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1

Determination of extractable arsenic in soils using slurry sampling-on-line microwave extraction-hydride generation-atomic absorption spectrometry  

Science Journals Connector (OSTI)

A flow injection procedure has been developed for the determination of acid-extractable arsenic in soils by hydride generation atomic absorption spectrometry. Several parameters, including acid and borohydride concentrations, exposure time to microwave energy, and the microwave power applied, were optimized. The on-line microwave extraction increased the recovery of the adsorbed arsenic significantly; whereas, preparation of the slurry in 10% hydrochloric acid instead of water increased the recovery only when the microwave oven was off. Low recoveries, which were investigated by removing the hydride generation manifold and connecting the system via an on-line filter to an inductively coupled plasma mass spectrometer, were due to the irreversible adsorption of arsenic on the soil. This irreversible adsorption does not allow standard additions calibration. The solution detection limit was 0.2 ?g l?1 for a 212-?l injection loop, corresponding to 7 ng g?1 in solid for a 2.5% m/v slurry prepared in 25 ml.

Hakan Gürleyük; Julian F. Tyson; Peter C Uden

2000-01-01T23:59:59.000Z

2

E-Print Network 3.0 - antimony hydrides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Sb(V) were the only hydride-forming species found... WATERS BY HYDRIDE GENERATION ATOMIC ABSORPTION SPECTROMETRY Water-Resources Investigations Report 03... Prior to the...

3

Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems  

SciTech Connect (OSTI)

HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNL’s metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800°C). A high-temperature tank in PNNL’s storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNL’s thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

None

2011-12-05T23:59:59.000Z

4

E-Print Network 3.0 - automated hydride generation-cryotrapping...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Beds... Laboratories Hydride DevelopmentHydride Development for Hydrogen Storagefor Hydrogen Storage Karl Gross Sandia... using light-weight reversible hydrides The lack of a...

5

E-Print Network 3.0 - arsenic hydrides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(2002) 1080-703902.50 Summary: for arsenic species using hydride generation and atomic absorption spectroscopy. The detec- tion limit for As... by ASP Estimation of...

6

Method of generating hydrogen-storing hydride complexes  

DOE Patents [OSTI]

A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

Srinivasan, Sesha S; Niemann, Michael U; Goswami, D. Yogi; Stefanakos, Elias K

2013-05-14T23:59:59.000Z

7

An automated hydride generation-cryogenic trapping-ICP-MS system for measuring inorganic and methylated Ge, Sb and As species  

E-Print Network [OSTI]

An automated hydride generation-cryogenic trapping-ICP-MS system for measuring inorganic of both flow injection and batch hydride generation and couples it to an automated cryogenic trapping unit with detection by ICP-MS. The Teflon cryogenic trap was packed with 10 cm of SE-30 5% Chromosorb W-HP 80­100 mesh

Canberra, University of

8

Photoelectron spectroscopy of boron aluminum hydride cluster anions  

SciTech Connect (OSTI)

Boron aluminum hydride clusters are studied through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations. Boron aluminum hydride cluster anions, B{sub x}Al{sub y}H{sub z}{sup ?}, were generated in a pulsed arc cluster ionization source and identified by time-of-flight mass spectrometry. After mass selection, their photoelectron spectra were measured by a magnetic bottle-type electron energy analyzer. The resultant photoelectron spectra as well as calculations on a selected series of stoichiometries reveal significant geometrical changes upon substitution of aluminum atoms by boron atoms.

Wang, Haopeng; Zhang, Xinxing; Ko, Yeon Jae; Gantefoer, Gerd; Bowen, Kit H., E-mail: kbowen@jhu.edu, E-mail: kiran@mcneese.edu [Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Li, Xiang [Center for Space Science and Technology, University of Maryland–Baltimore County, Baltimore, Maryland 21250 (United States)] [Center for Space Science and Technology, University of Maryland–Baltimore County, Baltimore, Maryland 21250 (United States); Kiran, Boggavarapu, E-mail: kbowen@jhu.edu, E-mail: kiran@mcneese.edu [Department of Chemistry and Physics, McNeese State University, Lake Charles, Louisiana 70609 (United States)] [Department of Chemistry and Physics, McNeese State University, Lake Charles, Louisiana 70609 (United States); Kandalam, Anil K. [Department of Physics, West Chester University, West Chester, Pennsylvania 19383 (United States)] [Department of Physics, West Chester University, West Chester, Pennsylvania 19383 (United States)

2014-04-28T23:59:59.000Z

9

Activated aluminum hydride hydrogen storage compositions and uses thereof  

SciTech Connect (OSTI)

In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

2010-11-23T23:59:59.000Z

10

Hydride compositions  

DOE Patents [OSTI]

Disclosed are a composition for use in storing hydrogen and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the H equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to H, and then heating below the softening temperature of any of the constituents. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P{sub H}{sub 2} and determining H/M from the isothermic function of the composition.

Lee, Myung, W.

1994-01-01T23:59:59.000Z

11

Hydride compositions  

DOE Patents [OSTI]

A composition for use in storing hydrogen, and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the hydrogen equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to hydrogen and then heating at a temperature below the softening temperature of any of the. constituents so that their chemical and structural integrity is preserved. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P.sub.H.sbsb.2 and determining H/M from the isothermic function of the composition.

Lee, Myung W. (North Augusta, SC)

1995-01-01T23:59:59.000Z

12

Constituting Atoms of a $?$ Algebra via Its Generator  

E-Print Network [OSTI]

To constitute atoms of a $\\sigma$ algebra is not a easy task due to the large number of its elements. However, determining them via generators seems a feasible and simple way since most $\\sigma$ algebras are generated by their smaller proper subsets. Precisely, under some conditions each atom of a $\\sigma$ algebra equals the intersection of the elements containing a point of the atom in the generator. In this paper, a very weak sufficient condition for determining atoms by the generator is presented. The condition, though not being a necessary one, is shown to be almost the weakest one in the sense that it can hardly be improved.

Jinshan Zhang

2007-11-15T23:59:59.000Z

13

Optically generated gauge potentials and their effects in cold atoms.  

E-Print Network [OSTI]

??Recent theoretical studies show the possibility of generating optical gauge potentials in neutral atoms using laser beams carrying orbital angular momentum. This is interesting not… (more)

Song, Jianjun

2008-01-01T23:59:59.000Z

14

Control momentum entanglement with atomic spontaneously generated coherence  

E-Print Network [OSTI]

With atomic spontaneously generated coherence (SGC), we propose a novel scheme to coherently control the atom--photon momentum entanglement through atomic internal coherence. A novel phenomena of ``phase entanglement in momentum'' is proposed, and we found, under certain conditions, that super--high degree of momentum entanglement can be produced with this scheme.

Rui Guo; Hong Guo

2007-01-05T23:59:59.000Z

15

The effect of oxide layers on gas-generating hydride particles during production of aluminium foams  

SciTech Connect (OSTI)

Melt routes to metallic foam production offer attractions of low cost and the potential for good microstructural control. In situ gas generation may be preferable to external gas injection in terms of the important objective of generating a fine and uniform cell structure. The main difficulty with this approach has been that of ensuring that the gas-generating powder is suitably dispersed throughout the melt before the gas is released and the cells are formed. In the present paper, procedures are outlined for preparation of powders for use in aluminium melts, where gas will be released only after a suitable delay, allowing the powders to first become well-dispersed in the melt and solidification to start. Pre-treatment of the foaming agent also facilitates a flexible production of castings with various porosity at the same processing conditions simply by varying the thickness of a diffusion barrier layer on the gas-releasing agent. The role of the melt viscosity history, as a function of a heat extraction rate from the solidifying melt and an alloy composition, on the final porosity of the castings is also briefly discussed.

Gergely, V.; Clyne, T.W. [Univ. of Cambridge (United Kingdom). Dept. of Materials Science and Metallurgy

1998-12-31T23:59:59.000Z

16

Metal Hydrides - Science Needs  

Broader source: Energy.gov (indexed) [DOE]

Storage Grand Challenge Pre-Solicitation Meeting, June 19, 2003 1 Metal Hydrides - Science Needs TRADITIONAL METALLIC HYDRIDES: 1.5 to 2 wt.% H. Well studied. COMPLEX...

17

Metal Hydride Hydrogen Storage R and D  

Broader source: Energy.gov [DOE]

DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

18

Metal Hydride Hydrogen Storage Research and Development  

Broader source: Energy.gov [DOE]

DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

19

Generation of atomic entangled states using linear optics  

E-Print Network [OSTI]

In this paper, we propose a novel scheme that can generate two-atom maximally entangled states from pure product states and mixed states using linear optics. Because the scheme can generate pure maximally entangled states from mixed states, we denote it as purification-like generation scheme.

Zhuo-Liang Cao; Ming Yang

2003-11-13T23:59:59.000Z

20

Pressure-induced phase transformations in alkali-metal hydrides calculated using an improved linear-muffin-tin-orbital–atomic-sphere-approximation energy scheme  

Science Journals Connector (OSTI)

A scheme for the calculation of total energies from first principles is described which is intermediate between the popular linear muffin-tin-orbital method in the atomic-sphere approximation (LMTO-ASA) and an exact full-potential treatment. The local-density total energy is evaluated accurately for the output charge density from the ASA potential. This method is applied to the study of static structural properties and the pressure-induced phase transformation from B1 (NaCl-structure) to B2 (CsCl-structure) phases for the partially ionic alkaki-metal hydrides NaH and KH and the alkali halide NaCl. Good agreement with experimental transition pressures and volumes is obtained. The series NaH, KH, and NaCl shows the observed strong cation and weak anion dependence. Charge densities and band structures are given at zero and high pressure. Calculated energy-volume curves for LiH show no transition up to 1 Mbar, in agreement with experimental data.

C. O. Rodriguez and M. Methfessel

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Theory of a coherent atomic-beam generator  

Science Journals Connector (OSTI)

We present a many-body theory of a driven and damped trapped gas of interacting bosons, and demonstrate that one of the trap levels can become coherently populated, thereby leading to a coherent atomic-beam generator, or ‘‘laser for atoms.’’ The specific system we consider consists of a sample of bosonic atoms interacting via the near-resonant dipole-dipole interaction. The transverse center-of-mass motion of the atoms is confined by a two-dimensional potential well created by an array of cooling laser beams, while their longitudinal motion is quantized by a Fabry-Pérot for atoms. Under appropriate conditions, the dipole-dipole selection rules lead to the simplification that only two quantized levels of atomic motion need to be considered explicitly, the other levels being treated as reservoirs. One of the two levels is the ‘‘pump level,’’ while the other is the one where atomic coherence builds up (the ‘‘lasing’’ level). The master equation describing the dynamics of these levels can be solved numerically, and its solution exhibits a ‘‘threshold behavior’’ with a transition from super-Poissonian to Poissonian atom statistics in the ‘‘lasing mode.’’ © 1996 The American Physical Society.

A. M. Guzmán; M. Moore; P. Meystre

1996-02-01T23:59:59.000Z

22

E-Print Network 3.0 - atomic beams generated Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beams generated Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic beams generated Page: << < 1 2 3 4 5 > >> 1 Superradiant Rayleigh scattering...

23

1/28/2014 CFCAM Workshop 2014 1 How to generate ^ PAW Atomic Datasets*  

E-Print Network [OSTI]

1/28/2014 CFCAM Workshop 2014 1 Good How to generate ^ PAW Atomic Datasets* N. A. W. Holzwarth 2014 2 Good How to generate ^ PAW Atomic Datasets Challenges Tricks Opportunities for collaboration Importance of having several independent codes (both for atomic dataset generation and for materials

Holzwarth, Natalie

24

Generators of the de Sitter Group for the Hydrogen Atom  

Science Journals Connector (OSTI)

Explicit Hermitian operator functions of q and p are constructed for the generators of the de Sitter group O(4, 1) on the bound-state wave functions for the hydrogen atom. This is done for each of the one-parameter family of irreducible unitary representations of O(4, 1) in which the irreducible representations of the four-dimensional rotation group O(4) correspond to the degeneracy subspaces of the bound-state energy levels. The commutation relations and the values of the invariants which label the representation of O(4, 1) are verified by direct operator calculations.

R. H. Pratt and T. F. Jordan

1966-08-26T23:59:59.000Z

25

Transition-Metal Hydrides  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transition-Metal Hydride Electrochromics Transition-Metal Hydride Electrochromics A new type of electrochromic hydride material has interesting and unusual properties. Thin Ni-Mg films, for example, are mirror-like in appearance and have very low visible transmittance. On exposure to hydrogen gas or on reduction in alkaline electrolyte, the films become transparent. The transition is believed to result from formation of nickel magnesium hydride, Mg2NiH4. Switchable mirrors based on rare earth hydrides were discovered in 1996 at Vrije University in the Netherlands, Rare earth-magnesium alloy films were subsequently found to be superior to the pure lanthanides in maximum transparency and mirror-state reflectivity by Philips Laboratories. The newer transition-metal types which use less expensive and less reactive materials were discovered at LBNL. This has now become a very active area of study with a network of researchers.

26

E-Print Network 3.0 - atomic nano-generators actinium-225-labeled...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nano-generators actinium-225-labeled Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic nano-generators actinium-225-labeled Page: << < 1 2 3 4...

27

Spontaneously generated coherence induced second-order susceptibility in atomic gases  

E-Print Network [OSTI]

The second-order susceptibility which vanishes in the electric-dipole approximation for an atom is induced by the spontaneously generated coherence. The spontaneously generated coherence considered in a lambda-type atomic system causes an indirect coupling between the lower two levels which acts equivalently as a DC-field and therefore makes possible the existence of second-order susceptibility.

Yueping Niu; Shangqing Gong

2006-03-12T23:59:59.000Z

28

Outcomes of Chronic Arsenic Exposure on Aquatic Insects  

E-Print Network [OSTI]

electrothermal atomic absorption spectrometry. AnalyticaHydride Generated Atomic Absorption Spectroscopy (HGAAS) andHydride Generated Atomic Absorption Spectroscopy (HGAAS).

Mogren, Christina Loraine

2013-01-01T23:59:59.000Z

29

Generation of genuine $?$-type four-particle entangled state of superconducting artificial atoms with broken symmetry  

E-Print Network [OSTI]

We propose a scheme for generating a genuine $\\chi$-type four-particle entangled state of superconducting artificial atoms with broken symmetry by using one-dimensional transmission line resonator as a data bus. The $\\Delta$-type three-level artificial atom we use in the scheme is different from natural atom and has cyclic transitions. After suitable interaction time and simple operations, the desired entangled state can be obtained. Since artificial atomic excited states and photonic states are adiabatically eliminated, our scheme is robust against the spontaneous emissions of artificial atoms and the decays of transmission line resonator.

Chun-Ling Leng; Qi Guo; Xin Ji; Shou Zhang

2014-12-11T23:59:59.000Z

30

Method for preparing porous metal hydride compacts  

DOE Patents [OSTI]

A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

1980-01-21T23:59:59.000Z

31

Theoretical Exploration of the Mechanism of Riboflavin Formation from 6,7-Dimethyl-8-ribityllumazine: Nucleophilic Catalysis, Hydride Transfer, Hydrogen Atom Transfer, or Nucleophilic Addition?  

Science Journals Connector (OSTI)

The calculated constellation of the two acting lumazine units in the transition state (see Figure 7) seems to be compatible with what is known of the active site of the enzyme. ... We assess these four functionals by comparing their performance to that of 12 other functionals and Hartree-Fock theory for 403 energetic data in 29 diverse databases, including ten databases for thermochem., four databases for kinetics, eight databases for noncovalent interactions, three databases for transition metal bonding, one database for metal atom excitation energies, and three databases for mol. ... Quantum Calculation of Molecular Energies and Energy Gradients in Solution by a Conductor Solvent Model ...

Martin Breugst; Albert Eschenmoser; K. N. Houk

2013-04-03T23:59:59.000Z

32

PNNL Chemical Hydride Capabilities | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Chemical Hydride Capabilities PNNL Chemical Hydride Capabilities Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC....

33

Structure of the novel ternary hydrides Li4Tt2D (Tt = Si and Ge)  

Science Journals Connector (OSTI)

The crystal structures of novel Li4Tt2D (Tt = Si and Ge) ternary hydrides were solved using neutron powder diffraction data. All hydrogen atoms were found to occupy Li6-octahedral interstices.

Wu, H.

2007-01-15T23:59:59.000Z

34

Generation of Werner states via collective decay of coherently driven atoms  

E-Print Network [OSTI]

We show deterministic generation of Werner states as a steady state of the collective decay dynamics of a pair of neutral atom coupled to a leaky cavity and strong coherent drive. We also show how the scheme can be extended to generate $2N$-particle analogue of the bipartite Werner states.

Girish S. Agarwal; Kishore T. Kapale

2005-10-13T23:59:59.000Z

35

Influence of uranium hydride oxidation on uranium metal behaviour  

SciTech Connect (OSTI)

This work addresses concerns that the rapid, exothermic oxidation of active uranium hydride in air could stimulate an exothermic reaction (burning) involving any adjacent uranium metal, so as to increase the potential hazard arising from a hydride reaction. The effect of the thermal reaction of active uranium hydride, especially in contact with uranium metal, does not increase in proportion with hydride mass, particularly when considering large quantities of hydride. Whether uranium metal continues to burn in the long term is a function of the uranium metal and its surroundings. The source of the initial heat input to the uranium, if sufficient to cause ignition, is not important. Sustained burning of uranium requires the rate of heat generation to be sufficient to offset the total rate of heat loss so as to maintain an elevated temperature. For dense uranium, this is very difficult to achieve in naturally occurring circumstances. Areas of the uranium surface can lose heat but not generate heat. Heat can be lost by conduction, through contact with other materials, and by convection and radiation, e.g. from areas where the uranium surface is covered with a layer of oxidised material, such as burned-out hydride or from fuel cladding. These rates of heat loss are highly significant in relation to the rate of heat generation by sustained oxidation of uranium in air. Finite volume modelling has been used to examine the behaviour of a magnesium-clad uranium metal fuel element within a bottle surrounded by other un-bottled fuel elements. In the event that the bottle is breached, suddenly, in air, it can be concluded that the bulk uranium metal oxidation reaction will not reach a self-sustaining level and the mass of uranium oxidised will likely to be small in relation to mass of uranium hydride oxidised. (authors)

Patel, N.; Hambley, D. [National Nuclear Laboratory (United Kingdom); Clarke, S.A. [Sellafield Ltd (United Kingdom); Simpson, K.

2013-07-01T23:59:59.000Z

36

Controlled generation of field squeezing with cold atomic clouds coupled to a superconducting transmission line resonator  

SciTech Connect (OSTI)

We propose an efficient method for controlled generation of field squeezing with cold atomic clouds trapped close to a superconducting transmission line resonator. It is shown that, based on the coherent strong magnetic coupling between the collective atomic spins and microwave fields in the transmission line resonator, two-mode or single-mode field squeezed states can be generated through coherent control on the dynamics of the system. The degree of squeezing and preparing time can be directly controlled through tuning the external classical fields. This protocol may offer a promising platform for implementing scalable on-chip quantum information processing with continuous variables.

Li Pengbo; Li Fuli [MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Department of Applied Physics, Xi'an Jiaotong University, Xi'an 710049 (China)

2010-03-15T23:59:59.000Z

37

Controlled generation of field squeezing with cold atomic clouds coupled to a superconducting transmission line resonator  

E-Print Network [OSTI]

We propose an efficient method for controlled generation of field squeezing with cold atomic clouds trapped close to a superconducting transmission line resonator. It is shown that, based on the coherent strong magnetic coupling between the collective atomic spins and microwave fields in the transmission line resonator, two-mode or single mode field squeezed states can be generated through coherent control on the dynamics of the system. The degree of squeezing and preparing time can be directly controlled through tuning the external classical fields. This protocol may offer a promising platform for implementing scalable on-chip quantum information processing with continuous variables.

Peng-Bo Li; Fu-Li Li

2010-02-26T23:59:59.000Z

38

Carrier-wave Rabi flopping signatures in high-order harmonic generation for alkali atoms  

E-Print Network [OSTI]

We present the first theoretical investigation of carrier-wave Rabi flopping in real atoms by employing numerical simulations of high-order harmonic generation (HHG) in alkali species. Given the short HHG cutoff, related to the low saturation intensity, we concentrate on the features of the third harmonic of sodium (Na) and potassium (K) atoms. For pulse areas of 2$\\pi$ and Na atoms, a characteristic unique peak appears, which, after analyzing the ground state population, we correlate with the conventional Rabi flopping. On the other hand, for larger pulse areas, carrier-wave Rabi flopping occurs, and is associated with a more complex structure in the third harmonic. These new characteristics observed in K atoms indicate the breakdown of the area theorem, as was already demonstrated under similar circumstances in narrow band gap semiconductors.

Ciappina, M F; Landsman, A S; Zimmermann, T; Lewenstein, M; Roso, L; Krausz, F

2015-01-01T23:59:59.000Z

39

Arc plasma generator of atomic driver for steady-state negative ion source  

SciTech Connect (OSTI)

The paper reviews the results of development of steady-state arc-discharge plasma generator with directly heated LaB{sub 6} cathode. This arc-discharge plasma generator produces a plasma jet which is to be converted into an atomic one after recombination on a metallic plate. The plate is electrically biased relative to the plasma in order to control the atom energies. Such an intensive jet of hydrogen atoms can be used in negative ion sources for effective production of negative ions on a cesiated surface of plasma grid. All elements of the plasma generator have an augmented water cooling to operate in long pulse mode or in steady state. The thermo-mechanical stresses and deformations of the most critical elements of the plasma generator were determined by simulations. Magnetic field inside the discharge chamber was optimized to reduce the local power loads. The first tests of the steady-state arc plasma generator prototype have performed in long-pulse mode.

Ivanov, A. A.; Belchenko, Yu. I.; Davydenko, V. I. [Budker Institute of Nuclear Physics, Novosibirsk (Russian Federation) [Budker Institute of Nuclear Physics, Novosibirsk (Russian Federation); Novosibirsk State University, Novosibirsk (Russian Federation); Ivanov, I. A.; Kolmogorov, V. V.; Listopad, A. A., E-mail: a.a.listopad@inp.nsk.su; Mishagin, V. V.; Shulzhenko, G. I. [Budker Institute of Nuclear Physics, Novosibirsk (Russian Federation)] [Budker Institute of Nuclear Physics, Novosibirsk (Russian Federation); Putvinsky, S. V.; Smirnov, A. [Tri Alpha Energy Inc., Rancho Santa Margarita, California 92688 (United States)] [Tri Alpha Energy Inc., Rancho Santa Margarita, California 92688 (United States)

2014-02-15T23:59:59.000Z

40

Hydride Rim Formation in Unirradiated Zircaloy  

Broader source: Energy.gov [DOE]

The purpose of this work is to develop the means of pre-hydriding unirradiated Zircaloy cladding such that a high concentration, or rim, of hydrides is formed at the cladding outside diameter.

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Crack propagation in hydrided zircaloy-2  

Science Journals Connector (OSTI)

Transmission electron microscope observations of cracks in thin foils of Zircaloy—2 which contains hydride particles have shown that the fracture process is one of linking up satellite cracks in the hydride ph...

G. Östberg

1968-06-01T23:59:59.000Z

42

Hydrogen, lithium, and lithium hydride production  

DOE Patents [OSTI]

A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

2014-03-25T23:59:59.000Z

43

E-Print Network 3.0 - alkali metal hydrides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hf for selected alkali metal hydrides, alkaline earth metal hydrides, transition metal hydrides... of binary hydrides based on alkali metals, alkaline earth ... Source:...

44

First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities  

SciTech Connect (OSTI)

Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density-functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest-energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium-hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities.

Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

2013-09-01T23:59:59.000Z

45

Fracture Initiation Due to Hydrides in Zircaloy-2  

Science Journals Connector (OSTI)

In hydride-forming metals, the presence of hydrides can sometimes lead to brittle fracture. Zirconium is a hydride-forming metal that forms the basis of a number of alloys used in CANDUTM nuclear reactors. Under ...

M. P. Puls; B. W. Leitch; W. R. Wallace

1987-01-01T23:59:59.000Z

46

Complex Hydrides for Hydrogen Storage  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrides for Hydrides for Hydrogen Storage George Thomas, Consultant Sandia National Laboratories G. J. Thomas Efficient onboard hydrogen storage is a critical enabling technology for the use of hydrogen in vehicles * The low volumetric density of gaseous fuels requires a storage method which densifies the fuel. - This is particularly true for hydrogen because of its lower energy density relative to hydrocarbon fuels. * Storage methods result in additional weight and volume above that of the fuel. How do we achieve adequate stored energy in an efficient, safe and cost-effective system? G. J. Thomas However, the storage media must meet certain requirements: - reversible hydrogen uptake/release - lightweight - low cost - cyclic stability - rapid kinetic properties - equilibrium properties (P,T) consistent

47

Activated Aluminum Hydride Hydrogen Storage Compositions - Energy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen and Fuel Cell Find More Like This Return to Search Activated Aluminum Hydride Hydrogen Storage Compositions Brookhaven National Laboratory Contact BNL About This...

48

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary...  

Broader source: Energy.gov (indexed) [DOE]

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities...

49

Recent developments in hydrogen storage applications based on metal hydrides  

Science Journals Connector (OSTI)

Metal hydrides have been commercialized for battery applications for more than 8 years. In case of storage applications, metal hydrides were extensively evaluated in combination with combustion engines. The relatively low gravimetric energy density of hydride tanks based on low temperature metal hydrides prevented the commercial use of that technology. Recently, lasting progress in the PEM fuel cell technology offers chances for metal hydride storage systems mainly for low power applications, but also for niche markets. The paper describes promising projects on metal hydride storage technology and gives an outlook about improvements of both the metal hydride alloy performance and the performance of metal hydride storage tanks.

V. Güther; A. Otto

1999-01-01T23:59:59.000Z

50

Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A Predictive Model through Computations. Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A...

51

Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors  

E-Print Network [OSTI]

of hydride fueled BWRs. Nuclear Engineering and Design, 239:Fueled PWR Cores. Nuclear Engineering and Design, 239:1489–Hydride Fueled LWRs. Nuclear Engineering and Design, 239:

Terrani, Kurt Amir

2010-01-01T23:59:59.000Z

52

ITOUGH2 Software Qualification  

E-Print Network [OSTI]

hydride generation atomic absorption spectrometry with on-B y conventional flame atomic absorption (FLAA) methods,hydride generation atomic absorption spectrometry with on-

Fraser, P.

2010-01-01T23:59:59.000Z

53

Selenium Fractionation and Cycling in the Intertidal Zone of the Carquinez Strait - October 1995 to December 1995  

E-Print Network [OSTI]

hydride generation atomic absorption spectrometry with on-B y conventional flame atomic absorption (FLAA) methods,hydride generation atomic absorption spectrometry with on-

Zawislanski, P.T.

2010-01-01T23:59:59.000Z

54

Diffusional exchange of isotopes in a metal hydride sphere.  

SciTech Connect (OSTI)

This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

2011-04-01T23:59:59.000Z

55

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films  

E-Print Network [OSTI]

X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic

56

Kinetics of hydride front in Zircaloy-2 and H release from a fractional hydrided surface  

Science Journals Connector (OSTI)

The authors study the hydriding process on commercial nuclear fuelcladdings from their inner surface using an ultrahigh vacuum method. The method allows determining the incubation and failure times of the fuel claddings as well as the dissipated energy and the partial pressure of the desorbed H 2 from the outer surface of fuel claddings during the hydriding process. The correlation between the hydriding dissipated energy and the amount of zirconium hydride (formed at different stages of the hydriding process) leads to a near t 1 ? 2 potential law corresponding to the time scaling of the reaction for the majority of the tested samples. The calibrated relation between energy and hydride thickness allows one to calculate the enthalpy of the ? - Zr H 1.5 phase. The measured H 2 desorption from the external surface is in agreement with a proposed kinetic desorption model from the hydrides precipitated at the surface.

M. Díaz; A. González-González; J. S. Moya; B. Remartínez; S. Pérez; J. L. Sacedón

2009-01-01T23:59:59.000Z

57

Hydriding and dehydriding characteristics of LiBH{sub 4} and transition metals-added magnesium hydride  

SciTech Connect (OSTI)

Graphical abstract: Hydriding reaction curves under 12 bar H{sub 2}, and dehydriding reaction curves under 1.0 bar H{sub 2}, at 593 K at the 1st cycle for MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti and MgH{sub 2}. Highlights: ? Addition of Ni, LiBH{sub 4}, and Ti to MgH{sub 2} to increase reaction rates. ? Sample preparation by reactive mechanical grinding. ? At n = 2, the sample absorbed 4.05 wt% H for 60 min at 593 K under 12 bar H{sub 2}. ? Analysis of rate-controlling step for dehydriding of the sample at n = 3. - Abstract: In this study, MgH{sub 2} was used as a starting material instead of Mg. Ni, Ti, and LiBH{sub 4} with a high hydrogen-storage capacity of 18.4 wt% were added. A sample with a composition of MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti was prepared by reactive mechanical grinding. The activation of MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti was completed after the first hydriding–dehydrding cycle. The hydriding rate decreases as the temperature increases due to the decrease in the driving force for the hydriding reaction. At the 1st cycle, the sample desorbs 1.45 wt% H for 10 min, 2.54 wt% H for 20 min, 3.13 wt% H for 30 min, and 3.40 wt% H for 60 min at 593 K under 1.0 bar H{sub 2}. At the 2nd cycle, the sample absorbs 3.84 wt% H for 5 min, 3.96 wt% H for 10 min, and 4.05 wt% H for 60 min at 593 K under 12 bar H{sub 2}. MgH{sub 2}–10Ni–2LiBH{sub 4}–2Ti after reactive mechanical grinding contained MgH{sub 2}, Mg, Ni, TiH{sub 1.924}, and MgO phases. The reactive mechanical grinding of Mg with Ni, LiBH{sub 4}, and Ti is considered to create defects on the surface and in the interior of Mg (to facilitate nucleation), and to reduce the particle size of Mg (to shorten diffusion distances of hydrogen atoms). The formation of Mg{sub 2}Ni during hydriding–dehydriding cycling increases the hydriding and dehydriding rates of the sample.

Song, Myoung Youp, E-mail: songmy@jbnu.ac.kr [Division of Advanced Materials Engineering, Hydrogen and Fuel Cell Research Center, Engineering Research Institute, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, 561-756 (Korea, Republic of); Kwak, Young Jun; Lee, Seong Ho [Department of Materials Engineering, Graduate School, Chonbuk National University, 567 Baekje-daero, Deokjin-gu, Jeonju, 561-756 (Korea, Republic of); Park, Hye Ryoung [Faculty of Applied Chemical Engineering, Chonnam National University, 300 Yongbongdong, Bukgu, Gwangju, 500-757 (Korea, Republic of)

2013-07-15T23:59:59.000Z

58

Zirconium hydride containing explosive composition  

DOE Patents [OSTI]

An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1500 and 10,000 meters per second and a minor amount of a donor additive comprising a non-explosive compound or mixture of non-explosive compounds which when subjected to an energy fluence of 1000 calories/cm.sup.2 or less is capable of releasing free radicals each having a molecular weight between 1 and 120. Exemplary donor additives are dibasic acids, polyamines and metal hydrides.

Walker, Franklin E. (18 Shadow Oak Rd., Danville, CA 94526); Wasley, Richard J. (4290 Colgate Way, Livermore, CA 94550)

1981-01-01T23:59:59.000Z

59

Wire Wrapped Hexagonal Pin Arrays for Hydride Fueled PWRs  

E-Print Network [OSTI]

This work contributes to the Hydride Fuels Project, a collaborative effort between UC Berkeley and MIT

Diller, Peter

60

Electrochemical process and production of novel complex hydrides  

DOE Patents [OSTI]

A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

Zidan, Ragaiy

2013-06-25T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Hydrogen-storing hydride complexes  

DOE Patents [OSTI]

A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

Srinivasan, Sesha S. (Tampa, FL); Niemann, Michael U. (Venice, FL); Goswami, D. Yogi (Tampa, FL); Stefanakos, Elias K. (Tampa, FL)

2012-04-10T23:59:59.000Z

62

Liquid suspensions of reversible metal hydrides  

DOE Patents [OSTI]

The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

1983-12-08T23:59:59.000Z

63

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Title X-Ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films Publication Type Journal Article LBNL Report Number LBNL-50574 Year of Publication 2002 Authors Richardson, Thomas J., Baker Farangis, Jonathan L. Slack, Ponnusamy Nachimuthu, Rupert C. C. Perera, Nobumichi Tamura, and Michael D. Rubin Journal Journal of Alloys and Compounds Volume 356-357 Start Page 204 Pagination 204-207 Date Published 08/2003 Keywords A. hydrogen storage materials, NEXAFS, thin film s; C. EXAFS, x-ray diffraction Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption spectroscopy. Mg K-edge and Ni, Co, and Ti L-edge spectra reflect both reversible and irreversible changes in the metal environments. A significant shift in the nickel L absorption edge shows it to be an active participant in hydride formation. The effect on cobalt and titanium is much less dramatic, suggesting that these metals act primarily as catalysts for formation of magnesium hydride.

64

High-order harmonic generation in atomic hydrogen at 248 nm: Dipole-moment versus acceleration spectrum  

E-Print Network [OSTI]

We present a study of the high-order harmonic-generation (HG) spectra of atomic hydrogen at 248 nm based on the Fourier transform of the expectation values of the induced dipole moment and acceleration. The calculations were performed by extending a...

Jiang, Tsin-Fu; Chu, Shih-I

1992-12-01T23:59:59.000Z

65

E-Print Network 3.0 - atomic hydrogen generated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 Theoretical study on interaction of hydrogen with single-walled boron nitride nanotubes. II. Collision, storage, and adsorption Summary: two hydrogen atoms, but only one of...

66

Generation of two-color EPR-entangled optical beams in macroscopic atomic ensembles  

SciTech Connect (OSTI)

We present a protocol for deterministically producing continuous-variable Einstein-Podolsky-Rosen- (EPR-) entangled optical beams in macroscopic atomic ensembles. In contrast to previous cavity-based schemes, our protocol requires only a single pass of two coherent light beams through two spin-polarized free-space atomic vapors, which greatly simplifies the experimental implementation and makes the scheme very efficient. The two entangled modes have a frequency difference of about twice the Zeeman frequency of the atomic vapors, which can be widely tuned via magnetic-field control. Under realistic experimental conditions, we show that large entanglement could be created even with room-temperature atomic vapors.

Wang Mingfeng; Gu Wenjing; Jin Qingli; Zheng Yizhuang [School of Physics and Electronics Information Engineering, Wenzhou University, Wenzhou 325027 (China)

2010-10-15T23:59:59.000Z

67

Observations of proton beam enhancement due to erbium hydride on gold foil targets  

SciTech Connect (OSTI)

Recent theoretical work suggests that the conversion efficiency from laser to protons in laser irradiated thin foil experiments increases if the atomic mass of nonhydrogen atoms on the foil rear surface increases. Experiments were performed at the Lawrence Livermore National Laboratory Jupiter Laser Facility to observe the effect of thin foils coated with erbium hydride on the conversion efficiency from laser to protons. Gold foils with and without the rear surface coated with ErH{sub 3} were irradiated using the ultrashort pulse, 40 TW Callisto laser. An argon-ion etching system was used to remove naturally occurring nanometer thick surface layer contaminants from the hydride. With the etcher, gold with ErH{sub 3} showed a 25% increase in the conversion efficiency to protons above 3.4 MeV relative to contaminants, where C{sup +4} and H{sup +} were the dominant ion species. No difference in the ion signal was observed without first cleaning the hydrides. Simulations using the hybrid PIC code, LSP, revealed that the increase due to erbium hydride versus contaminants is 37% for protons above 3 MeV.

Offermann, D. T.; Van Woerkom, L. D. [Department of Physics, Ohio State University, Columbus, Ohio 43210 (United States); Freeman, R. R. [Department of Physics, Ohio State University, Columbus, Ohio 43210 (United States); Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, California 92093 (United States); Department of Applied Science, University of California Davis, Livermore, California 94550 (United States); Foord, M. E.; Hey, D.; Key, M. H.; Mackinnon, A. J.; MacPhee, A. G.; Patel, P. K.; Ping, Y.; Sanchez, J. J.; Shen, N. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Bartal, T.; Beg, F. N. [Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, California 92093 (United States); Espada, L. [Sandia National Laboratory, Albuquerque, New Mexico 87185 (United States); Chen, C. D. [Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2009-09-15T23:59:59.000Z

68

Analytical assessment of the thermal behavior of nickel-metal hydride batteries  

E-Print Network [OSTI]

Analytical assessment of the thermal behavior of nickel-metal hydride batteries Peyman Taheri in batteries with orthotropic thermal conductivities, where the heat generation is due to irreversible of the battery thermal behavior with modest numerical effort. The accuracy of the proposed model is tested

Bahrami, Majid

69

Generation and Control of Chains of Entangled Atom-Ion Pairs with Quantum Light  

SciTech Connect (OSTI)

Coherent control using quantum light incident upon molecules in an optical lattice is shown to give rise to a direct way of writing arbitrary sequences of entangled atom-ion pairs. There is no evident limitation on the length of the word (i.e., the number of qbits) that can be formed.

Shapiro, Moshe [Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z3 (Canada); Department of Chemical Physics, Weizmann Institute, Rehovot 76100 (Israel); Brumer, Paul [Chemical Physics Theory Group, Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6 (Canada)

2011-04-15T23:59:59.000Z

70

Hydridable material for the negative electrode in a nickel-metal hydride storage battery  

SciTech Connect (OSTI)

A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

1997-01-01T23:59:59.000Z

71

Generating and controlling chains of entangled atoms by coherent control techniques  

SciTech Connect (OSTI)

A practical way of writing long sequences of entangled atomic qubits using coherent control with classical light sources is proposed. The method utilizes one-photon vs two-photon interference as a means of controlling the directionality of the motion of valence electrons during molecular dissociation processes. We show that, by dissociating in an optical lattice a one-dimensional array of ultracold diatomic molecules (e.g., Na{sub 2}{yields}Na+Na{sup *}), using a combination of photoabsorption of two mutually perpendicularly polarized beams at center frequency {omega} and a coherent Raman transition at frequencies {omega}{sub 1} and {omega}{sub 2}={omega}{sub 1}-{omega}, one can craft entangled states composed of arbitrary superpositions of sequences of atomic states, such as |f>|f>|b>+{center_dot}{center_dot}{center_dot}+|b>|b>|f>+{center_dot}{center_dot}{center_dot}, where |f> designates a dissociation process in which the ground-state Na atom goes in the forwarddirection and the excited-state Na{sup *} goes in the backward direction, while |b> designates the reverse process, namely, Na going in the backward direction and Na{sup *} going in the forward direction. The method, which on the basis of past work is expected to be robust against decoherence, would enable the encoding of very long sequences of entangled qubits.

Shapiro, Moshe [Department of Chemistry, University of British Columbia, Vancouver, British Columbia, V6T 1Z3 (Canada) and Department of Chemical Physics, Weizmann Institute, Rehovot 76100 (Israel)

2011-11-15T23:59:59.000Z

72

Gas phase contributions to topochemical hydride reduction reactions  

SciTech Connect (OSTI)

Alkali and alkali earth hydrides have been used as solid state reductants recently to yield many interesting new oxygen-deficient transition metal oxides. These reactions have tacitly been assumed to be a solid phase reaction between the reductant and parent oxide. We have conducted a number of experiments with physical separation between the reductant and oxides, and find that in some cases reduction proceeds even when the reagents are physically separated, implying reactions with in-situ generated H{sub 2} and, to a lesser extent, getter mechanisms. Our findings change our understanding of these topochemical reactions, and should enhance the synthesis of additional new oxides and nanostructures. - Graphical abstract: Topochemical reductions with hydrides: Solid state or gas phase reaction? Display Omitted - Highlights: • SrFeO{sub 2} and LaNiO{sub 2} were prepared by topochemical reduction of oxides. • Separating the reducing agent (CaH{sub 2}, Mg metal) from the oxide still results in reduction. • Such topochemical reactions can occur in the gas phase.

