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1

The influence of prestrained metalorganic vapor phase epitaxial gallium-nitride templates on hydride vapor phase epitaxial growth  

Science Journals Connector (OSTI)

We have varied the strain situation in metalorganic vapor phase epitaxial (MOVPE) grown gallium-nitride (GaN) by exchanging the nucleation layer and by inserting a submono-Si x N y -interlayer in the first few hundred nanometers of growth on sapphire substrates. The influence on the MOVPE template and subsequent hydride vapor phase epitaxial (HVPE) growth could be shown by in-situ measurements of the sample curvature. Using the results of these investigations we have established a procedure to confine the curvature development in MOVPE and HVPE growth to a minimum. By increasing the layer thickness in HVPE we could create self-separated freestanding GaN layers with small remaining curvature.

2014-01-01T23:59:59.000Z

2

FeP precipitates in hydride?vapor phase epitaxially grown InP:Fe  

Science Journals Connector (OSTI)

Fe?doped InP was grown by hydride?vapor phase epitaxy.Doping levels up to 8×1018 cm?3 were determined by secondary ion mass spectrometry. Additionally performed photoluminescence measurements revealed a homogeneous distribution of electrically active Fe atoms. From microstructural investigations by analytical transmission electron microscopy spherical?shaped precipitates were detected in plan?view samples. These precipitates with diameters up to 13 nm are homogeneously arranged in the epilayer. For conglomerates of precipitates a distinct enrichment with Fe and P was measured by a comparative energy dispersive x?ray analysis. The lattice plane distances of the precipitates were deduced from the electron diffraction patterns and from high?resolution electron micrographs. A comparison with calculated values for different Fe–P alloys indicates that the precipitates consist mainly of orthorhombic FeP.

M. Luysberg; R. Göbel; H. Janning

1994-01-01T23:59:59.000Z

3

Hydride vapor phase epitaxy and characterization of high-quality ScN epilayers  

SciTech Connect

The heteroepitaxial growth of ScN films was investigated on various substrates by hydride vapor phase epitaxy (HVPE). Single crystalline mirror-like ScN(100) and ScN(110) layers were successfully deposited on r- and m-plane sapphire substrates, respectively. Homogeneous stoichiometric films (N/Sc ratio 1.01?±?0.10) up to 40??m in thickness were deposited. Their mosaicity drastically improved with increasing the film thickness. The band gap was determined by optical methods to be 2.06?eV. Impurity concentrations including H, C, O, Si, and Cl were investigated through energy dispersive X-ray spectrometry and secondary ion mass spectrometry. As a result, it was found that the presence of impurities was efficiently suppressed in comparison with that of HVPE-grown ScN films reported in the past, which was possible thanks to the home-designed corrosion-free HVPE reactor. Room-temperature Hall measurements indicated that the residual free electron concentrations ranged between 10{sup 18}–10{sup 20}?cm{sup ?3}, which was markedly lower than the reported values. The carrier mobility increased monotonically with the decreasing in carrier concentration, achieving the largest value ever reported, 284?cm{sup 2}?V{sup ?1}?s{sup ?1} at n?=?3.7?×?10{sup 18}?cm{sup ?3}.

Oshima, Yuichi, E-mail: OSHIMA.Yuichi@nims.go.jp; Víllora, Encarnación G.; Shimamura, Kiyoshi [Environment and Energy Materials Research Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

2014-04-21T23:59:59.000Z

4

Time-resolved photoluminescence, positron annihilation, and Al0.23Ga0.77N/GaN heterostructure growth studies on low defect density polar and nonpolar freestanding GaN substrates grown by hydride vapor phase epitaxy  

Science Journals Connector (OSTI)

Time-resolved photoluminescence(TRPL) and positron annihilation measurements as well as Al0.23Ga0.77N/GaN heterostructuregrowth by metalorganic vapor phase epitaxy were carried out on very low defect density polar c-plane and nonpolar m-plane freestanding GaN (FS-GaN) substrates grown by hydride vapor phase epitaxy. Room-temperature photoluminescence(PL) lifetime for the near-band-edge (NBE) excitonic emission of the FS-GaN substrates increases with increasing positron diffusion length (L +); i.e. decreasing gross concentration of charged and neutral point defects and complexes. The best undoped c-plane FS-GaN exhibits record-long L + being 116?nm. The fast component of the PL lifetime for its NBE emission increases with temperature rise up to 100?K and levels off at approximately 1.1?ns. The result implies a saturation in thermal activation of nonradiative recombination centers. The surface and interface roughnesses for a Si-doped Al0.23Ga0.77N/GaN/Al0.18Ga0.82N/GaN heterostructure are improved by the use of FS-GaN substrates in comparison with the structure fabricated on a standard GaN template. The emission signals related to the recombination of a two-dimensional electron gas and excited holes are recognized for an Al0.23Ga0.77N/GaN single heterostructuregrown on the c-plane FS-GaN substrate.

S. F. Chichibu; K. Hazu; Y. Ishikawa; M. Tashiro; H. Namita; S. Nagao; K. Fujito; A. Uedono

2012-01-01T23:59:59.000Z

5

Vapor phase modifiers for oxidative coupling  

DOE Patents (OSTI)

Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

Warren, Barbara K. (Charleston, WV)

1991-01-01T23:59:59.000Z

6

Gas phase contributions to topochemical hydride reduction reactions  

SciTech Connect

Alkali and alkali earth hydrides have been used as solid state reductants recently to yield many interesting new oxygen-deficient transition metal oxides. These reactions have tacitly been assumed to be a solid phase reaction between the reductant and parent oxide. We have conducted a number of experiments with physical separation between the reductant and oxides, and find that in some cases reduction proceeds even when the reagents are physically separated, implying reactions with in-situ generated H{sub 2} and, to a lesser extent, getter mechanisms. Our findings change our understanding of these topochemical reactions, and should enhance the synthesis of additional new oxides and nanostructures. - Graphical abstract: Topochemical reductions with hydrides: Solid state or gas phase reaction? Display Omitted - Highlights: • SrFeO{sub 2} and LaNiO{sub 2} were prepared by topochemical reduction of oxides. • Separating the reducing agent (CaH{sub 2}, Mg metal) from the oxide still results in reduction. • Such topochemical reactions can occur in the gas phase.

Kobayashi, Yoji [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); Li, Zhaofei [Institute for Integrated Cell-Material Sciences, Kyoto University, Sakyo-ku, Kyoto 606-8502 (Japan); Hirai, Kei [Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Tassel, Cédric [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); The Hakubi Center for Advanced Research, Kyoto University, Yoshida-Ushinomiya-cho, Sakyo-ku, Kyoto 606-8302 (Japan); Loyer, François [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); Institut des Sciences Chimiques de Rennes, UMR 6226 Université de Rennes 1-CNRS, équipe CSM, Bât. 10B, Campus de Beaulieu, 263, Avenue du Général Leclerc, 35042 Rennes Cedex (France); Ichikawa, Noriya [CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Abe, Naoyuki [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502 (Japan); Yamamoto, Takafumi [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); Shimakawa, Yuichi [CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); and others

2013-11-15T23:59:59.000Z

7

Vapor phase modifiers for oxidative coupling  

DOE Patents (OSTI)

Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

Warren, B.K.

1991-12-17T23:59:59.000Z

8

Hydride-phase formation and its influence on fatigue crack propagationbehavior in a Zircaloy-4 alloy  

SciTech Connect

The hydride-phase formation and its influence on the fatigue behavior of a Zircaloy-4 alloy charged with hydrogen gas are investigated. First, the microstructure and fatigue crack propagation rate of the alloy in the as-received condition are studied. Second, the formation and homogeneous distribution of delta zirconium hydride ( -ZrH2) in the bulk, and its effect on the fatigue crack propagation rate are presented. The results show that in the presence of hydrides the zirconium alloy exhibits reduced toughness and enhanced crack growth rates. Finally, the influence of a pre-existing fatigue crack in the specimen and the subsequent hydride formation were investigated. The residual lattice strain profile around the fatigue crack tip was measured using neutron diffraction. The combined effects of residual strains and hydride precipitation on the fatigue behavior are discussed.

Garlea, Elena [University of Tennessee, Knoxville (UTK); Choo, H. [University of Tennessee, Knoxville (UTK); Wang, G Y [University of Tennessee, Knoxville (UTK); Liaw, Peter K [University of Tennessee, Knoxville (UTK); Clausen, B [Los Alamos National Laboratory (LANL); Brown, D. W. [Los Alamos National Laboratory (LANL); Park, Jae-Sung [University of Tennessee, Knoxville (UTK); Rack, P. D. [University of Tennessee, Knoxville (UTK); Kenik, Edward A [ORNL

2010-01-01T23:59:59.000Z

9

Verification and Validation Strategy for Implementation of Hybrid Potts-Phase Field Hydride Modeling Capability in MBM  

SciTech Connect

The Used Fuel Disposition (UFD) program has initiated a project to develop a hydride formation modeling tool using a hybrid Potts­phase field approach. The Potts model is incorporated in the SPPARKS code from Sandia National Laboratories. The phase field model is provided through MARMOT from Idaho National Laboratory.

Jason D. Hales; Veena Tikare

2014-04-01T23:59:59.000Z

10

Preliminary assessment of halogenated alkanes as vapor-phase tracers  

SciTech Connect

New tracers are needed to evaluate the efficiency of injection strategies in vapor-dominated environments. One group of compounds that seems to meet the requirements for vapor-phase tracing are the halogenated alkanes (HCFCs). HCFCs are generally nontoxic, and extrapolation of tabulated thermodynamic data indicate that they will be thermally stable and nonreactive in a geothermal environment. The solubilities and stabilities of these compounds, which form several homologous series, vary according to the substituent ratios of fluorine, chlorine, and hydrogen. Laboratory and field tests that will further define the suitability of HCFCs as vapor-phase tracers are under way.

Adams, Michael C.; Moore, Joseph N.; Hirtz, Paul

1991-01-01T23:59:59.000Z

11

Phase effects for electrons in liquid water and water vapor  

SciTech Connect

The objective of these studies is to compare transport, energy loss, and other phenomena for electrons in water in the liquid and vapor phases. Understanding the differences and similarities is an interesting physics problem in its own right. It is also important for applying the relatively large body of experimental data available for the vapor to the liquid, which is of greater relevance in radiobiology. This paper presents a summary of results from a series of collaborative studies carried out by the authors at Oak Ridge National Laboratory (ORNL) and the Gesellschaft fuer Strahlen- und Umweltforschung (GSF). 14 figs.

Turner, J.E.; Paretzke, H.G.; Wright, H.A.; Hamm, R.N.; Ritchie, R.H.

1988-01-01T23:59:59.000Z

12

Growth of manganese filled carbon nanofibers in the vapor phase  

Science Journals Connector (OSTI)

We report the vapor phase growth of partially filled graphitic fibers, 20-30 nm in diameter and up to a micron in length, during a manganese catalyzed carbon electric arc discharge. The fiber morphology resembles that of catalytic chemical vapor deposited carbon filaments but the inside hollow contains intermittent precipitates and continuous filling of Mn that at times occupy >50% of fiber lengths. Transmission electron microscopy and electron energy loss line spectra show that the fillings form as solid cores and may correspond to pure metal.

P. M. Ajayan; C. Colliex; J. M. Lambert; P. Bernier; L. Barbedette; M. Tence; O. Stephan

1994-03-14T23:59:59.000Z

13

Laves phase hydrogen storage alloys for super-high-pressure metal hydride hydrogen compressors  

Science Journals Connector (OSTI)

Ti-Cr- and Ti-Mn-based alloys were prepared to be low- and high-pressure stage metals for a double-stage super-high-pressure metal hydride hydrogen compressor. Their crystallographic characteristics and hydrogen

Xiumei Guo; Shumao Wang; Xiaopeng Liu; Zhinian Li; Fang Lü; Jing Mi; Lei Hao…

2011-06-01T23:59:59.000Z

14

First Principles Studies of Phase Stability and Reaction Dynamics in Complex Metal Hydrides  

SciTech Connect

Complex metal hydrides are believed to be one of the most promising materials for developing hydrogen storage systems that can operate under desirable conditions. At the same time, these are also a class of materials that exhibit intriguing properties. We have used state-of-the-art computational techniques to study the fundamental properties of these materials.

Chou, Mei-Yin

2014-09-29T23:59:59.000Z

15

Effect of dimensionality on vapor-liquid phase transition  

SciTech Connect

Dimensionality play significant role on ‘phase transitions’. Fluids in macroscopic confinement (bulk or 3-Dimensional, 3D) do not show significant changes in their phase transition properties with extent of confinement, since the number of molecules away from the surrounding surfaces is astronomically higher than the number of molecules in close proximity of the confining surfaces. In microscopic confinement (quasi 3D to quasi-2D), however, the number of molecules away from the close proximity of the surface is not as high as is the case with macroscopic (3D) confinement. Hence, under the same thermodynamic conditions ‘phase transition’ properties at microscopic confinement may not remain the same as the macroscopic or 3D values. Phase transitions at extremely small scale become very sensitive to the dimensions as well as the surface characteristics of the system. In this work our investigations reveal the effect of dimensionality on the phase transition from 3D to quasi-2D to 2D behavior. We have used grand canonical transition matrix Monte Carlo simulation to understand the vapor–liquid phase transitions from 3D to quasi-2D behavior. Such studies can be helpful in understanding and controlling the fluid film behaviour confined between solid surfaces of few molecular diameters, for example, in lubrication applications.

Singh, Sudhir Kumar, E-mail: sksingh@thapar.edu [Department Chemical Engineering, Thapar University, Patiala-147004 Punjab (India)

2014-04-24T23:59:59.000Z

16

Hydrogen, lithium, and lithium hydride production  

DOE Patents (OSTI)

A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

2014-03-25T23:59:59.000Z

17

Characterization of isothermal vapor phase epitaxial (Hg,Cd)Te  

Science Journals Connector (OSTI)

We report on the characterization of mercury cadmium telluride (Hg 1?x Cd x Te) film grown by the isothermal vapor phase epitaxial method (ISOVPE) and on the surface conversion of bulk Hg 1?xCd x Te to larger bandgap material. The crystal perfection is evaluated using defect etching electron beam and electrolyte electroreflectance (EBER and EER) and Rutherford backscattering spectrometry (RBS). Hall measurements are used to measure carrier densities and mobilities. Surface concentrations and concentration profiles are measured for the ISOVPE grown layers by transmission Fourier transform infrared spectroscopy (FTIR) and electron?probe microanalysis (EPMA) to establish quantitative informations about composition control. Metal–insulator?semiconductor (MIS) structures were made and the properties important to device performance such as compositional uniformity storage time and carrier concentration are measured. The ISOVPE layers are compared in quality to films grown by other methods and show promise for MIS devices.

S. B. Lee; L. K. Magel; M. F. S. Tang; D. A. Stevenson; J. H. Tregilgas; M. W. Goodwin; R. L. Strong

1990-01-01T23:59:59.000Z

18

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil  

DOE Patents (OSTI)

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08T23:59:59.000Z

19

Hydride compositions  

DOE Patents (OSTI)

Disclosed are a composition for use in storing hydrogen and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the H equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to H, and then heating below the softening temperature of any of the constituents. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P{sub H}{sub 2} and determining H/M from the isothermic function of the composition.

Lee, Myung, W.

1994-01-01T23:59:59.000Z

20

Hydride compositions  

DOE Patents (OSTI)

A composition for use in storing hydrogen, and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the hydrogen equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to hydrogen and then heating at a temperature below the softening temperature of any of the. constituents so that their chemical and structural integrity is preserved. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P.sub.H.sbsb.2 and determining H/M from the isothermic function of the composition.

Lee, Myung W. (North Augusta, SC)

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

E-Print Network 3.0 - analysis-hydride generation-gas phase Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

on the high-pressure phase diagram of molecular CO2... of a new molecular phase of carbon dioxide at high-pressure and high- temperature. Using x-ray diffraction... , we...

22

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From  

E-Print Network (OSTI)

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2010 William Acree, Jr. Department of Chemistry, University of North Texas, Denton, Texas 76203 James S. Chickosa... Department of Chemistry and Biochemistry

Chickos, James S.

23

The kinetics of heterogeneous nucleation in vapor-liquid phase transitions in the presence of ions  

Science Journals Connector (OSTI)

A method for calculating the work of nucleus formation in vapor-liquid phase transitions in the presence of ions was suggested. The method took into account ions localized in the boundary surface layer of...

G. V. Anikin; L. S. Podenko

2008-12-01T23:59:59.000Z

24

VAPOR-CONDENSED PHASE PROCESSES IN THE EARLY SOLAR SYSTEM. L. Grossman. Department of the  

E-Print Network (OSTI)

VAPOR-CONDENSED PHASE PROCESSES IN THE EARLY SOLAR SYSTEM. L. Grossman. Department@uchicago.edu. Equilibrium thermodynamic calculations of the sequence of condensation of phases from a cooling gas of solar that they underwent melting after condensation, crystallizing into the same phase as- semblage as their precursors

Grossman, Lawrence

25

Niobium hydride phase behavior studied using the cluster-variation method  

Science Journals Connector (OSTI)

We present several models for NbH phase behavior based on the cluster-variation method. The most important of these are the single-tetragonal-cell (STC) model and the twelve-cluster (TWC) model, which have as their basic clusters the single tetragonal cell and a twelve-sited cluster, respectively. The following conclusions can be drawn from our study of these models. From the STC ground-state analysis we find that, for interactions confined to the single tetragonal cell (a subset of the first 14 shells for the tetrahedral lattice), (1) it is possible to predict the ? and ? phases but not the ? phase, and (2) many-body interactions are needed to eliminate an extraneous pure phase (i.e., a phase that is not observed experimentally) at concentration [H]/[Nb]=0.25, assuming the ?, ?’, and ? phases are ground states. These observations suggest that longer-range interactions than those in the STC are important for NbH phase formation and many-body interactions may be necessary to eliminate unwanted phases at lower concentrations. We have also generated phase diagrams that are qualitatively similar (in the ordered regions) to experimental NbH phase diagrams. Our study of the TWC model shows that it is more accurate in comparison with a Monte Carlo model than the existing entropy approximations of Boureau, Richards, and MacGillivray, Soteros, and Hall. Furthermore, using the TWC model it is possible to predict an ?-?’-? phase envelope that compares well with the Futran and Hall Monte Carlo calculation. This is the first analytic free-energy calculation to predict the ?-?’-? transition. Using the TWC model we also show that, as Shirley and Hall have conjectured, many-body interactions work to lower the ?-?’ critical temperature when compared with calculations including only pair interactions. Since pair-interaction calculations overestimate the critical temperature, this is further evidence of the importance of many-body interactions.

Christine E. Soteros and Carol K. Hall

1990-10-01T23:59:59.000Z

26

Silica, Hybrid Silica, Hydride Silica and Non-Silica Stationary Phases for Liquid Chromatography  

Science Journals Connector (OSTI)

......microm was named HPLC. The price one had to pay was a high pressure...Ascentis Express C18, Acquity Ethylene Bridged Hybrid (BEH). and...the shape of their peaks on ethylene hybrid stationary phase under...contrast to what is observed for ethylene hybrid stationary phases in......

Endler M. Borges

2014-09-01T23:59:59.000Z

27

Silica, Hybrid Silica, Hydride Silica and Non-Silica Stationary Phases for Liquid Chromatography  

Science Journals Connector (OSTI)

......Marcon G., Tolon-Becerra A. Inputs of heavy metals due to agrochemical use in tobacco fields in Brazil's Southern Region. Environmental...chromatography influence of sorbent character, mobile phase composition, and pH on retention of basic compounds. Journal of Chromatography......

Endler M. Borges

2014-09-01T23:59:59.000Z

28

Metal Hydrides - Science Needs  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Storage Grand Challenge Pre-Solicitation Meeting, June 19, 2003 1 Metal Hydrides - Science Needs TRADITIONAL METALLIC HYDRIDES: 1.5 to 2 wt.% H. Well studied. COMPLEX...

29

Kinetics of hydride front in Zircaloy-2 and H release from a fractional hydrided surface  

Science Journals Connector (OSTI)

The authors study the hydriding process on commercial nuclear fuelcladdings from their inner surface using an ultrahigh vacuum method. The method allows determining the incubation and failure times of the fuel claddings as well as the dissipated energy and the partial pressure of the desorbed H 2 from the outer surface of fuel claddings during the hydriding process. The correlation between the hydriding dissipated energy and the amount of zirconium hydride (formed at different stages of the hydriding process) leads to a near t 1 ? 2 potential law corresponding to the time scaling of the reaction for the majority of the tested samples. The calibrated relation between energy and hydride thickness allows one to calculate the enthalpy of the ? - Zr H 1.5 phase. The measured H 2 desorption from the external surface is in agreement with a proposed kinetic desorption model from the hydrides precipitated at the surface.

M. Díaz; A. González-González; J. S. Moya; B. Remartínez; S. Pérez; J. L. Sacedón

2009-01-01T23:59:59.000Z

30

X-ray-induced phase transformation in congruent and vapor-transport-equilibrated lithium tantalate  

E-Print Network (OSTI)

X-ray-induced phase transformation in congruent and vapor-transport-equilibrated lithium tantalate an effect of a partially reversible x-ray-induced increase of diffuse x-ray scattering in both congruent been attributed to x-ray-induced decay of the ferroelectric phase at room temperature. The x-ray

Byer, Robert L.

31

Metal Hydride Hydrogen Storage R and D  

Energy.gov (U.S. Department of Energy (DOE))

DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

32

Metal Hydride Hydrogen Storage Research and Development  

Energy.gov (U.S. Department of Energy (DOE))

DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

33

Condensed phase conversion and growth of nanorods and other materials instead of from vapor  

DOE Patents (OSTI)

Compositions, systems and methods are described for condensed phase conversion and growth of nanorods and other materials. A method includes providing a condensed phase matrix material; and activating the condensed phase matrix material to produce a plurality of nanorods by condensed phase conversion and growth from the condensed phase matrix material instead of from vapor. The compositions are very strong. The compositions and methods provide advantages because they allow (1) formation rates of nanostructures necessary for reasonable production rates, and (2) the near net shaped production of component structures.

Geohegan, David B. (Knoxville, TN); Seals, Roland D. (Oak Ridge, TN); Puretzky, Alex A. (Knoxville, TN); Fan, Xudong (Oak Ridge, TN)

2010-10-19T23:59:59.000Z

34

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network (OSTI)

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

35

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network (OSTI)

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

36

Vapor-condensed phase processes in the early solar system Lawrence GROSSMAN*  

E-Print Network (OSTI)

Vapor-condensed phase processes in the early solar system Lawrence GROSSMAN* Department accepted 26 September 2009) Abstract­Equilibrium thermodynamic calculations of the sequence of condensation of condensation, and some may be pristine condensates that escaped later melting. Compact Type A and Type B

Grossman, Lawrence

37

Substrate effect on CdTe layers grown by metalorganic vapor phase N. V. Sochinskiia),b)  

E-Print Network (OSTI)

Substrate effect on CdTe layers grown by metalorganic vapor phase epitaxy N. V. Sochinskiia for publication 30 December 1996 CdTe layers were grown by metalorganic vapor phase epitaxy MOVPE on different substrates like sapphire, GaAs, and CdTe wafers. The growth was carried out at the temperature 340 °C

Viña, Luis

38

Modelling and Numerical Simulation of Liquid-Vapor Phase Transition  

E-Print Network (OSTI)

of pressurized water reactors in the nuclear industry. Indeed, understanding the triggering of boiling crisis, temperatures and chemical potentials, which enables dynamic generation of two-phase interfaces within a pure is a critical safety issue for the nuclear industry: when the transition occurs from nucleate boiling to film

Faccanoni, Gloria

39

Microsoft Word - Vapor Phase Elemental Sulfur Tech Brief DRAFT bbl 08-24.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

AT A GLANCE AT A GLANCE ï‚· eliminates excavation expense ï‚· applicable to large or small sites ï‚· straightforward deployment ï‚· uses heat to distribute sulfur throughout a soil ï‚· mercury reacts with sulfur to form immobile and insoluble minerals ï‚· patent applied for TechBrief Vapor Phase Elemental Sulfur Amendment for Sequestering Mercury in Contaminated Soil Scientists at the Savannah River National Laboratory (SRNL) have identified a method of targeting mercury in contaminated soil zone by use of sulfur vapor heated gas. Background Mercury contamination in soil is a common problem in the environment. The most common treatment is excavation - a method that works well for small sites where the

40

Liquid suspensions of reversible metal hydrides  

DOE Patents (OSTI)

The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

1983-12-08T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

In situ, subsurface monitoring of vapor-phase TCE using fiber optics  

SciTech Connect

A vapor-phase, reagent-based, fiber optic trichloroethylene (TCE) sensor developed by Lawrence Livermore National Laboratory (LLNL) was demonstrated at the Savannah River Site (SRS) in two configurations. The first incorporated the sensor into a down-well instrument bounded by two inflatable packers capable of sealing an area for discrete depth analysis. The second involved an integration of the sensor into the probe tip of the Army Corps of Engineers Waterways Experiment Station (WES) cone penetrometry system. Discrete depth measurements of vapor-phase concentrations of TCE in the vadose zone were successfully made using both configurations. These measurements demonstrate the first successful in situ sensing (as opposed to sampling) of TCE at a field site.

Rossabi, J. [Westinghouse Savannah River Co., Aiken, SC (United States); Colston, B. Jr.; Brown, S.; Milanovich, F. [Lawrence Livermore National Lab., CA (United States); Lee, L.T. Jr. [Army Engineer Waterways Experiment Station, Vicksburg, MS (United States). Geotechnical Lab.

1993-03-05T23:59:59.000Z

42

Ice-water and liquid-vapor phase transitions by a Ginzburg–Landau model  

Science Journals Connector (OSTI)

A model for the first order phase transitions as ice-water and liquid-vapor is proposed using the Ginzburg–Landau equation for the order parameter ? . In this model the density ? is composed of two quantities ? 0 and ? 1 such that 1 / ? = 1 / ? 0 + 1 / ? 1 where ? 1 is strictly connected to the order parameter ? . By means of this decomposition we are able to represent the Andrew diagram without the use of the heuristic van der Waals equation.

Mauro Fabrizio

2008-01-01T23:59:59.000Z

43

Molecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Richard J. Sadus  

E-Print Network (OSTI)

coexistence. 1. Introduction Henry's constant is a well-known measure of a solute's solubility in a particularMolecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Boundaries Richard to determine Henry's constant from the residual chemical potential at infinite dilution at the vapor-liquid

44

A description of the vapor phase in the lithium thionyl chloride battery  

E-Print Network (OSTI)

A DESCRIPTION OF TIIE YAPOP, PHASE IN THF. LITHIUM THIONYI. CHLORIDE BATTERY A Thesis by RODOLFO MORALES, JR. Submitted to the Graduate College of Texas AEzM University in partial fulfrHment of the requirement for the degree oi' MASTER... OF SCIENCE August 1988 Major Subject: Chemical Engineering A DESCRIPTION OF THE VAPOR PHASE IN THE LITHIUM THIONYL CHLORIDE BATTERY A Thesis bv RODOLFO 'vIORALES, JR. Approved as to style and content by: Ralph E. White (Chairman of Committee) James...

Morales, Rodolfo

1988-01-01T23:59:59.000Z

45

Hydride embrittlement in ZIRCALOY-4 plate; Part 2: Interaction between the tensile stress and the hydride morphology  

SciTech Connect

The effect of an applied tensile stress on the hydrides morphology in ZIRCALOY-4 was studied. To this end, the residual stresses around the hydride caused by the hydride precipitation was first evaluated. Considering the disability to predict hydride transformation stresses by ordinary macroscopical mechanical calculation in previous studies, X-ray diffraction (XRD) profile analysis and transmission electron microscopy (TEM) observations were carried out to quantify the microstructural evolution in hydrided ZIRCALOY-4. The residual microstrains and microstresses in the matrix and around the hydride were thus estimated. The big discrepancy between the results and the existing studies were explained by the major self-accommodation of phase transformation deformation remaining inside the hydrides and the local plastic accommodation of ZIRCALOY-4. In order to study the stress effect on hydride orientation and to estimate the hydride orientation threshold stresses, hydrogen was introduced into the specimens under tensile stress. A quantitative technique was used to evaluate the susceptibility to perpendicular hydride formation under the influence of texture, residual stresses, and externally applied tensile stresses, following an improved approach that had been first developed by Sauthoff and then applied to Zr-H system by Puls. Both analytical and experimental results indicate that the threshold stress for producing perpendicular hydrides varies with the microstructural features, the yield strength, and the residual stresses.

Bai, J.B.; Prioul, C.; Francois, D. (Ecole Centrale Paris, Chatenay-Malabry (France)); Ji, N. (ENSAM, Paris (France)); Gilbon, D. (C.E.N. Saclay, Gif-sur-Yvette (France))

1994-06-01T23:59:59.000Z

46

Synthesis of graphene nanoribbons from amyloid templates by gallium vapor-assisted solid-phase graphitization  

SciTech Connect

Single- and double-layer graphene nanoribbons (GNRs) with widths of around 10?nm were synthesized directly onto an insulating substrate by solid-phase graphitization using a gallium vapor catalyst and carbon templates made of amyloid fibrils. Subsequent investigation revealed that the crystallinity, conductivity, and carrier mobility were all improved by increasing the temperature of synthesis. The carrier mobility of the GNR synthesized at 1050?°C was 0.83 cm{sup 2}/V?s, which is lower than that of mechanically exfoliated graphene. This is considered to be most likely due to electron scattering by the defects and edges of the GNRs.

Murakami, Katsuhisa, E-mail: k.murakami@bk.tsukuba.ac.jp; Dong, Tianchen; Kajiwara, Yuya; Takahashi, Teppei; Fujita, Jun-ichi [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); Tsukuba Research Center for Interdisciplinary Materials Science, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); Hiyama, Takaki; Takai, Eisuke; Ohashi, Gai; Shiraki, Kentaro [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan)

2014-06-16T23:59:59.000Z

47

Pressure-induced phase transformations in alkali-metal hydrides calculated using an improved linear-muffin-tin-orbital–atomic-sphere-approximation energy scheme  

Science Journals Connector (OSTI)

A scheme for the calculation of total energies from first principles is described which is intermediate between the popular linear muffin-tin-orbital method in the atomic-sphere approximation (LMTO-ASA) and an exact full-potential treatment. The local-density total energy is evaluated accurately for the output charge density from the ASA potential. This method is applied to the study of static structural properties and the pressure-induced phase transformation from B1 (NaCl-structure) to B2 (CsCl-structure) phases for the partially ionic alkaki-metal hydrides NaH and KH and the alkali halide NaCl. Good agreement with experimental transition pressures and volumes is obtained. The series NaH, KH, and NaCl shows the observed strong cation and weak anion dependence. Charge densities and band structures are given at zero and high pressure. Calculated energy-volume curves for LiH show no transition up to 1 Mbar, in agreement with experimental data.

C. O. Rodriguez and M. Methfessel

1992-01-01T23:59:59.000Z

48

The growth of vapor bubble and relaxation between two-phase bubble flow  

Science Journals Connector (OSTI)

This paper presents the behavior of the bubble growth and relaxation between vapor and superheated...

S. Mohammadein; Rama Subba Reddy Gorla

2003-01-01T23:59:59.000Z

49

On the existence of vapor-liquid phase transition in dusty plasmas  

SciTech Connect

The phenomenon of phase transition in a dusty-plasma system (DPS) has attracted some attention in the past. Earlier Farouki and Hamaguchi [J. Chem. Phys. 101, 9876 (1994)] have demonstrated the existence of a liquid to solid transition in DPS where the dust particles interact through a Yukawa potential. However, the question of the existence of a vapor-liquid (VL) transition in such a system remains unanswered and relatively unexplored so far. We have investigated this problem by performing extensive molecular dynamics simulations which show that the VL transition does not have a critical curve in the pressure versus volume diagram for a large range of the Yukawa screening parameter ? and the Coulomb coupling parameter ?. Thus, the VL phase transition is found to be super-critical, meaning that this transition is continuous in the dusty plasma model given by Farouki and Hamaguchi. We provide an approximate analytic explanation of this finding by means of a simple model calculation.

Kundu, M.; Sen, A.; Ganesh, R. [Institute for Plasma Research, Bhat, Gandhinagar 382 428, Gujarat (India); Avinash, K. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India)

2014-10-15T23:59:59.000Z

50

Hydridable material for the negative electrode in a nickel-metal hydride storage battery  

SciTech Connect

A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

1997-01-01T23:59:59.000Z

51

Transition-Metal Hydrides  

NLE Websites -- All DOE Office Websites (Extended Search)

Transition-Metal Hydride Electrochromics Transition-Metal Hydride Electrochromics A new type of electrochromic hydride material has interesting and unusual properties. Thin Ni-Mg films, for example, are mirror-like in appearance and have very low visible transmittance. On exposure to hydrogen gas or on reduction in alkaline electrolyte, the films become transparent. The transition is believed to result from formation of nickel magnesium hydride, Mg2NiH4. Switchable mirrors based on rare earth hydrides were discovered in 1996 at Vrije University in the Netherlands, Rare earth-magnesium alloy films were subsequently found to be superior to the pure lanthanides in maximum transparency and mirror-state reflectivity by Philips Laboratories. The newer transition-metal types which use less expensive and less reactive materials were discovered at LBNL. This has now become a very active area of study with a network of researchers.

52

Vapor-deposited non-crystalline phase vs ordinary glasses and supercooled liquids: evidence for significant thermodynamic and kinetic differences  

E-Print Network (OSTI)

Vapor deposition of molecules on a substrate often results in glassy materials of high kinetic stability and low enthalpy. The extraordinary properties of such glasses are attributed to high rates of surface diffusion during sample deposition, which makes it possible for constituents to find a configuration of much lower energy on a typical laboratory time scale1,2,7. The exact structure of the resulting phase is often assumed to be identical to that obtained by aging of ordinary glass over exceedingly long times. Using Fast Scanning Calorimetry technique, we show that out-of-equilibrium relaxation kinetics and possibly the enthalpy of vapor-deposited films of toluene, an archetypical fragile glass former, are distinct from those of ordinary supercooled phase even when the deposition takes place at temperatures above the glass softening. These observations provide support to the conjecture that the vapor-deposition may result in formation of non-crystalline phase of unique structural, thermodynamic, and kinetic properties.

Deepanjan Bhattacharya; Vlad Sadtchenko

2014-10-31T23:59:59.000Z

53

Gas-phase reaction study of disilane pyrolysis: Applications to low pressure chemical vapor deposition  

SciTech Connect

The gas-phase thermal reactions during disilane decomposition at low pressure chemical vapor deposition conditions were studied from 300 to 1,000 K using resonance enhanced multiphoton ionization (REMPI) and multiphoton ionization (MPI). REMPI of gas-phase Si, mass 28, was detected from 640 to 840 K and 1 to 10 Torr, with a maximum signal intensity between 700 to 720 K. During disilane decomposition, no SiH (427.8 nm), SiH[sub 2] (494-515 nm), or SiH[sub 3] (419.0 nm) was detected. MPI of higher silanes, silenes, and silylenes were detected through mass fragments 2, 32, and 60; these species reached a maximum signal intensity 20 degrees prior to the mass-28 maximum. Modeling studies that included a detailed low pressure gas-phase kinetic scheme predict relative gas-phase partial pressures generated during disilane pyrolysis. The model predicted experimental trends in the Si partial pressure and the higher silane, silene, and silylene partial pressures.

Johannes, J.E.; Ekerdt, J.G. (Univ. of Texas, Austin, TX (United States). Dept. of Chemical Engineering)

1994-08-01T23:59:59.000Z

54

Gas-phase silicon atom densities in the chemical vapor deposition of silicon from silane  

SciTech Connect

Silicon atom number density profiles have been measured using laser-induced fluorescence during the chemical vapor deposition of silicon from silane. Measurements were obtained in a rotating-disk reactor as a function of silane partial pressure and the amount of hydrogen added to the carrier gas. Absolute number densities were obtained using an atomic absorption technique. Results were compared with calculated density profiles from a model of the coupled fluid flow, gas-phase and surface chemistry for an infinite-radius rotating disk. An analysis of the reaction mechanism showed that the unimolecular decomposition of SiH{sub 2} is not the dominant source of Si atoms. Profile shapes and positions, and all experimental trends are well matched by the calculations. However, the calculated number density is up to 100 times smaller than measured.

Coltrin, M.E.; Breiland, W.G.; Ho, P.

1993-12-31T23:59:59.000Z

55

Growth of vertical-cavity surface emitting lasers by metalorganic vapor phase epitaxy  

SciTech Connect

We present growth and characterization of visible and near-infrared vertical-cavity surface emitting lasers (VCSELs) grown by metalorganic vapor phase epitaxy. Discussions on the growth issue of VCSEL materials include growth rate and composition control using an {ital in}{ital situ} normal-incidence reflectometer, comprehensive p- and n-type doping study in AlGaAs by CCl{sub 4} and Si{sub 2}H{sub 6} over the entire composition range, and optimization of ultra-high material uniformity. We also demonstrate our recent achievements of all-AlGaAs VCSELs which include the first room-temperature continuous- wave demonstration of 700-nm red VCSELs and high-efficiency and low- threshold voltage 850-nm VCSELs.

Hou, H.Q.; Hammons, B.E.; Crawford, M.H.; Lear, K.L.; Choquette, K.D.

1996-10-01T23:59:59.000Z

56

Method for the generation of variable density metal vapors which bypasses the liquidus phase  

DOE Patents (OSTI)

The present invention provides a method for producing a metal vapor that includes the steps of combining a metal and graphite in a vessel to form a mixture; heating the mixture to a first temperature in an argon gas atmosphere to form a metal carbide; maintaining the first temperature for a period of time; heating the metal carbide to a second temperature to form a metal vapor; withdrawing the metal vapor and the argon gas from the vessel; and separating the metal vapor from the argon gas. Metal vapors made using this method can be used to produce uniform powders of the metal oxide that have narrow size distribution and high purity.

Kunnmann, Walter (Stony Brook, NY); Larese, John Z. (Rocky Point, NY)

2001-01-01T23:59:59.000Z

57

Ion-beam-induced epitaxial vapor-phase growth: A molecular-dynamics study  

Science Journals Connector (OSTI)

Low-energy ions which bombard a vapor-deposited film of low adatom mobility during growth mobilize surface atoms in the vicinity of the ion impact, causing a modification in the evolving microstructure. In a two-dimensional molecular-dynamics simulation where inert-gas ions strike a growing film of Lennard-Jones particles, it is demonstrated that ion bombardment during growth causes the filling of voids quenched in during vapor condensation and induces homoepitaxial growth. The dependence of film density and degree of homoepitaxial growth on the ion-to-vapor arrival rate ratio and ion energy is studied in detail.

Karl-Heinz Müller

1987-05-15T23:59:59.000Z

58

Desalination-of water by vapor-phase transport through hydrophobic nanopores  

E-Print Network (OSTI)

We propose a new approach to desalination of water whereby a pressure difference across a vapor-trapping nanopore induces selective transport of water by isothermal evaporation and condensation across the pore. Transport ...

Lee, Jongho

59

Aluminum Nitride Micro-Channels Grown via Metal Organic Vapor Phase Epitaxy for MEMs Applications  

SciTech Connect

Aluminum nitride (AlN) is a promising material for a number of applications due to its temperature and chemical stability. Furthermore, AlN maintains its piezoelectric properties at higher temperatures than more commonly used materials, such as Lead Zirconate Titanate (PZT) [1, 2], making AlN attractive for high temperature micro and nanoelectromechanical (MEMs and NEMs) applications including, but not limited to, high temperature sensors and actuators, micro-channels for fuel cell applications, and micromechanical resonators. This work presents a novel AlN micro-channel fabrication technique using Metal Organic Vapor Phase Epitaxy (MOVPE). AlN easily nucleates on dielectric surfaces due to the large sticking coefficient and short diffusion length of the aluminum species resulting in a high quality polycrystalline growth on typical mask materials, such as silicon dioxide and silicon nitride [3,4]. The fabrication process introduced involves partially masking a substrate with a silicon dioxide striped pattern and then growing AlN via MOVPE simultaneously on the dielectric mask and exposed substrate. A buffered oxide etch is then used to remove the underlying silicon dioxide and leave a free standing AlN micro-channel. The width of the channel has been varied from 5 ìm to 110 ìm and the height of the air gap from 130 nm to 800 nm indicating the stability of the structure. Furthermore, this versatile process has been performed on (111) silicon, c-plane sapphire, and gallium nitride epilayers on sapphire substrates. Reflection High Energy Electron Diffraction (RHEED), Atomic Force Microscopy (AFM), and Raman measurements have been taken on channels grown on each substrate and indicate that the substrate is influencing the growth of the AlN micro-channels on the SiO2 sacrificial layer.

