National Library of Energy BETA

Sample records for hydro hydrogen product

  1. Hydrogen production at run-of-river hydro plants

    SciTech Connect (OSTI)

    Tarnay, D.S.

    1983-12-01

    Production of energy from non-renewable petroleum, natural gas and coal is declining due to depletion and high prices. Presently, the research concentrates on reduction of consumption and more efficient use of traditional fuels, and on development of renewable sources of energy and new energy technologies. Most of the new energy sources, however, are not available in a convenient form for consumer. The new energy must be renewable, economically feasible and transportable. Not all the available renewable energy sources have these qualities. Many scientists and engineers believe that hydrogen meets these criteria best. Hydrogen can be produced from various renewable sources such as solar, wind, geothermal, tidal and glacier energies, ocean thermal energy conversion (OTEC), and obviously from - waterpower. The production of hydrogen at run-of-river hydropower plants via electrolysis could be the front-runner in developing new hydrogen energy technologies, and open the way to a new hydrogen era, similarly as the polyphase system and the a-c current generator of N. Tesla used at the Niagara Falls Hydropower Plant, opened the door to a new electrical age in 1895.

  2. HydroGen | Open Energy Information

    Open Energy Info (EERE)

    HydroGen Jump to: navigation, search Logo: HydroGen Name: HydroGen Address: Head Office, 9 GreenMeadows Place: Cardiff, Wales Country: United Kingdom Sector: Hydro, Hydrogen,...

  3. HydroGen Corporation formerly Chiste Corp | Open Energy Information

    Open Energy Info (EERE)

    HydroGen Corporation formerly Chiste Corp Jump to: navigation, search Name: HydroGen Corporation (formerly Chiste Corp) Place: Jefferson Hills, Pennsylvania Zip: 15025 Sector:...

  4. HydroGen Aquaphile sarl | Open Energy Information

    Open Energy Info (EERE)

    Aquaphile sarl Jump to: navigation, search Name: HydroGen Aquaphile sarl Region: France Sector: Marine and Hydrokinetic Website: www.hydro-gen.fr This company is listed in the...

  5. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power

    SciTech Connect (OSTI)

    Milbrandt, A.; Mann, M.

    2009-02-01

    This paper estimates the quantity of hydrogen that could be produced from coal, natural gas, nuclear, and hydro power by county in the United States. The study estimates that more than 72 million tonnes of hydrogen can be produced from coal, natural gas, nuclear, and hydro power per year in the country (considering only 30% of their total annual production). The United States consumed about 396 million tonnes of gasoline in 2007; therefore, the report suggests the amount of hydrogen from these sources could displace about 80% of this consumption.

  6. Florida Hydro Inc | Open Energy Information

    Open Energy Info (EERE)

    search Name: Florida Hydro Inc Place: Palatka, Florida Zip: 32177 Sector: Hydro, Hydrogen Product: Develops electrical generation and hydrogen production devices. Coordinates:...

  7. Hydrogen Production

    SciTech Connect (OSTI)

    2014-09-01

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produce hydrogen. It includes an overview of research goals as well as “quick facts” about hydrogen energy resources and production technologies.

  8. Hydrogen Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Hydrogen is an energy carrier, not an energy source-hydrogen stores and delivers energy in a usable form, but it must be produced from hydrogen- containing compounds. Hydrogen can be produced using diverse, domestic resources including fossil fuels, such as natural gas and coal (preferentially with carbon capture, utilization, and storage); biomass grown from renewable, non-food crops; or using nuclear energy and renewable energy sources, such as wind, solar, geothermal, and

  9. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  10. California Hydrogen Infrastructure Project | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Infrastructure Project Jump to: navigation, search Name: California Hydrogen Infrastructure Project Place: California Sector: Hydro, Hydrogen Product: String...

  11. Hydrogen Production: Photobiological

    Broader source: Energy.gov [DOE]

    The photobiological hydrogen production process uses microorganisms and sunlight to turn water, and sometimes organic matter, into hydrogen.

  12. Hydrogen Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  13. CTP Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    CTP Hydrogen Jump to: navigation, search Name: CTP Hydrogen Place: Westborough, Massachusetts Zip: 1581 Sector: Hydro, Hydrogen Product: CTP Hydrogen is an early stage company...

  14. Safe Hydrogen LLC | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen LLC Jump to: navigation, search Name: Safe Hydrogen LLC Place: Lexington, Massachusetts Sector: Hydro, Hydrogen Product: Focused on hydrogen storage, through a 'slurry' of...

  15. Hydrogen Car Co | Open Energy Information

    Open Energy Info (EERE)

    Car Co Jump to: navigation, search Name: Hydrogen Car Co Place: Los Angeles, California Zip: 90036 Sector: Hydro, Hydrogen Product: The Hydrogen Car Company produces hydrogen...

  16. Infinity Fuel Cell and Hydrogen | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Jump to: navigation, search Name: Infinity Fuel Cell and Hydrogen Place: Suffield, Connecticut Zip: 6078 Sector: Hydro, Hydrogen Product: A team of fuel cell, hydrogen and...

  17. Turnbull Hydro LLC | Open Energy Information

    Open Energy Info (EERE)

    Turnbull Hydro LLC Jump to: navigation, search Name: Turnbull Hydro LLC Place: Montana Sector: Hydro Product: Montana-based small hydro developer. References: Turnbull Hydro LLC1...

  18. Biological Hydrogen Production Workshop

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory (NREL) held a Biological Hydrogen Production Workshop on September 24–25, 2013, in Golden, Colorado. The workshop...

  19. NREL Wind to Hydrogen Project: Renewable Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & ...

  20. Florida Hydrogen Initiative Inc | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Initiative Inc Jump to: navigation, search Name: Florida Hydrogen Initiative Inc Place: Florida Sector: Hydro, Hydrogen Product: Provides grants to aid the development of...

  1. Hydrogen Solar Ltd | Open Energy Information

    Open Energy Info (EERE)

    Solar Ltd Jump to: navigation, search Name: Hydrogen Solar Ltd Place: Guildford, United Kingdom Zip: GU2 7YG Sector: Hydro, Hydrogen, Solar Product: Hydrogen Solar Ltd is...

  2. National Hydrogen Association | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Association Jump to: navigation, search Name: National Hydrogen Association Place: Washington, Washington, DC Zip: 20036 Sector: Hydro, Hydrogen Product: The source for...

  3. Highline Hydrogen Hybrids | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Hybrids Jump to: navigation, search Name: Highline Hydrogen Hybrids Place: farmington, Arkansas Zip: 72730-1500 Sector: Hydro, Hydrogen, Vehicles Product: US-based...

  4. Chevron Hydrogen Company LLC | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Company LLC Jump to: navigation, search Name: Chevron Hydrogen Company LLC Place: California Sector: Hydro, Hydrogen Product: California-based, subsidairy of Chevron...

  5. The London Hydrogen Partnership | Open Energy Information

    Open Energy Info (EERE)

    London Hydrogen Partnership Jump to: navigation, search Name: The London Hydrogen Partnership Place: London, United Kingdom Zip: SE1 2AA Sector: Hydro, Hydrogen Product: The London...

  6. Hunterston Hydrogen Ltd | Open Energy Information

    Open Energy Info (EERE)

    Hunterston Hydrogen Ltd Jump to: navigation, search Name: Hunterston Hydrogen Ltd Place: Anglesey, United Kingdom Zip: LL65 4RJ Sector: Hydro, Hydrogen, Wind energy Product:...

  7. German Hydrogen Association DWV | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Association DWV Jump to: navigation, search Name: German Hydrogen Association (DWV) Place: Berlin, Germany Zip: 12205 Sector: Hydro, Hydrogen Product: String...

  8. Hydrogen Engine Center HEC | Open Energy Information

    Open Energy Info (EERE)

    Engine Center HEC Jump to: navigation, search Name: Hydrogen Engine Center (HEC) Place: Algona, Iowa Zip: IA 50511 Sector: Hydro, Hydrogen Product: The Hydrogen Engine Center (HEC)...

  9. Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    Energy Jump to: navigation, search Name: Hydrogen Energy Place: Surrey, England, United Kingdom Zip: KT13 0NY Sector: Carbon, Hydro, Hydrogen Product: Surrey-based BP subsidiary...

  10. Clean Hydrogen Producers Ltd CHP | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Producers Ltd CHP Jump to: navigation, search Name: Clean Hydrogen Producers Ltd (CHP) Place: Geneva, Switzerland Zip: 1209 Sector: Hydro, Hydrogen, Solar Product: Swiss...

  11. India National Hydrogen Energy Board NHEB | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Energy Board NHEB Jump to: navigation, search Name: India National Hydrogen Energy Board (NHEB) Place: New Delhi, India Zip: 110 003 Sector: Hydro, Hydrogen Product: Set...

  12. Spanish Hydrogen Association AeH | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Association AeH Jump to: navigation, search Name: Spanish Hydrogen Association (AeH) Place: Madrid, Spain Zip: 28760 Sector: Hydro, Hydrogen Product: Spanish conference...

  13. Hydrogen production from carbonaceous material

    DOE Patents [OSTI]

    Lackner, Klaus S.; Ziock, Hans J.; Harrison, Douglas P.

    2004-09-14

    Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.

  14. Hydrogen Production | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Hydrogen Production Hydrogen Production Hydrogen is the simplest element on earth-it consists of only one proton and one electron-and it is an energy carrier, not an energy source. Hydrogen can store and deliver usable energy, but it doesn't typically exist by itself in nature and must be produced from compounds that contain it. WHY STUDY HYDROGEN PRODUCTION Hydrogen can be used in fuel cells to generate power using a chemical reaction rather than combustion, producing only water and

  15. Dharmshala Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    Dharmshala Hydro Power Ltd Jump to: navigation, search Name: Dharmshala Hydro Power Ltd. Place: Hyderabad, India Sector: Hydro Product: Hyderabad-based small hydro project...

  16. Ascent Hydro Projects Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ascent Hydro Projects Ltd Jump to: navigation, search Name: Ascent Hydro Projects Ltd. Place: Pune, Maharashtra, India Zip: 411007 Sector: Hydro Product: Pune-based small hydro...

  17. Neora Hydro Ltd | Open Energy Information

    Open Energy Info (EERE)

    Neora Hydro Ltd Jump to: navigation, search Name: Neora Hydro Ltd. Place: Kolkata, West Bengal, India Sector: Hydro Product: Kolkata-based small hydro project developer....

  18. A Photosynthetic Hydrogel for Catalytic Hydrogen Production ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production...

  19. Invervar Hydro | Open Energy Information

    Open Energy Info (EERE)

    Invervar Hydro Jump to: navigation, search Name: Invervar Hydro Place: United Kingdom Product: Scottish private project developer. References: Invervar Hydro1 This article is a...

  20. New Mexico Hydrogen Technology Partners HyTep | Open Energy Informatio...

    Open Energy Info (EERE)

    Hydrogen Technology Partners HyTep Jump to: navigation, search Name: New Mexico Hydrogen Technology Partners (HyTep) Place: New Mexico Sector: Hydro, Hydrogen Product: An alliance...

  1. Hydrogen Production Fact Sheet | Department of Energy

    Energy Savers [EERE]

    Production Fact Sheet Hydrogen Production Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen production. PDF icon Hydrogen Production More Documents & Publications Hydrogen Production Technical Team Roadmap US DRIVE Hydrogen Production Technical Team Roadmap FTA - SunLine Transit Agency - Final Report

  2. Hydrogen Production: Natural Gas Reforming

    Broader source: Energy.gov [DOE]

    Natural gas reforming is an advanced and mature production process that builds upon the existing natural gas pipeline delivery infrastructure. Today, 95% of the hydrogen produced in the United States is made by natural gas reforming in large central plants. This is an important technology pathway for near-term hydrogen production.

  3. Renewable Hydrogen Production from Biological Systems

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Production from Biological Systems Matthew Posewitz Colorado School of Mines DOE Biological Hydrogen Production Workshop September 24 th , 2013 H 2 production PSIIPSI...

  4. Manitoba Hydro | Open Energy Information

    Open Energy Info (EERE)

    Hydro Jump to: navigation, search Name: Manitoba Hydro Place: Winnipeg, Manitoba, Canada Zip: R3M 3T1 Sector: Hydro Product: Manitoba Hydro is the province's major energy...

  5. Hydrogen Production: Coal Gasification

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically through the process of coal gasification with carbon capture, utilization, and storage.

  6. Hydrogen company Hamburg E V | Open Energy Information

    Open Energy Info (EERE)

    company Hamburg E V Jump to: navigation, search Name: Hydrogen company Hamburg E V Place: Hamburg, Hamburg, Germany Sector: Hydro, Hydrogen Product: This organisation was created...

  7. Air Products Chemicals Inc | Open Energy Information

    Open Energy Info (EERE)

    Air Products & Chemicals Inc Place: Allentown, Pennsylvania Zip: 18195 Sector: Hydro, Hydrogen, Services Product: A global supplier of merchant hydrogen with a portfolio of...

  8. NREL: Hydrogen and Fuel Cells Research - Hydrogen Production and Delivery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Production and Delivery Learn how NREL is developing and advancing a number of pathways to renewable hydrogen production. Text Version Most of the hydrogen in the United States is produced by steam reforming of natural gas. For the near term, this production method will continue to dominate. Researchers at NREL are developing advanced processes to produce hydrogen economically from sustainable resources. NREL's hydrogen production and delivery R&D efforts, which are led by Huyen

  9. Potential Strategies for Integrating Solar Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis Webinar Potential Strategies for Integrating Solar Hydrogen Production and ...

  10. Autofermentative Biological Hydrogen Production by Cyanobacteria...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Hydrogen Production by Cyanobacteria Presentation by Charles Dismukes, Rutgers University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at...

  11. Hydrogenases and Barriers for Biotechnological Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Barriers for Biotechnological Hydrogen Production Technologies Presentation by John Peters, Montana State University, at the Biological Hydrogen Production Workshop held...

  12. Hydrogen Production Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    The Hydrogen Production Technical Team Roadmap identifies research pathways leading to hydrogen production technologies that produce near-zero net greenhouse gas (GHG) emissions from highly efficient and diverse renewable energy sources. This roadmap focuses on initial development of the technologies, identifies their gaps and barriers, and describes activities by various U.S. Department of Energy (DOE) offices to address the key issues and challenges.

  13. NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage & Transportation | Department of Energy Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation Presented at the Renewable Hydrogen Workshop, Nov. 16, 2009, in Palm Springs, CA PDF icon renewable_hydrogen_workshop_nov16_ramsden.pdf More Documents & Publications Hour-by-Hour Cost Modeling of Optimized Central Wind-Based Water Electrolysis

  14. Technical Analysis of Hydrogen Production

    SciTech Connect (OSTI)

    Ali T-Raissi

    2005-01-14

    The aim of this work was to assess issues of cost, and performance associated with the production and storage of hydrogen via following three feedstocks: sub-quality natural gas (SQNG), ammonia (NH{sub 3}), and water. Three technology areas were considered: (1) Hydrogen production utilizing SQNG resources, (2) Hydrogen storage in ammonia and amine-borane complexes for fuel cell applications, and (3) Hydrogen from solar thermochemical cycles for splitting water. This report summarizes our findings with the following objectives: Technoeconomic analysis of the feasibility of the technology areas 1-3; Evaluation of the hydrogen production cost by technology areas 1; and Feasibility of ammonia and/or amine-borane complexes (technology areas 2) as a means of hydrogen storage on-board fuel cell powered vehicles. For each technology area, we reviewed the open literature with respect to the following criteria: process efficiency, cost, safety, and ease of implementation and impact of the latest materials innovations, if any. We employed various process analysis platforms including FactSage chemical equilibrium software and Aspen Technologies AspenPlus and HYSYS chemical process simulation programs for determining the performance of the prospective hydrogen production processes.

  15. Thermochemical production of hydrogen

    DOE Patents [OSTI]

    Dreyfuss, Robert M.

    1976-07-13

    A thermochemical reaction cycle for the generation of hydrogen from water comprising the following sequence of reactions wherein M represents a metal and Z represents a metalloid selected from the arsenic-antimony-bismuth and selenium-tellurium subgroups of the periodic system: 2MO + Z + SO.sub.2 .fwdarw. MZ + MSO.sub.4 (1) mz + h.sub.2 so.sub.4 .fwdarw. mso.sub.4 + h.sub.2 z (2) 2mso.sub.4 .fwdarw. 2mo + so.sub.2 + so.sub.3 + 1/20.sub.2 (3) h.sub.2 z .fwdarw. z + h.sub.2 (4) h.sub.2 o + so.sub.3 .fwdarw. h.sub.2 so.sub.4 (5) the net reaction is the decomposition of water into hydrogen and oxygen.

  16. Negative hydrogen ion production mechanisms

    SciTech Connect (OSTI)

    Bacal, M.; Wada, M.

    2015-06-15

    Negative hydrogen/deuterium ions can be formed by processes occurring in the plasma volume and on surfaces facing the plasma. The principal mechanisms leading to the formation of these negative ions are dissociative electron attachment to ro-vibrationally excited hydrogen/deuterium molecules when the reaction takes place in the plasma volume, and the direct electron transfer from the low work function metal surface to the hydrogen/deuterium atoms when formation occurs on the surface. The existing theoretical models and reported experimental results on these two mechanisms are summarized. Performance of the negative hydrogen/deuterium ion sources that emerged from studies of these mechanisms is reviewed. Contemporary negative ion sources do not have negative ion production electrodes of original surface type sources but are operated with caesium with their structures nearly identical to volume production type sources. Reasons for enhanced negative ion current due to caesium addition to these sources are discussed.

  17. Thirumala Hydro Power P Ltd | Open Energy Information

    Open Energy Info (EERE)

    Thirumala Hydro Power P Ltd Jump to: navigation, search Name: Thirumala Hydro Power (P) Ltd. Place: Guntur, Andhra Pradesh, India Sector: Hydro Product: Guntur-based small hydro...

  18. V B Hydro Projects Ltd | Open Energy Information

    Open Energy Info (EERE)

    Hydro Projects Ltd Jump to: navigation, search Name: V. B. Hydro Projects Ltd. Place: Pathankot, Punjab, India Zip: 145001 Sector: Hydro Product: Pathankot-based small hydro...

  19. Solar Hydrogen Production

    SciTech Connect (OSTI)

    Koval, C.; Sutin, N.; Turner, J.

    1996-09-01

    This panel addressed different methods for the photoassisted dissociation of water into its component parts, hydrogen and oxygen. Systems considered include PV-electrolysis, photoelectrochemical cells, and transition-metal based microheterogeneous and homogeneous systems. While none of the systems for water splitting appear economically viable at the present time, the panel identified areas of basic research that could increase the overall efficiency and decrease the costs. Common to all the areas considered was the underlying belief that the water-to-hydrogen half reaction is reasonably well characterized, while the four-electron oxidation of water-to-oxygen is less well understood and represents a significant energy loss. For electrolysis, research in electrocatalysis to reduce overvoltage losses was identified as a key area for increased efficiency. Non-noble metal catalysts and less expensive components would reduce capital costs. While potentially offering higher efficiencies and lower costs, photoelectrochemical-based direct conversion systems undergo corrosion reactions and often have poor energetics for the water reaction. Research is needed to understand the factors that control the interfacial energetics and the photoinduced corrosion. Multi-photon devices were identified as promising systems for high efficiency conversion.

  20. Hydrogen production: Overview of technology options

    SciTech Connect (OSTI)

    None, None

    2009-01-15

    Overview of technology options for hydrogen production, its challenges and research needs and next steps

  1. Electrolytic Hydrogen Production: Potential Impacts to Utilities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolytic Hydrogen Production Potential Impacts to Utilities Electrolytic Hydrogen Production Workshop February 28, 2014 Frank Novachek Director, Corporate Planning 2 Electrolytic Hydrogen Production Potential Impacts - Electric System * Reliability * Capacity * Regulation * Generation Resources * On/Off Peak * Dispatchability Renewables Integration System Operations Electric Load Hydrogen Production * Ramp Control * Reserves * Plant Cycling 3 Unique Opportunities - Electric  Increased

  2. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Analysis of Photoelectrochemical (PEC) Hydrogen Production Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production This report documents the engineering and cost characteristics of four PEC hydrogen production systems selected by DOE to represent canonical embodiments of future systems. PDF icon Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production More Documents & Publications Technoeconomic Boundary Analysis of Biological

  3. Bacterial Fermentative Hydrogen Production | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bacterial Fermentative Hydrogen Production Bacterial Fermentative Hydrogen Production Presentation by Melanie Mormile, Missouri University of Science and Technology, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_mormile.pdf More Documents & Publications 2013 Biological Hydrogen Production Workshop Summary Report Autofermentative Biological Hydrogen Production by

  4. Hydrogen Production: Electrolysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    » Processes » Hydrogen Production: Electrolysis Hydrogen Production: Electrolysis Electrolysis is a promising option for hydrogen production from renewable resources. Electrolysis is the process of using electricity to split water into hydrogen and oxygen. This reaction takes place in a unit called an electrolyzer. Electrolyzers can range in size from small, appliance-size equipment that is well-suited for small-scale distributed hydrogen production to large-scale, central production

  5. Hydro Green Energy | Open Energy Information

    Open Energy Info (EERE)

    Green Energy Jump to: navigation, search Name: Hydro Green Energy Place: Houston, Texas Zip: 77056 Sector: Hydro Product: Hydro Green Energy is a project developer and integrator...

  6. Dharamshala Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    Dharamshala Hydro Power Ltd Jump to: navigation, search Name: Dharamshala Hydro Power Ltd Place: New Delhi, Delhi (NCT), India Zip: 110008 Sector: Hydro Product: Delhi-based...

  7. Bhilangana Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    Bhilangana Hydro Power Ltd Jump to: navigation, search Name: Bhilangana Hydro Power Ltd. Place: Noida, Uttar Pradesh, India Zip: 201301 Sector: Hydro Product: Noida-based small...

  8. North American Hydro | Open Energy Information

    Open Energy Info (EERE)

    Hydro Jump to: navigation, search Name: North American Hydro Place: Schofield, Wisconsin Zip: 54476 Sector: Hydro Product: Focused on developing, upgrading, owning, and operating...

  9. Advanced Hydro Solutions | Open Energy Information

    Open Energy Info (EERE)

    Hydro Solutions Jump to: navigation, search Name: Advanced Hydro Solutions Place: Fairlawn, Ohio Zip: 44333 Sector: Hydro Product: Ohio-based company seeking to develop...

  10. Himalayan Hydro P Ltd | Open Energy Information

    Open Energy Info (EERE)

    P Ltd Jump to: navigation, search Name: Himalayan Hydro (P) Ltd. Place: Hyderabad, Andhra Pradesh, India Zip: 500 033 Sector: Hydro Product: Hyderabad-based small hydro project...

  11. Cauvery Hydro Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    Cauvery Hydro Energy Ltd Jump to: navigation, search Name: Cauvery Hydro Energy Ltd. Place: Bangalore, Karnataka, India Zip: 560080 Sector: Hydro Product: Bangalore based small...

  12. Maximizing Light Utilization Efficiency and Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon iih1melis.pdf More Documents & Publications Webinar: Photosynthesis for Hydrogen and Fuels Production Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 ...

  13. 2013 Biological Hydrogen Production Workshop Summary Report ...

    Broader source: Energy.gov (indexed) [DOE]

    summary report for the 2013 Biological Hydrogen Production Workshop. bioh2workshopfinalreport.pdf More Documents & Publications The Hydrogen Program at NREL: A Brief Overview...

  14. Photoelectrochemical Hydrogen Production

    SciTech Connect (OSTI)

    Hu, Jian

    2013-12-23

    The objectives of this project, covering two phases and an additional extension phase, were the development of thin film-based hybrid photovoltaic (PV)/photoelectrochemical (PEC) devices for solar-powered water splitting. The hybrid device, comprising a low-cost photoactive material integrated with amorphous silicon (a-Si:H or a-Si in short)-based solar cells as a driver, should be able to produce hydrogen with a 5% solar-to-hydrogen conversion efficiency (STH) and be durable for at least 500 hours. Three thin film material classes were studied and developed under this program: silicon-based compounds, copper chalcopyrite-based compounds, and metal oxides. With the silicon-based compounds, more specifically the amorphous silicon carbide (a-SiC), we achieved a STH efficiency of 3.7% when the photoelectrode was coupled to an a-Si tandem solar cell, and a STH efficiency of 6.1% when using a crystalline Si PV driver. The hybrid PV/a-SiC device tested under a current bias of -3~4 mA/cm{sup 2}, exhibited a durability of up to ~800 hours in 0.25 M H{sub 2}SO{sub 4} electrolyte. Other than the PV driver, the most critical element affecting the photocurrent (and hence the STH efficiency) of the hybrid PV/a-SiC device was the surface energetics at the a-SiC/electrolyte interface. Without surface modification, the photocurrent of the hybrid PEC device was ~1 mA/cm{sup 2} or lower due to a surface barrier that limits the extraction of photogenerated carriers. We conducted an extensive search for suitable surface modification techniques/materials, of which the deposition of low work function metal nanoparticles was the most successful. Metal nanoparticles of ruthenium (Ru), tungsten (W) or titanium (Ti) led to an anodic shift in the onset potential. We have also been able to develop hybrid devices of various configurations in a monolithic fashion and optimized the current matching via altering the energy bandgap and thickness of each constituent cell. As a result, the short-circuit photocurrent density of the hybrid device (measured in a 2-electrode configuration) increased significantly without assistance of any external bias, i.e. from ?1 mA/cm{sup 2} to ~5 mA/cm{sup 2}. With the copper chalcopyrite compounds, we have achieved a STH efficiency of 3.7% in a coplanar configuration with 3 a-Si solar cells and one CuGaSe{sub 2} photocathode. This material class exhibited good durability at a photocurrent density level of -4 mA/cm{sup 2} (5% STH equivalent) at a fixed potential (-0.45 VRHE). A poor band-edge alignment with the hydrogen evolution reaction (HER) potential was identified as the main limitation for high STH efficiency. Three new pathways have been identified to solve this issue. First, PV driver with bandgap lower than that of amorphous silicon were investigated. Crystalline silicon was identified as possible bottom cell. Mechanical stacks made with one Si solar cell and one CuGaSe{sub 2} photocathode were built. A 400 mV anodic shift was observed with the Si cell, leading to photocurrent density of -5 mA/cm{sup 2} at 0VRHE (compared to 0 mA/cm{sup 2} at the same potential without PV driver). We also investigated the use of p-n junctions to shift CuGaSe{sub 2} flatband potential anodically. Reactively sputtered zinc oxy-sulfide thin films was evaluated as n-type buffer and deposited on CuGaSe{sub 2}. Ruthenium nanoparticles were then added as HER catalyst. A 250 mV anodic shift was observed with the p-n junction, leading to photocurrent density at 0VRHE of -1.5 mA/cm{sup 2}. Combining this device with a Si solar cell in a mechanical stack configuration shifted the onset potential further (+400 mV anodically), leading to photocurrent density of -7 mA/cm{sup 2} at 0VRHE. Finally, we developed wide bandgap copper chalcopyrite thin film materials. We demonstrated that Se can be substituted with S using a simple annealing step. Photocurrent densities in the 5-6 mA/cm{sub 2} range were obtained with red 2.0eV CuInGaS{sub 2} photocathodes. With the metal oxide compounds, we have demonstrated that a WO{sub 3}-based hybrid photoelectrode was feasible. Specifically, we showed that WO{sub 3} paired with an a-Si tandem solar cell can generate short circuit photocurrent density of 2.5 mA/cm{sup 2}, equivalent to STH efficiency of 3.1%. Long-term durability tests demonstrated WO{sub 3} ability to split water over extended periods, for up to 600 hours at current density levels of 2.0-2.5 mA/cm{sup 2}. Efforts have been done to decrease WO{sub 3} bandgap using foreign elements incorporation. We did not manage to reduce the bandgap of WO{sub 3} with this method. However, more promising results have been achieved with bilayered systems, where only the top part of WO{sub 3} films was modified. Also, we have demonstrated that alloying WO{sub 3} with CuO can form 2.2eV bandgap CuWO{sub 4}. Incorporating conductive carbon nanotubes in CuWO{sub 4} reduced its intrinsic bulk resistance. Saturation photocurrent densities in the 0.4-0.5 mA/cm{sub 2} range were achieved. Recently, in collaboration with University of Texas at Arlington, we have identified new quaternary metal oxides with CuWO{sub 4} as primary material host. Our experimental work on ceramics confirmed the theoretical calculations that crowned bismuth as a possible candidate to improve CuWO{sub 4} water splitting efficiency.

  15. Autofermentative Biological Hydrogen Production by Cyanobacteria |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Autofermentative Biological Hydrogen Production by Cyanobacteria Autofermentative Biological Hydrogen Production by Cyanobacteria Presentation by Charles Dismukes, Rutgers University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_dismukes.pdf More Documents & Publications 2013 Biological Hydrogen Production Workshop Summary Report Renewable Hydrogen

  16. Hydrogen Production Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Related Links Hydrogen Production Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen production activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Production Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and

  17. MHK Technologies/HydroGen 10 | Open Energy Information

    Open Energy Info (EERE)

    HydroGen 10 < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage HydroGen 10.jpg Technology Profile Primary Organization HydroGen Aquaphile sarl...

  18. Hydrogen Storage and Production Project

    SciTech Connect (OSTI)

    Bhattacharyya, Abhijit; Biris, A. S.; Mazumder, M. K.; Karabacak, T.; Kannarpady, Ganesh; Sharma, R.

    2011-07-31

    This is the final technical report. This report is a summary of the project. The goal of our project is to improve solar-to-hydrogen generation efficiency of the PhotoElectroChemical (PEC) conversion process by developing photoanodes with high absorption efficiency in the visible region of the solar radiation spectrum and to increase photo-corrosion resistance of the electrode for generating hydrogen from water. To meet this goal, we synthesized nanostructured heterogeneous semiconducting photoanodes with a higher light absorption efficiency compared to that of TiO2 and used a corrosion protective layer of TiO2. While the advantages of photoelectrochemical (PEC) production of hydrogen have not yet been realized, the recent developments show emergence of new nanostructural designs of photoanodes and choices of materials with significant gains in photoconversion efficiency.

  19. DOE Technical Targets for Photobiological Hydrogen Production

    Broader source: Energy.gov [DOE]

    These tables list the U.S. Department of Energy (DOE) technical targets for photobiological hydrogen production. The tables are organized into separate sections for photolytic biological and photosynthetic bacterial hydrogen production systems.

  20. Solar Thermochemical Hydrogen Production Research (STCH): Thermochemic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Thermochemical Hydrogen Production Research (STCH): Thermochemical Cycle Selection and ... Cycles International Nuclear Energy Research Initiative: 2008 Annual Report ...

  1. Hydrogenases and Barriers for Biotechnological Hydrogen Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies | Department of Energy Hydrogenases and Barriers for Biotechnological Hydrogen Production Technologies Hydrogenases and Barriers for Biotechnological Hydrogen Production Technologies Presentation by John Peters, Montana State University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_peters.pdf More Documents & Publications Renewable Hydrogen Production from

  2. Nanolipoprotein Particles for Hydrogen Production - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Nanolipoprotein Particles for Hydrogen Production Lawrence Livermore National Laboratory Contact LLNL About This Technology Technology Marketing Summary Lawrence Livermore National Laboratory has developed a method using nanolipoprotein particles (NLP) to solubilize and isolate membrane bound hydrogenases for the biological production of hydrogen. Hydrogen is a renewable energy carrier that has the

  3. Hydrogen Production Basics | Department of Energy

    Office of Environmental Management (EM)

    Education » Increase Your H2IQ » Hydrogen Production Basics Hydrogen Production Basics Hydrogen is an energy carrier, not an energy source-it stores and delivers energy in a usable form, but it must be produced from hydrogen containing compounds. Diverse and Domestic Supply Resources Hydrogen can be produced using diverse, domestic resources, including fossil fuels, such as coal (preferentially with carbon sequestration), and natural gas; nuclear energy; biomass and other renewable energy

  4. Solar Thermochemical Hydrogen Production Research (STCH): Thermochemical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cycle Selection and Investment Priority | Department of Energy Solar Thermochemical Hydrogen Production Research (STCH): Thermochemical Cycle Selection and Investment Priority Solar Thermochemical Hydrogen Production Research (STCH): Thermochemical Cycle Selection and Investment Priority This Sandia National Laboratories report documents the evaluation of nine solar thermochemical reaction cycles for the production of hydrogen and identifies the critical path challenges to the commercial

  5. Ayyappa Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ayyappa Hydro Power Ltd Jump to: navigation, search Name: Ayyappa Hydro Power Ltd. Place: Kolkata, West Bengal, India Zip: 700 017 Sector: Hydro Product: Kolkata-based small hydro...

