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We encourage you to perform a real-time search of NLEBeta
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1

NETL: Methane Hydrates - Hydrate Newsletter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Hydrate R&D Program Newsletter Methane Hydrate R&D Program Newsletter An image of a hydrate burning overlayed with the Newsletter Title: Fire in the Ice The methane hydrate newsletter, Fire in the Ice, is a bi-annual publication highlighting the latest developments in international gas hydrates R&D. Fire in the Ice promotes the exchange of information amoung those involved in gas hydrates research and development, and also recognizes the efforts of a hydrate researcher in each issue. The newsletter now reaches nearly 1300 scientists and other interested individuals in sixteen countries. To subscribe electronically to Fire in the Ice please send an email to karl.lang@contr.netl.doe.gov Please click on the links below to access issues of "Fire in the Ice". More on Methane Hydrates

2

NETL: Methane Hydrates - Hydrate Modeling - TOUGH-Fx/HYDRATE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrate Modeling - TOUGH+/HYDRATE & HydrateResSim Hydrate Modeling - TOUGH+/HYDRATE & HydrateResSim TOUGH+/HYDRATE v1.0 LBNL's new hydrate reservoir simulator (TOUGH+/HYDRATE v1.0) is now publicly available for licensing. TOUGH+/HYDRATE models non-isothermal gas release, phase behavior and flow of fluids and heat in complex geologic media. The code can simulate production from natural CH4-hydrate deposits in the subsurface (i.e., in the permafrost and in deep ocean sediments), as well as laboratory experiments of hydrate dissociation/formation in porous/fractured media. TOUGH+/HYDRATE v1.0 includes both an equilibrium and a kinetic model of hydrate formation and dissociation. More information on TOUGH+/Hydrate Also available is HydrateResSim. HydrateResSim (HRS) is a freeware, open-source reservoir simulator code available for use “as-is” from the NETL. HRS’ code was derived from an earlier version of the TOUGH+/Hydrate code.

3

Natural Gas Hydrates  

Science Journals Connector (OSTI)

Natural Gas Hydrates ... Formation Characteristics of Synthesized Natural Gas Hydrates in Meso- and Macroporous Silica Gels ... Formation Characteristics of Synthesized Natural Gas Hydrates in Meso- and Macroporous Silica Gels ...

Willard I. Wilcox; D. B. Carson; D. L. Katz

1941-01-01T23:59:59.000Z

4

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mechanical Testing of Gas Hydrate/Sediment Samples Mechanical Testing of Gas Hydrate/Sediment Samples DE-AT26-99FT40267 Goal Develop understanding of the mechanical characteristics of hydrate-containing sediments. Background The ACE CRREL has a unique group of experienced personnel that have studied the mechanical characteristics of ice and permafrost that can be applied to the study and characterization of the mechanical properties of gas hydrates. The effort aims to quantify the mechanical characteristics of methane hydrate and hydrate cemented sediments for use in models of the dynamic behavior of sediments related to drilling and seafloor installations in the Gulf of Mexico. Performers US Army Corp of Engineers, Engineer Research and Development Center, Cold Regions Research and Engineering Laboratory (CRREL) - project management and research products

5

CO2 Hydrate Composite for Ocean Carbon Sequestration  

Science Journals Connector (OSTI)

CO2 Hydrate Composite for Ocean Carbon Sequestration ... Further studies are needed to address hydrate conversion efficiency, scale-up criteria, sequestration longevity, and impact on the ocean biota before in-situ production of sinking CO2 hydrate composite can be applied to oceanic CO2 storage and sequestration. ...

Sangyong Lee; Liyuan Liang; David Riestenberg; Olivia R. West; Costas Tsouris; Eric Adams

2003-07-18T23:59:59.000Z

6

HydrateNewsIssue2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 1 T H E N A T I O N A L E N E R G Y T E C H N O L O G Y L A B O R A T O R Y M E T H A N E H Y D R A T E N E W S L E T T E R Announcements ChevronTexaco Gulf of Mexico Gas Hydrates Joint Industry Project Naturally Occurring Gas Hydrate Data Collection Workshop March 14-15, 2002, Adam's Mark Hotel, Houston, Texas The ChevronTexaco Gulf of Mexico Gas Hydrates Joint Industry Project (JIP), in collaboration with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL), will be holding a workshop to collect data on naturally occurring hydrates in the Gulf of Mexico (GOM). All key contributors to the understanding of naturally occurring hydrates are invited to apply to participate in the first of three workshops sponsored by the JIP. The purpose of the workshop is to develop a clear understanding of what

7

Hydrate-phobic surfaces  

E-Print Network [OSTI]

Clathrate hydrate formation and subsequent plugging of deep-sea oil and gas pipelines represent a significant bottleneck for ultra deep-sea production. Current methods for hydrate mitigation focus on injecting thermodynamic ...

Smith, Jonathan David, S.M. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

8

NETL: Methane Hydrates - Methane Hydrate Reference Shelf  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reference Shelf Reference Shelf The Methane Hydrate Reference Shelf was created to provide a repository for information collected from projects funded as part of the National Methane Hydrate R&D Program. As output from the projects is received, it will be reviewed and then placed onto the reference shelf to be available to other methane hydrate researchers. Projects: DOE/NETL Projects : These pages contain detailed information on methane hydrate projects funded through the National Energy Technology Laboratory. Publications: Newsletter | Bibliography | Software | Reports | Program Publications | Photo Gallery Newsletter: Fire in the Ice: A publication highlighting the National Methane Hydrate R&D Program Bibliography: "Project Reports Bibliography"[PDF]: The bibliography lists publications resulting from DOE/NETL-sponsored

9

Methane Hydrate Field Program  

SciTech Connect (OSTI)

This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. Historical Methane Hydrate Project Review Report Methane Hydrate Workshop Report Topical Report: Marine Methane Hydrate Field Research Plan Final Scientific/Technical Report

None

2013-12-31T23:59:59.000Z

10

Obsidian Hydration Rates  

Science Journals Connector (OSTI)

...OBSIDIAN HYDRATION RATE FOR KLAMATH BASIN OF CALIFORNIA AND OREGON...as the material is excreted, falls through the air, and dries...Friedman. Table 1 presents two new groups of hydra-tion readings for...the true age is believed to fall (3). The Snaketown age is...

Clement W. Meighan

1970-10-02T23:59:59.000Z

11

Methane Hydrates - Methane Hydrate Graduate Fellowship  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Future Supply and Emerging Resources Future Supply and Emerging Resources The National Methane Hydrates R&D Program - Graduate Fellowship Program Methane Hydrate Graduate Fellowship Program Jeffrey James Marlow, a graduate student in Geobiology at the California Institute of Technology, was recently selected as the 2012 recipient of the NETL-National Academy of Sciences (NAS) Methane Hydrate Research Fellowship. Please see page 15 of the March 2013 issue (Vol. 13, Issue 1) of Fire in the Ice for more information on the recipient. The Department of Energy has a long history of building synergistic relationships with research universities. Funding academic research is a "win-win-win" situation. The U.S. government is able to tap into some of the best minds available for solving national energy problems, the universities get the support they need to maintain cutting edge faculty and laboratories, and the students involved are provided with opportunities that help them along their chosen path of study, strengthening the national pool of scientists and engineers. According to Samuel Bodman, speaking about graduate research in methane hydrates, "Students are the foundation of our energy future, bringing new ideas and fresh perspectives to the energy industry. What better way to assure technology innovation than to encourage students working on the development of a resource that has the potential to tip our energy balance toward clean-burning, domestic fuels."

12

Chapter 8 - Methane Hydrates  

Science Journals Connector (OSTI)

Gas hydrate is a solid, naturally occurring substance consisting predominantly of methane gas and water. Recent scientific drilling programs in Japan, Canada, the United States, Korea and India have demonstrated that gas hydrate occurs broadly and in a variety of forms in shallow sediments of the outer continental shelves and in Arctic regions. Field, laboratory and numerical modelling studies conducted to date indicate that gas can be extracted from gas hydrates with existing production technologies, particularly for those deposits in which the gas hydrate exists as pore-filling grains at high saturation in sand-rich reservoirs. A series of regional resource assessments indicate that substantial volumes of gas hydrate likely exist in sand-rich deposits. Recent field programs in Japan, Canada and in the United States have demonstrated the technical viability of methane extraction from gas-hydrate-bearing sand reservoirs and have investigated a range of potential production scenarios. At present, basic reservoir depressurisation shows the greatest promise and can be conducted using primarily standard industry equipment and procedures. Depressurisation is expected to be the foundation of future production systems; additional processes, such as thermal stimulation, mechanical stimulation and chemical injection, will likely also be integrated as dictated by local geological and other conditions. An innovative carbon dioxide and methane swapping technology is also being studied as a method to produce gas from select gas hydrate deposits. In addition, substantial additional volumes of gas hydrate have been found in dense arrays of grain-displacing veins and nodules in fine-grained, clay-dominated sediments; however, to date, no field tests, and very limited numerical modelling, have been conducted with regard to the production potential of such accumulations. Work remains to further refine: (1) the marine resource volumes within potential accumulations that can be produced through exploratory drilling programs; (2) the tools for gas hydrate detection and characterisation from remote sensing data; (3) the details of gas hydrate reservoir production behaviour through additional, well-monitored and longer duration field tests and (4) the understanding of the potential environmental impacts of gas hydrate resource development. The results of future production tests, in the context of varying market and energy supply conditions around the globe, will be the key to determine the ultimate timing and scale of the commercial production of natural gas from gas hydrates.

Ray Boswell; Koji Yamamoto; Sung-Rock Lee; Timothy Collett; Pushpendra Kumar; Scott Dallimore

2014-01-01T23:59:59.000Z

13

Methane Hydrate | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Methane Hydrate Methane Hydrate Methane Hydrate Types of Methane Hydrate Deposits Types of Methane Hydrate Deposits Methane hydrate is a cage-like lattice of ice inside of which are trapped molecules of methane, the chief constituent of natural gas. If methane hydrate is either warmed or depressurized, it will revert back to water and natural gas. When brought to the earth's surface, one cubic meter of gas hydrate releases 164 cubic meters of natural gas. Hydrate deposits may be several hundred meters thick and generally occur in two types of settings: under Arctic permafrost, and beneath the ocean floor. Methane that forms hydrate can be both biogenic, created by biological activity in sediments, and thermogenic, created by geological processes deeper within the earth.

14

Methane Hydrate Program  

Broader source: Energy.gov (indexed) [DOE]

FY 2011 FY 2011 Methane Hydrate Program Report to Congress July 2012 United States Department of Energy Washington, DC 20585 Department of Energy | July 2012 FY 2011 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled U.S. Department of Energy FY 2011 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of research. Pursuant to statutory requirements, this report is being provided to the following

15

Marine Gas Hydrates  

Science Journals Connector (OSTI)

In several review articles, e.g., Boswell and Collett (2010), four gas hydrate reservoir types are evaluated in terms of their resource potential: sand-dominated reservoirs, clay-dominated fractured reservoirs, ....

Gerhard Bohrmann; Marta E. Torres

2014-09-01T23:59:59.000Z

16

Natural Gas Hydrate Dissociation  

Science Journals Connector (OSTI)

Materials for hydrate synthesis mainly include methane gas of purity 99.9% (produced by Nanjing Special Gases Factory Co., Ltd.), natural sea sand of grain sizes 0.063?0.09,...

Qingguo Meng; Changling Liu; Qiang Chen; Yuguang Ye

2013-01-01T23:59:59.000Z

17

Methane Hydrate Program  

Broader source: Energy.gov (indexed) [DOE]

Fiscal Year 2012 Fiscal Year 2012 Methane Hydrate Program Report to Congress August 2013 United States Department of Energy Washington, DC 20585 Department of Energy | August 2013 Fiscal Year 2012 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the actions taken to carry out methane hydrate research. I am pleased to submit the enclosed report, entitled U.S. Department of Energy Fiscal Year 2012 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area

18

Marine gas hydrates in thin sand layers that soak up microbial methane  

Science Journals Connector (OSTI)

At Site U1325 (IODP Exp. 311, Cascadia margin), gas hydrates occupy 2060% of pore space in thin sand layers (hydrate. This is a common occurrence in gas hydrate-bearing marine sequences, and it has been related to the inhibition of hydrate formation in the small pores of fine-grained sediments. This paper applies a mass balance model to gas hydrate formation in a stack of alternating fine- and coarse-grained sediment layers. The only source of methane considered is in situ microbial conversion of a small amount of organic carbon (gas hydrates in the fine-grained layers. Methane generated in these layers is transported by diffusion into the coarse-grained layers where it forms concentrated gas hydrate deposits. The vertical distribution and amount of gas hydrate observed at Site U1325 can be explained by in situ microbial methane generation, and a deep methane source is not necessary.

Alberto Malinverno

2010-01-01T23:59:59.000Z

19

Sedimentological control on saturation distribution in Arctic gas-hydrate-bearing sands  

Science Journals Connector (OSTI)

A mechanistic model is proposed to predict/explain hydrate saturation distribution in converted free gas hydrate reservoirs in sub-permafrost formations in the Arctic. This 1-D model assumes that a gas column accumulates and subsequently is converted to hydrate. The processes considered are the volume change during hydrate formation and consequent fluid phase transport within the column, the descent of the base of gas hydrate stability zone through the column, and sedimentological variations with depth. Crucially, the latter enable disconnection of the gas column during hydrate formation, which leads to substantial variation in hydrate saturation distribution. One form of variation observed in Arctic hydrate reservoirs is that zones of very low hydrate saturations are interspersed abruptly between zones of large hydrate saturations. The model was applied to data from Mount Elbert well, a gas hydrate stratigraphic test well drilled in the Milne Point area of the Alaska North Slope. The model is consistent with observations from the well log and interpretations of seismic anomalies in the area. The model also predicts that a considerable amount of fluid (of order one pore volume of gaseous and/or aqueous phases) must migrate within or into the gas column during hydrate formation. This paper offers the first explanatory model of its kind that addresses converted free gas reservoirs from a new angle: the effect of volume change during hydrate formation combined with capillary entry pressure variation versus depth.

Javad Behseresht; Steven L. Bryant

2012-01-01T23:59:59.000Z

20

HYDRATE CORE DRILLING TESTS  

SciTech Connect (OSTI)

The ''Methane Hydrate Production from Alaskan Permafrost'' project is a three-year endeavor being conducted by Maurer Technology Inc. (MTI), Noble, and Anadarko Petroleum, in partnership with the U.S. DOE National Energy Technology Laboratory (NETL). The project's goal is to build on previous and ongoing R&D in the area of onshore hydrate deposition. The project team plans to design and implement a program to safely and economically drill, core and produce gas from arctic hydrates. The current work scope includes drilling and coring one well on Anadarko leases in FY 2003 during the winter drilling season. A specially built on-site core analysis laboratory will be used to determine some of the physical characteristics of the hydrates and surrounding rock. Prior to going to the field, the project team designed and conducted a controlled series of coring tests for simulating coring of hydrate formations. A variety of equipment and procedures were tested and modified to develop a practical solution for this special application. This Topical Report summarizes these coring tests. A special facility was designed and installed at MTI's Drilling Research Center (DRC) in Houston and used to conduct coring tests. Equipment and procedures were tested by cutting cores from frozen mixtures of sand and water supported by casing and designed to simulate hydrate formations. Tests were conducted with chilled drilling fluids. Tests showed that frozen core can be washed out and reduced in size by the action of the drilling fluid. Washing of the core by the drilling fluid caused a reduction in core diameter, making core recovery very difficult (if not impossible). One successful solution was to drill the last 6 inches of core dry (without fluid circulation). These tests demonstrated that it will be difficult to capture core when drilling in permafrost or hydrates without implementing certain safeguards. Among the coring tests was a simulated hydrate formation comprised of coarse, large-grain sand in ice. Results with this core showed that the viscosity of the drilling fluid must also be carefully controlled. When coarse sand was being cored, the core barrel became stuck because the drilling fluid was not viscous enough to completely remove the large grains of sand. These tests were very valuable to the project by showing the difficulties in coring permafrost or hydrates in a laboratory environment (as opposed to a field environment where drilling costs are much higher and the potential loss of equipment greater). Among the conclusions reached from these simulated hydrate coring tests are the following: Frozen hydrate core samples can be recovered successfully; A spring-finger core catcher works best for catching hydrate cores; Drilling fluid can erode the core and reduces its diameter, making it more difficult to capture the core; Mud must be designed with proper viscosity to lift larger cuttings; and The bottom 6 inches of core may need to be drilled dry to capture the core successfully.

John H. Cohen; Thomas E. Williams; Ali G. Kadaster; Bill V. Liddell

2002-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Study on small-strain behaviours of methane hydrate sandy sediments using discrete element method  

SciTech Connect (OSTI)

Methane hydrate bearing soil has attracted increasing interest as a potential energy resource where methane gas can be extracted from dissociating hydrate-bearing sediments. Seismic testing techniques have been applied extensively and in various ways, to detect the presence of hydrates, due to the fact that hydrates increase the stiffness of hydrate-bearing sediments. With the recognition of the limitations of laboratory and field tests, wave propagation modelling using Discrete Element Method (DEM) was conducted in this study in order to provide some particle-scale insights on the hydrate-bearing sandy sediment models with pore-filling and cementation hydrate distributions. The relationship between shear wave velocity and hydrate saturation was established by both DEM simulations and analytical solutions. Obvious differences were observed in the dependence of wave velocity on hydrate saturation for these two cases. From the shear wave velocity measurement and particle-scale analysis, it was found that the small-strain mechanical properties of hydrate-bearing sandy sediments are governed by both the hydrate distribution patterns and hydrate saturation.

Yu Yanxin; Cheng Yipik [Department of Civil, Environmental and Geomatic Engineering, University College London (UCL), Gower Street, London, WC1E 6BT (United Kingdom); Xu Xiaomin; Soga, Kenichi [Geotechnical and Environmental Research Group, Department of Engineering, University of Cambridge, Trumpington Street, Cambridge, CB2 1PZ (United Kingdom)

2013-06-18T23:59:59.000Z

22

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pressurized Coring Equipment Pressurized Coring Equipment Pressure Core Equipment used by the Gulf of Mexico Gas Hydrate JIP Drilling Program Pressure Core Equipment - Photo Gallery One of the key objectives of the ChevronTexaco Gulf of Mexico hydrates Joint Industry Project is the collection and analyses of deepwater sediment samples. Because these samples may contain hydrate which is only stable at specific temperature and pressure conditions it is necessary to use specialized sampling equipment. Otherwise, the combination of reduced pressure and increased temperatures as the sample is retrieved through 4,000 feet of gulf seawater will fully dissociate the hydrate, leaving only gas and water. Although techniques exist to infer hydrates presence from distinctive geochemical markers, we have lost the ability to image the nature of hydrate distribution, or to conduct measurements of the various physical and chemical properties of hydrates in the host sediments.

23

Bonding Strength by Methane Hydrate Formed among Sand Particles  

Science Journals Connector (OSTI)

The mechanical properties of methane hydrate?bearing sand were investigated by low temperature and high confining pressure triaxial testing apparatus in the present study. The specimens were prepared by infiltrating the methane gas into partially saturated sand specimen under the given temperature and stress condition which is compatible with the phase equilibrium condition for the stability of methane hydrate. The tests were firstly performed to investigate the effect of temperature on the shear behaviour of the specimen. Then the effect of backpressure was investigated. The strength of methane hydrate bearing sand increased as the temperature decreased and the back pressure increased. The bonding strength due to methane hydrate was dependent on methane hydrate saturation temperature and back pressure but independent of effective stress. Dissociation tests of methane hydrate were also performed by applying the temperature to the specimen at the various initial stress conditions. The marked development of shear and volumetric strains were observed due to dissociation of the methane hydrate in the specimen corresponding to the initial stress conditions.

M. Hyodo; Y. Nakata; N. Yoshimoto; R. Orense; J. Yoneda

2009-01-01T23:59:59.000Z

24

NETL: Methane Hydrates - Global Assessment of Methane Gas Hydrates  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 Global Assessment of Methane Gas Hydrates Last Reviewed 12/18/2013 DE-FE0003060 Goal The goal of this project is to develop a global assessment of methane gas hydrates that will facilitate informed decision-making regarding the potential development of gas hydrate resources between the scientific community and other stakeholders/decision makers. The Assessment will provide science-based information on the role of gas hydrates in natural climate change and the carbon cycle, their sensitivity to climate change, and the potential environmental and socio-economic impacts of hydrate production. Performers Stiftelsen GRID-Arendal, Arendal, Norway Funding Institutions United Nations Environment Programme (UNEP) Statoil Schlumberger United States Department of Energy (USDOE)

25

Department of Energy Advance Methane Hydrates Science and Technology  

Broader source: Energy.gov (indexed) [DOE]

Advance Methane Hydrates Science and Technology Advance Methane Hydrates Science and Technology Projects Dollars awarded will go to research the advance understanding of the nature and occurrence of Deepwater and Arctic gas hydrates, and their implications for future resources, geohazards, and the environment Characterizing the Affect of Environmental Change on Gas-Hydrate-Bearing Deposits The University of California at San Diego (San Diego, Calif.) - Researchers at the University of California at San Diego will design, build, and test an electromagnetic (EM) system designed for very shallow water use and will apply the system to determine the extent of offshore permafrost on the U.S. Beaufort inner shelf. Energy Department Investment: $507,000 Duration: 36 months The University of Mississippi (Oxford, Miss.) - Using electronic measurements, the researchers will

26

Gas hydrate cool storage system  

DOE Patents [OSTI]

The invention presented relates to the development of a process utilizing a gas hydrate as a cool storage medium for alleviating electric load demands during peak usage periods. Several objectives of the invention are mentioned concerning the formation of the gas hydrate as storage material in a thermal energy storage system within a heat pump cycle system. The gas hydrate was formed using a refrigerant in water and an example with R-12 refrigerant is included. (BCS)

Ternes, M.P.; Kedl, R.J.

1984-09-12T23:59:59.000Z

27

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cruise Cruise Special Report - Bottom-Simulating Reflections(BSR). Seismic lines from deep continental shelves all around the world contain anomalous reflections known as bottom-simulating reflections(BSR). The reflections mimic the sea-floor topography at a near constant depth below the surface, and commonly cut across geological layers. The nature of the reflection indicates a horizon across which seismic velocity dramatically decreases. At one time, scientists thought the reflection must be due to some mineralogical alteration in the sediment due to heat and pressure. Once the existence of natural methane hydrate was established, BSRs were thought to record the decrease in velocity when passing from hydrate-bearing sediments to those containing only water. Therefore, BSRs were thought to be a direct indicator of hydrate: no BSR meant no hydrate. However, the velocity contrast between hydrate and no-hydrate was determined to be insufficient to cause BSRs. Today, scientists have established that BSRs are an indication of concentrations of free methane gas that is blocked from further upward migration by the presence of methane hydrate in the overlying layers. Consequently, the distribution of BSRs may mark only a subset of the areas containing hydrate.

28

NETL: Methane Hydrates - DOE/NETL Projects - Advanced Gas Hydrate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comparative Assessment of Advanced Gas Hydrate Production Methods Last Reviewed 09/23/2009 Comparative Assessment of Advanced Gas Hydrate Production Methods Last Reviewed 09/23/2009 DE-FC26-06NT42666 Goal The goal of this project is to compare and contrast, through numerical simulation, conventional and innovative approaches for producing methane from gas hydrate-bearing geologic reservoirs. Numerical simulation is being used to assess the production of natural gas hydrates from geologic deposits using three production technologies: 1) depressurization, 2) direct CO2 exchange, and 3) dissociation-reformation CO2 exchange. Performers Battelle Pacific Northwest Division, Richland, Washington 99352 Background There are relatively few published studies of commercial production methods for gas hydrates, and all of these studies have examined essentially

29

methane hydrate science plan-final.indd  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2013 Principal Authors: Consor um for Ocean Leadership and the Methane Hydrate Project Science Team December 2013 DOE Award Number: DE-FE0010195 Project Title: Methane Hydrate...

30

Methane hydrates: Fire from ice  

Science Journals Connector (OSTI)

... Attempts to compare these methods began last January. Most usable hydrate deposits probably lie offshore, but it is cheaper to begin with those beneath the Arctic. One of the ... As well as abundant hydrates, the site has similar geology and reservoir conditions to many offshore deposits, making it an ideal and accessible testing ground. Those involved say that they ...

David Adam

2002-08-29T23:59:59.000Z

31

The Great Gas Hydrate Escape  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Great Gas Great Gas Hydrate Escape The Great Gas Hydrate Escape Computer simulations revealing how methane and hydrogen pack into gas hydrates could enlighten alternative fuel production and carbon dioxide storage January 25, 2012 | Tags: Carver, Chemistry, Energy Technologies, Hopper, Materials Science PNNL Contact: Mary Beckman , +1 509 375-3688, mary.beckman@pnl.gov NERSC Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov The methane trapped in frozen water burns easily, creating ice on fire. For some time, researchers have explored flammable ice for low-carbon or alternative fuel or as a place to store carbon dioxide. Now, a computer analysis of the ice and gas compound, known as a gas hydrate, reveals key details of its structure. The results show that hydrates can hold hydrogen

32

Prediction and inhibition of hydrate and wax formation. Annual report, January-December 1991  

SciTech Connect (OSTI)

The first objective of the research project is to quantify and explain kinetics of co-precipitation of natural gas hydrates and wax. The second objective is to find means for inhibiting the rate of formation of natural gas hydrates, and the rate of natural gas/wax co-precipitation. During the first contract year, a method for measuring the rate of formation of natural gas hydrates was developed. This method has five advantages over other possible methods. First, it provides a defined surface area on which the hydrate nucleation and growth can proceed. Second, it minimizes the initial resistance to mass and heat transfer, thus maximizing sensitivity to kinetics. Third, it provides a way to test the effect of a variety of solid surfaces on hydrate formation. Fourth, it requires a low-cost apparatus with low operational cost. Fifth, it can be applied with little modification to the scheduled studies of kinetic inhibition and hydrate/wax-co-precipitation.

Sloan, E.D.; Christiansen, R.L.

1992-08-01T23:59:59.000Z

33

Measurement of in situ hydrate thermodynamic properties  

SciTech Connect (OSTI)

Heat capacities and heats of fusion measured in simulated in situ natural gas hydrates using tetrahydrofuran hydrates in clean sand indicated that sediments significantly affect hydrate formation conditions. These data are required to devise and evaluate methods for producing natural gas from hydrates, a potentially significant energy resource.

Sloan, E.D.

1982-03-01T23:59:59.000Z

34

Hydrates represent gas source, drilling hazard  

SciTech Connect (OSTI)

Gas hydrates look like ordinary ice. However, if a piece of such ice is put into warm water its behavior will be different from the ordinary melting of normal ice. In contrast, gas hydrates cause bubbles in the warm water, which indicates the high content of gas in the hydrate crystals. The presence of four components is required: gas itself, water, high pressure, and low temperature. The paper discusses how hydrates form, hydrates stability, South Caspian hydrates, and hydrates hazards for people, ships, pipelines, and drilling platforms.

Bagirov, E. [Azerbaijan Academy of Sciences, Baku (Azerbaijan); Lerche, I. [Univ. of South Carolina, Columbia, SC (United States)

1997-12-01T23:59:59.000Z

35

NETL: Methane Hydrates - DOE/NETL Projects - Advanced Hydrate Reservoir  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Hydrate Reservoir Modeling Using Rock Physics Techniques Last Reviewed 11/29/2013 Advanced Hydrate Reservoir Modeling Using Rock Physics Techniques Last Reviewed 11/29/2013 DE-FE0010160 Goal The primary goal of this research is to develop analytical techniques capable of quantitatively evaluating the nature of methane hydrate reservoir systems through modeling of their acoustic response using techniques that integrate rock physics theory, amplitude analysis, and spectral decomposition. Performers Fugro GeoConsulting, Inc., Houston TX Background Past efforts under the DOE-supported Gulf of Mexico Joint Industry project included the selection of well locations utilizing prospectivity analysis based primarily on a petroleum systems approach for gas hydrate using 3-D exploration seismic data and derivative analyses that produced predicted

36

Methane Hydrates R&D Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program Gas hydrates are a naturally-occurring combination of methane gas and water that form under specific conditions of low temperature and high pressure. Once thought to be rare in nature, gas hydrates are now known to occur in great abundance in association with arctic permafrost and in the shallow sediments of the deep-water continental shelves. The most recent estimates of gas hydrate abundance suggest that they contain

37

Hydrates as an Energy Source  

Science Journals Connector (OSTI)

As an energy resource, gas hydrates are considered together with other unconventional hydrocarbon ... of these unconventional resources. Besides the tar sands and extra heavy oils, other examples are shale gas an...

Carlo Giavarini; Keith Hester

2011-01-01T23:59:59.000Z

38

Methane Hydrate Research and Modeling  

Broader source: Energy.gov [DOE]

Research is focused on understanding the physical and chemical nature of gas hydrate-bearing sediments. These studies advance the understanding of the in situ nature of GHBS and their potential...

39

Hydrogen Storage in Clathrate Hydrates  

Science Journals Connector (OSTI)

Structure, stability, and reactivity of clathrate hydrates with or without hydrogen encapsulation are studied using standard density functional calculations. Conceptual density functional theory based reactivity descriptors and the associated electronic ...

Pratim Kumar Chattaraj; Sateesh Bandaru; Sukanta Mondal

2010-12-14T23:59:59.000Z

40

Modeling pure methane hydrate dissociation using a numerical simulator from a novel combination of X-ray computed tomography and macroscopic data  

SciTech Connect (OSTI)

The numerical simulator TOUGH+HYDRATE (T+H) was used to predict the transient pure methane hydrate (no sediment) dissociation data. X-ray computed tomography (CT) was used to visualize the methane hydrate formation and dissociation processes. A methane hydrate sample was formed from granular ice in a cylindrical vessel, and slow depressurization combined with thermal stimulation was applied to dissociate the hydrate sample. CT images showed that the water produced from the hydrate dissociation accumulated at the bottom of the vessel and increased the hydrate dissociation rate there. CT images were obtained during hydrate dissociation to confirm the radial dissociation of the hydrate sample. This radial dissociation process has implications for dissociation of hydrates in pipelines, suggesting lower dissociation times than for longitudinal dissociation. These observations were also confirmed by the numerical simulator predictions, which were in good agreement with the measured thermal data during hydrate dissociation. System pressure and sample temperature measured at the sample center followed the CH{sub 4} hydrate L{sub w}+H+V equilibrium line during hydrate dissociation. The predicted cumulative methane gas production was within 5% of the measured data. Thus, this study validated our simulation approach and assumptions, which include stationary pure methane hydrate-skeleton, equilibrium hydrate-dissociation and heat- and mass-transfer in predicting hydrate dissociation in the absence of sediments. It should be noted that the application of T+H for the pure methane hydrate system (no sediment) is outside the general applicability limits of T+H.

Gupta, A.; Moridis, G.J.; Kneafsey, T.J.; Sloan, Jr., E.D.

2009-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

NETL: Methane Hydrates - DOE/NETL Projects - Application of Crunch-Flow  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Application of CrunchFlow Routines to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites Last Reviewed 12/11/2013 Application of CrunchFlow Routines to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites Last Reviewed 12/11/2013 DE-FE0010496 Goal The goal of this project is to apply a multi-component, multi-dimensional reactive transport simulation code to constrain modern day methane fluxes and to reconstruct past episodes of methane flux that can be correlated with environmental changes. Performers Oregon State University – Corvallis, OR Background The importance of understanding the role that gas hydrates play in the global carbon cycle and in understanding their potential as a future energy resource have long been recognized and are key components of the Methane Hydrate R&D Program. Fundamental questions remain, however, as to the residence time of gas hydrates near the seafloor and deeper within the

42

NETL: Methane Hydrates - DOE/NETL Projects - Kinetic Parameters for the  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Kinetic Parameters for the Exchange of Hydrate Formers Last Reviewed 12/16/2013 Kinetic Parameters for the Exchange of Hydrate Formers Last Reviewed 12/16/2013 FWP 65213 Goal The overarching goal of this project is to gain an improved understanding of the dynamic processes of gas hydrate accumulations in geologic media by combining laboratory studies, numerical simulation, and analysis of shipboard infrared imaging of hydrate core samples. This project comprises four principal components: (1) fundamental laboratory investigations, (2) numerical simulator development and verification, (3) hydrate core characterization and analysis, and (4) applied laboratory and numerical investigations. Performer Pacific Northwest National Laboratory (PNNL), Richland, Washington Background Numerical Simulation A new simulator in the STOMP simulator series for the production of natural

43

Well log evaluation of natural gas hydrates  

SciTech Connect (OSTI)

Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question linking gas hydrate resource and hazard issues is: What is the volume of gas hydrates and included gas within a given gas hydrate occurrence? Most published gas hydrate resource estimates have, of necessity, been made by broad extrapolation of only general knowledge of local geologic conditions. Gas volumes that may be attributed to gas hydrates are dependent on a number of reservoir parameters, including the areal extent ofthe gas-hydrate occurrence, reservoir thickness, hydrate number, reservoir porosity, and the degree of gas-hydrate saturation. Two of the most difficult reservoir parameters to determine are porosity and degreeof gas hydrate saturation. Well logs often serve as a source of porosity and hydrocarbon saturation data; however, well-log calculations within gas-hydrate-bearing intervals are subject to error. The primary reason for this difficulty is the lack of quantitative laboratory and field studies. The primary purpose of this paper is to review the response of well logs to the presence of gas hydrates.

