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Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline  

DOE Patents (OSTI)

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Baker, E.G.; Elliott, D.C.

1993-01-19T23:59:59.000Z

2

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline  

DOE Patents (OSTI)

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

1993-01-01T23:59:59.000Z

3

Method for removing chlorine compounds from hydrocarbon mixtures  

DOE Patents (OSTI)

A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

Janoski, Edward J. (Havertown, PA); Hollstein, Elmer J. (Wilmington, DE)

1985-12-31T23:59:59.000Z

4

Method for removing chlorine compounds from hydrocarbon mixtures  

DOE Patents (OSTI)

A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

Janoski, E.J.; Hollstein, E.J.

1984-09-29T23:59:59.000Z

5

Removal of basic nitrogen compounds from hydrocarbon liquids  

DOE Patents (OSTI)

A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

Givens, Edwin N. (Bethlehem, PA); Hoover, David S. (New Tripoli, PA)

1985-01-01T23:59:59.000Z

6

Biodegradation of volatile aromatic hydrocarbons by native soil and groundwater microorganisms: Microcosm studies  

SciTech Connect

The goal of this project was twofold: to develop and test strategies for enhancing the microbial degradation of hydrocarbon contaminants in subsurface soil and groundwater, and to understand why and under what conditions these strategies can be successful. The work deals primarily with what are generally considered the highest priority contaminants, from a toxicological point of view, in a typical hydrocarbon remediation site -- the aromatic fraction, including benzene and related compounds. The work involved the determination of the relative degradation rates of aromatic, as well as several nonaromatic constituents, in conjunction with an analysis of the effect of oxygen concentration and with an extensive microbiological characterization.

Rai, D.N.; Dasch, J.M.; Gibson, T.L.; Ang, C.C.; Abdul, A.S.

1994-05-01T23:59:59.000Z

7

: Plasma-Hydrocarbon conversion  

crude oil and hydrocarbon gases like natural gas, into lighter hydrocarbon materials (e.g. synthetic light oil).

8

Apparatus for hydrocarbon extraction  

DOE Patents (OSTI)

Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

Bohnert, George W.; Verhulst, Galen G.

2013-03-19T23:59:59.000Z

9

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents (OSTI)

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

1988-01-01T23:59:59.000Z

10

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents (OSTI)

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

11

The Reaction Specificity of Nanoparticles in Solution: Application to the Reaction of Nanoparticulate Iron and Iron-Bimetallic Compounds with Chlorinated Hydrocarbons and Oxyanions  

SciTech Connect

The prospect for better remediation technologies using nanoparticles of iron, iron oxides, and iron with catalytic metals (i.e., bimetallics) has potentially transformative implications for environmental management of DOE sites across the country. Of particular interest is the potential to avoid undesirable products from the degradation of chlorinated solvents by taking advantage of the potential selectivity of nanoparticles to produce environmentally benign products from CCl{sub 4}. Chlorinated solvents are the most frequently reported subsurface contaminants across the whole DOE complex, and carbon tetrachloride (CCl{sub 4}) is the chlorinated solvent that is of greatest concern at Hanford (U. S. Department Energy 2001). In evaluating technologies that might be used at the site, a critical concern will be that CCl{sub 4} reduction usually occurs predominantly by hydrogenolysis to chloroform (CHCl{sub 3}) and methylene chloride (CH{sub 2}Cl{sub 2}), both of which are nearly as problematic as CCl{sub 4} (National Research Council, 1978). Competing reaction pathways produce the more desirable products carbon monoxide (CO) and/or formate (HCOO{sup -}), and possibly CO{sub 2}, but the proportion of reaction that occurs by these pathways is highly variable. Iron-based metallic and oxide nanoparticles have been shown to have enhanced reactivity towards a variety of chemical species, including chlorinated hydrocarbons and reducible oxyanions. Possibly of greater importance is the ability of nanoparticles to select for specific reaction products, potentially facilitating the formation of more environmentally acceptable products. The purpose of this study is to develop a fundamental understanding of the mechanism responsible for the overall particle reactivity and reaction selectivity of reactive metal and oxide nanoparticles. To achieve this objective the project involves the synthesis (using solution and vacuum synthesis methods) and characterization of well-defined nanoparticles, measurements of particle reactivity in solution or vacuum environments, and theory and modeling efforts to rationalize particle structure and reactivity.

None

2005-06-01T23:59:59.000Z

12

Modern Records of Radiatively Important Halogenated Compounds...  

NLE Websites -- All DOE Office Websites (Extended Search)

at CDIAC sites: Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including three Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in...

13

Removing the Hydrocarbon from Hydrocarbon Flow ...  

Science Conference Proceedings (OSTI)

... gas and petroleum products. Therefore is important to have primary calibration standards with low uncertainty. NIST has several hydrocarbon liquid ...

2014-01-03T23:59:59.000Z

14

Bismaleimide compounds  

DOE Patents (OSTI)

Bismaleimides of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C1 or Br, or R.sub.1 and R.sub.2 together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R.sub.1 and R.sub.2 are not t-butyl or t-butoxy; X is O, S or Se; n is 1-3; and the alkylene bridging group, optionally, is substituted by 1-3 methyl groups or by fluorine, form polybismaleimide resins which have valuable physical properties. Uniquely, these compounds permit extended cure times, i.e., they remain fluid for a time sufficient to permit the formation of a homogeneous melt prior to curing.

Adams, Johnnie E. (Grandview, MO); Jamieson, Donald R. (Merriam, KS)

1986-01-14T23:59:59.000Z

15

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents (OSTI)

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

1999-05-25T23:59:59.000Z

16

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents (OSTI)

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

17

Method for producing hydrocarbon and alcohol mixtures. [Patent application  

DOE Patents (OSTI)

It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

Compere, A.L.; Googin, J.M.; Griffith, W.L.

1980-12-01T23:59:59.000Z

18

Aromatic hydrocarbons associated with brines from geopressured wells. Annual report, fiscal 1985  

DOE Green Energy (OSTI)

Samples of cryocondensates - materials condensed at - 78.5/sup 0/C were taken on a regular basis from the gas stream for the USDOE geopressured wells. Most of the data has been taken from the Gladys McCall well as it has flowed on a regular and almost continous basis. The cryocondensates, not the ''condensate'' from gas wells, are almost exclusively aromatic hydrocarbons, primarily benzene, toluene, ethylbenzene, and the xylenes, but contain over 95 compounds, characterized using gas chromatographic-mass spectroscopy. The solubility in water and brine of benezene, toluene, ethylbenzene and o-xylene, some of the components of the cryocondensate, as well as distribution coefficients between water or brine and a standard oil have been measured. 25 refs.

Keeley, D.F.; Meriwether, J.R.

1985-01-01T23:59:59.000Z

19

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

DOE Green Energy (OSTI)

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

20

New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Study Shows Solar Manufacturing Costs Not Driven Primarily by Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor September 5, 2013 - 12:00pm Addthis Production scale, not lower labor costs, drives China's current advantage in manufacturing photovoltaic (PV) solar energy systems, according to a new report released today by the Energy Department's National Renewable Energy Laboratory (NREL) and the Massachusetts Institute of Technology (MIT). Although the prevailing belief is that low labor costs and direct government subsidies for PV manufacturing in China account for that country's dominance in PV manufacturing, the NREL/MIT study shows that a majority of the region's competitive advantage comes from production scale-enabled, in part, through preferred access to capital (indirect

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

New Study Shows Solar Manufacturing Costs Not Driven Primarily by New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor September 5, 2013 - 12:00pm Addthis Production scale, not lower labor costs, drives China's current advantage in manufacturing photovoltaic (PV) solar energy systems, according to a new report released today by the Energy Department's National Renewable Energy Laboratory (NREL) and the Massachusetts Institute of Technology (MIT). Although the prevailing belief is that low labor costs and direct government subsidies for PV manufacturing in China account for that country's dominance in PV manufacturing, the NREL/MIT study shows that a majority of the region's competitive advantage comes from production scale-enabled, in part, through preferred access to capital (indirect

22

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

23

Plasma Processing Of Hydrocarbon  

SciTech Connect

The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

2007-05-01T23:59:59.000Z

24

Hydrocarbon adsorption system  

SciTech Connect

In a solid adsorbent hydrocarbon recovery system for processing natural gas, towers adapted for performing adsorbing, cooling, and regenerating functions are used. It is recommended that a regeneration gas be used of substantially uniform richness in hydrocarbons in the closed-cycle regeneration system. The natural gas stream is flowed through an adsorbent bed to remove liquid hydrocarbons. A portion of the stripped gas stream is flowed through a second adsorbent bed for cooling purposes. A heated, rich, regeneration gas is circulated through a closed-cycle regeneration system that includes a third adsorbent bed. This rich regeneration gas is combined with the stripped gas stream. These steps are repeated in a cyclic operation. (10 claims)

Humphries, C.L.

1966-11-29T23:59:59.000Z

25

Hydrocarbon/Total Combustibles Sensor  

the invention is an electrochemical hydrocarbon sensor that is more reliable and reproducible than any other hydrocarbon sensor on the market today. The patented method for producing the sensor ensures reproducibility and reduces the need for ...

26

Dispersant solutions for dispersing hydrocarbons  

DOE Patents (OSTI)

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, Richard L. (Clinton, TN)

1997-01-01T23:59:59.000Z

27

Catalysts for hydrocarbon conversion  

Science Conference Proceedings (OSTI)

Catalyst, particularly useful in catalytic reforming and for producing highly pure aromatic hydrocarbons, comprising an alumina carrier and containing, expressed in proportion of the weight of the alumina carrier: 005 to 1% of platinum 01 to 4% of gallium, indium or thallium 01 to 2% of tungsten, and 1 to 10% of halogen.

Le P. J.; Malmaison, R.; Marcilly, C.; Martino, G.; Miquel, J.

1980-08-12T23:59:59.000Z

28

Process for conversion of lignin to reformulated hydrocarbon gasoline  

DOE Patents (OSTI)

A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

1999-09-28T23:59:59.000Z

29

Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels  

SciTech Connect

Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

2013-01-01T23:59:59.000Z

30

IRRADIATION METHOD OF CONVERTING ORGANIC COMPOUNDS  

DOE Patents (OSTI)

A method is given for changing the distribution of organic compounds from that produced by the irradiation of bulk alkane hydrocarbons. This method consists of depositing an alkane hydrocarbon on the surface of a substrate material and irradiating with gamma radiation at a dose rate of more than 100,000 rads. The substrate material may be a metal, metal salts, metal oxides, or carbons having a surface area in excess of 1 m/sup 2//g. The hydrocarbons are deposited in layers of from 0.1 to 10 monolayers on the surfaces of these substrates and irradiated. The product yields are found to vary from those which result from the irradiation of bulk hydrocarbons in that there is an increase in the quantity of branched hydrocarbons.

Allen, A.O.; Caffrey, J.M. Jr.

1960-10-11T23:59:59.000Z

31

Hydrocarbon reclaimer system  

SciTech Connect

This patent describes a filtering process for filtering sludge from a finished product oil storage tank and thereby separating solids from oil and hydrocarbon. The process requires no added water, solvents or diluents. It comprises: pumping a volume sludge from a finished product oil storage tank to a mixing tank; mixing the sludge; sampling the sludge to determine solid content; adding filter aid comprising diatomaceous earth to the mixing tank; mixing the filter aid with the sludge in the mixing tank; enclosing and sealing a plurality of filter plates inside a horizontal plate filter; pressurizing the horizontal plate filter by operation of pump means; pumping the sludge from the mixing tank through the horizontal plate filter to filter out solids; recirculating the sludge from the horizontal plate filter back through the mixing tank; and pumping a purified hydrocarbon and water filtrate from the horizontal plate filter.

Uremovich, M.J.

1990-09-04T23:59:59.000Z

32

FROZEN HYDROCARBONS IN COMETS  

SciTech Connect

Recent investigations of the luminescence of frozen hydrocarbon particles of icy cometary halos have been carried out. The process of luminescence of organic icy particles in a short-wavelength solar radiation field is considered. A comparative analysis of observed and laboratory data leads to 72 luminescent emission lines in the spectrum of the comet 153P/Ikeya-Zhang. The concept of cometary relict matter is presented, and the creation of a database of unidentified cometary emission lines is proposed.

Simonia, Irakli, E-mail: irakli.simonia@jcu.edu.au [School of Graduate Studies, Ilia State University, 3/5 Cholokashvili Street, Tbilisi, 0162 (Georgia); Center for Astronomy, James Cook University, Townsville QLD 4811 (Australia)

2011-02-15T23:59:59.000Z

33

THERMOCHEMISTRY OF HYDROCARBON RADICALS  

DOE Green Energy (OSTI)

Gas phase negative ion chemistry methods are employed to determine enthalpies of formation of hydrocarbon radicals that are important in combustion processes and to investigate the dynamics of ion-molecule reactions. Using guided ion beam tandem mass spectrometry, we measure collisional threshold energies of endoergic proton transfer and hydrogen atom transfer reactions of hydrocarbon molecules with negative reagent ions. The measured reaction threshold energies for proton transfer yield the relative gas phase acidities. In an alternative methodology, competitive collision-induced dissociation of proton-bound ion-molecule complexes provides accurate gas phase acidities relative to a reference acid. Combined with the electron affinity of the R {center_dot} radical, the gas phase acidity yields the RH bond dissociation energy of the corresponding neutral molecule, or equivalently the enthalpy of formation of the R{center_dot} organic radical, using equation: D(R-H) = {Delta}{sub acid}H(RH) + EA(R) - IE(H). The threshold energy for hydrogen abstraction from a hydrocarbon molecule yields its hydrogen atom affinity relative to the reagent anion, providing the RH bond dissociation energy directly. Electronic structure calculations are used to evaluate the possibility of potential energy barriers or dynamical constrictions along the reaction path, and as input for RRKM and phase space theory calculations. In newer experiments, we have measured the product velocity distributions to obtain additional information on the energetics and dynamics of the reactions.

Kent M. Ervin, Principal Investigator

2004-08-17T23:59:59.000Z

34

RADIOLYSIS OF ORGANIC COMPOUNDS IN THE ADSORBED STATE  

DOE Patents (OSTI)

>A method of forming branch chained hydrocarbons by means of energetic penetrating radiation is described. A solid zeolite substrate is admixed with a cobalt ion and is irradiated with a hydrocarbon adsorbed therein. Upon irradiation with gamma rays, there is an increased yield of branched and lower molecular straight chain compounds. (AEC)

Sutherland, J.W.; Allen, A.O.

1961-10-01T23:59:59.000Z

35

Solubilization of petroleum hydrocarbons using biosurfactants  

E-Print Network (OSTI)

Low solubility of petroleum hydrocarbons in water is the major factor limiting the degradation rates of these compounds (Zhang and Miller, 1994). The fraction that is more soluble in the aqueous phase is degraded at higher rates, while less soluble or insoluble compounds have lower degradation rates due to limited bioavailability to the microbial community. A recent study in our lab found no significant degradation of weathered petroleum at a Texas petrochemical plant site. It was concluded that bioavailability of the crude oil to the microorganisms limited the degradation rates (Mills, 1994). Preliminary experiments at our laboratories have also indicated enhanced solubilities of petroleum hydrocarbons due to the effects of biosurfactants (Kanga et al., 1994). This research focused on biosurfactants because they have been shown to be as effective as chemical surfactants and, most importantly, they enhance biodegradation. Glycolipid biosurfactants are produced by Rhodococcus species HI 3-A to enhance substrate solubility and promote bioavailability for degradation. The work proceeded in two stages. The initial stage involved production and characterization of extracellular biosurfactants by HI 3-A when grown on minimal salts media with hexadecane as the carbon source. The second stage evaluated the performance of the biosurfactants in enhancing the aqueous solubility of weathered West Texas Crude. Initial results indicated production of the biosurfactants by Rhodococcus species H13-A during the stationary growth stage. Biosurfactants lowered the surface tension from 72 to-30 dynes/cm and interfacial tension to below 5 dynes/cm. The two-, three-, and four-ring aromatic compounds showed substantial increase in their aqueous phase concentrations in the presence of biosurfactants. The enhancement was more dramatic with the larger aromatics and also the highly substituted-compounds. Preliminary experiments on toxicity and biodegradation indicated higher levels of toxicity in the surfactant/aqueous mixtures due to increased PAH partitioning (Lambert, 1995), and increased degradation rates for the target PAH compounds.

Kanga, Shahrukh

1995-01-01T23:59:59.000Z

36

HYDROCARBON LIQUID FLOW CALIBRATION SERVICE ...  

Science Conference Proceedings (OSTI)

... and is the cross correlation coefficient ... a NIST Hydrocarbon Liquid Flow Calibration Facility ... FED2004-56790, 2004 Heat Transfer/Fluids Engineering ...

2012-05-21T23:59:59.000Z

37

Enhanced solubility of petroleum hydrocarbons using biosurfactants  

E-Print Network (OSTI)

This research investigation included two similarly-designed experiments. In the first, a biological surfactant produced by Rhodococcus strain H13-A and a commonly-used synthetic surfactant, Tween-80 (polyoxyethylene sorbitan monooleate), were compared for their effectiveness in enhancing the transport of polycyclic aromatic hydrocarbons from a complex organic phase into aqueous solution. In the batch-reactor experiment, each reactor contained a surfactant solution and West Texas Crude oil, while the control reactors contained distilled-deionized water and the crude oil. Using a temporal-monitoring scheme, the reactors were sacrificially sampled to determine the water-accommodated fraction (WAF). The phenanthrenes, fluorenes, pyrenes, and chrysenes showed significant increases in their aqueous-plus-micellar-phase concentrations in the presence of surfactants; the increase was greater for the biosurfactant compared to the synthetic surfactant. The enhancement in "solubility" was also more significant for the highly-substituted aromatics, when compared to their parent compounds. In the second study, the effects of four biosurfactants on the solubility of petroleum saturated hydrocarbons were compared. Rhodococcus species H13-A (glycolipid-producing), Pseudomonas aeruginosa ATCC 9027 (rhamnolipid-producing), Candida bombicola ATCC 22214 (sophorolipid-producing), and Bacillus subtilis ATCC 21332 (surfactin-producing) were compared to a control of distilled-deionized water. The experimental design was similar that of the first study. The Pseudomonas aeruginosa treatment significantly enhanced the solubility of the lower-weight, higher-weight and branched saturated hydrocarbons. The Rhodococcus treatment significantly enhanced the solubility of the low-molecular-weight compounds, but only moderately increased the solubilities of the other saturates. Neither the Candida nor the Bacillus solutions produced any negligible increase in solubility under these laboratory conditions.

Page, Cheryl Ann

1997-01-01T23:59:59.000Z

38

Process for the production of ethylene and other hydrocarbons from coal  

DOE Patents (OSTI)

A process for the production of economically significant amounts of ethyl and other hydrocarbon compounds, such as benzene, from coal is disclosed wherein coal is reacted with methane at a temperature in the approximate range of 500.degree. C. to 1100.degree. C. at a partial pressure less than about 200 psig for a period of less than 10 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

Steinberg, Meyer (Huntington Station, NY); Fallon, Peter (East Moriches, NY)

1986-01-01T23:59:59.000Z

39

Hydrodesulfurization catalysis by Chevrel phase compounds  

DOE Patents (OSTI)

A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M.sub.x Mo.sub.6 S.sub.8, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS.sub.2 catalysts. The most active catalysts were the "large" cation compounds (Ho, Pb, Sn), and the least active catalysts were the "small" cation compounds (Cu, Fe, Ni, Co.).

McCarty, Kevin F. (Livermore, CA); Schrader, Glenn L. (Ames, IA)

1985-12-24T23:59:59.000Z

40

Molecular catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids.  

Science Conference Proceedings (OSTI)

This report presents the results of research on the development of new catalytic pathways for the hydrogenation of multiring aromatic hydrocarbons and the hydrotreating of coal liquids at The University of Chicago under DOE Contract No. DE-AC22-91PC91056. The work, which is described in three parts, is primarily concerned with the research on the development of new catalytic systems for the hydrogenation of aromatic hydrocarbons and for the improvement of the quality of coal liquids by the addition of dihydrogen. Part A discusses the activation of dihydrogen by very basic molecular reagents to form adducts that can facilitate the reduction of multiring aromatic hydrocarbons. Part B examines the hydrotreating of coal liquids catalyzed by the same base-activated dihydrogen complexes. Part C concerns studies of molecular organometallic catalysts for the hydrogenation of monocyclic aromatic hydrocarbons under mild conditions.

Yang, Shiyong; Stock, L.M.

1996-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Chemical and Radiological Toxicity of Uranium and Its Compounds  

SciTech Connect

The concentration of uranyl nitrate required to deliver the radiation dose limit for soluble uranium compounds is larger than the toxicity-based concentration limits. Therefore, for soluble uranium compounds, health consequences of exposure are primarily due to their chemical toxicity. For insoluble compounds of uranium, health consequences (e.g., fibrosis and/or carcinogenesis of the lung) are primarily due to irradiation of pulmonary tissues from inhaled respirable particles.

Tansky, R.R.

2001-07-26T23:59:59.000Z

42

Method for producing hydrocarbon fuels and fuel gas from heavy polynuclear hydrocarbons by the use of molten metal halide catalysts  

DOE Patents (OSTI)

In a process for hydrocracking heavy polynuclear carbonaceous feedstocks to produce lighter hydrocarbon fuels by contacting the heavy feedstocks with hydrogen in the presence of a molten metal halide catalyst in a hydrocracking zone, thereafter separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide and thereafter regenerating the spent molten metal halide by incinerating the spent molten metal halide by combustion of carbon and sulfur compounds in the spent molten metal halide in an incineration zone, the improvement comprising: (a) contacting the heavy feedstocks and hydrogen in the presence of the molten metal halide in the hydrocracking zone at reaction conditions effective to convert from about 60 to about 90 weight percent of the feedstock to lighter hydrocarbon fuels; (b) separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide; (c) contacting the spent molten metal halide with oxygen in a liquid phase gasification zone at a temperature and pressure sufficient to vaporize from about 25 to about 75 weight percent of the spent metal halide, the oxygen being introduced in an amount sufficient to remove from about 60 to about 90 weight percent of the carbon contained in the spent molten metal halide to produce a fuel gas and regenerated metal halide; and (d) incinerating the spent molten metal halide by combusting carbon and sulfur compounds contained therein.

Gorin, Everett (San Rafael, CA)

1979-01-01T23:59:59.000Z

43

Hydrocarbons in the deep earth  

NLE Websites -- All DOE Office Websites (Extended Search)

composed of the elements hydrogen and carbon) are the main building block of crude oil and natural gas. Hydrocarbons contribute to the global carbon cycle (one of the most...

44

Hydrocarbon adsorption apparatus and process  

SciTech Connect

A method of recovering hydrocarbons from natural gas by the use of solid adsorbents consists of 3 steps. The main flow stream of natural gas is passed through a first and only bed of solid adsorbent so that at least a portion of the hydrocarbons present is adsorbed in the bed. A heated regeneration gas is next passed through a second bed of solid adsorbent so that at least a portion of the hydrocarbons is desorbed from the bed. The main flow of natural gas is passed through the second and only bed when in a heated condition after regeneration and the flow of heated regeneration gas is passed through the first bed. The hydrocarbons desorbed from the first and second beds from the regeneration gas are recovered while the previous 3 steps are repeated. (6 claims)

Humphries, C.L.

1966-12-06T23:59:59.000Z

45

Abstract --The paper introduces a concept for integration of substation IED data, primarily coming from digital protective  

E-Print Network (OSTI)

Abstract -- The paper introduces a concept for integration of substation IED data, primarily coming from digital protective relays (DPRs) and digital fault recorders (DFRs) . Modern substations similar to that of DFRs. In some recent substation designs there are cases where DFR function is replaced

Kezunovic, Mladen

46

Polybenzimidazole compounds  

SciTech Connect

A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2--, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

2010-08-10T23:59:59.000Z

47

Polybenzimidazole compounds  

DOE Patents (OSTI)

A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO--, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Jones, Michael G. (Chubbuck, ID); Wertsching, Alan K. (Idaho Falls, ID); Luther, Thomas A. (Idaho Falls, ID); Trowbridge, Tammy L. (Idaho Falls, ID)

2011-11-22T23:59:59.000Z

48

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network (OSTI)

Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene, indene, azulene, fluorene, and biphenyl substituted compounds. Also, lighter hydrocarbons, such as ethylene and isobutene were produced. The reaction was conducted at different operating temperatures and different molar feed composition. The results showed that the conversion of both reactants increased with increasing the operating temperature; for example a conversion of 95.1% was achieved for acetylene at 350°C and 98.6% at 412°C. In addition, the conversion of both reactants decreased with increasing the molar feed ratio of methane to acetylene. A conversion of 96.4% for acetylene was achieved at a molar feed ratio of 6 to 1 (methane to acetylene) and 80.9% at a molar feed ration of 20 to 1 (methane to acetylene). The reaction of methane and ethane over HZSM-5 catalyst also led to the production of high molecular weight hydrocarbons, mainly aromatics, and some lighter products such as propane, and ethylene. Also methane by itself showed the ability to react over HZSM-5 to produce a small amount of aromatics, and ethylene.

Alkhawaldeh, Ammar

2000-01-01T23:59:59.000Z

49

Cleanup of hydrocarbon conversion system  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of a substantially contaminant-free second hydrocarbon feed using a second reforming catalyst, in a catalytic-reforming system having equipment contaminated through contact with a contaminant-containing prior feed. It comprises: contacting the first hydrocarbon feed in the catalytic-reforming system at first reforming conditions with a first reforming catalyst until contaminant removal from the conversion system is substantially completed and the system is contaminant-free; thereafter replacing the first reforming catalyst in the contaminant-free catalytic-reforming system with a second reforming catalyst; and thereafter contacting the second hydrocarbon feed in the contaminant-free catalytic-reforming system with the second reforming catalyst at second reforming conditions.

Peer, R.L.; Russ, M.B.

1990-07-10T23:59:59.000Z

50

Enrichment of light hydrocarbon mixture  

Science Conference Proceedings (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

51

Enrichment of light hydrocarbon mixture  

DOE Patents (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2010-08-10T23:59:59.000Z

52

Biological enhancement of hydrocarbon extraction  

SciTech Connect

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

53

Catalytic Conversion of Bioethanol to Hydrocarbons ...  

Conventional biomass to hydrocarbon conversion is generally not commercially feasible, due to costs of the conversion process.

54

Hydrocarbons from plants and trees  

DOE Green Energy (OSTI)

The way energy was used in the US in 1980 was examined. A diagram shows the development of energy from its source to its end use. The following are described: the carbon dioxide problem - the greenhouse effect, sugar cane as an energy source, hydrocarbon-producing plants and trees, and isoprenoids from plants and trees. (MHR)

Calvin, M.

1982-07-01T23:59:59.000Z

55

FADD Expression as a Prognosticator in Early-Stage Glottic Squamous Cell Carcinoma of the Larynx Treated Primarily With Radiotherapy  

Science Conference Proceedings (OSTI)

Purpose: We recently reported on the identification of the Fas-associated death domain (FADD) as a possible driver of the chromosome 11q13 amplicon and the association between increased FADD expression and disease-specific survival in advanced-stage laryngeal carcinoma. The aim of this study was to examine whether expression of FADD and its Ser194-phosphorylated isoform (pFADD) predicts local control in patients with early-stage glottic carcinoma primarily treated with radiotherapy only. Methods and Materials: Immunohistochemical staining for FADD and pFADD was performed on pretreatment biopsy specimens of 92 patients with T1-T2 glottic squamous cell carcinoma primarily treated with radiotherapy between 1996 and 2005. Cox regression analysis was used to correlate expression levels with local control. Results: High levels of pFADD were associated with significantly better local control (hazard ratio, 2.40; 95% confidence interval, 1.04-5.55; p = 0.040). FADD overexpression showed a trend toward better local control (hazard ratio, 3.656; 95% confidence interval, 0.853-15.663; p = 0.081). Multivariate Cox regression analysis showed that high pFADD expression was the best predictor of local control after radiotherapy. Conclusions: This study showed that expression of phosphorylated FADD is a new prognostic biomarker for better local control after radiotherapy in patients with early-stage glottic carcinomas.

Schrijvers, Michiel L. [Department of Otorhinolaryngology/Head and Neck Surgery, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Pattje, Wouter J. [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Department of Radiation Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Slagter-Menkema, Lorian [Department of Otorhinolaryngology/Head and Neck Surgery, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Mastik, Mirjam F.; Gibcus, Johan H. [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Langendijk, Johannes A. [Department of Radiation Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Wal, Jacqueline E. van der [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Laan, Bernard F.A.M. vn der [Department of Otorhinolaryngology/Head and Neck Surgery, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Schuuring, E., E-mail: e.schuuring@umcg.nl [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands)

2012-07-15T23:59:59.000Z

56

Method and apparatus for converting and removing organosulfur and other oxidizable compounds from distillate fuels, and compositions obtained thereby  

DOE Patents (OSTI)

The present disclosure is directed to a multi-stage system and a process utilizing said system with the design of reducing the sulfur-content in a liquid comprising hydrocarbons and organosulfur compounds. The process comprising at least one of the following states: (1) an oxidation stage; (2) an extraction state; (3) a raffinate washing stage; (4) a raffinate polishing stage; (5) a solvent recovery stage; (6) a solvent purification stage; and (7) a hydrocarbon recovery stage. The process for removing sulfur-containing hydrocarbons from gas oil, which comprises oxidizing gas oil comprising hydrocarbons and organosulfur compounds to obtain a product gas oil.

D' Alessandro, Robert N. (Spanish Fort, AL); Tarabocchia, John (Parsippany, NJ); Jones, Jerald Andrew (Frankfurt am Main, DE); Bonde, Steven E. (West Richard, WA); Leininger, Stefan (Langenselbold, DE)

2010-10-26T23:59:59.000Z

57

TRIBUTYL PHOSPHATE-HYDROCARBON DILUENT REPURIFICATION IN RADIOCHEMICAL PROCESSING AT ORNL: STATUS SUMMARY  

SciTech Connect

The need for, and the adequacy of, the sodium carbonate washing technique in chemical purification of tributyl phosphate-hydrocarbon extractant prior to its re-use in radiochemical processing was examined, primarily in terms of Ru, Zr, and Nb activities. Operating experience from ORNL Purex and Thorex Pilot Plants is compared with Hanford operations and upper limits for activities are suggested. Recommendations are made for development studies with the ORNL Power Reactor Fuel Processing Pilot Plant. (W.D.M.)

Davis, W. Jr.

1960-03-24T23:59:59.000Z

58

Separation of polar shale oil compounds using high-speed liquid chromatography. [Compounds known to exist in shale oil  

DOE Green Energy (OSTI)

Methods for separation of potentially toxic compounds from shale oil and its waste products by high-speed liquid chromatography (HSLC) are discussed. The following classes of compounds were selected for study: aromatic and polynuclear aromatic hydrocarbons, thiophenes, and indoles. No attempt was made to identify or quantitate compounds in shale oil, but it was demonstrated that HSLC can be a rapid and sensitive method for the separation of polar compounds from classes recognized to be present in shale oil and its waste products. Specific compounds studied were: phenanthrene, naphthalene, anthracene, pyrene, triphenylene, chrysene, benzo(a)pyrene, 1,2,3,4-dibenzanthracene, and 1,2,5,6-dibenzanthracene. (JGB)

Riley, R.G.

1976-11-01T23:59:59.000Z

59

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

60

Hydrocarbon biomarkers of Neoproterozoic to Lower Cambrian oils from eastern Siberia  

E-Print Network (OSTI)

with increasing amounts of thiol and thiophene compounds. Non-hydrocarbon gases from petroleum source rocks, L69 3GP It is assumed typically that minerals do not affect the geochemistry of petroleum, the consequences being bleaching of rocks by petroleum and the increasing availability of ferrous iron

Rothman, Daniel

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Examination of the Sources of Polycyclic Aromatic Hydrocarbon (PAH) in Urban Background Soil  

Science Conference Proceedings (OSTI)

Between 2000 and 2005, EPRI collected several hundred soil samples from urban background locations in three States and analyzed them for 17 polycyclic aromatic hydrocarbon compounds (PAHs). This report presents the initial results of efforts to extract additional chemical data from the urban background PAH database and to explore those data using chemical forensic methods for statistical properties and trends.

2008-12-22T23:59:59.000Z

62

Hydrocarbon Technologies | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Technologies Hydrocarbon Technologies Place Lawrenceville, New Jersey Zip 8648 Sector Efficiency Product String representation "Technology-base ... onmental risks." is too long. Coordinates 36.761678°, -77.845048° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.761678,"lon":-77.845048,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

63

Deep desulfurization of hydrocarbon fuels  

SciTech Connect

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

64

REFINING FLUORINATED COMPOUNDS  

DOE Patents (OSTI)

This invention relates to the method of refining a liquid perfluorinated hydrocarbon oil containing fluorocarbons from 12 to 28 carbon atoms per molecule by distilling between 150 deg C and 300 deg C at 10 mm Hg absolute pressure. The perfluorinated oil is washed with a chlorinated lower aliphatic hydrocarbon, which mairtains a separate liquid phase when mixed with the oil. Impurities detrimental to the stability of the oil are extracted by the chlorinated lower aliphatic hydrocarbon. (AEC)

Linch, A.L.

1963-01-01T23:59:59.000Z

65

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

DOE Green Energy (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

66

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically converting an alcohol ...

67

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically ...

68

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents (OSTI)

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

69

Process for the production of ethylene and other hydrocarbons from coal  

DOE Patents (OSTI)

A process is claimed for the production of substantial amounts of ethylene and other hydrocarbon compounds, such as benzene from coal. Coal is reacted with methane at a temperature in the approximate range of 500/sup 0/C to 1100/sup 0/C at a partial pressure less than about 200 psig for a period of less than 10 seconds, and preferably at a temperature of approximately 850/sup 0/C, and a partial pressure of 50 psig for a period of approximately 2 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

Steinberg, M.; Fallon, P.

1982-02-16T23:59:59.000Z

70

Pyrolitic Uranium Compound (PYRUC)  

NLE Websites -- All DOE Office Websites (Extended Search)

Pyrolitic Uranium Compound Pyrolitic Uranium Compound (PYRUC) PYRolitic Uranium Compound (PYRUC) is a shielding material consisting of depleted uranium UO2 or UC in either pellet...

71

Uranium and Its Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

and Its Compounds Uranium and Its Compounds line line What is Uranium? Chemical Forms of Uranium Properties of Uranium Compounds Radioactivity and Radiation Uranium Health Effects...

72

Conversion of organic solids to hydrocarbons  

DOE Patents (OSTI)

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

Greenbaum, Elias (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

73

Conversion of organic solids to hydrocarbons  

DOE Patents (OSTI)

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

74

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission...

75

Underground storage of natural gas, liquid hydrocarbons, and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana)...

76

Biogeochemistry of Isoprenoid Production and Anaerobic Hydrocarbon Biodgeradation.  

