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Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline  

DOE Patents [OSTI]

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Baker, E.G.; Elliott, D.C.

1993-01-19T23:59:59.000Z

2

E-Print Network 3.0 - aromatic hydrocarbon compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

3

IUPAC-NIST Solubility Data Series 68. Halogenated Aliphatic Hydrocarbon Compounds C3C14 With Water  

E-Print Network [OSTI]

IUPAC-NIST Solubility Data Series 68. Halogenated Aliphatic Hydrocarbon Compounds C3­C14 With Water 16, 1999 This volume covers the solubilities of halogenated aliphatic C3­C14 compounds with water, heavy water, and electrolyte solutions. All data were critically examined for their reliability and best

Magee, Joseph W.

4

Improving GC-PPC-SAFT equation of state for LLE of hydrocarbons and oxygenated compounds with water  

E-Print Network [OSTI]

1 Improving GC-PPC-SAFT equation of state for LLE of hydrocarbons and oxygenated compounds The GC-PPC-SAFT model has been shown to be useful for predicting the liquid- liquid phase split: Group Contribution, GC-PPC-SAFT, binary interaction parameter, LLE, oxygenated compounds. hal-01030846

Boyer, Edmond

5

Carbonyl compounds, hydrocarbons and priority pollutants in the southwestern USA. II. The El Paso - Ciudad Juarez transborder airshed  

SciTech Connect (OSTI)

The combined airshed of El Paso, Texas (USA) and Ciudad Juarez, Chihuahua (Mexico) presents a unique situation where autonomous governmental rules and regulations, economic situations, and cultural differences impact the common air quality of two different countries. Effective mitigation can only be achieved upon sufficient understanding of current atmospheric photochemistry. Atmospheric concentrations and seasonal and diurnal behavior of routinely monitored criteria pollutants and a wide range of reactive organic compounds have been quantified at separate sampling locations in each of the two cities during field studies in January and July of 1995. During the measurement campaigns, no exceedances of US ambient air quality standards were observed for any criteria pollutants. Similar concentrations were observed at both sites for both periods, with the exception of NO{sub x} compounds, which occurred at more elevated levels (>200 ppb) in Juarez during winter late evening periods. As expected summer O{sub 3} values were greater than winter values ({approx}33 ppb and {approx}14 ppb, respectively). Analysis of ambient non-methane hydrocarbons (NMHC) showed biogenic species, such as isoprene, {alpha}-pinene, {beta}-pinene, likely play a relatively minor role in local photochemistry, being detected infrequently and at low mixing ratios ({approx}0.2 ppb). NMHCs were dominated by species typically of anthropogenic origin. Concentrations of all carbonyls were higher in the summer than in the winter, in some cases by a factor of 10 or more. Acetone, an anthropogenic marker, was similar in concentration to formaldehyde and acetaldehyde. Carbonyl concentrations were considerably higher in Juarez in summer than in El Paso, while concentrations were similar in the winter. The wintertime similarities are likely due to the presence of temperature inversions and a more constant air masses over both cities. PAN and PPN levels were similar to those reported for other urban areas.

Martin, R.S.; Popp, C.J.; Dixon, R.W. [New Mexico Tech, Socorro, NM (United States)] [and others

1996-12-31T23:59:59.000Z

6

E-Print Network 3.0 - aromatic hydrocarbons based Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... Rana Novini ATOC 3500 Burn...

7

E-Print Network 3.0 - aromatic hydrocarbons assessment Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... of airborne soot. The air...

8

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Some Inorganic Substances, Chlorinated Hydrocarbons, Aromatic Amines, N-Nitroso Compounds,  

E-Print Network [OSTI]

, and Acrolein 1979; 513 pages ISBN 92 832 1219 3 (out of print) Volume 20 Some Halogenated Hydrocarbons 1979

Barthelat, Francois

9

Improving GC-PPC-SAFT equation of state for LLE of hydrocarbons and oxygenated compounds with water  

Science Journals Connector (OSTI)

Abstract The GC-PPC-SAFT model has been shown to be useful for predicting the liquidliquid phase split with water [Nguyen-Huynh et al. Ind. Eng. Chem. Res. 50 (2011) 74677483]. In order to extend the use of this model to oxygenated compounds for a large number of families (aliphatic ethers, aldehydes, ketones, formates, acetates, propionates/butyrates, n-aliphatic acids), it is proposed to consider cross-association in addition to a binary interaction parameter lij on the combining rules for the cross-segment diameter between water and the investigated compound. The binary interaction parameters lij, u ? ? , and w ? ? are fitted on mutual solubilities of water and organic compounds. The regressed values which are obtained for each chemical family, are subsequently used for predicting infinite dilution activity coefficient in water and n-octanol/water partition coefficient. In general, the results obtained are very much improved compared to the predictive approach discussed previously [Nguyen et al. Ind. Eng. Chem. Res. 52 (2013) 70147029]. The global deviation values on the decimal log scale for infinite dilution activity coefficient in water, water solubility and n-octanol/water partition coefficient are 0.377, 0.419, and 0.469, respectively.

Thanh-Binh Nguyen; Jean-Charles de Hemptinne; Benoit Creton; Georgios M. Kontogeorgis

2014-01-01T23:59:59.000Z

10

E-Print Network 3.0 - aromatic hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aromatic hydrocarbons... the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

11

Compound class specific {sup 14}C analysis of polycyclic aromatic hydrocarbons associated with PM10 and PM1.1 aerosols from residential areas of suburban Tokyo  

SciTech Connect (OSTI)

Compound class specific radiocarbon analysis (CCSRA) was performed for polycyclic aromatic hydrocarbons (PAHs) associated with airborne particulate matter (APM) with diameter {lt}10 {mu}m (PM{sub 10}) and {lt}1.1 {mu}m (PM{sub 1.1}) collected from a residential area of suburban Tokyo, Japan, and seasonal and particle-size radiocarbon variations were investigated. Source diagnostic isomer pair ratios indicated mixed contributions from petroleum combustion and from biomass and coal combustion to the PAHs in APM. The {Delta}{sup 14}C-PAHs in APM, ranging from -787 to -514{per_thousand}, indicated dominance of fossil fuel combustion. The {Delta}{sup 14}C of 5-6 rings (HMW) PAHs were higher than the 3-4 rings (LMW) species in both PM{sub 10} and PM{sub 1.1} samples. The {Delta}{sup 14}C of HMW-PAHs indicated greater biomass-burning contributions in summer than in winter and no apparent particle-size variation. Conversely, the {Delta}{sup 14}C of LMW species showed a greater contribution from fossil sources in summer and in larger particles (PM10). This finding could be tentatively attributed to the recondensation of fossil-PAHs vaporized from petroleum sources. A {Delta}{sup 14}C isotopic mass balance approach estimated that biomass burning contributes 17-45% of the PAH burden in suburban Tokyo, and that the increase in the biomass-PAH accounts for approximately 27% and 22% of winter-time elevation of LMW- and HMW-PAHs, respectively. These are far exceeding what is expected from the emission statistics for CO{sub 2} and combusted materials in Japan and emphasizing the importance of biomass-burning as a source of PAHs; which, in turn, demonstrates the utility and the significance of field-based source assessment by using CCSRA for an effective regulation of atmospheric pollution by PAHs. 37 refs., 3 figs., 2 tabs.

Hidetoshi Kumata; Masao Uchida; Eisuke Sakuma; Tatsuya Uchida; Kitao Fujiwara; Mikio Tsuzuki; Minoru Yoneda; Yasuyuki Shibata [Tokyo University of Pharmacy and Life Science, Tokyo (Japan). Faculty of Life Science

2006-06-01T23:59:59.000Z

12

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

...research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion...mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...Carcinogens 0 Epoxy Compounds 0 Fuel Oils 0 Hydrocarbons 0 Naphthalenes...

1975-01-01T23:59:59.000Z

13

Nonlinear dependence of the solubility of water in hydrocarbons on the molar volume of the hydrocarbon  

Science Journals Connector (OSTI)

The solubility of water in fifty hydrocarbon solvents at 20C is estimated by ... in nonspecific cohesion forces, and assuming that water is primarily monomeric in solution, the prediction ... breaking of the H-b...

Paul Ruelle; Ulrich W. Kesselring

1996-07-01T23:59:59.000Z

14

Determination of Polycyclic Aromatic Hydrocarbons in Fresh Milk by Hollow Fiber Liquid-Phase MicroextractionGas Chromatography Mass Spectrometry  

Science Journals Connector (OSTI)

......Polycyclic Aromatic Hydrocarbons in Fresh Milk by...polycyclic aromatic hydrocarbons (PAHs) in fresh...more volatile and heat sensitive. The...Polycyclic aromatic hydrocarbons (PAHs) are compounds...the incomplete combustion of carbon-containing...respectively. Data were collected......

Mohd Marsin Sanagi; Saw Hong Loh; Wan Aini Wan Ibrahim; Mohamed Noor Hasan; Hassan Y. Aboul Enein

2013-02-01T23:59:59.000Z

15

Solubilization of petroleum hydrocarbons using biosurfactants  

E-Print Network [OSTI]

Low solubility of petroleum hydrocarbons in water is the major factor limiting the degradation rates of these compounds (Zhang and Miller, 1994). The fraction that is more soluble in the aqueous phase is degraded at higher rates, while less soluble...

Kanga, Shahrukh

2012-06-07T23:59:59.000Z

16

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents [OSTI]

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

17

Simultaneous mobilization of trace elements and polycyclic aromatic hydrocarbon (PAH) compounds from soil with a nonionic surfactant and [S,S]-EDDS in admixture: Metals  

Science Journals Connector (OSTI)

This study evaluated the efficacy of soil washing with a nonionic surfactant (Brij98) in combination with a complexing reagent (ethylenediaminedisuccinic acid, [S,S]-EDDS) for the simultaneous mobilization of macro- and trace elements (MTEs) and PAH compounds from a field-contaminated soil. Soil fractionation studies indicated that an appreciable fraction of the Al, Ca, Cu, Fe and Mn was associated with the residual fraction but that much of the other trace elements (As, Cd, Cr, Ni, Pb and Zn) might be susceptible to soil washing. Ultrasonically aided mixing of the field contaminated soil with Brij98 and a sparing quantity (2mmol) of [S,S]-EDDS, simultaneously mobilized virtually all of the benzo[?]pyrene {B(a)P} and chrysene (CRY) and appreciable quantities of the trace elements (Cd, Cr, Mn, Ni, Pb, Zn) burdens. The recovery of both \\{PAHs\\} and trace elements were increased from the soil organic matter (SOM)-rich soil. This report concerns the fate of \\{MTEs\\} during soil washing. Multiple ultra-sonically aided washes (five or nine) with the same dosage of reagents mobilized virtually all of \\{PAHs\\} and decreased the levels of Cd, Cr, Ni, Pb and Zn to comply with recommended maxima. By contrast, the levels of As and Cu remained excessive after the treatments.

Yuexiang Wen; William D. Marshall

2011-01-01T23:59:59.000Z

18

Chapter 9 - Chemical and Physical Properties of Hydrocarbons  

Science Journals Connector (OSTI)

Publisher Summary Hydrocarbons are the simplest organic compounds and contain only carbon and hydrogen but they can be straight chain or branched chain with the same empirical formula but showing differences in properties. Chemical change results in the hydrocarbon yielding a product that may be entirely different in composition to the starting hydrocarbonthe exception is the isomerization reaction where a straight-chain hydrocarbon is converted to a branched-chain hydrocarbon. Chemical properties of hydrocarbons describe the potential of hydrocarbons to undergo chemical change or reaction by virtue of the hydrocarbon structure. Physical properties can be observed or measured without changing the composition of matter. Physical properties are used to observe and describe matter. Physical properties that are of interest in the current context include: boiling point, melting point, density, vapor density, flash point, ignition temperature, and dew point.

James G. Speight

2011-01-01T23:59:59.000Z

19

Naphthenic hydrocarbons  

SciTech Connect (OSTI)

An important type of naphthenic hydrocarbons is the monocyclic type, (k/sub 2/, 0, 0). In this instance the number of carbon atoms, n = k/sub 2/, and a formula, C/sub n/H/sub 2n/, can be written where H/C = 2. The value n can vary from 2 to infinity. In the case of n = 2, it is ethylene (I) (2-membered cyclic ring); n = 3, cyclopropane (II) (3-membered cyclic ring); n = 4, cyclobutane (III) (4-membered cyclic ring); etc. If the monocyclic naphthenic is planar, then the bond angle theta can be expressed as theta = (1 - 2/n)..pi.. where n is the number of carbon atoms. However, the tetrahedron angle of the carbon atom being phi = cos/sup -1/ (- 1/3).

Yen, T.F.; Kuo, J.F.; Chilingarian, G.V.

1987-01-01T23:59:59.000Z

20

Our planet is becoming increasingly polluted with inorganic and organic compounds, primarily as a  

E-Print Network [OSTI]

produced or expected to be present in organ- isms). Many of them are toxic and/or carcinogenic. Sources cleanup in the US, and $25­50 billion per year worldwide (Glass 1999; Tsao 2003). Most remediation that use plants to remove, reduce, degrade, or immobilize environmental pollutants from soil and water

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Polycyclic aromatic hydrocarbon (PAH) in four fish species from different trophic levels in the Persian Gulf  

Science Journals Connector (OSTI)

Concentration of ten polycyclic aromatic hydrocarbon (PAH) compounds were determined in liver of four fish species from different trophic levels (Aurigequula fasciata, omnivore; Alepes djedaba, carnivore; Liza ab...

Shirin Rahmanpour; Nasrin Farzaneh Ghorghani

2014-11-01T23:59:59.000Z

22

E-Print Network 3.0 - active aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

23

E-Print Network 3.0 - aryl hydrocarbon receptor-dna Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

24

E-Print Network 3.0 - aromatic hydrocarbon aryl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

25

E-Print Network 3.0 - aryl hydrocarbon monooxygenase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

26

E-Print Network 3.0 - aryl hydrocarbon nuclear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

27

E-Print Network 3.0 - ahr aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

28

E-Print Network 3.0 - aryl hydrocarbon receptor-dependent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

29

E-Print Network 3.0 - aryl hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

30

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible fuels comprising: (A) forming a hydrocarbosol using a surfactant package in a proportion of about 1:100 to about 1:20,000 by weight based on hydrocarbon, (1) the surfactant package comprising (a) at least one water-soluble surfactant, an effective amount of which surfactant promotes emulsification of a hydrocarbon with API gravity of about 20/sup 0//sup o/ API or less; and (b) at least one water-soluble bioemulsifier, being a microboally-derived substance which predominantly resides at hydrocarbon/water interfaces to substantially surround hydrocarbon droplets in hydrocarbon-in-water emulsions; (2) the hydrocarbosol (a) comprising a hydrocarbon characterized by an API gravity of about 20/sup 0//sup o/ API or less; (b) having a hydrocarbon:water ratio of about 70:30 by volume; and (B) burning the resultant hydrocarbosol.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III

1986-10-21T23:59:59.000Z

31

Manmade organic compounds in the surface waters of the United States: A review of current understanding  

SciTech Connect (OSTI)

On the basis of their aqueous solubilities, nonionic organic compounds partition themselves between water, dissolved organic matter, particulate organic matter, and the lipid reservoirs of aquatic organisms. Ionized organic compounds can be adsorbed to sediments, thereby reducing their aqueous concentrations. Transformation processes of photolysis, hydrolysis, biodegradation, and volatilization can attenuate organic compounds, and attenuation rates commonly follow a first-order kinetic process. Eight groups of manmade organic compounds are discussed: (1) polychlorinated biphenyls and organochlorine insecticides; (2) carbamate and organophosphorus; (3) herbicides; (4) phenols; (5) halogenated aliphatic and monocyclic aromatic hydrocarbons; (6) phthalate esters; (7) polychlorinated dibenzo-p-dioxins, and (8) polycyclic aromatic hydrocarbons. For each compound group, data pertaining to use, production, and properties are presented and discussed. Process that influence the environmental fate of each group, as determined primarily through laboratory studies, are reviewed, and important fate process are identified. Environmental concentrations of compounds from each group in water, biota, and sediment are given to demonstrate representative values for comparison to concentrations determined during ongoing research. Finally, where sufficient data exist, regional and temporal contamination trends in the US are discussed. 699 refs., 26 figs., 47 tabs.

Smith, J.A.; Witkowski, P.J.; Fusillo, T.V.

1990-01-01T23:59:59.000Z

32

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents [OSTI]

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

33

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible pre-atomized fuels, comprising: (A) forming a hydrocarbon-in-water emulsion using an effective amount of a surfactant package comprising at least one water-soluble surfactant, the hydrocarbon-in-water emulsion (1) comprising a hydrocarbon characterized by API gravity of about 20/sup 0/ API or less, viscosity of about 1000 centipoise or greater at 212/sup 0/F., a paraffin content of about 50% by weight or less and, an aromatic content of about 15% by weight or greater, and (2) having a hydrocarbon water ratio from about 60:40 to about 90:10 by volume; and (B) burning the resultant hydrocarbon-in-water emulsion.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III; Bolden, P.L. Jr.

1987-08-04T23:59:59.000Z

34

Hydrocarbon Potential of Deep Water  

Science Journals Connector (OSTI)

...research-article Hydrocarbon Potential of Deep Water H. R. Warman In...the geology and hydrocarbon potential of the Earth's deeper water areas, an attempt...United Kingdom 1981 Hydrocarbon potential of deep water Warman H. R. Author...

1978-01-01T23:59:59.000Z

35

Recovering hydrocarbons from hydrocarbon-containing vapors  

DOE Patents [OSTI]

Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

1980-09-30T23:59:59.000Z

36

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

SciTech Connect (OSTI)

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

37

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect (OSTI)

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

38

A generalized viscosity equation for pure heavy hydrocarbons  

SciTech Connect (OSTI)

This paper presents a method for the correlation and prediction of the viscosity of pure heavy hydrocarbons listed in API Research Project 42. The 273 heavy hydrocarbons in the database include branched/unbranched paraffins and olefins together with a variety of complex nonfused/fused aromatic and naphthenic compounds. A generalized one-parameter viscosity-temperature equation, log ({mu} + 0.8) = 100(0.01T){sup b}, is proposed (overall AAD {lt} 7-10%) for all heavy hydrocarbons in the database. For each hydrocarbon, an optimum value of parameter b is provided. It is shown that parameter b varies linearly with the logarithm of molar mass as well as the inverse of boiling temperature (at 10 mmHg). This important observation leads to the development of a predictive method for the liquid-phase viscosity of pure heavy hydrocarbons.

Mehrotra, A.K. (Dept. of Chemical and Petroleum Engineering, Univ. of Calgary, Calgary, Alberta T2N 1N4 (CA))

1991-02-01T23:59:59.000Z

39

Plasma Processing Of Hydrocarbon  

SciTech Connect (OSTI)

The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

2007-05-01T23:59:59.000Z

40

Process for the hydrotreatment of heavy hydrocarbons in the presence of reduced metals  

SciTech Connect (OSTI)

A heavy hydrocarbon charge containing sulfur, asphaltenes and/or resins is hydrotreated in the liquid phase at 250/sup 0/-500/sup 0/ C. under a pressure of 20-350 bars in the presence of a catalyst previously obtained by reacting an organic compound of a transition metal with an organic aluminum compound, in a hydrocarbon free of asphaltene and resin. The transition metal organic compound is advantageously an iron, nickel, cobalt, molybdenum, tungsten or vanadium acetylacetonate or carboxylate.

Dinh, C.T.; Desvard, A.; Jacquin, Y.; Martino, G.

1984-03-06T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Boron-containing amino carboxylic acid compounds and uses thereof  

DOE Patents [OSTI]

Novel compounds which are useful for boron neutron capture therapy (BNCT) are disclosed. The compounds comprise a stable boron-containing group and an aminocycloalkane carboxylic acid group or a boronated acyclic hydrocarbon-linked amino carboxylic acid. Methods for synthesis of the compounds and for use of the compounds in BNCT are disclosed.

Kabalka, George W. (Knoxville, TN); Srivastava, Rajiv R. (Knoxville, TN)

2000-03-14T23:59:59.000Z

42

A study of the structure of the hydrocarbons of primary hard-coal tar  

SciTech Connect (OSTI)

The hydrocarbons isolated from primary hard-coal (G/sub 6/ gas coal) tar have been investigated by a combination of physicochemical and chemical methods. It has been established that the hydrocarbons boiling up to 573 K are mainly aliphatic, hydroaromatic, and naphthenic and are aromatic only to a smaller degree. Molecular and presumable structural formulas of the oxygen compounds isolated from the 473-573 K hydrocarbon fraction have been derived.

Platonov, V.V.; Gerasimova, N.I.; Ivleva, L.N.; Klyavina, O.A.; Vishnyakov, S.N.

1985-01-01T23:59:59.000Z

43

E-Print Network 3.0 - aromatic organic compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

44

E-Print Network 3.0 - aromatic chemical compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... in burn pits include, but...

45

Dispersant solutions for dispersing hydrocarbons  

DOE Patents [OSTI]

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, R.L.

1997-03-11T23:59:59.000Z

46

Metabolism of mixtures of polycyclic aromatic hydrocarbons (PAHs) by Cunninghamella elegans  

E-Print Network [OSTI]

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant compounds due to the toxicity of some members. They are ubiquitous and are persistent bioaccumulative toxins(PBTs). The toxicity of PAHs represents a risk to human health...

Olatubi, Oluwaseun Alfred

2007-04-25T23:59:59.000Z

47

Calculation of the Heat of Combustion of Hydrocarbon Components of Fuels  

Science Journals Connector (OSTI)

Development is continued of the empirical method for the calculation of the heat of combustion of organic compounds and, in particular, of hydrocarbons of different structures by the additive scheme...

E. V. Sagadeev; V. V. Sagadeev

2004-05-01T23:59:59.000Z

48

Vertical transport and residence time of chlorinated hydrocarbons in the open ocean water column  

Science Journals Connector (OSTI)

The vertical transport of PCBs and chlorinated hydrocarbon pesticides such as DDT compounds and HCH ... of their adsorbed and dissolved fractions in surface water surveyed in the Western Pacific, Eastern Indian.....

Shinsuke Tanabe; Ryo Tatsukawa

1983-04-01T23:59:59.000Z

49

Carbon neutral hydrocarbons  

Science Journals Connector (OSTI)

...depends on a source of primary energy to drive the required chemical...synthetic hydrocarbons are an energy carrier produced from a primary energy source such as wind, nuclear...Gustavsson et al. 2007), using a conversion value of $1.00=0.72...

2008-01-01T23:59:59.000Z

50

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1987-01-01T23:59:59.000Z

51

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 5 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1988-09-13T23:59:59.000Z

52

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 6 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1987-05-19T23:59:59.000Z

53

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1988-01-01T23:59:59.000Z

54

Systems/Circuits Cortical Pitch Regions in Humans Respond Primarily to  

E-Print Network [OSTI]

Systems/Circuits Cortical Pitch Regions in Humans Respond Primarily to Resolved Harmonics and Cognitive Sciences, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 Pitch of pitch perception havedifferentiatedbetweentemporalandspectralcues

Kanwisher, Nancy

55

FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY  

E-Print Network [OSTI]

photolysis of these ices produces a host of new compounds, some of which show intriguing prebiotic behavior1 FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY LOUIS J. ALLAMANDOLA, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon

56

THERMOCHEMISTRY OF HYDROCARBON RADICALS  

SciTech Connect (OSTI)

Gas phase negative ion chemistry methods are employed to determine enthalpies of formation of hydrocarbon radicals that are important in combustion processes and to investigate the dynamics of ion-molecule reactions. Using guided ion beam tandem mass spectrometry, we measure collisional threshold energies of endoergic proton transfer and hydrogen atom transfer reactions of hydrocarbon molecules with negative reagent ions. The measured reaction threshold energies for proton transfer yield the relative gas phase acidities. In an alternative methodology, competitive collision-induced dissociation of proton-bound ion-molecule complexes provides accurate gas phase acidities relative to a reference acid. Combined with the electron affinity of the R {center_dot} radical, the gas phase acidity yields the RH bond dissociation energy of the corresponding neutral molecule, or equivalently the enthalpy of formation of the R{center_dot} organic radical, using equation: D(R-H) = {Delta}{sub acid}H(RH) + EA(R) - IE(H). The threshold energy for hydrogen abstraction from a hydrocarbon molecule yields its hydrogen atom affinity relative to the reagent anion, providing the RH bond dissociation energy directly. Electronic structure calculations are used to evaluate the possibility of potential energy barriers or dynamical constrictions along the reaction path, and as input for RRKM and phase space theory calculations. In newer experiments, we have measured the product velocity distributions to obtain additional information on the energetics and dynamics of the reactions.

Kent M. Ervin, Principal Investigator

2004-08-17T23:59:59.000Z

57

Radical scavengers from heavy hydrocarbons  

SciTech Connect (OSTI)

The hydrogen-donating properties of some hydrocarbons form the basis for processes such as coal liquefaction and heavy oil upgrading. However, these hydrocarbons have seldom been used for other purposes, because their potential applications have not been well recognized. Research has indicated that these hydrogen-donating hydrocarbons can be used in important reactions as radical scavengers and have properties particular to those of pure hydrocarbons without functional groups containing heteroatoms. Over years of study researchers have found that pure hydrocarbons with radical-scavenging effects nearly as high as those in conventional hindered phenolic antioxidants can be produced from petroleum, and these hydrogen-donating hydrocarbons exhibit such effects even in oxidative atmospheres (i.e., they function as antioxidants). He has also shown that these mixtures have some properties particular to pure hydrocarbons without functional groups containing heteroatoms, and they`ve seen that a mechanism based on the steric effects appears when these hydrocarbons are used in heavy oil hydroprocessing. Hydrogen-donating hydrocarbons should be a viable resource in many applications. In this article, he presents radical-scavenging abilities, characteristics as pure hydrocarbons, and applications on the basis of the studies.

Kubo, Junichi [Nippon Oil Co. Ltd. (Japan)

1996-10-01T23:59:59.000Z

58

Process for using alkyl substituted C8-C10 aromatic hydrocarbons as preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect (OSTI)

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream. The improvement consists of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent which provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100% which comprises: A. selectively extracting and stripping the hydrocarbon gas stream with the physical solvent to produce a residue hydrocarbon gas stream of pipeline specifications and a rich solvent stream containing ethane and heavier hydrocarbon components, the preferential physical solvent being: (1) rich in C/sub 8/-C/sub 10/ aromatic compounds having methyl, ethyl, or propyl aliphatic groups and (2) selective for ethane and heavier hydrocarbon components of the gas stream such that: (a) the relative volatility of methane over ethane is at least 5.0 and the hydrocarbon loading capacity, defined as solubility of ethane in solvent, is at least 0.25 standard cubic feet of ethane per gallon of solvent, or (b) the preferential factor determined by the multiplication of relative volatility of methane over ethane by the solubility of ethane in solvent, in standard cubic feet of ethane per gallon of solvent, of at least 1.25; and B. distilling the rich solvent to produce the hydrocarbon gas liquids and the physical solvent.

Mehra, Y.R.

1987-09-08T23:59:59.000Z

59

EXPENDITURE OBJECT CODES Foundation FOUNDATION EXPENDITURE OBJECT CODES are used primarily by Accounting Services for Foundation  

E-Print Network [OSTI]

EXPENDITURE OBJECT CODES ­ Foundation 2-J page 1 FOUNDATION EXPENDITURE OBJECT CODES are used primarily by Accounting Services for Foundation transactions. 3080 Foundation Service Fee: Allocation of administrative costs to Foundation beneficiary departmental accounts. 3120 LSU Magazine Costs - Foundation

Harms, Kyle E.

60

Brain reorganization, not relative brain size, primarily characterizes anthropoid brain evolution  

Science Journals Connector (OSTI)

...reserved. May 22, 2013 research-article Research articles 1001 42 70 133 Brain reorganization, not relative brain size, primarily characterizes anthropoid brain evolution J. B. Smaers 1 2 C. Soligo 1 e-mail: j.smaers@ucl.ac...

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The Utilization of Certain Hydrocarbons by Microorganisms  

Science Journals Connector (OSTI)

...UTILIZATION OF CERTAIN HYDROCARBONS BY MICROORGANISMS...1940 INTRODUCTION Hydrocarbons, as a class, represent...obtained by comparing the heat of combustion of some six carbon...biological utilization of hydrocarbons as sources of energy...

L. D. Bushnell; H. F. Haas

1941-05-01T23:59:59.000Z

62

Interaction between Carcinogenic Hydrocarbons and Nucleosides  

Science Journals Connector (OSTI)

...addition, the findings that hydrocarbons inhibit DNA syn thesis...for these carcinogens. Hydrocarbon-nucleic acid interaction...and the interactions of water molecules. Indeed, carcinogenic hydrocarbons tend to form 1 This investigation...

Ronald G. Harvey and Marilyn Halonen

1968-11-01T23:59:59.000Z

63

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for recovering liquid hydrocarbons. It comprises: injecting into a fractured subterranean formation a polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas, recovering liquid hydrocarbons from the formation.

Sydansk, R.D.

