National Library of Energy BETA

Sample records for hydrate production technologies

  1. Methane Hydrate Production Technologies to be Tested on Alaska's North

    Energy Savers [EERE]

    Slope | Department of Energy Methane Hydrate Production Technologies to be Tested on Alaska's North Slope Methane Hydrate Production Technologies to be Tested on Alaska's North Slope October 24, 2011 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy, the Japan Oil, Gas and Metals National Corporation, and ConocoPhillips will work together to test innovative technologies for producing methane gas from hydrate deposits on the Alaska North Slope. The collaborative testing will

  2. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluationof Technology and Potential

    SciTech Connect (OSTI)

    Reagan, Matthew; Moridis, George J.; Collett, Timothy; Boswell, Ray; Kurihara, M.; Reagan, Matthew T.; Koh, Carolyn; Sloan, E. Dendy

    2008-02-12

    Gas hydrates are a vast energy resource with global distribution in the permafrost and in the oceans. Even if conservative estimates are considered and only a small fraction is recoverable, the sheer size of the resource is so large that it demands evaluation as a potential energy source. In this review paper, we discuss the distribution of natural gas hydrate accumulations, the status of the primary international R&D programs, and the remaining science and technological challenges facing commercialization of production. After a brief examination of gas hydrate accumulations that are well characterized and appear to be models for future development and gas production, we analyze the role of numerical simulation in the assessment of the hydrate production potential, identify the data needs for reliable predictions, evaluate the status of knowledge with regard to these needs, discuss knowledge gaps and their impact, and reach the conclusion that the numerical simulation capabilities are quite advanced and that the related gaps are either not significant or are being addressed. We review the current body of literature relevant to potential productivity from different types of gas hydrate deposits, and determine that there are consistent indications of a large production potential at high rates over long periods from a wide variety of hydrate deposits. Finally, we identify (a) features, conditions, geology and techniques that are desirable in potential production targets, (b) methods to maximize production, and (c) some of the conditions and characteristics that render certain gas hydrate deposits undesirable for production.

  3. Newly Installed Alaska North Slope Well Will Test Innovative Hydrate Production Technologies

    Broader source: Energy.gov [DOE]

    A fully instrumented well that will test innovative technologies for producing methane gas from hydrate deposits has been safely installed on the North Slope of Alaska. As a result, the "Iġnik Sikumi" (Iñupiaq for "fire in the ice") gas hydrate field trial well will be available for field experiments as early as winter 2011-12.

  4. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Thomas E. Williams; Keith Millheim; Bill Liddell

    2005-03-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports.

  5. Detection and Production of Methane Hydrate

    SciTech Connect (OSTI)

    George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

    2011-12-31

    This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

  6. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new Arctic Drilling Platform in search of gas hydrate and free gas accumulations at depths of approximately 1200 to 2500 ft MD. A secondary objective was the gas-charged sands of the uppermost Campanian interval at approximately 3000 ft. Summary results of geophysical analysis of the well are presented in this report.

  7. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and implemented for determining physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. Final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models and to research teams for developing future gas-hydrate projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and has been documented by the project team. This Topical Report documents drilling and coring operations and other daily activities.

  8. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists planning hydrate exploration and development projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this and other project reports. This Topical Report contains details describing logging operations.

  9. Comparative Assessment of Advanced Gay Hydrate Production Methods

    SciTech Connect (OSTI)

    M. D. White; B. P. McGrail; S. K. Wurstner

    2009-06-30

    Displacing natural gas and petroleum with carbon dioxide is a proven technology for producing conventional geologic hydrocarbon reservoirs, and producing additional yields from abandoned or partially produced petroleum reservoirs. Extending this concept to natural gas hydrate production offers the potential to enhance gas hydrate recovery with concomitant permanent geologic sequestration. Numerical simulation was used to assess a suite of carbon dioxide injection techniques for producing gas hydrates from a variety of geologic deposit types. Secondary hydrate formation was found to inhibit contact of the injected CO{sub 2} regardless of injectate phase state, thus diminishing the exchange rate due to pore clogging and hydrate zone bypass of the injected fluids. Additional work is needed to develop methods of artificially introducing high-permeability pathways in gas hydrate zones if injection of CO{sub 2} in either gas, liquid, or micro-emulsion form is to be more effective in enhancing gas hydrate production rates.

  10. Department of Energy Advance Methane Hydrates Science and Technology Projects

    Broader source: Energy.gov [DOE]

    Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

  11. ConocoPhillips Gas Hydrate Production Test

    SciTech Connect (OSTI)

    Schoderbek, David; Farrell, Helen; Howard, James; Raterman, Kevin; Silpngarmlert, Suntichai; Martin, Kenneth; Smith, Bruce; Klein, Perry

    2013-06-30

    Work began on the ConocoPhillips Gas Hydrates Production Test (DOE award number DE-NT0006553) on October 1, 2008. This final report summarizes the entire project from January 1, 2011 to June 30, 2013.

  12. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. The work scope drilled and cored a well The Hot Ice No. 1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report. The Hot Ice No. 1 well was drilled from the surface to a measured depth of 2300 ft. There was almost 100% core recovery from the bottom of surface casing at 107 ft to total depth. Based on the best estimate of the bottom of the methane hydrate stability zone (which used new data obtained from Hot Ice No. 1 and new analysis of data from adjacent wells), core was recovered over its complete range. Approximately 580 ft of porous, mostly frozen, sandstone and 155 of conglomerate were recovered in the Ugnu Formation and approximately 215 ft of porous sandstone were recovered in the West Sak Formation. There were gas shows in the bottom part of the Ugnu and throughout the West Sak. No hydrate-bearing zones were identified either in recovered core or on well logs. The base of the permafrost was found at about 1260 ft. With the exception of the deepest sands in the West Sak and some anomalous thin, tight zones, all sands recovered (after thawing) are unconsolidated with high porosity and high permeability. At 800 psi, Ugnu sands have an average porosity of 39.3% and geometrical mean permeability of 3.7 Darcys. Average grain density is 2.64 g/cc. West Sak sands have an average porosity of 35.5%, geometrical mean permeability of 0.3 Darcys, and average grain density of 2.70 g/cc. There were several 1-2 ft intervals of carbonate-cemented sandstone recovered from the West Sak. These intervals have porosities of only a few percent and very low permeability. On a well log they appear as resistive with a high sonic velocity. In shallow sections of other wells these usually are the only logs available. Given the presence of gas in Hot Ice No. 1, if only resistivity and sonic logs and a mud log had been available, tight sand zones may have been interpreted as containing hydrates. Although this finding does not imply that all previously mapped hydrate zones are merely tight sands, it does add a note of caution to the practice of interpreting the presence of hydrates from old well information. The methane hydrate stability zone below the Hot Ice No. 1 location includes thick sections of sandstone and conglomerate which would make excellent reservoir rocks for hydrates and below the permafrost zone shallow gas. The Ugnu formation comprises a more sand-rich section than does the West Sak formation, and the Ugnu sands when cleaned and dried are slightly more porous and significantly more permeable than the West Sak.

  13. Methane Hydrate Production Feasibility | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    forms hydrate in the presence of water, low temperatures and high pressures. Alternatively, when the temperature is increased or the pressure decreased so that hydrates are outside ...

  14. Method for production of hydrocarbons from hydrates

    DOE Patents [OSTI]

    McGuire, Patrick L.

    1984-01-01

    A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl.sub.2 or CaBr.sub.2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl.sub.2 /CaBr.sub.2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl.sub.2 /CaBr.sub.2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

  15. The effect of reservoir heterogeneity on gas production from hydrate accumulations in the permafrost

    SciTech Connect (OSTI)

    Reagan, M. T.; Kowalsky, M B.; Moridis, G. J.; Silpngarmlert, S.

    2010-05-01

    The quantity of hydrocarbon gases trapped in natural hydrate accumulations is enormous, leading to significant interest in the evaluation of their potential as an energy source. Large volumes of gas can be readily produced at high rates for long times from methane hydrate accumulations in the permafrost by means of depressurization-induced dissociation combined with conventional technologies and horizontal or vertical well configurations. Initial studies on the possibility of natural gas production from permafrost hydrates assumed homogeneity in intrinsic reservoir properties and in the initial condition of the hydrate-bearing layers (either due to the coarseness of the model or due to simplifications in the definition of the system). These results showed great promise for gas recovery from Class 1, 2, and 3 systems in the permafrost. This work examines the consequences of inevitable heterogeneity in intrinsic properties, such as in the porosity of the hydrate-bearing formation, or heterogeneity in the initial state of hydrate saturation. Heterogeneous configurations are generated through multiple methods: (1) through defining heterogeneous layers via existing well-log data, (2) through randomized initialization of reservoir properties and initial conditions, and (3) through the use of geostatistical methods to create heterogeneous fields that extrapolate from the limited data available from cores and well-log data. These extrapolations use available information and established geophysical methods to capture a range of deposit properties and hydrate configurations. The results show that some forms of heterogeneity, such as horizontal stratification, can assist in production of hydrate-derived gas. However, more heterogeneous structures can lead to complex physical behavior within the deposit and near the wellbore that may obstruct the flow of fluids to the well, necessitating revised production strategies. The need for fine discretization is crucial in all cases to capture dynamic behavior during production.

  16. Ground movements associated with gas hydrate production. Final report

    SciTech Connect (OSTI)

    Siriwardane, H.J.; Kutuk, B.

    1992-03-01

    This report deals with a study directed towards a modeling effort on production related ground movements and subsidence resulting from hydrate dissociation. The goal of this research study was to evaluate whether there could be subsidence related problems that could be an impediment to hydrate production. During the production of gas from a hydrate reservoir, it is expected that porous reservoir matrix becomes more compressible which may cause reservoir compression (compaction) under the influence of overburden weight. The overburden deformations can propagate its influence upwards causing subsidence near the surface where production equipment will be located. In the present study, the reservoir compaction is modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The present study is expected to provide a ``lower bound`` solution to the subsidence caused by hydrate reservoir depletion. The reservoir compaction anticipated during hydrate production was modeled by using the finite element method, which is a powerful computer modeling technique. The ground movements at the reservoir roof (i.e. reservoir compression) cause additional stresses and disturbance in the overburden strata. In this study, the reservoir compaction was modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The resulting stresses and ground movements were computed by using the finite element method. Based on the parameters used in this investigation, the maximum ground subsidence could vary anywhere from 0.50 to 6.50 inches depending on the overburden depth and the size of the depleted hydrate reservoir.

  17. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    SciTech Connect (OSTI)

    Moridis, G.J.; Collett, T.S.; Pooladi-Darvish, M.; Hancock, S.; Santamarina, C.; Boswell, R.; Kneafsey, T.; Rutqvist, J.; Kowalsky, M.; Reagan, M.T.; Sloan, E.D.; Sum, A.K.; Koh, C.

    2010-11-01

    The current paper complements the Moridis et al. (2009) review of the status of the effort toward commercial gas production from hydrates. We aim to describe the concept of the gas hydrate petroleum system, to discuss advances, requirement and suggested practices in gas hydrate (GH) prospecting and GH deposit characterization, and to review the associated technical, economic and environmental challenges and uncertainties, including: the accurate assessment of producible fractions of the GH resource, the development of methodologies for identifying suitable production targets, the sampling of hydrate-bearing sediments and sample analysis, the analysis and interpretation of geophysical surveys of GH reservoirs, well testing methods and interpretation of the results, geomechanical and reservoir/well stability concerns, well design, operation and installation, field operations and extending production beyond sand-dominated GH reservoirs, monitoring production and geomechanical stability, laboratory investigations, fundamental knowledge of hydrate behavior, the economics of commercial gas production from hydrates, and the associated environmental concerns.

  18. Ground movements associated with gas hydrate production. Progress report, October 1--December 31, 1992

    SciTech Connect (OSTI)

    Siriwardane, H.J.

    1992-12-31

    The grantee will evaluate the influence of hydrate production on ground subsidence near the wellbore and the surface. The objective of this research will be achieved by using computer simulations of what is expected in a hydrate reservoir during the production stage as reported by hydrate production models and available data. The model will be based on theories of continuum mechanics, thermomechanics of hydrate production, principles of rock mechanics and geomechanics, and special features of geomaterials under cold temperatures such as those found in permafrost regions. The research work involved in the proposed investigation will be divided into three major tasks; mechanics of subsidence in permafrost regions, modeling of subsidence, and parametric studies.

  19. Drilling and Production Testing the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields

    SciTech Connect (OSTI)

    Steve McRae; Thomas Walsh; Michael Dunn; Michael Cook

    2010-02-22

    In November of 2008, the Department of Energy (DOE) and the North Slope Borough (NSB) committed funding to develop a drilling plan to test the presence of hydrates in the producing formation of at least one of the Barrow Gas Fields, and to develop a production surveillance plan to monitor the behavior of hydrates as dissociation occurs. This drilling and surveillance plan was supported by earlier studies in Phase 1 of the project, including hydrate stability zone modeling, material balance modeling, and full-field history-matched reservoir simulation, all of which support the presence of methane hydrate in association with the Barrow Gas Fields. This Phase 2 of the project, conducted over the past twelve months focused on selecting an optimal location for a hydrate test well; design of a logistics, drilling, completion and testing plan; and estimating costs for the activities. As originally proposed, the project was anticipated to benefit from industry activity in northwest Alaska, with opportunities to share equipment, personnel, services and mobilization and demobilization costs with one of the then-active exploration operators. The activity level dropped off, and this benefit evaporated, although plans for drilling of development wells in the BGF's matured, offering significant synergies and cost savings over a remote stand-alone drilling project. An optimal well location was chosen at the East Barrow No.18 well pad, and a vertical pilot/monitoring well and horizontal production test/surveillance well were engineered for drilling from this location. Both wells were designed with Distributed Temperature Survey (DTS) apparatus for monitoring of the hydrate-free gas interface. Once project scope was developed, a procurement process was implemented to engage the necessary service and equipment providers, and finalize project cost estimates. Based on cost proposals from vendors, total project estimated cost is $17.88 million dollars, inclusive of design work, permitting, barging, ice road/pad construction, drilling, completion, tie-in, long-term production testing and surveillance, data analysis and technology transfer. The PRA project team and North Slope have recommended moving forward to the execution phase of this project.

  20. Forest products technologies

    SciTech Connect (OSTI)

    None, None

    2006-07-18

    Report highlights DOE Industrial Technology Program co-funded R&D resulting in commercial energy-efficient technologies and emerging technologies helping the forest products industry save energy.

  1. Estimating the upper limit of gas production from Class 2 hydrate accumulations in the permafrost: 2. Alternative well designs and sensitivity analysis

    SciTech Connect (OSTI)

    Moridis, G.; Reagan, M.T.

    2011-01-15

    In the second paper of this series, we evaluate two additional well designs for production from permafrost-associated (PA) hydrate deposits. Both designs are within the capabilities of conventional technology. We determine that large volumes of gas can be produced at high rates (several MMSCFD) for long times using either well design. The production approach involves initial fluid withdrawal from the water zone underneath the hydrate-bearing layer (HBL). The production process follows a cyclical pattern, with each cycle composed of two stages: a long stage (months to years) of increasing gas production and decreasing water production, and a short stage (days to weeks) that involves destruction of the secondary hydrate (mainly through warm water injection) that evolves during the first stage, and is followed by a reduction in the fluid withdrawal rate. A well configuration with completion throughout the HBL leads to high production rates, but also the creation of a secondary hydrate barrier around the well that needs to be destroyed regularly by water injection. However, a configuration that initially involves heating of the outer surface of the wellbore and later continuous injection of warm water at low rates (Case C) appears to deliver optimum performance over the period it takes for the exhaustion of the hydrate deposit. Using Case C as the standard, we determine that gas production from PA hydrate deposits increases with the fluid withdrawal rate, the initial hydrate saturation and temperature, and with the formation permeability.

  2. Ice method for production of hydrogen clathrate hydrates

    DOE Patents [OSTI]

    Lokshin, Konstantin; Zhao, Yusheng

    2008-05-13

    The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

  3. Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?

    SciTech Connect (OSTI)

    Paull, C.K.; Ussler, W. III; Borowski, W.S.

    1993-09-01

    Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

  4. Ground movements associated with gas hydrate production. Progress report, July 1--September 30, 1992

    SciTech Connect (OSTI)

    Siriwardane, H.J.

    1992-12-31

    The grantee will evaluate the influence of hydrate production on ground subsidence near the wellbore and the surface. The objective of this research will be achieved by using computer simulations of what is expected in a hydrate reservoir during the production stage as reported by hydrate production models and available data. The model will be based on theories of continuum mechanics, thermomechanics of hydrate production, principles of rock mechanics and geomechanics, and special features of geomaterials under cold temperatures such as those found in permafrost regions. The research work involved in the proposed investigation will be divided into three major tasks: (1) Mechanics of subsidence in permafrost regions; (2) modeling of subsidence; and (3) parametric studies. Progress reports are presented for tasks 1 and 2.

  5. Production of hydrocarbons from hydrates. [DOE patent application

    DOE Patents [OSTI]

    McGuire, P.L.

    1981-09-08

    An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

  6. Technology's Impact on Production

    SciTech Connect (OSTI)

    Rachel Amann; Ellis Deweese; Deborah Shipman

    2009-06-30

    As part of a cooperative agreement with the United States Department of Energy (DOE) - entitled Technology's Impact on Production: Developing Environmental Solutions at the State and National Level - the Interstate Oil and Gas Compact Commission (IOGCC) has been tasked with assisting state governments in the effective, efficient, and environmentally sound regulation of the exploration and production of natural gas and crude oil, specifically in relation to orphaned and abandoned wells and wells nearing the end of productive life. Project goals include: (1) Developing (a) a model framework for prioritization and ranking of orphaned or abandoned well sites; (b) a model framework for disbursement of Energy Policy Act of 2005 funding; and (c) a research study regarding the current status of orphaned wells in the nation. (2) Researching the impact of new technologies on environmental protection from a regulatory perspective. Research will identify and document (a) state reactions to changing technology and knowledge; (b) how those reactions support state environmental conservation and public health; and (c) the impact of those reactions on oil and natural gas production. (3) Assessing emergent technology issues associated with wells nearing the end of productive life. Including: (a) location of orphaned and abandoned well sites; (b) well site remediation; (c) plugging materials; (d) plug placement; (e) the current regulatory environment; and (f) the identification of emergent technologies affecting end of life wells. New Energy Technologies - Regulating Change, is the result of research performed for Tasks 2 and 3.

  7. Methane Hydrate Field Studies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Field Studies Methane Hydrate Field Studies Arctic/Alaska North Slope Field Studies Since 2001, DOE has conducted field trials of exploration and production technology in the Alaska North Slope. Although Alaska methane hydrate resources are smaller than marine deposits and currently lack outlets to commercial markets, Alaska provides an excellent laboratory to study E&P technology. The research also has implications for various Alaska resources, including potential gas hydrate resources for

  8. Ground movements associated with gas hydrate production. Progress report, April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Siriwardane, H.J.

    1992-12-31

    An obvious consequence of hydrate dissociation is the compression of reservoir matrix causing displacements in the surrounding area. The reservoir compression is a time-dependent process which depends on the production rate. The ground movements cause additional stresses in the overburden which may result in rock mass fracture and failure. Rock failure may cause rubble formation or bulking in the fracture zone. This in turn can cause an increase in permeability for gas flow which may offset the reduction in permeability caused by closure of existing fractures during reservoir compression. The mechanics of ground movements during hydrate production can be more closely simulated by considering similarities with ground movements associated with subsidence in permafrost regions. The purpose of this research work is to investigate the potential strata movements associated with hydrate production by considering similarities with ground movements in permafrost regions. The work primarily involves numerical modeling of subsidence caused by hydrate dissociation. The investigation is based on the theories of continuum mechanics, thermomechanical behavior of frozen geo-materials, principles of rock mechanics and geomechanics. It is expected that some phases of the investigation will involve the use of finite element method, which is a powerful computer-based method which has been widely used in many areas of science and engineering. Parametric studies will be performed to predict expected strata movements and surface subsidence for different reservoir conditions and properties of geological materials. The results from this investigation will be useful in predicting the magnitude of the subsidence problem associated with gas hydrate production. The analogy of subsidence in permafrost regions may provide lower bounds for subsidence expected in hydrate reservoirs. Furthermore, it is anticipated that the results will provide insight into planning of hydrate recovery operations.

  9. Four Critical Needs to Change the Hydrate Energy Paradigm from Assessment to Production: The 2007 Report to Congress by the U.S. Federal methane Hydrate Advisory Committee

    SciTech Connect (OSTI)

    Mahajan,D.; Sloan, D.; Brewer, P.; Dutta, N.; Johnson, A.; Jones, E.; Juenger, K.; Kastner, M.; Masutani, S.; Swenson, R.; Whelan, J.; Wilson, s.; Woolsey, R.

    2009-03-11

    This work summarizes a two-year study by the U.S. Federal Methane Hydrate Advisory Committee recommending the future needs for federally-supported hydrate research. The Report was submitted to the US Congress on August 14, 2007 and includes four recommendations regarding (a) permafrost hydrate production testing, (b) marine hydrate viability assessment (c) climate effect of hydrates, and (d) international cooperation. A secure supply of natural gas is a vital goal of the U.S. national energy policy because natural gas is the cleanest and most widely used of all fossil fuels. The inherent cleanliness of natural gas, with the lowest CO2 emission per unit of heat energy of any fossil fuel, means substituting gas for coal and fuel oil will reduce emissions that can exacerbate the greenhouse effect. Both a fuel and a feedstock, a secure and reasonably priced supply of natural gas is important to industry, electric power generators, large and small commercial enterprises, and homeowners. Because each volume of solid gas hydrate contains as much as 164 standard volumes of methane, hydrates can be viewed as a concentrated form of natural gas equivalent to compressed gas but less concentrated than liquefied natural gas (LNG). Natural hydrate accumulations worldwide are estimated to contain 700,000 TCF of natural gas, of which 200,000 TCF are located within the United States. Compared with the current national annual consumption of 22 TCF, this estimate of in-place gas in enormous. Clearly, if only a fraction of the hydrated methane is recoverable, hydrates could constitute a substantial component of the future energy portfolio of the Nation (Figure 1). However, recovery poses a major technical and commercial challenge. Such numbers have sparked interest in natural gas hydrates as a potential, long-term source of energy, as well as concerns about any potential impact the release of methane from hydrates might have on the environment. Energy-hungry countries such as India and Japan are outspending the United States on hydrate science and engineering R&D by a factor of 10, and may bring this resource to market as much as a decade before the United States.

  10. Oil & Natural Gas Technology Temporal Characterization of Hydrates System Dynamics beneath Seafloor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil & Natural Gas Technology Temporal Characterization of Hydrates System Dynamics beneath Seafloor Mounds: Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters Final Technical Report Project Period: October 1, 2012 - January 31, 2015 Submitted by: Carol Blanton Lutken, Leonardo Macelloni, Marco D'Emidio, John Dunbar, Paul Higley August, 2015 DOE Award No.: DE- FE0010141 The University of Mississippi Mississippi Mineral Resources

  11. Geomechanical response of permafrost-associated hydrate deposits to depressurization-induced gas production

    SciTech Connect (OSTI)

    Rutqvist, J.; Moridis, G.J.; Grover, T.; Collett, T.

    2009-02-01

    In this simulation study, we analyzed the geomechanical response during depressurization production from two known hydrate-bearing permafrost deposits: the Mallik (Northwest Territories, Canada) deposit and Mount Elbert (Alaska, USA) deposit. Gas was produced from these deposits at constant pressure using horizontal wells placed at the top of a hydrate layer (HL), located at a depth of about 900 m at the Mallik and 600 m at the Mount Elbert. The simulation results show that general thermodynamic and geomechanical responses are similar for the two sites, but with substantially higher production and more intensive geomechanical responses at the deeper Mallik deposit. The depressurization-induced dissociation begins at the well bore and then spreads laterally, mainly along the top of the HL. The depressurization results in an increased shear stress within the body of the receding hydrate and causes a vertical compaction of the reservoir. However, its effects are partially mitigated by the relatively stiff permafrost overburden, and compaction of the HL is limited to less than 0.4%. The increased shear stress may lead to shear failure in the hydrate-free zone bounded by the HL overburden and the downward-receding upper dissociation interface. This zone undergoes complete hydrate dissociation, and the cohesive strength of the sediment is low. We determined that the likelihood of shear failure depends on the initial stress state as well as on the geomechanical properties of the reservoir. The Poisson's ratio of the hydrate-bearing formation is a particularly important parameter that determines whether the evolution of the reservoir stresses will increase or decrease the likelihood of shear failure.

  12. U.S. and Japan Complete Successful Field Trial of Methane Hydrate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Technologies | Department of Energy Japan Complete Successful Field Trial of Methane Hydrate Production Technologies U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies May 2, 2012 - 10:40am Addthis WASHINGTON, DC - U.S. Energy Secretary Steven Chu announced today the completion of a successful, unprecedented test of technology in the North Slope of Alaska that was able to safely extract a steady flow of natural gas from methane hydrates - a

  13. U.S. and Japan Complete Successful Field Trial of Methane Hydrate

    Energy Savers [EERE]

    Production Technologies | Department of Energy and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies May 2, 2012 - 1:00pm Addthis Washington, DC - U.S. Energy Secretary Steven Chu announced today the completion of a successful, unprecedented test of technology in the North Slope of Alaska that was able to safely extract a steady flow of natural gas from methane hydrates -

  14. Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico: Applications for Safe Exploration and Production Activities

    SciTech Connect (OSTI)

    Bent, Jimmy

    2014-05-31

    In 2000 Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deep water portion of the Gulf of Mexico (GOM). Chevron is an active explorer and operator in the Gulf of Mexico and is aware that natural gas hydrates need to be understood to operate safely in deep water. In August 2000 Chevron worked closely with the National Energy Technology Laboratory (NETL) of the United States Department of Energy (DOE) and held a workshop in Houston, Texas to define issues concerning the characterization of natural gas hydrate deposits. Specifically, the workshop was meant to clearly show where research, the development of new technologies, and new information sources would be of benefit to the DOE and to the oil and gas industry in defining issues and solving gas hydrate problems in deep water.

  15. Forest Products Industry Technology Roadmap

    SciTech Connect (OSTI)

    none,

    2010-04-01

    This document describes the forest products industry's research and development priorities. The original technology roadmap published by the industry in 1999 and was most recently updated in April 2010.

  16. Hydrogen production: Overview of technology options

    SciTech Connect (OSTI)

    None, None

    2009-01-15

    Overview of technology options for hydrogen production, its challenges and research needs and next steps

  17. Hydrate detection

    SciTech Connect (OSTI)

    Dillon, W.P.; Ahlbrandt, T.S.

    1992-06-01

    Project objectives were: (1) to create methods of analyzing gas hydrates in natural sea-floor sediments, using available data, (2) to make estimates of the amount of gas hydrates in marine sediments, (3) to map the distribution of hydrates, (4) to relate concentrations of gas hydrates to natural processes and infer the factors that control hydrate concentration or that result in loss of hydrate from the sea floor. (VC)

  18. Hydrate detection

    SciTech Connect (OSTI)

    Dillon, W.P.; Ahlbrandt, T.S.

    1992-01-01

    Project objectives were: (1) to create methods of analyzing gas hydrates in natural sea-floor sediments, using available data, (2) to make estimates of the amount of gas hydrates in marine sediments, (3) to map the distribution of hydrates, (4) to relate concentrations of gas hydrates to natural processes and infer the factors that control hydrate concentration or that result in loss of hydrate from the sea floor. (VC)

  19. Gas Production From a Cold, Stratigraphically Bounded Hydrate Deposit at the Mount Elbert Site, North Slope, Alaska

    SciTech Connect (OSTI)

    Moridis, G.J.; Silpngarmlert, S.; Reagan, M. T.; Collett, T.S.; Zhang, K.

    2009-09-01

    As part of an effort to identify suitable targets for a planned long-term field test, we investigate by means of numerical simulation the gas production potential from unit D, a stratigraphically bounded (Class 3) permafrost-associated hydrate occurrence penetrated in the ount Elbert well on North Slope, Alaska. This shallow, low-pressure deposit has high porosities, high intrinsic permeabilities and high hydrate saturations. It has a low temperature because of its proximity to the overlying permafrost. The simulation results indicate that vertical ells operating at a constant bottomhole pressure would produce at very low rates for a very long period. Horizontal wells increase gas production by almost two orders of magnitude, but production remains low. Sensitivity analysis indicates that the initial deposit temperature is y the far the most important factor determining production performance (and the most effective criterion for target selection) because it controls the sensible heat available to fuel dissociation.

  20. Conversion Technologies for Advanced Biofuels - Carbohydrates Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Production Conversion Technologies for Advanced Biofuels - Carbohydrates Production Purdue University report-out presentation at the CTAB webinar on Carbohydrates Production. PDF icon ctab_webinar_carbohydrates_production.pdf More Documents & Publications Advanced Conversion Roadmap Workshop Workshop on Conversion Technologies for Advanced Biofuels - Carbohydrates Conversion Technologies for Advanced Biofuels - Carbohydrates Upgrading

  1. The use of electrical impedance spectroscopy for monitoring the hydration products of Portland cement mortars with high percentage of pozzolans

    SciTech Connect (OSTI)

    Cruz, J.M.; Fita, I.C.; Soriano, L.; Pay, J.; Borrachero, M.V.

    2013-08-15

    In this paper, mortars and pastes containing large replacement of pozzolan were studied by mechanical strength, thermogravimetric analysis (TGA), scanning electronic microscopy (SEM), mercury intrusion porosimetry (MIP) and electrical impedance spectroscopy (EIS). The effect of metakaolin (35%) and fly ash (60%) was evaluated and compared with an inert mineral addition (andalusite). The portlandite content was measured, finding that the pozzolanic reaction produced cementing systems with all portlandite fixed. The EIS measurements were analyzed by the equivalent electrical circuit (EEC) method. An EEC with three branches in parallel was applied. The dc resistance was related to the degree of hydration and allowed us to characterize plain and blended mortars. A constant phase element (CPE) quantified the electrical properties of the hydration products located in the solidsolution interface and was useful to distinguish the role of inert and pozzolanic admixtures present in the cement matrix.

  2. New Oxygen-Production Technology Proving Successful

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

  3. TOUGH-Fx/Hydrate

    Energy Science and Technology Software Center (OSTI)

    2005-02-01

    TOUGH-Fx/HYORATL can model the non-isothermal gas release. phase behavior and flow of fluids and heat in complex geologic media. The code can simulate production from natural gas hydrate deposits in the subsurtace (i.e., in the permafrost and in deep ocean sediments), as well as laboratory experiments of hydrate dissociation/formation in porous/fractured media. T006H-Fx/HYDRATE vi .0 includes both an equilibrium and a kinetic model of hydrate Ibmiation and dissociation. The model accounts for heat and upmore » to four mass components-- i.e., water, CH4, hydrate, and water-soluble inhibitors such as salts or alcohols. These are partitioned among four possible phases (gas phase, liquid phase, ice phase and hydrate phase). Hydrate dIssociation or formation, phase changes, and the corresponding thermal effects are fully described, as are the effects of inhibitors. The model can describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects, and inhibItor-Induced effects.« less

  4. Biogas Production Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Technologies Biogas Production Technologies Presentation about UC Davis's biogas technologies and integration with fuel cells. Presented by Ruihong Zhang, UC Davis, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado. PDF icon june2012_biogas_workshop_zhang.pdf More Documents & Publications Biogas Markets and Federal Policy Biomass Program Perspectives on Anaerobic Digestion and Fuel Cell Integration at Biorefineries Project Reports for

  5. 2012 Pathways to Commercial Success: Technologies and Products...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2012 Pathways to Commercial Success: Technologies and Products Supported ...

  6. Buildings R&D Breakthroughs: Technologies and Products Supported...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R&D Breakthroughs: Technologies and Products Supported by the Building Technologies Program Buildings R&D Breakthroughs: Technologies and Products Supported by the Building ...

  7. 2013 Pathways to Commercial Success: Technologies and Products...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office 2013 Pathways to Commercial Success: Technologies and Products Supported by ...

  8. 2015 Pathways to Commercial Success: Technologies and Products...

    Energy Savers [EERE]

    5 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office 2015 Pathways to Commercial Success: Technologies and Products Supported ...

  9. 2014 Pathways to Commercial Success: Technologies and Products...

    Office of Environmental Management (EM)

    4 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office 2014 Pathways to Commercial Success: Technologies and Products Supported ...

  10. 2010 Pathways to Commercial Success: Technologies and Products...

    Office of Environmental Management (EM)

    0 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2010 Pathways to Commercial Success: Technologies and Products Supported ...

  11. 2011 Pathways to Commercial Success: Technologies and Products...

    Energy Savers [EERE]

    1 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2011 Pathways to Commercial Success: Technologies and Products Supported ...

  12. Evaluation of a deposit in the vicinity of the PBU L-106 Site, North Slope, Alaska, for a potential long-term test of gas production from hydrates

    SciTech Connect (OSTI)

    Moridis, G.J.; Reagan, M.T.; Boyle, K.L.; Zhang, K.

    2010-05-01

    As part of the effort to investigate the technical feasibility of gas production from hydrate deposits, a long-term field test (lasting 18-24 months) is under consideration in a project led by the U.S. Department of Energy. We evaluate a candidate deposit involving the C-Unit in the vicinity of the PBU-L106 site in North Slope, Alaska. This deposit is stratigraphically bounded by impermeable shale top and bottom boundaries (Class 3), and is characterized by high intrinsic permeabilities, high porosity, high hydrate saturation, and a hydrostatic pressure distribution. The C-unit deposit is composed of two hydrate-bearing strata separated by a 30-ft-thick shale interlayer, and its temperatrure across its boundaries ranges between 5 and 6.5 C. We investigate by means of numerical simulation involving very fine grids the production potential of these two deposits using both vertical and horizontal wells. We also explore the sensitivity of production to key parameters such as the hydrate saturation, the formation permeability, and the permeability of the bounding shale layers. Finally, we compare the production performance of the C-Unit at the PBU-L106 site to that of the D-Unit accumulation at the Mount Elbert site, a thinner, single-layer Class 3 deposit on the North Slope of Alaska that is shallower, less-pressurized and colder (2.3-2.6 C). The results indicate that production from horizontal wells may be orders of magnitude larger than that from vertical ones. Additionally, production increases with the formation permeability, and with a decreasing permeability of the boundaries. The effect of the hydrate saturation on production is complex and depends on the time frame of production. Because of higher production, the PBU-L106 deposit appears to have an advantage as a candidate for the long-term test.

  13. Efficient Technologies and Products for Federal Facilities

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides a one-stop shop for finding energy- and water-efficient technologies and products that can help agenices meet federal facility goals and requirements.

  14. Search for Efficient Technologies and Products for Federal Facilities |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Products & Technologies » Technology Deployment » Efficient Technologies & Products » Search for Efficient Technologies and Products for Federal Facilities Search for Efficient Technologies and Products for Federal Facilities The Federal Energy Management Program provides information and resources about energy- and water-efficient technologies and products that can help agencies meet federal facility goals and requirements. Search for technologies and products

  15. Production Technology | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Production Technology NNSA continues to assure the safety, security, and reliability of the existing stockpile as it progresses towards a newly responsive nuclear weapons infrastructure as called for in the 2001 Nuclear Posture Review and described in the vision for Complex Transformation. The work is one of the key providers of design-to-manufacturing and technological readiness capabilities for this transformation effort. NNSA closely integrates planning and project selection prioritization

  16. Fuel Cell Technologies Office Publication and Product Library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cell Technologies Office Publication & Product Library Fuel Cell Technologies Office Home Publication and Product Library Share this resource Publications Advanced Search ...

  17. Kinetic inhibition of natural gas hydrates in offshore drilling, production, and processing. Annual report, January 1--December 31, 1994

    SciTech Connect (OSTI)

    1994-12-31

    Natural gas hydrates are crystalline materials formed of natural gas and water at elevated pressures and reduced temperatures. Because natural gas hydrates can plug drill strings, pipelines, and process equipment, there is much effort expended to prevent their formation. The goal of this project was to provide industry with more economical hydrate inhibitors. The specific goals for the past year were to: define a rational approach for inhibitor design, using the most probable molecular mechanism; improve the performance of inhibitors; test inhibitors on Colorado School of Mines apparatuses and the Exxon flow loop; and promote sharing field and flow loop results. This report presents the results of the progress on these four goals.

  18. Kinetic inhibition of natural gas hydrates in offshore drilling, production, and processing. Annual report, January 1--December 31, 1993

    SciTech Connect (OSTI)

    1993-12-31

    Natural gas hydrates are crystalline materials formed of natural gas and water at elevated pressures and reduced temperatures. Because natural gas hydrates can plug drill strings, pipelines, and process equipment, there is much effort expended to prevent their formation. The goal of this project was to provide industry with more economical hydrate inhibitors. The specific goals for the past year were to: continue both screening and high pressure experiments to determine optimum inhibitors; investigate molecular mechanisms of hydrate formation/inhibition, through microscopic and macroscopic experiments; begin controlled tests on the Exxon pilot plant loop at their Houston facility; and continue to act as a forum for the sharing of field test results. Progress on these objectives are described in this report.

  19. Systematic Discrimination of Advanced Hydrogen Production Technologies

    SciTech Connect (OSTI)

    Charles V. Park; Michael W. Patterson

    2010-07-01

    The U.S. Department of Energy, in concert with industry, is developing a high-temperature gas-cooled reactor at the Idaho National Laboratory (INL) to demonstrate high temperature heat applications to produce hydrogen and electricity or to support other industrial applications. A key part of this program is the production of hydrogen from water that would significantly reduce carbon emissions compared to current production using natural gas. In 2009 the INL led the methodical evaluation of promising advanced hydrogen production technologies in order to focus future resources on the most viable processes. This paper describes how the evaluation process was systematically planned and executed. As a result, High-Temperature Steam Electrolysis was selected as the most viable near-term technology to deploy as a part of the Next Generation Nuclear Plant Project.

  20. Kinetic inhibition of natural gas hydrates in offshore drilling, production, and processing operations. Annual report, January 1--December 31, 1992

    SciTech Connect (OSTI)

    1992-12-31

    Natural gas hydrates are solid crystalline compounds which form when molecules smaller than n-butane contact molecules of water at elevated pressures and reduced temperatures, both above and below the ice point. Because these crystalline compounds plug flow channels, they are undesirable. In this project the authors proposed an alternate approach of controlling hydrate formation by preventing hydrate growth into a sizeable mass which could block a flow channel. The authors call this new technique kinetic inhibition, because while it allows the system to exist in the hydrate domain, it prevents the kinetic agglomeration of small hydrate crystals to the point of pluggage of a flow channel. In order to investigate the kinetic means of inhibiting hydrate formation, they held two consortium meetings, on June 1, 1990 and on August 31, 1990. At subsequent meetings, the authors determined the following four stages of the project, necessary to reach the goal of determining a new hydrate field inhibitor: (1) a rapid screening method was to be determined for testing the hydrate kinetic formation period of many surfactants and polymer candidates (both individually and combined), the present report presents the success of two screening apparatuses: a multi-reactor apparatus which is capable of rapid, high volume screening, and the backup screening method--a viscometer for testing with gas at high pressure; (2) the construction of two high, constant pressure cells were to experimentally confirm the success of the chemicals in the rapid screening apparatus; (3) in the third phase of the work, Exxon volunteered to evaluate the performance of the best chemicals from the previous two stages in their 4 inch I.D. Multiphase flow loop in Houston; (4) in the final phase of the work, the intention was to take the successful kinetic inhibition chemicals from the previous three stages and then test them in the field in gathering lines and wells from member companies.

  1. Hydrogen Production: Overview of Technology Options, January 2009

    Fuel Cell Technologies Publication and Product Library (EERE)

    Overview of technology options for hydrogen production, its challenges and research needs and next steps

  2. 2010 Pathways to Commercial Success: Technologies and Products Supported by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Fuel Cell Technologies Program | Department of Energy 0 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2010 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program This FY 2010 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office

  3. 2011 Pathways to Commercial Success: Technologies and Products Supported by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Fuel Cell Technologies Program | Department of Energy 1 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2011 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program This FY 2011 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office

  4. 2012 Pathways to Commercial Success: Technologies and Products Supported by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Fuel Cell Technologies Program | Department of Energy Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2012 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program This FY 2012 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office

  5. 2013 Pathways to Commercial Success: Technologies and Products Supported by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Fuel Cell Technologies Office | Department of Energy Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office 2013 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office This FY 2013 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office and

  6. 2014 Pathways to Commercial Success: Technologies and Products Supported by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Fuel Cell Technologies Office | Department of Energy Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office 2014 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office This FY 2014 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office and

  7. 2015 Pathways to Commercial Success: Technologies and Products Supported by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Fuel Cell Technologies Office | Department of Energy 5 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office 2015 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office This 2015 report updates the results of an effort to identify and document the commercial and emerging (projected to be commercialized within the next 3 to 5 years) hydrogen and fuel cell technologies and products that

  8. 2009 Pathways to Commercial Success: Technologies and Products...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathways to Commercial Success: Technologies and Products Supported by the Hydrogen, Fuel Cells and Infrastructure Technologies Program 2009 Pathways to Commercial Success: ...

  9. Conversion Technologies for Advanced Biofuels - Bio-Oil Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion Technologies for Advanced Biofuels - Bio-Oil Production RTI International report-out at the CTAB webinar on Conversion Technologies for Advanced Biofuels - Bio-Oil ...

  10. Technologies for Production of Heat and Electricity

    SciTech Connect (OSTI)

    Jacob J. Jacobson; Kara G. Cafferty

    2014-04-01

    Biomass is a desirable source of energy because it is renewable, sustainable, widely available throughout the world, and amenable to conversion. Biomass is composed of cellulose, hemicellulose, and lignin components. Cellulose is generally the dominant fraction, representing about 40 to 50% of the material by weight, with hemicellulose representing 20 to 50% of the material, and lignin making up the remaining portion [4,5,6]. Although the outward appearance of the various forms of cellulosic biomass, such as wood, grass, municipal solid waste (MSW), or agricultural residues, is different, all of these materials have a similar cellulosic composition. Elementally, however, biomass varies considerably, thereby presenting technical challenges at virtually every phase of its conversion to useful energy forms and products. Despite the variances among cellulosic sources, there are a variety of technologies for converting biomass into energy. These technologies are generally divided into two groups: biochemical (biological-based) and thermochemical (heat-based) conversion processes. This chapter reviews the specific technologies that can be used to convert biomass to energy. Each technology review includes the description of the process, and the positive and negative aspects.

  11. Rapid Gas Hydrate Formation Process - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Find More Like This Return to Search Rapid Gas Hydrate Formation Process National Energy Technology Laboratory Contact NETL About This Technology...

  12. EA-2012: Strategic Test Well (s) Planning and Drilling for Long-Term Methane Hydrate Production Testing in Alaska

    Broader source: Energy.gov [DOE]

    DOE is preparing an EA that evaluates the potential environmental impacts of providing financial support for planning, analysis, and engineering services to support a proposed project of Petrotechnical Resources of Alaska with Japan Oil, Gas and Metals National Corporation to perform gas hydrate drilling and testing on the North Slope of Alaska.

  13. Handbook of gas hydrate properties and occurrence

    SciTech Connect (OSTI)

    Kuustraa, V.A.; Hammershaimb, E.C.

    1983-12-01

    This handbook provides data on the resource potential of naturally occurring hydrates, the properties that are needed to evaluate their recovery, and their production potential. The first two chapters give data on the naturally occurring hydrate potential by reviewing published resource estimates and the known and inferred occurrences. The third and fourth chapters review the physical and thermodynamic properties of hydrates, respectively. The thermodynamic properties of hydrates that are discussed include dissociation energies and a simplified method to calculate them; phase diagrams for simple and multi-component gases; the thermal conductivity; and the kinetics of hydrate dissociation. The final chapter evaluates the net energy balance of recovering hydrates and shows that a substantial positive energy balance can theoretically be achieved. The Appendices of the Handbook summarize physical and thermodynamic properties of gases, liquids and solids that can be used in designing and evaluating recovery processes of hydrates. 158 references, 67 figures, 47 tables.

  14. Clean Energy Manufacturing Resources - Technology Full-Scale Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Full-Scale Production Clean Energy Manufacturing Resources - Technology Full-Scale Production Clean Energy Manufacturing Resources - Technology Full-Scale Production Find resources to help you design a production and manufacturing process for a new clean energy technology or product. For full-scale production, other areas to consider include workforce development; R&D funding; and regional, state, and local resources. For more resources, see the Clean Energy

  15. Solar and Wind Technologies for Hydrogen Production Report to Congress

    Fuel Cell Technologies Publication and Product Library (EERE)

    DOE's Solar and Wind Technologies for Hydrogen Production Report to Congress summarizes the technology roadmaps for solar- and wind-based hydrogen production. Published in December 2005, it fulfills t

  16. Conversion Technologies for Advanced Biofuels - Bio-Oil Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Oil Production Conversion Technologies for Advanced Biofuels - Bio-Oil Production RTI International report-out at the CTAB webinar on Conversion Technologies for Advanced Biofuels - Bio-Oil Production. PDF icon ctab_webinar_bio_oils_production.pdf More Documents & Publications Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading 2013 Peer Review Presentations-Bio-oil Workshop on Conversion Technologies for Advanced Biofuels - Bio-Oils

  17. Hydrogen Production Roadmap: Technology Pathways to the Future, January 2009

    Fuel Cell Technologies Publication and Product Library (EERE)

    Roadmap to identify key challenges and priority R&D needs associated with various hydrogen fuel production technologies.

  18. Hydrogen Production Roadmap. Technology Pathways to the Future, January 2009

    SciTech Connect (OSTI)

    Curry-Nkansah, Maria; Driscoll, Daniel; Farmer, Richard; Garland, Roxanne; Gruber, Jill; Gupta, Nikunj; Hershkowitz, Frank; Holladay, Jamelyn; Nguyen, Kevin; Schlasner, Steven; Steward, Darlene; Penev, Michael

    2009-01-01

    Roadmap to identify key challenges and priority R&D needs associated with various hydrogen fuel production technologies.