E-Print Network (OSTI)

??This dissertation is an exploration of microbial isoprenoid production and destruction by anaerobic hydrocarbon biodegradation. Isoprenoids are methyl-branched hydrocarbons, and include biomarkers from all three… (more)

Dawson, Katherine

2011-01-01T23:59:59.000Z

77

Magnetic and gravity anomaly patterns related to hydrocarbon fields in northern West Siberia  

SciTech Connect

A study of the features of gravity and magnetic fields in the vicinity of oil and gas reservoirs in West Siberia demonstrated a spatial relationship with the hydrocarbon deposits. The relevant magnetic and gravity anomalies cover approximately 900,000 km{sup 2} in northern West Siberia. Amplitude and frequency were investigated initially using double Fourier spectrum (DFS) analysis. This was followed by (1) application of transformations, filtering, and moving windows analysis; (2) compilation of maps of regional and local anomalies, and potential field derivatives; and (3) investigation of the distribution of parameters in areas of known deposits. Hydrocarbon deposits are located mostly at the slopes of positive regional gravity and magnetic anomalies which are interpreted as relating to deep riftogenic structures. At the same time, it is established that the location of hydrocarbon depositions coincides commonly with local gravity and magnetic minima generated by lows in basement density and magnetization. All known hydrocarbon deposits in northern West Siberia are in areas characterized by comparatively high gradients of constituent of gravity anomalies with a wavelength of about 90--100 km. These newly revealed links between reservoirs and potential field parameters may be a means to predict new discoveries in poorly explored territories and seas, primarily in Russia`s Arctic shelf.

Piskarev, A.L.; Tchernyshev, M.Yu. [VNIIOkeangeologia, St. Petersburg (Russian Federation)

1997-05-01T23:59:59.000Z

78

AMBIENT HYDROCARBONS IN THE HOUSTON METROPOLITAN AREA DURING TEXAQS 2000: AN IDENTIFICATION OF UNUSUAL FEATURES.  

SciTech Connect

Houston's ozone problem has been linked to the occurrence of very high light olefin concentrations. We have analyzed the DOE G-1 aircraft hydrocarbon data set to provide additional information on the geographic distribution and prevalence of air samples with high olefin concentration as well as an identification of other compounds which contribute to the high hydrocarbon reactivity in Houston. In order to identify high concentrations we need a definition of normal. For that purpose we use aircraft samples collected during a 1999 aircraft based field campaign in Philadelphia relying on the circumstance that the frequency distributions of NO{sub x} and C{sub 2}H{sub 2} in Philadelphia are nearly the same as in Houston. Comparison is made also with hydrocarbons collected in Phoenix which exhibit nearly the same NO{sub x} and C{sub 2}H{sub 2} frequency distribution as the other 2 cities, but in spite of that similarity have a much lower hydrocarbon reactivity. As in other studies we find that there is a subset of Houston hydrocarbon samples with very high OH-reactivity due to elevated concentrations of ethylene, propylene and less often butenes, including 1,3 butadiene. Although these samples stand out as being qualitatively different we present evidence that ethylene and propylene are significantly elevated in at least half of the Houston samples, covering a wide geographic area apart from the Ship Channel region. Frequency distributions for these compounds are log normal suggesting that Houston's atmosphere is a single entity rather than separate industrial and urban areas. The comparison between Houston and Philadelphia also identifies C{sub 2}-C{sub 5} alkanes, n-hexane, and benzene as having elevated concentrations. Emission reductions of these less reactive compounds sufficient to yield the concentrations observed in Philadelphia would have a minor effect on the most reactive samples, but about a 20% effect on samples with more typical (median) reactivity.

KLEINMAN, L.I.; DAUM P.H.

2004-11-01T23:59:59.000Z

79

Topical viscosity control for light hydrocarbon displacing fluids in petroleum recovery and in fracturing fluids for well stimulation  

DOE Patents (OSTI)

Solvent-type flooding fluids comprising light hydrocarbons in the range of ethane to hexane (and mixtures thereof) are used to displace crude oil in formations having temperatures of about 20 degrees to about 150 degrees Centigrade and pressures above about 650 psi, the light hydrocarbons having dissolved therein from about 0.05% to about 3% of an organotin compound of the formula R.sub.3 SnF where each R is independently an alkyl, aryl or alkyaryl group from 3 to 12 carbon atoms. Under the pressures and temperatures described, the organotin compounds become pentacoordinated and linked through the electronegative bridges, forming polymers within the light hydrocarbon flooding media to render them highly viscous. Under ambient conditions, the viscosity control agents will not readily be produced from the formation with either crude oil or water, since they are insoluble in the former and only sparingly soluble in the latter.

Heller, John P. (Socorro, NM); Dandge, Dileep K. (Socorro, NM)

1986-01-01T23:59:59.000Z

80

Process for recovery of liquid hydrocarbons  

SciTech Connect

Methane is recovered as a gas for discharge to a pipeline from a gas stream containing methane and heavier hydrocarbons, principally ethane and propane. Separation is accomplished by condensing the heavier hydrocarbons and distilling the methane therefrom. A liquid product (LPG) comprising the heavier hydrocarbons is subsequently recovered and transferred to storage. Prior to being discharged to a pipeline, the recovered methane gas is compressed and in undergoing compression the gas is heated. The heat content of the gas is employed to reboil the refrigerant in an absorption refrigeration unit. The refrigeration unit is used to cool the LPG prior to its storage.

Millar, J.F.; Cockshott, J.E.

1978-04-11T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

82

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

E-Print Network (OSTI)

W. and Calvin, M. J. Amer. Oil Chern. Assoc. Science,· 208,of the production of oil and alcohol from hydrocarbon-Figure 1 Cumulative U.S. crude oil discoveries as a function

Calvin, Melvin

2013-01-01T23:59:59.000Z

83

Thermodynamic Properties of Acetic Acid + Hydrocarbons ...  

Science Conference Proceedings (OSTI)

Thermodynamic Properties of Acetic Acid + Hydrocarbons Mixtures L. Negadi1,C,S, N. Ainous2, A. Negadi1, I. Mokbel2, A. Kaci3 and J. Jose2 ...

2006-07-20T23:59:59.000Z

84

Process for Photochemical Chlorination of Hydrocarbons  

DOE Patents (OSTI)

A process for chlorination of a major portion of the hydrogen atoms of paraffinic hydrocarbons of five or more carbon atoms may be replaced by subjecting the hydrocarbon to the action of chlorine under active light. The initial chlorination is begun at 25 to 30 deg C with the chlorine diluted with HCl. The later stages may be carried out with undiluted chlorine and the temperature gradually raised to about 129 deg C.

Beanblossom, W.S.

1950-10-31T23:59:59.000Z

85

Formation of hydrocarbons by bacteria and algae  

SciTech Connect

A literature review has been performed summarizing studies on hydrocarbon synthesis by microorganisms. Certain algal and bacterial species produce hydrocarbons in large quantities, 70 to 80% of dry cell mass, when in a controlled environment. The nutritional requirements of these organisms are simple: CO/sub 2/ and mineral salts. The studies were initiated to determine whether or not microorganisms played a role in petroleum formation. 90 references. (DMC)

Tornabene, T.G.

1980-12-01T23:59:59.000Z

86

Clean, economical, underwater (hydrocarbon) storage  

SciTech Connect

A consortium consisting of Howaldtswerke-Deutsche Werft A.G., Phoenix Gummiwerke A.G., Strabag Bau-A.G., and Bugsier Reederei und Bergungs-A.G. offers a plausible solution to the large-scale underwater storage of hydrocarbons. Up to 20 storage compartments of 8000 cu m capacity can be assembled for a capacity of 160,000 cu m. Each compartment is divided in half by a nylon-reinforced polyurethane diaphragm which isolates oil or other products on one side from sea-water ballast on the other side. As oil is pumped into storage on one side of the diaphragm, the diaphragm moves and ballast on the other side is displaced to the sea. Ballast re-enters the compartment during unloading. The system can enable small offshore platforms to produce more economically. Cargo tankers load at 8000 cu m/hr. The tanks will be used in 200 m or greater water depths. The loading station is installed in a buoy 30 m below the water surface.

1978-08-01T23:59:59.000Z

87

Remedial evaluation of a UST site impacted with chlorinated hydrocarbons  

Science Conference Proceedings (OSTI)

During assessment and remedial planning of an underground storage tank (UST) site, it was discovered that chlorinated hydrocarbons were present. A network of selected wells were sampled for analysis of halogenated volatile organics and volatile organic compounds to determine the extent of constituents not traditionally associated with refined petroleum motor fuel products. The constituents detected included vinyl chloride, tetrachloroethylene (PCE), bromodichloromethane, and 2-chloroethylvinyl ether. These analytical data were evaluated as to what effect the nonpetroleum hydrocarbon constituents may have on the remedial approach utilized the site hydrogeologic properties to its advantage and took into consideration the residential nature of the impacted area. The geometry of the dissolved plume is very flat and broad, emanating from the site and extending downgradient under a residential area situated in a transmissive sand unit. Ground-water pumping was proposed from two areas of the dissolved plume including five wells pumping at a combined rate of 55 gallons per minute (gpm) at a downgradient position, and two wells on-site to remove free product and highly impacted ground water. Also, to assist in remediation of the dissolved plume and to control vapors, a bioventing system was proposed throughout the plume area.

Ilgner, B.; Rainey, E. (Geraghty and Miller, Inc., Oak Ridge, TN (United States)); Ball, M.; Schutt, M.

1993-10-01T23:59:59.000Z

88

Conversion of ethane and of propane to higher olefin hydrocarbons  

DOE Green Energy (OSTI)

Purely thermal reactions for the conversion of ethane were carried out in an empty and in a quartz chip filled reactor over a temperature range of 300--800{degrees}C in the absence and presence of oxygen and oxygen plus water. Ethane alone shows no conversion below 600{degrees}C and some conversion to CH{sub 4} and very little C{sub 2}H{sub 4} at 700{degrees} and 800{degrees}C. Ethane and oxygen produce CO{sub 2} as the major product above 400{degrees}C. The additional presence of water does not appreciably change this picture. Converting ethane with oxygen and water over a Ca{sub 3}Ni{sub 1}K{sub 0.1} catalyst at very low space velocity gave increasing conversion with temperature, primarily CO{sub 2} production and a small amount of C{sub 3+} hydrocarbons. The CO{sub 2} production was decreased and slightly more C{sub 3} hydrocarbons were produced when the potassium concentration of the catalyst was increased. Activation energies have been calculated for the various ethane conversion reactions. It appears that the CaNiK oxide catalyst is not suited for oxidative ethane coupling at the conditions thus far investigated. The indications are that much shorter contact times are required to prevent oxidation of intermediates. Blank runs with propane and oxygen in the absence of a catalyst have shown significant reaction at temperatures as low as 400{degrees}C. 12 figs., 3 tabs.

Heinemann, H.; Somorjai, G.A.

1991-10-01T23:59:59.000Z

89

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

NLE Websites -- All DOE Office Websites (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

90

Toxicity Analysis of Polycyclic Aromatic Hydrocarbon Mixtures  

E-Print Network (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) are widely distributed in the environment and are generated by many sources. Though the potential of PAH-rich mixtures to cause health effects has been known for almost a century, there are still unanswered questions about the levels of PAHs in the environment, the potential for human exposure to PAHs, the health effects associated with exposure, and how genetic susceptibility influences the extent of health effects in individuals. The first objective of this research was to quantify concentrations of PAHs in samples of settled house dust collected from homes in Azerbaijan, China, and Texas. The trends of PAH surface loadings and percentage of carcinogenic PAHs were China > Azerbaijan > Texas, indicating that the risk of health effects from exposure to PAHs in house dust is highest in the Chinese population and lowest in the Texas population. PAHs in China and Azerbaijan were derived mainly from combustion sources; Texas PAHs were derived from unburned fossil fuels such as petroleum. The second objective of this research was to investigate the effect of pregnane X receptor (PXR) on the genotoxicity of benzo[a]pyrene (BaP). BaP treatment resulted in significantly lower DNA adduct levels in PXR-transfected HepG2 cells than in parental HepG2 cells. Total GST enzymatic activity and mRNA levels of several metabolizing enyzmes were significantly higher in cells overexpressing PXR. These results suggest that PXR protects cells against DNA damage by PAHs such as BaP, possibly through a coordinated regulation of genes involved in xenobiotic metabolism. The third objective of this research was to investigate biomarkers of exposure in house mice (Mus musculus) exposed to PAH mixtures in situ. Mice and soil were collected near homes in Sumgayit and Khizi, Azerbaijan. Mean liver adduct levels were significantly higher in Khizi than in Sumgayit. Mean lung and kidney adduct levels were similar in the two regions. The DNA lesions detected may be a combination of environmentally-induced DNA adducts and naturally-occurring I-compounds. PAHs were present at background levels in soils from both Khizi and Sumgayit. It appears that health risks posed to rodents by soil-borne PAHs are low in these two areas.

Naspinski, Christine S.

2009-05-01T23:59:59.000Z

91

Process for reducing organic compounds with calcium, amine, and alcohol  

DOE Patents (OSTI)

Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

Benkeser, Robert A. (West Lafayette, IN); Laugal, James A. (Lostant, IL); Rappa, Angela (Baltimore, MD)

1985-01-01T23:59:59.000Z

92

Process for reducing organic compounds with calcium, amine, and alcohol  

DOE Patents (OSTI)

Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about [minus]10 C to about 30 C or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

Benkeser, R.A.; Laugal, J.A.; Rappa, A.

1985-08-06T23:59:59.000Z

93

Process for the hydroisomerization and hydrocracking of Fisher-Tropsch waxes to produce a syncrude and upgraded hydrocarbon products  

SciTech Connect

A process is described for producing a pumpable syncrude from a Fischer-Tropsch wax containing oxygenate compounds, which comprises: (1) separating the Fischer-Tropsch wax into (a) a low-boiling fraction which contains most of the oxygenate compounds and (b) a high-boiling fraction which is substantially free of water and oxygenate compounds, (2) reacting the high-boiling fraction from step (1) with hydrogen at hydroisomerization and mild hydrocracking conditions in the presence of a fluorided Group VIII metal-on-alumina catalyst to produce a C/sub 5/ + hydrocarbon product, and (3) combining the C/sub 5/ + hydrocarbon product from step (2) with the low-boiling fraction from step (1) to produce a pumpable, refinery processable syncrude that can be transported at atmospheric conditions.

Hamner, G.P.

1989-05-23T23:59:59.000Z

94

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (‘syngas’) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

95

George A. Olah, Carbocation and Hydrocarbon Chemistry  

Office of Scientific and Technical Information (OSTI)

George A. Olah, Carbocation and Hydrocarbon Chemistry George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information · Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations are stable and their physical properties ... can be observed, thus allowing details of their structures to be determined. Besides trivalent ions ... Olah demonstrated the existence of higher coordinate carbocations ... . These species do not violate the octet rule, but involve 2-electron 3-center bonding. '1

96

Gulf Hydrocarbon Inc | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Inc Hydrocarbon Inc Jump to: navigation, search Name Gulf Hydrocarbon Inc Address 2016 Main St Place Houston, Texas Zip 77002 Sector Biofuels Product Wholesale marketing of biodiesel and ethanol to refiners, blenders and petroleum distributors Website http://www.gulfhydrocarbon.com Coordinates 29.749227°, -95.371693° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.749227,"lon":-95.371693,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

97

Catalysts for synthesizing various short chain hydrocarbons  

DOE Green Energy (OSTI)

Method and apparatus (10), including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO.sub.2 aerogels doped with photochemically active uranyl ions (18) are fluidized in a fluidized-bed reactor (12) having a transparent window (16), by hydrogen and CO, C.sub.2 H.sub.4 or C.sub.2 H.sub.6 gas mixtures (20), and exposed to radiation (34) from a light source (32) external to the reactor (12), to produce the short chain hydrocarbons (36).

Colmenares, Carlos (Alamo, CA)

1991-01-01T23:59:59.000Z

98

Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review  

Science Conference Proceedings (OSTI)

Nonmethane hydrocarbons are ubiquitous trace atmospheric constituents yet they control the oxidation capacity of the atmosphere. Both anthropogenic and biogenic processes contribute to the release of hydrocarbons to the atmosphere. In this ...

J. D. Fuentes; L. Gu; M. Lerdau; R. Atkinson; D. Baldocchi; J. W. Bottenheim; P. Ciccioli; B. Lamb; C. Geron; A. Guenther; T. D. Sharkey; W. Stockwell

2000-07-01T23:59:59.000Z

99

Co-cultured Synechococcus and Shewanella Produce Hydrocarbons ...  

... microbes has been developed. These hydrocarbons may be further processed into vehicle fuels using traditional oil refining techniques.

100

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents (OSTI)

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

102

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

103

Method for recovery of hydrocarbon material from hydrocarbon material-bearing formations  

SciTech Connect

A method is disclosed for heating a hydrocarbon material contained in a recovery zone in an underground hydrocarbon material-bearing formation to reduce the viscosity thereof for facilitating recovery of the hydrocarbon material. A gaseous penetration medium comprising a gaseous working fluid and a carrier gas, is fed into the formation at a penetration pressure sufficient for penetration of the recovery zone, the working fluid being a water soluble gas which generates heat of solution upon absorption in an aqueous medium, and in which the partial pressure of the working fluid in relation to the penetration pressure and the temperature prevailing in the recovery zone is controlled to inhibit working fluid condensation but to provide for absorption of working fluid by water present in the formation to release heat for heating the hydrocarbon material in the recovery zone.

Kalina, A.I.

1982-05-25T23:59:59.000Z

104

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

105

Method of dispersing a hydrocarbon using bacteria  

DOE Patents (OSTI)

New protozoan derived microbial consortia and method for their isolation are provided. Consortia and bacteria isolated therefrom are useful for treating wastes such as trichloroethylene and trinitrotoluene. Consortia, bacteria isolated therefrom, and dispersants isolated therefrom are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

Tyndall, Richard L. (Clinton, TN)

1996-01-01T23:59:59.000Z

106

Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs)  

E-Print Network (OSTI)

.2.2 Anthropogenic emissions 28 2.3 Polycyclic Aromatic Hydrocarbons 30 2.3.1 Sources of PAHs 30 2.3.2 Gas to particle distribution in atmosphere 32 2.3.3 Gas to particle distribution in atmosphere 32 CHAPTER THREE

Paris-Sud XI, Université de

107

Selective Sorbents For Purification Of Hydrocarbons  

DOE Patents (OSTI)

A method for removing thiophene and thiophene compounds from liquid fuel includes contacting the liquid fuel with an adsorbent which preferentially adsorbs the thiophene and thiophene compounds. The adsorption takes place at a selected temperature and pressure, thereby producing a non-adsorbed component and a thiophene/thiophene compound-rich adsorbed component. The adsorbent includes either a metal or a metal ion that is adapted to form p-complexation bonds with the thiophene and/or thiophene compounds, and the preferential adsorption occurs by p-complexation. A further method includes selective removal of aromatic compounds from a mixture of aromatic and aliphatic compounds.

Yang, Ralph T. (Ann Arbor, MI); Yang, Frances H. (Ann Arbor, MI); Takahashi, Akira (Yoko-Machi, JP); Hernandez-Maldonado, Arturo J. (Ann Arbor, MI)

2006-04-18T23:59:59.000Z

108

Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon  

SciTech Connect

The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

2012-08-19T23:59:59.000Z

109

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents (OSTI)

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

110

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents (OSTI)

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

111

Method and apparatus for synthesizing hydrocarbons  

DOE Patents (OSTI)

A method and apparatus for synthesizing a mixture of hydrocarbons having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further includes Na present as a substitutional cation in an amount of about 5 to 10 atom %. At a temperature of about 340 to 360/sup 0/C, and at pressures of about 20 to 50 atm, CH/sub 3/OH is produced in an amount of about 90 wt % of the total hydrocarbon mixture, and comprised 1 mole % of the effluent gas.

Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

1983-06-21T23:59:59.000Z

112

Chemical kinetic modelling of hydrocarbon ignition  

DOE Green Energy (OSTI)

Chemical kinetic modeling of hydrocarbon ignition is discussed with reference to a range of experimental configurations, including shock tubes, detonations, pulse combustors, static reactors, stirred reactors and internal combustion engines. Important conditions of temperature, pressure or other factors are examined to determine the main chemical reaction sequences responsible for chain branching and ignition, and kinetic factors which can alter the rate of ignition are identified. Hydrocarbon ignition usually involves complex interactions between physical and chemical factors, and it therefore is a suitable and often productive subject for computer simulations. In most of the studies to be discussed below, the focus of the attention is placed on the chemical features of the system. The other physical parts of each application are generally included in the form of initial or boundary conditions to the chemical kinetic parts of the problem, as appropriate for each type of application being addressed.

Westbrook, C.K.; Pitz, W.J.; Curran, H.J.; Gaffuri, P.; Marinov, N.M.

1995-08-25T23:59:59.000Z

113

XAFS Model Compound Library  

DOE Data Explorer (OSTI)

The XAFS Model Compound Library contains XAFS data on model compounds. The term "model" compounds refers to compounds of homogeneous and well-known crystallographic or molecular structure. Each data file in this library has an associated atoms.inp file that can be converted to a feff.inp file using the program ATOMS. (See the related Searchable Atoms.inp Archive at http://cars9.uchicago.edu/~newville/adb/) This Library exists because XAFS data on model compounds is useful for several reasons, including comparing to unknown data for "fingerprinting" and testing calculations and analysis methods. The collection here is currently limited, but is growing. The focus to date has been on inorganic compounds and minerals of interest to the geochemical community. [Copied, with editing, from http://cars9.uchicago.edu/~newville/ModelLib/

Newville, Matthew

114

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents (OSTI)

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

115

HYDROCARBON FORMATION ON POLYMER-SUPPORTED COBALT  

SciTech Connect

In this report we detail the synthesis catalytic chemistry of polystyrene supported {eta}{sup 5} ~cyclopentadienyl- dicarbonyl cobalt, CpCo(CO){sub 2}. This material is active in the hydrogenation of CO to saturated linear hydrocarbons and appears to retain its "homogeneous", mononuclear character during the course of its catalysis, During ·the course of our work 18% and 20% crosslinked analogs of polystyrene supported CpCo(CO){sub 2} were shown to exhibit limited catalytic activity and no CO activation.

Benner, Linda S.; Perkins, Patrick; Vollhardt, K.Peter C.

1980-10-01T23:59:59.000Z

116

A Review of World Hydrocarbon Resource Assessments  

Science Conference Proceedings (OSTI)

This study reviews assessments of world oil, natural gas, and oil shale resources made between the end of World War II and the end of 1980. Details are provided on the methods used in developing these assessments, geographic coverage, time horizons, and major assumptions (e.g., about discovery rates and recovery factor). Conclusions on the current state of knowledge concerning each of these hydrocarbon resources are presented.

1982-11-01T23:59:59.000Z

117

Literature Review of Background Polycyclic Aromatic Hydrocarbons  

Science Conference Proceedings (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) continuously move through the environment, often via atmospheric transport. The subsequent deposition of particulates containing PAHs along with other sources of PAHs, such as natural vegetative decay, result in "background" PAHs in surficial soils. Even in pristine areas, surface and near surface soils can contain detectable levels of PAHs. This study provides data on the concentrations and distributions of background PAHs observed in environmental media. Such inf...

2000-03-20T23:59:59.000Z

118

Hydrocarbon content of geopressured brines. Final report  

DOE Green Energy (OSTI)

Design Well data (bottomhole pressure minus wellhead pressure, GWR, and hydrocarbon composition) is presented as a function of producing conditions. These are examined in conjunction with the following models to attempt to deduce the reservoir brine saturation level: (1) reservoir contains gas dispersed in the pores and the gas saturation is greater than critical; (2) reservoir brine is gas-saturated; (3) bubble point below hydrostatic pressure; and (4) bubble point between hydrostatic pressure and reservoir pressure. 24 figs., 10 tabs. (ACR)

Osif, T.L.

1985-08-01T23:59:59.000Z

119

Getter pump for hydrogen and hydrocarbon gases  

DOE Patents (OSTI)

A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm.sup.2. The graphite may be heated to a temperature greater than 1000.degree. C. The new device offers high capacity, low noise, and gas species selectivity.

Hsu, Wen L. (Danville, CA)

1989-01-01T23:59:59.000Z

120

Preparation of uranium compounds  

SciTech Connect

UI.sub.3(1,4-dioxane).sub.1.5 and UI.sub.4(1,4-dioxane).sub.2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.

Kiplinger, Jaqueline L; Montreal, Marisa J; Thomson, Robert K; Cantat, Thibault; Travia, Nicholas E

2013-02-19T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hydrocarbon Fouling of SCR during PCCI combustion  

SciTech Connect

The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust. The Fe-zeolite NOX conversion efficiency was significantly degraded, especially at low temperatures (<250 C), after the catalyst was exposed to the raw engine exhaust. The degradation of the Fe-zeolite performance was similar for both combustion modes. The Cu-zeolite showed better tolerance to HC fouling at low temperatures compared to the Fe-zeolite but PCCI exhaust had a more significant impact than the exhaust from conventional combustion on the NOX conversion efficiency. Furthermore, chemical analysis of the hydrocarbons trapped on the SCR cores was conducted to better determine chemistry specific effects.

Prikhodko, Vitaly Y [ORNL; Pihl, Josh A [ORNL; Lewis Sr, Samuel Arthur [ORNL; Parks, II, James E [ORNL

2012-01-01T23:59:59.000Z

122

Partially fluorinated ionic compounds  

DOE Patents (OSTI)

Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.

Han, legal representative, Amy Qi (Hockessin, DE); Yang, Zhen-Yu (Hockessin, DE)

2008-11-25T23:59:59.000Z

123

Closure Report for Corrective Action Unit 499: Hydrocarbon Spill Site, Tonopah Test Range, Nevada  

DOE Green Energy (OSTI)

This Closure Report (CR) has been prepared for Corrective Action Unit (CAU) 499: Hydrocarbon Spill Site, in accordance with the Federal Facility Agreement and Consent Order (FFACO, 1996) and the Nevada Division of Environmental Protection (NDEP)-approved Streamlined Approach for Environmental Restoration (SAFER) Plan for CAU 499: Hydrocarbon Spill Site, Tonopah Test Range (TTR), Nevada (US Department of Energy, Nevada Operations Office [DOE/NV], 2001). CAU 499 consists of one Corrective Action Site (CAS): RG-25-001-RD24: Radar 24 Diesel Spill Site which is approximately 4.0 kilometers (2.5 miles) southwest of the Area 3 Compound at the end of Avenue 24. The Hydrocarbon Spill Site is a diesel fuel release site that is assumed to have been caused by numerous small historical over-fillings, spills, and leaks from an above-ground storage tank (AST) over a period of approximately 36 years. The tank was located on the east side of Building 24-50 on the TTR.

K. B. Campbell

2002-07-01T23:59:59.000Z

124

Evaluation of the total petroleum hydrocarbon standard for cleanup of petroleum contaminated sites. Master's thesis  

Science Conference Proceedings (OSTI)

This study evaluated the TPH (total petroleum hydrocarbon) cleanup standard for petroleum contaminated soils (PCS). A survey of 13 state regulators was performed to characterize current standards and regulatory viewpoints on the use of a TPH versus a BTEX cleanup standard. The regulatory community considers the BTEX constituents the greatest threat to groundwater, yet expressed concern that the use of a compound specific standard, without an accompanying analysis for TPH, might result in residual soil contamination that may present risk. This study also evaluated the ratio of BTEX TPH in soil over time. Based on JP-4 contaminated site soil data, this study demonstrated that the ratio of BTEX to TPH declines with time. The results indicate that the constant ratio of BTEX to TPH assumed by the California LUFT manual and Stokman and Dime's research is not valid for soils contaminated with JP-4. Lastly, this research identifies the cost savings potential that would result if a BTEX based standard, versus a TPH standard, were required at all Air Force sites. The research shows that only 13% of sites which would require cleanup under a TPH standard would require cleanup under a BTEX based standard. Soil cleanup standards, Petroleum hydrocarbons, Total petroleum hydrocarbons, TPH, Bezene, Toluene, Ethylbenzene, Ethyl-benzene, Xylene, BTEX, Petroleum contamination, JP-4.

Blaisdell, R.A.; Smallwood, M.E.

1993-09-01T23:59:59.000Z

125

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

126

Harvester ants utilize cuticular hydrocarbons in nestmate recognition  

E-Print Network (OSTI)

Abstract—Cuticular hydrocarbons appear to play a role in ant nestmate recognition, but few studies have tested this hypothesis experimentally with purified hydrocarbon extracts. We exposed captive colonies of the harvester ant Pogonomyrmex barbatus to small glass blocks coated with whole cuticular lipid extracts and the purified hydrocarbon portion of extracts from nestmate and nonnestmate workers. As an estimate of agonistic behavior, we measured the proportion of ants in contact with blocks that flared their mandibles. Blocks coated with cuticular extracts from nonnestmates were contacted by more workers in one of two experiments and elicited higher levels of aggression in both experiments than blocks bearing extracts from nestmates. The cuticular hydrocarbon fraction of extracts alone was sufficient to elicit agonistic behavior toward nonnestmates. The results demonstrate that harvester ants can perceive differences in cuticular hydrocarbon composition, and can use those differences in nestmate recognition. Key Words—Cuticular hydrocarbons, Formicidae, Nestmate recognition, Pogonomyrmex barbatus.

Diane Wagner; Madeleine Tissot; William Cuevas; Deborah M. Gordon

2000-01-01T23:59:59.000Z

127

Catalytic conversion of cellulose to liquid hydrocarbon fuels ...  

Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

128

Novel catalyst for selective NOx reduction using hydrocarbons ...  

This invention discloses a catalyst and process for removing nitrogen oxides from exhaust streams under lean burn conditions using hydrocarbons as the reductant.

129

ORGANIC GEOCHEMICAL STUDIES. I. MOLECULAR CRITERIA FOR HYDROCARBON GENESIS  

E-Print Network (OSTI)

isoprenoid hydrocarbons in crude oils and sediments must beisomers (up to C ) in crude oil and those characterised inarc found ubiqubtously in crude oils and shalt extracts as

McCarthy, Eugene D.; Calvin, Kevin

2008-01-01T23:59:59.000Z

130

Methods for natural gas and heavy hydrocarbon co-conversion  

DOE Patents (OSTI)

A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

Kong, Peter C. (Idaho Falls, ID); Nelson, Lee O. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

2009-02-24T23:59:59.000Z

131

Recovery of nitrogen and light hydrocarbons from polyalkene ...  

Recovery of nitrogen and light hydrocarbons from polyalkene purge gas United States Patent. Patent Number: 6,576,043: Issued: June 10, 2003: Official Filing:

132

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents (OSTI)

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

133

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents (OSTI)

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

134

Multi-step catalytic hydroprocessing to produce hydrocarbon fuels ...  

Multi-step catalytic hydroprocessing to produce hydrocarbon fuels from biomass pyrolysis bio-oil (PNNL IPID 16665) Pacific Northwest National Laboratory

135

Systems and methods for producing hydrocarbons from tar sands formations  

DOE Patents (OSTI)

A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

2009-07-21T23:59:59.000Z

136

Polycyclic Aromatic Hydrocarbon Exposure in German Coke Oven Workers.  

E-Print Network (OSTI)

??Polycyclic aromatic hydrocarbons (PAHs) are formed whenever there is incomplete combustion of carbonaceous material. They are ubiquitous in the environment and background levels are found… (more)

Thoroman, Jeffrey S.

2010-01-01T23:59:59.000Z

137

Hydrocarbon synthesis catalyst and method of preparation  

DOE Patents (OSTI)

A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

Sapienza, Richard S. (Shoreham, NY); Sansone, Michael J. (Summit, NJ); Slegeir, William A. R. (Hampton Bays, NY)

1983-08-02T23:59:59.000Z

138

Collisional processes of hydrocarbons in hydrogen plasmas  

DOE Green Energy (OSTI)

We have investigated the reactions of methane and its derivatives with hydrogen plasmas for use in modelling carbon and hydrocarbon transport in hydrogen plasmas. We provide quantitative information over the temperature range from 0.1 eV to 2 keV for the most significant reactions of methane and methane fragments with electrons and protons. We review the properties of each reaction, present graphs of the cross section and reaction rate coefficient, and give analytical fits for sigma and (sigmav). 34 refs.

Ehrhardt, A.B.; Langer, W.D.

1987-09-01T23:59:59.000Z

139

Heart testing compound  

DOE Patents (OSTI)

The compound 15-(p-(/sup 125/I)-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, F.F. Jr.; Goodman, M.M.

1983-06-29T23:59:59.000Z

140

Heart testing compound  

DOE Patents (OSTI)

The compound 15-(p-[.sup.125 I]-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, Jr., Furn F. (Oak Ridge, TN); Goodman, Mark M. (Knoxville, TN)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Geology and hydrocarbon potentials of Arafura Sea  

Science Conference Proceedings (OSTI)

The Arafura Sea is a continental-shelf sea located between Irian Jaya (western New Guinea) and the northern part of the Australian continent. On the south it adjoins the stable Australian craton, and on the north it is bordered by the Tertiary collision zone between the Australian craton and the northern Irian Jaya island arc. On the west and northwest it is bounded by the active Banda arc collision zone, whereas on the east it is bordered by the northern extension of the Gulf of Carpentaria that also forms the western limit of the zone of late Paleozoic granites. Shelf sediments, ranging in age from late Paleozoic to Cenozoic, predominate in the Arafura Sea continental shelf, and are underlain by granitic basement. Gas shows have been reported from Jurassic to Cretaceous fine-grained marine limestones and sandstones, and gas and condensate also are present in Cretaceous sediments and Middle Jurassic fine-grained sandstones. At the north, the most prospective area seems to be the hinge zone of the Aru high, where a combination of traps and reservoir rocks presumably exists. On the south, the Money Shoal area is considered a significant prospect. In the Arafura basin, stratigraphic traps seem to be the most promising target for hydrocarbon exploration as tectonics seems not to have played an important role in the area. The sedimentary area occupied by the eastern extension of the Tarera-Aiduna wrench fault should also be investigated in detail for its hydrocarbon potential.

Katili, J.A.

1984-09-01T23:59:59.000Z

142

Lubricant formulation for lower unburnt hydrocarbon emissions  

Science Conference Proceedings (OSTI)

Engine-out emissions of unburnt hydrocabons from spark ignition engines are attributable to a number of mechanisms, occurring during the engine cycle, by which fuel escapes combustion. These include absorption of fuel components into the bore lubricating oil film during compression, and subsequent desorption into hot combustion gases throughout expansion. A proportion of the hydrocarbons desorbed will then be emitted, either as unburnt or partially oxidised fuel. This mechanism has been studied by a number of workers, and estimates of its importance vary from 10 to 30% of total hydrocarbons being related to the absorption/desorption process. A novel lubricant additive has been formulated for the purpose of reducing the quantity of fuel which is absorbed into the bore lubricant film, and hence the quantity of fuel subsequently desorbed. This paper describes a programme to evaluate the effect that this lubricant additive can have on engine-out emissions from a single cylinder research engine, together with results from current technology, low-emitting US and European vehicles, tested over FTP and ECE drive cycles. 11 refs., 9 figs., 3 tabs.

Beckwith, P.; Cooper, J.H.

1994-10-01T23:59:59.000Z

143

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

1999-01-01T23:59:59.000Z

144

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2001-01-01T23:59:59.000Z

145

Selective thermal oxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2000-01-01T23:59:59.000Z

146

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Jones, S.

2013-03-01T23:59:59.000Z

147

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

2013-03-01T23:59:59.000Z

148

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

149

Cogeneration systems and processes for treating hydrocarbon containing formations  

Science Conference Proceedings (OSTI)

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

2009-12-29T23:59:59.000Z

150

Heating hydrocarbon containing formations in a line drive staged process  

DOE Patents (OSTI)

Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

Miller, David Scott (Katy, TX)

2009-07-21T23:59:59.000Z

151

Predicting flammability of gas mixtures containing volatile organic compounds  

DOE Green Energy (OSTI)

One requirement regarding the transportation of transuranic (TRU) radioactive waste containers currently limits the total concentration of potentially flammable volatile organic compounds (VOCs) and flammable gases in the headspace of the waste container. Typical VOCs observed in the drums include aromatic hydrocarbons, ketones, alcohols, cyclohexane, as well as chlorinated hydrocarbons (alkanes and alkenes). Flammable gases, such as hydrogen and methane, may be generated in the containers by radiation-induced decomposition (radiolysis) of water and hydrocarbon waste forms. An experimental program was initiated to identify an accurate means for predicting flammability for gas mixtures containing one or more of the following species: hydrogen, carbon tetrachloride, 1,2-dichloroethane, toluene, or 2-butanone. The lower flammability limits (LFL) of gas mixtures containing equimolar quantity for each species were determined in a 19-liter laboratory flammability chamber using a strong spark ignition source. The group factor contribution method was determined to be more accurate than the LeChatelier method for estimating the LFL for these gas mixtures.