Collett, T.S.

1992-10-01T23:59:59.000Z

44

Well log evaluation of natural gas hydrates  

SciTech Connect (OSTI)

Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question linking gas hydrate resource and hazard issues is: What is the volume of gas hydrates and included gas within a given gas hydrate occurrence Most published gas hydrate resource estimates have, of necessity, been made by broad extrapolation of only general knowledge of local geologic conditions. Gas volumes that may be attributed to gas hydrates are dependent on a number of reservoir parameters, including the areal extent ofthe gas-hydrate occurrence, reservoir thickness, hydrate number, reservoir porosity, and the degree of gas-hydrate saturation. Two of the most difficult reservoir parameters to determine are porosity and degreeof gas hydrate saturation. Well logs often serve as a source of porosity and hydrocarbon saturation data; however, well-log calculations within gas-hydrate-bearing intervals are subject to error. The primary reason for this difficulty is the lack of quantitative laboratory and field studies. The primary purpose of this paper is to review the response of well logs to the presence of gas hydrates.

Collett, T.S.

1992-10-01T23:59:59.000Z

45

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 In Situ Sampling and Characterization of Naturally Occurring Methane Hydrate Using the D/V JOIDES Resolution Last Reviewed 02/05/2010 DE-FC26-01NT41329 photo of a man showing the pressure core sampler on the deck of JOIDES Resolution Pressure core sampler on deck courtesy Texas A&M University Goal The goal of the project was to characterize hydrate accumulation at Hydrate Ridge (offshore Oregon) and improve the ability to use geophysical and subsurface logging to identify hydrates. A follow-on goal was to characterize hydrate accumulation at offshore Vancouver Island, BC, Canada. Background This project focused on physically verifying the existence of hydrates at Hydrate Ridge through the collection of pressurized and non-pressurized core samples and logging data. This study developed and tested tools to

46

Project to evaluate natural gas hydrates  

Science Journals Connector (OSTI)

More than 170 scf of natural gas, mostly methane, may be contained in 1 cu ft of hydrate, according to Malcolm A. Goodman, president of Enertech & Research Co., Houston, which is involved in the new hydrate project. ...

1980-07-28T23:59:59.000Z

47

methane_hydrates | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrate and its potential as a fuel source, please read the 2011 Methane Hydrates Primer. Information on other elements of the program can be found under the links below. Fire...

48

CX-000734: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

of Methane Hydrates CX(s) Applied: A9 Date: 01222010 Location(s): Stillwater, Oklahoma Office(s): Fossil Energy, National Energy Technology Laboratory Collect data and...

49

CX-005054: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

Exclusion Determination CX-005054: Categorical Exclusion Determination Gas Hydrate Production Test (Phase III - AdministrativePlanningModeling Tasks) CX(s) Applied: A2,...

50

SUBSURFACE CHARACTERIZATION OF THE HYDRATE BEARING  

E-Print Network [OSTI]

fps). The underlying wet sand at the base of the gas hydrate stability zone (GHSZ) has low resistivity

Sediments Near; Alaminos Canyon; Thomas Latham; Dianna Shelander; Ray Boswell; Timothy Collett; Myung Lee

51

Gas hydrates: past and future geohazard?  

Science Journals Connector (OSTI)

...David Pyle, John Smellie and David Tappin Gas hydrates: past and future geohazard? Mark...University of Bristol, , Bristol, UK Gas hydrates are ice-like deposits containing a mixture of water and gas; the most common gas is methane. Gas hydrates...

2010-01-01T23:59:59.000Z

52

Gas hydrates: past and future geohazard?  

Science Journals Connector (OSTI)

...seafloor samples were recovered in the Black Sea...warm to support the solid gas hydrates, so...stored in other fossil fuel reservoirs. However...Kvenvolden (2007). Solid points are locations...hydrates have been recovered. Figure 4. This...trapped below the solid gas hydrate layer...

2010-01-01T23:59:59.000Z

53

Analysing sand-dominated channel systems for potential gas-hydrate-reservoirs using an AVO seismic inversion technique on the Southern Hikurangi Margin, New Zealand  

Science Journals Connector (OSTI)

Gas hydrates have recently been recognised as a class of unconventional petroleum resource and the economic viability of gas production from hydrates is now being viewed as a realistic possibility within the next decade. Therefore, potential offshore hydrate accumulations in the world-class endowed gas hydrate province, the Hikurangi Margin, New Zealand, represent a significant medium- to long-term opportunity to meet the country's future energy requirements. In this paper we delineate a potential gas hydrate reservoir in the East Coast Basin, New Zealand and quantitatively estimate its gas hydrate concentrations from 2D seismic data with no well information available. The target is interesting for exploration since it shows evidence for gas-hydrate bearing sands, in particular, buried channel systems. We use a combined analysis of high-resolution velocity analysis, amplitude-versus-offset (AVO) attribute and AVO inversion to investigate whether we can identify regions that are likely to contain highly concentrated gas hydrates and whether they are likely to be sand-dominated. To estimate hydrate concentrations we apply a rock physics model. Our results indicate the presence of several up to 200m thick zones that are likely to host gas hydrates, with one location predicted to consist of high-permeable channel sands and an inferred gas hydrate saturation of ?25%. These findings suggest significant amounts of gas hydrates may be present in high-quality reservoirs on this part of the margin.

M. Fohrmann; I.A. Pecher

2012-01-01T23:59:59.000Z

54

Introductory overview: Hydrate knowledge development  

Science Journals Connector (OSTI)

...both within and without the pipeline is outlined, and examples...magnitude more problematic than wax, the next largest obstruction...energy resources, (2) pipeline blockage prevention and remediation...funding for hydrates inside the pipeline has provided physics and chemistry...

E. Dendy Sloan

55

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interrelation of Global Climate and the Response of Oceanic Hydrate Accumulations Last Reviewed 8/21/2013 Interrelation of Global Climate and the Response of Oceanic Hydrate Accumulations Last Reviewed 8/21/2013 Field Work Proposals: ESD07-014 (LBNL) and 08FE-003 (LANL) Project Goal The primary objectives of this project are to: 1) investigate the effect of rising water temperatures on the stability of oceanic hydrate accumulations, 2) estimate the global quantity of hydrate-originating carbon that could reach the upper atmosphere as CH4 or CO2 thus affecting global climate, 3) quantify the interrelationship between global climate and the amount of hydrate-derived carbon reaching the upper atmosphere focusing on the potential link between hydrate dissociation and cascading global warming and 4) test the discharge phase of the Clathrate Gun Hypothesis which stipulates large-scale hydrate dissociation and gas

56

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Petrophysical Characterization and Reservoir Simulator for Gas Hydrate Production and Hazard Avoidance in the Gulf of Mexico Petrophysical Characterization and Reservoir Simulator for Gas Hydrate Production and Hazard Avoidance in the Gulf of Mexico DE-FC26-02NT41327 Goal The project goal was to develop new methodologies to characterize the physical properties of methane hydrate and hydrate sediment systems. Performers Westport Technology Center International - Houston, TX University of Houston - Houston, TX Results Project researchers created a pressure cell for measuring acoustic velocity and resistivity on hydrate-sediment cores. They utilized the measurements for input to an existing reservoir model for evaluating possible offshore hydrate accumulations. The organization of an industry-led Advisory Board and the development of a Research Management Plan have been completed. The development of a handbook for transporting, preserving, and storing hydrate core samples brought from the field to the laboratory was completed and distributed for review by industry and researchers.

57

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 - Methane Hydrate Research - Geoscience Evaluations and Field Studies Last Reviewed 3/18/2013 Project Goals The primary goals of the DOE/NETL Natural Gas Hydrate Field Studies (NGHFS) project are: Conduct field-based studies that advance the ability to predict, detect, characterize, and understand distribution of and controls on natural gas hydrate occurrences. Analyze geologic, geochemical, and microbiologic data for indications of past and current changes to the stability of natural gas hydrate in marine settings. Develop links between the U.S. Gas Hydrate Program and international R&D efforts through direct participation in international field programs and workshops. Evaluate the potential role natural gas hydrates may play in the global carbon cycle through analysis of modern and paleo-natural gas

58

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 Characterization and Decomposition Kinetic Studies of Methane Hydrate in Host Sediments under Subsurface Mimic Conditions Last Reviewed 02/17/2010 EST-380-NEDA Goal The purpose of this study is to establish sediment lithology and quantification of methane in hydrates hosted in fine-grained sediments from the Gulf of Mexico (GoM), a marine site of methane hydrate occurrence. The results will help establish a correlation between laboratory data and hydrate accumulation field data on dispersed hydrates in the natural environment. Performer Brookhaven National Laboratory (BNL), Upton, New York 11973 Background Gas hydrates are located in permafrost and marine environments and show potential as a vast methane source worldwide. However, methane is about 17 times more potent a greenhouse gas than CO2 and the inherent instability of

59

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of Natural Hydrate Bearing Sediments and Hydrate Dissociation Kinetics Last Reviewed 12/6/2013 Characterization of Natural Hydrate Bearing Sediments and Hydrate Dissociation Kinetics Last Reviewed 12/6/2013 FWP-45133 Work conducted under this field work proposal (FWP) includes two distinct phases. Ongoing Phase 2 work is discussed directly below. Click here to review the completed, Phase 1 work, associated with this FWP. Phase 2 Project Information Characterization of Natural Hydrate Bearing Core Samples Goal The overarching goal of this project is to gain an improved understanding of the dynamic processes of gas hydrate accumulations in geologic media by combining laboratory studies, numerical simulation, and analysis of shipboard infrared imaging of hydrate core samples. This project comprises four principal components: (1) fundamental laboratory investigations, (2)

60

Methane Hydrate Advisory Committee | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Methane Hydrate Advisory Methane Hydrate Advisory Committee Methane Hydrate Advisory Committee The Methane Hydrate Advisory Committee was created in response to provisions of the Methane Hydrate Research and Development Act of 2000 and reauthorized by the Energy Policy Act of 2005. The Committee is to advise the Secretary of Energy on potential applications of methane hydrate; assist in developing recommendations and priorities for the methane hydrate research and development program; and submit to Congress one or more reports on an assessment of the research program and an assessment of the DOE 5-year research plan. The Committee's charter stipulates that up to 15 members can be appointed by the Secretary of Energy, representing institutions of higher education, industrial enterprises and oceanographic institutions and state agencies.

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

– Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 – Formation and Dissociation of Methane Hydrates Last Reviewed 07/7/2011 Project Objective Observe hydrate formation and dissociation phenomena in various porous media and characterize hydrate-bearing sediments by estimating physical properties (kinetic parameters for hydrate formation and dissociation, thermal conductivity, permeability, relative permeability, and mechanical strength) to enhance fundamental understanding on hydrate formation and accumulation and to support numerical simulations and potential gas hydrate production Project Performers Yongkoo Seol – NETL Office of Research & Development Jeong Choi – Oak Ridge Institute for Science and Education Jongho Cha-Virginia Polytech Institute Project Location National Energy Technology Laboratory - Morgantown, West Virginia

62

Methane Hydrate Production Feasibility | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Production Feasibility Production Feasibility Methane Hydrate Production Feasibility The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. Methane, the predominant component of natural gas, forms hydrate in the presence of water, low temperatures and high pressures. Alternatively, when the temperature is increased or the pressure decreased so that hydrates are outside their stability field, they dissociate into methane and water.

63

Handbook of gas hydrate properties and occurrence  

SciTech Connect (OSTI)

This handbook provides data on the resource potential of naturally occurring hydrates, the properties that are needed to evaluate their recovery, and their production potential. The first two chapters give data on the naturally occurring hydrate potential by reviewing published resource estimates and the known and inferred occurrences. The third and fourth chapters review the physical and thermodynamic properties of hydrates, respectively. The thermodynamic properties of hydrates that are discussed include dissociation energies and a simplified method to calculate them; phase diagrams for simple and multi-component gases; the thermal conductivity; and the kinetics of hydrate dissociation. The final chapter evaluates the net energy balance of recovering hydrates and shows that a substantial positive energy balance can theoretically be achieved. The Appendices of the Handbook summarize physical and thermodynamic properties of gases, liquids and solids that can be used in designing and evaluating recovery processes of hydrates. 158 references, 67 figures, 47 tables.

Kuustraa, V.A.; Hammershaimb, E.C.

1983-12-01T23:59:59.000Z

64

NETL: Methane Hydrates - DOE/NETL Projects - Hydrate-Bearing Clayey  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering/Geological Implications Last Reviewed 12/30/2013 Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering/Geological Implications Last Reviewed 12/30/2013 DE-FE0009897 Goal The primary goal of this research effort is to contribute to an in-depth understanding of hydrate bearing, fine-grained sediments with a focus on investigation of their potential for hydrate-based gas production. Performer Georgia Tech Research Corporation, Atlanta GA Background Fine-grained sediments host more than 90 percent of global gas hydrate accumulation. Yet hydrate formation in clay-dominated sediments is less understood and characterized than other types of hydrate occurrence. There is an inadequate understanding of hydrate formation mechanisms, segregation structures, hydrate-lense topology, system connectivity, and physical

65

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wireline Logging Wireline Logging From: Timothy Collett, USGS Conventional Wireline Logging Operations in the Gulf of Mexico Gas Hydrate JIP Drilling Program Conventional wireline (CWL) logging operations in the Gulf of Mexico Gas Hydrate JIP Drilling Program (GOM-JIP) was scheduled to include the deployment of a signal logging string (Figure 1) and a vertical seismic profiling (VSP) tool (Figure 2) in several of the Atwater Valley and Keathley Canyon drill sites. The only wireline logging tool scheduled to be deployed was the FMS-sonic tool string, which consisted of the Formation MicroScanner (FMS), a general purpose inclinometer tool (GPIT), and scintillation gamma ray tool (SGT), and the dipole shear sonic imager tool (DSI). The vertical seismic imager tool (VSI) will also be deployed during the GOM-JIP drilling program. The wireline logging tools were provided by Schlumberger wireline services.

66

NETL: Methane Hydrates - 2012 Ignik Sikumi gas hydrate field trial  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2012 Ignik Sikumi gas hydrate field trial 2012 Ignik Sikumi gas hydrate field trial Photo of the Ignik Drilling Pad Download 2011/2012 Field Test Data Ignik Sikumi #1 "Fire in the Ice" Video Project Background Participants Ignik Sikumi Well Review CO2-Ch4 Exchange Overview August 2, 2013 - Project operations are complete. Read the Final Project Technical Report [PDF-44.1MB] February 19, 2013 - Data from the 2011/2012 field test is now available! Click here to access data. Status Report - May 7, 2012 Final abandonment of Ignik Sikumi #1 wellsite has been completed. Tubing, casing-tubing annulus, and flatpack were filled with cement per the abandonment procedure approved by the Alaska Oil and Gas Conservation Commission. To minimize effects on the landscape and leave as little trace of the operations as possible, a small area around the wellhead was

67

2.0 Closed-Domain Hydrate Dissociation (Base Case w/ Hydrate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Closed-Domain Hydrate Dissociation (Base Case w/ Hydrate) Closed-Domain Hydrate Dissociation (Base Case w/ Hydrate) 2.1 Problem Description One half of a 20-m, one-dimensional horizontal domain, discretized using uniformly spaced 1-m grid cells (optionally 0.1-m grid cells) is initialized with aqueous-hydrate conditions; whereas, the other half of the domain is initialized with gas-aqueous conditions. As with the Base Case problem, a closed horizontal domain is used to eliminate gravitational body forces and boundary condition effects. The initial conditions are specified to yield complete dissociation of the hydrate, via the thermal capacitance of the domain-half initialized with gas-aqueous conditions. To initialize the aqueous-hydrate half of the domain, temperature, pressure, and hydrate saturation are

68

Hydrate-phobic surfaces: fundamental studies in clathrate hydrate adhesion reduction  

E-Print Network [OSTI]

Clathrate hydrate formation and subsequent plugging of deep-sea oil and gas pipelines represent a significant bottleneck for deep-sea oil and gas operations. Current methods for hydrate mitigation are expensive and energy ...

Smith, J. David

69

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 Detection and Production of Methane Hydrate Last Reviewed 5/15/2012 DE-FC26-06NT42960 Goal The goal of this project is to improve the understanding of regional and local differences in gas hydrate systems from three perspectives: as an energy resource, as a geohazard, and as a long-term influence on global climate. Performers Rice University, Houston, TX University of Texas, Austin, TX Oklahoma State University, Stillwater, OK Background Heterogeneity in the distribution of gas hydrate accumulations impacts all aspects of research into gas hydrate natural systems. The challenge is to delineate, understand, and appreciate these differences at the regional and local scales, where differences in in situ concentrations are relevant to the importance of gas hydrate as a resource, a geohazard, and a factor in

70

Rapid Gas Hydrate Formation Process Opportunity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Hydrate Formation Process Gas Hydrate Formation Process Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking collaborative research and licensing partners interested in implementing United States Non-provisional Patent Application entitled "Rapid Gas Hydrate Formation Process." Disclosed in this application is a method and device for producing gas hydrates from a two-phase mixture of water and a hydrate forming gas such as methane (CH 4 ) or carbon dioxide (CO 2 ). The two-phase mixture is created in a mixing zone, which may be contained within the body of the spray nozzle. The two-phase mixture is subsequently sprayed into a reaction vessel, under pressure and temperature conditions suitable for gas hydrate formation. The reaction

71

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed Gas Hydrate Production Trial Using CO2 / CH4 Exchange Completed DE-NT0006553 Goal The goal of this project is to define, plan, conduct and evaluate the results of a field trial of a methane hydrate production methodology whereby carbon dioxide (CO2) molecules are exchanged in situ for methane (CH4) molecules within a hydrate structure, releasing the methane for production. The objective is to evaluate the viability of this hydrate production technique and to understand the implications of the process at a field scale. image showing Conceptual rendering of proposed CO2 - CH4 exchange methodology for the production of natural gas from hydrates Conceptual rendering of proposed CO2 - CH4 exchange methodology for the

72

Detection and Production of Methane Hydrate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

July-September 2007 July-September 2007 Detection and Production of Methane Hydrate Submitted by: Rice University University of Houston George J. Hirasaki Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; FAX: 713-348-5478; Email: gjh@rice.edu Prepared for: United States Department of Energy National Energy Technology Laboratory December, 2007 Office of Fossil Energy Table of Contents DOE Methane Hydrate Program Peer Review.................................................. 3 Task 5: Carbon Inputs and Outputs to Gas Hydrate Systems ........................... 3 Task 6: Numerical Models for Quantification of Hydrate and Free Gas Accumulations....................................................................................................

73

Hydration dynamics near a model protein surface  

E-Print Network [OSTI]

AE, Onuchic JN. 2002. Protein folding mediated by solvation:of hydration forces in protein folding. Journal of Physicalthe broader context of protein folding and function and as

Russo, Daniela; Hura, Greg; Head-Gordon, Teresa

2003-01-01T23:59:59.000Z

74

Physical Properties of Gas Hydrates: A Review  

SciTech Connect (OSTI)

Methane gas hydrates in sediments have been studied by several investigators as a possible future energy resource. Recent hydrate reserves have been estimated at approximately 1016?m3 of methane gas worldwide at standard temperature and pressure conditions. In situ dissociation of natural gas hydrate is necessary in order to commercially exploit the resource from the natural-gas-hydrate-bearing sediment. The presence of gas hydrates in sediments dramatically alters some of the normal physical properties of the sediment. These changes can be detected by field measurements and by down-hole logs. An understanding of the physical properties of hydrate-bearing sediments is necessary for interpretation of geophysical data collected in field settings, borehole, and slope stability analyses; reservoir simulation; and production models. This work reviews information available in literature related to the physical properties of sediments containing gas hydrates. A brief review of the physical properties of bulk gas hydrates is included. Detection methods, morphology, and relevant physical properties of gas-hydrate-bearing sediments are also discussed.

Gabitto, Jorge [Prairie View A& M University; Tsouris, Costas [ORNL

2010-01-01T23:59:59.000Z

75

Imaging Hydrated Microbial Extracellular Polymers: Comparative...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dehydration-based sample preparation that resulted in the collapse of hydrated gel-like EPS into filamentous structures. Dehydration-induced polymer collapse can lead to...

76

Preliminary relative permeability estimates of methane hydrate-bearing sand  

E-Print Network [OSTI]

sand, the gas permeability of the sand with hydrate, and thefor gas and water through methane hydrate-bearing sand. X-hydrate dissociation and making a single-phase (gas or water) permeability measurement of the sand

Seol, Yongkoo; Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis, George J.

2006-01-01T23:59:59.000Z

77

Examination of Hydrate Formation Methods: Trying to Create Representative Samples  

E-Print Network [OSTI]

gas hydrate morphology on the seismic velocities of sands,sand does not distribute water and gas evenly. Resultant hydrateHydrate Using Excess Gas Method Followed by Water Saturation Description In this method, moist sand

Kneafsey, T.J.

2012-01-01T23:59:59.000Z

78

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The DOE/JIP Gulf of Mexico Hydrate Research Cruise The DOE/JIP Gulf of Mexico Hydrate Research Cruise Status Reports During this expedition we will maintain an intermittent log of information relayed from the chief scientist on the expedition. To view a report for a particular day click on the "Day x" link in any highlighted box. The planned cruise timeline [PDF-13KB] is April 17 - May 21, 2005. This is the "planned" timeline. The schedule may change without prior notification due weather conditions or other unplanned occurrences. April 17 Day 1 April 18 Day 2 April 19 Day 3 April 20 Day 4 April 21 Day 5 April 22 Day 6 April 23 Day 7 April 24 Day 8 April 25 Day 9 April 26 Day 10 April 27 Day 11 April 28 Day 12 April 29 Day 13 April 30 Day 14 May 1 Day 15 May 2 Day 16 May 3 Day 17 May 4 Day 18 May 5

79

Gas hydrate-filled fracture reservoirs on continental margins.  

E-Print Network [OSTI]

?? Many scientists predicted that gas hydrate forms in fractures or lenses in fine-grained sediments, but only in the last decade were gas hydrates found (more)

Cook, Ann Elizabeth

2010-01-01T23:59:59.000Z

80

Microstructural Response of Variably Hydrated Ca-Rich Montmorillonite...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Microstructural Response of Variably Hydrated Ca-Rich Montmorillonite to Supercritical CO2. Microstructural Response of Variably Hydrated Ca-Rich Montmorillonite to Supercritical...

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Chemically reacting plumes, gas hydrate dissociation and dendrite solidification  

E-Print Network [OSTI]

the coated bubbles leave the hydrate stability zone thestability zone extends far enough above the sea ?oor, gas hydrates may nucleate on the bubble

Conroy, Devin Thomas

2008-01-01T23:59:59.000Z

82

NETL: Methane Hydrates - DOE/NETL Projects - Natural Gas Hydrates in  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The National Methane Hydrates R&D Program The National Methane Hydrates R&D Program DOE/NETL Methane Hydrate Projects Natural Gas Hydrates in Permafrost and Marine Settings: Resources, Properties, and Environmental Issues Last Reviewed 12/30/2013 DE-FE0002911 Goal The objective of this DOE-USGS Interagency Agreement is to provide world-class expertise and research in support of the goals of the 2005 Energy Act for National Methane Hydrates R&D, the DOE-led U.S. interagency roadmap for gas hydrates research, and elements of the USGS mission related to energy resources, global climate, and geohazards. This project extends USGS support to the DOE Methane Hydrate R&D Program previously conducted under DE-AI26-05NT42496. Performer U.S. Geological Survey at Woods Hole, MA, Denver, CO, and Menlo Park, CA

83

NETL: Methane Hydrates - ANS Research Project  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Photo Gallery Photo Gallery Photo of hydrate saturated, fine grained sand core from the Mt. Elbert #1 well Hydrate saturated, fine grained sand core from the Mt. Elbert #1 well .- click on image to enlarge Photo of close up of fine grained sand core sample. This sample was taken for porewater geochemical analyses and was hydrate saturated at the time of recovery. Close up of fine grained sand core sample. This sample was taken for porewater geochemical analyses and was hydrate saturated at the time of recovery.- click on image to enlarge Photo of close up of fine grained sand core sample being placed in water. Links to video of hydrate dissociating One visual test used to confirm that a core contains hydrate is to place a small sample from the core in a canister of water. The gas dissociated from the hydrate-bearing sediment is released into the water and bubbles to the surface. In the video sequence shown here, dissociated hydrate gas from a sample of Mt. Elbert #1 core can be seen and heard as it is released into the water. - click on image to view video [MPEG]

84

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of Sea Floor Monitoring Station DE-FC26-02NT41328 Goal Determine the potential impacts of gas hydrate instability in terms of the release of methane into seafloor sediments, the ocean and the atmosphere. Performers University of California, San Diego (Scripps Institution of Oceanography) - manage geochemical, hydrological and sedimentological investigations Texas A&M University - manage field monitoring program Location La Jolla, California 92093 Background This project will monitor, characterize, and quantify the rates of formation and dissociation of methane gas hydrates at and near the seafloor in the northern Gulf of Mexico, and determine linkages between formation/dissociation and physical/chemical parameters of the deposits over the course of a year. The stability and response of shallow gas hydrates to temperature and chemical perturbations will be monitored in situ, and localized seafloor and water column environmental impacts of hydrate formation and dissociation characterized. The following will be determined: 1) The equilibrium/steady state conditions for structure II methane gas hydrates at the field site,2) whether the system is in dynamic equilibrium and the local hydrology is characterized by steady state episodic fluid flow, and 3) how fluid fluxes and fluid composition work together to dynamically influence gas hydrate stability.

85

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new Arctic Drilling Platform in search of gas hydrate and free gas accumulations at depths of approximately 1200 to 2500 ft MD. A secondary objective was the gas-charged sands of the uppermost Campanian interval at approximately 3000 ft. Summary results of geophysical analysis of the well are presented in this report.

Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

2005-02-01T23:59:59.000Z

86

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 Laboratory Studies in Support of Characterization of Recoverable Resources from Methane Hydrate Deposits Last Reviewed 5/10/2012 ESD05-048 Goal The project is bringing new laboratory measurements and evaluation techniques to bear on the difficult problems of characterization and gas recovery from methane hydrate deposits. Performer Lawrence Berkeley National Laboratory, Berkeley, CA 94720 Background LBNL is performing laboratory tests to provide data to support the characterization and development of methane hydrate deposits. Major areas of research underway include hydrologic measurements, combined geomechanical/geophysical measurements, and synthetic hydrate formation studies. Hydrologic Measurements Relatively little research has been done to experimentally determine

87

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Heat flow and gas hydrates on the continental margin of India Last Reviewed 12/15/2011 Heat flow and gas hydrates on the continental margin of India Last Reviewed 12/15/2011 DE-NT0005669 Goal The goals of this project are to construct maps of apparent and residual heat flow through the western continental margin of India and to investigate the relationship of residual heat flow anomalies to fluid flow and gas hydrate distribution in the subsurface. Performer Oregon State University, College of Oceanic and Atmospheric Science, Corvallis, OR 97331 Map of the four regions sampled during NGHP Expedition 01 Map of the four regions sampled during NGHP Expedition 01 Background Gas hydrate distribution in sediments depends on methane supply, which in turn depends on fluid flow. When drilling data are available to calibrate seismic observations of the base of the gas hydrate stability zone (GHSZ),

88

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

If you need help finding information on a particular project, please contact the content manager. If you need help finding information on a particular project, please contact the content manager. Search Hydrates Projects Active Projects | Completed Projects Click on project number for a more detailed description of the project. Project Number Project Name Primary Performer DE-FC26-01NT41332 Alaska North Slope Gas Hydrate Reservoir Characterization BP Exploration Alaska, Inc. DE-FC26-01NT41330 Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico: Applications for Safe Exploration Chevron Energy Technology Company DE-FE0009897 Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering/Geological Implications Georgia Tech Research Corporation DE-FE0009904 Structural and Stratigraphic Controls on Methane Hydrate Occurrence and Distribution: Gulf of Mexico, Walker Ridge 313 and Green Canyon 955 Oklahoma State University

89

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermal Properties of Hydrate – Tool Development Last Reviewed 3/18/2013 Thermal Properties of Hydrate – Tool Development Last Reviewed 3/18/2013 Project Goal The goal of this project is increased understanding of gas hydrate thermal properties through measurements on natural hydrate-bearing sediment cores and hydrate-bearing cores formed within laboratory pressure vessels. Project Performers Eilis Rosenbaum, NETL, Office of Research and Development Ronald Lynn, NETL, RDS/Parsons Dr. David Shaw, Geneva College Project Location National Energy Technology Laboratory, Pittsburgh, PA Background NETL utilizes a modified transient plane source (TPS) shown in Figure 1 using a technique originally developed by Gustafsson [1, 2] in a single-sided configuration (Figure 2). The TPS technique is capable of simultaneously determining both thermal conductivity and thermal

90

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gathering, Processing and Evaluating Seismic and Physical Data on Gas Hydrates in the Gulf of Mexico Last Reviewed 02/05/2010 Gathering, Processing and Evaluating Seismic and Physical Data on Gas Hydrates in the Gulf of Mexico Last Reviewed 02/05/2010 DE-AT26-97FT34343 photo of piston core apparatus prior to being dropped Piston core apparatus with 6-ton weight prior to being dropped Photo courtesy USGS Goal The goal of the project is to characterize hydrates in the Gulf of Mexico (GOM) and further develop field techniques for characterizing hydrates. Performer US Geological Survey, Woods Hole Field Center Location Woods Hole Massachusetts Background Oceanic methane hydrates are a major emerging research topic spanning energy resource issues, global climate change, seafloor stability, ocean acoustics, impact on deep marine biota, and a number of special topics. Recent developments in the last five years have both broadened and deepened

91

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Seismic-Scale Rock Physics of Methane Hydrate Seismic-Scale Rock Physics of Methane Hydrate DE-FC26-05NT42663 Goal The goal of this project was to establish rock physics models for use in generating synthetic seismic signatures of methane hydrate reservoirs. Ultimately, the intent was to improve seismic detection and quantification of offshore and onshore methane hydrate accumulations. Performer Stanford University, Stanford, CA 94305 Background Gas hydrate reservoir characterization is, in principle, no different from traditional hydrocarbon reservoir characterization. The seismic response of the subsurface is determined by the spatial distribution of the elastic properties (properties of the subsurface that deform as seismic waves pass through it) and attenuation. By mapping changes in the elastic properties, scientists can identify geologic features, including hydrocarbon reservoirs.