1992-07-14T23:59:59.000Z

64

Hydrocarbon sensors and materials therefor  

DOE Patents [OSTI]

An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

2000-01-01T23:59:59.000Z

65

New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor |  

Broader source: Energy.gov (indexed) [DOE]

Study Shows Solar Manufacturing Costs Not Driven Primarily by Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor September 5, 2013 - 12:00pm Addthis Production scale, not lower labor costs, drives China's current advantage in manufacturing photovoltaic (PV) solar energy systems, according to a new report released today by the Energy Department's National Renewable Energy Laboratory (NREL) and the Massachusetts Institute of Technology (MIT). Although the prevailing belief is that low labor costs and direct government subsidies for PV manufacturing in China account for that country's dominance in PV manufacturing, the NREL/MIT study shows that a majority of the region's competitive advantage comes from production scale-enabled, in part, through preferred access to capital (indirect

66

New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor |  

Broader source: Energy.gov (indexed) [DOE]

New Study Shows Solar Manufacturing Costs Not Driven Primarily by New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor New Study Shows Solar Manufacturing Costs Not Driven Primarily by Labor September 5, 2013 - 12:00pm Addthis Production scale, not lower labor costs, drives China's current advantage in manufacturing photovoltaic (PV) solar energy systems, according to a new report released today by the Energy Department's National Renewable Energy Laboratory (NREL) and the Massachusetts Institute of Technology (MIT). Although the prevailing belief is that low labor costs and direct government subsidies for PV manufacturing in China account for that country's dominance in PV manufacturing, the NREL/MIT study shows that a majority of the region's competitive advantage comes from production scale-enabled, in part, through preferred access to capital (indirect

67

Process for recovering hydrocarbons from a hydrocarbon-bearing formation  

SciTech Connect (OSTI)

A method is described for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion. Also disclosed is a method of recovery of hydrocarbons from a hydrocarbon bearing formation employing an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent.

Alston, R.B.; Braden, W.B.; Flournoy, K.H.

1980-03-11T23:59:59.000Z

68

Nitroaromatic Compounds, from Synthesis to Biodegradation  

Science Journals Connector (OSTI)

...explosives but also are the fundamental building blocks in...from all combustion engines contains hydrocarbons...atmospheric pollution is diesel engine-powered motor...compounds, but several fundamental aspects regarding their...Explosives development and fundamentals of explosives technology...

Kou-San Ju; Rebecca E. Parales

2010-06-01T23:59:59.000Z

69

New modified hydrocarbon resins; An alternative to styrenated terpene resins in hot melts  

SciTech Connect (OSTI)

This paper reports on the development of two hydrocarbon-based resin formulations that could be used with different thermoplastic block copolymers to formulate pressure-sensitive adhesives. Results are examined with one of these resins in formulations with styrene-isoprene-styrene (SIS) and styrene-butadiene (SB) compounds. The new modified hydrocarbon resin, with a softening point of 98{degrees} C, matches the adhesive performance of a terpene resin with a softening point of 105{degrees} C. The resin performs as well as the modified terpene in SIS-, SB-, and EVA-based adhesives. The new hydrocarbon resin is especially well suited for hot-melt adhesives. It exhibits low volatility, good color stability, and excellent melt viscosity stability. Since the new resin is based on petroleum hydrocarbon feedstocks, it should be available at moderate, stable prices. The other hydrocarbon resin, with a softening point of 85{degrees} C, produced comparable results.

Carper, J.D. (Hercules Inc., Wilmington, DE (US))

1990-06-01T23:59:59.000Z

70

In Situ Hydrocarbon Degradation by Indigenous Nearshore Bacterial Populations  

SciTech Connect (OSTI)

Potential episodic hydrocarbon inputs associated with oil mining and transportation together with chronic introduction of hydrocarbons via urban runoff into the relatively pristine coastal Florida waters poses a significant threat to Florida's fragile marine environment. It is therefore important to understand the extent to which indigenous bacterial populations are able to degrade hydrocarbon compounds and also determine factors that could potentially control and promote the rate at which these compounds are broken down in situ. Previous controlled laboratory experiments carried out by our research group demonstrated that separately both photo-oxidation and cometabolism stimulate bacterial hydrocarbon degradation by natural bacterial assemblages collected from a chronically petroleum contaminated site in Bayboro Bay, Florida. Additionally, we also demonstrated that stable carbon and radiocarbon abundances of respired CO{sub 2} could be used to trace in situ hydrocarbon degradation by indigenous bacterial populations at this same site. This current proposal had two main objectives: (a) to evaluate the cumulative impact of cometabolism and photo-oxidation on hydrocarbon degradation by natural bacterial assemblages collected the same site in Bayboro Bay, Florida and (b) to determine if in situ hydrocarbon degradation by indigenous bacterial populations this site could be traced using natural radiocarbon and stable carbon abundances of assimilated bacterial carbon. Funds were used for 2 years of full support for one ESI Ph.D. student, April Croxton. To address our first objective a series of closed system bacterial incubations were carried out using photo-oxidized petroleum and pinfish (i.e. cometabolite). Bacterial production of CO{sub 2} was used as the indicator of hydrocarbon degradation and {delta}{sup 13}C analysis of the resultant CO{sub 2} was used to evaluate the source of the respired CO{sub 2} (i.e. petroleum hydrocarbons or the pinfish cometabolite). Results from these time series experiments demonstrated that short-term exposure of petroleum to UV light enhanced hydrocarbon degradation by 48% over that observed for non-photo-oxidized petroleum. Despite the greater bio-availability of the photo-oxidized over the non-photo-oxidized petroleum, an initial lag in CO{sub 2} production was observed indicating potential phototoxicity of the photo- by-products. {delta}{sup 13}C analysis and mass balance calculations reveal that co-metabolism with pinfish resulted in increased hydrocarbon degradation for both photo-oxidized and non-photo-oxidized petroleum each by over 100%. These results demonstrate the cumulative effect of photo-oxidation and co-metabolism on petroleum hydrocarbon degradation by natural bacterial populations indigenous to systems chronically impacted by hydrocarbon input. To address the second objective of this proposal bacterial concentrates were collected from Bayboro Harbor in April 2001 for nucleic acid extraction and subsequent natural radiocarbon abundance analyses. Unfortunately, however, all of these samples were lost due to a faulty compressor in our -70 freezer. The freezer was subsequently repaired and samples were again collected from Bayboro Harbor in June 2002 and again December 2002. Several attempts were made to extract the nucleic acid samples--however, the student was not able to successfully extract and an adequate amount of uncontaminated nucleic acid samples for subsequent natural radiocarbon abundance measurements of the bacterial carbon by accelerator mass spectrometry (i.e. require at least 50 {micro}g carbon for AMS measurement). Consequently, we were not able to address the second objective of this proposed work.

Cherrier, J.

2005-05-16T23:59:59.000Z

71

Carcinogenic Hydrocarbons and Related Compounds in Processed Rubber  

Science Journals Connector (OSTI)

...is made by the incomplete combustion of natural gas. Furnace black...obtained by the incomplete combustion of oils and tars. It might...BARRON,H. Modern Rubber Chemistry, pp. 154-81, 202- 34...3,4-Benzpyrene from Coal Tar. Nature, 156:601...

Hans L. Falk; Paul E. Steiner; Sam Goldfein; Alexander Breslow; and Ruth Hykes

1951-05-01T23:59:59.000Z

72

A new technology for producing synthetic liquid hydrocarbons from gaseous hydrocarbons  

Science Journals Connector (OSTI)

Conventional technologies of synthetic liquid fuels (SLF) production from gaseous hydrocarbons by producing synthesis ... liquid hydrocarbons are examined. A high-efficiency SLF production technology that allows ...

D. L. Astanovskii; L. Z. Astanovskii; A. L. Lapidus

2012-09-01T23:59:59.000Z

73

Analysis of lipophilic compounds of tea coated on the surface of clay teapots  

Science Journals Connector (OSTI)

Abstract The surface of a clay teapot tends to be coated with a waterproof film after constant use for tea preparation. The waterproof films of two kinds of teapots (zisha and zhuni) used for preparing oolong tea and old oolong tea were extracted and subjected to gas chromatographymass spectrometry analysis. The results showed that comparable constituents were detected in these films; they were primarily fatty acids and linear hydrocarbons that were particularly rich in palmitic acid and stearic acid. To explore the source of these two abundant fatty acids, the fatty acid compositions of fresh tea leaves, granules, infusion, and vapor of infusion were analyzed by gas chromatography. Fresh tea leaves were rich in palmitic acid (C-16:0), unsaturated linolenic acid (C-18:3), linoleic acid (C-18:2), and oleic acid (C-18:1), which were presumably from the phospholipid membrane. During the process of manufacturing oolong tea, the three unsaturated fatty acids may be substantially degraded or oxidized to stearic acid (C-18:0), which was enriched with palmitic acid in the tea granules and in the infusion. The vapor of the tea infusion is primarily composed of palmitic acid and stearic acid. Thus, the coated films of teapots mostly originated from the lipophilic compounds of the tea infusions.

Tse-Yu Chung; Ping-Chung Kuo; Zih-Hui Liao; Yu-En Shih; Mei-Ling Cheng; Chia-Chang Wu; Jason T.C. Tzen

2014-01-01T23:59:59.000Z

74

Polybenzimidazole compounds  

DOE Patents [OSTI]

A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2--, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

2010-08-10T23:59:59.000Z

75

Enrichment of light hydrocarbon mixture  

DOE Patents [OSTI]

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

76

Biological enhancement of hydrocarbon extraction  

DOE Patents [OSTI]

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

77

Fluorescence Detection of Hydrocarbons in Harbour Water  

Science Journals Connector (OSTI)

In harbor water, the hydrocarbons pollution identification represents an important issue. Hydrocarbon presence derives from oil spills, for instance in bilge water, or it may come from industrial discharge ... Fl...

A. Catini; F. Dini; D. Polese; S. Petrocco; M. De Luca

2011-01-01T23:59:59.000Z

78

Method and apparatus for converting and removing organosulfur and other oxidizable compounds from distillate fuels, and compositions obtained thereby  

DOE Patents [OSTI]

The present disclosure is directed to a multi-stage system and a process utilizing said system with the design of reducing the sulfur-content in a liquid comprising hydrocarbons and organosulfur compounds. The process comprising at least one of the following states: (1) an oxidation stage; (2) an extraction state; (3) a raffinate washing stage; (4) a raffinate polishing stage; (5) a solvent recovery stage; (6) a solvent purification stage; and (7) a hydrocarbon recovery stage. The process for removing sulfur-containing hydrocarbons from gas oil, which comprises oxidizing gas oil comprising hydrocarbons and organosulfur compounds to obtain a product gas oil.

D'Alessandro, Robert N. (Spanish Fort, AL); Tarabocchia, John (Parsippany, NJ); Jones, Jerald Andrew (Frankfurt am Main, DE); Bonde, Steven E. (West Richard, WA); Leininger, Stefan (Langenselbold, DE)

2010-10-26T23:59:59.000Z

79

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

80

Extracting hydrocarbons from water using a centrifuge  

Science Journals Connector (OSTI)

An original method for the solid-phase microextraction of hydrocarbons from water using a centrifuge is proposed. Comparative results...

A. Yu. Ryabov; A. A. Ilyina; A. V. Chuikin

2014-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Photo-oxides of Carcinogenic Hydrocarbons  

Science Journals Connector (OSTI)

... are involved in the biological action of carcinogenic hydrocarbons, we have attempted to isolate the photo-oxides of some of these hydrocarbons. Such ... -oxides of some of these hydrocarbons. Such photo-oxides would naturally be insoluble in water and hence would represent merely one stage in ...

J. W. COOK; R. MARTIN; E. M. F. ROE

1939-06-17T23:59:59.000Z

82

Catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

The hot effluent from the catalytic steam reforming of a major portion of a fluid hydrocarbon feed stream in the reformer tubes of a primary reformer, or said effluent after secondary reforming thereof, is mixed with the hot effluent from the catalytic steam reforming of the remaining portion of the feed discharged from the reformer tubes of a primary reformer-exchanger. The combined gas steam is passed on the shell side of the reformer-exchanger countercurrently to the passage of feed in the reformer tubes thereof, thus supplying the heat for the reforming of the portion of the feed passed through the reformer tubes of the reformerexchanger. At least about 2/3 of the hydrocarbon feed stream is passed to the reformer tubes of said primary reformer, heated by radiant heat transfer and/or by contact with combustion gases, at a steam/hydrocarbon mole ratio of about 2-4/1. The remainder of said feed stream is passed to the reformer tubes of said reformer -exchanger at a steam/hydrocarbon mole ratio of about 3-6/1. The reformer shell of the reformer-exchanger is internally insulated by a refractory lining or by use of a double shell with passage of water or a portion of the feed material between the inner and outer shells. There is no significant difference between the pressure inside and outside of the reformer tubes of said primary reformer-exchanger.

Fuderer, A.

1982-06-29T23:59:59.000Z

83

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

84

2007-01-0472 Particulate and Hydrocarbon Emissions from a Spray Guided  

E-Print Network [OSTI]

International ABSTRACT The blending of oxygenated compounds with gasoline is projected to increase because in substitution of the aromatic fraction in gasoline. Blending oxygenates with gasoline changes the fuels-out emissions. In this work, the effect of blending methanol and ethanol with gasoline on unburned hydrocarbon

85

Hydrogen transfer in transformations of olefin and thiophene compounds for the refining of gasoline fractions  

Science Journals Connector (OSTI)

Abstract Hydrogen transfer reactions in the transformations of mixtures of model hydrocarbons (hydrogen donors and acceptors) on zeolite catalysts were studied. Hydrogen donors were represented by various classes of hydrocarbons, and acceptorsby unsaturated (olefin) and thiophene compounds. The [H]-donor activity series of hydrocarbons was revealed. Strong differences in the transformation pathways of 1-hexene and 1-octene under the conditions of catalytic refining were demonstrated. A new method for the refining of low-rank gasoline fractions was proposed. The method is based on the hydrogen transfer reactions between hydrogen donor hydrocarbons and hydrogen acceptor hydrocarbons, which proceed without molecular hydrogen. The proposed method allows the simultaneous removal of sulfur (more than 95%) and unsaturated (more than 90%) compounds.

Oleg V. Potapenko; Vladimir P. Doronin; Tatyana P. Sorokina; Vladimir A. Likholobov

2014-01-01T23:59:59.000Z

86

Catalysts and process for liquid hydrocarbon fuel production  

DOE Patents [OSTI]

The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

White, Mark G; Liu, Shetian

2014-12-09T23:59:59.000Z

87

Hydrocarbon Technologies | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Technologies Hydrocarbon Technologies Place Lawrenceville, New Jersey Zip 8648 Sector Efficiency Product String representation "Technology-base ... onmental risks." is too long. Coordinates 36.761678°, -77.845048° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.761678,"lon":-77.845048,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

88

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for the recovery of liquid hydrocarbons from a subterranean hydrocarbon-bearing formation. It comprises injecting natural gas into the formation via a well in fluid communication with the formation, the natural gas being at a temperature which is insufficient to significantly mobilize light density oil in the formation and at a pressure such that the natural gas is immiscible with the light density oil in the formation, the natural gas being injected in a volume sufficient to contact light density oil in the formation within a radius from the well of about 50 meters; shutting in the well for a period of time of about 1 to about 100 days which is sufficient to render the contacted light density oil mobile; and producing the light density oil which has been mobilized by solution of the natural gas from the well.

Haines, H.K.; Monger, T.G.; Kenyon, D.E.; Galvin, L.J.

1991-06-25T23:59:59.000Z

89

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

90

Chapter 3 - Hydrocarbons from Petroleum  

Science Journals Connector (OSTI)

Publisher Summary Petroleum products (in contrast to petrochemicals) are those hydrocarbon fractions that are derived from petroleum and have commercial value as a bulk product. A major group of hydrocarbon products from petroleum (petrochemicals) are the basis of a major industry. They are, in the strictest sense, different to petroleum products insofar as the petrochemicals are the basic building blocks of the chemical industry. The specific gravity of product gases, including liquefied petroleum gas, may be determined conveniently by a number of methods and a variety of instruments. The heat value of gases is generally determined at constant pressure in a flow calorimeter in which the heat released by the combustion of a definite quantity of gas is absorbed by a measured quantity of water or air. A continuous recording calorimeter is available for measuring heat values of natural gases.

James G. Speight

2011-01-01T23:59:59.000Z

91

Discharge produces hydrocarbons from coal  

Science Journals Connector (OSTI)

Discharge produces hydrocarbons from coal ... Studies of the reactions of coal in electric discharges by two chemists at the U.S. Bureau of Mines' Pittsburgh Coal Research Center may lead to improved ways of producing acetylene and other useful chemicals from coal. ... Other workers have produced high yields of acetylene from coal by extremely rapid pyrolysis using energy sources such as plasma jets, laser beams, arc-image reactors, and flash heaters. ...

1968-01-22T23:59:59.000Z

92

Deep desulfurization of hydrocarbon fuels  

DOE Patents [OSTI]

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

93

Process for the production of ethylene and other hydrocarbons from coal  

SciTech Connect (OSTI)

A process is claimed for the production of substantial amounts of ethylene and other hydrocarbon compounds, such as benzene from coal. Coal is reacted with methane at a temperature in the approximate range of 500/sup 0/C to 1100/sup 0/C at a partial pressure less than about 200 psig for a period of less than 10 seconds, and preferably at a temperature of approximately 850/sup 0/C, and a partial pressure of 50 psig for a period of approximately 2 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

Steinberg, M.; Fallon, P.

1982-02-16T23:59:59.000Z

94

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations  

Science Journals Connector (OSTI)

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations ... The environmental implications of offshore oil and gas activities ... The environmental implications of offshore oil and gas activities ...

Theodor C. Sauer

1981-08-01T23:59:59.000Z

95

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

SciTech Connect (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

96

Hydrocarbon Separations in MetalOrganic Frameworks  

Science Journals Connector (OSTI)

Given the large differences in the physical properties of methane and C2 hydrocarbons, both size selective effects and metalhydrocarbon interactions can be tuned to achieve a high selectivity within a metalorganic framework. ... Polycyclic aromatic hydrocarbons, or PAHs, are carcinogenic byproducts of incomplete combustion of organic matter such as fossil fuels. ... data and the heats of adsorption were found to fit well to a small group of mol. ...

Zoey R. Herm; Eric D. Bloch; Jeffrey R. Long

2013-11-22T23:59:59.000Z

97

catalytic_upgrading_sugars_to_hydrocarbons  

Broader source: Energy.gov (indexed) [DOE]

phase reforming into hydrocarbons for fuels and co-product commodities. Process Block Diagram Next Steps Additional modeling is necessary to quantify baseline costs associated...

98

Application of advanced hydrocarbon characterization and its...  

Broader source: Energy.gov (indexed) [DOE]

advanced hydrocarbon characterization and its consequences on future fuel properties and advanced combustion research Rafal Gieleciak, Craig Fairbridge and Darcy Hager Poster...

99

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents [OSTI]

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

100

Biodegradation of Aromatic Hydrocarbons in an Extremely Acidic Environment  

Science Journals Connector (OSTI)

...biodegradation of aromatic hydrocarbons can occur in environments...Polycyclic aromatic hydrocarbons (PAHs) occur as common...formed by incomplete combustion of fossil fuels...enrichments with aromatic hydrocarbons, mineralization assays...lysis was initiated by heat and sodium dodecyl...

Raymond D. Stapleton; Dwayne C. Savage; Gary S. Sayler; Gary Stacey

1998-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons| Introduction Esophageal...polycyclic aromatic hydrocarbon (PAH) content. PAHs...usually exposed to combustion products from burning...SRM 2260a Aromatic Hydrocarbons in Toluene, SRM 2269...dichloromethane; heat: preheat cell at 100C...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

102

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...polycyclic aromatic hydrocarbons| Introduction...mechanism. However, data on the association...polycyclic aromatic hydrocarbon (PAH) content...usually exposed to combustion products from burning...dichloromethane; heat: preheat cell...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

103

MICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air  

E-Print Network [OSTI]

from Waters Associates. Water used was deionized, distilled, and hydrocarbon filtered (BarnsteadMICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air to extract polycyclic aromatic hydrocarbons (PAH) from air particulate sampleswas investigated. High

Canberra, University of

104

Metabolism of Polycyclic Aromatic Hydrocarbons in Cell Cultures  

Science Journals Connector (OSTI)

...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...cytotoxicity and conversion of hydrocarbons to water-soluble products (Chart...

Eliezer Huberman; James K. Selkirk; and Charles Heidelberger

1971-12-01T23:59:59.000Z

105

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...80C) or cold (5C) water. Measurements were...polycyclic aromatic hydrocarbons in mate drinks. | Drinking...polycyclic aromatic hydrocarbons (PAH), including...cold (5 degrees C) water. Measurements were...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

106

Hydrocarbons in rift basins: the role of stratigraphy  

Science Journals Connector (OSTI)

...versus shallow-water environments...A (1999) Hydrocarbons in rift basins...Facies and hydrocarbon potential The...availability of water. This can either...form seals for hydrocarbons. The shallow-water environ- ments...

1999-01-01T23:59:59.000Z

107

Learning and discrimination of cuticular hydrocarbons in a social insect  

Science Journals Connector (OSTI)

...colony members. Cuticular hydrocarbons (CHCs) play a central...CHC profile with synthetic hydrocarbons [4-6] reveal that some hydrocarbons elicit aggression. However...non-volatile, insoluble in water and therefore difficult...

2012-01-01T23:59:59.000Z

108

Distribution and elimination routes of a naphthenic hydrocarbon (Dodecylcyclohexane) in rainbow trout (Salmo gairdneri)  

SciTech Connect (OSTI)

Contamination of fish by hydrocarbons, whether it occurred directly via the water or indirectly via the food chain has been the object of many studies during the last decade. The interest of laboratories have been focused on the most toxic components of crude oils, i.e., aromatic hydrocarbons but there is a lack of information on the fate of cyclic alkanes in fish. Naphthenic hydrocarbons are the least biologically active of the more mobile fractions of petroleum; nevertheless the fate of these compounds are worth considering, because they constitute respectively 41% and 19.2% of light and heavy crude oils. This paper reports the results of our experiment in which /sup 3/H-dodecylcyclohexane has been given per os to rainbow trout in order to evaluate the distribution and elimination routes of this cycloparaffin.

Cravedi, J.P.; Tulliez, J.

1981-03-01T23:59:59.000Z

109

Tensile Effective Stresses in Hydrocarbon Storage Caverns  

E-Print Network [OSTI]

Tensile Effective Stresses in Hydrocarbon Storage Caverns Hippolyte Djizanne and Pierre Bérest LMS, Germany,1-2 October 2012 TENSILE EFFECTIVE STRESSES IN HYDROCARBON STORAGE CAVERNS Hippolyte Djizanne1 that effective tensile stresses can be generated at a cavern wall after a rapid increase or decrease in pressure

Paris-Sud XI, Université de

110

Conversion of organic solids to hydrocarbons  

DOE Patents [OSTI]

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

111

The Effects of Two Isomeric Benzoflavones on Aryl Hydrocarbon Hydroxylase and the Toxicity and Carcinogenicity of Polycyclic Hydrocarbons  

Science Journals Connector (OSTI)

...recrystallized from alcohol : water. For tissue culture experiments the hydrocarbons and benzoflavones...metabolism of the hydrocarbons to water-soluble derivatives...chloroform:methanol. Hydrocarbon-3 H metabolized to water-soluble derivatives...

Leila Diamond; Rosemary McFall; Joel Miller; and Harry V. Gelboin

1972-04-01T23:59:59.000Z

112

Hydrocarbon fouling of SCR during Premixed Charge Compression...  

Broader source: Energy.gov (indexed) [DOE]

Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion...

113

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...  

Broader source: Energy.gov (indexed) [DOE]

and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Algal Lipid Extraction and Upgrading to Hydrocarbons...

114

DOE Perspectives on Advanced Hydrocarbon-based Biofuels | Department...  

Broader source: Energy.gov (indexed) [DOE]

DOE Perspectives on Advanced Hydrocarbon-based Biofuels DOE Perspectives on Advanced Hydrocarbon-based Biofuels Zia Haq, DPA Coordinator, presentation on DOE Perspectives on...

115

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel...  

Broader source: Energy.gov (indexed) [DOE]

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and...

116

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

117

Preparation of synthetic hydrocarbon lubricants  

SciTech Connect (OSTI)

A process is described for preparing synthetic lubricating materials which process comprises: (a) reacting (i) at least a portion of a reaction product of the liquid phase oligomerization of propylene, butylene or mixtures thereof containing a C/sub 6/ olefin component, (ii) a linear olefin reactant having an average carbon number ranging from about 10 to about 18 in the presence of a catalyst, (b) separating from the reaction mixture of (a) hydrocarbons which distill at a temperature above about 660/sup 0/ F. (316/sup 0/ C.), and (c) hydrogenating the reaction product of (b) by contact with hydrogen with or without a catalyst at a temperature ranging from about 25/sup 0/ C. to about 300/sup 0/ C.

Johnson, T.H.

1986-10-07T23:59:59.000Z

118

14 The College will remain primarily a residential university, offering research-led education in science, engineering, medicine and busi-  

E-Print Network [OSTI]

14 The College will remain primarily a residential university, offering research-led education at the College. · To provide a research-led education of the highest international quality within and practical experience Research-led education Intellectualand professionaldevelopment UG PGT PGR Imperial

119

Polycyclic Aromatic Hydrocarbons in C8 Isomer Aromatic Feed: Analysis by GC, GC/MS, and GC/FTIR Techniques  

Science Journals Connector (OSTI)

......in fossil fuels, combustion products, and automotive...understanding the chemistry of the formation...The analytical chemistry of P A H compounds...PAHs present in coal-derived hydrocarbons...Hazardous chemicals from coal conversion process...Bartle. Analytical Chemistry of Polycyclic Aromatic......

V.N. Garg; B.D. Bhatt; V.K. Kaushik; K.R. Murthy

1987-06-01T23:59:59.000Z

120

Association of Carcinogenic Polycyclic Aromatic Hydrocarbon Emissions and Smoking with Lung Cancer Mortality Rates on a Global Scale  

Science Journals Connector (OSTI)

(2, 4) For most populations, approximately 80% of all lung cancer cases are associated with tobacco smoking and the remaining 20% have been attributed to exposure to secondhand smoke, radon (and its decay products), asbestos, some metals (including arsenic, beryllium, cadmium), organic compounds (including carcinogenic polycyclic aromatic hydrocarbons (PAHs)), radiation, and genetic susceptibility. ...

Oleksii Motorykin; Melissa M. Matzke; Katrina M. Waters; Staci L. Massey Simonich

2013-03-08T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Partitioning of Crude Oil Polycyclic Aromatic Hydrocarbons in Aquatic Systems  

Science Journals Connector (OSTI)

Environmental and Water Resources Division, Civil Engineering Department, Texas A&M University, College Station, Texas 77843-3136, Conrad Blucher Institute for Surveying and Science, Texas A&M UniversityCorpus Christi, 6300 Ocean Drive, Corpus Christi, Texas 78412, and Environmental Engineering Department, Texas A&M UniversityKingsville, Kingsville, Texas 78363 ... In natural water systems, entrainment and mixing result primarily from wind and current stresses. ... For compound analysis, a 1-?L aliquot of the extracted sample was injected into a Hewlett-Packard 5890 Series II gas chromatograph (GC) interfaced to a Hewlett-Packard 5972 mass selective (MS) detector and operated using Hewlett-Packard MS Chemstation software. ...

Michael C. Sterling, Jr.; James S. Bonner; Cheryl A. Page; Christopher B. Fuller; Andrew N. S. Ernest; Robin L. Autenrieth

2003-09-06T23:59:59.000Z

122

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

123

Removal of trace olefins from aromatic hydrocarbons  

SciTech Connect (OSTI)

A process is described for treating a hydrocarbon process stream by converting trace quantities of olefinic impurities to nonolefinic hydrocarbons. The process comprises contacting the process stream, which contains trace olefins in an amount of from about 50 to about 2000 as measured by Bromine Index and at least 80% by weight of aromatic and naphthenic hydrocarbons having from 6 to 20 carbon atoms per molecule, at reaction conditions which ensure liquid phase operation with a solid catalyst composite comprising a crystalline aluminosilicate zeolite and a refractory inorganic oxide. A catalytic olefin-consuming alkylation reaction then produces an essentially olefinfree product stream with approximately the same quantity and distribution of aromatic and naphthenic hydrocarbons as contained in the process stream.

Sachtler, J.W.A.; Barger, P.T.

1989-01-03T23:59:59.000Z

124

Analyzing Biomass Conversion into Liquid Hydrocarbons  

Science Journals Connector (OSTI)

Variants of the FischerTropsch producer-gas conversion into liquid hydrocarbons are analyzed under the ... is attained in the reactions occurring in the biomass gasification. When the raw material is wood ... th...

