Sample records for hydro cracking catalytic

  1. Catalytic cracking of residual petroleum fractions

    SciTech Connect (OSTI)

    Moore, H.F.; Mayo, S.L.; Goolsby, T.L. (Research and Development Dept., Ashland Petroleum Co., Ashland, KY (US))

    1991-01-01T23:59:59.000Z

    This paper reports on Arabian Light crude oil vacuum bottoms fractionated into five high-boiling fractions by wiped film evaporation, and the fractions subjected to catalytic cracking in a fixed-fluidized bed using a commercial equilibrium cracking catalyst. Density, aromaticity, and heteroatom content generally increased with boiling point, as did metals content except for vanadium and iron which demonstrated possible bimodal distributions. The cracking response of these fractions showed increasing yields of dry gas and coke, with decreasing gasoline yields, as a function of increasing apparent boiling point as would normally be expected. Surprisingly, however, local maxima were observed for wet gas yield and total conversion, with local minima for cycle oil and slurry yields, in the region of the 1200-1263{degrees}F (650-680{degrees}C) middle fraction. All fractions showed significant response to cracking, with coke yields generally being the only negative factor observed.

  2. Protocol development for evaluation of commercial catalytic cracking catalysts

    SciTech Connect (OSTI)

    Mitchell, M.M. Jr.; Moore, H.F. (Ashland Petroleum Co., KY (USA))

    1988-09-01T23:59:59.000Z

    A complete, new set of testing protocols has been developed for qualification of catalysts for Ashland's commercial catalytic cracking units. The objective of this test development is to identify new generations of improved cracking catalysts. Prior test protocols have classically utilized microactivity (MAT) testing of steamed virgin catalysts, while more advanced methods have utilized fixed fluid bed and/or circulating pilot units. Each of these techniques, however, have been limited by their correlation to commercial operations, weaknesses in metallation and preparation of pseudo-equilibrium catalysts, and mechanical constraints on the use of heavy, vacuum bottoms-containing feedstocks. These new protocols have been baselined, compared to commercial Ashland results on known catalytic cracking catalysts, and utilized to evaluate a range of potentially new catalyst samples.

  3. Hydro-Mechanical Coupling in Damaged Porous Media Containing Isolated Cracks or/and Vugs: Model and Computations

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Hydro-Mechanical Coupling in Damaged Porous Media Containing Isolated Cracks or/and Vugs: Model In this paper we present the development of the macroscopic model describing the hydro-mechanical coupling) In this paper we present the macroscopic model describing the hydro-mechanical behaviour of such class

  4. Diffusion and Catalytic Cracking of 1,3,5 Tri-iso-propyl-benzene in FCC Catalysts

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    1 Diffusion and Catalytic Cracking of 1,3,5 Tri-iso- propyl-benzene in FCC Catalysts S.Al-Khattaf1 describes catalytic cracking experiments developed in a novel CREC Riser Simulator using 1,3,5-Tri-iso

  5. Methods applied to investigate the major VCE that occured in the TOTAL refinery's Fluid Catalytic Cracking Unit at La Mede,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    95-35 Methods applied to investigate the major ?VCE that occured in the TOTAL refinery's Fluid.V.C.E, occured in the Gas Plant of the TOTAL refinery's Fluid Catalytic Cracking ünit at La Mede, France

  6. Economics for iso-olefin production using the fluid catalytic cracking unit

    SciTech Connect (OSTI)

    McClung, R.G.; Witoshkin, A.; Bogert, D.C.; Winkler, W.S. [Englehard Corp., Iselin, NJ (United States)

    1993-12-31T23:59:59.000Z

    The Clean Air Act of 1990 requires use of oxygenates in some gasolines to improve both CO and hydrocarbon auto tailpipe emissions. Various oxygenates are currently being used by the refining industry. For the fully integrated refinery having a fluid catalytic cracking unit, the most commonly used oxygenates are methyl tertiary butyl ether (MTBE) and tertiary amyl ether (TAME). The FCC unit produces the isobutylene and iso-amylases need for manufacture of both MTBE and TAME. The economics for an assumed refinery processing scheme for several FCC cases are examined giving estimates of income and investments for each case. Up to one-third of the total gasoline pool can be made in reformulated gasoline using TAME and MTBE with the FCC unit as the sole source of feedstock. This processing route is much more economical than the alternative scheme using butane isomerization/iosbutane dehydrogenation.

  7. A lightweight three-phase Fluid Catalytic Cracking riser model for real-time simulation and interactive three-dimensional visualization

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    physical model and a fast numerical solver are proposed for the rendering of fluid catalytic cracking (FCC) dynamics in the riser cylinder reactor part of the FCC unit. For Real Time requirements, a trade, privileged paths for the gas phase, etc. Of course, the rendering is purely qualitative, but accurate enough

  8. Constraints on the lake volume required for hydro-fracture through ice sheets

    E-Print Network [OSTI]

    Skemer, Philip

    Constraints on the lake volume required for hydro-fracture through ice sheets M. J. Krawczynski,1 M April 2009; published 16 May 2009. [1] Water-filled cracks are an effective mechanism to drive hydro to rapidly drive hydro-fractures through 1­1.5 km of subfreezing ice. This represents $98% of the meltwater

  9. Saber's heavy oil cracking refinery project

    SciTech Connect (OSTI)

    Benefield, C.S.; Glasscock, W.L.

    1983-03-01T23:59:59.000Z

    Perhaps more than any other industry, petroleum refining has been subjected to the radical swings in business and political climates of the past several decades. Because of the huge investments and long lead times to construct refining facilities, stable government policies, predictable petroleum prices, secure feedstock supplies and markets, and reliable cost estimates are necessary ingredients to effectively plan new refinery projects. However, over the past ten years the political and economic climates have provided anything but these conditions. Yet, refiners have demonstrated a willingness to undertake risks by continuing to expand and modernize their refineries. The refining business -- just as most businesses -- responds to economic incentives. These incentives, when present, result in new technology and capacity additions. In the 1940's, significant technology advances were commercialized to refine higher-octane motor gasolines. Such processes as continuous catalytic cracking (Houdry Process Corporation), fluid catalytic cracking (Standard Oil Development Company), HF alkylation (UOP and Phillips Petroleum Company), and catalytic reforming (UOP) began to supply a growing gasoline market, generated from the war effort and the ever increasing numbers of automobiles on the road. The post-war economy of the 1950's and 1960's further escalated demand for refined products, products which had to meet higher performance specifications and be produced from a wider range of raw materials. The refining industry met the challenge by introducing hydro-processing technology, such as hydrocracking developed in 1960. But, the era must be characterized by the large crude processing capacity additions, required to meet demand from the rapidly expanding U.S. economy. In 1950, refining capacity was 6.2 million BPD. By 1970, capacity had grown to 11.9 million BPD, an increase of 91%.

  10. Wind/Hydro Study

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WindHydro Integration Feasibility Study Announcements (Updated July 8, 2010) The Final WindHydro Integration Feasibility Study Report, dated June 2, 2009, has been submitted to...

  11. Hydro Capital Asset Manager

    Broader source: Energy.gov [DOE]

    This position is located in Federal Hydro Projects, Generation Asset Management, Power Services. Additional vacancies may be filled through this vacancy announcement or if they become available.

  12. Fluid Catalytic Cracking Power Recovery Computer Simulation

    E-Print Network [OSTI]

    Samurin, N. A.

    1979-01-01T23:59:59.000Z

    operating conditions. The digital computer model simulates the performance of the axial compressor, power recovery expander, regenerator section, and system pressure drops. The program can simulate the process system design conditions for compatibility...

  13. Carbenium ion intermediates in catalytic cracking

    E-Print Network [OSTI]

    Zardkoohi, Minoo

    1987-01-01T23:59:59.000Z

    C, (d) 300 C, (e) 400 C C HNR spectra of sec-butyl chloride antimony pentafluoride mixture 16 13C NMR spectrum of C- ethene on H-ZSN5 . . . . 19 C CPNAS spectrum of tri-phenylmethyl chloride adsorbed on silica-alumina Schematic representation... &Vdk' 800 me )OO 0 - 100 -200 PPll Fig. 5 l~C CPNAS spectrum of tri-phenylmethyl chloride adsorbed on silica-alumina. 21 times, techniques which allow for moderately higher reso- lution are required. One such technique is combined cross...

  14. The complexity of catalytically "cracking" cellulose | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chain length affects oxygen's departure in key reaction for building bio-fuels Replacing fossil fuels in industrial applications could reduce economic, environmental and security...

  15. The complexity of catalytically "cracking" cellulose | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    However, transforming bio-feedstock into fuels means quickly and efficiently removing oxygen atoms. World energy consumption is predicted to grow by more than 50 percent between...

  16. Fluid Catalytic Cracking Power Recovery Computer Simulation

    E-Print Network [OSTI]

    Samurin, N. A.

    1979-01-01T23:59:59.000Z

    operating conditions. The digital computer model simulates the performance of the axial compressor, power recovery expander, regenerator section, and system pressure drops. The program can simulate the process system design conditions for compatibility...

  17. Catalytic Distillation

    E-Print Network [OSTI]

    Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

    1984-01-01T23:59:59.000Z

    Catalytic Distillation' refers to a chemical process which performs both a catalyzed reaction and primary fractionation of the reaction components simultaneously. A structured catalyst which also is an effective distillation component has been...

  18. New catalysts improves heavy feedstock hydro-cracking

    SciTech Connect (OSTI)

    Hoek, A.; Huizinga, T.; Esener, A.A.; Maxwell, I.E.; Stork, W. (Koninklijke/Shell Laboratorium, Amsterdam (NL)); van de Meerakker, F.J. (Shell Internationale Petroleum Maatschappij BV, The Hauge (NL)); Sy, O. (Shell Canada Ltd., Oakville, Ontario (CA))

    1991-04-22T23:59:59.000Z

    A new zeolite-Y-based second-stage hydrocracking catalyst, designated S-703, has been developed by Shell. Laboratory testing and commercial use show it has significantly improved performance with respect to gas make and middle-distillate selectivity in processing heavy feedstocks when compared to a Shell catalyst, S-753, developed earlier. Further, the new catalyst exhibits enhanced stability. Extensive laboratory testing of the S-703 catalyst has been carried out under single-stage, stacked- bed, two-stage-flow, and series-flow conditions. Commercial experience with the new catalyst has now been obtained in several units. To date, the commercial results have confirmed the laboratory results in terms of the superior, heavy- feedstock processing performance of the new catalyst in all respects. Because the trend toward heavier feedstocks is expected to continue, it is likely that catalysts such as S- 703 will find increasing applications in hydrocrackers in the future.

  19. A COMPARISON OF THE AQUATIC IMPACTS OF LARGE HYDRO AND SMALL HYDRO PROJECTS

    E-Print Network [OSTI]

    A COMPARISON OF THE AQUATIC IMPACTS OF LARGE HYDRO AND SMALL HYDRO PROJECTS by Lara A. Taylor, P Project: A Comparison of the Aquatic Impacts of Large Hydro and Small Hydro Projects Project No.: 501 of small hydro development in British Columbia has raised concerns surrounding the effects

  20. Ontario Hydro Motor Efficiency Study

    E-Print Network [OSTI]

    Dautovich, D. R.

    1980-01-01T23:59:59.000Z

    Electric motors consume more than one-half of the electrical energy produced by Ontario Hydro. In the residential sector, the major motor load is for refrigerators and freezers while packaged equipment dominate the motor load in the commercial...

  1. Midwest Hydro Users Group Meeting

    Broader source: Energy.gov [DOE]

    The Midwest Hydro Users Group will be holding their annual Fall meeting on November 12th and 13th in Wausau, Wisconsin. An Owners-only meeting on the afternoon of the 12th followed by a full...

  2. CATALYTIC BIOMASS LIQUEFACTION

    E-Print Network [OSTI]

    Ergun, Sabri

    2013-01-01T23:59:59.000Z

    LBL-11 019 UC-61 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,Catalytic Liquefaction of Biomass,n M, Seth, R. Djafar, G.of California. CATALYTIC BIOMASS LIQUEFACTION QUARTERLY

  3. Extreme hydro-meteorological events and their probabilities

    E-Print Network [OSTI]

    Beersma, Jules

    Extreme hydro-meteorological events and their probabilities Jules Beersma #12;Promotor: Prof. dr. A Onderzoekschool (BBOS) #12;Extreme hydro-meteorological events and their probabilities Extreme hydro

  4. Catalytic Coherence

    E-Print Network [OSTI]

    Johan Aberg

    2014-10-20T23:59:59.000Z

    Due to conservation of energy we cannot directly turn a quantum system with a definite energy into a superposition of different energies. However, if we have access to an additional resource in terms of a system with a high degree of coherence, as for standard models of laser light, we can overcome this limitation. The question is to what extent coherence gets degraded when utilized. Here it is shown that coherence can be turned into a catalyst, meaning that we can use it repeatedly without ever diminishing its power to enable coherent operations. This finding stands in contrast to the degradation of other quantum resources, and has direct consequences for quantum thermodynamics, as it shows that latent energy that may be locked into superpositions of energy eigenstates can be released catalytically.

  5. Catalytic reactor

    DOE Patents [OSTI]

    Aaron, Timothy Mark (East Amherst, NY); Shah, Minish Mahendra (East Amherst, NY); Jibb, Richard John (Amherst, NY)

    2009-03-10T23:59:59.000Z

    A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

  6. Doctoral Defense "Thermal-hydro-mechanical model

    E-Print Network [OSTI]

    Kamat, Vineet R.

    Doctoral Defense "Thermal-hydro-mechanical model for freezing and thawing soils" Yao Zhang Date been implemented in a finite element system, with a thermal-hydro- mechanical framework being used

  7. Hydro Research Program Seeking Graduate Student Applicants

    Broader source: Energy.gov [DOE]

    The Hydro Research Foundation is now accepting graduate student applications for its DOE-funded graduate student research program. The Hydro Research Awards Program is designed to spur innovation...

  8. Hydro-Qubec Net Metering (Quebec, Canada)

    Broader source: Energy.gov [DOE]

    In line with Hydro-Qubec's commitment to the environment and sustainable development, Hydro-Qubec is supporting self-generation with a new rate offering: the net metering option. This option...

  9. North West Hydro Resource Model Research to identify potential capacity and assist NW hydro power development

    E-Print Network [OSTI]

    Meju, Max

    North West Hydro Resource Model Research to identify potential capacity and assist NW hydro power University wide research, aims to develop a system to promote the exploitation of hydro power in North with regard to hydro schemes Reviewing and re-formulating ill defined requirements for environmental

  10. Prparation de votre examen stabilit hydro

    E-Print Network [OSTI]

    Hoepffner, Jérôme

    Préparation de votre examen stabilité hydro: - Relisez vos notes de cours - Refaites les exercices

  11. 4, 18791891, 2007 hydro-information

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    HESSD 4, 1879­1891, 2007 WS for hydro-information systems J. Horak et al. Title Page Abstract for distributed and interoperable hydro-information systems J. Horak, A. Orlik, and J. Stromsky Institute (antonin.orlik.hgf@vsb.cz) 1879 #12;HESSD 4, 1879­1891, 2007 WS for hydro-information systems J. Horak et

  12. CATALYTIC LIQUEFACTION OF BIOMASS

    E-Print Network [OSTI]

    Seth, Manu

    2012-01-01T23:59:59.000Z

    liquid Fuels from Biomass: "Catalyst Screening and KineticUC-61 (l, RCO osn CDL or BIOMASS CATALYTIC LIQUEFACTION ManuCATALYTIC LIQUEFACTION OF BIOMASS Manu Seth, Roger Djafar,

  13. CATALYTIC BIOMASS LIQUEFACTION

    E-Print Network [OSTI]

    Ergun, Sabri

    2013-01-01T23:59:59.000Z

    Solvent Systems Catalystic Biomass Liquefaction Investigatereactor Product collection Biomass liquefaction process12-13, 1980 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,

  14. Hydrocarbon cracking with yttrium exchanged zeolite y catalyst

    SciTech Connect (OSTI)

    Lochow, C.F.; Kovacs, D.B.

    1987-05-12T23:59:59.000Z

    A process is described for cracking a gas oil boiling range hydrocarbon feedstock comprising the step of contacting the feedstock in a catalytic cracking zone under catalytic cracking conditions to produce convulsion products comprising gasoline with a catalyst composition. The process comprises: a Y crystalline aluminosilicate zeolite, having the structure of faujasite and having uniform pore diameters and a silica to alumina mole ratio of at least about 5; an inorganic oxide matrix; and the zeolite having been ion exchanged with a mixture of rare earths prior to compositing with the matrix; and the zeolite having been subsequently further ion exchanged with yttrium following compositing with the matrix, whereby the catalyst composition contains 0.30 to 3.0 wt% yttrium.

  15. Crack coalescence in granite

    E-Print Network [OSTI]

    Miller, James Thomas, Ph. D. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    This thesis experimentally investigates crack coalescence in prismatic Barre Granite specimens with two pre-cut, open flaws under uniaxial compression. Using a high-speed video system, crack initiation, propagation, and ...

  16. Linkage of the ArcHydro Data Model with SWAT

    E-Print Network [OSTI]

    Linkage of the ArcHydro Data Model with SWAT Francisco Olivera, Ph.D., P.E. Milver Valenzuela Texas on a hub basis. Independent of the already connected models HUB #12;Arc Hydro Arc Hydro can be used as the hub for connecting hydrologic models. #12;Arc Hydro #12;What it is and what it is not ... Arc Hydro

  17. Invervar Hydro | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunanInformation sourceInvensys Building SystemInvervar Hydro

  18. Vortex Hydro Energy Develops Transformational Technology to Harness...

    Energy Savers [EERE]

    Vortex Hydro Energy Develops Transformational Technology to Harness Energy from Water Currents Vortex Hydro Energy Develops Transformational Technology to Harness Energy from Water...

  19. Rich catalytic injection

    DOE Patents [OSTI]

    Veninger, Albert (Coventry, CT)

    2008-12-30T23:59:59.000Z

    A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

  20. PHNOMNES DITS HYDRO-LECTRIQUES ET HYDRO-MAGNTIQUES; THO-RMES FONDAMENTAUX ET LEUR CONSTATATION EXPRIMENTALE;

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    PH?NOM?NES DITS HYDRO-?LECTRIQUES ET HYDRO-MAGN?TIQUES; TH?O- R?MES FONDAMENTAUX ET LEUR nouveaux phénomènes. Je les désignerai ainsi comme une hydro-électicité, un hydro-magnétisme, etc. Mais'idée, d'aimants au lieu d'hydro-aimants, de masses électriques au lieu de masses hydro-électriques, et

  1. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1984-01-01T23:59:59.000Z

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  2. Energy Recovery System for Fluid Catalytic Cracking Units

    E-Print Network [OSTI]

    Wen, H.; Lou, S. C.

    1982-01-01T23:59:59.000Z

    hot gas expanders. Flue gas from the FCC regenerator passes through a special cyclone separator to remove most of the entrained catalyst fines. It then enters the expander train to generate power for the compressor which supplies air...

  3. Fluidic Catalytic Cracking Power Recovery Dynamic Computer Simulation

    E-Print Network [OSTI]

    Samurin, N. A.

    1980-01-01T23:59:59.000Z

    operation of the primary mechanical components, specifically the axial compressor and hot gas expander. The present work expands upon the steady state model to add the dynamic characteristics of these elements as well as the effects of the controlling...

  4. Energy Conservation Revamps in Fluid Catalytic Cracking Systems

    E-Print Network [OSTI]

    Wilson, J. W.; Sloan, H. D.

    1984-01-01T23:59:59.000Z

    The FCC process continues as one of the major refinery technologies despite changes in refinery operations. The main fractionator/vapor recovery systems associated with many FCC units have the potential for significant gains in energy efficiency...

  5. Energy Recovery System for Fluid Catalytic Cracking Units

    E-Print Network [OSTI]

    Wen, H.; Lou, S. C.

    1982-01-01T23:59:59.000Z

    hot gas expanders. Flue gas from the FCC regenerator passes through a special cyclone separator to remove most of the entrained catalyst fines. It then enters the expander train to generate power for the compressor which supplies air...

  6. Cracking blends of gas oil and residual oil

    SciTech Connect (OSTI)

    Myers, G.D.

    1988-03-01T23:59:59.000Z

    In a catalytic cracking process unit wherein a gas oil feed is cracked in a cracking zone at an elevated temperature in the presence of a cracking catalyst, the cracking catalyst is regenerated in a regeneration zone by burning coke of the catalyst, and catalyst is circulated between the cracking zone and the regeneration zone. The improvement is described for obtaining a naphtha product of improved octane number comprising introducing sufficient of a nickel and vanadium metals-containing heavy feedstock with the gas oil feed introduced into the cracking zone to deposit nickel and vanadium metals on the catalyst and raise the nickel and metals-content of the catalyst to a level ranging from about 1500 to about 6000 parts per million of the metals expressed as equivalent nickel, based on the weight of the catalyst, and maintaining the nickel and vanadium metals level on the catalyst by withdrawing high nickel and vanadium metals containing catalyst and adding low nickel and vanadium metals-containing catalyst to the regeneration zone.

  7. Selective dehydrogenation of propane over novel catalytic materials

    SciTech Connect (OSTI)

    Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

    1998-02-01T23:59:59.000Z

    The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

  8. HEITSCH, R OMISCH --HYDRO-STORAGE SUBPROBLEMS IN POWER GENERATION 1 Hydro-Storage Subproblems in Power Generation

    E-Print Network [OSTI]

    Rmisch, Werner

    HEITSCH, R OMISCH -- HYDRO-STORAGE SUBPROBLEMS IN POWER GENERATION 1 Hydro-Storage Subproblems that owns a hydro-thermal generation sys- tem and trades on the power market often lead to complex stochas- tic optimization problems. We present a new approach to solving stochastic hydro-storage subproblems

  9. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01T23:59:59.000Z

    Using Self-Sustained Hydro- Gasification." [0011] In aprocess, using a steam hydro-gasification reactor (SHR) thepyrolysis and hydro-gasification in a single step. This

  10. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01T23:59:59.000Z

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  11. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1982-06-22T23:59:59.000Z

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  12. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1984-04-17T23:59:59.000Z

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  13. Automated pavement crack detection

    E-Print Network [OSTI]

    Rao, Ashok Madhava

    1991-01-01T23:59:59.000Z

    : Electrical Engineering AUTOMATED PAVEMENT CRACK DETECTION A Thesis by ASHOK MADHAVA RAO Approved as to style and content by . c Norman C. Grisw d (Chair of Committ ) Nasser Kehtarnavaz (Member) g, J~, Karan Watson Robert L. Lytt (Member) Jo W.... Howze (Head of Department) December 1991 111 ABSTRACT Automated Pavement Crack Detection. (December 1991) Ashok Madhava, Rao, B. E. , Mysore University Chair of Advisory Committee: Norman. C. Griswold Due to load, environmental and structural...

  14. Catalytic nanoporous membranes

    DOE Patents [OSTI]

    Pellin, Michael J; Hryn, John N; Elam, Jeffrey W

    2013-08-27T23:59:59.000Z

    A nanoporous catalytic membrane which displays several unique features Including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity. Also provided is a method for producing a catalytic membrane having flow-through pores and discreet catalytic clusters adhering to the inside surfaces of the pores.

  15. Steam reformer with catalytic combustor

    DOE Patents [OSTI]

    Voecks, Gerald E. (La Crescenta, CA)

    1990-03-20T23:59:59.000Z

    A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

  16. Coupled hydro-mechanical processes in crytalline rock and in induratedand plastic clays: A comparative discussion

    E-Print Network [OSTI]

    Tsang, Chin-Fu; Blumling, Peter; Bernier, Frederic

    2008-01-01T23:59:59.000Z

    at Grimsel. In Coupled Thermo-Hydro- Mechanical-ChemicalCOUPLED HYDRO-MECHANICAL PROCESSES IN CRYTALLINE ROCK AND IN

  17. | JANUARY/FEBRUARY 2014 | Hydro INTERNATIONAL22 symbols and features used on a

    E-Print Network [OSTI]

    New Hampshire, University of

    | JANUARY/FEBRUARY 2014 | Hydro INTERNATIONAL22 symbols and features used on a nautical chart #12;Hydro INT

  18. NOAA Fisheries Protocols For Hydro-dynamic Dredge Surveys

    E-Print Network [OSTI]

    NOAA Fisheries Protocols For Hydro-dynamic Dredge Surveys: Surf Clams and Ocean Quahogs December 19..................................................................................................................................... 1 NOAA Fisheries Hydro-dynamic Clam Dredge Survey Protocols........................................................................... 5 Clam Dredge Construction and Repair

  19. Vortex Hydro Energy (TRL 5 6 System) - Advanced Integration of...

    Broader source: Energy.gov (indexed) [DOE]

    Vortex Hydro Energy (TRL 5 6 System) - Advanced Integration of Power Take-Off in VIVACE Vortex Hydro Energy (TRL 5 6 System) - Advanced Integration of Power Take-Off in VIVACE...

  20. Transcending the Hydro-Illogical Building a Texas Hydrologic

    E-Print Network [OSTI]

    Yang, Zong-Liang

    Transcending the Hydro-Illogical Cycle Building a Texas Hydrologic Information System TX-HIS #12;Q to couple streamflow models to GCMs · We need to break the hydro-illogical cycle and plan for the delivery

  1. Lac Courte Oreilles Hydro Dam Assessment

    SciTech Connect (OSTI)

    Weaver, Jason [Lac Courte Oreilles; Meyers, Amy [Kiser Hydro

    2014-12-31T23:59:59.000Z

    The main objective of this project was to investigate upgrading the existing hydro power generating system at the Winter Dam. The tribe would like to produce more energy and receive a fair market power purchase agreement so the dam is no longer a drain on our budget but a contributor to our economy. We contracted Kiser Hydro, LLC Engineering for this project and received an engineering report that includes options for producing more energy with cost effective upgrades to the existing turbines. Included in this project was a negotiation of energy price sales negotiations.

  2. A Photosynthetic Hydrogel for Catalytic Hydrogen Production ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production...

  3. NOAA Technical Memorandum NWS HYDRO 45 RELATIONSHIP BETWEEN

    E-Print Network [OSTI]

    NOAA Technical Memorandum NWS HYDRO 45 RELATIONSHIP BETWEEN STORM AND ANTECEDENT PRECIPITATION OVER TECHNICAL MEMORANDUMS National Weather Service. Office of Hydrology Series The Office of Hydrology (HYDRO and development. NOAA Technical Memorandums in the NWS HYDRO series facilitate prompt distribution of scientific

  4. Atomic scale mixing for inertial confinement fusion associated hydro instabilities

    E-Print Network [OSTI]

    New York at Stoney Brook, State University of

    Atomic scale mixing for inertial confinement fusion associated hydro instabilities J. Melvina, , P Alamos, NM 87545, USA Abstract Hydro instabilities have been identified as a potential cause- able. We find numerical convergence for this important quantity, in a purely hydro study, with only

  5. NOAA Technical Memorandum NWS HYDRO 46 A CLIMATIC ANALYSIS

    E-Print Network [OSTI]

    NOAA Technical Memorandum NWS HYDRO 46 A CLIMATIC ANALYSIS OF OROGRAPHIC PRECIPITATION OVER THE BIGHydrology (HYDRO) ofthe National Weather Service (NWS) develops procedures for making river and water supply, and conducts pertinent research and development NOAA Teclmical Memorandums in the NWS HYDRO series facilitate

  6. Fraser River Hydro and Fisheries Research Project fonds

    E-Print Network [OSTI]

    Handy, Todd C.

    Fraser River Hydro and Fisheries Research Project fonds Revised by Erwin Wodarczak (1998 Fraser River Hydro and Fisheries Research Project fonds. ­ 19561961. 13 cm of textual records. Administrative History The Fraser River Hydro and Fisheries Research Project was established in 1956, financed

  7. Forestry Commission Wales Guidance on rental levels for Hydro Power

    E-Print Network [OSTI]

    Forestry Commission Wales Guidance on rental levels for Hydro Power Guidance on rental levels for hydro power projects Tel: 02920 475961 Email: hydrowales@forestry.gsi.gov.uk Version 1.0 Mike Pitcher 17th December, 2012 #12;2 Guidance on rental levels for hydro power |Version 1.0 | Mike Pitcher 17

  8. Interconnected hydro-thermal systems Models, methods, and applications

    E-Print Network [OSTI]

    Interconnected hydro-thermal systems Models, methods, and applications Magnus Hindsberger Kgs. Lyngby 2003 IMM-PHD-2003-112 Interconnected hydro-thermalsystems #12;Technical University of Denmark 45882673 reception@imm.dtu.dk www.imm.dtu.dk IMM-PHD-2003-112 ISSN 0909-3192 #12;Interconnected hydro

  9. Stochastic Co-optimization for Hydro-Electric Power Generation

    E-Print Network [OSTI]

    1 Stochastic Co-optimization for Hydro-Electric Power Generation Shi-Jie Deng, Senior Member, IEEE the optimal scheduling problem faced by a hydro-electric power producer that simultaneously participates in multiple markets. Specifically, the hydro-generator participates in both the electricity spot market

  10. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, D.; Sunder, S.

    1986-12-02T23:59:59.000Z

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  11. Ontario Hydro`s transportation of radioactive material and emergency response plan

    SciTech Connect (OSTI)

    Karmali, N. [Ontario Hydro, Toronto, Ontario (Canada). Nuclear Operations Branch

    1993-12-31T23:59:59.000Z

    Ontario Hydro has been transporting radioactive material for almost 30 years without any exposure to the public or release to the environment. However, there have been three accidents involving Hydro`s shipments of radioactive material. In addition to the quality packaging and shipping program, Ontario Hydro has an Emergency Response Plan and capability to deal with an accident involving a shipment of radioactive material. The Corporation`s ability to respond, to effectively control and contain the situation, site remediation, and to provide emergency public information in the event of a road accident minimizes the risk to the public and the environment. This emphasizes their commitment to worker safety, public safety and impact to the environment. Response capability is mandated under various legislation and regulations in Canada.

  12. 3-D hydro + cascade model at RHIC

    E-Print Network [OSTI]

    Chiho Nonaka; Steffen A. Bass

    2005-11-07T23:59:59.000Z

    We present a 3-D hydro + cascade model in which viscosity and a realistic freezeout process for the hadronic phase are taken into account. We compare our results to experimental data and discuss the finite state interaction effects on physical observables.

  13. LANL hydro test update(u)

    SciTech Connect (OSTI)

    Aragon, Ezekiel D [Los Alamos National Laboratory

    2011-01-06T23:59:59.000Z

    Briefings presenting W78 programmatic activities for FY11 and the status and plan for associated Hydro 3617, is included wherewith in support of the NNSA W78 Program Review Meeting scheduled for January 11 thru 13, 2011, at the Savannah River Plant, SC.

  14. Hydrocarbon cracking catalyst

    SciTech Connect (OSTI)

    Lochow, C.F.; Kovacs, D.B.

    1988-12-27T23:59:59.000Z

    This patent describes a catalyst composition for cracking hydrocarbons to maximize gasoline comprising: rare earth exchanged ''Y'' crystalline faujasite dispersed in a clay containing matrix material; and which has been subsequently further ion exchanged to contain 0.20 to 3.0 wt% yttrium, calculated as the oxide, whereby the yttrium is chemically combined in the catalyst composition.