Kobayashi, Yoji [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); Li, Zhaofei [Institute for Integrated Cell-Material Sciences, Kyoto University, Sakyo-ku, Kyoto 606-8502 (Japan); Hirai, Kei [Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Tassel, Cédric [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); The Hakubi Center for Advanced Research, Kyoto University, Yoshida-Ushinomiya-cho, Sakyo-ku, Kyoto 606-8302 (Japan); Loyer, François [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); Institut des Sciences Chimiques de Rennes, UMR 6226 Université de Rennes 1-CNRS, équipe CSM, Bât. 10B, Campus de Beaulieu, 263, Avenue du Général Leclerc, 35042 Rennes Cedex (France); Ichikawa, Noriya [CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Abe, Naoyuki [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502 (Japan); Yamamoto, Takafumi [Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan); Shimakawa, Yuichi [CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); and others

2013-11-15T23:59:59.000Z

73

Encapsulated Metal Hydride for Hydrogen Separation  

E-Print Network [OSTI]

concentration feed stock, not for low concentration � Hydrogen economy will need hydrogen recovery from lowEncapsulated Metal Hydride for Hydrogen Separation (Formerly Separation Membrane Development) DOE Hydrogen Program 2003 Merit Review and Peer Evaluation L. Kit Heung, Jim Congdon Savannah River Technology

74

Ductility Evaluation of As-Hydrided and Hydride Reoriented Zircaloy-4 Cladding under Simulated Dry-Storage Condition  

SciTech Connect (OSTI)

Pre-storage drying-transfer operations and early stage storage expose cladding to higher temperatures and much higher pressure-induced tensile hoop stresses relative to normal operation in-reactor and pool storage under these conditions. Radial hydrides could precipitate during slow cooling and provide an additional embrittlement mechanism as the cladding temperature decreases below the ductile-to-brittle transition temperature. As a means of simulating this behavior, unirradiated hydrided Zircaloy-4 samples were fabricated by a gas charging method to levels that encompass the range of hydrogen concentrations observed in current used fuel. Mechanical testing was carried out by the ring compression test (RCT) method at various temperatures to evaluate the sample s ductility for both as-hydrided and post-hydride reorientation treated specimens. As-hydrided samples with higher hydrogen concentration (>800 ppm) resulted in lower strain before fracture and reduced maximum load. Increasing RCT temperatures resulted in increased ductility of the as-hydrided cladding. A systematic radial hydride treatment was conducted at various pressures and temperatures for the hydrided samples with H content around 200 ppm. Following the radial hydride treatment, RCTs on the hydride reoriented samples were conducted and exhibited lower ductility compared to as-hydrided samples.

Yan, Yong [ORNL] [ORNL; Plummer, Lee K [ORNL] [ORNL; Ray, Holly B [ORNL] [ORNL; Cook, Tyler S [ORNL] [ORNL; Bilheux, Hassina Z [ORNL] [ORNL

2014-01-01T23:59:59.000Z

75

Hydride embrittlement in ZIRCALOY-4 plate; Part 2: Interaction between the tensile stress and the hydride morphology  

SciTech Connect (OSTI)

The effect of an applied tensile stress on the hydrides morphology in ZIRCALOY-4 was studied. To this end, the residual stresses around the hydride caused by the hydride precipitation was first evaluated. Considering the disability to predict hydride transformation stresses by ordinary macroscopical mechanical calculation in previous studies, X-ray diffraction (XRD) profile analysis and transmission electron microscopy (TEM) observations were carried out to quantify the microstructural evolution in hydrided ZIRCALOY-4. The residual microstrains and microstresses in the matrix and around the hydride were thus estimated. The big discrepancy between the results and the existing studies were explained by the major self-accommodation of phase transformation deformation remaining inside the hydrides and the local plastic accommodation of ZIRCALOY-4. In order to study the stress effect on hydride orientation and to estimate the hydride orientation threshold stresses, hydrogen was introduced into the specimens under tensile stress. A quantitative technique was used to evaluate the susceptibility to perpendicular hydride formation under the influence of texture, residual stresses, and externally applied tensile stresses, following an improved approach that had been first developed by Sauthoff and then applied to Zr-H system by Puls. Both analytical and experimental results indicate that the threshold stress for producing perpendicular hydrides varies with the microstructural features, the yield strength, and the residual stresses.

Bai, J.B.; Prioul, C.; Francois, D. (Ecole Centrale Paris, Chatenay-Malabry (France)); Ji, N. (ENSAM, Paris (France)); Gilbon, D. (C.E.N. Saclay, Gif-sur-Yvette (France))

1994-06-01T23:59:59.000Z

76

Intense multimicrojoule high-order harmonics generated from neutral atoms of In{sub 2}O{sub 3} nanoparticles  

SciTech Connect (OSTI)

We studied high-order harmonic generation from plasma that contains an abundance of indium oxide nanoparticles. We found that harmonics from nanoparticle-containing plasma are considerably more intense than from plasma produced on the In{sub 2}O{sub 3} bulk target, with high-order harmonic energy ranging from 6 {mu}J (for the ninth harmonic) to 1 {mu}J (for the 17th harmonic) in the former case. The harmonic cutoff from nanoparticles was at the 21st order, which is lower than that observed using indium oxide solid target. By comparing the harmonic spectra obtained from solid and nanoparticle indium oxide targets, we concluded that intense harmonics in the latter case are dominantly generated from neutral atoms of the In{sub 2}O{sub 3} nanoparticles.

Elouga Bom, L. B.; Abdul-Hadi, J.; Vidal, F.; Ozaki, T. [Centre Energie, Materiaux et Telecommunications, Institut National de la Recherche Scientifique, 1650 Lionel-Boulet, Varennes, Quebec J3X 1S2 (Canada); Ganeev, R. A. [Centre Energie, Materiaux et Telecommunications, Institut National de la Recherche Scientifique, 1650 Lionel-Boulet, Varennes, Quebec J3X 1S2 (Canada); Scientific Association Akadempribor, Uzbekistan Academy of Sciences, Akademgorodok, Tashkent 100125 (Uzbekistan)

2009-03-16T23:59:59.000Z

77

Enhancing and controlling single-atom high-harmonic generation spectra: a time-dependent density-functional scheme  

E-Print Network [OSTI]

High harmonic generation (HHG) provides a flexible framework for the development of coherent light sources in the extreme-ultraviolet and soft x-ray regimes. However it suffers from low conversion efficiencies as the control of the HHG spectral and temporal characteristics requires manipulating electron trajectories on attosecond time scale. The phase matching mechanism has been employed to selectively enhance specific quantum paths leading to HHG. A few important fundamental questions remain open, among those how much of the enhancement can be achieved by the single-emitter and what is the role of correlations (or the electronic structure) in the selectivity and control of HHG generation. Here we address those questions by examining computationally the possibility of optimizing the HHG spectrum of isolated Hydrogen and Helium atoms by shaping the slowly varying envelope of a 800 nm, 200-cycles long laser pulse. The spectra are computed with a fully quantum mechanical description, by explicitly computing the ...

Castro, Alberto; Gross, E K U

2014-01-01T23:59:59.000Z

78

Development of encapsulated lithium hydride thermal energy storage for space power systems  

SciTech Connect (OSTI)

Inclusion of thermal energy storage in a pulsed space power supply will reduce the mass of the heat rejection system. In this mode, waste heat generated during the brief high-power burst operation is placed in the thermal store; later, the heat in the store is dissipated to space via the radiator over the much longer nonoperational period of the orbit. Thus, the radiator required is of significantly smaller capacity. Scoping analysis indicates that use of lithium hydride as the thermal storage medium results in system mass reduction benefits for burst periods as long as 800 s. A candidate design for the thermal energy storage component utilizes lithium hydride encapsulated in either 304L stainless steel or molybdenum in a packed-bed configuration with a lithium or sodium-potassium (NaK) heat transport fluid. Key issues associated with the system design include phase-change induced stresses in the shell, lithium hydride and shell compatibility, lithium hydride dissociation and hydrogen loss from the system, void presence and movement associated with the melt-freeze process, and heat transfer limitations on obtaining the desired energy storage density. 58 refs., 40 figs., 11 tabs.

Morris, D.G.; Foote, J.P.; Olszewski, M.

1987-12-01T23:59:59.000Z

79

HYDRIDE-RELATED DEGRADATION OF SNF CLADDING UNDER REPOSITORY CONDITIONS  

SciTech Connect (OSTI)

The purpose and scope of this analysis/model report is to analyze the degradation of commercial spent nuclear fuel (CSNF) cladding under repository conditions by the hydride-related metallurgical processes, such as delayed hydride cracking (DHC), hydride reorientation and hydrogen embrittlement, thereby providing a better understanding of the degradation process and clarifying which aspects of the process are known and which need further evaluation and investigation. The intended use is as an input to a more general analysis of cladding degradation.

K. McCoy

2000-12-12T23:59:59.000Z

80

Enhancement of field generation via maximal atomic coherence prepared by fast adiabatic passage in Rb vapor  

E-Print Network [OSTI]

shift s200 MHzd. The optical path lengths for both beams are the same. The temporal be- havior of the pulses is detected by fast photodiode D3. One beam serves as the first coupling pulse and the probe pulse. The time duration of the first coupling... with opposite circular polar- izations are separated by a second l /4 wave plate and an- other polarizing beamsplitter. The transmitted first coupling pulse and probe pulse are detected by fast photodiode D1. The second coupling pulse and the generated...

Sautenkov, V. A.; Ye, C. Y.; Rostovtsev, Y. V.; Welch, George R.; Scully, Marlan O.

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Dissipative hydride precipitates in superconducting niobium cavities  

SciTech Connect (OSTI)

We report the first direct observation of the microstructural features exhibiting RF losses at high surface magnetic fields of above 100 mT in field emission free superconducting niobium cavities. The lossy areas were identified by advanced thermometry. Surface investigations using different techniques were carried out on cutout samples from lossy areas and showed the presence of dendritic niobium hydrides. This finding has possible implications to the mechanisms of RF losses in superconducting niobium at all field levels.

Romanenko, A.; Cooley, L.D.; /Fermilab; Ciovati, G.; / /Jefferson Lab; Wu, G.; /Argonne

2011-10-01T23:59:59.000Z

82

METAL HYDRIDE HYDROGEN COMPRESSORS: A REVIEW  

SciTech Connect (OSTI)

Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine the metal hydride material itself should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage, hydrogen sorption kinetics and effective thermal conductivity), the thermodynamics of the metal-hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimized to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors, reduction of slope of the isotherms and hysteresis, increase of cycling stability and life time, together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation. The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal-hydrogen systems suitable for the hydrogen compression; and (b) applied aspects, including their consideration from the applied thermodynamic viewpoint, system design features and performances of the metal hydride compressors and major applications.

Bowman Jr, Robert C [ORNL] [ORNL; Yartys, Dr. Volodymyr A. [Institute for Energy Technology (IFE)] [Institute for Energy Technology (IFE); Lototskyy, Dr. Michael V [University of the Western Cape, South Africa] [University of the Western Cape, South Africa; Pollet, Dr. B.G. [University of the Western Cape, South Africa

2014-01-01T23:59:59.000Z

83

Proposed Virtual Center for Excellence for Metal Hydride Development...  

Broader source: Energy.gov (indexed) [DOE]

Virtual Center for Excellence for Metal Hydride Development Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC....

84

Mathematical modelling of a metal hydride hydrogen storage system.  

E-Print Network [OSTI]

??In order for metal hydride hydrogen storage systems to compete with existing energy storage technology, such as gasoline tanks and batteries, it is important to… (more)

MacDonald, Brendan David

2009-01-01T23:59:59.000Z

85

E-Print Network 3.0 - americium hydrides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and complete processing... facility for hydride research 12;BNL Current Research in Hydrogen Storage Complex metal hydride ... Source: DOE Office of Energy Efficiency and...

86

LANL/PNNL Virtual Center for Chemical Hydrides and New Concepts...  

Broader source: Energy.gov (indexed) [DOE]

LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage...

87

E-Print Network 3.0 - argon hydrides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Polytechnique, Centre de mathmatiques Collection: Mathematics 4 Complex Hydrides for Hydrogen Storage Darlene K. Slattery and Michael D. Hampton Summary: Complex Hydrides for...

88

Nano-engineering of magnesium hydride for hydrogen storage  

Science Journals Connector (OSTI)

The destabilization of magnesium hydride (MgH"2) by solid-state reaction with Si in a nanoscale under vacuum was studied. The nanostructured Si films were deposited on the nanocrystalline MgH"2/Mg composite substrate by the pulsed laser deposition (PLD). ... Keywords: Destabilization, Magnesium hydride, Microstructure, Nano-engineering, Silicon

J. Bystrzycki; T. P?oci?ski; W. Zieli?ski; Z. Winiewski; M. Polanski; W. Mróz; Z. Bojar; K. J. Kurzd?owski

2009-04-01T23:59:59.000Z

89

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of  

Broader source: Energy.gov (indexed) [DOE]

Neutron Irradiation of Hydrided Cladding Material in HFIR Summary Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities Irradiation is known to have a significant impact on the properties and performance of Zircaloy cladding and structural materials (material degradation processes, e.g., effects of hydriding). This UFD study examines the behavior and performance of unirradiated cladding and actual irradiated cladding through testing and simulation. Three capsules containing hydrogen-charged Zircaloy-4 cladding material have been placed in the High Flux Isotope Reactor (HFIR). Irradiation of the capsules was conducted for post-irradiation examination (PIE) metallography. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of

90

Recent advances in metal hydrides for clean energy applications  

SciTech Connect (OSTI)

Metal hydrides are a fascinating class of materials that can be utilized for a surprising variety of clean energy applications, including smart solar collectors, smart windows, sensors, thermal energy storage, and batteries, in addition to their traditional application for hydrogen storage. Over the past decade, research on metal hydrides for hydrogen storage increased due to global governmental incentives and an increased focus on hydrogen storage research for polymer electrolyte membrane fuel cell operation. Tremendous progress has been made in so-called complex metal hydrides for hydrogen storage applications with the discovery of many new hydrides containing covalently bound complex anions. Many of these materials have applications beyond hydrogen storage and are being investigated for lithium-ion battery separator and anode materials. In this issue of MRS Bulletin , we present the state of the art of key evolving metal-hydride-based clean energy technologies with an outlook toward future needs.

Ronnebro, Ewa; Majzoub, Eric H.

2013-06-01T23:59:59.000Z

91

Porous metal hydride composite and preparation and uses thereof  

DOE Patents [OSTI]

A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

Steyert, W.A.; Olsen, C.E.

1980-03-12T23:59:59.000Z

92

Porous metal hydride composite and preparation and uses thereof  

DOE Patents [OSTI]

A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

Steyert, William A. (Los Alamos, NM); Olsen, Clayton E. (Los Alamos, NM)

1982-01-01T23:59:59.000Z

93

Metal hydride fuel storage and method thereof  

DOE Patents [OSTI]

An apparatus having a first substrate having (1) a cavity, (2) one or more resistive heaters, and (3) one or more coatings forming a diffusion barrier to hydrogen; a second substrate having (1) an outlet valve comprising a pressure relief structure and (2) one or more coatings forming a diffusion barrier to hydrogen, wherein said second substrate is coupled to said first substrate forming a sealed volume in said cavity; a metal hydride material contained within said cavity; and a gas distribution system formed by coupling a microfluidic interconnect to said pressure relief structure. Additional apparatuses and methods are also disclosed.

Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

2010-08-10T23:59:59.000Z

94

Anisotropic behavior and rupture of hydrided Zircaloy-4 sheets  

SciTech Connect (OSTI)

In a French pressurized water reactor (PWR), most of the structural parts of the fuel assembly consist of zirconium alloys (ZIRCALOY-2). The mechanical behavior of ZIRCALOY-4 sheets is investigated at room temperature. The effect of hydride precipitation on the mechanical behavior and on the rupture mechanism is also studied, in the range from 200 to 1,200 wt ppm hydrogen and for different stress triaxialities. It is shown that the material exhibits a strong anisotropy die to its pronounced texture, and that its mechanical properties depend on the strain rate. Hydride precipitation appears to have no effect on the anisotropy or on the strain-rate sensitivity, in the range from 10{sup {minus}4} to 10{sup {minus}2} s{sup {minus}1}. The main effect of hydrogen is the reduction of the ductility and of crack resistance. The ductile rupture mechanism is studied, focusing on the stage of damage nucleation by hydride fracture. Observations during scanning electron microscopy (SEM) in situ tests show that hydrides allow the transmission of slip, which occurs in ZIRCALOY-4 grains. Hydrides can also deform, together with surrounding zirconium matrix. Damage appears after a plastic-strain yield of about 14 to 25 pct. Fracture occurs first on intergranular hydrides. Fracture of transgranular hydrides is observed only prior to failure, for higher plastic strains.

Grange, M.; Besson, J.; Andrieu, E.

2000-03-01T23:59:59.000Z

95

OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES  

SciTech Connect (OSTI)

Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

2011-07-14T23:59:59.000Z

96

Chemical Hydride Slurry for Hydrogen Production and Storage  

SciTech Connect (OSTI)

The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: • Magnesium hydride slurry is stable for months and pumpable. • The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. • Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. • The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. • The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (“Milk of Magnesia”) and magnesium oxide. • We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

McClaine, Andrew W.

2008-09-30T23:59:59.000Z

97

Process for production of a metal hydride  

DOE Patents [OSTI]

A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

2014-08-12T23:59:59.000Z

98

Novel Hydride Transfer Catalysis for Carbohydrate Conversions  

SciTech Connect (OSTI)

5-Hydroxymethylfurfural (HMF), an important versatile sugar derivative has been synthesized from glucose using catalytic amounts of CrCl2 in 1-ethyl-3-methylimidizolium chloride. Glycerol and glyceraldehyde were tested as sugar model compounds. Glycerol is unreactive and does not interfere with glucose conversion. Glyceraldehyde is reactive and does interfere with glucose conversion in competitive experiments. MnCl2 or FeCl2 catalyze dehydration of glyceraldehyde dimer to form compound I, a cyclic hemiacetal with an exocyclic double bond. Upon aqueous work-up I forms pyruvaldehyde. CrCl2 or VCl3 further catalyze a hydride transfer of I to form lactide. Upon aqueous work-up lactide is converted to lactic acid.

Holladay, John E.; Brown, Heather M.; Appel, Aaron M.; Zhang, Z. Conrad

2008-04-03T23:59:59.000Z

99

Steps to Commercialization: Nickel Metal Hydride Batteries | Department of  

Broader source: Energy.gov (indexed) [DOE]

Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries October 17, 2011 - 10:42am Addthis Steps to Commercialization: Nickel Metal Hydride Batteries Matthew Loveless Matthew Loveless Data Integration Specialist, Office of Public Affairs How does it work? Through licensing and collaborative work, Energy Department-sponsored research can yield great economic benefits and help bring important new products to market. The Energy Department funds cutting-edge research on a broad range of topics ranging from advanced battery construction to the modeling of industrial processes and supercomputer simulation of supernovae. But this research is not only about furthering our understanding of the world around

100

Metal Hydride Chemical Heat Pumps for Industrial Use  

E-Print Network [OSTI]

Hydriding alloys are intermetallic absorbent compounds which have the remarkable quality of absorbing very large quantities of hydrogen gas per unit volume of metallic powder. The absorption and desorption of hydrogen are exothermic and endothermic...

Ally, M. R.; Rebello, W. J.; Rosso, M. J., Jr.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

High capacity stabilized complex hydrides for hydrogen storage  

DOE Patents [OSTI]

Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

2014-11-11T23:59:59.000Z

102

Delayed hydride cracking behavior for ZIRCALOY-2 tubing  

Science Journals Connector (OSTI)

The delayed hydride cracking (DHC) behavior for ZIRCALOY-2 tubing was characterized at temperatures ranging from 93 °C to 288 °C. Testing was performed on the three types of pressure tubes that were used in th...

F. H. Huang; W. J. Mills

1991-09-01T23:59:59.000Z

103

Development of a metal hydride electrode waste treatment process  

SciTech Connect (OSTI)

Manufacturing residues of metal hydride electrodes for nickel - metal hydride batteries were chemically processed to recover the metal part and heat treated for the organic part. Chemical recovery yielded Ni-Co alloy after electrolysis of the solution and hydroxides of other metal, mainly rare earths. The organic part, pyrolyzed at 700 C, led to separation between carbon and fluorinated matter. Infrared coupling at the output of the pyrolysis furnace was used to identify the pyrolysis gases.

Bianco, J.C.; Martin, D.; Ansart, F.; Castillo, S.

1999-12-01T23:59:59.000Z

104

Development of the Low-Pressure Hydride/Dehydride Process  

SciTech Connect (OSTI)

The low-pressure hydride/dehydride process was developed from the need to recover thin-film coatings of plutonium metal from the inner walls of an isotope separation chamber located at Los Alamos and to improve the safety operation of a hydride recovery process using hydrogen at a pressure of 0.7 atm at Rocky Flats. This process is now the heart of the Advanced Recovery and Integrated Extraction System (ARIES) project.

Rueben L. Gutierrez

2001-04-01T23:59:59.000Z

105

OBSERVATIONS IN REACTIVITY BETWEEN BH CONTAINING COMPOUNDS AND ORGANOMETALLIC REAGENTS: SYNTHESIS OF BORONIC ACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES  

E-Print Network [OSTI]

Reaction of BH 3 :THF with magnesium hydride byproduct. A.It was also observed that magnesium hydride can partiallyACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES A dissertation

Clary, Jacob William

2012-01-01T23:59:59.000Z

106

Synthesis and characterization of metal hydride/carbon aerogel composites for hydrogen storage  

Science Journals Connector (OSTI)

Two materials currently of interest for onboard lightweight hydrogen storage applications are sodium aluminum hydride (NaAlH4), a complex metal hydride, and carbon aerogels (CAs), a light porous material connected by several spherical nanoparticles. ...

Kuen-Song Lin; Yao-Jen Mai; Su-Wei Chiu; Jing-How Yang; Sammy L. I. Chan

2012-01-01T23:59:59.000Z

107

Characterization and High Throughput Analysis of Metal Hydrides for Hydrogen Storage  

E-Print Network [OSTI]

Metal Hydrides for Hydrogen Storage by Steven James BarceloMetal Hydrides for Hydrogen Storage by Steven James BarceloCo-chair Efficient hydrogen storage is required for fuel

Barcelo, Steven James

2009-01-01T23:59:59.000Z

108

Opening of a Post Doctoral Position Complex hydrides for hydrogen storage applications  

E-Print Network [OSTI]

Opening of a Post Doctoral Position Complex hydrides for hydrogen storage applications on complex hydrides for hydrogen storage applications in connection with the « Fast, reliable and cost effective boron hydride based high capacity solid state hydrogen storage materials» project co

109

Very-high-order harmonic generation from Ar atoms and Ar+ ions in superintense pulsed laser fields: An ab initio self-interaction-free time-dependent density-functional approach  

E-Print Network [OSTI]

We present an ab initio nonpertubative investigation of the mechanisms responsible for the production of very-high-order harmonic generation (HHG) from Ar atoms and Ar+ ions by means of the self-interaction-free time-dependent density...

Carrera, Juan J.; Chu, Shih-I; Tong, X. M.

2005-06-21T23:59:59.000Z

110

Final Report for the DOE Metal Hydride Center of Excellence  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SANDIA REPORT SANDIA REPORT SAND2012-0786 Unlimited Release Printed February 2012 Final Report for the DOE Metal Hydride Center of Excellence Lennie Klebanoff Director, Metal Hydride Center of Excellence Jay Keller Deputy Director, Metal Hydride Center of Excellence Prepared by Sandia National Laboratories Albuquerque, New Mexico 87185 and Livermore, California 94550 Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Approved for public release; further dissemination unlimited. Issued by Sandia National Laboratories, operated for the United States Department of Energy

111

Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.  

SciTech Connect (OSTI)

In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

2012-02-01T23:59:59.000Z

112

14 - Hydrogen storage in hydride-forming materials  

Science Journals Connector (OSTI)

Abstract: Hydrogen storage technologies are playing a significant and critical role in the so-called ‘hydrogen economy’: they are used to buffer primary energy sources for time-delayed end-uses. The purpose of this chapter is to review the main hydrogen storage processes and materials, with a special emphasis on chemical storage (metal and chemical hydrides). First, the main hydrogen processes (physical, chemical, electrochemical, geological) are reviewed. Then, reversible hydrogen storage in hydride-forming metals and intermetallics is discussed. Basic principles (thermodynamic properties, sorption mechanisms, kinetics) are presented and the properties of the main materials are listed and compared. Irreversible hydrogen storage in the main classes of chemical hydrides is then described. In the last section, specifications for automotive and stationary applications are reviewed and discussed.

P. Millet

2014-01-01T23:59:59.000Z

113

Brittle fracture induced by hydrides in zircaloy-4  

SciTech Connect (OSTI)

Zircaloy-4 is used as a cladding material in the nuclear industry for fuel elements. Its mechanical properties can be drastically affected by the presence of hydrides, which form when hydrogen content exceeds the terminal solid solubility. This change often manifests itself as a reduction in ductility (elongation and reduction in area), coupled with the evolution of the fracture mode from ductile microvoid nucleation and coalescence to intergranular fracture. It has been found, at room temperature, that Zircaloy-4 undergoes a ductile to brittle transition when the hydrogen content (hydride volume fraction) in the specimen is higher than some critical value depending on the microstructure and the hydride morphology. Heat treatment of the material can shift the transition end point from 1050 ppm wt H for the stress-relieved state to 100-150 ppm wt H for the {beta} treated state, thus strongly suggesting that there may be some relationship between the microstructure (grain size and shape) and the ductile-brittle transition. It has also been reported that for the same hydriding condition, the hydrogen absorption rate is higher for the stress-relieved and recrystallized states and lower for the {beta} treated state. This phenomenon is very important for engineering applications because it is related to the determination of the safe life. Insufficient attention has been drawn to the quantitative evaluation and the modelization of the influence of the microstructure on the ductile-brittle transition in hydrided Zircaloy-4, though there has been some general research on the boundary structural effect on intergranular fracture. The present authors attempt to modelize this influence by an upper-limit model using the results of image analysis on the microstructures and tensile tests on hydrided sheet specimens.

Bai, J.B.; Francois, D.; Prioul, C. (Lab. MSS/MAT CNRS URA 850, Ecole Centrale Paris, 92295 Chatenay Malabry Cedex (FR)); Lansiart, S. (CEA/DTA/CEREM/DTM/SRMA, C.E. Saclay, 91191 Gif-sur-Yvette Cedex (FR))

1991-11-01T23:59:59.000Z

114

X-RAY ABSORPTION SPECTROSCOPY OF TRANSITION METAL-MAGNESIUM HYDRIDE FILMS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy of Transition Metal-Magnesium Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardson a, *, B. Farangis a , J. L. Slack a , P. Nachimuthu b , R. Pereira b , N. Tamura b , and M. Rubin a a Environmental Energy Technologies Division, b Advanced Light Source, Ernest Orlando Lawrence Berkeley National Laboratory Berkeley, California 94720, USA *Corresponding author, E-mail address: tjrichardson@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large changes in both reflectance and transmittance on exposure to hydrogen gas. Changes in electronic structure and coordination of the magnesium and transition metal atoms during hydrogen absorption were studied using dynamic in situ transmission mode X-ray absorption

115

FeP precipitates in hydride?vapor phase epitaxially grown InP:Fe  

Science Journals Connector (OSTI)

Fe?doped InP was grown by hydride?vapor phase epitaxy.Doping levels up to 8×1018 cm?3 were determined by secondary ion mass spectrometry. Additionally performed photoluminescence measurements revealed a homogeneous distribution of electrically active Fe atoms. From microstructural investigations by analytical transmission electron microscopy spherical?shaped precipitates were detected in plan?view samples. These precipitates with diameters up to 13 nm are homogeneously arranged in the epilayer. For conglomerates of precipitates a distinct enrichment with Fe and P was measured by a comparative energy dispersive x?ray analysis. The lattice plane distances of the precipitates were deduced from the electron diffraction patterns and from high?resolution electron micrographs. A comparison with calculated values for different Fe–P alloys indicates that the precipitates consist mainly of orthorhombic FeP.

M. Luysberg; R. Göbel; H. Janning

1994-01-01T23:59:59.000Z

116

Effect of radial hydrides on the axial and hoop mechanical properties of Zircaloy-4 cladding  

Science Journals Connector (OSTI)

The effect of radial hydrides on the mechanical properties of stress-relief annealed Zircaloy-4 cladding was studied. Specimens were firstly hydrided to different target hydrogen levels between 100 and 600 wt ppm and then thermally cycled in an autoclave under a constant hoop stress to form radial hydrides by a hydride reorientation process. The effect of radial hydrides on the axial properties of the cladding was insignificant. On the other hand, the cladding ductility measurements decreased as its radial hydride content increased when the specimen was tested in plane strain tension. A reference hydrogen concentration for radial hydrides in the cladding was defined for assessing the fuel cladding integrity based on a criterion of the tensile strength 600 MPa. The reference hydrogen concentration increased with the specimen (bulk) hydrogen concentration to a maximum of ?90 wt ppm at the bulk concentration ?300 wt ppm H and then decreased towards higher concentrations.

H.C. Chu; S.K. Wu; K.F. Chien; R.C. Kuo

2007-01-01T23:59:59.000Z

117

Process of forming a sol-gel/metal hydride composite  

DOE Patents [OSTI]

An external gelation process is described which produces granules of metal hydride particles contained within a sol-gel matrix. The resulting granules are dimensionally stable and are useful for applications such as hydrogen separation and hydrogen purification. An additional coating technique for strengthening the granules is also provided.

Congdon, James W. (Aiken, SC)

2009-03-17T23:59:59.000Z

118

HYDROGEN STORAGE USINGHYDROGEN STORAGE USING COMPLEX HYDRIDESCOMPLEX HYDRIDES  

E-Print Network [OSTI]

, Michael D. HamptonDarlene K. Slattery, Michael D. Hampton FL Solar Energy Center, U. of Central FLFL Solar Energy Center, U. of Central FL #12;Objective · Identify a hydrogen storage system that meets the DOEHYDROGEN STORAGE USINGHYDROGEN STORAGE USING COMPLEX HYDRIDESCOMPLEX HYDRIDES Darlene K. Slattery

119

Design of a rural water provision system to decrease arsenic exposure in Bangladesh  

E-Print Network [OSTI]

Hydride Generation Atomic Absorption Spectrophotomery (HG-Graphite Furnace Atomic Absorption Spectrometry (GF-Graphite Furnace - Atomic Absorption Spectroscopy (GF-AAS),

Mathieu, Johanna

2009-01-01T23:59:59.000Z

120

Microstructural study by XRD profile analysis and TEM observations on hydrided recrystallized Zircaloy-4  

SciTech Connect (OSTI)

Zircaloy-4, used as cladding tube material in the nuclear reactors, may become brittle due to the precipitation of hydrides. During hydride formation, the anisotropic misfit strains between hydrides and the hexagonal-close-packed zirconium matrix results in a preferred orientation of the hydride platelets in the anisotropic stress field caused by non-relieved fabrication residual stresses and misfit stresses. To understand the mechanism of rupture and to predict the threshold stresses for hydride stress orientation, it is necessary to study the residual stresses, especially the microstrain caused by crystalline lattice misfit, in a hydrided specimen. The X-ray diffraction profile analysis is very sensitive to all the microstructure evolution in metallic materials. It is a non-destructive and voluminal technique compared with transmission electron microscope observation. The XRD peak broadening can be related closely with the microstrain in case of hydrided Zircaloy-4, because the hydride formation creates in general a great number of dislocations which contributes especially to the diminution of coherent domain size and to the increase of microstrain. To calibrate the internal microstrain due to precipitation effect of hydrided specimens, XRD profile analysis has also been realized on the non-hydrided specimens deformed by uniaxial tension. In this paper the authors restrict to analyzing the results about the recrystallized state, because more informations about the anisotropic elasticity, plasticity, thermal expansion, neutron diffraction measurement and the crystallographic texture results are available.

Bai, J.B. (Lab. MSS/MAT, CNRS URA 850, Ecole Centrale Paris, 92295 Chatenay Malabry Cedex (FR)); Gilbon, D. (LM3, CNRS URA 1219, ENSAM, 151 Bd. de l'Hopital, 75013 Paris (FR)); Lebrun, J.L. (CEA/DTA/CEREM/DTM/SRMA, C.E. Saclay, 91191 Gif-sur-Yvette Cedex (FR))

1992-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL  

SciTech Connect (OSTI)

The objective of this DOE NERI program sponsored project was to assess the feasibility of improving the plutonium (Pu) and minor actinide (MA) recycling capabilities of pressurized water reactors (PWRs) by using hydride instead of oxide fuels. There are four general parts to this assessment: 1) Identifying promising hydride fuel assembly designs for recycling Pu and MAs in PWRs 2) Performing a comprehensive systems analysis that compares the fuel cycle characteristics of Pu and MA recycling in PWRs using the promising hydride fuel assembly designs identified in Part 1 versus using oxide fuel assembly designs 3) Conducting a safety analysis to assess the likelihood of licensing hydride fuel assembly designs 4) Assessing the compatibility of hydride fuel with cladding materials and water under typical PWR operating conditions Hydride fuel was found to offer promising transmutation characteristics and is recommended for further examination as a possible preferred option for recycling plutonium in PWRs.

Greenspan, Ehud; Todreas, Neil; Taiwo, Temitope

2009-03-10T23:59:59.000Z

122

Preparation and X-Ray diffraction studies of curium hydrides  

SciTech Connect (OSTI)

Curium hydrides were prepared by reaction of curium-248 metal with hydrogen and characterized by X-ray powder diffraction. Several of the syntheses resulted in a hexagonal compound with average lattice parameters of a/sub 0/ = 0.3769(8) nm and c/sub 0/ = 0.6732(12) nm. These products are considere to be CmH/sub 3//sup -//sub 8/ by analogy with the behavior of lanthanide-hydrogen and lighter actinide-hydrogen systems. Face-centered cubic products with an average lattice parameter of a/sub 0/ = 0.5322(4) nm were obtained from other curium hydride preparations. This parameter is slightly smaller than that reported previously for cubic curium dihydride, CmH /SUB 2-x/ (B.M. Bansal and D. Damien. Inorg. Nucl. Chem. Lett. 6 603, 1970). The present results established a continuation of typical heavy trivalent lanthanidelike behavior of the transuranium actinide-hydrogen systems through curium.

Gibson, J.K.; Maire, R.G.

1985-10-01T23:59:59.000Z

123

Behavior and rupture of hydrided Zircaloy-4 tubes and sheets  

SciTech Connect (OSTI)

Zirconium alloys are used as structural parts in the nuclear fuel assembly. The mechanical behavior and rupture mechanisms of ZIRCALOY-4 guide tubes and sheet containing 150 to 1,200 wt ppm hydrogen have been investigated at room temperature. Sheets were notched to study the influence of geometrical defects on rupture. It is shown that hydrides strengthened the material, as maximum stresses sustained by the material are increased with increasing hydrogen contents. On the other hand, ductility is reduced. The material also exhibits a strong anisotropy due to its pronounced texture. Metallographic examinations have shown that damage by hydride cracking is a continuous process that starts after the onset of necking. Notches reduce ductility. A modified Gurson-Tvergaard model was used to represent the material behavior and rupture. Numerical simulation using the finite element method demonstrates the strong influence of plastic anisotropy on the behavior of structures and rupture modes.

Prat, F.; Besson, J. [Ecole des Mines de Paris, Evry (France); Grange, M. [Framatome Nuclear Fuel, Lyon (France); Andrieu, E. [ENSCT, Toulouse (France). Lab. Materiaux

1998-06-01T23:59:59.000Z

124

Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis  

E-Print Network [OSTI]

A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

Tomas Roubicek; Giuseppe Tomassetti

2013-09-12T23:59:59.000Z

125

Electrochromically switched, gas-reservoir metal hydride devices with  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrochromically switched, gas-reservoir metal hydride devices with Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows Title Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows Publication Type Journal Article LBNL Report Number LBNL-1089E Year of Publication 2008 Authors Anders, André, Jonathan L. Slack, and Thomas J. Richardson Journal Thin Solid Films Volume 1 Date Published 08/2003 Call Number LBNL-1089E Abstract Proof-of-principle gas-reservoir MnNiMg electrochromic mirror devices have been investigated. In contrast to conventional electrochromic approaches, hydrogen is stored (at low concentration) in the gas volume between glass panes of the insulated glass units (IGUs). The elimination of a solid state ion storage layer simplifies the layer stack, enhances overall transmission, and reduces cost. The cyclic switching properties were demonstrated and system durability improved with the incorporation a thin Zr barrier layer between the MnNiMg layer and the Pd catalyst. Addition of 9% silver to the palladium catalyst further improved system durability. About 100 full cycles have been demonstrated before devices slow considerably. Degradation of device performance appears to be related to Pd catalyst mobility, rather than delamination or metal layer oxidation issues originally presumed likely to present significant challenges.

126

Electrical Properties of Hydrides and Deuterides of Zirconium  

Science Journals Connector (OSTI)

Electrical properties of hydrides and deuterides of zirconium have been investigated between 1.1 and 410°K. The metallic nature of these materials is evident in the fact that for compositions approaching ZrH2, the hydride is a better conductor than is high-purity zirconium. Above ?150°K the electrical resistivity exhibits an interesting upturn, which arises from scattering from the optical-model lattice vibrations. Excellent fits to the ideal-resistivity data are obtained with a simple additive combination of Grüneisen and Howarth-Sondheimer functions for the respective acoustical- and optical-mode scattering contributions. The corresponding acoustical- and optical-mode characteristic temperatures are in good accord with expectations based on earlier inelastic neutron scattering data. Moreover, the optical-mode characteristic temperature exhibits the expected hydride-deuteride isotope shift of 2. The observed Hall coefficients are large in magnitude (much greater than for pure Zr), and indicate majority hole conduction for the fcc ? phase and majority electron conduction for the face-centered tetragonal ? phase. The thermoelectric power also changes from positive to negative with increasing hydrogen concentration in the range ZrH1.5-ZrH2.

P. W. Bickel and T. G. Berlincourt

1970-12-15T23:59:59.000Z

127

LANL/PNNL Virtual Center for Chemical Hydrides and New Concepts...  

Broader source: Energy.gov (indexed) [DOE]

LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage * Thermodynamics * Kinetics * Recycle * WeightVolume Capacity * Durability Investigate...

128

E-Print Network 3.0 - annulus metal hydride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Introduction Metal hydride applications span a wide variety of tech nologies eg energy conversion... chemical compressors and hydrogen storage A knowledge of heat and...

129

Thermodynamics of metal hydrides for hydrogen storage applications using first principles calculations.  

E-Print Network [OSTI]

??Metal hydrides are promising candidates for H2 storage, but high stability and poor kinetics are the important challenges which have to be solved for vehicular… (more)

Kim, Ki Chul

2010-01-01T23:59:59.000Z

130

Influence of an oxide layer on the hydride embrittlement in Zircaloy-4  

SciTech Connect (OSTI)

Hydrid embrittlement of zirconium and its alloy has been studied extensively. The common techniques used to hydride the specimens are electro-chemical and gaseous ones. During this operation, especially for cases of long duration, an oxide layer would form on the surface of specimens. The present paper reports on some evidence for the influence of this layer on the hydride embrittlement in Zircaloy-4. Tensile tests with or without this layer were performed on hydrided specimens. Metallographic and fractographic analyses were carried out in order to examine the fracture nature of this layer. An analysis based on the fracture mechanics was also proposed.

Bai, J.B. (Ecole Centrale de Paris, Chatenay Malabry (France). Lab. MSS/MAT)

1993-09-01T23:59:59.000Z

131

The Universe Adventure - Atoms  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Matter and Atoms Matter and Atoms Richard Feynman "If, in some cataclysm, all of scientific knowledge were to be destroyed, and only one sentence passed on to the next generations of creatures, what statement would contain the most information in the fewest words? I believe it is that...all things are made of atoms." -Richard P. Feynman, winner of the 1965 Nobel Prize in Physics All is atoms Matter is made of atoms, and atoms are comprised of protons, neutrons, and electrons. Everything in the Universe is made of matter. Though matter exists in many different forms, each form is made out of the same basic constituents: small particles called atoms. Atoms themselves are made of smaller particles: protons, neutrons, and electrons. Protons and neutrons are composed of even smaller particles called quarks.

