, are supported by preliminary geochemical data; more extensive and detailed geochemical analyses of oils from the various sources are under way.

  4. Real-time characterization of particle-bound polycyclic aromatic hydrocarbons in ambient aerosols and from motor-vehicle exhaust

    E-Print Network [OSTI]

    Polidori, A.; Hu, S.; Biswas, S.; Delfino, R. J; Sioutas, C.

    2008-01-01T23:59:59.000Z

    of polycyclic aromatic hydrocarbons in coupled out- door/polycyclic aromatic hydrocarbon concentration in combustionbound polycyclic aromatic hydrocarbons K. A. , Morris, J. ,

  5. Basement rift control on oil production in eastern Kansas

    SciTech Connect (OSTI)

    Gustavson, J.B.

    1983-08-01T23:59:59.000Z

    Improved understanding of the central North American rift system (CNARS) offers a new interpretation of the basement structure in certain parts of the Mid-Continent. In eastern Kansas, basement structure can be shown to control oil production from some producing fields. Structural control includes rotated blocks along faults created by horst and graben tectonics typically associated with rift zones. A distinctive gravity signature, the Mid-Continent geophysical anomaly (MGA) is related directly to the CNARS and provides good data for interpretation of the basement structure. Some oil fields can be correlated directly with gravity-interpreted basement structure. Aeromagnetic and Landsat information, combined with the gravity data, further define exploration targets along the general trend of basement features. Migration of thermally matured hydrocarbons into pre-Pennsylvanian, rift generated traps in the ancestral north Kansas basin is postulated. The Nemaha ridge subsequently divided that basin into two smaller basins, the present Salina and Forest City basins. Several exploration targets could exist in this area, with the Arbuckle, Simpson, and Viola units being primary targets. The source of hydrocarbons also may lie in the deep but distant Anadorko basin. An additional totally untested hydrocarbons potential exists in the deep Precambrian/Cambrian sedimentary subbasins created along the flanks of the CNARS. Recent data points to sedimentary columns with depths of approximately 15,000 ft (4500 m) which might be hosts to gas reserves similar to the Rome trough potential of the Appalachian region.

  6. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14T23:59:59.000Z

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  7. Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri

    E-Print Network [OSTI]

    McFall-Ngai, Margaret

    Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri So Polycyclic aromatic hydrocarbons a b s t r a c t Effects of individual petroleum hydrocarbons hydrocarbons, including benzene and its derivatives and polycyclic aromatic hydrocarbons (PAHs), were chosen

  8. Libyan oil industry

    SciTech Connect (OSTI)

    Waddams, F.C.

    1980-01-01T23:59:59.000Z

    Three aspects of the growth and progress of Libya's oil industry since the first crude oil discovery in 1961 are: (1) relations between the Libyan government and the concessionary oil companies; (2) the impact of Libyan oil and events in Libya on the petroleum markets of Europe and the world; and (3) the response of the Libyan economy to the development of its oil industry. The historical review begins with Libya's becoming a sovereign nation in 1951 and traces its subsequent development into a position as a leading world oil producer. 54 references, 10 figures, 55 tables.

  9. Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel

    SciTech Connect (OSTI)

    Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.; Santosa, Daniel M.; Preto, Fernando; Iisa, Kristiina

    2014-12-01T23:59:59.000Z

    Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBK wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.

  10. Formation of dl-limonene in used tire vacuum pyrolysis oils. [dipentene

    SciTech Connect (OSTI)

    Pakdel, H.; Roy, C.; Aubin, H.; Jean, G. (Univ. Lavel, Sainte-Foy, Quebec (Canada)); Coulombe, S. (CANMET, Varennes, Quebec (Canada))

    1991-09-01T23:59:59.000Z

    Tire recycling has become an important environmental issue recently due to the huge piles of tires that threaten the environment. Thermal decomposition of tire, a synthetic rubber material, enables the recovery of carbon black and liquid hydrocarbon oils. Both have potential economic values. Pyrolysis oils obtained under vacuum conditions contain a significant portion of a volatile, naptha-like fraction with an octane number similar to petroleum naphtha fraction, in addition, contains approximately 15% limonene. Potential applications of vacuum pyrolysis oil and carbon black have been investigated. However, the process economics is greatly influenced by the quality of the oil and carbon black products. This paper discusses limonene formation during used tire vacuum pyrolysis and its postulated reaction mechanism. The limonene separation method from pyrolysis oil, as well as its purification in laboratory scale, and structural characterization are discussed. Large-scale limonene separation and purification is under investigation.

  11. Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    aging, etc. deer09devarakonda.pdf More Documents & Publications The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst CLEERS Aftertreatment Modeling and...

  12. Systems and methods for producing hydrocarbons from tar sands formations

    DOE Patents [OSTI]

    Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

    2009-07-21T23:59:59.000Z

    A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

  13. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of catalyst materials to facilitate the low-temperature oxidation of hydrocarbons and CO in homogeneous charge compression ignition (HCCI) emissions. deer08...

  14. Process for making unsaturated hydrocarbons using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

    2011-04-12T23:59:59.000Z

    The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

  15. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  16. Biological Conversion of Sugars to Hydrocarbons Technology Pathway

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with...

  17. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  18. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  19. adsorption equilibria hydrocarbons: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Page Last Page Topic Index 1 Phase equilibria of polydisperse hydrocarbons: moment free energy method analysis Mathematical Physics (arXiv) Summary: We analyze the phase...

  20. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Broader source: Energy.gov (indexed) [DOE]

    the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

  1. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Nelson, Lee O. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2009-02-24T23:59:59.000Z

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  2. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Broader source: Energy.gov (indexed) [DOE]

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

  3. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production from Sewage Sludge

    Broader source: Energy.gov [DOE]

    Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste FeedstocksEnhanced Anaerobic Digestion and Hydrocarbon Precursor Production from Sewage...

  4. Oil and gas basins in the former Soviet Union

    SciTech Connect (OSTI)

    Clayton, J. (Geological Survey, Denver, CO (United States))

    1993-09-01T23:59:59.000Z

    The Pripyat basin is a Late Devonian rift characterized by a typical fault-block structure. Two synrift salt formations separate the Devonian stratigraphic succession into the subsalt, intersalt, and postsalt sections. Oil is produced from carbonate reservoirs of the subsalt and intersalt sections. Traps are controlled by crests of tilted fault blocks. We analyzed 276 shale and carbonate-rock samples and 21 oils to determine oil-source bed relationships in the basin. Maturities of the oils are from very immature, heavy (9[degrees] API), to very mature, light (42[degrees] API). All fields are in a narrow band on the north side of the basin, and only shows of immature, heavy oil have been obtained from the rest of the basin. Three genetic oil types are identified. Oil type A has high pristane/phytane ratios (>1.0), high amounts of C[sub 29] 18[alpha] (H) trisnorneohopane, and [delta]13C of hydrocarbons in the range of -31 to -27%. Oil types B and C contain very high amounts of gammacerane, which suggests that the oils were derived from carbonate-evaporite source facies. Type B oils are isotopically similar to type A, whereas type C oils are isotopically light (about -33%). Organic carbon content is as much as 5%, and kerogen types range from I to IV. Our data indicate that rocks within the intersalt carbonate formation are the source of the type B oils of low maturity. Thermally mature rocks that might be the source for the mature oils have not been found. Such rocks may occur in depressions adjacent to tilted fault blocks. Higher levels of thermal maturity on the north part of the basin in the vicinity of the most mature oils may be related to higher heat flow during and soon after rifting or to a suspected recently formed magmatic body in the crust below the northern zone. Present-day high temperatures in parts of the northern zone may support the latter alternative.

  5. REVIEW PAPER Biodeterioration of crude oil and oil derived

    E-Print Network [OSTI]

    Appanna, Vasu

    , the majority of applied microbiologi- cal methods of enhanced oil recovery also dete- riorates oil and appearsREVIEW PAPER Biodeterioration of crude oil and oil derived products: a review Natalia A. Yemashova January 2007 Ó Springer Science+Business Media B.V. 2007 Abstract Biodeterioration of crude oil and oil

  6. Acute Embryonic or Juvenile Exposure to Deepwater Horizon Crude Oil Impairs the Swimming Performance of Mahi-Mahi (Coryphaena

    E-Print Network [OSTI]

    Grosell, Martin

    with the water during ascent to the surface.11,12 Thus, PAH exposures likely occurred for adult fish breeding exposure of a water- accommodated fraction of oil from the spill to mahi-mahi as juveniles, or as embryos deficits, likely attributable to polycyclic aromatic hydrocarbons (PAHs), occurred at environmentally

  7. Using Oils As Pesticides

    E-Print Network [OSTI]

    Bogran, Carlos E.; Ludwig, Scott; Metz, Bradley

    2006-10-30T23:59:59.000Z

    Petroleum and plant-derived spray oils show increasing potential for use as part of Integrated Pest Management systems for control of soft-bodied pests on fruit trees, shade trees, woody ornamentals and household plants. Sources of oils, preparing...

  8. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    an alternative investment strategy to buying oil today andinvestments necessary to catch up. This was the view o?ered by oilinvestment strategy. date t) in order to purchase a quantity Q barrels of oil

  9. Gas and Oil (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment has the authority to enact regulations pertaining to oil and gas production, but it cannot prorate or limit the output of any gas or oil well. A permit from the...

  10. Metagenomics for Greener Production and Extraction of Hydrocarbon Energy

    E-Print Network [OSTI]

    Gieg, Lisa

    ............................................................................11 6.2.1 Oil and Gas Conservation Act..............................................................................................11 6.2.2 Oil and Gas Conservation Regulations.............................14 6.2.4 ERCB Directive 065: Resources Applications for Oil and Gas Reservoirs

  11. Structure, stratigraphy, and hydrocarbons offshore southern Kalimantan, Indonesia

    SciTech Connect (OSTI)

    Bishop, W.F.

    1980-01-01T23:59:59.000Z

    Offshore southern Kalimantan (Borneo), Indonesia, the Sunda Shelf is bounded on the south by the east-west-trending Java-Madura foreland basin and on the north by outcrops of the granitic core of Kalimantan. Major northeast-southwest-trending faults created a basin and ridge province which controlled sedimentation at least until early Miocene time. Just above the unconformity, the oldest pre-CD Limestone clastic strata are fluviatile and lacustrine, the remainder consisting largely of shallow-marine, calcareous shale with interbeds of fine-grained, quartzose sandstone. A flood of terrigenous detritus - Kudjung unit 3 - resulted from post-CD Limestone uplift, and is more widely distributed. Unit 3 consists largely of fluviatile sandstone interbedded with shale and mudstone, grading upward to marine clastics with a few thin limestones near the top. The resulting Kudjing unit 2 is largely a shallow-basinal deposit, comprising thin, micritic limestones interbedded with calcareous shale and mudstone. Infilling of the basins was nearly complete by the end of Kudjing unit 1 deposition. Eastern equivalents of Kudjing units 1 and 2 are known as the Berai limestone interval (comprising bank, reefal, basinal, and open-marine limestones, and marl). Of the three oil fields in the area, two are shut in, but one has produced nearly 100 million bbl. Gas shows were recorded in most wells of the area, but the maximum flow was 1.8 MMcf methane/day, although larger flows with high percentages of carbon dioxide and nitrogen were reported. Fine-grained clastic strata of unit 3 are continuous with those farther south, where geochemical data indicate good source and hydrocarbon-generating potential. Sandstones with reservoir capability are present in the clastic intervals, and several carbonate facies have sporadically developed porosity. A variety of structural and stratigraphic traps is present. 20 figures, 1 table.