Rodak, L.E.; Kuchibhatla, S.; Famouri, P.; Ting, L.; Korakakis, D.

2008-01-01T23:59:59.000Z

60

Recent progress in GaInAsSb thermophotovoltaics grown by organometallic vapor phase epitaxy  

SciTech Connect

Studies on the materials development of Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} alloys for thermophotovoltaic (TPV) devices are reviewed. Ga{sub 1{minus}x}In{sub x}As{sub y}Sb{sub 1{minus}y} epilayers were grown lattice matched to GaSb substrates by organometallic vapor phase epitaxy (OMVPE) using all organometallic precursors including triethylgallium, trimethylindium, tertiarybutylarsine, and trimethylantimony with diethyltellurium and dimethylzinc as the n- and p-type dopants, respectively. The overall material quality of these alloys depends on growth temperature, In content, V/III ratio, substrate misorientation, and to a lesser extent, growth rate. A mirror-like surface morphology and room temperature photoluminescence (PL) are obtained for GaInAsSb layers with peak emission in the wavelength range between 2 and 2.5 {micro}m. The crystal quality improves for growth temperature decreasing from 575 to 525 C, and with decreasing In content, as based on epilayer surface morphology and low temperature PL spectra. A trend of smaller full width at half-maximum for low temperature PL spectra is observed as the growth rate is increased from 1.5 to 2.5 and 5 {micro}m/h. In general, GaInAsSb layers grown on (100) GaSb substrates with a 6{degree} toward (111)B misorientation exhibited overall better material quality than layers grown on the more standard substrate (100)2{degree} toward (110). Consistent growth of high performance lattice-matched GaInAsSb TPV devices is also demonstrated.

Wang, C.A.; Choi, H.K.; Oakley, D.C. [Massachusetts Inst. of Tech., Lexington, MA (United States). Lincoln Lab.; Charache, G.W. [Lockheed Martin, Inc., Schenectady, NY (United States)

1998-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Treatment of Produced Waters Using a Surfactant Modified Zeolite/Vapor Phase Bioreactor System  

SciTech Connect

This report summarizes work performed on this project from October 2004 through March 2005. In previous work, a surfactant modified zeolite (SMZ) was shown to be an effective system for removing BTEX contaminants from produced water. Additional work on this project demonstrated that a compost-based biofilter could biodegrade the BTEX contaminants found in the SMZ regeneration waste gas stream. However, it was also determined that the BTEX concentrations in the waste gas stream varied significantly during the regeneration period and the initial BTEX concentrations were too high for the biofilter to handle effectively. A series of experiments were conducted to determine the feasibility of using a passive adsorption column placed upstream of the biofilter to attenuate the peak gas-phase VOC concentrations delivered to the biofilter during the SMZ regeneration process. In preparation for the field test of the SMZ/VPB treatment system in New Mexico, a pilot-scale SMZ system was also designed and constructed during this reporting period. Finally, a cost and feasibility analysis was also completed. To investigate the merits of the passive buffering system during SMZ regeneration, two adsorbents, SMZ and granular activated carbon (GAC) were investigated in flow-through laboratory-scale columns to determine their capacity to handle steady and unsteady VOC feed conditions. When subjected to a toluene-contaminated air stream, the column containing SMZ reduced the peak inlet 1000 ppmv toluene concentration to 630 ppmv at a 10 second contact time. This level of buffering was insufficient to ensure complete removal in the downstream biofilter and the contact time was longer than desired. For this reason, using SMZ as a passive buffering system for the gas phase contaminants was not pursued further. In contrast to the SMZ results, GAC was found to be an effective adsorbent to handle the peak contaminant concentrations that occur early during the SMZ regeneration process. At a one second residence time, the GAC bed reduced peak contaminant concentrations by 97%. After the initial peak, the inlet VOC concentration in the SMZ regeneration gas stream drops exponentially with time. During this period, the contaminants on the GAC subsequently desorbed at a nearly steady rate over the next 45 hours resulting in a relatively steady effluent concentration of approximately 25 ppm{sub v}. This lower concentration is readily degradable by a downstream vapor phase biofilter (VPB) and the steady nature of the feed stream will prevent the biomass in the VPB from enduring starvation conditions between SMZ regeneration cycles. Repetitive sorption and desorption cycles that would be expected in the field were also investigated. It was determined that although the GAC initially lost some VOC sorption capacity, the adsorption and desorption profiles stabilized after approximately 6 cycles indicating that a GAC bed should be suitable for continuous operation. In preparation for the pilot field testing of the SMZ/VPB system, design, ''in-house'' construction and testing of the field system were completed during this project period. The design of the SMZ system for the pilot test was based on previous investigations by the PI's in Wyoming, 2002 and on analyses of the produced water at the field site in New Mexico. The field tests are scheduled for summer, 2005. A cost survey, feasibility of application and cost analyses were completed to investigate the long term effectiveness of the SMZ/VPB system as a method of treating produced water for re-use. Several factors were investigated, including: current costs to treat and dispose of produced water, end-use water quality requirements, and state and federal permitting requirements.

Soondong Kwon; Elaine B. Darby; Li-Jung Chen; Lynn E. Katz; Kerry A. Kinney; R. S. Bowman; E. J. Sullivan

2005-03-11T23:59:59.000Z

62

Method for preparing porous metal hydride compacts  

DOE Patents (OSTI)

A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

1980-01-21T23:59:59.000Z

63

PNNL Chemical Hydride Capabilities | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chemical Hydride Capabilities PNNL Chemical Hydride Capabilities Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC....

64

Identification of vapor-phase chemical warfare agent simulants and rocket fuels using laser-induced breakdown spectroscopy  

SciTech Connect

Application of laser-induced breakdown spectroscopy (LIBS) to the identification of security threats is a growing area of research. This work presents LIBS spectra of vapor-phase chemical warfare agent simulants and typical rocket fuels. A large dataset of spectra was acquired using a variety of gas mixtures and background pressures and processed using partial least squares analysis. The five compounds studied were identified with a 99% success rate by the best method. The temporal behavior of the emission lines as a function of chamber pressure and gas mixture was also investigated, revealing some interesting trends that merit further study.

Stearns, Jaime A.; McElman, Sarah E.; Dodd, James A.

2010-05-01T23:59:59.000Z

65

METAL HYDRIDE HYDROGEN COMPRESSORS: A REVIEW  

SciTech Connect

Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine the metal hydride material itself should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage, hydrogen sorption kinetics and effective thermal conductivity), the thermodynamics of the metal-hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimized to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors, reduction of slope of the isotherms and hysteresis, increase of cycling stability and life time, together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation. The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal-hydrogen systems suitable for the hydrogen compression; and (b) applied aspects, including their consideration from the applied thermodynamic viewpoint, system design features and performances of the metal hydride compressors and major applications.

Bowman Jr, Robert C [ORNL] [ORNL; Yartys, Dr. Volodymyr A. [Institute for Energy Technology (IFE)] [Institute for Energy Technology (IFE); Lototskyy, Dr. Michael V [University of the Western Cape, South Africa] [University of the Western Cape, South Africa; Pollet, Dr. B.G. [University of the Western Cape, South Africa

2014-01-01T23:59:59.000Z

66

Enhanced quality thin film Cu(In,Ga)Se.sub.2 for semiconductor device applications by vapor-phase recrystallization  

DOE Patents (OSTI)

Enhanced quality thin films of Cu.sub.w (In,Ga.sub.y)Se.sub.z for semiconductor device applications are fabricated by initially forming a Cu-rich, phase-separated compound mixture comprising Cu(In,Ga):Cu.sub.x Se on a substrate to form a large-grain precursor and then converting the excess Cu.sub.x Se to Cu(In,Ga)Se.sub.2 by exposing it to an activity of In and/or Ga, either in vapor In and/or Ga form or in solid (In,Ga).sub.y Se.sub.z. Alternatively, the conversion can be made by sequential deposition of In and/or Ga and Se onto the phase-separated precursor. The conversion process is preferably performed in the temperature range of about 300.degree.-600.degree. C., where the Cu(In,Ga)Se.sub.2 remains solid, while the excess Cu.sub.x Se is in a liquid flux. The characteristic of the resulting Cu.sub.w (In,Ga).sub.y Se.sub.z can be controlled by the temperature. Higher temperatures, such as 500.degree.-600.degree. C., result in a nearly stoichiometric Cu(In,Ga)Se.sub.2, whereas lower temperatures, such as 300.degree.-400.degree. C., result in a more Cu-poor compound, such as the Cu.sub.z (In,Ga).sub.4 Se.sub.7 phase.

Tuttle, John R. (Denver, CO); Contreras, Miguel A. (Golden, CO); Noufi, Rommel (Golden, CO); Albin, David S. (Denver, CO)

1994-01-01T23:59:59.000Z

67

Enhanced quality thin film Cu(In,Ga)Se[sub 2] for semiconductor device applications by vapor-phase recrystallization  

DOE Patents (OSTI)

Enhanced quality thin films of Cu[sub w](In,Ga[sub y])Se[sub z] for semiconductor device applications are fabricated by initially forming a Cu-rich, phase-separated compound mixture comprising Cu(In,Ga):Cu[sub x]Se on a substrate to form a large-grain precursor and then converting the excess Cu[sub x]Se to Cu(In,Ga)Se[sub 2] by exposing it to an activity of In and/or Ga, either in vapor In and/or Ga form or in solid (In,Ga)[sub y]Se[sub z]. Alternatively, the conversion can be made by sequential deposition of In and/or Ga and Se onto the phase-separated precursor. The conversion process is preferably performed in the temperature range of about 300--600 C, where the Cu(In,Ga)Se[sub 2] remains solid, while the excess Cu[sub x]Se is in a liquid flux. The characteristic of the resulting Cu[sub w](In,Ga)[sub y]Se[sub z] can be controlled by the temperature. Higher temperatures, such as 500--600 C, result in a nearly stoichiometric Cu(In,Ga)Se[sub 2], whereas lower temperatures, such as 300--400 C, result in a more Cu-poor compound, such as the Cu[sub z](In,Ga)[sub 4]Se[sub 7] phase. 7 figs.

Tuttle, J.R.; Contreras, M.A.; Noufi, R.; Albin, D.S.

1994-10-18T23:59:59.000Z

68

Surface tension and vapor-liquid phase coexistence of confined square-well fluid  

E-Print Network (OSTI)

,4 Gibbs-Duhem integration GDI ,5 and N-P-T +test particle.6­8 Panagiotopoulos used GEMC to obtain, Sarkisov and Monson used GDI to get the phase behavior in a disordered porous structure,10 and Forsman

Singh, Jayant K.

69

A lattice Boltzmann study of phase separation in liquid-vapor systems with gravity  

E-Print Network (OSTI)

Phase separation of a two-dimensional van der Waals fluid subject to a gravitational force is studied by numerical simulations based on lattice Boltzmann methods (LBM) implemented with a finite difference scheme. A growth exponent $\\alpha=1$ is measured in the direction of the external force.

A. Cristea; G. Gonnella; A. Lamura; V. Sofonea

2009-07-16T23:59:59.000Z

70

Phase-Controlled Growth of Metastable Fe5Si3 Nanowires by a Vapor Transport Method  

E-Print Network (OSTI)

to produce other metal-rich silicide nanostructures for future spintronic devices. Introduction Iron. Depending on the concentration ratio of FeI2(g) to SiI4(g), different phases of iron silicides are formed. The growth of nanowires is facilitated by the initial nucleation of silicide particles on the substrate

Kim, Bongsoo

71

Hydride Rim Formation in Unirradiated Zircaloy  

Energy.gov (U.S. Department of Energy (DOE))

The purpose of this work is to develop the means of pre-hydriding unirradiated Zircaloy cladding such that a high concentration, or rim, of hydrides is formed at the cladding outside diameter.

72

Crack propagation in hydrided zircaloy-2  

Science Journals Connector (OSTI)

Transmission electron microscope observations of cracks in thin foils of Zircaloy—2 which contains hydride particles have shown that the fracture process is one of linking up satellite cracks in the hydride ph...

G. Östberg

1968-06-01T23:59:59.000Z

73

First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities  

SciTech Connect

Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density-functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest-energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium-hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities.

Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

2013-09-01T23:59:59.000Z

74

E-Print Network 3.0 - alkali metal hydrides Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Hf for selected alkali metal hydrides, alkaline earth metal hydrides, transition metal hydrides... of binary hydrides based on alkali metals, alkaline earth ... Source:...

75

Controlled Vapor Phase Growth of Single Crystalline, Two-Dimensional GaSe Crystals with High Photoresponse  

SciTech Connect

Abstract Compared with their bulk counterparts, atomically thin two-dimensional (2D) crystals exhibit new physical properties, and have the potential to enable next-generation electronic and optoelectronic devices. However, controlled synthesis of large uniform monolayer and multi-layer 2D crystals is still challenging. Here, we report the controlled synthesis of 2D GaSe crystals on SiO2/Si substrates using a vapor phase deposition method. For the first time, uniform, large (up to ~60 m in lateral size), single-crystalline, triangular monolayer GaSe crystals were obtained and their atomic resolution structure were characterized. The size, density, shape, thickness, and uniformity of the 2D GaSe crystals were shown to be controllable by growth duration, growth region, growth temperature, and argon carrier gas flow rate. The theoretical modeling of the electronic structure and Raman spectroscopy demonstrate a direct-to-indirect bandgap transition and progressive confinement-induced bandgap shifts for 2D GaSe crystals. The 2D GaSe crystals show p-type semiconductor characteristics and high photoresponsivity (~1.7 A/W under white light illumination) comparable to exfoliated GaSe nanosheets. These 2D GaSe crystals are potentially useful for next-generation electronic and optoelectronic devices such as photodetectors and field-effect transistors.

Li, Xufan [ORNL; Lin, Ming-Wei [ORNL; Zhang, Huidong [University of Tennessee, Knoxville (UTK); Puretzky, Alexander A [ORNL; Idrobo Tapia, Juan C [ORNL; Ma, Cheng [ORNL; Chi, Miaofang [ORNL; Yoon, Mina [ORNL; Rouleau, Christopher M [ORNL; Kravchenko, Ivan I [ORNL; Geohegan, David B [ORNL; Xiao, Kai [ORNL

2014-01-01T23:59:59.000Z

76

Characteristics of PCDD/F distributions in vapor and solid phases and emissions from the Waelz process  

SciTech Connect

The Waelz process is a classic method used for recovering zinc from electric arc furnace (EAF) dusts containing relatively high concentrations of PCDD/Fs (polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans) as well as volatile metals, such as Zn, Pb, and Cu, and chlorine. The EAF dust is mixed with coke (30%) and sand (20%) then fed into a rotary kiln. Significant PCDD/Fs are formed in the typical Waelz process, causing public concerns regarding PCDD/F emissions. In this study, flue gas and ash samplings are simultaneously conducted at different sampling points to evaluate the removal efficiency and the partitioning of PCDD/Fs between the vapor and solid phases in the Waelz plant investigated. With the environment (temperature window, sufficient retention time, chlorine, and catalysts available) conducive to PCDD/F formation in the dust settling chamber (DSC), a significantly high PCDD/F concentration (1223 ng TEQ/Nm{sup 3}) is measured in flue gas downstream from the DSC of the Waelz plant investigated. In addition, the cyclone and bag filter adopted in this facility can only remove 51.3% and 69.4%, respectively, of the PCDD/Fs in the flue gas, resulting in a high PCDD/F concentration (145 ng TEQ/Nm{sup 3}) measured in the stack gas of the Waelz plant investigated. On the basis of treating 1 ton of EAF dust, the total PCDD/F discharge (stack gas emission + ash discharge) is 840 ng TEQ/kg EAF dust of the Waelz plant investigated. Because of the lack of effective air pollutant control devices for PCDD/Fs, about 560 ng TEQ/kg EAF dust are discharged via stack gas in this facility. 16 refs., 7 figs., 2 tabs.

Kai Hsien Chi; Shu Hao Chang; Moo Been Chang [National Central University, Chungli (Taiwan). Graduate Institute of Environmental Engineering

2006-03-15T23:59:59.000Z

77

Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis  

E-Print Network (OSTI)

A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

Tomas Roubicek; Giuseppe Tomassetti

2013-09-12T23:59:59.000Z

78

Fracture Initiation Due to Hydrides in Zircaloy-2  

Science Journals Connector (OSTI)

In hydride-forming metals, the presence of hydrides can sometimes lead to brittle fracture. Zirconium is a hydride-forming metal that forms the basis of a number of alloys used in CANDUTM nuclear reactors. Under ...

M. P. Puls; B. W. Leitch; W. R. Wallace

1987-01-01T23:59:59.000Z

79

Complex Hydrides for Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrides for Hydrides for Hydrogen Storage George Thomas, Consultant Sandia National Laboratories G. J. Thomas Efficient onboard hydrogen storage is a critical enabling technology for the use of hydrogen in vehicles * The low volumetric density of gaseous fuels requires a storage method which densifies the fuel. - This is particularly true for hydrogen because of its lower energy density relative to hydrocarbon fuels. * Storage methods result in additional weight and volume above that of the fuel. How do we achieve adequate stored energy in an efficient, safe and cost-effective system? G. J. Thomas However, the storage media must meet certain requirements: - reversible hydrogen uptake/release - lightweight - low cost - cyclic stability - rapid kinetic properties - equilibrium properties (P,T) consistent

80

Diffusional exchange of isotopes in a metal hydride sphere.  

SciTech Connect

This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

2011-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Activated Aluminum Hydride Hydrogen Storage Compositions - Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen and Fuel Cell Find More Like This Return to Search Activated Aluminum Hydride Hydrogen Storage Compositions Brookhaven National Laboratory Contact BNL About This...

82

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities...

83

Recent developments in hydrogen storage applications based on metal hydrides  

Science Journals Connector (OSTI)

Metal hydrides have been commercialized for battery applications for more than 8 years. In case of storage applications, metal hydrides were extensively evaluated in combination with combustion engines. The relatively low gravimetric energy density of hydride tanks based on low temperature metal hydrides prevented the commercial use of that technology. Recently, lasting progress in the PEM fuel cell technology offers chances for metal hydride storage systems mainly for low power applications, but also for niche markets. The paper describes promising projects on metal hydride storage technology and gives an outlook about improvements of both the metal hydride alloy performance and the performance of metal hydride storage tanks.

V. Güther; A. Otto

1999-01-01T23:59:59.000Z

84

Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine...  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A Predictive Model through Computations. Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A...

85

Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors  

E-Print Network (OSTI)

of hydride fueled BWRs. Nuclear Engineering and Design, 239:Fueled PWR Cores. Nuclear Engineering and Design, 239:1489–Hydride Fueled LWRs. Nuclear Engineering and Design, 239:

Terrani, Kurt Amir

2010-01-01T23:59:59.000Z

86

Role of gas phase reactions in subatmospheric chemical-vapor deposition ozone/TEOS processes for oxide deposition  

E-Print Network (OSTI)

-vapor deposition. Our results for oxide deposition show optimum process window around 200 Torr for producing films a po- tentially optimum process window in which film properties, deposition rates, film uniformity requires high quality dielectric films that can be deposited rapidly and conformally on high aspect ratio

Rubloff, Gary W.

87

Observation of photoluminescence from Al1 xInxN heteroepitaxial films grown by metalorganic vapor phase epitaxy  

E-Print Network (OSTI)

Observation of photoluminescence from Al1 xInxN heteroepitaxial films grown by metalorganic vapor have observed photoluminescence of Al1 xInxN films. The films were grown on GaN by atmospheric pressure-temperature deposited AlN buffer layer. Photoluminescence, absorption, and x-ray diffraction measurements have shown

Wetzel, Christian M.

88

Electrical Properties of Hydrides and Deuterides of Zirconium  

Science Journals Connector (OSTI)

Electrical properties of hydrides and deuterides of zirconium have been investigated between 1.1 and 410°K. The metallic nature of these materials is evident in the fact that for compositions approaching ZrH2, the hydride is a better conductor than is high-purity zirconium. Above ?150°K the electrical resistivity exhibits an interesting upturn, which arises from scattering from the optical-model lattice vibrations. Excellent fits to the ideal-resistivity data are obtained with a simple additive combination of Grüneisen and Howarth-Sondheimer functions for the respective acoustical- and optical-mode scattering contributions. The corresponding acoustical- and optical-mode characteristic temperatures are in good accord with expectations based on earlier inelastic neutron scattering data. Moreover, the optical-mode characteristic temperature exhibits the expected hydride-deuteride isotope shift of 2. The observed Hall coefficients are large in magnitude (much greater than for pure Zr), and indicate majority hole conduction for the fcc ? phase and majority electron conduction for the face-centered tetragonal ? phase. The thermoelectric power also changes from positive to negative with increasing hydrogen concentration in the range ZrH1.5-ZrH2.

P. W. Bickel and T. G. Berlincourt

1970-12-15T23:59:59.000Z

89

Stress induced phase transition in Gd2O3 films by ion beam assisted reactive electron beam-physical vapor deposition (EB-PVD)  

Science Journals Connector (OSTI)

Abstract The structural evolution of thick polycrystalline gadolinium oxide (Gd2O3) films deposited by reactive electron beam-physical vapor deposition (EB-PVD) is investigated. High deposition rates (> 5 Å/s) lead to the growth of mixed phase films which are of the cubic phase near the film/substrate interface before forming monoclinic phase as distance from the interface increases. By decreasing the deposition rate to phase. The growth of the thermodynamically stable cubic phase under these conditions is attributed to both higher surface mobility of the adatoms during growth and to increased tensile stress within the film. Ion beam assisted deposition (IBAD) was then performed to introduce compressive stress into the film resulting in the formation of the monoclinic phase. Wafer curvature, X-ray diffraction, confocal Raman spectroscopy, and scanning electron microscopy are utilized to characterize the film and present evidence for the existence of a stress-induced phase transition in the Gd2O3 films.

Daniel A. Grave; Michael P. Schmitt; Joshua A. Robinson; Douglas E. Wolfe

2014-01-01T23:59:59.000Z

90

ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T. van Duin, and William A. Goddard III*  

E-Print Network (OSTI)

ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. TFFMgH) for magnesium and magnesium hydride systems. The parameters for this force field were derived from fitting to quantum chemical (QM) data on magnesium clusters and on the equations of states for condensed phases

van Duin, Adri

91

Zirconium hydride containing explosive composition  

DOE Patents (OSTI)

An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1500 and 10,000 meters per second and a minor amount of a donor additive comprising a non-explosive compound or mixture of non-explosive compounds which when subjected to an energy fluence of 1000 calories/cm.sup.2 or less is capable of releasing free radicals each having a molecular weight between 1 and 120. Exemplary donor additives are dibasic acids, polyamines and metal hydrides.

Walker, Franklin E. (18 Shadow Oak Rd., Danville, CA 94526); Wasley, Richard J. (4290 Colgate Way, Livermore, CA 94550)

1981-01-01T23:59:59.000Z

92

Wire Wrapped Hexagonal Pin Arrays for Hydride Fueled PWRs  

E-Print Network (OSTI)

This work contributes to the Hydride Fuels Project, a collaborative effort between UC Berkeley and MIT

Diller, Peter

93

Activated aluminum hydride hydrogen storage compositions and uses thereof  

SciTech Connect

In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

2010-11-23T23:59:59.000Z

94

Hydriding and dehydriding characteristics of LiBH{sub 4} and transition metals-added magnesium hydride  

SciTech Connect

Graphical abstract: Hydriding reaction curves under 12 bar H{sub 2}, and dehydriding reaction curves under 1.0 bar H{sub 2}, at 593 K at the 1st cycle for MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti and MgH{sub 2}. Highlights: ? Addition of Ni, LiBH{sub 4}, and Ti to MgH{sub 2} to increase reaction rates. ? Sample preparation by reactive mechanical grinding. ? At n = 2, the sample absorbed 4.05 wt% H for 60 min at 593 K under 12 bar H{sub 2}. ? Analysis of rate-controlling step for dehydriding of the sample at n = 3. - Abstract: In this study, MgH{sub 2} was used as a starting material instead of Mg. Ni, Ti, and LiBH{sub 4} with a high hydrogen-storage capacity of 18.4 wt% were added. A sample with a composition of MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti was prepared by reactive mechanical grinding. The activation of MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti was completed after the first hydriding–dehydrding cycle. The hydriding rate decreases as the temperature increases due to the decrease in the driving force for the hydriding reaction. At the 1st cycle, the sample desorbs 1.45 wt% H for 10 min, 2.54 wt% H for 20 min, 3.13 wt% H for 30 min, and 3.40 wt% H for 60 min at 593 K under 1.0 bar H{sub 2}. At the 2nd cycle, the sample absorbs 3.84 wt% H for 5 min, 3.96 wt% H for 10 min, and 4.05 wt% H for 60 min at 593 K under 12 bar H{sub 2}. MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti after reactive mechanical grinding contained MgH{sub 2}, Mg, Ni, TiH{sub 1.924}, and MgO phases. The reactive mechanical grinding of Mg with Ni, LiBH{sub 4}, and Ti is considered to create defects on the surface and in the interior of Mg (to facilitate nucleation), and to reduce the particle size of Mg (to shorten diffusion distances of hydrogen atoms). The formation of Mg{sub 2}Ni during hydriding–dehydriding cycling increases the hydriding and dehydriding rates of the sample.

Song, Myoung Youp, E-mail: songmy@jbnu.ac.kr [Division of Advanced Materials Engineering, Hydrogen and Fuel Cell Research Center, Engineering Research Institute, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, 561-756 (Korea, Republic of); Kwak, Young Jun; Lee, Seong Ho [Department of Materials Engineering, Graduate School, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, 561-756 (Korea, Republic of); Park, Hye Ryoung [Faculty of Applied Chemical Engineering, Chonnam National University, 300 Yongbongdong, Bukgu, Gwangju, 500-757 (Korea, Republic of)

2013-07-15T23:59:59.000Z

95

Hydrogen-storing hydride complexes  

DOE Patents (OSTI)

A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

Srinivasan, Sesha S. (Tampa, FL); Niemann, Michael U. (Venice, FL); Goswami, D. Yogi (Tampa, FL); Stefanakos, Elias K. (Tampa, FL)

2012-04-10T23:59:59.000Z

96

E-Print Network 3.0 - automated hydride generation-cryotrapping...  

NLE Websites -- All DOE Office Websites (Extended Search)

Beds... Laboratories Hydride DevelopmentHydride Development for Hydrogen Storagefor Hydrogen Storage Karl Gross Sandia... using light-weight reversible hydrides The lack of a...

97

Quantitative Infrared Intensity Studies of Vapor-Phase Glyoxal, Methylglyoxal, and 2,3-Butanedione (Diacetyl) with Vibrational Assignments  

SciTech Connect

Glyoxal, methylglyoxal and 2,3-butanedione (diacetyl) are all known biomass burning effluents and suspected aerosol precursors. Pressure-broadened quantitative infrared spectra of glyoxal, methylglyoxal and diacetyl vapors covering the 520–6500 cm?1 range are reported at 0.11 cm?1 resolution, each with a composite spectrum derived from a minimum of ten different sample pressures for the compound, representing some of the first quantitative data for these analytes. The ordinate corresponds to a 1 meter optical pathlength and a mixing ratio of 1ppmv at 296 K. Many vibrational assignments for methylglyoxal are reported for the first time, as are some near-IR and far-IR bands of glyoxal and diacetyl. To complete the vibrational assignments, the quantitative far-infrared spectra (25 to 600 cm-1) of all three vapors are also reported, methylglyoxal for the first time. Density functional theory and ab initio MP2 theory are used to help assign vibrational modes. Potential bands useful for atmospheric monitoring are discussed.

Profeta, Luisa T.; Sams, Robert L.; Johnson, Timothy J.; Williams, Stephen D.

2011-09-08T23:59:59.000Z

98

X-ray determination of threading dislocation densities in GaN/Al{sub 2}O{sub 3}(0001) films grown by metalorganic vapor phase epitaxy  

SciTech Connect

Densities of a- and a+c-type threading dislocations for a series of GaN films grown in different modes by metalorganic vapor phase epitaxy are determined from the x-ray diffraction profiles in skew geometry. The reciprocal space maps are also studied. Theory of x-ray scattering from crystals with dislocations is extended in order to take into account contribution from both threading and misfit dislocations. The broadening of the reciprocal space maps along the surface normal and the rotation of the intensity distribution ellipse is attributed to misfit dislocations at the interface. We find that the presence of a sharp AlN/GaN interface leads to an ordering of misfit dislocations and reduces strain inhomogeneity in GaN films.

Kopp, Viktor S., E-mail: victor.kopp@pdi-berlin.de; Kaganer, Vladimir M. [Paul-Drude-Institut für Festkörperelektronik, Hausvogteiplatz 5–7, 10117 Berlin (Germany); Baidakova, Marina V.; Lundin, Wsevolod V.; Nikolaev, Andrey E.; Verkhovtceva, Elena V.; Yagovkina, Maria A. [Ioffe Physical-Technical Institute of the Russian Academy of Sciences, Politekhnicheskaya 26, 194021 St.-Petersburg (Russian Federation); Cherkashin, Nikolay [CEMES-CNRS and Université de Toulouse, 29 rue J. Marvig, 31055 Toulouse (France)

2014-02-21T23:59:59.000Z

99

Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels, Phase 2: Evaluations of Field Samples and Laboratory Blends  

SciTech Connect

Study to measure the flammability of gasoline/ethanol fuel vapors at low ambient temperatures and develop a mathematical model to predict temperatures at which flammable vapors were likely to form.

Gardiner, D. P.; Bardon, M. F.; LaViolette, M.

2010-04-01T23:59:59.000Z

100

Synchroton X-Ray Studies of Liquid-Vapor Interfaces  

Science Journals Connector (OSTI)

The variation of density across the liquid-vapor interface from essentially zero density far out in the vapor phase to a homogeneous density deep in the liquid phase can be determined by X-ray reflectivity mea...

J. Als-Nielsen

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Organometallic Vapor Phase Epitaxy of n-GaSb and n-GaInAsSb for Low Resistance Ohmic Contacts  

SciTech Connect

A comparison of n-GaSb and n-GaInAsSb epilayers for ohmic contacts in GaSb-based devices is studied. The epilayers were grown by organometallic vapor phase epitaxy and doped with Te. At similar electron concentrations, the atomic Te concentration, as determined by secondary ion mass spectroscopy, is more than 2 times higher in n-GaSb compared to n-GaInAsSb. In addition, the electron mobility is lower in n-GaSb than n-GaInAsSb at similar electron concentrations. The electron concentration saturates at about 1.3 x 10{sup 18} cm{sup -3} for n-GaSb, but linearly increases for n-GaInAsSb. Pd/Ge/Au/Pt/Au metallization was studied for ohmic contacts. A specific contact resistivity of 1 x 10{sup -5}{Omega}-cm{sup 2} for n-GaSb was measured. The specific contact resistivity can be greatly improved by contacting n-GaInAsSb, and a significantly lower specific contact resistivity of 2 x 10{sup -6} {Omega}-cm{sup 2} for n-GaInAsSb was measured.

C.A. Wang; D.A. Shiau; R.K. Huang; C.T. Harris; M.K. Connors

2003-07-10T23:59:59.000Z

102

Draft of M2 Report on Integration of the Hybrid Hydride Model into INL’s MBM Framework for Review  

SciTech Connect

This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride {delta}-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. This document demonstrates a basic hydride precipitation model that is built on a recently developed hybrid Potts-phase field model that combines elements of Potts-Monte Carlo and the phase-field models (Homer et al., 2013; Tikare and Schultz, 2012). The model capabilities are demonstrated along with the incorporation of the starting microstructure, thermodynamics of the Zr-H system and the hydride formation mechanism.

Tikare, Veena; Weck, Philippe F.; Schultz, Peter A.; Clark, Blythe; Michael Glazoff; Eric Homer

2014-07-01T23:59:59.000Z

103

Encapsulated Metal Hydride for Hydrogen Separation  

E-Print Network (OSTI)

concentration feed stock, not for low concentration � Hydrogen economy will need hydrogen recovery from lowEncapsulated Metal Hydride for Hydrogen Separation (Formerly Separation Membrane Development) DOE Hydrogen Program 2003 Merit Review and Peer Evaluation L. Kit Heung, Jim Congdon Savannah River Technology

104

Ductility Evaluation of As-Hydrided and Hydride Reoriented Zircaloy-4 Cladding under Simulated Dry-Storage Condition  

SciTech Connect

Pre-storage drying-transfer operations and early stage storage expose cladding to higher temperatures and much higher pressure-induced tensile hoop stresses relative to normal operation in-reactor and pool storage under these conditions. Radial hydrides could precipitate during slow cooling and provide an additional embrittlement mechanism as the cladding temperature decreases below the ductile-to-brittle transition temperature. As a means of simulating this behavior, unirradiated hydrided Zircaloy-4 samples were fabricated by a gas charging method to levels that encompass the range of hydrogen concentrations observed in current used fuel. Mechanical testing was carried out by the ring compression test (RCT) method at various temperatures to evaluate the sample s ductility for both as-hydrided and post-hydride reorientation treated specimens. As-hydrided samples with higher hydrogen concentration (>800 ppm) resulted in lower strain before fracture and reduced maximum load. Increasing RCT temperatures resulted in increased ductility of the as-hydrided cladding. A systematic radial hydride treatment was conducted at various pressures and temperatures for the hydrided samples with H content around 200 ppm. Following the radial hydride treatment, RCTs on the hydride reoriented samples were conducted and exhibited lower ductility compared to as-hydrided samples.

Yan, Yong [ORNL] [ORNL; Plummer, Lee K [ORNL] [ORNL; Ray, Holly B [ORNL] [ORNL; Cook, Tyler S [ORNL] [ORNL; Bilheux, Hassina Z [ORNL] [ORNL

2014-01-01T23:59:59.000Z

105

Development of encapsulated lithium hydride thermal energy storage for space power systems  

SciTech Connect

Inclusion of thermal energy storage in a pulsed space power supply will reduce the mass of the heat rejection system. In this mode, waste heat generated during the brief high-power burst operation is placed in the thermal store; later, the heat in the store is dissipated to space via the radiator over the much longer nonoperational period of the orbit. Thus, the radiator required is of significantly smaller capacity. Scoping analysis indicates that use of lithium hydride as the thermal storage medium results in system mass reduction benefits for burst periods as long as 800 s. A candidate design for the thermal energy storage component utilizes lithium hydride encapsulated in either 304L stainless steel or molybdenum in a packed-bed configuration with a lithium or sodium-potassium (NaK) heat transport fluid. Key issues associated with the system design include phase-change induced stresses in the shell, lithium hydride and shell compatibility, lithium hydride dissociation and hydrogen loss from the system, void presence and movement associated with the melt-freeze process, and heat transfer limitations on obtaining the desired energy storage density. 58 refs., 40 figs., 11 tabs.

Morris, D.G.; Foote, J.P.; Olszewski, M.

1987-12-01T23:59:59.000Z

106

Phase-Transfer-Catalyzed Reductions  

Science Journals Connector (OSTI)

Phase-transfer catalysis (PTC) procedures that have been developed for use with sodium borohydride, lithium aluminum hydride, and several other reducing agents involving anion transfer to organic media are des...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

107

Three-Phase Vapor?Liquid?Liquid Equilibria for Methane + n-Octane + Monoethylene Glycol + Water at Pressures from (3.1 to 15.0) MPa and Temperatures from (281 to 363) K  

Science Journals Connector (OSTI)

There are several commercial processes available for the dehydration of gas, such as the use of liquid or solid desiccants and expansion refrigeration. ... The gaseous part of the liquid samples, and the gas phase samples direct from the equilibrium cell, were expanded into a series of evacuated vessels of known volume from which the total amount of substance was determined from the perfect gas equation using the measured low-pressure PVT data. ... To predict the losses of MEG in processes for the dehydration of natural gas, the concentrations of MEG in the vapor phase are of interest to the gas industry. ...

Stanley J. Ashcroft; Gerd Brunner; Hansjörg Vollmer; Christopher W. Sweeney

2009-03-06T23:59:59.000Z

108

HYDRIDE-RELATED DEGRADATION OF SNF CLADDING UNDER REPOSITORY CONDITIONS  

SciTech Connect

The purpose and scope of this analysis/model report is to analyze the degradation of commercial spent nuclear fuel (CSNF) cladding under repository conditions by the hydride-related metallurgical processes, such as delayed hydride cracking (DHC), hydride reorientation and hydrogen embrittlement, thereby providing a better understanding of the degradation process and clarifying which aspects of the process are known and which need further evaluation and investigation. The intended use is as an input to a more general analysis of cladding degradation.

K. McCoy

2000-12-12T23:59:59.000Z

109

Dissipative hydride precipitates in superconducting niobium cavities  

SciTech Connect

We report the first direct observation of the microstructural features exhibiting RF losses at high surface magnetic fields of above 100 mT in field emission free superconducting niobium cavities. The lossy areas were identified by advanced thermometry. Surface investigations using different techniques were carried out on cutout samples from lossy areas and showed the presence of dendritic niobium hydrides. This finding has possible implications to the mechanisms of RF losses in superconducting niobium at all field levels.

Romanenko, A.; Cooley, L.D.; /Fermilab; Ciovati, G.; / /Jefferson Lab; Wu, G.; /Argonne

2011-10-01T23:59:59.000Z

110

Proposed Virtual Center for Excellence for Metal Hydride Development...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Virtual Center for Excellence for Metal Hydride Development Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC....

111

Mathematical modelling of a metal hydride hydrogen storage system.  

E-Print Network (OSTI)

??In order for metal hydride hydrogen storage systems to compete with existing energy storage technology, such as gasoline tanks and batteries, it is important to… (more)

MacDonald, Brendan David

2009-01-01T23:59:59.000Z

112

E-Print Network 3.0 - antimony hydrides Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

and Sb(V) were the only hydride-forming species found... WATERS BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY Water-Resources Investigations Report 03... Prior to the...

113

E-Print Network 3.0 - americium hydrides Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

and complete processing... facility for hydride research 12;BNL Current Research in Hydrogen Storage Complex metal hydride ... Source: DOE Office of Energy Efficiency and...

114

LANL/PNNL Virtual Center for Chemical Hydrides and New Concepts...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage...

115

E-Print Network 3.0 - argon hydrides Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Polytechnique, Centre de mathmatiques Collection: Mathematics 4 Complex Hydrides for Hydrogen Storage Darlene K. Slattery and Michael D. Hampton Summary: Complex Hydrides for...

116

Long Term Field Development of a Surfactant Modified Zeolite/Vapor Phase Bioreactor System for Treatment of Produced Waters for Power Generation  

SciTech Connect

The main goal of this research was to investigate the feasibility of using a combined physicochemical/biological treatment system to remove the organic constituents present in saline produced water. In order to meet this objective, a physical/chemical adsorption process was developed and two separate biological treatment techniques were investigated. Two previous research projects focused on the development of the surfactant modified zeolite adsorption process (DE-AC26-99BC15221) and development of a vapor phase biofilter (VPB) to treat the regeneration off-gas from the surfactant modified zeolite (SMZ) adsorption system (DE-FC26-02NT15461). In this research, the SMZ/VPB was modified to more effectively attenuate peak loads and to maintain stable biodegradation of the BTEX constituents from the produced water. Specifically, a load equalization system was incorporated into the regeneration flow stream. In addition, a membrane bioreactor (MBR) system was tested for its ability to simultaneously remove the aromatic hydrocarbon and carboxylate components from produced water. The specific objectives related to these efforts included the following: (1) Optimize the performance VPBs treating the transient loading expected during SMZ regeneration: (a) Evaluate the impact of biofilter operating parameters on process performance under stable operating conditions. (b) Investigate how transient loads affect biofilter performance, and identify an appropriate technology to improve biological treatment performance during the transient regeneration period of an SMZ adsorption system. (c) Examine the merits of a load equalization technology to attenuate peak VOC loads prior to a VPB system. (d) Evaluate the capability of an SMZ/VPB to remove BTEX from produced water in a field trial. (2) Investigate the feasibility of MBR treatment of produced water: (a) Evaluate the biodegradation of carboxylates and BTEX constituents from synthetic produced water in a laboratory-scale MBR. (b) Evaluate the capability of an SMZ/MBR system to remove carboxylates and BTEX from produced water in a field trial. Laboratory experiments were conducted to provide a better understanding of each component of the SMZ/VPB and SMZ/MBR process. Laboratory VPB studies were designed to address the issue of influent variability and periodic operation (see DE-FC26-02NT15461). These experiments examined multiple influent loading cycles and variable concentration loadings that simulate air sparging as the regeneration option for the SMZ system. Two pilot studies were conducted at a produced water processing facility near Farmington, New Mexico. The first field test evaluated SMZ adsorption, SMZ regeneration, VPB buffering, and VPB performance, and the second test focused on MBR and SMZ/MBR operation. The design of the field studies were based on the results from the previous field tests and laboratory studies. Both of the biological treatment systems were capable of removing the BTEX constituents in the laboratory and in the field over a range of operating conditions. For the VPB, separation of the BTEX constituents from the saline aqueous phase yielded high removal efficiencies. However, carboxylates remained in the aqueous phase and were not removed in the combined VPB/SMZ system. In contrast, the MBR was capable of directly treating the saline produced water and simultaneously removing the BTEX and carboxylate constituents. The major limitation of the MBR system is the potential for membrane fouling, particularly when the system is treating produced water under field conditions. The combined process was able to effectively pretreat water for reverse osmosis treatment and subsequent downstream reuse options including utilization in power generation facilities. The specific conclusions that can be drawn from this study are summarized.