  19. 2009 Pathways to Commercial Success: Technologies and Products Supported by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Hydrogen, Fuel Cells and Infrastructure Technologies Program | Department of Energy Pathways to Commercial Success: Technologies and Products Supported by the Hydrogen, Fuel Cells and Infrastructure Technologies Program 2009 Pathways to Commercial Success: Technologies and Products Supported by the Hydrogen, Fuel Cells and Infrastructure Technologies Program This report documents the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies

  20. Novel membrane technology for green ethylene production.

    SciTech Connect (OSTI)

    Balachandran, U.; Lee, T. H.; Dorris, S. E.; Udovich, C. A.; Scouten, C. G.; Marshall, C. L.

    2008-01-01

    Ethylene is currently produced by pyrolysis of ethane in the presence of steam. This reaction requires substantial energy input, and the equilibrium conversion is thermodynamically limited. The reaction also produces significant amounts of greenhouse gases (CO and CO{sub 2}) because of the direct contact between carbon and steam. Argonne has demonstrated a new way to make ethylene via ethane dehydrogenation using a dense hydrogen transport membrane (HTM) to drive the unfavorable equilibrium conversion. Preliminary experiments show that the new approach can produce ethylene yields well above existing pyrolysis technology and also significantly above the thermodynamic equilibrium limit, while completely eliminating the production of greenhouse gases. With Argonne's approach, a disk-type dense ceramic/metal composite (cermet) membrane is used to produce ethylene by dehydrogenation of ethane at 850 C. The gas-transport membrane reactor combines a reversible chemical reaction with selective separation of one product species and leads to increased reactant conversion to the desired product. In an experiment ethane was passed over one side of the HTM membrane and air over the other side. The hydrogen produced by the dehydrogenation of ethane was removed and transported through the HTM to the air side. The air provided the driving force required for the transport of hydrogen through the HTM. The reaction between transported hydrogen and oxygen in air can provide the energy needed for the dehydrogenation reaction. At 850 C and 1-atm pressure, equilibrium conversion of ethane normally limits the ethylene yield to 64%, but Argonne has shown that an ethylene yield of 69% with a selectivity of 88% can be obtained under the same conditions. Coking was not a problem in runs extending over several weeks. Further improved HTM materials will lower the temperature required for high conversion at a reasonable residence time, while the lower temperature will suppress unwanted side reactions and prolong membrane life. With the Argonne approach, oxygen does not contact the ethane/ethylene stream, so oxidation products are not formed. Consequently, higher selectivity to ethylene and fewer by-products can be achieved. Some benefits are: (1) Simplifies overall product purification and processing schemes; (2) Results in greater energy efficiency; (3) Completely eliminates greenhouse gases from the reactor section; and (4) Lowers the cost of the 'back end' purification train, which accounts for about 70% of the capital cost of a conventional ethylene production unit.

  1. The Research Path to Determining the Natural Gas Supply Potential of Marine Gas Hydrates

    SciTech Connect (OSTI)

    Boswell, R.M.; Rose, K.K.; Baker, R.C.

    2008-06-01

    A primary goal of the U.S. National Interagency Gas Hydrates R&D program is to determine the natural gas production potential of marine gas hydrates. In pursuing this goal, four primary areas of effort are being conducted in parallel. First, are wide-ranging basic scientific investigations in both the laboratory and in the field designed to advance the understanding of the nature and behavior of gas hydrate bearing sediments (GHBS). This multi-disciplinary work has wide-ranging direct applications to resource recovery, including assisting the development of exploration and production technologies through better rock physics models for GHBS and also in providing key data for numerical simulations of productivity, reservoir geomechanical response, and other phenomena. In addition, fundamental science efforts are essential to developing a fuller understanding of the role gas hydrates play in the natural environment and the potential environmental implications of gas hydrate production, a critical precursor to commercial extraction. A second area of effort is the confirmation of resource presence and viability via a series of multi-well marine drilling expeditions. The collection of data in the field is essential to further clarifying what proportion of the likely immense in-place marine gas hydrate resource exists in accumulations of sufficient quality to represent potential commercial production prospects. A third research focus area is the integration of geologic, geophysical, and geochemical field data into an effective suite of exploration tools that can support the delineation and characterization commercial gas hydrate prospects prior to drilling. The fourth primary research focus is the development and testing of well-based extraction technologies (including drilling, completion, stimulation and production) that can safely deliver commercial gas production rates from gas hydrate reservoirs in a variety of settings. Initial efforts will take advantage of the relatively favorable economics of conducting production tests in Arctic gas-hydrate bearing sandstones with the intent of translating the knowledge gained to later testing in marine sandstone reservoirs. The full and concurrent pusuit of each of these research topics is essential to the determining the future production potential of naturally-occuring gas hydrates.

  2. 2011 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program September 2011 Prepared by Pacific Northwest National Laboratory for the U.S. Department of Energy Fuel Cell Technologies Program iii Table of Contents Summary

  3. Impact of Technological Change and Productivity on the Coal Market

    Reports and Publications (EIA)

    2000-01-01

    This paper examines the components of past gains in productivity, including regional shifts, the exit of less productive producers, and technological progress Future prospects for continuing productivity gains at sustained, but lower, rates of improvement are discussed.

  4. Pathways to Commercial Success: Technologies and Products Supported by the

    Office of Scientific and Technical Information (OSTI)

    Fuel Cell Technologies Office - 2015 (Technical Report) | SciTech Connect Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2015 Citation Details In-Document Search Title: Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2015 This FY 2015 report updates the results of an effort to identify and document the commercial and emerging (projected to be commercialized within the next 3

  5. CONTENTS Concentrated Gas Hydrate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concentrated Gas Hydrate Deposits in the Kumano Forearc Basin, Nankai Trough, Japan .....1 Recent Advances in NETL's Laboratory Studies of Hydrate- Bearing Sediments .......................5 Initial Interpretation of Results from the Iġnik Sikumi Gas Hydrate Exchange Field Trial .. 10 A Fresh Look at the Mediterranean and Black Sea Basins: Potential for High-Quality Hydrate Reservoirs .....................15 Announcements .......................19 * United Nations Hydrate Report Published

  6. Development of Alaskan gas hydrate resources

    SciTech Connect (OSTI)

    Kamath, V.A.; Sharma, G.D.; Patil, S.L.

    1991-06-01

    The research undertaken in this project pertains to study of various techniques for production of natural gas from Alaskan gas hydrates such as, depressurization, injection of hot water, steam, brine, methanol and ethylene glycol solutions through experimental investigation of decomposition characteristics of hydrate cores. An experimental study has been conducted to measure the effective gas permeability changes as hydrates form in the sandpack and the results have been used to determine the reduction in the effective gas permeability of the sandpack as a function of hydrate saturation. A user friendly, interactive, menu-driven, numerical difference simulator has been developed to model the dissociation of natural gas hydrates in porous media with variable thermal properties. A numerical, finite element simulator has been developed to model the dissociation of hydrates during hot water injection process.

  7. Pathways to Commercial Success: Technologies and Products Supported...

    Office of Scientific and Technical Information (OSTI)

    within the next 3 to 5 years) hydrogen and fuel cell technologies and products ... Country of Publication: United States Language: English Subject: 08 HYDROGEN ...

  8. Oil & Natural Gas Projects Exploration and Production Technologies...

    Open Energy Info (EERE)

    & Natural Gas Projects Exploration and Production Technologies Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Oil & Natural Gas Projects Exploration...

  9. Production Well Performance Enhancement using Sonication Technology

    SciTech Connect (OSTI)

    Adewumi, Michael A; Ityokumbul, M Thaddeus; Watson, Robert W; Eltohami, Eltohami; Farias, Mario; Heckman, Glenn; Houlihan, Brendan; Karoor, Samata Prakash; Miller, Bruce G; Mohammed, Nazia; Olanrewaju, Johnson; Ozdemir, Mine; Rejepov, Dautmamed; Sadegh, Abdallah A; Quammie, Kevin E; Zaghloul, Jose; Hughes, W Jack; Montgomery, Thomas C

    2005-12-31

    The objective of this project was to develop a sonic well performance enhancement technology that focused on near wellbore formation damage. In order to successfully achieve this objective, a three-year project was defined. The entire project was broken into four tasks. The overall objective of all this was to foster a better understanding of the mechanisms involved in sonic energy interactions with fluid flow in porous media and adapt such knowledge for field applications. The fours tasks are: Laboratory studies Mathematical modeling Sonic tool design and development Field demonstration The project was designed to be completed in three years; however, due to budget cuts, support was only provided for the first year, and hence the full objective of the project could not be accomplished. This report summarizes what was accomplished with the support provided by the US Department of Energy. Experiments performed focused on determining the inception of cavitation, studying thermal dissipation under cavitation conditions, investigating sonic energy interactions with glass beads and oil, and studying the effects of sonication on crude oil properties. Our findings show that the voltage threshold for onset of cavitation is independent of transducer-hydrophone separation distance. In addition, thermal dissipation under cavitation conditions contributed to the mobilization of deposited paraffins and waxes. Our preliminary laboratory experiments suggest that waxes are mobilized when the fluid temperature approaches 40C. Experiments were conducted that provided insights into the interactions between sonic wave and the fluid contained in the porous media. Most of these studies were carried out in a slim-tube apparatus. A numerical model was developed for simulating the effect of sonication in the nearwellbore region. The numerical model developed was validated using a number of standard testbed problems. However, actual application of the model for scale-up purposes was limited due to funding constraints. The overall plan for this task was to perlorm field trials with the sonication tooL These trials were to be performed in production and/or injection wells located in Pennsylvania, New York, and West Virginia. Four new wells were drilled in preparation for the field demonstration. Baseline production data were collected and reservoir simulator tuned to simulate these oil reservoirs. The sonication tools were designed for these wells. However, actual field testing could not be carried out because of premature termination of the project.

  10. Physical Properties of Gas Hydrates: A Review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gabitto, Jorge F.; Tsouris, Costas

    2010-01-01

    Memore » thane gas hydrates in sediments have been studied by several investigators as a possible future energy resource. Recent hydrate reserves have been estimated at approximately 10 16   m 3 of methane gas worldwide at standard temperature and pressure conditions. In situ dissociation of natural gas hydrate is necessary in order to commercially exploit the resource from the natural-gas-hydrate-bearing sediment. The presence of gas hydrates in sediments dramatically alters some of the normal physical properties of the sediment. These changes can be detected by field measurements and by down-hole logs. An understanding of the physical properties of hydrate-bearing sediments is necessary for interpretation of geophysical data collected in field settings, borehole, and slope stability analyses; reservoir simulation; and production models. This work reviews information available in literature related to the physical properties of sediments containing gas hydrates. A brief review of the physical properties of bulk gas hydrates is included. Detection methods, morphology, and relevant physical properties of gas-hydrate-bearing sediments are also discussed.« less

  11. DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2024: Hydrogen Production Cost Using Low-Cost Natural Gas DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production Cost Using Low-Cost Natural Gas This program record ...

  12. Pathways to Commercial Success. Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect (OSTI)

    none,

    2010-08-01

    This report identifies the commercial and near-commercial (emerging) hydrogen and fuel cell technologies and products that resulted from Department of Energy support through the Fuel Cell Technologies Program in the Office of Energy Efficiency and Renewable Energy.

  13. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report identifies the commercial and near-commercial (emerging) hydrogen and fuel cell technologies and products that resulted from Department of Energy support through the Fuel Cell Technologies

  14. Solar and Wind Technologies for Hydrogen Production Report to Congress

    SciTech Connect (OSTI)

    None, None

    2005-12-01

    DOE's Solar and Wind Technologies for Hydrogen Production Report to Congress summarizes the technology roadmaps for solar- and wind-based hydrogen production. Published in December 2005, it fulfills the requirement under section 812 of the Energy Policy Act of 2005.

  15. Methane Hydrate Program

    Energy Savers [EERE]

    Fiscal Year 2013 Methane Hydrate Program Report to Congress October 2014 United States Department of Energy Washington, DC 20585 Department of Energy | October 2014 Fiscal Year 2013 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary The Department of Energy is required 1 to submit to Congress an annual report on the actions taken to carry out methane hydrate research. I am pleased to submit the enclosed Report to Congress, Fiscal Year 2013 Methane Hydrate Program.

  16. Suite of Photo-electrochemical Technologies for Hydrogen Production -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Solar Photovoltaic Solar Photovoltaic Hydrogen and Fuel Cell Hydrogen and Fuel Cell Advanced Materials Advanced Materials Find More Like This Return to Search Suite of Photo-electrochemical Technologies for Hydrogen Production National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary The primary fuel powering new fuel cell technologies is hydrogen. The market for fuel cells is expected

  17. DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production Cost

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Low-Cost Natural Gas | Department of Energy 2024: Hydrogen Production Cost Using Low-Cost Natural Gas DOE Fuel Cell Technologies Office Record 12024: Hydrogen Production Cost Using Low-Cost Natural Gas This program record from the U.S. Department of Energy's Fuel Cell Technologies Office provides information about the cost of hydrogen production using low-cost natural gas. PDF icon DOE Hydrogen and Fuel Cells Program Record # 12024 More Documents & Publications Distributed Hydrogen

  18. Overview on Hydrate Coring, Handling and Analysis

    SciTech Connect (OSTI)

    Jon Burger; Deepak Gupta; Patrick Jacobs; John Shillinglaw

    2003-06-30

    Gas hydrates are crystalline, ice-like compounds of gas and water molecules that are formed under certain thermodynamic conditions. Hydrate deposits occur naturally within ocean sediments just below the sea floor at temperatures and pressures existing below about 500 meters water depth. Gas hydrate is also stable in conjunction with the permafrost in the Arctic. Most marine gas hydrate is formed of microbially generated gas. It binds huge amounts of methane into the sediments. Worldwide, gas hydrate is estimated to hold about 1016 kg of organic carbon in the form of methane (Kvenvolden et al., 1993). Gas hydrate is one of the fossil fuel resources that is yet untapped, but may play a major role in meeting the energy challenge of this century. In June 2002, Westport Technology Center was requested by the Department of Energy (DOE) to prepare a ''Best Practices Manual on Gas Hydrate Coring, Handling and Analysis'' under Award No. DE-FC26-02NT41327. The scope of the task was specifically targeted for coring sediments with hydrates in Alaska, the Gulf of Mexico (GOM) and from the present Ocean Drilling Program (ODP) drillship. The specific subjects under this scope were defined in 3 stages as follows: Stage 1: Collect information on coring sediments with hydrates, core handling, core preservation, sample transportation, analysis of the core, and long term preservation. Stage 2: Provide copies of the first draft to a list of experts and stakeholders designated by DOE. Stage 3: Produce a second draft of the manual with benefit of input from external review for delivery. The manual provides an overview of existing information available in the published literature and reports on coring, analysis, preservation and transport of gas hydrates for laboratory analysis as of June 2003. The manual was delivered as draft version 3 to the DOE Project Manager for distribution in July 2003. This Final Report is provided for records purposes.

  19. Methane Recovery from Hydrate-bearing Sediments

    SciTech Connect (OSTI)

    J. Carlos Santamarina; Costas Tsouris

    2011-04-30

    Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with emphasis; (6) detailed study of CH4-CO2 exchange as a unique alternative to recover CH4 gas while sequestering CO2; (7) the relevance of fines in otherwise clean sand sediments on gas recovery and related phenomena such as fines migration and clogging, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

  20. Buildings R&D Breakthroughs: Technologies and Products Supported by the Building Technologies Program

    SciTech Connect (OSTI)

    Weakley, Steven A.

    2012-04-15

    The purpose of the project described in this report is to identify and characterize commercially available products and emerging (near-commercial) technologies that benefited from the support of the Building Technologies Program (BTP) within the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy. The investigation specifically focused on technology-oriented research and development (R&D) projects funded by BTP’s Emerging Technologies subprogram from 2005-2011.

  1. Buildings R&D Breakthroughs. Technologies and Products Supported by the Building Technologies Program

    SciTech Connect (OSTI)

    none,

    2012-04-01

    This report identifies and characterizes commercially available products and emerging (near-commercial) technologies that benefited from the support of the Building Technologies Program (BTP) within the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy. The investigation specifically focused on technology-oriented research and development (R&D) projects sponsored by BTP’s Emerging Technologies subprogram from 2005-2009.

  2. Rapid gas hydrate formation processes: Will they work?

    SciTech Connect (OSTI)

    Brown, Thomas D.; Taylor, Charles E.; Bernardo, Mark P.

    2010-06-07

    Researchers at DOEs National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the laboratory. Numerous experiments were conducted with various high-pressure cells equipped with instrumentation to study rapid and continuous hydrate formation. The cells ranged in size from 100 mL for screening studies to proof-of-concept studies with NETLs 15-Liter Hydrate Cell. The results from this work demonstrate that the rapid and continuous formation of methane hydrate is possible at predetermined temperatures and pressures within the stability zone of a Methane Hydrate Stability Curve.

  3. Rapid gas hydrate formation processes: Will they work?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brown, Thomas D.; Taylor, Charles E.; Bernardo, Mark P.

    2010-06-07

    Researchers at DOE’s National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the laboratory. Numerous experiments were conducted with various high-pressure cells equipped with instrumentation to study rapid and continuous hydrate formation. The cells ranged in size from 100 mL for screening studies to proof-of-concept studies with NETL’s 15-Liter Hydrate Cell. The results from this work demonstrate that the rapid and continuousmore » formation of methane hydrate is possible at predetermined temperatures and pressures within the stability zone of a Methane Hydrate Stability Curve.« less

  4. Fuel Cell Technologies Researcher Lightens Green Fuel Production

    Broader source: Energy.gov [DOE]

    Research funded by EEREs Fuel Cell Technologies Office has dramatically increased the efficiency of biofuel production by changing certain genes in algae to make them pale green.

  5. Buildings R&D Breakthroughs: Technologies and Products Supported by the Building Technologies Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies Program Buildings R&D Breakthroughs: Technologies and Products Supported by the Building Technologies Program April 2012 Table of Contents Executive Summary v 1.0 Introduction 1-1 1.1 Organization of BTP and the Emerging Technologies Subprogram 1-1 1.2 Contents of this Report 1-3 2.0 Approach 2-1 2.1 Selection of Projects to Investigate 2-1 2.2 Technology Tracking of Commercially Available and Emerging Technologies 2-2 2.3 Quantifying Benefits of Commercially Available

  6. Characterization of morphology and hydration products of high-volume fly ash paste by monochromatic scanning x-ray micro-diffraction (?-SXRD)

    SciTech Connect (OSTI)

    Bae, Sungchul; Meral, Cagla; Oh, Jae-eun; Moon, Juhyuk; Kunz, Martin; Monteiro, Paulo J.M.

    2014-05-01

    The present study focuses on identification and micro-structural characterization of the hydration products formed in high-volume fly ash (HVFA)/portland cement (PC) systems using monochromatic scanning x-ray micro-diffraction (?-SXRD) and SEM-EDS. Pastes with up to 80% fly ash replacement were studied. Phase maps for HVFA samples using ?-SXRD patterns prove that ?-SXRD is an effective method to identify and visualize the distribution of phases in the matrix. ?-SXRD and SEM-EDS analysis shows that the C-S-H formed in HVFA system containing 50% or more of fly ash has a similar structure as C-S-H(I) with comparatively lower Ca/Si ratio than the one produced in PC system. Moreover, coexistence of C-S-H(I) and strtlingite is observed in the system containing 80% of fly ash, confirming that the amount of alumina and silicate phases provided by the fly ash is a major factor for the formation of C-S-H(I) and strtlingite in HVFA system. - Highlights: High-volume fly ash (HVFA) paste was studied by scanning x-ray micro-diffraction. Coexistence of C-S-H(I) and strtlingite in the HVFA system is clearly shown. The distribution of minor phases in the HVFA system is shown. Differences between inner and outer products of fly ash are observed by SEM-EDS.

  7. Guest Molecule Exchange Kinetics for the 2012 Ignik Sikumi Gas Hydrate Field Trial

    SciTech Connect (OSTI)

    White, Mark D.; Lee, Won Suk

    2014-05-14

    A commercially viable technology for producing methane from natural gas hydrate reservoirs remains elusive. Short-term depressurization field tests have demonstrated the potential for producing natural gas via dissociation of the clathrate structure, but the long-term performance of the depressurization technology ultimately requires a heat source to sustain the dissociation. A decade of laboratory experiments and theoretical studies have demonstrated the exchange of pure CO2 and N2-CO2 mixtures with CH4 in sI gas hydrates, yielding critical information about molecular mechanisms, recoveries, and exchange kinetics. Findings indicated the potential for producing natural gas with little to no production of water and rapid exchange kinetics, generating sufficient interest in the guest-molecule exchange technology for a field test. In 2012 the U.S. DOE/NETL, ConocoPhillips Company, and Japan Oil, Gas and Metals National Corporation jointly sponsored the first field trial of injecting a mixture of N2-CO2 into a CH4-hydrate bearing formation beneath the permafrost on the Alaska North Slope. Known as the Ignik Sikumi #1 Gas Hydrate Field Trial, this experiment involved three stages: 1) the injection of a N2-CO2 mixture into a targeted hydrate-bearing layer, 2) a 4-day pressurized soaking period, and 3) a sustained depressurization and fluid production period. Data collected during the three stages of the field trial were made available after an extensive quality check. These data included continuous temperature and pressure logs, injected and recovered fluid compositions and volumes. The Ignik Sikumi #1 data set is extensive, but contains no direct evidence of the guest-molecule exchange process. This investigation is directed at using numerical simulation to provide an interpretation of the collected data. A numerical simulator, STOMP-HYDT-KE, was recently completed that solves conservation equations for energy, water, mobile fluid guest molecules, and hydrate guest molecules, for up to three gas hydrate guest molecules: CH4, CO2, and N2. The independent tracking of mobile fluid and hydrate guest molecules allows for the kinetic exchange of guest molecules between the mobile fluids and hydrate. The particular interest of this numerical investigation is to determine whether kinetic exchange parameters, determined from laboratory-scale experiments, are directly applicable to interpreting the Ignik Sikumi #1 data.

  8. Methane Hydrate Field Program

    SciTech Connect (OSTI)

    2013-12-31

    This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. • Historical Methane Hydrate Project Review Report • Methane Hydrate Workshop Report • Topical Report: Marine Methane Hydrate Field Research Plan • Final Scientific/Technical Report

  9. CONTENTS Gas Hydrate Assessment in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas Hydrate Assessment in the Northern Gulf of Mexico: Preliminary Results Reveal New Prospects .........................................1 A Global Review of Gas Hydrate Resource Potential ........................5 Prospecting for Gas Hydrate Resources .........................................9 Announcements ...................... 14 * AGU Technical Sessions on Methane Hydrates * Ninth International Methane Hydrate Workshop in Hyderabad, India * Gulf of Mexico JIP Leg II Well Logs Available

  10. Methane Hydrate Program

    Energy Savers [EERE]

    FY 2011 Methane Hydrate Program Report to Congress July 2012 United States Department of Energy Washington, DC 20585 Department of Energy | July 2012 FY 2011 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled U.S. Department of Energy FY 2011 Methane

  11. Methane Hydrate Program

    Energy Savers [EERE]

    Fiscal Year 2012 Methane Hydrate Program Report to Congress August 2013 United States Department of Energy Washington, DC 20585 Department of Energy | August 2013 Fiscal Year 2012 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the actions taken to carry out methane hydrate research. I am pleased to submit the enclosed report, entitled U.S.

  12. Methane Hydrate Program

    Office of Environmental Management (EM)

    from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of ... implications of the potentially vast occurrence of gas hydrate in nature. ...

  13. Technology diffusion of energy-related products in residential markets

    SciTech Connect (OSTI)

    Davis, L.J.; Bruneau, C.L.

    1987-05-01

    Acceptance of energy-related technologies by end residential consumers, manufacturers of energy-related products, and other influential intermediate markets such as builders will influence the potential for market penetration of innovative energy-related technologies developed by the Department of Energy, Office of Building and Community Systems (OBCS). In this report, Pacific Northwest Laboratory reviewed the available information on technology adoption, diffusion, and decision-making processes to provide OBCS with a background and understanding of the type of research that has previously been conducted on this topic. Insight was gained as to the potential decision-making criteria and motivating factors that influence the decision-maker(s) selection of new technologies, and some of the barriers to technology adoption faced by potential markets for OBCS technologies.

  14. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2013

    Fuel Cell Technologies Publication and Product Library (EERE)

    This FY 2013 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell T

  15. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program - 2012

    Fuel Cell Technologies Publication and Product Library (EERE)

    This FY 2012 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell T

  16. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program - 2011

    Fuel Cell Technologies Publication and Product Library (EERE)

    This FY 2011 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell

  17. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2014

    Fuel Cell Technologies Publication and Product Library (EERE)

    This FY 2014 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell T

  18. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2014

    SciTech Connect (OSTI)

    None, None

    2015-02-01

    This FY 2014 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  19. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2013

    SciTech Connect (OSTI)

    none,

    2014-04-30

    This FY 2013 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  20. Pathways to Commercial Success. Technologies and Products Supported by the Fuel Cell Technologies Program - 2012

    SciTech Connect (OSTI)

    none,

    2012-09-01

    This FY 2012 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Program and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  1. Pathways to Commercial Success. Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect (OSTI)

    none,

    2011-09-01

    This FY 2011 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Program and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  2. Buildings R&D Breakthroughs: Technologies and Products Supported by the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building Technologies Program | Department of Energy R&D Breakthroughs: Technologies and Products Supported by the Building Technologies Program Buildings R&D Breakthroughs: Technologies and Products Supported by the Building Technologies Program PDF icon rd_breakthroughs.pdf More Documents & Publications 2012 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2011 Pathways to Commercial Success: Technologies and Products

  3. University of Maine Integrated Forest Product Refinery (IFPR) Technology Research

    SciTech Connect (OSTI)

    Pendse, Hemant P.

    2010-11-23

    This project supported research on science and technology that forms a basis for integrated forest product refinery for co-production of chemicals, fuels and materials using existing forest products industry infrastructure. Clear systems view of an Integrated Forest Product Refinery (IFPR) allowed development of a compelling business case for a small scale technology demonstration in Old Town ME for co-production of biofuels using cellulosic sugars along with pulp for the new owners of the facility resulting in an active project on Integrated Bio-Refinery (IBR) at the Old Town Fuel & Fiber. Work on production of advanced materials from woody biomass has led to active projects in bioplastics and carbon nanofibers. A lease for 40,000 sq. ft. high-bay space has been obtained to establish a Technology Research Center for IFPR technology validation on industrially relevant scale. UMaine forest bioproducts research initiative that began in April 2006 has led to establishment of a formal research institute beginning in March 2010.

  4. Novel Membrane Technology for Green Ethylene Production - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Find More Like This Return to Search Novel Membrane Technology for Green Ethylene Production Argonne National Laboratory Contact ANL About This Technology <p> Dehydrogenation1: This image is an electron micrograph of the Argonne catalytic membrane (side view).&nbsp; By decreasing the thickness and the overall hydrogen flux, researchers have dramatically improved the overall reactivity.</p> Dehydrogenation1: This image is an electron micrograph of the Argonne catalytic

  5. Innovative applications of technology for nuclear power plant productivity improvements

    SciTech Connect (OSTI)

    Naser, J. A.

    2012-07-01

    The nuclear power industry in several countries is concerned about the ability to maintain high plant performance levels due to aging and obsolescence, knowledge drain, fewer plant staff, and new requirements and commitments. Current plant operations are labor-intensive due to the vast number of operational and support activities required by commonly used technology in most plants. These concerns increase as plants extend their operating life. In addition, there is the goal to further improve performance while reducing human errors and increasingly focus on reducing operations and maintenance costs. New plants are expected to perform more productively than current plants. In order to achieve and increase high productivity, it is necessary to look at innovative applications of modern technologies and new concepts of operation. The Electric Power Research Inst. is exploring and demonstrating modern technologies that enable cost-effectively maintaining current performance levels and shifts to even higher performance levels, as well as provide tools for high performance in new plants. Several modern technologies being explored can provide multiple benefits for a wide range of applications. Examples of these technologies include simulation, visualization, automation, human cognitive engineering, and information and communications technologies. Some applications using modern technologies are described. (authors)

  6. Hydrogen Production Roadmap: Technology Pathways to the Future

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    FreedomCAR and Fuel Partnership Hydrogen Production Technical Team This roadmap was created by the Hydrogen Production Technical Team (HPTT) of the FreedomCAR and Fuel Partnership. This is a partnership of industry's U.S. Council for Automotive Research (USCAR), energy companies and the U.S. Department of Energy (DOE) to advance technologies that enable reduced oil consumption and increased energy efficiency in passenger vehicles. The Partnership focuses on the pre-competitive, high-risk

  7. Development of Alaskan gas hydrate resources. Final report

    SciTech Connect (OSTI)

    Kamath, V.A.; Sharma, G.D.; Patil, S.L.

    1991-06-01

    The research undertaken in this project pertains to study of various techniques for production of natural gas from Alaskan gas hydrates such as, depressurization, injection of hot water, steam, brine, methanol and ethylene glycol solutions through experimental investigation of decomposition characteristics of hydrate cores. An experimental study has been conducted to measure the effective gas permeability changes as hydrates form in the sandpack and the results have been used to determine the reduction in the effective gas permeability of the sandpack as a function of hydrate saturation. A user friendly, interactive, menu-driven, numerical difference simulator has been developed to model the dissociation of natural gas hydrates in porous media with variable thermal properties. A numerical, finite element simulator has been developed to model the dissociation of hydrates during hot water injection process.

  8. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, Jr., Earle D.

    1995-01-01

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member and/or six member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone.

  9. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes May 15, 2014 Washington, DC...

  10. International Cooperation in Methane Hydrates | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oil & Gas Methane Hydrate International Cooperation in Methane Hydrates International Cooperation in Methane Hydrates In 1982 the multi-national Deep Sea Drilling Program ...

  11. Western oil-shale development: a technology assessment. Volume 2: technology characterization and production scenarios

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    A technology characterization of processes that may be used in the oil shale industry is presented. The six processes investigated are TOSCO II, Paraho Direct, Union B, Superior, Occidental MIS, and Lurgi-Ruhrgas. A scanario of shale oil production to the 300,000 BPD level by 1990 is developed. (ACR)

  12. Conversion Technologies for Advanced Biofuels … Bio-Oil Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Report-Out Webinar February 9, 2012 David Dayton, Ph.D. RTI International Energy Efficiency & Renewable Energy eere.energy.gov 2 Dr. David C. Dayton Director, Chemistry and Biofuels Center for Energy Technology RTI International 2007 - present RTI International 1993 - 2007 National Renewable Energy Laboratory 1991-1993 U.S. Army Research Laboratory * Ph.D., Biochemistry, University of Texas Health Science Center at San Antonio, 2000 * B.S., Biochemistry, cum laude, Washington

  13. Geomechanical Performance of Hydrate-Bearing Sediment in Offshore Environments

    SciTech Connect (OSTI)

    Stephen Holditch; Tad Patzek; Jonny Rutqvist; George Moridis; Richard Plumb

    2008-03-31

    The objective of this multi-year, multi-institutional research project was to develop the knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate-bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus was on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. We have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. We also investigated the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. The objective of the UC Berkeley work was to develop a grain-scale model of hydrate-bearing sediments. Hydrate dissociation alters the strength of HBS. In particular, transformation of hydrate clusters into gas and liquid water weakens the skeleton and, simultaneously, reduces the effective stress by increasing the pore pressure. The large-scale objective of the study is evaluation of geomechanical stability of offshore oil and gas production infrastructure. At Lawrence Berkeley National Laboratory (LBNL), we have developed the numerical model TOUGH + Hydrate + FLAC3D to evaluate how the formation and disassociation of hydrates in seafloor sediments affects seafloor stability. Several technical papers were published using results from this model. LBNL also developed laboratory equipment and methods to produce realistic laboratory samples of sediments containing gas hydrates so that mechanical properties could be measured in the laboratory. These properties are required to run TOUGH + Hydrate + FLAC3D to evaluate seafloor stability issues. At Texas A&M University we performed a detailed literature review to determine what gas hydrate formation properties had been measured and reported in the literature. We then used TOUGH + Hydrate to simulate the observed gas production and reservoir pressure field data at Messoyakha. We simulated various scenarios that help to explain the field behavior. We have evaluated the effect of reservoir parameters on gas recovery from hydrates. Our work should be beneficial to others who are investigating how to produce gas from a hydrate capped gas reservoir. The results also can be used to better evaluate the process of producing gas from offshore hydrates. The Schlumberger PETREL model is used in industry to the description of geologic horizons and the special distribution of properties. An interface between FLAC3D and Petrel was built by Schlumberger to allow for efficient data entry into TOUGH + Hydrate + FLAC3D.

  14. GULF OF MEXICO SEAFLOOR STABILITY AND GAS HYDRATE MONITORING STATION PROJECT

    SciTech Connect (OSTI)

    J. Robert Woolsey; Thomas M. McGee; Robin C. Buchannon

    2004-11-01

    The gas hydrates research Consortium (HRC), established and administered at the University if Mississippi's Center for Marine Research and Environmental Technology (CMRET) has been active on many fronts in FY 03. Extension of the original contract through March 2004, has allowed completion of many projects that were incomplete at the end of the original project period due, primarily, to severe weather and difficulties in rescheduling test cruises. The primary objective of the Consortium, to design and emplace a remote sea floor station for the monitoring of gas hydrates in the Gulf of Mexico by the year 2005 remains intact. However, the possibility of levering HRC research off of the Joint Industries Program (JIP) became a possibility that has demanded reevaluation of some of the fundamental assumptions of the station format. These provisions are discussed in Appendix A. Landmark achievements of FY03 include: (1) Continuation of Consortium development with new researchers and additional areas of research contribution being incorporated into the project. During this period, NOAA's National Undersea Research Program's (NURP) National Institute for Undersea Science and Technology (NIUST) became a Consortium funding partner, joining DOE and Minerals Management Service (MMS); (2) Very successful annual and semiannual meetings in Oxford Mississippi in February and September, 2003; (3) Collection of piston cores from MC798 in support of the effort to evaluate the site for possible monitoring station installation; (4) Completion of the site evaluation effort including reports of all localities in the northern Gulf of Mexico where hydrates have been documented or are strongly suspected to exist on the sea floor or in the shallow subsurface; (5) Collection and preliminary evaluation of vent gases and core samples of hydrate from sites in Green Canyon and Mississippi Canyon, northern Gulf of Mexico; (6) Monitoring of gas activity on the sea floor, acoustically and thermally; (7) Design, construction, and successful deployment of an in situ pore-water sampling device; (8) Improvements to the original Raman spectrometer (methane sensor); (9) Laboratory demonstration of the impact of bacterially-produced surfactants' rates of hydrate formation; (10) Construction and sea floor emplacement and testing--with both watergun and ship noise sources--of the prototypal vertical line array (VLA); (11) Initiation of studies of spatial controls on hydrates; (12) Compilation and analyses of seismic data, including mapping of surface anomalies; (13) Additional field verification (bottom samples recovered), in support of the site selection effort; (14) Collection and preliminary analyses of gas hydrates from new sites that exhibit variant structures; (15) Initial shear wave tests carried out in shallow water; (16) Isolation of microbes for potential medicinal products development; (17) Preliminary modeling of occurrences of gas hydrates.

  15. Data from Alaska Test Could Help Advance Methane Hydrate R&D

    Broader source: Energy.gov [DOE]

    Methane Hydrates present an enormous energy resource. The Energy Department is working to advance technologies and reap the possible benefits for a more secure energy future.

  16. Methane Hydrate | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane hydrate is a cage-like lattice of ice inside of which are trapped molecules of methane, the chief constituent of natural gas. If methane hydrate is either warmed or ...

  17. Methane Hydrates and Climate Change

    Broader source: Energy.gov [DOE]

    Methane hydrates store huge volumes of methane formed by the bacterial decay of organic matter or leaked from underlying oil and natural gas deposits. The active formation of methane hydrates in...

  18. Methane Hydrate Program Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Reports Methane Hydrate Program Reports PDF icon Secretary of Energy Advisory Board Task Force Report on Methane Hydrate PDF icon FY14 Methane Hydrate Report to Congress PDF icon FY13 Methane Hydrate Report to Congress PDF icon FY12 Methane Hydrate Report to Congress More Documents & Publications Methane Hydrate Annual Reports Report of the Task Force on Methane Hydrates Presentations from the March 27th - 28th Methane Hydrates Advisory Committee

  19. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect (OSTI)

    Weakley, Steven A.

    2012-09-28

    The purpose of the project described in this report is to identify and document the commercial and emerging (projected to be commercialized within the next 3 years) hydrogen and fuel cell technologies and products that resulted from Department of Energy support through the Fuel Cell Technologies (FCT) Program in the Office of Energy Efficiency and Renewable Energy (EERE). Pacific Northwest National Laboratory (PNNL) undertook two efforts simultaneously to accomplish this project. The first effort was a patent search and analysis to identify patents related to hydrogen and fuel cells that are associated with FCT-funded projects (or projects conducted by DOE-EERE predecessor programs) and to ascertain the patents’ current status, as well as any commercial products that may have used the technology documented in the patent. The second effort was a series of interviews with current and past FCT personnel, a review of relevant program annual reports, and an examination of grants made under the Small Business Innovation Research and Small Business Technology Transfer Programs that are related to hydrogen and fuel cells.

  20. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect (OSTI)

    Weakley, Steven A.; Brown, Scott A.

    2011-09-29

    The purpose of the project described in this report is to identify and document the commercial and emerging (projected to be commercialized within the next 3 years) hydrogen and fuel cell technologies and products that resulted from Department of Energy support through the Fuel Cell Technologies (FCT) Program in the Office of Energy Efficiency and Renewable Energy (EERE). To do this, Pacific Northwest National Laboratory (PNNL) undertook two efforts simultaneously to accomplish this project. The first effort was a patent search and analysis to identify hydrogen- and fuel-cell-related patents that are associated with FCT-funded projects (or projects conducted by DOE-EERE predecessor programs) and to ascertain the patents current status, as well as any commercial products that may have used the technology documented in the patent. The second effort was a series of interviews with current and past FCT personnel, a review of relevant program annual reports, and an examination of hydrogen- and fuel-cell-related grants made under the Small Business Innovation Research and Small Business Technology Transfer Programs, and within the FCT portfolio.

  1. Engineering analysis of biomass gasifier product gas cleaning technology

    SciTech Connect (OSTI)

    Baker, E.G.; Brown, M.D.; Moore, R.H.; Mudge, L.K.; Elliott, D.C.

    1986-08-01

    For biomass gasification to make a significant contribution to the energy picture in the next decade, emphasis must be placed on the generation of clean, pollutant-free gas products. This reports attempts to quantify levels of particulated, tars, oils, and various other pollutants generated by biomass gasifiers of all types. End uses for biomass gases and appropriate gas cleaning technologies are examined. Complete systems analysis is used to predit the performance of various gasifier/gas cleanup/end use combinations. Further research needs are identified. 128 refs., 20 figs., 19 tabs.

  2. Energy-Efficient Products and Energy-Saving Technologies | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Energy-Efficient Products and Energy-Saving Technologies Energy-Efficient Products and Energy-Saving Technologies The Federal Energy Management Program (FEMP) provides information about energy-efficient products and promising new energy-saving technologies that can help agencies meet federal laws and requirements. Explore this section to learn about: Energy- and water-efficient products: Find products covered by federal efficiency programs, product purchasing specifications, and more.

  3. Natural gas hydrates on the North Slope of Alaska

    SciTech Connect (OSTI)

    Collett, T.S.

    1991-01-01

    Gas hydrates are crystalline substances composed of water and gas, mainly methane, in which a solid-water lattice accommodates gas molecules in a cage-like structure, or clathrate. These substances often have been regarded as a potential (unconventional) source of natural gas. Significant quantities of naturally occurring gas hydrates have been detected in many regions of the Arctic including Siberia, the Mackenzie River Delta, and the North Slope of Alaska. On the North Slope, the methane-hydrate stability zone is areally extensive beneath most of the coastal plain province and has thicknesses as great as 1000 meters in the Prudhoe Bay area. Gas hydrates have been identified in 50 exploratory and production wells using well-log responses calibrated to the response of an interval in one well where gas hydrates were recovered in a core by ARCO Alaska and EXXON. Most of these gas hydrates occur in six laterally continuous Upper Cretaceous and lower Tertiary sandstone and conglomerate units; all these gas hydrates are geographically restricted to the area overlying the eastern part of the Kuparuk River Oil Field and the western part of the Prudhoe Bay Oil Field. The volume of gas within these gas hydrates is estimated to be about 1.0 {times} 10{sup 12} to 1.2 {times} 10{sup 12} cubic meters (37 to 44 trillion cubic feet), or about twice the volume of conventional gas in the Prudhoe Bay Field. Geochemical analyses of well samples suggest that the identified hydrates probably contain a mixture of deep-source thermogenic gas and shallow microbial gas that was either directly converted to gas hydrate or first concentrated in existing traps and later converted to gas hydrate. The thermogenic gas probably migrated from deeper reservoirs along the same faults thought to be migration pathways for the large volumes of shallow, heavy oil that occur in this area. 51 refs., 11 figs., 3 tabs.

  4. Review of the findings of the Ignik Sikumi CO2-CH4 gas hydrate exchange field trial

    SciTech Connect (OSTI)

    Anderson, Brian J.; Boswell, Ray; Collett, Tim S.; Farrell, Helen; Ohtsuka, Satoshi; White, Mark D.

    2014-08-01

    The Ignik Sikumi Gas Hydrate Exchange Field Trial was conducted by ConocoPhillips in partnership with the U.S. Department of Energy, the Japan Oil, Gas, and Metals National Corporation, and the U.S. Geological Survey within the Prudhoe Bay Unit on the Alaska North Slope (ANS) during 2011 and 2012. The 2011 field program included drilling the vertical test well and performing extensive wireline logging through a thick section of gas-hydrate-bearing sand reservoirs that provided substantial new insight into the nature of ANS gas hydrate occurrences. The 2012 field program involved an extended, scientific field trial conducted within a single vertical well (“huff-and-puff” design) through three primary operational phases: 1) injection of a gaseous phase mixture of CO2, N2, and chemical tracers; 2) flowback conducted at down-hole pressures above the stability threshold for native CH4-hydrate, and 3) extended (30-days) flowback at pressures below the stability threshold of native CH4-hydrate. Ignik Sikumi represents the first field investigation of gas hydrate response to chemical injection, and the longest-duration field reservoir response experiment yet conducted. Full descriptions of the operations and data collected have been fully reported by ConocoPhillips and are available to the science community. The 2011 field program indicated the presence of free water within the gas hydrate reservoir, a finding with significant implications to the design of the exchange trial – most notably the use of a mixed gas injectant. While this decision resulted in a complex chemical environment within the reservoir that greatly tests current experimental and modeling capabilities – without such a mixture, it is apparent that injection could not have been achieved. While interpretation of the field data are continuing, the primary scientific findings and implications of the program are: 1) gas hydrate destabilizing is self-limiting, dispelling any notion of the potential for uncontrolled destabilization; 2) wells must be carefully designed to enable rapid remediation of well-bore blockages that will occur during any cessation in operations; 3) appropriate gas mixes can be successfully injected into hydrate-bearing reservoirs; 4) sand production can be well-managed through standard engineering controls; 5) reservoir heat exchange during depressurization was much more favorable than expected – mitigating concerns for near-well-bore freezing and enabling consideration of more aggressive pressure reduction and; 6) CO2-CH4 exchange can be accomplished in natural reservoirs. The next steps in evaluation of exchange technology should feature multiple well applications; however such field programs will require extensive preparatory experimental and numerical modeling studies and will likely be a secondary priority to further field testing of production through depressurization.

  5. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  6. Advanced Electrochemical Technologies for Hydrogen Production by Alternative Thermochemical Cycles

    SciTech Connect (OSTI)

    Lvov, Serguei; Chung, Mike; Fedkin, Mark; Lewis, Michele; Balashov, Victor; Chalkova, Elena; Akinfiev, Nikolay; Stork, Carol; Davis, Thomas; Gadala-Maria, Francis; Stanford, Thomas; Weidner, John; Law, Victor; Prindle, John

    2011-01-06

    Hydrogen fuel is a potentially major solution to the problem of climate change, as well as addressing urban air pollution issues. But a key future challenge for hydrogen as a clean energy carrier is a sustainable, low-cost method of producing it in large capacities. Most of the world's hydrogen is currently derived from fossil fuels through some type of reforming processes. Nuclear hydrogen production is an emerging and promising alternative to the reforming processes for carbon-free hydrogen production in the future. This report presents the main results of a research program carried out by a NERI Consortium, which consisted of Penn State University (PSU) (lead), University of South Carolina (USC), Tulane University (TU), and Argonne National Laboratory (ANL). Thermochemical water decomposition is an emerging technology for large-scale production of hydrogen. Typically using two or more intermediate compounds, a sequence of chemical and physical processes split water into hydrogen and oxygen, without releasing any pollutants externally to the atmosphere. These intermediate compounds are recycled internally within a closed loop. While previous studies have identified over 200 possible thermochemical cycles, only a few have progressed beyond theoretical calculations to working experimental demonstrations that establish scientific and practical feasibility of the thermochemical processes. The Cu-Cl cycle has a significant advantage over other cycles due to lower temperature requirements around 530 C and below. As a result, it can be eventually linked with the Generation IV thermal power stations. Advantages of the Cu-Cl cycle over others include lower operating temperatures, ability to utilize low-grade waste heat to improve energy efficiency, and potentially lower cost materials. Another significant advantage is a relatively low voltage required for the electrochemical step (thus low electricity input). Other advantages include common chemical agents and reactions going to completion without side reactions, and lower demands on materials of construction. Three university research groups from PSU, USC, and TU as well as a group from ANL have been collaborating on the development of enabling technologies for the Cu-Cl cycle, including experimental work on the Cu-Cl cycle reactions, modeling and simulation, and particularly electrochemical reaction for hydrogen production using a CuCl electrolyzer. The Consortium research was distributed over the participants and organized in the following tasks: (1) Development of CuCl electrolyzer (PSU), (2) Thermodynamic modeling of anolyte solution (PSU), (3) Proton conductive membranes for CuCl electrolysis (PSU), (4) Development of an analytical method for online analysis of copper compounds in highly concentrated aqueous solutions (USC), (5) Electrodialysis as a means for separation and purification of the streams exiting the electrolyzer in the Cu-Cl cycle (USC), (6) Development of nanostructured electrocatalysts for the Cu-Cl electrolysis (USC), (7) Cu-Cl electrolyzer modeling (USC), (8) Aspen Plus modeling of the Cu-Cl thermochemical cycle (TU), (9) International coordination of research on the development of the Cu-Cl thermochemical cycle (ANL). The results obtained in the project clearly demonstrate that the Cu-Cl alternative thermochemical cycle is a promising and viable technology to produce hydrogen efficiently.

