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Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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1

Hydration kinetics modeling of Portland cement considering the effects of curing temperature and applied pressure  

Science Conference Proceedings (OSTI)

A hydration kinetics model for Portland cement is formulated based on thermodynamics of multiphase porous media. The mechanism of cement hydration is discussed based on literature review. The model is then developed considering the effects of chemical composition and fineness of cement, water-cement ratio, curing temperature and applied pressure. The ultimate degree of hydration of Portland cement is also analyzed and a corresponding formula is established. The model is calibrated against the experimental data for eight different Portland cements. Simple relations between the model parameters and cement composition are obtained and used to predict hydration kinetics. The model is used to reproduce experimental results on hydration kinetics, adiabatic temperature rise, and chemical shrinkage of different cement pastes. The comparisons between the model reproductions and the different experimental results demonstrate the applicability of the proposed model, especially for cement hydration at elevated temperature and high pressure.

Lin Feng [Department of Civil Engineering and Engineering Mechanics, Columbia University, New York, NY 10027 (United States); Department of Civil Engineering, Tsinghua University, Beijing 100084 (China)], E-mail: fl2040@columbia.edu; Meyer, Christian [Department of Civil Engineering and Engineering Mechanics, Columbia University, New York, NY 10027 (United States)

2009-04-15T23:59:59.000Z

2

NETL: Methane Hydrates - Hydrate Newsletter  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate R&D Program Newsletter Methane Hydrate R&D Program Newsletter An image of a hydrate burning overlayed with the Newsletter Title: Fire in the Ice The methane hydrate newsletter, Fire in the Ice, is a bi-annual publication highlighting the latest developments in international gas hydrates R&D. Fire in the Ice promotes the exchange of information amoung those involved in gas hydrates research and development, and also recognizes the efforts of a hydrate researcher in each issue. The newsletter now reaches nearly 1300 scientists and other interested individuals in sixteen countries. To subscribe electronically to Fire in the Ice please send an email to karl.lang@contr.netl.doe.gov Please click on the links below to access issues of "Fire in the Ice". More on Methane Hydrates

3

NETL: Methane Hydrates - Hydrate Modeling - TOUGH-Fx/HYDRATE  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrate Modeling - TOUGH+/HYDRATE & HydrateResSim Hydrate Modeling - TOUGH+/HYDRATE & HydrateResSim TOUGH+/HYDRATE v1.0 LBNL's new hydrate reservoir simulator (TOUGH+/HYDRATE v1.0) is now publicly available for licensing. TOUGH+/HYDRATE models non-isothermal gas release, phase behavior and flow of fluids and heat in complex geologic media. The code can simulate production from natural CH4-hydrate deposits in the subsurface (i.e., in the permafrost and in deep ocean sediments), as well as laboratory experiments of hydrate dissociation/formation in porous/fractured media. TOUGH+/HYDRATE v1.0 includes both an equilibrium and a kinetic model of hydrate formation and dissociation. More information on TOUGH+/Hydrate Also available is HydrateResSim. HydrateResSim (HRS) is a freeware, open-source reservoir simulator code available for use “as-is” from the NETL. HRS’ code was derived from an earlier version of the TOUGH+/Hydrate code.

4

NETL: Methane Hydrates - Methane Hydrate Library  

NLE Websites -- All DOE Office Websites (Extended Search)

Ridge region Ongoing areas of study in the Hydrate Ridge region Map showing where gas hydrates occur off the Cascadia Margin Locations of methane hydrate off the Cascadia Margin...

5

NETL: Methane Hydrates - Methane Hydrate Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrates Primer provides background and general information about the history of hydrate R&D, the science of methane hydrates, their occurrences, and R&D related issues. Photo...

6

NETL: Methane Hydrates - Methane Hydrate Library  

NLE Websites -- All DOE Office Websites (Extended Search)

Texas A&M University - Geochemical & Research Environmental Group(GERG) - Gulf of Mexico Blue Mound w Tube Worms bulk hydrate sample oil slick showing possible hydrate location...

7

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Mechanical Testing of Gas Hydrate/Sediment Samples Mechanical Testing of Gas Hydrate/Sediment Samples DE-AT26-99FT40267 Goal Develop understanding of the mechanical characteristics of hydrate-containing sediments. Background The ACE CRREL has a unique group of experienced personnel that have studied the mechanical characteristics of ice and permafrost that can be applied to the study and characterization of the mechanical properties of gas hydrates. The effort aims to quantify the mechanical characteristics of methane hydrate and hydrate cemented sediments for use in models of the dynamic behavior of sediments related to drilling and seafloor installations in the Gulf of Mexico. Performers US Army Corp of Engineers, Engineer Research and Development Center, Cold Regions Research and Engineering Laboratory (CRREL) - project management and research products

8

NETL: Methane Hydrates - Hydrate Modeling - TOUGH-Fx/HYDRATE  

NLE Websites -- All DOE Office Websites (Extended Search)

Dynamics Geological & Env. Systems Materials Science Contacts TECHNOLOGIES Oil & Natural Gas Supply Deepwater Technology Enhanced Oil Recovery Gas Hydrates Natural Gas Resources...

9

HydrateNewsIssue2  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 T H E N A T I O N A L E N E R G Y T E C H N O L O G Y L A B O R A T O R Y M E T H A N E H Y D R A T E N E W S L E T T E R Announcements ChevronTexaco Gulf of Mexico Gas Hydrates Joint Industry Project Naturally Occurring Gas Hydrate Data Collection Workshop March 14-15, 2002, Adam's Mark Hotel, Houston, Texas The ChevronTexaco Gulf of Mexico Gas Hydrates Joint Industry Project (JIP), in collaboration with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL), will be holding a workshop to collect data on naturally occurring hydrates in the Gulf of Mexico (GOM). All key contributors to the understanding of naturally occurring hydrates are invited to apply to participate in the first of three workshops sponsored by the JIP. The purpose of the workshop is to develop a clear understanding of what

10

NETL: Methane Hydrates - Hydrate Model Code Comparison  

NLE Websites -- All DOE Office Websites (Extended Search)

Reservoir Simulator Code Comparison Study An International Effort to Compare Methane Hydrate Reservoir Simulators Code Comparison Logo The National Energy Technology Laboratory...

11

NETL: Methane Hydrates - Methane Hydrate Library  

NLE Websites -- All DOE Office Websites (Extended Search)

from the ANS drilling and coring operation - February, 2007 DOEJoint Industry Project - Gulf of Mexico Hydrate Research Cruise Photos from the Gulf of Mexico research cruise -...

12

NETL: Methane Hydrates - Methane Hydrate Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Reference Shelf Reference Shelf The Methane Hydrate Reference Shelf was created to provide a repository for information collected from projects funded as part of the National Methane Hydrate R&D Program. As output from the projects is received, it will be reviewed and then placed onto the reference shelf to be available to other methane hydrate researchers. Projects: DOE/NETL Projects : These pages contain detailed information on methane hydrate projects funded through the National Energy Technology Laboratory. Publications: Newsletter | Bibliography | Software | Reports | Program Publications | Photo Gallery Newsletter: Fire in the Ice: A publication highlighting the National Methane Hydrate R&D Program Bibliography: "Project Reports Bibliography"[PDF]: The bibliography lists publications resulting from DOE/NETL-sponsored

13

Cement Hydration Modelling  

Science Conference Proceedings (OSTI)

... Courtesy of Technion, Israel Institute of Technology, a Windows XP-based version of the hydration program is available. Many thanks to Prof. ...

2013-06-11T23:59:59.000Z

14

Methane Hydrate Advisory Committee Charter | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Charter Methane Hydrate Advisory Committee Charter Methane Hydrate Advisory Committee Charter Methane Hydrate Advisory Committee Charter...

15

Free energy of ionic hydration  

SciTech Connect

The hydration free energies of ions exhibit an approximately quadratic dependence on the ionic charge, as predicted by the Born model. We analyze this behavior using second-order perturbation theory. The average and the fluctuation of the electrostatic potential at charge sites appear as the first coefficients in a Taylor expansion of the free energy of charging. Combining the data from different charge states (e.g., charged and uncharged) allows calculation of free-energy profiles as a function of the ionic charge. The first two Taylor coefficients of the free-energy profiles can be computed accurately from equilibrium simulations, but they are affected by a strong system-size dependence. We apply corrections for these finite-size effects by using Ewald lattice summation and adding the self-interactions consistently. An analogous procedure is used for the reaction-field electrostatics. Results are presented for a model ion with methane-like Lennard-Jones parameters in simple point charge water. We find two very closely quadratic regimes with different parameters for positive and negative ions. We also studied the hydration free energy of potassium, calcium, fluoride, chloride, and bromide ions. We find negative ions to be solvated more strongly (as measured by hydration free energies) compared to positive ions of equal size, in agreement with experimental data. 56 refs., 6 figs., 8 tabs.

Hummer, G.; Pratt, L.R.; Garcia, A.E. [Los Alamos National Lab., NM (United States)

1996-01-25T23:59:59.000Z

16

Methane Hydrates - Methane Hydrate Graduate Fellowship  

NLE Websites -- All DOE Office Websites (Extended Search)

Future Supply and Emerging Resources Future Supply and Emerging Resources The National Methane Hydrates R&D Program - Graduate Fellowship Program Methane Hydrate Graduate Fellowship Program Jeffrey James Marlow, a graduate student in Geobiology at the California Institute of Technology, was recently selected as the 2012 recipient of the NETL-National Academy of Sciences (NAS) Methane Hydrate Research Fellowship. Please see page 15 of the March 2013 issue (Vol. 13, Issue 1) of Fire in the Ice for more information on the recipient. The Department of Energy has a long history of building synergistic relationships with research universities. Funding academic research is a "win-win-win" situation. The U.S. government is able to tap into some of the best minds available for solving national energy problems, the universities get the support they need to maintain cutting edge faculty and laboratories, and the students involved are provided with opportunities that help them along their chosen path of study, strengthening the national pool of scientists and engineers. According to Samuel Bodman, speaking about graduate research in methane hydrates, "Students are the foundation of our energy future, bringing new ideas and fresh perspectives to the energy industry. What better way to assure technology innovation than to encourage students working on the development of a resource that has the potential to tip our energy balance toward clean-burning, domestic fuels."

17

Methane Hydrate | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Methane Hydrate Methane Hydrate Types of Methane Hydrate Deposits Types of Methane Hydrate Deposits Methane hydrate is a cage-like lattice of ice inside of which are trapped molecules of methane, the chief constituent of natural gas. If methane hydrate is either warmed or depressurized, it will revert back to water and natural gas. When brought to the earth's surface, one cubic meter of gas hydrate releases 164 cubic meters of natural gas. Hydrate deposits may be several hundred meters thick and generally occur in two types of settings: under Arctic permafrost, and beneath the ocean floor. Methane that forms hydrate can be both biogenic, created by biological activity in sediments, and thermogenic, created by geological processes deeper within the earth.

18

Methane Hydrate Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FY 2011 FY 2011 Methane Hydrate Program Report to Congress July 2012 United States Department of Energy Washington, DC 20585 Department of Energy | July 2012 FY 2011 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled U.S. Department of Energy FY 2011 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of research. Pursuant to statutory requirements, this report is being provided to the following

19

Methane Hydrate Annual Reports  

Energy.gov (U.S. Department of Energy (DOE))

Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of Methane Hydrate research. Listed are the Annual Reports per...

20

Methane Hydrate Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fiscal Year 2012 Fiscal Year 2012 Methane Hydrate Program Report to Congress August 2013 United States Department of Energy Washington, DC 20585 Department of Energy | August 2013 Fiscal Year 2012 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the actions taken to carry out methane hydrate research. I am pleased to submit the enclosed report, entitled U.S. Department of Energy Fiscal Year 2012 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

of gas hydrates. The effort aims to quantify the mechanical characteristics of methane hydrate and hydrate cemented sediments for use in models of the dynamic behavior of...

22

Methane Hydrate Advisory Committee Meeting Minutes | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes June 6th - 7th, 2013...

23

NETL: Methane Hydrates - Global Assessment of Methane Gas Hydrates  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessment of Methane Gas Hydrates Last Reviewed 6142013 DE-FE0003060 Goal The goal of this project is to develop a global assessment of methane gas hydrates that will facilitate...

24

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

Pressurized Coring Equipment Pressurized Coring Equipment Pressure Core Equipment used by the Gulf of Mexico Gas Hydrate JIP Drilling Program Pressure Core Equipment - Photo Gallery One of the key objectives of the ChevronTexaco Gulf of Mexico hydrates Joint Industry Project is the collection and analyses of deepwater sediment samples. Because these samples may contain hydrate which is only stable at specific temperature and pressure conditions it is necessary to use specialized sampling equipment. Otherwise, the combination of reduced pressure and increased temperatures as the sample is retrieved through 4,000 feet of gulf seawater will fully dissociate the hydrate, leaving only gas and water. Although techniques exist to infer hydrates presence from distinctive geochemical markers, we have lost the ability to image the nature of hydrate distribution, or to conduct measurements of the various physical and chemical properties of hydrates in the host sediments.

25

NETL: Methane Hydrates - Global Assessment of Methane Gas Hydrates  

NLE Websites -- All DOE Office Websites (Extended Search)

Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 DE-FE0003060 Goal The goal of this project is to develop a global assessment of methane gas hydrates that will facilitate informed decision-making regarding the potential development of gas hydrate resources between the scientific community and other stakeholders/decision makers. The Assessment will provide science-based information on the role of gas hydrates in natural climate change and the carbon cycle, their sensitivity to climate change, and the potential environmental and socio-economic impacts of hydrate production. Performers Stiftelsen GRID-Arendal, Arendal, Norway Funding Institutions United Nations Environment Programme (UNEP) Statoil Schlumberger United States Department of Energy (USDOE)

26

NETL: Methane Hydrates - DOE/NETL Projects - Advanced Hydrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

is to develop analytical techniques capable of quantitatively evaluating the nature of methane hydrate reservoir systems through modeling of their acoustic response using...

27

NETL: Methane Hydrates - DOE/NETL Projects - Properties of Hydrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

is to measure physical, chemical, mechanical, and hydrologic property changes in methane hydrate-bearing sediments subjected to injection of carbon dioxide and nitrogen....

28

NETL: Methane Hydrates - DOE/NETL Projects - Hydrate-Bearing...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and EngineeringGeological Implications Last Reviewed 6192013 DE-FE0009897 Goal The primary goal of...

29

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

Analysis - Fugro Operations and Geotechnical Investigations PDF-7.13MB National Methane Hydrate R&D Program website. Photos: Photo Gallery - miscellaneous - Photos from...

30

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

The DOEJIP Gulf of Mexico Hydrate Research Cruise Status Reports During this expedition we will maintain an intermittent log of information relayed from the chief scientist on the...

31

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

Pressurized Coring Equipment Pressure Core Equipment used by the Gulf of Mexico Gas Hydrate JIP Drilling Program Pressure Core Equipment - Photo Gallery One of the key objectives...

32

Gas hydrate cool storage system  

DOE Patents (OSTI)

The invention presented relates to the development of a process utilizing a gas hydrate as a cool storage medium for alleviating electric load demands during peak usage periods. Several objectives of the invention are mentioned concerning the formation of the gas hydrate as storage material in a thermal energy storage system within a heat pump cycle system. The gas hydrate was formed using a refrigerant in water and an example with R-12 refrigerant is included. (BCS)

Ternes, M.P.; Kedl, R.J.

1984-09-12T23:59:59.000Z

33

HydrateNewsIssue2  

NLE Websites -- All DOE Office Websites (Extended Search)

is the physical response of the gas hydrate to depressurization and thermal production stimulation. Cores are being taken from the well, and scientists hope to retrieve at least...

34

NETL: Methane Hydrates - Interagency Coordination  

NLE Websites -- All DOE Office Websites (Extended Search)

Links to interagency pdf. The multi-faceted issues associated with naturally occurring methane hydrates demand a coordinated approach to studying (1) the potential of this resource...

35

THE PRODUCTION OF GAS HYDRATES  

E-Print Network (OSTI)

Mr. Chairman and Members of the Subcommittee, thank-you for the opportunity to appear before you today to discuss the production and economics of gas hydrate development.

Steven H. Hancock; P. Eng

2009-01-01T23:59:59.000Z

36

Department of Energy Advance Methane Hydrates Science and Technology  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advance Methane Hydrates Science and Technology Advance Methane Hydrates Science and Technology Projects Dollars awarded will go to research the advance understanding of the nature and occurrence of Deepwater and Arctic gas hydrates, and their implications for future resources, geohazards, and the environment Characterizing the Affect of Environmental Change on Gas-Hydrate-Bearing Deposits The University of California at San Diego (San Diego, Calif.) - Researchers at the University of California at San Diego will design, build, and test an electromagnetic (EM) system designed for very shallow water use and will apply the system to determine the extent of offshore permafrost on the U.S. Beaufort inner shelf. Energy Department Investment: $507,000 Duration: 36 months The University of Mississippi (Oxford, Miss.) - Using electronic measurements, the researchers will

37

Marine Electromagnetic Methods for Gas Hydrate Characterization  

E-Print Network (OSTI)

D. , 2003: Natural Gas Hydrates: Background and History ofIn Natural Gas Hydrate: Back- ground and History ofNatural Gas Hydrate: Occurrence, Distribution and Detection, chapter History

Weitemeyer, Karen A

2008-01-01T23:59:59.000Z

38

Marine electromagnetic methods for gas hydrate characterization  

E-Print Network (OSTI)

D. , 2003: Natural Gas Hydrates: Background and History ofIn Natural Gas Hydrate: Back- ground and History ofNatural Gas Hydrate: Occurrence, Distribution and Detection, chapter History

Weitemeyer, Karen Andrea

2008-01-01T23:59:59.000Z

39

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

Cruise Cruise Special Report - Bottom-Simulating Reflections(BSR). Seismic lines from deep continental shelves all around the world contain anomalous reflections known as bottom-simulating reflections(BSR). The reflections mimic the sea-floor topography at a near constant depth below the surface, and commonly cut across geological layers. The nature of the reflection indicates a horizon across which seismic velocity dramatically decreases. At one time, scientists thought the reflection must be due to some mineralogical alteration in the sediment due to heat and pressure. Once the existence of natural methane hydrate was established, BSRs were thought to record the decrease in velocity when passing from hydrate-bearing sediments to those containing only water. Therefore, BSRs were thought to be a direct indicator of hydrate: no BSR meant no hydrate. However, the velocity contrast between hydrate and no-hydrate was determined to be insufficient to cause BSRs. Today, scientists have established that BSRs are an indication of concentrations of free methane gas that is blocked from further upward migration by the presence of methane hydrate in the overlying layers. Consequently, the distribution of BSRs may mark only a subset of the areas containing hydrate.

40

NETL: Methane Hydrates - DOE/NETL Projects - Advanced Gas Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

Comparative Assessment of Advanced Gas Hydrate Production Methods Last Reviewed 09/23/2009 Comparative Assessment of Advanced Gas Hydrate Production Methods Last Reviewed 09/23/2009 DE-FC26-06NT42666 Goal The goal of this project is to compare and contrast, through numerical simulation, conventional and innovative approaches for producing methane from gas hydrate-bearing geologic reservoirs. Numerical simulation is being used to assess the production of natural gas hydrates from geologic deposits using three production technologies: 1) depressurization, 2) direct CO2 exchange, and 3) dissociation-reformation CO2 exchange. Performers Battelle Pacific Northwest Division, Richland, Washington 99352 Background There are relatively few published studies of commercial production methods for gas hydrates, and all of these studies have examined essentially

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate Projects If you need help finding information on a particular project, please contact the content manager. Search Hydrates Projects Active Projects | Completed...

42

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

with sampling and observation from the surface ship. Activities included collection of methane hydrate, sediment, water, and other materials from methane hydrate and seep sites...

43

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

goal was to develop new methodologies to characterize the physical properties of methane hydrate and hydrate sediment systems. Performers Westport Technology Center...

44

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3182013 Project Goals The primary goals of the DOENETL Natural Gas Hydrate Field Studies...

45

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

natural and simulated sediment samples, and to use these sediments as hosts to form methane hydrate and to investigate the kinetics of hydrate formation and dissociation...

46

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

NETL ORD Methane Hydrate Research - Thermal Properties of Hydrate Tool Development Last Reviewed 3182013 Project Goal The goal of this project is increased understanding of...

47

MethaneHydrateRD_FC.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Academies 2010 One of these is methane hydrate - molecules of natural gas trapped in ice crystals. Containing vast amounts of natural gas, methane hydrate occurs in a variety...

48

Gas production from hydrate-bearing sediments.  

E-Print Network (OSTI)

??Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane (more)

Jang, Jaewon

2011-01-01T23:59:59.000Z

49

The Great Gas Hydrate Escape  

NLE Websites -- All DOE Office Websites (Extended Search)

Great Gas Great Gas Hydrate Escape The Great Gas Hydrate Escape Computer simulations revealing how methane and hydrogen pack into gas hydrates could enlighten alternative fuel production and carbon dioxide storage January 25, 2012 | Tags: Carver, Chemistry, Energy Technologies, Hopper, Materials Science PNNL Contact: Mary Beckman , +1 509 375-3688, mary.beckman@pnl.gov NERSC Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov The methane trapped in frozen water burns easily, creating ice on fire. For some time, researchers have explored flammable ice for low-carbon or alternative fuel or as a place to store carbon dioxide. Now, a computer analysis of the ice and gas compound, known as a gas hydrate, reveals key details of its structure. The results show that hydrates can hold hydrogen

50

A scheme for reducing experimental heat capacity data of gas hydrates  

SciTech Connect

Experimental heat capacity data of simple gas hydrates on xenon, methane, ethane, and propane are reduced by application of classical thermodynamics and the ideal solid solution theory. It is shown that calculated heat capacities of the empty hydrate lattices of the structure 1 and 2 hydrates can be higher or lower than the heat capacity of ice. Similarly, the calculated partial molar heat capacity of the enclathrated gases are higher or lower than the corresponding experimental ideal gas heat capacity. These differences depend on the size of the guest relative to the cavity, the hydrate number, and the temperature. For estimation of the thermodynamic properties of the empty hydrate lattice, further experimental work is recommended. Within the present limitations, a consistent methodology is applied for the prediction of the heat capacity of a natural gas hydrate.

Avlonitis, D. (Aero-engines Factory, Elefsis (Greece). Division of Chemistry)

1994-12-01T23:59:59.000Z

51

NETL: Methane Hydrates - DOE/NETL Projects - Advanced Hydrate Reservoir  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Hydrate Reservoir Modeling Using Rock Physics Techniques Last Reviewed 11/29/2013 Advanced Hydrate Reservoir Modeling Using Rock Physics Techniques Last Reviewed 11/29/2013 DE-FE0010160 Goal The primary goal of this research is to develop analytical techniques capable of quantitatively evaluating the nature of methane hydrate reservoir systems through modeling of their acoustic response using techniques that integrate rock physics theory, amplitude analysis, and spectral decomposition. Performers Fugro GeoConsulting, Inc., Houston TX Background Past efforts under the DOE-supported Gulf of Mexico Joint Industry project included the selection of well locations utilizing prospectivity analysis based primarily on a petroleum systems approach for gas hydrate using 3-D exploration seismic data and derivative analyses that produced predicted

52

NETL: Methane Hydrates - The National R&D Program - Hydrates...  

NLE Websites -- All DOE Office Websites (Extended Search)

Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 (Enrolled Bill) H.R.1753 One Hundred Sixth Congress of the United States of America AT THE...

53

NETL: Methane Hydrates - DOE/NETL Projects - Advanced Gas Hydrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Comparative Assessment of Advanced Gas Hydrate Production Methods Last Reviewed 09232009 DE-FC26-06NT42666 Goal The goal of this project is to compare and contrast, through...

54

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

While Drilling Operations The downhole logging while drilling (LWD) operations in the Gulf of Mexico Gas Hydrate JIP Drilling Program (GOM-JIP) was designed in part to obtain...

55

Methane Hydrates R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program Gas hydrates are a naturally-occurring combination of methane gas and water that form under specific conditions of low temperature and high pressure. Once thought to be rare in nature, gas hydrates are now known to occur in great abundance in association with arctic permafrost and in the shallow sediments of the deep-water continental shelves. The most recent estimates of gas hydrate abundance suggest that they contain

56

NETL: Methane Hydrates - JIP Conference  

NLE Websites -- All DOE Office Websites (Extended Search)

Maurer Technology, Inc.,and Anadarko Petroleum Corp. Geologic Characterization of the Eileen and Tarn Gas Hydrate Accumulations on the North Slope of Alaska PDF- 1.12MB Author:...

57

Methane Hydrate Advisory Committee Meeting Minutes, June 6th...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee...

58

Methane Hydrate Research and Development Act of 2000 | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 Methane Hydrate Research and...

59

Methane Hydrate Advisory Committee Meeting Minutes, January 2010...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

January 2010 Methane Hydrate Advisory Committee Meeting Minutes, January 2010 Methane Hydrate Advisory Committee Meeting Minutes January, 2010 Atlanta, GA Methane Hydrate Advisory...

60

Methane Hydrate Advisory Committee Meeting Minutes, March 2010...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

March 2010 Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane Hydrate Advisory Committee Meeting Minutes March 2010 Washington, DC Methane Hydrate Advisory...

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Numerical Modeling of Gas Recovery from Methane Hydrate Reservoirs.  

E-Print Network (OSTI)

??ABSTRACTClass 1 hydrate deposits are characterized by a hydrate bearing layer underlain by a two phase, free-gas and water, zone. A Class 1 hydrate reservoir (more)

Silpngarmlert, Suntichai

2007-01-01T23:59:59.000Z

62

Calculation of gas hydrate dissociation with finite-element model  

SciTech Connect

In situ gas hydrates have been found abundantly in the Arctic regions of the US, Canada, and Russia. Gas recovery from such a hydrate reservoir under permafrost conditions is described in the present paper. The technique is based upon a finite-element transient heat-conduction model that includes the ability to handle phase change. That model is applied to field data available from the North Slope of Alaska for predicting natural-gas production. Parametric studies have also been conducted to explore the effects of hydrate zone thickness, wellbore temperature, wellbore radius, porosity, etc., on the gas production rate. Comparisons of temperature distributions throughout the medium, and the propagation of the moving dissociation front with respect to time predicted by the present scheme and a finite-difference scheme, show good agreement. The data generated in the present study may be useful in deciding on the most optimal technique for gas recovery from hydrates. Additionally, it may provide drilling engineers with valuable information to establish guidelines for safe drilling in the presence of hydrates.

Das, D.K.; Srivastava, V. (Univ. of Alaska, Fairbanks, AK (United States). Mechanical Engineering Dept.)

1993-12-01T23:59:59.000Z

63

Modeling pure methane hydrate dissociation using a numerical simulator from a novel combination of X-ray computed tomography and macroscopic data  

SciTech Connect

The numerical simulator TOUGH+HYDRATE (T+H) was used to predict the transient pure methane hydrate (no sediment) dissociation data. X-ray computed tomography (CT) was used to visualize the methane hydrate formation and dissociation processes. A methane hydrate sample was formed from granular ice in a cylindrical vessel, and slow depressurization combined with thermal stimulation was applied to dissociate the hydrate sample. CT images showed that the water produced from the hydrate dissociation accumulated at the bottom of the vessel and increased the hydrate dissociation rate there. CT images were obtained during hydrate dissociation to confirm the radial dissociation of the hydrate sample. This radial dissociation process has implications for dissociation of hydrates in pipelines, suggesting lower dissociation times than for longitudinal dissociation. These observations were also confirmed by the numerical simulator predictions, which were in good agreement with the measured thermal data during hydrate dissociation. System pressure and sample temperature measured at the sample center followed the CH{sub 4} hydrate L{sub w}+H+V equilibrium line during hydrate dissociation. The predicted cumulative methane gas production was within 5% of the measured data. Thus, this study validated our simulation approach and assumptions, which include stationary pure methane hydrate-skeleton, equilibrium hydrate-dissociation and heat- and mass-transfer in predicting hydrate dissociation in the absence of sediments. It should be noted that the application of T+H for the pure methane hydrate system (no sediment) is outside the general applicability limits of T+H.

Gupta, A.; Moridis, G.J.; Kneafsey, T.J.; Sloan, Jr., E.D.

2009-08-15T23:59:59.000Z

64

NETL: Methane Hydrates - DOE/NETL Projects - Application of Crunch-Flow  

NLE Websites -- All DOE Office Websites (Extended Search)

Application of CrunchFlow Routines to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites Last Reviewed 12/11/2013 Application of CrunchFlow Routines to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites Last Reviewed 12/11/2013 DE-FE0010496 Goal The goal of this project is to apply a multi-component, multi-dimensional reactive transport simulation code to constrain modern day methane fluxes and to reconstruct past episodes of methane flux that can be correlated with environmental changes. Performers Oregon State University – Corvallis, OR Background The importance of understanding the role that gas hydrates play in the global carbon cycle and in understanding their potential as a future energy resource have long been recognized and are key components of the Methane Hydrate R&D Program. Fundamental questions remain, however, as to the residence time of gas hydrates near the seafloor and deeper within the

65

NETL: Methane Hydrates - DOE/NETL Projects - Kinetic Parameters for the  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetic Parameters for the Exchange of Hydrate Formers Last Reviewed 12/16/2013 Kinetic Parameters for the Exchange of Hydrate Formers Last Reviewed 12/16/2013 FWP 65213 Goal The overarching goal of this project is to gain an improved understanding of the dynamic processes of gas hydrate accumulations in geologic media by combining laboratory studies, numerical simulation, and analysis of shipboard infrared imaging of hydrate core samples. This project comprises four principal components: (1) fundamental laboratory investigations, (2) numerical simulator development and verification, (3) hydrate core characterization and analysis, and (4) applied laboratory and numerical investigations. Performer Pacific Northwest National Laboratory (PNNL), Richland, Washington Background Numerical Simulation A new simulator in the STOMP simulator series for the production of natural

66

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 DE-FC26-01NT41329 photo of a man showing the pressure core sampler on the deck of JOIDES Resolution Pressure core sampler on deck courtesy Texas A&M University Goal The goal of the project was to characterize hydrate accumulation at Hydrate Ridge (offshore Oregon) and improve the ability to use geophysical and subsurface logging to identify hydrates. A follow-on goal was to characterize hydrate accumulation at offshore Vancouver Island, BC, Canada. Background This project focused on physically verifying the existence of hydrates at Hydrate Ridge through the collection of pressurized and non-pressurized core samples and logging data. This study developed and tested tools to

67

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

area, known as Mississippi Canyon lease block 118, is well-known for the occurrence of methane hydrate and is the location of the University of Mississippis gas hydrate...

68

Methane Hydrates - Mt. Elbert Well Log Data  

NLE Websites -- All DOE Office Websites (Extended Search)

more. Project background information - Alaska North Slope Gas Hydrate Reservoir Characterization - DE-FC26-01NT41332 More information on the National Methane Hydrates R&D Program...

69

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Photo of hydrate saturated, fine grained sand core from the Mt. Elbert 1 well Hydrate saturated, fine grained sand core from the Mt. Elbert 1 well .- click on image to enlarge...

70

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrates Research Database and Web Dissemination Channel Last Reviewed 1202010 DE-AI26-06NT42938 Goal The goal of this project is to facilitate advances in hydrate applications...

71

Natural Gas Hydrates Update 1998-2000  

Reports and Publications (EIA)

Significant events have transpired on the natural gas hydrate research and development front since "Future Supply Potential of Natural Gas Hydrates" appeared in Natural Gas 1998 Issues and Trends and in the Potential Gas Committee's 1998 biennial report.

David F. Morehouse

2001-04-25T23:59:59.000Z

72

Dehydration of plutonium trichloride hydrate  

DOE Patents (OSTI)

A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.

Foropoulos, J. Jr.; Avens, L.R.; Trujillo, E.A.

1991-12-31T23:59:59.000Z

73

Natural Gas Hydrates Update 2000-2002  

Reports and Publications (EIA)

Natural gas hydrates research and development (R&D) activity expanded significantly during the 2000-2002.

David F. Morehouse

2003-04-01T23:59:59.000Z

74

Gas hydrate reservoir characteristics and economics  

SciTech Connect

The primary objective of the DOE-funded USGS Gas Hydrate Program is to assess the production characteristics and economic potential of gas hydrates in northern Alaska. The objectives of this project for FY-1992 will include the following: (1) Utilize industry seismic data to assess the distribution of gas hydrates within the nearshore Alaskan continental shelf between Harrison Bay and Prudhoe Bay; (2) Further characterize and quantify the well-log characteristics of gas hydrates; and (3) Establish gas monitoring stations over the Eileen fault zone in northern Alaska, which will be used to measure gas flux from destabilized hydrates.

Collett, T.S.; Bird, K.J.; Burruss, R.C.; Lee, Myung W.

1992-01-01T23:59:59.000Z

75

Gas hydrate reservoir characteristics and economics  

SciTech Connect

The primary objective of the DOE-funded USGS Gas Hydrate Program is to assess the production characteristics and economic potential of gas hydrates in northern Alaska. The objectives of this project for FY-1992 will include the following: (1) Utilize industry seismic data to assess the distribution of gas hydrates within the nearshore Alaskan continental shelf between Harrison Bay and Prudhoe Bay; (2) Further characterize and quantify the well-log characteristics of gas hydrates; and (3) Establish gas monitoring stations over the Eileen fault zone in northern Alaska, which will be used to measure gas flux from destabilized hydrates.

Collett, T.S.; Bird, K.J.; Burruss, R.C.; Lee, Myung W.

1992-06-01T23:59:59.000Z

76

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Interrelation of Global Climate and the Response of Oceanic Hydrate Accumulations Last Reviewed 8/21/2013 Interrelation of Global Climate and the Response of Oceanic Hydrate Accumulations Last Reviewed 8/21/2013 Field Work Proposals: ESD07-014 (LBNL) and 08FE-003 (LANL) Project Goal The primary objectives of this project are to: 1) investigate the effect of rising water temperatures on the stability of oceanic hydrate accumulations, 2) estimate the global quantity of hydrate-originating carbon that could reach the upper atmosphere as CH4 or CO2 thus affecting global climate, 3) quantify the interrelationship between global climate and the amount of hydrate-derived carbon reaching the upper atmosphere focusing on the potential link between hydrate dissociation and cascading global warming and 4) test the discharge phase of the Clathrate Gun Hypothesis which stipulates large-scale hydrate dissociation and gas

77

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Petrophysical Characterization and Reservoir Simulator for Gas Hydrate Production and Hazard Avoidance in the Gulf of Mexico Petrophysical Characterization and Reservoir Simulator for Gas Hydrate Production and Hazard Avoidance in the Gulf of Mexico DE-FC26-02NT41327 Goal The project goal was to develop new methodologies to characterize the physical properties of methane hydrate and hydrate sediment systems. Performers Westport Technology Center International - Houston, TX University of Houston - Houston, TX Results Project researchers created a pressure cell for measuring acoustic velocity and resistivity on hydrate-sediment cores. They utilized the measurements for input to an existing reservoir model for evaluating possible offshore hydrate accumulations. The organization of an industry-led Advisory Board and the development of a Research Management Plan have been completed. The development of a handbook for transporting, preserving, and storing hydrate core samples brought from the field to the laboratory was completed and distributed for review by industry and researchers.

78

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

- Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 - Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 Project Goals The primary goals of the DOE/NETL Natural Gas Hydrate Field Studies (NGHFS) project are: Conduct field-based studies that advance the ability to predict, detect, characterize, and understand distribution of and controls on natural gas hydrate occurrences. Analyze geologic, geochemical, and microbiologic data for indications of past and current changes to the stability of natural gas hydrate in marine settings. Develop links between the U.S. Gas Hydrate Program and international R&D efforts through direct participation in international field programs and workshops. Evaluate the potential role natural gas hydrates may play in the global carbon cycle through analysis of modern and paleo-natural gas

79

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 EST-380-NEDA Goal The purpose of this study is to establish sediment lithology and quantification of methane in hydrates hosted in fine-grained sediments from the Gulf of Mexico (GoM), a marine site of methane hydrate occurrence. The results will help establish a correlation between laboratory data and hydrate accumulation field data on dispersed hydrates in the natural environment. Performer Brookhaven National Laboratory (BNL), Upton, New York 11973 Background Gas hydrates are located in permafrost and marine environments and show potential as a vast methane source worldwide. However, methane is about 17 times more potent a greenhouse gas than CO2 and the inherent instability of

80

Methane Hydrate Advisory Committee | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Advisory Methane Hydrate Advisory Committee Methane Hydrate Advisory Committee The Methane Hydrate Advisory Committee was created in response to provisions of the Methane Hydrate Research and Development Act of 2000 and reauthorized by the Energy Policy Act of 2005. The Committee is to advise the Secretary of Energy on potential applications of methane hydrate; assist in developing recommendations and priorities for the methane hydrate research and development program; and submit to Congress one or more reports on an assessment of the research program and an assessment of the DOE 5-year research plan. The Committee's charter stipulates that up to 15 members can be appointed by the Secretary of Energy, representing institutions of higher education, industrial enterprises and oceanographic institutions and state agencies.