  12. Fundamental measure theory of hydrated hydrocarbons

    E-Print Network [OSTI]

    Victor F. Sokolov; Gennady N. Chuev

    2006-04-13T23:59:59.000Z

    To calculate the solvation of hydrophobic solutes we have developed the method based on the fundamental measure treatment of the density functional theory. This method allows us to carry out calculations of density profiles and the solvation energy for various hydrophobic molecules with a high accuracy. We have applied the method to the hydration of various hydrocarbons (linear, branched and cyclic). The calculations of the entropic and the enthalpic parts are also carried out. We have examined a question about temperature dependence of the entropy convergence. Finally, we have calculated the mean force potential between two large hydrophobic nanoparticles immersed in water.

  13. Shale oil demetallization process

    SciTech Connect (OSTI)

    Silverman, M. A.

    1985-08-13T23:59:59.000Z

    Trace metals, particularly As, Fe and Ni, are removed from hydrocarbonaceous oils, particularly shale oil by contacting the shale oil with quadrolobe alumina with or without a processing gas such as hydrogen or nitrogen at 500/sup 0/ F. to 800/sup 0/ F. at 250 to 750 psig and LHSV of 0.4 to 3.0 to deposit a portion of said trace metal onto said alumina and recover an oil product having substantially reduced amounts of trace metal.

  14. Oil Peak or Panic?

    SciTech Connect (OSTI)

    Greene, David L [ORNL

    2010-01-01T23:59:59.000Z

    In this balanced consideration of the peak-oil controversy, Gorelick comes down on the side of the optimists.

  15. Effects of selected thermophilic microorganisms on crude oils at elevated temperatures and pressures. Final report

    SciTech Connect (OSTI)

    Premuzic, E.T.; Lin, M.S.

    1995-07-01T23:59:59.000Z

    During the past several years, a considerable amount of work has been carried out showing that microbially enhanced oil recovery (MEOR) is promising and the resulting biotechnology may be deliverable. At the Brookhaven National Laboratory (BNL), systematic studies have been conducted which dealt with the effects of thermophilic and thermoadapted bacteria on the chemical and physical properties of selected types of crude oils at elevated temperatures and pressures. Particular attention was paid to heavy crude oils from Venezuela, California, Alabama, Arkansas, Wyoming, Alaska, and other oil producing areas. Current studies indicate that during the biotreatment several chemical and physical properties of crude oils are affected. The oils are (1) emulsified; (2) acidified; (3) there is a qualitative and quantitative change in light and heavy fractions of the crudes; (4) there are chemical changes in fractions containing sulfur compounds; (5) there is an apparent reduction in the concentration of trace metals; (6) the qualitative and quantitative changes appear to be microbial species dependent; and (7) there is a distinction between {open_quotes}biodegraded{close_quotes} and {open_quotes}biotreated{close_quotes} oils. Preliminary results indicate the introduced microorganisms may become the dominant species in the bioconversion of oils. These studies also indicate the biochemical interactions between crude oils and microorganisms follow distinct trends, characterized by a group of chemical markers. Core-flooding experiments have shown significant additional crude oil recoveries are achievable with thermophilic microorganisms at elevated temperatures similar to those found in oil reservoirs. In addition, the biochemical treatment of crude oils has technological applications in downstream processing of crude oils such as in upgrading of low grade oils and the production of hydrocarbon based detergents.

  16. HYDROCARBONS OF BIOLOGICAL ORIGIN FROM A ONE-BILLION YEAR OLD SEDIMENT

    E-Print Network [OSTI]

    Eglinton, Geoffrey.; Scott, P.M.; Belsky, Ted.; Burlingame, A.L.; Calvin, Melvin.; Cloud Jr., Preston E.

    1964-01-01T23:59:59.000Z

    Contract No. W-7405-eng-48 HYDROCARBONS OF BIOLOGICAL ORIGINAbstract The isoprenoid hydrocarbons, phytane (C 20H4Z) andThe identification of these hydrocarbons augurs well for the

  17. Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments by providing

    E-Print Network [OSTI]

    Lovley, Derek

    Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments to simulate the degradation of aromatic hydrocarbons in anaerobic contaminated sediments was investigated as the sole electron acceptor. Providing graphite electrodes as an electron acceptor in hydrocarbon

  18. Field metabolomics and laboratory assessments of anaerobic intrinsic bioremediation of hydrocarbons

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Field metabolomics and laboratory assessments of anaerobic intrinsic bioremediation of hydrocarbons the in situ anaerobic attenuation of hydrocarbons in a contaminated aquifer underly- ing a former refinery. Metabolite profiles associated with anaerobic hydrocarbon decay revealed the microbial utilization

  19. Lasius niger ants discriminate aphids based on their cuticular hydrocarbons Corsin Langa,1

    E-Print Network [OSTI]

    Richner, Heinz

    Lasius niger ants discriminate aphids based on their cuticular hydrocarbons Corsin Langa,1 chemical communication cuticular hydrocarbon interspecific communication Lasius niger mutualism species covered with aphid cuticular hydrocarbons. Neutral control objects were antennated, but the ants quickly

  20. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst Study of effects of hydrocarbons on ammonia storage...

  1. Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons

    E-Print Network [OSTI]

    Goulay, Fabien

    2010-01-01T23:59:59.000Z

    with Small Unsaturated Hydrocarbons Fabien Goulay, 1, †,‡react with the selected hydrocarbon in a helium gas flow.Small cyclic unsaturated hydrocarbons such as c-C 3 H, c-C 3

  2. HYDROCARBON LIQUID FLOW CALIBRATION SERVICE NIST Special Publication 250-1039

    E-Print Network [OSTI]

    Magee, Joseph W.

    HYDROCARBON LIQUID FLOW CALIBRATION SERVICE NIST Special Publication 250-1039 T. T. Yeh, Jesús and Technology Laboratory National Institute of Standards and Technology Gaithersburg, MD 20899 #12;Hydrocarbon......................................... 3 4.0 Description of the Hydrocarbon Liquid Flow Standard

  3. The Hydrophobic Effect Drives the Recognition of Hydrocarbons by an Anionic Metal-Ligand Cluster

    E-Print Network [OSTI]

    Biros, Shannon

    2009-01-01T23:59:59.000Z

    Drives the Recognition of Hydrocarbons by an Anionic Metal-Drives the Recognition of Hydrocarbons by an Anionic Metal-including saturated hydrocarbons, 11,12 in aqueous solution,

  4. Oil and Gas Exploration

    E-Print Network [OSTI]

    Tingley, Joseph V.

    , oil and gas, and geothermal activities and accomplishments in Nevada: production statistics Products 23. Sloan dolomite quarry 24. Weiser gypsum quarry Oil Fields 1. Blackburn field 2. North WillowMetals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada

  5. Exploiting heavy oil reserves

    E-Print Network [OSTI]

    Levi, Ran

    North Sea investment potential Exploiting heavy oil reserves Beneath the waves in 3D Aberdeen the potential of heavy oil 8/9 Taking the legal lessons learned in the north Sea to a global audience 10 potential Exploiting heavy oil reserves Aberdeen: A community of science AT WORK FOR THE ENERGY SECTOR ISSUE

  6. Oil reservoir characterization using ensemble data assimilation

    E-Print Network [OSTI]

    Jafarpour, Behnam

    2008-01-01T23:59:59.000Z

    Increasing world energy demand combined with decreasing discoveries of new and accessible hydrocarbon reserves are necessitating optimal recovery from the world's current hydrocarbon resources. Advances in drilling and ...

  7. Rate controlling model for bioremediation of oil contaminated soil

    SciTech Connect (OSTI)

    Li, K.Y.; Annamali, S.N.; Hopper, J.R. (Lamar Univ., Beaumont, TX (United States))

    1993-11-01T23:59:59.000Z

    A mathematical model of bio-remediation of hydrocarbons in a soil matrix has been developed to predict the rate controlling step and the remediation rate during the bioremediation of a contaminated soil. The model is based on mass transfer of oxygen and oil into the aqueous solution in the soil matrix and the biodegradation of the hydrocarbons in the aqueous solution. Monod's equation was used to describe the biodegradation rate in aqueous solution while the mass transfer equations were used to describe the mass transfer rates of oxygen and oil in the soil matrix. Results from model calculations indicate that the bio-remediation rate increases and approaches a limiting value when one of the rates becomes controlling. When the parameters of the site soil samples are measured and the solubilities of oxygen and oil in aqueous solution are obtained, the bioremediation rate can be predicted by this model. The rate controlling step of the bioremediation site may be identified quickly and steps to improve the bioremediation rate can be recommended. 8 refs., 7 figs.

  8. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20T23:59:59.000Z

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  9. Solubility of hydrocarbons in salt water

    SciTech Connect (OSTI)

    Yaws, C.L.; Lin, X. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

    1994-01-01T23:59:59.000Z

    In the design and operation of industrial processes, physical and thermodynamic property data are required. Increasingly stringent regulations are making water solubility of substances even more critical. Water solubility data of naphthenes, or cycloalkanes, is applicable for the complete range of salt concentrations, including water without salt to water saturated with salt. The results are intended for use in initial engineering and environmental applications. Solubility values from the correlation are useful in determining the distribution of a hydrocarbon spill on its contact with sea water. Solubility values at other salt concentrations also may be computed. Results are presented for water solubility of hydrocarbons (naphthenes) as a function of salt concentration (log(S) = A + BX + CX[sup 2]). The correlation constants, A, B and C, are displayed in an easy-to-use tabular format that is applicable for rapid engineering use with the personal computer or hand-held calculator. The results for solubility in salt water are applicable for the complete range of salt concentrations. This range covers water without salt, X = 0, to water saturated with salt, X = 358,700 ppM(wt). Correlation and experimental results are in favorable agreement.

  10. Process for the production of liquid hydrocarbons

    DOE Patents [OSTI]

    Bhatt, Bharat Lajjaram; Engel, Dirk Coenraad; Heydorn, Edward Clyde; Senden, Matthijis Maria Gerardus

    2006-06-27T23:59:59.000Z

    The present invention concerns a process for the preparation of liquid hydrocarbons which process comprises contacting synthesis gas with a slurry of solid catalyst particles and a liquid in a reactor vessel by introducing the synthesis gas at a low level into the slurry at conditions suitable for conversion of the synthesis gas into liquid hydrocarbons, the solid catalyst particles comprising a catalytic active metal selected from cobalt or iron on a porous refractory oxide carrier, preferably selected from silica, alumina, titania, zirconia or mixtures thereof, the catalyst being present in an amount between 10 and 40 vol. percent based on total slurry volume liquids and solids, and separating liquid material from the solid catalyst particles by using a filtration system comprising an asymmetric filtration medium (the selective side at the slurry side), in which filtration system the average pressure differential over the filtration medium is at least 0.1 bar, in which process the particle size distribution is such that at least a certain amount of the catalyst particles is smaller than the average pore size of the selective layer of the filtration medium. The invention also comprises an apparatus to carry out the process described above.