Liekhus, K. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.; Zlochower, I. [National Inst. for Occupational Safety and Health, Pittsburgh, PA (United States). Pittsburgh Research Lab.; Djordjevic, S.; Loehr, C. [Benchmark Environmental, Albuquerque, NM (United States)

1997-12-31T23:59:59.000Z

152

Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California  

E-Print Network (OSTI)

Formation, the primary source of petroleum hydrocarbons inPetroleum Geologists, Tulsa Clark JF, Washburn L, Hornafius JS, Luyendyk BP (2000) Natural marine hydrocarbon seep source

Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

2010-01-01T23:59:59.000Z

153

The Spatial Scales, Distribution, and Intensity of Natural Marine Hydrocarbon Seeps near Coal Oil Point, California  

E-Print Network (OSTI)

marine hydrocarbon seeps (Coal Oil Point, Santa Barbara,marine hydrocarbon seepage near Coal Oil Point, California,associated with offshore oil production", Geology, 27(11),

Washburn, Libe; Clark, Jordan F.; Kyriakidis, Phaedon

2004-01-01T23:59:59.000Z

154

The Spatial Scales, Distribution, and Intensity of Natural Marine Hydrocarbon Seeps near Coal Oil Point, California  

E-Print Network (OSTI)

marine hydrocarbon seeps (Coal Oil Point, Santa Barbara,marine hydrocarbon seepage near Coal Oil Point, California,source areas such as near Coal Oil Point. Furthermore,

Washburn, Libe; Clark, Jordan F.; Kyriakidis, Phaedon

2004-01-01T23:59:59.000Z

155

Molecular and Biochemical Characterization of Hydrocarbon Production in the Green Microalga Botryococcus braunii  

E-Print Network (OSTI)

Botryococcus braunii (Chlorophyta, Botryococcaceae) is a colony-forming green microalga that produces large amounts of liquid hydrocarbons, which can be converted into transportation fuels. While B. braunii has been well studied for the chemistry of the hydrocarbon production, very little is known about the molecular biology of B. braunii. As such, this study developed both apparatus and techniques to culture B. braunii for use in the genetic and biochemical characterization. During genetic studies, the genome size was determined of a representative strain of each of the three races of B. braunii, A, B, and L, that are distinguished based on the type of hydrocarbon each produces. Flow cytometry analysis indicates that the A race, Yamanaka strain, of B. braunii has a genome size of 166.0 +/- 0.4 Mb, which is similar to the B race, Berkeley strain, with a genome size of 166 +/- 2.2 Mb, while the L race, Songkla Nakarin strain, has a substantially larger genome size at 211.3 +/- 1.7 Mb. Phylogenetic analysis with the nuclear small subunit (18S) rRNA and actin genes were used to classify multiple strains of A, B, and L races. These analyses suggest that the evolutionary relationship between B. braunii races is correlated with the type of liquid hydrocarbon they produce. Biochemical studies of B. braunii primarily focused on the B race, because it uniquely produces large amounts of botryococcenes that can be used as a fuel for internal combustion engines. C30 botryococcene is metabolized by methylation to generate intermediates of C31, C32, C33, and C34. Raman spectroscopy was used to characterize the structure of botryococcenes. The spectral region from 1600?1700 cm^-1 showed v(C=C) stretching bands specific for botryococcenes. Distinct botryococcene Raman bands at 1640 and 1647 cm^-1 were assigned to the stretching of the C=C bond in the botryococcene branch and the exomethylene C=C bonds produced by the methylations, respectively. A Raman band at 1670 cm^-1 was assigned to the backbone C=C bond stretching. Finally, confocal Raman microspectroscopy was used to map the presence and location of methylated botryococcenes within a living colony of B. braunii cells.

Weiss, Taylor Leigh

2012-08-01T23:59:59.000Z

156

Charge Density Wave Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Fisher Research Group Fisher Research Group Layered Chalcogenides 29 February 2008 Controlling the Wave by Brad Plummer, SLAC Communications Stanford University researchers working in part at SSRL have discovered a novel set of properties pertaining to a compound of materials called tritellurides. These compounds, composed of three atoms of tellurium and a single atom of one of the rare earth elements, demonstrate unique electronic properties that can be controlled by altering the temperature of the material. The tritellurides display phenomena known as charge density waves (CDW). In a normal conductive metal, electrons persist in a "sea" wherein they are evenly distributed and equally available, or conductive. A CDW occurs under certain circumstances and causes the electrons to clump together, lowering their availability, and thereby lowering the compound's conductivity. Tellurium, when crystallized into quasi-two-dimensional planes and combined with rare earth elements, produces a material with CDWs that can be manipulated and controlled.

157

Stable isotope investigations of chlorinated aliphatic hydrocarbons.  

Science Conference Proceedings (OSTI)

Stable isotope ratio measurements for carbon (C) and chlorine (Cl) can be used to elucidate the processes affecting transformation and transportation of chlorinated aliphatic hydrocarbons (CAHs) in the environment. Methods recently developed in our laboratory for isotopic analysis of CAHs have been applied to laboratory measurements of the kinetic isotope effects associated with aerobic degradation of dichloromethane (DCM) and with both anaerobic and aerobic cometabolic degradation of trichlomethene (TCE) in batch and column microbial cultures. These experimental determinations of fractionation factors are crucial for understanding the behavior of CAHs in complex natural systems, where the extent of biotransformation can be masked by dispersion and volatilization. We have also performed laboratory investigations of kinetic isotope effects accompanying evaporation of CAHs, as well as field investigations of natural attenuation and in situ remediation of CAHs in a number of contaminated shallow aquifers at sites operated by the federal government and the private sector.

Abrajano, T.; Heraty, L. J.; Holt, B. D.; Huang, L.; Sturchio, N. C.

1999-06-01T23:59:59.000Z

158

Microbial hydrocarbons: back to the future  

Science Conference Proceedings (OSTI)

The defining challenge of energy research in the 21st century is the development and deployment of technologies for large-scale reconfiguration of global energy infrastructure. Modern society is built upon a concentrated yet finite reservoir of diverse hydrocarbons formed through the photosynthetic transformation of several hundred million years of solar energy. In human history, the fossil energy era will be short lived and never repeated. Although the timing of peak oil is extensively debated, it is an eventuality. It is, therefore, imperative that projections for both when it will occur and the degree to which supply will fall short of demand be taken into serious consideration, especially in the sectors of energy technology development, political and economic decision making, and societal energy usage. The requirement for renewable energy systems is no longer a point for discussion, and swift advances on many fronts are vital to counteract current and impending crises in both energy and the environment.

Work, Victoria H.; Beliaev, Alex S.; Konopka, Allan; Posewitz, Matthew C.

2012-03-01T23:59:59.000Z

159

Method and apparatus for synthesizing hydrocarbons  

DOE Patents (OSTI)

A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

1985-04-16T23:59:59.000Z

160

Preignition oxidation characteristics of hydrocarbon fuels  

SciTech Connect

Experimental results obtained from a static reactor are presented for the oxidation of a variety of fuels. Pressure and temperature histories of the reacting fuel/oxidizer mixtures were obtained. Measurements of the stable reaction intermediate and product species were made using gas chromatographic analysis. One aspect of this work involved detailed studies of the oxidation chemistry of relatively low molecular weight aliphatic hydrocarbons: propane, propene, and n-butane. The oxidation chemistry of these fuels was examined at temperatures in the range 550-750 K, equivalence ratios ranging from 0.8 to 4.0 and at subatmospheric pressures. The main characteristics and features of the oxidation mechanisms were determined for each fuel in each temperature regime. The experimental results from propene and propane were used to develop a low and intermediate temperature kinetic mechanism for these fuels based on a low temperature acetaldehyde mechanism of Kaiser et al. and a high temperature propene/propane mechanism of Westbrook and Pitz. General preignition characteristics of higher molecular weight hydrocarbons and binary mixtures of these fuels were also studied. The low temperature/cool flame ignition characteristics of dodecane were investigated at temperatures in the range 523-623 K, equivalence s ranging from 0.8 to 1.0 and at subatmospheric pressures. The preignition characteristics of binary mixtures of dodecane and the aromatic component tetralin were examined. The addition of the tetralin had the overall effect of decreasing the ignition tendency of the mixture, although this effect was nonlinear with respect to the amount of tetralin added.

Wilk, R.D.

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Source profiles for nonmethane organic compounds in the atmosphere of Cairo, Egypt.  

Science Conference Proceedings (OSTI)

Profiles of the sources of nonmethane organic compounds (NMOCs) were developed for emissions from vehicles, petroleum fuels (gasoline, liquefied petroleum gas (LPG), and natural gas), a petroleum refinery, a smelter, and a cast iron factory in Cairo, Egypt. More than 100 hydrocarbons and oxygenated hydrocarbons were tentatively identified and quantified. Gasoline-vapor and whole-gasoline profiles could be distinguished from the other profiles by high concentrations of the C{sub 5} and C{sub 6} saturated hydrocarbons. The vehicle emission profile was similar to the whole-gasoline profile, with the exception of the unsaturated and aromatic hydrocarbons, which were present at higher concentrations in the vehicle emission profile. High levels of the C{sub 2}-C{sub 4} saturated hydrocarbons, particularly n-butane, were characteristic features of the petroleum refinery emissions. The smelter and cast iron factory emissions were similar to the refinery emissions; however, the levels of benzene and toluene were greater in the former two sources. The LPG and natural gas emissions contained high concentrations of n-butane and ethane, respectively. The NMOC source profiles for Cairo were distinctly different from profiles for U.S. sources, indicating that NMOC source profiles are sensitive to the particular composition of petroleum fuels that are used in a location.

Doskey, P. V.; Fukui, Y.; Sultan, M.; Maghraby, A. A.; Taher, A.; Environmental Research; Cairo Univ.

1999-07-01T23:59:59.000Z

162

Pyrolysis of Sunnyside (Utah) tar sand: Characterization of volatile compound evolution  

DOE Green Energy (OSTI)

Sunnyside (Utah) tar sand was subjected to programmed temperature pyrolysis and the volatile products were detected by tandem on-line mass spectrometry (MS/MS) in real time analyses. A heating rate of 4/degree/C/min from room temperature to 900/degree/C was employed. Evolution of hydrogen, light hydrocarbons, nitrogen-, sulfur- and oxygen-containing compounds was monitored by MS or MS/MS detection. Evolution of volatile organic compounds occurred in two regimes: 1) low temperature (maximum evolution at 150 to 175/degree C), corresponding to entrained organics, and 2) high temperature (maximum evolution at 440 to 460/degreeC), corresponding to cracking of large organic components. Pyrolysis yields were dominated by the evolution of light hydrocarbons. Alkanes and alkenes of two carbons and higher had temperatures of maximum evolution at approximately 440/degree/C, and methane at approximately 474/degree/C. Aromatic hydrocarbons had temperatures of maximum evolution slightly higher, at approximately 450/degree/C. In general, H/sub2/, CO, and CO/sub2/ exhibited evolution associated with hydrocarbon cracking reactions, and high temperature evolution associated with mineral decomposition, the water-gas shift reaction, and gasification reactions. Compared to other domestic tar sands, the gas evolution relected more mineral decomposition character for Sunnyside tar sand. 26 refs., 6 figs., 3 tabs.

Reynolds, J.G.; Crawford, R.W.

1988-06-01T23:59:59.000Z

163

8-fluoropurine compounds  

DOE Patents (OSTI)

An efficient, regiocontrolled approach to the synthesis of 8-fluoropurines by direct fluorination of purines with dilute elemental fluorine, or acetyl hypofluorite, is provided. In a preferred embodiment, a purine compound is dissolved in a polar solvent and reacted with a dilute mixture of F.sub.2 in He or other inert gas.

Barrio, Jorge R. (Agoura Hills, CA); Satyamurthy, Nagichettiar (Los Angeles, CA); Namavari, Mohammad (Los Angeles, CA); Phelps, Michael E. (Encino, CA)

2001-01-01T23:59:59.000Z

164

Compound semiconductor MOSFETs  

Science Conference Proceedings (OSTI)

Enhancement mode, high electron mobility MOSFET devices have been fabricated using an oxide high-@k gate dielectric stack developed using molecular beam epitaxy. A template layer of Ga"2O"3, initially deposited on the surface of the III-V device unpins ... Keywords: Compound semiconductors, GaAs gate dielectric, III-V MOSFETs

R. Droopad; K. Rajagopalan; J. Abrokwah; P. Zurcher; M. Passlack

2007-09-01T23:59:59.000Z

165

A compound parabolic concentrator  

SciTech Connect

A compound parabolic concentrator (CPC) for solar energy applications is presented in this work. A prototype was built and its thermal performance was determined. Operating temperatures of the order of 150 /sup 0/C with a reasonable efficiency can be attained by means of a fixed CPC.

Manrique, J.A.

1984-05-01T23:59:59.000Z

166

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

167

Thermal conversion of oil shale into recoverable hydrocarbons  

SciTech Connect

The production of hydrocarbons is accomplished by pyrolysis of oil shale with controlled removal of the resulting layer of spent oil-shale residue. A procedure is described for the in situ thermal conversion of oil shale wherein fluidized abrasive particles are employed to foster improved hydrocarbon production, in amount and kind, by a controlled partial removal of the layer of spent oil shale which results from application of flowing fluids to heat exposed surfaces of the oil shale to release hydrocarbons. (5 claims)

Slusser, M.L.; Bramhall, W.E.

1969-09-23T23:59:59.000Z

168

Analysis of the behavior of ternary hydrocarbon mixture as substitutes of the CFC-12  

Science Conference Proceedings (OSTI)

Hydrocarbons are stratospheric ozone friendly and have good heat transfer properties. The use of hydrocarbons (HCs) or their blend as refrigerant is extending in these days. This paper deals with the search of the best ternary hydrocarbons mixture of ... Keywords: CFC-12, LB-12, cub, hydrocarbon, ozone, refrigerant, ternary mixture

Rafael Quintero Ricardo

2007-05-01T23:59:59.000Z

169

Hydrogen in compound semiconductors  

DOE Green Energy (OSTI)

Progress in the understanding of hydrogen and its interactions in III/V and II/VI compound semiconductors is reviewed. Donor, acceptor and deep level passivation is well established in III/V compounds based on electrical measurements and on spectroscopic studies. The hydrogen donor levels in GaAs and GaP are estimated to lie near E{sub v}+0.5 eV and E{sub v}+0.3 eV, respectively. Arsenic acceptors have been passivated by hydrogen in CdTe and the very first nitrogen-hydrogen local vibrational model spectra in ZnSe have been reported. This long awaited result may lead to an explanation for the poor activation of nitrogen acceptors in ZnSe grown by techniques which involve high concentrations of hydrogen.

Haller, E.E.

1993-05-01T23:59:59.000Z

170

Injection Molding Compounds  

Science Conference Proceedings (OSTI)

Table 5   Common thermoplastic and thermoset molding compounds...(r) (s) (t) Phenolic Distributor caps, plastic ash trays (a) (b) (g) (h) (i) (j) (k) (l) (m) (n) (o) (q) (r) (s) (t) Urethane Automotive body panels, bumpers (a) (d) (e) (g) (i) (l) (m) (o) (q) (r) (t) Vinyl ester Composite car/truck springs, wheels (b) (d) (e) (g) (i) (j) (k) (l) (m) (n) (o) (p)...

171

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

storage of natural gas, liquid hydrocarbons, and carbon storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) < Back Eligibility Commercial Construction Industrial Investor-Owned Utility Municipal/Public Utility Utility Program Info State Louisiana Program Type Environmental Regulations Siting and Permitting The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the storage of natural gas and prior to the exercise of eminent domain by any person, firm, or corporation having such right under laws of the state of Louisiana, the commissioner, shall have found all of the following:

172

Process for converting light alkanes to higher hydrocarbons  

DOE Patents (OSTI)

A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.

Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA)

1988-01-01T23:59:59.000Z

173

Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis  

SciTech Connect

Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

Ekechukwu, A.A.

2002-05-10T23:59:59.000Z

174

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network (OSTI)

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

175

Trend Analysis for Atmospheric Hydrocarbon Partitioning Using Continuous Thermodynamics  

Science Conference Proceedings (OSTI)

The partitioning of atmospheric hydrocarbons into vapor and condensed phases when the species count is large is considered using the formalism of continuous thermodynamics. The vapor saturation pressures and condensate species distribution are ...

K. Harstad

2005-08-01T23:59:59.000Z

176

Biodegradation and phytoremediation of polycyclic aromatic hydrocarbons using mushroom compost.  

E-Print Network (OSTI)

??Soils contaminated with Polycyclic Aromatic Hydrocarbons (PAHs) are commonly found in petroleum, gas-work and wood-impregnation sites. Interest in the biodegradation and environmental fate of PAHs… (more)

Kodjo-Wayo, Lina Korkor

2006-01-01T23:59:59.000Z

177

Assessment of plant-derived hydrocarbons. Final report  

DOE Green Energy (OSTI)

A number of hydrocarbon producing plants are evaluated as possible sources of rubber, liquid fuels, and industrial lubricants. The plants considered are Euphorbia lathyris or gopher plant, milkweeds, guayule, rabbit brush, jojoba, and meadow foam. (ACR)

McFadden, K.; Nelson, S.H.

1981-09-30T23:59:59.000Z

178

Computer program for determining the thermodynamic properties of light hydrocarbons  

DOE Green Energy (OSTI)

This program was written to be used as a subroutine. The program determines the thermodynamics of light hydrocarbons. The following light hydrocarbons can be analyzed: butane, ethane, ethylene, heptane, hexane, isobutane, isopentane, methane, octane, pentane, propane and propylene. The subroutine can evaluate a thermodynamic state for the light hydrocarbons given any of the following pairs of state quantities: pressure and quality, pressure and enthalpy, pressure and entropy, temperature and pressure, temperature and quality and temperature and specific volume. These six pairs of knowns allow the user to analyze any thermodynamic cycle utilizing a light hydrocarbon as the working fluid. The Starling--Benedict--Webb--Rubin equation of state was used. A brief description, flowchart, listing and required equations for each subroutine are included.

Riemer, D.H.; Jacobs, H.R.; Boehm, R.F.; Cook, D.S.

1976-01-01T23:59:59.000Z

179

Computer program for determining the thermodynamic properties of light hydrocarbons  

DOE Green Energy (OSTI)

This program was written to be used as a subroutine. The program determines the thermodynamics of light hydrocarbons. The following light hydrocarbons can be analyzed: butane, ethane, ethylene, heptane, hexane, isobutane, isopentane, methane, octane, pentane, propane and propylene. The subroutine can evaluate a thermodynamic state for the light hydrocarbons given any of the following pairs of state quantities: pressure and quality, pressure and enthalpy, pressure and entropy, temperature and pressure, temperature and quality and temperature and specific volume. These six pairs of knowns allow the user to analyze any thermodynamic cycle utilizing a light hydrocarbon as the working fluid. The Starling-Benedict-Webb-Rubin equation of state was used. This report contains a brief description, flowchart, listing and required equations for each subroutine.

Riemer, D.H.; Jacobs, H.R.; Boehm, R.F.; Cook, D.S.

1976-07-01T23:59:59.000Z

180

Conversion of Pentose-Derived Furans into Hydrocarbon Fuels  

Science Conference Proceedings (OSTI)

We are interested in the conversion of biomass-derived hemicellulose into hydrocarbon molecules that can be used in the formulation of 'drop-in' fuels such as gasoline (C5-12), diesel (C10-20) and jet fuel (C9-16). Our focus lies on the use of furfuryl alcohol as a starting material since that is already produced commercially from hemicellulose-derived pentoses. The steps required to convert the latter into hydrocarbons are 1) oligomerization of furfuryl alcohol to form dimers (C10) and trimers (C15), and 2) hydrotreatment of the dimers and trimers to produce a mixture of linear hydrocarbons with carbon chain lengths in the range of diesel and jet fuels. However, furfuryl alcohol readily polymerizes to form resins in the presence of an acid catalyst, and the exothermic oligomerization must be carried out under reaction control. This presentation will discuss our progress in the development of this sugar-to-hydrocarbon pathway.

Moens, L.; Johnson, D. K.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

Biddy, M.; Jones, S.

2013-03-01T23:59:59.000Z

182

Hydrocarbon-enhanced particulate filter regeneration via microwave ignition  

DOE Patents (OSTI)

A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

2010-02-02T23:59:59.000Z

183

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents (OSTI)

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

184

Method for producing hydrocarbon fuels from heavy polynuclear hydrocarbons by use of molten metal halide catalyst  

DOE Patents (OSTI)

In a process for hydrocracking heavy polynuclear carbonaceous feedstocks to produce lighter hydrocarbon fuels by contacting the heavy feedstocks with hydrogen in the presence of a molten metal halide catalyst, thereafter separating at least a substantial portion of the carbonaceous material associated with the reaction mixture from the spent molten metal halide and thereafter regenerating the metal halide catalyst, an improvement comprising contacting the spent molten metal halide catalyst after removal of a major portion of the carbonaceous material therefrom with an additional quantity of hydrogen is disclosed.

Gorin, Everett (San Rafael, CA)

1979-01-01T23:59:59.000Z

185

Catalytic partial oxidation reforming of hydrocarbon fuels.  

DOE Green Energy (OSTI)

The polymer electrolyte fuel cell (PEFC) is the primary candidate as the power source for light-duty transportation systems. On-board conversion of fuels (reforming) to supply the required hydrogen has the potential to provide the driving range that is typical of today's automobiles. Petroleum-derived fuels, gasoline or some distillate similar to it, are attractive because of their existing production, distribution, and retailing infrastructure. The fuel may be either petroleum-derived or other alternative fuels such as methanol, ethanol, natural gas, etc. [1]. The ability to use a variety of fuels is also attractive for stationary distributed power generation [2], such as in buildings, or for portable power in remote locations. Argonne National Laboratory has developed a catalytic reactor based on partial oxidation reforming that is suitable for use in light-duty vehicles powered by fuel cells. The reactor has shown the ability to convert a wide variety of fuels to a hydrogen-rich gas at less than 800 C, temperatures that are several hundreds of degrees lower than alternative noncatalytic processes. The fuel may be methanol, ethanol, natural gas, or petroleum-derived fuels that are blends of various hydrocarbons such as paraffins, olefins, aromatics, etc., as in gasoline. This paper will discuss the results obtained from a bench-scale (3-kWe) reactor., where the reforming of gasoline and natural gas generated a product gas that contained 38% and 42% hydrogen on a dry basis at the reformer exit, respectively.

Ahmed, S.

1998-09-21T23:59:59.000Z

186

Fundamental studies in production of C[sub 2]-C[sub 4] hydrocarbons from coal  

DOE Green Energy (OSTI)

The following conclusions can be drawn from the result obtained in this kinetic study of single stage coal gasification to hydrocarbon (HC) gases high in C[sub 2]-C[sub 4] hydrocarbons. It was observed that the direct conversion of coal to HC gases involves two steps. The first step is thermal cleavage of the coal structure to produce liquids with small amounts of gases and coke. The second step is conversion of liquids to gases. Coal to liquids occurs very rapidly and was completed within 10 minutes. Liquids to gases is the rate-determining step of the overall process. The conversion of liquids to gases was observed to follow first order kinetics. The first order kinetics treatment of the data by isothermal approximation gave an apparent activation energy of approximately 23 kcal/mol. The first order kinetics treatment of the data by a more rigorous non-isothermal method gave an activation energy of 26 kcal/mol. The quantity of HC gases produced directly from coal reached a constant value of about l0% of the dmmf coal at a reaction time of 10 miutes. Most of the HC gases were produced from the liquids. The study of model compounds shows that conversion of liquids to HC gases.proceeds through a carbonium ion mechanism, and this accounts for the production of C[sub 2]-C[sub 4] gases. Liquid to gases occurs by a catalytic hydrocracking reaction.

Wiser, W.H.; Oblad, A.G.

1993-03-01T23:59:59.000Z

187

Formation of hydrocarbons from acid-Clay suspensions by gamma irradiation  

Science Conference Proceedings (OSTI)

The adsorption of certain organic compounds by clays gives rise to the transformation of the adsorbate through the action of the clays. This phenomenon can be enhanced using ionizing radiation. In this context, these kinds of reactions play an important role in many natural and industrial processes. For example, in oil and gas exploration, the source and trap of petroleum hydrocarbons is frequently clay-rich rocks. Clay-water-based muds are also seen as environmentally friendly alternatives to toxic oil-based fluids. The principal processes that occur in sediments are usually held to be of bacterial action and thermal transformation, which may include thermally induced catalytic alteration of the organic debris. On the other hand, radioactive materials are widely distributed throughout Earth. They were more abundant in the past, but are present in petroleum reservoirs. Their presence induced radioactive bombardment, which may have altered these sediments. This important subject has not been extensively studied. The aim of this work is to study the behavior of fatty acids-like behenic acid-and dicarboxylic acids-like fumaric acid-as model compounds, which are adsorbed in a clay mineral (Na-montmorillonite) and exposed to gamma radiation. The results show that the radiation-induced decomposition of the clay-acid system goes along a definitive path (oxidation), rather than following several modes of simultaneous decomposition, as happens in radiolysis without clay or by heating the system. The main radiolytic products for fatty acids are their corresponding hydrocarbons, with one C-atom less than the original acid.

Cruz-Castaneda, J.; Negron-Mendoza, A.; Ramos-Bernal, S. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, UNAM. Cd. Universitaria, A. P. 70-543, 04510 Mexico (Mexico)

2013-07-03T23:59:59.000Z

188

Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures  

E-Print Network (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered to be the primary mechanism of PAH removal from the environment. Biodegradation kinetics of individual PAHs by pure and mixed cultures have been reported by several researchers. However, contaminated sites commonly have complex mixtures of PAHs whose individual biodegradability may be altered in mixtures. Biodegradation kinetics for fluorene, naphthalene, 1,5-dimethylnaphthalene and 1- methylfluorene were evaluated in sole substrate systems, binary and ternary systems using Sphingomonas paucimobilis EPA505. The Monod model was fitted to the data from the sole substrate experiments to yield biokinetic parameters, (qmax and Ks). The first order rate constants (qmax/Ks) for fluorene, naphthalene and 1,5- dimethylnaphthalene were comparable, although statistically different. However, affinity constants for the three compounds were not comparable. Binary and ternary experiments indicated that the presence of another PAH retards the biodegradation of the co-occurring PAH. Antagonistic interactions between substrates were evident in the form of competitive inhibition, demonstrated mathematically by the Monod multisubstrate model. This model appropriately predicted the biodegradation kinetics in mixtures using the sole substrate parameters, validating the hypothesis of common enzyme systems. Competitive inhibition became pronounced under conditions of: Ks1 > Ks1 and S1 >> S. Experiments with equitable concentrations of substrates demonstrated the effect of concentration on competitive inhibition. Ternary experiments with naphthalene, 1,5-dimethylnapthalene and 1-methylfluorene revealed preferential degradation, where depletion of naphthalene and 1,5-dimethylnapthalene proceeded only after the complete removal of 1-methylfluorene. The substrate interactions observed in binary and ternary mixtures require a multisubstrate model to account for simultaneous degradation of substrates. However, developing models that account for sequential degradation may be useful in scenarios where PAHs may not be competitive substrates. These mixture results prove that substrate interactions must be considered in designing effective bioremediation strategies and that sole substrate performance is limited in predicting biodegradation kinetics of complex mixtures.

Desai, Anuradha M.

2005-12-01T23:59:59.000Z

189

Hydrocarbons associated with brines from geopressured wells  

DOE Green Energy (OSTI)

Efforts to determine the concentration of the cryocondensates in fluids of the various USDOE Geopressured wells a function of production volume. The wells are visited monthly as they are operating and samples are reported taken cryogenically during each visit. A gas scrubbing system continuously sample the gas streams of the wells in the intergas scrubbing system continuously sample the gas streams of the wells in the intervals between visit. Results obtained are to correlated the production of the collected compounds with reservoir and well production characteristics.

Not Available

1991-10-15T23:59:59.000Z

190

Review of current research on hydrocarbon production by plants  

DOE Green Energy (OSTI)

This review assesses the status of research and development in the area of plants that produce hydrocarbons as a possible replacement for traditional fossil fuels. The information is meant to be used as a basis for determining the scope of a possible R and D program by DOE/FFB. Except in the case of guayule (Parthenium argentatum Gray), research on hydrocarbon species generally has not advanced beyond preliminary screening, extraction, and growth studies. Virtually no field studies have been initiated; hydrocarbon component extraction, separation, identification, and characterization have been only timidly approached; the biochemistry of hydrocarbon formation remains virtually untouched; and potential market analysis has been based on insufficient data. Research interest is increasing in this area, however. Industrial interest understandably centers about guayule prospects and is supplemented by NSF and DOE research funds. Additional support for other research topics has been supplied by DOE and USDA and by certain university systems. Due to the infant state of technology in this area of energy research, it is not possible to predict or satisfactorily assess at this time the potential contribution that plant hydrocarbons might make toward decreasing the nation's dependence upon petroleum. However, the general impression received from experts interviewed during this review was that the major thrust of research should be directed toward the manufacture of petrochemical substitutes rather than fuel production.

Benedict, H. M.; Inman, B.

1979-01-01T23:59:59.000Z

191

Methane-derived hydrocarbons produced under upper-mantle conditions  

SciTech Connect

There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.; (CIW); (RITS)

2009-08-13T23:59:59.000Z

192

Marcellus natural gas pipeline projects to primarily ...  

U.S. Energy Information Administration (EIA)

Includes hydropower, solar, wind, geothermal, biomass and ethanol. Nuclear & Uranium. Uranium fuel, nuclear reactors, generation, spent fuel. ... ...

193

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

Science Conference Proceedings (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

Biddy, Mary J.; Jones, Susanne B.

2013-03-31T23:59:59.000Z

194

Method and apparatus for producing oxygenates from hydrocarbons  

DOE Patents (OSTI)

A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.

Kong, Peter C. (Idaho Falls, ID); Lessing, Paul A. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

195

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents (OSTI)

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P{sub 450} reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates. 1 fig. 2 tab.

Shelnutt, J.A.

1989-09-26T23:59:59.000Z

196

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents (OSTI)

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

Shelnutt, John A. (Tijeras, NM)

1990-01-01T23:59:59.000Z

197

Sandia National Labs: PCNSC: Research: Compound Semiconductor...  

NLE Websites -- All DOE Office Websites (Extended Search)

Compound Semiconductor Science and Technology Thrust The Physical, Chemical, and Nano Sciences Center's vision for Compound Semiconductors is to develop the science of compound...

198

Hydrocarbons associated with brines from geopressured wells  

DOE Green Energy (OSTI)

The purpose of this research is to determine the concentration of the cryocondensates in fluids of the various USDOE Geopressured wells as a function of production volume, to correlate the production of these compounds with reservoir and well production characteristics, to precisely measure solubilities of cryocondensates components in water and sodium chloride solutions (brines) as a function of ionic strength and temperature and the component's distribution coefficients between these solutions and oil, to develop models of the reservoir which are consistent with the data obtained, to monitor the wells for the production of aliphatic oils and relate any such production with the data obtained, and to develop a harsh environment pH probe for use in well brines. Results are summarized.

Not Available

1991-01-15T23:59:59.000Z

199

Reclamation and reuse of Freon in total petroleum hydrocarbon analyses  

Science Conference Proceedings (OSTI)

At the Savannah River Technology Center (SRTC), we have successfully demonstrated the use of a solvent recycling system to reclaim spent Freon solvent in total petroleum hydrocarbon (TPH) analyses of radioactive samples. A wide variety of sample types including ground water, organics, laboratory waste, process control, sludge, soils, and others are received by our lab for total petroleum hydrocarbon analysis. This paper demonstrates the successful use of a commercially available carbon bed recycle system which we modified to enable the recovery of 95-98 percent of the radioactive contaminated Freon. This system has been used successfully in our lab for the past three years.

Ekechukwu, A.A.; Young, J.E.

1997-12-31T23:59:59.000Z

200

Method and apparatus for synthesizing various short chain hydrocarbons  

DOE Patents (OSTI)

A method and apparatus, including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO{sub 2} aerogels doped with photochemically active uranyl ions are fluidized in a fluidized-bed reactor having a transparent window, by hydrogen and CO, C{sub 2}H{sub 4} or C{sub 2}H{sub 6} gas mixtures, and exposed to radiation from a light source external to the reactor, to produce the short chain hydrocarbons. 1 fig., 1 tab.

Colmenares, C.

1989-05-05T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents (OSTI)

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

Blandford, J.W.

1995-01-17T23:59:59.000Z

202

Method for recovering light hydrocarbons from coal agglomerates  

DOE Patents (OSTI)

A method and apparatus for removing light hydrocarbons, such as heptane, from coal agglomerates includes an enclosed chamber having a substantially horizontal perforate surface therein. The coal agglomerates are introduced into a water bath within the chamber. The agglomerates are advanced over the surface while steam is substantially continuously introduced through the surface into the water bath. Steam heats the water and causes volatilization of the light hydrocarbons, which may be collected from the overhead of the chamber. The resulting agglomerates may be collected at the opposite end from the surface and subjected to final draining processes prior to transportation or use.

Huettenhain, Horst (Benicia, CA); Benz, August D. (Hillsborough, CA); Getsoian, John (Ann Arbor, MI)

1991-01-01T23:59:59.000Z

203

Preliminary investigation of the nature of hydrocarbon migration and entrapment  

E-Print Network (OSTI)

Numerical simulations indicate that hydrocarbon migration and entrapment in stacked fault-bounded reservoirs are mainly affected by the following factors: charge time, faults, pressure and geological structures. The charge time for commercial hydrocarbon accumulation is much longer in oil-water systems than in oil-gas-water systems. Faults are classified into charging faults and 'back doors' faults other than charging faults in stacked fault-bounded reservoirs. The lower the displacement pressure of a fault, the higher its updip oil transportation ability. The downdip oil transportation ability of a fault is usually low and cannot cause commercial downdip oil accumulation. Back doors affect both hydrocarbon percent charge and hydrocarbon migration pathways. Updip back doors improve updip oil charge. The lower the displacement pressure of an updip back door, the more efficient the updip oil charge before 3,000 years. Back doors whose displacement pressure is equal to or higher than 28.76 psi are effective in sealing faults in oil-water systems. On the contrary, only sealing faults result in commercial gas accumulations in stacked fault-compartmentalized reservoirs. Otherwise gas is found over oil. Downdip back doors generally have few effects on downdip hydrocarbon charge. Geopressure enhances the updip oil transportation of a fault and improves the positive effects of updip back doors during updip oil charge. Geopressure and updip back doors result in more efficient updip oil charge. A physical barrier is not necessarily a barrier to oil migration with the aid of geopressure and updip back doors. The chance for hydrocarbon charge into reservoirs along growth faults is not equal. Any one of the above controlling factors can change the patterns of hydrocarbon charge and distribution in such complex geological structures. Generally, lower reservoirs and updip reservoirs are favored. Reservoirs along low-permeability charging faults may be bypassed. Gas can only charge the updip reservoirs. Both updip and downdip back doors can facilitate oil penetrating a barrier fault to charge reservoirs offset by the barrier fault. Interreservoir migration among stacked fault-compartmentalized reservoirs is an important mechanism for hydrocarbon accumulation and trap identification. The interreservoir migration is a very slow process, even though the displacement pressures of bounding faults may be very low.