132

The affect of erbium hydride on the conversion efficience to accelerated protons from ultra-shsort pulse laser irradiated foils  

SciTech Connect (OSTI)

This thesis work explores, experimentally, the potential gains in the conversion efficiency from ultra-intense laser light to proton beams using erbium hydride coatings. For years, it has been known that contaminants at the rear surface of an ultra-intense laser irradiated thin foil will be accelerated to multi-MeV. Inertial Confinement Fusion fast ignition using proton beams as the igniter source requires of about 10{sup 16} protons with an average energy of about 3MeV. This is far more than the 10{sup 12} protons available in the contaminant layer. Target designs must include some form of a hydrogen rich coating that can be made thick enough to support the beam requirements of fast ignition. Work with computer simulations of thin foils suggest the atomic mass of the non-hydrogen atoms in the surface layer has a strong affect on the conversion efficiency to protons. For example, the 167amu erbium atoms will take less energy away from the proton beam than a coating using carbon with a mass of 12amu. A pure hydrogen coating would be ideal, but technologically is not feasible at this time. In the experiments performed for my thesis, ErH{sub 3} coatings on 5 {micro}m gold foils are compared with typical contaminants which are approximately equivalent to CH{sub 1.7}. It will be shown that there was a factor of 1.25 {+-} 0.19 improvement in the conversion efficiency for protons above 3MeV using erbium hydride using the Callisto laser. Callisto is a 10J per pulse, 800nm wavelength laser with a pulse duration of 200fs and can be focused to a peak intensity of about 5 x 10{sup 19}W/cm{sup 2}. The total number of protons from either target type was on the order of 10{sup 10}. Furthermore, the same experiment was performed on the Titan laser, which has a 500fs pulse duration, 150J of energy and can be focused to about 3 x 10{sup 20} W/cm{sup 2}. In this experiment 10{sup 12} protons were seen from both erbium hydride and contaminants on 14 {micro} m gold foils. Significant improvements were also observed but possibly because of the depletion of hydrogen in the contaminant layer case.

Offermann, D

2008-09-04T23:59:59.000Z

133

Production of Hydrogen by Electrocatalysis: Making the H-H Bond by Combining Protons and Hydrides  

SciTech Connect (OSTI)

Generation of hydrogen by reduction of two protons by two electrons can be catalysed by molecular electrocatalysts. Determination of the thermodynamic driving force for elimination of H2 from molecular complexes is important for the rational design of molecular electrocatalysts, and allows the design of metal complexes of abundant, inexpensive metals rather than precious metals (“Cheap Metals for Noble Tasks”). The rate of H2 evolution can be dramatically accelerated by incorporating pendant amines into diphosphine ligands. These pendant amines in the second coordination sphere function as protons relays, accelerating intramolecular and intermolecular proton transfer reactions. The thermodynamics of hydride transfer from metal hydrides and the acidity of protonated pendant amines (pKa of N-H) contribute to the thermodynamics of elimination of H2; both of the hydricity and acidity can be systematically varied by changing the substituents on the ligands. A series of Ni(II) electrocatalysts with pendant amines have been developed. In addition to the thermochemical considerations, the catalytic rate is strongly influenced by the ability to deliver protons to the correct location of the pendant amine. Protonation of the amine endo to the metal leads to the N-H being positioned appropriately to favor rapid heterocoupling with the M-H. Designing ligands that include proton relays that are properly positioned and thermodynamically tuned is a key principle for molecular electrocatalysts for H2 production as well as for other multi-proton, multi-electron reactions important for energy conversions. The research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for DOE.

Bullock, R. Morris; Appel, Aaron M.; Helm, Monte L.

2014-03-25T23:59:59.000Z

134

Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices  

SciTech Connect (OSTI)

An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

2014-11-18T23:59:59.000Z

135

Hydride blisters Formation, Characterization and Effect on the Fracture of Zircaloy-4 Cladding Tubes Under Reactivity Initiated  

E-Print Network [OSTI]

failure in 1983[2], when an axial crack developed in a CANDU pressure tube following an array of hydride

136

Solid-State Gadolinium-Magnesium Hydride Optical Switch R. Armitage  

E-Print Network [OSTI]

-state electrochromic device. With positive polarization of the hydride electrode, the visible reflectance approaches 35 and reflecting states. Keywords: gadolinium-magnesium; electrochromic hydride; optical switching device. 2 #12;A conventional electrochromics5 . Optical switching has also been demonstrated by varying the H content

137

Hydrogen storage material and process using graphite additive with metal-doped complex hydrides  

DOE Patents [OSTI]

A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

Zidan, Ragaiy (Aiken, SC); Ritter, James A. (Lexington, SC); Ebner, Armin D. (Lexington, SC); Wang, Jun (Columbia, SC); Holland, Charles E. (Cayce, SC)

2008-06-10T23:59:59.000Z

138

Hydride precipitation and its influence on mechanical properties of notched and unnotched Zircaloy-4 plates  

Science Journals Connector (OSTI)

The hydride formation and its influence on the mechanical performance of hydrided Zircaloy-4 plates containing different hydrogen contents were studied at room temperature. For the unnotched plate samples with the hydrogen contents ranging from 25 to 850 wt. ppm, the hydrides exerted an insignificant effect on the tensile strength, while the ductility was severely degraded with increasing hydrogen content. The fracture mode and degree of embrittlement were strongly related to the hydrogen content. When the hydrogen content reached a level of 850 wt. ppm, the plate exhibited negligible ductility, resulting in almost completely brittle behavior. For the hydrided notched plate, the tensile stress concentration associated with the notch tip facilitated the hydride accumulation at the region near the notch tip and the premature crack propagation through the hydride fracture during hydriding. The final brittle through-thickness failure for this notched sample was mainly attributed to the formation of a continuous hydride network on the thickness section and the obtained very high hydrogen concentration (estimated to be 1965 wt. ppm).

Zhiyang Wang; Ulf Garbe; Huijun Li; Robert P. Harrison; Karl Toppler; Andrew J. Studer; Tim Palmer; Guillaume Planchenault

2013-01-01T23:59:59.000Z

139

Hydride-phase formation and its influence on fatigue crack propagationbehavior in a Zircaloy-4 alloy  

SciTech Connect (OSTI)

The hydride-phase formation and its influence on the fatigue behavior of a Zircaloy-4 alloy charged with hydrogen gas are investigated. First, the microstructure and fatigue crack propagation rate of the alloy in the as-received condition are studied. Second, the formation and homogeneous distribution of delta zirconium hydride ( -ZrH2) in the bulk, and its effect on the fatigue crack propagation rate are presented. The results show that in the presence of hydrides the zirconium alloy exhibits reduced toughness and enhanced crack growth rates. Finally, the influence of a pre-existing fatigue crack in the specimen and the subsequent hydride formation were investigated. The residual lattice strain profile around the fatigue crack tip was measured using neutron diffraction. The combined effects of residual strains and hydride precipitation on the fatigue behavior are discussed.

Garlea, Elena [University of Tennessee, Knoxville (UTK); Choo, H. [University of Tennessee, Knoxville (UTK); Wang, G Y [University of Tennessee, Knoxville (UTK); Liaw, Peter K [University of Tennessee, Knoxville (UTK); Clausen, B [Los Alamos National Laboratory (LANL); Brown, D. W. [Los Alamos National Laboratory (LANL); Park, Jae-Sung [University of Tennessee, Knoxville (UTK); Rack, P. D. [University of Tennessee, Knoxville (UTK); Kenik, Edward A [ORNL

2010-01-01T23:59:59.000Z

140

Getting metal-hydrides to do what you want them to  

SciTech Connect (OSTI)

With the discovery of AB/sub 5/ compounds, intermetallic hydrides with unusual properties began to be developed (H dissociation pressures of one to several atmospheres, extremely rapid and reversible adsorption/desorption very large amounts of H adsorbed). This paper reviews the factors that must be controlled in order to modify these hydrides to make them useful. The system LaNi/sub 5/ + H/sub 2/ is used as example. Use of AB/sub 5/ hydrides to construct a chemical heat pumps is discussed. Results of a systematic study substituting Al for Ni are reported; the HYCSOS pump is described briefly. Use of hydrides as hydrogen getters (substituted ZrV/sub 2/) is also discussed. Finally, possible developments in intermetallic hydride research in the 1980's and the hydrogen economy are discussed. 10 figures. (DLC)

Gruen, D.M.

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Stress-induced reorientation of hydrides and mechanical properties of Zircaloy-4 cladding tubes  

Science Journals Connector (OSTI)

Stress-induced reorientation of hydrides and its effect on the stress–strain response of Zircaloy-4 cladding tubes were investigated. The reorientation of hydrides along the radial direction was most pronounced if the tube was cooled from 300 to 200 °C under circumferential loading. Reorientation occurred much less frequently at either higher (cooled from 400 to 300 °C) or lower (cooled from 200 to 100 °C) temperature range. The population of radial hydrides in R43H7 (which was cooled from 400 to 300 °C and maintained at 300 °C for 7 h) increased drastically during annealing at 300 °C, suggesting time dependent stress-aided dissolution of circumferential hydrides and reprecipitation of radial hydrides. The drastic decrease of the strength and the complete loss of the ductility were observed in R32AC and R43H7.

S.I. Hong; K.W. Lee

2005-01-01T23:59:59.000Z

142

Designation of Sites for Remedial Action - Metal Hydrides, Beverly,  

Office of Legacy Management (LM)

T: T: Designation of Sites for Remedial Action - Metal Hydrides, Beverly, MA; Bridgeport Brass, Adrian, MI and Seymour, Chicago, IL CT; National Guard Armory, 0: Joe LaGrone, Manager Oak Ridge Operations Office Based on the attached radiological survey data (Attachments 1 through 3) and an appropriate authority review, the following properties are being authorized for remedial action. It should be noted that the attached survey data are for designation purposes only and that Bechtel National, Inc. (BNI) should conduct appropriate comprehensive characterization studies to determine the extent'and magnitude of contamination on properties. Site Location Priority Former Bridgeport Brass Co. (General Motors) Adrian, MI Low Former Bridgeport Brass Co.

143

Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications  

SciTech Connect (OSTI)

Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

2012-04-16T23:59:59.000Z

144

Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power  

SciTech Connect (OSTI)

A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

Melius, C F; Foltz, G W

1987-01-01T23:59:59.000Z

145

Synthesis, characterization and reactivity of several rhenium hydride complexes. A study of the role of metal hydrides in organometallic reactions  

SciTech Connect (OSTI)

The mechanistic role of transition metal hydrides in organometallic reactions has been studied using several low valent, electron rich rhenium complexes. The reaction ReH[sub 7](PPh[sub 3])[sub 2] with indene has been found to yield products that are [eta][sup 5]-C[sub 9]H[sub 7]ReH[sub 2](PPh[sub 3])[sub 2] and ([eta][sup 5]-C[sub 9]H[sub 11])ReH[sub 2](PPh[sub 3])[sub 2], respectively. The mechanism proposed for the formation of these two products consists of several metal to ring hydride migrations, and the activation parameters for one of the migrations have been obtained. Hydride migrations are prevalent in the subsequent chemistry of ([eta][sup 5]-C[sub 9]H[sub 11])ReH[sub 2](PPh[sub 3])[sub 2], as well as in the similar complex ([eta][sup 4]-C[sub 9]H[sub 12])ReH[sub 3](PPh[sub 3])[sub 2]. The complex ([eta][sup 4]-C[sub 4]H[sub 5]S)ReH[sub 2](PPh[sub 3])[sub 2] has been synthesized and structurally characterized in an attempt to model the interaction of thiophene with a metal hydride surface which is presumably present during typical hydrodesulfurization conditions. The thermolysis of ([eta][sup 4]-C[sub 4]H[sub 5]S)ReH[sub 2](PPh[sub 3])[sub 2] in the presence of PMe[sub 3] has been found to yield free tetrahydrothiophene and the cyclometallated Re(PMe[sub 3])[sub 4](PPH[sub 2]C[sub 6]H[sub 4]), while photolysis with excess PMe[sub 3] yields a mixture of organometallic products in which the thiophene ligand has undergone C-S bond cleavage. Products have been identified that contain an S-bound 1-butene-1-thiolate ligand, an [eta][sup 3]-allyl bound 1-butene-1-thiolate ligand, an ethylthioketene ligand and an S-bound 1-butanethiolate ligand, all of which represent the first such homogeneous transformations of thiophene. The photochemical ligand exchange reactions and the observed H/D exchange catalysis (between a deuterated solvent and a protio substrate) of CpReH[sub 2](PPh[sub 3])[sub 2] have been studied in detail.

Rosini, G.P.

1992-01-01T23:59:59.000Z

146

ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS  

SciTech Connect (OSTI)

The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

2011-07-18T23:59:59.000Z

147

Atomic magnetometer  

DOE Patents [OSTI]

An atomic magnetometer is disclosed which uses a pump light beam at a D1 or D2 transition of an alkali metal vapor to magnetically polarize the vapor in a heated cell, and a probe light beam at a different D2 or D1 transition to sense the magnetic field via a polarization rotation of the probe light beam. The pump and probe light beams are both directed along substantially the same optical path through an optical waveplate and through the heated cell to an optical filter which blocks the pump light beam while transmitting the probe light beam to one or more photodetectors which generate electrical signals to sense the magnetic field. The optical waveplate functions as a quarter waveplate to circularly polarize the pump light beam, and as a half waveplate to maintain the probe light beam linearly polarized.

Schwindt, Peter (Albuquerque, NM); Johnson, Cort N. (Albuquerque, NM)

2012-07-03T23:59:59.000Z

148

Hydride embrittlement in ZIRCALOY-4 plate; Part 1: Influence of microstructure on the hydride embrittlement in ZIRCALOY-4 at 20[degree]C and 350[degree]C  

SciTech Connect (OSTI)

The hydride embrittlement in ZIRCALOY-4 was studied at room temperature and 350 C. Sheet tensile specimens of two fabrication routes in the stress-relieved, recrystallized, and [beta]-treated states were hydrided with or without tensile stress. It was found generally that the effect on strength of increasing hydrogen content was not important. However, for the tensile tests at room temperature, there is a ductile-brittle transition when the hydrogen content is higher than a certain threshold. The prior thermomechanical treatment shifts this transition considerably. In situ scanning electron microscopy (SEM) tests, fractography, and fracture profile observations were carried out to determine the fracture micromechanisms and the microscopic processes. At 20 C, the fracture surfaces are characterized by voids and secondary cracks for low and medium hydrogen contents and by intergranular cracks and decohesion through the continuous hydride network for high hydrogen contents. This phenomenon disappears at 350 C, and the hydrogen seems to exert no more influence on the fracture micromechanism even for very high hydrogen contents (up to 1,500 wt ppm). A full-coverage model is proposed to estimate the critical hydrogen content that makes ZIRCALOY-4 totally brittle. The effect of microstructure on hydride embrittlement in different metallurgical states is thus explained according to the modeling. Special attention is devoted to relating the micromechanisms and the modeling in order to propose the possible measures needed to limit the hydride embrittlement effect.

Bai, J.B.; Prioul, C.; Francois, D. (Ecole Centrale Paris, Chatenay-Malabry (France))

1994-06-01T23:59:59.000Z

149

Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel  

Broader source: Energy.gov (indexed) [DOE]

for Simulation of Hydride Precipitation in Zr-Based Used Fuel for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities The report demonstrates a meso-scale, microstructural evolution model for simulation of zirconium hydride precipitation in the cladding of used fuels during long-term dry-storage. While the Zr-based claddings (regarded as a barrier for containment of radioactive fission products and fuel) are manufactured free of any hydrogen, they absorb hydrogen during service in the reactor. The amount of hydrogen that the cladding picks up is primarily a function of the exact chemistry and microstructure of the claddings and reactor operating conditions, time-temperature history, and

150

E-Print Network 3.0 - aluminium hydrides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Medicine 26 KV-tOOJHfe Metallurgy Department Summary: .3. Developaent of a Hydride Based Fuel Cell 32 4.4. Materials Research for Fuel Cell Application .. 33 4.5. Thin... . The...

151

Laves phase hydrogen storage alloys for super-high-pressure metal hydride hydrogen compressors  

Science Journals Connector (OSTI)

Ti-Cr- and Ti-Mn-based alloys were prepared to be low- and high-pressure stage metals for a double-stage super-high-pressure metal hydride hydrogen compressor. Their crystallographic characteristics and hydrogen

Xiumei Guo; Shumao Wang; Xiaopeng Liu; Zhinian Li; Fang Lü; Jing Mi; Lei Hao…

2011-06-01T23:59:59.000Z

152

The Safe Use of Sodium Hydride on Scale: The Process Development of a Chloropyrimidine Displacement  

Science Journals Connector (OSTI)

The Safe Use of Sodium Hydride on Scale: The Process Development of a Chloropyrimidine Displacement ... Global Pharmaceutical Commercialization, Merck Manufacturing Division, Rahway, New Jersey, 07065 ... This article is part of the Safety of Chemical Processes 11 special issue. ...

Jamie M. McCabe Dunn; Alicia Duran-Capece; Brendan Meehan; James Ulis; Tetsuo Iwama; Guy Gloor; George Wong; Evan Bekos

2011-09-30T23:59:59.000Z

153

Formation and Characterization of Hydride Blisters in Zircaloy-4 Cladding Tubes  

E-Print Network [OSTI]

in a CANDU Zircaloy-2 pressure tube along an array of hydride blisters on the external surface is the material that replaced Zircaloy-2 alloy for pressure tubes in the CANDU reactors. In all these studies

Paris-Sud XI, Université de

154

In situ x-ray absorption study of Zr(V0.29Ni0.71)3 hydride electrodes  

Science Journals Connector (OSTI)

We present an in situ x-ray absorption study of hydrogen absorption into the bulk of an electrode material while it is operating in an electrochemical cell. The active material is an overstoichiometric AB2-type alloy, namely, Zr(V0.29Ni0.71)3, with a cubic C15 Laves phase structure. Hydrogen absorption induces both structural and electronic changes due to the bonding between interstitial H atoms and each alloy element. The role of each element is revealed, allowing us to determine the inert role of Ni atoms and the dominant effect of the H-V interaction on the hydride formation process. Comparison between the alloyed element behavior and the H affinity of each pure element allows us to determine the influence of structural and alloying effects on bonding formation.

R. G. Agostino; G. Liberti; V. Formoso; E. Colavita; A. Züttel; C. Nützenadel; L. Schlapbach; A. Santaniello; C. Gauthier

2000-05-15T23:59:59.000Z

155

Photogeneration of Hydride Donors and Their Use Toward CO2 Reduction  

SciTech Connect (OSTI)

Despite substantial effort, no one has succeeded in efficiently producing methanol from CO2 using homogeneous photocatalytic systems. We are pursuing reaction schemes based on a sequence of hydride-ion transfers to carry out stepwise reduction of CO2 to methanol. We are using hydride-ion transfer from photoproduced C-H bonds in metal complexes with bio-inspired ligands (i.e., NADH-like ligands) that are known to store one proton and two electrons.

Fujita,E.; Muckerman, J.T.; Polyansky, D.E.

2009-06-07T23:59:59.000Z

156

\\{WS8e4\\} - EFFECT OF HYDRIDES ON THE MECHANICAL PROPERTIES OF ZIRCALOY-4  

Science Journals Connector (OSTI)

ABSTRACT In order to better understand the embrittlement of Zircaloy-4 by hydrides and the ductile-brittle transition on this alloy, Zircaloy-4 sheet tensile specimens in the stress-relieved, recrystallized and ? treated states were hydrided (10 to 1500 ppm wt H) and then tested at two temperatures (20°C, 350°C). Metallographic and fractographic analyses were carried out to determine the fracture micro-mechanisms. The results showed that, at 20°C, Zircaloy-4 undergoes a significant ductile to brittle transition for high hydrogen contents. Heat treatment shifts this transition (to zero elongation) considerably, from 1050 ppm wt H for the stress-relieved state to less than 250 ppm wt H for the ? treated state. However, at 350°C, Zircaloy-4 remains ductile up to hydrogen content higher than 1100 ppm wt. At 20°C, the fracture surfaces are characterized by voids and secondary cracks for low and medium hydrogen contents, and by intergranular crack and decohesion through the continuous hydride network for high hydrogen content. A model based on image analysis and hydride embrittlement micro-mechanism observations is used to calculate the upper-limit hydrogen content which makes Zircaloy-4 totally brittle. The difference between the mechanical behaviors of stress-relieved and recrystallized states is also explained. KEYWORDS Zircaloy-4, hydride embrittlement, ductile-brittle transition, cracked-hydride voids.

J.B. BAI; C. PRIOUL; D. FRANÇOIS

1992-01-01T23:59:59.000Z

157

Fracture of Hydrided Zircaloy-4 Sheet under Through-Thickness Crack Growth Conditions  

SciTech Connect (OSTI)

The failure of thin-wall components such as fuel cladding may be caused by crack initiation on the component surface and subsequent crack growth through its thickness. This study has determined the fracture toughness of hydrided cold-worked stress relieved Zircaloy-4 sheet subject to through-thickness crack growth at 25 deg. C. The experimental approach utilizes a novel procedure in which a narrow linear strip of brittle hydride blister across the specimen width creates a well-defined pre-crack upon initial loading. The subsequent crack growth resistance is then characterized by four-point bending of the specimen and an elastic-plastic fracture mechanics analysis. At room temperature, the through-thickness fracture toughness (K{sub Q}) is sensitive to the orientation of the hydride platelets, and K{sub Q} {approx_equal} 25 MPavm for crack growth through a mixed in-plane/out-of-plane hydride field. In contrast, K{sub Q} is much higher ({approx_equal} 75 MPavm) when the hydride platelets are oriented predominantly in the plane of the sheet (and therefore normal to both the crack plane and the crack growth direction). The implication of these fracture toughness values to the fracture strain behavior of hydrided Zircaloy-4 under through-thickness crack growth conditions is illustrated. (authors)

Raynaud, P.A.; Koss, D.A. [Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA 16802 (United States); Motta, A.T. [Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, PA 16802 (United States); Chan, K.S. [Southwest Research Institute, San Antonio, TX 78238 (United States)

2007-07-01T23:59:59.000Z

158

Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity  

SciTech Connect (OSTI)

The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ? 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ? 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150°C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination

Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

2008-02-18T23:59:59.000Z

159

Atomic absorption spectroscopy  

Science Journals Connector (OSTI)

... is given to the relatively little used hydride technique,whereas the very important area of flameless electrothermal AAS is relegated to the chapter on "Some further techniques"; and it ...

M. A. Ford

1979-04-05T23:59:59.000Z

160

Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy  

SciTech Connect (OSTI)

This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride ?-ZrH1.5 precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. In this work, a model to numerically simulate hydride precipitation at the microstructural scale, in a wide variety of Zr-based claddings, under dry-storage conditions is being developed. It will be used to aid in the evaluation of the mechanical integrity of used fuel rods during dry storage and transportation by providing the structural conditions from the microstructural scale to the continuum scale to engineering component scale models to predict if the used fuel rods will perform without failure under normal and off-normal conditions. The microstructure, especially, the hydride structure is thought to be a primary determinant of cladding failure, thus this component of UFD’s storage and transportation analysis program is critical. The model development, application and validation of the model are documented and the limitations of the current model are discussed. The model has been shown to simulate hydride precipitation in Zircaloy-4 cladding with correct morphology, thermodynamics and kinetics. An unexpected insight obtained from simulations hydride formation in Zircaloy-4 is that small (sub-micron) precipitates need to order themselves to form the larger hydrides typically described as radially-reoriented precipitates. A limitation of this model is that it does not currently solve the stress state that forms dynamically in the precipitate or matrix surrounding the precipitate. A method to overcome the limitations is suggested and described in detail. The necessary experiments to provide key materials physics and to validate the model are also recommended.

Veena Tikare; Philippe Weck; Peter Schultz; Blythe Clark; John Mitchell; Michael Glazoff; Eric Homer

2014-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

CHARACTERIZATION OF THE LOCAL TITANIUM ENVIRONMENT IN DOPED SODIUM ALUMINUM HYDRIDE USING X-RAY ADSORPTION SPECTROSCOPY.  

SciTech Connect (OSTI)

Ti K-edge x-ray absorption spectroscopy was used to explore the local titanium environment and valence in 2-4 mol% Ti-doped sodium alanate. An estimate of the oxidation state of the dopant, based upon known standards, revealed a zero-valent titanium atom. An analysis of the near-edge and extended fine structures indicates that the Ti does not enter substitutional or interstitial sites in the NaAlH{sub 4} lattice. Rather, the Ti is located on/near the surface and is coordinated by 10.2 {+-} 1 aluminum atoms with an interatomic distance of 2.82 {+-} 0.01 {angstrom}, similar to that of TiAl{sub 3}. The Fourier transformed EXAFS spectra reveals a lack of long-range order around the Ti dopant indicating that the Ti forms nano-clusters of TiAl{sub 3}. The similarity of the spectra in the hydrided and dehydrided samples suggests that the local Ti environment is nearly invariant during hydrogen cycling.

GRAETZ, J.; IGNATOV, A. YU; TYSON, T.A.; REILLY, J.J.; JOHNSON, J.

2004-11-30T23:59:59.000Z

162

Hadronic Atoms  

E-Print Network [OSTI]

We review the theory of hadronic atoms in QCD+QED. The non-relativistic effective Lagrangian approach, used to describe this type of bound states, is illustrated with the case of pi+pi- atoms. In addition, we discuss the evaluation of isospin-breaking corrections to hadronic atom observables by invoking chiral perturbation theory.

J. Gasser; V. E. Lyubovitskij; A. Rusetsky

2009-03-02T23:59:59.000Z

163

Proposed Virtual Center for Excellence for Metal Hydride Development  

Broader source: Energy.gov (indexed) [DOE]

& Engineering Sciences Center Atoms to Continuum Storage development within the DOE hydrogen Storage development within the DOE hydrogen program for 10 years program for 10...

164

Dynamic modeling and simulation of hydrogen supply capacity from a metal hydride tank  

Science Journals Connector (OSTI)

Abstract The current study presents a modeling of a LaNi5 metal hydride-based hydrogen storage tank to simulate and control the dynamic processes of hydrogen discharge from a metal hydride tank in various operating conditions. The metal hydride takes a partial volume in the tank and, therefore, hydrogen discharge through the exit of the tank was driven by two factors; one factor is compressibility of pressurized gaseous hydrogen in the tank, i.e. the pressure difference between the interior and the exit of the tank makes hydrogen released. The other factor is desorption of hydrogen from the metal hydride, which is subsequently released through the tank exit. The duration of a supposed full load supply is evaluated, which depends on the initial tank pressure, the circulation water temperature, and the metal hydride volume fraction in the tank. In the high pressure regime, the duration of full load supply is increased with increasing circulation water temperature while, in the low pressure regime where the initial amount of hydrogen absorbed in the metal hydride varies sensitively with the metal hydride temperature, the duration of full load supply is increased and then decreased with increasing circulation water temperature. PID control logic was implemented in the hydrogen supply system to simulate a representative scenario of hydrogen consumption demand for a fuel cell system. The demanded hydrogen consumption rate was controlled adequately by manipulating the discharge valve of the tank at a circulation water temperature not less than a certain limit, which is increased with an increase in the tank exit pressure.

Ju-Hyeong Cho; Sang-Seok Yu; Man-Young Kim; Sang-Gyu Kang; Young-Duk Lee; Kook-Young Ahn; Hyun-Jin Ji

2013-01-01T23:59:59.000Z

165

URANIUM METAL POWDER PRODUCTION, PARTICLE DISTRIBUTION ANALYSIS, AND REACTION RATE STUDIES OF A HYDRIDE-DEHYDRIDE PROCESS  

E-Print Network [OSTI]

atmosphere to reduce sample oxidation .................................................................................................. 13 12 Aluminum oxide crucible located at the bottom of the hydride-dehydride rig. ... 14 13 Furnace and furnace... at 60 minutes, 5psig, 250?C hydride, 325?C dehydride ................................................................................................... 30 27 Rotary kiln designed at ORNL for use in voloxidation...

Sames, William

2011-08-08T23:59:59.000Z

166

Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.  

SciTech Connect (OSTI)

We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom (Savannah River National Labs, Aiken, SC)

2012-01-01T23:59:59.000Z

167

Process for production of an aluminum hydride compound  

DOE Patents [OSTI]

A compound of formula M(AlH.sub.3OR.sup.1).sub.y, wherein R.sup.1 is phenyl substituted by at least one of: (i) an alkoxy group having from one to six carbon atoms; and (ii) an alkyl group having from three to twelve carbon atoms; wherein M is an alkali metal, Be or Mg; and y is one or two.

Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Miller, Dean Michael; Molzahn, David Craig

2013-08-06T23:59:59.000Z

168

Method and composition in which metal hydride particles are embedded in a silica network  

DOE Patents [OSTI]

A silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid. According to one embodiment of the invention, the solid is ground into granules for use of the product in hydrogen storage. Alternatively, the paste can be molded into plates or cylinders and then dried for use of the product as a hydrogen filter. Where mechanical strength is required, the paste can be impregnated in a porous substrate or wire network.

Heung, Leung K. (Aiken, SC)

1999-01-01T23:59:59.000Z

169

Semiclassical atom  

Science Journals Connector (OSTI)

Semiclassical quantization is incorporated into the average potential approach to atomic physics. The stationary energy functional is shown to be the sum of the Thomas-Fermi functional and a mainly oscillatory part. The latter turns out to be a small correction for sufficiently large atomic numbers, allowing perturbative treatment. Further, a detailed study of semiclassical spectra, with emphasis on energy degeneracy, is performed.

Berthold-Georg Englert and Julian Schwinger

1985-07-01T23:59:59.000Z

170

E-Print Network 3.0 - analysis-hydride generation-gas phase Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on the high-pressure phase diagram of molecular CO2... of a new molecular phase of carbon dioxide at high-pressure and high- temperature. Using x-ray diffraction... , we...

171

Reversible Metal Hydride Thermal Energy Storage for High Temperature Power Generation Systems  

Broader source: Energy.gov [DOE]

This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

172

Atomic line emission analyzer for hydrogen isotopes  

DOE Patents [OSTI]

Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

1993-01-01T23:59:59.000Z

173

Atomic line emission analyzer for hydrogen isotopes  

DOE Patents [OSTI]

Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

Kronberg, J.W.

1991-05-08T23:59:59.000Z

174

Atomic line emission analyzer for hydrogen isotopes  

DOE Patents [OSTI]

Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

Kronberg, J.W.

1993-03-30T23:59:59.000Z

175

The influence of hydride blisters on the fracture of Zircaloy-4 O.N. Pierron a  

E-Print Network [OSTI]

.elsevier.com/locate/jnucmat Journal of Nuclear Materials 322 (2003) 21­35 #12;hydrogen embrittlement [15]. Such an effect becomes, and radiation damage [1]. As the cladding undergoes oxidation with the associated hydrogen pickup, the total amount of hydrogen increases, and hydride precipitates form pref- erentially near the outer (cooler

Motta, Arthur T.

176

Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast charging  

E-Print Network [OSTI]

Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast to investigate transient thermal behavior of NiMH batteries. The thermal model uses integral transformation 2013 Available online 25 June 2013 Keywords: Battery thermal management Battery thermal model Fast

Bahrami, Majid

177

Influence of additives on the thermal behavior of nickel/metal hydride battery  

Science Journals Connector (OSTI)

This study discusses the thermal behavior of the 6.5 Ah cylinder Ni/MH hydride battery with 0.5 wt% ytterbium oxide (...2O3...) in nickel electrode and 1.0 wt% super absorbent polymer (SAP) in hydrogen-storage al...

Kai Yang; Jin Jing An; Shi Chen

2010-12-01T23:59:59.000Z

178

Project Profile: Low-Cost Metal Hydride Thermal Energy Storage System  

Broader source: Energy.gov [DOE]

The Savannah River National Laboratory (SRNL), under the National Laboratory R&D competitive funding opportunity, is collaborating with Curtin University (CU) to evaluate new metal hydride materials for thermal energy storage (TES) that meet the SunShot cost and performance targets for TES systems.

179

First Principles Studies of Phase Stability and Reaction Dynamics in Complex Metal Hydrides  

SciTech Connect (OSTI)

Complex metal hydrides are believed to be one of the most promising materials for developing hydrogen storage systems that can operate under desirable conditions. At the same time, these are also a class of materials that exhibit intriguing properties. We have used state-of-the-art computational techniques to study the fundamental properties of these materials.

Chou, Mei-Yin

2014-09-29T23:59:59.000Z

180

Complex Hydrides for Hydrogen Storage Darlene K. Slattery and Michael D. Hampton  

E-Print Network [OSTI]

at a temperature of less than 100 o C in order to be compatible with fuel cells and must have an installed hydrogen have reported the discovery of a number of catalysts that improve the reversing of the hydrogen release the hydrogenation/dehydrogenation of sodium aluminum hydride. Mechanical incorporation of the catalyst

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Evaluation of Protected Metal Hydride Slurries in a H2 Mini-  

E-Print Network [OSTI]

Evaluation of Protected Metal Hydride Slurries in a H2 Mini- Grid TIAX, LLC Acorn Park Cambridge_MERIT_REVIEW_MAY2003 2 Introduction Hydrogen Mini-Grid Concept Distributed FCPS utilizing a H2 Mini-Grid can provide waste heat can be used for hot water or space heating in buildings (i.e. "cogen") Distributed FCPS

182

Atom Interferometry  

ScienceCinema (OSTI)

Atom de Broglie wave interferometry has emerged as a tool capable of addressing a diverse set of questions in gravitational and condensed matter physics, and as an enabling technology for advanced sensors in geodesy and navigation. This talk will review basic principles, then discuss recent applications and future directions. Scientific applications to be discussed include measurement of G (Newton?s constant), tests of the Equivalence Principle and post-Newtonian gravity, and study of the Kosterlitz-Thouless phase transition in layered superfluids. Technology applications include development of precision gryoscopes and gravity gradiometers. The talk will conclude with speculative remarks looking to the future: Can atom interference methods be sued to detect gravity waves? Can non-classical (entangled/squeezed state) atom sources lead to meaningful sensor performance improvements?

Mark Kasevich

2010-01-08T23:59:59.000Z

183

New plasma source of hydrides for epitaxial growth. Final subcontract report, 15 April 1991--3 September 1993  

SciTech Connect (OSTI)

This report describes a novel plasma-activated selenium source that was developed during the course of this subcontract and which is significantly different than any other heretofore reported in the scientific literature. It involves microwave excited, magnetically confined plasma sources that are intended to operate under electron cyclotron resonance (ECR) conditions at 2.455 GHz. This source is designed to excite and dissociate the molecular vapor evaporating or subliming from a heated solid or liquid reservoir. It can combine an effusion cell vapor flux with a stream of hydrogen or helium gas, enabling the in-situ generation of hydrides for use in low-pressure growth techniques where long mean free paths are desirable. Experiments were conducted to demonstrate a stable discharge within the source, and measures were identified to improve its operational characteristics. Application of this novel source is anticipated to enable a low-temperature, safe process for the growth of high-quality epitaxial compound semiconductor films. This reduction of epitaxial growth temperatures may enable the fabrication of novel photovoltaic devices that have heretofore been impossible due to the deleterious effects of interdiffusion at heterointerfaces resulting from the high temperatures required to grow adequate quality material using conventional processes.

Stanbery, B.J. [Boeing Defense & Space Group, Seattle, WA (United States)

1994-05-01T23:59:59.000Z

184

Nickel-Metal-Hydride Batterie--High Energy Storage for Electric Vehicles  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freedomcar & Vehicle Technologies Program Freedomcar & Vehicle Technologies Program Nickel-Metal-Hydride Batteries - High Energy Storage for Electric Vehicles Background The key to making electric vehicles (EVs) practical is the development of batteries that can provide performance comparable with that of con ventional vehicles at a similar cost. Most EV batteries have limited energy storage capabili ties, permitting only relatively short driving distances before the batteries must be recharged. In 1991, under a coopera tive agreement with The U.S. Department of Energy (DOE), the United States Advanced Battery Consortium (USABC) initiated development of nickel- metal-hydride (NiMH) battery technology and established it as a prime mid-term candidate for use in EVs. DOE funding has been instru

185

Aluminum Hydride - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 1 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Jason Graetz (Primary Contact), James Wegrzyn Brookhaven National Laboratory (BNL) Building 815 Upton, NY 11973 Phone: (631) 344-3242 Email: graetz@bnl.gov DOE Manager HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov Project Start Date: October 1, 2011 Project End Date: Project continuation and direction determined annually by DOE Fiscal Year (FY) 2012 Objectives Develop onboard vehicle storage systems using aluminum hydride that meets all of DOE's targets for proton exchange membrane fuel cell vehicles. Produce aluminum hydride material with a hydrogen * storage capacity greater than 9.7% gravimetric (kg-H 2 /kg) and 0.13 kg-H 2 /L volumetric. Develop practical and economical processes for *

186

Pressure Acceleration of Hydride Formation on a Cobalt(I) Macrocycle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pressure Acceleration of Hydride Formation via Pressure Acceleration of Hydride Formation via Proton Binding to a Cobalt(I) Macrocycle Etsuko Fujita, James F. Wishart, and Rudi van Eldik Inorg. Chem. 41, 1579-1583 (2002) [Find paper at ACS Publications] Abstract: The effect of pressure on proton binding to the racemic isomer of the cobalt(I) macrocycle, CoL+ (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene), has been studied for a series of proton donors using pulse radiolysis techniques. The second-order rate constants for the reaction of CoL+ with proton donors decrease with increasing pKa of the donor acid, consistent with a reaction occurring via proton transfer. Whereas the corresponding volumes of activation (DVý) are rather small and negative for all acids (proton donors) with pKa values below 8.5, significantly larger negative

187

Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation  

DOE Patents [OSTI]

An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-based materials is disclosed. Samples of zirconium-based materials having different compositions and/or fabrication methods are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280 to 316 C). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hydriding for the same materials when subject to in-reactor (irradiated) corrosion. 1 figure.

Johnson, A.B. Jr.; Levy, I.S.; Trimble, D.J.; Lanning, D.D.; Gerber, F.S.

1990-04-10T23:59:59.000Z

188

Systems Modeling, Simulation and Material Operating Requirements for Chemical Hydride Based Hydrogen Storage  

SciTech Connect (OSTI)

Research on ammonia borane (AB, NH3BH3) has shown it to be a promising material for chemical hydride based hydrogen storage. AB was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to 19.6% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. A new systems concept based on augers, ballast tank, hydrogen heat exchanger and H2 burner was designed and implemented in simulation. In this design, the chemical hydride material was assumed to produce H2 on the augers itself, thus minimizing the size of ballast tank and reactor. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure, in various components of the storage system. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. The control variable AB (or alane) flow rate was determined through a simple expression based on the ballast tank pressure, H2 demand from the fuel cell and hydrogen production from AB (or alane) in the reactor. System simulation results for solid AB, liquid AB and alane for both steady state and transient drive cycle cases indicate the usefulness of the model for further analysis and prototype development.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.

2012-02-01T23:59:59.000Z

189

Gold Hydride Complexes DOI: 10.1002/anie.200803842  

E-Print Network [OSTI]

have been observed solely in the gas phase.[7] The N-heterocyclic carbene (NHC) ligand IPr (IPr= 1, dimeric [{(IPr)CuH}2], synthesized from [(IPr)CuCl] in two steps.[8] Since NHC ligands have been shown reactions. The reaction of the known compound [(IPr)AuCl][10] with sodium tert-butoxide generated [(IPr

Müller, Peter

190

Thermodynamic Changes in Mechanochemically Synthesized Magnesium Hydride Nanoparticles  

Science Journals Connector (OSTI)

Ball milling was performed at room temperature with a custom-made 316 stainless steel ball milling canister (650 cm3 internal volume) attached to a Glen Mills Turbula T2C shaker mixer. ... Due to limitations with extremely slow kinetics full pressure?composition isotherms were not generated. ... Marchi, C. S., Somerday, B. P., and Robinson, S. L. Int. ...

Mark Paskevicius; Drew A. Sheppard; Craig E. Buckley

2010-03-22T23:59:59.000Z

191

Atom Probe Tomography | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atom Probe Tomography Atom Probe Tomography The LEAP 4000 XHR local electrode atom probe tomography instrument enabled the first-ever comprehensive and accurate 3-D chemical...