  11. Past, Present, and Future Production of Bio-oil

    SciTech Connect (OSTI)

    Steele, Philip; Yu, Fei; Gajjela, Sanjeev

    2009-04-01T23:59:59.000Z

    Bio-oil is a liquid product produced by fast pyrol-ysis of biomass. The fast pyrolysis is performed by heating the biomass rapidly (2 sec) at temperatures ranging from 350 to 650 oC. The vapors produced by this rapid heating are then condensed to produce a dark brown water-based emulsion composed of frag-ments of the original hemicellulose, cellulose and lignin molecules contained in the biomass. Yields range from 60 to 75% based on the feedstock type and the pyrolysis reactor employed. The bio-oil pro-duced by this process has a number of negative prop-erties that are produced mainly by the high oxygen content (40 to 50%) contributed by that contained in water (25 to 30% of total mass) and oxygenated compounds. Each bio-oil contains hundreds of chemi-cal compounds. The chemical composition of bio-oil renders it a very recalcitrant chemical compound. To date, the difficulties in utilizing bio-oil have limited its commercial development to the production of liq-uid smoke as food flavoring. Practitioners have at-tempted to utilize raw bio-oil as a fuel; they have also applied many techniques to upgrade bio-oil to a fuel. Attempts to utilize raw bio-oil as a combustion engine fuel have resulted in engine or turbine dam-age; however, Stirling engines have been shown to successfully combust raw bio-oil without damage. Utilization of raw bio-oil as a boiler fuel has met with more success and an ASTM standard has recently been released describing bio-oil characteristics in relation to assigned fuel grades. However, commercialization has been slow to follow and no reports of distribution of these bio-oil boiler fuels have been reported. Co-feeding raw bio-oil with coal has been successfully performed but no current power generation facilities are following this practice. Upgrading of bio-oils to hydrocarbons via hydroprocessing is being performed by several organizations. Currently, limited catalyst life is the obstacle to commercialization of this tech-nology. Researchers have developed means to increase the anhydrosugars content of bio-oil above the usual 3% produced during normal pyrolysis by mild acid pretreatment of the biomass feedstock. Mississippi State University has developed a proprietary method to produce an aqueous fraction containing more than 50% of anhydrosugars content. These anhydrosugars can be catalyzed to hydrogen or hydrocarbons; alter-nately, the aqueous fraction can be hydrolyzed to pro-duce a high-glucose content. The hydrolyzed product can then be filtered to remove microbial inhibitor compounds followed by production of alcohols by fer-mentation. Production of bio-oil is now considered a major candidate as a technology promising production of drop-in transportation and boiler fuels.

  12. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    1999-01-01T23:59:59.000Z

    A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  13. Selective thermal oxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2000-01-01T23:59:59.000Z

    A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  14. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2001-01-01T23:59:59.000Z

    A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  15. Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE prototype working with a scroll compressor was built and tested. A near-industrial prototype is today being regarding hydrocarbons as refrigerants, this article reviews scroll compressor modelling studies

  16. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, H.; Blatter, F.; Sun, H.

    1999-06-22T23:59:59.000Z

    A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

  17. Biological Conversion of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  18. ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS

    E-Print Network [OSTI]

    Matsuoka, Hiroshige

    ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS H. MATSUOKA1 , T] or meniscus force [3], which have been neglected in the conventional and relatively large mechani- cal systems forces between mica surfaces in under- saturated vapors of several kind of hydrocarbon liquids are mea

  19. Underground storage of oil and gas

    SciTech Connect (OSTI)

    Bergman, S.M.

    1984-09-01T23:59:59.000Z

    The environmental and security advantages of underground storage of oil and gas are well documented. In many cases, underground storage methods such as storage in salt domes, abandoned mines, and mined rock caverns have proven to be cost effective when compared to storage in steel tanks constructed for that purpose on the surface. In good rock conditions, underground storage of large quantities of hydrocarbon products is normally less costly--up to 50-70% of the surface alternative. Under fair or weak rock conditions, economic comparisons between surface tanks and underground caverns must be evaluated on a case to case basis. The key to successful underground storage is enactment of a realistic geotechnical approach. In addition to construction cost, storage of petroleum products underground has operational advantages over similar storage above ground. These advantages include lower maintenance costs, less fire hazards, less land requirements, and a more even storage temperature.

  20. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Broader source: Energy.gov (indexed) [DOE]

    The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization...

  1. Heating hydrocarbon containing formations in a line drive staged process

    DOE Patents [OSTI]

    Miller, David Scott (Katy, TX)

    2009-07-21T23:59:59.000Z

    Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

  2. Cogeneration systems and processes for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

    2009-12-29T23:59:59.000Z

    A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

  3. The extraction of bitumen from western oil sands: Volume 1. Final report

    SciTech Connect (OSTI)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26T23:59:59.000Z

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains an executive summary and reports for five of these projects. 137 figs., 49 tabs.

  4. The extraction of bitumen from western oil sands: Volume 2. Final report

    SciTech Connect (OSTI)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26T23:59:59.000Z

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains reports on nine of these projects, references, and a bibliography. 351 refs., 192 figs., 65 tabs.

  5. Petrology and hydrocarbon reservoir potential of Mississippian (Chesterian) sandstones, Black Warrior basin, Mississippi

    SciTech Connect (OSTI)

    Hughes, S.B.; Meylan, M.A.

    1988-09-01T23:59:59.000Z

    The character and reservoir quality of six different Mississippian (Chesterian) sandstone units in frontier areas of the Black Warrior basin of Mississippi have been determined by core inspection, thin-section examination, and x-ray diffractometry. A total of 113 samples from ten wells was taken from cores of the following sandstones: the Lewis, a calcareous sandstone at the top of or just above the Lewis that the authors refer to as the Lewis limestone, the Evans, the Rea, the Sanders, and the Carter. Hydrocarbon production from the basin, which is located in northeastern Mississippi and northwestern Alabama, is mostly shallow gas (with minor gas condensate and oil) from the units. Sample depths range from about 2500 ft (762 m) in northern Chickasaw County to about 5500 ft (1676 m) in Monroe and Lowndes Counties, with the deepest samples coming from almost 11,000 ft (3353 m) in northern Clay County.

  6. Aromatic hydrocarbons associated with brines from geopressured wells. Annual report, fiscal 1985

    SciTech Connect (OSTI)

    Keeley, D.F.; Meriwether, J.R.

    1985-01-01T23:59:59.000Z

    Samples of cryocondensates - materials condensed at - 78.5/sup 0/C were taken on a regular basis from the gas stream for the USDOE geopressured wells. Most of the data has been taken from the Gladys McCall well as it has flowed on a regular and almost continous basis. The cryocondensates, not the ''condensate'' from gas wells, are almost exclusively aromatic hydrocarbons, primarily benzene, toluene, ethylbenzene, and the xylenes, but contain over 95 compounds, characterized using gas chromatographic-mass spectroscopy. The solubility in water and brine of benezene, toluene, ethylbenzene and o-xylene, some of the components of the cryocondensate, as well as distribution coefficients between water or brine and a standard oil have been measured. 25 refs.

  7. Geology and hydrocarbon potential of the Hamada and Murzuq basins in western Libya

    SciTech Connect (OSTI)

    Kirmani, K.U.; Elhaj, F.

    1988-08-01T23:59:59.000Z

    The Hamada and Murzuq intracratonic basins of western Libya form a continuation of the Saharan basin which stretches from Algeria eastward into Tunisia and Libya. The tectonics and sedimentology of this region have been greatly influenced by the Caledonian and Hercynian orogenies. Northwest- and northeast-trending faults are characteristic of the broad, shallow basins. The Cambrian-Ordovician sediments are fluvial to shallow marine. The Silurian constitutes a complete sedimentary cycle, ranging from deep marine shales to shallow marine and deltaic sediments. The Devonian occupies a unique position between two major orogenies. The Mesozoic strata are relatively thin. The Triassic consists of well-developed continental sands, whereas the Jurassic and Cretaceous sediments are mainly lagoonal dolomites, evaporites, and shales. Silurian shales are the primary source rock in the area. The quality of the source rock appears to be better in the deeper part of the basin than on its periphery. The Paleozoic has the best hydrocarbon potential. Hydrocarbons have also been encountered in the Triassic and Carboniferous. In the Hamada basin, the best-known field is the El Hamra, with reserves estimated at 155 million bbl from the Devonian. Significant accumulations of oil have been found in the Silurian. Tlacsin and Tigi are two fields with Silurian production. In the Murzuq basin the Cambrian-Ordovician has the best production capability. However, substantial reserves need to be established before developing any field in this basin. Large areas still remain unexplored in western Libya.

  8. Aux Vases Sandstone diagenesis: Implications for hydrocarbon recovery from southern Illinois reservoirs

    SciTech Connect (OSTI)

    Seyler, B.D.; Beaty, D.S.; Huff, B.G. (Illinois State Geological Survey, Champaign (United States))

    1991-03-01T23:59:59.000Z

    The Aux Vases Sandstone (Mississippian) is a problematic yet productive reservoir in the Illinois basin. The Aux Vases Formation was deposited in a mixed siliciclastic-carbonate offshore environment. Hydrocarbon reservoirs are dominantly elongate sandstone bodies interpreted as subtidal facies within a prograding tidally influenced deposystem. Oil saturated zones, in most cases, are composed of fine-grained, cross-bedded, friable, feldspathic quartz sandstone. Resistivity logs, even from productive wells, are typically characterized by unusually low resistivities (2-4 ohms) that lead to high calculated water saturations. X-ray diffraction, SEM/EDS, and thin section studies were used to analyze diagenetic processes that may affect hydrocarbon production in several Aux Vases reservoirs. Diagenetic processes common to the field studied include: (1) early calcite cementation occluding primary porosity and inhibiting compaction, (2) dissolution of feldspar grains to form authigenic clay, (3) dissolution of early calcite cement, (4) diagenesis of detrital clay minerals into new authigenic clay minerals, and (5) multiple stages of quartz overgrowths that reduce porosity. Commonly used drilling and completion practices may adversely affect reservoir quality by reacting with diagenetic products. Loosening of the fine mineral fraction that causes migration of fines and swelling of expandable clay minerals are examples of this type of damage. Knowledge of reservoir mineralogy and diagenesis may influence drilling and completion practices and affect selection of secondary and tertiary recovery methods.

  9. Cusiana trend exploration, Llanos Foothills thrustbelt, Colombia: The opening of a new hydrocarbon province

    SciTech Connect (OSTI)

    O'Leary, J.; Hayward, T.; Addison, F. (BP Exploration, Bogota (Colombia)); Espinosa, G. (Ecopetrol, Bogota (Colombia))

    1996-01-01T23:59:59.000Z

    The Llanos Foothills petroleum trend of the Eastern Cordillera in Colombia containing the giant Cusiana Field has proven to be one of the most exciting hydrocarbon provinces discovered in recent years. The Llanos Foothills trend is a fold and thrust belt with cumulative discovered reserves to date of nearly 6 billion barrels of oil equivalent. This paper summarizes the critical exploration techniques used in unlocking the potential of this major petroleum system. The first phase of exploration in the Llanos Foothills lasted from the early 1960's to the mid-70's. Several large structures defined by surface geology and seismic data were drilled. Although no major discoveries were made, evidence of a petroleum play was found. The seismic imaging and drilling technology combined with the geological understanding which was then available did not allow the full potential of the trend to be realized. In the late 1980's better data and a revised geological perception of the trend led BP, Triton and Total into active exploration, which resulted in the discovery of the Cusiana Field. The subsequent discovery of the Cupiagua, Volcanera, Florena and Pauto Sur Fields confirmed the trend as a major hydrocarbon province. The exploration programme has used a series of geological and geophysical practices and techniques which have allowed the successful exploitation of the trend. The critical success factor has been the correct application of technology in seismic acquisition and recessing and drilling techniques.

  10. Conversion of associated natural gas to liquid hydrocarbons. Final report, June 1, 1995--January 31, 1997

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The original concept envisioned for the use of Fischer-Tropsch processing (FTP) of United States associated natural gas in this study was to provide a way of utilizing gas which could not be brought to market because a pipeline was not available or for which there was no local use. Conversion of gas by FTP could provide a means of utilizing offshore associated gas which would not require installation of a pipeline or re-injection. The premium quality F-T hydrocarbons produced by conversion of the gas can be transported in the same way as the crude oil or in combination (blended) with it, eliminating the need for a separate gas transport system. FTP will produce a synthetic crude oil, thus increasing the effective size of the resource. The two conventional approaches currently used in US territory for handling of natural gas associated with crude petroleum production are re-injection and pipelining. Conversion of natural gas to a liquid product which can be transported to shore by tanker can be accomplished by FTP to produce hydrocarbons, or by conversion to chemical products such as methanol or ammonia, or by cryogenic liquefaction (LNG). This study considers FTP and briefly compares it to methanol and LNG. The Energy International Corporation cobalt catalyst, ratio adjusted, slurry bubble column F-T process was used as the basis for the study and the comparisons. An offshore F-T plant can best be accommodated by an FPSO (Floating Production, Storage, Offloading vessel) based on a converted surplus tanker, such as have been frequently used around the world recently. Other structure types used in deep water (platforms) are more expensive and cannot handle the required load.