Bai, Jianyong

2005-05-01T23:59:59.000Z

204

Process of producing liquid hydrocarbon fuels from biomass  

DOE Patents (OSTI)

A continuous thermochemical indirect liquefaction process to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C.sub.7 -C.sub.17 paraffinic hydrocarbons having cetane indices of 50+.

Kuester, James L. (Scottsdale, AZ)

1987-07-07T23:59:59.000Z

205

Process of producing liquid hydrocarbon fuels from biomass  

DOE Patents (OSTI)

A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.

Kuester, J.L.

1987-07-07T23:59:59.000Z

206

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents (OSTI)

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1995-01-01T23:59:59.000Z

207

Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars  

DOE Patents (OSTI)

Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as methanol, glycerol, sugars (e.g. glucose and xylose), or sugar alcohols (e.g. sorbitol). The method takes place in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2005-11-15T23:59:59.000Z

208

High-Value Fluorine Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Compounds Baseline plans call for production of anhydrous or aqueous Hydrogen Fluoride (HF) from the DU hexafluoride conversion plant and subsequent recycle of these...

209

Variability of Gas Composition and Flux Intensity in Natural Marine Hydrocarbon Seeps  

E-Print Network (OSTI)

Energy Development and Technology 008 "Variability of gas composition and flux intensity in natural marine hydrocarbon seeps" Jordan

Clark, J F; Schwager, Katherine; Washburn, Libe

2005-01-01T23:59:59.000Z

210

Hydrocarbon compositions of high elongational viscosity and process for making the same  

SciTech Connect

A hydrocarbon composition is described consisting essentially of a hydrocarbon liquid and an ionic-association or coordination-complex polymer in an amount sufficient to increase and maintain the elongational viscosity of the composition at a level greater than that of the hydrocarbon alone. The polymer is capable of dissociation upon application of the high shear regime to which the hydrocarbon is subjected, and reassociation upon withdrawal of the high shear.

Hamil, H.F.; Weatherford, W.D. Jr.; Fodor, G.E.

1988-03-15T23:59:59.000Z

211

U.S. Product Supplied of Other Hydrocarbons/Oxygenates (Thousand ...  

U.S. Energy Information Administration (EIA)

Product Supplied for Hydrogen/Oxygenates/Renewables/Other Hydrocarbons ; U.S. Product Supplied for Crude Oil and Petroleum Products ...

212

U.S. Exports of Other Hydrocarbons/Oxygenates (Thousand Barrels ...  

U.S. Energy Information Administration (EIA)

Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Supply and Disposition; U.S. Exports of Crude Oil and Petroleum Products ...

213

Recovery of normally gaseous hydrocarbons from net excess hydrogen in a catalytic reforming process  

Science Conference Proceedings (OSTI)

A process is disclosed for the catalytic reforming of hydrocarbons in the presence of hydrogen, preferably to produce high quality gasoline boiling range products. An improved recovery of normally gaseous hydrocarbons from the net excess hydrogen is realized by chilling and contacting said hydrogen with a normally liquid hydrocarbon stream in a plural stage absorption zone at an elevated pressure.

Scheifele, C.A.

1982-06-08T23:59:59.000Z

214

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network (OSTI)

, preferential oxidation) and gas separation stages required by conventional technologies (e.g., steam reforming and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive-situ generation of catalytically active carbon species produced by co-decomposition of methane and unsaturated and

215

METHOD OF REDUCING PLUTONIUM COMPOUNDS  

DOE Patents (OSTI)

A method is described for reducing plutonium compounds in aqueous solution from a higher to a lower valence state. This reduction of valence is achieved by treating the aqueous solution of higher valence plutonium compounds with hydrogen in contact with an activated platinum catalyst.

Johns, I.B.

1958-06-01T23:59:59.000Z

216

Devices for collecting chemical compounds  

SciTech Connect

A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

Scott, Jill R; Groenewold, Gary S

2013-12-24T23:59:59.000Z

217

Reclamation and reuse of freon in total petroleum hydrocarbon analyses  

SciTech Connect

ADS is using a commercially available solvent reclamation system to recycle 95-97 percent of the Freon used in total petroleum hydrocarbon analyses. ADS has further developed the commercially available solvent reclamation system to accommodate radioactive contaminated Freon. This report establishes the following: validity of the method; success of recycling; and effect of radionuclides in recycling radioactive contaminated Freon. The standard analysis method for determining total petroleum hydrocarbons (commonly known as oil and grease determination) involves solvent extraction of the hydrocarbons using Freon followed by quantitation using infrared detection. This has been the method of choice because it is simple, rugged, inexpensive, and applicable to both solid and liquid samples and to radioactive samples. Due to its deleterious effect on the ozone layer, the use of Freon and other chloro-fluorocarbons (CFCs) has been greatly restricted. Freon has become very expensive (800$/liter) and will soon be unavailable entirely. Several methods have been proposed to replace the Freon extraction method. These methods include solid-phase extraction, solvent extraction, and supercritical fluid extraction all of which use gravimetric determination or infrared analysis of the extracted hydrocarbons. These methods are not as precise or as sensitive as the Freon extraction method, and a larger amount of sample is therefore required due to the decreased sensitivity. The solid phase extraction method cannot accommodate solid samples. Supercritical fluid extraction requires expensive instrumentation. ADS opted to keep the existing Freon method and recycle the solvent. An inexpensive solvent reclamation system was procured to reclaim the spent Freon. This reclaimer removes hydrocarbons from the Freon solvent by passage through an activated carbon bed.

Ekechukwu, A.A.; Peterson, S.F.

1996-04-01T23:59:59.000Z

218

Photocatalytic degradation of oil industry hydrocarbons models at laboratory and at pilot-plant scale  

Science Conference Proceedings (OSTI)

Photodegradation/mineralization (TiO{sub 2}/UV Light) of the hydrocarbons: p-nitrophenol (PNP), naphthalene (NP) and dibenzothiophene (DBT) at three different reactors: batch bench reactor (BBR), tubular bench reactor (TBR) and tubular pilot-plant (TPP) were kinetically monitored at pH = 3, 6 and 10, and the results compared using normalized UV light exposition times. The results fit the Langmuir-Hinshelwood (LH) model; therefore, LH adsorption equilibrium constants (K) and apparent rate constants (k) are reported as well as the apparent pseudo-first-order rate constants, k{sub obs}{sup '} = kK/(1 + Kc{sub r}). The batch bench reactor is the most selective reactor toward compound and pH changes in which the reactivity order is: NP > DBT > PNP, however, the catalyst adsorption (K) order is: DBT > NP > PNP at the three pH used but NP has the highest k values. The tubular pilot-plant (TPP) is the most efficient of the three reactors tested. Compound and pH photodegradation/mineralization selectivity is partially lost at the pilot plant where DBT and NP reaches ca. 90% mineralization at the pH used, meanwhile, PNP reaches only 40%. The real time, in which these mineralization occur are: 180 min for PNP and 60 min for NP and DBT. The mineralization results at the TPP indicate that for the three compounds, the rate limiting step is the same as the degradation one. So that, there is not any stable intermediate that may accumulate during the photocatalytic treatment. (author)

Vargas, Ronald; Nunez, Oswaldo [Laboratorio de Fisicoquimica Organica y Quimica Ambiental, Departamento de Procesos y Sistemas, Universidad Simon Bolivar, Apartado Postal 89000, Caracas (Venezuela)

2010-02-15T23:59:59.000Z

219

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

A polishing compound for plastic surfaces. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS.TM., LEXAN.TM., LUCITE.TM., polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, Michael S. (New Ellenton, SC)

1995-01-01T23:59:59.000Z

220

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains colloidal silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{sup TM}, LEXAN{sup TM}, LUCITE{sup TM}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds  

DOE Green Energy (OSTI)

A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt. % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450.degree. to 700.degree. C. over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C.sub.1 -C.sub.8 hydrocarbons and a reduction in H.sub.2 S over gas obtainable by pyrolyzing cola without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

Khan, M. Rashid (Morgantown, WV)

1988-01-01T23:59:59.000Z

222

Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds  

DOE Patents (OSTI)

A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450 to 700/sup 0/C over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C/sub 1/ to C/sub 8/ hydrocarbons and a reduction in H/sub 2/S over gas obtainable by pyrolyzing coal without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

Khan, M.R.

1986-04-17T23:59:59.000Z

223

The hydroxyl radical initiated oxidation of unsaturated hydrocarbons in the troposphere: a theoretical and experimental approach  

E-Print Network (OSTI)

Isoprene is the dominant non-methane organic compound emitted by vegetation into the atmosphere, with a global emission rate of ~ 500 Tg yr-1. Its oxidation serves as a major source of ground level ozone in North America during the summer months. Despite the significant impact on tropospheric chemistry, questions remain concerning the detailed oxidation mechanism. The initial step in the mechanism is the addition of OH to form four distinct isomers. The relative branching between these isomers influences the distribution of the final products. I present a comprehensive investigation into the mechanistic details of early steps in the oxidation mechanism of unsaturated hydrocarbons in the troposphere and employ theoretical and experimental techniques. To understand the detailed kinetics of the initial OH addition to unsaturated hydrocarbons, I first present a model developed for the ethylene-OH system. I present the details of a robust two-transition state model. I extend the developed two-transition state model to the case of OH addition to isoprene. Excellent agreement with observed temperature and pressure dependent rate constants affords a high confidence level in understanding of the kinetics and in the calculated branching ratio of the initial OH addition step. I then focus attention on the subsequent reactivity of the OH-isoprene adducts. Until recently, all four of the OH-isoprene adducts were supposed to have reacted with O2 via addition to form alkylperoxy radicals. Previous computational results suggest that two of the OH-isoprene adducts undergo an intramolecular cyclic isomerization followed by hydrogen abstraction by O2 to form stable carbonyl compounds. I have synthesized photolytic precursors, presenting a novel approach to probe the subsequent reactivity of individual hydroxyalkyl radicals. Initial verification of the cyclic isomerization pathway involved synthesis of the photolytic precursor corresponding to the 1,3-butadiene-OH adduct. A culmination of theoretical and experimental techniques allowed verification of the cyclic isomerization pathway. I synthesized the photolytic precursor, which provided a single isoprene-OH adduct. Employing laser photolysis/laser induced fluorescence, time-dependent multiplexed mass spectrometry, velocity map ion imaging, and theoretical techniques, we present the full characterization of the reactivity of the single isoprene-OH adduct in the presence of O2.

Tullos, Erin Elizabeth

2007-05-01T23:59:59.000Z

224

Detection of chlorinated aromatic compounds  

SciTech Connect

A method for making a composition for measuring the concentration of chloated aromatic compounds in aqueous fluids, and an optical probe for use with the method. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis.

Ekechukwu, Amy A. (Augusta, GA)

1996-01-01T23:59:59.000Z

225

COMBUSTION SOURCES OF NITROGEN COMPOUNDS  

E-Print Network (OSTI)

Rasmussen, R.A. (1976). Combustion as a source of nitrousx control for stationary combustion sources. Prog. Energy,CA, March 3-4, 1977 COMBUSTION SOURCES OF NITROGEN COMPOUNDS

Brown, Nancy J.

2011-01-01T23:59:59.000Z

226

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

This invention is comprised of a polishing compound for plastic materials. The compound includes approximately by approximately by weight 25 to 80 parts at least one petroleum distillate lubricant, 1 to 12 parts mineral spirits, 50 to 155 parts abrasive paste, and 15 to 60 parts water. Preferably, the compound includes approximately 37 to 42 parts at least one petroleum distillate lubricant, up to 8 parts mineral spirits, 95 to 110 parts abrasive paste, and 50 to 55 parts water. The proportions of the ingredients are varied in accordance with the particular application. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC), and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1991-01-01T23:59:59.000Z

227

Detection of chlorinated aromatic compounds  

DOE Patents (OSTI)

A method for making a composition for measuring the concentration of chlorinated aromatic compounds in aqueous fluids, and an optical probe for use with the method are disclosed. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis. 5 figs.

Ekechukwu, A.A.

1996-02-06T23:59:59.000Z

228

Aza compounds as anion receptors  

SciTech Connect

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of Li.sup.+ ion in alkali metal batteries.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Qing (Port Jefferson Station, NY); McBreen, James (Bellport, NY)

1998-01-06T23:59:59.000Z

229

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

Science Conference Proceedings (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Jones, Susanne B.

2013-03-31T23:59:59.000Z

230

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

2013-03-31T23:59:59.000Z

231

Plasma-induced conversion of surface-adsorbed hydrocarbons  

DOE Green Energy (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-07-01T23:59:59.000Z

232

Plasma-induced conversion of surface-adsorbed hydrocarbons  

DOE Green Energy (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-01-01T23:59:59.000Z

233

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents (OSTI)

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, Ranjani V. (Morgantown, WV)

1993-01-01T23:59:59.000Z

234

Aryl hydrocarbon mono-oxygenase activity in human lymphocytes  

SciTech Connect

Aryl hydrocarbon mono-oxygenase (AHM), an enzyme of key importance in metabolism of xenobiotic chemicals such as polynuclear aromatic hydrocarbons (PNA), is present in human lymphocytes. Studies investing the relation of activity of AHM in human lymphocytes to parameters such as disease state, PNA exposure, in vitro mitogen stimulation, etc. have been summarized in this report. Some studies have demonstrated increased AHM activity in lymphocytes from cigarette smokers (compared to nonsmokers), and in lung cancer patients when compared to appropriate control groups. These observations are confused by extreme variability in human lymphocyte AHM activities, such variability arising from factors such as genetic variation in AHM activity, variation in in vitro culture conditions which affect AHM activity, and the problematical relationship of common AHM assays to actual PNA metabolism taking place in lymphocytes. If some of the foregoing problems can be adequately addressed, lymphocyte AHM activity could hold the promise of being a useful biomarker system for human PNA exposure.

Griffin, G.D.; Schuresko, D.D.

1981-06-01T23:59:59.000Z

235

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents (OSTI)

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700 to 900{degrees}C are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025--0.4 mole and about 0.1--0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800 to 850{degrees}C with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C{sub 2} hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, R.V.

1991-05-15T23:59:59.000Z

236

Environmental Distribution of Petroleum Hydrocarbons at a Utility Service Center  

Science Conference Proceedings (OSTI)

This report presents the results of a field study at a utility service center located in western New York where a petroleum product had leaked into the subsurface over a number of years. The study was a tailored collaboration effort between the Electric Power Research Institute (EPRI) and the Niagara Mohawk Power Corporation, aimed at delineating the nature and extent of migration of the dissolved hydrocarbons. The information is of interest to many utilities as they develop and implement management prac...

1999-06-30T23:59:59.000Z

237

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents (OSTI)

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

238

Determining Polycyclic Aromatic Hydrocarbon (PAH) Background in Sediments  

Science Conference Proceedings (OSTI)

Sediment remediation challenges at former manufactured gas plant (MGP) sites include defining sediment remedial zones, establishing risk-based remedial goals for specific polycyclic aromatic hydrocarbons (PAHs), and determining background conditions in what are often highly industrialized waterways. This technical update describes the various tools and approaches developed over approximately the past decade to determine site-specific background PAH concentrations in sediments attributable to ...

2012-11-14T23:59:59.000Z

239

Irregular spacing of heat sources for treating hydrocarbon containing formations  

SciTech Connect

A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

Miller, David Scott (Katy, TX); Uwechue, Uzo Philip (Houston, TX)

2012-06-12T23:59:59.000Z

240

Conversion of ethane and of propane to higher olefin hydrocarbons  

DOE Green Energy (OSTI)

It has become apparent during the past few months that results obtained in the oxidative coupling of methane cannot be extended to ethane and propane. Good selectivities and yields for the oxydehydrogenation to olefins can be obtained but production of higher hydrocarbons is small. The present report summarizes results of experiments using zeolite based catalysts and compares these with basic oxide catalysts. The oxydehydrogenation of ethane over zeolite based catalysts (H[sup [minus plus

Heinemann, H.; Somorjai, G.A.

1992-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents (OSTI)

A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, Carl B. (Augusta, GA)

1989-01-01T23:59:59.000Z

242

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents (OSTI)

This invention pertains to a chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H{sub 2}O and CO{sub 2} under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, C.B.

1988-10-12T23:59:59.000Z

243

Challenge for Mesozoic hydrocarbon exploration in the Eastern Indonesia  

Science Conference Proceedings (OSTI)

The eastern part of Indonesia covers approximately 3 million square kilometers, 35 percent being landmass and 65 percent covered by ocean. Only three of 38 sedimentary basins are producing hydrocarbon (Salawati, Bintuni, and Seram Basins). Oil and gas have discovered in the Lariang, Bone, Timor, Banggai, Sula and Biak Basins, however the discoveries have not developed yet. Hydrocarbon systems in Northern Australia and Papua New Guinea give the major contributions to the geological idea of Pre-Tertiary section in the less explored area in the Eastern Indonesia. The Triassic-Middle Jurassic marine carbonaceous shale sequences are the main hydrocarbon source rock in the Irian Jaya and surrounding area (Buton, gula and Seram basins). The main Mesozoic reservoir are the Kembelangan Formation in the Bintuni Basin of Irian Jaya and Bobong Formation in the North Sula Region. Exploration play types in the Eastern Indonesia can be divided into five types: 1 - Peri Cratonic, 2 - Marginal Rift Graben, 3 - Thrust Fold Belt Island Arc, 4 - Early Collision and 5 -Microcontinental Block - Advanced Collision. Recent discoveries through Mesozoic section in Eastern Indonesia are: Roabiba-1 (1990) in Bintuni Basin-Irian Jaya (Kambelangan Formation); Loku- 1 (1990) in North Sula region (Pre-Tertiary sediments); Oseil-1 (1993/94) in Bula-Seram Basin (Jurassic Manusela Formation); Elang-1 (1 994); Kakaktua-1 (1994) and Laminaria-1 in North Bonaparte Basin (Upper Jurassic Sands).

Abdullah, S.; Rukmiati, M.G.; Sitompul, N. (Pertamina Exploration and Production, Jakarta (Indonesia))

1996-01-01T23:59:59.000Z

244

Method for production of hydrocarbon diluent from heavy crude oil  

Science Conference Proceedings (OSTI)

This patent describes a method of producing a hydrocarbon diluent from a heavy crude oil extracted from an underground petroleum formation via a production well. It comprises: preheating a quantity of heavy crude oil extracted from the production well to yield a heated crude oil; separating in a separator vessel by flashing the heated crude oil to produce a first vapor fraction and a first liquid fraction; thermally cracking in a cracking unit at least a portion of the first liquid fraction to produce a first liquid effluent; quenching the first liquid effluent; introducing at least a portion of the quenched fist liquid effluent into a separator; condensing the first vapor fraction; separating in a separator vessel the condensed vapor fraction to produce a liquid hydrocarbon diluent middle fraction characterized in having a boiling range between about 400{degrees}-700{degrees}F. and a gas; and, directing the liquid hydrocarbon diluent into the formation via an injection well for enhancing production of petroleum from the formation via the production well.

McCants, M.F.

1992-05-05T23:59:59.000Z

245

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents (OSTI)

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

1996-06-18T23:59:59.000Z

246

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents (OSTI)

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

1996-01-01T23:59:59.000Z

247

Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels  

DOE Green Energy (OSTI)

The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

University of Central Florida

2004-01-30T23:59:59.000Z

248

Conversion of Biomass-Derived Furans into Hydrocarbon Fuels  

Science Conference Proceedings (OSTI)

One of the most studied chemical transformations of carbohydrates is their thermocatalytic dehydration to form furans. Cellulose-derived glucose is thereby converted into 5-hydroxymethylfurfuraldehyde (5-HMF), while the hemicellulose-derived pentoses (e.g., xylose, arabinose) form furfuraldehyde. Our objective is to identify new pathways to convert furfuryl alcohol into a mixture of aliphatic hydrocarbons that can be used as drop-in fuels for diesel (C10-20) and jet fuel (C9-16) blends. Furfuryl alcohol is produced commercially through hydrogenation of furfuraldehyde that is derived from hemicellulose-derived pentoses via acid-catalyzed dehydration. The steps that we are currently pursuing to convert furfuryl alcohol into hydrocarbons are 1) oligomerization of furfuryl alcohol to form dimers (C10) and trimers (C15), and 2) hydrotreatment of the dimers and trimers to produce a mixture of linear hydrocarbons with carbon chain lengths in the range of diesel and jet fuels. This presentation will discuss our progress in the development of this pathway.

Moens, L.; Johnson, D. K.

2013-01-01T23:59:59.000Z

249

Method for purifying bidentate organophosphorus compounds  

DOE Patents (OSTI)

Bidentate organophosphorus compounds useful for extracting actinide elements from acidic nuclear waste solutions are purified of undesirable acidic impurities by contacting the compounds with ethylene glycol which preferentially extracts the impurities found in technical grade bidentate compounds.

Schulz, Wallace W. (Richland, WA)

1977-01-01T23:59:59.000Z

250

Hydrocarbon evaluation proposed southeastern New Mexico radioactive material storage site Eddy County, New Mexico. Volume I. Discussion  

SciTech Connect

The proposed radioactive waste material storage site is located in the northern portion of the Delaware Basin. No hydrocarbon production exists within the current boundaries of the ''site area'', but oil and gas are being produced from 60 wells in a 368 square-mile area around the site. These wells produce from the Delaware, Bone Springs, Wolfcamp, Strawn, Atoka and Morrow zones at a total rate of about 22,682 MCF of gas and 429 barrels of oil per day. This area is considered to be potentially rich in hydrocarbon reserves and the lack of fuller development and exploration drilling is due primarily to low gas prices, lack of sales outlets and/or pipelines and moratoriums on drilling in the potash areas. Proved producing and proved nonproducing reserves are present in two wells in the Los Medanos Field area immediately adjacent to the southwest corner of the ''site area''. In addition, proved undeveloped, probable and possible reserves exist at six potential drilling locations in the Los Medanos Field. Further, probable and possible reserves were assigned to fifteen other potential drilling locations in the northwest and south-central portions of the ''site area''. Total future economically recoverable reserves projected for these wells are 62,253,244 MCF of gas and 409,628 barrels of oil. The future net undiscounted revenue to the oil operators was determined to be $48,410,821. The discounted future net revenue is $21,216,899, discounted at 10 percent per annum. The fair market value for these projected reserves is $12,730,139, assuming a fair market factor of 0.60.

1976-09-01T23:59:59.000Z

251

Conversion of ethane and of propane to higher olefin hydrocarbons. Quarterly report, July 1--September 30, 1991  

DOE Green Energy (OSTI)

Purely thermal reactions for the conversion of ethane were carried out in an empty and in a quartz chip filled reactor over a temperature range of 300--800{degrees}C in the absence and presence of oxygen and oxygen plus water. Ethane alone shows no conversion below 600{degrees}C and some conversion to CH{sub 4} and very little C{sub 2}H{sub 4} at 700{degrees} and 800{degrees}C. Ethane and oxygen produce CO{sub 2} as the major product above 400{degrees}C. The additional presence of water does not appreciably change this picture. Converting ethane with oxygen and water over a Ca{sub 3}Ni{sub 1}K{sub 0.1} catalyst at very low space velocity gave increasing conversion with temperature, primarily CO{sub 2} production and a small amount of C{sub 3+} hydrocarbons. The CO{sub 2} production was decreased and slightly more C{sub 3} hydrocarbons were produced when the potassium concentration of the catalyst was increased. Activation energies have been calculated for the various ethane conversion reactions. It appears that the CaNiK oxide catalyst is not suited for oxidative ethane coupling at the conditions thus far investigated. The indications are that much shorter contact times are required to prevent oxidation of intermediates. Blank runs with propane and oxygen in the absence of a catalyst have shown significant reaction at temperatures as low as 400{degrees}C. 12 figs., 3 tabs.

Heinemann, H.; Somorjai, G.A.

1991-10-01T23:59:59.000Z

252

Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs  

SciTech Connect

During this last period of the ''Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs'' project (Grant/Cooperative Agreement DE-FC26-02NT15342), we finalized integration of rock physics, well log analysis, seismic processing, and forward modeling techniques. Most of the last quarter was spent combining the results from the principal investigators and come to some final conclusions about the project. Also much of the effort was directed towards technology transfer through the Direct Hydrocarbon Indicators mini-symposium at UH and through publications. As a result we have: (1) Tested a new method to directly invert reservoir properties, water saturation, Sw, and porosity from seismic AVO attributes; (2) Constrained the seismic response based on fluid and rock property correlations; (3) Reprocessed seismic data from Ursa field; (4) Compared thin layer property distributions and averaging on AVO response; (5) Related pressures and sorting effects on porosity and their influence on DHI's; (6) Examined and compared gas saturation effects for deep and shallow reservoirs; (7) Performed forward modeling using geobodies from deepwater outcrops; (8) Documented velocities for deepwater sediments; (9) Continued incorporating outcrop descriptive models in seismic forward models; (10) Held an open DHI symposium to present the final results of the project; (11) Relations between Sw, porosity, and AVO attributes; (12) Models of Complex, Layered Reservoirs; and (14) Technology transfer Several factors can contribute to limit our ability to extract accurate hydrocarbon saturations in deep water environments. Rock and fluid properties are one factor, since, for example, hydrocarbon properties will be considerably different with great depths (high pressure) when compared to shallow properties. Significant over pressure, on the other hand will make the rocks behave as if they were shallower. In addition to the physical properties, the scale and tuning will alter our hydrocarbon indicators. Gas saturated reservoirs change reflection amplitudes significantly. The goal for the final project period was to systematically combine and document these various effects for use in deep water exploration and transfer this knowledge as clearly and effectively as possible.

Michael Batzle

2006-04-30T23:59:59.000Z

253

Streamlined Approach for Environmental Restoration Plan for Corrective Action Unit 499: Hydrocarbon Spill Site, Tonopah Test Range, Nevada  

SciTech Connect

This Streamlined Approach for Environmental Restoration (SAFER) plan addresses the action necessary for the closure of Corrective Action Unit (CAU) 499, Hydrocarbon Spill Site, Tonopah Test Range (TTR). This CAU is currently listed in Appendix III of the Federal Facility Agreement and Consent Order (FFACO) (FFACO, 1996). CAU 499 is located on the TTR and consists of the following single Corrective Action Site (CAS) (Figure 1): CAS RG-25-001-RD24 - Radar 24 Diesel Spill Site is a diesel fuel release site that is assumed to have been cased by numerous small historical over fillings, spills and leaks from an above-ground storage tank (AST) over a period of 36 years. The tank was located on the north side of Building 24-50 on the TTR approximately 4.0 kilometers (2.5 miles) southwest of the Area 3 Compound at the end of the Avenue 24.

T. M. Fitzmaurice

2001-09-01T23:59:59.000Z

254

Uranium Compounds and Other Natural Radioactivities  

NLE Websites -- All DOE Office Websites (Extended Search)

X-ray Science Division XSD Groups Industry Argonne Home Advanced Photon Source Uranium Compounds and Other Natural Radioactivities Uranium containing compounds and other...

255

compound queries | OpenEI Community  

Open Energy Info (EERE)

- 15:22 Multicolor Maps from Compound Queries ask queries compound queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a...

256

Motor vehicle fuel economy, the forgotten HC control stragegy. [Hydrocarbon (HC)  

DOE Green Energy (OSTI)

Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

Deluchi, M.; Wang, Quanlu; Greene, D.L.

1992-06-01T23:59:59.000Z

257

Analysis for polycyclic aromatic hydrocarbons in mussels (Mytilus galloprovincialis) from the Thermaikos Gulf, Greece  

SciTech Connect

The Thermaikos Gulf area is suspected of being contaminated with petroleum hydrocarbons. A total of 57 samples were analyzed as follows: 29 from the western area (industrial) and 28 from the eastern area (agricultural) of the Gulf. All samples examined were found to be contaminated. The levels detected ranged from trace to 13 ng/g (wet weight, drained). Seven of the samples examined contained benzo(a)pyrene at an average level of 1 ng/g. Dibenzo(a,i)pyrene was found at trace levels in a small proportion of samples. Another compound, benzo(a)anthracene, was found in 19 samples at concentrations ranging from 2 ng/g to 42 ng/g. Dibenzo(a,h)pyrene was not found in any of the samples analyzed. On the basis of the above data, the concentration of total PAH in mussels of the Thermaikos Gulf amounted to 91 ng/g (wet weight) and those of the carcinogenic PAH counted to 19 ng/g. (JMT)

Iosifidou, H.G.; Kilikidis, S.D.; Kamarianos, A.P.

1982-05-01T23:59:59.000Z

258

Partition behavior of polycyclic aromatic hydrocarbons between aged coal tar and water  

Science Conference Proceedings (OSTI)

Coal tar aged in a large-scale, artificial aquifer experiment for five years was subsequently investigated for leaching behavior of polycyclic aromatic hydrocarbons (PAHs). After five years, the initially liquid coal tar had solidified and formed segregated particles with a grain size similar to that of the sandy aquifer material. The composition of the aged coal tar (ACT) with regard to PAHs was remarkably different from that of the original bulk coal tar (BCT), because most of the low-molecular-weight compounds had been depleted. Equilibrium aqueous-phase concentrations of 17 PAHs leaching from the aquifer material containing the ACT were measured from consecutive equilibration steps at increasing temperatures of between 25 and 100 {sup o}C using accelerated solvent extraction. The results showed 2-to 5,000-fold lower concentrations than those from BCT, indicating dramatic changes of dissolution behavior of PAHs from coal tar after the five-year aging period. Predictions based on Raoult's law with the subcooled liquid solubilities substantially overestimated the equilibrium aqueous-phase concentrations of the PAHs from ACT, whereas the estimations were reasonable if the solid solubilities were employed instead. The enthalpies of phase transfer from ACT to water were determined based on the van't Hoff equation. The resulting values agreed with the dissolution enthalpies of pure solid rather than subcooled liquid PAHs.

Liu, L.H.; Endo, S.; Eberhardt, C.; Grathwohl, P.; Schmidt, T.C. [University of Tubingen, Tubingen (Germany)

2009-08-15T23:59:59.000Z

259

Sorption of organic compounds in the aqueous phase onto tire rubber  

Science Conference Proceedings (OSTI)

Batch sorption tests were conducted to investigate the sorption capacity of organic compounds by ground tire and to assess the effects of the presence of other organic compounds, ionic strength, pH, ground tire particle size, and temperature on sorption. None of the factors were significant under the conditions tested, m-Xylene had the highest partition coefficient, followed by ethylbenzene, toluene, trichloroethylene, 1,1,1-trichloroethane, chloroform, and methylene chloride (13 L/kg). The partition coefficients had a logarithmic linear relationship with the octanol-water partition coefficients. The diffusion coefficients of the compounds tested were in the range of 10{sup {minus}8} cm{sup 2}/s. The diffusion coefficients did not correlate well with the physical/chemical properties, such as molecular size, of the compounds tested. The heat of solutions of the compounds tested had relatively low values. Thus, the sorption may not be affected significantly by temperature change. Organic compounds sorbed onto tire rubber appear to be sorbed primarily onto tire rubber polymeric materials and partially carbon black in the tire rubber. Overall, ground tire shows significant capacity as a sorbent of organic compounds.

Kim, J.Y.; Park, J.K.; Edil, T.B. [Univ. of Wisconsin, Madison, WI (United States). Dept. of Civil and Environmental Engineering

1997-09-01T23:59:59.000Z

260

Method for direct production of carbon disulfide and hydrogen from hydrocarbons and hydrogen sulfide feedstock  

DOE Patents (OSTI)

A method for converting hydrocarbons and hydrogen sulfide to carbon disulfide and hydrogen is provided comprising contacting the hydrocarbons and hydrogen sulfide to a bi-functional catalyst residing in a controlled atmosphere for a time and at a temperature sufficient to produce carbon disulfide and hydrogen. Also provided is a catalyst for converting carbon sulfides and hydrogen sulfides to gasoline range hydrocarbons comprising a mixture containing a zeolite catalyst and a hydrogenating catalyst.

Miao, Frank Q.; Erekson, Erek James

1998-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Effect of temperature on wave velocities in sands and sandstones with heavy hydrocarbons  

SciTech Connect

A laboratory investigation was made of the effects of temperature on wave velocities in well cemented Massillon and Boise sandstones and unconsolidated Ottawa sand saturated with heavy hydrocarbons, as well as the dependence of compressional velocities in the hydrocarbons themselves as a function of temperature. The hydrocarbons selected as pore saturants were a commercial paraffin wax, 1-Eicosene, natural heavy crude, and natural tar. The experimental results show that the compressional wave velocities in the hydrocarbons decrease markedly with increasing temperature. In contrast wave velocities in the Massillon and Boise sandstones and unconsolidated Ottawa sand saturated with air or water decrease only little with increasing temperatures. The main reason for the large decreases in rocks with hydrocarbons is the melting of solid hydrocarbons, and high pore pressure. Thermal expansion of the saturants, and possibly thermal cracking of the heavy fractions and vaporization of the light fractions of the hydrocarbons may also contribute. The large decreases of the compressional and shear wave velocities in the hydrocarbon-saturated rocks and sands with temperature, suggest that seismic measurements such as used in seismology or borehole tomography may be very useful in detecting steam fronts in heavy hydrocarbon reservoirs undergoing steam flooding.

Wang, Z.; Nur, A.M.

1986-01-01T23:59:59.000Z

262

Catalytic conversion of C3+ alcohols to hydrocarbon blend-stock  

Catalytic conversion of C3+ alcohols to hydrocarbon blend-stock Note: The technology described above is an early stage opportunity. Licensing rights to this ...

263

Rare earth elements (REE) as geochemical clues to reconstruct hydrocarbon generation history.  

E-Print Network (OSTI)

??The REE distribution patterns and total concentrations of the organic matter of the Woodford shale reveal a potential avenue to investigate hydrocarbon maturation processes in… (more)

Ramirez-Caro, Daniel

2013-01-01T23:59:59.000Z

264

Hydrocarbon solubility and its migration processes: a look at the present status  

DOE Green Energy (OSTI)

In this study we review the present status of knowledge of solubility of hydrocarbons and its implications on primary migration processes. The intent is to examine the solubility and the transportation mechanisms relevant to geopressured-geothermal reservoirs, although the discussion included here accommodates a wide range of related aspects. Influences of parameters associated with hydrocarbon (especially methane) solubility have been studied. We have sought to evaluate several primary hydrocarbon migration processes and to point out their attractive features as well as their limitations. A brief discussion of hydrocarbon generation processes is also included.

Mamun, C.K.; Ohkuma, H.; Sepehrnoori, K.

1985-12-01T23:59:59.000Z

265

Two decades of hydrocarbon exploration activity in Indonesia  

SciTech Connect

During the past two decades, hydrocarbon exploration activity within Indonesia has been based on the Indonesian Energy Policy, aims of which include intensifying and expanding hydrocarbon exploration programs. Expansion into the offshore regions of the nation has resulted in the discovery of petroliferous basins. The first offshore oil production came on stream in 1971. Since then, significant achievements have been made in developing these resources. Intensified onshore exploration has resulted in additional oil fields being discovered in these more mature areas. Among the significant gas fields discovered during the past 20 years, Arun and Badak both supply major LNG projects. Oil fields have been found in the onshore areas of Sumatra, Kalimantan, Java, and Irian Jaya, and in the offshore areas around West Java, Madura, Natuna, and East Kalimantan. The exploration drilling success during this time has been approximately 32%. In addition, the ratio of oil field development to these discoveries is about 54%. For technical and economic reasons, not all discoveries can be developed into oil fields. Recently, Pertamina's Research and Development Division organized the study of data contributed by Pertamina exploration, foreign contractors, and science institutes. This study reveals that 60 basins are spread throughout the onshore and offshore areas of the nation. Using PAUS (plan and analysis of uncertainty situation), a Monte Carolo simulation program, the hydrocarbon potential of each basin has been estimated. These estimates will be continually revised as more data are made available to the study, as the geology of Indonesia is better understood in terms of plate tectonic theory, and as computing techniques improve.