  7. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, M.P.; Kedl, R.J.

    1984-09-12

    The invention presented relates to the development of a process utilizing a gas hydrate as a cool storage medium for alleviating electric load demands during peak usage periods. Several objectives of the invention are mentioned concerning the formation of the gas hydrate as storage material in a thermal energy storage system within a heat pump cycle system. The gas hydrate was formed using a refrigerant in water and an example with R-12 refrigerant is included. (BCS)

  8. Hydrates Annual FY13 Format (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Hydrates Annual FY13 Format Citation Details In-Document Search Title: Hydrates Annual FY13 Format Authors: Seol, Yongkoo ; Guthrie, George Publication Date: 2014-04-11 OSTI Identifier: 1128555 Report Number(s): NETL-PUB-930 Resource Type: Technical Report Research Org: National Energy Technology Laboratory - In-house Research Sponsoring Org: USDOE Office of Fossil Energy (FE) Country of Publication: United States Language: English Subject: 03 NATURAL GAS; 58 GEOSCIENCES natural gas hydrates;

  9. Pathways to Commercial Success: Technologies and Products Supported by the Hydrogen, Fuel Cells and Infrastructure Technologies Program

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report documents the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Hydrogen, Fuel Ce

  10. Methane Hydrate Advisory Committee | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane Hydrate Advisory Committee Methane Hydrate Advisory Committee The Methane Hydrate Advisory Committee was created in response to provisions of the Methane Hydrate Research and Development Act of 2000 and reauthorized by the Energy Policy Act of 2005. The Committee is to advise the Secretary of Energy on potential applications of methane hydrate; assist in developing recommendations and priorities for the methane hydrate research and development program; and submit to Congress one or more

  11. Methane Hydrate Annual Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Reports Methane Hydrate Annual Reports Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of Methane Hydrate research. Listed are the Annual Reports per Fiscal Year. PDF icon FY 13 Methane Hydrates Annual Report to Congress PDF icon FY 12 Methane Hydrates Annual Report to Congress PDF icon FY 11 Methane Hydrates Annual Report to Congress PDF icon FY 10 Methane Hydrates Annual Report to Congress More

  12. Methane Hydrate Reservoir Simulator Code Comparison Study

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Annual Reports Methane Hydrate Annual Reports Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of Methane Hydrate research. Listed are the Annual Reports per Fiscal Year. PDF icon FY 13 Methane Hydrates Annual Report to Congress PDF icon FY 12 Methane Hydrates Annual Report to Congress PDF icon FY 11 Methane Hydrates Annual Report to Congress PDF icon FY 10 Methane Hydrates Annual Report to Congress More

  13. Pathways to Commercial Success: Technologies and Products Supported by the Hydrogen, Fuel Cells and Infrastructure Technologies Program

    SciTech Connect (OSTI)

    none,

    2009-08-01

    This report documents the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Hydrogen, Fuel Cells and Infrastructure Technologies Program and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  14. Some thermodynamical aspects of protein hydration water

    SciTech Connect (OSTI)

    Mallamace, Francesco; Corsaro, Carmelo; Mallamace, Domenico; Vasi, Sebastiano; Vasi, Cirino; Stanley, H. Eugene; Chen, Sow-Hsin

    2015-06-07

    We study by means of nuclear magnetic resonance the self-diffusion of protein hydration water at different hydration levels across a large temperature range that includes the deeply supercooled regime. Starting with a single hydration shell (h = 0.3), we consider different hydrations up to h = 0.65. Our experimental evidence indicates that two phenomena play a significant role in the dynamics of protein hydration water: (i) the measured fragile-to-strong dynamic crossover temperature is unaffected by the hydration level and (ii) the first hydration shell remains liquid at all hydrations, even at the lowest temperature.

  15. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2012 Houston, TX PDF icon July 26, 2012 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting...

  16. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Office of Environmental Management (EM)

    Washington, DC PDF icon July 16, 2013 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting...

  17. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Energy Savers [EERE]

    DC PDF icon March 27-28, 2014, Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane Hydrate Advisory...

  18. methane_hydrates | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Hydrates Special Report: Frozen Heat: A Global Outlook on Methane Hydrates The United Nations Environmental Programme released this new, two-volume report in March 2015....

  19. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Broader source: Energy.gov (indexed) [DOE]

    June 6th - 7th, 2013 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee Meeting...

  20. Energy Department Invests $20 Million to Advance Hydrogen Production and Delivery Technologies

    Broader source: Energy.gov [DOE]

    The Energy Department today announced $20 million for ten new research and development projects that will advance hydrogen production and delivery technologies.

  1. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, E.D. Jr.

    1995-07-11

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

  2. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, Jr., Earle D.

    1995-01-01

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

  3. Environmental benefits of advanced oil and gas exploration and production technology

    SciTech Connect (OSTI)

    1999-10-01

    THROUGHOUT THE OIL AND GAS LIFE CYCLE, THE INDUSTRY HAS APPLIED AN ARRAY OF ADVANCED TECHNOLOGIES TO IMPROVE EFFICIENCY, PRODUCTIVITY, AND ENVIRONMENTAL PERFORMANCE. THIS REPORT FOCUSES SPECIFICALLY ON ADVANCES IN EXPLORATION AND PRODUCTION (E&P) OPERATIONS.

  4. DOE Announces Selections for SSL Core Technology and Product...

    Energy Savers [EERE]

    ... This synergistic approach will establish a technology platform capable of providing high efficiency components, drivers and luminaires. Recipient: Dupont Displays, Inc. Title: ...

  5. 2015 Pathways to Commercial Success: Technologies and Products...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... This report documents the methodology and results of an effort to identify and ... Commercialization of technologies that are cultivated in a government research and ...

  6. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01

    Performance and produced polymer evaluation of four alkaline-surfactant-polymer projects concluded that only one of the projects could have benefited from combining the alkaline-surfactant-polymer and gelation technologies. Cambridge, the 1993 Daqing, Mellott Ranch, and the Wardlaw alkaline-surfacant-polymer floods were studied. An initial gel treatment followed by an alkaline-surfactant-polymer flood in the Wardlaw field would have been a benefit due to reduction of fracture flow. Numerical simulation demonstrated that reducing the permeability of a high permeability zone of a reservoir with gel improved both waterflood and alkaline-surfactant-polymer flood oil recovery. A Minnelusa reservoir with both A and B sand production was simulated. A and B sands are separated by a shale layer. A sand and B sand waterflood oil recovery was improved by 196,000 bbls or 3.3% OOIP when a gel was placed in the B sand. Alkaline-surfactant-polymer flood oil recovery improvement over a waterflood was 392,000 bbls or 6.5% OOIP. Placing a gel into the B sand prior to an alkaline-surfactant-polymer flood resulted in 989,000 bbl or 16.4% OOIP more oil than only water injection. A sand and B sand alkaline-surfactant-polymer flood oil recovery was improved by 596,000 bbls or 9.9% OOIP when a gel was placed in the B sand.

  7. Battery Company Puts New Nanowire Technology into Production

    Broader source: Energy.gov [DOE]

    A battery company supported by the Vehicle Technologies Office (VTO) has an agreement to manufacture silicon nanowire material for lithium-ion batteries on a commercial scale for the first time....

  8. GIS-technologies for integrated assessment of the productive mining areas

    SciTech Connect (OSTI)

    Zamaraev, R.Y.; Oparin, V.N.; Popov, S.E.; Potapov, V.P.; Pyastunovich,O.L.

    2008-05-15

    The paper describes the bases of a new application of GIS-technologies for integrated assessment and comparison of the productive mining areas, involving a wide range of mining and technological factors, considering mineral properties, mineral occurrence conditions and geographical advantages of a mineral deposit location. The model capabilities are exemplified by a comparison of technological characteristics of coals, transportation and power supply infrastructure of the productive mining areas at the Kuznetsk Coal Basin.

  9. Wax and hydrate control with electrical power

    SciTech Connect (OSTI)

    1997-08-01

    Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the gas/water phase may freeze solid with hydrate particles. The paper discusses thermal-insulated flowlines, heat-loss compensation with electrical power, electrical power consumption and operation, and subsea electrical-power distribution system.

  10. Methane Hydrate Advisory Committee Meeting

    Broader source: Energy.gov (indexed) [DOE]

    Methane Hydrate Advisory Committee Meeting May 15, 2014 11:00am - 12:30pm (EDT) Public Access U.S. Department of Energy Forrestal Building, Room 3G-043 1000 Independence Ave., SW...

  11. Hydrogenases and Barriers for Biotechnological Hydrogen Production Technologies

    Broader source: Energy.gov [DOE]

    Presentation by John Peters, Montana State University, at the Biological Hydrogen Production Workshop held September 24-25, 2013, at the National Renewable Energy Laboratory in Golden, Colorado.

  12. methane hydrates | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methane hydrates methane-hydrates.jpg Maintaining a focused vision on what's next is one trait that makes NETL a lab of the future, and methane hydrates are one "cool" part of that vision. Found in Arctic and deep-water marine environments, methane hydrates are an untapped abundant source of natural gas. A hydrate comprises a crystal structure in which frozen water creates a cage that traps molecules of primarily methane (natural gas). NETL researchers are exploring and developing

  13. CONTENTS Gas Hydrate-Bearing Sand

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONTENTS Gas Hydrate-Bearing Sand Reservoir Systems in the Offshore of India: Results of the India National Gas Hydrate Program Expedition 02 ..............1 The Potential for Abiotic Methane in Arctic Gas Hydrates .................9 Coupled Thermo-Hydro-Chemo- Mechanical (THCM) Models for Hydrate-Bearing Sediments ....13 Emerging Issues in the Development of Geologic Models for Gas Hydrate Numerical Simulation ................19 Announcements ...................... 23 * DOE/NETL FY2016 Methane

  14. Development of a Numerical Simulator for Analyzing the Geomechanical Performance of Hydrate-Bearing Sediments

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Rutqvist, J.; Moridis, G.J.

    2008-06-01

    In this paper, we describe the development and application of a numerical simulator that analyzes the geomechanical performance of hydrate-bearing sediments, which may become an important future energy supply. The simulator is developed by coupling a robust numerical simulator of coupled fluid flow, hydrate thermodynamics, and phase behavior in geologic media (TOUGH+HYDRATE) with an established geomechanical code (FLAC3D). We demonstrate the current simulator capabilities and applicability for two examples of geomechanical responses of hydrate bearing sediments during production-induced hydrate dissociation. In these applications, the coupled geomechanical behavior within hydrate-bearing seducements are considered through a Mohr-Coulomb constitutive model, corrected for changes in pore-filling hydrate and ice content, based on laboratory data. The results demonstrate how depressurization-based gas production from oceanic hydrate deposits may lead to severe geomechanical problems unless care is taken in designing the production scheme. We conclude that the coupled simulator can be used to design production strategies for optimizing production, while avoiding damaging geomechanical problems.

  15. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; David Stewart; Bill Jones

    2005-10-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency for those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or those with thief zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. A prior fluid-fluid report discussed interaction of different gel chemical compositions and alkaline-surfactant-polymer solutions. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses. Aluminum-polyacrylamide, flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9. Chromium acetate-polyacrylamide flowing and rigid flowing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid flowing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Chromium acetate-xanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid flowing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid flowing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. None of the gels tested appeared to alter alkaline-surfactant-polymer solution oil recovery. Total waterflood plus chemical flood oil recovery sequence recoveries were all similar. Chromium acetate-polyacrylamide gel used to seal fractured core maintain fracture closure if followed by an alkaline-surfactant-polymer solution. Chromium acetate gels that were stable to injection of alkaline-surfactant-polymer solutions at 72 F were stable to injection of alkaline-surfactant-polymer solutions at 125 F and 175 F in linear corefloods. Chromium acetate-polyacrylamide gels maintained diversion capability after injection of an alkaline-surfactant-polymer solution in stacked; radial coreflood with a common well bore. Xanthan gum-chromium acetate gels maintained gel integrity in linear corefloods after injection of an alkaline-surfactant-polymer solution at 125 F. At 175 F, Xanthan gum-chromium acetate gels were not stable either with or without subsequent alkaline-surfactant-polymer solution injection. Numerical simulation demonstrated that reducing the permeability of a high permeability zone of a reservoir with gel improved both waterflood and alkaline-surfactant-polymer flood oil recovery. A Minnelusa reservoir with both A and B sand production was simulated. A and B sands are separated by a shale layer. A sand and B sand waterflood oil recovery was improved by 196,000 bbls when a gel was placed in the B sand. A sand and B sand alkaline-surfactant-polymer flood oil recovery was improved by 596,000 bbls when a gel was placed in the B sand. Alkaline-surfactant-polymer flood oil recovery improvement over a waterflood was 392,000 bbls. Placing a gel into the B sand prior to an alkaline-surfactant-polymer flood resulted in 989,000 bbl more oil than only water injection.

  16. May 15, 2014 Methane Hydrates Committee Meeting Agenda | Department...

    Office of Environmental Management (EM)

    May 15, 2014 Methane Hydrates Committee Meeting Agenda May 15, 2014 Methane Hydrates Committee Meeting Agenda May 15, 2014 Methane Hydrates Committee Meeting Agenda PDF icon...

  17. Methane Hydrate Advisory Committee Meeting Minutes, March 2010...

    Energy Savers [EERE]

    March 2010 Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane Hydrate Advisory Committee Meeting Minutes March 2010 Washington, DC PDF icon Methane Hydrate...

  18. Methane Hydrate Advisory Committee Meeting Minutes, June 6th...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee...

  19. Results from DOE Expedition Confirm Existence of Resource-Quality Gas Hydrate in Gulf of Mexico

    Broader source: Energy.gov [DOE]

    Gas hydrate, a potentially immense energy resource, occurs at high saturations within reservoir-quality sands in the Gulf of Mexico, according to reports released by the Office of Fossil Energy's National Energy Technology Laboratory.

  20. DOE Expedition Discovers the First Gulf of Mexico Resource-Quality Gas Hydrate Deposits

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has established that gas hydrate can and does occur at high saturations within reservoir-quality sands in the Gulf of Mexico.

  1. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2015

    Fuel Cell Technologies Publication and Product Library (EERE)

    This FY 2015 report updates the results of an effort to identify and document the commercial and emerging (projected to be commercialized within the next 3 to 5 years) hydrogen and fuel cell technolog

  2. Biofuels Fuels Technology Pathway Options for Advanced Drop-in Biofuels Production

    SciTech Connect (OSTI)

    Kevin L Kenney

    2011-09-01

    Advanced drop-in hydrocarbon biofuels require biofuel alternatives for refinery products other than gasoline. Candidate biofuels must have performance characteristics equivalent to conventional petroleum-based fuels. The technology pathways for biofuel alternatives also must be plausible, sustainable (e.g., positive energy balance, environmentally benign, etc.), and demonstrate a reasonable pathway to economic viability and end-user affordability. Viable biofuels technology pathways must address feedstock production and environmental issues through to the fuel or chemical end products. Potential end products include compatible replacement fuel products (e.g., gasoline, diesel, and JP8 and JP5 jet fuel) and other petroleum products or chemicals typically produced from a barrel of crude. Considering the complexity and technology diversity of a complete biofuels supply chain, no single entity or technology provider is capable of addressing in depth all aspects of any given pathway; however, all the necessary expert entities exist. As such, we propose the assembly of a team capable of conducting an in-depth technology pathway options analysis (including sustainability indicators and complete LCA) to identify and define the domestic biofuel pathways for a Green Fleet. This team is not only capable of conducting in-depth analyses on technology pathways, but collectively they are able to trouble shoot and/or engineer solutions that would give industrial technology providers the highest potential for success. Such a team would provide the greatest possible down-side protection for high-risk advanced drop-in biofuels procurement(s).

  3. Studies of Reaction Kinetics of Methane Hydrate Dissocation in Porous Media

    SciTech Connect (OSTI)

    Moridis, George J.; Seol, Yongkoo; Kneafsey, Timothy J.

    2005-03-10

    The objective of this study is the description of the kinetic dissociation of CH4-hydrates in porous media, and the determination of the corresponding kinetic parameters. Knowledge of the kinetic dissociation behavior of hydrates can play a critical role in the evaluation of gas production potential of gas hydrate accumulations in geologic media. We analyzed data from a sequence of tests of CH4-hydrate dissociation by means of thermal stimulation. These tests had been conducted on sand cores partially saturated with water, hydrate and CH4 gas, and contained in an x-ray-transparent aluminum pressure vessel. The pressure, volume of released gas, and temperature (at several locations within the cores) were measured. To avoid misinterpreting local changes as global processes, x-ray computed tomography scans provided accurate images of the location and movement of the reaction interface during the course of the experiments. Analysis of the data by means of inverse modeling (history matching ) provided estimates of the thermal properties and of the kinetic parameters of the hydration reaction in porous media. Comparison of the results from the hydrate-bearing porous media cores to those from pure CH4-hydrate samples provided a measure of the effect of the porous medium on the kinetic reaction. A tentative model of composite thermal conductivity of hydrate-bearing media was also developed.

  4. New Technologies that Enhance Environmental Protection, Increase Domestic Production, Result from DOE-Supported Consortium

    Broader source: Energy.gov [DOE]

    New technologies that help small, independent oil and natural gas operators contribute to domestic energy production while improving environmental protection have resulted from U.S. Department of Energy support of the Stripper Well Consortium.

  5. Large-Scale Pyrolysis Oil Production: A Technology Assessment and Economic Analysis

    SciTech Connect (OSTI)

    Ringer, M.; Putsche, V.; Scahill, J.

    2006-11-01

    A broad perspective of pyrolysis technology as it relates to converting biomass substrates to a liquid bio-oil product and a detailed technical and economic assessment of a fast pyrolysis plant.

  6. Response of oceanic hydrate-bearing sediments to thermalstresses

    SciTech Connect (OSTI)

    Moridis, G.J.; Kowalsky, M.B.

    2006-05-01

    In this study, we evaluate the response of oceanicsubsurface systems to thermal stresses caused by the flow of warm fluidsthrough noninsulated well systems crossing hydrate-bearing sediments.Heat transport from warm fluids, originating from deeper reservoirs underproduction, into the geologic media can cause dissociation of the gashydrates. The objective of this study is to determine whether gasevolution from hydrate dissociation can lead to excessive pressurebuildup, and possibly to fracturing of hydrate-bearing formations andtheir confining layers, with potentially adverse consequences on thestability of the suboceanic subsurface. This study also aims to determinewhether the loss of the hydrate--known to have a strong cementing effecton the porous media--in the vicinity of the well, coupled with thesignificant pressure increases, can undermine the structural stability ofthe well assembly.Scoping 1D simulations indicated that the formationintrinsic permeability, the pore compressibility, the temperature of theproduced fluids andthe initial hydrate saturation are the most importantfactors affecting the system response, while the thermal conductivity andporosity (above a certain level) appear to have a secondary effect.Large-scale simulations of realistic systems were also conducted,involving complex well designs and multilayered geologic media withnonuniform distribution of properties and initial hydrate saturationsthat are typical of those expected in natural oceanic systems. Theresults of the 2D study indicate that although the dissociation radiusremains rather limited even after long-term production, low intrinsicpermeability and/or high hydrate saturation can lead to the evolution ofhigh pressures that can threaten the formation and its boundaries withfracturing. Although lower maximum pressures are observed in the absenceof bottom confining layers and in deeper (and thus warmer and morepressurized) systems, the reduction is limited. Wellbore designs withgravel packs that allow gas venting and pressure relief result insubstantially lower pressures.

  7. Conversion Technologies for Advanced Biofuels … Carbohydrates Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Report-Out Webinar February 9, 2012 Mike Ladisch, Ph.D. Purdue University Energy Efficiency & Renewable Energy eere.energy.gov 2 Michael R. Ladisch Distinguished Professor and Director Department of Agricultural and Biological Engineering Laboratory of Renewable Resources Engineering http://engineering.purdue.edu/LORRE CTO, Mascoma Corporation http://www.mascoma.com 1978 - present, Professor at Purdue University; 2007 - present, CTO Mascoma Corporation B.S.ChE, Chemical Engineer,

  8. Nanotechnology for the Forest Products Industry Vision and Technology Roadmap

    SciTech Connect (OSTI)

    Atalla, Rajai; Beecher, James; Caron, Robert; Catchmark, Jeffrey; Deng, Yulin; Glasser, Wolfgang; Gray, Derek; Haigler, Candace; Jones, Philip; Joyce, Margaret; Kohlman, Jane; Koukoulas, Alexander; Lancaster, Peter; Perine, Lori; Rodriguez, Augusto; Ragauskas, Arthur; Wegner, Theodore; Zhu, Junyong

    2005-03-01

    A roadmap for Nanotechnology in the Forest Products Industries has been developed under the umbrella of the Agenda 2020 program overseen by the CTO committee. It is expected that the use of new analytical techniques and methodologies will allow us to understand the complex nature of wood based materials and allow the dramatically enhanced use of the major strategic asset the US has in renewable, recyclable resources based on its well managed Forests.

  9. MethaneHydrateRD_FC.indd

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FOSSIL ENERGY RESEARCH BENEFITS Methane Hydrate R&D "The (DOE) Program has supported and ... The Nati onal Academies 2010 One of these is methane hydrate - molecules of natural gas ...

  10. Natural Gas Hydrates Update 1998-2000

    Reports and Publications (EIA)

    2001-01-01

    Significant events have transpired on the natural gas hydrate research and development front since "Future Supply Potential of Natural Gas Hydrates" appeared in Natural Gas 1998 Issues and Trends and in the Potential Gas Committee's 1998 biennial report.

  11. METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy Advisory Committee Charter - - - - ---- ---- ------ 1. Committee's Official Designation. Methane Hydrate Advisory...

  12. Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates

    SciTech Connect (OSTI)

    Kwon, T.H.; Kneafsey, T.J.; Rees, E.V.L.

    2011-02-15

    Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO{sub 2}) and/or production of methane (CH{sub 4}) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH{sub 4} and CO{sub 2} hydrate (CH{sub 4}-CO{sub 2} mixed hydrates), as well as thermophysical property changes during gas exchange. This study explores the thermal dissociation behavior and dissociation enthalpies of CH{sub 4}-CO{sub 2} mixed hydrates. We prepared CH{sub 4}-CO{sub 2} mixed hydrate samples from two different, well-defined gas mixtures. During thermal dissociation of a CH{sub 4}-CO{sub 2} mixed hydrate sample, gas samples from the head space were periodically collected and analyzed using gas chromatography. The changes in CH{sub 4}-CO{sub 2} compositions in both the vapor phase and hydrate phase during dissociation were estimated based on the gas chromatography measurements. It was found that the CO{sub 2} concentration in the vapor phase became richer during dissociation because the initial hydrate composition contained relatively more CO{sub 2} than the vapor phase. The composition change in the vapor phase during hydrate dissociation affected the dissociation pressure and temperature; the richer CO{sub 2} in the vapor phase led to a lower dissociation pressure. Furthermore, the increase in CO{sub 2} concentration in the vapor phase enriched the hydrate in CO{sub 2}. The dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate was computed by fitting the Clausius-Clapeyron equation to the pressure-temperature (PT) trace of a dissociation test. It was observed that the dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate lays between the limiting values of pure CH{sub 4} hydrate and CO{sub 2} hydrate, increasing with the CO{sub 2} fraction in the hydrate phase.

  13. New Natural Gas Storage and Transportation Capabilities Utilizing Rapid Methane Hydrate Formation Techniques

    SciTech Connect (OSTI)

    Brown, T.D.; Taylor, C.E.; Bernardo, M.

    2010-01-01

    Natural gas (methane as the major component) is a vital fossil fuel for the United States and around the world. One of the problems with some of this natural gas is that it is in remote areas where there is little or no local use for the gas. Nearly 50 percent worldwide natural gas reserves of ~6,254.4 trillion ft3 (tcf) is considered as stranded gas, with 36 percent or ~86 tcf of the U.S natural gas reserves totaling ~239 tcf, as stranded gas [1] [2]. The worldwide total does not include the new estimates by U.S. Geological Survey of 1,669 tcf of natural gas north of the Arctic Circle, [3] and the U.S. ~200,000 tcf of natural gas or methane hydrates, most of which are stranded gas reserves. Domestically and globally there is a need for newer and more economic storage, transportation and processing capabilities to deliver the natural gas to markets. In order to bring this resource to market, one of several expensive methods must be used: 1. Construction and operation of a natural gas pipeline 2. Construction of a storage and compression facility to compress the natural gas (CNG) at 3,000 to 3,600 psi, increasing its energy density to a point where it is more economical to ship, or 3. Construction of a cryogenic liquefaction facility to produce LNG, (requiring cryogenic temperatures at <-161 C) and construction of a cryogenic receiving port. Each of these options for the transport requires large capital investment along with elaborate safety systems. The Department of Energy's Office of Research and Development Laboratories at the National Energy Technology Laboratory (NETL) is investigating new and novel approaches for rapid and continuous formation and production of synthetic NGHs. These synthetic hydrates can store up to 164 times their volume in gas while being maintained at 1 atmosphere and between -10 to -20C for several weeks. Owing to these properties, new process for the economic storage and transportation of these synthetic hydrates could be envisioned for stranded gas reserves. The recent experiments and their results from the testing within NETL's 15-Liter Hydrate Cell Facility exhibit promising results. Introduction of water at the desired temperature and pressure through an NETL designed nozzle into a temperature controlled methane environment within the 15-Liter Hydrate Cell allowed for instantaneous formation of methane hydrates. The instantaneous and continuous hydrate formation process was repeated over several days while varying the flow rate of water, its' temperature, and the overall temperature of the methane environment. These results clearly indicated that hydrates formed immediately after the methane and water left the nozzle at temperatures above the freezing point of water throughout the range of operating conditions. [1] Oil and Gas Journal Vol. 160.48, Dec 22, 2008. [2] http://www.eia.doe.gov/oiaf/servicerpt/natgas/chapter3.html and http://www.eia.doe.gov/oiaf/servicerpt/natgas/pdf/tbl7.pdf [3] U.S. Geological Survey, Circum-Arctic Resource Appraisal: Estimates of Undiscovered Oil and Gas North of the Arctic Circle, May 2008.

  14. Hydrates_Annual _FY13 Format

    Office of Scientific and Technical Information (OSTI)

    Natural Gas Hydrate Research Fiscal Year 2012, Quarter 2 Progress Report AR Carbon Capture Simulation Initiative (CCSI) January 1, 2012 - March 31, 2012 FWP Number 2012.04.02 Natural Gas Hydrate Research Natural Gas Hydrate Research Annual Report: Natural Gas Hydrate Research 30 September 2013 NETL Technical Report Series Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof,

  15. Natural Gas Hydrates Update 2000-2002

    Reports and Publications (EIA)

    2003-01-01

    Natural gas hydrates research and development (R&D) activity expanded significantly during the 2000-2002.

  16. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    2006-08-15

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  17. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson

    2004-10-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency for those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or those with thief zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. A prior fluid-fluid report discussed interaction of different gel chemical compositions and alkaline-surfactant-polymer solutions. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses. Aluminum-polyacrylamide, flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9. Chromium acetate-polyacrylamide flowing and rigid flowing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid flowing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Neither aluminum citrate-polyacrylamide nor silicate-polyacrylamide gel systems produced significant incremental oil in linear corefloods. Both flowing and rigid flowing chromium acetate-polyacrylamide gels produced incremental oil with the rigid flowing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. None of the gels tested appeared to alter alkaline-surfactant-polymer solution oil recovery. Total waterflood plus chemical flood oil recovery sequence recoveries were all similar.

  18. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qui; Dan Wilson; Phil Dowling

    2004-05-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding in the swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to the naturally fractured reservoirs or those with thief zones because much of the injected solution bypasses the target pore space containing oil. The objective of this work is to investigate whether combining these two technologies could broaden the applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium--polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values of 9.2 to 12.9.

  19. Methane Hydrate Advisory Committee Charter | Department of Energy

    Energy Savers [EERE]

    Charter Methane Hydrate Advisory Committee Charter Methane Hydrate Advisory Committee Charter PDF icon Methane Hydrate Advisory Committee Charter More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane Hydrate Advisory Committee Meeting Minutes, January 2010 Methane Hydrate Advisory Committee Meeting Minutes, October 2011

  20. Development and production of two explosive components using SCB technology

    SciTech Connect (OSTI)

    Tarbell, W.W.; Sanchez, D.H.; Oestreich, M.L.; Prentice, J.W.

    1995-05-01

    For many years, explosive components have used hotwires to convert an electrical stimulus into the thermal energy required to initiate the device. A Semi-Conductor Bridge (SCB) performs the same function, but with the advantage of requiring approximately 1/10 the input energy of a comparable hotwire, while retaining excellent no-fire characteristics. The SCB also demonstrates faster function times due to its inherently-lower thermal mass. This paper discusses the development and production of two SCB-based devices, the MC4491 Initiator and the MC4492 Actuator. The initiator is designed to shock initiate a linear shaped charge by accelerating a thin metal plate across a small gap. The actuator functions several different components, serving as either an actuator by producing a rapidly expanding gas to activate piston mechanisms or as an ignitor by providing hot particles for initiating pyrotechnic mixtures. Details are provided on the construction of both devices, methods of assembly, and performance characteristics (function time, flyer velocity, pressure in a closed bomb, heat content, and no-fire and all-fire levels).

  1. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; David Stewart; Bill Jones

    2005-04-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency for those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or those with thief zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. A prior fluid-fluid report discussed interaction of different gel chemical compositions and alkaline-surfactant-polymer solutions. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses. Aluminum-polyacrylamide, flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9. Chromium acetate-polyacrylamide flowing and rigid flowing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid flowing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Chromium acetate-xanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid flowing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid flowing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. None of the gels tested appeared to alter alkaline-surfactant-polymer solution oil recovery. Total waterflood plus chemical flood oil recovery sequence recoveries were all similar.

  2. Modeling pure methane hydrate dissociation using a numerical simulator from a novel combination of X-ray computed tomography and macroscopic data

    SciTech Connect (OSTI)

    Gupta, A.; Moridis, G.J.; Kneafsey, T.J.; Sloan, Jr., E.D.

    2009-08-15

    The numerical simulator TOUGH+HYDRATE (T+H) was used to predict the transient pure methane hydrate (no sediment) dissociation data. X-ray computed tomography (CT) was used to visualize the methane hydrate formation and dissociation processes. A methane hydrate sample was formed from granular ice in a cylindrical vessel, and slow depressurization combined with thermal stimulation was applied to dissociate the hydrate sample. CT images showed that the water produced from the hydrate dissociation accumulated at the bottom of the vessel and increased the hydrate dissociation rate there. CT images were obtained during hydrate dissociation to confirm the radial dissociation of the hydrate sample. This radial dissociation process has implications for dissociation of hydrates in pipelines, suggesting lower dissociation times than for longitudinal dissociation. These observations were also confirmed by the numerical simulator predictions, which were in good agreement with the measured thermal data during hydrate dissociation. System pressure and sample temperature measured at the sample center followed the CH{sub 4} hydrate L{sub w}+H+V equilibrium line during hydrate dissociation. The predicted cumulative methane gas production was within 5% of the measured data. Thus, this study validated our simulation approach and assumptions, which include stationary pure methane hydrate-skeleton, equilibrium hydrate-dissociation and heat- and mass-transfer in predicting hydrate dissociation in the absence of sediments. It should be noted that the application of T+H for the pure methane hydrate system (no sediment) is outside the general applicability limits of T+H.

  3. U.S. and Japan Complete Successful Field Trial of Methane Hydrate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... This test was the first ever field trial of a methane hydrate production methodology ... The next stages of the Department's research effort will be aimed in part at evaluating ...

  4. Comparison of kinetic and equilibrium reaction models insimulating gas hydrate behavior in porous media

    SciTech Connect (OSTI)

    Kowalsky, Michael B.; Moridis, George J.

    2006-11-29

    In this study we compare the use of kinetic and equilibriumreaction models in the simulation of gas (methane) hydrate behavior inporous media. Our objective is to evaluate through numerical simulationthe importance of employing kinetic versus equilibrium reaction modelsfor predicting the response of hydrate-bearing systems to externalstimuli, such as changes in pressure and temperature. Specifically, we(1) analyze and compare the responses simulated using both reactionmodels for natural gas production from hydrates in various settings andfor the case of depressurization in a hydrate-bearing core duringextraction; and (2) examine the sensitivity to factors such as initialhydrate saturation, hydrate reaction surface area, and numericaldiscretization. We find that for large-scale systems undergoing thermalstimulation and depressurization, the calculated responses for bothreaction models are remarkably similar, though some differences areobserved at early times. However, for modeling short-term processes, suchas the rapid recovery of a hydrate-bearing core, kinetic limitations canbe important, and neglecting them may lead to significantunder-prediction of recoverable hydrate. The use of the equilibriumreaction model often appears to be justified and preferred for simulatingthe behavior of gas hydrates, given that the computational demands forthe kinetic reaction model far exceed those for the equilibrium reactionmodel.

  5. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    SciTech Connect (OSTI)

    Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

    2009-07-15

    A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

  6. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or reservoirs with different sand lenses with high permeability contrast. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more crude oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or reservoirs with high permeability contrast zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium-polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses with the exception of the xanthan gum-chromium acetate gels. Aluminum-polyacrylamide flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9, either in linear corefloods or in dual separate radial core, common manifold corefloods. Chromium acetate-polyacrylamide flowing and rigid tonguing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid tonguing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Chromium acetate gels were stable to injection of alkaline-surfactant-polymer solutions at 72 F, 125 F and 175 F in linear corefloods. Chromium acetate-polyacrylamide gels maintained diversion capability after injection of an alkaline-surfactant-polymer solution in stacked; radial coreflood with a common well bore. Chromium acetate-polyacrylamide gel used to seal fractured core maintain fracture closure if followed by an alkaline-surfactant-polymer solution. Chromium acetatexanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection at 72, 125, and 175 F. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid tonguing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid tonguing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. Aluminum citrate-polyacrylamide gels, chromium acetate-polyacrylamide gels, silicate-polymer, and chromium-xanthan gum gels did not alter an alkaline-surfactant-polymer solution's ability to produce incremental oil. Incremental oil was reduced with the resorcinol-formaldehyde gel system. Total waterflood plus chemical flood oil recovery sequence recoveries were generally similar. Performance and produced polymer evaluation of four alkaline-surfactant-polymer projects concluded that only one of the projects could have benefited from combining the alkaline-surfactant-polymer and gelation technologies. Cambridge, the 1993 Daqing, Mellott Ranch, and the Wardlaw alkaline-surfacant-polymer floods were studied. An initial gel treatment followed by an alkaline-surfactant-polymer flood in the Wardlaw field would have been a benefit due to reduction of fracture flow.

  7. Development of Alaskan gas hydrate resources: Annual report, October 1986--September 1987

    SciTech Connect (OSTI)

    Sharma, G.D.; Kamath, V.A.; Godbole, S.P.; Patil, S.L.; Paranjpe, S.G.; Mutalik, P.N.; Nadem, N.

    1987-10-01

    Solid ice-like mixtures of natural gas and water in the form of natural gas hydrated have been found immobilized in the rocks beneath the permafrost in Arctic basins and in muds under the deep water along the American continental margins, in the North Sea and several other locations around the world. It is estimated that the arctic areas of the United States may contain as much as 500 trillion SCF of natural gas in the form of gas hydrates (Lewin and Associates, 1983). While the US Arctic gas hydrate resources may have enormous potential and represent long term future source of natural gas, the recovery of this resource from reservoir frozen with gas hydrates has not been commercialized yet. Continuing study and research is essential to develop technologies which will enable a detailed characterization and assessment of this alternative natural gas resource, so that development of cost effective extraction technology.

  8. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over several years, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana.

  9. Coupling the Alkaline-Surfactant-Polymer Technology and the Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or reservoirs with different sand lenses with high permeability contrast. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more crude oil than waterflooding froin swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or reservoirs with high permeability contrast zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium-polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses with the exception of the xanthan gum-chromium acetate gels. Aluminum-polyacrylamide flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9, either in linear corefloods or in dual separate radial core, common manifold corefloods. Chromium acetate-polyacrylamide flowing and rigid tonguing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid tonguing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Chromium acetate gels were stable to injection of alkaline-surfactant-polymer solutions at 72 F, 125 F and 175 F in linear corefloods. Chromium acetate-polyacrylamide gels maintained diversion capability after injection of an alkaline-surfactant-polymer solution in stacked; radial coreflood with a common well bore. Chromium acetate-polyacrylamide gel used to seal fractured core maintain fracture closure if followed by an alkaline-surfactant-polymer solution. Chromium acetate-xanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection at 72, 125, and 175 F. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid tonguing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid tonguing gel producing the greatest amount. Higher oil recovery could have been due to higher differentia

  10. HYDRATE RESEARCH ACTIVITIES THAT BOTH SUPPORT AND DERIVE FROM THE MONITORING STATION/SEA-FLOOR OBSERVATORY, MISSISSIPPI CANYON 118, NORTHERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Lutken, Carol

    2013-07-31

    A permanent observatory has been installed on the seafloor at Federal Lease Block, Mississippi Canyon 118 (MC118), northern Gulf of Mexico. Researched and designed by the Gulf of Mexico Hydrates Research Consortium (GOM-HRC) with the geological, geophysical, geochemical and biological characterization of in situ gas hydrates systems as the research goal, the site has been designated by the Bureau of Ocean Energy Management as a permanent Research Reserve where studies of hydrates and related ocean systems may take place continuously and cooperatively into the foreseeable future. The predominant seafloor feature at MC118 is a carbonate-hydrate complex, officially named Woolsey Mound for the founder of both the GOM-HRC and the concept of the permanent seafloor hydrates research facility, the late James Robert “Bob” Woolsey. As primary investigator of the overall project until his death in mid-2008, Woolsey provided key scientific input and served as chief administrator for the Monitoring Station/ Seafloor Observatory (MS-SFO). This final technical report presents highlights of research and accomplishments to date. Although not all projects reached the status originally envisioned, they are all either complete or positioned for completion at the earliest opportunity. All Department of Energy funds have been exhausted in this effort but, in addition, leveraged to great advantage with additional federal input to the project and matched efforts and resources. This report contains final reports on all subcontracts issued by the University of Mississippi, Administrators of the project, Hydrate research activities that both support and derive from the monitoring station/sea-floor Observatory, Mississippi Canyon 118, northern Gulf of Mexico, as well as status reports on the major components of the project. All subcontractors have fulfilled their primary obligations. Without continued funds designated for further project development, the Monitoring Station/Seafloor Observatory is in danger of lapsing into disuse. However, for the present, interest in the site on the continental slope is healthy and The Center for Marine Resources and Environmental Technology continues to coordinate all activity at the MS/SFO as arranged through the BOEM in 2005. Field and laboratory research projects and findings are reviewed, new technologies and tests described. Many new sensors, systems and two custom ROVs have been developed specifically for this project. Characteristics of marine gas hydrates are dramatically more refined than when the project was initiated and include appear in sections entitled Accomplishments, Products and Publications.

  11. Advancing Commercialization of Algal Biofuels Through Increased Biomass Productivity and Technology Integration

    SciTech Connect (OSTI)

    Bai, Xuemei; Sabarsky, Martin

    2013-09-30

    Cellana is a leading developer of algae-based bioproducts, and its pre-commercial production of marine microalgae takes place at Cellana?s Kona Demonstration Facility (KDF) in Hawaii. KDF is housing more than 70 high-performing algal strains for different bioproducts, of which over 30 have been grown outside at scale. So far, Cellana has produced more than 10 metric tons of algal biomass for the development of biofuels, animal feed, and high-value nutraceuticals. Cellana?s ALDUO algal cultivation technology allows Cellana to grow non-extremophile algal strains at large scale with no contamination disruptions. Cellana?s research and production at KDF have addressed three major areas that are crucial for the commercialization of algal biofuels: yield improvement, cost reduction, and the overall economics. Commercially acceptable solutions have been developed and tested for major factors limiting areal productivity of algal biomass and lipids based on years of R&D work conducted at KDF. Improved biomass and lipid productivity were achieved through strain improvement, culture management strategies (e.g., alleviation of self-shading, de-oxygenation, and efficient CO2 delivery), and technical advancement in downstream harvesting technology. Cost reduction was achieved through optimized CO2 delivery system, flue gas utilization technology, and energy-efficient harvesting technology. Improved overall economics was achieved through a holistic approach by integration of high-value co-products in the process, in addition to yield improvements and cost reductions.

  12. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, Mark P. (Knoxville, TN); Kedl, Robert J. (Oak Ridge, TN)

    1985-01-01

    This invention is a process for formation of a gas hydrate to be used as a cool storage medium using a refrigerant in water. Mixing of the immiscible refrigerant and water is effected by addition of a surfactant and agitation. The difficult problem of subcooling during the process is overcome by using the surfactant and agitation and performance of the process significantly improves and approaches ideal.

  13. Multiple stage multiple filter hydrate store

    DOE Patents [OSTI]

    Bjorkman, Jr., Harry K.

    1983-05-31

    An improved hydrate store for a metal halogen battery system is disclosed which employs a multiple stage, multiple filter means or separating the halogen hydrate from the liquid used in forming the hydrate. The filter means is constructed in the form of three separate sections which combine to substantially cover the interior surface of the store container. Exit conduit means is provided in association with the filter means for transmitting liquid passing through the filter means to a hydrate former subsystem. The hydrate former subsystem combines the halogen gas generated during the charging of the battery system with the liquid to form the hydrate in association with the store. Relief valve means is interposed in the exit conduit means for controlling the operation of the separate sections of the filter means, such that the liquid flow through the exit conduit means from each of the separate sections is controlled in a predetermined sequence. The three separate sections of the filter means operate in three discrete stages to provide a substantially uniform liquid flow to the hydrate former subsystem during the charging of the battery system. The separation of the liquid from the hydrate causes an increase in the density of the hydrate by concentrating the hydrate along the filter means.

  14. Multiple stage multiple filter hydrate store

    DOE Patents [OSTI]

    Bjorkman, H.K. Jr.

    1983-05-31

    An improved hydrate store for a metal halogen battery system is disclosed which employs a multiple stage, multiple filter means for separating the halogen hydrate from the liquid used in forming the hydrate. The filter means is constructed in the form of three separate sections which combine to substantially cover the interior surface of the store container. Exit conduit means is provided in association with the filter means for transmitting liquid passing through the filter means to a hydrate former subsystem. The hydrate former subsystem combines the halogen gas generated during the charging of the battery system with the liquid to form the hydrate in association with the store. Relief valve means is interposed in the exit conduit means for controlling the operation of the separate sections of the filter means, such that the liquid flow through the exit conduit means from each of the separate sections is controlled in a predetermined sequence. The three separate sections of the filter means operate in three discrete stages to provide a substantially uniform liquid flow to the hydrate former subsystem during the charging of the battery system. The separation of the liquid from the hydrate causes an increase in the density of the hydrate by concentrating the hydrate along the filter means. 7 figs.

  15. High Temperature Electrolysis for Hydrogen Production from Nuclear Energy – TechnologySummary

    SciTech Connect (OSTI)

    J. E. O'Brien; C. M. Stoots; J. S. Herring; M. G. McKellar; E. A. Harvego; M. S. Sohal; K. G. Condie

    2010-02-01

    The Department of Energy, Office of Nuclear Energy, has requested that a Hydrogen Technology Down-Selection be performed to identify the hydrogen production technology that has the best potential for timely commercial demonstration and for ultimate deployment with the Next Generation Nuclear Plant (NGNP). An Independent Review Team has been assembled to execute the down-selection. This report has been prepared to provide the members of the Independent Review Team with detailed background information on the High Temperature Electrolysis (HTE) process, hardware, and state of the art. The Idaho National Laboratory has been serving as the lead lab for HTE research and development under the Nuclear Hydrogen Initiative. The INL HTE program has included small-scale experiments, detailed computational modeling, system modeling, and technology demonstration. Aspects of all of these activities are included in this report. In terms of technology demonstration, the INL successfully completed a 1000-hour test of the HTE Integrated Laboratory Scale (ILS) technology demonstration experiment during the fall of 2008. The HTE ILS achieved a hydrogen production rate in excess of 5.7 Nm3/hr, with a power consumption of 18 kW. This hydrogen production rate is far larger than has been demonstrated by any of the thermochemical or hybrid processes to date.

  16. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Thomas Lynch

    2004-01-07

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead previously by Gasification Engineering Corporation (GEC). The project is now under the leadership of ConocoPhillips Company (COP) after it acquired GEC and the E-Gas{trademark} gasification technology from Global Energy in July 2003. The Phase I of this project was supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while the Phase II is supported by Gas Technology Institute, TDA Research, Inc., and Nucon International, Inc. The two project phases planned for execution include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and now COP and the industrial partners are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  17. Multi-property characterization chamber for geophysical-hydrological investigations of hydrate bearing sediments

    SciTech Connect (OSTI)

    Seol, Yongkoo Choi, Jeong-Hoon; Dai, Sheng

    2014-08-01

    With the increase in the interest of producing natural gas from methane hydrates as well as potential risks of massive hydrate dissociation in the context of global warming, studies have recently shifted from pure hydrate crystals to hydrates in sediments. Such a research focus shift requires a series of innovative laboratory devices that are capable of investigating various properties of hydrate-bearing sediments (HBS). This study introduces a newly developed high pressure testing chamber, i.e., multi-property characterization chamber (MPCC), that allows simultaneous investigation of a series of fundamental properties of HBS, including small-strain stiffness (i.e., P- and S-waves), shear strength, large-strain deformation, stress-volume responses, and permeability. The peripheral coolant circulation system of the MPCC permits stable and accurate temperature control, while the core holder body, made of aluminum, enables X-ray computer tomography scanning to be easily employed for structural and morphological characterization of specimens. Samples of hydrate-bearing sediments are held within a rubber sleeve inside the chamber. The thick sleeve is more durable and versatile than thin membranes while also being much softer than oedometer-type chambers that are incapable of enabling flow tests. Bias introduced by the rubber sleeve during large deformation tests are also calibrated both theoretically and experimentally. This system provides insight into full characterization of hydrate-bearing sediments in the laboratory, as well as pressure core technology in the field.