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

– Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 – Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 Project Objective Observe hydrate formation and dissociation phenomena in various porous media and characterize hydrate-bearing sediments by estimating physical properties (kinetic parameters for hydrate formation and dissociation, thermal conductivity, permeability, relative permeability, and mechanical strength) to enhance fundamental understanding on hydrate formation and accumulation and to support numerical simulations and potential gas hydrate production Project Performers Yongkoo Seol – NETL Office of Research & Development Jeong Choi – Oak Ridge Institute for Science and Education Jongho Cha-Virginia Polytech Institute Project Location National Energy Technology Laboratory - Morgantown, West Virginia

82

Methane Hydrate Production Feasibility | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Production Feasibility Production Feasibility Methane Hydrate Production Feasibility The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. Methane, the predominant component of natural gas, forms hydrate in the presence of water, low temperatures and high pressures. Alternatively, when the temperature is increased or the pressure decreased so that hydrates are outside their stability field, they dissociate into methane and water.

83

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterization of Natural Hydrate Bearing Sediments and Hydrate Dissociation Kinetics Last Reviewed 12/6/2013 Characterization of Natural Hydrate Bearing Sediments and Hydrate Dissociation Kinetics Last Reviewed 12/6/2013 FWP-45133 Work conducted under this field work proposal (FWP) includes two distinct phases. Ongoing Phase 2 work is discussed directly below. Click here to review the completed, Phase 1 work, associated with this FWP. Phase 2 Project Information Characterization of Natural Hydrate Bearing Core Samples Goal The overarching goal of this project is to gain an improved understanding of the dynamic processes of gas hydrate accumulations in geologic media by combining laboratory studies, numerical simulation, and analysis of shipboard infrared imaging of hydrate core samples. This project comprises four principal components: (1) fundamental laboratory investigations, (2)

84

NETL: Methane Hydrates - DOE/NETL Projects - Hydrate-Bearing Clayey  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering/Geological Implications Last Reviewed 12/30/2013 Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering/Geological Implications Last Reviewed 12/30/2013 DE-FE0009897 Goal The primary goal of this research effort is to contribute to an in-depth understanding of hydrate bearing, fine-grained sediments with a focus on investigation of their potential for hydrate-based gas production. Performer Georgia Tech Research Corporation, Atlanta GA Background Fine-grained sediments host more than 90 percent of global gas hydrate accumulation. Yet hydrate formation in clay-dominated sediments is less understood and characterized than other types of hydrate occurrence. There is an inadequate understanding of hydrate formation mechanisms, segregation structures, hydrate-lense topology, system connectivity, and physical

85

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

Wireline Logging Wireline Logging From: Timothy Collett, USGS Conventional Wireline Logging Operations in the Gulf of Mexico Gas Hydrate JIP Drilling Program Conventional wireline (CWL) logging operations in the Gulf of Mexico Gas Hydrate JIP Drilling Program (GOM-JIP) was scheduled to include the deployment of a signal logging string (Figure 1) and a vertical seismic profiling (VSP) tool (Figure 2) in several of the Atwater Valley and Keathley Canyon drill sites. The only wireline logging tool scheduled to be deployed was the FMS-sonic tool string, which consisted of the Formation MicroScanner (FMS), a general purpose inclinometer tool (GPIT), and scintillation gamma ray tool (SGT), and the dipole shear sonic imager tool (DSI). The vertical seismic imager tool (VSI) will also be deployed during the GOM-JIP drilling program. The wireline logging tools were provided by Schlumberger wireline services.

86

NETL: Methane Hydrates - 2012 Ignik Sikumi gas hydrate field trial  

NLE Websites -- All DOE Office Websites (Extended Search)

2012 Ignik Sikumi gas hydrate field trial 2012 Ignik Sikumi gas hydrate field trial Photo of the Ignik Drilling Pad Download 2011/2012 Field Test Data Ignik Sikumi #1 "Fire in the Ice" Video Project Background Participants Ignik Sikumi Well Review CO2-Ch4 Exchange Overview August 2, 2013 - Project operations are complete. Read the Final Project Technical Report [PDF-44.1MB] February 19, 2013 - Data from the 2011/2012 field test is now available! Click here to access data. Status Report - May 7, 2012 Final abandonment of Ignik Sikumi #1 wellsite has been completed. Tubing, casing-tubing annulus, and flatpack were filled with cement per the abandonment procedure approved by the Alaska Oil and Gas Conservation Commission. To minimize effects on the landscape and leave as little trace of the operations as possible, a small area around the wellhead was

87

Multiple stage multiple filter hydrate store  

DOE Patents (OSTI)

An improved hydrate store for a metal halogen battery system is disclosed which employs a multiple stage, multiple filter means for separating the halogen hydrate from the liquid used in forming the hydrate. The filter means is constructed in the form of three separate sections which combine to substantially cover the interior surface of the store container. Exit conduit means is provided in association with the filter means for transmitting liquid passing through the filter means to a hydrate former subsystem. The hydrate former subsystem combines the halogen gas generated during the charging of the battery system with the liquid to form the hydrate in association with the store. Relief valve means is interposed in the exit conduit means for controlling the operation of the separate sections of the filter means, such that the liquid flow through the exit conduit means from each of the separate sections is controlled in a predetermined sequence. The three separate sections of the filter means operate in three discrete stages to provide a substantially uniform liquid flow to the hydrate former subsystem during the charging of the battery system. The separation of the liquid from the hydrate causes an increase in the density of the hydrate by concentrating the hydrate along the filter means. 7 figs.

Bjorkman, H.K. Jr.

1983-05-31T23:59:59.000Z

88

Gas hydrates: Technology status report  

Science Conference Proceedings (OSTI)

In 1983, the US Department of Energy (DOE) assumed the responsibility for expanding the knowledge base and for developing methods to recover gas from hydrates. These are ice-like mixtures of gas and water where gas molecules are trapped within a framework of water molecules. This research is part of the Unconventional Gas Recovery (UGR) program, a multidisciplinary effort that focuses on developing the technology to produce natural gas from resources that have been classified as unconventional because of their unique geologies and production mechanisms. Current work on gas hydrates emphasizes geological studies; characterization of the resource; and generic research, including modeling of reservoir conditions, production concepts, and predictive strategies for stimulated wells. Complementing this work is research on in situ detection of hydrates and field tests to verify extraction methods. Thus, current research will provide a comprehensive technology base from which estimates of reserve potential can be made, and from which industry can develop recovery strategies. 7 refs., 3 figs., 6 tabs.

Not Available

1987-01-01T23:59:59.000Z

89

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 DE-FC26-06NT42960 Goal The goal of this project is to improve the understanding of regional and local differences in gas hydrate systems from three perspectives: as an energy resource, as a geohazard, and as a long-term influence on global climate. Performers Rice University, Houston, TX University of Texas, Austin, TX Oklahoma State University, Stillwater, OK Background Heterogeneity in the distribution of gas hydrate accumulations impacts all aspects of research into gas hydrate natural systems. The challenge is to delineate, understand, and appreciate these differences at the regional and local scales, where differences in in situ concentrations are relevant to the importance of gas hydrate as a resource, a geohazard, and a factor in

90

Rapid Gas Hydrate Formation Process Opportunity  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Hydrate Formation Process Gas Hydrate Formation Process Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking collaborative research and licensing partners interested in implementing United States Non-provisional Patent Application entitled "Rapid Gas Hydrate Formation Process." Disclosed in this application is a method and device for producing gas hydrates from a two-phase mixture of water and a hydrate forming gas such as methane (CH 4 ) or carbon dioxide (CO 2 ). The two-phase mixture is created in a mixing zone, which may be contained within the body of the spray nozzle. The two-phase mixture is subsequently sprayed into a reaction vessel, under pressure and temperature conditions suitable for gas hydrate formation. The reaction

91

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed DE-NT0006553 Goal The goal of this project is to define, plan, conduct and evaluate the results of a field trial of a methane hydrate production methodology whereby carbon dioxide (CO2) molecules are exchanged in situ for methane (CH4) molecules within a hydrate structure, releasing the methane for production. The objective is to evaluate the viability of this hydrate production technique and to understand the implications of the process at a field scale. image showing Conceptual rendering of proposed CO2 - CH4 exchange methodology for the production of natural gas from hydrates Conceptual rendering of proposed CO2 - CH4 exchange methodology for the

92

Development of Alaskan gas hydrate resources  

Science Conference Proceedings (OSTI)

The research undertaken in this project pertains to study of various techniques for production of natural gas from Alaskan gas hydrates such as, depressurization, injection of hot water, steam, brine, methanol and ethylene glycol solutions through experimental investigation of decomposition characteristics of hydrate cores. An experimental study has been conducted to measure the effective gas permeability changes as hydrates form in the sandpack and the results have been used to determine the reduction in the effective gas permeability of the sandpack as a function of hydrate saturation. A user friendly, interactive, menu-driven, numerical difference simulator has been developed to model the dissociation of natural gas hydrates in porous media with variable thermal properties. A numerical, finite element simulator has been developed to model the dissociation of hydrates during hot water injection process.

Kamath, V.A.; Sharma, G.D.; Patil, S.L.

1991-06-01T23:59:59.000Z

93

2.0 Closed-Domain Hydrate Dissociation (Base Case w/ Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

Closed-Domain Hydrate Dissociation (Base Case w/ Hydrate) Closed-Domain Hydrate Dissociation (Base Case w/ Hydrate) 2.1 Problem Description One half of a 20-m, one-dimensional horizontal domain, discretized using uniformly spaced 1-m grid cells (optionally 0.1-m grid cells) is initialized with aqueous-hydrate conditions; whereas, the other half of the domain is initialized with gas-aqueous conditions. As with the Base Case problem, a closed horizontal domain is used to eliminate gravitational body forces and boundary condition effects. The initial conditions are specified to yield complete dissociation of the hydrate, via the thermal capacitance of the domain-half initialized with gas-aqueous conditions. To initialize the aqueous-hydrate half of the domain, temperature, pressure, and hydrate saturation are

94

Temperature effect on the small-to-large crossover length-scale of hydrophobic hydration  

E-Print Network (OSTI)

The thermodynamics of hydration changes gradually from entropic for small solutes to enthalpic for large ones. The small-to-large crossover lengthscale of hydrophobic hydration depends on the thermodynamic conditions of the solvent such as temperature, pressure, presence of additives, etc... We attempt to shed some light on the temperature dependence of the crossover lengthscale by using a probabilistic approach to water hydrogen bonding that allows one to obtain an analytic expression for the number of bonds per water molecule as a function of both its distance to a solute and solute radius. Incorporating that approach into the density functional theory, one can examine the solute size effects on its hydration over the entire small-to-large lengthscale range at different temperatures. Knowing the dependence of the hydration free energy on temperature and solute size, one can obtain its enthalpic and entropic contributions as functions of temperature and solute size. These function can provide interesting insight into the temperature dependence of the crossover lengthscale of hydrophobic hydration. The model was applied to the hydration of spherical particles of various radii in water in the temperature range from T=293.15 K to T=333.15 K. The model predictions for the temperature dependence of the hydration free energy of small hydrophobes are consistent with the experimental and simulational data. Three alternative definitions for the small-to-large crossover length-scale of hydrophobic hydration are proposed, and their temperature dependence is obtained. Depending on the definition and temperature, the small-to-large crossover in the hydration mechanism is predicted to occur for hydrophobes of radii from one to several nanometers. Independent of its definition, the crossover length-scale is predicted to decrease with increasing temperature.

Yuri S. Djikaev; Eli Ruckenstein

2013-03-19T23:59:59.000Z

95

Detection and Production of Methane Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

July-September 2007 July-September 2007 Detection and Production of Methane Hydrate Submitted by: Rice University University of Houston George J. Hirasaki Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; FAX: 713-348-5478; Email: gjh@rice.edu Prepared for: United States Department of Energy National Energy Technology Laboratory December, 2007 Office of Fossil Energy Table of Contents DOE Methane Hydrate Program Peer Review.................................................. 3 Task 5: Carbon Inputs and Outputs to Gas Hydrate Systems ........................... 3 Task 6: Numerical Models for Quantification of Hydrate and Free Gas Accumulations....................................................................................................

96

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects, and inhibitor-induced effects. Under this project, LBNL...

97

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

and yield insight into the relative merit of various contemplated production and stimulation methods for gas hydrate. Accomplishments Field Testing (Phase 3) Completion of...

98

Electrical Resistivity Investigation of Gas Hydrate Distribution...  

NLE Websites -- All DOE Office Websites (Extended Search)

10 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354...

99

Electrical Resistivity Investigation of Gas Hydrate Distribution...  

NLE Websites -- All DOE Office Websites (Extended Search)

January 1 - March 31, 2011 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One...

100

Electrical Resistivity Investigation of Gas Hydrate Distribution...  

NLE Websites -- All DOE Office Websites (Extended Search)

09 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354...

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Electrical Resistivity Investigation of Gas Hydrate Distribution...  

NLE Websites -- All DOE Office Websites (Extended Search)

January 1 - March 31, 2012 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One...

102

Electrical Resistivity Investigation of Gas Hydrate Distribution...  

NLE Websites -- All DOE Office Websites (Extended Search)

April 1 - June 30, 2011 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One...

103

Electrical Resistivity Investigation of Gas Hydrate Distribution...  

NLE Websites -- All DOE Office Websites (Extended Search)

July 1 - September 30, 2011 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One...

104

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5102012 ESD05-048 Goal The project is bringing new laboratory measurements and...

105

Methane Hydrate Advisory Committee Meeting Minutes | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

16, 2013 Washington, DC July 16, 2013 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes Electricity Advisory Committee Notice of Open...

106

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

late Quaternary. An investigation of the nature of deposition and alteration of the methane hydrate in cores from the Umnak Plateau in the southeastern Bering Sea was conducted...

107

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

during NGHP Expedition 01 Background Gas hydrate distribution in sediments depends on methane supply, which in turn depends on fluid flow. When drilling data are available to...

108

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

(RUS) technique to examine hydrate formationdissociation processes. For determining methane abundance and location on a grain-to-grain scale, a completely new method of...

109

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

on the behavior of gas hydrates in their natural environment under either production (methane gas extraction) or climate change scenarios. This research is closely linked with...

110

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Determine the potential impacts of gas hydrate instability in terms of the release of methane into seafloor sediments, the ocean and the atmosphere. Performers University of...

111

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02172010 EST-380-NEDA Goal The purpose of this study is to...

112

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

and presentations as well as a listing of funded students can be found in the Methane Hydrate Program Bibliography PDF. A final report is available by request. Contact...

113

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

and presentations as well as a listing of funded students can be found in the Methane Hydrate Program Bibliography PDF. Final Project Report PDF-23MB - October, 2009...

114

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterization project has resulted in a characterization of two large prospective methane hydrate accumulations (or trends); the Eileen Trend, which underlies but extends well...

115

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Structure and Physical Properties of Methane Hydrate Deposit at Blake Ridge Last Reviewed 02052010 Bathymetric location map of the Blake Ridge study area Bathymetric location map...

116

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Slope represents an important milestone in an ongoing evaluation of Alaskan Arctic methane hydrate potential. This evaluation, a joint effort of DOE, USGS, BP Exploration...

117

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Survey, Woods Hole Field Center Location Woods Hole Massachusetts Background Oceanic methane hydrates are a major emerging research topic spanning energy resource issues, global...

118

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Participants The organizations involved in the DOENETL-funded Alaska North Slope Gas Hydrate Reservoir Characterization project, of which the drilling of the Mt. Elbert...

119

Methane Hydrate Production from Alaskan Permafrost  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE and Maurer Technology are to evaluate the subsurface hydrate occurrence and its production potential. It is anticipated that it will require two to three months from spud...

120

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Seol, Y. and T. J. Kneafsey, Methane hydrate induced permeability modification for multiphase flow in unsaturated porous media, Journal of Geophysical Research, 2011, In...

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Physical Properties of Gas Hydrates: A Review  

SciTech Connect

Methane gas hydrates in sediments have been studied by several investigators as a possible future energy resource. Recent hydrate reserves have been estimated at approximately 1016?m3 of methane gas worldwide at standard temperature and pressure conditions. In situ dissociation of natural gas hydrate is necessary in order to commercially exploit the resource from the natural-gas-hydrate-bearing sediment. The presence of gas hydrates in sediments dramatically alters some of the normal physical properties of the sediment. These changes can be detected by field measurements and by down-hole logs. An understanding of the physical properties of hydrate-bearing sediments is necessary for interpretation of geophysical data collected in field settings, borehole, and slope stability analyses; reservoir simulation; and production models. This work reviews information available in literature related to the physical properties of sediments containing gas hydrates. A brief review of the physical properties of bulk gas hydrates is included. Detection methods, morphology, and relevant physical properties of gas-hydrate-bearing sediments are also discussed.

Gabitto, Jorge [Prairie View A& M University; Tsouris, Costas [ORNL

2010-01-01T23:59:59.000Z

122

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

associated gas hydrate deposits on continental margins by compiling a remote sensing inventory of active gas and oil vents, and completing sea-truth measurement of flux from...

123

Natural gas production from Arctic gas hydrates  

Science Conference Proceedings (OSTI)

The natural gas hydrates of the Messoyakha field in the West Siberian basin of Russia and those of the Prudhoe Bay-Kuparuk River area on the North Slope of Alaska occur within a similar series of interbedded Cretaceous and Tertiary sandstone and siltstone reservoirs. Geochemical analyses of gaseous well-cuttings and production gases suggest that these two hydrate accumulations contain a mixture of thermogenic methane migrated from a deep source and shallow, microbial methane that was either directly converted to gas hydrate or was first concentrated in existing traps and later converted to gas hydrate. Studies of well logs and seismic data have documented a large free-gas accumulation trapped stratigraphically downdip of the gas hydrates in the Prudhoe Bay-Kuparuk River area. The presence of a gas-hydrate/free-gas contact in the Prudhoe Bay-Kuparuk River area is analogous to that in the Messoyakha gas-hydrate/free-gas accumulation, from which approximately 5.17x10[sup 9] cubic meters (183 billion cubic feet) of gas have been produced from the hydrates alone. The apparent geologic similarities between these two accumulations suggest that the gas-hydrated-depressurization production method used in the Messoyakha field may have direct application in northern Alaska. 30 refs., 15 figs., 3 tabs.

Collett, T.S. (Geological Survey, Denver, CO (United States))

1993-01-01T23:59:59.000Z

124

Desalination utilizing clathrate hydrates (LDRD final report).  

DOE Green Energy (OSTI)

Advances are reported in several aspects of clathrate hydrate desalination fundamentals necessary to develop an economical means to produce municipal quantities of potable water from seawater or brackish feedstock. These aspects include the following, (1) advances in defining the most promising systems design based on new types of hydrate guest molecules, (2) selection of optimal multi-phase reactors and separation arrangements, and, (3) applicability of an inert heat exchange fluid to moderate hydrate growth, control the morphology of the solid hydrate material formed, and facilitate separation of hydrate solids from concentrated brine. The rate of R141b hydrate formation was determined and found to depend only on the degree of supercooling. The rate of R141b hydrate formation in the presence of a heat exchange fluid depended on the degree of supercooling according to the same rate equation as pure R141b with secondary dependence on salinity. Experiments demonstrated that a perfluorocarbon heat exchange fluid assisted separation of R141b hydrates from brine. Preliminary experiments using the guest species, difluoromethane, showed that hydrate formation rates were substantial at temperatures up to at least 12 C and demonstrated partial separation of water from brine. We present a detailed molecular picture of the structure and dynamics of R141b guest molecules within water cages, obtained from ab initio calculations, molecular dynamics simulations, and Raman spectroscopy. Density functional theory calculations were used to provide an energetic and molecular orbital description of R141b stability in both large and small cages in a structure II hydrate. Additionally, the hydrate of an isomer, 1,2-dichloro-1-fluoroethane, does not form at ambient conditions because of extensive overlap of electron density between guest and host. Classical molecular dynamics simulations and laboratory trials support the results for the isomer hydrate. Molecular dynamics simulations show that R141b hydrate is stable at temperatures up to 265K, while the isomer hydrate is only stable up to 150K. Despite hydrogen bonding between guest and host, R141b molecules rotated freely within the water cage. The Raman spectrum of R141b in both the pure and hydrate phases was also compared with vibrational analysis from both computational methods. In particular, the frequency of the C-Cl stretch mode (585 cm{sup -1}) undergoes a shift to higher frequency in the hydrate phase. Raman spectra also indicate that this peak undergoes splitting and intensity variation as the temperature is decreased from 4 C to -4 C.

Simmons, Blake Alexander; Bradshaw, Robert W.; Dedrick, Daniel E.; Cygan, Randall Timothy (Sandia National Laboratories, Albuquerque, NM); Greathouse, Jeffery A. (Sandia National Laboratories, Albuquerque, NM); Majzoub, Eric H. (University of Missouri, Columbia, MO)

2008-01-01T23:59:59.000Z

125

CX-009264: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-009264: Categorical Exclusion Determination Controls on Methane Expulsion During Melting of Natural Gas Hydrate Systems CX(s) Applied: B3.6 Date: 09...

126

CX-009266: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-009266: Categorical Exclusion Determination Controls on Methane Expulsion During Melting of Natural Gas Hydrate Systems CX(s) Applied: A9 Date: 09...

127

CX-009304: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-009304: Categorical Exclusion Determination Planning of a Marine Methane Hydrate Pressure Coring Program CX(s) Applied: A1, A9 Date: 08312012 Location(s):...

128

CX-000733: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-000733: Categorical Exclusion Determination Detection and Production of Methane Hydrates CX(s) Applied: A9 Date: 01222010 Location(s): Austin,...

129

CX-000734: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-000734: Categorical Exclusion Determination Detection and Production of Methane Hydrates CX(s) Applied: A9 Date: 01222010 Location(s): Stillwater,...

130

CX-005054: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-005054: Categorical Exclusion Determination Gas Hydrate Production Test (Phase III - AdministrativePlanningModeling Tasks) CX(s) Applied: A2,...

131

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

The DOE/JIP Gulf of Mexico Hydrate Research Cruise The DOE/JIP Gulf of Mexico Hydrate Research Cruise Status Reports During this expedition we will maintain an intermittent log of information relayed from the chief scientist on the expedition. To view a report for a particular day click on the "Day x" link in any highlighted box. The planned cruise timeline [PDF-13KB] is April 17 - May 21, 2005. This is the "planned" timeline. The schedule may change without prior notification due weather conditions or other unplanned occurrences. April 17 Day 1 April 18 Day 2 April 19 Day 3 April 20 Day 4 April 21 Day 5 April 22 Day 6 April 23 Day 7 April 24 Day 8 April 25 Day 9 April 26 Day 10 April 27 Day 11 April 28 Day 12 April 29 Day 13 April 30 Day 14 May 1 Day 15 May 2 Day 16 May 3 Day 17 May 4 Day 18 May 5

132

NETL: Methane Hydrates - DOE/NETL Projects - Fate of methane...  

NLE Websites -- All DOE Office Websites (Extended Search)

Numerical modeling: Constraining the conditions under which rising bubbles become armored with hydrate, the impact of hydrate armoring on the eventual fate of a bubbles...

133

Methane Hydrate Advisory Committee Meeting Minutes, October 2011...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

October 2011 Methane Hydrate Advisory Committee Meeting Minutes, October 2011 Methane Hydrate Advisory Committee Meeting Minutes October 2011 Washington, DC Advisory Committee...

134

METHANE HYDRATE ADVISORY COMMITTEE U.S. DEPARTMENT OF ENERGY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

METHANE HYDRATE ADVISORY COMMITTEE U.S. DEPARTMENT OF ENERGY Advisory Committee Charter 1. Committee's Official Designation. Methane Hydrate Advisory Committee (MHAC) 2. Authority....

135

Department of Energy Advance Methane Hydrates Science and Technology...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advance Methane Hydrates Science and Technology Projects Department of Energy Advance Methane Hydrates Science and Technology Projects Descriptions for Energy Department Methane...

136

NETL: Methane Hydrates - DOE/NETL Projects - Mapping Permafrost...  

NLE Websites -- All DOE Office Websites (Extended Search)

20 percent of the land area in the northern hemisphere and often contains associated methane hydrate. Numerous studies have indicated that permafrost and hydrate are actively...

137

Method for the Photocatalytic Conversion of Gas Hydrates  

NLE Websites -- All DOE Office Websites (Extended Search)

the Photocatalytic Conversion of Gas Hydrates Opportunity Research is currently active on the patented technology "Method for the Photocatalytic Conversion of Gas Hydrates." The...

138

A Comparison Study of Portland Cement Hydration Kinetics as ...  

Science Conference Proceedings (OSTI)

... especially around the main hydration peaks. ... at the main hydration peak) seems to create a ... Oil Well Cement, Cement and Concrete Research 40 ...

2013-05-22T23:59:59.000Z

139

Determination of mixed hydrate thermodynamics for reservoir modeling.  

E-Print Network (OSTI)

??Natural gas hydrates are likely to contain more carbon than in all other fossil fuel reserves combined worldwide. Most of the natural gas hydrate deposits (more)

Garapati, Nagasree.

2009-01-01T23:59:59.000Z

140

NETL: Methane Hydrates - DOE/NETL Projects - Natural Gas Hydrates in  

NLE Websites -- All DOE Office Websites (Extended Search)

The National Methane Hydrates R&D Program The National Methane Hydrates R&D Program DOE/NETL Methane Hydrate Projects Natural Gas Hydrates in Permafrost and Marine Settings: Resources, Properties, and Environmental Issues Last Reviewed 12/30/2013 DE-FE0002911 Goal The objective of this DOE-USGS Interagency Agreement is to provide world-class expertise and research in support of the goals of the 2005 Energy Act for National Methane Hydrates R&D, the DOE-led U.S. interagency roadmap for gas hydrates research, and elements of the USGS mission related to energy resources, global climate, and geohazards. This project extends USGS support to the DOE Methane Hydrate R&D Program previously conducted under DE-AI26-05NT42496. Performer U.S. Geological Survey at Woods Hole, MA, Denver, CO, and Menlo Park, CA

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Photo Gallery Photo Gallery Photo of hydrate saturated, fine grained sand core from the Mt. Elbert #1 well Hydrate saturated, fine grained sand core from the Mt. Elbert #1 well .- click on image to enlarge Photo of close up of fine grained sand core sample. This sample was taken for porewater geochemical analyses and was hydrate saturated at the time of recovery. Close up of fine grained sand core sample. This sample was taken for porewater geochemical analyses and was hydrate saturated at the time of recovery.- click on image to enlarge Photo of close up of fine grained sand core sample being placed in water. Links to video of hydrate dissociating One visual test used to confirm that a core contains hydrate is to place a small sample from the core in a canister of water. The gas dissociated from the hydrate-bearing sediment is released into the water and bubbles to the surface. In the video sequence shown here, dissociated hydrate gas from a sample of Mt. Elbert #1 core can be seen and heard as it is released into the water. - click on image to view video [MPEG]

142

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station DE-FC26-02NT41328 Goal Determine the potential impacts of gas hydrate instability in terms of the release of methane into seafloor sediments, the ocean and the atmosphere. Performers University of California, San Diego (Scripps Institution of Oceanography) - manage geochemical, hydrological and sedimentological investigations Texas A&M University - manage field monitoring program Location La Jolla, California 92093 Background This project will monitor, characterize, and quantify the rates of formation and dissociation of methane gas hydrates at and near the seafloor in the northern Gulf of Mexico, and determine linkages between formation/dissociation and physical/chemical parameters of the deposits over the course of a year. The stability and response of shallow gas hydrates to temperature and chemical perturbations will be monitored in situ, and localized seafloor and water column environmental impacts of hydrate formation and dissociation characterized. The following will be determined: 1) The equilibrium/steady state conditions for structure II methane gas hydrates at the field site,2) whether the system is in dynamic equilibrium and the local hydrology is characterized by steady state episodic fluid flow, and 3) how fluid fluxes and fluid composition work together to dynamically influence gas hydrate stability.

143

Solid alcohol fuel with hydration inhibiting coating  

Science Conference Proceedings (OSTI)

This patent describes a process for preparing a solid alcohol fuel. It comprises: mixing an alcohol solution with a cellulose derivative having a hydration inhibiting coating thereby forming a slurry and then adding an effective amount sufficient to increase the pH level above 8, of a caustic material so as to effect hydration and solidification.

Gartner, S.

1990-11-20T23:59:59.000Z

144

Multipole Electrostatics in Hydration Free Energy Calculations  

E-Print Network (OSTI)

Multipole Electrostatics in Hydration Free Energy Calculations YUE SHI,1 CHUANJIE WU,2 JAY W. PONDER,2 PENGYU REN1 1 Department of Biomedical Engineering, The University of Texas, Austin, Texas 78712: Hydration free energy (HFE) is generally used for evaluating molecular solubility, which is an important

Ponder, Jay

145

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

Science Conference Proceedings (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new Arctic Drilling Platform in search of gas hydrate and free gas accumulations at depths of approximately 1200 to 2500 ft MD. A secondary objective was the gas-charged sands of the uppermost Campanian interval at approximately 3000 ft. Summary results of geophysical analysis of the well are presented in this report.

Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

2005-02-01T23:59:59.000Z

146

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Properties of Hydrate – Tool Development Last Reviewed 3/18/2013 Thermal Properties of Hydrate – Tool Development Last Reviewed 3/18/2013 Project Goal The goal of this project is increased understanding of gas hydrate thermal properties through measurements on natural hydrate-bearing sediment cores and hydrate-bearing cores formed within laboratory pressure vessels. Project Performers Eilis Rosenbaum, NETL, Office of Research and Development Ronald Lynn, NETL, RDS/Parsons Dr. David Shaw, Geneva College Project Location National Energy Technology Laboratory, Pittsburgh, PA Background NETL utilizes a modified transient plane source (TPS) shown in Figure 1 using a technique originally developed by Gustafsson [1, 2] in a single-sided configuration (Figure 2). The TPS technique is capable of simultaneously determining both thermal conductivity and thermal

147

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gathering, Processing and Evaluating Seismic and Physical Data on Gas Hydrates in the Gulf of Mexico Last Reviewed 02/05/2010 Gathering, Processing and Evaluating Seismic and Physical Data on Gas Hydrates in the Gulf of Mexico Last Reviewed 02/05/2010 DE-AT26-97FT34343 photo of piston core apparatus prior to being dropped Piston core apparatus with 6-ton weight prior to being dropped Photo courtesy USGS Goal The goal of the project is to characterize hydrates in the Gulf of Mexico (GOM) and further develop field techniques for characterizing hydrates. Performer US Geological Survey, Woods Hole Field Center Location Woods Hole Massachusetts Background Oceanic methane hydrates are a major emerging research topic spanning energy resource issues, global climate change, seafloor stability, ocean acoustics, impact on deep marine biota, and a number of special topics. Recent developments in the last five years have both broadened and deepened

148

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Seismic-Scale Rock Physics of Methane Hydrate Seismic-Scale Rock Physics of Methane Hydrate DE-FC26-05NT42663 Goal The goal of this project was to establish rock physics models for use in generating synthetic seismic signatures of methane hydrate reservoirs. Ultimately, the intent was to improve seismic detection and quantification of offshore and onshore methane hydrate accumulations. Performer Stanford University, Stanford, CA 94305 Background Gas hydrate reservoir characterization is, in principle, no different from traditional hydrocarbon reservoir characterization. The seismic response of the subsurface is determined by the spatial distribution of the elastic properties (properties of the subsurface that deform as seismic waves pass through it) and attenuation. By mapping changes in the elastic properties, scientists can identify geologic features, including hydrocarbon reservoirs.

149

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 DE-FC26-06NT42963 Goal The goal of this project is to develop observational and experimental data that can provide a better understanding of the basic mechanisms at work in a methane hydrate reservoir that is under production. To this end, a thorough physical understanding of underlying phenomena associated with methane hydrate production will be acquired through unique, multi-scale experiments and associated analyses. In addition, one or more mathematical models that account for the observed phenomena and provide insights that may help to optimize methane hydrate production methods will be developed. Performers Georgia Tech Research Corporation, Atlanta, Georgia 30332 Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee 37831

150

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 ESD05-048 Goal The project is bringing new laboratory measurements and evaluation techniques to bear on the difficult problems of characterization and gas recovery from methane hydrate deposits. Performer Lawrence Berkeley National Laboratory, Berkeley, CA 94720 Background LBNL is performing laboratory tests to provide data to support the characterization and development of methane hydrate deposits. Major areas of research underway include hydrologic measurements, combined geomechanical/geophysical measurements, and synthetic hydrate formation studies. Hydrologic Measurements Relatively little research has been done to experimentally determine

151

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Heat flow and gas hydrates on the continental margin of India Last Reviewed 12/15/2011 Heat flow and gas hydrates on the continental margin of India Last Reviewed 12/15/2011 DE-NT0005669 Goal The goals of this project are to construct maps of apparent and residual heat flow through the western continental margin of India and to investigate the relationship of residual heat flow anomalies to fluid flow and gas hydrate distribution in the subsurface. Performer Oregon State University, College of Oceanic and Atmospheric Science, Corvallis, OR 97331 Map of the four regions sampled during NGHP Expedition 01 Map of the four regions sampled during NGHP Expedition 01 Background Gas hydrate distribution in sediments depends on methane supply, which in turn depends on fluid flow. When drilling data are available to calibrate seismic observations of the base of the gas hydrate stability zone (GHSZ),

152

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

If you need help finding information on a particular project, please contact the content manager. If you need help finding information on a particular project, please contact the content manager. Search Hydrates Projects Active Projects | Completed Projects Click on project number for a more detailed description of the project. Project Number Project Name Primary Performer DE-FC26-01NT41332 Alaska North Slope Gas Hydrate Reservoir Characterization BP Exploration Alaska, Inc. DE-FC26-01NT41330 Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico: Applications for Safe Exploration Chevron Energy Technology Company DE-FE0009897 Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering/Geological Implications Georgia Tech Research Corporation DE-FE0009904 Structural and Stratigraphic Controls on Methane Hydrate Occurrence and Distribution: Gulf of Mexico, Walker Ridge 313 and Green Canyon 955 Oklahoma State University

153

Overview on Hydrate Coring, Handling and Analysis  

SciTech Connect

Gas hydrates are crystalline, ice-like compounds of gas and water molecules that are formed under certain thermodynamic conditions. Hydrate deposits occur naturally within ocean sediments just below the sea floor at temperatures and pressures existing below about 500 meters water depth. Gas hydrate is also stable in conjunction with the permafrost in the Arctic. Most marine gas hydrate is formed of microbially generated gas. It binds huge amounts of methane into the sediments. Worldwide, gas hydrate is estimated to hold about 1016 kg of organic carbon in the form of methane (Kvenvolden et al., 1993). Gas hydrate is one of the fossil fuel resources that is yet untapped, but may play a major role in meeting the energy challenge of this century. In June 2002, Westport Technology Center was requested by the Department of Energy (DOE) to prepare a ''Best Practices Manual on Gas Hydrate Coring, Handling and Analysis'' under Award No. DE-FC26-02NT41327. The scope of the task was specifically targeted for coring sediments with hydrates in Alaska, the Gulf of Mexico (GOM) and from the present Ocean Drilling Program (ODP) drillship. The specific subjects under this scope were defined in 3 stages as follows: Stage 1: Collect information on coring sediments with hydrates, core handling, core preservation, sample transportation, analysis of the core, and long term preservation. Stage 2: Provide copies of the first draft to a list of experts and stakeholders designated by DOE. Stage 3: Produce a second draft of the manual with benefit of input from external review for delivery. The manual provides an overview of existing information available in the published literature and reports on coring, analysis, preservation and transport of gas hydrates for laboratory analysis as of June 2003. The manual was delivered as draft version 3 to the DOE Project Manager for distribution in July 2003. This Final Report is provided for records purposes.

Jon Burger; Deepak Gupta; Patrick Jacobs; John Shillinglaw

2003-06-30T23:59:59.000Z

154

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

Science Conference Proceedings (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope drilled and cored a well The HOT ICE No.1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report.

Thomas E. Williams; Keith Millheim; Buddy King

2004-06-01T23:59:59.000Z

155

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

Science Conference Proceedings (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope drilled and cored a well The HOT ICE No.1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report.

Thomas E. Williams; Keith Millheim; Buddy King

2004-07-01T23:59:59.000Z

156

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports.