  6. Gehra Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    Gehra Hydro Power Ltd Jump to: navigation, search Name: Gehra Hydro Power Ltd. Place: New Delhi, Delhi (NCT), India Zip: 110008 Sector: Hydro Product: Delhi-based small hydro...

  7. Jiuquan Sanyuan Hydro Power | Open Energy Information

    Open Energy Info (EERE)

    Hydro Power Jump to: navigation, search Name: Jiuquan Sanyuan Hydro Power Place: China Sector: Hydro Product: Developer of 26.55MW Gansu hydro plant in China. References: Jiuquan...

  8. KKK Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    KKK Hydro Power Ltd Jump to: navigation, search Name: KKK Hydro Power Ltd. Place: Faridabad, Haryana, India Zip: 121 003 Sector: Hydro Product: Faridabad-based small hydro project...

  9. Hydrogen Production: Fundamentals and Case Study Summaries (Presentation)

    SciTech Connect (OSTI)

    Harrison, K.; Remick, R.; Hoskin, A.; Martin, G.

    2010-05-19

    This presentation summarizes hydrogen production fundamentals and case studies, including hydrogen to wind case studies.

  10. Distributed Hydrogen Production from Natural Gas: Independent...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production from Natural Gas: Independent Review Panel Report Distributed Hydrogen Production from Natural Gas: Independent Review Panel Report Independent review report on the ...

  11. Webinar: Hydrogen Production by Polymer Electrolyte Membrane...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotlight on Giner and Proton Webinar: Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotligh...

  12. Electrolytic Hydrogen Production Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolytic Hydrogen Production Workshop Electrolytic Hydrogen Production Workshop The U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Fuel Cell Technologies Office (FCTO) held the Electrolytic Hydrogen Production Workshop on February 27-28, 2014, at The National Renewable Energy Laboratory (NREL) in Golden, Colorado, to discuss and share information on the research, development, and demonstration (RD&D) needs for enabling low-cost, effective hydrogen

  13. Hydrogen Production Pathways | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathways Hydrogen Production Pathways Hydrogen Production Pathways DOE is focused on developing technologies that can produce hydrogen at a target of less than $4/kg (delivered and dispensed). To reach these goals, the program looks at a wide portfolio of processes over a range of time frames and production scales. Currently, most hydrogen in the United States is produced by large-scale natural gas reforming. This established technology has been shown to be able to reach the cost targets in the

  14. NREL: Hydrogen and Fuel Cells Research - Hydrogen Production Cost Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Production Cost Analysis NREL analyzed the cost of hydrogen production via wind-based water electrolysis at 42 potential sites in 11 states across the nation. This analysis included centralized plants producing the Department of Energy (DOE) target of 50,000 kg of hydrogen per day, using both wind and grid electricity. The use of wind and grid electricity can be balanced either by power or cost, including or excluding the purchase of peak summer electricity. Current wind incentives-such

  15. System for thermochemical hydrogen production

    DOE Patents [OSTI]

    Werner, R.W.; Galloway, T.R.; Krikorian, O.H.

    1981-05-22

    Method and apparatus are described for joule boosting a SO/sub 3/ decomposer using electrical instead of thermal energy to heat the reactants of the high temperature SO/sub 3/ decomposition step of a thermochemical hydrogen production process driven by a tandem mirror reactor. Joule boosting the decomposer to a sufficiently high temperature from a lower temperature heat source eliminates the need for expensive catalysts and reduces the temperature and consequent materials requirements for the reactor blanket. A particular decomposer design utilizes electrically heated silicon carbide rods, at a temperature of 1250/sup 0/K, to decompose a cross flow of SO/sub 3/ gas.

  16. Hydrogen Production Processes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processes Hydrogen Production Processes Hydrogen can be produced using a number of different processes. Thermochemical processes use heat and chemical reactions to release hydrogen from organic materials such as fossil fuels and biomass. Water (H2O) can be split into hydrogen (H2) and oxygen (O2) using electrolysis or solar energy. Microorganisms such as bacteria and algae can produce hydrogen through biological processes. Thermochemical Processes Some thermal processes use the energy in various

  17. Hydrogen Production Technical Team Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... hydrogen control to assure public safety and address ... pathway," International Journal of Hydrogen Energy 34 ... Texas: Center for Energy Economics, 2004), http:...

  18. American Wind Power Hydrogen LLC | Open Energy Information

    Open Energy Info (EERE)

    Power Hydrogen LLC Jump to: navigation, search Name: American Wind Power & Hydrogen LLC Place: New York, New York Zip: 10022 Sector: Hydro, Hydrogen, Vehicles Product: AWP&H is a...

  19. Hydrogen production from microbial strains

    DOE Patents [OSTI]

    Harwood, Caroline S; Rey, Federico E

    2012-09-18

    The present invention is directed to a method of screening microbe strains capable of generating hydrogen. This method involves inoculating one or more microbes in a sample containing cell culture medium to form an inoculated culture medium. The inoculated culture medium is then incubated under hydrogen producing conditions. Once incubating causes the inoculated culture medium to produce hydrogen, microbes in the culture medium are identified as candidate microbe strains capable of generating hydrogen. Methods of producing hydrogen using one or more of the microbial strains identified as well as the hydrogen producing strains themselves are also disclosed.

  20. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report documents the engineering and cost characteristics of four PEC hydrogen production systems selected by DOE to represent canonical embodiments of future systems.

  1. Summary of Electrolytic Hydrogen Production: Milestone Completion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This report provides an overview of the current state of electrolytic hydrogen production techonologies and an economic analysis of the processes and systems available as of ...

  2. Updated Cost Analysis of Photobiological Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Updated Cost Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report This report updates the 1999 economic analysis ...

  3. Technoeconomic Analysis of Photoelectrochemical (PEC) Hydrogen Production

    SciTech Connect (OSTI)

    James, Brian D.; Baum, George N.; Perez, Julie; Baum, Kevin N.

    2009-12-01

    This report documents the engineering and cost characteristics of four PEC hydrogen production systems selected by DOE to represent canonical embodiments of future systems.

  4. Hydrogen Production Cost Estimate Using Biomass Gasification...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Estimate Using Biomass Gasification: Independent Review Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review This independent review is the ...

  5. Potential Strategies for Integrating Solar Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Future Central Hydrogen Production from Nuclear Energy via High Temperature Electrolysis, H2A Case Study Current analysis assumes solar thermal energy Assume solar ...

  6. Hydrogen Production: Biomass Gasification | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Gasification Hydrogen Production: Biomass Gasification Photo of a man standing near a pilot-scale gasification system. Biomass gasification is a mature technology pathway ...

  7. Metallic Membrane Materials Development for Hydrogen Production...

    Office of Scientific and Technical Information (OSTI)

    Metallic Membrane Materials Development for Hydrogen Production from Coal Derived Syngas Citation Details In-Document Search Title: Metallic Membrane Materials Development for...

  8. Promising technique improves hydrogen production of affordable...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Materialscientist, Wikipedia) (click image to enlarge) Promising technique improves hydrogen production of affordable alternative to platinum By Angela Hardin * October 26, 2015...

  9. Hydrogenases and Barriers for Biotechnological Hydrogen Production...

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogenases and barriers for biotechnological hydrogen production technologies John W. Peters Department of Chemistry and Biochemistry Department of Microbiology Montana State...

  10. Metallic Membrane Materials Development for Hydrogen Production...

    Office of Scientific and Technical Information (OSTI)

    Title: Metallic Membrane Materials Development for Hydrogen Production from Coal Derived Syngas The goals of Office of Clean Coal are: (1) Improved energy security; (2) Reduced ...

  11. Electrolytic Hydrogen Production Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Randy Petri, Versa Power Systems PDF icon Renewables and Grid Integration, Kevin Harrison, NREL PDF icon Electrolytic Hydrogen Production: Potential Impacts to Utilities, ...

  12. Hydrogen Production: Photoelectrochemical Water Splitting

    Broader source: Energy.gov [DOE]

    In photoelectrochemical (PEC) water splitting, hydrogen is produced from water using sunlight and specialized semiconductors called photoelectrochemical materials, which use light energy to directly dissociate water molecules into hydrogen and oxygen.

  13. Mobile Energy Products Inc | Open Energy Information

    Open Energy Info (EERE)

    Name: Mobile Energy Products Inc Place: Colorado Springs, Colorado Sector: Hydro, Hydrogen Product: Manufacturing subsidiary, which produces nickel sintered plaque for...

  14. The Hydrogen Company | Open Energy Information

    Open Energy Info (EERE)

    Company Jump to: navigation, search Name: The Hydrogen Company Abbreviation: HydroGen Address: The Hydrogen Company, HydroGen Engineering and Consulting, Head Office, 9...

  15. Vindhyachal Hydro Power Ltd VHPL | Open Energy Information

    Open Energy Info (EERE)

    Vindhyachal Hydro Power Ltd VHPL Jump to: navigation, search Name: Vindhyachal Hydro Power Ltd. (VHPL) Place: Mumbai, Maharashtra, India Zip: 400001 Sector: Hydro Product:...

  16. Fengning Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Fengning Hydro Power Development Co Ltd Jump to: navigation, search Name: Fengning Hydro Power Development Co., Ltd. Place: Guizhou Province, China Sector: Hydro Product:...

  17. Madkini Hydro Power Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Madkini Hydro Power Pvt Ltd Jump to: navigation, search Name: Madkini Hydro Power Pvt Ltd. Place: Dehradun, Uttaranchal, India Zip: 248006 Sector: Hydro Product: Dehradun-based...

  18. Vijayalakshmi Hydro Power Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Vijayalakshmi Hydro Power Pvt Ltd Jump to: navigation, search Name: Vijayalakshmi Hydro Power Pvt. Ltd. Place: Bangalore, Karnataka, India Zip: 560 001 Sector: Hydro Product:...

  19. Longchuan Minhong Hydro power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Minhong Hydro power Co Ltd Jump to: navigation, search Name: Longchuan Minhong Hydro power Co. Ltd Place: Yunnan Province, China Zip: 678700 Sector: Hydro Product: China-based...

  20. Gunsola Hydro Power Generation Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Gunsola Hydro Power Generation Pvt Ltd Jump to: navigation, search Name: Gunsola Hydro Power Generation Pvt Ltd Place: Dehradun, Uttaranchal, India Sector: Hydro Product:...

  1. Zhangping Huakou Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Zhangping Huakou Hydro Power Co Ltd Jump to: navigation, search Name: Zhangping Huakou Hydro Power Co Ltd Place: Zhangping, Fujian Province, China Sector: Hydro Product:...

  2. Shizong Heier Hydro power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Shizong Heier Hydro power Development Co Ltd Jump to: navigation, search Name: Shizong Heier Hydro power Development Co.Ltd Place: Yunnan Province, China Sector: Hydro Product:...

  3. Jiangxi Jiangwan Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Jiangwan Hydro Power Co Ltd Jump to: navigation, search Name: Jiangxi Jiangwan Hydro Power Co., Ltd. Place: Shangrao, China Zip: 344000 Sector: Hydro Product: China-based small...

  4. Libo Lidu Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Lidu Hydro Power Development Co Ltd Jump to: navigation, search Name: Libo Lidu Hydro Power Development Co.Ltd. Place: Guizhou Province, China Zip: 558400 Sector: Hydro Product:...

  5. Yu County Hydro electric Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    County Hydro electric Power Co Ltd Jump to: navigation, search Name: Yu County Hydro-electric Power Co., Ltd. Place: Shaanxi Province, China Zip: 45100 Sector: Hydro Product:...

  6. Leshan Kaiyuan Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Co Ltd Jump to: navigation, search Name: Leshan Kaiyuan Hydro Power Co., Ltd. Place: Leshan, Sichuan Province, China Zip: 614000 Sector: Hydro Product: Sichuan-based small hydro...

  7. Macaohe Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Macaohe Hydro Power Development Co Ltd Jump to: navigation, search Name: Macaohe Hydro Power Development Co., Ltd. Place: Tongren, Guizhou Province, China Sector: Hydro Product:...

  8. Zhongjing Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Zhongjing Hydro Power Development Co Ltd Jump to: navigation, search Name: Zhongjing Hydro Power Development Co., Ltd. Place: Guizhou Province, China Sector: Hydro Product:...

  9. Guizhou Anshun Sanchawan Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Anshun Sanchawan Hydro Power Co Ltd Jump to: navigation, search Name: Guizhou Anshun Sanchawan Hydro Power Co., Ltd. Place: Anshun, Guizhou Province, China Sector: Hydro Product:...

  10. Shimen Zhangjiadu Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Zhangjiadu Hydro Power Co Ltd Jump to: navigation, search Name: Shimen Zhangjiadu Hydro Power Co. Ltd. Place: Changde City, Hunan Province, China Zip: 415000 Sector: Hydro Product:...

  11. Jiangshan Jinlong hydro power development Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Jiangshan Jinlong hydro power development Co Ltd Jump to: navigation, search Name: Jiangshan Jinlong hydro power development Co. Ltd. Place: Jiangshan, China Sector: Hydro Product:...

  12. Qingyang Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Qingyang Hydro Power Development Co Ltd Jump to: navigation, search Name: Qingyang Hydro Power Development Co. Ltd. Place: Lishui City, China Zip: 323800 Sector: Hydro Product:...

  13. Huaiji County Huilian Hydro electric Group Company Limited |...

    Open Energy Info (EERE)

    Zip: 526400 Sector: Hydro Product: Hydro-electric project designer, constructor, and maintenance service provider. CLP Holding has 25% ownership of Huilian Hydro-electric....

  14. Voith Hydro Ocean Current Technologies | Open Energy Information

    Open Energy Info (EERE)

    Ocean Current Technologies Jump to: navigation, search Name: Voith Hydro Ocean Current Technologies Place: Germany Sector: Hydro Product: Germany-based JV between Voith Hydro and...

  15. Nagarjuna Hydro Energy Pvt Ltd NHEPL | Open Energy Information

    Open Energy Info (EERE)

    Hydro Energy Pvt Ltd NHEPL Jump to: navigation, search Name: Nagarjuna Hydro Energy Pvt. Ltd. (NHEPL) Place: Hyderabad, Andhra Pradesh, India Sector: Hydro Product: Hyderabad-based...

  16. Gowthami Hydro Electric Co P Ltd | Open Energy Information

    Open Energy Info (EERE)

    Hydro Electric Co P Ltd Jump to: navigation, search Name: Gowthami Hydro Electric Co. (P) Ltd. Place: Secunderabad, Andhra Pradesh, India Zip: 500 003 Sector: Hydro Product:...

  17. Redirection of metabolism for hydrogen production

    SciTech Connect (OSTI)

    Harwood, Caroline S.

    2011-11-28

    This project is to develop and apply techniques in metabolic engineering to improve the biocatalytic potential of the bacterium Rhodopseudomonas palustris for nitrogenase-catalyzed hydrogen gas production. R. palustris, is an ideal platform to develop as a biocatalyst for hydrogen gas production because it is an extremely versatile microbe that produces copious amounts of hydrogen by drawing on abundant natural resources of sunlight and biomass. Anoxygenic photosynthetic bacteria, such as R. palustris, generate hydrogen and ammonia during a process known as biological nitrogen fixation. This reaction is catalyzed by the enzyme nitrogenase and normally consumes nitrogen gas, ATP and electrons. The applied use of nitrogenase for hydrogen production is attractive because hydrogen is an obligatory product of this enzyme and is formed as the only product when nitrogen gas is not supplied. Our challenge is to understand the systems biology of R. palustris sufficiently well to be able to engineer cells to produce hydrogen continuously, as fast as possible and with as high a conversion efficiency as possible of light and electron donating substrates. For many experiments we started with a strain of R. palustris that produces hydrogen constitutively under all growth conditions. We then identified metabolic pathways and enzymes important for removal of electrons from electron-donating organic compounds and for their delivery to nitrogenase in whole R. palustris cells. For this we developed and applied improved techniques in 13C metabolic flux analysis. We identified reactions that are important for generating electrons for nitrogenase and that are yield-limiting for hydrogen production. We then increased hydrogen production by blocking alternative electron-utilizing metabolic pathways by mutagenesis. In addition we found that use of non-growing cells as biocatalysts for hydrogen gas production is an attractive option, because cells divert all resources away from growth and to hydrogen. Also R. palustris cells remain viable in a non-growing state for long periods of time.

  18. Hydrogen Production by Water Biophotolysis

    SciTech Connect (OSTI)

    Ghirardi, Maria L.; King, Paul W.; Mulder, David W.; Eckert, Carrie; Dubini, Alexandra; Maness, Pin-Ching; Yu, Jianping

    2014-01-22

    The use of microalgae for production of hydrogen gas from water photolysis has been studied for many years, but its commercialization is still limited by multiple challenges. Most of the barriers to commercialization are attributed to the existence of biological regulatory mechanisms that, under anaerobic conditions, quench the absorbed light energy, down-regulate linear electron transfer, inactivate the H2-producing enzyme, and compete for electrons with the hydrogenase. Consequently, the conversion efficiency of absorbed photons into H2 is significantly lower than its estimated potential of 1213 %. However, extensive research continues towards addressing these barriers by either trying to understand and circumvent intracellular regulatory mechanisms at the enzyme and metabolic level or by developing biological systems that achieve prolonged H2 production albeit under lower than 1213 % solar conversion efficiency. This chapter describes the metabolic pathways involved in biological H2 photoproduction from water photolysis, the attributes of the two hydrogenases, [FeFe] and [NiFe], that catalyze biological H2 production, and highlights research related to addressing the barriers described above. These highlights include: (a) recent advances in improving our understanding of the O2 inactivation mechanism in different classes of hydrogenases; (b) progress made in preventing competitive pathways from diverting electrons from H2 photoproduction; and (c) new developments in bypassing the non-dissipated proton gradient from down-regulating photosynthetic electron transfer. As an example of a major success story, we mention the generation of truncated-antenna mutants in Chlamydomonas and Synechocystis that address the inherent low-light saturation of photosynthesis. In addition, we highlight the rationale and progress towards coupling biological hydrogenases to non-biological, photochemical charge-separation as a means to bypass the barriers of photobiological systems.

  19. Production of hydrogen from alcohols

    DOE Patents [OSTI]

    Deluga, Gregg A. (St. Paul, MN); Schmidt, Lanny D. (Minneapolis, MN)

    2007-08-14

    A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

  20. Hydrogen Production: Thermochemical Water Splitting

    Broader source: Energy.gov [DOE]

    Thermochemical water splitting uses high temperatures—from concentrated solar power or from the waste heat of nuclear power reactions—and chemical reactions to produce hydrogen and oxygen from water.

  1. Production of Hydrogen from Underground Coal Gasification

    DOE Patents [OSTI]

    Upadhye, Ravindra S. (Pleasanton, CA)

    2008-10-07

    A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

  2. 2013 Biological Hydrogen Production Workshop Summary Report | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Biological Hydrogen Production Workshop Summary Report 2013 Biological Hydrogen Production Workshop Summary Report November 2013 summary report for the 2013 Biological Hydrogen Production Workshop. PDF icon bio_h2_workshop_final_report.pdf More Documents & Publications The Hydrogen Program at NREL: A Brief Overview Hydrogenases and Barriers for Biotechnological Hydrogen Production Technolog

  3. Beck Mickle Hydro Ltd | Open Energy Information

    Open Energy Info (EERE)

    Mickle Hydro Ltd Jump to: navigation, search Name: Beck Mickle Hydro Ltd. Place: Lancashire, England, United Kingdom Zip: LA4 4AY Product: Development of a technology, which...

  4. Belij Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    Belij Hydro Power Ltd Jump to: navigation, search Name: Belij Hydro Power Ltd Place: New Delhi, Delhi (NCT), India Zip: 110008 Product: Private investorproject developer which has...

  5. The Small Hydro Company | Open Energy Information

    Open Energy Info (EERE)

    Hydro Company Jump to: navigation, search Name: The Small Hydro Company Place: Oxfordshire, United Kingdom Product: Privately-held owner, developer and operator of assets....

  6. Solar Thermochemical Hydrogen Production Research (STCH)

    Fuel Cell Technologies Publication and Product Library (EERE)

    Eight cycles in a coordinated set of projects for Solar Thermochemical Cycles for Hydrogen production (STCH) were self-evaluated for the DOE-EERE Fuel Cell Technologies Program at a Working Group Meet

  7. HydroChina Corporation | Open Energy Information

    Open Energy Info (EERE)

    China Zip: 100011 Sector: Hydro, Wind energy Product: Beijing-based firm focused on hydro and wind power development. References: HydroChina Corporation1 This article is a...

  8. Norsk Hydro ASA | Open Energy Information

    Open Energy Info (EERE)

    Norsk Hydro ASA Jump to: navigation, search Name: Norsk Hydro ASA Place: Oslo, Norway Zip: NO-0283 Sector: Hydro, Renewable Energy, Solar Product: Oslo-based energy and aluminium...

  9. Hydrogen and Biogas Production using Microbial Electrolysis Cells...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Biogas Production using Microbial Electrolysis Cells Hydrogen and Biogas Production using Microbial Electrolysis Cells Breakout Session 2-C: Biogas and Beyond: ...

  10. Hydrogen Production and Purification from Coal and Other Heavy...

    Office of Scientific and Technical Information (OSTI)

    Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - ... Title: Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - ...

  11. Energy Department Invests $20 Million to Advance Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department Invests 20 Million to Advance Hydrogen Production and Delivery Technologies Energy Department Invests 20 Million to Advance Hydrogen Production and Delivery...

  12. Hydrogen Production by Polymer Electrolyte Membrane (PEM)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolysis-Spotlight on Giner and Proton | Department of Energy by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotlight on Giner and Proton Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotlight on Giner and Proton Presentation slides and speaker biographies from the DOE Fuel Cell Technologies Office webinar "Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotlight on Giner and Proton" held on May 23, 2011. PDF icon Water

  13. Hydrogen production using ammonia borane

    DOE Patents [OSTI]

    Hamilton, Charles W; Baker, R. Thomas; Semelsberger, Troy A; Shrestha, Roshan P

    2013-12-24

    Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.

  14. AD Hydro Power Ltd ADHPL | Open Energy Information

    Open Energy Info (EERE)

    AD Hydro Power Ltd ADHPL Jump to: navigation, search Name: AD Hydro Power Ltd. (ADHPL) Place: Noida, Uttar Pradesh, India Zip: 201301 Sector: Hydro Product: Noida-based small hydro...

  15. Hydrolysis reactor for hydrogen production

    DOE Patents [OSTI]

    Davis, Thomas A.; Matthews, Michael A.

    2012-12-04

    In accordance with certain embodiments of the present disclosure, a method for hydrolysis of a chemical hydride is provided. The method includes adding a chemical hydride to a reaction chamber and exposing the chemical hydride in the reaction chamber to a temperature of at least about 100.degree. C. in the presence of water and in the absence of an acid or a heterogeneous catalyst, wherein the chemical hydride undergoes hydrolysis to form hydrogen gas and a byproduct material.

  16. Central Versus Distributed Hydrogen Production | Department of Energy

    Office of Environmental Management (EM)

    Production » Central Versus Distributed Hydrogen Production Central Versus Distributed Hydrogen Production Central, semi-central, and distributed production facilities are expected to play a role in the evolution and long-term use of hydrogen as an energy carrier. The different resources and processes used to produce hydrogen may be suitable to one or more of these scales of production. Distributed Production Hydrogen can be produced in small units where it is needed, such as vehicle refueling

  17. Alternative Fuels Data Center: Hydrogen Production and Distribution

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Production and Distribution to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Production and Distribution on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Production and Distribution on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Production and Distribution on Google Bookmark Alternative Fuels Data Center: Hydrogen Production and Distribution on Delicious Rank Alternative Fuels Data Center: Hydrogen Production and Distribution on Digg Find More places

  18. Low-cost process for hydrogen production

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Bauer, Hans F. (Morgantown, WV); Grimes, Robert W. (Laramie, WY)

    1993-01-01

    A method is provided for producing hydrogen and carbon black from hydrocarbon gases comprising mixing the hydrocarbon gases with a source of carbon and applying radiofrequency energy to the mixture. The hydrocarbon gases and the carbon can both be the products of gasification of coal, particularly the mild gasification of coal. A method is also provided for producing hydrogen an carbon monoxide by treating a mixture of hydrocarbon gases and steam with radio-frequency energy.

  19. Low-cost process for hydrogen production

    DOE Patents [OSTI]

    Cha, C.H.; Bauer, H.F.; Grimes, R.W.

    1993-03-30

    A method is provided for producing hydrogen and carbon black from hydrocarbon gases comprising mixing the hydrocarbon gases with a source of carbon and applying radiofrequency energy to the mixture. The hydrocarbon gases and the carbon can both be the products of gasification of coal, particularly the mild gasification of coal. A method is also provided for producing hydrogen and carbon monoxide by treating a mixture of hydrocarbon gases and steam with radio-frequency energy.

  20. Hydrogen Production: Overview of Technology Options, January 2009

    Fuel Cell Technologies Publication and Product Library (EERE)

    Overview of technology options for hydrogen production, its challenges and research needs and next steps

  1. Hydrogen Production Infrastructure Options Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research Partner * Air Products, Industrial Gas Supplier * Advisory Board * Graham Moore, Chevron Technology Ventures * Mike Miller, Teledyne Energy Systems * Sandy Thomas, H 2 ...

  2. Photoelectrochemical Hydrogen Production - Final Report

    SciTech Connect (OSTI)

    Miller, E.L.; Marsen, B.; Paluselli, D.; Rocheleau, R.

    2004-11-17

    The scope of this photoelectrochemical hydrogen research project is defined by multijunction photoelectrode concepts for solar-powered water splitting, with the goal of efficient, stable, and economic operation. From an initial selection of several planar photoelectrode designs, the Hybrid Photoelectrode (HPE) has been identified as the most promising candidate technology. This photoelectrode consists of a photoelectrochemical (PEC) junction and a solid-state photovoltaic (PV) junction. Immersed in aqueous electrolyte and exposed to sunlight, these two junctions provide the necessary voltage to split water into hydrogen and oxygen gas. The efficiency of the conversion process is determined by the performance of the PEC- and the PV-junctions and on their spectral match. Based on their stability and cost effectiveness, iron oxide (Fe2O3) and tungsten oxide (WO3) films have been studied and developed as candidate semiconductor materials for the PEC junction (photoanode). High-temperature synthesis methods, as reported for some high-performance metal oxides, have been found incompatible with multijunction device fabrication. A low-temperature reactive sputtering process has been developed instead. In the parameter space investigated so far, the optoelectronic properties of WO3 films were superior to those of Fe2O3 films, which showed high recombination of photo-generated carriers. For the PV-junction, amorphous-silicon-based multijunction devices have been studied. Tandem junctions were preferred over triple junctions for better stability and spectral matching with the PEC junction. Based on a tandem a-SiGe/a-SiGe device and a tungsten trioxide film, a prototype hybrid photoelectrode has been demonstrated at 0.7% solar-to-hydrogen (STH) conversion efficiency. The PEC junction performance has been identified as the most critical element for higher-efficiency devices. Research into sputter-deposited tungsten trioxide films has yielded samples with higher photocurrents of up to 1.3 mA/cm2. An improved a-Si/aSi tandem device has been demonstrated that would provide a better voltage match to the recently improved WO3 films. For a hybrid photoelectrode based on these component devices the projected STH efficiency is 1.3%. For significant efficiency enhancements, metal oxide films with increased optical absorption, thus lower bandgap, are necessary. Initial experiments were successful in lowering the WO3 bandgap by nitrogen doping, from 3.0 eV to 2.1 eV. Optimizing the electronic properties of these compounds, or other reduced-bandgap materials such as Fe2O3, is the most immediate challenge. As the photocurrent levels of the PEC junction are improved, increasing attention will have to be paid to the matching PV junction.

  3. Systematic Discrimination of Advanced Hydrogen Production Technologies

    SciTech Connect (OSTI)

    Charles V. Park; Michael W. Patterson

    2010-07-01

    The U.S. Department of Energy, in concert with industry, is developing a high-temperature gas-cooled reactor at the Idaho National Laboratory (INL) to demonstrate high temperature heat applications to produce hydrogen and electricity or to support other industrial applications. A key part of this program is the production of hydrogen from water that would significantly reduce carbon emissions compared to current production using natural gas. In 2009 the INL led the methodical evaluation of promising advanced hydrogen production technologies in order to focus future resources on the most viable processes. This paper describes how the evaluation process was systematically planned and executed. As a result, High-Temperature Steam Electrolysis was selected as the most viable near-term technology to deploy as a part of the Next Generation Nuclear Plant Project.

  4. Hydrogen (H2) Production by Oxygenic Phototrophs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygenic Phototrophs Hydrogen (H2) Production by Oxygenic Phototrophs Presentation by Eric Hegg, Michigan State University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_hegg.pdf More Documents & Publications Renewable Hydrogen Production from Biological Systems Autofermentative Biological Hydrogen Production by Cyanobacteria 2013 Biological Hydrogen Production Workshop

  5. US DRIVE Hydrogen Production Technical Team Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Technical Team Roadmap US DRIVE Hydrogen Production Technical Team Roadmap The mission of the Hydrogen Production Technical Team (HPTT) is to enable the development of hydrogen production technologies, using clean, domestic resources, which will allow for an as-produced, delivered, and dispensed cost of $2 to $4 per gasoline gallon equivalent (gge) of hydrogen. PDF icon hptt_roadmap_june2013.pdf More Documents & Publications Hydrogen Production Technical Team Roadmap Bio-Derived

  6. Method for the enzymatic production of hydrogen

    DOE Patents [OSTI]

    Woodward, J.; Mattingly, S.M.

    1999-08-24

    The present invention is an enzymatic method for producing hydrogen comprising the steps of: (a) forming a reaction mixture within a reaction vessel comprising a substrate capable of undergoing oxidation within a catabolic reaction, such as glucose, galactose, xylose, mannose, sucrose, lactose, cellulose, xylan and starch; the reaction mixture also comprising an amount of glucose dehydrogenase in an amount sufficient to catalyze the oxidation of the substrate, an amount of hydrogenase sufficient to catalyze an electron-requiring reaction wherein a stoichiometric yield of hydrogen is produced, an amount of pH buffer in an amount sufficient to provide an environment that allows the hydrogenase and the glucose dehydrogenase to retain sufficient activity for the production of hydrogen to occur and also comprising an amount of nicotinamide adenine dinucleotide phosphate sufficient to transfer electrons from the catabolic reaction to the electron-requiring reaction; (b) heating the reaction mixture at a temperature sufficient for glucose dehydrogenase and the hydrogenase to retain sufficient activity and sufficient for the production of hydrogen to occur, and heating for a period of time that continues until the hydrogen is no longer produced by the reaction mixture, wherein the catabolic reaction and the electron-requiring reactions have rates of reaction dependent upon the temperature; and (c) detecting the hydrogen produced from the reaction mixture. 8 figs.