  18. Review of AVLIS technology for production-scale LIS systems and construction

    SciTech Connect (OSTI)

    Davis, J.I.; Moses, E.I.

    1983-12-01

    The use of lasers for uranium and/or plutonium isotope separation is expected to be the first application of lasers utilizing specific atomic processes for large-scale materials processing. Specific accomplishments toward the development of production-scale technology for LIS systems will be presented, along with the status of major construction projects. 24 figures.

  19. Scientific Objectives of the Gulf of Mexico Gas Hydrate JIP Leg II Drilling

    SciTech Connect (OSTI)

    Jones, E.; Latham, T.; McConnell, D.; Frye, M.; Hunt, J.; Shedd, W.; Shelander, D.; Boswell, R.M.; Rose, K.K.; Ruppel, C.; Hutchinson, D.; Collett, T.; Dugan, B.; Wood, W.

    2008-05-01

    The Gulf of Mexico Methane Hydrate Joint Industry Project (JIP) has been performing research on marine gas hydrates since 2001 and is sponsored by both the JIP members and the U.S. Department of Energy. In 2005, the JIP drilled the Atwater Valley and Keathley Canyon exploration blocks in the Gulf of Mexico to acquire downhole logs and recover cores in silt- and clay-dominated sediments interpreted to contain gas hydrate based on analysis of existing 3-D seismic data prior to drilling. The new 2007-2009 phase of logging and coring, which is described in this paper, will concentrate on gas hydrate-bearing sands in the Alaminos Canyon, Green Canyon, and Walker Ridge protraction areas. Locations were selected to target higher permeability, coarser-grained lithologies (e.g., sands) that have the potential for hosting high saturations of gas hydrate and to assist the U.S. Minerals Management Service with its assessment of gas hydrate resources in the Gulf of Mexico. This paper discusses the scientific objectives for drilling during the upcoming campaign and presents the results from analyzing existing seismic and well log data as part of the site selection process. Alaminos Canyon 818 has the most complete data set of the selected blocks, with both seismic data and comprehensive downhole log data consistent with the occurrence of gas hydrate-bearing sands. Preliminary analyses suggest that the Frio sandstone just above the base of the gas hydrate stability zone may have up to 80% of the available sediment pore space occupied by gas hydrate. The proposed sites in the Green Canyon and Walker Ridge areas are also interpreted to have gas hydrate-bearing sands near the base of the gas hydrate stability zone, but the choice of specific drill sites is not yet complete. The Green Canyon site coincides with a 4-way closure within a Pleistocene sand unit in an area of strong gas flux just south of the Sigsbee Escarpment. The Walker Ridge site is characterized by a sand-prone sedimentary section that rises stratigraphically across the base of the gas hydrate stability zone and that has seismic indicators of gas hydrate. Copyright 2008, Offshore Technology Conference

  20. Methane Hydrate Program Annual Report to Congress

    Energy Savers [EERE]

    FY 2010 Methane Hydrate Program Annual Report to Congress September 2011 U.S. Department of ENERGY United States Department of Energy Washington, DC 20585 Department of Energy | September 2011 FY 2010 Methane Hydrate Program Annual Report to Congress | Page 2 Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report

  1. MethaneHydrateRD_FC.indd

    Energy Savers [EERE]

    Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 PDF icon Methane Hydrate Research and Development Act of 2000 More Documents & Publications NATIONAL DEFENSE AUTHORIZATION ACT FOR FISCAL YEAR 2000 E:\PUBLAW\PUBL404.106 Intelligence Reform and Terrorism Prevention Act - December 17, 200

    gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The

  2. Productivity genefits from new energy technology: A case study of a paint manufacturing company

    SciTech Connect (OSTI)

    Raghunathan, P.; Capehart, B.L.

    1997-06-01

    In many cases, implementing new energy efficiency technologies not only helps facilities reduce their energy costs, but it also creates greater profits by increasing productivity. These added benefits from productivity improvements can sometimes be greater than the energy cost savings, and can result in an attractive overall payback period for implementing the new technology. This paper presents a case study of productivity improvement at a paint manufacturing company as a result of implementing new energy efficiency technology. During an industrial energy assessment, it was noted that the company had experienced frequent failures of motor belts and sheaves on five paint mixers resulting in significant replacement costs and labor costs. In addition, a bigger loss was being suffered due to lost potential profit associated with the frequent work stoppages. The IAC recommendation was to install motor soft starters (also known as motor voltage controllers) on the five mixing machines. Installation of soft starters would have the following benefits: lower energy costs, lower replacement costs for transmission components, lower labor costs, and higher production levels and increased profits. The total annual benefits were estimated at $122,659, of which the benefits from increased productivity were nearly $67,000. The overall simple payback period for installing the soft starters was less than 2 months.

  3. Methane Hydrates R&D Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... and recommendations for future offshore drilling campaigns. * The University of Texas, ... Gulf of Mexico. * The geophysical evaluation of gas hydrates is being advanced ...

  4. Methane Hydrate Advisory Committee (MHAC) Meeting

    Broader source: Energy.gov (indexed) [DOE]

    the U.S. Department of Energy (DOE) and Designated Federal Officer (DFO) for the Methane Hydrate Advisory Committee (MHAC). She thanked members for their continued...

  5. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Gary Harmond; Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the U.S. Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. During the reporting period, various methods to remove low-level contaminants for the synthesis gas were reviewed. In addition, there was a transition of the project personnel for GEC which has slowed the production of the outstanding project reports.

  6. Large-scale production, harvest and logistics of switchgrass (Panicum virgatum L.) - current technology and envisioning a mature technology

    SciTech Connect (OSTI)

    Sokhansanj, Shahabaddine; Turhollow, Jr., Anthony; Mani, Sudhagar; Kumar, Amit; Bransby, David; Lynd, L.; Laser, Mark

    2009-03-01

    Switchgrass (Panicum virgatum L.) is a promising cellulosic biomass feedstock for biorefineries and biofuel production. This paper reviews current and future potential technologies for production, harvest, storage, and transportation of switchgrass. Our analysis indicates that for a yield of 10 Mg ha 1, the current cost of producing switchgrass (after establishment) is about $41.50 Mg 1. The costs may be reduced to about half this if the yield is increased to 30 Mg ha 1 through genetic improvement, intensive crop management, and/or optimized inputs. At a yield of 10 Mg ha 1, we estimate that harvesting costs range from $23.72 Mg 1 for current baling technology to less than $16 Mg 1 when using a loafing collection system. At yields of 20 and 30 Mg ha 1 with an improved loafing system, harvesting costs are even lower at $12.75 Mg 1 and $9.59 Mg 1, respectively. Transport costs vary depending upon yield and fraction of land under switchgrass, bulk density of biomass, and total annual demand of a biorefinery. For a 2000 Mg d 1 plant and an annual yield of 10 Mg ha 1, the transport cost is an estimated $15.42 Mg 1, assuming 25% of the land is under switchgrass production. Total delivered cost of switchgrass using current baling technology is $80.64 Mg 1, requiring an energy input of 8.5% of the feedstock higher heating value (HHV). With mature technology, for example, a large, loaf collection system, the total delivered cost is reduced to about $71.16 Mg 1 with 7.8% of the feedstock HHV required as input. Further cost reduction can be achieved by combining mature technology with increased crop productivity. Delivered cost and energy input do not vary significantly as biorefinery capacity increases from 2000 Mg d 1 to 5000 Mg d 1 because the cost of increased distance to access a larger volume feedstock offsets the gains in increased biorefinery capacity. This paper outlines possible scenarios for the expansion of switchgrass handling to 30 Tg (million Mg) in 2015 and 100 Tg in 2030 based on predicted growth of the biorefinery industry in the USA. The value of switchgrass collection operations is estimated at more than $0.6 billion in 2015 and more than $2.1 billion in 2030. The estimated value of post harvest operations is $0.6 $2.0 billion in 2015, and $2.0 $6.5 billion in 2030, depending on the degree of preprocessing. The need for power equipment (tractors) will increase from 100 MW in 2015 to 666 MW in 2030, with corresponding annual values of $150 and $520 million, respectively. 2009 Society of Chemical Industry and John Wiley & Sons, Ltd

  7. RESULTS FROM THE (1) DATA COLLECTION WORKSHOP, (2) MODELING WORKSHOP AND (3) DRILLING AND CORING METHODS WORKSHOP AS PART OF THE JOINT INDUSTRY PARTICIPATION (JIP) PROJECT TO CHARACTERIZE NATURAL GAS HYDRATES IN THE DEEPWATER GULF OF MEXICO

    SciTech Connect (OSTI)

    Stephen A. Holditch; Emrys Jones

    2002-09-01

    In 2000, Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deepwater portions of the Gulf of Mexico. A Joint Industry Participation (JIP) group was formed in 2001, and a project partially funded by the U.S. Department of Energy (DOE) began in October 2001. The primary objective of this project is to develop technology and data to assist in the characterization of naturally occurring gas hydrates in the deepwater Gulf of Mexico. These naturally occurring gas hydrates can cause problems relating to drilling and production of oil and gas, as well as building and operating pipelines. Other objectives of this project are to better understand how natural gas hydrates can affect seafloor stability, to gather data that can be used to study climate change, and to determine how the results of this project can be used to assess if and how gas hydrates act as a trapping mechanism for shallow oil or gas reservoirs. As part of the project, three workshops were held. The first was a data collection workshop, held in Houston during March 14-15, 2002. The purpose of this workshop was to find out what data exist on gas hydrates and to begin making that data available to the JIP. The second and third workshop, on Geoscience and Reservoir Modeling, and Drilling and Coring Methods, respectively, were held simultaneously in Houston during May 9-10, 2002. The Modeling Workshop was conducted to find out what data the various engineers, scientists and geoscientists want the JIP to collect in both the field and the laboratory. The Drilling and Coring workshop was to begin making plans on how we can collect the data required by the project's principal investigators.

  8. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-06-01

    This sixteenth quarterly report describes work done during the sixteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, and making and responding to several outside contacts.

  9. Lubricant oil production: The proper marriage of process and catalyst technologies

    SciTech Connect (OSTI)

    Everett, G.L.; Suchanek, A.

    1996-12-01

    As the industry moves into the next millennium, higher product quality demands to meet the higher performance needs of modern engine technology and rising costs of traditional good quality lube crudes are driving lubricant base oil manufacturers to select hydroprocessing options versus traditional solvent refining techniques. This paper discusses how to properly select the best economic hydroprocessing technology necessary to produce high quality lubricant base oils and waxes. The economic success of such operations depends on the proper combination of process and catalyst technologies that maximizes yields of high quality products with minimum consumption of hydrogen resources and process utilities. This is particular true on the extreme end of the quality spectrum, namely, Very High Viscosity Index (VHVI) base oils and food grade white oils and waxes where there is no room for marginal product quality. Multiplicity of operations is also becoming more important as refiners try to upgrade their facilities with as little capital expense as possible, while at the same time, broaden their high valued product slate to recoup these expenses in the shortest possible payback period. Lyondell Licensing and Criterion Catalyst have put together an effective alliance based on years of development and commercial experience in both the process and catalyst areas to assist lubricant oil manufacturers in meeting these future challenges using as much existing equipment and infrastructure as is practical. Their experience will permit the proper fitting of the chemistry of hydroprocessing to make lubricant base oils to existing or new operations.

  10. New Methane Hydrate Research: Investing in Our Energy Future...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ...

  11. Properties and hydration of blended cements with steelmaking slag

    SciTech Connect (OSTI)

    Kourounis, S.; Tsivilis, S. . E-mail: stsiv@central.ntua.gr; Tsakiridis, P.E.; Papadimitriou, G.D.; Tsibouki, Z.

    2007-06-15

    The present research study investigates the properties and hydration of blended cements with steelmaking slag, a by-product of the conversion process of iron to steel. For this purpose, a reference sample and three cements containing up to 45% w/w steel slag were tested. The steel slag fraction used was the '0-5 mm', due to its high content in calcium silicate phases. Initial and final setting time, standard consistency, flow of normal mortar, autoclave expansion and compressive strength at 2, 7, 28 and 90 days were measured. The hydrated products were identified by X-ray diffraction while the non-evaporable water was determined by TGA. The microstructure of the hardened cement pastes and their morphological characteristics were examined by scanning electron microscopy. It is concluded that slag can be used in the production of composite cements of the strength classes 42.5 and 32.5 of EN 197-1. In addition, the slag cements present satisfactory physical properties. The steel slag slows down the hydration of the blended cements, due to the morphology of contained C{sub 2}S and its low content in calcium silicates.

  12. Scale-up and Technology Transfer of Protein-based Plastic Products

    SciTech Connect (OSTI)

    Grewell, David

    2008-12-08

    Over the last number of years researchers at ISU have been developing protein based plastics from soybeans, funded by Soy Works Corporation. These materials have been characterized and the processing of these materials into prototype products has been demonstrated. A wide range of net-shape forming processes, including but not limited to extrusion, injection molding and compression molding have been studied. Issues, including technology transfer, re-formulation and product consistency, have been addressed partially during this contract. Also, commercial-scale processing parameters for protein based plastic products were designed, but not yet applicable in the industry. Support in the trouble shooting processing and the manufacturing of protein based plastic products was provided by Iowa State University during the one year contract.

  13. FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Gumusut- Kakap Taiwan Messoyahka New Zealand Cascadia Margin Japan Sea Mexico Costa Rica Peru Selected gas-hydrates study areas The types of gas hydrate deposits considered most ...

  14. Methane Hydrate Advisory Committee Meeting Minutes, October 2011...

    Office of Environmental Management (EM)

    October 2011 Methane Hydrate Advisory Committee Meeting Minutes, October 2011 Methane Hydrate Advisory Committee Meeting Minutes October 2011 Washington, DC PDF icon Advisory...

  15. Methane Hydrate Advisory Committee Meeting Minutes, January 2010...

    Broader source: Energy.gov (indexed) [DOE]

    0 Atlanta, GA Methane Hydrate Advisory Committee Meeting Minutes, January 2010 More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane...

  16. gas-hydrate-global-assessment | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas-hydrate-global-assessment Frozen Heat: A Global Outlook on Methane Hydrate cover of executive summary The United Nations Environmental Programme released this new, two-volume...

  17. Coupled Physical/Chemical and Biofiltration Technologies to Reduce Air Emissions from Forest Products Industries

    SciTech Connect (OSTI)

    Gary D. McGinnis

    2001-12-31

    The research is a laboratory and bench-scale investigation of a system to concentrate and destroy volatile organic compounds (VOCs), including hazardous air pollutants, formed from the drying of wood and the manufacture of wood board products (e.g., particle board and oriented strandboard). The approach that was investigated involved concentrating the dilute VOCs (<500 ppmv) with a physical/chemical adsorption unit, followed by the treatment of the concentrated voc stream (2,000 to 2,500 ppmv) with a biofiltration unit. The research program lasted three years, and involved three research organizations. Michigan Technological University was the primary recipient of the financial assistance, the USDA Forest Products Laboratory (FPL) and Mississippi State University (MSU) were subcontractors to MTU. The ultimate objective of this research was to develop a pilot-scale demonstration of the technology with sufficient data to provide for the design of an industrial system. No commercialization activities were included in this project.

  18. Reactive Dehydration technology for Production of Fuels and Chemicals from Biomass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dr. James R. Kittrell, KSE, Inc. Dr. Carl R. Dupre, KSE, Inc. Dr. Michael F. Malone (Subcontractor) U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. 2 Project Objective Commercialize a novel reactive distillation technology using the iCARD platform (Intensified Catalytic and Reactive Distillation) for compact, inexpensive production of biomass-based

  19. Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies Technologies Scientists and engineers at Los Alamos have developed a variety of advanced technologies that anticipate-affect, detect, and neutralize & mitigate all types of explosive threats. v Technologies Since its inception in 1943, Los Alamos National Laboratory has been a driving force in explosives science. Scientists and engineers at Los Alamos have developed a variety of advanced technologies that anticipate, detect, and mitigate all types of explosive threats. ANDE:

  20. A wide variety of injection molding technologies is now applicable to small series and mass production

    SciTech Connect (OSTI)

    Blo, P., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Jttner, G., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Jacob, S., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Lser, C., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Michaelis, J., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Krajewsky, P., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de [Kunststoff-Zentrum in Leipzig gGmbH (KuZ), Leipzig (Germany)

    2014-05-15

    Micro plastic parts open new fields for application, e. g., to electronics, sensor technologies, optics, and medical engineering. Before micro parts can go to mass production, there is a strong need of having the possibility for testing different designs and materials including material combinations. Hence, flexible individual technical and technological solutions for processing are necessary. To manufacture high quality micro parts, a micro injection moulding machine named formicaPlast based on a two-step plunger injection technology was developed. Resulting from its design, the residence time and the accuracy problems for managing small shot volumes with reproducible high accuracy are uncompromisingly solved. Due to their simple geometry possessing smooth transitions and non adherent inner surfaces, the plunger units allow to process 'all' thermoplastics from polyolefines to high performance polymers, optical clear polymers, thermally sensitive bioresorbables, highly filled systems (the so-called powder injection molding PIM), and liquid silicon rubber (LSR, here with a special kit). The applied platform strategy in the 1K and 2K version allows integrating automation for assembling, handling and packaging. A perpendicular arrangement allows encapsulation of inserts, also partially, and integration of this machine into process chains. Considering a wide variety of different parts consisting of different materials, the high potential of the technology is demonstrated. Based on challenging industrial parts from electronic applications (2K micro MID and bump mat, where both are highly structured parts), the technological solutions are presented in more detail.

  1. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., parent company of GEC and WREL, as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. During the reporting period, effort continues on identifying potential technologies for removing contaminants from synthesis gas to the level required by methanol synthesis. A liquid phase Claus process and a direct sulfur oxidation process were evaluated. Preliminary discussion was held with interested parties on cooperating on RD&T in Phase II of the project. Also, significant progress was made during the period in the submission of project deliverables. A meeting was held at DOE's National Energy Technology Laboratory in Morgantown between GEC and the DOE IMPPCCT Project Manager on the status of the project, and reached an agreement on the best way to wrap up Phase I and transition into the Phase II RD&T. Potential projects for the Phase II, cost, and fund availability were also discussed.

  2. Gas Hydrate Storage of Natural Gas

    SciTech Connect (OSTI)

    Rudy Rogers; John Etheridge

    2006-03-31

    Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

  3. Modern plant metabolomics: Advanced natural product gene discoveries, improved technologies, and future prospects

    SciTech Connect (OSTI)

    Sumner, Lloyd W.; Lei, Zhentian; Nikolau, Basil J.; Saito, Kazuki

    2014-10-24

    Plant metabolomics has matured and modern plant metabolomics has accelerated gene discoveries and the elucidation of a variety of plant natural product biosynthetic pathways. This study highlights specific examples of the discovery and characterization of novel genes and enzymes associated with the biosynthesis of natural products such as flavonoids, glucosinolates, terpenoids, and alkaloids. Additional examples of the integration of metabolomics with genome-based functional characterizations of plant natural products that are important to modern pharmaceutical technology are also reviewed. This article also provides a substantial review of recent technical advances in mass spectrometry imaging, nuclear magnetic resonance imaging, integrated LC-MS-SPE-NMR for metabolite identifications, and x-ray crystallography of microgram quantities for structural determinations. The review closes with a discussion on the future prospects of metabolomics related to crop species and herbal medicine.

  4. Modern plant metabolomics: Advanced natural product gene discoveries, improved technologies, and future prospects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sumner, Lloyd W.; Lei, Zhentian; Nikolau, Basil J.; Saito, Kazuki

    2014-10-24

    Plant metabolomics has matured and modern plant metabolomics has accelerated gene discoveries and the elucidation of a variety of plant natural product biosynthetic pathways. This study highlights specific examples of the discovery and characterization of novel genes and enzymes associated with the biosynthesis of natural products such as flavonoids, glucosinolates, terpenoids, and alkaloids. Additional examples of the integration of metabolomics with genome-based functional characterizations of plant natural products that are important to modern pharmaceutical technology are also reviewed. This article also provides a substantial review of recent technical advances in mass spectrometry imaging, nuclear magnetic resonance imaging, integrated LC-MS-SPE-NMR formore » metabolite identifications, and x-ray crystallography of microgram quantities for structural determinations. The review closes with a discussion on the future prospects of metabolomics related to crop species and herbal medicine.« less

  5. AISI/DOE Technology Roadmap Program: A Technology of Low Coal Rate and High Productivity of RHF Ironmaking

    SciTech Connect (OSTI)

    Wei-Kao Lu

    2002-09-15

    An economical and environment-friendly ironmaking process based on heating the chemiexecy self-sufficient green balls of iron ore and coal in a hearth furnace is being developed with financial support from AISI members and DOE. DRI, which is hot (1400 C), dense (3.2 g/cm) and of high degree of metallization (95%), has been produced in laboratory and in a pilot plant in Genoa, Italy. Products of such quality have been made from American and Brazilian ores, BOF sludge, EAF dust/BOF sludge mixtures and millscale. The removal of zinc and lead from green balls by this process is essentially complete. In comparison with typical blast furnace operation, the new technology with a melter would have a lower total coal rate by 200kg.THM. The elimination of cokemaking and high temperature agglomeration steps, and a simpler gas handling system would lead to lower capital and operating costs. In comparison with commercial RHF practice it is different in atmosphere (fully oxidized at 1600 to 1650 C), in bed height (120 mm instead of 20-25 mm) and in pellet composition (much less coal but of higher VM). The combined effect leads to three times higher furnace productivity, lower coal consumption and superior DRI quality. The risk of re-oxidation (slag formation) and dusty operation are practiexecy eliminated. The process is stable, tolerant and independent of the size, shape and movement of the hearth. However, materials handling (e.g., discharge of hot DRI) and the exact energy savings have to be established in a larger furnace, straight or rotary, and in a continuous mode of operation.

  6. Gas Hydrates Research Programs: An International Review

    SciTech Connect (OSTI)

    Jorge Gabitto; Maria Barrufet

    2009-12-09

    Gas hydrates sediments have the potential of providing a huge amount of natural gas for human use. Hydrate sediments have been found in many different regions where the required temperature and pressure conditions have been satisfied. Resource exploitation is related to the safe dissociation of the gas hydrate sediments. Basic depressurization techniques and thermal stimulation processes have been tried in pilot efforts to exploit the resource. There is a growing interest in gas hydrates all over the world due to the inevitable decline of oil and gas reserves. Many different countries are interested in this valuable resource. Unsurprisingly, developed countries with limited energy resources have taken the lead in worldwide gas hydrates research and exploration. The goal of this research project is to collect information in order to record and evaluate the relative strengths and goals of the different gas hydrates programs throughout the world. A thorough literature search about gas hydrates research activities has been conducted. The main participants in the research effort have been identified and summaries of their past and present activities reported. An evaluation section discussing present and future research activities has also been included.

  7. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-10-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Two project phases are planned for execution, including: (1) Feasibility study and conceptual design for an integrated demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility is a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., parent company of GEC and WREL, as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. During the reporting period, DOE approved the RD&T Plan submitted in the previous quarter. The RD&T Plan forms the basis for the Continuation Application to initiate the transition of the project from Phase I to Phase II. Potential technologies for removing contaminants from synthesis gas to the level required by methanol synthesis will be tested in slipstream units at the WREL facility during Phase II. A supplemental information package consisting of a revised Work Breakdown Structure and Budget Plan for Phase II and other necessary forms was also submitted. Agreement is being reached with DOE's patent attorney on the scope of the limited rights data to be provided under the Cooperative Agreement. Preparation of a comprehensive Final Report for Phase I of the project, which will consolidate the remaining deliverables including the Initial Feasibility Report, Concept Report, Site Analysis Report, Economic Analysis, and Preliminary Project Financing Plan, continued during the reporting period. Significant progress was made in the Subsystem Design Specification section of the report.

  8. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Doug Strickland; Albert Tsang

    2002-10-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial plants operated at Dow Chemical or Dow Corning chemical plant locations; (2) Research, development, and testing to define any technology gaps or critical design and integration issues; and (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. This report describes management planning, work breakdown structure development, and feasibility study activities by the IMPPCCT consortium in support of the first project phase. Project planning activities have been completed, and a project timeline and task list has been generated. Requirements for an economic model to evaluate the West Terre Haute implementation and for other commercial implementations are being defined. Specifications for methanol product and availability of local feedstocks for potential commercial embodiment plant sites have been defined. The WREL facility is a project selected and co-funded under the fifth phase solicitation of the U.S. Department of Energy's Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the U.S. Department of Energy, working under a Cooperative Agreement Award from the ''Early Entrance Coproduction Plant'' (EECP) initiative, the GEC and an Industrial Consortia are investigating the application of synthesis gas from the E-GAS{trademark} technology to a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  9. CaCl 2 -Accelerated Hydration of Tricalcium Silicate: A STXM Study Combined with 29 Si MAS NMR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Qinfei; Ge, Yong; Geng, Guoqing; Bae, Sungchul; Monteiro, Paulo J. M.

    2015-01-01

    Tmore » he effect of calcium chloride (CaCl 2 ) on tricalcium silicate (C 3 S) hydration was investigated by scanning transmission X-ray microscopy (STXM) with Near Edge X-ray Absorption Fine Structure (NEXAFS) spectra and 29 Si MAS NMR. STXM is demonstrated to be a powerful tool for studying the chemical composition of a cement-based hydration system.he Ca L 3,2 -edge NEXAFS spectra obtained by examining C 3 S hydration in the presence of CaCl 2 showed that this accelerator does not change the coordination of calcium in the calcium silicate hydrate (C-S-H), which is the primary hydration product. O K-edge NEXAFS is also very useful in distinguishing the chemical components in hydrated C 3 S. Based on the Ca L 3,2 -edge spectra and chemical component mapping, we concluded that CaCl 2 prefers to coexist with unhydrated C 3 S instead of C-S-H. In Si K-edge NEXAFS analysis, CaCl 2 increases the degree of silicate polymerization of C-S-H in agreement with the 29 Si CP/MAS NMR results, which show that the presence of CaCl 2 in hydrated C 3 S considerably accelerates the formation of middle groups ( Q 2 ) and branch sites ( Q 3 ) in the silicate chains of C-S-H gel at 1-day hydration.« less

  10. CONTENTS Preliminary Results of China's Third Gas Hydrate Drilling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preliminary Results of China's Third Gas Hydrate Drilling Expedition: A Critical Step From Discovery to Development in the South China Sea ............................1 Gas Hydrate Occurrences in the Black Sea - New Observations from the German SUGAR Project ...............................................6 Methane Hydrate Dynamics on the Northern US Atlantic Margin ............................................ 10 Gas Hydrate, Carbonate Crusts, and Chemosynthetic Organisms on A Vestnesa Ridge

  11. GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS

    SciTech Connect (OSTI)

    James Sorensen; Jaroslav Solc; Bethany Bolles

    2000-07-01

    The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

  12. Additives and method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, Jr., Earle Dendy; Christiansen, Richard Lee; Lederhos, Joseph P.; Long, Jin Ping; Panchalingam, Vaithilingam; Du, Yahe; Sum, Amadeu Kun Wan

    1997-01-01

    Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

  13. Additives and method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, E.D. Jr.; Christiansen, R.L.; Lederhos, J.P.; Long, J.P.; Panchalingam, V.; Du, Y.; Sum, A.K.W.

    1997-06-17

    Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hindrance and/or charge repulsion. Also, polymers having an amide on which a C{sub 1}-C{sub 4} group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

  14. Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model Andy Aden Technical Report NREL/TP-510-43205 May 2008 NREL is operated by Midwest Research Institute ● Battelle Contract No. DE-AC36-99-GO10337 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov Operated for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy by Midwest Research Institute * Battelle Contract No.

  15. Advanced Gas Storage Concepts: Technologies for the Future

    SciTech Connect (OSTI)

    Freeway, Katy; Rogers, R.E.; DeVries, Kerry L.; Nieland, Joel D.; Ratigan, Joe L.; Mellegard, Kirby D.

    2000-02-01

    This full text product includes: 1) A final technical report titled Advanced Underground Gas Storage Concepts, Refrigerated-Mined Cavern Storage and presentations from two technology transfer workshops held in 1998 in Houston, Texas, and Pittsburgh, Pennsylvania (both on the topic of Chilled Gas Storage in Mined Caverns); 2) A final technical report titled Natural Gas Hydrates Storage Project, Final Report 1 October 1997 - 31 May 1999; 3) A final technical report titled Natural Gas Hydrates Storage Project Phase II: Conceptual Design and Economic Study, Final Report 9 June - 10 October 1999; 4) A final technical report titled Commerical Potential of Natural Gas Storage in Lined Rock Caverns (LRC) and presentations from a DOE-sponsored workshop on Alternative Gas Storage Technologies, held Feb 17, 2000 in Pittsburgh, PA; and 5) Phase I and Phase II topical reports titled Feasibility Study for Lowering the Minimum Gas Pressure in Solution-Mined Caverns Based on Geomechanical Analyses of Creep-Induced Damage and Healing.

  16. Hydrate Control for Gas Storage Operations

    SciTech Connect (OSTI)

    Jeffrey Savidge

    2008-10-31

    The overall objective of this project was to identify low cost hydrate control options to help mitigate and solve hydrate problems that occur in moderate and high pressure natural gas storage field operations. The study includes data on a number of flow configurations, fluids and control options that are common in natural gas storage field flow lines. The final phase of this work brings together data and experience from the hydrate flow test facility and multiple field and operator sources. It includes a compilation of basic information on operating conditions as well as candidate field separation options. Lastly the work is integrated with the work with the initial work to provide a comprehensive view of gas storage field hydrate control for field operations and storage field personnel.

  17. Technolog

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research in Science and Technolog y Sandia pushes frontiers of knowledge to meet the nation's needs, today and tomorrow Sandia National Laboratories' fundamental science and technology research leads to greater understanding of how and why things work and is intrinsic to technological advances. Basic research that challenges scientific assumptions enables the nation to push scientific boundaries. Innovations and breakthroughs produced at Sandia allow it to tackle critical issues, from

  18. Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology /newsroom/_assets/images/s-icon.png Technology Delivering science to the marketplace through commercialization, spinoffs and industry partnerships. Health Space Computing Energy Earth Materials Science Technology The Lab All Glen Wurden in the stellarator's vacuum vessel during camera installation in 2014. Innovative imaging systems on the Wendelstein 7-X bring steady-state fusion energy closer to reality Innovative new imaging systems designed at Los Alamos are helping physicists

  19. Technolog

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research in Science and Technolog y Sandia pushes frontiers of knowledge to meet the nation's needs, today and tomorrow ... Basic research that challenges scientific assumptions ...

  20. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    SciTech Connect (OSTI)

    Conocophillips

    2007-09-30

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-Gas technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and later COP and the industrial partners investigated the use of syngas produced by the E-Gas technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort were to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from syngas derived from coal, or, coal in combination with some other carbonaceous feedstock. The intended result of the project was to provide the necessary technical, economic, and environmental information that would be needed to move the EECP forward to detailed design, construction, and operation by industry. The EECP study conducted in Phase 1 of the IMPPCCT Project confirmed that the concept for the integration of gasification-based (E-Gas) electricity generation from coal and/or petroleum coke and methanol production (Liquid Phase Methanol or LPMEOH{trademark}) processes was feasible for the coproduction of power and chemicals. The results indicated that while there were minimal integration issues that impact the deployment of an IMPPCCT CEP, the major concern was the removal of sulfur and other trace contaminants, which are known methanol catalyst poisons, from the syngas. However, economic concerns in the domestic methanol market which is driven by periodic low natural gas prices and cheap offshore supplies limit the commercial viability of this more capital intensive concept. The objective of Phase 2 was to conduct RD&T as outlined in the Phase 1 RD&T Plan to enhance the development and commercial acceptance of coproduction technology. Studies were designed to address the technical concerns that would make the IMPPCCT concept competitive with natural gas-based systems in the commercial marketplace. Efforts in Phase 2 investigated the cleanup of the syngas by removing contaminants, particularly sulfur species, to a level acceptable for the methanol synthesis catalyst, and reducing the cost of the current sulfur removal system such as via warm gas cleanup methods. Laboratory testing followed by on-site field testing at SGS with bench-scale slipstream units was conducted. Actual syngas produced by the facility was evaluated at system pressure and temperature.

  1. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect (OSTI)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies would result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs.

  2. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect (OSTI)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. It was hoped that the successful application of these technologies would result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs.

  3. DOE/Fossil Energy`s drilling, completion, and stimulation RD&D: A technologies/products overview

    SciTech Connect (OSTI)

    Duda, J.R.; Yost, A.B. II

    1995-12-31

    An overview of natural gas drilling, completion, and stimulation RD&D sponsored by the US Department of Energy is reported in this paper. Development of high rate-of-penetration drilling systems and underbalanced drilling technologies are detailed among other RD&D activities. The overview serves as a technology transfer medium and is intended to accelerate the deployment of the products and technologies described.

  4. Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids

    SciTech Connect (OSTI)

    Oyama, Ted; Agblevor, Foster; Battaglia, Francine; Klein, Michael

    2013-01-18

    The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

  5. NETL Collaborates with Partners to Produce Global Outlook on Natural Gas Hydrates

    Broader source: Energy.gov [DOE]

    Researchers at the Office of Fossil Energy’s National Energy Technology Laboratory (NETL) were part of an international team, including the United Nations Environmental Programme (UNEP), that contributed to a newly released report explaining the prospect of gas hydrates as a potential worldwide energy source that can contribute in the transition to the low-carbon energy systems of the future.

  6. WABASH RIVER IMPPCCT, INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES

    SciTech Connect (OSTI)

    Doug Strickland

    2001-09-28

    In a joint effort with the U.S. Department of Energy, working under a Cooperative Agreement Award from the ''Early Entrance Coproduction Plant'' (EECP) initiative, the Gasification Engineering Corporation and an Industrial Consortium are investigating the application of synthesis gas from the E-GAS{trademark} technology to a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an Early Entrance Coproduction Plant located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, financial, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution, including: (1) Feasibility Study and conceptual design for an integrated demonstration facility and for fence-line commercial plants operated at The Dow Chemical Company or Dow Corning Corporation chemical plant locations (i.e. the Commercial Embodiment Plant or CEP) (2) Research, development, and testing to address any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Ltd., plant in West Terre Haute, Indiana. During the reporting period work was furthered to support the development of capital and operating cost estimates associated with the installation of liquid or gas phase methanol synthesis technology in a Commercial Embodiment Plant (CEP) utilizing the six cases previously defined. In addition, continued development of the plant economic model was accomplished by providing combined cycle performance data. Performance and emission estimates for gas turbine combined cycles was based on revised methanol purge gas information. The economic model was used to evaluate project returns with various market conditions and plant configurations and was refined to correct earlier flaws. Updated power price projections were obtained and incorporated in the model. Sensitivity studies show that break-even methanol prices which provide a 12% return are 47-54 cents/gallon for plant scenarios using $1.25/MM Btu coal, and about 40 cents/gallon for most of the scenarios with $0.50/MM Btu petroleum coke as the fuel source. One exception is a high power price and production case which could be economically attractive at 30 cents/gallon methanol. This case was explored in more detail, but includes power costs predicated on natural gas prices at the 95th percentile of expected price distributions. In this case, the breakeven methanol price is highly sensitive to the required project return rate, payback period, and plant on-line time. These sensitivities result mainly from the high capital investment required for the CEP facility ({approx}$500MM for a single train IGCC-methanol synthesis plant). Finally, during the reporting period the Defense Contractor Audit Agency successfully executed an accounting audit of Global Energy Inc. for data accumulated over the first year of the IMPPCCT project under the Cooperative Agreement.

  7. Complex admixtures of clathrate hydrates in a water desalination method

    DOE Patents [OSTI]

    Simmons, Blake A.; Bradshaw, Robert W.; Dedrick, Daniel E.; Anderson, David W.

    2009-07-14

    Disclosed is a method that achieves water desalination by utilizing and optimizing clathrate hydrate phenomena. Clathrate hydrates are crystalline compounds of gas and water that desalinate water by excluding salt molecules during crystallization. Contacting a hydrate forming gaseous species with water will spontaneously form hydrates at specific temperatures and pressures through the extraction of water molecules from the bulk phase followed by crystallite nucleation. Subsequent dissociation of pure hydrates yields fresh water and, if operated correctly, allows the hydrate-forming gas to be efficiently recycled into the process stream.

  8. New Methane Hydrate Research: Investing in Our Energy Future | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped

  9. CO-PRODUCTION OF HYDROGEN AND ELECTRICITY USING PRESSURIZED CIRCULATING FLUIDIZED BED GASIFICATION TECHNOLOGY

    SciTech Connect (OSTI)

    Zhen Fan

    2006-05-30

    Foster Wheeler has completed work under a U.S. Department of Energy cooperative agreement to develop a gasification equipment module that can serve as a building block for a variety of advanced, coal-fueled plants. When linked with other equipment blocks also under development, studies have shown that Foster Wheeler's gasification module can enable an electric generating plant to operate with an efficiency exceeding 60 percent (coal higher heating value basis) while producing near zero emissions of traditional stack gas pollutants. The heart of the equipment module is a pressurized circulating fluidized bed (PCFB) that is used to gasify the coal; it can operate with either air or oxygen and produces a coal-derived syngas without the formation of corrosive slag or sticky ash that can reduce plant availabilities. Rather than fuel a gas turbine for combined cycle power generation, the syngas can alternatively be processed to produce clean fuels and or chemicals. As a result, the study described herein was conducted to determine the performance and economics of using the syngas to produce hydrogen for sale to a nearby refinery in a hydrogen-electricity co-production plant setting. The plant is fueled with Pittsburgh No. 8 coal, produces 99.95 percent pure hydrogen at a rate of 260 tons per day and generates 255 MWe of power for sale. Based on an electricity sell price of $45/MWhr, the hydrogen has a 10-year levelized production cost of $6.75 per million Btu; this price is competitive with hydrogen produced by steam methane reforming at a natural gas price of $4/MMBtu. Hence, coal-fueled, PCFB gasifier-based plants appear to be a viable means for either high efficiency power generation or co-production of hydrogen and electricity. This report describes the PCFB gasifier-based plant, presents its performance and economics, and compares it to other coal-based and natural gas based hydrogen production technologies.

  10. Anomalous porosity preservation and preferential accumulation of gas hydrate in the Andaman accretionary wedge, NGHP-01 site 17A

    SciTech Connect (OSTI)

    Rose, Kelly K.; Johnson, Joel E.; Torres, Marta E.; Hong, WeiLi; Giosan, Liviu; Solomon, E.; Kastner, Miriam; Cawthern, Thomas; Long, Philip E.; Schaef, Herbert T.

    2014-12-01

    In addition to well established properties that control the presence or absence of the hydrate stability zone, such as pressure, temperature, and salinity, additional parameters appear to influence the concentration of gas hydrate in host sediments. The stratigraphic record at Site 17A in the Andaman Sea, eastern Indian Ocean, illustrates the need to better understand the role pore-scale phenomena play in the distribution and presence of marine gas hydrates in a variety of subsurface settings. In this paper we integrate field-generated datasets with newly acquired sedimentology, physical property, imaging and geochemical data with mineral saturation and ion activity products of key mineral phases such as amorphous silica and calcite, to document the presence and nature of secondary precipitates that contributed to anomalous porosity preservation at Site 17A in the Andaman Sea. This study demonstrates the importance of grain-scale subsurface heterogeneities in controlling the occurrence and distribution of concentrated gas hydrate accumulations in marine sediments, and document the importance that increased permeability and enhanced porosity play in supporting gas concentrations sufficient to support gas hydrate formation. The grain scale relationships between porosity, permeability, and gas hydrate saturation documented at Site 17A likely offer insights into what may control the occurrence and distribution of gas hydrate in other sedimentary settings.

  11. RESOURCE CHARACTERIZATION AND QUANTIFICATION OF NATURAL GAS-HYDRATE AND ASSOCIATED FREE-GAS ACCUMULATIONS IN THE PRUDHOE BAY - KUPARUK RIVER AREA ON THE NORTH SLOPE OF ALASKA

    SciTech Connect (OSTI)

    Robert Hunter; Shirish Patil; Robert Casavant; Tim Collett

    2003-06-02

    Interim results are presented from the project designed to characterize, quantify, and determine the commercial feasibility of Alaska North Slope (ANS) gas-hydrate and associated free-gas resources in the Prudhoe Bay Unit (PBU), Kuparuk River Unit (KRU), and Milne Point Unit (MPU) areas. This collaborative research will provide practical input to reservoir and economic models, determine the technical feasibility of gas hydrate production, and influence future exploration and field extension of this potential ANS resource. The large magnitude of unconventional in-place gas (40-100 TCF) and conventional ANS gas commercialization evaluation creates industry-DOE alignment to assess this potential resource. This region uniquely combines known gas hydrate presence and existing production infrastructure. Many technical, economical, environmental, and safety issues require resolution before enabling gas hydrate commercial production. Gas hydrate energy resource potential has been studied for nearly three decades. However, this knowledge has not been applied to practical ANS gas hydrate resource development. ANS gas hydrate and associated free gas reservoirs are being studied to determine reservoir extent, stratigraphy, structure, continuity, quality, variability, and geophysical and petrophysical property distribution. Phase 1 will characterize reservoirs, lead to recoverable reserve and commercial potential estimates, and define procedures for gas hydrate drilling, data acquisition, completion, and production. Phases 2 and 3 will integrate well, core, log, and long-term production test data from additional wells, if justified by results from prior phases. The project could lead to future ANS gas hydrate pilot development. This project will help solve technical and economic issues to enable government and industry to make informed decisions regarding future commercialization of unconventional gas-hydrate resources.

  12. Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Matter and Technologies R&D activities towards a future cw LINAC at GSI Winfried Barth Matter and Technologies Super Heavy Nuclei International Symposium, Texas A & M University, College Station TX, USA, March 31 - April 02, 2015 W. Barth, R&D activities towards a future cw LINAC at GSI 2 R&D activities towards a future cw LINAC at GSI 1. Introduction 2. Status of the Unilac High Current Performance 3. Cavity Development 4. General linac layout 5. R&D approach 6. Status of

  13. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O.; Walsh, Michael M.

    2003-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  14. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O.; Walsh, Michael M.

    1999-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel in order to mix its respective portion of liquid water with the corresponding portion of the stream. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  15. Development of an Immobilisation Technology for Radioactive Waste Solution from Mo-99 Production

    SciTech Connect (OSTI)

    Sizgek, G.D.; Sizgek, E.

    2006-07-01

    Australian Nuclear Science and Technology Organisation (ANSTO) developed a method to immobilize the Intermediate Level Liquid Waste (ILLW) arising from its Mo-99 production process. The immobilisation process involves impregnation of waste solution into ceramic precursor powders, drying, calcining and consolidation (Hot Isostatic Pressing, HIP) to produce final ceramic waste form. Ceramic precursor powder is produced by spray drying of a sol-gel based colloidal dispersion. These free-flowing, microspherical, 20-80 microns, precursors have porosity of 40-50%. An in-house custom designed and manufactured microwave-heated and mechanically fluidized mixer-drier was used for impregnation of the precursor powder with the simulated waste (Depleted Uranyl Nitrate Hexahydrate, DUNH, and inactive Cs, Sr nitrates as fission products) and drying. During impregnation an evaporation rate of 1 l/h water per kW microwave energy in steady state was achieved by matching the feed rate of DUNH to produce equivalent of 35% UO{sub 2} loading. It was demonstrated that the tuned microwave energy can be delivered to the mixer-drier during the entire impregnation process within very low reflection values. The samples of the waste loaded free-flowing powder were subsequently calcined at 750 deg. C under reducing atmosphere for thermal denitration and mineral phase nucleation. Calcined powders were filled into cans. After evacuation and sealing, the cans were isostatically pressed at 1260 deg. C. The consolidated ceramic waste form produced from the DUNH run has been assessed by durability and material characterization tests. Successful confirmation of each processing step at pilot and/or plant scale, has led to the design and construction of the overall process at full scale (equivalent of processing 8 kg U per batch) in a simulated hot-cell mock-up plant. The constructed plant mainly consists of a Microwave-heated Mechanical Fluidized Bed (MWMFB) mixer-drier a fluidized bed calciner, an off gas unit, material transfer/holding and can filling units. Performance of the overall process by integrating each of the processing steps and material transfer operations are currently being tested with inactive simulants from the point of remote operated plant design perspective. Definitive design of a hot-cell production system has been initiated in parallel to the mock-up plant tests. This paper describes the results of both full-scale DUNH impregnation run and inactive mock-up plant tests in developing unique Mo-99 waste immobilisation technology. (authors)

  16. Dehydration of plutonium or neptunium trichloride hydrate

    DOE Patents [OSTI]

    Foropoulos, Jr., Jerry (Los Alamos, NM); Avens, Larry R. (Los Alamos, NM); Trujillo, Eddie A. (Espanola, NM)

    1992-01-01

    A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.

  17. Dehydration of plutonium or neptunium trichloride hydrate

    DOE Patents [OSTI]

    Foropoulos, J. Jr.; Avens, L.R.; Trujillo, E.A.

    1992-03-24

    A process is described for preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride.