192

Study on generating of thermal neutron scattering cross sections for LiH  

SciTech Connect (OSTI)

LiH is designated as a promising moderator and shielding material because of its low density, high melting point and large fraction of H atoms. However, lack of the thermal neutron cross sections of LiH makes numerical calculation deviate from experimental data to some extent. As a result, it is necessary to study LiH thermal kernel effect. The phonon property of LiH has been investigated by first-principles calculations using the plane-wave pseudo potential method with CASTEP code. The scattering law and the thermal neutron scattering cross sections for Li and H have been generated using this distribution. The results have been compared with zirconium hydride data. The GASKET and NJOY/LEAPR codes have been used in the calculation of scattering law, whose results have been compared with the reference; the discrepancy mainly comes from phonon spectrums and its expansion. LEAPR had the capability to compute scattering through larger energy and momentum transfers than GASKET did. By studying LiH phonon spectrum and constructing the model of LiH thermal kernel and scattering matrix, the ACE format LiH thermal neutron cross sections for MCNP software could be made and used for reactor Neutronics calculation. (authors)

Wang, L.; Jiang, X.; Zhao, Z.; Chen, L. [Northwest Institute of Nuclear Technology, Xi'an 710024 (China)

2013-07-01T23:59:59.000Z

193

Electromagnetically induced grating with maximal atomic coherence  

SciTech Connect (OSTI)

We describe theoretically an atomic diffraction grating that combines an electromagnetically induced grating with a coherence grating in a double-{Lambda} atomic system. With the atom in a condition of maximal coherence between its lower levels, the combined gratings simultaneously diffract both the incident probe beam as well as the signal beam generated through four-wave mixing. A special feature of the atomic grating is that it will diffract any beam resonantly tuned to any excited state of the atom accessible by a dipole transition from its ground state.

Carvalho, Silvania A.; Araujo, Luis E. E. de [Instituto de Fisica ''Gleb Wataghin'', Universidade Estadual de Campinas, Campinas-SP, 13083-859 Sao Paulo (Brazil)

2011-10-15T23:59:59.000Z

194

Draft of M2 Report on Integration of the Hybrid Hydride Model into INL’s MBM Framework for Review  

SciTech Connect (OSTI)

This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride {delta}-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. This document demonstrates a basic hydride precipitation model that is built on a recently developed hybrid Potts-phase field model that combines elements of Potts-Monte Carlo and the phase-field models (Homer et al., 2013; Tikare and Schultz, 2012). The model capabilities are demonstrated along with the incorporation of the starting microstructure, thermodynamics of the Zr-H system and the hydride formation mechanism.

Tikare, Veena; Weck, Philippe F.; Schultz, Peter A.; Clark, Blythe; Michael Glazoff; Eric Homer

2014-07-01T23:59:59.000Z

195

ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T. van Duin, and William A. Goddard III*  

E-Print Network [OSTI]

ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. TFFMgH) for magnesium and magnesium hydride systems. The parameters for this force field were derived from fitting to quantum chemical (QM) data on magnesium clusters and on the equations of states for condensed phases

van Duin, Adri

196

Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermodynamic guidelines for the prediction of hydrogen Thermodynamic guidelines for the prediction of hydrogen storage reactions and their application to destabilized hydride mixtures Hydrogen Storage & Nanoscale Modeling Group Ford Motor Company Don Siegel dsiegel2@ford.com Phys. Rev. B 76, 134102 (2007) 1 Acknowledgements C. Wolverton V. Ozolins Computation Northwestern UCLA J. Yang A. Sudik Experiments Ford Ford 2 Computational Methodology * Atomistic computer simulations based on quantum mechanics (Density Functional Theory) * First-principles approach: - Only empirical input are crystal structure and fundamental physical constants - VASP code - PAW potentials - PW91 GGA - Temperature-dependent thermodynamic contributions evaluated within harmonic approximation * "Direct method" for construction of dynamical matrix

197

Measurements of Ionic Structure in Shock Compressed Lithium Hydride from Ultrafast X-Ray Thomson Scattering  

SciTech Connect (OSTI)

We present the first ultrafast temporally, spectrally, and angularly resolved x-ray scattering measurements from shock-compressed matter. The experimental spectra yield the absolute elastic and inelastic scattering intensities from the measured density of free electrons. Laser-compressed lithium-hydride samples are well characterized by inelastic Compton and plasmon scattering of a K-alpha x-ray probe providing independent measurements of temperature and density. The data show excellent agreement with the total intensity and structure when using the two-species form factor and accounting for the screening of ion-ion interactions.

Kritcher, A. L. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Neumayer, P.; Doeppner, T.; Landen, O. L.; Glenzer, S. H. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Brown, C. R. D. [Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); AWE plc., Aldermaston, Reading, RG7 4PR (United Kingdom); Davis, P. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Falcone, R. W.; Lee, H. J. [Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Gericke, D. O.; Vorberger, J.; Wuensch, K. [CFSA, Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Gregori, G. [Department of Physics, Oxford University, Oxford OX1 3PU (United Kingdom); Holst, B.; Redmer, R. [Universitaet Rostock, Institut fuer Physik, D-18051 Rostock (Germany); Morse, E. C. [Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Pelka, A.; Roth, M. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, Darmstadt (Germany)

2009-12-11T23:59:59.000Z

198

Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper  

DOE Patents [OSTI]

An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

1982-08-10T23:59:59.000Z

199

Positron binding to alkali-metal hydrides: The role of molecular vibrations  

SciTech Connect (OSTI)

The bound vibrational levels for J=0 have been computed for the series of alkali-metal hydride molecules from LiH to RbH, including NaH and KH. For all four molecules the corresponding potential-energy curves have been obtained for each isolated species and for its positron-bound complex (e{sup +}XH). It is found that the calculated positron affinity values strongly depend on the molecular vibrational state for which they are obtained and invariably increase as the molecular vibrational energy content increases. The consequences of our findings on the likelihood of possibly detecting such weakly bound species are briefly discussed.

Gianturco, Franco A.; Franz, Jan; Buenker, Robert J.; Liebermann, Heinz-Peter; Pichl, Lukas; Rost, Jan-Michael; Tachikawa, Masanori; Kimura, Mineo [Department of Chemistry and INFM, University of Rome La Sapienza, Piazzale A. Moro 5, 00185 Rome (Italy); Fachbereich C-Mathematik und Naturwissenschaften, Bergische Universitaet Wuppertal, Gaussstrasse 20, D-42119 Wuppertal (Germany); Max Planck Institute for the Physics of Complex Systems, Noethnitzer St. 38, D-01187 Dresden (Germany); Graduate School of Science, Yokohama-city University, Seto 22-2, Kanazawa-ku, Yokohama 236-0027 (Japan); Graduate School of Sciences, Kyushu University, Fukuoka 812-8581 (Japan)

2006-02-15T23:59:59.000Z

200

Electron Diffraction from a Cold Atom Electron Source  

Science Journals Connector (OSTI)

We present single-shot nanosecond and picosecond electron diffraction measurements from gold and graphene using ultracold electrons generated by photoionisation of laser cooled atoms.

Speirs, Rory W; Thompson, Daniel J; Murphy, Dene; Sparkes, Ben M; Scholten, Rob E

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Theory of Hydride-Proton Transfer (HPT) Carbonyl Reduction by [Os(III)(tpy)(Cl)(NH=CHCH3)(NSAr)  

SciTech Connect (OSTI)

Quantum mechanical analysis reveals that carbonyl reduction of aldehydes and ketones by the imine-based reductant cis-[Os{sup III}(tpy)(Cl)(NH?CHCH{sub 3})(NSAr)] (2), which is accessible by reduction of the analogous nitrile, occurs by hydride-proton transfer (HPT) involving both the imine and sulfilimido ligands. In carbonyl reduction, water or alcohol is necessary to significantly lower the barrier for proton shuttling between ligands. The ?N(H)SAr group activates the carbonyl group through hydrogen bonding while the ?NC(H)CH{sub 3} ligand delivers the hydride.

Ess, Daniel H.; Schauer, Cynthia; Meyer, Thomas J.

2010-01-01T23:59:59.000Z

202

Single atom as a macroscopic entanglement source  

E-Print Network [OSTI]

by many authors including the generation of entangled coherent state #3;1?3#4;, single photon and vacuum entanglement #3;4#4;, and two-atom entanglement #3;5#4;. More recently, generation of macroscopic entangled states via phase sensitive... cascade configuration crossing or trapped in a two-mode field cavity. The atomic level configuration is depicted in Fig. 1. The two atomic transitions #5;a#6;? #5;b#6; and #5;b#6;? #5;c#6; interact with the two cavity modes with detunings #1...

Zhou, Ling; Xiong, Han; Zubairy, M. Suhail.

2006-01-01T23:59:59.000Z

203

Measuring atomic properties with an atom interferometer  

E-Print Network [OSTI]

Two experiments are presented which measure atomic properties using an atom interferometer. The interferometer splits the sodium de Broglie wave into two paths, one of which travels through an interaction region. The paths ...

Roberts, Tony David, 1972-

2002-01-01T23:59:59.000Z

204

Nondestructive Evaluation on Hydrided LWR Fuel Cladding by Small Angle Incoherent Neutron Scattering of Hydrogen  

SciTech Connect (OSTI)

A non-destructive neutron scattering method was developed to precisely measure the uptake of total hydrogen in nuclear grade Ziraloy-4 cladding. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and H gas. By controlling the initial H gas pressure in the vessel and the temperature profile, target H concentrations from tens of ppm to a few thousands of wppm have been successfully achieved. Following H charging, the H content of the hydrided specimens was measured using the vacuum hot extraction method (VHE), by which the samples with desired H concentration were selected for the neutron study. Small angle neutron incoherent scattering (SANIS) were performed in the High Flux Isotope Reactor at Oak Ridge national Laboratory (ORNL). Our study indicates that a very small amount ( 20 ppm) H in commercial Zr cladding can be measured very accurately in minutes for a wide range of H concentration by a nondestructive method. The H distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor, which is determined by calibration process with direct chemical analysis method on the specimen. This scale factor can be used for future test with unknown H concentration, thus provide a nondestructive method for absolute H concentration determination.

Yan, Yong [ORNL; Qian, Shuo [ORNL; Littrell, Ken [ORNL; Parish, Chad M [ORNL; Bell, Gary L [ORNL; Plummer, Lee K [ORNL

2013-01-01T23:59:59.000Z

205

Hydride-dehydride module within ARIES (Advanced Recovery and Integrated Extraction System)  

SciTech Connect (OSTI)

One of the many requirements placed on the DOE is the reduction of the nuclear stockpile through dismantlement programs. The DOE Office of Fissile Materials Disposition (OFMD) has been tasked with the disposition of excess plutonium and other fissile materials. On the list of items containing excess fissile materials are nuclear weapon cores, pits. The Advanced Recovery and integrated Extraction System (ARIES) at Los Alamos National Laboratory is the pit disassembly and conversion demonstration line that is being used to gather data to support the design of the full scale pit disassembly and conversion facility. The Hydride Dehydride recycle system is an important element to this program, because it provides these dismantlement programs with a technology for removing plutonium from nuclear weapons without producing large amounts of waste compared to historical processes used in the DOE complex. The Hydride Dehydride recycle process can separate plutonium from other weapons components resulting in an unclassified plutonium metal button. After separation, this button can be stored in long term storage containers or processed to produce plutonium oxide, which will be used by either of the plutonium disposition options, mixed oxide fuel burning in a nuclear reactor or immobilization. Once placed into long term storage containers, either the plutonium metal or plutonium oxide can be inspected by bilateral or international agencies to invoke transparency of the plutonium.

Flamm, B.F.; Isom, G.M.; Nelson, T.O.

1998-12-31T23:59:59.000Z

206

Mechanical Behavior Studies of Depleted Uranium in the Presence of Hydrides  

SciTech Connect (OSTI)

This project addresses critical issues related to aging in the presence of hydrides (UH{sub 3}) in DU and the subsequent effect on mechanical behavior. Rolled DU specimens with three different hydrogen concentrations and the as-rolled condition were studied. The texture measurements indicate that the hydrogen charging is affecting the initial as-rolled DU microstructure/texture. The macroscopic mechanical behavior suggests the existence of a threshold between the 0 wpmm H and 0.3 wppm H conditions. A VPSC simulation of the macroscopic strain-stress behavior, when taking into account only a texture effect, shows no agreement with the experiment. This suggests that the macroscopic mechanical behavior observed is indeed due to the presence of hydrogen/hydrides in the DU bulk. From the lattice strain variation it can be concluded that the hydrogen is affecting the magnitude and/or the nature of CRSS. The metallography indicates the specimens that underwent the hydrogen charging process, developed large grains and twinning, which were enhanced by the presence of hydrogen. Further studies using electron microscopy and modeling will be conducted to learn about the deformation mechanisms responsible for the observed behavior.

Garlea, E.; Morrell, J. S.; Bridges, R. L.; Powell, G. L.; Brown, d. W.; Sisneros, T. A.; Tome, C. N.; Vogel, S. C.

2011-02-14T23:59:59.000Z

207

Method of performing MRI with an atomic magnetometer  

DOE Patents [OSTI]

A method and apparatus are provided for performing an in-situ magnetic resonance imaging of an object. The method includes the steps of providing an atomic magnetometer, coupling a magnetic field generated by magnetically resonating samples of the object through a flux transformer to the atomic magnetometer and measuring a magnetic resonance of the atomic magnetometer.

Savukov, Igor Mykhaylovich; Matlashov, Andrei Nikolaevich; Espy, Michelle A.; Volegov, Petr Lvovich; Kraus, Jr., Robert Henry; Zotev, Vadim Sergeyevich

2012-11-06T23:59:59.000Z

208

Method of performing MRI with an atomic magnetometer  

DOE Patents [OSTI]

A method and apparatus are provided for performing an in-situ magnetic resonance imaging of an object. The method includes the steps of providing an atomic magnetometer, coupling a magnetic field generated by magnetically resonating samples of the object through a flux transformer to the atomic magnetometer and measuring a magnetic resonance of the atomic magnetometer.

Savukov, Igor Mykhaylovich; Matlashov, Andrei Nikolaevich; Espy, Michelle A; Volegov, Petr Lvovich; Kraus, Jr., Robert Henry; Zotev, Vadim Sergeyevich

2013-08-27T23:59:59.000Z

209

OBSERVATIONS IN REACTIVITY BETWEEN BH CONTAINING COMPOUNDS AND ORGANOMETALLIC REAGENTS: SYNTHESIS OF BORONIC ACIDS, BORONIC ESTERS, AND MAGNESIUM HYDRIDES  

E-Print Network [OSTI]

aryl bromides and H 2 BN(iPr) 2 Scheme 2.7. Hydroboration oftransfer hydride to BH 2 -N(iPr) 2 Scheme 2.10. Conversionchloride with BH 2 -N(iPr) 2 Scheme 3; Aqueous quench of p-

Clary, Jacob William

2012-01-01T23:59:59.000Z

210

Verification and Validation Strategy for Implementation of Hybrid Potts-Phase Field Hydride Modeling Capability in MBM  

SciTech Connect (OSTI)

The Used Fuel Disposition (UFD) program has initiated a project to develop a hydride formation modeling tool using a hybrid Potts­phase field approach. The Potts model is incorporated in the SPPARKS code from Sandia National Laboratories. The phase field model is provided through MARMOT from Idaho National Laboratory.

Jason D. Hales; Veena Tikare

2014-04-01T23:59:59.000Z

211

Combustion Processes in the Zr-Co-H2 System and Synthesis of Hydrides of Intermetallic Compounds  

Science Journals Connector (OSTI)

The researches on Zr2Co, ZrCo, ZrCo2 synthesis and hydriding in a self-propagating hightemperature synthesis — SHS mode are carried out. In IMC — hydrogen systems low temperature (350–500°C) and high temperature ...

H. G. Hakobyan; S. K. Dolukhanyan

2002-01-01T23:59:59.000Z

212

The combined system for fuel supply of fuel cells on the basis of the aluminum-water hydrogen generator and the metal hybride hydrogen storage  

Science Journals Connector (OSTI)

The system for fuel supply of a hydrogen-air fuel cell on the basis of the aluminum-water hydrogen generator and hydride-forming alloy as an intermediate gas storage has been developed. For a series of...4.5 ? x ...

I. V. Yanilkin; Ye. I. Shkol’nikov; S. N. Klyamkin; M. S. Vlaskin…

2010-12-01T23:59:59.000Z

213

Anticipating the atom: popular perceptions of atomic power before Hiroshima  

E-Print Network [OSTI]

to spontaneously generate light and heat. s Theory chased research after the turn of the century. Rutherford and his partner Frederick Soddy, in Montreal in 1902, noticed that the heaviest radioactive elements were slowly changing into lighter elements, throwing... the Atlantic. More importantly, in 1908, the final chapter of Frederick Soddy's The Jnterpretati on of Radium, a collection of six free popular lectures given at the University of Glasgow, speculated on the possibility of controlling the rate of atomic...

d'Emal, Jacques-Andre Christian

2012-06-07T23:59:59.000Z

214

Elements & Compounds Atoms (Elements)  

E-Print Network [OSTI]

#12;Elements & Compounds #12;Atoms (Elements) Molecules (Compounds) Cells Elements & Compounds #12;Nucleus Electrons Cloud of negative charge (2 electrons) Fig. 2.5: Simplified model of a Helium (He) Atom He 4.002602 2 Helium Mass Number (~atomic mass) = number of Neutrons + Protons = 4 for Helium Atomic

Frey, Terry

215

Neutral atom traps.  

SciTech Connect (OSTI)

This report describes progress in designing a neutral atom trap capable of trapping sub millikelvin atom in a magnetic trap and shuttling the atoms across the atom chip from a collection area to an optical cavity. The numerical simulation and atom chip design are discussed. Also, discussed are preliminary calculations of quantum noise sources in Kerr nonlinear optics measurements based on electromagnetically induced transparency. These types of measurements may be important for quantum nondemolition measurements at the few photon limit.

Pack, Michael Vern

2008-12-01T23:59:59.000Z

216

Quantum Simulation of Helium Hydride in a Solid-State Spin Register  

E-Print Network [OSTI]

\\emph{Ab initio} computation of molecular properties is one of the most promising applications of quantum computing. While this problem is widely believed to be intractable for classical computers, efficient quantum algorithms exist which have the potential to vastly accelerate research throughput in fields ranging from material science to drug discovery. Using a solid-state quantum register realized in a nitrogen-vacancy (NV) defect in diamond, we compute the bond dissociation curve of the minimal basis helium hydride cation, HeH$^+$. Moreover, we report an energy uncertainty (given our model basis) of the order of $10^{-14}$ Hartree, which is ten orders of magnitude below desired chemical precision. As NV centers in diamond provide a robust and straightforward platform for quantum information processing, our work provides several important steps towards a fully scalable solid state implementation of a quantum chemistry simulator.

Ya Wang; Florian Dolde; Jacob Biamonte; Ryan Babbush; Ville Bergholm; Sen Yang; Ingmar Jakobi; Philipp Neumann; Alán Aspuru-Guzik; James D. Whitfield; Jörg Wrachtrup

2014-05-12T23:59:59.000Z

217

RF sputtering for controlling dihydride and monohydride bond densities in amorphous silicon hydride  

DOE Patents [OSTI]

A process is described for controlling the dihydride and monohydride bond densities in hydrogenated amorphous silicone produced by reactive rf sputtering of an amorphous silicon target. There is provided a chamber with an amorphous silicon target and a substrate therein with the substrate and the target positioned such that when rf power is applied to the target the substrate is in contact with the sputtering plasma produced thereby. Hydrogen and argon are fed to the chamber and the pressure is reduced in the chamber to a value sufficient to maintain a sputtering plasma therein, and then rf power is applied to the silicon target to provide a power density in the range of from about 7 watts per square inch to about 22 watts per square inch to sputter an amorphous solicone hydride onto the substrate, the dihydride bond density decreasing with an increase in the rf power density. Substantially pure monohydride films may be produced.

Jeffery, F.R.; Shanks, H.R.

1980-08-26T23:59:59.000Z

218

Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation  

DOE Patents [OSTI]

An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-bsed materials is disclosed. Samples of zirconium-based materials having different composition and/or fabrication are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280.degree. to 316.degree. C.). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hyriding for the same materials when subject to in-reactor (irradiated) corrision.

Johnson, Jr., A. Burtron (Richland, WA); Levy, Ira S. (Kennewick, WA); Trimble, Dennis J. (Kennewick, WA); Lanning, Donald D. (Kennewick, WA); Gerber, Franna S. (Richland, WA)

1990-01-01T23:59:59.000Z

219

Startup and Operation of a Metal Hydride Based Isotope Separation Process  

SciTech Connect (OSTI)

Production scale separation of tritium from other hydrogen isotopes at the Savannah River Site (SRS) in Aiken, SC, has been accomplished by several methods. These methods include thermal diffusion (1957--1986), fractional absorption (1964--1968), and cryogenic distillation (1967-present). Most recently, the Thermal Cycling Absorption Process (TCAP), a metal hydride based hydrogen isotope separation system, began production in the Replacement Tritium Facility (RTF) on April 9, 1994. TCAP has been in development at the Savannah River Technology Center since 1980. The production startup of this semi-continuous gas chromatographic separation process is a significant accomplishment for the Savannah River Site and was achieved after years of design, development, and testing.

Scogin, J.H.; Poore, A.S.

1995-02-27T23:59:59.000Z

220

Prediction of a multicenter-bonded solid boron hydride for hydrogen storage  

Science Journals Connector (OSTI)

A layered solid boron hydride structure (B2H2) consisting of a hexagonal boron network and bridge hydrogen which has a gravimetric capacity of 8wt% hydrogen is predicted. The structural, electronic, and dynamical properties of the proposed structure are investigated using first-principles electronic structure methods. The absence of soft phonon modes confirms the dynamical stability of the proposed structure. Charging the structure significantly softens hydrogen related phonon modes. Boron modes, in contrast, are either hardened or not significantly affected by electron doping. Furthermore, self-doping the structure considerably reduces the energy barrier against hydrogen release. These results suggest that electrochemical charging or self-doping mechanisms may facilitate hydrogen release while the underlying boron network remains intact for subsequent rehydrogenation.

Tesfaye A. Abtew; Bi-ching Shih; Pratibha Dev; Vincent H. Crespi; Peihong Zhang

2011-03-07T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells  

DOE Patents [OSTI]

An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

1999-03-30T23:59:59.000Z

222

Hydrogen Generation from Hydrolysis and Methanolysis of Guanidinium Borohydride  

Science Journals Connector (OSTI)

With the addition of 2.0 mol % CoCl2 at 25 °C, the methanolysis of GBH could generate 4 equiv of H2 within 10 min with a maximum hydrogen generation rate of 9961.5 mL·min–1·g–1 while only 1.8 equiv of H2 was obtained under the same conditions at a maximum hydrogen generation rate of 692.3 mL·min–1·g–1 for hydrolysis. ... The continuously rising concerns over dwindling energy resources and the environmental impact of burning fossil fuels (petroleum, for example) have triggered intensive attention on the exploration of sustainable and renewable alternative energy carriers, such as nuclear energy, solar energy, and hydrogen energy. ... Another advantage of hydrogen generation by hydrolysis of chemical hydrides is that half of the generated hydrogen originates from water, and the slightly humid hydrogen can be directly used in a polymer electrolyte membrane fuel cell (PEMFC). ...

Leigang Li; Shaofeng Li; Yingbin Tan; Ziwei Tang; Wanyu Cai; Yanhui Guo; Qian Li; Xuebin Yu

2012-06-13T23:59:59.000Z

223

7 -ATOMIC PROCESSES Atomic processes can be  

E-Print Network [OSTI]

1 7 - ATOMIC PROCESSES Atomic processes can be: 1. Scattering 2. Absorption/Thermal Emission scattering, although the results won't change much when this condition is relaxed. Absorption/Thermal Emission Free-free (continuum) ("Bremsstrahlung") Emission/Absorption #12;2 Bound-Bound & Bound

Sitko, Michael L.

224

7 -ATOMIC PROCESSES Atomic processes can be  

E-Print Network [OSTI]

1 7 - ATOMIC PROCESSES Atomic processes can be: 1. Scattering 2. Absorption/Thermal Emission scattering, although the results won't change much when this condition is relaxed. #12;2 Absorption/Thermal Emission Free-free (continuum) ("Bremsstrahlung") Emission/Absorption Bound-Bound & Bound-Free Processes

Sitko, Michael L.

225

Production of mesoscopic superpositions with ultracold atoms  

E-Print Network [OSTI]

We study mesoscopic superpositions of two component Bose-Einstein condensates. Atomic condensates, with long coherence times, are good systems in which to study such quantum phenomenon. We show that the mesoscopic superposition states can be rapidly generated in which the atoms dispersively interact with the photon field in a cavity. We also discuss the production of compass states which are generalized Schr\\"{o}dinger cat states. The physical realization of mesoscopic states is important in studying decoherence and precision measurement.

H. T. Ng

2007-07-16T23:59:59.000Z

226

Manhattan Project: Atomic Bombardment, 1932-1938  

Office of Scientific and Technical Information (OSTI)

Solvay Physics Conference, Brussels, October 1933 ATOMIC BOMBARDMENT Solvay Physics Conference, Brussels, October 1933 ATOMIC BOMBARDMENT (1932-1938) Events > Atomic Discoveries, 1890s-1939 A Miniature Solar System, 1890s-1919 Exploring the Atom, 1919-1932 Atomic Bombardment, 1932-1938 The Discovery of Fission, 1938-1939 Fission Comes to America, 1939 M. Stanley Livingston and Ernest O. Lawrence in front of a 27-inch cyclotron, Rad Lab, University of California, Berkeley, 1934. In the 1930s, scientists learned a tremendous amount about the structure of the atom by bombarding it with sub-atomic particles. Ernest O. Lawrence's cyclotron, the Cockroft-Walton machine, and the Van de Graaff generator, developed by Robert J. Van de Graaff at Princeton University, were particle accelerators designed to bombard the nuclei of various elements to disintegrate atoms. Attempts of the early 1930s to split atoms, however, required huge amounts of energy because the first accelerators used proton beams and alpha particles as sources of energy. Since protons and alpha particles are positively charged, they Albert Einstein met substantial resistance from the positively charged target nucleus when they attempted to penetrate atoms. Even high-speed protons and alpha particles scored direct hits on a nucleus only approximately once in a million tries. Most simply passed by the target nucleus. Not surprisingly, Ernest Rutherford, Albert Einstein (right), and Niels Bohr regarded particle bombardment as useful in furthering knowledge of nuclear physics but believed it unlikely to meet public expectations of harnessing the power of the atom for practical purposes anytime in the near future. In a 1933 interview, Rutherford called such expectations "moonshine." Einstein compared particle bombardment with shooting in the dark at scarce birds, while Bohr, the Danish Nobel laureate, agreed that the chances of taming atomic energy were remote.

227

Generation of graph-state streams  

E-Print Network [OSTI]

We propose a protocol to generate a stream of mobile qubits in a graph state through a single stationary parent qubit and discuss two types of its physical implementation, namely, the generation of photonic graph states through an atom-like qubit and those of flying atoms through a cavity-mode photonic qubit. The generated graph states fall into an important class that can hugely reduce the resource requirement of fault-tolerant linear optics quantum computation, which was previously known to be far from realistic. In regard to the flying atoms, we also propose a heralded generation scheme, which allows for high-fidelity graph states even under the photon loss.

Daniel Ballester; Jaeyoon Cho; M. S. Kim

2010-12-08T23:59:59.000Z

228

Development of a lithium hydride powered hydrogen generator for use in long life, low power PEM fuel cell power supplies  

E-Print Network [OSTI]

This thesis studies a hybrid PEM fuel cell system for use in low power, long life sensor networks. PEM fuel cells offer high efficiency and environmental friendliness but have not been widely adopted due to cost, reliability, ...

Strawser, Daniel DeWitt

2012-01-01T23:59:59.000Z

229

Diophantine Generation,  

E-Print Network [OSTI]

Diophantine Generation, Horizontal and Vertical Problems, and the Weak Vertical Method Alexandra Shlapentokh Diophantine Sets, Definitions and Generation Diophantine Sets Diophantine Generation Properties of Diophantine Generation Diophantine Family of Z Diophantine Family of a Polynomial Ring Going Down Horizontal

Shlapentokh, Alexandra

230

Materials Go/No-Go Decisions Made Within the Department of Energy Metal Hydride Center of Excellence  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Go/No-Go Decisions Made Within Materials Go/No-Go Decisions Made Within the Department of Energy Metal Hydride Center of Excellence (MHCoE) In fulfillment of the end of Fiscal Year 2007 Project Milestone on Materials Down-selection Lennie Klebanoff, Director Sandia National Laboratories Livermore, CA 94551 September/October 2007 1 Acknowledgements The author wishes to acknowledge the contributions of all Principal Investigators within the Metal Hydride Center of Excellence (MHCoE) to the work summarized herein. Their names and affiliations are listed below. Especially significant contributions to this document were made by Dr. Ewa Ronnebro (SNL), Dr. John Vajo (HRL), Prof. Zak Fang (U. Utah), Dr. Robert Bowman Jr. (JPL), Prof. David Sholl (CMU) and Prof. Craig Jensen (U. Hawaii). The author thanks Dr.

231

Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes  

E-Print Network [OSTI]

There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

Widom, A; Larsen, L

2012-01-01T23:59:59.000Z

232

Study of integrated metal hydrides heat pump and cascade utilization of liquefied natural gas cold energy recovery system  

Science Journals Connector (OSTI)

The traditional cold energy utilization of the liquefied natural gas system needs a higher temperature heat source to improve exergy efficiency, which barricades the application of the common low quality thermal energy. The adoption of a metal hydride heat pump system powered by low quality energy could provide the necessary high temperature heat and reduce the overall energy consumption. Thus, an LNG cold energy recovery system integrating metal hydride heat pump was proposed, and the exergy analysis method was applied to study the case. The performance of the proposed integration system was evaluated. Moreover, some key factors were also theoretically investigated about their influences on the system performance. According to the results of the analysis, some optimization directions of the integrated system were also pointed out.

Xiangyu Meng; Feifei Bai; Fusheng Yang; Zewei Bao; Zaoxiao Zhang

2010-01-01T23:59:59.000Z

233

Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes  

E-Print Network [OSTI]

There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

A. Widom; Y. N. Srivastava; L. Larsen

2012-10-17T23:59:59.000Z

234

Effects on the positive electrode of the corrosion of AB{sub 5} alloys in nickel-metal-hydride batteries  

SciTech Connect (OSTI)

Effects of corrosion of MmNi{sub 4.3{minus}x}Mn{sub 0.3}Al{sub 0.4}Co{sub x} alloys (where Mm = Ce 50%, La 30%, Nd 15%, Pr 5%) are evaluated in nickel-metal-hydride (Ni-MH) cells. Particularly, it is shown how Al released by the corroded alloys pollutes the positive electrode, which endures a loss of charging efficiency, due to the formation of a hydrotalcite-like phase stabilized with Al. Furthermore, since Al is eluted from the hydride electrode and is completely trapped in the positive active material, the titration of this element in the positive electrode is a powerful technique for quantification of the corrosion of AB{sub 5} alloys in Ni-MH cells.

Bernard, P. [SAFT, Marcoussis (France). Research Dept.

1998-02-01T23:59:59.000Z

235

Reading Comprehension - Atomic History  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atomic History Atomic History A Greek philosopher named Democritus said that all atoms are small, hard particles. He thought that atoms were made of a single material formed into different shapes and sizes. The word " _________ element compound mixture atom " is derived from the Greek word "atomos" which means "not able to be divided." In 1803, John Dalton, a school teacher, proposed his atomic theory. Dalton's theory states that elements (substances composed of only one type of _________ molecules ions atom ) combine in certain proportions to form _________ compounds atoms mixtures elements . In 1897, a British scientist named J. J. Thomson experimented with a cathode-ray tube which had a positively charged plate. The plate attracted negatively charged particles that we now call _________ protons neutrons

236

Atomizing nozzle and process  

DOE Patents [OSTI]

High pressure atomizing nozzle includes a high pressure gas manifold having a divergent expansion chamber between a gas inlet and arcuate manifold segment to minimize standing shock wave patterns in the manifold and thereby improve filling of the manifold with high pressure gas for improved melt atomization. The atomizing nozzle is especially useful in atomizing rare earth-transition metal alloys to form fine powder particles wherein a majority of the powder particles exhibit particle sizes having near-optimum magnetic properties.

Anderson, I.E.; Figliola, R.S.; Molnar, H.M.

1993-07-20T23:59:59.000Z

237

Atomic Energy Commission : Atomic Power at Shippingport - 1958 Educational Film  

SciTech Connect (OSTI)

The United States Atomic Energy Commission & Westinghouse Electric Company take us on a tour of an atomic power station.

None

2013-02-02T23:59:59.000Z

238

E-Print Network 3.0 - atomic matter waves Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the matter-wave analog of optical... in this effort. Matter-Wave Interferometry with Cold Atoms Cold atoms make it possible to generate very small... their wavelike behavior....

239

E-Print Network 3.0 - atomic beam produced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in the scattering of light by a condensate Summary: for the generation of directed beams of atoms and light. B C D E F G Laser Beam Light Atoms A Observation... ). However,...

240

Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oxygen flux determined by mixed-phase AgAg2O deposition. Atomic oxygen flux determined by mixed-phase AgAg2O deposition. Abstract: The flux of atomic oxygen generated in a...

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Systems Modeling of Chemical Hydride Hydrogen Storage Materials for Fuel Cell Applications  

SciTech Connect (OSTI)

A fixed bed reactor was designed, modeled and simulated for hydrogen storage on-board the vehicle for PEM fuel cell applications. Ammonia Borane (AB) was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to {approx}16% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. The design evaluated consisted of a tank with 8 thermally isolated sections in which H2 flows freely between sections to provide ballast. Heating elements are used to initiate reactions in each section when pressure drops below a specified level in the tank. Reactor models in Excel and COMSOL were developed to demonstrate the proof-of-concept, which was then used to develop systems models in Matlab/Simulink. Experiments and drive cycle simulations showed that the storage system meets thirteen 2010 DOE targets in entirety and the remaining four at greater than 60% of the target.

Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; Holladay, Jamelyn D.

2011-10-05T23:59:59.000Z

242

Methodology of Materials Discovery in Complex Metal Hydrides Using Experimental and Computational Tools  

SciTech Connect (OSTI)

We present a review of the experimental and theoretical methods used in the discovery of new metal-hydrogen materials systems for hydrogen storage applications. Rather than a comprehensive review of all new materials and methods used in the metal hydride community, we focus on a specific subset of successful methods utilizing theoretical crystal structure prediction methods, computational approaches for screening large numbers of compound classes, and medium-throughput experimental methods for the preparation of such materials. Monte Carlo techniques paired with a simplified empirical Hamiltonian provide crystal structure candidates that are refined using Density Functional Theory. First-principle methods using high-quality structural candidates are further screened for an estimate of reaction energetics, decomposition enthalpies, and determination of reaction pathways. Experimental synthesis utilizes a compacted-pellet sintering technique under high-pressure hydrogen at elevated temperatures. Crystal structure determination follows from a combination of Rietveld refinements of diffraction patterns and first-principles computation of total energies and dynamical stability of competing structures. The methods presented within are general and applicable to a wide class of materials for energy storage.

Majzoub, Eric H.; Ronnebro, Ewa

2012-02-22T23:59:59.000Z

243

Hydride vapor phase epitaxy and characterization of high-quality ScN epilayers  

SciTech Connect (OSTI)

The heteroepitaxial growth of ScN films was investigated on various substrates by hydride vapor phase epitaxy (HVPE). Single crystalline mirror-like ScN(100) and ScN(110) layers were successfully deposited on r- and m-plane sapphire substrates, respectively. Homogeneous stoichiometric films (N/Sc ratio 1.01?±?0.10) up to 40??m in thickness were deposited. Their mosaicity drastically improved with increasing the film thickness. The band gap was determined by optical methods to be 2.06?eV. Impurity concentrations including H, C, O, Si, and Cl were investigated through energy dispersive X-ray spectrometry and secondary ion mass spectrometry. As a result, it was found that the presence of impurities was efficiently suppressed in comparison with that of HVPE-grown ScN films reported in the past, which was possible thanks to the home-designed corrosion-free HVPE reactor. Room-temperature Hall measurements indicated that the residual free electron concentrations ranged between 10{sup 18}–10{sup 20}?cm{sup ?3}, which was markedly lower than the reported values. The carrier mobility increased monotonically with the decreasing in carrier concentration, achieving the largest value ever reported, 284?cm{sup 2}?V{sup ?1}?s{sup ?1} at n?=?3.7?×?10{sup 18}?cm{sup ?3}.

Oshima, Yuichi, E-mail: OSHIMA.Yuichi@nims.go.jp; Víllora, Encarnación G.; Shimamura, Kiyoshi [Environment and Energy Materials Research Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

2014-04-21T23:59:59.000Z

244

Mixing effect of metal oxides on negative electrode reactions in the nickel-hydride battery  

SciTech Connect (OSTI)

Negative electrodes for use in nickel-hydride batteries were prepared from MmNi[sub 3.6]Mn[sub 0.4]Al[sub 0.3]Co[sub 0.7] (Mm = misch metal with the composition of 24.87% La, 52.56% Ce, 5.57% Pr, 16.86% Nd, and 0.14% Sm) alloy being mixed with RuO[sub 2] or Co[sub 3]O[sub 4] powder. Then the hydrogen evolution reactions at the electrodes were investigated by measuring the potential decay immediately after the interruption of an applied cathodic current. The reactions were found to proceed by the Volmer-Tafel mechanism. The total overvoltage ([eta]) was divided into two components ([eta][sub 1] and [eta][sub 2]) corresponding to the Tafel and Volmer reactions. The exchange current densities of the elementary reactions, i[sub 0V] and i[sub 0T], were then evaluated by extrapolating the Tafel lines for [eta][sub 1] and [eta][sub 2]. The Volmer reaction is much more accelerated by surface modification with RuO[sub 2] or Co[sub 3]O[sub 4] powder than the Tafel reaction, which results in the enrichment of adsorbed hydrogen, leading to higher charging efficiency.

Iwakura, Chiaki; Matsuoka, Masao; Kohno, Tatsuoki (Univ. of Osaka Prefecture (Japan). Dept. of Applied Chemistry)

1994-09-01T23:59:59.000Z

245

Calculation of tin atomic data and plasma properties.  

SciTech Connect (OSTI)

This report reviews the major methods and techniques we use in generating basic atomic and plasma properties relevant to extreme ultraviolet (EUV) lithography applications. The basis of the work is the calculation of the atomic energy levels, transitions probabilities, and other atomic data by various methods, which differ in accuracy, completeness, and complication. Later on, we calculate the populations of atomic levels and ion states in plasmas by means of the collision-radiation equilibrium (CRE) model. The results of the CRE model are used as input to the thermodynamic functions, such as pressure and temperature from the internal energy and density (equation of state), electric resistance, thermal conduction, and other plasma properties. In addition, optical coefficients, such as emission and absorption coefficients, are generated to resolve a radiation transport equation (RTE). The capabilities of our approach are demonstrated by generating the required atomic and plasma properties for tin ions and plasma within the EUV region near 13.5 nm.

Morozov, V.; Tolkach, V.; Hassanein, A.

2005-08-26T23:59:59.000Z

246

ATOMS PEACE WAR Eisenhower  

Broader source: Energy.gov (indexed) [DOE]

ATOMS ATOMS PEACE WAR Eisenhower and the Atomic Energy Commission Richard G. Hewlett and lack M. Roll With a Foreword by Richard S. Kirkendall and an Essay on Sources by Roger M. Anders University of California Press Berkeley Los Angeles London Published 1989 by the University of California Press Berkeley and Los Angeles, California University of California Press, Ltd. London, England Prepared by the Atomic Energy Commission; work made for hire. Library of Congress Cataloging-in-Publication Data Hewlett, Richard G. Atoms for peace and war, 1953-1961. (California studies in the history of science) Bibliography: p. Includes index. 1. Nuclear energy-United States-History. 2. U.S. Atomic Energy Commission-History. 3. Eisenhower, Dwight D. (Dwight David), 1890-1969.

247

1. Generation 1 1. Generation  

E-Print Network [OSTI]

1. Generation 1 _________________________________________________________________________ 1. Generation Sound and vibrations or, in more general terms, oscillations of matter (solids or fluids) are generated in many different dynamic processes. The basic mechanisms which underlie these oscillations

Berlin,Technische Universität

248

Accelerated guided atomic pulse  

Science Journals Connector (OSTI)

The deleterious effects of dispersion on a propagating coherent atomic pulse, along the axis of a traveling-wave laser beam, can be ameliorated by the nonlinear self-interacting force due to dipole-dipole coupling between atoms. We show that a wide atomic pulse with a particular profile can retain its shape during propagation and, moreover, the momentum of the pulse increases due to photon absorption. For the wide soliton case, we demonstrate analytically that the self-interacting atomic force scales inversely with the third power of the pulse width.