Suardy, A.; Taruno, J.; Simbolon, P.H.; Simbolon, B.

1986-07-01T23:59:59.000Z

266

Novel metalloporphyrin catalysts for the oxidation of hydrocarbons  

DOE Green Energy (OSTI)

Work was done for developing biomimetic oxidation catalysts. Two classes of metalloporphyrin catalysts were studied. The first class of catalysts studied were a novel series of highly substituted metalloporphyrins, the fluorinated iron dodecaphenylporphyrins. These homogeneous metalloporphyrin catalysts were screened for activity as catalysts in the oxidation of hydrocarbons by dioxygen. Results are discussed with respect to catalyst structural features. The second type of catalysts studied were heterogeneous catalysts consisting of metalloporphyrins applied to inorganic supports. Preliminary catalytic testing results with these materials are presented.

Showalter, M.C.; Nenoff, T.M.; Shelnutt, J.A.

1996-11-01T23:59:59.000Z

267

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1991-01-01T23:59:59.000Z

268

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1990-01-01T23:59:59.000Z

269

Polycyclic Aromatic Hydrocarbons (PAHS) in Surface Soil in Illinois  

Science Conference Proceedings (OSTI)

One hundred sixty soil samples were collected and analyzed from sites in the State of Illinois as part of EPRI's nationwide study of polycyclic aromatic hydrocarbons (PAHs) in surface soil. The samples were collected from 10 pseudo-randomly selected locations in 16 pseudo-randomly selected populated areas throughout the State, excluding the City of Chicago. At each location, the soils were logged and samples were collected from 0 to 15 cm below ground surface. At the laboratory, the soil samples were ana...

2004-12-27T23:59:59.000Z

270

Hydrous metal oxide catalysts for oxidation of hydrocarbons  

DOE Green Energy (OSTI)

This report describes work performed at Sandia under a CRADA with Shell Development of Houston, Texas aimed at developing hydrous metal oxide (HMO) catalysts for oxidation of hydrocarbons. Autoxidation as well as selective oxidation of 1-octene was studied in the presence of HMO catalysts based on known oxidation catalysts. The desired reactions were the conversion of olefin to epoxides, alcohols, and ketones, HMOs seem to inhibit autoxidation reactions, perhaps by reacting with peroxides or radicals. Attempts to use HMOs and metal loaded HMOs as epoxidation catalysts were unsuccessful, although their utility for this reaction was not entirely ruled out. Likewise, alcohol formation from olefins in the presence of HMO catalysts was not achieved. However, this work led to the discovery that acidified HMOs can lead to carbocation reactions of hydrocarbons such as cracking. An HMO catalyst containing Rh and Cu that promotes the reaction of {alpha}-olefins with oxygen to form methyl ketones was identified. Although the activity of the catalyst is relatively low and isomerization reactions of the olefin simultaneously occur, results indicate that these problems may be addressed by eliminating mass transfer limitations. Other suggestions for improving the catalyst are also made. 57 refs.

Miller, J.E.; Dosch, R.G.; McLaughlin, L.I. [Sandia National Labs., Albuquerque, NM (United States). Process Research Dept.

1993-07-01T23:59:59.000Z

271

Energy Conservation Opportunities in Hydrocarbon Resin Manufacturing Facilities  

E-Print Network (OSTI)

"The results of a plant-wide assessment of the manufacturing facilities of Neville Chemical Company, a manufacturer of hydrocarbon resins will be presented in this paper. The project was co-funded by US Department of Energy under its Plant-Wide Opportunity Assessment Program. Resin manufacturing is a highly energy intensive process. The process needs extensive heating accomplished through steam boilers and thermal oil heaters, and cooling which is accomplished through refrigeration as well as process cooling water systems. Detailed energy assessment of Neville Chemical plants has shown significant energy conservation opportunities. For the less capital-intensive measures, energy cost savings of 20% to 30% with paybacks of less than two years were identified. The identified measures can be easily replicated in similar facilities. In this paper, details of the processes in hydrocarbon resin production from an energy consumption viewpoint will be discussed, current prevalent practices in the industry will be elaborated, and potential measures for energy use and cost savings will be outlined."

Ganji, A. R.

2003-05-01T23:59:59.000Z

272

Flexible hydrogen plant utilizing multiple refinery hydrocarbon streams  

Science Conference Proceedings (OSTI)

Numerous processes are available to produce hydrogen, however, steam reforming is still the dominant and currently preferred process because it can economically process a variety of refinery feedstocks into hydrogen. This paper discusses the Air Products 88 MMSCFD hydrogen plant built by KTI, adjacent to Shell`s Martinez refinery, which utilizes up to eight separate refinery hydrocarbon streams as feed and fuel for the production of hydrogen in the steam reforming unit. The integration of refinery hydrocarbon purge streams, normally sent to fuel, allows greater flexibility in refinery operations and increases the overall refinery fuel efficiencies. The hydrogen plant also incorporates a number of process control design features to enhance reliability, such as two out of three voting systems, in-line sparing, and reduced bed PSA operation. The final section of the paper describes the environmental features of the plant required for operation in the Bay Area Air Quality Management District (BAAQMD). Air Products and KTI designed BACT features into the hydrogen plant to minimize emissions from the facility.

Kramer, K.A.; Patel, N.M. [Air Products and Chemicals Inc., Allentown, PA (United States); Sekhri, S. [Kinetics Technology International Corp., San Dimas, CA (United States); Brown, M.G. [Shell Oil Products Co., Martinez, CA (United States)

1996-12-01T23:59:59.000Z

273

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents (OSTI)

A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

1996-01-01T23:59:59.000Z

274

Mineralization of hydrocarbons in soils under decreasing oxygen availability  

SciTech Connect

Techniques for remediation of soils contaminated with hydrocarbons (HCs) can be improved when the factors that control the decomposition rate are identified. In this study, the effect of O{sub 2} availability on the decomposition rate of hydrocarbons in soils is examined. A kinetic second-order model with the O{sub 2} concentration and biomass concentration as rate-controlling variables is used to quantify HC decomposition, O{sub 2} consumption, and CO{sub 2} production. Concentrations O{sub 2} and CO{sub 2} are calculated analytically as a function of time in a three-phase closed system. These calculations are compared with measurements of repetitive O{sub 2}-depletion experiments in closed jars containing a layer of soil contaminated with HCs. About 80% of the HC decrease could be attributed to mineralization, while the other 20% was assumed to be converted into biomass and metabolites. After calibration, model calculations agree with the experimental results, which makes the concept of O{sub 2} concentration and biomass concentration as rate-controlling variables plausible. The parameter values that are obtained by calibration have a clear biochemical significance. It is concluded that attention has to be paid to the O{sub 2} supply in closed-jar experiments to avoid erroneous interpretation of the results. 34 refs., 5 figs., 4 tabs.

Freijer, J.I. [Univ. of Amsterdam (Netherlands)

1996-03-01T23:59:59.000Z

275

Reaction of Si(111) Surface with Saturated Hydrocarbon  

SciTech Connect

Reaction of Si(111) surface with saturated hydrocarbon such as methane (CH{sub 4}) and ethane (C{sub 2}H{sub 6}) was carried out in a gas source molecular beam epitaxy (GSMBE). After carbonization, structures formed on the surface were observed by in situ reflection high-energy electron diffraction (RHEED). Structures transition formed on the surface were 7x7, {delta}-7x7, 1x1, and SiC structures. In the case of CH{sub 4}, the Si surfaces were carbonized at 800 deg. C for 120 min (7.2x10{sup 4} L) with a W-filament of 2800 deg. C, and SiC layers were obtained. In the case of C{sub 2}H{sub 6}, the mixture of 7x7 and SiC structure was observed. Decomposition of hydrocarbon was characterized in quadrupole mass spectroscopy (QMS) measurements. An atomic force microscopy (AFM) image of the mixture of 7x7 and SiC shows a wandering shape. Whereas, the SiC layer shows a regular step. This result seems to be related to the different in the amount of CH{sub 3} molecules on the surface.

Suryana, Risa [Department of Physics, Faculty of Mathematics and Natural Sciences, Sebelas Maret University Jl. Ir. Sutami 36A Kentingan Surakarta 57126 (Indonesia); Nakahara, Hitoshi; Saito, Yahachi [Department of Quantum Engineering, Graduate School of Engineering, Nagoya University Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Ichimiya, Ayahiko [Department of Mathematical and Physical Science, Faculty of Science, Japan Women's University Mejirodai 2-8-1, Tokyo 112-8681 (Japan)

2011-12-10T23:59:59.000Z

276

Southern Mozambique basin: most promising hydrocarbon province offshore eat Africa  

Science Conference Proceedings (OSTI)

Recent offshore acquisition of 12,800 km (8,000 mi) of seismic reflection data, with gravity and magnetic profiles encompassing the southern half of the Mozambique basin, reveals new facets of the subsurface geology. Integrated interpretation of these new geophysical data with old well information results in the development of depositional and tectonic models that positively establish the hydrocarbon potential of the basin. The recent comprehensive interpretation affords the following conclusions. (1) Significant oil shows accompany wet gas discoveries suggest that the South Mozambique basin is a mature province, as the hydrocarbon associations imply thermogenic processes. (2) Super-Karoo marine Jurassic sequences have been encountered in Nhamura-1 well onshore from the application of seismic stratigraphy and well correlation. (3) Steeply dipping reflectors truncated by the pre-Cretaceous unconformity testify to significant tectonic activity preceding the breakup of Gondwanaland. Hence, preconceived ideas about the depth of the economic basement and the absence of mature source rocks of pre-Cretaceous age should be revised. (4) Wildcats in the vicinity of ample structural closures have not been, in retrospect, optimally positioned nor drilled to sufficient depth to test the viability of prospects mapped along a major offshore extension of the East African rift system delineated by this new survey.

De Buyl, M.; Flores, G.

1984-09-01T23:59:59.000Z

277

Catalytic autothermal reforming of hydrocarbon fuels for fuel cells.  

DOE Green Energy (OSTI)

Fuel cell development has seen remarkable progress in the past decade because of an increasing need to improve energy efficiency as well as to address concerns about the environmental consequences of using fossil fuel for producing electricity and for propulsion of vehicles [1]. The lack of an infrastructure for producing and distributing H{sub 2} has led to a research effort to develop on-board fuel processing technology for reforming hydrocarbon fuels to generate H{sub 2} [2]. The primary focus is on reforming gasoline, because a production and distribution infrastructure for gasoline already exists to supply internal combustion engines [3]. Existing reforming technology for the production of H{sub 2} from hydrocarbon feedstocks used in large-scale manufacturing processes, such as ammonia synthesis, is cost prohibitive when scaled down to the size of the fuel processor required for transportation applications (50-80 kWe) nor is it designed to meet the varying power demands and frequent shutoffs and restarts that will be experienced during normal drive cycles. To meet the performance targets required of a fuel processor for transportation applications will require new reforming reactor technology developed to meet the volume, weight, cost, and operational characteristics for transportation applications and the development of new reforming catalysts that exhibit a higher activity and better thermal and mechanical stability than reforming catalysts currently used in the production of H{sub 2} for large-scale manufacturing processes.

Krumpelt, M.; Krause, T.; Kopasz, J.; Carter, D.; Ahmed, S.

2002-01-11T23:59:59.000Z

278

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents (OSTI)

A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

Ruka, R.J.; Basel, R.A.

1996-03-12T23:59:59.000Z

279

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-09-07T23:59:59.000Z

280

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1994-06-14T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.

1989-07-18T23:59:59.000Z

282

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

283

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1994-01-01T23:59:59.000Z

284

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Houston, TX)

1989-01-01T23:59:59.000Z

285

Effect of temperature on wave velocities in sands and sandstones with heavy hydrocarbons  

SciTech Connect

A laboratory investigation was made of the effects of temperature on wave velocities in sandstones and unconsolidated sand saturated with heavy hydrocarbons. The large decreases of the compressional and shear velocities in such sandstones and sand with increasing temperature suggest that seismic methods may be very useful in detecting heat fronts in heavy hydrocarbon reservoirs undergoing steamflooding or in-situ combustion.

Wang, Z.; Nur, A.

1988-02-01T23:59:59.000Z

286

Process And Apparatus For Producing A Stream Of Inert Gases From A Hydrocarbon Fuel Source  

Science Conference Proceedings (OSTI)

An experimental research study involving an unconventional method of producing a stream of inert gases from common hydrocarbon fuel sources has been described. Design and processing science elements from several different scientific, engineering, and ... Keywords: design, engine, fuel, hydrocarbon, inert gas, process, production, system

F. W. Giacobbe

2004-08-01T23:59:59.000Z

287

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California  

E-Print Network (OSTI)

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil pollution sources. A field of strong hydrocarbon seepage offshore of Coal Oil Point near Santa Barbara in the Coal Oil Point field to measure directly the atmospheric gas flux from three seeps of varying size

California at Santa Barbara, University of

288

Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer  

E-Print Network (OSTI)

hydrocarbon, i.e. oil and gas, exploration, and are provenoil and gas reservoirs at the highest resolution possible, and on time scales acceptable to the explorationexploration in basin hydrocarbon systems including the subsurface visualization of earth resistivity volumes applied to oil and gas

2008-01-01T23:59:59.000Z

289

Evaluation of In Situ Remedial Technologies for Sites Contaminated With Hydrocarbons  

Science Conference Proceedings (OSTI)

Utility managers are faced at times with decision making regarding remediation of sites contaminated with petroleum hydrocarbons. This report, which presents the results of a survey of the literature on established and emerging technologies for in situ remediation of petroleum hydrocarbons, is intended to support such decision making.

1998-04-20T23:59:59.000Z

290

A study of hydrocarbons associated with brines from DOE geopressured wells  

DOE Green Energy (OSTI)

Accomplishments are summarized on the following tasks: distribution coefficients and solubilities, DOE design well sampling, analysis of well samples, review of theoretical models of geopressured reservoir hydrocarbons, monitor for aliphatic hydrocarbons, development of a ph meter probe, DOE design well scrubber analysis, removal and disposition of gas scrubber equipment at Pleasant Bayou Well, and disposition of archived brines.

Keeley, D.F.

1993-01-01T23:59:59.000Z

291

A study of hydrocarbons associated with brines from DOE geopressured wells. Final report  

DOE Green Energy (OSTI)

Accomplishments are summarized on the following tasks: distribution coefficients and solubilities, DOE design well sampling, analysis of well samples, review of theoretical models of geopressured reservoir hydrocarbons, monitor for aliphatic hydrocarbons, development of a ph meter probe, DOE design well scrubber analysis, removal and disposition of gas scrubber equipment at Pleasant Bayou Well, and disposition of archived brines.

Keeley, D.F.

1993-07-01T23:59:59.000Z

292

Numerical Simulation of Polycyclic Aromatic Hydrocarbon Formation in n-Heptane HCCI Combustion  

Science Conference Proceedings (OSTI)

By modifying the SENKIN code of CHEMKIN chemical kinetics package, the combustion processes and the characteristics of hydrocarbon (HC) and carbon monoxide(CO) emissions of a HCCI engine were simulated. Furthermore, the formation of benzene (A1) and ... Keywords: n-neptane, HCCI, multi-zone model, polycyclic aromatic hydrocarbons

Zeng Wen; Ma Hong-an

2011-02-01T23:59:59.000Z

293

Curvature analysis applied to the Cantarell structure, southern Gulf of Mexico: implications for hydrocarbon exploration  

Science Conference Proceedings (OSTI)

The middle Miocene Cantarell structure is host to the largest hydrocarbon field in Mexico. It has been variously interpreted as a fold-and-thrust or a dextral transpressional structure and the hydrocarbons are generally located in fold culminations adjacent ... Keywords: Folds, Geological algorithm, Geological surfaces, Petroleum, Structural geology, Transpressional structure

J. J. Mandujano; R. V. Khachaturov; G. Tolson; J. Duncan Keppie

2005-06-01T23:59:59.000Z

294

Natural organic compounds as tracers for biomass combustion in aerosols  

SciTech Connect

Biomass combustion is an important primary source of carbonaceous particles in the global atmosphere. Although various molecular markers have already been proposed for this process, additional specific organic tracers need to be characterized. The injection of natural product organic tracers to smoke occurs primarily by direct volatilization/steam stripping and by thermal alteration based on combustion temperature. The degree of alteration increases as the burn temperature rises and the moisture content of the fuel decreases. Although the molecular composition of organic matter in smoke particles is highly variable, the molecular structures of the tracers are generally source specific. The homologous compound series and biomarkers present in smoke particles are derived directly from plant wax, gum and resin by volatilization and secondarily from pyrolysis of biopolymers, wax, gum and resin. The complexity of the organic components of smoke aerosol is illustrated with examples from controlled burns of temperate and tropical biomass fuels. Burning of biomass from temperate regions (i.e., conifers) yields characteristic tracers from diterpenoids as well as phenolics and other oxygenated species, which are recognizable in urban airsheds. The major organic components of smoke particles from tropical biomass are straight-chain, aliphatic and oxygenated compounds and triterpenoids. The precursor-to-product approach of organic geochemistry can be applied successfully to provide tracers for studying smoke plume chemistry and dispersion.

Simoneit, B.R.T. [Brookhaven National Lab., Upton, NY (United States)]|[Oregon State Univ., Corvallis, OR (United States). Coll. of Oceanic and Atmospheric Sciences; Abas, M.R. bin [Brookhaven National Lab., Upton, NY (United States)]|[Univ. of Malaya, Kuala Lumpur (Malaysia); Cass, G.R. [Brookhaven National Lab., Upton, NY (United States)]|[California Inst. of Tech., Pasadena, CA (United States). Environmental Engineering Science Dept.; Rogge, W.F. [Brookhaven National Lab., Upton, NY (United States)]|[Florida International Univ., University Park, FL (United States). Dept. of Civil and Environmental Engineering; Mazurek, M.A. [Brookhaven National Lab., Upton, NY (United States); Standley, L.J. [Academy of Natural Sciences, Avondale, PA (United States). Stroud Water Research Center; Hildemann, L.M. [Stanford Univ., CA (United States). Dept. of Civil Engineering

1995-08-01T23:59:59.000Z

295

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents (OSTI)

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

296

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents (OSTI)

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

297

Biofuel from Bacteria and Sunlight: Shewanella as an Ideal Platform for Producing Hydrocarbons  

SciTech Connect

Broad Funding Opportunity Announcement Project: The University of Minnesota is developing clean-burning, liquid hydrocarbon fuels from bacteria. The University is finding ways to continuously harvest hydrocarbons from a type of bacteria called Shewanella by using a photosynthetic organism to constantly feed Shewanella the sugar it needs for energy and hydrocarbon production. The two organisms live and work together as a system. Using Shewanella to produce hydrocarbon fuels offers several advantages over traditional biofuel production methods. First, it eliminates many of the time-consuming and costly steps involved in growing plants and harvesting biomass. Second, hydrocarbon biofuels resemble current petroleum-based fuels and would therefore require few changes to the existing fuel refining and distribution infrastructure in the U.S.

None

2010-01-01T23:59:59.000Z

298

Process for removal of polynuclear aromatics from a hydrocarbon in an endothermic reformer reaction system  

Science Conference Proceedings (OSTI)

A process is described for reforming a hydrocarbon in a multi-stage endothermic reforming series of catalytic reforming reactors where the hydrocarbon is passed through the series of catalytic reforming reactors to form a reformate. The hydrocarbon is heated prior to entry to the next catalytic reforming reactor in the series, which process comprises contact of the hydrocarbon intermediate from the series of catalytic reforming reactors containing reforming catalyst with a polynuclear aromatic adsorbent to adsorb at least a portion of the polynuclear aromatic content from the hydrocarbon prior to entry to each of the next catalytic reforming reactor in the series and recovering a reformate from the last catalytic reforming reactor in the series, the recovered reformate having a reduced content of polynuclear aromatics.

Ngan, D.Y.

1989-02-14T23:59:59.000Z

299

Recovery of C/sub 3/. sqrt. hydrocarbon conversion products and net excess hydrogen in a catalytic reforming process  

Science Conference Proceedings (OSTI)

This invention relates to a hydrocarbon conversion process effected in the presence of hydrogen, especially a hydrogenproducing hydrocarbon conversion process. More particularly, this invention relates to the catalytic reforming of a naphtha feedstock, and is especially directed to an improved recovery of the net excess hydrogen, and to an improved recovery of a C/sub 3/..sqrt.. normally gaseous hydrocarbon conversion product and a C/sub 5/..sqrt.. hydrocarbon conversion product boiling in the gasoline range.

Degraff, R.R.; Peters, K.D.

1982-12-21T23:59:59.000Z

300

GIS-based modeling of secondary hydrocarbon migration pathways and its application in the northern Songliao Basin, northeast China  

Science Conference Proceedings (OSTI)

Hydrocarbon migration pathways are the linkage between hydrocarbon source areas and accumulation sites. Modeling accurately the pathways of hydrocarbon migration is of important significance in determining the location of favorable petroleum exploration ... Keywords: Digital elevation model (DEM), Geographic information system (GIS), Migration pathway, Oil and gas-bearing basin, Visualization

Xuefeng Liu; Guangfa Zhong; Jingyuan Yin; Youbin He; Xianhua Li

2008-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Separation and recovery of hydrogen and normally gaseous hydrocarbons from net excess hydrogen from a catalytic reforming process  

Science Conference Proceedings (OSTI)

A process is disclosed for the catalytic reforming of hydrocarbons in the presence of hydrogen, preferably to produce high quality gasoline boiling range products. An improved recovery of normally gaseous hydrocarbons from the net excess hydrogen is realized by chilling and contacting said hydrogen with a normally liquid hydrocarbon stream in a plural stage absorption zone at an elevated pressure.

Scheifele, C.A.

1982-06-08T23:59:59.000Z

302

Feedback Capacity of the Compound Channel  

E-Print Network (OSTI)

In this work, we find the capacity of a compound finite-state channel (FSC) with time-invariant deterministic feedback. We consider the use of fixed length block codes over the compound channel. Our achievability result ...

Shrader, Brooke E.

303

Method and apparatus for hydrocarbon recovery from tar sands  

DOE Patents (OSTI)

A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

Westhoff, James D. (Laramie, WY); Harak, Arnold E. (Laramie, WY)

1989-01-01T23:59:59.000Z

304

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

Amoco Oil Company is investigating the direct conversion of light hydrocarbon gases to liquid fuels via partial oxidation. This report describes work completed in the first quarter of the two-year project (first quarter FY 1990). Task 1 of the work, preparation of the Project Management Plan, has been completed. Work was started and progress made on three other tasks during this quarter: Task 2. Modification of an existing Amoco pilot plant to handle the conditions of this project. Minor modifications were made to increase the maximum operating pressure to 1500 psig. Other more extensive modifications are being designed, including addition of an oxygen compressor and recycle system. Task 3.1. Evaluation of a Los Alamos National Laboratory methane oxidation kinetic model for suitability in guiding the experimental portions of this project. Task 3.2. Process variable (e.g. temperature, pressure, residence time) studies to determine optimal partial oxidation conditions. 1 fig.

Foral, M.J.

1990-01-01T23:59:59.000Z

305

Solution mining systems and methods for treating hydrocarbon containing formations  

Science Conference Proceedings (OSTI)

A method for treating an oil shale formation comprising nahcolite is disclosed. The method includes providing a first fluid to a portion of the formation through at least two injection wells. A second fluid is produced from the portion through at least one injection well until at least two injection wells are interconnected such that fluid can flow between the two injection wells. The second fluid includes at least some nahcolite dissolved in the first fluid. The first fluid is injected through one of the interconnected injection wells. The second fluid is produced from at least one of the interconnected injection wells. Heat is provided from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation.

Vinegar, Harold J. (Bellaire, TX); de Rouffignac, Eric Pierre (Rijswijk, NL); Schoeling, Lanny Gene (Katy, TX)

2009-07-14T23:59:59.000Z

306

Method and apparatus for hydrocarbon recovery from tar sands  

DOE Patents (OSTI)

A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

Westhoff, J.D.; Harak, A.E.

1988-05-04T23:59:59.000Z

307

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents (OSTI)

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

308

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

Science Conference Proceedings (OSTI)

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

309

Role of crude-oil components in surfactant interaction. [Effect of acids, bases and heavy ends hydrocarbons (alkanes) on the solubilization, optimal salinity and interfacial tension of surfactant systems  

Science Conference Proceedings (OSTI)

Three crude oils from Bell Creek, Bradford, and Delaware-Childers fields were separated into distillates, acids, bases and heavy ends hydrocarbon. The effect of these components on the solubilization, optimal salinity, and bases shifted the optimal salinity significantly; their effects on the solubilization and interfacial tension are smaller. The bases appear to interact with the sulfonates, causing desorption from the interface, phase separation, and higher interfacial tension. The hydrocarbons, as expected have the strongest influence on the properties studied, due to their high concentration. The importance of the chemical nature and molecular weights of these components was also apparent. Even though the product sigma*/sup 2/..gamma.. is not constant, it was found that there is a definite relation between the solubilization (sigma*) and the interfacial tension (..gamma..). This is true even for such complex compounds as acids and bases. 41 references, 6 figures, 14 tables.

Tham, M.K.; Lorenz, P.B.

1983-09-01T23:59:59.000Z

310

Biodegradation of petroleum hydrocarbons in contaminated aqueous and sediment environments  

E-Print Network (OSTI)

Six bioremediation methods were tested in laboratory microcosms using field soil and water samples from within the fire-wall area of a petroleum storage tank. This soil had been intermittently contaminated with Bunker C fuel oil and other petroleum materials over an extended period of time. This study focuses on the behavior of the laboratory microcosms designed to simulate the in situ conditions and the six bioremedial methods employed in a related field study. The six treatment methods were: 1) aeration with essential nutrients and indigenous organisms, 2) aeration with essential nutrients and an inoculation from a refinery wastewater treatment facility, 3) aeration with oleophilic fertilizer and indigenous organisms, 4) aeration with essential nutrients and biosurfactant organisms, 5) aeration with nutrients and proprietary organisms, and 6) aeration only. Total petroleum hydrocarbons (TPH) analyses and gas chromatographic/mass spectrophotometric (GC-MS) analyses of the petroleum fractions were used to determine if the enhancement methods were more effective than the control in biodegrading the contaminants. Results indicated that there was no significant difference in the petroleum reduction rates among the six treatment methods. The conclusions were that the petroleum was not bioavailable --transfer from soil-to-water was likely the rate controlling factor in this study. Biodegradation rates were significantly slowed by the highly weathered state of the petroleum, and the extreme spatial heterogeneity hindered the sampling and analysis of the petroleum. These conclusions were further supported in a second experiment using only the extracted petroleum contaminant. The extracted petroleum was biodegraded when made available in shake flasks. Three different ,consortia were shown to significantly biodegrade the petroleum contaminant when made bioavailable. These consortia were able to reduce the TPH and many other specific hydrocarbons.

Mills, Marc Allyn

1994-01-01T23:59:59.000Z

311

The Compound Capacity of Polar Codes  

E-Print Network (OSTI)

We consider the compound capacity of polar codes under successive cancellation decoding for a collection of binary-input memoryless output-symmetric channels. By deriving a sequence of upper and lower bounds, we show that in general the compound capacity under successive decoding is strictly smaller than the unrestricted compound capacity.

Hassani, S Hamed; Urbanke, Ruediger

2009-01-01T23:59:59.000Z

312

Thin films of mixed metal compounds  

DOE Patents (OSTI)

A compositionally uniform thin film of a mixed metal compound is formed by simultaneously evaporating a first metal compound and a second metal compound from independent sources. The mean free path between the vapor particles is reduced by a gas and the mixed vapors are deposited uniformly. The invention finds particular utility in forming thin film heterojunction solar cells.

Mickelsen, Reid A. (Bellevue, WA); Chen, Wen S. (Seattle, WA)

1985-01-01T23:59:59.000Z

313

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

DOE Green Energy (OSTI)

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

314

Fuel-flexible partial oxidation reforming of hydrocarbons for automotive applications.  

DOE Green Energy (OSTI)

Micro-reactor tests indicate that our partial oxidation catalyst is fuel-flexible and can reform conventional (gasoline and diesel) and alternative (ethanol, methanol, natural gas) fuels to hydrogen rich product gases with high hydrogen selectivity. Alcohols are reformed at lower temperatures (< 600 C) while alkanes and unsaturated hydrocarbons require slightly higher temperatures. Cyclic hydrocarbons and aromatics have also been reformed at relatively low temperatures, however, a different mechanism appears to be responsible for their reforming. Complex fuels like gasoline and diesel, which are mixtures of a broad range of hydrocarbons, require temperatures of > 700 C for maximum hydrogen production.

Ahmed, S.; Carter, J. D.; Kopasz, J. P.; Krumpelt, M.; Wilkenhoener, R.

1999-06-07T23:59:59.000Z

315

Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid  

DOE Patents (OSTI)

A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

2009-09-01T23:59:59.000Z

316

Thin films of mixed metal compounds  

DOE Patents (OSTI)

Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

Mickelsen, R.A.; Chen, W.S.

1985-06-11T23:59:59.000Z

317

An automatic analysis of Norwegian compounds  

E-Print Network (OSTI)

Introduction The University of Oslo is currently developing an automatic morphosyntactic tagger for Norwegian. 2 A very important module is one which can analyse compounds. Compounding is extremely productive in Norwegian, and it is futile to ever hope for a lexicon (dictionary) that will contain all or even most of the compounds that occr in actual texts. Since the tagger we are developing is based on the possibility of recognising words by the help of a lexicon, it is of great importance to have a module that recognises new compounds. According to Munthe (1972), 10.4 per cent of all words in running text are compounds. Any text sample will contain a greatnumber of compounds. This statistics is true even for small samples. I took an arbitrary 440-word article from the newspaper Aftenposten from September this year, Full penhet om passunion (Full openness on passport union), and I quickly counted 47 compounds. Many of them a

Janne Bondi Johannessen; Helge Hauglin

1996-01-01T23:59:59.000Z

318

METHOD OF RECOVERING URANIUM COMPOUNDS  

DOE Patents (OSTI)

S>The recovery of uranium compounds which have been adsorbed on anion exchange resins is discussed. The uranium and thorium-containing residues from monazite processed by alkali hydroxide are separated from solution, and leached with an alkali metal carbonate solution, whereby the uranium and thorium hydrorides are dissolved. The carbonate solution is then passed over an anion exchange resin causing the uranium to be adsorbed while the thorium remains in solution. The uranium may be recovered by contacting the uranium-holding resin with an aqueous ammonium carbonate solution whereby the uranium values are eluted from the resin and then heating the eluate whereby carbon dioxide and ammonia are given off, the pH value of the solution is lowered, and the uranium is precipitated.

Poirier, R.H.

1957-10-29T23:59:59.000Z

319

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

Lancaster, Gregory D. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID); Reagen, William K. (Stillwater, MN)

1995-01-01T23:59:59.000Z

320

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

1995-08-29T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Regen, W.K.

1993-12-31T23:59:59.000Z

322

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

323

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

324

Recovery and evaluation of the solid products produced by thermocatalytic decomposition of tire rubber compounds  

E-Print Network (OSTI)

A thermal catalytic decomposition process has been developed to recycle used tire rubber. This process enables the recovery of useful products, such as hydrocarbons and carbon blacks. During the catalytic decomposition process, the tire rubber is decomposed into smaller hydrocarbons, which are collected in the process. The solid reaction residue, which normally consists of carbon black, catalysts, other inorganic rubber compound components, and organic carbonaceous deposits, was subjected to a series of treatments with the intention to recover the valuable carbon black and catalyst. The process economics depend strongly on the commercial value of the recovered carbon black and the ability to recover and recycle the catalysts used in the process. Some of the important properties of the recovered carbon black product have been characterized and compared with that of commercial-grade carbon blacks. The composition of the recovered carbon black was analyzed by TGA and EDX, the structure and morphology were studied through transmission electron microscopy (TEM), and the specific surface area was measured by BET nitrogen adsorption. The recovered products possess qualities at least comparable to (or even better than) that of the commercial-grade carbon black N660. Methods for increasing the market value of this recovered carbon black product are discussed. Anhydrous aluminum chloride (AlCl3) was used as the primary catalyst in the process. A catalyst recovery method based on the AlCl3 sublimation and recondensation was studied and found to be non-feasible. It is believed that the catalyst forms an organometallic complex with the decomposed hydrocarbons, such that it becomes chemically bonded to the residue material and hence not removable by evaporation. A scheme for the further study of the catalyst recovery is suggested.

Liang, Lan

2004-05-01T23:59:59.000Z

325

Carbon-13 magnetic resonance of hydrocarbons. Annual report  

SciTech Connect

Several tetralins, tetrahydrophenanthrenes, and dihydroanthracenes were synthesized, /sup 13/C spin-lattice relaxation measurements were carried out on aromatic and hydroaromatic compounds. /sup 13/C chemical shift studies were also conducted on methylated 1,2,3,4-tetrahydronaphthalenes, 1,2,3,4-tetrahydrophenanthrenes, and 9,10-dihydroanthracenes. (DLC)

Grant, D.M.; Pugmire, R.J.

1979-01-01T23:59:59.000Z

326

Modelling of catalytic aftertreatment of NOx emissions using hydrocarbon as a reductant.  

E-Print Network (OSTI)

??Hydrocarbon selective catalytic reduction (HC-SCR) is emerging as one of the most practical methods for the removal of nitrogen oxides (NOx) from light-duty-diesel engine exhaust… (more)

Sawatmongkhon, Boonlue

2012-01-01T23:59:59.000Z

327

Understanding the Adsorption of Polycyclic Aromatic Hydrocarbons from Aqueous Phase onto Activated Carbon.  

E-Print Network (OSTI)

??Non-competitive adsorption of polycyclic aromatic hydrocarbons (PAHs) from water onto activated carbon was studied alongside the performance of CO2-activated petroleum coke as a low-cost adsorbent.… (more)

Awoyemi, Ayodeji

2011-01-01T23:59:59.000Z

328

Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer  

E-Print Network (OSTI)

of potential offshore oil and gas reservoirs. To cope within hydrocarbon, i.e. oil and gas, exploration, and aresuch as brines, water, oil and gas. This has encouraged the

2008-01-01T23:59:59.000Z

329

Complex conductivity tensor of anisotropic hydrocarbon-1 bearing shales and mudrocks2  

E-Print Network (OSTI)

to describe seismic and electromagnetic (EM) measurements in these anisotropic54 materials.55 Oil-shale to release their hydrocarbons. Hence, oil shales and58 mudrocks are typically water-wet, single- or dual

Torres-Verdín, Carlos

330

Black carbon in marine sediments : quantification and implications for the sorption of polycyclic aromatic hydrocarbons  

E-Print Network (OSTI)

Sorption is a key factor in determining the fate of polycyclic aromatic hydrocarbons (PAHs) in the environment. Here, PAH sorption is proposed as the sum of two mechanisms: absorption into a biogenic, organic carbon (OC) ...