  18. Report of the Task Force on Methane Hydrates

    Broader source: Energy.gov [DOE]

    This report presents the findings and recommendations for the Secretary of Energy Advisory Board (SEAB) Task Force on Methane Hydrates.

  19. Draft Report of the Task Force on Methane Hydrates

    Broader source: Energy.gov [DOE]

    This report presents the findings and recommendations for the Secretary of Energy Advisory Board (SEAB) Task Force on Methane Hydrates.

  20. Technical support for the Ohio Coal Technology Program. Volume 1, Baseline of knowledge concerning by-product characteristics: Final report

    SciTech Connect (OSTI)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L.

    1989-08-28

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LRl and comprises two volumes. Volume I presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume II consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  1. Long-term affected energy production of waste to energy technologies identified by use of energy system analysis

    SciTech Connect (OSTI)

    Muenster, M.; Meibom, P.

    2010-12-15

    Affected energy production is often decisive for the outcome of consequential life-cycle assessments when comparing the potential environmental impact of products or services. Affected energy production is however difficult to determine. In this article the future long-term affected energy production is identified by use of energy system analysis. The focus is on different uses of waste for energy production. The Waste-to-Energy technologies analysed include co-combustion of coal and waste, anaerobic digestion and thermal gasification. The analysis is based on optimization of both investments and production of electricity, district heating and bio-fuel in a future possible energy system in 2025 in the countries of the Northern European electricity market (Denmark, Norway, Sweden, Finland and Germany). Scenarios with different CO{sub 2} quota costs are analysed. It is demonstrated that the waste incineration continues to treat the largest amount of waste. Investments in new waste incineration capacity may, however, be superseded by investments in new Waste-to-Energy technologies, particularly those utilising sorted fractions such as organic waste and refuse derived fuel. The changed use of waste proves to always affect a combination of technologies. What is affected varies among the different Waste-to-Energy technologies and is furthermore dependent on the CO{sub 2} quota costs and on the geographical scope. The necessity for investments in flexibility measures varies with the different technologies such as storage of heat and waste as well as expansion of district heating networks. Finally, inflexible technologies such as nuclear power plants are shown to be affected.

  2. Development of an In Situ Biosurfactant Production Technology for Enhanced Oil Recovery

    SciTech Connect (OSTI)

    M.J. McInerney; R.M. Knapp; Kathleen Duncan; D.R. Simpson; N. Youssef; N. Ravi; M.J. Folmsbee; T.Fincher; S. Maudgalya; Jim Davis; Sandra Weiland

    2007-09-30

    The long-term economic potential for enhanced oil recovery (EOR) is large with more than 300 billion barrels of oil remaining in domestic reservoirs after conventional technologies reach their economic limit. Actual EOR production in the United States has never been very large, less than 10% of the total U. S. production even though a number of economic incentives have been used to stimulate the development and application of EOR processes. The U.S. DOE Reservoir Data Base contains more than 600 reservoirs with over 12 billion barrels of unrecoverable oil that are potential targets for microbially enhanced oil recovery (MEOR). If MEOR could be successfully applied to reduce the residual oil saturation by 10% in a quarter of these reservoirs, more than 300 million barrels of oil could be added to the U.S. oil reserve. This would stimulate oil production from domestic reservoirs and reduce our nation's dependence on foreign imports. Laboratory studies have shown that detergent-like molecules called biosurfactants, which are produced by microorganisms, are very effective in mobilizing entrapped oil from model test systems. The biosurfactants are effective at very low concentrations. Given the promising laboratory results, it is important to determine the efficacy of using biosurfactants in actual field applications. The goal of this project is to move biosurfactant-mediated oil recovery from laboratory investigations to actual field applications. In order to meet this goal, several important questions must be answered. First, it is critical to know whether biosurfactant-producing microbes are present in oil formations. If they are present, then it will be important to know whether a nutrient regime can be devised to stimulate their growth and activity in the reservoir. If biosurfactant producers are not present, then a suitable strain must be obtained that can be injected into oil reservoirs. We were successful in answering all three questions. The specific objectives of the project were (1) to determine the prevalence of biosurfactant producers in oil reservoirs, and (2) to develop a nutrient regime that would stimulate biosurfactant production in the oil reservoir.

  3. Videos of Experiments from ORNL Gas Hydrate Research

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gas hydrate research performed by the Environmental Sciences Division utilizes the ORNL Seafloor Process Simulator, the Parr Vessel, the Sapphire Cell, a fiber optic distributed sensing system, and Raman spectroscopy. The group studies carbon sequestration in the ocean, desalination, gas hydrates in the solar system, and nucleation and dissociation kinetics. The videos available at the gas hydrates website are very short clips from experiments.

  4. The thermodynamic properties of hydrated -Al2O3 nanoparticles

    SciTech Connect (OSTI)

    Spencer, Elinor; Huang, Baiyu; Parker, Stewart F.; Kolesnikov, Alexander I; Ross, Dr. Nancy; Woodfield, Brian

    2013-01-01

    In this paper we report a combined calorimetric and inelastic neutron scattering (INS) study of hydrated -Al2O3 ( -alumina) nanoparticles. These complementary techniques have enabled a comprehensive evaluation of the thermodynamic properties of this technological and industrially important metal oxide to be achieved. The isobaric heat capacity (Cp) data presented herein provide further critical insights into the much-debated chemical composition of -alumina nanoparticles. Furthermore, the isochoric heat capacity (Cv) of the surface water, which is so essential to the stability of all metal-oxides at the nanoscale, has been extracted from the high-resolution INS data and differs significantly from that of ice Ih due to the dominating influence of strong surface-water interactions. This study also encompassed the analysis of four -alumina samples with differing pore diameters [4.5 (1), 13.8 (2), 17.9 (3), and 27.2 nm (4)], and the results obtained allow us to unambiguously conclude that the water content and pore size have no influence on the thermodynamic behaviour of hydrated -alumina nanoparticles.

  5. 28. annual offshore technology conference: Proceedings. Volume 4: Field drilling and development systems

    SciTech Connect (OSTI)

    1996-12-31

    The 88 papers in this volume cover the following topics: Small operator implementation of subsea technology; Control system umbilicals, components and ROV interfacing; DeepStar--Results and plans; Deepwater subsea manifold systems; Drilling technology; Limit state design criteria for pipelines; Liuhua project; Mobile offshore drilling units; Offshore coiled tubing operations; Oman-India gas pipeline; Paraffin and hydrate control; Pompano--A deepwater subsea development; Severe operating conditions; Subsea production systems; and Well completions technology. Papers have been processed separately for inclusion on the data base.

  6. International technology exchange in support of the Defense Waste Processing Facility wasteform production

    SciTech Connect (OSTI)

    Kitchen, B.G.

    1989-08-23

    The nearly completed Defense Waste Processing Facility (DWPF) is a Department of Energy (DOE) facility at the Savannah River Site that is designed to immobilize defense high level radioactive waste (HLW) by vitrification in borosilicate glass and containment in stainless steel canisters suitable for storage in the future DOE HLW repository. The DWPF is expected to start cold operation later this year (1990), and will be the first full scale vitrification facility operating in the United States, and the largest in the world. The DOE has been coordinating technology transfer and exchange on issues relating to HLW treatment and disposal through bi-lateral agreements with several nations. For the nearly fifteen years of the vitrification program at Savannah River Laboratory, over two hundred exchanges have been conducted with a dozen international agencies involving about five-hundred foreign national specialists. These international exchanges have been beneficial to the DOE`s waste management efforts through confirmation of the choice of the waste form, enhanced understanding of melter operating phenomena, support for paths forward in political/regulatory arenas, confirmation of costs for waste form compliance programs, and establishing the need for enhancements of melter facility designs. This paper will compare designs and schedules of the international vitrification programs, and will discuss technical areas where the exchanges have provided data that have confirmed and aided US research and development efforts, impacted the design of the DWPF and guided the planning for regulatory interaction and product acceptance.

  7. International technology exchange in support of the Defense Waste Processing Facility wasteform production

    SciTech Connect (OSTI)

    Kitchen, B.G.

    1989-08-23

    The nearly completed Defense Waste Processing Facility (DWPF) is a Department of Energy (DOE) facility at the Savannah River Site that is designed to immobilize defense high level radioactive waste (HLW) by vitrification in borosilicate glass and containment in stainless steel canisters suitable for storage in the future DOE HLW repository. The DWPF is expected to start cold operation later this year (1990), and will be the first full scale vitrification facility operating in the United States, and the largest in the world. The DOE has been coordinating technology transfer and exchange on issues relating to HLW treatment and disposal through bi-lateral agreements with several nations. For the nearly fifteen years of the vitrification program at Savannah River Laboratory, over two hundred exchanges have been conducted with a dozen international agencies involving about five-hundred foreign national specialists. These international exchanges have been beneficial to the DOE's waste management efforts through confirmation of the choice of the waste form, enhanced understanding of melter operating phenomena, support for paths forward in political/regulatory arenas, confirmation of costs for waste form compliance programs, and establishing the need for enhancements of melter facility designs. This paper will compare designs and schedules of the international vitrification programs, and will discuss technical areas where the exchanges have provided data that have confirmed and aided US research and development efforts, impacted the design of the DWPF and guided the planning for regulatory interaction and product acceptance.

  8. DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program Integrated Hydrogen Production, Purification and Compression System

    SciTech Connect (OSTI)

    Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

    2011-06-30

    The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of <$1.50/gge, which was later revised by DOE to $2-$3/gge range for hydrogen to be competitive with gasoline as a fuel for vehicles. For small, on-site hydrogen plants being evaluated at the time for refueling stations (the 'forecourt'), it was determined that capital cost is the main contributor to the high cost of delivered hydrogen. The concept of this project was to reduce the cost by combining unit operations for the entire generation, purification, and compression system (refer to Figure 1). To accomplish this, the Fluid Bed Membrane Reactor (FBMR) developed by MRT was used. The FBMR has hydrogen selective, palladium-alloy membrane modules immersed in the reformer vessel, thereby directly producing high purity hydrogen in a single step. The continuous removal of pure hydrogen from the reformer pushes the equilibrium 'forward', thereby maximizing the productivity with an associated reduction in the cost of product hydrogen. Additional gains were envisaged by the integration of the novel Metal Hydride Hydrogen Compressor (MHC) developed by Ergenics, which compresses hydrogen from 0.5 bar (7 psia) to 350 bar (5,076 psia) or higher in a single unit using thermal energy. Excess energy from the reformer provides up to 25% of the power used for driving the hydride compressor so that system integration improved efficiency. Hydrogen from the membrane reformer is of very high, fuel cell vehicle (FCV) quality (purity over 99.99%), eliminating the need for a separate purification step. The hydride compressor maintains hydrogen purity because it does not have dynamic seals or lubricating oil. The project team set out to integrate the membrane reformer developed by MRT and the hydride compression system developed by Ergenics in a single package. This was expected to result in lower cost and higher efficiency compared to conventional hydrogen production technologies. The overall objective was to develop an integrated system to directly produce high pressure, high-purity hydrogen from a single unit, which can meet the DOE cost H2 cost target of $2 - $3/gge when mass produced. The project was divided into two phases with the following tasks and corresponding milestones, targets and decision points. Phase 1 - Task 1 - Verify feasibility of the concept, perform a detailed techno-economic analysis, and develop a test plan; and Task 2: Build and experimentally test a Proof of Concept (POC) integrated membrane reformer/metal hydride compressor system. Phase 2 - Task 3: Build an Advanced Prototype (AP) system with modifications based on POC learning and demonstrate at a commercial site; and Task 4: Complete final product design for mass manufacturing units capable of achieving DOE 2010 H2 cost and performance targets.

  9. Maintaining a Technology-Neutral Approach to Hydrogen Production Process Development through Conceptual Design of the Next Generation Nuclear Plant

    SciTech Connect (OSTI)

    Michael W. Patterson

    2008-05-01

    The Next Generation Nuclear Plant (NGNP) project was authorized in the Energy Policy Act of 2005 (EPAct), tasking the U.S. Department of Energy (DOE) with demonstrating High Temperature Gas-Cooled Reactor (HTGR) technology. The demonstration is to include the technical, licensing, operational, and commercial viability of HTGR technology for the production of electricity and hydrogen. The Nuclear Hydrogen Initiative (NHI), a component of the DOE Hydrogen Program managed by the Office of Nuclear Energy, is also investigating multiple approaches to cost effective hydrogen production from nuclear energy. The objective of NHI is development of the technology and information basis for a future decision on commercial viability. The initiatives are clearly intertwined. While the objectives of NGNP and NHI are generally consistent, NGNP has progressed to the project definition phase and the project plan has matured. Multiple process applications for the NGNP require process heat, electricity and hydrogen in varied combinations and sizes. Coupling these processes to the reactor in multiple configurations adds complexity to the design, licensing and demonstration of both the reactor and the hydrogen production process. Commercial viability of hydrogen production may depend on the specific application and heat transport configuration. A component test facility (CTF) is planned by the NGNP to support testing and demonstration of NGNP systems, including those for hydrogen production, in multiple configurations. Engineering-scale demonstrations in the CTF are expected to start in 2012 to support scheduled design and licensing activities leading to subsequent construction and operation. Engineering-scale demonstrations planned by NHI are expected to start at least two years later. Reconciliation of these schedules is recommended to successfully complete both initiatives. Hence, closer and earlier integration of hydrogen process development and heat transport systems is sensible. For integration purposes, an analysis comparing the design, cost and schedule impact of maintaining a technology neutral approach through conceptual design or making an early hydrogen process technology selection was performed. Early selection does not specifically eliminate a technology, but rather selects the first hydrogen technology for demonstration. A systems-engineering approach was taken to define decision-making criteria for selecting a hydrogen technology. The relative technical, cost and schedule risks of each approach were analyzed and risk mitigation strategies were recommended, including provisions to maintain close collaboration with the NHI. The results of these analyses are presented here.

  10. DOE Selects Projects to Advance Technologies for the Co-Production...

    Energy Savers [EERE]

    ... Georgia Institute of Technology (Atlanta, Ga.)--Georgia Tech will team with the National Renewable Energy Laboratory in Golden, Colo., to obtain experimental reactor data and ...

  11. Breakthrough Water Cleaning Technology Could Lessen Environmental Impacts from Shale Production

    Office of Energy Efficiency and Renewable Energy (EERE)

    A novel water cleaning technology currently being tested in field demonstrations could help significantly reduce potential environmental impacts from producing natural gas from the Marcellus shale and other geologic formations, according to the Department of Energy’s National Energy Technology Laboratory

  12. Oil & Natural Gas Technology Temporal Characterization of Hydrates...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... out as clear resistivity anomalies relative to sediment containing saline pore water. ... Observatory at MC118. The ROV provided power from its onboard battery and an emulated ...

  13. Emerging Energy-efficiency and CO{sub 2} Emission-reduction Technologies for Cement and Concrete Production

    SciTech Connect (OSTI)

    Hasanbeigi, Ali; Price, Lynn; Lin, Elina

    2012-04-06

    Globally, the cement industry accounts for approximately 5 percent of current anthropogenic carbon dioxide (CO{sub 2}) emissions. World cement demand and production are increasing significantly, leading to an increase in this industry's absolute energy use and CO{sub 2} emissions. Development of new energy-efficiency and CO{sub 2} emission-reduction technologies and their deployment in the market will be key for the cement industry's mid- and long-term climate change mitigation strategies. This report is an initial effort to compile available information on process description, energy savings, environmental and other benefits, costs, commercialization status, and references for emerging technologies to reduce the cement industry's energy use and CO{sub 2} emissions. Although studies from around the world identify a variety of sector-specific and cross-cutting energy-efficiency technologies for the cement industry that have already been commercialized, information is scarce and/or scattered regarding emerging or advanced energy-efficiency and low-carbon technologies that are not yet commercialized. This report consolidates available information on nineteen emerging technologies for the cement industry, with the goal of providing engineers, researchers, investors, cement companies, policy makers, and other interested parties with easy access to a well-structured database of information on these technologies.

  14. Geothermal Energy Production with Co-produced and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP)

    Broader source: Energy.gov [DOE]

    This fact sheet provides an overview of geothermal energy production using co-produced and geopressured resources.

  15. Innovation in Nuclear Technology for the Least Product Price and Cost

    SciTech Connect (OSTI)

    Duffey, Romney

    2003-09-01

    In energy markets, costs dominate for all new technology introductions (pressure valves, gas turbines, reactors) both now and far into the future. Technology improves, and costs are reduced as markets are penetrated with the trend following a learning/experience curve (MCE) based on classic economic forces. The curve followed is governed by development costs and market targets, and nuclear systems follow such a curve in order to compete with other technologies and projected future cost for alternate energy initiatives. Funding impacts directly on market penetration and on the ''learning rate.'' The CANDU/AECL development path (experience curve) is a chosen balance between evolution and revolution for a competitive advantage.

  16. Clean-coal technology by-products used in a highway embankment stabilization demonstration project. Master's thesis

    SciTech Connect (OSTI)

    Nodjomian, S.M.

    1994-01-01

    Clean-coal technology by-products are used in a highway embankment demonstration project. This research chronicles the procedures used in the process and analyzes the stability of a repaired highway embankment. The reconstructed slope is analyzed using an Intelligent Discussion Support System that was developed from a slope stability program. Water quality studies are performed and an instrumentation plan is suggested. The calculated factors of safety and the observed embankment performance give indications that the field demonstration project was a success. Long-term monitoring will be the best barometer for determining embankment gross movement and the future of FGD by-products as a stabilizing material.

  17. Insights into the structure of mixed CO2/CH4 in gas hydrates

    SciTech Connect (OSTI)

    Everett, Susan M; Rawn, Claudia J; Chakoumakos, Bryan C; Keffer, David J.; Huq, Ashfia; Phelps, Tommy Joe

    2015-01-01

    The exchange of CO2 for CH4 in natural gas hydrates is an attractive approach to methane for energy production while simultaneously sequestering CO2. In addition to the energy and environmental implications, the solid solution of clathrate hydrate (CH4)1-x(CO2)x 5.75H2O provides a model system to study how the distinct bonding and shapes of CH4 and CO2 influence the structure and properties of the compound. High-resolution neutron diffraction was used to examine mixed CO2/CH4 gas hydrates. CO2-rich hydrates had smaller lattice parameters, which were attributed to the higher affinity of the CO2 molecule interacting with H2O molecules that form the surrounding cages, and resulted in a reduction in the unit cell volume. Experimental nuclear scattering densities illustrate how the cage occupants and energy landscape change with composition. These results provide important insights on the impact and mechanisms for exchanging CH4 and CO2.

  18. Insights into the structure of mixed CO2/CH4 in gas hydrates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Everett, Susan M; Rawn, Claudia J; Chakoumakos, Bryan C; Keffer, David J.; Huq, Ashfia; Phelps, Tommy Joe

    2015-01-01

    The exchange of CO2 for CH4 in natural gas hydrates is an attractive approach to methane for energy production while simultaneously sequestering CO2. In addition to the energy and environmental implications, the solid solution of clathrate hydrate (CH4)1-x(CO2)x 5.75H2O provides a model system to study how the distinct bonding and shapes of CH4 and CO2 influence the structure and properties of the compound. High-resolution neutron diffraction was used to examine mixed CO2/CH4 gas hydrates. CO2-rich hydrates had smaller lattice parameters, which were attributed to the higher affinity of the CO2 molecule interacting with H2O molecules that form the surrounding cages,more » and resulted in a reduction in the unit cell volume. Experimental nuclear scattering densities illustrate how the cage occupants and energy landscape change with composition. These results provide important insights on the impact and mechanisms for exchanging CH4 and CO2.« less

  19. DOE Announces Selections for SSL Core Technology and Product Development Funding Opportunities (Round 5)

    Broader source: Energy.gov [DOE]

    The National Energy Technology Laboratory, on behalf of the U.S. Department of Energy (DOE), is pleased to announce its selections for solid-state lighting (SSL) funding opportunities. Fourteen...

  20. Vehicle Technologies Office Merit Review 2015: Lithium-Ion Battery Production and Recycling Materials Issues

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about lithium-ion...

  1. EERE Success Story—Battery Company Puts New Nanowire Technology into Production

    Broader source: Energy.gov [DOE]

    A battery company supported by the Vehicle Technologies Office (VTO) has an agreement to manufacture silicon nanowire material for lithium-ion batteries on a commercial scale for the first time. ...

  2. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-06-27

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies will result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs.

  3. Methane Hydrate Research and Modeling | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research and Modeling Methane Hydrate Research and Modeling Research is focused on understanding the physical and chemical nature of gas hydrate-bearing sediments. These studies advance the understanding of the in situ nature of GHBS and their potential response in terms of fluid flow and geomechanical response to destabilizing forces. The latest research results from DOE projects, both current and completed, can be found on the NETL website. These include: Gas Hydrate Characterization in the

  4. Study of alinite cement hydration by impedance spectroscopy (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Study of alinite cement hydration by impedance spectroscopy Citation Details In-Document Search Title: Study of alinite cement hydration by impedance spectroscopy Two types of alinite cements, Mg-alinite and Zn-alinite, were synthesized using the reagent grade chemicals. Their hydration behavior was compared with ordinary Portland cement (OPC) using impedance spectroscopy (IS) and {sup 29}Si nuclear magnetic resonance (NMR) spectroscopy. The bulk resistance in the

  5. DOE Announces $2 Million Funding for Methane Hydrates Projects | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 Million Funding for Methane Hydrates Projects DOE Announces $2 Million Funding for Methane Hydrates Projects November 7, 2005 - 12:43pm Addthis Seeks to Unlock World's Biggest Potential Source of "Ice That Burns" WASHINGTON, DC - The Department of Energy (DOE) today announced a total of $2 million in funding to five research projects that will assess the energy potential, safety, and environmental aspects of methane hydrate exploration and development. Termed the

  6. Task 1.13 - Data Collection and Database Development for Clean Coal Technology By-Product Characteristics and Management Practices

    SciTech Connect (OSTI)

    Debra F. Pflughoeft-Hassett

    1998-02-01

    U.S. Department of Energy Federal Energy Technology Center-Morgantown (DOE FETC) efforts in the areas of fossil fuels and clean coal technology (CCT) have included involvement with both conventional and advanced process coal conversion by-products. In 1993, DOE submitted a Report to Congress on "Barriers to the Increased Utilization of Coal Combustion Desulfurization Byproducts by Governmental and Commercial Sectors" that provided an outline of activities to remove the barriers identified in the report. DOE charged itself with participation in this process, and the work proposed in this document facilitates DOE's response to its own recommendations for action. The work reflects DOE's commitment to the coal combustion by-product (CCB) industry, to the advancement of clean coal technology, and to cooperation with other government agencies. Information from DOE projects and commercial endeavors in fluidized-bed combustion (FBC) and coal gasification is the focus of this task. The primary goal is to provide an easily accessible compilation of characterization information on the by-products from these processes to government agencies and industry to facilitate sound regulatory and management decisions. Additional written documentation will facilitate the preparation of an updated final version of background information collected for DOE in preparation of the Report to Congress on barriers to CCB utilization.

  7. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack; Tim Francis; Peter Schultheiss; Philip E. Long; Barry M. Freifeld

    2005-04-01

    The primary activities accomplished during this quarter were continued efforts to develop plans for Phase 2 of this cooperative agreement based on the evolving operational planning for IODP Expedition 311, which will use the JOIDES Resolution to study marine methane hydrates along the Cascadia margin, offshore Vancouver Island. IODP Expedition 311 has been designed to further constrain the models for the formation of marine gas hydrate in subduction zone accretionary prisms. The objectives include characterizing the deep origin of the methane, its upward transport, its incorporation in gas hydrate, and its subsequent loss to the seafloor. The main attention of this expedition is on the widespread seafloor-parallel layer of dispersed gas hydrate located just above the base of the predicted stability field. In a gas hydrate formation model, methane is carried upward through regional sediment or small-scale fracture permeability, driven by the tectonic consolidation of the accretionary prism. The upward moving methane is incorporated into the gas hydrate clathrate as it enters the methane hydrate stability zone. Also important is the focusing of a portion of the upward methane flux into localized plumes or channels to form concentrations of near-seafloor gas hydrate. The amount of gas hydrate in local concentrations near the seafloor is especially important for understanding the response of marine gas hydrate to climate change. The expedition includes coring and downhole measurements at five sites across the Northern Cascadia accretionary prism. The sites will track the history of methane in an accretionary prism from (1) its production by mainly microbiological processes over a thick sediment vertical extent, (2) its upward transport through regional or locally focused fluid flow, (3) its incorporation in the regional hydrate layer above the BSR or in local concentrations at or near the seafloor, (4) methane loss from the hydrate by upward diffusion, and (5) methane oxidation and incorporation in seafloor carbonate, or expulsion to the ocean. This expedition builds on the previous Cascadia gas hydrate drilling of ODP Leg 146 and on more recent ODP Leg 204 off Oregon. Important experiments being considered for DOE/NETL funding as part of the JOI cooperative agreement include, (1) Logging-While-Drilling/Measurements-While-Drilling (LWD/MWD), (2) Pressure Core Sampling (PCS/HYACINTH) of gas hydrate, and fluid recovery under in situ conditions, (3) X-ray CT logging of whole cores under in situ conditions, and (4) Infrared thermal imaging of whole round cores to map temperature variations resulting from the presence of hydrate. Preliminary budget estimates have been made for each of these tasks and discussions are ongoing with DOE/NETL program managers to develop a final plan that can be implemented within the constraints of the available funding and logistical considerations.

  8. Method for the photocatalytic conversion of gas hydrates

    DOE Patents [OSTI]

    Taylor, Charles E.; Noceti, Richard P.; Bockrath, Bradley C.

    2001-01-01

    A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0.degree. C., and allows for the direct conversion of methane contained within the hydrate in situ.

  9. An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs...

    Open Energy Info (EERE)

    based on the analysis of geochemical anomalies to the main components, such as methane and hydrocarbon series, an integrated assessment of prospective gas hydrate...

  10. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Unknown

    2001-08-08

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a novel alkaline-steam well completion technique for the containment of the unconsolidated formation sands and control of fluid entry and injection profiles. (5) Installation of a 2100 ft, 14 inch insulated, steam line beneath a harbor channel to supply steam to an island location. (6) Testing and proposed application of thermal recovery technologies to increase oil production and reserves: (a) Performing pilot tests of cyclic steam injection and production on new horizontal wells. (b) Performing pilot tests of hot water-alternating-steam (WAS) drive in the existing steam drive area to improve thermal efficiency. (7) Perform a pilot steamflood with the four horizontal injectors and producers using a pseudo steam-assisted gravity-drainage (SAGD) process. (8) Advanced reservoir management, through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring and evaluation.

  11. Investigating the Metastability of Clathrate Hydrates for Energy Storage

    SciTech Connect (OSTI)

    Koh, Carolyn Ann

    2014-11-18

    Important breakthrough discoveries have been achieved from the DOE award on the key processes controlling the synthesis and structure-property relations of clathrate hydrates, which are critical to the development of clathrate hydrates as energy storage materials. Key achievements include: (i) the discovery of key clathrate hydrate building blocks (stable and metastable) leading to clathrate hydrate nucleation and growth; (ii) development of a rapid clathrate hydrate synthesis route via a seeding mechanism; (iii) synthesis-structure relations of H2 + CH4/CO2 binary hydrates to control thermodynamic requirements for energy storage and sequestration applications; (iv) discovery of a new metastable phase present during clathrate hydrate structural transitions. The success of our research to-date is demonstrated by the significant papers we have published in high impact journals, including Science, Angewandte Chemie, J. Am. Chem. Soc. Intellectual Merits of Project Accomplishments: The intellectual merits of the project accomplishments are significant and transformative, in which the fundamental coupled computational and experimental program has provided new and critical understanding on the key processes controlling the nucleation, growth, and thermodynamics of clathrate hydrates containing hydrogen, methane, carbon dioxide, and other guest molecules for energy storage. Key examples of the intellectual merits of the accomplishments include: the first discovery of the nucleation pathways and dominant stable and metastable structures leading to clathrate hydrate formation; the discovery and experimental confirmation of new metastable clathrate hydrate structures; the development of new synthesis methods for controlling clathrate hydrate formation and enclathration of molecular hydrogen. Broader Impacts of Project Accomplishments: The molecular investigations performed in this project on the synthesis (nucleation & growth)-structure-stability relations of clathrate hydrate systems are pivotal in the fundamental understanding of crystalline clathrate hydrates and the discovery of new clathrate hydrate properties and novel materials for a broad spectrum of energy applications, including: energy storage (hydrogen, natural gas); carbon dioxide sequestration; controlling hydrate formation in oil/gas transportation in subsea pipelines. The Project has also enabled the training of undergraduate, graduate and postdoctoral students in computational methods, molecular spectroscopy and diffraction, and measurement methods at extreme conditions of high pressure and low temperature.

  12. Design manual for management of solid by-products from advanced coal technologies

    SciTech Connect (OSTI)

    1994-10-01

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  13. Presentations from the March 27th - 28th Methane Hydrates Advisory

    Energy Savers [EERE]

    Committee Meeting | Department of Energy the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting PDF icon International Gas Hydrate Research PDF icon DOE's Natural Gas Hydrates Program PDF icon Gas Hydrates as a Geohazard: What Really Are the Issues? PDF icon Quantifying Climate-Hydrate Interactions: A Progress Report More Documents & Publications May 21, 2014 Committee Recommendations to

  14. Surfactant process for promoting gas hydrate formation and application of the same

    DOE Patents [OSTI]

    Rogers, Rudy E. (Starkville, MS); Zhong, Yu (Brandon, MS)

    2002-01-01

    This invention relates to a method of storing gas using gas hydrates comprising forming gas hydrates in the presence of a water-surfactant solution that comprises water and surfactant. The addition of minor amounts of surfactant increases the gas hydrate formation rate, increases packing density of the solid hydrate mass and simplifies the formation-storage-decomposition process of gas hydrates. The minor amounts of surfactant also enhance the potential of gas hydrates for industrial storage applications.

  15. Computer analyses for the design, operation and safety of new isotope production reactors: A technology status review

    SciTech Connect (OSTI)

    Wulff, W.

    1990-01-01

    A review is presented on the currently available technologies for nuclear reactor analyses by computer. The important distinction is made between traditional computer calculation and advanced computer simulation. Simulation needs are defined to support the design, operation, maintenance and safety of isotope production reactors. Existing methods of computer analyses are categorized in accordance with the type of computer involved in their execution: micro, mini, mainframe and supercomputers. Both general and special-purpose computers are discussed. Major computer codes are described, with regard for their use in analyzing isotope production reactors. It has been determined in this review that conventional systems codes (TRAC, RELAP5, RETRAN, etc.) cannot meet four essential conditions for viable reactor simulation: simulation fidelity, on-line interactive operation with convenient graphics, high simulation speed, and at low cost. These conditions can be met by special-purpose computers (such as the AD100 of ADI), which are specifically designed for high-speed simulation of complex systems. The greatest shortcoming of existing systems codes (TRAC, RELAP5) is their mismatch between very high computational efforts and low simulation fidelity. The drift flux formulation (HIPA) is the viable alternative to the complicated two-fluid model. No existing computer code has the capability of accommodating all important processes in the core geometry of isotope production reactors. Experiments are needed (heat transfer measurements) to provide necessary correlations. It is important for the nuclear community, both in government, industry and universities, to begin to take advantage of modern simulation technologies and equipment. 41 refs.

  16. Presentations from the March 27th - 28th Methane Hydrates Advisory...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting PDF icon International Gas ...

  17. UST corrective action technologies: Engineering design of free product recovery systems. Project report

    SciTech Connect (OSTI)

    Parker, J.C.; Waddill, D.W.; Johnson, J.A.

    1996-03-01

    The objective of this project was to develop a technical assistance document for assessment of subsurface hydrocarbon spills and for evaluating effects of well placement and pumping rates on separate phase plume control and on free product recovery. Procedures developed for estimation of hydrocarbon spill volume include interpolation and spatial integration of measurements from soil cores, and fluid level data from monitoring wells. The first method involves vertical integration of soil concentration measurements to yield oil volume or species mass per unit area followed by kriging and areal integration to estimate the total mass or volume within the measurement zone. The second method involves kriging of well fluid levels, calculation of free oil volume per area using a physically based model for vertically hydrostatic three phase fluid distributions that converts well product thickness to soil product thickness, followed by areal integration to estimate the volume of free product floating on the water table. A procedure is presented to evaluate effects of steady-state water pumping from multiple point sources on the oil flow gradients to evaluate if hydraulic control of plume spreading will be obtained for a selected system of pumping wells and/or trenches. The applicability of trenches and vacuum-enhanced product recovery to hydrocarbon spills is also discussed.

  18. Heat of Hydration of Low Activity Cementitious Waste Forms

    SciTech Connect (OSTI)

    Nasol, D.

    2015-07-23

    During the curing of secondary waste grout, the hydraulic materials in the dry mix react exothermally with the water in the secondary low-activity waste (LAW). The heat released, called the heat of hydration, can be measured using a TAM Air Isothermal Calorimeter. By holding temperature constant in the instrument, the heat of hydration during the curing process can be determined. This will provide information that can be used in the design of a waste solidification facility. At the Savannah River National Laboratory (SRNL), the heat of hydration and other physical properties are being collected on grout prepared using three simulants of liquid secondary waste generated at the Hanford Site. From this study it was found that both the simulant and dry mix each had an effect on the heat of hydration. It was also concluded that the higher the cement content in the dry materials mix, the greater the heat of hydration during the curing of grout.

  19. Relative permeability of hydrate-bearing sediments from percolation theory and critical path analysis: theoretical and experimental results

    SciTech Connect (OSTI)

    Daigle, Hugh; Rice, Mary Anna; Daigle, Hugh

    2015-12-14

    Relative permeabilities to water and gas are important parameters for accurate modeling of the formation of methane hydrate deposits and production of methane from hydrate reservoirs. Experimental measurements of gas and water permeability in the presence of hydrate are difficult to obtain. The few datasets that do exist suggest that relative permeability obeys a power law relationship with water or gas saturation with exponents ranging from around 2 to greater than 10. Critical path analysis and percolation theory provide a framework for interpreting the saturation-dependence of relative permeability based on percolation thresholds and the breadth of pore size distributions, which may be determined easily from 3-D images or gas adsorption-desorption hysteresis. We show that the exponent of the permeability-saturation relationship for relative permeability to water is related to the breadth of the pore size distribution, with broader pore size distributions corresponding to larger exponents. Relative permeability to water in well-sorted sediments with narrow pore size distributions, such as Berea sandstone or Toyoura sand, follows percolation scaling with an exponent of 2. On the other hand, pore-size distributions determined from argon adsorption measurements we performed on clays from the Nankai Trough suggest that relative permeability to water in fine-grained intervals may be characterized by exponents as large as 10 as determined from critical path analysis. We also show that relative permeability to the gas phase follows percolation scaling with a quadratic dependence on gas saturation, but the threshold gas saturation for percolation changes with hydrate saturation, which is an important consideration in systems in which both hydrate and gas are present, such as during production from a hydrate reservoir. Our work shows how measurements of pore size distributions from 3-D imaging or gas adsorption may be used to determine relative permeabilities.

  20. Supplying the nuclear arsenal: Production reactor technology, management, and policy, 1942--1992

    SciTech Connect (OSTI)

    Carlisle, R.P.; Zenzen, J.M.

    1994-01-01

    This book focuses on the lineage of America`s production reactors, those three at Hanford and their descendants, the reactors behind America`s nuclear weapons. The work will take only occasional sideways glances at the collateral lines of descent, the reactor cousins designed for experimental purposes, ship propulsion, and electric power generation. Over the decades from 1942 through 1992, fourteen American production reactors made enough plutonium to fuel a formidable arsenal of more than twenty thousand weapons. In the last years of that period, planners, nuclear engineers, and managers struggled over designs for the next generation of production reactors. The story of fourteen individual machines and of the planning effort to replace them might appear relatively narrow. Yet these machines lay at the heart of the nation`s nuclear weapons complex. The story of these machines is the story of arming the winning weapon, supplying the nuclear arms race. This book is intended to capture the history of the first fourteen production reactors, and associated design work, in the face of the end of the Cold War.

  1. Energy Department Announces $10 Million for Technologies to Produce Advanced Biofuel Products from Biomass

    Broader source: Energy.gov [DOE]

    The Energy Department today announced up to $10 million in funding to advance the production of advanced biofuels, substitutes for petroleum-based feedstocks, and bioproducts made from renewable, non-food-based biomass, such as agricultural residues and woody biomass.

  2. Genetically enhanced cellulase production in Pseudomonas cellulosa using recombinant DNA technology

    DOE Patents [OSTI]

    Dees, H. Craig

    1999-01-01

    An enhanced strain of Pseudomonas celllulosa was obtained by introducing a recombinant genetic construct comprising a heterologous cellulase gene operably connected to a promoter into ATCC 55702, mutagenizing the transformants by treatment with MNNG, and selecting a high cellulase producing transformant. The transformant, designated Pseudomonas cellulosa ATCC XXXX, exhibits enhanced levels of cellulase production relative to the untransformed Pseudomonas cellulosa strain #142 ATCC 55702.

  3. Quarterly Report: Microchannel-Assisted Nanomaterial Deposition Technology for Photovoltaic Material Production

    SciTech Connect (OSTI)

    Palo, Daniel R.

    2011-04-26

    Quarterly report to ITP for Nanomanufacturing program. Report covers FY11 Q2. The primary objective of this project is to develop a nanomanufacturing process which will reduce the manufacturing energy, environmental discharge, and production cost associated with current nano-scale thin-film photovoltaic (PV) manufacturing approaches. The secondary objective is to use a derivative of this nanomanufacturing process to enable greener, more efficient manufacturing of higher efficiency quantum dot-based photovoltaic cells now under development. The work is to develop and demonstrate a scalable (pilot) microreactor-assisted nanomaterial processing platform for the production, purification, functionalization, and solution deposition of nanomaterials for photovoltaic applications. The high level task duration is shown. Phase I consists of a pilot platform for Gen II PV films along with parallel efforts aimed at Gen III PV quantum dot materials. Status of each task is described.

  4. Genetically enhanced cellulase production in Pseudomonas cellulosa using recombinant DNA technology

    SciTech Connect (OSTI)

    Dees, H.C.

    1999-09-28

    An enhanced strain of Pseudomonas cellulosa was obtained by introducing a recombinant genetic construct comprising a heterologous cellulase gene operably connected to a promoter into ATCC 55702, mutagenizing the transformants by treatment with MNNG, and selecting a high cellulase producing transformant. The transformant, designated Pseudomonas cellulosa ATCC XXXX, exhibits enhanced levels of cellulase production relative to the untransformed Pseudomonas cellulosa strain {number{underscore}sign}142 ATCC 55702.

  5. Increasing Heavy Oil Reserves in the Wilmington Oil Field through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect (OSTI)

    City of Long Beach; David K.Davies and Associates; Tidelands Oil Production Company; University of Southern California

    1999-06-25

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California. This is realized through the testing and application of advanced reservoir characterization and thermal production technologies. It is hoped that the successful application of these technologies will result in their implementation throughout the Wilmington Field and through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively insufficient because of several producability problems which are common in SBC reservoir; inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves.

  6. Investigation and Analytical Description of Acoustic Production by Magneto-Acoustic Mixing Technology

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Henderson, Hunter Bryant; Rios, Orlando; Ludtka, Gerard Michael; Manuel, Michele V.

    2015-05-07

    Magneto-Acoustic Mixing Technology (MAMT) is a novel manufacturing method that combines two magnetic fields to produce high-intensity sonication for liquid-state materials processing. This method may be adapted to the manufacture of various materials that benefit from a combination of high temperature, magnetic fields, and acoustic energy. In this work, the acoustic generation mechanism is described in detail and found to be dependent on the skin depth of the induction currents. Analytical models of acoustic pressure are derived, based on two mutually exclusive vibration modes, crucible vibration and melt vibration. Additionally, grain size evidence of acoustic pressure distribution is presented asmore » model validation.« less

  7. Metal halogen battery system with multiple outlet nozzle for hydrate

    DOE Patents [OSTI]

    Bjorkman, Jr., Harry K.

    1983-06-21

    A metal halogen battery system, including at least one cell having a positive electrode and a negative electrode contacted by aqueous electrolyte containing the material of said metal and halogen, store means whereby halogen hydrate is formed and stored as part of an aqueous material, means for circulating electrolyte through the cell and to the store means, and conduit means for transmitting halogen gas formed in the cell to a hydrate former whereby the hydrate is formed in association with the store means, said store means being constructed in the form of a container which includes a filter means, said filter means being inoperative to separate the hydrate formed from the electrolyte, said system having, a hydrate former pump means associated with the store means and being operative to intermix halogen gas with aqueous electrolyte to form halogen hydrate, said hydrate former means including, multiple outlet nozzle means connected with the outlet side of said pump means and being operative to minimize plugging, said nozzle means being comprised of at least one divider means which is generally perpendicular to the rotational axes of gears within the pump means, said divider means acting to divide the flow from the pump means into multiple outlet flow paths.

  8. Gerar Technology | Open Energy Information

    Open Energy Info (EERE)

    Gerar Technology Jump to: navigation, search Name: Gerar Technology Place: Rio de Janeiro, Brazil Product: Developer of new technology for production of biodiesel from vegetable...

  9. Comparing Laser Welding Technologies with Friction Stir Welding for Production of Aluminum Tailor-Welded Blanks

    SciTech Connect (OSTI)

    Hovanski, Yuri; Carsley, John; Carlson, Blair; Hartfield-Wunsch, Susan; Pilli, Siva Prasad

    2014-01-15

    A comparison of welding techniques was performed to determine the most effective method for producing aluminum tailor-welded blanks for high volume automotive applications. Aluminum sheet was joined with an emphasis on post weld formability, surface quality and weld speed. Comparative results from several laser based welding techniques along with friction stir welding are presented. The results of this study demonstrate a quantitative comparison of weld methodologies in preparing tailor-welded aluminum stampings for high volume production in the automotive industry. Evaluation of nearly a dozen welding variations ultimately led to down selecting a single process based on post-weld quality and performance.

  10. Advanced Production Surface Preparation Technology Development for Ultra-High Pressure Diesel Injection

    SciTech Connect (OSTI)

    Grant, Marion B.

    2012-04-30

    In 2007, An Ultra High Injection Pressure (UHIP) fueling method has been demonstrated by Caterpillar Fuel Systems - Product Development, demonstrating ability to deliver U.S. Environment Protection Agency (EPA) Tier 4 Final diesel engine emission performance with greatly reduced emissions handling components on the engine, such as without NOx reduction after-treatment and with only a through-flow 50% effective diesel particulate trap (DPT). They have shown this capability using multiple multi-cylinder engine tests of an Ultra High Pressure Common Rail (UHPCR) fuel system with higher than traditional levels of CEGR and an advanced injector nozzle design. The system delivered better atomization of the fuel, for more complete burn, to greatly reduce diesel particulates, while CEGR or high efficiency NOx reduction after-treatment handles the NOx. With the reduced back pressure of a traditional DPT, and with the more complete fuel burn, the system reduced levels of fuel consumption by 2.4% for similar delivery of torque and horsepower over the best Tier 4 Interim levels of fuel consumption in the diesel power industry. The challenge is to manufacture the components in high-volume production that can withstand the required higher pressure injection. Production processes must be developed to increase the toughness of the injector steel to withstand the UHIP pulsations and generate near perfect form and finish in the sub-millimeter size geometries within the injector. This project resulted in two developments in 2011. The first development was a process and a machine specification by which a high target of compressive residual stress (CRS) can be consistently imparted to key surfaces of the fuel system to increase the toughness of the steel, and a demonstration of the feasibility of further refinement of the process for use in volume production. The second development was the demonstration of the feasibility of a process for imparting near perfect, durable geometry to these same feature surfaces to withstand the pulsating UHIP diesel injection without fatigue failure, through the expected life of the fuel system's components (10,000 hours for the pump and common rail, 5000 hours for the injector). The potential to Caterpillar of this fueling approach and the overall emissions reduction system is the cost savings of the fuel, the cost savings of not requiring a full emissions module and other emissions hardware, and the enabling of the use of biodiesel fuel due to the reduced dependency on after-treatment. A proprietary production CRS generating process was developed to treat the interior of the sac-type injector nozzle tip region (particularly for the sac region). Ninety-five tips passed ultra high pulsed pressure fatigue testing with no failures assignable to treated surfaces or materials. It was determined that the CRS impartation method does not weaken the tip internal seat area. Caterpillar Fuel Systems - Product Development accepts that the CRS method initial production technical readiness level has been established. A method to gage CRS levels in production was not yet accomplished, but it is believed that monitoring process parameters call be used to guarantee quality. A precision profiling process for injector seat and sac regions has been shown to be promising but not yet fully confirmed. It was demonstrated that this precision profiling process can achieve form and geometry to well under an aggressively small micron peak-to-valley and that there are no surface flaws that approach an even tighter micron peak-to-valley tolerance. It is planned to purchase machines to further develop and move the process towards production. The system is targeted towards the high-power diesel electric power generators and high-power diesel marine power generators, with displacement from 20 liters to 80 liters and with power from 800 brake horsepower (BHP) to 3200BHP (0.6 megawatts to 2.4 megawatts). However, with market adoption, this system has the potential to meet EPA exhaust standards for all diesel engines nine liters and up, or 300B

  11. Premium Fuel Production From Mining and Timber Waste Using Advanced Separation and Pelletizing Technologies

    SciTech Connect (OSTI)

    Honaker, R. Q.; Taulbee, D.; Parekh, B. K.; Tao, D.