92

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 Methane Recovery from Hydrate-bearing Sediments Last Reviewed 11/30/2011 DE-FC26-06NT42963 Goal The goal of this project is to develop observational and experimental data that can provide a better understanding of the basic mechanisms at work in a methane hydrate reservoir that is under production. To this end, a thorough physical understanding of underlying phenomena associated with methane hydrate production will be acquired through unique, multi-scale experiments and associated analyses. In addition, one or more mathematical models that account for the observed phenomena and provide insights that may help to optimize methane hydrate production methods will be developed. Performers Georgia Tech Research Corporation, Atlanta, Georgia 30332 Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee 37831

93

Overview on Hydrate Coring, Handling and Analysis  

SciTech Connect (OSTI)

Gas hydrates are crystalline, ice-like compounds of gas and water molecules that are formed under certain thermodynamic conditions. Hydrate deposits occur naturally within ocean sediments just below the sea floor at temperatures and pressures existing below about 500 meters water depth. Gas hydrate is also stable in conjunction with the permafrost in the Arctic. Most marine gas hydrate is formed of microbially generated gas. It binds huge amounts of methane into the sediments. Worldwide, gas hydrate is estimated to hold about 1016 kg of organic carbon in the form of methane (Kvenvolden et al., 1993). Gas hydrate is one of the fossil fuel resources that is yet untapped, but may play a major role in meeting the energy challenge of this century. In June 2002, Westport Technology Center was requested by the Department of Energy (DOE) to prepare a ''Best Practices Manual on Gas Hydrate Coring, Handling and Analysis'' under Award No. DE-FC26-02NT41327. The scope of the task was specifically targeted for coring sediments with hydrates in Alaska, the Gulf of Mexico (GOM) and from the present Ocean Drilling Program (ODP) drillship. The specific subjects under this scope were defined in 3 stages as follows: Stage 1: Collect information on coring sediments with hydrates, core handling, core preservation, sample transportation, analysis of the core, and long term preservation. Stage 2: Provide copies of the first draft to a list of experts and stakeholders designated by DOE. Stage 3: Produce a second draft of the manual with benefit of input from external review for delivery. The manual provides an overview of existing information available in the published literature and reports on coring, analysis, preservation and transport of gas hydrates for laboratory analysis as of June 2003. The manual was delivered as draft version 3 to the DOE Project Manager for distribution in July 2003. This Final Report is provided for records purposes.

Jon Burger; Deepak Gupta; Patrick Jacobs; John Shillinglaw

2003-06-30T23:59:59.000Z

94

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope drilled and cored a well The HOT ICE No.1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report.

Thomas E. Williams; Keith Millheim; Buddy King

2004-06-01T23:59:59.000Z

95

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope drilled and cored a well The HOT ICE No.1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report.

Thomas E. Williams; Keith Millheim; Buddy King

2004-07-01T23:59:59.000Z

96

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports.

Thomas E. Williams; Keith Millheim; Bill Liddell

2005-03-01T23:59:59.000Z

97

APPLIED PHYSICS APPLIED PHYSICS  

E-Print Network [OSTI]

MSc APPLIED PHYSICS #12;MSc APPLIED PHYSICS This taught Masters course is based on the strong research in Applied Physics in the University's Department of Physics. The department has an impressive photonics and quantum optics, Physics and the Life Sciences, and solid state physics. The knowledge gained

Mottram, Nigel

98

NETL: Methane Hydrates - DOE/JIP GOM Hydrate Research Cruise  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Core Handling Core Handling From: Cruise Prospectus [PDF-827KB] Visit the Photo Gallery for more pictures showing core handling Non-pressurized and Pressure Core Handling Non-pressurized Core Handling (Fugro Hydraulic Piston Corer and Fugro Corer) Photo of Core packed in ice bath Core packed in ice bath Cores that might contain gas hydrates should be recovered as quickly as possible. An ice bath may be used in some cases to slow the dissociation process. A core reception/preparation van will be on the deck of the Uncle John where individual cores (perhaps up to 9 m long) can be laid on ‘core hooks' and quickly drilled, labeled and sectioned. Infrared (IR) camera imaging will be done as soon as practical after core recovery. Both track-mounted and hand held IR cameras will be used to identify the

99

Gas Hydrate Storage of Natural Gas  

SciTech Connect (OSTI)

Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

Rudy Rogers; John Etheridge

2006-03-31T23:59:59.000Z

100

Structural Investigation of Methane Hydrate Sediments by Microfocus X-ray Computed Tomography Technique under High-Pressure Conditions  

Science Journals Connector (OSTI)

The structure of natural gas hydrate sediments was observed by microfocus X-ray computed tomography (CT). A newly developed high-pressure vessel for the microfocus X-ray CT system was applied to observe the sediments at a temperature above 273 K and under high-pressure conditions. The obtained two-dimensional CT images clearly showed the spatial distribution of the free-gas pore, sand particles, water, and hydrates. These results demonstrated that microfocus X-ray CT can be effective for studying natural gas hydrate sediment samples.

Shigeki Jin; Jiro Nagao; Satoshi Takeya; Yusuke Jin; Junko Hayashi; Yasushi Kamata; Takao Ebinuma; Hideo Narita

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gulf of Mexico Gas Hydrates Joint Industry Project (JIP) Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico - Applications for Safe Exploration and Production Last Reviewed 12/18/2013 Gulf of Mexico Gas Hydrates Joint Industry Project (JIP) Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico - Applications for Safe Exploration and Production Last Reviewed 12/18/2013 DE-FC26-01NT41330 Goal: The goal of this project is to develop technology and collect data to assist in the characterization of naturally occurring gas hydrates in the deep water Gulf of Mexico (GoM). The intent of the project is to better understand the impact of hydrates on safety and seafloor stability as well as provide data for use by scientists in their study of climate change and assessment of the feasibility of marine hydrate as a potential future energy resource. Photo of the Helix Q4000 The Semi-Submersible Helix Q4000 used on the 21 day JIP Leg II Drilling and Logging Expedition

102

Department of Energy Advance Methane Hydrates Science and Technology Projects  

Broader source: Energy.gov [DOE]

Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

103

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the second year of a three-year endeavor being sponsored by Maurer Technology, Noble, and Anadarko Petroleum, in partnership with the DOE. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition. We plan to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. We also plan to design and implement a program to safely and economically drill, core and produce gas from arctic hydrates. The current work scope is to drill and core a well on Anadarko leases in FY 2003 and 2004. We are also using an on-site core analysis laboratory to determine some of the physical characteristics of the hydrates and surrounding rock. The well is being drilled from a new Anadarko Arctic Platform that will have minimal footprint and environmental impact. We hope to correlate geology, geophysics, logs, and drilling and production data to allow reservoir models to be calibrated. Ultimately, our goal is to form an objective technical and economic evaluation of reservoir potential in Alaska.

Thomas E. Williams; Keith Millheim; Buddy King

2004-03-01T23:59:59.000Z

104

Opacity reduction using hydrated lime injection  

SciTech Connect (OSTI)

The purpose of this investigation is to study the effects of injecting dry hydrated lime into flue gas to reduce sulfur trioxide (SO{sub 3}) concentrations and consequently stack opacity at the University of Missouri, Columbia power plant. Burning of high sulfur coal (approx. 4% by weight) at the power plant resulted in opacity violations. The opacity problem was due to sulfuric acid mist (H{sub 2}SO{sub 4}) forming at the stack from high SO{sub 3} concentrations. As a result of light scattering by the mist, a visible plume leaves the stack. Therefore, reducing high concentrations of SO{sub 3} reduces the sulfuric acid mist and consequently the opacity problem. The current hydrated lime injection system has reduced the opacity to acceptable limits. To reduce SO{sub 3} concentrations, dry hydrated lime is injected into the flue gas upstream of a particulate collection device (baghouse) and downstream of the induced draft fan. The lime is periodically injected into the flue via a pneumatic piping system. The hydrated lime is transported down the flue and deposited on the filter bags in the baghouse. As the hydrated lime is deposited on the bags a filter cake is established. The reaction between the SO{sub 3} and the hydrated lime takes place on the filter bags. The hydrated lime injection system has resulted in at least 95% reduction in the SO{sub 3} concentration. Low capital equipment requirements and operating cost coupled with easy installation and maintenance makes the system very attractive to industries with similar problems. This paper documents the hydrated lime injection system and tests the effectiveness of the system on SO{sub 3} removal and subsequent opacity reduction. Measurements Of SO{sub 3} concentrations, flue gas velocities, and temperatures have been performed at the duct work and baghouse. A complete analysis of the hydrated lime injection system is provided.

Wolf, D.E.; Seaba, J.P. [Univ. of Missouri, Columbia, MO (United States)

1993-12-31T23:59:59.000Z

105

New Methane Hydrate Research: Investing in Our Energy Future | Department  

Broader source: Energy.gov (indexed) [DOE]

Methane Hydrate Research: Investing in Our Energy Future Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Jenny Hakun What Are Methane Hydrates? Methane hydrates are 3D ice-lattice structures with natural gas locked inside. The substance looks remarkably like white ice, but it does not behave like ice. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas.

106

Structural Determination of the Hydrophobic Hydration Shell of Kr  

Science Journals Connector (OSTI)

We report the first direct measurement by extended x-ray absorption fine structure spectroscopy of the hydrophobic hydration shell of the noble gas krypton. Measurements were made in aqueous solution at gas pressures in the range 20 to 100 bars and at a temperature of 320 K. Data of excellent quality were collected taking advantage of the high brilliance of a third generation synchrotron radiation source. An advanced data analysis procedure has been applied to determine the Kr-O partial radial distribution function in the short range.

Adriano Filipponi; Daniel T. Bowron; Colin Lobban; John L. Finney

1997-08-18T23:59:59.000Z

107

Methane Hydrate Program Annual Report to Congress  

Broader source: Energy.gov (indexed) [DOE]

FY 2010 FY 2010 Methane Hydrate Program Annual Report to Congress September 2011 U.S. Department of ENERGY United States Department of Energy Washington, DC 20585 Department of Energy | September 2011 FY 2010 Methane Hydrate Program Annual Report to Congress | Page 2 Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled, U.S. Department of Energy FY 2010 Methane Hydrate Program Report to Congress. The report was prepared by the Department of Energy's Office of Fossil Energy and summarizes the progress being made in this important area of

108

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection and Microbiological Analysis of Gas Hydrate Cores Collection and Microbiological Analysis of Gas Hydrate Cores FWP-4340-60 and FWP-42C1-01 Goal Determine the presence and activity of methanogens in methane hydrate-bearing sediments. Background The project was set up to determine a fundamental modeling parameter - the amount of methane generated in deep sediments by methanogenic microorganisms. This would allow methane distribution models of gas hydrate reservoirs to accurately reflect an unknown volume and the distribution of biogenic methane within in a reservoir. The personnel at INEL have experience in similar biologic research and are considered to be experts by their global peers. Performer Idaho National Engineering and Environmental Laboratory (INEEL) - sample collection and analysis Location

109

Arctic Methane, Hydrates, and Global Climate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Arctic Methane, Hydrates, and Global Climate Arctic Methane, Hydrates, and Global Climate Speaker(s): Matthew T. Reagan Date: March 17, 2010 - 12:00pm Location: 90-3122 Paleooceanographic evidence has been used to postulate that methane may have had a significant role in regulating past climate. However, the behavior of contemporary permafrost deposits and oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. A recent expedition to the west coast of Spitsbergen discovered substantial methane gas plumes exiting the seafloor at depths that correspond to the upper limit of the receding gas hydrate stability zone. It has been suggested that these plumes may be the

110

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 Methane Hydrate Production from Alaskan Permafrost Last Reviewed 02/05/2010 DE-FC26-01NT41331 photo of new Anadarko drilling rig in place at Hot Ice No.1 on Alaska's North Slope Hot Ice No. 1 Drilling Platform courtesy Anadarko Petroleum Corp. Goal The goal of the project was to develop technologies for drilling and recovering hydrates in arctic areas. The specific objectives were to drill, core, and test a well through the hydrate stability zone in northern Alaska Performers Maurer Technology, Inc.* - Project coordination with DOE Anadarko Petroleum Corporation - Overall project management for the design, construction, and operation of the Arctic Drilling Platform and mobile core lab, and field coring operations Noble Engineering and Development* - Real time data collection and

111

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 Assessing the Efficacy of the Aerobic Methanotropic Biofilter in Methane Hydrate Environments Last Reviewed 1/8/2013 DE-NT0005667 Goal The goal of this project is to assess the efficacy of aerobic methanotrophy in preventing the escape of methane from marine, hydrate-bearing reservoirs to the atmosphere and ultimately to better define the role of aerobic methanotrophy in the global carbon cycle. Graph overlayed on photo - Methane seeps with the resulting methane plume Methane seeps with the resulting methane plume, Geophysical Research Letters, November 2007 Performers University of California – Santa Barbara, Santa Barbara (UCSB), CA 93106 Background The global methane reservoir in the form of gas hydrate is estimated at 500–10,000 Gt (KVENVOLDEN, 1995; MILKOV, 2004). This pool of carbon

112

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterizing Arctic Hydrates (Canadian Test Well and Alaskan "Wells of Opportunity") Characterizing Arctic Hydrates (Canadian Test Well and Alaskan "Wells of Opportunity") photo of drilling rig at Mallik 2L-38 location Rig at Mallik 2L-38 location courtesy Geological Survey of Canada DE-AT26-97FT34342 Goal The purpose of this project is to assess the recoverability and potential production characteristics of the onshore natural gas hydrate and associated free-gas accumulations in the Arctic of North America Performer United States Geological Survey, Denver, Colorado 80225 - partner in GSC-managed consortium and provide expertise in data gathering and analysis Background The U.S. Geological Survey has been participating in natural gas hydrate reservoir research with DOE NETL through an interagency agreement which began in the early 1980’s. The work has been an ongoing effort as part of

113

ConocoPhillips Gas Hydrate Production Test  

SciTech Connect (OSTI)

Work began on the ConocoPhillips Gas Hydrates Production Test (DOE award number DE-NT0006553) on October 1, 2008. This final report summarizes the entire project from January 1, 2011 to June 30, 2013.

Schoderbek, David; Farrell, Helen; Howard, James; Raterman, Kevin; Silpngarmlert, Suntichai; Martin, Kenneth; Smith, Bruce; Klein, Perry

2013-06-30T23:59:59.000Z

114

Gas hydrate formation in fine sand  

Science Journals Connector (OSTI)

Gas hydrate formation from two types of dissolved gas (methane and mixed gas) was studied under varying thermodynamic conditions in ... Sea. The testing media consisted of silica sand particles with diameters of ...

XiaoYa Zang; DeQing Liang; NengYou Wu

2013-04-01T23:59:59.000Z

115

Weakening of ice by magnesium perchlorate hydrate  

E-Print Network [OSTI]

I show that perchlorate hydrates, which have been indirectly detected at high Martian circumpolar latitudes by the Phoenix Mars Lander, have a dramatic effect upon the rheological behavior of polycrystalline water ice under ...

Lenferink, Hendrik J., 1985-

2012-01-01T23:59:59.000Z

116

Hydrate Control for Gas Storage Operations  

SciTech Connect (OSTI)

The overall objective of this project was to identify low cost hydrate control options to help mitigate and solve hydrate problems that occur in moderate and high pressure natural gas storage field operations. The study includes data on a number of flow configurations, fluids and control options that are common in natural gas storage field flow lines. The final phase of this work brings together data and experience from the hydrate flow test facility and multiple field and operator sources. It includes a compilation of basic information on operating conditions as well as candidate field separation options. Lastly the work is integrated with the work with the initial work to provide a comprehensive view of gas storage field hydrate control for field operations and storage field personnel.

Jeffrey Savidge

2008-10-31T23:59:59.000Z

117

Methane Hydrate Field Studies | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Field Studies Field Studies Methane Hydrate Field Studies Arctic/Alaska North Slope Field Studies Since 2001, DOE has conducted field trials of exploration and production technology in the Alaska North Slope. Although Alaska methane hydrate resources are smaller than marine deposits and currently lack outlets to commercial markets, Alaska provides an excellent laboratory to study E&P technology. The research also has implications for various Alaska resources, including potential gas hydrate resources for local communities, conventional "stranded" gas, as well as Alaska's large unconventional oil resources. The hydrate deposits have been delineated in the process of developing underlying oil fields, and drilling costs are much lower than offshore. DOE-BP Project

118

Metal-Catalyzed Hydration of 2-Pyridyloxirane  

E-Print Network [OSTI]

In the presence of CuII the hydration of 2-pyridyloxiran is accelerated 18,000-fold, and its reaction with Cl, Br, and MeO becomes 100% regiospecific for ?-attack.

Hanzlik, Robert P.; Michaely, William J.

1975-01-01T23:59:59.000Z

119

Methane Hydrates R&D Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

abundance suggest that they contain perhaps more organic carbon that all the world's oil, gas, and coal combined. The primary mission of the Methane Hydrates R&D Program is to...

120

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists planning hydrate exploration and development projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this and other project reports. This Topical Report contains details describing logging operations.

Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

2005-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored a well (the Hot Ice No. 1) on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports. Documenting the results of this effort are key to extracting lessons learned and maximizing the industry's benefits for future hydrate exploitation. In addition to the Final Report, several companion Topical Reports are being published.

Thomas E. Williams; Keith Millheim; Bill Liddell

2004-11-01T23:59:59.000Z

122

Presentations from the March 27th - 28th Methane Hydrates Advisory...  

Broader source: Energy.gov (indexed) [DOE]

the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting International Gas Hydrate...

123

Microsoft Word - Oct2011_Semi-Annual Report_Hydrates_GRID-Arendal.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

October October 15 2011 2 ADMINISTRATIVE SUMMARY The UNEP Global Outlook on Methane Gas Hydrates project has received funding from the US Department of Energy under award number DE-FE0003060. The project director is Yannick Beaudoin and the recipient institution is Stiftelsen GRID-Arendal in Arendal, Norway. The current report is for the period starting April 1, 2010 and ending September 30, 2011. EXECUTIVE SUMMARY The UNEP Global Outlook on Methane Gas Hydrates seeks to provide policy makers, the gen- eral public and the media with a synthesis of aspects of natural, social and applied sciences that relate to this type of natural gas occurrence. With an emphasis on visual media, the Outlook is working to define global methane gas hydrate occurrences in their natural settings and examine

124

Controls on Gas Hydrate Formation and Dissociation  

SciTech Connect (OSTI)

The main objectives of the project were to monitor, characterize, and quantify in situ the rates of formation and dissociation of methane hydrates at and near the seafloor in the northern Gulf of Mexico, with a focus on the Bush Hill seafloor hydrate mound; to record the linkages between physical and chemical parameters of the deposits over the course of one year, by emphasizing the response of the hydrate mound to temperature and chemical perturbations; and to document the seafloor and water column environmental impacts of hydrate formation and dissociation. For these, monitoring the dynamics of gas hydrate formation and dissociation was required. The objectives were achieved by an integrated field and laboratory scientific study, particularly by monitoring in situ formation and dissociation of the outcropping gas hydrate mound and of the associated gas-rich sediments. In addition to monitoring with the MOSQUITOs, fluid flow rates and temperature, continuously sampling in situ pore fluids for the chemistry, and imaging the hydrate mound, pore fluids from cores, peepers and gas hydrate samples from the mound were as well sampled and analyzed for chemical and isotopic compositions. In order to determine the impact of gas hydrate dissociation and/or methane venting across the seafloor on the ocean and atmosphere, the overlying seawater was sampled and thoroughly analyzed chemically and for methane C isotope ratios. At Bush hill the pore fluid chemistry varies significantly over short distances as well as within some of the specific sites monitored for 440 days, and gas venting is primarily focused. The pore fluid chemistry in the tub-warm and mussel shell fields clearly documented active gas hydrate and authigenic carbonate formation during the monitoring period. The advecting fluid is depleted in sulfate, Ca Mg, and Sr and is rich in methane; at the main vent sites the fluid is methane supersaturated, thus bubble plumes form. The subsurface hydrology exhibits both up-flow and down-flow of fluid at rates that range between 0.5 to 214 cm/yr and 2-162 cm/yr, respectively. The fluid flow system at the mound and background sites are coupled having opposite polarities that oscillate episodically between 14 days to {approx}4 months. Stability calculations suggest that despite bottom water temperature fluctuations, of up to {approx}3 C, the Bush Hill gas hydrate mound is presently stable, as also corroborated by the time-lapse video camera images that did not detect change in the gas hydrate mound. As long as methane (and other hydrocarbon) continues advecting at the observed rates the mound would remain stable. The {_}{sup 13}C-DIC data suggest that crude oil instead of methane serves as the primary electron-donor and metabolic substrate for anaerobic sulfate reduction. The oil-dominated environment at Bush Hill shields some of the methane bubbles from being oxidized both anaerobically in the sediment and aerobically in the water column. Consequently, the methane flux across the seafloor is higher at Bush hill than at non-oil rich seafloor gas hydrate regions, such as at Hydrate Ridge, Cascadia. The methane flux across the ocean/atmosphere interface is as well higher. Modeling the methane flux across this interface at three bubble plumes provides values that range from 180-2000 {_}mol/m{sup 2} day; extrapolating it over the Gulf of Mexico basin utilizing satellite data is in progress.

Miriam Kastner; Ian MacDonald

2006-03-03T23:59:59.000Z

125

NETL: Methane Hydrates - DOE/NETL Projects - Natural Gas Hydrates in  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Gas Hydrates in Permafrost and Marine Settings: Resources, Properties, and Environmental Issues Last Reviewed 12/30/2013 Natural Gas Hydrates in Permafrost and Marine Settings: Resources, Properties, and Environmental Issues Last Reviewed 12/30/2013 DE-FE0002911 Goal The objective of this DOE-USGS Interagency Agreement is to provide world-class expertise and research in support of the goals of the 2005 Energy Act for National Methane Hydrates R&D, the DOE-led U.S. interagency roadmap for gas hydrates research, and elements of the USGS mission related to energy resources, global climate, and geohazards. This project extends USGS support to the DOE Methane Hydrate R&D Program previously conducted under DE-AI26-05NT42496. Performer U.S. Geological Survey at Woods Hole, MA, Denver, CO, and Menlo Park, CA Background The USGS Interagency Agreement (IA) involves laboratory research and

126

Natural gas hydrates on the continental slope off Pakistan: constraints from seismic techniques  

Science Journals Connector (OSTI)

......2000 research-article Articles Natural gas hydrates on the continental slope...J. Int. (2000) 140, 295310 Natural gas hydrates on the continental slope...adequate gas supplies for hydrate Natural gas hydrates (clathrates) are a crystalline......

Ingo Grevemeyer; Andreas Rosenberger; Heinrich Villinger

2000-02-01T23:59:59.000Z

127

Methane Hydrate Formation and Dissocation in a Partially Saturated Sand--Measurements and Observations  

E-Print Network [OSTI]

Energy Technology Laboratory Methane Hydrates Research Group USA Arvind Gupta Colorado School of Mines Center for Hydrate Research USA ABSTRACT

2005-01-01T23:59:59.000Z

128

Methane Hydrate Formation and Dissociation in a Partially Saturated Core-Scale Sand Sample  

E-Print Network [OSTI]

Energy Technology Laboratory Methane Hydrates Research Group USA Arvind Gupta Colorado School of Mines Center for Hydrate Research USA ABSTRACT

2005-01-01T23:59:59.000Z

129

International Cooperation in Methane Hydrates | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Oil & Gas » Methane Hydrate » Oil & Gas » Methane Hydrate » International Cooperation in Methane Hydrates International Cooperation in Methane Hydrates In 1982 the multi-national Deep Sea Drilling Program (DSDP) recovered the first subsea substantial methane hydrate deposits, which spurred methane hydrate research in the US and other countries. The successor programs, the Ocean Drilling Program (ODP) and the Integrated Ocean Drilling Program (IODP) sampled hydrate deposits off Oregon (ODP 204, 2002) and in the Cascadia Margin off Vancouver Island, Canada (ODP 146, 1992 and IODP 311, 2005). In the Atlantic Ocean off the US, ODP Leg 146 sampled hydrate deposits on the Blake Ridge and Carolina Rise in 1995. International cooperation helps scientists in the US and other countries

130

DPF -"Hydrated EGR" Fuel Saver System | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Saver System DPF -"Hydrated EGR" Fuel Saver System GreenPower muffler uses hydrated exhaust gas recirculation to reduce NOx and improve fuel efficiency deer08rim.pdf More...

131

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Numerical Simulation Last Reviewed 3/8/2013 Numerical Simulation Last Reviewed 3/8/2013 Project Goal The goal of NETL's gas hydrate numerical simulation studies is to obtain pertinent, high-quality information on the behavior of gas hydrates in their natural environment under either production (methane gas extraction) or climate change scenarios. This research is closely linked with NETL's experimental and field studies programs to ensure the validity of input datasets and scenarios. Project Performers Brian Anderson, NETL/RUA Fellow (West Virginia University) Hema Siriwardane, NETL/RUA Fellow (West Virginia University) Eugene Myshakin, NETL/URS Project Locations National Energy Technology Laboratory, Pittsburgh PA, and Morgantown WV West Virginia University, Morgantown, WV Background Field-scale hydrate production tests rely heavily on reservoir-scale

132

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gulf of Mexico Gas Hydrates Sea-floor Observatory Project Last Reviewed 12/18/2013 Gulf of Mexico Gas Hydrates Sea-floor Observatory Project Last Reviewed 12/18/2013 DE-FE26-06NT42877, DE-FC26-02NT41628, and DE-FC26-00NT40920 Goal The goal of this project is to conduct activities leading to the development, implementation, and operation of a remote, multi-sensor seafloor observatory focused on behavior of the marine hydrocarbon system within the gas hydrate stability zone of the deepwater Gulf of Mexico and analysis of data resultant from that observatory over time. Attaining this goal will lead to an enhanced understanding of the role the hydrocarbon system plays in the environment surrounding the site. Investigations include physical, chemical, and microbiological studies. Models developed from these studies are designed to provide a better understanding of gas

133

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields Phase 1 - Characterization and Qualification of the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields DE-FC26-06NT42962 Goal The goal of this project is to characterize and quantify the postulated gas hydrate resource associated with the Barrow Gas Fields – three producing fields located in a permafrost region near Barrow, the North Slope's biggest population center and economic hub. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Map of the North Slope Borough showing the location of its eight major communities, including Barrow, the site of this research project. Performers North Slope Borough, Barrow, Alaska (North Slope Borough) 99723

134

Method for production of hydrocarbons from hydrates  

DOE Patents [OSTI]

A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl.sub.2 or CaBr.sub.2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl.sub.2 /CaBr.sub.2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl.sub.2 /CaBr.sub.2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

McGuire, Patrick L. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

135

MethaneHydrateRD_FC.indd  

Broader source: Energy.gov (indexed) [DOE]

gas is an important energy gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy (FE) has played a major role in developing technologies to help tap new, unconventional sources of natural gas. FOSSIL ENERGY RESEARCH BENEFITS Methane Hydrate R&D "The (DOE) Program has supported and managed a high-quality research portf olio that has enabled signifi cant progress toward the (DOE) Program's long-term goals." The Nati onal Academies 2010 One of these is methane hydrate - molecules of natural gas trapped in ice crystals. Containing vast amounts of natural gas, methane hydrate occurs in a variety of forms in sediments within and below thick permafrost in Arctic regions, and in the

136

CHARACTERIZATION OF MIXED CO2-TBPB HYDRATE FOR REFRIGERATION APPLICATIONS  

E-Print Network [OSTI]

in a dynamic loop and an Ostwald-de Waele model was obtained. Keywords: CO2, TBPB, mixed hydrates, solubility

Paris-Sud XI, Université de

137

Potential effects of gas hydrate on human welfare  

Science Journals Connector (OSTI)

...distribution of gas hydrate (Fig. 4). According...sediment) of methane hydrate is 10-fold greater...unconventional sources of gas, such as coal beds, tight sands, black shales...conventional natural gas. Given these attractive...that natural gas hydrate could serve as...

Keith A. Kvenvolden

1999-01-01T23:59:59.000Z

138

Measurement and modeling of hydrate dissociation: Final report  

SciTech Connect (OSTI)

Natural gas could be recovered from hydrate deposits by either of two basic methods (1) thermal stimulation in which an external source of energy is provided and (2) lowering of the equilibrium pressure (depressurization) in which the energy of the hydrate-containing and the surrounding media is utilized. In this work, we have measured and modeled mathematically the dissociation of hydrates in consolidated and unconsolidated porous media. Hydrates were formed in laboratory samples of Ottawa sand and Berea sandstone using miscible and non-miscible hydrate formers. A state-of-the-art, computer-controlled transient hot wire needle probe apparatus was developed for the measurements of thermal conductivity of pure hydrates and hydrate-containing porous media. We have measured the thermal conductivity of hydrate-containing Ottawa sand and Berea sandstone samples in order to determine the physical properties necessary for the mathematical models. We have also measured the electric resistivity of methane hydrate-containing Berea sandstone in order to verify the formation of the hydrate and to track the dissociation front during hydrate depressurization. Two mathematical models were developed for the process of hydrate dissociation in porous media using the two recovery schemes thermal stimulation and depressurization. 10 refs., 9 figs., 1 tab.

Sloan, E.D.; Selim, M.S.

1988-04-01T23:59:59.000Z

139

The goal of this work is to quantify the Van der Waals interactions in systems involving gas hydrates. Gas hydrates are crystalline com-  

E-Print Network [OSTI]

gas hydrates. Gas hydrates are crystalline com- pounds that are often encountered in oil and gas briefly present the hydrate crystalline structure and the role of hydrates in oil-and gas industry the industrial contexts where they appear, we shall cite : hydrate plugs obstructing oil- or gas

Boyer, Edmond

140

NETL: Methane Hydrates - DOE/NETL Projects - Estimate Gas-Hydrate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Last Reviewed 6/14/2013 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Last Reviewed 6/14/2013 DE-FC26-06NT42959 Goal The goal of this project is to evaluate the direct-current electrical resistivity (DCR) method for remotely detecting and characterizing the concentration of gas hydrates in the deep marine environment. This will be accomplished by adapting existing DCR instrumentation for use on the sea floor in the deep marine environment and testing the new instrumentation at Mississippi Canyon Block 118. Performer Baylor University, Waco, TX 76798 Collaborators Advanced Geosciences Inc., Austin, TX 78726 Specialty Devices Inc., Wylie, TX 75098 Background Marine occurrences of methane hydrates are known to form in two distinct

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

NETL: Methane Hydrates - DOE/NETL Projects - Properties of Hydrate-Bearing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Properties of Hydrate-Bearing Sediments Subjected to Changing Gas Compositions Last Reviewed 12/11/2013 Properties of Hydrate-Bearing Sediments Subjected to Changing Gas Compositions Last Reviewed 12/11/2013 ESD12-011 Goal The objective of this research is to measure physical, chemical, mechanical, and hydrologic property changes in methane hydrate-bearing sediments subjected to injection of carbon dioxide and nitrogen. Performer Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA 94720 Background A number of studies have investigated the impact of injecting carbon dioxide (CO2) and CO2-nitrogen (N2) mixtures into methane hydrate for the purpose of sequestering CO2 and releasing methane (CH4), and review articles have been published summarizing the literature. Most of these studies have investigated the fundamental physical/chemical nature of the exchange of CO2 and/or N2 with CH4 in the clathrate. These studies have

142

NETL: Methane Hydrates - Gas Hydrate Research in Deep Sea Sediments - New  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrate Research in Deep Sea Sediments - Chatham Rise, New Zealand Task Last Reviewed 12/30/2013 Hydrate Research in Deep Sea Sediments - Chatham Rise, New Zealand Task Last Reviewed 12/30/2013 DE-AI26-06NT42878 Goal The goal of the Interagency Agreement between the National Energy Technology Laboratory and the Naval Research Laboratory is to conduct research to enhance understanding of the extent and dynamics of gas hydrate deposits and their relation to areas of focused fluid flux at and beneath the seafloor. Performer Marine Biogeochemistry Section, Naval Research Laboratory, Washington, DC 20375 Background Methane is a potent greenhouse gas necessitating a better understanding of the mechanisms controlling its contribution to the atmospheric carbon cycle. Active methane fluxes (from deep sediment hydrates and seeps) contribute to shallow sediment biogeochemical carbon cycles, which in turn

143

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Hydrate Research in Deep Sea Sediments - New Zealand Task Gas Hydrate Research in Deep Sea Sediments - New Zealand Task DE-AI26-06NT42878 Goal The objective of this research is to determine the extent and dynamics of gas hydrate deposits and their relation to areas of focused fluid flux at and beneath the seafloor. Specific objectives include: a). Refine geophysical, geochemical and microbiological technologies for prospecting hydrate distribution and content; b). Contribute to establishing high-priority geographical regions of prospective interest, in terms of methane volume estimates; c). Prediction of environmental effects and geologic risks at the continental margin associated to the natural resource occurrence and resource exploitation; and d). Expand understanding of the biogeochemical parameters and associated microbial community diversity in shallow sediments that influence the porewater sulfate gradient observed through anaerobic oxidation of methane. To accomplish these objectives, the Naval Research Laboratory (NRL) collaborated with New Zealand’s Institute of Geological and Nuclear Sciences (GNS) in a research cruise off the coast of New Zealand. NRL has conducted similar research cruises off the west coast and east coast of the United States, in the Gulf of Mexico and off the coast of Chile.