V. D. Meshcheryakov; V. A. Kirillov

2002-09-01T23:59:59.000Z

125

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

126

Polynuclear aromatic hydrocarbons (PAHs) in fish from the Arabian Gulf  

SciTech Connect (OSTI)

Emphasis has been placed upon the identification and qualification of compounds with potential adverse health effects on humans. Prominent among this group are polynuclear aromatic hydrocarbons (PAHs), several of which are known or suspected carcinogens. PAHs enter the marine environment from a variety of sources including petroleum pollution, industrial and domestic effluents, atmospheric particles, and biosynthesis by plants and microorganisms. Although one-third of the world's oil is produced around the Arabian Gulf, no detailed analysis have been conducted to determine PAHs in this region. Nevertheless, numerous investigations have shown the ability of marine organisms including fish to accumulation PAHs from solution or dispersion in seawater. When fish are harvested, a human health hazard may result. In the present communication, high performance liquid chromatography (HPLC) was used to identify and measure sixteen PAHs priority pollutants issued by US Environmental Protection Agency (EPA) in fourteen species of commercially significant fish from the NW Arabian Gulf.

DouAbdul, A.A.Z.; Abaychi, J.K.; Al-Edanee, T.E.; Ghani, A.A.; Al-Saad, H.T.

1987-03-01T23:59:59.000Z

127

Distribution of polycyclic aromatic hydrocarbons (PAH's) in marsh sediments, Iraq  

SciTech Connect (OSTI)

Recently there has been a growing concern in the release of harmful organics into the environment. Carcinogenic polycyclic aromatic hydrocarbons (PAH's) are a class of compounds of interset due to their possible harmful effects to man as well as organisms. Anthropogenic PAH's may reach aquatic environment as a result of both industrial and domestic effluents, deposition of airborne particles, surface runoff and oil spillage. Having a relatively low water solubility and high affinity to sorb to the suspended particulate matter, most of the PAH's introduced to the aquatic environment tend to accumulate in bottom sediments. Sedimentary PAH's may thus provide a record of the input and history of these pollutants. Consequently, the distribution of PAH's in aquatic sediments have received considerable attention. The purpose of the present work was to establish the distribution of PAH's in the sediments of the marsh region located in southern Iraq.

Al-Saad, H.T.; Al-Timari, A.A. (Univ. of Basrah (Iraq))

1989-12-01T23:59:59.000Z

128

Methanol conversion to higher hydrocarbons  

SciTech Connect (OSTI)

Several indirect options exist for producing chemicals and transportation fuels from coal, natural gas, or biomass. All involve an initial conversion step to synthesis gas (CO and H{sub 2}). Presently, there are two commercial technologies for converting syngas to liquids: Fischer-Tropsch, which yields a range of aliphatic hydrocarbons with molecular weights determined by Schulz-Flory kinetics, and methanol synthesis. Mobil`s diversity of technology for methanol conversion gives the methanol synthesis route flexibility for production of either gasoline, distillate or chemicals. Mobil`s ZSM-5 catalyst is the key in several processes for producing chemicals and transportation fuels from methanol: MTO for light olefins, MTG for gasoline, MOGD for distillates. The MTG process has been commercialized in New Zealand since 1985, producing one-third of the country`s gasoline supply, while MTO and MOGD have been developed and demonstrated at greater than 100 BPD scale. This paper will discuss recent work in understanding methanol conversion chemistry and the various options for its use.

Tabak, S.A. [Mobil Research and Development Corp., Princeton, NJ (United States). Central Research Lab.

1994-12-31T23:59:59.000Z

129

Prognostic Cell Biological Markers in Cervical Cancer Patients Primarily Treated With (Chemo)radiation: A Systematic Review  

SciTech Connect (OSTI)

The aim of this study was to systematically review the prognostic and predictive significance of cell biological markers in cervical cancer patients primarily treated with (chemo)radiation. A PubMed, Embase, and Cochrane literature search was performed. Studies describing a relation between a cell biological marker and survival in {>=}50 cervical cancer patients primarily treated with (chemo)radiation were selected. Study quality was assessed, and studies with a quality score of 4 or lower were excluded. Cell biological markers were clustered on biological function, and the prognostic and predictive significance of these markers was described. In total, 42 studies concerning 82 cell biological markers were included in this systematic review. In addition to cyclooxygenase-2 (COX-2) and serum squamous cell carcinoma antigen (SCC-ag) levels, markers associated with poor prognosis were involved in epidermal growth factor receptor (EGFR) signaling (EGFR and C-erbB-2) and in angiogenesis and hypoxia (carbonic anhydrase 9 and hypoxia-inducible factor-1{alpha}). Epidermal growth factor receptor and C-erbB-2 were also associated with poor response to (chemo)radiation. In conclusion, EGFR signaling is associated with poor prognosis and response to therapy in cervical cancer patients primarily treated with (chemo)radiation, whereas markers involved in angiogenesis and hypoxia, COX-2, and serum SCC-ag levels are associated with a poor prognosis. Therefore, targeting these pathways in combination with chemoradiation may improve survival in advanced-stage cervical cancer patients.

Noordhuis, Maartje G.; Eijsink, Jasper J.H.; Roossink, Frank; Graeff, Pauline de [Department of Gynecologic Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Pras, Elisabeth [Department of Radiation Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Schuuring, Ed [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Wisman, G. Bea A. [Department of Gynecologic Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Bock, Geertruida H. de [Department of Epidemiology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Zee, Ate G.J. van der, E-mail: a.g.j.van.der.zee@og.umcg.n [Department of Gynecologic Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands)

2011-02-01T23:59:59.000Z

130

Corrosion inhibitors in hydrocarbon systems  

SciTech Connect (OSTI)

An attempt has been made to provide directions to select the various corrosion inhibitors for different areas of petroleum industry based on their available structure-activity relationship. The present review highlights the utility of most of the inhibitors (used in production, handling, and distillation of crude oils) which are either N-containing compounds or their derivatives. The action of specific corrosion inhibitors used in oil well acidizing, refining units handling naphthenic acid crudes, and amine gas absorbers has been explained. Emphasis has been laid on the dependence of the inhibitor performance on the type of the test method used for its evaluation. 54 refs., 6 figs., 5 tabs.

Jayaraman, A.; Saxena, R.C. [Indian Inst. of Petroleum, Dehra Dun (India)

1996-08-01T23:59:59.000Z

131

Influence of resinous compounds in petroleum oils on formation of protective films by additives with labeled atoms  

SciTech Connect (OSTI)

The role of resinous compounds present in oil media in terms of their effects of protective film formation and corrosive wear of metal is investigated. Radioactive additives consisting of barium salts of an alkylphenol sulfide and an alkylphenol disulfide, containing a functional group of sulfur 35, were synthesized. These additives were added to the test oil in an amount of 3%. In most cases, the additives tend to form more stable films on the metal surface when they are used in oils containing resinous compounds than when they are used in individual groups of hydrocarbons. The quantity and efficiency of the protective film formed by the additive depends not only on the hydrocarbon structure of the oil hydrocarbons, but also on the quality of the additive, the nature of the metal, and the content of resinous compounds in the oil and the structure of these compounds.

Faradzhev, K.F.

1988-09-01T23:59:59.000Z

132

Hydrocarbons in age-dated sediment cores from two basins in the Southern California Bight  

Science Journals Connector (OSTI)

The distributions of hydrocarbons in sediment cores dated by 210Pb (18451977) from San Pedro and San Nicolas Basins in the Southern California Bight have been determined by gas Chromatographic and combined gas chromatographic-mass spectrometric analysis. The chromatograms of the hydrocarbons contain peaks of resolved alkanes and cycloalkanes, as well as an unresolved complex mixture which decrease in content with increasing depth in both of the cores. The concentrations of o,p' andp,p'-DDE are highest in the top 50 mm of the San Pedro core section. The 4550 mm segment of this core was deposited in the 19451950 period when DDT (the precursor of DDE compounds) came into common use. The relatively high content of hydrocarbons and DDE in this core is attributable to the proximity of the site to the San Pedro Harbor which receives petroleum residues from shipping, sewage outfalls and industrial effluents. The presence of only traces of DDE throughout the San Nicolas core, and the low hydrocarbon content are explainable by the greater distance of this basin from anthropogenic inputs and probably a greater rate of degradation of deposited organic matter during bioturbation. ?13C, ?15N and electron-spin resonance analyses of kerogens and humic substances in these cores, indicate that most of this organic matter in these sediments is of a marine origin.

M.I Venkatesan; S Brenner; E Ruth; J Bonilla; I.R Kaplan

1980-01-01T23:59:59.000Z

133

Gulf Hydrocarbon Inc | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Inc Hydrocarbon Inc Jump to: navigation, search Name Gulf Hydrocarbon Inc Address 2016 Main St Place Houston, Texas Zip 77002 Sector Biofuels Product Wholesale marketing of biodiesel and ethanol to refiners, blenders and petroleum distributors Website http://www.gulfhydrocarbon.com Coordinates 29.749227°, -95.371693° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.749227,"lon":-95.371693,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

134

George A. Olah, Carbocation and Hydrocarbon Chemistry  

Office of Scientific and Technical Information (OSTI)

George A. Olah, Carbocation and Hydrocarbon Chemistry George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information · Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations are stable and their physical properties ... can be observed, thus allowing details of their structures to be determined. Besides trivalent ions ... Olah demonstrated the existence of higher coordinate carbocations ... . These species do not violate the octet rule, but involve 2-electron 3-center bonding. '1

135

Using supercritical fluids to refine hydrocarbons  

DOE Patents [OSTI]

This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

Yarbro, Stephen Lee

2014-11-25T23:59:59.000Z

136

Regressing Gas/Particle Partitioning Data for Polycyclic Aromatic Hydrocarbons  

Science Journals Connector (OSTI)

Regressing Gas/Particle Partitioning Data for Polycyclic Aromatic Hydrocarbons ... Although PAHs can be emitted to the environment as a result of natural combustion processes (e.g., forest fires and volcanoes), human activities are believed to dominate global PAH emissions, because high atmospheric concentrations of PAHs are usually observed in urban and industrial areas where vehicle traffic, aluminum smelting, residential heating, and other activities emit PAHs into the atmosphere (4, 5). ... One of the earliest approaches to describing the G/P partitioning equilibrium of PAHs, known as the Junge?Pankow model, relates ? to PL using the following: The parameter A in this equation is sometimes interpreted as the product of two terms c and ?. ? is the surface area of particles in a unit volume of air (cm2cm-3) and c (Pacm) is a substance-specific factor depending on ambient temper ature, compound, sorption sites, and the heats of desorption from surface and vaporization from the liquid compound (7, 10, 14). ...

Yushan Su; Ying Duan Lei; Frank Wania; Mahiba Shoeib; Tom Harner

2006-04-22T23:59:59.000Z

137

E-Print Network 3.0 - aromatic hydrocarbons evaluated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

138

E-Print Network 3.0 - aromatic hydrocarbons part Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

139

Sexual selection on cuticular hydrocarbons of male sagebrush crickets in the wild  

Science Journals Connector (OSTI)

...association between cuticular hydrocarbon composition and desiccation...temperature on cuticular lipids and water balance in a desert Drosophila...interactions for cuticular hydrocarbon expression in Drosophila simulans...evolutionary roles of cuticular hydrocarbons in Diptera. In Insect hydrocarbons...

2013-01-01T23:59:59.000Z

140

Sustainable treatment of hydrocarbon-contaminated industrial land  

E-Print Network [OSTI]

Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

Cunningham, Colin John

2012-06-25T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Chemical nature of high-molecular hydrocarbons of gaseous condensates  

SciTech Connect (OSTI)

Mass spectrometry was used to study the group-structure composition of high-boiling 50 deg (200/degrees/-250/degrees/, 250/degrees/-300/degrees/, and 300/degrees/-350/degrees/C) fractions of East Turkmenistan condensates: the hydrocarbons composition is characterized by a high content of paraffinic hydrocarbons, and that of others by aromatic and naphthenic hydrocarbons. For all the condensates under investigation, as the boiling temperature of fractions increases, the content of paraffinic hydrocarbons in them is increased, while that of naphthenic hydrocarbons is reduced. The distribution of naphthenic hydrocarbons according to the number of rings is identical. In high-paraffin condensates, monoaromatic hydrocarbons consist mainly structures with alkyl substituents, but in condensates with a high content of aromatic and naphthenic hydrocarbons they consist mainly of structures with naphthenic substituents. 4 references, 1 figures, 2 tables.

Kul'dzhayev, B.A.; Makarov, V.V.; Sergiyenko, S.R.; Khramova, E.V.

1987-01-01T23:59:59.000Z

142

E-Print Network 3.0 - aromatic hydrocarbons methyl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Renewable Energy 2 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

143

E-Print Network 3.0 - aromatic hydrocarbons progress Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

144

E-Print Network 3.0 - aromatic hydrocarbons fluorene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

145

E-Print Network 3.0 - aromatic hydrocarbon phenanthrene Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

146

E-Print Network 3.0 - aromatic hydrocarbons Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

147

E-Print Network 3.0 - aromatic hydrocarbons pah5 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants Summary: 1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous,...

148

E-Print Network 3.0 - aromatic hydrocarbons inenvironmental Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

149

E-Print Network 3.0 - aromatic hydrocarbon o-quinones Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

150

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enzymes Acid + Caustic Wastewater Treatment Process Heat and Power Integration Biogas + Sludge Fuel Finishing (hydroprocessing, as needed) Electricity Hydrogen Hydrocarbon...

151

THE ELECTRON MICROSCOPY OF HYDROCARBON PRODUCTION IN PARTHENIUM ARGENTATUM (GUAYULE)  

E-Print Network [OSTI]

conversion of solar energy is the production of hydrocarbonsproduction of hydrocarbons. Mankind's use of biologically converted solar energy

Bauer, T.E.

2010-01-01T23:59:59.000Z

152

aromatic hydrocarbons coated: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ??Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, known human lung carcinogens, and potent mammary carcinogens in animal models....

153

Polycyclic aromatic hydrocarbons (PAH) in top soil, leachate and groundwater from Ruseifa solid waste landfill, Jordan  

Science Journals Connector (OSTI)

The distribution profiles and pathways of polynuclear aromatic hydrocarbons in the surroundings of Ruseifa landfill area in Jordan were investigated for surface sediments, leachate, and groundwater. The total concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in sediments ranged from 286 to 1704 ppm with an average value of 751 ppm. Meanwhile, concentrations of PAH in groundwater ranged between 7.1 and 12.6 ppm with an average value of 9.1 ppm. The PAH in leachate varied between 0.10 and 0.40 with an average value of 0.29 ppm. The overall PAH distribution profiles appeared to be similar for leachate and groundwater dominated by 2??3 rings system molecules. While, the sediments profile was dominated by 4??6 rings system molecules which indicated the loss of low molecular weight compounds of PAH and accumulation of higher molecular weight of PAH under prevailing semiarid and hot climatic conditions.

Anwar Jiries; Omar Rimawi; Jutta Lintelmann; Mufeed Batarseh

2005-01-01T23:59:59.000Z

154

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents [OSTI]

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

155

Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons  

Science Journals Connector (OSTI)

... in the flask's headspace. This procedure produced negligible amounts of contaminating hydrocarbons. The geothermal hydrocarbons were separated and combusted, and the carbon dioxide product purified and measured using ... of the pyrolysis and spark discharge experiments, b, Isotopic abundance of hydrocarbons from four geothermal localities as follows: D, Cerro Prieto, well M-5, sampled January 1979; ...

David J. Des Marais; Jason H. Donchin; Nancy L. Nehring; Alfred H. Truesdell

1981-08-27T23:59:59.000Z

156

Mononuclear Organolead Compounds  

Science Journals Connector (OSTI)

Tetraorganolead compounds in general exhibit lower thermal stability and greater reactivity than the corresponding compounds of the lighter Group 14 elements. The thermal stability is strongly dependent on the...

Friedo Huber; Wolfgang Petz

1987-01-01T23:59:59.000Z

157

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

158

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

159

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

160

Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon  

SciTech Connect (OSTI)

The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

2012-08-19T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Mass Transfer of Polynuclear Aromatic Hydrocarbons from  

E-Print Network [OSTI]

of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

Peters, Catherine A.

162

Elements & Compounds Atoms (Elements)  

E-Print Network [OSTI]

#12;Elements & Compounds #12;Atoms (Elements) Molecules (Compounds) Cells Elements & Compounds #12;Nucleus Electrons Cloud of negative charge (2 electrons) Fig. 2.5: Simplified model of a Helium (He) Atom He 4.002602 2 Helium Mass Number (~atomic mass) = number of Neutrons + Protons = 4 for Helium Atomic

Frey, Terry

163

Predicting the Net Heat of Combustion of Organosilicon Compounds from Molecular Structures  

Science Journals Connector (OSTI)

Predicting the Net Heat of Combustion of Organosilicon Compounds from Molecular Structures ... ?Hc is an important physicochemical property which can be used to calculate the reactive heat in many chemical engineering processes such as the processes of hydrogenation and dehydrogenation of hydrocarbon. ... (4) In his paper, empirical equations have been developed to predict the gross and the net heats of combustion of organosilicon compounds based on the atomic contribution method. ...

Yong Pan; Juncheng Jiang; Yinyan Zhang

2012-09-05T23:59:59.000Z

164

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...WI 53706 The aryl hydrocarbon receptor (AHR) is...The mammalian aryl hydrocarbon receptor (AHR) is...complex with the 90-kDa heat shock protein (HSP90) and...polycyclic aromatic hydrocarbons such as {beta...cigarette smoking and other combustion processes, initiate...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

165

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...mammalian aryl hydrocarbon receptor...the 90-kDa heat shock protein (HSP90...polycyclic aromatic hydrocarbons such as {beta...smoking and other combustion processes...we searched data from the...Helminth HSP90 Heat-Shock Proteins...Molecular Sequence Data Protein Binding...Receptors, Aryl Hydrocarbon genetics metabolism...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

166

Aerobic Biofilms Grown from Athabasca Watershed Sediments Are Inhibited by Increasing Concentrations of Bituminous Compounds  

Science Journals Connector (OSTI)

...step at 95C, followed by 25 cycles of 30 s at 95C, 30 s at 55C...hydrocarbon compounds. Thus, for general inhibition of the microbial...temperature and freeze-thaw cycle frequency. Environ. Microbiol...degradation in Arctic soils following diesel and nutrient disturbance. ISME...

Etienne Yergeau; John R. Lawrence; Sylvie Sanschagrin; Julie L. Roy; George D. W. Swerhone; Darren R. Korber; Charles W. Greer

2013-09-20T23:59:59.000Z

167

Hydrocarbon composition of crude oils near the Caspian depression  

SciTech Connect (OSTI)

The structural-group composition of hydrocarbons of Mesozoic crude oils near the Caspian depression was investigated by mass-spectrometry, followed by the analysis of the mass-spectra using a computer. The distribution of naphthenic hydrocarbons, according to the number of rings and of aromatic hydrocarbons, according to the degree of hydrogen unsaturation is similar for all the crude oils examined. The hydrocarbon composition of Mesozoic crude oils is characterized by a reduction in the content of aliphatic hydrocarbons and alkyl benzenes.

Botneva, T.A.; Khramova, E.V.; Nekhamkina, L.G.; Polyakova, A.A.

1983-01-01T23:59:59.000Z

168

Composition of paraffinic and naphthenic hydrocarbons in petroleum asphalts  

SciTech Connect (OSTI)

Uses a combination of chromatographic, chemical, and spectroscopic methods to determine the composition of the paraffinic and naphthenic hydrocarbons recovered from asphalts. Monitors the completeness of separation of the hydrocarbons from the aromatics on the basis of UV spectra. Finds that in the mixture of adduct-forming hydrocarbons, along with the n-paraffins there were admixtures of isoparaffins and longchain alkylnaphthenes. Concludes that a comparison of the structural-group composition of the asphalt fractions from the different crudes shows that there are only slight differences in the structure of the paraffinic/naphthenic hydrocarbons present in these asphalts, particularly with regard to those hydrocarbons that do not react with urea.

Botvin'eva, A.M.; Dubkova, R.V.; Shkredova, N.A.

1982-11-01T23:59:59.000Z

169

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents [OSTI]

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

170

Electric Turbo Compounding Technology Update  

Broader source: Energy.gov (indexed) [DOE]

Turbo Compounding Technology Update Electric Turbo Compounding Technology Update 15 August, 2007 Carl Vuk 15 August, 2007 Carl Vuk Electric Turbo Compounding Highlights Electric...

171

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents [OSTI]

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

172

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

SciTech Connect (OSTI)

We have suggested that certain plants rich in hydrocarbon-like materials might be cultivated for renewable photosynthetic products. Two species were selected for experimental plantations: Euphorbia lathyris, an annual from seed and Euphorbia tirucalli, a perennial from cuttings, The yield from each species is over 10 barrels of oil/acre/year without genetic or agronomic improvement. In addition to plants, there are trees, such as species of Copaifera in Brazil and other tropical areas, which produce a diesel-like oil upon tapping. Each tree produces approximately 40 liters of hydrocarbon per year, and this material can be used directly by a diesel-powered car. Further efforts to develop plants as alternate energy sources are underway, as well as a continuing search for additional plant species throughout the world which have a similar capability.

Calvin, Melvin

1980-05-01T23:59:59.000Z

173

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents [OSTI]

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

174

Getter pump for hydrogen and hydrocarbon gases  

DOE Patents [OSTI]

A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

Hsu, Wen Ling

1987-10-14T23:59:59.000Z

175

Partially fluorinated ionic compounds  

DOE Patents [OSTI]

Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.

Han, legal representative, Amy Qi (Hockessin, DE); Yang, Zhen-Yu (Hockessin, DE)

2008-11-25T23:59:59.000Z

176

Comparisons of hydrocarbon and nitrogen distributions in geologically diverse tar sand bitumen  

SciTech Connect (OSTI)

The characteristics of bitumens from different tar sand deposits are generally significantly different and affect the utilization of the resource. The chemical and physical properties of bitumen are a result of maturation reactions on the varied organic sediments. For example, saturated hydrocarbon distributions have been related to the geochemical history of organic matter. Very paraffinic or sometimes paraffinic-naphthenic distributions in organic matter are derived from a nonmarine depositional environment. More aromatic and paraffinic-naphthenic hydrocarbon distributions are derived from organic matter deposited in a marine environment. The characteristics of the bitumen also influence the potential for recovery and subsequent processing of the material. For example, saturated hydrocarbons contribute to the high pour points of recovered oils. The origin and composition of an oil influence its viscosity, API gravity, and coke formation during processing, particularly under low-temperature oxidation conditions. The objective of this work is to determine the chemical and physical properties of several samples of bitumen from geologically diverse tar sand deposits. The compound-type distributions and LTD properties of these bitumens are discussed relative to the depositional environment and processing potential of the organic matter.

Holmes, S.A.

1988-06-01T23:59:59.000Z

177

Modeling of structure H hydrate equilibria for methane, intermediate hydrocarbon molecules and water systems  

SciTech Connect (OSTI)

Clathrate hydrates are inclusion compounds in which guest molecules are engaged by water molecules under favorable conditions of pressure and temperature. The well known structures 1 and 2 have been discovered since last century, while a new structure called H has been recently described in the literature. Since that time, structure H hydrate equilibrium data involving methane and different intermediate liquid hydrocarbon molecules have been published. The equilibrium calculations involving hydrates are based on the fact that the chemical potential of water in the aqueous liquid phase is equal to the one in the hydrate phase. The chemical potential of water in the liquid aqueous phase can be easily described by classical thermodynamic relations, while the chemical potential of water in the hydrates phase is described by the expressions proposed by Van der Walls and Platteeuw derived from an adsorption model based on statistical thermodynamics. The authors present in this paper a set of Kihara potential parameters which enable the calculation of Langmuir constants which characterize the adsorption of some naphthenic and iso-paraffinic intermediate hydrocarbons in the larger cage of structure H hydrates. This work thus allows the computation of structural H hydrate equilibrium conditions for systems made of methane, intermediate hydrocarbon molecules and water.

Thomas, M.; Behar, E. [Inst. Francais du Petrole, Rueil-Malmaison (France)

1996-12-31T23:59:59.000Z

178

Assessment of soil pollution based on total petroleum hydrocarbons and individual oil substances  

Science Journals Connector (OSTI)

Abstract Different oil products like gasoline, diesel or heavy oils can cause soil contamination. The assessment of soils exposed to oil products can be conducted through the comparison between a measured concentration and an intervention value (IV). Several national policies include the IV based on the so called total petroleum hydrocarbons (TPH) measure. However, the TPH assessment does not indicate the individual substances that may produce contamination. The soil quality assessment can be improved by including common hazardous compounds as polycyclic aromatic hydrocarbons (PAHs) and aromatic volatile hydrocarbons like benzene, toluene, ethylbenzene and xylenes (BTEX). This study, focused on 62 samples collected from different sites throughout The Netherlands, evaluates TPH, PAH and BTEX concentrations in soils. Several indices of pollution are defined for the assessment of individual variables (TPH, PAH, B, T, E, and X) and multivariables (MV, BTEX), allowing us to group the pollutants and simplify the methodology. TPH and PAH concentrations above the IV are mainly found in medium and heavy oil products such as diesel and heavy oil. On the other hand, unacceptable BTEX concentrations are reached in soils contaminated with gasoline and kerosene. The TPH assessment suggests the need for further action to include lighter products. The application of multivariable indices allows us to include these products in the soil quality assessment without changing the IV for TPH. This work provides useful information about the soil quality assessment methodology of oil products in soils, focussing the analysis into the substances that mainly cause the risk.

J. Pinedo; R. Ibez; J.P.A. Lijzen; . Irabien

2013-01-01T23:59:59.000Z

179

Polyhalogenated hydrocarbon refrigerants and refrigerant oils colored with fluorescent dyes and method for their use as leak detectors  

SciTech Connect (OSTI)

A leak detectable refrigeration composition is described comprising: (A) a refrigeration liquid selection from the group consisting of: (1) a polyhalogenated hydrocarbon refrigerant; (2) a refrigeration oil selected from the group consisting of naphthenic oils, paraffinic oils, alkylated benzenes, silicones, polyglycols, diesters or triesters of dicarboxylic or tricarboxylic acids, and polyalkyl silicate oils, and (3) a mixture of A(1) and A(2), and (B) a fluorescent dye compound or composition comprising the dye selected from the group consisting of: (1) a fluorescent dye selected from the group consisting of perylene, naphthoxanthene, monocyclic aromatic compounds having an organometallic compound, (2) a solution of fluorescent dye in a solvent, and (3) a mixture of B(1) and B(2). The fluorescent dye compound or composition is soluble in the refrigeration liquid. The concentration of the dye being at least 0.001 grams per 100 grams of the refrigeration liquid.

Parekh, M.

1988-07-19T23:59:59.000Z

180

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Liquefaction of cellulosic wastes. 6: Oxygen compounds in pyrolytic oil and water fractions  

SciTech Connect (OSTI)

Liquid hydrocarbon oil and water have been produced from the liquefaction of cellulosic matter present in municipal solid wastes. The produced pyrolytic oil and water fraction seemed to be contaminated with considerable amounts of oxygen compounds as compared with fuels derived from a petroleum origin. The oxygen compounds included organic acids (fatty and naphthenic acids), phenols, and carbonyl compounds. These classes of oxygen compounds were extracted selectively from the pyrolytic oils and water using chemical extraction methods. Methyl esters of fatty acids and 2,4-dinitrophenylhydrazones of carbonyl compounds were identified by gas chromatography and thin layer chromatography, respectively. It was suggested that the identified oxygen compounds could be produced from the pyrolysis of volatiles (e.g., levoglucosane, which is the primary product of cellulose depolymerization) via different mechanistic pathways.

Gharieb, H.K.; Faramawy, S.; El-Amrousi, F.A.; El-Sabagh, S.M. [Egyptian Petroleum Research Inst., Cairo (Egypt)

1998-07-01T23:59:59.000Z

182

Multimedia fate of petroleum hydrocarbons in the soil: Oil matrix of constructed biopiles  

Science Journals Connector (OSTI)

A dynamic multimedia fugacity model was used to evaluate the partitioning and fate of petroleum hydrocarbon fractions and aromatic indicator compounds within the soil: oil matrix of three biopiles. Each biopile was characterised by four compartments: air, water, soil solids and non-aqueous phase liquid (NAPL). Equilibrium partitioning in biopile A and B suggested that most fractions resided in the NAPL, with the exception of the aromatic fraction with an equivalent carbon number from 5 to 7 (EC5?7). In Biopile C, which had the highest soil organic carbon content (13%), the soil solids were the most important compartment for both light aliphatic fractions (EC5?6 and EC6?8) and aromatic fractions, excluding the EC16?21 and EC21?35. Our starting hypothesis was that hydrocarbons do not degrade within the NAPL. This was supported by the agreement between predicted and measured hydrocarbon concentrations in Biopile B when the degradation rate constant in NAPL was set to zero. In all scenarios, biodegradation in soil was predicted as the dominant removal process for all fractions, except for the aliphatic EC5?6 which was predominantly lost via volatilization. The absence of an explicit NAPL phase in the model yielded a similar prediction of total petroleum hydrocarbon (TPH) behaviour; however the predicted concentrations in the air and water phases were significantly increased with consequent changes in potential mobility. Further comparisons between predictions and measured data, particularly concentrations in the soil mobile phases, are required to ascertain the true value of including an explicit NAPL in models of this kind.