  7. Method for the enzymatic production of hydrogen

    DOE Patents [OSTI]

    Woodward, Jonathan (Kingston, TN); Mattingly, Susan M. (State College, PA)

    1999-01-01

    The present invention is an enzymatic method for producing hydrogen comprising the steps of: a) forming a reaction mixture within a reaction vessel comprising a substrate capable of undergoing oxidation within a catabolic reaction, such as glucose, galactose, xylose, mannose, sucrose, lactose, cellulose, xylan and starch. The reaction mixture further comprises an amount of glucose dehydrogenase in an amount sufficient to catalyze the oxidation of the substrate, an amount of hydrogenase sufficient to catalyze an electron-requiring reaction wherein a stoichiometric yield of hydrogen is produced, an amount of pH buffer in an amount sufficient to provide an environment that allows the hydrogenase and the glucose dehydrogenase to retain sufficient activity for the production of hydrogen to occur and also comprising an amount of nicotinamide adenine dinucleotide phosphate sufficient to transfer electrons from the catabolic reaction to the electron-requiring reaction; b) heating the reaction mixture at a temperature sufficient for glucose dehydrogenase and the hydrogenase to retain sufficient activity and sufficient for the production of hydrogen to occur, and heating for a period of time that continues until the hydrogen is no longer produced by the reaction mixture, wherein the catabolic reaction and the electron-requiring reactions have rates of reaction dependent upon the temperature; and c) detecting the hydrogen produced from the reaction mixture.

  8. Energy Department Invests $20 Million to Advance Hydrogen Production...

    Office of Environmental Management (EM)

    20 Million to Advance Hydrogen Production and Delivery Technologies Energy Department Invests 20 Million ... materials that can produce hydrogen from water using solar energy. ...

  9. Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Direct Hydrogen PEM Fuel Cell Systems for Transportation Applications: 2012 Update Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell Systems for Transportation...

  10. Renewable Hydrogen Production Using Sugars and Sugar Alcohols...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Production Using Sugars and Sugar Alcohols (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007...

  11. On-Board Hydrogen Gas Production System For Stirling Engines...

    Office of Scientific and Technical Information (OSTI)

    By controlling the temperature of the absorbing material, the stored hydrogen gas may be provided to the Stirling engine as needed. A hydrogen production system for use in ...

  12. The plutonium-hydrogen reaction: SEM characterization of product...

    Office of Scientific and Technical Information (OSTI)

    The plutonium-hydrogen reaction: SEM characterization of product morphology Citation Details In-Document Search Title: The plutonium-hydrogen reaction: SEM characterization of...

  13. The plutonium-hydrogen reaction: SEM characterization of product...

    Office of Scientific and Technical Information (OSTI)

    The plutonium-hydrogen reaction: SEM characterization of product morphology Citation Details In-Document Search Title: The plutonium-hydrogen reaction: SEM characterization of ...

  14. New Screening System Detects Algae with Increased H2 Production...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for screening through million-member algal libraries for strains with increased hydro- gen production. The screen uses H 2 -sensing bacteria that fluoresce when hydrogen is...

  15. Method for the continuous production of hydrogen

    DOE Patents [OSTI]

    Getty, John Paul (Knoxville, TN); Orr, Mark T. (Kingsport, TN); Woodward, Jonathan (Kingston, TN)

    2002-01-01

    The present invention is a method for the continuous production of hydrogen. The present method comprises reacting a metal catalyst with a degassed aqueous organic acid solution within a reaction vessel under anaerobic conditions at a constant temperature of .ltoreq.80.degree. C. and at a pH ranging from about 4 to about 9. The reaction forms a metal oxide when the metal catalyst reacts with the water component of the organic acid solution while generating hydrogen, then the organic acid solution reduces the metal oxide thereby regenerating the metal catalyst and producing water, thus permitting the oxidation and reduction to reoccur in a continual reaction cycle. The present method also allows the continuous production of hydrogen to be sustained by feeding the reaction with a continuous supply of degassed aqueous organic acid solution.

  16. Hydrogen Production Technical Team Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Team Roadmap Hydrogen Production Technical Team Roadmap The mission of the Hydrogen Production Technical Team (HPTT) is to enable the development of hydrogen production technologies, using clean, domestic resources, which will allow for an as-produced, delivered, and dispensed cost of $2 to $4 per gasoline gallon equivalent (gge) of hydrogen. PDF icon hptt_roadmap_june2013.pdf More Documents & Publications US DRIVE Hydrogen Production Technical Team Roadmap Bio-Derived Liquids to

  17. Thermoelectrochemical hydrogen production using sodium chloride

    SciTech Connect (OSTI)

    El-Bassuoni, A.M.A.; Sheffield, J.W.; Veziroglu, T.N.

    1981-01-01

    Three closed-cycle processes for the thermoelectrochemical production of hydrogen from water using sodium chloride are under investigation. The maximum required temperature of 700/degree/C can be achieved by solar energy using various concentration techniques. By means of photovoltaic cells or a solar power station, the required electric power can be obtained. 11 refs.

  18. DOE Science Showcase - Hydrogen Production | OSTI, US Dept of Energy,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Scientific and Technical Information Hydrogen Production Hydrogen Research in DOE Databases Energy Citations Database Information Bridge Science.gov WorldWideScience.org More information Making molecular hydrogen more efficiently Breaking Up (Hydrogen) No Longer As Hard To Do Hydrogen and Our Energy Future Fuel Cell Animation Hydrogen & Fuel Cells Increase your Hydrogen IQ Visit the Science Showcase homepage. Last updated on Monday 29 July

  19. Hydrogen Production and Purification from Coal and Other Heavy Feedstocks

    Office of Scientific and Technical Information (OSTI)

    Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology Air Products and

  20. DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production Cost

    Office of Environmental Management (EM)

    Using Low-Cost Natural Gas | Department of Energy 2024: Hydrogen Production Cost Using Low-Cost Natural Gas DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production Cost Using Low-Cost Natural Gas This program record from the U.S. Department of Energy's Fuel Cell Technologies Office provides information about the cost of hydrogen production using low-cost natural gas. PDF icon DOE Hydrogen and Fuel Cells Program Record # 12024 More Documents & Publications Distributed Hydrogen

  1. HydroVision International

    Broader source: Energy.gov [DOE]

    The HydroVision International Conference and Exhibition offers attendees countless opportunities to network, share best practices, meet with product and service providers, and more.  Held over five...

  2. Resource Assessment for Hydrogen Production: Hydrogen Production Potential from Fossil and Renewable Energy Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resource Assessment for Hydrogen Production Hydrogen Production Potential from Fossil and Renewable Energy Resources M. Melaina, M. Penev, and D. Heimiller National Renewable Energy Laboratory Technical Report NREL/TP-5400-55626 September 2013 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable Energy, LLC This report is available at no cost from the National Renewable Energy Laboratory (NREL)

  3. Fujian Shun Chang Yangkou Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Chang Yangkou Hydro Power Co Ltd Jump to: navigation, search Name: Fujian Shun Chang Yangkou Hydro Power Co., Ltd. Place: Fujian Province, China Zip: 353200 Sector: Hydro Product:...

  4. Solar and Wind Technologies for Hydrogen Production Report to Congress

    Fuel Cell Technologies Publication and Product Library (EERE)

    DOE's Solar and Wind Technologies for Hydrogen Production Report to Congress summarizes the technology roadmaps for solar- and wind-based hydrogen production. Published in December 2005, it fulfills t

  5. Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings

    Fuel Cell Technologies Publication and Product Library (EERE)

    This document summarizes the opportunities and challenges for low-cost renewable hydrogen production from wind and hydropower. The Workshop on Electrolysis Production of Hydrogen from Wind and Hydropo

  6. DOE Issues Request for Information on Biological Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Hydrogen Production DOE Issues Request for Information on Biological Hydrogen Production January 23, 2014 - 12:00am Addthis The U.S. Department of Energy's (DOE's) Fuel...

  7. DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production...

    Office of Environmental Management (EM)

    2024: Hydrogen Production Cost Using Low-Cost Natural Gas DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production Cost Using Low-Cost Natural Gas This program record...

  8. A Photosynthetic Hydrogel for Catalytic Hydrogen Production | ANSER Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Argonne-Northwestern National Laboratory A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production

  9. Electrolysis Production of Hydrogen from Wind and Hydropower Workshop Proceedings

    SciTech Connect (OSTI)

    2003-09-01

    This document summarizes the opportunities and challenges for low-cost renewable hydrogen production from wind and hydropower. The Workshop on Electrolysis Production of Hydrogen from Wind and Hydropower was held September 9-10, 2003.

  10. Startech Hydrogen Production Final Technical Report

    SciTech Connect (OSTI)

    Startech Engineering Department

    2007-11-27

    The assigned work scope includes the modification and utilization of the Plasma Converter System, Integration of a StarCell{trademark} Multistage Ceramic Membrane System (StarCell), and testing of the integrated systems towards DOE targets for gasification and membrane separation. Testing and evaluation was performed at the Startech Engineering and Demonstration Test Center in Bristol, CT. The Objectives of the program are as follows: (1) Characterize the performance of the integrated Plasma Converter and StarCell{trademark} Systems for hydrogen production and purification from abundant and inexpensive feedstocks; (2) Compare integrated hydrogen production performance to conventional technologies and DOE benchmarks; (3) Run pressure and temperature testing to baseline StarCell's performance; and (4) Determine the effect of process contaminants on the StarCell{trademark} system.

  11. DOE Technical Targets for Hydrogen Production from Microbial Biomass Conversion

    Broader source: Energy.gov [DOE]

    This table lists the U.S. Department of Energy (DOE) technical targets for hydrogen production from microbial biomass conversion.

  12. Hydrogen Production Roadmap: Technology Pathways to the Future, January 2009

    Fuel Cell Technologies Publication and Product Library (EERE)

    Roadmap to identify key challenges and priority R&D needs associated with various hydrogen fuel production technologies.

  13. Life Cycle Assessment of Hydrogen Production via Natural Gas Steam

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reforming | Department of Energy Hydrogen Production via Natural Gas Steam Reforming Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental consequences. PDF icon 27637.pdf More Documents & Publications Life Cycle Assessment of Renewable Hydrogen Production via Wind/Electrolysis: Milestone

  14. Hydrogen Production Roadmap. Technology Pathways to the Future, January 2009

    SciTech Connect (OSTI)

    Curry-Nkansah, Maria; Driscoll, Daniel; Farmer, Richard; Garland, Roxanne; Gruber, Jill; Gupta, Nikunj; Hershkowitz, Frank; Holladay, Jamelyn; Nguyen, Kevin; Schlasner, Steven; Steward, Darlene; Penev, Michael

    2009-01-01

    Roadmap to identify key challenges and priority R&D needs associated with various hydrogen fuel production technologies.

  15. Summary of Electrolytic Hydrogen Production: Milestone Completion Report |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Electrolytic Hydrogen Production: Milestone Completion Report Summary of Electrolytic Hydrogen Production: Milestone Completion Report This report provides an overview of the current state of electrolytic hydrogen production techonologies and an economic analysis of the processes and systems available as of December 2003. PDF icon 36734.pdf More Documents & Publications Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis

  16. Hydrogen Production and Purification from Coal and Other Heavy Feedstocks

    Office of Scientific and Technical Information (OSTI)

    Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology × You are accessing a

  17. Maximizing Light Utilization Efficiency and Hydrogen Production in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Microalgal Cultures, DOE Hydrogen Program FY 2010 Annual Progress Report | Department of Energy Maximizing Light Utilization Efficiency and Hydrogen Production in Microalgal Cultures, DOE Hydrogen Program FY 2010 Annual Progress Report Maximizing Light Utilization Efficiency and Hydrogen Production in Microalgal Cultures, DOE Hydrogen Program FY 2010 Annual Progress Report UCB will minimize, or truncate, the chlorophyll antenna size in green algae to maximize photobiological solar conversion

  18. Updated Cost Analysis of Photobiological Hydrogen Production from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chlamydomonas reinhardtii Green Algae: Milestone Completion Report | Department of Energy Updated Cost Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report Updated Cost Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report This report updates the 1999 economic analysis of NREL's photobiological hydrogen production from Chlamydomonas reinhardtii. PDF icon

  19. Photosynthesis for Hydrogen and Fuels Production Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photosynthesis for Hydrogen and Fuels Production Tasios Melis, UC Berkeley 24-Jan-2011 1 UCB-Melis 2 CO 2 H 2 O Photosynthesis Photons H 2 HC O 2 , Biomass Feedstock and products Process offers a renewable fuels supply and mitigation of climate change. UCB-Melis Average US Solar insolation = 5 kWh m -2 d -1 CA household electricity consumption = 15 kWh d -1 Sunlight 3 UCB-Melis Gains upon improving the carbon reactions of photosynthesis: up to 50% 4 "Six potential routes of increasing

  20. Integrated Ceramic Membrane System for Hydrogen Production

    SciTech Connect (OSTI)

    Schwartz, Joseph; Lim, Hankwon; Drnevich, Raymond

    2010-08-05

    Phase I was a technoeconomic feasibility study that defined the process scheme for the integrated ceramic membrane system for hydrogen production and determined the plan for Phase II. The hydrogen production system is comprised of an oxygen transport membrane (OTM) and a hydrogen transport membrane (HTM). Two process options were evaluated: 1) Integrated OTM-HTM reactor in this configuration, the HTM was a ceramic proton conductor operating at temperatures up to 900C, and 2) Sequential OTM and HTM reactors in this configuration, the HTM was assumed to be a Pd alloy operating at less than 600C. The analysis suggested that there are no technical issues related to either system that cannot be managed. The process with the sequential reactors was found to be more efficient, less expensive, and more likely to be commercialized in a shorter time than the single reactor. Therefore, Phase II focused on the sequential reactor system, specifically, the second stage, or the HTM portion. Work on the OTM portion was conducted in a separate program. Phase IIA began in February 2003. Candidate substrate materials and alloys were identified and porous ceramic tubes were produced and coated with Pd. Much effort was made to develop porous substrates with reasonable pore sizes suitable for Pd alloy coating. The second generation of tubes showed some improvement in pore size control, but this was not enough to get a viable membrane. Further improvements were made to the porous ceramic tube manufacturing process. When a support tube was successfully coated, the membrane was tested to determine the hydrogen flux. The results from all these tests were used to update the technoeconomic analysis from Phase I to confirm that the sequential membrane reactor system can potentially be a low-cost hydrogen supply option when using an existing membrane on a larger scale. Phase IIB began in October 2004 and focused on demonstrating an integrated HTM/water gas shift (WGS) reactor to increase CO conversion and produce more hydrogen than a standard water gas shift reactor would. Substantial improvements in substrate and membrane performance were achieved in another DOE project (DE-FC26-07NT43054). These improved membranes were used for testing in a water gas shift environment in this program. The amount of net H2 generated (defined as the difference of hydrogen produced and fed) was greater than would be produced at equilibrium using conventional water gas shift reactors up to 75 psig because of the shift in equilibrium caused by continuous hydrogen removal. However, methanation happened at higher pressures, 100 and 125 psig, and resulted in less net H2 generated than would be expected by equilibrium conversion alone. An effort to avoid methanation by testing in more oxidizing conditions (by increasing CO2/CO ratio in a feed gas) was successful and net H2 generated was higher (40-60%) than a conventional reactor at equilibrium at all pressures tested (up to 125 psig). A model was developed to predict reactor performance in both cases with and without methanation. The required membrane area depends on conditions, but the required membrane area is about 10 ft2 to produce about 2000 scfh of hydrogen. The maximum amount of hydrogen that can be produced in a membrane reactor decreased significantly due to methanation from about 2600 scfh to about 2400 scfh. Therefore, it is critical to eliminate methanation to fully benefit from the use of a membrane in the reaction. Other modeling work showed that operating a membrane reactor at higher temperature provides an opportunity to make the reactor smaller and potentially provides a significant capital cost savings compared to a shift reactor/PSA combination.

  1. Energy Department Invests $20 Million to Advance Hydrogen Production and

    Office of Environmental Management (EM)

    Delivery Technologies | Department of Energy 20 Million to Advance Hydrogen Production and Delivery Technologies Energy Department Invests $20 Million to Advance Hydrogen Production and Delivery Technologies June 16, 2014 - 1:21pm Addthis The Energy Department today announced $20 million for ten new research and development projects that will advance hydrogen production and delivery technologies. Developing technologies that can economically produce and deliver hydrogen to power fuel cells

  2. Webinar: Photosynthesis for Hydrogen and Fuels Production | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy slides, webinar Q&A, and speaker biography from the Fuel Cell Technologies Office webinar "Photosynthesis for Hydrogen and Fuels Production" held on January 24, 2011. PDF icon Photosynthesis for Hydrogen and Fuels Production Webinar Slides PDF icon Webinar Q&A PDF icon Professional Biography for Tasios Melis More Documents & Publications Maximizing Light Utilization Efficiency and Hydrogen Production in Microalgal Cultures, DOE Hydrogen Program FY 2010 Annual

  3. Hydro Generation Ltd | Open Energy Information

    Open Energy Info (EERE)

    Services Product: Micro hydropower company. Provides technical services such as feasibility studies, mechanicalcivilelectical design. References: Hydro Generation Ltd1...

  4. Production of hydrogen from oil shale

    SciTech Connect (OSTI)

    Schora, F. C.; Feldkirchner, H. L.; Janka, J. C.

    1985-12-24

    A process for production of hydrogen from oil shale fines by direct introduction of the oil shale fines into a fluidized bed at temperatures about 1200/sup 0/ to about 2000/sup 0/ F. to obtain rapid heating of the oil shale. The bed is fluidized by upward passage of steam and oxygen, the steam introduced in the weight ratio of about 0.1 to about 10 on the basis of the organic carbon content of the oil shale and the oxygen introduced in less than the stoichiometric quantity for complete combustion of the organic carbonaceous kerogen content of the oil shale. Embodiments are disclosed for heat recovery from the spent shale and heat recovery from the spent shale and product gas wherein the complete process and heat recovery is carried out in a single reaction vessel. The process of this invention provides high conversion of organic carbon component of oil shale and high production of hydrogen from shale fines which when used in combination with a conventional oil shale hydroconversion process results in increased overall process efficiency of greater than 15 percent.

  5. Hydrogen Production in the U.S. and Worldwide - 2013

    SciTech Connect (OSTI)

    Brown, Daryl R.

    2015-04-01

    This article describes the different categories of hydrogen production (captive, by-product, and merchant) and presents production data for 2013 by industry within these categories. Merchant production data is provided for the top-four industrial gas companies.

  6. Tehri Hydro Development Corporation Limited | Open Energy Information

    Open Energy Info (EERE)

    Solar, Wind energy Product: Focused on hydro projects; diversifying into solar and wind power. References: Tehri Hydro Development Corporation Limited1 This article is a stub....

  7. Department of Hydro Power Development | Open Energy Information

    Open Energy Info (EERE)

    Development Jump to: navigation, search Name: Department of Hydro Power Development Place: Itanagar, Arunachal Pradesh, India Zip: 791 110 Sector: Hydro Product: Itanagar-based...

  8. Orissa Hydro Power Corporation Ltd | Open Energy Information

    Open Energy Info (EERE)

    Orissa Hydro Power Corporation Ltd Jump to: navigation, search Name: Orissa Hydro Power Corporation Ltd. Place: Bhubaneswar, Orissa, India Zip: 751002 Product: Bhubaneswar-based...

  9. Ningyuan County Hydro Power Development Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Development Co Ltd Jump to: navigation, search Name: Ningyuan County Hydro Power Development Co., Ltd. Place: Yongzhou, Hunan Province, China Zip: 425600 Sector: Hydro Product:...

  10. Statoil formerly StatoilHydro | Open Energy Information

    Open Energy Info (EERE)

    Stavanger, Norway Zip: N-4035 Sector: Hydro, Renewable Energy Product: Norway-based oil and gas company. StatoilHydro(tm)s New Energy business unit involves renewable...

  11. Smart Hydro Power GmbH | Open Energy Information

    Open Energy Info (EERE)

    Smart Hydro Power GmbH Address: Alte Traubinger Str. 17 Place: Garatshausen Country: Germany Zip: 82340 Sector: Marine and Hydrokinetic Product: Micro Hydro Kinetic Turbine...

  12. Dhauladhar Hydro System Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Sector: Hydro Product: Himachal-based developer of small hydro projects. Coordinates: 23.25149, 87.522408 Show Map Loading map... "minzoom":false,"mappingservice":"googlema...

  13. Super Hydro Electric Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Electric Pvt Ltd Jump to: navigation, search Name: Super Hydro Electric Pvt. Ltd. Place: New Delhi, Delhi (NCT), India Zip: 1100024 Sector: Hydro Product: Delhi-based small hydro...

  14. Ledong Xinyuan Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ledong Xinyuan Hydro Power Co Ltd Jump to: navigation, search Name: Ledong Xinyuan Hydro Power Co. Ltd Place: Hainan Province, China Zip: 572500 Sector: Hydro Product: China-based...

  15. Hul Hydro Power Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Hul Hydro Power Pvt Ltd Jump to: navigation, search Name: Hul Hydro Power Pvt. Ltd. Place: Hyderabad, Andhra Pradesh, India Zip: 500004 Sector: Hydro Product: Hyderabad-based small...

  16. Huichang Bai exia Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Huichang Bai exia Hydro Power Co Ltd Jump to: navigation, search Name: Huichang Bai'exia Hydro Power Co., Ltd Place: Jiangxi Province, China Zip: 342600 Sector: Hydro Product:...

  17. Puer Xianmei Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Puer Xianmei Hydro Power Co Ltd Jump to: navigation, search Name: Puer Xianmei Hydro Power Co., Ltd. Place: Yunnan Province, China Zip: 665108 Sector: Hydro Product: Yunnan-based...

  18. Siri Ram Syal Hydro Power Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Siri Ram Syal Hydro Power Pvt Ltd Jump to: navigation, search Name: Siri Ram Syal Hydro Power Pvt Ltd Place: New Delhi, Delhi (NCT), India Zip: 110070 Sector: Hydro Product:...

  19. Cosmos Hydro Power Ltd CHPL | Open Energy Information

    Open Energy Info (EERE)

    Ltd CHPL Jump to: navigation, search Name: Cosmos Hydro Power Ltd. (CHPL) Place: New Delhi, Delhi (NCT), India Zip: 110060 Sector: Hydro Product: Delhi-based small hydro project...

  20. Birahi Ganga Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    Birahi Ganga Hydro Power Ltd Jump to: navigation, search Name: Birahi Ganga Hydro Power Ltd. Place: New Delhi, Delhi (NCT), India Zip: 110019 Sector: Hydro Product: Delhi-based...

  1. Chamoli Hydro Power P Ltd | Open Energy Information

    Open Energy Info (EERE)

    Chamoli Hydro Power P Ltd Jump to: navigation, search Name: Chamoli Hydro Power (P) Ltd. Place: Hyderabad, Andhra Pradesh, India Zip: 500 033 Sector: Hydro Product: Hyderabad-based...

  2. SBA Hydro Systems Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    SBA Hydro Systems Pvt Ltd Jump to: navigation, search Name: SBA Hydro Systems Pvt. Ltd. Place: New Delhi, Delhi (NCT), India Zip: 110019 Sector: Hydro Product: Delhi-based...

  3. Usaka Hydro Powers Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Usaka Hydro Powers Pvt Ltd Jump to: navigation, search Name: Usaka Hydro Powers Pvt. Ltd. Place: Anand Parvat, Delhi (NCT), India Zip: 110005 Sector: Hydro Product: Delhi-based...

  4. Renewable Hydrogen Production from Biological Systems | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy from Biological Systems Renewable Hydrogen Production from Biological Systems Presentation by Matthew Posewitz, Colorado School of Mines, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_posewitz.pdf More Documents & Publications The Hydrogen Program at NREL: A Brief Overview Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report

  5. DOE Technical Targets for Hydrogen Production from Biomass Gasification |

    Energy Savers [EERE]

    Department of Energy Biomass Gasification DOE Technical Targets for Hydrogen Production from Biomass Gasification These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen production from biomass gasification. More information about targets can be found in the Hydrogen Production section of the Fuel Cell Technologies Office's Multi-Year Research, Development, and Demonstration Plan. Technical Targets: Biomass Gasification/Pyrolysis

  6. DOE Technical Targets for Hydrogen Production from Thermochemical Water

    Energy Savers [EERE]

    Splitting | Department of Energy from Thermochemical Water Splitting DOE Technical Targets for Hydrogen Production from Thermochemical Water Splitting These tables list the U.S. Department of Energy (DOE) technical targets and example cost and performance parameter values that achieve the targets for hydrogen production from thermochemical water splitting. More information about targets can be found in the Hydrogen Production section of the Fuel Cell Technologies Office's Multi-Year

  7. Life Cycle Assessment of Renewable Hydrogen Production via

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind/Electrolysis: Milestone Completion Report | Department of Energy Renewable Hydrogen Production via Wind/Electrolysis: Milestone Completion Report Life Cycle Assessment of Renewable Hydrogen Production via Wind/Electrolysis: Milestone Completion Report This report summarizes the results of a lifecycle assessment of a renewable hydrogen production process employing wind/electrolysis. PDF icon 35404.pdf More Documents & Publications Analysis Activities at National Renewable Energy

  8. High Temperature Electrolysis for Efficient Hydrogen Production from Nuclear Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Electrolysis for Efficient Hydrogen Production from Nuclear Energy - INL Research Program Summary Jim O'Brien Idaho National Laboratory Electrolytic Hydrogen Production Workshop National Renewable Energy Laboratory Golden, CO February 27-28, 2014 NGNP/VHTR Concept for Large-Scale Centralized Nuclear Hydrogen Production based on High-Temperature Steam Electrolysis * Directly coupled to high-temperature gas-cooled reactor for electrical power and process heat * 600 MWth reactor

  9. Hydrogen (H2) Production by Anoxygenic Purple Nonsulfur Bacteria |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Anoxygenic Purple Nonsulfur Bacteria Hydrogen (H2) Production by Anoxygenic Purple Nonsulfur Bacteria Presentation by Jake McKinlay, Indiana University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_mckinlay.pdf More Documents & Publications 2013 Biological Hydrogen Production Workshop Summary Report Savannah River National Laboratory (SRNL)

  10. Hydrogen and Biogas Production using Microbial Electrolysis Cells |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrogen and Biogas Production using Microbial Electrolysis Cells Hydrogen and Biogas Production using Microbial Electrolysis Cells Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste Feedstocks Hydrogen and Biogas Production using Microbial Electrolysis Cells Bruce Logan, Kappe Professor of Environmental Engineering and Evan Pugh Professor, Pennsylvania State University PDF icon logan_bioenergy_2015.pdf More

  11. Co-production of Hydrogen and Electricity (A Developer's Perspective) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Co-production of Hydrogen and Electricity (A Developer's Perspective) Co-production of Hydrogen and Electricity (A Developer's Perspective) FuelCell Energy Overview, Direct Fuel Cell (DFC) Technology Status, Hydrogen Co-production Technology, Benefits and Status, Strategic Input PDF icon tspi_patel.pdf More Documents & Publications Fuel Cell Power Plants Renewable and Waste Fuels DFC Technology Status Fuel Cell Power Plants Biofuel Case Study - Tulare, CA

  12. DOE Issues Request for Information on Biological Hydrogen Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Biological Hydrogen Production DOE Issues Request for Information on Biological Hydrogen Production January 23, 2014 - 12:00am Addthis The U.S. Department of Energy's (DOE's) Fuel Cell Technologies Office has issued a request for information (RFI) seeking feedback from interested stakeholders regarding biological hydrogen production research and development (R&D) pathways, barriers, issues, and opportunities for development of technologies that can ultimately produce

  13. Deadline Extended for RFI on Biological Hydrogen Production | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy on Biological Hydrogen Production Deadline Extended for RFI on Biological Hydrogen Production February 26, 2014 - 12:00am Addthis DOE has extended the submission deadline for this Request for Information. Responses must be submitted by 5:00 p.m. Eastern Time on March 14, 2014. The U.S. Department of Energy's (DOE's) Fuel Cell Technologies Office has issued a request for information (RFI) seeking feedback from interested stakeholders regarding biological hydrogen production research

  14. Webinar: Potential Strategies for Integrating Solar Hydrogen Production and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Concentrating Solar Power: A Systems Analysis | Department of Energy Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis Webinar: Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis January 21, 2016 12:00PM to 1:00PM EST The Energy Department will present a live webinar titled "Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar

  15. Nuclear Hydrogen for Peak Electricity Production and Spinning Reserve

    SciTech Connect (OSTI)

    Forsberg, C.W.

    2005-01-20

    Nuclear energy can be used to produce hydrogen. The key strategic question is this: ''What are the early markets for nuclear hydrogen?'' The answer determines (1) whether there are incentives to implement nuclear hydrogen technology today or whether the development of such a technology could be delayed by decades until a hydrogen economy has evolved, (2) the industrial partners required to develop such a technology, and (3) the technological requirements for the hydrogen production system (rate of production, steady-state or variable production, hydrogen purity, etc.). Understanding ''early'' markets for any new product is difficult because the customer may not even recognize that the product could exist. This study is an initial examination of how nuclear hydrogen could be used in two interconnected early markets: the production of electricity for peak and intermediate electrical loads and spinning reserve for the electrical grid. The study is intended to provide an initial description that can then be used to consult with potential customers (utilities, the Electric Power Research Institute, etc.) to better determine the potential real-world viability of this early market for nuclear hydrogen and provide the starting point for a more definitive assessment of the concept. If this set of applications is economically viable, it offers several unique advantages: (1) the market is approximately equivalent in size to the existing nuclear electric enterprise in the United States, (2) the entire market is within the utility industry and does not require development of an external market for hydrogen or a significant hydrogen infrastructure beyond the utility site, (3) the technology and scale match those of nuclear hydrogen production, (4) the market exists today, and (5) the market is sufficient in size to justify development of nuclear hydrogen production techniques independent of the development of any other market for hydrogen. These characteristics make it an ideal early market for nuclear hydrogen.

  16. Fermentation and Electrohydrogenic Approaches to Hydrogen Production (Presentation)

    SciTech Connect (OSTI)

    Maness, P. C.; Thammannagowda, S.; Magnusson, L.; Logan, B.

    2010-06-01

    This work describes the development of a waste biomass fermentation process using cellulose-degrading bacteria for hydrogen production. This process is then integrated with an electrohydrogenesis process via the development of a microbial electrolysis cell reactor, during which fermentation waste effluent is further converted to hydrogen to increase the total output of hydrogen from biomass.

  17. Solar Thermochemical Hydrogen Production Research (STCH)

    SciTech Connect (OSTI)

    Perret, Robert

    2011-05-01

    Eight cycles in a coordinated set of projects for Solar Thermochemical Cycles for Hydrogen production (STCH) were self-evaluated for the DOE-EERE Fuel Cell Technologies Program at a Working Group Meeting on October 8 and 9, 2008. This document reports the initial selection process for development investment in STCH projects, the evaluation process meant to reduce the number of projects as a means to focus resources on development of a few most-likely-to-succeed efforts, the obstacles encountered in project inventory reduction and the outcomes of the evaluation process. Summary technical status of the projects under evaluation is reported and recommendations identified to improve future project planning and selection activities.

  18. Method for low temperature catalytic production of hydrogen

    DOE Patents [OSTI]

    Mahajan, Devinder

    2003-07-22

    The invention provides a process for the catalytic production of a hydrogen feed by exposing a hydrogen feed to a catalyst which promotes a base-catalyzed water-gas-shift reaction in a liquid phase. The hydrogen feed can be provided by any process known in the art of making hydrogen gas. It is preferably provided by a process that can produce a hydrogen feed for use in proton exchange membrane fuel cells. The step of exposing the hydrogen feed takes place preferably from about 80.degree. C. to about 150.degree. C.

  19. Suite of Photo-electrochemical Technologies for Hydrogen Production...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Solar Photovoltaic Solar Photovoltaic ... Suite of Photo-electrochemical Technologies for Hydrogen Production National Renewable Energy Laboratory ...

  20. DOE Technical Targets for Hydrogen Production from Electrolysis

    Broader source: Energy.gov [DOE]

    These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen production from electrolysis.