  15. Development of reduced crude cracking catalysts

    SciTech Connect (OSTI)

    Hettinger, W.P. Jr. (Ashland Petroleum Company, KY (USA))

    1987-08-01T23:59:59.000Z

    In 1974 OPEC imposed an embargo on oil to the United States and caused a rapid rise in the price of a barrel of oil. At the time of the embargo, Ashland imported a considerable portion of its oil from the Middle East, thus raising the question of oil availability. As the problem increased in severity, Messrs. George Meyer, Oliver Zandona and Llyod Busch, began to explore alternative ways of squeezing more product from a given barrel of crude. After considering many alternatives, they arrived at the innovative thought that it might be possible to catalytically crack the 1050{degree}F plus fraction of the barrel directly to gasoline which would in effect, give them an additional volume of crude oil. Also, if vacuum fractionation were eliminated and if the entire 650{degree}F plus (reduced crude) portion of the barrel processed, this would further reduce operating costs. With these objectives and some new process innovations in mind, they began reduced crude cracking experimentation in a small 12,000 B/D FCC operating unit at Louisville. It was from these goals, concepts and a small operating unit, that the RCC process was born.

  16. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A. (Orlando, FL); Campbell, Christian X. (Orlando, FL); Subramanian, Ramesh (Oviedo, FL)

    2009-06-02T23:59:59.000Z

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  17. Concentric catalytic combustor

    DOE Patents [OSTI]

    Bruck, Gerald J. (Oviedo, FL); Laster, Walter R. (Oviedo, FL)

    2009-03-24T23:59:59.000Z

    A catalytic combustor (28) includes a tubular pressure boundary element (90) having a longitudinal flow axis (e.g., 56) separating a first portion (94) of a first fluid flow (e.g., 24) from a second portion (95) of the first fluid flow. The pressure boundary element includes a wall (96) having a plurality of separate longitudinally oriented flow paths (98) annularly disposed within the wall and conducting respective portions (100, 101) of a second fluid flow (e.g., 26) therethrough. A catalytic material (32) is disposed on a surface (e.g., 102, 103) of the pressure boundary element exposed to at least one of the first and second portions of the first fluid flow.

  18. Catalytic hydrodesulfurization of bitumen

    SciTech Connect (OSTI)

    Sharma, R.K.; Olson, E.S. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31T23:59:59.000Z

    Investigations of the catalytic hydrodesulfurization of Venezuela bitumen and its water emulsion (Orimulsion) were carried out. This material contained a large amount of sulfur and organometallics, such as vanadium and nickel compounds. A variety of nickel and molybdenum catalysts were prepared. These, as well as two commercial catalysts, were tested with Orimulsion and vacuum-dried, pentane-insoluble and soluble bitumen. Catalytic hydrotreatment removed up to 75% of sulfur from the bitumen. Hydrodesulfurization was found to be affected by reaction temperature, reaction time, catalyst, and feed material. Moisture-free bitumen and a pentane-soluble bitumen fraction were desulfurized more effectively than Orimulsion. Zeolite-based catalysts gave higher desulfurization than synthetic clay catalysts.

  19. Catalytic reforming catalyst

    SciTech Connect (OSTI)

    Buss, W.C.; Kluksdahl, H.E.

    1980-12-09T23:59:59.000Z

    An improved catalyst, having a reduced fouling rate when used in a catalytic reforming process, said catalyst comprising platinum disposed on an alumina support wherein the alumina support is obtained by removing water from aluminum hydroxide produced as a by-product from a ziegler higher alcohol synthesis reaction, and wherein the alumina is calcined at a temperature of 1100-1400/sup 0/F so as to have a surface area of 165 to 215 square meters per gram.

  20. Catalytic reforming methods

    DOE Patents [OSTI]

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14T23:59:59.000Z

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  1. Catalytic hydrodesulfurization of bitumen

    SciTech Connect (OSTI)

    Sharma, R.K.; Olson, E.S. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31T23:59:59.000Z

    Investigations of the catalytic hydrodesulfurization of Venezuela bitumen and its water-emulsion (Orimulsion) were carried out. A variety of catalysts were prepared and some impregnated with molybdenum and sulfided. These and two commercial catalysts were tested with Orimulsion, vacuum-dried Orimulsion, and pentane-insoluble and soluble Orimulsion. Hydrotreatment of feed material was done in a 15-mL tube reactor using a variety of catalysts at 390{degrees}C under an initial 1000-psi hydrogen pressure with a reaction time of 1-3 hours. The hydrotreated products were analyzed by total sulfur analysis. Catalytic hydrotreatment removed up to 75% of sulfur from the bitumen. Nickel and/or molybdenum impregnation on various supports promoted sulfur removal from Orimulsion. Hydrodesulfurization was found to be affected by reaction temperature, reaction time, catalyst, and feed material. A moisture-free bitumen and a pentane-soluble bitumen fraction were desulfurized more effectively than Orimulsion. Zeolite-based catalysts gave higher desulfurization than synthetic clay catalysts or commercial AMOCAT and HDN catalysts.

  2. Novel Catalytic Membrane Reactors

    SciTech Connect (OSTI)

    Stuart Nemser, PhD

    2010-10-01T23:59:59.000Z

    There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

  3. Hydro-Qubec Net Metering (Quebec, Canada) | Open Energy Information

    Open Energy Info (EERE)

    Canada) Policy Type Net Metering Affected Technologies Geothermal Electric, Solar Photovoltaics Active Policy Yes Implementing Sector Utility Funding Source Hydro-Quebec Primary...

  4. Robust optimization based self scheduling of hydro-thermal Genco ...

    E-Print Network [OSTI]

    Alireza Soroudi

    2013-12-29T23:59:59.000Z

    Dec 29, 2013 ... Abstract: This paper proposes a robust optimization model for optimal self scheduling of a hydro-thermal generating company. The proposed...

  5. Rye Patch geothermal development, hydro-chemistry of thermal...

    Open Energy Info (EERE)

    development, hydro-chemistry of thermal water applied to resource definition Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Rye Patch geothermal...

  6. Optimizing Trading Decisions for Hydro Storage Systems using ...

    E-Print Network [OSTI]

    2012-09-19T23:59:59.000Z

    solar, or run-of-river. The European ... and generating companies are currently investing about 26 billion Euros into new pumped-hydro storage plants with a...

  7. Optimierung eines hydro-thermischen Kraftwerks-systems unter Ungewi heit

    E-Print Network [OSTI]

    Römisch, Werner

    Optimierung eines hydro-thermischen Kraftwerks- systems unter Ungewi heit Dr. rer. nat. N. Growe Arbeit beschreiben wir ein stochastisches Modell fur den ko- stenoptimalen Einsatz eines hydro ein, entwickeln ein Losungsverfahren und validieren dies am Beispiel des hydro

  8. Thermo-hydro-chemical Predictive analysis for the drift-scale predictive heater test,

    E-Print Network [OSTI]

    Sonnenthal, Eric L.; Spycher, Nicolas; Apps, John; Simmons, Ardyth

    1998-01-01T23:59:59.000Z

    Characterization Project Thermo-Hydro-Chemical Predictive90-1116 Berkeley, C A 94720 Thermo-Hydro-Chemical PredictiveVersion 1.0 Thermo-Hydro-Chemical Predictive Analysis for

  9. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01T23:59:59.000Z

    OPERATION OF A S T E A M HYDRO-GASIFIER IN A FLUIDIZED BEDMaterial Using Self-Sustained Hydro- Gasification." [0011]the process, using a steam hydro-gasification reactor (SHR)

  10. Crack Path Selection Fatigue crack path imaged via SEM

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Crack path selects secondary phases and interface Conclusions Nb-Si Alloys tested exhibited toughness phases fail in a brittle manner Fatigue Crack Growth ABSTRACT Advanced aerospace materials continue at high temperatures. An important property of any high temperature aerospace engineering material is its

  11. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants...

  12. Methods and apparatus for catalytic hydrothermal gasification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods and apparatus for catalytic hydrothermal gasification of biomass Re-direct Destination: Continuous processing of wet biomass feedstock by catalytic hydrothermal...

  13. Synthesis, Characterization, and Catalytic Function of Novel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization, and Catalytic Function of Novel Highly Dispersed Tungsten Oxide Catalysts on Mesoporous Silica . Synthesis, Characterization, and Catalytic Function of Novel...

  14. Preparation, Characterization, and Catalytic Properties of Tungsten...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preparation, Characterization, and Catalytic Properties of Tungsten Trioxide Cyclic Trimers on FeO(111)Pt(111). Preparation, Characterization, and Catalytic Properties of Tungsten...

  15. Stress corrosion crack growth in porous sandstones.

    E-Print Network [OSTI]

    Ojala, Ira O

    Stress corrosion crack growth occurs when the chemical weakening of strained crack tip bonds facilitates crack propagation. I have examined the effect of chemical processes on the growth of a creack population by carrying out triaxial compression...

  16. Florida Hydro Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489 NoEuropeStrat.pdfInactive JumpFirstFlorence High SchoolHydro Inc

  17. First Hydro Company | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A PotentialJumpGermanFife Energy Park at MethilGlobalFirstFirst Hydro Company

  18. HydroChina Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDIT REPORTEnergyFarms AHefei SungrowHelukabelHonitonHydroChina

  19. Vortex Hydro Energy LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTri Global EnergyUtility RateVirginia/WindCounty, California |Vortex Hydro

  20. Property:HydroInfo | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag Jump to: navigation,ProjectStartDate Jump to:Property Edit withpurposeHydroInfo

  1. Hydro Green Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEIHesperia, California:Project JumpHyEnergy SystemsHydro Green Energy

  2. Dharmshala Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A Potential Microhydro SiteDaytonDestilaria dethe MekongDharmshala Hydro

  3. Cauvery Hydro Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation inOpenadd: China Datang Corporation Trina SolarCathayCauvery Hydro

  4. Ambient Hydro Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat Place:Alvan Blanch Green FuelsEnergyAmandus KahlAmbient Hydro

  5. Turnbull Hydro LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlin Baxin HydropowerTrinityTurnbull Hydro LLC Jump to: navigation, search

  6. Himalayan Hydro P Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | Open EnergyInformation Hess RetailHillsdale BoardHimalayan Hydro P

  7. Bhilangana Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation in Carbonof Alternative Sources ofBeyondPV Co LtdBhilangana Hydro

  8. MODELING OF HYDRO-PNEUMATIC ENERGY STORAGE USING PUMP TURBINES

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    MODELING OF HYDRO-PNEUMATIC ENERGY STORAGE USING PUMP TURBINES E. Ortego, A. Dazin, G. Caignaert, F. Colas, O. Coutier-Delgosha Abstract: Modelling of a hydro-pneumatic energy storage system is the main demand response strategy. 1 Introduction Energy storage is one of the most exciting solutions considered

  9. antas river hydro: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    antas river hydro First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Dworshak & Brownlee Hydro Operations...

  10. Hydro-Thermal Scheduling (HTS) 1.0 Introduction

    E-Print Network [OSTI]

    McCalley, James D.

    1 Hydro-Thermal Scheduling (HTS) 1.0 Introduction From an overall systems view, the single most, relative to that of thermal plants, are very small. There are three basic types of hydroelectric plants;2 Pump-storage This kind of hydro plant is a specialized reservoir-type plant which has capability to act

  11. POWER SCHEDULING IN A HYDRO-THERMAL SYSTEM UNDER UNCERTAINTY

    E-Print Network [OSTI]

    Rmisch, Werner

    POWER SCHEDULING IN A HYDRO-THERMAL SYSTEM UNDER UNCERTAINTY C.C. Car e1, M.P. Nowak2, W. Romisch2 Forschungsgemeinschaft. leads to a tremendous increase in the complex- ity of the traditional power optimization mod- els-burning) thermal units, pumped-storage hydro plants and delivery con- tracts and describe an optimization model

  12. Optimal sequencing site of hydro-power stations

    SciTech Connect (OSTI)

    Hayashi, T.; Yoshino, F.; Waka, R. [Tottori Univ., Koyama (Japan). Dept. of Mechanical Engineering

    1995-06-01T23:59:59.000Z

    At the first stage of a hydro-power survey of a river, it is important to select the optimal hydro-power site. The most important condition to be satisfied is to determine the optimal site where the greatest and most economical amount of hydro-energy can be obtained. This paper proposes a new method in which the optimal arrangement of the hydro-power stations is determined by a computational operation using discrete data at points along the river such as the drainage area, altitude, and distance along the river channel as obtained from topographical maps instead of drawing on engineers` experiences and the intuitions of experts. The results by this method are then compared with data on existing hydro-power stations and the results planned by expert engineers to show that this new computational method is superior.

  13. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  14. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  15. Canonical Correlation Analysis (CCA) of GRACE, hydrological and hydro-meteorological signals

    E-Print Network [OSTI]

    Stuttgart, Universität

    1 Canonical Correlation Analysis (CCA) of GRACE, hydrological and hydro-meteorological signals M. J and Hydro-meteorology Hydrology GRACE Hydro-meteorology RQ dt dS dt dMdS RETP . dt AH a #12;3 GRACE, times based signals #12;12 CCA on catchments based ­ GRACE and hydro-meteorology T GDGDGD T VUQ dt d

  16. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01T23:59:59.000Z

    applications including coal gasification, fer- tilizers fromin hydro-gasification reactions, such as coal and biomass,

  17. Peridynamic model for fatigue cracking.

    SciTech Connect (OSTI)

    Silling, Stewart A.; Abe Askari (Boeing)

    2014-10-01T23:59:59.000Z

    The peridynamic theory is an extension of traditional solid mechanics in which the field equations can be applied on discontinuities, such as growing cracks. This paper proposes a bond damage model within peridynamics to treat the nucleation and growth of cracks due to cyclic loading. Bond damage occurs according to the evolution of a variable called the %22remaining life%22 of each bond that changes over time according to the cyclic strain in the bond. It is shown that the model reproduces the main features of S-N data for typical materials and also reproduces the Paris law for fatigue crack growth. Extensions of the model account for the effects of loading spectrum, fatigue limit, and variable load ratio. A three-dimensional example illustrates the nucleation and growth of a helical fatigue crack in the torsion of an aluminum alloy rod.

  18. Progressive flow cracking of coal/oil mixtures with high metals content catalyst

    SciTech Connect (OSTI)

    Zandona, O.J.

    1989-10-10T23:59:59.000Z

    This patent describes a process for economically producing liquid fuel products at least partly from coal. It comprises: introducing a progressive flow catalytic cracking zone a charge stock comprising a pumpable mixture of solid, particulate coal and carbo-metallic oil and forming within the zone a stream having a linear velocity of at least about 25 feet per second. The stream comprising the charge stock and a hydrocarbon zeolite cracking catalyst promoting dehydrogenation of the charge stock; forming mobile hydrogen within the zone by the dehydrogenation; introducing the mobile hydrogen into the stream by dehydrogenation of the charge stock in the absence of added molecular hydrogen, thereby producing liquid products from the charge stock while laying down coke on the hydrocarbon cracking catalyst in the range of about 0.3% to about 3% and thereby producing spent catalyst; separating from the spent catalyst the liquid products.

  19. Final Report - Wind and Hydro Energy Feasibility Study - June 2011

    SciTech Connect (OSTI)

    Jim Zoellick; Richard Engel; Rubin Garcia; Colin Sheppard

    2011-06-17T23:59:59.000Z

    This feasibility examined two of the Yurok Tribe's most promising renewable energy resources, wind and hydro, to provide the Tribe detailed, site specific information that will result in a comprehensive business plan sufficient to implement a favorable renewable energy project.

  20. EIS-0166: Bangor Hydro-Electric Transmission Line, Maine

    Broader source: Energy.gov [DOE]

    The Department of Energy prepared this environmental impact statement while considering whether to authorize a Presidential permit for Bangor Hydro to construct a new electric transmission facility at the U.S. border with Canada.

  1. Parallel interacting edge cracks under pure bending

    E-Print Network [OSTI]

    Moran, Ivan

    1991-01-01T23:59:59.000Z

    specimens. . . 66 Table 6. 4 a SIFs for interactive cracks. Position 14. . 73 Table 6. 4 b SIFs for interactive cracks. Position 24 . . 79 Table 6. 4 c SIFs for interactive cracks. Position 13. . 83 Table 6. 5 a K~ff for position 14 Table 6. 5 b K... Table 5. 3 Models Dimensions SPECIMEN MODEL 1 MODEL 2 Length L (inches) Dimension m (in) 6. 50 6. 50 1. 25 1. 25 Spec. Width H (in) 1. 100 1. 276 Thickness t (in) 0. 238 0. 238 Crack Angle p (o) 90 54 Crack Width c (in) Crack Length a (in) 0...

  2. Hydro-Balanced Stuffing Box field test

    SciTech Connect (OSTI)

    Giangiacomo, L.A.

    1999-05-28T23:59:59.000Z

    The Hydro-Balanced Stuffing Box is a seal assembly for polished rod pumping installations commonly used in oil and gas pumping well installations to contain produced well fluids. The improved stuffing box was developed and patented by Harold H. Palmour of The Palmour Group of Livingston, TX. The stuffing box is designed to reduce the incidence of seal leakage and to utilize an environmentally safe fluid, so that if there is any leakage, environmental damage is reduced or eliminated. The unit was tested on two wells at the Rocky Mountain Oilfield Testing Center. During the test period, the performance of the stuffing box was measured by monitoring the pressure on the tubing and the inner chamber with a Barton Two-pen recorder. The amount of safe fluid consumed, fluid leakage at the top of the stuffing box, pressure supplied from the nitrogen bottle, ambient temperature, and polish rod temperature was recorded. The stuffing box is capable of providing a better seal between well fluids an d the environment than conventional stuffing boxes. It allows the polished rod to operate cooler and with lubrication, extending the life of the packing elements, and reducing the amount of attention required to prevent leakage.

  3. INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING

    E-Print Network [OSTI]

    INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

  4. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  5. Nonlinear structural crack growth monitoring

    DOE Patents [OSTI]

    Welch, Donald E. (Oak Ridge, TN); Hively, Lee M. (Philadelphia, TN); Holdaway, Ray F. (Clinton, TN)

    2002-01-01T23:59:59.000Z

    A method and apparatus are provided for the detection, through nonlinear manipulation of data, of an indicator of imminent failure due to crack growth in structural elements. The method is a process of determining energy consumption due to crack growth and correlating the energy consumption with physical phenomena indicative of a failure event. The apparatus includes sensors for sensing physical data factors, processors or the like for computing a relationship between the physical data factors and phenomena indicative of the failure event, and apparatus for providing notification of the characteristics and extent of such phenomena.

  6. Ashland Oil Inc. has new heavy oil cracking technology

    SciTech Connect (OSTI)

    Not Available

    1980-04-21T23:59:59.000Z

    Ashland's new ''Reduced Crude Conversion'' is a fluid catalytic cracking process that permits more efficient use of the bottoms of the crude barrel, including the production of a given amount of gasoline from 20% less crude. Gasoline yields go from 49.8% for Arabian light crudes to 56.9% for Murban crudes. The new process, details of which have not been revealed, operates at ''high'' temperatures and about 1 atm; requires no feed hydrogen (and therefore, according to Ashland, compares favorably with hydrocracking); is not inhibited by catalyst poisons such as nickel and vanadium, even though these metals might adhere to the proprietary catalyst; and probably uses a zeolite catalyst. Ashland is planning a $70 million, 40,000 bbl/day unit which is scheduled to go on stream in 1982 at its Catlettsburg, Ky., refinery.

  7. Assess the key physics that underpins high-hydro coupling-efficiency in NDCX-II experiments and high-gain heavy ion direct drive target designs using proven hydro codes like HYDRA

    E-Print Network [OSTI]

    Barnard, J. J.

    2010-01-01T23:59:59.000Z

    physics that underpins high-hydro coupling-efficiency in N Dtarget designs using proven hydro codes like H Y D R A . byF E targets, we have studied hydro and implosion efficiency

  8. Evolving Einstein's Field Equations with Matter: The ``Hydro without Hydro'' Test

    E-Print Network [OSTI]

    Thomas W. Baumgarte; Scott A. Hughes; Stuart L. Shapiro

    1999-02-09T23:59:59.000Z

    We include matter sources in Einstein's field equations and show that our recently proposed 3+1 evolution scheme can stably evolve strong-field solutions. We insert in our code known matter solutions, namely the Oppenheimer-Volkoff solution for a static star and the Oppenheimer-Snyder solution for homogeneous dust sphere collapse to a black hole, and evolve the gravitational field equations. We find that we can evolve stably static, strong-field stars for arbitrarily long times and can follow dust sphere collapse accurately well past black hole formation. These tests are useful diagnostics for fully self-consistent, stable hydrodynamical simulations in 3+1 general relativity. Moreover, they suggest a successive approximation scheme for determining gravitational waveforms from strong-field sources dominated by longitudinal fields, like binary neutron stars: approximate quasi-equilibrium models can serve as sources for the transverse field equations, which can be evolved without having to re-solve the hydrodynamical equations (``hydro without hydro'').

  9. CrackTree: Automatic crack detection from pavement images Qin Zou a,b,c,

    E-Print Network [OSTI]

    Wang, Song

    CrackTree: Automatic crack detection from pavement images Qin Zou a,b,c, , Yu Cao c , Qingquan Li b t Pavement cracks are important information for evaluating the road condition and conducting the neces- sary pavement images. In practice, crack detection is a very challenging problem because of (1) low con- trast

  10. Original article Stem cracks in Norway spruce

    E-Print Network [OSTI]

    Boyer, Edmond

    Original article Stem cracks in Norway spruce in southern Scandinavia: causes and consequences Garpenberg, Sweden (Received 1st September 1992; accepted 17 June 1993) Summary Stem cracks in Norway;INTRODUCTION Background During this century, the widespread crack- ing of Norway spruce (Picea abies L Karst

  11. Cracking Resistance of Asphalt Rubber Mix Versus

    E-Print Network [OSTI]

    Mobasher, Barzin

    . crack length curve for KR #12;Load vs. CMOD 0.0 0.5 1.0 1.5 2.0 Crack mouth opening, mm 0 500 1000 1500 non-linear fracture mechanics Compliance approach R-Curve approach #12;Conventional Fatigue Testing factor R-Curve approach Resistance to initiation & growth of cracks Evaluates fracture toughness

  12. Climatic regulation of the Black Sea hydro-meteorological and ecological properties at interannual-to-decadal time scales

    E-Print Network [OSTI]

    Dippner, Joachim W.

    Climatic regulation of the Black Sea hydro-meteorological and ecological properties at interannual Available online 3 March 2006 Abstract An examination of a wide spectrum of hydro

  13. Simulated watershed responses to land cover changes using the Regional Hydro-Ecological Simulation System

    E-Print Network [OSTI]

    Tarboton, David

    Simulated watershed responses to land cover changes using the Regional Hydro-Ecological Simulation Old Main Hill, Logan, UT, 84322-8200, USA Abstract: In this work, we used the Regional Hydro

  14. HESSD '98 17 Safety concerns at Ontario Hydro: The need for safety

    E-Print Network [OSTI]

    Lee, John D.

    HESSD '98 17 Safety concerns at Ontario Hydro: The need for safety management through incident of complex socio-technical systems Ontario Hydro -- one of the largest electrical utilities in North America

  15. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01T23:59:59.000Z

    of the process, using a steam hydro-gasification reactor (simultaneously in the presence of both hydrogen and steam toundergo steam pyrolysis and hydro-gasification in a single

  16. GE Hydro Asia Co Ltd formerly Kvaerner Power Equipment Co Ltd...

    Open Energy Info (EERE)

    GE Hydro Asia Co Ltd formerly Kvaerner Power Equipment Co Ltd Kvaerner Hangfa Jump to: navigation, search Name: GE Hydro Asia Co Ltd (formerly Kvaerner Power Equipment Co., Ltd...

  17. Maximizing Energy Savings Reliability in BC Hydro Industrial Demand-side Management Programs

    E-Print Network [OSTI]

    Victoria, University of

    Maximizing Energy Savings Reliability in BC Hydro Industrial Demand-side Management Programs Supervisory Committee Maximizing Energy Savings Reliability in BC Hydro Industrial Demand-side Management of Environmental Studies) Departmental Member For energy utilities faced with expanded jurisdictional energy

  18. Hydro-Ecologic Responses to Land Use in Small Urbanizing Watersheds Within the Chesapeake Bay

    E-Print Network [OSTI]

    Palmer, Margaret A.

    Hydro-Ecologic Responses to Land Use in Small Urbanizing Watersheds Within the Chesapeake Bay. The consequences for both the hydrology and 41 #12;42 HYDRO-ECOLOGIC RESPONSES TO LAND USE IN SMALL URBANIZING

  19. Application of life cycle assessment methodology at Ontario Hydro

    SciTech Connect (OSTI)

    Reuber, B.; Khan, A. [Ontario Hydro, Ontario (Canada)

    1996-12-31T23:59:59.000Z

    Ontario Hydro is an electrical utility located in Ontario, Canada. In 1995, Ontario Hydro adopted Sustainable Energy Development Policy and Principles that include the governing principle: {open_quotes}Ontario Hydro will integrate environmental and social factors into its planning, decision-making, and business practices.{close_quotes} Life cycle assessment was identified as a useful tool for evaluating environmental impacts of products and processes in support of decision-making. Ontario Hydro has developed a methodology for life cycle assessment (LCA) that is consistent with generally accepted practices, practical, and suitable for application in Ontario Hydro Business Units. The methodology is based on that developed by the Society of Environmental Toxicology and Chemistry (SETAC) but follows a pragmatic and somewhat simplified approach. In scoping an LCA, the breadth and depth of analysis are compatible with and sufficient to address the stated goal of the study. The depth of analysis is tied to (i) the dollar value of the commodity, process or activity being assessed, (ii) the degree of freedom available to the assessor to make meaningful choices among options, and (iii) the importance of the environmental or technological issues leading to the evaluation. A pilot study was completed to apply the methodology to an LCA of the light vehicle fleet (cars, vans and light pick-up trucks) at Ontario Hydro. The objective of the LCA was to compare the life cycle impacts of alternative vehicle fuel cycles: gasoline, diesel, natural gas, propane, and alcohol; with particular focus on life cycle emissions, efficiency and cost. The study concluded that for large vehicles (1/2 ton and 3/4 ton) that travel more than 35000 km/year, natural gas and propane fuelling offer both cost reduction and emissions reduction when compared to gasoline vehicles.

  20. Environmentally assisted cracking of LWR materials

    SciTech Connect (OSTI)

    Chopra, O.K.; Chung, H.M.; Kassner, T.F.; Shack, W.J.

    1995-12-01T23:59:59.000Z

    Research on environmentally assisted cracking (EAC) of light water reactor materials has focused on (a) fatigue initiation in pressure vessel and piping steels, (b) crack growth in cast duplex and austenitic stainless steels (SSs), (c) irradiation-assisted stress corrosion cracking (IASCC) of austenitic SSs, and (d) EAC in high- nickel alloys. The effect of strain rate during different portions of the loading cycle on fatigue life of carbon and low-alloy steels in 289{degree}C water was determined. Crack growth studies on wrought and cast SSs have been completed. The effect of dissolved-oxygen concentration in high-purity water on IASCC of irradiated Type 304 SS was investigated and trace elements in the steel that increase susceptibility to intergranular cracking were identified. Preliminary results were obtained on crack growth rates of high-nickel alloys in water that contains a wide range of dissolved oxygen and hydrogen concentrations at 289 and 320{degree}C. The program on Environmentally Assisted Cracking of Light Water Reactor Materials is currently focused on four tasks: fatigue initiation in pressure vessel and piping steels, fatigue and environmentally assisted crack growth in cast duplex and austenitic SS, irradiation-assisted stress corrosion cracking of austenitic SSs, and environmentally assisted crack growth in high-nickel alloys. Measurements of corrosion-fatigue crack growth rates (CGRs) of wrought and cast stainless steels has been essentially completed. Recent progress in these areas is outlined in the following sections.

  1. ROOT LOCUS TECHNIQUE 323 7.6.1 Hydro Power Plant Experiment

    E-Print Network [OSTI]

    Gajic, Zoran

    ROOT LOCUS TECHNIQUE 323 7.6.1 Hydro Power Plant Experiment The design of a static controller for a real hydro power plant is considered in Skatari?? c and Gaji?? c (1992). The hydro power plant is treated variables of this hydro power plant are represented by x T = [1` 1! 1u f 1/ d 1/ q 1/ f 1/D 1/Q ] where 1

  2. Volume reduction/solidification of liquid radioactive waste using bitumen at Ontario Hydro`s Bruce Nuclear Generating Station `A`

    SciTech Connect (OSTI)

    Day, J.E.; Baker, R.L.

    1995-05-01T23:59:59.000Z

    Ontario Hydro at the Bruce Nuclear Generating Station `A` has undertaken a program to render the station`s liquid radioactive waste suitable for discharge to Lake Huron by removing sufficient radiological and chemical contaminants to satisfy regulatory requirements for emissions. The system will remove radionuclide and chemical contaminants from five different plant waste streams. The contaminants will be immobilized and stored at on-site radioactive waste storage facilities and the purified streams will be discharged. The discharge targets established by Ontario Hydro are set well below the limits established by the Ontario Ministry of Environment (MOE) and are based on the Best Available Technology Economically Achievable Approach (B.A.T.E.A.). ADTECHS Corporation has been selected by Ontario Hydro to provide volume reduction/solidification technology for one of the five waste streams. The system will dry and immobilize the contaminants from a liquid waste stream in emulsified asphalt using thin film evaporation technology.

  3. A Study of the Hydro-Mechanical Behaviour of Compacted Crushed Argillite

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 A Study of the Hydro-Mechanical Behaviour of Compacted Crushed Argillite C.S. Tang a, b , A and the microstruc- ture on the hydro-mechanical behaviour of the compacted crushed argillite have been in a strong effect of the grain size distribution on the hydro-mechanical behaviour and thus the close link

  4. Dimensionnement et gestion d'un systme de stockage thermique par hydro-accumulation : application la

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Dimensionnement et gestion d'un système de stockage thermique par hydro-accumulation : application de stockage thermique de type hydro-accumulation destiné à une chaufferie collective multi, mix-énergétique, stockage thermique, hydro-accumulation, dimensionnement optimal, gestion, graphe d

  5. Mod`ele Elements Finis d'un Pli Vocal Artificiel avec Couplage Hydro-elastique

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Mod`ele El´ements Finis d'un Pli Vocal Artificiel avec Couplage Hydro-´elastique N. Hermanta , F formulation variationnelle du couplage hydro-élastique. Un premier calcul hyper-élastique simule le gonflement dans l'analyse modale des vibrations de petite amplitude du système hydro-élastique, permettant ainsi

  6. NOAA Technical Memorandum NWS HYDRO 39 PROBABLE MAXIMUM PRECIPITATION FOR THE UPPER

    E-Print Network [OSTI]

    NOAA Technical Memorandum NWS HYDRO 39 PROBABLE MAXIMUM PRECIPITATION FOR THE UPPER DEERFIELD RIVER The Office of Hydrology (HYDRO) of the National Weather Service (NWS) develops procedures for making river agencies, and conducts pertinent research and development. NOAA Technical Memorandums in the NWS HYDRO

  7. Title: Hydraulic modeling of a mixed water level control hydro-mechanical gate

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Title: Hydraulic modeling of a mixed water level control hydro-mechanical gate Ludovic Cassan1 Abstract: The article describes the hydraulic functioning of a mixed water level control hydro- mechanical of the model to reproduce the functioning of this complex hydro-mechanical system. CE database Subject headings

  8. Numerical Modeling of Hydro-acoustic Waves In Weakly Compressible Fluid Ali Abdolali1,2

    E-Print Network [OSTI]

    Kirby, James T.