Frdric Coulon; Michael J. Whelan; Graeme I. Paton; Kirk T. Semple; Raffaella Villa; Simon J.T. Pollard

2010-01-01T23:59:59.000Z

183

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fractionation Hydrogen Acid, Caustic, Enzymes Wastewater Treatment Insoluble solids Biogas + Sludge Process Heat and Power Integration Corn Stover Hydrocarbon Biofuels (i.e....

184

Biological Conversion of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with...

185

CSIA of Petroleum Hydrocarbons: Forensic Fingerprinting and Oil Spill Characterisation.  

E-Print Network [OSTI]

??This thesis has identified a suite of hydrocarbon diagnostic indices to be applied in the forensic fingerprinting of diesel oil characterisation and source identification using (more)

Muhammad, Syahidah Akmal binti

2012-01-01T23:59:59.000Z

186

The mobility of petroleum hydrocarbons in Athabasca oil sands tailings.  

E-Print Network [OSTI]

??Several oil sands tailings from Suncor Energy Inc. were analysed with respect to the mobility and solubility of the petroleum hydrocarbon (PHC) contaminants. At sites (more)

Brickner, Heather

2014-01-01T23:59:59.000Z

187

Process for making unsaturated hydrocarbons using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

2011-04-12T23:59:59.000Z

188

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

189

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

190

Selective aerobic oxidation of hydrocarbons over supported gold catalysts.  

E-Print Network [OSTI]

??The selective oxidation of hydrocarbons is of vital importance for the production of valuable chemicals from crude oil and natural gas resources. Unfortunately, when using (more)

Hereijgers, B.P.C.

2011-01-01T23:59:59.000Z

191

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

192

Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst  

Broader source: Energy.gov [DOE]

Understanding what reactions and which catalytic functions are affected by hydrocarbons can lead to improved tolerances for selective catalytic reduction performance

193

Electrical dispersion of water drops suspended in hydrocarbons  

Science Journals Connector (OSTI)

The effects of alternating (50 Hz) and direct current fields on drops of distilled water in a nonpolar hydrocarbon medium were examined.

G. M. Panchenkov; V. V. Papko; V. Ya. Baranov

1968-10-01T23:59:59.000Z

194

Systems and methods for producing hydrocarbons from tar sands formations  

DOE Patents [OSTI]

A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

2009-07-21T23:59:59.000Z

195

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Broader source: Energy.gov (indexed) [DOE]

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

196

Selected Values of Heats of Combustion and Heats of Formation of Organic Compounds Containing the Elements C, H, N, O, P, and S.  

Science Journals Connector (OSTI)

Selected values of the heats of combustion and heats of formation of 719 organic compounds are reported here. The data tabulated pertain to compounds containing the elements carbon hydrogen nitrogen oxygen phosphorus and sulfur (CHNOPS). The information is arranged according to classes of compounds and within each class compounds are arranged by empirical formula. The general classes covered are: hydrocarbons alcohols phenols polyols ethers aldehydes ketones acids acid anhydrides esters steroids lactones carbohydrates heterocyclic oxygen compounds amines amides urea derivatives guanidine derivatives amino acids peptides alkaloids heterocyclic nitrogen compounds porphyrins organic sulfur compounds and organic phosphorus compounds. When a selection was made from among several investigators commentary is provided to indicate the choice and usually some relevant data. The number of references cited is 596. An alphabetical compound index is provided which gives the name page number empirical formula and the Wiswesser Line Notation (WLN) for each compound.

Eugene S. Domalski

1972-01-01T23:59:59.000Z

197

Optimizing hydrocarbon recoveries in nitrogen rejection units  

SciTech Connect (OSTI)

In order to address conceptual questions such as process selection and natural gas liquids plant integration, an understanding of the effects of several additional factors on nitrogen rejection unit design is important. These factors, which may influence optimum hydrocarbon recovery, installed compression, etc., include current and forecast values for natural gas and utilities, project life, plant size, feed gas composition and product specifications, feed pressure, and process variations. Prices, project life, and plant size are analyzed in detail and presented in terms of methane recoveries as a function of nitrogen content in the feed for both double and single column processes. Trends are qualitatively discussed for the remaining factors. 13 references.

Chesney, J.D.; Davis, R.A.; Hilton, M.F.; Vines, H.L.

1983-01-01T23:59:59.000Z

198

Electronic Structure and Carcinogenic Activity of Aromatic Compounds: I. Condensed Aromatic Hydrocarbons  

Science Journals Connector (OSTI)

...the isolated molecule. The fundamental supposition in the localization...13).In that theory the electronic interaction between the molecule...in the sense of or ganic electronic theory, and is taken as...mm@ffNE NAGATA et al. "Electronic Structure and Carcinogenic...

Chikayoshi Nagata; Kenichi Fukui; Teijiro Yonezawa; and Yusaku Tagashira

1955-05-01T23:59:59.000Z

199

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons were quantitatively...polycyclic aromatic hydrocarbon constituent in a kerosene...polycyclic aromatic hydrocarbon fraction in terms of...formed by the incomplete combustion of organic material...and sediments (1), heat and power generation...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

200

E-Print Network 3.0 - aromatic hydrocarbon investigation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

E-Print Network 3.0 - aromatic hydrocarbons investigated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

202

E-Print Network 3.0 - aromatic hydrocarbon components Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

203

E-Print Network 3.0 - aromatic hydrocarbon molecules Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

204

E-Print Network 3.0 - aromatic hydrocarbons molecules Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

205

E-Print Network 3.0 - aromatic hydrocarbons resulting Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

206

Ozonation of Mutagenic and Carcinogenic Polyaromatic Amines and Polyaromatic Hydrocarbons in Water  

Science Journals Connector (OSTI)

...Amines and Polyaromatic Hydrocarbons in Water 1 1 Supported by a grant...amines and polyaromatic hydrocarbons in water. | The Salmonella-microsome...g., 13 halogenated hydrocarbons were identified in the drinking water of New Orleans (13...

Gary R. Burleson; Michael J. Caulfield; and Morris Pollard

1979-06-01T23:59:59.000Z

207

Determination of hydrocarbons in water interlaboratory method validation before routine monitoring  

Science Journals Connector (OSTI)

The clarification of hydrocarbon input into the Baltic sea via rivers ... of a new method for the determination of hydrocarbons by solvent extraction and gas chromatography. Surrogate oil solutions with known hydrocarbon

P. Woitke; Reinhard Krener; Peter Lepom

2001-04-01T23:59:59.000Z

208

Process for using preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect (OSTI)

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream, wherein a need exists for recovering to any selected degree and at extremely high recoveries a selected hydrocarbon component and heavier hydrocarbons. The hydrocarbons are within the group consisting of ethane, propane, butane, and pentane without the need simultaneously to recover hydrocarbons lighter than the selected hydrocarbon component from the hydrocarbon gas stream, The improvement of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent is described here. The method provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100%.

Mehra, Y.R.

1986-10-14T23:59:59.000Z

209

Exploratory and Newer Compounds  

Science Journals Connector (OSTI)

In writing a chapter on Exploratory and Newer Compounds in a book concerned with anesthesia, the authors feel that it is most important to have a clear idea of the aims of their work. The Why? must never b...

T. H. S. Burns; A. Bracken

1972-01-01T23:59:59.000Z

210

Heart testing compound  

DOE Patents [OSTI]

The compound 15-(p-[.sup.125 I]-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, Jr., Furn F. (Oak Ridge, TN); Goodman, Mark M. (Knoxville, TN)

1985-01-01T23:59:59.000Z

211

Heart testing compound  

DOE Patents [OSTI]

The compound 15-(p-(/sup 125/I)-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, F.F. Jr.; Goodman, M.M.

1983-06-29T23:59:59.000Z

212

Application of electrochemical technology for removing petroleum hydrocarbons from produced water using lead dioxide and boron-doped diamond electrodes  

Science Journals Connector (OSTI)

Abstract Although diverse methods exist for treating polluted water, the most promising and innovating technology is the electrochemical remediation process. This paper presents the anodic oxidation of real produced water (PW), generated by the petroleum exploration of the Petrobras plant-Tunisia. Experiments were conducted at different current densities (30, 50 and 100mAcm?2) using the lead dioxide supported on tantalum (Ta/PbO2) and boron-doped diamond (BDD) anodes in an electrolytic batch cell. The electrolytic process was monitored by the chemical oxygen demand (COD) and the residual total petroleum hydrocarbon [TPH] in order to know the feasibility of electrochemical treatment. The characterization and quantification of petroleum wastewater components were performed by gas chromatography mass spectrometry. The COD removal was approximately 85% and 96% using PbO2 and BDD reached after 11 and 7h, respectively. Compared with PbO2, the BDD anode showed a better performance to remove petroleum hydrocarbons compounds from produced water. It provided a higher oxidation rate and it consumed lower energy. However, the energy consumption and process time make useless anodic oxidation for the complete elimination of pollutants from PW. Cytotoxicity has shown that electrochemical oxidation using BDD could be efficiently used to reduce more than 90% of hydrocarbons compounds. All results suggest that electrochemical oxidation could be an effective approach to treat highly concentrated organic pollutants present in the industrial petrochemical wastewater and significantly reduce the cost and time of treatment.

Boutheina Gargouri; Olfa Dridi Gargouri; Bochra Gargouri; Souhel Kallel Trabelsi; Ridha Abdelhedi; Mohamed Bouaziz

2014-01-01T23:59:59.000Z

213

Hydrocarbon steam reforming using series steam superheaters  

SciTech Connect (OSTI)

In a process for steam reforming of a hydrocarbon gas feedstream wherein: the hydrocarbon gas feedstream is partially reformed at elevated temperatures in indirect heat exchange with hot combustion gases in a direct fired primary reforming furnace provided with a convection section for recovery of excess heat from said combustion gases; and the partially reformed feedstream is then further reformed in the presence of an oxygen-containing gas and steam in a secondary reformer to form a secondary reformer gaseous effluent; the improvement which comprises recovering waste heat from said secondary reformer effluent gas and from said primary reforming combustion products by heating a high pressure saturated steam in a first steam superheating zone by indirect heat exchange with at least a portion of said secondary reformer effluent gas to form a first superheated steam stream; and further heating said first superheated steam in a second steam superheating zone by indirect heat exchange with at least a portion of said primary reformer hot combustion gases for form a second superheated steam stream.

Osman, R. M.

1985-10-08T23:59:59.000Z

214

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

215

Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants  

E-Print Network [OSTI]

1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

Paris-Sud XI, Université de

216

Contemplation on the heats of combustion of isomeric hydrocarbons  

Science Journals Connector (OSTI)

Within the Hckel molecular orbital theory, the heats of combustion of isomeric hydrocarbons are related to some topological factors. The standard heats of combustion values of alternant hydrocarbons, expressed as kcal/g, seem to be related to a4 coefficient of their secular polynomials.

Lemi Trker

2004-01-01T23:59:59.000Z

217

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network [OSTI]

aromatic hydrocarbons PAHs up to 788 amu (C64H20) were detected in the combustion gases. Only the most applications including heating systems and gas turbines for electric power generation.62­64 The combustionFormation mechanism for polycyclic aromatic hydrocarbons in methane flames K. Siegmanna) Swiss

Sattler, Klaus

218

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

2013-03-01T23:59:59.000Z

219

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

220

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

High levels of carcinogenic polycyclic aromatic hydrocarbons in mate drinks  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mate drinks Farin Kamangar...exposure to polycyclic aromatic hydrocarbons (PAHs), including known...80 oC) or cold (4 oC) water and two commonly used brands...Infusions were made by adding water to the leaves, steeping for...

Farin Kamangar; Michele Schantz; Christian Abnet; Renato Fagundes; and Sanford Dawsey

2008-05-01T23:59:59.000Z

222

Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids  

E-Print Network [OSTI]

O H H Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids O O t-BuO3C Br O O Br Br Ph PhPh Ph PhPh Ph Ph COOH HOOC Total Synthesis of Convex Polyhedral Hydrocarbons The Five Matter Icosahedron Water · Polyhedron: a closed surface made up of polygonal regions. · Regular

Stoltz, Brian M.

223

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings  

Science Journals Connector (OSTI)

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings ... Relation between Bioavailability and Fuel Oil Hydrocarbon Composition in Contaminated Soils ...

Claude-Henri. ChaIneau; Jean-Louis. Morel; Jean. Oudot

1995-06-01T23:59:59.000Z

224

E-Print Network 3.0 - aromatic hydrocarbons affect Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

225

E-Print Network 3.0 - aromatic hydrocarbons annual Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: releases about 5 billion kilograms of hydrocarbons...

226

E-Print Network 3.0 - aromatic hydrocarbons implications Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

227

E-Print Network 3.0 - aromatic hydrocarbon exposure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay... of aromatic hydrocarbons in coastal waters, using solvent extraction and...

228

E-Print Network 3.0 - aromatic hydrocarbon contamination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs). PAHs are...

229

E-Print Network 3.0 - aromatic hydrocarbons extracted Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Toxic Contamination Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs)....

230

E-Print Network 3.0 - aromatic hydrocarbon metabolism Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon is introduced into the ocean via oil spillage, offshore drilling leaks, industrial... hydrocarbons have been attributed to inhibition of ... Source: National...

231

E-Print Network 3.0 - aromatic hydrocarbon-degrading bacteria...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ydrocarbonDegradation It was hypothesized... aromatic hydrocarbon degradation. Hypothesis Test Result Groundwater stimulates Fe(lll) reduction Cell... Hydrocarbon Degradation At...

232

Chlorinated C$_{1}$ and C$_{2}$ Hydrocarbons in the Marine Environment [and Discussion  

Science Journals Connector (OSTI)

...the marine environment. | Journal Article | 0 Hydrocarbons, Chlorinated | Air Pollution analysis Animals Fresh Water Great Britain Hydrocarbons, Chlorinated analysis metabolism Seawater Water Pollution, Chemical analysis The Royal Society...

1975-01-01T23:59:59.000Z

233

Bioremediation of soil contaminated with hydrocarbons and heavy metals  

SciTech Connect (OSTI)

This investigation showed that a soil contaminated with petroleum hydrocarbons and heavy metals had sufficient indigenous microbial activity for hydrocarbon biodegradation under nonlimiting conditions. Nutrient supplementation with nitrogen and phosphate, together with aeration, seemed to be the most important factors for enhancing biodegradation. Hydrocarbon biodegradation occurred to a much greater extent under aerobic than under anaerobic conditions. Biodegradation did, however, induce low pH conditions and thus caused high heavy-metal concentrations in the leachate. Anaerobic conditions inhibited hydrocarbon biodegradation with no subsequent drop in pH and low heavy-metal concentrations in the leachate. Thus, anaerobic conditions were shown to facilitate less metal mobility than low pH conditions. Air sparging did not cause a significant increase in biodegradation. Adsorption of heavy-fraction hydrocarbons (> C{sub 20}) to microorganisms and colloidal material in the leachate was suspected of facilitating mobility of these fractions and thus their subsequent detection in the leachate.

Plessis, C.A. du; Phaal, C.B.; Senior, E. [Univ. of Natal, Scottsville (South Africa)

1995-12-31T23:59:59.000Z

234

Cogeneration systems and processes for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

2009-12-29T23:59:59.000Z

235

Heating hydrocarbon containing formations in a line drive staged process  

DOE Patents [OSTI]

Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

Miller, David Scott (Katy, TX)

2009-07-21T23:59:59.000Z

236

Oxidation of carbon monoxide and hydrocarbons on platinum and palladium catalysts in the presence of sulfur dioxide  

SciTech Connect (OSTI)

The authors report on a study of the effect of sulfur dioxide on the activity of platinum and palladium catalysts with respect to oxidation of the principal toxic components in the exhaust gases of internal combustion engines: carbon monoxide and hydrocarbons (propylene (C/sub 3/H/sub 6/) and propane (C/sub 3/H/sub 8/)). The experiments were carried out in a flow system equipped with Beckman infrared analyzers to monitor the concentrations of CO and hydrocarbons and of sulfur dioxide. A series of thermal desorption experiments was carried out in a low-pressure flow system with mass spectrometric analysis of the gas phase. The results indicate that the low-temperature adsorption of sulfur dioxide on platinum (and also palladium) catalysts inhibits the oxidation of carbon monoxide and propylene. The poisoning effect of O/sub 2/ is due to blockage of the platinum centers for adsorption of the oxidizable compounds and oxygen.

Panchishnyi, V.I.; Bondareva, N.K.; Sklyarov, A.V.; Rozanov, V.V.; Chadina, G.P.

1988-11-10T23:59:59.000Z

237

Charge Density Wave Compounds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fisher Research Group Fisher Research Group Layered Chalcogenides 29 February 2008 Controlling the Wave by Brad Plummer, SLAC Communications Stanford University researchers working in part at SSRL have discovered a novel set of properties pertaining to a compound of materials called tritellurides. These compounds, composed of three atoms of tellurium and a single atom of one of the rare earth elements, demonstrate unique electronic properties that can be controlled by altering the temperature of the material. The tritellurides display phenomena known as charge density waves (CDW). In a normal conductive metal, electrons persist in a "sea" wherein they are evenly distributed and equally available, or conductive. A CDW occurs under certain circumstances and causes the electrons to clump together, lowering their availability, and thereby lowering the compound's conductivity. Tellurium, when crystallized into quasi-two-dimensional planes and combined with rare earth elements, produces a material with CDWs that can be manipulated and controlled.

238

Process for steam reforming of hydrocarbons  

SciTech Connect (OSTI)

A process is provided for the steam reforming of normally liquid hydrocarbons to produce carbon monoxide and hydrogen, which does not promote the deposition of carbonacious materials upon catalytic surfaces. The catalyst consists of nickel promoted with the oxides of iron and manganese within a specific manganese to iron ratio, said metal and metal oxides being supported upon a refractory support. The support is preferably aluminum oxide in its alpha phase having a surface area of more than 0.5 m2/gm but no more than 10 m2/gm. The metallic constituents are impregnated onto said refractory low surface area support as salts and are calcined at sufficiently high temperature to convert the salts to the oxide but at a sufficiently low temperature that they do not chemically react with the support.

Broughton, D.R.; Russ, K.J.

1980-11-11T23:59:59.000Z

239

Method and apparatus for detecting halogenated hydrocarbons  

DOE Patents [OSTI]

A halogenated hydrocarbon (HHC) detector is formed from a silent discharge (also called a dielectric barrier discharge) plasma generator. A silent discharge plasma device receives a gas sample that may contain one or more HHCs and produces free radicals and excited electrons for oxidizing the HHCs in the gas sample to produce water, carbon dioxide, and an acid including halogens in the HHCs. A detector is used to sensitively detect the presence of the acid. A conductivity cell detector combines the oxidation products with a solvent where dissociation of the acid increases the conductivity of the solvent. The conductivity cell output signal is then functionally related to the presence of HHCs in the gas sample. Other detectors include electrochemical cells, infrared spectrometers, and negative ion mobility spectrometers.

Monagle, Matthew (Los Alamos, NM); Coogan, John J. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

240

For decades, traffic safety improvements have relied primarily upon engineering and enforcement solutions. If we are limited to those options, further  

E-Print Network [OSTI]

Traffic Safety Culture For decades, traffic safety improvements have relied primarily upon about driving ­ changing our traffic safety culture. A survey by the Center for Transportation Safety on the roads than drivers nationwide, as measured in the 2010 Traffic Safety Culture Index published by the AAA

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Resistance of Bacillus subtilis Spore DNA to Lethal Ionizing Radiation Damage Relies Primarily on Spore Core Components and DNA Repair, with Minor Effects of Oxygen Radical Detoxification  

Science Journals Connector (OSTI)

...Spore DNA to Lethal Ionizing Radiation Damage Relies Primarily on...Institute of Aerospace Medicine, Radiation Biology Department, Cologne...Radiological Sciences, Chiba-shi, Japan c University of Florida, Proton...different types of ionizing radiation including X rays, protons...

Ralf Moeller; Marina Raguse; Gnther Reitz; Ryuichi Okayasu; Zuofeng Li; Stuart Klein; Peter Setlow; Wayne L. Nicholson

2013-10-11T23:59:59.000Z

242

Asterix is a reflectometer/diffractometer/grazing-incidence-SANS/SESAME-enabled-SANS spectrometer that is primarily used for experiments or neutron scattering  

E-Print Network [OSTI]

that is primarily used for experiments or neutron scattering techniques requiring polarized neutron beams detector arm is readily configurable for polarization or energy analysis of the scattered neutron beam be translated in the horizontal and vertical directions. Neutron detector (Spin Echo Scattering Angle

243

Biocharis a relatively new concept that has been promoted primarily as a form of carbon storage but also for its poten-  

E-Print Network [OSTI]

allows long-term (multi-centennial) soil carbon storage, with potential benefits for agriculturalBiocharis a relatively new concept that has been promoted primarily as a form of carbon storage to the waste-processing industry in allowing the recovery of waste as a potentially useful by-product [10

244

UCLA PHYSICAL CHEMISTRY CONCENTRATION 2012-2013 CHEMISTRY MAJOR (B.S.), PHYSICAL CHEMISTRY CONCENTRATION: This concentration is designed primarily for  

E-Print Network [OSTI]

UCLA PHYSICAL CHEMISTRY CONCENTRATION 2012-2013 CHEMISTRY MAJOR (B.S.), PHYSICAL CHEMISTRY CONCENTRATION: This concentration is designed primarily for Chemistry majors who are interested in attending graduate school in Physical Chemistry/Physics or related areas. It may also satisfy some of the needs

Levine, Alex J.

245

UCLA CHEMISTRY MAJOR 2012-2013 CHEMISTRY MAJOR (B.S.): This major is designed primarily for students who are interested in attending  

E-Print Network [OSTI]

UCLA CHEMISTRY MAJOR 2012-2013 CHEMISTRY MAJOR (B.S.): This major is designed primarily for students who are interested in attending graduate school in Chemistry or related areas. It also satisfies this major and others offered in the Department of Chemistry and Biochemistry, consult the Undergraduate

Levine, Alex J.

246

Microoptical compound lens  

DOE Patents [OSTI]

An apposition microoptical compound lens comprises a plurality of lenslets arrayed around a segment of a hollow, three-dimensional optical shell. The lenslets collect light from an object and focus the light rays onto the concentric, curved front surface of a coherent fiber bundle. The fiber bundle transports the light rays to a planar detector, forming a plurality of sub-images that can be reconstructed as a full image. The microoptical compound lens can have a small size (millimeters), wide field of view (up to 180.degree.), and adequate resolution for object recognition and tracking.

Sweatt, William C. (Albuquerque, NM); Gill, David D. (Albuquerque, NM)

2007-10-23T23:59:59.000Z

247

Hydrocarbon concentrations at the Alpine mountain sites Jungfraujoch and Arosa  

Science Journals Connector (OSTI)

Volatile hydrocarbons have been measured for 1yr at Arosa (2010m asl) to determine the contribution of European emissions to the trace gas concentrations at this remote site. Results are compared to concurrent hydrocarbon concentrations at the high Alpine background site Jungfraujoch (3580m asl). Hydrocarbon concentrations at Arosa are generally much higher than at Jungfraujoch. The influence of the Alpine boundary layer air was studied based on the diurnal variation of hydrocarbon concentrations, i.e. rising pollutant concentrations in the morning at Arosa and in the afternoon at Jungfraujoch. Different hydrocarbon emission sources of the uplifting air were found at the two sites. At Jungfraujoch, several transatlantic events were detected from October 2001 to January 2002 based on analysis of hydrocarbon ratios and air parcel trajectories. The OH concentration during the transatlantic transport was estimated to be around 5105cm?3, derived from simultaneous hydrocarbon oxidation and dilution in the free troposphere. These transatlantic transport events were tracked back to warm conveyor belts, characterized by uniform dynamics and relatively uniform surface sources. In addition, ozone production in the free tropospheric transport was also documented in these events.

Yingshi Li; Mike Campana; Stefan Reimann; Daniel Schaub; Konrad Stemmler; Johannes Staehelin; Thomas Peter

2005-01-01T23:59:59.000Z

248

Unsaturated macrocyclic carbonyl bridge compounds  

Science Journals Connector (OSTI)

Unsaturated macrocyclic carbonyl bridge compounds ... Catalytic Ring-Closing Metathesis of Doubly Armed, Bridged Bicyclic Sulfones. ...

C. F. H. Allen; J. A. VanAllan

1953-07-01T23:59:59.000Z

249

Compound floating pivot micromechanisms  

DOE Patents [OSTI]

A new class of tilting micromechanical mechanisms have been developed. These new mechanisms use compound floating pivot structures to attain far greater tilt angles than are practical using other micromechanical techniques. The new mechanisms are also capable of bi-directional tilt about multiple axes.

Garcia, Ernest J. (Albuquerque, NM)

2001-04-24T23:59:59.000Z

250

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Broader source: Energy.gov (indexed) [DOE]

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

251

Iraq`s significant hydrocarbon potential remains relatively undeveloped  

SciTech Connect (OSTI)

Iraq is probably one of the least explored countries in the Middle East, despite the fact that it possesses one of the richest hydrocarbon basins in the world almost on a par to Saudi Arabia`s potential, if not more. The aim of this article is to state the facts about Iraq and focus on the huge but untapped and undeveloped hydrocarbon resources to the international oil community. Perhaps it is best to start by describing briefly the sedimentary and tectonic elements responsible for accumulating such large hydrocarbon resources. The paper describes the basin, tectonic elements, structural anomalies, deep drilling, source rocks, reservoir rocks, characteristics, and new reserves.

AL-Gailani, M. [GeoDesign Ltd., Kingston-upon-Thames (United Kingdom)

1996-07-29T23:59:59.000Z

252

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents [OSTI]

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

1999-07-27T23:59:59.000Z

253

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents [OSTI]

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

1999-01-01T23:59:59.000Z

254

Identification and evaluation of volatile compounds associated with vacuum and modified atmosphere packaged fresh red meats  

E-Print Network [OSTI]

with Lacrobacillus planrarum or Leuconostoc mesenteroides and stored for 28 days at 3'C included acetone, toluene, acetic acid, ethyl acetate, a hydrocarbon and CHCls. The profile of volatiles in packaged sterile loin tissue stored for 28 days was very similar.... , 1979, 1983; Vanderzant et al. , 1986). ~Although many studies have reported these off-odors, very little published information exists relative to the nature of the volatile aroma compounds which result from microbial or enzymatic activity during...

Jackson, Timothy Court

1989-01-01T23:59:59.000Z

255

E-Print Network 3.0 - aromatic hydrocarbon emission Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emission Search Powered by Explorit Topic List Advanced Search Sample search results for: aromatic hydrocarbon emission...

256

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network [OSTI]

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

257

Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO/Al2O3 and ZSM-5 Composite Catalyst System  

SciTech Connect (OSTI)

A composite Pd/ZnO/Al2O3-HZSM-5 (Si/Al=40) catalytic system was evaluated for the synthesis of gasoline-range hydrocarbons directly from synthesis gas. Bifunctional catalyst comprising PdZn metal and acid sites present the required catalytically active sites necessary for the methanol synthesis, methanol dehydration, and methanol-to-gasoline reactions. This system provides a unique catalytic pathway for the production of liquid hydrocarbons directly from syngas. However, selectivity control is difficult and poses many challenges. The composite catalytic system was evaluated under various process conditions. Investigated were the effects of temperature (310-375oC), pressure (300-1000 psig), time-on-stream (50 hrs), and gas-hour space velocity (740-2970 hr-1), using a H2/CO molar syngas ratio of 2.0. By operating at the lower end of the temperature range investigated, liquid hydrocarbon formation was favored, as was decreased amounts of undesirable light hydrocarbons. However, lower operating temperatures also facilitated undesirable CO2 formation via the water-gas shift reaction. Higher operating pressures slightly favored liquid synthesis. Operating at relatively low pressures (e.g. 300 psig) was made possible, whereas for methanol synthesis alone higher pressure are usually required to achieve similar conversion levels (e.g. 1000 psig). Thermodynamic constraints on methanol synthesis are eased by pushing the equilibrium through hydrocarbon formation. Catalytic performance was also evaluated by altering Pd and Zn composition of the Pd/ZnO/Al2O3 catalyst. Of the catalysts and conditions tested, selectivity toward liquid hydrocarbon was highest when using a 5% Pd metal loading and Pd/Zn molar ratio of 0.25 and mixed with HZMS-5, operating at 310oC and 300 psig, CO conversion was 43 % and selectivity (carbon weight basis) to hydrocarbons was 49 wt. %. Of the hydrocarbon fraction, 44wt. % was in the C5-C12 liquid product range and consisted primarily of aromatic polymethylbenzenes. However, as syngas conversion increases with increasing temperature, selectivity to liquid product diminished. This is attributed, in large part, to increased saturation of the olefinic intermediates over PdZn metal sites. Under all the conditions and catalysts evaluated in this study, generating liquid product in high yield was challenging (<10 wt. % C5+ yield).

Dagle, Robert A.; Lizarazo Adarme, Jair A.; Lebarbier, Vanessa MC; Gray, Michel J.; White, James F.; King, David L.; Palo, Daniel R.