  1. Hydrogen Production by Polymer Electrolyte Membrane (PEM)Electrolysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation slides and speaker biographies from the DOE Fuel Cell Technologies Office webinar "Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotlight on ...

  2. Life Cycle Assessment of Renewable Hydrogen Production viaWind...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Hydrogen Production via WindElectrolysis: Milestone Completion Report Life Cycle ... Analysis Activities at National Renewable Energy Laboratory Life Cycle Assessment of ...

  3. Co-production of Hydrogen and Electricity (A Developer's Perspective...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Electricity (A Developer's Perspective) FuelCell Energy Overview, Direct Fuel Cell (DFC) Technology Status, Hydrogen Co-production Technology, Benefits and Status, Strategic...

  4. Life Cycle Assessment of Hydrogen Production via Natural Gas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental ...

  5. Technoeconomic Boundary Analysis of Biological Pathways to Hydrogen Production

    SciTech Connect (OSTI)

    James, B. D.; Baum, G. N.; Perez, J.; Baum, K. N.

    2009-09-01

    Report documenting the biological and engineering characteristics of five algal and bacterial hydrogen production systems selected by DOE and NREL for evaluation.

  6. NREL Photoelectrode Research Advances Hydrogen Production Efforts

    SciTech Connect (OSTI)

    Gu, Jing

    2015-12-01

    Scientists have created a high-performing photoelectrode that boosts the ability of solar water-splitting to produce hydrogen.

  7. 2014 Electrolytic Hydrogen Production Workshop Summary Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Materials durability Lower-temperature SOEC materials Long-term integrated ... grid services (frequencyvoltage regulation), renewable hydrogen for petroleum ...

  8. Methods and systems for the production of hydrogen

    DOE Patents [OSTI]

    Oh, Chang H. (Idaho Falls, ID); Kim, Eung S. (Ammon, ID); Sherman, Steven R. (Augusta, GA)

    2012-03-13

    Methods and systems are disclosed for the production of hydrogen and the use of high-temperature heat sources in energy conversion. In one embodiment, a primary loop may include a nuclear reactor utilizing a molten salt or helium as a coolant. The nuclear reactor may provide heat energy to a power generation loop for production of electrical energy. For example, a supercritical carbon dioxide fluid may be heated by the nuclear reactor via the molten salt and then expanded in a turbine to drive a generator. An intermediate heat exchange loop may also be thermally coupled with the primary loop and provide heat energy to one or more hydrogen production facilities. A portion of the hydrogen produced by the hydrogen production facility may be diverted to a combustor to elevate the temperature of water being split into hydrogen and oxygen by the hydrogen production facility.

  9. Ceramic Membranes for Hydrogen/Oxygen Production - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Startup America Startup America Industrial Technologies Industrial Technologies Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Ceramic Membranes for Hydrogen/Oxygen Production Ceramic Membranes Developed at Argonne May Bring Fuel-Cell Cars Closer to Reality Argonne National Laboratory Contact ANL About This Technology Technology Marketing Summary In the long term, hydrogen is expected to be the fuel of choice for both the

  10. Renewable Hydrogen Production at Hickam Air Force Base | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy at Hickam Air Force Base Renewable Hydrogen Production at Hickam Air Force Base Presented at the Renewable Hydrogen Workshop, Nov. 16, 2009, in Palm Springs, CA PDF icon renewable_hydrogen_workshop_nov16_quinn.pdf More Documents & Publications Hickam Air Force Base Fuel Cell Vehicles: Early Implementation Experience Fuel Cell Hybrid Bus Lands at Hickam AFB: Hydrogen Fuel Cell & Infrastructure Technologies Program, Fuel Cell Bus Demonstration Project (Fact Sheet) Hawaii

  11. Production of negative hydrogen ions on metal grids

    SciTech Connect (OSTI)

    Oohara, W.; Maetani, Y.; Takeda, Takashi; Takeda, Toshiaki; Yokoyama, H.; Kawata, K.

    2015-03-15

    Negative hydrogen ions are produced on a nickel grid with positive-ion irradiation. In order to investigate the production mechanism, a copper grid without the chemisorption of hydrogen atoms and positive helium ions without negative ionization are used for comparison. Positive hydrogen ions reflected on the metal surface obtain two electrons from the surface and become negatively ionized. It is found that the production yield of negative ions by desorption ionization of chemisorbed hydrogen atoms seems to be small, and the production is a minor mechanism.

  12. Hydrogen Production and Storage for Fuel Cells: Current Status | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy and Storage for Fuel Cells: Current Status Hydrogen Production and Storage for Fuel Cells: Current Status Presented at the Clean Energy States Alliance and U.S. Department of Energy Webinar: Hydrogen Production and Storage for Fuel Cells, February 2, 2011. PDF icon infocallfeb11_lipman.pdf More Documents & Publications Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined Heat and Power Systems Financing Fuel Cells The Department of Energy Hydrogen and Fuel Cells

  13. Hydrogen Production: Microbial Biomass Conversion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Microbial Biomass Conversion Hydrogen Production: Microbial Biomass Conversion Photo of a fermentation reactor Microbial biomass conversion processes take advantage of the ability of microorganisms to consume and digest biomass and release hydrogen. Depending on the pathway, this research could result in commercial-scale systems in the mid- to long-term timeframe that could be suitable for distributed, semi-central, or central hydrogen production scales, depending on the feedstock used. How Does

  14. Waste/By-Product Hydrogen | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Waste/By-Product Hydrogen Waste/By-Product Hydrogen Presentation by Ruth Cox, Fuel Cell and Hydrogen Energy Association, at the DOE-DOD Waste-to-Energy using Fuel Cells Workshop held Jan. 13, 2011 PDF icon waste_cox.pdf More Documents & Publications Biogas Technologies and Integration with Fuel Cells Tri-Generation Success Story: World's First Tri-Gen Energy Station-Fountain Valley Biogas and Fuel Cells

  15. Hydrogen production from water: Recent advances in photosynthesis research

    SciTech Connect (OSTI)

    Greenbaum, E.; Lee, J.W.

    1997-12-31

    The great potential of hydrogen production by microalgal water splitting is predicated on quantitative measurement of the algae`s hydrogen-producing capability, which is based on the following: (1) the photosynthetic unit size of hydrogen production; (2) the turnover time of photosynthetic hydrogen production; (3) thermodynamic efficiencies of conversion of light energy into the Gibbs free energy of molecular hydrogen; (4) photosynthetic hydrogen production from sea water using marine algae; (5) the potential for research advances using modern methods of molecular biology and genetic engineering to maximize hydrogen production. ORNL has shown that sustained simultaneous photoevolution of molecular hydrogen and oxygen can be performed with mutants of the green alga Chlamydomonas reinhardtii that lack a detectable level of the Photosystem I light reaction. This result is surprising in view of the standard two-light reaction model of photosynthesis and has interesting scientific and technological implications. This ORNL discovery also has potentially important implications for maximum thermodynamic conversion efficiency of light energy into chemical energy by green plant photosynthesis. Hydrogen production performed by a single light reaction, as opposed to two, implies a doubling of the theoretically maximum thermodynamic conversion efficiency from {approx}10% to {approx}20%.

  16. Process for the thermochemical production of hydrogen

    DOE Patents [OSTI]

    Norman, John H. (La Jolla, CA); Russell, Jr., John L. (La Jolla, CA); Porter, II, John T. (Del Mar, CA); McCorkle, Kenneth H. (Del Mar, CA); Roemer, Thomas S. (Cardiff, CA); Sharp, Robert (Del Mar, CA)

    1978-01-01

    Hydrogen is thermochemically produced from water in a cycle wherein a first reaction produces hydrogen iodide and H.sub.2 SO.sub.4 by the reaction of iodine, sulfur dioxide and water under conditions which cause two distinct aqueous phases to be formed, i.e., a lighter sulfuric acid-bearing phase and a heavier hydrogen iodide-bearing phase. After separation of the two phases, the heavier phase containing most of the hydrogen iodide is treated, e.g., at a high temperature, to decompose the hydrogen iodide and recover hydrogen and iodine. The H.sub.2 SO.sub.4 is pyrolyzed to recover sulfur dioxide and produce oxygen.

  17. Maximizing Light Utilization Efficiency and Hydrogen Production in Microalgal Cultures

    SciTech Connect (OSTI)

    Melis, Anastasios

    2014-12-31

    The project addressed the following technical barrier from the Biological Hydrogen Production section of the Fuel Cell Technologies Program Multi-Year Research, Development and Demonstration Plan: Low Sunlight Utilization Efficiency in Photobiological Hydrogen Production is due to a Large Photosystem Chlorophyll Antenna Size in Photosynthetic Microorganisms (Barrier AN: Light Utilization Efficiency).

  18. Solar and Wind Technologies for Hydrogen Production Report to Congress

    SciTech Connect (OSTI)

    None, None

    2005-12-01

    DOE's Solar and Wind Technologies for Hydrogen Production Report to Congress summarizes the technology roadmaps for solar- and wind-based hydrogen production. Published in December 2005, it fulfills the requirement under section 812 of the Energy Policy Act of 2005.

  19. FCRPS Hydro Projects (generation/hydro)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydro Power FCRPS Hydro Projects FCRPS Information Kiosk Current Hydrological Info Fish Funding Agreement FCRPS Definitions Wind Power Monthly GSP BPA White Book Dry Year...

  20. Anti-reflective nanoporous silicon for efficient hydrogen production

    DOE Patents [OSTI]

    Oh, Jihun; Branz, Howard M

    2014-05-20

    Exemplary embodiments are disclosed of anti-reflective nanoporous silicon for efficient hydrogen production by photoelectrolysis of water. A nanoporous black Si is disclosed as an efficient photocathode for H.sub.2 production from water splitting half-reaction.

  1. Designing catalysts for hydrogen production | Center for Bio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    catalysts for hydrogen production 12 Oct 2012 Dr. Anne Jones is a Principal Investigator in the Center of Bio-Inspired Solar Fuel production at Arizona State University. Her lab is...

  2. Structured material for the production of hydrogen

    DOE Patents [OSTI]

    Flickinger, Michael C.; Harwood, Caroline S.; Rey, Federico

    2010-06-29

    The present invention provides composite biological devices that include biological material as an integral component thereof. The devices can be used for producing hydrogen gas, for example.

  3. Hydrogen Production: Biomass-Derived Liquid Reforming

    Broader source: Energy.gov [DOE]

    Liquids derived from biomass resources—including ethanol and bio-oils—can be reformed to produce hydrogen in a process similar to natural gas reforming.

  4. Techno-economic Analysis of PEM Electrolysis for Hydrogen Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PEM Electrolysis for Hydrogen Production Strategic Analysis Inc. Whitney G. Colella Brian D. James Jennie M. Moton NREL Genevieve Saur Todd Ramsden Electrolytic Hydrogen Production Workshop NREL, Golden, Colorado 27 February 2014 2 Introduction and Purpose 2 * Analyze H 2 Production & Delivery (P&D) pathways to determine the most economical, environmentally-benign, and societally- feasible paths forward for the production and delivery of H 2 fuel for fuel cell vehicles (FCVs). *

  5. Hydrogen production by the decomposition of water

    DOE Patents [OSTI]

    Hollabaugh, C.M.; Bowman, M.G.

    A process is described for the production of hydrogen from water by a sulfuric acid process employing electrolysis and thermo-chemical decomposition. The water containing SO/sub 2/ is electrolyzed to produce H/sub 2/ at the cathode and to oxidize the SO/sub 2/ to form H/sub 2/SO/sub 4/ at the anode. After the H/sub 2/ has been separated, a compound of the type M/sub r/X/sub s/ is added to produce a water insoluble sulfate of M and a water insoluble oxide of the metal in the radical X. In the compound M/sub r/X/sub s/, M is at least one metal selected from the group consisting of Ba/sup 2 +/, Ca/sup 2 +/, Sr/sup 2 +/, La/sup 2 +/, and Pb/sup 2 +/; X is at least one radical selected from the group consisting of molybdate (MoO/sub 4//sup 2 -/), tungstate (WO/sub 4//sup 2 -/), and metaborate (BO/sub 2//sup 1 -/); and r and s are either 1, 2, or 3 depending upon the valence of M and X. The precipitated mixture is filtered and heated to a temperature sufficiently high to form SO/sub 3/ gas and to reform M/sub r/X/sub s/. The SO/sub 3/ is dissolved in a small amount of H/sub 2/O to produce concentrated H/sub 2/SO/sub 4/, and the M/sub r/X/sub s/ is recycled to the process. Alternatively, the SO/sub 3/ gas can be recycled to the beginning of the process to provide a continuous process for the production of H/sub 2/ in which only water need be added in a substantial amount. (BLM)

  6. Process for the production of hydrogen peroxide

    DOE Patents [OSTI]

    Datta, R.; Randhava, S.S.; Tsai, S.P.

    1997-09-02

    An integrated membrane-based process method for producing hydrogen peroxide is provided comprising oxidizing hydrogenated anthraquinones with air bubbles which were created with a porous membrane, and then contacting the oxidized solution with a hydrophilic membrane to produce an organics free, H{sub 2}O{sub 2} laden permeate. 1 fig.

  7. Process for the production of hydrogen peroxide

    DOE Patents [OSTI]

    Datta, Rathin (Chicago, IL); Randhava, Sarabjit S. (Evanston, IL); Tsai, Shih-Perng (Naperville, IL)

    1997-01-01

    An integrated membrane-based process method for producing hydrogen peroxide is provided comprising oxidizing hydrogenated anthraquinones with air bubbles which were created with a porous membrane, and then contacting the oxidized solution with a hydrophilic membrane to produce an organics free, H.sub.2 O.sub.2 laden permeate.

  8. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review

    SciTech Connect (OSTI)

    none,

    2011-10-01

    This independent review is the conclusion arrived at from data collection, document reviews, interviews and deliberation from December 2010 through April 2011 and the technical potential of Hydrogen Production Cost Estimate Using Biomass Gasification. The Panel reviewed the current H2A case (Version 2.12, Case 01D) for hydrogen production via biomass gasification and identified four principal components of hydrogen levelized cost: CapEx; feedstock costs; project financing structure; efficiency/hydrogen yield. The panel reexamined the assumptions around these components and arrived at new estimates and approaches that better reflect the current technology and business environments.

  9. Hydrogen production with coal using a pulverization device

    DOE Patents [OSTI]

    Paulson, Leland E. (Morgantown, WV)

    1989-01-01

    A method for producing hydrogen from coal is described wherein high temperature steam is brought into contact with coal in a pulverizer or fluid energy mill for effecting a steam-carbon reaction to provide for the generation of gaseous hydrogen. The high temperature steam is utilized to drive the coal particles into violent particle-to-particle contact for comminuting the particulates and thereby increasing the surface area of the coal particles for enhancing the productivity of the hydrogen.

  10. Process for the production of hydrogen from water

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Maroni, Victor A. (Naperville, IL); Willit, James L. (Batavia, IL)

    2010-05-25

    A method and device for the production of hydrogen from water and electricity using an active metal alloy. The active metal alloy reacts with water producing hydrogen and a metal hydroxide. The metal hydroxide is consumed, restoring the active metal alloy, by applying a voltage between the active metal alloy and the metal hydroxide. As the process is sustainable, only water and electricity is required to sustain the reaction generating hydrogen.

  11. Integrated Boiler, Superheater & Decomposer Bayonet for Hydrogen Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Industrial Technologies Industrial Technologies Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Integrated Boiler, Superheater & Decomposer Bayonet for Hydrogen Production Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (906 KB) Technology Marketing SummaryWith the growing pressure placed on energy efficiency and reliance

  12. Methods and Systems for the Production of Hydrogen - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Methods and Systems for the Production of Hydrogen Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL has developed a novel process for producing hydrogen using a reduced outlet temperature of Very High Temperature Gas Cooled Reactor. This process uses a combination of hydrogen recycle, a molten salt or helium, and a supercritical CO2 cycle. This method preheats the feed, reduces pumping power in the primary side and/or thermal transmission

  13. 2014 Electrolytic Hydrogen Production Workshop Summary Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    About the Cover (Photos from top to bottom) A vehicle refueling at an electrolysis-based fueling station. Photo courtesy of Proton OnSite. A vehicle refuels at an ITM Power mobile refueler. Photo courtesy of ITM Power. Dr. Kevin Harrison inspects a hydrogen-producing electrolyzer system. Photographer: Greg Martin. Photo courtesy of NREL. (NREL 23852-C) Shell's Santa Monica Blvd. hydrogen fueling station in west Los Angeles. Photographer: Keith Wipke. Photo courtesy of NREL. (NREL 17321) Vehicles

  14. DOE Technical Targets for Hydrogen Production from Thermochemical...

    Broader source: Energy.gov (indexed) [DOE]

    cost per TPD H2d yr-TPD H2 NA 1.47M 89K 11K Solar to hydrogen (STH) energy conversion ratioe,f % NA 10 20 26 1-sun hydrogen production rateg kgs per m2 NA 8.1E-7 1.6E-6 2.1E-6 a ...

  15. DOE Technical Targets for Hydrogen Production from Photoelectrochemica...

    Broader source: Energy.gov (indexed) [DOE]

    per TPD H2d yr-TPD H2 NA 2.0M 255K 14K Solar to hydrogen (STH) energy conversion ratioe,f % 4 to 12 15 20 25 1-sun hydrogen production rateg kgs per m2 3.3E-7 1.2E-6 1.6E-6 ...

  16. Carbonate thermochemical cycle for the production of hydrogen

    DOE Patents [OSTI]

    Collins, Jack L (Knoxville, TN) [Knoxville, TN; Dole, Leslie R (Knoxville, TN) [Knoxville, TN; Ferrada, Juan J (Knoxville, TN) [Knoxville, TN; Forsberg, Charles W (Oak Ridge, TN) [Oak Ridge, TN; Haire, Marvin J (Oak Ridge, TN) [Oak Ridge, TN; Hunt, Rodney D (Oak Ridge, TN) [Oak Ridge, TN; Lewis Jr., Benjamin E (Knoxville, TN) [Knoxville, TN; Wymer, Raymond G (Oak Ridge, TN) [Oak Ridge, TN

    2010-02-23

    The present invention is directed to a thermochemical method for the production of hydrogen from water. The method includes reacting a multi-valent metal oxide, water and a carbonate to produce an alkali metal-multi-valent metal oxide compound, carbon dioxide, and hydrogen.

  17. On-Board Hydrogen Gas Production System For Stirling Engines

    DOE Patents [OSTI]

    Johansson, Lennart N. (Ann Arbor, MI)

    2004-06-29

    A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated Stirling engine. The hydrogen gas may be generated by various techniques including electrolysis and stored by various means including the use of a metal hydride absorbing material. By controlling the temperature of the absorbing material, the stored hydrogen gas may be provided to the Stirling engine as needed. A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated Stirling engine. The hydrogen gas may be generated by various techniques including electrolysis and stored by various means including the use of a metal hydride absorbing material. By controlling the temperature of the absorbing material, the stored hydrogen gas may be provided to the Stirling engine as needed.

  18. Hydrogen Production and Consumption in the U.S.: The Last 25...

    Office of Scientific and Technical Information (OSTI)

    Hydrogen Production and Consumption in the U.S.: The Last 25 Years. Brown, Daryl R. hydrogen; production; U.S.; merchant; captive hydrogen; production; U.S.; merchant; captive This...

  19. Vacancy Announcements Posted for Hydrogen Production and Delivery Program

    Broader source: Energy.gov [DOE]

    The Fuel Cell Technologies Office has posted two vacancy announcements for a position to serve as Program Manager for the Hydrogen Production and Delivery Program in the DOE EERE Fuel Cell Technologies Office. The closing date is October 28, 2014.

  20. Hydrogen Production and Dispensing Facility Opens at W. Va. Airport

    Broader source: Energy.gov [DOE]

    A hydrogen production and dispensing station constructed and operated with support from the Office of Fossil Energy's National Energy Technology Laboratory was officially opened Monday at the Yeager Airport in Charleston, W.Va.

  1. Potential for Hydrogen Production from Key Renewable Resources...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Potential for Hydrogen Production from Key Renewable Resources in the United States A. Milbrandt and M. Mann Technical Report NRELTP-640-41134 February 2007 NREL is operated by...

  2. Hydro Alternative Energy | Open Energy Information

    Open Energy Info (EERE)

    Alternative Energy Jump to: navigation, search Name: Hydro Alternative Energy Place: Boca Raton, Florida Zip: 33486 Sector: Ocean Product: Marine project developer focusing on...

  3. HydroVolts | Open Energy Information

    Open Energy Info (EERE)

    Hydro Product: Aims to develop renewable energy from canals, waterways, streams, and ocean currents Website: www.hydrovolts.com Coordinates: 47.645778, -122.3257532 Show...

  4. First Hydro Company | Open Energy Information

    Open Energy Info (EERE)

    Company Jump to: navigation, search Name: First Hydro Company Place: Flintshire, England, United Kingdom Zip: CH5 3XJ Sector: Renewable Energy Product: Flintshire-based renewable...

  5. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Presented at the 2007...

  6. Current (2009) State-of-the-Art Hydrogen Production Cost Estimate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water ...

  7. Workshop Tackles Biological Hydrogen Production - News Releases | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workshop Tackles Biological Hydrogen Production Available report outlines goals, challenges, and research areas October 21, 2003 Golden, Colo. - The results of a two-day workshop on hydrogen production through biological and artificial systems now is available. The workshop, sponsored by the Air Force Office of Scientific Research and hosted jointly by the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) and the Air Force Research Laboratory (AFRL), included key

  8. NGNP Process Heat Applications: Hydrogen Production Accomplishments for FY2010

    SciTech Connect (OSTI)

    Charles V Park

    2011-01-01

    This report summarizes FY10 accomplishments of the Next Generation Nuclear Plant (NGNP) Engineering Process Heat Applications group in support of hydrogen production technology development. This organization is responsible for systems needed to transfer high temperature heat from a high temperature gas-cooled reactor (HTGR) reactor (being developed by the INL NGNP Project) to electric power generation and to potential industrial applications including the production of hydrogen.

  9. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review | Department of Energy Cost Estimate Using Biomass Gasification: Independent Review Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review This independent review is the conclusion arrived at from data collection, document reviews, interviews and deliberation from December 2010 through April 2011 and the technical potential of Hydrogen Production Cost Estimate Using Biomass Gasification The Panel reviewed the current H2A case (Version 2.12, Case 01D) for

  10. Bioelectrocatalysis of hydrogen oxidation/production by hydrogenases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioelectrocatalysis of hydrogen oxidation/production by hydrogenases Authors: Jones, A.K., McIntosh, C.L., Dutta, A., Kwan, P., Roy, S., Yang, S. Title: Bioelectrocatalysis of hydrogen oxidation/production by hydrogenases Source: In: Enzymatic fuel cells: From fundamentals to applications. Edited by H. Luckarift, G. Johnson and P. Attanasov, Wiley-VCH, Weinheim, Germany Year: 2013 Volume: in press Pages: ABSTRACT: Date of online publication: Link online: http://solarfuel.clas.asu.edu/

  11. Hydrogen Production Roadmap: Technology Pathways to the Future

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    FreedomCAR and Fuel Partnership Hydrogen Production Technical Team This roadmap was created by the Hydrogen Production Technical Team (HPTT) of the FreedomCAR and Fuel Partnership. This is a partnership of industry's U.S. Council for Automotive Research (USCAR), energy companies and the U.S. Department of Energy (DOE) to advance technologies that enable reduced oil consumption and increased energy efficiency in passenger vehicles. The Partnership focuses on the pre-competitive, high-risk

  12. Hydrogen Production by High Temperature Electrolysis with Nuclear Reactor

    SciTech Connect (OSTI)

    Ogawa, Takashi; Fujiwara, Seiji; Kasai, Shigeo; Yamada, Kazuya

    2007-07-01

    In this paper, we report our design of high temperature electrolysis plant system and the analysis results. The system efficiency increases with the increase of the steam utilization in the solid oxide electrolysis cell (SOEC) or the decrease of the hydrogen recycle (hydrogen recycle flow to product hydrogen flow) ratio,. The system efficiency is nearly independent of the SOEC operating temperature and pressure, and the air to product O{sub 2} ratio. In this study, the maximum system efficiency is 56.3%. (authors)

  13. Hydrogen production by the decomposition of water

    DOE Patents [OSTI]

    Hollabaugh, Charles M.; Bowman, Melvin G.

    1981-01-01

    How to produce hydrogen from water was a problem addressed by this invention. The solution employs a combined electrolytical-thermochemical sulfuric acid process. Additionally, high purity sulfuric acid can be produced in the process. Water and SO.sub.2 react in electrolyzer (12) so that hydrogen is produced at the cathode and sulfuric acid is produced at the anode. Then the sulfuric acid is reacted with a particular compound M.sub.r X.sub.s so as to form at least one water insoluble sulfate and at least one water insoluble oxide of molybdenum, tungsten, or boron. Water is removed by filtration; and the sulfate is decomposed in the presence of the oxide in sulfate decomposition zone (21), thus forming SO.sub.3 and reforming M.sub.r X.sub.s. The M.sub.r X.sub.s is recycled to sulfate formation zone (16). If desired, the SO.sub.3 can be decomposed to SO.sub.2 and O.sub.2 ; and the SO.sub.2 can be recycled to electrolyzer (12) to provide a cycle for producing hydrogen.

  14. Onboard Plasmatron Hydrogen Production for Improved Vehicles

    SciTech Connect (OSTI)

    Daniel R. Cohn; Leslie Bromberg; Kamal Hadidi

    2005-12-31

    A plasmatron fuel reformer has been developed for onboard hydrogen generation for vehicular applications. These applications include hydrogen addition to spark-ignition internal combustion engines, NOx trap and diesel particulate filter (DPF) regeneration, and emissions reduction from spark ignition internal combustion engines First, a thermal plasmatron fuel reformer was developed. This plasmatron used an electric arc with relatively high power to reform fuels such as gasoline, diesel and biofuels at an oxygen to carbon ratio close to 1. The draw back of this device was that it has a high electric consumption and limited electrode lifetime due to the high temperature electric arc. A second generation plasmatron fuel reformer was developed. It used a low-current high-voltage electric discharge with a completely new electrode continuation. This design uses two cylindrical electrodes with a rotating discharge that produced low temperature volumetric cold plasma., The lifetime of the electrodes was no longer an issue and the device was tested on several fuels such as gasoline, diesel, and biofuels at different flow rates and different oxygen to carbon ratios. Hydrogen concentration and yields were measured for both the thermal and non-thermal plasmatron reformers for homogeneous (non-catalytic) and catalytic reforming of several fuels. The technology was licensed to an industrial auto part supplier (ArvinMeritor) and is being implemented for some of the applications listed above. The Plasmatron reformer has been successfully tested on a bus for NOx trap regeneration. The successful development of the plasmatron reformer and its implementation in commercial applications including transportation will bring several benefits to the nation. These benefits include the reduction of NOx emissions, improving engine efficiency and reducing the nation's oil consumption. The objective of this program has been to develop attractive applications of plasmatron fuel reformer technology for onboard applications in internal combustion engine vehicles using diesel, gasoline and biofuels. This included the reduction of NOx and particulate matter emissions from diesel engines using plasmatron reformer generated hydrogen-rich gas, conversion of ethanol and bio-oils into hydrogen rich gas, and the development of new concepts for the use of plasmatron fuel reformers for enablement of HCCI engines.

  15. Hydro | Open Energy Information

    Open Energy Info (EERE)

    Page Edit History Hydro Jump to: navigation, search Hydro or hydroelectric systems capture the energy in naturally flowing water and convert it to electricity. Related Links List...

  16. Hydro | Open Energy Information

    Open Energy Info (EERE)

    Page Edit History Hydro (Redirected from Hydropower) Jump to: navigation, search Hydro or hydroelectric systems capture the energy in naturally flowing water and convert it to...

  17. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    60-42773 February 2009 Hydrogen Resource Assessment Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power Anelia Milbrandt and Margaret Mann National Renewable Energy...

  18. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOE Patents [OSTI]

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  19. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  20. Discovery of Photocatalysts for Hydrogen Production

    SciTech Connect (OSTI)

    D. Brent MacQueen

    2006-10-01

    This project for DOE was designed to address these materials-related issues through a combination of high-throughput screening of semiconductor candidates and theoretical modeling of nanostructures. High-throughput screening is an effective and economical way to examine a large number of candidates and identify those worthy of further study. Unfortunately, in the course of this project, we discovered no semiconductor candidates that can meet the DOEs stringent requirements for an economically feasible photoelectrochemical process. However, some of our results indicated that several systems may have potential if further optimized. In particular, the published theoretical modeling work indicates that core-shell nanorod structures, if properly engineered, have the potential to overcome the shortfalls of current semiconductors. Although the synthesis of the designed core-shell nanorod structures proved to be beyond the current capabilities of our laboratories, recent advances in the synthesis of core-shell nanorod structures imply that the designed structures can be synthesized. SRI is confident that once these materials are made they will validate our models and lead to economical and environmentally friendly hydrogen from sunlight and water. The high-throughput photolysis analysis module developed at SRI will also have utility in applications such as identifying catalysts for photo-assisted chemical detoxification, as well as non-photolytic applications such as hydrogen storage, which can take advantage of the ability of the analysis module to monitor pressure over time.

  1. HydroChina ZhongNan Engineering Corp | Open Energy Information

    Open Energy Info (EERE)

    ZhongNan Engineering Corp Jump to: navigation, search Name: HydroChina ZhongNan Engineering Corp Place: Hunan Province, China Sector: Hydro, Wind energy Product: Hunan...

  2. Metallic Membrane Materials Development for Hydrogen Production...

    Office of Scientific and Technical Information (OSTI)

    PRODUCTION; GREENHOUSE GASES The goals of Office of Clean Coal are: (1) Improved energy security; (2) Reduced green house gas emissions; (3) High tech job creation; and...

  3. Analyzing the Levelized Cost of Centralized and Distributed Hydrogen Production Using the H2A Production Model, Version 2

    SciTech Connect (OSTI)

    Ramsden, T.; Steward, D.; Zuboy, J.

    2009-09-01

    Analysis of the levelized cost of producing hydrogen via different pathways using the National Renewable Energy Laboratory's H2A Hydrogen Production Model, Version 2.

  4. EVermont Renewable Hydrogen Production and Transportation Fueling System

    SciTech Connect (OSTI)

    Garabedian, Harold T. Wight, Gregory Dreier, Ken Borland, Nicholas

    2008-03-30

    A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable transportation energy capable system. The prime energy for this project comes from an agreement with a wind turbine operator.

  5. The plutonium-hydrogen reaction: SEM characterization of product morphology

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect The plutonium-hydrogen reaction: SEM characterization of product morphology Citation Details In-Document Search Title: The plutonium-hydrogen reaction: SEM characterization of product morphology Authors: Dinh, L N ; McCall, S K ; Saw, C K ; Haschke, J M ; Allen, P G ; McClean II, W Publication Date: 2013-12-23 OSTI Identifier: 1150726 Report Number(s): LLNL-JRNL-648158 DOE Contract Number: DE-AC52-07NA27344 Resource Type: Journal Article Resource Relation:

  6. Thermochemical cycles for the production of hydrogen

    DOE Patents [OSTI]

    Steinberg, M.; Dang, V.D.

    Two-step processes for the preparation of hydrogen are described: CrCl/sub 3/(g) ..-->.. CrCl/sub 2/(g) + 1/2Cl/sub 2/(g) and CrCl/sub 2/(s) + HCl(g) reversible CrCl/sub 3/(s) + 1/2H/sub 2/(g); UCl/sub 4/(g) ..-->.. UCl/sub 3/(g) + 1/2Cl/sub 2/(g) and UCl/sub 3/(s) + HCl(g) ..-->.. UCl/sub 4/(s) + 1/2H/sub 2/(g); and CaSO/sub 4/(s) ..-->.. CaO(s) + SO/sub 2/(g) + 1/2O/sub 2/(g) and CaO(s) + SO/sub 2/(g) + H/sub 2/O(l) ..-->.. CaSO/sub 4/(s) + H/sub 2/(g). The high temperature available from solar collectors, high temperature gas reactors or fusion reactors is utilized in the first step in which the reaction is endothermic. The efficiency is at least 60% and with process heat recovery, the efficiency may be increased up to 74.4%. An apparatus fr carrying out the process in conjunction with a fusion reactor, is described.