Accardi-Dey, AmyMarie, 1976-

2003-01-01T23:59:59.000Z

331

Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California  

E-Print Network (OSTI)

Mar Lett (2010) 30:331–338 Fig. 3 Coal Oil Point seep field,hydrocarbon seeps near Coal Oil Point, California. Marhydrocarbon seep emissions, Coal Oil Point seep field,

Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

2010-01-01T23:59:59.000Z

332

Factor Analysis of Hydrocarbon Species in the South-Central Coast Air Basin  

Science Conference Proceedings (OSTI)

The composition of canister hydrocarbon data collected at four surface sites and from aircraft during a 1985 field experiment in California's south-central coast air basin was analyzed to determine the source. Statistical routines from a commonly ...

James P. Killus; Gary E. Moore

1991-05-01T23:59:59.000Z

333

Impact of retarded spark timing on engine combustion, hydrocarbon emissions, and fast catalyst light-off  

E-Print Network (OSTI)

An experimental study was performed to determine the effects of substantial spark retard on engine combustion, hydrocarbon (HC) emissions, feed gas enthalpy, and catalyst light-off. Engine experiments were conducted at ...

Hallgren, Brian E. (Brian Eric), 1976-

2005-01-01T23:59:59.000Z

334

From upstream to downstream: Megatrends and latest developments in Latin America`s hydrocarbons sector  

SciTech Connect

In recent years, Latin America`s hydrocarbons sector has been characterized by reorganization, revitalization, regional cooperation, environmental awakening, and steady expansion. The pattern of these changes, which appear to be the megatrends of the region`s hydrocarbons sector development, will continue during the rest of the 1990s. To further study the current situation and future prospects of Latin America`s hydrocarbons sector, we critically summarize in this short article the key issues in the region`s oil and gas development. These megatrends in Latin America`s hydrocarbons sector development will impact not only the future energy demand and supply in the region, but also global oil flows in the North American market and across the Pacific Ocean. Each country is individually discussed; pipelines to be constructed are discussed also.

Wu, Kang; Pezeshki, S.; McMahon, J.

1995-08-01T23:59:59.000Z

335

Hydrocarbon emissions in a homogeneous direct-injection spark engine : gasoline and gasohol  

E-Print Network (OSTI)

In order to better understand the effects on hydrocarbon emissions of loading, engine temperature, fuel type, and injection timing, a series of experiments was performed. The effect of loading was observed by running the ...

Tharp, Ronald S

2008-01-01T23:59:59.000Z

336

Assessing the hydrocarbon emissions in a homogeneous direct injection spark ignited engine  

E-Print Network (OSTI)

For the purpose of researching hydrocarbon (HC) emissions in a direct-injection spark ignited (DISI) engine, five experiments were performed. These experiments clarified the role of coolant temperature, injection pressure, ...

Radovanovic, Michael S

2006-01-01T23:59:59.000Z

337

Effect of Sulfur and Hydrocarbon Fuels on Titanate/Ceria SOFC Anodes  

DOE Green Energy (OSTI)

The purpose of the project is to develop low-cost, high-performance anodes that offer low polarization resistance as well as improved tolerance for nonidealities in anode environment such as redox cycles, sulfur and other poisons, and hydrocarbons.

Marina, O.A.; Pedersen, L.R.; Stevenson, J.W.

2005-01-27T23:59:59.000Z

338

Zeolite deactivation during hydrocarbon reactions: characterisation of coke precursors and acidity, product distribution.  

E-Print Network (OSTI)

??The catalytic conversion of hydrocarbons over zeolites has been applied in large scale petroleum-refining processes. However, there is always formation and retention of heavy by-products,… (more)

Wang, B.

2008-01-01T23:59:59.000Z

339

Evaluation of biological treatment for the degradation of petroleum hydrocarbons in a wastewater treatment plant  

E-Print Network (OSTI)

Biodegradation of petroleum hydrocarbon can be an effective treatment method applied to control oil pollution in both fresh water and marine environments. Hydrocarbon degraders, both indigenous and exogenous, are responsible for utilizing petroleum hydrocarbon as their substrate for growth and energy, thereby degrading them. Biodegradation of hydrocarbons is often enhanced by bioaugmentation and biostimulation depending on the contaminated environment and the competence of the hydrocarbon degraders present. An evaluation of the performance of the biological treatment of petroleum hydrocarbon by the hydrocarbon degrading microbes at the Brayton Fire School??s 4 million gallon per day (MGD) wastewater treatment plant was the main research objective. Samples were taken for two seasons, winter (Nov 03 ?? Jan 03) and summer (Jun 04 ?? Aug 04), from each of the four treatment units: the inlet tank, equalization tank, aeration tank and the outfall tank. The population of aliphatic hydrocarbon degraders were enumerated and nutrient availability in the system were used to evaluate the effectiveness of on-going bioaugmentation and biostimulation. Monitoring of general effluent parameters was conducted to evaluate the treatment plant??s removal efficiency and to determine if effluent discharge was in compliance with the TCEQ permit. The aeration tank is an activated sludge system with no recycling. Hydrocarbon degraders are supplied at a constant rate with additional nutrient supplement. There was a significant decrease in the population of microbes that was originally fed to the system and the quantity resident in the aeration tank. Nutrient levels in the aeration tank were insufficient for the concentration of hydrocarbon degraders, even after the application of dog food as a biostimulant. The use of dog food is not recommended as a nutrient supplement. Adding dog food increases the nitrogen and phosphorus concentration in the aeration tank but the amount of carbon being added with the dog food increases the total chemical oxygen demand (COD) and biochemical oxygen demand (BOD). An increase in the concentration of total COD and BOD further increases the nitrogen and phosphorus requirement in the system. The main objective of supplying adequate nutrients to the hydrocarbon degraders would never be achieved as there would be an additional demand of nutrients to degrade the added carbon source. This research study was conducted to identify the drawbacks in the treatment plant which needs further investigation to improve efficiency.

Basu, Pradipta Ranjan

2006-05-01T23:59:59.000Z

340

OPERATION OF SOLID OXIDE FUEL CELL ANODES WITH PRACTICAL HYDROCARBON FUELS  

DOE Green Energy (OSTI)

This work was carried out to achieve a better understanding of how SOFC anodes work with real fuels. The motivation was to improve the fuel flexibility of SOFC anodes, thereby allowing simplification and cost reduction of SOFC power plants. The work was based on prior results indicating that Ni-YSZ anode-supported SOFCs can be operated directly on methane and natural gas, while SOFCs with novel anode compositions can work with higher hydrocarbons. While these results were promising, more work was clearly needed to establish the feasibility of these direct-hydrocarbon SOFCs. Basic information on hydrocarbon-anode reactions should be broadly useful because reformate fuel gas can contain residual hydrocarbons, especially methane. In the Phase I project, we have studied the reaction mechanisms of various hydrocarbons--including methane, natural gas, and higher hydrocarbons--on two kinds of Ni-containing anodes: conventional Ni-YSZ anodes and a novel ceramic-based anode composition that avoid problems with coking. The effect of sulfur impurities was also studied. The program was aimed both at achieving an understanding of the interactions between real fuels and SOFC anodes, and providing enough information to establish the feasibility of operating SOFC stacks directly on hydrocarbon fuels. A combination of techniques was used to provide insight into the hydrocarbon reactions at these anodes during SOFC operation. Differentially-pumped mass spectrometry was be used for product-gas analysis both with and without cell operation. Impedance spectroscopy was used in order to understand electrochemical rate-limiting steps. Open-circuit voltages measurements under a range of conditions was used to help determine anode electrochemical reactions. Life tests over a wide range of conditions were used to establish the conditions for stable operation of anode-supported SOFC stacks directly on methane. Redox cycling was carried out on ceramic-based anodes. Tests on sulfur tolerance of Ni-YSZ anodes were carried out.

Scott A. Barnett; Jiang Liu; Yuanbo Lin

2004-07-30T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Polyethylene composites containing a phase change material having a C14 straight chain hydrocarbon  

DOE Patents (OSTI)

A composite useful in thermal energy storage, said composite being formed of a polyethylene matrix having a straight chain alkyl hydrocarbon incorporated therein, said polyethylene being crosslinked to such a degree that said polyethylene matrix is form stable and said polyethylene matrix is capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon; the composite is useful in forming pellets or sheets having thermal energy storage characteristics.

Salyer, Ival O. (Dayton, OH)

1987-01-01T23:59:59.000Z

342

Chemical kinetic study of the oxidation of toluene and related cyclic compounds  

SciTech Connect

Chemical kinetic models of hydrocarbons found in transportation fuels are needed to simulate combustion in engines and to improve engine performance. The study of the combustion of practical fuels, however, has to deal with their complex compositions, which generally involve hundreds of compounds. To provide a simplified approach for practical fuels, surrogate fuels including few relevant components are used instead of including all components. Among those components, toluene, the simplest of the alkyl benzenes, is one of the most prevalent aromatic compounds in gasoline in the U.S. (up to 30%) and is a promising candidate for formulating gasoline surrogates. Unfortunately, even though the combustion of aromatics been studied for a long time, the oxidation processes relevant to this class of compounds are still matter of discussion. In this work, the combustion of toluene is systematically approached through the analysis of the kinetics of some important intermediates contained in its kinetic submechanism. After discussing the combustion chemistry of cyclopentadiene, benzene, phenol and, finally, of toluene, the model is validated against literature experimental data over a wide range of operating conditions.

Mehl, M; Frassoldati, A; Fietzek, R; Faravelli, T; Pitz, W; Ranzi, E

2009-10-01T23:59:59.000Z

343

Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems  

Science Conference Proceedings (OSTI)

The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

Reimus, Paul W [Los Alamos National Laboratory

2011-01-21T23:59:59.000Z

344

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons to liquid transportation fuels via a partial oxidation process. The process will be tested in existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various option will be performed as experimental data become available. The project is of two year's duration and contains three major tasks: Project Management Plan, Pilot Plant Modification, and Comparison of Preliminary Data With Los Alamos Model: We will determine if the kinetic model developed by Los Alamos National Laboratory can be used to guide our experimental effort. Other subtasks under Task 3 include: Pressure/Temperature/Reaction Time Effects; Study of Different Injection Systems: Different schemes for introducing and mixing reactants before or within the reactor will be evaluated theoretically and/or experimentally; Study of Different Quench Systems; Effect of Reactor Geometry; Effect of Reactor Recycle; and Enhanced-Yield Catalyst Study. 5 refs., 12 figs., 4 tabs.

Foral, M.J.

1990-01-01T23:59:59.000Z

345

Plantwide Energy Management for Hydrocarbon and Petrochemical Industry  

E-Print Network (OSTI)

Within the hydrocarbon and petrochemical industry the generation and utilization of various forms of energy is a highly complex and dynamic process. The process plant normally generates steam and fuel in the form of process off-gas. The same process plant also requires fuel, steam, and electricity, which is supplied from the utility plant. Also, the utility plant transforms energy from one form to another for economic efficiency. The low grade energy is transformed to medium grade energy as steam. This steam is then transformed to high grade energy in the form of electric or mechanical power. As a result, the transformation and utilization of energy requires a critical balance of plantwide steam and power. The balance of power production with actual plant requirements depends largely upon the production rate and quality of various products. It is the function of an energy managcment system to control and monitor this complex interactive system to insure the reliable availability of adequate energy for the process plant at minimum cost.

Ahmed, A.; Clinkscales, T.

1988-09-01T23:59:59.000Z

346

Catalyst for the production of hydrocarbons from the synthesis gas  

SciTech Connect

This patent describes a catalyst for the production of hydrocarbons from the synthesis gas, which comprises the combination of an iron-containing Fisher-Tropsch catalyst, a zeolite and at least one metal selected from the group consisting of ruthenium, rhodium, platinum, palladium, irridium, cobalt and molybdenum. The metal supported upon the iron-containing Fischer-Tropsch catalyst or supported upon a mixture of the iron-containing Fischer-Tropsch catalyst and the zeolite. The iron in terms of iron oxide in the iron-containing Fischer-Tropsch catalyst is present in an amount of 5 to 80% by weight, based on the combined weight of the iron oxide and zeolite. The metal is present in amounts of 0.3 to 5% by weight, based upon the combined weight of the iron oxide and the zeolite. The zeolite is selected from the group consisting of zeolites having a pore size of 5 o 9 A and a silica to alumina mole ratio of at least 12 is described.

Koikeda, M.; Suzuki, T.; Munemura, K.; Nishimoto, Y.; Imai, T.

1986-11-11T23:59:59.000Z

347

Possible hydrocarbon habitat of the bulge, Alaska and Yukon Territory  

Science Conference Proceedings (OSTI)

Bedrock geology of the northernmost Bulge of the Rocky Mountain Cordillera consists of units ranging in age from the Proterozoic to the Recent. Concerted LANDSAT imagery, field mapping, and CDP seismic interpretation indicates that there are several thick, unconformity-bounded and areally distinct depositional mega-sequences in northern Alaska and Yukon Territory. Analyses of the Arctic National Wildlife Refuge (ANWR), 1002 area, subsurface suggest the presence of several large structures. However, seismic resolution is insufficient to determine the stratigraphy with a high degree of confidence. The oldest sediments in the Bulge are the northerly derived Katakturuk dolomite and the southerly derived, predominantly clastic Neruokpuk Formation. Tests of these units immediately outside ANWR produced oil, gas, and water from vugs and fractures. Both the Katakturuk and Neruokpuk are overlain by dissimilar but thick and areally limited Cambrian-Devonian sediments with undetermined reservoir potential. Middle and Upper Ellesmerian crop out around the periphery of the coastal plain and are found in the subsurface. Their presence and reservoir development in the structures of the 1002 area depend upon the extent of Lower Cretaceous truncation. Two dissimilar locally derived breakup megasequence sandstones having limited lateral extends overlie older units. They have increasing regional importance as commercial oil and gas reservoirs. Very thick, southerly derived, Brookian clastics overstep this area. They contain the largest endowment of the in-place hydrocarbons in Alaska and the Yukon. Their commercial development is incipient.

Banet, A.C. Jr. (Bureau of Land Management, Anchorage, AK (United States))

1991-03-01T23:59:59.000Z

348

Blowdown of hydrocarbons pressure vessel with partial phase separation  

E-Print Network (OSTI)

We propose a model for the simulation of the blowdown of vessels containing two-phase (gas-liquid) hydrocarbon fluids, considering non equilibrium between phases. Two phases may be present either already at the beginning of the blowdown process (for instance in gas-liquid separators) or as the liquid is formed from flashing of the vapor due to the cooling induced by pressure decrease. There is experimental evidence that the assumption of thermodynamic equilibrium is not appropriate, since the two phases show an independent temperature evolution. Thus, due to the greater heat transfer between the liquid phase with the wall, the wall in contact with the liquid experiences a stronger cooling than the wall in contact with the gas, during the blowdown. As a consequence, the vessel should be designed for a lower temperature than if it was supposed to contain vapor only. Our model is based on a compositional approach, and it takes into account internal heat and mass transfer processes, as well as heat transfer with ...

Speranza, Alessandro; 10.1142/9789812701817_0046

2011-01-01T23:59:59.000Z

349

Using Ionic Liquids in Selective Hydrocarbon Conversion Processes  

DOE Green Energy (OSTI)

This is the Final Report of the five-year project Using Ionic Liquids in Selective Hydrocarbon Conversion Processes (DE-FC36-04GO14276, July 1, 2004- June 30, 2009), in which we present our major accomplishments with detailed descriptions of our experimental and theoretical efforts. Upon the successful conduction of this project, we have followed our proposed breakdown work structure completing most of the technical tasks. Finally, we have developed and demonstrated several optimized homogenously catalytic methane conversion systems involving applications of novel ionic liquids, which present much more superior performance than the Catalytica system (the best-to-date system) in terms of three times higher reaction rates and longer catalysts lifetime and much stronger resistance to water deactivation. We have developed in-depth mechanistic understandings on the complicated chemistry involved in homogenously catalytic methane oxidation as well as developed the unique yet effective experimental protocols (reactors, analytical tools and screening methodologies) for achieving a highly efficient yet economically feasible and environmentally friendly catalytic methane conversion system. The most important findings have been published, patented as well as reported to DOE in this Final Report and our 20 Quarterly Reports.

Tang, Yongchun; Periana, Roy; Chen, Weiqun; van Duin, Adri; Nielsen, Robert; Shuler, Patrick; Ma, Qisheng; Blanco, Mario; Li, Zaiwei; Oxgaard, Jonas; Cheng, Jihong; Cheung, Sam; Pudar, Sanja

2009-09-28T23:59:59.000Z

350

Fundamental studies in production of C{sub 2}-C{sub 4} hydrocarbons from coal. Final report, 1 September 1988--31 August 1992  

DOE Green Energy (OSTI)

The following conclusions can be drawn from the result obtained in this kinetic study of single stage coal gasification to hydrocarbon (HC) gases high in C{sub 2}-C{sub 4} hydrocarbons. It was observed that the direct conversion of coal to HC gases involves two steps. The first step is thermal cleavage of the coal structure to produce liquids with small amounts of gases and coke. The second step is conversion of liquids to gases. Coal to liquids occurs very rapidly and was completed within 10 minutes. Liquids to gases is the rate-determining step of the overall process. The conversion of liquids to gases was observed to follow first order kinetics. The first order kinetics treatment of the data by isothermal approximation gave an apparent activation energy of approximately 23 kcal/mol. The first order kinetics treatment of the data by a more rigorous non-isothermal method gave an activation energy of 26 kcal/mol. The quantity of HC gases produced directly from coal reached a constant value of about l0% of the dmmf coal at a reaction time of 10 miutes. Most of the HC gases were produced from the liquids. The study of model compounds shows that conversion of liquids to HC gases.proceeds through a carbonium ion mechanism, and this accounts for the production of C{sub 2}-C{sub 4} gases. Liquid to gases occurs by a catalytic hydrocracking reaction.

Wiser, W.H.; Oblad, A.G.

1993-03-01T23:59:59.000Z

351

Hydrocarbon prospectivity assessment of the Southern Pattani Trough, Gulf of Thailand  

SciTech Connect

The Pattani Trough is an elongate north to south basin in the Gulf of Thailand offshore area that developed from Oligocene times onward. Numerous hydrocarbon discoveries, mainly gas, have been made within the Tertiary stratigraphic section in areas adjacent to the depocenter of the basin, but only dry holes have been drilled on the extreme basin margins and flanking platform areas. The southern Pattani Trough represents a [open quotes]transition zone[close quotes] in terms of potential hydrocarbon prospectivity between the low potential/high exploration risk basin marginal areas, and the high potential/low exploration risk basin marginal area. The development of hydrocarbon accumulation potential within the southern Pattani Trough can be related to a number of major controlling factors. These include structure, which on a regional scale shows a marked influence of tectonic regime on depositional system development, and on a more local scale determines trap development; stratigraphy, which determines reservoir geometry and potential hydrocarbon source rock facies distribution; petrology, which exerts a major control on depth related reservoir quality; overpressure development, which controls local migration pathways for generated hydrocarbons, and locally provides very efficient trap seals; geochemical factors, related to potential source facies distribution, hydrocarbon type; and thermal maturation of the section. The above factors have been combined to define low-, medium-, and high-risk exploration [open quotes]play fairways[close quotes] within the prospectivity transition zone of the southern Pattani Trough.

Mountford, N. (Unocal Thailand Ltd., Bangkok (Thailand))

1994-07-01T23:59:59.000Z

352

Compound cryopump for fusion reactors  

E-Print Network (OSTI)

We reconsider an old idea: a three-stage compound cryopump for use in fusion reactors such as DEMO. The helium "ash" is adsorbed on a 4.5 K charcoal-coated surface, while deuterium and tritium are adsorbed at 15-22 K on a second charcoal-coated surface. The helium is released by raising the first surface to ~30 K. In a separate regeneration step, deuterium and tritium are released at ~110 K. In this way, the helium can be pre-separated from other species. In the simplest design, all three stages are in the same vessel, with a single valve to close the pump off from the tokamak during regeneration. In an alternative design, the three stages are in separate vessels, connected by valves, allowing the stages to regenerate without interfering with each other. The inclusion of the intermediate stage would not affect the overall pumping speed significantly. The downstream exhaust processing system could be scaled down, as much of the deuterium and tritium could be returned directly to the reactor. This could reduce ...

Kovari, M; Shephard, T

2013-01-01T23:59:59.000Z

353

Complete genome sequence of the sulfur compounds oxidizing chemolithoautotroph Sulfuricurvum kujiense type strain (YK-1T)  

SciTech Connect

Sulfuricurvum kujiense Kodama and Watanabe 2004 is the type species of the monotypic genus Sulfuricurvum, which belongs to the family Helicobacteriaceae in the class Epsilonproteobacteria. The species is of interest because it is frequently found in crude oil and oil sands where it utilizes various reduced sulfur compounds such as elemental sulfur, sulfide and thiosulfate as electron donors. Members of the species do not utilize sugars, organic acids and hydrocarbons as carbon and energy sources. This is the first completed genome sequence of a member of the genus Sulfuricurvum. The genome, which consists of a circular chromosome of 2,574,824 bp length and four plasmids of 118,585 bp, 71,513 bp, 51,014 bp, and 3,421 bp length, respectively, harboring a total of 2,879 protein-coding and 61 RNA genes and is a part of the Genomic Encyclopedia of Bacteria and Archaea project.

Han, Cliff [Los Alamos National Laboratory (LANL); Kotsyurbenko, Oleg [Technical University of Braunschweig; Chertkov, Olga [Los Alamos National Laboratory (LANL); Held, Brittany [Los Alamos National Laboratory (LANL); Lapidus, Alla L. [U.S. Department of Energy, Joint Genome Institute; Nolan, Matt [U.S. Department of Energy, Joint Genome Institute; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Hammon, Nancy [U.S. Department of Energy, Joint Genome Institute; Deshpande, Shweta [U.S. Department of Energy, Joint Genome Institute; Cheng, Jan-Fang [U.S. Department of Energy, Joint Genome Institute; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Liolios, Konstantinos [U.S. Department of Energy, Joint Genome Institute; Pagani, Ioanna [U.S. Department of Energy, Joint Genome Institute; Ivanova, N [U.S. Department of Energy, Joint Genome Institute; Mavromatis, K [U.S. Department of Energy, Joint Genome Institute; Mikhailova, Natalia [U.S. Department of Energy, Joint Genome Institute; Pati, Amrita [U.S. Department of Energy, Joint Genome Institute; Chen, Amy [U.S. Department of Energy, Joint Genome Institute; Palaniappan, Krishna [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Hauser, Loren John [ORNL; Chang, Yun-Juan [ORNL; Jeffries, Cynthia [Oak Ridge National Laboratory (ORNL); Brambilla, Evelyne-Marie [DSMZ - German Collection of Microorganisms and Cell Cultures GmbH, Braunschweig, Germany; Rohde, Manfred [HZI - Helmholtz Centre for Infection Research, Braunschweig, Germany; Spring, Stefan [DSMZ - German Collection of Microorganisms and Cell Cultures GmbH, Braunschweig, Germany; Sikorski, Johannes [DSMZ - German Collection of Microorganisms and Cell Cultures GmbH, Braunschweig, Germany; Goker, Markus [DSMZ - German Collection of Microorganisms and Cell Cultures GmbH, Braunschweig, Germany; Woyke, Tanja [U.S. Department of Energy, Joint Genome Institute; Bristow, James [U.S. Department of Energy, Joint Genome Institute; Eisen, Jonathan [U.S. Department of Energy, Joint Genome Institute; Markowitz, Victor [U.S. Department of Energy, Joint Genome Institute; Hugenholtz, Philip [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Klenk, Hans-Peter [DSMZ - German Collection of Microorganisms and Cell Cultures GmbH, Braunschweig, Germany; Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute

2012-01-01T23:59:59.000Z

354

Reading Comprehension - Dissecting and Compound Microscopes  

NLE Websites -- All DOE Office Websites (Extended Search)

Dissecting and Compound Microscopes Two types of microscopes. _________ Dissecting and Compound Microscopes Two types of microscopes. _________ Dissecting Microscope Compound Microscope _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ Dissecting Microscope Compound Microscope _________ eyepieces focus knob light light switch objective stage _________ eyepieces focus knob light light switch objective stage _________ eyepieces focus knob light light switch objective stage _________ eyepieces focus knob light

355

Volatile organic compound emissions from composting.  

E-Print Network (OSTI)

??This paper is a review of the aerobic composting process and the emissions of volatile organic compounds (VOCs) from this process. To understand why and… (more)

Harris, Stephanie Rose Renée

2013-01-01T23:59:59.000Z

356

Why Sequence Bacteria That Reduce Sulfur Compounds?  

NLE Websites -- All DOE Office Websites (Extended Search)

Bacteria That Reduce Sulfur Compounds? Combustion of sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such...

357

PLUTONIUM COMPOUNDS AND PROCESS FOR THEIR PREPARATION  

DOE Patents (OSTI)

This patent relates to certain new compounds of plutonium, and to the utilization of these compounds to effect purification or separation of the plutonium. The compounds are organic chelate compounds consisting of tetravalent plutonium together with a di(salicylal) alkylenediimine. These chelates are soluble in various organic solvents, but not in water. Use is made of this property in extracting the plutonium by contacting an aqueous solution thereof with an organic solution of the diimine. The plutonium is chelated, extracted and effectively separated from any impurities accompaying it in the aqueous phase.

Wolter, F.J.; Diehl, H.C. Jr.

1958-01-01T23:59:59.000Z

358

Process for synthesizing compounds from elemental powders  

DOE Patents (OSTI)

A process for synthesizing intermetallic compounds from elemental powders. The elemental powders are initially combined in ratio a which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe{sub 3}Al and FeAl.

Rabin, B.H.; Wright, R.N.

1990-01-01T23:59:59.000Z

359

Alloys and Compounds for Thermoelectric and Solar Cell Applications  

Science Conference Proceedings (OSTI)

Alloys and Compounds for Thermoelectric and Solar Cell Applications II: Alloys and Compounds for Thermoelectric and Solar Cell Applications: Thermoelectric ...

360

Atmospheric deposition of polycyclic aromatic hydrocarbons in an urban and a suburban area of Korea from 2002 to 2004  

SciTech Connect

Atmospheric bulk samples (wet and dry) were collected monthly during 2002 to 2004 from an urban and a suburban area in Korea for assessment of depositional flux and seasonal variations in the concentrations of polycyclic aromatic hydrocarbons (PAHs). PAH depositional flux ranged from 64.1 to 610 {mu} g/m{sup 2}/y for the urban area and from 65 to 460 {mu} g/m{sup 2}/y for the suburban area. The fluxes of PAHs measured in this study were comparable with those reported for urban and suburban areas in other countries. The fluxes of particulates and PAHs were higher in winter than in summer, consistent with the greater per capita consumption of fossil fuel in winter than in summer. Ambient temperature played a major role in the seasonal variability in PAH fluxes. Photochemical degradation of PAHs appears to occur during the summer months. The relationship of PAH depositional fluxes with major air pollutants, such as ozone, sulfur dioxide, carbon monoxide, nitrogen dioxide, and presence of particulate matter up to 10 {mu} m in size (PM10), was also investigated. Dominant PAH compounds in both the urban and the suburban locations were benzo(g,h,i)perylene, pyrene, and indeno(1,2,3-c,d)pyrene. Based on the PAH diagnostic ratios and a factor analysis, the major sources of PAHs in the urban and the suburban regions were found to be similar. Diesel exhaust, coal combustion, and gasoline emissions contributed predominantly to atmospheric PAH contamination.

Moon, H.B.; Kannan, K.; Lee, S.J.; Ok, G. [National Fisheries Research & Development Institute, Pusan (Republic of Korea)

2006-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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361

Effectiveness of in site biodegradation for the remediation of polycyclic aromatic hydrocarbons at a contaminated oil refinery, Port Arthur, Texas  

E-Print Network (OSTI)

The effectiveness of bioremediation for the removal of polycyclic aromatic hydrocarbons (PAHs) from sediments contaminated with highly weathered petroleum was evaluated at a contaminated oil refinery. The sediments were chronically contaminated with crude oil and Bunker C fuel oil for the past 20 years. Two treatments, Inipol EAP-22 (INIPOL) and basic nutrients with indigenous organisms (BNIO), were compared to a control (CONTROL) plot over an 11 week period. In site PAH biodegradation was quantified by plotting the time dependence of PAH to 17?,21?-hopane concentration ratios. 17?,21?-hopane, a nondegradable, C30 triterpane, was used as a natural internal standard. Sediment characterization was performed to determine the effect of geologic conditions on PAH biodegradation rates. Total Ion Chromatograms (TICs) of extracted oil showed high concentrations of an unresolved complex mixture that did not change over the 11 week period. The particle size of the sediments from the plots averaged 51% and 34% for clay and silt content, respectively. Sediment mineralogy was dominated by kaolinite and smectite. [PAH]/[Hopane] ratios indicate no significant PAH degradation in either the INIPOL, BNIO, or CONTROL plots over the 11 week period. This data indicates that bioremediation was unsuccessful at this site due to the extreme weathered state of the oil, the limited bioavailability of the PAH compounds, and the potential toxicity of the petroleum. The use of hopane as a natural internal standard was important in quantifying the effectiveness of bioremediation due to the high spatial variability in initial oil concentrations.

Moffit, Alfred Edward

2000-01-01T23:59:59.000Z

362

Final Report, "Molecular Design of Hydrocarbon Oxidation Catalytic Processes"  

SciTech Connect

The main goal of this project had been to use model systems to correlate selectivities in partial oxidation catalysis with the presence of specific sites on the surface of the catalyst. Extensive work was performed this year on characterizing oxygen-treated nickel surfaces by chemical means. Specifically, the surface chemistry of ammonia coadsorbed with atomic oxygen on Ni(110) single-crystal surfaces was studied by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). It was determined that at intermediate oxygen coverages direct ammonia adsorption on nickel sites is suppressed, but a new high-temperature reaction regime is generated at 400 K where NHx surface fragments are rehydrogenated concurrently with the production of water and molecular hydrogen. The extensive isotope scrambling and hydrogen transfer seen from nitrogen- to oxygen-containing surface intermediates, and the optimum yields seen for this 400 K state at intermediate oxygen coverages, strongly suggest the direct interaction of the adsorbed ammonia with oxygen atoms at the end of the –Ni–O- rows that form upon reconstruction of the surface. Hydrogen transfer between ammonia and oxygen appears to take place directly via hydrogen bonding, and to be reversible but biased towards water formation. An equilibrium is reached between the produced water and the reacting surface oxygen and hydrogen. The strong influence of the OH surface groups on the thermal chemistry of the adsorbed ammonia was interpreted in terms of the adsorbing geometry of the OH groups on the surface, and of hydrogen bonding between adsorbed OH and NH3 species. In terms of alcohol reactivity, the adsorption of 2-iodoethanol, a precursor for the preparation of 2-hydroxyethyl and oxametallacycle surface species, was found to lead to two configurations involving either just the iodine atom or both iodine and hydroxyl ends of the molecule. A complex chemical behavior starts around 140 K with the production of small amounts of ethylene and water, most likely via the concerted decomposition or disproportionation of the adsorbed molecular species. The bulk of the 2-iodoethanol decomposes at about 150 K via an initial carbon-iodine scission to form –O(H)CH2CH2– (~80%) and 2-hydroxyethyl (~20%) intermediates. Two competing reactions are involved with the subsequent conversion of the 2-hydroxyethyl species around 160 K, a reductive elimination with surface hydrogen to yield ethanol, and a ?-H elimination to surface vinyl alcohol. The –O(H)CH2CH2–, on the other hand, dehydrogenates to a –OCH2CH2– oxametallacycle species about the same temperature. Both 2-hydroxyethyl and oxametallacycle species tautomerize to acetaldehyde, around 210 K and above 250 K, respectively, and some of that acetaldehyde desorbs while the rest decomposes to hydrogen and carbon monoxide. We contend that a better understanding of the surface chemistry of oxygen-containing surfaces can lead to better selectivities in catalysis. This is arguably the most important issue in the field of catalysis in the near future, and one that impacts several technologies of interest to DOE such as the manufacturing of speciality chemicals and the control and removal of pollutants. Additional work was performed on the characterization of the chemistry of methyl and methylene adsorbed species on oxygen-treated nickel surfaces. Complex chemistry was observed involving not only hydrogenation and dehydrogenation steps, but also C-C couplings and methylene insertions to produce heavier hydrocarbons, and oxygen insertion reactions that yield oxygenates. Finally, a dual titration technique employing xenon and a chemically sensitive probe was developed to identify minority catalytic sites on oxide surfaces. In the case of oxygen-treated Ni(110) single crystals, it was found that both hydrogen transfer with adsorbed water or ammonia and certain hydrocarbon hydrogenation reactions take place at the end of the –Ni–O rows that form in this system. Carbon and nitrogen oxides, on the other hand, display no pre

Professor Francisco Zaera

2007-08-09T23:59:59.000Z

363

Characterization and analysis of Devonian shales as related to release of gaseous hydrocarbons. Well R-109, Washington County, Ohio  

DOE Green Energy (OSTI)

Coring of Well R-109 (Washington County, Ohio) was accomplished in August 1976. A total of 25 samples were collected. Hydrocarbon gas analyses indicate that higher chain hydrocarbon gases (C/sub 2/-C/sub 5/) make up a significant portion of total hydrocarbons in the shales, but methane is still the dominant single gas. Distinct relationships exist between the carbon and hydrocarbon gas contents, showing increase in hydrocarbon gas contents with increasing carbon. Similar relationships between hydrogen and hydrocarbon gas contents exist, though they are not as pronounced. Gas contents appear not to be related to the bulk densities in any quantitative manner, though organic contents (carbon and hydrogen) seem to be related to bulk density values much more clearly. R-109 shales are virtually impermeable to gases and other fluids, as attempted helium gas permeability measurements indicated extremely small (< 10/sup -12/ Darcy) permeability values.

Kalyoncu, R.S.; Boyer, J.P.; Snyder, M.J.

1979-06-20T23:59:59.000Z

364

Application of Inorganic Membrane Technology to Hydrogen-hydrocarbon Separations  

DOE Green Energy (OSTI)

Separation efficiency for hydrogen/light hydrocarbon mixtures was examined for three inorganic membranes. Five binary gas mixtures were used in this study: H{sub 2}/CH{sub 4} , H{sub 2}/C{sub 2}H{sub 6}, H{sub 2}/C{sub 3}H{sub 8}, He/CO{sub 2}, and He/Ar. The membranes examined were produced during a development program at the Inorganic Membrane Technology Laboratory in Oak Ridge and provided to us for this testing. One membrane was a (relatively) large-pore-diameter Knudsen membrane, and the other two had much smaller pore sizes. Observed separation efficiencies were generally lower than Knudsen separation but, for the small-pore membranes, were strongly dependent on temperature, pressure, and gas mixture, with the most condensable gases showing the strongest effect. This finding suggests that the separation is strongly influenced by surface effects (i.e., adsorption and diffusion), which enhance the transport of the heavier and more adsorption-prone component and may also physically impede flow of the other component. In one series of experiments, separation reversal was observed (the heavier component preferentially separating to the low-pressure side of the membrane). Trends showing increased separation factors at higher temperatures as well as observations of some separation efficiencies in excess of that expected for Knudsen flow suggest that at higher temperatures, molecular screening effects were observed. For most of the experiments, surface effects were stronger and thus apparently overshadow molecular sieving effects.

Trowbridge, L.D.