  11. Deconvolution and Quantification of Hydrocarbon-like and Oxygenated

    E-Print Network [OSTI]

    Zhang, Qi

    , lubricating oil, and freshly emitted traffic aerosols observed in urban areas, while the spectrum of OOA

  12. Wrenching and oil migration, Mervine field, Kay County, Oklahoma

    SciTech Connect (OSTI)

    Davis, H.G.

    1985-02-01T23:59:59.000Z

    Since 1913, Mervine field (T27N, R3E) has produced oil from 11 Mississippian and Pennsylvanian zones, and gas from 2 Permian zones. The field exhibits an impressive asymmetric surface anticline, with the steeper flank dipping 30/sup 0/E maximum. A nearly vertical, basement-involved fault develops immediately beneath the steeper flank of the surface anticline. Three periods of left-lateral wrench faulting account for 93% of all structural growth: 24% in post-Mississippian-pre-Desmoinesian time, 21% in Virgilian time, and 48% in post-Wolfcampian time. In Mesozoic through early Cenozoic times, the Devonian Woodford Shale (and possibly the Desmoinesian Cherokee shales) locally generated oil, which should have been structurally trapped in the Ordovician Bromide sandstone. This oil may have joined oil already trapped in the Bromide, which had migrated to the Mervine area in the Early Pennsylvanian from a distant source. Intense post-Wolfcampian movement(s) fractured the competent pre-Pennsylvanian rocks, allowing Bromide brine and entrained oil to migrate vertically up the master fault, finally accumulating in younger reservoirs. Pressure, temperature, and salinity anomalies attest to vertical fluid migration continuing at the present time at Mervine field. Consequently, pressure, temperature, and salinity mapping should be considered as valuable supplements to structural and lithologic mapping when prospecting for structural hydrocarbon accumulations in epicratonic provinces.

  13. Millimeter wave analysis of the dielectric properties of oil shales

    E-Print Network [OSTI]

    John A. Scales; Michael Batzle

    2006-06-06T23:59:59.000Z

    Natural sedimentation processes give rise to fine layers in shales. If these layers alternate between organic-rich and organic-poor sediments, then the contrast in dielectric properties gives rise to an effective birefringence as the presence of hydrocarbons suppresses the dielectric constant of the host rock. We have measured these effects with a quasioptical millimeter wave setup that is rapid and noncontacting. We find that the strength of this birefringence and the overall dielectric permittivity provide two useful diagnostic of the organic content of oil shales.

  14. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1985-04-16T23:59:59.000Z

    A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

  15. Pyrochlore catalysts for hydrocarbon fuel reforming

    DOE Patents [OSTI]

    Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

    2012-08-14T23:59:59.000Z

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

  16. Metagenomic analysis of microbial consortium from natural crude oil that seeps into the marine ecosystem offshore Southern California

    SciTech Connect (OSTI)

    Hawley, Erik R.; Piao, Hailan; Scott, Nicole M.; Malfatti, Stephanie; Pagani, Ioanna; Huntemann, Marcel; Chen, Amy; del Rio, Tijana G.; Foster, Brian; Copeland, A.; Jansson, Janet K.; Pati, Amrita; Gilbert, Jack A.; Tringe, Susannah G.; Lorenson, Thomas D.; Hess, Matthias

    2014-01-02T23:59:59.000Z

    Crude oils can be major contaminants of the marine ecosystem and microorganisms play a significant role in the degradation of the main constituents of crude oil. To increase our understanding of the microbial hydrocarbon degradation process in the marine ecosystem, we collected crude oil from an active seep area located in the Santa Barbara Channel (SBC) and generated a total of about 52 Gb of raw metagenomic sequence data. The assembled data comprised ~500 Mb, representing ~1.1 million genes derived primarily from chemolithoautotrophic bacteria. Members of Oceanospirillales, a bacterial order belonging to the Deltaproteobacteria, recruited less than 2% of the assembled genes within the SBC metagenome. In contrast, the microbial community associated with the oil plume that developed in the aftermath of the Deepwater Horizon (DWH) blowout in 2010, was dominated by Oceanospirillales, which comprised more than 60% of the metagenomic data generated from the DWH oil plume. This suggests that Oceanospirillales might play a less significant role in the microbially mediated hydrocarbon conversion within the SBC seep oil compared to the DWH plume oil. We hypothesize that this difference results from the SBC oil seep being mostly anaerobic, while the DWH oil plume is aerobic. Within the Archaea, the phylum Euryarchaeota, recruited more than 95% of the assembled archaeal sequences from the SBC oil seep metagenome, with more than 50% of the sequences assigned to members of the orders Methanomicrobiales and Methanosarcinales. These orders contain organisms capable of anaerobic methanogenesis and methane oxidation (AOM) and we hypothesize that these orders and their metabolic capabilities may be fundamental to the ecology of the SBC oil seep.

  17. Use of bitumen reflectance in hydrocarbon exploration

    SciTech Connect (OSTI)

    Goodarzi, F.; Gentzis, T. (Geological Survey of Canada, Calgary, Alberta)

    1989-09-01T23:59:59.000Z

    Bitumen is a sensitive indicator of the thermal maturity of sedimentary rocks, particularly in carbonates and lower Paleozoic, where vitrinite is scarce. The optical properties of bitumen (at 546 nm) follow trends similar to those of vitrinite with increasing maturity. However, the following differences exist: (1) bitumen has lower reflectance than vitrinite up to the onset of oil generation, as determined by vitrinite reflectance; (2) reflectance of bitumen follows a higher trend than that of vitrinite at an R{sub 0} level of 1.0% (peak of oil generation). Bitumen reflectance can be converted to vitrinite reflectance using Jacob's formula. In lower Paleozoic rocks (Ordovician and older) bitumen can be used as a thermal indicator for determining the level of maturity with increasing burial depth. There are, however, complexities in the above application because of differentiation between reservoir-migrated and primary bitumen.

  18. World Oil: Market or Mayhem?

    E-Print Network [OSTI]

    Smith, James L.

    2008-01-01T23:59:59.000Z

    The world oil market is regarded by many as a puzzle. Why are oil prices so volatile? What is OPEC and what does OPEC do? Where are oil prices headed in the long run? Is “peak oil” a genuine concern? Why did oil prices ...

  19. Near Shore Submerged Oil Assessment

    E-Print Network [OSTI]

    Near Shore Submerged Oil Assessment September 2010 In the context of the BP Deepwater Horizon (DWH) oil spill in the Gulf of Mexico, submerged oil refers to near shore oil which has picked up sediments from very different physical and chemical processes. In this spill, the oil was released more than 5

  20. Oil spill response resources

    E-Print Network [OSTI]

    Muthukrishnan, Shankar

    1996-01-01T23:59:59.000Z

    and development program. Title VIII concerns the amendments to the Trans Alaska Pipeline System Act. Title I deals with probably the most important part of OPA-90 ? liability and compensation. Claim procedures, federal authority, financial responsibility... minimum. LITERATURE REVIEW From the time that oil was discovered, drilled and transported, oil spills have been occurring. As long as crude oils and petroleum products are transported across the seas by ships or pipelines, there is the risk of spillage...

  1. Non-Sticking of Helium Buffer Gas to Hydrocarbons

    E-Print Network [OSTI]

    Croft, James F E

    2014-01-01T23:59:59.000Z

    Lifetimes of complexes formed during helium-hydrocarbon collisions at low temperature are estimated for symmetric top hydrocarbons. The lifetimes are obtained using a density-of-states approach. In general the lifetimes are less than 10-100 ns, and are found to decrease with increasing hydrocarbon size. This suggests that clustering will not limit precision spectroscopy in helium buffer gas experiments. Lifetimes are computed for noble-gas benzene collisions and are found to be in reasonable agreement with lifetimes obtained from classical trajectories as reported by Cui {\\it et al}.

  2. Using comprehensive two-dimensional gas chromatography to explore the geochemistry of the Santa Barbara oil seeps

    SciTech Connect (OSTI)

    Reddy, Christopher; Nelson, Robert

    2013-03-27T23:59:59.000Z

    The development of comprehensive two-dimensional gas chromatography (GC x GC) has expanded the analytical window for studying complex mixtures like oil. Compared to traditional gas chromatography, this technology separates and resolves at least an order of magnitude more compounds, has a much larger signal to noise ratio, and sorts compounds based on their chemical class; hence, providing highly refined inventories of petroleum hydrocarbons in geochemical samples that was previously unattainable. In addition to the increased resolution afforded by GC x GC, the resulting chromatograms have been used to estimate the liquid vapor pressures, aqueous solubilities, octanol-water partition coefficients, and vaporization enthalpies of petroleum hydrocarbons. With these relationships, powerful and incisive analyses of phase-transfer processes affecting petroleum hydrocarbon mixtures in the environment are available. For example, GC x GC retention data has been used to quantitatively deconvolve the effects of phase transfer processes such as water washing and evaporation. In short, the positive attributes of GC x GC-analysis have led to a methodology that has revolutionized the analysis of petroleum hydrocarbons. Overall, this research has opened numerous fields of study on the biogeochemical "?genetics"ť (referred to as petroleomics) of petroleum samples in both subsurface and surface environments. Furthermore, these new findings have already been applied to the behavior of oil at other seeps as well, for petroleum exploration and oil spill studies.

  3. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01T23:59:59.000Z

    disruptions, and the peak in U.S. oil production account foroil increased 81.1% (logarithmically) between January 1979 and the peak

  4. Oil and Gas (Indiana)

    Broader source: Energy.gov [DOE]

    This division of the Indiana Department of Natural Resources provides information on the regulation of oil and gas exploration, wells and well spacings, drilling, plugging and abandonment, and...

  5. NETL: Oil & Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that address the unique nature and challenging locations of many of our remaining oil and natural gas accumulations. The National Energy Technology Laboratory's (NETL)...

  6. New insights into microbial responses to oil spills from the Deepwater Horizon incident

    SciTech Connect (OSTI)

    Mason, O.U.; Hazen, T.C.

    2011-06-15T23:59:59.000Z

    On April 20, 2010, a catastrophic eruption of methane caused the Deepwater Horizon exploratory drill rig drilling the Macondo Well in Mississippi Canyon Block 252 (MC252) to explode. The Deepwater Horizon oil spill was unprecendeted for several reasons: the volume of oil released; the spill duration; the well depth; the distance from the shore-line (77 km or about 50 miles); the type of oil (light crude); and the injection of dispersant directly at the wellhead. This study clearly demonstrated that there was a profound and significant response by certain members of the in situ microbial community in the deep-sea in the Gulf of Mexico. In particular putative hydrocarbon degrading Bacteria appeared to bloom in response to the Deepwater Horizon oil spill, even though the temperature at these depths is never >5 C. As the plume aged the shifts in the microbial community on a temporal scale suggested that different, yet metabolically important members of the community were able to respond to a myriad of plume constituents, e.g. shifting from propane/ethane to alkanes and finally to methane. Thus, the biodegradation of hydrocarbons in the plume by Bacteria was a highly significant process in the natural attenuation of many compounds released during the Deepwater Horizon oil spill.