  7. DOE Issues 2 Requests for Information on Low-Cost Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for information (RFIs) seeking feedback from the research community and relevant stakeholders about hydrogen production and hydrogen delivery research, development, and...

  8. Designer proton-channel transgenic algae for photobiological hydrogen production

    DOE Patents [OSTI]

    Lee, James Weifu

    2011-04-26

    A designer proton-channel transgenic alga for photobiological hydrogen production that is specifically designed for production of molecular hydrogen (H.sub.2) through photosynthetic water splitting. The designer transgenic alga includes proton-conductive channels that are expressed to produce such uncoupler proteins in an amount sufficient to increase the algal H.sub.2 productivity. In one embodiment the designer proton-channel transgene is a nucleic acid construct (300) including a PCR forward primer (302), an externally inducible promoter (304), a transit targeting sequence (306), a designer proton-channel encoding sequence (308), a transcription and translation terminator (310), and a PCR reverse primer (312). In various embodiments, the designer proton-channel transgenic algae are used with a gas-separation system (500) and a gas-products-separation and utilization system (600) for photobiological H.sub.2 production.

  9. DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program Integrated Hydrogen Production, Purification and Compression System

    SciTech Connect (OSTI)

    Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

    2011-06-30

    The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of <$1.50/gge, which was later revised by DOE to $2-$3/gge range for hydrogen to be competitive with gasoline as a fuel for vehicles. For small, on-site hydrogen plants being evaluated at the time for refueling stations (the 'forecourt'), it was determined that capital cost is the main contributor to the high cost of delivered hydrogen. The concept of this project was to reduce the cost by combining unit operations for the entire generation, purification, and compression system (refer to Figure 1). To accomplish this, the Fluid Bed Membrane Reactor (FBMR) developed by MRT was used. The FBMR has hydrogen selective, palladium-alloy membrane modules immersed in the reformer vessel, thereby directly producing high purity hydrogen in a single step. The continuous removal of pure hydrogen from the reformer pushes the equilibrium 'forward', thereby maximizing the productivity with an associated reduction in the cost of product hydrogen. Additional gains were envisaged by the integration of the novel Metal Hydride Hydrogen Compressor (MHC) developed by Ergenics, which compresses hydrogen from 0.5 bar (7 psia) to 350 bar (5,076 psia) or higher in a single unit using thermal energy. Excess energy from the reformer provides up to 25% of the power used for driving the hydride compressor so that system integration improved efficiency. Hydrogen from the membrane reformer is of very high, fuel cell vehicle (FCV) quality (purity over 99.99%), eliminating the need for a separate purification step. The hydride compressor maintains hydrogen purity because it does not have dynamic seals or lubricating oil. The project team set out to integrate the membrane reformer developed by MRT and the hydride compression system developed by Ergenics in a single package. This was expected to result in lower cost and higher efficiency compared to conventional hydrogen production technologies. The overall objective was to develop an integrated system to directly produce high pressure, high-purity hydrogen from a single unit, which can meet the DOE cost H2 cost target of $2 - $3/gge when mass produced. The project was divided into two phases with the following tasks and corresponding milestones, targets and decision points. Phase 1 - Task 1 - Verify feasibility of the concept, perform a detailed techno-economic analysis, and develop a test plan; and Task 2: Build and experimentally test a Proof of Concept (POC) integrated membrane reformer/metal hydride compressor system. Phase 2 - Task 3: Build an Advanced Prototype (AP) system with modifications based on POC learning and demonstrate at a commercial site; and Task 4: Complete final product design for mass manufacturing units capable of achieving DOE 2010 H2 cost and performance targets.

  10. DOE Technical Targets for Hydrogen Production from Photoelectrochemical Water Splitting

    Broader source: Energy.gov [DOE]

    These tables list the U.S. Department of Energy (DOE) technical targets and example cost and performance parameter values that achieve the targets for hydrogen production from photoelectrochemical water splitting. The tables are organized into separate sections for photoelectrode systems and dual bed photocatalyst systems.

  11. Livermore team awarded for hydrogen production research | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration team awarded for hydrogen production research | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo

  12. Webinar: Hydrogen Production by Polymer Electrolyte Membrane (PEM)

    Broader source: Energy.gov (indexed) [DOE]

    Electrolysis-Spotlight on Giner and Proton | Department of Energy Above is the video recording for the webinar, "Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis-Spotlight on Giner and Proton," originally held on May 23, 2011. In addition to this recording, you can access the presentation slides

  13. Company Name Company Name Address Place Zip Sector Product Website

    Open Energy Info (EERE)

    ANV Partners ANV Partners Denver Colorado Hydro Hydrogen Services Solar Wind energy AQWON Motors AQWON Motors Speinshart Germany Hydro Hydrogen AQWON Motors has developed the first...

  14. Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels

    SciTech Connect (OSTI)

    University of Central Florida

    2004-01-30

    The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

  15. Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants

    SciTech Connect (OSTI)

    Stephen Schey

    2009-07-01

    Cooperative Agreement DE-FC07-06ID14788 was executed between the U.S. Department of Energy, Electric Transportation Applications, and Idaho National Laboratory to investigate the economics of producing hydrogen by electrolysis using electricity generated by nuclear power. The work under this agreement is divided into the following four tasks: Task 1 – Produce Data and Analyses Task 2 – Economic Analysis of Large-Scale Alkaline Electrolysis Task 3 – Commercial-Scale Hydrogen Production Task 4 – Disseminate Data and Analyses. Reports exist on the prospect that utility companies may benefit from having the option to produce electricity or produce hydrogen, depending on market conditions for both. This study advances that discussion in the affirmative by providing data and suggesting further areas of study. While some reports have identified issues related to licensing hydrogen plants with nuclear plants, this study provides more specifics and could be a resource guide for further study and clarifications. At the same time, this report identifies other area of risks and uncertainties associated with hydrogen production on this scale. Suggestions for further study in some of these topics, including water availability, are included in the report. The goals and objectives of the original project description have been met. Lack of industry design for proton exchange membrane electrolysis hydrogen production facilities of this magnitude was a roadblock for a significant period. However, recent design breakthroughs have made costing this facility much more accurate. In fact, the new design information on proton exchange membrane electrolyzers scaled to the 1 kg of hydrogen per second electrolyzer reduced the model costs from $500 to $100 million. Task 1 was delayed when the original electrolyzer failed at the end of its economic life. However, additional valuable information was obtained when the new electrolyzer was installed. Products developed during this study include a process model and a N2H2 economic assessment model (both developed by the Idaho National Laboratory). Both models are described in this report. The N2H2 model closely tracked and provided similar results as the H2A model and was instrumental in assessing the effects of plant availability on price when operated in the shoulder mode for electrical pricing. Differences between the H2A and N2H2 model are included in this report.

  16. Low-Cost Hydrogen Distributed Production System Development

    SciTech Connect (OSTI)

    C.E. Thomas, Ph.D., President Franklin D. Lomax, Ph.D, CTO & Principal Investigator, and Maxim Lyubovski, Ph.D.

    2011-03-10

    H{sub 2}Gen, with the support of the Department of Energy, successfully designed, built and field-tested two steam methane reformers with 578 kg/day capacity, which has now become a standard commercial product serving customers in the specialty metals and PV manufacturing businesses. We demonstrated that this reformer/PSA system, when combined with compression, storage and dispensing (CSD) equipment could produce hydrogen that is already cost-competitive with gasoline per mile driven in a conventional (non-hybrid) vehicle. We further showed that mass producing this 578 kg/day system in quantities of just 100 units would reduce hydrogen cost per mile approximately 13% below the cost of untaxed gasoline per mile used in a hybrid electric vehicle. If mass produced in quantities of 500 units, hydrogen cost per mile in a FCEV would be 20% below the cost of untaxed gasoline in an HEV in the 2015-2020 time period using EIA fuel cost projections for natural gas and untaxed gasoline, and 45% below the cost of untaxed gasoline in a conventional car. This 20% to 45% reduction in fuel cost per mile would accrue even though hydrogen from this 578 kg/day system would cost approximately $4.14/kg, well above the DOE hydrogen cost targets of $2.50/kg by 2010 and $2.00/kg by 2015. We also estimated the cost of a larger, 1,500 kg/day SMR/PSA fueling system based on engineering cost scaling factors derived from the two H{sub 2}Gen products, a commercial 115 kg/day system and the 578 kg/day system developed under this DOE contract. This proposed system could support 200 to 250 cars per day, similar to a medium gasoline station. We estimate that the cost per mile from this larger 1,500 kg/day hydrogen fueling system would be 26% to 40% below the cost per mile of untaxed gasoline in an HEV and ICV respectively, even without any mass production cost reductions. In quantities of 500 units, we are projecting per mile cost reductions between 45% (vs. HEVs) and 62% (vs ICVs), with hydrogen costing approximately $2.87/kg, still above the DOE's 2010 $2.50/kg target. We also began laboratory testing of reforming ethanol, which we showed is currently the least expensive approach to making renewable hydrogen. Extended testing of neat ethanol in micro-reactors was successful, and we also were able to reform E-85 acquired from a local fueling station for 2,700 hours, although some modifications were required to handle the 15% gasoline present in E-85. We began initial tests of a catalyst-coated wall reformer tube that showed some promise in reducing the propensity to coke with E-85. These coated-wall tests ran for 350 hours. Additional resources would be required to commercialize an ethanol reformer operating on E-85, but there is no market for such a product at this time, so this ethanol reformer project was moth-balled pending future government or industry support. The two main objectives of this project were: (1) to design, build and test a steam methane reformer and pressure swing adsorption system that, if scaled up and mass produced, could potentially meet the DOE 2015 cost and efficiency targets for on-site distributed hydrogen generation, and (2) to demonstrate the efficacy of a low-cost renewable hydrogen generation system based on reforming ethanol to hydrogen at the fueling station.

  17. Assessment of methods for hydrogen production using concentrated solar energy

    SciTech Connect (OSTI)

    Glatzmaier, G.; Blake, D.; Showalter, S.

    1998-01-01

    The purpose of this work was to assess methods for hydrogen production using concentrated solar energy. The results of this work can be used to guide future work in the application of concentrated solar energy to hydrogen production. Specifically, the objectives were to: (1) determine the cost of hydrogen produced from methods that use concentrated solar thermal energy, (2) compare these costs to those of hydrogen produced by electrolysis using photovoltaics and wind energy as the electricity source. This project had the following scope of work: (1) perform cost analysis on ambient temperature electrolysis using the 10 MWe dish-Stirling and 200 MWe power tower technologies; for each technology, sue two cases for projected costs, years 2010 and 2020 the dish-Stirling system, years 2010 and 2020 for the power tower, (2) perform cost analysis on high temperature electrolysis using the 200 MWe power tower technology and projected costs for the year 2020, and (3) identify and describe the key technical issues for high temperature thermal dissociation and the thermochemical cycles.

  18. South Carolina Hydrogen and Fuel Cell Alliance | Open Energy...

    Open Energy Info (EERE)

    Hydrogen and Fuel Cell Alliance Jump to: navigation, search Name: South Carolina Hydrogen and Fuel Cell Alliance Place: Columbia, South Carolina Zip: 29201 Sector: Hydro, Hydrogen...

  19. Aiken County Center for Hydrogen Research | Open Energy Information

    Open Energy Info (EERE)

    Aiken County Center for Hydrogen Research Jump to: navigation, search Name: Aiken County Center for Hydrogen Research Place: South Carolina Zip: 29803 Sector: Hydro, Hydrogen...

  20. International Partnership for Hydrogen Energy IPHE | Open Energy...

    Open Energy Info (EERE)

    for Hydrogen Energy IPHE Jump to: navigation, search Name: International Partnership for Hydrogen Energy (IPHE) Place: Washington, Washington, DC Zip: 20004 Sector: Hydro, Hydrogen...

  1. Hydrogen Production and Consumption in the U.S.: The Last 25...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Hydrogen Production and Consumption in the U.S.: The Last 25 Years. Citation Details In-Document Search Title: Hydrogen Production and Consumption in the U.S.: The...

  2. Critical Updates to the Hydrogen Analysis Production Model (H2A...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Critical Updates to the Hydrogen Analysis Production Model (H2A v3) Critical Updates to the Hydrogen Analysis Production Model (H2A v3) Presentation slides from the February 8,...

  3. High-Efficiency Solar Thermochemical Reactor for Hydrogen Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency Solar Thermochemical Reactor for Hydrogen Production - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle

  4. Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis

    SciTech Connect (OSTI)

    none,

    2009-09-01

    This independent review examines DOE cost targets for state-of-the art hydrogen production using water electrolysis.

  5. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Presentation) | Department of Energy Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 04_h2gen_low-cost_h2_distributed_production_systems.pdf More Documents & Publications Low-Cost Hydrogen-from-Ethanol: A Distributed Production System

  6. On-Board Hydrogen Gas Production System For Stirling Engines (Patent) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Patent: On-Board Hydrogen Gas Production System For Stirling Engines Citation Details In-Document Search Title: On-Board Hydrogen Gas Production System For Stirling Engines A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated

  7. Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Electrolysis | Department of Energy Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis This is an independent review of the estimated 2009 state-of-the-art cost of producing hydrogen from both alkaline and PEM water electrolyzers for distributed and central production. PDF icon Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water

  8. Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis: Independent Review

    SciTech Connect (OSTI)

    Not Available

    2009-09-01

    This independent review examines DOE cost targets for state-of-the art hydrogen production using water electrolysis.

  9. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W.

    2008-09-30

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: Magnesium hydride slurry is stable for months and pumpable. The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (Milk of Magnesia) and magnesium oxide. We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

  10. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    SciTech Connect (OSTI)

    Francis Lau

    2002-12-01

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

  11. Development of efficient photoreactors for solar hydrogen production

    SciTech Connect (OSTI)

    Huang, Cunping; Yao, Weifeng; T-Raissi, Ali; Muradov, Nazim

    2011-01-15

    The rate of hydrogen evolution from a photocatalytic process depends not only on the activity of a photocatalyst, but also on photoreactor design. Ideally, a photoreactor should be able to absorb the incident light, promoting photocatalytic reactions in an effective manner with minimal photonic losses. There are numerous technical challenges and cost related issues when designing a large-scale photoreactor for hydrogen production. Active stirring of the photocatalyst slurry within a photoreactor is not practical in large-scale applications due to cost related issues. Rather, the design should allow facile self-mixing of the flow field within the photoreactor. In this paper two types of photocatalytic reactor configurations are studied: a batch type design and another involving passive self-mixing of the photolyte. Results show that energy loss from a properly designed photoreactor is mainly due to reflection losses from the photoreactor window. We describe the interplay between the reaction and the photoreactor design parameters as well as effects on the rate of hydrogen evolution. We found that a passive self-mixing of the photolyte is possible. Furthermore, the use of certain engineering polymer films as photoreactor window materials has the potential for substantial cost savings in large-scale applications, with minimal reduction of photon energy utilization efficiency. Eight window materials were tested and the results indicate that Aclar trademark polymer film used as the photoreactor window provides a substantial cost saving over other engineering polymers, especially with respect to fused silica glass at modest hydrogen evolution rates. (author)

  12. Pathway of Fermentative Hydrogen Production by Sulfate-reducing Bacteria

    SciTech Connect (OSTI)

    Wall, Judy D.

    2015-02-16

    Biofuels are a promising source of sustainable energy. Such biofuels are intermediate products of microbial metabolism of renewable substrates, in particular, plant biomass. Not only are alcohols and solvents produced in this degradative process but energy-rich hydrogen as well. Non photosynthetic microbial hydrogen generation from compounds other than sugars has not been fully explored. We propose to examine the capacity of the abundant soil anaerobes, sulfate-reducing bacteria, for hydrogen generation from organic acids. These apparently simple pathways have yet to be clearly established. Information obtained may facilitate the exploitation of other microbes not yet readily examined by molecular tools. Identification of the flexibility of the metabolic processes to channel reductant to hydrogen will be useful in consideration of practical applications. Because the tools for genetic and molecular manipulation of sulfate-reducing bacteria of the genus Desulfovibrio are developed, our efforts will focus on two strains, D. vulgaris Hildenborough and Desulfovibrio G20.Therefore total metabolism, flux through the pathways, and regulation are likely to be limiting factors which we can elucidate in the following experiments.

  13. Advanced Electrochemical Technologies for Hydrogen Production by Alternative Thermochemical Cycles

    SciTech Connect (OSTI)

    Lvov, Serguei; Chung, Mike; Fedkin, Mark; Lewis, Michele; Balashov, Victor; Chalkova, Elena; Akinfiev, Nikolay; Stork, Carol; Davis, Thomas; Gadala-Maria, Francis; Stanford, Thomas; Weidner, John; Law, Victor; Prindle, John

    2011-01-06

    Hydrogen fuel is a potentially major solution to the problem of climate change, as well as addressing urban air pollution issues. But a key future challenge for hydrogen as a clean energy carrier is a sustainable, low-cost method of producing it in large capacities. Most of the world's hydrogen is currently derived from fossil fuels through some type of reforming processes. Nuclear hydrogen production is an emerging and promising alternative to the reforming processes for carbon-free hydrogen production in the future. This report presents the main results of a research program carried out by a NERI Consortium, which consisted of Penn State University (PSU) (lead), University of South Carolina (USC), Tulane University (TU), and Argonne National Laboratory (ANL). Thermochemical water decomposition is an emerging technology for large-scale production of hydrogen. Typically using two or more intermediate compounds, a sequence of chemical and physical processes split water into hydrogen and oxygen, without releasing any pollutants externally to the atmosphere. These intermediate compounds are recycled internally within a closed loop. While previous studies have identified over 200 possible thermochemical cycles, only a few have progressed beyond theoretical calculations to working experimental demonstrations that establish scientific and practical feasibility of the thermochemical processes. The Cu-Cl cycle has a significant advantage over other cycles due to lower temperature requirements around 530 C and below. As a result, it can be eventually linked with the Generation IV thermal power stations. Advantages of the Cu-Cl cycle over others include lower operating temperatures, ability to utilize low-grade waste heat to improve energy efficiency, and potentially lower cost materials. Another significant advantage is a relatively low voltage required for the electrochemical step (thus low electricity input). Other advantages include common chemical agents and reactions going to completion without side reactions, and lower demands on materials of construction. Three university research groups from PSU, USC, and TU as well as a group from ANL have been collaborating on the development of enabling technologies for the Cu-Cl cycle, including experimental work on the Cu-Cl cycle reactions, modeling and simulation, and particularly electrochemical reaction for hydrogen production using a CuCl electrolyzer. The Consortium research was distributed over the participants and organized in the following tasks: (1) Development of CuCl electrolyzer (PSU), (2) Thermodynamic modeling of anolyte solution (PSU), (3) Proton conductive membranes for CuCl electrolysis (PSU), (4) Development of an analytical method for online analysis of copper compounds in highly concentrated aqueous solutions (USC), (5) Electrodialysis as a means for separation and purification of the streams exiting the electrolyzer in the Cu-Cl cycle (USC), (6) Development of nanostructured electrocatalysts for the Cu-Cl electrolysis (USC), (7) Cu-Cl electrolyzer modeling (USC), (8) Aspen Plus modeling of the Cu-Cl thermochemical cycle (TU), (9) International coordination of research on the development of the Cu-Cl thermochemical cycle (ANL). The results obtained in the project clearly demonstrate that the Cu-Cl alternative thermochemical cycle is a promising and viable technology to produce hydrogen efficiently.

  14. Technology status of hydrogen road vehicles. IEA technical report from the IEA Agreement of the production and utilization of hydrogen

    SciTech Connect (OSTI)

    Doyle, T.A.

    1998-01-31

    The report was commissioned under the Hydrogen Implementing Agreement of the International Energy Agency (IEA) and examines the state of the art in the evolving field of hydrogen-fueled vehicles for road transport. The first phase surveys and analyzes developments since 1989, when a comprehensive review was last published. The report emphasizes the following: problems, especially backfiring, with internal combustion engines (ICEs); operational safety; hydrogen handling and on-board storage; and ongoing demonstration projects. Hydrogen vehicles are receiving much attention, especially at the research and development level. However, there has been a steady move during the past 5 years toward integral demonstrations of operable vehicles intended for public roads. Because they emit few, or no greenhouse gases, hydrogen vehicles are beginning to be taken seriously as a promising solution to the problems of urban air quality. Since the time the first draft of the report was prepared (mid-19 96), the 11th World Hydrogen Energy Conference took place in Stuttgart, Germany. This biennial conference can be regarded as a valid updating of the state of the art; therefore, the 1996 results are included in the current version. Sections of the report include: hydrogen production and distribution to urban users; on-board storage and refilling; vehicle power units and drives, and four appendices titled: 'Safety questions of hydrogen storage and use in vehicles', 'Performance of hydrogen fuel in internal production engines for road vehicles, 'Fuel cells for hydrogen vehicles', and 'Summaries of papers on hydrogen vehicles'. (refs., tabs.)

  15. Influence of acidic pH on hydrogen and acetate production by an

    Office of Scientific and Technical Information (OSTI)

    electrosynthetic microbiome (Journal Article) | DOE PAGES Influence of acidic pH on hydrogen and acetate production by an electrosynthetic microbiome « Prev Next » Title: Influence of acidic pH on hydrogen and acetate production by an electrosynthetic microbiome Production of hydrogen and organic compounds by an electrosynthetic microbiome using electrodes and carbon dioxide as sole electron donor and carbon source, respectively, was examined after exposure to acidic pH (~5). Hydrogen

  16. H2A Hydrogen Production Analysis Tool (Presentation) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Production Analysis Tool (Presentation) H2A Hydrogen Production Analysis Tool (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 02_nrel_h2a_production_analysis_tool.pdf More Documents & Publications BILIWG: Consistent "Figures of Merit" (Presentation) Distributed Hydrogen Fueling Station Based on GEGR SCPO Technology (Presentation) Pioneer Plants Study User's Manu

  17. DOE Hydrogen and Fuel Cells Program Record 12024: Hydrogen Production Cost Using Low-Cost Natural Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2024 Date: September 19, 2012 Title: Hydrogen Production Cost Using Low-Cost Natural Gas Originator: Sara Dillich, Todd Ramsden & Marc Melaina Approved by: Sunita Satyapal Date: September 24, 2012 Item: Hydrogen produced and dispensed in distributed facilities at high-volume refueling stations using current technology and DOE's Annual Energy Outlook (AEO) 2009 projected prices for industrial natural gas result in a hydrogen levelized cost of $4.49 per gallon-gasoline-equivalent (gge)

  18. NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)

    SciTech Connect (OSTI)

    Ramsden, T.; Harrison, K.; Steward, D.

    2009-11-16

    Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

  19. Liquid Hydrogen Production and Delivery from a Dedicated Wind...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fuel cell vehiclesday. The hydrogen would be delivered from a region in New Mexico near Albuquerque with high average wind speeds where the hydrogen is produced via electrolysis. ...

  20. Production of Hydrogen at the Forecourt Using Off-Peak Electricity: June 2005 (Milestone Report)

    SciTech Connect (OSTI)

    Levene, J. I.

    2007-02-01

    This milestone report provides information about the production of hydrogen at the forecourt using off-peak electricity as well as the Hydrogen Off-Peak Electricity (HOPE) model.

  1. Long-Term Demonstration of Hydrogen Production from Coal at Elevated

    Office of Scientific and Technical Information (OSTI)

    Temperatures Year 6 - Activity 1.12 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Technical Report: Long-Term Demonstration of Hydrogen Production from Coal at Elevated Temperatures Year 6 - Activity 1.12 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Long-Term Demonstration of Hydrogen Production from Coal at Elevated Temperatures Year 6 - Activity 1.12 - Development of a National Center

  2. Method of Production of Pure Hydrogen Near Room Temperature From Ultra High

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capacity Hydride Materials - Energy Innovation Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Method of Production of Pure Hydrogen Near Room Temperature From Ultra High Capacity Hydride Materials Ames Laboratory Contact AMES About This Technology Technology Marketing Summary This is a cost-effective method for the production of pure hydrogen gas from ultra high capacity hydride

  3. ENHANCED HYDROGEN ECONOMICS VIA COPRODUCTION OF FUELS AND CARBON PRODUCTS

    SciTech Connect (OSTI)

    Kennel, Elliot B; Bhagavatula, Abhijit; Dadyburjor, Dady; Dixit, Santhoshi; Garlapalli, Ravinder; Magean, Liviu; Mukkha, Mayuri; Olajide, Olufemi A; Stiller, Alfred H; Yurchick, Christopher L

    2011-03-31

    This Department of Energy National Energy Technology Laboratory sponsored research effort to develop environmentally cleaner projects as a spin-off of the FutureGen project, which seeks to reduce or eliminate emissions from plants that utilize coal for power or hydrogen production. New clean coal conversion processes were designed and tested for coproducing clean pitches and cokes used in the metals industry as well as a heavy crude oil. These new processes were based on direct liquefaction and pyrolysis techniques that liberate volatile liquids from coal without the need for high pressure or on-site gaseous hydrogen. As a result of the research, a commercial scale plant for the production of synthetic foundry coke has broken ground near Wise, Virginia under the auspices of Carbonite Inc. This plant will produce foundry coke by pyrolyzing a blend of steam coal feedstocks. A second plant is planned by Quantex Energy Inc (in Texas) which will use solvent extraction to coproduce a coke residue as well as crude oil. A third plant is being actively considered for Kingsport, Tennessee, pending a favorable resolution of regulatory issues.

  4. Ice method for production of hydrogen clathrate hydrates

    DOE Patents [OSTI]

    Lokshin, Konstantin (Santa Fe, NM); Zhao, Yusheng (Los Alamos, NM)

    2008-05-13

    The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

  5. Micro Hydro Kinetic Turbines from Smart Hydro Power | Open Energy...

    Open Energy Info (EERE)

    Hydro Kinetic Turbines from Smart Hydro Power Jump to: navigation, search << Return to the MHK database homepage Tauchturbine.jpg Technology Profile Project(s) where this...

  6. Hydro Power (pbl/generation)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Generation > Generation Hydro Power FCRPS Hydro Projects FCRPS Information Kiosk Current Hydrological Info Fish Funding Agreement FCRPS Definitions Wind Power Monthly GSP BPA White...

  7. Switchable photosystem-II designer algae for photobiological hydrogen production

    DOE Patents [OSTI]

    Lee, James Weifu

    2010-01-05

    A switchable photosystem-II designer algae for photobiological hydrogen production. The designer transgenic algae includes at least two transgenes for enhanced photobiological H.sub.2 production wherein a first transgene serves as a genetic switch that can controls photosystem II (PSII) oxygen evolution and a second transgene encodes for creation of free proton channels in the algal photosynthetic membrane. In one embodiment, the algae includes a DNA construct having polymerase chain reaction forward primer (302), a inducible promoter (304), a PSII-iRNA sequence (306), a terminator (308), and a PCR reverse primer (310). In other embodiments, the PSII-iRNA sequence (306) is replaced with a CF.sub.1-iRNA sequence (312), a streptomycin-production gene (314), a targeting sequence (316) followed by a proton-channel producing gene (318), or a PSII-producing gene (320). In one embodiment, a photo-bioreactor and gas-product separation and utilization system produce photobiological H.sub.2 from the switchable PSII designer alga.

  8. Microbial Electrolysis Cells (MECs) for High Yield Hydrogen (H2) Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Biodegradable Materials | Department of Energy Electrolysis Cells (MECs) for High Yield Hydrogen (H2) Production from Biodegradable Materials Microbial Electrolysis Cells (MECs) for High Yield Hydrogen (H2) Production from Biodegradable Materials Presentation by Jason Ren, University of Colorado Boulder, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado. PDF icon bio_h2_workshop_ren.pdf More

  9. DOE Issues 2 Requests for Information on Low-Cost Hydrogen Production and Delivery

    Broader source: Energy.gov [DOE]

    The US DOE's FCTO has issued two RFIs seeking feedback from the research community and relevant stakeholders about hydrogen production and hydrogen delivery RD&D activities aimed at developing technologies that can ultimately produce and deliver low-cost hydrogen.

  10. Natural Gas Used as Feedstock for Hydrogen Production

    Gasoline and Diesel Fuel Update (EIA)

    Used as Feedstock for Hydrogen Production (Million Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Area 2009 2010 2011 2012 2013 2014 View History U.S. 143,004 154,503 169,465 183,051 182,715 186,006 2008-2014 East Coast (PADD 1) 4,178 3,346 4,815 6,313 5,261 5,723 2008-2014 Midwest (PADD 2) 36,936 45,452 44,623 46,640 45,069 46,871 2008-2014 Gulf Coast (PADD 3) 41,049 43,170 50,968 62,829 62,936 60,887

  11. Next Generation Hydrogen Station Composite Data Products: Data through Quarter 2 of 2013

    SciTech Connect (OSTI)

    Sprik, S.; Kurtz, J.; Ainscough, C.; Post, M.; Saur, G.; Peters, M.

    2013-11-01

    This report includes 18 composite data products (CDPs) produced for next generation hydrogen stations, with data through quarter 2 of 2013.

  12. DOE Technical Targets for Hydrogen Production from Biomass-Derived Liquid Reforming

    Broader source: Energy.gov [DOE]

    These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen production from biomass-derived liquid reforming.

  13. Critical Updates to the Hydrogen Analysis Production Model (H2A v3)

    Broader source: Energy.gov [DOE]

    Presentation slides from the February 8, 2012, Fuel Cell Technologies Program webinar, "Critical Updates to the Hydrogen Analysis Production Model (H2A v3)".

  14. Next Generation Hydrogen Station Composite Data Products: Data through Quarter 4 of 2013

    SciTech Connect (OSTI)

    Sprik, S.; Kurtz, J.; Peters, M.

    2014-05-01

    This report includes 25 composite data products (CDPs) produced for next generation hydrogen stations, with data through quarter 4 of 2013.

  15. Long-Term Demonstration of Hydrogen Production from Coal at Elevated...

    Office of Scientific and Technical Information (OSTI)

    Title: Long-Term Demonstration of Hydrogen Production from ... information resources in energy science and technology. ... from the State of Wyoming Clean Coal Technology Program and ...

  16. Long-Term Demonstration of Hydrogen Production from Coal at Elevated...

    Office of Scientific and Technical Information (OSTI)

    Title: Long-Term Demonstration of Hydrogen Production from ... The Energy & Environmental Research Center (EERC) has ... from the State of Wyoming Clean Coal Technology Program and ...

  17. Hydrogen Production from Biomass via Indirect Gasification: The Impact of NREL Process Development Unit Gasifier Correlations

    SciTech Connect (OSTI)

    Kinchin, C. M.; Bain, R. L.

    2009-05-01

    This report describes a set of updated gasifier correlations developed by NREL to predict biomass gasification products and Minimum Hydrogen Selling Price.

  18. IEA Agreement on the production and utilization of hydrogen: 1999 annual report

    SciTech Connect (OSTI)

    Elam, Carolyn C. )

    2000-01-31

    The annual report begins with an overview of the IEA Hydrogen Agreement, including guiding principles and their strategic plan followed by the Chairman's report providing the year's highlights. Annex reports included are: the final report for Task 11, Integrated Systems; task updates for Task 12, Metal Hydrides and Carbon for Hydrogen Storage, Task 13, Design and Optimization of Integrated Systems, Task 14, Photoelectrolytic Production of Hydrogen, and Task 15, Photobiological Production of Hydrogen; and a feature article by Karsten Wurr titled 'Large-Scale Industrial Uses of Hydrogen: Final Development Report'.

  19. IEA agreement on the production and utilization of hydrogen: 2000 annual report

    SciTech Connect (OSTI)

    Elam, Carolyn C.