Thomas E. Williams; Keith Millheim; Bill Liddell

2005-03-01T23:59:59.000Z

157

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

NLE Websites -- All DOE Office Websites (Extended Search)

Core Handling Core Handling From: Cruise Prospectus [PDF-827KB] Visit the Photo Gallery for more pictures showing core handling Non-pressurized and Pressure Core Handling Non-pressurized Core Handling (Fugro Hydraulic Piston Corer and Fugro Corer) Photo of Core packed in ice bath Core packed in ice bath Cores that might contain gas hydrates should be recovered as quickly as possible. An ice bath may be used in some cases to slow the dissociation process. A core reception/preparation van will be on the deck of the Uncle John where individual cores (perhaps up to 9 m long) can be laid on ‘core hooks' and quickly drilled, labeled and sectioned. Infrared (IR) camera imaging will be done as soon as practical after core recovery. Both track-mounted and hand held IR cameras will be used to identify the

158

Gas Hydrate Storage of Natural Gas  

Science Conference Proceedings (OSTI)

Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

Rudy Rogers; John Etheridge

2006-03-31T23:59:59.000Z

159

Methane Recovery from Hydrate-bearing Sediments  

Science Conference Proceedings (OSTI)

Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with emphasis; (6) detailed study of CH4-CO2 exchange as a unique alternative to recover CH4 gas while sequestering CO2; (7) the relevance of fines in otherwise clean sand sediments on gas recovery and related phenomena such as fines migration and clogging, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

J. Carlos Santamarina; Costas Tsouris

2011-04-30T23:59:59.000Z

160

Detection and Production of Methane Hydrate  

Science Conference Proceedings (OSTI)

This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

2011-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gulf of Mexico Gas Hydrates Joint Industry Project (JIP) Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico - Applications for Safe Exploration and Production Last Reviewed 12/18/2013 Gulf of Mexico Gas Hydrates Joint Industry Project (JIP) Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico - Applications for Safe Exploration and Production Last Reviewed 12/18/2013 DE-FC26-01NT41330 Goal: The goal of this project is to develop technology and collect data to assist in the characterization of naturally occurring gas hydrates in the deep water Gulf of Mexico (GoM). The intent of the project is to better understand the impact of hydrates on safety and seafloor stability as well as provide data for use by scientists in their study of climate change and assessment of the feasibility of marine hydrate as a potential future energy resource. Photo of the Helix Q4000 The Semi-Submersible Helix Q4000 used on the 21 day JIP Leg II Drilling and Logging Expedition

162

Gas Hydrates Research Programs: An International Review  

SciTech Connect

Gas hydrates sediments have the potential of providing a huge amount of natural gas for human use. Hydrate sediments have been found in many different regions where the required temperature and pressure conditions have been satisfied. Resource exploitation is related to the safe dissociation of the gas hydrate sediments. Basic depressurization techniques and thermal stimulation processes have been tried in pilot efforts to exploit the resource. There is a growing interest in gas hydrates all over the world due to the inevitable decline of oil and gas reserves. Many different countries are interested in this valuable resource. Unsurprisingly, developed countries with limited energy resources have taken the lead in worldwide gas hydrates research and exploration. The goal of this research project is to collect information in order to record and evaluate the relative strengths and goals of the different gas hydrates programs throughout the world. A thorough literature search about gas hydrates research activities has been conducted. The main participants in the research effort have been identified and summaries of their past and present activities reported. An evaluation section discussing present and future research activities has also been included.

Jorge Gabitto; Maria Barrufet

2009-12-09T23:59:59.000Z

163

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the second year of a three-year endeavor being sponsored by Maurer Technology, Noble, and Anadarko Petroleum, in partnership with the DOE. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition. We plan to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. We also plan to design and implement a program to safely and economically drill, core and produce gas from arctic hydrates. The current work scope is to drill and core a well on Anadarko leases in FY 2003 and 2004. We are also using an on-site core analysis laboratory to determine some of the physical characteristics of the hydrates and surrounding rock. The well is being drilled from a new Anadarko Arctic Platform that will have minimal footprint and environmental impact. We hope to correlate geology, geophysics, logs, and drilling and production data to allow reservoir models to be calibrated. Ultimately, our goal is to form an objective technical and economic evaluation of reservoir potential in Alaska.

Thomas E. Williams; Keith Millheim; Buddy King

2004-03-01T23:59:59.000Z

164

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the US have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the second year of a three-year endeavor being sponsored by maurer Technology, noble, and Anadarko Petroleum, in partnership with the DOE. The purpose of the project is to build on previous and ongoing R and D in the area of onshore hydrate deposition. They plan to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. They also plan to design and implement a program to safely and economically drill, core and produce gas from arctic hydrates. The current work scope is to drill and core a well on Anadarko leases in FY 2003 and 2004. They are also using an on-site core analysis laboratory to determine some of the physical characteristics of the hydrates and surrounding rock. The well is being drilled from a new Anadarko Arctic Platform that will have minimal footprint and environmental impact. They hope to correlate geology, geophysics, logs, and drilling and production data to allow reservoir models to be calibrated. Ultimately, the goal is to form an objective technical and economic evaluation of reservoir potential in Alaska.

Thomas E. Williams; Keith Millheim; Buddy King

2003-12-01T23:59:59.000Z

165

Department of Energy Advance Methane Hydrates Science and Technology Projects  

Energy.gov (U.S. Department of Energy (DOE))

Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

166

Noble gases and radiocarbon in natural gas hydrates Gisela Winckler  

E-Print Network (OSTI)

Noble gases and radiocarbon in natural gas hydrates Gisela Winckler Lamont-Doherty Earth 2001; published 24 May 2002. [1] In samples of pure natural gas hydrates from Hydrate Ridge, Cascadia of rigid cages of water molecules that enclose guest gas molecules. The gas component of natural hydrates

Winckler, Gisela

167

New Methane Hydrate Research: Investing in Our Energy Future | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Research: Investing in Our Energy Future Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Jenny Hakun What Are Methane Hydrates? Methane hydrates are 3D ice-lattice structures with natural gas locked inside. The substance looks remarkably like white ice, but it does not behave like ice. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas.

168

Methane Hydrate Program Annual Report to Congress  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FY 2010 FY 2010 Methane Hydrate Program Annual Report to Congress September 2011 U.S. Department of ENERGY United States Department of Energy Washington, DC 20585 Department of Energy | September 2011 FY 2010 Methane Hydrate Program Annual Report to Congress | Page 2 Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled, U.S. Department of Energy FY 2010 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of

169

Arctic Methane, Hydrates, and Global Climate  

NLE Websites -- All DOE Office Websites (Extended Search)

Arctic Methane, Hydrates, and Global Climate Arctic Methane, Hydrates, and Global Climate Speaker(s): Matthew T. Reagan Date: March 17, 2010 - 12:00pm Location: 90-3122 Paleooceanographic evidence has been used to postulate that methane may have had a significant role in regulating past climate. However, the behavior of contemporary permafrost deposits and oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. A recent expedition to the west coast of Spitsbergen discovered substantial methane gas plumes exiting the seafloor at depths that correspond to the upper limit of the receding gas hydrate stability zone. It has been suggested that these plumes may be the

170

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 DE-FC26-01NT41331 photo of new Anadarko drilling rig in place at Hot Ice No.1 on Alaska's North Slope Hot Ice No. 1 Drilling Platform courtesy Anadarko Petroleum Corp. Goal The goal of the project was to develop technologies for drilling and recovering hydrates in arctic areas. The specific objectives were to drill, core, and test a well through the hydrate stability zone in northern Alaska Performers Maurer Technology, Inc.* - Project coordination with DOE Anadarko Petroleum Corporation - Overall project management for the design, construction, and operation of the Arctic Drilling Platform and mobile core lab, and field coring operations Noble Engineering and Development* - Real time data collection and

171

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 DE-NT0005667 Goal The goal of this project is to assess the efficacy of aerobic methanotrophy in preventing the escape of methane from marine, hydrate-bearing reservoirs to the atmosphere and ultimately to better define the role of aerobic methanotrophy in the global carbon cycle. Graph overlayed on photo - Methane seeps with the resulting methane plume Methane seeps with the resulting methane plume, Geophysical Research Letters, November 2007 Performers University of California – Santa Barbara, Santa Barbara (UCSB), CA 93106 Background The global methane reservoir in the form of gas hydrate is estimated at 500–10,000 Gt (KVENVOLDEN, 1995; MILKOV, 2004). This pool of carbon

172

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Characterizing Arctic Hydrates (Canadian Test Well and Alaskan "Wells of Opportunity") Characterizing Arctic Hydrates (Canadian Test Well and Alaskan "Wells of Opportunity") photo of drilling rig at Mallik 2L-38 location Rig at Mallik 2L-38 location courtesy Geological Survey of Canada DE-AT26-97FT34342 Goal The purpose of this project is to assess the recoverability and potential production characteristics of the onshore natural gas hydrate and associated free-gas accumulations in the Arctic of North America Performer United States Geological Survey, Denver, Colorado 80225 - partner in GSC-managed consortium and provide expertise in data gathering and analysis Background The U.S. Geological Survey has been participating in natural gas hydrate reservoir research with DOE NETL through an interagency agreement which began in the early 1980’s. The work has been an ongoing effort as part of

173

Methane Hydrate Field Studies | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Field Studies Field Studies Methane Hydrate Field Studies Arctic/Alaska North Slope Field Studies Since 2001, DOE has conducted field trials of exploration and production technology in the Alaska North Slope. Although Alaska methane hydrate resources are smaller than marine deposits and currently lack outlets to commercial markets, Alaska provides an excellent laboratory to study E&P technology. The research also has implications for various Alaska resources, including potential gas hydrate resources for local communities, conventional "stranded" gas, as well as Alaska's large unconventional oil resources. The hydrate deposits have been delineated in the process of developing underlying oil fields, and drilling costs are much lower than offshore. DOE-BP Project

174

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Sampling and Characterization of Naturally Occurring Methane Hydrate Using the DV JOIDES Resolution Last Reviewed 02052010 DE-FC26-01NT41329 photo of a man showing the pressure...

175

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

that the hydrate in this region occurs in patchy deposits and may require a high methane flux from the subsurface in order to form more continuous drilling prospects. Project...

176

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

DE-AF26-01NT00370 Goal The goal of the project is to better characterize potential methane hydrate drilling sites in the Gulf of Mexico for the Ocean Drilling Program....

177

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

FWP-4340-60 and FWP-42C1-01 Goal Determine the presence and activity of methanogens in methane hydrate-bearing sediments. Background The project was set up to determine a...

178

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 182013 DE-NT0005667 Goal The goal of this project is to assess the efficacy of...

179

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

to develop a two-dimensional, basin-scale model for the deep sediment biosphere with methane dynamics to provide a better picture of the distribution of hydrates on the sea floor...

180

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Goal The overall objective of this project is to develop a new method to assess methane hydrate distribution using 3-D seismic data calibrated to wellbore data. The method...

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Production of Methane Hydrate Last Reviewed 5152012 DE-FC26-06NT42960 Goal The goal of this project is to improve the understanding of regional and local differences in gas...

182

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Hydrate Production Trial Using CO2 CH4 Exchange Last Reviewed 822013 DE-NT0006553 Goal The goal of this project is to define, plan, conduct and evaluate the results of a...

183

Detection and Production of Methane Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

and Rice to be appropriate. The initial ocean locations are Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location is Mallik. Although the ultimate goal of the...

184

NETL: News Release - Methane Hydrate Production Technologies...  

NLE Websites -- All DOE Office Websites (Extended Search)

of CO2 molecules for methane molecules in the solid-water hydrate lattice, the release of methane gas, and the permanent storage of CO2 in the formation. This field experiment will...

185

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Natural Gas Hydrates in the Deep Water Gulf of Mexico - Applications for Safe Exploration and Production Last Reviewed 6142013 DE-FC26-01NT41330 Goal: The goal of...

186

Hydrate Control for Gas Storage Operations  

Science Conference Proceedings (OSTI)

The overall objective of this project was to identify low cost hydrate control options to help mitigate and solve hydrate problems that occur in moderate and high pressure natural gas storage field operations. The study includes data on a number of flow configurations, fluids and control options that are common in natural gas storage field flow lines. The final phase of this work brings together data and experience from the hydrate flow test facility and multiple field and operator sources. It includes a compilation of basic information on operating conditions as well as candidate field separation options. Lastly the work is integrated with the work with the initial work to provide a comprehensive view of gas storage field hydrate control for field operations and storage field personnel.

Jeffrey Savidge

2008-10-31T23:59:59.000Z

187

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection and Microbiological Analysis of Gas Hydrate Cores Collection and Microbiological Analysis of Gas Hydrate Cores FWP-4340-60 and FWP-42C1-01 Goal Determine the presence and activity of methanogens in methane hydrate-bearing sediments. Background The project was set up to determine a fundamental modeling parameter - the amount of methane generated in deep sediments by methanogenic microorganisms. This would allow methane distribution models of gas hydrate reservoirs to accurately reflect an unknown volume and the distribution of biogenic methane within in a reservoir. The personnel at INEL have experience in similar biologic research and are considered to be experts by their global peers. Performer Idaho National Engineering and Environmental Laboratory (INEEL) - sample collection and analysis Location

188

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect

Natural-gas hydrates have been encountered beneath the permafrost and considered a drilling hazard by the oil and gas industry for years. Drilling engineers working in Russia, Canada and the USA have documented numerous problems, including drilling kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates as a potential energy source agree that the resource potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained from physical samples taken from actual hydrate-bearing rocks. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The project team drilled and continuously cored the Hot Ice No. 1 well on Anadarko-leased acreage beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and used for determining physical characteristics of hydrates and surrounding rock. After the well was logged, a 3D vertical seismic profile (VSP) was recorded to calibrate the shallow geologic section with seismic data and to investigate techniques to better resolve lateral subsurface variations of potential hydrate-bearing strata. Paulsson Geophysical Services, Inc. deployed their 80 level 3C clamped borehole seismic receiver array in the wellbore to record samples every 25 ft. Seismic vibrators were successively positioned at 1185 different surface positions in a circular pattern around the wellbore. This technique generated a 3D image of the subsurface. Correlations were generated of these seismic data with cores, logging, and other well data. Unfortunately, the Hot Ice No. 1 well did not encounter hydrates in the reservoir sands, although brine-saturated sands containing minor amounts of methane were encountered within the hydrate stability zone (HSZ). Synthetic seismograms created from well log data were in agreement with reflectivity data measured by the 3D VSP survey. Modeled synthetic seismograms indicated a detectable seismic response would be expected in the presence of hydrate-bearing sands. Such a response was detected in the 3D VSP data at locations up-dip to the west of the Hot Ice No. 1 wellbore. Results of this project suggest that the presence of hydrate-bearing strata may not be related as simply to HSZ thickness as previously thought. Geological complications of reservoir facies distribution within fluvial-deltaic environments will require sophisticated detection technologies to assess the locations of recoverable volumes of methane contained in hydrates. High-resolution surface seismic data and more rigorous well log data analysis offer the best near-term potential. The hydrate resource potential is huge, but better tools are needed to accurately assess their location, distribution and economic recoverability.

Donn McGuire; Thomas Williams; Bjorn Paulsson; Alexander Goertz

2005-02-01T23:59:59.000Z

189

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Mallik 5L-39 location Drillsite at Mallik 5L-38 location courtesy Geological Survey of Canada Goal Obtain information that can be utilized to develop gas hydrate computer...

190

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

Science Conference Proceedings (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored a well (the Hot Ice No. 1) on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports. Documenting the results of this effort are key to extracting lessons learned and maximizing the industry's benefits for future hydrate exploitation. In addition to the Final Report, several companion Topical Reports are being published.

Thomas E. Williams; Keith Millheim; Bill Liddell

2004-11-01T23:59:59.000Z

191

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

Science Conference Proceedings (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists planning hydrate exploration and development projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this and other project reports. This Topical Report contains details describing logging operations.

Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

2005-02-01T23:59:59.000Z

192

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored a well (the Hot Ice No. 1) on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports. Documenting the results of this effort are key to extracting lessons learned and maximizing the industry's benefits for future hydrate exploitation.

Thomas E. Williams; Keith Millheim; Bill Liddell

2005-02-01T23:59:59.000Z

193

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

Science Conference Proceedings (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and implemented for determining physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. Final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models and to research teams for developing future gas-hydrate projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and has been documented by the project team. This Topical Report documents drilling and coring operations and other daily activities.

Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

2005-02-01T23:59:59.000Z

194

NETL: Methane Hydrates - DOE/NETL Projects - A New Approach to...  

NLE Websites -- All DOE Office Websites (Extended Search)

of gas hydrate in over 1700 industry wells, this research will directly identify methane hydrate resources, and may identify new potentially commercial hydrate-bearing sand...

195

Controls on Gas Hydrate Formation and Dissociation  

SciTech Connect

The main objectives of the project were to monitor, characterize, and quantify in situ the rates of formation and dissociation of methane hydrates at and near the seafloor in the northern Gulf of Mexico, with a focus on the Bush Hill seafloor hydrate mound; to record the linkages between physical and chemical parameters of the deposits over the course of one year, by emphasizing the response of the hydrate mound to temperature and chemical perturbations; and to document the seafloor and water column environmental impacts of hydrate formation and dissociation. For these, monitoring the dynamics of gas hydrate formation and dissociation was required. The objectives were achieved by an integrated field and laboratory scientific study, particularly by monitoring in situ formation and dissociation of the outcropping gas hydrate mound and of the associated gas-rich sediments. In addition to monitoring with the MOSQUITOs, fluid flow rates and temperature, continuously sampling in situ pore fluids for the chemistry, and imaging the hydrate mound, pore fluids from cores, peepers and gas hydrate samples from the mound were as well sampled and analyzed for chemical and isotopic compositions. In order to determine the impact of gas hydrate dissociation and/or methane venting across the seafloor on the ocean and atmosphere, the overlying seawater was sampled and thoroughly analyzed chemically and for methane C isotope ratios. At Bush hill the pore fluid chemistry varies significantly over short distances as well as within some of the specific sites monitored for 440 days, and gas venting is primarily focused. The pore fluid chemistry in the tub-warm and mussel shell fields clearly documented active gas hydrate and authigenic carbonate formation during the monitoring period. The advecting fluid is depleted in sulfate, Ca Mg, and Sr and is rich in methane; at the main vent sites the fluid is methane supersaturated, thus bubble plumes form. The subsurface hydrology exhibits both up-flow and down-flow of fluid at rates that range between 0.5 to 214 cm/yr and 2-162 cm/yr, respectively. The fluid flow system at the mound and background sites are coupled having opposite polarities that oscillate episodically between 14 days to {approx}4 months. Stability calculations suggest that despite bottom water temperature fluctuations, of up to {approx}3 C, the Bush Hill gas hydrate mound is presently stable, as also corroborated by the time-lapse video camera images that did not detect change in the gas hydrate mound. As long as methane (and other hydrocarbon) continues advecting at the observed rates the mound would remain stable. The {_}{sup 13}C-DIC data suggest that crude oil instead of methane serves as the primary electron-donor and metabolic substrate for anaerobic sulfate reduction. The oil-dominated environment at Bush Hill shields some of the methane bubbles from being oxidized both anaerobically in the sediment and aerobically in the water column. Consequently, the methane flux across the seafloor is higher at Bush hill than at non-oil rich seafloor gas hydrate regions, such as at Hydrate Ridge, Cascadia. The methane flux across the ocean/atmosphere interface is as well higher. Modeling the methane flux across this interface at three bubble plumes provides values that range from 180-2000 {_}mol/m{sup 2} day; extrapolating it over the Gulf of Mexico basin utilizing satellite data is in progress.

Miriam Kastner; Ian MacDonald

2006-03-03T23:59:59.000Z

196

NETL: Methane Hydrates - DOE/NETL Projects - Natural Gas Hydrates in  

NLE Websites -- All DOE Office Websites (Extended Search)

Natural Gas Hydrates in Permafrost and Marine Settings: Resources, Properties, and Environmental Issues Last Reviewed 12/30/2013 Natural Gas Hydrates in Permafrost and Marine Settings: Resources, Properties, and Environmental Issues Last Reviewed 12/30/2013 DE-FE0002911 Goal The objective of this DOE-USGS Interagency Agreement is to provide world-class expertise and research in support of the goals of the 2005 Energy Act for National Methane Hydrates R&D, the DOE-led U.S. interagency roadmap for gas hydrates research, and elements of the USGS mission related to energy resources, global climate, and geohazards. This project extends USGS support to the DOE Methane Hydrate R&D Program previously conducted under DE-AI26-05NT42496. Performer U.S. Geological Survey at Woods Hole, MA, Denver, CO, and Menlo Park, CA Background The USGS Interagency Agreement (IA) involves laboratory research and

197

Microsoft Word - Oct2011_Semi-Annual Report_Hydrates_GRID-Arendal.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

October October 15 2011 2 ADMINISTRATIVE SUMMARY The UNEP Global Outlook on Methane Gas Hydrates project has received funding from the US Department of Energy under award number DE-FE0003060. The project director is Yannick Beaudoin and the recipient institution is Stiftelsen GRID-Arendal in Arendal, Norway. The current report is for the period starting April 1, 2010 and ending September 30, 2011. EXECUTIVE SUMMARY The UNEP Global Outlook on Methane Gas Hydrates seeks to provide policy makers, the gen- eral public and the media with a synthesis of aspects of natural, social and applied sciences that relate to this type of natural gas occurrence. With an emphasis on visual media, the Outlook is working to define global methane gas hydrate occurrences in their natural settings and examine

198

Complex admixtures of clathrate hydrates in a water desalination method  

DOE Patents (OSTI)

Disclosed is a method that achieves water desalination by utilizing and optimizing clathrate hydrate phenomena. Clathrate hydrates are crystalline compounds of gas and water that desalinate water by excluding salt molecules during crystallization. Contacting a hydrate forming gaseous species with water will spontaneously form hydrates at specific temperatures and pressures through the extraction of water molecules from the bulk phase followed by crystallite nucleation. Subsequent dissociation of pure hydrates yields fresh water and, if operated correctly, allows the hydrate-forming gas to be efficiently recycled into the process stream.

Simmons, Blake A. (San Francisco, CA); Bradshaw, Robert W. (Livermore, CA); Dedrick, Daniel E. (Berkeley, CA); Anderson, David W. (Riverbank, CA)

2009-07-14T23:59:59.000Z

199

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. The work scope drilled and cored a well The Hot Ice No. 1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report. The Hot Ice No. 1 well was drilled from the surface to a measured depth of 2300 ft. There was almost 100% core recovery from the bottom of surface casing at 107 ft to total depth. Based on the best estimate of the bottom of the methane hydrate stability zone (which used new data obtained from Hot Ice No. 1 and new analysis of data from adjacent wells), core was recovered over its complete range. Approximately 580 ft of porous, mostly frozen, sandstone and 155 of conglomerate were recovered in the Ugnu Formation and approximately 215 ft of porous sandstone were recovered in the West Sak Formation. There were gas shows in the bottom part of the Ugnu and throughout the West Sak. No hydrate-bearing zones were identified either in recovered core or on well logs. The base of the permafrost was found at about 1260 ft. With the exception of the deepest sands in the West Sak and some anomalous thin, tight zones, all sands recovered (after thawing) are unconsolidated with high porosity and high permeability. At 800 psi, Ugnu sands have an average porosity of 39.3% and geometrical mean permeability of 3.7 Darcys. Average grain density is 2.64 g/cc. West Sak sands have an average porosity of 35.5%, geometrical mean permeability of 0.3 Darcys, and average grain density of 2.70 g/cc. There were several 1-2 ft intervals of carbonate-cemented sandstone recovered from the West Sak. These intervals have porosities of only a few percent and very low permeability. On a well log they appear as resistive with a high sonic velocity. In shallow sections of other wells these usually are the only logs available. Given the presence of gas in Hot Ice No. 1, if only resistivity and sonic logs and a mud log had been available, tight sand zones may have been interpreted as containing hydrates. Although this finding does not imply that all previously mapped hydrate zones are merely tight sands, it does add a note of caution to the practice of interpreting the presence of hydrates from old well information. The methane hydrate stability zone below the Hot Ice No. 1 location includes thick sections of sandstone and conglomerate which would make excellent reservoir rocks for hydrates and below the permafrost zone shallow gas. The Ugnu formation comprises a more sand-rich section than does the West Sak formation, and the Ugnu sands when cleaned and dried are slightly more porous and significantly more permeable than the West Sak.

Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

2005-02-01T23:59:59.000Z

200

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Numerical Simulation Last Reviewed 3/8/2013 Numerical Simulation Last Reviewed 3/8/2013 Project Goal The goal of NETL's gas hydrate numerical simulation studies is to obtain pertinent, high-quality information on the behavior of gas hydrates in their natural environment under either production (methane gas extraction) or climate change scenarios. This research is closely linked with NETL's experimental and field studies programs to ensure the validity of input datasets and scenarios. Project Performers Brian Anderson, NETL/RUA Fellow (West Virginia University) Hema Siriwardane, NETL/RUA Fellow (West Virginia University) Eugene Myshakin, NETL/URS Project Locations National Energy Technology Laboratory, Pittsburgh PA, and Morgantown WV West Virginia University, Morgantown, WV Background Field-scale hydrate production tests rely heavily on reservoir-scale

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201

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gulf of Mexico Gas Hydrates Sea-floor Observatory Project Last Reviewed 12/18/2013 Gulf of Mexico Gas Hydrates Sea-floor Observatory Project Last Reviewed 12/18/2013 DE-FE26-06NT42877, DE-FC26-02NT41628, and DE-FC26-00NT40920 Goal The goal of this project is to conduct activities leading to the development, implementation, and operation of a remote, multi-sensor seafloor observatory focused on behavior of the marine hydrocarbon system within the gas hydrate stability zone of the deepwater Gulf of Mexico and analysis of data resultant from that observatory over time. Attaining this goal will lead to an enhanced understanding of the role the hydrocarbon system plays in the environment surrounding the site. Investigations include physical, chemical, and microbiological studies. Models developed from these studies are designed to provide a better understanding of gas

202

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields DE-FC26-06NT42962 Goal The goal of this project is to characterize and quantify the postulated gas hydrate resource associated with the Barrow Gas Fields – three producing fields located in a permafrost region near Barrow, the North Slope's biggest population center and economic hub. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Performers North Slope Borough, Barrow, Alaska (North Slope Borough) 99723

203

MethaneHydrateRD_FC.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

gas is an important energy gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy (FE) has played a major role in developing technologies to help tap new, unconventional sources of natural gas. FOSSIL ENERGY RESEARCH BENEFITS Methane Hydrate R&D "The (DOE) Program has supported and managed a high-quality research portf olio that has enabled signifi cant progress toward the (DOE) Program's long-term goals." The Nati onal Academies 2010 One of these is methane hydrate - molecules of natural gas trapped in ice crystals. Containing vast amounts of natural gas, methane hydrate occurs in a variety of forms in sediments within and below thick permafrost in Arctic regions, and in the

204

Fuel cell membrane hydration and fluid metering  

DOE Patents (OSTI)

A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel in order to mix its respective portion of liquid water with the corresponding portion of the stream. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

Jones, Daniel O. (Glenville, NY); Walsh, Michael M. (Fairfield, CT)

1999-01-01T23:59:59.000Z

205

Fuel cell membrane hydration and fluid metering  

DOE Patents (OSTI)

A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

Jones, Daniel O. (Glenville, NY); Walsh, Michael M. (Fairfield, CT)

2003-01-01T23:59:59.000Z

206

Method for production of hydrocarbons from hydrates  

DOE Patents (OSTI)

A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl.sub.2 or CaBr.sub.2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl.sub.2 /CaBr.sub.2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl.sub.2 /CaBr.sub.2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

McGuire, Patrick L. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

207

International Cooperation in Methane Hydrates | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oil & Gas » Methane Hydrate » Oil & Gas » Methane Hydrate » International Cooperation in Methane Hydrates International Cooperation in Methane Hydrates In 1982 the multi-national Deep Sea Drilling Program (DSDP) recovered the first subsea substantial methane hydrate deposits, which spurred methane hydrate research in the US and other countries. The successor programs, the Ocean Drilling Program (ODP) and the Integrated Ocean Drilling Program (IODP) sampled hydrate deposits off Oregon (ODP 204, 2002) and in the Cascadia Margin off Vancouver Island, Canada (ODP 146, 1992 and IODP 311, 2005). In the Atlantic Ocean off the US, ODP Leg 146 sampled hydrate deposits on the Blake Ridge and Carolina Rise in 1995. International cooperation helps scientists in the US and other countries

208

NETL: Methane Hydrates - DOE/NETL Projects - NT42496  

NLE Websites -- All DOE Office Websites (Extended Search)

Studies of Natural Gas Hydrates to Support the DOE Efforts to Evaluate and Understand Methane Hydrates Last Reviewed 05162011 DE-AI26-05NT42496 Goal The United States Geological...

209

Rock-physics Models for Gas-hydrate Systems Associated  

E-Print Network (OSTI)

at Austin, Austin, Texas, U.S.A. ABSTRACT R ock-physics models are presented describing gas-hydrate systems. Knapp, and R. Boswell, eds., Natural gas hydrates--Energy resource potential and associated geologic

Texas at Austin, University of

210

Status of DOE Research Efforts in Gas Hydrates | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Status of DOE Research Efforts in Gas Hydrates Status of DOE Research Efforts in Gas Hydrates July 30, 2009 - 1:38pm Addthis Statement of Dr. Ray Boswell, National Energy...

211

Dehydration of plutonium or neptunium trichloride hydrate  

DOE Patents (OSTI)

A process is described for preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride.

Foropoulos, J. Jr.; Avens, L.R.; Trujillo, E.A.

1992-03-24T23:59:59.000Z

212

Strategies for gas production from oceanic Class 3 hydrate accumulations  

E-Print Network (OSTI)

gas phase, liquid phase, ice phase, and hydrate phase. AHydrate; V: Vapor (gas phase); I: Ice; Q 1 : Quadruple point

Moridis, George J.; Reagan, Matthew T.

2007-01-01T23:59:59.000Z

213

New NIST Database on Gas Hydrates to Aid Energy and ...  

Science Conference Proceedings (OSTI)

New NIST Database on Gas Hydrates to Aid Energy and Climate Research. For Immediate Release: October 6, 2009. ...

2012-10-15T23:59:59.000Z

214

Dynamic behavior of hydration water in calcium-silicate-hydrate gel: A quasielastic neutron scattering spectroscopy investigation  

E-Print Network (OSTI)

The translational dynamics of hydration water confined in calcium-silicate-hydrate (C-S-H) gel was studied by quasielastic neutron scattering spectroscopy in the temperature range from 280 to 230 K. The stretch exponent ...

Li, Hua

215

NETL: Methane Hydrates - DOE/NETL Projects - Estimate Gas-Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Last Reviewed 6/14/2013 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Last Reviewed 6/14/2013 DE-FC26-06NT42959 Goal The goal of this project is to evaluate the direct-current electrical resistivity (DCR) method for remotely detecting and characterizing the concentration of gas hydrates in the deep marine environment. This will be accomplished by adapting existing DCR instrumentation for use on the sea floor in the deep marine environment and testing the new instrumentation at Mississippi Canyon Block 118. Performer Baylor University, Waco, TX 76798 Collaborators Advanced Geosciences Inc., Austin, TX 78726 Specialty Devices Inc., Wylie, TX 75098 Background Marine occurrences of methane hydrates are known to form in two distinct

216

NETL: Methane Hydrates - Gas Hydrate Research in Deep Sea Sediments - New  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrate Research in Deep Sea Sediments - Chatham Rise, New Zealand Task Last Reviewed 12/30/2013 Hydrate Research in Deep Sea Sediments - Chatham Rise, New Zealand Task Last Reviewed 12/30/2013 DE-AI26-06NT42878 Goal The goal of the Interagency Agreement between the National Energy Technology Laboratory and the Naval Research Laboratory is to conduct research to enhance understanding of the extent and dynamics of gas hydrate deposits and their relation to areas of focused fluid flux at and beneath the seafloor. Performer Marine Biogeochemistry Section, Naval Research Laboratory, Washington, DC 20375 Background Methane is a potent greenhouse gas necessitating a better understanding of the mechanisms controlling its contribution to the atmospheric carbon cycle. Active methane fluxes (from deep sediment hydrates and seeps) contribute to shallow sediment biogeochemical carbon cycles, which in turn

217

NETL: Methane Hydrates - DOE/NETL Projects - Estimate Gas-Hydrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

TX 78726 Specialty Devices Inc., Wylie, TX 75098 Background Marine occurrences of methane hydrates are known to form in two distinct ways. By far the most common occurrence is...

218

NETL: Methane Hydrates - DOE/NETL Projects - Properties of Hydrate-Bearing  

NLE Websites -- All DOE Office Websites (Extended Search)

Properties of Hydrate-Bearing Sediments Subjected to Changing Gas Compositions Last Reviewed 12/11/2013 Properties of Hydrate-Bearing Sediments Subjected to Changing Gas Compositions Last Reviewed 12/11/2013 ESD12-011 Goal The objective of this research is to measure physical, chemical, mechanical, and hydrologic property changes in methane hydrate-bearing sediments subjected to injection of carbon dioxide and nitrogen. Performer Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA 94720 Background A number of studies have investigated the impact of injecting carbon dioxide (CO2) and CO2-nitrogen (N2) mixtures into methane hydrate for the purpose of sequestering CO2 and releasing methane (CH4), and review articles have been published summarizing the literature. Most of these studies have investigated the fundamental physical/chemical nature of the exchange of CO2 and/or N2 with CH4 in the clathrate. These studies have

219

Modeling the interactions between poly(n-vinylpyrrolidone) and gas hydrates: factors involved in suppressing and accelerating hydrate growth  

Science Conference Proceedings (OSTI)

Gas hydrates represent both a bane and a potential boon to the oil and gas industry, and considerable research into hydrate formation has been undertaken. We have recently developed a multi-threaded version of a Monte Carlo crystal growth algorithm and ... Keywords: Monte Carlo simulations, PVP, gas hydrates, parallel computing

Brent Wathen; Peter Kwan; Zongchao Jia; Virginia K. Walker

2009-06-01T23:59:59.000Z

220

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas Hydrate Research in Deep Sea Sediments - New Zealand Task Gas Hydrate Research in Deep Sea Sediments - New Zealand Task DE-AI26-06NT42878 Goal The objective of this research is to determine the extent and dynamics of gas hydrate deposits and their relation to areas of focused fluid flux at and beneath the seafloor. Specific objectives include: a). Refine geophysical, geochemical and microbiological technologies for prospecting hydrate distribution and content; b). Contribute to establishing high-priority geographical regions of prospective interest, in terms of methane volume estimates; c). Prediction of environmental effects and geologic risks at the continental margin associated to the natural resource occurrence and resource exploitation; and d). Expand understanding of the biogeochemical parameters and associated microbial community diversity in shallow sediments that influence the porewater sulfate gradient observed through anaerobic oxidation of methane. To accomplish these objectives, the Naval Research Laboratory (NRL) collaborated with New Zealand’s Institute of Geological and Nuclear Sciences (GNS) in a research cruise off the coast of New Zealand. NRL has conducted similar research cruises off the west coast and east coast of the United States, in the Gulf of Mexico and off the coast of Chile.

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Methane Hydrates R&D U S  

NLE Websites -- All DOE Office Websites (Extended Search)

the Power of Working Together Interagency Coordination on Methane Hydrates R&D U . S . D e p a r t m e n t o f E n e r g y * O f f i c e o f F o s s i l E n e r g y N a t i o n a l...

222

Methane Hydrates - The National R&D Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program The National Methane Hydrates R&D Program Welcome to the information portal for the National Methane Hydrate R&D Program. Over the past eight years, research carried out under this program has resulted in significant advances in our understanding of methane hydrates, their role in nature, and their potential as a future energy resource. This success is largely due to an unprecedented level of cooperation between federal agencies, industry, national laboratories, and academic institutions. For a quick introduction to methane hydrate and its potential as a fuel source, please read the 2011 Methane Hydrates Primer. Information on other elements of the program can be found under the remaining Key Links. Read More.

223

Methane Hydrates and Climate Change | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrates and Climate Change Hydrates and Climate Change Methane Hydrates and Climate Change Methane hydrates store huge volumes of methane formed by the bacterial decay of organic matter or leaked from underlying oil and natural gas deposits. The active formation of methane hydrates in the shallow crust prevents methane, a greenhouse gas, from entering the atmosphere. On the other hand, warming of arctic sediments or ocean waters has the potential to cause methane hydrate to dissociate, releasing methane into the deepwater sediments, the ocean or atmosphere. DOE is conducting research to understand the mechanisms and volumes involved in these little-studied processes. DOE environmental and climate change research projects related to Arctic methane hydrate deposits include: Characterization of Methane Degradation and Methane-Degrading

224

Rapid Gas Hydrate Formation Processes: Will They Work?  