2014-07-01T23:59:59.000Z

258

Sources of local variation in polynuclear aromatic hydrocarbon and pesticide body burden in oysters (Crassostrea virginica) from Galveston Bay, Texas  

Science Journals Connector (OSTI)

1. Eggs and sperm contain significantly more PAH (polynuclear aromatic hydrocarbon) than somatic tissues in oysters (Crassostrea virginica) taken from Galveston Bay. 2. The quantity of gonadal material was the most important correlate of PAH body burden. 3. Eggs, but not sperm, were enriched in chlorinated compounds (e.g. DDD, chlordane), while both eggs and sperm were enriched in total \\{PCBs\\} relative to somatic tissue. 4. Oysters may lose up to 50% of their total body burden of certain \\{PAHs\\} and pesticides in a single spawn.

Matthew S. Ellis; Kwang-Sik Choi; Terry L. Wade; Eric N. Powell; Thomas J. Jackson; Donald H. Lewis

1993-01-01T23:59:59.000Z

259

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide  

Broader source: Energy.gov (indexed) [DOE]

storage of natural gas, liquid hydrocarbons, and carbon storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) < Back Eligibility Commercial Construction Industrial Investor-Owned Utility Municipal/Public Utility Utility Program Info State Louisiana Program Type Environmental Regulations Siting and Permitting The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the storage of natural gas and prior to the exercise of eminent domain by any person, firm, or corporation having such right under laws of the state of Louisiana, the commissioner, shall have found all of the following:

260

Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis  

SciTech Connect (OSTI)

Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

Ekechukwu, A.A.

2002-05-10T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN'  

E-Print Network [OSTI]

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN' OSpemnenr Of C%sITIkby. M k I. A biographyand photograph of Kenneth D. Jordan appear In previous paper in this issue. far outweighsthat

Simons, Jack

262

Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures  

E-Print Network [OSTI]

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

Desai, Anuradha M.

2007-04-25T23:59:59.000Z

263

Experiments on Hydrocarbon Gas Hydrates in Unconsolidated Sand  

Science Journals Connector (OSTI)

Experiments were carried out to observe the formation and decomposition of hydrocarbon gas hydrates in an unconsolidated sand pack 4.4 cm in diameter and ... 43 bars and 5 to 10C; gas used was 90% methane and 10...

P. E. Baker

1974-01-01T23:59:59.000Z

264

Filtration Combustion in Hydrocarbon Desorption from a Porous Medium  

Science Journals Connector (OSTI)

We have investigated theoretically and experimentally the process of filtration combustion with hydrocarbon desorption from a porous skeleton realized, in particular, in heat cleaning of porous media out of resid...

S. I. Fut'ko; K. V. Dobrego; E. S. Shmelev

2003-11-01T23:59:59.000Z

265

Fireball during combustion of hydrocarbon fueld releases II. Thermal radiation  

Science Journals Connector (OSTI)

The processes of radiative heat transfer in a fireball which develops upon ignition of a cloud of hydrocarbon fuel near the Earths surface are simulated numerically. The emissive characteristics of combustion pr...

G. M. Makhviladze; J. P. Roberts; S. E. Yakush

266

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network [OSTI]

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

267

Effect of the Composition of Hydrocarbon Streams on HCCI Performance  

Broader source: Energy.gov (indexed) [DOE]

of hydrocarbon samples and can be treated as compositional variables which could describe bulk properties of the samples Sample fingerprint STEP 1: Data receiving Q(2d)RPR How...

268

Hydrocarbon pollution control and remediation of groundwater: a brief review  

Science Journals Connector (OSTI)

...oil-contaminated sediments. There are two main remediation techniques: soil washing and bio- remediation. With soil washing, contaminated soil is leached with water containing a surfactant to assist in hydrocarbon removal. In situ washing is undertaken...

L. Clark

269

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE.  

Science Journals Connector (OSTI)

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE. ... Citation data is made available by participants in CrossRef's Cited-by Linking service. ... Experimental methods included adiabatic heat-capacity calorimetry (5 K to 420 K), comparative ... ...

Theodore W. Richards; Frederick Barry

1915-01-01T23:59:59.000Z

270

Measurements of dissolved nonmethane hydrocarbons in sea water  

Science Journals Connector (OSTI)

An automated stripping technique for the measurement of dissolved hydrocarbons in sea water is presented together with some results obtained ... cruise from Europe to Brazil. The sea water concentrations of NMHC ...

C. Plass; R. Koppmann; J. Rudolph

271

Hygienic rating of hydrocarbons in bottom deposits of water ecosystems  

Science Journals Connector (OSTI)

The authors of this article draw the readers attention to the topical problem of the contamination of bottom deposits of water ecosystems by hydrocarbons, such as oil and gas condensate,...

Rauf Valievich Galiulin

2014-05-01T23:59:59.000Z

272

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents [OSTI]

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

273

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network [OSTI]

CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 2000 Major Subject: Chemical Engineering CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Alkhawaldeh, Ammar

2012-06-07T23:59:59.000Z

274

Response to Comment on Experimental observation of carbon dioxide reduction in exhaust gas from hydrocarbon fuel burning [Phys. Plasmas17, 014701 (2010)  

Science Journals Connector (OSTI)

A high-voltage cathode initiates an electron emission resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.

Han S. Uhm; Chul H. Kim

2010-01-01T23:59:59.000Z

275

Method for the production of hydrocarbons using iron-carbon-based catalysts  

SciTech Connect (OSTI)

This patent describes a process for producing C/sub 2/+ aliphatic hydrocarbons from a CO and H/sub 2/ mixture comprising the step of contacting the mixture with a catalyst comprising finely divided nonpyrophoric iron-carbon catalyst particles comprising iron and carbon, in the substantial absence of silicon, a substantial portion of which is dementite, which was produced in a reaction zone in the presence of laser radiation under such conditions of laser flux density, power adsorption, concentration of iron compound reactants selected from the group consisting of iron carbonyls, iron acetylacetonate, and ferrocene, and pressure sufficient to produce non-pyrophoric iron-carbon particles having average diameters between 1 and 100 nm.

Rice, G.W.; Fiato, R.A.; Soled, S.L.

1988-11-29T23:59:59.000Z

276

Low severity hydrocarbon steam reforming process  

SciTech Connect (OSTI)

A process is described for producing ammonia which comprises: (a) primary catalytically reforming at super atmospheric pressure in a direct-fired primary reforming zone, a hydrocarbon feedstock with steam to produce a gas containing carbon oxides, hydrogen and methane; (b) secondary catalytically reforming the gas from step (a) by introducing air and bringing the mixture towards equilibrium thereby producing a secondary reformer effluent gas containing nitrogen, carbon oxides, hydrogen and a decreased quantity of methane; (c) converting carbon monoxide catalytically with steam to carbon dioxide and hydrogen; (d) removing carbon oxides to give an ammonia synthesis gas comprising nitrogen and hydrogen and compressing the gas to ammonia synthesis pressure; (e) reacting the synthesis gas in an ammonia synthesis zone to produce ammonia and recovering ammonia from the reacted gas to produce an ammonia-depleted gas stream; (f) recycling at least a portion of the ammonia-depleted gas stream to the ammonia synthesis zone; and (g) treating a sidestream of the ammonia-depleted gas to separate a stream enriched in hydrogen and an inerts-enriched gas stream, and returning the enriched hydrogen stream to the ammonia synthesis zone.

Osman, R.M.; Byington, R.G.

1986-06-03T23:59:59.000Z

277

Emission of polycyclic aromatic hydrocarbons in China  

SciTech Connect (OSTI)

Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-02-01T23:59:59.000Z

278

Rock types, pore types, and hydrocarbon exploration  

SciTech Connect (OSTI)

A proposed exploration-oriented method of classifying porosity in sedimentary rocks is based on microscopic examination cores or cuttings. Factors include geometry, size, abundance, and connectivity of the pores. The porosity classification is predictive of key petrophysical characteristics: porosity-permeability relationships, capillary pressures, and (less certainly) relative permeabilities. For instance, intercrystalline macroporosity typically is associated with high permeability for a given porosity, low capillarity, and favorable relative permeabilities. This is found to be true whether this porosity type occurs in a sucrosic dolomite or in a sandstone with pervasive quartz overgrowths. This predictive method was applied in three Rocky Mountain oil plays. Subtle pore throat traps could be recognized in the J sandstone (Cretaceous) in the Denver basin of Colorado by means of porosity permeability plotting. Variations in hydrocarbon productivity from a Teapot Formation (Cretaceous) field in the Powder River basin of Wyoming were related to porosity types and microfacies; the relationships were applied to exploration. Rock and porosity typing in the Red River Formation (Ordovician) reconciled apparent inconsistencies between drill-stem test, log, and mud-log data from a Williston basin wildcat. The well was reevaluated and completed successfully, resulting in a new field discovery. In each of these three examples, petrophysics was fundamental for proper evaluation of wildcat wells and exploration plays.

Coalson, E.B.; Hartmann, D.J.; Thomas, J.B.

1985-05-01T23:59:59.000Z

279

FIELD SCREENING FOR HALOGENATED VOLATILE ORGANIC COMPOUNDS  

SciTech Connect (OSTI)

Western Research Institute (WRI) initiated exploratory work towards the development of new field screening methodology and a test kit to measure halogenated volatile organic compounds (VOCs) in the field. Heated diode and corona discharge sensors are commonly used to detect leaks of refrigerants from air conditioners, freezers, and refrigerators. They are both selective to the presence of carbon-halogen bonds. Commercially available heated diode and corona discharge leak detectors were procured and evaluated for halogenated VOC response. The units were modified to provide a digital readout of signal related to VOC concentration. Sensor response was evaluated with carbon tetrachloride and tetrachloroethylene (perchloroethylene, PCE), which represent halogenated VOCs with and without double bonds. The response characteristics were determined for the VOCs directly in headspace in Tedlar bag containers. Quantitation limits in air were estimated. Potential interferences from volatile hydrocarbons, such as toluene and heptane, were evaluated. The effect of humidity was studied also. The performance of the new devices was evaluated in the laboratory by spiking soil samples and monitoring headspace for halogenated VOCs. A draft concept of the steps for a new analytical method was outlined. The results of the first year effort show that both devices show potential utility for future analytical method development work towards the goal of developing a portable test kit for screening halogenated VOCs in the field.

John F. Schabron; Joseph F. Rovani Jr.; Theresa M. Bomstad

2002-06-01T23:59:59.000Z

280

A preliminary evaluation model for reservoir hydrocarbon-generating potential established based on dissolved hydrocarbons in oilfield water  

Science Journals Connector (OSTI)

A large number of oilfield water samples were analyzed in this work. Research ... relationship between the concentrations and distribution of dissolved hydrocarbons suggested that the contents and composition of ...

Hongjing Zhao; Weilin Sun; Baotian He; Bowen Mei

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Formation of hydrocarbons from acid-Clay suspensions by gamma irradiation  

SciTech Connect (OSTI)

The adsorption of certain organic compounds by clays gives rise to the transformation of the adsorbate through the action of the clays. This phenomenon can be enhanced using ionizing radiation. In this context, these kinds of reactions play an important role in many natural and industrial processes. For example, in oil and gas exploration, the source and trap of petroleum hydrocarbons is frequently clay-rich rocks. Clay-water-based muds are also seen as environmentally friendly alternatives to toxic oil-based fluids. The principal processes that occur in sediments are usually held to be of bacterial action and thermal transformation, which may include thermally induced catalytic alteration of the organic debris. On the other hand, radioactive materials are widely distributed throughout Earth. They were more abundant in the past, but are present in petroleum reservoirs. Their presence induced radioactive bombardment, which may have altered these sediments. This important subject has not been extensively studied. The aim of this work is to study the behavior of fatty acids-like behenic acid-and dicarboxylic acids-like fumaric acid-as model compounds, which are adsorbed in a clay mineral (Na-montmorillonite) and exposed to gamma radiation. The results show that the radiation-induced decomposition of the clay-acid system goes along a definitive path (oxidation), rather than following several modes of simultaneous decomposition, as happens in radiolysis without clay or by heating the system. The main radiolytic products for fatty acids are their corresponding hydrocarbons, with one C-atom less than the original acid.

Cruz-Castaneda, J.; Negron-Mendoza, A.; Ramos-Bernal, S. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, UNAM. Cd. Universitaria, A. P. 70-543, 04510 Mexico (Mexico)

2013-07-03T23:59:59.000Z

282

CHARACTERISTICS Nitrated compounds constitute a  

E-Print Network [OSTI]

compounds. If there is a chance of an explosive reaction, conduct the operation behind a blast shield

Wilcock, William

283

Naming chemical compounds: Calculator drill  

Science Journals Connector (OSTI)

36. Bits and pieces, 13. A calculator can be programmed to drill students on chemical compound naming rules.

David Holdsworth; Evelyn Lacanienta

1983-01-01T23:59:59.000Z

284

Boronated porphyrin compounds  

DOE Patents [OSTI]

A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

Kahl, S.B.; Koo, M.S.

1992-09-22T23:59:59.000Z

285

Boronated porphyrin compounds  

DOE Patents [OSTI]

A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

Kahl, Stephen B. (Portola Valley, CA); Koo, Myoung-Seo (San Francisco, CA)

1992-01-01T23:59:59.000Z

286

Kidney cancer and hydrocarbon exposures among petroleum refinery workers  

SciTech Connect (OSTI)

To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

Poole, C.; Dreyer, N.A.; Satterfield, M.H. [Epidemiology Resources Inc., Newton Lower Falls, MA (United States); Levin, L. [Drexel Univ., Philadelphia, PA (United States)

1993-12-01T23:59:59.000Z

287

A model for correlating properties with molecular structure and its application to fuel/hydrocarbon processing  

SciTech Connect (OSTI)

Structural indices such as n (carbon number), z (hydrogen deficiency C{sub n}H{sub 2n+z}) and i (isomeric deviation from the normal compound) are defined to characterize the molecular structure in an unambiguous manner. The parameters are defined in a manner that results in complete orthogonality, one with any of the others. Classification of hydrocarbon compounds into z series yields a systematic change of property with molecular weight in a mathematically definable fashion. For pure compounds, molecular weight as a function of n and z is correlated with properties using regression techniques. Boiling point, density, freezing point, gravimetric and volumetric heat of combustion, heat of vaporization, heat capacity and viscosity were correlated for the z series of paraffins (2), cycloparaffins (0), alkyldecalins(-2), alkylbenzenes(-6), alkyltetralins(-8), and alkylnaphthalenes(-12). The equation form: P{sub z} = (a{sub z}m + b{sub z})/(m + c{sub z}) was found to fit well for all n and z values correlated. Isomeric structural effects may be expressed through an i parameter that quantifies the effects of methyl substituents, adjacency of bonds and symmetry of the molecule. Properties such as boiling point can be related to this parameter. Equations have been derived for properties of mixtures from pure compound data. A computer program for optimizing the composition of various components of fuel has been developed. Consideration has been given to the historic problem of accurate molecular weight measurements of mixtures. A procedure for calculating true molecular weights based on quantification of the thermodynamics of the associated state has been devised. Results suggest that conventional methods based on VPO may be highly erroneous.

Devineni, A.V.P.

1989-01-01T23:59:59.000Z

288

Preliminary assessment of hydrocarbon potential in southern Illinois  

SciTech Connect (OSTI)

Hydrocarbon exploration has been sparse south of the Cottage Grove fault system in southern Illinois. Over 240,000 ac in this area are within the Shawnee National Forest (SNF). Upcoming review of mineral exploration policy on SNF land and a recent amendment to the Mineral Leasing Act (1987) will result in release of portions of the SNF for competitive and potentially noncompetitive bidding for mineral exploration tracts in the near future. Preliminary assessment of hydrocarbon potential has been carried out in southern Illinois. Numerous oil shows occur in Paleozoic strata south of the Cottage Grove fault system, which, at present, describes the southern boundary of most oil production in Illinois. Only Mitchellsville oil field in southern Saline County lies south of the Cottage Grove fault system. The Upper Devonian New Albany Shale, though to be the primary source rock for Illinois basin hydrocarbons, underlies most of the area. Older potential source rocks may be present. Depositional trends of prolific oil-productive Mississippian strata in Illinois continue southward through the area. Few drill holes have tested strata older than Mississippian in the area. Complex faulting in the Rough Creek-Shawneetown fault system may have improved the potential for hydrocarbon emplacement and entrapment in this region. Preliminary assessment of hydrocarbon potential indicates that this wildcat region deserves further tests.

Crockett, J.E.; Oltz, D.F. (Illinois State Geological Survey, Champaign (USA))

1989-08-01T23:59:59.000Z

289

Methane-derived hydrocarbons produced under upper-mantle conditions  

SciTech Connect (OSTI)

There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.; (CIW); (RITS)

2009-08-13T23:59:59.000Z

290

Hepatic coenzyme Q redox balance of fishes as a potential bioindicator of environmental contamination by polycyclic aromatic hydrocarbons  

Science Journals Connector (OSTI)

...at the land-water interface are...polycyclic aromatic hydrocarbon (PAH) contamination...Markers 0 Polycyclic Hydrocarbons, Aromatic 0 Water Pollutants, Chemical...metabolism Polycyclic Hydrocarbons, Aromatic toxicity...Ubiquinone metabolism Water Pollutants, Chemical...

2011-01-01T23:59:59.000Z

291

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents [OSTI]

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

Shelnutt, John A. (Tijeras, NM)

1990-01-01T23:59:59.000Z

292

Method and apparatus for producing oxygenates from hydrocarbons  

DOE Patents [OSTI]

A chemical reactor for oxygenating hydrocarbons includes: (a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; (b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; (c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and (d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed. 4 figs.

Kong, P.C.; Lessing, P.A.

1995-06-27T23:59:59.000Z

293

Chlorinated hydrocarbons in early life stages of the common snapping turtle (Chelydra serpentina serpentina) from a coastal wetland on Lake Ontario, Canada  

SciTech Connect (OSTI)

To assess intra-clutch variation in contaminant concentrations in eggs, and to investigate the dynamics of chlorinated hydrocarbon accumulation in embryos of the common snapping turtle (Chelydra serpentina), concentrations of p,p{prime}-DDE, hexachlorobenzene, trans-nonachlor, cis-chlordane, and six PCB congeners were measured in eggs, embryos, and hatchlings. Samples were collected from Cootes Paradise, a wetland at the western end of Lake Ontario, Ontario, Canada. The intra-clutch variation in chlorinated hydrocarbon concentrations within four snapping turtle clutches was determined by analyzing the first, last, and middle five eggs oviposited in the nest. The first five eggs had the highest mean concentrations of all chlorinated hydrocarbons, wet weight, and egg diameter. On a lipid weight basis, the first five eggs contained the highest concentration of all compounds except total PCBs and cis-chlordane. The concentration of cis-chlordane was the only parameter measured that was significantly different among the three sets of eggs. At hatching, snapping turtles without yolk sacs contained from 55.2 to 90.5% of the absolute amount of organochlorine compounds measured in the egg at oviposition. Eighteen days after hatching, the body burden of PCBs and pesticides decreased to 45.3 to 62.2% of that in the fresh egg. The accumulation of organochlorine chemicals in embryonic turtles peaked at or just before hatching and then declined thereafter, which is consistent with trends reported in developing sea turtles, fish, and birds.

Bishop, C.A.; Lean, D.R.S.; Carey, J.H. [Environment Canada, Burlington, Ontario (Canada); Brooks, R.J. [Univ. of Guelph, Ontario (Canada); Ng, P. [York Univ., North York, Ontario (Canada)

1995-03-01T23:59:59.000Z

294

Hydrocarbon composition of crude oil from Lam Bank  

SciTech Connect (OSTI)

The authors discuss the crude oil from a new offshore field called the Lam Bank in the Caspian Sea. A segregated commercial crude was distilled and the distillation data is shown. In order to determine the content of n-paraffins, the naphthenic-paraffinic part of the narrow cuts was subjected to adsorptive separation on CaA zeolite. Owing to the high contents of naphthenic and isoparaffinic hydrocarbons and the low content of aromatic hydrocarbons in the distillate part, this crude can be used to produce high-quality fuels and oils by the use of the dewaxing processes.

Samedova, F.I.; Agaeva, R.M.; Alieva, F.Z.; Valiev, M.A.

1987-07-01T23:59:59.000Z

295

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

Blandford, J.W.

1995-01-17T23:59:59.000Z

296

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1995-01-01T23:59:59.000Z

297

Method for determining processability of a hydrocarbon containing feedstock  

SciTech Connect (OSTI)

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

Schabron, John F.; Rovani, Jr., Joseph F.

2013-09-10T23:59:59.000Z

298

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents [OSTI]

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

299

Isoconversional Kinetic Analysis of the Combustion of Heavy Hydrocarbons  

Science Journals Connector (OSTI)

One method to access unconventional, heavy-oil resources as well as waterflood residual oil is to apply in situ combustion (ISC) to oxidize in place a small fraction of the hydrocarbon, thereby providing heat to reduce oil viscosity and pressure that enhances recovery. ... As shown by Vyazovkin,(12) these deviations of temperature yield erroneous values of activation energy, when such a data set is used with a model that assumes linear heating. ... Estimates were made of the heat produced, and a formula was derived for computing the heat of combustion of hydrocarbons in the high-temp. ...

Murat Cinar; Louis M. Castanier; Anthony R. Kovscek

2009-07-06T23:59:59.000Z

300

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon flamesq  

E-Print Network [OSTI]

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon after the methane flames, respectively. Three-layer, feed- forward type artificial neural networks rights reserved. Keywords: Soot; Hydrocarbon flames; Artificial neural networks 1. Introduction

Senkan, Selim M.

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

20 May 1975 research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion] E...have been made of their fate in mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...

1975-01-01T23:59:59.000Z

302

Bioenergy Technologies Office Conversion R&D Pathway: Syngas Upgrading to Hydrocarbon Fuels  

Broader source: Energy.gov [DOE]

Syngas upgrading to hydrocarbon fuels is one of eight priority pathways chosen to convert biomass into hydrocarbon fuels by the Bioenergy Technologies Office. These pathways were down-selected from an initial list of 18.

303

Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina*  

E-Print Network [OSTI]

1/28 Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina* , P of the heat transfer dynamics. Finally, the combustion mechanism is applied and validated experimentally for kerosene pyrolysis application. Keywords Regenerative cooling; Hydrocarbon pyrolysis; Supersonic Combustion

Boyer, Edmond

304

The Energies of the Atomic Linkages in the Normal Paraffin Hydrocarbons  

Science Journals Connector (OSTI)

...normal paraffin hydrocarbons, in the gaseous...values for the heats of combustion of these gases...values for the heats of combustion of the hydrocarbon gases,4'5...Jessup4 on the heats of combustion of normal heptane...

Frederick D. Rossini

1934-01-01T23:59:59.000Z

305

E-Print Network 3.0 - aromatic hydrocarbons molecular Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... ,b, Seong Gyu Seo,c and Sang-Chai Kim d a Department of Molecular Science and...

306

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

307

Vibration Spectra of Hydrocarbon Molecules. II. Skeletal Frequencies in Certain Branched Paraffins  

Science Journals Connector (OSTI)

25 October 1949 research-article Vibration Spectra of Hydrocarbon Molecules. II...characteristic frequencies should be assigned as vibrations of the carbon skeleton of these structural...problem of the interpretation of the vibration spectra of hydrocarbons is considered...

1949-01-01T23:59:59.000Z

308

Environmental and Transport Effects on Core Measurements of Water Saturation, Salinity, Wettability, and Hydrocarbon Composition  

E-Print Network [OSTI]

and core surfacing operations can significantly alter the water saturation, salinity, hydrocarbon measurements of water saturation, salinity, hydrocarbon composition, and wettability are critical for accurateSPE 166154 Environmental and Transport Effects on Core Measurements of Water Saturation, Salinity

Torres-Verdín, Carlos

309

Light hydrocarbons in the surface water of the mid-Atlantic  

Science Journals Connector (OSTI)

During a cruise of RV Polarstern over the Atlantic in September/October 1988, C2?C4 hydrocarbons were measured in surface sea water. The ship passed through three different ocean ... at 8 N and 3 S. Hydrocarbon

C. Plass; R. Koppmann; J. Rudolph

1992-11-01T23:59:59.000Z

310

Chemoprevention by Fruit Phenolic Compounds  

Science Journals Connector (OSTI)

This chapter summarizes available information on the chemopreventive effects of fruit phenolic compounds in various experimental systems. Emphasis is placed on the anticarcinogenic activity of these phenolics ...

Gary D. Stoner PhD; Bruce C. Casto ScD

2004-01-01T23:59:59.000Z

311

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS  

E-Print Network [OSTI]

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS ROBERT C. CLARK, JR., AND JOHN S. FINLEY' ABSTRACT Petroleum paraffin hydrocarbons (n-CI4H30 to n-C37H76 system that simulated tides. The mussels were exposed to levels of petroleum hydrocarbons from a surface

312

A 4D Synchrotron X-Ray-Tomography Study of the Formation of Hydrocarbon-  

E-Print Network [OSTI]

hydrocarbons and the growing production of hydrocarbons from low-permeability tight rocks. Quantitative models, University of Oslo, Idaho National Laboratory, and Institute for Energy Technology Summary Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes

Mazzini, Adriano

313

The Interaction of Carcinogenic Hydrocarbons with Tissues VII. Fractionation of Mouse Skin Proteins  

Science Journals Connector (OSTI)

...Inferaction of Hydrocarbons with Tissues. VII...separation of the water- soluble proteins...in Chart 1, and water-soluble proteins...Interaction of Hydrocarbons with Tissues. VII...noncarcinogenic hydrocarbons could be detected...electrophoretic separation of water-soluble proteins...

G. Rodman Davenport; C. W. Abell; and Charles Heidelberger

1961-06-01T23:59:59.000Z

314

Male-derived cuticular hydrocarbons signal sperm competition intensity and affect ejaculate expenditure in crickets  

Science Journals Connector (OSTI)

...taxa has shown that cuticular hydrocarbons (CHCs), contact pheromones...They were supplied with water and fed cat food ad libitum...between-family variation in male hydrocarbon profiles (Thomas Simmons...variation within the blends of hydrocarbons in this experiment, male...

2009-01-01T23:59:59.000Z

315

Review of storage stability characteristics of hydrocarbon fuels, 1952-1982  

SciTech Connect (OSTI)

This discussion and data compilation relating to the storage stability of hydrocarbon liquids is divided into four principal sections: 1) background narrative, 2) references, 3) summary table, and 4) data tables. The Background narrative section provides a general discussion of various types of storage stability tests arranged by type of sample involved. This generic review will provide an introduction for those new in the field or cited in this section to aid in further investigation. The second section is the References, consisting of an alphabetical listing of the literature cited along with an abstract for each entry. This section should provide additional details for anyone needing to use the data provided in the tables. Since many of the publications are difficult, if not impossible, to obtain today, these abstracts may have to suffice in place of the actual report. The third section, or Summary Table, serves as a multientry index for the approximately 230 tables of raw data to follow. Information has been grouped according to the type of material involved, such as gasoline, diesel, jet fuel, coal liquid, etc. In addition, any compounds added are described along with the conditions under which the test was run. This should provide easy identification of data tables relevant to a particular investigation. References to original publications are provided so that more detail can be pursued. The final section is made up entirely of Data Tables. These tables have all been retypeset for easier reading and rapid scanning. Formats have been changed from those in the original articles where it seemed it would help in understanding the data without access to the entire publication. This compilation is as complete as practical, and represents a broad spectrum of stability data. In combination, these four sections should provide a ready reference source of data for those involved in the study of the storage stability of hydrocarbon liquids. 143 references, 231 tables.

Goetzinger, J.W.; Thompson, C.J.; Brinkman, D.W.

1983-10-01T23:59:59.000Z

316

Speciation and Quantitation of Hydrocarbons in Gasoline Engine Exhaust  

Science Journals Connector (OSTI)

......laboratory engines or reactors. In this paper we...computer technology have advanced to the state where...2-1 m), and the heavy (C5 -C1 2 ) hydrocarbons...PLOT column with water or heavy hy drocarbons...technology to prevent water vapor from condensing...computer technology have advanced to the state where......

Keith L. Olson; Robert M. Sinkevitch; Thompson M. Sloane

1992-12-01T23:59:59.000Z

317

Hydrocarbon Condensation in Heavy-Duty Diesel Exhaust  

Science Journals Connector (OSTI)

Hydrocarbon Condensation in Heavy-Duty Diesel Exhaust ... The semivolatile mass fraction of diesel exhaust particles was studied using size-resolved on-line techniques (DMA-ELPI; TDMA-ELPI). ... The measured size resolved values of mass transfer imply that condensation, or diffusion-limited mass transfer, plays a major role in driving the volatile matter to the diesel exhaust particles. ...

Jyrki Ristimki; Kati Vaaraslahti; Maija Lappi; Jorma Keskinen

2007-08-10T23:59:59.000Z

318

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...leaves and/or exposure to combustion products or formation of ash...analysis of the mainstream smoke chemistry of samples of the U.S. cigarette...comparison of the tumors induced by coal tar and benzo[a]pyrene...Spectrometry Ilex paraguariensis chemistry Polycyclic Hydrocarbons, Aromatic...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

319

Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection  

E-Print Network [OSTI]

data quality is good. This technique can be directly applied to the processed 2D and 3 D pre-stack/post-stack data sets (1) to detect hydrocarbon zones in both clastic and carbonate reservoirs by analyzing the low frequency signals in the decomposed...