    2001-12-01

    The 2000 annual report of the IEA Hydrogen Agreement contains an overview of the agreement, including its guiding principles, latest strategic plan, and a report from the Chairman, Mr. Neil P. Rossmeissl, U.S. Department of Energy. Overviews of the National Hydrogen Programs of nine member countries are given: Canada, Japan, Lithuania, the Netherlands, Norway, Spain, Sweden, Switzerland, and the United States. Task updates are provided on the following annexes: Annex 12 - Metal Hydrides and Carbon for Hydrogen Storage, Annex 13 - Design and Optimization of Integrated Systems, Annex 14 - Photoelectrolytic Production of Hydrogen, and, Annex 15 - Photobiological Production of Hydrogen.

  20. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials

    DOE Patents [OSTI]

    Pecharsky, Vitalij K.; Balema, Viktor P.

    2004-08-10

    The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is mechanically processed in the presence of a catalyst to obtain pure gaseous hydrogen. Unlike previous methods, hydrogen may be obtained from the solid material without heating, and without the addition of a solvent during processing. The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous hydrogen as a fuel.

  1. EUHYFIS Hydrogen Filling Station Consortium | Open Energy Information

    Open Energy Info (EERE)

    EUHYFIS Hydrogen Filling Station Consortium Jump to: navigation, search Name: EUHYFIS (Hydrogen Filling Station Consortium) Place: Oldenburg, Germany Zip: 26123 Sector: Hydro,...

  2. Marine Hydrogen and Fuel Cell Association MHFCA | Open Energy...

    Open Energy Info (EERE)

    Hydrogen and Fuel Cell Association MHFCA Jump to: navigation, search Name: Marine Hydrogen and Fuel Cell Association (MHFCA) Place: Leipzig, Germany Zip: D-04318 Sector: Hydro,...

  3. EERC National Center for Hydrogen Technology | Open Energy Information

    Open Energy Info (EERE)

    National Center for Hydrogen Technology Jump to: navigation, search Name: EERC National Center for Hydrogen Technology Place: Grand Forks, North Dakota Zip: 58203 Sector: Hydro,...

  4. SBIR/STTR FY15 Phase 2 Awards Announced-Includes Hydrogen Production and

    Energy Savers [EERE]

    FCEV Systems | Department of Energy Phase 2 Awards Announced-Includes Hydrogen Production and FCEV Systems SBIR/STTR FY15 Phase 2 Awards Announced-Includes Hydrogen Production and FCEV Systems March 23, 2015 - 3:37pm Addthis The U.S. Department of Energy has announced the 2015 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase 2 Release 1 Awards, including three Office of Science projects focusing on hydrogen production from electrolysis and hydrogen

  5. hydrogen

    National Nuclear Security Administration (NNSA)

    3%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  6. hydrogen

    National Nuclear Security Administration (NNSA)

    3%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  7. Distributed Hydrogen Production from Natural Gas: Independent Review

    SciTech Connect (OSTI)

    Fletcher, J.; Callaghan, V.

    2006-10-01

    Independent review report on the available information concerning the technologies needed for forecourts producing 150 kg/day of hydrogen from natural gas.

  8. Hydrogen Production via Reforming of Bio-Derived Liquids

    Broader source: Energy.gov [DOE]

    Presentation by Yong Wang and David King at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  9. Renewable Hydrogen Production Using Sugars and Sugar Alcohols (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  10. Distributed Hydrogen Production from Natural Gas: Independent Review Panel Report

    Broader source: Energy.gov [DOE]

    Independent review report on the available information concerning the technologies needed for forecourts producing 150 kg/day of hydrogen from natural gas.

  11. Hydrogen production from switchgrass via a hybrid pyrolysis-microbial electrolysis process

    SciTech Connect (OSTI)

    Lewis, Alex J; Ren, Shoujie; Ye, Philip; Kim, Pyoungchung; Labbe, Niki; Borole, Abhijeet P

    2015-01-01

    A new approach to hydrogen production using a hybrid pyrolysis-microbial electrolysis process is described. The aqueous stream generated during pyrolysis of switchgrass was used as a substrate for hydrogen production in a microbial electrolysis cell, achieving a maximum hydrogen production rate of 4.3 L H2/L-day at a loading of 10 g COD/L-anode-day. Hydrogen yields ranged from 50 3.2% to76 0.5% while anode coulombic efficiency ranged from 54 6.5% to 96 0.21%, respectively. Significant conversion of furfural, organic acids and phenolic molecules was observed under both batch and continuous conditions. The electrical and overall energy efficiency ranged from 149-175% and 48-63%, respectively. The results demonstrate the potential of the pyrolysis-microbial electrolysis process as a sustainable and efficient route for production of renewable hydrogen with significant implications for hydrocarbon production from biomass.

  12. Brigham City Hydro Generation Project

    SciTech Connect (OSTI)

    Ammons, Tom B.

    2015-10-31

    Brigham City owns and operates its own municipal power system which currently includes several hydroelectric facilities. This project was to update the efficiency and capacity of current hydro production due to increased water flow demands that could pass through existing generation facilities. During 2006-2012, this project completed efficiency evaluation as it related to its main objective by completing a feasibility study, undergoing necessary City Council approvals and required federal environmental reviews. As a result of Phase 1 of the project, a feasibility study was conducted to determine feasibility of hydro and solar portions of the original proposal. The results indicated that the existing Hydro plant which was constructed in the 1960’s was running at approximately 77% efficiency or less. Brigham City proposes that the efficiency calculations be refined to determine the economic feasibility of improving or replacing the existing equipment with new high efficiency equipment design specifically for the site. Brigham City completed the Feasibility Assessment of this project, and determined that the Upper Hydro that supplies the main culinary water to the city was feasible to continue with. Brigham City Council provided their approval of feasibility assessment’s results. The Upper Hydro Project include removal of the existing powerhouse equipment and controls and demolition of a section of concrete encased penstock, replacement of penstock just upstream of the turbine inlet, turbine bypass, turbine shut-off and bypass valves, turbine and generator package, control equipment, assembly, start-up, commissioning, Supervisory Control And Data Acquisition (SCADA), and the replacement of a section of conductors to the step-up transformer. Brigham City increased the existing 575 KW turbine and generator with an 825 KW turbine and generator. Following the results of the feasibility assessment Brigham City pursued required environmental reviews with the DOE and the U.S. Fish and Wildlife Services (USFWS) concurring with the National Environmental Policy Act of 1969 (NEPA) It was determined that Brigham City’s Upper Hydroelectric Power Plant upgrade would have no effect to federally listed or candidate species. However Brigham City has contributed a onetime lump sum towards Bonneville cutthroat trout conservation in the Northern Bonneville Geographic Management Unit with the intention to offset any impacts from the Upper Hydro Project needed to move forward with design and construction and is sufficient for NEPA compliance. No work was done in the river or river bank. During construction, the penstock was disconnected and water was diverted through and existing system around the powerhouse and back into the water system. The penstock, which is currently a 30-inch steel pipe, would be removed and replaced with a new section of 30-inch pipe. Brigham City worked with the DOE and was awarded a new modification and the permission to proceed with Phase III of our Hydro Project in Dec. 2013; with the exception to the modification of the award for the construction phase. Brigham City developed and issued a Request for Proposal for Engineer and Design vendor. Sunrise Engineering was selected for the Design and throughout the Construction Phase of the Upper Hydroelectric Power Plant. Brigham City conducted a Kickoff Meeting with Sunrise June 28, 2013 and received a Scope of Work Brigham City along with engineering firm sent out a RFP for Turbine, Generator and Equipment for Upper Hydro. We select Turbine/Generator Equipment from Canyon Industries located in Deming, WA. DOE awarded Brigham City a new modification and the permission to proceed with Phase III Construction of our Hydro Project. Brigham City Crews removed existing turbine/generator and old equipment alone with feeder wires coming into the building basically giving Caribou Construction an empty shell to begin demolition. Brigham City contracted with Caribou Construction from Jerome, Idaho for the Upper Power Plant construction. A kickoff meeting was June 24, 2014 and demolition was immediately started on building. Because of a delivery delay of Turbine, Generator and Equipment from Canyon Brigham City had to request another extension for the final date of completion. DOE awarded modification (.007) to Brigham City with a new completion date of August 1, 2015. The Turbine has had a few adjustments to help with efficiency; but the Generator had a slight vibration when generator got hot so Canyon Industries had U S Motor’s that manufactured the generator come to check out the issue. The other Equipment seems to be running normal. Brigham City, Sunrise Engineering and Canyon Industries met to determine what the vibration in the generator was and how to solve the issue Us Motor’s found some welds that failed: they have been repaired. U S Motor’s delivered the repaired generator Feb. 17, 2015. Canyon Industries arranged for a crane to installed generator in Power Plant. U S Motor’s balanced and wired generator. Plant Operators put the generator back on line. Canyon Industries returned and gave their approval to keep Hydro online. After Hydro was put back into operations it kept going off line because of overheating issues. Canyon Industries returned and replaced sensors and adjusted them to the proper settings for normal operations. Brigham City added additional steel screens to windows to increase air flow in Power Plant Building. After construction phase of the Upper Hydro Plant some landscaping has been restored around the building additional gravel brought in and leveled out and the road that was cut through for conduits to run wires. A retaining wall was installed to protect penstock. The Upper Hydro Plant is complete and in full operations. The final reimbursement was submitted.

  13. System for the co-production of electricity and hydrogen

    DOE Patents [OSTI]

    Pham, Ai Quoc (San Jose, CA); Anderson, Brian Lee (Lodi, CA)

    2007-10-02

    Described herein is a system for the co-generation of hydrogen gas and electricity, wherein the proportion of hydrogen to electricity can be adjusted from 0% to 100%. The system integrates fuel cell technology for power generation with fuel-assisted steam-electrolysis. A hydrocarbon fuel, a reformed hydrocarbon fuel, or a partially reformed hydrocarbon fuel can be fed into the system.

  14. Liquid Hydrogen Production and Delivery from a Dedicated Wind Power Plant |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrogen Production and Delivery from a Dedicated Wind Power Plant Liquid Hydrogen Production and Delivery from a Dedicated Wind Power Plant This May 2012 study assesses the costs and potential for remote renewable energy to be transported via hydrogen to a demand center for transportation use. The study is based on a projected 40 tonne/day need in the Los Angeles, California, region to serve an average 80,000 fuel cell vehicles/day. The hydrogen would be delivered from

  15. HYDROGEN PRODUCTION AND DELIVERY INFRASTRUCTURE AS A COMPLEX ADAPTIVE SYSTEM

    SciTech Connect (OSTI)

    Tolley, George S

    2010-06-29

    An agent-based model of the transition to a hydrogen transportation economy explores influences on adoption of hydrogen vehicles and fueling infrastructure. Attention is given to whether significant penetration occurs and, if so, to the length of time required for it to occur. Estimates are provided of sensitivity to numerical values of model parameters and to effects of alternative market and policy scenarios. The model is applied to the Los Angeles metropolitan area In the benchmark simulation, the prices of hydrogen and non-hydrogen vehicles are comparable. Due to fuel efficiency, hydrogen vehicles have a fuel savings advantage of 9.8 cents per mile over non-hydrogen vehicles. Hydrogen vehicles account for 60% of new vehicle sales in 20 years from the initial entry of hydrogen vehicles into show rooms, going on to 86% in 40 years and reaching still higher values after that. If the fuel savings is 20.7 cents per mile for a hydrogen vehicle, penetration reaches 86% of new car sales by the 20th year. If the fuel savings is 0.5 cents per mile, market penetration reaches only 10% by the 20th year. To turn to vehicle price difference, if a hydrogen vehicle costs $2,000 less than a non-hydrogen vehicle, new car sales penetration reaches 92% by the 20th year. If a hydrogen vehicle costs $6,500 more than a non-hydrogen vehicle, market penetration is only 6% by the 20th year. Results from other sensitivity runs are presented. Policies that could affect hydrogen vehicle adoption are investigated. A tax credit for the purchase of a hydrogen vehicle of $2,500 tax credit results in 88% penetration by the 20th year, as compared with 60% in the benchmark case. If the tax credit is $6,000, penetration is 99% by the 20th year. Under a more modest approach, the tax credit would be available only for the first 10 years. Hydrogen sales penetration then reach 69% of sales by the 20th year with the $2,500 credit and 79% with the $6,000 credit. A carbon tax of $38 per metric ton is not large enough to noticeably affect sales penetration. A tax of $116 per metric ton makes centrally produced hydrogen profitable in the very first year but results in only 64% penetration by year 20 as opposed to the 60% penetration in the benchmark case. Provision of 15 seed stations publicly provided at the beginning of the simulation, in addition to the 15 existing stations in the benchmark case, gives sales penetration rates very close to the benchmark after 20 years, namely, 63% and 59% depending on where they are placed.

  16. Hydro-Pac Inc., A High Pressure Company | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydro-Pac Inc., A High Pressure Company Hydro-Pac Inc., A High Pressure Company This presentation was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop in March 2013. PDF icon csd_workshop_6_siefert.pdf More Documents & Publications 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report Haskel/BuTech/PPI Hydrogen Transmission and Distribution Workshop

  17. Photo-induced hydrogen production in a helical peptide incorporating a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    [FeFe] hydrogenase active site mimic Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic Authors: Roy, A., Madden, C., and Ghirlanda, G. Title: Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic Source: Chemical Communications Year: 2012 Volume: 48 Pages: 9816-9818 ABSTRACT: There is growing interest in the development of hydrogenase mimics for solar fuel production. Here, we

  18. High Pressure Ethanol Reforming for Distributed Hydrogen Production

    Broader source: Energy.gov [DOE]

    Presentation by S. Ahmed and S.H.D. Lee at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  19. Hydrogen Analysis (H2A) Production Component Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Use a standard discounted cash flow rate of return analysis methodology to determine the hydrogen selling cost given a specified after-tax internal rate of return. Key Attributes & ...

  20. EA-281 Manitoba Hydro | Department of Energy

    Energy Savers [EERE]

    Manitoba Hydro EA-281 Manitoba Hydro Order authorizing Manitoba Hydro to export electric energy to Canada. PDF icon EA-281 Manitoba Hydro More Documents & Publications EA-281-B

  1. Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: Spring 2010; Composite Data Products, Final Version March 29, 2010

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.

    2010-05-01

    Graphs of composite data products produced by DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation project through March 2010.

  2. Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project: Fall 2009; Composite Data Products, Final Version September 11, 2009

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.

    2009-09-01

    Graphs of composite data products produced by DOE's Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation project through September 2009.

  3. Hydrogen Compression, Storage, and Dispensing Cost Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report Storage - Challenges and Opportunities Hydro-Pac Inc., A High Pressure Company

  4. Fast-quench reactor for hydrogen and elemental carbon production from natural gas and other hydrocarbons

    DOE Patents [OSTI]

    Detering, Brent A.; Kong, Peter C.

    2006-08-29

    A fast-quench reactor for production of diatomic hydrogen and unsaturated carbons is provided. During the fast quench in the downstream diverging section of the nozzle, such as in a free expansion chamber, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

  5. Hydrogen Production and Consumption in the U.S.: The Last 25 Years.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Journal Article) | SciTech Connect Hydrogen Production and Consumption in the U.S.: The Last 25 Years. Citation Details In-Document Search Title: Hydrogen Production and Consumption in the U.S.: The Last 25 Years. This article was requested by Cryogas International, which is celebrating its 25th anniversary this year. At the title suggests, the article identifies hydrogen consumption in the U.S., broken out by the major contributors to total production. Explanatory information is provided

  6. Hydrogen Pathways. Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios

    SciTech Connect (OSTI)

    Ruth, Mark; Laffen, Melissa; Timbario, Thomas A.

    2009-09-01

    Report of levelized cost in 2005 U.S. dollars, energy use, and GHG emission benefits of seven hydrogen production, delivery, and distribution pathways.

  7. Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios

    Fuel Cell Technologies Publication and Product Library (EERE)

    Report of levelized cost in 2005 U.S. dollars, energy use, and GHG emission benefits of seven hydrogen production, delivery, and distribution pathways.

  8. Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios

    SciTech Connect (OSTI)

    Ruth, M.; Laffen, M.; Timbario, T. A.

    2009-09-01

    Report of levelized cost in 2005 U.S. dollars, energy use, and GHG emission benefits of seven hydrogen production, delivery, and distribution pathways.

  9. DOE NSF Partnership to Address Critical Challenges in Hydrogen Production from Solar Water Splitting

    Office of Energy Efficiency and Renewable Energy (EERE)

    EERE and the National Science Foundation (NSF) announce a funding opportunity in the area of renewable hydrogen technology research and development, specifically addressing discovery and development of advanced materials systems and chemical proceesses for direct photochemical and/or thermochemical water splitting for application in the solar production of hydrogen fuel.

  10. Analysis of Improved Reference Design for a Nuclear-Driven High Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Edwin A. Harvego; James E. O'Brien; Michael G. McKellar

    2010-06-01

    The use of High Temperature Electrolysis (HTE) for the efficient production of hydrogen without the greenhouse gas emissions associated with conventional fossil-fuel hydrogen production techniques has been under investigation at the Idaho National Engineering Laboratory (INL) for the last several years. The activities at the INL have included the development, testing and analysis of large numbers of solid oxide electrolysis cells, and the analyses of potential plant designs for large scale production of hydrogen using an advanced Very-High Temperature Reactor (VHTR) to provide the process heat and electricity to drive the electrolysis process. The results of these system analyses, using the UniSim process analysis software, have shown that the HTE process, when coupled to a VHTR capable of operating at reactor outlet temperatures of 800 C to 950 C, has the potential to produce the large quantities of hydrogen needed to meet future energy and transportation needs with hydrogen production efficiencies in excess of 50%. In addition, economic analyses performed on the INL reference plant design, optimized to maximize the hydrogen production rate for a 600 MWt VHTR, have shown that a large nuclear-driven HTE hydrogen production plant can to be economically competitive with conventional hydrogen production processes, particularly when the penalties associated with greenhouse gas emissions are considered. The results of this research led to the selection in 2009 of HTE as the preferred concept in the U.S. Department of Energy (DOE) hydrogen technology down-selection process. However, the down-selection process, along with continued technical assessments at the INL, has resulted in a number of proposed modifications and refinements to improve the original INL reference HTE design. These modifications include changes in plant configuration, operating conditions and individual component designs. This paper describes the resulting new INL reference design and presents results of system analyses performed to optimize the design and to determine required plant performance and operating conditions.

  11. Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis Webinar

    Broader source: Energy.gov [DOE]

    Access the recording and download the presentation slides from the Fuel Cell Technologies Office webinar "Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis" held on January 21, 2016.

  12. Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product

    DOE Patents [OSTI]

    Davis, Benjamin L; Rekken, Brian D

    2014-04-01

    Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

  13. Ni-Si Alloys for the S-I Reactor-Hydrogen Production Process Interface

    SciTech Connect (OSTI)

    Joseph W. Newkirk; Richard K. Brow

    2010-01-21

    The overall goal of this project was to develop Ni-Si alloys for use in vessels to contain hot, pressurized sulfuric acid. The application was to be in the decomposition loop of the thermochemical cycle for production of hydrogen.

  14. HydroPulse Drilling

    SciTech Connect (OSTI)

    J.J. Kolle

    2004-04-01

    Tempress HydroPulse{trademark} tool increases overbalanced drilling rates by generating intense suction pulses at the drill bit. This report describes the operation of the tool; results of pressure drilling tests, wear tests and downhole drilling tests; and the business case for field applications. The HydroPulse{trademark} tool is designed to operate on weighted drilling mud at conventional flow rates and pressures. Pressure drilling tests confirm that the HydroPulse{trademark} tool provides 33% to 200% increased rate of penetration. Field tests demonstrated conventional rotary and mud motor drilling operations. The tool has been operated continuous for 50 hours on weighted mud in a wear test stand. This level of reliability is the threshold for commercial application. A seismic-while-drilling version of the tool was also developed and tested. This tool was used to demonstrate reverse vertical seismic profiling while drilling an inclined test well with a PDC bit. The primary applications for the HydroPulse{trademark} tool are deep onshore and offshore drilling where rate of penetration drives costs. The application of the seismic tool is vertical seismic profiling-while-drilling and look-ahead seismic imaging while drilling.

  15. LARGE-SCALE HYDROGEN PRODUCTION FROM NUCLEAR ENERGY USING HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    James E. O'Brien

    2010-08-01

    Hydrogen can be produced from water splitting with relatively high efficiency using high-temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high-temperature process heat. When coupled to an advanced high temperature nuclear reactor, the overall thermal-to-hydrogen efficiency for high-temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. Demand for hydrogen is increasing rapidly for refining of increasingly low-grade petroleum resources, such as the Athabasca oil sands and for ammonia-based fertilizer production. Large quantities of hydrogen are also required for carbon-efficient conversion of biomass to liquid fuels. With supplemental nuclear hydrogen, almost all of the carbon in the biomass can be converted to liquid fuels in a nearly carbon-neutral fashion. Ultimately, hydrogen may be employed as a direct transportation fuel in a hydrogen economy. The large quantity of hydrogen that would be required for this concept should be produced without consuming fossil fuels or emitting greenhouse gases. An overview of the high-temperature electrolysis technology will be presented, including basic theory, modeling, and experimental activities. Modeling activities include both computational fluid dynamics and large-scale systems analysis. We have also demonstrated high-temperature electrolysis in our laboratory at the 15 kW scale, achieving a hydrogen production rate in excess of 5500 L/hr.

  16. Hydrogen Production Forwards and Backwards | U.S. DOE Office of Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SC) Hydrogen Production Forwards and Backwards Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 02.01.12 Hydrogen Production Forwards and

  17. Chapter 7: Advancing Systems and Technologies to Produce Cleaner Fuels | Hydrogen Production and Delivery Technology Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7: Advancing Systems and Technologies to Produce Cleaner Fuels Technology Assessments Bioenergy Conversion Biomass Feedstocks and Logistics Gas Hydrates Research and Development Hydrogen Production and Delivery Natural Gas Delivery Infrastructure Offshore Safety and Spill Reduction Unconventional Oil and Gas ENERGY U.S. DEPARTMENT OF Quadrennial Technology Review 2015 1 Quadrennial Technology Review 2015 Hydrogen Production and Delivery Chapter 7: Technology Assessments Introduction to the

  18. Global Assessment of Hydrogen Technologies Tasks 3 & 4 Report Economic, Energy, and Environmental Analysis of Hydrogen Production and Delivery Options in Select Alabama Markets: Preliminary Case Studies

    SciTech Connect (OSTI)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Gillette, Jerry; Elgowainy, Amgad; Mintz, Marianne

    2007-12-01

    This report documents a set of case studies developed to estimate the cost of producing, storing, delivering, and dispensing hydrogen for light-duty vehicles for several scenarios involving metropolitan areas in Alabama. While the majority of the scenarios focused on centralized hydrogen production and pipeline delivery, alternative delivery modes were also examined. Although Alabama was used as the case study for this analysis, the results provide insights into the unique requirements for deploying hydrogen infrastructure in smaller urban and rural environments that lie outside the DOEs high priority hydrogen deployment regions. Hydrogen production costs were estimated for three technologies steam-methane reforming (SMR), coal gasification, and thermochemical water-splitting using advanced nuclear reactors. In all cases examined, SMR has the lowest production cost for the demands associated with metropolitan areas in Alabama. Although other production options may be less costly for larger hydrogen markets, these were not examined within the context of the case studies.

  19. Updated Cost Analysis of Photobiological Hydrogen Production from Chlamydomonas reinhardtii Green Algae: Milestone Completion Report

    SciTech Connect (OSTI)

    Amos, W. A.

    2004-01-01

    This report updates the 1999 economic analysis of NREL's photobiological hydrogen production from Chlamydomonas reinhardtii. The previous study had looked mainly at incident light intensities, batch cycles and light adsorption without directly attempting to model the saturation effects seen in algal cultures. This study takes a more detailed look at the effects that cell density, light adsorption and light saturation have on algal hydrogen production. Performance estimates based on actual solar data are also included in this study. Based on this analysis, the estimated future selling price of hydrogen produced from algae ranges $0.57/kg to $13.53/kg.

  20. Hydrogen and elemental carbon production from natural gas and other hydrocarbons

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2002-01-01

    Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

  1. Hydrogen Production in Radioactive Solutions in the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    CRAWFORD, CHARLES L.

    2004-05-26

    In the radioactive slurries and solutions to be processed in the Defense Waste Processing Facility (DWPF), hydrogen will be produced continuously by radiolysis. This production results from alpha, beta, and gamma rays from decay of radionuclides in the slurries and solutions interacting with the water. More than 1000 research reports have published data concerning this radiolytic production. The results of these studies have been reviewed in a comprehensive monograph. Information about radiolytic hydrogen production from the different process tanks is necessary to determine air purge rates necessary to prevent flammable mixtures from accumulating in the vapor spaces above these tanks. Radiolytic hydrogen production rates are usually presented in terms of G values or molecules of hydrogen produced per 100ev of radioactive decay energy absorbed by the slurry or solution. With the G value for hydrogen production, G(H2), for a particular slurry and the concentrations of radioactive species in that slurry, the rate of H2 production for that slurry can be calculated. An earlier investigation estimated that the maximum rate that hydrogen could be produced from the sludge slurry stream to the DWPF is with a G value of 0.45 molecules per 100ev of radioactive decay energy sorbed by the slurry.

  2. System Evaluation and Economic Analysis of a HTGR Powered High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego; Anastasia A. Gandrik

    2010-10-01

    A design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The power conversion unit will be a Rankine steam cycle with a power conversion efficiency of 40%. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 40.4% at a hydrogen production rate of 1.75 kg/s and an oxygen production rate of 13.8 kg/s. An economic analysis of this plant was performed with realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.67/kg of hydrogen assuming an internal rate of return, IRR, of 12% and a debt to equity ratio of 80%/20%. A second analysis shows that if the power cycle efficiency increases to 44.4%, the hydrogen production efficiency increases to 42.8% and the hydrogen and oxygen production rates are 1.85 kg/s and 14.6 kg/s respectively. At the higher power cycle efficiency and an IRR of 12% the cost of hydrogen production is $3.50/kg.

  3. Hydro-electric generator

    SciTech Connect (OSTI)

    Vauthier, P.

    1980-06-03

    The efficiency of a hydro-electric generator is improved by providing open-ended hollow tubes having influx ends proximate the axis and efflux ends proximate the periphery of a fan-bladed turbine. The jets of water developed by rotation of the fanbladed turbine are directed against turbine vanes at the periphery of the fan blades. The device is particularly suitable for mounting in a water current such as in an ocean current or river.

  4. Capabilities to Support Thermochemical Hydrogen Production Technology Development

    SciTech Connect (OSTI)

    Daniel M. Ginosar

    2009-05-01

    This report presents the results of a study to determine if Idaho National Laboratory (INL) has the skilled staff, instrumentation, specialized equipment, and facilities required to take on work in thermochemical research, development, and demonstration currently being performed by the Nuclear Hydrogen Initiative (NHI). This study outlines the beneficial collaborations between INL and other national laboratories, universities, and industries to strengthen INL's thermochemical efforts, which should be developed to achieve the goals of the NHI in the most expeditious, cost effective manner. Taking on this work supports INL's long-term strategy to maintain leadership in thermochemical cycle development. This report suggests a logical path forward to accomplish this transition.

  5. The reaction of cobaloximes with hydrogen: Products and thermodynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Estes, Deven P.; Grills, David C.; Norton, Jack R.

    2014-11-26

    In this study, a cobalt hydride has been proposed as an intermediate in many reactions of the Co(dmgBF₂)₂L₂ system, but its observation has proven difficult. We have observed the UV–vis spectra of Co(dmgBF₂)₂L₂ (1) in CH₃CN under hydrogen pressures up to 70 atm. A Co(I) compound (6), with an exchangeable proton, is eventually formed. We have determined the bond dissociation free energy and pKa of the new O–H bond in 6 to be 50.5 kcal/mol and 13.4, respectively, in CH₃CN, matching previous reports.

  6. The reaction of cobaloximes with hydrogen: Products and thermodynamics

    SciTech Connect (OSTI)

    Estes, Deven P.; Grills, David C.; Norton, Jack R.

    2014-11-26

    In this study, a cobalt hydride has been proposed as an intermediate in many reactions of the Co(dmgBF?)?L? system, but its observation has proven difficult. We have observed the UVvis spectra of Co(dmgBF?)?L? (1) in CH?CN under hydrogen pressures up to 70 atm. A Co(I) compound (6), with an exchangeable proton, is eventually formed. We have determined the bond dissociation free energy and pKa of the new OH bond in 6 to be 50.5 kcal/mol and 13.4, respectively, in CH?CN, matching previous reports.

  7. Photobiological hydrogen production with switchable photosystem-II designer algae

    DOE Patents [OSTI]

    Lee, James Weifu

    2014-02-18

    A process for enhanced photobiological H.sub.2 production using transgenic alga. The process includes inducing exogenous genes in a transgenic alga by manipulating selected environmental factors. In one embodiment inducing production of an exogenous gene uncouples H.sub.2 production from existing mechanisms that would downregulate H.sub.2 production in the absence of the exogenous gene. In other embodiments inducing an exogenous gene triggers a cascade of metabolic changes that increase H.sub.2 production. In some embodiments the transgenic alga are rendered non-regenerative by inducing exogenous transgenes for proton channel polypeptides that are targeted to specific algal membranes.

  8. Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons

    DOE Patents [OSTI]

    Muradov, Nazim Z. (Melbourne, FL)

    2011-08-23

    A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

  9. Hydrogen production and delivery analysis in US markets : cost, energy and greenhouse gas emissions.

    SciTech Connect (OSTI)

    Mintz, M.; Gillette, J.; Elgowainy, A.

    2009-01-01

    Hydrogen production cost conclusions are: (1) Steam Methane Reforming (SMR) is the least-cost production option at current natural gas prices and for initial hydrogen vehicle penetration rates, at high production rates, SMR may not be the least-cost option; (2) Unlike coal and nuclear technologies, the cost of natural gas feedstock is the largest contributor to SMR production cost; (3) Coal- and nuclear-based hydrogen production have significant penalties at small production rates (and benefits at large rates); (4) Nuclear production of hydrogen is likely to have large economies of scale, but because fixed O&M costs are uncertain, the magnitude of these effects may be understated; and (5) Given H2A default assumptions for fuel prices, process efficiencies and labor costs, nuclear-based hydrogen is likely to be more expensive to produce than coal-based hydrogen. Carbon taxes and caps can narrow the gap. Hydrogen delivery cost conclusions are: (1) For smaller urban markets, compressed gas delivery appears most economic, although cost inputs for high-pressure gas trucks are uncertain; (2) For larger urban markets, pipeline delivery is least costly; (3) Distance from hydrogen production plant to city gate may change relative costs (all results shown assume 100 km); (4) Pipeline costs may be reduced with system 'rationalization', primarily reductions in service pipeline mileage; and (5) Liquefier and pipeline capital costs are a hurdle, particularly at small market sizes. Some energy and greenhouse gas Observations: (1) Energy use (per kg of H2) declines slightly with increasing production or delivery rate for most components (unless energy efficiency varies appreciably with scale, e.g., liquefaction); (2) Energy use is a strong function of production technology and delivery mode; (3) GHG emissions reflect the energy efficiency and carbon content of each component in a production-delivery pathway; (4) Coal and natural gas production pathways have high energy consumption and significant GHG emissions (in the absence of carbon caps, taxes or sequestration); (5) Nuclear pathway is most favorable from energy use and GHG emissions perspective; (6) GH2 Truck and Pipeline delivery have much lower energy use and GHG emissions than LH2 Truck delivery; and (7) For LH2 Truck delivery, the liquefier accounts for most of the energy and GHG emissions.