144

Dynamics of Kr in dense clathrate hydrates  

Science Journals Connector (OSTI)

The dynamics of Kr atoms as guests in dense clathrate hydrate structures are investigated using site specific Kr83 nuclear resonant inelastic x-ray scattering (NRIXS) spectroscopy in combination with molecular dynamics simulations. The dense structure H hydrate and filled-ice structures are studied at high pressures in a diamond anvil high-pressure cell. The dynamics of Kr in the structure H clathrate hydrate quench recovered at 77 K is also investigated. The Kr phonon density of states obtained from the experimental NRIXS data are compared with molecular dynamics simulations. The temperature and pressure dependence of the phonon spectra provide details of the Kr dynamics in the clathrate hydrate cages. Comparison with the dynamics of Kr atoms in the low-pressure structure II obtained previously was made. The Lamb-Mossbauer factor obtained from NRIXS experiments and molecular dynamics calculations are in excellent agreement and are shown to yield unique information on the strength and temperature dependence of guest-host interactions.

D. D. Klug; J. S. Tse; J. Y. Zhao; W. Sturhahn; E. E. Alp; C. A. Tulk

2011-05-25T23:59:59.000Z

145

Stable Conditions of Marine Gas Hydrate  

Science Journals Connector (OSTI)

Figure9.7 shows the P-T...curve determined by the temperature-pressure method in a sediment-water-methane-hydrate system (natural sand of 20?40, 40?60, and 220?240mesh). Methane gas is injected into the reactor...

Shicai Sun; Yuguang Ye; Changling Liu; Jian Zhang

2013-01-01T23:59:59.000Z

146

Storage capacity of hydrogen in tetrahydrothiophene and furan clathrate hydrates  

Science Journals Connector (OSTI)

The storage capacity of hydrogen in the tetrahydrothiophene and furan hydrates was investigated by means of pressurevolumetemperature measurement. The hydrogenabsorption rate of tetrahydrothiophene and furan hydrates is much larger than that of tetrahydrofuran hydrate in spite of same crystal structure (structure-II). The storage amount of hydrogen at 275.1K is about 1.2mol (hydrogen)/mol (tetrahydrothiophene or furan hydrate) (?0.6mass%) at 41.5MPa, which is coincident with that of tetrahydrofuran hydrate.

Takaaki Tsuda; Kyohei Ogata; Shunsuke Hashimoto; Takeshi Sugahara; Masato Moritoki; Kazunari Ohgaki

2009-01-01T23:59:59.000Z

147

Detection of gas hydrates by the measurement of instantaneous temperature  

E-Print Network [OSTI]

. Changes, either in temperature or pressure, can cause the hydrate to dissociate. In situ gas hydrates were discovered in the permafrost region of the Soviet Union and have been typically The Journal of Geotechnical En ineerin of the American Society... to detect hydrates. Both of these methods, illustrated in Fig. 6, may not detect hydrates in the form of nodules or thin layers. Hence it is necessary to develop a local method to detect Ocean Floor BASE QE GAS HYDRATE PIG. 5. Bottom Simulating...

Dinakaran, Srikanth

2012-06-07T23:59:59.000Z

148

Methane Hydrates - The National R&D Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Hydrates R&D Program Methane Hydrates R&D Program The National Methane Hydrates R&D Program Welcome to the information portal for the National Methane Hydrate R&D Program. Over the past eight years, research carried out under this program has resulted in significant advances in our understanding of methane hydrates, their role in nature, and their potential as a future energy resource. This success is largely due to an unprecedented level of cooperation between federal agencies, industry, national laboratories, and academic institutions. For a quick introduction to methane hydrate and its potential as a fuel source, please read the 2011 Methane Hydrates Primer. Information on other elements of the program can be found under the remaining Key Links. Read More.

149

Methane Hydrates and Climate Change | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrates and Climate Change Hydrates and Climate Change Methane Hydrates and Climate Change Methane hydrates store huge volumes of methane formed by the bacterial decay of organic matter or leaked from underlying oil and natural gas deposits. The active formation of methane hydrates in the shallow crust prevents methane, a greenhouse gas, from entering the atmosphere. On the other hand, warming of arctic sediments or ocean waters has the potential to cause methane hydrate to dissociate, releasing methane into the deepwater sediments, the ocean or atmosphere. DOE is conducting research to understand the mechanisms and volumes involved in these little-studied processes. DOE environmental and climate change research projects related to Arctic methane hydrate deposits include: Characterization of Methane Degradation and Methane-Degrading

150

Comparative Assessment of Advanced Gay Hydrate Production Methods  

SciTech Connect (OSTI)

Displacing natural gas and petroleum with carbon dioxide is a proven technology for producing conventional geologic hydrocarbon reservoirs, and producing additional yields from abandoned or partially produced petroleum reservoirs. Extending this concept to natural gas hydrate production offers the potential to enhance gas hydrate recovery with concomitant permanent geologic sequestration. Numerical simulation was used to assess a suite of carbon dioxide injection techniques for producing gas hydrates from a variety of geologic deposit types. Secondary hydrate formation was found to inhibit contact of the injected CO{sub 2} regardless of injectate phase state, thus diminishing the exchange rate due to pore clogging and hydrate zone bypass of the injected fluids. Additional work is needed to develop methods of artificially introducing high-permeability pathways in gas hydrate zones if injection of CO{sub 2} in either gas, liquid, or micro-emulsion form is to be more effective in enhancing gas hydrate production rates.

M. D. White; B. P. McGrail; S. K. Wurstner

2009-06-30T23:59:59.000Z

151

AN INTERNATIONAL EFFORT TO COMPARE GAS HYDRATE RESERVOIR SIMULATORS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AN INTERNATIONAL EFFORT TO COMPARE GAS HYDRATE RESERVOIR SIMULATORS Joseph W. Wilder 1 , George J. Moridis 2 , Scott J. Wilson 3 , Masanori Kurihara 4 , Mark D. White 5 , Yoshihiro Masuda 6 , Brian J. Anderson 7, 8 *, Timothy S. Collett 9 , Robert B. Hunter 10 , Hideo Narita 11 , Mehran Pooladi-Darvish 12 , Kelly Rose 7 , Ray Boswell 7 1 Department of Theoretical & Applied Math University of Akron 302 Buchtel Common Akron, OH 44325-4002 USA 2 Lawrence Berkeley National Laboratory, University of California Earth Sciences Division, 1 Cyclotron Rd., MS 90-1116 Berkeley, CA 94720 USA 3 Ryder Scott Company, Petroleum Consultants 621 17th Street, Suite 1550 Denver, Colorado 80293 USA 4 Japan Oil Engineering Company, Ltd. Kachidoki Sun-Square 1-7-3, Kachidoki, Chuo-ku,

152

Evidence for natural gas hydrate occurrences in Colombia Basin  

SciTech Connect (OSTI)

Multichannel and selected single-channel seismic lines of the continental margin sediments of the Colombia basin display compelling evidence for large accumulations of natural gas hydrate. Seismic bottom simulating reflectors (BSRs), interpreted to mark the base of the hydrate stability zone, are pronounced and very widespread along the entire Panama-Colombia lower continental slope. BSRs have also been identified at two locations on the abyssal plain. Water depths for these suspected hydrate occurrences range from 900 to 4000 m. Although no gas hydrate samples have been recovered from this area, biogenic methane is abundant in Pliocene turbidites underlying the abyssal plain. More deeply buried rocks beneath the abyssal plain are thermally mature. Thermogenic gas from these rocks may migrate upward along structural pathways into the hydrate stability zone and form hydrate. Impermeable hydrate layers may form caps over large accumulations of free gas, accounting for the very well-defined BSRs in the area. The abyssal plain and the deformed continental margin hold the highest potential for major economic accumulations of gas hydrate in the basin. The extensive continuity of BSRs, relatively shallow water depths, and promixity to onshore production facilities render the marginal deformed belt sediments the most favorable target for future economic development of the gas hydrate resource within the Colombia basin. The widespread evidence of gas hydrates in the Colombia basin suggests a high potential for conventional hydrocarbon deposits offshore of Panama and Colombia.

Finley, P.D.; Krason, J.; Dominic, K.

1987-05-01T23:59:59.000Z

153

NETL: Methane Hydrates - ANS Research Project  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The Alaska North Slope Stratigraphic Test Well The Alaska North Slope Stratigraphic Test Well image showing Donyon Rig Photo courtesy Doyon Drilling Inc Project Background Participants Status Report Maps of Research Area Science Plan Photo Gallery Well log Data From BP-DOE-US "Mount Elbert" Test Is Now Available. Digital well log data acquired at the February 2007 gas hydrates test well at Milne Point, Alaska are now available. Data include Gamma ray, neutron porosity, density porosity, three-dimensional high resolution resistivity, acoustics including compressional- and shear-wave data and nuclear magnetic resonance. A listing of the available data, as well as instructions on obtaining the data, can be found on the NETL Gas Hydrates Website . The drilling of the “Mt. Elbert prospect” within the Milne Point Unit

154

NETL: Methane Hydrates - ANS Research Project  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Well - Location Maps Well - Location Maps Maps of Prospect The Mt. Elbert prospect is located within the Milne Point Unit on Alaska’s North Slope. The Milne Point field, one of a number of distinct oil fields on the North Slope, extends offshore into the Beaufort Sea and is situated north of the large Kuparuk Field and northwest of the well known Prudhoe Bay Field. Map showing project location Map showing Milne Point Unit on Alaska’s North Slope The work done under the “Alaska North Slope Gas Hydrate Reservoir Characterization” project has resulted in a characterization of two large prospective methane hydrate accumulations (or trends); the Eileen Trend, which underlies but extends well beyond the Milne Point field, and the Tarn Trend to the west of the Kuparuk Field.

155

Detection and Production of Methane Hydrate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oil & Natural Gas Technology Oil & Natural Gas Technology DOE Award No.: DE-FC26-06NT42960 Quarterly Progress Report Reporting Period: April-June 2007 Detection and Production of Methane Hydrate Submitted by: Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Prepared for: United States Department of Energy National Energy Technology Laboratory August, 2007 Office of Fossil Energy Detection and Production of Methane Hydrate Quarterly Progress Report Reporting Period: April-June 2007 Prepared by: George Hirasaki Rice University August 2007 CONTRACT NO. DE-FC26-06NT42960 Department of Chemical and Biomolecular Engineering Rice University - MS 362 6100 Main St. Houston, TX 77251-1892 Phone: 713-348-5416; Fax: 713-348-5478; Email: gjh@rice.edu

156

A statistical mechanical description of biomolecular hydration  

SciTech Connect (OSTI)

We present an efficient and accurate theoretical description of the structural hydration of biological macromolecules. The hydration of molecules of almost arbitrary size (tRNA, antibody-antigen complexes, photosynthetic reaction centre) can be studied in solution and in the crystal environment. The biomolecular structure obtained from x-ray crystallography, NMR, or modeling is required as input information. The structural arrangement of water molecules near a biomolecular surface is represented by the local water density analogous to the corresponding electron density in an x-ray diffraction experiment. The water-density distribution is approximated in terms of two- and three-particle correlation functions of solute atoms with water using a potentials-of-mean-force expansion.

NONE

1996-02-01T23:59:59.000Z

157

Wax and hydrate control with electrical power  

SciTech Connect (OSTI)

Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the gas/water phase may freeze solid with hydrate particles. The paper discusses thermal-insulated flowlines, heat-loss compensation with electrical power, electrical power consumption and operation, and subsea electrical-power distribution system.

NONE

1997-08-01T23:59:59.000Z

158

Methane Hydrate Production Technologies to be Tested on Alaska's North  

Broader source: Energy.gov (indexed) [DOE]

Methane Hydrate Production Technologies to be Tested on Alaska's Methane Hydrate Production Technologies to be Tested on Alaska's North Slope Methane Hydrate Production Technologies to be Tested on Alaska's North Slope October 24, 2011 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy, the Japan Oil, Gas and Metals National Corporation, and ConocoPhillips will work together to test innovative technologies for producing methane gas from hydrate deposits on the Alaska North Slope. The collaborative testing will take place under the auspices of a Statement of Intent for Cooperation in Methane Hydrates signed in 2008 and extended in 2011 by DOE and Japan's Ministry of Economy, Trade, and Industry. The production tests are the next step in both U.S. and Japanese national efforts to evaluate the response of gas hydrate reservoirs to alternative

159

NETL: Methane Hydrates - DOE/NETL Projects - Measurement and Interpretation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement and Interpretation of Seismic Velocities and Attenuation in Hydrate-Bearing Sediments Last Reviewed 12/18/2013 Measurement and Interpretation of Seismic Velocities and Attenuation in Hydrate-Bearing Sediments Last Reviewed 12/18/2013 DE-FE0009963 Goal The primary project objectives are to relate seismic and acoustic velocities and attenuations to hydrate saturation and texture. The information collected will be a unique dataset in that seismic attenuation will be acquired within the seismic frequency band. The raw data, when combined with other measurements (e.g., complex resistivity, micro-focus x-ray computed tomography, etc.), will enable researchers to understand not only the interaction between mineral surfaces and gas hydrates, but also how the hydrate formation method affects the hydrate-sediment system in terms of elastic properties. An over-arching goal of this research is to calibrate geophysical

160

History of the Development of Low Dosage Hydrate Inhibitors  

Science Journals Connector (OSTI)

Low dosage hydrate inhibitors (LDHIs) are a recent and alternative technology to thermodynamic inhibitors for preventing gas hydrates from plugging oil and gas production wells and pipelines. ... A wide range of OPEX savings, possible extended field lifetime and multi-million dollar CAPEX savings, are economic drivers for choosing LDHIs instead of other hydrate prevention methods.2 ... A second apparatus is the ball-stop rig or rocker rig. ...

Malcolm A. Kelland

2006-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Detection and evaluation methods for in-situ gas hydrates  

SciTech Connect (OSTI)

With the increased interest in naturally occuring hydrates, the need for improved detection and evaluation methods has also increased. In this paper, logging of hydrates is discussed and selected logs from four arctic wells are examined. A new procedure based on temperature log analysis is described. The concept of a downhole heater for use with drill stem testing is also described for testing and evaluation of hydrate intervals. 12 refs.

Goodman, M.A.; Guissani, A.P.; Alger, R.P.

1982-01-01T23:59:59.000Z

162

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member and/or six member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

163

Strategies for gas production from oceanic Class 3 hydrate accumulations  

E-Print Network [OSTI]

Mexico, Fire In The Ice: NETL Methane Hydrates R&D Programand Kelly Boswell of DOE-NETL for making the Tigershark data

Moridis, George J.; Reagan, Matthew T.

2007-01-01T23:59:59.000Z

164

Methane Hydrate Formation and Dissociation in a Partially Saturated Core-Scale Sand Sample  

E-Print Network [OSTI]

gas system and the sand/hydrate/water/gas systems, as wellproperties of the sand/water/gas system, hydrate formation,saturated sand/water/gas (s/w/g) system, hydrate formation,

2005-01-01T23:59:59.000Z

165

Methane Hydrate Formation and Dissocation in a Partially Saturated Sand--Measurements and Observations  

E-Print Network [OSTI]

gas system and the sand/hydrate/water/gas systems, as wellproperties of the sand/water/gas system, hydrate formation,saturated sand/water/gas (s/w/g) system, hydrate formation,

2005-01-01T23:59:59.000Z

166

Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico  

E-Print Network [OSTI]

Documented Example of Gas Hydrate Saturated Sand in the Gulfthat observed for gas hydrate-bearing sand sediments in thethan those for the gas hydrate-bearing sand formations in

Boswell, R.D.

2010-01-01T23:59:59.000Z

167

Feasibility of monitoring gas hydrate production with time-lapse VSP  

E-Print Network [OSTI]

Documented Example of Gas Hydrate Saturated Sand in the Gulfmoduli for the sand/gas/water/hydrate mixture with theK eff for the sand/gas/aqueous/hydrate mixture is calculated

Kowalsky, M.B.

2010-01-01T23:59:59.000Z

168

Laboratory measurements on core-scale sediment/hydrate samples to predice reservoir behavior  

E-Print Network [OSTI]

top) and for the sand/hydrate/water/gas system (bottom),3.145 W / m K for the sand/hydrate/water/gas system (watertop-left) and the sand-hydrate-water-gas system (bottom-

Kneafsey, Timothy J.; Seol, Yongkoo; Moridis, George J.; Tomutsa, Liviu; Freifeld, Barry M.

2008-01-01T23:59:59.000Z

169

Challenges, uncertainties and issues facing gas production from gas hydrate deposits  

E-Print Network [OSTI]

conductivity of gas hydrate-bearing sand. J. Geophys. Res.seal overlying gas hydrate-bearing sand reservoirs togeologic data on gas-hydrate-bearing sand reservoirs in the

Moridis, G.J.

2011-01-01T23:59:59.000Z

170

Physical property changes in hydrate-bearing sediment due to depressurization and subsequent repressurization  

E-Print Network [OSTI]

documented example of gas hydrate saturated sand in the Gulfa volume of water to gas hydrate in sands at these pressureseffects of hydrate redistribution in cemented, gas-rich sand

Waite, W.F.

2008-01-01T23:59:59.000Z

171

Hydration-dependent dynamics of deeply cooled water under strong confinement  

E-Print Network [OSTI]

We have measured the hydration-level dependence of the single-particle dynamics of water confined in the ordered mesoporous silica MCM-41. The dynamic crossover observed at full hydration is absent at monolayer hydration. ...

Bertrand, C. E.

172

Presentations from June 6-7 2013 Methane Hydrates Advisory Meeting...  

Broader source: Energy.gov (indexed) [DOE]

June 6-7 2013 Methane Hydrates Advisory Meeting Presentations from June 6-7 2013 Methane Hydrates Advisory Meeting ConocoPhillips test results and data analysis Methane Hydrate...

173

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network [OSTI]

hydrates, Fire In The Ice, NETL Methane Hydrates R&D ProgramCanada, Fire In The Ice, NETL Methane Hydrates R&D Programat MMS, Fire In The Ice, NETL Methane Hydrates R&D Program

Moridis, George J.

2008-01-01T23:59:59.000Z

174

X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well  

E-Print Network [OSTI]

Gas hydrate formation in a variable volume bed of silica sandamount of sand, gas, and water. Although methane hydrate has

Kneafsey, T.J.

2012-01-01T23:59:59.000Z

175

CX-010982: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Mechanisms for Methane Transport and Hydrate Accumulation in Coarse-Grained Sediments CX(s) Applied: A9 Date: 09/13/2013 Location(s): Ohio Offices(s): National Energy Technology Laboratory

176

CX-010983: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Mechanisms for Methane Transport and Hydrate Accumulation in Coarse-Grained Sediments CX(s) Applied: A9 Date: 09/13/2013 Location(s): New York Offices(s): National Energy Technology Laboratory

177

CX-009285: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering... CX(s) Applied: A1, A9, B3.6 Date: 09/07/2012 Location(s): Georgia Offices(s): National Energy Technology Laboratory

178

CX-011282: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Mechanisms for Methane Transport and Hydrate Accumulation in Coarse-Grained Sediments CX(s) Applied: A9 Date: 09/26/2013 Location(s): Texas Offices(s): National Energy Technology Laboratory

179

Scaled-Up Ocean Injection of CO2Hydrate Composite Particles  

Science Journals Connector (OSTI)

Institute of Ocean Sciences of Fisheries and Oceans, Canada, 9860 West Saanich Road, P.O. ... For example, with a release of 100 kg/s (e.g., from a 400-MW power plant(28)), the smallest particles are predicted to sink ?9 times further as part of a plume, than as individual particles, whereas the largest particles will sink to the bottom of the seafloor regardless of whether a plume forms. ... Further studies are needed to address hydrate conversion efficiency, scale-up criteria, sequestration longevity, and impact on the ocean biota before in situ prodn. of sinking CO2 hydrate composite can be applied to oceanic CO2 storage and sequestration. ...

C. Tsouris; P. Szymcek; P. Taboada-Serrano; S. D. McCallum; P. Brewer; E. Peltzer; P. Walz; E. Adams; A. Chow; W. K. Johnson; J. Summers

2007-10-02T23:59:59.000Z

180

Macromolecular hydration compared with preferential hydration and their role on macromolecule-osmolyte coupled diffusionwz  

E-Print Network [OSTI]

to solute hydration and size ratio and is not complicated by other factors such as ionic interactions should not be neglected in multicomponent-diffusion theoretical models even when ionic interactions quantities that shape the thermodynamic and diffusion behavior of macromolecule­additive­water solutions.1

Annunziata, Onofrio

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Studies of Reaction Kinetics of Methane Hydrate Dissocation in Porous Media  

E-Print Network [OSTI]

sand cores partially satu- rated with water, hydrate and CH 4 gas,the formation of hydrates. For the sand/water/gas/CH 4 -

Moridis, George J.; Seol, Yongkoo; Kneafsey, Timothy J.

2005-01-01T23:59:59.000Z

182

Gas hydrates in the Gulf of Mexico  

E-Print Network [OSTI]

filled by one or more gases. In marine sediments gas hydrates are found in regions where high pressure, low temperature and gas in excess of solubility are present. Low molecular weight hydrocarbons (LMWH), I. e. methane through butane, carbon dioxide... loop at a helium carrier flow of 12 ml/min with an elution order of methane, ethane, carbon dioxide and propane. Each fraction was trapped in a U- shaped Porpak-Q filled glass tube immersed in LN2. Butanes and heartier weight gases were trapped...

Cox, Henry Benjamin

1986-01-01T23:59:59.000Z

183

Design Options for Avoiding Hydrates in Deep Offshore Production  

Science Journals Connector (OSTI)

Hydrate blockage in subsea systems is responsible for a portion of lost profits in several deepwater oil fields. ... Additionally, in this scenario, the logistic for hydrate remediation, if a rig is required, is even more complex due to the greater distance from shore. ...

Carlos A. B. R. Cardoso; Marcelo A. L. Gonalves; Ricardo M. T. Camargo

2014-10-10T23:59:59.000Z

184

Rock-physics Models for Gas-hydrate Systems Associated  

E-Print Network [OSTI]

Rock-physics Models for Gas-hydrate Systems Associated with Unconsolidated Marine Sediments Diana associated with unconsolidated marine sediments. The goals are to predict gas-hydrate concentration from intercalated with unconsolidated sediments. We show that the geometrical details of how gas hy- drates

Texas at Austin, University of

185

Effects of Antiagglomerants on the Interactions between Hydrate Particles  

E-Print Network [OSTI]

production Introduction The undesirable formation of gas hydrates in natural gas pipelines, and their prevention is a problem that has received considerable interest. In subsea pipelines, the presence of water of hydrates. These crystalline compounds can agglomerate and form plugs in the pipelines. The costs associated

Firoozabadi, Abbas

186

Energy Department Advances Research on Methane Hydrates - the World's  

Broader source: Energy.gov (indexed) [DOE]

Research on Methane Hydrates - the Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource Energy Department Advances Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource August 31, 2012 - 1:00pm Addthis Washington, DC - The Energy Department today announced the selection of 14 new research projects across 11 states that will be a part of an expanding portfolio of projects designed to increase our understanding of methane hydrates' potential as a future energy supply. Methane hydrates are 3D ice-lattice structures with natural gas locked inside, and are found both onshore and offshore - including under the Arctic permafrost and in ocean sediments along nearly every continental shelf in the world. Today's projects build on the completion of a successful, unprecedented test

187

NETL: Methane Hydrates - Barrow Gas Fields - North Slope Borough, Alaska  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phase 2- Drilling and Production Testing the Methane Hydrate Resource Potential associated with the Barrow Gas Fields Last Reviewed 04/06/2010 Phase 2- Drilling and Production Testing the Methane Hydrate Resource Potential associated with the Barrow Gas Fields Last Reviewed 04/06/2010 DE-FC26-06NT42962 Goal The goal of this project is to evaluate, design, drill, log, core and production test methane hydrate resources in the Barrow Gas Fields near Barrow, Alaska to determine its impact on future free gas production and its viability as an energy source. Photo of Barrow welcome sign Performers North Slope Borough, Barrow, Alaska 99723 Petrotechnical Resources Alaska (PRA), Fairbanks, AK 99775 University of Alaska Fairbanks, Fairbanks, AK 99775 Background Phase 1 of the Barrow Gas Fields Hydrate Study provided very strong evidence for the existence of hydrates updip of the East Barrow and Walakpa Gas Fields. Full-field history matched reservoir modeling supported the

188

NETL: Methane Hydrates - DOE/NETL Projects - Temporal Characterization of  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Temporal Characterization of Hydrates System Dynamics Beneath Seafloor Mounds Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters Last Reviewed 12/18/2013 Temporal Characterization of Hydrates System Dynamics Beneath Seafloor Mounds Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters Last Reviewed 12/18/2013 DE-FE0010141 Goal The overall objective of the project is to investigate hydrate system dynamics beneath seafloor mounds—a structurally focused example of hydrate occurrence at the landward extreme of their stability field—in the northern Gulf of Mexico. Researchers will conduct observatory-based in situ measurements at Woolsey Mound, MC118 to: Characterize (geophysically) the sub-bottom distribution of hydrate and its temporal variability and, Contemporaneously record relevant environmental parameters (temperature, pressure, salinity, turbidity, bottom currents, and seafloor

189

Energy Department Advances Research on Methane Hydrates - the World's  

Broader source: Energy.gov (indexed) [DOE]

Energy Department Advances Research on Methane Hydrates - the Energy Department Advances Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource Energy Department Advances Research on Methane Hydrates - the World's Largest Untapped Fossil Energy Resource August 31, 2012 - 1:20pm Addthis News Media Contact (202) 586-4940 WASHINGTON, D.C. - The Energy Department today announced the selection of 14 new research projects across 11 states that will be a part of an expanding portfolio of projects designed to increase our understanding of methane hydrates' potential as a future energy supply. Methane hydrates are 3D ice-lattice structures with natural gas locked inside, and are found both onshore and offshore - including under the Arctic permafrost and in ocean sediments along nearly every continental shelf in the world.

190

METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

METHANE HYDRATE ADVISORY COMMITTEE METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy Advisory Committee Charter - - - - ---- ---- ------~ 1. Committee's Official Designation. Methane Hydrate Advisory Committee (MHAC) 2. Authority:. This charter establishes the Methane Hydrate Advisory Committee (Committee) pursuant to Title IX, Subtitle F, Section 968, Methane Hydrate Research of the Energy Policy Act of 2005 (EPACT), Public Law 109-58. This charter establishes the MHAC under the authority of the Department of Energy (DOE). The MHAC is being renewed in accordance with the provisions of the Federal Advisory Committee Act (FACA), as amended, 5 U.S.C., App.2. 3. Objectives and Scope of Activities. The Committee provides advice to the Secretary of Energy by developing recommendations and broad programmatic priorities for the methane

191

Seismic-Scale Rock Physics of Methane Hydrate  

SciTech Connect (OSTI)

We quantify natural methane hydrate reservoirs by generating synthetic seismic traces and comparing them to real seismic data: if the synthetic matches the observed data, then the reservoir properties and conditions used in synthetic modeling might be the same as the actual, in-situ reservoir conditions. This approach is model-based: it uses rock physics equations that link the porosity and mineralogy of the host sediment, pressure, and hydrate saturation, and the resulting elastic-wave velocity and density. One result of such seismic forward modeling is a catalogue of seismic reflections of methane hydrate which can serve as a field guide to hydrate identification from real seismic data. We verify this approach using field data from known hydrate deposits.

Amos Nur

2009-01-08T23:59:59.000Z

192

NETL: Methane Hydrates - DOE/NETL Projects - Structural and Stratigraphic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structural and Stratigraphic Controls on Methane Hydrate Occurrence and Distribution: Gulf of Mexico, Walker Ridge 313 and Green Canyon 955 Last Reviewed 12/24/2013 Structural and Stratigraphic Controls on Methane Hydrate Occurrence and Distribution: Gulf of Mexico, Walker Ridge 313 and Green Canyon 955 Last Reviewed 12/24/2013 DE-FE0009904 Goal The goal of this project is to determine structural and stratigraphic controls on hydrate occurrence and distribution in Green Canyon (GC) 955 and Walker Ridge (WR) 313 blocks with special emphasis on hydrate-bearing sand reservoirs. Structural and stratigraphic controls on hydrate distribution are examined by jointly analyzing surface-towed, multichannel seismic (MCS) and Ocean Bottom Seismometer (OBS) data and well logs through a combination of pre-stack depth migration (PSDM), traveltime and full-waveform inversion (FWI), and rock physics modeling methods. Performers Oklahoma State University, Stillwater, OK 74078-1026

193

DOE Announces $2 Million Funding for Methane Hydrates Projects | Department  

Broader source: Energy.gov (indexed) [DOE]

DOE Announces $2 Million Funding for Methane Hydrates Projects DOE Announces $2 Million Funding for Methane Hydrates Projects DOE Announces $2 Million Funding for Methane Hydrates Projects November 7, 2005 - 12:43pm Addthis Seeks to Unlock World's Biggest Potential Source of "Ice That Burns" WASHINGTON, DC - The Department of Energy (DOE) today announced a total of $2 million in funding to five research projects that will assess the energy potential, safety, and environmental aspects of methane hydrate exploration and development. Termed the "ice that burns," methane hydrates are crystalline solids that release a flammable gas when melted. They are considered the Earth's biggest potential source of hydrocarbon energy and could be a key element in meeting natural gas demand in the United States,

194

HYDRATE DISSOCIATION IN A 1-D DOMAIN  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

HYDRATE DISSOCIATION IN A 1-D DOMAIN HYDRATE DISSOCIATION IN A 1-D DOMAIN I. Domain Description 1-D Cartesian system, L x W x H = 1.5 m x 1.0 m x 1.0 m Discretization: 30 x 1 x 1 in (x,y,z) Uniform Δx = 0.05 m each; Δy = Δz = 1 m II. Initial Conditions Pressure: P i = 8 MPa Temperature: T i = 2 o C (for thermal stimulation), T i = 6 o C (for depressurization) Saturations: S H = 0.5, S A = 0.5, S G = 0.0 III. Boundary Conditions At x = X max : No mass or heat flow At x = 0: Constant S A = 1.0 (1) Constant P 0 = P i Constant T 0 = 45 o C Thermal stimulation (2) Constant T 0 = T i = 6 o C Constant P 0 = 2.8 MPa Depressurization to a pressure above the Q-point, no ice formation (3) Constant T 0 = T i = 6 o C Constant P 0 = 0.5 MPa Depressurization to a pressure below the Q-point,

195

SIAM J. NUMER. ANAL. c 2007 Society for Industrial and Applied Mathematics Vol. 45, No. 1, pp. 389420  

E-Print Network [OSTI]

[8], frozen or partially frozen sandstones [29, 10, 11], gas-hydrates in ocean-bottom sediments [12, and Cavallini [8] applied this theory to study the acoustic properties of shaley sandstones, assuming that sand

Sheen, Dongwoo

196

NETL: Methane Hydrates - DOE/NETL Projects - NT42496  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conducting Scientific Studies of Natural Gas Hydrates to Support the DOE Efforts to Evaluate and Understand Methane Hydrates Last Reviewed 05/16/2011 Conducting Scientific Studies of Natural Gas Hydrates to Support the DOE Efforts to Evaluate and Understand Methane Hydrates Last Reviewed 05/16/2011 DE-AI26-05NT42496 Goal The United States Geological Survey (USGS) conducts scientific studies of natural gas hydrates in support of DOE efforts to evaluate and understand methane hydrates, their potential as an energy resource, and the hazard they may pose to ongoing drilling efforts. This project extends USGS support to the DOE Methane Hydrate Research Program previously supported under DE-AT26-97FT34342 and DE-AT26-97FT34343. Performer U.S. Geological Survey at Denver, CO, Woods Hole, MA, and Menlo Park, CA. Background The USGS Interagency Agreement (IA) involves laboratory research and international field studies in which DOE/NETL has a significant interest.