S. Dyrting; Weiping Zhang; B. C. Sanders

1997-09-01T23:59:59.000Z

249

Atomic Collapse Observed  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Scientists Observe Atomic Collapse State Quantum Mechanics Prediction Confirmed in Graphene Using NERSC's Hopper April 26, 2013 | Tags: Hopper, Materials Science Contact: Linda...

250

Multiplicative Sets of Atoms.  

E-Print Network [OSTI]

??It is possible for an element to have both an atom factorization and a factorization that will always contain a reducible element. This leads us… (more)

Rand, Ashley Nicole

2013-01-01T23:59:59.000Z

251

Improved graphite furnace atomizer  

DOE Patents [OSTI]

A graphite furnace atomizer for use in graphite furnace atomic absorption spectroscopy is described wherein the heating elements are affixed near the optical path and away from the point of sample deposition, so that when the sample is volatilized the spectroscopic temperature at the optical path is at least that of the volatilization temperature, whereby analyteconcomitant complex formation is advantageously reduced. The atomizer may be elongated along its axis to increase the distance between the optical path and the sample deposition point. Also, the atomizer may be elongated along the axis of the optical path, whereby its analytical sensitivity is greatly increased.

Siemer, D.D.

1983-05-18T23:59:59.000Z

252

Atom Nano-Optics  

Science Journals Connector (OSTI)

Nanolocalized light fields composed of photon dots and photon holes are being used to control the motion of atoms on a nanometer spatial scale.

Balykin, Victor; Klimov, Vasilii; Letokhov, Vladilen

2005-01-01T23:59:59.000Z

253

Atoms for Peace Awards  

Science Journals Connector (OSTI)

... Technology, is to be chairman of the Organization and Planning Committee of Atoms for Peace Awards. In addition to Dr. Killian, the Committee will include Dr. Detlev W. ... and Dr. Alan Waterman, director of the National Science Foundation. The Atoms for Peace Awards, it will be recalled, were established last summer as a memorial to Henry Ford ...

1955-10-29T23:59:59.000Z

254

Hirshfeld atom refinement  

Science Journals Connector (OSTI)

The new automated iterative Hirshfeld atom refinement method is explained and validated through comparison of structural models of Gly-L-Ala obtained from synchrotron X-ray and neutron diffraction data at 12, 50, 150 and 295 K. Structural parameters involving hydrogen atoms are determined with comparable precision from both experiments and agree mostly to within two combined standard uncertainties.

Capelli, S.C.

2014-08-29T23:59:59.000Z

255

A coupled transport and solid mechanics formulation with improved reaction kinetics parameters for modeling oxidation and decomposition in a uranium hydride bed.  

SciTech Connect (OSTI)

Modeling of reacting flows in porous media has become particularly important with the increased interest in hydrogen solid-storage beds. An advanced type of storage bed has been proposed that utilizes oxidation of uranium hydride to heat and decompose the hydride, releasing the hydrogen. To reduce the cost and time required to develop these systems experimentally, a valid computational model is required that simulates the reaction of uranium hydride and oxygen gas in a hydrogen storage bed using multiphysics finite element modeling. This SAND report discusses the advancements made in FY12 (since our last SAND report SAND2011-6939) to the model developed as a part of an ASC-P&EM project to address the shortcomings of the previous model. The model considers chemical reactions, heat transport, and mass transport within a hydride bed. Previously, the time-varying permeability and porosity were considered uniform. This led to discrepancies between the simulated results and experimental measurements. In this work, the effects of non-uniform changes in permeability and porosity due to phase and thermal expansion are accounted for. These expansions result in mechanical stresses that lead to bed deformation. To describe this, a simplified solid mechanics model for the local variation of permeability and porosity as a function of the local bed deformation is developed. By using this solid mechanics model, the agreement between our reacting bed model and the experimental data is improved. Additionally, more accurate uranium hydride oxidation kinetics parameters are obtained by fitting the experimental results from a pure uranium hydride oxidation measurement to the ones obtained from the coupled transport-solid mechanics model. Finally, the coupled transport-solid mechanics model governing equations and boundary conditions are summarized and recommendations are made for further development of ARIA and other Sandia codes in order for them to sufficiently implement the model.

Salloum, Maher N.; Shugard, Andrew D.; Kanouff, Michael P.; Gharagozloo, Patricia E.

2013-03-01T23:59:59.000Z

256

Atomic dark matter  

SciTech Connect (OSTI)

We propose that dark matter is dominantly comprised of atomic bound states. We build a simple model and map the parameter space that results in the early universe formation of hydrogen-like dark atoms. We find that atomic dark matter has interesting implications for cosmology as well as direct detection: Weak-scale dark atoms can accommodate hyperfine splittings of order 100 keV, consistent with the inelastic dark matter interpretation of the DAMA data while naturally evading direct detection bounds. Moreover, protohalo formation can be suppressed below M{sub proto} ? 10{sup 3}–10{sup 6}M{sub s}un for weak scale dark matter due to Ion-Radiation and Ion-Atom interactions in the dark sector.

Kaplan, David E.; Krnjaic, Gordan Z.; Rehermann, Keith R.; Wells, Christopher M., E-mail: dkaplan@pha.jhu.edu, E-mail: gordan@pha.jhu.edu, E-mail: keith@pha.jhu.edu, E-mail: cwells13@pha.jhu.edu [Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218-2686 (United States)

2010-05-01T23:59:59.000Z

257

Method and apparatus for atomic imaging  

DOE Patents [OSTI]

A method and apparatus for three dimensional imaging of the atomic environment of disordered adsorbate atoms are disclosed. The method includes detecting and measuring the intensity of a diffuse low energy electron diffraction pattern formed by directing a beam of low energy electrons against the surface of a crystal. Data corresponding to reconstructed amplitudes of a wave form is generated by operating on the intensity data. The data corresponding to the reconstructed amplitudes is capable of being displayed as a three dimensional image of an adsorbate atom. The apparatus includes a source of a beam of low energy electrons and a detector for detecting the intensity distribution of a DLEED pattern formed at the detector when the beam of low energy electrons is directed onto the surface of a crystal. A device responsive to the intensity distribution generates a signal corresponding to the distribution which represents a reconstructed amplitude of a wave form and is capable of being converted into a three dimensional image of the atomic environment of an adsorbate atom on the crystal surface.

Saldin, Dilano K. (Milwaukee, WI); de Andres Rodriquez, Pedro L. (Madrid, ES)

1993-01-01T23:59:59.000Z

258

Distributed Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Untapped Value of Backup Generation Untapped Value of Backup Generation While new guidelines and regulations such as IEEE (Institute of Electrical and Electronics Engineers) 1547 have come a long way in addressing interconnection standards for distributed generation, utilities have largely overlooked the untapped potential of these resources. Under certain conditions, these units (primarily backup generators) represent a significant source of power that can deliver utility services at lower costs than traditional centralized solutions. These backup generators exist today in large numbers and provide utilities with another option to reduce peak load, relieve transmission congestion, and improve power reliability. Backup generation is widely deployed across the United States. Carnegie Mellon's Electricity

259

Ultra compact direct hydrogen fuel cell prototype using a metal hydride hydrogen storage tank for a mobile phone  

Science Journals Connector (OSTI)

Abstract The small fuel cell is being researched as an alternative power source to the Li-ion battery in mobile phone. In this paper, a direct hydrogen fuel cell system which powers a mobile phone without a supplementary battery is compactly integrated below 25 ml volume at the backside of the phone. The system consists of a small (8 ml) metal hydride hydrogen storage tank with 4 L hydrogen storage or an energy density of ?640 W h/L, a thin air-breathing planar polymer electrolyte membrane fuel cell (PEMFC) stack (13.44 cm2 × 3 mm for a volumetric power density of 335 W/L), miniature pressure regulator, and a high efficiency DC–DC voltage converting circuitry. The hydrogen storage tank is packed with the AB5 type metal hydride alloy. The eight-cell air-breathing planar stack (8 ml) is very thin (3 mm) due to a thin flexible printed circuit board current collectors as well as a unique riveting assembly and is capable of a robust performance of 2.68 W (200 mW/cm2). A miniature pressure regulator is compact with fluidic and electrical connections within 4 ml. A miniature DC–DC voltage converter operates at an overall efficiency of 90%. Consequently, the estimated energy density of a fully integrated fuel cell system is 205 W h/L (70.5 W h/kg).

Sung Han Kim; Craig M. Miesse; Hee Bum Lee; Ik Whang Chang; Yong Sheen Hwang; Jae Hyuk Jang; Suk Won Cha

2014-01-01T23:59:59.000Z

260

Generation Planning (pbl/generation)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Generation Hydro Power Wind Power Monthly GSP BPA White Book Dry Year Tools Firstgov Generation Planning Thumbnail image of BPA White Book BPA White Book (1998 - 2011) Draft Dry...

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

general_atomics.cdr  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

former former General Atomics Hot Cell Facility was constructed in 1959 and operated until 1991. The site encompassed approximately 7,400 square feet of laboratory and remote operations cells. Licensed operations at the facility included receipt, handling, and shipment of radioactive materials; remote handling, examination, and storage of previously irradiated nuclear fuel materials; pilot-scale tritium extraction operations; and development, fabrication, and inspection of uranium oxide-beryllium oxide fuel materials. General Atomics performed most of the work for the federal government. The General Atomics Hot Cell Facility was located in a 60-acre complex 13 miles northwest of downtown San Diego, 1 mile inland from the Pacific Ocean, and approximately 300 feet above sea level. The General Atomics site is in the center of Torrey Mesa Science Center, a 304-acre industrial

262

Uncertainties on Atomic Data  

Science Journals Connector (OSTI)

Technical Paper / Selected papers from IAEA-NFRI Technical Meeting on Data Evaluation for Atomic, Molecular and Plasma-Material Interaction Processes in Fusion, September 4-7, 2012, Daejeon, Republic of Korea

C. P. Ballance; S. D. Loch; A. R. Foster; R. K. Smith; M. C. Witthoeft; T. R. Kallman

263

Relativistic Atomic Structure Calculations  

Science Journals Connector (OSTI)

This review surveys methods for computing the electronic structures of atoms based on the use of relativistic quantum mechanics. The main mathematical formulas are presented with some account of the underlying...

Ian P. Grant

1988-01-01T23:59:59.000Z

264

general_atomics.cdr  

Office of Legacy Management (LM)

300 feet above sea level. The General Atomics site is in the center of Torrey Mesa Science Center, a 304-acre industrial park. No ground water wells are at or near the Hot Cell...

265

The Harnessed Atom | Department of Energy  

Energy Savers [EERE]

Atom The Harnessed Atom The Harnessed Atom The Harnessed Atom is a new middle school science, technology, engineering, and math (STEM) curriculum extension that focuses on...

266

Optical imaging of Rydberg atoms .  

E-Print Network [OSTI]

??We present an experiment exploring electromagnetically induced transparency (EIT) in Rydberg atoms in order to observe optical nonlinearities at the single photon level. ??Rb atoms… (more)

Mazurenko, Anton

2012-01-01T23:59:59.000Z

267

Rydberg Atoms for Quantum Information.  

E-Print Network [OSTI]

??I examine interactions between ensembles of cold Rydberg atoms, and between Rydberg atoms and an intense, optical standing wave. Because of their strong electrostatic interactions,… (more)

Younge, Kelly Cooper

2010-01-01T23:59:59.000Z

268

Optical atomic magnetometer  

DOE Patents [OSTI]

An optical atomic magnetometers is provided operating on the principles of nonlinear magneto-optical rotation. An atomic vapor is optically pumped using linearly polarized modulated light. The vapor is then probed using a non-modulated linearly polarized light beam. The resulting modulation in polarization angle of the probe light is detected and used in a feedback loop to induce self-oscillation at the resonant frequency.

Budker, Dmitry; Higbie, James; Corsini, Eric P

2013-11-19T23:59:59.000Z

269

Metal atomization spray nozzle  

DOE Patents [OSTI]

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

Huxford, T.J.

1993-11-16T23:59:59.000Z

270

Model based design of an automotive-scale, metal hydride hydrogen storage system.  

SciTech Connect (OSTI)

Sandia and General Motors have successfully designed, fabricated, and experimentally operated a vehicle-scale hydrogen storage system using the complex metal hydride sodium alanate. Over the 6 year project, the team tackled the primary barriers associated with storage and delivery of hydrogen including mass, volume, efficiency and cost. The result was the hydrogen storage demonstration system design. The key technologies developed for this hydrogen storage system include optimal heat exchange designs, thermal properties enhancement, a unique catalytic hydrogen burner and energy efficient control schemes. The prototype system designed, built, and operated to demonstrate these technologies consists of four identical hydrogen storage modules with a total hydrogen capacity of 3 kg. Each module consists of twelve stainless steel tubes that contain the enhanced sodium alanate. The tubes are arranged in a staggered, 4 x 3 array and enclosed by a steel shell to form a shell and tube heat exchanger. Temperature control during hydrogen absorption and desorption is accomplished by circulating a heat transfer fluid through each module shell. For desorption, heat is provided by the catalytic oxidation of hydrogen within a high efficiency, compact heat exchanger. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to the circulating heat transfer fluid. The demonstration system module design and the system control strategies were enabled by experiment-based, computational simulations that included heat and mass transfer coupled with chemical kinetics. Module heat exchange systems were optimized using multi-dimensional models of coupled fluid dynamics and heat transfer. Chemical kinetics models were coupled with both heat and mass transfer calculations to design the sodium alanate vessels. Fluid flow distribution was a key aspect of the design for the hydrogen storage modules and computational simulations were used to balance heat transfer with fluid pressure requirements. An overview of the hydrogen storage system will be given, and examples of these models and simulation results will be described and related to component design. In addition, comparisons of demonstration system experimental results to model predictions will be reported.

Johnson, Terry Alan; Kanouff, Michael P.; Jorgensen, Scott W. (General Motors R& D); Dedrick, Daniel E.; Evans, Gregory Herbert

2010-11-01T23:59:59.000Z

271

Polar intermetallic compounds of the silicon and arsenic family elements and their ternary hydrides and fluorides  

SciTech Connect (OSTI)

An investigation has been made on the effects of hydrogen and fluoride in the solid state chemistry of alkaline-earth and divalent rare-earth metal pnictide (Pn) and tetrelide (Tt) phases A{sub 5}(Pn,Tt,){sub 3}Z{sub x}, where A = Ca, Sr, Ba, Sm, Eu, Yb; Pn = As, Sb, Bi; Tt = Si, Ge, Sn, Pb and Z = H, F. Several trivalent rare-earth-metal pnictides, RE{sub 5}Pn{sub 3} (RE = Y, La, Gd, Tb, Dy, Ho, Er, Tm) and alkaline-earth-metal trielides, A{sub 5}Tr{sub 3}Z{sub x} (Tr = Ga, In, Tl) have been included in an effort to complete observed structural trends. Two main experimental techniques were followed throughout this work, (a) reactions in absence of hydrogen or under continuous high vacuum, and (b) reactions with binary metal hydrides, AH{sub x}, in closed containers. The results demonstrate that all the phases reported with the {beta}-Yb{sub 5}Sb{sub 3}-type structure in the A{sub 5}Pn{sub 3} systems are hydrogen-stabilized compounds. Reactions in absence of hydrogen lead to compounds with the Mn{sub 5}Si{sub 3}-type structure. The structure type {beta}-Yb{sub 5}Sb{sub 3} (= Ca{sub 5}SB{sub 3}F) was found to be characteristic of ternary systems and inaccurately associated with phases that form in the Y{sub 5}Bi{sub 3}-type. A new series of isomorphous Zintl compounds with the Ca{sub 16}Sb{sub 11}-type structure were prepared and studied as well. All the alkaline-earth-metal tetrelides, A{sub 5}Tt{sub 3}, that crystallize in the Cr{sub 5}B{sub 3}-type structure can be interstitially derivatized by hydrogen or fluoride. Binary and ternary compounds were characterized by Guinier powder patterns, single crystal X-ray and powder neutron diffraction techniques. In an effort to establish property-structure relationships, electrical resistivity and magnetic measurements were performed on selected systems, and the results were explained in terms of the Zintl concepts, aided by extended Hueckel band calculations.

Leon-Escamilla, E.A.

1996-10-17T23:59:59.000Z

272

Trapping cold atoms using surface-grown carbon nanotubes P. G. Petrov,1,* S. Machluf,1  

E-Print Network [OSTI]

Trapping cold atoms using surface-grown carbon nanotubes P. G. Petrov,1,* S. Machluf,1 S. Younis,1 atomic clouds into magnetic traps created by single-wall carbon nanotubes grown directly onto dielectric surfaces. We show that atoms may be captured for experimen- tally sustainable nanotube currents, generating

Joselevich, Ernesto

273

Determination of Tellurium by Atomic-absorption Spectroscopy with Electrothermal Atomisation  

E-Print Network [OSTI]

305 Determination of Tellurium by Atomic-absorption Spectroscopy with Electrothermal Atomisation at sub-microgram levels by atomic-absorption spectroscopy ,,'ith electrothermal atomisation after the e generation -atomic-absorption spectroscopy. The prior con- version of tellurium into hydrogen telluride

Canberra, University of

274

Atomic mass compilation 2012  

SciTech Connect (OSTI)

Atomic mass reflects the total binding energy of all nucleons in an atomic nucleus. Compilations and evaluations of atomic masses and derived quantities, such as neutron or proton separation energies, are indispensable tools for research and applications. In the last decade, the field has evolved rapidly after the advent of new production and measuring techniques for stable and unstable nuclei resulting in substantial ameliorations concerning the body of data and their precision. Here, we present a compilation of atomic masses comprising the data from the evaluation of 2003 as well as the results of new measurements performed. The relevant literature in refereed journals and reports as far as available, was scanned for the period beginning 2003 up to and including April 2012. Overall, 5750 new data points have been collected. Recommended values for the relative atomic masses have been derived and a comparison with the 2003 Atomic Mass Evaluation has been performed. This work has been carried out in collaboration with and as a contribution to the European Nuclear Structure and Decay Data Network of Evaluations.

Pfeiffer, B., E-mail: bpfeiffe@uni-mainz.de [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); Venkataramaniah, K. [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India)] [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India); Czok, U. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)] [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); Scheidenberger, C. [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany) [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)

2014-03-15T23:59:59.000Z

275

Standard Model tests with trapped radioactive atoms  

E-Print Network [OSTI]

We review the use of laser cooling and trapping for Standard Model tests, focusing on trapping of radioactive isotopes. Experiments with neutral atoms trapped with modern laser cooling techniques are testing several basic predictions of electroweak unification. For nuclear $\\beta$ decay, demonstrated trap techniques include neutrino momentum measurements from beta-recoil coincidences, along with methods to produce highly polarized samples. These techniques have set the best general constraints on non-Standard Model scalar interactions in the first generation of particles. They also have the promise to test whether parity symmetry is maximally violated, to search for tensor interactions, and to search for new sources of time reversal violation. There are also possibilites for exotic particle searches. Measurements of the strength of the weak neutral current can be assisted by precision atomic experiments using traps of small numbers of radioactive atoms, and sensitivity to possible time-reversal violating electric dipole moments can be improved.

J. A. Behr; G. Gwinner

2009-03-04T23:59:59.000Z

276

Identification of a new pseudo-binary hydroxide during calendar corrosion of (La, Mg)2Ni7-type hydrogen storage alloys for Nickel-Metal Hydride batteries  

E-Print Network [OSTI]

hydrogen storage alloys for Nickel-Metal Hydride batteries J. Monnier 1 , H. Chen 1 , S. Joiret2,3 , J present higher hydrogen storage capacity and higher discharge capacity, eg. 356mAh/g for LaCaMgNi9 [4 in the huge market of hybrid electric vehicles (HEV) and Emergency Light Units (ELU). Hydrogen

Boyer, Edmond

277

Sensing mode atomic force microscope  

DOE Patents [OSTI]

An atomic force microscope utilizes a pulse release system and improved method of operation to minimize contact forces between a probe tip affixed to a flexible cantilever and a specimen being measured. The pulse release system includes a magnetic particle affixed proximate the probe tip and an electromagnetic coil. When energized, the electromagnetic coil generates a magnetic field which applies a driving force on the magnetic particle sufficient to overcome adhesive forces exhibited between the probe tip and specimen. The atomic force microscope includes two independently displaceable piezo elements operable along a Z-axis. A controller drives the first Z-axis piezo element to provide a controlled approach between the probe tip and specimen up to a point of contact between the probe tip and specimen. The controller then drives the first Z-axis piezo element to withdraw the cantilever from the specimen. The controller also activates the pulse release system which drives the probe tip away from the specimen during withdrawal. Following withdrawal, the controller adjusts the height of the second Z-axis piezo element to maintain a substantially constant approach distance between successive samples.

Hough, Paul V. C. (Port Jefferson, NY); Wang, Chengpu (Upton, NY)

2003-01-01T23:59:59.000Z

278

Peaceful Uses of the Atom and Atoms for Peace  

Office of Scientific and Technical Information (OSTI)

Peaceful Uses of the Atom Peaceful Uses of the Atom Fermi and Atoms for Peace · Understanding the Atom · Seaborg · Teller Atoms for Peace Atoms for Peace + 50 - Conference, October 22, 2003 Celebrating the 50th anniversary of President Eisenhower's "Atoms for Peace" speech to the UN General Assembly Atoms for Peace (video 12:00 Minutes) Atoms for Peace Address given by Dwight D. Eisenhower before the General Assembly of the United Nations, New York City, December 8, 1953 Documents: Atomic Power in Space: A History A history of the Space Isotope Power Program of the United States from the mid-1950s through 1982; interplanetary space exploration successes and achievements have been made possible by this technology. Establishing Site X: Letter, Arthur H. Compton to Enrico Fermi, September 14, 1942

279

Lesson 3- Atoms and Isotopes  

Broader source: Energy.gov [DOE]

You’ve probably heard people refer to nuclear energy as “atomic energy.” Why? Nuclear energy is the energy that is stored in the bonds of atoms, inside the nucleus. Nuclear power plants are designed to capture this energy as heat and convert it to electricity. This lesson looks closely at what atoms are and how atoms store energy.

280

Educational Multiwavelength Atomic Emission Spectrometer  

E-Print Network [OSTI]

atomic absorption is the capability for simultaneous multielement analysis. It can be used colleges had acquired atomic absorption instruments by the year 1990.[2] In contrast, atomic emission with the acetylene-air flame source taken from an existing atomic absorption instrument. Two spectrometer units

Nazarenko, Alexander

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

general_atomics.cdr  

Office of Legacy Management (LM)

former General former General Atomics Hot Cell Facility was constructed in 1959 and operated until 1991. The site encompassed approximately 7,400 square feet of laboratory and remote operations cells. Licensed operations at the facility included receipt, handling, and shipment of radioactive materials; remote handling, examination, and storage of previously irradiated nuclear fuel materials; pilot-scale tritium extraction operations; and development, fabrication, and inspection of uranium oxide-beryllium oxide fuel materials. General Atomics performed most of the work for the federal government. The General Atomics Hot Cell Facility was located in a 60-acre complex 13 miles northwest of downtown San Diego, 1 mile inland from the Pacific Ocean, and approximately 300 feet above sea level.

282

Iowa Powder Atomization Technologies  

SciTech Connect (OSTI)

The same atomization effect seen in a fuel injector is being applied to titanium metal resulting in fine titanium powders that are less than half the width of a human hair. Titanium melts above 3,000°F and is highly corrosive therefore requiring specialized containers. The liquid titanium is poured through an Ames Laboratory - USDOE patented tube which is intended to increase the energy efficiency of the atomization process, which has the ability to dramatically decrease the cost of fine titanium powders. This novel process could open markets for green manufacturing of titanium components from jet engines to biomedical implants.

None

2012-01-01T23:59:59.000Z

283

Atomic Josephson vortices  

SciTech Connect (OSTI)

We show that Josephson vortices in a quasi-one-dimensional atomic Bose Josephson junction can be controllably manipulated by imposing a difference of chemical potentials on the atomic Bose-Einstein condensate waveguides forming the junction. This effect, which has its origin in the Berry phase structure of a vortex, turns out to be very robust in the whole range of the parameters where such vortices can exist. We also propose that a Josephson vortex can be created by the phase imprinting technique and can be identified by a specific tangential feature in the interference picture produced by expanding clouds released from the waveguides.

Kaurov, V. M.; Kuklov, A. B. [Department of Engineering Science and Physics, College of Staten Island, CUNY, Staten Island, New York 10314 (United States)

2006-01-15T23:59:59.000Z

284

Atomic Force Microscope  

SciTech Connect (OSTI)

The Atomic Force Microscope (AFM) is a recently developed instrument that has achieved atomic resolution imaging of both conducting and non- conducting surfaces. Because the AFM is in the early stages of development, and because of the difficulty of building the instrument, it is currently in use in fewer than ten laboratories worldwide. It promises to be a valuable tool for obtaining information about engineering surfaces and aiding the .study of precision fabrication processes. This paper gives an overview of AFM technology and presents plans to build an instrument designed to look at engineering surfaces.

Day, R.D.; Russell, P.E.

1988-12-01T23:59:59.000Z

285

Lightweight Metal Hydrides for Hydrogen Storage - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Ji-Cheng Zhao (Primary Contact), Xuenian Chen, Sheldon G. Shore The Ohio State University, Department of Materials Science and Engineering, 286 Watts Hall, 2041 College Road Columbus, OH 43210 Phone: (614) 292-9462 Email: zhao.199@osu.edu DOE Managers HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FC3605GO15062 Project Start Date: January 1, 2005 Project End Date: August 31, 2011 (No-cost extension to December 31, 2012) Fiscal Year (FY) 2012 Objectives Develop a high-capacity lightweight hydride for * reversible vehicular hydrogen storage, capable of meeting or exceeding the 2010 DOE FreedomCAR

286

The influence of prestrained metalorganic vapor phase epitaxial gallium-nitride templates on hydride vapor phase epitaxial growth  

Science Journals Connector (OSTI)

We have varied the strain situation in metalorganic vapor phase epitaxial (MOVPE) grown gallium-nitride (GaN) by exchanging the nucleation layer and by inserting a submono-Si x N y -interlayer in the first few hundred nanometers of growth on sapphire substrates. The influence on the MOVPE template and subsequent hydride vapor phase epitaxial (HVPE) growth could be shown by in-situ measurements of the sample curvature. Using the results of these investigations we have established a procedure to confine the curvature development in MOVPE and HVPE growth to a minimum. By increasing the layer thickness in HVPE we could create self-separated freestanding GaN layers with small remaining curvature.

2014-01-01T23:59:59.000Z

287

A unified view of coherent and incoherent dihydrogen exchange in transition metal hydrides by nuclear resonance and inelastic neutron scattering  

SciTech Connect (OSTI)

In this paper a unified view of coherent and incoherent dihydrogen exchange in transition metal hydrides by nuclear magnetic resonance (NMR) and inelastic neutron scattering (INS) is presented. It is shown that both exchange processes coexist i.e. do not transform into each other although they may dominate the spectra in different temperature ranges. This superposition is the consequence of the incorporation of the tunnel frequency J of the coherent process into the nuclear two-spin hamiltonian of hydrogen pairs which allows to treat the problem using the well known density matrix theory of NMR line-shapes developed by Alexander and Binsch. It is shown that this theory can also be used to predict the line-shapes of the rotational tunneling transitions observed in the INS spectra of transition metal dihydrogen complexes and that both NMR and INS spectra depend on similar parameters.

Limbach, H.H.; Ulrich, S.; Buntkowsky, G. [Freie Univ. Berlin (Germany). Inst. fuer Organische Chemie; Sabo-Etienne, S.; Chaudret, B. [Toulouse-3 Univ., 31 (France). Lab. de Chimie de Coordination du C.N.R.S.; Kubas, G.J.; Eckert, J. [Los Alamos National Lab., NM (United States)

1995-08-12T23:59:59.000Z

288

Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density  

SciTech Connect (OSTI)

Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?°C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

2014-07-01T23:59:59.000Z

289

Thermoelectric Generators 1. Thermoelectric generator  

E-Print Network [OSTI]

. Cold Hot I - -- - - - - -- Figure 1 Electron concentration in a thermoelectric material. #12;2 A large1 Thermoelectric Generators HoSung Lee 1. Thermoelectric generator 1.1 Basic Equations In 1821 on the direction of current and material [3]. This is called the Thomson effect (or Thomson heat). These three

Lee, Ho Sung

290

Quasiseparable Generators  

Science Journals Connector (OSTI)

It is clear from the preceding chapter that any matrix has quasiseparable representations. By padding given quasiseparable generators with zero matrices of large sizes one ... large orders. However, one is lookin...

Yuli Eidelman; Israel Gohberg…

2014-01-01T23:59:59.000Z

291

Atomic Scientists Brief Congress  

Science Journals Connector (OSTI)

Topics covered included underground explosions to produce energy, chemicals, or petroleum; advanced reactors capable of producing chemicals; atomic power for space propulsion; direct conversion of heat energy to electricity; and controlled thermonuclear reactions. ... (For details on controlled fusion research see page 46.) ...

1960-04-04T23:59:59.000Z

292

Atomic Power in Japan  

Science Journals Connector (OSTI)

NUCLEAR ENERGY will provide most of the power requirements in Japan by the end of this century. So predicts Charles H. Weaver, vice president in charge of atomic power activities for Westinghouse Electric.Addressing the Conference on Peaceful Uses of ...

1957-05-27T23:59:59.000Z

293

Bohr's model: Extreme atoms  

Science Journals Connector (OSTI)

... by bombarding atoms with accelerated protons, then slow them down by passing them through metallic foil, cool them with cold electrons and trap them with electromagnetic fields. A similar trap ... Curiosity and national pride undoubtedly have a role, with politicians and scientists both looking to stamp their country's name into a new box on the periodic table. But each ...

Richard Van Noorden

2013-06-05T23:59:59.000Z

294

Magnetism and Atomic Structure  

Science Journals Connector (OSTI)

... the information with regard to the atom has been obtained by studying spectra; chemistry, magnetism, X-ray scattering, etc., play only a subsidiary part. We must admit, ... for fresh sources of information. Much may be said in support of the opinion that magnetism will open a new way by which to approach the study of the structure of ...

P. KAPITZA

1927-06-04T23:59:59.000Z

295

Generation of thermonuclear energy by fusing hydrogen and lithium atoms  

Science Journals Connector (OSTI)

A method of designing a thermonuclear reactor based on the modified Cockroft-Walton accelerator, where the lithium-proton fusion was first observed, is considered. It...15 W/cm2...to the cathode are determined. T...

V. E. Tyrsa; L. P. Burtseva

2003-07-01T23:59:59.000Z

296

Transmission-line decelerators for atoms in high Rydberg states  

E-Print Network [OSTI]

Beams of helium atoms in Rydberg states with principal quantum number $n=52$, and traveling with an initial speed of 1950 m/s, have been accelerated, decelerated and guided while confined in moving electric traps generated above a curved, surface-based electrical transmission line with a segmented center conductor. Experiments have been performed with atoms guided at constant speed, and with accelerations exceeding $10^7$ m/s$^2$. In each case the manipulated atoms were detected by spatially resolved, pulsed electric field ionization. The effects of tangential and centripetal accelerations on the effective trapping potentials experienced by the atoms in the decelerator have been studied, with the resulting observations highlighting contributions from the density of excited Rydberg atoms to the acceleration, deceleration and guiding efficiencies in the experiments.

Lancuba, P

2014-01-01T23:59:59.000Z

297

A Multi-Path Interferometer on an Atom Chip  

E-Print Network [OSTI]

Cold-atom interferometry is a powerful tool for high-precision measurements of the quantum properties of atoms, many-body interactions and gravity. Further enhancement of sensitivity and reduction of complexity of these devices are crucial conditions for success of their applications. Here we introduce a multi-path interferometric scheme that offers advances in both these aspects. It uses coherent coupling between Bose-Einstein condensates in different Zeeman states to generate an interferometric signal with sharp fringes. We realise such an interferometer as a compact easy-to-use atom-chip device and thus provide an alternative method for measurement of the light-atom and surface-atom interactions.

Jovana Petrovic; Ivan Herrera; Pietro Lombardi; Francesco S. Cataliotti

2011-11-18T23:59:59.000Z

298

A Multi-Path Interferometer on an Atom Chip  

E-Print Network [OSTI]

Cold-atom interferometry is a powerful tool for high-precision measurements of the quantum properties of atoms, many-body interactions and gravity. Further enhancement of sensitivity and reduction of complexity of these devices are crucial conditions for success of their applications. Here we introduce a multi-path interferometric scheme that offers advances in both these aspects. It uses coherent coupling between Bose-Einstein condensates in different Zeeman states to generate an interferometric signal with sharp fringes. We realise such an interferometer as a compact easy-to-use atom-chip device and thus provide an alternative method for measurement of the light-atom and surface-atom interactions.

Petrovic, Jovana; Lombardi, Pietro; Cataliotti, Francesco S

2011-01-01T23:59:59.000Z

299

Photon statistics of atomic fluorescence after {pi}-pulse excitation  

SciTech Connect (OSTI)

The photon statistics of atomic fluorescence after {pi}-pulse excitation is investigated in a system in which the input and output ports are connected to an atom. Since spontaneous decay during input pulse excitation occurs, the output pulse generally contains a multiphoton component with a certain probability. We quantitatively evaluate the probability of the output pulse containing multiple photons and determine the conditions for ideal single-photon generation.

Yoshimi, Kazuyoshi [College of Liberal Arts and Sciences, Tokyo Medical and Dental University, Ichikawa, Chiba 272-0827 (Japan); Koshino, Kazuki [College of Liberal Arts and Sciences, Tokyo Medical and Dental University, Ichikawa, Chiba 272-0827 (Japan); PRESTO, Japan Science and Technology Agency, Kawaguchi, Saitama 332-0012 (Japan)

2010-09-15T23:59:59.000Z

300

High Rydberg Atoms: Newcomers to the Atomic Physics Scene  

Science Journals Connector (OSTI)

...HYDROGEN ATOM, NUCLEAR FUSION 5 : 41 ( 1965 ). BAYFIELD...HIGHLY-EXCITED KR ATOMS BY HF AND HCL MOLECULES, BULLETIN...USING A CW TUNABLE DYE LASER, PHYSICAL REVIEW LETTERS...such diverse fields as laser development, laser isotopeseparation, energy...

Ronald F. Stebbings

1976-08-13T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Storage rings for investigation of ion-atom collisions  

SciTech Connect (OSTI)

In this survey, we give a brief description of synchrotron storage rings for heavy ions, and examples for their use in ion-atom collision physics. The compression of the phase space distribution of the ions by electron cooling, and the gain factors of in-ring experiments compared to single-pass experiments are explained. Some examples of a new generation of ion-atom collision experiments which may become feasible with storage rings are given. These include the studies of angular differential single- and double-electron capture cross sections, the production of slow highly charged recoil ions, and atomic collision processes using decelerated and crossed beam. 30 refs.

Schuch, R.

1987-08-01T23:59:59.000Z

302

Emission spectrum of the atomic chain excited by channeled particle  

E-Print Network [OSTI]

Basic properties of radiation of the atomic chains excited by a channeled particle are considered. Using a very simple two-dimensional model of a crystal lattice we have shown that the main part of this radiation is generated on the frequency of oscillations of a channeled particle between the crystal planes, shifted by the Doppler effect. Spectral and angular distribution and spectral distribution of the radiation of the atomic chain excited by channeled particle were calculated. Emission spectrum of the atomic chain excited by channeled particle was plotted.

Epp, V

2014-01-01T23:59:59.000Z

303

Subwavelength atom localization via quantum coherence in a three-level atomic system  

SciTech Connect (OSTI)

We propose a three-level atomic system where quantum coherence is generated by a classical standing-wave field coupled to the two upper excited decaying levels. Quantum coherence results in cancellation of the spontaneously emitted spectral lines depending on the choice of the phase of the standing wave. We exploit this phenomenon for precision measurement of the atomic position in the standing wave. Measurement of the conditional position probability distribution shows one to eight peaks per unit wavelength of the standing wave. Only one controllable parameter, that is, the phase of the driving standing wave, is enough to control these atomic positions. Along with the other results, the result of obtaining a single peak is remarkable as it enhances the efficiency of our system by a factor of 8.

Ghafoor, Fazal [Centre for Quantum Physics, COMSATS Institute of Information Technology, Islamabad (Pakistan)

2011-12-15T23:59:59.000Z

304

Microwave generator  

DOE Patents [OSTI]

A microwave generator is provided for generating microwaves substantially from virtual cathode oscillation. Electrons are emitted from a cathode and accelerated to an anode which is spaced apart from the cathode. The anode has an annular slit there through effective to form the virtual cathode. The anode is at least one range thickness relative to electrons reflecting from the virtual cathode. A magnet is provided to produce an optimum magnetic field having the field strength effective to form an annular beam from the emitted electrons in substantial alignment with the annular anode slit. The magnetic field, however, does permit the reflected electrons to axially diverge from the annular beam. The reflected electrons are absorbed by the anode in returning to the real cathode, such that substantially no reflexing electrons occur. The resulting microwaves are produced with a single dominant mode and are substantially monochromatic relative to conventional virtual cathode microwave generators. 6 figs.

Kwan, T.J.T.; Snell, C.M.

1987-03-31T23:59:59.000Z

305

Optical imaging of Rydberg atoms  

E-Print Network [OSTI]

We present an experiment exploring electromagnetically induced transparency (EIT) in Rydberg atoms in order to observe optical nonlinearities at the single photon level. ??Rb atoms are trapped and cooled using a magneto-optical ...

Mazurenko, Anton

2012-01-01T23:59:59.000Z

306

Seaborg Predicts Bright Atomic Future  

Science Journals Connector (OSTI)

Seaborg Predicts Bright Atomic Future ... To explore both the immediate and long-term ramifications of the cutbacks, C&EN talked to the Chairman of the Atomic Energy Commission, Dr. Glenn T. Seaborg . ...

1964-06-15T23:59:59.000Z

307

Parametric Amplification of Scattered Atom Pairs Gretchen K. Campbell, Jongchul Mun, Micah Boyd, Erik W. Streed, Wolfgang Ketterle, and David E. Pritchard*  

E-Print Network [OSTI]

and the atom- optics analog of optical parametric generation. Phase matching is essential for high efficiency parametric generation and amplification of ultracold atom pairs. A 87Rb Bose- Einstein condensate was loaded and amplification of photons and could be used to efficiently create entangled pairs of atoms. Furthermore

308

Single-atom cavity QED and optomicromechanics  

SciTech Connect (OSTI)

In a recent publication [K. Hammerer, M. Wallquist, C. Genes, M. Ludwig, F. Marquardt, P. Treutlein, P. Zoller, J. Ye, and H. J. Kimble, Phys. Rev. Lett. 103, 063005 (2009)] we have shown the possibility to achieve strong coupling of the quantized motion of a micron-sized mechanical system to the motion of a single trapped atom. In the proposed setup the coherent coupling between a SiN membrane and a single atom is mediated by the field of a high finesse cavity and can be much larger than the relevant decoherence rates. This makes the well-developed tools of cavity quantum electrodynamics with single atoms available in the realm of cavity optomechanics. In this article we elaborate on this scheme and provide detailed derivations and technical comments. Moreover, we give numerical as well as analytical results for a number of possible applications for transfer of squeezed or Fock states from atom to membrane as well as entanglement generation, taking full account of dissipation. In the limit of strong-coupling the preparation and verification of nonclassical states of a mesoscopic mechanical system is within reach.