SciTech Connect

Researchers at DOEs National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the laboratory. Numerous experiments were conducted with various high-pressure cells equipped with instrumentation to study rapid and continuous hydrate formation. The cells ranged in size from 100 mL for screening studies to proof-of-concept studies with NETLs 15-Liter Hydrate Cell. Results from this work demonstrate that the rapid and continuous formation of methane hydrate is possible at predetermined temperatures and pressures within the stability zone of a Methane Hydrate Stability Curve (see Figure 1).

Brown, T.D.; Taylor, C.E.; Bernardo, M.P.

2010-01-01T23:59:59.000Z

225

Comparative Assessment of Advanced Gay Hydrate Production Methods  

Science Conference Proceedings (OSTI)

Displacing natural gas and petroleum with carbon dioxide is a proven technology for producing conventional geologic hydrocarbon reservoirs, and producing additional yields from abandoned or partially produced petroleum reservoirs. Extending this concept to natural gas hydrate production offers the potential to enhance gas hydrate recovery with concomitant permanent geologic sequestration. Numerical simulation was used to assess a suite of carbon dioxide injection techniques for producing gas hydrates from a variety of geologic deposit types. Secondary hydrate formation was found to inhibit contact of the injected CO{sub 2} regardless of injectate phase state, thus diminishing the exchange rate due to pore clogging and hydrate zone bypass of the injected fluids. Additional work is needed to develop methods of artificially introducing high-permeability pathways in gas hydrate zones if injection of CO{sub 2} in either gas, liquid, or micro-emulsion form is to be more effective in enhancing gas hydrate production rates.

M. D. White; B. P. McGrail; S. K. Wurstner

2009-06-30T23:59:59.000Z

226

RESOURCE CHARACTERIZATION AND QUANTIFICATION OF NATURAL GAS-HYDRATE AND ASSOCIATED FREE-GAS ACCUMULATIONS IN THE PRUDHOE BAY - KUPARUK RIVER AREA ON THE NORTH SLOPE OF ALASKA  

SciTech Connect

Interim results are presented from the project designed to characterize, quantify, and determine the commercial feasibility of Alaska North Slope (ANS) gas-hydrate and associated free-gas resources in the Prudhoe Bay Unit (PBU), Kuparuk River Unit (KRU), and Milne Point Unit (MPU) areas. This collaborative research will provide practical input to reservoir and economic models, determine the technical feasibility of gas hydrate production, and influence future exploration and field extension of this potential ANS resource. The large magnitude of unconventional in-place gas (40-100 TCF) and conventional ANS gas commercialization evaluation creates industry-DOE alignment to assess this potential resource. This region uniquely combines known gas hydrate presence and existing production infrastructure. Many technical, economical, environmental, and safety issues require resolution before enabling gas hydrate commercial production. Gas hydrate energy resource potential has been studied for nearly three decades. However, this knowledge has not been applied to practical ANS gas hydrate resource development. ANS gas hydrate and associated free gas reservoirs are being studied to determine reservoir extent, stratigraphy, structure, continuity, quality, variability, and geophysical and petrophysical property distribution. Phase 1 will characterize reservoirs, lead to recoverable reserve and commercial potential estimates, and define procedures for gas hydrate drilling, data acquisition, completion, and production. Phases 2 and 3 will integrate well, core, log, and long-term production test data from additional wells, if justified by results from prior phases. The project could lead to future ANS gas hydrate pilot development. This project will help solve technical and economic issues to enable government and industry to make informed decisions regarding future commercialization of unconventional gas-hydrate resources.

Robert Hunter; Shirish Patil; Robert Casavant; Tim Collett

2003-06-02T23:59:59.000Z

227

AN INTERNATIONAL EFFORT TO COMPARE GAS HYDRATE RESERVOIR SIMULATORS  

NLE Websites -- All DOE Office Websites (Extended Search)

AN INTERNATIONAL EFFORT TO COMPARE GAS HYDRATE RESERVOIR SIMULATORS Joseph W. Wilder 1 , George J. Moridis 2 , Scott J. Wilson 3 , Masanori Kurihara 4 , Mark D. White 5 , Yoshihiro Masuda 6 , Brian J. Anderson 7, 8 *, Timothy S. Collett 9 , Robert B. Hunter 10 , Hideo Narita 11 , Mehran Pooladi-Darvish 12 , Kelly Rose 7 , Ray Boswell 7 1 Department of Theoretical & Applied Math University of Akron 302 Buchtel Common Akron, OH 44325-4002 USA 2 Lawrence Berkeley National Laboratory, University of California Earth Sciences Division, 1 Cyclotron Rd., MS 90-1116 Berkeley, CA 94720 USA 3 Ryder Scott Company, Petroleum Consultants 621 17th Street, Suite 1550 Denver, Colorado 80293 USA 4 Japan Oil Engineering Company, Ltd. Kachidoki Sun-Square 1-7-3, Kachidoki, Chuo-ku,

228

TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media  

E-Print Network (OSTI)

phase, liquid phase, ice phase and hydrate phase). Hydratephase, liquid phase, ice phase and hydrate phase). Hydratebetween the liquid and ice phases) are accommodated through

Moridis, George

2008-01-01T23:59:59.000Z

229

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

The Alaska North Slope Stratigraphic Test Well The Alaska North Slope Stratigraphic Test Well image showing Donyon Rig Photo courtesy Doyon Drilling Inc Project Background Participants Status Report Maps of Research Area Science Plan Photo Gallery Well log Data From BP-DOE-US "Mount Elbert" Test Is Now Available. Digital well log data acquired at the February 2007 gas hydrates test well at Milne Point, Alaska are now available. Data include Gamma ray, neutron porosity, density porosity, three-dimensional high resolution resistivity, acoustics including compressional- and shear-wave data and nuclear magnetic resonance. A listing of the available data, as well as instructions on obtaining the data, can be found on the NETL Gas Hydrates Website . The drilling of the “Mt. Elbert prospect” within the Milne Point Unit

230

Detection and Production of Methane Hydrate  

NLE Websites -- All DOE Office Websites (Extended Search)

Oil & Natural Gas Technology Oil & Natural Gas Technology DOE Award No.: DE-FC26-06NT42960 Quarterly Progress Report Reporting Period: April-June 2007 Detection and Production of Methane Hydrate Submitted by: Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Prepared for: United States Department of Energy National Energy Technology Laboratory August, 2007 Office of Fossil Energy Detection and Production of Methane Hydrate Quarterly Progress Report Reporting Period: April-June 2007 Prepared by: George Hirasaki Rice University August 2007 CONTRACT NO. DE-FC26-06NT42960 Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; Fax: 713-348-5478; Email: gjh@rice.edu

231

NETL: Methane Hydrates - ANS Research Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Well - Location Maps Well - Location Maps Maps of Prospect The Mt. Elbert prospect is located within the Milne Point Unit on Alaska’s North Slope. The Milne Point field, one of a number of distinct oil fields on the North Slope, extends offshore into the Beaufort Sea and is situated north of the large Kuparuk Field and northwest of the well known Prudhoe Bay Field. Map showing project location Map showing Milne Point Unit on Alaska’s North Slope The work done under the “Alaska North Slope Gas Hydrate Reservoir Characterization” project has resulted in a characterization of two large prospective methane hydrate accumulations (or trends); the Eileen Trend, which underlies but extends well beyond the Milne Point field, and the Tarn Trend to the west of the Kuparuk Field.

232

Is Iodate a Strongly Hydrated Cation?  

SciTech Connect

We show, through a combination of density function theory based molecular dynamics simulations (DFTMD) and experimental x-ray absorption fine structure spectroscopy (XAFS) studies, that the iodate ion (IO3-) is a zwitterion in solution. The local region adjoining the I atom is sufficiently electropositive that three hydrating waters are oriented with their Os atoms directly interacting with the iodine atom at an I-OH2O distance of 2.95 . This is the orientation of water hydrating a cation. Further, approximately 2-3 water molecules hydrate each O of IO3 - through a single H atom in an orientation of the water that is expected for an anion at an IOH2O distance of 3.85 . We predict that this structure persists, although to a much lesser degree, for BrO3 -, and ClO3 -. This type of local microstructure profoundly affects the behavior of the "anion" at interfaces and how it interacts with other ionic species in solution.

Baer, Marcel D.; Pham, Thai V.; Fulton, John L.; Schenter, Gregory K.; Balasubramanian, Mahalingam; Mundy, Christopher J.

2011-10-06T23:59:59.000Z

233

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network (OSTI)

Mallik Gas Hydrate Production Research Program, Northwestof Depressurization for Gas Production from Gas Hydrate5L-38 Gas Hydrate Thermal Production Test Through Numerical

Moridis, George J.

2008-01-01T23:59:59.000Z

234

Gas Production From a Cold, Stratigraphically Bounded Hydrate Deposit at the Mount Elbert Site, North Slope, Alaska  

E-Print Network (OSTI)

Mallik 2002 Gas Hydrate Production Research Well Program,Of Methane Hydrate Production Methods To Reservoirs WithNumerical Studies of Gas Production From Methane Hydrates,

Moridis, G.J.

2010-01-01T23:59:59.000Z

235

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network (OSTI)

www.netl.doe.gov/technologies/oil-gas/publications/Hydrates/Exploration priorities for marine gas hydrates, Fire In Thewww.netl.doe.gov/technologies/oil-gas/publications/Hydrates/

Moridis, George J.

2008-01-01T23:59:59.000Z

236

A Domain Decomposition Approach for Large-Scale Simulations of Flow Processes in Hydrate-Bearing Geologic Media  

E-Print Network (OSTI)

phase, liquid phase, ice phase, and hydrate phase). Hydratepresence of the ice and hydrate solid phases, the criticalof solid phases of lower density (such as ice and hydrate)

Zhang, Keni

2009-01-01T23:59:59.000Z

237

Natural gas hydrates - issues for gas production and geomechanical stability  

E-Print Network (OSTI)

Natural gas hydrates are solid crystalline substances found in the subsurface. Since gas hydrates are stable at low temperatures and moderate pressures, gas hydrates are found either near the surface in arctic regions or in deep water marine environments where the ambient seafloor temperature is less than 10C. This work addresses the important issue of geomechanical stability in hydrate bearing sediments during different perturbations. I analyzed extensive data collected from the literature on the types of sediments where hydrates have been found during various offshore expeditions. To better understand the hydrate bearing sediments in offshore environments, I divided these data into different sections. The data included water depths, pore water salinity, gas compositions, geothermal gradients, and sedimentary properties such as sediment type, sediment mineralogy, and sediment physical properties. I used the database to determine the types of sediments that should be evaluated in laboratory tests at the Lawrence Berkeley National Laboratory. The TOUGH+Hydrate reservoir simulator was used to simulate the gas production behavior from hydrate bearing sediments. To address some important gas production issues from gas hydrates, I first simulated the production performance from the Messsoyakha Gas Field in Siberia. The field has been described as a free gas reservoir overlain by a gas hydrate layer and underlain by an aquifer of unknown strength. From a parametric study conducted to delineate important parameters that affect gas production at the Messoyakha, I found effective gas permeability in the hydrate layer, the location of perforations and the gas hydrate saturation to be important parameters for gas production at the Messoyakha. Second, I simulated the gas production using a hydraulic fracture in hydrate bearing sediments. The simulation results showed that the hydraulic fracture gets plugged by the formation of secondary hydrates during gas production. I used the coupled fluid flow and geomechanical model "TOUGH+Hydrate- FLAC3D" to model geomechanical performance during gas production from hydrates in an offshore hydrate deposit. I modeled geomechanical failures associated with gas production using a horizontal well and a vertical well for two different types of sediments, sand and clay. The simulation results showed that the sediment and failures can be a serious issue during the gas production from weaker sediments such as clays.

Grover, Tarun

2008-08-01T23:59:59.000Z

238

Methane Hydrate Production Technologies to be Tested on Alaska's North  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Methane Hydrate Production Technologies to be Tested on Alaska's Methane Hydrate Production Technologies to be Tested on Alaska's North Slope Methane Hydrate Production Technologies to be Tested on Alaska's North Slope October 24, 2011 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy, the Japan Oil, Gas and Metals National Corporation, and ConocoPhillips will work together to test innovative technologies for producing methane gas from hydrate deposits on the Alaska North Slope. The collaborative testing will take place under the auspices of a Statement of Intent for Cooperation in Methane Hydrates signed in 2008 and extended in 2011 by DOE and Japan's Ministry of Economy, Trade, and Industry. The production tests are the next step in both U.S. and Japanese national efforts to evaluate the response of gas hydrate reservoirs to alternative

239

NETL: Methane Hydrates - DOE/NETL Projects - Measurement and Interpretation  

NLE Websites -- All DOE Office Websites (Extended Search)

Measurement and Interpretation of Seismic Velocities and Attenuation in Hydrate-Bearing Sediments Last Reviewed 12/18/2013 Measurement and Interpretation of Seismic Velocities and Attenuation in Hydrate-Bearing Sediments Last Reviewed 12/18/2013 DE-FE0009963 Goal The primary project objectives are to relate seismic and acoustic velocities and attenuations to hydrate saturation and texture. The information collected will be a unique dataset in that seismic attenuation will be acquired within the seismic frequency band. The raw data, when combined with other measurements (e.g., complex resistivity, micro-focus x-ray computed tomography, etc.), will enable researchers to understand not only the interaction between mineral surfaces and gas hydrates, but also how the hydrate formation method affects the hydrate-sediment system in terms of elastic properties. An over-arching goal of this research is to calibrate geophysical

240

Development of Alaskan gas hydrate resources. Final report  

Science Conference Proceedings (OSTI)

The research undertaken in this project pertains to study of various techniques for production of natural gas from Alaskan gas hydrates such as, depressurization, injection of hot water, steam, brine, methanol and ethylene glycol solutions through experimental investigation of decomposition characteristics of hydrate cores. An experimental study has been conducted to measure the effective gas permeability changes as hydrates form in the sandpack and the results have been used to determine the reduction in the effective gas permeability of the sandpack as a function of hydrate saturation. A user friendly, interactive, menu-driven, numerical difference simulator has been developed to model the dissociation of natural gas hydrates in porous media with variable thermal properties. A numerical, finite element simulator has been developed to model the dissociation of hydrates during hot water injection process.

Kamath, V.A.; Sharma, G.D.; Patil, S.L.

1991-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

CFD Modeling of Methane Production from Hydrate-Bearing Reservoir  

Science Conference Proceedings (OSTI)

Methane hydrate is being examined as a next-generation energy resource to replace oil and natural gas. The U.S. Geological Survey estimates that methane hydrate may contain more organic carbon the the world's coal, oil, and natural gas combined. To assist in developing this unfamiliar resource, the National Energy Technology Laboratory has undertaken intensive research in understanding the fate of methane hydrate in geological reservoirs. This presentation reports preliminary computational fluid dynamics predictions of methane production from a subsurface reservoir.

Gamwo, I.K.; Myshakin, E.M.; Warzinski, R.P.

2007-04-01T23:59:59.000Z

242

Detection and evaluation methods for in-situ gas hydrates  

Science Conference Proceedings (OSTI)

With the increased interest in naturally occuring hydrates, the need for improved detection and evaluation methods has also increased. In this paper, logging of hydrates is discussed and selected logs from four arctic wells are examined. A new procedure based on temperature log analysis is described. The concept of a downhole heater for use with drill stem testing is also described for testing and evaluation of hydrate intervals. 12 refs.

Goodman, M.A.; Guissani, A.P.; Alger, R.P.

1982-01-01T23:59:59.000Z

243

NETL: Methane Hydrates - DOE/NETL Projects - Numerical Studies  

NLE Websites -- All DOE Office Websites (Extended Search)

describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects, and inhibitor-induced effects. Under this project, LBNL...

244

NETL: Methane Hydrates - DOE/NETL Projects - Downhole Oxyfuel...  

NLE Websites -- All DOE Office Websites (Extended Search)

for producing natural gas from hydrate-bearing sediments are depressurization and thermal stimulation. Test well results indicate that depressurization alone may not be sufficient...

245

NETL-ORD Methane Hydrate Project - Micro XCT Characterization...  

NLE Websites -- All DOE Office Websites (Extended Search)

the experimental systempressure vessel development and system parameter optimization, methane hydrate will be formed and dissociated in packed sediments. Micro-XCT scans will be...

246

Method for the photocatalytic conversion of gas hydrates  

DOE Patents (OSTI)

A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0.degree. C., and allows for the direct conversion of methane contained within the hydrate in situ.

Taylor, Charles E. (Pittsburg, PA); Noceti, Richard P. (Pittsburg, PA); Bockrath, Bradley C. (Bethel Park, PA)

2001-01-01T23:59:59.000Z

247

NETL: Methane Hydrates - DOE/NETL Projects - Verification Of...  

NLE Websites -- All DOE Office Websites (Extended Search)

will help to determine bottomhole pressure, predict more accurate production rates of methane and water, and facilitate the selection of hydrate reservoirs for economic...

248

NETL: Methane Hydrates - DOE/NETL Projects - Development of a...  

NLE Websites -- All DOE Office Websites (Extended Search)

activities to assess the geologic occurrence, regional context, and characteristics of methane hydrate deposits along the continental margins of the U.S. with an emphasis on the...

249

Department of Energy Advance Methane Hydrates Science and Technology  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advance Methane Hydrates Science and Technology Projects Dollars awarded will go to research the advance understanding of the nature and occurrence of Deepwater and Arctic gas...

250

NETL-ORD Methane Hydrate Project - Experimental Analysis and...  

NLE Websites -- All DOE Office Websites (Extended Search)

to describe the experimentally-observed stress-strain behavior as a function of methane hydrate saturation All the experimental data and their relationships will be...

251

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

or grain to hydrate interaction. The Hertzian model is being extended to contact mechanics of several grains. The natural coupling between inter-grain interactions makes the...

252

NETL: Methane Hydrates - DOE/NETL Projects - THCM Coupled Model...  

NLE Websites -- All DOE Office Websites (Extended Search)

effort are to develop a truly coupled numerical model that addresses the complex thermo-hydro-chemo-mechanical (THCM) phenomena in hydrate-bearing sediments through incorporation...

253

Characterizing Natural Gas Hydrates in the Deep Water Gulf...  

NLE Websites -- All DOE Office Websites (Extended Search)

Natural Gas Hydrates in the Deep Water Gulf of Mexico: Applications for Safe Exploration and Production Activities Semi-Annual Report" Report Type: Semi-Annual No:...

254

Swapping Global Warming Gases for Methane in Gas Hydrate ...  

Science Conference Proceedings (OSTI)

Swapping Global Warming Gases for Methane in Gas Hydrate Layer ... would serve as energy sources as well as carbon dioxide storage sites in the ...

2006-07-20T23:59:59.000Z

255

Methane Hydrate Research and Modeling | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Research and Modeling Clean Coal Carbon Capture and Storage Oil & Gas Methane Hydrate LNG Offshore Drilling Enhanced Oil Recovery Shale Gas Research is focused on understanding...

256

An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs...  

Open Energy Info (EERE)

Login | Sign Up Search Page Edit with form History Facebook icon Twitter icon An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs In Marine Areas Jump to:...

257

The polarization contribution to the free energy of hydration  

Science Conference Proceedings (OSTI)

The magnitude of the polarization contribution to the free energy of hydration is analyzed using several approaches. Monte Carlo quantum mechanical?molecular mechanical (MC?QM/MM)

Modesto Orozco; F. J. Luque; Darius Habibollahzadeh; Jiali Gao

1995-01-01T23:59:59.000Z

258

Geomechanical Performance of Hydrate-Bearing Sediment in Offshore Environments  

Science Conference Proceedings (OSTI)

The objective of this multi-year, multi-institutional research project was to develop the knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate-bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus was on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. We have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. We also investigated the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. The objective of the UC Berkeley work was to develop a grain-scale model of hydrate-bearing sediments. Hydrate dissociation alters the strength of HBS. In particular, transformation of hydrate clusters into gas and liquid water weakens the skeleton and, simultaneously, reduces the effective stress by increasing the pore pressure. The large-scale objective of the study is evaluation of geomechanical stability of offshore oil and gas production infrastructure. At Lawrence Berkeley National Laboratory (LBNL), we have developed the numerical model TOUGH + Hydrate + FLAC3D to evaluate how the formation and disassociation of hydrates in seafloor sediments affects seafloor stability. Several technical papers were published using results from this model. LBNL also developed laboratory equipment and methods to produce realistic laboratory samples of sediments containing gas hydrates so that mechanical properties could be measured in the laboratory. These properties are required to run TOUGH + Hydrate + FLAC3D to evaluate seafloor stability issues. At Texas A&M University we performed a detailed literature review to determine what gas hydrate formation properties had been measured and reported in the literature. We then used TOUGH + Hydrate to simulate the observed gas production and reservoir pressure field data at Messoyakha. We simulated various scenarios that help to explain the field behavior. We have evaluated the effect of reservoir parameters on gas recovery from hydrates. Our work should be beneficial to others who are investigating how to produce gas from a hydrate capped gas reservoir. The results also can be used to better evaluate the process of producing gas from offshore hydrates. The Schlumberger PETREL model is used in industry to the description of geologic horizons and the special distribution of properties. An interface between FLAC3D and Petrel was built by Schlumberger to allow for efficient data entry into TOUGH + Hydrate + FLAC3D.

Stephen Holditch; Tad Patzek; Jonny Rutqvist; George Moridis; Richard Plumb

2008-03-31T23:59:59.000Z

259

NETL: Methane Hydrates - DOE/NETL Projects - Borehole Tool for...  

NLE Websites -- All DOE Office Websites (Extended Search)

liquid and gas permeabilities and their variation with saturation define flow rates; and heat capacity and conduction limit dissociation. The study of methane hydrate-bearing...

260

Method for controlling clathrate hydrates in fluid systems  

DOE Patents (OSTI)

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member and/or six member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico  

E-Print Network (OSTI)

and quantification of gas hydrates using rock physics andAdvances in the Study of Gas Hydrates. Kluwer, New York, pp.2008. Fracture-controlled gas hydrate systems in the Gulf of

Boswell, R.D.

2010-01-01T23:59:59.000Z

262

The dynamic response of oceanic hydrate deposits to ocean temperature change  

E-Print Network (OSTI)

phase behavior of water, methane, solid hydrate, ice, andgaseous phase (V), solid hydrate (H), and solid ice (I). Thegaseous phase (V), solid hydrate (H), and solid ice (I). The

Reagan, Matthew T.

2008-01-01T23:59:59.000Z

263

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network (OSTI)

Hydrate; V: Vapor (gas phase); I: Ice; Q 1 : Quadruple pointof the solid phases (hydrate and ice) as tantamount to thealong the 3-phase (aqueous + hydrate + gas, or ice + hydrate

Moridis, George J.

2008-01-01T23:59:59.000Z

264

Natural gas hydrates on the North Slope of Alaska  

SciTech Connect

Gas hydrates are crystalline substances composed of water and gas, mainly methane, in which a solid-water lattice accommodates gas molecules in a cage-like structure, or clathrate. These substances often have been regarded as a potential (unconventional) source of natural gas. Significant quantities of naturally occurring gas hydrates have been detected in many regions of the Arctic including Siberia, the Mackenzie River Delta, and the North Slope of Alaska. On the North Slope, the methane-hydrate stability zone is areally extensive beneath most of the coastal plain province and has thicknesses as great as 1000 meters in the Prudhoe Bay area. Gas hydrates have been identified in 50 exploratory and production wells using well-log responses calibrated to the response of an interval in one well where gas hydrates were recovered in a core by ARCO Alaska and EXXON. Most of these gas hydrates occur in six laterally continuous Upper Cretaceous and lower Tertiary sandstone and conglomerate units; all these gas hydrates are geographically restricted to the area overlying the eastern part of the Kuparuk River Oil Field and the western part of the Prudhoe Bay Oil Field. The volume of gas within these gas hydrates is estimated to be about 1.0 {times} 10{sup 12} to 1.2 {times} 10{sup 12} cubic meters (37 to 44 trillion cubic feet), or about twice the volume of conventional gas in the Prudhoe Bay Field. Geochemical analyses of well samples suggest that the identified hydrates probably contain a mixture of deep-source thermogenic gas and shallow microbial gas that was either directly converted to gas hydrate or first concentrated in existing traps and later converted to gas hydrate. The thermogenic gas probably migrated from deeper reservoirs along the same faults thought to be migration pathways for the large volumes of shallow, heavy oil that occur in this area. 51 refs., 11 figs., 3 tabs.

Collett, T.S.

1991-01-01T23:59:59.000Z

265

Sonic and resistivity measurements on Berea sandstone containing tetrahydrofuran hydrates: a possible analogue to natural-gas-hydrate deposits. [Tetrahydrofuran hydrates  

Science Conference Proceedings (OSTI)

Deposits of natural gas hydrates exist in arctic sedimentary basins and in marine sediments on continental slopes and rises. However, the physical properties of such sediments are largely unknown. In this paper, we report laboratory sonic and resistivity measurements on Berea sandstone cores saturated with a stoichiometric mixture of tetrahydrofuran (THF) and water. We used THF as the guest species rather than methane or propane gas because THF can be mixed with water to form a solution containing proportions of the proper stoichiometric THF and water. Because neither methane nor propane is soluble in water, mixing the guest species with water sufficiently to form solid hydrate is difficult. Because THF solutions form hydrates readily at atmospheric pressure it is an excellent experimental analogue to natural gas hydrates. Hydrate formation increased the sonic P-wave velocities from a room temperature value of 2.5 km/s to 4.5 km/s at -5/sup 0/C when the pores were nearly filled with hydrates. Lowering the temperature below -5/sup 0/C did not appreciably change the velocity however. In contrast, the electrical resistivity increases nearly two orders of magnitude upon hydrate formation and continues to increase more slowly as the temperature is further decreased. In all cases the resistivities are nearly frequency independent to 30 kHz and the loss tangents are high, always greater than 5. The dielectric loss shows a linear decrease with frequency suggesting that ionic conduction through a brine phase dominates at all frequencies, even when the pores are nearly filled with hydrates. We find that the resistivities are strongly a function of the dissolved salt content of the pore water. Pore water salinity also influences the sonic velocity, but this effect is much smaller and only important near the hydrate formation temperature.

Pearson, C.; Murphy, J.; Halleck, P.; Hermes, R.; Mathews, M.

1983-01-01T23:59:59.000Z

266

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network (OSTI)

gas hydrate concentrations previously unseen in shale-gas hydrate, generally found encased in fine-grained muds and shales.

Moridis, George J.

2008-01-01T23:59:59.000Z

267

Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates  

E-Print Network (OSTI)

of Methane Title: Carbon Dioxide Mixed Hydrates Tae-Hyukof methane with carbon dioxide in hydrate has been proposedsequestration of carbon dioxide ( CO 2 ) and/or production

Kwon, T.H.

2012-01-01T23:59:59.000Z

268

U.S. and Japan Complete Successful Field Trial of Methane Hydrate...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Japan Complete Successful Field Trial of Methane Hydrate Production Technologies U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies May 2,...

269

Ice method for production of hydrogen clathrate hydrates  

DOE Patents (OSTI)

The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

Lokshin, Konstantin (Santa Fe, NM); Zhao, Yusheng (Los Alamos, NM)

2008-05-13T23:59:59.000Z

270

HYDRATE DISSOCIATION IN A 1-D DOMAIN  

NLE Websites -- All DOE Office Websites (Extended Search)

HYDRATE DISSOCIATION IN A 1-D DOMAIN HYDRATE DISSOCIATION IN A 1-D DOMAIN I. Domain Description 1-D Cartesian system, L x W x H = 1.5 m x 1.0 m x 1.0 m Discretization: 30 x 1 x 1 in (x,y,z) Uniform Δx = 0.05 m each; Δy = Δz = 1 m II. Initial Conditions Pressure: P i = 8 MPa Temperature: T i = 2 o C (for thermal stimulation), T i = 6 o C (for depressurization) Saturations: S H = 0.5, S A = 0.5, S G = 0.0 III. Boundary Conditions At x = X max : No mass or heat flow At x = 0: Constant S A = 1.0 (1) Constant P 0 = P i Constant T 0 = 45 o C Thermal stimulation (2) Constant T 0 = T i = 6 o C Constant P 0 = 2.8 MPa Depressurization to a pressure above the Q-point, no ice formation (3) Constant T 0 = T i = 6 o C Constant P 0 = 0.5 MPa Depressurization to a pressure below the Q-point,

271

Energy Department Advances Research on Methane Hydrates - the World's  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Research on Methane Hydrates - the Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource Energy Department Advances Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource August 31, 2012 - 1:00pm Addthis Washington, DC - The Energy Department today announced the selection of 14 new research projects across 11 states that will be a part of an expanding portfolio of projects designed to increase our understanding of methane hydrates' potential as a future energy supply. Methane hydrates are 3D ice-lattice structures with natural gas locked inside, and are found both onshore and offshore - including under the Arctic permafrost and in ocean sediments along nearly every continental shelf in the world. Today's projects build on the completion of a successful, unprecedented test

272

NETL: Methane Hydrates - Barrow Gas Fields - North Slope Borough, Alaska  

NLE Websites -- All DOE Office Websites (Extended Search)

Phase 2- Drilling and Production Testing the Methane Hydrate Resource Potential associated with the Barrow Gas Fields Last Reviewed 04/06/2010 Phase 2- Drilling and Production Testing the Methane Hydrate Resource Potential associated with the Barrow Gas Fields Last Reviewed 04/06/2010 DE-FC26-06NT42962 Goal The goal of this project is to evaluate, design, drill, log, core and production test methane hydrate resources in the Barrow Gas Fields near Barrow, Alaska to determine its impact on future free gas production and its viability as an energy source. Photo of Barrow welcome sign Performers North Slope Borough, Barrow, Alaska 99723 Petrotechnical Resources Alaska (PRA), Fairbanks, AK 99775 University of Alaska Fairbanks, Fairbanks, AK 99775 Background Phase 1 of the Barrow Gas Fields Hydrate Study provided very strong evidence for the existence of hydrates updip of the East Barrow and Walakpa Gas Fields. Full-field history matched reservoir modeling supported the

273

NETL: Methane Hydrates - DOE/NETL Projects - Temporal Characterization of  

NLE Websites -- All DOE Office Websites (Extended Search)

Temporal Characterization of Hydrates System Dynamics Beneath Seafloor Mounds Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters Last Reviewed 12/18/2013 Temporal Characterization of Hydrates System Dynamics Beneath Seafloor Mounds Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters Last Reviewed 12/18/2013 DE-FE0010141 Goal The overall objective of the project is to investigate hydrate system dynamics beneath seafloor mounds—a structurally focused example of hydrate occurrence at the landward extreme of their stability field—in the northern Gulf of Mexico. Researchers will conduct observatory-based in situ measurements at Woolsey Mound, MC118 to: Characterize (geophysically) the sub-bottom distribution of hydrate and its temporal variability and, Contemporaneously record relevant environmental parameters (temperature, pressure, salinity, turbidity, bottom currents, and seafloor

274

Energy Department Advances Research on Methane Hydrates - the World's  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Energy Department Advances Research on Methane Hydrates - the Energy Department Advances Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource Energy Department Advances Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource August 31, 2012 - 1:20pm Addthis News Media Contact (202) 586-4940 WASHINGTON, D.C. - The Energy Department today announced the selection of 14 new research projects across 11 states that will be a part of an expanding portfolio of projects designed to increase our understanding of methane hydrates' potential as a future energy supply. Methane hydrates are 3D ice-lattice structures with natural gas locked inside, and are found both onshore and offshore - including under the Arctic permafrost and in ocean sediments along nearly every continental shelf in the world.

275

METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

METHANE HYDRATE ADVISORY COMMITTEE METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy Advisory Committee Charter - - - - ---- ---- ------~ 1. Committee's Official Designation. Methane Hydrate Advisory Committee (MHAC) 2. Authority:. This charter establishes the Methane Hydrate Advisory Committee (Committee) pursuant to Title IX, Subtitle F, Section 968, Methane Hydrate Research of the Energy Policy Act of 2005 (EPACT), Public Law 109-58. This charter establishes the MHAC under the authority of the Department of Energy (DOE). The MHAC is being renewed in accordance with the provisions of the Federal Advisory Committee Act (FACA), as amended, 5 U.S.C., App.2. 3. Objectives and Scope of Activities. The Committee provides advice to the Secretary of Energy by developing recommendations and broad programmatic priorities for the methane

276

NETL: Methane Hydrates - DOE/NETL Projects - Structural and Stratigraphic  

NLE Websites -- All DOE Office Websites (Extended Search)

Structural and Stratigraphic Controls on Methane Hydrate Occurrence and Distribution: Gulf of Mexico, Walker Ridge 313 and Green Canyon 955 Last Reviewed 12/24/2013 Structural and Stratigraphic Controls on Methane Hydrate Occurrence and Distribution: Gulf of Mexico, Walker Ridge 313 and Green Canyon 955 Last Reviewed 12/24/2013 DE-FE0009904 Goal The goal of this project is to determine structural and stratigraphic controls on hydrate occurrence and distribution in Green Canyon (GC) 955 and Walker Ridge (WR) 313 blocks with special emphasis on hydrate-bearing sand reservoirs. Structural and stratigraphic controls on hydrate distribution are examined by jointly analyzing surface-towed, multichannel seismic (MCS) and Ocean Bottom Seismometer (OBS) data and well logs through a combination of pre-stack depth migration (PSDM), traveltime and full-waveform inversion (FWI), and rock physics modeling methods. Performers Oklahoma State University, Stillwater, OK 74078-1026

277

DOE Announces $2 Million Funding for Methane Hydrates Projects | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Announces $2 Million Funding for Methane Hydrates Projects DOE Announces $2 Million Funding for Methane Hydrates Projects DOE Announces $2 Million Funding for Methane Hydrates Projects November 7, 2005 - 12:43pm Addthis Seeks to Unlock World's Biggest Potential Source of "Ice That Burns" WASHINGTON, DC - The Department of Energy (DOE) today announced a total of $2 million in funding to five research projects that will assess the energy potential, safety, and environmental aspects of methane hydrate exploration and development. Termed the "ice that burns," methane hydrates are crystalline solids that release a flammable gas when melted. They are considered the Earth's biggest potential source of hydrocarbon energy and could be a key element in meeting natural gas demand in the United States,

278

Seismic-Scale Rock Physics of Methane Hydrate  

SciTech Connect

We quantify natural methane hydrate reservoirs by generating synthetic seismic traces and comparing them to real seismic data: if the synthetic matches the observed data, then the reservoir properties and conditions used in synthetic modeling might be the same as the actual, in-situ reservoir conditions. This approach is model-based: it uses rock physics equations that link the porosity and mineralogy of the host sediment, pressure, and hydrate saturation, and the resulting elastic-wave velocity and density. One result of such seismic forward modeling is a catalogue of seismic reflections of methane hydrate which can serve as a field guide to hydrate identification from real seismic data. We verify this approach using field data from known hydrate deposits.

Amos Nur

2009-01-08T23:59:59.000Z

279

Applied Science  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Science Applied Science Correlation of predicted and measured iron oxidation states in mixed iron oxides H. D. Rosenfeld and W. L. Holstein Development of a quantitative measurement of a diesel spray core using synchrotron x-rays C.F. Powell, Y. Yue, S. Gupta, A. McPherson, R. Poola, and J. Wang Localized phase transformations by x-ray-induced heating R.A. Rosenberg, Q. Ma, W. Farrell, E.D. Crozier, G.J. Soerensen, R.A. Gordon, and D.-T. Jiang Resonant x-ray scattering at the Se edge in ferroelectric liquid crystal materials L. Matkin, H. Gleeson, R. Pindak, P. Mach, C. Huang, G. Srajer, and J. Pollmann Synchrotron-radiation-induced anisotropic wet etching of GaAs Q. Ma, D.C. Mancini, and R.A. Rosenberg Synchrotron-radiation-induced, selective-area deposition of gold on

280

NETL: Methane Hydrates - DOE/NETL Projects - NT42496  

NLE Websites -- All DOE Office Websites (Extended Search)

Conducting Scientific Studies of Natural Gas Hydrates to Support the DOE Efforts to Evaluate and Understand Methane Hydrates Last Reviewed 05/16/2011 Conducting Scientific Studies of Natural Gas Hydrates to Support the DOE Efforts to Evaluate and Understand Methane Hydrates Last Reviewed 05/16/2011 DE-AI26-05NT42496 Goal The United States Geological Survey (USGS) conducts scientific studies of natural gas hydrates in support of DOE efforts to evaluate and understand methane hydrates, their potential as an energy resource, and the hazard they may pose to ongoing drilling efforts. This project extends USGS support to the DOE Methane Hydrate Research Program previously supported under DE-AT26-97FT34342 and DE-AT26-97FT34343. Performer U.S. Geological Survey at Denver, CO, Woods Hole, MA, and Menlo Park, CA. Background The USGS Interagency Agreement (IA) involves laboratory research and international field studies in which DOE/NETL has a significant interest.