Lynn Katz; Kerry Kinney; Robert Bowman; Enid Sullivan; Soondong Kwon; Elaine Darby; Li-Jung Chen; Craig Altare

2007-12-31T23:59:59.000Z

117

Calibrated vapor generator source  

DOE Patents (OSTI)

A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

1995-09-26T23:59:59.000Z

118

Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems  

SciTech Connect

HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNL’s metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800°C). A high-temperature tank in PNNL’s storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNL’s thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

None

2011-12-05T23:59:59.000Z

119

Nano-engineering of magnesium hydride for hydrogen storage  

Science Journals Connector (OSTI)

The destabilization of magnesium hydride (MgH"2) by solid-state reaction with Si in a nanoscale under vacuum was studied. The nanostructured Si films were deposited on the nanocrystalline MgH"2/Mg composite substrate by the pulsed laser deposition (PLD). ... Keywords: Destabilization, Magnesium hydride, Microstructure, Nano-engineering, Silicon

J. Bystrzycki; T. P?oci?ski; W. Zieli?ski; Z. Winiewski; M. Polanski; W. Mróz; Z. Bojar; K. J. Kurzd?owski

2009-04-01T23:59:59.000Z

120

Spray structures and vaporizing characteristics of a GDI fuel spray  

Science Journals Connector (OSTI)

The spray structures and distribution characteristics of liquid and vapor phases in non-evaporating and evaporating Gasoline Direct Injection (GDI) fuel sprays were investigated using Laser Induced...

Dong-Seok Choi; Gyung-Min Choi; Duck-Jool Kim

2002-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities Irradiation is known to have a significant impact on the properties and performance of Zircaloy cladding and structural materials (material degradation processes, e.g., effects of hydriding). This UFD study examines the behavior and performance of unirradiated cladding and actual irradiated cladding through testing and simulation. Three capsules containing hydrogen-charged Zircaloy-4 cladding material have been placed in the High Flux Isotope Reactor (HFIR). Irradiation of the capsules was conducted for post-irradiation examination (PIE) metallography. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of

122

Recent advances in metal hydrides for clean energy applications  

SciTech Connect

Metal hydrides are a fascinating class of materials that can be utilized for a surprising variety of clean energy applications, including smart solar collectors, smart windows, sensors, thermal energy storage, and batteries, in addition to their traditional application for hydrogen storage. Over the past decade, research on metal hydrides for hydrogen storage increased due to global governmental incentives and an increased focus on hydrogen storage research for polymer electrolyte membrane fuel cell operation. Tremendous progress has been made in so-called complex metal hydrides for hydrogen storage applications with the discovery of many new hydrides containing covalently bound complex anions. Many of these materials have applications beyond hydrogen storage and are being investigated for lithium-ion battery separator and anode materials. In this issue of MRS Bulletin , we present the state of the art of key evolving metal-hydride-based clean energy technologies with an outlook toward future needs.

Ronnebro, Ewa; Majzoub, Eric H.

2013-06-01T23:59:59.000Z

123

Porous metal hydride composite and preparation and uses thereof  

DOE Patents (OSTI)

A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

Steyert, W.A.; Olsen, C.E.

1980-03-12T23:59:59.000Z

124

Porous metal hydride composite and preparation and uses thereof  

DOE Patents (OSTI)

A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

Steyert, William A. (Los Alamos, NM); Olsen, Clayton E. (Los Alamos, NM)

1982-01-01T23:59:59.000Z

125

Metal hydride fuel storage and method thereof  

DOE Patents (OSTI)

An apparatus having a first substrate having (1) a cavity, (2) one or more resistive heaters, and (3) one or more coatings forming a diffusion barrier to hydrogen; a second substrate having (1) an outlet valve comprising a pressure relief structure and (2) one or more coatings forming a diffusion barrier to hydrogen, wherein said second substrate is coupled to said first substrate forming a sealed volume in said cavity; a metal hydride material contained within said cavity; and a gas distribution system formed by coupling a microfluidic interconnect to said pressure relief structure. Additional apparatuses and methods are also disclosed.

Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

2010-08-10T23:59:59.000Z

126

Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity  

SciTech Connect

The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ? 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ? 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150°C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination

Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

2008-02-18T23:59:59.000Z

127

Anisotropic behavior and rupture of hydrided Zircaloy-4 sheets  

SciTech Connect

In a French pressurized water reactor (PWR), most of the structural parts of the fuel assembly consist of zirconium alloys (ZIRCALOY-2). The mechanical behavior of ZIRCALOY-4 sheets is investigated at room temperature. The effect of hydride precipitation on the mechanical behavior and on the rupture mechanism is also studied, in the range from 200 to 1,200 wt ppm hydrogen and for different stress triaxialities. It is shown that the material exhibits a strong anisotropy die to its pronounced texture, and that its mechanical properties depend on the strain rate. Hydride precipitation appears to have no effect on the anisotropy or on the strain-rate sensitivity, in the range from 10{sup {minus}4} to 10{sup {minus}2} s{sup {minus}1}. The main effect of hydrogen is the reduction of the ductility and of crack resistance. The ductile rupture mechanism is studied, focusing on the stage of damage nucleation by hydride fracture. Observations during scanning electron microscopy (SEM) in situ tests show that hydrides allow the transmission of slip, which occurs in ZIRCALOY-4 grains. Hydrides can also deform, together with surrounding zirconium matrix. Damage appears after a plastic-strain yield of about 14 to 25 pct. Fracture occurs first on intergranular hydrides. Fracture of transgranular hydrides is observed only prior to failure, for higher plastic strains.

Grange, M.; Besson, J.; Andrieu, E.

2000-03-01T23:59:59.000Z

128

ARM Water Vapor IOP  

NLE Websites -- All DOE Office Websites (Extended Search)

ARM Water Vapor IOP The SGP CART site will host the third ARM water vapor IOP on September 18-October 8, 2000. The CART site is home to a powerful array of instruments capable of...

129

Chemical Hydride Slurry for Hydrogen Production and Storage  

SciTech Connect

The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: • Magnesium hydride slurry is stable for months and pumpable. • The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. • Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. • The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. • The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (“Milk of Magnesia”) and magnesium oxide. • We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

McClaine, Andrew W.

2008-09-30T23:59:59.000Z

130

Process for production of a metal hydride  

DOE Patents (OSTI)

A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

2014-08-12T23:59:59.000Z

131

Novel Hydride Transfer Catalysis for Carbohydrate Conversions  

SciTech Connect

5-Hydroxymethylfurfural (HMF), an important versatile sugar derivative has been synthesized from glucose using catalytic amounts of CrCl2 in 1-ethyl-3-methylimidizolium chloride. Glycerol and glyceraldehyde were tested as sugar model compounds. Glycerol is unreactive and does not interfere with glucose conversion. Glyceraldehyde is reactive and does interfere with glucose conversion in competitive experiments. MnCl2 or FeCl2 catalyze dehydration of glyceraldehyde dimer to form compound I, a cyclic hemiacetal with an exocyclic double bond. Upon aqueous work-up I forms pyruvaldehyde. CrCl2 or VCl3 further catalyze a hydride transfer of I to form lactide. Upon aqueous work-up lactide is converted to lactic acid.

Holladay, John E.; Brown, Heather M.; Appel, Aaron M.; Zhang, Z. Conrad

2008-04-03T23:59:59.000Z

132

Steps to Commercialization: Nickel Metal Hydride Batteries | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries October 17, 2011 - 10:42am Addthis Steps to Commercialization: Nickel Metal Hydride Batteries Matthew Loveless Matthew Loveless Data Integration Specialist, Office of Public Affairs How does it work? Through licensing and collaborative work, Energy Department-sponsored research can yield great economic benefits and help bring important new products to market. The Energy Department funds cutting-edge research on a broad range of topics ranging from advanced battery construction to the modeling of industrial processes and supercomputer simulation of supernovae. But this research is not only about furthering our understanding of the world around

133

Metal Hydride Chemical Heat Pumps for Industrial Use  

E-Print Network (OSTI)

Hydriding alloys are intermetallic absorbent compounds which have the remarkable quality of absorbing very large quantities of hydrogen gas per unit volume of metallic powder. The absorption and desorption of hydrogen are exothermic and endothermic...

Ally, M. R.; Rebello, W. J.; Rosso, M. J., Jr.

1984-01-01T23:59:59.000Z

134

High capacity stabilized complex hydrides for hydrogen storage  

DOE Patents (OSTI)

Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

2014-11-11T23:59:59.000Z

135

Delayed hydride cracking behavior for ZIRCALOY-2 tubing  

Science Journals Connector (OSTI)

The delayed hydride cracking (DHC) behavior for ZIRCALOY-2 tubing was characterized at temperatures ranging from 93 °C to 288 °C. Testing was performed on the three types of pressure tubes that were used in th...

F. H. Huang; W. J. Mills

1991-09-01T23:59:59.000Z

136

Development of a metal hydride electrode waste treatment process  

SciTech Connect

Manufacturing residues of metal hydride electrodes for nickel - metal hydride batteries were chemically processed to recover the metal part and heat treated for the organic part. Chemical recovery yielded Ni-Co alloy after electrolysis of the solution and hydroxides of other metal, mainly rare earths. The organic part, pyrolyzed at 700 C, led to separation between carbon and fluorinated matter. Infrared coupling at the output of the pyrolysis furnace was used to identify the pyrolysis gases.

Bianco, J.C.; Martin, D.; Ansart, F.; Castillo, S.

1999-12-01T23:59:59.000Z

137

Development of the Low-Pressure Hydride/Dehydride Process  

SciTech Connect

The low-pressure hydride/dehydride process was developed from the need to recover thin-film coatings of plutonium metal from the inner walls of an isotope separation chamber located at Los Alamos and to improve the safety operation of a hydride recovery process using hydrogen at a pressure of 0.7 atm at Rocky Flats. This process is now the heart of the Advanced Recovery and Integrated Extraction System (ARIES) project.

Rueben L. Gutierrez

2001-04-01T23:59:59.000Z

138

InGaAs heterostructure formation in catalyst-free GaAs nanopillars by selective-area metal-organic vapor phase epitaxy  

SciTech Connect

We investigate axial GaAs/InGaAs/GaAs heterostructures embedded in GaAs nanopillars via catalyst-free selective-area metal-organic chemical vapor deposition. Structural characterization by transmission electron microscopy with energy dispersive x-ray spectroscopy (EDS) indicates formation of axial In{sub x}Ga{sub 1-x}As (x{approx}0.20) inserts with thicknesses from 36 to 220 nm with {+-}10% variation and graded Ga:In transitions controlled by In segregation. Using the heterointerfaces as markers, the vertical growth rate is determined to increase linearly during growth. Photoluminescence from 77 to 290 K and EDS suggest the presence of strain in the shortest inserts. This capability to control the formation of axial nanopillar heterostructures is crucial for optimized device integration.

Shapiro, J. N.; Lin, A.; Wong, P. S.; Scofield, A. C.; Tu, C.; Senanayake, P. N.; Mariani, G.; Liang, B. L.; Huffaker, D. L. [Department of Electrical Engineering and California Nano-Systems Institute, University of California at Los Angeles, Los Angeles, California 90095 (United States)

2010-12-13T23:59:59.000Z

139

OBSERVATIONS IN REACTIVITY BETWEEN BH CONTAINING COMPOUNDS AND ORGANOMETALLIC REAGENTS: SYNTHESIS OF BORONIC ACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES  

E-Print Network (OSTI)

Reaction of BH 3 :THF with magnesium hydride byproduct. A.It was also observed that magnesium hydride can partiallyACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES A dissertation

Clary, Jacob William

2012-01-01T23:59:59.000Z

140

Charge transport properties of p-CdTe/n-CdTe/n{sup +}-Si diode-type nuclear radiation detectors based on metalorganic vapor-phase epitaxy-grown epilayers  

SciTech Connect

Charge transport properties of p-CdTe/n-CdTe/n{sup +}-Si diode-type nuclear radiation detectors, fabricated by growing p-and n-type CdTe epilayers on (211) n{sup +}-Si substrates using metalorganic vapor-phase epitaxy (MOVPE), were studied by analyzing current-voltage characteristics measured at various temperatures. The diode fabricated shows good rectification properties, however, both forward and reverse biased currents deviate from their ideal behavior. The forward current exhibits typical feature of multi-step tunneling at lower biases; however, becomes space charge limited type when the bias is increased. On the other hand, the reverse current exhibits thermally activated tunneling-type current. It was found that trapping centers at the p-CdTe/n-CdTe junction, which were formed due to the growth induced defects, determine the currents of this diode, and hence limit the performance of the nuclear radiation detectors developed.

Niraula, M.; Yasuda, K.; Wajima, Y.; Yamashita, H.; Tsukamoto, Y.; Suzuki, Y.; Matsumoto, M.; Takai, N.; Tsukamoto, Y.; Agata, Y. [Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555 (Japan)] [Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555 (Japan)

2013-10-28T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Vapor spill monitoring method  

DOE Patents (OSTI)

Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

1985-01-01T23:59:59.000Z

142

Influence of uranium hydride oxidation on uranium metal behaviour  

SciTech Connect

This work addresses concerns that the rapid, exothermic oxidation of active uranium hydride in air could stimulate an exothermic reaction (burning) involving any adjacent uranium metal, so as to increase the potential hazard arising from a hydride reaction. The effect of the thermal reaction of active uranium hydride, especially in contact with uranium metal, does not increase in proportion with hydride mass, particularly when considering large quantities of hydride. Whether uranium metal continues to burn in the long term is a function of the uranium metal and its surroundings. The source of the initial heat input to the uranium, if sufficient to cause ignition, is not important. Sustained burning of uranium requires the rate of heat generation to be sufficient to offset the total rate of heat loss so as to maintain an elevated temperature. For dense uranium, this is very difficult to achieve in naturally occurring circumstances. Areas of the uranium surface can lose heat but not generate heat. Heat can be lost by conduction, through contact with other materials, and by convection and radiation, e.g. from areas where the uranium surface is covered with a layer of oxidised material, such as burned-out hydride or from fuel cladding. These rates of heat loss are highly significant in relation to the rate of heat generation by sustained oxidation of uranium in air. Finite volume modelling has been used to examine the behaviour of a magnesium-clad uranium metal fuel element within a bottle surrounded by other un-bottled fuel elements. In the event that the bottle is breached, suddenly, in air, it can be concluded that the bulk uranium metal oxidation reaction will not reach a self-sustaining level and the mass of uranium oxidised will likely to be small in relation to mass of uranium hydride oxidised. (authors)

Patel, N.; Hambley, D. [National Nuclear Laboratory (United Kingdom); Clarke, S.A. [Sellafield Ltd (United Kingdom); Simpson, K.

2013-07-01T23:59:59.000Z

143

ARM - Water Vapor  

NLE Websites -- All DOE Office Websites (Extended Search)

Water Vapor Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global...

144

Aerogel composites using chemical vapor infiltration  

NLE Websites -- All DOE Office Websites (Extended Search)

Aerogel composites using chemical vapor infiltration Aerogel composites using chemical vapor infiltration Title Aerogel composites using chemical vapor infiltration Publication Type Journal Article Year of Publication 1995 Authors Hunt, Arlon J., Michael R. Ayers, and Wanqing Cao Journal Journal of Non-Crystalline Solids Volume 185 Pagination 227-232 Abstract A new method to produce novel composite materials based on the use of aerogels as a starting material is described. Using chemical vapor infiltration, a variety of solid materials were thermally deposited into the open pore structure of aerogel. The resulting materials possess new and unusual properties including photoluminescence, magnetism and altered optical properties. An important characteristic of this preparation process is the very small size of the deposits that gives rise to new behaviors. Silicon deposits exhibit photoluminescence, indicating quantum confinement. Two or more phases may be deposited simultaneously and one or both chemically or thermally reacted to produce new structures.

145

Synthesis and characterization of metal hydride/carbon aerogel composites for hydrogen storage  

Science Journals Connector (OSTI)

Two materials currently of interest for onboard lightweight hydrogen storage applications are sodium aluminum hydride (NaAlH4), a complex metal hydride, and carbon aerogels (CAs), a light porous material connected by several spherical nanoparticles. ...

Kuen-Song Lin; Yao-Jen Mai; Su-Wei Chiu; Jing-How Yang; Sammy L. I. Chan

2012-01-01T23:59:59.000Z

146

Characterization and High Throughput Analysis of Metal Hydrides for Hydrogen Storage  

E-Print Network (OSTI)

Metal Hydrides for Hydrogen Storage by Steven James BarceloMetal Hydrides for Hydrogen Storage by Steven James BarceloCo-chair Efficient hydrogen storage is required for fuel

Barcelo, Steven James

2009-01-01T23:59:59.000Z

147

Effects on the positive electrode of the corrosion of AB{sub 5} alloys in nickel-metal-hydride batteries  

SciTech Connect

Effects of corrosion of MmNi{sub 4.3{minus}x}Mn{sub 0.3}Al{sub 0.4}Co{sub x} alloys (where Mm = Ce 50%, La 30%, Nd 15%, Pr 5%) are evaluated in nickel-metal-hydride (Ni-MH) cells. Particularly, it is shown how Al released by the corroded alloys pollutes the positive electrode, which endures a loss of charging efficiency, due to the formation of a hydrotalcite-like phase stabilized with Al. Furthermore, since Al is eluted from the hydride electrode and is completely trapped in the positive active material, the titration of this element in the positive electrode is a powerful technique for quantification of the corrosion of AB{sub 5} alloys in Ni-MH cells.

Bernard, P. [SAFT, Marcoussis (France). Research Dept.

1998-02-01T23:59:59.000Z

148

1. Roller J. , Arellano-Jimneza J., Yu H. , Carter C.B., and Maric R., "Catalyst nanoscale assembly from the vapor phase on corrosion resistant supports",  

E-Print Network (OSTI)

and reactive spray deposition technology for low temperature solid oxide fuel cell", Journal of Thermal Spray Temperature Solid Oxide Fuel Cell (LTSOFC) by Reactive Spray Deposition Technology, RSDT, ECS Trans., 35.-P., Stöver, D., "Gas phase deposition of diffusion barriers for metal substrates in solid oxide fuel cells

Alpay, S. Pamir

149

Chemical vapor deposition sciences  

SciTech Connect

Chemical vapor deposition (CVD) is a widely used method for depositing thin films of a variety of materials. Applications of CVD range from the fabrication of microelectronic devices to the deposition of protective coatings. New CVD processes are increasingly complex, with stringent requirements that make it more difficult to commercialize them in a timely fashion. However, a clear understanding of the fundamental science underlying a CVD process, as expressed through computer models, can substantially shorten the time required for reactor and process development. Research scientists at Sandia use a wide range of experimental and theoretical techniques for investigating the science of CVD. Experimental tools include optical probes for gas-phase and surface processes, a range of surface analytic techniques, molecular beam methods for gas/surface kinetics, flow visualization techniques and state-of-the-art crystal growth reactors. The theoretical strategy uses a structured approach to describe the coupled gas-phase and gas-surface chemistry, fluid dynamics, heat and mass transfer of a CVD process. The software used to describe chemical reaction mechanisms is easily adapted to codes that model a variety of reactor geometries. Carefully chosen experiments provide critical information on the chemical species, gas temperatures and flows that are necessary for model development and validation. This brochure provides basic information on Sandia`s capabilities in the physical and chemical sciences of CVD and related materials processing technologies. It contains a brief description of the major scientific and technical capabilities of the CVD staff and facilities, and a brief discussion of the approach that the staff uses to advance the scientific understanding of CVD processes.

NONE

1992-12-31T23:59:59.000Z

150

Opening of a Post Doctoral Position Complex hydrides for hydrogen storage applications  

E-Print Network (OSTI)

Opening of a Post Doctoral Position Complex hydrides for hydrogen storage applications on complex hydrides for hydrogen storage applications in connection with the « Fast, reliable and cost effective boron hydride based high capacity solid state hydrogen storage materials» project co

151

Final Report for the DOE Metal Hydride Center of Excellence  

NLE Websites -- All DOE Office Websites (Extended Search)

SANDIA REPORT SANDIA REPORT SAND2012-0786 Unlimited Release Printed February 2012 Final Report for the DOE Metal Hydride Center of Excellence Lennie Klebanoff Director, Metal Hydride Center of Excellence Jay Keller Deputy Director, Metal Hydride Center of Excellence Prepared by Sandia National Laboratories Albuquerque, New Mexico 87185 and Livermore, California 94550 Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Approved for public release; further dissemination unlimited. Issued by Sandia National Laboratories, operated for the United States Department of Energy

152

Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.  

SciTech Connect

In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

2012-02-01T23:59:59.000Z

153

14 - Hydrogen storage in hydride-forming materials  

Science Journals Connector (OSTI)

Abstract: Hydrogen storage technologies are playing a significant and critical role in the so-called ‘hydrogen economy’: they are used to buffer primary energy sources for time-delayed end-uses. The purpose of this chapter is to review the main hydrogen storage processes and materials, with a special emphasis on chemical storage (metal and chemical hydrides). First, the main hydrogen processes (physical, chemical, electrochemical, geological) are reviewed. Then, reversible hydrogen storage in hydride-forming metals and intermetallics is discussed. Basic principles (thermodynamic properties, sorption mechanisms, kinetics) are presented and the properties of the main materials are listed and compared. Irreversible hydrogen storage in the main classes of chemical hydrides is then described. In the last section, specifications for automotive and stationary applications are reviewed and discussed.

P. Millet

2014-01-01T23:59:59.000Z

154

A coupled transport and solid mechanics formulation with improved reaction kinetics parameters for modeling oxidation and decomposition in a uranium hydride bed.  

SciTech Connect

Modeling of reacting flows in porous media has become particularly important with the increased interest in hydrogen solid-storage beds. An advanced type of storage bed has been proposed that utilizes oxidation of uranium hydride to heat and decompose the hydride, releasing the hydrogen. To reduce the cost and time required to develop these systems experimentally, a valid computational model is required that simulates the reaction of uranium hydride and oxygen gas in a hydrogen storage bed using multiphysics finite element modeling. This SAND report discusses the advancements made in FY12 (since our last SAND report SAND2011-6939) to the model developed as a part of an ASC-P&EM project to address the shortcomings of the previous model. The model considers chemical reactions, heat transport, and mass transport within a hydride bed. Previously, the time-varying permeability and porosity were considered uniform. This led to discrepancies between the simulated results and experimental measurements. In this work, the effects of non-uniform changes in permeability and porosity due to phase and thermal expansion are accounted for. These expansions result in mechanical stresses that lead to bed deformation. To describe this, a simplified solid mechanics model for the local variation of permeability and porosity as a function of the local bed deformation is developed. By using this solid mechanics model, the agreement between our reacting bed model and the experimental data is improved. Additionally, more accurate uranium hydride oxidation kinetics parameters are obtained by fitting the experimental results from a pure uranium hydride oxidation measurement to the ones obtained from the coupled transport-solid mechanics model. Finally, the coupled transport-solid mechanics model governing equations and boundary conditions are summarized and recommendations are made for further development of ARIA and other Sandia codes in order for them to sufficiently implement the model.

Salloum, Maher N.; Shugard, Andrew D.; Kanouff, Michael P.; Gharagozloo, Patricia E.

2013-03-01T23:59:59.000Z

155

Mechanism of the [alpha]-to-[beta] phase transformation in the LaNi[subscript 5]?H[subscript 2] system  

SciTech Connect

High-energy synchrotron in situ X-ray powder diffraction has been used to elucidate the mechanism of the hydriding phase transformation in a LaNi5 model hydrogen storage intermetallic in real time. The transformation proceeds at 10 C via the transient growth of an interfacial phase, the {gamma} phase, with lattice parameters intermediate between those of the {alpha} (dilute solid solution) and {beta} (concentrated hydride) phases. The {gamma} phase forms to partially accommodate the 24% change in unit cell volume between the {alpha} and {beta} phases during hydriding and dehydriding. The {alpha}, {gamma} and {beta} phases coexist at the nanoscopic level.

Gray, E. MacA.; Blach, T.P.; Pitt, M.P.; Cookson, D.J. (Griffith U); (ASRP)

2014-09-24T23:59:59.000Z

156

Brittle fracture induced by hydrides in zircaloy-4  

SciTech Connect

Zircaloy-4 is used as a cladding material in the nuclear industry for fuel elements. Its mechanical properties can be drastically affected by the presence of hydrides, which form when hydrogen content exceeds the terminal solid solubility. This change often manifests itself as a reduction in ductility (elongation and reduction in area), coupled with the evolution of the fracture mode from ductile microvoid nucleation and coalescence to intergranular fracture. It has been found, at room temperature, that Zircaloy-4 undergoes a ductile to brittle transition when the hydrogen content (hydride volume fraction) in the specimen is higher than some critical value depending on the microstructure and the hydride morphology. Heat treatment of the material can shift the transition end point from 1050 ppm wt H for the stress-relieved state to 100-150 ppm wt H for the {beta} treated state, thus strongly suggesting that there may be some relationship between the microstructure (grain size and shape) and the ductile-brittle transition. It has also been reported that for the same hydriding condition, the hydrogen absorption rate is higher for the stress-relieved and recrystallized states and lower for the {beta} treated state. This phenomenon is very important for engineering applications because it is related to the determination of the safe life. Insufficient attention has been drawn to the quantitative evaluation and the modelization of the influence of the microstructure on the ductile-brittle transition in hydrided Zircaloy-4, though there has been some general research on the boundary structural effect on intergranular fracture. The present authors attempt to modelize this influence by an upper-limit model using the results of image analysis on the microstructures and tensile tests on hydrided sheet specimens.

Bai, J.B.; Francois, D.; Prioul, C. (Lab. MSS/MAT CNRS URA 850, Ecole Centrale Paris, 92295 Chatenay Malabry Cedex (FR)); Lansiart, S. (CEA/DTA/CEREM/DTM/SRMA, C.E. Saclay, 91191 Gif-sur-Yvette Cedex (FR))

1991-11-01T23:59:59.000Z

157

Characterization of particle- and vapor-phase organic fraction emissions from a heavy-duty diesel engine equipped with a particle trap and regeneration controls  

SciTech Connect

The effects of a ceramic particle trap on the chemical and biological character of the exhaust from a heavy-duty diesel engine have been studied during steady-state operation and during periods of trap regeneration. Phase I of this project involved developing and refining the methods using a Caterpillar 3208 engine, and Phase II involved more detailed experiments with a Cummins LTA10-300 engine, which met Federal 1988 particulate matter standards, and a ceramic particle trap with built-in regeneration controls. During the Phase I experiments, samples wee collected at the Environmental Protection Agency (EPA)* steady-state mode 4 (50% load at intermediate speed). Varying the dilution ratio to obtain a constant filter-face temperature resulted in less variability in total particulate matter (TPM), particle-associated soluble organic fraction (SOF), solids (SOL), and polynuclear aromatic hydrocarbon (PAH) levels than sampling with a constant dilution ratio and allowing filter-face temperature to vary. A modified microsuspension Ames assay detected mutagenicity in the SOF samples, and in the semivolatile organic fraction extracted from XAD-2 resin (XAD-2 resin organic component, XOC) with at least 10 times less sample mass than the standard plate incorporation assay. Measurement techniques for PAH and nitro-PAH in the SOF and XOC also were developed during this portion of the project. For the Phase II work, two EPA steady-state rated speed modes were selected: mode 11 (25% load) and mode 9 (75% load). With or without the trap, filter-face temperatures were kept at 45 degrees +/- 2 degrees C, nitrogen dioxide (NO2) levels less than 5 parts per million (ppm), and sampling times less than 60 minutes. Particle sizes were determined using an electrical aerosol analyzer. Similar sampling methods were used when the trap was regenerated, except that a separate dilution tunnel and sampling system was designed and built to collect all of the regeneration emissions.

Bagley, S.T.; Gratz, L.D.; Leddy, D.G.; Johnson, J.H. (Michigan Technological Univ., Houghton, MI (United States))

1993-07-01T23:59:59.000Z

158

System for exchange of hydrogen between liquid and solid phases  

DOE Patents (OSTI)

The reversible reaction M + x/2 H/sub 2/ reversible MH/sub x/, wherein M is a reversible metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the actual H/sub 2/ pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the actual pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

Reilly, J.J.; Grohse, E.W.; Johnson, J.R.; Winsche, W.E.

1985-02-22T23:59:59.000Z

159

System for exchange of hydrogen between liquid and solid phases  

DOE Patents (OSTI)

The reversible reaction M+x/2 H.sub.2 .rarw..fwdarw.MH.sub.x, wherein M is a reversible metal hydride former that forms a hydride MH.sub.x in the presence of H.sub.2, generally used to store and recall H.sub.2, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H.sub.2, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H.sub.2 through the liquid is dependent upon the H.sub.2 pressure in the gas phase at a given temperature. When the actual H.sub.2 pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particles. When the actual pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

Reilly, James J. (Bellport, NY); Grohse, Edward W. (Port Jefferson Station, NY); Johnson, John R. (Calverton, NY); Winsche, deceased, Warren E. (late of Bellport, NY)

1988-01-01T23:59:59.000Z

160

Photoelectron spectroscopy of boron aluminum hydride cluster anions  

SciTech Connect

Boron aluminum hydride clusters are studied through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations. Boron aluminum hydride cluster anions, B{sub x}Al{sub y}H{sub z}{sup ?}, were generated in a pulsed arc cluster ionization source and identified by time-of-flight mass spectrometry. After mass selection, their photoelectron spectra were measured by a magnetic bottle-type electron energy analyzer. The resultant photoelectron spectra as well as calculations on a selected series of stoichiometries reveal significant geometrical changes upon substitution of aluminum atoms by boron atoms.

Wang, Haopeng; Zhang, Xinxing; Ko, Yeon Jae; Gantefoer, Gerd; Bowen, Kit H., E-mail: kbowen@jhu.edu, E-mail: kiran@mcneese.edu [Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Li, Xiang [Center for Space Science and Technology, University of Maryland–Baltimore County, Baltimore, Maryland 21250 (United States)] [Center for Space Science and Technology, University of Maryland–Baltimore County, Baltimore, Maryland 21250 (United States); Kiran, Boggavarapu, E-mail: kbowen@jhu.edu, E-mail: kiran@mcneese.edu [Department of Chemistry and Physics, McNeese State University, Lake Charles, Louisiana 70609 (United States)] [Department of Chemistry and Physics, McNeese State University, Lake Charles, Louisiana 70609 (United States); Kandalam, Anil K. [Department of Physics, West Chester University, West Chester, Pennsylvania 19383 (United States)] [Department of Physics, West Chester University, West Chester, Pennsylvania 19383 (United States)

2014-04-28T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Chemistry, phase formation, and catalytic activity of thin palladium-containing oxide films synthesized by plasma-assisted physical vapor deposition  

SciTech Connect

The chemistry, microstructure, and catalytic activity of thin films incorporating palladium were studied using scanning and transmission electron microscopies, X-ray diffraction, spectrophotometry, 4-point probe and catalytic tests. The films were synthesized using pulsed filtered cathodic arc and magnetron sputter deposition, i.e. techniques far from thermodynamic equilibrium. Catalytic particles were formed by thermally cycling thin films of the Pd-Pt-O system. The evolution and phase formation in such films as a function of temperature were discussed in terms of the stability of PdO and PtO2 in air. The catalytic efficiency was found to be strongly affected by the chemical composition, with oxidized palladium definitely playing a major role in the combustion of methane. Reactive sputter deposition of thin films in the Pd-Zr-Y-O system allowed us forming microstructures ranging from nanocrystalline zirconia to palladium nanoparticles embedded in a (Zr,Y)4Pd2O matrix. The sequence of phase formation is put in relation to simple thermodynamic considerations.

Anders, Andre

2010-11-26T23:59:59.000Z

162

Effect of radial hydrides on the axial and hoop mechanical properties of Zircaloy-4 cladding  

Science Journals Connector (OSTI)

The effect of radial hydrides on the mechanical properties of stress-relief annealed Zircaloy-4 cladding was studied. Specimens were firstly hydrided to different target hydrogen levels between 100 and 600 wt ppm and then thermally cycled in an autoclave under a constant hoop stress to form radial hydrides by a hydride reorientation process. The effect of radial hydrides on the axial properties of the cladding was insignificant. On the other hand, the cladding ductility measurements decreased as its radial hydride content increased when the specimen was tested in plane strain tension. A reference hydrogen concentration for radial hydrides in the cladding was defined for assessing the fuel cladding integrity based on a criterion of the tensile strength 600 MPa. The reference hydrogen concentration increased with the specimen (bulk) hydrogen concentration to a maximum of ?90 wt ppm at the bulk concentration ?300 wt ppm H and then decreased towards higher concentrations.

H.C. Chu; S.K. Wu; K.F. Chien; R.C. Kuo

2007-01-01T23:59:59.000Z

163

Process of forming a sol-gel/metal hydride composite  

DOE Patents (OSTI)

An external gelation process is described which produces granules of metal hydride particles contained within a sol-gel matrix. The resulting granules are dimensionally stable and are useful for applications such as hydrogen separation and hydrogen purification. An additional coating technique for strengthening the granules is also provided.

Congdon, James W. (Aiken, SC)

2009-03-17T23:59:59.000Z

164

HYDROGEN STORAGE USINGHYDROGEN STORAGE USING COMPLEX HYDRIDESCOMPLEX HYDRIDES  

E-Print Network (OSTI)

, Michael D. HamptonDarlene K. Slattery, Michael D. Hampton FL Solar Energy Center, U. of Central FLFL Solar Energy Center, U. of Central FL #12;Objective · Identify a hydrogen storage system that meets the DOEHYDROGEN STORAGE USINGHYDROGEN STORAGE USING COMPLEX HYDRIDESCOMPLEX HYDRIDES Darlene K. Slattery

165

Measurements of atmospheric water vapor above Mauna Kea using an infrared radiometer  

E-Print Network (OSTI)

Measurements of atmospheric water vapor above Mauna Kea using an infrared radiometer David A in atmospheric water vapor that distort the phase coherence of incoming celestial signals. The signal received water vapor, this paper presents results obtained with a second generation IRMA operating at the James

Naylor, David A.

166

Microstructural study by XRD profile analysis and TEM observations on hydrided recrystallized Zircaloy-4  

SciTech Connect

Zircaloy-4, used as cladding tube material in the nuclear reactors, may become brittle due to the precipitation of hydrides. During hydride formation, the anisotropic misfit strains between hydrides and the hexagonal-close-packed zirconium matrix results in a preferred orientation of the hydride platelets in the anisotropic stress field caused by non-relieved fabrication residual stresses and misfit stresses. To understand the mechanism of rupture and to predict the threshold stresses for hydride stress orientation, it is necessary to study the residual stresses, especially the microstrain caused by crystalline lattice misfit, in a hydrided specimen. The X-ray diffraction profile analysis is very sensitive to all the microstructure evolution in metallic materials. It is a non-destructive and voluminal technique compared with transmission electron microscope observation. The XRD peak broadening can be related closely with the microstrain in case of hydrided Zircaloy-4, because the hydride formation creates in general a great number of dislocations which contributes especially to the diminution of coherent domain size and to the increase of microstrain. To calibrate the internal microstrain due to precipitation effect of hydrided specimens, XRD profile analysis has also been realized on the non-hydrided specimens deformed by uniaxial tension. In this paper the authors restrict to analyzing the results about the recrystallized state, because more informations about the anisotropic elasticity, plasticity, thermal expansion, neutron diffraction measurement and the crystallographic texture results are available.

Bai, J.B. (Lab. MSS/MAT, CNRS URA 850, Ecole Centrale Paris, 92295 Chatenay Malabry Cedex (FR)); Gilbon, D. (LM3, CNRS URA 1219, ENSAM, 151 Bd. de l'Hopital, 75013 Paris (FR)); Lebrun, J.L. (CEA/DTA/CEREM/DTM/SRMA, C.E. Saclay, 91191 Gif-sur-Yvette Cedex (FR))

1992-02-01T23:59:59.000Z

167

Gasoline vapor recovery  

SciTech Connect

In a gasoline distribution network wherein gasoline is drawn from a gasoline storage tank and pumped into individual vehicles and wherein the gasoline storage tank is refilled periodically from a gasoline tanker truck, a method of recovering liquid gasoline from gasoline vapor that collects in the headspace of the gasoline storage tank as the liquid gasoline is drawn therefrom, said method comprising the steps of: (a) providing a source of inert gas; (b) introducing inert gas into the gasoline storage tank as liquid gasoline is drawn therefrom so that liquid gasoline drawn from the tank is displaced by inert gas and gasoline vapor mixes with the inert gas in the headspace of the tank; (c) collecting the inert gas/gasoline vapor mixture from the headspace of the gasoline storage tank as the tank is refilled from a gasoline tanker truck; (d) cooling the inert gas/gasoline vapor mixture to a temperature sufficient to condense the gasoline vapor in the mixture to liquid gasoline but not sufficient to liquify the inert gas in the mixture; (e) separating the condensed liquid gasoline from the inert gas; and delivering the condensed liquid gasoline to a remote location for subsequent use.

Lievens, G.; Tiberi, T.P.

1993-06-22T23:59:59.000Z

168

Electrolyte vapor condenser  

DOE Patents (OSTI)

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

1983-02-08T23:59:59.000Z

169

Electrolyte vapor condenser  

DOE Patents (OSTI)

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

Sederquist, Richard A. (Newington, CT); Szydlowski, Donald F. (East Hartford, CT); Sawyer, Richard D. (Canton, CT)

1983-01-01T23:59:59.000Z

170

Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power  

SciTech Connect

A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

Melius, C F; Foltz, G W

1987-01-01T23:59:59.000Z

171

FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL  

SciTech Connect

The objective of this DOE NERI program sponsored project was to assess the feasibility of improving the plutonium (Pu) and minor actinide (MA) recycling capabilities of pressurized water reactors (PWRs) by using hydride instead of oxide fuels. There are four general parts to this assessment: 1) Identifying promising hydride fuel assembly designs for recycling Pu and MAs in PWRs 2) Performing a comprehensive systems analysis that compares the fuel cycle characteristics of Pu and MA recycling in PWRs using the promising hydride fuel assembly designs identified in Part 1 versus using oxide fuel assembly designs 3) Conducting a safety analysis to assess the likelihood of licensing hydride fuel assembly designs 4) Assessing the compatibility of hydride fuel with cladding materials and water under typical PWR operating conditions Hydride fuel was found to offer promising transmutation characteristics and is recommended for further examination as a possible preferred option for recycling plutonium in PWRs.

Greenspan, Ehud; Todreas, Neil; Taiwo, Temitope

2009-03-10T23:59:59.000Z

172

Photoelectric and luminescence properties of GaSb-Based nanoheterostructures with a deep Al(As)Sb/InAsSb/Al(As)Sb quantum well grown by metalorganic vapor-phase epitaxy  

SciTech Connect

The luminescence and photoelectric properties of heterostructures with a deep Al(As)Sb/InAsSb/Al(As)Sb quantum well grown on n-GaSb substrates by metalorganic vapor-phase epitaxy are investigated. Intense superlinear luminescence and increased optical power as a function of the pump current in the photon energy range of 0.6-0.8 eV are observed at temperatures of T = 77 and 300 K. The photoelectric, current-voltage, and capacitance characteristics of these heterostructures are studied in detail. The photosensitivity is examined with photodetectors operating in the photovoltaic mode in the spectral range of 0.9-2.0 {mu}m. The sensitivity maximum at room temperature is observed at a wavelength of 1.55 {mu}m. The quantum efficiency, detectivity, and response time of the photodetectors were estimated. The quantum efficiency and detectivity at the peak of the photosensitivity spectrum are as high as {eta} = 0.6-0.7 and D{sub {lambda}max}{sup *} = (5-7) Multiplication-Sign 10{sup 10} cm Hz{sup 1/2} W{sup -1}, respectively. The photodiode response time determined as the rise time of the photoresponse pulse from 0.1 to the level 0.9 is 100-200 ps. The photodiode transmission bandwidth is 2-3 GHz. Photodetectors with a deep Al(As)Sb/InAsSb/Al(As)Sb quantum well grown on n-GaSb substrates are promising foruse in heterodyne detection systems and in information technologies.