Cai, Rui

2012-02-14T23:59:59.000Z

320

Chemical Kinetics of Hydrocarbon Ignition in Practical Combustion Systems  

SciTech Connect (OSTI)

Chemical kinetic factors of hydrocarbon oxidation are examined in a variety of ignition problems. Ignition is related to the presence of a dominant chain branching reaction mechanism that can drive a chemical system to completion in a very short period of time. Ignition in laboratory environments is studied for problems including shock tubes and rapid compression machines. Modeling of the laboratory systems are used to develop kinetic models that can be used to analyze ignition in practical systems. Two major chain branching regimes are identified, one consisting of high temperature ignition with a chain branching reaction mechanism based on the reaction between atomic hydrogen with molecular oxygen, and the second based on an intermediate temperature thermal decomposition of hydrogen peroxide. Kinetic models are then used to describe ignition in practical combustion environments, including detonations and pulse combustors for high temperature ignition, and engine knock and diesel ignition for intermediate temperature ignition. The final example of ignition in a practical environment is homogeneous charge, compression ignition (HCCI) which is shown to be a problem dominated by the kinetics intermediate temperature hydrocarbon ignition. Model results show why high hydrocarbon and CO emissions are inevitable in HCCI combustion. The conclusion of this study is that the kinetics of hydrocarbon ignition are actually quite simple, since only one or two elementary reactions are dominant. However, there are many combustion factors that can influence these two major reactions, and these are the features that vary from one practical system to another.

Westbrook, C.K.

2000-07-07T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Energy Conservation Opportunities in Hydrocarbon Resin Manufacturing Facilities  

E-Print Network [OSTI]

"The results of a plant-wide assessment of the manufacturing facilities of Neville Chemical Company, a manufacturer of hydrocarbon resins will be presented in this paper. The project was co-funded by US Department of Energy under its Plant...

Ganji, A. R.; Hackett, B.; Chow, S.; Lonergan, R.; Wimer, J.

322

Fundamental spectroscopic studies of carbenes and hydrocarbon radicals  

SciTech Connect (OSTI)

Highly reactive carbenes and carbon-chain radicals are studied at millimeter wavelengths by observing their rotational spectra. The purpose is to provide definitive spectroscopic identification, accurate spectroscopic constants in the lowest vibrational states, and reliable structures of the key intermediates in reactions leading to aromatic hydrocarbons and soot particles in combustion.

Gottlieb, C.A.; Thaddeus, P. [Harvard Univ., Cambridge, MA (United States)

1993-12-01T23:59:59.000Z

323

Climatically driven emissions of hydrocarbons from marine sediments during deglaciation  

Science Journals Connector (OSTI)

...destabilizing hydrates shown in the lighter...destabilization of methane hydrates and release of...in SBC suggest gas emissions during...investigate the sand-sized fraction...the presence of sand layers (23...hydrocarbons and methane hydrate, which is widely...4) (24). Gas hydrates commonly...

T. M. Hill; J. P. Kennett; D. L. Valentine; Z. Yang; C. M. Reddy; R. K. Nelson; R. J. Behl; C. Robert; L. Beaufort

2006-01-01T23:59:59.000Z

324

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network [OSTI]

1 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management : United States (2008)" #12;2 I. Introduction One of the main issues of the development of scramjet, an air to the endothermicity of its thermal decomposition. Because of the large heat load found in a scramjet, engine

Paris-Sud XI, Université de

325

Hydrocarbon saturation determination using acoustic velocities obtained through casing  

DOE Patents [OSTI]

Compressional and shear velocities of earth formations are measured through casing. The determined compressional and shear velocities are used in a two component mixing model to provides improved quantitative values for the solid, the dry frame, and the pore compressibility. These are used in determination of hydrocarbon saturation.

Moos, Daniel (Houston, TX)

2010-03-09T23:59:59.000Z

326

Increased olefins production via recovery of refinery gas hydrocarbons  

SciTech Connect (OSTI)

In the process of catalytically cracking heavy petroleum fractions to make gasoline and light fuel oil, by-product waste gases are also generated. The waste gases, normally used as fuel, are themselves rich sources of ethylene, propylene and other light hydrocarbons which can be recovered inexpensively via a cryogenic dephlegmator process. This gas separation technique is exploited in a system, in operation since spring of 1987, which reclaims C/sub 2/+ hydrocarbons from a refinery gas. The reclamation process bolsters production in a nearby ethylene plant. Causing no disruption of ethylene plant operations, the cryogenic hydrocarbon recovery system functions smoothly with existing systems. The dephlegmation unit operation melds distillation and heat transfer processes in a single easily-controlled step which boosts the hydrocarbon purity and recovery above the levels profitably achievable with conventional cryogenic separation techniques. Very attractive operating economics follow from high purity, high recovery, and high energy efficiency. This paper discusses process concepts, economic benefits, plant operation, and early performance results.

Bernhard, D.P.; Rowles, H.C.; Moss, J.A.; Pickering, J.L. Jr.

1988-01-01T23:59:59.000Z

327

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network [OSTI]

THERMOCATALYTIC CO2- FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS N. Muradov Florida Solar Energy Center 1679 Clearlake Road, Cocoa, Florida 32922 tel. 321-638-1448, fax. 321-638-1010, muradov (except for the start-up operation). This results in the following advantages: (1) no CO/CO2 byproducts

328

Biodegradation of total petroleum hydrocarbon (TPH) in Jordanian petroleum sludge  

Science Journals Connector (OSTI)

Bioremediation, or the use of micro-organisms to decontaminate soil or groundwater, is being increasingly seen as an effective, environment-friendly treatment for oil-contaminated sites. In this study, the results are presented concerning a laboratory screening of several natural bacterial consortia and laboratory tests to establish the performance in degradation of hydrocarbons contained in oily sludge from the Jordan Oil Refinery Plant. As a result of the laboratory screening, 18 isolates were selected and grouped into two main clusters; cluster 1 containing 12 isolates grown at 43°C, and cluster 2 containing six isolates grown at 37°C. Three natural bacterial consortia with ability to degrade total petroleum hydrocarbons (TPH) were prepared from these isolates. Experiments were conducted in Erlenmeyer flasks under aerobic conditions, with TPH removal percentage varying from 5.9% to 25.1%, depending upon consortia type and concentration. Consortia 7B and 13B exhibited the highest TPH removal percentages of 25% and 23%, respectively before nutrient addition. TPH removal rate was enhanced after addition of nutrients to incubated flasks. The highest TPH reduction (37%) was estimated after addition of a combination of nitrogen, phosphorus and sulphur to consortia 7B. This is the first report concerning biological treatment of total petroleum hydrocarbon by bacteria isolated from the oil refinery plant, where it lay the ground for full integrated studies recommended for hydrocarbon degradation that assist in solving sludge problems.

Bassam Mrayyan; Mohammad Battikhi

2004-01-01T23:59:59.000Z

329

Hydrocarbons in rift basins: the role of stratigraphy  

Science Journals Connector (OSTI)

...succession that causes the shales to reach thermal maturity and generate hydrocarbons. Simple...T. J. 1988 Rift basins of interior Sudan--petroleum exploration and discovery...basins? Is that what we could call the thermal subsidence phase? J. J. Lambiase...

1999-01-01T23:59:59.000Z

330

Application of Resource-Ratio Theory to Hydrocarbon Biodegradation  

Science Journals Connector (OSTI)

Application of Resource-Ratio Theory to Hydrocarbon Biodegradation ... We suggest that the procedures outlined here can be used to help guide practical decisions about the nutrients that are most likely to be growth-limiting and help define the subsequent nutrient application rates. ...

Val H. Smith; David W. Graham; Dale D. Cleland

1998-09-12T23:59:59.000Z

331

Theoretical studies of hydrocarbon combustion chemistry. Annual progress report  

SciTech Connect (OSTI)

The author reports here the results of DZP CISD calculations for methylcarbene. Geometry, symmetry, and vibrational modes for the radical are reported for both the singlet and the triplet state. Future work will focus on the ethyl radical-oxygen interaction relevant to hydrocarbon combustion.

Schaefer, H.F. III

1994-08-01T23:59:59.000Z

332

Chemical Fate of Contaminants in the Environment: Chlorinated Hydrocarbons in the Groundwater  

SciTech Connect (OSTI)

Chlorinated hydrocarbons (CHCs) are the most common contaminant found at hazardous waste sites and are the most prevalent contaminants on U.S. Department of Energy (DOE) weapons production sites. Many of the CHCs are either known or suspected carcinogens and thus pose health risks to the public and/or site workers. Unlike simple hydrocarbons, CHCs are resistant to biodegradation, but can degrade by abiotic processes such as hydrolysis, nucleophilic substitution, and dehydrochlorination. Unfortunately, few studies of the reactions of chlorinated hydrocarbons have been reported in literature, and disagreement still exists about the mechanisms and rates of many of the key reactions. In this work, we modeled the reactions involved in the degradation of CHCs in the groundwater. The goals of the research proposed are: development of a computational approach that will allow reaction pathways and rate constants to be accurately calculated development of more approximate approaches, evaluated against the more accurate approach, which will lay the groundwork for exploratory studies of more complex CHCs application of these approaches to study the degradation pathways of CHCs in aqueous liquids application of the more approximate approaches to study the mechanism of forming complex CHC polychlorinated benzene compounds and dioxins. We examined elementary reactions involved in the aqueous-phase chemistry of chlorinated methanes and ethylenes in an attempt to obtain a detailed understanding of the abiotic processes involved in the degradation of this important class of contaminants. We began by studying the reactions of CHnCl(4-n) and C2HnCl(4-n) with OH, as these are thought to be the dominant processes involved in the degradation of these chlorinated species. We used state-of-the-art theoretical techniques to model the elementary reactions of CHCs important in the groundwater. We employed high-accuracy electronic structure methods (e.g., perturbation theory and coupled cluster methods with correlation-consistent basis sets) to determine the energies of the various stable species, intermediates, and transition states involved in the elementary reactions of CHCs. Effects of solvation on the reaction energetics were studied by including small numbers of solvent molecules (microsolvation). Our own N-layered molecular orbital + molecular mechanics (ONIOM) method was used because it allows the number of solvent molecules to be increased, and hybrid quantum mechanical/molecular mechanics (QM/MM) methods and continuum solvation models were used to estimate the effects of bulk solvation. Rate constants for the gas-phase, microsolvated, and bulk-phase reactions were computed using variational transition state theory (VTST).

Truhlar, Donald G.; Cramer, Christopher; Gao, Jiali; Garrett, Bruce C.; Dupuis, Michel; Straatsma, TP; Morokuma, Keiji; Dunning, Thomas H.; Borisov, Yurii A.; Arcia, Edgar E.; Thompson, Jacob S.

2006-09-21T23:59:59.000Z

333

Reclamation and groundwater remediation at a hydrocarbon site in Alaska  

SciTech Connect (OSTI)

As part of a joint hydrocarbon cleanup project between Unocal and Marathon, we have initiated the use of constructed wetlands for restoration of the 40-acre Poppy Lane gravel pit located near Kenai, Alaska. Gravel excavated from this site was used to construct roads and drilling pads in the 1960`-70`s. During this period it was also used as a refuse dump for waste from the Kenai gas field and from local residents. The bulk wastes were removed and pockets of oily sand were removed, treated and returned to a stockpile on the site. This left the site with residual pockets of hydrocarbon-impacted sand (<1000 TPH) plus traces of hydrocarbon contamination in the uppermost shallow groundwater flowing through the outwash gravels. The final part of the cleanup will be land restoration and bioremediation of the final traces of hydrocarbons, which are predominantly diesel-range. High resolution gas chromatography analysis indicated that common plants already growing on the site (willow, cottonwood, and alder) did not concentrate diesel-range petroleum hydrocarbons in their foliage when growing in soils containing these contaminants. As part of the planned restoration and shallow groundwater remediation, two 1/3 acre test plots were constructed to promote in-situ biodegradation processes. In spring 1995, the first test, a tree root-barrier plot, was planted with dormant cuttings of four native wetland tree and shrub species, which were planted to depths up to five feet. Alder and elderberry did not succeed under any conditions, nor did any species planted in standing water. For cottonwood and willow species, approximately one half of each rooted and survived. When the water table dropped the second year, the willow cuttings rooted deeper in the vadose zone, while cottonwood did not. As a result of these findings, a tree root-barrier wetland is not considered to be a viable option for groundwater treatment at Poppy Lane.

Ririe, G.T. [Unocal, Brea, CA (United States); Drake, L.D. [Univ. of Iowa, Iowa City, IA (United States); Olson, S.S. [Marathon Oil, Tyler, TX (United States)

1997-12-31T23:59:59.000Z

334

Interaction of Carcinogenic Hydrocarbons with Tissues: VIII. Binding of Tritium-labeled Hydrocarbons to the Soluble Proteins of Mouse Skin  

Science Journals Connector (OSTI)

...treated as described in "Materials and Methods." A demonstration...of the unbound radio active hydrocarbon was removed...migrated toward the cathode, a neutral in dicator...pro teins toward the cathode was affected by electro...dermis as described in "Materials and Methods." The...

C. W. Abell and Charles Heidelberger

1962-09-01T23:59:59.000Z

335

Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds  

DOE Patents [OSTI]

A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt. % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450.degree. to 700.degree. C. over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C.sub.1 -C.sub.8 hydrocarbons and a reduction in H.sub.2 S over gas obtainable by pyrolyzing cola without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

Khan, M. Rashid (Morgantown, WV)

1988-01-01T23:59:59.000Z

336

Polishing compound for plastic surfaces  

DOE Patents [OSTI]

A polishing compound for plastic surfaces. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS.TM., LEXAN.TM., LUCITE.TM., polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, Michael S. (New Ellenton, SC)

1995-01-01T23:59:59.000Z

337

Polishing compound for plastic surfaces  

DOE Patents [OSTI]

A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired. 5 figs.

Stowell, M.S.

1995-08-22T23:59:59.000Z

338

Polishing compound for plastic surfaces  

DOE Patents [OSTI]

A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains colloidal silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{sup TM}, LEXAN{sup TM}, LUCITE{sup TM}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1993-01-01T23:59:59.000Z

339

Nitroaromatic Compounds, from Synthesis to Biodegradation  

Science Journals Connector (OSTI)

...exhaust from all combustion engines contains hydrocarbons that...atmospheric pollution is diesel engine-powered motor vehicles (165). Diesel exhaust contains PAHs such...studies have revealed that the general strategy used to metabolize...

Kou-San Ju; Rebecca E. Parales

2010-06-01T23:59:59.000Z

340

Crystallographic properties of fertilizer compounds  

SciTech Connect (OSTI)

This bulletin is a compilation of crystallographic data collected at NFERC on 450 fertilizer-related compounds. In TVA's fertilizer R and D program, petrographic examination, XRD, and infrared spectroscopy are combined with conventional chemical analysis methods in identifying the individual compounds that occur in fertilizer materials. This handbook brings together the results of these characterization studies and supplemental crystallographic data from the literature. It is in one-compound-per-page, loose-leaf format, ordered alphabetically by IUPAC name. Indexes provided include IUPAC name, formula, group, alternate formula, synonyms, x-ray data, optical data. Tables are given for solids, compounds in commercial MAP and DAP, and matrix materials in phosphate rock.

Frazier, A.W.; Dillard, E.F.; Thrasher, R.D.; Waerstad, K.R.; Hunter, S.R.; Kohler, J.J.; Scheib, R.M.

1991-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Polishing compound for plastic surfaces  

DOE Patents [OSTI]

This invention is comprised of a polishing compound for plastic materials. The compound includes approximately by approximately by weight 25 to 80 parts at least one petroleum distillate lubricant, 1 to 12 parts mineral spirits, 50 to 155 parts abrasive paste, and 15 to 60 parts water. Preferably, the compound includes approximately 37 to 42 parts at least one petroleum distillate lubricant, up to 8 parts mineral spirits, 95 to 110 parts abrasive paste, and 50 to 55 parts water. The proportions of the ingredients are varied in accordance with the particular application. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC), and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1991-01-01T23:59:59.000Z

342

Detection of chlorinated aromatic compounds  

DOE Patents [OSTI]

A method for making a composition for measuring the concentration of chloated aromatic compounds in aqueous fluids, and an optical probe for use with the method. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis.

Ekechukwu, Amy A. (Augusta, GA)

1996-01-01T23:59:59.000Z

343

Distribution and concentrations of petroleum hydrocarbons associated with the BP/Deepwater Horizon Oil Spill, Gulf of Mexico  

Science Journals Connector (OSTI)

Abstract We examined the geographic extent of petroleum hydrocarbon contamination in sediment, seawater, biota, and seafood during/after the BP/Deepwater Horizon Oil Spill (April 20July 15, 2010; 28.736667N, ?88.386944W). TPH, PAHs, and 12 compound classes were examined, particularly C1-benzo(a)anthracenes/chrysenes, C-2-/C-4-phenanthrenes/anthracenes, and C3-naphthalenes. Sediment TPH, PAHs, and all classes peaked near Pensacola, Florida, and Galveston, Texas. Seawater TPH peaked off Pensacola; all of the above classes peaked off the Mississippi River, Louisiana and Galveston. Biota TPH and \\{PAHs\\} peaked near the Mississippi River; C-3 napthalenes peaked near the spill site. Seafood TPH peaked near the spill site, with \\{PAHs\\} and all classes peaking near Pensacola. We recommend that oil concentrations continued to be monitored in these media well after the spill has ceased to assist in defining re-opening dates for fisheries; closures should be maintained until hydrocarbon levels are deemed within appropriate limits.

Paul W. Sammarco; Steve R. Kolian; Richard A.F. Warby; Jennifer L. Bouldin; Wilma A. Subra; Scott A. Porter

2013-01-01T23:59:59.000Z

344

Growth Yields of Bacteria on Selected Organic Compounds  

Science Journals Connector (OSTI)

...calculate heats of combustion of an exceedingly...carbohydrates, and hydrocarbons, wehave calculated...9, 10), heats of combustion per available...microbial cells on hydrocarbons. Science...S. 1929. Heats of combustion of organic...

W. R. Mayberry; G. J. Prochazka; W. J. Payne

1967-11-01T23:59:59.000Z

345

Apparatus for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

346

Method for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

347

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents [OSTI]

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, Ranjani V. (Morgantown, WV)

1993-01-01T23:59:59.000Z

348

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

2013-03-31T23:59:59.000Z

349

Faults as potential hydrocarbon barriers, Arroyo Grande, California  

E-Print Network [OSTI]

OPTICALMICROSCOPY. Composition. Grain Size Characteristics Deformation Fluorescence Observations . Microprobe Observations. CAPILLARY PRESSURE. Sample Preparation. Test Procedures. Interpretation of the Mercury Injection Capillary Pressure Curve... rim of hydrocarbons seen on the grains. 41 , , 42 25 Photomicrograph of one of the microcracks that contains oil, 43 26 Microprobe image of the zone of quartz cement seen in the quarry, 27 Mercury injection capillary pressure apparatus, 45 48...

Switek, Daniel Paul

2012-06-07T23:59:59.000Z

350

THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS  

SciTech Connect (OSTI)

The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

Ricca, Alessandra [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Allamandola, Louis J., E-mail: Alessandra.Ricca-1@nasa.gov, E-mail: Charles.W.Bauschlicher@nasa.gov [Space Science Division, Mail Stop 245-6, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

2013-10-10T23:59:59.000Z

351

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and expert riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1992-01-01T23:59:59.000Z

352

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and export riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1994-01-01T23:59:59.000Z

353

Petroleum hydrocarbon-degrading bacteria in the Galveston Bay system  

E-Print Network [OSTI]

PETROLEUM HYDRQCARBOiV-DEGRADING BACTERIA IN THE GALVESTON BAY SYSTEM A Thesis by STEVEN JAMES SCHROPP Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER OF SCIFNCE... December 1979 Major Subject: Biology PETROLEUM HYDROCARBON-DEGRADING BACTERIA IN THE GALVESTON BAY SYSTEM A Thesis by STEVEN JAMES SCHROPP Approved as to style and content by: (Co-Chairman of Committee) '( ~CA. ( -Chairman of Committee) (Head...

Schropp, Steven James

1979-01-01T23:59:59.000Z

354

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents [OSTI]

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

355

Direct production of fractionated and upgraded hydrocarbon fuels from biomass  

SciTech Connect (OSTI)

Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

2014-08-26T23:59:59.000Z

356

Catalyst and process for steam-reforming of hydrocarbons  

SciTech Connect (OSTI)

An improved catalyst and an improved process for use of the catalyst in the steam-hydrocarbon reforming reaction are disclosed. The catalyst comprises a group VIII metal on a cylindrical ceramic support consisting essentially of alpha alumina and having a plurality of gas passages extending axially therethrough. These supported catalysts display a higher geometric surface area and a lower pressure drop than do standard rings.

Atwood, K.; Merriam, J.S.; Wright, J.H.

1980-11-11T23:59:59.000Z

357

Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments  

E-Print Network [OSTI]

. Sandberg, B. A. , University of Colorado Chairman of Advisory Committee: Dr. James M. Brooks Polycyclic aromatic hydrocarbon (PAH) distributions in Upper Pleistocene sediments of the Mississippi Fan and two intraslope basins in the Gulf of Mexico... chemistries is separate phase migration driven by hydrodynamic flow upward along fault planes. The same variables at intraslope basin sites are highly altered, possibly due to extensive gravity slump faulting. High- performance liquid chromatography...

Sandberg, William Allan

2012-06-07T23:59:59.000Z

358

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents [OSTI]

A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, Carl B. (Augusta, GA)

1989-01-01T23:59:59.000Z

359

Irregular spacing of heat sources for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

Miller, David Scott (Katy, TX); Uwechue, Uzo Philip (Houston, TX)

2012-06-12T23:59:59.000Z

360

Federal Environmental Regulations Impacting Hydrocarbon Exploration, Drilling, and Production Operations  

SciTech Connect (OSTI)

Waste handling and disposal from hydrocarbon exploration, drilling, and production are regulated by the US Environmental Protection Agency (EPA) through federal and state regulations and/or through implementation of federal regulations. Some wastes generated in these operations are exempt under the Resource Conservation and Recovery Act (RCRA) but are not exempt under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendments and Reauthorization Act (SARA), and other federal environmental laws. Exempt wastes remain exempt only if they are not mixed with hazardous wastes or hazardous substances. Once mixture occurs, the waste must be disposed as a hazardous material in an approved hazardous waste disposal facility. Before the Clean Air Act as amended in 1990, air emissions from production, storage, steam generation, and compression facilities associated with hydrocarbon exploration, drilling, and production industry were not regulated. A critical proposed regulatory change which will significantly effect Class II injection wells for disposal of produced brine and injection for enhanced oil recovery is imminent. Federal regulations affecting hydrocarbon exploration, drilling and production, proposed EPA regulatory changes, and a recent significant US Court of Appeals decision are covered in this report. It appears that this industry will, in the future, fall under more stringent environmental regulations leading to increased costs for operators.

Carroll, Herbert B.; Johnson, William I.

1999-04-27T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Paleotopography and hydrocarbon accumulation: Williston, Powder River, and Denver basins  

SciTech Connect (OSTI)

Recent geomorphic analyses of 1:24,000 scale topographic maps in the three major basins of the northern Great Plains have disclosed a persistent system of basement paleotopographic features that trend north-northeast throughout the region. Superimposed across this system and subtly influenced by it, are the northwesterly trending Laramide structural features. Paleozoic depositional patterns have been strongly influenced by the paleoridge and trough system formed by the north-northeast features. Mesozoic deposition has also been affected by the ancient subsurface system but in a more subtle manner. Many of the Paleozoic and Mezoxoic hydrocarbon locations in the three basins appear to be the results of paleotopographic control on hydrocarbon accumulation sites. This affect ranges from Paleozoic reef sites in the Williston basin through paleotrough localization of Pennsylvanian Minnelusa production in the Powder River basin to fractured Cretaceous Niobrara production at the Silo field in the Denver basin. Basement paleotopography is the underlying factor in all deposition and subsequent hydrocarbon migration in any basin. As such, it should be considered a major factor in the exploration for oil and gas.

Thomas, G.E. (Thomas and Associates, Denver, CO (United States))

1991-06-01T23:59:59.000Z

362

Nitroaromatic Compounds, from Synthesis to Biodegradation  

Science Journals Connector (OSTI)

...compounds that enter the TCA cycle. Interestingly, expression...and then converted to TCA cycle compounds, with salicylate...nitroaromatic compounds, but several fundamental aspects regarding their biosynthesis...Explosives development and fundamentals of explosives technology...

Kou-San Ju; Rebecca E. Parales

2010-06-01T23:59:59.000Z

363

compound queries | OpenEI Community  

Open Energy Info (EERE)

Jweers's picture Submitted by Jweers(83) Contributor 16 May, 2013 - 14:22 Multicolor Maps from Compound Queries ask queries compound queries developer Google maps maps...

364

Electric Turbo Compounding Technology Update | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Compounding Technology Update Electric Turbo Compounding Technology Update Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

365

Novel Phosphazene Compounds for Enhancing Electrolyte Stability...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion Cells Novel Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion...

366

Novel Phosphazene Compounds for Enhancing Electrolyte Stability...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Novel Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion Cells Novel Phosphazene Compounds for Enhancing Electrolyte Stability and Safety of...

367

Measurement of polynuclear aromatic hydrocarbon concentrations in the plume of Kuwait oil well fires  

SciTech Connect (OSTI)

Following their retreat from Kuwait during February and March of 1991, the Iraqi Army set fire to over 500 oil wells dispersed throughout the Kuwait oil fields. During the period of sampling from July to August 1991, it was estimated that between 3.29 {times} 10{sup 6} barrels per day of crude oil were combusted. The resulting fires produced several plumes of black and white smoke that coalesced to form a composite ``super`` plume. Because these fires were uncontrolled, significant quantities of organic materials were dispersed into the atmosphere and drifted throughout the Middle East. The organic particulants associated with the plume of the oil well fires had a potential to be rich in polynuclear aromatic hydrocarbon (PAH) compounds. Based on the extreme mutagenic and carcinogenic activities of PAHs found in laboratory testing, a serious health threat to the population of that region potentially existed. Furthermore, the Kuwait oil fire plumes represented a unique opportunity to study the atmospheric chemistry associated with PAHs in the plume. If samples were collected near the plume source and from the plume many kilometers downwind from the source, comparisons could be made to better understand atmospheric reactions associated with particle-bound and gas-phase PAHs. To help answer health-related concerns and to better understand the fate and transport of PAHs in an atmospheric environment, a sampling and analysis program was developed.

Olsen, K.B.; Wright, C.W.; Veverka, C. [Pacific Northwest Lab., Richland, WA (United States); Ball, J.C. [Ford Motor Co., Dearborn, MI (United States). Scientific Research Lab.; Stevens, R. [US Environmental Protection Agency (United States). Atmospheric Research and Exposure Assessment Lab.

1995-03-01T23:59:59.000Z

368

AN EMPIRICAL APPROACH FOR PREDICTING VISCOSITIES OF HYDROCARBON SYSTEMS: DEFINED COMPOUNDS, DIRECT COAL LIQUID OILS AND LIGHT CRUDE OILS.  

E-Print Network [OSTI]

??A single parameter empirical method, based on the Effective Carbon Number (ECN) concept proposed by Allan and Teja (1991), was modified and extended to predict (more)

Krishnamoorthy, Vijayaragavan

2010-01-01T23:59:59.000Z

369

Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites  

SciTech Connect (OSTI)

Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

2014-05-06T23:59:59.000Z

370

Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device  

DOE Patents [OSTI]

A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

2014-05-06T23:59:59.000Z

371

Apparatus and method for rapid separation and detection of hydrocarbon fractions in a fluid stream  

DOE Patents [OSTI]

An apparatus and method for rapid fractionation of hydrocarbon phases in a sample fluid stream are disclosed. Examples of the disclosed apparatus and method include an assembly of elements in fluid communication with one another including one or more valves and at least one sorbent chamber for removing certain classifications of hydrocarbons and detecting the remaining fractions using a detector. The respective ratios of hydrocarbons are determined by comparison with a non separated fluid stream.

Sluder, Charles S.; Storey, John M.; Lewis, Sr., Samuel A.

2013-01-22T23:59:59.000Z

372

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel  

Science Journals Connector (OSTI)

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel ... We found that the primary decomposition reactions involve either (1) dissociation of ethylene from JP-10, resulting in the formation of a C8 hydrocarbon intermediate, or (2) the production of two C5 hydrocarbons. ... Heats of combustion (kcal/mole) were measured via O bomb calorimetry; adamantane (I) (c), -1441.95 ...

Kimberly Chenoweth; Adri C. T. van Duin; Siddharth Dasgupta; William A. Goddard III

2009-02-11T23:59:59.000Z

373

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust  

Science Journals Connector (OSTI)

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust ... Diesel and Gasoline Engine Exhausts and Some Nitroarenes; IARC:? Lyon, France 1989. ...