Wallquist, M.; Hammerer, K.; Zoller, P.; Genes, C.; Ludwig, M.; Marquardt, F.; Treutlein, P.; Ye, J.; Kimble, H. J. [Institute for Theoretical Physics, University of Innsbruck, and Institute for Quantum Optics and Quantum Communication, Austrian Academy of Sciences, Technikerstrasse 25, 6020 Innsbruck, Austria and Norman Bridge Laboratory of Physics 12-33, California Institute of Technology, Pasadena, California 91125 (United States); Institute for Theoretical Physics, University of Innsbruck, and Institute for Quantum Optics and Quantum Communication, Austrian Academy of Sciences, Technikerstrasse 25, 6020 Innsbruck (Austria); Department of Physics, Center for NanoScience, and Arnold Sommerfeld Center for Theoretical Physics, Ludwig-Maximilians-Universitaet Muenchen, Theresienstr. 37, D-80333 Munich (Germany); Max-Planck-Institute of Quantum Optics and Department of Physics, Ludwig-Maximilians-Universitaet Muenchen, Schellingstr. 4, D-80799 Munich (Germany); JILA, National Institute of Standards and Technology and University of Colorado, Boulder, Colorado 80309-0440, USA and Norman Bridge Laboratory of Physics 12-33, California Institute of Technology, Pasadena, California 91125 (United States); Norman Bridge Laboratory of Physics 12-33, California Institute of Technology, Pasadena, California 91125 (United States)

2010-02-15T23:59:59.000Z

309

Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Executive Summaries Executive Summaries for the Hydrogen Storage Materials Centers of Excellence Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Period of Performance: 2005-2010 Fuel Cell Technologies Program Office of Energy Efficiency and Renewable Energy U. S. Department of Energy April 2012 2 3 Primary Authors: Chemical Hydrogen Storage (CHSCoE): Kevin Ott, Los Alamos National Laboratory Hydrogen Sorption (HSCoE): Lin Simpson, National Renewable Energy Laboratory Metal Hydride (MHCoE): Lennie Klebanoff, Sandia National Laboratory Contributors include members of the three Materials Centers of Excellence and the Department of Energy Hydrogen Storage Team in the Office of Energy Efficiency and Renewable Energy's Fuel Cell Technologies Program.

310

THE BIRTH OF NUCLEAR-GENERATED ELECTRICITY  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BIRTH OF NUCLEAR-GENERATED ELECTRICITY BIRTH OF NUCLEAR-GENERATED ELECTRICITY The first time that electricity was generated from nuclear energy occurred in an experimental breeder reactor in Idaho in 1951. The idea for a breeder reactor (a reactor that could produce more fuel than it uses) first occurred to scientists working on the nation's wartime atomic energy program in the early 1940's. Experimental evidence indicated that the breeding of nuclear fuel was possible in a properly designed reactor, but time and resources were not then available to pursue the idea After the war, the newly established Atomic Energy Commission (now the Department of Energy) assigned some of the nation's nuclear skills and resources to developing peaceful uses of the atom. The large bodies of uranium ore found in the 1950's were

311

Appendix G: Radiation HYDROGEN ATOM  

E-Print Network [OSTI]

. People are exposed to naturally occurring radiation constantly. For example, cosmic radiation; radon effects on the environment and biological systems. Radiation comes from natural and human-made sourcesAppendix G: Radiation #12;#12;P P P E E E N NN HYDROGEN ATOM DEUTERIUM ATOM TRITIUM ATOM HYDROGEN

Pennycook, Steve

312

Appendix A: Radiation HYDROGEN ATOM  

E-Print Network [OSTI]

. People are exposed to naturally occurring radiation constantly. For example, cosmic radiation; radon effects on the environment and biological systems. Radiation comes from natural and human-made sourcesAppendix A: Radiation #12;P P P E E E N NN HYDROGEN ATOM DEUTERIUM ATOM TRITIUM ATOM HYDROGEN

Pennycook, Steve

313

Recent Progress in ultracold atoms  

E-Print Network [OSTI]

and Einstein What is Bose-Einstein condensation (BEC)? #12;300 K to 1 mK 109 atoms 1 mK to 1 mK 108 106 atoms How to make a BEC: Cool atoms at ultra low temperature Laser beams Fluorescence Laser cooling (Doppler

Baltisberger, Jay H.

314

Synthesis of poly(vinyl alcohol)-graft-poly(-caprolactone) and poly(vinyl alcohol)-graft-poly(lactide) in melt with magnesium hydride as catalyst  

E-Print Network [OSTI]

)-graft-poly(lactide) in melt with magnesium hydride as catalyst Nadia Guerrouani, André Mas* , François Schué UMR 5253 CNRS-UM2%) was investigated using MgH2 environmental catalyst and melt-grown ring opening polymerization (ROP) of -caprolactone (CL) and L- lactide (LA), that avoiding undesirable toxic catalyst and solvent. The ability of Mg

Paris-Sud XI, Université de

315

VARIOUS APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY  

E-Print Network [OSTI]

APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPYthe Zeeman effect to atomic absorption spectroscopy has beenthe Zeeman effect on atomic absorption spectrometry has been

Koizumi, Hideaki

2011-01-01T23:59:59.000Z

316

Hydrogen atom in Palatini theories of gravity  

E-Print Network [OSTI]

We study the effects that the gravitational interaction of $f(R)$ theories of gravity in Palatini formalism has on the stationary states of the Hydrogen atom. We show that the role of gravity in this system is very important for lagrangians $f(R)$ with terms that grow at low curvatures, which have been proposed to explain the accelerated expansion rate of the universe. We find that new gravitationally induced terms in the atomic Hamiltonian generate a strong backreaction that is incompatible with the very existence of bound states. In fact, in the 1/R model, Hydrogen disintegrates in less than two hours. The universe that we observe is, therefore, incompatible with that kind of gravitational interaction. Lagrangians with high curvature corrections do not lead to such instabilities.

Gonzalo J. Olmo

2008-06-03T23:59:59.000Z

317

Magnetocumulative generator  

DOE Patents [OSTI]

An improved magnetocumulative generator is described that is useful for producing magnetic fields of very high energy content over large spatial volumes. The polar directed pleated magnetocumulative generator has a housing providing a housing chamber with an electrically conducting surface. The chamber forms a coaxial system having a small radius portion and a large radius portion. When a magnetic field is injected into the chamber, from an external source, most of the magnetic flux associated therewith positions itself in the small radius portion. The propagation of an explosive detonation through high-explosive layers disposed adjacent to the housing causes a phased closure of the chamber which sweeps most of the magnetic flux into the large radius portion of the coaxial system. The energy content of the magnetic field is greatly increased by flux stretching as well as by flux compression. The energy enhanced magnetic field is utilized within the housing chamber itself.

Pettibone, J.S.; Wheeler, P.C.

1981-06-08T23:59:59.000Z

318

Monthly Generation System Peak (pbl/generation)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Generation > Generation Hydro Power Wind Power Monthly GSP BPA White Book Dry Year Tools Firstgov Monthly Generation System Peak (GSP) This site is no longer maintained. Page last...

319

Photon generator  

DOE Patents [OSTI]

A photon generator includes an electron gun for emitting an electron beam, a laser for emitting a laser beam, and an interaction ring wherein the laser beam repetitively collides with the electron beam for emitting a high energy photon beam therefrom in the exemplary form of x-rays. The interaction ring is a closed loop, sized and configured for circulating the electron beam with a period substantially equal to the period of the laser beam pulses for effecting repetitive collisions.

Srinivasan-Rao, Triveni (Shoreham, NY)

2002-01-01T23:59:59.000Z

320

On neutron numbers and atomic masses  

Science Journals Connector (OSTI)

On neutron numbers and atomic masses ... Assigning neutron numbers, correct neutron numbers, and atomic masses and nucleon numbers. ...

R. Heyrovská

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Role of Pyridine as a Biomimetic Organo-Hydride for Homogeneous Reduction of CO2 to Methanol  

E-Print Network [OSTI]

We use quantum chemical calculations to elucidate a viable homogeneous mechanism for pyridine-catalyzed reduction of CO2 to methanol. In the first component of the catalytic cycle, pyridine (Py) undergoes a H+ transfer (PT) to form pyridinium (PyH+) followed by an e- transfer (ET) to produce pyridinium radical (PyH0). Examples of systems to effect this ET to populate the LUMO of PyH+(E0calc ~ -1.3V vs. SCE) to form the solution phase PyH0 via highly reducing electrons include the photo-electrochemical p-GaP system (ECBM ~ -1.5V vs. SCE at pH= 5) and the photochemical [Ru(phen)3]2+/ascorbate system. We predict that PyH0 undergoes further PT-ET steps to form the key closed-shell, dearomatized 1,2-dihydropyridine (PyH2) species. Our proposed sequential PT-ET-PT-ET mechanism transforming Py into PyH2 is consistent with the mechanism described in the formation of related dihydropyridines. Because it is driven by its proclivity to regain aromaticity, PyH2 is a potent recyclable organo-hydride donor that mimics the ...

Lim, Chern-Hooi; Hynes, James T; Musgrave, Charles B

2014-01-01T23:59:59.000Z

322

Generation Technologies  

E-Print Network [OSTI]

Many local governments are using green power in their facilities and providing assistance to local businesses and residents to do the same. Green power is a subset of renewable energy that is produced with no GHG emissions, typically from solar, wind, geothermal, biogas, biomass, or low-impact small hydroelectric sources, includes three types of products: utility products (i.e., green power purchased from the utility through the electricity grid), renewable energy certificates (RECs), and on-site generation. Opportunities to purchase these products are increasing significantly, with annual green power market growth rates

Green Power

2005-01-01T23:59:59.000Z

323

Atomic Energy Commission Takes Over Responsibility for all Atomic...  

National Nuclear Security Administration (NNSA)

Takes Over Responsibility for all Atomic Energy Programs | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile...

324

Intracollisional interference of R lines of HD in mixtures of deuterium hydride and helium gas  

Science Journals Connector (OSTI)

Line shapes of the R0(0) and R0(1) lines in the pure rotational band, and of the R1(0) and R1(1) lines in the fundamental band of HD are computed from first principles for HD molecules that interact collisionally with He atoms. Interference of the permanent dipole of the HD molecule and the interaction-induced dipole of HD–He supermolecular complex shapes these profiles. We use the close-coupling scheme for the scattering calculations which take into account the anisotropy of the HD–He interaction potential. Thus rotational level mixing is accounted for in a non-perturbative manner. The treatment is fully quantum mechanical and takes into account single binary collisions between HD and He. Spectral absorption profiles and line shape parameters of the R-lines are computed for comparison with existing measurements at 77 K. Agreement between theory and measurements is observed in the low-helium-density limit of the measured absorption as expected.

Magnus Gustafsson and Lothar Frommhold

2001-04-18T23:59:59.000Z

325

EA-1053: Decontaminating and Decommissioning the General Atomics Hot Cell  

Broader source: Energy.gov (indexed) [DOE]

3: Decontaminating and Decommissioning the General Atomics 3: Decontaminating and Decommissioning the General Atomics Hot Cell Facility, San Diego, California EA-1053: Decontaminating and Decommissioning the General Atomics Hot Cell Facility, San Diego, California SUMMARY This EA evaluates the environmental impacts of the proposal for low-level radioactive and mixed wastes generated by decontaminating and decommissioning activities at the U.S. Department of Energy's General Atomics' Hot Cell Facility would be transported to either a DOE owned facility, such as the Hanford site in Washington, or to a commercial facility, such as Envirocare in Utah, for treatment and/or storage and disposal. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD August 14, 1995 EA-1053: Finding of No Significant Impact

326

Magnetocumulative generator  

DOE Patents [OSTI]

An improved magnetocumulative generator is described that is useful for producing magnetic fields of very high energy content over large spatial volumes. The polar directed pleated magnetocumulative generator has a housing (100, 101, 102, 103, 104, 105) providing a housing chamber (106) with an electrically conducting surface. The chamber (106) forms a coaxial system having a small radius portion and a large radius portion. When a magnetic field is injected into the chamber (106), from an external source, most of the magnetic flux associated therewith positions itself in the small radius portion. The propagation of an explosive detonation through high-explosive layers (107, 108) disposed adjacent to the housing causes a phased closure of the chamber (106) which sweeps most of the magnetic flux into the large radius portion of the coaxial system. The energy content of the magnetic field is greatly increased by flux stretching as well as by flux compression. The energy enhanced magnetic field is utilized within the housing chamber itself.

Pettibone, Joseph S. (Livermore, CA); Wheeler, Paul C. (Livermore, CA)

1983-01-01T23:59:59.000Z

327

Light element opacities of astrophysical interest from ATOMIC  

SciTech Connect (OSTI)

We present new calculations of local-thermodynamic-equilibrium (LTE) light element opacities from the Los Alamos ATOMIC code for systems of astrophysical interest. ATOMIC is a multi-purpose code that can generate LTE or non-LTE quantities of interest at various levels of approximation. Our calculations, which include fine-structure detail, represent a systematic improvement over previous Los Alamos opacity calculations using the LEDCOP legacy code. The ATOMIC code uses ab-initio atomic structure data computed from the CATS code, which is based on Cowan's atomic structure codes, and photoionization cross section data computed from the Los Alamos ionization code GIPPER. ATOMIC also incorporates a new equation-of-state (EOS) model based on the chemical picture. ATOMIC incorporates some physics packages from LEDCOP and also includes additional physical processes, such as improved free-free cross sections and additional scattering mechanisms. Our new calculations are made for elements of astrophysical interest and for a wide range of temperatures and densities.

Colgan, J.; Kilcrease, D. P.; Magee, N. H. Jr.; Armstrong, G. S. J.; Abdallah, J. Jr.; Sherrill, M. E. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Fontes, C. J.; Zhang, H. L.; Hakel, P. [Computational Physics Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

2013-07-11T23:59:59.000Z

328

Atoms.inp Archive: Crystallographic Data from GSECARS  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The Atoms.inp Archive is a collection of crystallographic data for use in XAFS analysis. The crystallographic data is stored as atoms.inp files, which contain all the information necessary to describe the crystal, and can be used by the program ATOMS to generate feff.inp files. These files can then be used by the FEFF program [See http://leonardo.phys.washington.edu/feff/] to calculate a theoretical XAFS spectrum for the crystal. This archive exists because it can take a considerable amount of time to locate a suitable reference for a model structure to use for making theoretical XAFS standards. Even then, references sometimes give non-standard or incomplete crystallographic notation that ATOMS has difficulty interpreting. All of this means that getting a reliable atoms.inp file can take quite a bit of effort. It is hoped that this collection of well-documented and well-tested atoms.inp files will eliminate much of the work in creating theoretical XAFS standards from FEFF. [Taken from http://cars9.uchicago.edu/~newville/adb/]. The collection currently has more than 200 crystal structures, 2748 data files, and it continues to expand. The collection is related to the UWXAFS Project [http://depts.washington.edu/uwxafs/] and to the work of the Consortium for Advanced Radiation Sources (CARS). After searching the Archive, a user may also choose to run the web version of ATOMS software.

Newville, Matthew

329

Magnetic trap for thulium atoms  

SciTech Connect (OSTI)

For the first time ultra-cold thulium atoms were trapped in a magnetic quadrupole trap with a small field gradient (20 Gs cm{sup -1}). The atoms were loaded from a cloud containing 4x10{sup 5} atoms that were preliminarily cooled in a magneto-optical trap to the sub-Doppler temperature of 80 {mu}K. As many as 4x10{sup 4} atoms were trapped in the magnetic trap at the temperature of 40 {mu}K. By the character of trap population decay the lifetime of atoms was determined (0.5 s) and an upper estimate was obtained for the rate constant of inelastic binary collisions for spin-polarised thulium atoms in the ground state (g{sub in} < 10{sup -11}cm{sup 3} s{sup -1}). (magnetic traps)

Sukachev, D D; Sokolov, A V; Chebakov, K A; Akimov, A V; Kolachevskii, N N; Sorokin, Vadim N [P N Lebedev Physical Institute, Russian Academy of Sciences, Moscow (Russian Federation)

2011-08-31T23:59:59.000Z

330

Transient x-ray absorption spectroscopy of hydrated halogen atom  

E-Print Network [OSTI]

Time-resolved x-ray absorption spectroscopy has been used to observe the transient species generated by one-photon detachment of an electron from aqueous bromide. The K-edge spectrum of the short-lived Br(0) atom exhibits a resonant 1s-4p transition...

Elles, Christopher G.; Shkrob, Ilya A.; Crowell, Robert A.; Arms, Dohn A.; Landahl, Eric C.

2008-02-11T23:59:59.000Z

331

WORLD ATOMIC POWER TIMETABLE  

Science Journals Connector (OSTI)

Fusion is just about as far ahead of fission in its potentialities as is the latter over the conventional fuels. ... Most encouraging was the decision reached independently by the U. S.. the U. K. and the U.S.S.R. to take off the wraps of secrecy from thermonuclear research in power generation. ...

WALTER J. MURPHY

1958-10-27T23:59:59.000Z

332

ATOMIC ENERGY COMMISSION  

Office of Legacy Management (LM)

' ' ATOMIC ENERGY COMMISSION Frank K. Pittman, Director, bivisioa of Waste &&gement and s- portation, Headquarters j CONTAMItUTED RX-AEC-OWNED OR LEASED FACILITIES' This memorandum responds to your TWX certain information on the above subject. the documentation necessary to answer your available due to the records disposal vailing at the time of release or From records that are available and from disc&ions with most familiar with the transfer operations, &have the current radiological conditibn of transferred property is adequate under present standards. The following tabulations follow the format suggested in your TWX and are grouped to an operations or contract r+ponsibility. A,I Ex-AEC Storage Sites - I r:/ National Stockpile Site '(NSS) and OperatEonal

333

Bettis Atomic Power Laboratory  

SciTech Connect (OSTI)

The Bettis Atomic Power Laboratory (Bettis) is owned by the US Department of Energy (DOE) and has been operated under Government contract by the Westinghouse Electric Corporation since 1949. The Bettis Site in West Mifflin, Pennsylvania conducts research and development work on improved nuclear propulsion plants for US Navy warships and is the headquarters for all of the Laboratory's operations. For many years, environmental monitoring has been performed to demonstrate that the Bettis Site is being operated in accordance with environmental standards. While the annual report describes monitoring practices and results, it does not describe the nature and environmental aspects of work and facilities at the Bettis Site nor give a historical perspective of Bettis' operations. The purpose of this report is to provide this information as well as background information, such as the geologic and hydrologic nature of the Bettis Site, pertinent to understanding the environmental aspects of Bettis operations. Waste management practices are also described.

Not Available

1992-01-01T23:59:59.000Z

334

Rydberg Atoms in Ponderomotive Potentials.  

E-Print Network [OSTI]

??In this thesis, we examine the ponderomotive interaction between an applied optical field and a highly excited Rydberg electron. An atom in a Rydberg state… (more)

Knuffman, Brenton J.

2009-01-01T23:59:59.000Z

335

Absorption properties of identical atoms  

SciTech Connect (OSTI)

Emission rates and other optical properties of multi-particle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas. -- Highlights: •The absorption rates of a pair of identical atoms in product and (anti)symmetrized states are different. •The modifications of the optical properties are essentially determined by the overlapping between the atoms. •The absorption properties differ, in some cases, for bosons and fermions.

Sancho, Pedro, E-mail: psanchos@aemet.es

2013-09-15T23:59:59.000Z

336

EMSL - atomic-resolution imaging  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic-resolution-imaging en Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). http:www.emsl.pnl.govemslwebpublicationsmolecular-hydrogen-formation-proxima...

337

Magnetism and Atomic Structure. I  

Science Journals Connector (OSTI)

3 January 1921 research-article Magnetism and Atomic Structure. I A. E. Oxley The Royal Society is collaborating with JSTOR to digitize, preserve, and extend access...

1921-01-01T23:59:59.000Z

338

Atom bouncers have it taped  

Science Journals Connector (OSTI)

... University have repeatedly bounced rubidium atoms from magnetic tape of the kind used to record audio signals1. In later experiments, they obtained better results with floppy disks.

Wayne M. Itano

1995-09-28T23:59:59.000Z

339

Low energy neutral atom imaging techniques  

SciTech Connect (OSTI)

The potential scientific return from low energy neutral atom (LENA) imaging of the magnetosphere is extraordinary. The technical challenges of LENA detection include (1) removal of LENAs from the tremendous ambient UV without losing information of their incident trajectories, (2) quantification of their trajectories, and (3) obtaining high sensitivity measurements. Two techniques that have been proposed for this purpose are based on fundamentally different atomic interaction mechanisms between LENAs and a solid: LENA transmission through an ultrathin foil and LENA reflection from a solid surface. Both of these methods provide LENA ionization (for subsequent removal from the UV by electrostatic deflection) and secondary electron emission (for start pulse generation for time-of-flight and/or coincidence). We present a comparative study of the transmission and reflection techniques based on differences in atomic interactions with solids and surfaces. We show that transmission methods yield an order of magnitude greater secondary electron emission than reflection methods. Transmission methods are shown to be sufficient for LENA energies of approximately 1 keV to greater than 30 keV. Reflection methods using low work function surfaces could be employed for LENA ionization for energies less than several keV.

Funsten, H.O. McComas, D.J.; Scime, E.E.

1993-01-01T23:59:59.000Z

340

Biogass Generator  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Another internet tool by: Another internet tool by: Build Your Own Page 1 of 5 Teach...build...learn...renewable energy! Biogas Generator A Renewable Energy Project Kit The Pembina Institute What Is Biogas? Biogas is actually a mixture of gases, usually carbon dioxide and methane. It is produced by a few kinds of microorganisms, usually when air or oxygen is absent. (The absence of oxygen is called "anaerobic conditions.") Animals that eat a lot of plant material, particularly grazing animals such as cattle, produce large amounts of biogas. The biogas is produced not by the cow or elephant, but by billions of microor- ganisms living in its digestive system. Biogas also develops in bogs and at the bottom of lakes, where decaying organic matter builds up under wet and

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS  

SciTech Connect (OSTI)

I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

Huggins, John Mitchell

1980-06-01T23:59:59.000Z

342

Similarity between positronium-atom and electron-atom scattering  

E-Print Network [OSTI]

We employ the impulse approximation for description of positronium-atom scattering. Our analysis and calculations of Ps-Kr and Ps-Ar collisions provide theoretical explanation of the similarity between the cross sections for positronium scattering and electron scattering for a range of atomic and molecular targets observed by S. J. Brawley et al. [Science 330, 789 (2010)].

Fabrikant, I I

2015-01-01T23:59:59.000Z

343

Nondegenerate parametric down conversion in coherently prepared two-level atomic gas  

E-Print Network [OSTI]

We describe parametric down conversion process in a two-level atomic gas, where the atoms are in a superposition state of relevant energy levels. This superposition results in splitting of the phase matching condition into three different conditions. Another, more important, peculiarity of the system under discussion is the nonsaturability of amplification coefficients with increasing pump wave intensity, under "sideband" generation conditions.

Gevorg Muradyan; Atom Zh. Muradyan

2008-07-14T23:59:59.000Z

344

Nondegenerate parametric down conversion in coherently prepared two-level atomic gas  

E-Print Network [OSTI]

We describe parametric down conversion process in a two-level atomic gas, where the atoms are in a superposition state of relevant energy levels. This superposition results in splitting of the phase matching condition into three different conditions. Another, more important, peculiarity of the system under discussion is the nonsaturability of amplification coefficients with increasing pump wave intensity, under "sideband" generation conditions.

Muradyan, Gevorg

2008-01-01T23:59:59.000Z

345

Quantum stochastic calculus approach to modeling double-pass atom-field coupling  

Science Journals Connector (OSTI)

We examine a proposal by Sherson and Mølmer to generate polarization-squeezed light in terms of quantum stochastic calculus (QSC). We investigate the statistics of the output field and confirm their results using the QSC formalism. In addition, we study the atomic dynamics of the system and find that this setup can produce up to 3 dB of atomic spin squeezing.

Gopal Sarma; Andrew Silberfarb; Hideo Mabuchi

2008-08-07T23:59:59.000Z

346

The Atomic City / The Magic of the Atom - 1950's Atomic Energy Commission Documentary  

SciTech Connect (OSTI)

The story of American cities located near atomic power plants, and steps taken monitoring radiation to ensure the safety of the public who live nearby. .

None

2012-06-04T23:59:59.000Z

347

E-Print Network 3.0 - atomization atomic absorption Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atomic absorption Search Powered by Explorit Topic List Advanced Search Sample search results for: atomization atomic absorption Page: << < 1 2 3 4 5 > >> 1 :coherently trapped in...

348

Bogoliubov theory and bosonic atoms  

E-Print Network [OSTI]

We formulate the Bogoliubov variational principle in a mathematical framework similar to the generalized Hartree-Fock theory. Then we analyze the Bogoliubov theory for bosonic atoms in details. We discuss heuristically why the Bogoliubov energy should give the first correction to the leading energy of large bosonic atoms.

Phan Thanh Nam

2011-09-13T23:59:59.000Z

349

Thermoelectric generator  

SciTech Connect (OSTI)

A thermoelectric generator unit is described comprising: a hot side heat exchanger including a plate having extruded retention posts projecting from one surface of the plate, and fins adapted for contact with a heating source. The fins are positioned between two of the retention posts. Retention rods are inserted between the retention posts and the base of the fins to retain the fin in thermal contact with the plate surface upon insertion of the retention rod between the engaging surface of the post and the corresponding fin. Thermoelectric semi-conductor modules are in thermal contact with the opposite side of the hot side heat exchanger plate from the contact with the fins. The modules are arranged in a grid pattern so that heat flow is directed into each of the modules from the hot side heat exchanger. The modules are connected electrically so as to combine their electrical output; and a cold side heat exchanger is in thermal contact with the modules acting as a heat sink on the opposite side of the module from the hot side heat exchanger plate so as to produce a thermal gradient across the modules.

Shakun, W.; Bearden, J.H.; Henderson, D.R.

1988-03-29T23:59:59.000Z

350

Atomic, Molecular & Optical Sciences  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atomic, Molecular and Optical Sciences Atomic, Molecular and Optical Sciences The goal of the program is to understand the structure and dynamics of atoms and molecules using photons and ions as probes. The current program is focussed on studying inner-shell photo-ionization and photo-excitation of atoms and molecules, molecular orientation effects in slow collisions, slowing and cooling molecules, and X-ray photo-excitation of laser-dressed atoms. The experimental and theoretical efforts are designed to break new ground and to provide basic knowledge that is central to the programmatic goals of the Department of Energy (DOE). Unique LBNL facilities such as the Advanced Light Source (ALS), the ECR ion sources at the 88-inch cyclotron, and the National Energy Research Scientific Computing Center (NERSC) are

351

Spectral Emission of Moving Atom  

E-Print Network [OSTI]

A renewed analysis of the H.E. Ives and G.R. Stilwell's experiment on moving hydrogen canal rays (J. Opt. Soc. Am., 1938, v.28, 215) concludes that the spectral emission of a moving atom exhibits always a redshift which informs not the direction of the atom's motion. The conclusion is also evident from a simple energy relation: atomic spectral radiation is emitted as an orbiting electron consumes a portion of its internal energy on transiting to a lower-energy state which however has in a moving atom an additional energy gain; this results in a redshift in the emission frequency. Based on auxiliary experimental information and a scheme for de Broglie particle formation, we give a vigorous elucidation of the mechanism for deceleration radiation of atomic electron; the corresponding prediction of the redshift is in complete agreement with the Ives and Stilwell's experimental formula.

J. X. Zheng-Johansson

2008-03-17T23:59:59.000Z

352

Nanoscale Cluster Detection in Massive Atom Probe Tomography Data  

SciTech Connect (OSTI)

Recent technological advances in atom probe tomography (APT) have led to unprecedented data acquisition capabilities that routinely generate data sets containing hundreds of millions of atoms. Detecting nanoscale clusters of different atom types present in these enormous amounts of data and analyzing their spatial correlations with one another are fundamental to understanding the structural properties of the material from which the data is derived. Extant algorithms for nanoscale cluster detection do not scale to large data sets. Here, a scalable, CUDA-based implementation of an autocorrelation algorithm is presented. It isolates spatial correlations amongst atomic clusters present in massive APT data sets in linear time using a linear amount of storage. Correctness of the algorithm is demonstrated using large synthetically generated data with known spatial distributions. Benefits and limitations of using GPU-acceleration for autocorrelation-based APT data analyses are presented with supporting performance results on data sets with up to billions of atoms. To our knowledge, this is the first nanoscale cluster detection algorithm that scales to massive APT data sets and executes on commodity hardware.

Seal, Sudip K [ORNL] [ORNL; Yoginath, Srikanth B [ORNL] [ORNL; Miller, Michael K [ORNL] [ORNL

2014-01-01T23:59:59.000Z

353

Manhattan Project: Adventures Inside the Atom  

Office of Scientific and Technical Information (OSTI)

ADVENTURES INSIDE THE ATOM ADVENTURES INSIDE THE ATOM General Electric, National Archives (1948) Resources > Library Below is Adventures Inside the Atom, a comic book history of nuclear energy that was produced in 1948 by the General Electric Company. Scroll down to view the full-size images of each page. This publication was produced at the request of the the Assistant Manager for Public Education, Oak Ridge Operations Office, Atomic Energy Commission. It is reproduced here via the National Archives. Adventures Inside the Atom, p. 1 Adventures Inside the Atom, p. 2 Adventures Inside the Atom, p. 3 Adventures Inside the Atom, p. 4 Adventures Inside the Atom, p. 5 Adventures Inside the Atom, p. 6 Adventures Inside the Atom, p. 7 Adventures Inside the Atom, p. 8 Adventures Inside the Atom, p. 9

354

AtomicNuclear Properties  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

HTML_PAGES HTML_PAGES This AtomicNuclearProperties page is under intermittent development. Suggestions and comments are welcome. Please report errors. Chemical elements: For entries in red, a pull-down menu permits selection of the physical state. Cryogenic liquid densties are at the boiling point at 1 atm. 0n 1Ps 1H 2He 3Li 4Be 5B 6C 7N 8O 9F 10Ne 11Na 12Mg 13Al 14Si 15P 16S 17Cl 18Ar 19K 20Ca 21Sc 22Ti 23V 24Cr 25Mn 26Fe 27Co 28Ni 29Cu 30Zn 31Ga 32Ge 33As 34Se 35Br 36Kr 37Rb 38Sr 39Y 40Zr 41Nb 42Mo 43Tc 44Ru 45Rh 46Pd 47Ag 48Cd 49In 50Sn 51Sb 52Te 53I 54Xe 55Cs 56Ba 57La 72Hf 73Ta 74W 75Re 76Os 77Ir 78Pt 79Au 80Hg 81Tl 82Pb 83Bi 84Po 85At 86Rn 87Fr 88Ra 89Ac 104Rf 105Db 106Sg 107Bh 108Hs 109Mt 110Ds 111Rg 112 113 114 115 116 mt 118

355

In-situ control system for atomization  

DOE Patents [OSTI]

Melt atomizing apparatus comprising a melt supply orifice for supplying the melt for atomization and gas supply orifices proximate the melt supply orifice for supplying atomizing gas to atomize the melt as an atomization spray. The apparatus includes a sensor, such as an optical and/or audio sensor, for providing atomization spray data, and a control unit responsive to the sensed atomization spray data for controlling at least one of the atomizing gas pressure and an actuator to adjust the relative position of the gas supply orifice and melt supply in a manner to achieve a desired atomization spray.

Anderson, Iver E. (Ames, IA); Figliola, Richard S. (Central, SC); Terpstra, Robert L. (Ames, IA)

1995-06-13T23:59:59.000Z

356

Analysis of Na and Ba in an atomic fluorescence method with excitation by a pulsed dye laser with lamp pumping  

SciTech Connect (OSTI)

Among the laser methods used in atomic spectroscopy, atomic fluorescence resonance spectroscopy together with an atomic ionization technique make it possible to work with individual atoms. This paper reports on the determination of Na and Ba in aqueous solutions of their salts with atomic fluorescence analysis performed wih a dye laser and lamp pumping, the pulse of generation having a length of 1-2 usec. The detection limit of elements in atomic fluorescence analysis performed wih dye lasers with lamp pumping can be reduced by increasing the spectral density of the laser radiation through narrowing the line of generation, by employing other dyes to excite lines of greater intensity, by improving the recording system of the fluorescence spectra, and by improving the atomization of the samples to be analyzed.

Kukvshim, V.G.

1986-04-01T23:59:59.000Z

357

Supersonic coal water slurry fuel atomizer  

DOE Patents [OSTI]

A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Balsavich, John (Foxborough, MA)

1991-01-01T23:59:59.000Z

358

Niobium hydride phase behavior studied using the cluster-variation method  

Science Journals Connector (OSTI)

We present several models for NbH phase behavior based on the cluster-variation method. The most important of these are the single-tetragonal-cell (STC) model and the twelve-cluster (TWC) model, which have as their basic clusters the single tetragonal cell and a twelve-sited cluster, respectively. The following conclusions can be drawn from our study of these models. From the STC ground-state analysis we find that, for interactions confined to the single tetragonal cell (a subset of the first 14 shells for the tetrahedral lattice), (1) it is possible to predict the ? and ? phases but not the ? phase, and (2) many-body interactions are needed to eliminate an extraneous pure phase (i.e., a phase that is not observed experimentally) at concentration [H]/[Nb]=0.25, assuming the ?, ?’, and ? phases are ground states. These observations suggest that longer-range interactions than those in the STC are important for NbH phase formation and many-body interactions may be necessary to eliminate unwanted phases at lower concentrations. We have also generated phase diagrams that are qualitatively similar (in the ordered regions) to experimental NbH phase diagrams. Our study of the TWC model shows that it is more accurate in comparison with a Monte Carlo model than the existing entropy approximations of Boureau, Richards, and MacGillivray, Soteros, and Hall. Furthermore, using the TWC model it is possible to predict an ?-?’-? phase envelope that compares well with the Futran and Hall Monte Carlo calculation. This is the first analytic free-energy calculation to predict the ?-?’-? transition. Using the TWC model we also show that, as Shirley and Hall have conjectured, many-body interactions work to lower the ?-?’ critical temperature when compared with calculations including only pair interactions. Since pair-interaction calculations overestimate the critical temperature, this is further evidence of the importance of many-body interactions.

Christine E. Soteros and Carol K. Hall

1990-10-01T23:59:59.000Z

359

Introduction Minimal generation  

E-Print Network [OSTI]

Introduction Minimal generation Random generation Minimal and probabilistic generation of finite generation of finite groups #12;Introduction Minimal generation Random generation Some motivation Let x1 random elements of G = x1, . . . , xk . (G is the group generated by x1, . . . , xk : all possible

St Andrews, University of

360

Entanglement of a two-mode field in a collective three-level atomic system  

SciTech Connect (OSTI)

The entanglement properties of two-mode field from a laser-driven collective three-level atomic system are investigated by taking into account the spontaneously generated coherence. Under some conditions, it is found that the entanglement between the two cavity modes can be significantly enhanced by the collectivity of the atoms compared to the case of independent atoms when the relative phase {Delta}{phi}={pi}. Moreover, the spontaneously generated coherence can also greatly enhance the entanglement in comparison to the case without this coherence.

Tang Zhaohong [Department of Physics, Huazhong Normal University, Wuhan 430079 (China); School of Science, Wuhan Institute of Technology, Wuhan 430073 (China); Li Gaoxiang [Department of Physics, Huazhong Normal University, Wuhan 430079 (China)

2011-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Questions and Answers - Does an atom smasher really smash atoms?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is an accelerator? is an accelerator? Previous Question (What is an accelerator?) Questions and Answers Main Index Next Question (Where and how do you get your electrons for your accelerator?) Where and how do you get yourelectrons for your accelerator? Does an atom smasher really smash atoms? Well, yes, they do, but we now prefer to call them by their less aggression-centered name, "particle harmony disrupters." Of course some atom smashers do much more smashing than others. We use electrons in our accelerator to study the nucleus of an atom. Remember that electrons are negative, as are the electrons surrounding the target. Since like charged particles repel each other, our particles have to have enough energy to blast through that electron cloud to get to the nucleus. The electrons then

362

Atoms 2014, 2, 378-381; doi:10.3390/atoms2030378 OPEN ACCESS  

E-Print Network [OSTI]

Atoms 2014, 2, 378-381; doi:10.3390/atoms2030378 OPEN ACCESS atomsISSN 2218-2004 www.mdpi.com/journal/atoms.calisti@univ-amu.fr 3 International Atomic Energy Agency, Atomic and Molecular Data Unit, Nuclear Data Section, P.O. Box for the first two SLSP workshops are for simple atomic systems: the hydrogen atom or hydrogen-like one

363

Chemical factors influencing selenium atomization  

E-Print Network [OSTI]

Atomization. (August 1980) Mary Sue Buren, B, S. , Angelo State University Chairman of Advisory Comm1ttee: Dr. Thomas M. Vickrey Selenium in an acid1c matrix was analyzed using graphite furnace atom1c absorption with Zeeman-effect background correct1on.... Nickel(II} and lanthanum( III) were introduced as matrix modifiers to determine their effect on interferences 1n selenium atom1zation. In add1tion to matr1x mod1ficat1on, surface coating the graphite furnace with z1rconium and tantalum salts was also...

Buren, Mary Sue

2012-06-07T23:59:59.000Z

364

Next Generation Light Source Workshops  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Next Generation Light Source Workshops Next Generation Light Source Workshops A series of workshops will be held in late August with the goal of refining the scientific drivers for the facility and translating the scientific needs into the technical performance requirements. Feedback from these workshops will provide important input for advancing the design of the facility. Workshops are planned in the following areas Fundamental Atomic, Molecular, Optical Physics & Combustion Dynamics Mon. Aug. 20 - Tues. Aug 21, 2012 Physical Chemistry, Catalysis, & Photosynthesis Thurs. Aug. 23 - Fri. Aug 24, 2012 Quantum Materials, Magnetism & Spin Dynamics Mon. Aug. 27 - Tues. Aug 28, 2012 Materials & Bio-imaging at the Nanoscale Thurs. Aug. 30 - Fri. Aug 31, 2012 Further information is available on the workshop website:

365

THE INTERACTION OF RARE GAS METASTABLE ATOMS  

E-Print Network [OSTI]

in the study of metastable atom reactions. > 1 it- Fig, laa raetastable rare gas atom, three quantities are necessaryOF iiARE GAS METASTABLF ATOMS Andrew Zun-Foh Wang M a t e r

Wang, A.Z.-F.

2011-01-01T23:59:59.000Z

366

Imaging atoms in 3-D  

ScienceCinema (OSTI)

Berkeley Lab's Peter Ercius discusses "Imaging atoms in 3-D" in this Oct. 28, 2013 talk, which is part of a Science at the Theater event entitled Eight Big Ideas

Ercius, Peter

2014-06-27T23:59:59.000Z

367

ATOMIC ENERGY ACT OF 1946  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ect of the us0 of atomic energy for civilian purposes upon the social, economic, and political structures of today cannot now bo determined. It is a field in which unknown factors...

368

Quantum information with Rydberg atoms  

Science Journals Connector (OSTI)

Rydberg atoms with principal quantum number n?1 have exaggerated atomic properties including dipole-dipole interactions that scale as n4 and radiative lifetimes that scale as n3. It was proposed a decade ago to take advantage of these properties to implement quantum gates between neutral atom qubits. The availability of a strong long-range interaction that can be coherently turned on and off is an enabling resource for a wide range of quantum information tasks stretching far beyond the original gate proposal. Rydberg enabled capabilities include long-range two-qubit gates, collective encoding of multiqubit registers, implementation of robust light-atom quantum interfaces, and the potential for simulating quantum many-body physics. The advances of the last decade are reviewed, covering both theoretical and experimental aspects of Rydberg-mediated quantum information processing.

M. Saffman; T. G. Walker; K. Mølmer

2010-08-18T23:59:59.000Z

369

Absorption properties of identical atoms  

E-Print Network [OSTI]

Emission rates and other optical properties of multiparticle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas.

Pedro Sancho

2013-07-31T23:59:59.000Z

370

Practical scheme for a light-induced gauge field in an atomic Bose gas  

Science Journals Connector (OSTI)

We propose a scheme to generate an Abelian gauge field in an atomic gas using two crossed laser beams. If the internal atomic state follows adiabatically the eigenstates of the atom-laser interaction, Berry’s phase gives rise to a vector potential that can nucleate vortices in a Bose gas. The present scheme operates even for a large detuning with respect to the atomic resonance, making it applicable to alkali-metal atoms without significant heating due to spontaneous emission. We test the validity of the adiabatic approximation by integrating the set of coupled Gross-Pitaevskii equations associated with the various internal atomic states, and we show that the steady state of the interacting gas indeed exhibits a vortex lattice, as expected from the adiabatic gauge field.

