Sample records for hydrocarbons hydrogen oxygenates

  1. Selective photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

    1998-01-01T23:59:59.000Z

    A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

  2. Getter pump for hydrogen and hydrocarbon gases

    DOE Patents [OSTI]

    Hsu, Wen Ling

    1987-10-14T23:59:59.000Z

    A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

  3. The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

    E-Print Network [OSTI]

    The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

  4. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect (OSTI)

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01T23:59:59.000Z

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  5. Method for making hydrogen rich gas from hydrocarbon fuel

    DOE Patents [OSTI]

    Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

    1999-07-27T23:59:59.000Z

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

  6. THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS

    E-Print Network [OSTI]

    THERMOCATALYTIC CO2- FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS N. Muradov Florida Solar Energy Center 1679 Clearlake Road, Cocoa, Florida 32922 tel. 321-638-1448, fax. 321-638-1010, muradov (except for the start-up operation). This results in the following advantages: (1) no CO/CO2 byproducts

  7. Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (7 Rocky Brook Rd., Dover, MA 02030); Mitchell, William L. (111 Oakley Rd., Belmont, MA 02178); Bentley, Jeffrey M. (20 Landmark Rd., Westford, MA 01886); Thijssen, Johannes H. J. (1 Richdale Ave.#2, Cambridge, MA 02140)

    2002-01-01T23:59:59.000Z

    Hydrocarbon fuel reformer 100 suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first tube 108 has a first tube inlet 110 and a first tube outlet 112. The first tube inlet 110 is adapted for receiving a first mixture including an oxygen-containing gas and a first fuel. A partially oxidized first reaction reformate is directed out of the first tube 108 into a mixing zone 114. A second tube 116 is annularly disposed about the first tube 108 and has a second tube inlet 118 and a second tube outlet 120. The second tube inlet 118 is adapted for receiving a second mixture including steam and a second fuel. A steam reformed second reaction reformate is directed out of the second tube 116 and into the mixing zone 114. From the mixing zone 114, the first and second reaction reformates may be directed into a catalytic reforming zone 144 containing a reforming catalyst 147.

  8. Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels

    SciTech Connect (OSTI)

    University of Central Florida

    2004-01-30T23:59:59.000Z

    The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

  9. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

    1996-01-01T23:59:59.000Z

    A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

  10. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, R.J.; Basel, R.A.

    1996-03-12T23:59:59.000Z

    A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

  11. Hydrocarbon desulfurization process

    SciTech Connect (OSTI)

    Plummer, M.A.; Zimmerman, C.C. Jr.

    1986-04-08T23:59:59.000Z

    A process is described for converting a sour hydrocarbon feedstock having a relatively high sulfur content to a hydrocarbon product having a relatively low sulfur content comprising the steps of: (a) hydrodesulfurizing the feedstock having a relatively high sulfur contact with hydrogen to produce the hydrocarbon product having a relatively low sulfur content and hydrogen sulfide gas; (b) contacting the hydrogen sulfide gas with an anthraquinone dissolved in a polar organic solvent having a polarity greater than about 3 Debye units to produce sulfur and an anthrahydroquinone in the solvent; (c) regenerating the anthraquinone from the anthrahydroquinone upon contact with air to produce the anthraquinone and hydrogen peroxide; (d) recycling the anthraquinone to step (b); (e) reducing the hydrogen peroxide to oxygen and water; (f) partially oxidizing a hydrocarbon fuel with the oxygen to produce carbon dioxide and hydrogen; and (g) recycling the hydrogen to step (a).

  12. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, H.; Blatter, F.; Sun, H.

    1999-06-22T23:59:59.000Z

    A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

  13. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    1999-01-01T23:59:59.000Z

    A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  14. Selective thermal oxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2000-01-01T23:59:59.000Z

    A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  15. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2001-01-01T23:59:59.000Z

    A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  16. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24T23:59:59.000Z

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  17. Method for simultaneous recovery of hydrogen from water and from hydrocarbons

    DOE Patents [OSTI]

    Willms, R. Scott (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    Method for simultaneous recovery of hydrogen and hydrogen isotopes from water and from hydrocarbons. A palladium membrane, when utilized in cooperation with a nickel catalyst in a reactor, has been found to drive reactions such as water gas shift, steam reforming and methane cracking to substantial completion by removing the product hydrogen from the reacting mixture. In addition, ultrapure hydrogen is produced, thereby eliminating the need for an additional processing step.

  18. Apparatus and method for simultaneous recovery of hydrogen from water and from hydrocarbons

    DOE Patents [OSTI]

    Willms, R. Scott (Los Alamos, NM); Birdsell, Stephen A. (Los Alamos, NM)

    2000-01-01T23:59:59.000Z

    Apparatus and method for simultaneous recovery of hydrogen from water and from hydrocarbon feed material. The feed material is caused to flow over a heated catalyst which fosters the water-gas shift reaction (H.sub.2 O+COH.sub.2 +CO.sub.2) and the methane steam reforming reaction (CH.sub.4 +H.sub.2 O3 H.sub.2 +CO). Both of these reactions proceed only to partial completion. However, by use of a Pd/Ag membrane which is exclusively permeable to hydrogen isotopes in the vicinity of the above reactions and by maintaining a vacuum on the permeate side of the membrane, product hydrogen isotopes are removed and the reactions are caused to proceed further toward completion. A two-stage palladium membrane reactor was tested with a feed composition of 28% CQ.sub.4, 35% Q.sub.2 O (where Q=H, D, or T), and 31% Ar in 31 hours of continuous operation during which 4.5 g of tritium were processed. Decontamination factors were found to increase with decreasing inlet rate. The first stage was observed to have a decontamination factor of approximately 200, while the second stage had a decontamination factor of 2.9.times.10.sup.6. The overall decontamination factor was 5.8.times.10.sup.8. When a Pt/.alpha.-Al.sub.2 O.sub.3 catalyst is employed, decoking could be performed without catalyst degradation. However, by adjusting the carbon to oxygen ratio of the feed material with the addition of oxygen, coking could be altogether avoided.

  19. Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

    2001-01-01T23:59:59.000Z

    An improved process for separating hydrogen from hydrocarbons. The process includes a pressure swing adsorption step, a compression/cooling step and a membrane separation step. The membrane step relies on achieving a methane/hydrogen selectivity of at least about 2.5 under the conditions of the process.

  20. Hydrogen and elemental carbon production from natural gas and other hydrocarbons

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2002-01-01T23:59:59.000Z

    Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

  1. Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons

    DOE Patents [OSTI]

    Muradov, Nazim Z. (Melbourne, FL)

    2011-08-23T23:59:59.000Z

    A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

  2. Characteristics of Knock in Hydrogen-Oxygen-Argon SI Engine

    SciTech Connect (OSTI)

    Killingsworth, N; Rapp, V; Flowers, D; Aceves, S; Chen, J; Dibble, R

    2010-02-23T23:59:59.000Z

    A promising approach for improving the efficiency of internal combustion engines is to employ a working fluid with a high specific heat ratio such as the noble gas argon. Moreover, all harmful emissions are eliminated when the intake charge is composed of oxygen, nonreactive argon, and hydrogen fuel. Previous research demonstrated indicated thermal efficiencies greater than 45% at 5.5 compression ratio in engines operating with hydrogen, oxygen, and argon. However, knock limits spark advance and increasing the efficiency further. Conditions under which knock occurs in such engines differs from typical gasoline fueled engines. In-cylinder temperatures using hydrogen-oxygen-argon are higher due to the high specific heat ratio and pressures are lower because of the low compression ratio. Better understanding of knock under these conditions can lead to operating strategies that inhibit knock and allow operation closer to the knock limit. In this work we compare knock with a hydrogen, oxygen, and argon mixture to that of air-gasoline mixtures in a variable compression ratio cooperative fuels research (CFR) engine. The focus is on stability of knocking phenomena, as well as, amplitude and frequency of the resulting pressure waves.

  3. Process, including membrane separation, for separating hydrogen from hydrocarbons

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

    2001-01-01T23:59:59.000Z

    Processes for providing improved methane removal and hydrogen reuse in reactors, particularly in refineries and petrochemical plants. The improved methane removal is achieved by selective purging, by passing gases in the reactor recycle loop across membranes selective in favor of methane over hydrogen, and capable of exhibiting a methane/hydrogen selectivity of at least about 2.5 under the process conditions.

  4. Study of net soot formation in hydrocarbon reforming for hydrogen fuel cells. Final report

    SciTech Connect (OSTI)

    Edelman, R. B.; Farmer, R. C.; Wang, T. S.

    1982-08-01T23:59:59.000Z

    The hydrogen fuel cell is expected to be a valuable addition to the electric utility industry; however, the current fuel supply availability requires that conventional heavier hydrocarbon fuels also be considered as primary fuels. Typical heavier fuels would be No. 2 fuel oil with its accompanying sulfur impurities, compared with the currently used light hydrocarbon gases. The potential future use of alternate fuels which are rich in aromatics would exacerbate the problems associated with hydrogen production. Among the more severe of these problems, is the greater tendency of heavier hydrocarbons to form soot. The development of a quasi-global kinetics model to represent the homogeneous and heterogeneous reactions which control the autothermal hydrogen reforming process and the accompanying soot formation and gasification was the objective of this study.

  5. Thermochemical generation of hydrogen and oxygen from water

    DOE Patents [OSTI]

    Robinson, Paul R. (Knoxville, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1981-01-01T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  6. Thermochemical generation of hydrogen and oxygen from water

    DOE Patents [OSTI]

    Robinson, Paul R. (Knoxville, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1982-01-01T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO.sub.2) and titanium dioxide (TiO.sub.2) to form sodium titanate (Na.sub.2 TiO.sub.3), manganese (II) titanate (MnTiO.sub.3) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  7. Hydrogen Production from Methane Using Oxygen-permeable Ceramic Membranes

    E-Print Network [OSTI]

    Faraji, Sedigheh

    2010-06-08T23:59:59.000Z

    is the existence of hot spots in the catalyst bed due to the reaction exothermicity [1]. This hydrogen production process could be cost-effective if oxygen is provided by sources other than air separation plant. CO2 reforming (or dry reforming) of methane... information about equilibrium product compositions and equilibrium constants at different temperatures were provided by one of the former students in Dr Susan Williams’ research group [8]. Syngas can also be produced by coal gasification. The syngas...

  8. Hydrogen and Oxygen Gas Monitoring System Design and Operation

    SciTech Connect (OSTI)

    Lee C. Cadwallader; Kevin G. DeWall; J. Stephen Herring

    2007-06-01T23:59:59.000Z

    This paper describes pertinent design practices of selecting types of monitors, monitor unit placement, setpoint selection, and maintenance considerations for gas monitors. While hydrogen gas monitors and enriched oxygen atmosphere monitors as they would be needed for hydrogen production experiments are the primary focus of this paper, monitors for carbon monoxide and carbon dioxide are also discussed. The experiences of designing, installing, and calibrating gas monitors for a laboratory where experiments in support of the DOE Nuclear Hydrogen Initiative (NHI) are described along with codes, standards, and regulations for these monitors. Information from the literature about best operating practices is also presented. The NHI program has two types of activities. The first, near-term activity is laboratory and pilot-plant experimentation with different processes in the kilogram per day scale to select the most promising types of processes for future applications of hydrogen production. Prudent design calls for indoor gas monitors to sense any hydrogen leaks within these laboratory rooms. The second, longer-term activity is the prototype, or large-scale plants to produce tons of hydrogen per day. These large, outdoor production plants will require area (or “fencepost”) monitoring of hydrogen gas leaks. Some processes will have oxygen production with hydrogen production, and any oxygen releases are also safety concerns since oxygen gas is the strongest oxidizer. Monitoring of these gases is important for personnel safety of both indoor and outdoor experiments. There is some guidance available about proper placement of monitors. The fixed point, stationary monitor can only function if the intruding gas contacts the monitor. Therefore, monitor placement is vital to proper monitoring of the room or area. Factors in sensor location selection include: indoor or outdoor site, the location and nature of potential vapor/gas sources, chemical and physical data of the gases or vapors, liquids with volatility need sensors near the potential sources of release, nature and concentration of gas releases, natural and mechanical ventilation, detector installation locations not vulnerable to mechanical or water damage from normal operations, and locations that lend themselves to convenient maintenance and calibration. The guidance also states that sensors should be located in all areas where hazardous accumulations of gas may occur. Such areas might not be close to release points but might be areas with restricted air movement. Heavier than air gases are likely to accumulate in pits, trenches, drains, and other low areas. Lighter than air gases are more likely to accumulate in overhead spaces, above drop ceilings, etc. In general, sensors should be located close to any potential sources of major release of gas. The paper gives data on monitor sensitivity and expected lifetimes to support the monitor selection process. Proper selection of indoor and outdoor locations for monitors is described, accounting for the vapor densities of hydrogen and oxygen. The latest information on monitor alarm setpoint selection is presented. Typically, monitors require recalibration at least every six months, or more frequently for inhospitable locations, so ready access to the monitors is an important issue to consider in monitor siting. Gas monitors, depending on their type, can be susceptible to blockages of the detector element (i.e., dus

  9. Formation of Hydrogen, Oxygen, and Hydrogen Peroxide in Electron Irradiated Crystalline Water Ice

    E-Print Network [OSTI]

    Weijun Zheng; David Jewitt; Ralf I. Kaiser

    2005-11-18T23:59:59.000Z

    Water ice is abundant both astrophysically, for example in molecular clouds, and in planetary systems. The Kuiper belt objects, many satellites of the outer solar system, the nuclei of comets and some planetary rings are all known to be water-rich. Processing of water ice by energetic particles and ultraviolet photons plays an important role in astrochemistry. To explore the detailed nature of this processing, we have conducted a systematic laboratory study of the irradiation of crystalline water ice in an ultrahigh vacuum setup by energetic electrons holding a linear energy transfer of 4.3 +/- 0.1 keV mm-1. The irradiated samples were monitored during the experiment both on line and in situ via mass spectrometry (gas phase) and Fourier transform infrared spectroscopy (solid state). We observed the production of hydrogen and oxygen, both molecular and atomic, and of hydrogen peroxide. The likely reaction mechanisms responsible for these species are discussed. Additional formation routes were derived from the sublimation profiles of molecular hydrogen (90-140 K), molecular oxygen (147 -151 K) and hydrogen peroxide (170 K). We also present evidence on the involvement of hydroxyl radicals and possibly oxygen atoms as building blocks to yield hydrogen peroxide at low temperatures (12 K) and via a diffusion-controlled mechanism in the warming up phase of the irradiated sample.

  10. Fast-quench reactor for hydrogen and elemental carbon production from natural gas and other hydrocarbons

    DOE Patents [OSTI]

    Detering, Brent A.; Kong, Peter C.

    2006-08-29T23:59:59.000Z

    A fast-quench reactor for production of diatomic hydrogen and unsaturated carbons is provided. During the fast quench in the downstream diverging section of the nozzle, such as in a free expansion chamber, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

  11. Ignition quality determination of diesel fuels from hydrogen type distribution of hydrocarbons

    SciTech Connect (OSTI)

    Gulder, O.L.; Glavincevski, B.

    1986-02-01T23:59:59.000Z

    Hydrogen types of diesel like hydrocarbon fuels which have dominant effect on the ignition quality have been identified. A scheme of characterizing the chemistry of hydrocarbon fuels in terms of these hydrogen types using proton nuclear resonance spectrometry has been proposed. Using this analysis technique on 70 different diesel fuels, whose cetane numbers were determined on a number of standard cetane rating engines, an empirical expression which relates the ignition quality to the hydrogen type distribution of the fuels has been developed. The developed expression and the relationship between the ignition delay and cetane number imply that the effective activation energy term in the usual semiempirical ignition delay expression is not a constant for a given fuel but is a function of pressure and temperature as well as the fuel chemistry.

  12. Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds M Abstract. -- The thermal behavior of oxygen-stabilized RjFegO^-hydrogen (R = Y, Dy, Ho) systems was studied decade to the study of the hydrogenation characte- ristics of a variety of intermetallic compounds, our

  13. Mach 2 combustion characteristics of hydrogen/hydrocarbon fuel mixtures

    SciTech Connect (OSTI)

    Diskin, G.S.; Jachimowski, C.J.; Northam, G.B.; Bell, R.A.

    1987-01-01T23:59:59.000Z

    The combustion of H/sub 2//CH/sub 4/ and H/sub 2//C/sub 2/H/sub 4/ mixtures containing 10 to 70 vol pct hydrocarbon at combustor inlet Mach number 2 and temperatures 2000 to 4000 R is investigated experimentally, applying direct-connect test hardware and techniques similar to those described by Diskin and Northam (1987) in the facilities of the NASA Langley Hypersonic Propulsion Branch. The experimental setup, procedures, and data-reduction methods are described; and the results are presented in extensive tables and graphs and characterized in detail. Fuel type and mixture are found to have little effect on the wall heating rate measured near the combustor exit, but H/sub 2//C/sub 2/H/sub 4/ is shown to burn much more efficiently than H/sub 2//CH/sub 4/, with no pilot-off blowout equivalence ratios greater than 0.5. It is suggested that H/sub 2//hydrocarbon mixtures are feasible fuels (at least in terms of combustion efficiency) for scramjet SSTO vehicles operating at freestream Mach numbers above 4.

  14. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: AlternativeEnvironment, Safety andGeothermalGreen FlagHomeResearch andEnergy Hydrogen|

  15. Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon

    DOE Patents [OSTI]

    Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

    2000-01-01T23:59:59.000Z

    In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

  16. Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform Fikile R of hydrogen H2 and oxygen O2 . Operating fuel cells in alkaline media, as opposed to acidic media, has on an alkaline microfluidic fuel cell for catalyst and electrode characterization. Its constantly refreshing

  17. Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational Study

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational be used to make an efficient and relatively inexpensive graphene-based material for hydrogen fuel cells fuel cells for oxygen reduction at the cathode. In an attempt to find a cheap yet efficient catalyst

  18. THE INFRARED SPECTRA OF POLYCYCLIC AROMATIC HYDROCARBONS WITH SOME OR ALL HYDROGEN ATOMS REMOVED

    SciTech Connect (OSTI)

    Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Ricca, Alessandra, E-mail: Charles.W.Bauschlicher@nasa.gov, E-mail: Alessandra.Ricca-1@nasa.gov [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Mountain View, CA 94043 (United States)

    2013-10-20T23:59:59.000Z

    The loss of one hydrogen from C{sub 96}H{sub 24} does not significantly affect the infrared spectra of the neutral, cation, or anion. Excluding a very weak C-C stretching band at 5.1 ?m, the loss of two adjacent duo hydrogens does not significantly affect the spectra compared with the parent. Removing all of the hydrogen atoms significantly increases the intensity of the new C-C stretching band, and, for the cation, shifts it to a longer (5.2 ?m) wavelength. Observations show a feature near 5.25 ?m, which has been attributed to overtone and combination bands from polycyclic aromatic hydrocarbons (PAHs). This current work suggests that dehydrogenated PAHs might also contribute to this band, but its weakness implies that fully dehydrogenated cationic or dicationic species are very rare.

  19. Hydrogen removal from e-beam deposited alumina thin films by oxygen ion beam

    SciTech Connect (OSTI)

    Das, Arijeet, E-mail: arijeet@rrcat.gov.in; Mukharjee, C., E-mail: arijeet@rrcat.gov.in; Rajiv, K., E-mail: arijeet@rrcat.gov.in; Bose, Aniruddha, E-mail: arijeet@rrcat.gov.in; Singh, S. D., E-mail: arijeet@rrcat.gov.in; Rai, S. K.; Ganguli, Tapas; Joshi, S. C.; Deb, S. K. [Raja Ramanna Centre for Advanced Technology, Indore-452013 (India); Phase, D. M. [UGC-DAE Consortium for Scientific Research, Indore-452017 (India)

    2014-04-24T23:59:59.000Z

    Hydrogen interstitials and oxygen vacancies defects create energy levels in the band gap of alumina. This limits the application of alumina as a high-k dielectric. A low thermal budget method for removal of hydrogen from alumina is discussed. It is shown that bombardment of alumina films with low energy oxygen ion beam during electron beam evaporation deposition decreases the hydrogen concentration in the film significantly.

  20. The role of oxygen in hydrogen sensing by a platinum-gate silicon carbide gas sensor: An ultrahigh vacuum study

    E-Print Network [OSTI]

    Tobin, Roger G.

    The role of oxygen in hydrogen sensing by a platinum-gate silicon carbide gas sensor: An ultrahigh conditions that elucidate the role of oxygen in the functioning of silicon carbide field-effect gas sensors hydrogen-depleted state; competition between hydrogen oxidation and hydrogen diffusion to metal/ oxide

  1. A Chemical Kinetic Modeling Study of the Effects of Oxygenated Hydrocarbons on Soot Emissions from Diesel Engines

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J

    2005-11-14T23:59:59.000Z

    A detailed chemical kinetic modeling approach is used to examine the phenomenon of suppression of sooting in diesel engines by addition of oxygenated hydrocarbon species to the fuel. This suppression, which has been observed experimentally for a few years, is explained kinetically as a reduction in concentrations of soot precursors present in the hot products of a fuel-rich diesel ignition zone when oxygenates are included. Oxygenates decrease the overall equivalence ratio of the igniting mixture, producing higher ignition temperatures and more radical species to consume more soot precursor species, leading to lower soot production. The kinetic model is also used to show how different oxygenates, ester structures in particular, can have different soot-suppression efficiencies due to differences in molecular structure of the oxygenated species.

  2. Hydrogen and oxygen permeation through Nafion 117 and XUS 13204.10 fuel cell membranes

    E-Print Network [OSTI]

    Lee, Steven Ray

    1992-01-01T23:59:59.000Z

    HYDROGEN AND OXYGEN PERMEATION THROUGH NAFION 117 AND XUS 13204. 10 FUEL CELL MEMBRANES A Thesis by STEVEN RAY LEE Submitted to the Office of Graduate Studies of Texas AdrM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1992 Major Subject Chemical Engineering HYDROGEN AND OXYGEN PERMEATION THROUGH NAFION 117 AND XUS 13204. 10 FUEL CELL MEMBRANES A Thesis by STEVEN RAY LEE Approved as to style and content by: Ralph E. White (Chair...

  3. Flammability Characteristics of Hydrogen and Its Mixtures with Light Hydrocarbons at Atmospheric and Sub-atmospheric Pressures

    E-Print Network [OSTI]

    Le, Thuy Minh Hai

    2013-07-13T23:59:59.000Z

    of hydrogen and each hydrocarbon were determined experimentally at room temperature (20şC) and initial pressures ranging from 1.0 atm to 0.1 atm. The experiments were conducted in a closed cylindrical stainless steel vessel with upward flame propagation...

  4. Field-scale investigation of enhanced petroleum hydrocarbon biodegradation in the vadose zone combining soil venting as an oxygen source with moisture and nutrient addition. Appendices. Doctoral thesis

    SciTech Connect (OSTI)

    Miller, R.N.

    1990-01-01T23:59:59.000Z

    This document contains appendices regarding a reprint on a field scale investigation of enhanced petroleum hydrocarbon biodegradation in the vadose zone combining soil venting as a oxygen source with moisture and nutrient addition.

  5. Method for producing hydrogen and oxygen by use of algae

    DOE Patents [OSTI]

    Greenbaum, Elias (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    Efficiency of process for producing H.sub.2 by subjecting algae in an aqueous phase to light irradiation is increased by culturing algae which has been bleached during a first period of irradiation in a culture medium in an aerobic atmosphere until it has regained color and then subjecting this algae to a second period of irradiation wherein hydrogen is produced at an enhanced rate.

  6. Method for producing hydrogen and oxygen by use of algae

    DOE Patents [OSTI]

    Greenbaum, E.

    1982-06-16T23:59:59.000Z

    Efficiency of process for producing H/sub 2/ by subjecting algae in an aqueous phase to light irradiation is increased by culturing algae which has been bleached during a first period of irradiation in a culture medium in an aerobic atmosphere until it has regained color and then subjecting this algae to a second period of irradiation wherein hydrogen is produced at an enhanced rate.

  7. Thermocatalytic CO{sub 2}-Free Production of Hydrogen from Hydrocarbon Fuels - Final Report for the Period August 1999 - September 2000

    SciTech Connect (OSTI)

    Nazim Muradov, Ph.D.

    2000-10-01T23:59:59.000Z

    The overall objective of this work is to develop a novel process for CO{sub 2}-free production of hydrogen via thermocatalytic decomposition (pyrolysis) of hydrocarbon fuels as a viable alternative to the conventional processes of methane steam reforming or partial oxidation. The objective of Phase I work was to demonstrate the technical feasibility of CO{sub 2}-free production of hydrogen and carbon from different hydrocarbons, including methane, propane and gasoline.

  8. Cavitation-induced ignition of cryogenic hydrogen-oxygen fluids V. V. Osipov,1,a

    E-Print Network [OSTI]

    Muratov, Cyrill

    Cavitation-induced ignition of cryogenic hydrogen-oxygen fluids V. V. Osipov,1,a C. B. Muratov,2 E-ignite in the process of their sudden mixing. Here, we propose a cavitation-induced self-ignition mechanism that may a cavitation-induced self- ignition mechanism of cryogenic H2/Ox fluids. Cavitation is the formation

  9. Evidence of the production of hot hydrogen atoms in RF plasmas by catalytic reactions between hydrogen and oxygen species

    E-Print Network [OSTI]

    Jonathan Phillips; Chun Ku Chen; Randell Mills

    2004-02-06T23:59:59.000Z

    Selective H-atom line broadening was found to be present throughout the volume (13.5 cm ID x 38 cm length) of RF generated H2O plasmas in a GEC cell. Notably, at low pressures (ca. hydrogen was 'hot' with energies greater than 40 eV with a pressure dependence, but only a weak power dependence. The degree of broadening was virtually independent of the position studied within the GEC cell, similar to the recent finding for He/H2 and Ar/H2 plasmas in the same GEC cell. In contrast to the atomic hydrogen lines, no broadening was observed in oxygen species lines at low pressures. Also, in control Xe/H2 plasmas run in the same cell at similar pressures and adsorbed power, no significant broadening of atomic hydrogen, Xe, or any other lines was observed. Stark broadening or acceleration of charged species due to high electric fields can not explain the results since (i) the electron density was insufficient by orders of magnitude, (ii) the RF field was essentially confined to the cathode fall region in contrast to the broadening that was independent of position, and (iii) only the atomic hydrogen lines were broadened. Rather, all of the data is consistent with a model that claims specific, predicted, species can act catalytically through a resonant energy transfer mechanism to create hot hydrogen atoms in plasmas.

  10. ccsd-00000318(version1):29Apr2003 Calculation of muon transfer from muonic hydrogen to atomic oxygen

    E-Print Network [OSTI]

    Boyer, Edmond

    oxygen Arnaud Dupays, Bruno Lepetit, J. Alberto Beswick, Carlo Rizzo Laboratoire Collisions, Agrgats and an oxygen atom are calculated in a constrained geometry one dimensional model for collision energies between energy dependence of muon transfer from the muonic hydrogen to an oxygen molecule, has been proposed [3

  11. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    polycyclic aromatic hydrocarbons; Size distribution; Atmospheric pollution; POVA (POllution des Vallées, published in "Atmospheric Environment 42, 173 (2008) 55 à 64" DOI : 10.1016/j.atmosenv.2007.10.008 #12 was determined during the intensive sampling campaigns of the POVA (POllution des Vallées Alpines) research

  12. Sensing performances of ZnO nanostructures grown under different oxygen pressures to hydrogen

    SciTech Connect (OSTI)

    Chu, Jin; Peng, Xiaoyan [Department of Physics, University of Puerto Rico Rio Piedras, San Juan, 00936-8377 PR (United States)] [Department of Physics, University of Puerto Rico Rio Piedras, San Juan, 00936-8377 PR (United States); Wang, Zhenbo [School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001 (China)] [School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001 (China); Feng, Peter, E-mail: P.feng@upr.edu [Department of Physics, University of Puerto Rico Rio Piedras, San Juan, 00936-8377 PR (United States)] [Department of Physics, University of Puerto Rico Rio Piedras, San Juan, 00936-8377 PR (United States)

    2012-12-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Surface morphology depends on the oxygen pressure. ? Structural degradation was observed for the ZnO samples when oxygen pressure was overhigh. ? The sensitivity of the ZnO-based sensors increase with grown oxygen pressure. -- Abstract: For extensive use in an industrialized process of individual ZnO nanostructures applied in gas sensors, a simple, inexpensive, and safe synthesis process is required. Here, nanostructured ZnO films were grown by a pulsed laser deposition technique under different oxygen pressures. Scanning electron microscopy images show nanopores, nanotips, and nanoparticles are obtained and energy dispersive X-ray spectroscopy data indicate oxygen concentration of the synthesized samples increases monotonously with oxygen pressure. The sensor based on ZnO with high oxygen concentration has high sensitivity, rapid response (9 s) and recovery (80 s) behavior to 500 ppm hydrogen below 150 °C. Experimental data indicate that high oxygen concentration effectively improves the sensing properties of nanostructured ZnO.