Mikhailova, M. P.; Andreev, I. A., E-mail: igor@iropt9.ioffe.ru; Ivanov, E. V.; Konovalov, G. G.; Grebentshikova, E. A.; Yakovlev, Yu. P. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Hulicius, E.; Hospodkova, A.; Pangrac, Y. [Academy of Sciences of the Czech Republic, Institute of Physics (Czech Republic)] [Academy of Sciences of the Czech Republic, Institute of Physics (Czech Republic)

2013-08-15T23:59:59.000Z

173

Electronic parameters and interfacial properties of GaAs/AlxGa1-xAs multiquantum wells grown on (111)A GaAs by metalorganic vapor phase epitaxy  

Science Journals Connector (OSTI)

We report a comprehensive study of the optical and interfacial properties of GaAs/AlxGa1-xAs multiquantum wells grown on (111)A GaAs substrates by metalorganic vapor phase epitaxy which allowed the determination of the electronic parameters appropriate for such quantum wells. High-resolution x-ray diffractometry studies indicate an excellent crystal quality and good periodicity for the multiquantum wells and provided their structural parameters accurately. The photoreflectance spectra exhibit all the allowed and almost all the weakly allowed optical transitions between the confined hole and electron states. From an analysis of the photoreflectance spectra it is shown that the quantum well interfaces have an abruptness better than ±1 ML. Photoluminescence spectroscopy was also performed to evaluate independently the roughness of the interfaces and multiquantum well period reproducibility. For a 25-period multiquantum well structure with a well width of 55 Å, a photoluminescence linewidth of 12.5 meV, which corresponds to a combined well-width fluctuation and interface roughness of less than ±1 monolayer over the 25 periods, proves the achievement of heterointerfaces with excellent interfacial quality. From a detailed analysis of the high-order transitions observed in the photoreflectance spectra we determined key quantum well electronic parameters, such as, the heavy-hole valence-band offset Qv=0.33±0.02, the transverse GaAs heavy-hole effective mass mhh=(0.95±0.02)m0, and the light-hole effective mass mlh=0.08m0 in ?111? directions, for ?111?-oriented GaAs/AlxGa1-xAs quantum well structures.

Soohaeng Cho; A. Sanz-Hervás; A. Majerfeld; B. W. Kim

2003-07-10T23:59:59.000Z

174

Preparation and X-Ray diffraction studies of curium hydrides  

SciTech Connect

Curium hydrides were prepared by reaction of curium-248 metal with hydrogen and characterized by X-ray powder diffraction. Several of the syntheses resulted in a hexagonal compound with average lattice parameters of a/sub 0/ = 0.3769(8) nm and c/sub 0/ = 0.6732(12) nm. These products are considere to be CmH/sub 3//sup -//sub 8/ by analogy with the behavior of lanthanide-hydrogen and lighter actinide-hydrogen systems. Face-centered cubic products with an average lattice parameter of a/sub 0/ = 0.5322(4) nm were obtained from other curium hydride preparations. This parameter is slightly smaller than that reported previously for cubic curium dihydride, CmH /SUB 2-x/ (B.M. Bansal and D. Damien. Inorg. Nucl. Chem. Lett. 6 603, 1970). The present results established a continuation of typical heavy trivalent lanthanidelike behavior of the transuranium actinide-hydrogen systems through curium.

Gibson, J.K.; Maire, R.G.

1985-10-01T23:59:59.000Z

175

Behavior and rupture of hydrided Zircaloy-4 tubes and sheets  

SciTech Connect

Zirconium alloys are used as structural parts in the nuclear fuel assembly. The mechanical behavior and rupture mechanisms of ZIRCALOY-4 guide tubes and sheet containing 150 to 1,200 wt ppm hydrogen have been investigated at room temperature. Sheets were notched to study the influence of geometrical defects on rupture. It is shown that hydrides strengthened the material, as maximum stresses sustained by the material are increased with increasing hydrogen contents. On the other hand, ductility is reduced. The material also exhibits a strong anisotropy due to its pronounced texture. Metallographic examinations have shown that damage by hydride cracking is a continuous process that starts after the onset of necking. Notches reduce ductility. A modified Gurson-Tvergaard model was used to represent the material behavior and rupture. Numerical simulation using the finite element method demonstrates the strong influence of plastic anisotropy on the behavior of structures and rupture modes.

Prat, F.; Besson, J. [Ecole des Mines de Paris, Evry (France); Grange, M. [Framatome Nuclear Fuel, Lyon (France); Andrieu, E. [ENSCT, Toulouse (France). Lab. Materiaux

1998-06-01T23:59:59.000Z

176

Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol  

SciTech Connect

This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

Gardiner, D. P.; Bardon, M. F.; Clark, W.

2011-07-01T23:59:59.000Z

177

Electrochromically switched, gas-reservoir metal hydride devices with  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrochromically switched, gas-reservoir metal hydride devices with Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows Title Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows Publication Type Journal Article LBNL Report Number LBNL-1089E Year of Publication 2008 Authors Anders, André, Jonathan L. Slack, and Thomas J. Richardson Journal Thin Solid Films Volume 1 Date Published 08/2003 Call Number LBNL-1089E Abstract Proof-of-principle gas-reservoir MnNiMg electrochromic mirror devices have been investigated. In contrast to conventional electrochromic approaches, hydrogen is stored (at low concentration) in the gas volume between glass panes of the insulated glass units (IGUs). The elimination of a solid state ion storage layer simplifies the layer stack, enhances overall transmission, and reduces cost. The cyclic switching properties were demonstrated and system durability improved with the incorporation a thin Zr barrier layer between the MnNiMg layer and the Pd catalyst. Addition of 9% silver to the palladium catalyst further improved system durability. About 100 full cycles have been demonstrated before devices slow considerably. Degradation of device performance appears to be related to Pd catalyst mobility, rather than delamination or metal layer oxidation issues originally presumed likely to present significant challenges.

178

E-Print Network 3.0 - arsenic hydrides Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

(2002) 1080-703902.50 Summary: for arsenic species using hydride generation and atomic absorption spectroscopy. The detec- tion limit for As... by ASP Estimation of...

179

LANL/PNNL Virtual Center for Chemical Hydrides and New Concepts...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage * Thermodynamics * Kinetics * Recycle * WeightVolume Capacity * Durability Investigate...

180

E-Print Network 3.0 - annulus metal hydride Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Introduction Metal hydride applications span a wide variety of tech nologies eg energy conversion... chemical compressors and hydrogen storage A knowledge of heat and...

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Thermodynamics of metal hydrides for hydrogen storage applications using first principles calculations.  

E-Print Network (OSTI)

??Metal hydrides are promising candidates for H2 storage, but high stability and poor kinetics are the important challenges which have to be solved for vehicular… (more)

Kim, Ki Chul

2010-01-01T23:59:59.000Z

182

Influence of an oxide layer on the hydride embrittlement in Zircaloy-4  

SciTech Connect

Hydrid embrittlement of zirconium and its alloy has been studied extensively. The common techniques used to hydride the specimens are electro-chemical and gaseous ones. During this operation, especially for cases of long duration, an oxide layer would form on the surface of specimens. The present paper reports on some evidence for the influence of this layer on the hydride embrittlement in Zircaloy-4. Tensile tests with or without this layer were performed on hydrided specimens. Metallographic and fractographic analyses were carried out in order to examine the fracture nature of this layer. An analysis based on the fracture mechanics was also proposed.

Bai, J.B. (Ecole Centrale de Paris, Chatenay Malabry (France). Lab. MSS/MAT)

1993-09-01T23:59:59.000Z

183

Organic vapor jet printing system  

SciTech Connect

An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

Forrest, Stephen R

2012-10-23T23:59:59.000Z

184

A Bibliography of Vapor Phase Thermal Fragmentation  

Science Journals Connector (OSTI)

......inert gas on hexa- decane pyrolysis", Can. J. Chem. 47, 3477...General Review of Ether Pyrolysis," Chapt. 4 of "The Chemistry...Chralovsky, "Phenyl Dimethyl Silane," Coll. Czech. Chem. Commun...Tebben and M. A. Ring, "Disilane and Trisilane," Inorg. Chem......

Stanley F. Sarner

1972-02-01T23:59:59.000Z

185

Vapor phase transport at a hillside landfill  

Science Journals Connector (OSTI)

...ambient density gradients. Post-landfill gas input reverses the direction of...landfill may explain observations of landfill gas found at depth. Post-landfill...of gas generation. Transport of landfill gas is shown to be dominated by diffusion...

P. H. Stauffer; N. D. Rosenberg

186

A Bibliography of Vapor Phase Thermal Fragmentation  

Science Journals Connector (OSTI)

......Catalysis 7, 386 (1967). S. J. Price, "Toluene," Can. J. Chem...Green, and L. P. Hallee, "Ethylene," Oil Gas J. 65, 192 (1967...1962). M. Krech and S. J. Price, "Dimethyl Mercury," Can...1963). M. Krech and S. J. Price, "Dimethyl Cadmium," Can......

Stanley F. Sarner

1972-02-01T23:59:59.000Z

187

New plasma source of hydrides for epitaxial growth. Final subcontract report, 15 April 1991--3 September 1993  

SciTech Connect

This report describes a novel plasma-activated selenium source that was developed during the course of this subcontract and which is significantly different than any other heretofore reported in the scientific literature. It involves microwave excited, magnetically confined plasma sources that are intended to operate under electron cyclotron resonance (ECR) conditions at 2.455 GHz. This source is designed to excite and dissociate the molecular vapor evaporating or subliming from a heated solid or liquid reservoir. It can combine an effusion cell vapor flux with a stream of hydrogen or helium gas, enabling the in-situ generation of hydrides for use in low-pressure growth techniques where long mean free paths are desirable. Experiments were conducted to demonstrate a stable discharge within the source, and measures were identified to improve its operational characteristics. Application of this novel source is anticipated to enable a low-temperature, safe process for the growth of high-quality epitaxial compound semiconductor films. This reduction of epitaxial growth temperatures may enable the fabrication of novel photovoltaic devices that have heretofore been impossible due to the deleterious effects of interdiffusion at heterointerfaces resulting from the high temperatures required to grow adequate quality material using conventional processes.

Stanbery, B.J. [Boeing Defense & Space Group, Seattle, WA (United States)

1994-05-01T23:59:59.000Z

188

E-Print Network 3.0 - acid vapor pressures Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Sciences and Ecology 22 3b. Thermodynamics of moist air Water phase, water latent heat of vaporization Lv Summary: 3b. Thermodynamics of moist air Water phase, water latent...

189

Mercury Vapor | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor Mercury Vapor Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Mercury Vapor Details Activities (23) Areas (23) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Anomalously high concentrations can indicate high permeability or conduit for fluid flow Hydrological: Field wide soil sampling can generate a geometrical approximation of fluid circulation Thermal: High concentration in soils can be indicative of active hydrothermal activity Dictionary.png Mercury Vapor: Mercury is discharged as a highly volatile vapor during hydrothermal

190

Stratified vapor generator  

DOE Patents (OSTI)

A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

Bharathan, Desikan (Lakewood, CO); Hassani, Vahab (Golden, CO)

2008-05-20T23:59:59.000Z

191

Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices  

SciTech Connect

An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

2014-11-18T23:59:59.000Z

192

Hydride blisters Formation, Characterization and Effect on the Fracture of Zircaloy-4 Cladding Tubes Under Reactivity Initiated  

E-Print Network (OSTI)

failure in 1983[2], when an axial crack developed in a CANDU pressure tube following an array of hydride

193

Storing images in warm atomic vapor  

E-Print Network (OSTI)

Reversible and coherent storage of light in atomic medium is a key-stone of future quantum information applications. In this work, arbitrary two-dimensional images are slowed and stored in warm atomic vapor for up to 30 $\\mu$s, utilizing electromagnetically induced transparency. Both the intensity and the phase patterns of the optical field are maintained. The main limitation on the storage resolution and duration is found to be the diffusion of atoms. A techniqueanalogous to phase-shift lithography is employed to diminish the effect of diffusion on the visibility of the reconstructed image.

M. Shuker; O. Firstenberg; R. Pugatch; A. Ron; N. Davidson

2008-06-17T23:59:59.000Z

194

Solid-State Gadolinium-Magnesium Hydride Optical Switch R. Armitage  

E-Print Network (OSTI)

-state electrochromic device. With positive polarization of the hydride electrode, the visible reflectance approaches 35 and reflecting states. Keywords: gadolinium-magnesium; electrochromic hydride; optical switching device. 2 #12;A conventional electrochromics5 . Optical switching has also been demonstrated by varying the H content

195

Hydrogen storage material and process using graphite additive with metal-doped complex hydrides  

DOE Patents (OSTI)

A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

Zidan, Ragaiy (Aiken, SC); Ritter, James A. (Lexington, SC); Ebner, Armin D. (Lexington, SC); Wang, Jun (Columbia, SC); Holland, Charles E. (Cayce, SC)

2008-06-10T23:59:59.000Z

196

Hydride precipitation and its influence on mechanical properties of notched and unnotched Zircaloy-4 plates  

Science Journals Connector (OSTI)

The hydride formation and its influence on the mechanical performance of hydrided Zircaloy-4 plates containing different hydrogen contents were studied at room temperature. For the unnotched plate samples with the hydrogen contents ranging from 25 to 850 wt. ppm, the hydrides exerted an insignificant effect on the tensile strength, while the ductility was severely degraded with increasing hydrogen content. The fracture mode and degree of embrittlement were strongly related to the hydrogen content. When the hydrogen content reached a level of 850 wt. ppm, the plate exhibited negligible ductility, resulting in almost completely brittle behavior. For the hydrided notched plate, the tensile stress concentration associated with the notch tip facilitated the hydride accumulation at the region near the notch tip and the premature crack propagation through the hydride fracture during hydriding. The final brittle through-thickness failure for this notched sample was mainly attributed to the formation of a continuous hydride network on the thickness section and the obtained very high hydrogen concentration (estimated to be 1965 wt. ppm).

Zhiyang Wang; Ulf Garbe; Huijun Li; Robert P. Harrison; Karl Toppler; Andrew J. Studer; Tim Palmer; Guillaume Planchenault

2013-01-01T23:59:59.000Z

197

Getting metal-hydrides to do what you want them to  

SciTech Connect

With the discovery of AB/sub 5/ compounds, intermetallic hydrides with unusual properties began to be developed (H dissociation pressures of one to several atmospheres, extremely rapid and reversible adsorption/desorption very large amounts of H adsorbed). This paper reviews the factors that must be controlled in order to modify these hydrides to make them useful. The system LaNi/sub 5/ + H/sub 2/ is used as example. Use of AB/sub 5/ hydrides to construct a chemical heat pumps is discussed. Results of a systematic study substituting Al for Ni are reported; the HYCSOS pump is described briefly. Use of hydrides as hydrogen getters (substituted ZrV/sub 2/) is also discussed. Finally, possible developments in intermetallic hydride research in the 1980's and the hydrogen economy are discussed. 10 figures. (DLC)

Gruen, D.M.

1981-01-01T23:59:59.000Z

198

Stress-induced reorientation of hydrides and mechanical properties of Zircaloy-4 cladding tubes  

Science Journals Connector (OSTI)

Stress-induced reorientation of hydrides and its effect on the stress–strain response of Zircaloy-4 cladding tubes were investigated. The reorientation of hydrides along the radial direction was most pronounced if the tube was cooled from 300 to 200 °C under circumferential loading. Reorientation occurred much less frequently at either higher (cooled from 400 to 300 °C) or lower (cooled from 200 to 100 °C) temperature range. The population of radial hydrides in R43H7 (which was cooled from 400 to 300 °C and maintained at 300 °C for 7 h) increased drastically during annealing at 300 °C, suggesting time dependent stress-aided dissolution of circumferential hydrides and reprecipitation of radial hydrides. The drastic decrease of the strength and the complete loss of the ductility were observed in R32AC and R43H7.

S.I. Hong; K.W. Lee

2005-01-01T23:59:59.000Z

199

Vapor Barriers or Vapor Diffusion Retarders | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Home Air Sealing for New Home Construction Insulation Types of Insulation Insulation and Air Sealing Products and Services External Resources Find a Local AirVapor Barrier...

200

Designation of Sites for Remedial Action - Metal Hydrides, Beverly,  

Office of Legacy Management (LM)

T: T: Designation of Sites for Remedial Action - Metal Hydrides, Beverly, MA; Bridgeport Brass, Adrian, MI and Seymour, Chicago, IL CT; National Guard Armory, 0: Joe LaGrone, Manager Oak Ridge Operations Office Based on the attached radiological survey data (Attachments 1 through 3) and an appropriate authority review, the following properties are being authorized for remedial action. It should be noted that the attached survey data are for designation purposes only and that Bechtel National, Inc. (BNI) should conduct appropriate comprehensive characterization studies to determine the extent'and magnitude of contamination on properties. Site Location Priority Former Bridgeport Brass Co. (General Motors) Adrian, MI Low Former Bridgeport Brass Co.

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Electrochemical process and production of novel complex hydrides  

DOE Patents (OSTI)

A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

Zidan, Ragaiy

2013-06-25T23:59:59.000Z

202

Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications  

SciTech Connect

Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

2012-04-16T23:59:59.000Z

203

Production of higher quality bio-oils by in-line esterification of pyrolysis vapor  

DOE Patents (OSTI)

The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

2014-12-02T23:59:59.000Z

204

Synthesis, characterization and reactivity of several rhenium hydride complexes. A study of the role of metal hydrides in organometallic reactions  

SciTech Connect

The mechanistic role of transition metal hydrides in organometallic reactions has been studied using several low valent, electron rich rhenium complexes. The reaction ReH[sub 7](PPh[sub 3])[sub 2] with indene has been found to yield products that are [eta][sup 5]-C[sub 9]H[sub 7]ReH[sub 2](PPh[sub 3])[sub 2] and ([eta][sup 5]-C[sub 9]H[sub 11])ReH[sub 2](PPh[sub 3])[sub 2], respectively. The mechanism proposed for the formation of these two products consists of several metal to ring hydride migrations, and the activation parameters for one of the migrations have been obtained. Hydride migrations are prevalent in the subsequent chemistry of ([eta][sup 5]-C[sub 9]H[sub 11])ReH[sub 2](PPh[sub 3])[sub 2], as well as in the similar complex ([eta][sup 4]-C[sub 9]H[sub 12])ReH[sub 3](PPh[sub 3])[sub 2]. The complex ([eta][sup 4]-C[sub 4]H[sub 5]S)ReH[sub 2](PPh[sub 3])[sub 2] has been synthesized and structurally characterized in an attempt to model the interaction of thiophene with a metal hydride surface which is presumably present during typical hydrodesulfurization conditions. The thermolysis of ([eta][sup 4]-C[sub 4]H[sub 5]S)ReH[sub 2](PPh[sub 3])[sub 2] in the presence of PMe[sub 3] has been found to yield free tetrahydrothiophene and the cyclometallated Re(PMe[sub 3])[sub 4](PPH[sub 2]C[sub 6]H[sub 4]), while photolysis with excess PMe[sub 3] yields a mixture of organometallic products in which the thiophene ligand has undergone C-S bond cleavage. Products have been identified that contain an S-bound 1-butene-1-thiolate ligand, an [eta][sup 3]-allyl bound 1-butene-1-thiolate ligand, an ethylthioketene ligand and an S-bound 1-butanethiolate ligand, all of which represent the first such homogeneous transformations of thiophene. The photochemical ligand exchange reactions and the observed H/D exchange catalysis (between a deuterated solvent and a protio substrate) of CpReH[sub 2](PPh[sub 3])[sub 2] have been studied in detail.

Rosini, G.P.

1992-01-01T23:59:59.000Z

205

Vapor spill pipe monitor  

DOE Patents (OSTI)

The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

Bianchini, G.M.; McRae, T.G.

1983-06-23T23:59:59.000Z

206

Method of generating hydrogen-storing hydride complexes  

DOE Patents (OSTI)

A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

Srinivasan, Sesha S; Niemann, Michael U; Goswami, D. Yogi; Stefanakos, Elias K

2013-05-14T23:59:59.000Z

207

ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS  

SciTech Connect

The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

2011-07-18T23:59:59.000Z

208

New High Performance Water Vapor Membranes to Improve Fuel Cell Balance of Plant Efficiency and Lower Costs (SBIR Phase I) - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

0 0 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Earl H. Wagener (Primary Contact), Brad P. Morgan, Jeffrey R. DiMaio Tetramer Technologies L.L.C. 657 S. Mechanic St. Pendleton, SC 29670 Phone: (864) 646-6282 Email: earl.wagener@tetramertechnologies.com DOE Manager HQ: Nancy Garland Phone: (202) 586-5673 Email: Nancy.Garland@ee.doe.gov Contract Number: DE-SC0006172 Project Start Date: June 17, 2011 Project End Date: March 16, 2012 Fiscal Year (FY) 2012 Objectives Demonstrate water vapor transport membrane with * >18,000 gas permeation units (GPU) Water vapor membrane with less than 20% loss in * performance after stress tests Crossover leak rate: <150 GPU * Temperature Durability of 90°C with excursions to * 100°C Cost of <$10/m

209

Hydrogen Cars and Water Vapor  

E-Print Network (OSTI)

. This cycle is currently under way with hydrogen fuel cells. As fuel cell cars are suggested as a solutionHydrogen Cars and Water Vapor D.W.KEITHANDA.E.FARRELL'S POLICY FORUM "Rethinking hydrogen cars" (18 misidentified as "zero-emissions vehicles." Fuel cell vehicles emit water vapor. A global fleet could have

Colorado at Boulder, University of

210

Fuel vapor control device  

SciTech Connect

A fuel vapor control device is described having a valve opening and closing a passage connecting a carburetor and a charcoal canister according to a predetermined temperature. A first coil spring formed by a ''shape memory effect'' alloy is provided to urge the valve to open the passage when the temperature is high. A second coil spring urges the valve to close the passage. A solenoid is provided to urge an armature against the valve to close the passage against the force of the first coil spring when the engine is running. The solenoid heats the first coil spring to generate a spring force therein when the engine is running. When the engine is turned off, the solenoid is deactivated, and the force of the first spring overcomes the force of the second spring to open the passage until such time as the temperature of the first spring drops below the predetermined temperature.

Ota, I.; Nishimura, Y.; Nishio, S.; Yogo, K.

1987-10-20T23:59:59.000Z

211

The Dust Settles on Water Vapor Feedback  

Science Journals Connector (OSTI)

...To understand water vapor feedback...shifts in the atmospheric circulation...caused a positive water vapor feedback...temperature. Condensation, evaporation...shifts in the atmospheric circulation...caused a positive water vapor feedback...temperature. Condensation, evaporation...

Anthony D. Del Genio

2002-04-26T23:59:59.000Z

212

Indium and tellurium doping of CdS crystals in cadmium vapor and their luminescent properties  

Science Journals Connector (OSTI)

A technique is devised for vapor-phase doping of CdS in the quaternary system Cd-In-Te-S. CdS crystals are doped with In and Te via four-zone ... InTe vapors. The luminescence spectra of the CdS?In,Te?[Cd] crysta...

I. N. Odin; M. V. Chukichev; M. E. Rubina

213

Indium and tellurium doping of CdS crystals in cadmium vapor and their luminescent properties  

Science Journals Connector (OSTI)

—A technique is devised for vapor-phase doping of CdS in the quaternary system Cd—In—Te—S. CdS crystals are doped with In and Te via four-zone ... InTe vapors. The luminescence spectra of the CdS?In,Te?[Cd] cryst...

I. N. Odin; M. V. Chukichev; M. E. Rubina

214

Optimization of the chemical vapor deposition process for carbon nanotubes fabrication  

E-Print Network (OSTI)

Optimization of the chemical vapor deposition process for carbon nanotubes fabrication M. Grujicica-phase chemistry and surface chemistry model is developed to analyze, at the reactor length scale, chemical vapor (carrier gas) in the presence of cobalt catalytic particles in a cylindrical reactor. The model allows

Grujicic, Mica

215

Hydride embrittlement in ZIRCALOY-4 plate; Part 1: Influence of microstructure on the hydride embrittlement in ZIRCALOY-4 at 20[degree]C and 350[degree]C  

SciTech Connect

The hydride embrittlement in ZIRCALOY-4 was studied at room temperature and 350 C. Sheet tensile specimens of two fabrication routes in the stress-relieved, recrystallized, and [beta]-treated states were hydrided with or without tensile stress. It was found generally that the effect on strength of increasing hydrogen content was not important. However, for the tensile tests at room temperature, there is a ductile-brittle transition when the hydrogen content is higher than a certain threshold. The prior thermomechanical treatment shifts this transition considerably. In situ scanning electron microscopy (SEM) tests, fractography, and fracture profile observations were carried out to determine the fracture micromechanisms and the microscopic processes. At 20 C, the fracture surfaces are characterized by voids and secondary cracks for low and medium hydrogen contents and by intergranular cracks and decohesion through the continuous hydride network for high hydrogen contents. This phenomenon disappears at 350 C, and the hydrogen seems to exert no more influence on the fracture micromechanism even for very high hydrogen contents (up to 1,500 wt ppm). A full-coverage model is proposed to estimate the critical hydrogen content that makes ZIRCALOY-4 totally brittle. The effect of microstructure on hydride embrittlement in different metallurgical states is thus explained according to the modeling. Special attention is devoted to relating the micromechanisms and the modeling in order to propose the possible measures needed to limit the hydride embrittlement effect.

Bai, J.B.; Prioul, C.; Francois, D. (Ecole Centrale Paris, Chatenay-Malabry (France))

1994-06-01T23:59:59.000Z

216

Category:Mercury Vapor | Open Energy Information  

Open Energy Info (EERE)

search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Mercury Vapor page? For detailed information on Mercury Vapor as exploration techniques,...

217

Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

for Simulation of Hydride Precipitation in Zr-Based Used Fuel for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities The report demonstrates a meso-scale, microstructural evolution model for simulation of zirconium hydride precipitation in the cladding of used fuels during long-term dry-storage. While the Zr-based claddings (regarded as a barrier for containment of radioactive fission products and fuel) are manufactured free of any hydrogen, they absorb hydrogen during service in the reactor. The amount of hydrogen that the cladding picks up is primarily a function of the exact chemistry and microstructure of the claddings and reactor operating conditions, time-temperature history, and

218

E-Print Network 3.0 - aluminium hydrides Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Medicine 26 KV-tOOJHfe Metallurgy Department Summary: .3. Developaent of a Hydride Based Fuel Cell 32 4.4. Materials Research for Fuel Cell Application .. 33 4.5. Thin... . The...

219

The Safe Use of Sodium Hydride on Scale: The Process Development of a Chloropyrimidine Displacement  

Science Journals Connector (OSTI)

The Safe Use of Sodium Hydride on Scale: The Process Development of a Chloropyrimidine Displacement ... Global Pharmaceutical Commercialization, Merck Manufacturing Division, Rahway, New Jersey, 07065 ... This article is part of the Safety of Chemical Processes 11 special issue. ...

Jamie M. McCabe Dunn; Alicia Duran-Capece; Brendan Meehan; James Ulis; Tetsuo Iwama; Guy Gloor; George Wong; Evan Bekos

2011-09-30T23:59:59.000Z

220

Structure of the novel ternary hydrides Li4Tt2D (Tt = Si and Ge)  

Science Journals Connector (OSTI)

The crystal structures of novel Li4Tt2D (Tt = Si and Ge) ternary hydrides were solved using neutron powder diffraction data. All hydrogen atoms were found to occupy Li6-octahedral interstices.

Wu, H.

2007-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Formation and Characterization of Hydride Blisters in Zircaloy-4 Cladding Tubes  

E-Print Network (OSTI)

in a CANDU Zircaloy-2 pressure tube along an array of hydride blisters on the external surface is the material that replaced Zircaloy-2 alloy for pressure tubes in the CANDU reactors. In all these studies

Paris-Sud XI, Université de

222

Photogeneration of Hydride Donors and Their Use Toward CO2 Reduction  

SciTech Connect

Despite substantial effort, no one has succeeded in efficiently producing methanol from CO2 using homogeneous photocatalytic systems. We are pursuing reaction schemes based on a sequence of hydride-ion transfers to carry out stepwise reduction of CO2 to methanol. We are using hydride-ion transfer from photoproduced C-H bonds in metal complexes with bio-inspired ligands (i.e., NADH-like ligands) that are known to store one proton and two electrons.

Fujita,E.; Muckerman, J.T.; Polyansky, D.E.

2009-06-07T23:59:59.000Z

223

\\{WS8e4\\} - EFFECT OF HYDRIDES ON THE MECHANICAL PROPERTIES OF ZIRCALOY-4  

Science Journals Connector (OSTI)

ABSTRACT In order to better understand the embrittlement of Zircaloy-4 by hydrides and the ductile-brittle transition on this alloy, Zircaloy-4 sheet tensile specimens in the stress-relieved, recrystallized and ? treated states were hydrided (10 to 1500 ppm wt H) and then tested at two temperatures (20°C, 350°C). Metallographic and fractographic analyses were carried out to determine the fracture micro-mechanisms. The results showed that, at 20°C, Zircaloy-4 undergoes a significant ductile to brittle transition for high hydrogen contents. Heat treatment shifts this transition (to zero elongation) considerably, from 1050 ppm wt H for the stress-relieved state to less than 250 ppm wt H for the ? treated state. However, at 350°C, Zircaloy-4 remains ductile up to hydrogen content higher than 1100 ppm wt. At 20°C, the fracture surfaces are characterized by voids and secondary cracks for low and medium hydrogen contents, and by intergranular crack and decohesion through the continuous hydride network for high hydrogen content. A model based on image analysis and hydride embrittlement micro-mechanism observations is used to calculate the upper-limit hydrogen content which makes Zircaloy-4 totally brittle. The difference between the mechanical behaviors of stress-relieved and recrystallized states is also explained. KEYWORDS Zircaloy-4, hydride embrittlement, ductile-brittle transition, cracked-hydride voids.

J.B. BAI; C. PRIOUL; D. FRANÇOIS

1992-01-01T23:59:59.000Z

224

Fracture of Hydrided Zircaloy-4 Sheet under Through-Thickness Crack Growth Conditions  

SciTech Connect

The failure of thin-wall components such as fuel cladding may be caused by crack initiation on the component surface and subsequent crack growth through its thickness. This study has determined the fracture toughness of hydrided cold-worked stress relieved Zircaloy-4 sheet subject to through-thickness crack growth at 25 deg. C. The experimental approach utilizes a novel procedure in which a narrow linear strip of brittle hydride blister across the specimen width creates a well-defined pre-crack upon initial loading. The subsequent crack growth resistance is then characterized by four-point bending of the specimen and an elastic-plastic fracture mechanics analysis. At room temperature, the through-thickness fracture toughness (K{sub Q}) is sensitive to the orientation of the hydride platelets, and K{sub Q} {approx_equal} 25 MPavm for crack growth through a mixed in-plane/out-of-plane hydride field. In contrast, K{sub Q} is much higher ({approx_equal} 75 MPavm) when the hydride platelets are oriented predominantly in the plane of the sheet (and therefore normal to both the crack plane and the crack growth direction). The implication of these fracture toughness values to the fracture strain behavior of hydrided Zircaloy-4 under through-thickness crack growth conditions is illustrated. (authors)

Raynaud, P.A.; Koss, D.A. [Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA 16802 (United States); Motta, A.T. [Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, PA 16802 (United States); Chan, K.S. [Southwest Research Institute, San Antonio, TX 78238 (United States)

2007-07-01T23:59:59.000Z

225

Vapor deposition of hardened niobium  

DOE Patents (OSTI)

A method of coating ceramic nuclear fuel particles containing a major amount of an actinide ceramic in which the particles are placed in a fluidized bed maintained at ca. 800.degree. to ca. 900.degree. C., and niobium pentachloride vapor and carbon tetrachloride vapor are led into the bed, whereby niobium metal is deposited on the particles and carbon is deposited interstitially within the niobium. Coating apparatus used in the method is also disclosed.

Blocher, Jr., John M. (Columbus, OH); Veigel, Neil D. (Columbus, OH); Landrigan, Richard B. (Columbus, OH)

1983-04-19T23:59:59.000Z

226

Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy  

SciTech Connect

This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride ?-ZrH1.5 precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. In this work, a model to numerically simulate hydride precipitation at the microstructural scale, in a wide variety of Zr-based claddings, under dry-storage conditions is being developed. It will be used to aid in the evaluation of the mechanical integrity of used fuel rods during dry storage and transportation by providing the structural conditions from the microstructural scale to the continuum scale to engineering component scale models to predict if the used fuel rods will perform without failure under normal and off-normal conditions. The microstructure, especially, the hydride structure is thought to be a primary determinant of cladding failure, thus this component of UFD’s storage and transportation analysis program is critical. The model development, application and validation of the model are documented and the limitations of the current model are discussed. The model has been shown to simulate hydride precipitation in Zircaloy-4 cladding with correct morphology, thermodynamics and kinetics. An unexpected insight obtained from simulations hydride formation in Zircaloy-4 is that small (sub-micron) precipitates need to order themselves to form the larger hydrides typically described as radially-reoriented precipitates. A limitation of this model is that it does not currently solve the stress state that forms dynamically in the precipitate or matrix surrounding the precipitate. A method to overcome the limitations is suggested and described in detail. The necessary experiments to provide key materials physics and to validate the model are also recommended.

Veena Tikare; Philippe Weck; Peter Schultz; Blythe Clark; John Mitchell; Michael Glazoff; Eric Homer

2014-10-01T23:59:59.000Z

227

Dynamic modeling and simulation of hydrogen supply capacity from a metal hydride tank  

Science Journals Connector (OSTI)

Abstract The current study presents a modeling of a LaNi5 metal hydride-based hydrogen storage tank to simulate and control the dynamic processes of hydrogen discharge from a metal hydride tank in various operating conditions. The metal hydride takes a partial volume in the tank and, therefore, hydrogen discharge through the exit of the tank was driven by two factors; one factor is compressibility of pressurized gaseous hydrogen in the tank, i.e. the pressure difference between the interior and the exit of the tank makes hydrogen released. The other factor is desorption of hydrogen from the metal hydride, which is subsequently released through the tank exit. The duration of a supposed full load supply is evaluated, which depends on the initial tank pressure, the circulation water temperature, and the metal hydride volume fraction in the tank. In the high pressure regime, the duration of full load supply is increased with increasing circulation water temperature while, in the low pressure regime where the initial amount of hydrogen absorbed in the metal hydride varies sensitively with the metal hydride temperature, the duration of full load supply is increased and then decreased with increasing circulation water temperature. PID control logic was implemented in the hydrogen supply system to simulate a representative scenario of hydrogen consumption demand for a fuel cell system. The demanded hydrogen consumption rate was controlled adequately by manipulating the discharge valve of the tank at a circulation water temperature not less than a certain limit, which is increased with an increase in the tank exit pressure.

Ju-Hyeong Cho; Sang-Seok Yu; Man-Young Kim; Sang-Gyu Kang; Young-Duk Lee; Kook-Young Ahn; Hyun-Jin Ji

2013-01-01T23:59:59.000Z

228

The Vaporization Enthalpies and Vapor Pressures of Some Primary Amines of Pharmaceutical Importance by Correlation Gas  

E-Print Network (OSTI)

by Correlation Gas Chromatography Chase Gobble, Nigam Rath, and James Chickos* Department of Chemistry Information ABSTRACT: Vapor pressures, vaporization, and sublimation enthalpies of several pharmaceuticals and boiling temperatures when available. Sublimation enthalpies and vapor pressures are also evaluated for 1

Chickos, James S.

229

Mercury Source Zone Identification using Soil Vapor Sampling and Analysis  

SciTech Connect

Development and demonstration of reliable measurement techniqes that can detect and help quantify the nature and extent of elemental mercury (Hg(0)) in the subsurface are needed to reduce certainties in the decision making process and increase the effectiveness of remedial actions. We conducted field tests at the Y-12 National Security Complex (NSC) in Oak Ridge, TN, to determine if sampling and analysis of Hg(0) vapors in the shallow subsurface (<0.3 m depth) can be used to as an indicator of the location and extent of Hg(0) releases in the subsurface. We constructed a rigid PVC pushprobe assembly, which was driven into the ground. Soil gas samples were collected through a sealed inner tube of the assembly and analyzed immediately in the field with a Lumex and/or Jerome Hg(0) analyzer. Time-series sampling showed that Hg vapor concentrations were fairly stable over time suggesting that the vapor phase Hg(0) was not being depleted and that sampling results were not dependent on the soil gas purge volume. Hg(0) vapor data collected at over 200 pushprobe locations at 3 different release sites correlated well to areas of known Hg(0) contamination. Vertical profiling of Hg(0) vapor concentrations conducted at 2 locations provided information on the vertical distribution of Hg(0) contamination in the subsurface. We concluded from our studies that soil gas sampling and analysis can be conducted rapidly and inexpensively at a large scale to help identify areas contaminated with Hg(0).

Watson, David B [ORNL] [ORNL; Miller, Carrie L [ORNL] [ORNL; Lester, Brian P [ORNL] [ORNL; Lowe, Kenneth Alan [ORNL] [ORNL; Southworth, George R [ORNL] [ORNL; Bogle, Mary Anna [ORNL] [ORNL; Liang, Liyuan [ORNL] [ORNL; Pierce, Eric M [ORNL] [ORNL

2014-01-01T23:59:59.000Z

230

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin  

NLE Websites -- All DOE Office Websites (Extended Search)

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Title X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Publication Type Journal Article LBNL Report Number LBNL-50574 Year of Publication 2002 Authors Richardson, Thomas J., Baker Farangis, Jonathan L. Slack, Ponnusamy Nachimuthu, Rupert C. C. Perera, Nobumichi Tamura, and Michael D. Rubin Journal Journal of Alloys and Compounds Volume 356-357 Start Page 204 Pagination 204-207 Date Published 08/2003 Keywords A. hydrogen storage materials, NEXAFS, thin film s; C. EXAFS, x-ray diffraction Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption spectroscopy. Mg K-edge and Ni, Co, and Ti L-edge spectra reflect both reversible and irreversible changes in the metal environments. A significant shift in the nickel L absorption edge shows it to be an active participant in hydride formation. The effect on cobalt and titanium is much less dramatic, suggesting that these metals act primarily as catalysts for formation of magnesium hydride.

231

VAPORIZATION THERMODYNAMICS OF KCl. COMBINING VAPOR PRESSURE AND GRAVIMETRIC DATA  

E-Print Network (OSTI)

.B. Department of Chemistry, Moscow State University, Moscow, 119899, Russia Bonnell D.W., Hastie J.W. National temperature chemistry situations, vapor pressures are typically less than 100 kPa. The molar volume is p = 101325 Pa). The subscript trs denotes that the changeisfor a transition, typically sublimation

Rudnyi, Evgenii B.

232

URANIUM METAL POWDER PRODUCTION, PARTICLE DISTRIBUTION ANALYSIS, AND REACTION RATE STUDIES OF A HYDRIDE-DEHYDRIDE PROCESS  

E-Print Network (OSTI)

atmosphere to reduce sample oxidation .................................................................................................. 13 12 Aluminum oxide crucible located at the bottom of the hydride-dehydride rig. ... 14 13 Furnace and furnace... at 60 minutes, 5psig, 250?C hydride, 325?C dehydride ................................................................................................... 30 27 Rotary kiln designed at ORNL for use in voloxidation...

Sames, William

2011-08-08T23:59:59.000Z

233

Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.  

SciTech Connect

We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom (Savannah River National Labs, Aiken, SC)

2012-01-01T23:59:59.000Z

234

Vacuum vapor deposition gun assembly  

DOE Patents (OSTI)

A vapor deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, a hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

Zeren, Joseph D. (Boulder, CO)

1985-01-01T23:59:59.000Z

235

LNG Vaporizer Utilizing Vacuum Steam Condensing  

Science Journals Connector (OSTI)

This report concerns the field test results of a new type of peak-shaving LNG vaporizer (VSV) whose heat source is ... heat of vacuum steam to vaporize and superheat LNG within heat transfer tubes. Prior to the.....

Y. Miyata; M. Hanamure; H. Kujirai; Y. Sato…

1991-01-01T23:59:59.000Z

236

Running-Film Vaporizer for LNG  

Science Journals Connector (OSTI)

Advances in welding technology and steel fabrication techniques have permitted the development of a new concept in cryogenic vaporizers—the running-film plate vaporizer. Although similar in heat transfer philosop...

H. H. West; G. L. Puckett

1975-01-01T23:59:59.000Z

237

Vapor Retarder Classification- Building America Top Innovation  

Energy.gov (U.S. Department of Energy (DOE))

This Building America Innovations profile describes research in vapor retarders. Since 2006 the IRC has permitted Class III vapor retarders like latex paint (see list above) in all climate zones under certain conditions thanks to research by Building America teams.