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

NETL: Methane Hydrates - DOE/NETL Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

High-Resolution Sidescan Sonar and Multibeam Bathymetric Data Collection and Processing, Atwater Canyon, Gulf of Mexico High-Resolution Sidescan Sonar and Multibeam Bathymetric Data Collection and Processing, Atwater Canyon, Gulf of Mexico DE-AT26-97FT34344 photo of DTAGS seismic source being deployed DTAG seismic source being deployed courtesy Naval Research Laboratory Goal: During February 14-18, 2005, a scientific cruise was conducted using the R/V Pelican to obtain high-resolution sidescan sonar and multibeam bathymetric data of Mounds D and F in the Atwater Valley area of the Gulf of Mexico, to better characterize sites selected for experimental drilling by the ChevronTexaco Gas Hydrates Joint Industry Project (JIP). Performers: Naval Research Lab - Dr. Joan Gardner Location: Washington, DC 20375 Atwater Valley, Gulf of Mexico Background: During May, 2004 the Naval Research Lab (NRL) collected piston cores and

282

Examination of Hydrate Formation Methods: Trying to Create Representative Samples  

Science Conference Proceedings (OSTI)

Forming representative gas hydrate-bearing laboratory samples is important so that the properties of these materials may be measured, while controlling the composition and other variables. Natural samples are rare, and have often experienced pressure and temperature changes that may affect the property to be measured [Waite et al., 2008]. Forming methane hydrate samples in the laboratory has been done a number of ways, each having advantages and disadvantages. The ice-to-hydrate method [Stern et al., 1996], contacts melting ice with methane at the appropriate pressure to form hydrate. The hydrate can then be crushed and mixed with mineral grains under controlled conditions, and then compacted to create laboratory samples of methane hydrate in a mineral medium. The hydrate in these samples will be part of the load-bearing frame of the medium. In the excess gas method [Handa and Stupin, 1992], water is distributed throughout a mineral medium (e.g. packed moist sand, drained sand, moistened silica gel, other porous media) and the mixture is brought to hydrate-stable conditions (chilled and pressurized with gas), allowing hydrate to form. This method typically produces grain-cementing hydrate from pendular water in sand [Waite et al., 2004]. In the dissolved gas method [Tohidi et al., 2002], water with sufficient dissolved guest molecules is brought to hydrate-stable conditions where hydrate forms. In the laboratory, this is can be done by pre-dissolving the gas of interest in water and then introducing it to the sample under the appropriate conditions. With this method, it is easier to form hydrate from more soluble gases such as carbon dioxide. It is thought that this method more closely simulates the way most natural gas hydrate has formed. Laboratory implementation, however, is difficult, and sample formation is prohibitively time consuming [Minagawa et al., 2005; Spangenberg and Kulenkampff, 2005]. In another version of this technique, a specified quantity of gas is placed in a sample, then the sample is flooded with water and cooled [Priest et al., 2009]. We have performed a number of tests in which hydrate was formed and the uniformity of the hydrate formation was examined. These tests have primarily used a variety of modifications of the excess gas method to make the hydrate, although we have also used a version of the excess water technique. Early on, we found difficulties in creating uniform samples with a particular sand/ initial water saturation combination (F-110 Sand, {approx} 35% initial water saturation). In many of our tests we selected this combination intentionally to determine whether we could use a method to make the samples uniform. The following methods were examined: Excess gas, Freeze/thaw/form, Freeze/pressurize/thaw, Excess gas followed by water saturation, Excess water, Sand and kaolinite, Use of a nucleation enhancer (SnoMax), and Use of salt in the water. Below, each method, the underlying hypothesis, and our results are briefly presented, followed by a brief conclusion. Many of the hypotheses investigated are not our own, but were presented to us. Much of the data presented is from x-ray CT scanning our samples. The x-ray CT scanner provides a three-dimensional density map of our samples. From this map and the physics that is occurring in our samples, we are able to gain an understanding of the spatial nature of the processes that occur, and attribute them to the locations where they occur.

Kneafsey, T.J.; Rees, E.V.L.; Nakagawa, S.; Kwon, T.-H.

2011-04-01T23:59:59.000Z

283

Hydration structures of U(III) and U(IV) ions from ab initio molecular dynamics simulations  

Science Conference Proceedings (OSTI)

We apply DFT+U-based ab initio molecular dynamics simulations to study the hydration structures of U(III) and U(IV) ions, pertinent to redox reactions associated with uranium salts in aqueous media. U(III) is predicted to be coordinated to 8 water molecules, while U(IV) has a hydration number between 7 and 8. At least one of the innershell water molecules of the hydrated U(IV) complex becomes spontaneously deprotonated. As a result, the U(IV)-O pair correlation function exhibits a satellite peak at 2.15 A associated with the shorter U(IV)-(OH{sup -}) bond. This feature is not accounted for in analysis of extended x-ray absorption fine structure and x-ray adsorption near edge structure measurements, which yield higher estimates of U(IV) hydration numbers. This suggests that it may be useful to include the effect of possible hydrolysis in future interpretation of experiments, especially when the experimental pH is close to the reported hydrolysis equilibrium constant value.

Leung, Kevin; Nenoff, Tina M. [Sandia National Laboratories, MS 1415, Albuquerque, New Mexico 87185 (United States)

2012-08-21T23:59:59.000Z

284

Newly Installed Alaska North Slope Well Will Test Innovative Hydrate  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Newly Installed Alaska North Slope Well Will Test Innovative Newly Installed Alaska North Slope Well Will Test Innovative Hydrate Production Technologies Newly Installed Alaska North Slope Well Will Test Innovative Hydrate Production Technologies May 17, 2011 - 1:00pm Addthis Washington, DC - A fully instrumented well that will test innovative technologies for producing methane gas from hydrate deposits has been safely installed on the North Slope of Alaska. As a result, the "Iġnik Sikumi" (Iñupiaq for "fire in the ice") gas hydrate field trial well will be available for field experiments as early as winter 2011-12. The well, the result of a partnership between ConocoPhillips and the Office of Fossil Energy's (FE) National Energy Technology Laboratory, will test a technology that involves injecting carbon dioxide (CO2) into sandstone

285

Energy Department Expands Research into Methane Hydrates, a Vast, Untapped  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Expands Research into Methane Hydrates, a Vast, Expands Research into Methane Hydrates, a Vast, Untapped Potential Energy Resource of the U.S. Energy Department Expands Research into Methane Hydrates, a Vast, Untapped Potential Energy Resource of the U.S. November 20, 2013 - 12:08pm Addthis NEWS MEDIA CONTACT (202) 586-4940 WASHINGTON - Today, U.S. Energy Secretary Ernest Moniz announced nearly $5 million in funding across seven research projects nationwide designed to increase our understanding of methane hydrates - a large, completely untapped natural gas resource-and what it could mean for the environment, as well as American economic competiveness and energy security. "The recent boom in natural gas production - in part due to long-term Energy Department investments beginning in the 70's and 80's - has had

286

NETL: Methane Hydrates - DOE/NETL Projects - Verification Of Capillary  

NLE Websites -- All DOE Office Websites (Extended Search)

Verification Of Capillary Pressure Functions And Relative Permeability Equations For Modeling Gas Production From Gas Hydrates Last Reviewed 12/12/2013 Verification Of Capillary Pressure Functions And Relative Permeability Equations For Modeling Gas Production From Gas Hydrates Last Reviewed 12/12/2013 DE-FE0009927 Goal The goal of this project is to verify and validate the capillary pressure functions and relative permeability equations that are frequently used in hydrate numerical simulators. In order to achieve this goal, numerical simulation using a network model will be used to suggest fitting parameters, modify existing equations or, if necessary, develop new equations for better simulation results. Performers Wayne State University, Detroit, MI 48202-3622 Background Numerical simulation is used to estimate and predict long-term behavior of hydrate-bearing sediments during gas production [Kurihara et al., 2008;

287

NETL: Methane Hydrates - DOE/NETL Projects - Structural and Stratigrap...  

NLE Websites -- All DOE Office Websites (Extended Search)

Stratigraphic Controls on Methane Hydrate Occurrence and Distribution: Gulf of Mexico, Walker Ridge 313 and Green Canyon 955 Last Reviewed 6242013 DE-FE0009904 Goal The goal of...

288

NETL: Methane Hydrates - DOE/NETL Projects - Controls On Methane...  

NLE Websites -- All DOE Office Websites (Extended Search)

On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 6242013 DE-FE0010406 Goal The project goal is to predict, given characteristic climate-induced...

289

NETL: Methane Hydrates - Barrow Gas Fields - North Slope Borough...  

NLE Websites -- All DOE Office Websites (Extended Search)

- Drilling and Production Testing the Methane Hydrate Resource Potential associated with the Barrow Gas Fields Last Reviewed 04062010 DE-FC26-06NT42962 Goal The goal of this...

290

Energy Department Expands Research into Methane Hydrates, a Vast...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

to safely and sustainably unlock the natural gas held within." Methane hydrates are ice-like structures with natural gas locked inside, which can be found both onshore and...

291

Method for controlling clathrate hydrates in fluid systems  

DOE Patents (OSTI)

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, E.D. Jr.

1995-07-11T23:59:59.000Z

292

Method for controlling clathrate hydrates in fluid systems  

DOE Patents (OSTI)

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

293

Heat or cold storage composition containing a hydrated hydraulic cement  

SciTech Connect

A polyphase composition for the storage of heat or cold is disclosed that utlizes the latent heat of fusion of a salt hydrate continuous phase intimately intermixed with a hydrated hydraulic cement continuous phase and wherein said continuous phases are optionally in contact with a discontinuous crystalline phase comprising a nucleating component and wherein the composition is enveloped, contained, or packaged within a vapor impermeable material.

Boardman, B.J.

1981-07-07T23:59:59.000Z

294

CX-008917: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Application of Crunch-Flow to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites CX(s) Applied: A9 Date: 08/29/2012 Location(s): Oregon Offices(s): National Energy Technology Laboratory

295

CX-009286: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Structural and Stratigraphic Controls on Methane Hydrate Occurrence and Distribution CX(s) Applied: A9 Date: 09/07/2012 Location(s): Oklahoma Offices(s): National Energy Technology Laboratory

296

CX-009313: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Advanced Methane Hydrate Reservoir Modeling Using Rock Physics Techniques CX(s) Applied: A1, A9 Date: 08/30/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory

297

CX-009330: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Gas Hydrate Dynamics on the Alaskan Beaufort Continental Slope: Modeling and Field Characterization CX(s) Applied: A9, B3.16 Date: 09/27/2012 Location(s): Alaska Offices(s): National Energy Technology Laboratory

298

CX-009329: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Gas Hydrate Dynamics on the Alaskan Beaufort Continental Slope: Modeling and Field Characterization CX(s) Applied: A9, B3.16 Date: 09/27/2012 Location(s): Alaska Offices(s): National Energy Technology Laboratory

299

CX-009327: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Gas Hydrate Dynamics on the Alaskan Beaufort Continental Slope: Modeling and Field Characterization CX(s) Applied: A9 Date: 09/27/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory

300

CX-010962: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico CX(s) Applied: A9, B3.11 Date: 09162013 Location(s): Oklahoma Offices(s):...

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

CX-010961: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico CX(s) Applied: A9, A11 Date: 09162013 Location(s): Oklahoma Offices(s):...

302

Simteche Hydrate CO2 Capture Process  

SciTech Connect

As a result of an August 4, 2005 project review meeting held at Los Alamos National Laboratory (LANL) to assess the project's technical progress, Nexant/Simteche/LANL project team was asked to meet four targets related to the existing project efforts. The four targets were to be accomplished by the September 30, 2006. These four targets were: (1) The CO{sub 2} hydrate process needs to show, through engineering and sensitivity analysis, that it can achieve 90% CO{sub 2} capture from the treated syngas stream, operating at 1000 psia. The cost should indicate the potential of achieving the Sequestration Program's cost target of less than 10% increase in the cost of electricity (COE) of the non-CO{sub 2} removal IGCC plant or demonstrate a significant cost reduction from the Selexol process cost developed in the Phase II engineering analysis. (2) The ability to meet the 20% cost share requirement for research level efforts. (3) LANL identifies through equilibrium and bench scale testing a once-through 90% CO{sub 2} capture promoter that supports the potential to achieve the Sequestration Program's cost target. Nexant is to perform an engineering analysis case to verify any economic benefits, as needed; no ETM validation is required, however, for this promoter for FY06. (4) The CO{sub 2} hydrate once-through process is to be validated at 1000 psia with the ETM at a CO{sub 2} capture rate of 60% without H{sub 2}S. The performance of 68% rate of capture is based on a batch, equilibrium data with H{sub 2}S. Validation of the test results is required through multiple runs and engineering calculations. Operational issues will be solved that will specifically effect the validation of the technology. Nexant was given the primary responsibility for Target No.1, while Simteche was mainly responsible for Target No.2; with LANL having the responsibility of Targets No.3 and No.4.

Nexant and Los Alamos National Laboratory

2006-09-30T23:59:59.000Z

303

Use of Computed X-ray Tomographic Data for Analyzing the Thermodynamics of a Dissociating Porous Sand/Hydrate Mixture  

DOE R&D Accomplishments (OSTI)

X-ray computed tomography (CT) is a method that has been used extensively in laboratory experiments for measuring rock properties and fluid transport behavior. More recently, CT scanning has been applied successfully to detect the presence and study the behavior of naturally occurring hydrates. In this study, we used a modified medical CT scanner to image and analyze the progression of a dissociation front in a synthetic methane hydrate/sand mixture. The sample was initially scanned under conditions at which the hydrate is stable (atmospheric pressure and liquid nitrogen temperature, 77 K). The end of the sample holder was then exposed to the ambient air, and the core was continuously scanned as dissociation occurred in response to the rising temperature. CT imaging captured the advancing dissociation front clearly and accurately. The evolved gas volume was monitored as a function of time. Measured by CT, the advancing hydrate dissociation front was modeled as a thermal conduction problem explicitly incorporating the enthalpy of dissociation, using the Stefan moving-boundary-value approach. The assumptions needed to perform the analysis consisted of temperatures at the model boundaries. The estimated value for thermal conductivity of 2.6 W/m K for the remaining water ice/sand mixture is higher than expected based on conduction alone; this high value may represent a lumped parameter that incorporates the processes of heat conduction, methane gas convection, and any kinetic effects that occur during dissociation. The technique presented here has broad implications for future laboratory and field testing that incorporates geophysical techniques to monitor gas hydrate dissociation.

Freifeld, Barry M.; Kneafsey, Timothy J.; Tomutsa, Liviu; Stern, Laura A.; Kirby, Stephen H.

2002-02-28T23:59:59.000Z

304

Data from Alaska Test Could Help Advance Methane Hydrate R&D | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

from Alaska Test Could Help Advance Methane Hydrate R&D from Alaska Test Could Help Advance Methane Hydrate R&D Data from Alaska Test Could Help Advance Methane Hydrate R&D March 25, 2013 - 1:27pm Addthis Image of how methane hydrates can form in arctic and marine environments. | Illustration by the Energy Department. Image of how methane hydrates can form in arctic and marine environments. | Illustration by the Energy Department. Gayland Barksdale Technical Writer, Office of Fossil Energy DOE & Methane Hydrates The Methane Hydrate Research and Development Act of 2000 established DOE as the lead U.S. agency for methane hydrate R&D. Innovative technology is being developed to inject CO2 into methane hydrate deposits to both release the fuel and permanently store carbon dioxide. DOE's R&D program is focused on developing the tools and

305

In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution  

Science Conference Proceedings (OSTI)

Cooperative Agreement DE-FC26-01NT41329 between Joint Oceanographic Institutions and DOE-NETL was divided into two phases based on successive proposals and negotiated statements of work pertaining to activities to sample and characterize methane hydrates on ODP Leg 204 (Phase 1) and on IODP Expedition 311 (Phase 2). The Phase 1 Final Report was submitted to DOE-NETL in April 2004. This report is the Phase 2 Final Report to DOE-NETL. The primary objectives of Phase 2 were to sample and characterize methane hydrates using the systems and capabilities of the D/V JOIDES Resolution during IODP Expedition 311, to enable scientists the opportunity to establish the mass and distribution of naturally occurring gas and gas hydrate at all relevant spatial and temporal scales, and to contribute to the DOE methane hydrate research and development effort. The goal of the work was to provide expanded measurement capabilities on the JOIDES Resolution for a dedicated hydrate cruise to the Cascadia continental margin off Vancouver Island, British Columbia, Canada (IODP Expedition 311) so that hydrate deposits in this region would be well characterized and technology development continued for hydrate research. IODP Expedition 311 shipboard activities on the JOIDES Resolution began on August 28 and were concluded on October 28, 2005. The statement of work for this project included three primary tasks: (1) research management oversight, provided by JOI; (2) mobilization, deployment and demobilization of pressure coring and core logging systems, through a subcontract with Geotek Ltd.; and, (3) mobilization, deployment and demobilization of a refrigerated container van that will be used for degassing of the Pressure Core Sampler and density logging of these pressure cores, through a subcontract with the Texas A&M Research Foundation (TAMRF). Additional small tasks that arose during the course of the research were included under these three primary tasks in consultation with the DOE-NETL Program Manager. All tasks outlined in the original statement of work were accomplished except for the deployment and use of the X-ray CT system under Subtask 2-2. This reduction in scope provided resources that were applied to other activities to support the overall project. Post-expedition analysis of results and report writing will continue beyond this reporting period, however, all field deployments associated with this project have been successfully concluded as of this writing.

Frank R. Rack

2006-09-20T23:59:59.000Z

306

Methane Hydrate Field Program: Development of a Scientific Plan for a Methane Hydrate-Focused Marine Drilling, Logging and Coring Program  

SciTech Connect

This topical report represents a pathway toward better understanding of the impact of marine methane hydrates on safety and seafloor stability and future collection of data that can be used by scientists, engineers, managers and planners to study climate change and to assess the feasibility of marine methane hydrate as a potential future energy resource. Our understanding of the occurrence, distribution and characteristics of marine methane hydrates is incomplete; therefore, research must continue to expand if methane hydrates are to be used as a future energy source. Exploring basins with methane hydrates has been occurring for over 30 years, but these e?orts have been episodic in nature. To further our understanding, these e?orts must be more regular and employ new techniques to capture more data. This plan identifies incomplete areas of methane hydrate research and o?ers solutions by systematically reviewing known methane hydrate Science Challenges and linking them with Technical Challenges and potential field program locations.

Collett, Tim; Bahk, Jang-Jun; Frye, Matt; Goldberg, Dave; Husebo, Jarle; Koh, Carolyn; Malone, Mitch; Shipp, Craig; Torres, Marta; Myers, Greg; Divins, David; Morell, Margo

2013-11-30T23:59:59.000Z

307

Geological evolution and analysis of confirmed or suspected gas hydrate localities. Volume 5. Gas hydrates in the Russian literature. [271 references  

Science Conference Proceedings (OSTI)

This document is Volume V of a series of reports entitled ''Geological Evolution and Analysis of Confirmed or Suspected Gas Hydrate Localities.'' Volume V is an analysis of ''Gas Hydrates in the Russian Literature.'' This report presents an assessment of gas hydrate research as documented in Russian literature. It presents material that includes regional and local settings, geological history, stratigraphy, and physical properties. It provides some necessary regional and geological background of major hydrate occurrences in Russia. This report provides a better understanding of the gas hydrate phenomena in Russia and gives a detailed account of gas production history from a gas hydrate field in Siberia. It provides an important assessment of the understanding of gas hydrate deposition and production. 271 refs., 51 figs., 19 tabs.

Krason, J.; Ciesnik, M.

1985-10-01T23:59:59.000Z

308

Gas Hydrate Research Database and Web Dissemination Channel  

Science Conference Proceedings (OSTI)

To facilitate advances in application of technologies pertaining to gas hydrates, a United States database containing experimentally-derived information about those materials was developed. The Clathrate Hydrate Physical Property Database (NIST Standard Reference Database {number_sign} 156) was developed by the TRC Group at NIST in Boulder, Colorado paralleling a highly-successful database of thermodynamic properties of molecular pure compounds and their mixtures and in association with an international effort on the part of CODATA to aid in international data sharing. Development and population of this database relied on the development of three components of information-processing infrastructure: (1) guided data capture (GDC) software designed to convert data and metadata into a well-organized, electronic format, (2) a relational data storage facility to accommodate all types of numerical and metadata within the scope of the project, and (3) a gas hydrate markup language (GHML) developed to standardize data communications between 'data producers' and 'data users'. Having developed the appropriate data storage and communication technologies, a web-based interface for both the new Clathrate Hydrate Physical Property Database, as well as Scientific Results from the Mallik 2002 Gas Hydrate Production Research Well Program was developed and deployed at http://gashydrates.nist.gov.

Micheal Frenkel; Kenneth Kroenlein; V Diky; R.D. Chirico; A. Kazakow; C.D. Muzny; M. Frenkel

2009-09-30T23:59:59.000Z

309

Integrating Natural Gas Hydrates in the Global Carbon Cycle  

Science Conference Proceedings (OSTI)

We produced a two-dimensional geological time- and basin-scale model of the sedimentary margin in passive and active settings, for the simulation of the deep sedimentary methane cycle including hydrate formation. Simulation of geochemical data required development of parameterizations for bubble transport in the sediment column, and for the impact of the heterogeneity in the sediment pore fluid flow field, which represent new directions in modeling methane hydrates. The model is somewhat less sensitive to changes in ocean temperature than our previous 1-D model, due to the different methane transport mechanisms in the two codes (pore fluid flow vs. bubble migration). The model is very sensitive to reasonable changes in organic carbon deposition through geologic time, and to details of how the bubbles migrate, in particular how efficiently they are trapped as they rise through undersaturated or oxidizing chemical conditions and the hydrate stability zone. The active margin configuration reproduces the elevated hydrate saturations observed in accretionary wedges such as the Cascadia Margin, but predicts a decrease in the methane inventory per meter of coastline relative to a comparable passive margin case, and a decrease in the hydrate inventory with an increase in the plate subduction rate.

David Archer; Bruce Buffett

2011-12-31T23:59:59.000Z

310

Energy Department Expands Research into Methane Hydrates, a Vast, Untapped  

NLE Websites -- All DOE Office Websites (Extended Search)

0, 2013 0, 2013 Energy Department Expands Research into Methane Hydrates, a Vast, Untapped Potential Energy Resource of the U.S. WASHINGTON - Today, U.S. Energy Secretary Ernest Moniz announced nearly $5 million in funding across seven research projects nationwide designed to increase our understanding of methane hydrates - a large, completely untapped natural gas resource-and what it could mean for the environment, as well as American economic competiveness and energy security. "The recent boom in natural gas production - in part due to long-term Energy Department investments beginning in the 70's and 80's - has had a transformative impact on our energy landscape, helping to reduce greenhouse gas emissions and support thousands of American jobs," said Secretary Moniz. "While our research into methane hydrates is still in its early stages, these investments will increase our understanding of this domestic resource and the potential to safely and sustainably unlock the natural gas held within."

311

Dynamics of biopolymers and their hydration water studied by neutron and X-ray scattering  

E-Print Network (OSTI)

Protein functions are intimately related to their dynamics. Moreover, protein hydration water is believed to have significant influence on the dynamics of proteins. One of the evidence is that both protein and its hydration ...

Chu, Xiang-qiang

2010-01-01T23:59:59.000Z

312

Presentations from June 6-7 2013 Methane Hydrates Advisory Meeting...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Presentations from June 6-7 2013 Methane Hydrates Advisory Meeting Presentations from June 6-7 2013 Methane Hydrates Advisory Meeting ConocoPhillips test results and data analysis...

313

The dynamic response of oceanic hydrate deposits to ocean temperature change  

E-Print Network (OSTI)

during transit through the ocean water column Geophys. Res.hydrate in the world's oceans. Global Biogeochem. Cycles, 8,of methane hydrate in ocean sediment. Energy and Fuels, 19,

Reagan, Matthew T.

2008-01-01T23:59:59.000Z

314

Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico  

E-Print Network (OSTI)

hydrate systems in the Gulf of Mexico. Marine and Petroleumof the northern Gulf of Mexico gas-hydrate-stability zone.Cold seeps of the deep Gulf of Mexico: community structure

Boswell, R.D.

2010-01-01T23:59:59.000Z

315

Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico  

Science Conference Proceedings (OSTI)

Studies of geologic and geophysical data from the offshore of India have revealed two geologically distinct areas with inferred gas hydrate occurrences: the passive continental margins of the Indian Peninsula and along the Andaman convergent margin. The Indian National Gas Hydrate Program (NGHP) Expedition 01 was designed to study the occurrence of gas hydrate off the Indian Peninsula and along the Andaman convergent margin with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. NGHP Expedition 01 established the presence of gas hydrates in Krishna- Godavari, Mahanadi and Andaman basins. The expedition discovered one of the richest gas hydrate accumulations yet documented (Site 10 in the Krishna-Godavari Basin), documented the thickest and deepest gas hydrate stability zone yet known (Site 17 in Andaman Sea), and established the existence of a fully-developed gas hydrate system in the Mahanadi Basin (Site 19).

Collett, T.S. (USGS); Riedel, M. (McGill Univ., Montreal, Quebec, Canada); Cochran, J.R. (Columbia Univ., Palisades, NY); Boswell, R.M.; Kumar, Pushpendra (Oil and Natural Gas Corporation Ltd., Navi Mumbai, India); Sathe, A.V. (Oil and Natural Gas Corporation Ltd., Uttaranchal, INDIA)

2008-07-01T23:59:59.000Z

316

Ground movements associated with gas hydrate production. Final report  

SciTech Connect

This report deals with a study directed towards a modeling effort on production related ground movements and subsidence resulting from hydrate dissociation. The goal of this research study was to evaluate whether there could be subsidence related problems that could be an impediment to hydrate production. During the production of gas from a hydrate reservoir, it is expected that porous reservoir matrix becomes more compressible which may cause reservoir compression (compaction) under the influence of overburden weight. The overburden deformations can propagate its influence upwards causing subsidence near the surface where production equipment will be located. In the present study, the reservoir compaction is modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The present study is expected to provide a ``lower bound`` solution to the subsidence caused by hydrate reservoir depletion. The reservoir compaction anticipated during hydrate production was modeled by using the finite element method, which is a powerful computer modeling technique. The ground movements at the reservoir roof (i.e. reservoir compression) cause additional stresses and disturbance in the overburden strata. In this study, the reservoir compaction was modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The resulting stresses and ground movements were computed by using the finite element method. Based on the parameters used in this investigation, the maximum ground subsidence could vary anywhere from 0.50 to 6.50 inches depending on the overburden depth and the size of the depleted hydrate reservoir.

Siriwardane, H.J.; Kutuk, B.

1992-03-01T23:59:59.000Z

317

Electrical Resistivity Investigation of Gas Hydrate Distribution in  

NLE Websites -- All DOE Office Websites (Extended Search)

10 10 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354 Waco, TX 76798 Principal Author: John A. Dunbar Prepared for: United States Department of Energy National Energy Technology Laboratory January 15, 2011 Office of Fossil Energy 1 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Pr oject Quar ter 17 Repor t Report Type: Quarterly Starting October 1, 2010 Ending December 31, 2010 Author: John A. Dunbar Baylor University Department of Geology January 15, 2011 DOE Award Number: DE-FC26-06NT142959

318

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

Oil & Natural Gas Technology DOE Field Work Proposal.: ESD12-011 2012 Annual Research Progress Report (April - December 2012) Numerical Studies for the Characterization of Recoverable Resources from Methane Hydrate Deposits Project Period (April 2012 - March 2013) Lawrence Berkeley National Laboratory George Moridis (Principal Investigator) GJMoridis@lbl.gov Tel: (510) 486-4746 Prepared for: United States Department of Energy National Energy Technology Laboratory Submission date: 2/4/2013 Office of Fossil Energy ii 2012Annual Progress Report Numerical Studies for the Characterization of Recoverable Resources from Methane Hydrate Deposits WORK PERFORMED UNDER ESD12-010 Lawrence Berkeley National Laboratory George Moridis (Principal Investigator)

319

Drilling through gas hydrates formations: possible problems and suggested solution  

E-Print Network (OSTI)

Gas hydrate research in the last two decades has taken various directions ranging from ways to understand the safe and economical production of this enormous resource to drilling problems. as more rigs and production platforms move into deeper waters to its environmental impact on global warming and cooling. Gas hydrates are ice-like structures of a water lattice with cavities, which contain guest gases. Gas hydrates are stable at low temperatures and high pressures. The amount of energy trapped in gas hydrates all over the world is about twice the amount found in all recoverable fossil fuels today. This research identifies the problems facing the oil and gas industry as it drills in deeper waters where gas hydrates are present and suggests solutions to some of the problems. The problems considered in this research have been approached from a drilling point of view. Hence, the parameters investigated and discussed are drilling controlled parameters. They include rate of penetration, circulation rate and drilling fluid density. The rate of penetration in offshore wells contributes largely to the final cost of the drilling process. These 3 parameters have been linked in the course of this research in order to suggest an optimum rate of penetration. The results show the rate of penetration is directly proportional to the amount of gas released when drilling through gas hydrate. As the volume of gas released increases, the problems facing the drilling rigs, drilling crew and environment is seen to increase. The results also show the extent of risk to be expected while drilling through gas hydrate formations. A chart relating the rate of penetration, circulation rate and effective mud weight was used to select the optimum drilling rate within the drilling safety window. Finally, future considerations and recommendations in order to improve the analyses presented in this work are presented. Other drilling parameters proposed for future analysis include drill bit analysis with respect to heat transfer and the impact of dissociation of gas hydrate around the wellbore and seafloor stability.

Amodu, Afolabi Ayoola

2008-08-01T23:59:59.000Z

320

Fire in the Ice, August 2010 Methane Hydrate Newsletter  

NLE Websites -- All DOE Office Websites (Extended Search)

Figure 1: Simulation results of coupled thermo-dynamic and geomechanical changes around a hot Figure 1: Simulation results of coupled thermo-dynamic and geomechanical changes around a hot production well intersecting an HBS near a sloping seafloor after 30 years of production and heating (Rutqvist and Moridis, 2010). CONTENTS Geohazards of In Situ Gas Hydrates ...........................................1 Behavior of Methane Released in the Deep Ocean.....5 Core-Scale Heterogeneity ............6 Gas Volume Ratios ........................9 The Role of Methane Hydrates in the Earth System ....................12 Announcements .......................15 * Inter-Laboratory Comparison Project * Mississippi Canyon 118 * Research Fellowship * Call for Papers * Call for Abstracts * Upcoming Meetings Spotlight on Research .......... 20 Graham Westbrook CONTACT

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Geomechanical response of permafrost-associated hydrate deposits to depressurization-induced gas production  

E-Print Network (OSTI)

shales, depressurization is rapid and effective, leading to fast hydrate dissociation and considerable cooling during the 5 years of production

Rutqvist, J.

2009-01-01T23:59:59.000Z

322

Driving force and composition for multicomponent gas hydrate nucleation from supersaturated aqueous solutions  

E-Print Network (OSTI)

Driving force and composition for multicomponent gas hydrate nucleation from supersaturated aqueous.1063/1.1817999 I. INTRODUCTION Gas hydrate crystallization from mixtures of natural gases and water is of interest for both the prevention of hy- drate formation in natural gas production and for promotion of hydration

Firoozabadi, Abbas

323

Separation and Purification of Methane from coal-Bed Methane via the Hydrate Technology  

Science Conference Proceedings (OSTI)

The separation of methane from coal-bed methane (CBM) via hydrate process using tetrahydrofuran (THF) + sodium dodecyl sulfate (SDS) as additives was investigated in this work. The effect of additives, the concentration of the additives and hydrate memory ... Keywords: CBM, hydrate, separation, THF, SDS

Cai Jing; Chen Zhaoyang; Li Xiaosen; Xu Chungang

2010-12-01T23:59:59.000Z

324

Geophysical evidence for gas hydrates in the deep water of the South Caspian Basin, Azerbaijan  

E-Print Network (OSTI)

as methane clathrates or clathrate hydrates of natural gas, these substances are similar to ice accumulations of natural gas on Earth are in the form of gas hydrates (Collett, 1994) that occur mainly offshore water, concern over the potential hazard posed by gas hydrates has become an important issue. Chev- ron

Knapp, James Howard

325

Submarine pingoes: Indicators of shallow gas hydrates in a pockmark at Nyegga, Norwegian Sea  

E-Print Network (OSTI)

forming and disintegrating gas hydrate pingoes on the seafloor. The two most important ones are believed also manifest the whereabouts of shallow gas hydrates. The pingoes emphasise the dynamic nature and removal of plugs. Proc. Conf. on Natural Gas Hydrates. Salt Lake City. Bates, R.L., Jackson, J.A., 1987

Svensen, Henrik

326

E ects of the Driving Force on the Composition of Natural Gas Hydrates  

E-Print Network (OSTI)

- ciates to yield natural gas and water. Such hydrate technology has two important characteristics: AmbientE ects of the Driving Force on the Composition of Natural Gas Hydrates Odd I. Levik(1) , Jean for storage and transport of natural gas. Storage of natural gas in the form of hydrate at elevated pressure

Gudmundsson, Jon Steinar

327

NETL: Methane Hydrates Interagency R&D Conference  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane Hydrates Interagency R&D Conference Methane Hydrates Interagency R&D Conference March 20-22, 2002 Table of Contents Disclaimer Papers and Presentations The Curiosity of Hydrates Methane Hydrates Issues Arctic Region Projects West Coast Projects East Coast Projects Gulf of Mexico Projects Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

328

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents (OSTI)

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

329

Drilling Through Gas Hydrates Formations: Managing Wellbore Stability Risks  

E-Print Network (OSTI)

As hydrocarbon exploration and development moves into deeper water and onshore arctic environments, it becomes increasingly important to quantify the drilling hazards posed by gas hydrates. To address these concerns, a 1D semi-analytical model for heat and fluid transport in the reservoir was coupled with a numerical model for temperature distribution along the wellbore. This combination allowed the estimation of the dimensions of the hydratebearing layer where the initial pressure and temperature can dynamically change while drilling. These dimensions were then used to build a numerical reservoir model for the simulation of the dissociation of gas hydrate in the layer. The bottomhole pressure (BHP) and formation properties used in this workflow were based on a real field case. The results provide an understanding of the effects of drilling through hydratebearing sediments and of the impact of drilling fluid temperature and BHP on changes in temperature and pore pressure within the surrounding sediments. It was found that the amount of gas hydrate that can dissociate will depend significantly on both initial formation characteristics and bottomhole conditions, namely mud temperature and pressure. The procedure outlined suggested in this work can provide quantitative results of the impact of hydrate dissociation on wellbore stability, which can help better design drilling muds for ultra deep water operations.

Khabibullin, Tagir R.

2010-08-01T23:59:59.000Z

330

The U.S. DOE Methane Hydrate R&D Program DOE Sponsored Student Researchers  

NLE Websites -- All DOE Office Websites (Extended Search)

U.S. DOE Methane Hydrate R&D Program U.S. DOE Methane Hydrate R&D Program DOE Sponsored Student Researchers Publications and Presentations of DOE Supported Methane Hydrate R&D 1999-2013 December 2013 Table of Contents Section I: Documentation of Support for Education .................................................................................... 5 Additional Post-Degree Assignments at National Labs and USGS .......................................................... 14 Papers Authored and Presentations Given by NETL Methane Hydrate Fellows .................................... 15 Section II: Publications Related to the Program's Major Field Projects .................................................... 21 Alaska North Slope Gas Hydrate Reservoir Characterization (DE-FC26-01NT41332) ............................ 21

331

Effect of bubble size and density on methane conversion to hydrate  

SciTech Connect

Research is underway at NETL to understand the physical properties of methane hydrates. One area of investigation is the storage of methane as methane hydrates. An economical and efficient means of storing methane in hydrates opens many commercial opportunities such as transport of stranded gas, off-peak storage of line gas, etc.We have observed during our investigations that the ability to convert methane to methane hydrate is enhanced by foaming of the methanewater solution using a surfactant. The density of the foam, along with the bubble size, is important in the conversion of methane to methane hydrate.

Leske, J.; Taylor, C.E.; Ladner, E.P.