    Numerical Modeling of Hydro-acoustic Waves In Weakly Compressible Fluid Ali Abdolali1,2 , James T of Civil Engineering, University of Roma Tre Low-frequency hydro-acoustic waves are precursors of tsunamis. Detection of hydro-acoustic waves generated due to the water column compression triggered by sudden seabed

  9. A lattice-based query system for assessing the quality of hydro-ecosystems

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A lattice-based query system for assessing the quality of hydro-ecosystems Agn`es Braud1 Cristina used for building a hierarchy of site pro- files which are annotated by hydro in the project. This paper presents an application of Galois lattices to the hydro-ecological domain, focussing

  10. To: NW Hydro Association From: Dick Wanderscheid, Angus Duncan and Todd Reeve

    E-Print Network [OSTI]

    Memo To: NW Hydro Association From: Dick Wanderscheid, Angus Duncan and Todd Reeve Re: The Bonneville Environmental Foundation's comments on the draft hydro potential study BEF staff completed to address the larger, conceptual picture of the hydro potential in the region. In particular, we attempted

  11. Evaluation of the Hydro-Thermodynamic Soil Vegetation Scheme and implementation of a new numerical scheme

    E-Print Network [OSTI]

    Moelders, Nicole

    ii Evaluation of the Hydro-Thermodynamic Soil Vegetation Scheme and implementation of a new.S. Fairbanks, Alaska August 2005 #12;iii Abstract The Hydro-Thermodynamic Soil-Vegetation Scheme (HTSVS........................................................................................................................... 24 Evaluation of snow depth and soil temperatures predicted by the Hydro- Thermodynamic Soil

  12. Arctic Region Evaluation of the Hydro-Thermodynamic Soil Vegetation Scheme (HTSVS)

    E-Print Network [OSTI]

    Moelders, Nicole

    Arctic Region Evaluation of the Hydro-Thermodynamic Soil Vegetation Scheme (HTSVS) Pamela Spier, University of Alaska, Fairbanks, AK Abstract This paper presents an evaluation of the Hydro. Introduction and Motivation The Hydro-Thermodynamic Soil Vegetation Scheme (HTSVS, Kramm et al. 1996, Mölders

  13. Towards Better Utilization of NEXRAD Data in Hydrology: an Overview of Hydro-NEXRAD

    E-Print Network [OSTI]

    Lawrence, Ramon

    Towards Better Utilization of NEXRAD Data in Hydrology: an Overview of Hydro-NEXRAD Witold F metadata extraction and management techniques are required. The authors describe and discuss the Hydro of the Hydro-NEXRAD project is to increase the use of NEXRAD data in hydrologic research. The project

  14. Hydro-thermal flow in a rough fracture EC Contract SES6-CT-2003-502706

    E-Print Network [OSTI]

    Schmittbuhl, Jean

    Hydro-thermal flow in a rough fracture EC Contract SES6-CT-2003-502706 PARTICIPANT ORGANIZATION NAME: CNRS Synthetic 2nd year report Related with Work Package............ HYDRO-THERMAL FLOW in the influence of a realistic geometry of the fracture on its hydro-thermal response. Several studies have

  15. Estimating runoff using hydro-geodetic approaches; assessment and comparison M. J. Tourian1

    E-Print Network [OSTI]

    Stuttgart, Universität

    Estimating runoff using hydro-geodetic approaches; assessment and comparison M. J. Tourian1 , C- drological balance equation, hydro-meteorological balance equation, least squares prediction using change from GRACE hydro-meteorological balance equation (Ratm) Ratm = - · Q - dM dt . · Q refers

  16. Climate Change in Scotland: Impact on Mini-Hydro G.P. Harrison

    E-Print Network [OSTI]

    Harrison, Gareth

    be generated from wind, wave, biomass or small- or mini-hydro plant. Production from these resources some 300 MW is small hydro potential capable of producing energy at less than 7p/kWh (Garrad Hassan, 2001). Although many of the better sites for small and mini-hydro have already been developed

  17. Cascading of fluid cracking catalysts

    SciTech Connect (OSTI)

    Kovach, S.M.; Miller, C.B.

    1986-05-27T23:59:59.000Z

    A process is described for conversion of hydrocarbon feedstocks by cascading a cracking catalyst containing zeolite in an acidic matrix from one hydrocarbon processing unit to another, wherein there are at least three different interconnected hydrocarbon processing units comprising a first unit having a regeneration zone and a riser zone, a second unit having having a regeneration zone and a riser zone, and a third unit having a riser zone and a regeneration zone, each unit having different processing conditions.

  18. Simulation of FCC riser flow with multiphase heat transfer and cracking reactions.

    SciTech Connect (OSTI)

    Chang, S. L.; Zhou, C. Q.; Energy Systems

    2003-08-01T23:59:59.000Z

    A validated Computational Fluid Dynamics (CFD) code ICRKFLO was developed for simulations of three-dimensional three-phase reacting flows in Fluid Catalytic Cracking (FCC) riser reactors. It calculates the product yields based on local flow properties by solving the fundamental conservation principles of mass, momentum, and energy for the flow properties associated with the gas, liquid, and solid phases. Unique phenomenological models and numerical techniques were developed specifically for the FCC flow simulation. The models include a spray vaporization model, a particle-solid interaction model, and an interfacial heat transfer model. The numerical techniques include a time-integral approach to overcome numerical stiffness problems in chemical kinetics rate calculations and a hybrid hydrodynamic-kinetic treatment to facilitate detailed kinetics calculations of cracking reactions. ICRKFLO has been validated with extensive test data from two pilot and one commercial FCC units. It is proven to be useful for advanced development of FCC riser reactors.

  19. Hydro, Solar, Wind The Future of Renewable Energy

    E-Print Network [OSTI]

    Lavaei, Javad

    Hydro, Solar, Wind The Future of Renewable Energy Joseph Flocco David Lath Department of Electrical. Hydropower Water has grown in previous years to become the most widely used form of renewable energy across years to come from Hydropower. It is considered to be a renewable energy source because it uses

  20. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    as Reductants Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx...

  1. Plasma-assisted catalytic reduction system

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1998-01-27T23:59:59.000Z

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  2. Superconducting Cuprates on Catalytic Substrates - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Electricity Transmission Find More Like This Return to Search Superconducting Cuprates on Catalytic Substrates Brookhaven National Laboratory Contact BNL About...

  3. Catalytic membranes for fuel cells

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL); Wang, Xiaoping (Naperville, IL)

    2011-04-19T23:59:59.000Z

    A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

  4. Catalytic Nanostructures | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C lKieling ,CatalysisPortalCatalytic

  5. Characterization of cracking restraint at sawcut joints using the German Cracking Frame

    E-Print Network [OSTI]

    Vepakomma, Shilpa

    2002-01-01T23:59:59.000Z

    Cracking of concrete slabs at sawcut notches is a major concern in the early stages of construction. Several factors affecting crack initiation are material strength parameters, method and quality of curing, slab/subbase stiffness, and concrete...

  6. Characterization of geothermal reservoir crack patterns using...

    Open Energy Info (EERE)

    reservoir crack patterns using shear-wave splitting Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Characterization of geothermal reservoir...

  7. Slow crack growth in polycarbonate films

    E-Print Network [OSTI]

    Cortet, Pierre-Philippe; Vanel, Loic; Ciliberto, Sergio

    2005-01-01T23:59:59.000Z

    We study experimentally the slow growth of a single crack in polycarbonate films submitted to uniaxial and constant imposed stress. The specificity of fracture in polycarbonate films is the appearance of flame shaped macroscopic process zones at the tips of the crack. Supported by an experimental study of the mechanical properties of polycarbonate films, an analysis of the stress dependence of the mean ratio between the process zone and crack lengths, during the crack growth, show a quantitative agreement with the Dugdale-Barenblatt model of the plastic process zone. We find that the fracture growth curves obey strong scaling properties that lead to a well defined growth master curve.

  8. White Etching Cracks | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Etching Cracks Presented by Walter Holweger of Schaeffler at the Wind Turbine Tribology Seminar 2014. NREL Chicago291014Holweger26nosec...

  9. Reaction kinetics of olefin saturation in the hydrodesulfurization of fluid catalytic cracked naphtha

    E-Print Network [OSTI]

    Schumann, Brian Herbert

    1995-01-01T23:59:59.000Z

    . . . 30 . . . 3 I . . . 3 I 13. Run 222-92-70--Comparison ofkw/rto Carbon Number forNormalOlefin . . . . 32 14. Run 222-92-70 ? -Comparison of k w/r to Carbon Number for Iso Olefins . . . . . . . . . . . 32 15. Run 222-92-70 ? -Comparison of k w.../r to Carbon Number for Cycfic Olefins . . . . . . 33 16. Run 963-94-24 ? -Comparison of k w/r to Carbon Number for Normal Olefins . . . . 33 17. Run 963-94-24 ? -Comparison of k w/r to Carbon Number for Iso Olefins . . . . . . . . . . . 34 18. Run 963...

  10. 7. Low temperature cracking in HMA Pavement Cracking Al-Qadi, Scarpas & Loizos (eds)

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    7. Low temperature cracking in HMA 367 #12;#12;Pavement Cracking Al-Qadi, Scarpas & Loizos (eds, Storrs, Connecticut, USA ABSTRACT: Low temperature cracking remains one of the major pavement distresses in asphalt concrete pavements in cold regions. An integrated laboratory testing, field performance data

  11. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons...

  12. Measurement of diesel solid nanoparticle emissions using a catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol Measurement of diesel solid nanoparticle emissions using a catalytic...

  13. Atomic-Structural Synergy for Catalytic CO Oxidation over Palladium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic-Structural Synergy for Catalytic CO Oxidation over Palladium-Nickel Nanoalloys. Atomic-Structural Synergy for Catalytic CO Oxidation over Palladium-Nickel Nanoalloys....

  14. High Catalytic Rates for Hydrogen Production Using Nickel Electrocatal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Catalytic Rates for Hydrogen Production Using Nickel Electrocatalysts with Seven-Membered Diphosphine Ligands Containing High Catalytic Rates for Hydrogen Production Using...

  15. Nanoporous carbon catalytic membranes and method for making the same

    DOE Patents [OSTI]

    Foley, Henry C. (Hockessin, DE); Strano, Michael (Wilmington, DE); Acharya, Madhav (New Castle, DE); Raich, Brenda A. (Houston, TX)

    2002-01-01T23:59:59.000Z

    Catalytic membranes comprising highly-dispersed, catalytically-active metals in nanoporous carbon membranes and a novel single-phase process to produce the membranes.

  16. Catalytic converter with thermoelectric generator

    SciTech Connect (OSTI)

    Parise, R.J.

    1998-07-01T23:59:59.000Z

    The unique design of an electrically heated catalyst (EHC) and the inclusion of an ECO valve in the exhaust of an internal combustion engine will meet the strict new emission requirements, especially at vehicle cold start, adopted by several states in this country as well as in Europe and Japan. The catalytic converter (CC) has been a most useful tool in pollution abatement for the automobile. But the emission requirements are becoming more stringent and, along with other improvements, the CC must be improved to meet these new standards. Coupled with the ECO valve, the EHC can meet these new emission limits. In an internal combustion engine vehicle (ICEV), approximately 80% of the energy consumed leaves the vehicle as waste heat: out the tail pipe, through the radiator, or convected/radiated off the engine. Included with the waste heat out the tail pipe are the products of combustion which must meet strict emission requirements. The design of a new CC is presented here. This is an automobile CC that has the capability of producing electrical power and reducing the quantity of emissions at vehicle cold start, the Thermoelectric Catalytic Power Generator. The CC utilizes the energy of the exothermic reactions that take place in the catalysis substrate to produce electrical energy with a thermoelectric generator. On vehicle cold start, the thermoelectric generator is used as a heat pump to heat the catalyst substrate to reduce the time to catalyst light-off. Thus an electrically heated catalyst (EHC) will be used to augment the abatement of tail pipe emissions. Included with the EHC in the exhaust stream of the automobile is the ECO valve. This valve restricts the flow of pollutants out the tail pipe of the vehicle for a specified amount of time until the EHC comes up to operating temperature. Then the ECO valve opens and allows the full exhaust, now treated by the EHC, to leave the vehicle.

  17. Crack shape developments and leak rates for circumferential complex-cracked pipes

    SciTech Connect (OSTI)

    Brickstad, B.; Bergman, M. [SAQ Inspection Ltd., Stockholm (Sweden)

    1997-04-01T23:59:59.000Z

    A computerized procedure has been developed that predicts the growth of an initial circumferential surface crack through a pipe and further on to failure. The crack growth mechanism can either be fatigue or stress corrosion. Consideration is taken to complex crack shapes and for the through-wall cracks, crack opening areas and leak rates are also calculated. The procedure is based on a large number of three-dimensional finite element calculations of cracked pipes. The results from these calculations are stored in a database from which the PC-program, denoted LBBPIPE, reads all necessary information. In this paper, a sensitivity analysis is presented for cracked pipes subjected to both stress corrosion and vibration fatigue.

  18. Development of crack shape: LBB methodology for cracked pipes

    SciTech Connect (OSTI)

    Moulin, D.; Chapuliot, S.; Drubay, B. [Commissariat a l Energie Atomique, Gif sur Yvette (France)

    1997-04-01T23:59:59.000Z

    For structures like vessels or pipes containing a fluid, the Leak-Before-Break (LBB) assessment requires to demonstrate that it is possible, during the lifetime of the component, to detect a rate of leakage due to a possible defect, the growth of which would result in a leak before-break of the component. This LBB assessment could be an important contribution to the overall structural integrity argument for many components. The aim of this paper is to review some practices used for LBB assessment and to describe how some new R & D results have been used to provide a simplified approach of fracture mechanics analysis and especially the evaluation of crack shape and size during the lifetime of the component.

  19. SciTech Connect: CRACK TIP PLASTICITY AND FRACTURE INITIATION...

    Office of Scientific and Technical Information (OSTI)

    N50000* --Metals, Ceramics, & Other Materials; CRACKS; FRACTURE PROPERTIES; METALS BUILDING MATERIALSfracture of metal, crack tip plasticity and initiation criteria for;...

  20. Life prediction for bridged fatigue cracks

    SciTech Connect (OSTI)

    Cox, B.N.

    1994-08-01T23:59:59.000Z

    One of the more promising classes of composites touted for high temperature applications, and certainly the most available, is that of relatively brittle matrices, either ceramic or intermetallic, reinforced by strong, aligned, continuous fibers. Under cyclic loading in the fiber direction, these materials develop matrix cracks that often run perpendicular to the fibers, while the fibers remain intact in the crack wake, supplying bridging tractions across the fracture surfaces. The bridging tractions shield the crack tip from the applied load, dramatically reducing the crack velocity from that expected in an unreinforced material subjected to the same value, {Delta}K{sub a}, of the cyclic applied stress intensity factor. An important issue in reliability is the prediction of the growth rates of the bridged cracks. The growth rates of matrix fatigue cracks bridged by sliding fibers are now commonly predicted by models based on the micromechanics of frictional interfaces. However, there exist many reasons, both theoretical and experimental, for suspecting that the most popular micromechanical models are probably wrong in detail in the context of fatigue cracks. Furthermore, a review of crack growth data reveals that the validity of the micromechanics-based predictive model has never been tested and may never be tested. In this paper, two alternative approaches are suggested to the engineering problem of predicting the growth rates of bridged cracks without explicit recourse to micromechanics. Instead, it is shown that the material properties required to analyze bridging effects can be deduced directly from crack growth data. Some experiments are proposed to test the validity of the proposals.

  1. Early stages in the development of stress corrosion cracks

    SciTech Connect (OSTI)

    Jones, R.H.; Simonen, E.P.

    1993-12-01T23:59:59.000Z

    Processes in growth of short cracks and stage I of long stress corrosion cracks were identified and evaluated. There is evidence that electrochemical effects can cause short stress corrosion cracks to grow at rates faster or slower than long cracks. Short cracks can grow at faster rates than long cracks for a salt film dissolution growth mechanism or from reduced oxygen inhibition of hydrolytic acidification. An increasing crack growth rate with increasing crack length could result from a process of increasing crack tip concentration of a critical anion, such as Cl{sup {minus}}, with increasing crack length in a system where the crack velocity is dependent on the Cl{sup {minus}} or some other anion concentration. An increasing potential drop between crack tip and mouth would result in an increased anion concentration at the crack tip and hence an increasing crack velocity. Stage I behavior of long cracks is another early development stage in the life of a stress corrosion crack which is poorly understood. This stage can be described by da/dt = AK{sup m} where da/dt is crack velocity, A is a constant, K is stress intensity and m ranges from 2 to 24 for a variety of materials and environments. Only the salt film dissolution model was found to quantitatively describe this stage; however, the model was only tested on one material and its general applicability is unknown.

  2. PHNOMNES DITS HYDRO-LECTRIQUES ET HYDROMAGNTIQUES; PAR M. C.-A. BJERKNES (1),

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    509 PH?NOM?NES DITS HYDRO-?LECTRIQUES ET HYDROMAGN?TIQUES; PAR M. C.-A. BJERKNES (1), Professeur à corps hydro- électrisés s'attirent ou se repoussent, suivant que leurs vibrations sont concordantes ou- minuent en même temps). Un hydro-aimant, formé ou bien d'une splzère oscillante ou de deux pulsateurs

  3. Role of Pumped Storage Hydro Resources in Electricity Markets and System Operation: Preprint

    SciTech Connect (OSTI)

    Ela, E.; Kirby, B.; Botterud, A.; Milostan, C.; Krad, I.; Koritarov, V.

    2013-05-01T23:59:59.000Z

    The most common form of utility- sized energy storage system is the pumped storage hydro system. Originally, these types of storage systems were economically viable simply because they displace more expensive generating units. However, over time, as those expensive units became more efficient and costs declined, pumped hydro storage units no longer have the operational edge. As a result, in the current electricity market environment, pumped storage hydro plants are struggling. To offset this phenomenon, certain market modifications should be addressed. This paper will introduce some of the challenges faced by pumped storage hydro plants in today's markets and purpose some solutions to those problems.

  4. BC Hydro Brings Energy Savings to Low-Income Families in Canada...

    Broader source: Energy.gov (indexed) [DOE]

    The number of British Columbia, Canada, households eligible for Better Buildings Residential Network member BC Hydro's Energy Conservation Assistance Program (ECAP) just doubled....

  5. Studies on fruit cracking of tomatoes

    E-Print Network [OSTI]

    Cotner, Sam Don

    1966-01-01T23:59:59.000Z

    calcium , 33 Means for naturally occurring cracks as influenced by foliar calcium applications 33 Analysis of variance for tomato fruit cracking as influended by foliar applications of CaC12 36 LIST QF TABLES CONTINUED 17. Analysis of variance...on of the cell contents oi' tomato fruits late in the season have been reported (10). Whatley (37) states that there is a 20 percent increase in osmot1c pressure from mature green to the red ripe stags. Radial cracking may be due to an increase...

  6. Vacuum-insulated catalytic converter

    DOE Patents [OSTI]

    Benson, David K. (Golden, CO)

    2001-01-01T23:59:59.000Z

    A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

  7. Methodology for extracting local constants from petroleum cracking flows

    DOE Patents [OSTI]

    Chang, Shen-Lin (Woodridge, IL); Lottes, Steven A. (Naperville, IL); Zhou, Chenn Q. (Munster, IN)

    2000-01-01T23:59:59.000Z

    A methodology provides for the extraction of local chemical kinetic model constants for use in a reacting flow computational fluid dynamics (CFD) computer code with chemical kinetic computations to optimize the operating conditions or design of the system, including retrofit design improvements to existing systems. The coupled CFD and kinetic computer code are used in combination with data obtained from a matrix of experimental tests to extract the kinetic constants. Local fluid dynamic effects are implicitly included in the extracted local kinetic constants for each particular application system to which the methodology is applied. The extracted local kinetic model constants work well over a fairly broad range of operating conditions for specific and complex reaction sets in specific and complex reactor systems. While disclosed in terms of use in a Fluid Catalytic Cracking (FCC) riser, the inventive methodology has application in virtually any reaction set to extract constants for any particular application and reaction set formulation. The methodology includes the step of: (1) selecting the test data sets for various conditions; (2) establishing the general trend of the parametric effect on the measured product yields; (3) calculating product yields for the selected test conditions using coupled computational fluid dynamics and chemical kinetics; (4) adjusting the local kinetic constants to match calculated product yields with experimental data; and (5) validating the determined set of local kinetic constants by comparing the calculated results with experimental data from additional test runs at different operating conditions.

  8. CRACK SPACING IN STRAINED FILMS B.B. Guzina1

    E-Print Network [OSTI]

    Guzina, Bojan

    , similar transverse cracking patterns are a feature of asphalt concrete pavements systems in cold climates

  9. Coding the cracks | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . October 3, 2014 Printer-friendly version Researchers use Mira to study stress-corrosion cracking in silicates Encased in the rocks that comprise much of Earth's crust and...

  10. Cracking in reinforced concrete bent caps

    E-Print Network [OSTI]

    Young, Bradley S.

    2000-01-01T23:59:59.000Z

    by studying the relationship between stresses in the longitudinal tension reinforcement, reinforcement detailing, shear resistance, and cracking of the bent cap during service loading through to failure. As a part of this investigation, sixteen full...

  11. Shrinkage - cracking characteristics of structural lightweight concrete

    E-Print Network [OSTI]

    McKeen, Robert Gordon

    1969-01-01T23:59:59.000Z

    1969 ABSTRACT Shrinkage-Cracking Characteristics of Structural Lightweight Concrete (August 1969) B. S. C. E. , Texas AERY University Directed by: if. B. Ledbetter Tests were conducted to det. trains the effect of coarse. s -gre- gate type...'csults indicated that both unrestrained shrinkage and concret. c water loss relate to restrained shrinkage stress. Unrestrained shrinks e did not indicate. cracking ter. dency while we+ er loss provided an indi cati on of cr cking tendency. ACRRO!Jr. ROOD. i...

  12. Pion correlations in hydro-inspired models with resonances

    E-Print Network [OSTI]

    W. Florkowski; W. Broniowski; A. Kisiel; J. Pluta

    2006-09-19T23:59:59.000Z

    The effects of the freeze-out hypersurface and resonance decays on the pion correlation functions in relativistic heavy-ion collisions are studied with help of the hydro-inspired models with single freeze-out. The heavy-ion Monte-Carlo generator THERMINATOR is used to generate hadronic events describing production of particles from a thermalized and expanding source. We find that the short-lived resonances increase the pionic HBT radii by about 1 fm. We also find that the pion HBT data from RHIC are fully compatible with the single freeze-out scenario provided a special choice of the freeze-out hypersurface is made.

  13. A new multidimensional AMR Hydro+Gravity Cosmological code

    E-Print Network [OSTI]

    Vicent Quilis

    2004-05-20T23:59:59.000Z

    A new cosmological multidimensional hydrodynamic and N-body code based on an Adaptive Mesh Refinement scheme is described and tested. The hydro part is based on modern high-resolution shock-capturing techniques, whereas N-body approach is based on the Particle Mesh method. The code has been specifically designed for cosmological applications. Tests including shocks, strong gradients, and gravity have been considered. A cosmological test based on Santa Barbara cluster is also presented. The usefulness of the code is discussed. In particular, this powerful tool is expected to be appropriate to describe the evolution of the hot gas component located inside asymmetric cosmological structures.

  14. Fengning Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A PotentialJumpGerman AerospaceEfficiencyInformationFengning Hydro Power

  15. Smart Hydro Power GmbH | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt LtdShawangunk, New York:SiG SolarSkykomish,NewEnergySmallSystem |Smart Hydro

  16. AD Hydro Power Ltd ADHPL | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDITCaliforniaWeifangwiki Home Jweers's APTAPFinal ReportAD Hydro Power

  17. Qingyang Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form History Facebook icon TwitterZipQingdao DTKQinghaiQingyang Hydro Power

  18. Qingyuan County Xiankeng Hydro Power Development Co Ltd | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form History Facebook icon TwitterZipQingdao DTKQinghaiQingyang Hydro

  19. HydroCoil Power Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEIHesperia, California:Project JumpHyEnergy SystemsHydro Green

  20. HydroGen Aquaphile sarl | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEIHesperia, California:Project JumpHyEnergy SystemsHydro

  1. HydroGen Corporation formerly Chiste Corp | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEIHesperia, California:Project JumpHyEnergy SystemsHydroChiste Corp

  2. Snohomish PUD see OpenHydro | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ |RippeyInformation SlimSloughCreekRhodePUD see OpenHydro

  3. Jinxiu Guangneng Hydro Power Company Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |Jilin Zhongdiantou New Energy Co Ltd JumpInformationGuangneng Hydro

  4. Ledong Xinyuan Hydro Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |Jilin Zhongdiantou NewKoreaLaor BatteriesLedong Xinyuan Hydro Power Co

  5. Madkini Hydro Power Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |JilinLu an Group Jump to:Macquarie Energy LLC JumpMadkini Hydro Power

  6. Tongdao Yaolaitan Hydro Power Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlin Baxin Hydropower Station Jump to:TiogaTongdao Yaolaitan Hydro Power

  7. Usaka Hydro Powers Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlin BaxinUmwelt Management AG UMaAGUnitilMichiganNewUrbemisUsaka Hydro

  8. Voith Hydro Ocean Current Technologies | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlin BaxinUmweltVillageGraph Home Wzeng's pictureVivergo FuelsVoith Hydro

  9. Birahi Ganga Hydro Power Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation in CarbonofBiotins Energia Jump to: navigation,Birahi Ganga Hydro

  10. Selective oxidation of hydrocarbons in a catalytic dense membrane reactor: Catalytic properties of BIMEVOX (Me = Ta)

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Selective oxidation of hydrocarbons in a catalytic dense membrane reactor: Catalytic properties for syngas or H2 production from light hydrocarbons. #12;2 Keywords: Dense membrane reactor, BIMEVOX, BITAVOX to decouple the two steps of the redox mechanism that prevails in selective oxidation of hydrocarbons [1

  11. VOC Destruction by Catalytic Combustion Microturbine

    SciTech Connect (OSTI)

    Tom Barton

    2009-03-10T23:59:59.000Z

    This project concerned the application of a catalytic combustion system that has been married to a micro-turbine device. The catalytic combustion system decomposes the VOC's and transmits these gases to the gas turbine. The turbine has been altered to operate on very low-level BTU fuels equivalent to 1.5% methane in air. The performance of the micro-turbine for VOC elimination has some flexibility with respect to operating conditions, and the system is adaptable to multiple industrial applications. The VOC source that was been chosen for examination was the emissions from coal upgrading operations. The overall goal of the project was to examine the effectiveness of a catalytic combustion based system for elimination of VOCs while simultaneously producing electrical power for local consumption. Project specific objectives included assessment of the feasibility for using a Flex-Microturbine that generates power from natural gas while it consumes VOCs generated from site operations; development of an engineering plan for installation of the Flex-Microturbine system; operation of the micro-turbine through various changes in site and operation conditions; measurement of the VOC destruction quantitatively; and determination of the required improvements for further studies. The micro-turbine with the catalytic bed worked effectively to produce power on levels of fuel much lower than the original turbine design. The ability of the device to add or subtract supplemental fuel to augment the amount of VOC's in the inlet air flow made the device an effective replacement for a traditional flare. Concerns about particulates in the inlet flow and the presence of high sulfur concentrations with the VOC mixtures was identified as a drawback with the current catalytic design. A new microturbine design was developed based on this research that incorporates a thermal oxidizer in place of the catalytic bed for applications where particulates or contamination would limit the lifetime of the catalytic bed.

  12. Formulaire de demande de bourse institutionnelle d'Hydro-Qubec Bourse de recrutement* OU Bourse de persvrance**

    E-Print Network [OSTI]

    Vellend, Mark

    Annexe B Formulaire de demande de bourse institutionnelle d'Hydro-Québec Bourse de recrutement* OU'étudiant : Montant de la bourse institutionnelle d'Hydro-Québec : 5 000 $ Montant de l

  13. Hydro-mechanical modelling of geological CO2 storage and the study of possible caprock fracture mechanisms

    E-Print Network [OSTI]

    Hydro-mechanical modelling of geological CO2 storage and the study of possible caprock fracture element modelling of a hypothetical underground carbon dioxide (CO2) storage operation. The hydro

  14. Author's personal copy Opportunities and barriers to pumped-hydro energy storage in the United States

    E-Print Network [OSTI]

    Jackson, Robert B.

    Author's personal copy Opportunities and barriers to pumped-hydro energy storage in the United available commercially for grid-tied electricity storage, pumped- hydro energy storage (PHES) and compressed air energy storage (CAES). Of the two, PHES is far more widely adopted. In the United States

  15. Stephen N. Ehrenberg $ StatoilHydro, N-9481, Harstad, Norway; present address

    E-Print Network [OSTI]

    Miami, University of

    studies for exploration and production projects. Tore A. Svana $ StatoilHydro, N-9481 Harstad, Norway at Norsk Hydro and thereafter at Statoil. He has worked on Barents Sea exploration and Mideastern carbonate versions of this article. Uranium depletion across the PermianTriassic boundary in Middle East carbonates

  16. Intelligent Voltage and Reactive Power Control of Mini-Hydro Power Stations for Maximisation of Real

    E-Print Network [OSTI]

    Harrison, Gareth

    1 Intelligent Voltage and Reactive Power Control of Mini-Hydro Power Stations for Maximisation Control (APFC) modes. The ability to export active and reactive power from mini-hydro power generators electrical power generation from renewable resources. Additionally, the potential early retiral of central

  17. PRIMAL AND DUAL METHODS FOR UNIT COMMITMENT IN A HYDRO-THERMAL POWER SYSTEM

    E-Print Network [OSTI]

    Rmisch, Werner

    PRIMAL AND DUAL METHODS FOR UNIT COMMITMENT IN A HYDRO-THERMAL POWER SYSTEM R. Gollmer1 , A. Moller comprising thermal and pumped-storage hydro units a large-scale mixed-integer optimization model is developed aims at the cost optimal scheduling of on/o decisions and output levels for generating units. The power

  18. Optimization and Control of a Hydro-Mechanical Transmission based Hybrid Hydraulic Passenger Vehicle

    E-Print Network [OSTI]

    Li, Perry Y.