197

E ects of the Driving Force on the Composition of Natural Gas Hydrates  

E-Print Network [OSTI]

E ects of the Driving Force on the Composition of Natural Gas Hydrates Odd I. Levik(1) , Jean for storage and transport of natural gas. Storage of natural gas in the form of hydrate at elevated pressure concept) (Gud- mundsson et al. 1998). Natural gas hydrate contains up to 182 Sm3 gas per m3 hydrate

Gudmundsson, Jon Steinar

198

The sensitivity of seismic responses to gas hydrates  

SciTech Connect (OSTI)

The sensitivity of seismic reflection coefficients and amplitudes, and their variations with changing incidence angles and offsets, was determined with respect to changes in the parameters which characterize marine sediments containing gas hydrates. Using the results of studies of ice saturation effects in permafrost soils, we have introduced rheological effects of hydrate saturation. The replacement of pore fluids in highly porous and unconsolidated marine sediments with crystalline gas hydrates, increases the rigidity of the sediments, and alters the ratio of compressional/shear strength ratio. This causes Vp/Vs ratio variations which have an effect on the amplitudes of P-wave and S-wave reflections. Analysis of reflection coefficient functions has revealed that amplitudes are very sensitive to porosity estimates, and errors in the assumed model porosity can effect the estimates of hydrate saturation. Additionally, we see that the level of free gas saturation is difficult to determine. A review of the effects of free gas and hydrate saturation on shear wave arrivals indicates that far-offset P to S wave converted arrivals may provide a means of characterizing hydrate saturations. Complications in reflection coefficient and amplitude modelling can arise from gradients in hydrate saturation levels and from rough sea floor topography. An increase in hydrate saturation with depth in marine sediments causes rays to bend towards horizontal and increases the reflection incidence angles and subsequent amplitudes. This effect is strongly accentuated when the vertical separation between the source and the hydrate reflection horizon is reduced. The effect on amplitude variations with offset due to a rough sea floor was determined through finite difference wavefield modelling. Strong diffractions in the waveforms add noise to the amplitude versus offset functions.

Foley, J.E.; Burns, D.R.

1992-08-01T23:59:59.000Z

199

The sensitivity of seismic responses to gas hydrates. Final report  

SciTech Connect (OSTI)

The sensitivity of seismic reflection coefficients and amplitudes, and their variations with changing incidence angles and offsets, was determined with respect to changes in the parameters which characterize marine sediments containing gas hydrates. Using the results of studies of ice saturation effects in permafrost soils, we have introduced rheological effects of hydrate saturation. The replacement of pore fluids in highly porous and unconsolidated marine sediments with crystalline gas hydrates, increases the rigidity of the sediments, and alters the ratio of compressional/shear strength ratio. This causes Vp/Vs ratio variations which have an effect on the amplitudes of P-wave and S-wave reflections. Analysis of reflection coefficient functions has revealed that amplitudes are very sensitive to porosity estimates, and errors in the assumed model porosity can effect the estimates of hydrate saturation. Additionally, we see that the level of free gas saturation is difficult to determine. A review of the effects of free gas and hydrate saturation on shear wave arrivals indicates that far-offset P to S wave converted arrivals may provide a means of characterizing hydrate saturations. Complications in reflection coefficient and amplitude modelling can arise from gradients in hydrate saturation levels and from rough sea floor topography. An increase in hydrate saturation with depth in marine sediments causes rays to bend towards horizontal and increases the reflection incidence angles and subsequent amplitudes. This effect is strongly accentuated when the vertical separation between the source and the hydrate reflection horizon is reduced. The effect on amplitude variations with offset due to a rough sea floor was determined through finite difference wavefield modelling. Strong diffractions in the waveforms add noise to the amplitude versus offset functions.

Foley, J.E.; Burns, D.R.

1992-08-01T23:59:59.000Z

200

NETL: Methane Hydrates - DOE/NETL Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High-Resolution Sidescan Sonar and Multibeam Bathymetric Data Collection and Processing, Atwater Canyon, Gulf of Mexico High-Resolution Sidescan Sonar and Multibeam Bathymetric Data Collection and Processing, Atwater Canyon, Gulf of Mexico DE-AT26-97FT34344 photo of DTAGS seismic source being deployed DTAG seismic source being deployed courtesy Naval Research Laboratory Goal: During February 14-18, 2005, a scientific cruise was conducted using the R/V Pelican to obtain high-resolution sidescan sonar and multibeam bathymetric data of Mounds D and F in the Atwater Valley area of the Gulf of Mexico, to better characterize sites selected for experimental drilling by the ChevronTexaco Gas Hydrates Joint Industry Project (JIP). Performers: Naval Research Lab - Dr. Joan Gardner Location: Washington, DC 20375 Atwater Valley, Gulf of Mexico Background: During May, 2004 the Naval Research Lab (NRL) collected piston cores and

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Molecular dynamics simulation of hydration in myoglobin  

SciTech Connect (OSTI)

This study was carried out to evaluate the stability of the 89 bound water molecules that were observed in the neutron diffraction study of CO myoglobin. The myoglobin structure derived from the neutron analysis was used as the starting point in the molecular dynamics simulation using the software package CHARMM. After salvation of the protein, energy minimization and equilibration of the system, 50 pico seconds of Newtonian dynamics was performed. This data showed that only 4 water molecules are continously bound during the length of this simulation while the other solvent molecules exhibit considerable mobility and are breaking and reforming hydrogen bonds with the protein. At any instant during the simulation, 73 of the hydration sites observed in the neutron structure are occupied by water.

Gu, Wei [New Mexico Univ., Albuquerque, NM (United States). Dept. of Biochemistry; Schoenborn, B.P. [Los Alamos National Lab., NM (United States)

1995-09-01T23:59:59.000Z

202

The growth rate of gas hydrate from refrigerant R12  

SciTech Connect (OSTI)

Experimental and theoretical investigations were presented dealing with three phase direct-contact heat transfer by evaporation of refrigerant drops in an immiscible liquid. Refrigerant R12 was used as the dispersed phase, while water and brine were the immiscible continuous phase. A numerical solution is presented to predict the formation rate of gas hydrates in test column. The solution provided an acceptable agreement when compared with experimental results. The gas hydrate growth rate increased with time. It increased with increasing dispersed phase flow rate. The presence of surface-active sodium chloride in water had a strong inhibiting effect on the gas hydrate formation rate. (author)

Kendoush, Abdullah Abbas; Jassim, Najim Abid [Centre of Engineering Physics, Ministry of Sciences and Technology, P.O. Box 765, Baghdad (Iraq); Joudi, Khalid A. [Al-Nahrain University, Baghdad (Iraq)

2006-07-15T23:59:59.000Z

203

Examination of Hydrate Formation Methods: Trying to Create Representative Samples  

SciTech Connect (OSTI)

Forming representative gas hydrate-bearing laboratory samples is important so that the properties of these materials may be measured, while controlling the composition and other variables. Natural samples are rare, and have often experienced pressure and temperature changes that may affect the property to be measured [Waite et al., 2008]. Forming methane hydrate samples in the laboratory has been done a number of ways, each having advantages and disadvantages. The ice-to-hydrate method [Stern et al., 1996], contacts melting ice with methane at the appropriate pressure to form hydrate. The hydrate can then be crushed and mixed with mineral grains under controlled conditions, and then compacted to create laboratory samples of methane hydrate in a mineral medium. The hydrate in these samples will be part of the load-bearing frame of the medium. In the excess gas method [Handa and Stupin, 1992], water is distributed throughout a mineral medium (e.g. packed moist sand, drained sand, moistened silica gel, other porous media) and the mixture is brought to hydrate-stable conditions (chilled and pressurized with gas), allowing hydrate to form. This method typically produces grain-cementing hydrate from pendular water in sand [Waite et al., 2004]. In the dissolved gas method [Tohidi et al., 2002], water with sufficient dissolved guest molecules is brought to hydrate-stable conditions where hydrate forms. In the laboratory, this is can be done by pre-dissolving the gas of interest in water and then introducing it to the sample under the appropriate conditions. With this method, it is easier to form hydrate from more soluble gases such as carbon dioxide. It is thought that this method more closely simulates the way most natural gas hydrate has formed. Laboratory implementation, however, is difficult, and sample formation is prohibitively time consuming [Minagawa et al., 2005; Spangenberg and Kulenkampff, 2005]. In another version of this technique, a specified quantity of gas is placed in a sample, then the sample is flooded with water and cooled [Priest et al., 2009]. We have performed a number of tests in which hydrate was formed and the uniformity of the hydrate formation was examined. These tests have primarily used a variety of modifications of the excess gas method to make the hydrate, although we have also used a version of the excess water technique. Early on, we found difficulties in creating uniform samples with a particular sand/ initial water saturation combination (F-110 Sand, {approx} 35% initial water saturation). In many of our tests we selected this combination intentionally to determine whether we could use a method to make the samples uniform. The following methods were examined: Excess gas, Freeze/thaw/form, Freeze/pressurize/thaw, Excess gas followed by water saturation, Excess water, Sand and kaolinite, Use of a nucleation enhancer (SnoMax), and Use of salt in the water. Below, each method, the underlying hypothesis, and our results are briefly presented, followed by a brief conclusion. Many of the hypotheses investigated are not our own, but were presented to us. Much of the data presented is from x-ray CT scanning our samples. The x-ray CT scanner provides a three-dimensional density map of our samples. From this map and the physics that is occurring in our samples, we are able to gain an understanding of the spatial nature of the processes that occur, and attribute them to the locations where they occur.

Kneafsey, T.J.; Rees, E.V.L.; Nakagawa, S.; Kwon, T.-H.

2011-04-01T23:59:59.000Z

204

Newly Installed Alaska North Slope Well Will Test Innovative Hydrate  

Broader source: Energy.gov (indexed) [DOE]

Newly Installed Alaska North Slope Well Will Test Innovative Newly Installed Alaska North Slope Well Will Test Innovative Hydrate Production Technologies Newly Installed Alaska North Slope Well Will Test Innovative Hydrate Production Technologies May 17, 2011 - 1:00pm Addthis Washington, DC - A fully instrumented well that will test innovative technologies for producing methane gas from hydrate deposits has been safely installed on the North Slope of Alaska. As a result, the "Iġnik Sikumi" (Iñupiaq for "fire in the ice") gas hydrate field trial well will be available for field experiments as early as winter 2011-12. The well, the result of a partnership between ConocoPhillips and the Office of Fossil Energy's (FE) National Energy Technology Laboratory, will test a technology that involves injecting carbon dioxide (CO2) into sandstone

205

Energy Department Expands Research into Methane Hydrates, a Vast, Untapped  

Broader source: Energy.gov (indexed) [DOE]

Expands Research into Methane Hydrates, a Vast, Expands Research into Methane Hydrates, a Vast, Untapped Potential Energy Resource of the U.S. Energy Department Expands Research into Methane Hydrates, a Vast, Untapped Potential Energy Resource of the U.S. November 20, 2013 - 12:08pm Addthis NEWS MEDIA CONTACT (202) 586-4940 WASHINGTON - Today, U.S. Energy Secretary Ernest Moniz announced nearly $5 million in funding across seven research projects nationwide designed to increase our understanding of methane hydrates - a large, completely untapped natural gas resource-and what it could mean for the environment, as well as American economic competiveness and energy security. "The recent boom in natural gas production - in part due to long-term Energy Department investments beginning in the 70's and 80's - has had

206

NETL: Methane Hydrates - DOE/NETL Projects - Verification Of Capillary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Verification Of Capillary Pressure Functions And Relative Permeability Equations For Modeling Gas Production From Gas Hydrates Last Reviewed 12/12/2013 Verification Of Capillary Pressure Functions And Relative Permeability Equations For Modeling Gas Production From Gas Hydrates Last Reviewed 12/12/2013 DE-FE0009927 Goal The goal of this project is to verify and validate the capillary pressure functions and relative permeability equations that are frequently used in hydrate numerical simulators. In order to achieve this goal, numerical simulation using a network model will be used to suggest fitting parameters, modify existing equations or, if necessary, develop new equations for better simulation results. Performers Wayne State University, Detroit, MI 48202-3622 Background Numerical simulation is used to estimate and predict long-term behavior of hydrate-bearing sediments during gas production [Kurihara et al., 2008;

207

2D Ising model for hydrated protein surfaces  

Science Journals Connector (OSTI)

To understand the nature of the glassy dielectric relaxation recently observed in hydrated protein powders, we model the protein surface as a 2D Ising square net, and identify frustration at the...

G. Careri

208

Chloral Hydrate Warning Author(s): Martyn T. Smith  

E-Print Network [OSTI]

Chloral Hydrate Warning Author(s): Martyn T. Smith Source: Science, New Series, Vol. 250, No. 4979 associated with its use. MARTYNT. SMITH DepartmentofBiomedicaland EnvironmentalHealthSciences, Schoolof

California at Berkeley, University of

209

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, E.D. Jr.

1995-07-11T23:59:59.000Z

210

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

211

Drilling through gas hydrates formations: possible problems and suggested solution  

E-Print Network [OSTI]

Gas hydrate research in the last two decades has taken various directions ranging from ways to understand the safe and economical production of this enormous resource to drilling problems. as more rigs and production platforms move into deeper...

Amodu, Afolabi Ayoola

2009-05-15T23:59:59.000Z

212

Measurement of Gas Hydrate by Laser Raman Spectrometry  

Science Journals Connector (OSTI)

Four types of natural sand (respectively 250350, 180250, 125 ... ) are used as media to synthesize methane hydrate that is measured by laser Raman spectrometry. ... show that sediment grain sizes do not influen...

Changling Liu; Qingguo Meng; Yuguang Ye

2013-01-01T23:59:59.000Z

213

Experiments on Hydrocarbon Gas Hydrates in Unconsolidated Sand  

Science Journals Connector (OSTI)

Experiments were carried out to observe the formation and decomposition of hydrocarbon gas hydrates in an unconsolidated sand pack 4.4 cm in diameter and ... 43 bars and 5 to 10C; gas used was 90% methane and 10...

P. E. Baker

1974-01-01T23:59:59.000Z

214

Gas hydrate detection and mapping on the US east coast  

SciTech Connect (OSTI)

Project objectives are to identify and map gas hydrate accumulations on the US eastern continental margin using remote sensing (seismic profiling) techniques and to relate these concentrations to the geological factors that-control them. In order to test the remote sensing methods, gas hydrate-cemented sediments will be tested in the laboratory and an effort will be made to perform similar physical tests on natural hydrate-cemented sediments from the study area. Gas hydrate potentially may represent a future major resource of energy. Furthermore, it may influence climate change because it forms a large reservoir for methane, which is a very effective greenhouse gas; its breakdown probably is a controlling factor for sea-floor landslides; and its presence has significant effect on the acoustic velocity of sea-floor sediments.

Ahlbrandt, T.S.; Dillon, W.P.

1993-12-31T23:59:59.000Z

215

Membrane Ion Channels and Ionic Hydration Energies [Abstract Only  

Science Journals Connector (OSTI)

25 November 1980 research-article Membrane Ion Channels and Ionic Hydration Energies [Abstract Only] D. T. Edmonds The Royal Society is collaborating with JSTOR to digitize, preserve, and extend access to Proceedings...

1980-01-01T23:59:59.000Z

216

An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs...  

Open Energy Info (EERE)

approach for exploration of gas hydrate reservoirs in marine areas. Authors C. Y. Sun, B. H. Niu, P. F. Wen, Y. Y. Huang, H. Y. Wang, X. W. Huang and J. Li Published Journal...

217

Natural Gas Hydrate Dissociation by Presence of Ethylene Glycol  

Science Journals Connector (OSTI)

Natural Gas Hydrate Dissociation by Presence of Ethylene Glycol ... solids that form from mixts. of water and light natural gases such as methane, carbon dioxide, ethane, propane and butane. ... Pulse Combustion Characteristics of Various Gaseous Fuels ...

Shuanshi Fan; Yuzhen Zhang; Genlin Tian; Deqing Liang; Dongliang Li

2005-11-08T23:59:59.000Z

218

Ultrasonic velocity measurements for synthetic gas?hydrate samples  

Science Journals Connector (OSTI)

Laboratory ultrasonic methods offer a way of studying acoustic velocity of a gas?hydrate bearing formation. By measuringultrasonic velocities of the gas?hydrate samples in various temperature and pressure conditions more effective inversion techniques can be developed to quantitatively evaluate gas?hydrate concentration and distributions. Low?temperature laboratory measurements of compressional velocities in compacted samples are conducted. These gas?hydrate samples are synthesized by using various densities at various pressures and temperatures. At ?10C the compressional velocities of the compacted gas?hydrate samples are from 2440 to 3570 m/s with the density range from 475 to 898 kg/m3. Compressional velocity measurements are made where the temperature and pressure can be controlled. When the pore pressure increases from 10 to 40 MPa the compressional velocities of the sample increases from 2340 to 2600 m/s at 1.5C. When the temperature decreases from 10 to ?13C the compressional velocity will increase from 3600 to 3800 m/s at a pore pressure of 6 MPa. Our experimental results are qualitatively in agreement with those of weighted average model and the Biot?Gassmanns model when the gas?hydrate concentration in a sediment bearing sand is about 20%. [Work supported by National Natural Science Fundation of China No. 10534040.

2006-01-01T23:59:59.000Z

219

Applied Science  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Applied Science Applied Science Correlation of predicted and measured iron oxidation states in mixed iron oxides H. D. Rosenfeld and W. L. Holstein Development of a quantitative measurement of a diesel spray core using synchrotron x-rays C.F. Powell, Y. Yue, S. Gupta, A. McPherson, R. Poola, and J. Wang Localized phase transformations by x-ray-induced heating R.A. Rosenberg, Q. Ma, W. Farrell, E.D. Crozier, G.J. Soerensen, R.A. Gordon, and D.-T. Jiang Resonant x-ray scattering at the Se edge in ferroelectric liquid crystal materials L. Matkin, H. Gleeson, R. Pindak, P. Mach, C. Huang, G. Srajer, and J. Pollmann Synchrotron-radiation-induced anisotropic wet etching of GaAs Q. Ma, D.C. Mancini, and R.A. Rosenberg Synchrotron-radiation-induced, selective-area deposition of gold on

220

Use of computed X-ray tomographic data for analyzing the thermodynamics of a dissociating porous sand/hydrate mixture  

SciTech Connect (OSTI)

X-ray computed tomography (CT) is a method that has been used extensively in laboratory experiments for measuring rock properties and fluid transport behavior. More recently, CT scanning has been applied successfully to detect the presence and study the behavior of naturally occurring hydrates. In this study, we used a modified medical CT scanner to image and analyze the progression of a dissociation front in a synthetic methane hydrate/sand mixture. The sample was initially scanned under conditions at which the hydrate is stable (atmospheric pressure and liquid nitrogen temperature, 77 K). The end of the sample holder was then exposed to the ambient air, and the core was continuously scanned as dissociation occurred in response to the rising temperature. CT imaging captured the advancing dissociation front clearly and accurately. The evolved gas volume was monitored as a function of time. Measured by CT, the advancing hydrate dissociation front was modeled as a thermal conduction problem explicitly incorporating the enthalpy of dissociation, using the Stefan moving-boundary-value approach. The assumptions needed to perform the analysis consisted of temperatures at the model boundaries. The estimated value for thermal conductivity of 2.6 W/m K for the remaining water ice/sand mixture is higher than expected based on conduction alone; this high value may represent a lumped parameter that incorporates the processes of heat conduction, methane gas convection, and any kinetic effects that occur during dissociation. The technique presented here has broad implications for future laboratory and field testing that incorporates geophysical techniques to monitor gas hydrate dissociation.

Freifeld, Barry M.; Kneafsey, Timothy J.; Tomutsa, Liviu; Stern, Laura A.; Kirby, Stephen H.

2002-02-28T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Use of Computed X-ray Tomographic Data for Analyzing the Thermodynamics of a Dissociating Porous Sand/Hydrate Mixture  

DOE R&D Accomplishments [OSTI]

X-ray computed tomography (CT) is a method that has been used extensively in laboratory experiments for measuring rock properties and fluid transport behavior. More recently, CT scanning has been applied successfully to detect the presence and study the behavior of naturally occurring hydrates. In this study, we used a modified medical CT scanner to image and analyze the progression of a dissociation front in a synthetic methane hydrate/sand mixture. The sample was initially scanned under conditions at which the hydrate is stable (atmospheric pressure and liquid nitrogen temperature, 77 K). The end of the sample holder was then exposed to the ambient air, and the core was continuously scanned as dissociation occurred in response to the rising temperature. CT imaging captured the advancing dissociation front clearly and accurately. The evolved gas volume was monitored as a function of time. Measured by CT, the advancing hydrate dissociation front was modeled as a thermal conduction problem explicitly incorporating the enthalpy of dissociation, using the Stefan moving-boundary-value approach. The assumptions needed to perform the analysis consisted of temperatures at the model boundaries. The estimated value for thermal conductivity of 2.6 W/m K for the remaining water ice/sand mixture is higher than expected based on conduction alone; this high value may represent a lumped parameter that incorporates the processes of heat conduction, methane gas convection, and any kinetic effects that occur during dissociation. The technique presented here has broad implications for future laboratory and field testing that incorporates geophysical techniques to monitor gas hydrate dissociation.

Freifeld, Barry M.; Kneafsey, Timothy J.; Tomutsa, Liviu; Stern, Laura A.; Kirby, Stephen H.

2002-02-28T23:59:59.000Z

222

Data from Alaska Test Could Help Advance Methane Hydrate R&D | Department  

Broader source: Energy.gov (indexed) [DOE]

from Alaska Test Could Help Advance Methane Hydrate R&D from Alaska Test Could Help Advance Methane Hydrate R&D Data from Alaska Test Could Help Advance Methane Hydrate R&D March 25, 2013 - 1:27pm Addthis Image of how methane hydrates can form in arctic and marine environments. | Illustration by the Energy Department. Image of how methane hydrates can form in arctic and marine environments. | Illustration by the Energy Department. Gayland Barksdale Technical Writer, Office of Fossil Energy DOE & Methane Hydrates The Methane Hydrate Research and Development Act of 2000 established DOE as the lead U.S. agency for methane hydrate R&D. Innovative technology is being developed to inject CO2 into methane hydrate deposits to both release the fuel and permanently store carbon dioxide. DOE's R&D program is focused on developing the tools and

223

Effect of under-inhibition with methanol and ethylene glycol on the hydrate control process  

SciTech Connect (OSTI)

Hydrate control can be achieved by chemical injection. Currently, methanol and ethylene glycol are the most widely used inhibitors in offshore hydrate control operations. To achieve effective hydrate inhibition, a sufficient amount of inhibitor must be injected to shift the thermodynamic equilibrium condition for hydrate formation outside the pipeline operating pressure and temperature. Recently published field experiments showed that hydrate blockages form more readily in under-inhibited systems than in systems completely without inhibitor. A laboratory study is conducted to determine the effect of low concentration (1--5wt%) methanol and ethylene glycol on the hydrate formation process. The results show that, although these chemicals are effective hydrate inhibitors when added in sufficient quantities, they actually enhance the rate of hydrate formation when added at low concentrations to the water. Furthermore, the presence of these chemicals seems to affect the size of the forming hydrate particles.

Yousif, M.H.

1996-12-31T23:59:59.000Z

224

DNA hydration studied by neutron fiber diffraction  

SciTech Connect (OSTI)

The development of neutron high angle fiber diffraction to investigate the location of water around the deoxyribonucleic acid (DNA) double-helix is described. The power of the technique is illustrated by its application to the D and A conformations of DNA using the single crystal diffractometer, D19, at the Institute Laue-Langevin, Grenoble and the time of flight diffractometer, SXD, at the Rutherford Appleton ISIS Spallation Neutron Source. These studies show the existence of bound water closely associated with the DNA. The patterns of hydration in these two DNA conformations are quite distinct and are compared to those observed in X-ray single crystal studies of two-stranded oligodeoxynucleotides. Information on the location of water around the DNA double-helix from the neutron fiber diffraction studies is combined with that on the location of alkali metal cations from complementary X-ray high angle fiber diffraction studies at the Daresbury Laboratory SRS using synchrotron radiation. These analyses emphasize the importance of viewing DNA, water and ions as a single system with specific interactions between the three components and provide a basis for understanding the effect of changes in the concentration of water and ions in inducing conformations] transitions in the DNA double-helix.

Fuller, W.; Forsyth, V.T.; Mahendrasingam, A.; Langan, P.; Pigram, W.J. [Keele Univ. (United Kingdom)] [and others

1994-12-31T23:59:59.000Z

225

Response of oceanic hydrate-bearing sediments to thermalstresses  

SciTech Connect (OSTI)

In this study, we evaluate the response of oceanicsubsurface systems to thermal stresses caused by the flow of warm fluidsthrough noninsulated well systems crossing hydrate-bearing sediments.Heat transport from warm fluids, originating from deeper reservoirs underproduction, into the geologic media can cause dissociation of the gashydrates. The objective of this study is to determine whether gasevolution from hydrate dissociation can lead to excessive pressurebuildup, and possibly to fracturing of hydrate-bearing formations andtheir confining layers, with potentially adverse consequences on thestability of the suboceanic subsurface. This study also aims to determinewhether the loss of the hydrate--known to have a strong cementing effecton the porous media--in the vicinity of the well, coupled with thesignificant pressure increases, can undermine the structural stability ofthe well assembly.Scoping 1D simulations indicated that the formationintrinsic permeability, the pore compressibility, the temperature of theproduced fluids andthe initial hydrate saturation are the most importantfactors affecting the system response, while the thermal conductivity andporosity (above a certain level) appear to have a secondary effect.Large-scale simulations of realistic systems were also conducted,involving complex well designs and multilayered geologic media withnonuniform distribution of properties and initial hydrate saturationsthat are typical of those expected in natural oceanic systems. Theresults of the 2D study indicate that although the dissociation radiusremains rather limited even after long-term production, low intrinsicpermeability and/or high hydrate saturation can lead to the evolution ofhigh pressures that can threaten the formation and its boundaries withfracturing. Although lower maximum pressures are observed in the absenceof bottom confining layers and in deeper (and thus warmer and morepressurized) systems, the reduction is limited. Wellbore designs withgravel packs that allow gas venting and pressure relief result insubstantially lower pressures.

Moridis, G.J.; Kowalsky, M.B.

2006-05-01T23:59:59.000Z

226

Methane hydrate distribution from prolonged and repeated formation in natural and compacted sand samples: X-ray CT observations  

E-Print Network [OSTI]

voxel contained sand, gas, hydrate (under proper conditions)of Gas Hydrate Formation in a Bed of Silica Sand Particles.Gas Hydrate Formation in a Variable Volume Bed of Silica Sand

Rees, E.V.L.

2012-01-01T23:59:59.000Z

227

X-ray computed-tomography observations of water flow through anisotropic methane hydrate-bearing sand  

E-Print Network [OSTI]

conductivity of gas hydrate-bearing sand. J. Geophys. Res.the water and gas flow through hydrate-bearing sands.The gas from hydrate dissociation in the fine sand appears

Seol, Yongkoo

2010-01-01T23:59:59.000Z

228

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network [OSTI]

Documented Example of Gas Hydrate Saturated Sand in the Gulfthe behavior of gas hydrate bearing sand reservoirs can beof highly-saturated gas-hydrate bearing sand in the Gulf of

Moridis, George J.

2008-01-01T23:59:59.000Z

229

Hydration water dynamics and instigation of protein structuralrelaxation  

SciTech Connect (OSTI)

Until a critical hydration level is reached, proteins do not function. This critical level of hydration is analogous to a similar lack of protein function observed for temperatures below a dynamical temperature range of 180-220K that also is connected to the dynamics of protein surface water. Restoration of some enzymatic activity is observed in partially hydrated protein powders, sometimes corresponding to less than a single hydration layer on the protein surface, which indicates that the dynamical and structural properties of the surface water is intimately connected to protein stability and function. Many elegant studies using both experiment and simulation have contributed important information about protein hydration structure and timescales. The molecular mechanism of the solvent motion that is required to instigate the protein structural relaxation above a critical hydration level or transition temperature has yet to be determined. In this work we use experimental quasi-elastic neutron scattering (QENS) and molecular dynamics simulation to investigate hydration water dynamics near a greatly simplified protein system. We consider the hydration water dynamics near the completely deuterated N-acetyl-leucine-methylamide (NALMA) solute, a hydrophobic amino acid side chain attached to a polar blocked polypeptide backbone, as a function of concentration between 0.5M-2.0M under ambient conditions. We note that roughly 50-60% of a folded protein's surface is equally distributed between hydrophobic and hydrophilic domains, domains whose lengths are on the order of a few water diameters, that justify our study of hydration dynamics of this simple model protein system. The QENS experiment was performed at the NIST Center for Neutron Research, using the disk chopper time of flight spectrometer (DCS). In order to separate the translational and rotational components in the spectra, two sets of experiments were carried out using different incident neutron wavelengths of 7.5{angstrom} and 5.5{angstrom} to give two different time resolutions. All the spectra have been measure at room temperature. The spectra were corrected for the sample holder contribution and normalized using the vanadium standard. The resulting data were analyzed with DAVE programs (http://www.ncnr.nist.gov/dave/). The AMBER force field and SPCE water model were used for modeling the NALMA solute and water, respectively. For the analysis of the water dynamics in the NALMA aqueous solutions, we performed simulations of a dispersed solute configuration consistent with our previous structural analysis, where we had primarily focused on the structural organization of these peptide solutions and their connection to protein folding. Further details of the QENS experiment and molecular dynamics simulations are reported elsewhere.

Russo, Daniela; Hura, Greg; Head-Gordon, Teresa

2003-09-01T23:59:59.000Z

230

Phase behavior of methane hydrate in silica sand  

Science Journals Connector (OSTI)

Abstract Two kinds of silica sand powder with different particle size were used to investigate the phase behavior of methane hydrate bearing sediment. In coarse-grained silica sand, the measured temperature and pressure range was (281.1 to 284.2)K and (5.9 to 7.8)MPa, respectively. In fine-grained silica sand, the measured temperature and pressure range was (281.5 to 289.5)K and (7.3 to 16.0)MPa, respectively. The results show that the effect of coarse-grained silica sand on methane hydrate phase equilibrium can be ignored; however, the effect of fine-grained silica sand on methane hydrate phase equilibrium is significant, which is attributed to the depression of water activity caused by the hydrophilicity and negatively charged characteristic of silica particle as well as the pore capillary pressure. Besides, the analysis of experimental results using the GibbsThomson equation shows that methane hydrate phase equilibrium is related to the pore size distribution of silica sand. Consequently, for the correct application of phase equilibrium data of hydrate bearing sediment, the geological condition and engineering requirement should be taken into consideration in gas production, resource evaluation, etc.

Shi-Cai Sun; Chang-Ling Liu; Yu-Guang Ye; Yu-Feng Liu

2014-01-01T23:59:59.000Z

231

Journal of Crystal Growth 250 (2003) 499515 Induction time in crystallization of gas hydrates  

E-Print Network [OSTI]

for revealing how additives in the solution that act as kinetic inhibitors of hydrate crystallization can affect to prevent hydrate crystallization. These options include heating, insulation, water removal, and the use

Firoozabadi, Abbas

232

Hydrogen Production by Reforming Clathrate Hydrates Using the in-Liquid Plasma Method  

Science Journals Connector (OSTI)

Clathrate hydrates, which were formed from methane and cyclopentane, were decomposed by plasma at atmospheric pressure. Methane hydrate was synthesized by injecting methane into shaved ice in the reactor at a pre...

Andi Erwin Eka Putra; Shinfuku Nomura

2014-01-01T23:59:59.000Z

233

Study on gas hydrates for the solid transportation of natural gas  

Science Journals Connector (OSTI)

Natural gas hydrate typically contains 85 wt.% water and 15 wt.% natural gas, and commonly belongs to cubic structure I...3 solid hydrate contains up to 200 m3 of natural gas depending on pressure and temperature...