2007-03-01T23:59:59.000Z

332

Gas Hydrate: A Realistic Future Source of Gas Supply? | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? August 24, 2009 - 1:00pm Addthis Washington, D.C - A Department of Energy scientist writes in this week's Science magazine that a search is underway for a potentially immense untapped energy resource that, given its global distribution, has the potential to alter existing energy production and supply paradigms. In the article, Is Gas Hydrate Energy Within Reach?, Dr. Ray Boswell, technology manager for the Office of Fossil Energy's National Energy Technology Laboratory methane hydrates program, discusses recent findings and new research approaches that are clarifying gas hydrates energy potential. Driving the current interest in gas hydrate resource appraisal is the focus

333

Gas Hydrate: A Realistic Future Source of Gas Supply? | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? August 24, 2009 - 1:00pm Addthis Washington, D.C - A Department of Energy scientist writes in this week's Science magazine that a search is underway for a potentially immense untapped energy resource that, given its global distribution, has the potential to alter existing energy production and supply paradigms. In the article, Is Gas Hydrate Energy Within Reach?, Dr. Ray Boswell, technology manager for the Office of Fossil Energy's National Energy Technology Laboratory methane hydrates program, discusses recent findings and new research approaches that are clarifying gas hydrates energy potential. Driving the current interest in gas hydrate resource appraisal is the focus

334

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network (OSTI)

history of the Messoyakha field demonstrates that gas hydrates are a readily producible source of natural

Moridis, George J.

2008-01-01T23:59:59.000Z

335

Analysis of the Development of Messoyakha Gas Field: A Commercial Gas Hydrate Reservoir  

E-Print Network (OSTI)

Natural gas is an important energy source that contributes up to 25% of the total US energy reserves (DOE 2011). An increase in natural gas demand spurs further development of unconventional resources, including methane hydrate (Rajnauth 2012). Natural gas from methane hydrate has the potential to play a major role in ensuring adequate future energy supplies in the US. The worldwide volume of gas in the hydrate state has been estimated to be approximately 1.5 x 10^16 m^3 (Makogon 1984). More than 230 gas-hydrate deposits have been discovered globally. Several production technologies have been tested; however, the development of the Messoyakha field in the west Siberian basin is the only successful commercial gas-hydrate field to date. Although the presence of gas hydrates in the Messoyakha field was not a certainty, this current study determined the undeniable presence of gas hydrates in the reservoir. This study uses four models of the Messoyakha field structure and reservoir conditions and examines them based on the available geologic and engineering data. CMG STARS and IMEX software packages were used to calculate gas production from a hydrate-bearing formation on a field scale. Results of this analysis confirm the presence of gas hydrates in the Messoyakha field and also determine the volume of hydrates in place. The cumulative production from the field on January 1, 2012 is 12.9 x 10^9 m^3, and it was determined in this study that 5.4 x 10^9 m^3 was obtained from hydrates. The important issue of pressure-support mechanisms in developing a gas hydrate reservoir was also addressed in this study. Pressure-support mechanisms were investigated using different evaluation methods such as the use of gas-injection well patterns and gas/water injection using isothermal and non-isothermal simulators. Several aquifer models were examined. Simulation results showed that pressure support due to aquifer activity was not possible. Furthermore, it was shown that the water obtained from hydrates was not produced and remained in the reservoir. Results obtained from the aquifer models were confirmed by the actual water production from the field. It was shown that water from hydrates is a very strong pressure-support mechanism. Water not only remained in the reservoir, but it formed a thick water-saturated layer between the free-gas and gas-hydrate zone. Finally, thermodynamic behavior of gas hydrate decomposition was studied. Possible areas of hydrate preservation were determined. It was shown that the central top portion of the field preserved most of hydrates due to temperature reduction of hydrate decomposition.

Omelchenko, Roman 1987-

2012-12-01T23:59:59.000Z

336

Full quantitative phase analysis of hydrated lime using the Rietveld method  

SciTech Connect

Full quantitative phase analysis (FQPA) using X-ray powder diffraction and Rietveld refinements is a well-established method for the characterization of various hydraulic binders such as Portland cement and hydraulic limes. In this paper, the Rietveld method is applied to hydrated lime, a non-hydraulic traditional binder. The potential presence of an amorphous phase in this material is generally ignored. Both synchrotron radiation and a conventional X-ray source were used for data collection. The applicability of the developed control file for the Rietveld refinements was investigated using samples spiked with glass. The results were cross-checked by other independent methods such as thermal and chemical analyses. The sample microstructure was observed by transmission electron microscopy. It was found that the consistency between the different methods was satisfactory, supporting the validity of FQPA for this material. For the samples studied in this work, the amount of amorphous material was in the range 2-15 wt.%.

Lassinantti Gualtieri, Magdalena, E-mail: magdalena.gualtieri@unimore.it [Dipartimento Ingegneria dei Materiali e dell'Ambiente, Universita Degli Studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41100 Modena (Italy); Romagnoli, Marcello; Miselli, Paola; Cannio, Maria [Dipartimento Ingegneria dei Materiali e dell'Ambiente, Universita Degli Studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41100 Modena (Italy)] [Dipartimento Ingegneria dei Materiali e dell'Ambiente, Universita Degli Studi di Modena e Reggio Emilia, Via Vignolese 905/a, I-41100 Modena (Italy); Gualtieri, Alessandro F. [Dipartimento di Scienze della Terra, Universita Degli Studi di Modena e Reggio Emilia, I-41100 Modena (Italy)] [Dipartimento di Scienze della Terra, Universita Degli Studi di Modena e Reggio Emilia, I-41100 Modena (Italy)

2012-09-15T23:59:59.000Z

337

TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media  

Science Conference Proceedings (OSTI)

TOUGH+HYDRATE v1.0 is a new code for the simulation of the behavior of hydrate-bearing geologic systems. By solving the coupled equations of mass and heat balance, TOUGH+HYDRATE can model the non-isothermal gas release, phase behavior and flow of fluids and heat under conditions typical of common natural CH{sub 4}-hydrate deposits (i.e., in the permafrost and in deep ocean sediments) in complex geological media at any scale (from laboratory to reservoir) at which Darcy's law is valid. TOUGH+HYDRATE v1.0 includes both an equilibrium and a kinetic model of hydrate formation and dissociation. The model accounts for heat and up to four mass components, i.e., water, CH{sub 4}, hydrate, and water-soluble inhibitors such as salts or alcohols. These are partitioned among four possible phases (gas phase, liquid phase, ice phase and hydrate phase). Hydrate dissociation or formation, phase changes and the corresponding thermal effects are fully described, as are the effects of inhibitors. The model can describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects and inhibitor-induced effects. TOUGH+HYDRATE is the first member of TOUGH+, the successor to the TOUGH2 [Pruess et al., 1991] family of codes for multi-component, multiphase fluid and heat flow developed at the Lawrence Berkeley National Laboratory. It is written in standard FORTRAN 95, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available.

Moridis, George; Moridis, George J.; Kowalsky, Michael B.; Pruess, Karsten

2008-03-01T23:59:59.000Z

338

Geomechanical Performance of Hydrate-Bearing Sediments in Offshore Environments  

Science Conference Proceedings (OSTI)

The main objective of this study is to develop the necessary knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus is on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. To achieve this objective, we have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. To be sure our geomechanical modeling is realistic, we are also investigating the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. In Phase II of the project, we will review all published core data and generate additional core data to verify the models. To generate data for our models, we are using data from the literature and we will be conducting laboratory studies in 2007 that generate data to (1) evaluate the conceptual pore-scale models, (2) calibrate the mathematical models, (3) determine dominant relations and critical parameters defining the geomechanical behavior of HBS, and (4) establish relationships between the geomechanical status of HBS and the corresponding geophysical signature. The milestones for Phase I of this project are given as follows: Literature survey on typical sediments containing gas hydrates in the ocean (TAMU); Recommendations on how to create typical sediments in the laboratory (TAMU); Demonstrate that typical sediments can be created in a repeatable manner in the laboratory and gas hydrates can be created in the pore space (TAMU); Develop a conceptual pore-scale model based on available data and reports (UCB); Test the developed pore-scale concepts on simple configurations and verify the results against known measurements and observations (UCB); Complete the FLAC3D routines that will be linked with the reservoir model (LBNL); Complete the TOUGH+/HYDRATE modifications and extensions (LBNL); Complete the TOUGH+/FLAC3D interaction interface (LBNL); Integrate and test the coupled geomechanical numerical model TFxH/FLAC3D (LBNL); and Demonstrate that Petrel can be used to develop an earth model for providing data to the TOUGH+/FLAC3D (SLB).

Stephen A. Holditch

2006-12-31T23:59:59.000Z

339

TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media  

E-Print Network (OSTI)

R.C. Schroeder. SHAFT 79 Users Manual, Lawrence BerkeleyFx/HYDRATE v1.0 Users Manual: A Code for the Simulation ofTOUGH+HYDRATE v1.0 Users Manual: A Code for the Simulation

Moridis, George

2008-01-01T23:59:59.000Z

340

GEOTECHNICAL INVESTIGATION CHEVRON GULF OF MEXICO GAS HYDRATES JIP  

NLE Websites -- All DOE Office Websites (Extended Search)

GEOTECHNICAL INVESTIGATION GEOTECHNICAL INVESTIGATION CHEVRON GULF OF MEXICO GAS HYDRATES JIP BLOCKS 13 AND 14, ATWATER VALLEY AREA BLOCK 151, KEATHLEY CANYON AREA GULF OF MEXICO RESULTS OF CORE SAMPLE ANALYSIS, STANDARD AND ADVANCED LABORATORY TESTING Report No. 0201-5081 CHEVRON TEXACO ENERGY TECHNOLOGY COMPANY Houston, Texas FUGRO-McCLELLAND MARINE GEOSCIENCES, INC. P. O. Box 740010, Houston, Texas 77274, Phone: 713-369-5600, Fax: 713-369-5570 GEOTECHNICAL INVESTIGATION CHEVRON GULF OF MEXICO GAS HYDRATES JIP BLOCKS 13 AND 14, ATWATER VALLEY AREA BLOCK 151, KEATHLEY CANYON AREA GULF OF MEXICO RESULTS OF CORE SAMPLE ANALYSIS, STANDARD AND ADVANCED LABORATORY TESTING REPORT NO. 0201-5081 Client: ChevronTexaco Energy Technology Company 1500 Louisiana St. Houston, Tx 77002

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Electrical Resistivity Investigation of Gas Hydrate Distribution in  

NLE Websites -- All DOE Office Websites (Extended Search)

July 1 - September 30, 2011 July 1 - September 30, 2011 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354 Waco, TX 76798 Principal Author: John A. Dunbar Prepared for: United States Department of Energy National Energy Technology Laboratory October 14, 2011 Office of Fossil Energy 1 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Pr oject Quar ter 20 Repor t Report Type: Quarterly Starting July 1, 2011 Ending September 30, 2011 Author: John A. Dunbar Baylor University Department of Geology October 14, 2011 DOE Award Number: DE-FC26-06NT142959

342

Electrical Resistivity Investigation of Gas Hydrate Distribution in  

NLE Websites -- All DOE Office Websites (Extended Search)

January 1 - March 31, 2012 January 1 - March 31, 2012 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354 Waco, TX 76798 Principal Author: John A. Dunbar Prepared for: United States Department of Energy National Energy Technology Laboratory April 18, 2012 Office of Fossil Energy 1 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Pr oject Quar ter 22 Repor t Report Type: Quarterly Starting January 1, 2012 Ending March 31, 2012 Author: John A. Dunbar Baylor University Department of Geology April 18, 2012 DOE Award Number: DE-FC26-06NT142959

343

NETL-ORD Methane Hydrate Project - Micro XCT Characterization and  

NLE Websites -- All DOE Office Websites (Extended Search)

Micro-XCT Characterization and Examination of Pressured Cores Last Reviewed 7/15/2013 Micro-XCT Characterization and Examination of Pressured Cores Last Reviewed 7/15/2013 Goal The primary goal of this research is to visualize gas hydrate within sediment pore spaces under in situ conditions using a high-resolution micro-XCT scanner. Performers Yongkoo Seol – NETL Office of Research & Development Eilis Rosenbaum – NETL Office of Research & Development Jongho Cha- Oak Ridge Institute for Science and Education Location National Energy Technology Laboratory - Morgantown, West Virginia Description The initial phase of this research will focus on developing the experimental system needed to accommodate hydrate-bearing samples under in-situ conditions within an existing micro-XCT (X-ray transparent cell) system. Development will consist of designing, building, and testing the

344

Notices DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

32 Federal Register 32 Federal Register / Vol. 77, No. 130 / Friday, July 6, 2012 / Notices DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. The Federal Advisory Committee Act (Pub. L. 92- 463, 86 Stat. 770) requires that notice of these meetings be announced in the Federal Register. DATES: Thursday, July 26, 2012, 8:00 a.m. to 8:30 a.m. (CDT)- Registration, 8:30 a.m. to 5:00 p.m. (CDT)-Meeting. ADDRESSES: Marriott Houston Airport, 18700 John F. Kennedy Boulevard, Houston, Texas 77032. FOR FURTHER INFORMATION CONTACT: Lou Capitanio, U.S. Department of Energy, Office of Oil and Natural Gas, 1000

345

Natural gas production from hydrate dissociation: An axisymmetric model  

Science Conference Proceedings (OSTI)

This paper describes an axisymmetric model for natural gas production from the dissociation of methane hydrate in a confined reservoir by a depressurizing well. During the hydrate dissociation, heat and mass transfer in the reservoir are analyzed. The system of governing equations is solved by a finite difference scheme. For different well pressures and reservoir temperatures, distributions of temperature and pressure in the reservoir, as well as the natural gas production from the well are evaluated. The numerical results are compared with those obtained by a linearization method. It is shown that the gas production rate is a sensitive function of well pressure. The simulation results are compared with the linearization approach and the shortcomings of the earlier approach are discussed.

Ahmadi, G. (Clarkson Univ., Pottsdam, NY); Ji, Chuang (Clarkson Univ., Pottsdam, NY); Smith, D.H.

2007-08-01T23:59:59.000Z

346

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

2 - June 2012 2 - June 2012 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory July 31, 2012 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion..................................................................................................... 4 Cost Status......................................................................................................5

347

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

7 7 Quarterly Progress Report (April - June 2009) ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFILTER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory July 17, 2009 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 5 Cost Status..................................................................................................... 6

348

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

09 - December 2009 09 - December 2009 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory January 16, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

349

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

2 - March 2012 2 - March 2012 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory April 26, 2012 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion..................................................................................................... 4 Cost Status......................................................................................................5

350

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

0 - March 2010 0 - March 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory April 15, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

351

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

09 - September 2009 09 - September 2009 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory October 31, 2009 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

352

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

0 - June 2010 0 - June 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory July 17, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

353

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

0 - December 2010 0 - December 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory January 31, 2011 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion.................................................................................................... 5 Cost Status......................................................................................................7

354

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

1 - September 2011 1 - September 2011 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory October 23, 2011 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion..................................................................................................... 4 Cost Status......................................................................................................5

355

Hydrogen speciation in hydrated layers on nuclear waste glass  

DOE Green Energy (OSTI)

The hydration of an outer layer on nuclear waste glasses is known to occur during leaching, but the actual speciation of hydrogen (as water or hydroxyl groups) in these layers has not been determined. As part of the Nevada Nuclear Waste Storage Investigations Project, we have used infrared spectroscopy to determine hydrogen speciations in three nuclear waste glass compositions (SRL-131 & 165, and PNL 76-68), which were leached at 90{sup 0}C (all glasses) or hydrated in a vapor-saturated atmosphere at 202{sup 0}C (SRL-131 only). Hydroxyl groups were found in the surface layers of all the glasses. Molecular water was found in the surface of SRL-131 and PNL 76-68 glasses that had been leached for several months in deionized water, and in the vapor-hydrated sample. The water/hydroxyl ratio increases with increasing reaction time; molecular water makes up most of the hydrogen in the thick reaction layers on vapor-phase hydrated glass while only hydroxyl occurs in the least reacted samples. Using the known molar absorptivities of water and hydroxyl in silica-rich glass the vapor-phase layer contained 4.8 moles/liter of molecular water, and 0.6 moles water in the form hydroxyl. A 15 {mu}m layer on SRL-131 glass formed by leaching at 90{sup 0}C contained a total of 4.9 moles/liter of water, 2/3 of which was as hydroxyl. The unreacted bulk glass contains about 0.018 moles/liter water, all as hydroxyl. The amount of hydrogen added to the SRL-131 glass was about 70% of the original Na + Li content, not the 300% that would result from alkali=hydronium ion interdiffusion. If all the hydrogen is then assumed to be added as the result of alkali-H{sup +} interdiffusion, the molecular water observed may have formed from condensation of the original hydroxyl groups.

Aines, R.D.; Weed, H.C.; Bates, J.K.

1987-01-15T23:59:59.000Z

356

Why alite stops hydrating below 80% relative humidity  

Science Conference Proceedings (OSTI)

It has been observed that the hydration of cement paste stops when the relative humidity drops below about 80%. A thermodynamic analysis shows that the capillary pressure exerted at that RH shifts the solubility of tricalcium silicate, so that it is in equilibrium with water. This is a reflection of the chemical shrinkage in this system: according to Le Chatelier's principle, since the volume of the products is less than that of the reactants, a negative (capillary) pressure opposes the reaction.

Flatt, Robert J. [Sika Technology AG, Zuerich (Switzerland); Scherer, George W., E-mail: scherer@princeton.edu [Princeton University, Eng. Quad. E-319, Princeton NJ 08544 (United States); Bullard, Jeffrey W. [National Institute of Standards and Technology, Gaithersburg MD (United States)

2011-09-15T23:59:59.000Z

357

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

0 - September 2010 0 - September 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory October 30, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary....................................................................................... 2 Progress, Results and Discussion........................................................................ 3 Conclusion....................................................................................................5 Cost Status...................................................................................................6

358

Additives and method for controlling clathrate hydrates in fluid systems  

DOE Patents (OSTI)

Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hindrance and/or charge repulsion. Also, polymers having an amide on which a C{sub 1}-C{sub 4} group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

Sloan, E.D. Jr.; Christiansen, R.L.; Lederhos, J.P.; Long, J.P.; Panchalingam, V.; Du, Y.; Sum, A.K.W.

1997-06-17T23:59:59.000Z

359

Gas Production from Hydrate-Bearing Sediments - Emergent Phenomena -  

SciTech Connect

Even a small fraction of fine particles can have a significant effect on gas production from hydrate-bearing sediments and sediment stability. Experiments were conducted to investigate the role of fine particles on gas production using a soil chamber that allows for the application of an effective stress to the sediment. This chamber was instrumented to monitor shear-wave velocity, temperature, pressure, and volume change during CO{sub 2} hydrate formation and gas production. The instrumented chamber was placed inside the Oak Ridge National Laboratory Seafloor Process Simulator (SPS), which was used to control the fluid pressure and temperature. Experiments were conducted with different sediment types and pressure-temperature histories. Fines migrated within the sediment in the direction of fluid flow. A vuggy structure formed in the sand; these small cavities or vuggs were precursors to the development of gas-driven fractures during depressurization under a constant effective stress boundary condition. We define the critical fines fraction as the clay-to-sand mass ratio when clays fill the pore space in the sand. Fines migration, clogging, vugs, and gas-driven fracture formation developed even when the fines content was significantly lower than the critical fines fraction. These results show the importance of fines in gas production from hydrate-bearing sediments, even when the fines content is relatively low.

Jung, J.W. [Georgia Institute of Technology; Jang, J.W. [Georgia Institute of Technology; Tsouris, Costas [ORNL; Phelps, Tommy Joe [ORNL; Rawn, Claudia J [ORNL; Santamarina, Carlos [Georgia Institute of Technology

2012-01-01T23:59:59.000Z

360

Additives and method for controlling clathrate hydrates in fluid systems  

DOE Patents (OSTI)

Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

Sloan, Jr., Earle Dendy (Golden, CO); Christiansen, Richard Lee (Littleton, CO); Lederhos, Joseph P. (Wheatridge, CO); Long, Jin Ping (Dallas, TX); Panchalingam, Vaithilingam (Lakewood, CO); Du, Yahe (Golden, CO); Sum, Amadeu Kun Wan (Golden, CO)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Assessing the Thermodynamic Feasibility of the Conversion of Methane Hydrate into Carbon Dioxide Hydrate in Porous Media  

NLE Websites -- All DOE Office Websites (Extended Search)

Assessing the Thermodynamic Feasibility of the Conversion of Methane Assessing the Thermodynamic Feasibility of the Conversion of Methane Hydrate into Carbon Dioxide Hydrate in Porous Media Duane H. Smith (dsmith@netl.doe.gov; 304-285-4069), U.S. Department of Energy, National Energy Technology Laboratory, Morgantown, WV 26507-0880 Kal Seshadri (kal.seshadri@netl.doe.gov; 304-285-4680), Parsons Infrastructure and Technology Group, Morgantown, WV 26505 Joseph W. Wilder (wilder@math.wvu.edu; 304-293-2011), U.S. Department of Energy, National Energy Technology Laboratory, Morgantown, WV 26507-0880 (Permanent Address: Dept of Mathematics, P. O. Box 6310, West Virginia University, Morgantown, WV, 26506-6310) Abstract Concerns about the potential effects of rising carbon dioxide levels in the atmosphere have stimulated interest in a number of carbon dioxide sequestration studies. One

362

NETL: Methane Hydrates - DOE/NETL Projects - A New Approach to  

NLE Websites -- All DOE Office Websites (Extended Search)

A New Approach to Understanding the Occurrence and Volume of Natural Gas Hydrate in the Northern Gulf of Mexico Using Petroleum Industry Well Logs Last Reviewed 12/18/2013 A New Approach to Understanding the Occurrence and Volume of Natural Gas Hydrate in the Northern Gulf of Mexico Using Petroleum Industry Well Logs Last Reviewed 12/18/2013 DE-FE0009949 Goal The overarching objective of the project is to significantly increase our understanding of the occurrence, volume, and fine scale distribution of natural gas hydrate in the northern Gulf of Mexico using petroleum industry and Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) well logs. Performer The Ohio State University, Columbus, OH 43210 Background A large quantity of natural gas hydrate certainly occurs within the sediments of the northern Gulf of Mexico; however, the total amount and distribution of gas hydrate across the basin is relatively unconstrained

363

Challenges, uncertainties and issues facing gas production from gas hydrate deposits  

SciTech Connect

The current paper complements the Moridis et al. (2009) review of the status of the effort toward commercial gas production from hydrates. We aim to describe the concept of the gas hydrate petroleum system, to discuss advances, requirement and suggested practices in gas hydrate (GH) prospecting and GH deposit characterization, and to review the associated technical, economic and environmental challenges and uncertainties, including: the accurate assessment of producible fractions of the GH resource, the development of methodologies for identifying suitable production targets, the sampling of hydrate-bearing sediments and sample analysis, the analysis and interpretation of geophysical surveys of GH reservoirs, well testing methods and interpretation of the results, geomechanical and reservoir/well stability concerns, well design, operation and installation, field operations and extending production beyond sand-dominated GH reservoirs, monitoring production and geomechanical stability, laboratory investigations, fundamental knowledge of hydrate behavior, the economics of commercial gas production from hydrates, and the associated environmental concerns.

Moridis, G.J.; Collett, T.S.; Pooladi-Darvish, M.; Hancock, S.; Santamarina, C.; Boswell, R.; Kneafsey, T.; Rutqvist, J.; Kowalsky, M.; Reagan, M.T.; Sloan, E.D.; Sum, A.K.; Koh, C.

2010-11-01T23:59:59.000Z

364

Integrated Geologic and Geophysical Assessment of the Eileen Gas Hydrate Accumulation, North Slope, Alaska  

SciTech Connect

Using detailed analysis and interpretation of 2-D and 3-D seismic data, along with modeling and correlation of specially processed log data, a viable methodology has been developed for identifying sub-permafrost gas hydrate prospects within the Gas Hydrate Stability Zone (HSZ) and associated ''sub-hydrate'' free gas prospects in the Milne Point area of northern Alaska (Figure 1). The seismic data, in conjunction with modeling results from a related study, was used to characterize the conditions under which gas hydrate prospects can be delineated using conventional seismic data, and to analyze reservoir fluid properties. Monte Carlo style gas hydrate volumetric estimates using Crystal Ball{trademark} software to estimate expected in-place reserves shows that the identified prospects have considerable potential as gas resources. Future exploratory drilling in the Milne Point area should provide answers about the producibility of these shallow gas hydrates.

Timothy S. Collett; David J. Taylor; Warren F. Agena; Myung W. Lee; John J. Miller; Margarita Zyrianova

2005-04-30T23:59:59.000Z

365

Salinity-induced hydrate dissociation: A mechanism for recent CH4 release on Mars  

SciTech Connect

Recent observations of CH4 in the Martian atmosphere suggest that CH4 has been added relatively recently. Several mechanisms for recent CH4 release have been proposed including subsurface biological methanogenesis, abiogenic hydrothermal and/or volcanic activity, dissociation of CH4 hydrates, atmospheric photolysis, or addition of organics via bolide impact. This study examines the effects of increasing salinity on gas hydrate stability and compares estimates of the Martian geothermal gradient to CH4 and CO2 hydrate stability fields in the presence of high salinity brines. The results demonstrate that salinity increases alone result in a significant decrease in the predicted hydrate stability zone within the Martian subsurface and may be a driving force in CH4 hydrate destabilization. Active thermal and/or pressure fluctuations are not required in order for CH4 hydrates to be the source of atmospheric CH4.

Madden, Megan Elwood [ORNL; Ulrich, Shannon M [ORNL; Onstott, Tullis [Princeton University; Phelps, Tommy Joe [ORNL

2007-01-01T23:59:59.000Z

366

Methane hydrate distribution from prolonged and repeated formation in natural and compacted sand samples: X-ray CT observations  

SciTech Connect

To study physical properties of methane gas hydrate-bearing sediments, it is necessary to synthesize laboratory samples due to the limited availability of cores from natural deposits. X-ray computed tomography (CT) and other observations have shown gas hydrate to occur in a number of morphologies over a variety of sediment types. To aid in understanding formation and growth patterns of hydrate in sediments, methane hydrate was repeatedly formed in laboratory-packed sand samples and in a natural sediment core from the Mount Elbert Stratigraphic Test Well. CT scanning was performed during hydrate formation and decomposition steps, and periodically while the hydrate samples remained under stable conditions for up to 60 days. The investigation revealed the impact of water saturation on location and morphology of hydrate in both laboratory and natural sediments during repeated hydrate formations. Significant redistribution of hydrate and water in the samples was observed over both the short and long term.

Rees, E.V.L.; Kneafsey, T.J.; Seol, Y.

2010-07-01T23:59:59.000Z

367

Four Critical Needs to Change the Hydrate Energy Paradigm from Assessment to Production: The 2007 Report to Congress by the U.S. Federal methane Hydrate Advisory Committee  

Science Conference Proceedings (OSTI)

This work summarizes a two-year study by the U.S. Federal Methane Hydrate Advisory Committee recommending the future needs for federally-supported hydrate research. The Report was submitted to the US Congress on August 14, 2007 and includes four recommendations regarding (a) permafrost hydrate production testing, (b) marine hydrate viability assessment (c) climate effect of hydrates, and (d) international cooperation. A secure supply of natural gas is a vital goal of the U.S. national energy policy because natural gas is the cleanest and most widely used of all fossil fuels. The inherent cleanliness of natural gas, with the lowest CO2 emission per unit of heat energy of any fossil fuel, means substituting gas for coal and fuel oil will reduce emissions that can exacerbate the greenhouse effect. Both a fuel and a feedstock, a secure and reasonably priced supply of natural gas is important to industry, electric power generators, large and small commercial enterprises, and homeowners. Because each volume of solid gas hydrate contains as much as 164 standard volumes of methane, hydrates can be viewed as a concentrated form of natural gas equivalent to compressed gas but less concentrated than liquefied natural gas (LNG). Natural hydrate accumulations worldwide are estimated to contain 700,000 TCF of natural gas, of which 200,000 TCF are located within the United States. Compared with the current national annual consumption of 22 TCF, this estimate of in-place gas in enormous. Clearly, if only a fraction of the hydrated methane is recoverable, hydrates could constitute a substantial component of the future energy portfolio of the Nation (Figure 1). However, recovery poses a major technical and commercial challenge. Such numbers have sparked interest in natural gas hydrates as a potential, long-term source of energy, as well as concerns about any potential impact the release of methane from hydrates might have on the environment. Energy-hungry countries such as India and Japan are outspending the United States on hydrate science and engineering R&D by a factor of 10, and may bring this resource to market as much as a decade before the United States.

Mahajan,D.; Sloan, D.; Brewer, P.; Dutta, N.; Johnson, A.; Jones, E.; Juenger, K.; Kastner, M.; Masutani, S.; Swenson, R.; Whelan, J.; Wilson, s.; Woolsey, R.

2009-03-11T23:59:59.000Z

368

Mechanisms Leading to Co-existence of Gas and Hydrate in Ocean Sediments  

NLE Websites -- All DOE Office Websites (Extended Search)

Leading to Co-existence of Gas Leading to Co-existence of Gas and Hydrate in Ocean Sediments Steven Bryant Dept. of Petroleum and Geosystems Engineering The University of Texas at Austin and Ruben Juanes Dept. of Civil Engineering MIT Observations and Ruminations * Some proposed explanations for co-existence - kinetics of hydrate formation; - regional geotherms; - hypersaline brines as a result of hydrate formation;

369

Methane hydrate formation in turbidite sediments of northern Cascadia IODP Expedition 311  

Science Conference Proceedings (OSTI)

Expedition 311 of the Integrated Ocean Drilling Program (IODP) to northern Cascadia recovered gas-hydrate bearing sediments along a SWNE transect from the first ridge of the accretionary margin to the eastward limit of gas-hydrate stability. In this study we contrast the gas gas-hydrate distribution from two sites drilled ~8 km apart in different tectonic settings. At Site U1325, drilled on a depositional basin with nearly horizontal sedimentary sequences, the gas-hydrate distribution shows a trend of increasing saturation toward the base of gas-hydrate stability, consistent with several model simulations in the literature. Site U1326 was drilled on an uplifted ridge characterized by faulting, which has likely experienced some mass wasting events. Here the gas hydrate does not show a clear depth-distribution trend, the highest gas-hydrate saturation occurs well within the gas-hydrate stability zone at the shallow depth of ~49 mbsf. Sediments at both sites are characterized by abundant coarse-grained (sand) layers up to 23 cm in thickness, and are interspaced within fine-grained (clay and silty clay) detrital sediments. The gas-hydrate distribution is punctuated by localized depth intervals of high gas-hydrate saturation, which preferentially occur in the coarse-grained horizons and occupy up to 60% of the pore space at Site U1325 and N80% at Site U1326. Detailed analyses of contiguous samples of different lithologies show that when enough methane is present, about 90% of the variance in gas-hydrate saturation can be explained by the sand (N63 ?m) content of the sediments. The variability in gas-hydrate occupancy of sandy horizons at Site U1326 reflects an insufficient methane supply to the sediment section between 190 and 245 mbsf.

Torres, M. E.; Trehu, Ann M.; cespedes, N.; Kastner, Miriam; Wortmann, Ulrich; Kim, J.; Long, Philip E.; Malinverno, Alberto; Pohlman, J. W.; Collett, T. S.

2008-07-15T23:59:59.000Z

370

Applied Quantum Information Science  

Science Conference Proceedings (OSTI)

Applied Quantum Information Science. Summary: Theory is being developed and used to devise methods for preserving ...

2012-05-30T23:59:59.000Z

371

U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies  

Energy.gov (U.S. Department of Energy (DOE))

Methane Hydrates May Exceed the Energy Content of All Other Fossil Fuels Combined; Could Ensure Decades of Affordable Natural Gas and Cut Americas Foreign Oil Dependence

372

Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments  

E-Print Network (OSTI)

Page viable gas production. The overall conclusion drawnnot promising targets for gas production. Acknowledgment TheTS. Strategies for gas production from hydrate accumulations

Moridis, George J.; Sloan, E. Dendy

2006-01-01T23:59:59.000Z

373

Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates  

SciTech Connect

Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO{sub 2}) and/or production of methane (CH{sub 4}) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH{sub 4} and CO{sub 2} hydrate (CH{sub 4}-CO{sub 2} mixed hydrates), as well as thermophysical property changes during gas exchange. This study explores the thermal dissociation behavior and dissociation enthalpies of CH{sub 4}-CO{sub 2} mixed hydrates. We prepared CH{sub 4}-CO{sub 2} mixed hydrate samples from two different, well-defined gas mixtures. During thermal dissociation of a CH{sub 4}-CO{sub 2} mixed hydrate sample, gas samples from the head space were periodically collected and analyzed using gas chromatography. The changes in CH{sub 4}-CO{sub 2} compositions in both the vapor phase and hydrate phase during dissociation were estimated based on the gas chromatography measurements. It was found that the CO{sub 2} concentration in the vapor phase became richer during dissociation because the initial hydrate composition contained relatively more CO{sub 2} than the vapor phase. The composition change in the vapor phase during hydrate dissociation affected the dissociation pressure and temperature; the richer CO{sub 2} in the vapor phase led to a lower dissociation pressure. Furthermore, the increase in CO{sub 2} concentration in the vapor phase enriched the hydrate in CO{sub 2}. The dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate was computed by fitting the Clausius-Clapeyron equation to the pressure-temperature (PT) trace of a dissociation test. It was observed that the dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate lays between the limiting values of pure CH{sub 4} hydrate and CO{sub 2} hydrate, increasing with the CO{sub 2} fraction in the hydrate phase.

Kwon, T.H.; Kneafsey, T.J.; Rees, E.V.L.

2011-02-15T23:59:59.000Z

374

Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?  

SciTech Connect

Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

Paull, C.K.; Ussler, W. III; Borowski, W.S.

1993-09-01T23:59:59.000Z

375

Challenges, uncertainties and issues facing gas production from gas hydrate deposits  

E-Print Network (OSTI)

focus of GH exploration and production studies in northernoil and gas exploration and production activities; includingGas hydrate exploration and production activities will be

Moridis, G.J.

2011-01-01T23:59:59.000Z

376

Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report  

Science Conference Proceedings (OSTI)

Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

2007-09-01T23:59:59.000Z

377

Experimental study on the formation and dissociation conditions of methane hydrates in porous media  

E-Print Network (OSTI)

Gas hydrates are crystalline compounds formed when gas and water molecules are combined under low temperature and high pressure conditions. This study experimentally investigates the conditions leading to the formation and dissociation of gas hydrates formed by methane gas and pure water in porous media. Methane gas hydrates were formed in a cell packed with 0.177-mm (0.007 in) diameter single sand (U.S. Sieve Series Designation Mesh No. 80) and 0.420-mm (0.017 in) diameter single sand (U.S. Sieve Series Designation Mesh No. 40), which were saturated with pure methane gas and distilled deionized water. From the plots of pressure and temperature curves for the formation and dissociation of methane hydrates in porous media, the beginning and ending points of hydrate formation as the cell was cooled are investigated. The ending point of hydrate dissociation occurs as the cell is heated, so that the cell pressure increases at the conditions of hydrate dissociation. The initial conditions in this experiment were in the range of 82.4 bars (1,200 psi) to 102.7 bars (1,497 psi) of pressure and in the range of 24.3?C (75.7?F) to 27.3?C (81.1?F) of temperature. At the end of hydrate dissociation, the conditions of equilibrium phase was found approximately at a pressure of 88.8 bars (1,294 psi) and temperature of 14.5oC (58.1?F) in Runs 1 to 10, at a pressure of 91.8 bars (1,337 psi) and temperature of 17.4?C (63.3?F) in Runs 11 and 12, at a pressure of 86.5 bars (1,260 psi) and temperature of 17.31oC (63.2?F) in Run 13, and at a pressure of 93.2 bars (1,359 psi) and temperature of 15.9?C (60.6?F) in Runs 14 to 16. Temperature jumping data at the beginning point of hydrate formation and the variation with time of pressure and temperature during hydrate formation and dissociation were recorded. These experimental data may be used to improve predictive thermodynamic models of methane hydrates in porous media. The accurate prediction of methane hydrates in porous media may remove a hazard to drilling from seafloor hydrate slides resulting from the dissociation of gas hydrates. A predictive thermodynamic model would also allow the prediction of the onset of hydrate formation conditions in porous media, and the evaluation of methods to recover methane gas from gas hydrate reservoirs.

Jung, Woodong

2002-01-01T23:59:59.000Z

378

NETL: National Methane Hydrates R&D Program- 2009 GOM JIP Expedition  

NLE Websites -- All DOE Office Websites (Extended Search)

of fracture-filling gas hydrate. As drilling proceeding, the lack of use of heavy drilling fluids and slow penetration rates (both designed intentionally to maximize the...