Kenneth J. Günter, Marc Cheneau, Tarik Yefsah, Steffen P. Rath, and Jean Dalibard

2009-01-21T23:59:59.000Z

371

Temperature effect on recol tritium ractions in solid alkanes at 20 to 300 K. Comparison of recoil T atoms with H (D) atoms in. gamma. radiolysis  

SciTech Connect (OSTI)

Hydrogen atom abstraction by recoil T atoms in neopentane and decane-d/sub 22/ has been studied at 20, 77, 195, and 300 K by means of ESR spectroscopy and radiogas chromatography. The results are compared with the reaction of H (or D) atoms produced by ..gamma.. radiolysis. When the experiments are conducted at 77 K, the reaction or recoil tritium atoms in the neo-C/sub 5/H/sub 12/-i-C/sub 4/H/sub 9/D (2 mol %) and n-C/sub 10/D/sub 22/-n-C/sub 10/H/sub 22/ (10 mol %) mixtures do not parallel those of H and D atoms generated by ..gamma.. irradiation, whereas the results at other temperatures below and above 77 K (20, 195, and 300 K) are more nealy comparable. The different results at 77 K are attributed to the ability of H and D atoms but not T atoms to diffuse and react with i-C/sub 4/H/sub 9/D (or n-C/sub 10/H/sub 22/) solute molecules. The failure of the thermal diffusion of the T atoms at 77 K is explained by a model in which nearly all of the recoil T atoms react either by hot reaction or have a high probability of reacting with a fragment near the end of the path and only a few percent of them diffuse into the bulk matrix.

Aratono, Y. (Japan Atomic Energy Research Institute, Ibaraki); Tachikawa, E.; Miyazaki, T.; Kawai, Y.; Fueki, K.

1982-01-21T23:59:59.000Z

372

Investigations of Alternative Steam Generator Location and Flatter Core Geometry for Lead-Cooled Fast Reactors  

SciTech Connect (OSTI)

This paper concerns two independent safety investigations on critical and sub-critical heavy liquid metal cooled fast reactors using simple flow paths. The first investigation applies to locating the steam generators in the risers instead of the down-comers of a simple flow path designed sub-critical reactor of 600 MW{sub th} power. This was compared to a similar design, but with the steam generators located in the downcomers. The transients investigated were Total-Loss-of-Power and unprotected Loss-Of-Flow. It is shown that this reactor peaks at 1041 K after 29 hours during a Total-Loss-Of-Power accident. The difference between locating the steam generators in the risers and the downcomers is insignificant for this accident type. During an unprotected Loss-Of-Flow accident at full power, the core outlet temperature stabilizes at 1010 K, which is 337 K above nominal outlet temperature. The second investigation concerns a 1426 MW{sub th} critical reactor where the influence of the core height versus the core outlet temperature is studied during an unprotected Loss-Of-Flow and Total-Loss-Of-Power accident. A pancake type core geometry of 1.0 m height and 5.8 m diameter, is compared to a compact core of 2 m height and 4.5 m diameter. Moderators, like BeO and hydrides, and their influence on safety coefficients and burnup swings are also presented. Both cores incinerate transuranics from spent LWR fuel with minor actinide fraction of 5%. We show that LFRs can be designed both to breed and burn transuranics from LWRs. It is shown that the hydrides lead to the most favorable reactivity feedbacks, but the poorest reactivity swing. The computational fluid dynamics code STAR-CD was used for all thermal hydraulic calculations, and the MCNP and MCB for neutronics, and burn-up calculations. (authors)

Carlsson, Johan; Tucek, Kamil; Wider, Hartmut [Joint Research Centre, Institute for Energy, P.O. Box 2, NL-1755 ZG Petten (Netherlands)

2006-07-01T23:59:59.000Z

373

DOE - Office of Legacy Management -- Shippingport Atomic Power Plant - PA  

Office of Legacy Management (LM)

Shippingport Atomic Power Plant - Shippingport Atomic Power Plant - PA 13 FUSRAP Considered Sites Site: SHIPPINGPORT ATOMIC POWER PLANT (PA.13 ) Eliminated from further consideration under FUSRAP. Designated Name: Not Designated Alternate Name: Duquesne Light Company PA.13-1 Location: 25 miles west of Pittsburgh in Beaver County , Shippingport , Pennsylvania PA.13-2 Evaluation Year: circa 1987 PA.13-3 Site Operations: First commercially operated nuclear power reactor. Joint project (Federal Government an Duquesne Light Company) to demonstrate pressurized water reactor technology and to generate electricity. Plant operated by Duquesne Light Company under supervision of the Office of the DOE Deputy Assistant Secretary for Naval Reactors -- 1957 to October 1982. PA.13-2 Site Disposition: Eliminated - No Authority. DOE chartered Major Project #118, Shippingport Station Decommissioning Project completed cleanup in 1989. PA.13-1

374

CO{sub 2} Mitigation Using Atomic Power  

SciTech Connect (OSTI)

Atomic power must grow 4.6%/yr in order to displace fossil fuel by 2080 and arrest CO{sub 2} at twice pre-industrial level. World energy use grows 2%/yr and World economy grows 3%/yr. Light Water Reactor (LWR) generation is expanded to the limit of the uranium supply, using a once-through fuel cycle. LWR Spent fuel plutonium is used in breeder reactor first cores. Absent atomic power, rising coal consumption will cause CO{sub 2} to double by 2050, triple by 2075, and be times 4 by 2090. Each 1.0 GWe atomic power plant delays CO{sub 2} doubling 1 week. (author)

Schenewerk, William Ernest [Parsons, Pasadena, CA, 5060 San Rafael Ave., Los Angeles CA 90042-3239 (United States)

2002-07-01T23:59:59.000Z

375

Delta-doping of boron atoms by photoexcited chemical vapor deposition  

SciTech Connect (OSTI)

Boron delta-doped structures in Si crystals were fabricated by means of photoexcited chemical vapor deposition (CVD). Core electronic excitation with high-energy photons ranging from vacuum ultraviolet to soft x rays decomposes B{sub 2}H{sub 6} molecules into fragments. Combined with in situ monitoring by spectroscopic ellipsometry, limited number of boron hydrides can be delivered onto a Si(100) surface by using the incubation period before the formation of a solid boron film. The boron-covered surface is subsequently embedded in a Si cap layer by Si{sub 2}H{sub 6} photo-excited CVD. The crystallinity of the Si cap layer depended on its thickness and the substrate temperature. The evaluation of the boron depth profile by secondary ion mass spectroscopy revealed that boron atoms were confined within the delta-doped layer at a concentration of 2.5 x 10{sup 20} cm{sup -3} with a full width at half maximum of less than 9 nm, while the epitaxial growth of a 130-nm-thick Si cap layer was sustained at 420 deg. C.

Akazawa, Housei [NTT Microsystem Integration Laboratories, 3-1 Morinosato Wakamiya, Atsugi, Kanagawa 243-0198 (Japan)

2012-03-15T23:59:59.000Z

376

Understanding and Managing Generation Y  

E-Print Network [OSTI]

There are four generations in the workplace today; they consist of the Silent Generation, Baby Boom Generation, Generation X, and Generation Y. Generation Y, being the newest generation, is the least understood generation although marketers...

Wallace, Kevin

2007-12-14T23:59:59.000Z

377

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides  

E-Print Network [OSTI]

Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage the dissociative chemisorption of hydrogen in Ti-doped alanate storage materials. © 2007 American Institute

Ciobanu, Cristian

378

Selfish atom selects quantum resonances at fractional atomic frequencies  

E-Print Network [OSTI]

We show that the atom as a "quantum entity", driven by an external field in the form of pulse sequence at repetition rate equal to the internal quantum frequency divided by an integer n, responds resonantly. It seeks and finds its characteristic frequencies in any possible combination of its frequencies. This is an indication of self expression by the atom at many sub-frequencies of its own transition frequencies. It is a non-intuitive phenomenon since the external repetition rate has no quantum character, yet the atom responds to it if the rate is equal to 1/n its eigen-frequency. We believe that our results will have implications in other quantum related processes, such as resonant enhancement of chemical reactions and biological processes.

Gennady A. Koganov; Reuben Shuker

2014-09-17T23:59:59.000Z

379

Collection of atomic mercury by electrostatic precipitators  

Science Journals Connector (OSTI)

... Flameless atomic absorption spectroscopy was used to measure the difference in the mercury concentration of gas ...

O. M. G. NEWMAN; D. J. PALMER

1978-10-12T23:59:59.000Z

380

RICE UNIVERSITY Ultracold Collisions in Atomic Strontium  

E-Print Network [OSTI]

RICE UNIVERSITY Ultracold Collisions in Atomic Strontium by Sarah B. Nagel A Thesis Submitted Houston, Texas February, 2008 #12;Abstract Ultracold Collisions in Atomic Strontium by Sarah B. Nagel In this work with atomic Strontium, the atoms are first laser cooled and subse- quently trapped, in a MOT

Killian, Thomas C.

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Atomic Cascade in Muonic and Hadronic Hydrogen Atoms  

E-Print Network [OSTI]

The atomic cascade in $\\mu^- p$ and $\\pi^- p$ atoms has been studied with the improved version of the extended cascade model in which new quantum mechanical calculations of the differential and integral cross sections of the elastic scattering, Stark transitions and Coulomb de-excitation have been included for the principal quantum number values $n\\le 8$ and the relative energies $E \\ge 0.01$ eV. The $X$-ray yields and kinetic energy distributions are compared with the experimental data.

T. S. Jensen; V. P. Popov; V. N. Pomerantsev

2007-12-18T23:59:59.000Z

382

Waterless TiO{sub 2} atomic layer deposition using titanium tetrachloride and titanium tetraisopropoxide  

SciTech Connect (OSTI)

The surface chemistry for TiO{sub 2} atomic layer deposition (ALD) typically utilizes water or other oxidants that can oxidize underlying substrates such as magnetic disks or semiconductors. To avoid this oxidation, waterless or oxidant-free surface chemistry can be used that involves titanium halides and titanium alkoxides. In this study, waterless TiO{sub 2} ALD was accomplished using titanium tetrachloride (TiCl{sub 4}) and titanium tetraisopropoxide (TTIP). In situ transmission Fourier transform infrared (FTIR) studies were employed to study the surface species and the reactions during waterless TiO{sub 2} ALD. At low temperatures between 125 and 225??°C, the FTIR absorbance spectra revealed that the isopropoxide species remained on the surface after TTIP exposures. The TiCl{sub 4} exposures then removed the isopropoxide species and deposited additional titanium species. At high temperatures between 250 and 300??°C, the isopropoxide species were converted to hydroxyl species by ?-hydride elimination. The observation of propene gaseous reaction product by quadrupole mass spectrometry (QMS) confirmed the ?-hydride elimination reaction pathway. The TiCl{sub 4} exposures then easily reacted with the hydroxyl species. QMS studies also observed the 2-chloropropane and HCl gaseous reaction products and monitored the self-limiting nature of the TTIP reaction. Additional studies examined the waterless TiO{sub 2} ALD growth at low and high temperature. Quartz crystal microbalance measurements observed growth rates of ?3?ng/cm{sup 2} at a low temperature of 150??°C. Much higher growth rates of ?15?ng/cm{sup 2} were measured at a higher temperature of 250??°C under similar reaction conditions. X-ray reflectivity analysis measured a growth rate of 0.55 ± 0.05?Å/cycle at 250??°C. X-ray photoelectron depth-profile studies showed that the TiO{sub 2} films contained low Cl concentrations <1 at. %. This waterless TiO{sub 2} ALD process using TiCl{sub 4} and TTIP should be valuable to prevent substrate oxidation during TiO{sub 2} ALD on oxygen-sensitive substrates.

Anderson, Virginia R.; Cavanagh, Andrew S.; Abdulagatov, Aziz I. [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 (United States); Gibbs, Zachary M. [Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309-0424 (United States); George, Steven M., E-mail: Steven.George@Colorado.Edu [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 and Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309-0427. (United States)

2014-01-15T23:59:59.000Z

383

A high-flux BEC source for mobile atom interferometers  

E-Print Network [OSTI]

Quantum sensors based on coherent matter-waves are precise measurement devices whose ultimate accuracy is achieved with Bose-Einstein condensates (BEC) in extended free fall. This is ideally realized in microgravity environments such as drop towers, ballistic rockets and space platforms. However, the transition from lab-based BEC machines to robust and mobile sources with comparable performance is a technological challenge. Here we report on the realization of a miniaturized setup, generating a flux of $4 \\times 10^5$ quantum degenerate $^{87}$Rb atoms every 1.6 s. Ensembles of $1 \\times 10^5$ atoms can be produced at a 1 Hz rate. This is achieved by loading a cold atomic beam directly into a multi-layer atom chip that is designed for efficient transfer from laser-cooled to magnetically trapped clouds. The attained flux of degenerate atoms is on par with current lab-based experiments while offering significantly higher repetition rates. The compact and robust design allows for mobile operation in a variety of...

Rudolph, Jan; Grzeschik, Christoph; Sternke, Tammo; Grote, Alexander; Popp, Manuel; Becker, Dennis; Müntinga, Hauke; Ahlers, Holger; Peters, Achim; Lämmerzahl, Claus; Sengstock, Klaus; Gaaloul, Naceur; Ertmer, Wolfgang; Rasel, Ernst M

2015-01-01T23:59:59.000Z

384

A high-flux BEC source for mobile atom interferometers  

E-Print Network [OSTI]

Quantum sensors based on coherent matter-waves are precise measurement devices whose ultimate accuracy is achieved with Bose-Einstein condensates (BEC) in extended free fall. This is ideally realized in microgravity environments such as drop towers, ballistic rockets and space platforms. However, the transition from lab-based BEC machines to robust and mobile sources with comparable performance is a technological challenge. Here we report on the realization of a miniaturized setup, generating a flux of $4 \\times 10^5$ quantum degenerate $^{87}$Rb atoms every 1.6 s. Ensembles of $1 \\times 10^5$ atoms can be produced at a 1 Hz rate. This is achieved by loading a cold atomic beam directly into a multi-layer atom chip that is designed for efficient transfer from laser-cooled to magnetically trapped clouds. The attained flux of degenerate atoms is on par with current lab-based experiments while offering significantly higher repetition rates. The compact and robust design allows for mobile operation in a variety of demanding environments and paves the way for portable high-precision quantum sensors.

Jan Rudolph; Waldemar Herr; Christoph Grzeschik; Tammo Sternke; Alexander Grote; Manuel Popp; Dennis Becker; Hauke Müntinga; Holger Ahlers; Achim Peters; Claus Lämmerzahl; Klaus Sengstock; Naceur Gaaloul; Wolfgang Ertmer; Ernst M. Rasel

2015-01-02T23:59:59.000Z

385

Light-induced gauge fields for ultracold atoms  

E-Print Network [OSTI]

Gauge fields are central in our modern understanding of physics at all scales. At the highest energy scales known, the microscopic universe is governed by particles interacting with each other through the exchange of gauge bosons. At the largest length scales, our universe is ruled by gravity, whose gauge structure suggests the existence of a particle - the graviton - that mediates the gravitational force. At the mesoscopic scale, solid-state systems are subjected to gauge fields of different nature: materials can be immersed in external electromagnetic fields, but they can also feature emerging gauge fields in their low-energy description. In this review, we focus on another kind of gauge field: those engineered in systems of ultracold neutral atoms. In these setups, atoms are suitably coupled to laser fields that generate effective gauge potentials in their description. Neutral atoms "feeling" laser-induced gauge potentials can potentially mimic the behavior of an electron gas subjected to a magnetic field, but also, the interaction of elementary particles with non-Abelian gauge fields. Here, we review different realized and proposed techniques for creating gauge potentials - both Abelian and non-Abelian - in atomic systems and discuss their implication in the context of quantum simulation. While most of these setups concern the realization of background and classical gauge potentials, we conclude with more exotic proposals where these synthetic fields might be made dynamical, in view of simulating interacting gauge theories with cold atoms.

N. Goldman; G. Juzeliunas; P. Ohberg; I. B. Spielman

2014-12-12T23:59:59.000Z

386

Observation of relativistic antihydrogen atoms  

SciTech Connect (OSTI)

An observation of relativistic antihydrogen atoms is reported in this dissertation. Experiment 862 at Fermi National Accelerator Laboratory observed antihydrogen atoms produced by the interaction of a circulating beam of high momentum (3 < p < 9 GeV/c) antiprotons and a jet of molecular hydrogen gas. Since the neutral antihydrogen does not bend in the antiproton source magnets, the detectors could be located far from the interaction point on a beamline tangent to the storage ring. The detection of the antihydrogen is accomplished by ionizing the atoms far from the interaction point. The positron is deflected by a magnetic spectrometer and detected, as are the back to back photons resulting from its annihilation. The antiproton travels a distance long enough for its momentum and time of flight to be measured accurately. A statistically significant sample of 101 antihydrogen atoms has been observed. A measurement of the cross section for {bar H}{sup 0} production is outlined within. The cross section corresponds to the process where a high momentum antiproton causes e{sup +} e{sup -} pair creation near a nucleus with the e{sup +} being captured by the antiproton. Antihydrogen is the first atom made exclusively of antimatter to be detected. The observation experiment's results are the first step towards an antihydrogen spectroscopy experiment which would measure the n = 2 Lamb shift and fine structure.

Blanford, Glenn DelFosse

1998-01-01T23:59:59.000Z

387

Atomizing, continuous, water monitoring module  

DOE Patents [OSTI]

A system for continuously analyzing volatile constituents of a liquid is described. The system contains a pump for continuously pumping the liquid to be tested at a predetermined flow rate into an extracting container through a liquid directing tube having an orifice at one end and positioned to direct the liquid into the extracting container at a flow rate sufficient to atomize the liquid within the extracting container. A continuous supply of helium carrier gas at a predetermined flow rate is directed through a tube into the extracting container and co-mingled with the atomized liquid to extract the volatile constituents contained within the atomized liquid. The helium containing the extracted volatile constituents flows out of the extracting container into a mass spectrometer for an analysis of the volatile constituents of the liquid. 3 figs.

Thompson, C.V.; Wise, M.B.

1997-07-08T23:59:59.000Z

388

Vibrational Modes of Adsorbed Atoms  

E-Print Network [OSTI]

for AronXe B. Neon Ar The lowest surface m ver g.ur ace mode branc mo d o' td 'th es of the " rin " ce e wit an adsorbate of modes assoc' tia ed with th e; there are for the ads stion, the bra h sorbate atoms I c 1.ons ranch labeled 2H s. n... , are the real ads teristic force con t tons ants for ad is evident that in Fi . 2 t "heavier" than th ig. the adsorbate is n e substrate M & terpretation b M, ) in tkis in- ecause the weaknes th l' ht ofth ds o ke adsorbate atoms (m, &m, IBRATIQNAI...

LAWRENCE, WR; Allen, Roland E.

1977-01-01T23:59:59.000Z

389

Relativistic atomic beam spectroscopy II  

SciTech Connect (OSTI)

The negative ion of H is one of the simplest 3-body atomic systems. The techniques we have developed for experimental study of atoms moving near speed of light have been productive. This proposal request continuing support for experimental studies of the H{sup -} system, principally at the 800 MeV linear accelerator (LAMPF) at Los Alamos. Four experiments are currently planned: photodetachment of H{sup -} near threshold in electric field, interaction of relativistic H{sup -} ions with matter, high excitations and double charge escape in H{sup -}, and multiphoton detachment of electrons from H{sup -}.

NONE

1989-12-31T23:59:59.000Z

390

Atomic-binding-energy oscillations  

Science Journals Connector (OSTI)

We investigate the oscillatory supplement to the statistical nonrelativistic binding-energy formula for neutral atoms. The semiclassical approach proves capable of deriving these oscillations. It turns out that their amplitude is proportional to Z4/3 (Z is the number of electrons), and that their period is determined by the maximum angular momentum available in Thomas-Fermi atoms, i.e., 0.928Z1/3. Our calculation also provides an understanding of the peculiar shape of the oscillations, which show sharp minima and wide, structured maxima.

Berthold-Georg Englert and Julian Schwinger

1985-07-01T23:59:59.000Z

391

Metal Hydrides- Science Needs  

Broader source: Energy.gov [DOE]

Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

392

Regeneration of aluminum hydride  

DOE Patents [OSTI]

The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

2009-04-21T23:59:59.000Z

393

PNNL Chemical Hydride Capabilities  

Broader source: Energy.gov (indexed) [DOE]

and surface reactions * High resolution transmission and analytical electron microscopy * Hydrogen charging system - Microchannel reformer technology for enhancing reaction...

394

Next Generation Radioisotope Generators | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

» Next Generation Radioisotope Generators » Next Generation Radioisotope Generators Next Generation Radioisotope Generators Advanced Stirling Radioisotope Generator (ASRG) - The ASRG is currently being developed as a high-efficiency RPS technology to support future space missions on the Martian surface or in the vacuum of space. This system uses Stirling convertors, which have moving parts to mechanically convert heat to electricity. This power conversion system, if successfully deployed, will reduce the weight of each RPS and the amount of Pu-238 needed per mission. A HISTORY OF MISSION SUCCESSES For over fifty years, the Department of Energy has enabled space exploration on 27 missions by providing safe reliable radioistope power systems and radioisotope heater units for NASA, Navy and Air Force.

395

Definition: Thermoelectric power generation | Open Energy Information  

Open Energy Info (EERE)

Thermoelectric power generation Thermoelectric power generation Jump to: navigation, search Dictionary.png Thermoelectric power generation The conversion of thermal energy into electrical energy. Thermoelectric generation relies on a fuel source (e.g. fossil, nuclear, biomass, geothermal, or solar) to heat a fluid to drive a turbine[1] View on Wikipedia Wikipedia Definition The thermoelectric effect is the direct conversion of temperature differences to electric voltage and vice-versa. A thermoelectric device creates voltage when there is a different temperature on each side. Conversely, when a voltage is applied to it, it creates a temperature difference. At the atomic scale, an applied temperature gradient causes charge carriers in the material to diffuse from the hot side to the cold

396

Anisotropic etching of polymer films by high energy ,,100s of eV... oxygen atom neutral beams  

E-Print Network [OSTI]

Anisotropic etching of polymer films by high energy ,,Ã?100s of eV... oxygen atom neutral beams to generate an energetic 100s of eV , high flux equivalent of 10s mA/cm2 oxygen atom neutral beam. Positive of the boundary voltage which controls neutral beam energy , and was independent of substrate temperature

Economou, Demetre J.

397

Generation gaps in engineering?  

E-Print Network [OSTI]

There is much enthusiastic debate on the topic of generation gaps in the workplace today; what the generational differences are, how to address the apparent challenges, and if the generations themselves are even real. ...

Kim, David J. (David Jinwoo)

2008-01-01T23:59:59.000Z

398

Hydrogen Generation by Electrolysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Better Engineered Solutions. Better Engineered Solutions. What Listening Generates. Better Engineered Solutions. What Listening Generates. Hydrogen Generation by Electrolysis September 2004 Steve Cohen Hydrogen Generation by Electrolysis September 2004 Steve Cohen NREL H 2 Electrolysis - Utility Integration Workshop NREL H 2 Electrolysis - Utility Integration Workshop 2 Hydrogen Generation by Electrolysis Hydrogen Generation by Electrolysis  Intro to Teledyne Energy Systems  H 2 Generator Basics & Major Subsystems  H 2 Generating & Storage System Overview  Electrolysis System Efficiency & Economics  Focus for Attaining DOE H 2 Production Cost Goals 3 Teledyne Energy Systems Locations - ISO 9001 Teledyne Energy Systems Locations - ISO 9001 Hunt Valley, Maryland  State-of-the-art thermoelectric,

399

Entangling two atoms in spatially separated cavities through both photon emission and absorption processes  

E-Print Network [OSTI]

We consider a system consisting of a $\\Lambda$-type atom and a V-type atom, which are individually trapped in two spatially separated cavities that are connected by an optical fibre. We show that an extremely entangled state of the two atoms can be deterministically generated through both photon emission of the $\\Lambda$-type atom and photon absorption of the V-type atom in an ideal situation. The influence of various decoherence processes such as spontaneous emission and photon loss on the fidelity of the entangled state is also investigated. We find that the effect of photon leakage out of the fibre on the fidelity can be greatly diminished in some special cases. As regards the effect of spontaneous emission and photon loss from the cavities, we find that the present scheme with a fidelity higher than 0.98 may be realized under current experiment conditions.

Peng Peng; Fu-li Li

2006-12-29T23:59:59.000Z

400

Theory of Hydrogen Storage in Complex Hydrides - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

53 53 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Christopher Wolverton Department of Materials Science & Engineering, Northwestern University 2220 Campus Drive, Room 2036 Evanston, IL 60208-3108 Phone: (734) 678-6319 Email: c-wolverton@northwestern.edu Vidvuds Ozolins Department of Materials Science & Engineering, University of California, Los Angeles DOE Program Officer: James Davenport Program Manager Theoretical Condensed Matter Physics Office of Basic Energy Sciences Email: James.Davenport@science.doe.gov Phone: (301) 903-0035 Objectives Using first-principles methods, determine the atomic- level processes that are rate limiting in hydrogen storage

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

ENERGY GENERATION RESEARCH PIER Energy Generation Research  

E-Print Network [OSTI]

ENERGY GENERATION RESEARCH PIER Energy Generation Research www.energy.ca.gov/research/ renewable/ November 2010 Sonoma County RESCO A Local Level Approach to Renewable Energy Portfolios. The Issue To address energy usage that contributes to climate change, California has enacted legislation to guide

402

Preliminary steps to the Atomic Energy Commission  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

steps to the Atomic Energy Commission By October 1946, General Groves had seen the writing on the wall. The Manhattan District was destined to give up the atomic energy program to...

403

Moving closer to the Atomic Energy Commission  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Moving closer to the Atomic Energy Commission Last week we examined some events in Oak Ridge resulting from the struggle for control of atomic weapons. There was also a transition...

404

Gamma ray generator  

DOE Patents [OSTI]

An embodiment of a gamma ray generator includes a neutron generator and a moderator. The moderator is coupled to the neutron generator. The moderator includes a neutron capture material. In operation, the neutron generator produces neutrons and the neutron capture material captures at least some of the neutrons to produces gamma rays. An application of the gamma ray generator is as a source of gamma rays for calibration of gamma ray detectors.

Firestone, Richard B; Reijonen, Jani

2014-05-27T23:59:59.000Z

405

UNITED STATES ATOMIC ENERGY COMMISSION  

Office of Legacy Management (LM)

I(S.0 -01: I(S.0 -01: SPECIAL NUCLEAR MATERIAL LlCEWSE Pursuant to the Atomic Energy Act of 1954 and Title 10, Code of Federal Regulations, Chapter 1, Part 70, "Special Nuclear Material Regulations," o. license is hereby issued authorizing the licensee to receive and possess the special nuclear material designated below; to use such special nuclear material for the purpose(s) and at the place(s) designated below; and to transfer such material to persons' authorized to receive it in accordance with the regulations in said Port. This license shall be deemed to contain the conditions specified in Section 70.32(a) of said regulations, and is subject to all applicable rules, regtdations, and orders of the Atomic Energy Commission now or hereafter in

406

The Modified Embedded Atom Method  

SciTech Connect (OSTI)

Recent modifications have been made to generalize the Embedded Atom Method (EAM) to describe bonding in diverse materials. By including angular dependence of the electron density in an empirical way, the Modified Embedded Atom Method (MEAM) has been able to reproduce the basic energetic and structural properties of 45 elements. This method is ideally suited for examining the interfacial behavior of dissimilar materials. This paper explains in detail the derivation of the method, shows how the parameters of the MEAM are determined directly from experiment or first principles calculations, and examines the quality of the reproduction of the database. Materials with fcc, bcc, hcp, and diamond cubic crystal structure are discussed. A few simple examples of the application of the MEAM to surfaces and interfaces are presented. Calculations of pullout of a SiC fiber in a diamond matrix as a function of applied stress show non-uniform deformation of the fiber.

Baskes, M.I.

1994-08-01T23:59:59.000Z

407

Generation to Generation: The Heart of Family Medicine  

E-Print Network [OSTI]

Ageism in the Workplace. Generations Spring, 5. Westman,of caring for multiple generations simultaneously. StronglyGeneration to Generation: The Heart of Family Medicine

Winter, Robin O

2012-01-01T23:59:59.000Z

408

Muon bremsstrahlung on heavy atoms  

Science Journals Connector (OSTI)

The cross section for high energy muon bremsstrahlung on heavy atoms is calculated without the use of the Born approximation. It is shown that the correction to the Born approximation in the region of momentum transfers q of the order of ?c has the same order of magnitude as the well-known correction of Davies, Bethe, and Maximon. It is shown also that these corrections have different signs and nearly compensate each other.

Yu. M. Andreev and E. V. Bugaev

1997-02-01T23:59:59.000Z

409

The Future of Atomic Energy  

DOE R&D Accomplishments [OSTI]

There is definitely a technical possibility that atomic power may gradually develop into one of the principal sources of useful power. If this expectation will prove correct, great advantages can be expected to come from the fact that the weight of the fuel is almost negligible. This feature may be particularly valuable for making power available to regions of difficult access and far from deposits of coal. It also may prove a great asset in mobile power units for example in a power plant for ship propulsion. On the negative side there are some technical limitations to be applicability of atomic power of which perhaps the most serious is the impossibility of constructing light power units; also there will be some peculiar difficulties in operating atomic plants, as for example the necessity of handling highly radioactive substances which will necessitate, at least for some considerable period, the use of specially skilled personnel for the operation. But the chief obstacle in the way of developing atomic power will be the difficulty of organizing a large scale industrial development in an internationally safe way. This presents actually problems much more difficult to solve than any of the technical developments that are necessary, It will require an unusual amount of statesmanship to balance properly the necessity of allaying the international suspicion that arises from withholding technical secrets against the obvious danger of dumping the details of the procedures for an extremely dangerous new method of warfare on a world that may not yet be prepared to renounce war. Furthermore, the proper balance should be found in the relatively short time that will elapse before the 'secrets' will naturally become open knowledge by rediscovery on part of the scientists and engineers of other countries.

Fermi, E.

1946-05-27T23:59:59.000Z

410

Atomic Ordering Enhanced Electrocatalytic Activity of Nanoalloys...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ordering Enhanced Electrocatalytic Activity of Nanoalloys for Oxygen Reduction Reaction. Atomic Ordering Enhanced Electrocatalytic Activity of Nanoalloys for Oxygen Reduction...

411

Electron-hole generation and recombination rates for Coulomb scattering in graphene Farhan Rana*  

E-Print Network [OSTI]

Electron-hole generation and recombination rates for Coulomb scattering in graphene Farhan Rana ionization in zero band-gap graphene. The conduction and valence band dispersion relation in graphene.55.Cn I. INTRODUCTION Graphene is a single two-dimensional 2D atomic layer of carbon atoms forming

Afshari, Ehsan

412

Classical Radiative Cascade in Antiproton Atoms  

SciTech Connect (OSTI)

An interrelation between radiative cascade transitions and annihilation rates in antiproton atoms is considered. The population of antiproton atom energy levels is described by a classical distribution function f(n,l), determining intensities of spectral lines in antiproton atoms. A strong dependence of spectral line intensities on the nuclear size is shown which could be used for the determination of effective nuclear radius.

Bureyeva, L. [Institute of Spectroscopy of the RAS, Troitsk, Moscow Reg., 142190 (Russian Federation); Lisitsa, V. [Nuclear Fusion Institute, Russian Research Center 'Kurchatov Institute' Moscow (Russian Federation); Putlitz, G. zu [Physikalisches Institut, Universitaet Heidelberg, Philosophenweg 12, 69120 Heidelberg (Germany)

2005-10-26T23:59:59.000Z

413

Sources of polarized ions and atoms  

SciTech Connect (OSTI)

In this presentation we discuss methods of producing large quantities of polarized atoms and ions (Stern-Gerlach separation, optical pumping, and spin-exchange) as well as experimental methods of measuring the degree of polarization of atomic systems. The usefulness of polarized atoms in probing the microscopic magnetic surface properties of materials will also be discussed. 39 refs., 5 figs., 2 tabs.

Cornelius, W.D.

1988-01-01T23:59:59.000Z

414

Atoms, photons, and Information Andrew Silberfarb  

E-Print Network [OSTI]

Atoms, photons, and Information by Andrew Silberfarb B.S. California Institute of Technology, 1998 #12;Atoms, photons, and Information by Andrew Silberfarb ABSTRACT OF DISSERTATION Submitted in Partial Albuquerque, New Mexico March, 2006 #12;Atoms, photons, and Information by Andrew Silberfarb B.S. California

Deutsch, Ivan H.

415

Stark spectroscopy on rare gas atoms  

E-Print Network [OSTI]

Stark spectroscopy on rare gas atoms PROEFSCHRIFT ter verkrijging van de graad van doctor aan de-DATA LIBRARY TECHNISCHE UNIVERSITEIT EINDHOVEN Jiang, Tao Stark spectroscopy on rare gas atoms / by Tao Jiang / gasontladingen Subject headings : plasma diagnostics / Stark effect / optogalvanic spectroscopy / atomic emission

Eindhoven, Technische Universiteit

416

The Reaction of Hydrogen Atoms with Ethylene  

Science Journals Connector (OSTI)

...research-article The Reaction of Hydrogen Atoms with Ethylene M. P. Halstead D. A. Leathard R...the reaction between hydrogen atoms and ethylene in a discharge-flow system at 290 3...argon were used and the hydrogen atom and ethylene flow rates were in the ranges 5 to 10...

1970-01-01T23:59:59.000Z

417

Riso Report No. Danish Atomic Energy Commission  

E-Print Network [OSTI]

fM O o 8- OL '·O c/i Riso Report No. Danish Atomic Energy Commission Research Establishment Riso/t on exchangefrom: Library, Danish Atomic Energy Commission, Risd, Roskilde, Denmark #12;May, 1966 Ris6 Report No Jagiellonski Institute of Physics Krakow, Poland and P. A. Lindgård Mogensen The Danish Atomic Energy

418

Danish Atomic Energy Commission Research Establishment Riso  

E-Print Network [OSTI]

10 Ol CM l-l I S l ^. n ·H Danish Atomic Energy Commission Research Establishment Riso Chemistry Atomic Energy Commission Z. Fordos, Concrete Research Laboratory Karlstrup M. Skytte, Betonvarefabriken. E. Bjergbakke, Accelerator Dept. Danish Atomic Energy Commission Z. FSrdos, Concrete Research

419

so Ris Report * Danish Atomic Energy Commission  

E-Print Network [OSTI]

so Risø Report r- 6 §* Danish Atomic Energy Commission 2 Research Establishment Risø Incorporation Commission Research Establishment Risø by lb Larsen Danish Atomic Energy Commission Research Establishment in Bitumen of Low-Level Radioactive Waste Water Evaporator Concentrate at the Danish Atomic Energy Com

420

Using Chemical Shifts to Assess Transient Secondary Structure and Generate Ensemble Structures of Intrinsically Disordered Proteins  

Science Journals Connector (OSTI)

The chemical shifts of backbone atoms in polypeptides are sensitive to the dihedral angles phi and psi and can be used to estimate transient secondary structure and to generate structural ensembles of intrinsical...

Stepan Kashtanov; Wade Borcherds; Hongwei Wu…

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Carbon Layers Lead the Way towards a New Generation of Metamaterials...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Layers Lead the Way towards a New Generation of Metamaterials Graphene - a one layer thick sheet of carbon atoms - has special properties that make it a desirable material...

422

Left alone, palladium atoms get the job done | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Left alone, palladium atoms get the job done Left alone, palladium atoms get the job done Isolated atoms tackle carbon monoxide, potentially reducing engine emissions A vehicle's...

423

Self-corrected Sensors Based On Atomic Absorption Spectroscopy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy. Self-corrected Sensors Based On Atomic Absorption Spectroscopy For...

424

Understanding Atom Probe Tomography of Oxide-Supported Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atom Probe Tomography of Oxide-Supported Metal Nanoparticles by Correlation with Atomic Resolution Electron Understanding Atom Probe Tomography of Oxide-Supported Metal...

425

Design and Fabrication of a Chip-based Continuous-wave Atom Laser  

E-Print Network [OSTI]

We present a design for a continuous-wave (CW) atom laser on a chip and describe the process used to fabricate the device. Our design aims to integrate quadrupole magnetic guiding of ground state Rb atoms with continuous surface adsorption evaporative cooling to create a continuous Bose-Einstein condensate; out-coupled atoms from the condensate should realize a CW atom laser. We choose a geometry with three wires embedded in a spiral pattern in a silicon subtrate. The guide features an integrated solenoid to mitigate spin-flip losses and provide a tailored longitudinal magnetic field. Our design also includes multiple options for atom interferometry: accomodations are in place for laser-generated atom Fabry-Perot and Mach-Zehnder interferometers, and a pair of atomic beam X-splitters is incorporated for an all-magnetic atom Mach-Zehnder setup. We demonstrate the techniques necessary to fabricate our device using existing micro- and nano-scale fabrication equipment, and discuss future options for modified desi...

Power, E P; Vanderelzen, B; Herrera-Fierro, P; Murphy, R; Yalisove, S M; Raithel, G

2012-01-01T23:59:59.000Z

426

Cooling and Trapping Atoms Atoms are slowed and cooled by radiation pressure from laser light  

E-Print Network [OSTI]

Cooling and Trapping Atoms Atoms are slowed and cooled by radiation pressure from laser light and then trapped in a bottle whose "walls" are magnetic fields. Cooled atoms are ideal for exploring basic. research has traditionally been the study of the intrinsic prop erties of isolated atoms. In the early part

Johannesson, Henrik

427

Atomic flux measurement by diode-laser-based atomic absorption spectroscopy  

E-Print Network [OSTI]

Atomic flux measurement by diode-laser-based atomic absorption spectroscopy Weizhi Wang,a) R. H, California 94305 Received 5 May 1999; accepted 6 June 1999 Diode-laser-based atomic absorption AA sensors- quirements, and only the QCM measures the flux. Lamp- based atomic absorption AA sensors have been success

Fejer, Martin M.

428

NAAP Hydrogen Atom 1/9 The Hydrogen Atom Student Guide  

E-Print Network [OSTI]

Name: NAAP ­ Hydrogen Atom 1/9 The Hydrogen Atom ­ Student Guide Background Material Carefully read and the Quantum model represent the Hydrogen atom. In some cases they both describe things in the same way frequency, smaller energy, and the same velocity through space as a blue photon". #12;NAAP ­Hydrogen Atom 2

Farritor, Shane

429

Zeeman deceleration of electron-impact-excited metastable helium atoms  

E-Print Network [OSTI]

We present experimental results that demonstrate - for the first time - the Zeeman deceleration of helium atoms in the metastable 2^3S_1state. A more than 40% decrease of the kinetic energy of the beam is achieved for deceleration from 490 m/s to a final velocity of 370 m/s. Metastable atom generation is achieved with an electron-impact-excitation source whose performance is enhanced through an additional discharge-type process which we characterize in detail. Comparison of deceleration data at different electron beam pulse durations confirms that a matching between the initial particle distribution and the phase-space acceptance of the decelerator is crucial for the production of a decelerated packet with a well-defined velocity distribution. The experimental findings are in good agreement with three-dimensional numerical particle trajectory simulations.

Dulitz, Katrin; Softley, Timothy P

2015-01-01T23:59:59.000Z

430

The 1993 atomic mass evaluation: (I) Atomic mass table  

Science Journals Connector (OSTI)

This paper is the first of a series of four. In it, a table is given to replace the 1983 atomic mass table. The differences with the earlier table are briefly discussed and information is given of interest for the users of this table. Part II of this series gives values for several derived quantities (decay-, separation- and reaction energies), part III shows graphs of several of those quantities, and part IV gives a list of input data and full information on the used input data and on the procedures used in deriving the tables in the preceding parts.

G. Audi; A.H. Wapstra

1993-01-01T23:59:59.000Z

431

CERTIFICATION DOCKET WESTINGHOUSE ATOMIC POWER DEVELOPMENT PLANT  

Office of Legacy Management (LM)

WESTINGHOUSE ATOMIC POWER DEVELOPMENT PLANT WESTINGHOUSE ATOMIC POWER DEVELOPMENT PLANT EAST PITTSBURGH PLANT FOREST HILLS PITTSBURGH, PENNSYLVANIA Department of Energy Office of Nuclear Energy Office of Terminal Waste Disposal and Remedial Action Division of Remedial Action Projects ..-.. --__- _".-.-l--_--l -_._ _- --- ~~~. . ..~ CONTENTS Page - - I NTRODUCTI ON 1 Purpose 1 Docket Contents 1 Exhibit I: Summary of Activities at Westinghouse Atomic Power Development Plant, East Pittsburgh Plant, Forest Hills, Pittsburgh, Pennsylvania I-l Exhibit II: Documents Supporting the Certification of Westinghouse Atomic Power Development Plant, East Pittsburgh Plant, Forest Hills, Pittsburgh, Pennsylvania iii II-1 . . .- .__.^ I ^_... _.-__^-____-. - CERTIFICATION DOCKET WESTINGHOUSE ATOMIC POWER DEVELOPMENT PLANT

432

Princeton Plasma Physics Lab - General Atomics (GA)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

general-atomics-ga General general-atomics-ga General Atomics en The Scorpion's Strategy: "Catch and Subdue" http://www.pppl.gov/node/1132

American Fusion News Category: 
atomics-ga">General Atomics (GA)
433

Laser-induced "two-atom" coherence  

Science Journals Connector (OSTI)

Our analysis shows that if an electromagnetic field excites a coherent superposition of states of two different types of atoms, then the results of a collision of those two atoms can be quite different from the usual dephasing that a coherently excited atom suffers upon collision with another atom. We present the concept of "two-atom" coherence as one feature of this interaction where the field of a given wavelength may interact with the system coherently over a wide range of internuclear distances.