  13. Liquid-liquid equilibria of fuel oxygenate + water + hydrocarbon mixtures. 3: Effect of temperature

    SciTech Connect (OSTI)

    Wagner, G. [Universitaet Karlsruhe (Germany). Institut fuer Thermische Verfahrenstechnik; Sandler, S.I. [Univ. of Delaware, Newark, DE (United States). Center for Molecular and Engineering Thermodynamics

    1995-09-01T23:59:59.000Z

    The authors have measured the ternary liquid-liquid equilibria of water + ethanol mixtures with, separately, 2,2,4-trimethylpentane and toluene at 5 and 40 C, water + tert-amyl alcohol (TAOH) mixtures with, separately, toluene and hexane at 5 and 40 C, and of water + TAOH + pentane mixtures at 5 C. The ethanol-containing systems exhibit type 1 liquid-liquid phase behavior, and the TAOH-containing systems exhibit type 2 behavior. These data, together with the data they have previously reported at 25 C, provide information on how the liquid-liquid equilibria of these systems change as a function of temperature. While the addition of ethanol is found to increase the solubility of hydrocarbons in the aqueous phase, the concentration of the hydrocarbon in the water-rich phase decreases with increasing temperature. With the exception of hydrocarbon in the water-rich phase, the experimental data could be correlated quite well with either the UNIQUAC or NRTL models. For most of the systems considered here the predictions of the phase behavior with the liquid-liquid UNIFAC group-contribution model are only qualitatively correct. However, the liquid-liquid UNIFAC model erroneously predicts type 2 phase behavior to occur for water + ethanol + 2,2,4-trimethylpentane system at 5 C.

  14. Method of producing metallized chloroplasts and use thereof in the photochemical production of hydrogen and oxygen

    DOE Patents [OSTI]

    Greenbaum, Elias (Oak Ridge, TN)

    1987-01-01T23:59:59.000Z

    The invention is primarily a metallized chloroplast composition for use in a photosynthetic reaction. A catalytic metal is precipitated on a chloroplast membrane at the location where a catalyzed reduction reaction occurs. This metallized chloroplast is stabilized by depositing it on a support medium such as fiber so that it can be easily handled. A possible application of this invention is the splitting of water to form hydrogen and oxygen that can be used as a renewable energy source.

  15. Instrumented impact properties of zircaloy-oxygen and zircaloy-hydrogen alloys

    SciTech Connect (OSTI)

    Garde, A.M.; Kassner, T.F.

    1980-04-01T23:59:59.000Z

    Instrumented-impact tests were performed on subsize Charpy speciments of Zircaloy-2 and -4 with up to approx. 1.3 wt % oxygen and approx. 2500 wt ppM hydrogen at temperatures between 373 and 823/sup 0/K. Self-consistent criteria for the ductile-to-brittle transition, based upon a total absorbed energy of approx. 1.3 x 10/sup 4/ J/m/sup 2/, a dynamic fracture toughness of approx. 10 MPa.m/sup 1/2/, and a ductility index of approx. 0, were established relative to the temperature and oxygen concentration of the transformed BETA-phase material. The effect of hydrogen concentration and hydride morphology, produced by cooling Zircaloy-2 specimens through the temperature range of the BETA ..-->.. ..cap alpha..' = hydride phase transformation at approx. 0.3 and 3 K/s, on the impact properties was determined at temperatures between 373 and 673 K. On an atom fraction basis, oxygen has a greater effect than hydrogen on the impact properties of Zircaloy at temperatures between approx. 400 and 600 K. 34 figures.

  16. Process for making unsaturated hydrocarbons using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

    2011-04-12T23:59:59.000Z

    The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

  17. Hydrogen Selective Inorganic membranes for Gas Separations under High Pressure Intermediate Temperature Hydrocarbonic Envrionment

    SciTech Connect (OSTI)

    Rich Ciora; Paul KT Liu

    2012-06-27T23:59:59.000Z

    In this project, we have successfully developed a full scale commercially ready carbon molecular sieve (CMS) based membrane for applications in H{sub 2} recovery from refinery waste and other aggressive gas streams. Field tests at a refinery pilot plant and a coal gasification facility have successfully demonstrated its ability to recovery hydrogen from hydrotreating and raw syngas respectively. High purity H{sub 2} and excellent stability of the membrane permeance and selectivity were obtained in testing conducted over >500 hours at each site. The results from these field tests as well as laboratory testing conclude that the membranes can be operated at high pressures (up to 1,000 psig) and temperatures (up to 300 C) in presence of aggressive contaminants, such as sulfur and nitrogen containing species (H{sub 2}S, CO{sub 2}, NH{sub 3}, etc), condensable hydrocarbons, tar-like species, heavy metals, etc. with no observable effect on membrane performance. By comparison, similar operating conditions and/or environments would rapidly destroy competing membranes, such as polymeric, palladium, zeolitic, etc. Significant cost savings can be achieved through recovering H{sub 2} from refinery waste gas using this newly developed CMS membrane. Annual savings of $2 to 4MM/year (per 20,000 scfd of waste gas) can be realized by recovering the H{sub 2} for reuse (versus fuel). Projecting these values over the entire US market, potential H{sub 2} savings from refinery waste gases on the order of 750 to 1,000MM scfd and $750 to $1,000MM per year are possible. In addition to the cost savings, potential energy savings are projected to be ca. 150 to 220 tBTU/yr and CO{sub 2} gas emission reductions are projected to be ca. 5,000 to 6,500MMtons/year. The full scale membrane bundle developed as part of this project, i.e., 85 x 30 inch ceramic membrane tubes packaged into a full ceramic potting, is an important accomplishment. No comparable commercial scale product exists in the inorganic membrane field. Further, this newly developed full scale bundle concept can be extended to other thin film inorganic membrane technology (Pd, zeolite, etc), providing a potential commercialization pathway for these membrane materials that demonstrate high potential in a variety of separation applications yet remain a laboratory 'novelty' for lack of a full scale support. Overall, the project has been highly successful and all of the project objectives have been met. We have developed the first of its kind commercial scale carbon molecular sieve membrane and demonstrated its performance in field testing under aggressive operating conditions and in the presence of chemical contaminants that would rapidly destroy alternative organic and inorganic membranes. This innovative membrane permits H{sub 2} recovery from gas streams that up until now have not been successfully treated with membrane or conventional technology. Our end user participant is currently pursuing the field demonstration of this membrane for hydrogen recovery at its refinery site.

  18. Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$

    E-Print Network [OSTI]

    Santilli, R M

    2000-01-01T23:59:59.000Z

    We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capaciti...

  19. Size-extensivity-corrected multireference configuration interaction schemes to accurately predict bond dissociation energies of oxygenated hydrocarbons

    SciTech Connect (OSTI)

    Oyeyemi, Victor B. [Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544 (United States)] [Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Krisiloff, David B. [Department of Chemistry, Princeton University, Princeton, New Jersey 08544 (United States)] [Department of Chemistry, Princeton University, Princeton, New Jersey 08544 (United States); Keith, John A.; Libisch, Florian [Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States)] [Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Pavone, Michele [Department of Chemical Sciences, University of Napoli Federico II, Napoli 80120 (Italy)] [Department of Chemical Sciences, University of Napoli Federico II, Napoli 80120 (Italy); Carter, Emily A., E-mail: eac@princeton.edu [Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Program in Applied and Computational Mathematics, Princeton University, Princeton, New Jersey 08544 (United States); Andlinger Center for Energy and the Environment, Princeton University, Princeton, New Jersey 08544 (United States)

    2014-01-28T23:59:59.000Z

    Oxygenated hydrocarbons play important roles in combustion science as renewable fuels and additives, but many details about their combustion chemistry remain poorly understood. Although many methods exist for computing accurate electronic energies of molecules at equilibrium geometries, a consistent description of entire combustion reaction potential energy surfaces (PESs) requires multireference correlated wavefunction theories. Here we use bond dissociation energies (BDEs) as a foundational metric to benchmark methods based on multireference configuration interaction (MRCI) for several classes of oxygenated compounds (alcohols, aldehydes, carboxylic acids, and methyl esters). We compare results from multireference singles and doubles configuration interaction to those utilizing a posteriori and a priori size-extensivity corrections, benchmarked against experiment and coupled cluster theory. We demonstrate that size-extensivity corrections are necessary for chemically accurate BDE predictions even in relatively small molecules and furnish examples of unphysical BDE predictions resulting from using too-small orbital active spaces. We also outline the specific challenges in using MRCI methods for carbonyl-containing compounds. The resulting complete basis set extrapolated, size-extensivity-corrected MRCI scheme produces BDEs generally accurate to within 1 kcal/mol, laying the foundation for this scheme's use on larger molecules and for more complex regions of combustion PESs.

  20. Production of hydrogen in non oxygen-evolving systems: co-produced hydrogen as a bonus in the photodegradation of organic pollutants and hydrogen sulfide

    SciTech Connect (OSTI)

    Sartoretti, C. Jorand; Ulmann, M.; Augustynski, J. (Electrochemistry Laboratory, Department of Chemistry, University of Geneva (CH)); Linkous, C.A. (Florida Solar Energy Center, University of Central Florida (US))

    2000-01-01T23:59:59.000Z

    This report was prepared as part of the documentation of Annex 10 (Photoproduction of Hydrogen) of the IEA Hydrogen Agreement. Subtask A of this Annex concerned photo-electrochemical hydrogen production, with an emphasis on direct water splitting. However, studies of non oxygen-evolving systems were also included in view of their interesting potential for combined hydrogen production and waste degradation. Annex 10 was operative from 1 March 1995 until 1 October 1998. One of the collaborative projects involved scientists from the Universities of Geneva and Bern, and the Federal Institute of Technology in Laussane, Switzerland. A device consisting of a photoelectrochemical cell (PEC) with a WO{sub 3} photoanode connected in series with a so-called Grazel cell (a dye sensitized liquid junction photovoltaic cell) was developed and studied in this project. Part of these studies concerned the combination of hydrogen production with degradation of organic pollutants, as described in Chapter 3 of this report. For completeness, a review of the state of the art of organic waste treatment is included in Chapter 2. Most of the work at the University of Geneva, under the supervision of Prof. J. Augustynski, was focused on the development and testing of efficient WO{sub 3} photoanodes for the photoelectrochemical degradation of organic waste solutions. Two types of WO{sub 3} anodes were developed: non transparent bulk photoanodes and non-particle-based transparent film photoanodes. Both types were tested for degradation and proved to be very efficient in dilute solutions. For instance, a solar-to-chemical energy conversion efficiency of 9% was obtained by operating the device in a 0.01M solution of methanol (as compared to about 4% obtained for direct water splitting with the same device). These organic compounds are oxidized to CO{sub 2} by the photocurrent produced by the photoanode. The advantages of this procedure over conventional electrolytic degradation are that much (an order of magnitude) less energy is required and that sunlight can be used directly. In the case of photoproduction of hydrogen, as compared to water splitting, feeding the anodic compartment of the PEC with an organic pollutant, instead of the usual supporting electrolyte, will bring about a substantial increase of the photocurrent at a given illumination. Thus, the replacement of the photo-oxidation of water by the photodegradation of organic waste will be accompanied by a gain in solar-to-chemical conversion efficiency and hence by a decrease in the cost of the photoproduced hydrogen. Taking into account the benefits and possible revenues obtainable by the waste degradation, this would seem to be a promising approach to the photoproduction of hydrogen. Hydrogen sulfide (H{sub 2}S) is another waste effluent requiring extensive treatment, especially in petroleum refineries. The so-called Claus process is normally used to convert the H{sub 2}S to elemental sulfur. A sulfur recovery process developed at the Florida Solar Energy Center is described briefly in Chapter 4 by Dr. C. Linkous as a typical example of the photoproduction of hydrogen in a non oxygen-evolving system. The encouraging results obtained in these investigations of photoelectrochemical hydrogen production combined with organic waste degradation, have prompted a decision to continue the work under the new IEA Hydrogen Agreement Annex 14, Photoelectrolytic Hydrogen Production.

  1. Reference concepts for a space-based hydrogen-oxygen combustion, turboalternator, burst power system

    SciTech Connect (OSTI)

    Edenburn, M.W.

    1990-07-01T23:59:59.000Z

    This report describes reference concepts for a hydrogen-oxygen combustion, turboalternator power system that supplies power during battle engagement to a space-based, ballistic missile defense platform. All of the concepts are open''; that is, they exhaust hydrogen or a mixture of hydrogen and water vapor into space. We considered the situation where hydrogen is presumed to be free to the power system because it is also needed to cool the platform's weapon and the situation where hydrogen is not free and its mass must be added to that of the power system. We also considered the situation where water vapor is an acceptable exhaust and the situation where it is not. The combination of these two sets of situations required four different power generation systems, and this report describes each, suggests parameter values, and estimates masses for each of the four. These reference concepts are expected to serve as a baseline'' to which other types of power systems can be compared, and they are expected to help guide technology development efforts in that they suggest parameter value ranges that will lead to optimum system designs. 7 refs., 18 figs., 5 tabs.

  2. Observations of nonmethane hydrocarbons and oxygenated volatile organic compounds at a rural site in the southeastern United States

    SciTech Connect (OSTI)

    Riemer, Daniel; Pos, Willer; Milne, Peter; Farmer, Charlesk; Zika, Rod [Division of Marine and Atmospheric Chemistry, Rosenstiel School of Marine and Atmospheric Science, University of Miami, Miami, Florida (United States)] [Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, Colorado (United States)] [Atmospheric Sciences, Tennessee Valley Authority, Muscle Shoals, Alabama (United States)] Apel, Eric [Atmospheric Chemistry Group, Mantech Environmental Research Triangle Park, North Carolina (United States)] Olszyna, Ken [National Environmental Research Laboratory, U.S. EPA. Research Triangle Park, North Carolina (United States)] Kliendienst, Tad [Department of Chemistry, Western Michigan University, Kalamazoo, Michigan (United States)] Lonneman, William [Departments of Chemistry, and Earth and Atmospheric Science, Purdue University, West Lafayette, Indiana (United States); Shepson, Paul; Starn, Tim

    1998-11-01T23:59:59.000Z

    Measurements of an extensive range of nonmethane hydrocarbons (NMHCs) including alkanes, alkenes, and aromatics, and oxygenated volatile organic compounds (OVOCs) including alcohols, ketones, and aldehydes were conducted for several weeks during the summer of 1995 as part of the Southern Oxidants Study (SOS) at a rural experimental site (Youth, Inc.) 32 km southeast of Nashville, Tennessee, in the southeastern United States. These measurements were conducted to (1) determine the absolute magnitude and variability of oxygenated compounds found in a contemporary rural region; (2) assess the importance of the measured ambient levels of OVOCs on a photochemical reactivity basis relative to the more commonly determined NMHCs; and (3) to evaluate our ability to accurately measure oxygenates by the current techniques employed under a field study scenario. Several other physical (temperature, insolation, etc.), meteorological (wind velocity, wind direction, atmospheric structure, and boundary layer height), and chemical (criterion pollutants, NO{sub x}, SO{sub 2}, CO, O{sub 3}, etc.) parameters were measured concurrently with the NMHC and OVOC measurements. During the study period, OVOCs were consistently the dominant compounds present, and methanol and acetone had the highest mixing ratios. Although OVOCs made up the majority of the volatile organic compound component on a mass basis, a substantial sink for OH was isoprene and its immediate oxidation products, methacrolein and methyl vinyl ketone. In combination with CO and formaldehyde, these compounds comprised about 85{percent} of the observed OH reactivity at the site. Acetaldehyde and methanol were responsible for an additional 10{percent}, with the NMHCs and remaining OVOCs making up the final 5{percent} of the measured OH reactivity at the site. These observed patterns reinforce recent studies which find OVOCs to be an important component of the rural troposphere. {copyright} 1998 American Geophysical Union

  3. Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant

    E-Print Network [OSTI]

    Gates, Kent. S.

    Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

  4. Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$

    E-Print Network [OSTI]

    R. M. Santilli

    2000-09-04T23:59:59.000Z

    We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capacities of quantum chemistry. In fact, magnegas contains up to 50% hydrogen, while having combustion exhaust with: 1) a positive oxygen balance (releasing more oxygen in the exhaust than that used in the combustion); 2) no appreciable carcinogenic or toxic substances; 3) considerably reduced carbon dioxide as compared to fossil fuels; 4) considerably reduced nitrogen oxides; and 5) general reduction of pollutants in the exhaust up to 96% of current EPA standards.

  5. On the mechanism of the deflagration-to-detonation transition in a hydrogen-oxygen mixture

    SciTech Connect (OSTI)

    Liberman, M. A., E-mail: misha.liberman@gmail.co [Uppsala University, Department of Physics (Sweden); Ivanov, M. F.; Kiverin, A. D. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation); Kuznetsov, M. S., E-mail: mike.kuznetsov@kit.ed [Forschungszentrum Karlsruhe (Germany); Rakhimova, T. V.; Chukalovskii, A. A. [Moscow State University, Institute of Nuclear Physics (Russian Federation)

    2010-10-15T23:59:59.000Z

    The flame acceleration and the physical mechanism underlying the deflagration-to-detonation transition (DDT) have been studied experimentally, theoretically, and using a two-dimensional gasdynamic model for a hydrogen-oxygen gas mixture by taking into account the chain chemical reaction kinetics for eight components. A flame accelerating in a tube is shown to generate shock waves that are formed directly at the flame front just before DDT occurred, producing a layer of compressed gas adjacent to the flame front. A mixture with a density higher than that of the initial gas enters the flame front, is heated, and enters into reaction. As a result, a high-amplitude pressure peak is formed at the flame front. An increase in pressure and density at the leading edge of the flame front accelerates the chemical reaction, causing amplification of the compression wave and an exponentially rapid growth of the pressure peak, which 'drags' the flame behind. A high-amplitude compression wave produces a strong shock immediately ahead of the reaction zone, generating a detonation wave. The theory and numerical simulations of the flame acceleration and the new physical mechanism of DDT are in complete agreement with the experimentally observed flame acceleration, shock formation, and DDT in a hydrogen-oxygen gas mixture.

  6. The processing of alcohols, hydrocarbons and ethers to produce hydrogen for a PEMFC for transportation applications

    SciTech Connect (OSTI)

    Dams, R.A.J.; Hayter, P.R.; Moore, S.C. [Wellman CJB Limited, Portsmouth (United Kingdom)

    1997-12-31T23:59:59.000Z

    Wellman CJB Limited is involved in a number of projects to develop fuel processors to provide a hydrogen-rich fuel in Proton Exchange Membrane Fuel Cells (PEMFC) systems for transportation applications. This work started in 1990 which resulted in the demonstration of 10kW PEMFC system incorporating a methanol reformer and catalytic gas clean-up system. Current projects include: The development of a compact fast response methanol reformer and gas clean-up system for a motor vehicle; Reforming of infrastructure fuels including gasoline, diesel, reformulated fuel gas and LPG to produce a hydrogen rich gas for PEMFC; Investigating the potential of dimethylether (DME) as source of hydrogen rich gas for PEMFCs; The use of thin film palladium diffusers to produce a pure hydrogen stream from the hydrogen rich gas from a reformer; and Processing of naval logistic fuels to produce a hydrogen rich gas stream for PEMFC power system to replace diesel generators in surface ships. This paper outlines the background to these projects and reports their current status.

  7. Carbon and oxygen stable isotopes in the Toa Baja Well, Puerto Rico: implications for burial diagenesis and hydrocarbon generation

    E-Print Network [OSTI]

    Gonzalez, Luis A.

    1991-03-01T23:59:59.000Z

    that the bulk of the sediment pile has not been exposed to temperatures above the oil window and possibly hydrocarbons have been generated deeper in the basin....

  8. New type of microengine using internal combustion of hydrogen and oxygen

    E-Print Network [OSTI]

    Vitaly B. Svetovoy; Remco G. P. Sanders; Kechun Ma; Miko C. Elwenspoek

    2014-02-27T23:59:59.000Z

    Microsystems become part of everyday life but their application is restricted by lack of strong and fast motors (actuators) converting energy into motion. For example, widespread internal combustion engines cannot be scaled down because combustion reactions are quenched in a small space. Here we present an actuator with the dimensions 100x100x5 um^3 that is using internal combustion of hydrogen and oxygen as part of its working cycle. Water electrolysis driven by short voltage pulses creates an extra pressure of 0.5-4 bar for a time of 100-400 us in a chamber closed by a flexible membrane. When the pulses are switched off this pressure is released even faster allowing production of mechanical work in short cycles. We provide arguments that this unexpectedly fast pressure decrease is due to spontaneous combustion of the gases in the chamber. This actuator is the first step to truly microscopic combustion engines.

  9. Reforming of Liquid Hydrocarbons in a Novel Hydrogen-Selective Membrane-Based Fuel Processor

    SciTech Connect (OSTI)

    Shamsuddin Ilias

    2006-03-10T23:59:59.000Z

    In this work, asymmetric dense Pd/porous stainless steel composite membranes were fabricated by depositing palladium on the outer surface of the tubular support. The electroless plating method combined with an osmotic pressure field was used to deposit the palladium film. Surface morphology and microstructure of the composite membranes were characterized by SEM and EDX. The SEM and EDX analyses revealed strong adhesion of the plated pure palladium film on the substrate and dense coalescence of the Pd film. Membranes were further characterized by conducting permeability experiments with pure hydrogen, nitrogen, and helium gases at temperatures from 325 to 450 C and transmembrane pressure differences from 5 to 45 psi. The permeation results showed that the fabricated membranes have both high hydrogen permeability and selectivity. For example, the hydrogen permeability for a composite membrane with a 20 {micro}m Pd film was 3.02 x 10{sup -5} moles/m{sup 2}.s.Pa{sup 0.765} at 450 C. Hydrogen/nitrogen selectivity for this composite membrane was 1000 at 450 C with a transmembrane pressure difference of 14.7 psi. Steam reforming of methane is one of the most important chemical processes in hydrogen and syngas production. To investigate the usefulness of palladium-based composite membranes in membrane-reactor configuration for simultaneous production and separation of hydrogen, steam reforming of methane by equilibrium shift was studied. The steam reforming of methane using a packed-bed inert membrane tubular reactor (PBIMTR) was simulated. A two-dimensional pseudo-homogeneous reactor model with parallel flow configuration was developed for steam reforming of methane. The shell volume was taken as the feed and sweep gas was fed to the inside of the membrane tube. Radial diffusion was taken into account for concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system and then solved by finite difference method with appropriate boundary and initial conditions. An iterative scheme was used to obtain a converged solution. Membrane reactor performance was compared to that in a traditional non-membrane packed-bed reactor (PBR). Their performances were also compared with thermodynamic equilibrium values achievable in a conventional non-membrane reactor. Numerical results of the models show that the methane conversions in the PBIMTR are always higher than that in the PBR, as well as thermodynamic equilibrium conversions. For instance, at a reaction pressure of 6 atm, a temperature of 650 C, a space velocity of 900/16.0 SCCM/gm{sub cat}, a steam to methane molar feed ratio of 3.0, a sweep ratio of 0.15, the conversion in the membrane reactor is about 86.5%, while the conversion in the non-membrane reactor is about 50.8%. The corresponding equilibrium conversion is about 56.4%. The effects on the degree of conversion and hydrogen yield were analyzed for different parameters such as temperature, reactor pressure, feed and sweep flow rate, feed molar ratio, and space time. From the analysis of the model results, it is obvious that the membrane reactor operation can be optimized for conversion or yield through the choice of proper operating and design parameters. Comparisons with available literature data for both membrane and non-membrane reactors showed a good agreement.

  10. System and method for controlling hydrogen elimination during carbon nanotube synthesis from hydrocarbons

    DOE Patents [OSTI]

    Reilly, Peter T. A. (Knoxville, TN)

    2010-03-23T23:59:59.000Z

    A system and method for producing carbon nanotubes by chemical vapor deposition includes a catalyst support having first and second surfaces. The catalyst support is capable of hydrogen transport from the first to the second surface. A catalyst is provided on the first surface of the catalyst support. The catalyst is selected to catalyze the chemical vapor deposition formation of carbon nanotubes. A fuel source is provided for supplying fuel to the catalyst.

  11. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect (OSTI)

    None

    2010-07-15T23:59:59.000Z

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  12. Nanoparticulate-catalyzed oxygen transfer processes

    DOE Patents [OSTI]

    Hunt, Andrew T. (Atlanta, GA); Breitkopf, Richard C. (Dunwoody, GA)

    2009-12-01T23:59:59.000Z

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  13. Method of controlling injection of oxygen into hydrogen-rich fuel cell feed stream

    DOE Patents [OSTI]

    Meltser, Mark Alexander (Pittsford, NY); Gutowski, Stanley (Pittsford, NY); Weisbrod, Kirk (Los Alamos, NM)

    2001-01-01T23:59:59.000Z

    A method of operating a H.sub.2 --O.sub.2 fuel cell fueled by hydrogen-rich fuel stream containing CO. The CO content is reduced to acceptable levels by injecting oxygen into the fuel gas stream. The amount of oxygen injected is controlled in relation to the CO content of the fuel gas, by a control strategy that involves (a) determining the CO content of the fuel stream at a first injection rate, (b) increasing the O.sub.2 injection rate, (c) determining the CO content of the stream at the higher injection rate, (d) further increasing the O.sub.2 injection rate if the second measured CO content is lower than the first measured CO content or reducing the O.sub.2 injection rate if the second measured CO content is greater than the first measured CO content, and (e) repeating steps a-d as needed to optimize CO consumption and minimize H.sub.2 consumption.

  14. Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars

    DOE Patents [OSTI]

    Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

    2005-11-15T23:59:59.000Z

    Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as methanol, glycerol, sugars (e.g. glucose and xylose), or sugar alcohols (e.g. sorbitol). The method takes place in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

  15. LIFE Chamber Chemical Equilibrium Simulations with Additive Hydrogen, Oxygen, and Nitrogen

    SciTech Connect (OSTI)

    DeMuth, J A; Simon, A J

    2009-09-03T23:59:59.000Z

    In order to enable continuous operation of a Laser Inertial confinement Fusion Energy (LIFE) engine, the material (fill-gas and debris) in the fusion chamber must be carefully managed. The chamber chemical equilibrium compositions for post-shot mixtures are evaluated to determine what compounds will be formed at temperatures 300-5000K. It is desired to know if carbon and or lead will deposit on the walls of the chamber, and if so: at what temperature, and what elements can be added to prevent this from happening. The simulation was conducted using the chemical equilibrium solver Cantera with a Matlab front-end. Solutions were obtained by running equilibrations at constant temperature and constant specific volume over the specified range of temperatures. It was found that if nothing is done, carbon will deposit on the walls once it cools to below 2138K, and lead below 838K. Three solutions to capture the carbon were found: adding pure oxygen, hydrogen/nitrogen combo, and adding pure nitrogen. The best of these was the addition of oxygen which would readily form CO at around 4000K. To determine the temperature at which carbon would deposit on the walls, temperature solutions to evaporation rate equations needed to be found. To determine how much carbon or any species was in the chamber at a given time, chamber flushing equations needed to be developed. Major concerns are deposition of carbon and/or oxygen on the tungsten walls forming tungsten oxides or tungsten carbide which could cause embrittlement and cause failure of the first wall. Further research is needed.

  16. Hydrogenation of carbonaceous materials

    DOE Patents [OSTI]

    Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

    1980-01-01T23:59:59.000Z

    A method for reacting pulverized coal with heated hydrogen-rich gas to form hydrocarbon liquids suitable for conversion to fuels wherein the reaction involves injection of pulverized coal entrained in a minimum amount of gas and mixing the entrained coal at ambient temperature with a separate source of heated hydrogen. In accordance with the present invention, the hydrogen is heated by reacting a small portion of the hydrogen-rich gas with oxygen in a first reaction zone to form a gas stream having a temperature in excess of about 1000.degree. C. and comprising a major amount of hydrogen and a minor amount of water vapor. The coal particles then are reacted with the hydrogen in a second reaction zone downstream of the first reaction zone. The products of reaction may be rapidly quenched as they exit the second reaction zone and are subsequently collected.

  17. Process for converting light alkanes to higher hydrocarbons

    DOE Patents [OSTI]

    Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA)

    1988-01-01T23:59:59.000Z

    A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.

  18. POLYCYCLIC AROMATIC HYDROCARBONS, IONIZED GAS, AND MOLECULAR HYDROGEN IN BRIGHTEST CLUSTER GALAXIES OF COOL-CORE CLUSTERS OF GALAXIES

    SciTech Connect (OSTI)

    Donahue, Megan; Mark Voit, G.; Hoffer, Aaron [Physics and Astronomy Department, Michigan State University, East Lansing, MI 48824 (United States); De Messieres, Genevieve E.; O'Connell, Robert W. [Astronomy Department, University of Virginia, Charlottesville, VA (United States); McNamara, Brian R. [Department of Physics and Astronomy, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1 (Canada); Nulsen, Paul E. J., E-mail: donahue@pa.msu.edu, E-mail: voit@pa.msu.edu, E-mail: hofferaa@msu.edu [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2011-05-01T23:59:59.000Z

    We present measurements of 5-25 {mu}m emission features of brightest cluster galaxies (BCGs) with strong optical emission lines in a sample of nine cool-core clusters of galaxies observed with the Infrared Spectrograph on board the Spitzer Space Telescope. These systems provide a view of dusty molecular gas and star formation, surrounded by dense, X-ray-emitting intracluster gas. Past work has shown that BCGs in cool-core clusters may host powerful radio sources, luminous optical emission-line systems, and excess UV, while BCGs in other clusters never show this activity. In this sample, we detect polycyclic aromatic hydrocarbons (PAHs), extremely luminous, rotationally excited molecular hydrogen line emission, forbidden line emission from ionized gas ([Ne II] and [Ne III]), and infrared continuum emission from warm dust and cool stars. We show here that these BCGs exhibit more luminous forbidden neon and H{sub 2} rotational line emission than star-forming galaxies with similar total infrared luminosities, as well as somewhat higher ratios of 70 {mu}m/24 {mu}m luminosities. Our analysis suggests that while star formation processes dominate the heating of the dust and PAHs, a heating process consistent with suprathermal electron heating from the hot gas, distinct from star formation, is heating the molecular gas and contributing to the heating of the ionized gas in the galaxies. The survival of PAHs and dust suggests that dusty gas is somehow shielded from significant interaction with the X-ray gas.