    2005-12-05

    The Commonwealth of Kentucky is one of the leading states in the production of both coal and timber. As a result of mining and processing coal, an estimated 3 million tons of fine coal are disposed annually to waste-slurry impoundments with an additional 500 million tons stored at a number of disposal sites around the state due to past practices. Likewise, the Kentucky timber industry discards nearly 35,000 tons of sawdust on the production site due to unfavorable economics of transporting the material to industrial boilers for use as a fuel. With an average heating value of 6,700 Btu/lb, the monetary value of the energy disposed in the form of sawdust is approximately $490,000 annually. Since the two industries are typically in close proximity, one promising avenue is to selectively recover and dewater the fine-coal particles and then briquette them with sawdust to produce a high-value fuel. The benefits are i) a premium fuel product that is low in moisture and can be handled, transported, and utilized in existing infrastructure, thereby avoiding significant additional capital investment and ii) a reduction in the amount of fine-waste material produced by the two industries that must now be disposed at a significant financial and environmental price. As such, the goal of this project was to evaluate the feasibility of producing a premium fuel with a heating value greater than 10,000 Btu/lb from waste materials generated by the coal and timber industries. Laboratory and pilot-scale testing of the briquetting process indicated that the goal was successfully achieved. Low-ash briquettes containing 5% to 10% sawdust were produced with energy values that were well in excess of 12,000 Btu/lb. A major economic hurdle associated with commercially briquetting coal is binder cost. Approximately fifty binder formulations, both with and without lime, were subjected to an extensive laboratory evaluation to assess their relative technical and economical effectiveness as binding agents for the briquetting of 90% coal and 10% sawdust blends. Guar gum, wheat starch, and a multi-component formulation were identified as most cost-effective for the production of briquettes targeted for the pulverized-coal market with costs being around $8 per ton of the coal-sawdust blend. REAX/lime and a second multi-component formulation were identified as the most cost-effective for the production of briquettes targeted for the stoker-coal market. Various sources of sawdust generated from different wood types were also investigated to determine their chemical properties and to evaluate their relative performance when briquetted with clean coal to form a premium fuel. The highest heating values, approaching 7,000 Btu/lb, were obtained from oak. Sawdusts from higher-density, red oak, white oak, hickory, and beech trees provided higher quality briquettes relative to their lower-density counterparts. In addition to sawdust type, a number of other parameters were evaluated to characterize their impact on briquette properties. The parameters that exhibited the greatest impact on briquette performance were binder concentration; sawdust concentration and particle size; cure temperature; and ash content. Parameters that had the least impact on briquette properties, at least over the ranges studied, were moisture content, briquetting force, and briquetting dwell time. The continuous production of briquettes from a blend of coal and sawdust was evaluated using a 200 lbs/hr Komarek Model B-100 briquetter. The heating values of briquettes produced by the unit exceeded the goal of the project by a large margin. A significant observation was the role of feed moisture on the stability of the mass flow rate through the briquetter and on briquette strength. Excessive feed moisture levels caused inconsistent or stoppage of material flow through the feed hopper and resulted in the production of variable-quality briquettes. Obviously, the limit on feed moisture content has a significant impact on the economics of coal-sawdust briquetting since it will ultimately dictate dewatering costs. Interestingly, the maximum feed moisture was found to be dependent to some extent on the binder type with molasses-containing blends being difficult to feed when the moisture content approached 12% while guar gum blends flowed consistently at moisture levels as high as 15% by weight. Due to the low ash and moisture contents of the coal-sawdust briquettes, a production increase of about 50 tons/hr would potentially be realized at a 1,400 ton/hr preparation plant. The overall capital cost of a 50 ton/hr flotation and briquetting addition was estimated to be around $8 million. Based on a conservative briquetting operating cost of $12/ton, the annual profit before taxes was approximated to be $4 million thereby indicating a return on investment in about 2 years. The internal rate of return based on a 10 year life was an attractive 43%.

  12. Fuel-Flexible Gasification-Combustion Technology for Production of H2 and Sequestration-Ready CO2

    SciTech Connect (OSTI)

    George Rizeq; Parag Kulkarni; Wei Wei; Arnaldo Frydman; Thomas McNulty; Roger Shisler

    2005-11-01

    It is expected that in the 21st century the Nation will continue to rely on fossil fuels for electricity, transportation, and chemicals. It will be necessary to improve both the process efficiency and environmental impact performance of fossil fuel utilization. GE Global Research is developing an innovative fuel-flexible Unmixed Fuel Processor (UFP) technology to produce H{sub 2}, power, and sequestration-ready CO{sub 2} from coal and other solid fuels. The UFP module offers the potential for reduced cost, increased process efficiency relative to conventional gasification and combustion systems, and near-zero pollutant emissions including NO{sub x}. GE was awarded a contract from U.S. DOE NETL to develop the UFP technology. Work on the Phase I program started in October 2000, and work on the Phase II effort started in April 2005. In the UFP technology, coal and air are simultaneously converted into separate streams of (1) high-purity hydrogen that can be utilized in fuel cells or turbines, (2) sequestration-ready CO{sub 2}, and (3) high temperature/pressure vitiated air to produce electricity in a gas turbine. The process produces near-zero emissions with an estimated efficiency higher than IGCC with conventional CO2 separation. The Phase I R&D program established the feasibility of the integrated UFP technology through lab-, bench- and pilot-scale testing and investigated operating conditions that maximize separation of CO{sub 2} and pollutants from the vent gas, while simultaneously maximizing coal conversion efficiency and hydrogen production. The Phase I effort integrated experimental testing, modeling and preliminary economic studies to demonstrate the UFP technology. The Phase II effort will focus on three high-risk areas: economics, sorbent attrition and lifetime, and product gas quality for turbines. The economic analysis will include estimating the capital cost as well as the costs of hydrogen and electricity for a full-scale UFP plant. These costs will be benchmarked with IGCC polygen costs for plants of similar size. Sorbent attrition and lifetime will be addressed via bench-scale experiments that monitor sorbent performance over time and by assessing materials interactions at operating conditions. The product gas from the third reactor (high-temperature vitiated air) will be evaluated to assess the concentration of particulates, pollutants and other impurities relative to the specifications required for gas turbine feed streams. This is the eighteenth quarterly technical progress report for the UFP program, which is supported by U.S. DOE NETL (Contract No. DE-FC26-00FT40974) and GE. This report summarizes program accomplishments for the Phase II period starting July 01, 2005 and ending September 30, 2005. The report includes an introduction summarizing the UFP technology, main program tasks, and program objectives; it also provides a summary of program activities and accomplishments covering progress in tasks including process modeling, scale-up and economic analysis.

  13. Final technical report: Commercialization of the Biofine technology for levulinic acid production from paper sludge

    SciTech Connect (OSTI)

    Fitzpatrick, Stephen W.

    2002-04-23

    This project involved a three-year program managed by BioMetics, Inc. (Waltham, MA) to demonstrate the commercial feasibility of Biofine thermochemical process technology for conversion of cellulose-containing wastes or renewable materials into levulinic acid, a versatile platform chemical. The program, commencing in October 1995, involved the design, procurement, construction and operation of a plant utilizing the Biofine process to convert 1 dry ton per day of paper sludge waste. The plant was successfully designed, constructed, and commissioned in 1997. It was operated for a period of one year on paper sludge from a variety of source paper mills to collect data to verify the design for a commercial scale plant. Operational results were obtained for four different feedstock varieties. Stable, continuous operation was achieved for two of the feedstocks. Continuous operation of the plant at demonstration scale provided the opportunity for process optimization, development of operational protocols, operator training and identification of suitable materials of construction for scale up to commercial operation . Separated fiber from municipal waster was also successfully processed. The project team consisted of BioMetics Inc., Great Lakes Chemical Corporation (West Lafayette, IN), and New York State Energy Research and Development Authority (Albany, NY).

  14. Sun Materials Technology aka Shanyang Technology | Open Energy...

    Open Energy Info (EERE)

    Technology aka Shanyang Technology Jump to: navigation, search Name: Sun Materials Technology (aka Shanyang Technology) Place: Yilan County, Taiwan Product: A US-Taiwan JV company...

  15. Examination of Hydrate Formation Methods: Trying to Create Representative Samples

    SciTech Connect (OSTI)

    Kneafsey, T.J.; Rees, E.V.L.; Nakagawa, S.; Kwon, T.-H.

    2011-04-01

    Forming representative gas hydrate-bearing laboratory samples is important so that the properties of these materials may be measured, while controlling the composition and other variables. Natural samples are rare, and have often experienced pressure and temperature changes that may affect the property to be measured [Waite et al., 2008]. Forming methane hydrate samples in the laboratory has been done a number of ways, each having advantages and disadvantages. The ice-to-hydrate method [Stern et al., 1996], contacts melting ice with methane at the appropriate pressure to form hydrate. The hydrate can then be crushed and mixed with mineral grains under controlled conditions, and then compacted to create laboratory samples of methane hydrate in a mineral medium. The hydrate in these samples will be part of the load-bearing frame of the medium. In the excess gas method [Handa and Stupin, 1992], water is distributed throughout a mineral medium (e.g. packed moist sand, drained sand, moistened silica gel, other porous media) and the mixture is brought to hydrate-stable conditions (chilled and pressurized with gas), allowing hydrate to form. This method typically produces grain-cementing hydrate from pendular water in sand [Waite et al., 2004]. In the dissolved gas method [Tohidi et al., 2002], water with sufficient dissolved guest molecules is brought to hydrate-stable conditions where hydrate forms. In the laboratory, this is can be done by pre-dissolving the gas of interest in water and then introducing it to the sample under the appropriate conditions. With this method, it is easier to form hydrate from more soluble gases such as carbon dioxide. It is thought that this method more closely simulates the way most natural gas hydrate has formed. Laboratory implementation, however, is difficult, and sample formation is prohibitively time consuming [Minagawa et al., 2005; Spangenberg and Kulenkampff, 2005]. In another version of this technique, a specified quantity of gas is placed in a sample, then the sample is flooded with water and cooled [Priest et al., 2009]. We have performed a number of tests in which hydrate was formed and the uniformity of the hydrate formation was examined. These tests have primarily used a variety of modifications of the excess gas method to make the hydrate, although we have also used a version of the excess water technique. Early on, we found difficulties in creating uniform samples with a particular sand/ initial water saturation combination (F-110 Sand, {approx} 35% initial water saturation). In many of our tests we selected this combination intentionally to determine whether we could use a method to make the samples uniform. The following methods were examined: Excess gas, Freeze/thaw/form, Freeze/pressurize/thaw, Excess gas followed by water saturation, Excess water, Sand and kaolinite, Use of a nucleation enhancer (SnoMax), and Use of salt in the water. Below, each method, the underlying hypothesis, and our results are briefly presented, followed by a brief conclusion. Many of the hypotheses investigated are not our own, but were presented to us. Much of the data presented is from x-ray CT scanning our samples. The x-ray CT scanner provides a three-dimensional density map of our samples. From this map and the physics that is occurring in our samples, we are able to gain an understanding of the spatial nature of the processes that occur, and attribute them to the locations where they occur.

  16. HEAT OF HYDRATION OF SALTSTONE MIXES-MEASUREMENT BY ISOTHERMAL CALORIMETRY

    SciTech Connect (OSTI)

    Harbour, J; Vickie Williams, V; Tommy Edwards, T

    2007-07-02

    This report provides initial results on the measurement of heat of hydration of Saltstone mixes using isothermal calorimetry. The results were obtained using a recently purchased TAM Air Model 3116 Isothermal Conduction Calorimeter. Heat of hydration is an important property of Saltstone mixes. Greater amounts of heat will increase the temperature of the curing mix in the vaults and limit the processing rate. The heat of hydration also reflects the extent of the hydraulic reactions that turn the fluid mixture into a ''stone like'' solid and consequently impacts performance properties such as permeability. Determining which factors control these reactions, as monitored by the heat of hydration, is an important goal of the variability study. Experiments with mixes of portland cement in water demonstrated that the heats measured by this technique over a seven day period match very well with the literature values of (1) seven day heats of hydration using the standard test method for heat of hydration of hydraulic cement, ASTM C 186-05 and (2) heats of hydration measured using isothermal calorimetry. The heats of hydration of portland cement or blast furnace slag in a Modular Caustic Side Solvent Extraction Unit (MCU) simulant revealed that if the cure temperature is maintained at 25 C, the amount of heat released over a seven day period is roughly 62% less than the heat released by portland cement in water. Furthermore, both the blast furnace slag and the portland cement were found to be equivalent in heat production over the seven day period in MCU. This equivalency is due to the activation of the slag by the greater than 1 Molar free hydroxide ion concentration in the simulant. Results using premix (a blend of 10% cement, 45% blast furnace slag, and 45% fly ash) in MCU, Deliquification, Dissolution and Adjustment (DDA) and Salt Waste Processing Facility (SWPF) simulants reveal that the fly ash had not significantly reacted (undergone hydration reactions) after seven days (most likely less than 5%). There were clear differences in the amount of heat released and the peak times of heat release for the three different simulants. It turns out that SWPF simulant mixes give off greater heat than does MCU and DDA simulant mixes. The temperature dependence of the heat of hydration was measured by carrying out these measurements at 25, 40 and 55 C. In general, the peak times shifted to shorter times as the isothermal temperature increased and the amount of heat released was independent of temperature for DDA and MCU but slightly higher at higher temperatures for SWPF. The goal of this study is to apply this technique to the measurement of the heat of hydration of mixes that will be made as part of the variability study. It is important to understand which variables will impact (and to what extent) the amount of heat generated and the peak times for the heat release. Those variables that can be controlled can then be tuned to adjust the heat of hydration as long as the other properties are still acceptable. The first application of heat of hydration measurements to the variability study was completed and the results presented in this report. These measurements were made using Phase VI mixes (SWPF simulants) following a statistical design that included variation in the compositional and operational variables. Variation in both the amount of heat released and the peak times for the heat release were observed. The measured ranges were 23 Joules per gram of premix for the heat release and 23 hours for the peak time of heat release at 25 C. Linear models with high R{sup 2} values and no statistical evidence for lack of fit were developed that relate the amount of heat release and the peak time for heat release for the Phase VI mixes to certain variables. The amount of heat released was a function of the aluminate and portland cement concentrations as well as the temperature of mixing. The peak time for heat release was a function of aluminate, portland cement and total nitrate plus nitrite concentrations. A comparison was made of the measured values of heat release by isothermal calorimetry to a previous study of the measurement of the heat of hydration using adiabatic calorimetry by Steimke and Fowler. After 80 hours of reaction time, the two techniques provided heat release results that were roughly in the same range. However, additional experiments at higher isothermal temperatures will be required to see how well the two measurements agree for longer times. This is due to the higher temperatures that are experienced in adiabatic calorimetry ({approx}105 C).

  17. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2003-09-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing an 2400 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  18. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2003-06-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing an 2400 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  19. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2004-03-05

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the existing steam drive area to improve thermal efficiency. (7) Installing an 2400 foot insulated, subsurface harbor channel crossing to supply steam to an island location. (8) Test a novel alkaline steam completion technique to control well sanding problems and fluid entry profiles. (9) Advanced reservoir management through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation.

  20. Research Extension and Education Programs on Bio-based Energy Technologies and Products

    SciTech Connect (OSTI)

    Jackson, Sam; Harper, David; Womac, Al

    2010-03-02

    The overall objectives of this project were to provide enhanced educational resources for the general public, educational and development opportunities for University faculty in the Southeast region, and enhance research knowledge concerning biomass preprocessing and deconstruction. All of these efforts combine to create a research and education program that enhances the biomass-based industries of the United States. This work was broken into five primary objective areas: • Task A - Technical research in the area of biomass preprocessing, analysis, and evaluation. • Tasks B&C - Technical research in the areas of Fluidized Beds for the Chemical Modification of Lignocellulosic Biomass and Biomass Deconstruction and Evaluation. • Task D - Analyses for the non-scientific community to provides a comprehensive analysis of the current state of biomass supply, demand, technologies, markets and policies; identify a set of feasible alternative paths for biomass industry development and quantify the impacts associated with alternative path. • Task E - Efforts to build research capacity and develop partnerships through faculty fellowships with DOE national labs The research and education programs conducted through this grant have led to three primary results. They include: • A better knowledge base related to and understanding of biomass deconstruction, through both mechanical size reduction and chemical processing • A better source of information related to biomass, bioenergy, and bioproducts for researchers and general public users through the BioWeb system. • Stronger research ties between land-grant universities and DOE National Labs through the faculty fellowship program. In addition to the scientific knowledge and resources developed, funding through this program produced a minimum of eleven (11) scientific publications and contributed to the research behind at least one patent.

  1. Pilot-Scale Demonstration of Pefi's Oxygenated Transportation Fuels Production Technology

    SciTech Connect (OSTI)

    2005-05-01

    Coal-cleaning processes have been utilized to increase the heating value of coal by extracting ash-forming minerals in the coal. These processes involve the crushing or grinding of raw coal followed by physical separation processes, taking advantage of the density difference between carbonaceous particles and mineral particles. In addition to the desired increase in the heating value of coal, a significant reduction of the sulfur content of the coal fed to a combustion unit is effected by the removal of pyrite and other sulfides found in the mineral matter. WRI is assisting PulseWave to develop an alternate, more efficient method of liberating and separating the undesirable mineral matter from the carbonaceous matter in coal. The approach is based on PulseWave's patented resonance disintegration technology that reduces that particle size of materials by application of destructive resonance, shock waves, and vortex generating forces. Illinois No.5 coal, a Wyodak coal, and a Pittsburgh No.8 coal were processed using the resonance disintegration apparatus then subjected to conventional density separations. Initial microscopic results indicate that up to 90% of the pyrite could be liberated from the coal in the machine, but limitations in the density separations reduced overall effectiveness of contaminant removal. Approximately 30-80% of the pyritic sulfur and 30-50% of the mercury was removed from the coal. The three coals (both with and without the pyritic phase separated out) were tested in WRI's 250,000 Btu/hr Combustion Test Facility, designed to replicate a coal-fired utility boiler. The flue gases were characterized for elemental, particle bound, and total mercury in addition to sulfur. The results indicated that pre-combustion cleaning could reduce a large fraction of the mercury emissions.

  2. Methane Hydrate R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R&D Methane Hydrate R&D Natural gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of ...

  3. Gas hydrate detection and mapping on the US east coast

    SciTech Connect (OSTI)

    Ahlbrandt, T.S.; Dillon, W.P.

    1993-12-31

    Project objectives are to identify and map gas hydrate accumulations on the US eastern continental margin using remote sensing (seismic profiling) techniques and to relate these concentrations to the geological factors that-control them. In order to test the remote sensing methods, gas hydrate-cemented sediments will be tested in the laboratory and an effort will be made to perform similar physical tests on natural hydrate-cemented sediments from the study area. Gas hydrate potentially may represent a future major resource of energy. Furthermore, it may influence climate change because it forms a large reservoir for methane, which is a very effective greenhouse gas; its breakdown probably is a controlling factor for sea-floor landslides; and its presence has significant effect on the acoustic velocity of sea-floor sediments.

  4. Methane Hydrate Advisory Committee Meetings | Department of Energy

    Energy Savers [EERE]

    Meetings Methane Hydrate Advisory Committee Meetings May 7, 2015 Advisory Committee Meeting Presentations from the Advisory Committee Meeting May 21, 2014 Committee Recommendations to Secretary of Energy Advisory Committee Meeting Minutes, May 7, 2015 Federal Register Notice for May 7, 2015 Meeting May 15, 2014 Advisory Committee Meeting Federal Register Notice for May 15, 2014 Meeting Methane Hydrates Committee Meeting Agenda Advisory Committee Meeting Minutes, May 15, 2014 March 27-28, 2014

  5. Tricalcium aluminate hydration in additivated systems. A crystallographic

    Office of Scientific and Technical Information (OSTI)

    study by SR-XRPD (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Tricalcium aluminate hydration in additivated systems. A crystallographic study by SR-XRPD Citation Details In-Document Search Title: Tricalcium aluminate hydration in additivated systems. A crystallographic study by SR-XRPD Synchrotron radiation X-ray powder diffraction has been used to monitor the evolution of ettringite in C3A-gypsum synthetic mixture and in commercial cement systems

  6. Nucleation Rate Analysis of Methane Hydrate from Molecular Dynamics Simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yuhara, Daisuke; Barnes, Brian C.; Suh, Donguk; Knott, Brandon C.; Beckham, Gregg T.; Yasuoka, Kenji; Wu, David T.; Amadeu K. Sum

    2015-01-06

    Clathrate hydrates are solid crystalline structures most commonly formed from solutions that have nucleated to form a mixed solid composed of water and gas. Understanding the mechanism of clathrate hydrate nucleation is essential to grasp the fundamental chemistry of these complex structures and their applications. Molecular dynamics (MD) simulation is an ideal method to study nucleation at the molecular level because the size of the critical nucleus and formation rate occur on the nano scale. Moreover, various analysis methods for nucleation have been developed through MD to analyze nucleation. In particular, the mean first-passage time (MFPT) and survival probability (SP)more » methods have proven to be effective in procuring the nucleation rate and critical nucleus size for monatomic systems. This study assesses the MFPT and SP methods, previously used for monatomic systems, when applied to analyzing clathrate hydrate nucleation. Because clathrate hydrate nucleation is relatively difficult to observe in MD simulations (due to its high free energy barrier), these methods have yet to be applied to clathrate hydrate systems. In this study, we have analyzed the nucleation rate and critical nucleus size of methane hydrate using MFPT and SP methods from data generated by MD simulations at 255 K and 50 MPa. MFPT was modified for clathrate hydrate from the original version by adding the maximum likelihood estimate and growth effect term. The nucleation rates were calculated by MFPT and SP methods and are within 5%; the critical nucleus size estimated by the MFPT method was 50% higher, than values obtained through other more rigorous but computationally expensive estimates. These methods can also be extended to the analysis of other clathrate hydrates.« less

  7. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-01-31

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through September 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Fourth Quarter 2001 performing routine well work and reservoir surveillance on the Tar II-A post-steamflood and Tar V pilot steamflood projects. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. The project team ramped up well work activity from October 2000 through November 2001 to increase production and injection. In December, water injection well FW-88 was plug and abandoned and replaced by new well FW-295 into the ''D'' sands to accommodate the Port of Long Beach at their expense. Well workovers are planned for 2002 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The steamflood operation in the Tar V pilot project is mature and profitable. Recent production performance is below projections because of wellbore mechanical limitations that were being addressed in 2001. As the fluid production is hot, the pilot steamflood was converted to a hot waterflood project in June 2001.

  8. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2000-02-18

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through March 1999, project work has been completed related to data preparation, basic reservoir engineering, developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model, and a rock-log model, well drilling and completions, and surface facilities. Work is continuing on the stochastic geologic model, developing a 3-D stochastic thermal reservoir simulation model of the Fault Block IIA Tar (Tar II-A) Zone, and operational work and research studies to prevent thermal-related formation compaction. Thermal-related formation compaction is a concern of the project team due to observed surface subsidence in the local area above the steamflood project. Last quarter on January 12, the steamflood project lost its inexpensive steam source from the Harbor Cogeneration Plant as a result of the recent deregulation of electrical power rates in California. An operational plan was developed and implemented to mitigate the effects of the two situations. Seven water injection wells were placed in service in November and December 1998 on the flanks of the Phase 1 steamflood area to pressure up the reservoir to fill up the existing steam chest. Intensive reservoir engineering and geomechanics studies are continuing to determine the best ways to shut down the steamflood operations in Fault Block II while minimizing any future surface subsidence. The new 3-D deterministic thermal reservoir simulator model is being used to provide sensitivity cases to optimize production, steam injection, future flank cold water injection and reservoir temperature and pressure. According to the model, reservoir fill up of the steam chest at the current injection rate of 28,000 BPD and gross and net oil production rates of 7,700 BPD and 750 BOPD (injection to production ratio of 4) will occur in October 1999. At that time, the reservoir should act more like a waterflood and production and cold water injection can be operated at lower net injection rates to be determined. Modeling runs developed this quarter found that varying individual well injection rates to meet added production and local pressure problems by sub-zone could reduce steam chest fill-up by up to one month.

  9. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-04-30

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through December 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. During the First Quarter 2002, the project team developed an accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project and began implementing the associated well work in March. The Tar V pilot steamflood project will be converted to post-steamflood cold water injection in April 2002. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. Most of the 2001 well work resulted in maintaining oil and gross fluid production and water injection rates. Reservoir pressures in the ''T'' and ''D'' sands are at 88% and 91% hydrostatic levels, respectively. Well work during the first quarter and plans for 2002 are described in the Reservoir Management section. The steamflood operation in the Tar V pilot project is mature and profitable. Recent production performance has been below projections because of wellbore mechanical limitations that have been addressed during this quarter. As the fluid production temperatures were beginning to exceed 350 F, our self-imposed temperature limit, the pilot steamflood was converted to a hot waterflood project in June 2001 and will be converted to cold water injection next quarter.

  10. Hydrate Evolution in Response to Ongoing Environmental Shifts

    SciTech Connect (OSTI)

    Rempel, Alan

    2015-12-31

    Natural gas hydrates have the potential to become a vital domestic clean-burning energy source. However, past changes in environmental conditions have caused hydrates to become unstable and trigger both massive submarine landslides and the development of crater-like pockmarks, thereby releasing methane into the overlying seawater and atmosphere, where it acts as a powerful greenhouse gas. This project was designed to fill critical gaps in our understanding of domestic hydrate resources and improve forecasts for their response to environmental shifts. Project work can be separated into three interrelated components, each involving the development of predictive mathematical models. The first project component concerns the role of sediment properties on the development and dissociation of concentrated hydrate anomalies. To this end, we developed numerical models to predict equilibrium solubility of methane in twophase equilibrium with hydrate as a function of measureable porous medium characteristics. The second project component concerned the evolution of hydrate distribution in heterogeneous reservoirs. To this end, we developed numerical models to predict the growth and decay of anomalies in representative physical environments. The third project component concerned the stability of hydrate-bearing slopes under changing environmental conditions. To this end, we developed numerical treatments of pore pressure evolution and consolidation, then used "infinite-slope" analysis to approximate the landslide potential in representative physical environments, and developed a "rate-and-state" frictional formulation to assess the stability of finite slip patches that are hypothesized to develop in response to the dissociation of hydrate anomalies. The increased predictive capabilities that result from this work provide a framework for interpreting field observations of hydrate anomalies in terms of the history of environmental forcing that led to their development. Moreover, by taking explicit account of anomaly dissociation, project results are designed to help improve forecasts for changes in slope stability that could pose significant threats to energy infrastructure, disrupt hydrate reserves, and pollute the atmosphere with vast quantities of methane. This report presents the details of our work and outlines some of the highlights from our findings.

  11. Effect of under-inhibition with methanol and ethylene glycol on the hydrate control process

    SciTech Connect (OSTI)

    Yousif, M.H.

    1996-12-31

    Hydrate control can be achieved by chemical injection. Currently, methanol and ethylene glycol are the most widely used inhibitors in offshore hydrate control operations. To achieve effective hydrate inhibition, a sufficient amount of inhibitor must be injected to shift the thermodynamic equilibrium condition for hydrate formation outside the pipeline operating pressure and temperature. Recently published field experiments showed that hydrate blockages form more readily in under-inhibited systems than in systems completely without inhibitor. A laboratory study is conducted to determine the effect of low concentration (1--5wt%) methanol and ethylene glycol on the hydrate formation process. The results show that, although these chemicals are effective hydrate inhibitors when added in sufficient quantities, they actually enhance the rate of hydrate formation when added at low concentrations to the water. Furthermore, the presence of these chemicals seems to affect the size of the forming hydrate particles.

  12. Dynamics of lysozyme and its hydration water under electric field

    SciTech Connect (OSTI)

    Favi, Pelagie M; Zhang, Qiu; O'Neill, Hugh Michael; Mamontov, Eugene; Omar Diallo, Souleymane; Palmer, Jeremy

    2014-01-01

    The effects of static electric field on the dynamics of lysozyme and its hydration water have been investigated by means of incoherent quasi-elastic neutron scattering (QENS). Measurements were performed on lysozyme samples, hydrated respectively with heavy water (D2O) to capture the protein dynamics, and with light water (H2O), to probe the dynamics of the hydration shell, in the temperature range from 210 < T < 260 K. The hydration fraction in both cases was about 0.38 gram of water per gram of dry protein. The field strengths investigated were respectively 0 kV/mm and 2 kV/mm ( 2 106 V/m) for the protein hydrated with D2O and 0 kV and 1 kV/mm for the H2O-hydrated counterpart. While the overall internal protons dynamics of the protein appears to be unaffected by the application of electric field up to 2 kV/mm, likely due to the stronger intra-molecular interactions, there is also no appreciable quantitative enhancement of the diffusive dynamics of the hydration water, as would be anticipated based on our recent observations in water confined in silica pores under field values of 2.5 kV/mm. This may be due to the difference in surface interactions between water and the two adsorption hosts (silica and protein), or to the existence of a critical threshold field value Ec 2 3 kV/mm for increased molecular diffusion, for which electrical breakdown is a limitation for our sample.

  13. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank R. Rack

    2006-09-20

    Cooperative Agreement DE-FC26-01NT41329 between Joint Oceanographic Institutions and DOE-NETL was divided into two phases based on successive proposals and negotiated statements of work pertaining to activities to sample and characterize methane hydrates on ODP Leg 204 (Phase 1) and on IODP Expedition 311 (Phase 2). The Phase 1 Final Report was submitted to DOE-NETL in April 2004. This report is the Phase 2 Final Report to DOE-NETL. The primary objectives of Phase 2 were to sample and characterize methane hydrates using the systems and capabilities of the D/V JOIDES Resolution during IODP Expedition 311, to enable scientists the opportunity to establish the mass and distribution of naturally occurring gas and gas hydrate at all relevant spatial and temporal scales, and to contribute to the DOE methane hydrate research and development effort. The goal of the work was to provide expanded measurement capabilities on the JOIDES Resolution for a dedicated hydrate cruise to the Cascadia continental margin off Vancouver Island, British Columbia, Canada (IODP Expedition 311) so that hydrate deposits in this region would be well characterized and technology development continued for hydrate research. IODP Expedition 311 shipboard activities on the JOIDES Resolution began on August 28 and were concluded on October 28, 2005. The statement of work for this project included three primary tasks: (1) research management oversight, provided by JOI; (2) mobilization, deployment and demobilization of pressure coring and core logging systems, through a subcontract with Geotek Ltd.; and, (3) mobilization, deployment and demobilization of a refrigerated container van that will be used for degassing of the Pressure Core Sampler and density logging of these pressure cores, through a subcontract with the Texas A&M Research Foundation (TAMRF). Additional small tasks that arose during the course of the research were included under these three primary tasks in consultation with the DOE-NETL Program Manager. All tasks outlined in the original statement of work were accomplished except for the deployment and use of the X-ray CT system under Subtask 2-2. This reduction in scope provided resources that were applied to other activities to support the overall project. Post-expedition analysis of results and report writing will continue beyond this reporting period, however, all field deployments associated with this project have been successfully concluded as of this writing.

  14. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of...

  15. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-11-01

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through June 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Third Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. The project team ramped up well work activity from October 2000 to September 2001 to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being addressed in 2001.

  16. Hydration water dynamics and instigation of protein structuralrelaxation

    SciTech Connect (OSTI)

    Russo, Daniela; Hura, Greg; Head-Gordon, Teresa

    2003-09-01

    Until a critical hydration level is reached, proteins do not function. This critical level of hydration is analogous to a similar lack of protein function observed for temperatures below a dynamical temperature range of 180-220K that also is connected to the dynamics of protein surface water. Restoration of some enzymatic activity is observed in partially hydrated protein powders, sometimes corresponding to less than a single hydration layer on the protein surface, which indicates that the dynamical and structural properties of the surface water is intimately connected to protein stability and function. Many elegant studies using both experiment and simulation have contributed important information about protein hydration structure and timescales. The molecular mechanism of the solvent motion that is required to instigate the protein structural relaxation above a critical hydration level or transition temperature has yet to be determined. In this work we use experimental quasi-elastic neutron scattering (QENS) and molecular dynamics simulation to investigate hydration water dynamics near a greatly simplified protein system. We consider the hydration water dynamics near the completely deuterated N-acetyl-leucine-methylamide (NALMA) solute, a hydrophobic amino acid side chain attached to a polar blocked polypeptide backbone, as a function of concentration between 0.5M-2.0M under ambient conditions. We note that roughly 50-60% of a folded protein's surface is equally distributed between hydrophobic and hydrophilic domains, domains whose lengths are on the order of a few water diameters, that justify our study of hydration dynamics of this simple model protein system. The QENS experiment was performed at the NIST Center for Neutron Research, using the disk chopper time of flight spectrometer (DCS). In order to separate the translational and rotational components in the spectra, two sets of experiments were carried out using different incident neutron wavelengths of 7.5{angstrom} and 5.5{angstrom} to give two different time resolutions. All the spectra have been measure at room temperature. The spectra were corrected for the sample holder contribution and normalized using the vanadium standard. The resulting data were analyzed with DAVE programs (http://www.ncnr.nist.gov/dave/). The AMBER force field and SPCE water model were used for modeling the NALMA solute and water, respectively. For the analysis of the water dynamics in the NALMA aqueous solutions, we performed simulations of a dispersed solute configuration consistent with our previous structural analysis, where we had primarily focused on the structural organization of these peptide solutions and their connection to protein folding. Further details of the QENS experiment and molecular dynamics simulations are reported elsewhere.

  17. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-05-07

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through September 2000, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood projects. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone so the project team could use the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. The project team spent the fourth quarter 2000 performing well work and reservoir surveillance on the Tar II-A post-steamflood project and the Tar V horizontal well steamflood pilot. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being evaluated.

  18. Integrating Natural Gas Hydrates in the Global Carbon Cycle

    SciTech Connect (OSTI)

    David Archer; Bruce Buffett

    2011-12-31

    We produced a two-dimensional geological time- and basin-scale model of the sedimentary margin in passive and active settings, for the simulation of the deep sedimentary methane cycle including hydrate formation. Simulation of geochemical data required development of parameterizations for bubble transport in the sediment column, and for the impact of the heterogeneity in the sediment pore fluid flow field, which represent new directions in modeling methane hydrates. The model is somewhat less sensitive to changes in ocean temperature than our previous 1-D model, due to the different methane transport mechanisms in the two codes (pore fluid flow vs. bubble migration). The model is very sensitive to reasonable changes in organic carbon deposition through geologic time, and to details of how the bubbles migrate, in particular how efficiently they are trapped as they rise through undersaturated or oxidizing chemical conditions and the hydrate stability zone. The active margin configuration reproduces the elevated hydrate saturations observed in accretionary wedges such as the Cascadia Margin, but predicts a decrease in the methane inventory per meter of coastline relative to a comparable passive margin case, and a decrease in the hydrate inventory with an increase in the plate subduction rate.

  19. Methane Hydrate Field Program. Development of a Scientific Plan for a Methane Hydrate-Focused Marine Drilling, Logging and Coring Program

    SciTech Connect (OSTI)

    Collett, Tim; Bahk, Jang-Jun; Frye, Matt; Goldberg, Dave; Husebo, Jarle; Koh, Carolyn; Malone, Mitch; Shipp, Craig; Torres, Marta; Myers, Greg; Divins, David; Morell, Margo

    2013-12-31

    This topical report represents a pathway toward better understanding of the impact of marine methane hydrates on safety and seafloor stability and future collection of data that can be used by scientists, engineers, managers and planners to study climate change and to assess the feasibility of marine methane hydrate as a potential future energy resource. Our understanding of the occurrence, distribution and characteristics of marine methane hydrates is incomplete; therefore, research must continue to expand if methane hydrates are to be used as a future energy source. Exploring basins with methane hydrates has been occurring for over 30 years, but these efforts have been episodic in nature. To further our understanding, these efforts must be more regular and employ new techniques to capture more data. This plan identifies incomplete areas of methane hydrate research and offers solutions by systematically reviewing known methane hydrate “Science Challenges” and linking them with “Technical Challenges” and potential field program locations.

  20. ENDF/B-VII.1 Nuclear Data for Science and Technology: Cross Sections, Covariances, Fission Product Yields and Decay Data

    SciTech Connect (OSTI)

    G. Palmiotti

    2011-12-01

    The ENDF/B-VII.1 library is our latest recommended evaluated nuclear data file for use in nuclear science and technology applications, and incorporates advances made in the five years since the release of ENDF/B-VII.0. These advances focus on neutron cross sections, covariances, fission product yields and decay data, and represent work by the US Cross Section Evaluation Working Group (CSEWG) in nuclear data evaluation that utilizes developments in nuclear theory, modeling, simulation, and experiment. The principal advances in the new library are: (1) An increase in the breadth of neutron reaction cross section coverage, extending from 393 nuclides to 418 nuclides; (2) Covariance uncertainty data for 185 of the most important nuclides, as documented in companion papers in this edition; (3) R-matrix analyses of neutron reactions on light nuclei, including isotopes of He, Li, and Be; (4) Resonance parameter analyses at lower energies and statistical high energy reactions at higher energies for isotopes of F, Cl, K, Ti, V, Mn, Cr, Ni, Zr and W; (5) Modifications to thermal neutron reactions on fission products (isotopes of Mo, Tc, Rh, Ag, Cs, Nd, Sm, Eu) and neutron absorber materials (Cd, Gd); (6) Improved minor actinide evaluations for isotopes of U, Np, Pu, and Am (we are not making changes to the major actinides 235,238U and 239Pu at this point, except for delayed neutron data, and instead we intend to update them after a further period of research in experiment and theory), and our adoption of JENDL-4.0 evaluations for isotopes of Cm, Bk, Cf, Es, Fm, and some other minor actinides; (7) Fission energy release evaluations; (8) Fission product yield advances for fission-spectrum neutrons and 14 MeV neutrons incident on 239Pu; and (9) A new Decay Data sublibrary. Integral validation testing of the ENDF/B-VII.1 library is provided for a variety of quantities: For nuclear criticality, the VII.1 library maintains the generally-good performance seen for VII.0 for a wide range of MCNP simulations of criticality benchmarks, with improved performance coming from new structural material evaluations, especially for Ti, Mn, Cr, Zr and W. For Be we see some improvements although the fast assembly data appear to be mutually inconsistent. Actinide cross section updates are also assessed through comparisons of fission and capture reaction rate measurements in critical assemblies and fast reactors. We describe the cross section evaluations that have been updated for ENDF/B-VII.1 and the measured data and calculations that motivated the changes, and therefore this paper augments the ENDF/B-VII.0 publication [1].

  1. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-05-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through March 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Second Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A steamflood reservoirs have been operated over fifteen months at relatively stable pressures, due in large part to the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase in January 1999. Starting in the Fourth Quarter 2000, the project team has ramped up activity to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being addressed in 2001. Much of the second quarter was spent writing DOE annual and quarterly reports to stay current with contract requirements.

  2. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of cultivation systems.

  3. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-11-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through June 2002, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V post-steamflood pilot and Tar II-A post-steamflood projects. During the Third Quarter 2002, the project team essentially completed implementing the accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project developed in March 2002 and is proceeding with additional related work. The project team has completed developing laboratory research procedures to analyze the sand consolidation well completion technique and will initiate work in the fourth quarter. The Tar V pilot steamflood project terminated hot water injection and converted to post-steamflood cold water injection on April 19, 2002. Proposals have been approved to repair two sand consolidated horizontal wells that sanded up, Tar II-A well UP-955 and Tar V well J-205, with gravel-packed inner liner jobs to be performed next quarter. Other well work to be performed next quarter is to convert well L-337 to a Tar V water injector and to recomplete vertical well A-194 as a Tar V interior steamflood pattern producer. Plans have been approved to drill and complete well A-605 in Tar V in the first quarter 2003. Plans have been approved to update the Tar II-A 3-D deterministic reservoir simulation model and run sensitivity cases to evaluate the accelerated oil recovery and reservoir cooling plan. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. Well work related to the Tar II-A accelerated oil recovery and reservoir cooling plan began in March 2002 with oil production increasing from 1009 BOPD in the first quarter to 1145 BOPD in the third quarter. Reservoir pressures have been increased during the quarter from 88% to 91% hydrostatic levels in the ''T'' sands and from 91% to 94% hydrostatic levels in the ''D'' sands. Well work during the quarter is described in the Reservoir Management section. The post-steamflood production performance in the Tar V pilot project has been below projections because of wellbore mechanical limitations and the loss of a horizontal producer a second time to sand inflow that are being addressed in the fourth quarter. As the fluid production temperatures exceeded 350 F, our self-imposed temperature limit, the pilot steamflood was converted to a hot waterflood project in June 2001 and converted to cold water injection on April 19, 2002.

  4. Protein structure and hydration probed by SANS and osmotic stress

    SciTech Connect (OSTI)

    Rau, Dr. Donald [National Institutes of Health

    2008-01-01

    Interactions governing protein folding, stability, recognition, and activity are mediated by hydration. Here, we use small-angle neutron scattering coupled with osmotic stress to investigate the hydration of two proteins, lysozyme and guanylate kinase (GK), in the presence of solutes. By taking advantage of the neutron contrast variation that occurs upon addition of these solutes, the number of protein-associated (solute-excluded) water molecules can be estimated from changes in both the zero-angle scattering intensity and the radius of gyration. Poly(ethylene glycol) exclusion varies with molecular weight. This sensitivity can be exploited to probe structural features such as the large internal GK cavity. For GK, small-angle neutron scattering is complemented by isothermal titration calorimetry with osmoticstress to also measure hydration changes accompanying ligand binding. These results provide a framework for studying other biomolecular systems and assemblies using neutron scattering together with osmotic stress.

  5. Bioconversion Technologies | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Bioconversion Technologies Place: United Kingdom Sector: Biofuels Product: Second-generation biofuels technology developer References: Bioconversion...

  6. Hydrocarbon Technologies | Open Energy Information

    Open Energy Info (EERE)

    Technologies Jump to: navigation, search Name: Hydrocarbon Technologies Place: Lawrenceville, New Jersey Zip: 8648 Sector: Efficiency Product: String representation...

  7. TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of...

    Office of Scientific and Technical Information (OSTI)

    System Behavior in Hydrate-Bearing Geologic Media Citation Details In-Document Search Title: TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in ...

  8. Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico

    SciTech Connect (OSTI)

    Collett, T.S.; Riedel, M.; Cochran, J.R.; Boswell, R.M.; Kumar, Pushpendra; Sathe, A.V.

    2008-07-01

    Studies of geologic and geophysical data from the offshore of India have revealed two geologically distinct areas with inferred gas hydrate occurrences: the passive continental margins of the Indian Peninsula and along the Andaman convergent margin. The Indian National Gas Hydrate Program (NGHP) Expedition 01 was designed to study the occurrence of gas hydrate off the Indian Peninsula and along the Andaman convergent margin with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. NGHP Expedition 01 established the presence of gas hydrates in Krishna- Godavari, Mahanadi and Andaman basins. The expedition discovered one of the richest gas hydrate accumulations yet documented (Site 10 in the Krishna-Godavari Basin), documented the thickest and deepest gas hydrate stability zone yet known (Site 17 in Andaman Sea), and established the existence of a fully-developed gas hydrate system in the Mahanadi Basin (Site 19).

  9. Promotion of n-Butane isomerization activity by hydration of sulfated zirconia

    SciTech Connect (OSTI)

    Gonzalez, M.R.; Kobe, J.M.; Fogash, K.B.; Dumesic, J.A.

    1996-05-01

    The effects of sulfated zirconia catalyst hydration on the activity for n-butane isomerization is reported. The catalytic activity of of a partially hydrated catalyst is enhanced. 66 refs., 11 figs.

  10. Microsoft Word - NETL-TRS-6-2015 Detection of Hydrates on Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detection of Hydrates on Gas Bubbles during a Subsea OilGas Leak 22 July 2015 Office of ... of Hydrates on Gas Bubbles during a Subsea OilGas Leak; NETL-TRS-6- 2015; EPAct Technical ...

  11. TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of...

    Office of Scientific and Technical Information (OSTI)

    User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media Citation Details In-Document Search Title: TOUGH+Hydrate v1.0 User's Manual: A Code ...

  12. Green Purchasing & Green Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchasing & Technology Goals 6 & 7: Green Purchasing & Green Technology Our goal is to purchase and use environmentally sustainable products whenever possible and to implement...

  13. Geothermal Technologies Office: Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geothermal Technologies Office Details Bookmark & Share View Related Welcome to the Energy Department's Geothermal Technologies Office Publication and Product Library. Here...

  14. Up to $1.15 Million Available to Small Businesses for New Products or Technologies that Expand Geothermal Markets

    Broader source: Energy.gov [DOE]

    The Energy Department announced funds targeted to small businesses in two separate geothermal subtopics: a) innovations to develop under-utilized markets and b) a technology transfer opportunity...

  15. Phase I (CATTS Theory), Phase II (Milne Point), Phase III (Hydrate Ridge)

    SciTech Connect (OSTI)

    2009-10-31

    This study introduces a new type of “cumulative seismic attribute” (CATT) which quantifies gas hydrates resources in Hydrate Ridge offshore Oregon. CATT is base on case-specific transforms that portray hydrated reservoir properties. In this study we used a theoretical rock physics model to correct measured velocity log data.

  16. Methane Hydrate Research and Development Act of 2000 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 PDF icon Methane Hydrate Research and Development Act of 2000 More Documents & Publications NATIONAL DEFENSE AUTHORIZATION ACT FOR FISCAL YEAR 2000 E:\PUBLAW\PUBL404.106 Intelligence Reform and Terrorism Prevention Act - December 17, 2004

  17. Study on small-strain behaviours of methane hydrate sandy sediments using discrete element method

    SciTech Connect (OSTI)

    Yu Yanxin; Cheng Yipik; Xu Xiaomin; Soga, Kenichi

    2013-06-18

    Methane hydrate bearing soil has attracted increasing interest as a potential energy resource where methane gas can be extracted from dissociating hydrate-bearing sediments. Seismic testing techniques have been applied extensively and in various ways, to detect the presence of hydrates, due to the fact that hydrates increase the stiffness of hydrate-bearing sediments. With the recognition of the limitations of laboratory and field tests, wave propagation modelling using Discrete Element Method (DEM) was conducted in this study in order to provide some particle-scale insights on the hydrate-bearing sandy sediment models with pore-filling and cementation hydrate distributions. The relationship between shear wave velocity and hydrate saturation was established by both DEM simulations and analytical solutions. Obvious differences were observed in the dependence of wave velocity on hydrate saturation for these two cases. From the shear wave velocity measurement and particle-scale analysis, it was found that the small-strain mechanical properties of hydrate-bearing sandy sediments are governed by both the hydrate distribution patterns and hydrate saturation.