    Optimization and Control of a Hydro-Mechanical Transmission based Hybrid Hydraulic Passenger Vehicle Perry Y. Li Felicitas Mensing Center for Compact and Efficient Fluid Power, University of Minnesota, Minneapolis, USA ABSTRACT Hydro-mechanical transmission (HMT) based hybrid hydraulic vehicle

  19. ANALYSIS AND CONTROL DESIGN OF A HYDRO-MECHANICAL HYDRAULIC HYBRID PASSENGER VEHICLE

    E-Print Network [OSTI]

    Li, Perry Y.

    for optimal engine management. The hydro-mechanical drive train splits the engine power through two pathsANALYSIS AND CONTROL DESIGN OF A HYDRO-MECHANICAL HYDRAULIC HYBRID PASSENGER VEHICLE Teck Ping, Sim Minneapolis, Minnesota 55455 Email: tpsim@me.umn.edu Perry Y. Li Center for Compact and Efficient Fluid Power

  20. Paper Number Development of a Hydro-Mechanical Hydraulic Hybrid Drive

    E-Print Network [OSTI]

    Li, Perry Y.

    for the Center for Compact and Efficient Fluid Power at the University of Minnesota. The hydro-mechanical hybrid is leveraging the intrinsically high power density of the hydraulic energy storage system through optimal enginePaper Number Development of a Hydro-Mechanical Hydraulic Hybrid Drive Train with Independent Wheel

  1. LOCAL UNDERSTANDING OF HYDRO-CLIMATE CHANGES IN MONGOLIA Submitted by

    E-Print Network [OSTI]

    MacDonald, Lee

    THESIS LOCAL UNDERSTANDING OF HYDRO-CLIMATE CHANGES IN MONGOLIA Submitted by Tumenjargal Sukh 2012 All Rights Reserved #12;ABSTRACT LOCAL UNDERSTANDING OF HYDRO-CLIMATE CHANGES IN MONGOLIA Air temperatures have increased more in semi-arid regions than in many other parts of the world. Mongolia has

  2. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    W. R. Laster; E. Anoshkina; P. Szedlacsek

    2006-03-31T23:59:59.000Z

    Under the sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse is conducting a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1-Implementation Plan, Phase 2-Validation Testing and Phase 3-Field Testing. The Phase 1 program has been completed. Phase II was initiated in October 2004. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCL{trademark}) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to react part of the fuel, increasing the fuel/air mixture temperature. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the catalytic concept will be demonstrated through subscale testing. Phase III will consist of full-scale combustor basket testing on natural gas and syngas.

  3. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    W. R. Laster; E. Anoshkina

    2008-01-31T23:59:59.000Z

    Under the sponsorship of the U. S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1 - Implementation Plan, Phase 2 - Validation Testing and Phase 3 - Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

  4. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    Laster, W. R.; Anoshkina, E.

    2008-01-31T23:59:59.000Z

    Under the sponsorship of the U. S. Department of Energys National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1- Implementation Plan, Phase 2- Validation Testing and Phase 3 Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

  5. Hydro-kinetic approach to relativistic heavy ion collisions

    E-Print Network [OSTI]

    S. V. Akkelin; Y. Hama; Iu. A. Karpenko; Yu. M. Sinyukov

    2008-08-28T23:59:59.000Z

    We develop a combined hydro-kinetic approach which incorporates a hydrodynamical expansion of the systems formed in \\textit{A}+\\textit{A} collisions and their dynamical decoupling described by escape probabilities. The method corresponds to a generalized relaxation time ($\\tau_{\\text{rel}}$) approximation for the Boltzmann equation applied to inhomogeneous expanding systems; at small $\\tau_{\\text{rel}}$ it also allows one to catch the viscous effects in hadronic component - hadron-resonance gas. We demonstrate how the approximation of sudden freeze-out can be obtained within this dynamical picture of continuous emission and find that hypersurfaces, corresponding to a sharp freeze-out limit, are momentum dependent. The pion $m_{T}$ spectra are computed in the developed hydro-kinetic model, and compared with those obtained from ideal hydrodynamics with the Cooper-Frye isothermal prescription. Our results indicate that there does not exist a universal freeze-out temperature for pions with different momenta, and support an earlier decoupling of higher $p_{T}$ particles. By performing numerical simulations for various initial conditions and equations of state we identify several characteristic features of the bulk QCD matter evolution preferred in view of the current analysis of heavy ion collisions at RHIC energies.

  6. Laboratory Hydro-mechanical Characterisation of Boom Clay at Essen and Mol Y. F. Deng1, 2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Laboratory Hydro-mechanical Characterisation of Boom Clay at Essen and Mol Y. F. Deng1, 2 , A. M. In the present work, the hydro-mechanical behaviour of Boom clay samples from the borehole Essen-1 at a depth and hydro-mechanical behaviour of Boom clay from Essen at 227-m, 240-m and 248-m depths are similar

  7. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1002/, Hydro-acoustic and tsunami waves generated by the1

    E-Print Network [OSTI]

    Kirby, James T.

    JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1002/, Hydro-acoustic and tsunami waves TSUNAMI Abstract. Detection of low-frequency hydro-acoustic waves as precur-4 sor components model gave us the opportunity to study13 the hydro-acoustic wave propagation in a large-scale domain

  8. Phenomene couple thermo-hydro-mecanique des roches fracturees: Recents developpements des methodes de modelisation et tests de validation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    95-54 Phenomene couple thermo-hydro-mecanique des roches fracturees: Recents developpements des methodes de modelisation et tests de validation Coupled thermo-hydro-mechanical phenomena in fractured fracture.La deuxiemequestion concemela modelisation des phenomenes couples thenno-hydro-mecaniques. L

  9. February 16-18, 2011 / Biel (Bienne), Switzerland Comparison between accelerated thermo-hydro aged wood and naturally

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    February 16-18, 2011 / Biel (Bienne), Switzerland Comparison between accelerated thermo-hydro aged Bois 3 DEISTAF ­ University of Florence, Italy Key words: accelerated aging, micro-mechanics, thermo-hydro]. It has been observed that similar degradation can be found in thermo-hydro (TH) treated wood [4]. The aim

  10. Hydro-economic models: Concepts, design, applications, and future prospects Julien J. Harou a,*, Manuel Pulido-Velazquez b

    E-Print Network [OSTI]

    Pasternack, Gregory B.

    Review Hydro-economic models: Concepts, design, applications, and future prospects Julien J. Harou of Frank Ward, Associate Editor Keywords: Hydro-economic models Integrated water resource management (IWRM and space will increasingly motivate efforts to address water scarcity and reduce water conflicts. Hydro

  11. Do phreatomagmatic eruptions at Ubehebe Crater (Death Valley, California) relate to a wetter than present hydro-climate?

    E-Print Network [OSTI]

    Christie-Blick, Nicholas

    present hydro-climate? Peri Sasnett,1,2 Brent M. Goehring,1,2,3 Nicholas Christie-Blick,1,2 and Joerg M the idea that volcanism may relate to a wetter than present hydro-climate. Twelve of the fifteen ages that eruptive timing relates to a wetter hydro-climate. Instead, the presence of a relatively shallow modern

  12. Topology of desiccation crack patterns in clay and invariance of crack interface area with thickness

    E-Print Network [OSTI]

    Tajkera Khatun; Tapati Dutta; Sujata Tarafdar

    2014-12-09T23:59:59.000Z

    We study the crack patterns developed on desiccating films of an aqueous colloidal suspension of bentonite on a glass substrate. Varying the thickness of the layer $h$ gives the following new and interesting results: (i)We identify a critical thickness $h_{c}$, above which isolated cracks join each other to form a fully connected network. A topological analysis of the crack network shows that the Euler number falls to a minimum at $h_{c}$. (ii) We find further, that the total vertical surface area of the clay $A_v$, which has opened up due to cracking, is a constant independent of the layer thickness for $h \\geq h_c$. (iii) The total area of the glass substrate $A_s$, exposed by the hierarchical sequence of cracks is also a constant for $h \\geq h_c$. These results are shown to be consistent with a simple energy conservation argument, neglecting dissipative losses. (iv) Finally we show that if the crack pattern is viewed at successively finer resolution, the total cumulative area of cracks visible at a certain resolution, scales with the layer thickness. A suspension of Laponite in methanol is found to exhibit similar salient features (i)-(iv), though in this case the crack initiation process for very thin layers is quite different.

  13. Contstraint effects of shallow cracks in structures containing fillet weld toe cracks

    E-Print Network [OSTI]

    Neligon, Melinda T

    1995-01-01T23:59:59.000Z

    for structures containing a/W--O.l and a/W--O.5 fillet weld toe cracks. The Anderson-Dodds scaling model is applied to quantify the effects of finite size on J contour integral values for structures containing a/W=O.l and a/W=0.5 fillet weld toe cracks loaded...

  14. Contstraint effects of shallow cracks in structures containing fillet weld toe cracks

    E-Print Network [OSTI]

    Neligon, Melinda T

    1995-01-01T23:59:59.000Z

    for structures containing a/W--O.l and a/W--O.5 fillet weld toe cracks. The Anderson-Dodds scaling model is applied to quantify the effects of finite size on J contour integral values for structures containing a/W=O.l and a/W=0.5 fillet weld toe cracks loaded...

  15. Recent evaluations of crack-opening-area in circumferentially cracked pipes

    SciTech Connect (OSTI)

    Rahman, S.; Brust, F.; Ghadiali, N.; Wilkowski, G.; Miura, N.

    1997-04-01T23:59:59.000Z

    Leak-before-break (LBB) analyses for circumferentially cracked pipes are currently being conducted in the nuclear industry to justify elimination of pipe whip restraints and jet shields which are present because of the expected dynamic effects from pipe rupture. The application of the LBB methodology frequently requires calculation of leak rates. The leak rates depend on the crack-opening area of the through-wall crack in the pipe. In addition to LBB analyses which assume a hypothetical flaw size, there is also interest in the integrity of actual leaking cracks corresponding to current leakage detection requirements in NRC Regulatory Guide 1.45, or for assessing temporary repair of Class 2 and 3 pipes that have leaks as are being evaluated in ASME Section XI. The objectives of this study were to review, evaluate, and refine current predictive models for performing crack-opening-area analyses of circumferentially cracked pipes. The results from twenty-five full-scale pipe fracture experiments, conducted in the Degraded Piping Program, the International Piping Integrity Research Group Program, and the Short Cracks in Piping and Piping Welds Program, were used to verify the analytical models. Standard statistical analyses were performed to assess used to verify the analytical models. Standard statistical analyses were performed to assess quantitatively the accuracy of the predictive models. The evaluation also involved finite element analyses for determining the crack-opening profile often needed to perform leak-rate calculations.

  16. TRANSPORT THROUGH CRACKED CONCRETE: LITERATURE REVIEW

    SciTech Connect (OSTI)

    Langton, C.

    2012-05-11T23:59:59.000Z

    Concrete containment structures and cement-based fills and waste forms are used at the Savannah River Site to enhance the performance of shallow land disposal systems designed for containment of low-level radioactive waste. Understanding and measuring transport through cracked concrete is important for describing the initial condition of radioactive waste containment structures at the Savannah River Site (SRS) and for predicting performance of these structures over time. This report transmits the results of a literature review on transport through cracked concrete which was performed by Professor Jason Weiss, Purdue University per SRR0000678 (RFP-RQ00001029-WY). This review complements the NRC-sponsored literature review and assessment of factors relevant to performance of grouted systems for radioactive waste disposal. This review was performed by The Center for Nuclear Waste Regulatory Analyses, San Antonio, TX, and The University of Aberdeen, Aberdeen Scotland and was focused on tank closure. The objective of the literature review on transport through cracked concrete was to identify information in the open literature which can be applied to SRS transport models for cementitious containment structures, fills, and waste forms. In addition, the literature review was intended to: (1) Provide a framework for describing and classifying cracks in containment structures and cementitious materials used in radioactive waste disposal, (2) Document the state of knowledge and research related to transport through cracks in concrete for various exposure conditions, (3) Provide information or methodology for answering several specific questions related to cracking and transport in concrete, and (4) Provide information that can be used to design experiments on transport through cracked samples and actual structures.

  17. STRESS CORROSION CRACKING IN TEAR DROP SPECIMENS

    SciTech Connect (OSTI)

    Lam, P; Philip Zapp, P; Jonathan Duffey, J; Kerry Dunn, K

    2009-05-01T23:59:59.000Z

    Laboratory tests were conducted to investigate the stress corrosion cracking (SCC) of 304L stainless steel used to construct the containment vessels for the storage of plutonium-bearing materials. The tear drop corrosion specimens each with an autogenous weld in the center were placed in contact with moist plutonium oxide and chloride salt mixtures. Cracking was found in two of the specimens in the heat affected zone (HAZ) at the apex area. Finite element analysis was performed to simulate the specimen fabrication for determining the internal stress which caused SCC to occur. It was found that the tensile stress at the crack initiation site was about 30% lower than the highest stress which had been shifted to the shoulders of the specimen due to the specimen fabrication process. This finding appears to indicate that the SCC initiation took place in favor of the possibly weaker weld/base metal interface at a sufficiently high level of background stress. The base material, even subject to a higher tensile stress, was not cracked. The relieving of tensile stress due to SCC initiation and growth in the HAZ and the weld might have foreclosed the potential for cracking at the specimen shoulders where higher stress was found.

  18. Crack detection using pulsed eddy current stimulated thermography

    SciTech Connect (OSTI)

    Kostson, E.; Weekes, B.; Almond, D. P. [RCNDE, Department of Mechanical Engineering, University of Bath (United Kingdom); Wilson, J.; Tian, G. Y. [School of Electrical, Electronic and Computer Engineering, Newcastle University (United Kingdom)

    2011-06-23T23:59:59.000Z

    This contribution presents results from studies investigating factors that influence the detection of surface breaking cracks using pulsed eddy current thermography. The influences of the current strength and crack orientation in both ferromagnetic and non-ferromagnetic metals have been investigated. It has been found that crack detection is far more sensitive to crack orientation in non-ferromagnetic metals than in ferromagnetic metals. The effects of crack size on detectability are presented for a large number of steel, nickel alloy and titanium samples. Results of studies comparing crack images obtained prior and after coating a nickel alloy sample with a thermal barrier coating are presented.

  19. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31T23:59:59.000Z

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  20. Porous Core-Shell Nanostructures for Catalytic Applications

    E-Print Network [OSTI]

    Ewers, Trevor David

    2012-01-01T23:59:59.000Z

    C.Y Mou. Catalytic nano-rattle of Au@ hollow silica: towardshollow nanostructures induced by the Kirkendall effect: The basic concept. NanoHollow mesoporous aluminosilica spheres with perpendicular pore channels as catalytic nanoreactors. ACS Nano,

  1. Environmentally assisted cracking of LWR materials.

    SciTech Connect (OSTI)

    Chopra, O. K.; Chung, H. M.; Kassner, T. F.; Park, J. H.; Shack, W. J.; Zhang, J.; Brust, F. W.; Dong, P.

    1997-12-05T23:59:59.000Z

    The effect of dissolved oxygen level on fatigue life of austenitic stainless steels is discussed and the results of a detailed study of the effect of the environment on the growth of cracks during fatigue initiation are presented. Initial test results are given for specimens irradiated in the Halden reactor. Impurities introduced by shielded metal arc welding that may affect susceptibility to stress corrosion cracking are described. Results of calculations of residual stresses in core shroud weldments are summarized. Crack growth rates of high-nickel alloys under cyclic loading with R ratios from 0.2-0.95 in water that contains a wide range of dissolved oxygen and hydrogen concentrations at 289 and 320 C are summarized.

  2. Crack detection using resonant ultrasound spectroscopy

    DOE Patents [OSTI]

    Migliori, Albert (Santa Fe, NM); Bell, Thomas M. (Santa Fe, NM); Rhodes, George W. (Albuquerque, NM)

    1994-01-01T23:59:59.000Z

    Method and apparatus are provided for detecting crack-like flaws in components. A plurality of exciting frequencies are generated and applied to a component in a dry condition to obtain a first ultrasonic spectrum of the component. The component is then wet with a selected liquid to penetrate any crack-like flaws in the component. The plurality of exciting frequencies are again applied to the component and a second ultrasonic spectrum of the component is obtained. The wet and dry ultrasonic spectra are then analyzed to determine the second harmonic components in each of the ultrasonic resonance spectra and the second harmonic components are compared to ascertain the presence of crack-like flaws in the component.

  3. Crack detection using resonant ultrasound spectroscopy

    DOE Patents [OSTI]

    Migliori, A.; Bell, T.M.; Rhodes, G.W.

    1994-10-04T23:59:59.000Z

    Method and apparatus are provided for detecting crack-like flaws in components. A plurality of exciting frequencies are generated and applied to a component in a dry condition to obtain a first ultrasonic spectrum of the component. The component is then wet with a selected liquid to penetrate any crack-like flaws in the component. The plurality of exciting frequencies are again applied to the component and a second ultrasonic spectrum of the component is obtained. The wet and dry ultrasonic spectra are then analyzed to determine the second harmonic components in each of the ultrasonic resonance spectra and the second harmonic components are compared to ascertain the presence of crack-like flaws in the component. 5 figs.

  4. Demetallization of asphaltenes: Thermal and catalytic effects with small-pore catalysts

    SciTech Connect (OSTI)

    Adarme, R. (Oklahoma State Univ., Stillwater, OK (United States)); Sughrue, E.L.; Johnson, M.M.; Kidd, D.R.; Phillips, M.D.; Shaw, J.E. (Phillips Petroleum Co., Bartlesville, OK (United States))

    1990-08-01T23:59:59.000Z

    Residual oil hydrotreating has become an important front end process in commercial oil upgrading schemes because of tighter environmental regulations and a continuing trend toward processing heavier crudes. At Phillips Petroleum, residual oil hydrotreating pretreates feed for heavy oil cracking (HOC) by removing sulfur, a pollutant in the HOC stack gas, and metals such as nickel and vanadium, which adversely affect the cracking catalyst and gasoline yield in the HOC. Metals in residual oil are found almost exclusively in the resin and asphaltene fractions. Research has showed that metals in the resin fraction react more rapidly than metals in the asphaltene fraction. The hydrodemetallization (HDM) reaction is known to be diffusion limited and the larger molecular size of the asphaltene molecules may explain the slower reaction rates. Richardson and Alley and Asaoka, et al. have shown a reduction in asphaltene molecular weights with thermal and catalytic processing. Reynolds and Biggs demonstrated shifts in vanadium size distributions from thermally and catalytically treated residual. Recently Savage and Javanmaridian showed theoretically that reduction in molecular sizes external to catalyst pellets increases the reaction rate by as much as the inverse of the effectiveness factor. This work attempts to extend information on how metals are removed from asphaltenes and the interaction with small-pore catalysts generally found at the back end of residual oil hydrotreaters, where they are protected from deactivation by metal deposition. The small-pore catalysts are generally high in hydrodesulfurization (HDS) activity and generally restrict the large asphaltene molecules from entering their pores and depositing metals.

  5. Fast electromigration crack in nanoscale aluminum film

    SciTech Connect (OSTI)

    Emelyanov, O. A., E-mail: oaemel2@gmail.com; Ivanov, I. O. [St. Petersburg State Polytechnical University, Saint-Petersburg (Russian Federation)

    2014-08-14T23:59:59.000Z

    The current-induced breakage of 20?nm thin aluminum layers deposited onto capacitor grade polypropylene (PP) films is experimentally studied. Biexponential current pulses of different amplitude (1015?A) and duration (0.11??s) were applied to the samples. Breakage occurred after fast development of electromigrating ?200?nm-wide cracks with initial propagation velocity of ?1?m/s under a high current density of ?10{sup 12?}A/m{sup 2}. The cracks stopped when their lengths reached 250450??m. This behavior is explained by the balance of electromigration and stress-induced atomic fluxes.

  6. CATALYTICALLY ENCHANCED SYSTEMS FOR HYDROGEN STORAGE

    E-Print Network [OSTI]

    to the conversion of the world to a "hydrogen economy" is the problem of onboard hydrogen storage. Despite decadesCATALYTICALLY ENCHANCED SYSTEMS FOR HYDROGEN STORAGE Craig M. Jensen, Dalin Sun, Sesha Sai RamanH/Al and the reverse hydrogenation reactions have been determined through kinetic studies of 2 mol % Ti and Zr doped

  7. Performance characterization of a hydrogen catalytic heater.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Kanouff, Michael P.

    2010-04-01T23:59:59.000Z

    This report describes the performance of a high efficiency, compact heater that uses the catalytic oxidation of hydrogen to provide heat to the GM Hydrogen Storage Demonstration System. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to a circulating heat transfer fluid. The fluid then transfers the heat to one or more of the four hydrogen storage modules that make up the Demonstration System to drive off the chemically bound hydrogen. The heater consists of three main parts: (1) the reactor, (2) the gas heat recuperator, and (3) oil and gas flow distribution manifolds. The reactor and recuperator are integrated, compact, finned-plate heat exchangers to maximize heat transfer efficiency and minimize mass and volume. Detailed, three-dimensional, multi-physics computational models were used to design and optimize the system. At full power the heater was able to catalytically combust a 10% hydrogen/air mixture flowing at over 80 cubic feet per minute and transfer 30 kW of heat to a 30 gallon per minute flow of oil over a temperature range from 100 C to 220 C. The total efficiency of the catalytic heater, defined as the heat transferred to the oil divided by the inlet hydrogen chemical energy, was characterized and methods for improvement were investigated.

  8. Transparent and Catalytic Carbon Nanotube Films

    E-Print Network [OSTI]

    Hone, James

    for the dye-sensitized solar cell. Other possible applications include batteries, fuel cells and intercalation in hydrogen fuel cells and lithium ion batteries.1,10,12,14 However, the electrochemical activity to optimize performance through processing. In this study, we quantify the catalytic activity of single

  9. Methods of cracking a crude product to produce additional crude products

    DOE Patents [OSTI]

    Mo, Weijian (Sugar Land, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX); Nair, Vijay (Katy, TX)

    2009-09-08T23:59:59.000Z

    A method for producing a crude product is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce one or more crude products. At least one of the crude products has a boiling range distribution from 38.degree. C. and 343.degree. C. as determined by ASTM Method D5307. The crude product having the boiling range distribution from 38.degree. C. and 343.degree. C. is catalytically cracked to produce one or more additional crude products. At least one of the additional crude products is a second gas stream. The second gas stream has a boiling point of at most 38.degree. C. at 0.101 MPa.

  10. Crack closure effects on fatigue crack growth thresholds and remaining life in an HSLA steel

    SciTech Connect (OSTI)

    Todd, J.A.; Mostovoy, S. [Illinois Inst. of Tech., Chicago, IL (United States). Dept. of Mechanical, Materials and Aerospace Engineering; Chen, L. [Texas Instruments, Attleboro, MA (United States); Yankov, E.Y. [A. Finkl and Sons, Chicago, IL (United States)

    1997-02-01T23:59:59.000Z

    The effects of crack closure on the near-threshold corrosion fatigue crack growth behavior of Mil S-24645 HSLA steel and its weld metal have been investigated in air, ASTM seawater at the free corrosion potential, and ASTM seawater at {minus}0.8V and {minus}1.0V (SCE) using frequencies of 10, 2, and 0.2 Hz, and a stress ratio, R = 0.1. Remaining life, in the presence and absence of crack closure, has been estimated as a function of applied stress range for a structure containing a 3-mm-deep surface semi-elliptical flaw.

  11. Revue. Volume X n x/anne, pages 1 X Comportement thermo-hydro-mcanique

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Revue. Volume X ­ n° x/année, pages 1 à X Comportement thermo-hydro-mécanique (THM) d'un ouvrage en'évaluer les risques de la dégradation de la pierre dues aux couplages thermo-hydro-mécaniques qui conduisent à'année 2008 par une station météo aérienne située proche du château. Les analyses couplées thermo-hydro

  12. Reflective Cracking Study: HVS Test Section Forensic Investigation

    E-Print Network [OSTI]

    Jones, David; Steven, B.; Harvey, John T

    2008-01-01T23:59:59.000Z

    the asphalt concrete. Summary of Testing on the Underlyingtesting performed to validate Caltrans overlay strategies for the rehabilitation of cracked asphalt concrete.concrete. It describes the forensic investigation of the HVS rutting and reflective cracking testing

  13. Characterization of Fatigue Cracking and Healing of Asphalt Mixtures

    E-Print Network [OSTI]

    Luo, Xue

    2012-07-16T23:59:59.000Z

    mixtures using an energy-based mechanistic approach. A controlled-strain repeated direct tension (RDT) test is selected to generate both fatigue cracking and permanent deformation in an asphalt mixture specimen. Fatigue cracking is separated from...

  14. Grain Boundary Structure Effects on Intergranular Stress Corrosion Cracking of

    E-Print Network [OSTI]

    Olson, Tamara

    Grain Boundary Structure Effects on Intergranular Stress Corrosion Cracking of Alloy X­750 Y. Pan B­of­freedom) and correlations with intergranular stress corrosion cracking observed in Alloy X­750. Orientation imaging

  15. A dynamical law for slow crack growth in polycarbonate films

    E-Print Network [OSTI]

    Cortet, Pierre-Philippe; Ciliberto, Sergio

    2007-01-01T23:59:59.000Z

    We study experimentally the slow growth of a single crack in polycarbonate films submitted to uniaxial and constant imposed stress. For this visco-plastic material, we uncover a dynamical law that describes the dependence of the instantaneous crack velocity with experimental parameters. The law involves a Dugdale-Barenblatt static description of crack tip plastic zones associated to an Eyring's law and an empirical dependence with the crack length that may come from a residual elastic field.

  16. Prediction of thermal crack spacing D.H. Timm a

    E-Print Network [OSTI]

    Guzina, Bojan

    understanding of thin film coatings but an understanding of how so-called thermal cracks, a feature of cold

  17. autogenous shrinkage cracking: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Restrained Shrinkage Cracking of Concrete Materials," 15th International Glass Fibre Reinforced Concrete Association Engineering Websites Summary: . The experiments...

  18. Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids

    SciTech Connect (OSTI)

    Ted Oyama, Foster Agblevor, Francine Battaglia, Michael Klein

    2013-01-18T23:59:59.000Z

    The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

  19. Catalytic co-processing of coal with bitumen and bitumen derived liquids

    SciTech Connect (OSTI)

    Chakma, A.; Zaman, J. [Univ. of Calgary, Alberta (Canada)

    1993-12-31T23:59:59.000Z

    Experimental studies on the co-processing of coal with bitumen and bitumen derived liquids are described. A subbituminous coal was coprocessed with Athabasca bitumen and its various liquid fractions in a batch autoclave under hydrogen pressure at reaction temperatures varying from 400 to 440{degrees}C. Both thermal and catalytic coprocessing experiments were conducted. The catalysts used were molten halide type and included ZnCl{sub 2}, MoCl{sub 5}, KCl, CuCl, and SnCl{sub 2}. Higher reaction temperature resulted in higher conversion of asphaltenes into both maltenes and coke and gases. As a result the H/C atomic ratio of the unconverted asphaltenes decreased with temperature. Higher reaction time on the other hand allowed maltenes to be converted to asphaltenes. While all the catalysts tested had catalytic effects on asphaltene conversion, MoCl{sub 5} was found to provide the highest conversion of asphaltenes due to its ability to hydrogenate the radicals formed due to asphaltene cracking. Processing of coal with bitumen derived liquids provided higher yields than those obtained with virgin bitumen. The H/C ratios were also higher for the products obtained with bitumen derived liquids.

  20. CRACK STATISTIC OF CRYSTALLINE SILICON PHOTOVOLTAIC MODULES M. Kntges1

    E-Print Network [OSTI]

    the risk of cracks, as well as for statistical power loss assessment. Keywords: PV module, micro cracks separation, thus resulting in inactive cell parts. For this special case a clear assessment of the power loss this gap and provide a first statistic of cracks in PV modules for future power loss assessment

  1. RESEARCH Open Access Pavement crack characteristic detection based

    E-Print Network [OSTI]

    Joensuu, University of

    RESEARCH Open Access Pavement crack characteristic detection based on sparse representation Xiaoming Sun1 , Jianping Huang1 , Wanyu Liu1* and Mantao Xu2 Abstract Pavement crack detection plays an important role in pavement maintaining and management. The three- dimensional (3D) pavement crack detection

  2. Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion

    SciTech Connect (OSTI)

    Beck, H.W.; Carruthers, J.D.; Cornelius, E.B.; Hettinger, Jr., W.P.; Kovach, S.M.; Palmer, J.L.; Zandona, O.J.

    1988-06-14T23:59:59.000Z

    This patent describes a process for the cracking of a hydrocarbon oil feed having a significant content of at least 0.1 ppm vanadium to lighter oil products. The process consists of contacting the feed under conversion conditions in a conversion zone with a catalyst containing a precipitated metal additive to immobilize vanadium compounds by forming compounds therewith that have melting points above temperatures found in regenerating a coked catalyst; and having catalytic cracking characteristics, coke and vanadium being deposited on the catalyst by the contact; regenerating the coked catalyst in the presence of an oxygen containing gas at a temperature sufficient to remove at least some of the coke, and, recycling the regenerated catalyst to the conversion zone for contact with fresh feed; the metal additive being present on the catalyst in an amount sufficient to immobilize at least a portion of the vanadium compound in the presence of the oxygen containing gas at the catalyst regeneration temperature; wherein the metal additive to immobilize vanadium compounds deposited on the catalyst is selected from the group consisting of Sr, Sc, Y, Nb, and Ta elements, and an element in the actinide series, or a combination of two or more of the elements.

  3. Enhanced ultrasonic detection of fatigue cracks by laser-induced crack closure

    E-Print Network [OSTI]

    Nagy, Peter B.

    , corrosion, etc. . Sec- ond, it is important to distinguish small fatigue cracks as early as possible after threshold in aluminum, aluminum lithium, and titanium alloys.1 For example, extensive multiple-site fatigue

  4. Stress corrosion cracking and crack tip characterization of Alloy X-750 in light water reactor environments

    E-Print Network [OSTI]

    Gibbs, Jonathan Paul

    2011-01-01T23:59:59.000Z

    Stress corrosion cracking (SCC) susceptibility of Inconel Alloy X-750 in the HTH condition has been evaluated in high purity water at 93 and 288C under Boiling Water Reactor Normal Water Chemistry (NWC) and Hydrogen Water ...

  5. Stress Corrosion Cracking and Crack Tip Characterization of Alloy X-750 in Light Water Reactor Environments

    E-Print Network [OSTI]

    Gibbs, Jonathan Paul

    Stress corrosion cracking (SCC) susceptibility of Inconel Alloy X-750 in the HTH condition has been evaluated in high purity water at 93 and 288C under Boiling Water Reactor Normal Water Chemistry (NWC) and Hydrogen Water ...

  6. The true toughness of human cortical bone measured with realistically short cracks

    E-Print Network [OSTI]

    Ritchie, Robert

    crack-resistance curves. We find that after only 500 m of cracking, the driving force for crack. However, the toughness in the longitudinal orientation, where cracks tend to follow the cement lines mechanisms, which act primarily in the crack wake to `shield' the crack from the applied driving force

  7. Digital radiographic systems detect boiler tube cracks

    SciTech Connect (OSTI)

    Walker, S. [EPRI, Charlotte, NC (United States)

    2008-06-15T23:59:59.000Z

    Boiler water wall leaks have been a major cause of steam plant forced outages. But conventional nondestructive evaluation techniques have a poor track record of detecting corrosion fatigue cracking on the inside surface of the cold side of waterwall tubing. EPRI is performing field trials of a prototype direct-digital radiographic system that promises to be a game changer. 8 figs.

  8. Environmentally assisted cracking in light water reactors

    SciTech Connect (OSTI)

    Chopra, O.K.; Chung, H.M.; Gruber, E.E. [and others

    1996-07-01T23:59:59.000Z

    This report summarizes work performed by Argonne National Laboratory on fatigue and environmentally assisted cracking (EAC) in light water reactors (LWRs) from April 1995 to December 1995. Topics that have been investigated include fatigue of carbon and low-alloy steel used in reactor piping and pressure vessels, EAC of Alloy 600 and 690, and irradiation-assisted stress corrosion cracking (IASCC) of Type 304 SS. Fatigue tests were conducted on ferritic steels in water that contained various concentrations of dissolved oxygen (DO) to determine whether a slow strain rate applied during different portions of a tensile-loading cycle are equally effective in decreasing fatigue life. Crack-growth-rate tests were conducted on compact-tension specimens from several heats of Alloys 600 and 690 in simulated LWR environments. Effects of fluoride-ion contamination on susceptibility to intergranular cracking of high- and commercial- purity Type 304 SS specimens from control-tensile tests at 288 degrees Centigrade. Microchemical changes in the specimens were studied by Auger electron spectroscopy and scanning electron microscopy to determine whether trace impurity elements may contribute to IASCC of these materials.