  7. A Feasibility Study for Recycling Used Automotive Oil Filters In A Blast Furnace

    SciTech Connect (OSTI)

    Ralph M. Smailer; Gregory L. Dressel; Jennifer Hsu Hill

    2002-01-21T23:59:59.000Z

    This feasibility study has indicated that of the approximately 120,000 tons of steel available to be recycled from used oil filters (UOF's), a maximum blast furnace charge of 2% of the burden may be anticipated for short term use of a few months. The oil contained in the most readily processed UOF's being properly hot drained and crushed is approximately 12% to 14% by weight. This oil will be pyrolized at a rate of 98% resulting in additional fuel gas of 68% and a condensable hydrocarbon fraction of 30%, with the remaining 2% resulting as carbon being added into the burden. Based upon the writer's collected information and assessment, there appears to be no operational problems relating to the recycling of UOF's to the blast furnace. One steel plant in the US has been routinely charging UOF's at about 100 tons to 200 tons per month for many years. Extensive analysis and calculations appear to indicate no toxic consideration as a result of the pyrolysis of the small contained oil ( in the 'prepared' UOFs) within the blast furnace. However, a hydrocarbon condensate in the ''gasoline'' fraction will condense in the blast furnace scrubber water and may require additional processing the water treatment system to remove benzene and toluene from the condensate. Used oil filters represent an additional source of high quality iron units that may be effectively added to the charge of a blast furnace for beneficial value to the operator and to the removal of this resource from landfills.

  8. Molecular and Biochemical Characterization of Hydrocarbon Production in the Green Microalga Botryococcus braunii

    E-Print Network [OSTI]

    Weiss, Taylor Leigh

    2012-10-19T23:59:59.000Z

    Algae biofuels ................................................................................ 1 Algae .............................................................................................. 2 Botryococcus braunii... ..................................................................... 4 General biology ........................................................................ 4 Biofuel potential ....................................................................... 9 Hydrocarbon synthesis...

  9. Hydrocarbons on Harvester Ant (Pogonomyrmex barbatus) Middens Guide Foragers to the Nest

    E-Print Network [OSTI]

    Gordon, Deborah

    Hydrocarbons on Harvester Ant (Pogonomyrmex barbatus) Middens Guide Foragers to the Nest Shelby J hydrocarbons are used by social insects in nestmate recognition. Here, we showed that hydrocarbons found-specific hydrocarbons, which ants use to distinguish nestmates from non-nestmates, are found on the midden pebbles

  10. Biocorrosive Thermophilic Microbial Communities in Alaskan North Slope Oil Facilities

    SciTech Connect (OSTI)

    Duncan, Kathleen E.; Gieg, Lisa M.; Parisi, Victoria A.; Tanner, Ralph S.; Green Tringe, Susannah; Bristow, Jim; Suflita, Joseph M.

    2009-09-16T23:59:59.000Z

    Corrosion of metallic oilfield pipelines by microorganisms is a costly but poorly understood phenomenon, with standard treatment methods targeting mesophilic sulfatereducing bacteria. In assessing biocorrosion potential at an Alaskan North Slope oil field, we identified thermophilic hydrogen-using methanogens, syntrophic bacteria, peptideand amino acid-fermenting bacteria, iron reducers, sulfur/thiosulfate-reducing bacteria and sulfate-reducing archaea. These microbes can stimulate metal corrosion through production of organic acids, CO2, sulfur species, and via hydrogen oxidation and iron reduction, implicating many more types of organisms than are currently targeted. Micromolar quantities of putative anaerobic metabolites of C1-C4 n-alkanes in pipeline fluids were detected, implying that these low molecular weight hydrocarbons, routinely injected into reservoirs for oil recovery purposes, are biodegraded and provide biocorrosive microbial communities with an important source of nutrients.

  11. Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation

    SciTech Connect (OSTI)

    Garg, D.

    1986-08-19T23:59:59.000Z

    A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

  12. Major Oil Plays in Utah and Vicinity

    SciTech Connect (OSTI)

    Thomas C. Chidsey; Craig D. Morgan; Kevin McClure; Douglas A. Sprinkel; Roger L. Bon; Hellmut H. Doelling

    2003-12-31T23:59:59.000Z

    Utah oil fields have produced over 1.2 billion barrels (191 million m{sup 3}). However, the 13.7 million barrels (2.2 million m{sup 3}) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil-producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; locations of major oil pipelines; identification and discussion of land-use constraints; descriptions of reservoir outcrop analogs; and summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play. This report covers research activities for the sixth quarter of the project (October 1 through December 31, 2003). This work included describing outcrop analogs for the Jurassic Twin Creek Limestone and Mississippian Leadville Limestone, major oil producers in the thrust belt and Paradox Basin, respectively, and analyzing best practices used in the southern Green River Formation play of the Uinta Basin. Production-scale outcrop analogs provide an excellent view of reservoir petrophysics, facies characteristics, and boundaries contributing to the overall heterogeneity of reservoir rocks. They can be used as a ''template'' for evaluation of data from conventional core, geophysical and petrophysical logs, and seismic surveys. In the Utah/Wyoming thrust belt province, the Jurassic Twin Creek Limestone produces from subsidiary closures along major ramp anticlines where the low-porosity limestone beds are extensively fractured and sealed by overlying argillaceous and non-fractured units. The best outcrop analogs for Twin Creek reservoirs are found at Devils Slide and near the town of Peoa, Utah, where fractures in dense, homogeneous non-porous limestone beds are in contact with the basal siltstone units (containing sealed fractures) of the overlying units. The shallow marine, Mississippian Leadville Limestone is a major oil and gas reservoir in the Paradox Basin of Utah and Colorado. Hydrocarbons are produced from basement-involved, northwest-trending structural traps with closure on both anticlines and faults. Excellent outcrops of Leadville-equivalent rocks are found along the south flank of the Uinta Mountains, Utah. For example, like the Leadville, the Mississippian Madison Limestone contains zones of solution breccia, fractures, and facies variations. When combined with subsurface geological and production data, these outcrop analogs can improve (1) development drilling and production strategies such as horizontal drilling, (2) reservoir-simulation models, (3) reserve calculations, and (4) design and implementation of secondary/tertiary oil recovery programs and other best practices used in the oil fields of Utah and vicinity. In the southern Green River Formation play of the Uinta Basin, optimal drilling, development, and production practices consist of: (1) owning drilling rigs and frac holding tanks; (2) perforating sandstone beds with more than 8 percent neutron porosity and stimulate with separate fracture treatments; (3) placing completed wells on primary production using artificial lift; (4) converting wells relatively soon to secondary waterflooding maintaining reservoir pressure above the bubble point to maximize oil recovery; (5) developing waterflood units using an alternating injector--producer pattern on 40-acre (16-ha) spacing; and (6) recompleting producing wells by perforating all beds that are productive in the waterflood unit. As part of technology transfer activities during this quarter, an abstract describing outcrop reservoir analogs was accepted by the American Assoc

  13. Leaching of BTEX from Aged Crude Oil Contaminated Model Soils: Experimental and Modeling Results

    SciTech Connect (OSTI)

    Huesemann, Michael H.; Hausmann, Tom S.; Fortman, Timothy J.

    2005-01-01T23:59:59.000Z

    It is generally assumed that soil properties such as organic matter content, porosity, and mineral surface area have a significant effect on the bioavailability and leachability of aged petroleum hydrocarbons. In order to test this hypothesis, nine model soils or sorbents (i.e., fine and coarse quartz sand, montmorillonite and kaolinite clay, peat, 60? and 150? silica gel, a loam soil, and non-porous glass beads) were spiked with a crude oil, aged for 27 months in the laboratory, and transferred to glass columns for the performance of continuous flow leaching experiments. The column effluents were periodically sampled for 43 days and analyzed for BTEX. A one-dimensional flow model for predicting the dissolution and dispersion of individual hydrocarbons from a multi-component NAPL such as crude oil was used to fit the leaching data (i.e., the BTEX concentration versus time curves) by adjusting the equilibrium oil-leachate partitioning coefficient (Kol) for each respective hydrocarbon. The Peclet number, which is a measure of dispersion and a required modeling parameter, was measured in separate chloride tracer experiments for each soil column. Results demonstrate that soil properties did not significantly affect the leaching kinetics of BTEX from the columns. Instead, BTEX leaching curves could be successfully fitted with the one-dimensional NAPL dissolution flow model for all sorbents with the exception of montmorillonite clay. The fitting parameter Kol for each hydrocarbon was found to be similar to the Kol values that were independently measured for the same crude oil by Rixey et al. (Journal of Hazardous Materials B, 65: 137-156, 1999). In addition, the fitted Kol values were very similar for BTEX leaching from aged compared to freshly spiked loam soil. These findings indicate that leaching of BTEX in the aged soils that are contaminated with crude oil at the high concentrations commonly found in the environment (i.e., >20,000 mg/kg) was not affected by soil properties or aging but rather was governed by the equilibrium dissolution of these hydrocarbons from the crude oil NAPL that is coating the soil particles.

  14. H{sub 2}-rich and Hydrocarbon Gas Recovered in a Deep Precambrian Well in Northeastern Kansas

    SciTech Connect (OSTI)

    Newell, K. David, E-mail: dnewell@kgs.ku.edu; Doveton, John H.; Merriam, Daniel F. [University of Kansas, Kansas Geological Survey (United States); Lollar, Barbara Sherwood [University of Toronto, Department of Geology (Canada)], E-mail: bslollar@chem.utoronto.ca; Waggoner, William M. [WTW Oil Co., Inc. (United States)], E-mail: bill@wtwoil.com; Magnuson, L. Michael [University of Kansas, Kansas Geological Survey (United States)

    2007-09-15T23:59:59.000Z

    In late 2005 and early 2006, the WTW Operating, LLC (W.T.W. Oil Co., Inc.) no. 1 Wilson well (T.D. = 5772 ft; 1759.3 m) was drilled for 1826 ft (556.6 m) into Precambrian basement underlying the Forest City Basin in northeastern Kansas. Approximately 4500 of the 380,000 wells drilled in Kansas penetrate Precambrian basement. Except for two previous wells drilled into the arkoses and basalts of the 1.1-Ga Midcontinent Rift and another well drilled in 1929 in basement on the Nemaha Uplift east of the Midcontinent Rift, this well represents the deepest penetration into basement rocks in the state to date. Granite is the typical lithology observed in wells that penetrate the Precambrian in the northern Midcontinent. Although no cores were taken to definitively identify lithologies, well cuttings and petrophysical logs indicate that this well encountered basement metamorphic rocks consisting of schist, gneiss, and amphibolitic gneiss, all cut by aplite dikes.The well was cased and perforated in the Precambrian, and then acidized. After several days of swabbing operations, the well produced shows of low-Btu gas, dominated by the non-flammable component gases of nitrogen (20%), carbon dioxide (43%), and helium (1%). Combustible components include methane (26%), hydrogen (10%), and higher molecular-weight hydrocarbons (1%). Although Coveney and others [Am. Assoc. Petroleum Geologists Bull., v. 71, no, 1, p. 39-48, 1987] identified H{sub 2}-rich gas in two wells located close to the Midcontinent Rift in eastern Kansas, this study indicates that high levels of H{sub 2} may be a more widespread phenomenon than previously thought. Unlike previous results, the gases in this study have a significant component of hydrocarbon gas, as well as H{sub 2}, N{sub 2}, and CO{sub 2}. Although redox reactions between iron-bearing minerals and groundwater are a possible source of H{sub 2} in the Precambrian basement rocks, the hydrocarbon gas does not exhibit the characteristics typically associated with proposed abiogenic hydrocarbon gases from Precambrian Shield sites in Canada, Finland, and South Africa. Compositional and isotopic signatures for gas from the no. 1 Wilson well are consistent with a predominantly thermogenic origin, with possible mixing with a component of microbial gas. Given the geologic history of uplift and rifting this region, and the major fracture systems present in the basement, this hydrocarbon gas likely migrated from source rocks and reservoirs in the overlying Paleozoic sediments and is not evidence for abiogenic hydrocarbons generated in situ in the Precambrian basement.