379

Basin scale assessment of gas hydrate dissociation in response to climate change  

SciTech Connect

Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating climate. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. Field investigations have discovered substantial methane gas plumes exiting the seafloor along the Arctic Ocean margin, and the plumes appear at depths corresponding to the upper limit of a receding gas hydrate stability zone. It has been suggested that these plumes may be the first visible signs of the dissociation of shallow hydrate deposits due to ongoing climate change in the arctic. We simulate the release of methane from oceanic deposits, including the effects of fully-coupled heat transfer, fluid flow, hydrate dissociation, and other thermodynamic processes, for systems representative of segments of the Arctic Ocean margins. The modeling encompasses a range of shallow hydrate deposits from the landward limit of the hydrate stability zone down to water depths beyond the expected range of century-scale temperature changes. We impose temperature changes corresponding to predicted rates of climate change-related ocean warming and examine the possibility of hydrate dissociation and the release of methane. The assessment is performed at local-, regional-, and basin-scales. The simulation results are consistent with the hypothesis that dissociating shallow hydrates alone can result in significant methane fluxes at the seafloor. However, the methane release is likely to be confined to a narrow region of high dissociation susceptibility, defined by depth and temperature, and that any release will be continuous and controlled, rather than explosive. This modeling also establishes the first realistic bounds for methane release along the arctic continental shelf for potential hydrate dissociation scenarios, and ongoing work may help confirm whether climate change is already impacting the stability of the vast oceanic hydrate reservoir.

Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.; Cameron-Smith, P.

2011-07-01T23:59:59.000Z

380

NATURAL GAS HYDRATES STORAGE PROJECT PHASE II. CONCEPTUAL DESIGN AND ECONOMIC STUDY  

SciTech Connect

DOE Contract DE-AC26-97FT33203 studied feasibility of utilizing the natural-gas storage property of gas hydrates, so abundantly demonstrated in nature, as an economical industrial process to allow expanded use of the clean-burning fuel in power plants. The laboratory work achieved breakthroughs: (1) Gas hydrates were found to form orders of magnitude faster in an unstirred system with surfactant-water micellar solutions. (2) Hydrate particles were found to self-pack by adsorption on cold metal surfaces from the micellar solutions. (3) Interstitial micellar-water of the packed particles were found to continue forming hydrates. (4) Aluminum surfaces were found to most actively collect the hydrate particles. These laboratory developments were the bases of a conceptual design for a large-scale process where simplification enhances economy. In the design, hydrates form, store, and decompose in the same tank in which gas is pressurized to 550 psi above unstirred micellar solution, chilled by a brine circulating through a bank of aluminum tubing in the tank employing gas-fired refrigeration. Hydrates form on aluminum plates suspended in the chilled micellar solution. A low-grade heat source, such as 110 F water of a power plant, circulates through the tubing bank to release stored gas. The design allows a formation/storage/decomposition cycle in a 24-hour period of 2,254,000 scf of natural gas; the capability of multiple cycles is an advantage of the process. The development costs and the user costs of storing natural gas in a scaled hydrate process were estimated to be competitive with conventional storage means if multiple cycles of hydrate storage were used. If more than 54 cycles/year were used, hydrate development costs per Mscf would be better than development costs of depleted reservoir storage; above 125 cycles/year, hydrate user costs would be lower than user costs of depleted reservoir storage.

R.E. Rogers

1999-09-27T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Microsoft Word - Quarterly Report 4- DOE Hydrates.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

10195 10195 Quarterly Research Performance Progress Report (Period ending 8/31/2013) Methane Hydrate Field Program Project Period (October 1, 2012 - December 31, 2013) Submitted by: Greg Myers - Principal Investigator _________________________ Signature Consortium for Ocean Leadership DUNS #:046862582 1201 New York Avenue, NW Fourth Floor e-mail: gmyers@oceanleadership.org Phone number: (202) 448-1258 Prepared for: United States Department of Energy National Energy Technology Laboratory October 31, 2013 Office of Fossil Energy 2 ACCOMPLISHMENTS: The primary objective of the project is to conduct scientific planning that will help enable future scientific ocean drilling, coring, logging, testing and analytical activities to assess the geologic occurrence, regional

382

Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico  

E-Print Network (OSTI)

volumes of shale (gray), sand (yellow), gas hydrate-?lledgas hydrate-bearing zone is also bounded laterally with impermeable shaleshale section that overlies the Frio sand showing four-way closure that forms the trap for the AC818 gas

Boswell, R.D.

2010-01-01T23:59:59.000Z

383

Evaluation of Hydration Free Energy by Level-Set Variational Implicit-Solvent Model  

E-Print Network (OSTI)

Evaluation of Hydration Free Energy by Level-Set Variational Implicit-Solvent Model with Coulomb free energy but also the polar and nonpolar contributions individually. The correlation between VISM-CFA and experiments is R2 = 0.763 for total hydration free energy, with a root mean square deviation (RMSD) of 1

Li, Bo

384

Hydration of Gases to Reduce Major Greenhouse Gases Emission into the Atmosphere  

Science Conference Proceedings (OSTI)

A technology on replacement methane (CH4) from natural gas hydrate (NGH) with carbon dioxide (CO2) is described. And the technology is demonstrated in theoretics and experiment, respectively. Moreover, combined with the main emission channel of CH4 in ... Keywords: greenhouse effect, hydrate, CO2, CH4

Feng Xu; Lihua Zhu; Qiang Wu

2009-10-01T23:59:59.000Z

385

Estimation of methane flux offshore SW Taiwan and the influence of tectonics on gas hydrate accumulation  

E-Print Network (OSTI)

­510 INTRODUCTION Gas hydrates are naturally occurring solids, nonstoichio- metric clathrates, stable at relatively and in sedimentary strata of continen- tal deep sea areas and are typically composed of natural gas, mainly methane have suggested that methane concentra- tions play an important role in gas hydrate investigations. Very

Lin, Andrew Tien-Shun

386

Geophysical constraints on the surface distribution of authigenic carbonates across the Hydrate Ridge region,  

E-Print Network (OSTI)

car- bonate and gas hydrate buried by hemipelagic sediments. The similar nature of the category II nature of the conduits can only be speculated at this time. The important observation, however the shallow source of methane and water contained in subsurface and surface gas hydrates. The distribution

Goldfinger, Chris

387

STRUCTURE OF A CARBONATE/HYDRATE MOUND IN THE NORTHERN GULF OF MEXICO  

E-Print Network (OSTI)

STRUCTURE OF A CARBONATE/HYDRATE MOUND IN THE NORTHERN GULF OF MEXICO T. McGee1* , J. R. Woolsey1 of Mississippi Canyon Block 118 (MC118) This mound has been chosen by the Gulf of Mexico Hydrates Research

Gerstoft, Peter

388

Influence of Fly Ash and Fluorgypsum on Hydration Heat and Mortar ...  

Science Conference Proceedings (OSTI)

The results show that: the heat of hydration of cement hydration heat is lower than ... Analysis of Carbon Fiber Recovered from Optimized Processes of Commercial Scale Recycling Facilities Clayey Ceramic Incorporated with Powder from the Sintering Plant of a ... Production of Rock Wool from Ornamental Rock Wastes.

389

Comparison of kinetic and equilibrium reaction models insimulating gas hydrate behavior in porous media  

SciTech Connect

In this study we compare the use of kinetic and equilibriumreaction models in the simulation of gas (methane) hydrate behavior inporous media. Our objective is to evaluate through numerical simulationthe importance of employing kinetic versus equilibrium reaction modelsfor predicting the response of hydrate-bearing systems to externalstimuli, such as changes in pressure and temperature. Specifically, we(1) analyze and compare the responses simulated using both reactionmodels for natural gas production from hydrates in various settings andfor the case of depressurization in a hydrate-bearing core duringextraction; and (2) examine the sensitivity to factors such as initialhydrate saturation, hydrate reaction surface area, and numericaldiscretization. We find that for large-scale systems undergoing thermalstimulation and depressurization, the calculated responses for bothreaction models are remarkably similar, though some differences areobserved at early times. However, for modeling short-term processes, suchas the rapid recovery of a hydrate-bearing core, kinetic limitations canbe important, and neglecting them may lead to significantunder-prediction of recoverable hydrate. The use of the equilibriumreaction model often appears to be justified and preferred for simulatingthe behavior of gas hydrates, given that the computational demands forthe kinetic reaction model far exceed those for the equilibrium reactionmodel.

Kowalsky, Michael B.; Moridis, George J.

2006-11-29T23:59:59.000Z

390

Methane Hydrates R&D U S  

NLE Websites -- All DOE Office Websites (Extended Search)

the Power of Working Together the Power of Working Together Interagency Coordination on Methane Hydrates R&D U . S . D e p a r t m e n t o f E n e r g y * O f f i c e o f F o s s i l E n e r g y N a t i o n a l E n e r g y T e c h n o l o g y L a b o r a t o r y  Introduction Perhaps no areas of science are receiving more care- ful scrutiny and public discussion than those that deal with the interactions among earth, ocean, climate, and humanity. At the same time, our growing demands for energy are challenging us to find additional sources of clean fuel. The science of methane hydrates, a poten- tially vast source of natural gas that is part of a complex of dynamic natural systems, sits squarely in the center of these issues and the debates that surround them. Over the past two decades, scientists have been

391

Uptake of chloride and carbonate ions by calcium monosulfoaluminate hydrate  

Science Conference Proceedings (OSTI)

Decommissioning of old nuclear reactors may produce waste streams containing chlorides and carbonates, including radioactive {sup 36}Cl{sup -} and {sup 14}CO{sub 3}{sup 2-}. Their insolubilization by calcium monosulfoaluminate hydrate was investigated. Carbonates were readily depleted from the solution, giving at thermodynamic equilibrium monocarboaluminate, monocarboaluminate + calcite, or calcite only, depending on the initial ratio between the anion and calcium monosulfoaluminate hydrate. Chloride ions reacted more slowly and were precipitated as Kuzel's salt, Kuzel's and Friedel's salts, or Friedel's salt only. Rietveld refinement of X-Ray powder diffraction patterns was successfully used to quantify the phase distributions, which were compared to thermodynamic calculations. Moreover, analysing the lattice parameters of Kuzel's salt as a function of its chloride content showed the occurrence of a restricted solid solution towards the sulfate side with general formula 3CaO{center_dot}Al{sub 2}O{sub 3}{center_dot}xCaCl{sub 2}{center_dot}(1 - x)CaSO{sub 4}{center_dot}(12 - 2x){center_dot}H{sub 2}O (0.36 {<=} x {<=} 0.50).

Mesbah, Adel [Commissariat a l'Energie Atomique et aux Energies Alternatives, CEA DEN/DTCD/SPDE, F-30207 Bagnols sur Ceze (France); Clermont Universite, ENSCCF, Laboratoire des Materiaux Inorganiques, BP 10448, F-63000 Clermont-Ferrand (France); Cau-dit-Coumes, Celine, E-mail: celine.cau-dit-coumes@cea.fr [Commissariat a l'Energie Atomique et aux Energies Alternatives, CEA DEN/DTCD/SPDE, F-30207 Bagnols sur Ceze (France); Renaudin, Guillaume [Clermont Universite, ENSCCF, Laboratoire des Materiaux Inorganiques, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6002, F-63177 Aubiere (France); Frizon, Fabien [Commissariat a l'Energie Atomique et aux Energies Alternatives, CEA DEN/DTCD/SPDE, F-30207 Bagnols sur Ceze (France); Leroux, Fabrice [Clermont Universite, Universite Blaise Pascal, Laboratoire des Materiaux Inorganiques, BP 10448, F-63000 Clermont-Ferrand (France); CNRS, UMR 6002, F-63177 Aubiere (France)

2012-08-15T23:59:59.000Z

392

An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs In  

Open Energy Info (EERE)

Study Method For Exploration Of Gas Hydrate Reservoirs In Study Method For Exploration Of Gas Hydrate Reservoirs In Marine Areas Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs In Marine Areas Details Activities (0) Areas (0) Regions (0) Abstract: We propose an integrated study method for exploration of gas hydrate reservoirs in marine areas. This method combines analyses of geology, seismology, and geochemistry. First, geological analysis is made using data of material sources, structures, sediments, and geothermal regimes to determine the hydrocarbon-formation conditions of gas hydrate in marine areas. Then analyses of seismic attributes,such as BSR, AVO, and BZ as well as forward modeling are conducted to predict the potential

393

Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico May 14, 2013 - 10:00am Addthis USGS technicians Eric Moore and Jenny White deploy instruments at the start of a seismic survey to explore gas hydrates in the deepwater Gulf of Mexico from April to May 2013 | Photo courtesy of USGS USGS technicians Eric Moore and Jenny White deploy instruments at the start of a seismic survey to explore gas hydrates in the deepwater Gulf of Mexico from April to May 2013 | Photo courtesy of USGS Washington, DC - A joint-federal-agency 15-day research expedition in the northern Gulf of Mexico yielded innovative high-resolution seismic data and imagery that will help refine characterizations of large methane

394

Data from Innovative Methane Hydrate Test on Alaska's North Slope Now  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Data from Innovative Methane Hydrate Test on Alaska's North Slope Data from Innovative Methane Hydrate Test on Alaska's North Slope Now Available on NETL Website Data from Innovative Methane Hydrate Test on Alaska's North Slope Now Available on NETL Website March 11, 2013 - 10:07am Addthis DOE participated in gas hydrate field production trials in early 2012 in partnership with ConocoPhillips and the Japan Oil, Gas and Metals National Corp at the IÄ¡nik Sikumi (Inupiat for “Fire in the Ice”) test well, shown here, on the north slope of Alaska. Datasets from that field trial are now available to the public. DOE participated in gas hydrate field production trials in early 2012 in partnership with ConocoPhillips and the Japan Oil, Gas and Metals National Corp at the Iġnik Sikumi (Inupiat for "Fire in the Ice") test well,

395

Status of DOE Research Efforts in Gas Hydrates | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Status of DOE Research Efforts in Gas Hydrates Status of DOE Research Efforts in Gas Hydrates Status of DOE Research Efforts in Gas Hydrates July 30, 2009 - 1:38pm Addthis Statement of Dr. Ray Boswell, National Energy Technology Laboratory before the Committee on Natural Resources, Subcommittee on Energy and Mineral Resources, U.S. House of Representatives. Thank you, Mr. Chairman and Members of the Subcommittee. I appreciate this opportunity to provide testimony on the status of the United States Department of Energy's (DOE's) research efforts in naturally-occurring gas hydrates. INTRODUCTION Since 2000, DOE, through the Office of Fossil Energy's National Energy Technology Laboratory (NETL), has led the national research program in gas hydrates. The program is conducted through partnerships with private

396

The effect of gyrolite additive on the hydration properties of Portland cement  

SciTech Connect

The influence of gyrolite additive on the hydration properties of ordinary Portland cement was examined. It was found that the additive of synthetic gyrolite accelerates the early stage of hydration of OPC. This compound binds alkaline ions and serves as a nucleation site for the formation of hydration products (stage I). Later on, the crystal lattice of gyrolite becomes unstable and turns into C-S-H, with higher basicity (C/S {approx} 0.8). This recrystallization process is associated with the consumption of energy (the heat of reaction) and with a decrease in the rate of heat evolution of the second exothermic reaction (stage II). The experimental data and theoretical hypothesis were also confirmed by thermodynamic and the apparent kinetic parameters of the reaction rate of C{sub 3}S hydration calculations. The changes occur in the early stage of hydration of OPC samples and do not have a significant effect on the properties of cement stone.

Eisinas, A., E-mail: anatolijus.eisinas@ktu.lt; Baltakys, K.; Siauciunas, R.

2012-01-15T23:59:59.000Z

397

DOE Leads National Research Program in Gas Hydrates | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Leads National Research Program in Gas Hydrates Leads National Research Program in Gas Hydrates DOE Leads National Research Program in Gas Hydrates July 30, 2009 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy today told Congress the agency is leading a nationwide program in search of naturally occurring natural gas hydrates - a potentially significant storehouse of methane--with far reaching implications for the environment and the nation's future energy supplies. Read Dr. Boswell's testimony Dr. Ray Boswell, Senior Management and Technology Advisor at the Office of Fossil Energy's National Energy Technology Laboratory, testified before the House Natural Resources Subcommittee on Energy and Mineral Resources that the R&D program in gas hydrates is working to integrate and leverage

398

Simulations of Methane Hydrate Phenomena Over Geologic Timescales. Part I: Effect of Sediment Compaction Rates on Methans Hydrate and Free Gas Accumulation  

Science Conference Proceedings (OSTI)

The focus of this work is a model that describes migration and biogenic formation of methane under conditions representative of dynamic marine basins, and the conversion of soluble methane into either solid hydrate or exsolved gas. Incorporated into the overall model are an accurate phase equilibria model for seawater-methane, a methane source term based on biogenesis data, and a sediment compaction model based on porosity as a function of position, time, and the local volume fractions of hydrate solids and free gas. Simulations have shown that under some compaction scenarios, liquid overpressures reach the lithostatic limit due to permeability constraints, which can diminish the advective transfer of soluble methane within the porous sediment. As such, the formation of methane hydrate can be somewhat of a self-moderating process. The occurrence and magnitude of hydrate formation is directly tied to fundamental parameters such as the compaction/sedimentation rates, liquid advection rates, seafloor depth, geothermal gradient, etc. Results are shown for simulations covering 20 million years, wherein growth profiles for methane hydrate and free gas (neither exceeding 10 vol% at any location) are tracked within a vertical sediment column spanning over 3000 m. A case study is also presented for the Blake Ridge region (Ocean Drilling Program Leg 164, Sites 994, 995, and 997) based on simulations covering 6 Ma, wherein it is concluded that methane migration from compaction-driven advection may account for 15-30% of the total hydrate mass present in this region.

Gering, Kevin Leslie

2003-01-01T23:59:59.000Z

399

On the Nonpolar Hydration Free Energy of Proteins: Surface Area and Continuum Solvent Models for the Solute-Solvent  

E-Print Network (OSTI)

On the Nonpolar Hydration Free Energy of Proteins: Surface Area and Continuum Solvent Models solvent hydration free energy models are an important component of most modern computational methods aimed. The nonpolar component of the hydration free energy, consisting of a repulsive cavity term and an attractive

400

Trapping and migration of methane associated with the gas hydrate stability zone at the Blake Ridge Diapir  

E-Print Network (OSTI)

on lateral variations of the BGHS and BSR. This may be important for gas hydrate studies in regions of the manuscript. References Brown, K.M., 1996. The nature, distribution, and origin of gas hydrate in the ChileTrapping and migration of methane associated with the gas hydrate stability zone at the Blake Ridge

Taylor, Michael H.

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401

Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico  

SciTech Connect

A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

2009-07-15T23:59:59.000Z

402

Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico  

Science Conference Proceedings (OSTI)

In the late spring of 2008, the Chevron-led Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) expects to conduct an exploratory drilling and logging campaign to better understand gas hydrate-bearing sands in the deepwater Gulf of Mexico. The JIP Site Selection team selected three areas to test alternative geological models and geophysical interpretations supporting the existence of potential high gas hydrate saturations in reservoir-quality sands. The three sites are near existing drill holes which provide geological and geophysical constraints in Alaminos Canyon (AC) lease block 818, Green Canyon (GC) 955, and Walker Ridge (WR) 313. At the AC818 site, gas hydrate is interpreted to occur within the Oligocene Frio volcaniclastic sand at the crest of a fold that is shallow enough to be in the hydrate stability zone. Drilling at GC955 will sample a faulted, buried Pleistocene channel-levee system in an area characterized by seafloor fluid expulsion features, structural closure associated with uplifted salt, and abundant seismic evidence for upward migration of fluids and gas into the sand-rich parts of the sedimentary section. Drilling at WR313 targets ponded sheet sands and associated channel/levee deposits within a minibasin, making this a non-structural play. The potential for gas hydrate occurrence at WR313 is supported by shingled phase reversals consistent with the transition from gas-charged sand to overlying gas-hydrate saturated sand. Drilling locations have been selected at each site to 1) test geological methods and models used to infer the occurrence of gas hydrate in sand reservoirs in different settings in the northern Gulf of Mexico; 2) calibrate geophysical models used to detect gas hydrate sands, map reservoir thicknesses, and estimate the degree of gas hydrate saturation; and 3) delineate potential locations for subsequent JIP drilling and coring operations that will collect samples for comprehensive physical property, geochemical and other analyses.

Hutchinson, D.R. (USGS); Shelander, D. (Schlumberger, Houston, TX); Dai, J. (Schlumberger, Hoston, TX); McConnell, D. (AOA Geophysics, Inc., Houston, TX); Shedd, W. (Minerals Management Service); Frye, M. (Minerals Management Service); Ruppel, C. (USGS); Boswell, R.; Jones, E. (Chevron Energy Technology Corp., Houston, TX); Collett, T.S. (USGS); Rose, K.; Dugan, B. (Rice Univ., Houston, TX); Wood, W. (U.S. Naval Research Laboratory); Latham, T. (Chevron Energy Technology Corp., Houston, TX)

2008-07-01T23:59:59.000Z

403

SOUTHVIEWDR Center for Applied  

E-Print Network (OSTI)

/Geology Chemistry Biological Sciences Geology Lab Bookstore Reed Milledge Payne Memorial Hall SANFORD DR Center CAES Activity Center Visitors Center (Four Towers) Greenhouses Center for Applied Isotope Study

Hall, Daniel

404

Scientific Objectives of the Gulf of Mexico Gas Hydrate JIP Leg II Drilling  

Science Conference Proceedings (OSTI)

The Gulf of Mexico Methane Hydrate Joint Industry Project (JIP) has been performing research on marine gas hydrates since 2001 and is sponsored by both the JIP members and the U.S. Department of Energy. In 2005, the JIP drilled the Atwater Valley and Keathley Canyon exploration blocks in the Gulf of Mexico to acquire downhole logs and recover cores in silt- and clay-dominated sediments interpreted to contain gas hydrate based on analysis of existing 3-D seismic data prior to drilling. The new 2007-2009 phase of logging and coring, which is described in this paper, will concentrate on gas hydrate-bearing sands in the Alaminos Canyon, Green Canyon, and Walker Ridge protraction areas. Locations were selected to target higher permeability, coarser-grained lithologies (e.g., sands) that have the potential for hosting high saturations of gas hydrate and to assist the U.S. Minerals Management Service with its assessment of gas hydrate resources in the Gulf of Mexico. This paper discusses the scientific objectives for drilling during the upcoming campaign and presents the results from analyzing existing seismic and well log data as part of the site selection process. Alaminos Canyon 818 has the most complete data set of the selected blocks, with both seismic data and comprehensive downhole log data consistent with the occurrence of gas hydrate-bearing sands. Preliminary analyses suggest that the Frio sandstone just above the base of the gas hydrate stability zone may have up to 80% of the available sediment pore space occupied by gas hydrate. The proposed sites in the Green Canyon and Walker Ridge areas are also interpreted to have gas hydrate-bearing sands near the base of the gas hydrate stability zone, but the choice of specific drill sites is not yet complete. The Green Canyon site coincides with a 4-way closure within a Pleistocene sand unit in an area of strong gas flux just south of the Sigsbee Escarpment. The Walker Ridge site is characterized by a sand-prone sedimentary section that rises stratigraphically across the base of the gas hydrate stability zone and that has seismic indicators of gas hydrate. Copyright 2008, Offshore Technology Conference

Jones, E. (Chevron); Latham, T. (Chevron); McConnell, D. (AOA Geophysics); Frye, M. (Minerals Management Service); Hunt, J. (Minerals Management Service); Shedd, W. (Minerals Management Service); Shelander, D. (Schlumberger); Boswell, R.M. (NETL); Rose, K.K. (NETL); Ruppel, C. (USGS); Hutchinson, D. (USGS); Collett, T. (USGS); Dugan, B. (Rice University); Wood, W. (Naval Research Laboratory)

2008-05-01T23:59:59.000Z

405

Geologic interrelations relative to gas hydrates within the North Slope of Alaska: Task No. 6, Final report  

SciTech Connect

The five primary objectives of the US Geological Survey North Slope Gas Hydrate Project were to: (1) Determine possible geologic controls on the occurrence of gas hydrate; (2) locate and evaluate possible gas-hydrate-bearing reservoirs; (3) estimate the volume of gas within the hydrates; (4) develop a model for gas-hydrate formation; and (5) select a coring site for gas-hydrate sampling and analysis. Our studies of the North Slope of Alaska suggest that the zone in which gas hydrates are stable is controlled primarily by subsurface temperatures and gas chemistry. Other factors, such as pore-pressure variations, pore-fluid salinity, and reservior-rock grain size, appear to have little effect on gas hydrate stability on the North Slope. Data necessary to determine the limits of gas hydrate stability field are difficult to obtain. On the basis of mud-log gas chromatography, core data, and cuttings data, methane is the dominant species of gas in the near-surface (0--1500 m) sediment. Gas hydrates were identified in 34 wells utilizing well-log responses calibrated to the response of an interval in one well where gas hydrates were actually recovered in a core by an oil company. A possible scenario describing the origin of the interred gas hydrates on the North Slope involves the migration of thermogenic solution- and free-gas from deeper reservoirs upward along faults into the overlying sedimentary rocks. We have identified two (dedicated) core-hole sites, the Eileen and the South-End core-holes, at which there is a high probability of recovering a sample of gas hydrate. At the Eileen core-hole site, at least three stratigraphic units may contain gas hydrate. The South-End core-hole site provides an opportunity to study one specific rock unit that appears to contain both gas hydrate and oil. 100 refs., 72 figs., 24 tabs.

Collett, T.S.; Bird, K.J.; Kvenvolden, K.A.; Magoon, L.B.

1988-01-01T23:59:59.000Z

406

Detection of Gas Hydrates in Garden Banks and Keathley Canyon from Seismic Data  

E-Print Network (OSTI)

Gas hydrate is a potential energy source that has recently been the subject of much academic and industrial research. The search for deep-water gas hydrate involves many challenges that are especially apparent in the northwestern Gulf of Mexico, where the sub-seafloor is a complex structure of shallow salt diapirs and sheets underlying heavily deformed shallow sediments and surrounding diverse minibasins. Here, we consider the effect these structural factors have on gas hydrate occurrence in Garden Banks and Keathley Canyon blocks of the Gulf of Mexico. This was accomplished by first mapping the salt and shallow deformation structures throughout the region using a 2D grid of seismic reflection data. In addition, major deep-rooted faults and shallow-rooted faults were mapped throughout the area. A shallow sediment deformation map was generated that defined areas of significant faulting. We then quantified the thermal impact of shallow salt to better estimate the gas hydrate stability zone (GHSZ) thickness. The predicted base of the GHSZ was compared to the seismic data, which showed evidence for bottom simulating reflectors and gas chimneys. These BSRs and gas chimneys were used to ground-truth the calculated depth of the base of GHSZ. Finally, the calculated GHSZ thickness was used to estimate the volume of the gas hydrate reservoir in the area after determining the most reasonable gas hydrate concentrations in sediments within the GHSZ. An estimate of 5.5 trillion cubic meters of pure hydrate methane in Garden Banks and Keathley Canyon was obtained.

Murad, Idris

2009-05-01T23:59:59.000Z

407

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

SciTech Connect

Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

2011-06-01T23:59:59.000Z

408

Physical property changes in hydrate-bearingsediment due to depressurization and subsequent repressurization  

SciTech Connect

Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed at least briefly to non-in situ conditions during recovery. To examine effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes and speeds are compared between the original and depressurized/repressurized samples. X-ray computed tomography (CT) images track how the gas-hydrate distribution changes in the hydrate-cemented sands due to the depressurization/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.

Kneafsey, Timothy; Waite, W.F.; Kneafsey, T.J.; Winters, W.J.; Mason, D.H.

2008-06-01T23:59:59.000Z

409

Evaluation of the gas production economics of the gas hydrate cyclic thermal injection model  

SciTech Connect

The objective of the work performed under this directive is to assess whether gas hydrates could potentially be technically and economically recoverable. The technical potential and economics of recovering gas from a representative hydrate reservoir will be established using the cyclic thermal injection model, HYDMOD, appropriately modified for this effort, integrated with economics model for gas production on the North Slope of Alaska, and in the deep offshore Atlantic. The results from this effort are presented in this document. In Section 1, the engineering cost and financial analysis model used in performing the economic analysis of gas production from hydrates -- the Hydrates Gas Economics Model (HGEM) -- is described. Section 2 contains a users guide for HGEM. In Section 3, a preliminary economic assessment of the gas production economics of the gas hydrate cyclic thermal injection model is presented. Section 4 contains a summary critique of existing hydrate gas recovery models. Finally, Section 5 summarizes the model modification made to HYDMOD, the cyclic thermal injection model for hydrate gas recovery, in order to perform this analysis.

Kuuskraa, V.A.; Hammersheimb, E.; Sawyer, W.

1985-05-01T23:59:59.000Z

410

Applied Energy Programs  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Energy Programs Applied Energy Programs Applied Energy Programs Los Alamos is using its world-class scientific capabilities to enhance national energy security by developing energy sources with limited environmental impact and by improving the efficiency and reliability of the energy infrastructure. CONTACT US Acting Program Director Melissa Fox (505) 663-5538 Email Applied Energy Program Office serves as the hub connecting the Laboratory's scientific and technical resources to DOE sponsors, DoD programs, and to industry. The Applied Energy Program Office manages Los Alamos National Laboratory programs funded by the Department of Energy's (DOE's) Offices of Energy Efficiency/Renewable Energy, Electricity Delivery and Energy Reliability, and Fossil Energy. With energy use increasing across the nation and the

411

Guest disorder and high pressure behavior of argon hydrates  

SciTech Connect

The structure of argon hydrate was studied at ambient pressure and low temperature, and between 1.7 and 4.2 GPa at 295 K. This analysis produced a single Ar guest atom, positionally disordered off-center in the large cages of sII. Above 1.7 GPa Ar clathrate transformed to a mixture of a body-centered orthorhombic filled-ice phase, which can be viewed as a polytype of ice-Ih, and high pressure forms of pure ice. The guest disorder is further substantiated by analysis of the guest to host ratio in this high pressure filled-ice structure. The bulk modulus of Ar filled-ice found to be 11.7 {+-} 0.4 GPa.

Yang, L.; Tulk, C.A.; Klug, D.D.; Chakoumakos, B.C.; Ehm, L.; Molaison, J.J.; Parise, J.B.; Simonson, J.M. (NRCC); (SBU); (ORNL)

2010-03-29T23:59:59.000Z

412

Method and apparatus for recovering a gas from a gas hydrate located on the ocean floor  

DOE Patents (OSTI)

A method and apparatus for recovering a gas from a gas hydrate on the ocean floor includes a flexible cover, a plurality of steerable base members secured to the cover, and a steerable mining module. A suitable source for inflating the cover over the gas hydrate deposit is provided. The mining module, positioned on the gas hydrate deposit, is preferably connected to the cover by a control cable. A gas retrieval conduit or hose extends upwardly from the cover to be connected to a support ship on the ocean surface.

Wyatt, Douglas E. (Aiken, SC)

2001-01-01T23:59:59.000Z

413

Sulfur geochemistry of thermogenic gas hydrate and associated sediment from the Texas-Louisiana continental slope  

E-Print Network (OSTI)

Thermogenic gas hydrate and associated sediment were recovered from the northern Gulf of Mexico east of the Mississippi Canyon to investigate the interactions between gas hydrate and sedimentary sulfides. Sediment solid phase analyses included total reduced sulfide (TRS), acid volatile sulfide, and citrate-dithionate and HCl extractable iron. Pore-fluid measurements included []H?S, chloride, sulfate, ammonia and total dissolved inorganic carbon. Gas hydrate hydrogen sulfide and carbon dioxide content were measured using a new wet chemical technique. The []?S relative to Vienna Canyon Diablo troilite was determined for TRS and hydrate H?S. Extensive (>95%) reduction of pore-fluid sulfate occurred, resulting in exceptionally high []H?S concentrations (up to ~10 mM) and TRS concentrations (271 50 []mole/g). However, the mole fraction of H?S within the gas hydrate was too low (~0.3%) to significantly influence hydrate stability. This appears related to high reactive iron concentrations which average 256 66 []mol/g (pyrite iron + HCl extractable iron). These iron-rich sediments are thus capable of sequestering much of the generated sulfide in the form of TRS minerals, thereby making it unavailable for incorporation by gas hydrate. The TRS concentrations are about an order of magnitude greater than expected for sites at similar water depths in the northern Gulf of Mexico. Steep dissolved []H?S concentration gradients were observed both above and below the gas hydrate indicating diffusion of sulfide from the surrounding system into the gas hydrate. The gradients were used to estimate an incorporation rate of ~1 []mol H?S/yr-cm assuming molecular diffusion. TRS in close proximity to the hydrate was depleted in ?S by ~10[0/00] relative to TRS remote to the hydrate. The precise mechanism responsible for this relative depletion in ?S is not clear, but may prove an important geochemical indicator of sediments in which gas hydrate is or has been present. Studies at other sites will be necessary to confirm the generality of these observations.

Gledhill, Dwight Kuehl

2001-01-01T23:59:59.000Z

414

Categorical Exclusion Determinations: A1 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

August 31, 2012 August 31, 2012 CX-009304: Categorical Exclusion Determination Planning of a Marine Methane Hydrate Pressure Coring Program CX(s) Applied: A1, A9 Date: 08/31/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory August 30, 2012 CX-009313: Categorical Exclusion Determination Advanced Methane Hydrate Reservoir Modeling Using Rock Physics Techniques CX(s) Applied: A1, A9 Date: 08/30/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory August 29, 2012 CX-008916: Categorical Exclusion Determination Development of a Scientific Plan for a Hydrate-Focused Marine Drilling, Logging and Coring Program CX(s) Applied: A1, A9 Date: 08/29/2012 Location(s): Washington, DC Offices(s): National Energy Technology Laboratory August 29, 2012 CX-008912: Categorical Exclusion Determination

415

Essays in applied microeconomics  

E-Print Network (OSTI)

This dissertation consists of three chapters on topics in applied microeconomics. In the first chapter. I investigate whether voters are more likely to support additional spending on local public services when they perceive ...

Aron-Dine, Aviva

2012-01-01T23:59:59.000Z

416

Current State of Literature on CO2 Clathrate Hydrates -- Transport Related Issues  

NLE Websites -- All DOE Office Websites (Extended Search)

State of Literature on State of Literature on CO 2 Clathrate Hydrates Transport Related Issues Transport Related Issues Hydrate in suspension models Model (3) Model (3) Analysis Analysis Perforated plate models Model (2) Model (2) Analysis Analysis CO2 Permeable Plate models Model (2) Model (2) Analysis Analysis Transport model and analysis Wrong or no physical basis Not proven correct Correct and/or consistent CO 2 Transport Mechanisms in the literature: CO 2 H 2 O diffuse boundary layer Concentra tion r C o C infty C h1 C h2 C i C o : Conc. of pure liq CO 2 C h1 : Conc. of CO2 at full occupancy C h2 : Conc.of CO 2 in hydrate at interface that in equil with water saturated with CO 2 . C i : Conc. of CO 2 in liq. water adjoining hydrate C infty

417

NETL: National Methane Hydrates R&D Program- 2009 GOM JIP Expedition  

NLE Websites -- All DOE Office Websites (Extended Search)

The National Methane Hydrates R&D Program The National Methane Hydrates R&D Program 2009 Gulf of Mexico JIP - Leg II DOE-Sponsored Expedition Confirms Resource-Quality Gas Hydrate in the Gulf of Mexico Leg II Initial Scientific Reports Now Available Photo of semi-submersible Helix Project Background Participants Pre-Drilling Expedition Overview Drilling/Logging Sites The LWD Program Site Summaries Walker Ridge-Block 313 Green Canyon-Block 955 Alaminos Canyon block 21 and East Breaks block 992 JIP Website [external site] FITI article - Summer 2009 Leg II Initial Scientific Reports On May 6, 2009, the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL)in collaboration with the U.S. Geological Survey (USGS), the U.S. Minerals Management Service, an industry research consortium led by Chevron, and others completed a landmark gas hydrate

418

U.S. and Japan Complete Successful Field Trial of Methane Hydrate  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

U.S. and Japan Complete Successful Field Trial of Methane Hydrate U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies May 2, 2012 - 1:00pm Addthis Washington, DC - U.S. Energy Secretary Steven Chu announced today the completion of a successful, unprecedented test of technology in the North Slope of Alaska that was able to safely extract a steady flow of natural gas from methane hydrates - a vast, entirely untapped resource that holds enormous potential for U.S. economic and energy security. Building upon this initial, small-scale test, the Department is launching a new research effort to conduct a long-term production test in the Arctic as well as research to test additional technologies that could be used to locate,

419

Proceedings of the Guld of Mexico Hydrates R&D Planning Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Gulf of Mexico Hydrates R&D Planning Workshop Gulf of Mexico Hydrates R&D Planning Workshop Contents Disclaimer Participant Letter Executive Summary Papers and Presentations Welcome DOE National Hydrates Program Overview Industry Perspectives Panel Session Project Reviews Panel Session Appendices A - Breakout Session Products B - Participants List C - Poster Session Participants Proceedings of the Gulf of Mexico Hydrates R&D Planning Workshop Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

420

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

422

Further studies on hydration of alkynes by the PtCl4-CO catalyst  

E-Print Network (OSTI)

for the hydration of alkynes by the PtCl 4 -CO catalystalkynes by the PtCl 4 -CO catalyst in aqueous glyme aalkynes by the PtCl 4 -CO catalyst Osnat Israelsohn a , K.