Munir H. Nayfeh and G. B. Hillard

1984-04-01T23:59:59.000Z

434

The Atomic Energy Commission By Alice Buck  

Broader source: Energy.gov (indexed) [DOE]

Atomic Energy Atomic Energy Commission By Alice Buck July 1983 U.S. Department of Energy Office of Management Office of the Executive Secretariat Office of History and Heritage Resources 1 Introduction Almost a year after World War II ended, Congress established the United States Atomic Energy Commission to foster and control the peacetime development of atomic science and technology. Reflecting America's postwar optimism, Congress declared that atomic energy should be employed not only in the Nation's defense, but also to promote world peace, improve the public welfare, and strengthen free competition in private

435

Fresh-Core Reload of the Neutron Radiography (NRAD) Reactor with Uranium(20)-Erbium-Zirconium-Hydride Fuel  

SciTech Connect (OSTI)

The neutron radiography (NRAD) reactor is a 250 kW TRIGA® (Training, Research, Isotopes, General Atomics) Mark II , tank-type research reactor currently located in the basement, below the main hot cell, of the Hot Fuel Examination Facility (HFEF) at the Idaho National Laboratory (INL). It is equipped with two beam tubes with separate radiography stations for the performance of neutron radiography irradiation on small test components. The 60-fuel-element operational core configuration of the NRAD LEU TRIGA reactor has been evaluated as an acceptable benchmark experiment. The initial critical configuration developed during the fuel loading process, which contains only 56 fuel elements, has not been evaluated as it is very similar to the evaluated core configuration. The benchmark eigenvalue is 1.0012 ± 0.0029. Calculated eigenvalues differ significantly (~±1%) from the benchmark eigenvalue and have demonstrated sensitivity to the thermal scattering treatment of hydrogen in the U-Er-Zr-H fuel.

John D. Bess; Thomas L. Maddock; Margaret A. Marshall; Leland M. Montierth

2011-03-01T23:59:59.000Z

436

Fresh-Core Reload of the Neutron Radiography (NRAD) Reactor with Uranium(20)-Erbium-Zirconium-Hydride Fuel  

SciTech Connect (OSTI)

The neutron radiography (NRAD) reactor is a 250 kW TRIGA® (Training, Research, Isotopes, General Atomics) Mark II , tank-type research reactor currently located in the basement, below the main hot cell, of the Hot Fuel Examination Facility (HFEF) at the Idaho National Laboratory (INL). It is equipped with two beam tubes with separate radiography stations for the performance of neutron radiography irradiation on small test components. The 60-fuel-element operational core configuration of the NRAD LEU TRIGA reactor has been evaluated as an acceptable benchmark experiment. The initial critical configuration developed during the fuel loading process, which contains only 56 fuel elements, has not been evaluated as it is very similar to the evaluated core configuration. The benchmark eigenvalue is 1.0012 ± 0.0029. Calculated eigenvalues differ significantly (~±1%) from the benchmark eigenvalue and have demonstrated sensitivity to the thermal scattering treatment of hydrogen in the U-Er-Zr-H fuel.

John D. Bess; Thomas L. Maddock; Margaret A. Marshall; Leland M. Montierth

2014-03-01T23:59:59.000Z

437

Contaminant-Generation Mechanisms  

Science Journals Connector (OSTI)

In the last chapter, the areas where contaminants are generated were discussed. Knowing the location of contaminant generation is helpful in controlling that contamination, but understanding the mechanisms is ...

Alvin Lieberman

1992-01-01T23:59:59.000Z

438

Using Backup Generators  

Broader source: Energy.gov [DOE]

Power outages are commonplace during disasters, and they may last for several days. You can reduce losses and speed the recovery process by installing an emergency generator. Portable generators...

439

X-Ray Generators  

Science Journals Connector (OSTI)

There are many types of X-ray generators sold commercially. The following are some of ... that should be considered when selecting a particular generator for a particular purpose. All the companies listed below s...

Reuben Rudman

1972-01-01T23:59:59.000Z

440

Geothermal Power Generation  

SciTech Connect (OSTI)

The report provides an overview of the renewed market interest in using geothermal for power generation including a concise look at what's driving interest in geothermal power generation, the current status of geothermal power generation, and plans for the future. Topics covered in the report include: an overview of geothermal power generation including its history, the current market environment, and its future prospects; an analysis of the key business factors that are driving renewed interest in geothermal power generation; an analysis of the challenges that are hindering the implementation of geothermal power generation projects; a description of geothermal power generation technologies; a review of the economic drivers of geothermal power generation project success; profiles of the major geothermal power producing countries; and, profiles of the major geothermal power project developers.

NONE

2007-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Atomic Structure Calculations from the Los Alamos Atomic Physics Codes  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The well known Hartree-Fock method of R.D. Cowan, developed at Los Alamos National Laboratory, is used for the atomic structure calculations. Electron impact excitation cross sections are calculated using either the distorted wave approximation (DWA) or the first order many body theory (FOMBT). Electron impact ionization cross sections can be calculated using the scaled hydrogenic method developed by Sampson and co-workers, the binary encounter method or the distorted wave method. Photoionization cross sections and, where appropriate, autoionizations are also calculated. Original manuals for the atomic structure code, the collisional excitation code, and the ionization code, are available from this website. Using the specialized interface, you will be able to define the ionization stage of an element and pick the initial and final configurations. You will be led through a series of web pages ending with a display of results in the form of cross sections, collision strengths or rates coefficients. Results are available in tabular and graphic form.

Cowan, R. D.

442

Manhattan Project: Atomic Discoveries, 1890s-1939  

Office of Scientific and Technical Information (OSTI)

Excerpt from the comic book "Adventures Inside the Atom." Click on this image or visit the "Library" to view the whole comic book. ATOMIC DISCOVERIES Excerpt from the comic book "Adventures Inside the Atom." Click on this image or visit the "Library" to view the whole comic book. ATOMIC DISCOVERIES (1890s-1939) Events A Miniature Solar System, 1890s-1919 Exploring the Atom, 1919-1932 Atomic Bombardment, 1932-1938 The Discovery of Fission, 1938-1939 Fission Comes to America, 1939 Philosophers of Ancient Greece reasoned that all matter in the universe must be composed of fundamental, unchangeable, and indivisible objects, which they called "atoma" ("ατoµα"). The exact nature of these atoms remained elusive, however, despite centuries of attempts by alchemists to create a "philosopher's stone" that could transmute atoms of lead to gold, prove the Greeks wrong, and make its inventors Modern model of an atom very rich. It was only in the late 1890s and the early twentieth-century that this view of a solid atom, bouncing around the universe like a billiard ball, was replaced by an atom that resembled more a miniature solar system, its electrons orbiting around a small nucleus. Explorations into the nature of the atom from 1919 to 1932 confirmed this new model, especially with Ernest Rutherford's 1919 success in finally transmuting an atom of one substance into another and with James Chadwick's 1932 discovery of the elusive final basic particle of the atom, the neutron. From 1932 to 1938, scientists around the world learned a great deal more about atoms, primarily by bombarding the nuclei of atoms and using a variety of particle accelerators. In 1938, word came from Berlin of the most startling result of them all: the nucleus of an atom could actually be split in two, or "fissioned." This breakthrough was quickly confirmed in the United States and elsewhere. According to the theories of Albert Einstein, the fission of an atom should result in a release of energy. An "atomic bomb" was now no longer just science fiction -- it was a distinct possibility.

443

ARPA-E PROJECT SELECTIONS ROBUST AFFORDABLE NEXT GENERATION EV-STORAGE (RANGE)  

E-Print Network [OSTI]

Propulsion Laboratory $2,834,335 Pasadena, CA Metal Hydride-Air Battery Jet Propulsion Laboratory (JPL) will develop a new water-based metal hydride-air battery. When compared to the lithium-ion batteries currently. $448,680 Emeryville, CA Dendrite Free Zinc-Air Battery EnZinc, in collaboration with the U.S. Naval

444

Atomic Spectroscopy and Separated Isotopes  

Science Journals Connector (OSTI)

The advantages in the use of separated isotopes in atomic spectroscopy for the determination of nuclear momentsI ? Q and for studies of the isotope-shift phenomena are discussed. Illustrations of spectra are given for mercury uranium and samarium. In addition a summary is given of twenty-two so-called problem nuclei i.e. those naturally occurring isotopes for which the nuclear moments are completely uncertain. Concluding remarks are made on such problems as the evaluation of the absolute magnitude of isotope shifts the role of “forbidden transitions” in isotope spectra and the potential future value of spectro-isotopic assay techniques.

J. R. McNally Jr.

1952-01-01T23:59:59.000Z

445

A Generative Dependency Grammar  

Science Journals Connector (OSTI)

We propose a new kind of grammar: the Generative Dependency Grammar (GDG) based on dependency trees (DT) and a generative process. By generating a surface text using these GDG, the DT of the text is obtained too. GDG formalism is starting to be used ...

Stefan Diaconescu

2002-08-01T23:59:59.000Z

446

Plasma production by the trapping of energetic atoms  

Science Journals Connector (OSTI)

The production of a hot plasma by the injection of streams of energetic atoms into a confining magnetic field is discussed. The experiments described are directed towards injection of 20-keV hydrogen or deuterium atoms into a magnetic mirror field. The results of some numerical calculations of the plasma growth to a steady-state in a constant magnetic field are presented, including the calculation of the spatial distribution of the trapped ions. In these calculations, the primary trapping mechanism is the ionization of beam atoms by trapped ions and electrons. Parametric values are assigned to approximate the experimentally attainable conditions. The indicated equilibrium densities are in the range of 1014/cm3, at ? ? 1%, with typical growth times of a few seconds, if the final density is determined by ion-ion scattering into the mirror loss cone.The practical achievement of a hot plasma by this injection method depends upon maximizing the trapping rate, and minimizing the particle loss due to charge-exchange scattering. Severe requirements are therefore placed on the atomic beam intensity and the gas density in the confinement region. Some of the requirements on the build-up conditions imposed by plasma stability considerations are also discussed.Progress toward meeting the technological requirements is described. A highly collimated beam of hydrogen atoms in excess of 5 × 1017 atoms/sec at 20-keV energy has been produced. The cross-sectional area of the beam is 20 cm2 at a distance of 360 cm from the source; the half-angle divergence is less than 10 milliradians. Vacuum techniques have been developed to achieve base pressures in the 10?10 mm Hg range without extensive bakeout procedure. At the same time pumping speeds exceeding 105l/sec for hydrogen are available.A method of trapping the energetic atoms by means of a transient “cold” plasma is also discussed. This procedure greatly increases the initial plasma growth rate. The plasma density attainable depends upon the beam intensity, vacuum, and cold plasma density, the latter two being time-dependent. The generation of a suitable cold plasma is described.

C.C. Damm; A.H. Futch; F. Gordon; A.L. Hunt; E.C. Popp; R.F. Post; J.F. Steinhaus

1961-01-01T23:59:59.000Z

447

Hydrogen Atom in Relativistic Motion  

E-Print Network [OSTI]

The Lorentz contraction of bound states in field theory is often appealed to in qualitative descriptions of high energy particle collisions. Surprisingly, the contraction has not been demonstrated explicitly even in simple cases such as the hydrogen atom. It requires a calculation of wave functions evaluated at equal (ordinary) time for bound states in motion. Such wave functions are not obtained by kinematic boosts from the rest frame. Starting from the exact Bethe-Salpeter equation we derive the equal-time wave function of a fermion-antifermion bound state in QED, i.e., positronium or the hydrogen atom, in any frame to leading order in alpha. We show explicitly that the bound state energy transforms as the fourth component of a vector and that the wave function of the fermion-antifermion Fock state contracts as expected. Transverse photon exchange contributes at leading order to the binding energy of the bound state in motion. We study the general features of the corresponding fermion-antifermion-photon Fock states, and show that they do not transform by simply contracting. We verify that the wave function reduces to the light-front one in the infinite momentum frame.

M. Jarvinen

2005-04-11T23:59:59.000Z

448

Quantum Noise and Correlations in Resonantly Enhanced Wave Mixing Based on Atomic Coherence  

Science Journals Connector (OSTI)

We investigate the quantum properties of fields generated by resonantly enhanced wave mixing based on atomic coherence in Raman systems. We show that such a process can be used for generation of pairs of Stokes and anti-Stokes fields with nearly perfect quantum correlations, yielding almost complete (i.e., 100%) squeezing without the use of a cavity. We discuss the extension of the wave mixing interactions into the domain of a few interacting light quanta.

M. D. Lukin; A. B. Matsko; M. Fleischhauer; M. O. Scully

1999-03-01T23:59:59.000Z

449

The Harnessed Atom | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Services » The Harnessed Atom Services » The Harnessed Atom The Harnessed Atom The Harnessed Atom The Harnessed Atom is a new middle school science, technology, engineering, and math (STEM) curriculum extension that focuses on nuclear science and energy. It offers teachers accurate, unbiased, and up-to-date information on the roles that energy and nuclear science play in our lives. The curriculum includes essential principles and fundamental concepts of energy science. This teacher's kit is an updated and expanded edition of the acclaimed 1985 Harnessed Atom curriculum from the U.S. Department of Energy. It was developed with extensive input from classroom teachers across the country in pilot test reviews and workshops, as well as technical reviews from scientists and experts at universities, professional societies, and

450

An output coupler for Bose condensed atoms The observations of BEC have stimulated interest in atom lasers, coherent sources of  

E-Print Network [OSTI]

An output coupler for Bose condensed atoms The observations of BEC have stimulated interest in atom lasers, coherent sources of atomic matter waves. The build-up of atoms in the ground state of a magnetic. We demonstrated a scheme for doing this with Bose condensed atoms [1]. A variable fraction of atoms

451

Atomic-level control of the thermoelectric properties in polytypoid nanowires Sean C. Andrews,ab  

E-Print Network [OSTI]

electrical power is generated through the scavenging of waste heat. The efficiency of this conversion the scavenging of waste heat. Materials containing nanometer-sized structural and compositional features canAtomic-level control of the thermoelectric properties in polytypoid nanowires Sean C. Andrews

Yang, Peidong

452

Addendum to "Theory of a He3 Atom in Liquid He4 at T=0"  

Science Journals Connector (OSTI)

An improved estimate of the interaction matrix element ?k?, k??|H-?k?|H|k??|k?? is generated by a new approximation for the three-particle distribution function. Revised numerical results are presented for binding energy, effective mass, and differential volume coefficient of the He3 atom in solution.

T. B. Davison and E. Feenberg

1969-06-05T23:59:59.000Z

453

Statistical atom: Some quantum improvements  

Science Journals Connector (OSTI)

The Thomas-Fermi model is improved by simultaneously introducing three different quantum corrections. The first concerns the nonlocality of quantum mechanics; we go beyond the von Weizsäcker approach by including arbitrary powers of the gradient of the single-particle potential. The second is a special treatment of the strongly bound electrons, which removes the incorrect statistical description of the vicinity of the nucleus. In the third we generalize Dirac's way of handling the exchange interaction by, again, including gradient effects to arbitrary order. All this is done in the framework of a "potential-functional method" and results in a new differential equation for the potential. The comparison of numerical results with both experimental and Hartree-Fock data for the mean-squared distance indicates a superiority of the new statistical theory over the Hartree-Fock theory, at least for the description of the outer reaches of the atom.

Berthold-Georg Englert and Julian Schwinger

1984-05-01T23:59:59.000Z

454

Ps-atom scattering at low energies  

E-Print Network [OSTI]

A pseudopotential for positronium-atom interaction, based on electron-atom and positron-atom phase shifts, is constructed, and the phase shifts for Ps-Kr and Ps-Ar scattering are calculated. This approach allows us to extend the Ps-atom cross sections, obtained previously in the impulse approximation [Phys. Rev. Lett. 112, 243201 (2014)], to energies below the Ps ionization threshold. Although experimental data are not available in this low-energy region, our results describe well the tendency of the measured cross sections to drop with decreasing velocity at $venergy region, in contrast to the inter...

Fabrikant, I I

2015-01-01T23:59:59.000Z

455

Gas Atomization of Stainless Steel - Slow Motion  

SciTech Connect (OSTI)

Stainless steel liquid atomized by supersonic argon gas into a spray of droplets at ~1800ºC. Atomization of metal requires high pressure gas and specialized chambers for cooling and collecting the powders without contamination. The critical step for morphological control is the impingement of the gas on the melt stream. The video is a black and white high speed video of a liquid metal stream being atomized by high pressure gas. This material was atomized at the Ames Laboratory's Materials Preparation Center http://www.mpc.ameslab.gov

None

2011-01-01T23:59:59.000Z

456

Interfacing ultracold atoms and mechanical oscillators.  

E-Print Network [OSTI]

??In this thesis I present experiments investigating controlled coupling between mechanical oscillators and ultracold atoms. I report on three different coupling mechanisms. In a first… (more)

Camerer, Stephan

2011-01-01T23:59:59.000Z

457

Cold collisions of Rb and Cs atoms  

E-Print Network [OSTI]

Jamieson,M.J. Sarbazi-Azad,H. 18'th International Conference on Atomic Physics, MIT, Cambridge, MA, USA Academic Press

Jamieson, M.J.

458

Nonlinear optics with two trapped atoms  

SciTech Connect (OSTI)

We show theoretically that two atomic dipoles in a resonator constitute a nonlinear medium, whose properties can be controlled through the relative position of the atoms inside the cavity and the detuning and intensity of the driving laser. We identify the parameter regime where the system operates as a parametric amplifier, based on the cascade emission of the collective dipole of the atoms, and determine the corresponding spectrum of squeezing of the field at the cavity output. This dynamics might be observed as a result of self-organization of laser-cooled atoms in resonators.

Fernandez-Vidal, Sonia; Zippilli, Stefano [Departament de Fisica, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain); ICFO-Institut de Ciencies Fotoniques, E-08860 Castelldefels, Barcelona (Spain); Morigi, Giovanna [Departament de Fisica, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain)

2007-11-15T23:59:59.000Z

459

United States Atomic Energy Commission formed  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

formed As the United Nations Atomic Energy Commission failed to come to grips with the growing nuclear weapons problem, the United States worked to establish its own formal...

460

Atomic Physics and Thermonuclear Fusion Research  

Science Journals Connector (OSTI)

Presently thermonuclear fusion research is faced with a number of atomic and molecular physics problems depending on the type of high-temperature plasma investigated. The present article discusses some particular atomic physics aspects in connection with magnetically confined plasmas (Tokamaks, Stellarators): (1) rate equations for density, momentum and energy with application to plasmas; (2) initial phase of Tokamak plasmas; (3) influence of impurity radiation on operating conditions of fusion plasmas in general and on Tokamak plasmas in particular; (4) influence of atomic elementary reactions on thermodynamic plasma properties; (5) level structures of highly ionized atoms; (6) spectroscopic diagnostic problems.

H W Drawin

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

A History of the Atomic Energy Commission  

Broader source: Energy.gov [DOE]

A History of the Atomic Energy Commission - written by Alice L. BuckWashington, D.C.: U.S. Department of Energy, July 1983. 41 pp. 

462

Using Atomic Clocks to Detect Gravitational Waves  

E-Print Network [OSTI]

Atomic clocks have recently reached a fractional timing precision of $test masses separated by less than a GW wavelength, currently envisioned for the eLISA mission.

Loeb, Abraham

2015-01-01T23:59:59.000Z

463

Atomic 'mismatch' creates nano 'dumbbells' | Argonne National...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Brochures and Reports Summer Science Writing Internship Atomic 'mismatch' creates nano 'dumbbells' By Jared Sagoff * December 4, 2014 Tweet EmailPrint ARGONNE, Ill. - Like...

464

Directly correlated transmission electron microscopy and atom...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Directly correlated transmission electron microscopy and atom probe tomography of grain boundary oxidation in a Ni-Al binary Directly correlated transmission electron microscopy...

465

Steam generator support system  

DOE Patents [OSTI]

A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances.

Moldenhauer, James E. (Simi Valley, CA)

1987-01-01T23:59:59.000Z

466

Steam generator support system  

DOE Patents [OSTI]

A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source is disclosed. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances. 4 figs.

Moldenhauer, J.E.

1987-08-25T23:59:59.000Z

467

generation | OpenEI  

Open Energy Info (EERE)

generation generation Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 16, and contains only the reference case. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords AEO generation renewable energy renewable energy generating capacity Data application/vnd.ms-excel icon AEO2011: Renewable Energy Generating Capacity and Generation- Reference Case (xls, 118.9 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License License Open Data Commons Public Domain Dedication and Licence (PDDL) Comment Rate this dataset Usefulness of the metadata

468

Atomic physics at the Advanced Photon Source: Workshop report  

SciTech Connect (OSTI)

The first Workshop on Atomic Physics at the Advanced Photon Source was held at Argonne National Laboratory on March 29--30, 1990. The unprecedented brightness of the Advanced Photon Source (APS) in the hard X-ray region is expected to make possible a vast array of new research opportunities for the atomic-physics community. Starting with discussions of the history and current status of the field, presentations were made on various future directions for research with hard X-rays interacting with atoms, ions, clusters, and solids. Also important were the discussions on the design and status of the four next-generation rings coming on line during the 1990's: the ALS 1.6 GeV ring at Berkeley; the ESRF 6.0-GeV ring at Grenoble (1993); the APS 7.0-GeV ring at Argonne (1995); and the SPring-8 8.0-GeV ring in Japan (1998). The participation of more than one hundred scientists from domestic as well as foreign institutions demonstrated a strong interest in this field. We plan to organize follow-up workshops in the future emphasizing specific research topics.

Not Available

1990-10-01T23:59:59.000Z

469

NLO Partonic Event Generators  

E-Print Network [OSTI]

Merging the benefits of an NLO calculation with event generators is a topic of current interest. Among other things, it is advantageous to be able to generate unweighted events according to NLO matrix elements. I report on an algorithm which generates a sequence of unweighted momentum configurations, each configuration containing either n or n+1 four-vectors, such that for any infrared safe observable the average over these configurations coincides with the NLO calculation up to errors of a resolution variable.

Stefan Weinzierl

2002-05-10T23:59:59.000Z

470

Generation adequacy: Who decides?  

SciTech Connect (OSTI)

As part of a project for the Edison Electric Institute, the authors examined the commercial and reliability aspects of investments in new generation. This article reviews historical data and projections on new generating capacity, discusses the pros and cons of alternative ways to maintain adequacy, and quantifies the effects of mandating minimum planning-reserve margins versus reliance on market prices to stimulate investments in new generation.

Hirst, E.; Hadley, S.

1999-10-01T23:59:59.000Z

471

Annual Report Generator.  

E-Print Network [OSTI]

?? This report analyzes the needs to build an annual report generator which has the properties of Modularity, Simplicity in use and Maintainability based on… (more)

Lin, Yingwei

2006-01-01T23:59:59.000Z

472

Hydrogen Generator Appliance  

Broader source: Energy.gov (indexed) [DOE]

lAbOrAtOry NG Workshop summary report - appeNDIX J slide presentation: hydrogen Generator appliance Gus Block, Nuvera Fuel Cells...

473

Biomass: Biogas Generator  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BIOGAS GENERATOR Curriculum: Biomass Power (organic chemistry, chemicalcarbon cycles, plants, energy resourcestransformations) Grade Level: Middle School (6-8) Small groups (3 to...

474

Isolated trigger pulse generator  

DOE Patents [OSTI]

A trigger pulse generation system capable of delivering a multiplicity of isolated 100 kV trigger pulses with picosecond simultaneity. 2 figs.

Aaland, K.

1980-02-19T23:59:59.000Z

475

Generation | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

scheduling, dispatching, and accounting for capacity and energy generated at the 22 hydroelectric projects in the agencys 11-state marketing area. Southeastern has Certified...

476

EIA - Electricity Generating Capacity  

U.S. Energy Information Administration (EIA) Indexed Site

Electricity Generating Capacity Release Date: January 3, 2013 | Next Release: August 2013 Year Existing Units by Energy Source Unit Additions Unit Retirements 2011 XLS XLS XLS 2010...

477

SNE TRAFIC GENERATOR  

Energy Science and Technology Software Center (OSTI)

003027MLTPL00 Network Traffic Generator for Low-rate Small Network Equipment Software  http://eln.lbl.gov/sne_traffic_gen.html 

478

Electricity Generation | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Electricity Generation Electricity Generation Photo of geothermal power plant. A geothermal resource requires fluid, heat and permeability in order to generate electricity:...

479

Next-generation transcriptome assembly  

E-Print Network [OSTI]

technologies - the next generation. Nat Rev Genet 11, 31-algorithms for next-generation sequencing data. Genomicsassembly from next- generation sequencing data. Genome Res

Martin, Jeffrey A.

2012-01-01T23:59:59.000Z

480

Optical control of ground-state atomic orbital alignment: Cl,,2 P3/2... atoms  

E-Print Network [OSTI]

Optical control of ground-state atomic orbital alignment: Cl,,2 P3/2... atoms from HCl,,v=2,J=1-of-flight mass spectrometry. The 35 Cl 2 P3/2 atoms are aligned by two mechanisms: 1 the time-dependent transfer is conserved during the photodissociation and thus contributes to the total 35 Cl 2 P3/2 photofragment atomic

Zare, Richard N.

Note: This page contains sample records for the topic "hydride generation atomic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Atom chip microscopy: A novel probe for strongly correlated materials  

SciTech Connect (OSTI)

Improved measurements of strongly correlated systems will enable the predicative design of the next generation of supermaterials. In this program, we are harnessing recent advances in the quantum manipulation of ultracold atomic gases to expand our ability to probe these technologically important materials in heretofore unexplored regions of temperature, resolution, and sensitivity parameter space. We are working to demonstrate the use of atom chips to enable single-shot, large area detection of magnetic flux at the 10^-7 flux quantum level and below. By harnessing the extreme sensitivity of atomic clocks and Bose-Einstein condensates (BECs) to external perturbations, the cryogenic atom chip technology developed here will provide a magnetic flux detection capability that surpasses other techniques---such as scanning SQUIDs---by a factor of 10--1000. We are testing the utility of this technique by using rubidium BECs to image the magnetic fields emanating from charge transport and magnetic domain percolation in strongly correlated materials as they undergo temperature-tuned metal--to--insulator phase transitions. Cryogenic atom chip microscopy introduces three very important features to the toolbox of high-resolution, strongly correlated material microscopy: simultaneous detection of magnetic and electric fields (down to the sub-single electron charge level); no invasive large magnetic fields or gradients; simultaneous micro- and macroscopic spatial resolution; freedom from 1/f flicker noise at low frequencies; and, perhaps most importantly, the complete decoupling of probe and sample temperatures. The first of these features will play an important role in studying the interplay between magnetic and electric domain structure. The last two are crucial for low frequency magnetic noise detection in, e.g., the cuprate pseudogap region and for precision measurements of transport in the high temperature, technologically relevant regime inaccessible to other techniques based on superconducting scanning probes. In periods 1--3 of this grant, which we now close at the University of Illinois at Urbana-Champaign and restart at Stanford University where our new lab is being built, we have demonstrated the ability to rapidly create Rb BECs and trap them within microns of a surface ina cryostat. Period 4 of this grant, to be performed at Stanford, will demonstrate the feasibility of using atom chips with a BEC to image transport features on a cryogenically cooled surface. Successful demonstration, in future funding cycles, will lead directly to the use of system for studies of transport in exotic and technologically relevant materials such as cuprate superconductors and topological insulators.

Lev, Benjamin L

2011-11-03T23:59:59.000Z

482

Kivalina wind generator  

SciTech Connect (OSTI)

The project reported was to construct a system to harness the winds of an Arctic site to generate electricity that would power a greenhouse where fruit and vegetables could be raised for local consumption. The installation of the tower and an Enertech 4K wind generator are described. (LEW)

Aldrich, D.

1984-02-18T23:59:59.000Z

483

Nanowires for energy generation  

Science Journals Connector (OSTI)

As a result of their morphology, nanowires bring new properties and the promise of performance for a range of electronic devices. This review looks into the properties of nanowires and the multiple ways in which they have been exploited for energy generation, from photovoltaics to piezoelectric generators.

Pritesh Hiralal; Husnu Emrah Unalan; Gehan A

2012-01-01T23:59:59.000Z

484

features Utility Generator  

E-Print Network [OSTI]

#12;#12;#12;#12;features function utility Training Pool Utility Generator Per-frame function content utility classes utility classes utility Tree Decision Generator Module Utility Clustering Adaptive Content Classification Loop features content VO selection & Utility Selector content features Real

Chang, Shih-Fu

485

Event generator overview  

SciTech Connect (OSTI)

Due to their ability to provide detailed and quantitative predictions, the event generators have become an important part of studying relativistic heavy ion physics and of designing future experiments. In this talk, the author will briefly summarize recent progress in developing event generators for the relativistic heavy ion collisions.

Pang, Y.

1997-12-01T23:59:59.000Z

486

Improved solid aerosol generator  

DOE Patents [OSTI]

An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

Prescott, D.S.; Schober, R.K.; Beller, J.

1988-07-19T23:59:59.000Z

487

Instead of splitting the atom --the  

E-Print Network [OSTI]

the atomic bomb and led to civilian nuclear plants - - ITER seeks to harness nuclear fusion: the power the atomic bomb and led to civilian nuclear plants -- ITER seeks to harness nuclear fusion: the power a few minutes and input/yield ratios remain low. That compares with ITER's goal of producing sustained

488

Chapter 7 - Nanofabrication via atom optics  

Science Journals Connector (OSTI)

Publisher Summary This chapter presents a review of the basic concepts that are used for atomoptical nanofabrication, as well as a discussion of the progress to date in realizations of the techniques. As a new approach to nanofabrication, atom optics offers the possibility of several advantages over existing techniques. For one thing, the fundamental diffraction limit imposed on resolution, present in any process where one attempts to focus particles (whether photons, charged particles, or neutral atoms), can be very small for atoms. Furthermore, atom optics can be used both in a direct deposition mode, where neutral atoms are focused by atom lenses into an extremely fine spot as they deposit onto a substrate, and also in a lithography mode, where focused atoms are used to expose a suitable resist material. In the direct deposition mode, nanostructures can be fabricated in a clean, resist-free environment, with little or no damage to the underlying substrate. Thus, the process can be very localized, with very little scattering and resist penetration. In either mode, parallelism, which is advantageous when issues of fabrication speed and/or long-range spatial coherence are important, can be achieved with very high dimensional accuracy over a large area of the substrate using laser focusing of atoms in a laser interference pattern.

Jabez J. McClelland

2000-01-01T23:59:59.000Z

489

Hartree-Fock theory for pseudorelativistic atoms  

E-Print Network [OSTI]

We study the Hartree-Fock model for pseudorelativistic atoms, that is, atoms where the kinetic energy of the electrons is given by the pseudorelativistic operator \\sqrt{(pc)^2+(mc^2)^2}-mc^2. We prove the existence of a Hartree-Fock minimizer, and prove regularity away from the nucleus and pointwise exponential decay of the corresponding orbitals.

Anna Dall'Acqua; Thomas Østergaard Sørensen; Edgardo Stockmeyer

2007-07-31T23:59:59.000Z

490

Formation of $??$ atoms in $K_{?4} decay  

E-Print Network [OSTI]

We derive the decay rate of $\\pi\\mu$ atom formation in $K_{\\mu 4}$ decay. Using the obtained expressions we calculate the decay rate of atom formation and point out that considered decay can give a noticeable contribution as a background to the fundamental decay $K^+\\to \\pi^+\

S. R. Gevorkyan; A. V. Tarasov; O. O. Voskresenskaya

2009-12-01T23:59:59.000Z

491

Hydrogen atom moving across a magnetic field  

Science Journals Connector (OSTI)

A hydrogen atom moving across a magnetic field is considered in a wide region of magnitudes of magnetic field and atom momentum. We solve the Schrödinger equation of the system numerically using an imaginary time method and find wave functions of the lowest states of atom. We calculate the energy and the mean electron-nucleus separation as a function of atom momentum and magnetic field. All the results obtained could be summarized as a phase diagram on the “atom-momentum – magnetic-field” plane. There are transformations of wave-function structure at critical values of atom momentum and magnetic field that result in a specific behavior of dependencies of energy and mean interparticle separation on the atom momentum P. We discuss a transition from the Zeeman regime to the high magnetic field regime. A qualitative analysis of the complicated behavior of wave functions vs P based on the effective potential examination is given. We analyze a sharp transition at the critical momentum from a Coulomb-type state polarized due to atom motion to a strongly decentered (Landau-type) state at low magnetic fields. A crossover occurring at intermediate magnetic fields is also studied.

Yu. E. Lozovik and S. Yu. Volkov

2004-08-23T23:59:59.000Z

492

Interaction of trapped ions with trapped atoms  

E-Print Network [OSTI]

In this thesis, I present results from two Paul-trap based ion traps carried out in the Vuleti? laboratory: the Atom-Ion trap for collision studies between cold atoms and cold ions, and the Cavity-Array trap for studying ...

Grier, Andrew T. (Andrew Todd)

2011-01-01T23:59:59.000Z

493

Relativistic atomic physics at the SSC  

SciTech Connect (OSTI)

This report discusses the following proposed work for relativistic atomic physics at the Superconducting Super Collider: Beam diagnostics; atomic physics research; staffing; education; budget information; statement concerning matching funds; description and justification of major items of equipment; statement of current and pending support; and assurance of compliance.

NONE

1990-12-31T23:59:59.000Z

494

New statistical atom: A numerical study  

Science Journals Connector (OSTI)

The new differential equation for the statistical atom is derived and discussed in detail. Numerical results are presented which provide evidence for the validity of all approximations that have entered the formalism. A comparison of experimental data for diamagnetic susceptibilities with theoretical predictions shows that the new statistical atom significantly surpasses its Hartree-Fock competitor.

Berthold-Georg Englert and Julian Schwinger

1984-05-01T23:59:59.000Z

495

Reactivity of Acid Generators  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity of Acid Generators for Chemically Amplified Resists with Reactivity of Acid Generators for Chemically Amplified Resists with Low-Energy Electrons Atsuro Nakano, Takahiro Kozawa, Seiichi Tagawa, Tomasz Szreder, James F. Wishart, Toshiyuki Kai and Tsutomu Shimokawa Jpn. J. Appl. Phys., 45, L197-L200 (2006). [Find paper at the Japanese Journal of Applied Physics] Abstract: In chemically amplified resists for ionizing radiations such as electron beams and extreme ultraviolet (EUV), low-energy electrons play an important role in the pattern formation processes. The reactivity of acid generators with low-energy electrons was evaluated using solvated electrons in tetrahydrofuran, which were generated by a pulsed electron beam. The rate constants of acid generators with the solvated electrons ranged from 0.6 to 1.9 x 1011 M-1s-1

496

Quantum-noise quenching in atomic tweezers  

SciTech Connect (OSTI)

The efficiency of extracting single atoms or molecules from an ultracold bosonic reservoir is theoretically investigated for a protocol based on lasers, coupling the hyperfine state in which the atoms form a condensate to another stable state, in which the atom experiences a tight potential in the regime of collisional blockade, the quantum tweezers. The transfer efficiency into the single-atom ground state of the tight trap is fundamentally limited by the collective modes of the condensate, which are thermally and dynamically excited. The noise due to these excitations can be quenched for sufficiently long laser pulses, thereby achieving high efficiencies. These results show that this protocol can be applied to initializing a quantum register based on tweezer traps for neutral atoms.

Zippilli, Stefano [Departament de Fisica, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain); Theoretische Physik, Universitaet des Saarlandes, D-66041 Saarbruecken (Germany); Fachbereich Physik and Research Center OPTIMAS, Technische Universitaet Kaiserslautern, D-67663 Kaiserslautern (Germany); Mohring, Bernd; Schleich, Wolfgang [Institut fuer Quantenphysik, Universitaet Ulm, D-89081 Ulm (Germany); Lutz, Eric [Department of Physics, University of Augsburg, D-86135 Augsburg (Germany); Morigi, Giovanna [Departament de Fisica, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain); Theoretische Physik, Universitaet des Saarlandes, D-66041 Saarbruecken (Germany)

2011-05-15T23:59:59.000Z

497

Quantum-noise quenching in atomic tweezers  

E-Print Network [OSTI]

The efficiency of extracting single atoms or molecules from an ultracold bosonic reservoir is theoretically investigated for a protocol based on lasers, coupling the hyperfine state in which the atoms form a condensate to another stable state, in which the atom experiences a tight potential in the regime of collisional blockade, the quantum tweezers. The transfer efficiency into the single-atom ground state of the tight trap is fundamentally limited by the collective modes of the condensate, which are thermally and dynamically excited. The noise due to these excitations can be quenched for sufficiently long laser pulses, thereby achieving high efficiencies. These results show that this protocol can be applied for initializing a quantum register based on tweezer traps for neutral atoms.

Stefano Zippilli; Bernd Mohring; Eric Lutz; Giovanna Morigi; Wolfgang Schleich

2011-04-15T23:59:59.000Z

498

Quantum computing with atomic Josephson junction arrays  

SciTech Connect (OSTI)

We present a quantum computing scheme with atomic Josephson junction arrays. The system consists of a small number of atoms with three internal states and trapped in a far-off-resonant optical lattice. Raman lasers provide the 'Josephson' tunneling, and the collision interaction between atoms represent the 'capacitive' couplings between the modes. The qubit states are collective states of the atoms with opposite persistent currents. This system is closely analogous to the superconducting flux qubit. Single-qubit quantum logic gates are performed by modulating the Raman couplings, while two-qubit gates result from a tunnel coupling between neighboring wells. Readout is achieved by tuning the Raman coupling adiabatically between the Josephson regime to the Rabi regime, followed by a detection of atoms in internal electronic states. Decoherence mechanisms are studied in detail promising a high ratio between the decoherence time and the gate operation time.

Tian Lin; Zoller, P. [Institute for Theoretical Physics, University of Innsbruck, A-6020 Innsbruck (Austria)

2003-10-01T23:59:59.000Z

499

Quantum Computing with Atomic Josephson Junction Arrays  

E-Print Network [OSTI]

We present a quantum computing scheme with atomic Josephson junction arrays. The system consists of a small number of atoms with three internal states and trapped in a far-off resonant optical lattice. Raman lasers provide the "Josephson" tunneling, and the collision interaction between atoms represent the "capacitive" couplings between the modes. The qubit states are collective states of the atoms with opposite persistent currents. This system is closely analogous to the superconducting flux qubit. Single qubit quantum logic gates are performed by modulating the Raman couplings, while two-qubit gates result from a tunnel coupling between neighboring wells. Readout is achieved by tuning the Raman coupling adiabatically between the Josephson regime to the Rabi regime, followed by a detection of atoms in internal electronic states. Decoherence mechanisms are studied in detail promising a high ratio between the decoherence time and the gate operation time.

Lin Tian; P. Zoller

2003-06-12T23:59:59.000Z

500

SunShot Initiative: Baseload Concentrating Solar Power Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Concentrating Solar Power Generation Concentrating Solar Power Generation In 2010, DOE issued the Baseload Concentrating Solar Power (CSP) Generation funding opportunity announcement (FOA). The following projects were selected under this competitive solicitation: Abengoa: Advanced Nitrate Salt Central Receiver Power Plant eSolar: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility General Atomics: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage HiTek: Low-Cost Heliostat Development Infinia: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power PPG: Next-Generation Low-Cost Reflector Rocketdyne: Solar Power Tower Improvements with the Potential to Reduce Costs SENER: High-Efficiency Thermal Storage System for Solar Plants