  15. THE WASTE OIL INFLUENCE AND RISKS ON ENVIRONMENT IN REFER TO BOSNIA AND HERZEGOVINA

    E-Print Network [OSTI]

    Rajfa Musemi?; Azra Baši?

    The main impurities usually present in used oil are various organic acid, polymer residua, metal particles arisen by wear and tear parts of lubricated equipment like: lead, chromium, nickel, cadmium, aluminum, polycyclic aromatic hydrocarbons (PAH), mercaptans, various halogenated compounds, soot, sand, dust and microbes. In addition, but with less frequency, waste oils may contain high-harmful polychlorinated biphenyls (PCBs), polychlorinated terphenyls (PCT) or polybrominated biphenyls (PBB). Waste oil can have a number of significant, short-term and long-term impacts on the environment if they are treated or managed in an uncontrolled manner. Oil prevents the penetration of oxygen into the water, thereby makes violation the conditions of life of many species. Taking into account that Bosnia and Herzegovina interspersed with a large number of surface and groundwater, and paying attention to the fact that water contains only 1-2 mg per liter of lubricating oils are not suitable for drinking, it is obvious that the risks short-and long-term impact for the entire huge living world are present. An existing initial database of oil distributors, importers, manufacturers and users in Bosnia and Herzegovina has been analyzed, on the base of the lubricants related practice waste oil generation. Key words: waste oil, risks, environmental impact assessment, PCBs.

  16. Naval Petroleum and Oil Shale Reserves. Annual report of operations, Fiscal year 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    During fiscal year 1993, the reserves generated $440 million in revenues, a $33 million decrease from the fiscal year 1992 revenues, primarily due to significant decreases in oil and natural gas prices. Total costs were $207 million, resulting in net cash flow of $233 million, compared with $273 million in fiscal year 1992. From 1976 through fiscal year 1993, the Naval Petroleum and Oil Shale Reserves generated $15.7 billion in revenues for the US Treasury, with expenses of $2.9 billion. The net revenues of $12.8 billion represent a return on costs of 441 percent. See figures 2, 3, and 4. In fiscal year 1993, production at the Naval Petroleum and Oil Shale Reserves at maximum efficient rates yielded 25 million barrels of crude oil, 123 billion cubic feet of natural gas, and 158 million gallons of natural gas liquids. The Naval Petroleum and Oil Shale Reserves has embarked on an effort to identify additional hydrocarbon resources on the reserves for future production. In 1993, in cooperation with the US Geological Survey, the Department initiated a project to assess the oil and gas potential of the program`s oil shale reserves, which remain largely unexplored. These reserves, which total a land area of more than 145,000 acres and are located in Colorado and Utah, are favorably situated in oil and gas producing regions and are likely to contain significant hydrocarbon deposits. Alternatively the producing assets may be sold or leased if that will produce the most value. This task will continue through the first quarter of fiscal year 1994.

  17. Source rock evaluation, oil-source rock correlation, and kinetic modeling - San Juan Sag, CO

    SciTech Connect (OSTI)

    Clayton, J.L. (Geological survey, Denver, CO (USA)); Gries, R.R.

    1990-05-01T23:59:59.000Z

    Recently, oil and gas shows have been reported in Cretaceous and Tertiary rocks of the San Juan sag, and minor oil production was established from volcanic rocks (Kirby Petroleum 1 Jynnifer well, Sec. 9, T40N, R5E.). Potential source rocks present in the San Juan sag are the upper and lower (including the Niobrara Member) Mancos Shale (Upper Cretaceous). The combined upper and lower Mancos Shale is about 666 m thick and contains between about 0.5 and 5.5% organic carbon, although most values are between about 1.5 and 2.0%. The Niobrara Member of the lower Mancos Shale has the highest overall organic matter content in the section (organic carbon averages <2.0%). Pyrolysis and solvent extraction data (typically 2,000-6,000 and 1,000-4,000 ppm, respectively) indicate that the upper and lower Mancos Shale and the Niobrara Member are all good potential source rocks for oil and gas. Oil-source rock correlations using gas chromatography, mass spectrometry, and stable carbon isotope ratios indicate that the upper Mancos Shale is the most likely source for the oil produced from the 1 Jynnifer discovery well. The source of the oil produced from the nearby Gramps field is less certain, but may be the lower Mancos Shale or Niobrara Member. The hydrocarbon generation history of the San Juan sag is complex because of highly variable heat flow in the area caused by Oligocene volcanism. Sills have caused thermal alteration of organic matter in shales on a local scale, and larger volcanic bodies may have produced proportionality larger thermal effects. More regional heating by larger volcanic bodies is an important factor in the oil generation history of the area. The authors have constructed kinetic models at several locations in the area to estimate the timing and amount of hydrocarbon products generated from the source rocks. The main phase of oil and gas generation and expulsion occurred during the Oligocene.

  18. Urethane coatings rehabilitate large crude oil pipeline

    SciTech Connect (OSTI)

    Kresic, W. [Interprovincial Pipe Line Inc., Edmonton, Alberta (Canada)

    1995-10-01T23:59:59.000Z

    Interprovincial Pipe Line Inc. (IPL) provides a vital transportation link for moving liquid petroleum resources from oil-producing areas of western Canada to refining centers and markets in eastern canada and the midwestern US. Together with Lakehead Pipe Line Co., Inc., the pipeline system consists of about 7,600 miles of pipe. Approximately 1.6 million bpd of crude oil and liquid hydrocarbons are transported by the system. Along with high-resolution inspection data, an in-house engineering critical assessment process based on Battelle`s NG-18 surface flaw equation was developed to identify corrosion anomalies needing structural reinforcement sleeve repairs. A majority of ht non-critical anomalies remained unearthed and were exposed to possible future growth which could become critical. Several rehabilitation methods were considered including on-going sleeve repair, selective pipe replacement, and coating reconditioning. Economics and logistics of sleeving programs and selective pipe replacement were well known at IPL. However, aspects of replacing a coating system over a relatively long length of pipe were not completely known. Preliminary cost estimates favored replacement of the coating over a massive sleeving program or pipe replacement. To gain further insight, IPL began a two-year pilot program to research long length coating replacement feasibility. Two sections of Line 3 ultimately were rehabilitated in this manner. This paper reviews the project.

  19. Carbometallic oil conversion with ballistic separation

    SciTech Connect (OSTI)

    Walters, P.W.; Benslay, R.M.; Barger, D.F.

    1991-09-03T23:59:59.000Z

    This patent describes improvement in a method for converting carbo-metallic containing residual oils to form upgraded liquid products by mixing. The improvement comprises: discharging the suspension from the reaction zone at a velocity of 55 to 100 ft/sec. imparting greater momentum to the solid particles than to the hydrocarbon product vapors whereby instantaneous separation of at least about 80 wt % of the vapors from the solid particles occurs; encouraging separation of solids from remaining vapors following discharge from the reaction zone by diverting solids from the remaining vapors by directional impingement on a target baffle and by providing a lower pressure vapor recovery zone in open communication with one or more cyclone separation zones outside the reaction zone open end; recovering solid particles separated by momentum from the suspension and diverted laterally from the vapor recovery zone as a mass of collected solid particles; stripping and regenerating the collected the particles in a sequence of separate zones; and recycling hot regenerated solids to the reaction zone for contact with the residual oil feed.

  20. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01T23:59:59.000Z

    reserves. In the data, crude oil reserve addi- tions consistForce and Proven Reserves in the Venezuelan Oil Industry .such as crude oil production, proved reserves, new reserves,

  1. Oil and Gas Production (Missouri)

    Broader source: Energy.gov [DOE]

    A State Oil and Gas Council regulates and oversees oil and gas production in Missouri, and conducts a biennial review of relevant rules and regulations. The waste of oil and gas is prohibited. This...

  2. The Legacy of Oil Spills

    E-Print Network [OSTI]

    Trevors, J. T.; Saier, M. H.

    2010-01-01T23:59:59.000Z

    010-0527-5 The Legacy of Oil Spills J. T. Trevors & M. H.workers were killed, and oil has been gushing out everday. It is now June, and oil continues to spew forth into

  3. Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

    DOE Patents [OSTI]

    Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

    1999-01-01T23:59:59.000Z

    This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

  4. Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

    DOE Patents [OSTI]

    Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

    1999-05-25T23:59:59.000Z

    This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

  5. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01T23:59:59.000Z

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  6. aromatic hydrocarbon emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Detection of mid-infrared Aromatic Hydrocarbon Emission Features from the Small Magellanic Cloud Astrophysics...

  7. aromatic hydrocarbon cations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 NEAR-INFRARED SPECTROSCOPY OF NITROGENATED POLYCYCLIC AROMATIC HYDROCARBON CATIONS FROM 0.7 TO 2.5...

  8. aromatic hydrocarbon emission: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Detection of mid-infrared Aromatic Hydrocarbon Emission Features from the Small Magellanic Cloud Astrophysics...

  9. Process for conversion of lignin to reformulated hydrocarbon gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    1999-09-28T23:59:59.000Z

    A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

  10. Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels

    E-Print Network [OSTI]

    Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

  11. Whole Ecosystem Measurements of Biogenic Hydrocarbon Emissions Final Report

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Whole Ecosystem Measurements of Biogenic Hydrocarbon Emissions Final Report ARB Award No. 98 of Environmental Science, Policy, and Management Ecosystem Sciences Division 151 Hilgard Hall University Department of Environmental Science, Policy, and Mangement Ecosystem Sciences Division 151 Hilgard Hall

  12. Subcontinuum mass transport of condensed hydrocarbons in nanoporous media

    E-Print Network [OSTI]

    Falk, Kerstin

    Although hydrocarbon production from unconventional reservoirs, the so-called shale gas, has exploded recently, reliable predictions of resource availability and extraction are missing because conventional tools fail to ...

  13. Petroleum hydrocarbon pollution of urban topsoil in Ibadan city, Nigeria

    SciTech Connect (OSTI)

    Onianwa, P.C. [Univ. of Ibadan (Nigeria)] [Univ. of Ibadan (Nigeria)

    1995-08-01T23:59:59.000Z

    The distribution of total petroleum hydrocarbon in topsoils from various parts of Ibadan city, Nigeria, was studied. Samples were selected from around the following zones: (a) railway tracks, (b) petrol stations, (c) refuse dumps, (d) residential areas, (e) high traffic density areas, (f) mechanical workshops, and (g) control zones. Contamination of the topsoil with hydrocarbons was significant only around petrol stations and mechanical workshops where the factors of accumulation were 10.1 and 4.72, respectively. The general trend in hydrocarbon levels was petrol station > mechanical workshop > refuse dumps > high traffic areas {ge} rail tracks > control residential areas. The results highlight the need to monitor urban environments that are remote from petroleum exploration activities for petroleum hydrocarbon contamination. 19 refs., 3 tabs.

  14. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Laboratory U.S. Department of Energy Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Ken Rapp, Liyu Li, Jonathan Male, Dave King...

  15. Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures

    E-Print Network [OSTI]

    Desai, Anuradha M.

    2007-04-25T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

  16. Modeling the biodegradability and physicochemical properties of polycyclic aromatic hydrocarbons

    E-Print Network [OSTI]

    Dimitriou-Christidis, Petros

    2006-10-30T23:59:59.000Z

    The biodegradability and physicochemical properties of unsubstituted and methylated polycyclic aromatic hydrocarbons (PAHs) were investigated. The focus was on the development of models expressing the influence of molecular structure and properties...