  18. The thermodynamic properties of hydrated γ-Al{sub 2}O{sub 3} nanoparticles

    SciTech Connect (OSTI)

    Spencer, Elinor C.; Ross, Nancy L.; Huang, Baiyu; Woodfield, Brian F.; Parker, Stewart F.; Kolesnikov, Alexander I.

    2013-12-28

    In this paper we report a combined calorimetric and inelastic neutron scattering (INS) study of hydrated γ-Al{sub 2}O{sub 3} (γ-alumina) nanoparticles. These complementary techniques have enabled a comprehensive evaluation of the thermodynamic properties of this technological and industrially important metal oxide to be achieved. The isobaric heat capacity (C{sub p}) data presented herein provide further critical insights into the much-debated chemical composition of γ-alumina nanoparticles. Furthermore, the isochoric heat capacity (C{sub v}) of the surface water, which is so essential to the stability of all metal-oxides at the nanoscale, has been extracted from the high-resolution INS data and differs significantly from that of ice‑Ih due to the dominating influence of strong surface-water interactions. This study also encompassed the analysis of four γ-alumina samples with differing pore diameters [4.5 (1), 13.8 (2), 17.9 (3), and 27.2 nm (4)], and the results obtained allow us to unambiguously conclude that the water content and pore size have no influence on the thermodynamic behaviour of hydrated γ-alumina nanoparticles.

  19. Briza Technologies | Open Energy Information

    Open Energy Info (EERE)

    Briza Technologies Jump to: navigation, search Name: Briza Technologies Place: Hillsborough, New Jersey Zip: 8844 Sector: Wind energy Product: Developing wind turbine technology....

  20. EKB Technology | Open Energy Information

    Open Energy Info (EERE)

    EKB Technology Jump to: navigation, search Name: EKB Technology Place: Oxfordshire, United Kingdom Product: Developer of a new bioprocessing technology. Coordinates: 51.813938,...

  1. Rubicon Technology | Open Energy Information

    Open Energy Info (EERE)

    Rubicon Technology Jump to: navigation, search Name: Rubicon Technology Place: Franklin Park, Illinois Zip: 60131 Product: Rubicon Technology makes a sapphire substrates for use in...

  2. PCN Technology | Open Energy Information

    Open Energy Info (EERE)

    PCN Technology Jump to: navigation, search Name: PCN Technology Place: San Diego, California Zip: CA 92127 Product: California-based smart grid technology developer. References:...

  3. Topanga Technologies | Open Energy Information

    Open Energy Info (EERE)

    Technologies Place: Canoga Park, California Zip: 91303 Product: Stealth-mode high-intensity discharge (HID) lighting technology developer. References: Topanga Technologies1...

  4. Time-dependent water dynamics in hydrated uranyl fluoride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miskowiec, Andrew J.; Anderson, Brian B.; Herwig, Kenneth W.; Huq, Ashfia; Mamontov, Eugene; Rondinone, Adam; Trowbridge, Lee D.

    2015-09-15

    In this study, uranyl fluoride is a three-layer, hexagonal structure with significant stacking disorder in the c-direction. It supports a range of unsolved ‘thermodynamic’ hydrates with 0–2.5 water molecules per uranium atom, and perhaps more. However, the relationship between water, hydrate crystal structures, and thermodynamic results, collectively representing the chemical pathway through these hydrate structures, has not been sufficiently elucidated. We used high-resolution quasielastic neutron scattering to study the dynamics of water in partially hydrated uranyl fluoride powder over the course of 4 weeks under closed conditions. The spectra are composed of two quasielastic components: one is associated with translationalmore » diffusive motion of water that is approximately five to six times slower than bulk water, and the other is a slow (on the order of 2–300 ps), spatially bounded water motion. The translational component represents water diffusing between the weakly bonded layers in the crystal, while the bounded component may represent water trapped in subnanometre ‘pockets’ formed by the space between uranium-centred polymerisation units. Complementary neutron diffraction measurements do not show any significant structural changes, suggesting that a chemical conversion of the material does not occur in the thermodynamically isolated system on this timescale.« less

  5. Time-dependent water dynamics in hydrated uranyl fluoride

    SciTech Connect (OSTI)

    Miskowiec, Andrew J.; Anderson, Brian B.; Herwig, Kenneth W.; Huq, Ashfia; Mamontov, Eugene; Rondinone, Adam; Trowbridge, Lee D.

    2015-09-15

    In this study, uranyl fluoride is a three-layer, hexagonal structure with significant stacking disorder in the c-direction. It supports a range of unsolved ‘thermodynamic’ hydrates with 0–2.5 water molecules per uranium atom, and perhaps more. However, the relationship between water, hydrate crystal structures, and thermodynamic results, collectively representing the chemical pathway through these hydrate structures, has not been sufficiently elucidated. We used high-resolution quasielastic neutron scattering to study the dynamics of water in partially hydrated uranyl fluoride powder over the course of 4 weeks under closed conditions. The spectra are composed of two quasielastic components: one is associated with translational diffusive motion of water that is approximately five to six times slower than bulk water, and the other is a slow (on the order of 2–300 ps), spatially bounded water motion. The translational component represents water diffusing between the weakly bonded layers in the crystal, while the bounded component may represent water trapped in subnanometre ‘pockets’ formed by the space between uranium-centred polymerisation units. Complementary neutron diffraction measurements do not show any significant structural changes, suggesting that a chemical conversion of the material does not occur in the thermodynamically isolated system on this timescale.

  6. DOE Leads National Research Program in Gas Hydrates

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy today told Congress the agency is leading a nationwide program in search of naturally occurring natural gas hydrates - a potentially significant storehouse of methane--with far reaching implications for the environment and the nation's future energy supplies.

  7. Ethane enrichment and propane depletion in subsurface gases indicate gas hydrate occurrence in marine sediments at southern Hydrate Ridge offshore Oregon

    SciTech Connect (OSTI)

    Milkov, Alexei V.; Claypool, G E.; Lee, Young-Joo; Torres, Marta E.; Borowski, W S.; Tomaru, H; Sassen, Roger; Long, Philip E.

    2004-07-02

    The recognition of finely disseminated gas hydrate in deep marine sediments heavily depends on various indirect techniques because this mineral quickly decomposes upon recovery from in situ pressure and temperature conditions. Here, we discuss molecular properties of closely spaced gas voids (formed as a result of core recovery) and gas hydrates from an area of relatively low gas flux at the flanks of the southern Hydrate Ridge Offshore Oregon (ODP Sites 1244, 1245 and 1247).

  8. Effect of bubble size and density on methane conversion to hydrate

    SciTech Connect (OSTI)

    Leske, J.; Taylor, C.E.; Ladner, E.P.

    2007-03-01

    Research is underway at NETL to understand the physical properties of methane hydrates. One area of investigation is the storage of methane as methane hydrates. An economical and efficient means of storing methane in hydrates opens many commercial opportunities such as transport of stranded gas, off-peak storage of line gas, etc.We have observed during our investigations that the ability to convert methane to methane hydrate is enhanced by foaming of the methanewater solution using a surfactant. The density of the foam, along with the bubble size, is important in the conversion of methane to methane hydrate.

  9. Global Assessment of Hydrogen Technologies – Tasks 3 & 4 Report Economic, Energy, and Environmental Analysis of Hydrogen Production and Delivery Options in Select Alabama Markets: Preliminary Case Studies

    SciTech Connect (OSTI)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Gillette, Jerry; Elgowainy, Amgad; Mintz, Marianne

    2007-12-01

    This report documents a set of case studies developed to estimate the cost of producing, storing, delivering, and dispensing hydrogen for light-duty vehicles for several scenarios involving metropolitan areas in Alabama. While the majority of the scenarios focused on centralized hydrogen production and pipeline delivery, alternative delivery modes were also examined. Although Alabama was used as the case study for this analysis, the results provide insights into the unique requirements for deploying hydrogen infrastructure in smaller urban and rural environments that lie outside the DOE’s high priority hydrogen deployment regions. Hydrogen production costs were estimated for three technologies – steam-methane reforming (SMR), coal gasification, and thermochemical water-splitting using advanced nuclear reactors. In all cases examined, SMR has the lowest production cost for the demands associated with metropolitan areas in Alabama. Although other production options may be less costly for larger hydrogen markets, these were not examined within the context of the case studies.

  10. DOE Announces Selections for Solid-State Lighting Core Technology and Product Development Funding Opportunities (Round 3)

    Broader source: Energy.gov [DOE]

    The National Energy Technology Laboratory (NETL), on behalf of the U.S. Department of Energy (DOE), is pleased to announce eight selections in response to the Solid-State Lighting (SSL) Core...

  11. Vehicle Technologies Office Merit Review 2015: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  12. Vehicle Technologies Office Merit Review 2014: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  13. DOE Announces Selections for Solid-State Lighting Core Technology and Product Development Funding Opportunities (Round 4)

    Broader source: Energy.gov [DOE]

    The National Energy Technology Laboratory (NETL), on behalf of the U.S. Department of Energy (DOE), is pleased to announce 13 selections in response to the Solid-State Lighting (SSL) Core...

  14. Hydrogen Pathways: Updated Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Ten Hydrogen Production, Delivery, and Distribution Scenarios

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Pathways Updated Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Ten Hydrogen Production, Delivery, and Distribution Scenarios T. Ramsden, M. Ruth, V. Diakov National Renewable Energy Laboratory M. Laffen, T.A. Timbario Alliance Technical Services, Inc. Technical Report NREL/TP-6A10-60528 March 2013 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable

  15. Semi-Annual Technical Progress Report of Radioisotope Power System Materials Production and Technology Program Tasks for April 1, 2002 Through September 20, 2002

    SciTech Connect (OSTI)

    Moore, J.P.

    2002-12-03

    The Office of Space and Defense Power Systems of the Department of Energy (DOE) provides Radioisotope Power Systems (RPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. For the Cassini Mission, for example, ORNL was involved in the production of carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVS). This report has been divided into three sections to reflect program guidance from the Office of Space and Defense Power Systems for fiscal year (FY) 2002. The first section deals primarily with maintenance of the capability to produce flight quality (FQ) CBCF insulator sets, iridium alloy blanks and foil, and CVS. In all three cases, production maintenance is assured by the manufacture of limited quantities of FQ components. The second section deals with several technology activities to improve the manufacturing processes, characterize materials, or to develop technologies for new radioisotope power systems. The last section is dedicated to studies related to the production of {sup 238}Pu.

  16. Annual Technical Progress Report of Radioisotope Power System Materials Production and Technology Program Tasks for October 1, 2002 Through September 30, 2003

    SciTech Connect (OSTI)

    King, J.F.

    2004-05-18

    The Office of Space and Defense Power Systems of the Department of Energy (DOE) provides Radioisotope Power Systems (RPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. For the Cassini Mission, for example, ORNL was involved in the production of carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVS). This report has been divided into three sections to reflect program guidance from the Office of Space and Defense Power Systems for fiscal year (FY) 2003. The first section deals primarily with maintenance of the capability to produce flight quality (FQ) CBCF insulator sets, iridium alloy blanks and foil, and CVS. In all three cases, production maintenance is assured by the manufacture of limited quantities of FQ components. The second section deals with several technology activities to improve the manufacturing processes, characterize materials, or to develop technologies for new radioisotope power systems. The last section is dedicated to studies related to the production of {sup 238}Pu.

  17. Productization and Manufacturing Scaling of High-Efficiency Solar Cell and Module Products Based on a Disruptive Low-Cost, Mono-Crystalline Technology: Final Technical Progress Report, April 1, 2009 - December 30, 2010

    SciTech Connect (OSTI)

    Fatemi, H.

    2012-07-01

    Final report for PV incubator subcontract with Solexel, Inc. The purpose of this project was to develop Solexel's Unique IP, productize it, and transfer it to manufacturing. Silicon constitutes a significant fraction of the total solar cell cost, resulting in an industry-wide drive to lower silicon usage. Solexel's disruptive Solar cell structure got around these challenges and promised superior light trapping, efficiency and mechanical strength, despite being significantly thinner than commercially available cells. Solexel's successful participation in this incubator project became evident as the company is now moving into commercial production and position itself to be competitive for the next Technology Pathway Partnerships (TPP) funding opportunity.

  18. Geomechanical Performance of Hydrate-Bearing Sediments in Offshore Environments

    SciTech Connect (OSTI)

    Stephen A. Holditch

    2006-12-31

    The main objective of this study is to develop the necessary knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus is on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. To achieve this objective, we have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. To be sure our geomechanical modeling is realistic, we are also investigating the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. In Phase II of the project, we will review all published core data and generate additional core data to verify the models. To generate data for our models, we are using data from the literature and we will be conducting laboratory studies in 2007 that generate data to (1) evaluate the conceptual pore-scale models, (2) calibrate the mathematical models, (3) determine dominant relations and critical parameters defining the geomechanical behavior of HBS, and (4) establish relationships between the geomechanical status of HBS and the corresponding geophysical signature. The milestones for Phase I of this project are given as follows: Literature survey on typical sediments containing gas hydrates in the ocean (TAMU); Recommendations on how to create typical sediments in the laboratory (TAMU); Demonstrate that typical sediments can be created in a repeatable manner in the laboratory and gas hydrates can be created in the pore space (TAMU); Develop a conceptual pore-scale model based on available data and reports (UCB); Test the developed pore-scale concepts on simple configurations and verify the results against known measurements and observations (UCB); Complete the FLAC3D routines that will be linked with the reservoir model (LBNL); Complete the TOUGH+/HYDRATE modifications and extensions (LBNL); Complete the TOUGH+/FLAC3D interaction interface (LBNL); Integrate and test the coupled geomechanical numerical model TFxH/FLAC3D (LBNL); and Demonstrate that Petrel can be used to develop an earth model for providing data to the TOUGH+/FLAC3D (SLB).

  19. Membrane Technology Workshop

    Broader source: Energy.gov [DOE]

    Presentation by Charles Page (Air Products & Chemicals, Inc.) for the Membrane Technology Workshop held July 24, 2012

  20. Imaging hydrated microbial extracellular polymers: Comparative analysis by electron microscopy

    SciTech Connect (OSTI)

    Dohnalkova, A.C.; Marshall, M. J.; Arey, B. W.; Williams, K. H.; Buck, E. C.; Fredrickson, J. K.

    2011-01-01

    Microbe-mineral and -metal interactions represent a major intersection between the biosphere and geosphere but require high-resolution imaging and analytical tools for investigating microscale associations. Electron microscopy has been used extensively for geomicrobial investigations and although used bona fide, the traditional methods of sample preparation do not preserve the native morphology of microbiological components, especially extracellular polymers. Herein, we present a direct comparative analysis of microbial interactions using conventional electron microscopy approaches of imaging at room temperature and a suite of cryogenic electron microscopy methods providing imaging in the close-to-natural hydrated state. In situ, we observed an irreversible transformation of the hydrated bacterial extracellular polymers during the traditional dehydration-based sample preparation that resulted in their collapse into filamentous structures. Dehydration-induced polymer collapse can lead to inaccurate spatial relationships and hence could subsequently affect conclusions regarding nature of interactions between microbial extracellular polymers and their environment.

  1. Hydration of Kr(aq) in dilute and concentrated solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chaudhari, Mangesh I.; Sabo, Dubravko; Pratt, Lawrence R.; Rempe, Susan B.

    2014-10-13

    Molecular dynamics simulations of water with both multi-Kr and single Kr atomic solutes are carried out to implement quasi-chemical theory evaluation of the hydration free energy of Kr(aq). This approach obtains free energy differences reflecting Kr–Kr interactions at higher concentrations. Those differences are negative changes in hydration free energies with increasing concentrations at constant pressure. The changes are due to a slight reduction of packing contributions in the higher concentration case. The observed Kr–Kr distributions, analyzed with the extrapolation procedure of Krüger et al., yield a modestly attractive osmotic second virial coefficient, B2 ≈ -60 cm3/mol. Moreover, the thermodynamic analysismore » interconnecting these two approaches shows that they are closely consistent with each other, providing support for both approaches.« less

  2. Determining the role of hydration forces in protein folding

    SciTech Connect (OSTI)

    Sorenson, J.M. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry] [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; Hura, G. [Univ. of California, Berkeley, CA (United States)] [Univ. of California, Berkeley, CA (United States); [Lawrence Berkeley National Lab., CA (United States). Life Sciences Div.; Soper, A.K. [Rutherford Appleton Lab., Didcot (United Kingdom). ISIS Facility] [Rutherford Appleton Lab., Didcot (United Kingdom). ISIS Facility; Pertsemlidis, A. [Univ. of Texas Southwestern Medical Center, Dallas, TX (United States). Dept. of Biochemistry] [Univ. of Texas Southwestern Medical Center, Dallas, TX (United States). Dept. of Biochemistry; Head-Gordon, T. [Lawrence Berkeley National Lab., CA (United States)] [Lawrence Berkeley National Lab., CA (United States)

    1999-07-01

    One of the primary issues in protein folding is determining what forces drive folding and eventually stabilize the native state. A delicate balance exists between electrostatic forces such as hydrogen bonding and salt bridges, and the hydrophobic effect, which are present for both intramolecular protein interactions and intermolecular contributions with the surrounding aqueous environment. This article describes a combined experimental, theoretical, and computational effort to show how the complexity of aqueous hydration can influence the structure, folding and aggregation, and stability of model protein systems. The unification of the theoretical and experimental work is the development or discovery of effective amino acid interactions that implicitly include the effects of aqueous solvent. The authors show that consideration of the full range of complexity of aqueous hydration forces such as many-body effects, long-ranged character of aqueous solvation, and the assumptions made about the degree of protein hydrophobicity can directly impact the observed structure, folding, and stability of model protein systems.

  3. Production technology and provenance study of archaeological ceramics from relevant sites in the Alcantara River Valley (North-eastern Sicily, Italy)

    SciTech Connect (OSTI)

    Belfiore, Cristina Maria; Di Bella, Marcella; Triscari, Maurizio; Viccaro, Marco

    2010-04-15

    In this paper, volcanic-rich ceramic remains from the archaeological sites of Francavilla, Naxos and Taormina (Province of Messina, North-eastern Sicily) were studied by using inclusions as main provenance marker. Technological features, such as temper choice, vitrification degree and firing temperatures, were investigated by polarizing microscopy, X-ray diffractometry (XRD) and scanning electron microscopy (SEM). Information on the production centres was obtained through the identification of the source area of raw materials used as temper. Indeed, petrochemical analysis of the volcanic inclusions within the examined ceramics displayed strong affinities with structures/textures and compositions of the locally outcropping mugearitic products, probably ascribed to the eruptive activity of an eccentric vent of Mt. Etna (Mt. Mojo). A local production for the studied pottery samples has been therefore advanced, assuming that the used volcanic temper was easily available from the alluvial deposits along the Alcantara River stream, which is connected to the lava flow of Mt. Mojo.

  4. Order and disorder in calcium–silicate–hydrate

    SciTech Connect (OSTI)

    Bauchy, M.; Qomi, M. J. Abdolhosseini; Ulm, F.-J.; Pellenq, R. J.-M.

    2014-06-07

    Despite advances in the characterization and modeling of cement hydrates, the atomic order in Calcium–Silicate–Hydrate (C–S–H), the binding phase of cement, remains an open question. Indeed, in contrast to the former crystalline model, recent molecular models suggest that the nanoscale structure of C–S–H is amorphous. To elucidate this issue, we analyzed the structure of a realistic simulated model of C–S–H, and compared the latter to crystalline tobermorite, a natural analogue of C–S–H, and to an artificial ideal glass. The results clearly indicate that C–S–H appears as amorphous, when averaged on all atoms. However, an analysis of the order around each atomic species reveals that its structure shows an intermediate degree of order, retaining some characteristics of the crystal while acquiring an overall glass-like disorder. Thanks to a detailed quantification of order and disorder, we show that, while C–S–H retains some signatures of a tobermorite-like layered structure, hydrated species are completely amorphous.

  5. Petroleum and geothermal production technology in Russia: Summary of information obtained during informational meetings with several Russian Institutes

    SciTech Connect (OSTI)

    Schafer, D.M.; Glowka, D.A.; Teufel, L.W.

    1995-04-01

    Russian scientists and engineers have drilled the deepest holes in the world. It is recognized that this experience has given them an expertise in drilling superdeep holes, as well as other aspects of drilling, completions, and geophysics. More and more US oil and gas companies are vigorously expanding their exploration and development into Russia. It is important for them to identify and use Russian technology in drilling, completion, logging, and reservoir characterization to the extent possible, in order to both reduce drilling costs and help support the Russian economy. While these US companies are interested in becoming involved in and/or sponsoring research in Russia, they have been unsure as to which scientists and institutes are working on problems of interest. It was also important to determine in which areas Russian technology is farther advanced than in the West. Such technology could then be commercialized as part of the Industrial Partnering Program. In order to develop a clear understanding of these issues, two Sandia engineers with drilling and completions expertise and a geophysicist with expertise in reservoir analysis traveled to Russia to meet with Russian scientists and engineers to discuss their technologies and areas of interest. This report contains a summary of the information obtained during the visit.

  6. Fuel-Flexible Gasification-Combustion Technology for Production of H2 and Sequestration-Ready CO2

    SciTech Connect (OSTI)

    George Rizeq; Janice West; Raul Subia; Arnaldo Frydman; Parag Kulkarni; Jennifer Schwerman; Valadimir Zamansky; John Reinker; Kanchan Mondal; Lubor Stonawski; Hana Loreth; Krzysztof Piotrowski; Tomasz Szymanski; Tomasz Wiltowski; Edwin Hippo

    2005-02-28

    GE Global Research is developing an innovative energy technology for coal gasification with high efficiency and near-zero pollution. This Unmixed Fuel Processor (UFP) technology simultaneously converts coal, steam and air into three separate streams of hydrogen-rich gas, sequestration-ready CO{sub 2}, and high-temperature, high-pressure vitiated air to produce electricity in gas turbines. This is the draft final report for the first stage of the DOE-funded Vision 21 program. The UFP technology development program encompassed lab-, bench- and pilot-scale studies to demonstrate the UFP concept. Modeling and economic assessments were also key parts of this program. The chemical and mechanical feasibility were established via lab and bench-scale testing, and a pilot plant was designed, constructed and operated, demonstrating the major UFP features. Experimental and preliminary modeling results showed that 80% H{sub 2} purity could be achieved, and that a UFP-based energy plant is projected to meet DOE efficiency targets. Future work will include additional pilot plant testing to optimize performance and reduce environmental, operability and combined cycle integration risks. Results obtained to date have confirmed that this technology has the potential to economically meet future efficiency and environmental performance goals.

  7. SUPPORT OF GULF OF MEXICO HYDRATE RESEARCH CONSORTIUM: ACTIVITIES TO SUPPORT ESTABLISHMENT OF A SEA FLOOR MONITORING STATION PROJECT

    SciTech Connect (OSTI)

    J. Robert Woolsey; Tom McGee; Carol Lutken; Elizabeth Stidham

    2006-06-01

    The Gulf of Mexico Hydrates Research Consortium (GOM-HRC) was established in 1999 to assemble leaders in gas hydrates research. The Consortium is administered by the Center for Marine Resources and Environmental Technology, CMRET, at the University of Mississippi. The primary objective of the group is to design and emplace a remote monitoring station or sea floor observatory (MS/SFO) on the sea floor in the northern Gulf of Mexico by the year 2007, in an area where gas hydrates are known to be present at, or just below, the sea floor. This mission, although unavoidably delayed by hurricanes and other disturbances, necessitates assembling a station that will monitor physical and chemical parameters of the marine environment, including sea water and sea-floor sediments, on a more-or-less continuous basis over an extended period of time. In 2005, biological monitoring, as a means of assessing environmental health was added to the mission of the MS/SFO. Establishment of the Consortium has succeeded in fulfilling the critical need to coordinate activities, avoid redundancies and communicate effectively among researchers in the arena of gas hydrates research. Complementary expertise, both scientific and technical, has been assembled to promote innovative research methods and construct necessary instrumentation. The observatory has now achieved a microbial dimension in addition to the geophysical and geochemical components it had already included. Initial components of the observatory, a probe that collects pore-fluid samples and another that records sea floor temperatures, were deployed in Mississippi Canyon 118 in May of 2005. Follow-up deployments, planned for fall 2005, had to be postponed due to the catastrophic effects of Hurricane Katrina (and later, Rita) on the Gulf Coast. Every effort was made to locate and retain the services of a suitable vessel and submersibles or Remotely Operated Vehicles (ROVs) following the storms and the loss of the contracted vessel, the M/V Ocean Quest and its two submersibles, but these efforts have been fruitless due to the demand for these resources in the tremendous recovery effort being made in the Gulf area. Station/observatory completion, anticipated for 2007, will likely be delayed by at least one year. The seafloor monitoring station/observatory is funded approximately equally by three federal Agencies: Minerals Management Services (MMS) of the Department of the Interior (DOI), National Energy Technology Laboratory (NETL) of the Department of Energy (DOE), and the National Institute for Undersea Science and Technology (NIUST), an agency of the National Oceanographic and Atmospheric Administration (NOAA).

  8. The U.S. DOE Methane Hydrate R&D Program Publications and Presentations Resulting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. DOE Methane Hydrate R&D Program Publications and Presentations Resulting from DOE-Supported Methane Hydrate R&D 1999-2016 Including a Listing of DOE-Sponsored Student Researchers March 2016 U.S. DOE Methane Hydrate R&D Program Bibliography Page 2 Table of Contents Section I: Documentation of Support for Education .................................................................................... 6 Undergraduate (B.S. and B.E.), Master of Science (M.S.), Doctoral (Ph.D.), and

  9. EA-1929: NorthStar Medical Technologies LLC, Commercial Domestic Production of the Medical Isotope Molybdenum-99

    Broader source: Energy.gov [DOE]

    This EA evaluates the potential environmental impacts of a proposal to use federal funds to support and accelerate Northstar Medical Radioisotopes' project to develop domestic, commercial production capability for the medical isotope Molybdenum-99 without the use of highly enriched uranium.

  10. Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report

    SciTech Connect (OSTI)

    McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

    2007-09-01

    Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

  11. Presentations from the March 27th - 28th Methane Hydrates Advisory...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications May 21, 2014 Committee Recommendations to Secretary of Energy Methane Hydrate Annual Reports Presentations from the May 7, 2015 Advisory Committee...

  12. Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico

    SciTech Connect (OSTI)

    Dunbar, John

    2012-12-31

    Electrical methods offer a geophysical approach for determining the sub-bottom distribution of hydrate in deep marine environments. Methane hydrate is essentially non-conductive. Hence, sediments containing hydrate are more resistive than sediments without hydrates. To date, the controlled source electromagnetic (CSEM) method has been used in marine hydrates studies. This project evaluated an alternative electrical method, direct current resistivity (DCR), for detecting marine hydrates. DCR involves the injection of direct current between two source electrodes and the simultaneous measurement of the electric potential (voltage) between multiple receiver electrodes. The DCR method provides subsurface information comparable to that produced by the CSEM method, but with less sophisticated instrumentation. Because the receivers are simple electrodes, large numbers can be deployed to achieve higher spatial resolution. In this project a prototype seafloor DCR system was developed and used to conduct a reconnaissance survey at a site of known hydrate occurrence in Mississippi Canyon Block 118. The resulting images of sub-bottom resistivities indicate that high-concentration hydrates at the site occur only in the upper 50 m, where deep-seated faults intersect the seafloor. Overall, there was evidence for much less hydrate at the site than previously thought based on available seismic and CSEM data alone.

  13. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, November 1994--February 1995

    SciTech Connect (OSTI)

    1995-03-01

    This second quarterly report describes work during the second three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSI) and the Center for Hazardous Materials Research (CHMR). The report describes the activities of the project team during the reporting period. The principal work has focussed upon the acquisition of by-product samples and their initial analysis. Other efforts during the second quarter have been directed toward identifying the first hazardous waste samples and preparing for their treatment and analysis. Relatively little data has yet been collected. Major presentation of technical details and data will appear for the first time in the third quarterly report. The activity on the project during the second quarter of Phase One, as presented in the following sections, has fallen into seven areas: (1) Acquiring by-products, (2) Analyzing by-products, (3) Identifying, analyzing and treating suitable hazardous wastes, (4) Carrying out the quality assurance/quality control program, (5) Developing background, and (6) Initiating public relations

  14. VICA Technologies LLC | Open Energy Information

    Open Energy Info (EERE)

    Technologies LLC Jump to: navigation, search Name: VICA Technologies LLC Place: Philadelphia, Pennsylvania Zip: 19104 Sector: Biomass, Renewable Energy Product:...

  15. Lithium Technology Corporation | Open Energy Information

    Open Energy Info (EERE)

    Technology Corporation Jump to: navigation, search Name: Lithium Technology Corporation Place: Plymouth Meeting, Pennsylvania Zip: PA 19462 Sector: Vehicles Product:...

  16. Premier Solar Technologies | Open Energy Information

    Open Energy Info (EERE)

    Premier Solar Technologies Name: Premier Solar Technologies Place: Dubai, United Arab Emirates Sector: Renewable Energy Product: Integrated Storage Collector Website:...

  17. Centre for Neighbourhood Technology | Open Energy Information

    Open Energy Info (EERE)

    for Neighbourhood Technology Place: Chicago, Illinois Zip: 60647 5415 Product: Urban sustainable development consultant. References: Centre for Neighbourhood Technology1...

  18. Siemens Technology Accelerator | Open Energy Information

    Open Energy Info (EERE)

    Technology Accelerator Jump to: navigation, search Name: Siemens Technology Accelerator Place: Germany Sector: Services Product: General Financial & Legal Services ( Subsidiary ...

  19. Albuquerque Technology Incubator | Open Energy Information

    Open Energy Info (EERE)

    Albuquerque Technology Incubator Jump to: navigation, search Name: Albuquerque Technology Incubator Place: United States Sector: Services Product: General Financial & Legal...

  20. Metering Technology Corporation | Open Energy Information

    Open Energy Info (EERE)

    Technology Corporation Jump to: navigation, search Name: Metering Technology Corporation Place: Scotts Valley, California Product: Engineering related to communicating meters....

  1. Sunnyside Technologies Inc | Open Energy Information

    Open Energy Info (EERE)

    Technologies, Inc Place: Minneapolis, Minnesota Zip: 55413 Sector: Carbon, Hydro, Hydrogen Product: Technology firm developing advanced materials and nanotechnologies including...

  2. HYDRATE v1.5 OPTION OF TOUGH+ v1.5

    Energy Science and Technology Software Center (OSTI)

    2015-08-27

    HYDRATE v1.5 is a numerical code that for the simulation of the behavior of hydrate-bearing geologic systems, and represents the third update of the code since its first release [Moridis et al., 2008]. It is an option of TOUGH+ v1.5 [Moridis and Pruess, 2014], a successor to the TOUGH2 [Pruess et al., 1999, 2012] family of codes for multi-component, multiphase fluid and heat flow developed at the Lawrence Berkeley National Laboratory. HYDRATE v1.5 needs themore » TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRAN 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. By solving the coupled equations of mass and heat balance, the fully operational TOUGH+HYDRATE code can model the non-isothermal gas release, phase behavior and flow of fluids and heat under conditions typical of common natural CH4-hydrate deposits (i.e., in the permafrost and in deep ocean sediments) in complex geological media at any scale (from laboratory to reservoir) at which Darcy’s law is valid. TOUGH+HYDRATE v1.5 includes both an equilibrium and a kinetic model of hydrate formation and dissociation. The model accounts for heat and up to four mass components, i.e., water, CH4, hydrate, and water-soluble inhibitors such as salts or alcohols. These are partitioned among four possible phases (gas phase, liquid phase, ice phase and hydrate phase). Hydrate dissociation or formation, phase changes and the corresponding thermal effects are fully described, as are the effects of inhibitors. The model can describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects and inhibitor-induced effects.« less

  3. Basin scale assessment of gas hydrate dissociation in response to climate change

    SciTech Connect (OSTI)

    Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.; Cameron-Smith, P.

    2011-07-01

    Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating climate. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. Field investigations have discovered substantial methane gas plumes exiting the seafloor along the Arctic Ocean margin, and the plumes appear at depths corresponding to the upper limit of a receding gas hydrate stability zone. It has been suggested that these plumes may be the first visible signs of the dissociation of shallow hydrate deposits due to ongoing climate change in the arctic. We simulate the release of methane from oceanic deposits, including the effects of fully-coupled heat transfer, fluid flow, hydrate dissociation, and other thermodynamic processes, for systems representative of segments of the Arctic Ocean margins. The modeling encompasses a range of shallow hydrate deposits from the landward limit of the hydrate stability zone down to water depths beyond the expected range of century-scale temperature changes. We impose temperature changes corresponding to predicted rates of climate change-related ocean warming and examine the possibility of hydrate dissociation and the release of methane. The assessment is performed at local-, regional-, and basin-scales. The simulation results are consistent with the hypothesis that dissociating shallow hydrates alone can result in significant methane fluxes at the seafloor. However, the methane release is likely to be confined to a narrow region of high dissociation susceptibility, defined by depth and temperature, and that any release will be continuous and controlled, rather than explosive. This modeling also establishes the first realistic bounds for methane release along the arctic continental shelf for potential hydrate dissociation scenarios, and ongoing work may help confirm whether climate change is already impacting the stability of the vast oceanic hydrate reservoir.

  4. Hydrogen Production

    SciTech Connect (OSTI)

    2014-09-01

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produce hydrogen. It includes an overview of research goals as well as “quick facts” about hydrogen energy resources and production technologies.

  5. Class III Mid-Term Project, "Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies"

    SciTech Connect (OSTI)

    Scott Hara

    2007-03-31

    The overall objective of this project was to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involved improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective has been to transfer technology that can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The first budget period addressed several producibility problems in the Tar II-A and Tar V thermal recovery operations that are common in SBC reservoirs. A few of the advanced technologies developed include a three-dimensional (3-D) deterministic geologic model, a 3-D deterministic thermal reservoir simulation model to aid in reservoir management and subsequent post-steamflood development work, and a detailed study on the geochemical interactions between the steam and the formation rocks and fluids. State of the art operational work included drilling and performing a pilot steam injection and production project via four new horizontal wells (2 producers and 2 injectors), implementing a hot water alternating steam (WAS) drive pilot in the existing steamflood area to improve thermal efficiency, installing a 2400-foot insulated, subsurface harbor channel crossing to supply steam to an island location, testing a novel alkaline steam completion technique to control well sanding problems, and starting on an advanced reservoir management system through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation. The second budget period phase (BP2) continued to implement state-of-the-art operational work to optimize thermal recovery processes, improve well drilling and completion practices, and evaluate the geomechanical characteristics of the producing formations. The objectives were to further improve reservoir characterization of the heterogeneous turbidite sands, test the proficiency of the three-dimensional geologic and thermal reservoir simulation models, identify the high permeability thief zones to reduce water breakthrough and cycling, and analyze the nonuniform distribution of the remaining oil in place. This work resulted in the redevelopment of the Tar II-A and Tar V post-steamflood projects by drilling several new wells and converting idle wells to improve injection sweep efficiency and more effectively drain the remaining oil reserves. Reservoir management work included reducing water cuts, maintaining or increasing oil production, and evaluating and minimizing further thermal-related formation compaction. The BP2 project utilized all the tools and knowledge gained throughout the DOE project to maximize recovery of the oil in place.

  6. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However, additional analyses plus detailed regional and site characterization is needed, along with a closer examination of competing storage demands.

  7. Advanced uranium enrichment technologies. Hearing before the Subcommittee on Energy Research and Production of the Committee on Science and Technology, US House of Representatives, Ninety-Sixth Congress, first session, September 22, 1979

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    This hearing was to learn about projected requirements for enriched uranium. The gas centrifuge work at Oak Ridge, Tennessee, and Portsmouth, Ohio, needed assessing. Laser isotope separation technique needed to be reviewed. Three technologies currently being emphasized in the Department of Energy's Advanced Isotope Separation (AIS) program were discussed; these included the Molecular Laser Isotope Separation (MLIS), Livermore's process called Atomic Vapor Laser Isotope Separation (AVLIS), and Plasma Separation Process (PSP). The status of each process was given. The present DOE AIS program calls for a process selection at the end of FY 1981, development module operation starting in the mid-1980's, pilot plant operations through the late 1980's and early 1990's, and a first production plant in the mid-1990's. (DP)

  8. Technology status of hydrogen road vehicles. IEA technical report from the IEA Agreement of the production and utilization of hydrogen

    SciTech Connect (OSTI)

    Doyle, T.A.

    1998-01-31

    The report was commissioned under the Hydrogen Implementing Agreement of the International Energy Agency (IEA) and examines the state of the art in the evolving field of hydrogen-fueled vehicles for road transport. The first phase surveys and analyzes developments since 1989, when a comprehensive review was last published. The report emphasizes the following: problems, especially backfiring, with internal combustion engines (ICEs); operational safety; hydrogen handling and on-board storage; and ongoing demonstration projects. Hydrogen vehicles are receiving much attention, especially at the research and development level. However, there has been a steady move during the past 5 years toward integral demonstrations of operable vehicles intended for public roads. Because they emit few, or no greenhouse gases, hydrogen vehicles are beginning to be taken seriously as a promising solution to the problems of urban air quality. Since the time the first draft of the report was prepared (mid-19 96), the 11th World Hydrogen Energy Conference took place in Stuttgart, Germany. This biennial conference can be regarded as a valid updating of the state of the art; therefore, the 1996 results are included in the current version. Sections of the report include: hydrogen production and distribution to urban users; on-board storage and refilling; vehicle power units and drives, and four appendices titled: 'Safety questions of hydrogen storage and use in vehicles', 'Performance of hydrogen fuel in internal production engines for road vehicles, 'Fuel cells for hydrogen vehicles', and 'Summaries of papers on hydrogen vehicles'. (refs., tabs.)

  9. Ardica Technologies | Open Energy Information

    Open Energy Info (EERE)

    Ardica Technologies Place: San Francisco, California Zip: 94107 Product: Micro fuel cell company focused on customer-centric applications of fuel cell technologies. References:...

  10. Budasolar Technologies | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Budasolar Technologies Place: Budapest, Hungary Zip: H - 1121 Sector: Solar Product: BudaSolar is a developer of thin film technologies and...

  11. MAK Technologies | Open Energy Information

    Open Energy Info (EERE)

    MAK Technologies Jump to: navigation, search Name: MAK Technologies Place: Lebanon, New Jersey Zip: 8833 Sector: Solar Product: Designs and installs solar electric and solar...

  12. Wakonda Technologies | Open Energy Information

    Open Energy Info (EERE)

    Logo: Wakonda Technologies Name: Wakonda Technologies Address: 2A Gill Street Place: Woburn, Massachusetts Zip: 01801 Region: Greater Boston Area Sector: Solar Product: High...

  13. Technology Application R&D

    Broader source: Energy.gov [DOE]

    Technology application R&D projects monitor SSL technology advances and provide laboratory and field evaluations of emerging products. Impartial, trusted analysis from DOE identifies and...

  14. Greenward Technologies | Open Energy Information

    Open Energy Info (EERE)

    Technologies Jump to: navigation, search Name: Greenward Technologies Address: PO Box 203814 Place: Austin, Texas Zip: 78720 Region: Texas Area Sector: Wind energy Product:...

  15. Danen Technology | Open Energy Information

    Open Energy Info (EERE)

    Danen Technology Jump to: navigation, search Name: Danen Technology Place: Guanyin, Taiwan Product: PV ingot and wafer maker based in northern Taiwan. Coordinates: 25.032009,...

  16. Clearpower Technology | Open Energy Information

    Open Energy Info (EERE)

    Clearpower Technology Jump to: navigation, search Name: Clearpower Technology Place: Belfast, Northern Ireland, United Kingdom Zip: BT3 9DT Sector: Wind energy Product: Clearpower...

  17. Unimicron Technology | Open Energy Information

    Open Energy Info (EERE)

    Unimicron Technology Jump to: navigation, search Name: Unimicron Technology Place: Taoyuan, Taiwan Sector: Solar Product: Unimicron established solar venture jointly with United...

  18. Greenbox Technology | Open Energy Information

    Open Energy Info (EERE)

    Greenbox Technology Jump to: navigation, search Name: Greenbox Technology Place: San Bruno, California Zip: 94066 Sector: Carbon Product: California-based, interactive energy...

  19. Shenmao Technology | Open Energy Information

    Open Energy Info (EERE)

    Shenmao Technology Jump to: navigation, search Name: Shenmao Technology Place: Taoyuan, Taiwan Zip: 328 Product: Maker of solder paste and PV ribbons. Coordinates: 25.001909,...

  20. Evince Technology | Open Energy Information

    Open Energy Info (EERE)

    Evince Technology Jump to: navigation, search Name: Evince Technology Place: United Kingdom Sector: Efficiency, Wind energy Product: String representation "Evince has pion ... ing...

  1. Mears Technology | Open Energy Information

    Open Energy Info (EERE)

    Waltham, Massachusetts Zip: 2451 Sector: Solar Product: Waltham-based developer of manufacturing technology for semiconductor chip producers. The firm's MEARS Silicon Technology...

  2. Fuel Cell Technologies Office: Publications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Technologies Office EERE Fuel Cell Technologies Office Share this resource Publications Advanced Search Browse by Topic Mail Requests Help Feature featured product...

  3. Statpower Technologies | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Statpower Technologies Place: British Columbia, Canada Zip: V5A 4B5 Product: Statpower Technologies develops and markets mobile and backup...

  4. IPower Technologies | Open Energy Information

    Open Energy Info (EERE)

    Place: Andersen, Indiana Zip: 46013 Product: iPower Technologies provides advanced technologies and systems integration capabilities for the distributed generation market....

  5. Play Analysis and Digital Portfolio of Major Oil Reservoirs in the Permian Basin: Application and Transfer of Advanced Geological and Engineering Technologies for Incremental Production Opportunities

    SciTech Connect (OSTI)

    Shirley P. Dutton; Eugene M. Kim; Ronald F. Broadhead; Caroline L. Breton; William D. Raatz; Stephen C. Ruppel; Charles Kerans

    2004-01-13

    A play portfolio is being constructed for the Permian Basin in west Texas and southeast New Mexico, the largest onshore petroleum-producing basin in the United States. Approximately 1,300 reservoirs in the Permian Basin have been identified as having cumulative production greater than 1 MMbbl (1.59 x 10{sup 5} m{sup 3}) of oil through 2000. Of these significant-sized reservoirs, approximately 1,000 are in Texas and 300 in New Mexico. There are 32 geologic plays that have been defined for Permian Basin oil reservoirs, and each of the 1,300 major reservoirs was assigned to a play. The reservoirs were mapped and compiled in a Geographic Information System (GIS) by play. The final reservoir shapefile for each play contains the geographic location of each reservoir. Associated reservoir information within the linked data tables includes RRC reservoir number and district (Texas only), official field and reservoir name, year reservoir was discovered, depth to top of the reservoir, production in 2000, and cumulative production through 2000. Some tables also list subplays. Play boundaries were drawn for each play; the boundaries include areas where fields in that play occur but are smaller than 1 MMbbl (1.59 x 10{sup 5} m{sup 3}) of cumulative production. Oil production from the reservoirs in the Permian Basin having cumulative production of >1 MMbbl (1.59 x 10{sup 5} m{sup 3}) was 301.4 MMbbl (4.79 x 10{sup 7} m{sup 3}) in 2000. Cumulative Permian Basin production through 2000 was 28.9 Bbbl (4.59 x 10{sup 9} m{sup 3}). The top four plays in cumulative production are the Northwest Shelf San Andres Platform Carbonate play (3.97 Bbbl [6.31 x 10{sup 8} m{sup 3}]), the Leonard Restricted Platform Carbonate play (3.30 Bbbl [5.25 x 10{sup 8} m{sup 3}]), the Pennsylvanian and Lower Permian Horseshoe Atoll Carbonate play (2.70 Bbbl [4.29 x 10{sup 8} m{sup 3}]), and the San Andres Platform Carbonate play (2.15 Bbbl [3.42 x 10{sup 8} m{sup 3}]). Detailed studies of three reservoirs are in progress: Kelly-Snyder (SACROC unit) in the Pennsylvanian and Lower Permian Horseshoe Atoll Carbonate play, Fullerton in the Leonard Restricted Platform Carbonate play, and Barnhart (Ellenburger) in the Ellenburger Selectively Dolomitized Ramp Carbonate play. For each of these detailed reservoir studies, technologies for further, economically viable exploitation are being investigated.

  6. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    SciTech Connect (OSTI)

    Kneafsey, T.J.; Rees, E.V.L.

    2010-03-01

    When maintained under hydrate-stable conditions, methane hydrate in laboratory samples is often considered a stable and immobile solid material. Currently, there do not appear to be any studies in which the long-term redistribution of hydrates in sediments has been investigated in the laboratory. These observations are important because if the location of hydrate in a sample were to change over time (e.g. by dissociating at one location and reforming at another), the properties of the sample that depend on hydrate saturation and pore space occupancy would also change. Observations of hydrate redistribution under stable conditions are also important in understanding natural hydrate deposits, as these may also change over time. The processes by which solid hydrate can move include dissociation, hydrate-former and water migration in the gas and liquid phases, and hydrate formation. Chemical potential gradients induced by temperature, pressure, and pore water or host sediment chemistry can drive these processes. A series of tests were performed on a formerly natural methane-hydrate-bearing core sample from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well, in order to observe hydrate formation and morphology within this natural sediment, and changes over time using X-ray computed tomography (CT). Long-term observations (over several weeks) of methane hydrate in natural sediments were made to investigate spatial changes in hydrate saturation in the core. During the test sequence, mild buffered thermal and pressure oscillations occurred within the sample in response to laboratory temperature changes. These oscillations were small in magnitude, and conditions were maintained well within the hydrate stability zone.

  7. Manufacturing technologies

    SciTech Connect (OSTI)

    1995-09-01

    The Manufacturing Technologies Center is an integral part of Sandia National Laboratories, a multiprogram engineering and science laboratory, operated for the Department of Energy (DOE) with major facilities at Albuquerque, New Mexico, and Livermore, California. Our Center is at the core of Sandia`s Advanced Manufacturing effort which spans the entire product realization process.