  9. Application of the cracked pipe element to creep crack growth prediction

    SciTech Connect (OSTI)

    Brochard, J.; Charras, T.

    1997-04-01T23:59:59.000Z

    The modification of a computer code for leak before break analysis is very briefly described. The CASTEM2000 code was developed for ductile fracture assessment of piping systems with postulated circumferential through-wall cracks under static or dynamic loading. The modification extends the capabilities of the cracked pipe element to the determination of fracture parameters under creep conditions (C*, {phi}c and {Delta}c). The model has the advantage of evaluating significant secondary effects, such as those from thermal loading.

  10. Method and apparatus for a catalytic firebox reactor

    DOE Patents [OSTI]

    Smith, Lance L. (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Ulkarim, Hasan (Hamden, CT); Castaldi, Marco J. (Bridgeport, CT); Pfefferle, William C. (Madison, CT)

    2001-01-01T23:59:59.000Z

    A catalytic firebox reactor employing an exothermic catalytic reaction channel and multiple cooling conduits for creating a partially reacted fuel/oxidant mixture. An oxidation catalyst is deposited on the walls forming the boundary between the multiple cooling conduits and the exothermic catalytic reaction channel, on the side of the walls facing the exothermic catalytic reaction channel. This configuration allows the oxidation catalyst to be backside cooled by any fluid passing through the cooling conduits. The heat of reaction is added to both the fluid in the exothermic catalytic reaction channel and the fluid passing through the cooling conduits. After discharge of the fluids from the exothermic catalytic reaction channel, the fluids mix to create a single combined flow. A further innovation in the reactor incorporates geometric changes in the exothermic catalytic reaction channel to provide streamwise variation of the velocity of the fluids in the reactor.

  11. Dayao County Yupao River BasDayao County Yupao River Basin Hydro...

    Open Energy Info (EERE)

    Dayao County Yupao River BasDayao County Yupao River Basin Hydro electricity Development Co Ltd in Jump to: navigation, search Name: Dayao County Yupao River BasDayao County Yupao...

  12. For Immediate Release --Friday, September 20, 2013 Current polygamy challenges and First Nations Hydro-

    E-Print Network [OSTI]

    Seldin, Jonathan P.

    of Norway. Both groups were affected by large-scale hydroelectric power developments challenges and First Nations Hydro- power rights in Norway and Canada: Parkland framed the implementation of hydroelectric projects on indigenous land. Though

  13. A Geological and Hydro-Geochemical Study of the Animas Geothermal...

    Open Energy Info (EERE)

    Hydro-Geochemical Study of the Animas Geothermal Area, Hidalgo County, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Geological...

  14. Polymers with hydro-responsive topography identified using high throughput AFM of an acrylate microarray

    E-Print Network [OSTI]

    Hook, Andrew L.

    Atomic force microscopy has been applied to an acrylate polymer microarray to achieve a full topographic characterisation. This process discovered a small number of hydro-responsive materials created from monomers with ...

  15. Hydro-Quebec Sustainable Development Action Plan 2009-2013 (Quebec, Canada)

    Broader source: Energy.gov [DOE]

    To meet the requirements set out in the Qubec governments Sustainable Development Strategy and strategy to ensure the occupancy and vitality of territories, Hydro-Qubec has established a...

  16. Bangor Hydro Electric Company- Residential and Small Commercial Heat Pump Program (Maine)

    Broader source: Energy.gov [DOE]

    Bangor Hydro Electric Company offers a two-tiered incentive program for residential and small commercial customers. Mini-Split Heat Pumps are eligible for a rebate of $600, as well as a loan to...

  17. DOE/RMOTC/05.98001 Hydro-Balanced Stuffing Box Field Test Field...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RMOTC05.98001 Hydro-Balanced Stuffing Box Field Test Field Test Project Report Date Published: May 28, 1999 Leo A. Giangiacomo, P.E. Rocky Mountain Oilfield Testing Center 907 N....

  18. Hydro-Qubec Distribution- Biomass- EAP 2011-1 (Quebec, Canada)

    Broader source: Energy.gov [DOE]

    Hydro-Qubec Distribution established a program for the purchase of 300 MW of electricity in Quebec from cogeneration based residual forest biomass. Each project is limited to a maximum of 50 MW....

  19. Operation of a steam hydro-gasifier in a fluidized bed reactor

    E-Print Network [OSTI]

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01T23:59:59.000Z

    GASIFIER IN A FLUIDIZED BED REACTOR Inventors: Joseph M .a steam hydro-gasification reactor (SHR) the carbonaceous0012] Fluidized bed reactors are well known and used in a

  20. BC Hydro Industrial Sector: Marketing Sector Marketing Plan (Fiscal 2005/Fiscal 2006)

    E-Print Network [OSTI]

    Willis, P.; Wallace, K.

    2005-01-01T23:59:59.000Z

    BC Hydro, the major electricity utility in the Province of British Columbia has been promoting industrial energy efficiency for more than 15 years. Recently it has launched a new Demand Side Management initiative with the objective of obtaining 2000...

  1. Volume reduction/solidification of liquid radioactive waste using bitumen at Ontario hydro`s Bruce nuclear generating station {open_quotes}A{close_quotes}

    SciTech Connect (OSTI)

    Day, J.E.; Baker, R.L. [ADTECHS Corporation, Herndon, VA (United States)

    1994-12-31T23:59:59.000Z

    Ontario Hydro at the Bruce Nuclear Generating Station {open_quotes}A{close_quotes} has undertaken a program to render the station`s liquid radioactive waste suitable for discharge to Lake Huron by removing sufficient radiological and chemical contaminants from five different plant waste streams. The contaminants will be immobilized and stored at on-site radioactive waste storage facilities and the purified streams will be discharged. The discharge targets established by Ontario Hydro are set well below the limits established by the Ontario Ministry of Environment (MOE) and are based on the Best Available Technology Economically Achievable Approach (B.A.T.E.A.). ADTECHS Corporation has been selected by Ontario Hydro to provide volume reduction/solidification technology for one of the five waste streams. The system will dry and immobilize the contaminants from a liquid waste stream in emulsified asphalt using thin film evaporation technology.

  2. Model of crack propagation in a clay soil

    E-Print Network [OSTI]

    Carriere, Patrick Edwidge

    1985-01-01T23:59:59.000Z

    in elevation of the soil surface were recorded over time of drying for each of the treatments. A logarithmic model to predict the crack depth, the crack width, and the drop in elevation of the soil surface expressed by the equation y = A + C*logt, was found... 2 MEANS procedure results for crack depth. 3 ANOVA results for crack depth. 19 29 30 4 Values of A and C obtained from linear regression analysis for crack depth. 35 5 Selection of combinations of independent variables for maximum R...

  3. Why Do Kraft Recovery Boiler Composite Floor Tubes Crack?

    SciTech Connect (OSTI)

    Keiser, J.R.

    2001-10-22T23:59:59.000Z

    Cracks were first reported in 1992 in co-extruded 304L stainless steel/SA210 Gd Al carbon steel floor tubes of North American black liquor recovery boilers. Since then, a considerable amount of information has been collected on the tube environment, crack characteristics, the stress state of the tubes, and the crack initiation and propagation mechanisms. These studies have identified both operating procedures that apparently can greatly lessen the likelihood of crack formation in the stainless steel layer and alternate materials that appear to be much more resistant to cracking than is 304L stainless.

  4. Effect of aging of the pillaring reagent on the microstructure and cracking activity of pillared clay

    SciTech Connect (OSTI)

    Harris, J.R. (Phillips Petroleum Company, Bartlesville, OK (USA))

    1987-08-01T23:59:59.000Z

    Pillared interlayer clay (PILC) is formed by exchanging large hydroxyaluminum polycations into the interlayer of a smectite clay such as montmorillonite, which is made up of sheet-like silica/alumina layers. Calcination of the exchanged clay gives a well dispersed array of metal oxide clumps (i.e., pillars) bonded top and bottom to the silica/alumina layers of the clay. The permanent separation of the clay layers gives an 8 to 10-fold increase in surface area, from 30 to 250-300 m{sup 2}/g, and a microporous structure similar to but less constrained than that of zeolites. Recently, there has been an increased interest in the use of these clays as cracking catalysts. For example, pillared clays have been shown to be an active cracking catalyst for both single component and gas oil feeds. PILC's also lead to both higher light cycle oil (LCO) and coke yields than conventional cracking catalysts. Commercially available, metal-hydrolyzed hydroxyaluminum solutions containing chlorhydrol, A1{sub 2}(OH){sub 5}C1.2H{sub 2}O, have been used as one source of the polycation solution. The approach of these hydrolyzed polycation solutions to equilibrium is known as aging. During the aging process certain polycationic species disappear from the solution and new species are formed. For this reason, the aging process can have a significant influence on the properties of the pillared clays. The objective of this work was to determine how the physical and catalytic properties of the pillared clay depend on the aging of dilute cholorhydrol solutions.

  5. Catalytic fast pyrolysis of lignocellulosic biomass

    SciTech Connect (OSTI)

    Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

    2014-11-21T23:59:59.000Z

    Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuelbio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

  6. Catalytic extraction processing of contaminated scrap metal

    SciTech Connect (OSTI)

    Griffin, T.P.; Johnston, J.E.; Payea, B.M.; Zeitoon, B.M.

    1995-12-01T23:59:59.000Z

    Molten Metal Technology was awarded a contract to demonstrate the applicability of the Catalytic Extraction Process, a proprietary process that could be applied to US DOE`s inventory of low level mixed waste. This paper is a description of that technology, and included within this document are discussions of: (1) Program objectives, (2) Overall technology review, (3) Organic feed conversion to synthetic gas, (4) Metal, halogen, and transuranic recovery, (5) Demonstrations, (6) Design of the prototype facility, and (7) Results.

  7. Preface: Challenges for Catalytic Exhaust Aftertreatment

    SciTech Connect (OSTI)

    Nova, Isabella; Epling, Bill; Peden, Charles HF

    2014-03-31T23:59:59.000Z

    This special issue of Catalysis Today continues the tradition established since the 18th NAM in Cancun, 2003, of publishing the highlights coming from these catalytic after-treatment technologies sessions, where this volume contains 18 papers based on oral and poster presentations of the 23rd NAM, 2013. The guest editors would like to thank all of the catalyst scientists and engineers who presented in the "Emission control" sessions, and especially the authors who contributed to this special issue of Catalysis Today.

  8. Soil cracking modelling using the mesh-free SPH method

    E-Print Network [OSTI]

    Bui, H H; Kodikara, J; Sanchez, M

    2015-01-01T23:59:59.000Z

    The presence of desiccation cracks in soils can significantly alter their mechanical and hydrological properties. In many circumstances, desiccation cracking in soils can cause significant damage to earthen or soil supported structures. For example, desiccation cracks can act as the preference path way for water flow, which can facilitate seepage flow causing internal erosion inside earth structures. Desiccation cracks can also trigger slope failures and landslides. Therefore, developing a computational procedure to predict desiccation cracking behaviour in soils is vital for dealing with key issues relevant to a range of applications in geotechnical and geo-environment engineering. In this paper, the smoothed particle hydrodynamics (SPH) method will be extended for the first time to simulate shrinkage-induced soil cracking. The main objective of this work is to examine the performance of the proposed numerical approach in simulating the strong discontinuity in material behaviour and to learn about the crack ...

  9. SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS

    SciTech Connect (OSTI)

    Klein, J; Jeffrey Holder, J

    2007-07-16T23:59:59.000Z

    Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

  10. Screening tests for improved methane cracking materials

    SciTech Connect (OSTI)

    Klein, J. E.; Hoelder, J. S. [Savannah River National Laboratory, Aiken, SC 29808 (United States)

    2008-07-15T23:59:59.000Z

    Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{sup R} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 deg.C, 101.3 kPa (760 torr) with a 10 seem feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAESr getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas. (authors)

  11. Process for magnetic beneficiating petroleum cracking catalyst

    DOE Patents [OSTI]

    Doctor, R.D.

    1993-10-05T23:59:59.000Z

    A process is described for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded. 1 figures.

  12. Process for magnetic beneficiating petroleum cracking catalyst

    DOE Patents [OSTI]

    Doctor, Richard D. (Lisle, IL)

    1993-01-01T23:59:59.000Z

    A process for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded.

  13. Circumferential cracking of steam generator tubes

    SciTech Connect (OSTI)

    Karwoski, K.J.

    1997-04-01T23:59:59.000Z

    On April 28, 1995, the U.S. Nuclear Regulatory Commission (NRC) issued Generic Letter (GL) 95-03, {open_quote}Circumferential Cracking of Steam Generator Tubes.{close_quote} GL 95-03 was issued to obtain information needed to verify licensee compliance with existing regulatory requirements regarding the integrity of steam generator tubes in domestic pressurized-water reactors (PWRs). This report briefly describes the design and function of domestic steam generators and summarizes the staff`s assessment of the responses to GL 95-03. The report concludes with several observations related to steam generator operating experience. This report is intended to be representative of significant operating experience pertaining to circumferential cracking of steam generator tubes from April 1995 through December 1996. Operating experience prior to April 1995 is discussed throughout the report, as necessary, for completeness.

  14. Congrs SHF : Environnement et Hydro-lectricit , Lyon,6 & 7 octobre 2010 Pigay, Aelbrecht, Beal RESTAURATION MORPHO-DYNAMIQUE ET

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Congrès SHF : « Environnement et Hydro-électricité », Lyon,6 & 7 octobre 2010 ­Piégay, Aelbrecht pour la protection contre les crues et la navigation, puis après la construction de barrages hydro deux projets est de définir un plan de restauration hydro-morphologique et écologique conduisant à la

  15. Structures for dense, crack free thin films

    DOE Patents [OSTI]

    Jacobson, Craig P. (Lafayette, CA); Visco, Steven J. (Berkeley, CA); De Jonghe, Lutgard C. (Lafayette, CA)

    2011-03-08T23:59:59.000Z

    The process described herein provides a simple and cost effective method for making crack free, high density thin ceramic film. The steps involve depositing a layer of a ceramic material on a porous or dense substrate. The deposited layer is compacted and then the resultant laminate is sintered to achieve a higher density than would have been possible without the pre-firing compaction step.

  16. Piloted rich-catalytic lean-burn hybrid combustor

    DOE Patents [OSTI]

    Newburry, Donald Maurice (Orlando, FL)

    2002-01-01T23:59:59.000Z

    A catalytic combustor assembly which includes, an air source, a fuel delivery means, a catalytic reactor assembly, a mixing chamber, and a means for igniting a fuel/air mixture. The catalytic reactor assembly is in fluid communication with the air source and fuel delivery means and has a fuel/air plenum which is coated with a catalytic material. The fuel/air plenum has cooling air conduits passing therethrough which have an upstream end. The upstream end of the cooling conduits is in fluid communication with the air source but not the fuel delivery means.

  17. Catalytic Consequences of Acid Strength in the Conversion of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Consequences of Acid Strength in the Conversion of Methanol to Dimethyl Ether. Catalytic Consequences of Acid Strength in the Conversion of Methanol to Dimethyl Ether. Abstract:...

  18. Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an individual catalytic nanoparticle while reactions are occurring. Catalysts are used in manufacturing everything from stain remover to rocket fuel; they make production more...

  19. Improved Low-Temperature Performance of Catalytic Converters...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalytic converters, installed on vehicles with internal combustion and diesel engines, convert the toxic byproducts of combustion to less toxic compounds. In two-way (lean...

  20. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13T23:59:59.000Z

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  1. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Broader source: Energy.gov (indexed) [DOE]

    the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

  2. The Effects of Trace Contaminants on Catalytic Processing of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processing of Biomass-Derived Feedstocks . Abstract: Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to...

  3. Hydro-Gravitational-Dynamics of Planets and Dark Energy

    E-Print Network [OSTI]

    Carl H. Gibson; Rudolph E. Schild

    2008-08-24T23:59:59.000Z

    Self-gravitational fluid mechanical methods termed hydro-gravitational-dynamics (HGD) predict plasma fragmentation 0.03 Myr after the turbulent big bang to form protosuperclustervoids, turbulent protosuperclusters, and protogalaxies at the 0.3 Myr transition from plasma to gas. Linear protogalaxyclusters fragment at 0.003 Mpc viscous-inertial scales along turbulent vortex lines or in spirals, as observed. The plasma protogalaxies fragment on transition into white-hot planet-mass gas clouds (PFPs) in million-solar-mass clumps (PGCs) that become globular-star-clusters (GCs) from tidal forces or dark matter (PGCs) by freezing and diffusion into 0.3 Mpc halos with 97% of the galaxy mass. The weakly collisional non-baryonic dark matter diffuses to > Mpc scales and frag-ments to form galaxy cluster halos. Stars and larger planets form by binary mergers of the trillion PFPs per PGC on 0.03 Mpc galaxy accretion disks. Star deaths depend on rates of planet accretion and internal star mixing. Moderate accretion rates produce white dwarfs that evaporate surrounding gas planets by spin-radiation to form planetary nebulae before Supernova Ia events, dimming some events to give systematic distance errors misinterpreted as the dark energy hypothesis and overestimates of the universe age. Failures of standard LCDM cosmological models reflect not only obsolete Jeans 1902 fluid mechanical assumptions, but also failures of standard turbulence models that claim the cascade of turbulent kinetic energy is from large scales to small. Because turbulence is always driven at all scales by inertial-vortex forces the turbulence cascade is always from small scales to large.

  4. Application of the cracked pipe element to creep crack growth prediction

    SciTech Connect (OSTI)

    Brochard, J.; Charras, T. [C.E.A.-C.E.-Saclay DRN/DMT, Gif Sur Yvette (France); Ghoudi, M. [C.E.A.-C.E.-Saclay, Gif Sur Yvette (France)

    1997-04-01T23:59:59.000Z

    Modifications to a computer code for ductile fracture assessment of piping systems with postulated circumferential through-wall cracks under static or dynamic loading are very briefly described. The modifications extend the capabilities of the CASTEM2000 code to the determination of fracture parameters under creep conditions. The main advantage of the approach is that thermal loads can be evaluated as secondary stresses. The code is applicable to piping systems for which crack propagation predictions differ significantly depending on whether thermal stresses are considered as primary or secondary stresses.

  5. Catalytic multi-stage liquefaction (CMSL)

    SciTech Connect (OSTI)

    Comolli, A.G.; Ganguli, P.; Karolkiewicz, W.F.; Lee, T.L.K.; Pradhan, V.R.; Popper, G.A.; Smith, T.; Stalzer, R.

    1996-11-01T23:59:59.000Z

    Under contract with the U.S. Department of Energy, Hydrocarbon Technologies, Inc. has conducted a series of eleven catalytic, multi-stage, liquefaction (CMSL) bench scale runs between February, 1991, and September, 1995. The purpose of these runs was to investigate novel approaches to liquefaction relating to feedstocks, hydrogen source, improved catalysts as well as processing variables, all of which are designed to lower the cost of producing coal-derived liquid products. This report summarizes the technical assessment of these runs, and in particular the evaluation of the economic impact of the results.

  6. Thin film porous membranes for catalytic sensors

    SciTech Connect (OSTI)

    Hughes, R.C.; Boyle, T.J.; Gardner, T.J. [and others

    1997-06-01T23:59:59.000Z

    This paper reports on new and surprising experimental data for catalytic film gas sensing resistors coated with nanoporous sol-gel films to impart selectivity and durability to the sensor structure. This work is the result of attempts to build selectivity and reactivity to the surface of a sensor by modifying it with a series of sol-gel layers. The initial sol-gel SiO{sub 2} layer applied to the sensor surprisingly showed enhanced O{sub 2} interaction with H{sub 2} and reduced susceptibility to poisons such as H{sub 2}S.

  7. Catalytic Solutions Inc CSI | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomassSustainableCSLInformationMissouri:Catalyst Regeneration MarketCatalytic

  8. BioCatalytics | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,Belcher Homes JumpMaintenance |BigBigLakeBioCatalytics

  9. CYCLIC PLASTICITY OF A CRACKED STRUCTURE SUBJECTED TO MIXED MODE LOADING

    E-Print Network [OSTI]

    CYCLIC PLASTICITY OF A CRACKED STRUCTURE SUBJECTED TO MIXED MODE LOADING Sylvie Pommier1, a 1 LMT, mixed mode crack propagation, plasticity, crack deflection. Abstract. Cyclic plasticity in the crack tip stresses in the overload's plastic zone. Moreover, if the overload's ratio is large enough, the crack may

  10. amplitude fatigue crack: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rate testing to evaluate the susceptibility of metallic materials to environmentally assisted cracking CERN Preprints Summary: 1.1 This practice covers procedures for the design,...

  11. assisted cracking resistance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    video system, crack initiation, propagation, and ... Miller, James Thomas, Ph. D. Massachusetts Institute of Technology 2008-01-01 36 Dynamic fracture of compositionally...

  12. alligator cracking: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    video system, crack initiation, propagation, and ... Miller, James Thomas, Ph. D. Massachusetts Institute of Technology 2008-01-01 40 A new alligator-clip compound for...

  13. P wave anisotropy, stress, and crack distribution at Coso geothermal...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: P wave anisotropy, stress, and crack distribution at Coso geothermal field, California...

  14. High-Resolution Crack Imaging Reveals Degradation Processes in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reveals Degradation Processes in Nuclear Reactor Structural Materials. Abstract: Corrosion and cracking represent critical failure mechanisms for structural materials in many...

  15. Tribological Analysis of White Etching Crack (WEC) Failures in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Crack (WEC) Failures in Rolling Element Bearings Presented by Arnaud Ruellan, INSA de Lyon at the Wind Turbine Tribology Seminar 2014. 20141030NREL2014ArgonneRuellancomV...

  16. NORTHWESTERN UNIVERSITY Qualification of Autonomous Crack Monitoring Systems

    E-Print Network [OSTI]

    NORTHWESTERN UNIVERSITY Qualification of Autonomous Crack Monitoring Systems A Thesis Submitted Term or Static Testing Equipment Setup.............................................29 Long Term Response.....................................................................33 Dynamic Testing Equipment

  17. Catalytic reactor for low-Btu fuels

    DOE Patents [OSTI]

    Smith, Lance (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Karim, Hasan (Simpsonville, SC); Pfefferle, William C. (Madison, CT)

    2009-04-21T23:59:59.000Z

    An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

  18. Development of HydroImage, A User Friendly Hydrogeophysical Characterization Software

    SciTech Connect (OSTI)

    Mok, Chin Man [GSI Environmental] [GSI Environmental; Hubbard, Susan [Lawrence Berkeley National Laboratory] [Lawrence Berkeley National Laboratory; Chen, Jinsong [Lawrence Berkeley National Laboratory] [Lawrence Berkeley National Laboratory; Suribhatla, Raghu [AMEC E& I] [AMEC E& I; Kaback, Dawn Samara [AMEC E& I] [AMEC E& I

    2014-01-29T23:59:59.000Z

    HydroImage, user friendly software that utilizes high-resolution geophysical data for estimating hydrogeological parameters in subsurface strate, was developed under this grant. HydroImage runs on a personal computer platform to promote broad use by hydrogeologists to further understanding of subsurface processes that govern contaminant fate, transport, and remediation. The unique software provides estimates of hydrogeological properties over continuous volumes of the subsurface, whereas previous approaches only allow estimation of point locations. thus, this unique tool can be used to significantly enhance site conceptual models and improve design and operation of remediation systems. The HydroImage technical approach uses statistical models to integrate geophysical data with borehole geological data and hydrological measurements to produce hydrogeological parameter estimates as 2-D or 3-D images.

  19. Abstract-Coal and hydro will be the main sources of electric energy in Chile for the near future, given that natural gas

    E-Print Network [OSTI]

    Dixon, Juan

    Abstract- Coal and hydro will be the main sources of electric energy in Chile for the near future and the environmental dilemma faced by the country, where both coal and hydro produce some kind of impact. The role

  20. Catalytic cracking of n-Dodecane and Alkyl benzenes over FCC Zeolite Catalysts: Time on Stream and Reactant Converted Models

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    hydrocarbon model compounds (n-dodecane, 1,3,5- triisopropylbenzene, and 1,4-diisopropylbenzene) has been investigated over two FCC zeolite catalysts in a novel riser simulator that resembles closely the operating compounds. This can be due to the smaller ZSM-5 pore diameter (in the range of 5-6 ) that restricts alkyl

  1. Crack opening area estimates in pressurized through-wall cracked elbows under bending

    SciTech Connect (OSTI)

    Franco, C.; Gilles, P.; Pignol, M.

    1997-04-01T23:59:59.000Z

    One of the most important aspects in the leak-before-break approach is the estimation of the crack opening area corresponding to potential through-wall cracks at critical locations during plant operation. In order to provide a reasonable lower bound to the leak area under such loading conditions, numerous experimental and numerical programs have been developed in USA, U.K. and FRG and widely discussed in literature. This paper aims to extend these investigations on a class of pipe elbows characteristic of PWR main coolant piping. The paper is divided in three main parts. First, a new simplified estimation scheme for leakage area is described, based on the reference stress method. This approach mainly developed in U.K. and more recently in France provides a convenient way to account for the non-linear behavior of the material. Second, the method is carried out for circumferential through-wall cracks located in PWR elbows subjected to internal pressure. Finite element crack area results are presented and comparisons are made with our predictions. Finally, in the third part, the discussion is extended to elbows under combined pressure and in plane bending moment.

  2. Cracking in reinforced concrete bent caps

    E-Print Network [OSTI]

    Young, Bradley S.

    2000-01-01T23:59:59.000Z

    ) . . . . . . . . . . . . . . . . 4. 2 Group It2 Response (Specimens 3C, 3D, 4C, 4E, 5D, 5E) . . . 4. 3 Group tt3 Response (Specimens 6F, 6G, 7F, 7H, 8G, 8H) . . . 4. 4 General Response 4. 5 Sununary. . . . . 49 . . . . 58 . . . . 64 70 . . . 75 5. STRUT-AND-TIE MODELING... be expressed as the product of the steel strain (s, ) at that level multiplied by the crack spacing (s, ); 20 w =z*s C S C (2. 6) a linear strain gradient can be used to project the maximum strain occurring at the level of the flexural reinforcement...

  3. 3:2:1 Crack Spread

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 Oil demand8)Commercial5 1:2:1 Crack

  4. Ability of Catalytic Converters to Reduce Air Pollution

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    NOx - 1 Ability of Catalytic Converters to Reduce Air Pollution MEASUREMENT OF SELECTED AIR POLLUTANTS IN CAR EXHAUST Last updated: June 17, 2014 #12;NOx - 2 Ability of Catalytic Converters to Reduce Air Pollution MEASUREMENT OF SELECTED AIR POLLUTANTS IN CAR EXHAUST INTRODUCTION Automobile engines

  5. Proposition de sujet de Thse de Doctorat Caractrisation multi chelle des proprits hydro-go-physiques des

    E-Print Network [OSTI]

    Naud Frédéric

    Proposition de sujet de Thèse de Doctorat Caractérisation multi échelle des propriétés hydro structurales et ainsi développer des méthodologies d'acquisition hydro-géo-physique en ce milieu complexe

  6. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power

    SciTech Connect (OSTI)

    Milbrandt, A.; Mann, M.

    2009-02-01T23:59:59.000Z

    This paper estimates the quantity of hydrogen that could be produced from coal, natural gas, nuclear, and hydro power by county in the United States. The study estimates that more than 72 million tonnes of hydrogen can be produced from coal, natural gas, nuclear, and hydro power per year in the country (considering only 30% of their total annual production). The United States consumed about 396 million tonnes of gasoline in 2007; therefore, the report suggests the amount of hydrogen from these sources could displace about 80% of this consumption.

  7. A Hydro-mechanical Model and Analytical Solutions for Geomechanical Modeling of Carbon Dioxide Geological Sequestration

    SciTech Connect (OSTI)

    Xu, Zhijie; Fang, Yilin; Scheibe, Timothy D.; Bonneville, Alain

    2012-05-15T23:59:59.000Z

    We present a hydro-mechanical model for geological sequestration of carbon dioxide. The model considers the poroelastic effects by taking into account the coupling between the geomechanical response and the fluid flow in greater detail. The simplified hydro-mechanical model includes the geomechanical part that relies on the linear elasticity, while the fluid flow is based on the Darcys law. Two parts were coupled using the standard linear poroelasticity. Analytical solutions for pressure field were obtained for a typical geological sequestration scenario. The model predicts the temporal and spatial variation of pressure field and effects of permeability and elastic modulus of formation on the fluid pressure distribution.

  8. Integrated Biomass Gasification with Catalytic Partial Oxidation for Selective Tar Conversion

    SciTech Connect (OSTI)

    Zhang, Lingzhi; Wei, Wei; Manke, Jeff; Vazquez, Arturo; Thompson, Jeff; Thompson, Mark

    2011-05-28T23:59:59.000Z

    Biomass gasification is a flexible and efficient way of utilizing widely available domestic renewable resources. Syngas from biomass has the potential for biofuels production, which will enhance energy security and environmental benefits. Additionally, with the successful development of low Btu fuel engines (e.g. GE Jenbacher engines), syngas from biomass can be efficiently used for power/heat co-generation. However, biomass gasification has not been widely commercialized because of a number of technical/economic issues related to gasifier design and syngas cleanup. Biomass gasification, due to its scale limitation, cannot afford to use pure oxygen as the gasification agent that used in coal gasification. Because, it uses air instead of oxygen, the biomass gasification temperature is much lower than well-understood coal gasification. The low temperature leads to a lot of tar formation and the tar can gum up the downstream equipment. Thus, the biomass gasification tar removal is a critical technology challenge for all types of biomass gasifiers. This USDA/DOE funded program (award number: DE-FG36-O8GO18085) aims to develop an advanced catalytic tar conversion system that can economically and efficiently convert tar into useful light gases (such as syngas) for downstream fuel synthesis or power generation. This program has been executed by GE Global Research in Irvine, CA, in collaboration with Professor Lanny Schmidt's group at the University of Minnesota (UoMn). Biomass gasification produces a raw syngas stream containing H2, CO, CO2, H2O, CH4 and other hydrocarbons, tars, char, and ash. Tars are defined as organic compounds that are condensable at room temperature and are assumed to be largely aromatic. Downstream units in biomass gasification such as gas engine, turbine or fuel synthesis reactors require stringent control in syngas quality, especially tar content to avoid plugging (gum) of downstream equipment. Tar- and ash-free syngas streams are a critical requirement for commercial deployment of biomass-based power/heat co-generation and biofuels production. There are several commonly used syngas clean-up technologies: (1) Syngas cooling and water scrubbing has been commercially proven but efficiency is low and it is only effective at small scales. This route is accompanied with troublesome wastewater treatment. (2) The tar filtration method requires frequent filter replacement and solid residue treatment, leading to high operation and capital costs. (3) Thermal destruction typically operates at temperatures higher than 1000oC. It has slow kinetics and potential soot formation issues. The system is expensive and materials are not reliable at high temperatures. (4) In-bed cracking catalysts show rapid deactivation, with durability to be demonstrated. (5) External catalytic cracking or steam reforming has low thermal efficiency and is faced with problematic catalyst coking. Under this program, catalytic partial oxidation (CPO) is being evaluated for syngas tar clean-up in biomass gasification. The CPO reaction is exothermic, implying that no external heat is needed and the system is of high thermal efficiency. CPO is capable of processing large gas volume, indicating a very compact catalyst bed and a low reactor cost. Instead of traditional physical removal of tar, the CPO concept converts tar into useful light gases (eg. CO, H2, CH4). This eliminates waste treatment and disposal requirements. All those advantages make the CPO catalytic tar conversion system a viable solution for biomass gasification downstream gas clean-up. This program was conducted from October 1 2008 to February 28 2011 and divided into five major tasks. - Task A: Perform conceptual design and conduct preliminary system and economic analysis (Q1 2009 ~ Q2 2009) - Task B: Biomass gasification tests, product characterization, and CPO tar conversion catalyst preparation. This task will be conducted after completing process design and system economics analysis. Major milestones include identification of syngas cleaning requirements for proposed system

  9. A nanomechanical investigation of the crack tip process zone of marble

    E-Print Network [OSTI]

    Brooks, Zenzile (Zenzile Z.)