  17. Faults as potential hydrocarbon barriers, Arroyo Grande, California

    E-Print Network [OSTI]

    Switek, Daniel Paul

    1994-01-01T23:59:59.000Z

    Faulting in a sandstone introduces properties which are different from the country rock. Previous work has shown that these new properties can significantly impede the flow of hydrocarbons through the country rock. This thesis seeks to analyze...

  18. Vertimass licenses ORNL biofuel-to-hydrocarbon conversion technology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    McCorkle Communications and Media Relations 865.574.7308 Vertimass licenses ORNL biofuel-to-hydrocarbon conversion technology Vertimass LLC, a California-based start-up...

  19. Conversion of methane and acetylene into gasoline range hydrocarbons 

    E-Print Network [OSTI]

    Alkhawaldeh, Ammar

    2000-01-01T23:59:59.000Z

    , indene, azulene, fluorene, and biphenyl substituted compounds. Also, lighter hydrocarbons, such as ethylene and isobutene were produced. The reaction was conducted at different operating temperatures and different molar feed composition. The results...

  20. Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures 

    E-Print Network [OSTI]

    Desai, Anuradha M.

    2007-04-25T23:59:59.000Z

    Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

  1. active natural hydrocarbon: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 MPa and 6 MPa have been performed on the hydrocarbon fuel pyrolysis to evaluate the coking Paris-Sud XI, Universit de 2 Assessment of natural and anthropogenic...

  2. Kinetics simulation for natural gas conversion to unsaturated C? hydrocarbons

    E-Print Network [OSTI]

    Yang, Li

    2003-01-01T23:59:59.000Z

    ) techniques are being studied to convert natural gas to useful hydrocarbon liquids, which can be transported with far less cost. Direct pyrolysis of methane, followed by catalytic reaction, is a promising technology that can be commercialized in industry...

  3. TABLE33.CHP:Corel VENTURA

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Imports of Crude Oil and Petroleum Products by PAD District, a Crude oil and unfinished oils are reported by the PAD District in which they are to be processed; all other products...

  4. TABLE34.CHP:Corel VENTURA

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    4. Year-to-Date Imports of Crude Oil and Petroleum Products by PAD District, a Crude oil and unfinished oils are reported by the PAD District in which they are to be processed; all...

  5. Petroleum hydrocarbon-degrading bacteria in the Galveston Bay system

    E-Print Network [OSTI]

    Schropp, Steven James

    1979-01-01T23:59:59.000Z

    of Department) (Membge' ) I, (Member) December, 1979 ABSTRACT Petroleum Hydrocarbon-Degrading Bacteria in the Galveston Bay System {December 1979) Steven James Schropp: B. S. , Texas A&M University Co-Chairmen of Advisory Committee: Dr. John R. Schwarz... about the distribution and abundance of petroleum hydrocarbon-degrad- ing bacteria in the Galveston Bay system. Several parts of the Galveston Bay system were sampled during this study. Petroleum input to the study area ranged from relatively small...

  6. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

    2010-02-02T23:59:59.000Z

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  7. Origin of gaseous hydrocarbons in east-central Texas groundwaters

    E-Print Network [OSTI]

    Coffman, Bryan Keith

    1988-01-01T23:59:59.000Z

    ; Follett, 1974). The high transmissivity and sandy lithology of the Sparta are much like those of the Queen City, as is the quality of water. 40 LIGNITE STREAKS 30 Laminated and discontinuous lenticular. Trough cross bedded siltstones. 20 ROAD l... hydrocarbons simply reflects a difference in the 5 C of the substrate. Sparta lignite is about 7%%do enriched in ' C relative to Yegua lignite, comparable to the difference seen in the gaseous hydrocarbons. ACKNOWLEDGMENTS I would like to thank Dr. Steven...

  8. Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments

    E-Print Network [OSTI]

    Sandberg, William Allan

    1986-01-01T23:59:59.000Z

    POLYCYCLIC AROMATIC HYDROCARBON DISTRIBUTIONS IN MISSISSIPPI FAN SEDIMENTS A Thesis by WILLIAM ALLAN SANDBERG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE December 1986 Major Subject: Oceanography POLYCYCLIC AROMATIC HYDROCARBON DISTRIBUTIONS IN MISSISSIPPI FAN SEDIMENTS A Thesis by WILLIAM ALLAN SANDBERG Approved as to style and content by: James M. Brooks (Chairman of Committee) Leis M...

  9. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Jones, S.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

  10. Air Chemistry in the Gulf of Mexico Oil Spill Area NOAA WP-3D Airborne Chemical Laboratory Flights of 8 and 10 June 2010

    E-Print Network [OSTI]

    Air Chemistry in the Gulf of Mexico Oil Spill Area NOAA WP-3D Airborne Chemical Laboratory Flights of Mexico near the spill site. At the time it was called on for this mission, the NOAA WP-3D aircraft and extensive survey of atmospheric loadings of hydrocarbon and other organic species air pollution in the Gulf

  11. 36 selected citations from Petroleum: An Annotated Bibliography on Petroleum Pollution Chabreck, R. H. 1973. Bird usage of marsh ponds subjected to oil spills. Proceedings of the

    E-Print Network [OSTI]

    Torgersen, Christian

    36 selected citations from Petroleum: An Annotated Bibliography on Petroleum Pollution Chabreck, R period. Data on bird usage, plants, invertebrates, fish, and oil in sediments and water. The petroleum and calculated LC50s Anderson, R. D. 1975. Petroleum hydrocarbons and oyster resources of Galveston Bay, Texas

  12. OIL SHALE DEVELOPMENT IN CHINA

    E-Print Network [OSTI]

    J. Qian; J. Wang; S. Li

    In this paper history, current status and forecast of Chinese oil shale indus-try, as well as the characteristics of some typical Chinese oil shales are given.

  13. Balancing oil and environment... responsibly.

    SciTech Connect (OSTI)

    Weimer, Walter C.; Teske, Lisa

    2007-01-25T23:59:59.000Z

    Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

  14. Petroleum Oil | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Petroleum Oil Petroleum Oil The production of energy feedstock and fuels requires substantial water input. Not only do biofuel feedstocks like corn, switchgrass and agricultural...

  15. Synthetic aircraft turbine oil

    SciTech Connect (OSTI)

    Yaffe, R.

    1982-03-16T23:59:59.000Z

    Synthetic lubricating oil composition having improved oxidation stability comprising a major portion of an aliphatic ester base oil having lubricating properties, formed by the reaction of pentaerythritol and an organic monocarboxylic acid and containing a phenylnaphthylamine, a dialkyldiphenylamine, a polyhydroxy anthraquinone, a hydrocarbyl phosphate ester and a dialkyldisulfide.

  16. Shale oil by 1990

    SciTech Connect (OSTI)

    Isaac, E.D.; Svoboda, D.

    1981-01-01T23:59:59.000Z

    Commercial processing of oil shale is currently being carried out in two countries, these being Manchuria and Estonia. Germany, Israel, Australia, Brazil and the United States are planning commercial development of oil shale during the 1980's. In the United States, developers currently pursuing production facilities in the Piceance Basin in Colorado are the Union Oil Company; Colony Development Company, now owned by Tosco and Exxon; Occidental Oil Shale Inc.; The Rio Blanco Shale Company (Amoco and Gulf) CA Tract; The Cathedral Bluff's Oil Shale Company (Oxy and Tenneco) at CB tract; The Anvil Points Bureau of Mines Site under the direction of DOE which has been leased to the Paraho Development Company to optimize their process; and Superior Oil. Superior Oil plans to recover Negcolite and Dowsonite that are associated with their oil shale. The processes used by these companies are described briefly. These are the Union B process, Tosco II process, Paraho process, and Occidental process. It is estimated that between 400,000 to 500,000 barrels per day (63,600 to 79,500 m/sup 3//day) production would be achieved by 1990 if all of the effects on the infrastructure are planned for and constructed in an orderly manner.

  17. Marathon Oil Company

    E-Print Network [OSTI]

    unknown authors

    Marine oil shale from the Shenglihe oil shale section in the Qiangtang basin, northern Tibet, China, was dated by the Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measure-ment. An isochron was obtained giving an age of 101±24 Ma with an initial

  18. Oil Quantity : The histori

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    model for Prudhoe Bay. Figure 11: Historical Prudhoe Bay oil production data, modeled economically Production (million bbl per Month) Historical Production Best Fit (Hist. Tax w/ELF, Ref. P) High Price 120 140 160 19 Oil Quantity Con Wel N E A N N ng Results e Bay : The histori Bay over tim : Prudhoe Ba

  19. Adsorption calorimetry in enhanced oil recovery

    SciTech Connect (OSTI)

    Noll, L.A.

    1988-05-01T23:59:59.000Z

    Adsorption calorimetry is a technique which has been used at the National Institute for Petroleum and Energy Reserch (NIPER) to help in the understanding of adsorption as it impacts enhanced oil recovery by chemical flooding. Abstraction of chemicals by reservoir minerals comprises a major obstacle to the technical and economic success of this process. Adsorption is also important in other fields such as catalysis, lubrication, ore flotation, and printing. Adsorption calorimetry is useful because it measures both the amount of adsorption and its enthalpy. The enthalpy helps to guide the extrapolation of adsorption to higher temperatures as well as acting as a probe of surface properties such as heterogeneity. Adsorption calorimetry helps to distinguish physical from chemisorption. It is also useful in distinguishing water-wet from oil-wet surfaces. This paper discusses flow adsorption calorimetry. The advantage of using a flowing system over the classic immersion technique is that it is fast and easy to use, and data for the entire isotherm are collected on a single sample of solid. In flow calorimetry the surface excess amount and the thermal data are obtained simultaneously on one and the same sample of solid, thus avoiding some sampling problems. Some disadvantages of the method are somewhat short equilibration times and the cumulative nature of the data. Aspects of adsorption of special interest to enhanced oil recovery such as the nature and charge of minerals, the structure and charge of surfactants, the effects of brine and temperature, and the effects of aqueous or hydrocarbon environment are important parameters of surfactant flooding; they are treated in this paper.

  20. Integrated hydrocarbon reforming system and controls

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Thijssen, Johannes; Davis, Robert; Papile, Christopher; Rumsey, Jennifer W.; Longo, Nathan; Cross, III, James C.; Rizzo, Vincent; Kleeburg, Gunther; Rindone, Michael; Block, Stephen G.; Sun, Maria; Morriseau, Brian D.; Hagan, Mark R.; Bowers, Brian

    2003-11-04T23:59:59.000Z

    A hydrocarbon reformer system including a first reactor configured to generate hydrogen-rich reformate by carrying out at least one of a non-catalytic thermal partial oxidation, a catalytic partial oxidation, a steam reforming, and any combinations thereof, a second reactor in fluid communication with the first reactor to receive the hydrogen-rich reformate, and having a catalyst for promoting a water gas shift reaction in the hydrogen-rich reformate, and a heat exchanger having a first mass of two-phase water therein and configured to exchange heat between the two-phase water and the hydrogen-rich reformate in the second reactor, the heat exchanger being in fluid communication with the first reactor so as to supply steam to the first reactor as a reactant is disclosed. The disclosed reformer includes an auxiliary reactor configured to generate heated water/steam and being in fluid communication with the heat exchanger of the second reactor to supply the heated water/steam to the heat exchanger.

  1. Emission of polycyclic aromatic hydrocarbons in China

    SciTech Connect (OSTI)

    Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-02-01T23:59:59.000Z

    Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

  2. D-area oil seepage basin bioventing optimization test plan

    SciTech Connect (OSTI)

    Berry, C.J.; Radway, J.C.; Alman, D.; Hazen, T.C.