  8. Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates

    SciTech Connect (OSTI)

    Chaka, Anne M.; Felmy, Andrew R.

    2014-03-28

    An ab initio thermodynamic framework for predicting properties of hydrated magnesium carbonate minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including semiempirical dispersion via the Grimme method and small corrections to the generalized gradient approximation of Perdew, Burke, and Ernzerhof for the heat of formation yields a model with quantitative agreement for the benchmark minerals brucite, magnesite, nesquehonite, and hydromagnesite. The model shows how small differences in experimental conditions determine whether nesquehonite, hydromagnesite, or magnesite is the result of laboratory synthesis from carbonation of brucite, and what transformations are expected to occur on geological time scales. Because of the reliance on parameter-free first principles methods, the model is reliably extensible to experimental conditions not readily accessible to experiment and to any mineral composition for which the structure is known or can be hypothesized, including structures containing defects, substitutions, or transitional structures during solid state transformations induced by temperature changes or processes such as water, CO2, or O2 diffusion. Demonstrated applications of the ab initio thermodynamic framework include an independent means to evaluate differences in thermodynamic data for lansfordite, predicting the properties of Mg analogs of Ca-based hydrated carbonates monohydrocalcite and ikaite which have not been observed in nature, and an estimation of the thermodynamics of barringtonite from the stoichiometry and a single experimental observation.

  9. Hydration studies of calcium sulfoaluminate cements blended with fly ash

    SciTech Connect (OSTI)

    Garca-Mat, M.; De la Torre, A.G.; Len-Reina, L.; Aranda, M.A.G.; CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona ; Santacruz, I.

    2013-12-15

    The main objective of this work is to study the hydration and properties of calcium sulfoaluminate cement pastes blended with fly ash (FA) and the corresponding mortars at different hydration ages. Laboratory X-ray powder diffraction, rheological studies, thermal analysis, porosimetry and compressive strength measurements were performed. The analysis of the diffraction data by Rietveld method allowed quantifying crystalline phases and overall amorphous contents. The studied parameters were: i) FA content, 0, 15 and 30 wt.%; and ii) water addition, water-to-CSA mass ratio (w/CSA = 0.50 and 0.65), and water-to-binder mass ratio (w/b = 0.50). Finally, compressive strengths after 6 months of 0 and 15 wt.% FA [w/CSA = 0.50] mortars were similar: 73 2 and 72 3 MPa, respectively. This is justified by the filler effect of the FA as no strong evidences of reactivity of FA with CSA were observed. These results support the partial substitution of CSA cements with FA with the economic and environmental benefits.

  10. METHANE HYDRATE STUDIES: DELINEATING PROPERTIES OF HOST SEDIMENTS TO ESTABLISH REPRODUCIBLE DECOMPOSITION KINETICS.

    SciTech Connect (OSTI)

    Mahajan, Devinder; Jones, Keith W.; Feng, Huan; Winters, William J.

    2004-12-01

    The use of methane hydrate as an energy source requires development of a reliable method for its extraction from its highly dispersed locations in oceanic margin sediments and permafrost. The high pressure (up to 70 MPa) and low temperature (272 K to 278 K) conditions under which hydrates are stable in the marine environment can be mimicked in a laboratory setting and several kinetic studies of pure methane hydrate decomposition have been reported. However, the effect of host sediments on methane hydrate occurrence and decomposition are required to develop reliable hydrate models. In this paper, we describe methods to measure sediment properties as they relate to pore-space methane gas hydrate. Traditional geotechnical techniques are compared to the micrometer level by use of the synchrotron Computed Microtomography (CMT) technique. CMT was used to measure the porosity at the micrometer level and to show pore-space pathways through field samples. Porosities for three sediment samples: one from a site on Georges Bank and two from the known Blake Ridge methane hydrate site, from different depths below the mud line were measured by traditional drying and by the new CMT techniques and found to be in good agreement. The integration of the two analytical approaches is necessary to enable better understanding of methane hydrate interactions with the surrounding sediment particles.

  11. Superior Process Technology Inc | Open Energy Information

    Open Energy Info (EERE)

    Process Technology Inc Jump to: navigation, search Name: Superior Process Technology Inc Place: Minneapolis, Minnesota Zip: 55424 Sector: Services Product: Biodiesel production...

  12. Gore Fuel Cell Technologies | Open Energy Information

    Open Energy Info (EERE)

    Gore Fuel Cell Technologies Jump to: navigation, search Name: Gore Fuel Cell Technologies Place: Elkton, Maryland Zip: 21922-1488 Product: Gore Fuel Cell Technologies supplies the...

  13. Ener Solar Technology srl | Open Energy Information

    Open Energy Info (EERE)

    Ener Solar Technology srl Jump to: navigation, search Name: Ener Solar Technology srl Place: Italy Sector: Solar Product: Solar project developer. References: Ener Solar Technology...

  14. American Electric Technologies Inc | Open Energy Information

    Open Energy Info (EERE)

    Technologies Inc Jump to: navigation, search Name: American Electric Technologies Inc Place: Houston, Texas Zip: TX 77087 Sector: Services Product: American Electric Technologies...

  15. Bio Gas Technologies LTd | Open Energy Information

    Open Energy Info (EERE)

    Gas Technologies LTd Jump to: navigation, search Name: Bio-Gas Technologies LTd Place: Norwalk, Ohio Zip: 44857 Sector: Renewable Energy Product: Bio-gas Technologies is involved...

  16. Bio Processing Technology Inc | Open Energy Information

    Open Energy Info (EERE)

    Processing Technology Inc Jump to: navigation, search Name: Bio Processing Technology Inc Place: New Indiana, Indiana Product: Focused on technologies that convert corn and other...

  17. Impact Technologies LLC | Open Energy Information

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    Technologies LLC Jump to: navigation, search Name: Impact Technologies LLC Place: Tulsa, OK Zip: 74153 Sector: Geothermal energy Product: drilling technology Phone Number:...

  18. World Waste Technologies | Open Energy Information

    Open Energy Info (EERE)

    Waste Technologies Jump to: navigation, search Name: World Waste Technologies Place: San Diego, California Sector: Biofuels Product: Technology developer that focuses on converting...

  19. Advanced Green Technologies | Open Energy Information

    Open Energy Info (EERE)

    Green Technologies Jump to: navigation, search Name: Advanced Green Technologies Place: Fort Lauderdale, Florida Zip: 33311 Product: Advanced Green Technologies is a US-based...

  20. Efun Technology Co Ltd | Open Energy Information

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    Efun Technology Co Ltd Jump to: navigation, search Name: Efun Technology Co Ltd. Place: Tainan, Taiwan Zip: 70955 Sector: Solar Product: Efun Technology principally engaged in the...

  1. Leadis Technology Inc | Open Energy Information

    Open Energy Info (EERE)

    Leadis Technology Inc Jump to: navigation, search Name: Leadis Technology Inc. Place: Sunnyvale, California Zip: 94086-4834 Product: Leadis Technology is a semiconductor company...

  2. Axeon Technology Ltd | Open Energy Information

    Open Energy Info (EERE)

    Technology Ltd Jump to: navigation, search Name: Axeon Technology Ltd Place: United Kingdom Product: Owns the Vindax technology, which controls batteries for more efficient...

  3. Universal Lighting Technologies | Open Energy Information

    Open Energy Info (EERE)

    Lighting Technologies Jump to: navigation, search Name: Universal Lighting Technologies Place: Nashville, Tennessee Zip: 37214-3683 Product: Universal Lighting Technologies...

  4. Ryle Technology Ltd UK | Open Energy Information

    Open Energy Info (EERE)

    Technology Ltd UK Place: United Kingdom Sector: Wind energy Product: Focused on wind blade technology development. References: Ryle Technology Ltd UK1 This article is a stub....

  5. C D Technologies Inc | Open Energy Information

    Open Energy Info (EERE)

    D Technologies Inc Jump to: navigation, search Name: C&D Technologies Inc Place: Blue Bell, Pennsylvania Zip: 19422 Product: A technology company that produces and markets systems...

  6. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2000-12-06

    Through December 1999, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar (Tar II-A) Zone. Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood project. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone in order to focus the remaining time on using the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. Thermal-related formation compaction is a concern of the project team due to observed surface subsidence in the local area above the Tar II-A steamflood project. On January 12, 1999, the steamflood project lost its inexpensive steam source from the Harbor Cogeneration Plant as a result of the recent deregulation of electrical power rates in California. An operational plan was developed and implemented to mitigate the effects of the two situations by injecting cold water into the flanks of the steamflood. The purpose of flank injection has been to increase and subsequently maintain reservoir pressures at a level that would fill-up the steam chests in the ''T'' and ''D'' sands before they can collapse and cause formation compaction and to prevent the steam chests from reoccurring. A new 3-D deterministic thermal reservoir simulation model was used to provide operations with the necessary water injection rates and allowable production rates by well to minimize future surface subsidence and to accurately project reservoir steam chest fill-up by October 1999. A geomechanics study and a separate reservoir simulation study have been performed to determine the possible indicators of formation compaction, the temperatures at which specific indicators are affected and the projected temperature profiles in the over and underburden shales over a ten year period following steam injection. It was believed that once steam chest fill-up occurred, the reservoir would act more like a waterflood and production and cold water injection could be operated at lower Injection to production ratios (I/P) and net injection rates. In mid-September 1999, net water injection was reduced substantially in the ''D'' sands following steam chest fill-up. This caused reservoir pressures to plummet about 100 psi within six weeks. Starting in late-October 1999, net ''D'' sand injection was increased and reservoir pressures have slowly increased back to steam chest fill-up pressures as of the end of March 2000. When the ''T'' sands reached fill-up, net ''T'' sand injection was lowered only slightly and reservoir pressures stabilized. A more detailed discussion of the operational changes is in the Reservoir Management section of this report. A reservoir pressure monitoring program was developed as part of the poststeamflood reservoir management plan. This bi-monthly sonic fluid level program measures the static fluid levels in all idle wells an average of once a month. The fluid levels have been calibrated for liquid and gas density gradients by comparing a number of them with Amerada bomb pressures taken within a few days. This data allows engineering to respond quickly to rises or declines in reservoir pressure by either increasing injection or production or idling production. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current thermal operations in the Wilm

  7. Gas hydrates on the Atlantic Continental Margin of the United States - controls on concentration

    SciTech Connect (OSTI)

    Dillon, W.P.; Fehlhaber, K.; Coleman, D.F. ); Lee, M.W. )

    1993-01-01

    Large volumes of gas hydrates exist within ocean-floor deposits at water depths exceeding about 300 to 500 m. They cement a surface layer of sediments as much as about 1,000 m thick, limited at its base by increasing temperature. Gas hydrates are identified by drilled samples and by their characteristic responses in seismic reflection profiles. These seismic responses include, at the base of the hydrate-cemented surface layer, a marked velocity decrease and a sea-floor-paralleling reflection (known as the bottom-simulating reflection, or BSR), and, within the hydrate-cemented layer, a reduction in amplitude of seismic reflections (known as blanking), which is apparently caused by cementation of strata. By using seismic-reflection data we have mapped the volume of hydrate and thickness of the hydrate-cemented layer off the US East Coast. The sources of gas at these concentrations are probably bacterial generation of methane at the locations of rapid deposition, and possibly the migration of deep, thermogenic gap up faults near diapirs. The thickness of the gas-hydrate layer decreases markedly at landslide scars, possibly due to break-down of hydrate resulting from pressure reduction caused by removal of sediment by the slide. Gas traps appear to exist where a seal is formed by the gas-hydrate-cemented layer. Such traps are observed (1) where the sea floor forms a dome, and therefore the bottom-paralleling, hydrate-cemented layer also forms a dome; (2) above diapirs, where the greater thermal conductivity of salt creates a warm spot and salt ions act as antifreeze, both effects resulting in a local shallowing of the base of the hydrate; and (3) at locations where strata dip relative to the sea floor, and the updip regions of porous strata are sealed by the gas-hydrate-cemented layer to form a trap. In such situations the gas in the hydrate-sealed trap, as well as the gas that forms the hydrate, may become a resource. 32 refs., 19 figs.

  8. Unconventional gas hydrate seals may trap gas off southeast US. [North Carolina, South Carolina

    SciTech Connect (OSTI)

    Dillion, W.P.; Grow, J.A.; Paull, C.K.

    1980-01-07

    Seismic profiles have indicated to the US Geological Survey that an unconventional seal, created by gas hydrates that form in near-bottom sediments, may provide gas traps in continental slopes and rises offshore North and South Carolina. The most frequently cited evidence for the presence of gas hydrate in ocean sediments is the observation of a seismic reflection event that occurs about 1/2 s below and parallel with the seafloor. If gas-hydrate traps do exist, they will occur at very shallow sub-bottom depths of about 1600 ft (500m). Exploration of such traps will probably take place in the federally controlled Blake Ridge area off the coast of South Carolina where seismic data suggest a high incidence of gas hydrates. However, drilling through the gas-hydrate-cemented layer may require new engineering techniques for sealing the casing.

  9. Energy Department Expands Research into Methane Hydrates, a Vast, Untapped Potential Energy Resource of the U.S.

    Broader source: Energy.gov [DOE]

    Projects Will Determine Whether methane Hydrates Are an Economically and Environmentally Viable Option for America's Energy Future

  10. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2000-12-06

    Through March 2000, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar (Tar II-A) Zone. Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood project. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone so the project team could use the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. The project team spent the second quarter 2000 writing the 1997-2000 Annual Report, completing research for the project on the subjects mentioned above, and operating the Tar II-A post-steamflood project and the Tar V horizontal well steamflood pilot. Thermal-related formation compaction is a concern of the project team due to observed surface subsidence in the local area above the Tar II-A steamflood project. On January 12, 1999, the steamflood project lost its inexpensive steam source from the Harbor Cogeneration Plant as a result of the recent deregulation of electrical power rates in California. An operational plan was developed and implemented to mitigate the effects of the two situations by injecting cold water into the flanks of the steamflood. The purpose of flank injection has been to increase and subsequently maintain reservoir pressures at a level that would fill-up the steam chests in the ''T'' and ''D'' sands before they can collapse and cause formation compaction and to prevent the steam chests from reoccurring. A new 3-D deterministic thermal reservoir simulation model was used to provide operations with the necessary water injection rates and allowable production rates by well to minimize future surface subsidence and to accurately project reservoir steam chest fill-up by October 1999. A geomechanics study and a separate reservoir simulation study have been performed to determine the possible indicators of formation compaction, the temperatures at which specific indicators are affected and the projected temperature profiles in the over and underburden shales over a ten year period following steam injection. Further geomechanics work should be conducted. It was believed that once steam chest fill-up occurred, the reservoir would act more like a waterflood and production and cold water injection could be operated at lower Injection to production ratios (I/P) and net injection rates. In mid-September 1999, net water injection was reduced substantially in the ''D'' sands following steam chest fill-up. This caused reservoir pressures to plummet about 100 psi within six weeks. Starting in late-October 1999, net ''D'' sand injection was increased and reservoir pressures have slowly increased back to steam chest fill-up pressures as of the end of March 2000. When the ''T'' sands reached fill-up, net ''T'' sand injection remained at a high rate and reservoir pressures stabilized. A more detailed discussion of the operational changes is in the Reservoir Management section of this report. A reservoir pressure monitoring program was developed as part of the poststeamflood reservoir management plan. This bi-monthly sonic fluid level program measures the static fluid levels in all idle wells an average of once a month. The fluid levels have been calibrated for liquid and gas density gradients by comparing a number of them with Amerada bomb pressures taken within a few days. This data allows engineering to respond quickly to rises or declines in reservoir pressure by either increasing injection or production or idling production. Expanding thermal recovery oper

  11. Technology Deployment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Products & Technologies » Technology Deployment Technology Deployment The Federal Energy Management Program (FEMP) provides the federal government and commercial buildings sector with unbiased information about energy- and water-efficient technologies available for deployment. FEMP identifies technologies that: Have a high potential for energy savings Offer cost benefits Are commercially available for deployment. Get Started Start identifying technologies that enhance energy efficiency in

  12. Combining Multicomponent Seismic Attributes, New Rock Physics Models, and In Situ Data to Estimate Gas-Hydrate Concentrations in Deep-Water, Near-Seafloor Strata of the Gulf of Mexico

    SciTech Connect (OSTI)

    Bureau of Economic Geology

    2009-04-30

    The Bureau of Economic Geology was contracted to develop technologies that demonstrate the value of multicomponent seismic technology for evaluating deep-water hydrates across the Green Canyon area of the Gulf of Mexico. This report describes the methodologies that were developed to create compressional (P-P) and converted-shear (P-SV) images of near-seafloor geology from four-component ocean-bottom-cable (4C OBC) seismic data and the procedures used to integrate P-P and P-SV seismic attributes with borehole calibration data to estimate hydrate concentration across two study areas spanning 16 and 25 lease blocks (or 144 and 225 square miles), respectively. Approximately 200 km of two-dimensional 4C OBC profiles were processed and analyzed over the course of the 3-year project. The strategies we developed to image near-seafloor geology with 4C OBC data are unique, and the paper describing our methodology was peer-recognized with a Best Paper Award by the Society of Exploration Geophysicists in the first year of the project (2006). Among the valuable research findings demonstrated in this report, the demonstrated ability to image deep-water near-seafloor geology with sub-meter resolution using a standard-frequency (10-200 Hz) air gun array on the sea surface and 4C sensors on the seafloor has been the accomplishment that has received the most accolades from professional peers. Our study found that hydrate is pervasive across the two study areas that were analyzed but exists at low concentrations. Although our joint inversion technique showed that in some limited areas, and in some geologic units across those small areas, hydrates occupied up to 40-percent of the sediment pore space, we found that when hydrate was present, hydrate concentration tended to occupy only 10-percent to 20-percent of the pore volume. We also found that hydrate concentration tended to be greater near the base of the hydrate stability zone than it was within the central part of the stability zone.

  13. Re-Use of Clean Coal Technology By-Products in the Construction of Low Permeability Liners. Final report

    SciTech Connect (OSTI)

    Wolfe, William E.; Butalia, Tarunjit S.; Walker, Harold; Mitsch, William

    2005-07-15

    This final project report presents the results of a research program conducted at The Ohio State University from January 3, 2000 to June 30, 2005 to investigate the long-term use of stabilized flue gas desulfurization (FGD) materials in the construction of low permeability liners for ponds and wetlands. The objective of the research program was to establish long-term field-verified time-dependent relationships for the performance of liners constructed from stabilized FGD byproducts generated in Ohio. The project objective was accomplished with a coordinated program of testing and analyzing small-scale laboratory specimens under controlled conditions, mediumscale wetland experiments, and monitoring of a full-scale FGD-lined pond facility. Although the specific uses directly addressed by this report include liners for surface impoundments, the results presented in this study are also useful in other applications especially in the design of daily covers and liners for landfills, seepage cutoff walls and trenches, and for nutrient retention and pollution mitigation wetlands. The small-scale laboratory tests and monitoring of the full-scale FGD lined facility (capacity of one million gallons) shows that stabilized FGD materials can be used as low permeability liners in the construction of water and manure holding ponds. Actual long-term permeability coefficients in the range of 10-7 cm/sec (3 x 10-9 ft/sec) can be obtained in the field by compacting lime and fly ash enriched stabilized FGD materials. Leachate from the FGD material meets Ohios non-toxic criteria for coal combustion by-products, and for most potential contaminants the national primary and secondary drinking water standards are also met. The low permeability non-toxic FGD material investigated in this study poses very minimal risks, if any, for groundwater contamination. The FGD wetland experiments indicated no significant differences in phosphorus retention between the clay and FGD-lined basins. The FGD-lined basins had a greater richness of plant species but lower total plant productivity than did the claylined basins. Future research work investigating the use of FGD materials in the construction of landfill caps and liners, and wetland experiments at the medium to full-scale level is recommended.

  14. Temperature effect on the small-to-large crossover lengthscale of hydrophobic hydration

    SciTech Connect (OSTI)

    Djikaev, Y. S. Ruckenstein, E.

    2013-11-14

    The thermodynamics of hydration is expected to change gradually from entropic for small solutes to enthalpic for large ones. The small-to-large crossover lengthscale of hydrophobic hydration depends on the thermodynamic conditions of the solvent such as temperature, pressure, presence of additives, etc. We attempt to shed some light on the temperature dependence of the crossover lengthscale by using a probabilistic approach to water hydrogen bonding that allows one to obtain an analytic expression for the number of bonds per water molecule as a function of both its distance to a solute and solute radius. Incorporating that approach into the density functional theory, one can examine the solute size effects on its hydration over the entire small-to-large lengthscale range at a series of different temperatures. Knowing the dependence of the hydration free energy on the temperature and solute size, one can also obtain its enthalpic and entropic contributions as functions of both temperature and solute size. These functions can provide some interesting insight into the temperature dependence of the crossover lengthscale of hydrophobic hydration. The model was applied to the hydration of spherical particles of various radii in water in the temperature range from T = 293.15 K to T = 333.15 K. The model predictions for the temperature dependence of the hydration free energy of small hydrophobes are consistent with the experimental and simulational data on the hydration of simple molecular solutes. Three alternative definitions for the small-to-large crossover length-scale of hydrophobic hydration are proposed, and their temperature dependence is obtained. Depending on the definition and temperature, the small-to-large crossover in the hydration mechanism is predicted to occur for hydrophobes of radii from one to several nanometers. Independent of its definition, the crossover length-scale is predicted to decrease with increasing temperature.

  15. Permeability and porosity of hydrate-bearing sediments in the northern Gulf of Mexico

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Daigle, Hugh; Cook, Ann; Malinverno, Alberto

    2015-10-14

    Hydrate-bearing sands are being actively explored because they contain the highest concentrations of hydrate and are the most economically recoverable hydrate resource. However, relatively little is known about the mechanisms or timescales of hydrate formation, which are related to methane supply, fluid flux, and host sediment properties such as permeability. We used logging-while-drilling data from locations in the northern Gulf of Mexico to develop an effective medium theory-based model for predicting permeability based on clay-sized sediment fraction. The model considers permeability varying between sand and clay endpoint permeabilities that are defined from laboratory data. We verified the model using permeabilitymore » measurements on core samples from three boreholes, and then used the model to predict permeability in two wells drilled in Walker Ridge Block 313 during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II expedition in 2009. We found that the cleanest sands (clay-sized fraction <0.05) had intrinsic (hydrate-free) permeability contrasts of 5-6 orders of magnitude with the surrounding clays, which is sufficient to provide focused hydrate formation due to advection of methane from a deep source or diffusion of microbial methane from nearby clay layers. In sands where the clay-sized fraction exceeds 0.05, the permeability reduces significantly and focused flow is less pronounced. In these cases, diffusion of dissolved microbial methane is most likely the preferred mode of methane supply for hydrate formation. In conclusion, our results provide important constraints on methane supply mechanisms in the Walker Ridge area and have global implications for evaluating rates of methane migration and hydrate formation in hydrate-bearing sands.« less

  16. Permeability and porosity of hydrate-bearing sediments in the northern Gulf of Mexico

    SciTech Connect (OSTI)

    Daigle, Hugh; Cook, Ann; Malinverno, Alberto

    2015-10-14

    Hydrate-bearing sands are being actively explored because they contain the highest concentrations of hydrate and are the most economically recoverable hydrate resource. However, relatively little is known about the mechanisms or timescales of hydrate formation, which are related to methane supply, fluid flux, and host sediment properties such as permeability. We used logging-while-drilling data from locations in the northern Gulf of Mexico to develop an effective medium theory-based model for predicting permeability based on clay-sized sediment fraction. The model considers permeability varying between sand and clay endpoint permeabilities that are defined from laboratory data. We verified the model using permeability measurements on core samples from three boreholes, and then used the model to predict permeability in two wells drilled in Walker Ridge Block 313 during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II expedition in 2009. We found that the cleanest sands (clay-sized fraction <0.05) had intrinsic (hydrate-free) permeability contrasts of 5-6 orders of magnitude with the surrounding clays, which is sufficient to provide focused hydrate formation due to advection of methane from a deep source or diffusion of microbial methane from nearby clay layers. In sands where the clay-sized fraction exceeds 0.05, the permeability reduces significantly and focused flow is less pronounced. In these cases, diffusion of dissolved microbial methane is most likely the preferred mode of methane supply for hydrate formation. In conclusion, our results provide important constraints on methane supply mechanisms in the Walker Ridge area and have global implications for evaluating rates of methane migration and hydrate formation in hydrate-bearing sands.

  17. Technology for Increasing Geothermal Energy Productivity. Computer Models to Characterize the Chemical Interactions of Goethermal Fluids and Injectates with Reservoir Rocks, Wells, Surface Equiptment

    SciTech Connect (OSTI)

    Nancy Moller Weare

    2006-07-25

    This final report describes the results of a research program we carried out over a five-year (3/1999-9/2004) period with funding from a Department of Energy geothermal FDP grant (DE-FG07-99ID13745) and from other agencies. The goal of research projects in this program were to develop modeling technologies that can increase the understanding of geothermal reservoir chemistry and chemistry-related energy production processes. The ability of computer models to handle many chemical variables and complex interactions makes them an essential tool for building a fundamental understanding of a wide variety of complex geothermal resource and production chemistry. With careful choice of methodology and parameterization, research objectives were to show that chemical models can correctly simulate behavior for the ranges of fluid compositions, formation minerals, temperature and pressure associated with present and near future geothermal systems as well as for the very high PT chemistry of deep resources that is intractable with traditional experimental methods. Our research results successfully met these objectives. We demonstrated that advances in physical chemistry theory can be used to accurately describe the thermodynamics of solid-liquid-gas systems via their free energies for wide ranges of composition (X), temperature and pressure. Eight articles on this work were published in peer-reviewed journals and in conference proceedings. Four are in preparation. Our work has been presented at many workshops and conferences. We also considerably improved our interactive web site (geotherm.ucsd.edu), which was in preliminary form prior to the grant. This site, which includes several model codes treating different XPT conditions, is an effective means to transfer our technologies and is used by the geothermal community and other researchers worldwide. Our models have wide application to many energy related and other important problems (e.g., scaling prediction in petroleum production systems, stripping towers for mineral production processes, nuclear waste storage, CO2 sequestration strategies, global warming). Although funding decreases cut short completion of several research activities, we made significant progress on these abbreviated projects.

  18. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quartery report, August 1994--November 1994

    SciTech Connect (OSTI)

    1994-12-01

    This first quarterly report describes work during the first three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSO and the Center for Hazardous Materials Research (CHMR)). The report states the goals of the project - both general and specific - and then describes the activities of the project team during the reporting period. All of this work has been organizational and developmental in nature. No data has yet been collected. Technical details and data will appear for the first time in the second quarterly report and be the major topic of subsequent reports.

  19. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2000-12-14

    Through June 2000, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar (Tar II-A) Zone. Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood project. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone so the project team could use the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. The project team spent the third quarter 2000 revising the draft 1997-2000 Annual Report submitted last quarter, writing final reports on the research projects mentioned above, and operating the Tar II-A post-steamflood project and the Tar V horizontal well steamflood pilot. Thermal-related formation compaction is a concern of the project team due to observed surface subsidence in the local area above the Tar II-A steamflood project. On January 12, 1999, the steamflood project lost its inexpensive steam source from the Harbor Cogeneration Plant as a result of the recent deregulation of electrical power rates in California. An operational plan was developed and implemented to mitigate the effects of the two situations by injecting cold water into the flanks of the steamflood. The purpose of flank injection has been to increase and subsequently maintain reservoir pressures at a level that would fill-up the steam chests in the ''T'' and ''D'' sands before they can collapse and cause formation compaction and to prevent the steam chests from reoccurring. A new 3-D deterministic thermal reservoir simulation model was used to provide operations with the necessary water injection rates and allowable production rates by well to minimize future surface subsidence and to accurately project reservoir steam chest fill-up by October 1999. A geomechanics study and a separate reservoir simulation study have been performed to determine the possible indicators of formation compaction, the temperatures at which specific indicators are affected and the projected temperature profiles in the over and underburden shales over a ten year period following steam injection. Further geomechanics work should be conducted. It was believed that once steam chest fill-up occurred, the reservoir would act more like a waterflood and production and cold water injection could be operated at lower Injection to production ratios (I/P) and net injection rates. In mid-September 1999, net water injection was reduced substantially in the ''D'' sands following steam chest fill-up. This caused reservoir pressures to plummet about 100 psi within six weeks. Starting in late-October 1999, net ''D'' sand injection was increased and reservoir pressures increased back to steam chest fill-up pressures of 90% hydrostatic pressure by March 2000 and have been maintained through September 2000. When the ''T'' sands reached fill-up in October 1999, net ''T'' sand injection remained at a high rate through April 2000 and reservoir pressures stabilized at 98% hydrostatic pressure. The objective is to lower ''T'' sand pressure slowly to 90% hydrostatic. Net injection was reduced and ''T'' sand reservoir pressure was at 97% hydrostatic in September 2000. A more detailed discussion of the operational changes is in the Reservoir Management section of this report. A reservoir pressure monitoring program was developed as part of the poststeamflood reservoir management plan. This bi-monthly sonic fluid level program measures the static fluid levels in all idle wells an average of once a month.

  20. Annual Technical Progress Report of Radioisotope Power Systems Materials Production and Technology Program Tasks for October 1, 2007 Through September 30,2008

    SciTech Connect (OSTI)

    King, James F

    2009-04-01

    The Office of Radioisotope Power Systems (RPS) of the Department of Energy (DOE) provides RPS for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration (NASA) for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. For the Cassini Mission, ORNL produced carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVS) used in the generators. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. This report reflects program guidance from the Office of RPS for fiscal year (FY) 2008. Production activities for prime quality (prime) CBCF insulator sets, iridium alloy blanks and foil, and CVS are summarized in this report. Technology activities are also reported that were conducted to improve the manufacturing processes, characterize materials, or to develop information for new RPS.

  1. ANNUAL TECHNICAL PROGRESS REPORT OF RADIOISOTOPE POWER SYSTEM MATERIALS PRODUCTION AND TECHNOLOGY PROGRAM TASKS FOR OCTOBER 1, 2005 THROUGH SEPTEMBER 30, 2006

    SciTech Connect (OSTI)

    King, James F

    2007-04-01

    The Office of Space and Defense Power Systems of the Department of Energy (DOE) provides Radioisotope Power Systems (RPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. For the Cassini Mission, ORNL produced carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVS) used in the generators. The Oak Ridge National Laboratory (ORNL) has been involved in developing materials and technology and producing components for the DOE for more than three decades. This report reflects program guidance from the Office of Space and Defense Power Systems for fiscal year (FY) 2006. Production activities for prime quality (prime) CBCF insulator sets, iridium alloy blanks and foil, and CVS are summarized in this report. Technology activities are also reported that were conducted to improve the manufacturing processes, characterize materials, or to develop information for new radioisotope power systems.

  2. Annual Technical Progress Report of the Radioisotope Power Systems Materials Production and Technology Program Tasks for October 1, 2008 through September 30, 2009

    SciTech Connect (OSTI)

    King, James F

    2010-05-01

    The Office of Space and Defense Power Systems of the U. S. Department of Energy (DOE) provides Radioisotope Power Systems (RPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators (RTG) were supplied by the DOE to the National Aeronautics and Space Administration (NASA) for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. For the Cassini Mission, the Oak Ridge National Laboratory (ORNL) produced carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVS) used in the generators. ORNL has been involved in developing materials and technology and producing components for the DOE for more than three decades. This report reflects program guidance from the Office of Space and Defense Power Systems for fiscal year (FY) 2009. Production activities for prime quality (prime) CBCF insulator sets, iridium alloy blanks and foil, and CVS are summarized in this report. Technology activities are also reported that were conducted to improve the manufacturing processes, characterize materials, or to develop information for new RPS.

  3. ANNUAL TECHNICAL PROGRESS REPORT OF RADIOISOTOPE POWER SYSTEMS MATERIALS PRODUCTION AND TECHNOLOGY PROGRAM TASKS FOR OCTOBER 1, 2010 THROUGH SEPTEMBER 30, 2011

    SciTech Connect (OSTI)

    King, James F

    2012-05-01

    The Office of Space and Defense Power Systems of the Department of Energy (DOE) provides Radioisotope Power Systems (RPS) for applications where conventional power systems are not feasible. For example, radioisotope thermoelectric generators were supplied by the DOE to the National Aeronautics and Space Administration (NASA) for deep space missions including the Cassini Mission launched in October of 1997 to study the planet Saturn. For the Cassini Mission, the Oak Ridge National Laboratory (ORNL) produced carbon-bonded carbon fiber (CBCF) insulator sets, iridium alloy blanks and foil, and clad vent sets (CVS) used in the generators. These components were also produced for the Pluto New Horizons and Mars Science Lab missions launched in January 2006 and November 2011respectively. The ORNL has been involved in developing materials and technology and producing components for the DOE for nearly four decades. This report reflects program guidance from the Office of RPS for fiscal year (FY) 2011. Production activities for prime quality (prime) CBCF insulator sets, iridium alloy blanks and foil, and CVS are summarized in this report. Technology activities are also reported that were conducted to improve the manufacturing processes, characterize materials, or to develop information for new RPS. Work has also been initiated to establish fabrication capabilities for the Light Weight Radioisotope Heater Units.

  4. SUPPORT OF GULF OF MEXICO HYDRATE RESEARCH CONSORTIUM: ACTIVITIES TO SUPPORT ESTABLISHMENT OF A SEA FLOOR MONITORING STATION PROJECT

    SciTech Connect (OSTI)

    Paul Higley; J. Robert Woolsey; Ralph Goodman; Vernon Asper; Boris Mizaikoff; Angela Davis; Bob A. Hardage; Jeffrey Chanton; Rudy Rogers

    2006-03-01

    The Gulf of Mexico Hydrates Research Consortium was established in 1999 to assemble leaders in gas hydrates research. The group is administered by the Center for Marine Resources and Environmental Technology, CMRET, at the University of Mississippi. The primary objective of the group is to design and emplace a remote monitoring station or sea floor observatory on the sea floor in the northern Gulf of Mexico by the year 2005, in an area where gas hydrates are known to be present at, or just below, the sea floor. This mission necessitates assembling a station that will monitor physical and chemical parameters of the sea water and sea floor sediments on a more-or-less continuous basis over an extended period of time. Development of the station has always included the possibility of expanding its capabilities to include biological monitoring, as a means of assessing environmental health. This possibility has recently received increased attention and the group of researchers working on the station has expanded to include several microbial biologists. Establishment of the Consortium has succeeded in fulfilling the critical need to coordinate activities, avoid redundancies and communicate effectively among researchers in this relatively new research arena. Complementary expertise, both scientific and technical, has been assembled to promote innovative research methods and construct necessary instrumentation. Initial components of the observatory, a probe that collects pore-fluid samples and another that records sea floor temperatures, were deployed in Mississippi Canyon 118 in May of 2005. Follow-up deployments are planned for fall 2005 and center about the use of the vessel M/V Ocean Quest and its two manned submersibles. The subs will be used to effect bottom surveys, emplace sensors and sea floor experiments and make connections between sensor data loggers and the integrated data power unit (IDP). Station/observatory completion is anticipated for 2007 following the construction, testing and deployment of the horizontal line arrays, not yet funded. The seafloor monitoring station/observatory is funded approximately equally by three federal Agencies: Minerals Management Services (MMS) of the Department of the Interior (DOI), National Energy Technology Laboratory (NETL) of the Department of Energy (DOE), and the National Institute for Undersea Science and Technology (NIUST), an agency of the National Oceanographic and Atmospheric Administration (NOAA).

  5. New and Emerging Technologies

    Broader source: Energy.gov [DOE]

    This power point presentation provides an overview of CHP technologies and how they can be used in industrial manufacturing plants to increase productivity and reduce energy and costs.

  6. Technology Demonstration Partnership Policy

    Broader source: Energy.gov [DOE]

    This City Council memorandum establishes a framework for engaging in and evaluating demonstration partnerships with the goal of developing, testing, and demonstrating emerging technologies, product, and service innovations.

  7. Director, Geothermal Technologies Office

    Broader source: Energy.gov [DOE]

    The mission of the Geothermal Technologies Office (GTO) is to accelerate the development and deployment of clean, domestic geothermal resources that will promote a stronger, more productive economy...

  8. Geologic interrelations relative to gas hydrates within the North Slope of Alaska: Task No. 6, Final report

    SciTech Connect (OSTI)

    Collett, T.S.; Bird, K.J.; Kvenvolden, K.A.; Magoon, L.B.

    1988-01-01

    The five primary objectives of the US Geological Survey North Slope Gas Hydrate Project were to: (1) Determine possible geologic controls on the occurrence of gas hydrate; (2) locate and evaluate possible gas-hydrate-bearing reservoirs; (3) estimate the volume of gas within the hydrates; (4) develop a model for gas-hydrate formation; and (5) select a coring site for gas-hydrate sampling and analysis. Our studies of the North Slope of Alaska suggest that the zone in which gas hydrates are stable is controlled primarily by subsurface temperatures and gas chemistry. Other factors, such as pore-pressure variations, pore-fluid salinity, and reservior-rock grain size, appear to have little effect on gas hydrate stability on the North Slope. Data necessary to determine the limits of gas hydrate stability field are difficult to obtain. On the basis of mud-log gas chromatography, core data, and cuttings data, methane is the dominant species of gas in the near-surface (0--1500 m) sediment. Gas hydrates were identified in 34 wells utilizing well-log responses calibrated to the response of an interval in one well where gas hydrates were actually recovered in a core by an oil company. A possible scenario describing the origin of the interred gas hydrates on the North Slope involves the migration of thermogenic solution- and free-gas from deeper reservoirs upward along faults into the overlying sedimentary rocks. We have identified two (dedicated) core-hole sites, the Eileen and the South-End core-holes, at which there is a high probability of recovering a sample of gas hydrate. At the Eileen core-hole site, at least three stratigraphic units may contain gas hydrate. The South-End core-hole site provides an opportunity to study one specific rock unit that appears to contain both gas hydrate and oil. 100 refs., 72 figs., 24 tabs.

  9. Molecular dynamics simulations of methane hydrate using polarizable force fields

    SciTech Connect (OSTI)

    Jiang, H.N.; Jordan, K.D.; Taylor, C.E.

    2007-03-01

    Molecular dynamics simulations of methane hydrate have been carried out using the AMOEBA and COS/G2 polarizable force fields. Properties examined include the temperature dependence of the lattice constant, the OC and OO radial distribution functions and the vibrational spectra. Both the AMOEBA and COS/G2 models are found to successfully account for the available experimental data, with overall slightly better agreement with experiment being found for the AMOEBA model. Several properties calculated using the AMOEBA and COS/G2 models differ appreciable from the corresponding results obtained previously using the polarizable TIP4P-FQ model. This appears to be due to the inadequacy of the treatment of polarization, especially, the restriction of polarization to in-plane only, in the TIP4P-FQ model.

  10. Origin of Entropy Convergence in Hydrophobic Hydration and Protein Folding

    SciTech Connect (OSTI)

    Garde, S.; Hummer, G.; Garcia, A.E.; Paulaitis, M.E.; Pratt, L.R. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); [Center for Molecular and Engineering Thermodynamics, Department of Chemical Engineering, University of Delaware, Newark, Delaware 19716 (United States); [Department of Chemical Engineering, Johns Hopkins University, Baltimore, Maryland 21218 (United States)

    1996-12-01

    An information theory model of hydrophobic effects is used to construct a molecular explanation why hydrophobic solvation entropies of protein unfolding measured by high sensitivity calorimetry converge to zero at a common convergence temperature. The entropy convergence follows directly from the weak temperature dependence of occupancy fluctuations {l_angle}{delta}{ital n}{sup 2}{r_angle} for molecular-scale volumes in water. The macroscopic expression of the contrasting entropic behavior of water relative to common organic solvents is the {ital relative} temperature insensitivity of the water isothermal compressibility compared to hydrocarbon liquids. The information theory model used provides a quantitative description of small molecule hydration and, in addition, predicts that the value of the entropy at convergence is slightly {ital negative}. Interpretations of entropic contributions to protein folding should account for this result. {copyright} {ital 1996 The American Physical Society.}

  11. CO{sub 2} HYDRATE PROCESS FOR GAS SEPARATION

    SciTech Connect (OSTI)

    G. Deppe; R. Currier; D. Spencer

    2004-01-01

    Modifications were implemented to the hydrogen flow test rig per safety review comments, and the apparatus was tested for leaks. Tests were then done using Helium/CO{sub 2} mixtures to re-verify performance prior to hydrogen testing. It was discovered that hydrate formation was more difficult to initiate, and new initiation methods were developed to improve the tests. Delivery of ETM hardware continued and buildup of the ETM system continued, the ETM is now mechanically complete. The STU (pilot plant) site selection process was resumed because Tennessee Eastman declined to participate in the program. Two potential sites were visited: The Global Energy/Conoco-Phillips Wabash River Plant, and the Tampa Electric Polk Power Plant.

  12. Ion mixing, hydration, and transport in aqueous ionic systems

    SciTech Connect (OSTI)

    Tse, Ying-Lung Steve; Voth, Gregory A.; Witten, Thomas A.

    2015-05-14

    The enhancement effect on the ion mobility of fluoride (and that of chloride) in a polycationic system, as the chloride content increases, is shown to also exist in other more simple ionic systems with cations such as the cesium ion and an organic ammonium ion. As the chloride content increases, in addition to the finding that there is more unbound water associated with the cation, we also observe that the average lifetime of a hydrogen bond decreases. This change to the hydrogen bonds is correlated to significant changes to both the structural and dynamical properties of water. The more disordered water structure and faster water dynamics are hypothesized to be also responsible for the enhanced ion mobilities. Furthermore, when either the chloride content or hydration level is changed, the self-diffusion constant of each co-ion changes by almost the same factor, implying the existence of a single universal transport mechanism that determines ion mobilities.

  13. Supan Technologies | Open Energy Information

    Open Energy Info (EERE)

    Supan Technologies Place: Ontario, Canada Zip: K1C 2W6 Product: Manufactures chemical etching stations, wafer transfer equipment and turnkey PV cell and module production lines....

  14. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    SciTech Connect (OSTI)

    Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

    2011-06-01

    Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

  15. Physical property changes in hydrate-bearingsediment due to depressurization and subsequent repressurization

    SciTech Connect (OSTI)

    Kneafsey, Timothy; Waite, W.F.; Kneafsey, T.J.; Winters, W.J.; Mason, D.H.

    2008-06-01

    Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed at least briefly to non-in situ conditions during recovery. To examine effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes and speeds are compared between the original and depressurized/repressurized samples. X-ray computed tomography (CT) images track how the gas-hydrate distribution changes in the hydrate-cemented sands due to the depressurization/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.

  16. Precede Technologies | Open Energy Information

    Open Energy Info (EERE)

    search Name: Precede Technologies Place: Israel Sector: Services Product: General Financial & Legal Services ( Private family-controlled ) References: Precede...

  17. Comparison and analysis of zinc and cobalt-based systems as catalytic entities for the hydration of carbon dioxide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lau, E. Y.; Wong, S. E.; Baker, S. E.; Bearinger, J. P.; Koziol, L.; Valdez, C. A.; Satcher, J. H.; Aines, R. D.; Lightstone, F. C.

    2013-06-20

    In nature, the zinc metalloenzyme carbonic anhydrase II (CAII) efficiently catalyzes the conversion of carbon dioxide (CO 2) to bicarbonate under physiological conditions. Efforts have been directed towards the development of small molecule mimetics that can facilitate this process and thus have a beneficial environmental impact, but these efforts have met very limited success. Herein, we undertook quantum mechanical calculations of four mimetics, 1,5,9-triazacyclododedacane, 1,4,7,10-tetraazacyclododedacane, tris(4,5-dimethyl-2-imidazolyl)phosphine, and tris(2-benzimidazolylmethyl)amine, in their complexed form either with the Zn 2+ or the Co 2+ ion and studied their reaction coordinate for CO 2 hydration. These calculations demonstrated that the ability of the complexmore » to maintain a tetrahedral geometry and bind bicarbonate in a unidentate manner were vital for the hydration reaction to proceed favorably. Moreover, these calculations show that the catalytic activity of the examined zinc complexes was insensitive to coordination states for zinc, while coordination states above four were found to have an unfavorable effect on product release for the cobalt counterparts.« less

  18. {sup 1}H nuclear magnetic resonance study of hydrated water dynamics in perfluorosulfonic acid ionomer Nafion

    SciTech Connect (OSTI)

    Han, Jun Hee; Lee, Kyu Won; Jeon, G. W.; Lee, Cheol Eui; Park, W. K.; Choi, E. H.

    2015-01-12

    We have studied the dynamics of hydrated water molecules in the proton exchange membrane of Nafion by means of high-resolution {sup 1}H nuclear magnetic resonance (NMR) measurements. “Bound” and “free” states of hydrated water clusters as well as the exchange protons were identified from the NMR chemical shift measurements, and their activation energies were obtained from the temperature-dependent laboratory- and rotating-frame spin-lattice relaxation measurements. Besides, a peculiar motional transition in the ultralow frequency region was observed at 373 K for the “free” hydrated water from the rotating-frame NMR spin-lattice relaxation time measurements.

  19. Method and apparatus for recovering a gas from a gas hydrate located on the ocean floor

    DOE Patents [OSTI]

    Wyatt, Douglas E.

    2001-01-01

    A method and apparatus for recovering a gas from a gas hydrate on the ocean floor includes a flexible cover, a plurality of steerable base members secured to the cover, and a steerable mining module. A suitable source for inflating the cover over the gas hydrate deposit is provided. The mining module, positioned on the gas hydrate deposit, is preferably connected to the cover by a control cable. A gas retrieval conduit or hose extends upwardly from the cover to be connected to a support ship on the ocean surface.

  20. EERE Publication and Product Library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biobased Products Biochemical Platform Technology Bioethanol ... Integrated Biorefineries Processing & Conversion ... Concentrating Solar Power Grid Integration Photovoltaics ...