  19. Effects of hydrogen anneals on oxygen deficient SrTio3-x single crystals

    E-Print Network [OSTI]

    Jalan, Bharat; Engel-Herbert, Roman; Mates, Thomas E.; Stemmer, Susanne

    2008-01-01T23:59:59.000Z

    have suggested that hydrogen may also be substituted on thethat the in?uence of hydrogen anneals on the conductivity ofmay be passivated by the hydrogen anneal. A complex Author

  20. Fossil fuel and hydrocarbon conversion using hydrogen-rich plasmas. Topical report February 1994--February 1995

    SciTech Connect (OSTI)

    NONE

    1995-02-01T23:59:59.000Z

    Experiments were made on use of H and CH plasmas for converting waste materials and heavy oils to H-rich transportation fuels. Batch and continuous experiments were conducted with an industrial microwave generator and a commercial microwave oven. A continuously circulating reactor was constructed for conducting experiments on flowing oils. Experiments on decomposition of scrap tires showed that microwave plasmas can be used to decompose scrap tires into potentially useful liquid products. In a batch experiment using a commercial microwave oven, about 20% of the tire was converted to liquid products in about 9 minutes. Methane was decomposed in a microwave plasma to yield a liquid products composed of various compound types; GC/MS analyses identified unsaturated compounds including benzene, toluene, ethyl benzene, methyl and ethyl naphthalene, small amounts of larger aromatic rings, and olefinic compounds. Experiments on a crude oil in a continuously flowing reactor showed that distillate materials are produced using H and CH plasmas. Also, the recycle oils had an overall carbon aromaticity lower than that of starting feed material, indicating that some hydrogenation and methanation had taken place in the recycle oils.

  1. Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/

    DOE Patents [OSTI]

    Robinson, P.R.; Bamberger, C.E.

    1980-02-08T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  2. Hyperspherical elliptic coordinates treatment of muon transfer from muonic hydrogen to atomic oxygen

    E-Print Network [OSTI]

    Arnaud Dupays; Bruno Lepetit; J. Alberto Beswick; Carlo Rizzo; Dimitar Bakalov

    2006-12-20T23:59:59.000Z

    Quantum-mechanical calculations of muon transfer between muonic hydrogen and an oxygen nuclei for $s$ waves and collision energies in the range $10^{-3} - 10^3$ eV, are presented. Close-coupling time-independent Schr\\"odinger equations, written in terms of hyperspherical elliptic coordinates were integrated along the hyper-radius to obtain the partial and total muon-transfer probabilities. The results show the expected Wigner-Bethe threshold behavior up to collision energies of the order of $10^{-2}$ eV and pronounced maxima at $10^2$ eV which can be interpreted in terms of crossings between potential energy curves corresponding to the entrance channel state $(\\mu p)_{1s} + \\mO$ and two product channels which asymptotically correlate to $p + (\\mO\\mu)_{n=5,6}$. The population of the final states with different orbital angular momenta is found to be essentially independent of energy in the range considered in this work. This can be attributed to a strong selection rule for the conservation of the quantum number associated to one of the elliptic hyperangles.

  3. Chemical Engineering Journal 93 (2003) 6980 Production of COx-free hydrogen for fuel cells via step-wise hydrocarbon

    E-Print Network [OSTI]

    Goodman, Wayne

    Chemical Engineering Journal 93 (2003) 69­80 Production of COx-free hydrogen for fuel cells via Abstract The stringent COx-free hydrogen requirement for the current low temperature fuel cells has Hydrogen is the most promising fuel for the low temper- ature fuel cells, however, chemical processes

  4. Effect of the type of carrier on the properties of cobalt catalysts in the synthesis of aliphatic hydrocarbons from carbon monoxide and hydrogen

    SciTech Connect (OSTI)

    Lapidus, A.L.; Jem, H.C.; Krylova, A.Y.

    1983-04-10T23:59:59.000Z

    The properties of catalysts used in the synthesis of hydrocarbons from CO and H/sub 2/ are determined to a significant degree by the carriers used in their preparation. This paper deals with a study of the effect of the type of carrier on the properties of cobalt-based catalysts in the synthesis of aliphatic hydrocarbons from CO and H/sub 2/. Co catalysts that are active in the synthesis of hydrocarbons from CO and H/sub 2/ are those on which the adsorption of H/sub 2/ exceeds 3.10/sup -2/ mmole/g Co and the adsorptin of carbon monoxide exceeds 7.10/sup -2/ mmole/g Co. Carbon monoxide and hydrogen are adsorbed on active catalysts in weakly bound forms. A mechanism is proposed for the formatin of an active center and the adsorption of carbon monoxide on Co-catalysts which includes the appearance of a partial positive charge on the cobalt atom.

  5. Plasma Reforming And Partial Oxidation Of Hydrocarbon Fuel Vapor To Produce Synthesis Gas And/Or Hydrogen Gas

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2004-10-19T23:59:59.000Z

    Methods and systems are disclosed for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.

  6. Plasma reforming and partial oxidation of hydrocarbon fuel vapor to produce synthesis gas and/or hydrogen gas

    DOE Patents [OSTI]

    Kong, Peter C.; Detering, Brent A.

    2003-08-19T23:59:59.000Z

    Methods and systems for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.

  7. Biological Conversion of Sugars to Hydrocarbons Technology Pathway

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enzymes Acid + Caustic Wastewater Treatment Process Heat and Power Integration Biogas + Sludge Fuel Finishing (hydroprocessing, as needed) Electricity Hydrogen Hydrocarbon...

  8. Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2001-01-01T23:59:59.000Z

    Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

  9. Ab-initio study of hydrogen doping and oxygen vacancy at anatase TiO{sub 2} surface

    SciTech Connect (OSTI)

    Sotoudeh, M.; Mohammadizadeh, M. R., E-mail: zadeh@ut.ac.ir [Superconductivity Research Laboratory (SRL), Department of Physics, University of Tehran, North Kargar Ave., P.O. Box 14395-547, Tehran (Iran, Islamic Republic of); Hashemifar, S. J. [Departement of Physics, Isfahan University of Technology, 84156 83111, Isfahan (Iran, Islamic Republic of)] [Departement of Physics, Isfahan University of Technology, 84156 83111, Isfahan (Iran, Islamic Republic of); Abbasnejad, M. [Department of Physics, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of)] [Department of Physics, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of)

    2014-02-15T23:59:59.000Z

    Density functional–pseudopotential calculations were performed to study the effects of hydrogen doping and oxygen vacancy, both individually and together, on the electronic structure and stability of (001) surface of TiO{sub 2} in the anatase phase. Based on our calculations, O/Ti termination is the most stable one, and it appears that p-states of deep and surface O atoms and d-orbitals of surface Ti atoms have roles in the valence band and, the conduction band comes from the d-orbitals of deep Ti atoms. Although, no considerable change was seen during H doping, a mid-gap state appeared below the conduction band in the O vacancy configuration. In the framework of ab-initio atomistic thermodynamics, we argue that the anatase TiO{sub 2} prefers a defected O layer termination in the [001] direction. The obtained electronic structures indicate that H doping in the bulk creates the empty mid-gap state below the conduction band and hence decreases the band gap of the system. This phenomenon may explain the enhanced photocatalytic activity of the anatase TiO{sub 2} (001) surface after hydrogenation.

  10. Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

    E-Print Network [OSTI]

    VanVeller, Brett

    The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

  11. Final Report, "Molecular Design of Hydrocarbon Oxidation Catalytic Processes"

    SciTech Connect (OSTI)

    Professor Francisco Zaera

    2007-08-09T23:59:59.000Z

    The main goal of this project had been to use model systems to correlate selectivities in partial oxidation catalysis with the presence of specific sites on the surface of the catalyst. Extensive work was performed this year on characterizing oxygen-treated nickel surfaces by chemical means. Specifically, the surface chemistry of ammonia coadsorbed with atomic oxygen on Ni(110) single-crystal surfaces was studied by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). It was determined that at intermediate oxygen coverages direct ammonia adsorption on nickel sites is suppressed, but a new high-temperature reaction regime is generated at 400 K where NHx surface fragments are rehydrogenated concurrently with the production of water and molecular hydrogen. The extensive isotope scrambling and hydrogen transfer seen from nitrogen- to oxygen-containing surface intermediates, and the optimum yields seen for this 400 K state at intermediate oxygen coverages, strongly suggest the direct interaction of the adsorbed ammonia with oxygen atoms at the end of the –Ni–O- rows that form upon reconstruction of the surface. Hydrogen transfer between ammonia and oxygen appears to take place directly via hydrogen bonding, and to be reversible but biased towards water formation. An equilibrium is reached between the produced water and the reacting surface oxygen and hydrogen. The strong influence of the OH surface groups on the thermal chemistry of the adsorbed ammonia was interpreted in terms of the adsorbing geometry of the OH groups on the surface, and of hydrogen bonding between adsorbed OH and NH3 species. In terms of alcohol reactivity, the adsorption of 2-iodoethanol, a precursor for the preparation of 2-hydroxyethyl and oxametallacycle surface species, was found to lead to two configurations involving either just the iodine atom or both iodine and hydroxyl ends of the molecule. A complex chemical behavior starts around 140 K with the production of small amounts of ethylene and water, most likely via the concerted decomposition or disproportionation of the adsorbed molecular species. The bulk of the 2-iodoethanol decomposes at about 150 K via an initial carbon-iodine scission to form –O(H)CH2CH2– (~80%) and 2-hydroxyethyl (~20%) intermediates. Two competing reactions are involved with the subsequent conversion of the 2-hydroxyethyl species around 160 K, a reductive elimination with surface hydrogen to yield ethanol, and a ?-H elimination to surface vinyl alcohol. The –O(H)CH2CH2–, on the other hand, dehydrogenates to a –OCH2CH2– oxametallacycle species about the same temperature. Both 2-hydroxyethyl and oxametallacycle species tautomerize to acetaldehyde, around 210 K and above 250 K, respectively, and some of that acetaldehyde desorbs while the rest decomposes to hydrogen and carbon monoxide. We contend that a better understanding of the surface chemistry of oxygen-containing surfaces can lead to better selectivities in catalysis. This is arguably the most important issue in the field of catalysis in the near future, and one that impacts several technologies of interest to DOE such as the manufacturing of speciality chemicals and the control and removal of pollutants. Additional work was performed on the characterization of the chemistry of methyl and methylene adsorbed species on oxygen-treated nickel surfaces. Complex chemistry was observed involving not only hydrogenation and dehydrogenation steps, but also C-C couplings and methylene insertions to produce heavier hydrocarbons, and oxygen insertion reactions that yield oxygenates. Finally, a dual titration technique employing xenon and a chemically sensitive probe was developed to identify minority catalytic sites on oxide surfaces. In the case of oxygen-treated Ni(110) single crystals, it was found that both hydrogen transfer with adsorbed water or ammonia and certain hydrocarbon hydrogenation reactions take place at the end of the –Ni–O rows that form in this system. Carbon and nitrogen oxides, on the other hand, display no pre

  12. Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report

    SciTech Connect (OSTI)

    Sinskey, Anthony J. [MIT] [MIT; Worden, Robert Mark [Michigan State University MSU] [Michigan State University MSU; Brigham, Christopher [MIT] [MIT; Lu, Jingnan [MIT] [MIT; Quimby, John Westlake [MIT] [MIT; Gai, Claudia [MIT] [MIT; Speth, Daan [MIT] [MIT; Elliott, Sean [Boston University] [Boston University; Fei, John Qiang [MIT] [MIT; Bernardi, Amanda [MIT] [MIT; Li, Sophia [MIT] [MIT; Grunwald, Stephan [MIT] [MIT; Grousseau, Estelle [MIT] [MIT; Maiti, Soumen [MSU] [MSU; Liu, Chole [MSU] [MSU

    2013-12-16T23:59:59.000Z

    This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation Calvin–Benson–Bassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide into complex cellular molecules using the energy from hydrogen. In this research project, engineered strains of R. eutropha redirected the excess carbon from PHB storage into the production of isobutanol and 3-methyl-1-butanol (branched-chain higher alcohols). These branched-chain higher alcohols can be used directly as substitutes for fossil-based fuels and are seen as alternative biofuels to ethanol and biodiesel. Importantly, these alcohols have approximately 98 % of the energy content of gasoline, 17 % higher than the current gasoline additive ethanol, without impacting corn market production for feed or food. Unlike ethanol, these branched-chain alcohols have low vapor pressure, hygroscopicity, and water solubility, which make them readily compatible with the existing pipelines, gasoline pumps, and engines in our transportation infrastructure. While the use of alternative energies from solar, wind, geothermal, and hydroelectric has spread for stationary power applications, these energy sources cannot be effectively or efficiently employed in current or future transportation systems. With the ongoing concerns of fossil fuel availability and price stability over the long term, alternative biofuels like branched-chain higher alcohols hold promise as a suitable transportation fuel in the future. We showed in our research that various mutant strains of R. eutropha with isobutyraldehyde dehydrogenase activity, in combination with the overexpression of plasmid-borne, native branched-chain amino acid biosynthesis pathway genes and the overexpression of heterologous ketoisovalerate decarboxylase gene, would produce isobutanol and 3-methyl-1-butanol when initiated during nitrogen or phosphorus limitation. Early on, we isolated one mutant R. eutropha strain which produced over 180 mg/L branched-chain alcohols in flask culture while being more tolerant of isobutanol toxicity. After the targeted elimination of genes encoding several potential carbon sinks (ilvE, bkdAB, and aceE), the production titer of the improved to 270 mg/L isobutanol and 40 mg/L 3-methyl-1-butanol.

  13. Chemical Kinetics of Hydrocarbon Ignition in Practical Combustion Systems

    SciTech Connect (OSTI)

    Westbrook, C.K.

    2000-07-07T23:59:59.000Z

    Chemical kinetic factors of hydrocarbon oxidation are examined in a variety of ignition problems. Ignition is related to the presence of a dominant chain branching reaction mechanism that can drive a chemical system to completion in a very short period of time. Ignition in laboratory environments is studied for problems including shock tubes and rapid compression machines. Modeling of the laboratory systems are used to develop kinetic models that can be used to analyze ignition in practical systems. Two major chain branching regimes are identified, one consisting of high temperature ignition with a chain branching reaction mechanism based on the reaction between atomic hydrogen with molecular oxygen, and the second based on an intermediate temperature thermal decomposition of hydrogen peroxide. Kinetic models are then used to describe ignition in practical combustion environments, including detonations and pulse combustors for high temperature ignition, and engine knock and diesel ignition for intermediate temperature ignition. The final example of ignition in a practical environment is homogeneous charge, compression ignition (HCCI) which is shown to be a problem dominated by the kinetics intermediate temperature hydrocarbon ignition. Model results show why high hydrocarbon and CO emissions are inevitable in HCCI combustion. The conclusion of this study is that the kinetics of hydrocarbon ignition are actually quite simple, since only one or two elementary reactions are dominant. However, there are many combustion factors that can influence these two major reactions, and these are the features that vary from one practical system to another.

  14. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04T23:59:59.000Z

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  15. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fractionation Hydrogen Acid, Caustic, Enzymes Wastewater Treatment Insoluble solids Biogas + Sludge Process Heat and Power Integration Corn Stover Hydrocarbon Biofuels (i.e....

  16. Hydrogenation apparatus

    DOE Patents [OSTI]

    Friedman, J.; Oberg, C. L.; Russell, L. H.

    1981-06-23T23:59:59.000Z

    Hydrogenation reaction apparatus is described comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1,100 to 1,900 C, while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products. 2 figs.

  17. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology

    SciTech Connect (OSTI)

    Swanson, Michael; Henderson, Ann

    2012-04-01T23:59:59.000Z

    The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

  18. Low-cost process for hydrogen production

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Bauer, Hans F. (Morgantown, WV); Grimes, Robert W. (Laramie, WY)

    1993-01-01T23:59:59.000Z

    A method is provided for producing hydrogen and carbon black from hydrocarbon gases comprising mixing the hydrocarbon gases with a source of carbon and applying radiofrequency energy to the mixture. The hydrocarbon gases and the carbon can both be the products of gasification of coal, particularly the mild gasification of coal. A method is also provided for producing hydrogen an carbon monoxide by treating a mixture of hydrocarbon gases and steam with radio-frequency energy.

  19. Low-cost process for hydrogen production

    DOE Patents [OSTI]

    Cha, C.H.; Bauer, H.F.; Grimes, R.W.

    1993-03-30T23:59:59.000Z

    A method is provided for producing hydrogen and carbon black from hydrocarbon gases comprising mixing the hydrocarbon gases with a source of carbon and applying radiofrequency energy to the mixture. The hydrocarbon gases and the carbon can both be the products of gasification of coal, particularly the mild gasification of coal. A method is also provided for producing hydrogen and carbon monoxide by treating a mixture of hydrocarbon gases and steam with radio-frequency energy.

  20. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

    DOE Patents [OSTI]

    Dumesic, James A. (Verona, WI); Ruiz, Juan Carlos Serrano (Madison, WI); West, Ryan M. (Madison, WI)

    2012-04-03T23:59:59.000Z

    Described is a method to make liquid chemicals, such as functional intermediates, solvents, and liquid fuels from biomass-derived cellulose. The method is cascading; the product stream from an upstream reaction can be used as the feedstock in the next downstream reaction. The method includes the steps of deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be converted to a mixture of n-butenes. The pentanoic acid so formed can be further reacted to yield a host of valuable products. For example, the pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes. Alternatively, the nonene may be isomerized to yield a mixture of branched olefins, which can be hydrogenated to yield a mixture of branched alkanes. The mixture of n-butenes formed from .gamma.-valerolactone can also be subjected to isomerization and oligomerization to yield olefins in the gasoline, jet and Diesel fuel ranges.

  1. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

    DOE Patents [OSTI]

    Dumesic, James A [Verona, WI; Ruiz, Juan Carlos Serrano [Madison, WI; West, Ryan M [Madison, WI

    2014-01-07T23:59:59.000Z

    Described is a method to make liquid chemicals. The method includes deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be conveted to a mixture of n-butenes. The pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes.

  2. Apparatus for hydrocarbon extraction

    DOE Patents [OSTI]

    Bohnert, George W.; Verhulst, Galen G.

    2013-03-19T23:59:59.000Z

    Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

  3. anhydrous hydrogen fluoride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    effect of Hydrogen Booster System on exhaust gases emissions of an internal combustion engine. The hydrogen booster produces hydrogen and oxygen using six water fuel cells and...

  4. Mixed Ionic and Electonic Conductors for Hydrogen Generation and Separation: A New Approach

    SciTech Connect (OSTI)

    Srikanth Gopalan

    2006-12-31T23:59:59.000Z

    Composite mixed conductors comprising one electronic conducting phase, and one ionic conducting phase (MIECs) have been developed in this work. Such MIECs have applications in generating and separating hydrogen from hydrocarbon fuels at high process rates and high purities. The ionic conducting phase comprises of rare-earth doped ceria and the electronic conducting phase of rare-earth doped strontium titanate. These compositions are ideally suited for the hydrogen separation application. In the process studied in this project, steam at high temperatures is fed to one side of the MIEC membrane and hydrocarbon fuel or reformed hydrocarbon fuel to the other side of the membrane. Oxygen is transported from the steam side to the fuel side down the electrochemical potential gradient thereby enriching the steam side flow in hydrogen. The remnant water vapor can then be condensed to obtain high purity hydrogen. In this work we have shown that two-phase MIECs comprising rare-earth ceria as the ionic conductor and doped-strontium titanate as the electronic conductor are stable in the operating environment of the MIEC. Further, no adverse reaction products are formed when these phases are in contact at elevated temperatures. The composite MIECs have been characterized using a transient electrical conductivity relaxation technique to measure the oxygen chemical diffusivity and the surface exchange coefficient. Oxygen permeation and hydrogen generation rates have been measured under a range of process conditions and the results have been fit to a model which incorporates the oxygen chemical diffusivity and the surface exchange coefficient from the transient measurements.

  5. Hydrocarbon conversion catalysts

    SciTech Connect (OSTI)

    Hoek, A.; Huizinga, T.; Maxwell, I.E.

    1989-08-15T23:59:59.000Z

    This patent describes a process for hydrocracking hydrocarbon oils into products of lower average molecular weight and lower average boiling point. It comprises contacting a hydrocarbon oil at a temperature between 250{sup 0}C and 500{sup 0}C and a pressure up to 300 bar in the presence of hydrogen with a catalyst consisting essentially of a Y zeolite modified to have a unit cell size below 24.35A, a water absorption capacity (at 25{sup 0}C and a rho/rho/sub o/ value of 0.2) of at least 8% by weight of the zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm; an alumina binder and at least one hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal and mixtures thereof.

  6. System for the co-production of electricity and hydrogen

    DOE Patents [OSTI]

    Pham, Ai Quoc (San Jose, CA); Anderson, Brian Lee (Lodi, CA)

    2007-10-02T23:59:59.000Z

    Described herein is a system for the co-generation of hydrogen gas and electricity, wherein the proportion of hydrogen to electricity can be adjusted from 0% to 100%. The system integrates fuel cell technology for power generation with fuel-assisted steam-electrolysis. A hydrocarbon fuel, a reformed hydrocarbon fuel, or a partially reformed hydrocarbon fuel can be fed into the system.

  7. E-Print Network 3.0 - advanced nuclear-electrolytic hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of H2 from Hydrocarbon Fuels Novel Catalytic... ) Fossil-Based Hydrogen Production Praxair Praxair ... Source: DOE Office of Energy Efficiency and Renewable Energy, Hydrogen,...

  8. Deep desulfurization of hydrocarbon fuels

    DOE Patents [OSTI]

    Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

    2012-04-17T23:59:59.000Z

    The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

  9. Hydrocarbon composition of crude oils near the Caspian depression

    SciTech Connect (OSTI)

    Botneva, T.A.; Khramova, E.V.; Nekhamkina, L.G.; Polyakova, A.A.

    1983-01-01T23:59:59.000Z

    The structural-group composition of hydrocarbons of Mesozoic crude oils near the Caspian depression was investigated by mass-spectrometry, followed by the analysis of the mass-spectra using a computer. The distribution of naphthenic hydrocarbons, according to the number of rings and of aromatic hydrocarbons, according to the degree of hydrogen unsaturation is similar for all the crude oils examined. The hydrocarbon composition of Mesozoic crude oils is characterized by a reduction in the content of aliphatic hydrocarbons and alkyl benzenes.

  10. Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil

    DOE Patents [OSTI]

    Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

  11. E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

  12. Palladium-Cobalt Particles As Oxygen-Reduction Electrocatalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Palladium-Cobalt Particles As Oxygen-Reduction Electrocatalysts Brookhaven National Laboratory...

  13. Electron-Stimulated Production of Molecular Oxygen in Amorphous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precursor Transport Through the Hydrogen Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water on Pt(111): Precursor Transport Through the Hydrogen...

  14. Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels

    E-Print Network [OSTI]

    Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

  15. Naphthenic hydrocarbons

    SciTech Connect (OSTI)

    Yen, T.F.; Kuo, J.F.; Chilingarian, G.V.

    1987-01-01T23:59:59.000Z

    An important type of naphthenic hydrocarbons is the monocyclic type, (k/sub 2/, 0, 0). In this instance the number of carbon atoms, n = k/sub 2/, and a formula, C/sub n/H/sub 2n/, can be written where H/C = 2. The value n can vary from 2 to infinity. In the case of n = 2, it is ethylene (I) (2-membered cyclic ring); n = 3, cyclopropane (II) (3-membered cyclic ring); n = 4, cyclobutane (III) (4-membered cyclic ring); etc. If the monocyclic naphthenic is planar, then the bond angle theta can be expressed as theta = (1 - 2/n)..pi.. where n is the number of carbon atoms. However, the tetrahedron angle of the carbon atom being phi = cos/sup -1/ (- 1/3).

  16. Plasma-assisted conversion of solid hydrocarbon to diamond

    DOE Patents [OSTI]

    Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

    1996-01-01T23:59:59.000Z

    A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

  17. Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

    DOE Patents [OSTI]

    Kung, H.H.; Chaar, M.A.

    1988-10-11T23:59:59.000Z

    Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

  18. argon-seeded hydrogen sheet: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    effect of Hydrogen Booster System on exhaust gases emissions of an internal combustion engine. The hydrogen booster produces hydrogen and oxygen using six water fuel cells and...

  19. attenuates hydrogen peroxide-induced: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    effect of Hydrogen Booster System on exhaust gases emissions of an internal combustion engine. The hydrogen booster produces hydrogen and oxygen using six water fuel cells and...

  20. Executive Summaries for the Hydrogen Storage Materials Center...

    Broader source: Energy.gov (indexed) [DOE]

    bonds. Some work had been done on 'activated' hydrocarbons systems by researchers at Air Products; and the release of hydrogen from ammonia borane was known largely through...

  1. Hydrogen recovery process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

    2000-01-01T23:59:59.000Z

    A treatment process for a hydrogen-containing off-gas stream from a refinery, petrochemical plant or the like. The process includes three separation steps: condensation, membrane separation and hydrocarbon fraction separation. The membrane separation step is characterized in that it is carried out under conditions at which the membrane exhibits a selectivity in favor of methane over hydrogen of at least about 2.5.

  2. Catalysts for synthesizing various short chain hydrocarbons

    DOE Patents [OSTI]

    Colmenares, Carlos (Alamo, CA)

    1991-01-01T23:59:59.000Z

    Method and apparatus (10), including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO.sub.2 aerogels doped with photochemically active uranyl ions (18) are fluidized in a fluidized-bed reactor (12) having a transparent window (16), by hydrogen and CO, C.sub.2 H.sub.4 or C.sub.2 H.sub.6 gas mixtures (20), and exposed to radiation (34) from a light source (32) external to the reactor (12), to produce the short chain hydrocarbons (36).

  3. Simulation of Nitrogen Emissions in a Premixed Hydrogen Flame Stabilized on a Low Swirl Burner

    E-Print Network [OSTI]

    Bell, John B.

    of fuels such as pure hydrogen and hydrogen-seeded hydrocarbon mixtures. However, many hydrogen-rich fuels in the context of a laboratory-scale low swirl burner fueled with a lean hydrogen-air mixture at atmospheric of burning lean hydrogen or hydrogen-enriched lean hydrocar- bon fuels (e.g., [2­5]). For these fuels

  4. Hydrogen, Fuel Infrastructure

    E-Print Network [OSTI]

    results of using hydrogen power, of course, will be energy independence for this nation... think about between hydrogen and oxygen generates energy, which can be used to power a car producing only water to taking these cars from laboratory to showroom so that the first car driven by a child born today could

  5. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013DepartmentAgenda for

  6. Hydrocarbon conversion process and catalysts

    SciTech Connect (OSTI)

    Hoek, A.; Huizinga, T.; Maxwell, I.E.

    1989-08-15T23:59:59.000Z

    This patent describes a process for hydrocracking hydrocarbon oils into products of lower average molecular weight and lower average boiling point. It comprises contacting hydrocarbon oil at a temperature between 250{sup 0}C and 500{sup 0}C and a pressure up to 300 bar in the presence of hydrogen with a catalyst consisting essentially of a Y zeolite modified to have a unit cell size below 24.40 A, a water adsorption capacity (at 25{sup 0}C and a rho/rho/sub o/ value of 0.2) of between 10% and 15% by weight of the zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm; am amorphous cracking component, a binder and at least one hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal and mixtures thereof.

  7. Recombinant hydrogen-producing cyanobacterium and uses thereof

    DOE Patents [OSTI]

    Xu, Qing; Smith, Hamilton O

    2014-10-14T23:59:59.000Z

    A recombinant cyanobacterium comprising an oxygen-tolerant, hydrogen-evolving hydrogenase, kit, and methods of use.

  8. Fuel-flexible partial oxidation reforming of hydrocarbons for automotive applications.

    SciTech Connect (OSTI)

    Ahmed, S.; Carter, J. D.; Kopasz, J. P.; Krumpelt, M.; Wilkenhoener, R.

    1999-06-07T23:59:59.000Z

    Micro-reactor tests indicate that our partial oxidation catalyst is fuel-flexible and can reform conventional (gasoline and diesel) and alternative (ethanol, methanol, natural gas) fuels to hydrogen rich product gases with high hydrogen selectivity. Alcohols are reformed at lower temperatures (< 600 C) while alkanes and unsaturated hydrocarbons require slightly higher temperatures. Cyclic hydrocarbons and aromatics have also been reformed at relatively low temperatures, however, a different mechanism appears to be responsible for their reforming. Complex fuels like gasoline and diesel, which are mixtures of a broad range of hydrocarbons, require temperatures of > 700 C for maximum hydrogen production.

  9. The Fundamental Role of Nano-Scale Oxide Films in the Oxidation of Hydrogen and the Reduction of Oxygen on Noble Metal Electrocatalysts

    SciTech Connect (OSTI)

    Digby Macdonald

    2005-04-15T23:59:59.000Z

    The derivation of successful fuel cell technologies requires the development of more effective, cheaper, and poison-resistant electrocatalysts for both the anode (H{sub 2} oxidation in the presence of small amounts of CO from the reforming of carbonaceous fuels) and the cathode (reduction of oxygen in the presence of carried-over fuel). The proposed work is tightly focused on one specific aspect of electrocatalysis; the fundamental role(s) played by nanoscale (1-2 nm thick) oxide (''passive'') films that form on the electrocatalyst surfaces above substrate-dependent, critical potentials, on charge transfer reactions, particularly at elevated temperatures (25 C < T < 200 C). Once the role(s) of these films is (are) adequately understood, we will then use this information to specify, at the molecular level, optimal properties of the passive layer for the efficient electrocatalysis of the oxygen reduction reaction.

  10. Kinetics and intermediate products in the interaction of straight-chain and cyclic hydrocarbon radicals with 9,10-Anthraquinone

    SciTech Connect (OSTI)

    Ladygin, B.V.; Revina, A.A.

    1986-04-01T23:59:59.000Z

    The authors use a pulse radiolysis technique with optical registration of the destruction of hydrocarbon radicals R in determining the rate constants for the interaction of cyclododecyl radicals and n-dodecyl radicals with 9,10-anthraquinone in the corresponding liquid hydrocarbons, at various temperatures. It is shown that in the presence of oxygen, hydrocarbon radicals with the quinone form oxygen-containing species that are capable of propagating the oxidation chain and regenerating the original quinone.