Israelsohn, Osnat; Vollhardt, K. Peter C.; Blum, Jochanan

2002-01-01T23:59:59.000Z

423

Fluid dynamics of sinking carbon dioxide hydrate particle releases for direct ocean carbon sequestration  

E-Print Network (OSTI)

One strategy to remove anthropogenic CO? from the atmosphere to mitigate climate change is by direct ocean injection. Liquid CO? can react with seawater to form solid partially reacted CO? hydrate composite particles (pure ...

Chow, Aaron C. (Aaron Chunghin), 1978-

2008-01-01T23:59:59.000Z

424

Challenges, uncertainties and issues facing gas production from gas hydrate deposits  

E-Print Network (OSTI)

gas such as tight gas, shale gas, or coal bed methane gas tolocation. Development of shale oil and gas, tar sands, coalGas hydrates will undoubtedly also be present in shales,

Moridis, G.J.

2011-01-01T23:59:59.000Z

425

Polymer electrolyte membranes from fluorinated polyisoprene-block-sulfonated polystyrene: Structural evolution with hydration and heating  

Science Conference Proceedings (OSTI)

Small-angle neutron scattering (SANS) and ultra-small-angle X-ray scattering (USAXS) have been used to study the structural changes in fluorinated polyisoprene/sulfonated polystyrene (FISS) diblock copolymers as they evolved from the dry state to the water swollen state. A dilation of the nanometer-scale hydrophilic domains has been observed as hydration increased, with greater dilation occurring in the more highly sulfonated samples or upon hydration at higher temperatures. Furthermore, a decrease in the order in these phase separated structures is observed upon swelling. The glass transition temperatures of the fluorinated blocks have been observed to decrease upon hydration of these materials, and at the highest hydration levels, differential scanning calorimetry (DSC) has shown the presence of tightly bound water. A precipitous drop in the mechanical integrity of the 50% sulfonated materials is also observed upon exceeding the glass transition temperature (Tg), as measured by dynamic mechanical analysis (DMA).

Sodeye, Akinbode [Department of Polymer Science and Engineering, University of Massachusetts; Huang, Tianzi [University of Tennessee, Knoxville (UTK); Gido, Samuel [University of Massachusetts, Amherst; Mays, Jimmy [ORNL

2011-01-01T23:59:59.000Z

426

NETL: Methane Hydrates - DOE/NETL Projects - Planning of a Marine...  

NLE Websites -- All DOE Office Websites (Extended Search)

Marine Methane Hydrate Pressure Coring Program for the Walker Ridge and Green Canyon Areas of the Gulf of Mexico Last Reviewed 6192013 DE-FE0010175 Goal The primary goal of this...

427

Kinetics of Methane Hydrate Decomposition Studied via in Situ Low Temperature X-ray Powder Diffraction  

SciTech Connect

Gas hydrates are known to have a slowed decomposition rate at ambient pressure and temperatures below the melting point of ice termed self-preservation or anomalous preservation. As hydrate exothermically decomposes, gas is released and water of the clathrate cages transforms into ice. Two regions of slowed decomposition for methane hydrate, 180 200 K and 230 260 K, were observed, and the kinetics were studied by in situ low temperature x-ray powder diffraction. The kinetic constants for ice formation from methane hydrate were determined by the Avrami model within each region and activation energies, Ea, were determined by the Arrhenius plot. Ea determined from the data for 180 200 K was 42 kJ/mol and for 230 260 K was 22 kJ/mol. The higher Ea in the colder temperature range was attributed to a difference in the microstructure of ice between the two regions.

Everett, Susan M [ORNL; Rawn, Claudia J [ORNL; Keffer, David J. [University of Tennessee, Knoxville (UTK); Mull, Derek L [ORNL; Payzant, E Andrew [ORNL; Phelps, Tommy Joe [ORNL

2013-01-01T23:59:59.000Z

428

Molecular computations for reactions and phase transitions: applications to protein stabilization, hydrates and catalysis  

E-Print Network (OSTI)

In this work we have made significant contributions in three different areas of interest: therapeutic protein stabilization, thermodynamics of natural gas clathrate-hydrates, and zeolite catalysis. In all three fields, ...

Anderson, Brian J.

429

Phosphogypsum-fly ash cementitious binder -- Its hydration and strength development  

SciTech Connect

The paper deals with the formulation of a cementitious binder based on calcined phosphogypsum, flyash, hydrated lime and portland cement. Strength properties and hydration of the cementitious binder studies at room temperature and at 50 C in over 90% R.H are presented. It was found that the compressive strength of the cementitious binder was remarkably enhanced at 50 C than at 27 C. The hydration of the cementitious binder as studied by differential thermal analysis and scanning electron microscopy showed that the early age strength in the cementitious binder was due to the hardening of calcined gypsum and the hydration of portland cement while later age strength development was ascribed to the formation of ettringite and CSH.

Singh, M.; Garg, M. [Central Building Research Inst., Roorkee (India)] [Central Building Research Inst., Roorkee (India)

1995-05-01T23:59:59.000Z

430

Mechanisms Leading to Co-existence of Gas and Hydrate in Ocean...  

NLE Websites -- All DOE Office Websites (Extended Search)

Leading to Co-existence of Gas and Hydrate in Ocean Sediments Steven Bryant Dept. of Petroleum and Geosystems Engineering The University of Texas at Austin and Ruben Juanes Dept....

431

Development of a Numerical Simulator for Analyzing the Geomechanical Performance of Hydrate-Bearing Sediments  

E-Print Network (OSTI)

x = 0.5 m Z (m) HBS x = 10 m SHALE X (m) (d) (c) TIME (days)hydraulically confined by shales, depressurization is rapidadjacent upper and lower shales. As hydrate is progressively

Rutqvist, J.

2008-01-01T23:59:59.000Z

432

A computational study of the role of hydration in the assembly of collagen and other biofilaments  

Science Conference Proceedings (OSTI)

Hydration is known to be crucial in biomolecular interactions including ligand binding and self-assembly. In our earlier studies we have shown the key role of water in stabilizing the specific parts of the collagen triple helix depending on ...

Krishnakumar Mayuram Ravikumar / Alvin T. Yeh

2011-01-01T23:59:59.000Z

433

Feasibility of monitoring gas hydrate production with time-lapse VSP  

E-Print Network (OSTI)

We do not include the ice phase, since ice does not form ingas, liquid, ice or hydrate phases, existing individually orphase theory that considers the existence of two solids (grain and ice

Kowalsky, M.B.

2010-01-01T23:59:59.000Z

434

Challenges, uncertainties and issues facing gas production from gas hydrate deposits  

E-Print Network (OSTI)

of Gas Price ($/Mscf) for Offshore Gas Hydrate StudyProceedings of the 2010 Offshore Technology Conference, 3-6Proceedings of the 2010 Offshore Technology Conference, 3-6

Moridis, G.J.

2011-01-01T23:59:59.000Z

435

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

436

CONTENTS BOEM Releases Assessment of In-Place Gas Hydrate Resources  

NLE Websites -- All DOE Office Websites (Extended Search)

BOEM Releases Assessment of BOEM Releases Assessment of In-Place Gas Hydrate Resources of the Lower 48 United States Outer Continental Shelf ..............1 Re-examination of Seep Activity at the Blake Ridge Diapir ............6 Field Data from 2011/2012 ConocoPhillips-JOGMEC-DOE Iġnik Sikumi Gas Hydrate Field Trial Now Available .......................9 Announcements .......................11 * Norwegian Center of Excellence to Receive Ten Years of Arctic Research Funding * Release of Mallik 2007-2008 Results * Goldschmidt Conference * 2012 Methane Hydrate Research Fellowship Awarded to Jeffrey James Marlow Spotlight on Research........... 16 Bjørn Kvamme CONTACT Ray Boswell Technology Manager-Methane Hydrates, Strategic Center for Natural Gas & Oil 304-285-4541 ray.boswell@netl.doe.gov

437

NETL: Methane Hydrates - DOE/NETL Projects - Controls On Methane Expulsion  

NLE Websites -- All DOE Office Websites (Extended Search)

Controls On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 12/24/2013 Controls On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 12/24/2013 DE-FE0010406 Goal The project goal is to predict, given characteristic climate-induced temperature change, the conditions under which gas will be expelled from existing accumulations of gas hydrate into the shallow ocean or directly to the atmosphere. When those conditions are met, the fraction of the gas accumulation that escapes and the rate of escape shall be quantified. The predictions shall be applicable in Arctic regions and in gas hydrate systems at the updip limit of the stability zone on continental margins. The behavior shall be explored in response to both longer term changes in sea level (e.g., twenty-thousand years) and shorter term due to atmospheric

438

Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico  

NLE Websites -- All DOE Office Websites (Extended Search)

4, 2013 Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico USGS technicians Eric Moore and Jenny White deploy instruments at the start of a seismic survey to explore...

439

The effect of reservoir heterogeneity on gas production from hydrate accumulations in the permafrost  

SciTech Connect

The quantity of hydrocarbon gases trapped in natural hydrate accumulations is enormous, leading to significant interest in the evaluation of their potential as an energy source. Large volumes of gas can be readily produced at high rates for long times from methane hydrate accumulations in the permafrost by means of depressurization-induced dissociation combined with conventional technologies and horizontal or vertical well configurations. Initial studies on the possibility of natural gas production from permafrost hydrates assumed homogeneity in intrinsic reservoir properties and in the initial condition of the hydrate-bearing layers (either due to the coarseness of the model or due to simplifications in the definition of the system). These results showed great promise for gas recovery from Class 1, 2, and 3 systems in the permafrost. This work examines the consequences of inevitable heterogeneity in intrinsic properties, such as in the porosity of the hydrate-bearing formation, or heterogeneity in the initial state of hydrate saturation. Heterogeneous configurations are generated through multiple methods: (1) through defining heterogeneous layers via existing well-log data, (2) through randomized initialization of reservoir properties and initial conditions, and (3) through the use of geostatistical methods to create heterogeneous fields that extrapolate from the limited data available from cores and well-log data. These extrapolations use available information and established geophysical methods to capture a range of deposit properties and hydrate configurations. The results show that some forms of heterogeneity, such as horizontal stratification, can assist in production of hydrate-derived gas. However, more heterogeneous structures can lead to complex physical behavior within the deposit and near the wellbore that may obstruct the flow of fluids to the well, necessitating revised production strategies. The need for fine discretization is crucial in all cases to capture dynamic behavior during production.

Reagan, M. T.; Kowalsky, M B.; Moridis, G. J.; Silpngarmlert, S.

2010-05-01T23:59:59.000Z

440

Natural gas hydrates of the Prudhoe Bay and Kuparuk River area, North Slope, Alaska  

SciTech Connect

Gas hydrates are crystalline substances composed of water and gas, mainly methane, in which a solid-water lattice accommodates gas molecules in a cage-like structure, or clathrate. These substances commonly have been regarded as a potential unconventional source of natural gas because of their enormous gas-storage capacity. Significant quantities of naturally occurring gas hydrates have been detected in many regions of the Arctic, including Siberia, the Mackenzie River Delta, and the North Slope of Alaska. On the North Slope, the methane-hydrate stability zone is a really extensive beneath most of the coastal plain province and has thicknesses greater than 1000 m in the Prudhoe Bay area. Gas hydrates have been inferred to occur in 50 North Slope exploratory and production wells on the basis of well-log responses calibrated to the response of an interval in a well where gas hydrates were recovered in a core by ARCO and Exxon. Most North Slope gas hydrates occur in six laterally continuous lower Tertiary sandstones and conglomerates; all these gas hydrates are geographically restricted to the area overlying the eastern part of the Kuparuk River oil field and the western part of the Prudhoe Bay oil field. The volume of gas within these gas hydrates is estimated to be about 1.0 [times] 10[sup 12] to 1.2 [times] 10[sup 12] m[sup 3] (37 to 44 tcf), or about twice the volume of conventional gas in the Prudhoe Bay field. 52 refs., 13 figs., 2 tabs.

Collett, T.S. (Geological Survey, Denver, CO (United States))

1993-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

A Laboratory Study of Hydrated Lime Properties in Dilute Phase Conveyance  

Science Conference Proceedings (OSTI)

Recent regulatory actions are reducing allowable emissions of sulfur trioxide (SO3) from coal-fired power plants. Therefore, the need to economically and reliably remove SO3 from flue gas streams is taking on additional urgency. Three sorbents are commonly used for SO3 removal151hydrated lime, trisodium hydrogendicarbonate dihydrate (trona), and sodium bisulfate. Hydrated lime has been shown to be an economical choice; however, dilute phase conveyance from storage hoppers to duct injection lances has bee...

2010-12-31T23:59:59.000Z

442

Applied Mathematics | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Mathematics Applied Mathematics Our work in applied mathematics ranges from algorithm design, to development of software tools and technology, to advanced simulations in...

443

Applied Science/Techniques  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Science/Techniques Applied Science/Techniques Applied Science/Techniques Print The ALS is an excellent incubator of new scientific techniques and instrumentation. Many of the technical advances that make the ALS a world-class soft x-ray facility are developed at the ALS itself. The optical components in use at the ALS-mirrors and lenses optimized for x-ray wavelengths-require incredibly high-precision surfaces and patterns (often formed through extreme ultraviolet lithography at the ALS) and must undergo rigorous calibration and testing provided by beamlines and equipment from the ALS's Optical Metrology Lab and Berkeley Lab's Center for X-Ray Optics. New and/or continuously improved experimental techniques are also a crucial element of a thriving scientific facility. At the ALS, examples of such "technique" highlights include developments in lensless imaging, soft x-ray tomography, high-throughput protein analysis, and high-power coherent terahertz radiation.

444

Hydration characteristics of tricalcium aluminate phase in mixes containing {beta}-hemihydate and phosphogypsum  

SciTech Connect

The tricalcium aluminte phase was prepared from pure chemicals on a laboratory scale. Five mixes were formulated from the prepared C{sub 3}A phase, {beta}-hemihydate, phosphogypsum, calcium hydroxide and quartz. Different mixes were hydrated at various time intervals, namely, 6, 24, 72 and 168 h. The kinetics of hydration was measured from chemically combined water and combined lime contents. The phase compositions and microstructures of the hydrated products were studied by X-ray diffraction (XRD), differential thermal analysis (DTA)/TG, scanning electron microscopy (SEM) techniques and FT-IR spectroscopy. This work aimed to study the effect of partial to full substitution of phosphogypsum by {beta}-hemihydate on the hydration characteristics and microstructures of tricalcium aluminte phase. The results showed that the combined lime slightly increases with the increase of amounts of phosphogypsum. The XRD patterns showed the increase in the intensities of monosulphate and different forms of calcium aluminate (C{sub 4}AH{sub 13} and C{sub 4}AH{sub 19}) with phosphogypsum content. Ettringite is less stable than monosulphoaluminate, so it transformed into monosulpho-aluminate after 24 h, which persisted up to 168 h. The mechanism of the hydration process of C{sub 3}A phase in the presence of phosphogypsum proceeds in a similar path as with {beta}-hemihydate. Phosphogypsum reacts with C{sub 3}A in the presence of Ca(OH){sub 2} forming sulphoaluminate hydrates, which are responsible for setting regulation in cementitious system.

Radwan, M.M. [National Research Center, Dokki, Cairo (Egypt); Heikal, M. [Chemistry Department, Faculty of Science, Zagazig University, Benha Branch, Benha (Egypt)]. E-mail: ayaheikal@hotmail.com

2005-08-01T23:59:59.000Z

445

GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS  

SciTech Connect

The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

James Sorensen; Jaroslav Solc; Bethany Bolles

2000-07-01T23:59:59.000Z

446

Gas Hydrate Characterization in the GoM using Marine EM Methods  

SciTech Connect

In spite of the importance of gas hydrate as a low-carbon fuel, a possible contributor to rapid climate change, and a significant natural hazard, our current understanding about the amount and distribution of submarine gas hydrate is somewhat poor; estimates of total volume vary by at least an order of magnitude, and commercially useful concentrations of hydrate have remained an elusive target. This is largely because conventional geophysical tools have intrinsic limitations in their ability to quantitatively image hydrate. It has long been known from well logs that gas hydrate is resistive compared to the host sediments, and electrical and electromagnetic methods have been proposed and occasionally used to image hydrates. This project seeks to expand our capabilities to use electromagnetic methods to explore for gas hydrate in the marine environment. An important basic science aspect of our work was to quantify the resistivity of pure gas hydrate as a function of temperature at seafloor pressures. We designed, constructed, and tested a highpressure cell in which hydrate could be synthesized and then subjected to electrical conductivity measurements. Impedance spectroscopy at frequencies between 20 Hz and 2 MHz was used to separate the effect of the blocking electrodes from the intrinsic conductivity of the hydrate. We obtained very reproducible results that showed that pure methane hydrate was several times more resistive than the water ice that seeded the synthesis, 20,000 {Ohm}m at 0{degrees}#14;C, and that the activation energy is 30.6 kJ/mol over the temperature range of -15 to 15{degrees}#14;C. Adding silica sand to the hydrate, however, showed that the addition of the extra phase caused the conductivity of the assemblage to increase in a counterintuitive way. The fact that the increased conductivity collapsed after a percolation threshold was reached, and that the addition of glass beads does not produce a similar increase in conductivity, together suggest that while the surface of the gas hydrate grains are not intrinsically conductive, the presence of sand does increase their conductivity. In the field component of this project, we carried out an 18day cruise on the R.V. Roger Revelle in the Gulf of Mexico from 7th-??26th October 2008 to collect controlled-source electromagnetic (CSEM) data over four hydrate prospects; blocks AC 818, WR 313, GC 955, and MC 118. During these surveys we deployed 30 ocean bottom electromagnetic (OBEM) recorders a total of 94 times at four survey areas and towed the Scripps Undersea Electromagnetic Source Instrument (SUESI) a total of 103 hours. SUESI transmission was 200 A on a 50 m dipole antenna at heights of 70-100 m above the seafloor. We also towed a neutrally buoyant 3-axis electric field recorder behind the SUESI antenna at a constant offset of 300 m. The use of a towed receiver that is "flown" above the seafloor allowed us to operate in areas where seafloor infrastructure such as wellheads, pipelines, and installed scientific equipment existed. We reduced the data to apparent resistivity psuedosections. The most compelling results come from the hydrate observatory at MC 118, where a localized resistivity anomaly is clearly identified under the southeast crater in an otherwise uniform 1 {Ohm}m background. The data from MC 118 also show that authigenic carbonate does not necessarily express itself as a confounding resistor, as was feared at the start of this project. While the results from the other prospects are much more complicated, the data are well correlated with known geology, and line to line agreement is good. Although these data are not amenable to 1D inversion as was initially hoped, we expect to use a newly developed 2D CSEM inversion code to continue to get useful information from this rich data set.

Steven Constable

2012-03-31T23:59:59.000Z

447

In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution  

Science Conference Proceedings (OSTI)

The primary accomplishment of the JOI Cooperative Agreement with DOE/NETL in this quarter was the deployment of tools and measurement systems on ODP Leg 204 to study hydrate deposits on Hydrate Ridge, offshore Oregon from July through September, 2002. During Leg 204, we cored and logged 9 sites on the Oregon continental margin to determine the distribution and concentration of gas hydrates in an accretionary ridge and adjacent slope basin, investigate the mechanisms that transport methane and other gases into the gas hydrate stability zone (GHSZ), and obtain constraints on physical properties of hydrates in situ. A 3D seismic survey conducted in 2000 provided images of potential subsurface fluid conduits and indicated the position of the GHSZ throughout the survey region. After coring the first site, we acquired Logging-While-Drilling (LWD) data at all but one site to provide an overview of downhole physical properties. The LWD data confirmed the general position of key seismic stratigraphic horizons and yielded an initial estimate of hydrate concentration through the proxy of in situ electrical resistivity. These records proved to be of great value in planning subsequent coring. The second new hydrate proxy to be tested was infrared thermal imaging of cores on the catwalk as rapidly as possible after retrieval. The thermal images were used to identify hydrate samples and to map estimate the distribution and texture of hydrate within the cores. Geochemical analyses of interstitial waters and of headspace and void gases provide additional information on the distribution and concentration of hydrate within the stability zone, the origin and pathway of fluids into and through the GHSZ, and the rates at which the process of gas hydrate formation is occurring. Bio- and lithostratigraphic description of cores, measurement of physical properties, and in situ pressure core sampling and thermal measurements complement the data set, providing ground-truth tests of inferred physical and sedimentological properties. Among the most interesting preliminary results are: (1) the discovery that gas hydrates are distributed through a broad depth range within the GHSZ and that different physical and chemical proxies for hydrate distribution and concentration give generally consistent results; (2) evidence for the importance of sediment properties for controlling the migration of fluids in the accretionary complex; (3) geochemical indications that the gas hydrate system at Hydrate Ridge contains significant concentrations of higher order hydrocarbons and that fractionation and mixing signals will provide important constraints on gas hydrate dynamics; and (4) the discovery of very high chlorinity values that extend for at least 10 mbsf near the summit, indicating that hydrate formation here must be very rapid.

Frank Rack; Gerhard Bohrmann; Anne Trehu; Michael Storms; Derryl Schroeder; ODP Leg 204 Shipboard Scientific Party

2002-09-30T23:59:59.000Z

448

Structure Stability of Methane Hydrate at High Pressures  

SciTech Connect

The structural stability of methane hydrate under pressure at room temperature was examined by both in-situ single-crystal and powder X-ray diffraction techniques on samples with structure types I, II, and H in diamond-anvil cells. The diffraction data for types II (sII) and H (sH) were refined to the known structures with space groups Fd3m and P6{sub 3}/mmc, respectively. Upon compression, sI methanehydrate transforms to the sII phase at 120 MPa, and then to the sH phase at 600 MPa. The sII methanehydrate was found to coexist locally with sI phase up to 500 MPa and with sH phase up to 600 MPa. The pure sH structure was found to be stable between 600 and 900 MPa. Methanehydrate decomposes at pressures above 3 GPa to form methane with the orientationally disordered Fm3mstructure and ice VII (Pn3m). The results highlight the role of guest (CH{sub 4})-host (H{sub 2}O) interactions in the stabilization of the hydratestructures under pressure.

J Shu; X Chen; I Chou; W Yang; J Hu; R Hemley; K Mao

2011-12-31T23:59:59.000Z

449

The Research Path to Determining the Natural Gas Supply Potential of Marine Gas Hydrates  

Science Conference Proceedings (OSTI)

A primary goal of the U.S. National Interagency Gas Hydrates R&D program is to determine the natural gas production potential of marine gas hydrates. In pursuing this goal, four primary areas of effort are being conducted in parallel. First, are wide-ranging basic scientific investigations in both the laboratory and in the field designed to advance the understanding of the nature and behavior of gas hydrate bearing sediments (GHBS). This multi-disciplinary work has wide-ranging direct applications to resource recovery, including assisting the development of exploration and production technologies through better rock physics models for GHBS and also in providing key data for numerical simulations of productivity, reservoir geomechanical response, and other phenomena. In addition, fundamental science efforts are essential to developing a fuller understanding of the role gas hydrates play in the natural environment and the potential environmental implications of gas hydrate production, a critical precursor to commercial extraction. A second area of effort is the confirmation of resource presence and viability via a series of multi-well marine drilling expeditions. The collection of data in the field is essential to further clarifying what proportion of the likely immense in-place marine gas hydrate resource exists in accumulations of sufficient quality to represent potential commercial production prospects. A third research focus area is the integration of geologic, geophysical, and geochemical field data into an effective suite of exploration tools that can support the delineation and characterization commercial gas hydrate prospects prior to drilling. The fourth primary research focus is the development and testing of well-based extraction technologies (including drilling, completion, stimulation and production) that can safely deliver commercial gas production rates from gas hydrate reservoirs in a variety of settings. Initial efforts will take advantage of the relatively favorable economics of conducting production tests in Arctic gas-hydrate bearing sandstones with the intent of translating the knowledge gained to later testing in marine sandstone reservoirs. The full and concurrent pusuit of each of these research topics is essential to the determining the future production potential of naturally-occuring gas hydrates.

Boswell, R.M.; Rose, K.K.; Baker, R.C.

2008-06-01T23:59:59.000Z

450

Formation of Hydrates from Single-Phase Aqueous Solutions and Implications for Oceanic Sequestration of CO2  

NLE Websites -- All DOE Office Websites (Extended Search)

Formation of Hydrates from Single-Phase Aqueous Solutions Formation of Hydrates from Single-Phase Aqueous Solutions and Implications for Oceanic Sequestration of CO 2 . G. Holder (holder@engrng.pitt.edu) 412-624-9809 L. Mokka (lakshmi.mokka@netl.doe.gov) 412-386-6019 Department of Chemical and Petroleum Engineering University of Pittsburgh Pittsburgh, PA 15261 R. Warzinski* (robert.warzinski@netl.doe.gov) 412-386-5863 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 10940 Pittsburgh, PA 15236-0940 Introduction a Gas hydrates are crystalline solids formed from mixtures of water and low molecular weight compounds, referred to as hydrate formers, that typically are gases at ambient conditions (1). Generally, hydrates are formed in the laboratory from two-phase systems by contacting a hydrate former or formers in the gas or liquid phase with liquid water and increasing the pressure until

451

Applied Science/Techniques  

NLE Websites -- All DOE Office Websites (Extended Search)

Applied Science/Techniques Print Applied Science/Techniques Print The ALS is an excellent incubator of new scientific techniques and instrumentation. Many of the technical advances that make the ALS a world-class soft x-ray facility are developed at the ALS itself. The optical components in use at the ALS-mirrors and lenses optimized for x-ray wavelengths-require incredibly high-precision surfaces and patterns (often formed through extreme ultraviolet lithography at the ALS) and must undergo rigorous calibration and testing provided by beamlines and equipment from the ALS's Optical Metrology Lab and Berkeley Lab's Center for X-Ray Optics. New and/or continuously improved experimental techniques are also a crucial element of a thriving scientific facility. At the ALS, examples of such "technique" highlights include developments in lensless imaging, soft x-ray tomography, high-throughput protein analysis, and high-power coherent terahertz radiation.

452

Methane Hydrates: Major Energy Source for the Future or Wishful Thinking?  

SciTech Connect

Methane hydrates are methane bearing, ice-like materials that occur in abundance in permafrost areas such as on the North Slope of Alaska and Canada and as well as in offshore continental margin environments throughout the world including the Gulf of Mexico and the East and West Coasts of the United States. Methane hydrate accumulations in the United States are currently estimated to be about 200,000 Tcf, which is enormous when compared to the conventional recoverable resource estimate of 2300 Tcf. On a worldwide basis, the estimate is 700,000 Tcf or about two times the total carbon in coal, oil and conventional gas in the world. The enormous size of this resource, if producible to any degree, has significant implications for U.S. and worldwide clean energy supplies and global environmental issues. Historically the petroleum industry's interests in methane hydrates have primarily been related to safety issues such as wellbore stability while drilling, seafloor stability, platform subsidence, and pipeline plugging. Many questions remain to be answered to determine if any of this potential energy resource is technically and economically viable to produce. Major technical hurdles include: 1) methods to find, characterize, and evaluate the resource; 2) technology to safely and economically produce natural gas from methane hydrate deposits; and 3) safety and seafloor stability issues related to drilling through gas hydrate accumulations to produce conventional oil and gas. The petroleum engineering profession currently deals with gas hydrates in drilling and production operations and will be key to solving the technical and economic problems that must be overcome for methane hydrates to be part of the future energy mix in the world.

Thomas, Charles Phillip

2001-09-01T23:59:59.000Z

453

Development of an electrical resistivity cone for the detection of gas hydrates in marine sediments  

E-Print Network (OSTI)

Natural gas hydrates are formed when, under certain pressure and temperature conditions, gas molecules become encaged by hydrogenbonded oxygen atoms, forming a solid, ice-like crystalline substance. They have been found all over the world in both onshore and offshore environments, as well as in permafrost and tropical regions. The presence of natural gas hydrates in marine sediments are of concern to geotechnical engineers for several reasons, including: (1) their effect on the load bearing properties of ocean sediments, and (2) the effect that their dissociation has on the engineering properties of ocean sediments. The recovery of intact, in-situ samples of gas hydrates can be difficult due to their dependence on pressure and temperature conditions. The development of an electrical resistivity cone for the detection of gas hydrates in marine sediments would be ideal because: (1) there is a dramatic contrast between the electrical properties of gas hydrates and ocean sediments; (2) the resistivity module could be incorporated with standard cone penetrometer testing equipment; and (3) it could allow the in-situ detection of gas hydrates without dramatically affecting the surrounding temperature and pressure conditions. The objectives of this study were to design, fabricate and test an electrical resistivity cone using a two-electrode and four-electrode configuration. The laboratory testing program consisted of pushing the cone through a three-layer soil profile in which the central layer (target layer) consisted of simulated gas hydrates. The target layer thickness varied from 1 to 6 inches (2.5 to 15 cm) and the "hydrate" content varied from 10% to 100% by volume. The objective was to determine the effectiveness of the cone for use in the detection of thin resistive layers and randomly dispersed resistive nodules. The laboratory test results indicated that the four-electrode configuration may be more appropriate for the detection of both thin resistive layers and random resistive nodules. Layers as thin as 1 inch (2.5 cm) and containing as little as 10% "hydrate" nodules were successfully detected using this configuration.

McClelland, Martha Ann

1994-01-01T23:59:59.000Z

454

Cage occupancies in the high pressure structure H methane hydrate: A neutron diffraction study  

SciTech Connect

A neutron diffraction study was performed on the CD{sub 4}: D{sub 2}O structure H clathrate hydrate to refine its CD{sub 4} fractional cage occupancies. Samples of ice VII and hexagonal (sH) methane hydrate were produced in a Paris-Edinburgh press and in situ neutron diffraction data collected. The data were analyzed with the Rietveld method and yielded average cage occupancies of 3.1 CD{sub 4} molecules in the large 20-hedron (5{sup 12}6{sup 8}) cages of the hydrate unit cell. Each of the pentagonal dodecahedron (5{sup 12}) and 12-hedron (4{sup 3}5{sup 6}6{sup 3}) cages in the sH unit cell are occupied with on average 0.89 and 0.90 CD{sub 4} molecules, respectively. This experiment avoided the co-formation of Ice VI and sH hydrate, this mixture is more difficult to analyze due to the proclivity of ice VI to form highly textured crystals, and overlapping Bragg peaks of the two phases. These results provide essential information for the refinement of intermolecular potential parameters for the water methane hydrophobic interaction in clathrate hydrates and related dense structures.

Tulk, Christopher A [ORNL; Klug, Dennis D [National Research Council of Canada; Moreira Dos Santos, Antonio F [ORNL; Karotsis, Georgios [ORNL; Guthrie, Malcolm [Carnegie Institution of Washington; Molaison, Jamie J [ORNL; Pradhan, Neelam [ORNL

2012-01-01T23:59:59.000Z

455

Mechanisms Leading to Co-Existence of Gas Hydrate in Ocean Sediments  

Science Conference Proceedings (OSTI)

In this project we have sought to explain the co-existence of gas and hydrate phases in sediments within the gas hydrate stability zone. We have focused on the gas/brine interface at the scale of individual grains in the sediment. The capillary forces associated with a gas/brine interface play a dominant role in many processes that occur in the pores of sediments and sedimentary rocks. The mechanical forces associated with the same interface can lead to fracture initiation and propagation in hydrate-bearing sediments. Thus the unifying theme of the research reported here is that pore scale phenomena are key to understanding large scale phenomena in hydrate-bearing sediments whenever a free gas phase is present. Our analysis of pore-scale phenomena in this project has delineated three regimes that govern processes in which the gas phase pressure is increasing: fracturing, capillary fingering and viscous fingering. These regimes are characterized by different morphology of the region invaded by the gas. On the other hand when the gas phase pressure is decreasing, the corresponding regimes are capillary fingering and compaction. In this project, we studied all these regimes except compaction. Many processes of interest in hydrate-bearing sediments can be better understood when placed in the context of the appropriate regime. For example, hydrate formation in sub-permafrost sediments falls in the capillary fingering regime, whereas gas invasion into ocean sediments is likely to fall into the fracturing regime. Our research provides insight into the mechanisms by which gas reservoirs are converted to hydrate as the base of the gas hydrate stability zone descends through the reservoir. If the reservoir was no longer being charged, then variation in grain size distribution within the reservoir explain hydrate saturation profiles such as that at Mt. Elbert, where sand-rich intervals containing little hydrate are interspersed between intervals containing large hydrate saturations. Large volumes (of order one pore volume) of gaseous and aqueous phases must be transported into the gas hydrate stability zone. The driver for this transport is the pressure sink induced by a reduction in occupied pore volume that accompanies the formation of hydrate from gas and water. Pore-scale imbibition models and bed-scale multiphase flow models indicate that the rate-limiting step in converting gas to hydrate is the supply of water to the hydrate stability zone. Moreover, the water supply rate is controlled by capillarity-driven flux for conditions typical of the Alaska North Slope. A meter-scale laboratory experiment confirms that significant volumes of fluid phases move into the hydrate stability zone and that capillarity is essential for the water flux. The model shows that without capillarity-driven flux, large saturations of hydrate cannot form. The observations of thick zones of large saturation at Mallik and Mt Elbert thus suggest that the primary control on these systems is the rate of transport of gaseous and aqueous phases, driven by the pressure sink at the base of the gas hydrate stability zone. A key finding of our project is the elucidation of capillary fracturing as a dominant gas transport mechanism in low-permeability media. We initially investigate this phenomenon by means of grain-scale simulations in which we extended a discrete element mechanics code (PFC, by Itasca) to incorporate the dynamics of first single-phase and then multiphase flow. A reductionist model on a square lattice allows us to determine some of the fundamental dependencies of the mode of gas invasion (capillary fingering, viscous fingering, and fracturing) on the parameters of the system. We then show that the morphology of the gas-invaded region exerts a fundamental control on the fabric of methane hydrate formation, and on the overpressures caused by methane hydrate dissociation. We demonstrate the existence of the different invasion regimes by means of controlled laboratory experiments in a radial cell. We collapse the behavior in the form of a phas

Bryant, Steven; Juanes, Ruben

2011-12-31T23:59:59.000Z

456

Mechanisms Leading to Co-Existence of Gas Hydrate in Ocean Sediments  

SciTech Connect

In this project we have sought to explain the co-existence of gas and hydrate phases in sediments within the gas hydrate stability zone. We have focused on the gas/brine interface at the scale of individual grains in the sediment. The capillary forces associated with a gas/brine interface play a dominant role in many processes that occur in the pores of sediments and sedimentary rocks. The mechanical forces associated with the same interface can lead to fracture initiation and propagation in hydrate-bearing sediments. Thus the unifying theme of the research reported here is that pore scale phenomena are key to understanding large scale phenomena in hydrate-bearing sediments whenever a free gas phase is present. Our analysis of pore-scale phenomena in this project has delineated three regimes that govern processes in which the gas phase pressure is increasing: fracturing, capillary fingering and viscous fingering. These regimes are characterized by different morphology of the region invaded by the gas. On the other hand when the gas phase pressure is decreasing, the corresponding regimes are capillary fingering and compaction. In this project, we studied all these regimes except compaction. Many processes of interest in hydrate-bearing sediments can be better understood when placed in the context of the appropriate regime. For example, hydrate formation in sub-permafrost sediments falls in the capillary fingering regime, whereas gas invasion into ocean sediments is likely to fall into the fracturing regime. Our research provides insight into the mechanisms by which gas reservoirs are converted to hydrate as the base of the gas hydrate stability zone descends through the reservoir. If the reservoir was no longer being charged, then variation in grain size distribution within the reservoir explain hydrate saturation profiles such as that at Mt. Elbert, where sand-rich intervals containing little hydrate are interspersed between