238

Method and composition in which metal hydride particles are embedded in a silica network  

DOE Patents (OSTI)

A silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid. According to one embodiment of the invention, the solid is ground into granules for use of the product in hydrogen storage. Alternatively, the paste can be molded into plates or cylinders and then dried for use of the product as a hydrogen filter. Where mechanical strength is required, the paste can be impregnated in a porous substrate or wire network.

Heung, Leung K. (Aiken, SC)

1999-01-01T23:59:59.000Z

239

Polar intermetallic compounds of the silicon and arsenic family elements and their ternary hydrides and fluorides  

SciTech Connect

An investigation has been made on the effects of hydrogen and fluoride in the solid state chemistry of alkaline-earth and divalent rare-earth metal pnictide (Pn) and tetrelide (Tt) phases A{sub 5}(Pn,Tt,){sub 3}Z{sub x}, where A = Ca, Sr, Ba, Sm, Eu, Yb; Pn = As, Sb, Bi; Tt = Si, Ge, Sn, Pb and Z = H, F. Several trivalent rare-earth-metal pnictides, RE{sub 5}Pn{sub 3} (RE = Y, La, Gd, Tb, Dy, Ho, Er, Tm) and alkaline-earth-metal trielides, A{sub 5}Tr{sub 3}Z{sub x} (Tr = Ga, In, Tl) have been included in an effort to complete observed structural trends. Two main experimental techniques were followed throughout this work, (a) reactions in absence of hydrogen or under continuous high vacuum, and (b) reactions with binary metal hydrides, AH{sub x}, in closed containers. The results demonstrate that all the phases reported with the {beta}-Yb{sub 5}Sb{sub 3}-type structure in the A{sub 5}Pn{sub 3} systems are hydrogen-stabilized compounds. Reactions in absence of hydrogen lead to compounds with the Mn{sub 5}Si{sub 3}-type structure. The structure type {beta}-Yb{sub 5}Sb{sub 3} (= Ca{sub 5}SB{sub 3}F) was found to be characteristic of ternary systems and inaccurately associated with phases that form in the Y{sub 5}Bi{sub 3}-type. A new series of isomorphous Zintl compounds with the Ca{sub 16}Sb{sub 11}-type structure were prepared and studied as well. All the alkaline-earth-metal tetrelides, A{sub 5}Tt{sub 3}, that crystallize in the Cr{sub 5}B{sub 3}-type structure can be interstitially derivatized by hydrogen or fluoride. Binary and ternary compounds were characterized by Guinier powder patterns, single crystal X-ray and powder neutron diffraction techniques. In an effort to establish property-structure relationships, electrical resistivity and magnetic measurements were performed on selected systems, and the results were explained in terms of the Zintl concepts, aided by extended Hueckel band calculations.

Leon-Escamilla, E.A.

1996-10-17T23:59:59.000Z

240

Vapor Pressures and Heats of Vaporization of Primary Coal Tars  

Office of Scientific and Technical Information (OSTI)

/ PC92544-18 / PC92544-18 VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS FINAL REPORT Grant Dates: August, 1992 - November, 1996 Principal Authors: Eric M. Suuberg (PI) and Vahur Oja Report Submitted: April, 1997 Revised: July, 1997 Grant Number: DE-FG22-92PC92544 Report Submitted by: ERIC M. SUUBERG DIVISION OF ENGINEERING BROWN UNIVERSITY PROVIDENCE, RI 02912 TEL. (401) 863-1420 Prepared For: U. S. DEPT. OF ENERGY FEDERAL ENERGY TECHNOLOGY CENTER P.O. BOX 10940 PITTSBURGH, PA 15236 DR. KAMALENDU DAS, FETC, MORGANTOWN , WV TECHNICAL PROJECT OFFICER "US/DOE Patent Clearance is not required prior to the publication of this document" ii United States Government Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Desorption efficiencies of toluene and n-butanol in an organic vapor monitor  

E-Print Network (OSTI)

&jards has become one of the most important industrial hygiene f unct i one e The levei of exposure to many organic vapor;=, is det r- mined by co' lecting the chemical on some type o solid sor- bent. Of the various adsorbents available {silica gel... two of these paramet rs) ~ The objective of this re, . earch wa, . to investigate the effe ts of chemical phase (liquid or vapor) on the desorp- tion efficiencies of toluene and n-buta?ol adsorbed on acti- vated charcoal in organic vapor monitors...

Heaney, Mary Ann

2012-06-07T23:59:59.000Z

242

Vapor deposition of tantalum and tantalum compounds  

SciTech Connect

Tantalum, and many of its compounds, can be deposited as coatings with techniques ranging from pure, thermal chemical vapor deposition to pure physical vapor deposition. This review concentrates on chemical vapor deposition techniques. The paper takes a historical approach. The authors review classical, metal halide-based techniques and current techniques for tantalum chemical vapor deposition. The advantages and limitations of the techniques will be compared. The need for new lower temperature processes and hence new precursor chemicals will be examined and explained. In the last section, they add some speculation as to possible new, low-temperature precursors for tantalum chemical vapor deposition.

Trkula, M. [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.

1996-04-01T23:59:59.000Z

243

Means and method for vapor generation  

DOE Patents (OSTI)

A liquid, in heat transfer contact with a surface heated to a temperature well above the vaporization temperature of the liquid, will undergo a multiphase (liquid-vapor) transformation from 0% vapor to 100% vapor. During this transition, the temperature driving force or heat flux and the coefficients of heat transfer across the fluid-solid interface, and the vapor percentage influence the type of heating of the fluid--starting as "feedwater" heating where no vapors are present, progressing to "nucleate" heating where vaporization begins and some vapors are present, and concluding with "film" heating where only vapors are present. Unstable heating between nucleate and film heating can occur, accompanied by possibly large and rapid temperature shifts in the structures. This invention provides for injecting into the region of potential unstable heating and proximate the heated surface superheated vapors in sufficient quantities operable to rapidly increase the vapor percentage of the multiphase mixture by perhaps 10-30% and thereby effectively shift the multiphase mixture beyond the unstable heating region and up to the stable film heating region.

Carlson, Larry W. (Oswego, IL)

1984-01-01T23:59:59.000Z

244

The influence of hydride blisters on the fracture of Zircaloy-4 O.N. Pierron a  

E-Print Network (OSTI)

.elsevier.com/locate/jnucmat Journal of Nuclear Materials 322 (2003) 21­35 #12;hydrogen embrittlement [15]. Such an effect becomes, and radiation damage [1]. As the cladding undergoes oxidation with the associated hydrogen pickup, the total amount of hydrogen increases, and hydride precipitates form pref- erentially near the outer (cooler

Motta, Arthur T.

245

Analytical assessment of the thermal behavior of nickel-metal hydride batteries  

E-Print Network (OSTI)

Analytical assessment of the thermal behavior of nickel-metal hydride batteries Peyman Taheri in batteries with orthotropic thermal conductivities, where the heat generation is due to irreversible of the battery thermal behavior with modest numerical effort. The accuracy of the proposed model is tested

Bahrami, Majid

246

Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast charging  

E-Print Network (OSTI)

Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast to investigate transient thermal behavior of NiMH batteries. The thermal model uses integral transformation 2013 Available online 25 June 2013 Keywords: Battery thermal management Battery thermal model Fast

Bahrami, Majid

247

Influence of additives on the thermal behavior of nickel/metal hydride battery  

Science Journals Connector (OSTI)

This study discusses the thermal behavior of the 6.5 Ah cylinder Ni/MH hydride battery with 0.5 wt% ytterbium oxide (...2O3...) in nickel electrode and 1.0 wt% super absorbent polymer (SAP) in hydrogen-storage al...

Kai Yang; Jin Jing An; Shi Chen

2010-12-01T23:59:59.000Z

248

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films  

E-Print Network (OSTI)

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic

249

Project Profile: Low-Cost Metal Hydride Thermal Energy Storage System  

Energy.gov (U.S. Department of Energy (DOE))

The Savannah River National Laboratory (SRNL), under the National Laboratory R&D competitive funding opportunity, is collaborating with Curtin University (CU) to evaluate new metal hydride materials for thermal energy storage (TES) that meet the SunShot cost and performance targets for TES systems.

250

Observations of proton beam enhancement due to erbium hydride on gold foil targets  

SciTech Connect

Recent theoretical work suggests that the conversion efficiency from laser to protons in laser irradiated thin foil experiments increases if the atomic mass of nonhydrogen atoms on the foil rear surface increases. Experiments were performed at the Lawrence Livermore National Laboratory Jupiter Laser Facility to observe the effect of thin foils coated with erbium hydride on the conversion efficiency from laser to protons. Gold foils with and without the rear surface coated with ErH{sub 3} were irradiated using the ultrashort pulse, 40 TW Callisto laser. An argon-ion etching system was used to remove naturally occurring nanometer thick surface layer contaminants from the hydride. With the etcher, gold with ErH{sub 3} showed a 25% increase in the conversion efficiency to protons above 3.4 MeV relative to contaminants, where C{sup +4} and H{sup +} were the dominant ion species. No difference in the ion signal was observed without first cleaning the hydrides. Simulations using the hybrid PIC code, LSP, revealed that the increase due to erbium hydride versus contaminants is 37% for protons above 3 MeV.

Offermann, D. T.; Van Woerkom, L. D. [Department of Physics, Ohio State University, Columbus, Ohio 43210 (United States); Freeman, R. R. [Department of Physics, Ohio State University, Columbus, Ohio 43210 (United States); Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, California 92093 (United States); Department of Applied Science, University of California Davis, Livermore, California 94550 (United States); Foord, M. E.; Hey, D.; Key, M. H.; Mackinnon, A. J.; MacPhee, A. G.; Patel, P. K.; Ping, Y.; Sanchez, J. J.; Shen, N. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Bartal, T.; Beg, F. N. [Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, California 92093 (United States); Espada, L. [Sandia National Laboratory, Albuquerque, New Mexico 87185 (United States); Chen, C. D. [Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2009-09-15T23:59:59.000Z

251

Complex Hydrides for Hydrogen Storage Darlene K. Slattery and Michael D. Hampton  

E-Print Network (OSTI)

at a temperature of less than 100 o C in order to be compatible with fuel cells and must have an installed hydrogen have reported the discovery of a number of catalysts that improve the reversing of the hydrogen release the hydrogenation/dehydrogenation of sodium aluminum hydride. Mechanical incorporation of the catalyst

252

Evaluation of Protected Metal Hydride Slurries in a H2 Mini-  

E-Print Network (OSTI)

Evaluation of Protected Metal Hydride Slurries in a H2 Mini- Grid TIAX, LLC Acorn Park Cambridge_MERIT_REVIEW_MAY2003 2 Introduction Hydrogen Mini-Grid Concept Distributed FCPS utilizing a H2 Mini-Grid can provide waste heat can be used for hot water or space heating in buildings (i.e. "cogen") Distributed FCPS

253

Results of Soil Vapor Extraction of a Chlorinated Solvent Dnapl Waste Site at the Rocky Flats Superfund Site  

Science Journals Connector (OSTI)

A full scale Soil Vapor Extraction (SVE) system was evaluated for remediation of subsurface contamination of the chlorinated Dense Non-Aqueous Phase Liquids (DNAPL) at a waste site at the Rocky Flats Environmenta...

S. Grace; E. Dille

1995-01-01T23:59:59.000Z

254

Shock formation in the collapse of a vapor nano-bubble  

E-Print Network (OSTI)

In this paper a diffuse-interface model featuring phase change, transition to supercritical conditions, thermal conduction, compressibility effects and shock wave propagation is exploited to deal with the dynamics of a cavitation bubble. At variance with previous descriptions, the model is uniformly valid for all phases (liquid, vapor and supercritical) and phase transitions involved, allowing to describe the non-equilibrium processes ongoing during the collapse. As consequence of this unitary description, rather unexpectedly for pure vapor bubbles, the numerical experiments show that the collapse is accompanied by the emission of a strong shock wave in the liquid and by the oscillation of the bubble that periodically disappears and reappears, due to transition to super/sub critical conditions. The mechanism of shock wave formation is strongly related to the transition of the vapor to supercritical state, with a progressive steepening of the compression wave to form the shock which is eventually reflected as ...

Magaletti, Francesco; Casciola, Carlo Massimo

2014-01-01T23:59:59.000Z

255

Wick for metal vapor laser  

DOE Patents (OSTI)

An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

Duncan, David B. (Livermore, CA)

1992-01-01T23:59:59.000Z

256

Non-Vapor Compression HVAC Technologies Report  

Energy.gov (U.S. Department of Energy (DOE))

While vapor-compression technologies have served heating, ventilation, and air-conditioning (HVAC) needs very effectively, and have been the dominant HVAC technology for close to 100 years, the conventional refrigerants used in vapor-compression equipment contribute to global climate change when released to the atmosphere. The Building Technologies Office is evaluating low-global warming potential (GWP) alternatives to vapor-compression technologies.

257

Role of Pyridine as a Biomimetic Organo-Hydride for Homogeneous Reduction of CO2 to Methanol  

E-Print Network (OSTI)

We use quantum chemical calculations to elucidate a viable homogeneous mechanism for pyridine-catalyzed reduction of CO2 to methanol. In the first component of the catalytic cycle, pyridine (Py) undergoes a H+ transfer (PT) to form pyridinium (PyH+) followed by an e- transfer (ET) to produce pyridinium radical (PyH0). Examples of systems to effect this ET to populate the LUMO of PyH+(E0calc ~ -1.3V vs. SCE) to form the solution phase PyH0 via highly reducing electrons include the photo-electrochemical p-GaP system (ECBM ~ -1.5V vs. SCE at pH= 5) and the photochemical [Ru(phen)3]2+/ascorbate system. We predict that PyH0 undergoes further PT-ET steps to form the key closed-shell, dearomatized 1,2-dihydropyridine (PyH2) species. Our proposed sequential PT-ET-PT-ET mechanism transforming Py into PyH2 is consistent with the mechanism described in the formation of related dihydropyridines. Because it is driven by its proclivity to regain aromaticity, PyH2 is a potent recyclable organo-hydride donor that mimics the ...

Lim, Chern-Hooi; Hynes, James T; Musgrave, Charles B

2014-01-01T23:59:59.000Z

258

Mercury Vapor (Kooten, 1987) | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor (Kooten, 1987) Mercury Vapor (Kooten, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor (Kooten, 1987) Exploration Activity Details Location Unspecified Exploration Technique Mercury Vapor Activity Date Usefulness useful DOE-funding Unknown Notes Surface soil-mercury surveys are an inexpensive and useful exploration tool for geothermal resources. ---- Surface geochemical surveys for mercury were conducted in 16 areas in 1979-1981 by ARCO Oil and Gas Company as part of its geothermal evaluation program. Three techniques used together have proved satisfactory in evaluating surface mercury data. These are contouring, histograms and cumulative frequency plots of the data. Contouring geochemical data and constructing histograms are standard

259

In situ x-ray absorption study of Zr(V0.29Ni0.71)3 hydride electrodes  

Science Journals Connector (OSTI)

We present an in situ x-ray absorption study of hydrogen absorption into the bulk of an electrode material while it is operating in an electrochemical cell. The active material is an overstoichiometric AB2-type alloy, namely, Zr(V0.29Ni0.71)3, with a cubic C15 Laves phase structure. Hydrogen absorption induces both structural and electronic changes due to the bonding between interstitial H atoms and each alloy element. The role of each element is revealed, allowing us to determine the inert role of Ni atoms and the dominant effect of the H-V interaction on the hydride formation process. Comparison between the alloyed element behavior and the H affinity of each pure element allows us to determine the influence of structural and alloying effects on bonding formation.

R. G. Agostino; G. Liberti; V. Formoso; E. Colavita; A. Züttel; C. Nützenadel; L. Schlapbach; A. Santaniello; C. Gauthier

2000-05-15T23:59:59.000Z

260

Near real time vapor detection and enhancement using aerosol adsorption  

SciTech Connect

A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

Novick, Vincent J.; Johnson, Stanley A.

1997-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Near real time vapor detection and enhancement using aerosol adsorption  

DOE Patents (OSTI)

A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

Novick, V.J.; Johnson, S.A.

1999-08-03T23:59:59.000Z

262

Near real time vapor detection and enhancement using aerosol adsorption  

DOE Patents (OSTI)

A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

Novick, Vincent J. (Downers Grove, IL); Johnson, Stanley A. (Countryside, IL)

1999-01-01T23:59:59.000Z

263

G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) Value-Added Product  

SciTech Connect

The G-Band Vapor Radiometer Precipitable Water Vapor (GVRPWV) value-added product (VAP) computes precipitable water vapor using neural network techniques from data measured by the GVR. The GVR reports time-series measurements of brightness temperatures for four channels located at 183.3 ± 1, 3, 7, and 14 GHz.

Koontz, A; Cadeddu, M

2012-12-05T23:59:59.000Z

264

Phase transitions of helium in aerogel  

Science Journals Connector (OSTI)

The effect of dilute quenched impurities on the liquid-vapor critical point, superfluid and He3?He4 phase separation transitions were studied by introducing liquid helium into aerogel. Aerogel is a highly porous ...

M. H. W. Chan

1996-01-01T23:59:59.000Z

265

Nickel-Metal-Hydride Batterie--High Energy Storage for Electric Vehicles  

NLE Websites -- All DOE Office Websites (Extended Search)

Freedomcar & Vehicle Technologies Program Freedomcar & Vehicle Technologies Program Nickel-Metal-Hydride Batteries - High Energy Storage for Electric Vehicles Background The key to making electric vehicles (EVs) practical is the development of batteries that can provide performance comparable with that of con ventional vehicles at a similar cost. Most EV batteries have limited energy storage capabili ties, permitting only relatively short driving distances before the batteries must be recharged. In 1991, under a coopera tive agreement with The U.S. Department of Energy (DOE), the United States Advanced Battery Consortium (USABC) initiated development of nickel- metal-hydride (NiMH) battery technology and established it as a prime mid-term candidate for use in EVs. DOE funding has been instru

266

Aluminum Hydride - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Jason Graetz (Primary Contact), James Wegrzyn Brookhaven National Laboratory (BNL) Building 815 Upton, NY 11973 Phone: (631) 344-3242 Email: graetz@bnl.gov DOE Manager HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov Project Start Date: October 1, 2011 Project End Date: Project continuation and direction determined annually by DOE Fiscal Year (FY) 2012 Objectives Develop onboard vehicle storage systems using aluminum hydride that meets all of DOE's targets for proton exchange membrane fuel cell vehicles. Produce aluminum hydride material with a hydrogen * storage capacity greater than 9.7% gravimetric (kg-H 2 /kg) and 0.13 kg-H 2 /L volumetric. Develop practical and economical processes for *

267

Pressure Acceleration of Hydride Formation on a Cobalt(I) Macrocycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Pressure Acceleration of Hydride Formation via Pressure Acceleration of Hydride Formation via Proton Binding to a Cobalt(I) Macrocycle Etsuko Fujita, James F. Wishart, and Rudi van Eldik Inorg. Chem. 41, 1579-1583 (2002) [Find paper at ACS Publications] Abstract: The effect of pressure on proton binding to the racemic isomer of the cobalt(I) macrocycle, CoL+ (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene), has been studied for a series of proton donors using pulse radiolysis techniques. The second-order rate constants for the reaction of CoL+ with proton donors decrease with increasing pKa of the donor acid, consistent with a reaction occurring via proton transfer. Whereas the corresponding volumes of activation (DVý) are rather small and negative for all acids (proton donors) with pKa values below 8.5, significantly larger negative

268

Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation  

DOE Patents (OSTI)

An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-based materials is disclosed. Samples of zirconium-based materials having different compositions and/or fabrication methods are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280 to 316 C). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hydriding for the same materials when subject to in-reactor (irradiated) corrosion. 1 figure.

Johnson, A.B. Jr.; Levy, I.S.; Trimble, D.J.; Lanning, D.D.; Gerber, F.S.

1990-04-10T23:59:59.000Z

269

Gold Hydride Complexes DOI: 10.1002/anie.200803842  

E-Print Network (OSTI)

have been observed solely in the gas phase.[7] The N-heterocyclic carbene (NHC) ligand IPr (IPr= 1, dimeric [{(IPr)CuH}2], synthesized from [(IPr)CuCl] in two steps.[8] Since NHC ligands have been shown reactions. The reaction of the known compound [(IPr)AuCl][10] with sodium tert-butoxide generated [(IPr

Müller, Peter

270

Quantitative organic vapor-particle sampler  

DOE Patents (OSTI)

A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

1998-01-01T23:59:59.000Z

271

LNG fire and vapor control system technologies  

SciTech Connect

This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

1982-06-01T23:59:59.000Z

272

OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES  

SciTech Connect

Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

2011-07-14T23:59:59.000Z

273

Systems Modeling, Simulation and Material Operating Requirements for Chemical Hydride Based Hydrogen Storage  

SciTech Connect

Research on ammonia borane (AB, NH3BH3) has shown it to be a promising material for chemical hydride based hydrogen storage. AB was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to 19.6% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. A new systems concept based on augers, ballast tank, hydrogen heat exchanger and H2 burner was designed and implemented in simulation. In this design, the chemical hydride material was assumed to produce H2 on the augers itself, thus minimizing the size of ballast tank and reactor. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure, in various components of the storage system. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. The control variable AB (or alane) flow rate was determined through a simple expression based on the ballast tank pressure, H2 demand from the fuel cell and hydrogen production from AB (or alane) in the reactor. System simulation results for solid AB, liquid AB and alane for both steady state and transient drive cycle cases indicate the usefulness of the model for further analysis and prototype development.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.

2012-02-01T23:59:59.000Z

274

ARM - Field Campaign - Water Vapor IOP  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsWater Vapor IOP govCampaignsWater Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Water Vapor IOP 2000.09.18 - 2000.10.08 Lead Scientist : Henry Revercomb Data Availability Yes For data sets, see below. Description Scientific hypothesis: 1. Microwave radiometer (MWR) observations of the 22 GHz water vapor line can accurately constrain the total column amount of water vapor (assuming a calibration accuracy of 0.5 degC or better, which translates into 0.35 mm PWV). 2. Continuous profiling by Raman lidar provides a stable reference for handling sampling problems and observes a fixed column directly above the site only requiring a single height- independent calibration factor. 3. Agreement between the salt-bath calibrated in-situ probes, chilled

275

Energy balance in laser-irradiated vaporizing droplets  

Science Journals Connector (OSTI)

The interactions of vaporizing aerosols with a high energy laser beam are analyzed in the diffusive vaporization regime. This is the regime in which diffusive mass transport and...

Zardecki, Andrew; Armstrong, Robert L

1988-01-01T23:59:59.000Z

276

Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et...  

Open Energy Info (EERE)

Vapor (Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et...

277

Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

278

Reduced gravity rankine cycle design and optimization with passive vortex phase separation  

E-Print Network (OSTI)

. Potential drawbacks to the technology in a reduced gravity environment include two-phase fluid management processes such as liquid-vapor phase separation. The most critical location for phase separation is at the boiler exit where only vapor must be sent...

Supak, Kevin Robert

2009-05-15T23:59:59.000Z

279

MODELLING AND SIMULATION OF LIQUID-VAPOR PHASE TRANSITION  

E-Print Network (OSTI)

Generator Turbine Generator Cooling Tower Condenser Cooling Water Pump Reactor Core Reactor Vessel Control and Steam (secondary loop) Water (cooling loop) Pump Steam Generator Turbine Generator Cooling Tower Water pressurized (primary loop) Water and Steam (secondary loop) Water (cooling loop) Pump Steam

Faccanoni, Gloria

280

Luminescent Properties of CdS Crystals Doped with Gallium and Tellurium in Cadmium Vapor  

Science Journals Connector (OSTI)

A technique is devised for vapor-phase doping CdS in the quaternary system Cd–Ga–Te–S. CdS crystals are doped with Ga and Te via four-zone ... and Cd (the more volatile component of CdS). The luminescence spectra...

I. N. Odin; M. V. Chukichev; M. E. Rubina

2003-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Water Vapor Radiometry : Outline of Goals and Tasks for the Spring Semester 2001  

E-Print Network (OSTI)

that can accu­ rately measure the spectrum of the water vapor emis­ sion. The current receivers follow, as in a conventional re­ ceiver, the correlation receiver splits the rf signal into two with a splitter that follows the feed horn. Both branches are mixed with a carefully controlled ther­ mal load. A 180 ffi phase shift

Backer, Don

282

Capillary waves and the inherent density profile for the liquid-vapor interface  

E-Print Network (OSTI)

. This approach in turn allows: (1) identification of an "outermost layer" of particles on the liquid. (2). is a nonmonotonic function of normal distance through the interface. and is expected to reflect the diverging bulk distribution for the system in a state of liquid-vapor phase coexistence. This leads to identification

Stillinger, Frank

283

Recovering hydrocarbons from hydrocarbon-containing vapors  

DOE Patents (OSTI)

Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

1980-09-30T23:59:59.000Z

284

An automated hydride generation-cryogenic trapping-ICP-MS system for measuring inorganic and methylated Ge, Sb and As species  

E-Print Network (OSTI)

An automated hydride generation-cryogenic trapping-ICP-MS system for measuring inorganic of both flow injection and batch hydride generation and couples it to an automated cryogenic trapping unit with detection by ICP-MS. The Teflon cryogenic trap was packed with 10 cm of SE-30 5% Chromosorb W-HP 80­100 mesh

Canberra, University of

285

Chemical vapor detection using nanomechanical platform  

Science Journals Connector (OSTI)

For high sensitive and multiplexed chemical analysis, an opto-mechanical detection platform has been built. To check the performance of the platform, we performed water vapor response measurements for ... sensors...

S. H. Lim

2007-11-01T23:59:59.000Z

286

Chemical vapor deposition of functionalized isobenzofuran polymers  

E-Print Network (OSTI)

This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

Olsson, Ylva Kristina

2007-01-01T23:59:59.000Z

287

Vapor Power Systems MAE 4263 Final Exam  

E-Print Network (OSTI)

Vapor Power Systems MAE 4263 Final Exam Wednesday, May 5, 2004 Prof. P.M. Moretti Key Instructions, then think, then write! 1. What is the dewpoint of the exhaust of your car, if the gasoline consists2 so that the mole fraction of water vapor is yH2 O = 9 9 + 8 + 47 = 0:14063 pH2 O = 0:14063 14

288

Delta-doping of boron atoms by photoexcited chemical vapor deposition  

SciTech Connect

Boron delta-doped structures in Si crystals were fabricated by means of photoexcited chemical vapor deposition (CVD). Core electronic excitation with high-energy photons ranging from vacuum ultraviolet to soft x rays decomposes B{sub 2}H{sub 6} molecules into fragments. Combined with in situ monitoring by spectroscopic ellipsometry, limited number of boron hydrides can be delivered onto a Si(100) surface by using the incubation period before the formation of a solid boron film. The boron-covered surface is subsequently embedded in a Si cap layer by Si{sub 2}H{sub 6} photo-excited CVD. The crystallinity of the Si cap layer depended on its thickness and the substrate temperature. The evaluation of the boron depth profile by secondary ion mass spectroscopy revealed that boron atoms were confined within the delta-doped layer at a concentration of 2.5 x 10{sup 20} cm{sup -3} with a full width at half maximum of less than 9 nm, while the epitaxial growth of a 130-nm-thick Si cap layer was sustained at 420 deg. C.

Akazawa, Housei [NTT Microsystem Integration Laboratories, 3-1 Morinosato Wakamiya, Atsugi, Kanagawa 243-0198 (Japan)

2012-03-15T23:59:59.000Z

289

Optical monitor for water vapor concentration  

DOE Patents (OSTI)

A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma. 5 figs.

Kebabian, P.

1998-06-02T23:59:59.000Z

290

Optical monitor for water vapor concentration  

DOE Patents (OSTI)

A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma.

Kebabian, Paul (Acton, MA)

1998-01-01T23:59:59.000Z

291

Synthetic IIuid inclusions in natural quartz. III. Determination of phase equilibrium properties in the system H,O-NaCI to 1000C and 1500 bars  

E-Print Network (OSTI)

and a lower salinity vapor phase and produce coexisting halite-bearing and vapor-rich fluid inclusions with shallow intrusions. particularly the porphyry copper deposits, in which halite-bearing and coexisting

Bodnar, Robert J.

292

CORRELATIONS BETWEEN VAPOR SATURATION, FLUID COMPOSITION, AND WELL DECLINE IN LARDERELLO  

SciTech Connect

A large body of field data from Larderello shows striking temporal correlations between decline of well flow-rate, produced gas/steam ratio, chloride concentration and produced vapor fraction. The latter is inferred from measured concentrations of non-condensible gases in samples of well fluid, using chemical phase equilibrium principles. Observed temporal changes in the vapor fractions can be interpreted in term of a ''multiple source'' model, as suggested by D'Amore and Truesdell (1979). This provides clues to the dynamics of reservoir depletion, and to the evaluation of well productivity and longevity.

D'Amore, F.; Pruess, K.

1985-01-22T23:59:59.000Z

293

Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermodynamic guidelines for the prediction of hydrogen Thermodynamic guidelines for the prediction of hydrogen storage reactions and their application to destabilized hydride mixtures Hydrogen Storage & Nanoscale Modeling Group Ford Motor Company Don Siegel dsiegel2@ford.com Phys. Rev. B 76, 134102 (2007) 1 Acknowledgements C. Wolverton V. Ozolins Computation Northwestern UCLA J. Yang A. Sudik Experiments Ford Ford 2 Computational Methodology * Atomistic computer simulations based on quantum mechanics (Density Functional Theory) * First-principles approach: - Only empirical input are crystal structure and fundamental physical constants - VASP code - PAW potentials - PW91 GGA - Temperature-dependent thermodynamic contributions evaluated within harmonic approximation * "Direct method" for construction of dynamical matrix

294

Measurements of Ionic Structure in Shock Compressed Lithium Hydride from Ultrafast X-Ray Thomson Scattering  

SciTech Connect

We present the first ultrafast temporally, spectrally, and angularly resolved x-ray scattering measurements from shock-compressed matter. The experimental spectra yield the absolute elastic and inelastic scattering intensities from the measured density of free electrons. Laser-compressed lithium-hydride samples are well characterized by inelastic Compton and plasmon scattering of a K-alpha x-ray probe providing independent measurements of temperature and density. The data show excellent agreement with the total intensity and structure when using the two-species form factor and accounting for the screening of ion-ion interactions.

Kritcher, A. L. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Neumayer, P.; Doeppner, T.; Landen, O. L.; Glenzer, S. H. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Brown, C. R. D. [Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); AWE plc., Aldermaston, Reading, RG7 4PR (United Kingdom); Davis, P. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Falcone, R. W.; Lee, H. J. [Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Gericke, D. O.; Vorberger, J.; Wuensch, K. [CFSA, Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Gregori, G. [Department of Physics, Oxford University, Oxford OX1 3PU (United Kingdom); Holst, B.; Redmer, R. [Universitaet Rostock, Institut fuer Physik, D-18051 Rostock (Germany); Morse, E. C. [Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Pelka, A.; Roth, M. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, Darmstadt (Germany)

2009-12-11T23:59:59.000Z

295

Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper  

DOE Patents (OSTI)

An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

1982-08-10T23:59:59.000Z

296

Positron binding to alkali-metal hydrides: The role of molecular vibrations  

SciTech Connect

The bound vibrational levels for J=0 have been computed for the series of alkali-metal hydride molecules from LiH to RbH, including NaH and KH. For all four molecules the corresponding potential-energy curves have been obtained for each isolated species and for its positron-bound complex (e{sup +}XH). It is found that the calculated positron affinity values strongly depend on the molecular vibrational state for which they are obtained and invariably increase as the molecular vibrational energy content increases. The consequences of our findings on the likelihood of possibly detecting such weakly bound species are briefly discussed.

Gianturco, Franco A.; Franz, Jan; Buenker, Robert J.; Liebermann, Heinz-Peter; Pichl, Lukas; Rost, Jan-Michael; Tachikawa, Masanori; Kimura, Mineo [Department of Chemistry and INFM, University of Rome La Sapienza, Piazzale A. Moro 5, 00185 Rome (Italy); Fachbereich C-Mathematik und Naturwissenschaften, Bergische Universitaet Wuppertal, Gaussstrasse 20, D-42119 Wuppertal (Germany); Max Planck Institute for the Physics of Complex Systems, Noethnitzer St. 38, D-01187 Dresden (Germany); Graduate School of Science, Yokohama-city University, Seto 22-2, Kanazawa-ku, Yokohama 236-0027 (Japan); Graduate School of Sciences, Kyushu University, Fukuoka 812-8581 (Japan)

2006-02-15T23:59:59.000Z

297

Theory of Hydride-Proton Transfer (HPT) Carbonyl Reduction by [Os(III)(tpy)(Cl)(NH=CHCH3)(NSAr)  

SciTech Connect

Quantum mechanical analysis reveals that carbonyl reduction of aldehydes and ketones by the imine-based reductant cis-[Os{sup III}(tpy)(Cl)(NH?CHCH{sub 3})(NSAr)] (2), which is accessible by reduction of the analogous nitrile, occurs by hydride-proton transfer (HPT) involving both the imine and sulfilimido ligands. In carbonyl reduction, water or alcohol is necessary to significantly lower the barrier for proton shuttling between ligands. The ?N(H)SAr group activates the carbonyl group through hydrogen bonding while the ?NC(H)CH{sub 3} ligand delivers the hydride.

Ess, Daniel H.; Schauer, Cynthia; Meyer, Thomas J.

2010-01-01T23:59:59.000Z

298

Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids  

E-Print Network (OSTI)

Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids Joe A. Wilson and James S. Chickos* Department of Chemistry and Biochemistry, University of MissouriSt. Louis, St. Louis, Missouri 63121, United States *S Supporting Information ABSTRACT: Sublimation enthalpies

Chickos, James S.

299

Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas Chromatography  

E-Print Network (OSTI)

Chromatography Chase Gobble and James Chickos* Department of Chemistry and Biochemistry University of Missouri-St. Louis, St. Louis Missouri 63121, United States Sergey P. Verevkin Department of Physical Chemistry: Experimental vapor pressures, vaporization, fusion and sublimation enthalpies of a number of dialkyl

Chickos, James S.

300

The influence of ice nucleation mode and ice vapor growth on simulation of  

NLE Websites -- All DOE Office Websites (Extended Search)

The influence of ice nucleation mode and ice vapor growth on simulation of The influence of ice nucleation mode and ice vapor growth on simulation of arctic mixed-phase clouds Avramov, Alexander The Pennsylvania State University Category: Modeling Mixed-phase arctic stratus clouds are the predominant cloud type in the Arctic . Perhaps one of the most intriguing of their features is that they tend to have liquid tops that precipitate ice. Despite the fact that this situation is colloidally unstable, these cloud systems are quite long lived - from a few days to over a couple of weeks. Previous studies have suggested that this longevity may be due to a paucity of ice nucleating aerosols (ice nuclei, or IN) in the Arctic. Such studies have shown that small changes in IN concentrations can cause large changes in the amount of liquid water within a mixed-phase stratus deck. We use the Regional

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Nondestructive Evaluation on Hydrided LWR Fuel Cladding by Small Angle Incoherent Neutron Scattering of Hydrogen  

SciTech Connect

A non-destructive neutron scattering method was developed to precisely measure the uptake of total hydrogen in nuclear grade Ziraloy-4 cladding. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and H gas. By controlling the initial H gas pressure in the vessel and the temperature profile, target H concentrations from tens of ppm to a few thousands of wppm have been successfully achieved. Following H charging, the H content of the hydrided specimens was measured using the vacuum hot extraction method (VHE), by which the samples with desired H concentration were selected for the neutron study. Small angle neutron incoherent scattering (SANIS) were performed in the High Flux Isotope Reactor at Oak Ridge national Laboratory (ORNL). Our study indicates that a very small amount ( 20 ppm) H in commercial Zr cladding can be measured very accurately in minutes for a wide range of H concentration by a nondestructive method. The H distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor, which is determined by calibration process with direct chemical analysis method on the specimen. This scale factor can be used for future test with unknown H concentration, thus provide a nondestructive method for absolute H concentration determination.

Yan, Yong [ORNL; Qian, Shuo [ORNL; Littrell, Ken [ORNL; Parish, Chad M [ORNL; Bell, Gary L [ORNL; Plummer, Lee K [ORNL

2013-01-01T23:59:59.000Z

302

Hydride-dehydride module within ARIES (Advanced Recovery and Integrated Extraction System)  

SciTech Connect

One of the many requirements placed on the DOE is the reduction of the nuclear stockpile through dismantlement programs. The DOE Office of Fissile Materials Disposition (OFMD) has been tasked with the disposition of excess plutonium and other fissile materials. On the list of items containing excess fissile materials are nuclear weapon cores, pits. The Advanced Recovery and integrated Extraction System (ARIES) at Los Alamos National Laboratory is the pit disassembly and conversion demonstration line that is being used to gather data to support the design of the full scale pit disassembly and conversion facility. The Hydride Dehydride recycle system is an important element to this program, because it provides these dismantlement programs with a technology for removing plutonium from nuclear weapons without producing large amounts of waste compared to historical processes used in the DOE complex. The Hydride Dehydride recycle process can separate plutonium from other weapons components resulting in an unclassified plutonium metal button. After separation, this button can be stored in long term storage containers or processed to produce plutonium oxide, which will be used by either of the plutonium disposition options, mixed oxide fuel burning in a nuclear reactor or immobilization. Once placed into long term storage containers, either the plutonium metal or plutonium oxide can be inspected by bilateral or international agencies to invoke transparency of the plutonium.

Flamm, B.F.; Isom, G.M.; Nelson, T.O.

1998-12-31T23:59:59.000Z

303

Mechanical Behavior Studies of Depleted Uranium in the Presence of Hydrides  

SciTech Connect

This project addresses critical issues related to aging in the presence of hydrides (UH{sub 3}) in DU and the subsequent effect on mechanical behavior. Rolled DU specimens with three different hydrogen concentrations and the as-rolled condition were studied. The texture measurements indicate that the hydrogen charging is affecting the initial as-rolled DU microstructure/texture. The macroscopic mechanical behavior suggests the existence of a threshold between the 0 wpmm H and 0.3 wppm H conditions. A VPSC simulation of the macroscopic strain-stress behavior, when taking into account only a texture effect, shows no agreement with the experiment. This suggests that the macroscopic mechanical behavior observed is indeed due to the presence of hydrogen/hydrides in the DU bulk. From the lattice strain variation it can be concluded that the hydrogen is affecting the magnitude and/or the nature of CRSS. The metallography indicates the specimens that underwent the hydrogen charging process, developed large grains and twinning, which were enhanced by the presence of hydrogen. Further studies using electron microscopy and modeling will be conducted to learn about the deformation mechanisms responsible for the observed behavior.

Garlea, E.; Morrell, J. S.; Bridges, R. L.; Powell, G. L.; Brown, d. W.; Sisneros, T. A.; Tome, C. N.; Vogel, S. C.

2011-02-14T23:59:59.000Z

304

Demonstration of a vapor density monitoring system using UV radiation generated from quasi-phasematched SHG waveguide devices  

SciTech Connect

Many industrial applications require non-intrusive diagnostics for process monitoring and control. One example is the physical vapor deposition of titanium alloys. In this paper we present a system based on laser absorption spectroscopy for monitoring titanium vapor. Appropriate transitions for monitoring high rate vaporization of titanium require extension of available IR diode technology to the UV. The heart of this vapor density monitoring system is the 390nm radiation generated from quasi-phase matched interactions within periodically poled waveguides. In this paper, key system components of a UV laser absorption spectroscopy based system specific for titanium density monitoring are described. Analysis is presented showing the minimum power levels necessary from the ultraviolet laser source. Performance data for prototype systems using second harmonic generation (SHG) waveguide technology is presented. Application of this technology to other alloy density monitoring systems is discussed.

Galanti, S.A.; Berzins, L.V.; Brown, J.B.; Tamosaitis, R.S.; Bortz, M.L.; Day, T.; Fejer, M.M.; Wang, W.

1996-01-29T23:59:59.000Z

305

ARM - Field Campaign - Water Vapor IOP  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsWater Vapor IOP govCampaignsWater Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Water Vapor IOP 1996.09.10 - 1996.09.30 Lead Scientist : Henry Revercomb For data sets, see below. Summary SCHEDULE This IOP will be conducted from September 10 - 30, 1996 (coincident with the Fall ARM-UAV IOP). Instruments that do not require supervision will be operated continuously during this period. Instruments that do require supervision are presently planned to be operated for 8-hour periods each day. Because it is necessary to cover as broad a range of environmental conditions as possible, the daily 8-hour period will be shifted across the diurnal cycle as deemed appropriate during the IOP (but will be maintained as a contiguous 8-hour block).