2003-06-30T23:59:59.000Z

365

Kinetics simulation for natural gas conversion to unsaturated C? hydrocarbons  

E-Print Network (OSTI)

Natural gas resource is abundant and can be found throughout the world. But most natural gas reserves are at remote sites and considered stranded because of the extremely expensive transportation cost. Therefore advanced gas-to-liquid (GTL) techniques are being studied to convert natural gas to useful hydrocarbon liquids, which can be transported with far less cost. Direct pyrolysis of methane, followed by catalytic reaction, is a promising technology that can be commercialized in industry. In this process, methane is decomposed to ethylene, acetylene and carbon. Ethylene and acetylene are the desired products, while carbon formation should be stopped in the decomposition reaction. Some researchers have studied the dilution effect of various inert gases on carbon suppression. All previous results are based on the isothermal assumption. In this thesis, our simulator can be run under adiabatic conditions. We found there was a crossover temperature for carbon formation in the adiabatic case. Below the crossover temperature, the carbon formation from pure methane feed is higher than the one from a methane/hydrogen feed, while above the crossover temperature, the carbon formation from pure methane feed is lower than the one from a methane/hydrogen feed. In addition to the pure methane and methane/hydrogen feed, we also simulated the rich natural gas feed, rich natural gas with combustion gas, rich natural gas with combustion gas and methane recycle. We found the outlet temperature increases only slightly when we increase the initial feed temperature. Furthermore, the combustion gas or the recycled methane has a dilute effect, which increases the total heat capacity of reactants. The outlet temperature from the cracker will not drop so much when these gases are present, causing the methane conversion to increase correspondingly. Up to now there is no adiabatic simulator for methane pyrolysis. This work has significant meaning in practice, especially for rich natural gases.

Yang, Li

2003-01-01T23:59:59.000Z

366

Catalytic Cracking of Gaseous Heavy Hydrocarbons by Ceramic Filters  

DOE Green Energy (OSTI)

The use of syngas from waste or biomass gasification to generate electricity is a way which is attracting increasing attention especially with regard to the demands of regenerable energy consumption and to the reduction of waste disposal. In order to feed the syngas to a gas motor or a gas turbine the gas has to be cleaned. In future also the coupling of biomass gasification with a fuel cell will be applied, which needs a very efficient gas cleaning. The decomposition of tars and the removal of particles from the gas are the key issues of gas cleaning. Up to now these two steps are performed in two separate units. Normally, the tars are decomposed in catalytic beds or honeycomb structures. The catalytic decomposition is achieved at temperatures between 750 C and 900 C depending on the catalyst used. Particles are removed by filtration of the hot gas. Filtration at high temperatures and with high efficiencies is possible when using ceramic filter elements. Ceramic hot gas filters are well established in advanced coal gasification, such as the integrated gasification combined cycle process, as well as in waste and biomass gasification and pyrolysis processes. Since the catalytic reaction requires high temperatures the gas has to be reheated after the particles are removed in the filter or the hot unfiltered gas has to flow through the catalytic unit. If the gas is filtered first, reheating of the gas stream is an additional cost factor. Furthermore, pipes downstream of the filter can be plugged, if the temperature of the gas falls below the condensation temperature of the heavy hydrocarbons. Using the second way of hot unfiltered gas flows through the catalytic unit, there is the problem of deactivation of the catalyst by deposition of dust at higher dust concentrations. At worst the catalytic unit can be plugged by dust deposition.

Heidenreich, S.; Nacken, M.; Walch, A.; Chudzinski, S.

2002-09-19T23:59:59.000Z

367

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting  

Science Conference Proceedings (OSTI)

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

2011-03-15T23:59:59.000Z

368

On Quantum Capacity of Compound Channels  

E-Print Network (OSTI)

In this paper we address the issue of universal or robust communication over quantum channels. Specifically, we consider memoryless communication scenario with channel uncertainty which is an analog of compound channel in classical information theory. We determine the quantum capacity of finite compound channels and arbitrary compound channels with informed decoder. Our approach in the finite case is based on the observation that perfect channel knowledge at the decoder does not increase the capacity of finite quantum compound channels. As a consequence we obtain coding theorem for finite quantum averaged channels, the simplest class of channels with long-term memory. The extension of these results to quantum compound channels with uninformed encoder and decoder, and infinitely many constituents remains an open problem.

I. Bjelakovic; H. Boche; J. Noetzel

2008-08-07T23:59:59.000Z

369

Evolutionary sequences and hydrocarbon potential of Kenya sedimentary basins  

Science Conference Proceedings (OSTI)

Kenya basins have evolved primarily through extension related to episodic continental rifting. In eastern Kenya, thick accumulations of sediments formed within grabens during the prerift phase (Precambrian to Carboniferous) of the Gondwana breakup. Synrift sedimentation (Late Carboniferous to Middle Jurassic) occurred within a north-south rift system, which included the Mandera basin, South Anza basin, and Lamu embayment. During the Early Jurassic, a marine transgression invaded the margins of the eastern Kenya rift basins, resulting in the deposition of platform carbonates and shales. A Callovian-aged salt basin formed in the offshore regions of the Lamu embayment. Intermittent tectonic activity and eustatic sea-level changes controlled sedimentation, which produced marine shales, carbonates or evaporites, and fluvio-deltaic to lacustrine sandstones. From the Early Cretaceous to recent, continental sediments were deposited within the North Anza and Turkana basins. These fluvial-lacustrine sediments are similar to the Lower Cretaceous sequences that have produced oil in the Mesozoic Sudanese Abu Gabra rift. Although exploration activities began in the early 1950s, significant occurrences of potential reservoir, source, and seal lithologies as well as trapping configurations remain in many areas. Favorable structures and sequences of reservoir sandstones and carbonates overlain by potentially sealing lacustrine or marine shales, evaporites, or volcanics have been noted. Potential source beds are believed to be present within shales of the lacustrine or marine depositional environments.

Cregg, A.K. (Western Atlas International, Inc., Carrollton, TX (United States))

1991-03-01T23:59:59.000Z

370

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

371

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

372

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Towards Heavy Fermions in Europium Intermetallic Compounds Towards Heavy Fermions in Europium Intermetallic Compounds Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

373

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

374

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

375

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

376

Modeling the biodegradability and physicochemical properties of polycyclic aromatic hydrocarbons  

E-Print Network (OSTI)

The biodegradability and physicochemical properties of unsubstituted and methylated polycyclic aromatic hydrocarbons (PAHs) were investigated. The focus was on the development of models expressing the influence of molecular structure and properties on observed behavior. Linear free energy relationships (LFERs) were developed for the estimation of aqueous solubilities, octanol/water partition coefficients, and vapor pressures as functions of chromatographic retention time. LFERs were tested in the estimation of physicochemical properties for twenty methylated naphthalenes containing up to four methyl substituents. It was determined that LFERs can accurately estimate physicochemical properties for methylated naphthalenes. Twenty unsubstituted and methylated PAHs containing up to four aromatic rings were biodegraded individually by Sphingomonas paucimobilis strain EPA505, and Monod-type kinetic coefficients were estimated for each PAH using the integral method. Estimated extant kinetic parameters included the maximal specific biodegradation rate, the affinity coefficient, and the inhibition coefficient. The generic Andrews model adequately simulated kinetic data. The ability of PAHs to serve as sole energy and carbon sources was also evaluated. Quantitative structure-biodegradability relationships (QSBRs) were developed based on the estimates of the kinetic and growth parameters. A genetic algorithm was used for QSBR development. Statistical analysis and validation demonstrated the predictive value of the QSBRs. Spatial and topological molecular descriptors were essential in explaining biodegradability. Mechanistic interpretation of the kinetic data and the QSBRs provided evidence that simple or facilitated diffusion through the cell membranes is the rate-determining step in PAH biodegradation by strain EPA505. A kinetic experiment was conducted to investigate biodegradation of PAH mixtures by strain EPA505. The investigation focused on 2-methylphenanthrene, fluoranthene, and pyrene, and their mixtures. Integrated material balance equations describing different interaction types were fitted to the depletion data and evaluated on a statistical and probabilistic basis. Mixture degradation was most adequately described by a pure competitive interaction model with mutual substrate exclusivity, a fully predictive model utilizing parameters estimated in the sole-PAH experiments only. The models developed in this research provide insight into how molecular structure and properties influence physicochemical properties and biodegradability of PAHs. The models have considerable predictive value and could reduce the need for laboratory testing.

Dimitriou-Christidis, Petros

2005-08-01T23:59:59.000Z

377

PHASE BEHAVIOR OF LIGHT GASES IN HYDROCARBON AND AQUEOUS SOLVENTS  

Science Conference Proceedings (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present period, the Park-Gasem-Robinson (PGR) equation of state (EOS) has been modified to improve its volumetric and equilibrium predictions. Specifically, the attractive term of the PGR equation was modified to enhance the flexibility of the model, and a new expression was developed for the temperature dependence of the attractive term in this segment-segment interaction model. The predictive capability of the modified PGR EOS for vapor pressure, and saturated liquid and vapor densities was evaluated for selected normal paraffins, normal alkenes, cyclo-paraffins, light aromatics, argon, carbon dioxide and water. The generalized EOS constants and substance-specific characteristic parameters in the modified PGR EOS were obtained from the pure component vapor pressures, and saturated liquid and vapor molar volumes. The calculated phase properties were compared to those of the Peng-Robinson (PR), the simplified-perturbed-hard-chain theory (SPHCT) and the original PGR equations. Generally, the performance of the proposed EOS was better than the PR, SPHCT and original PGR equations in predicting the pure fluid properties (%AAD of 1.3, 2.8 and 3.7 for vapor pressure, saturated liquid and vapor densities, respectively).

KHALED A.M. GASEM; ROBERT L. ROBINSON, JR.

1998-08-31T23:59:59.000Z

378

STATEMENT OF CONSIDERATIONS REQUEST BY BECHTEL HYDROCARBON TECHNOLOGY SOLUTIONS FOR AN  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

BECHTEL HYDROCARBON TECHNOLOGY SOLUTIONS FOR AN BECHTEL HYDROCARBON TECHNOLOGY SOLUTIONS FOR AN ADVANCE WAIVER OF DOMESTIC AND FOREIGN INVENTION RIGHTS UNDER DOE COOPERATIVE AGREEMENT NO. DE-FE0000896, W(A)-2012-030; CH-1667 The Petitioner, Bechtel Hydrocarbon Technology Solutions (Bechtel) was awarded a subcontract under the subject cooperative agreement between the Department of Energy and SRI International (SRI) for the performance of work entitled , "C0 2 Capture from IGCC (Integrated Gasification Combined Cycle) Gas Streams Using the AC-ABC (ammonium carbonate-ammonium bicarbonate) Process". The objective of the subcontract is to show the effectiveness of two technologies - one from SRI and one from Bechtel. This will include four to six weeks of testing at the National Carbon Capture Center in Wilsonville

379

DIESEL OXIDATION CATALYST CONTROL OF HYDROCARBON AEROSOLS FROM REACTIVITY CONTROLLED COMPRESSION IGNITION COMBUSTION  

SciTech Connect

Reactivity Controlled Compression Ignition (RCCI) is a novel combustion process that utilizes two fuels with different reactivity to stage and control combustion and enable homogeneous combustion. The technique has been proven experimentally in previous work with diesel and gasoline fuels; low NOx emissions and high efficiencies were observed from RCCI in comparison to conventional combustion. In previous studies on a multi-cylinder engine, particulate matter (PM) emission measurements from RCCI suggested that hydrocarbons were a major component of the PM mass. Further studies were conducted on this multi-cylinder engine platform to characterize the PM emissions in more detail and understand the effect of a diesel oxidation catalyst (DOC) on the hydrocarbon-dominated PM emissions. Results from the study show that the DOC can effectively reduce the hydrocarbon emissions as well as the overall PM from RCCI combustion. The bimodal size distribution of PM from RCCI is altered by the DOC which reduces the smaller mode 10 nm size particles.

Prikhodko, Vitaly Y [ORNL; Parks, II, James E [ORNL; Barone, Teresa L [ORNL; Curran, Scott [ORNL; Cho, Kukwon [ORNL; Lewis Sr, Samuel Arthur [ORNL; Storey, John Morse [ORNL; Wagner, Robert M [ORNL

2011-01-01T23:59:59.000Z

380

Study of net soot formation in hydrocarbon reforming for hydrogen fuel cells. Final report  

DOE Green Energy (OSTI)

The hydrogen fuel cell is expected to be a valuable addition to the electric utility industry; however, the current fuel supply availability requires that conventional heavier hydrocarbon fuels also be considered as primary fuels. Typical heavier fuels would be No. 2 fuel oil with its accompanying sulfur impurities, compared with the currently used light hydrocarbon gases. The potential future use of alternate fuels which are rich in aromatics would exacerbate the problems associated with hydrogen production. Among the more severe of these problems, is the greater tendency of heavier hydrocarbons to form soot. The development of a quasi-global kinetics model to represent the homogeneous and heterogeneous reactions which control the autothermal hydrogen reforming process and the accompanying soot formation and gasification was the objective of this study.

Edelman, R. B.; Farmer, R. C.; Wang, T. S.

1982-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Systems including catalysts in porous zeolite materials within a reactor for use in synthesizing hydrocarbons  

Science Conference Proceedings (OSTI)

Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

Rolllins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

2012-07-24T23:59:59.000Z

382

Assessment of Hydrocarbon Seepage on Fort Peck Reservation, Northeast Montana: A Comparison of Surface Exploration Techniques  

Science Conference Proceedings (OSTI)

Surface exploration techniques have been employed in separate study areas on the Fort Peck Reservation in northeastern Montana. Anomalies associated with hydrocarbon seepage are documented in all three areas and a variety of surface exploration techniques can be compared. In a small area with established production, head gas and thermal desorption methods best match production; other methods also mapped depletion. In a moderate-size area that has prospects defined by 3D seismic data, head gas along with microbial, iodine, and Eh soil anomalies are all associated with the best hydrocarbon prospect. In a large area that contains many curvilinear patterns observed on Landsat images, results are preliminary. Reconnaissance mapping of magnetic susceptibility has identified a potential prospect; subsequent soil gas and head gas surveys suggest hydrocarbon potential.

Monson, Lawrence M.

2002-09-09T23:59:59.000Z

383

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents (OSTI)

A method of converting low H.sub.2 /CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200.degree. to 350.degree. C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n+1).gtoreq.x.gtoreq.O and for olefinic hydrocarbons: 2n.gtoreq.x.gtoreq.O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); Goldberg, Robert I. (Selden, NY)

1987-01-01T23:59:59.000Z

384

Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons  

SciTech Connect

A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

Muradov, Nazim Z. (Melbourne, FL)

2011-08-23T23:59:59.000Z

385

Preliminary design of axial flow hydrocarbon turbine/generator set for geothermal applications  

DOE Green Energy (OSTI)

This report outlines the design of a 65 MW (e) gross turbine generator set in which a hydrocarbon gas mixture is used as the motive fluid. The turbine generator set is part of a geothermal binary cycle electric power plant proposed for the Heber site in the Imperial Valley, California. Aerodynamic design considerations and estimated unit performance for three hydrocarbon gas mixtures are presented. Real gas properties and equations of state are reviewed as they affect the turbine design and the thermodynamic cycle. The mechanical designs for the casing, rotor dynamics, shaft sealing and unit construction are detailed. Support systems such as the lube and seal supply system, turbine controls, etc., are reviewed. An extensive hydrocarbon turbine general specification is also included.

Barnes, B.; Samurin, N.A.; Shields, J.R.

1979-05-01T23:59:59.000Z

386

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents (OSTI)

A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

1985-11-06T23:59:59.000Z

387

Compound and Elemental Analysis | Open Energy Information  

Open Energy Info (EERE)

Compound and Elemental Analysis Compound and Elemental Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Compound and Elemental Analysis Details Activities (104) Areas (69) Regions (6) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Results can aid in the determination of fluid source regions and circulation pathways. Thermal: Certain elements exhibit high spatial correlation with high-temperature geothermal systems. Cost Information Low-End Estimate (USD): 15.001,500 centUSD 0.015 kUSD 1.5e-5 MUSD 1.5e-8 TUSD / compound Median Estimate (USD): 30.003,000 centUSD

388

Fission Barriers of Compound Superheavy Nuclei  

E-Print Network (OSTI)

The dependence of fission barriers on the excitation energy of the compound nucleus impacts the survival probability of superheavy nuclei synthesized in heavy-ion fusion reactions. In this work, we investigate the isentropic ...

Sheikh, J. A.

389

Production method for making rare earth compounds  

DOE Patents (OSTI)

A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.

McCallum, R. William (Ames, IA); Ellis, Timothy W. (Ames, IA); Dennis, Kevin W. (Ames, IA); Hofer, Robert J. (Ames, IA); Branagan, Daniel J. (Ames, IA)

1997-11-25T23:59:59.000Z

390

Aza crown ether compounds as anion receptors  

DOE Patents (OSTI)

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI{sup +} ion in alkali metal batteries. 3 figs.

Lee, H.S.; Yang, X.O.; McBreen, J.

1998-08-04T23:59:59.000Z

391

Aza crown ether compounds as anion receptors  

SciTech Connect

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI.sup.+ ion in alkali metal batteries.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Oing (Port Jefferson Station, NY); McBreen, James (Bellport, NY)

1998-08-04T23:59:59.000Z

392

Conversion of light hydrocarbon gases to metal carbides for production of liquid fuels and chemicals. Quarterly technical progress report, January 1--March 31, 1995  

DOE Green Energy (OSTI)

The methane plasma stabilization problem was resolved with the reconfiguration of the DC power supply to give a higher open circuit voltage to enable operation of the arc at higher voltage levels and with the installation of a solenoid around the plasma reactor to magnetically rotate the are. Cathode tip erosion problems were encountered with the 1/4-inch graphite and tungsten tips which necessitated a redesign of the plasma reactor. The new plasma reactor consists of an enlarged 3/4-inch O.D. graphite tip to reduce current density and a 1-inch I.D. graphite anode. Products from MgO/CH{sub 4} scoping runs in the redesigned reactor under conditions of excess MgO gave strong indications that a breakthrough has finally been achieved i.e. that synthesis of magnesium carbides from MgO and methane in the arc discharge reactor has been demonstrated. Significant quantities of hydrocarbons, primarily C{sub 3}H{sub 4} and C{sub 2}H{sub 2}, were detected in the headspace above hydrolyzed solid samples by GC analysis. In one run, solids glowed upon exposure to the atmosphere, strongly suggesting carbide reaction with moisture in the air, exothermically forming acetylenes which ignited instantaneously in the presence of oxygen and elevated temperatures arising from localized heat-up of the specimens.

Diaz, A.F.; Modestino, A.J.; Pride, J.D.; Howard, J.B.; Tester, J.W.; Peters, W.A.

1995-05-01T23:59:59.000Z

393

Hydrogen and elemental carbon production from natural gas and other hydrocarbons  

DOE Patents (OSTI)

Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

394

Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents  

Science Conference Proceedings (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

1997-09-01T23:59:59.000Z

395

The Use of Conditional Probability Functions and Potential Source Contribution Functions to Identify Source Regions and Advection Pathways of Hydrocarbon Emissions in Houston, Texas  

SciTech Connect

In this study, we demonstrate the utility of conditional probability functions (CPFs), potential source contribution functions (PSCFs), and hierarchical clustering analysis to identify the source region and transport pathways of hydrocarbons measured at five photochemical assessment monitoring stations (PAMS) near the Houston ship channel from June to October 2003. Over 50 volatile organic compound (VOC) concentrations were measured on the hourly collected samples. Routine surface observations of wind directions measured at each of the receptor sites were used extensively. We show that VOCs with similar CPF patterns likely have common transport pathways. This was established with the multivariate technique, which uses the hierarchical clustering analysis to allow clusters of groups of VOCs to form with similar CPF patterns. This method revealed that alkenes, and in particular those with geometric isomers such as cis-/trans-2-butene and cis-/trans-2-pentene, have similar CPF patterns. The alkane isomers often show CPF patterns among themselves, and similarly, aromatic compounds often show similar patterns among themselves too. We also show how trajectory information can be used in conjunction with the PSCF analysis to produce a graphic analysis suggesting specific source areas for a given VOC. The use of these techniques in the chemically and meteorologically complex environment of Houston, Texas, suggests its further utility in other areas with relatively simpler conditions.

Xie, YuLong; Berkowitz, Carl M.

2007-09-01T23:59:59.000Z

396

Marcellus natural gas pipeline projects to primarily benefit New ...  

U.S. Energy Information Administration (EIA)

On October 17, the Federal Energy Regulatory Agency (FERC) authorized the start of initial service on these expansions. New England consumers, however, ...

397

Measurment and Interpretation of Seismic Attenuation for Hydrocarbon Exploration  

Science Conference Proceedings (OSTI)

This research project is the combined effort of several leading research groups. Advanced theoretical work is being conducted at the Lawrence Berkeley National Laboratory. Here, the fundamental controls on loss mechanisms are being examined, primarily by use of numerical models of heterogeneous porous media. At the University of California, Berkeley, forward modeling is combined with direct measurement of attenuation. This forward modeling provides an estimate of the influence of 1/Q on the observed seismic signature. Direct measures of losses in Vertical Seismic Profiles (VSPs) indicate mechanisms to separate scattering versus intrinsic losses. At the Colorado School of Mines, low frequency attenuation measurements are combined with geologic models of deep water sands. ChevronTexaco is our corporate cosponsor and research partner. This corporation is providing field data over the Genesis Field, Gulf of Mexico. In addition, ChevronTexaco has rebuilt and improved their low frequency measurement system. Soft samples representative of the Genesis Field can now be measured for velocities and attenuations under reservoir conditions. Throughout this project we have: Assessed the contribution of mechanical compaction on time-lapse monitoring; Developed and tested finite difference code to model dispersion and attenuation; Heterogeneous porous materials were modeled and 1/Q calculated vs. frequency; 'Self-affine' heterogeneous materials with differing Hurst exponent modeled; Laboratory confirmation was made of meso-scale fluid motion influence on 1/Q; Confirmed theory and magnitude of layer-based scattering attenuation at Genesis and at a shallow site in California; Scattering Q's of between 40 and 80 were obtained; Measured very low intrinsic Q's (2-20) in a partially saturated vadose zone VSP; First field study to separate scattering and intrinsic attenuation in real data set; Revitalized low frequency device at ChevronTexaco's Richmond lab completed; First complete frequency dependent measurements on Berea sandstones from dry to various saturations (brine and decane); Frequency dependent forward modeling code is running, and tested on a couple of Cases--derives frequency dependent reflectivity from porosity based logs; Genesis seismic data obtained but is on hold until forward modeling is complete; Boundary and end effects modeled for soft material measurements at CSM; and Numerous papers published or submitted and presentations made.

Michael Batzle; Luca Duranti; James Rector; Steve Pride

2007-12-31T23:59:59.000Z

398

Pentan isomers compound flame front structure  

DOE Green Energy (OSTI)

The fuels (hexane, pentane, diethyl ether) and conditions investigated in this study are relevant to engine knock in spark- ignition engines. A review is provided of the field of low temperature hydrocarbon oxidation. Studies were made of radical and stable intermediate distribution in the front of cool flames: Maximum concentrations of H atoms and peroxy radicals were observed in the luminous zone of the cool flame front. Peroxy radicals appear before the luminous zone at 430 K due to diffusion. H atoms were found in cool flames of butane and hexane. H atoms diffuses from the luminous zone to the side of the fresh mixture, and they penetrate into the fresh mixture to a small depth. Extension of action sphear of peroxy radicals in the fresh mixture is much greater than that of H atoms due to their small activity and high concentrations.

Mansurov, Z.A.; Mironenko, A.W.; Bodikov, D.U.; Rachmetkaliev, K.N. [Kazakh Al-Farabi State National Univ., Almaty (Kazakhstan)

1995-08-13T23:59:59.000Z

399

Polymers containing borane or carborane cage compounds and related applications  

DOE Patents (OSTI)

Polymers comprising residues of cage compound monomers having at least one polyalkoxy silyl substituent are provided. The cage compound monomers are selected from borane cage compound monomers comprising at least 7 cage atoms and/or carborane cage compound monomers comprising 7 to 11 cage compound monomers. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Articles of manufacture comprising such polymers are also disclosed.

Bowen, III, Daniel E; Eastwood, Eric A

2013-04-23T23:59:59.000Z

400

Petrographic, Mineralogic, and Geochemical Studies of Hydrocarbon-derived Authigenic Carbonate Rock from Gas Venting, Seepage, Free Gas, and Gas Hydrate Sites in the Gulf of Mexico and offshore India  

E-Print Network (OSTI)

Authigenic carbonate rock (ACR) is derived from microbial oxidation of methane, biodegradation of crude oil, and oxidation of sedimentary organic matter. The precipitation of ACR was characterized petrographically, mineralogically, and geochemically. ACR collected from the seafloor in the Gulf of Mexico (GOM) and ACR recovered from drilled cores in the Krishna-Godawari (KG) basin offshore India were used. All study sites are associated with hydrocarbon gas venting, seepage, free gas, or gas hydrate. ACR from the GOM is densely cemented and extremely irregular in shape, whereas ACR from offshore India is generally an oval-shaped smooth nodule and also densely cemented. The dominant mineral in ACR is authigenic calcite. ACR contains carbon derived from sedimentary organic carbon oxidation that geologically sequesters much fossil carbon. Bulk carbon and oxygen isotopes of ACR were measured. ACR from the GOM is strongly depleted in 13C with ?13C of ?42.5? and enriched in 18O with ?18O of 4.67?. The ?13C of hydrocarbon is typically more depleted in 13C than in the associated ACR. The reason is that authigenic carbonate cements from hydrocarbon oxidation generally enclose skeletal material characterized by normal marine carbonate. Three groups that represent different hydrocarbon sources to ACR were classified in this study: primary carbon sources to ACR from (1) methane plus biodegraded oil, (2) methane, or (3) biodegraded oil. Wide ranges in ?13C (?49.12 to 14.06?) and ?18O ( 1.27 to 14.06?) were observed in ACR from offshore India. In sediments, the ?13C may be affected by differences in the rate of organic carbon oxidation, which generate varying ?13C with depth during methanogenesis. Based on the wide range in ?13C, ACR from offshore India was classified: (1) ?13C may reflect high rates of organic carbon oxidation, (2) ACR may be derived primarily from methane oxidation, and (3) ?13C may reflect low rates of organic carbon oxidation. ?18O values are heavier than those of normal marine carbonates. The ?18O may be caused by reaction with deep-sourced water that was isotopically heavier than ambient seawater. Some samples may reflect heavy ?18O from gas hydrate decomposition, but it would not cause significant heavy oxygen isotopes.

Jung, Woodong

2008-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)  

E-Print Network (OSTI)

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide, and 13C NMR spectroscopic studies of 6Li-15N labeled lithium hexamethyldisilazide ([6Li,15N]- Li ligand structure and lithium amide aggregation state is a complex and sensitive function of amine alkyl

Collum, David B.

402

Mobilization of trace elements in aquifers by biodegradation of hydrocarbon contaminants. Master Thesis  

Science Conference Proceedings (OSTI)

This study had two objectives: (1) to determine the extent of metal mobility within petroleum-contaminated aquifers, (2) to determine if biodegradation of petroleum hydrocarbons can explain metal mobility. The approach reviewed analytical results from 2305 groundwater sampling events, taken from 958 wells, located at 136 sites found at 53 Air Force installations. The study showed that high levels of metals are present at petroleum hydrocarbon sites where metals would not generally be expected. Of the metals with drinking water maximum contaminant levels (MCLs), mercury and silver were detected the least frequently. Barium and copper were detected at the sites, but fewer than 2.5 percent of the samples exceeded their MCLs. All other metals exceeded their MCLs in at least 2.5 percent of the samples, with antimony and lead exceeding their MCLs in 19 percent and 10 percent of samples, respectively. Higher concentrations of barium and manganese were most strongly correlated with petroleum hydrocarbon contamination, and relatively strong correlations also existed for aluminum, arsenic, iron, and lead. Major cations such as calcium, magnesium, sodium and potassium were least affected by petroleum hydrocarbons concentrations.

Kearney, S.L.

1997-12-01T23:59:59.000Z

403

Continental margin subsidence and heat flow: important parameters in formation of petroleum hydrocarbons  

Science Conference Proceedings (OSTI)

Passive continental margins have been shown to subside with a 50-My exponentially decaying rate which cannot be explained by isostatic compensation for sediment loading. This suggests that the subsidence is dominated by geodynamic processes similar to those in the deep ocean. Two simple geologic models for continental breakup are developed: (1) attenuation of continental lithosphere; and (2) intrusion of mantle diapirs. These models for rifting give a direct relation between subsidence of passive margins and their surface heat flow through time. On this basis we develop a method of reconstructing the thermal history of sedimentary strata from regional subsidence and sedimentation history. Because generation of petroleum hydrocarbons depends on the intergrated time/temperature history of buried organic material, this reconstruction technique can be used to determine the depth to the oil range of the hydrocarbon generation window in advance of drilling. By way of example, we reconstruct time/temperature/depth plots and estimate hydrocarbon maturity for one site in the Falkland Plateau and three sites in the North Atlantic near Cape Hatteras. In addition to providing a method for evaluating hydrocarbon potential in frontier regions where there is little or no well control, this approach suggests that there may be significant potential for oil and gas generation on the outer part of the continental rise and in deep-sea sedimentary basins. 13 figures, 1 table.

Royden, L. (Massachusetts Inst. of Tech., Cambridge); Sclater, J.G.; Von Herzen, R.P.

1980-02-01T23:59:59.000Z

404

Hydrocarbon rate coefficients for proton and electron impact ionization, dissociation, and recombination in a hydrogen plasma.  

DOE Green Energy (OSTI)

We estimate cross sections and rate coefficients for proton and electron impact ionization, dissociation, and recombination of neutral and ionized hydrocarbon molecules and fragments of the form C{sub x}H{sub y}{sup k}, x = 1-3, y = 1-6, k = 0,1 in a thermalized hydrogen-electron plasma.

Alman, D.A.; Brooks, J.N.; Ruzic, D.N.; Wang, Z.

1999-07-21T23:59:59.000Z

405

Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation  

E-Print Network (OSTI)

to reduce volume, remove pathogens, and to gain energy. Anaerobic digestion is by far the most commonRemoval of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N treatment in a wastewater treatment plant. They therefore proceed directly to the anaerobic post treatment

406

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons  

E-Print Network (OSTI)

BP Oil Spill and Air Chemistry Crude oil contains various hydrocarbons NOAA and CIRES here at CU went to the oil spill in an aircraft that was equipped with instruments to measure the air quality. 1/3 of the oil dissolved into the water column (methane completely, benzene and ethane almost completely) Showed

Toohey, Darin W.

407

DETERMINATION OF SOLID-LIQUID EQUILIBRIA DATA FOR MIXTURES OF HEAVY HYDROCARBONS IN A LIGHT SOLVENT  

Science Conference Proceedings (OSTI)

A methodology was developed using an FT-IR spectroscopic technique to obtain solid-liquid equilibria (SLE) data for mixtures of heavy hydrocarbons in significantly lighter hydrocarbon diluents. SLE was examined in multiple Model Oils that were assembled to simulate waxes. The various Model oils were comprised of C-30 to C-44 hydrocarbons in decane. The FT-IR technique was used to identify the wax precipitation temperature (WPT). The DSC technique was also used in the identification of the onset of the two-phase equilibrium in this work. An additional Model oil made up of C-20 to C-30 hydrocarbons in decane was studied using the DSC experiment. The weight percent solid below the WPT was calculated using the FT-IR experimental results. The WPT and the weight percent solid below the WPT were predicted using an activity coefficient based thermodynamic model. The FT-IR spectroscopy method is found to successfully provide SLE data and also has several advantages over other laboratory-based methods.

F.V. Hanson; J.V. Fletcher; Karthik R.

2003-06-01T23:59:59.000Z

408

Sliding mode control of a hydrocarbon degradation in biopile system using recurrent neural network model  

Science Conference Proceedings (OSTI)

This paper proposes the use of a Recurrent Neural Network (RNN) for modeling a hydrocarbon degradation process carried out in a biopile system. The proposed RNN model represents a Kalman-like filter and it has seven inputs, five outputs and twelve neurons ...

Ieroham Baruch; Carlos-Roman Mariaca-Gaspar; Israel Cruz-Vega; Josefina Barrera-Cortes

2007-11-01T23:59:59.000Z

409

Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons  

DOE Patents (OSTI)

An improved process for separating hydrogen from hydrocarbons. The process includes a pressure swing adsorption step, a compression/cooling step and a membrane separation step. The membrane step relies on achieving a methane/hydrogen selectivity of at least about 2.5 under the conditions of the process.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

2001-01-01T23:59:59.000Z

410

MathematicalModelingofCarbonDioxide(CO2)Injection intheSubsurfaceforImprovedHydrocarbonRecoveryand  

E-Print Network (OSTI)

and Environmental Engineering, Yale University, New Haven, CT 06511, USA World Energy Demand Global energy demand from fossil fuels is expected to remain over 70% in 2035 [1]. Society must balance its high demand, CA, USA). Carbon Dioxide Injection for Improved Hydrocarbon Recovery Simulation of diffusion

Firoozabadi, Abbas

411

Solution mining and heating by oxidation for treating hydrocarbon containing formations  

DOE Patents (OSTI)

A method for treating an oil shale formation comprising nahcolite includes providing a first fluid to a portion of the formation. A second fluid is produced from the portion. The second fluid includes at least some nahcolite dissolved in the first fluid. A controlled amount of oxidant is provided to the portion of the formation. Hydrocarbon fluids are produced from the formation.

Vinegar, Harold J. (Bellaire, TX); Stegemeier, George Leo (Houston, TX)

2009-06-23T23:59:59.000Z

412

2008 Special Issue: An adaptive method for industrial hydrocarbon flame detection  

Science Conference Proceedings (OSTI)

An adaptive method for an infrared (IR) hydrocarbon flame detection system is presented. The model makes use of joint time-frequency analysis (JTFA) for feature extraction and the artificial neural networks (ANN) for training and classification. Multiple ... Keywords: Artificial neural networks, Flame detection, Signal processing

Javid J. Huseynov; Shankar B. Baliga; Alan Widmer; Zvi Boger

2008-03-01T23:59:59.000Z

413

On-Line Measurement of Heat of Combustion of Gaseous Hydrocarbon Fuel Mixtures  

Science Conference Proceedings (OSTI)

A method for the on-line measurement of the heat of combustion of gaseous hydrocarbon fuel mixtures has been developed and tested. The method involves combustion of a test gas with a measured quantity of air to achieve a preset concentration of oxygen ...

Sprinkle Danny R.; Chaturvedi Sushil K.; Kheireddine Ali

1996-03-01T23:59:59.000Z

414

Compound and Elemental Analysis At Salt Wells Area (Shevenell...  

Open Energy Info (EERE)

Compound and Elemental Analysis At Salt Wells Area (Shevenell & Garside, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and...

415

Alloys and Compounds for Thermoelectric and Solar Cell Applications  

Science Conference Proceedings (OSTI)

Alloys and Compounds for Thermoelectric and Solar Cell Applications II: Alloys and Compounds for Thermoelectric and Solar Cell Applications: Thermoelectric I

416

Energy-efficient indoor volatile organic compound air cleaning...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy-efficient indoor volatile organic compound air cleaning using activated carbon fiber media with nightly regeneration Title Energy-efficient indoor volatile organic compound...

417

Compound and Elemental Analysis At Black Warrior Area (DOE GTP...  

Open Energy Info (EERE)

Compound and Elemental Analysis At Black Warrior Area (DOE GTP) Exploration Activity Details Location Black Warrior Area Exploration Technique Compound and Elemental Analysis...

418

Compound and Elemental Analysis At Wister Area (DOE GTP) | Open...  