  11. Direct conversion of light hydrocarbon gases to liquid fuel

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  12. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenati...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on...

  13. Analysis of a direct methane conversion to high molecular weight hydrocarbons

    E-Print Network [OSTI]

    Al-Ghafran, Moh'd. J.

    2000-01-01T23:59:59.000Z

    Methane conversion to heavier hydrocarbons was studied using electrical furnaces and a plasma apparatus. The experiments were performed with pure methane for the electrical furnace experiments while pure methane and additions such as hydrogen...

  14. A study of the structure of the hydrocarbons of primary hard-coal tar

    SciTech Connect (OSTI)

    Platonov, V.V.; Gerasimova, N.I.; Ivleva, L.N.; Klyavina, O.A.; Vishnyakov, S.N.

    1985-01-01T23:59:59.000Z

    The hydrocarbons isolated from primary hard-coal (G/sub 6/ gas coal) tar have been investigated by a combination of physicochemical and chemical methods. It has been established that the hydrocarbons boiling up to 573 K are mainly aliphatic, hydroaromatic, and naphthenic and are aromatic only to a smaller degree. Molecular and presumable structural formulas of the oxygen compounds isolated from the 473-573 K hydrocarbon fraction have been derived.

  15. Process for partial oxidation of a hydrocarbon-containing fuel

    SciTech Connect (OSTI)

    Martens, F.J.A.; Hasenack, H.J.A.

    1988-12-06T23:59:59.000Z

    This patent describes a process for partial oxidation of a hydrocarbon-containing fuel comprising supplying an oxygen-containing gas and a hydrocarbon-containing fuel to a gasification zone through a concentric arrangement of three oxygen channels and one fuel channel, and oxidizing the fuel and producing auto-thermically a gaseous stream containing synthesis gas, the oxygen-containing gas being supplied through the central channel of the concentric arrangement at a velocity of 21-42 m/sec and through the first concentric channel encircling the central channel at a velocity of 60-120 m/sec, fuel being supplied through the second concentric channel encircling the first channel at a velocity of 3.0-3.8 m/sec, and oxygen-containing gas being supplied through the third concentric channel encircling the second channel at a velocity of 60-120 m/sec.

  16. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H. (Danville, CA)

    1986-01-01T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  17. The hydrogenation and dehydrogenation of C{sub 2}-C{sub 4} hydrocarbons on Pt(111) monitored in situ over 13 orders of magnitude in pressure with infrared-visible sum frequency generation

    SciTech Connect (OSTI)

    Cremer, P.S.

    1996-05-01T23:59:59.000Z

    The hydrogenation and dehydrogenation of ethylene, propylene, and isobutene were monitored in situ during heterogeneous catalysis over Pt(111) between 10{sup -10} Torr and 1000 Torr with infrared-visible sum frequency generation (SFG). SFG is a surface specific vibrational spectroscopy capable of achieving submonolayer sensitivity under reaction conditions in the presence of hundreds of Toff of reactants and products. Olefin dehydrogenation experiments were carried out with SFG under ultra high vacuum (UHV) conditions on the (111) crystal face of platinum Ethylene chemisorbed on Pt(111) below 230 K in the di-{sigma} bonded conformation (Pt-CH{sub 2}CH{sub 2}-Pt). Upon annealing the system to form the dehydrogenation product, ethylidyne (M=CCH{sub 3}), evidence was found for an ethylidene intermediate (M=CHCH{sub 3}) from its characteristic v{sub as}(CH{sub 3}) near 2960 cm{sup -1}. Hydrogenation of ethylene was carried out between 1 Toff and 700 Torr of H{sub 2} while the vibrational spectrum of surface species was monitored with SFG. Simultaneously, gas chromatography was used to obtain the turnover rate for the catalytic reaction, which could be correlated with the adsorbed intermediate concentration to determine the reaction rate per surface intermediate. Di-{sigma} bonded ethylene, {pi}-bonded ethylene, ethyl groups and ethylidyne resided on the surface during reaction. The mechanistic pathway for ethylene hydrogenation involved the stepwise hydrogenation of {pi}-bonded ethylene through an ethyl intermediate to ethane. The hydrogenation of propylene was carried out under the same conditions as ethylene. It was found that propylene hydrogenates from {pi}-bonded propylene through a 2-propyl intermediate to propane on Pt(111). The rate of reaction was approximately 50% slower than that of ethylene hydrogenation. Isobutene, however, was found to hydrogenate almost two order of magnitude slower than propylene on Pt(111).

  18. OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES

    SciTech Connect (OSTI)

    K.Krist; O. Spaldon-Stewart; R. Remick

    2004-03-01T23:59:59.000Z

    This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

  19. NATURAL MARINE HYDROCARBON SEEPAGE

    E-Print Network [OSTI]

    Luyendyk, Bruce

    affects ocean chemistry (Dando and Hovland, 1992) and provides a natural source of petroleum pollution the water column above submarine vents, plumes of hydrocarbon gas bubbles act as acoustic scattering targets

  20. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

    1986-01-01T23:59:59.000Z

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

  1. LES of a Hydrogen-Enriched Lean Turbulent Premixed Flame

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    LES of a Hydrogen-Enriched Lean Turbulent Premixed Flame Francisco E. Hern´andez-P´erez , Clinton the observed behaviour is examined. Hydrogen-hydrocarbon fuel blends appear to be a promising option to synergistically pave the way toward pure hydrogen-based combustion systems while alleviating green-house gas

  2. Author's personal copy Photoelectrochemical hydrogen production from water/

    E-Print Network [OSTI]

    Wood, Thomas K.

    coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resourcesAuthor's personal copy Photoelectrochemical hydrogen production from water/ methanol decomposition

  3. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  4. Process for conversion of lignin to reformulated hydrocarbon gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    1999-09-28T23:59:59.000Z

    A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

  5. Process for light-driven hydrocarbon oxidation at ambient temperatures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM)

    1990-01-01T23:59:59.000Z

    A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

  6. Theoretical studies of hydrocarbon combustion chemistry. Annual progress report

    SciTech Connect (OSTI)

    Schaefer, H.F. III

    1994-08-01T23:59:59.000Z

    The author reports here the results of DZP CISD calculations for methylcarbene. Geometry, symmetry, and vibrational modes for the radical are reported for both the singlet and the triplet state. Future work will focus on the ethyl radical-oxygen interaction relevant to hydrocarbon combustion.

  7. Oxidation resistant organic hydrogen getters

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Buffleben, George M. (Tracy, CA)

    2008-09-09T23:59:59.000Z

    A composition for removing hydrogen from an atmosphere, comprising a mixture of a polyphenyl ether and a hydrogenation catalyst, preferably a precious metal catalyst, and most preferably Pt. This composition is stable in the presence of oxygen, will not polymerize or degrade upon exposure to temperatures in excess of 200.degree. C., or prolonged exposure to temperatures in the range of 100-300.degree. C. Moreover, these novel hydrogen getter materials can be used to efficiently removing hydrogen from mixtures of hydrogen/inert gas (e.g., He, Ar, N.sub.2), hydrogen/ammonia atmospheres, such as may be encountered in heat exchangers, and hydrogen/carbon dioxide atmospheres. Water vapor and common atmospheric gases have no adverse effect on the ability of these getter materials to absorb hydrogen.

  8. TABLE30.CHP:Corel VENTURA

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    ... 315 4 319 202 52 301 555 Other HydrocarbonsHydrogenOxygenates ... 769 0 769 18 29 0 47 Other HydrocarbonsHydrogen...

  9. WASTE HYDROGEN PIPELINES MONITORING IN MODERN POWER PLANT Pawel Gsior, Jerzy Kaleta

    E-Print Network [OSTI]

    Boyer, Edmond

    for combustion generators (leading technology), and the second one use purified hydrogen for fuel cells of four supply gas pipelines (one with pure hydrogen to the fuel cell and three others with waste hydrogen and constructed. Two energetic technologies were applied. First use hydrogen and hydrocarbons as a fuel

  10. Applications of hydrogenation and dehydrogenation on noble metal catalysts

    E-Print Network [OSTI]

    Wang, Bo

    2009-05-15T23:59:59.000Z

    Hydrogenation and dehydrogenation on Pd- and Pt- catalysts are encountered in many industrial hydrocarbon processes. The present work considers the development of catalysts and their kinetic modeling along a general and rigorous approach. The first...

  11. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01T23:59:59.000Z

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  12. Florida Hydrogen Initiative

    SciTech Connect (OSTI)

    Block, David L

    2013-06-30T23:59:59.000Z

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cel

  13. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1997-01-01T23:59:59.000Z

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  14. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, R.L.

    1997-03-11T23:59:59.000Z

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  15. EFFECT ON PERFORMANCE OF ENGINE BY INJECTING HYDROGEN

    E-Print Network [OSTI]

    Rob Res; Suryakant Sharma Et Al; Suryakant Sharma; Deepak Bhardwaj; Vinay Kumar; Corresponding Suryakant Sharma

    The principle of this type of combustion is to addition of hydrogen gas to the combustion reactions of either compression or spark ignition engines. The addition of hydrogen has been shown to decrease the formation of NOx, CO and unburnt hydrocarbons. Studies have shown that added hydrogen in percentages as low as 5-10 % of the hydrocarbon fuel can reduce that hydrocarbon fuel consumption. The theory behind this concept is that the addition of hydrogen can increase the lean operation limit, improve the lean burn ability, and decrease burning time. To apply this method to an engine a source of hydrogen is needed. At this time the simplest option would be to carry a tank of hydrogen. Research is being conducted to allow the hydrogen to be reformed from the vehicles hydrocarbon fuel supply or produce hydrogen from electrolysis of water. In the future, better methods could be developed for storing hydrogen in the vehicle or production of hydrogen on-board the vehicle.

  16. Optical methods and systems for detecting a constituent in a gas containing oxygen in harsh environments

    DOE Patents [OSTI]

    Carpenter, Michael A. (Scotia, NY); Sirinakis, George (Bronx, NY)

    2011-01-04T23:59:59.000Z

    A method for detecting a gas phase constituent such as carbon monoxide, nitrogen dioxide, hydrogen, or hydrocarbons in a gas comprising oxygen such as air, includes providing a sensing material or film having a metal embedded in a catalytically active matrix such as gold embedded in a yttria stabilized zirconia (YSZ) matrix. The method may include annealing the sensing material at about 900.degree. C., exposing the sensing material and gas to a temperature above 400.degree. C., projecting light onto the sensing material, and detecting a change in the absorption spectrum of the sensing material due to the exposure of the sensing material to the gas in air at the temperature which causes a chemical reaction in the sensing material compared to the absorption spectrum of the sensing material in the absence of the gas. Systems employing such a method are also disclosed.

  17. Hydrogen Filling Station

    SciTech Connect (OSTI)

    Boehm, Robert F; Sabacky, Bruce; Anderson II, Everett B; Haberman, David; Al-Hassin, Mowafak; He, Xiaoming; Morriseau, Brian

    2010-02-24T23:59:59.000Z

    Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. The Freedom CAR and Freedom FUEL initiatives emphasize the importance of hydrogen as a future transportation fuel. Presently, Las Vegas has one hydrogen fueling station powered by natural gas. However, the use of traditional sources of energy to produce hydrogen does not maximize the benefit. The hydrogen fueling station developed under this grant used electrolysis units and solar energy to produce hydrogen fuel. Water and electricity are furnished to the unit and the output is hydrogen and oxygen. Three vehicles were converted to utilize the hydrogen produced at the station. The vehicles were all equipped with different types of technologies. The vehicles were used in the day-to-day operation of the Las Vegas Valley Water District and monitoring was performed on efficiency, reliability and maintenance requirements. The research and demonstration utilized for the reconfiguration of these vehicles could lead to new technologies in vehicle development that could make hydrogen-fueled vehicles more cost effective, economical, efficient and more widely used. In order to advance the development of a hydrogen future in Southern Nevada, project partners recognized a need to bring various entities involved in hydrogen development and deployment together as a means of sharing knowledge and eliminating duplication of efforts. A road-mapping session was held in Las Vegas in June 2006. The Nevada State Energy Office, representatives from DOE, DOE contractors and LANL, NETL, NREL were present. Leadership from the National hydrogen Association Board of Directors also attended. As a result of this session, a roadmap for hydrogen development was created. This roadmap has the ability to become a tool for use by other road-mapping efforts in the hydrogen community. It could also become a standard template for other states or even countries to approach planning for a hydrogen future. Project partners also conducted a workshop on hydrogen safety and permitting. This provided an opportunity for the various permitting agencies and end users to gather to share experiences and knowledge. As a result of this workshop, the permitting process for the hydrogen filling station on the Las Vegas Valley Water District’s land was done more efficiently and those who would be responsible for the operation were better educated on the safety and reliability of hydrogen production and storage. The lessons learned in permitting the filling station and conducting this workshop provided a basis for future hydrogen projects in the region. Continuing efforts to increase the working pressure of electrolysis and efficiency have been pursued. Research was also performed on improving the cost, efficiency and durability of Proton Exchange Membrane (PEM) hydrogen technology. Research elements focused upon PEM membranes, electrodes/catalysts, membrane-electrode assemblies, seals, bipolar plates, utilization of renewable power, reliability issues, scale, and advanced conversion topics. Additionally, direct solar-to-hydrogen conversion research to demonstrate stable and efficient photoelectrochemistry (PEC) hydrogen production systems based on a number of optional concepts was performed. Candidate PEC concepts included technical obstacles such as inefficient photocatalysis, inadequate photocurrent due to non-optimal material band gap energies, rapid electron-hole recombination, reduced hole mobility and diminished operational lifetimes of surface materials exposed to electrolytes. Project Objective 1: Design, build, operate hydrogen filling station Project Objective 2: Perform research and development for utilizing solar technologies on the hydrogen filling station and convert two utility vehicles for use by the station operators Project Objective 3: Increase capacity of hydrogen filling station; add additional vehicle; conduct safety workshop; develop a roadmap for hydrogen development; accelerate the development of photovoltaic components Project Objective 4:

  18. Hydrocarbon cracking catalyst

    SciTech Connect (OSTI)

    Lochow, C.F.; Kovacs, D.B.

    1988-12-27T23:59:59.000Z

    This patent describes a catalyst composition for cracking hydrocarbons to maximize gasoline comprising: rare earth exchanged ''Y'' crystalline faujasite dispersed in a clay containing matrix material; and which has been subsequently further ion exchanged to contain 0.20 to 3.0 wt% yttrium, calculated as the oxide, whereby the yttrium is chemically combined in the catalyst composition.

  19. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, J.L.

    1987-07-07T23:59:59.000Z

    A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.

  20. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, James L. (Scottsdale, AZ)

    1987-07-07T23:59:59.000Z

    A continuous thermochemical indirect liquefaction process to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C.sub.7 -C.sub.17 paraffinic hydrocarbons having cetane indices of 50+.

  1. Polymer system for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy Jon (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Whinnery, LeRoy L. (4929 Julie St., Livermore, Alameda County, CA 94550)

    2000-01-01T23:59:59.000Z

    A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

  2. Polymer formulations for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy Jon (Livermore, CA); Whinnery, LeRoy L. (Livermore, CA)

    1998-11-17T23:59:59.000Z

    A novel composition comprising organic polymer molecules having carbon-carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces. Organic polymers molecules containing carbon-carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble catalyst composition, comprising a hydrogenation catalyst and a catalyst support, preferably Pd supported on carbon, provide a hydrogen getter composition useful for removing hydrogen from enclosed spaces even in the presence of contaminants such as common atmospheric gases, water vapor, carbon dioxide, ammonia, oil mists, and water. The hydrogen getter composition disclosed herein is particularly useful for removing hydrogen from enclosed spaces containing potentially explosive mixtures of hydrogen and oxygen.

  3. Hydrogen sensor

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Cao, Wenqing (Katy, TX)

    2010-11-23T23:59:59.000Z

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  4. In-Cylinder Reaction Chemistry and Kinetics During Negative Valve Overlap Fuel Injection Under Low-Oxygen Conditions

    SciTech Connect (OSTI)

    Kalaskar, Vickey B [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL; Splitter, Derek A [ORNL] [ORNL; Pihl, Josh A [ORNL] [ORNL; Gao, Zhiming [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) as well as other forms of advanced combustion. During this event, at least a portion of the fuel hydrocarbons can be converted to products containing significant levels of H2 and CO, as well as other short chain hydrocarbons by means of thermal cracking, water-gas shift, and partial oxidation reactions, depending on the availability of oxygen and the time-temperature-pressure history. The resulting products alter the autoignition properties of the combined fuel mixture for HCCI. Fuel-rich chemistry in a partial oxidation environment is also relevant to other high efficiency engine concepts (e.g., the dedicated EGR (D-EGR) concept from SWRI). In this study, we used a unique 6-stroke engine cycle to experimentally investigate the chemistry of a range of fuels injected during NVO under low oxygen conditions. Fuels investigated included iso-octane, iso-butanol, ethanol, and methanol. Products from NVO chemistry were highly dependent on fuel type and injection timing, with iso-octane producing less than 1.5% hydrogen and methanol producing more than 8%. We compare the experimental trends with CHEMKIN (single zone, 0-D model) predictions using multiple kinetic mechanisms available in the current literature. Our primary conclusion is that the kinetic mechanisms investigated are unable to accurately predict the magnitude and trends of major species we observed.

  5. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

    1986-01-01T23:59:59.000Z

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

  6. Combustion process for synthesis of carbon nanomaterials from liquid hydrocarbon

    DOE Patents [OSTI]

    Diener, Michael D.; Alford, J. Michael; Nabity, James; Hitch, Bradley D.

    2007-01-02T23:59:59.000Z

    The present invention provides a combustion apparatus for the production of carbon nanomaterials including fullerenes and fullerenic soot. Most generally the combustion apparatus comprises one or more inlets for introducing an oxygen-containing gas and a hydrocarbon fuel gas in the combustion system such that a flame can be established from the mixed gases, a droplet delivery apparatus for introducing droplets of a liquid hydrocarbon feedstock into the flame, and a collector apparatus for collecting condensable products containing carbon nanomaterials that are generated in the combustion system. The combustion system optionally has a reaction zone downstream of the flame. If this reaction zone is present the hydrocarbon feedstock can be introduced into the flame, the reaction zone or both.

  7. Catalysts for conversion of methane to higher hydrocarbons

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1993-01-01T23:59:59.000Z

    Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

  8. Catalysts and process for liquid hydrocarbon fuel production

    DOE Patents [OSTI]

    White, Mark G; Liu, Shetian

    2014-12-09T23:59:59.000Z

    The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

  9. Production of valuable hydrocarbons by flash pyrolysis of oil shale

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.T.

    1985-04-01T23:59:59.000Z

    A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

  10. Process for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture

    SciTech Connect (OSTI)

    vanEijl, A.T.

    1986-06-24T23:59:59.000Z

    A process is described for separating an ethylenically unsaturated hydrocarbon from a hydrocarbon mixture characterized by: (a) distilling a hydrocarbon mixture containing the unsaturated hydrocarbon with an N-(aminoalkyl) piperazine; and (b) separating the amine/hydrocarbon mixture into at least two factions, one of which contains the amine and the unsaturated hydrocarbon.

  11. Deconvolution and Quantification of Hydrocarbon-like and Oxygenated

    E-Print Network [OSTI]

    Zhang, Qi

    , lubricating oil, and freshly emitted traffic aerosols observed in urban areas, while the spectrum of OOA

  12. Vapor-liquid equilibria of hydrocarbons and fuel oxygenates. 2

    SciTech Connect (OSTI)

    Bennett, A.; Lamm, S.; Orbey, H.; Sandler, S.I. (Univ. of Delaware, Newark (United States))

    1993-04-01T23:59:59.000Z

    Vapor-liquid equilibrium data for methyl tert-butyl ether (MTBE) + 1-heptene, MTBE + four-component gasoline prototype, ethanol + four-component gasoline prototype, and separately MTBE and ethanol with the Auto/Oil Air Quality Improvement Research Gasoline Blend A are reported. Small additions of MTBE have a very small effect on the total equilibrium pressure of this gasoline blend, and at most temperatures will decrease this pressure. In contrast, small additions of ethanol to this gasoline blend result in a significant increase in the equilibrium pressure at all temperatures. Analysis shows that the vapor-liquid equilibrium data for the MTBE-containing systems are easily correlated using a modified Peng-Robinson equation of state with conventional van der Waals one-fluid mixing rules. Data for mixtures containing ethanol cannot be accurately correlated in this way.

  13. Code for Hydrogen Hydrogen Pipeline

    E-Print Network [OSTI]

    #12;2 Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop Augusta, Georgia August development · Charge from BPTCS to B31 Standards Committee for Hydrogen Piping/Pipeline code development · B31.12 Status & Structure · Hydrogen Pipeline issues · Research Needs · Where Do We Go From Here? #12;4 Code

  14. Direct conversion of light hydrocarbon gases to liquid fuel. Final report No. 33

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  15. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    SciTech Connect (OSTI)

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27T23:59:59.000Z

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  16. Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  17. Hydrocarbon sensors and materials therefor

    DOE Patents [OSTI]

    Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

  18. Catalytic two-stage coal hydrogenation and hydroconversion process

    DOE Patents [OSTI]

    MacArthur, James B. (Denville, NJ); McLean, Joseph B. (So. Somerville, NJ); Comolli, Alfred G. (Yardley, PA)

    1989-01-01T23:59:59.000Z

    A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F. temperature for further hydrogenation and thermal hydroconversion reactions. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, which results in significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of undesirable residuum and unconverted coal and hydrocarbon gases, with use of less energy to obtain the low molecular weight products, while catalyst life is substantially increased.

  19. Hydrogen Analysis

    Broader source: Energy.gov [DOE]

    Presentation on Hydrogen Analysis to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004 to discuss and define role of systems analysis in DOE Hydrogen Program.

  20. Nuclear Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen High temperature options for nuclear generation of hydrogen on a commercial basis are several years in the future. Thermo-chemical water splitting has been proven to be...

  1. Hydrogen Safety

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

  2. Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

  3. Pyrochlore catalysts for hydrocarbon fuel reforming

    DOE Patents [OSTI]

    Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

    2012-08-14T23:59:59.000Z

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

  4. Hydrogen in Type Ic Supernovae?

    E-Print Network [OSTI]

    David Branch; David J. Jeffery; Timothy R. Young; E. Baron

    2006-05-09T23:59:59.000Z

    By definition, a Type Ic supernova (SN Ic) does not have conspicuous lines of hydrogen or helium in its optical spectrum. SNe Ic usually are modelled in terms of the gravitational collapse of bare carbon-oxygen cores. We consider the possibility that the spectra of ordinary (SN 1994I-like) SNe Ic have been misinterpreted, and that SNe Ic eject hydrogen. An absorption feature usually attributed to a blend of Si II 6355 and C II 6580 may be produced by H-alpha. If SN 1994I-like SNe Ic eject hydrogen, the possibility that hypernova (SN 1998bw-like) SNe Ic, some of which are associated with gamma-ray bursts, also eject hydrogen should be considered. The implications of hydrogen for SN Ic progenitors and explosion models are briefly discussed.

  5. IONICALLY CONDUCTING MEMBRANES FOR HYDROGEN PRODUCTION AND

    E-Print Network [OSTI]

    SEQUESTRATION Oxygen Transport Membrane Hydrogen Transport Membrane Natural Gas Coal Biomass Syngas CO/H2 WGS H2 operating experience. #12;ELTRON RESEARCH INC. Syngas Production Rate ­ 60 mL/min cm2 @ 900°C Equivalent O2 Operational Experience Under High Pressure Differential SUMMARY OF ELTRON OXYGEN TRANSPORT MEMBRANE SYNGAS

  6. Oxygen stabilized zirconium vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  7. Process for recovering hydrocarbons from a hydrocarbon-bearing formation

    SciTech Connect (OSTI)

    Alston, R.B.; Braden, W.B.; Flournoy, K.H.

    1980-03-11T23:59:59.000Z

    A method is described for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion. Also disclosed is a method of recovery of hydrocarbons from a hydrocarbon bearing formation employing an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent.

  8. PHOTOELECTROCHEMICAL SYSTEMS FOR HYDROGEN PRODUCTION

    E-Print Network [OSTI]

    to allow the overlap of the bandedges with the water redox potentials in the dark. Charge transfer analysis A photoelectrochemical (PEC) system combines the harvesting of solar energy with the electrolysis of water. When, the energy can be sufficient to split water into hydrogen and oxygen. Depending on the type of semiconductor

  9. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

  10. Dissolution of oxygen reduction electrocatalysts in acidic environment

    E-Print Network [OSTI]

    Gu, Zhihui

    2009-05-15T23:59:59.000Z

    Platinum (Pt) alloy nanoparticles are used as catalysts in electrochemical cells to reduce oxygen to water and to oxidize hydrogen; the overall reaction converts chemical energy into electrical energy. These nanocatalysts are deposited on a carbon...

  11. CRYOGENIC SYSTEM FOR CONTINUOUS ULTRAHIGH HYDROGEN PURIFICATION IN CIRCULATION MODE

    E-Print Network [OSTI]

    Kammel, Peter

    1 CRYOGENIC SYSTEM FOR CONTINUOUS ULTRAHIGH HYDROGEN PURIFICATION IN CIRCULATION MODE A. Vasilyev1 (Circulation Hydrogen Ultrahigh Purification System) is designed to solve these two tasks: providing, the total level of all contaminants (water, nitrogen, oxygen etc.) has to be lower than 0.01 ppm. Hydrogen

  12. Abstract--A novel methodology for economic evaluation of hydrogen storage for a mixed wind-nuclear power plant is

    E-Print Network [OSTI]

    Cañizares, Claudio A.

    : hydrogen efficiency of electrolyzer (kg/MWh) d : hydrogen efficiency of fuel cell (kg/MWh) O : oxygen hydrogen production (kg) dischargeV : fuel cells hydrogen consumption (kg) hsellV : hydrogen exchange capacity (MW) STG Vmax : maximum storage level (kg) STGDISCH Pmax : maximum fuel cell power (MW) STGDISCH

  13. Oxygen addition to sulfur of metal thiolates

    E-Print Network [OSTI]

    Soma, Takako

    2012-06-07T23:59:59.000Z

    , and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

  14. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

    1996-01-01T23:59:59.000Z

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  15. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19T23:59:59.000Z

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  16. CdSe-MoS2: A Quantum Size-Confined Photocatalyst for Hydrogen Evolution from Water under Visible Light

    E-Print Network [OSTI]

    Osterloh, Frank

    and for the conversion of carbon dioxides into methanol and hydrocarbons. Metal chalcogenides1­9 are promisingCdSe-MoS2: A Quantum Size-Confined Photocatalyst for Hydrogen Evolution from Water under Visible driven pathway to hydrogen. Hydrogen is not only an environmentally benign fuel for the generation

  17. Fuel Cell Technologies Office Overview: 2015 Hydrogen, Hydrocarbons, and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional ElectricalEnergy Frozen TelescopeRenewable 0 0 A N

  18. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy Health andof Energy EmbrittlementFactEducationEvaluationWebinar|

  19. Hydrogen Bibliography

    SciTech Connect (OSTI)

    Not Available

    1991-12-01T23:59:59.000Z

    The Hydrogen Bibliography is a compilation of research reports that are the result of research funded over the last fifteen years. In addition, other documents have been added. All cited reports are contained in the National Renewable Energy Laboratory (NREL) Hydrogen Program Library.

  20. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO)

    1991-01-01T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

  1. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2006-03-30T23:59:59.000Z

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

  2. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2001-12-01T23:59:59.000Z

    Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  3. Enrichment of light hydrocarbon mixture

    SciTech Connect (OSTI)

    Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2010-08-10T23:59:59.000Z

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  4. Enrichment of light hydrocarbon mixture

    DOE Patents [OSTI]

    Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2011-11-29T23:59:59.000Z

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  5. Occurrence of chlorinated polynuclear aromatic hydrocarbons in tap water

    SciTech Connect (OSTI)

    Shiraishi, H.; Pilkington, N.H.; Otsuki, A.; Fuwa, K.

    1985-07-01T23:59:59.000Z

    Organic compounds in tap waters were extracted by a modified continuous liquid-liquid extractor and analyzed by computerized gas chromatography/mass spectrometry using a fused silica capillary column. The results indicate the presence of monochlorinated derivatives of naphthalene, dibenzofuran, fluorene, fluorenone, phenanthrene, and fluoranthene and dichlorinated derivatives of naphthalene, phenanthrene, and fluoranthene. The parent polynuclear aromatic hydrocarbons (PAHs) and their oxygenated derivatives such as fluorenone and anthraquinone were also found. It was demonstrated that chlorinated PAHs (Cl-PAHs) were really present in tap waters at 10/sup -1/-10/sup -2/ ng/L levels.

  6. DME-to-oxygenates process studies

    SciTech Connect (OSTI)

    Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

    1994-12-31T23:59:59.000Z

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  7. Biological enhancement of hydrocarbon extraction

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

    2009-01-06T23:59:59.000Z

    A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

  8. Trends in hydrogen plant design

    SciTech Connect (OSTI)

    Johansen, T.; Raghuraman, K.S.; Hackett, L.A. (KTI, Zoetermeer (NL))

    1992-08-01T23:59:59.000Z

    Understanding important design considerations for H{sub 2} production via steam reforming require detailed attention to the many elements that make up the process. This paper discusses design trends focus on improvements to the plant's three principal unit operations: Generation of H{sub 2}/CO syngas, Conversion of CO in the syngas and Separation/purification of H{sub 2} from syngas. Natural gas, LPG, oil, coal and coke are all potential raw materials for H{sub 2} production. For the first step in the process, generation of H{sub 2} syngas, the processes available are: Reforming the steam; Autothermal reforming with oxygen and steam; and Partial oxidation with oxygen (POX). Most syngas is presently produced by steam reforming of natural gas or light hydrocarbons up to naphtha.