306

atmospheric water vapor | OpenEI  

Open Energy Info (EERE)

atmospheric water vapor atmospheric water vapor Dataset Summary Description (Abstract): Monthly Average Solar Resource for 2-axis tracking concentrating collectors for Mexico, Central America, and the Caribbean Islands. (Purpose): Provide information on the solar resource potential for the data domain. The insolation values represent the average solar energy available to a concentrating collector, such as a dish collector, which tracks the sun continuously. Source NREL Date Released July 31st, 2006 (8 years ago) Date Updated October 30th, 2007 (7 years ago) Keywords atmospheric water vapor Carribean Islands Central America DNI GIS Mexico NREL GEF solar SWERA UNEP Data application/zip icon Download Shapefile (zip, 247.8 KiB) text/csv icon Download Data (csv, 370.6 KiB) Quality Metrics Level of Review Some Review

307

atmoshperic water vapor | OpenEI  

Open Energy Info (EERE)

atmoshperic water vapor atmoshperic water vapor Dataset Summary Description (Abstract): Monthly Average Solar Resource for flat-plate collectors tilted at latitude for China. Source NREL Date Released April 12th, 2005 (9 years ago) Date Updated October 30th, 2007 (7 years ago) Keywords atmoshperic water vapor China GEF GIS NREL solar SWERA TILT UNEP Data application/zip icon Download Shapefile (zip, 625.6 KiB) text/csv icon Download Data (csv, 704.1 KiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage Frequency Time Period 01/01/1985 - 12/31/1991 License License Open Data Commons Public Domain Dedication and Licence (PDDL) Comment Rate this dataset Usefulness of the metadata Average vote Your vote Usefulness of the dataset Average vote Your vote Ease of access

308

OBSERVATIONS IN REACTIVITY BETWEEN BH CONTAINING COMPOUNDS AND ORGANOMETALLIC REAGENTS: SYNTHESIS OF BORONIC ACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES  

E-Print Network (OSTI)

aryl bromides and H 2 BN(iPr) 2 Scheme 2.7. Hydroboration oftransfer hydride to BH 2 -N(iPr) 2 Scheme 2.10. Conversionchloride with BH 2 -N(iPr) 2 Scheme 3; Aqueous quench of p-

Clary, Jacob William

2012-01-01T23:59:59.000Z

309

Combustion Processes in the Zr-Co-H2 System and Synthesis of Hydrides of Intermetallic Compounds  

Science Journals Connector (OSTI)

The researches on Zr2Co, ZrCo, ZrCo2 synthesis and hydriding in a self-propagating hightemperature synthesis — SHS mode are carried out. In IMC — hydrogen systems low temperature (350–500°C) and high temperature ...

H. G. Hakobyan; S. K. Dolukhanyan

2002-01-01T23:59:59.000Z

310

Vapor characterization of Tank 241-C-103  

SciTech Connect

The Westinghouse Hanford Company Tank Vapor Issue Resolution Program has developed, in cooperation with Northwest Instrument Systems, Inc., Oak Ridge National Laboratory, Oregon Graduate Institute of Science and Technology, Pacific Northwest Laboratory, and Sandia National Laboratory, the equipment and expertise to characterize gases and vapors in the high-level radioactive waste storage tanks at the Hanford Site in south central Washington State. This capability has been demonstrated by the characterization of the tank 241-C-103 headspace. This tank headspace is the first, and for many reasons is expected to be the most problematic, that will be characterized (Osborne 1992). Results from the most recent and comprehensive sampling event, sample job 7B, are presented for the purpose of providing scientific bases for resolution of vapor issues associated with tank 241-C-103. This report is based on the work of Clauss et al. 1994, Jenkins et al. 1994, Ligotke et al. 1994, Mahon et al. 1994, and Rasmussen and Einfeld 1994. No attempt has been made in this report to evaluate the implications of the data presented, such as the potential impact of headspace gases and vapors to tank farm workers health. That and other issues will be addressed elsewhere. Key to the resolution of worker health issues is the quantitation of compounds of toxicological concern. The Toxicology Review Panel, a panel of Pacific Northwest Laboratory experts in various areas, of toxicology, has chosen 19 previously identified compounds as being of potential toxicological concern. During sample job 7B, the sampling and analytical methodology was validated for this preliminary list of compounds of toxicological concern. Validation was performed according to guidance provided by the Tank Vapor Conference Committee, a group of analytical chemists from academic institutions and national laboratories assembled and commissioned by the Tank Vapor Issue Resolution Program.

Huckaby, J.L. [Westinghouse Hanford Co., Richland, WA (United States); Story, M.S. [Northwest Instrument Systems, Inc. Richland, WA (United States)

1994-06-01T23:59:59.000Z

311

Thermal electric vapor trap arrangement and method  

DOE Patents (OSTI)

A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

Alger, T.

1988-03-15T23:59:59.000Z

312

Diode pumped alkali vapor fiber laser  

DOE Patents (OSTI)

A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

2006-07-26T23:59:59.000Z

313

Diode pumped alkali vapor fiber laser  

DOE Patents (OSTI)

A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

2007-10-23T23:59:59.000Z

314

Micro and nanostructured surfaces for enhanced phase change heat transfer  

E-Print Network (OSTI)

Two-phase microchannel heat sinks are of significant interest for thermal management applications, where the latent heat of vaporization offers an efficient method to dissipate large heat fluxes in a compact device. However, ...

Chu, Kuang-Han, Ph. D. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

315

Design of a microbreather for two-phase microchannel devices  

E-Print Network (OSTI)

Multiphase flows in microchannels are encountered in a variety of microfluidic applications. Two-phase microchannel heat sinks leverage the latent heat of vaporization to offer an efficient method of dissipating large heat ...

Alexander, Brentan R

2008-01-01T23:59:59.000Z

316

Phase-Transfer Catalysis Displacement Reactions with Simple Anions  

Science Journals Connector (OSTI)

Phase-transfer catalysis (PTC) is an excellent technique both in liquid—liquid and liquid—solid (and sometimes in liquid—vapor) modes for conducting displacement reactions with anions.

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

317

Gas phase 129Xe NMR imaging and spectroscopy  

E-Print Network (OSTI)

5 l l Dynamic NMR microscopy of gas phase Poiseuille flowmetal vapors and noble gases can be used to efficientlypolarize the nuclei ofthe noble-gas atoms. As a result, the

Kaiser, Lana G.

2010-01-01T23:59:59.000Z

318

Phase relations in the system NaCl-KCl-H/sub 2/O. III. Solubilities of halite in vapor-saturated liquids above 445/sup 0/C and redetermination of phase equilibrium properties in the system NaCl-H/sub 2/O to 1000/sup 0/C and 1500 bars  

SciTech Connect

Halite solubilities along the three-phase curve in the binary system NaCl-H/sub 2/O determined by differential thermal analysis (DTA) experiment can be represented by the discussed equation where 447 less than or equal to T less than or equal to 800/sup 0/C. Even though these halite solubilities are up to approx. 7 wt.% higher than those reported in literature, extrapolated values at temperatures below 447/sup 0/C merge with the literature values. It is considered that the equation adequately describes halite solubilities between 382 and 800/sup 0/C. The newly established solubility data are believed to be more reliable because they are compatible with data obtained by using synthetic fluid inclusions and with the observed DTA signals and also because they were measured in a relatively corrosion-free system. In an earlier publication the authors were puzzled greatly by multiple and rather unreproducible DTA peaks appearing during isobaric cooling at pressures below about 500 bars. These DTA signals apparently suggested that the halite liquidus swung sharply upward in temperature as pressure decreased from about 500 bars to that of the halite-saturated boiling curve. Further analysis of the data and helpful discussions with several individuals have revealed that the behavior is a consequence of the initial separation of the fluid into NaCl-poor gas and NaCl-rich liquid that failed to homogenize in the short time encompassed by the DTA experiments. The present analysis is based on extrapolations of the dP/dT slopes from pressures above 500 bars.

Chou, I.

1987-07-01T23:59:59.000Z

319

Feasibility of UV lasing without inversion in mercury vapor  

E-Print Network (OSTI)

We investigate the feasibility of UV lasing without inversion at a wavelength of $253.7$ nm utilizing interacting dark resonances in mercury vapor. Our theoretical analysis starts with radiation damped optical Bloch equations for all relevant 13 atomic levels. These master equations are generalized by considering technical phase noise of the driving lasers. From the Doppler broadened complex susceptibility we obtain the stationary output power from semiclassical laser theory. The finite overlap of the driving Gaussian laser beams defines an ellipsoidal inhomogeneous gain distribution. Therefore, we evaluate the intra-cavity field inside a ring laser self-consistently with Fourier optics. This analysis confirms the feasibility of UV lasing and reveals its dependence on experimental parameters.

Martin R. Sturm; Benjamin Rein; Thomas Walther; Reinhold Walser

2014-06-27T23:59:59.000Z

320

Chemical vapor deposition of hydrogenated amorphous silicon from disilane  

SciTech Connect

The authors describe hydrogenated amorphous silicon (a-Si:H) thin films deposited at growth rates of 1 to 30 A/s by chemical vapor deposition (CVD) from disilane source gas at 24 torr total pressure in a tubular reactor. The effects of substrate temperature and gas holding time (flow rate) on film growth rate and effluent gas composition were measured at temperatures ranging from 360{sup 0} to 485{sup 0}C and gas holding times from 3 to 62s. Effluent gases determined by gas chromatography included silane, disilane and other higher order silanes. A chemical reaction engineering model, based on a silylene (SiH/sub 2/) insertion gas phase reaction network and film growth from both SiH/sub 2/ and high molecular weight silicon species, Si/sub n/H/sub 2n/, was developed. The model predictions were in good agreement with experimentally determined growth rates and effluent gas compositions.

Bogaert, R.J.; Russell, T.W.F.; Klein, M.T. (Delaware Univ., Newark, DE (USA). Dept. of Chemical Engineering); Rocheleau, R.E.; Baron, B.N. (Delaware Univ., Newark, DE (USA). Inst. of Energy Conversion)

1989-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Environmental Chemistry at Vapor/Water Interfaces  

E-Print Network (OSTI)

Environmental Chemistry at Vapor/Water Interfaces: Insights from Vibrational Sum Frequency Generation Spectroscopy Aaron M. Jubb, Wei Hua, and Heather C. Allen Department of Chemistry, The Ohio State/0505-0107$20.00 Keywords salts, lipids, atmospheric chemistry, ion binding, oxidation Abstract The chemistry that occurs

322

Advancing Explosives Detection Capabilities: Vapor Detection  

ScienceCinema (OSTI)

A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

Atkinson, David

2014-07-24T23:59:59.000Z

323

Program performs vapor-liquid equilibrium calculations  

SciTech Connect

A program designed for the Hewlett-Packard HP-41CV or 41C calculators solves basic vapor-liquid equilibrium problems, including figuring the dewpoint, bubblepoint, and equilibrium flash. The algorithm uses W.C. Edmister's method for predicting ideal-solution K values.

Rice, V.L.

1982-06-28T23:59:59.000Z

324

Vapor intrusion modeling : limitations, improvements, and value of information analyses  

E-Print Network (OSTI)

Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

Friscia, Jessica M. (Jessica Marie)

2014-01-01T23:59:59.000Z

325

Estimating the Atmospheric Water Vapor Content from Sun Photometer Measurements  

Science Journals Connector (OSTI)

The differential absorption technique for estimating columnar water vapor values from the analysis of sunphotometric measurements with wide- and narrowband interferential filters centered near 0.94 ?m is discussed and adapted. Water vapor line ...

Artemio Plana-Fattori; Michel Legrand; Didier Tanré; Claude Devaux; Anne Vermeulen; Philippe Dubuisson

1998-08-01T23:59:59.000Z

326

OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL  

E-Print Network (OSTI)

given by U.S. Department of Energy, Geothermal Division. #12;vii Table of Contents ABSTRACTOPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL RESERVOIRS CONSIDERING ADSORPTION governing the behavior of vapor- dominated geothermal reservoirs. These mechanisms affect both

Stanford University

327

X-RAY ABSORPTION SPECTROSCOPY OF TRANSITION METAL-MAGNESIUM HYDRIDE FILMS  

NLE Websites -- All DOE Office Websites (Extended Search)

Spectroscopy of Transition Metal-Magnesium Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardson a, *, B. Farangis a , J. L. Slack a , P. Nachimuthu b , R. Pereira b , N. Tamura b , and M. Rubin a a Environmental Energy Technologies Division, b Advanced Light Source, Ernest Orlando Lawrence Berkeley National Laboratory Berkeley, California 94720, USA *Corresponding author, E-mail address: tjrichardson@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption

328

Quantum Simulation of Helium Hydride in a Solid-State Spin Register  

E-Print Network (OSTI)

\\emph{Ab initio} computation of molecular properties is one of the most promising applications of quantum computing. While this problem is widely believed to be intractable for classical computers, efficient quantum algorithms exist which have the potential to vastly accelerate research throughput in fields ranging from material science to drug discovery. Using a solid-state quantum register realized in a nitrogen-vacancy (NV) defect in diamond, we compute the bond dissociation curve of the minimal basis helium hydride cation, HeH$^+$. Moreover, we report an energy uncertainty (given our model basis) of the order of $10^{-14}$ Hartree, which is ten orders of magnitude below desired chemical precision. As NV centers in diamond provide a robust and straightforward platform for quantum information processing, our work provides several important steps towards a fully scalable solid state implementation of a quantum chemistry simulator.

Ya Wang; Florian Dolde; Jacob Biamonte; Ryan Babbush; Ville Bergholm; Sen Yang; Ingmar Jakobi; Philipp Neumann; Alán Aspuru-Guzik; James D. Whitfield; Jörg Wrachtrup

2014-05-12T23:59:59.000Z

329

RF sputtering for controlling dihydride and monohydride bond densities in amorphous silicon hydride  

DOE Patents (OSTI)

A process is described for controlling the dihydride and monohydride bond densities in hydrogenated amorphous silicone produced by reactive rf sputtering of an amorphous silicon target. There is provided a chamber with an amorphous silicon target and a substrate therein with the substrate and the target positioned such that when rf power is applied to the target the substrate is in contact with the sputtering plasma produced thereby. Hydrogen and argon are fed to the chamber and the pressure is reduced in the chamber to a value sufficient to maintain a sputtering plasma therein, and then rf power is applied to the silicon target to provide a power density in the range of from about 7 watts per square inch to about 22 watts per square inch to sputter an amorphous solicone hydride onto the substrate, the dihydride bond density decreasing with an increase in the rf power density. Substantially pure monohydride films may be produced.

Jeffery, F.R.; Shanks, H.R.

1980-08-26T23:59:59.000Z

330

Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation  

DOE Patents (OSTI)

An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-bsed materials is disclosed. Samples of zirconium-based materials having different composition and/or fabrication are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280.degree. to 316.degree. C.). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hyriding for the same materials when subject to in-reactor (irradiated) corrision.

Johnson, Jr., A. Burtron (Richland, WA); Levy, Ira S. (Kennewick, WA); Trimble, Dennis J. (Kennewick, WA); Lanning, Donald D. (Kennewick, WA); Gerber, Franna S. (Richland, WA)

1990-01-01T23:59:59.000Z

331

Startup and Operation of a Metal Hydride Based Isotope Separation Process  

SciTech Connect

Production scale separation of tritium from other hydrogen isotopes at the Savannah River Site (SRS) in Aiken, SC, has been accomplished by several methods. These methods include thermal diffusion (1957--1986), fractional absorption (1964--1968), and cryogenic distillation (1967-present). Most recently, the Thermal Cycling Absorption Process (TCAP), a metal hydride based hydrogen isotope separation system, began production in the Replacement Tritium Facility (RTF) on April 9, 1994. TCAP has been in development at the Savannah River Technology Center since 1980. The production startup of this semi-continuous gas chromatographic separation process is a significant accomplishment for the Savannah River Site and was achieved after years of design, development, and testing.

Scogin, J.H.; Poore, A.S.

1995-02-27T23:59:59.000Z

332

Prediction of a multicenter-bonded solid boron hydride for hydrogen storage  

Science Journals Connector (OSTI)

A layered solid boron hydride structure (B2H2) consisting of a hexagonal boron network and bridge hydrogen which has a gravimetric capacity of 8wt% hydrogen is predicted. The structural, electronic, and dynamical properties of the proposed structure are investigated using first-principles electronic structure methods. The absence of soft phonon modes confirms the dynamical stability of the proposed structure. Charging the structure significantly softens hydrogen related phonon modes. Boron modes, in contrast, are either hardened or not significantly affected by electron doping. Furthermore, self-doping the structure considerably reduces the energy barrier against hydrogen release. These results suggest that electrochemical charging or self-doping mechanisms may facilitate hydrogen release while the underlying boron network remains intact for subsequent rehydrogenation.

Tesfaye A. Abtew; Bi-ching Shih; Pratibha Dev; Vincent H. Crespi; Peihong Zhang

2011-03-07T23:59:59.000Z

333

LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells  

DOE Patents (OSTI)

An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

1999-03-30T23:59:59.000Z

334

Production of Hydrogen by Electrocatalysis: Making the H-H Bond by Combining Protons and Hydrides  

SciTech Connect

Generation of hydrogen by reduction of two protons by two electrons can be catalysed by molecular electrocatalysts. Determination of the thermodynamic driving force for elimination of H2 from molecular complexes is important for the rational design of molecular electrocatalysts, and allows the design of metal complexes of abundant, inexpensive metals rather than precious metals (“Cheap Metals for Noble Tasks”). The rate of H2 evolution can be dramatically accelerated by incorporating pendant amines into diphosphine ligands. These pendant amines in the second coordination sphere function as protons relays, accelerating intramolecular and intermolecular proton transfer reactions. The thermodynamics of hydride transfer from metal hydrides and the acidity of protonated pendant amines (pKa of N-H) contribute to the thermodynamics of elimination of H2; both of the hydricity and acidity can be systematically varied by changing the substituents on the ligands. A series of Ni(II) electrocatalysts with pendant amines have been developed. In addition to the thermochemical considerations, the catalytic rate is strongly influenced by the ability to deliver protons to the correct location of the pendant amine. Protonation of the amine endo to the metal leads to the N-H being positioned appropriately to favor rapid heterocoupling with the M-H. Designing ligands that include proton relays that are properly positioned and thermodynamically tuned is a key principle for molecular electrocatalysts for H2 production as well as for other multi-proton, multi-electron reactions important for energy conversions. The research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for DOE.

Bullock, R. Morris; Appel, Aaron M.; Helm, Monte L.

2014-03-25T23:59:59.000Z

335

Apparent Temperature Dependence on Localized Atmospheric Water Vapor  

E-Print Network (OSTI)

Apparent Temperature Dependence on Localized Atmospheric Water Vapor Matthew Montanaroa, Carl), hence water vapor is the primary constituent of concern. The tower generates a localized water vapor, Office B108, Aiken, SC, USA ABSTRACT The atmosphere is a critical factor in remote sensing. Radiance from

Salvaggio, Carl

336

Metal organic chemical vapor deposition of 111-v compounds on silicon  

DOE Patents (OSTI)

Expitaxial composite comprising thin films of a Group III-V compound semiconductor such as gallium arsenide (GaAs) or gallium aluminum arsenide (GaAlAs) on single crystal silicon substrates are disclosed. Also disclosed is a process for manufacturing, by chemical deposition from the vapor phase, epitaxial composites as above described, and to semiconductor devices based on such epitaxial composites. The composites have particular utility for use in making light sensitive solid state solar cells.

Vernon, Stanley M. (Wellesley, MA)

1986-01-01T23:59:59.000Z

337

Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank  

Energy.gov (U.S. Department of Energy (DOE))

Case study covering Compact Membrane Systems, Inc. and its membrane vapor processor that recovers fuel vapors from gasoline refueling.

338

Precision micro drilling with copper vapor lasers  

SciTech Connect

The authors have developed a copper vapor laser based micro machining system using advanced beam quality control and precision wavefront tilting technologies. Micro drilling has been demonstrated through percussion drilling and trepanning using this system. With a 30 W copper vapor laser running at multi-kHz pulse repetition frequency, straight parallel holes with size varying from 500 microns to less than 25 microns and with aspect ratio up to 1:40 have been consistently drilled on a variety of metals with good quality. For precision trepanned holes, the hole-to-hole size variation is typically within 1% of its diameter. Hole entrance and exit are both well defined with dimension error less than a few microns. Materialography of sectioned holes shows little (sub-micron scale) recast layer and heat affected zone with surface roughness within 1--2 microns.

Chang, J.J.; Martinez, M.W.; Warner, B.E.; Dragon, E.P.; Huete, G.; Solarski, M.E.

1994-09-02T23:59:59.000Z

339

Copper vapor laser modular packaging assembly  

DOE Patents (OSTI)

A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

Alger, Terry W. (Tracy, CA); Ault, Earl R. (Dublin, CA); Moses, Edward I. (Castro Valley, CA)

1992-01-01T23:59:59.000Z

340

Materials Go/No-Go Decisions Made Within the Department of Energy Metal Hydride Center of Excellence  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Go/No-Go Decisions Made Within Materials Go/No-Go Decisions Made Within the Department of Energy Metal Hydride Center of Excellence (MHCoE) In fulfillment of the end of Fiscal Year 2007 Project Milestone on Materials Down-selection Lennie Klebanoff, Director Sandia National Laboratories Livermore, CA 94551 September/October 2007 1 Acknowledgements The author wishes to acknowledge the contributions of all Principal Investigators within the Metal Hydride Center of Excellence (MHCoE) to the work summarized herein. Their names and affiliations are listed below. Especially significant contributions to this document were made by Dr. Ewa Ronnebro (SNL), Dr. John Vajo (HRL), Prof. Zak Fang (U. Utah), Dr. Robert Bowman Jr. (JPL), Prof. David Sholl (CMU) and Prof. Craig Jensen (U. Hawaii). The author thanks Dr.

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes  

E-Print Network (OSTI)

There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

Widom, A; Larsen, L

2012-01-01T23:59:59.000Z

342

Study of integrated metal hydrides heat pump and cascade utilization of liquefied natural gas cold energy recovery system  

Science Journals Connector (OSTI)

The traditional cold energy utilization of the liquefied natural gas system needs a higher temperature heat source to improve exergy efficiency, which barricades the application of the common low quality thermal energy. The adoption of a metal hydride heat pump system powered by low quality energy could provide the necessary high temperature heat and reduce the overall energy consumption. Thus, an LNG cold energy recovery system integrating metal hydride heat pump was proposed, and the exergy analysis method was applied to study the case. The performance of the proposed integration system was evaluated. Moreover, some key factors were also theoretically investigated about their influences on the system performance. According to the results of the analysis, some optimization directions of the integrated system were also pointed out.

Xiangyu Meng; Feifei Bai; Fusheng Yang; Zewei Bao; Zaoxiao Zhang

2010-01-01T23:59:59.000Z

343

Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes  

E-Print Network (OSTI)

There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

A. Widom; Y. N. Srivastava; L. Larsen

2012-10-17T23:59:59.000Z

344

Developmental of a Vapor Cloud Explosion Risk Analysis Tool Using Exceedance Methodology  

E-Print Network (OSTI)

cloud explosions [4]. Lenoir and Davenport [5] have presented a review of many major incidents involving vapor cloud explosions worldwide from 1921 to 1991. Hydrocarbon materials such as ethane, ethylene, propane, and butane, which have been involved... are typically either in the form of gas, liquid, or two-phase. Examples of hydrocarbon gas releases are methane through butane, while liquid releases could be crude oil, diesel, jet fuel, or others. An example of a two-phase leak is condensate since it is a...

Alghamdi, Salem

2012-10-19T23:59:59.000Z

345

Heat storage system utilizing phase change materials government rights  

DOE Patents (OSTI)

A thermal energy transport and storage system is provided which includes an evaporator containing a mixture of a first phase change material and a silica powder, and a condenser containing a second phase change material. The silica powder/PCM mixture absorbs heat energy from a source such as a solar collector such that the phase change material forms a vapor which is transported from the evaporator to the condenser, where the second phase change material melts and stores the heat energy, then releases the energy to an environmental space via a heat exchanger. The vapor is condensed to a liquid which is transported back to the evaporator. The system allows the repeated transfer of thermal energy using the heat of vaporization and condensation of the phase change material.

Salyer, Ival O. (Dayton, OH)

2000-09-12T23:59:59.000Z

346

Formation of amorphous metal alloys by chemical vapor deposition  

DOE Patents (OSTI)

Amorphous alloys are deposited by a process of thermal dissociation of mixtures of organometallic compounds and metalloid hydrides,e.g., transition metal carbonyl, such as nickel carbonyl and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit. 1 fig.

Mullendore, A.W.

1988-03-18T23:59:59.000Z

347

ARM - Field Campaign - Fall 1997 Water Vapor IOP  

NLE Websites -- All DOE Office Websites (Extended Search)

Water Vapor IOP Water Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Fall 1997 Water Vapor IOP 1997.09.15 - 1997.10.05 Lead Scientist : Henry Revercomb For data sets, see below. Summary The Water Vapor IOP was conducted as a follow-up to a predecessor IOP on water vapor held in September 1996. This IOP relied heavily on both ground-based guest and CART instrumentation and in-situ aircraft and tethered sonde/kite measurements. Primary operational hours were from 6 p.m. Central until at least midnight, with aircraft support normally from about 9 p.m. until midnight when available. However, many daytime measurements were made to support this IOP. The first Water Vapor IOP primarily concentrated on the atmosphere's lowest

348

G-Band Vapor Radiometer Profiler (GVRP) Handbook  

SciTech Connect

The G-Band Vapor Radiometer Profiler (GVRP) provides time-series measurements of brightness temperatures from 15 channels between 170 and 183.310 GHz. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. Channels between 170.0 and 176.0 GHz are particularly sensitive to the presence of liquid water. The sensitivity to water vapor of the 183.31-GHz line is approximately 30 times higher than at the frequencies of the two-channel microwave radiometer (MWR) for a precipitable water vapor (PWV) amount of less than 2.5 mm. Measurements from the GVRP instrument are therefore especially useful during low-humidity conditions (PWV < 5 mm). In addition to integrated water vapor and liquid water, the GVRP can provide low-resolution vertical profiles of water vapor in very dry conditions.

Caddeau, MP

2010-06-23T23:59:59.000Z

349

Systems Modeling of Chemical Hydride Hydrogen Storage Materials for Fuel Cell Applications  

SciTech Connect

A fixed bed reactor was designed, modeled and simulated for hydrogen storage on-board the vehicle for PEM fuel cell applications. Ammonia Borane (AB) was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to {approx}16% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. The design evaluated consisted of a tank with 8 thermally isolated sections in which H2 flows freely between sections to provide ballast. Heating elements are used to initiate reactions in each section when pressure drops below a specified level in the tank. Reactor models in Excel and COMSOL were developed to demonstrate the proof-of-concept, which was then used to develop systems models in Matlab/Simulink. Experiments and drive cycle simulations showed that the storage system meets thirteen 2010 DOE targets in entirety and the remaining four at greater than 60% of the target.

Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; Holladay, Jamelyn D.

2011-10-05T23:59:59.000Z

350

Methodology of Materials Discovery in Complex Metal Hydrides Using Experimental and Computational Tools  

SciTech Connect

We present a review of the experimental and theoretical methods used in the discovery of new metal-hydrogen materials systems for hydrogen storage applications. Rather than a comprehensive review of all new materials and methods used in the metal hydride community, we focus on a specific subset of successful methods utilizing theoretical crystal structure prediction methods, computational approaches for screening large numbers of compound classes, and medium-throughput experimental methods for the preparation of such materials. Monte Carlo techniques paired with a simplified empirical Hamiltonian provide crystal structure candidates that are refined using Density Functional Theory. First-principle methods using high-quality structural candidates are further screened for an estimate of reaction energetics, decomposition enthalpies, and determination of reaction pathways. Experimental synthesis utilizes a compacted-pellet sintering technique under high-pressure hydrogen at elevated temperatures. Crystal structure determination follows from a combination of Rietveld refinements of diffraction patterns and first-principles computation of total energies and dynamical stability of competing structures. The methods presented within are general and applicable to a wide class of materials for energy storage.

Majzoub, Eric H.; Ronnebro, Ewa

2012-02-22T23:59:59.000Z

351

Mixing effect of metal oxides on negative electrode reactions in the nickel-hydride battery  

SciTech Connect

Negative electrodes for use in nickel-hydride batteries were prepared from MmNi[sub 3.6]Mn[sub 0.4]Al[sub 0.3]Co[sub 0.7] (Mm = misch metal with the composition of 24.87% La, 52.56% Ce, 5.57% Pr, 16.86% Nd, and 0.14% Sm) alloy being mixed with RuO[sub 2] or Co[sub 3]O[sub 4] powder. Then the hydrogen evolution reactions at the electrodes were investigated by measuring the potential decay immediately after the interruption of an applied cathodic current. The reactions were found to proceed by the Volmer-Tafel mechanism. The total overvoltage ([eta]) was divided into two components ([eta][sub 1] and [eta][sub 2]) corresponding to the Tafel and Volmer reactions. The exchange current densities of the elementary reactions, i[sub 0V] and i[sub 0T], were then evaluated by extrapolating the Tafel lines for [eta][sub 1] and [eta][sub 2]. The Volmer reaction is much more accelerated by surface modification with RuO[sub 2] or Co[sub 3]O[sub 4] powder than the Tafel reaction, which results in the enrichment of adsorbed hydrogen, leading to higher charging efficiency.

Iwakura, Chiaki; Matsuoka, Masao; Kohno, Tatsuoki (Univ. of Osaka Prefecture (Japan). Dept. of Applied Chemistry)

1994-09-01T23:59:59.000Z

352

The Impact of Thermal Conductivity and Diffusion Rates on Water Vapor Transport through Gas Diffusion Layers  

E-Print Network (OSTI)

Water management in a hydrogen polymer electrolyte membrane (PEM) fuel cell is critical for performance. The impact of thermal conductivity and water vapor diffusion coefficients in a gas diffusion layer (GDL) has been studied by a mathematical model. The fraction of product water that is removed in the vapour phase through the GDL as a function of GDL properties and operating conditions has been calculated and discussed. Furthermore, the current model enables identification of conditions when condensation occurs in each GDL component and calculation of temperature gradient across the interface between different layers, providing insight into the overall mechanism of water transport in a given cell design. Water transport mode and condensation conditions in the GDL components depend on the combination of water vapor diffusion coefficients and thermal conductivities of the GDL components. Different types of GDL and water removal scenarios have been identified and related to experimentally-determined GDL proper...

Burlatsky, S F; Gummallaa, M; Condita, D; Liua, F

2013-01-01T23:59:59.000Z

353

Vapor port and groundwater sampling well  

DOE Patents (OSTI)

A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

Hubbell, Joel M. (Idaho Falls, ID); Wylie, Allan H. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

354

Chemical vapor deposition of epitaxial silicon  

DOE Patents (OSTI)

A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

Berkman, Samuel (Florham Park, NJ)

1984-01-01T23:59:59.000Z

355

Recovery of benzene in an organic vapor monitor  

E-Print Network (OSTI)

solid adsorbents available (silica gel, activated alumina, etc. ), activated charcoal is most frequently utilized. Activated charcoal has retentivity for sorbed vapors several times that of silica gel and it displays a selectivity for organic vapors... (diffusion rate) of the vapor molecules to the sur- face of the adsorbent. The adsorption process determine how effective the adsorbent collects and holds the contam- inant on the surface of the activated charcoal. Recovery of the contaminant from...

Krenek, Gregory Joel

2012-06-07T23:59:59.000Z

356

Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Exploration Activity Details Location Haleakala Volcano Area Exploration Technique Mercury Vapor Activity Date Usefulness not indicated DOE-funding Unknown Notes The field survey program on the northwest rift zone consisted of soil mercury and radon emanometry surveys, groundwater temperature and chemistry studies, Schlumberger resistivity soundings and self-potential profiles. Geophysical and geochemical surveys along this rift (southwest) were limited by difficult field conditions and access limitations. The geophysical program consisted of one Schlumberger sounding, one

357

Mercury Vapor At Vale Hot Springs Area (Varekamp & Buseck, 1983...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Vale Hot Springs Area (Varekamp & Buseck, 1983) Exploration Activity Details...

358

Mercury Vapor At Breitenbush Hot Springs Area (Varekamp & Buseck...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Breitenbush Hot Springs Area (Varekamp & Buseck, 1983) Exploration Activity...

359

Mercury Vapor At Mickey Hot Springs Area (Varekamp & Buseck,...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mickey Hot Springs Area (Varekamp & Buseck, 1983) Exploration Activity...

360

Mercury Vapor At Desert Peak Area (Varekamp & Buseck, 1983) ...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Desert Peak Area (Varekamp & Buseck, 1983) Exploration Activity Details...

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Mercury Vapor At Socorro Mountain Area (Kooten, 1987) | Open...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Socorro Mountain Area (Kooten, 1987) Exploration Activity Details Location...

362

Mercury Vapor At Lassen Volcanic National Park Area (Varekamp...  

Open Energy Info (EERE)

Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lassen Volcanic National Park Area (Varekamp & Buseck, 1983) Exploration...

363

Thermal Performance of a Double-Tube Type Lng Vaporizer  

Science Journals Connector (OSTI)

This report concerns the confirmed test results and method of analysis of the thermal performance of a double-tube type LNG vaporizer (DTV). The DTV is a...

Y. Miyata; T. Miura; S. Kasahara; H. Shohtani…

1994-01-01T23:59:59.000Z

364

Optimal Control of Vapor Extraction of Heavy Oil.  

E-Print Network (OSTI)

??Vapor extraction (Vapex) process is an emerging technology for viscous oil recovery that has gained much attention in the oil industry. However, the oil production… (more)

Muhamad, Hameed (Author)

2012-01-01T23:59:59.000Z

365

Geographic Information System At Cove Fort Area - Vapor (Nash...  

Open Energy Info (EERE)

navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geographic Information System At Cove Fort Area - Vapor (Nash, Et Al., 2002) Exploration Activity Details...

366

Raman Lidar Measurements of Aerosols and Water Vapor During the...  

NLE Websites -- All DOE Office Websites (Extended Search)

modifications reduced but could not eliminate these adverse effects. The Raman lidar water vapor (aerosol extinction) measurements produced by these modified algorithms were,...

367

Thermal Gradient Holes At Cove Fort Area - Vapor (Warpinski,...  

Open Energy Info (EERE)

Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Cove Fort Area - Vapor (Warpinski, Et Al.,...

368

Ground Magnetics At Cove Fort Area - Vapor (Warpinski, Et Al...  

Open Energy Info (EERE)

Vapor (Warpinski, Et Al., 2004) Exploration Activity Details Location Cove Fort Geothermal Area Exploration Technique Ground Magnetics Activity Date Usefulness useful DOE-funding...

369

Synthesis of alloys with controlled phase structure  

DOE Patents (OSTI)

A method for preparing controlled phase alloys useful for engineering and hydrogen storage applications. This novel method avoids melting the constituents by employing vapor transport, in a hydrogen atmosphere, of an active metal constituent, having a high vapor pressure at temperatures .apprxeq.300 C. and its subsequent condensation on and reaction with the other constituent (substrate) of an alloy thereby forming a controlled phase alloy and preferably a single phase alloy. It is preferred that the substrate material be a metal powder such that diffusion of the active metal constituent, preferably magnesium, and reaction therewith can be completed within a reasonable time and at temperatures .apprxeq.300 C. thereby avoiding undesirable effects such as sintering, local compositional inhomogeneities, segregation, and formation of unwanted second phases such as intermetallic compounds.

Guthrie, Stephen Everett (Livermore, CA); Thomas, George John (Livermore, CA); Bauer, Walter (Livermore, CA); Yang, Nancy Yuan Chi (Lafayette, CA)

1999-04-20T23:59:59.000Z

370

Synthesis of alloys with controlled phase structure  

DOE Patents (OSTI)

A method is described for preparing controlled phase alloys useful for engineering and hydrogen storage applications. This novel method avoids melting the constituents by employing vapor transport, in a hydrogen atmosphere, of an active metal constituent, having a high vapor pressure at temperatures {approx_equal}300 C and its subsequent condensation on and reaction with the other constituent (substrate) of an alloy thereby forming a controlled phase alloy and preferably a single phase alloy. It is preferred that the substrate material be a metal powder such that diffusion of the active metal constituent, preferably magnesium, and reaction therewith can be completed within a reasonable time and at temperatures {approx_equal}300 C thereby avoiding undesirable effects such as sintering, local compositional inhomogeneities, segregation, and formation of unwanted second phases such as intermetallic compounds. 4 figs.

Guthrie, S.E.; Thomas, G.J.; Bauer, W.; Yang, N.Y.C.

1999-04-20T23:59:59.000Z

371

Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates  

NLE Websites -- All DOE Office Websites (Extended Search)

Integration of Global Positioning System and Scanning Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates V. Mattioli and P. Basili Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado Introduction In recent years the Global Positioning System (GPS) has proved to be a reliable instrument for measuring precipitable water vapor (PWV) (Bevis et al. 1992), offering an independent source of information on water vapor when compared with microwave radiometers (MWRs), and/or radiosonde

372

Vapor and gas sampling of Single-Shell Tank 241-T-111 using the vapor sampling system  

SciTech Connect

This document presents sampling data resulting from the January 20, 1995, sampling of SST 241-T-111 using the vapor sampling system.

Caprio, G.S.

1995-09-01T23:59:59.000Z

373

Vapor and gas sampling of single-shell tank 241-BY-112 using the vapor sampling system  

SciTech Connect

This document presents sampling data from the November 18, 1994, sampling of SST 241-BY-112 using the vapor sampling system.

Caprio, G.S.

1995-09-20T23:59:59.000Z

374

Development of a Water Based, Critical Flow, Non-Vapor Compression cooling Cycle  

SciTech Connect

Expansion of a high-pressure liquid refrigerant through the use of a thermostatic expansion valve or other device is commonplace in vapor-compression cycles to regulate the quality and flow rate of the refrigerant entering the evaporator. In vapor-compression systems, as the condensed refrigerant undergoes this expansion, its pressure and temperature drop, and part of the liquid evaporates. We (researchers at Kansas State University) are developing a cooling cycle that instead pumps a high-pressure refrigerant through a supersonic converging-diverging nozzle. As the liquid refrigerant passes through the nozzle, its velocity reaches supersonic (or critical-flow) conditions, substantially decreasing the refrigerant’s pressure. This sharp pressure change vaporizes some of the refrigerant and absorbs heat from the surrounding conditions during this phase change. Due to the design of the nozzle, a shockwave trips the supersonic two-phase refrigerant back to the starting conditions, condensing the remaining vapor. The critical-flow refrigeration cycle would provide space cooling, similar to a chiller, by running a secondary fluid such as water or glycol over one or more nozzles. Rather than utilizing a compressor to raise the pressure of the refrigerant, as in a vapor-cycle system, the critical-flow cycle utilizes a high-pressure pump to drive refrigerant liquid through the cooling cycle. Additionally, the design of the nozzle can be tailored for a given refrigerant, such that environmentally benign substances can act as the working fluid. This refrigeration cycle is still in early-stage development with prototype development several years away. The complex multi-phase flow at supersonic conditions presents numerous challenges to fully understanding and modeling the cycle. With the support of DOE and venture-capital investors, initial research was conducted at PAX Streamline, and later, at Caitin. We (researchers at Kansas State University) have continued development of the cycle and have gained an in-depth understanding of the governing fundamental knowledge, based on the laws of physics and thermodynamics and verified with our testing results. Through this research, we are identifying optimal working fluid and operating conditions to eventually demonstrate the core technology for space cooling or other applications.

Hosni, Mohammad H.

2014-03-30T23:59:59.000Z

375

Chemical vapor deposition of amorphous silicon films from disilane  

SciTech Connect

Amorphous silicon films for fabrication of solar cells have been deposited by thermal chemical vapor deposition (CVD) from disilane (Si/sub 2/H/sub 6/) using a tubular flow reactor. A mathematical description for the CVD reactor was developed and solved by a numerical procedure. The proposed chemical reaction network for the model is based on silylene (SiH/sub 2/) insertion in the gas phase and film growth from SiH/sub 2/ and silicon polymers (Si/sub n/N/sub 2n/, n approx. 10). Estimates of the rate constants have been obtained for trisilane decomposition, silicon polymer formation, and polymer dehydrogenation. The silane unimolecular decomposition rate constants were corrected for pressure effects. The model behavior is compared to the experimental results over the range of conditions: reactor temperature (360 to 485/sup 0/C), pressures (2 to 48 torr), and gas holding time (1 to 70 s). Within the above range of conditions, film growth rate varies from 0.01 to 30 A/s. Results indicate that silicon polymers are the main film precursors for gas holding times greater than 3 s. Film growth by silylene only becomes important at short holding times, large inert gas dilution, and positions near the beginning of the reactor hot zone.