Open Energy Info (EERE)

Compound and Elemental Analysis At Wister Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At...

419

Studies on multi-phase equilibrium separation of hydrocarbon/water systems  

E-Print Network (OSTI)

Equations of State (EOS) have been used successfully in compositional simulators to describe phase behavior of reservoir crude and gas condensates without water. The three-phase behavior of water/reservoir crude oils both at reservoir and steam flooding temperature has not yet been successfully predicted by an EOS. Recent publications show that incorporation of the association concept into simple cubic equations such as Peng-Robinson EOS significantly improves phase behavior prediction of water/hydrocarbon and nonhydrate systems, but there are still some numerical difficulties in the pre-diction of three phase flash equilibria. In this thesis we presented, an efficient procedure that will help us eliminate common numerical difficulties in predicting three-phase equilibria for systems containing water, and simplify the programming technique. This scheme checks the existence of three-phase flash at given reservoir conditions, and if three-phase flash (vapor-oleic-aqueous) doesn't exist, it automatically switches to check correct type of two-phase flash (vapor-oleic, vapor-aqueous, or oleic-aqueous). This convergence scheme is used in an EOS-simulator (VLLESIM), which uses nine different EOS's and van der Waals mixing rules, to accurately describe multi-phase equilibrium separation of hydrocarbon/water systems. VLLESIM will be validated with literature data and experimental results obtained from two different experimental setups, for different multi-component hydrocarbon/water systems, for hydrocarbon component varying from C6 to C20. PVT-VLLE apparatus can provide on-line compositional analysis and phase volumes of all equilibrium phases for temperatures up to 350 'F and an Isochoric Steam Distillation Cell (ISDC) can provide only vapor phase compositions, but it can be used up to 500 'F. VLLESIM will then be used to study the effect of temperature, pressure and molecular weight of hydrocarbon components on multiphase equilibria of different hydrocarbon/water systems. Detailed analysis is also provided in this thesis, of the effect of increasing concentration of different hydrocarbon components on the size of the three-phase region for ranges of temperature and pressure mostly prevalent under reservoir conditions.

Chawla, Inderjit Singh

1995-01-01T23:59:59.000Z

420

Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds  

SciTech Connect

There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

Wang, Huamin; Male, Jonathan L.; Wang, Yong

2013-05-01T23:59:59.000Z

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We encourage you to perform a real-time search of NLEBeta
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421

Hydrocarbon anomaly in soil gas as near-surface expressions of upflows and outflows in geothermal systems  

SciTech Connect

A variety of hydrocarbons, C1 - C12, have been found in volcanic gases (fumarolic) and in geothermal waters and gases. The hydrocarbons are thought to have come from products of pyrolysis of kerogen in sedimentary rocks or they could be fed into the geothermal system by the recharging waters which may contain dissolved hydrocarbons or hydrocarbons extracted by the waters from the rocks. In the hot geothermal zone, 300°+ C, many of these hydrocarbons are in their critical state. It is thought that they move upwards due to buoyancy and flux up with the upflowing geothermal fluids in the upflow zones together with the magmatic gases. Permeability which could be provided by faults, fissures, mini and micro fractures are thought to provide pathways for the upward flux. A sensitive technique (Petrex) utilizing passive integrative adsorption of the hydrocarbons in soil gas on activated charcoal followed by desorption and analysis of the hydrocarbons by direct introduction mass spectrometry allows mapping of the anomalous areas. Surveys for geothermal resources conducted in Japan and in Indonesia show that the hydrocarbon anomaly occur over known fields and over areas strongly suspected of geothermal potential. The hydrocarbons found and identified were n-paraffins (C7-C9) and aromatics (C7-C8). Detection of permeable, i.e. active or open faults, parts of older faults which have been reactivated, e.g. by younger intersecting faults, and the area surrounding these faulted and permeable region is possible. The mechanism leading to the appearance of the hydrocarbon in the soil gas over upflow zones of the geothermal reservoir is proposed. The paraffins seems to be better pathfinders for the location of upflows than the aromatics. However the aromatics may, under certain circumstances, give better indications of the direction of the outflow of the geothermal system. It is thought that an upflow zone can be defined when conditions exist where the recharging waters containing the hydrocarbons feed into the geothermal kitchen. The existence of open and active faults, fissures, mini and micro fractures allow sufficient permeability for the gases to flux up and express themselves at the surface as hydrocarbon anomaly in the soil gas. When any of the requirements is absent, i.e. in the absence of the recharging waters, hydrocarbons, temperature, or permeability, no anomaly can be expected. It assumes a dynamic convective system, i.e. recharging waters, upflow and outflow. The anomalies however can define to a certain extent, regions of geothermal upflow, buoyant transport of gases, and frequently down-gradient of cooling waters.

Ong, H.L.; Higashihara, M.; Klusman, R.W.; Voorhees, K.J.; Pudjianto, R.; Ong, J

1996-01-24T23:59:59.000Z

422

Hydrocarbon anomaly in soil gas as near-surface expressions of upflows and outflows in geothermal systems  

Science Conference Proceedings (OSTI)

A variety of hydrocarbons, C1 - C12, have been found in volcanic gases (fumarolic) and in geothermal waters and gases. The hydrocarbons are thought to have come from products of pyrolysis of kerogen in sedimentary rocks or they could be fed into the geothermal system by the recharging waters which may contain dissolved hydrocarbons or hydrocarbons extracted by the waters from the rocks. In the hot geothermal zone, 300°+ C, many of these hydrocarbons are in their critical state. It is thought that they move upwards due to buoyancy and flux up with the upflowing geothermal fluids in the upflow zones together with the magmatic gases. Permeability which could be provided by faults, fissures, mini and micro fractures are thought to provide pathways for the upward flux. A sensitive technique (Petrex) utilizing passive integrative adsorption of the hydrocarbons in soil gas on activated charcoal followed by desorption and analysis of the hydrocarbons by direct introduction mass spectrometry allows mapping of the anomalous areas. Surveys for geothermal resources conducted in Japan and in Indonesia show that the hydrocarbon anomaly occur over known fields and over areas strongly suspected of geothermal potential. The hydrocarbons found and identified were n-paraffins (C7-C9) and aromatics (C7-C8). Detection of permeable, i.e. active or open faults, parts of older faults which have been reactivated, e.g. by younger intersecting faults, and the area surrounding these faulted and permeable region is possible. The mechanism leading to the appearance of the hydrocarbon in the soil gas over upflow zones of the geothermal reservoir is proposed. The paraffins seems to be better pathfinders for the location of upflows than the aromatics. However the aromatics may, under certain circumstances, give better indications of the direction of the outflow of the geothermal system. It is thought that an upflow zone can be defined when conditions exist where the recharging waters containing the hydrocarbons feed into the geothermal kitchen. The existence of open and active faults, fissures, mini and micro fractures allow sufficient permeability for the gases to flux up and express themselves at the surface as hydrocarbon anomaly in the soil gas. When any of the requirements is absent, i.e. in the absence of the recharging waters, hydrocarbons, temperature, or permeability, no anomaly can be expected. It assumes a dynamic convective system, i.e. recharging waters, upflow and outflow. The anomalies however can define to a certain extent, regions of geothermal upflow, buoyant transport of gases, and frequently down-gradient of cooling waters.

Ong, H.L.; Higashihara, M.; Klusman, R.W.; Voorhees, K.J.; Pudjianto, R.; Ong, J

1996-01-24T23:59:59.000Z

423

SEPARATION PROCESS FOR ZIRCONIUM AND COMPOUNDS THEREOF  

DOE Patents (OSTI)

The separation of zirconium from columbium, rare earths, yttrium and the alkaline earth metals, such mixtures of elements occurring in zirconium ores or neutron irradiated uranium is described. According to the invention a suitable separation of zirconium from a one normal acidic aqueous solution containing salts, nitrates for example, of tetravalent zirconium, pentavalent columbium, yttrium, rare earths in the trivalent state and alkaline earths can be obtained by contacting the aqueous solution with a fluorinated beta diketonc alone or in an organic solvent solution, such as benzene, to form a zirconium chelate compound. When the organic solvent is present the zirconium chelate compound is directly extracted; otherwise it is separated by filtration. The zirconium may be recovered from contacting the organic solvent solution containing the chelated compound by back extraction with either an aqueous hydrofluoric acid or an oxalic acid solution.

Crandall, H.W.; Thomas, J.R.

1959-06-30T23:59:59.000Z

424

Polycyclic aromatic hydrocarbon emission profiles and removal efficiency by electrostatic precipitator and wetfine scrubber in an iron ore sintering plant  

Science Conference Proceedings (OSTI)

A monitoring campaign of polychlorinated dibenzo-p-dioxins and dibenzofurans, polyaromatic hydrocarbons (PAHs), and polychlorinated biphenyl was carried out in an Italian iron ore sintering plant by sampling the combustion gases at the electrostatic precipitator (ESP) outlet, at the Wetfine scrubber (WS) outlet, and by collecting the ESP dust. Few data are available on these micropollutants produced in iron ore sintering plants, particularly from Italian plants. This study investigates the PAH emission profiles and the removal efficiency of ESPs and WS. PAHs were determined at the stack, ESP outlet flue gases, and in ESP dust to characterize the emission profiles and the performance of the ESP and the WS for reducing PAH emission. The 11 PAHs monitored are listed in the Italian legislative decree 152/2006. The mean total PAH sum concentration in the stack flue gases is 3.96 {mu}g/N m{sup 3}, in ESP outlet flue gases is 9.73 {mu}g/N m{sup 3}, and in ESP dust is 0.53 {mu}g/g. Regarding the emission profiles, the most abundant compound is benzo(b)fluoranthene, which has a relative low BaP toxic equivalency factors (TEF) value, followed by dibenzo(a,l)pyrene, which has a very high BaP(TEF) value. The emission profiles in ESP dust and in the flue gases after the ESP show some changes, whereas the fingerprint in ESP and stack flue gases is very similar. The removal efficiency of the ESP and of WS on the total PAH concentration is 5.2 and 59.5%, respectively. 2 figs., 5 tabs.

Ettore Guerriero; Antonina Lutri; Rosanna Mabilia; Maria Concetta Tomasi Sciano; Mauro Rotatori [Istituto sull'Inquinamento Atmosferico, Monterotondo Scalo (Italy). Consiglio Nazionale delle Ricerche

2008-11-15T23:59:59.000Z

425

Direct catalytic conversion of methane and light hydrocarbon gases. Quarterly report No. 7, April 16, 1988--July 15, 1988  

DOE Green Energy (OSTI)

The goal of this research is to develop catalysts that directly convert methane and light hydrocarbons to intermediates that later can be converted to either liquid fuels or value-added chemicals, as economics dictate. During this reporting period, much of our effort focused on investigating the stability of the methane reforming catalysts (Task 2) with respect to storage time. Many of these catalysts demonstrated lessened activity when they were reexamined up to 18 months after they ere first synthesized and tested. We also synthesized and tested two new phthalocyanines supported on magnesia (MgO) for examination in the methane oxidation reaction. We reexamined many of the hexaruthenium and tetraruthenium clusters which had been supported on zeolite Y, zeolite 5A, alumina or magnesia. These reexaminations were conducted at relatively slow flow rates (15 ml/min), since previous studies had shown that the lower flow rates maximized the conversion of methane in this reaction. In every case, the catalyst exhibited diminished activity compared to the earlier runs. In addition, the selectivity of the catalysts changed as well; relatively less C{sub 2} and no C{sub 6} was observed in the reactions conducted during this reporting period. In the previous technical report we reported that palladium tetrasulfophthalocyanine (PDTSPC) supported on MgO exhibited exceptional activity in the methane oxidation reaction; it produced ethane at much lower temperatures than previously reported in the literature. We synthesized two close analogues of this compound, one with a different metal (nickel) from the same family as palladium, and the other with a different substituent (carboxylic acid rather than sulfonic acid) on the phthalocyanine ring. Both of these complexes were supported on magnesia, and tested for activity. The nickel complex displayed some activity, producing only carbon dioxide and water.

Wilson, R.B. Jr.; Chan, Yee Wai; Posin, B.M.

1988-08-31T23:59:59.000Z

426

Transformation of Acetone and Isopropanol to Hydrocarbons using HZSM-5 Catalyst  

E-Print Network (OSTI)

This research describes the production of hydrocarbons from acetone and isopropanol produced by the MixAlco process. The MixAlco process has two types of products: acetone and isopropanol. The effect of the temperature, weight hourly space velocity (WHSV), type of catalyst, feed composition, and pressure are studied. For the isopropanol reaction, the following conditions were used: HZSM-5 (280), 1 atm, 300–410°C, and 0.5–11.5 h–1, respectively. The temperature and WHSV affect the average carbon number of the reaction products. A product similar to commercial gasoline was obtained at T = 320 °C and WHSV= 1.3 to 2.7 h–1. Also, at these conditions, the amount of light hydrocarbons (C1–C4) is low. For the acetone reaction, the following conditions were used: HZSM-5 with silica alumina ratio (Si/Al) 80 and 280 mol silica/mol alumina, 1–7.8 atm, 305–415°C, 1.3–11.8 h–1, and hydrogen acetone ratio 0–1 mol H2 /mol acetone. The conversion on HZSM-5 (80) was higher than HZSM-5 (280); however, for HZM–5 (80) the production of light hydrocarbons (C1–C4) was more abundant than (280), and it formed less coke. For acetone, the effect of high pressure (P = 7.8 atm) was evaluated. At high pressure, the conversion was lower than at atmospheric pressure. HZSM-5 (280) rapidly deactivated, and the amount of light hydrocarbons (C1–C4) increased. For acetone, co-feeding hydrogen inhibited coke formation and decreased the amount of light hydrocarbons (C1–C4).

Taco Vasquez, Sebastian

2009-12-01T23:59:59.000Z

427

Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .  

DOE Green Energy (OSTI)

The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

Wallner, T. (Energy Systems)

2011-08-01T23:59:59.000Z

428

ASSESSMENT OF HYDROCARBON SEEPAGE DETECTION METHODS ON THE FORT PECK RESERVATION, NORTHEAST MONTANA  

Science Conference Proceedings (OSTI)

Surface exploration techniques have been employed in separate study areas on the Fort Peck Reservation in northeastern Montana. Anomalies associated with hydrocarbon seepage are documented in all three areas and a variety of surface exploration techniques can be compared. In a small area with established production, Head Gas and Thermal Desorption methods best match production; other methods also map depletion. In a moderate-size area that has prospects defined by 3D seismic data, Head Gas along with Microbial, Iodine, and Eh soil anomalies are all associated with the best hydrocarbon prospect. In a large area that contains many curvilinear patterns observed on Landsat images, that could represent micro-seepage chimneys, results are inconclusive. Reconnaissance mapping using Magnetic Susceptibility has identified a potential prospect; subsequent Soil Gas and Head Gas surveys suggest hydrocarbon potential. In the final year of this project the principle contractor, the Fort Peck Tribes, completed a second survey in the Wicape 3D Seismic Prospect Area (also known as Area 6 in Phase I of the project) and sampled several Landsat image features contained in the Smoke Creek Aeromag Anomaly Area (also known as Area 1 in Phase II of the project). Methods determined to be most useful in Phases I and II, were employed in this final Phase III of the study. The Southwest Wicape seismic anomaly was only partially confirmed. The abundant curvilinears proposed to be possible hydrocarbon micro-seepage chimneys in the Smoke Creek Area were not conclusively verified as such. Insufficient sampling of background data precludes affirmative identification of these mostly topographic Landsat features as gas induced soil and vegetation anomalies. However relatively higher light gas concentrations were found associated with some of the curvilinears. Based on the findings of this work the Assiniboine & Sioux Tribes of the Fort Peck Reservation intend to utilize surface hydrocarbon exploration techniques for future identification and confirmation of oil and gas prospects.

Lawrence M. Monson

2003-06-30T23:59:59.000Z

429

Inelastic neutron scattering in valence fluctuation compounds  

SciTech Connect

The valence fluctuation compounds are rare earth intermetallics where hybridization of the nearly-localized 4f electrons with the conduction electrons leads to incorporation of the 4f's into the itinerant states. This hybridization slows down the conduction electrons and hence gives them a heavy effective mass, justifying application of the term 'heavy Fermion' (HF) to these materials. During the project period, we grew large single crystals of several such compounds and measured their properties using both standard thermodynamic probes and state-of-the-art inelastic neutron scattering. We obtained three main results. For the intermediate valence compounds CePd{sub 3} and YbAl{sub 3}, we showed that the scattering of neutrons by the fluctuations of the 4f magnetic moment does not have the momentum dependence expected for the itinerant heavy mass state; rather, the scattering is more typical of a localized spin fluctuation. We believe that incoherent scattering localizes the excitation. For the heavy Fermion compound Ce(Ni{sub 0.935}Pd{sub 0.065}){sub 2}Ge{sub 2}, which sits at a T = 0 critical point for transformation into an antiferromagnetic (AF) phase, we showed that the scattering from the AF fluctuations does not exhibit any of the divergences that are expected at a phase transition. We speculate that alloy disorder profoundly suppresses the growth of the fluctuating AF regions, leading to short range clusters rather than regions of infinite size. Finally, we explored the applicability of key concepts used to describe the behavior of rare earth heavy Fermions to uranium based HF compounds where the 5f electrons are itinerant as opposed to localized. We found that scaling laws relating the spin fluctuation energy measured in neutron scattering to the low temperature specific heat and susceptibility are valid for the uranium compounds, once corrections are made for AF fluctuations; however, the degeneracy of the high temperature moment is smaller than expected for rare-earth-like Hund's rule behavior, essentially because the orbital moment is suppressed for itinerant 5f electrons. We also found that the standard local-moment-based theory of the temperature dependence of the specific heat, susceptibility and neutron scattering fails badly for URu{sub 2}Zn{sub 20} and UCo{sub 2}Zn{sub 20}, even though the theory is phenomenally successful for the closely related rare earth compound YbFe{sub 2}Zn{sub 20}. Both these results highlight the distinction between the itineracy of the 5f's and the localization of the 4f's. It is our hope that these results are sufficiently significant as to stimulate deeper investigation of these compounds.

Jon M Lawrence

2011-02-15T23:59:59.000Z

430

Process for producing phenolic compounds from lignins  

DOE Patents (OSTI)

A process is described for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400 C to about 600 C at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1--3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof. 16 figs.

Agblevor, F.A.

1998-09-15T23:59:59.000Z

431

Organic photosensitive devices using subphthalocyanine compounds  

DOE Patents (OSTI)

An organic photosensitive optoelectronic device, having a donor-acceptor heterojunction of a donor-like material and an acceptor-like material and methods of making such devices is provided. At least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound; and/or the device optionally has at least one of a blocking layer or a charge transport layer, where the blocking layer and/or the charge transport layer includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound.

Rand, Barry (Princeton, NJ); Forrest, Stephen R. (Ann Arbor, MI); Mutolo, Kristin L. (Hollywood, CA); Mayo, Elizabeth (Alhambra, CA); Thompson, Mark E. (Anaheim Hills, CA)

2011-07-05T23:59:59.000Z

432

Process for producing phenolic compounds from lignins  

DOE Patents (OSTI)

A process for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400.degree. C. to about 600.degree. C. at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1-3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof.

Agblevor, Foster A. (Lakewood, CO)

1998-01-01T23:59:59.000Z

433

Quantitative Changes in Hydrocarbons over Time in Fecal Pellets of Incisitermes minor May Predict Whether Colonies Are Alive or Dead  

E-Print Network (OSTI)

# The Author(s) 2010. This article is published with open access at Springerlink.com Abstract Hydrocarbon mixtures extracted from fecal pellets of drywood termites are species-specific and can be characterized to identify the termites responsible for damage, even when termites are no longer present or are unable to be recovered easily. In structures infested by drywood termites, it is common to find fecal pellets, but difficult to sample termites from the wood. When fecal pellets appear after remedial treatment of a structure, it is difficult to determine whether this indicates that termites in the structure are still alive and active or not. We examined the hydrocarbon composition of workers, alates, and soldiers of Incisitermes minor (Hagen) (family Kalotermitidae) and of fecal pellets of workers. Hydrocarbons were qualitatively similar among castes and pellets. Fecal pellets that were aged for periods of 0, 30, 90, and 365 days after collection were qualitatively similar across all time periods, however, the relative quantities of certain individual hydrocarbons changed over time, with 19 of the 73 hydrocarbon peaks relatively increasing or decreasing. When the sums of the positive and negative slopes of these 19 hydrocarbons were indexed, they produced a highly significant linear correlation (R 2 =0.89). Consequently, the quantitative differences of these hydrocarbons peaks can be used to determine the age of worker fecal pellets, and thus help determine whether the colony that produced them is alive or dead.

Vernard R. Lewis; Lori J. Nelson; Michael I. Haverty; James A. Baldwin

2010-01-01T23:59:59.000Z

434

On the Insignificance of Photochemical Hydrocarbon Aerosols in the Atmospheres of Close-in Extrasolar Giant Planets  

E-Print Network (OSTI)

The close-in extrasolar giant planets (CEGPs) reside in irradiated environments much more intense than that of the giant planets in our solar system. The high UV irradiance strongly influences their photochemistry and the general current view believed that this high UV flux will greatly enhance photochemical production of hydrocarbon aerosols. In this letter, we investigate hydrocarbon aerosol formation in the atmospheres of CEGPs. We find that the abundances of hydrocarbons in the atmospheres of CEGPs are significantly less than that of Jupiter except for models in which the CH$_4$ abundance is unreasonably high (as high as CO) for the hot (effective temperatures $\\gtrsim 1000$ K) atmospheres. Moreover, the hydrocarbons will be condensed out to form aerosols only when the temperature-pressure profiles of the species intersect with the saturation profiles--a case almost certainly not realized in the hot CEGPs atmospheres. Hence our models show that photochemical hydrocarbon aerosols are insignificant in the atmospheres of CEGPs. In contrast, Jupiter and Saturn have a much higher abundance of hydrocarbon aerosols in their atmospheres which are responsible for strong absorption shortward of 600 nm. Thus the insignificance of photochemical hydrocarbon aerosols in the atmospheres of CEGPs rules out one class of models with low albedos and featureless spectra shortward of 600 nm.

Mao-Chang Liang; Sara Seager; Christopher D. Parkinson; Anthony Y. -T; . Lee; Yuk L. Yung

2004-02-25T23:59:59.000Z

435

Recovery of semi-volatile organic compounds during sample preparation: Compilation for characterization of airborne particulate matter  

DOE Green Energy (OSTI)

Semi-volatile compounds present special analytical challenges not met by conventional methods for analysis of ambient particulate matter (PM). Accurate quantification of PM-associated organic compounds requires validation of the laboratory procedures for recovery over a wide volatility and polarity range. To meet these challenges, solutions of n-alkanes (nC{sub 12} to nC{sub 40}) and polycyclic aromatic hydrocarbons PAHs (naphthalene to benzo[ghi]perylene) were reduced in volume from a solvent mixture (equal volumes of hexane, dichloromethane and methanol), to examine recovery after reduction in volume. When the extract solution volume reached 0.5 mL the solvent was entirely methanol, and the recovery averaged 60% for n-alkanes nC{sub 12} to nC{sub 25} and PAHs from naphthalene to chrysene. Recovery of higher MW compounds decreased with MW, because of their insolubility in methanol. When the walls of the flasks were washed with 1 mL of equal parts hexane and dichloromethane (to reconstruct the original solvent composition), the recovery of nC{sub 18} and higher MW compounds increased dramatically, up to 100% for nC{sub 22}-nC{sub 32} and then slowly decreasing with MW due to insolubility. To examine recovery during extraction of the components of the High Capacity Integrated Gas and Particle Sampler, the same standards were used to spike its denuders and filters. For XAD-4 coated denuders and filters, normalized recovery was > 95% after two extractions. Recovery from spiked quartz filters matched the recovery from the coated surfaces for alkanes nC{sub 18} and larger, and for fluoranthene and larger PAHs. Lower MW compounds evaporated from the quartz filter with the spiking solvent. This careful approach allowed quantification of organics by correcting for volatility- and solubility-related sample preparation losses. This method is illustrated for an ambient sample collected with this sampler during the Texas Air Quality Study 2000.

Swartz, Erick; Stockburger, Leonard; Gundel, Lara

2002-05-01T23:59:59.000Z

436

Fluorescent compounds for plastic scintillation applications  

SciTech Connect

Several 2-(2{prime}-hydroxyphenyl)benzothiazole, -benzoxazole, and -benzimidazole derivatives have been prepared. Transmittance, fluorescence, light yield, and decay time characteristics of these compounds have been studied in a polystyrene matrix and evaluated for use in plastic scintillation detectors. Radiation damage studies utilizing a {sup 60}C source have also been performed.

Pla-Dalmau, A.; Bross, A.D.

1994-04-01T23:59:59.000Z

437

Pyrolysis mechanisms of lignin model compounds  

DOE Green Energy (OSTI)

The flash vacuum pyrolysis of lignin model compounds was studied under conditions optimized for the production of liquid products to provide mechanistic insight into the reaction pathways that lead to product formation. The major reaction products can be explained by cleavage of the C-O either linkage by a free radial or concerted 1,2-elimination.

Britt, P.F.; Buchanan, A.C. III; Cooney, M.J.

1997-06-01T23:59:59.000Z

438

Compound nucleus studies withy reverse kinematics  

SciTech Connect

Reverse kinematics reactions are used to demonstrate the compound nucleus origin of intermediate mass particles at low energies and the extension of the same mechanism at higher energies. No evidence has appeared in our energy range for liquid-vapor equilibrium or cold fragmentation mechanisms. 11 refs., 12 figs.

Moretto, L.G.

1985-06-01T23:59:59.000Z

439

PRODUCTION OF URANIUM AND THORIUM COMPOUNDS  

DOE Patents (OSTI)

Compounds of Th and U are extracted with an organic solvent in the presence of an adsorbent substance which has greater retentivity for impurities present than for the uranium and/or thorium. The preferred adsorbent material is noted as being cellulose. The uranium and thoriumcontaining substances treated are preferably in the form of dissolved nitrates, and the preferred organic solvent is diethyl ether.

Arden, T.V.; Burstall, F.H.; Linstead, R.P.; Wells, R.A.

1955-12-27T23:59:59.000Z

440

Stable surface passivation process for compound semiconductors  

DOE Patents (OSTI)

A passivation process for a previously sulfided, selenided or tellurated III-V compound semiconductor surface. The concentration of undesired mid-gap surface states on a compound semiconductor surface is reduced by the formation of a near-monolayer of metal-(sulfur and/or selenium and/or tellurium)-semiconductor that is effective for long term passivation of the underlying semiconductor surface. Starting with the III-V compound semiconductor surface, any oxidation present thereon is substantially removed and the surface is then treated with sulfur, selenium or tellurium to form a near-monolayer of chalcogen-semiconductor of the surface in an oxygen-free atmosphere. This chalcogenated surface is then contacted with a solution of a metal that will form a low solubility chalcogenide to form a near-monolayer of metal-chalcogen-semiconductor. The resulting passivating layer provides long term protection for the underlying surface at or above the level achieved by a freshly chalcogenated compound semiconductor surface in an oxygen free atmosphere.

Ashby, Carol I. H. (Edgewood, NM)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Tuning the Gate Opening Pressure of Metal Organic Frameworks (MOFs) for the Selective Separation of Hydro-carbons  

E-Print Network (OSTI)

Separation of hydrocarbons is one of the most energy demanding processes. The need to develop materials for the selective adsorption of hydrocarbons, under reasonable conditions, is therefore of paramount importance. This work unveils unexpected hydrocarbon selectivity in a flexible Metal Organic Framework (MOF), based on differences in their gate opening pressure. We show selectivity dependence on both chain length and specific framework-gas interaction. Combining Raman spectroscopy and theoretical van der Waals Density Functional (vdW-DF) calculations, the separation mechanisms governing this unexpected gate opening behavior are revealed.

Nijem, Nour; Canepa, Pieremanuele; Marti, Anne; Balkus,, Kenneth J; Thonhauser, T; Li, Jing; Chabal, Yves J; 10.1021/ja305754f

2012-01-01T23:59:59.000Z

442

Tritium labeling of organic compounds deposited on porous structures  

DOE Patents (OSTI)

An improved process for labeling organic compounds with tritium is carried out by depositing the selected compound on the extensive surface of a porous structure such as a membrane filter and exposing the membrane containing the compound to tritium gas activated by the microwave discharge technique. The labeled compound is then recovered from the porous structure.

Ehrenkaufer, Richard L. E. (Speonk, NY); Wolf, Alfred P. (Setauket, NY); Hembree, Wylie C. (Woodcliff Lake, NJ)

1979-01-01T23:59:59.000Z

443

Compositions containing borane or carborane cage compounds and related applications  

DOE Patents (OSTI)

Compositions comprising a polymer-containing matrix and a filler comprising a cage compound selected from borane cage compounds, carborane cage compounds, metal complexes thereof, residues thereof, mixtures thereof, and/or agglomerations thereof, where the cage compound is not covalently bound to the matrix polymer. Methods of making and applications for using such compositions are also disclosed.

Bowen, III, Daniel E; Eastwood, Eric A

2013-05-28T23:59:59.000Z

444

A 4D synchrotron X-ray tomography study of the formation of hydrocarbon migration pathways in heated organic-rich shale  

E-Print Network (OSTI)

Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes that have received renewed interests in recent years because of the ever tightening supply of conventional hydrocarbons and the growing production of hydrocarbons from low permeability tight rocks. Quantitative models for conversion of kerogen into oil and gas and the timing of hydrocarbon generation have been well documented. However, lack of consensus about the kinetics of hydrocarbon formation in source rocks, expulsion timing and how the resulting hydrocarbons escape from or are retained in the source rocks motivates further investigation. In particular, many mechanisms for the transport of hydrocarbons from the source rocks in which they are generated into adjacent rocks with higher permeabilities and smaller capillary entry pressures have been proposed, and a better understanding of this complex process (primary migration) is needed. To characterize these processes it is imperative to use the ...

Panahi, Hamed; Renard, Francois; Mazzini, Adriano; Scheibert, Julien; Dysthe, Dag Kristian; Jamtveit, Bjorn; Malthe-Sørenssen, Anders; Meakin, Paul

2014-01-01T23:59:59.000Z

445

Experimental measurements and modeling prediction of flammability limits of binary hydrocarbon mixtures  

E-Print Network (OSTI)

Flammability limit is a significant safety issue for industrial processes. A certain amount of flammability limit data for pure hydrocarbons are available in the literature, but for industrial applications, there are conditions including different combinations of fuels at standard and non-standard conditions, in which the flammability limit data are scarce and sometimes unavailable. This research is two-fold: (i) Performing experimental measurements to estimate the lower flammability limits and upper flammability limits of binary hydrocarbon mixtures, conducting experimental data numerical analysis to quantitatively characterize the flammability limits of these mixtures with parameters, such as component compositions, flammability properties of pure hydrocarbons, and thermo-kinetic values; (ii) Estimating flammability limits of binary hydrocarbon mixtures through CFT-V modeling prediction (calculated flame temperature at constant volume), which is based on a comprehensive consideration of energy conservation. For the experimental part, thermal detection was used in this experiment. The experimental results indicate that the experimental results fit Le Chatelier’s Law within experimental uncertainty at the lower flammability limit condition. At the upper flammability limit condition, Le Chatelier’s Law roughly fits the saturated hydrocarbon mixture data, while with mixtures that contain one or more unsaturated components, a modification of Le Chatelier’s is preferred to fit the experimental data. The easy and efficient way to modify Le Chatelier’s Law is to power the molar percentage concentrations of hydrocarbon components. For modeling prediction part, the CFT-V modeling is an extended modification of CAFT modeling at constant volume and is significantly related to the reaction vessel configuration. This modeling prediction is consistent with experimental observation and Le Chatelier’s Law at the concentrations of lower flammability limits. When the quenching effect is negligible, this model can be simplified by ignoring heat loss from the reaction vessel to the external surroundings. Specifically, when the total mole changes in chemical reactions can be neglected and the quenching effect is small, CFTV modeling can be simplified to CAFT modeling.

Zhao, Fuman

2008-05-01T23:59:59.000Z

446

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons  

DOE Green Energy (OSTI)

This report describes one potential conversion process to hydrocarbon products by way of biological conversion of lingnocellulosic-dervied sugars. The process design converts biomass to a hydrocarbon intermediate, a free fatty acid, using dilute-acid pretreatement, enzymatic saccharification, and bioconversion. Ancillary areas--feed handling, hydrolysate conditioning, product recovery and upgrading (hydrotreating) to a final blendstock material, wastewater treatment, lignin combusion, and utilities--are also included in the design.

Davis, R.; Tao, L.; Tan, E. C. D.; Biddy, M. J.; Beckham, G. T.; Scarlata, C.; Jacobson, J.; Cafferty, K.; Ross, J.; Lukas, J.; Knorr, D.; Schoen, P.

2013-10-01T23:59:59.000Z

447

Effect of in-cylinder liquid fuel films on engine-out unburned hydrocarbon emissions for SI engines  

E-Print Network (OSTI)

Nearly all of the hydrocarbon emissions from a modern gasoline-fueled vehicle occur when the engine is first started. One important contributing factor to this is the fact that, during this time, temperatures throughout ...

Costanzo, Vincent S. (Vincent Stanley), 1979-

2011-01-01T23:59:59.000Z

448

Reducing cold start hydrocarbon emissions from port fuel injected spark ignition engines with improved management of hardware & controls  

E-Print Network (OSTI)

An experimental study was performed to investigate strategies for reducing cold start hydrocarbon (HC) emissions from port fuel injected (PFI) spark ignition (SI) engines with better use of existing hardware and control ...

Lang, Kevin R., 1980-

2006-01-01T23:59:59.000Z

449

Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon  

DOE Patents (OSTI)

In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

2000-01-01T23:59:59.000Z

450

Screening and Ranking of Hydrocarbon Reservoirs for CO2 Storage in the Alberta Basin, Canada  

NLE Websites -- All DOE Office Websites (Extended Search)

Screening and Ranking of Hydrocarbon Reservoirs for CO Screening and Ranking of Hydrocarbon Reservoirs for CO 2 Storage in the Alberta Basin, Canada Stefan Bachu (Stefan.Bachu@gov.ab.ca; 780-427-1517) Alberta Energy and Utilities Board 4999-98 Avenue Edmonton, AB, T6B 2X3, Canada Introduction Human activity since the industrial revolution has had the effect of increasing atmospheric concentrations of gases with a greenhouse effect, such as carbon dioxide (CO 2 ) and methane (CH 4 ), leading to climate warming and weather changes (Bryant, 1997; Jepma and Munasinghe, 1998). Because of its relative abundance compared with the other greenhouse gases, CO 2 is by far the most important, being responsible for about 64% of the enhanced "greenhouse effect" (Bryant, 1997). Given their inherent advantages, such as availability, competitive cost, ease of

451

High-energy-density solid and liquid hydrocarbon fuels. Final report, July 1987-December 1988  

Science Conference Proceedings (OSTI)

The development of new high-energy hydrocarbon fuels for use in air-breathing missiles has been the objective of a number of investigations which have received support during the past decade through programs sponsored by the Air Force Systems Command and/or the Naval Air Systems Command. The key characteristics which must be met by potential cruise missile fuels have been described by Burdette and coworkers. A primary requirement in this regard is that candidate fuels must possess high net volumetric heat of combustion (preferably greater than 160,000 BTU/gallon). In order to meet the primary requirement of high net volumetric heat of combustion, hydrocarbon systems have been sought which maximize the ratio of carbon-atom to hydrogen-atom content have been sought that maximize the ratio n/m.(JES)

Marchand, A.P.

1989-02-01T23:59:59.000Z