  9. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

  10. aromatic hydrocarbon components: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AROMATIC HYDROCARBONS 2005 April 19 ABSTRACT Interstellar polycyclic aromatic hydrocarbon (PAH) infrared emission features 26 Dehydrogenation of polycyclic aromatic...

  11. Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream

    DOE Patents [OSTI]

    Berry, David A; Shekhawat, Dushyant; Smith, Mark; Haynes, Daniel

    2013-07-16T23:59:59.000Z

    The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.

  12. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  13. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2002-01-01T23:59:59.000Z

    Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

  14. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30T23:59:59.000Z

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  15. Effect of Water Transport on the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    be developed that provides efficient production of clean hydrogen. The methods existing today for large-scale produc- tion of hydrogen typically involve hydrocarbon reforming of natural gas or coal gasification% , the overall efficiency is 40%.7 Two issues remain, however, that make the future of this technology un

  16. Photoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2 nanocomposite

    E-Print Network [OSTI]

    coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity A & M University, College Station, TX 77843 3136, USA a r t i c l e i n f o Article history: Received 18, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resources

  17. Reduced Turbine Emissions Using Hydrogen-Enriched Fuels R.W. Schefer

    E-Print Network [OSTI]

    as a fuel for aircraft gas turbine operation. The burner configuration consisted of nine 6.73 mm diameter capabilities for gaseous hydrogen and hydrogen- blended hydrocarbon fuels in gas turbine applications source of cost-effective fuels for gas turbines. A second need is related to the recognition that ultra

  18. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

  19. Oxygen stabilized zirconium-vanadium-iron alloy

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  20. Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working Group Workshop: Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines Code for Hydrogen Piping and Pipelines. B31 Hydrogen...

  1. Reduced Turbine Emissions Using Hydrogen-Enriched Fuels

    E-Print Network [OSTI]

    optimal use of fuel lean combustion for NOx control ­ Replaces hydrocarbon fuels for reduced CO2 emissions ­ Enables use of domestically-produced H2 #12;U.S. CO2 EmissionsU.S. CO2 Emissions by Combustion Source 0 81Reduced Turbine Emissions Using Hydrogen-Enriched Fuels Robert W. Schefer Joseph C. Oefelein Jay O

  2. Hydrogen program overview

    SciTech Connect (OSTI)

    Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

    1997-12-31T23:59:59.000Z

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  3. Polymer formulations for gettering hydrogen

    DOE Patents [OSTI]

    Shepodd, Timothy J. (330 Thrasher Ave., Livermore, CA 94550); Even, Jr., William R. (4254 Drake Way, Livermore, CA 94550)

    2000-01-01T23:59:59.000Z

    A novel method for preparing a hydrogenation composition comprising organic polymer molecules having carbon--carbon double bonds, for removing hydrogen from the atmosphere within enclosed spaces and particularly from atmospheres within enclosed spaces that contain air, water vapor, oxygen, carbon dioxide or ammonia. The organic polymers molecules containing carbon--carbon double bonds throughout their structures, preferably polybutadiene, polyisoprene and derivatives thereof, intimately mixed with an insoluble noble metal catalyst composition. High molecular weight polymers may be added to the organic polymer/catalyst mixture in order to improve their high temperature performance. The hydrogenation composition is prepared by dispersing the polymers in a suitable solvent, forming thereby a solution suspension, flash-freezing droplets of the solution in a liquid cryogen, freeze-drying the frozen droplets to remove frozen solvent incorporated in the droplets, and recovering the dried powder thus formed.

  4. Hydrogen Permeability and Integrity of Hydrogen

    E-Print Network [OSTI]

    Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Z. Feng*, L.M. Anovitz*, J and industry expectations · DOE Pipeline Working Group and Tech Team activities - FRP Hydrogen Pipelines - Materials Solutions for Hydrogen Delivery in Pipelines - Natural Gas Pipelines for Hydrogen Use #12;3 OAK

  5. Hydrogen Technologies Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    The Hydrogen Technologies Group at the National Renewable Energy Laboratory advances the Hydrogen Technologies and Systems Center's mission by researching a variety of hydrogen technologies.

  6. The Hype About Hydrogen

    E-Print Network [OSTI]

    Mirza, Umar Karim

    2006-01-01T23:59:59.000Z

    economy based on the hydrogen fuel cell, but this cannot beus to look toward hydrogen. Fuel cell basics, simplifiedthe path to fuel cell commercialization. Hydrogen production

  7. Hydrogen Transition Infrastructure Analysis

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2005-05-01T23:59:59.000Z

    Presentation for the 2005 U.S. Department of Energy Hydrogen Program review analyzes the hydrogen infrastructure needed to accommodate a transitional hydrogen fuel cell vehicle demand.

  8. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    onsite SMRs. Hydrogen from 100% solar photovoltaic poweredphotovoltaic (PV) electricity. Oxygen exhaust stream 12 x 6,250-psi compressed hydrogenphotovoltaic (PV) electricity Alkaline Electrolyzer Reverse osmosis and deionizer water purification Oxygen exhaust stream 12 x 6,250-psi compressed hydrogen

  9. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  10. Dry reforming of hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

    2014-01-01T23:59:59.000Z

    Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

  11. Underground caverns for hydrocarbon storage

    SciTech Connect (OSTI)

    Barron, T.F. [Exeter Energy Services, Houston, TX (United States)

    1998-12-31T23:59:59.000Z

    Large, international gas processing projects and growing LPG imports in developing countries are driving the need to store large quantities of hydrocarbon liquids. Even though underground storage is common in the US, many people outside the domestic industry are not familiar with the technology and the benefits underground storage can offer. The latter include lower construction and operating costs than surface storage, added safety, security and greater environmental acceptance.

  12. Catalytic partial oxidation of hydrocarbons

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Krummenacher, Jakob J.; West, Kevin N.

    2007-08-28T23:59:59.000Z

    A process for the production of a reaction product including a carbon containing compound. The process includes providing a film of a fuel source including at least one organic compound on a wall of a reactor, contacting the fuel source with a source of oxygen, forming a vaporized mixture of fuel and oxygen, and contacting the vaporized mixture of fuel and oxygen with a catalyst under conditions effective to produce a reaction product including a carbon containing compound. Preferred products include .alpha.-olefins and synthesis gas. A preferred catalyst is a supported metal catalyst, preferably including rhodium, platinum, and mixtures thereof.

  13. Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons

    DOE Patents [OSTI]

    Rolllins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

    2012-07-24T23:59:59.000Z

    Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

  14. Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons

    DOE Patents [OSTI]

    Rollins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

    2011-02-01T23:59:59.000Z

    Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

  15. RELATIVE ECONOMIC INCENTIVES FOR HYDROGEN FROM NUCLEAR, RENEWABLE, AND FOSSIL ENERGY SOURCES

    SciTech Connect (OSTI)

    Gorensek, M; Charles W. Forsberg, C

    2008-08-04T23:59:59.000Z

    The specific hydrogen market determines the value of hydrogen from different sources. Each hydrogen production technology has its own distinct characteristics. For example, steam reforming of natural gas produces only hydrogen. In contrast, nuclear and solar hydrogen production facilities produce hydrogen together with oxygen as a by-product or co-product. For a user who needs both oxygen and hydrogen, the value of hydrogen from nuclear and solar plants is higher than that from a fossil plant because 'free' oxygen is produced as a by-product. Six factors that impact the relative economics of fossil, nuclear, and solar hydrogen production to the customer are identified: oxygen by-product, avoidance of carbon dioxide emissions, hydrogen transport costs, storage costs, availability of low-cost heat, and institutional factors. These factors imply that different hydrogen production technologies will be competitive in different markets and that the first markets for nuclear and solar hydrogen will be those markets in which they have a unique competitive advantage. These secondary economic factors are described and quantified in terms of dollars per kilogram of hydrogen.

  16. Relative Economic Incentives for Hydrogen from Nuclear, Renewable, and Fossil Energy Sources

    SciTech Connect (OSTI)

    Forsberg, Charles W [ORNL] [ORNL; Gorensek, M. B. [Savannah River National Laboratory (SRNL)] [Savannah River National Laboratory (SRNL)

    2007-01-01T23:59:59.000Z

    The specific hydrogen market determines the value of hydrogen from different sources. Each hydrogen production technology has its own distinct characteristics. For example, steam reforming of natural gas produces only hydrogen. In contrast, nuclear and solar hydrogen production facilities produce hydrogen together with oxygen as a by-product or co-product. For a user who needs both oxygen and hydrogen, the value of hydrogen from nuclear and solar plants is higher than that from a fossil plant because 'free' oxygen is produced as a by-product. Six factors that impact the relative economics of fossil, nuclear, and solar hydrogen production to the customer are identified: oxygen by-product, avoidance of carbon dioxide emissions, hydrogen transport costs, storage costs, availability of low-cost heat, and institutional factors. These factors imply that different hydrogen production technologies will be competitive in different markets and that the first markets for nuclear and solar hydrogen will be those markets in which they have a unique competitive advantage. These secondary economic factors are described and quantified in terms of dollars per kilogram of hydrogen.

  17. HYDROGEN IGNITION MECHANISM FOR EXPLOSIONS IN NUCLEAR FACILITY PIPE SYSTEMS

    SciTech Connect (OSTI)

    Leishear, R

    2010-05-02T23:59:59.000Z

    Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions exist. Pipe ruptures at nuclear facilities were attributed to hydrogen explosions inside pipelines, in nuclear facilities, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents an ignition source for hydrogen was questionable, but these accidents, demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein.

  18. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

  19. Polymer formulation for removing hydrogen and liquid water from an enclosed space

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA)

    2006-02-21T23:59:59.000Z

    This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

  20. HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE

    SciTech Connect (OSTI)

    Licia M. Petkovic; Harry W. Rollins; Daniel M. Ginosar; Kyle C. Burch

    2006-09-01T23:59:59.000Z

    HYBRID HETEROGENEOUS CATALYSTS FOR HYDROGENATION OF CARBON DIOXIDE Lucia M. Petkovic, Harry W. Rollins, Daniel M. Ginosar, and Kyle C. Burch Idaho National Laboratory P.O. Box 1625 Idaho Falls, ID 83415-2208 Introduction Anthropogenic emissions of carbon dioxide, a gas often associated with global warming, have increased considerably since the beginning of the industrial age.1 In the U.S., stationary CO2 sources, such as electricity generation plants, produce about one-third of the anthropogenic CO2 generation. Reports2 indicate that the power required to recover 90% of the CO2 from an integrated coal-fired power-plant is about 10% of the power-plant capacity. This energy requirement can be reduced to less than 1% if the recovered CO2 is applied to the production of synthetic fuels. However, the lack of efficient catalysts along with the costs of energy and hydrogen has prevented the development of technologies for direct hydrogenation of CO2.3 Although the cost of hydrogen for hydrogenating CO2 is not economically attractive at present, the future production of hydrogen by nuclear power sources could completely change this scenario.2 Still, an efficient catalyst will be essential for commercial application of those processes. The objective of the work presented here was the development of hybrid catalysts for one-step carbon dioxide hydrogenation to liquid fuels. The hybrid catalysts, which were prepared by two novel techniques, included a copper/zinc oxide catalytic function distributed within an acidic zeolitic matrix. Results of catalyst activity and selectivity studies at atmospheric pressure are presented in this contribution. Experimental Catalysts were prepared by two novel techniques and under several different conditions to produce copper/zinc oxide/zeolite materials. Once synthesized, samples were pelletized and the fraction between 40-60 mesh was utilized for the experiments. Two hundred milligrams of catalyst were loaded in a U-tube stainless steel reactor and a flow of 100 cm3/min of a 10:90 H2:Ar mixture was passed through the catalyst bed while the temperature was increased from room temperature to 513 K at 1.8 K/min and held at 513 K for 15 h. A reactant gas mixture composed by 10 cm3/min of CO2 and 30 cm3/min of H2 was then passed through the catalyst bed and the reaction products monitored by on-line gas chromatographic analyses using an SRI Multiple Gas Analyzer #2 equipped with 3 columns (MoleSieve 13X, Hayesep-D, and MXT-1) and 3 detectors (TCD, FID, and FID-methanizer). This GC system allowed for quantification of inert gases, CO, CO2, methanol, dimethylether, higher alcohols, water, and hydrocarbons up to C20. One hundred milligrams of a commercial syngas-to-methanol catalyst along with the same amount of a commercial zeolite catalyst was utilized under the same reaction conditions for comparison purposes. These catalysts were utilized either in two-layers (Com1) or mixed together (Com2). Results and Discussion Under the conditions applied in this study, the main reaction products were CO, CH3OH, CH3OCH3, and H2O. Methanol and dimethylether production rates and selectivities with respect to CO formation are presented in Figures 1 and 2, respectively. Although the activity of the synthesized catalysts did not surpass the commercial catalysts, the selectivity to oxygenates with respect to CO on most of the synthesized catalysts were better than on the commercial catalysts. For example, cat

  1. Use of once-through treat gas to remove the heat of reaction in solvent hydrogenation processes

    DOE Patents [OSTI]

    Nizamoff, Alan J. (Convent Station, NJ)

    1980-01-01T23:59:59.000Z

    In a coal liquefaction process wherein feed coal is contacted with molecular hydrogen and a hydrogen-donor solvent in a liquefaction zone to form coal liquids and vapors and coal liquids in the solvent boiling range are thereafter hydrogenated to produce recycle solvent and liquid products, the improvement which comprises separating the effluent from the liquefaction zone into a hot vapor stream and a liquid stream; cooling the entire hot vapor stream sufficiently to condense vaporized liquid hydrocarbons; separating condensed liquid hydrocarbons from the cooled vapor; fractionating the liquid stream to produce coal liquids in the solvent boiling range; dividing the cooled vapor into at least two streams; passing the cooling vapors from one of the streams, the coal liquids in the solvent boiling range, and makeup hydrogen to a solvent hydrogenation zone, catalytically hydrogenating the coal liquids in the solvent boiling range and quenching the hydrogenation zone with cooled vapors from the other cooled vapor stream.

  2. Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2003 Progress Report President Bush Launches the Hydrogen Fuel Initiative

    E-Print Network [OSTI]

    of using hydrogen power, of course, will be energy independence for this nation... think about a legacy between hydrogen and oxygen generates energy, which can be used to power a car producing only water to taking these cars from laboratory to showroom so that the first car driven by a child born today could

  3. Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .

    SciTech Connect (OSTI)

    Wallner, T. (Energy Systems)

    2011-08-01T23:59:59.000Z

    The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

  4. The Hype About Hydrogen

    E-Print Network [OSTI]

    Mirza, Umar Karim

    2006-01-01T23:59:59.000Z

    another promising solution for hydrogen storage. However,storage and delivery, and there are safety issues as well with hydrogen

  5. Hydrogen Technology Validation

    Fuel Cell Technologies Publication and Product Library (EERE)

    This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

  6. Hydrogen Analysis Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    NREL factsheet that describes the general activites of the Hydrogen Analysis Group within NREL's Hydrogen Technologies and Systems Center.

  7. ECONOMIC FEASIBILITY ANALYSIS OF HYDROGEN PRODUCTION BY

    E-Print Network [OSTI]

    . Shah and Raymond F. Drnevich Praxair, Inc. P.O. Box 44 Tonawanda, NY 14151 Abstract Praxair has on oxygen transport membrane (OTM) and hydrogen transport membrane (HTM). This system has a potential process option, both the OTM and the HTM were integrated into a single unit such that various processing

  8. Catalytic hydrodechlorination of industrial wastewater containing chlorinated hydrocarbons in a trickle bed reactor

    E-Print Network [OSTI]

    Leong, Chee Kong

    1996-01-01T23:59:59.000Z

    reaction has long been applied in chemical synthesis and liquid organic waste decomposition, very little attention is devoted to direct treatment of chlorinated hydrocarbons in wastewater (aqueous) or contannnated groundwater with hydrogen. The main..., Trichlorobenzene m Benzene Catal sts Group VIII Metals (Pt, Pd, Rh, Ru, Os, Ir, Ni) Rare earth oxide of the Lanthanide series and metal of the Platinum u Supported Palladium catalyst Tem efature 80 - 2750C 400 - 600'C 170 C Pressure atm...

  9. Hydrogen: The Fuel that Drill Bits Cannot Reach

    SciTech Connect (OSTI)

    Miller, Alistair I.; Duffey, Romney B. [Atomic Energy of Canada Limited (Canada)

    2006-07-01T23:59:59.000Z

    As realization grows of the damaging cumulative effects of CO{sub 2} on our biosphere, the prospect of substituting hydrogen for oil-based fuels attracts growing attention. Japan provides a leading example of remedial action with the expectation of five million fuel-cell-powered vehicles in operation by 2020. But where will the fuel for these and the rest of a 'Hydrogen Age' come from? The hydrogen market used to be straightforward: small-scale or high-purity markets were supplied relatively expensively by electrolysis; the other 95% was supplied much more cheaply by reforming hydrocarbons -- mostly using steam-methane reforming (SMR) and low-cost natural gas. The recent rise in the price of hydrocarbons -- natural gas as well as oil -- plus the need to sequester CO{sub 2} has disrupted this scenario. It seems likely that this is a permanent shift driven by growing demand for limited low-cost sources of fluid hydrocarbons. So the traditional SMR route to hydrogen will be in competition with reforming of heavier hydrocarbons (particularly coal and residual oils) as well as with electrolysis based on electricity produced from low-CO{sub 2}-emitting sources. By 2025, new high-temperature thermochemical or thermo-electrolytic sources based on high-temperature nuclear reactors could be in contention. This paper assesses the economics of all these potential sources of hydrogen and their price sensitivities. It also considers their environmental footprints. Is hydrogen from 'clean coal' or other lower value hydrocarbons cost-effective if it is also CO{sub 2}-free? Is intermittent low-temperature electrolysis based on nuclear- and wind-produced electricity (NuWind{sup C}) the best way or does the hydrogen future belong to thermochemistry or thermo-electrolytic sources? How can one produce hydrogen to upgrade Canada's vast oil sands resources without the detraction of a large CO{sub 2} processing penalty? Fortunately for our planet, switching to hydrogen is no more than a technical challenge with a range of possible solutions but we need to make that point clearly to the political decision-takers and be able to provide assurance that the preferred solution will not be a source of new problems. (authors)

  10. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01T23:59:59.000Z

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  11. Application of advanced hydrocarbon characterization and its...

    Broader source: Energy.gov (indexed) [DOE]

    advanced hydrocarbon characterization and its consequences on future fuel properties and advanced combustion research Rafal Gieleciak, Craig Fairbridge and Darcy Hager Poster...

  12. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14T23:59:59.000Z

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  13. Nox reduction system utilizing pulsed hydrocarbon injection

    DOE Patents [OSTI]

    Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

  14. Oxygen enriched fireflooding

    SciTech Connect (OSTI)

    Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

    1995-02-01T23:59:59.000Z

    Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

  15. Ionwater hydrogen-bond switching observed with 2D IR vibrational echo chemical

    E-Print Network [OSTI]

    Fayer, Michael D.

    Ion­water hydrogen-bond switching observed with 2D IR vibrational echo chemical exchange for review November 8, 2008) The exchange of water hydroxyl hydrogen bonds between anions and water oxygens of anion­ water hydroxyl hydrogen bond switching under thermal equilib- rium conditions as Taw 7 1 ps. Pump

  16. Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor

    E-Print Network [OSTI]

    Tobin, Roger G.

    monitoring, solid-oxide fuel cells, and coal gasification, require operation at much higher temperatures thanSulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor Yung Ho to hydrogen sulfide, even in the presence of hydrogen or oxygen at partial pressures of 20­600 times greater

  17. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); Lee, Lap-Keung (Cranbury, NJ)

    2001-01-01T23:59:59.000Z

    A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

  18. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01T23:59:59.000Z

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  19. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06T23:59:59.000Z

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  20. Modification of Gold Catalysis withModification of Gold Catalysis with Aluminum Phosphate for OxygenAluminum Phosphate for Oxygen--Reduction ReactionReduction Reaction

    E-Print Network [OSTI]

    Park, Byungwoo

    Ford Toshiba Samsung Byungwoo Park's Group #12;Scheme of Fuel Cells Load e- e- Hydrogen Methanol + Water (DMFC· Morphology of Au/AlPO4 Nanocomposite Catalyst · Oxygen Reduction Activity ­ Hydrogen Peroxide Intermediate to Gold Seoul National University Yejun Park et al. 22Byungwoo Park's Group #12;Applications of Fuel Cells

  1. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Phillip, Bradley L. (Shaker Heights, OH)

    1997-01-01T23:59:59.000Z

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100.degree. C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  2. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Phillip, Bradley L. (20976 Fairmount Blvd., Shaker Heights, Cuyahoga County, OH 44120)

    1997-01-01T23:59:59.000Z

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compostions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  3. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, James B. (Denville, NJ); Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (Somerville, NJ)

    1989-01-01T23:59:59.000Z

    A process for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600.degree.-750.degree. F. to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650.degree. F. and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-90 lb/hr per ft.sup.3 catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760.degree.-860.degree. F. temperature for further hydrogenation and hydroconversion reactions. A 600.degree.-750.degree. F..sup.+ fraction containing 0-20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials.

  4. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

    1989-10-17T23:59:59.000Z

    A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

  5. Hydrogen as a fuel for fuel cell vehicles: A technical and economic comparison

    SciTech Connect (OSTI)

    Ogden, J.; Steinbugler, M.; Kreutz, T. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies

    1997-12-31T23:59:59.000Z

    All fuel cells currently being developed for near term use in vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, ethanol or hydrocarbon fuels derived from crude oil (e.g., Diesel, gasoline or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, the authors compare three leading options for fuel storage onboard fuel cell vehicles: compressed gas hydrogen storage; onboard steam reforming of methanol; onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. Equilibrium, kinetic and heat integrated system (ASPEN) models have been developed to estimate the performance of onboard steam reforming and POX fuel processors. These results have been incorporated into a fuel cell vehicle model, allowing us to compare the vehicle performance, fuel economy, weight, and cost for various fuel storage choices and driving cycles. A range of technical and economic parameters were considered. The infrastructure requirements are also compared for gaseous hydrogen, methanol and hydrocarbon fuels from crude oil, including the added costs of fuel production, storage, distribution and refueling stations. Considering both vehicle and infrastructure issues, the authors compare hydrogen to other fuel cell vehicle fuels. Technical and economic goals for fuel cell vehicle and hydrogen technologies are discussed. Potential roles for hydrogen in the commercialization of fuel cell vehicles are sketched.

  6. Reactive oxygen species and Udx1 during early sea urchin development Julian L. Wong, Gary M. Wessel*

    E-Print Network [OSTI]

    Wessel, Gary M.

    Reactive oxygen species and Udx1 during early sea urchin development Julian L. Wong, Gary M. Wessel Abstract Sea urchin fertilization is marked by a massive conversion of molecular oxygen to hydrogen of these defective embryos. We also report an unequal distribution of reactive oxygen species between sister

  7. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Gasoline and Diesel Fuel Update (EIA)

    741 317 245 1,303 IsobutaneIsobutylene 206 7 213 155 55 184 394 Other HydrocarbonsHydrogenOxygenates 512 0 512 29 18 0 47 Other HydrocarbonsHydrogen 0 0 0 28 0 0 28...

  8. untitled

    Gasoline and Diesel Fuel Update (EIA)

    741 317 267 1,325 IsobutaneIsobutylene 206 7 213 155 55 170 380 Other HydrocarbonsHydrogenOxygenates 512 0 512 29 18 0 47 Other HydrocarbonsHydrogen 0 0 0 28 0 0 28...

  9. Polynuclear aromatic hydrocarbons for fullerene synthesis in flames

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D.

    2006-12-19T23:59:59.000Z

    This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

  10. DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fuel Cells Program Record 11007: Hydrogen Threshold Cost Calculation DOE Hydrogen and Fuel Cells Program Record 11007: Hydrogen Threshold Cost Calculation The hydrogen...

  11. Hydrogen permeability and Integrity of hydrogen transfer pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    permeability and Integrity of hydrogen transfer pipelines Hydrogen permeability and Integrity of hydrogen transfer pipelines Presentation by 03-Babu for the DOE Hydrogen Pipeline...

  12. NREL Wind to Hydrogen Project: Renewable Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage &...

  13. Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...

    Broader source: Energy.gov (indexed) [DOE]

    Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  14. Tensile Effective Stresses in Hydrocarbon Storage Caverns

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Tensile Effective Stresses in Hydrocarbon Storage Caverns Hippolyte Djizanne and Pierre BĂ©rest LMS, Germany,1-2 October 2012 TENSILE EFFECTIVE STRESSES IN HYDROCARBON STORAGE CAVERNS Hippolyte Djizanne1 that effective tensile stresses can be generated at a cavern wall after a rapid increase or decrease in pressure

  15. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, Elias (Oak Ridge, TN)

    1995-01-01T23:59:59.000Z

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

  16. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, E.

    1995-05-23T23:59:59.000Z

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

  17. Control of Fuel Cell Breathing: Initial Results on the Oxygen Starvation Problem

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    operate at low temperatures (50-100 degree Support is provided by the National Science Foundation under and distribution. In the long term, a hydrogen generation and distribution infrastructure based on renewable energy from wind, water, and sun, or reformed hydrocarbon fuel will help reduce our dependency on fossil fuels

  18. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI...

  19. Commercialization of IH2® Biomass Direct-to-Hydrocarbon Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and...

  20. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

  1. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17T23:59:59.000Z

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  2. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  3. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  4. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  5. Species measurements in a hypersonic, hydrogen-air, combustion wake

    SciTech Connect (OSTI)

    Skinner, K.A.; Stalker, R.J. [Univ. of Queensland, Brisbane, Queensland (Australia)] [Univ. of Queensland, Brisbane, Queensland (Australia)

    1996-09-01T23:59:59.000Z

    A continuously sampling, time-of-flight mass spectrometer has been used to measure relative species concentrations in a two-dimensional, hydrogen-air combustion wake at mainstream Mach numbers exceeding 5. The experiments, in a free piston shock tunnel, yielded distributions of hydrogen, oxygen, nitrogen, water, and nitric oxide at stagnation enthalpies ranging from 5.6 MJ/kg to 12.2 MJ/kg and at a distance of approximately 100s times the thickness of the initial hydrogen jet. The amount of hydrogen mixed in stoichiometric proportions was approximately independent of the stagnation enthalpy, despite the fact that the proportion of hydrogen in the wake was increased with stagnation enthalpy. Roughly 50% of the mixed hydrogen underwent combustion at the highest enthalpy. The proportion of hydrogen reacting to water could be approximately predicted using reaction rates based on mainstream temperatures.

  6. Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars

    SciTech Connect (OSTI)

    Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

    2014-05-18T23:59:59.000Z

    Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

  7. HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM

    E-Print Network [OSTI]

    to serve as "go-to" organization to catalyze PA Hydrogen and Fuel Cell Economy development #12;FundingHYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA Melissa Klingenberg, PhDMelissa Klingenberg, PhD #12;Hydrogen ProgramHydrogen Program Air Products

  8. Hydrogen Delivery Mark Paster

    E-Print Network [OSTI]

    Liquids (e.g. ethanol etc.) ­ Truck: HP Gas & Liquid Hydrogen ­ Regional Pipelines ­ Breakthrough Hydrogen;Delivery Key Challenges · Pipelines ­ Retro-fitting existing NG pipeline for hydrogen ­ Utilizing existing NG pipeline for Hythane with cost effective hydrogen separation technology ­ New hydrogen pipeline

  9. Pyrochlore-type catalysts for the reforming of hydrocarbon fuels

    DOE Patents [OSTI]

    Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

    2012-03-13T23:59:59.000Z

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

  10. Hydrous metal oxide catalysts for oxidation of hydrocarbons

    SciTech Connect (OSTI)

    Miller, J.E.; Dosch, R.G.; McLaughlin, L.I. [Sandia National Labs., Albuquerque, NM (United States). Process Research Dept.

    1993-07-01T23:59:59.000Z

    This report describes work performed at Sandia under a CRADA with Shell Development of Houston, Texas aimed at developing hydrous metal oxide (HMO) catalysts for oxidation of hydrocarbons. Autoxidation as well as selective oxidation of 1-octene was studied in the presence of HMO catalysts based on known oxidation catalysts. The desired reactions were the conversion of olefin to epoxides, alcohols, and ketones, HMOs seem to inhibit autoxidation reactions, perhaps by reacting with peroxides or radicals. Attempts to use HMOs and metal loaded HMOs as epoxidation catalysts were unsuccessful, although their utility for this reaction was not entirely ruled out. Likewise, alcohol formation from olefins in the presence of HMO catalysts was not achieved. However, this work led to the discovery that acidified HMOs can lead to carbocation reactions of hydrocarbons such as cracking. An HMO catalyst containing Rh and Cu that promotes the reaction of {alpha}-olefins with oxygen to form methyl ketones was identified. Although the activity of the catalyst is relatively low and isomerization reactions of the olefin simultaneously occur, results indicate that these problems may be addressed by eliminating mass transfer limitations. Other suggestions for improving the catalyst are also made. 57 refs.

  11. Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy (Culver City, CA)

    1982-01-01T23:59:59.000Z

    In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

  12. Fuel Cell Electric Vehicle Powered by Renewable Hydrogen

    SciTech Connect (OSTI)

    None

    2011-01-01T23:59:59.000Z

    The National Renewable Energy Laboratory (NREL) recently received a Borrego fuel cell electric vehicle (FCEV) on loan from Kia for display at a variety of summer events. The Borrego is fueled using renewable hydrogen that is produced and dispensed at NREL's National Wind Technology Center near Boulder, Colorado. The hydrogen dispensed at the station is produced via renewable electrolysis as part of the wind-to-hydrogen project, which uses wind turbines and photovoltaic arrays to power electrolyzer stacks that split water into hydrogen and oxygen. The FCEV features state-of-the-art technology with zero harmful emissions.