Nam-Jin Kim; Chong-Bo Kim

2004-04-01T23:59:59.000Z

234

Methane Hydrate Formation and Dissocation in a Partially Saturated Sand--Measurements and Observations  

SciTech Connect (OSTI)

We performed a sequence of tests on a partially water-saturated sand sample contained in an x-ray transparent aluminum pressure vessel that is conducive to x-ray computed tomography (CT) observation. These tests were performed to gather data for estimation of thermal properties of the sand/water/gas system and the sand/hydrate/water/gas systems, as well as data to evaluate the kinetic nature of hydrate dissociation. The tests included mild thermal perturbations for the estimation of the thermal properties of the sand/water/gas system, hydrate formation, thermal perturbations with hydrate in the stability zone, hydrate dissociation through thermal stimulation, additional hydrate formation, and hydrate dissociation through depressurization with thermal stimulation. Density changes throughout the sample were observed as a result of hydrate formation and dissociation, and these processes induced capillary pressure changes that altered local water saturation.

Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis, George J.; Seol, Yongkoo; Freifeld, Barry; Taylor, Charles E.; Gupta, Arvind

2005-03-01T23:59:59.000Z

235

Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico  

SciTech Connect (OSTI)

Studies of geologic and geophysical data from the offshore of India have revealed two geologically distinct areas with inferred gas hydrate occurrences: the passive continental margins of the Indian Peninsula and along the Andaman convergent margin. The Indian National Gas Hydrate Program (NGHP) Expedition 01 was designed to study the occurrence of gas hydrate off the Indian Peninsula and along the Andaman convergent margin with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. NGHP Expedition 01 established the presence of gas hydrates in Krishna- Godavari, Mahanadi and Andaman basins. The expedition discovered one of the richest gas hydrate accumulations yet documented (Site 10 in the Krishna-Godavari Basin), documented the thickest and deepest gas hydrate stability zone yet known (Site 17 in Andaman Sea), and established the existence of a fully-developed gas hydrate system in the Mahanadi Basin (Site 19).

Collett, T.S. (USGS); Riedel, M. (McGill Univ., Montreal, Quebec, Canada); Cochran, J.R. (Columbia Univ., Palisades, NY); Boswell, R.M.; Kumar, Pushpendra (Oil and Natural Gas Corporation Ltd., Navi Mumbai, India); Sathe, A.V. (Oil and Natural Gas Corporation Ltd., Uttaranchal, INDIA)

2008-07-01T23:59:59.000Z

236

Effects of Hydration and Oxygen Vacancy on CO2 Adsorption and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydration and Oxygen Vacancy on CO2 Adsorption and Activation on ?-Ga2O3(100). Effects of Hydration and Oxygen Vacancy on CO2 Adsorption and Activation on ?-Ga2O3(100)....

237

Gas Hydrate Equilibrium Measurements for Multi-Component Gas Mixtures and Effect of Ionic Liquid Inhibitors  

E-Print Network [OSTI]

hydrate inhibition data from a newly commissioned micro bench top reactor, a high-pressure autoclave and a rocking cell. The conditions for hydrate formation for pure methane and carbon dioxide were also measured, for validation purposes. The measured data...

Othman, Enas Azhar

2014-04-07T23:59:59.000Z

238

Nano measurements with micro-devices: mechanical properties of hydrated collagen fibrils  

Science Journals Connector (OSTI)

2005 The Royal Society 22 February 2006 Nano measurements with micro-devices: mechanical properties of hydrated...287, 637-640. doi:10.1126/science.287.5453.637 . Nano measurements with micro-devices: mechanical properties of hydrated...

2006-01-01T23:59:59.000Z

239

Energy Department Expands Research into Methane Hydrates, a Vast, Untapped  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0, 2013 0, 2013 Energy Department Expands Research into Methane Hydrates, a Vast, Untapped Potential Energy Resource of the U.S. WASHINGTON - Today, U.S. Energy Secretary Ernest Moniz announced nearly $5 million in funding across seven research projects nationwide designed to increase our understanding of methane hydrates - a large, completely untapped natural gas resource-and what it could mean for the environment, as well as American economic competiveness and energy security. "The recent boom in natural gas production - in part due to long-term Energy Department investments beginning in the 70's and 80's - has had a transformative impact on our energy landscape, helping to reduce greenhouse gas emissions and support thousands of American jobs," said Secretary Moniz. "While our research into methane hydrates is still in its early stages, these investments will increase our understanding of this domestic resource and the potential to safely and sustainably unlock the natural gas held within."

240

Chitosan as green kinetic inhibitors for gas hydrate formation  

Science Journals Connector (OSTI)

The kinetic inhibiting effect of a number of chitosans on hydrate formation was investigated using methane and methane/ethane gas mixtures. The results indicated that chitosan was a good kinetic inhibitor. The induction time of gas hydrate formation evidently increased with the degree of deacetylation (DD), however, when DD was higher than 80%, the effect of DD on the induction time was negligible. Moreover, it was found that the molecular weight (MW) of chitosan and the addition of polyethylene oxide (PEO) had little effect on the induction time. The optimal concentration of chitosan was found to be 0.6 wt%. Finally, the mechanisms of the kinetic inhibitor on the hydrate formation were discussed.

Yongjun Xu; Minlin Yang; Xiaoxi Yang

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Protein structure and hydration probed by SANS and osmotic stress  

SciTech Connect (OSTI)

Interactions governing protein folding, stability, recognition, and activity are mediated by hydration. Here, we use small-angle neutron scattering coupled with osmotic stress to investigate the hydration of two proteins, lysozyme and guanylate kinase (GK), in the presence of solutes. By taking advantage of the neutron contrast variation that occurs upon addition of these solutes, the number of protein-associated (solute-excluded) water molecules can be estimated from changes in both the zero-angle scattering intensity and the radius of gyration. Poly(ethylene glycol) exclusion varies with molecular weight. This sensitivity can be exploited to probe structural features such as the large internal GK cavity. For GK, small-angle neutron scattering is complemented by isothermal titration calorimetry with osmoticstress to also measure hydration changes accompanying ligand binding. These results provide a framework for studying other biomolecular systems and assemblies using neutron scattering together with osmotic stress.

Rau, Dr. Donald [National Institutes of Health

2008-01-01T23:59:59.000Z

242

Ground movements associated with gas hydrate production. Final report  

SciTech Connect (OSTI)

This report deals with a study directed towards a modeling effort on production related ground movements and subsidence resulting from hydrate dissociation. The goal of this research study was to evaluate whether there could be subsidence related problems that could be an impediment to hydrate production. During the production of gas from a hydrate reservoir, it is expected that porous reservoir matrix becomes more compressible which may cause reservoir compression (compaction) under the influence of overburden weight. The overburden deformations can propagate its influence upwards causing subsidence near the surface where production equipment will be located. In the present study, the reservoir compaction is modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The present study is expected to provide a ``lower bound`` solution to the subsidence caused by hydrate reservoir depletion. The reservoir compaction anticipated during hydrate production was modeled by using the finite element method, which is a powerful computer modeling technique. The ground movements at the reservoir roof (i.e. reservoir compression) cause additional stresses and disturbance in the overburden strata. In this study, the reservoir compaction was modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The resulting stresses and ground movements were computed by using the finite element method. Based on the parameters used in this investigation, the maximum ground subsidence could vary anywhere from 0.50 to 6.50 inches depending on the overburden depth and the size of the depleted hydrate reservoir.

Siriwardane, H.J.; Kutuk, B.

1992-03-01T23:59:59.000Z

243

Numerical studies on two-way coupled fluid flow and geomechanics in hydrate deposits  

E-Print Network [OSTI]

Hydrate deposits that are desirable gas production targets almost invariably involve coarse, unlithified, unconsolidated media (such as sands

Kim, J.

2014-01-01T23:59:59.000Z

244

Preliminary Assessment of Hydrocarbon Gas Sources from the Mt. Elbert No. 1 Gas Hydrate Test Well  

E-Print Network [OSTI]

in two primary horizons; an upper zone, (D Unit) containing 14 meters of gas hydrate-bearing sands

Thomas D. Lorenson; Timothy S. Collett; Robert B. Hunter

245

Recovery of gas from hydrate deposits using conventional production technology. [Salt-frac technique  

SciTech Connect (OSTI)

Methane hydrate gas could be a sizeable energy resource if methods can be devised to produce this gas economically. This paper examines two methods of producing gas from hydrate deposits by the injection of hot water or steam, and also examines the feasibility of hydraulic fracturing and pressure reduction as a hydrate gas production technique. A hydraulic fracturing technique suitable for hydrate reservoirs is also described.

McGuire, P.L.

1982-01-01T23:59:59.000Z

246

Electrical Resistivity Investigation of Gas Hydrate Distribution in  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

10 10 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354 Waco, TX 76798 Principal Author: John A. Dunbar Prepared for: United States Department of Energy National Energy Technology Laboratory January 15, 2011 Office of Fossil Energy 1 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Pr oject Quar ter 17 Repor t Report Type: Quarterly Starting October 1, 2010 Ending December 31, 2010 Author: John A. Dunbar Baylor University Department of Geology January 15, 2011 DOE Award Number: DE-FC26-06NT142959

247

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oil & Natural Gas Technology DOE Field Work Proposal.: ESD12-011 2012 Annual Research Progress Report (April - December 2012) Numerical Studies for the Characterization of Recoverable Resources from Methane Hydrate Deposits Project Period (April 2012 - March 2013) Lawrence Berkeley National Laboratory George Moridis (Principal Investigator) GJMoridis@lbl.gov Tel: (510) 486-4746 Prepared for: United States Department of Energy National Energy Technology Laboratory Submission date: 2/4/2013 Office of Fossil Energy ii 2012Annual Progress Report Numerical Studies for the Characterization of Recoverable Resources from Methane Hydrate Deposits WORK PERFORMED UNDER ESD12-010 Lawrence Berkeley National Laboratory George Moridis (Principal Investigator)

248

Electronic stucture of methane hydrate studied by Compton scattering  

Science Journals Connector (OSTI)

High-resolution Compton scattering spectra of methane, methane hydrate, and ice were measured using incident photon energy of 56.4keV at beamline ID15B of the European Synchrotron Radiation Facility. The experimental Compton profiles are compared to calculations employing density-functional theory using model atomic clusters. The hydrate has a cagelike structure built up from water molecules and the related Compton profile is observed to change apparently when compared to hexagonal ice. Furthermore, the influence of the guest-host interactions between the methane molecules and the water molecules of the cages on the Compton profile is discussed.

C. Sternemann; S. Huotari; M. Hakala; M. Paulus; M. Volmer; C. Gutt; T. Buslaps; N. Hiraoka; D. D. Klug; K. Hmlinen; M. Tolan; J. S. Tse

2006-05-03T23:59:59.000Z

249

Fire in the Ice, August 2010 Methane Hydrate Newsletter  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Figure 1: Simulation results of coupled thermo-dynamic and geomechanical changes around a hot Figure 1: Simulation results of coupled thermo-dynamic and geomechanical changes around a hot production well intersecting an HBS near a sloping seafloor after 30 years of production and heating (Rutqvist and Moridis, 2010). CONTENTS Geohazards of In Situ Gas Hydrates ...........................................1 Behavior of Methane Released in the Deep Ocean.....5 Core-Scale Heterogeneity ............6 Gas Volume Ratios ........................9 The Role of Methane Hydrates in the Earth System ....................12 Announcements .......................15 * Inter-Laboratory Comparison Project * Mississippi Canyon 118 * Research Fellowship * Call for Papers * Call for Abstracts * Upcoming Meetings Spotlight on Research .......... 20 Graham Westbrook CONTACT

250

Hydration kinetics modeling of Portland cement considering the effects of curing temperature and applied pressure  

E-Print Network [OSTI]

such as heat generation, strength development and shrinkage are the results of interrelated chemical, physical and mechanical processes. A thorough understanding of theses processes is a critical prerequisite for modeling

Meyer, Christian

251

International Conference on Gas Hydrates May 19-23, 2002, Yokohama  

E-Print Network [OSTI]

of hydrates for transport and storage of natural gas and in cold flow technology. In a continuous stirred tank. The same conditions are relevant in cold flow technology where oil, gas and water are passed through4th International Conference on Gas Hydrates May 19-23, 2002, Yokohama Hydrate Formation Rate

Gudmundsson, Jon Steinar

252

ORIGINAL RESEARCH PAPER Canyon-infilling and gas hydrate occurrences in the frontal fold  

E-Print Network [OSTI]

ORIGINAL RESEARCH PAPER Canyon-infilling and gas hydrate occurrences in the frontal fold to infer the canyon-infilling, fold uplift, and gas hydrate occurrences beneath the frontal fold at the toe simu- lating reflector (BSR) on seismic sections indicates the base of gas hydrate stability zone

Lin, Andrew Tien-Shun

253

Methane Hydrate and Free Gas on the Blake Ridge from Vertical Seismic Profiling  

Science Journals Connector (OSTI)

...expression: The phase boundary between methane hydrate and methane plus...and methane hydrate, CH4-5.75H20...a structure I hydrate construct-ed...documented anomalous behavior in the formation...325 Fig. 1. Phase diagram for the...

W. Steven Holbrook; Hartley Hoskins; Warren T. Wood; Ralph A. Stephen; Daniel Lizarralde

1996-09-27T23:59:59.000Z

254

Effect of Brine on Hydrate Antiagglomeration J. Dalton York and Abbas Firoozabadi*,  

E-Print Network [OSTI]

production lines often favor formation of crystalline inclusion compounds known as gas hydrates. Water, 2008. ReVised Manuscript ReceiVed March 19, 2009 Natural gas production poses a risk of flow-line hydrate blockage from coproduced water and hydrate- forming species. Our previous studies have focused

Firoozabadi, Abbas

255

Micromechanics of Hydrate Dissociation in Marine Sediments by Grain-Scale Simulations  

E-Print Network [OSTI]

SPE 114223 Micromechanics of Hydrate Dissociation in Marine Sediments by Grain-Scale Simulations dissociation on the strength of hydrate-bearing sediments. Dissociation of gas-hydrates in marine sediments pressure increase, this process reduces the stiffness of the sediments, which may fracture or be flu

Patzek, Tadeusz W.

256

Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen in the  

E-Print Network [OSTI]

1 Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen the mole fraction of CO2 in the carbon dioxide + nitrogen + cyclopentane mixed hydrate phase, both defined;2 {water +carbon dioxide + nitrogen}, the equilibrium pressure of the mixed hydrate is reduced by 0.95 up

Paris-Sud XI, Université de

257

Impacts of ocean acidification and mitigative hydrated lime addition on Pacific oyster larvae  

E-Print Network [OSTI]

Impacts of ocean acidification and mitigative hydrated lime addition on Pacific oyster larvae, and for other species. Keywords: Ocean acidification; Pacific oyster; Larval stages; Hydrated lime; Shellfish No.: 577 Title of Project: Impacts of ocean acidification and mitigative hydrated lime addition

258

Acoustic and Thermal Characterization of Oil Migration, Gas Hydrates Formation and Silica Diagenesis  

E-Print Network [OSTI]

Acoustic and Thermal Characterization of Oil Migration, Gas Hydrates Formation and Silica Rights Reserved #12;ABSTRACT Acoustic and Thermal Characterization of Oil Migration, Gas Hydrates-A to Opal-CT, the formation of gas hydrates, fluid substitution in hydrocarbon reservoirs, and fluid

Guerin, Gilles

259

Oil and Gas CDT Gas hydrate distribution on tectonically active continental  

E-Print Network [OSTI]

Oil and Gas CDT Gas hydrate distribution on tectonically active continental margins: Impact on gas. Gregory F. Moore, University of Hawaii (USA) http://www.soest.hawaii.edu/moore/ Key Words Gas Hydrates, Faults, Fluid Flow, gas prospectivity Overview Fig. 1. Research on gas hydrates is often undertaken

Henderson, Gideon

260

NETL: Methane Hydrates Interagency R&D Conference  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Hydrates Interagency R&D Conference Methane Hydrates Interagency R&D Conference March 20-22, 2002 Table of Contents Disclaimer Papers and Presentations The Curiosity of Hydrates Methane Hydrates Issues Arctic Region Projects West Coast Projects East Coast Projects Gulf of Mexico Projects Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents [OSTI]

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

262

Possible Martensitic Transformation in Hydrated Phospholipid Liquid Crystals  

Science Journals Connector (OSTI)

The main phase transition in smectic liquid crystals of a hydrated phospholipid involves a Martensitic transformation driven by the molecular-conformation changes. This inhomogeneous shear transformation generates periodic crystallographic twins that appear as corrugations of the molecular bilayer sheets. The model accounts for the observed lipid shedding, hysteresis, double corrugation periodicities, and diffusion anomalies, and may account for other smectic herringbone structures.

Winston K. Chan and Watt W. Webb

1981-01-05T23:59:59.000Z

263

Discovery in Hydrating Plaster Using Multiple Machine Learning Methods  

E-Print Network [OSTI]

Discovery in Hydrating Plaster Using Multiple Machine Learning Methods Judith E. Devaney, John G plaster over multiple time periods. We use three dimensional data obtained through X-ray microtomography of the plaster datasets that had been labeled with their autoclass predictions. The rules were found to have both

Fernandez, Thomas

264

Natural gas hydrates - issues for gas production and geomechanical stability  

E-Print Network [OSTI]

bearing sediments in offshore environments, I divided these data into different sections. The data included water depths, pore water salinity, gas compositions, geothermal gradients, and sedimentary properties such as sediment type, sediment mineralogy... .................................................................. 9 2.2 Hydrate patterns in sediments .................................................................... 24 3.1 Water depths and penetration for the Blake Ridge..................................... 31 3.2 Geothermal gradients measured...

Grover, Tarun

2008-10-10T23:59:59.000Z

265

Massive dissociation of gas hydrate during a Jurassic  

E-Print Network [OSTI]

release of methane from gas hydrate contained in marine continental-margin sediments. The better-known positive carbon-isotope excursion of the Early Toarcian is well illustrated by European organic-poor marine-resolution ammonite biostratigraphy is simply determined. Fossil wood is also present, preserved as coal (some

Hesselbo, Stephen P.

266

NH4-smectite: Characterization, hydration properties and hydro mechanical behaviour  

E-Print Network [OSTI]

NH4-smectite: Characterization, hydration properties and hydro mechanical behaviour M. Gautier a and drive to environmental problems. The purpose of this study was to understand the hydro- physical changes the pressure on small amounts of samples, proved the strong increase of the permeability of NH4-smectite

Paris-Sud XI, Université de

267

The Microstructure and Chemistry of Tricalcium Aluminate Hydration [and Discussion  

Science Journals Connector (OSTI)

...to account for the metastability of ettringite with respect to calcium aluminate monosulphate...Consideration of the crystal structure of ettringite and the monosulphate hydrate suggests...the type of defect occurring in the ettringite structure at high pH. The Royal Society...

1983-01-01T23:59:59.000Z

268

Predicted geoacoustic properties of gas hydrate saturated marine sediments  

E-Print Network [OSTI]

for various temperatures and pressures. . . . . . . . . . . . . . . . . . , . . . . . . . . . . . . . . . . ? 53 3 Physical properties of grain material, pore fluid, variables affecting global fluid motion, and skeletal frame... of quartz and glass as a function of pressure 79 27 Skeletal frame elastic moduli as a function of varying hydrate concen- tration. . . , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , . . . . . . . . . . . . . . . . . . . . ?. 81 28...

Curtis, William Robert

2012-06-07T23:59:59.000Z

269

The U.S. DOE Methane Hydrate R&D Program DOE Sponsored Student Researchers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

U.S. DOE Methane Hydrate R&D Program U.S. DOE Methane Hydrate R&D Program DOE Sponsored Student Researchers Publications and Presentations of DOE Supported Methane Hydrate R&D 1999-2013 December 2013 Table of Contents Section I: Documentation of Support for Education .................................................................................... 5 Additional Post-Degree Assignments at National Labs and USGS .......................................................... 14 Papers Authored and Presentations Given by NETL Methane Hydrate Fellows .................................... 15 Section II: Publications Related to the Program's Major Field Projects .................................................... 21 Alaska North Slope Gas Hydrate Reservoir Characterization (DE-FC26-01NT41332) ............................ 21

270

Potential gradients produced by pore-space heterogeneities: Application to isothermal frost damage and submarine hydrate anomalies  

E-Print Network [OSTI]

from simple laboratory experiments. Field observations of hydrate anomalies in a submarine sand layer, gas hydrates are com- monly concentrated within the most coarse-grained material. Natural gas hydrates and submarine hydrate anomalies Alan W. Rempel1 and Laura J. Van Alst2 1 Department of Geological Sciences

Rempel, Alan W.

271

Gas Hydrate: A Realistic Future Source of Gas Supply? | Department of  

Broader source: Energy.gov (indexed) [DOE]

Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? August 24, 2009 - 1:00pm Addthis Washington, D.C - A Department of Energy scientist writes in this week's Science magazine that a search is underway for a potentially immense untapped energy resource that, given its global distribution, has the potential to alter existing energy production and supply paradigms. In the article, Is Gas Hydrate Energy Within Reach?, Dr. Ray Boswell, technology manager for the Office of Fossil Energy's National Energy Technology Laboratory methane hydrates program, discusses recent findings and new research approaches that are clarifying gas hydrates energy potential. Driving the current interest in gas hydrate resource appraisal is the focus

272

Gas Hydrate: A Realistic Future Source of Gas Supply? | Department of  

Broader source: Energy.gov (indexed) [DOE]

Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? Gas Hydrate: A Realistic Future Source of Gas Supply? August 24, 2009 - 1:00pm Addthis Washington, D.C - A Department of Energy scientist writes in this week's Science magazine that a search is underway for a potentially immense untapped energy resource that, given its global distribution, has the potential to alter existing energy production and supply paradigms. In the article, Is Gas Hydrate Energy Within Reach?, Dr. Ray Boswell, technology manager for the Office of Fossil Energy's National Energy Technology Laboratory methane hydrates program, discusses recent findings and new research approaches that are clarifying gas hydrates energy potential. Driving the current interest in gas hydrate resource appraisal is the focus

273

Strength behavior of methane hydrate bearing sand in undrained triaxial testing  

Science Journals Connector (OSTI)

Gas hydrates represent a potential future energy source as well as a considerable geohazard. In order to assess both the benefits and risks that gas hydrate bearing sediments pose, fundamental information about their physical properties is required. In this study, the undrained shear strength of methane hydrate bearing sand was investigated. The experimental program required modifications to an existing triaxial apparatus and accurate determination of the hydrate saturation lead to the use of two methods for comparison of the saturation calculations. Strength results indicated that the presence of gas hydrate will increase the sediment's undrained shear strength and corresponding stiffness. The relative contribution of cohesion and friction angle was observed to be a function of the hydrate saturation, for this particular hydrate formation methodology.

Hossein Ghiassian; Jocelyn L.H. Grozic

2013-01-01T23:59:59.000Z

274

Methane Hydrate Formation and Dissociation in a PartiallySaturated Core-Scale Sand Sample  

SciTech Connect (OSTI)

We performed a sequence of tests on a partiallywater-saturated sand sample contained in an x-ray transparent aluminumpressure vessel that is conducive to x-ray computed tomography (CT)observation. These tests were performed to gather data for estimation ofthermal properties of the sand/water/gas system and thesand/hydrate/water/gas systems, as well as data to evaluate the kineticnature of hydrate dissociation. The tests included mild thermalperturbations for the estimation of the thermal properties of thesand/water/gas system, hydrate formation, thermal perturbations withhydrate in the stability zone, hydrate dissociation through thermalstimulation, additional hydrate formation, and hydrate dissociationthrough depressurization with thermal stimulation. Density changesthroughout the sample were observed as a result of hydrate formation anddissociation, and these processes induced capillary pressure changes thataltered local water saturation.

Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis, George J.; Seol,Yongkoo; Freifeld, Barry M.; Taylor, Charles E.; Gupta, Arvind

2005-11-03T23:59:59.000Z

275

X-ray Scanner for ODP Leg 204: Drilling Gas Hydrates on Hydrate Ridge, Cascadia Continental Margin  

SciTech Connect (OSTI)

An x-ray scanner was designed and fabricated at Lawrence Berkeley National Laboratory to provide high speed acquisition of x-ray images of sediment cores collected on the Ocean Drilling Program (ODP) Leg 204: Drilling Gas Hydrates On Hydrate Ridge, Cascadia Continental Margin. This report discusses the design and fabrication of the instrument, detailing novel features that help reduce the weight and increase the portability of the instrument. Sample x-ray images are included. The x-ray scanner was transferred to scientific drilling vessel, the JOIDES Resolution, by the resupply ship Mauna Loa, out of Coos Bay, Oregon on July 25. ODP technicians were trained in the instruments operation. The availability of the x-ray scanner at the drilling site allows real-time imaging of cores containing methane hydrate immediately after retrieval. Thus, imaging experiments on cores can yield information on the distribution and quantity of methane hydrates. Performing these measurements at the location of core collection eliminates the need for high pressures or low temperature core handling while the cores are stored and transported to a remote imaging laboratory.

Freifeld, Barry; Kneafsey, Tim; Pruess, Jacob; Reiter, Paul; Tomutsa, Liviu

2002-08-08T23:59:59.000Z

276

Deep-Sea Field Test of the CH4 Hydrate to CO2 Hydrate Spontaneous Conversion Hypothesis  

Science Journals Connector (OSTI)

We have carried out a small-scale deep-sea field test of the hypothesis that CH4 gas can be spontaneously produced from CH4 hydrate by injection of a CO2/N2 gas mixture, thereby inducing release of the encaged molecules with sequestration of the injected ...

Peter G. Brewer; Edward T. Peltzer; Peter M. Walz; Elizabeth K. Coward; Laura A. Stern; Stephen H. Kirby; John Pinkston

2014-10-06T23:59:59.000Z

277

Gas hydrate occurrences and their relation to host sediment properties: Results from Second Ulleung Basin Gas Hydrate Drilling Expedition, East Sea  

Science Journals Connector (OSTI)

Abstract The Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2) recovered various forms of gas-hydrate bearing sediments from 10 drill sites in the lower slope and basin floor of the Ulleung Basin. To characterize the gas-hydrate occurrences and the properties of the host sediments, whole-round core samples were taken from portions of recovered cores determined to be hydrate-bearing based on infrared (IR) scanning. These samples were further characterized by a variety of shipboard experiments such as imaging of the sediments with hand-held IR and visual cameras, measurements of pore water chlorinity within and around IR inferred cold regions in the core and grain-size analysis of pore-water squeeze cakes. Sediment compositions of selected samples were further characterized by X-ray diffraction and scanning electron microscopes during post-cruise analysis. The shipboard and post-cruise analysis results collectively indicate that the recovered gas hydrates mainly occur as 1) pore-filling type bounded by discrete silty sand to sandy silt layers, 2) fracture-filling veins and nodules, or 3) disseminated type in silt. In addition, minor but significant variation in gas hydrate concentrations were observed in diatomaceous silt where gas hydrates occur as pore-filling material in layers dominated by intact diatom frustules. Gas hydrate accumulations of fracture-filling type occur predominantly in regions where acoustic blanking features in the seismic record suggest gas migration from below the gas hydrate stability zone. Results from the UBGH2 core studies along with the analysis of similar samples from other expeditions, including those executed by the Ocean Drilling Program, the Integrated Ocean Drilling Program, and the First Ulleung Basin Gas Hydrate Drilling Expedition, greatly improved our understanding of lithologic controls on marine gas hydrate occurrences.

J.-J. Bahk; D.-H. Kim; J.-H. Chun; B.-K. Son; J.-H. Kim; B.-J. Ryu; M.E. Torres; M. Riedel; P. Schultheiss

2013-01-01T23:59:59.000Z

278

Methane hydrate formation and dissociation in a partially saturated core-scale sand sample  

SciTech Connect (OSTI)

We performed a series of experiments to provide data for validating numerical models of gas hydrate behavior in porous media. Methane hydrate was formed and dissociated under various conditions in a large X-ray transparent pressure vessel, while pressure and temperature were monitored. In addition, X-ray computed tomography (CT) was used to determine local density changes during the experiment. The goals of the experiments were to observe changes occurring due to hydrate formation and dissociation, and to collect data to evaluate the importance of hydrate dissociation kinetics in porous media. In the series of experiments, we performed thermal perturbations on the sand/water/gas system, formed methane hydrate, performed thermal perturbations on the sand/hydrate/water/gas system resulting in hydrate formation and dissociation, formed hydrate in the resulting partially dissociated system, and dissociated the hydrate by depressurization coupled with thermal stimulation. Our CT work shows significant water migration in addition to possible shifting of mineral grains in response to hydrate formation and dissociation. The extensive data including pressure, temperatures at multiple locations, and density from CT data is described.

Kneafsey, T.J. (LBNL); Tomutsa, L. (LBNL); Moridis, G.J. (LBNL); Seol, Y. (LBNL); Freifeld, B.M. (LBNL); Taylor, C.E.; Gupta, A. (Colorado School of Mines, Golden, CO)

2007-03-01T23:59:59.000Z

279

Experimental and Numerical Observations of Hydrate Reformation during Depressurization in a Core-Scale Reactor  

SciTech Connect (OSTI)

Gas hydrate has been predicted to reform around a wellbore during depressurization-based gas production from gas hydrate-bearing reservoirs. This process has an adverse effect on gas production rates and it requires time and sometimes special measures to resume gas flow to producing wells. Due to lack of applicable field data, laboratory scale experiments remain a valuable source of information to study hydrate reformation. In this work, we report laboratory experiments and complementary numerical simulations executed to investigate the hydrate reformation phenomenon. Gas production from a pressure vessel filled with hydrate-bearing sand was induced by depressurization with and without heat flux through the boundaries. Hydrate decomposition was monitored with a medical X-ray CT scanner and pressure and temperature measurements. CT images of the hydrate-bearing sample were processed to provide 3-dimensional data of heterogeneous porosity and phase saturations suitable for numerical simulations. In the experiments, gas hydrate reformation was observed only in the case of no-heat supply from surroundings, a finding consistent with numerical simulation. By allowing gas production on either side of the core, numerical simulations showed that initial hydrate distribution patterns affect gas distribution and flow inside the sample. This is a direct consequence of the heterogeneous pore network resulting in varying hydraulic properties of the hydrate-bearing sediment.

Seol, Yongkoo; Myshakin, Evgeniy

2011-01-01T23:59:59.000Z

280

Geochemical and geologic factors effecting the formulation of gas hydrate: Task No. 5, Final report  

SciTech Connect (OSTI)

The main objective of our work has been to determine the primary geochemical and geological factors controlling gas hydrate information and occurrence and particularly in the factors responsible for the generation and accumulation of methane in oceanic gas hydrates. In order to understand the interrelation of geochemical/geological factors controlling gas hydrate occurrence, we have undertaken a multicomponent program which has included (1) comparison of available information at sites where gas hydrates have been observed through drilling by the Deep Sea Drilling Project (DSDP) on the Blake Outer Ridge and Middle America Trench; (2) regional synthesis of information related to gas hydrate occurrences of the Middle America Trench; (3) development of a model for the occurrence of a massive gas hydrate as DSDP Site 570; (4) a global synthesis of gas hydrate occurrences; and (5) development of a predictive model for gas hydrate occurrence in oceanic sediment. The first three components of this program were treated as part of a 1985 Department of Energy Peer Review. The present report considers the last two components and presents information on the worldwide occurrence of gas hydrates with particular emphasis on the Circum-Pacific and Arctic basins. A model is developed to account for the occurrence of oceanic gas hydrates in which the source of the methane is from microbial processes. 101 refs., 17 figs., 6 tabs.

Kvenvolden, K.A.; Claypool, G.E.