  10. Renewable Hydrogen Production from Biomass Pyrolysis Aqueous Phase Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7, 2015 Thermochem Conversion Review PI: Abhijeet P. Borole, Ph.D. Oak Ridge National Laboratory Co:PI's & Collaborators: S. Pavlostathis, C. Tsouris, S. Yiacoumi, Georgia Tech; P. Ye, N. Labbe, University of Tennessee, Knoxville, R. Bhave, ORNL DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Renewable Hydrogen Production from Biomass Pyrolysis Aqueous Phase 2 Managed by UT-Battelle for the U.S. Department of Energy Presentation_name Goal Statement * Carbon, Hydrogen and

  11. Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Transportation Applications: 2012 Update | Department of Energy of Direct Hydrogen PEM Fuel Cell Systems for Transportation Applications: 2012 Update Mass Production Cost Estimation of Direct Hydrogen PEM Fuel Cell Systems for Transportation Applications: 2012 Update This report is the sixth annual update of a comprehensive automotive fuel cell cost analysis conducted by Strategic Analysis under contract to the U.S. Department of Energy. This 2012 update will cover current status

  12. Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic

    SciTech Connect (OSTI)

    Smith, Stuart E.; Yang, Jenny Y.; DuBois, Daniel L.; Bullock, Morris

    2012-03-26

    A new bis(diphosphine) nickel(II) complex, [Ni(PPh2NR2)2](BF4)2, 1, (R = CH2CH2OCH3) is described. A {Delta}G{sup o} of 0.84 kcal/mol{sup -1} for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displays reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, a characteristic most commonly associated with hydrogenase enzymes.

  13. FCRPS Definitions (hydro/fcrps)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Reclamation (USBR). Portion of Cost Allocated to Power The cost allocated to the power generating portion of hydro projects. Flood control, navigation, and irrigation are...

  14. MEASUREMENT AND PREDICTION OF RADIOLYTIC HYDROGEN PRODUCTION IN DEFENSE WASTE PROCESSING SLURRIES AT SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Bibler, N; John Pareizs, J; Terri Fellinger, T; Cj Bannochie, C

    2007-01-10

    This paper presents results of measurements and predictions of radiolytic hydrogen production rates from two actual process slurries in the Defense Waste Processing Facility (DWPF) at Savannah River Site (SRS). Hydrogen is a flammable gas and its production in nuclear facilities can be a safety hazard if not mitigated. Measurements were made in the Shielded Cells of Savannah River National Laboratory (SRNL) using a sample of Sludge Batch 3 (SB3) currently being processed by the DWPF. Predictions were made using published values for rates of radiolytic reactions producing H{sub 2} in aqueous solutions and the measured radionuclide and chemical compositions of the two slurries. The agreement between measured and predicted results for nine experiments ranged from complete agreement to 24% difference. This agreement indicates that if the composition of the slurry being processed is known, the rate of radiolytic hydrogen production can be reasonably estimated.

  15. Comparative environmental impact and efficiency assessment of selected hydrogen production methods

    SciTech Connect (OSTI)

    Ozbilen, Ahmet Dincer, Ibrahim Rosen, Marc A.

    2013-09-15

    The environmental impacts of various hydrogen production processes are evaluated and compared, considering several energy sources and using life cycle analysis. The results indicate that hydrogen produced by thermochemical water decomposition cycles are more environmentally benign options compared to conventional steam reforming of natural gas. The nuclear based four-step CuCl cycle has the lowest global warming potential (0.559 kg CO{sub 2}-eq per kg hydrogen production), mainly because it requires the lowest quantity of energy of the considered processes. The acidification potential results show that biomass gasification has the highest impact on environment, while wind based electrolysis has the lowest. The relation is also investigated between efficiency and environmental impacts. -- Highlights: Environmental performance of nuclear-based hydrogen production is investigated. The GWP and AP results are compared with various hydrogen production processes. Nuclear based 4-step CuCl cycle is found to be an environmentally benign process. Wind-based electrolysis has the lowest AP value.

  16. CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY

    SciTech Connect (OSTI)

    Zhen Fan

    2006-05-30

    Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

  17. System Evaluations and Life-Cycle Cost Analyses for High-Temperature Electrolysis Hydrogen Production Facilities

    SciTech Connect (OSTI)

    Edwin A. Harvego; James E. O'Brien; Michael G. McKellar

    2012-05-01

    This report presents results of system evaluations and lifecycle cost analyses performed for several different commercial-scale high-temperature electrolysis (HTE) hydrogen production concepts. The concepts presented in this report rely on grid electricity and non-nuclear high-temperature process heat sources for the required energy inputs. The HYSYS process analysis software was used to evaluate both central plant designs for large-scale hydrogen production (50,000 kg/day or larger) and forecourt plant designs for distributed production and delivery at about 1,500 kg/day. The HYSYS software inherently ensures mass and energy balances across all components and it includes thermodynamic data for all chemical species. The optimized designs described in this report are based on analyses of process flow diagrams that included realistic representations of fluid conditions and component efficiencies and operating parameters for each of the HTE hydrogen production configurations analyzed. As with previous HTE system analyses performed at the INL, a custom electrolyzer model was incorporated into the overall process flow sheet. This electrolyzer model allows for the determination of the average Nernst potential, cell operating voltage, gas outlet temperatures, and electrolyzer efficiency for any specified inlet steam, hydrogen, and sweep-gas flow rates, current density, cell active area, and external heat loss or gain. The lifecycle cost analyses were performed using the H2A analysis methodology developed by the Department of Energy (DOE) Hydrogen Program. This methodology utilizes spreadsheet analysis tools that require detailed plant performance information (obtained from HYSYS), along with financial and cost information to calculate lifecycle costs. There are standard default sets of assumptions that the methodology uses to ensure consistency when comparing the cost of different production or plant design options. However, these assumptions may also be varied within the spreadsheets when better information is available or to allow the performance of sensitivity studies. The selected reference plant design for this study was a 1500 kg/day forecourt hydrogen production plant operating in the thermal-neutral mode. The plant utilized industrial natural gas-fired heaters to provide process heat, and grid electricity to supply power to the electrolyzer modules and system components. Modifications to the reference design included replacing the gas-fired heaters with electric resistance heaters, changing the operating mode of the electrolyzer (to operate below the thermal-neutral voltage), and considering a larger 50,000 kg/day central hydrogen production plant design. Total H2A-calculated hydrogen production costs for the reference 1,500 kg/day forecourt hydrogen production plant were $3.42/kg. The all-electric plant design using electric resistance heaters for process heat, and the reference design operating below the thermal-neutral voltage had calculated lifecycle hydrogen productions costs of $3.55/kg and $5.29/kg, respectively. Because of its larger size and associated economies of scale, the 50,000 kg/day central hydrogen production plant was able to produce hydrogen at a cost of only $2.89/kg.

  18. An Integrated Hydrogen Production-CO2 Capture Process from Fossil Fuel

    SciTech Connect (OSTI)

    Zhicheng Wang

    2007-03-15

    The new technology concept integrates two significant complementary hydrogen production and CO{sub 2}-sequestration approaches that have been developed at Oak Ridge National Laboratory (ORNL) and Clark Atlanta University. The process can convert biomass into hydrogen and char. Hydrogen can be efficiently used for stationary power and mobile applications, or it can be synthesized into Ammonia which can be used for CO{sub 2}-sequestration, while char can be used for making time-release fertilizers (NH{sub 4}HCO{sub 3}) by absorption of CO{sub 2} and other acid gases from exhaust flows. Fertilizers are then used for the growth of biomass back to fields. This project includes bench scale experiments and pilot scale tests. The Combustion and Emission Lab at Clark Atlanta University has conducted the bench scale experiments. The facility used for pilot scale tests was built in Athens, GA. The overall yield from this process is 7 wt% hydrogen and 32 wt% charcoal/activated carbon of feedstock (peanut shell). The value of co-product activated carbon is about $1.1/GJ and this coproduct reduced the selling price of hydrogen. And the selling price of hydrogen is estimated to be $6.95/GJ. The green house experimental results show that the samples added carbon-fertilizers have effectively growth increase of three different types of plants and improvement ability of keeping fertilizer in soil to avoid the fertilizer leaching with water.

  19. Low-Cost Production of Hydrogen and Electricity | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Cost Production of Hydrogen and Electricity Low-Cost Production of Hydrogen and Electricity April 10, 2013 - 12:00am Addthis At an airport in Anchorage, Alaska, EERE provided funds to Bloom Energy in completing a one-year demonstration of two 25-kilowatt fuel cells-providing valuable, real-world data in one of the harshest environments on earth. Each fuel cell showed an impressive peak electrical efficiency of more than 50%. The high operating temperature of these specific fuel cells allows

  20. EERE Success Story-Low-Cost Production of Hydrogen and Electricity |

    Office of Environmental Management (EM)

    Department of Energy Low-Cost Production of Hydrogen and Electricity EERE Success Story-Low-Cost Production of Hydrogen and Electricity April 10, 2013 - 12:00am Addthis At an airport in Anchorage, Alaska, EERE provided funds to Bloom Energy in completing a one-year demonstration of two 25-kilowatt fuel cells-providing valuable, real-world data in one of the harshest environments on earth. Each fuel cell showed an impressive peak electrical efficiency of more than 50%. The high operating

  1. Next Generation Hydrogen Station Composite Data Products: Data through Quarter 4 of 2014; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Sprik, S.; Kurtz, J.; Ainscough, C.; Peters, M.

    2015-05-14

    This publication includes 43 composite data products (CDPs) produced for next generation hydrogen stations, with data through the fourth quarter of 2014.

  2. Novel Hydrogen Production Systems Operative at Thermodynamic Extremes

    SciTech Connect (OSTI)

    Gunsalus, Robert

    2012-11-30

    We have employed a suite of molecular, bioinformatics, and biochemical tools to interrogate the thermodynamically limiting steps of H{sub 2} production from fatty acids in syntrophic communities. We also developed a new microbial model system that generates high H{sub 2} concentrations (over 17% of the gas phase) with high H{sub 2} yields of over 3 moles H{sub 2} per mole glucose. Lastly, a systems-based study of biohydrogen production in model anaerobic consortia was performed to begin identifying key regulated steps as a precursor to modeling co-metabolism. The results of these studies significantly expand our ability to predict and model systems for H{sub 2} production in novel anaerobes that are currently very poorly documented or understood.

  3. A Process Model for the Production of Hydrogen Using High Temperature Electrolysis

    SciTech Connect (OSTI)

    M. G. Mc Kellar; E. A. Harvego; M. Richards; A. Shenoy

    2006-07-01

    High temperature electrolysis (HTE) involves the splitting of stream into hydrogen and oxygen at high temperatures. The primary advantage of HTE over conventional low temperature electrolysis is that considerably higher hydrogen production efficiencies can be achieved. Performing the electrolysis process at high temperatures results in more favorable thermodynamics for electrolysis, more efficient production of electricity, and allows direct use of process heat to generate steam. This paper presents the results of process analyses performed to evaluate the hydrogen production efficiencies of an HTE plant coupled to a 600 MWt Modular Helium Reactor (MHR) that supplies both the electricity and process heat needed to drive the process. The MHR operates with a coolant outlet temperature of 950 C. Approximately 87% of the high-temperature heat is used to generate electricity at high efficiency using a direct, Brayton-cycle power conversion system. The remaining high-temperature heat is used to generate a superheated steam / hydrogen mixture that is supplied to the electrolyzers. The analyses were performed using the HYSYS process modeling software. The model used to perform the analyses consisted of three loops; a primary high temperature helium loop, a secondary helium loop and the HTE process loop. The detailed model included realistic representations of all major components in the system, including pumps, compressors, heat exchange equipment, and the electrolysis stack. The design of the hydrogen production process loop also included a steam-sweep gas system to remove oxygen from the electrolysis stack so that it can be recovered and used for other applications. Results of the process analyses showed that hydrogen production efficiencies in the range of 45% to 50% are achievable with this system.

  4. High Temperature Electrolysis for Hydrogen Production from Nuclear Energy TechnologySummary

    SciTech Connect (OSTI)

    J. E. O'Brien; C. M. Stoots; J. S. Herring; M. G. McKellar; E. A. Harvego; M. S. Sohal; K. G. Condie

    2010-02-01

    The Department of Energy, Office of Nuclear Energy, has requested that a Hydrogen Technology Down-Selection be performed to identify the hydrogen production technology that has the best potential for timely commercial demonstration and for ultimate deployment with the Next Generation Nuclear Plant (NGNP). An Independent Review Team has been assembled to execute the down-selection. This report has been prepared to provide the members of the Independent Review Team with detailed background information on the High Temperature Electrolysis (HTE) process, hardware, and state of the art. The Idaho National Laboratory has been serving as the lead lab for HTE research and development under the Nuclear Hydrogen Initiative. The INL HTE program has included small-scale experiments, detailed computational modeling, system modeling, and technology demonstration. Aspects of all of these activities are included in this report. In terms of technology demonstration, the INL successfully completed a 1000-hour test of the HTE Integrated Laboratory Scale (ILS) technology demonstration experiment during the fall of 2008. The HTE ILS achieved a hydrogen production rate in excess of 5.7 Nm3/hr, with a power consumption of 18 kW. This hydrogen production rate is far larger than has been demonstrated by any of the thermochemical or hybrid processes to date.

  5. Influence of acidic pH on hydrogen and acetate production by an electrosynthetic microbiome

    SciTech Connect (OSTI)

    LaBelle, Edward V.; Marshall, Christopher W.; Gilbert, Jack A.; May, Harold D.; Battista, John R.

    2014-10-15

    Production of hydrogen and organic compounds by an electrosynthetic microbiome using electrodes and carbon dioxide as sole electron donor and carbon source, respectively, was examined after exposure to acidic pH (~5). Hydrogen production by biocathodes poised at -600 mV vs. SHE increased>100-fold and acetate production ceased at acidic pH, but ~5–15 mM (catholyte volume)/day acetate and>1,000 mM/day hydrogen were attained at pH ~6.5 following repeated exposure to acidic pH. Cyclic voltammetry revealed a 250 mV decrease in hydrogen overpotential and a maximum current density of 12.2 mA/cm2 at -765 mV (0.065 mA/cm2 sterile control at -800 mV) by the Acetobacterium-dominated community. Supplying -800 mV to the microbiome after repeated exposure to acidic pH resulted in up to 2.6 kg/m3/day hydrogen (≈2.6 gallons gasoline equivalent), 0.7 kg/m3/day formate, and 3.1 kg/m3/day acetate ( = 4.7 kg CO2 captured).

  6. Bioengineering and Coordination of Regulatory Networks and Intracellular Complexes to Maximize Hydrogen Production by Phototrophic Microorganisms

    SciTech Connect (OSTI)

    Tabita, F. Robert [The Ohio State University] [The Ohio State University

    2013-07-30

    In this study, the Principal Investigator, F.R. Tabita has teemed up with J. C. Liao from UCLA. This project's main goal is to manipulate regulatory networks in phototrophic bacteria to affect and maximize the production of large amounts of hydrogen gas under conditions where wild-type organisms are constrained by inherent regulatory mechanisms from allowing this to occur. Unrestrained production of hydrogen has been achieved and this will allow for the potential utilization of waste materials as a feed stock to support hydrogen production. By further understanding the means by which regulatory networks interact, this study will seek to maximize the ability of currently available unrestrained organisms to produce hydrogen. The organisms to be utilized in this study, phototrophic microorganisms, in particular nonsulfur purple (NSP) bacteria, catalyze many significant processes including the assimilation of carbon dioxide into organic carbon, nitrogen fixation, sulfur oxidation, aromatic acid degradation, and hydrogen oxidation/evolution. Moreover, due to their great metabolic versatility, such organisms highly regulate these processes in the cell and since virtually all such capabilities are dispensable, excellent experimental systems to study aspects of molecular control and biochemistry/physiology are available.

  7. Village Hydro Technology Module | Open Energy Information

    Open Energy Info (EERE)

    Hydro Technology Module Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Village Hydro Technology Module AgencyCompany Organization: World Bank Sector: Energy Focus...

  8. Aquaphile sarl Hydro Gen | Open Energy Information

    Open Energy Info (EERE)

    Aquaphile sarl Hydro Gen Jump to: navigation, search Name: Aquaphile sarl Hydro Gen Address: 210 Le Vrennic Place: Landda Zip: 29870 Region: France Sector: Marine and Hydrokinetic...

  9. Geo Hydro Supply | Open Energy Information

    Open Energy Info (EERE)

    Hydro Supply Jump to: navigation, search Name: Geo Hydro Supply Address: 997 State Route 93 NW Place: Sugarcreek, Ohio Zip: 44681 Sector: Geothermal energy Phone Number:...

  10. Voith Hydro Wavegen Limited | Open Energy Information

    Open Energy Info (EERE)

    Voith Hydro Wavegen Limited Jump to: navigation, search Name: Voith Hydro Wavegen Limited Region: United Kingdom Sector: Marine and Hydrokinetic Website: www.wavegen.co.uk This...

  11. EA-281-A Manitoba Hydro | Department of Energy

    Energy Savers [EERE]

    -A Manitoba Hydro EA-281-A Manitoba Hydro Order authorizing Manitoba Hydro to export electric energy to Canada. PDF icon EA-281-A Manitoba Hydro More Documents & Publications EA-281 Manitoba Hydro EA-281-B

  12. Hydrogen production. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The bibliography contains citations concerning the manufacture of hydrogen by electrolysis, photosynthesis, and coal conversion processes. Citations discuss plant and process evaluations, theoretical and laboratory investigations, economic analyses, and the use of thermonuclear reactors as production source. (Contains 250 citations and includes a subject term index and title list.)

  13. Hydrogen Production and Consumption in the U.S.: The Last 25 Years.

    SciTech Connect (OSTI)

    Brown, Daryl R.

    2015-09-01

    This article was requested by Cryogas International, which is celebrating its 25th anniversary this year. At the title suggests, the article identifies hydrogen consumption in the U.S., broken out by the major contributors to total production. Explanatory information is provided describing the causes underlying the significant changes seen in the summary data.

  14. Assessement of Codes and Standards Applicable to a Hydrogen Production Plant Coupled to a Nuclear Reactor

    SciTech Connect (OSTI)

    M. J. Russell

    2006-06-01

    This is an assessment of codes and standards applicable to a hydrogen production plant to be coupled to a nuclear reactor. The result of the assessment is a list of codes and standards that are expected to be applicable to the plant during its design and construction.

  15. Zeolite Membrane Reactor for Water Gas Shift Reaction for Hydrogen Production

    SciTech Connect (OSTI)

    Lin, Jerry Y.S.

    2013-01-29

    Gasification of biomass or heavy feedstock to produce hydrogen fuel gas using current technology is costly and energy-intensive. The technology includes water gas shift reaction in two or more reactor stages with inter-cooling to maximize conversion for a given catalyst volume. This project is focused on developing a membrane reactor for efficient conversion of water gas shift reaction to produce a hydrogen stream as a fuel and a carbon dioxide stream suitable for sequestration. The project was focused on synthesizing stable, hydrogen perm-selective MFI zeolite membranes for high temperature hydrogen separation; fabricating tubular MFI zeolite membrane reactor and stable water gas shift catalyst for membrane reactor applications, and identifying experimental conditions for water gas shift reaction in the zeolite membrane reactor that will produce a high purity hydrogen stream. The project has improved understanding of zeolite membrane synthesis, high temperature gas diffusion and separation mechanisms for zeolite membranes, synthesis and properties of sulfur resistant catalysts, fabrication and structure optimization of membrane supports, and fundamentals of coupling reaction with separation in zeolite membrane reactor for water gas shift reaction. Through the fundamental study, the research teams have developed MFI zeolite membranes with good perm-selectivity for hydrogen over carbon dioxide, carbon monoxide and water vapor, and high stability for operation in syngas mixture containing 500 part per million hydrogen sulfide at high temperatures around 500C. The research teams also developed a sulfur resistant catalyst for water gas shift reaction. Modeling and experimental studies on the zeolite membrane reactor for water gas shift reaction have demonstrated the effective use of the zeolite membrane reactor for production of high purity hydrogen stream.

  16. Production of Hydrogen for Clean and Renewable Source of Energy for Fuel Cell Vehicles

    SciTech Connect (OSTI)

    Deng, Xunming; Ingler, William B, Jr.; Abraham, Martin; Castellano, Felix; Coleman, Maria; Collins, Robert; Compaan, Alvin; Giolando, Dean; Jayatissa, Ahalapitiya. H.; Stuart, Thomas; Vonderembse, Mark

    2008-10-31

    This was a two-year project that had two major components: 1) the demonstration of a PV-electrolysis system that has separate PV system and electrolysis unit and the hydrogen generated is to be used to power a fuel cell based vehicle; 2) the development of technologies for generation of hydrogen through photoelectrochemical process and bio-mass derived resources. Development under this project could lead to the achievement of DOE technical target related to PEC hydrogen production at low cost. The PEC part of the project is focused on the development of photoelectrochemical hydrogen generation devices and systems using thin-film silicon based solar cells. Two approaches are taken for the development of efficient and durable photoelectrochemical cells; 1) An immersion-type photoelectrochemical cells (Task 3) where the photoelectrode is immersed in electrolyte, and 2) A substrate-type photoelectrochemical cell (Task 2) where the photoelectrode is not in direct contact with electrolyte. Four tasks are being carried out: Task 1: Design and analysis of DC voltage regulation system for direct PV-to-electrolyzer power feed Task 2: Development of advanced materials for substrate-type PEC cells Task 3: Development of advanced materials for immersion-type PEC cells Task 4: Hydrogen production through conversion of biomass-derived wastes

  17. Multi-stage microbial system for continuous hydrogen production

    DOE Patents [OSTI]

    Kosourov, Sergey; Ghirardi, Maria L.; Seibert, Michael

    2010-06-08

    A method of using sequential chemostat culture vessels to provide continuous H.sub.2 production, in which photosynthetic O.sub.2 evolution and H.sub.2 photoproduction are separated physically into two separate bioreactors, comprising: a) growing a microorganism culture able to continuously generate H.sub.2 by photosynthetically producing cells at about the early-to-late log state in a first photobioreactor operating as a sulfur chemostat under aerobic and/or conditions; b) continuously feeding cells from the first photobioreactor to a second photobioreactor operating under anaerobic conditions and sulfur deprivation conditions resulting from constant uptake of sulfate in the first bioreactor and a low rate of culture flow between the first and second bioreactors, for induction of hydrogenase and H.sub.2 photoproduction to allow for continuous cultivation of the microorganism's cells in the first photobioreactor and constant H.sub.2 production in the second photobioreactor, and c) H.sub.2 gas from the second photobioreactor.

  18. Analysis of Reference Design for Nuclear-Assisted Hydrogen Production at 750C Reactor Outlet Temperature

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego

    2010-05-01

    The use of High Temperature Electrolysis (HTE) for the efficient production of hydrogen without the greenhouse gas emissions associated with conventional fossil-fuel hydrogen production techniques has been under investigation at the Idaho National Engineering Laboratory (INL) for the last several years. The activities at the INL have included the development, testing and analysis of large numbers of solid oxide electrolysis cells, and the analyses of potential plant designs for large scale production of hydrogen using a high-temperature gas-cooled reactor (HTGR) to provide the process heat and electricity to drive the electrolysis process. The results of this research led to the selection in 2009 of HTE as the preferred concept in the U.S. Department of Energy (DOE) hydrogen technology down-selection process. However, the down-selection process, along with continued technical assessments at the INL, has resulted in a number of proposed modifications and refinements to improve the original INL reference HTE design. These modifications include changes in plant configuration, operating conditions and individual component designs. This report describes the resulting new INL reference design coupled to two alternative HTGR power conversion systems, a Steam Rankine Cycle and a Combined Cycle (a Helium Brayton Cycle with a Steam Rankine Bottoming Cycle). Results of system analyses performed to optimize the design and to determine required plant performance and operating conditions when coupled to the two different power cycles are also presented. A 600 MWt high temperature gas reactor coupled with a Rankine steam power cycle at a thermal efficiency of 44.4% can produce 1.85 kg/s of hydrogen and 14.6 kg/s of oxygen. The same capacity reactor coupled with a combined cycle at a thermal efficiency of 42.5% can produce 1.78 kg/s of hydrogen and 14.0 kg/s of oxygen.

  19. SIMULTANEOUS PRODUCTION OF HIGH-PURITY HYDROGEN AND SEQUESTRATION-READY CO2 FROM SYNGAS

    SciTech Connect (OSTI)

    Linda Denton; Hana Lorethova; Tomasz Wiltowski; Court Moorefield; Parag Kulkarni; Vladimir Zamansky; Ravi Kumar

    2003-12-01

    This final report summarizes the progress made on the program ''Simultaneous Production of High-Purity Hydrogen and Sequestration-Ready CO{sub 2} from Syngas (contract number DE-FG26-99FT40682)'', during October 2000 through September of 2003. GE Energy and Environmental Research (GE-EER) and Southern Illinois University (SIU) at Carbondale conducted the research work for this program. This program addresses improved methods to efficiently produce simultaneous streams of high-purity hydrogen and separated carbon dioxide from synthesis gas (syngas). The syngas may be produced through either gasification of coal or reforming of natural gas. The process of production of H{sub 2} and separated CO{sub 2} utilizes a dual-bed reactor and regenerator system. The reactor produces hydrogen and the regenerator produces separated CO{sub 2}. The dual-bed system can be operated under either a circulating fluidized-bed configuration or a cyclic fixed-bed configuration. Both configurations were evaluated in this project. The experimental effort was divided into lab-scale work at SIU and bench-scale work at GE-EER. Tests in a lab-scale fluidized bed system demonstrated the process for the conversion of syngas to high purity H{sub 2} and separated CO{sub 2}. The lab-scale system generated up to 95% H{sub 2} (on a dry basis). Extensive thermodynamic analysis of chemical reactions between the syngas and the fluidized solids determined an optimum range of temperature and pressure operation, where the extent of the undesirable reactions is minimum. The cycling of the process between hydrogen generation and oxygen regeneration has been demonstrated. The fluidized solids did not regenerate completely and the hydrogen purity in the reuse cycle dropped to 70% from 95% (on a dry basis). Changes in morphology and particle size may be the most dominant factor affecting the efficiency of the repeated cycling between hydrogen production and oxygen regeneration. The concept of simultaneous production of hydrogen and separated stream of CO{sub 2} was proved using a fixed bed 2 reactor system at GE-EER. This bench-scale cyclic fixed-bed reactor system designed to reform natural gas to syngas has been fabricated in another coordinated DOE project. This system was modified to reform natural gas to syngas and then convert syngas to H{sub 2} and separated CO{sub 2}. The system produced 85% hydrogen (dry basis).

  20. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

  1. A review of dark fermentative hydrogen production from biodegradable municipal waste fractions

    SciTech Connect (OSTI)

    De Gioannis, G.; Muntoni, A.; Polettini, A.; Pomi, R.

    2013-06-15

    Highlights: ? A large number of factors affect fermentative hydrogen production. ? Harmonization and systematic comparison of results from different literature sources are needed. ? More than 80 publications on H{sub 2} production from food waste and OFMSW have been examined. ? Experimental data from the reviewed literature were analyzed using statistical tools. ? For a reliable assessment of the process performance, the use of multiple parameters appears to be recommended. - Abstract: Hydrogen is believed to play a potentially key role in the implementation of sustainable energy production, particularly when it is produced from renewable sources and low energy-demanding processes. In the present paper an attempt was made at critically reviewing more than 80 recent publications, in order to harmonize and compare the available results from different studies on hydrogen production from FW and OFMSW through dark fermentation, and derive reliable information about process yield and stability in view of building related predictive models. The review was focused on the effect of factors, recognized as potentially affecting process evolution (including type of substrate and co-substrate and relative ratio, type of inoculum, food/microorganisms [F/M] ratio, applied pre-treatment, reactor configuration, temperature and pH), on the fermentation yield and kinetics. Statistical analysis of literature data from batch experiments was also conducted, showing that the variables affecting the H{sub 2} production yield were ranked in the order: type of co-substrate, type of pre-treatment, operating pH, control of initial pH and fermentation temperature. However, due to the dispersion of data observed in some instances, the ambiguity about the presence of additional hidden variables cannot be resolved. The results from the analysis thus suggest that, for reliable predictive models of fermentative hydrogen production to be derived, a high level of consistency between data is strictly required, claiming for more systematic and comprehensive studies on the subject.

  2. Hydrogen Pathways: Updated Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Ten Hydrogen Production, Delivery, and Distribution Scenarios

    SciTech Connect (OSTI)

    Ramsden, T.; Ruth, M.; Diakov, V.; Laffen, M.; Timbario, T. A.

    2013-03-01

    This report describes a life-cycle assessment conducted by the National Renewable Energy Laboratory (NREL) of 10 hydrogen production, delivery, dispensing, and use pathways that were evaluated for cost, energy use, and greenhouse gas (GHG) emissions. This evaluation updates and expands on a previous assessment of seven pathways conducted in 2009. This study summarizes key results, parameters, and sensitivities to those parameters for the 10 hydrogen pathways, reporting on the levelized cost of hydrogen in 2007 U.S. dollars as well as life-cycle well-to-wheels energy use and GHG emissions associated with the pathways.

  3. Hydrogen Pathways: Updated Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Ten Hydrogen Production, Delivery, and Distribution Scenarios

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Pathways Updated Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Ten Hydrogen Production, Delivery, and Distribution Scenarios T. Ramsden, M. Ruth, V. Diakov National Renewable Energy Laboratory M. Laffen, T.A. Timbario Alliance Technical Services, Inc. Technical Report NREL/TP-6A10-60528 March 2013 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable

  4. Midwest Hydro Users Group Meeting

    Broader source: Energy.gov [DOE]

    The Midwest Hydro Users Group will be holding their annual Fall meeting on November 12th and 13th in Wausau, Wisconsin.  An Owners-only meeting on the afternoon of the 12th followed by a full...

  5. Pumped Hydro | Open Energy Information

    Open Energy Info (EERE)

    Introduction caption:Pumped Storage diagram at TVA's Racoon mountain Pumped Hydro is an energy storage technique where water is used as a medium in order to store energy. During...

  6. Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis

    SciTech Connect (OSTI)

    T.A. Semelsberger

    2004-10-01

    The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

  7. Production of hydrogen by thermocatalytic cracking of natural gas. Task 4 report; Annual report

    SciTech Connect (OSTI)

    1995-10-01

    The conventional methods of hydrogen production from natural gas, for example, steam reforming (SR), are complex multi-step processes. These processes also result in the emission of large quantities of CO{sub 2} into the atmosphere. One alternative is the single-step thermocatalytic cracking (TCC) (or decomposition) of natural gas into hydrogen and carbon. The comparative assessment of SR and TCC processes was conducted. Thermocatalytic cracking of methane over various catalysts and supports in a wide range of temperatures (500--900 C) and flow rates was conducted. Two types of fix bed catalytic reactors were designed, built and tested: continuous flow and pulse reactors. Ni-Mo/Alumina and Fe-catalysts demonstrated relatively high efficiency in the methane cracking reaction at the range of temperatures 600--800 C. Fe-catalyst demonstrated fairly good stability, whereas alumina-supported Pt-catalyst rapidly lost its catalytic activity. Methane decomposition reaction over Ni-Mo/alumina was studied over wide range of space velocities in a continuous flow fixed bed catalytic reactor. The experimental results indicate that the hydrogen yield decreases noticeably with an increase in the space velocity of methane. The pulse type catalytic reactor was used to test the activity of the catalysts. It was found that induction period on the kinetic curve of hydrogen production corresponded to the reduction of metal oxide to metallic form of the catalyst. SEM method was used to study the structure of the carbon deposited on the catalyst surface.