  13. Method for the purification of noble gases, nitrogen and hydrogen

    DOE Patents [OSTI]

    Baker, John D. (Blackfoot, ID); Meikrantz, David H. (Idaho Falls, ID); Tuggle, Dale G. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    A method and apparatus for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes.

  14. Method for the purification of noble gases, nitrogen and hydrogen

    DOE Patents [OSTI]

    Baker, J.D.; Meikrantz, D.H.; Tuggle, D.G.

    1997-09-23T23:59:59.000Z

    A method and apparatus are disclosed for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes. 15 figs.

  15. Fuel Cell Electric Vehicle Powered by Renewable Hydrogen

    ScienceCinema (OSTI)

    None

    2013-05-29T23:59:59.000Z

    The National Renewable Energy Laboratory (NREL) recently received a Borrego fuel cell electric vehicle (FCEV) on loan from Kia for display at a variety of summer events. The Borrego is fueled using renewable hydrogen that is produced and dispensed at NREL's National Wind Technology Center near Boulder, Colorado. The hydrogen dispensed at the station is produced via renewable electrolysis as part of the wind-to-hydrogen project, which uses wind turbines and photovoltaic arrays to power electrolyzer stacks that split water into hydrogen and oxygen. The FCEV features state-of-the-art technology with zero harmful emissions.

  16. Electrolytic hydrogen production infrastructure options evaluation. Final subcontract report

    SciTech Connect (OSTI)

    Thomas, C.E.; Kuhn, I.F. Jr. [Directed Technologies, Inc., Arlington, VA (United States)

    1995-09-01T23:59:59.000Z

    Fuel-cell electric vehicles have the potential to provide the range, acceleration, rapid refueling times, and other creature comforts associated with gasoline-powered vehicles, but with virtually no environmental degradation. To achieve this potential, society will have to develop the necessary infrastructure to supply hydrogen to the fuel-cell vehicles. Hydrogen could be stored directly on the vehicle, or it could be derived from methanol or other hydrocarbon fuels by on-board chemical reformation. This infrastructure analysis assumes high-pressure (5,000 psi) hydrogen on-board storage. This study evaluates one approach to providing hydrogen fuel: the electrolysis of water using off-peak electricity. Other contractors at Princeton University and Oak Ridge National Laboratory are investigating the feasibility of producing hydrogen by steam reforming natural gas, probably the least expensive hydrogen infrastructure alternative for large markets. Electrolytic hydrogen is a possible short-term transition strategy to provide relatively inexpensive hydrogen before there are enough fuel-cell vehicles to justify building large natural gas reforming facilities. In this study, the authors estimate the necessary price of off-peak electricity that would make electrolytic hydrogen costs competitive with gasoline on a per-mile basis, assuming that the electrolyzer systems are manufactured in relatively high volumes compared to current production. They then compare this off-peak electricity price goal with actual current utility residential prices across the US.

  17. Design and Testing of a Labview- Controlled Catalytic Packed- Bed Reactor System For Production of Hydrocarbon Fuels

    SciTech Connect (OSTI)

    Street, J.; Yu, F.; Warnock, J.; Wooten, J.; Columbus, E.; White, M. G.

    2012-05-01T23:59:59.000Z

    Gasified woody biomass (producer gas) was converted over a Mo/H+ZSM-5 catalyst to produce gasolinerange hydrocarbons. The effect of contaminants in the producer gas showed that key retardants in the system included ammonia and oxygen. The production of gasoline-range hydrocarbons derived from producer gas was studied and compared with gasoline-range hydrocarbon production from two control syngas mixes. Certain mole ratios of syngas mixes were introduced into the system to evaluate whether or not the heat created from the exothermic reaction could be properly controlled. Contaminant-free syngas was used to determine hydrocarbon production with similar mole values of the producer gas from the gasifier. Contaminant-free syngas was also used to test an ideal contaminant-free synthesis gas situation to mimic our particular downdraft gasifier. Producer gas was used in this study to determine the feasibility of using producer gas to create gasoline-range hydrocarbons on an industrial scale using a specific Mo/H+ZSM-5 catalyst. It was determined that after removing the ammonia, other contaminants poisoned the catalyst and retarded the hydrocarbon production process as well.

  18. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01T23:59:59.000Z

    Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would becost than both. Solar-hydrogen fuel- cell vehicles would be

  19. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01T23:59:59.000Z

    Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September byet al. , 1988,1989 HYDROGEN FUEL-CELL VEHICLES: TECHNICALIn the FCEV, the hydrogen fuel cell could supply the "net"

  20. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01T23:59:59.000Z

    for the hydrogen refueling station. Compressor cost: inputcost) Compressor power requirement: input data 288.80 Initial temperature of hydrogen (Compressor cost per unit of output ($/hp/million standard ft [SCF] of hydrogen/

  1. Transition metal-promoted oxygen ion conductors as oxidation catalyst

    SciTech Connect (OSTI)

    Liu, W.; Sarofim, A. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Chemical Engineering; Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering

    1994-12-31T23:59:59.000Z

    A novel metal oxide composite catalyst for the complete oxidation of carbon monoxide and hydrocarbons was prepared by combining oxygen ion conducting materials with active transition metals. The oxygen ion conductors used were typical fluorite-type oxides, such as ceria, zirconia, and others. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of oxygen ion conductors. The intimate contact of the two kinds of materials gave rise to a highly active oxidation catalyst. On Cu-Ce-O composite catalysts, 95% of carbon monoxide was oxidized by air at {approximately} 100 C. Complete methane oxidation on the same catalyst took place at {approximately} 550 C. When the stoichiometric amount of sulfur dioxide was sued to oxidize carbon monoxide, 96% of sulfur dioxide was reduced to elemental sulfur at temperatures above 460 C with 99% of sulfur dioxide conversion. This type of composite catalyst also showed excellent resistance to water poisoning.

  2. Hydrogen production by water dissociation using ceramic membranes - annual report for FY 2010.

    SciTech Connect (OSTI)

    Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J. (Energy Systems)

    2011-03-14T23:59:59.000Z

    The objective of this project is to develop dense ceramic membranes that can produce hydrogen via coal/coal gas-assisted water dissociation without using an external power supply or circuitry. This project grew from an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen production by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen using OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

  3. Hydrogen production by water dissociation using ceramic membranes - annual report for FY 2008.

    SciTech Connect (OSTI)

    Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J.; Energy Systems

    2009-03-25T23:59:59.000Z

    The objective of this project is to develop dense ceramic membranes that, without using an external power supply or circuitry, can produce hydrogen via coal/coal gas-assisted water dissociation. This project grew from an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen production by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen by means of OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

  4. Dissociation of water on oxygen-covered Rh^111 A. Shavorskiy,1

    E-Print Network [OSTI]

    Schnadt, Joachim

    to the somewhat unusual situation that these water layers are actually hydrophobic due to the lack of hydrogenDissociation of water on oxygen-covered Rh^111 A. Shavorskiy,1 T. Eralp,1 E. Ataman,2 C. Isvoranu,2 November 2009; published online 4 December 2009 The adsorption of water and coadsorption with oxygen on Rh

  5. Hydrogen Fuel Cells and Storage Technology: Fundamental Research for Optimization of Hydrogen Storage and Utilization

    SciTech Connect (OSTI)

    Perret, Bob; Heske, Clemens; Nadavalath, Balakrishnan; Cornelius, Andrew; Hatchett, David; Bae, Chusung; Pang, Tao; Kim, Eunja; Hemmers, Oliver

    2011-03-28T23:59:59.000Z

    Design and development of improved low-cost hydrogen fuel cell catalytic materials and high-capacity hydrogenn storage media are paramount to enabling the hydrogen economy. Presently, effective and durable catalysts are mostly precious metals in pure or alloyed form and their high cost inhibits fuel cell applications. Similarly, materials that meet on-board hydrogen storage targets within total mass and volumetric constraints are yet to be found. Both hydrogen storage performance and cost-effective fuel cell designs are intimately linked to the electronic structure, morphology and cost of the chosen materials. The FCAST Project combined theoretical and experimental studies of electronic structure, chemical bonding, and hydrogen adsorption/desorption characteristics of a number of different nanomaterials and metal clusters to develop better fundamental understanding of hydrogen storage in solid state matrices. Additional experimental studies quantified the hydrogen storage properties of synthesized polyaniline(PANI)/Pd composites. Such conducting polymers are especially interesting because of their high intrinsic electron density and the ability to dope the materials with protons, anions, and metal species. Earlier work produced contradictory results: one study reported 7% to 8% hydrogen uptake while a second study reported zero hydrogen uptake. Cost and durability of fuel cell systems are crucial factors in their affordability. Limits on operating temperature, loss of catalytic reactivity and degradation of proton exchange membranes are factors that affect system durability and contribute to operational costs. More cost effective fuel cell components were sought through studies of the physical and chemical nature of catalyst performance, characterization of oxidation and reduction processes on system surfaces. Additional development effort resulted in a new hydrocarbon-based high-performance sulfonated proton exchange membrane (PEM) that can be manufactured at low cost and accompanied by improved mechanical and thermal stability.

  6. Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; French, Richard; Deutch, Steve; Iisa, Kristiina

    2014-08-14T23:59:59.000Z

    Hot-vapor filtered bio-oils were produced from two different biomass feedstocks, oak and switchgrass, and the oils were evaluated in hydroprocessing tests for production of liquid hydrocarbon products. Hot-vapor filtering reduced bio-oil yields and increased gas yields. The yields of fuel carbon as bio-oil were reduced by ten percentage points by hot-vapor filtering for both feedstocks. The unfiltered bio-oils were evaluated alongside the filtered bio-oils using a fixed bed catalytic hydrotreating test. These tests showed good processing results using a two-stage catalytic hydroprocessing strategy. Equal-sized catalyst beds, a sulfided Ru on carbon catalyst bed operated at 220°C and a sulfided CoMo on alumina catalyst bed operated at 400°C were used with the entire reactor at 100 atm operating pressure. The products from the four tests were similar. The light oil phase product was fully hydrotreated so that nitrogen and sulfur were below the level of detection, while the residual oxygen ranged from 0.3 to 2.0%. The density of the products varied from 0.80 g/ml up to 0.86 g/ml over the period of the test with a correlated change of the hydrogen to carbon atomic ratio from 1.79 down to 1.57, suggesting some loss of catalyst activity through the test. These tests provided the data needed to assess the suite of liquid fuel products from the process and the activity of the catalyst in relationship to the existing catalyst lifetime barrier for the technology.

  7. Hydrogen and Infrastructure Costs

    Broader source: Energy.gov (indexed) [DOE]

    FUEL CELL TECHNOLOGIES PROGRAM Hydrogen and Infrastructure Costs Hydrogen Infrastructure Market Readiness Workshop Washington D.C. February 17, 2011 Fred Joseck U.S. Department of...

  8. Hydrogen and fuel taxation.

    E-Print Network [OSTI]

    Hansen, Anders Chr.

    2007-01-01T23:59:59.000Z

    ??The competitiveness of hydrogen depends on how it is integrated in the energy tax system in Europe. This paper addresses the competitiveness of hydrogen and… (more)

  9. Hydrogen Permeation Barrier Coatings

    SciTech Connect (OSTI)

    Henager, Charles H.

    2008-01-01T23:59:59.000Z

    Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

  10. Hydrogen Program Overview

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to the DOE Hydrogen Program. It describes the program mission and answers the question: “Why Hydrogen?”

  11. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Sources Hydrogen Hydrogen September 30, 2014 Developed by Sandia National Laboratories and several industry partners, the fuel cell mobile light (H2LT) offers a cleaner, quieter...

  12. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately...

  13. Kinetics of Electron Transfer and Oxygen Evolution in the Reaction of [Ru(bpy)3]3+ with Colloidal Iridium Oxide

    E-Print Network [OSTI]

    hydrogen and oxygen has been studied since the early 1970s1 and today remains one of the major challenges in the field of chemistry.2 Overall water splitting has been demonstrated in series and tandem and oxygen. Although the reduction of water to hydrogen at noble metal catalysts is facile, the water

  14. Operating characteristics of a hydrogen-argon plasma torch for supersonic combustion applications

    SciTech Connect (OSTI)

    Barbi, E.; Mahan, J.R.; O'brien, W.F.; Wagner, T.C.

    1989-04-01T23:59:59.000Z

    The residence time of the combustible mixture in the combustion chamber of a scramjet engine is much less than the time normally required for complete combustion. Hydrogen and hydrocarbon fuels require an ignition source under conditions typically found in a scramjet combustor. Analytical studies indicate that the presence of hydrogen atoms should greatly reduce the ignition delay in this environment. Because hydrogen plasmas are prolific sources of hydrogen atoms, a low-power, uncooled hydrogen plasma torch has been built and tested to evaluate its potential as a possible flame holder for supersonic combustion. The torch was found to be unstable when operated on pure hydrogen; however, stable operation could be obtained by using argon as a body gas and mixing in the desired amount of hydrogen. The stability limits of the torch are delineated and its electrical and thermal behavior documented. An average torch thermal efficiency of around 88 percent is demonstrated. 10 references.

  15. CAN HYDROGEN WIN?: EXPLORING SCENARIOS FOR HYDROGEN

    E-Print Network [OSTI]

    such as biofuel plug-in hybrids, but did well when biofuels were removed or priced excessively. Hydrogen fuel cells failed unless costs were assumed to descend independent of demand. However, hydrogen vehicles were; Hydrogen as fuel -- Economic aspects; Technological innovations -- Environmental aspects; Climatic changes

  16. Detonations in Hydrocarbon Fuel Blends J.M. Austin and J.E. Shepherd

    E-Print Network [OSTI]

    Low, Steven H.

    .3), nitrogen dilutions (fuel-oxygen to fuel-air), and initial pressures (20-130 kPa). The cell widths of the JP to be comparable. The addition of lower molecular weight fuels (hydrogen, acetylene, ethylene, 1 #12;and carbon, but addition of more than about 75 % (by fuel mass) carbon monoxide results in a significant increase in cell

  17. Process and apparatus for coal hydrogenation

    DOE Patents [OSTI]

    Ruether, John A. (McMurray, PA); Simpson, Theodore B. (McLean, VA)

    1991-01-01T23:59:59.000Z

    In a coal liquefaction process an aqueous slurry of coal is prepared containing a dissolved liquefaction catalyst. A small quantity of oil is added to the slurry and then coal-oil agglomerates are prepared by agitation of the slurry at atmospheric pressure. The resulting mixture is drained of excess water and dried at atmospheric pressure leaving catalyst deposited on the agglomerates. The agglomerates then are fed to an extrusion device where they are formed into a continuous ribbon of extrudate and fed into a hydrogenation reactor at elevated pressure and temperature. The catalytic hydrogenation converts the extrudate primarily to liquid hydrocarbons in the reactor. The liquid drained in recovering the agglomerates is recycled.

  18. Hydrogenation of O and OH on Pt(111): A comparison between the reaction rates of the first and the second hydrogen addition steps

    SciTech Connect (OSTI)

    Näslund, L.-Ĺ., E-mail: lars-ake.naslund@liu.se [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States)

    2014-03-14T23:59:59.000Z

    The formation of water through hydrogenation of oxygen on platinum occurs at a surprisingly low reaction rate. The reaction rate limited process for this catalytic reaction is, however, yet to be settled. In the present work, the reaction rates of the first and the second hydrogen addition steps are compared when hydrogen is obtained through intense synchrotron radiation that induces proton production in a water overlayer on top of the adsorbed oxygen species. A substantial amount of the produced hydrogen diffuses to the platinum surface and promotes water formation at the two starting conditions O/Pt(111) and (H{sub 2}O+OH)/Pt(111). The comparison shows no significant difference in the reaction rate between the first and the second hydrogen addition steps, which indicates that the rate determining process of the water formation from oxygen on Pt(111) is neither the first nor the second H addition step or, alternatively, that both H addition steps exert rate control.

  19. Regenerable MgO promoted metal oxide oxygen carriers for chemical looping combustion

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.; Miller, Duane D.

    2014-08-19T23:59:59.000Z

    The disclosure provides an oxygen carrier comprised of a plurality of metal oxide particles in contact with a plurality of MgO promoter particles. The MgO promoter particles increase the reaction rate and oxygen utilization of the metal oxide when contacting with a gaseous hydrocarbon at a temperature greater than about 725.degree. C. The promoted oxide solid is generally comprised of less than about 25 wt. % MgO, and may be prepared by physical mixing, incipient wetness impregnation, or other methods known in the art. The oxygen carrier exhibits a crystalline structure of the metal oxide and a crystalline structure of MgO under XRD crystallography, and retains these crystalline structures over subsequent redox cycles. In an embodiment, the metal oxide is Fe.sub.2O.sub.3, and the gaseous hydrocarbon is comprised of methane.

  20. Water solubility data for 151 hydrocarbons

    SciTech Connect (OSTI)

    Yaws, C.L.; Pan, Xiang; Lin, Xiaoyin (Lamar Univ., Beaumont, TX (United States))

    1993-02-01T23:59:59.000Z

    The solubility of a hydrocarbon in water is important from both an environmental and a safety perspective. This information is required by engineers who design or operate stripping processes that remove hydrocarbons from air or water, or who must determine the amount of a hydrocarbon that has dissolved in water following a chemical spill. In particular, the water solubilities of paraffins are increasingly important because of more-stringent government regulations. Paraffins, along with naphthenes and aromatics, are the three major components of unrefined fuels. The water solubilities of 151 paraffins are listed in tables. The data are valid between 25 and 121 C, typical temperature in air- and steam-stripping operations. Also included is a correlation equation that allows users to estimate hydrocarbon solubilities above the given temperature range.

  1. Solubilization of petroleum hydrocarbons using biosurfactants

    E-Print Network [OSTI]

    Kanga, Shahrukh

    1995-01-01T23:59:59.000Z

    that bioavailability of the crude oil to the microorganisms limited the degradation rates (Mills, 1994). Preliminary experiments at our laboratories have also indicated enhanced solubilities of petroleum hydrocarbons due to the effects of biosurfactants (Kanga et al...

  2. Removal of trace olefins from aromatic hydrocarbons

    SciTech Connect (OSTI)

    Sachtler, J.W.A.; Barger, P.T.

    1989-01-03T23:59:59.000Z

    A process is described for treating a hydrocarbon process stream by converting trace quantities of olefinic impurities to nonolefinic hydrocarbons. The process comprises contacting the process stream, which contains trace olefins in an amount of from about 50 to about 2000 as measured by Bromine Index and at least 80% by weight of aromatic and naphthenic hydrocarbons having from 6 to 20 carbon atoms per molecule, at reaction conditions which ensure liquid phase operation with a solid catalyst composite comprising a crystalline aluminosilicate zeolite and a refractory inorganic oxide. A catalytic olefin-consuming alkylation reaction then produces an essentially olefinfree product stream with approximately the same quantity and distribution of aromatic and naphthenic hydrocarbons as contained in the process stream.

  3. Hydrogen Energy Technology Geoff Dutton

    E-Print Network [OSTI]

    Watson, Andrew

    Integrated gasification combined cycle (IGCC) Pyrolysis Water electrolysis Reversible fuel cell Hydrogen Hydrogen-fuelled internal combustion engines Hydrogen-fuelled turbines Fuel cells Hydrogen systems Overall expensive. Intermediate paths, employing hydrogen derived from fossil fuel sources, are already used

  4. Hydrogen Storage and Supply for Vehicular Fuel Systems

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2012-05-11T23:59:59.000Z

    Various alternative-fuel systems have been proposed for passenger vehicles and light-duty trucks to reduce the worldwide reliance on fossils fuels and thus mitigate their polluting effects.  Replacing gasoline and other refined hydrocarbon fuels continues to present research and implementation challenges for the automotive industry. During the last decade, hydrogen fuel technology has emerged as the prime alternative that will finally drive automotive fuel systems into the new millennium....

  5. Methods of reforming hydrocarbon fuels using hexaaluminate catalysts

    DOE Patents [OSTI]

    Gardner, Todd H. (Morgantown, WV); Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV)

    2012-03-27T23:59:59.000Z

    A metal substituted hexaaluminate catalyst for reforming hydrocarbon fuels to synthesis gas of the general formula AB.sub.yAl.sub.12-yO.sub.19-.delta., A being selected from alkali metals, alkaline earth metals and lanthanide metals or mixtures thereof. A dopant or surface modifier selected from a transitions metal, a spinel of an oxygen-ion conductor is incorporated. The dopant may be Ca, Cs, K, La, Sr, Ba, Li, Mg, Ce, Co, Fe, Ir, Rh, Ni, Ru, Cu, Pe, Os, Pd, Cr, Mn, W, Re, Sn, Gd, V, Ti, Ag, Au, and mixtures thereof. The oxygen-ion conductor may be a perovskite selected from M'RhO.sub.3, M'PtO.sub.3, M'PdO.sub.3, M'IrO.sub.3, M'RuO.sub.3 wherein M'=Mg, Sr, Ba, La, Ca; a spinel selected from MRh.sub.2O.sub.4, MPt.sub.2O.sub.4, MPd.sub.2O.sub.4, MIr.sub.2O.sub.4, MRu.sub.2O.sub.4 wherein M=Mg, Sr, Ba, La, Ca and mixtures thereof; a florite is selected from M''O.sub.2.

  6. Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte Ranga S. Jayashree, Michael Mitchell, Dilip Natarajan, Larry J. Markoski, and

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Letters Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte Ranga S. Jayashree, Michael and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion membrane as the electrolyte. We studied the effect of cell resistance, hydrogen and oxygen flow rates

  7. of hydrogen-powered cars," he says. But a major hurdle remains: the cost of platinum metal

    E-Print Network [OSTI]

    of hydrogen-powered cars," he says. But a major hurdle remains: the cost of platinum metal needed to make fuel cells efficient. Fuel cells work by combining hydrogen gas with oxygen from the air for hydrogen-powered cars in mass production facilities," says SFU chemistry professor Steve Holdcroft, who

  8. Methods and systems for the production of hydrogen

    DOE Patents [OSTI]

    Oh, Chang H. (Idaho Falls, ID); Kim, Eung S. (Ammon, ID); Sherman, Steven R. (Augusta, GA)

    2012-03-13T23:59:59.000Z

    Methods and systems are disclosed for the production of hydrogen and the use of high-temperature heat sources in energy conversion. In one embodiment, a primary loop may include a nuclear reactor utilizing a molten salt or helium as a coolant. The nuclear reactor may provide heat energy to a power generation loop for production of electrical energy. For example, a supercritical carbon dioxide fluid may be heated by the nuclear reactor via the molten salt and then expanded in a turbine to drive a generator. An intermediate heat exchange loop may also be thermally coupled with the primary loop and provide heat energy to one or more hydrogen production facilities. A portion of the hydrogen produced by the hydrogen production facility may be diverted to a combustor to elevate the temperature of water being split into hydrogen and oxygen by the hydrogen production facility.

  9. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  10. Hydrogen Delivery Liquefaction & Compression

    E-Print Network [OSTI]

    Hydrogen Delivery Liquefaction & Compression Raymond Drnevich Praxair - Tonawanda, NY Strategic Initiatives for Hydrogen Delivery Workshop - May 7, 2003 #12;2 Agenda Introduction to Praxair Hydrogen Liquefaction Hydrogen Compression #12;3 Praxair at a Glance The largest industrial gas company in North

  11. NATIONAL HYDROGEN ENERGY ROADMAP

    E-Print Network [OSTI]

    NATIONAL HYDROGEN ENERGY ROADMAP NATIONAL HYDROGEN ENERGY ROADMAP . . Toward a More Secure and Cleaner Energy Future for America Based on the results of the National Hydrogen Energy Roadmap Workshop to make it a reality. This Roadmap provides a framework that can make a hydrogen economy a reality

  12. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2002-07-01T23:59:59.000Z

    In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

  13. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15T23:59:59.000Z

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  14. Hydrogen and oxygen adsorption stoichiometries on silica supported ruthenium nanoparticles

    SciTech Connect (OSTI)

    Berthoud, Romain; Delichere, Pierre; Gajan, David; Lukens, Wayne; Pelzer, Katrin; Basset, Jean-Marie; Candy, Jean-Pierre; Coperet, Christophe

    2008-12-01T23:59:59.000Z

    Treatment under H{sub 2} at 300 C of Ru(COD)(COT) dispersed on silica yields 2 nm ruthenium nanoparticles, [Ru{sub p}/SiO{sub 2}], according to EXAFS, HRTEM and XPS. H{sub 2} adsorption measurements on [Ru{sub p}/SiO{sub 2}] in the absence of O{sub 2} show that Ru particles adsorb up to ca. 2 H per surface ruthenium atoms (2H/Ru{sub s}) on various samples; this technique can therefore be used to measure the dispersion of Ru particles. In contrast, O{sub 2} adsorption on [Ru{sub p}/SiO{sub 2}] leads to a partial oxidation of the bulk at 25 C, to RuO{sub 2} at 200 C and to sintering upon further reduction under H{sub 2}, showing that O{sub 2} adsorption cannot be used to measure the dispersion of Ru particles.

  15. Ceramic Membranes for Hydrogen/Oxygen Production - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStanding Friedel Waves,TheoryParliament'v0, 12/9/14Ceramic

  16. Self-powered Hydrogen + Oxygen Injection System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartment of Energy Moniz: WhatM-1at theFigureSelf-powered

  17. Hydrogen (H2) Production by Oxygenic Phototrophs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Groundto Apply forInstitute Mission&

  18. Gaseous Hydrogen Delivery Breakout - Strategic Directions for...

    Broader source: Energy.gov (indexed) [DOE]

    Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop...

  19. Composition for absorbing hydrogen

    DOE Patents [OSTI]

    Heung, L.K.; Wicks, G.G.; Enz, G.L.

    1995-05-02T23:59:59.000Z

    A hydrogen absorbing composition is described. The composition comprises a porous glass matrix, made by a sol-gel process, having a hydrogen-absorbing material dispersed throughout the matrix. A sol, made from tetraethyl orthosilicate, is mixed with a hydrogen-absorbing material and solidified to form a porous glass matrix with the hydrogen-absorbing material dispersed uniformly throughout the matrix. The glass matrix has pores large enough to allow gases having hydrogen to pass through the matrix, yet small enough to hold the particles dispersed within the matrix so that the hydrogen-absorbing particles are not released during repeated hydrogen absorption/desorption cycles.

  20. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  1. High-energy-density solid and liquid hydrocarbon fuels. Final report, July 1987-December 1988

    SciTech Connect (OSTI)

    Marchand, A.P.

    1989-02-01T23:59:59.000Z

    The development of new high-energy hydrocarbon fuels for use in air-breathing missiles has been the objective of a number of investigations which have received support during the past decade through programs sponsored by the Air Force Systems Command and/or the Naval Air Systems Command. The key characteristics which must be met by potential cruise missile fuels have been described by Burdette and coworkers. A primary requirement in this regard is that candidate fuels must possess high net volumetric heat of combustion (preferably greater than 160,000 BTU/gallon). In order to meet the primary requirement of high net volumetric heat of combustion, hydrocarbon systems have been sought which maximize the ratio of carbon-atom to hydrogen-atom content have been sought that maximize the ratio n/m.(JES)

  2. Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids

    SciTech Connect (OSTI)

    Not Available

    1981-10-01T23:59:59.000Z

    The mechanisms by which various fuel component hydrocarbons related to both heavy petroleum and coal-derived liquids are converted to hydrogen without forming carbon were investigated. Reactive differences between paraffins and aromatics in autothermal reforming (ATR) were shown to be responsible for the observed fuel-specific carbon formation characteristics. The types of carbon formed in the reformer were identified by SEM and XRD analyses of catalyst samples and carbon deposits. From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation. The effects of propylene addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics, synergistic effects on conversion characteristics were identified. Indications that the sulfur content of the fuel may be the limiting factor for efficient ATR operation were found. The conversion and degradation effects of the sulfur additive (thiophene) were examined.

  3. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  4. E-Print Network 3.0 - aromatic hydrocarbons estimated Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences 26 2006-01-0201 Speciated Hydrocarbon Emissions from an Automotive Diesel Summary: estimated for many hydrocarbons 26, 27. The MIR of a hydrocarbon is the...

  5. E-Print Network 3.0 - aromatic hydrocarbons investigated Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

  6. E-Print Network 3.0 - aromatic hydrocarbon investigation Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

  7. E-Print Network 3.0 - aromatic hydrocarbons evaluated Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

  8. E-Print Network 3.0 - aromatic hydrocarbon diol-epoxide Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

  9. E-Print Network 3.0 - aromatic hydrocarbon residues Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

  10. E-Print Network 3.0 - aromatic hydrocarbons analyses Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compounds with two multiple-ringed polynuclear aromatic hydrocarbons (PAHs) or naphthenic hydrocarbons... Prediction of hydrocarbon molecular structure using infrared, Raman,...

  11. Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Permeability and Integrity of Hydrogen Delivery Pipelines Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Project Objectives: To gain basic understanding of...

  12. DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...

    Broader source: Energy.gov (indexed) [DOE]

    5037: Hydrogen Storage Materials - 2004 vs. 2006 DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials - 2004 vs. 2006 This program record from the Department...

  13. Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

  14. Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping...

    Broader source: Energy.gov (indexed) [DOE]

    Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22, 2002-July 22, 2002 Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22,...

  15. Some general laws of the hydrogenation of carbon monoxide on metals

    SciTech Connect (OSTI)

    Golodets, G.I.; Pavlenko, N.V.; Tripol'skii, A.I.

    1988-01-01T23:59:59.000Z

    The catalytic properties of supported transition metals in the hydrogenation of CO to hydrocarbons have been studied. A kinetic model interpreting the unusual dependence of the activation energy on temperature is proposed. It is shown that the catalytic activity (r) decreases and the selectivity with respect to methane (SCH/sub 4/) increases with an increase in the heat of adsorption of CO.