    2010-01-01T23:59:59.000Z

    This study explores the interaction between crack initiation and nanomechanical properties in the crack tip process zone (zone of microcracking at the tip of a propagating crack) of a brittle geomaterial. Samples of Carrara ...

  10. The displacement field characterization of two interacting parallel edge cracks in a finite body

    E-Print Network [OSTI]

    Keener, Todd Whitney

    1996-01-01T23:59:59.000Z

    The goals of this research were to: (1) develop a model to represent the displacement field surrounding two interacting, parallel edge cracks; and (2) use this model to investigate the influence of crack separation and relative crack length...

  11. Hydro-climatology: Variability and Change (Proceedings of symposium J-H02 held during IUGG2011 in Melbourne, Australia, July 2011) (IAHS Publ. 344, 2011).

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Hydro-climatology: Variability and Change (Proceedings of symposium J-H02 held during IUGG2011 in Melbourne, Australia, July 2011) (IAHS Publ. 344, 2011). Copyright © 2011 IAHS Press 195 How could hydro , L. COLLET2 , S. ARDOIN-BARDIN3 & P. ROUCOU4 1 CNRS, 2 UM2, 3 IRD ­ UMR HydroSciences Montpellier

  12. Operational hydro-meteorological warning and real-time flood forecasting:the Piemonte region case study Hydrology and Earth System Sciences, 9(4), 457466 (2005) EGU

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Operational hydro-meteorological warning and real-time flood forecasting:the Piemonte region case study 457 Hydrology and Earth System Sciences, 9(4), 457466 (2005) © EGU Operational hydro forecasting system in the context of the Piemonte Regions hydro-meteorological operational alert procedure

  13. Eco-Hydro-Climate Science/Engineering in SESE Definition: An emerging frontier in Earth system science is the interaction of ecological,

    E-Print Network [OSTI]

    Rhoads, James

    Eco-Hydro-Climate Science/Engineering in SESE Definition: An emerging frontier in Earth system that are `retooled' to treat the coupled eco-hydro-climate system. Arid and semiarid regions (deserts) are a fruitful Southwest is thus an ideal laboratory for eco-hydro-climate studies and provides several case studies

  14. A FULLY COUPLED THERMO-HYDRO MECHANICAL ANALYSIS OF THE IMPACT OF TEMPERATURE AND HUMIDITY VARIATION ON THE STATE OF HISTORICAL STONE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A FULLY COUPLED THERMO-HYDRO MECHANICAL ANALYSIS OF THE IMPACT OF TEMPERATURE AND HUMIDITY Keywords: Thermo-hydro-mechanical coupling, modelling, inverse problem, tuffeau, monument, in situ measures initiation and growth due to the variation of climate conditions; thermo-hydro-mechanical incompatibility

  15. Toward hydro-social modeling: Merging human variables and the social sciences with climate-glacier runoff models (Santa River, Peru)

    E-Print Network [OSTI]

    McKenzie, Jeffrey M.

    Toward hydro-social modeling: Merging human variables and the social sciences with climate mountain range, this paper provides a holistic hydro-social framework that identifies five major human of watershed dynamics. This hydro-social framework has wide- spread implications for hydrological modeling

  16. Virtues of simple hydro-economic optimization: Baja California, Mexico J. Medellin-Azuara a,*, L.G. Mendoza-Espinosa b

    E-Print Network [OSTI]

    Pasternack, Gregory B.

    Virtues of simple hydro-economic optimization: Baja California, Mexico J. Medelli´n-Azuara a,*, L in revised form 1 May 2009 Accepted 22 May 2009 Available online 26 June 2009 Keywords: Hydro-economic models simple hydro-economic optimization to investigate a wide range of regional water system management

  17. Long-term evaluation of the Hydro-Thermodynamic Soil-Vegetation Scheme's frozen ground/permafrost component using observations at

    E-Print Network [OSTI]

    Moelders, Nicole

    Long-term evaluation of the Hydro-Thermodynamic Soil-Vegetation Scheme's frozen ground/permafrost component of the hydro-thermodynamic soil-vegetation scheme (HTSVS) was evaluated by means of permafrost computational time. Citation: Mo¨lders, N., and V. E. Romanovsky (2006), Long-term evaluation of the Hydro

  18. Preparation and characterization of VOx/TiO2 catalytic coatings on stainless steel plates for structured catalytic reactors.

    E-Print Network [OSTI]

    Boyer, Edmond

    for structured catalytic reactors. Thierry Giornelli, Axel Löfberg* and Elisabeth Bordes-Richard Unité de.Lofberg@univ-lille1.fr Abstract The parameters to be controlled to coat metallic walls by VOx/TiO2 catalysts which) was chosen because of its large application in industrial catalytic reactors. TiO2 films on stainless steel

  19. Field Manual for Crack Sealing in Asphalt Pavements

    E-Print Network [OSTI]

    Texas at Austin, University of

    Field Manual for Crack Sealing in Asphalt Pavements Yetkin Yildirim, Ahmed Qatan, and Jorge Prozzi January 2006 3208RedRiver Austin,TX78705 #12;Dr. Yetkin Yildirim, P.E. Director Texas Pavement for Crack Sealing in Asphalt Pavements #12;Performing Organization: Center for Transportation Research

  20. NORTHWESTERN UNIVERSITY Crack Response to Weather Effects, Blasting, and Construction

    E-Print Network [OSTI]

    NORTHWESTERN UNIVERSITY Crack Response to Weather Effects, Blasting, and Construction Vibrations Acknowledgements iii Abstract iv List of Figures v List of Tables xi Chapter 1- Introduction 1 Chapter 2- Blast Vibration Response, Southbury, Connecticut 5 Structural Description Instrumentation Blast Response Crack

  1. Crack-based analysis of concrete with brittle reinforcement

    E-Print Network [OSTI]

    Burgoyne, Chris

    { FaberMaunsell Ltd; University of Cambridge Brittle reinforcement (such as fibre-reinforced plastic to the surround- ing concrete, at a crack surface sL=sR s on the left/right side of a crack u increase in unbonded

  2. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27T23:59:59.000Z

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  3. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20T23:59:59.000Z

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  4. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1984-01-01T23:59:59.000Z

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  5. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1985-01-01T23:59:59.000Z

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  6. Catalytic cartridge SO/sub 3/ decomposer

    DOE Patents [OSTI]

    Galloway, T.R.

    1980-11-18T23:59:59.000Z

    A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO/sub 3/ decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO/sub 3/ gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO/sub 3/ gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety. A fusion reactor may be used as the heat source.

  7. Catalytic carbon membranes for hydrogen production

    SciTech Connect (OSTI)

    Damle, A.S.; Gangwal, S.K.

    1992-01-01T23:59:59.000Z

    Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC)

  8. Experimental Verification of a Cracked Fuel Mechanical Model

    SciTech Connect (OSTI)

    Williford, R. E.

    1982-12-01T23:59:59.000Z

    This report describes the results of a series of laboratory experiments conducted to independently verify a model that describes the nonlinear mechanical behavior of cracked fuel in pelletized UO{sub 2}/Zircaloy nuclear fuel rods under normal operating conditions. After a brief description of the analytical model, each experiment is discussed in detail. Experiments were conducted to verify the general behavior and numerical values for the three primary independent modelling parameters (effective crack roughness, effective gap roughness, and total crack length), and to verify the model predictions that the effective Young's moduli for cracked fuel systems were substantially less than those for solid UO{sub 2} pellets. In general, the model parameters and predictions were confirmed, and new insight was gained concerning the complexities of cracked fuel mechanics.

  9. SciTech Connect: Stress corrosion cracking of alloy 600 using...

    Office of Scientific and Technical Information (OSTI)

    Stress corrosion cracking of alloy 600 using the constant strain rate test Citation Details In-Document Search Title: Stress corrosion cracking of alloy 600 using the constant...

  10. A Crack in the Pipeline: Why Female Underrepresented Racial Minority Students Leave Engineering

    E-Print Network [OSTI]

    Vazquez-Akim, Jenn

    2014-01-01T23:59:59.000Z

    Espinosa, Lorelle L. (2011). Pipelines and pathways: womenAngeles A Crack in the Pipeline: Why Female UnderrepresentedA Crack in the Pipeline: Why Female Underrepresented Racial

  11. Geek-Up[04.01.2011]: Charting Wind, Thermal, Hydro Generation

    Broader source: Energy.gov [DOE]

    Check out Bonneville Power Administrations new near real-time energy monitoring it displays the output of all wind, thermal and hydro generation in the agencys balancing authority against its load. Updated every five minutes, its a great resource for universities, research laboratories and other utilities.

  12. An Integrated Approach for Optimal Coordination of Wind Power and Hydro Pumping Storage

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    of hydro storage used and the market characteristics and several options are compared in this study is the down regulation price in the electricity market paid to put in operation reserves to decrease generation at interval i; downreg ip^ is the down regulation price forecasted at period i during the intraday

  13. Hydro-Mechanical Loading and Compressibility of Fibrous Media for Resin Infusion Processes

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    1 Hydro-Mechanical Loading and Compressibility of Fibrous Media for Resin Infusion Processes P investigating the compressibility behaviour of composite preform with a view of modelling resin infusion Infusion The need for manufacturing large composite parts in the aeronautic industry is ever increasing

  14. EIS-0141: Washington Water Power/B.C. Hydro Transmission Interconnection Project

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate the environmental impacts of constructing and operating a double-circuit 230-kilovolt electrical transmission line that would link the electrical systems of the Washington Water Power Company and the British Columbia Hydro and Power Authority.

  15. Hydro: A Hybrid Routing Protocol for Low-Power and Lossy Networks

    E-Print Network [OSTI]

    California at Berkeley, University of

    1 Hydro: A Hybrid Routing Protocol for Low-Power and Lossy Networks Stephen Dawson-based traffic, or optimize for point-to-point traffic in a homogeneous network. As these networks become more by the resource constraints of low-power and lossy networks (L2Ns). Our design leverages the predominantly two

  16. A model for dynamic chance constraints in hydro power reservoir management

    E-Print Network [OSTI]

    Rmisch, Werner

    A model for dynamic chance constraints in hydro power reservoir management L. Andrieu , R. Henrion In this paper, a model for (joint) dynamic chance constraints is proposed and ap- plied to an optimization for two and three stages. 1 Introduction A conventional optimization problem under chance constraints

  17. Hydro International Corals and Water Column Study for Gulf Oil Spill Response

    E-Print Network [OSTI]

    Belogay, Eugene A.

    of NOAA's response to the Deepwater Horizon/BP oil spill. "This is a major catastrophe," said Nelson of Mexico to gather baseline data against which to measure change if oil from the Deepwater Horizon spillHydro International Corals and Water Column Study for Gulf Oil Spill Response 14/07/2010 A science

  18. Heat transfer rates in fixed bed catalytic reactors

    E-Print Network [OSTI]

    Levelton, Bruce Harding

    1951-01-01T23:59:59.000Z

    HEAT TRANSFER RATES IN FIXED BED CATALYTIC REACTORS H EATTRNSFSAIX DB DNCLR YFNOAXa rRJRuSIX nSeR 1951i HssNIJFu FT SI TSBuR FXO LIXSRXS NRLIeeRXOROt HEAT TRANSFER RATES IN FIXED BED CATALYTIC REACTORS H EATTRNSFSAIX BSar DNCLR YFNOAXa r...RJRuSIX June 1951 HEAT TRANSFER RATES IN FIXED BED CATALYTIC REACTORS A Dissertation Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  19. Sequential tasks performed by catalytic pumps for colloidal crystallization

    E-Print Network [OSTI]

    Ali Afshar Farniya; Maria J. Esplandiu; Adrian Bachtold

    2014-10-20T23:59:59.000Z

    Gold-platinum catalytic pumps immersed in a chemical fuel are used to manipulate silica colloids. The manipulation relies on the electric field and the fluid flow generated by the pump. Catalytic pumps perform various tasks, such as the repulsion of colloids, the attraction of colloids, and the guided crystallization of colloids. We demonstrate that catalytic pumps can execute these tasks sequentially over time. Switching from one task to the next is related to the local change of the proton concentration, which modifies the colloid zeta potential and consequently the electric force acting on the colloids.

  20. Implications of early stages in the growth of stress corrosion cracking on component reliability

    SciTech Connect (OSTI)

    Jones, R.H.; Simonen, E.P.

    1995-04-01T23:59:59.000Z

    Environment-induced crack growth generally progresses through several stages prior to component failure. Crack initiation, short crack growth, and stage 1 growth are early stages in crack development that are summarized in this paper. The implications of these stages on component reliability, derive from the extended time that the crack exists in the early stages because crack velocity is slow. The duration of the early stages provides a greater opportunity for corrective action if cracks can be detected. Several important factors about the value of understanding short crack behavior include: (1) life prediction requires a knowledge of the total life cycle of the crack including the early stages, (2) greater reliability is possible if the transition between short and long crack behavior is known component life after this transition is short and (3) remedial actions are more effective for short than long cracks.

  1. Reliability of steam generator tubes with axial cracks

    SciTech Connect (OSTI)

    Cizelj, L.; Mavko, B. [Jozef Stefan Inst., Ljubljana (Slovenia). Reactor Engineering Div.; Vencelj, P. [Univ. of Ljubljana (Slovenia). Faculty of Mathematics and Physics

    1996-11-01T23:59:59.000Z

    An approach for estimating the failure probability of tubes containing through-wall axial cracks has already been proposed by the authors. It is based on probabilistic fracture mechanics and accounts for scatter in tube geometry and material properties, scatter in residual and operational stresses responsible for crack propagation, and characteristics of nondestructive examination and plugging procedures (e.g., detection probability, sizing accuracy, human errors). Results of preliminary tests demonstrated wide applicability of this approach and triggered some improvements. The additions to the model are extensively discussed in this paper. Capabilities are demonstrated by results of analysis of steam generator no. 1 in Slovenian nuclear power plant located in Krsko after the 1992 inspection and plugging campaign. First, the number of cracked tubes and the crack length distribution were estimated using data obtained by the 100% motorized pancake coil inspection. The inspection and plugging activities were simulated in the second step to estimate the efficiency of maintenance in terms of single and multiple-tube rupture probabilities. They were calculated as a function of maximum allowable crack length. The importance of human errors and some limitations of present nondestructive examination techniques were identified. The traditional wall thickness and crack-length-based plugging criteria are compared. The crack-length-based criterion is shown to be more efficient and more safe, especially because of strong suppression effect on probability of multiple-tube rupture. The results are considered to be important for safety and maintenance of existing plants and for further research.

  2. Standard test method for creep-fatigue crack growth testing

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01T23:59:59.000Z

    1.1 This test method covers the determination of creep-fatigue crack growth properties of nominally homogeneous materials by use of pre-cracked compact type, C(T), test specimens subjected to uniaxial cyclic forces. It concerns fatigue cycling with sufficiently long loading/unloading rates or hold-times, or both, to cause creep deformation at the crack tip and the creep deformation be responsible for enhanced crack growth per loading cycle. It is intended as a guide for creep-fatigue testing performed in support of such activities as materials research and development, mechanical design, process and quality control, product performance, and failure analysis. Therefore, this method requires testing of at least two specimens that yield overlapping crack growth rate data. The cyclic conditions responsible for creep-fatigue deformation and enhanced crack growth vary with material and with temperature for a given material. The effects of environment such as time-dependent oxidation in enhancing the crack growth ra...

  3. La dynamique de communication entre Hydro-Qubec et les Innus dans le cadre du projet de la Romaine

    E-Print Network [OSTI]

    La dynamique de communication entre Hydro-Québec et les Innus dans le cadre du projet de la Romaine Fortin, 2014 #12;#12;iii Résumé Le mémoire porte sur la dynamique de communication entre Hydro-Québec et, composées dInnus et de représentants dHydro-Québec, et dont le rôle est de gérer les fonds. De plus, le

  4. Control of Substrate Access to the Active Site and Catalytic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control of Substrate Access to the Active Site and Catalytic Mechanism of Methane and Toluene Monooxygenases Friday, June 22, 2012 - 3:30pm SSRL Main Conference Room 137-322 Prof....

  5. Hydrogen permeable protective coating for a catalytic surface

    DOE Patents [OSTI]

    Liu, Ping (Irvine, CA); Tracy, C. Edwin (Golen, CO); Pitts, J. Roland (Lakewood, CO); Lee, Se-Hee (Lakewood, CO)

    2007-06-19T23:59:59.000Z

    A protective coating for a surface comprising a layer permeable to hydrogen, said coating being deposited on a catalyst layer; wherein the catalytic activity of the catalyst layer is preserved.

  6. Emerging catalytic processes for the production of adipic acid

    E-Print Network [OSTI]

    Van de Vyver, Stijn

    Research efforts to find more sustainable pathways for the synthesis of adipic acid have led to the introduction of new catalytic processes for producing this commodity chemical from alternative resources. With a focus on ...

  7. Catalytic H2O2 decomposition on palladium surfaces

    E-Print Network [OSTI]

    Salinas, S. Adriana

    1998-01-01T23:59:59.000Z

    The catalytic decomposition of H?O? at smooth single-crystal and polycrystalline palladium surfaces that had been subjected to various surface modifications has been studied. Monolayer and submonolayer coverages of I, Br and Cl adsorbates were used...

  8. An Energy Analysis of the Catalytic Combustion Burner

    E-Print Network [OSTI]

    Dong, Q.; Zhang, S.; Duan, Z.; Zhou, Q.

    2006-01-01T23:59:59.000Z

    The gas boilers of conventional flame always produce varying degrees of combustion products NOx and CO, which pollute the environment and waste energy. As a new way of combustion, catalytic combustion breaks the flammable limits of conventional...

  9. In situ XAS Characterization of Catalytic Nano-Materials with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    XAS Characterization of Catalytic Nano-Materials with Applications to Fuel Cells and Batteries Friday, July 12, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Qingying...

  10. atp catalytic domain: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 328 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  11. acidic multimetallic catalytic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 106 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  12. automobile catalytic converters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Odei 2006-01-01 408 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  13. atp catalytic cycle: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 275 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  14. advanced catalytic hydrogenation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 188 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  15. apparent catalytic site: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 257 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  16. advanced catalytic materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 225 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  17. acrylamide catalytically inhibits: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 78 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  18. assisted catalytic oxidation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 251 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  19. active catalytic sites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 337 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  20. atpase catalytic domain: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 266 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  1. advanced catalytic materials 1996: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 467 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  2. archaeal primase catalytic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 92 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  3. advanced catalytic science: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 488 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  4. Catalytic studies of supported Pd-Au catalysts

    E-Print Network [OSTI]

    Boopalachandran, Praveenkumar

    2006-08-16T23:59:59.000Z

    Although Pd-Au high-surface area catalysts are used in industry to improve activity and selectivity, a thorough understanding of the nature of these enhancements is lacking. A molecular-level understanding of catalytic ...

  5. Catalytic Membrane Reactor for Extraction of Hydrogen from Bioethanol Reforming

    E-Print Network [OSTI]

    Kuncharam, Bhanu Vardhan

    2013-11-26T23:59:59.000Z

    This research explores a novel application of catalytic membrane reactors for high- purity hydrogen extraction from bioethanol reforming. Conventional membrane systems employ hydrogen permselective materials such as palladium, polymer membranes...

  6. Prediction of thermal reflection cracking in west Texas

    E-Print Network [OSTI]

    Chang, Hang-Sun

    1975-01-01T23:59:59.000Z

    for the stress intensity factor, Ck, following Barenblatt (53) is used. z 'e(')4' C = ? / k n o (3-11) where C is the distance away from crack tip and o (g) is the surface e stress inside the crack tip element, i. e. ? o is the thermal stress at the depth... of the studies being conducted on pavement temp- erature cracking have been mainly concerned with the fracture suscepti- bilityy of asphalt concrete under extremely low temperature (3, 4). Find- ings of these studies could not provide satisfactory...

  7. Northwestern University Facility for Clean Catalytic Process Research

    SciTech Connect (OSTI)

    Marks, Tobin Jay [Northwestern University

    2013-05-08T23:59:59.000Z

    Northwestern University with DOE support created a Facility for Clean Catalytic Process Research. This facility is designed to further strengthen our already strong catalysis research capabilities and thus to address these National challenges. Thus, state-of-the art instrumentation and experimentation facility was commissioned to add far greater breadth, depth, and throughput to our ability to invent, test, and understand catalysts and catalytic processes, hence to improve them via knowledge-based design and evaluation approaches.

  8. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Jones, S.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

  9. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christpher P; Boldingh, Edwin P

    2013-12-17T23:59:59.000Z

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  10. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christopher P; Boldingh, Edwin P

    2014-10-07T23:59:59.000Z

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  11. Microchannel Reactor System for Catalytic Hydrogenation

    SciTech Connect (OSTI)

    Adeniyi Lawal; Woo Lee; Ron Besser; Donald Kientzler; Luke Achenie

    2010-12-22T23:59:59.000Z

    We successfully demonstrated a novel process intensification concept enabled by the development of microchannel reactors, for energy efficient catalytic hydrogenation reactions at moderate temperature, and pressure, and low solvent levels. We designed, fabricated, evaluated, and optimized a laboratory-scale microchannel reactor system for hydrogenation of onitroanisole and a proprietary BMS molecule. In the second phase of the program, as a prelude to full-scale commercialization, we designed and developed a fully-automated skid-mounted multichannel microreactor pilot plant system for multiphase reactions. The system is capable of processing 1 10 kg/h of liquid substrate, and an industrially relevant immiscible liquid-liquid was successfully demonstrated on the system. Our microreactor-based pilot plant is one-of-akind. We anticipate that this process intensification concept, if successfully demonstrated, will provide a paradigm-changing basis for replacing existing energy inefficient, cost ineffective, environmentally detrimental slurry semi-batch reactor-based manufacturing practiced in the pharmaceutical and fine chemicals industries.

  12. PLASMA Approximate Dynamic Programming finally cracks the locomotive optimization problem

    E-Print Network [OSTI]

    Powell, Warren B.

    PLASMA ­ Approximate Dynamic Programming finally cracks the locomotive optimization problem schedules and new operating policies. PLASMA is currently running at Norfolk Southern for strategic of PLASMA: Each locomotive is modeled individually, making it possible to capture both horsepower

  13. Automated crack control analysis for concrete pavement construction

    E-Print Network [OSTI]

    Jang, Se Hoon

    2005-11-01T23:59:59.000Z

    The focus of this research is on the control of random cracking in concrete paving by using sawcut notch locations in the early stages of construction. This is a major concern in concrete pavement construction. This research also addresses a...

  14. Shear-wave splitting and reservoir crack characterization: the...

    Open Energy Info (EERE)

    Shear-wave splitting and reservoir crack characterization: the Coso geothermal field Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Shear-wave...

  15. Climate change: A crack in the natural-gas bridge

    E-Print Network [OSTI]

    Davis, SJ; Shearer, C

    2014-01-01T23:59:59.000Z

    J. D. & Wirth, T. E. Natural Gas: A Bridge Fuel for the 21stexpanding supplies of natural gas will not help us to avoidLIM ATE CHANGE A crack in the natural-gas bridge Integrated

  16. A crack in the natural-gas bridge

    E-Print Network [OSTI]

    Davis, SJ; Shearer, C

    2014-01-01T23:59:59.000Z

    J. D. & Wirth, T. E. Natural Gas: A Bridge Fuel for the 21stexpanding supplies of natural gas will not help us to avoidLIM ATE CHANGE A crack in the natural-gas bridge Integrated

  17. Modeling of crack initiation, propagation and coalescence in rocks

    E-Print Network [OSTI]

    Gonalves da Silva, Bruno Miguel

    2009-01-01T23:59:59.000Z

    Natural or artificial fracturing of rock plays a very important role in geologic processes and for engineered structures in and on rock. Fracturing is associated with crack initiation, propagation and coalescence, which ...

  18. Crack coalescence in rock-like material under cycling loading

    E-Print Network [OSTI]

    Ko, Tae Young, 1973-

    2005-01-01T23:59:59.000Z

    A total of 170 tests (68 tests for monotonic loading, 102 tests for cyclic loading) have been performed to investigate crack initiation, propagation and coalescence. The specimens have two pre-existing flaws which are ...

  19. Field Examples of Axial Cracked Bearings in Wind Turbine Gearboxes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Field Examples of Axial Cracked Bearings in Wind Turbine Gearboxes Presented by Paul John Baker of FrontierPro Services at the Wind Turbine Tribology Seminar 2014. 141030 Axial...

  20. Technique to eliminate helium induced weld cracking in stainless steels

    SciTech Connect (OSTI)

    Chin-An Wang; Chin, B.A. [Auburn Univ., AL (United States). Dept. of Materials Engineering; Grossbeck, M.L. [Oak Ridge National Lab., TN (United States)

    1992-12-31T23:59:59.000Z

    Experiments have shown that Type 316 stainless steel is susceptible to heat-affected-zone (HAZ) cracking upon cooling when welded using the gas tungsten arc (GTA) process under lateral constraint. The cracking has been hypothesized to be caused by stress-assisted helium bubble growth and rupture at grain boundaries. This study utilized an experimental welding setup which enabled different compressive stresses to be applied to the plates during welding. Autogenous GTA welds were produced in Type 316 stainless steel doped with 256 appm helium. The application of a compressive stress, 55 Mpa, during welding suppressed the previously observed catastrophic cracking. Detailed examinations conducted after welding showed a dramatic change in helium bubble morphology. Grain boundary bubble growth along directions parallel to the weld was suppressed. Results suggest that stress-modified welding techniques may be used to suppress or eliminate helium-induced cracking during joining of irradiated materials.

  1. Numerical Modeling of Hydraulic Fracture Propagation Using Thermo-hydro-mechanical Analysis with Brittle Damage Model by Finite Element Method

    E-Print Network [OSTI]

    Min, Kyoung

    2013-07-16T23:59:59.000Z

    are studied using a coupled thermo-hydro-mechanical (THM) analysis. The models are used to simulate microscopic and macroscopic fracture behaviors of laboratory-scale uniaxial and triaxial experiments on rock using an elastic/brittle damage model considering...

  2. Understanding Spatio-Temporal Variability and Associated Physical Controls of Near-Surface Soil Moisture in Different Hydro-Climates

    E-Print Network [OSTI]

    Joshi, Champa

    2013-05-06T23:59:59.000Z

    -scale), spatial extents (field-, watershed-, and regional-scale), and changing hydro-climates. Various analysis techniques (e.g., time stability, geostatistics, Empirical Orthogonal Function, and Singular Value Decomposition) have been employed to characterize...

  3. Understanding Spatio-Temporal Variability and Associated Physical Controls of Near-Surface Soil Moisture in Different Hydro-Climates

    E-Print Network [OSTI]

    Joshi, Champa

    2013-05-06T23:59:59.000Z

    -scale), spatial extents (field-, watershed-, and regional-scale), and changing hydro-climates. Various analysis techniques (e.g., time stability, geostatistics, Empirical Orthogonal Function, and Singular Value Decomposition) have been employed to characterize...

  4. Ris Energy Report 5 Hydro, ocean and geothermal 4 This chapter gives an overview of the development of

    E-Print Network [OSTI]

    in 2003. [1] OECD, 47% Latin America, 20% China, 11% Former USSR, 9% Other Asia, 7% Africa, 3% Non of the development of other renewable energy technologies such as hydro, ocean and geothermal. These technologies

  5. Assessment of crack opening area for leak rates

    SciTech Connect (OSTI)

    Sharples, J.K.; Bouchard, P.J.

    1997-04-01T23:59:59.000Z

    This paper outlines the background to recommended crack opening area solutions given in a proposed revision to leak before break guidance for the R6 procedure. Comparisons with experimental and analytical results are given for some selected cases of circumferential cracks in cylinders. It is shown that elastic models can provide satisfactory estimations of crack opening displacement (and area) but they become increasingly conservative for values of L{sub r} greater than approximately 0.4. The Dugdale small scale yielding model gives conservative estimates of crack opening displacement with increasing enhancement for L{sub r} values greater than 0.4. Further validation of the elastic-plastic reference stress method for up to L{sub r} values of about 1.0 is presented by experimental and analytical comparisons. Although a more detailed method, its application gives a best estimate of crack opening displacement which may be substantially greater than small scale plasticity models. It is also shown that the local boundary conditions in pipework need to be carefully considered when evaluating crack opening area for through-wall bending stresses resulting from welding residual stresses or geometry discontinuities.

  6. Catastrophic Cracking Courtesy of Quiescent Cavitation

    E-Print Network [OSTI]

    Daily, D Jesse; Thomson, Scott L; Truscott, Tadd T

    2012-01-01T23:59:59.000Z

    A popular party trick is to fill a glass bottle with water and hit the top of the bottle with an open hand, causing the bottom of the bottle to break open. We investigate the source of the catastrophic cracking through the use of high-speed video and an accelerometer attached to the bottom of a glass bottle. Upon closer inspection, it is obvious that the acceleration caused by hitting the top of the bottle is followed by the formation of bubbles near the bottom. The nearly instantaneous acceleration creates an area of low pressure on the bottom of the bottle where cavitation bubbles form. Moments later, the cavitation bubbles collapse at roughly 10 times the speed of formation, causing the bottle to break. The accelerometer data shows that the bottle is broken after the bubbles collapse and that the magnitude of the bubble collapse is greater than the initial impact. The fluid dynamics video highlights that this trick will not work if the bottle is empty nor if it is filled with a carbonated fluid because the...

  7. Spectral Modeling of SNe Ia Near Maximum Light: Probing the Characteristics of Hydro Models

    E-Print Network [OSTI]

    E. Baron; S. Bongard; David Branch; Peter H. Hauschildt

    2006-03-03T23:59:59.000Z

    We have performed detailed NLTE spectral synthesis modeling of 2 types of 1-D hydro models: the very highly parameterized deflagration model W7, and two delayed detonation models. We find that overall both models do about equally well at fitting well observed SNe Ia near to maximum light. However, the Si II 6150 feature of W7 is systematically too fast, whereas for the delayed detonation models it is also somewhat too fast, but significantly better than that of W7. We find that a parameterized mixed model does the best job of reproducing the Si II 6150 line near maximum light and we study the differences in the models that lead to better fits to normal SNe Ia. We discuss what is required of a hydro model to fit the spectra of observed SNe Ia near maximum light.