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

GEOTECHNICAL INVESTIGATION CHEVRON GULF OF MEXICO GAS HYDRATES JIP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

GEOTECHNICAL INVESTIGATION GEOTECHNICAL INVESTIGATION CHEVRON GULF OF MEXICO GAS HYDRATES JIP BLOCKS 13 AND 14, ATWATER VALLEY AREA BLOCK 151, KEATHLEY CANYON AREA GULF OF MEXICO RESULTS OF CORE SAMPLE ANALYSIS, STANDARD AND ADVANCED LABORATORY TESTING Report No. 0201-5081 CHEVRON TEXACO ENERGY TECHNOLOGY COMPANY Houston, Texas FUGRO-McCLELLAND MARINE GEOSCIENCES, INC. P. O. Box 740010, Houston, Texas 77274, Phone: 713-369-5600, Fax: 713-369-5570 GEOTECHNICAL INVESTIGATION CHEVRON GULF OF MEXICO GAS HYDRATES JIP BLOCKS 13 AND 14, ATWATER VALLEY AREA BLOCK 151, KEATHLEY CANYON AREA GULF OF MEXICO RESULTS OF CORE SAMPLE ANALYSIS, STANDARD AND ADVANCED LABORATORY TESTING REPORT NO. 0201-5081 Client: ChevronTexaco Energy Technology Company 1500 Louisiana St. Houston, Tx 77002

282

Electrical Resistivity Investigation of Gas Hydrate Distribution in  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

July 1 - September 30, 2011 July 1 - September 30, 2011 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354 Waco, TX 76798 Principal Author: John A. Dunbar Prepared for: United States Department of Energy National Energy Technology Laboratory October 14, 2011 Office of Fossil Energy 1 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Pr oject Quar ter 20 Repor t Report Type: Quarterly Starting July 1, 2011 Ending September 30, 2011 Author: John A. Dunbar Baylor University Department of Geology October 14, 2011 DOE Award Number: DE-FC26-06NT142959

283

Electrical Resistivity Investigation of Gas Hydrate Distribution in  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

January 1 - March 31, 2012 January 1 - March 31, 2012 Electrical Resistivity Investigation of Gas Hydrate Distribution in the Mississippi Canyon Block 118, Gulf of Mexico Submitted by: Baylor University One Bear Place, Box 97354 Waco, TX 76798 Principal Author: John A. Dunbar Prepared for: United States Department of Energy National Energy Technology Laboratory April 18, 2012 Office of Fossil Energy 1 Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico Pr oject Quar ter 22 Repor t Report Type: Quarterly Starting January 1, 2012 Ending March 31, 2012 Author: John A. Dunbar Baylor University Department of Geology April 18, 2012 DOE Award Number: DE-FC26-06NT142959

284

NETL-ORD Methane Hydrate Project - Micro XCT Characterization and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Micro-XCT Characterization and Examination of Pressured Cores Last Reviewed 7/15/2013 Micro-XCT Characterization and Examination of Pressured Cores Last Reviewed 7/15/2013 Goal The primary goal of this research is to visualize gas hydrate within sediment pore spaces under in situ conditions using a high-resolution micro-XCT scanner. Performers Yongkoo Seol – NETL Office of Research & Development Eilis Rosenbaum – NETL Office of Research & Development Jongho Cha- Oak Ridge Institute for Science and Education Location National Energy Technology Laboratory - Morgantown, West Virginia Description The initial phase of this research will focus on developing the experimental system needed to accommodate hydrate-bearing samples under in-situ conditions within an existing micro-XCT (X-ray transparent cell) system. Development will consist of designing, building, and testing the

285

Notices DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee  

Broader source: Energy.gov (indexed) [DOE]

32 Federal Register 32 Federal Register / Vol. 77, No. 130 / Friday, July 6, 2012 / Notices DEPARTMENT OF ENERGY Methane Hydrate Advisory Committee AGENCY: Office of Fossil Energy, Department of Energy. ACTION: Notice of open meeting. SUMMARY: This notice announces a meeting of the Methane Hydrate Advisory Committee. The Federal Advisory Committee Act (Pub. L. 92- 463, 86 Stat. 770) requires that notice of these meetings be announced in the Federal Register. DATES: Thursday, July 26, 2012, 8:00 a.m. to 8:30 a.m. (CDT)- Registration, 8:30 a.m. to 5:00 p.m. (CDT)-Meeting. ADDRESSES: Marriott Houston Airport, 18700 John F. Kennedy Boulevard, Houston, Texas 77032. FOR FURTHER INFORMATION CONTACT: Lou Capitanio, U.S. Department of Energy, Office of Oil and Natural Gas, 1000

286

Imaging Hydrated Microbial Extracellular Polymers: Comparative Analysis by Electron Microscopy  

SciTech Connect (OSTI)

Microbe-mineral and -metal interactions represent a major intersection between the biosphere and geosphere but require high-resolution imaging and analytical tools for investigating microscale associations. Electron microscopy has been used extensively for geomicrobial investigations and although used bona fide, the traditional methods of sample preparation do not preserve the native morphology of microbiological components, especially extracellular polymers. Herein, we present a direct comparative analysis of microbial interactions using conventional electron microscopy approaches of imaging at room temperature and a suite of cryo-electron microscopy methods providing imaging in the close-to-natural hydrated state. In situ, we observed an irreversible transformation of bacterial extracellular polymers during the traditional dehydration-based sample preparation that resulted in the collapse of hydrated gel-like EPS into filamentous structures. Dehydration-induced polymer collapse can lead to inaccurate spatial relationships and hence could subsequently affect conclusions regarding nature of interactions between microbial extracellular polymers and their environment.

Dohnalkova, Alice; Marshall, Matthew J.; Arey, Bruce W.; Williams, Kenneth H.; Buck, Edgar C.; Fredrickson, Jim K.

2011-02-01T23:59:59.000Z

287

Determining the role of hydration forces in protein folding  

SciTech Connect (OSTI)

One of the primary issues in protein folding is determining what forces drive folding and eventually stabilize the native state. A delicate balance exists between electrostatic forces such as hydrogen bonding and salt bridges, and the hydrophobic effect, which are present for both intramolecular protein interactions and intermolecular contributions with the surrounding aqueous environment. This article describes a combined experimental, theoretical, and computational effort to show how the complexity of aqueous hydration can influence the structure, folding and aggregation, and stability of model protein systems. The unification of the theoretical and experimental work is the development or discovery of effective amino acid interactions that implicitly include the effects of aqueous solvent. The authors show that consideration of the full range of complexity of aqueous hydration forces such as many-body effects, long-ranged character of aqueous solvation, and the assumptions made about the degree of protein hydrophobicity can directly impact the observed structure, folding, and stability of model protein systems.

Sorenson, J.M. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry] [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; Hura, G. [Univ. of California, Berkeley, CA (United States)] [Univ. of California, Berkeley, CA (United States); [Lawrence Berkeley National Lab., CA (United States). Life Sciences Div.; Soper, A.K. [Rutherford Appleton Lab., Didcot (United Kingdom). ISIS Facility] [Rutherford Appleton Lab., Didcot (United Kingdom). ISIS Facility; Pertsemlidis, A. [Univ. of Texas Southwestern Medical Center, Dallas, TX (United States). Dept. of Biochemistry] [Univ. of Texas Southwestern Medical Center, Dallas, TX (United States). Dept. of Biochemistry; Head-Gordon, T. [Lawrence Berkeley National Lab., CA (United States)] [Lawrence Berkeley National Lab., CA (United States)

1999-07-01T23:59:59.000Z

288

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 - June 2012 2 - June 2012 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory July 31, 2012 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion..................................................................................................... 4 Cost Status......................................................................................................5

289

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 7 Quarterly Progress Report (April - June 2009) ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFILTER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory July 17, 2009 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 5 Cost Status..................................................................................................... 6

290

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

09 - December 2009 09 - December 2009 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory January 16, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

291

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 - March 2012 2 - March 2012 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory April 26, 2012 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion..................................................................................................... 4 Cost Status......................................................................................................5

292

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0 - March 2010 0 - March 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory April 15, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

293

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0 - September 2010 0 - September 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory October 30, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary....................................................................................... 2 Progress, Results and Discussion........................................................................ 3 Conclusion....................................................................................................5 Cost Status...................................................................................................6

294

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

09 - September 2009 09 - September 2009 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory October 31, 2009 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

295

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0 - June 2010 0 - June 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory July 17, 2010 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion........................................................................... 3 Conclusion..................................................................................................... 6 Cost Status..................................................................................................... 7

296

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0 - December 2010 0 - December 2010 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory January 31, 2011 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion.................................................................................................... 5 Cost Status......................................................................................................7

297

Task 1: Hydrate Code release, Maintenance and Support  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 - September 2011 1 - September 2011 ASSESSING THE EFFICACY OF THE AEROBIC METHANOTROPHIC BIOFIL- TER IN METHANE HYDRATE ENVIRONMENTS Submitted by: University of California Santa Barbara CA 93106 Principal Investigator: David L. Valentine Prepared for: United States Department of Energy National Energy Technology Laboratory October 23, 2011 Office of Fossil Energy 1 TABLE OF CONTENTS Executive Summary.......................................................................................... 2 Progress, Results and Discussion............................................................................3 Conclusion..................................................................................................... 4 Cost Status......................................................................................................5

298

Additives and method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hindrance and/or charge repulsion. Also, polymers having an amide on which a C{sub 1}-C{sub 4} group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

Sloan, E.D. Jr.; Christiansen, R.L.; Lederhos, J.P.; Long, J.P.; Panchalingam, V.; Du, Y.; Sum, A.K.W.

1997-06-17T23:59:59.000Z

299

Additives and method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

Sloan, Jr., Earle Dendy (Golden, CO); Christiansen, Richard Lee (Littleton, CO); Lederhos, Joseph P. (Wheatridge, CO); Long, Jin Ping (Dallas, TX); Panchalingam, Vaithilingam (Lakewood, CO); Du, Yahe (Golden, CO); Sum, Amadeu Kun Wan (Golden, CO)

1997-01-01T23:59:59.000Z

300

Methane hydrate formation and dissociation in a partially saturated sand  

SciTech Connect (OSTI)

To predict the behavior of hydrate-bearing sediments and the economic extractability of natural gas from reservoirs containing gas hydrates, we need reservoir simulators that properly represent the processes that occur, as well as accurate parameters. Several codes are available that represent some or all of the expected processes, and values for some parameters are available. Where values are unavailable, modelers have used estimation techniques to help with their predictions. Although some of these techniques are well respected, measurements are needed in many cases to verify the parameters. We have performed a series of experiments in a partially water saturated silica sand sample. The series included methane hydrate formation, and dissociation by both thermal stimulation and depressurization. The sample was 7.6 cm in diameter and 25 cm in length. In addition to measuring the system pressure and temperatures at four locations in the sample, we measured local density within the sample using x-ray computed tomography. Our goals in performing the experiment were to gather information for estimating thermal properties of the medium and to examine nonequilibrium processes.

Kneafsey, Timothy J.; Tomutsa, Liviu; Taylor, Charles E.; Gupta, Arvind; Moridis, George; Freifeld, Barry; Seol, Yongkoo

2004-11-24T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Gas Production from Hydrate-Bearing Sediments - Emergent Phenomena -  

SciTech Connect (OSTI)

Even a small fraction of fine particles can have a significant effect on gas production from hydrate-bearing sediments and sediment stability. Experiments were conducted to investigate the role of fine particles on gas production using a soil chamber that allows for the application of an effective stress to the sediment. This chamber was instrumented to monitor shear-wave velocity, temperature, pressure, and volume change during CO{sub 2} hydrate formation and gas production. The instrumented chamber was placed inside the Oak Ridge National Laboratory Seafloor Process Simulator (SPS), which was used to control the fluid pressure and temperature. Experiments were conducted with different sediment types and pressure-temperature histories. Fines migrated within the sediment in the direction of fluid flow. A vuggy structure formed in the sand; these small cavities or vuggs were precursors to the development of gas-driven fractures during depressurization under a constant effective stress boundary condition. We define the critical fines fraction as the clay-to-sand mass ratio when clays fill the pore space in the sand. Fines migration, clogging, vugs, and gas-driven fracture formation developed even when the fines content was significantly lower than the critical fines fraction. These results show the importance of fines in gas production from hydrate-bearing sediments, even when the fines content is relatively low.

Jung, J.W. [Georgia Institute of Technology; Jang, J.W. [Georgia Institute of Technology; Tsouris, Costas [ORNL; Phelps, Tommy Joe [ORNL; Rawn, Claudia J [ORNL; Santamarina, Carlos [Georgia Institute of Technology

2012-01-01T23:59:59.000Z

302

Assessing the Thermodynamic Feasibility of the Conversion of Methane Hydrate into Carbon Dioxide Hydrate in Porous Media  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Assessing the Thermodynamic Feasibility of the Conversion of Methane Assessing the Thermodynamic Feasibility of the Conversion of Methane Hydrate into Carbon Dioxide Hydrate in Porous Media Duane H. Smith (dsmith@netl.doe.gov; 304-285-4069), U.S. Department of Energy, National Energy Technology Laboratory, Morgantown, WV 26507-0880 Kal Seshadri (kal.seshadri@netl.doe.gov; 304-285-4680), Parsons Infrastructure and Technology Group, Morgantown, WV 26505 Joseph W. Wilder (wilder@math.wvu.edu; 304-293-2011), U.S. Department of Energy, National Energy Technology Laboratory, Morgantown, WV 26507-0880 (Permanent Address: Dept of Mathematics, P. O. Box 6310, West Virginia University, Morgantown, WV, 26506-6310) Abstract Concerns about the potential effects of rising carbon dioxide levels in the atmosphere have stimulated interest in a number of carbon dioxide sequestration studies. One

303

Methane hydrate distribution from prolonged and repeated formation in natural and compacted sand samples: X-ray CT observations  

SciTech Connect (OSTI)

To study physical properties of methane gas hydrate-bearing sediments, it is necessary to synthesize laboratory samples due to the limited availability of cores from natural deposits. X-ray computed tomography (CT) and other observations have shown gas hydrate to occur in a number of morphologies over a variety of sediment types. To aid in understanding formation and growth patterns of hydrate in sediments, methane hydrate was repeatedly formed in laboratory-packed sand samples and in a natural sediment core from the Mount Elbert Stratigraphic Test Well. CT scanning was performed during hydrate formation and decomposition steps, and periodically while the hydrate samples remained under stable conditions for up to 60 days. The investigation revealed the impact of water saturation on location and morphology of hydrate in both laboratory and natural sediments during repeated hydrate formations. Significant redistribution of hydrate and water in the samples was observed over both the short and long term.

Rees, E.V.L.; Kneafsey, T.J.; Seol, Y.

2010-07-01T23:59:59.000Z

304

NETL: Methane Hydrates - DOE/NETL Projects - A New Approach to  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A New Approach to Understanding the Occurrence and Volume of Natural Gas Hydrate in the Northern Gulf of Mexico Using Petroleum Industry Well Logs Last Reviewed 12/18/2013 A New Approach to Understanding the Occurrence and Volume of Natural Gas Hydrate in the Northern Gulf of Mexico Using Petroleum Industry Well Logs Last Reviewed 12/18/2013 DE-FE0009949 Goal The overarching objective of the project is to significantly increase our understanding of the occurrence, volume, and fine scale distribution of natural gas hydrate in the northern Gulf of Mexico using petroleum industry and Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) well logs. Performer The Ohio State University, Columbus, OH 43210 Background A large quantity of natural gas hydrate certainly occurs within the sediments of the northern Gulf of Mexico; however, the total amount and distribution of gas hydrate across the basin is relatively unconstrained

305

Challenges, uncertainties and issues facing gas production from gas hydrate deposits  

SciTech Connect (OSTI)

The current paper complements the Moridis et al. (2009) review of the status of the effort toward commercial gas production from hydrates. We aim to describe the concept of the gas hydrate petroleum system, to discuss advances, requirement and suggested practices in gas hydrate (GH) prospecting and GH deposit characterization, and to review the associated technical, economic and environmental challenges and uncertainties, including: the accurate assessment of producible fractions of the GH resource, the development of methodologies for identifying suitable production targets, the sampling of hydrate-bearing sediments and sample analysis, the analysis and interpretation of geophysical surveys of GH reservoirs, well testing methods and interpretation of the results, geomechanical and reservoir/well stability concerns, well design, operation and installation, field operations and extending production beyond sand-dominated GH reservoirs, monitoring production and geomechanical stability, laboratory investigations, fundamental knowledge of hydrate behavior, the economics of commercial gas production from hydrates, and the associated environmental concerns.

Moridis, G.J.; Collett, T.S.; Pooladi-Darvish, M.; Hancock, S.; Santamarina, C.; Boswell, R.; Kneafsey, T.; Rutqvist, J.; Kowalsky, M.; Reagan, M.T.; Sloan, E.D.; Sum, A.K.; Koh, C.

2010-11-01T23:59:59.000Z

306

Integrated Geologic and Geophysical Assessment of the Eileen Gas Hydrate Accumulation, North Slope, Alaska  

SciTech Connect (OSTI)

Using detailed analysis and interpretation of 2-D and 3-D seismic data, along with modeling and correlation of specially processed log data, a viable methodology has been developed for identifying sub-permafrost gas hydrate prospects within the Gas Hydrate Stability Zone (HSZ) and associated ''sub-hydrate'' free gas prospects in the Milne Point area of northern Alaska (Figure 1). The seismic data, in conjunction with modeling results from a related study, was used to characterize the conditions under which gas hydrate prospects can be delineated using conventional seismic data, and to analyze reservoir fluid properties. Monte Carlo style gas hydrate volumetric estimates using Crystal Ball{trademark} software to estimate expected in-place reserves shows that the identified prospects have considerable potential as gas resources. Future exploratory drilling in the Milne Point area should provide answers about the producibility of these shallow gas hydrates.

Timothy S. Collett; David J. Taylor; Warren F. Agena; Myung W. Lee; John J. Miller; Margarita Zyrianova

2005-04-30T23:59:59.000Z

307

Mechanisms Leading to Co-existence of Gas and Hydrate in Ocean Sediments  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Leading to Co-existence of Gas Leading to Co-existence of Gas and Hydrate in Ocean Sediments Steven Bryant Dept. of Petroleum and Geosystems Engineering The University of Texas at Austin and Ruben Juanes Dept. of Civil Engineering MIT Observations and Ruminations * Some proposed explanations for co-existence - kinetics of hydrate formation; - regional geotherms; - hypersaline brines as a result of hydrate formation;

308

Methane hydrate formation in turbidite sediments of northern Cascadia IODP Expedition 311  

SciTech Connect (OSTI)

Expedition 311 of the Integrated Ocean Drilling Program (IODP) to northern Cascadia recovered gas-hydrate bearing sediments along a SWNE transect from the first ridge of the accretionary margin to the eastward limit of gas-hydrate stability. In this study we contrast the gas gas-hydrate distribution from two sites drilled ~8 km apart in different tectonic settings. At Site U1325, drilled on a depositional basin with nearly horizontal sedimentary sequences, the gas-hydrate distribution shows a trend of increasing saturation toward the base of gas-hydrate stability, consistent with several model simulations in the literature. Site U1326 was drilled on an uplifted ridge characterized by faulting, which has likely experienced some mass wasting events. Here the gas hydrate does not show a clear depth-distribution trend, the highest gas-hydrate saturation occurs well within the gas-hydrate stability zone at the shallow depth of ~49 mbsf. Sediments at both sites are characterized by abundant coarse-grained (sand) layers up to 23 cm in thickness, and are interspaced within fine-grained (clay and silty clay) detrital sediments. The gas-hydrate distribution is punctuated by localized depth intervals of high gas-hydrate saturation, which preferentially occur in the coarse-grained horizons and occupy up to 60% of the pore space at Site U1325 and N80% at Site U1326. Detailed analyses of contiguous samples of different lithologies show that when enough methane is present, about 90% of the variance in gas-hydrate saturation can be explained by the sand (N63 ?m) content of the sediments. The variability in gas-hydrate occupancy of sandy horizons at Site U1326 reflects an insufficient methane supply to the sediment section between 190 and 245 mbsf.

Torres, M. E.; Trehu, Ann M.; cespedes, N.; Kastner, Miriam; Wortmann, Ulrich; Kim, J.; Long, Philip E.; Malinverno, Alberto; Pohlman, J. W.; Collett, T. S.

2008-07-15T23:59:59.000Z

309

Single Bifunctional Ruthenium Catalyst for One-Pot Cyclization and Hydration giving Functionalized Indoles and Benzofurans  

E-Print Network [OSTI]

Soc. 2004, 126, 12232. Catalyst 1 is now available from7992 7995 Bifunctional Ruthenium Catalyst COMMUNICATIONuse of bifunctional catalyst 1 for hydration and cycliza-

Nair, Reji??N.; Lee, Paul??J.; Rheingold, Arnold??L.; Grotjahn, Douglas??B.

2010-01-01T23:59:59.000Z

310

Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?  

SciTech Connect (OSTI)

Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

Paull, C.K.; Ussler, W. III; Borowski, W.S.

1993-09-01T23:59:59.000Z

311

Studies of Reaction Kinetics of Methane Hydrate Dissocation in Porous Media  

SciTech Connect (OSTI)

The objective of this study is the description of the kinetic dissociation of CH4-hydrates in porous media, and the determination of the corresponding kinetic parameters. Knowledge of the kinetic dissociation behavior of hydrates can play a critical role in the evaluation of gas production potential of gas hydrate accumulations in geologic media. We analyzed data from a sequence of tests of CH4-hydrate dissociation by means of thermal stimulation. These tests had been conducted on sand cores partially saturated with water, hydrate and CH4 gas, and contained in an x-ray-transparent aluminum pressure vessel. The pressure, volume of released gas, and temperature (at several locations within the cores) were measured. To avoid misinterpreting local changes as global processes, x-ray computed tomography scans provided accurate images of the location and movement of the reaction interface during the course of the experiments. Analysis of the data by means of inverse modeling (history matching ) provided estimates of the thermal properties and of the kinetic parameters of the hydration reaction in porous media. Comparison of the results from the hydrate-bearing porous media cores to those from pure CH4-hydrate samples provided a measure of the effect of the porous medium on the kinetic reaction. A tentative model of composite thermal conductivity of hydrate-bearing media was also developed.

Moridis, George J.; Seol, Yongkoo; Kneafsey, Timothy J.

2005-03-10T23:59:59.000Z

312

Ground movements associated with gas hydrate production. Progress report, October 1--December 31, 1992  

SciTech Connect (OSTI)

The grantee will evaluate the influence of hydrate production on ground subsidence near the wellbore and the surface. The objective of this research will be achieved by using computer simulations of what is expected in a hydrate reservoir during the production stage as reported by hydrate production models and available data. The model will be based on theories of continuum mechanics, thermomechanics of hydrate production, principles of rock mechanics and geomechanics, and special features of geomaterials under cold temperatures such as those found in permafrost regions. The research work involved in the proposed investigation will be divided into three major tasks; mechanics of subsidence in permafrost regions, modeling of subsidence, and parametric studies.

Siriwardane, H.J.

1992-12-31T23:59:59.000Z

313

Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates  

SciTech Connect (OSTI)

Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO{sub 2}) and/or production of methane (CH{sub 4}) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH{sub 4} and CO{sub 2} hydrate (CH{sub 4}-CO{sub 2} mixed hydrates), as well as thermophysical property changes during gas exchange. This study explores the thermal dissociation behavior and dissociation enthalpies of CH{sub 4}-CO{sub 2} mixed hydrates. We prepared CH{sub 4}-CO{sub 2} mixed hydrate samples from two different, well-defined gas mixtures. During thermal dissociation of a CH{sub 4}-CO{sub 2} mixed hydrate sample, gas samples from the head space were periodically collected and analyzed using gas chromatography. The changes in CH{sub 4}-CO{sub 2} compositions in both the vapor phase and hydrate phase during dissociation were estimated based on the gas chromatography measurements. It was found that the CO{sub 2} concentration in the vapor phase became richer during dissociation because the initial hydrate composition contained relatively more CO{sub 2} than the vapor phase. The composition change in the vapor phase during hydrate dissociation affected the dissociation pressure and temperature; the richer CO{sub 2} in the vapor phase led to a lower dissociation pressure. Furthermore, the increase in CO{sub 2} concentration in the vapor phase enriched the hydrate in CO{sub 2}. The dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate was computed by fitting the Clausius-Clapeyron equation to the pressure-temperature (PT) trace of a dissociation test. It was observed that the dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate lays between the limiting values of pure CH{sub 4} hydrate and CO{sub 2} hydrate, increasing with the CO{sub 2} fraction in the hydrate phase.

Kwon, T.H.; Kneafsey, T.J.; Rees, E.V.L.

2011-02-15T23:59:59.000Z

314

Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report  

SciTech Connect (OSTI)

Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

2007-09-01T23:59:59.000Z

315

Experimental determination of permeability of porous media in the presence of gas hydrates  

Science Journals Connector (OSTI)

Abstract Permeability variation, particularly in the presence of gas hydrates, greatly influences production of natural gas from hydrate reservoirs. A series of experiments were performed to investigate the variation of permeability in gas hydrates-bearing sediments. Carbon dioxide hydrate was formed in Ottawa 20/30 sand samples contained within a rigid cell using a partial water saturation formation methodology. Different initial water saturations were used to achieve hydrate saturations up to 45% and the corresponding water permeability was measured during steady-state flow. The experimental permeability results were compared with several theoretical models using both the quantitative and graphical analyses. A hybrid modeling approach based on the weighted combination of grain coating and the pore filling models was used to fit the measured experimental data. The experimental results were also compared to relevant experimental studies that used similar methods to form hydrates. Our analysis indicates a gradual reduction in permeability with increasing hydrate saturation, which is consistent with earlier studies. Further analysis using hybrid modeling suggests a progressive change in the hydrate formation morphology from cementing to that of the pore filling with increasing hydrate saturation.

Mohana L. Delli; Jocelyn L.H. Grozic

2014-01-01T23:59:59.000Z

316

Sensitivity Analysis of Gas Production from Class 2 and Class 3 Hydrate Deposits  

E-Print Network [OSTI]

Mexico, Fire In The Ice, NETL Methane Hydrates R&D ProgramBoswell and Kelly Rose of DOE-NETL for making the Tigershark

Reagan, Matthew

2009-01-01T23:59:59.000Z

317

Efficient storage of hydrogen fuel into leaky cages of clathrate hydrate  

Science Journals Connector (OSTI)

We demonstrate an alternative principle to efficiently store molecular hydrogen fuel into clathrate hydrate medium. Hydrogen-free hydrate powders quickly absorb the hydrogen gas at moderate pressure appropriate for industrial applications. The absorption kinetics was observed in situ by nuclear magnetic resonance(NMR)spectroscopy in a pressurized tube. The diffusion of hydrogen through the solid hydrate medium was directly measured by pulsed field gradient NMR. At temperatures down to 250 K the stored hydrogen is still mobile so that the hydrate storage should work well even in cold environments.

Takuo Okuchi; Igor L. Moudrakovski; John. A. Ripmeester

2007-01-01T23:59:59.000Z

318

U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies  

Broader source: Energy.gov [DOE]

Methane Hydrates May Exceed the Energy Content of All Other Fossil Fuels Combined; Could Ensure Decades of Affordable Natural Gas and Cut Americas Foreign Oil Dependence

319

Categorical Exclusion Determinations: A1 | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

August 31, 2012 August 31, 2012 CX-009304: Categorical Exclusion Determination Planning of a Marine Methane Hydrate Pressure Coring Program CX(s) Applied: A1, A9 Date: 08/31/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory August 30, 2012 CX-009313: Categorical Exclusion Determination Advanced Methane Hydrate Reservoir Modeling Using Rock Physics Techniques CX(s) Applied: A1, A9 Date: 08/30/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory August 29, 2012 CX-008916: Categorical Exclusion Determination Development of a Scientific Plan for a Hydrate-Focused Marine Drilling, Logging and Coring Program CX(s) Applied: A1, A9 Date: 08/29/2012 Location(s): Washington, DC Offices(s): National Energy Technology Laboratory August 29, 2012 CX-008912: Categorical Exclusion Determination

320

Basin scale assessment of gas hydrate dissociation in response to climate change  

SciTech Connect (OSTI)

Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating climate. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. Field investigations have discovered substantial methane gas plumes exiting the seafloor along the Arctic Ocean margin, and the plumes appear at depths corresponding to the upper limit of a receding gas hydrate stability zone. It has been suggested that these plumes may be the first visible signs of the dissociation of shallow hydrate deposits due to ongoing climate change in the arctic. We simulate the release of methane from oceanic deposits, including the effects of fully-coupled heat transfer, fluid flow, hydrate dissociation, and other thermodynamic processes, for systems representative of segments of the Arctic Ocean margins. The modeling encompasses a range of shallow hydrate deposits from the landward limit of the hydrate stability zone down to water depths beyond the expected range of century-scale temperature changes. We impose temperature changes corresponding to predicted rates of climate change-related ocean warming and examine the possibility of hydrate dissociation and the release of methane. The assessment is performed at local-, regional-, and basin-scales. The simulation results are consistent with the hypothesis that dissociating shallow hydrates alone can result in significant methane fluxes at the seafloor. However, the methane release is likely to be confined to a narrow region of high dissociation susceptibility, defined by depth and temperature, and that any release will be continuous and controlled, rather than explosive. This modeling also establishes the first realistic bounds for methane release along the arctic continental shelf for potential hydrate dissociation scenarios, and ongoing work may help confirm whether climate change is already impacting the stability of the vast oceanic hydrate reservoir.

Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.; Cameron-Smith, P.

2011-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Microsoft Word - Quarterly Report 4- DOE Hydrates.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

10195 10195 Quarterly Research Performance Progress Report (Period ending 8/31/2013) Methane Hydrate Field Program Project Period (October 1, 2012 - December 31, 2013) Submitted by: Greg Myers - Principal Investigator _________________________ Signature Consortium for Ocean Leadership DUNS #:046862582 1201 New York Avenue, NW Fourth Floor e-mail: gmyers@oceanleadership.org Phone number: (202) 448-1258 Prepared for: United States Department of Energy National Energy Technology Laboratory October 31, 2013 Office of Fossil Energy 2 ACCOMPLISHMENTS: The primary objective of the project is to conduct scientific planning that will help enable future scientific ocean drilling, coring, logging, testing and analytical activities to assess the geologic occurrence, regional

322

X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well  

SciTech Connect (OSTI)

When maintained under hydrate-stable conditions, methane hydrate in laboratory samples is often considered a stable and immobile solid material. Currently, there do not appear to be any studies in which the long-term redistribution of hydrates in sediments has been investigated in the laboratory. These observations are important because if the location of hydrate in a sample were to change over time (e.g. by dissociating at one location and reforming at another), the properties of the sample that depend on hydrate saturation and pore space occupancy would also change. Observations of hydrate redistribution under stable conditions are also important in understanding natural hydrate deposits, as these may also change over time. The processes by which solid hydrate can move include dissociation, hydrate-former and water migration in the gas and liquid phases, and hydrate formation. Chemical potential gradients induced by temperature, pressure, and pore water or host sediment chemistry can drive these processes. A series of tests were performed on a formerly natural methane-hydrate-bearing core sample from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well, in order to observe hydrate formation and morphology within this natural sediment, and changes over time using X-ray computed tomography (CT). Long-term observations (over several weeks) of methane hydrate in natural sediments were made to investigate spatial changes in hydrate saturation in the core. During the test sequence, mild buffered thermal and pressure oscillations occurred within the sample in response to laboratory temperature changes. These oscillations were small in magnitude, and conditions were maintained well within the hydrate stability zone.

Kneafsey, T.J.; Rees, E.V.L.

2010-03-01T23:59:59.000Z

323

Experimental studies on the P-T stability conditions and influencing factors of gas hydrate in different systems  

Science Journals Connector (OSTI)

The P-T stability conditions of gas hydrate in different systems (i.e., solution, silica sand, and marine sediment) were studied using...P-T stability conditions of gas hydrate were investigated. The results show...

ChangLing Liu; YuGuang Ye; ShiCai Sun; Qiang Chen

2013-04-01T23:59:59.000Z

324

theoretical and applied fracture  

E-Print Network [OSTI]

theoretical and applied fracture mechanics ELSEVIER Theoretical and Applied Fracture Mechanics 00 and Applied Fracture Mechanics 00 (1995) 000-000 Recently, some European countries developed defect specific. A suitable probabilistic fracture mechanic

Cizelj, Leon

325

Effect of Elevated Curing Temperature on Early Hydration and Microstructure of Composite Cements  

E-Print Network [OSTI]

Effect of Elevated Curing Temperature on Early Hydration and Microstructure of Composite Cements J, Seascale, Cumbria, CA20 1PG, UK Abstract The heat of hydration of a number of composite cement systems has of composite cements based on the partial replacement of Portland cement by waste materials has become

Sheffield, University of

326

New Project To Improve Characterization of U.S. Gas Hydrate Resources  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy today announced the selection of a multi-year, field-based research project designed to gain further insight into the nature, formation, occurrence and physical properties of methane hydrate?bearing sediments for the purpose of methane hydrate resource appraisal.