  16. Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report Section VII. Conversion Devices

    E-Print Network [OSTI]

    addition on flame stability, combustor acoustics, emissions and efficiency in a gas turbine. · Establish burner that simulates the basic features of gas turbine combustors. · Apply advanced experimental problem areas in practical gas turbine combustors where hydrogen enrichment of hydrocarbon fuels could

  17. DEVELOPMENT OF DOPED NANOPOROUS CARBONS FOR HYDROGEN STORAGE

    SciTech Connect (OSTI)

    Angela D. Lueking; Qixiu Li; John V. Badding; Dania Fonseca; Humerto Gutierrez; Apurba Sakti; Kofi Adu; Michael Schimmel

    2010-03-31T23:59:59.000Z

    Hydrogen storage materials based on the hydrogen spillover mechanism onto metal-doped nanoporous carbons are studied, in an effort to develop materials that store appreciable hydrogen at ambient temperatures and moderate pressures. We demonstrate that oxidation of the carbon surface can significantly increase the hydrogen uptake of these materials, primarily at low pressure. Trace water present in the system plays a role in the development of active sites, and may further be used as a strategy to increase uptake. Increased surface density of oxygen groups led to a significant enhancement of hydrogen spillover at pressures less than 100 milibar. At 300K, the hydrogen uptake was up to 1.1 wt. % at 100 mbar and increased to 1.4 wt. % at 20 bar. However, only 0.4 wt% of this was desorbable via a pressure reduction at room temperature, and the high lowpressure hydrogen uptake was found only when trace water was present during pretreatment. Although far from DOE hydrogen storage targets, storage at ambient temperature has significant practical advantages oner cryogenic physical adsorbents. The role of trace water in surface modification has significant implications for reproducibility in the field. High-pressure in situ characterization of ideal carbon surfaces in hydrogen suggests re-hybridization is not likely under conditions of practical interest. Advanced characterization is used to probe carbon-hydrogen-metal interactions in a number of systems and new carbon materials have been developed.

  18. Method for providing oxygen ion vacancies in lanthanide oxides

    DOE Patents [OSTI]

    Kay, D. Alan R. (4305 Lakeshore Rd., Burlington, CA); Wilson, William G. (820 Harden Dr., Pittsburgh, PA 15229)

    1989-12-05T23:59:59.000Z

    A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

  19. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (‘syngas’) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  20. Hydrogen energy systems studies

    SciTech Connect (OSTI)

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M. [Princeton Univ., NJ (United States)] [and others

    1996-10-01T23:59:59.000Z

    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  1. Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

    DOE Patents [OSTI]

    Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

    2014-01-07T23:59:59.000Z

    A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

  2. The role of oxygen in the uptake of deuterium in lithiated graphite

    SciTech Connect (OSTI)

    C.N. Taylor; J. Dadras; K.E. Luitjohan; J.P. Allain; P.S. Krstic; C.H. Skinner

    2013-12-01T23:59:59.000Z

    We investigate the mechanism of deuterium retention by lithiated graphite and its relationship to the oxygen concentration through surface sensitive experiments and atomistic simulations. Deposition of lithium on graphite yielded 5%–8% oxygen surface concentration and when subsequently irradiated with D ions at energies between 500 and 1000?eV/amu and fluences over 1016?cm-2 the oxygen concentration rose to between 25% and 40%. These enhanced oxygen levels were reached in a few seconds compared to about 300?h when the lithiated graphite was allowed to adsorb oxygen from the ambient environment under equilibrium conditions. Irradiating graphite without lithium deposition, however, resulted in complete removal of oxygen to levels below the detection limit of XPS (e.g., <1%). These findings confirm the predictions of atomistic simulations, which had concluded that oxygen was the primary component for the enhanced hydrogen retention chemistry on the lithiated graphite surface.

  3. Hydrogen Bus Technology Validation Program

    E-Print Network [OSTI]

    Burke, Andy; McCaffrey, Zach; Miller, Marshall; Collier, Kirk; Mulligan, Neal

    2005-01-01T23:59:59.000Z

    and evaluate hydrogen enriched natural gas (HCNG) enginewas to demonstrate that hydrogen enriched natural gas (HCNG)characteristics of hydrogen enriched natural gas combustion,

  4. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    will trump hydrogen and fuel cell vehicles. Advocates ofbenefits sooner than hydrogen and fuel cells ever could.emissions from a hydrogen fuel cell vehicle will be about

  5. Liquid Hydrogen Absorber for MICE

    E-Print Network [OSTI]

    Ishimoto, S.

    2010-01-01T23:59:59.000Z

    REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

  6. Hydrogen in semiconductors and insulators

    E-Print Network [OSTI]

    Van de Walle, Chris G.

    2007-01-01T23:59:59.000Z

    the electronic level of hydrogen (thick red bar) was notdescribing the behavior of hydrogen atoms as impuritiesenergy of interstitial hydrogen as a function of Fermi level

  7. Support and crystallite effects in CO hydrogenation on nickel

    SciTech Connect (OSTI)

    Bartholomew, C.H.; Pannell, R.B.; Butler, J.L.

    1980-10-01T23:59:59.000Z

    The adsorption and reaction of carbon monoxide and hydrogen were studied on seven alumina-supported catalysts containing 0.5-23% nickel, four silica-supported catalysts containing 2.7-15% nickel, and 2.8 and 15% nickel on titanium oxide. On the silica and alumina-supported catalysts, hydrogen adsorption, per cent reduction of metal, carbon monoxide/hydrogen adsorption ratio, and methane yield increased with increasing metal dispersion, the methane turnover number decreased with increasing metal dispersion, and the carbon monoxide turnover number was not affected by dispersion. Hydrogen adsorption was suppressed by the titanium dioxide support. The suppression of hydrogen adsorption and the activity for carbon monoxide hydrogenation decreased as a function of support in the order TiO/sub 2/ > Al/sub 2/O/sub 3/ > SiO/sub 2/ and apparently depended on the strength of the electronic interaction of support and metal. The selectivity shifted to higher hydrocarbons as the metal dispersion increased and as the carbon monoxide/hydrogen adsorption ratio increased. Effects of preparation method are also reported.

  8. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25T23:59:59.000Z

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  9. Oxygen-stabilized zirconium-vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1981-10-06T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula Zr/sub x/OV/sub y/ where x = 0.7 to 2.0 and y = 0.18 to 0.33 is described. The compound is capable of reversibly sorbing hydrogen at temperatures from - 196/sup 0/C to 450/sup 0/C at pressures down to 10/sup -6/ Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO/sub 2/.

  10. Hydrogen Delivery Technologies and Pipeline Transmission of Hydrogen

    E-Print Network [OSTI]

    Hydrogen Delivery Technologies and Systems Pipeline Transmission of Hydrogen Strategic Initiatives, and Infrastructure Technologies Program #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Design & Operation development) #12;Pipeline Transmission of Hydrogen --- 3 Copyright: Future H2 Infrastructure Wind Powered

  11. Gaseous Hydrogen Delivery Breakout- Strategic Directions for Hydrogen Delivery Workshop

    Broader source: Energy.gov [DOE]

    Targets, barriers and research and development priorities for gaseous delivery of hydrogen through hydrogen and natural gas pipelines.

  12. A HYDROGEN IGNITION MECHANISM FOR EXPLOSIONS IN NUCLEAR FACILITY PIPING SYSTEMS

    SciTech Connect (OSTI)

    Leishear, R.

    2013-03-28T23:59:59.000Z

    Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein. Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions may occur. Pipe ruptures in nuclear reactor cooling systems were attributed to hydrogen explosions inside pipelines, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents, an ignition source for hydrogen was not clearly demonstrated, but these accidents demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. A new theory to identify an ignition source and explosion cause is presented here, and further research is recommended to fully understand this explosion mechanism.

  13. DOE Hydrogen Program Overview

    Broader source: Energy.gov (indexed) [DOE]

    Intl. J. Hydrogen Energy 27: 1217-1228 Melis A, Seibert M and Happe T (2004) Genomics of green algal hydrogen research. Photosynth. Res. 82: 277- 288 Maness P-C, Smolinski...

  14. Gaseous Hydrogen Delivery Breakout

    E-Print Network [OSTI]

    Gaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7 detection Pipeline Safety: odorants, flame visibility Compression: cost, reliability #12;Breakout Session goal of a realistic, multi-energy distribution network model Pipeline Technology Improved field

  15. Hydrogen transport membranes

    DOE Patents [OSTI]

    Mundschau, Michael V.

    2005-05-31T23:59:59.000Z

    Composite hydrogen transport membranes, which are used for extraction of hydrogen from gas mixtures are provided. Methods are described for supporting metals and metal alloys which have high hydrogen permeability, but which are either too thin to be self supporting, too weak to resist differential pressures across the membrane, or which become embrittled by hydrogen. Support materials are chosen to be lattice matched to the metals and metal alloys. Preferred metals with high permeability for hydrogen include vanadium, niobium, tantalum, zirconium, palladium, and alloys thereof. Hydrogen-permeable membranes include those in which the pores of a porous support matrix are blocked by hydrogen-permeable metals and metal alloys, those in which the pores of a porous metal matrix are blocked with materials which make the membrane impervious to gases other than hydrogen, and cermets fabricated by sintering powders of metals with powders of lattice-matched ceramic.

  16. Hydrogen Fuel Quality (Presentation)

    SciTech Connect (OSTI)

    Ohi, J.

    2007-05-17T23:59:59.000Z

    Jim Ohi of NREL's presentation on Hydrogen Fuel Quality at the 2007 DOE Hydrogen Program Annual Merit Review and Peer Evaluation on May 15-18, 2007 in Arlington, Virginia.

  17. Miniature Enzyme-Based Electrodes for Detection of Hydrogen Peroxide Release from Alcohol-Injured Hepatocytes

    E-Print Network [OSTI]

    Ferrara, Katherine W.

    generated by hepatocytes has not been undertaken to the best of our knowledge. Hydrogen peroxide (H2O2Miniature Enzyme-Based Electrodes for Detection of Hydrogen Peroxide Release from Alcohol clinical and experimental studies, it has been found that the production of reactive oxygen species (ROS

  18. An experimental investigation of the ignition properties of hydrogen and carbon monoxide

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    for syngas turbine applications S.M. Walton *, X. He, B.T. Zigler, M.S. Wooldridge Department of Mechanical of simulated syngas mixtures of hydrogen (H2), carbon monoxide (CO), oxygen (O2), nitrogen (N2), and carbon. Keywords: Carbon monoxide; Hydrogen; Syngas; Ignition; Rapid compression facility 1. Introduction Syngas

  19. Hydrogen separation membranes annual report for FY 2006.

    SciTech Connect (OSTI)

    Balachandran, U.; Chen, L.; Ciocco, M.; Doctor, R. D.; Dorris, S.E.; Emerson, J. E.; Fisher, B.; Lee, T. H.; Killmeyer, R. P.; Morreale,B.; Picciolo, J. J.; Siriwardane, R. V.; Song, S. J.

    2007-02-05T23:59:59.000Z

    The objective of this work is to develop dense ceramic membranes for separating hydrogen from other gaseous components in a nongalvanic mode, i.e., without using an external power supply or electrical circuitry. This goal of this project is to develop two types of dense ceramic membrane for producing hydrogen nongalvanically, i.e., without electrodes or external power supply, at commercially significant fluxes under industrially relevant operating conditions. The first type of membrane, hydrogen transport membranes (HTMs), will be used to separate hydrogen from gas mixtures such as the product streams from coal gasification, methane partial oxidation, and water-gas shift reactions. Potential ancillary uses of HTMs include dehydrogenation and olefin production, as well as hydrogen recovery in petroleum refineries and ammonia synthesis plants, the largest current users of deliberately produced hydrogen. The second type of membrane, oxygen transport membranes (OTMs), will produce hydrogen by nongalvanically removing oxygen that is generated when water dissociates at elevated temperatures. This report describes progress that was made during FY 2006 on the development of OTM and HTM materials.

  20. Conversion of methane and acetylene into gasoline range hydrocarbons

    E-Print Network [OSTI]

    Alkhawaldeh, Ammar

    2000-01-01T23:59:59.000Z

    Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene...

  1. Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection

    E-Print Network [OSTI]

    Cai, Rui

    2012-02-14T23:59:59.000Z

    result in successful hydrocarbon finds because abnormal seismic amplitude variations can sometimes be caused by other factors, such as alternative lithology and residual hydrocarbons in certain depositional environments. Furthermore, not all gas fields...

  2. Chemical nature of high-molecular hydrocarbons of gaseous condensates

    SciTech Connect (OSTI)

    Kul'dzhayev, B.A.; Makarov, V.V.; Sergiyenko, S.R.; Khramova, E.V.

    1987-01-01T23:59:59.000Z

    Mass spectrometry was used to study the group-structure composition of high-boiling 50 deg (200/degrees/-250/degrees/, 250/degrees/-300/degrees/, and 300/degrees/-350/degrees/C) fractions of East Turkmenistan condensates: the hydrocarbons composition is characterized by a high content of paraffinic hydrocarbons, and that of others by aromatic and naphthenic hydrocarbons. For all the condensates under investigation, as the boiling temperature of fractions increases, the content of paraffinic hydrocarbons in them is increased, while that of naphthenic hydrocarbons is reduced. The distribution of naphthenic hydrocarbons according to the number of rings is identical. In high-paraffin condensates, monoaromatic hydrocarbons consist mainly structures with alkyl substituents, but in condensates with a high content of aromatic and naphthenic hydrocarbons they consist mainly of structures with naphthenic substituents. 4 references, 1 figures, 2 tables.

  3. Sustainable treatment of hydrocarbon-contaminated industrial land 

    E-Print Network [OSTI]

    Cunningham, Colin John

    2012-06-25T23:59:59.000Z

    Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

  4. A Parametric Study of the Effect of Temperature and Hydrocarbon...

    Broader source: Energy.gov (indexed) [DOE]

    of Temperature and Hydrocarbon Species on the Product Distribution from a Non-Thermal Plasma Reactor A Parametric Study of the Effect of Temperature and Hydrocarbon Species on the...

  5. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2003-01-01T23:59:59.000Z

    In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

  6. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1997-01-01T23:59:59.000Z

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  7. Hydrogen Technologies Safety Guide

    SciTech Connect (OSTI)

    Rivkin, C.; Burgess, R.; Buttner, W.

    2015-01-01T23:59:59.000Z

    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  8. Webinar: Hydrogen Refueling Protocols

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Hydrogen Refueling Protocols, originally presented on February 22, 2013.

  9. E-Print Network 3.0 - aromatic hydrocarbons methyl Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Renewable Energy 2 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

  10. E-Print Network 3.0 - aromatic hydrocarbons progress Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collection: Chemistry 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

  11. E-Print Network 3.0 - aromatic hydrocarbons fluorene Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

  12. E-Print Network 3.0 - aromatic hydrocarbon phenanthrene Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

  13. E-Print Network 3.0 - aromatic hydrocarbons based Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... Rana Novini ATOC 3500 Burn...

  14. E-Print Network 3.0 - aromatic hydrocarbons Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

  15. E-Print Network 3.0 - aromatic hydrocarbons pah5 Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants Summary: 1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous,...

  16. E-Print Network 3.0 - aromatic hydrocarbons inenvironmental Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

  17. E-Print Network 3.0 - aromatic hydrocarbon o-quinones Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

  18. E-Print Network 3.0 - aromatic hydrocarbons assessment Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... of airborne soot. The air...

  19. Questions and Issues on Hydrogen Pipeline Transmission of Hydrogen

    E-Print Network [OSTI]

    Questions and Issues on Hydrogen Pipelines Pipeline Transmission of Hydrogen Doe Hydrogen Pipeline Working Group Meeting August 31, 2005 #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Air Liquide Transmission of Hydrogen --- 3 Copyright: #12;Pipeline Transmission of Hydrogen --- 4 Copyright: 3. Special

  20. Method and apparatus for low temperature destruction of halogenated hydrocarbons

    DOE Patents [OSTI]

    Reagen, William Kevin (Stillwater, MN); Janikowski, Stuart Kevin (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    A method and apparatus for decomposing halogenated hydrocarbons are provided. The halogenated hydrocarbon is mixed with solvating agents and maintained in a predetermined atmosphere and at a predetermined temperature. The mixture is contacted with recyclable reactive material for chemically reacting with the recyclable material to create dehalogenated hydrocarbons and halogenated inorganic compounds. A feature of the invention is that the process enables low temperature destruction of halogenated hydrocarbons.

  1. aromatic hydrocarbons coated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: ??Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, known human lung carcinogens, and potent mammary carcinogens in animal models....

  2. OXYGEN DEPLETION IN THE INTERSTELLAR MEDIUM: IMPLICATIONS FOR GRAIN MODELS AND THE DISTRIBUTION OF ELEMENTAL OXYGEN

    SciTech Connect (OSTI)

    Whittet, D. C. B. [New York Center for Astrobiology, and Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, 110 Eighth Street, Troy, NY 12180 (United States)

    2010-02-20T23:59:59.000Z

    This paper assesses the implications of a recent discovery that atomic oxygen is being depleted from diffuse interstellar gas at a rate that cannot be accounted for by its presence in silicate and metallic oxide particles. To place this discovery in context, the uptake of elemental O into dust is considered over a wide range of environments, from the tenuous intercloud gas and diffuse clouds sampled by the depletion observations to dense clouds where ice mantles and gaseous CO become important reservoirs of O. The distribution of O in these contrasting regions is quantified in terms of a common parameter, the mean number density of hydrogen (n{sub H}). At the interface between diffuse and dense phases (just before the onset of ice-mantle growth) as much as {approx}160 ppm of the O abundance is unaccounted for. If this reservoir of depleted oxygen persists to higher densities it has implications for the oxygen budget in molecular clouds, where a shortfall of the same order is observed. Of various potential carriers, the most plausible appears to be a form of O-bearing carbonaceous matter similar to the organics found in cometary particles returned by the Stardust mission. The 'organic refractory' model for interstellar dust is re-examined in the light of these findings, and it is concluded that further observations and laboratory work are needed to determine whether this class of material is present in quantities sufficient to account for a significant fraction of the unidentified depleted oxygen.

  3. Hydrogen Production CODES & STANDARDS

    E-Print Network [OSTI]

    Hydrogen Production DELIVERY FUEL CELLS STORAGE PRODUCTION TECHNOLOGY VALIDATION CODES & STANDARDS for 2010 · Reduce the cost of distributed production of hydrogen from natural gas and/or liquid fuels to $1 SYSTEMS INTEGRATION / ANALYSES SAFETY EDUCATION RESEARCH & DEVELOPMENT Economy Pete Devlin #12;Hydrogen

  4. Sensitive hydrogen leak detector

    DOE Patents [OSTI]

    Myneni, Ganapati Rao (Yorktown, VA)

    1999-01-01T23:59:59.000Z

    A sensitive hydrogen leak detector system using passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor.

  5. In situ method for recovering hydrocarbon from subterranean oil shale deposits

    SciTech Connect (OSTI)

    Friedman, R.H.

    1987-11-03T23:59:59.000Z

    This patent describes in situ method for recovering hydrocarbons from subterranean oil shale deposits, the deposits comprising mineral rock and kerogen, comprising (a) penetrating the oil shale deposit with at least one well; (b) forming a zone of fractured and/or rubbilized oil shale material adjacent the well by hydraulic or explosive fracturing; (c) introducing a hydrogen donor solvent including tetralin into the portion of the oil shale formation treated in step (b) in a volume sufficient to fill substantially all of the void space created by the fracturing and rubbilizing treatment; (d) applying hydrogen to the tetralin and maintaining a predetermined pressure for a predetermined period of time sufficient to cause disintegration of the oil shale material; (e) thereafter introducing an oxidative environment into the portion of the oil shale deposit (f) producing the solvent in organic fragments to the surface of the earth, and (g) separating the organic fragments from the solvent.

  6. A C-H...O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif

    E-Print Network [OSTI]

    Babu, M. Madan

    A C-H...O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C-terminus of Helices between the C atom of residue Ala 4 (T-4) and the backbone oxygen atom of DLeu 9. The C-H...O hydrogen Nitrogenase MoFe protein (PDB: 1qh8). The N-H...O hydrogen bond parameters are: O...N = 3.19Ă?; O...H = 2.48 Ă?

  7. Hydrogen Delivery Liquefaction and Compression

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Liquefaction and Compression - Overview of commercial hydrogen liquefaction and compression and opportunities to improve efficiencies and reduce cost.

  8. Alternative Transportation Technologies: Hydrogen, Biofuels,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transportation Technologies: Hydrogen, Biofuels, Advanced Efficiency, and Plug-in Hybrid Electric Vehicles Alternative Transportation Technologies: Hydrogen, Biofuels, Advanced...

  9. Hydrogen production from water: Recent advances in photosynthesis research

    SciTech Connect (OSTI)

    Greenbaum, E.; Lee, J.W. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.

    1997-12-31T23:59:59.000Z

    The great potential of hydrogen production by microalgal water splitting is predicated on quantitative measurement of the algae`s hydrogen-producing capability, which is based on the following: (1) the photosynthetic unit size of hydrogen production; (2) the turnover time of photosynthetic hydrogen production; (3) thermodynamic efficiencies of conversion of light energy into the Gibbs free energy of molecular hydrogen; (4) photosynthetic hydrogen production from sea water using marine algae; (5) the potential for research advances using modern methods of molecular biology and genetic engineering to maximize hydrogen production. ORNL has shown that sustained simultaneous photoevolution of molecular hydrogen and oxygen can be performed with mutants of the green alga Chlamydomonas reinhardtii that lack a detectable level of the Photosystem I light reaction. This result is surprising in view of the standard two-light reaction model of photosynthesis and has interesting scientific and technological implications. This ORNL discovery also has potentially important implications for maximum thermodynamic conversion efficiency of light energy into chemical energy by green plant photosynthesis. Hydrogen production performed by a single light reaction, as opposed to two, implies a doubling of the theoretically maximum thermodynamic conversion efficiency from {approx}10% to {approx}20%.

  10. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

  11. Production of hydrocarbons from hydrates. [DOE patent application

    DOE Patents [OSTI]

    McGuire, P.L.

    1981-09-08T23:59:59.000Z

    An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

  12. Method for removing chlorine compounds from hydrocarbon mixtures

    DOE Patents [OSTI]

    Janoski, E.J.; Hollstein, E.J.

    1984-09-29T23:59:59.000Z

    A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

  13. Hydrogen separation process

    DOE Patents [OSTI]

    Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

    2011-05-24T23:59:59.000Z

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  14. Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

    1981-02-19T23:59:59.000Z

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  15. Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

    1983-01-01T23:59:59.000Z

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  16. Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

    1984-01-01T23:59:59.000Z

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  17. Anti-Hydrogen Jonny Martinez

    E-Print Network [OSTI]

    Budker, Dmitry

    Anti-Hydrogen Jonny Martinez University of California, Berkeley #12;OUTLINE WHAT IS ANTI-HYDROGEN? HISTORY IMPORTANCE THEORY HOW TO MAKE ANTI-HYDROGEN OTHER ANTI-MATTER EXPERIMENTS CONCLUSION #12;WHAT IS ANTI-HYDROGEN? Anti-hydrogen is composed of a Positron(anti-electron) and anti-Proton. Anti-Hydrogen

  18. Method of dispersing a hydrocarbon using bacteria

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1996-01-01T23:59:59.000Z

    New protozoan derived microbial consortia and method for their isolation are provided. Consortia and bacteria isolated therefrom are useful for treating wastes such as trichloroethylene and trinitrotoluene. Consortia, bacteria isolated therefrom, and dispersants isolated therefrom are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

  19. Mass Transfer of Polynuclear Aromatic Hydrocarbons from

    E-Print Network [OSTI]

    Peters, Catherine A.

    of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

  20. Method for producing hydrogen

    SciTech Connect (OSTI)

    Preston, J.L.

    1980-02-26T23:59:59.000Z

    In a method for producing high quality hydrogen, the carbon monoxide level of a hydrogen stream which also contains hydrogen sulfide is shifted in a bed of iron oxide shift catalyst to a desired low level of carbon monoxide using less catalyst than the minimum amount of catalyst which would otherwise be required if there were no hydrogen sulfide in the gas stream. Under normal operating conditions the presence of even relatively small amounts of hydrogen sulfide can double the activity of the catalyst such that much less catalyst may be used to do the same job.

  1. Experimental and modeling investigation of aromatic and polycyclic aromatic hydrocarbon formation in a premixed ethylene flame

    SciTech Connect (OSTI)

    Castaldi, M.J.; Marinov, N.M.; Melius, C.F. [and others

    1996-02-01T23:59:59.000Z

    Experimental and detailed chemical kinetic modeling has been performed to investigate aromatic and polyaromatic hydrocarbon formation pathways in a rich, sooting, ethylene-oxygen-argon premixed flame. An atmospheric pressure, laminar flat flame operated at an equivalence ratio of 2.5 was used to acquire experimental data for model validation. Gas composition analysis was conducted by an on-line gas chromatograph/mass spectrometer (GC/MS) technique. Measurements were made in the flame and post-flame zone for a number of low molecular weight species, aliphatics, aromatics and polycyclic aromatic hydrocarbons (PAHs) ranging from two to five-aromatic fused rings. The modeling results show the key reaction sequences leading to aromatic and polycyclic aromatic hydrocarbon growth involve the combination of resonantly stabilized radicals. In particular, propargyl and 1-methylallenyl combination reactions lead to benzene and methyl substituted benzene formation, while polycyclic aromatics are formed from cyclopentadienyl radicals and fused rings that have a shared C{sub 5} side structure. Naphthalene production through the reaction step of cyclopentadienyl self-combination and phenanthrene formation from indenyl and cyclopentadienyl combination were shown to be important in the flame modeling study. The removal of phenyl by O{sub 2} leading to cyclopentadienyl formation is expected to play a pivotal role in the PAH or soot precursor growth process under fuel-rich oxidation conditions.

  2. Liquefaction of cellulosic wastes. 6: Oxygen compounds in pyrolytic oil and water fractions

    SciTech Connect (OSTI)

    Gharieb, H.K.; Faramawy, S.; El-Amrousi, F.A.; El-Sabagh, S.M. [Egyptian Petroleum Research Inst., Cairo (Egypt)

    1998-07-01T23:59:59.000Z

    Liquid hydrocarbon oil and water have been produced from the liquefaction of cellulosic matter present in municipal solid wastes. The produced pyrolytic oil and water fraction seemed to be contaminated with considerable amounts of oxygen compounds as compared with fuels derived from a petroleum origin. The oxygen compounds included organic acids (fatty and naphthenic acids), phenols, and carbonyl compounds. These classes of oxygen compounds were extracted selectively from the pyrolytic oils and water using chemical extraction methods. Methyl esters of fatty acids and 2,4-dinitrophenylhydrazones of carbonyl compounds were identified by gas chromatography and thin layer chromatography, respectively. It was suggested that the identified oxygen compounds could be produced from the pyrolysis of volatiles (e.g., levoglucosane, which is the primary product of cellulose depolymerization) via different mechanistic pathways.

  3. HYDROGEN USAGE AND STORAGE

    E-Print Network [OSTI]

    It is thought that it will be useful to inform society and people who are interested in hydrogen energy. The study below has been prepared due to this aim can be accepted as an article to exchange of information between people working on this subject. This study has been presented to reader to be utilized as a “technical note”. Main Energy sources coal, petroleum and natural gas are the fossil fuels we use today. They are going to be exhausted since careless usage in last decades through out the world, and human being is going to face the lack of energy sources in the near future. On the other hand as the fossil fuels pollute the environment makes the hydrogen important for an alternative energy source against to the fossil fuels. Due to the slow progress in hydrogen’s production, storage and converting into electrical energy experience, extensive usage of Hydrogen can not find chance for applications in wide technological practices. Hydrogen storage stands on an important point in the development of Hydrogen energy Technologies. Hydrogen is volumetrically low energy concentration fuel. Hydrogen energy, to meet the energy quantity necessary for the nowadays technologies and to be accepted economically and physically against fossil fuels, Hydrogen storage technologies have to be developed in this manner. Today the most common method in hydrogen storage may be accepted as the high pressurized composite tanks. Hydrogen is stored as liquid or gaseous phases. Liquid hydrogen phase can be stored by using composite tanks under very high pressure conditions. High technology composite material products which are durable to high pressures, which should not be affected by hydrogen embrittlement and chemical conditions.[1

  4. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1992-01-01T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  5. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  6. Composition of paraffinic and naphthenic hydrocarbons in petroleum asphalts

    SciTech Connect (OSTI)

    Botvin'eva, A.M.; Dubkova, R.V.; Shkredova, N.A.

    1982-11-01T23:59:59.000Z

    Uses a combination of chromatographic, chemical, and spectroscopic methods to determine the composition of the paraffinic and naphthenic hydrocarbons recovered from asphalts. Monitors the completeness of separation of the hydrocarbons from the aromatics on the basis of UV spectra. Finds that in the mixture of adduct-forming hydrocarbons, along with the n-paraffins there were admixtures of isoparaffins and longchain alkylnaphthenes. Concludes that a comparison of the structural-group composition of the asphalt fractions from the different crudes shows that there are only slight differences in the structure of the paraffinic/naphthenic hydrocarbons present in these asphalts, particularly with regard to those hydrocarbons that do not react with urea.

  7. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-08-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

  8. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

  9. Engineering Bacteria for Efficient Fuel Production: Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Free Fatty Acids

    SciTech Connect (OSTI)

    None

    2010-07-12T23:59:59.000Z

    Electrofuels Project: OPX Biotechnologies is engineering a microorganism currently used in industrial biotechnology to directly produce a liquid fuel from hydrogen and carbon dioxide (CO2). The microorganism has the natural ability to use hydrogen and CO2 for growth. OPX Biotechnologies is modifying the microorganism to divert energy and carbon away from growth and towards the production of liquid fuels in larger, commercially viable quantities. The microbial system will produce a fuel precursor that can be chemically upgraded to various hydrocarbon fuels.