    1998-12-31T23:59:59.000Z

    The D Area Oil Seepage Basin (DOSB) was used from 1952 to 1975 for disposal of petroleum-based products (waste oils), general office and cafeteria waste, and apparently some solvents [trichloroethylene (TCE)/tetrachloroethylene (PCE)]. Numerous analytical results have indicated the presence of TCE and its degradation product vinyl chloride in groundwater in and around the unit, and of petroleum hydrocarbons in soils within the unit. The DOSB is slated for additional assessment and perhaps for environmental remediation. In situ bioremediation represents a technology of demonstrated effectiveness in the reclamation of sites contaminated with petroleum hydrocarbons and chlorinated solvents, and has been retained as an alternative for the cleanup of the DOSB. The Savannah River Site is therefore proposing to conduct a field treatability study designed to demonstrate and optimize the effectiveness of in situ microbiological biodegradative processes at the DOSB. The introduction of air and gaseous nutrients via two horizontal injection wells (bioventing) is expected to enhance biodegradation rates of petroleum components and stimulate microbial degradation of chlorinated solvents. The data gathered in this test will allow a determination of the biodegradation rates of contaminants of concern in the soil and groundwater, allow an evaluation of the feasibility of in situ bioremediation of soil and groundwater at the DOSB, and provide data necessary for the functional design criteria for the final remediation system.

  3. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    methane from near-surface gas hydrates. Chem Geol 205:291–volcanoes and associated gas hydrates. Mar Geol 167:29–42

  4. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    initiated a modern reservoir characterization study of thecharacterization and well path navigation system for effective re-development and enhancement of ultimate recovery from the complex Monterey Reservoir

  5. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    source and a fractured reservoir (Kamerling et al. 2003).giant reserves in a fractured reservoir, California. In:

  6. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    incorporating the new seismic interpretation, well logs,seismic data. Integrated geologic studies continued in the early 1990s based on the original structural interpretation.

  7. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    M. J. Kamerling Venoco Inc. , Carpinteria, CA 95076, USA I.and operated by Venoco Inc. , Carpinteria, CA Geo-Mar Lett (from Venoco Inc. , Carpinteria, CA For the South Ellwood

  8. THE ELECTRON MICROSCOPY OF HYDROCARBON PRODUCTION IN PARTHENIUM ARGENTATUM (GUAYULE)

    E-Print Network [OSTI]

    Bauer, T.E.

    2010-01-01T23:59:59.000Z

    natural gas left, and oil reserves are variously estimatedlonger estimates for oil reserves depend upon the obtainingoil and gas often mentioned and cur- rently being developed is coal. The United States possesses coal reserves

  9. U.S. Department of Energy Naval Petroleum and Oil Shale Reserves combined financial statements, September 30, 1996 and 1995

    SciTech Connect (OSTI)

    NONE

    1997-03-01T23:59:59.000Z

    The Naval Petroleum and Oil Shale Reserves (NPOSR) produces crude oil and associated hydrocarbons from the Naval Petroleum Reserves (NPR) numbered 1, 2, and 3, and the Naval Oil Shale Reserves (NOSR) numbered 1, 2, and 3 in a manner to achieve the greatest value and benefits to the US taxpayer. NPOSR consists of the Naval Petroleum Reserve in California (NPRC or Elk Hills), which is responsible for operations of NPR-1 and NPR-2; the Naval Petroleum Oil Shale Reserve in Colorado, Utah, and Wyoming (NPOSR-CUW), which is responsible for operations of NPR-3, NOSR-1, 2, and 3 and the Rocky Mountain Oilfield Testing Center (RMOTC); and NPOSR Headquarters in Washington, DC, which is responsible for overall program direction. Each participant shares in the unit costs and production of hydrocarbons in proportion to the weighted acre-feet of commercially productive oil and gas formations (zones) underlying the respective surface lands as of 1942. The participating shares of NPR-1 as of September 30, 1996 for the US Government and Chevron USA, Inc., are listed. This report presents the results of the independent certified public accountants` audit of the Department of Energy`s (Department) Naval Petroleum and Oil Shale Reserves (NPOSR) financial statements as of September 30, 1996.

  10. Oil removal from water via adsorption 

    E-Print Network [OSTI]

    Jacobs, William Edward

    1973-01-01T23:59:59.000Z

    . TABLE OF CONTENTS CHAPTER I. INTRODUCTION I I. LITERATURE REVIEW Significance of Oil Spill Proble. ". . s Growth of Marine Commerce Superport Oil Spills Oil Spills and the Law Oil Spill Control Methods Physical Removal of Oil III. MATERIALS... IV Table V Table VI Significant Facts about Major Oil Spills Viscosity of Test Oils Determined by Capillary Viscometer Percent of Oil Remaining in Water After Removal of Oil-Carrier Combination Maximum Oil Adsorption Capacity for Light Crude...

  11. Induced biochemical interactions in immature and biodegraded heavy crude oils

    SciTech Connect (OSTI)

    Premuzic, E.T.; Lin, M.S.; Bohenek, M.; Joshi-Tope, G.; Shelenkova, L.; Zhou, W.M.

    1998-11-01T23:59:59.000Z

    Studies in which selective chemical markers have been used to explore the mechanisms by which biocatalysts interact with heavy crude oils have shown that the biochemical reactions follow distinct trends. The term biocatalyst refers to a group of extremophilic microorganisms which, under the experimental conditions used, interact with heavy crude oils to (1) cause a redistribution of hydrocarbons, (2) cause chemical changes in oil fractions containing sulfur compounds and lower the sulfur content, (3) decrease organic nitrogen content, and (4) decrease the concentration of trace metals. Current data indicate that the overall effect is due to simultaneous reactions yielding products with relatively higher concentration of saturates and lower concentrations of aromatics and resins. The compositional changes depend on the microbial species and the chemistry of the crudes. Economic analysis of a potential technology based on the available data indicate that such a technology, used in a pre-refinery mode, may be cost efficient and promising. In the present paper, the background of oil biocatalysis and some recent results will be discussed.

  12. INDUCED BIOCHEMICAL INTERACTIONS IN IMMATURE AND BIODEGRADED HEAVY CRUDE OILS

    SciTech Connect (OSTI)

    PREMUZIC,E.T.; LIN,M.S.; BOHENEK,M.; JOSHI-TOPE,G.; SHELENKOVA,L.; ZHOU,W.M.

    1998-10-27T23:59:59.000Z

    Studies in which selective chemical markers have been used to explore the mechanisms by which biocatalysts interact with heavy crude oils have shown that the biochemical reactions follow distinct trends. The term biocatalyst refers to a group of extremophilic microorganisms which, under the experimental conditions used, interact with heavy crude oils to (1) cause a redistribution of hydrocarbons, (2) cause chemical changes in oil fractions containing sulfur compounds and lower the sulfur content, (3) decrease organic nitrogen content, and (4) decrease the concentration of trace metals. Current data indicate that the overall effect is due to simultaneous reactions yielding products with relatively higher concentration of saturates and lower concentrations of aromatics and resins. The compositional changes depend on the microbial species and the chemistry of the crudes. Economic analysis of a potential technology based on the available data indicate that such a technology, used in a pre-refinery mode, may be cost efficient and promising. In the present paper, the background of oil biocatalysis and some recent results will be discussed.

  13. Polycyclic aromatic hydrocarbons in fresh and smoked fish samples from three Nigerian cities

    SciTech Connect (OSTI)

    Akpan, V.; Lodovici, M.; Dolara, P. (Dept. of Pharmacology and Toxicology, Florence (Italy))

    1994-08-01T23:59:59.000Z

    Nigeria is a major producer of crude oil in sub-Saharan Africa. In-shore and off-shore wells are located in richly watered creeks in the southern part of the country. Although published data on environmental impact assessment of the petroleum industry in Nigeria are lacking, there is a growing concern about the possible contamination of estuarine and coastal waters and of marine species by polycyclic aromatic hydrocarbon (PAHs). PAHs are ubiquitous priority pollutants that occur naturally in crude oil, automobile exhaust emissions and smoke condensates from incomplete combustion of carbonaceous materials. PAHs with high molecular weight are less readily biodegraded by indigenous microorganisms in some regions, and given their marked hydrophobic characteristics, may persist in the aqueous environment, thus contaminating the food chain by bioaccumulating in aquatic species like fish and mussels. Major Nigerian oil wells are located in the vicinity of breeding and harvesting sites serving the fresh-water fishing industry. Large hauls of fresh fish are normally consumed cooked in soups or smoke cured in handcrafted traditional ovens using freshly cut red mangrove (Rhizophora racemosa) wood as fuel. Though smoke curing is economical and may ensure longer conservation of fish, it undoubtedly increases the burden of PAHs in finished products as a result of partial charring and from smoke condensates or mangroves that also contain PAHs in measurable quantities as reported by Asita et al. (1991). Apart from PAHs analyzed by Emerole (1980) in smoked food samples from Ibadan using simple analytical methods, those from industrial and other anthropogenic sources have rarely been analyzed in Nigeria. We tried therefore to update the data and address this discrepancy. 14 refs., 4 figs., 2 tabs.

  14. Cardiac toxicity of 5-ring polycyclic aromatic hydrocarbons is differentially dependent on the aryl hydrocarbon receptor 2 isoform during zebrafish development

    E-Print Network [OSTI]

    Cardiac toxicity of 5-ring polycyclic aromatic hydrocarbons is differentially dependent on the aryl hydrocarbon receptor 2 isoform during zebrafish development John P. Incardona , Tiffany L. Linbo, Nathaniel L aromatic hydrocarbons (PAHs), commonly occur as com- plex mixtures in the environment. Recent studies using

  15. IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater Revised and Updated. Part 7. C8H12C8H18 Hydrocarbons

    E-Print Network [OSTI]

    IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater Revised and Updated. Part 7. C8H12­C8H18 Hydrocarbons with Water Volume Editors David G. Shawa... University of Alaska on the evaluation of the all experimental data for a given homologous series of aliphatic and aromatic hydrocarbons

  16. 5 World Oil Trends WORLD OIL TRENDS

    E-Print Network [OSTI]

    for gasoline, diesel and other petroleum products. This chapter provides an overview of world oil trends agreements on export routes have limited development. Petroleum production in the United States, including half of petroleum supplies to the United States. OPEC petroleum production also increased in 1994

  17. ORGANIC GEOCHEMICAL STUDIES. II. THE DISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA, AND IN A RECENT LAKE SEDIMENT: A PRELIMINARY REPORT

    E-Print Network [OSTI]

    Han, Jerry; McCarthy, E.D.; Van Hoeven Jr., William; Calvin, Melvin; Bradley, W. H.

    2008-01-01T23:59:59.000Z

    significantly to the hydrocarbons of higher molecular weightDISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA,T E DISTRIBUTION O ALIPHATIC HYDROCARBONS H F A PRELIMINARY

  18. Long-range transport of particulate polycyclic aromatic hydrocarbons at Cape Hedo remote island site in the East China Sea between 2005 and 2008

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    of polycyclic aromatic hydrocarbons (PAHs) for 2004. Atmos.of polynuclear aromatic hydrocarbons in ambient air throughpolycyclic aromatic hydrocarbons in urban air of Hong Kong.

  19. Hydrocarbon Seeps of the Mesozoic Great Valley Group Forearc Strata and Franciscan Complex, Northern and Central California, U.S.A.

    E-Print Network [OSTI]

    Keenan, Kristin Euphrat

    2010-01-01T23:59:59.000Z

    and Cretaceous Gastropods from Hydrocarbon Seeps in ForearcPeregrinella-Dominated Hydrocarbon-Seep Deposit on the1999. Signatures of Hydrocarbon Venting in a Middle Devonian

  20. Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    Bohrmann, G. , 2007. In situ hydrocarbon concentrations fromM. , Bohrmann, G. , 2003. Hydrocarbon gases in deposits fromMethane and other hydrocarbon gases in marine sediment.