Wei Huang; Thomas J. Smith; Long Ngo; Tong Wang; Hongqiao Chen; Fanggu Wu; Robert F. Herrick; David C. Christiani; Hui Ding

2007-03-16T23:59:59.000Z

374

Naphthenic/paraffinic hydrocarbons of residual lube stock from West Siberian crudes  

SciTech Connect (OSTI)

The lube stocks from West Siberian crudes are characterized by high contents of aromatic hydrocarbons and by high viscosity indexes of the naphthenic/paraffinic and aromatic hydrocarbons. Mass spectrometric analysis showed that isoparaffins account for one-third of the total naphthenic/paraffinic hydrocarbons. The study showed that the naphthenic/paraffinic hydrocarbons of the residual lube stock from West Siberia crudes, even with a variation of molecular weight over broad limits, are relatively uniform in composition. They consist mainly of isoparaffinic and monocyclic and noncondensed naphthenic structures.

Detusheva, E.P.; Bogdanov, Sh.K.; Khramtsova, L.P.; Nekrasova, A.V.; Shkol'nikov, V.M.

1983-03-01T23:59:59.000Z

375

E-Print Network 3.0 - abundant accessible hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functionalization: An Energy Frontier Research... such as hydrocarbons, dioxygen, water, carbon dioxide and dihydrogen are central to new technologies for the use... of...

376

E-Print Network 3.0 - aromatic hydrocarbon exhaust Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: : Acetylenes: Aromatics: 57 15 2 26 A breakdown of 17...

377

Calculation of the heats of combustion of aromatic hydrocarbons contained in power-generating fuel  

Science Journals Connector (OSTI)

The additive method of group contributions is used for the calculation of the heats of combustion of aromatic hydrocarbons of different structures.

E. V. Sagadeev; V. V. Sagadeev

2006-07-01T23:59:59.000Z

378

Calculation of the Heats of Combustion of Saturated Hydrocarbons Contained in Power-Generating Fuels  

Science Journals Connector (OSTI)

An empirical method is suggested for the calculation of the heats of combustion of saturated hydrocarbons by the additive scheme proceeding from their...

E. V. Sagadeev; V. V. Sagadeev

2002-07-01T23:59:59.000Z

379

E-Print Network 3.0 - aromatic hydrocarbon diol-epoxide Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with a DNA... ), a polycyclic aromatic hydrocarbon. A residue of fuel and tobacco combustion and frequently ingested by humans... , BP is metabolized in mammals to...

380

Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI Emission Control  

Broader source: Energy.gov [DOE]

Development of catalyst materials to facilitate the low-temperature oxidation of hydrocarbons and CO in homogeneous charge compression ignition (HCCI) emissions.

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

The Impact of Low Octane Hydrocarbon Blending Streams on "E85...  

Broader source: Energy.gov (indexed) [DOE]

Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization deer12szybist.pdf More Documents &...

382

E-Print Network 3.0 - aromatic hydrocarbons adducted Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon... to its high reactivity toward DNA and cellular proteins. The major acrolein-DNA adduct, -hydrox- ypropano... -hy- droxynonenal, and acrolein, that readily form...

383

E-Print Network 3.0 - aromatic hydrocarbon pah-degrading Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

degradation Summary: Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N... , terminate in the sludge, and can be released to the...

384

E-Print Network 3.0 - aromatic hydrocarbons pahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

385

E-Print Network 3.0 - aromatic hydrocarbons pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

386

E-Print Network 3.0 - aromatic hydrocarbon pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

387

Polycyclic Aromatic Hydrocarbons Formation in Sludge Incineration by Fluidised Bed and Rotary Kiln Furnace  

Science Journals Connector (OSTI)

Polycyclic Aromatic Hydrocarbons (PAHs) are typical pollutants arising from incineration. They are produced in any incomplete combustion principally due to inhomogeneities in a combustion chamber. The effects ...

Giuseppe Mininni; Andrea Sbrilli; Ettore Guerriero

2004-05-01T23:59:59.000Z

388

E-Print Network 3.0 - aromatic polycyclic hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

coal, oil, gas... called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called Source: Rock, Chris - Department of Biological Sciences,...

389

E-Print Network 3.0 - aromatic hydrocarbons modulate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

390

E-Print Network 3.0 - aromatic hydrocarbon tracers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

391

E-Print Network 3.0 - aryl hydrocarbon receptor-regulated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

classes of the aryl hydrocarbon receptor (AHR). A grander objective is to provide... pollutants is a direct consequence of their interactions with the aryl ... Source: Bradfield,...

392

E-Print Network 3.0 - aryl hydrocarbon receptor-1 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

393

E-Print Network 3.0 - aromatic hydrocarbon water-soluble Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... with their lipophilicity and water...

394

E-Print Network 3.0 - aromatic hydrocarbons phahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

WH, Caton JE. 1983. Extraction of polycyclic aromatic hydrocarbons for qualitative analysis. In... : Handbook of Polycyclic Aromatic ... Source: Rock, Chris - Department of...

395

E-Print Network 3.0 - aryl hydrocarbon receptor-independent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

396

E-Print Network 3.0 - aryl hydrocarbon receptor-mediated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 TOXICOLOGICAL SCIENCES 106(1), 8392 (2008) doi:10.1093toxscikfn149 Summary: ). Analysis of aryl hydrocarbon receptor-mediated signaling during physiological hypoxia reveals...

397

E-Print Network 3.0 - aromatic hydrocarbon-contaminated soil...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

soil... hydrocarbon degraders, and polycyclic aromatic ... Source: Ma, Lena - Soil and Water Science Department, University of Florida Collection: Environmental Sciences and...

398

Examination of polycyclic aromatic hydrocarbons in an urban stormwater system and bioaccumulation in Odonata.  

E-Print Network [OSTI]

??Polycyclic aromatic hydrocarbons (PAHs) are toxic organic pollutants produced from combustion processes. Associated with urban runoff they have been detected worldwide in urban wetlands. PAH (more)

Heintzman, Lucas

2013-01-01T23:59:59.000Z

399

Problems in Catalytic Oxidation of Hydrocarbons and Detailed Simulation of Combustion Processes.  

E-Print Network [OSTI]

??This dissertation research consists of two parts, with Part I on the kinetics of catalytic oxidation of hydrocarbons and Part II on aspects on the (more)

Xin, Yuxuan

2014-01-01T23:59:59.000Z

400

New IR Fiber-Optic Chemical Sensor for in Situ Measurements of Chlorinated Hydrocarbons in Water  

Science Journals Connector (OSTI)

In this work the development and validation of a new MIR fiber-optic physicochemical sensor system for the continuous in situ analysis of chlorinated hydrocarbons (CHCs) in...

Krska, R; Taga, K; Kellner, R

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Detection of Hydrocarbons in Water by MIR Evanescent-Wave Spectroscopy with Flattened Silver Halide Fibers  

Science Journals Connector (OSTI)

IR transmitting AgClxBr1-x fibers were used as internal reflection elements for the spectroscopic detection of hydrocarbons that are dissolved in water in an...

Hahn, P; Tacke, M; Jakusch, M; Mizaikoff, B; Spector, O; Katzir, A

2001-01-01T23:59:59.000Z

402

Characterization of hydrocarbons found in the arctic aquatic environment near the Ekati diamond mine.  

E-Print Network [OSTI]

??Polycyclic aromatic hydrocarbons (PAHs) in the aquatic environment of the Ekati Diamond Mine were evaluated in snow, sediment, air and water (via passive membrane samplers). (more)

Nabess, Stephanie Ann

2014-01-01T23:59:59.000Z

403

Hydrocarbon solubility and its migration processes: a look at the present status  

SciTech Connect (OSTI)

In this study we review the present status of knowledge of solubility of hydrocarbons and its implications on primary migration processes. The intent is to examine the solubility and the transportation mechanisms relevant to geopressured-geothermal reservoirs, although the discussion included here accommodates a wide range of related aspects. Influences of parameters associated with hydrocarbon (especially methane) solubility have been studied. We have sought to evaluate several primary hydrocarbon migration processes and to point out their attractive features as well as their limitations. A brief discussion of hydrocarbon generation processes is also included.

Mamun, C.K.; Ohkuma, H.; Sepehrnoori, K.

1985-12-01T23:59:59.000Z

404

Emissions of non-methane organic compounds from a grassland site  

SciTech Connect (OSTI)

A mixture of oxygenated hydrocarbons (OxHCs), isoprene, and monoterpenes was detected in the emissions from a grassland site in the Midwestern United States. A plot dominated by crown vetch (Coronilla varia) and bluegrass (Poa spp.), exhibited a constant decrease in emissions of total non-methane organic compounds (NMOCs) from 580 {mu}g m{sup -2} hr{sup -1} in June 1992 to 150 {mu}g m{sup - 2} hr{sup -1} in October 1992, except for a slight increase in August. Oxygenated hydrocarbons (methanol, acetaldehyde, and acetone) and terpenes (isoprene, limonene, myrcene, {alpha}-pinene, and {beta}- pinene) composed about 90% and 10% of the identified NMOC emissions, respectively. Isoprene represented about 10% of the terpene emissions. Total NMOC emission rates based on vegetative biomass averaged 2.3 {mu}g g{sup -1} hr{sup -1}, with 10% of the identified NMOCs attributed to monoterpenes and the remainder mainly OxHCs. Over the course of the investigation, the relationship between the monoterpene emission rate and the temperature for a single plot was logarithmic and similar to the one between compound vapor pressure and temperature. However, emission rates normalized to temperature decreased throughout the summer and fall, indicating that parameterizations of emission rates from herbaceous plants must include a factor to compensate for environmental conditions such as soil moisture and nutrient deposition, which affect plant phenology and the seasonal pattern of species dominance.

Fukui, Yoshiko; Doskey, P.V.

1996-03-01T23:59:59.000Z

405

Volatile compounds from marine algae  

Science Journals Connector (OSTI)

Volatile compounds from marine algae ... Seasonal Variations of Bromophenols in Brown Algae (Padina arborescens, Sargassum siliquastrum, and Lobophora variegata) Collected in Hong Kong ... Seasonal Variations of Bromophenols in Brown Algae (Padina arborescens, Sargassum siliquastrum, and Lobophora variegata) Collected in Hong Kong ...

Richard E. Moore

1977-02-01T23:59:59.000Z

406

Electrochemical continuous decomposition of chloroform and other volatile chlorinated hydrocarbons in water using a column type metal impregnated carbon fiber electrode  

SciTech Connect (OSTI)

Trihalomethane and other chlorinated hydrocarbons are known to be toxic to human health. However, removal of these compounds from water is not easy. The authors attempted continuous electrochemical decomposition of chloroform that is the main compound of trihalomethanes and some toxic chlorinated hydrocarbons in water using a metal-impregnated CFE, concentration of chloroform in 0.5 M K{sub 2}SO{sub 4} (the supporting electrolyte) solution was decreased from 0.23m mol/L to below the limit of detection of their analysis system (1 ppm) at a flow rate of 1 mL/min. The main product of electrolysis was methane. This high efficiency, determined by the chemical yield, hardly changed at a flow rate of 20 mL/min at a Ag-impregnated CFE. At a flow rate of 1 mL/min, chloroform was degraded with a decomposition efficiency of almost 100% even in the solution without the supporting electrolyte, whereas at a higher flow rate, the efficiency for the decomposition of chloroform decreased with a decrease in the concentration of the supporting electrolyte. Tetrachloroethylene, 1,1,1-trichloroethane, and 1,1,2-trichloroethane were also decomposed at a Ag-impregnated CFE with an efficiency of almost 100%.

Sonoyama, Noriyuki; Sakata, Tadayoshi

1999-10-01T23:59:59.000Z

407

Hydrocarbon and non-hydrocarbon gas in salt environments, a contribution to gas genesis understanding  

SciTech Connect (OSTI)

The analysis of organic inclusions is a contribution to the understanding of the thermal and biochemical history of the evaporite basins by the in-situ observation of organic evolution products which are preserved by entrapment in salt. Recent applications of microanalytical techniques (FT-infrared, Raman, FT-Raman, UV-fluorescence) have confirmed and elucidated the nature of the organic phases trapped in inclusions. Three geological environments were studied corresponding to different levels of organic maturation: (1) the Bresse salt deposit (France) where the presence of solid organic matter, immature oil, carbon dioxide, and ammonium is detected, is characteristic of the early diagenesis of the massive salt series deposited at the Eocene-Oligocene period in the West European continental rift, (2) the Gabon margin where oil, methane, carbon dioxide and ammonium correspond to catagenetic products trapped in a salt diapir of the Cretaceous salt series of the Ogooue delta, and (3) the Lena-Tungusska oil-bearing region of Siberian platform where graphite, carbonaceous material, sulphur, carbon dioxide, methane, nitrogen, and oils correspond to the evolution of the evaporite-brine-organic matter system under influence of basalt intrusions. The organic history of salt rocks can be followed from Bresse to Siberian examples. Proteins and carbohydrates are rapidly destroyed during early diagenesis (Bresse-France): ammonium and carbon dioxide are produced by deamination and decarboxylation respectively, the complex organic molecular association is simplified and geopolymers (kerogen precursors) are produced. With increasing maturity (Gabon), kerogen is transformed in aliphatic compounds which are progressively cracked to produce short alkane chains and finally methane. Residual carbon dioxide is also produced. In Siberia, the organic matter evolution is linked to the d/h ratio, where d is the distance to the dolerite sill and h the thickness of the sill.

Pironon, J. [BP, Vandoeuvre-les-Nancy (France); Grishina, S. [United Institute of geology, Novosibirsk (Russian Federation)

1995-08-01T23:59:59.000Z

408

Mach 2 combustion characteristics of hydrogen/hydrocarbon fuel mixtures  

SciTech Connect (OSTI)

The combustion of H/sub 2//CH/sub 4/ and H/sub 2//C/sub 2/H/sub 4/ mixtures containing 10 to 70 vol pct hydrocarbon at combustor inlet Mach number 2 and temperatures 2000 to 4000 R is investigated experimentally, applying direct-connect test hardware and techniques similar to those described by Diskin and Northam (1987) in the facilities of the NASA Langley Hypersonic Propulsion Branch. The experimental setup, procedures, and data-reduction methods are described; and the results are presented in extensive tables and graphs and characterized in detail. Fuel type and mixture are found to have little effect on the wall heating rate measured near the combustor exit, but H/sub 2//C/sub 2/H/sub 4/ is shown to burn much more efficiently than H/sub 2//CH/sub 4/, with no pilot-off blowout equivalence ratios greater than 0.5. It is suggested that H/sub 2//hydrocarbon mixtures are feasible fuels (at least in terms of combustion efficiency) for scramjet SSTO vehicles operating at freestream Mach numbers above 4.

Diskin, G.S.; Jachimowski, C.J.; Northam, G.B.; Bell, R.A.

1987-01-01T23:59:59.000Z

409

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

1996-01-01T23:59:59.000Z

410

Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars  

SciTech Connect (OSTI)

Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

2014-05-18T23:59:59.000Z

411

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

Ruka, R.J.; Basel, R.A.

1996-03-12T23:59:59.000Z

412

Distillation sequence for the purification and recovery of hydrocarbons  

DOE Patents [OSTI]

This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

2007-12-25T23:59:59.000Z

413

Mutual solubilities of water and hydrocarbons from the Cubic plus Association equation of state: A new mixing rule for the correlation of observed minimum hydrocarbon solubilities  

Science Journals Connector (OSTI)

Abstract The cubic plus association (CPA) equation of state was employed to correlate the mutual solubilities of water and hydrocarbons (n-alkanes, cycloalkanes and aromatics). In order to reproduce the minimums observed in concentration vs. temperature curves, a new mixing rule is proposed based on Kabadi and Danner's idea, whereby the waterwater dispersive term is corrected to include the hydrophobic hydration effect. With this correction, correlated hydrocarbon solubilities curves have observable curvature at low temperatures. Two binary interaction parameters are required for saturated hydrocarbons and three for aromatics, which is just one more than the original CPA formulation. Using parameters determined from binary data, this improved mixing rule was employed for multicomponent waterhydrocarbon systems, with no further regression, producing better predictions when compared to the conventional van der Waals rules.

Milton Medeiros

2014-01-01T23:59:59.000Z

414

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.

1989-07-18T23:59:59.000Z

415

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Houston, TX)

1989-01-01T23:59:59.000Z

416

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1994-01-01T23:59:59.000Z

417

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-09-07T23:59:59.000Z

418

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1994-06-14T23:59:59.000Z

419

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

420

Desiccant bed on hydrocarbon charged to and removed from underground (salt) cavern  

SciTech Connect (OSTI)

A hydrocarbon fluid storage system is described which consists of in operable conjunction: a cavern formed within an underground salt strata below a ground surface, the cavern comprises a lower liquid volume of saturated sodium chloride storage brine and an upper fluid volume of wet hydrocarbon storage fluid, surface fluid handling means; conduit connecting the lower storage brine and upper storage hydrocarbon fluid with the surface fluid handling means, of fluid transfer means enabling transfer of brine and hydrocarbon fluid from the surface to the cavern and from the cavern to the surface, such that brine can be added to or withdrawn from the lower brine volume and hydrocarbon fluids can be added to or withdrawn from the upper hydrocarbon fluid volume, and at least one desiccant drier means positioned at the surface in operable association with the surface fluid handling means whereby the wet hydrocarbon fluid upon withdrawal from the cavern passes through the desiccant drier means and thereby becomes dry, and dry hydrocarbon fluid intended for storage passes through the desiccant drier prior to entering the storage cavern and thereby becomes wet.

Washer, S.P.

1986-06-03T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Adsorption and Desorption of Hydrocarbons on a Supported Nickel Cracking Catalyst  

Science Journals Connector (OSTI)

...Hydrocarbons on a Supported Nickel Cracking Catalyst A. K. Galwey A study has been made...a high area supported nickel cracking catalyst. Measurements have been made of (i...adsorbed, after standard preparation of the catalyst, when a known volume of each hydrocarbon...

1963-01-01T23:59:59.000Z

422

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing  

E-Print Network [OSTI]

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section hydrocarbons in surface sediment from the Coal Oil Point seep field, offshore Santa4 Barbara, California. After

Sessions, Alex L.

423

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California  

E-Print Network [OSTI]

area) are not well established, either globally or within strong source areas such as near Coal OilThe spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil hydrocarbon seepage from marine environments is an important source of methane and other gases

Washburn, Libe

424

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon fraction in terms...by the incomplete combustion of organic material...sediments (1), heat and power generation...PAH from fuel combustion found in the atmosphere...polycyclic aromatic hydrocarbons; PMS, postmitochondrial...amounts of mutation (data not presented...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

425

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus heteroclitus)  

E-Print Network [OSTI]

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus aromatic hydrocarbons (HAHs) such as 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) as well as polynuclear and that the frequencies of the major allele types differ between dioxin- sensitive and dioxin-resistant populations

Hahn, Mark E.

426

Assessment of natural and anthropogenic hydrocarbon inputs using PAHs as tracers.  

E-Print Network [OSTI]

to produce liquid hydrocarbons and water. -- Coal-to-liquids (CTLs) are derived either by pyrolysis of coal authors accept that conventional oil resources are at an advanced stage of depletion and that liquid fuels is a heterogeneous mix of hydrocarbons that remain in liquid phase when extracted to the surface. -- Condensate

427

QSPR models of boiling point, octanolwater partition coefficient and retention time index of polycyclic aromatic hydrocarbons  

E-Print Network [OSTI]

QSPR models of boiling point, octanol­water partition coefficient and retention time index of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro, Ma´rcia Miguel Castro Ferreira* Laborato Structure­Property Relationship (QSPR) analysis and study of polycyclic aromatic hydrocarbons (PAHs

Ferreira, Márcia M. C.

428

NEW MARINE DECAPOD CRUSTACEANS FROM WATERS INFLUENCED BY HYDROmERMAL DISCHARGE, BRINE, AND HYDROCARBON SEEPAGE  

E-Print Network [OSTI]

and waters influenced by brine and hydrocarbon seeps continue to yield species new to science. Such enNEW MARINE DECAPOD CRUSTACEANS FROM WATERS INFLUENCED BY HYDROmERMAL DISCHARGE, BRINE, AND HYDROCARBON SEEPAGE AUSTIN B. WILLIAMS} ABSTRACT Five species of decapod crustaceans new to science

429

Polycyclic aromatic hydrocarbons: a QSPR study Marcia M.C. Ferreira  

E-Print Network [OSTI]

Polycyclic aromatic hydrocarbons: a QSPR study Marcia M.C. Ferreira UNICAMP Instituto de Quõmica studies such as the boiling temperature (Tb), the retention index (RI), n-octanol/water partition coecient; Chemometrics 1. Introduction The polycyclic aromatic hydrocarbons (PAH) have been, for a long time, a focus

Ferreira, Márcia M. C.

430

PARTICLE-ASSOCIATED POLYCYCLIC AROMATIC HYDROCARBONS IN THE ATMOSPHERE OF HONG KONG  

E-Print Network [OSTI]

PARTICLE-ASSOCIATED POLYCYCLIC AROMATIC HYDROCARBONS IN THE ATMOSPHERE OF HONG KONG M. ZHENG and M Technology, Clear Water Bay, Hong Kong, China ( present address: Graduate School of Oceanography, University@ust.hk) (Received 3 June 1998; accepted 22 December 1998) Abstract. Polycyclic aromatic hydrocarbons (PAHs) in total

Zheng, Mei

431

Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: W. Scott Phillips  

E-Print Network [OSTI]

Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: A Review W. Scott or production of fluids can induce microseismic events in hydrocarbon and geothermal reservoirs. By deploying sensors downhole, data sets have been collected that consist of a few hundred to well over 10,000 induced

432

Evolution of Titan and implications for its hydrocarbon cycle  

Science Journals Connector (OSTI)

...TK), in which gas molecules have very low solubility, and so potentially very large amounts of gas compounds, notably...ammonia has a high solubility in water, so that most of...then converted into nitrogen. Most of the methane...

2009-01-01T23:59:59.000Z

433

Methods for Determination of Hydrocarbons in Air, Soil & Water  

Science Journals Connector (OSTI)

Many environmental investigations often demand a quick indication of the nature and levels of contamination in air, soil and water. A portable GC for on-site monitoring allows the user to fast screen compounds in...

Hans Ole Andersen

1997-01-01T23:59:59.000Z

434

Biological Monitoring of Fire Fighters: Sister Chromatid Exchange and Polycyclic Aromatic Hydrocarbon-DNA Adducts in Peripheral Blood Cells  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon-DNA adduct levels...exposure to carcinogenic combustion products. Cytoge...polycyclic aromatic hydrocarbon; CI, confidence interval...estimating exposures to combustion and pyrolysis products...into water, briefly heat denatured (100 Cfor...

Saou-Hsing Liou; David Jacobson-Kram; Miriam C. Poirier; Dung Nguyen; Paul T. Strickland; and Melvyn S. Tockman

1989-09-01T23:59:59.000Z

435

Biological Monitoring of Fire Fighters: Sister Chromatid Exchange and Polycyclic Aromatic Hydrocarbon-DNA Adducts in Peripheral Blood Cells  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon-DNA adduct levels...to carcinogenic combustion products. Cytoge...polycyclic aromatic hydrocarbon; CI, confidence...controlled for during data analysis. Collection...estimating exposures to combustion and pyrolysis products...water, briefly heat denatured (100...

Saou-Hsing Liou; David Jacobson-Kram; Miriam C. Poirier; Dung Nguyen; Paul T. Strickland; and Melvyn S. Tockman

1989-09-01T23:59:59.000Z

436

Levels of Tobacco-Specific Nitrosamines and Polycyclic Aromatic Hydrocarbons in Mainstream Smoke from Different Tobacco Varieties  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mainstream cigarette...21 U.S. EPA. Ambient Water Quality Criteria for Polynuclear Aromatic Hydrocarbons. EPA 440/5-80-069...Quality Criteria for Water; EPA 440/5-86-001...

Yan S. Ding; Liqin Zhang; Ram B. Jain; Ntasha Jain; Richard Y. Wang; David L. Ashley; and Clifford H. Watson

2008-12-01T23:59:59.000Z

437

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

438

Time sequenced heating of multiple layers in a hydrocarbon containing formation  

DOE Patents [OSTI]

A method for treating a hydrocarbon containing formation may include providing heat to a first hydrocarbon layer in the formation from a first heater located in an opening in the formation. The opening and the first heater may have a horizontal or inclined portion located in the first hydrocarbon layer and at least one connecting portion extending between the horizontal or inclined portion and the surface. Isolation material is placed in the opening such that the isolation material partially isolates the layer in which the horizontal or inclined portion of the first heater is located. An additional horizontal or inclined opening portion that extends from at least one of the connecting portions of the opening is formed in a second hydrocarbon layer. A second heater to provide heat the second hydrocarbon formation is placed in the additional substantially horizontal opening portion.

Goldberg, Bernard (Houston, TX); Hale, Arthur Herman (Houston, TX); Miller, David Scott (Katy, TX); Vinegar, Harold J. (Bellaire, TX)

2009-12-22T23:59:59.000Z

439

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

440

Kinetic Studies on the Hydrogen Peroxide-Enhanced In Situ Biodegradation of Hydrocarbons in Water-Saturated Ground Zone  

Science Journals Connector (OSTI)

Techniques are rapidly developing for aerobic biodegradation of hydrocarbons in lower water-bearing formations. It is well known that...

Dr. E. R. Barenschee; Dr. O. Helmling; S. Dahmer; B. Del Grosso

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Role of crude-oil components in surfactant interaction. [Effect of acids, bases and heavy ends hydrocarbons (alkanes) on the solubilization, optimal salinity and interfacial tension of surfactant systems  

SciTech Connect (OSTI)

Three crude oils from Bell Creek, Bradford, and Delaware-Childers fields were separated into distillates, acids, bases and heavy ends hydrocarbon. The effect of these components on the solubilization, optimal salinity, and bases shifted the optimal salinity significantly; their effects on the solubilization and interfacial tension are smaller. The bases appear to interact with the sulfonates, causing desorption from the interface, phase separation, and higher interfacial tension. The hydrocarbons, as expected have the strongest influence on the properties studied, due to their high concentration. The importance of the chemical nature and molecular weights of these components was also apparent. Even though the product sigma*/sup 2/..gamma.. is not constant, it was found that there is a definite relation between the solubilization (sigma*) and the interfacial tension (..gamma..). This is true even for such complex compounds as acids and bases. 41 references, 6 figures, 14 tables.

Tham, M.K.; Lorenz, P.B.

1983-09-01T23:59:59.000Z

442

One-Step Production of Superhydrophobic Coatings on Flat Substrates via Atmospheric Rf Plasma Process Using Non-Fluorinated Hydrocarbons  

Science Journals Connector (OSTI)

One-Step Production of Superhydrophobic Coatings on Flat Substrates via Atmospheric Rf Plasma Process Using Non-Fluorinated Hydrocarbons ... This paper describes the direct deposition of hydrocarbon coatings with a static water contact angle higher than 150 using simple C6 hydrocarbons as a reactive gas in helium plasma generated in ambient air without any preroughening of the silicon (100) substrate. ...

Seul Hee Lee; Zachary R. Dilworth; Erik Hsiao; Anna L. Barnette; Matthew Marino; Jeong Hoon Kim; Jung-Gu Kang; Tae-Hwan Jung; Seong H. Kim

2011-01-31T23:59:59.000Z

443

Identification of Novel Methane-, Ethane-, and Propane-Oxidizing Bacteria at Marine Hydrocarbon Seeps by Stable Isotope Probing  

Science Journals Connector (OSTI)

...detector. When the hydrocarbon gas had nearly been...additional 5 ml of hydrocarbon gas was added. Oxygen...second 5-ml aliquot of hydrocarbon had been consumed...splitless injector, a GC combustion III interface, and...at 37C, followed by heat inactivation for 20...

Molly C. Redmond; David L. Valentine; Alex L. Sessions

2010-07-30T23:59:59.000Z

444

Activated carbon and biochar amendments decrease pore-water concentrations of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge  

E-Print Network [OSTI]

hydrocarbons (PAHs) in sewage sludge Patryk Oleszczuk a,b, , Sarah E. Hale a , Johannes Lehmann c , Gerard Polycyclic aromatic hydrocarbons Bioavailability Sewage sludge a b s t r a c t The aim of the research of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge. Two different biochars (MSB and PMW) and two ACs

Lehmann, Johannes

445

Polycyclic Aromatic Hydrocarbons in C8 Isomer Aromatic Feed: Analysis by GC, GC/MS, and GC/FTIR Techniques  

Science Journals Connector (OSTI)

......the concentrated hydrocarbon residue of C 8...Polycyclic aromatic hydrocarbons (PAHs) are recognized...fossil fuels, combustion products, and...monocyclic aro matic hydrocarbons like benzene or...feed-effluent heat exchangers (16...and a Shimadzu data pro cessor (C-R......

V.N. Garg; B.D. Bhatt; V.K. Kaushik; K.R. Murthy

1987-06-01T23:59:59.000Z

446

Molecular Dynamics Simulations of End-to-End Contact Formation in Hydrocarbon Chains in Water and Aqueous Urea  

E-Print Network [OSTI]

Molecular Dynamics Simulations of End-to-End Contact Formation in Hydrocarbon Chains in Water is to probe contact formation between two ends of model hydrocarbon chains in water and 6 M aqueous urea "folding" event, namely, the formation of end-to-end contact in the linear hydrocarbon chain (HC) CH3(CH2

Thirumalai, Devarajan

447

Hyperpolarizable compounds and devices fabricated therefrom  

DOE Patents [OSTI]

Substituted compounds having relatively large molecular first order hyperpolarizabilities are provided, along with devices and materials containing them. In general, the compounds bear electron-donating and electron-withdrawing chemical substituents on a polyheterocyclic core. 13 figs.