Bogaert, R.J.

1986-01-01T23:59:59.000Z

376

Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-  

E-Print Network (OSTI)

I BNL- 62834 Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-· [D VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY- A DISCUSSION OF TECHNICAL FEASIBILITY Concept MONEY --A DISCUSSION OF TECHNICAL FEASffiILITY Russell N. Dietz, Head Tracer Technology Center

377

RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR  

E-Print Network (OSTI)

RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR By SCOTT RUSSELL WAITUKAITIS A Thesis Submitted: #12;Abstract I describe a study of Faraday rotation in a hot lithium vapor. I begin by dis- cussing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.3 The Lithium Oven and Solenoid . . . . . . . . . . . . . . . . . 7 3 Theoretical Framework

Cronin, Alex D.

378

Gas: A Neglected Phase in Remediation of Metals and Radionuclides  

SciTech Connect

The gas phase is generally ignored in remediation of metals and radionuclides because it is assumed that there is no efficient way to exploit it. In the literal sense, all remediations involve the gas phase because this phase is linked to the liquid and solid phases by vapor pressure and thermodynamic relationships. Remediation methods that specifically use the gas phase as a central feature have primarily targeted volatile organic contaminants, not metals and radionuclides. Unlike many organic contaminants, the vapor pressure and Henry's Law constants of metals and radionuclides are not generally conducive to direct air stripping of dissolved contaminants. Nevertheless, the gas phase can play an important role in remediation of inorganic contaminants and provide opportunities for efficient, cost effective remediation. The objective here is to explore ways in which manipulation of the gas phase can be used to facilitate remediation of metals and radionuclides.

Denham, Miles E.; Looney, Brian B

2005-09-28T23:59:59.000Z

379

FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS  

Office of Scientific and Technical Information (OSTI)

Bulletin 627 Bulletin 627 BUREAU o b MINES FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS By Michael G. Zabetakis DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement,

380

New Regenerative Cycle for Vapor Compression Refrigeration  

Office of Scientific and Technical Information (OSTI)

SCIENTIFIC REPORT SCIENTIFIC REPORT Title Page Project Title: New Regenerative Cycle for Vapor Compression Refrigeration DOE Award Number: DE-FG36-04GO14327 Document Title: Final Scientific Report Period Covered by Report: September 30, 2004 to September 30, 2005 Name and Address of Recipient Organization: Magnetic Development, Inc., 68 Winterhill Road, Madison, CT 06443, phone: 203-214-7247, fax: 203-421-7948, e-mail: mjb1000@aol.com Contact Information: Mark J. Bergander, Ph.D., P.E., Principal Investigator, phone: 203-214-7247, fax: 203-421-7948, e-mail: mjb1000@aol.com Project Objective (as stated in the proposal): The main objective of this project is to confirm on a well-instrumented prototype the theoretically derived claims of higher efficiency and coefficient

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Chemical vapor deposition of group IIIB metals  

DOE Patents (OSTI)

Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

Erbil, A.

1989-11-21T23:59:59.000Z

382

Kinetics of wet sodium vapor complex plasma  

SciTech Connect

In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

2014-04-15T23:59:59.000Z

383

Photo-Electric Ionization of Caesium Vapor  

Science Journals Connector (OSTI)

Measurement of photo-electric ionization in gases.—The current from a filament, normally limited by space change, is increased by the presence of positive ions. As shown by Kingdon this effect may be greatly magnified if a small cathode is practically enclosed by the anode so that the ions are imprisoned. This method was used for the detection of photo-electric ionization. Besides possessing extreme sensitivity it is unaffected by photo-electric emission from the electrodes.Photo-electric effect in caesium vapor.—The change in thermionic current with the unresolved radiation from a mercury arc was measured as functions of the applied voltage, filament temperature, and vapor pressure. Then the photo-electric effect as a function of wave-length was studied using a monochromatic illuminator to disperse light from the arc or a Mazda lamp. The ionization per unit flux was found to increase with increasing wave-length to a sharp maximum at the limit 1s=3184A of the principal series, as is required by the Bohr theory. For longer wave-lengths the ionization decreased to about 10 percent at 3400A. Photo-excitation. The simple theory does not admit of ionization by wave-lengths greater than 3184A but the data are in qualitative agreement with the hypothesis that such radiation produces excited atoms which upon collision with other atoms acquire sufficient additional energy to become ionized. Hence, unlike an x-ray limit, the photo-ionization effect for a valence electron is not sharply discontinuous at the true threshold for direct ionization.Photo-ionization photometer and intensitometer. A tube of the type described, with suitable gases for the range of wave-length involved, may be used as a photometer or may be calibrated to measure intensity of radiation directly.

Paul D. Foote and F. L. Mohler

1925-08-01T23:59:59.000Z

384

Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes  

DOE Patents (OSTI)

A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

2003-06-03T23:59:59.000Z

385

Hybrid Vapor Compression Adsorption System: Thermal Storage Using Hybrid Vapor Compression Adsorption System  

SciTech Connect

HEATS Project: UTRC is developing a new climate-control system for EVs that uses a hybrid vapor compression adsorption system with thermal energy storage. The targeted, closed system will use energy during the battery-charging step to recharge the thermal storage, and it will use minimal power to provide cooling or heating to the cabin during a drive cycle. The team will use a unique approach of absorbing a refrigerant on a metal salt, which will create a lightweight, high-energy-density refrigerant. This unique working pair can operate indefinitely as a traditional vapor compression heat pump using electrical energy, if desired. The project will deliver a hot-and-cold battery that provides comfort to the passengers using minimal power, substantially extending the driving range of EVs.

None

2012-01-04T23:59:59.000Z

386

E-Print Network 3.0 - atomic vapor laser Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

with the exception of pagination. IEEE TRANSACTIONS ON PLASMA SCIENCE 1 Summary: vapor, atomic physics and vapor ionization, absorption reflection in a heated plasma layer, and...

387

E-Print Network 3.0 - atom vapor cells Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

rotation in the vapor cell due to inten- sity-induced birefringence in the rubidium atomic vapor. While... Super efficient absorption filter for quantum memory using atomic...

388

Ultra compact direct hydrogen fuel cell prototype using a metal hydride hydrogen storage tank for a mobile phone  

Science Journals Connector (OSTI)

Abstract The small fuel cell is being researched as an alternative power source to the Li-ion battery in mobile phone. In this paper, a direct hydrogen fuel cell system which powers a mobile phone without a supplementary battery is compactly integrated below 25 ml volume at the backside of the phone. The system consists of a small (8 ml) metal hydride hydrogen storage tank with 4 L hydrogen storage or an energy density of ?640 W h/L, a thin air-breathing planar polymer electrolyte membrane fuel cell (PEMFC) stack (13.44 cm2 × 3 mm for a volumetric power density of 335 W/L), miniature pressure regulator, and a high efficiency DC–DC voltage converting circuitry. The hydrogen storage tank is packed with the AB5 type metal hydride alloy. The eight-cell air-breathing planar stack (8 ml) is very thin (3 mm) due to a thin flexible printed circuit board current collectors as well as a unique riveting assembly and is capable of a robust performance of 2.68 W (200 mW/cm2). A miniature pressure regulator is compact with fluidic and electrical connections within 4 ml. A miniature DC–DC voltage converter operates at an overall efficiency of 90%. Consequently, the estimated energy density of a fully integrated fuel cell system is 205 W h/L (70.5 W h/kg).

Sung Han Kim; Craig M. Miesse; Hee Bum Lee; Ik Whang Chang; Yong Sheen Hwang; Jae Hyuk Jang; Suk Won Cha

2014-01-01T23:59:59.000Z

389

Model based design of an automotive-scale, metal hydride hydrogen storage system.  

SciTech Connect

Sandia and General Motors have successfully designed, fabricated, and experimentally operated a vehicle-scale hydrogen storage system using the complex metal hydride sodium alanate. Over the 6 year project, the team tackled the primary barriers associated with storage and delivery of hydrogen including mass, volume, efficiency and cost. The result was the hydrogen storage demonstration system design. The key technologies developed for this hydrogen storage system include optimal heat exchange designs, thermal properties enhancement, a unique catalytic hydrogen burner and energy efficient control schemes. The prototype system designed, built, and operated to demonstrate these technologies consists of four identical hydrogen storage modules with a total hydrogen capacity of 3 kg. Each module consists of twelve stainless steel tubes that contain the enhanced sodium alanate. The tubes are arranged in a staggered, 4 x 3 array and enclosed by a steel shell to form a shell and tube heat exchanger. Temperature control during hydrogen absorption and desorption is accomplished by circulating a heat transfer fluid through each module shell. For desorption, heat is provided by the catalytic oxidation of hydrogen within a high efficiency, compact heat exchanger. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to the circulating heat transfer fluid. The demonstration system module design and the system control strategies were enabled by experiment-based, computational simulations that included heat and mass transfer coupled with chemical kinetics. Module heat exchange systems were optimized using multi-dimensional models of coupled fluid dynamics and heat transfer. Chemical kinetics models were coupled with both heat and mass transfer calculations to design the sodium alanate vessels. Fluid flow distribution was a key aspect of the design for the hydrogen storage modules and computational simulations were used to balance heat transfer with fluid pressure requirements. An overview of the hydrogen storage system will be given, and examples of these models and simulation results will be described and related to component design. In addition, comparisons of demonstration system experimental results to model predictions will be reported.

Johnson, Terry Alan; Kanouff, Michael P.; Jorgensen, Scott W. (General Motors R& D); Dedrick, Daniel E.; Evans, Gregory Herbert

2010-11-01T23:59:59.000Z

390

Mercury Vapor At Medicine Lake Area (Kooten, 1987) | Open Energy  

Open Energy Info (EERE)

Kooten, 1987) Kooten, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Medicine Lake Area (Kooten, 1987) Exploration Activity Details Location Medicine Lake Area Exploration Technique Mercury Vapor Activity Date Usefulness could be useful with more improvements DOE-funding Unknown References Gerald K. Van Kooten (1987) Geothermal Exploration Using Surface Mercury Geochemistry Retrieved from "http://en.openei.org/w/index.php?title=Mercury_Vapor_At_Medicine_Lake_Area_(Kooten,_1987)&oldid=386431" Category: Exploration Activities What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation:

391

Identification of a new pseudo-binary hydroxide during calendar corrosion of (La, Mg)2Ni7-type hydrogen storage alloys for Nickel-Metal Hydride batteries  

E-Print Network (OSTI)

hydrogen storage alloys for Nickel-Metal Hydride batteries J. Monnier 1 , H. Chen 1 , S. Joiret2,3 , J present higher hydrogen storage capacity and higher discharge capacity, eg. 356mAh/g for LaCaMgNi9 [4 in the huge market of hybrid electric vehicles (HEV) and Emergency Light Units (ELU). Hydrogen

Boyer, Edmond

392

Phase equilibrium studies  

SciTech Connect

A phase equilibrium model has been developed for the SRC-I process, as well as the other coal liquefaction processes. It is applicable to both vapor/liquid and liquid/liquid equilibria; it also provides an approximate but adequate description of aqueous mixtures where the volatile electrolyte components dissociate to form ionic species. This report completes the description of the model presented in an earlier report (Mathias and Stein, 1983a). Comparisons of the model to previously published data on coal-fluid mixtures are presented. Further, a preliminary analysis of new data on SRC-I coal fluids is presented. Finally, the current capabilities and deficiencies of the model are discussed. 25 references, 17 figures, 30 tables.

Mathias, P.M.; Stein, F.P.

1983-09-01T23:59:59.000Z

393

Catalytic Reactor For Oxidizing Mercury Vapor  

DOE Patents (OSTI)

A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

Helfritch, Dennis J. (Baltimore, MD)

1998-07-28T23:59:59.000Z

394

Laser techniques for studying chemical vapor deposition  

SciTech Connect

Chemical vapor deposition (CVD) is widely used to produce thin films for microelectronics, protective coatings and other materials processing applications. Despite the large number of applications, however, little is known about the fundamental chemistry and physics of most CVD processes. CVD recipes have generally been determined empirically, but as process requirements become more stringent, a more basic understanding will be needed to improve reactor design and speed process optimization. In situ measurements of the reacting gas are important steps toward gaining such an understanding, both from the standpoint of characterizing the reactor and testing models of a CVD process. Our work, a coordinated program of experimental and theoretical research in the fundamental mechanisms of CVD, illustrates the application of laser techniques to the understanding of a CVD system. We have used a number of laser-based techniques to probe CVD systems and have compared our measurements with predictions from computer models, primarily for the silane CVD system. The silane CVD model solves the two-dimensional, steady-state boundary layer equations of fluid flow coupled to 26 elementary chemical reactions describing the thermal decomposition of silane and the subsequent reactions of intermediate species that result in the deposition of a silicon film.

Ho, P.; Breiland, W.G.; Coltrin, M.E.

1990-01-01T23:59:59.000Z

395

Phase five  

NLE Websites -- All DOE Office Websites (Extended Search)

Phase five Phase five 1663 Los Alamos science and technology magazine Latest Issue:November 2013 All Issues » submit Phase five Los Alamos physicists have conclusively demonstrated the existence of a new phase of matter. November 25, 2013 Phase five Scientists still have more to learn about the exotic physics of specialty materials. What makes the cuprates special? How about a new phase of matter. Ceramic metals known as cuprates have mystified physicists for decades. They exhibit a variety of distinct phases of matter, each with its own specific properties, including a phase bearing an exotic type of magnetism, a high-temperature superconducting phase, an ordinary metal phase, a poorly understood and weird metallic phase simply called a strange metal, and an equally poorly understood metallic phase known as the pseudogap. The

396

ARM - Field Campaign - Arctic Winter Water Vapor IOP  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsArctic Winter Water Vapor IOP govCampaignsArctic Winter Water Vapor IOP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Arctic Winter Water Vapor IOP 2004.03.09 - 2004.04.09 Lead Scientist : Ed Westwater Data Availability http://www.etl.noaa.gov/programs/2004/wviop/data will contain quicklooks of all of the data. For data sets, see below. Summary During the IOP, the Ground-based Scanning Radiometer of NOAA/ETL, and the ARM MicroWave Radiometer and Microwave Profiler, yielded excellent data over a range of conditions. In all, angular-scanned and calibrated radiometric data from 22.345 to 380 GHz were taken. The Precipitable Water Vapor varied about an order of magnitude from 1 to 10 mm, and surface temperatures varied from about -10 to -40 deg. Celcius. Vaisala RS90

397

Overview of the ARM/FIRE Water Vapor Experiment (AFWEX)  

NLE Websites -- All DOE Office Websites (Extended Search)

Overview of the ARM/FIRE Water Vapor Overview of the ARM/FIRE Water Vapor Experiment (AFWEX) D. C. Tobin, H. E. Revercomb, and D. D. Turner University of Wisconsin-Madison Madison, Wisconsin Introduction An overview of the ARM/FIRE Water Vapor Experiment (AFWEX) is given. This field experiment was conducted during November-December 2000 near the central ground-based Atmospheric Radiation Measurement (ARM) site in north central Oklahoma, and was sponsored jointly by the ARM, the National Aeronautics and Space Administration (NASA) First ISCCP Regional Experiment (FIRE), and the National Polar-orbiting Operational Environmental Satellite System (NPOESS) programs. Its primary goal was to collect accurate measurements of upper-level (~8 to 12 km) water vapor near the ground-based ARM site. These data are being used to determine the accuracy of measurements that are

398

Initiated chemical vapor deposition of functional polyacrylic thin films  

E-Print Network (OSTI)

Initiated chemical vapor deposition (iCVD) was explored as a novel method for synthesis of functional polyacrylic thin films. The process introduces a peroxide initiator, which can be decomposed at low temperatures (<200?C) ...

Mao, Yu, 1975-

2005-01-01T23:59:59.000Z

399

Low Level Heat Recovery Through Heat Pumps and Vapor Recompression  

E-Print Network (OSTI)

The intent of this paper is to examine the methods and economics of recovering low level heat through heat pumps and vapor recompression. Actual commercially available equipment is considered to determine the near-term and future economic viability...

Gilbert, J.

1980-01-01T23:59:59.000Z

400

Applications of Mechanical Vapor Recompression to Evaporation and Crystallization  

E-Print Network (OSTI)

there is no boiler plant available or when electrical power is priced competitively in comparison to steam. Vapor recompression is accomplished using centrifugal, axial-flow, or positive displacement compressors and these compressors can be powered by electricity...

Outland, J. S.

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Enabling integration of vapor-deposited polymer thin films  

E-Print Network (OSTI)

Initiated Chemical Vapor Deposition (iCVD) is a versatile, one-step process for synthesizing conformal and functional polymer thin films on a variety of substrates. This thesis emphasizes the development of tools to further ...

Petruczok, Christy D. (Christy Danielle)

2014-01-01T23:59:59.000Z

402

Hyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy  

E-Print Network (OSTI)

the frequency of a laser with respect to an atomic spectral feature.[20] As such, saturated absorptionHyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 Broadening Mechanisms . . . . . . . . . . . . . . . . . . . . . 15 3.4 Saturated Absorption

Cronin, Alex D.

403

All graphene electromechanical switch fabricated by chemical vapor deposition  

E-Print Network (OSTI)

We demonstrate an electromechanical switch comprising two polycrystalline graphene films; each deposited using ambient pressure chemical vapor deposition. The top film is pulled into electrical contact with the bottom film ...

Milaninia, Kaveh M.

404

Systems and methods for generation of hydrogen peroxide vapor  

DOE Patents (OSTI)

A system according to one embodiment includes a moisture trap for drying air; at least one of a first container and a second container; and a mechanism for at least one of: bubbling dried air from the moisture trap through a hydrogen peroxide solution in the first container for producing a hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above a hydrogen peroxide solution in the second container for producing a hydrogen peroxide vapor. A method according one embodiment includes at least one of bubbling dried air through a hydrogen peroxide solution in a container for producing a first hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above the hydrogen peroxide solution in a container for producing a second hydrogen peroxide vapor. Additional systems and methods are also presented.

Love, Adam H; Eckels, Joel Del; Vu, Alexander K; Alcaraz, Armando; Reynolds, John G

2014-12-02T23:59:59.000Z

405

Optical Precursors in Rubidium Vapor and Their Relation to Superradiance  

E-Print Network (OSTI)

Optical precursor is the sharp optical pulse front that does not show delay in absorptive media. In this thesis, optical precursor behavior in rubidium (Rb) vapor was investigated in the picoseconds regime. An amplified femtosecond laser was shaped...

Yang, Wenlong

2012-10-19T23:59:59.000Z

406

Photocoupling of Methane in Water Vapor to Saturated Hydrocarbons  

Science Journals Connector (OSTI)

Methane can be converted into alkanes (from C2 to C6) continuously by ultraviolet (185 nm) irradiation in the presence of water vapor. The products from this reaction are alkanes, which is different from the comp...

JunePyo Oh; Taketoshi Matsumoto; Junji Nakamura

2008-08-01T23:59:59.000Z

407

Mercury Vapor At Kawaihae Area (Thomas, 1986) | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor At Kawaihae Area (Thomas, 1986) Mercury Vapor At Kawaihae Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Kawaihae Area (Thomas, 1986) Exploration Activity Details Location Kawaihae Area Exploration Technique Mercury Vapor Activity Date Usefulness not useful DOE-funding Unknown Notes The soil geochemistry yielded quite complex patterns of mercury concentrations and radonemanation rates within the survey area (Cox and Cuff, 1981c). Mercury concentrations (Fig. 38) showed a general minimum along the Kawaihae-Waimea roads and a broad trend of increasing mercury concentrations toward both the north and south. There is no correlation apparent between the mercury patterns and either the resistivity sounding data or the surface geology in the area. The radon emanometry data (Fig.

408

Mercury Vapor At Lualualei Valley Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lualualei Valley Area (Thomas, 1986) Exploration Activity Details Location Lualualei Valley Area Exploration Technique Mercury Vapor Activity Date Usefulness useful DOE-funding Unknown Notes Soil mercury and radon emanation surveys were performed over much of the accessible surface of Lualualei Valley (Cox and Thomas, 1979). The results of these surveys (Figs 7 and 8) delineated several areas in which soil mercury concentrations or radon emanation rates were substantially above normal background values. Some of these areas were apparently coincident with the mapped fracture systems associated with the caldera boundaries.

409

Quantitative IR Spectrum and Vibrational Assignments for Glycolaldehyde Vapor: Glycolaldehyde Measurements in Biomass Burning Plumes  

SciTech Connect

Glycolaldehyde (GA, 2-hydroxyethanal, C2H4O2) is a semi-volatile molecule of atmospheric importance, recently proposed as a precursor in the formation of aqueous-phase secondary organic aerosol (SOA). There are few methods to measure glycolaldehyde vapor, but infrared spectroscopy has been used successfully. Using vetted protocols we have completed the first assignment of all fundamental vibrational modes and derived quantitative IR absorption band strengths using both neat and pressure-broadened GA vapor. Even though GA is problematic due to its propensity to both dimerize and condense, our intensities agree well with the few previously published values. Using the reference ?10 band Q-branch at 860.51 cm-1, we have also determined GA mixing ratios in biomass burning plumes generated by field and laboratory burns of fuels from the southeastern and southwestern United States, including the first field measurements of glycolaldehyde in smoke. The GA emission factors were anti-correlated with modified combustion efficiency confirming release of GA from smoldering combustion. The GA emission factors (g of GA emitted per kg dry biomass burned on a dry mass basis) had a low dependence on fuel type consistent with the production mechanism being pyrolysis of cellulose. GA was emitted at 0.23 ± 0.13% of CO from field fires and we calculate that it accounts for ~18% of the aqueous-phase SOA precursors that we were able to measure.

Johnson, Timothy J.; Sams, Robert L.; Profeta, Luisa T.; Akagi, Sheryl; Burling, Ian R.; Yokelson, Robert J.; Williams, Stephen D.

2013-04-15T23:59:59.000Z

410

Advanced Chemical Heat Pumps Using Liquid-Vapor Reactions  

E-Print Network (OSTI)

ically feasible systems have significant potential advantage over conventional tech nology. An electric drive reactive heat pump can use smaller heat exchangers and compressor than a vapor-compression machine, and have more flexible operating... are discussed, and performance is bounded. A discussion on liquid-vapor equilibria is included as introduction to the systems I- considered. The electric drive heat pump and TA are promising systems; the TA has potential for higher COP than absorption...

Kirol, L.

411

D/sup -/ production by charge transfer in metal vapors  

SciTech Connect

Fast D/sup -/ ions can be produced from D/sup +/ by multiple charge-transfer collisions in a metal-vapor target. Experimental cross sections and thick-target D/sup -/ yields are presented and discussed. The high D/sup -/ yield experimentally observed from charge transfer in cesium vapor is consistent with recent low-energy cross-section calculations and measurements.

Schlachter, A.S.

1980-10-01T23:59:59.000Z

412

Injection locked oscillator system for pulsed metal vapor lasers  

DOE Patents (OSTI)

An injection locked oscillator system for pulsed metal vapor lasers is disclosed. The invention includes the combination of a seeding oscillator with an injection locked oscillator (ILO) for improving the quality, particularly the intensity, of an output laser beam pulse. The present invention includes means for matching the first seeder laser pulses from the seeding oscillator to second laser pulses of a metal vapor laser to improve the quality, and particularly the intensity, of the output laser beam pulse.

Warner, Bruce E. (Livermore, CA); Ault, Earl R. (Dublin, CA)

1988-01-01T23:59:59.000Z

413

The affect of erbium hydride on the conversion efficience to accelerated protons from ultra-shsort pulse laser irradiated foils  

SciTech Connect

This thesis work explores, experimentally, the potential gains in the conversion efficiency from ultra-intense laser light to proton beams using erbium hydride coatings. For years, it has been known that contaminants at the rear surface of an ultra-intense laser irradiated thin foil will be accelerated to multi-MeV. Inertial Confinement Fusion fast ignition using proton beams as the igniter source requires of about 10{sup 16} protons with an average energy of about 3MeV. This is far more than the 10{sup 12} protons available in the contaminant layer. Target designs must include some form of a hydrogen rich coating that can be made thick enough to support the beam requirements of fast ignition. Work with computer simulations of thin foils suggest the atomic mass of the non-hydrogen atoms in the surface layer has a strong affect on the conversion efficiency to protons. For example, the 167amu erbium atoms will take less energy away from the proton beam than a coating using carbon with a mass of 12amu. A pure hydrogen coating would be ideal, but technologically is not feasible at this time. In the experiments performed for my thesis, ErH{sub 3} coatings on 5 {micro}m gold foils are compared with typical contaminants which are approximately equivalent to CH{sub 1.7}. It will be shown that there was a factor of 1.25 {+-} 0.19 improvement in the conversion efficiency for protons above 3MeV using erbium hydride using the Callisto laser. Callisto is a 10J per pulse, 800nm wavelength laser with a pulse duration of 200fs and can be focused to a peak intensity of about 5 x 10{sup 19}W/cm{sup 2}. The total number of protons from either target type was on the order of 10{sup 10}. Furthermore, the same experiment was performed on the Titan laser, which has a 500fs pulse duration, 150J of energy and can be focused to about 3 x 10{sup 20} W/cm{sup 2}. In this experiment 10{sup 12} protons were seen from both erbium hydride and contaminants on 14 {micro} m gold foils. Significant improvements were also observed but possibly because of the depletion of hydrogen in the contaminant layer case.

Offermann, D

2008-09-04T23:59:59.000Z

414

Tank 241-S-102 headspace gas and vapor characterization results for samples collected in March 1995  

SciTech Connect

Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories

Huckaby, J.L. [Pacific Northwest Lab., Richland, WA (United States); Bratzel, D.R. [Westinghouse Hanford Co., Richland, WA (United States)

1995-09-26T23:59:59.000Z

415

investigating the source, transport, and isotope fractionation of water vapor in the atmospheric boundary layer  

E-Print Network (OSTI)

investigating the source, transport, and isotope fractionation of water vapor in the atmospheric cospectral similarity for temperature and water vapor isotope fluxes. mixing ratio generator Routine field use in water vapor isotope research. The unit generates a stable water vapor mixing ratio by measuring

Minnesota, University of

416

Calculating the vapor pressure of water from the second law of thermodynamics  

Science Journals Connector (OSTI)

Calculating the vapor pressure of water from the second law of thermodynamics ... Thermodynamics ...

M. H. Everdell

1969-01-01T23:59:59.000Z

417

Tank Vapor Characterization Project: Annual status report for FY 1996  

SciTech Connect

In Fiscal Year 1996, staff at the Vapor Analytical Laboratory at Pacific Northwest National Laboratory performed work in support of characterizing the vapor composition of the headspaces of radioactive waste tanks at the Hanford Site. Work performed included support for technical issues and sampling methodologies, upgrades for analytical equipment, analytical method development, preparation of unexposed samples, analyses of tank headspaces samples, preparation of data reports, and operation of the tank vapor database. Progress made in FY 1996 included completion and issuance of 50 analytical data reports. A sampling system comparison study was initiated and completed during the fiscal year. The comparison study involved the vapor sampling system (VSS), a truck-based system, and the in situ vapor sampling system (ISVS), a cart-based system. Samples collected during the study were characterized for inorganic, permanent gases, total non-methane organic compounds and organic speciation by SUMMA{trademark} and TST methods. The study showed comparable sampling results between the systems resulting in the program switching from the VSS to the less expensive ISVS methodology in late May 1996. A temporal study was initiated in January 1996 in order to understand the influences seasonal temperatures changes have on the vapors in the headspace of Hanford waste tanks. A holding time study was initiated in the fourth quarter of FY 1996. Samples were collected from tank S-102 and rushed to the laboratory for time zero analysis. Additional samples will be analyzed at 1, 2, 4, 8, 16, and 32 weeks.

Silvers, K.L.; Fruchter, J.S.; Huckaby, J.L.; Almeida, T.L.; Evans, J.C. Jr.; Pool, K.H.; Simonen, C.A.; Thornton, B.M.

1997-01-01T23:59:59.000Z

418

Lightweight Metal Hydrides for Hydrogen Storage - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Ji-Cheng Zhao (Primary Contact), Xuenian Chen, Sheldon G. Shore The Ohio State University, Department of Materials Science and Engineering, 286 Watts Hall, 2041 College Road Columbus, OH 43210 Phone: (614) 292-9462 Email: zhao.199@osu.edu DOE Managers HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FC3605GO15062 Project Start Date: January 1, 2005 Project End Date: August 31, 2011 (No-cost extension to December 31, 2012) Fiscal Year (FY) 2012 Objectives Develop a high-capacity lightweight hydride for * reversible vehicular hydrogen storage, capable of meeting or exceeding the 2010 DOE FreedomCAR

419

A unified view of coherent and incoherent dihydrogen exchange in transition metal hydrides by nuclear resonance and inelastic neutron scattering  

SciTech Connect

In this paper a unified view of coherent and incoherent dihydrogen exchange in transition metal hydrides by nuclear magnetic resonance (NMR) and inelastic neutron scattering (INS) is presented. It is shown that both exchange processes coexist i.e. do not transform into each other although they may dominate the spectra in different temperature ranges. This superposition is the consequence of the incorporation of the tunnel frequency J of the coherent process into the nuclear two-spin hamiltonian of hydrogen pairs which allows to treat the problem using the well known density matrix theory of NMR line-shapes developed by Alexander and Binsch. It is shown that this theory can also be used to predict the line-shapes of the rotational tunneling transitions observed in the INS spectra of transition metal dihydrogen complexes and that both NMR and INS spectra depend on similar parameters.

Limbach, H.H.; Ulrich, S.; Buntkowsky, G. [Freie Univ. Berlin (Germany). Inst. fuer Organische Chemie; Sabo-Etienne, S.; Chaudret, B. [Toulouse-3 Univ., 31 (France). Lab. de Chimie de Coordination du C.N.R.S.; Kubas, G.J.; Eckert, J. [Los Alamos National Lab., NM (United States)

1995-08-12T23:59:59.000Z

420

Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density  

SciTech Connect

Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?°C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

2014-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Numerical Simulation of Hydrodynamics of a Heavy Liquid Drop Covered by Vapor Film in a Water Pool  

SciTech Connect

A numerical study on the hydrodynamics of a droplet covered by vapor film in water pool is carried out. Two level set functions are used as to implicitly capture the interfaces among three immiscible fluids (melt-drop, vapor and coolant). This approach leaves only one set of conservation equations for the three phases. A high-order Navier-Stokes solver, called Cubic-Interpolated Pseudo-Particle (CIP) algorithm, is employed in combination with level set approach, which allows large density ratios (up to 1000), surface tension and jump in viscosity. By this calculation, the hydrodynamic behavior of a melt droplet falling into a volatile coolant is simulated, which is of great significance to reveal the mechanism of steam explosion during a hypothetical severe reactor accident. (authors)

Ma, W.M.; Yang, Z.L.; Giri, A.; Sehgal, B.R. [Royal Institute of Technology (KTH), Drottning Kristinas vaeg 33 A, 100 44, Stockholm (Sweden)

2002-07-01T23:59:59.000Z

422

Vapor etching of nuclear tracks in dielectric materials  

DOE Patents (OSTI)

A process involving vapor etching of nuclear tracks in dielectric materials for creating high aspect ratio (i.e., length much greater than diameter), isolated cylindrical holes in dielectric materials that have been exposed to high-energy atomic particles. The process includes cleaning the surface of the tracked material and exposing the cleaned surface to a vapor of a suitable etchant. Independent control of the temperatures of the vapor and the tracked materials provide the means to vary separately the etch rates for the latent track region and the non-tracked material. As a rule, the tracked regions etch at a greater rate than the non-tracked regions. In addition, the vapor-etched holes can be enlarged and smoothed by subsequent dipping in a liquid etchant. The 20-1000 nm diameter holes resulting from the vapor etching process can be useful as molds for electroplating nanometer-sized filaments, etching gate cavities for deposition of nano-cones, developing high-aspect ratio holes in trackable resists, and as filters for a variety of molecular-sized particles in virtually any liquid or gas by selecting the dielectric material that is compatible with the liquid or gas of interest.

Musket, Ronald G. (Danville, CA); Porter, John D. (Berkeley, CA); Yoshiyama, James M. (Fremont, CA); Contolini, Robert J. (Lake Oswego, OR)

2000-01-01T23:59:59.000Z

423

Used Fuel Disposition Campaign Phase I Ring Compression Testing of High  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Phase I Ring Compression Testing of Phase I Ring Compression Testing of High Burnup Cladding Used Fuel Disposition Campaign Phase I Ring Compression Testing of High Burnup Cladding The purpose of ring compression testing is to generate data to support the development of the technical basis for extended storage and transportation of high-burnup fuel. This report highlights the results of completed Phase I testing of high-burnup M5® cladding and the revised three-year test plan. The goal of the ring compression testing is to identify process conditions that would minimize radial-hydride formation and the corresponding DBTT of high-burnup fuel cladding and to generate data and models to support the development of the technical basis for extended storage and transportation of high-burnup fuel.

424

Phase studies of the Zr-H system at high hydrogen concentrations  

Science Journals Connector (OSTI)

The phase boundaries of the Zr-H system have been defined at high hydrogen concentrations, on the basis of studies performed on zirconium hydrides containing 4 at % uranium. The methods used include hightemperature X-ray diffraction, electrical resistance, dilatometry, and, to a limited extent, hot stage microscopy. The (?+?) two-phase region was found to exist between ZrH1.64 and ZrHi1.74 at 24 °C. This region diminishes in width with increasing temperature and closes at 455 °C and ZrH1.70. From this point, a single boundary, sloping toward higher hydrogen concentrations, separates the ? and ? single-phase regions. Precise lattice parameter measurements indicate that first-order transitions occur at the boundaries of the two-phase region. Theoretical considerations suggest that the ? ? ? transition is second order.

K.E. Moore; W.A. Young

1968-01-01T23:59:59.000Z

425

phase coherence  

Science Journals Connector (OSTI)

The state in which two signals, such as electronic or optical signals, maintain (a) a fixed phase relationship with each other or (b) a fixed phase relationship with a third signal that can serve as a referenc...

2001-01-01T23:59:59.000Z

426

Validation of TES Temperature and Water Vapor Retrievals with ARM  

NLE Websites -- All DOE Office Websites (Extended Search)

Validation of TES Temperature and Water Vapor Retrievals with ARM Validation of TES Temperature and Water Vapor Retrievals with ARM Observations Cady-Pereira, Karen Atmospheric and Environmental Research, Inc. Shephard, Mark Atmospheric and Environmental Research, Inc. Clough, Shepard Atmospheric and Environmental Research Mlawer, Eli Atmospheric & Environmental Research, Inc. Turner, David University of Wisconsin-Madison Category: Atmospheric State and Surface The primary objective of the TES (Tropospheric Emission Spectrometer) instrument on the Aura spacecraft is the retrieval of trace gases, especially water vapor and ozone. The TES retrievals extremely useful for global monitoring of the atmospheric state, but they must be validated. The ARM sites are well instrumented and provide continuous measurements, which

427

VAPORIZATION OF TUNGSTEN-METAL IN STEAM AT HIGH TEMPERATURES.  

SciTech Connect

The vaporization of tungsten from the APT spallation target dominates the radiological source term for unmitigated target overheating accidents. Chemical reactions of tungsten with steam which persist to tungsten temperatures as low as 800 C result in the formation of a hydrated tungsten-oxide which has a high vapor pressure and is readily convected in a flowing atmosphere. This low-temperature vaporization reaction essentially removes the oxide film that forms on the tungsten-metal surface as soon as it forms, leaving behind a fresh metallic surface for continued oxidation and vaporization. Experiments were conducted to measure the oxidative vaporization rates of tungsten in steam as part of the effort to quantify the MT radiological source term for severe target accidents. Tests were conducted with tungsten rods (1/8 inch diameter, six inches long) heated to temperatures from approximately 700 C to 1350 C in flowing steam which was superheated to 140 C. A total of 19 experiments was conducted. Fifteen tests were conducted by RF induction heating of single tungsten rods held vertical in a quartz glass retort. Four tests were conducted in a vertically-mounted tube furnace for the low temperature range of the test series. The aerosol which was generated and transported downstream from the tungsten rods was collected by passing the discharged steam through a condenser. This procedure insured total collection of the steam along with the aerosol from the vaporization of the rods. The results of these experiments revealed a threshold temperature for tungsten vaporization in steam. For the two tests at the lowest temperatures which were tested, approximately 700 C, the tungsten rods were observed to oxidize without vaporization. The remainder of the tests was conducted over the temperature range of 800 C to 1350 C. In these tests, the rods were found to have lost weight due to vaporization of the tungsten and the missing weight was collected in the downstream condensate system. The aerosol formed a fine white smoke of tungsten-oxide which was visible to the eye as it condensed in the laminar boundary layer of steam which flowed along the surface of the rod. The aerosol continued to flow as a smoke tube downstream of the rod, flowing coaxially along the centerline axis of the quartz glass tube and depositing by impaction along the outside of a bend and at sudden area contractions in the piping. The vaporization rate data from the 17 experiments which exceeded the vaporization threshold temperature are shown in Figure 5 in the form of vaporization rates (g/cm{sup 2} s) vs. inverse temperature (K{sup {minus}1}). Two correlations to the present data are presented and compared to a published correlation by Kilpatrick and Lott. The differences are discussed.

GREENE,G.A.; FINFROCK,C.C.

2000-10-01T23:59:59.000Z

428

Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE  

NLE Websites -- All DOE Office Websites (Extended Search)

Executive Summaries Executive Summaries for the Hydrogen Storage Materials Centers of Excellence Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Period of Performance: 2005-2010 Fuel Cell Technologies Program Office of Energy Efficiency and Renewable Energy U. S. Department of Energy April 2012 2 3 Primary Authors: Chemical Hydrogen Storage (CHSCoE): Kevin Ott, Los Alamos National Laboratory Hydrogen Sorption (HSCoE): Lin Simpson, National Renewable Energy Laboratory Metal Hydride (MHCoE): Lennie Klebanoff, Sandia National Laboratory Contributors include members of the three Materials Centers of Excellence and the Department of Energy Hydrogen Storage Team in the Office of Energy Efficiency and Renewable Energy's Fuel Cell Technologies Program.

429

Synthesis of poly(vinyl alcohol)-graft-poly(-caprolactone) and poly(vinyl alcohol)-graft-poly(lactide) in melt with magnesium hydride as catalyst  

E-Print Network (OSTI)

)-graft-poly(lactide) in melt with magnesium hydride as catalyst Nadia Guerrouani, André Mas* , François Schué UMR 5253 CNRS-UM2%) was investigated using MgH2 environmental catalyst and melt-grown ring opening polymerization (ROP) of -caprolactone (CL) and L- lactide (LA), that avoiding undesirable toxic catalyst and solvent. The ability of Mg

Paris-Sud XI, Université de

430

Selective deposition of silicon and silicon-germanium alloys by rapid thermal chemical vapor deposition  

SciTech Connect

Selective deposition of SiGe alloys by rapid thermal deposition has been studied using a commercially available Rapid Thermal Chemical Vapor Deposition (RTCVD) cluster tool. The precursors used in this work were dichlorosilane and germane diluted in either hydrogen or argon. An initial characterization was performed to find the appropriate temperature and GeH{sub 4} flow ranges to deposit epitaxial layers with low surface roughness. For layers with higher germanium concentration lower deposition temperatures are required to minimize surface roughness. The effects of the dilutant gas on the deposition were examined. An H{sub 2} dilutant affects the deposition by consuming chlorine released by the SiCl{sub 2}H{sub 2} and forming HCl. When Ar is used as the dilutant, more chlorine is available for other reactions that can result in etching of the silicon surface. Finally, the effects of pre-deposition treatment were determined. When compared to a wet HF dip, a gas/vapor phase HF/methanol native oxide removal treatment appears to increase the initiation time for the epitaxial deposition reaction. This is most likely due to increased fluorine termination of the surface. When a wet HF or HF/methanol native oxide removal is followed by a UV-Cl{sub 2} process, the deposition reaction initiation time is reduced. The UV-Cl{sub 2} process was also found to etch silicon through the native oxide.

Grant, J.M.; Ang, M.; Allen, L.R. [Sharp Microelectronics Technology, Inc., Camas, WA (United States)

1996-12-01T23:59:59.000Z

431

Flavin Amine Oxidases from the Monoamine Oxidase Structural Family Utilize a Hydride Transfer Mechanism  

E-Print Network (OSTI)

-acetylspermine, stopped-flow traces were fit to equation 2.4, which describes a triphasic exponential decay, where k1, k2, and k3 are first order rate constants, A1, A2, A3 correspond to the absorbance changes in each phase, and A? is the final absorbance...