  10. Oxygen abundances in the most oxygen-rich spiral galaxies

    E-Print Network [OSTI]

    L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

    2006-01-06T23:59:59.000Z

    Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

  11. Oxygen Concentration Microgradients for Cell Culture

    E-Print Network [OSTI]

    Park, Jaehyun

    2010-01-01T23:59:59.000Z

    The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

  12. System Evaluation and Economic Analysis of a HTGR Powered High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego; Anastasia A. Gandrik

    2010-10-01T23:59:59.000Z

    A design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The power conversion unit will be a Rankine steam cycle with a power conversion efficiency of 40%. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 40.4% at a hydrogen production rate of 1.75 kg/s and an oxygen production rate of 13.8 kg/s. An economic analysis of this plant was performed with realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.67/kg of hydrogen assuming an internal rate of return, IRR, of 12% and a debt to equity ratio of 80%/20%. A second analysis shows that if the power cycle efficiency increases to 44.4%, the hydrogen production efficiency increases to 42.8% and the hydrogen and oxygen production rates are 1.85 kg/s and 14.6 kg/s respectively. At the higher power cycle efficiency and an IRR of 12% the cost of hydrogen production is $3.50/kg.

  13. Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum

    SciTech Connect (OSTI)

    Cho, P.; Law, C.K.

    1986-11-01T23:59:59.000Z

    Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

  14. Oxygen Transport Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay

    2008-08-30T23:59:59.000Z

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

  15. Hydrogen Energy Stations: Poly-Production of Electricity, Hydrogen, and Thermal Energy

    E-Print Network [OSTI]

    Lipman, Timothy; Brooks, Cameron

    2006-01-01T23:59:59.000Z

    psi) High-pressure hydrogen compressor Compressed hydrogen2005 High-pressure hydrogen compressor Compressed hydrogenthe hydrogen, a hydrogen compressor, high-pressure tank

  16. Ultrafine hydrogen storage powders

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Ellis, Timothy W. (Doylestown, PA); Pecharsky, Vitalij K. (Ames, IA); Ting, Jason (Ames, IA); Terpstra, Robert (Ames, IA); Bowman, Robert C. (La Mesa, CA); Witham, Charles K. (Pasadena, CA); Fultz, Brent T. (Pasadena, CA); Bugga, Ratnakumar V. (Arcadia, CA)

    2000-06-13T23:59:59.000Z

    A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

  17. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  18. ORGANIC GEOCHEMISTRY, DEPOSITIONAL ENVIRONMENT AND HYDROCARBON POTENTIAL OF THE TERTIARY OIL SHALE DEPOSITS IN NW ANATOLIA, TURKEY

    E-Print Network [OSTI]

    R. Kara Gülbay; S. Korkmaz

    In this study, organic geochemical characteristics and depositional environ-ment of the Tertiary-aged oil shale deposits in Northwest Anatolia have been examined. Oil shales in all the studied areas are typically characterized by high hydrogen index and low oxygen index values. Beypazar?

  19. Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors

    SciTech Connect (OSTI)

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-10-14T23:59:59.000Z

    A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

  20. Natural gas conversion to higher hydrocarbons using plasma interactions with surfaces. Final report

    SciTech Connect (OSTI)

    Sackinger, W.M.; Kamath, V.A.; Morgan, B.L.; Airey, R.W.

    1993-12-01T23:59:59.000Z

    Experiments are reported in which a methane plasma is created, and the methyl ions and hydrogen ions are accelerated within a microchannel array so that they interact with neutral methane molecules on the inside surfaces of the microchannels. No catalysts are used, and the device operates at room temperature. Impact energies of the ions are in the range of 10 eV to greater than 100 eV, and the energy delivered in the interaction at the surfaces causes the production of larger hydrocarbon molecules, such as C{sub 2}H{sub 2}, C{sub 2}H{sub 4}, and C{sub 2}H{sub 6}, along with C{sub 3}, C{sub 4}, C{sub 5}m C{sub 6}, C{sub 7}m and C{sub 8} molecules. There is a decreasing percentage of larger molecules produced, in comparison with the C{sub 2} and C{sub 3} types. Conversion effectiveness is greater at higher pressure, due to the increased ionic activity. The yield of the higher hydrocarbons depends upon the external voltage used, and voltage can be used as a control parameter to adjust the output mixture proportions. A conversion energy of 2.59 kilowatt hours/killogram of output has been demonstrated, and a reduction of this by a factor of 10 is possible using known techniques. In batch experiments, the selectivity for C{sub 2} has varied from 47% to 88%, and selectivity for C{sub 6} has ranged from 0% to 12.8%. Other hydrocarbon selectivities also span a wide and useful range. The estimated costs for hydrocarbons produced with this technology are in the range of $200 per tonne, in production quantities, depending upon natural gas costs. Pilot production experiments are recommended to make these estimates more precise, and to address strategies for scaling the technology up to production levels. Applications are discussed.

  1. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  2. Oxygen detoxification in micro-metazoans of the sulfide-system

    E-Print Network [OSTI]

    Morrill, Audrey Carr

    1986-01-01T23:59:59.000Z

    )& neither need or possess the enzymes catalase and superoxide dismutase (SOD), which are neccessary to detoxify hydrogen peroxide& H 0 , and superoxide radicals, 0 , respectively. Second& if meioi'auna do contain catalase and superoxide dismutase, could.... It is possible that superoxi. de radioals and The style and format of this thesis follows that of &) ~~ hydrogen peroxide are formed in the process of sulfur detoxificationi since these are unwanted byproducts of any reaction involving molecular oxygen...

  3. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    ; Atmospheric pollution; POVA (POllution des Vallées Alpines); Alpine valleys 1. Introduction and objectives of atmospheric pollution in these two French Alpines valleys before and after the reopening of the TMB to heavy-12Feb2014 Author manuscript, published in "Atmospheric Environment 42, 173 (2008) 43 à 54" DOI : 10

  4. Polycyclic Aromatic Hydrocarbons (PAHs), nitrated PAHs and oxygenated PAHs in ambient air of the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    lower. 9- Fluorenone and 9,10-anthraquinone were the most abundant OPAHs, accounting for about 60[a]anthracene-7,12-dione seems to be diesel vehicles. Finally, 9,10-anthraquinone presents a double origin: primary diesel emission and photochemical processes. Formation of 9,10- anthraquinone from anthracene

  5. Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang; Vukmirovic, Miomir

    2012-11-13T23:59:59.000Z

    The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen.

  6. Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Zhang, Junliang (Stony Brook, NY); Vukmirovic, Miomir (Port Jefferson Station, NY)

    2011-11-22T23:59:59.000Z

    The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen.

  7. BP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop

    E-Print Network [OSTI]

    BP and Hydrogen Pipelines DOE Hydrogen Pipeline Working Group Workshop August 30-31, 2005 Gary P · UK partnership opened the first hydrogen demonstration refueling station · Two hydrogen pipelines l · " i i l i 2 i i ll i i l pl ifi i · 8" ly idl i i l s Hydrogen Pipelines Two nes, on y a brand

  8. Hawaii hydrogen power park Hawaii Hydrogen Power Park

    E-Print Network [OSTI]

    . (Barrier R ­ Cost) Generate public interest & support. (Barrier S­Siting) #12;Hawaii hydrogen power park H Electrolyzer ValveManifold Water High Pressure H2 Storage Fuel Cell AC Power H2 Compressor Hydrogen Supply O2Hawaii hydrogen power park H Hawaii Hydrogen Power Park 2003 Hydrogen & Fuel Cells Merit Review

  9. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham

    2006-12-31T23:59:59.000Z

    Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

  10. High Pressure Hydrogen Materials Compatibility of Piezoelectric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressure Hydrogen Materials Compatibility of Piezoelectric Films. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films. Abstract: Abstract: Hydrogen is being...

  11. HYDROCARBON-DEGRADING BACTERIA AND SURFACTANT ACTIVITY

    SciTech Connect (OSTI)

    Brigmon, R; Topher Berry, T; Grazyna A. Plaza, G; jacek Wypych, j

    2006-08-15T23:59:59.000Z

    Fate of benzene ethylbenzene toluene xylenes (BTEX) compounds through biodegradation was investigated using two different bacteria, Ralstonia picketti (BP-20) and Alcaligenes piechaudii (CZOR L-1B). These bacteria were isolated from extremely polluted petroleum hydrocarbon contaminated soils. PCR and Fatty Acid Methyl Ester (FAME) were used to identify the isolates. Biodegradation was measured using each organism individually and in combination. Both bacteria were shown to degrade each of the BTEX compounds. Alcaligenes piechaudii biodegraded BTEXs more efficiently while mixed with BP-20 and individually. Biosurfactant production was observed by culture techniques. In addition 3-hydroxy fatty acids, important in biosurfactant production, was observed by FAME analysis. In the all experiments toluene and m+p- xylenes were better growth substrates for both bacteria than the other BTEX compounds. In addition, the test results indicate that the bacteria could contribute to bioremediation of aromatic hydrocarbons (BTEX) pollution increase biodegradation through the action by biosurfactants.

  12. Behavioral toxicology, risk assessment, and chlorinated hydrocarbons

    SciTech Connect (OSTI)

    Evangelista de Duffard, A.M.; Duffard, R. [Laboratorio de Toxicologia Experimental, Santa Fe (Argentina)

    1996-04-01T23:59:59.000Z

    Behavioral end points are being used with greater frequency in neurotoxicology to detect and characterize the adverse effects of chemicals on the nervous system. Behavioral measures are particularly important for neurotoxicity risk assessment since many known neurotoxicants do not result in neuropathology. The chlorinated hydrocarbon class consists of a wide variety of chemicals including polychlorinated biphenyls, clioquinol, trichloroethylene, hexachlorophene, organochlorine insecticides (DDT, dicofol, chlordecone, dieldrin, and lindane), and phenoxyherbicides. Each of these chemicals has effects on motor, sensory, or cognitive function that are detectable using functional measures such as behavior. Furthermore, there is evidence that if exposure occurs during critical periods of development, many of the chlorinated hydrocarbons are developmental neurotoxicants. Developmental neurotoxicity is frequently expressed as alterations in motor function or cognitive abilities or charges in the ontogeny of sensorimotor reflexes. Neurotoxicity risk assessment should include assessments of the full range of possible neurotoxicological effects, including both structural and functional indicators of neurotoxicity. 121 refs., 1 tab.

  13. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1983-06-21T23:59:59.000Z

    A method and apparatus for synthesizing a mixture of hydrocarbons having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further includes Na present as a substitutional cation in an amount of about 5 to 10 atom %. At a temperature of about 340 to 360/sup 0/C, and at pressures of about 20 to 50 atm, CH/sub 3/OH is produced in an amount of about 90 wt % of the total hydrocarbon mixture, and comprised 1 mole % of the effluent gas.

  14. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01T23:59:59.000Z

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  15. Hydrogen powered bus

    ScienceCinema (OSTI)

    None

    2013-11-22T23:59:59.000Z

    Take a ride on a new type of bus, fueled by hydrogen. These hydrogen taxis are part of a Department of Energy-funded deployment of hydrogen powered vehicles and fueling infrastructure at nine federal facilities across the country to demonstrate this market-ready advanced technology. Produced and leased by Ford Motor Company , they consist of one 12- passenger bus and one nine-passenger bus. More information at: http://go.usa.gov/Tgr

  16. Hydrogen energy systems studies

    SciTech Connect (OSTI)

    Ogden, J.M.; Steinbugler, M.; Dennis, E. [Princeton Univ., NJ (United States)] [and others

    1995-09-01T23:59:59.000Z

    For several years, researchers at Princeton University`s Center for Energy and Environmental Studies have carried out technical and economic assessments of hydrogen energy systems. Initially, we focussed on the long term potential of renewable hydrogen. More recently we have explored how a transition to renewable hydrogen might begin. The goal of our current work is to identify promising strategies leading from near term hydrogen markets and technologies toward eventual large scale use of renewable hydrogen as an energy carrier. Our approach has been to assess the entire hydrogen energy system from production through end-use considering technical performance, economics, infrastructure and environmental issues. This work is part of the systems analysis activity of the DOE Hydrogen Program. In this paper we first summarize the results of three tasks which were completed during the past year under NREL Contract No. XR-11265-2: in Task 1, we carried out assessments of near term options for supplying hydrogen transportation fuel from natural gas; in Task 2, we assessed the feasibility of using the existing natural gas system with hydrogen and hydrogen blends; and in Task 3, we carried out a study of PEM fuel cells for residential cogeneration applications, a market which might have less stringent cost requirements than transportation. We then give preliminary results for two other tasks which are ongoing under DOE Contract No. DE-FG04-94AL85803: In Task 1 we are assessing the technical options for low cost small scale production of hydrogen from natural gas, considering (a) steam reforming, (b) partial oxidation and (c) autothermal reforming, and in Task 2 we are assessing potential markets for hydrogen in Southern California.

  17. Production of synthetic hydrocarbon fuels from peat

    SciTech Connect (OSTI)

    Bodle, W.W.; Punwani, D.; Weil, S.A.

    1982-06-22T23:59:59.000Z

    A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.

  18. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    electric cooperatives* to offer net metering to customers who generate electricity using solar energy, wind energy, hydropower, hydrogen, biomass, landfill gas, geothermal energy,...

  19. Renewable Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Remick, R. J.

    2009-11-16T23:59:59.000Z

    Presentation about the United State's dependence on oil, how energy solutions are challenging, and why hydrogen should be considered as a long-term alternative for transportation fuel.

  20. Hydrogen Industrial Trucks

    Broader source: Energy.gov [DOE]

    Slides from the U.S. Department of Energy Hydrogen Component and System Qualification Workshop held November 4, 2010 in Livermore, CA.

  1. Hydrogen purification system

    DOE Patents [OSTI]

    Golben, Peter Mark

    2010-06-15T23:59:59.000Z

    The present invention provides a system to purify hydrogen involving the use of a hydride compressor and catalytic converters combined with a process controller.

  2. Hydrogen Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.

  3. Department of Energy - Hydrogen

    Broader source: Energy.gov (indexed) [DOE]

    Goes to.... Lighting Up Operations with Hydrogen and Fuel Cell Technology http:energy.goveerearticlesand-oscar-sustainable-mobile-lighting-goes-lighting-operations-hydro...

  4. Sustainable hydrogen production

    SciTech Connect (OSTI)

    Block, D.L.; Linkous, C.; Muradov, N.

    1996-01-01T23:59:59.000Z

    This report describes the Sustainable Hydrogen Production research conducted at the Florida Solar Energy Center (FSEC) for the past year. The report presents the work done on the following four tasks: Task 1--production of hydrogen by photovoltaic-powered electrolysis; Task 2--solar photocatalytic hydrogen production from water using a dual-bed photosystem; Task 3--development of solid electrolytes for water electrolysis at intermediate temperatures; and Task 4--production of hydrogen by thermocatalytic cracking of natural gas. For each task, this report presents a summary, introduction/description of project, and results.

  5. Hydrogen permeation resistant barrier

    DOE Patents [OSTI]

    McGuire, Joseph C. (Richland, WA); Brehm, William F. (Richland, WA)

    1982-01-01T23:59:59.000Z

    A hydrogen permeation resistant barrier is formed by diffusing aluminum into an iron or nickel alloy and forming an intermetallic aluminide layer.

  6. Thin film hydrogen sensor

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); Hoffheins, Barbara S. (Knoxville, TN); Fleming, Pamela H. (Oak Ridge, TN)

    1994-01-01T23:59:59.000Z

    A hydrogen sensor element comprises an essentially inert, electrically-insulating substrate having a thin-film metallization deposited thereon which forms at least two resistors on the substrate. The metallization comprises a layer of Pd or a Pd alloy for sensing hydrogen and an underlying intermediate metal layer for providing enhanced adhesion of the metallization to the substrate. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors, and at least one of the resistors is left uncovered. The difference in electrical resistances of the covered resistor and the uncovered resistor is related to hydrogen concentration in a gas to which the sensor element is exposed.

  7. Hydrogen production by water dissociation using ceramic membranes. Annual report for FY 2007.

    SciTech Connect (OSTI)

    Balachandran, U.; Chen, L.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Park, C. Y.; Picciolo, J. J.; Song, S. J.; Energy Systems

    2008-03-04T23:59:59.000Z

    The objective of this project is to develop dense ceramic membranes that, without using an external power supply or circuitry, can produce hydrogen via coal/coal gas-assisted water dissociation. This project grew out of an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions [1]. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen to be produced by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting [1, 2]. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen by means of OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

  8. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

  9. Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

  10. Hydrogen Delivery - Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Delivery Hydrogen Delivery - Basics Hydrogen Delivery - Basics Photo of light-duty vehicle at hydrogen refueling station. Infrastructure is required to move hydrogen from the...

  11. Enhancing hydrogen spillover and storage

    DOE Patents [OSTI]

    Yang, Ralph T. (Ann Arbor, MI); Li, Yingwel (Ann Arbor, MI); Lachawiec, Jr., Anthony J. (Ann Arbor, MI)

    2011-05-31T23:59:59.000Z

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  12. Enhancing hydrogen spillover and storage

    SciTech Connect (OSTI)

    Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

    2013-02-12T23:59:59.000Z

    Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

  13. Electrochemical hydrogen Storage Systems

    SciTech Connect (OSTI)

    Dr. Digby Macdonald

    2010-08-09T23:59:59.000Z

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

  14. Composite oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05T23:59:59.000Z

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  15. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2000-10-01T23:59:59.000Z

    This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  16. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

    1980-08-12T23:59:59.000Z

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  17. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas

    2005-09-30T23:59:59.000Z

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

  18. Theoretical and experimental investigations into the particular features of the process of converting coal gas hydrocarbons on incandescent coke

    SciTech Connect (OSTI)

    Zubilin, I.G.; Umanskii, V.E.

    1984-01-01T23:59:59.000Z

    The prospects of the use of reducing gases in ferrous metallurgy and the possibilities for using them as a basis for coke production have been presented by the authors of the present article in the past. In the present report, the authors present certain results of theoretical and experimental investigations into the process of converting coal gas hydrocarbons on incandescent coke. The modification of the present-day method of thermodynamically calculating stable compositions of coking products, which was developed by the authors, has made it possible to apply it to specific chemical systems and process conditions not met with before, such as the conversion of hydrocarbons in mixtures of actual industrial gases (coal gas and blast furnace gas) in the presence of carbon and considerable amounts of hydrogen.

  19. Membrane for hydrogen recovery from streams containing hydrogen sulfide

    DOE Patents [OSTI]

    Agarwal, Pradeep K.

    2007-01-16T23:59:59.000Z

    A membrane for hydrogen recovery from streams containing hydrogen sulfide is provided. The membrane comprises a substrate, a hydrogen permeable first membrane layer deposited on the substrate, and a second membrane layer deposited on the first layer. The second layer contains sulfides of transition metals and positioned on the on a feed side of the hydrogen sulfide stream. The present invention also includes a method for the direct decomposition of hydrogen sulfide to hydrogen and sulfur.

  20. Integrated technical and economic assessments of transport and storage of hydrogen

    SciTech Connect (OSTI)

    Berry, G.D. [Lawrence Livermore National Lab., CA (United States)]|[Illinois Univ., Urbana, IL (United States); Smith, J.R. [Lawrence Livermore National Lab., CA (United States)

    1994-04-01T23:59:59.000Z

    Transportation will be a major market for hydrogen because of its great size and the value of energy at the wheels of a vehicle in comparison to its heating value. Hydrogen also offers important potential efficiency gains over hydrocarbon fuels. However, hydrogen end-use technologies will not develop without a reliable hydrogen supply infrastructure. By the same token, reliable infrastructures will not develop without end-use demand. Our task is to analyze the costs of various infrastructure options for providing hydrogen, as the number of vehicles serviced increased from very small numbers initially, to moderate numbers in the mid-term and to determine if a smooth transition may be possible. We will determine viable market sizes for transport and storage options by examining the technologies and the capital and operating costs of these systems, as well as related issues such as safety, construction time, etc. The product of our work will be data based scenarios of the likely transitions to hydrogen fuel, beginning with small and progressing to larger numbers of vehicles. We are working closely with the suppliers of relevant technologies to (1) determine realistic component costs, and (2) to assure availability of our analyses to business. Preliminary analyses indicate that the cost of transport and storage is as important as production cost in determining the cost of hydrogen fuel to the consumer, and that home electrolysis and centrally processed liquid hydrogen may provide hydrogen in the initial stages.

  1. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-12-30T23:59:59.000Z

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100 C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  2. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-04-29T23:59:59.000Z

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  3. Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes &

    E-Print Network [OSTI]

    for hydrogen refueling and storage, by 2006; · Complete and adopt the revised NFPA 55 standard for hydrogen storage of hydrogen, by 2008; · Complete U.S. adoption of a Global Technical Regulation (GTR) for hydrogen, storage, and use of hydrogen incorporate project safety requirements into the procurements, by 2005

  4. Oxidation of carbon monoxide and hydrocarbons on platinum and palladium catalysts in the presence of sulfur dioxide

    SciTech Connect (OSTI)

    Panchishnyi, V.I.; Bondareva, N.K.; Sklyarov, A.V.; Rozanov, V.V.; Chadina, G.P.

    1988-11-10T23:59:59.000Z

    The authors report on a study of the effect of sulfur dioxide on the activity of platinum and palladium catalysts with respect to oxidation of the principal toxic components in the exhaust gases of internal combustion engines: carbon monoxide and hydrocarbons (propylene (C/sub 3/H/sub 6/) and propane (C/sub 3/H/sub 8/)). The experiments were carried out in a flow system equipped with Beckman infrared analyzers to monitor the concentrations of CO and hydrocarbons and of sulfur dioxide. A series of thermal desorption experiments was carried out in a low-pressure flow system with mass spectrometric analysis of the gas phase. The results indicate that the low-temperature adsorption of sulfur dioxide on platinum (and also palladium) catalysts inhibits the oxidation of carbon monoxide and propylene. The poisoning effect of O/sub 2/ is due to blockage of the platinum centers for adsorption of the oxidizable compounds and oxygen.

  5. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01T23:59:59.000Z

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  6. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, Barbara S. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1995-01-01T23:59:59.000Z

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

  7. August 2006 Hydrogen Program

    E-Print Network [OSTI]

    after the date of enactment of this Act, the Secretary shall submit to Congress a report evaluating's primary transportation fuel from petroleum, which is increasingly imported, to hydrogen, which can the energy, environmental and economic benefits of a hydrogen economy. The goals and milestones

  8. Hydrogen Delivery- Current Technology

    Broader source: Energy.gov [DOE]

    Hydrogen is transported from the point of production to the point of use via pipeline, over the road in cryogenic liquid trucks or gaseous tube trailers, or by rail or barge. Read on to learn more about current hydrogen delivery and storage technologies.

  9. Metal-support interactions: their effects upon adsorption, electronic, and activity/selectivity properties of cobalt in CO hydrogenation. Final progress report, April 1, 1982-September 30, 1983

    SciTech Connect (OSTI)

    Bartholomew, C.H.

    1983-10-01T23:59:59.000Z

    Measurements of dispersion, extent of reduction, H/sub 2/ and CO adsorption stoichiometries, CO hydrogenation activity and selectivity, and H/sub 2/ adsorption/desorption kinetics were conducted on 18 catalysts. Hydrogen adsorption was found to be highly activated and quite reversible; the adsorption stoichiometry corresponds to one hydrogen atom per surface cobalt atom. CO adsorption stoichiometries on the other hand vary considerably with support, dispersion, and preparation. Binding energies and adsorption states for H/sub 2/ on cobalt vary with support. Activity and selectivity in CO hydrogenation on cobalt vary with support, dispersion, and preparation. The specific activity and selectivity for heavier hydrocarbons decrease with increasing dispersion.

  10. Removing oxygen from a solvent extractant in an uranium recovery process

    DOE Patents [OSTI]

    Hurst, Fred J. (Oak Ridge, TN); Brown, Gilbert M. (Knoxville, TN); Posey, Franz A. (Concord, TN)

    1984-01-01T23:59:59.000Z

    An improvement in effecting uranium recovery from phosphoric acid solutions is provided by sparging dissolved oxygen contained in solutions and solvents used in a reductive stripping stage with an effective volume of a nonoxidizing gas before the introduction of the solutions and solvents into the stage. Effective volumes of nonoxidizing gases, selected from the group consisting of argon, carbon dioxide, carbon monoxide, helium, hydrogen, nitrogen, sulfur dioxide, and mixtures thereof, displace oxygen from the solutions and solvents thereby reduce deleterious effects of oxygen such as excessive consumption of elemental or ferrous and accumulation of complex iron phosphates or cruds.

  11. Method for oxygen reduction in a uranium-recovery process. [US DOE patent application

    DOE Patents [OSTI]

    Hurst, F.J.; Brown, G.M.; Posey, F.A.

    1981-11-04T23:59:59.000Z

    An improvement in effecting uranium recovery from phosphoric acid solutions is provided by sparging dissolved oxygen contained in solutions and solvents used in a reductive stripping stage with an effective volume of a nonoxidizing gas before the introduction of the solutions and solvents into the stage. Effective volumes of nonoxidizing gases, selected from the group consisting of argon, carbon dioxide, carbon monoxide, helium, hydrogen, nitrogen, sulfur dioxide, and mixtures thereof, displace oxygen from the solutions and solvents thereby reduce deleterious effects of oxygen such as excessive consumption of elemental or ferrous iron and accumulation of complex iron phosphates or cruds.

  12. Renewable Resources for Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A. A.

    2010-05-03T23:59:59.000Z

    This presentation provides an overview of renewable resources for hydrogen. It was presented at the National Hydrogen Association Hydrogen Conference & Expo in Long Beach, CA, May 3-6, 2010.

  13. Hydrogen in semiconductors and insulators

    E-Print Network [OSTI]

    Van de Walle, Chris G.

    2007-01-01T23:59:59.000Z

    type can be applied to hydrogen storage materials. Keywords:can be applied to hydrogen storage materials. Manuscript O-of the formalism to hydrogen storage materials. A partial

  14. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    in the cost of hydrogen production, distribution, and use.accelerate R&D of zero-emission hydrogen production methods.Renewable hydrogen production is a key area for focused

  15. Hydrogen from Coal Edward Schmetz

    E-Print Network [OSTI]

    Turbines Carbon Capture & Sequestration Carbon Capture & Sequestration The Hydrogen from Coal Program Cells, Turbines, and Carbon Capture & Sequestration #12;Production Goal for Hydrogen from Coal Central Separation System PSA Membrane Membrane Carbon Sequestration Yes (87%) Yes (100%) Yes (100%) Hydrogen

  16. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    It appears to us that hydrogen is a highly promising option06—16 The Bumpy Road to Hydrogen Daniel Sperling Joan OgdenThe Bumpy Road to Hydrogen 1 Daniel Sperling and Joan Ogden

  17. High-Performance Palladium Based Membrane for Hydrogen Separation and Purification

    SciTech Connect (OSTI)

    Scott Hopkins

    2012-01-31T23:59:59.000Z

    The mission of the DOE's Fuel Cell Technologies'�Hydrogen Fuels R&D effort is to research, develop, and validate technologies for producing, storing, and delivering hydrogen in an efficient, clean, safe, reliable, and affordable manner. A key program technical milestone for hydrogen technology readiness is to produce hydrogen from diverse, domestic resources at $2.00-$3.00 per gallon of gasoline equivalent (gge) delivered, untaxed. Low-cost, high-temperature hydrogen separation membranes represent a key enabling technology for small-scale distributed hydrogen production units. Availability of such membranes with high selectivity and high permeability for hydrogen will allow their integration with hydrocarbon reforming and water gas shift reactions, potentially reducing the cost of hydrogen produced. Pd-metal-based dense membranes are known for their excellent hydrogen selectivity and permeability characteristics, however, utilization of these membranes has so far been limited to small scale niche markets for hydrogen purification primarily due to the relatively high cost of Pd-alloy tubes compared to pressure swing adsorption (PSA) units. This project was aimed at development of thin-film Pd-alloy membranes deposited on Pall Corporation's DOE-based AccuSep® porous metal tube substrates to form a composite hydrogen separation membrane for these applications. Pall's composite membrane development addressed the typical limitations of composite structures by developing robust membranes capable of withstanding thermal and mechanical stresses resulting from high temperature (400C), high pressure (400 psi steam methane reformer and 1000 psi coal) operations and thermal cycling involved in conventional hydrogen production. In addition, the Pd-alloy membrane composition was optimized to be able to offer the most stability in the typical synthesis gas environments produced by reforming of natural gas and bio-derived liquid fuels (BILI) validating the technical effectiveness and economic feasibility of the technology demonstrated. Results from this research added technology and product design information that offers the potential to significantly advance the commercial viability of hydrogen production.

  18. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

  19. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

    2011-03-22T23:59:59.000Z

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  20. Hydrogen Fuel Quality

    SciTech Connect (OSTI)

    Rockward, Tommy [Los Alamos National Laboratory

    2012-07-16T23:59:59.000Z

    For the past 6 years, open discussions and/or meetings have been held and are still on-going with OEM, Hydrogen Suppliers, other test facilities from the North America Team and International collaborators regarding experimental results, fuel clean-up cost, modeling, and analytical techniques to help determine levels of constituents for the development of an international standard for hydrogen fuel quality (ISO TC197 WG-12). Significant progress has been made. The process for the fuel standard is entering final stages as a result of the technical accomplishments. The objectives are to: (1) Determine the allowable levels of hydrogen fuel contaminants in support of the development of science-based international standards for hydrogen fuel quality (ISO TC197 WG-12); and (2) Validate the ASTM test method for determining low levels of non-hydrogen constituents.