  8. Co-Production of Electricity and Hydrogen Using a Novel Iron-based Catalyst

    SciTech Connect (OSTI)

    Hilaly, Ahmad; Georgas, Adam; Leboreiro, Jose; Arora, Salil; Head, Megann; Trembly, Jason; Turk, Brian; Gupta, Raghubir

    2011-09-30

    The primary objective of this project was to develop a hydrogen production technology for gasification applications based on a circulating fluid-bed reactor and an attrition resistant iron catalyst. The work towards achieving this objective consisted of three key activities: • Development of an iron-based catalyst suitable for a circulating fluid-bed reactor • Design, construction, and operation of a bench-scale circulating fluid-bed reactor system for hydrogen production • Techno-economic analysis of the steam-iron and the pressure swing adsorption hydrogen production processes. This report describes the work completed in each of these activities during this project. The catalyst development and testing program prepared and iron-based catalysts using different support and promoters to identify catalysts that had sufficient activity for cyclic reduction with syngas and steam oxidation and attrition resistance to enable use in a circulating fluid-bed reactor system. The best performing catalyst from this catalyst development program was produced by a commercial catalyst toll manufacturer to support the bench-scale testing activities. The reactor testing systems used during material development evaluated catalysts in a single fluid-bed reactor by cycling between reduction with syngas and oxidation with steam. The prototype SIP reactor system (PSRS) consisted of two circulating fluid-bed reactors with the iron catalyst being transferred between the two reactors. This design enabled demonstration of the technical feasibility of the combination of the circulating fluid-bed reactor system and the iron-based catalyst for commercial hydrogen production. The specific activities associated with this bench-scale circulating fluid-bed reactor systems that were completed in this project included design, construction, commissioning, and operation. The experimental portion of this project focused on technical demonstration of the performance of an iron-based catalyst and a circulating fluid-bed reactor system for hydrogen production. Although a technology can be technically feasible, successful commercial deployment also requires that a technology offer an economic advantage over existing commercial technologies. To effective estimate the economics of this steam-iron process, a techno-economic analysis of this steam iron process and a commercial pressure swing adsorption process were completed. The results from this analysis described in this report show the economic potential of the steam iron process for integration with a gasification plant for coproduction of hydrogen and electricity.

  9. System Evaluation and Economic Analysis of a Nuclear Reactor Powered High-Temperature Electrolysis Hydrogen-Production Plant

    SciTech Connect (OSTI)

    E. A. Harvego; M. G. McKellar; M. S. Sohal; J. E. O'Brien; J. S. Herring

    2010-06-01

    A reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production was developed to provide a basis for comparing the HTE concept with other hydrogen production concepts. The reference plant design is driven by a high-temperature helium-cooled nuclear reactor coupled to a direct Brayton power cycle. The reference design reactor power is 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 540°C and 900°C, respectively. The electrolysis unit used to produce hydrogen includes 4,009,177 cells with a per-cell active area of 225 cm2. The optimized design for the reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes an air-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The inlet air for the air-sweep system is compressed to the system operating pressure of 5.0 MPa in a four-stage compressor with intercooling. The alternating current (AC) to direct current (DC) conversion efficiency is 96%. The overall system thermal-to-hydrogen production efficiency (based on the lower heating value of the produced hydrogen) is 47.1% at a hydrogen production rate of 2.356 kg/s. An economic analysis of this plant was performed using the standardized H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program, and using realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.23/kg of hydrogen was calculated assuming an internal rate of return of 10%.

  10. Hydrogenation apparatus

    DOE Patents [OSTI]

    Friedman, Joseph (Encino, CA); Oberg, Carl L. (Canoga Park, CA); Russell, Larry H. (Agoura, CA)

    1981-01-01

    Hydrogenation reaction apparatus comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1100.degree. to 1900.degree. C., while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products.

  11. Carbonaceous material for production of hydrogen from low heating value fuel gases

    DOE Patents [OSTI]

    Koutsoukos, Elias P. (Los Angeles, CA)

    1989-01-01

    A process for the catalytic production of hydrogen, from a wide variety of low heating value fuel gases containing carbon monoxide, comprises circulating a carbonaceous material between two reactors--a carbon deposition reactor and a steaming reactor. In the carbon deposition reactor, carbon monoxide is removed from a fuel gas and is deposited on the carbonaceous material as an active carbon. In the steaming reactor, the reactive carbon reacts with steam to give hydrogen and carbon dioxide. The carbonaceous material contains a metal component comprising from about 75% to about 95% cobalt, from about 5% to about 15% iron, and up to about 10% chromium, and is effective in suppressing the production of methane in the steaming reactor.

  12. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  13. Production and Engineering of Hydrogenase as a Biocatalyst for Hydrogen Fuel

    SciTech Connect (OSTI)

    Wang, Guangyi

    2010-04-09

    Hydrogenases are fascinating redox proteins, showing tremendous promise in the utilization of hydrogen fuel as a bioelectrocatalyst. They play critical roles in both biohydrogen production and hydrogen oxidation. Specifically, the recently-established comparability of the oxidative activity of the [NiFe]-hydrogenase active site to that of the fuel cell catalyst platinum marks a significant milestone for the potential application of hydrogenase in hydrogen fuel cells to replace platinum. However, the ability of producing hydrogenase in heterologous expression hosts and the sensitivity of hydrogenases to oxygen and carbon monoxide, etc. have seriously limited the viable macroscale utilization and production of hydrogen from the renewable source. A new technology for the production of up-take hydrogenase is being developed for the utilization of hydrogenase as a hydrogen catalyst. The development of this new technology integrates knowledge of structural biology, molecular biology, and principles of metabolic engineering to produce and engineer a stable hydrogenase as a hydrogen bioelectrocatalyst. It contributes to the critical issues of expensive noble metal catalysts (i.e., platinum) and their limited reserves threatening the long-term sustainability of a hydrogen economy. It also provides a model to design natural materials and enzyme catalyst for efficient and cost-effective technologies for a clean and sustainable energy in 21st century. This new technology includes 3 major components. The first component is the synthetic operons, which carry hydrogenase maturation pathways of Ralstonia eutropha. These synthetic operons are engineered to produce RH hydrogenase in the Escherichia coli strains based on our current molecular and genetic information of hydrogenase maturation mechanisms and pathways of R. eutropha. It presents the first example of producing hydrogenase in the conventional expression host using synthetic biology principles and tool kits. For the high-yield production of the hydrogenase, protein degradation pathways are altered to prevent hydrogenase degradation. This part of the new technology provides a frame work for the design of hydrogenase production pathways for desirable bioengineering purposes. The results of this work are significantly beneficial to research in the areas of enzyme fuel cells, bioelectrocatalyst production, and biohydrogen production as well as basic research in hydrogenase structure biology. The second component of the new technology includes the stable hydrogenase with the improved electrochemical and catalytic properties. With the guidance of the current information on [NiFe] hydrogenase structure, hydrogenase mutants and mutant libraries are generated using protein engineering approaches. The resulting mutants are screened for better hydrogenase stability and catalytic activities. This part of the research results in the identification of new hydrogenase mutants with improved catalytic properties, which can be used for the future studies on enzyme full cells and the catalytic mechanism of hydrogenase. The third component is the optimized production of the selected hydrogenase mutant using current fermentation and metabolic engineering strategies. Metabolic burdens and biomass is balanced using different induction conditions for the optimum production of the engineered hydrogenase in genetically engineered E. coli strains. The success of this work presents a good example of the application of modern fermentation technologies in bioelectrocatalyst production.

  14. Yushan Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Yushan Hydro Power Development Co Ltd Jump to: navigation, search Name: Yushan Hydro Power Development Co. Ltd. Place: Chongqing, Jiangsu Province, China Zip: 405800 Sector: Hydro...

  15. Jinxiu Guangneng Hydro Power Company Ltd | Open Energy Information

    Open Energy Info (EERE)

    Guangneng Hydro Power Company Ltd Jump to: navigation, search Name: Jinxiu Guangneng Hydro Power Company Ltd. Place: Guangxi Autonomous Region, China Zip: 530022 Sector: Hydro...

  16. Fujian Jinzaoqiao Hydro Power Limited Corporation | Open Energy...

    Open Energy Info (EERE)

    Jinzaoqiao Hydro Power Limited Corporation Jump to: navigation, search Name: Fujian Jinzaoqiao Hydro Power Limited Corporation Place: Ningde, Fujian Province, China Sector: Hydro...

  17. Janapadu Hydro Power Project Pvt Ltd JHPPPL | Open Energy Information

    Open Energy Info (EERE)

    Janapadu Hydro Power Project Pvt Ltd JHPPPL Jump to: navigation, search Name: Janapadu Hydro Power Project Pvt. Ltd.(JHPPPL) Place: Andhra Pradesh, India Zip: 522005 Sector: Hydro...

  18. Him Kailash Hydro Power P Ltd | Open Energy Information

    Open Energy Info (EERE)

    Him Kailash Hydro Power P Ltd Jump to: navigation, search Name: Him Kailash Hydro Power (P) Ltd. Place: West Godavari District, Andhra Pradesh, India Zip: 434101 Sector: Hydro...

  19. Shri Shashi Hydro Electric Power P Ltd | Open Energy Information

    Open Energy Info (EERE)

    Shri Shashi Hydro Electric Power P Ltd Jump to: navigation, search Name: Shri Shashi Hydro Electric Power (P) Ltd. Place: Mandi, Himachal Pradesh, India Zip: 174401 Sector: Hydro...

  20. Guizhou Sanhe Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Hydro Power Development Co Ltd Jump to: navigation, search Name: Guizhou Sanhe Hydro Power Development Co.Ltd. Place: Guiyang, Guizhou Province, China Zip: 550002 Sector: Hydro...

  1. Antu County Hengxin Hydro Power Development Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Antu County Hengxin Hydro Power Development Co Ltd Jump to: navigation, search Name: Antu County Hengxin Hydro Power Development Co., Ltd Place: China Zip: 133609 Sector: Hydro...

  2. Qingyuan Longjing Hydro Power Development Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Longjing Hydro Power Development Co Ltd Jump to: navigation, search Name: Qingyuan Longjing Hydro Power Development Co. Ltd. Place: Lishui City, China Zip: 323800 Sector: Hydro...

  3. Ningshan Luotuoya Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ningshan Luotuoya Hydro Power Co Ltd Jump to: navigation, search Name: Ningshan Luotuoya Hydro Power Co. Ltd., Place: Ankang, Shaanxi Province, China Zip: 711600 Sector: Hydro...

  4. Sunan Longchanghe Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Sunan Longchanghe Hydro Power Co Ltd Jump to: navigation, search Name: Sunan Longchanghe Hydro Power Co., Ltd Place: Zhangye, Gansu Province, China Zip: 620721 Sector: Hydro...

  5. Kapil Mohan Associates Hydro Power Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Kapil Mohan Associates Hydro Power Pvt Ltd Jump to: navigation, search Name: Kapil Mohan & Associates Hydro Power Pvt. Ltd. Place: Chandigarh, Chandigarh, India Sector: Hydro...

  6. Sichuan Xingchen Hydro Investment Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Xingchen Hydro Investment Co Ltd Jump to: navigation, search Name: Sichuan Xingchen Hydro Investment Co., Ltd. Place: Mianyang, Sichuan Province, China Zip: 617067 Sector: Hydro...

  7. Sichuan Tianquan Xiacun Hydro Generation Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Xiacun Hydro Generation Co Ltd Jump to: navigation, search Name: Sichuan Tianquan Xiacun Hydro Generation Co. Ltd Place: Ya'an, Sichuan Province, China Zip: 625500 Sector: Hydro...

  8. Paschim Hydro Energy Pvt Ltd PHEPL | Open Energy Information

    Open Energy Info (EERE)

    Paschim Hydro Energy Pvt Ltd PHEPL Jump to: navigation, search Name: Paschim Hydro Energy Pvt. Ltd. (PHEPL) Place: Hyderabad, Andhra Pradesh, India Zip: 500034 Sector: Hydro...

  9. Evaluation of the Potential Environmental Impacts from Large-Scale Use and Production of Hydrogen in Energy and Transportation Applications

    SciTech Connect (OSTI)

    Wuebbles, D.J.; Dubey, M.K., Edmonds, J.; Layzell, D.; Olsen, S.; Rahn, T.; Rocket, A.; Wang, D.; Jia, W.

    2010-06-01

    The purpose of this project is to systematically identify and examine possible near and long-term ecological and environmental effects from the production of hydrogen from various energy sources based on the DOE hydrogen production strategy and the use of that hydrogen in transportation applications. This project uses state-of-the-art numerical modeling tools of the environment and energy system emissions in combination with relevant new and prior measurements and other analyses to assess the understanding of the potential ecological and environmental impacts from hydrogen market penetration. H2 technology options and market penetration scenarios will be evaluated using energy-technology-economics models as well as atmospheric trace gas projections based on the IPCC SRES scenarios including the decline in halocarbons due to the Montreal Protocol. Specifically we investigate the impact of hydrogen releases on the oxidative capacity of the atmosphere, the long-term stability of the ozone layer due to changes in hydrogen emissions, the impact of hydrogen emissions and resulting concentrations on climate, the impact on microbial ecosystems involved in hydrogen uptake, and criteria pollutants emitted from distributed and centralized hydrogen production pathways and their impacts on human health, air quality, ecosystems, and structures under different penetration scenarios

  10. Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors

    DOE Patents [OSTI]

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-10-14

    A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

  11. Metabolic Engineering and Modeling of Metabolic Pathways to Improve Hydrogen Production by Photosynthetic Bacteria

    SciTech Connect (OSTI)

    Jiao, Y.; Navid, A.

    2014-12-19

    Rising energy demands and the imperative to reduce carbon dioxide (CO2) emissions are driving research on biofuels development. Hydrogen gas (H2) is one of the most promising biofuels and is seen as a future energy carrier by virtue of the fact that 1) it is renewable, 2) does not evolve the greenhouse gas CO2 in combustion, 3) liberates large amounts of energy per unit weight in combustion (having about 3 times the energy content of gasoline), and 4) is easily converted to electricity by fuel cells. Among the various bioenergy strategies, environmental groups and others say that the concept of the direct manufacture of alternative fuels, such as H2, by photosynthetic organisms is the only biofuel alternative without significant negative criticism [1]. Biological H2 production by photosynthetic microorganisms requires the use of a simple solar reactor such as a transparent closed box, with low energy requirements, and is considered as an attractive system to develop as a biocatalyst for H2 production [2]. Various purple bacteria including Rhodopseudomonas palustris, can utilize organic substrates as electron donors to produce H2 at the expense of solar energy. Because of the elimination of energy cost used for H2O oxidation and the prevention of the production of O2 that inhibits the H2-producing enzymes, the efficiency of light energy conversion to H2 by anoxygenic photosynthetic bacteria is in principle much higher than that by green algae or cyanobacteria, and is regarded as one of the most promising cultures for biological H2 production [3]. Here implemented a simple and relatively straightforward strategy for hydrogen production by photosynthetic microorganisms using sunlight, sulfur- or iron-based inorganic substrates, and CO2 as the feedstock. Carefully selected microorganisms with bioengineered beneficial traits act as the biocatalysts of the process designed to both enhance the system efficiency of CO2 fixation and the net hydrogen production rate. Additionally we applied metabolic engineering approaches guided by computational modeling for the chosen model microorganisms to enable efficient hydrogen production.

  12. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  13. Pathways to Commercial Success: Technologies and Products Supported by the Hydrogen, Fuel Cells and Infrastructure Technologies Program

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report documents the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Hydrogen, Fuel Ce

  14. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  15. Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon

    DOE Patents [OSTI]

    Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

    2000-01-01

    In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

  16. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

  17. A review of recent advances of numerical simulations of microscale fuel processors for hydrogen production

    SciTech Connect (OSTI)

    Holladay, Jamelyn D.; Wang, Yong

    2015-05-01

    Microscale (<5W) reformers for hydrogen production have been investigated for over a decade. These devices are intended to provide hydrogen for small fuel cells. Due to the reformers small size, numerical simulations are critical to understand heat and mass transfer phenomena occurring in the systems. This paper reviews the development of the numerical codes and details the reaction equations used. The majority of the devices utilized methanol as the fuel due to methanols low reforming temperature and high conversion, although, there are several methane fueled systems. As computational power has decreased in cost and increased in availability, the codes increased in complexity and accuracy. Initial models focused on the reformer, while more recently, the simulations began including other unit operations such as vaporizers, inlet manifolds, and combustors. These codes are critical for developing the next generation systems. The systems reviewed included, plate reactors, microchannel reactors, annulus reactors, wash-coated, packed bed systems.

  18. EA-281-B Manitoba Hydro | Department of Energy

    Energy Savers [EERE]

    -B Manitoba Hydro EA-281-B Manitoba Hydro Order authorizing Manitoba Hydro to export electric energy to Canada. PDF icon EA-281-B Manitoba Hydro More Documents & Publications EA-281

  19. Webinar January 21: Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis

    Broader source: Energy.gov [DOE]

    The Energy Department will present a live webinar titled "Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis" on Thursday, January 21, from 12 to 1 p.m. EST. This webinar will present the results of an analysis conducted by Sandia National Laboratories that explored potential synergies that may be realized by integrating solar hydrogen production and concentrating solar power (CSP) technologies.

  20. Webinar November 19: Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis

    Broader source: Energy.gov [DOE]

    The Energy Department will present a live webinar titled "Potential Strategies for Integrating Solar Hydrogen Production and Concentrating Solar Power: A Systems Analysis" on Thursday, November 19, from 1:00 to 2:00 p.m. EST. This webinar will present the results of an analysis conducted by Sandia National Laboratories that explored potential synergies that may be realized by integrating solar hydrogen production and concentrating solar power (CSP) technologies.

  1. Ocean thermal plantships for production of ammonia as the hydrogen carrier.

    SciTech Connect (OSTI)

    Panchal, C.B.; Pandolfini, P. P.; Kumm, W. H.; Energy Systems; Johns Hopkins Univ.; Arctic Energies, Ltd.

    2009-12-02

    Conventional petroleum, natural gas, and coal are the primary sources of energy that have underpinned modern civilization. Their continued availability in the projected quantities required and the impacts of emission of greenhouse gases (GHGs) on the environment are issues at the forefront of world concerns. New primary sources of energy are being sought that would significantly reduce the emissions of GHGs. One such primary source that can help supply energy, water, and fertilizer without GHG emissions is available in the heretofore unexploited thermal gradients of the tropical oceans. The world's oceans are the largest natural collector and reservoir of solar energy. The potential of ocean energy is limitless for producing base-load electric power or ammonia as the hydrogen carrier and fresh water from seawater. However, until now, ocean energy has been virtually untapped. The general perception is that ocean thermal energy is limited to tropical countries. Therefore, the full potential of at-sea production of (1) ammonia as a hydrogen carrier and (2) desalinated water has not been adequately evaluated. Using ocean thermal plantships for the at-sea co-production of ammonia as a hydrogen carrier and desalinated water offer potential energy, environmental, and economic benefits that support the development of the technology. The introduction of a new widespread solution to our projected energy supply requires lead times of a decade or more. Although continuation of the ocean thermal program from the 1970s would likely have put us in a mitigating position in the early 2000s, we still have a window of opportunity to dedicate some of our conventional energy sources to the development of this renewable energy by the time new sources would be critically needed. The primary objective of this project is to evaluate the technical and economic viability of ocean thermal plantships for the production of ammonia as the hydrogen carrier. This objective is achieved by completing project tasks that consist of updating the John Hopkins University/Applied Physics Laboratory (JHU/APL) pilot plantship design and extrapolating it to commercial plantships, evaluating a new energy-efficient ammonia synthesis process, evaluating the co-production of desalinated water on plantships, and developing a conceptual design of a satellite plantships system for commercial-scale ammonia production. In addition, an industrial workshop was organized to present the results and develop future goals for commercialization of ocean thermal plantships by 2015. The following goals, arranged in chronological order, were examined at the workshop: (1) Global displacement of petroleum-fuel-based (diesel, fuel oil, naphtha) power generation for freeing up these fuels for transportation, chemical feedstock, and other high-valued uses; (2) At-sea production of desalinated water for regions of critical water shortages; (3) Displacement of carbon-based feed stocks and energy for production of ammonia fertilizers; (4) Development of hydrogen supply to allow economic processing of heavy crude oils and upgrading oil sands; (5) Development of ammonia-fueled distributed energy to displace natural-gas fueled power generation to free up natural gas for higher-value uses and the mitigation of issues associated with imported liquefied natural gas (LNG); and (6) Use of ammonia as a hydrogen carrier for transportation.

  2. Hydrogen program overview

    SciTech Connect (OSTI)

    Gronich, S.

    1997-12-31

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  3. Hydro Research Program Seeking Graduate Student Applicants

    Broader source: Energy.gov [DOE]

    The Hydro Research Foundation is now accepting graduate student applications for its DOE-funded graduate student research program. The Hydro Research Awards Program is designed to spur innovation...

  4. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  5. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2005-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  6. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  7. Improving Photosynthesis for Hydrogen and Fuels Production - Webinar Q&A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improving Photosynthesis for Hydrogen and Fuels Production January 24, 2011 Webinar Q&A Q: How do you induce hypoxic photosynthesis? I imagine you N-stress, to accumulate starch first? A: Initially, sulfur deprivation was used as the tool by which to accumulate starch in the cells, and also to bring photosynthesis to a level lower than that of respiration. Since then, a number of labs in different countries have worked to devise genetic methods for achieving the same result without the

  8. Critical Updates to the Hydrogen Analysis Production Model (H2A v3)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Critical Updates to the Hydrogen Analysis Production Model (H2A v3) Darlene Steward NREL Thursday, February 9, 2012 3:00 PM - 4:30 PM EST Darlene.steward@nrel.gov (303) 275 3837 NREL/PR-5600-54276 NATIONAL RENEWABLE ENERGY LABORATORY Outline 2 Introduction - Sara Dillich Overview of the H2A Model H2A Version 3 Changes Case Study Walkthrough Resources 1 2 3 4 NATIONAL RENEWABLE ENERGY LABORATORY Outline 3 Introduction - Sara Dillich Overview of the H2A Model H2A Version 3 Changes Case Study

  9. Webinar: Critical Updates to the Hydrogen Analysis Production Model (H2A

    Broader source: Energy.gov (indexed) [DOE]

    v3) | Department of Energy Critical Updates to the Hydrogen Analysis Production Model (H2A v3)," originally presented on February 8, 2012. In addition to this text version of the audio, you can access the presentation slides. Darlene Steward: So I have a little presentation here. The real focus of this is to kind of walk folks through the model with the goal of really helping you understand how to use it. [Next Slide] So the outline...Sara has already given an introduction, so we're

  10. IEA Agreement on the production and utilization of hydrogen: 1996 annual report

    SciTech Connect (OSTI)

    Elam, Carolyn C. )

    1997-01-31

    The annual report includes an overview of the IEA Hydrogen Agreement, including a brief summary of hydrogen in general. The Chairman's report provides highlights for the year. Sections are included on hydrogen energy activities in the IEA Hydrogen Agreement member countries, including Canada, European Commission, Germany, Japan, Netherlands, Norway, Spain, Sweden, Switzerland, and the US. Lastly, Annex reports are given for the following tasks: Task 10, Photoproduction of Hydrogen, Task 11, Integrated Systems, and Task 12, Metal Hydrides and Carbon for Hydrogen Storage.

  11. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect (OSTI)

    2010-07-15

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  12. BIMETALLIC NANOCATALYSTS IN MESOPOROUS SILICA FOR HYDROGEN PRODUCTION FROM COAL-DERIVED FUELS

    SciTech Connect (OSTI)

    Kuila, Debasish; Ilias, Shamsuddin

    2013-02-13

    In steam reforming reactions (SRRs) of alkanes and alcohols to produce H{sub 2}, noble metals such as platinum (Pt) and palladium (Pd) are extensively used as catalyst. These metals are expensive; so, to reduce noble-metal loading, bi-metallic nanocatalysts containing non-noble metals in MCM-41 (Mobil Composition of Material No. 41, a mesoporous material) as a support material with high-surface area were synthesized using one-pot hydrothermal procedure with a surfactant such as cetyltrimethylammonium bromide (CTAB) as a template. Bi-metallic nanocatalysts of Pd-Ni and Pd-Co with varying metal loadings in MCM-41 were characterized by x-ray diffraction (XRD), N{sub 2} adsorption, and Transmission electron microscopy (TEM) techniques. The BET surface area of MCM-41 (~1000 m{sup 2}/g) containing metal nanoparticles decreases with the increase in metal loading. The FTIR studies confirm strong interaction between Si-O-M (M = Pd, Ni, Co) units and successful inclusion of metal into the mesoporous silica matrix. The catalyst activities were examined in steam reforming of methanol (SRM) reactions to produce hydrogen. Reference tests using catalysts containing individual metals (Pd, Ni and Co) were also performed to investigate the effect of the bimetallic system on the catalytic behavior in the SRM reactions. The bimetallic system remarkably improves the hydrogen selectivity, methanol conversion and stability of the catalyst. The results are consistent with a synergistic behavior for the Pd-Ni-bimetallic system. The performance, durability and thermal stability of the Pd-Ni/MCM-41 and Pd-Co/MCM-41 suggest that these materials may be promising catalysts for hydrogen production from biofuels. A part of this work for synthesis and characterization of Pd-Ni-MCM-41 and its activity for SRM reactions has been published (Development of Mesoporous Silica Encapsulated Pd-Ni Nanocatalyst for Hydrogen Production in Production and Purification of Ultraclean Transportation Fuels; Hu, Y., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2011.)

  13. A Theoretical Study of Methanol Synthesis from CO(2) Hydrogenation on Metal-doped Cu(111) Surfaces

    SciTech Connect (OSTI)

    Liu P.; Yang, Y.; White, M.G.

    2012-01-12

    Density functional theory (DFT) calculations and Kinetic Monte Carlo (KMC) simulations were employed to investigate the methanol synthesis reaction from CO{sub 2} hydrogenation (CO{sub 2} + 3H{sub 2} {yields} CH{sub 3}OH + H{sub 2}O) on metal-doped Cu(111) surfaces. Both the formate pathway and the reverse water-gas shift (RWGS) reaction followed by a CO hydrogenation pathway (RWGS + CO-Hydro) were considered in the study. Our calculations showed that the overall methanol yield increased in the sequence: Au/Cu(111) < Cu(111) < Pd/Cu(111) < Rh/Cu(111) < Pt/Cu(111) < Ni/Cu(111). On Au/Cu(111) and Cu(111), the formate pathway dominates the methanol production. Doping Au does not help the methanol synthesis on Cu(111). Pd, Rh, Pt, and Ni are able to promote the methanol production on Cu(111), where the conversion via the RWGS + CO-Hydro pathway is much faster than that via the formate pathway. Further kinetic analysis revealed that the methanol yield on Cu(111) was controlled by three factors: the dioxomethylene hydrogenation barrier, the CO binding energy, and the CO hydrogenation barrier. Accordingly, two possible descriptors are identified which can be used to describe the catalytic activity of Cu-based catalysts toward methanol synthesis. One is the activation barrier of dioxomethylene hydrogenation, and the other is the CO binding energy. An ideal Cu-based catalyst for the methanol synthesis via CO{sub 2} hydrogenation should be able to hydrogenate dioxomethylene easily and bond CO moderately, being strong enough to favor the desired CO hydrogenation rather than CO desorption but weak enough to prevent CO poisoning. In this way, the methanol production via both the formate and the RWGS + CO-Hydro pathways can be facilitated.

  14. Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils

    SciTech Connect (OSTI)

    Huber, George W; Vispute, Tushar P; Routray, Kamalakanta

    2014-06-03

    Disclosed herein is a method of generating hydrogen from a bio-oil, comprising hydrogenating a water-soluble fraction of the bio-oil with hydrogen in the presence of a hydrogenation catalyst, and reforming the water-soluble fraction by aqueous-phase reforming in the presence of a reforming catalyst, wherein hydrogen is generated by the reforming, and the amount of hydrogen generated is greater than that consumed by the hydrogenating. The method can further comprise hydrocracking or hydrotreating a lignin fraction of the bio-oil with hydrogen in the presence of a hydrocracking catalyst wherein the lignin fraction of bio-oil is obtained as a water-insoluble fraction from aqueous extraction of bio-oil. The hydrogen used in the hydrogenating and in the hydrocracking or hydrotreating can be generated by reforming the water-soluble fraction of bio-oil.

  15. Hydrogen Demand and Resource Analysis (HyDRA) Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    cost and availability, hydrogen production potential, hydrogen production cost, resource consumption, hydrogen demand, infrastructure, and results from integration with other...

  16. Engineering Bacteria for Efficient Fuel Production: Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Free Fatty Acids

    SciTech Connect (OSTI)

    2010-07-12

    Electrofuels Project: OPX Biotechnologies is engineering a microorganism currently used in industrial biotechnology to directly produce a liquid fuel from hydrogen and carbon dioxide (CO2). The microorganism has the natural ability to use hydrogen and CO2 for growth. OPX Biotechnologies is modifying the microorganism to divert energy and carbon away from growth and towards the production of liquid fuels in larger, commercially viable quantities. The microbial system will produce a fuel precursor that can be chemically upgraded to various hydrocarbon fuels.

  17. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure hydrogen and carbon nanotubes using binary Fe-based catalysts containing Mo, Ni, or Pd in a single step non-oxidative reaction. (7) Partial dehydrogenation of liquid hydrocarbons (cyclohexane and methyl cyclohexane) has been performed using catalysts consisting of Pt and other metals on stacked-cone carbon nanotubes. (8) An understanding of the catalytic reaction mechanisms of the catalysts developed in the CFFS C1 program is being achieved by structural characterization using multiple techniques, including XAFS and Moessbauer spectroscopy, XRD, TEM, NMR, ESR, and magnetometry.

  18. System Evaluation and Life-Cycle Cost Analysis of a Commercial-Scale High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Edwin A. Harvego; James E. O'Brien; Michael G. McKellar

    2012-11-01

    Results of a system evaluation and lifecycle cost analysis are presented for a commercial-scale high-temperature electrolysis (HTE) central hydrogen production plant. The plant design relies on grid electricity to power the electrolysis process and system components, and industrial natural gas to provide process heat. The HYSYS process analysis software was used to evaluate the reference central plant design capable of producing 50,000 kg/day of hydrogen. The HYSYS software performs mass and energy balances across all components to allow optimization of the design using a detailed process flow sheet and realistic operating conditions specified by the analyst. The lifecycle cost analysis was performed using the H2A analysis methodology developed by the Department of Energy (DOE) Hydrogen Program. This methodology utilizes Microsoft Excel spreadsheet analysis tools that require detailed plant performance information (obtained from HYSYS), along with financial and cost information to calculate lifecycle costs. The results of the lifecycle analyses indicate that for a 10% internal rate of return, a large central commercial-scale hydrogen production plant can produce 50,000 kg/day of hydrogen at an average cost of $2.68/kg. When the cost of carbon sequestration is taken into account, the average cost of hydrogen production increases by $0.40/kg to $3.08/kg.

  19. Final LDRD report : metal oxide films, nanostructures, and heterostructures for solar hydrogen production.

    SciTech Connect (OSTI)

    Kronawitter, Coleman X.; Antoun, Bonnie R.; Mao, Samuel S.

    2012-01-01

    The distinction between electricity and fuel use in analyses of global power consumption statistics highlights the critical importance of establishing efficient synthesis techniques for solar fuels-those chemicals whose bond energies are obtained through conversion processes driven by solar energy. Photoelectrochemical (PEC) processes show potential for the production of solar fuels because of their demonstrated versatility in facilitating optoelectronic and chemical conversion processes. Tandem PEC-photovoltaic modular configurations for the generation of hydrogen from water and sunlight (solar water splitting) provide an opportunity to develop a low-cost and efficient energy conversion scheme. The critical component in devices of this type is the PEC photoelectrode, which must be optically absorptive, chemically stable, and possess the required electronic band alignment with the electrochemical scale for its charge carriers to have sufficient potential to drive the hydrogen and oxygen evolution reactions. After many decades of investigation, the primary technological obstacle remains the development of photoelectrode structures capable of efficient conversion of light with visible frequencies, which is abundant in the solar spectrum. Metal oxides represent one of the few material classes that can be made photoactive and remain stable to perform the required functions.

  20. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.