  8. The OSU Hydro-Mechanical Fuel Test Facility: Standard Fuel Element Testing

    SciTech Connect (OSTI)

    Wade R. Marcum; Brian G. Woods; Ann Marie Phillips; Richard G. Ambrosek; James D. Wiest; Daniel M. Wachs

    2001-10-01T23:59:59.000Z

    Oregon State University (OSU) and the Idaho National Laboratory (INL) are currently collaborating on a test program which entails hydro-mechanical testing of a generic plate type fuel element, or standard fuel element (SFE), for the purpose of qualitatively demonstrating mechanical integrity of uranium-molybdenum monolithic plates as compared to that of uranium aluminum dispersion, and aluminum fuel plates due to hydraulic forces. This test program supports ongoing work conducted for/by the fuel development program and will take place at OSU in the Hydro-Mechanical Fuel Test Facility (HMFTF). Discussion of a preliminary test matrix, SFE design, measurement and instrumentation techniques, and facility description are detailed in this paper.

  9. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  10. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  11. Roles of grain boundaries in cleavage cracking and thermal crack arrest experiments in iron-silicon alloy

    E-Print Network [OSTI]

    Qiao, Yu, 1972-

    2002-01-01T23:59:59.000Z

    High-angle grain boundaries in steel offer an important resistance to the propagation of cleavage cracks that affects the fracture toughness and can modulate the ductile-to-brittle transition temperature of fracture downward. ...

  12. ffe1098 FFE March 7, 2007 21:55 Crack tip displacements of microstructurally small cracks in 316L steel

    E-Print Network [OSTI]

    Cizelj, Leon

    steel and their dependence on crystallographic orientations of grains I. SIMONOVSKI1 , KARL orientations on a short Stage I surface crack in a 316L stainless steel. The analysis is based on a plane

  13. Quantifying Barotrauma Risk to Juvenile Fish during Hydro-turbine Passage

    SciTech Connect (OSTI)

    Richmond, Marshall C.; Serkowski, John A.; Ebner, Laurie L.; Sick, Mirjam; Brown, Richard S.; Carlson, Thomas J.

    2014-03-15T23:59:59.000Z

    We introduce a method for hydro turbine biological performance assessment (BioPA) to bridge the gap between field and laboratory studies on fish injury and turbine engineering design. Using this method, a suite of biological performance indicators is computed based on simulated data from a computational fluid dynamics (CFD) model of a proposed hydro turbine design. Each performance indicator is a measure of the probability of exposure to a certain dose of an injury mechanism. If the relationship between the dose of an injury mechanism (stressor) and frequency of injury (dose-response) is known from laboratory or field studies, the likelihood of fish injury for a turbine design can be computed from the performance indicator. By comparing the values of the indicators from various turbine designs, engineers and biologists can identify the more-promising designs and operating conditions to minimize hydraulic conditions hazardous to passing fish. In this paper, the BioPA method is applied to estimate barotrauma induced mortal injury rates for Chinook salmon exposed to rapid pressure changes in Kaplan-type hydro turbines. Following the description of the general method, application of the BioPA to estimate the probability of mortal injury from exposure to rapid decompression is illustrated using a Kaplan hydro turbine at the John Day Dam on the Columbia River in the Pacific Northwest region of the USA. The estimated rates of mortal injury increased from 0.3% to 1.7% as discharge through the turbine increased from 334 to 564 m3/s for fish assumed to be acclimated to a depth of 5 m. The majority of pressure nadirs occurred immediately below the runner blades, with the lowest values in the gap at the blade tips and just below the leading edge of the blades. Such information can help engineers focus on problem areas when designing new turbine runners to be more fish-friendly than existing units.

  14. Turbulent Flow Effects on the Biological Performance of Hydro-Turbines

    SciTech Connect (OSTI)

    Richmond, Marshall C.; Romero Gomez, Pedro DJ

    2014-08-25T23:59:59.000Z

    The hydro-turbine industry uses Computational Fluid Dynamics (CFD) tools to predict the flow conditions as part of the design process for new and rehabilitated turbine units. Typically the hydraulic design process uses steady-state simulations based on Reynolds-Averaged Navier-Stokes (RANS) formulations for turbulence modeling because these methods are computationally efficient and work well to predict averaged hydraulic performance, e.g. power output, efficiency, etc. However, in view of the increasing emphasis on environmental concerns, such as fish passage, the consideration of the biological performance of hydro-turbines is also required in addition to hydraulic performance. This leads to the need to assess whether more realistic simulations of the turbine hydraulic environment ?those that resolve unsteady turbulent eddies not captured in steady-state RANS computations? are needed to better predict the occurrence and extent of extreme flow conditions that could be important in the evaluation of fish injury and mortality risks. In the present work, we conduct unsteady, eddy-resolving CFD simulations on a Kaplan hydro-turbine at a normal operational discharge. The goal is to quantify the impact of turbulence conditions on both the hydraulic and biological performance of the unit. In order to achieve a high resolution of the incoming turbulent flow, Detached Eddy Simulation (DES) turbulence model is used. These transient simulations are compared to RANS simulations to evaluate whether extreme hydraulic conditions are better captured with advanced eddy-resolving turbulence modeling techniques. The transient simulations of key quantities such as pressure and hydraulic shear flow that arise near the various components (e.g. wicket gates, stay vanes, runner blades) are then further analyzed to evaluate their impact on the statistics for the lowest absolute pressure (nadir pressures) and for the frequency of collisions that are known to cause mortal injury in fish passing through hydro-turbines.

  15. Buda-Lund hydro model and the elliptic flow at RHIC

    E-Print Network [OSTI]

    M. Csanad; T. Csorgo; B. Lorstad

    2004-02-12T23:59:59.000Z

    The ellipsoidally symmetric Buda-Lund hydrodynamic model describes naturally the transverse momentum and the pseudorapidity dependence of the elliptic flow in Au+Au collisions at $\\sqrt{s_{NN}} = 130$ and 200 GeV. The result confirms the indication of quark deconfinement in Au+Au collisions at RHIC, obtained from Buda-Lund hydro model fits to combined spectra and HBT radii of BRAHMS, PHOBOS, PHENIX and STAR.

  16. Advances in constitutive modelling of jointed rock hydro mechanical interactions at laboratory scale

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ) INPL-LAEGO-ENSMN, Parc de Saurupt, Ecole des mines, 54000 Nancy, France) (2) INERIS, Parc de Saurupt. The hydro mechanical modelling performed using 3DEC code can be improved from the previous analysis through débit hydraulique dans la fracture. La modélisation hydromécanique réalisée à l'aide du code 3DEC peut

  17. Catalytic C-H Activation and Functionalization: Some Applications in Organic Synthesis

    E-Print Network [OSTI]

    Stoltz, Brian M.

    Non-hydro renewables Hydro power Natural Gas Transportation is Costly - CH4 major constituent,000 3,000 4,000 5,000 6,000 1970 1980 1990 2000 2010 2020 2030 Mtoe Oil Natural gas Coal Nuclear power of natural gas with 5-10% ethane - The energy efficiency of natural gas liquefaction and regasification add

  18. Boundary Conditions of the Hydro-Cascade Model and Relativistic Kinetic Equations for Finite Domains

    E-Print Network [OSTI]

    K. A. Bugaev

    2004-01-29T23:59:59.000Z

    A detailed analysis of the coupled relativistic kinetic equations for two domains separated by a hypersurface having both space- and time-like parts is presented. Integrating the derived set of transport equations, we obtain the correct system of the hydro+cascade equations to model the relativistic nuclear collision process. Remarkably, the conservation laws on the boundary between domains conserve separately both the incoming and outgoing components of energy, momentum and baryonic charge. Thus, the relativistic kinetic theory generates twice the number of conservation laws compared to traditional hydrodynamics. Our analysis shows that these boundary conditions between domains, the three flux discontinuity, can be satisfied only by a special superposition of two cut-off distribution functions for the ``out'' domain. All these results are applied to the case of the phase transition between quark gluon plasma and hadronic matter. The possible consequences for an improved hydro+cascade description of the relativistic nuclear collisions are discussed. The unique properties of the three flux discontinuity and their effect on the space-time evolution of the transverse expansion are also analyzed. The possible modifications of both transversal radii from pion correlations generated by a correct hydro+cascade approach are discussed.

  19. Strengthening, Crack Arrest And Multiple Cracking In Brittle Materials Using Residual Stresses.

    DOE Patents [OSTI]

    Green, David J. (State College, PA); Sglavo, Vincenzo M. (Roncegno, IT); Tandon, Rajan (Fremont, CA)

    2003-02-11T23:59:59.000Z

    Embodiments include a method for forming a glass which displays visible cracking prior to failure when subjected to predetermined stress level that is greater than a predetermined minimum stress level and less than a failure stress level. The method includes determining a critical flaw size in the glass and introducing a residual stress profile to the glass so that a plurality of visible cracks are formed prior to failure when the glass is subjected to a stress that is greater than the minimum stress level and lower than the critical stress. One method for forming the residual stress profile includes performing a first ion exchange so that a first plurality of ions of a first element in the glass are exchanged with a second plurality of ions of a second element that have a larger volume than the first ions. A second ion exchange is also performed so that a plurality of the second ions in the glass are exchanged back to ions of the first element.

  20. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31T23:59:59.000Z

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  1. Correlations between surface structure and catalytic activity/selectivity

    SciTech Connect (OSTI)

    Goodman, D.W.

    1992-10-01T23:59:59.000Z

    Objective is to address the keys to understanding the relation between surface structure and catalytic activity/selectivity. Of concern are questions related to enhanced catalytic properties of mixed-metal catalysts and critical active site requirements for molecular synthesis and rearrangement. The experimental approach utilizes a microcatalytic reactor contiguous to a surface analysis system, an arrangement which allows in vacuo transfer of the catalyst from one chamber to the other. Surface techniques being used include Auger (AES), UV and X-ray photoemission spectroscopy (UPS and XPS), temperature programmed desorption (TPD), low energy electron diffraction (LEED), high resolution electron energy loss spectroscopy (HREELS) and infrared reflection-absorption spectroscopy (IRAS). Our research program builds upon our previous experience relating the results of single crystal kinetic measurements with the results obtained with supported analogs. As well we are exploiting our recent work on the preparation, the characterization, and the determination of the catalytic properties of ultra-thin metal and metal oxide films. The program is proceeding toward the study of the unique catalytic properties of ultrathin metal films; the investigation of the critical ensemble size requirements for principal catalytic reaction types; and the modelling of supported catalysts using ultra-thin planar oxide surfaces.

  2. Determination of crack morphology parameters from service failures for leak-rate analyses

    SciTech Connect (OSTI)

    Wilkowski, G.; Ghadiali, N.; Paul, D. [Battelle Memorial Institute, Columbus, OH (United States)] [and others

    1997-04-01T23:59:59.000Z

    In leak-rate analyses described in the literature, the crack morphology parameters are typically not well agreed upon by different investigators. This paper presents results on a review of crack morphology parameters determined from examination of service induced cracks. Service induced cracks were found to have a much more tortuous flow path than laboratory induced cracks due to crack branching associated with the service induced cracks. Several new parameters such as local and global surface roughnesses, as well as local and global number of turns were identified. The effect of each of these parameters are dependent on the crack-opening displacement. Additionally, the crack path is typically assumed to be straight through the pipe thickness, but the service data show that the flow path can be longer due to the crack following a fusion line, and/or the number of turns, where the number of turns in the past were included as a pressure drop term due to the turns, but not the longer flow path length. These parameters were statistically evaluated for fatigue cracks in air, corrosion-fatigue, IGSCC, and thermal fatigue cracks. A refined version of the SQUIRT leak-rate code was developed to account for these variables. Sample calculations are provided in this paper that show how the crack size can vary for a given leak rate and the statistical variation of the crack morphology parameters.

  3. Method for measuring recovery of catalytic elements from fuel cells

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley, NJ)

    2011-03-08T23:59:59.000Z

    A method is provided for measuring the concentration of a catalytic clement in a fuel cell powder. The method includes depositing on a porous substrate at least one layer of a powder mixture comprising the fuel cell powder and an internal standard material, ablating a sample of the powder mixture using a laser, and vaporizing the sample using an inductively coupled plasma. A normalized concentration of catalytic element in the sample is determined by quantifying the intensity of a first signal correlated to the amount of catalytic element in the sample, quantifying the intensity of a second signal correlated to the amount of internal standard material in the sample, and using a ratio of the first signal intensity to the second signal intensity to cancel out the effects of sample size.

  4. High-Resolution Characterizations of Stress-Corrosion Cracks in Austenitic Stainless Steel from Crack Growth Tests in BWR-Simulated Environments

    SciTech Connect (OSTI)

    Bruemmer, Stephen M.; Thomas, Larry E.

    2005-07-20T23:59:59.000Z

    Mechanisms controlling environmental degradation and cracking in light-water-reactor (LWR) systems have been investigated by analytical transmission electron microscopy (ATEM) of cracks and crack tips. The current work focuses on intergranular stress corrosion cracking (IGSCC) of 300-series, austenitic stainless steels in high-temperature LWR environments. Comparisons are made between cold-worked 304SS containing stress-corrosion cracks produced in a simulated boiling-water-reactor (BWR) environment during crack-growth tests, and a 304SS core component with cracks produced during 26-year BWR service. Similar corrosion products consisting of duplex-layered spinel oxides were found along the walls of open cracks in the service and laboratory test samples. These oxide films consisted of oriented Cr-rich spinel up to ~30 nm thick along the metal crack walls and large-grained Fe-rich spinel at the crack centers. Cracks in the service sample were generally more filled with oxide, perhaps reflecting the much longer times available for corrosion to occur after the crack passage. Crack tips in the BWR top-guide sample exhibited unique and unexpected structures with oxide-filled cracks <10 nm wide ending in finger-like attack and locally dealloyed zones of Fe/Cr-depleted, Ni-rich metal. Alloy compositions measured at numerous crack tips were 40 wt% Fe, 4 wt% Cr and 55 wt% Ni immediately ahead of the degradation front versus approximately 70 wt% Fe, 19 wt% Cr and 9 wt% Ni in the bulk 304SS. Laboratory samples with cracks grown over much shorted times (~1.5 months) did not show the distinctive crack tip structures or strong Ni enrichment in the metal ahead of the crack tips as for the service sample. This suggests that although selective oxidation processes occur during degradation, significant composition differences may only develop after crack propagation has slowed or stopped. Additional nanometer-scale measurements elucidating corrosion processes occurring during crack advance are presented to provide insights into mechanisms controlling IGSCC.

  5. Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications

    SciTech Connect (OSTI)

    Eteman, Shahrokh

    2013-06-30T23:59:59.000Z

    Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

  6. Progress in Statistical Crack Mechanics : An Approach to Initiation

    SciTech Connect (OSTI)

    Dienes, John K.; Middleditch, J. (John); Kershner, James D.; Zuo, Q. K. (Qiuhai K.); Starobin, A. J. (Andre J.)

    2002-01-01T23:59:59.000Z

    We have developed a general theory for the formation of hot spots from defects in explosives and propellants, and applied the theory to a variety of issues concerning the sensitivity of reactive materials. The defects of greatest concern in PBXs are cracks formed in the explosive grains, which are normally brittle. The theory accounts for the opening, shear, growth, and coalescence of cracks. In addition, the theory accounts for the heating caused by interfacial friction in closed (shear) cracks and the ignition process that results. Heat conduction and chemical reactions are treated on a smaller spatial scale than the overall continuum response; this is accomplished in the numerical (FEA) simulation with a sub-grid model. In previous work we have shown the feasibility of using this approach to model explosions that result from relatively mild insults, where many other hot-spot mechanisms fail. This paper addresses some of the complications that arise as mechanical failure and heating are examined in greater detail, including the effects of crack orientation, friction, melting, viscosity in molten regions, radial crack formation via a new approach to percolation theory, and 3-D effects.

  7. Develop statewide recommendations for application of PCC joint reflective cracking rehabilitation strategies

    E-Print Network [OSTI]

    Jain, Rahul Padamkumar

    2004-11-15T23:59:59.000Z

    Spalling of cracks and joints is the cracking, breaking or chipping of the slab edges within 2 ft (0.6m) if the joint or crack (Huang et. al 2004). Joint spalling is a construction related distress in the rigid pavement that mainly affects the structural... in the asphalt concrete overlays laid on the concrete pavements. Reflection cracks are caused by discontinuities in the underlying layers which propagate through the HMA surface due to movement at crack (Roberts et al 1996). Reflection cracks in AC overlays...

  8. The backflow cell model for fluidized bed catalytic reactors

    E-Print Network [OSTI]

    Ganapathy, E. V

    1967-01-01T23:59:59.000Z

    THE BACKFLOW CELL MODEL FOR FLUIDI2ED BED CATALYTIC REACTORS A Thesis By E. V. Ganapathy Submitted to the Graduate College of the Texas A&M University in partial fulfillment of' the requirements for the degree of MASTER OF SCIENCE May 1967... Major Subject Chemical En ineerin THE BACKFLOW CELL MODEL FOR FLUIDIZED BED CATALYTIC REACTORS A Thesis E. V. Ganapathy Approved as to style and content by: chairman of Committee ~H+d d D p t t Member Member) May 1967 SO THE BACKFLOW CELL...

  9. Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons

    DOE Patents [OSTI]

    Rollins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

    2011-02-01T23:59:59.000Z

    Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

  10. Continued investigations of the catalytic reduction of N? to NH? by molybdenum triamidoamine complexes

    E-Print Network [OSTI]

    Hanna, Brian S. (Brian Stewart)

    2011-01-01T23:59:59.000Z

    A study of the effects of employing different solvents and the introduction of dihydrogen during the catalytic reduction of dinitrogen to ammonia with [HIPTN 3N]Mo complexes was completed. During a catalytic reaction, the ...

  11. Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine

    E-Print Network [OSTI]

    Peck, Jhongwoo, 1976-

    2003-01-01T23:59:59.000Z

    As part of the MIT micro-gas turbine engine project, the development of a hydrocarbon-fueled catalytic micro-combustion system is presented. A conventionally-machined catalytic flow reactor was built to simulate the ...

  12. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Broader source: Energy.gov (indexed) [DOE]

    Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using...

  13. Boundary integral formulation for interfacial cracks in thermodiffusive bimaterials

    E-Print Network [OSTI]

    L. Morini; A. Piccolroaz

    2015-04-29T23:59:59.000Z

    An original boundary integral formulation is proposed for the problem of a semi-infinite crack at the interface between two dissimilar elastic materials in the presence of heat flows and mass diffusion. Symmetric and skew-symmetric weight function matrices are used together with a generalized Betti's reciprocity theorem in order to derive a system of integral equations that relate the applied loading, the temperature and mass concentration fields, the heat and mass fluxes on the fracture surfaces and the resulting crack opening. The obtained integral identities can have many relevant applications, such as for the modelling of crack and damage processes at the interface between different components in electrochemical energy devices characterized by multi-layered structures (solid oxide fuel cells and lithium ions batteries).

  14. Method for fabrication of crack-free ceramic dielectric films

    DOE Patents [OSTI]

    Ma, Beihai; Balachandran, Uthamalingam; Chao, Sheng; Liu, Shanshan; Narayanan, Manoj

    2014-02-11T23:59:59.000Z

    The invention provides a process for forming crack-free dielectric films on a substrate. The process comprise the application of a dielectric precursor layer of a thickness from about 0.3 .mu.m to about 1.0 .mu.m to a substrate. The deposition is followed by low temperature heat pretreatment, prepyrolysis, pyrolysis and crystallization step for each layer. The deposition, heat pretreatment, prepyrolysis, pyrolysis and crystallization are repeated until the dielectric film forms an overall thickness of from about 1.5 .mu.m to about 20.0 .mu.m and providing a final crystallization treatment to form a thick dielectric film. Also provided was a thick crack-free dielectric film on a substrate, the dielectric forming a dense thick crack-free dielectric having an overall dielectric thickness of from about 1.5 .mu.m to about 20.0 .mu.m.

  15. Reflective Cracking Study: First-level Report on HVS Testing on Section 588RF - 90 mm AR4000-DOverlay

    E-Print Network [OSTI]

    Jones, David; Wu, R; Harvey, John T

    2008-01-01T23:59:59.000Z

    testing being performed to validate Caltrans overlay strategies for the rehabilitation of cracked asphalt concrete.concrete. It describes the results of the fourth HVS reflective cracking testingconcrete. It describes the results of the fourth HVS reflective cracking testing

  16. Reflective Cracking Study: First-Level Report on HVS Testing on Section 590RF - 90 mm MB4-G Overlay

    E-Print Network [OSTI]

    Jones, David; Tsai, Bor-Wen; Harvey, John T

    2008-01-01T23:59:59.000Z

    testing being performed to validate Caltrans overlay strategies for the rehabilitation of cracked asphalt concrete.concrete. It describes the results of the first HVS reflective cracking testingconcrete. It describes the results of the first HVS reflective cracking testing

  17. Weld solidification cracking in 304 to 204L stainless steel

    SciTech Connect (OSTI)

    Hochanadel, Patrick W [Los Alamos National Laboratory; Lienert, Thomas J [Los Alamos National Laboratory; Martinez, Jesse N [Los Alamos National Laboratory; Johnson, Matthew Q [Los Alamos National Laboratory

    2010-09-15T23:59:59.000Z

    A series of annulus welds were made between 304 and 304L stainless steel coaxial tubes using both pulsed laser beam welding (LBW) and pulsed gas tungsten arc welding (GTAW). In this application, a change in process from pulsed LBW to pulsed gas tungsten arc welding was proposed to limit the possibility of weld solidification cracking since weldability diagrams developed for GTAW display a greater range of compositions that are not crack susceptible relative to those developed for pulsed LBW. Contrary to the predictions of the GTAW weldability diagram, cracking was found.This result was rationalized in terms of the more rapid solidification rate of the pulsed gas tungsten arc welds. In addition, for the pulsed LBW conditions, the material compositions were predicted to be, by themselves, 'weldable' according to the pulsed LBW weldability diagram. However, the composition range along the tie line connecting the two compositions passed through the crack susceptible range. Microstructurally, the primary solidification mode (PSM) of the material processed with higher power LBW was determined to be austenite (A), while solidification mode of the materials processed with lower power LBW apparently exhibited a dual PSM of both austenite (A) and ferrite-austenite (FA) within the same weld. The materials processed by pulsed GTAW showed mostly primary austenite solidification, with some regions of either primary austenite-second phase ferrite (AF) solidification or primary ferrite-second phase austenite (FA) solidification. This work demonstrates that variations in crack susceptibility may be realized when welding different heats of 'weldable' materials together, and that slight variations in processing can also contribute to crack susceptibility.

  18. Weld solidification cracking in 304 to 304L stainless steel

    SciTech Connect (OSTI)

    Hochanadel, Patrick W [Los Alamos National Laboratory; Lienert, Thomas J [Los Alamos National Laboratory; Martinez, Jesse N [Los Alamos National Laboratory; Martinez, Raymond J [Los Alamos National Laboratory; Johnson, Matthew Q [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    A series of annulus welds were made between 304 and 304L stainless steel coaxial tubes using both pulsed laser beam welding (LBW) and pulsed gas tungsten arc welding (GTAW). In this application, a change in process from pulsed LBW to pulsed gas tungsten arc welding was proposed to limit the possibility of weld solidification cracking since weldability diagrams developed for GTAW display a greater range of compositions that are not crack susceptible relative to those developed for pulsed LBW. Contrary to the predictions of the GTAW weldability diagram, cracking was found. This result was rationalized in terms of the more rapid solidification rate of the pulsed gas tungsten arc welds. In addition, for the pulsed LBW conditions, the material compositions were predicted to be, by themselves, 'weldable' according to the pulsed LBW weldability diagram. However, the composition range along the tie line connecting the two compositions passed through the crack susceptible range. Microstructurally, the primary solidification mode (PSM) of the material processed with higher power LBW was determined to be austenite (A), while solidification mode of the materials processed with lower power LBW apparently exhibited a dual PSM of both austenite (A) and ferrite-austenite (FA) within the same weld. The materials processed by pulsed GT A W showed mostly primary austenite solidification, with some regions of either primary austenite-second phase ferrite (AF) solidification or primary ferrite-second phase austenite (FA) solidification. This work demonstrates that variations in crack susceptibility may be realized when welding different heats of 'weldable' materials together, and that slight variations in processing can also contribute to crack susceptibility.

  19. Dynamic crack initiation toughness : experiments and peridynamic modeling.

    SciTech Connect (OSTI)

    Foster, John T.

    2009-10-01T23:59:59.000Z

    This is a dissertation on research conducted studying the dynamic crack initiation toughness of a 4340 steel. Researchers have been conducting experimental testing of dynamic crack initiation toughness, K{sub Ic}, for many years, using many experimental techniques with vastly different trends in the results when reporting K{sub Ic} as a function of loading rate. The dissertation describes a novel experimental technique for measuring K{sub Ic} in metals using the Kolsky bar. The method borrows from improvements made in recent years in traditional Kolsky bar testing by using pulse shaping techniques to ensure a constant loading rate applied to the sample before crack initiation. Dynamic crack initiation measurements were reported on a 4340 steel at two different loading rates. The steel was shown to exhibit a rate dependence, with the recorded values of K{sub Ic} being much higher at the higher loading rate. Using the knowledge of this rate dependence as a motivation in attempting to model the fracture events, a viscoplastic constitutive model was implemented into a peridynamic computational mechanics code. Peridynamics is a newly developed theory in solid mechanics that replaces the classical partial differential equations of motion with integral-differential equations which do not require the existence of spatial derivatives in the displacement field. This allows for the straightforward modeling of unguided crack initiation and growth. To date, peridynamic implementations have used severely restricted constitutive models. This research represents the first implementation of a complex material model and its validation. After showing results comparing deformations to experimental Taylor anvil impact for the viscoplastic material model, a novel failure criterion is introduced to model the dynamic crack initiation toughness experiments. The failure model is based on an energy criterion and uses the K{sub Ic} values recorded experimentally as an input. The failure model is then validated against one class of problems showing good agreement with experimental results.

  20. Analysis of weld solidification cracking in cast nickel aluminide alloys

    SciTech Connect (OSTI)

    Santella, M.L.; Feng, Z. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1995-09-01T23:59:59.000Z

    A study of the response of several nickel aluminide alloys to SigmaJig testing was done to examine their weld solidification cracking behavior and the effect of Zr concentration. The alloys were based on the Ni-8Al-7.7Cr-1.5Mo-0.003B wt% composition and contained Zr concentrations of 3, 4.5, and 6 wt%. Vacuum induction melted ingots with a diameter of 2.7 in and weight about 18 lb were made of each alloy, and were used to make 2 x 2 x 0.030 in specimens for the Sigmajig test. The gas tungsten arc welds were made at travel speeds of 10, 20, and 30 ipm with heat inputs of 2--2.5 kJ/in. When an arc was established before traveling onto the test specimen centerline cracking was always observed. This problem was overcome by initiating the arc directly on the specimens. Using this approach, the 3 wt% Zr alloy withstood an applied stress of 24 ksi without cracking at a welding speed of 10 ipm. This alloy cracked at 4 ksi applied at 20 ipm, and with no applied load at 30 ipm. Only limited testing was done on the remaining alloys, but the results indicate that resistance to solidification cracking increases with Zr concentration. Zirconium has limited solid solubility and segregates strongly to interdendritic regions during solidification where it forms a Ni solid solution-Ni{sub 5}Zr eutectic. The volume fraction of the eutectic increases with Zr concentration. The solidification cracking behavior of these alloys is consistent with phenomenological theory, and is discussed in this context. The results from SigmaJig testing are analyzed using finite element modeling of the development of mechanical strains during solidification of welds. Experimental data from the test substantially agree with recent analysis results.

  1. Stress Corrosion Crack Detection on HU-25 Guardian Aircraft

    SciTech Connect (OSTI)

    Blackmon, R.; Huffman, J.; Mello, C.W.; Moore, D.G.; Walkington, P.D.

    1999-02-17T23:59:59.000Z

    Several ultrasonic inspection methods were developed at the Federal Aviation Administration's Airworthiness Assurance NDI Validation Center (AANC) to easily and rapidly detect hidden stress corrosion cracks in all vertical windshield posts on the US Coast Guard (USCG) HU-25 Guardian aircraft. The inspection procedure locates cracks as small as 2.0 millimeters emanating from internal fastener holes and determines their length. A test procedure was developed and a baseline assessment of the USCG fleet was conducted. Inspection results on twenty-five aircraft revealed a good correlation with results made during subsequent structural disassembly and visual inspection.

  2. Interacting FisherWright Diffusions in a Catalytic Medium Andreas Greven

    E-Print Network [OSTI]

    Klenke, Achim

    environment (catalytic medium). Here we introduce a model of interacting Fisher­Wright diffusions where environment, catalytic medium, longtime behaviour, rescaling. AMS Subject Classification: 60K35, 60J70Interacting Fisher­Wright Diffusions in a Catalytic Medium Andreas Greven Mathematisches Institut

  3. Data reconciliation and optimal operation of a catalytic naphtha reformer

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Data reconciliation and optimal operation of a catalytic naphtha reformer Tore Lid Statoil Mongstad-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high-octane components for use in high-performance gasoline fuels. The reformer also has a important function

  4. Data reconciliation and optimal operation of a catalytic naphtha reformer

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Data reconciliation and optimal operation of a catalytic naphtha reformer Tore Lid Statoil Mongstad-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high-octane components for use in high-performance gasoline fuels. The reformer also has an important function

  5. Catalytic two-stage coal hydrogenation and hydroconversion process

    DOE Patents [OSTI]

    MacArthur, James B. (Denville, NJ); McLean, Joseph B. (So. Somerville, NJ); Comolli, Alfred G. (Yardley, PA)

    1989-01-01T23:59:59.000Z

    A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F. temperature for further hydrogenation and thermal hydroconversion reactions. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, which results in significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of undesirable residuum and unconverted coal and hydrocarbon gases, with use of less energy to obtain the low molecular weight products, while catalyst life is substantially increased.

  6. Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines Peter Mauermann1,* , Michael Dornseiffer6 , Frank Amkreutz6 1 Institute for Combustion Engines , RWTH Aachen University, Schinkelstr. 8, D of the hydrocarbon exhaust of internal combustion engines. In contrast to other gaseous hydrocarbons, significant

  7. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  8. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  9. Catalytic, Enantioselective Alkylations of N,O-Acetals

    E-Print Network [OSTI]

    Lectka, Thomas

    , 10998-10999. (2) Hoveyda et al. have developed a Ni-catalyzed alkylation reaction of allylic acetalsCatalytic, Enantioselective Alkylations of N,O-Acetals Dana Ferraris, Travis Dudding, Brandon Young alkylation reactions of acetals have attained a prominent position in organic synthesis.1 Methods employing

  10. Catalytic Asymmetric Synthesis of Hydroxy Enol Ethers: Approach to a

    E-Print Network [OSTI]

    Walsh, Patrick J.

    for the generation of polypro- pionate backbone.1-7 In contrast, the asymmetric acetate aldol reaction that leads associated with acetate aldol reactions have prompted investigations into alternative methods to generate the catalytic asymmetric allylation of aldehydes followed by oxidative cleavage of the allyl group (Scheme 1, A

  11. Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC)

    E-Print Network [OSTI]

    Williams, Roger L.

    Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC) MUTATIONAL ANALYSIS OF RESIDUES WITHIN THE ACTIVE SITE AND HYDROPHOBIC RIDGE OF PLC 1* (Received for publication, November 20, 1997 Institute, University of Dundee, Dundee DD1 4HN, United Kingdom Structural studies of phospholipase C 1 (PLC

  12. Utilization of char from biomass gasification in catalytic applications

    E-Print Network [OSTI]

    temperature or time. In addition, micropores were observed in char that was made in CO2, but not in char, but sintering was not observed during gasification with CO2. This showed that the properties of char depend catalytically or thermally. However, thermal decomposition requires high temperatures, and catalyst deactivation

  13. Short Communication Catalytic coal gasification: use of calcium versus potassium*

    E-Print Network [OSTI]

    Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis was to study the relative merits (or liabilities) of these two catalysts in coal char gasification. This work

  14. Structural Dynamics of a Catalytic Monolayer Probed by Ultrafast

    E-Print Network [OSTI]

    Fayer, Michael D.

    REPORTS Structural Dynamics of a Catalytic Monolayer Probed by Ultrafast 2D IR Vibrational Echoes in solutions. Here, we extend the technique to probing the interfacial dynamics and structure of a silica. The structural dynamics, as reported on by a carbonyl stretch vibration of the surface-bound complex, have

  15. Evaluation of Blade-Strike Models for Estimating the Biological Performance of Large Kaplan Hydro Turbines

    SciTech Connect (OSTI)

    Deng, Zhiqun; Carlson, Thomas J.; Ploskey, Gene R.; Richmond, Marshall C.

    2005-11-30T23:59:59.000Z

    BioIndex testing of hydro-turbines is sought as an analog to the hydraulic index testing conducted on hydro-turbines to optimize their power production efficiency. In BioIndex testing the goal is to identify those operations within the range identified by Index testing where the survival of fish passing through the turbine is maximized. BioIndex testing includes the immediate tailrace region as well as the turbine environment between a turbine's intake trashracks and the exit of its draft tube. The US Army Corps of Engineers and the Department of Energy have been evaluating a variety of means, such as numerical and physical turbine models, to investigate the quality of flow through a hydro-turbine and other aspects of the turbine environment that determine its safety for fish. The goal is to use these tools to develop hypotheses identifying turbine operations and predictions of their biological performance that can be tested at prototype scales. Acceptance of hypotheses would be the means for validation of new operating rules for the turbine tested that would be in place when fish were passing through the turbines. The overall goal of this project is to evaluate the performance of numerical blade strike models as a tool to aid development of testable hypotheses for bioIndexing. Evaluation of the performance of numerical blade strike models is accomplished by comparing predictions of fish mortality resulting from strike by turbine runner blades with observations made using live test fish at mainstem Columbia River Dams and with other predictions of blade strike made using observations of beads passing through a 1:25 scale physical turbine model.

  16. Failure probability of axially cracked steam generator tubes; A probabilistic fracture mechanics model

    SciTech Connect (OSTI)

    Mavko, B.; Cizelj, L. (Jozef Stefan Inst., Reactor Engineering Div., P.O. Box 100, 61111 Ljubljana, Slovenia (YU))

    1992-05-01T23:59:59.000Z

    In this paper a model for estimating the failure probability of axially cracked steam generator tubes is proposed. The model compares observed crack length distribution with critical crack length distribution by means of probabilistic fracture mechanics. The observed crack length is influenced by measured data, measurement reliability, sizing accuracy, and predicted crack growth rate. The critical crack length is defined by a deterministic mechanical model. All cracks are conservatively assumed to extend through the tube wall. The effect of the plugging limit is studied along with the number of cracked tubes to perform risk-based lifetime optimization of steam generators. A numerical example presented considers hypothetical accidental operating conditions during a feedwater line break.

  17. Monitoring Cracking of a Smectitic Vertisol using Three-dimensional Electrical Resistivity Tomography

    E-Print Network [OSTI]

    Ackerson, Jason Paul

    2013-11-20T23:59:59.000Z

    Upon desiccation, the matrix of Vertisols and other expansive soils shrinks. Matrix shrinkage results in the formation of cracks that can alter the hydrology of the soil. Despite the importance of cracks, many hydrologic models do not account...

  18. The centrality dependence of v2/epsilon: the ideal hydro limit and eta/s

    E-Print Network [OSTI]

    H. Masui; J-Y. Ollitrault; R. Snellings; A. Tang

    2009-09-25T23:59:59.000Z

    The large elliptic flow observed at RHIC is considered to be evidence for almost perfect liquid behavior of the strongly coupled quark-gluon plasma produced in the collisions. In these proceedings we present a two parameter fit for the centrality dependence of the elliptic flow scaled by the spatial eccentricity. We show by comparing to viscous hydrodynamical calculations that these two parameters are in good approximation proportional to the shear viscosity over entropy ratio and the ideal hydro limit of the ratio v2/epsilon.

  19. Quantifying the Operational Benefits of Conventional and Advanced Pumped Storage Hydro on Reliability and Efficiency: Preprint

    SciTech Connect (OSTI)

    Krad, I.; Ela, E.; Koritarov, V.

    2014-07-01T23:59:59.000Z

    Pumped storage hydro (PSH) plants have significant potential to provide reliability and efficiency benefits in future electric power systems with high penetrations of variable generation. New PSH technologies, such as adjustable-speed PSH, have been introduced that can also present further benefits. This paper demonstrates and quantifies some of the reliability and efficiency benefits afforded by PSH plants by utilizing the Flexible Energy Scheduling Tool for the Integration of Variable generation (FESTIV), an integrated power system operations tool that evaluates both reliability and production costs.

  20. HydroChina ZhongNan Engineering Corp | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDIT REPORTEnergyFarms AHefei SungrowHelukabelHonitonHydroChinaZhongNan

  1. HydroVenturi Ltd previously RV Power Company Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEIHesperia, California:Project JumpHyEnergy SystemsHydroChiste

  2. Lichuan City Yujiang River Valley Hydro Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |Jilin ZhongdiantouLichuan City Yujiang River Valley Hydro Co Ltd Jump

  3. Industrial Gas Turbine Engine Catalytic Pilot Combustor-Prototype Testing

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2009-09-30T23:59:59.000Z

    PCI has developed and demonstrated its Rich Catalytic Lean-burn (RCL®) technology for industrial and utility gas turbines to meet DOE??s goals of low single digit emissions. The technology offers stable combustion with extended turndown allowing ultra-low emissions without the cost of exhaust after-treatment and further increasing overall efficiency (avoidance of after-treatment losses). The objective of the work was to develop and demonstrate emission benefits of the catalytic technology to meet strict emissions regulations. Two different applications of the RCL® concept were demonstrated: RCL® catalytic pilot and Full RCL®. The RCL® catalytic pilot was designed to replace the existing pilot (a typical source of high NOx production) in the existing Dry Low NOx (DLN) injector, providing benefit of catalytic combustion while minimizing engine modification. This report discusses the development and single injector and engine testing of a set of T70 injectors equipped with RCL® pilots for natural gas applications. The overall (catalytic pilot plus main injector) program NOx target of less than 5 ppm (corrected to 15% oxygen) was achieved in the T70 engine for the complete set of conditions with engine CO emissions less than 10 ppm. Combustor acoustics were low (at or below 0.1 psi RMS) during testing. The RCL® catalytic pilot supported engine startup and shutdown process without major modification of existing engine controls. During high pressure testing, the catalytic pilot showed no incidence of flashback or autoignition while operating over a wide range of flame temperatures. In applications where lower NOx production is required (i.e. less than 3 ppm), in parallel, a Full RCL® combustor was developed that replaces the existing DLN injector providing potential for maximum emissions reduction. This concept was tested at industrial gas turbine conditions in a Solar Turbines, Incorporated high-pressure (17 atm.) combustion rig and in a modified Solar Turbines, Incorporated Saturn engine rig. High pressure single-injector rig and modified engine rig tests demonstrated NOx less than 2 ppm and CO less than 10 ppm over a wide flame temperature operating regime with low combustion noise (<0.15% peak-to-peak). Minimum NOx for the optimized engine retrofit Full RCL® designs was less than 1 ppm with CO emissions less than 10 ppm. Durability testing of the substrate and catalyst material was successfully demonstrated at pressure and temperature showing long term stable performance of the catalytic reactor element. Stable performance of the reactor element was achieved when subjected to durability tests (>5000 hours) at simulated engine conditions (P=15 atm, Tin=400C/750F.). Cyclic tests simulating engine trips was also demonstrated for catalyst reliability. In addition to catalyst tests, substrate oxidation testing was also performed for downselected substrate candidates for over 25,000 hours. At the end of the program, an RCL® catalytic pilot system has been developed and demonstrated to produce NOx emissions of less than 3 ppm (corrected to 15% O2) for 100% and 50% load operation in a production engine operating on natural gas. In addition, a Full RCL® combustor has been designed and demonstrated less than 2 ppm NOx (with potential to achieve 1 ppm) in single injector and modified engine testing. The catalyst/substrate combination has been shown to be stable up to 5500 hrs in simulated engine conditions.

  4. IEEE Transaction on Power Apparatus and Systems, Vol. PAS-103, No. 12, December 1984 EFFICIENT LARGE-SCALE HYDRO SYSTEM SCHEDULING WITH FORCED SPILL CONDITIONS

    E-Print Network [OSTI]

    Gross, George

    releases from each reservoir and through each power house so as to optimize the total benefit of the hydroIEEE Transaction on Power Apparatus and Systems, Vol. PAS-103, No. 12, December 1984 EFFICIENT LARGE-SCALE HYDRO SYSTEM SCHEDULING WITH FORCED SPILL CONDITIONS Yoshiro Ikura George Gross Systems

  5. SEPTARIAN CONCRETIONS Septarian structures are former cracks, often lled with cement

    E-Print Network [OSTI]

    S SEPTARIAN CONCRETIONS Septarian structures are former cracks, often lled with cement may show a component of shear displacement. Crack filling cements Cracks may range from largely unlled to fully cement lled, often with a variety of distinctively colored spar cements. The lls may also

  6. A fast multipole boundary element method for modeling 2-D multiple crack problems with constant elements

    E-Print Network [OSTI]

    Liu, Yijun

    A fast multipole boundary element method for modeling 2-D multiple crack problems with constant 3 April 2014 Accepted 20 May 2014 Keywords: Fast multipole BEM 2-D multi-crack problems Constant elements Crack opening displacements Stress intensity factors a b s t r a c t A fast multipole boundary

  7. Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D

    E-Print Network [OSTI]

    Zhou, Wei

    Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D W. Zhou*, T. Z. Long and C. K of the plates were produced using tungsten inert gas (TIG) welding method. The TIG arc was also used to deposit welding beads on some of the thin plates. No cracking was found in the butt joints. However, hot cracking

  8. Stress corrosion cracking under low stress: Continuous or discontinuous Longkui K. Zhu a

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Stress corrosion cracking under low stress: Continuous or discontinuous cracks? Longkui K. Zhu a , Yu Yan a , Jinxu X. Li a , Lijie J. Qiao a, , Alex A. Volinsky b,a a Corrosion and Protection Center. Stress corrosion C. Anodic dissolution a b s t r a c t Two-dimensional and three-dimensional crack

  9. Effects of Matrix Cracks on the Thermal Diffusivity of a Fiber-Reinforced Ceramic Composite

    E-Print Network [OSTI]

    Zok, Frank

    Effects of Matrix Cracks on the Thermal Diffusivity of a Fiber-Reinforced Ceramic Composite of Engineering Science, University of Western Ontario, London, Ontario N6A 5B9, Canada Effects of matrix cracks conductances coupled with a unit cell model for a fiber composite containing a periodic array of matrix cracks

  10. Thermal resistance of bridged cracks in fiber-reinforced ceramic John Dryden

    E-Print Network [OSTI]

    Zok, Frank

    -reinforced ceramic composites obtain high toughness is through the de- velopment of multiple matrix cracksThermal resistance of bridged cracks in fiber-reinforced ceramic composites John Dryden Department November 2000; accepted for publication 16 January 2001 The thermal resistance of a bridged matrix crack

  11. Analytical Investigation of Repair Methods for Fatigue Cracks in Steel Bridges

    E-Print Network [OSTI]

    Richardson, Temple

    2012-08-31T23:59:59.000Z

    ..................................................................................................................... 22 Retrofit measure 5: Bolted Stiffener-to-Flange Angles .......................................................................................... 23 Retrofit measure 6: Bolted Web-to-Stiffener Angles and Backing Plate... crack and a 204-mm (8-in.) web-to-flange weld crack. ............................................. 55 Table 2. Comparison of stress intensity factors for three crack surface displacements with the web-to-stiffener angles and a backing plate retrofit...

  12. A cracked beam finite element for rotating shaft dynamics and stability analysis

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    A cracked beam finite element for rotating shaft dynamics and stability analysis Saber El Arem Palaiseau, France Abstract In this paper, a method for the construction of a cracked beam finite element is presented. The additional flexibility due to the cracks is identified from three- dimensional finite element

  13. A creep model for austenitic stainless steels incorporating cavitation and wedge cracking

    E-Print Network [OSTI]

    Mahesh, Sivasambu

    A creep model for austenitic stainless steels incorporating cavitation and wedge cracking S Mahesh evolution in the form of cavitation and wedge- cracking on grain boundary facets is considered. Both: Austenitic stainless steel, creep, grain boundary sliding, cavitation, wedge- cracking. Submitted to

  14. Solvent control of crack dynamics in a reversible hydrogel

    E-Print Network [OSTI]

    Tristan Baumberger; Christiane Caroli; David Martina

    2006-05-16T23:59:59.000Z

    The resistance to fracture of reversible biopolymer hydrogels is an important control factor of the cutting/slicing and eating characteristics of food gels. It is also critical for their utilization in tissue engineering, for which mechanical protection of encapsulated components is needed. Its dependence on loading rate and, recently, on the density and strength of cross-links has been investigated. But no attention was paid so far to solvent nor to environment effects. Here we report a systematic study of crack dynamics in gels of gelatin in water/glycerol mixtures. We show on this model system that: (i) increasing solvent viscosity slows down cracks; (ii) soaking with solvent increases markedly gel fragility; (iii) tuning the viscosity of the (miscible) environmental liquid affects crack propagation via diffusive invasion of the crack tip vicinity. The results point toward the fact that fracture occurs by viscoplastic chain pull-out. This mechanism, as well as the related phenomenology, should be common to all reversibly cross-linked (physical) gels.

  15. Thin film with oriented cracks on a flexible substrate

    DOE Patents [OSTI]

    Feng, Bao; McGilvray, Andrew; Shi, Bo

    2010-07-27T23:59:59.000Z

    A thermoelectric film is disclosed. The thermoelectric film includes a substrate that is substantially electrically non-conductive and flexible and a thermoelectric material that is deposited on at least one surface of the substrate. The thermoelectric film also includes multiple cracks oriented in a predetermined direction.

  16. CONTAINED PLASTIC DEFORMATION NEAR CRACKS AND NOTCHES UNDER LONGITUDINAL SHEAR

    E-Print Network [OSTI]

    CONTAINED PLASTIC DEFORMATION NEAR CRACKS AND NOTCHES UNDER LONGITUDINAL SHEAR James R. Rice* ABSTRACT An exact linear elastic-perfectly plastic solution is presented for the problem of a sharp notch coordinates corresponding to given stresses, position of the elastic-plastic boundary, and accompanying

  17. Variable amplitude fatigue crack growth, experimental results and modeling

    E-Print Network [OSTI]

    a,*, F. Bumbieler b a Laboratory of Mechanics and Technology Cachan, 61, Avenue du Pres. Wilson method. This identification was performed for a 0.48%C carbon steel. Then various fatigue crack growth) is required so as to capture the very details of the elasticplastic cyclic deformation of the mate- rial

  18. Fracture mechanics analysis of slow crack growth in polyethylene

    E-Print Network [OSTI]

    Self, Robert Alan

    1997-01-01T23:59:59.000Z

    polyethylenes were used to evaluate the new test and analysis methods. Static loading of deeply notched three-point bend specimens was conducted at 26.7 'C, 40 'C, and 70 'C on 1.27 cm , 0.953 cm, and 0.635 cm material. The crack length as a function of time...

  19. EARLY-AGE CRACKING REVIEW: MECHANISMS, MATERIAL PROPERTIES,

    E-Print Network [OSTI]

    Bentz, Dale P.

    ://cementbarriers.org/ and Savannah River National Laboratory website: http://srnl.doe.gov #12;Early-Age Cracking Review: Mechanisms Commission (NRC), the National Institute of Standards and Technology (NIST), the Savannah River National of work performed in part under that contract. This report was prepared in support of the Savannah River

  20. Crack-resistant siloxane molding compounds. [Patent application

    DOE Patents [OSTI]

    McFarland, J.W.; Swearngin, C.B.

    1980-11-03T23:59:59.000Z

    The crack resistance of phenyl silicone molding resins containing siliceous fillers is improved by incorporating therein about 0.5 to 5.5% by weight of ..beta..-eucryptite, a lithium aluminum silicate having a negative thermal expansion coefficient. These molding resins are particularly suitable for encapsulating electronic devices such as diodes, coils, resistors, and the like.

  1. AUTONOMOUS CRACK MEASUREMENT FOR COMPARISON OF VIBRATORY COMPACTION EXCITATION AND

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Establishment of the fragility of historic structures near rights of way often produces costly delays the potential for adjacent construction activities to cause cosmetic cracking in both historic and non-historic of Civil & Environmental Engineering, Northwestern University c-dowding@northwestern.edu ABSTRACT

  2. Method of making crack-free zirconium hydride

    DOE Patents [OSTI]

    Sullivan, Richard W. (Denver, CO)

    1980-01-01T23:59:59.000Z

    Crack-free hydrides of zirconium and zirconium-uranium alloys are produced by alloying the zirconium or zirconium-uranium alloy with beryllium, or nickel, or beryllium and scandium, or nickel and scandium, or beryllium and nickel, or beryllium, nickel and scandium and thereafter hydriding.

  3. Steady crack growth in elasticplastic uid-saturated porous media

    E-Print Network [OSTI]

    Bigoni, Davide

    at the crack-tip were analyzed by van den Hoek et al. (1993) and Mohr-Coulomb elastoplasticity was considered a combined nite dierence/nite element technique. In this article, an asymptotic solution is obtained criterion with volumetric non-associative ow law and isotropic hardening. The technique used to solved

  4. Thin film cracking and ratcheting caused by temperature cycling

    E-Print Network [OSTI]

    Suo, Zhigang

    Thin film cracking and ratcheting caused by temperature cycling M. Huang and Z. Suo Mechanical caused by ratcheting in an adjacent ductile layer. For example, on a silicon die directly attached corners. Aided by cycling temperature, the shear stresses cause ratcheting in the aluminum pads

  5. Incipient Crack Detection in Composite Wind Turbine Blades

    SciTech Connect (OSTI)

    Taylor, Stuart G. [Los Alamos National Laboratory; Choi, Mijin [Chonbuk National University, Korea; Jeong, Hyomi [Chonbuk National University, Korea; Jang, Jae Kyeong [Chonbuk National University, Korea; Park, Gyuhae [Chonnam National University, Korea; Farinholt, Kevin [Commonwealth Center for Advanced Manufacturing, VA; Farrar, Charles R. [Los Alamos National Laboratory; Ammerman, Curtt N. [Los Alamos National Laboratory; Todd, Michael D. [Los Alamos National Laboratory; Lee, Jung-Ryul [Chonbuk National University, Korea

    2012-08-28T23:59:59.000Z

    This paper presents some analysis results for incipient crack detection in a 9-meter CX-100 wind turbine blade that underwent fatigue loading to failure. The blade was manufactured to standard specifications, and it underwent harmonic excitation at its first resonance using a hydraulically-actuated excitation system until reaching catastrophic failure. This work investigates the ability of an ultrasonic guided wave approach to detect incipient damage prior to the surfacing of a visible, catastrophic crack. The blade was instrumented with piezoelectric transducers, which were used in an active, pitchcatch mode with guided waves over a range of excitation frequencies. The performance results in detecting incipient crack formation in the fiberglass skin of the blade is assessed over the range of frequencies in order to determine the point at which the incipient crack became detectable. Higher excitation frequencies provide consistent results for paths along the rotor blade's carbon fiber spar cap, but performance falls off with increasing excitation frequencies for paths off of the spar cap. Lower excitation frequencies provide more consistent performance across all sensor paths.

  6. Method for recovering catalytic elements from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ); Heinz, Robert (Ludwigshafen, DE)

    2012-06-26T23:59:59.000Z

    A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

  7. A Conceptual Approach to Two-Scale Constitutive Modelling For Hydro-Mechanical Coupling

    E-Print Network [OSTI]

    Giang D. Nguyen; Abbas El-Zein; Terry Bennett

    2014-06-05T23:59:59.000Z

    Large scale modelling of fluid flow coupled with solid failure in geothermal reservoirs or hydrocarbon extraction from reservoir rocks usually involves behaviours at two scales: lower scale of the inelastic localization zone, and larger scale of the bulk continuum where elastic behaviour can be reasonably assumed. The hydraulic conductivities corresponding to the mechanical properties at these two scales are different. In the bulk elastic host rock, the hydraulic conductivity does not vary much with the deformation, while it significantly changes in the lower scale of the localization zone due to inelastic deformation. Increase of permeability due to fracture and/or dilation, or reduction of permeability due to material compaction can take place inside this zone. The challenge is to predict the evolution of hydraulic conductivities coupled with the mechanical behaviour of the material in all stages of the deformation process. In the early stage of diffuse deformation, the permeability of the material can be reasonably assumed to be homogenous over the whole Representative Volume Element (RVE) However, localized failure results in distinctly different conductivities in different parts of the RVE. This paper establishes a general framework and corresponding field equations to describe the hydro-mechanical coupling in both diffuse and localized stages of deformation in rocks. In particular, embedding the lower scale hydro-mechanical behaviour of the localization zone inside an elastic bulk, together with their corresponding effective sizes, helps effectively deal with scaling issues in large-scale modelling. Preliminary results are presented which demonstrate the promising features of this new approach.

  8. BETHE-Hydro: An Arbitrary Lagrangian-Eulerian Multi-dimensional Hydrodynamics Code for Astrophysical Simulations

    E-Print Network [OSTI]

    Jeremiah W. Murphy; Adam Burrows

    2008-07-09T23:59:59.000Z

    In this paper, we describe a new hydrodynamics code for 1D and 2D astrophysical simulations, BETHE-hydro, that uses time-dependent, arbitrary, unstructured grids. The core of the hydrodynamics algorithm is an arbitrary Lagrangian-Eulerian (ALE) approach, in which the gradient and divergence operators are made compatible using the support-operator method. We present 1D and 2D gravity solvers that are finite differenced using the support-operator technique, and the resulting system of linear equations are solved using the tridiagonal method for 1D simulations and an iterative multigrid-preconditioned conjugate-gradient method for 2D simulations. Rotational terms are included for 2D calculations using cylindrical coordinates. We document an incompatibility between a subcell pressure algorithm to suppress hourglass motions and the subcell remapping algorithm and present a modified subcell pressure scheme that avoids this problem. Strengths of this code include a straightforward structure, enabling simple inclusion of additional physics packages, the ability to use a general equation of state, and most importantly, the ability to solve self-gravitating hydrodynamic flows on time-dependent, arbitrary grids. In what follows, we describe in detail the numerical techniques employed and, with a large suite of tests, demonstrate that BETHE-hydro finds accurate solutions with 2$^{nd}$-order convergence.

  9. Conservation Laws for Coupled Hydro-mechanical Processes in Unsaturated Porous Media: Theory and Implementation

    SciTech Connect (OSTI)

    Borja, R I; White, J A

    2010-02-19T23:59:59.000Z

    We develop conservation laws for coupled hydro-mechanical processes in unsaturated porous media using three-phase continuum mixture theory. From the first law of thermodynamics, we identify energy-conjugate variables for constitutive modeling at macroscopic scale. Energy conjugate expressions identified relate a certain measure of effective stress to the deformation of the solid matrix, the degree of saturation to the matrix suction, the pressure in each constituent phase to the corresponding intrinsic volume change of this phase, and the seepage forces to the corresponding pressure gradients. We then develop strong and weak forms of boundary-value problems relevant for 3D finite element modeling of coupled hydro-mechanical processes in unsaturated porous media. The paper highlights a 3D numerical example illustrating the advances in the solution of large-scale coupled finite element systems, as well as the challenges in developing more predictive tools satisfying the basic conservation laws and the observed constitutive responses for unsaturated porous materials.

  10. Final environmental impact statement, Washington Water Power/B.C. Hydro Transmission Interconnection Project

    SciTech Connect (OSTI)

    Not Available

    1992-10-01T23:59:59.000Z

    Washington Water Power (WWP) proposes to construct and operate an electric transmission line that would connect with the electrical system of the British Columbia Hydro and Power Authority (B.C. Hydro). The project would be composed of a double-circuit, 230-kilovolt (kV) transmission line from WWP`s existing Beacon Substation located northeast of Spokane, Washington to the international border located northwest of Metaline Falls, Washington. The original Presidential permit application and associated proposed route presented in the draft environmental impact statement (DEIS) have been modified to terminate at the Beacon Substation, instead of WWP`s initially proposed termination point at the planned Marshall Substation located southwest of Spokane. A supplemental draft EIS was prepared and submitted for review to not only examine the new proposed 5.6 miles of route, but to also compare the new Proposed Route to the other alternatives previously analyzed in the DEIS. This final EIS (FEIS) assesses the environmental effects of the proposed transmission line through construction, operation, maintenance, and abandonment activities and addresses the impacts associated with the Proposed Action, Eastern Alternative, Western Alternative, Northern Crossover Alternative, Southern Crossover Alternative, and No Action Alternative. The FEIS also contains the comments received and the responses to these comments submitted on the DEIS and Supplemental DEIS.

  11. Hydro overview

    E-Print Network [OSTI]

    Jean-Yves Ollitrault; Fernando G. Gardim

    2012-10-31T23:59:59.000Z

    We review recent progress in applying relativistic hydrodynamics to the modeling of heavy-ion collisions at RHIC and LHC, with emphasis on anisotropic flow and flow fluctuations.

  12. FURTHER EXAMINATION OF CRACK TIP MICROSTRUCTURES IN F82H ON THE LOWER SHELF

    SciTech Connect (OSTI)

    Gelles, David S.; Odette, George R.; Spatig, P.

    2003-09-03T23:59:59.000Z

    Dislocation microstructures have been further examined near the crack tip of a compact tension specimen of unirradiated F82H loaded to 25.6 MPa m square root at 196 degrees C after fatigue precracking. A specimen was prepared by sectioning, dimple grinding and ion milling to produce electron transparency just ahead of the crack tip. Further ion milling has allowed improved examination of the microstructure immediately ahead of the crack tip. It is found that subgrain structure is relatively unaffected near the crack tip whereas 3 micron from the crack tip, dislocation loop structure was identified.

  13. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04T23:59:59.000Z

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  14. Catalytic destruction of groundwater contaminants in reactive extraction wells

    DOE Patents [OSTI]

    McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

    2002-01-01T23:59:59.000Z

    A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

  15. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Jones, Susanne B.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

  16. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30T23:59:59.000Z

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOEs) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  17. Catalytic membrane reactors for chemicals upgrading and environmental control

    SciTech Connect (OSTI)

    Sammells, A.F. [Eltron Research, Inc., Boulder, CO (United States)

    1994-12-31T23:59:59.000Z

    Mixed ionic and electronic conducting catalytic membrane reactors are being developed for promoting a number of spontaneous chemical reactions either leading to synthesis of value added products or decomposition of environmental contaminants. The dense non-porous ceramic materials behave as short-circuited electrochemical devices whereby ions (oxygen anions or protons) and electrons become simultaneously mediated for one reaction surface to another. The rationale behind membrane materials selection and specific applications will be discussed.

  18. Hybrid lean premixing catalytic combustion system for gas turbines

    DOE Patents [OSTI]

    Critchley, Ian L.

    2003-12-09T23:59:59.000Z

    A system and method of combusting a hydrocarbon fuel is disclosed. The system combines the accuracy and controllability of an air staging system with the ultra-low emissions achieved by catalytic combustion systems without the need for a pre-heater. The result is a system and method that is mechanically simple and offers ultra-low emissions over a wide range of power levels, fuel properties and ambient operating conditions.

  19. Model catalytic oxidation studies using supported monometallic and heterobimetallic oxides

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1992-02-03T23:59:59.000Z

    This research program is directed toward a more fundamental understanding of the effects of catalyst composition and structure on the catalytic properties of metal oxides. Metal oxide catalysts play an important role in many reactions bearing on the chemical aspects of energy processes. Metal oxides are the catalysts for water-gas shift reactions, methanol and higher alcohol synthesis, isosynthesis, selective catalytic reduction of nitric oxides, and oxidation of hydrocarbons. A key limitation to developing insight into how oxides function in catalytic reactions is in not having precise information of the surface composition under reaction conditions. To address this problem we have prepared oxide systems that can be used to study cation-cation effects and the role of bridging (-O-) and/or terminal (=O) surface oxygen anion ligands in a systematic fashion. Since many oxide catalyst systems involve mixtures of oxides, we selected a model system that would permit us to examine the role of each cation separately and in pairwise combinations. Organometallic molybdenum and tungsten complexes were proposed for use, to prepare model systems consisting of isolated monomeric cations, isolated monometallic dimers and isolated bimetallic dimers supported on silica and alumina. The monometallic and bimetallic dimers were to be used as models of more complex mixed- oxide catalysts. Our current program was to develop the systems and use them in model oxidation reactions.

  20. Theory of hydro-equivalent ignition for inertial fusion and its applications to OMEGA and the National Ignition Facility

    SciTech Connect (OSTI)

    Nora, R.; Betti, R.; Bose, A.; Woo, K. M.; Christopherson, A. R.; Meyerhofer, D. D. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States); Fusion Science Center, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States); Department of Physics and/or Mechanical Engineering, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States); Anderson, K. S.; Shvydky, A.; Marozas, J. A.; Collins, T. J. B.; Radha, P. B.; Hu, S. X.; Epstein, R.; Marshall, F. J.; Sangster, T. C. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States); McCrory, R. L. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States); Department of Physics and/or Mechanical Engineering, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States)

    2014-05-15T23:59:59.000Z

    The theory of ignition for inertial confinement fusion capsules [R. Betti et al., Phys. Plasmas 17, 058102 (2010)] is used to assess the performance requirements for cryogenic implosion experiments on the Omega Laser Facility. The theory of hydrodynamic similarity is developed in both one and two dimensions and tested using multimode hydrodynamic simulations with the hydrocode DRACO [P. B. Radha et al., Phys. Plasmas 12, 032702 (2005)] of hydro-equivalent implosions (implosions with the same implosion velocity, adiabat, and laser intensity). The theory is used to scale the performance of direct-drive OMEGA implosions to the National Ignition Facility (NIF) energy scales and determine the requirements for demonstrating hydro-equivalent ignition on OMEGA. Hydro-equivalent ignition on OMEGA is represented by a cryogenic implosion that would scale to ignition on the NIF at 1.8?MJ of laser energy symmetrically illuminating the target. It is found that a reasonable combination of neutron yield and areal density for OMEGA hydro-equivalent ignition is 3 to 6??10{sup 13} and ?0.3?g/cm{sup 2}, respectively, depending on the level of laser imprinting. This performance has not yet been achieved on OMEGA.