Henderson Pozzi, Michelle

2011-08-08T23:59:59.000Z

432

Phase equilibrium data for development of correlations for coal fluids  

SciTech Connect

The overall objective of the authors' work is to develop accurate predictive methods for representations of vapor-liquid equilibria in systems encountered in coal-conversion processes. The objectives pursued in the present project include: (1) Measurements of binary vapor-liquid phase behavior data for selected solute gases (e.g., C{sub 2}H{sub 6}, CH{sub 4}) in a series of paraffinic, naphthenic, and aromatic hydrocarbon solvents to permit evaluations of interaction parameters in models for phase behavior. Solubilities of the gases in the liquid phase have been determined. (2) Evaluation of existing equations of state and other models for representations of phase behavior in systems of the type studied experimentally; development of new correlation frameworks as needed. (3) Generalization of the interaction parameters for the solutes studied to a wide spectrum of heavy solvents; presentation of final results in formats useful in the design/optimization of coal liquefaction processes.

Robinson, R.L. Jr.; Gasem, K.A.M.; Darwish, N.A.; Raff, A.M.

1991-02-01T23:59:59.000Z

433

PHASE BEHAVIOR OF LIGHT GASES IN HYDROCARBON AND AQUEOUS SOLVENTS  

SciTech Connect

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present period, the Park-Gasem-Robinson (PGR) equation of state (EOS) has been modified to improve its volumetric and equilibrium predictions. Specifically, the attractive term of the PGR equation was modified to enhance the flexibility of the model, and a new expression was developed for the temperature dependence of the attractive term in this segment-segment interaction model. The predictive capability of the modified PGR EOS for vapor pressure, and saturated liquid and vapor densities was evaluated for selected normal paraffins, normal alkenes, cyclo-paraffins, light aromatics, argon, carbon dioxide and water. The generalized EOS constants and substance-specific characteristic parameters in the modified PGR EOS were obtained from the pure component vapor pressures, and saturated liquid and vapor molar volumes. The calculated phase properties were compared to those of the Peng-Robinson (PR), the simplified-perturbed-hard-chain theory (SPHCT) and the original PGR equations. Generally, the performance of the proposed EOS was better than the PR, SPHCT and original PGR equations in predicting the pure fluid properties (%AAD of 1.3, 2.8 and 3.7 for vapor pressure, saturated liquid and vapor densities, respectively).

KHALED A.M. GASEM; ROBERT L. ROBINSON, JR.

1998-08-31T23:59:59.000Z

434

The development of a passive dosimeter for airborne aniline vapors  

E-Print Network (OSTI)

passive sampl1ng dosimeter was designed to measure concen- trat1ons of aniline vapor in air. Diffus1on tubes of 1. 5, 3. 0 and 4. 5 cm lengths were tested under controlled conditions of relative humid1ty, air temperature and vapor concentrations. A... of Measured vs Calculated Concentrations APPENDIX D-Student-t Test on Slopes of Measured vs Calculated Data . APPENDIX E-Statistical Analysis of Four Hour Time- Weighted Average Study on 3. 0 cm Dosimeter VITA ~pa e 42 45 48 59 62 63 65 70 73...

Campbell, James Evan

1977-01-01T23:59:59.000Z

435

Solid–Liquid–Vapor Equilibrium Models for Cryogenic Biogas Upgrading  

Science Journals Connector (OSTI)

In cryogenic upgrading processes involving dry ice formation, accurate predictions of solid–liquid, solid–vapor, and solid–liquid–vapor equilibria are fundamental for a correct design of the heat exchanger surface in order to achieve the desired biomethane purity. ... Moreover, the liquefied biogas production process, particularly interesting for cryogenic upgrading processes due to the low temperature of the obtained biomethane, requires an accurate knowledge of carbon dioxide solubility in liquid methane to avoid solid deposition. ... For some applications demanding a high energy content gas, namely vehicle fuels and injection in the natural gas grid, the biogas has to be upgraded into biomethane. ...

Mauro Riva; Marco Campestrini; Joseph Toubassy; Denis Clodic; Paolo Stringari

2014-10-13T23:59:59.000Z

436

Phase transformations in neutron-irradiated Zircaloys  

SciTech Connect

Microstructural evolution in Zircaloy-2 and -4 spent-fuel cladding specimens after approx.3 years of irradiation in commercial power reactors has been investigated by TEM and HVEM. Two kinds of precipitates induced by the fast-neutron irradiation in the reactors have been identified, i.e., Zr/sub 3/O and cubic-ZrO/sub 2/ particles approximately 2 to 10 nm in size. By means of a weak-beam dark-field ''2-1/2D-microscopy'' technique, the bulk nature of the precipitates and the surficial nature of artifact oxide and hydride phases could be discerned. The Zr(Fe/sub x/,Cr/sub 1-x/)/sub 2/ and Zr/sub 2/(Fe/sub x/,Ni/sub 1-x/) intermetallic precipitates normally present in the as-fabricated material virtually dissolved in the spent-fuel cladding specimens after a fast-neutron fluence of approx.4 x 10/sup 21/ ncm/sup -2/ in the power reactors. The observed radiation-induced phase transformations are compared with predictions based on the currently available understanding of the alloy characteristics. 29 refs.

Chung, H.M.

1986-04-01T23:59:59.000Z

437

Disilane: A new silicon doping source in metalorganic chemical vapor deposition of GaAs  

Science Journals Connector (OSTI)

Disilane (Si2H6) is presented as a new silicon doping source in the metalorganic chemical vapor deposition of GaAs together with comparison results obtained using the conventional silane (SiH4) doping source. The dopingcharacteristics of disilane were studied over a wide range of growth conditions: temperature gas phase stoichiometry and disilane concentration in the growth ambient. Silicon incorporation by means of disilane pyrolysis showed no temperature dependence in sharp contrast to the strong temperature activated dependence found when employing silane. The decomposition reaction of disilane proved to be very efficient reducing the amount of dopant gas required by about two orders of magnitude at the lower growth temperatures. Electrical measurements on disilane?doped GaAs yield the same high mobilities as obtained in silane?doped GaAs films indicative of low compensation.

T. F. Kuech; B. S. Meyerson; E. Veuhoff

1984-01-01T23:59:59.000Z

438

A QSPR Study of the Solubility of Gases and Vapors in Water  

Science Journals Connector (OSTI)

QSPR correlation equations were developed for the prediction of the solubilities of organic gases and vapors in water. ... The Ostwald solubility coefficient (L) is defined as the ratio of the equilibrium concentrations of a gaseous compound in the liquid and in the gas phase (eq 1), where a superscript w (Lw) usually denotes water as a solvent. ... Table 2) are as follows:? the energy gap between HOMO and LUMO (EHOMO ? ELUMO), the numbers of nitrogen atoms and of oxygen atoms in the molecule, and the most negative partial charge weighted topological electronic index43a (PCWTE) defined by eq 7, where qi and qj are the Zefirov partial charges43b of the bonded atoms, rij is the respective bond lengths, and Qmin is the most negative partial charge. ...

Alan R. Katritzky; Lan Mu; Mati Karelson

1996-11-21T23:59:59.000Z

439

Unsaturated drip tests on sludge based SRL glass : the effects of prior vapor hydration.  

SciTech Connect

The behavior of a sludge-based Savannah River Laboratory (SRL) waste glasses exposed to as much as 7 years of unsaturated test conditions is reported. This test series included both as-cast glass and glass that had been pre-altered by exposure to 200 C water vapor. Actinides (except neptunium) are retained in alteration products and released primarily as solution-borne colloids and particulate when fresh glass is reacted. Pre-altered glass, however, rapidly releases most elements (including actinides) in a nearly congruent manner when first exposed to dripping water. Normalized boron release from the aged glass is more rapid than that of any other element by an order of magnitude. The response of pre-altered glass, as determined by cumulative boron release, follows a power-law behavior with time, corresponding roughly to t{sup 1/4}. This is consistent with a diffusion transport through clay alteration phases on the glass surface.

Fortner, J. A.

1998-12-18T23:59:59.000Z

440

UNCORRECTEDPROOF 2 Vaporization, fusion and sublimation enthalpies of the  

E-Print Network (OSTI)

UNCORRECTEDPROOF 2 Vaporization, fusion and sublimation enthalpies of the 3 dicarboxylic acids from of Chemistry and Biochemistry, University of Missouri-St. Louis, 8001 Natural Bridge, St. Louis, MO 63121, USA observed previously in the sublimation enthalpies of these compounds. The results are dis- 16 cussed

Chickos, James S.

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Vapor-side corrosion in thermal desalination plants  

SciTech Connect

This article reports the results of vapor-size corrosion monitoring studies carried out in multistage flash (MSF) desal unit No. 100 of Al-Khafji power and Desalination Plant in Saudi Arabia. Corrosion behavior of 70/30 Cu-Ni alloy, carbon steel (CS), and type 316L stainless steel (SS) was studied in vents and in the vapor size of distillers for 2,000, 4,000, and 9,000 h. Analyses of the experimental data indicated that in addition to O{sub 2}, S-containing compounds evolved during flashing of seawater reacted more with Cu-Ni alloy than with CS and type 316L SS. Explanations for comparatively higher corrosion of alloys exposed to the vapors of the first three (1 to 3) and middle (11 to 13) stages of the MSF plant are given with experimental results. Type 316L SS was found to be the alloy most resistant to vapor-side corrosion in all stages of distillers.

Asrar, N.; Malik, A.U.; Ahmed, S. [Saline Water Conversion Corp. (Saudi Arabia); Al-Khalidi, M.; Al-Moaili, K. [Al-Khafji Desalination Plant (Saudi Arabia)

1999-04-01T23:59:59.000Z

442

Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement  

E-Print Network (OSTI)

This dissertation has two key objectives: the first objective is to develop a method of predicting and quantifying the amount of water that can enter into a pavement system by vapor transport; the second objective is to identify to which extent...

Tong, Yunwei

2013-11-08T23:59:59.000Z

443

The chemical vapor deposition of zirconium carbide onto ceramic substrates  

SciTech Connect

Zirconium carbide is an attractive ceramic material due to its unique properties such as high melting point, good thermal conductivity, and chemical resistance. The controlled preparation of zirconium carbide films of superstoichiometric, stoichiometric, and substoichiometric compositions has been achieved utilizing zirconium tetrachloride and methane precursor gases in an atmospheric pressure high temperature chemical vapor deposition system.

Glass, John A, Jr.; Palmisiano, Nick, Jr.; Welsh, R. Edward

1999-07-01T23:59:59.000Z

444

A transient model for a cesium vapor thermionic converter. [Cs  

SciTech Connect

This paper presents an analytical model for simulating the transient and steady-state operation of cesium vapor thermionic converters. A parametric analysis is performed to assess the transient response of the converter to changes in fission power and width of interelectrode gap. The model optimizes the converter performance for maximum electric power to the load.(AIP)

El-Genk, M.S.; Murray, C.S.; Chaudhuri, S. (Institute for Space Nuclear Power Studies, Department of Chemical and Nuclear Engineering, The University of New Mexico, Albuquerque, New Mexico (USA))

1991-01-10T23:59:59.000Z

445

Experimental Study of Water Vapor Adsorption on Geothermal  

E-Print Network (OSTI)

Geothermal Program under Department of Energy Grant No. DE-FG07-90IDI2934,and by the Department of PetroleumSGP-TR-148 Experimental Study of Water Vapor Adsorption on Geothermal Reservoir Rocks Shubo Shang Engineering, Stanford University Stanford Geothermal Program Interdisciplinary Research in Engineering

Stanford University

446

CVD CNT CNT (Vapor-grown carbon fiber, VGCF)  

E-Print Network (OSTI)

CNT CNT CVD CNT CNT (Vapor-grown carbon fiber, VGCF) 10001300 CNT CVD Smalley CO 24 CCVD 1 #12; 27 mm 3% 200 sccm 800 10 10 Torr 300 sccm Ethanol tank Hot bath boat Ar/H2 Ar or Ethanol tank Hot bath Ethanol tank Hot bath Pressure gauge Maindraintube Subdraintube

Maruyama, Shigeo

447

Method for removing metal vapor from gas streams  

DOE Patents (OSTI)

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

Ahluwalia, R. K. (6440 Hillcrest Dr., Burr Ridge, IL 60521); Im, K. H. (925 Lehigh Cir., Naperville, IL 60565)

1996-01-01T23:59:59.000Z

448

Sorption and Diffusion of Organic Vapors in Two Fluoroelastomers  

E-Print Network (OSTI)

Sorption and Diffusion of Organic Vapors in Two Fluoroelastomers PING WANG,* NATHANIEL S. SCHNEIDER of II in polar liquids: over 100% (wt/wt) in two ketones and a phosphate ester. Sorption isotherms deter determined from sorption kinetics, corrected for nonisothermal effects, and converted to solvent self

Wang, Ping

449

High-resolution terahertz atmospheric water vapor continuum measurements  

E-Print Network (OSTI)

High-resolution terahertz atmospheric water vapor continuum measurements David M. Slocum,* Thomas M such as pollution monitoring and the detection of energetic chemicals using remote sensing over long path lengths through the atmosphere. Although there has been much attention to atmospheric effects over narrow

Massachusetts at Lowell, University of

450

Method and apparatus to measure vapor pressure in a flow system  

DOE Patents (OSTI)

The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process.

Grossman, Mark W. (Belmont, MA); Biblarz, Oscar (Swampscott, MA)

1991-01-01T23:59:59.000Z

451

Tropical Water Vapor and Cloud Feedbacks in Climate Models: A Further Assessment Using Coupled Simulations  

Science Journals Connector (OSTI)

By comparing the response of clouds and water vapor to ENSO forcing in nature with that in Atmospheric Model Intercomparison Project (AMIP) simulations by some leading climate models, an earlier evaluation of tropical cloud and water vapor ...

De-Zheng Sun; Yongqiang Yu; Tao Zhang

2009-03-01T23:59:59.000Z

452

Metalorganic chemical vapor deposition of carbon-free ZnO using...  

NLE Websites -- All DOE Office Websites (Extended Search)

Metalorganic chemical vapor deposition of carbon-free ZnO using the bis(2,2,6,6-tetramethyl-3,5-heptanedionato)zinc precursor. Metalorganic chemical vapor deposition of carbon-free...

453

Economic and Technical Tradeoffs Between Open and Closed Cycle Vapor Compression Evaporators  

E-Print Network (OSTI)

and solute. Evaporation tends to be a very energy intensive process. Approximately 1000 BTUs of energy are required to vaporize one pound of water. Many techniques have been developed to reuse energy Within an evaporation system so as to vaporize... Recompression A schematic of an open cycle vapor recompression evaporator is shown in Figure 2. This method uses the vapor in an open cycle for both heating and cooling. Rather than being condensed after the last effect, steam is compressed to a slightly...

Timm, M. L.

454

Pressure dependence of phonons and excitons in InSe films prepared by metal-organic chemical vapor deposition  

Science Journals Connector (OSTI)

The pressure dependence of the Raman spectra of phase-pure InSe thin films prepared by the low-pressure metal-organic chemical vapor deposition technique has been studied using a diamond-anvil high-pressure cell. Enhancement in the intensities of the Raman modes has been observed as a result of pressure-induced “tuning” of the energy of the M1-type hyperbolic exciton in InSe at ?2.54 eV through discrete incident laser photon energies. The pressure coefficients of the phonon modes and of the hyperbolic exciton in InSe have been determined.

In-Hwan Choi and Peter Y. Yu

2003-10-27T23:59:59.000Z

455

Determination of vaporization efficiencies and overall mass transfer coefficients from a packed absorber at steady state operation  

E-Print Network (OSTI)

typical tower used in gas absorption is shown in Figure l. A gas mixture, referred to as the rich gas is introduced at the bottom of the tower and is contacted counter-currently with the lean oil introduced at the top of the tower. The gas leaving... the towe" is called the lean gas and the liquid leaving the tower is called rich oil. The heavier components in the rich gas are absorbed in part by the lean oil. The driving force for the mass transfer of a component from the vapor phase to the liquid...

McDaniel, Ronald

2012-06-07T23:59:59.000Z

456

Metamorphosis: Phases of UF{sub 6}  

SciTech Connect

A 15-minute videotape is presented. The subject matter is 150 grams of UF{sub 6} sealed in a glass tube. Close-up views show the UF{sub 6} as phase changes are effected by the addition or removal of heat from the closed system. The solid-to-liquid transition is shown as heat is added, both slowly and rapidly. The solid phases which result from freezing and from desublimation are contrasted. In the solid state, uranium hexafluoride is a nearly-white, dense crystalline solid. The appearance of this solid depends on whether it is formed by freezing from the liquid or by desublimation from the vapor phase. If frozen from the liquid, the solid particles take the form of irregularly shaped coarse grains, while the solid product of desublimation tends to be a rather formless mass without individually distinguishable particles. The changes in state are presented in terms of the UF{sub 6} phase diagram.

Dyer, R.H. [Department of Energy, Oak Ridge, TN (United States)

1991-12-31T23:59:59.000Z

457

CHARACTERIZATION OF THE LOCAL TITANIUM ENVIRONMENT IN DOPED SODIUM ALUMINUM HYDRIDE USING X-RAY ADSORPTION SPECTROSCOPY.  

SciTech Connect

Ti K-edge x-ray absorption spectroscopy was used to explore the local titanium environment and valence in 2-4 mol% Ti-doped sodium alanate. An estimate of the oxidation state of the dopant, based upon known standards, revealed a zero-valent titanium atom. An analysis of the near-edge and extended fine structures indicates that the Ti does not enter substitutional or interstitial sites in the NaAlH{sub 4} lattice. Rather, the Ti is located on/near the surface and is coordinated by 10.2 {+-} 1 aluminum atoms with an interatomic distance of 2.82 {+-} 0.01 {angstrom}, similar to that of TiAl{sub 3}. The Fourier transformed EXAFS spectra reveals a lack of long-range order around the Ti dopant indicating that the Ti forms nano-clusters of TiAl{sub 3}. The similarity of the spectra in the hydrided and dehydrided samples suggests that the local Ti environment is nearly invariant during hydrogen cycling.

GRAETZ, J.; IGNATOV, A. YU; TYSON, T.A.; REILLY, J.J.; JOHNSON, J.

2004-11-30T23:59:59.000Z

458

Quantitative Analysis of Ternary Vapor Mixtures Using a Microcantilever-Based Electronic Nose  

SciTech Connect

The authors report the identification and quantification of the components of a ternary vapor mixture using a microcantilever-based electronic nose. An artificial neural network was used for pattern recognition. Dimethyl methyl phosphonate vapor in ppb concentrations and water and ethanol vapors in ppm concentrations were quantitatively identified either individually or in binary and ternary mixtures at varying concentrations.

Pinnaduwage, Lal A [ORNL; Zhao, Weichang [ORNL; Gehl, Anthony C [ORNL; Allman, Steve L [ORNL

2007-01-01T23:59:59.000Z

459

Sample Vapor Introduction Techniques for Use with Cryofocusing GC Inlet Systems  

Science Journals Connector (OSTI)

......the vapor generator was operated at atmospheric pressure for...condensed water. Other studies...Because the water vapor was...tail of the water peak. Thus...obtained from an atmospheric pressure source...the vapor generator over a 1......

Christine L. Rankin; Richard D. Sacks

1994-01-01T23:59:59.000Z

460

Characterization of the {beta}-phase of the palladium-hydrogen equation of state  

SciTech Connect

The {beta}-phase of the P-C-T curves of the palladium-hydrogen system is encountered at high pressures of gaseous hydrogen and low temperatures of this system. The {beta}-phase is characterized by an increase in the concentration of hydrogen in the palladium lattice with an increase in pressure of the free hydrogen gas surrounding the palladium. The P-C-T curves in this study are determined by gravimetric measurements of the hydrided palladium sample to determine the amount of hydrogen within the palladium lattice. The amount of hydrogen is kept constant within the experimental system and the temperature is varied which changes the pressures. The objective of this experimental thesis is to accurately determine the P-C-T curves of palladium in the {beta}-phase region to pressures of 20,000 psia and medium to low temperature region of {minus}60 C to 100 C.

Fisher, K.J.

1998-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Rapid Research Note Raman Scattering in Resonance  

E-Print Network (OSTI)

-uniformity in the ternary alloy InGaN [4, 5]. However, resonance Raman scattering at bound excitons as reported for CdS doped 220 mm thick GaN film grown by hydride vapor phase epitaxy. Sapphire (0001) with a sputtered Zn

Nabben, Reinhard

462

physica status solidi 1 Rapid Research Note To be published in: phys. stat. sol. (b) 223, No. 3 (2001)  

E-Print Network (OSTI)

-uniformity in the ternary alloy InGaN [4, 5]. However, resonance Raman scattering at bound excitons as reported for CdS doped 220 µm thick GaN film grown by hydride vapor phase epitaxy. Sapphire (0001) with a sputtered Zn

Nabben, Reinhard

463

A TWO-DIMENSIONAL, FINITE-DIFFERENCE MODEL OF THE PHASE DISTRIBUTION AND VAPOR  

E-Print Network (OSTI)

Size Determination .................................................................. 31 Mass Balance Calculation ......................................................................... 33 Data Requirements

464

Bundles of carbon nanotubes generated by vapor-phase growth Maohui Ge and Klaus Sattler  

E-Print Network (OSTI)

Z.t They were initially found at the end of an electrode in the arc discharge method and were later produced, thinning and opening of the tubes by oxidation was observed.4v5In the arc discharge method the generation of the tubes might be initiated by the substrate and proceed due to the electric field between the two elec

Sattler, Klaus

465

A Gas Lift Bioreactor for Removal of Contaminants from the Vapor Phase  

Science Journals Connector (OSTI)

...conditions, and the reactor was again allowed...of samplings and analysis took place. The...while maintaining reliability of the degradative...was fed into the reactor inlet at different...phenol found in the reactor contents unless...be detected by GC analysis under the conditions...

B. D. Ensley; P. R. Kurisko

1994-01-01T23:59:59.000Z

466

High Rates of Oxygen Reduction over a Vapor Phase–Polymerized PEDOT Electrode  

Science Journals Connector (OSTI)

...electrode. Recently, the development of chemical polymerization...application of the PEDOT electrocatalyst concept would require...from the anode to the cathode is a major issue in...2 reduction on the cathode side (9). In...31). Thus, the development of the gas-ICP-electrolyte...

Bjorn Winther-Jensen; Orawan Winther-Jensen; Maria Forsyth; Douglas R. MacFarlane

2008-08-01T23:59:59.000Z

467

Controlled Vapor Phase Growth of Single Crystalline, Two-Dimensional GaSe  

E-Print Network (OSTI)

, and have the potential to enable next-generation electronic and optoelectronic devices. However, controlled-generation electronic and optoelectronic devices such as photodetectors and field-effect transistors. T wo-generation electronic and optoelectronic devices. Although most research has focused on 2D transition metal

Geohegan, David B.

468

THz Quantum Cascade Lasers Grown by Low-Pressure Metalorganic Vapor Phase Epitaxy  

Science Journals Connector (OSTI)

A terahertz quantum cascade laser (QCL) has been successfully grown by low-pressure MOVPE. Very high quality semiconductor interfaces are demonstrated as well as very promising lasing...

Sirigu, Lorenzo; Rudra, Alok; Amanti, Maria I; Scalari, Giacomo; Fischer, Milan; Giovannini, Marcella; Faist, Jerome; Kapon, Eli

469

Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mokapu Penninsula Area (Thomas, 1986) Mokapu Penninsula Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Mokapu Penninsula Area (Thomas, 1986) Exploration Activity Details Location Mokapu Penninsula Area Exploration Technique Mercury Vapor Activity Date Usefulness not useful DOE-funding Unknown Notes The high degree of cultural activity (e.g. residential areas, streets, jet runways, etc.) on Mokapu both limited the extent of the soil geochemical surveys performed and rendered their interpretation much more difficult. Soil mercury concentrations and radon emanometry data on the peninsula showed a few localized high values (Figs 13, 14), but no consistent correlation between the anomalous zones and geologic features could be

470

Detonation wave driven by condensation of supersaturated carbon vapor  

Science Journals Connector (OSTI)

An experimental observation of a detonation wave driven by the energy of condensation of supersaturated carbon vapor is reported. The carbon vapor was formed by the thermal decay of unstable carbon suboxide C3O2 behind shock waves in mixtures containing 10–30% C3O2 in Ar. In the mixture 10% C3O2+Ar the insufficient heat release resulted in a regime of overdriven detonation. In the mixture 20% C3O2+Ar measured values of the pressure and wave velocity coincident with calculated Chapman-Jouguet parameters were attained. In the richest mixture 30% C3O2+Ar an excess heat release caused the slowing down of the condensation rate and the regime of underdriven detonation was observed.

A. Emelianov; A. Eremin; V. Fortov; H. Jander; A. Makeich; H. Gg. Wagner

2009-03-10T23:59:59.000Z

471

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents (OSTI)

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

1989-01-01T23:59:59.000Z

472

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents (OSTI)

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Riley, B.; Szreders, B.E.

1988-04-26T23:59:59.000Z

473

Mechanism of compensation of the donor impurity in the near-surface layer of gap during heat treatment in phosphorus vapors  

SciTech Connect

The secondary ion mass spectrometry and capacitance-voltage measurements have been used to study the mechanism of formation of the near-surface layer with a low concentration of uncompensated donors in n-GaP grown by vapor-phase epitaxy and subjected to heat treatment at different pressures of phosphorus vapors. The dependence of the thickness of the mentioned layer on the pressure of phosphorus vapors has a minimum at a pressure of (1.5 {+-} 0.5) x 10{sup 3} Pa. It is shown that at vapor pressures above the mentioned value, the interstitial P, which forms a deep electron trap, is a suitable candidate for the role of compensating acceptor. At low pressures, the probable compensating center is the P vacancy giving rise to a deep level with the energy Ec-(0.21 {+-} 0.01) eV. At 700 deg. C, the effective diffusivity of interstitial P is {approx}(3 {+-} 1) s- 10{sup -15} cm{sup 2}/s, while that of the P vacancy is {approx}(3 {+-} 1) x 10{sup -14} cm{sup 2}/s.

Krutogolov, Yu. K., E-mail: krutogolov@mail.ru [Research Institute for Materials of Electronic Engineering (Russian Federation)

2010-06-15T23:59:59.000Z

474

Specific Mass Estimates for A Vapor Core Reactor With MHD  

SciTech Connect

This study investigated the development of a system concept for space power generation and nuclear electric propulsion based on a vapor core reactor (VCR) with magnetohydrodynamic (MHD) power conversion system, coupled to a magnetoplasma-dynamic (MPD) thruster. The VCR is a liquid-vapor core reactor concept operating with metallic uranium or uranium tetrafluoride (UF{sub 4}) vapor as the fissioning fuel and alkali metals or their fluorides as working fluid in a closed Rankine cycle with MHD energy conversion. Gaseous and liquid-vapor core reactors can potentially provide the highest reactor and cycle temperature among all existing or proposed fission reactor designs. This unique feature makes this reactor concept a very natural and attractive candidate for very high power (10 to 1000 MWe) and low specific mass (0.4 to 5 kg/kWe) nuclear electric propulsion (NEP) applications since the MHD output could be coupled with minimal power conditioning to MPD thrusters or other types of thruster for producing thrust at very high specific impulse (I{sub sp} 1500 to 10,000 s). The exceptional specific mass performance of an optimized VCRMHD- NEP system could lead to a dramatic reduction in the cost and duration of manned or robotic interplanetary as well as interstellar missions. The VCR-MHD-NEP system could enable very efficient Mars cargo transfers or short (<8 month) Mars round trips with less initial mass in low Earth orbit (IMLEO). The system could also enable highly efficient lunar cargo transfer and rapid missions to other destinations throughout the solar system. (authors)

Knight, Travis; Smith, Blair; Anghaie, Samim [Innovative Nuclear Space Power and Propulsion Institute (INSPI), PO Box 116502, University of Florida, Gainesville, FL 32611-6502 (United States)

2002-07-01T23:59:59.000Z

475

Heat Recovery in Distillation by Mechanical Vapor Recompression  

E-Print Network (OSTI)

be classified generally into two types,.aerodynamic and positive displacement (Figure 5). Among the various types of compressors, centrifugal, reciprocating, lobe and screw have been used for vapor recompression. I AXIAL AERODYNAMIC I I CENTRIFUGAL I... speeds of centri fugal compressors make them highly susceptible to erosion from entrained liquid droplets. This ero sion can reduce the efficiency and cause dynamic instability from rotor imbalance and mechanical failure. Next, it is important...

Becker, F. E.; Zakak, A. I.

476

High average power magnetic modulator for metal vapor lasers  

DOE Patents (OSTI)

A three-stage magnetic modulator utilizing magnetic pulse compression designed to provide a 60 kV pulse to a copper vapor laser at a 4.5 kHz repetition rate is disclosed. This modulator operates at 34 kW input power. The circuit includes a step up auto transformer and utilizes a rod and plate stack construction technique to achieve a high packing factor.

Ball, Don G. (Livermore, CA); Birx, Daniel L. (Oakley, CA); Cook, Edward G. (Livermore, CA); Miller, John L. (Livermore, CA)

1994-01-01T23:59:59.000Z

477

Methanol vaporization and injection system for internal combustion engine  

SciTech Connect

An engine equipped with an alcohol vaporization injection system operates as a four stroke cycle diesel engine that transfers the heat of exiting exhaust gases and cylinder head walls to the fuel. The engine runs on alcohol. The alcohol becomes vaporized and its pressure is high enough so that when a valve is opened between the high pressure fuel line and the combustion chamber (when it is at the peak of its compression ratio) enough alcohol will enter the combustion chamber to allow proper combustion. The overall advantages to this type of alcohol vaporization injection system is that it adds relatively few new mechanisms to the spark ignition four cycle internal combustion engine to enable it to operate as a diesel engine with a high thermal efficiency. This alcohol injection system exploits the engine's need for greater volumes of alcohol caused by the alcohol's relatively low heat of combustion (When compared to gasoline) by using this greater volume of fuel to return greater quantities of heat back to the engine to a much greater degree than other fuels can.

Bayley, R.I.

1980-05-06T23:59:59.000Z

478

Program plan for the resolution of tank vapor issues  

SciTech Connect

Since 1987, workers at the Hanford Site waste tank farms in Richland, Washington, have reported strong odors emanating from the large, underground high-level radioactive waste storage tanks. Some of these workers have complained of symptoms (e.g., headaches, nausea) related to the odors. In 1992, the U.S. Department of Energy, which manages the Hanford Site, and Westinghouse Hanford Company determined that the vapor emissions coming from the tanks had not been adequately characterized and represented a potential health risk to workers in the immediate vicinity of the tanks. At that time, workers in certain areas of the tank farms were required to use full-face, supplied-breathing-air masks to reduce their exposure to the fugitive emissions. While use of supplied breathing air reduced the health risks associated with the fugitive emissions, it introduced other health and safety risks (e.g., reduced field of vision, air-line tripping hazards, and heat stress). In 1992, an aggressive program was established to assure proper worker protection while reducing the use of supplied breathing air. This program focuses on characterization of vapors inside the tanks and industrial hygiene monitoring in the tank farms. If chemical filtration systems for mitigation of fugitive emissions are deemed necessary, the program will also oversee their design and installation. This document presents the plans for and approach to resolving the Hanford Site high-level waste tank vapor concerns. It is sponsored by the Department of Energy Office of Environmental Restoration and Waste Management.

Osborne, J.W.; Huckaby, J.L.

1994-05-01T23:59:59.000Z

479

Examining the Adsorption (Vapor?Liquid Equilibria) of Short-Chain Hydrocarbons in Low-Density Polyethylene with the SAFT-VR Approach  

Science Journals Connector (OSTI)

Examining the Adsorption (Vapor?Liquid Equilibria) of Short-Chain Hydrocarbons in Low-Density Polyethylene with the SAFT-VR Approach ... The versatility of the SAFT-VR approach in the prediction of fluid-phase equilibria of complex fluids is illustrated for systems of short and long hydrocarbons. ... 1999, 1, 2057), the phase behavior of pure long-chain n-alkane molecules was examined using the SAFT-VR approach; the intermolecular potential parameters were found to tend to a limiting value as the chain length of the n-alkane increases. ...

Clare McCabe; Amparo Galindo; M. Nieves García-Lisbona; George Jackson

2001-07-28T23:59:59.000Z

480

Tank 241-TX-118 headspace gas and vapor characterization results for samples collected in September 1994 and December 1994  

SciTech Connect

Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories

Huckaby, J.L. [Pacific Northwest Lab., Richland, WA (United States); Bratzel, D.R. [Westinghouse Hanford Co., Richland, WA (United States)

1995-09-27T23:59:59.000Z

Note: This page contains sample records for the topic "hydride vapor phase" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Vapor–liquid equilibrium for binary system of tetrahydrothiophene + 2,2,4-trimethylpentane and tetrahydrothiophene + 2,4,4-trimethyl-1-pentene at 358.15 and 368.15 K  

Science Journals Connector (OSTI)

Isothermal vapor–liquid equilibrium (VLE) for tetrahydrothiophene + 2,2,4-trimethylpentane and tetrahydrothiophene + 2,4,4-trimethyl-1-pentene at 358.15 and 368.15 K were measured with a circulation still. All systems studied exhibit positive deviation from Raoult's law. No azeotropic behavior was found in all systems at the measured temperatures. The experimental results were correlated with the Wilson model and compared to COSMO-SAC predictive model. Analyses of liquid and vapor phase composition were determined with gas chromatography. All VLE measurements passed the three thermodynamic consistency tests used. The activity coefficients at infinite dilution are also presented.

Erlin Sapei; Petri Uusi-Kyyny; Kari I. Keskinen; Juha-Pekka Pokki; Ville Alopaeus

2010-01-01T23:59:59.000Z

482

Headspace vapor characterization of Hanford Waste Tank 241-T-110: Results from samples collected on August 31, 1995. Tank Vapor Characterization Project  

SciTech Connect

This report describes the results of vapor samples taken from the headspace of waste storage tank 241-T-110 (Tank T-110) at the Hanford Site in Washington State. Pacific Northwest National Laboratory (PNNL) contracted with Westinghouse Hanford Company (WHC) to provide sampling devices and analyze samples for inorganic and organic analytes collected from the tank headspace and ambient air near the tank. The analytical work was performed by the PNNL Vapor Analytical Laboratory (VAL) by the Tank Vapor Characterization Project. Work performed was based on a sample and analysis plan (SAP) prepared by WHC. The SAP provided job-specific instructions for samples, analyses, and reporting. The SAP for this sample job was {open_quotes}Vapor Sampling and Analysis Plan{close_quotes}, and the sample job was designated S5056. Samples were collected by WHC on August 31, 1995, using the Vapor Sampling System (VSS), a truck-based sampling method using a heated probe inserted into the tank headspace.

McVeety, B.D.; Thomas, B.L.; Evans, J.C. [and others

1996-05-01T23:59:59.000Z

483

Final Report for ARM Project Measuring 4-D Water Vapor Fields with GPS  

SciTech Connect

Water vapor is a primary element in the Earth’s climate system. Atmospheric water vapor is central to cloud processes, radiation transfer, and the hydrological cycle. Using funding from Department of Energy (DOE) grant DE-FG03-02ER63327, the University Corporation for Atmospheric Research (UCAR) developed new observational techniques to measure atmospheric water vapor and applied these techniques to measure four dimensional water vapor fields throughout the United States Southern Great Plains region. This report summarizes the development of a new observation from ground based Global Positioning System (GPS) stations called Slant Water Vapor (SW) and it’s utilization in retrieving four dimensional water vapor fields. The SW observation represents the integrated amount of water vapor between a GPS station and a transmitting satellite. SW observations provide improved temporal and spatial sampling of the atmosphere when compared to column-integrated quantities such as preciptitable water vapor (PW). Under funding from the DOE Atmospheric Radiation Measurement (ARM) program, GPS networks in the Southern Great Plains (SGP) region were deployed to retrieve SW to improve the characterization of water vapor throughout the region. These observations were used to estimate four dimensional water vapor fields using tomographic approaches and through assimilation into the MM5 numerical weather model.

Braun, John

2006-02-06T23:59:59.000Z

484

Uranium Powder Production Via Hydride Formation and Alpha Phase Sintering of Uranium and Uranium-zirconium Alloys for Advanced Nuclear Fuel Applications.  

E-Print Network (OSTI)

??The research in this thesis covers the design and implementation of a depleted uranium (DU) powder production system and the initial results of a DU-Zr-Mg… (more)

Garnetti, David J.

2010-01-01T23:59:59.000Z

485

Determination of extractable arsenic in soils using slurry sampling-on-line microwave extraction-hydride generation-atomic absorption spectrometry  

Science Journals Connector (OSTI)

A flow injection procedure has been developed for the determination of acid-extractable arsenic in soils by hydride generation atomic absorption spectrometry. Several parameters, including acid and borohydride concentrations, exposure time to microwave energy, and the microwave power applied, were optimized. The on-line microwave extraction increased the recovery of the adsorbed arsenic significantly; whereas, preparation of the slurry in 10% hydrochloric acid instead of water increased the recovery only when the microwave oven was off. Low recoveries, which were investigated by removing the hydride generation manifold and connecting the system via an on-line filter to an inductively coupled plasma mass spectrometer, were due to the irreversible adsorption of arsenic on the soil. This irreversible adsorption does not allow standard additions calibration. The solution detection limit was 0.2 ?g l?1 for a 212-?l injection loop, corresponding to 7 ng g?1 in solid for a 2.5% m/v slurry prepared in 25 ml.

Hakan Gürleyük; Julian F. Tyson; Peter C Uden

2000-01-01T23:59:59.000Z

486

Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Salt Wells Area (Henkle, Et Al., 2005) Exploration Activity Details Location Salt Wells Area Exploration Technique Mercury Vapor Activity Date - 2005 Usefulness useful DOE-funding Unknown Exploration Basis Adsorbed mercury soil geochemical surveys and radiometric geophysical surveys were carried out in conjunction with geologic mapping to test the application of these ground-based techniques to geothermal exploration at three prospects in Nevada by Henkle Jr. et al. in 2005. Mercury soil vapor surveys were not widely used in geothermal exploration in the western US at the time, although the association of mercury vapors with geothermal

487

MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN  

NLE Websites -- All DOE Office Websites (Extended Search)

MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN MEASUREMENTS AND RETRIEVALS FROM A NEW 183-GHz WATER VAPOR RADIOMETER IN THE ARCTIC Cadeddu, Maria Argonne National Laboratory Category: Instruments A new G-band (183 GHz) vapor radiometer (GVR), developed and built by Prosensing Inc. (http://www.prosensing.com), was deployed in Barrow, Alaska, in April 2005. The radiometer was deployed as part of the ongoing Atmospheric Radiation Measurement (ARM) program's effort to improve water vapor retrievals in the cold, dry Arctic environment. The instrument measures brightness temperatures from four double sideband channels centered at 1, 3, 7, and 14 GHz from the 183.31-GHz water vapor line. Atmospheric emission in this spectral region is primarily due to water vapor, with some influence from liquid water. The GVR will remain in Barrow

488

Vapor–liquid equilibrium for the binary systems tetrahydrothiophene + toluene and tetrahydrothiophene + o-xylene at 368.15 K and 383.15 K  

Science Journals Connector (OSTI)

Isothermal vapor–liquid equilibrium (VLE) for tetrahydrothiophene + toluene and tetrahydrothiophene + o-xylene at 368.15 K and 383.15 K was measured with a recirculation still. Liquid- and vapor-phase compositions were determined with gas chromatography. All systems exhibit a small positive deviation from Raoult's law and show nearly ideal behavior. All VLE measurements passed the point test used. The experimental results were correlated with the Wilson model and compared with COSMO-SAC predictive models. COSMO-SAC predictions show a slight negative deviation from Raoult's law for all systems measured. Raoult's law can be used to describe all systems studied. The activity coefficients at infinite dilution are presented.

Erlin Sapei; Petri Uusi-Kyyny; Kari I. Keskinen; Juha-Pekka Pokki; Ville Alopaeus

2010-01-01T23:59:59.000Z

489

Chemical vapor deposition of amorphous semiconductor films. Final subcontract report  

SciTech Connect

Chemical vapor deposition (CVD) from higher order silanes has been studied for fabricating amorphous hydrogenated silicon thin-film solar cells. Intrinsic and doped a-Si:H films were deposited in a reduced-pressure, tubular-flow reactor, using disilane feed-gas. Conditions for depositing intrinsic films at growth rates up to 10 A/s were identified. Electrical and optical properties, including dark conductivity, photoconductivity, activation energy, optical absorption, band-gap and sub-band-gap absorption properties of CVD intrinsic material were characterized. Parameter space for depositing intrinsic and doped films, suitable for device analysis, was identified.

Rocheleau, R.E.