Therien, M.J.; DiMagno, S.G.

1998-07-21T23:59:59.000Z

448

Experimental measurements of the diffusion parameters of light hydrocarbons in water-saturated sedimentary rocks: II. Results and geochemical significance  

SciTech Connect (OSTI)

Diffusion parameters (diffusion coefficient, diffusion permeability, solubility coefficient) for methane, ethane, propane, n-butane, methylpropane and 2,2-dimethylpropane were measured on 21 samples of water-saturated sedimentary rocks at different temperatures (30, 50, and 70 C). The rock samples include sandstones, siltstones, and claystones with porosities ranging from 0.4 to 16.5% and permeabilities from <0.005 to 33.4 millidarcy. Experimental diffusion coefficients ranged from c. 6 {times} 10{sup {minus}10} to 9 {times} 10{sup {minus}13} m{sup 2}/s, solubility coefficients covered a range from c. 5 {times} 10{sup {minus}1} to 5 {times} 10{sup {minus}4}, and diffusion permeabilities lay between c. 4 {times} 10{sup {minus}12} and 1 {times} 10{sup {minus}14} m{sup 2}/s. Diffusion coefficients decrease with increasing molecular weight of the hydrocarbon compound, the decrease depending on the petrophysical properties and the mineralogy of the rocks and being most drastic in shales. None of the petrophysical parameters examined in this study (porosity, permeability, formation resistivity factor) gave a good correlation with the nonsteady-state diffusion coefficient, D. An excellent correlation was found between the formation resistivity factor, F, and the steady-state diffusion permeability. P. A possibly useful-though less significant-relation bearing some resemblance with Archie's law appears to exist between the porosity and the diffusion permeability. The temperature dependence of the diffusion parameters was determined on two calcareous sandstones. Based on an activated diffusion model activation energies for the diffusion process ranging around 50 kJ/mol were calculated for all hydrocarbons examined.

Krooss, B.M.; Leythaeuser, D. (Institute of petroleum and Organic Geochemistry, Juelich (Germany, F.R.))

1988-01-01T23:59:59.000Z

449

Atmospheric distribution of polycyclic aromatic hydrocarbons and deposition to Galveston Bay, Texas, USA  

Science Journals Connector (OSTI)

Estimates of the atmospheric deposition to Galveston Bay of polycyclic aromatic hydrocarbons (PAHs) are made using precipitation and meteorological data that were collected continuously from 2 February 1995 to 6 August 1996 at Seabrook, TX, USA. Particulate and vapor phase \\{PAHs\\} in ambient air and particulate and dissolved phases in rain samples were collected and analyzed. More than 95% of atmospheric \\{PAHs\\} were in the vapor phase and about 73% of \\{PAHs\\} in the rain were in the dissolved phase. Phenanthrene and napthalene were the dominant compounds in air vapor and rain dissolved phases, respectively, while 5 and 6 ring PAH were predominant in the particulate phase of both air and rain samples. Total PAH concentrations ranged from 4 to 161ngm?3 in air samples and from 50 to 312ngl?1 in rain samples. Temporal variability in total PAH air concentrations were observed, with lower concentrations in the spring and fall (434ngm?3) compared to the summer and winter (37161ngm?3). \\{PAHs\\} in the air near Galveston Bay are derived from both combustion and petroleum vaporization. Gas exchange from the atmosphere to the surface water is estimated to be the major deposition process for \\{PAHs\\} (1211?gm? 2yr? 1), relative to wet deposition (130?gm?2yr? 1) and dry deposition (99?gm?2yr? 1). Annual deposition of \\{PAHs\\} directly to Galveston Bay from the atmosphere is estimated as 2 tyr?1.

June-Soo Park; Terry L. Wade; Stephen Sweet

2001-01-01T23:59:59.000Z

450

Solution mining systems and methods for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A method for treating an oil shale formation comprising nahcolite is disclosed. The method includes providing a first fluid to a portion of the formation through at least two injection wells. A second fluid is produced from the portion through at least one injection well until at least two injection wells are interconnected such that fluid can flow between the two injection wells. The second fluid includes at least some nahcolite dissolved in the first fluid. The first fluid is injected through one of the interconnected injection wells. The second fluid is produced from at least one of the interconnected injection wells. Heat is provided from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation.

Vinegar, Harold J. (Bellaire, TX); de Rouffignac, Eric Pierre (Rijswijk, NL); Schoeling, Lanny Gene (Katy, TX)

2009-07-14T23:59:59.000Z

451

Chapter 4 - Physical Properties of Hydrocarbons and Petrochemicals  

Science Journals Connector (OSTI)

Abstract A brief description of the most common hydrocarbons and chemicals used in the process industries is provided, starting from the simplest to the more complex. Additionally, several tables are provided that identify the molecular compositions and typical fire hazards (flash points, flammability limits, autoignition temperatures) of these common materials. The specific fire hazard terms are explained in further detail for better understanding of the risks involved with processing and handling of the materials. An autoignition temperature approximation method is also provided for use where a mixture of material may be present. Physical properties that may influence the severity of an incident from these materials are mentioned and described, which includes vapor density, vapor pressure, and specific gravity.

Dennis P. Nolan

2014-01-01T23:59:59.000Z

452

Method and apparatus for hydrocarbon recovery from tar sands  

DOE Patents [OSTI]

A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

Westhoff, J.D.; Harak, A.E.

1988-05-04T23:59:59.000Z

453

Method and apparatus for hydrocarbon recovery from tar sands  

DOE Patents [OSTI]

A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

Westhoff, James D. (Laramie, WY); Harak, Arnold E. (Laramie, WY)

1989-01-01T23:59:59.000Z

454

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

455

Heating hydrocarbon containing formations in a spiral startup staged sequence  

DOE Patents [OSTI]

Methods for treating a hydrocarbon containing formation are described herein. Methods may include treating a first zone of the formation. Treatment of a plurality of zones of the formation may be begun at selected times after the treatment of the first zone begins. The treatment of at least two successively treated zones may begin at a selected time after treatment of the previous zone begins. At least two of the successively treated zones may be adjacent to the zone treated previously. The successive treatment of the zones proceeds in an outward, substantially spiral sequence from the first zone so that the treatment of the zones may move substantially spirally outwards towards a boundary of the treatment area.

Vinegar, Harold J. (Bellaire, TX); Miller, David Scott (Katy, TX)

2009-12-15T23:59:59.000Z

456

Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues  

Reports and Publications (EIA)

Over the past five years, rapid growth in U.S. onshore natural gas and oil production has led to increased volumes of natural gas plant liquids (NGPL) and liquefied refinery gases (LRG). The increasing economic importance of these volumes, as a result of their significant growth in production, has revealed the need for better data accuracy and transparency to improve the quality of historical data and projections for supply, demand, and prices of these liquids, co-products, and competing products. To reduce confusion in terminology and improve its presentation of data, EIA has worked with industry and federal and state governments to clarify gas liquid terminology and has developed the term Hydrocarbon Gas Liquids, or HGL.

2014-01-01T23:59:59.000Z

457

Thermodynamic properties of hydrocarbon liquids at high pressures and temperatures  

SciTech Connect (OSTI)

Understanding the organic/inorganic interface in the Earth's crust requires values of the thermodynamic properties of hydrocarbon species in crude oil, coal, and natural gas at elevated temperatures and pressures. Values of the apparent standard partial molal Gibbs free energies and enthalpies of formation and the standard partial molal entropies and heat capacities of these organic species can be computed as a function of temperature at 1 bar using the equations of state adopted by Helgeson et al (1991). The pressure dependence of the thermodynamic properties can be calculated from a modified version of the Parameters From Group Contributions (PFGC) equation of state. To improve the accuracy of these predictions, critical evaluation of high-pressure density experiments reported in the literature was used in the present study to characterize b[sub j] as a function of pressure and temperature. The revised PFGC equation of state permits accurate calculation of the standard partial molal volumes of the major hydrocarbon species in the aliphatic, aromatic, and naphthenic fractions of crude oil, as well as fatty acids, phenols, and naphthenic acids at temperatures and pressures to 500 C and 5 kbar. Combining the revised PFGC equation of state and parameters with the standard partial molal properties of these species at one bar and those of aqueous species and minerals permits calculation of the apparent standard partial molal Gibbs Free energies of reaction, and thus equilibrium constants for a wide variety of chemical equilibria among organic liquids, solids, and gases, aqueous species, and minerals at temperatures and pressures characteristic of both diagenetic and low-grade metamorphic processes in the Earth's crust.

Aagaard, P. (Univ. of Oslo (Norway). Dept. of Geology); Oelkers, E.H. (Univ. Paul Sabatier, Toulouse (France). Lab. de Geochimie); Helgeson, H.C. (Univ. of California, Berkeley, CA (United States). Dept. of Geology and Geophysics)

1992-01-01T23:59:59.000Z

458

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

SciTech Connect (OSTI)

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

459

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting  

SciTech Connect (OSTI)

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

2011-03-15T23:59:59.000Z

460

Observations of the Release of Non-methane Hydrocarbons from Fractured Shale  

Science Journals Connector (OSTI)

The organic content of shale has become of commercial interest as a source of hydrocarbons, owing to the development of hydraulic fracturing (fracking). ... These findings suggest that other hydrocarbons of commercial interest may be extracted from shale and open the possibility to optimize the fracking process, improving gas yields and reducing environmental impacts. ... This technique, termed hydraulic fracturing (commonly known as fracking), consists of drilling a well in the prospective shale units and injecting water under high pressure mixed with sand (?5%) and chemical additives (?0.2%) to fracture the rock and stimulate the release of hydrocarbons. ...

Roberto Sommariva; Robert S. Blake; Robert J. Cuss; Rebecca L. Cordell; Jon F. Harrington; Iain R. White; Paul S. Monks

2014-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Method for silicon carbide production by reacting silica with hydrocarbon gas  

DOE Patents [OSTI]

A method is described for producing silicon carbide particles using a silicon source material and a hydrocarbon. The method is efficient and is characterized by high yield. Finely divided silicon source material is contacted with hydrocarbon at a temperature of 400.degree. C. to 1000.degree. C. where the hydrocarbon pyrolyzes and coats the particles with carbon. The particles are then heated to 1100.degree. C. to 1600.degree. C. to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process.

Glatzmaier, Gregory C. (Boulder, CO)

1994-01-01T23:59:59.000Z

462

Method of treating emissions of a hybrid vehicle with a hydrocarbon absorber and a catalyst bypass system  

DOE Patents [OSTI]

A method of treating emissions from an internal combustion engine of a hybrid vehicle includes directing a flow of air created by the internal combustion engine when the internal combustion engine is spinning but not being fueled through a hydrocarbon absorber to collect hydrocarbons within the flow of air. When the hydrocarbon absorber is full and unable to collect additional hydrocarbons, the flow of air is directed through an electrically heated catalyst to treat the flow of air and remove the hydrocarbons. When the hydrocarbon absorber is not full and able to collect additional hydrocarbons, the flow of air is directed through a bypass path that bypasses the electrically heated catalyst to conserve the thermal energy stored within the electrically heated catalyst.

Roos, Bryan Nathaniel; Gonze, Eugene V; Santoso, Halim G; Spohn, Brian L

2014-01-14T23:59:59.000Z

463

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

464

Volatile organic compound sensing devices  

DOE Patents [OSTI]

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

Lancaster, Gregory D. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID); Reagen, William K. (Stillwater, MN)

1995-01-01T23:59:59.000Z

465

Volatile organic compound sensing devices  

DOE Patents [OSTI]

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

1995-08-29T23:59:59.000Z

466

Development of a Fundamental Understanding of Chemical Bonding and Electronic Structure in Spinel Compounds  

SciTech Connect (OSTI)

This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos national Laboratory (LANL). Hundreds of ceramic compounds possess the spinel crystal structure and exhibit a remarkable variety of properties, ranging from compounds that are electrical insulators to compounds that are superconducting, or from compounds with ferri- and antiferromagnetic behavior to materials with colossal magnetoresistive characteristics. The unique crystal structure of spinel compounds is in many ways responsible for the widely varying physical properties of spinels. The objective of this project is to investigate the nature of chemical bonding, point defects, and electronic structure in compounds with the spinel crystal structure. Our goal is to understand and predict the stability of the spinel structure as a function of chemical composition, stoichiometry, and cation disorder. The consequences of cation disorder in spinel materials can be profound . The ferromagnetic characteristics of magnesioferrite, for instance, are entirely attributable to disorder on the cation sublattices. Our studies provide insight into the mechanisms of point defect formation and cation disorder and their effects on the electronic band structure and crystal structure of spinel-structure materials. our ultimate objective is to develop a more substantive knowledge of the spinel crystal structure and to promote new and novel uses for spinel compounds. The technical approach to achieve our goals is to combine first-principles calculations with experimental measurements. The structural and electronic properties of spinel samples were experimentally determined primarily with X-ray and neutron scattering, optical and X-ray absorption, and electron energy-loss spectroscopy. Total energy electronic structure calculations were performed to determine structural stability, band structure, density of states, and electron distribution. We also used shell-model total -energy calculations to assess point-defect formation and migration energies in magnesio-aluminate spinel.

Sickafus, K.E.; Wills, J.M.; Chen, S.-P.; Terry, J.H., Jr.; Hartmann, T.; Sheldon, R.I.

1999-05-14T23:59:59.000Z

467

Laboratory testing and modeling to evaluate perfluorocarbon compounds as tracers in geothermal systems  

SciTech Connect (OSTI)

The thermal stability and adsorption characteristics of three perfluorinated hydrocarbon compounds were evaluated under geothermal conditions to determine the potential to use these compounds as conservative or thermally-degrading tracers in Engineered (or Enhanced) Geothermal Systems (EGS). The three compounds tested were perfluorodimethyl-cyclobutane (PDCB), perfluoromethylcyclohexane (PMCH), and perfluorotrimethylcyclohexane (PTCH), which are collectively referred to as perfluorinated tracers, or PFTs. Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second pair was charged with the brine-PFT mixture plus a mineral assemblage chosen to be representative of activated fractures in an EGS reservoir. A fifth reactor was charged with deionized water containing the three PFTs. The experiments were conducted at {approx}100 bar, with temperatures ranging from 230 C to 300 C. Semi-analytical and numerical modeling was also conducted to show how the PFTs could be used in conjunction with other tracers to interrogate surface area to volume ratios and temperature profiles in EGS reservoirs. Both single-well and cross-hole tracer tests are simulated to illustrate how different suites of tracers could be used to accomplish these objectives. The single-well tests are especially attractive for EGS applications because they allow the effectiveness of a stimulation to be evaluated without drilling a second well.

Reimus, Paul W [Los Alamos National Laboratory

2011-01-21T23:59:59.000Z

468

Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion  

Broader source: Energy.gov [DOE]

Analyzed the effects of higher hydrocarbon emissions from PCCI combustion on SCR catalysts in operating a light-duty 1.9-liter GM diesel engine in both PCCI and conventional combustion modes

469

Thermally Coupled Catalytic Reactor for Steam Reforming of Methane and Liquid Hydrocarbons: Experiment and Mathematical Modeling  

Science Journals Connector (OSTI)

An energy-efficient catalytic reactor for producing synthesis gas from methane and liquid hydrocarbons is proposed that is ... on the coupling of an endothermic reaction (steam reforming of methane, hexane, or is...

V. A. Kirillov; N. A. Kuzin; A. V. Kulikov

2003-05-01T23:59:59.000Z

470

Active Hydrocarbon Biosynthesis and Accumulation in a Green Alga, Botryococcus braunii (Race A)  

Science Journals Connector (OSTI)

...Energy's Aquatic Species Program: biodiesel from algae.National Renewable Energy Laboratory...botryococcenes-hydrocarbons of novel structure from the alga Botryococcus braunii Kutzing. Phytochemistry...physiological state in the green alga Botryococcus braunii. Phytochemistry...

Mana Hirose; Fukiko Mukaida; Sigeru Okada; Tetsuko Noguchi

2013-06-21T23:59:59.000Z

471

SYNTHESIS OF HYDROCARBON STANDARDS Tetrahydrofuran (THF) was distilled from sodium/benzophenone under argon  

E-Print Network [OSTI]

SYNTHESIS OF HYDROCARBON STANDARDS Tetrahydrofuran (THF) was distilled from sodium Synthesis (Pelham, NH, USA). Other phosphonium salts were synthesized as follows. A solution, USA). Synthesis of Straight-chain Z-alkenes. Aldehydes needed for Wittig reactions that were

Hanks, Lawrence M.

472

Magnetic signature of hydrocarbon-contaminated soils and sediments at the former oil field Hnigsen, Germany  

Science Journals Connector (OSTI)

Magnetic properties of hydrocarbon (HC) containing soils and sediments from two sites (Site A and B) of the former oil-field Hnigsen were analyzed in order to determine whether magnetic methods can be employe...

Moti L. Rijal; Katharina Porsch; Erwin Appel

2012-07-01T23:59:59.000Z

473

Characteristics of naphthenic and paraffinic hydrocarbons of residual oil from West Siberian crudes  

SciTech Connect (OSTI)

This article examines the naphthenic/paraffinic hydrocarbons segregated by liquid chromatography from a residual oil after removal of the resins and solid hydrocarbons. The studied hydrocarbons were fractionated on the basis of molecular weight (by molecular distillation) and on the basis of the content of rings (by thermal diffusion separation in a laboratory column). The results of mass-spectrometric analysis indicate that the first fraction consists mainly of isoparaffins and naphthenes with few rings. The polycyclic condensed naphthenes are concentrated in the last fraction. The content of isoparaffins drops off and the content of condensed polycyclic naphthenic structures increases from the second fraction to the next to the last. It is concluded that the naphthenic/paraffinic hydrocarbons of the residual oil from mixed West Siberian crudes have a relatively narrow composition and therefore have similar physicochemical properties.

Detusheva, E.P.; Khramtsova, L.P.; Muchinskii, T.D.; Shkol'nikov, V.M.

1984-05-01T23:59:59.000Z

474

Spectral Decomposition Using S-transform for Hydrocarbon Detection and Filtering  

E-Print Network [OSTI]

Spectral decomposition is a modern tool that utilizes seismic data to generate additional useful information in seismic exploration for hydrocarbon detection, lithology identification, stratigraphic interpretation, filtering and others. Different...

Zhang, Zhao

2012-10-19T23:59:59.000Z

475

Selectivity Enhancement for Petroleum Hydrocarbons Using a Smectic Liquid Crystalline Stationary Phase in Supercritical Fluid Chromatography  

Science Journals Connector (OSTI)

......Lee* Department of Chemistry, Brigham Young University...Bartle. Analytical Chemistry of Polycyclic Aromatic...Physical and Biological Chemistry. M. Cooke, A.J...hydrocarbon isomers in coal tars and combustion products. Environ......

H-C.K. Chang; K.E. Markides; J.S. Bradshaw; M.L. Lee

1988-06-01T23:59:59.000Z

476

Modeling of heat and mass transfer in a hydrocarbon fluid under inductive heating  

Science Journals Connector (OSTI)

Results of numerical simulations of the thermal action on a high-viscosity hydrocarbon fluid with temperature-dependent viscosity and thermal conductivity are presented. A system of equations of thermal convec...

L. A. Kovaleva; V. N. Kireev; A. A. Musin

2009-01-01T23:59:59.000Z

477

Reductive dechlorination of chlorinated aliphatic hydrocarbons by Fe(ii) in degradative solidification/stabilization  

E-Print Network [OSTI]

This dissertation examines the applicability of the iron-based degradative solidification/stabilization (DS/S-Fe(II)) to various chlorinated aliphatic hydrocarbons (CAHs) that are common chemicals of concern at contaminated sites. The research...

Jung, Bahng Mi

2007-04-25T23:59:59.000Z

478

The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst  

Broader source: Energy.gov [DOE]

Study of effects of hydrocarbons on ammonia storage and NOx reduction over a commercial Fe-zeolite SCR catalyst to understand catalyst behaviors at low temperatures and improve NOx reduction performance and reduce system cost

479

Complex conductivity tensor of anisotropic hydrocarbon-1 bearing shales and mudrocks2  

E-Print Network [OSTI]

to describe seismic and electromagnetic (EM) measurements in these anisotropic54 materials.55 Oil-shale to release their hydrocarbons. Hence, oil shales and58 mudrocks are typically water-wet, single- or dual

Torres-Verdín, Carlos

480

Hydrocarbon trapping mechanisms in the Miller Creek area of the Powder River Basin, Wyoming  

E-Print Network [OSTI]

'' 1975 43'W'79 ABSTRACT Hydrocarbon Trapoing Mechanisms in the Miller Creek Area of the Powder River Basin, Wyoming. (May 1975) Jennifer Ann Armstrong, B. S. , University of Texas at Austin Chairman of Advisory Committee: 17r. Robert. R. Berg...

Armstrong, Jennifer Ann

1975-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrocarbon compounds primarily" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Interpretation of side-scan sonar images from hydrocarbon seep areas of the Louisiana continental slope  

E-Print Network [OSTI]

seeps are crude oil or gas that occurs on the earth's surface, having migrated from underlying buried source strata along faults. Hydrocarbon seeps can alter acoustic properties of the sediment in which they occur and these alterations can be detected...

Hou, Rusheng

2012-06-07T23:59:59.000Z

482

New approaches to the development of high-performance hydrocarbon propellants  

Science Journals Connector (OSTI)

An approach to express screening of promising hydrocarbon propellants, based on the calculation of the ... the results of quantum-chemical calculation of their heats of combustion, was suggested. The approach ens...

M. V. Savoskin; L. M. Kapkan; G. E. Vaiman

2007-01-01T23:59:59.000Z

483

Burning of Hydrocarbon Fuels Directly in a Water-Based Heat Carrier  

Science Journals Connector (OSTI)

A principal possibility of burning hydrocarbon fuels directly in a water-based heat carrier is demonstrated. The first experimental results are presented by an example of burning acetylene in water with initia...

V. S. Teslenko; V. I. Manzhalei; R. N. Medvedev

2010-07-01T23:59:59.000Z

484

Experimental study of the effect of top-ring clearance volume on unburned hydrocarbon concentrations  

Science Journals Connector (OSTI)

The clearance volume between the piston, the cylinder and the top compression ring in an internal combustion engine has a significant effect on the unburned hydrocarbon concentration. The high heat transfer from the burning mixture to the cylinder surface extinguishes the flame front, and this is the main reason for increased unburned hydrocarbon concentrations. The heat transfer between the mixture and the clearance volume surface is affected by the ratio of coolant surface to the clearance volume. In this study the effect of the ratio of the coolant surface to the clearance volume on the unburned hydrocarbon concentration was investigated using three different purpose-built pistons. A decrease of this ratio reduced the unburned hydrocarbon concentration by 40%.

Muammer Ozkan; Orhan Deniz; Tarkan Sandalci

2002-01-01T23:59:59.000Z

485

Determination of Hydrocarbons Types and Oxygenates in Motor Gasoline: A Comparative Study by Different Analytical Techniques  

Science Journals Connector (OSTI)

Various standard and published methods based on chromatographic and spectroscopic techniques are routinely used for hydrocarbon types (aromatics, olefins, oxygenates, etc.) in gasoline range fuel products for the assessment of product quality monitoring (...

V. Bansal; G. J. Krishna; A. P. Singh; A. K. Gupta; A. S. Sarpal

2007-12-04T23:59:59.000Z

486

Novel Antifoam for Fermentation Processes:? Fluorocarbon?Hydrocarbon Hybrid Unsymmetrical Bolaform Surfactant  

Science Journals Connector (OSTI)

Novel Antifoam for Fermentation Processes:? Fluorocarbon?Hydrocarbon Hybrid Unsymmetrical Bolaform Surfactant ... The infrastructure used in the experiments provided by SPO (Turkey) Grants 2001K121030 is gratefully acknowledged. ...

Pinar alik; Nazar Ileri; Burak I. Erdin; Nihal Aydogan; Muharrem Argun

2005-08-18T23:59:59.000Z

487

E-Print Network 3.0 - aromatic hydrocarbon neutrals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in deep seated HP-HT reservoirs or produced during in-situ upgrading steps... of heavy oils and oil shales. Our research shows that experimental hydrocarbon cracking results...

488

E-Print Network 3.0 - aromatic hydrocarbons concentrations Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Science ; Chemistry 52 0600B5--Brooks-McCall Cruise 05 MAY 30-JUN 1 2010 ****DATA SOURCE**** Summary: Aromatic Hydrocarbons | 8270M BTHIOPHNE Benzo(b)thiophene...

489

E-Print Network 3.0 - aromatic hydrocarbon bioremediation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Biotechnology 78 0600B5--Brooks-McCall Cruise 05 MAY 30-JUN 1 2010 ****DATA SOURCE**** Summary: Aromatic Hydrocarbons | 8270M BTHIOPHNE Benzo(b)thiophene...

490

The Energies of the Atomic Linkages in the Normal Paraffin Hydrocarbons  

Science Journals Connector (OSTI)

...No previous data Normal pentane...The new values for the heats of combustion of the hydrocarbon gases,4'5 together with new data obtained by Jessup4 on the heats of combustion of normal heptane and...

Frederick D. Rossini

1934-01-01T23:59:59.000Z

491

E-Print Network 3.0 - aromatic hydrocarbon concentrations Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Science ; Chemistry 52 0600B5--Brooks-McCall Cruise 05 MAY 30-JUN 1 2010 ****DATA SOURCE**** Summary: Aromatic Hydrocarbons | 8270M BTHIOPHNE Benzo(b)thiophene...

492

Sources and bioavailability of polynuclear aromatic hydrocarbons in Galveston Bay, Texas  

Science Journals Connector (OSTI)

Oyster and sediment samples collected from six sites in Galveston Bay from 1986 to 1998 were analyzed for polynuclear aromatic hydrocarbons (PAHs). Total concentrations of parent PAHs in oysters ranged from 20...

Yaorong Qian; Terry L. Wade; Jose L. Sericano

2001-12-01T23:59:59.000Z

493

Zeolite deactivation during hydrocarbon reactions: characterisation of coke precursors and acidity, product distribution.  

E-Print Network [OSTI]

??The catalytic conversion of hydrocarbons over zeolites has been applied in large scale petroleum-refining processes. However, there is always formation and retention of heavy by-products, (more)

Wang, B.

2008-01-01T23:59:59.000Z

494

The potential of hydrocarbons generation in the Chia Gara Formation at Amadia area, north of Iraq  

Science Journals Connector (OSTI)

Sixteen rock samples of outcrop of Chia Gara Formations from the type locality area, south of Amadia, North Iraq showed evidences for hydrocarbon generation potential by...1986) which contain brazinophyte algae,

Sahar Y. Jasim

2013-09-01T23:59:59.000Z

495

The methanol-to-hydrocarbons reaction : Influence of acid strength on the mechanism of olefin formation.  

E-Print Network [OSTI]

??The methanol-to-hydrocarbons (MTH) reaction is a flexible alternative step in the upgrading of natural gas, coal or biomass. By tuning the catalyst and process conditions, (more)

Erichsen, Marius Westgrd

2010-01-01T23:59:59.000Z

496

Hydrocarbon emissions in a homogeneous direct-injection spark engine : gasoline and gasohol  

E-Print Network [OSTI]

In order to better understand the effects on hydrocarbon emissions of loading, engine temperature, fuel type, and injection timing, a series of experiments was performed. The effect of loading was observed by running the ...

Tharp, Ronald S

2008-01-01T23:59:59.000Z

497

Black carbon in marine sediments : quantification and implications for the sorption of polycyclic aromatic hydrocarbons  

E-Print Network [OSTI]

Sorption is a key factor in determining the fate of polycyclic aromatic hydrocarbons (PAHs) in the environment. Here, PAH sorption is proposed as the sum of two mechanisms: absorption into a biogenic, organic carbon (OC) ...

Accardi-Dey, AmyMarie, 1976-

2003-01-01T23:59:59.000Z

498

Fouling of reverse osmosis membranes by hydrocarbonated and fluorinated surfactants contained in firefighting water  

E-Print Network [OSTI]

Title: Fouling of reverse osmosis membranes by hydrocarbonated and fluorinated surfactants osmosis efficiently treated the water from fire extinguishment. In this work we focused on the reverse surfactants [1]. Experimental results indicated that electrocoagulation and filtration followed by reverse

Paris-Sud XI, Université de

499

Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California  

E-Print Network [OSTI]

Mar Lett (2010) 30:331338 Fig. 3 Coal Oil Point seep field,hydrocarbon seeps near Coal Oil Point, California. Marhydrocarbon seep emissions, Coal Oil Point seep field,

Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

2010-01-01T23:59:59.000Z

500

Biodegradation of polycyclic Aromatic hydrocarbons by a bacterial consortium from Marine environment; -.  

E-Print Network [OSTI]

??newlinePolycyclic aromatic hydrocarbons PAHs are ubiquitous, newlineCarcinogenic mutagenic and persistent environmental pollutants generated by newlinenatural combustion processes as well as from human activities newlineAnthropogenic inputs (more)

Arulazhagan, P

2014-01-01T23:59:59.000Z