327

Analysis of the Development of Messoyakha Gas Field: A Commercial Gas Hydrate Reservoir  

E-Print Network [OSTI]

). Natural gas from methane hydrate has the potential to play a major role in ensuring adequate future energy supplies in the US. The worldwide volume of gas in the hydrate state has been estimated to be approximately 1.5 x 10^16 m^3 (Makogon 1984). More than...

Omelchenko, Roman 1987-

2012-12-11T23:59:59.000Z

328

Effects of Hydration on Mechanical Properties of a Highly Sclerotized Tissue  

E-Print Network [OSTI]

,* Michael G. Pontin,y J. Herbert Waite,* and Frank W. Zoky *Marine Science Institute and y Materials, this study examines the effects of hydration on their response to in- dentation, scratching, and wear. Hydration effects are greatest during wear testing, rates of material removal in water being about three

Zok, Frank

329

Development of a Numerical Simulator for Analyzing the Geomechanical Performance of Hydrate-Bearing Sediments  

SciTech Connect (OSTI)

In this paper, we describe the development and application of a numerical simulator that analyzes the geomechanical performance of hydrate-bearing sediments, which may become an important future energy supply. The simulator is developed by coupling a robust numerical simulator of coupled fluid flow, hydrate thermodynamics, and phase behavior in geologic media (TOUGH+HYDRATE) with an established geomechanical code (FLAC3D). We demonstrate the current simulator capabilities and applicability for two examples of geomechanical responses of hydrate bearing sediments during production-induced hydrate dissociation. In these applications, the coupled geomechanical behavior within hydrate-bearing seducements are considered through a Mohr-Coulomb constitutive model, corrected for changes in pore-filling hydrate and ice content, based on laboratory data. The results demonstrate how depressurization-based gas production from oceanic hydrate deposits may lead to severe geomechanical problems unless care is taken in designing the production scheme. We conclude that the coupled simulator can be used to design production strategies for optimizing production, while avoiding damaging geomechanical problems.

Rutqvist, Jonny; Rutqvist, J.; Moridis, G.J.

2008-06-01T23:59:59.000Z

330

METHANE HYDRATE STUDIES: DELINEATING PROPERTIES OF HOST SEDIMENTS TO ESTABLISH REPRODUCIBLE DECOMPOSITION KINETICS.  

SciTech Connect (OSTI)

The use of methane hydrate as an energy source requires development of a reliable method for its extraction from its highly dispersed locations in oceanic margin sediments and permafrost. The high pressure (up to 70 MPa) and low temperature (272 K to 278 K) conditions under which hydrates are stable in the marine environment can be mimicked in a laboratory setting and several kinetic studies of pure methane hydrate decomposition have been reported. However, the effect of host sediments on methane hydrate occurrence and decomposition are required to develop reliable hydrate models. In this paper, we describe methods to measure sediment properties as they relate to pore-space methane gas hydrate. Traditional geotechnical techniques are compared to the micrometer level by use of the synchrotron Computed Microtomography (CMT) technique. CMT was used to measure the porosity at the micrometer level and to show pore-space pathways through field samples. Porosities for three sediment samples: one from a site on Georges Bank and two from the known Blake Ridge methane hydrate site, from different depths below the mud line were measured by traditional drying and by the new CMT techniques and found to be in good agreement. The integration of the two analytical approaches is necessary to enable better understanding of methane hydrate interactions with the surrounding sediment particles.

MAHAJAN,D.SERVIO,P.JONES,K.W.FENG,H.WINTERS,W.J.

2004-12-01T23:59:59.000Z

331

Methane hydrate formation and dissociationin a partially saturatedcore-scale sand sample  

SciTech Connect (OSTI)

We performed a series of experiments to provide data forvalidating numerical models of gas hydrate behavior in porous media.Methane hydrate was formed and dissociated under various conditions in alarge X-ray transparent pressure vessel, while pressure and temperaturewere monitored. In addition, X-ray computed tomography (CT) was used todetermine local density changes during the experiment. The goals of theexperiments were to observe changes occurring due to hydrate formationand dissociation, and to collect data to evaluate the importance ofhydrate dissociation kinetics in porous media. In the series ofexperiments, we performed thermal perturbations on the sand/water/gassystem, formed methane hydrate, performed thermal perturbations on thesand/hydrate/water/gas system resulting in hydrate formation anddissociation, formed hydrate in the resulting partially dissociatedsystem, and dissociated the hydrate by depressurization coupled withthermal stimulation. Our CT work shows significant water migration inaddition to possible shifting of mineral grains in response to hydrateformation and dissociation. The extensive data including pressure,temperatures at multiple locations, and density from CT data isdescribed.

Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis, George J.; Seol,Yongkoo; Freifeld, Barry M.; Taylor, Charles E.; Gupta, Arvind

2006-02-03T23:59:59.000Z

332

Experimental study on the formation and dissociation conditions of methane hydrates in porous media  

E-Print Network [OSTI]

hydrates formed by methane gas and pure water in porous media. Methane gas hydrates were formed in a cell packed with 0.177-mm (0.007 in) diameter single sand (U.S. Sieve Series Designation Mesh No. 80) and 0.420-mm (0.017 in) diameter single sand (U...

Jung, Woodong

2012-06-07T23:59:59.000Z

333

High-Pressure Phase Behavior and Cage Occupancy for the CF4 Hydrate System  

Science Journals Connector (OSTI)

stability of Xe and CF4 clathrate hydrates was studied by evaluating various components of the free energy of formation. ... Introduction of CF4 gives rise to a significant distortion of the structure; whereas, Xe does not change the structure from the empty lattice. ... stability of Xe and CF4 hydrates. ...

Keisuke Sugahara; Masayoshi Yoshida; Takeshi Sugahara; Kazunari Ohgaki

2004-01-16T23:59:59.000Z

334

Estimation of methane flux offshore SW Taiwan and the influence of tectonics on gas hydrate accumulation  

E-Print Network [OSTI]

Estimation of methane flux offshore SW Taiwan and the influence of tectonics on gas hydrate simulating reflectors (BSRs) imply the potential existence of gas hydrates offshore southwestern Taiwan that the fluxes are very high in offshore southwestern Taiwan. The depths of the SMI are different at sites GH6

Lin, Andrew Tien-Shun

335

Born?Oppenheimer Molecular Dynamics of the Hydration of Na+ in a Water Cluster  

Science Journals Connector (OSTI)

Born?Oppenheimer Molecular Dynamics of the Hydration of Na+ in a Water Cluster ... The hydration of Na+ in a water cluster is studied through all-electron Born?Oppenheimer molecular dynamics. ... The method chosen in the present study was all-electron, density functional theory based, Born?Oppenheimer molecular dynamics (BOMD). ...

N. Galamba; B. J. Costa Cabral

2009-11-23T23:59:59.000Z

336

Sulfates on Mars: A systematic Raman spectroscopic study of hydration states of magnesium sulfates  

E-Print Network [OSTI]

Sulfates on Mars: A systematic Raman spectroscopic study of hydration states of magnesium sulfates of magnesium sulfates on the martian surface. In situ identification of the hydration states of magnesium of magnesium sulfate. Characteristic and distinct Raman spectral patterns were observed for each of the 11

337

Ocean methane hydrates as a slow tipping point in the global carbon cycle  

Science Journals Connector (OSTI)

...Hydrates in the Gulf of Mexico and Hydrate Ridge...half flowing down. The geothermal gradient is 40 K/km...42) climates, as well as intercomparisons...subsurface in the Gulf of Mexico . Mar Petrol Geol 18 : 551 560...the northern Gulf of Mexico . Geophys Res Lett 32...

David Archer; Bruce Buffett; Victor Brovkin

2009-01-01T23:59:59.000Z

338

Evaluation of the Gas Production Potential of Marine Hydrate Deposits in the Ulleung Basin of the Korean East Sea  

E-Print Network [OSTI]

sands interlayered with silts and clays, a regime that is not conducive to significant free gas and/or hydrate

Moridis, George J.; Reagan, Matthew T.; Kim, Se-Joon; Seol, Yongkoo; Zhang, Keni

2007-01-01T23:59:59.000Z

339

Tetrahydrofuran Hydrate Crystal Growth Inhibition by Trialkylamine Oxides and Synergism with the Gas Kinetic Hydrate Inhibitor Poly(N-vinyl caprolactam)  

Science Journals Connector (OSTI)

High Pressure Gas Hydrate Rocker Rig Equipment Test Methods ... Solid plugs caused by gas hydrate formation are a menace in various stages of the upstream oil and gas industry such as in production lines, during drilling (especially in deep water), and in work-over operations. ... (1, 4-7) In particular, the design of a new field development with LDHI technology can give large CAPEX savings. ...

Malcolm A. Kelland; Ann Helen Kvstad; Erik Langeland Astad

2012-06-26T23:59:59.000Z

340

An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs In  

Open Energy Info (EERE)

Study Method For Exploration Of Gas Hydrate Reservoirs In Study Method For Exploration Of Gas Hydrate Reservoirs In Marine Areas Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs In Marine Areas Details Activities (0) Areas (0) Regions (0) Abstract: We propose an integrated study method for exploration of gas hydrate reservoirs in marine areas. This method combines analyses of geology, seismology, and geochemistry. First, geological analysis is made using data of material sources, structures, sediments, and geothermal regimes to determine the hydrocarbon-formation conditions of gas hydrate in marine areas. Then analyses of seismic attributes,such as BSR, AVO, and BZ as well as forward modeling are conducted to predict the potential

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341

DOE Leads National Research Program in Gas Hydrates | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Leads National Research Program in Gas Hydrates Leads National Research Program in Gas Hydrates DOE Leads National Research Program in Gas Hydrates July 30, 2009 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy today told Congress the agency is leading a nationwide program in search of naturally occurring natural gas hydrates - a potentially significant storehouse of methane--with far reaching implications for the environment and the nation's future energy supplies. Read Dr. Boswell's testimony Dr. Ray Boswell, Senior Management and Technology Advisor at the Office of Fossil Energy's National Energy Technology Laboratory, testified before the House Natural Resources Subcommittee on Energy and Mineral Resources that the R&D program in gas hydrates is working to integrate and leverage

342

Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico |  

Broader source: Energy.gov (indexed) [DOE]

Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico Expedition Provides New Insight on Gas Hydrates in Gulf of Mexico May 14, 2013 - 10:00am Addthis USGS technicians Eric Moore and Jenny White deploy instruments at the start of a seismic survey to explore gas hydrates in the deepwater Gulf of Mexico from April to May 2013 | Photo courtesy of USGS USGS technicians Eric Moore and Jenny White deploy instruments at the start of a seismic survey to explore gas hydrates in the deepwater Gulf of Mexico from April to May 2013 | Photo courtesy of USGS Washington, DC - A joint-federal-agency 15-day research expedition in the northern Gulf of Mexico yielded innovative high-resolution seismic data and imagery that will help refine characterizations of large methane

343

Data from Innovative Methane Hydrate Test on Alaska's North Slope Now  

Broader source: Energy.gov (indexed) [DOE]

Data from Innovative Methane Hydrate Test on Alaska's North Slope Data from Innovative Methane Hydrate Test on Alaska's North Slope Now Available on NETL Website Data from Innovative Methane Hydrate Test on Alaska's North Slope Now Available on NETL Website March 11, 2013 - 10:07am Addthis DOE participated in gas hydrate field production trials in early 2012 in partnership with ConocoPhillips and the Japan Oil, Gas and Metals National Corp at the IÄ¡nik Sikumi (Inupiat for “Fire in the Ice”) test well, shown here, on the north slope of Alaska. Datasets from that field trial are now available to the public. DOE participated in gas hydrate field production trials in early 2012 in partnership with ConocoPhillips and the Japan Oil, Gas and Metals National Corp at the Iġnik Sikumi (Inupiat for "Fire in the Ice") test well,

344

Laboratory measurements on core-scale sediment/hydrate samples topredice reservoir behavior  

SciTech Connect (OSTI)

Measurements on hydrate-bearing laboratory and field samplesare necessary in order to provide realistic bounds on parameters used innumerically modeling the production of natural gas from hydrate-bearingreservoirs. The needed parameters include thermal conductivity,permeability, relative permeability-saturation(s) relationships, andcapillary pressure-saturation(s) relationships. We have developed atechnique to make hydrate-bearing samples ranging in scale from coreplug-size to core-size in the laboratory to facilitate making thesemeasurements. In addition to pressure and temperature measurements, weuse x-ray computed tomography scanning to provide high-resolution dataproviding insights on processes occurring in our samples. Several methodsare available to make gas hydrates in the laboratory, and we expect thatthe method used to make the hydrate will impact the behavior of thehydrate sample, and the parameters measured.

Kneafsey, Timothy J.; Seol, Yongkoo; Moridis, George J.; Tomutsa,Liviu; Freifeld, Barry M.

2005-11-02T23:59:59.000Z

345

Status of DOE Research Efforts in Gas Hydrates | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Status of DOE Research Efforts in Gas Hydrates Status of DOE Research Efforts in Gas Hydrates Status of DOE Research Efforts in Gas Hydrates July 30, 2009 - 1:38pm Addthis Statement of Dr. Ray Boswell, National Energy Technology Laboratory before the Committee on Natural Resources, Subcommittee on Energy and Mineral Resources, U.S. House of Representatives. Thank you, Mr. Chairman and Members of the Subcommittee. I appreciate this opportunity to provide testimony on the status of the United States Department of Energy's (DOE's) research efforts in naturally-occurring gas hydrates. INTRODUCTION Since 2000, DOE, through the Office of Fossil Energy's National Energy Technology Laboratory (NETL), has led the national research program in gas hydrates. The program is conducted through partnerships with private

346

Methane Hydrates R&D U S  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Power of Working Together the Power of Working Together Interagency Coordination on Methane Hydrates R&D U . S . D e p a r t m e n t o f E n e r g y * O f f i c e o f F o s s i l E n e r g y N a t i o n a l E n e r g y T e c h n o l o g y L a b o r a t o r y  Introduction Perhaps no areas of science are receiving more care- ful scrutiny and public discussion than those that deal with the interactions among earth, ocean, climate, and humanity. At the same time, our growing demands for energy are challenging us to find additional sources of clean fuel. The science of methane hydrates, a poten- tially vast source of natural gas that is part of a complex of dynamic natural systems, sits squarely in the center of these issues and the debates that surround them. Over the past two decades, scientists have been

347

Hydration of non-polar anti-parallel ?-sheets  

SciTech Connect (OSTI)

In this work we focus on anti-parallel ?-sheets to study hydration of side chains and polar groups of the backbone using all-atom molecular dynamics simulations. We show that: (i) water distribution around the backbone does not depend significantly on amino acid sequence, (ii) more water molecules are found around oxygen than nitrogen atoms of the backbone, and (iii) water molecules around nitrogen are highly localized in the planed formed by peptide backbones. To study hydration around side chains we note that anti-parallel ?-sheets exhibit two types of cross-strand pairing: Hydrogen-Bond (HB) and Non-Hydrogen-Bond (NHB) pairing. We show that distributions of water around alanine, leucine, and valine side chains are very different at HB compared to NHB faces. For alanine pairs, the space between side chains has a higher concentration of water if residues are located in the NHB face of the ?-sheet as opposed to the HB face. For leucine residues, the HB face is found to be dry while the space between side chains at the NHB face alternates between being occupied and non-occupied by water. Surprisingly, for valine residues the NHB face is dry, whereas the HB face is occupied by water. We postulate that these differences in water distribution are related to context dependent propensities observed for ?-sheets.

Urbic, Tomaz [Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aker?eva 5, SI-1000 Ljubljana (Slovenia)] [Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aker?eva 5, SI-1000 Ljubljana (Slovenia); Dias, Cristiano L., E-mail: cld@njit.edu [Physics Department, New Jersey Institute of Technology, Newark, New Jersey 07102-1982 (United States)

2014-04-28T23:59:59.000Z

348

Liquid-state polaron theory of the hydrated electron revisited  

E-Print Network [OSTI]

The quantum path integral/classical liquid-state theory of Chandler and co-workers, created to describe an excess electron in solvent, is re-examined for the hydrated electron. The portion that models electron-water density correlations is replaced by two equations: the range optimized random phase approximation (RO-RPA), and the DRL approximation to the "two-chain" equation, both shown previously to describe accurately the static structure and thermodynamics of strongly charged polyelectrolyte solutions. The static equilibrium properties of the hydrated electron are analyzed using five different electron-water pseudopotentials. The theory is then compared with data from mixed quantum/classical Monte Carlo and molecular dynamics simulations using these same pseudopotentials. It is found that the predictions of the RO-RPA and DRL-based polaron theories are similar and improve upon previous theory, with values for almost all properties analyzed in reasonable quantitative agreement with the available simulation data. Also, it is found using the Larsen, Glover and Schwartz pseudopotential that the theories give values for the solvation free energy that are at least three times larger than that from experiment.

James P. Donley; David R. Heine; Caleb A. Tormey; David T. Wu

2014-12-25T23:59:59.000Z

349

Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates  

SciTech Connect (OSTI)

An ab initio thermodynamic framework for predicting properties of hydrated magnesium carbonate minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including semiempirical dispersion via the Grimme method and small corrections to the generalized gradient approximation of Perdew, Burke, and Ernzerhof for the heat of formation yields a model with quantitative agreement for the benchmark minerals brucite, magnesite, nesquehonite, and hydromagnesite. The model shows how small differences in experimental conditions determine whether nesquehonite, hydromagnesite, or magnesite is the result of laboratory synthesis from carbonation of brucite, and what transformations are expected to occur on geological time scales. Because of the reliance on parameter-free first principles methods, the model is reliably extensible to experimental conditions not readily accessible to experiment and to any mineral composition for which the structure is known or can be hypothesized, including structures containing defects, substitutions, or transitional structures during solid state transformations induced by temperature changes or processes such as water, CO2, or O2 diffusion. Demonstrated applications of the ab initio thermodynamic framework include an independent means to evaluate differences in thermodynamic data for lansfordite, predicting the properties of Mg analogs of Ca-based hydrated carbonates monohydrocalcite and ikaite which have not been observed in nature, and an estimation of the thermodynamics of barringtonite from the stoichiometry and a single experimental observation.

Chaka, Anne M.; Felmy, Andrew R.

2014-03-28T23:59:59.000Z

350

Invasion of drilling mud into gas-hydrate-bearing sediments. Part II: Effects of geophysical properties of sediments  

Science Journals Connector (OSTI)

......sediments with hydrate veins or lenses...fracturing and the phase equilibrium pressure...with fractures, hydrate veins and lenses...2003). In the sand-silt mixture...gas production behavior in porous media...of Mexico Gas Hydrates joint Industry...estimating three-phase relative permeability......

Fulong Ning; Nengyou Wu; Yibing Yu; Keni Zhang; Guosheng Jiang; Ling Zhang; Jiaxin Sun; Mingming Zheng

2013-01-01T23:59:59.000Z

351

Application of Crunch-Flow Routines to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites  

SciTech Connect (OSTI)

In November 2012, Oregon State University initiated the project entitled: Application of Crunch-Flow routines to constrain present and past carbon fluxes at gas-hydrate bearing sites. Within this project we developed Crunch-Flow based modeling modules that include important biogeochemical processes that need to be considered in gas hydrate environments. Our modules were applied to quantify carbon cycling in present and past systems, using data collected during several DOE-supported drilling expeditions, which include the Cascadia margin in US, Ulleung Basin in South Korea, and several sites drilled offshore India on the Bay of Bengal and Andaman Sea. Specifically, we completed modeling efforts that: 1) Reproduce the compositional and isotopic profiles observed at the eight drilled sites in the Ulleung Basin that constrain and contrast the carbon cycling pathways at chimney (high methane flux) and non-chimney sites (low methane, advective systems); 2) Simulate the Ba record in the sediments to quantify the past dynamics of methane flux in the southern Hydrate Ridge, Cascadia margin; and 3) Provide quantitative estimates of the thickness of individual mass transport deposits (MTDs), time elapsed after the MTD event, rate of sulfate reduction in the MTD, and time required to reach a new steady state at several sites drilled in the Krishna-Godavari (K-G) Basin off India. In addition we developed a hybrid model scheme by coupling a home-made MATLAB code with CrunchFlow to address the methane transport and chloride enrichment at the Ulleung Basins chimney sites, and contributed the modeling component to a study focusing on pore-scale controls on gas hydrate distribution in sediments from the Andaman Sea. These efforts resulted in two manuscripts currently under review, and contributed the modeling component of another pare, also under review. Lessons learned from these efforts are the basis of a mini-workshop to be held at Oregon State University (Feb 2014) to instruct graduate students (OSU and UW) as well as DOE staff from the NETL lab in Albany on the use of Crunch Flow for geochemical applications.

Torres, Marta

2014-01-31T23:59:59.000Z

352

Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico  

SciTech Connect (OSTI)

A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

2009-07-15T23:59:59.000Z

353

Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico  

SciTech Connect (OSTI)

In the late spring of 2008, the Chevron-led Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) expects to conduct an exploratory drilling and logging campaign to better understand gas hydrate-bearing sands in the deepwater Gulf of Mexico. The JIP Site Selection team selected three areas to test alternative geological models and geophysical interpretations supporting the existence of potential high gas hydrate saturations in reservoir-quality sands. The three sites are near existing drill holes which provide geological and geophysical constraints in Alaminos Canyon (AC) lease block 818, Green Canyon (GC) 955, and Walker Ridge (WR) 313. At the AC818 site, gas hydrate is interpreted to occur within the Oligocene Frio volcaniclastic sand at the crest of a fold that is shallow enough to be in the hydrate stability zone. Drilling at GC955 will sample a faulted, buried Pleistocene channel-levee system in an area characterized by seafloor fluid expulsion features, structural closure associated with uplifted salt, and abundant seismic evidence for upward migration of fluids and gas into the sand-rich parts of the sedimentary section. Drilling at WR313 targets ponded sheet sands and associated channel/levee deposits within a minibasin, making this a non-structural play. The potential for gas hydrate occurrence at WR313 is supported by shingled phase reversals consistent with the transition from gas-charged sand to overlying gas-hydrate saturated sand. Drilling locations have been selected at each site to 1) test geological methods and models used to infer the occurrence of gas hydrate in sand reservoirs in different settings in the northern Gulf of Mexico; 2) calibrate geophysical models used to detect gas hydrate sands, map reservoir thicknesses, and estimate the degree of gas hydrate saturation; and 3) delineate potential locations for subsequent JIP drilling and coring operations that will collect samples for comprehensive physical property, geochemical and other analyses.

Hutchinson, D.R. (USGS); Shelander, D. (Schlumberger, Houston, TX); Dai, J. (Schlumberger, Hoston, TX); McConnell, D. (AOA Geophysics, Inc., Houston, TX); Shedd, W. (Minerals Management Service); Frye, M. (Minerals Management Service); Ruppel, C. (USGS); Boswell, R.; Jones, E. (Chevron Energy Technology Corp., Houston, TX); Collett, T.S. (USGS); Rose, K.; Dugan, B. (Rice Univ., Houston, TX); Wood, W. (U.S. Naval Research Laboratory); Latham, T. (Chevron Energy Technology Corp., Houston, TX)

2008-07-01T23:59:59.000Z

354

In situ apparatus for the study of clathrate hydrates relevant to solar system bodies using synchrotron X-ray diffraction and Raman spectroscopy  

E-Print Network [OSTI]

Clathrate hydrates are believed to play a significant role in various solar system environments, e.g. comets, and the surfaces and interiors of icy satellites, however the structural factors governing their formation and dissociation are poorly understood. We demonstrate the use of a high pressure gas cell, combined with variable temperature cooling and time-resolved data collection, to the in situ study of clathrate hydrates under conditions relevant to solar system environments. Clathrates formed and processed within the cell are monitored in situ using synchrotron X-ray powder diffraction and Raman spectroscopy. X-ray diffraction allows the formation of clathrate hydrates to be observed as CO2 gas is applied to ice formed within the cell. Complete conversion is obtained by annealing at temperatures just below the ice melting point. A subsequent rise in the quantity of clathrate is observed as the cell is thermally cycled. Four regions between 100-5000cm-1 are present in the Raman spectra that carry feature...

Day, Sarah J; Evans, Aneurin; Parker, Julia E

2015-01-01T23:59:59.000Z

355

Geologic interrelations relative to gas hydrates within the North Slope of Alaska: Task No. 6, Final report  

SciTech Connect (OSTI)

The five primary objectives of the US Geological Survey North Slope Gas Hydrate Project were to: (1) Determine possible geologic controls on the occurrence of gas hydrate; (2) locate and evaluate possible gas-hydrate-bearing reservoirs; (3) estimate the volume of gas within the hydrates; (4) develop a model for gas-hydrate formation; and (5) select a coring site for gas-hydrate sampling and analysis. Our studies of the North Slope of Alaska suggest that the zone in which gas hydrates are stable is controlled primarily by subsurface temperatures and gas chemistry. Other factors, such as pore-pressure variations, pore-fluid salinity, and reservior-rock grain size, appear to have little effect on gas hydrate stability on the North Slope. Data necessary to determine the limits of gas hydrate stability field are difficult to obtain. On the basis of mud-log gas chromatography, core data, and cuttings data, methane is the dominant species of gas in the near-surface (0--1500 m) sediment. Gas hydrates were identified in 34 wells utilizing well-log responses calibrated to the response of an interval in one well where gas hydrates were actually recovered in a core by an oil company. A possible scenario describing the origin of the interred gas hydrates on the North Slope involves the migration of thermogenic solution- and free-gas from deeper reservoirs upward along faults into the overlying sedimentary rocks. We have identified two (dedicated) core-hole sites, the Eileen and the South-End core-holes, at which there is a high probability of recovering a sample of gas hydrate. At the Eileen core-hole site, at least three stratigraphic units may contain gas hydrate. The South-End core-hole site provides an opportunity to study one specific rock unit that appears to contain both gas hydrate and oil. 100 refs., 72 figs., 24 tabs.

Collett, T.S.; Bird, K.J.; Kvenvolden, K.A.; Magoon, L.B.

1988-01-01T23:59:59.000Z

356

Scientific Objectives of the Gulf of Mexico Gas Hydrate JIP Leg II Drilling  

SciTech Connect (OSTI)

The Gulf of Mexico Methane Hydrate Joint Industry Project (JIP) has been performing research on marine gas hydrates since 2001 and is sponsored by both the JIP members and the U.S. Department of Energy. In 2005, the JIP drilled the Atwater Valley and Keathley Canyon exploration blocks in the Gulf of Mexico to acquire downhole logs and recover cores in silt- and clay-dominated sediments interpreted to contain gas hydrate based on analysis of existing 3-D seismic data prior to drilling. The new 2007-2009 phase of logging and coring, which is described in this paper, will concentrate on gas hydrate-bearing sands in the Alaminos Canyon, Green Canyon, and Walker Ridge protraction areas. Locations were selected to target higher permeability, coarser-grained lithologies (e.g., sands) that have the potential for hosting high saturations of gas hydrate and to assist the U.S. Minerals Management Service with its assessment of gas hydrate resources in the Gulf of Mexico. This paper discusses the scientific objectives for drilling during the upcoming campaign and presents the results from analyzing existing seismic and well log data as part of the site selection process. Alaminos Canyon 818 has the most complete data set of the selected blocks, with both seismic data and comprehensive downhole log data consistent with the occurrence of gas hydrate-bearing sands. Preliminary analyses suggest that the Frio sandstone just above the base of the gas hydrate stability zone may have up to 80% of the available sediment pore space occupied by gas hydrate. The proposed sites in the Green Canyon and Walker Ridge areas are also interpreted to have gas hydrate-bearing sands near the base of the gas hydrate stability zone, but the choice of specific drill sites is not yet complete. The Green Canyon site coincides with a 4-way closure within a Pleistocene sand unit in an area of strong gas flux just south of the Sigsbee Escarpment. The Walker Ridge site is characterized by a sand-prone sedimentary section that rises stratigraphically across the base of the gas hydrate stability zone and that has seismic indicators of gas hydrate. Copyright 2008, Offshore Technology Conference

Jones, E. (Chevron); Latham, T. (Chevron); McConnell, D. (AOA Geophysics); Frye, M. (Minerals Management Service); Hunt, J. (Minerals Management Service); Shedd, W. (Minerals Management Service); Shelander, D. (Schlumberger); Boswell, R.M. (NETL); Rose, K.K. (NETL); Ruppel, C. (USGS); Hutchinson, D. (USGS); Collett, T. (USGS); Dugan, B. (Rice University); Wood, W. (Naval Research Laboratory)

2008-05-01T23:59:59.000Z

357

Modeling of structure H hydrate equilibria for methane, intermediate hydrocarbon molecules and water systems  

SciTech Connect (OSTI)

Clathrate hydrates are inclusion compounds in which guest molecules are engaged by water molecules under favorable conditions of pressure and temperature. The well known structures 1 and 2 have been discovered since last century, while a new structure called H has been recently described in the literature. Since that time, structure H hydrate equilibrium data involving methane and different intermediate liquid hydrocarbon molecules have been published. The equilibrium calculations involving hydrates are based on the fact that the chemical potential of water in the aqueous liquid phase is equal to the one in the hydrate phase. The chemical potential of water in the liquid aqueous phase can be easily described by classical thermodynamic relations, while the chemical potential of water in the hydrates phase is described by the expressions proposed by Van der Walls and Platteeuw derived from an adsorption model based on statistical thermodynamics. The authors present in this paper a set of Kihara potential parameters which enable the calculation of Langmuir constants which characterize the adsorption of some naphthenic and iso-paraffinic intermediate hydrocarbons in the larger cage of structure H hydrates. This work thus allows the computation of structural H hydrate equilibrium conditions for systems made of methane, intermediate hydrocarbon molecules and water.

Thomas, M.; Behar, E. [Inst. Francais du Petrole, Rueil-Malmaison (France)

1996-12-31T23:59:59.000Z

358

Physical property changes in hydrate-bearingsediment due to depressurization and subsequent repressurization  

SciTech Connect (OSTI)

Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed at least briefly to non-in situ conditions during recovery. To examine effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes and speeds are compared between the original and depressurized/repressurized samples. X-ray computed tomography (CT) images track how the gas-hydrate distribution changes in the hydrate-cemented sands due to the depressurization/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.

Kneafsey, Timothy; Waite, W.F.; Kneafsey, T.J.; Winters, W.J.; Mason, D.H.

2008-06-01T23:59:59.000Z

359

Sensitivity Analysis of Gas Production from Class 2 and Class 3 Hydrate Deposits  

SciTech Connect (OSTI)

Gas hydrates are solid crystalline compounds in which gas molecules are lodged within the lattices of an ice-like crystalline solid. The vast quantities of hydrocarbon gases trapped in hydrate formations in the permafrost and in deep ocean sediments may constitute a new and promising energy source. Class 2 hydrate deposits are characterized by a Hydrate-Bearing Layer (HBL) that is underlain by a saturated zone of mobile water. Class 3 hydrate deposits are characterized by an isolated Hydrate-Bearing Layer (HBL) that is not in contact with any hydrate-free zone of mobile fluids. Both classes of deposits have been shown to be good candidates for exploitation in earlier studies of gas production via vertical well designs - in this study we extend the analysis to include systems with varying porosity, anisotropy, well spacing, and the presence of permeable boundaries. For Class 2 deposits, the results show that production rate and efficiency depend strongly on formation porosity, have a mild dependence on formation anisotropy, and that tighter well spacing produces gas at higher rates over shorter time periods. For Class 3 deposits, production rates and efficiency also depend significantly on formation porosity, are impacted negatively by anisotropy, and production rates may be larger, over longer times, for well configurations that use a greater well spacing. Finally, we performed preliminary calculations to assess a worst-case scenario for permeable system boundaries, and found that the efficiency of depressurization-based production strategies are compromised by migration of fluids from outside the system.

Reagan, Matthew; Moridis, George; Zhang, Keni

2008-05-01T23:59:59.000Z

360

Evaluation of the geological relationships to gas hydrate formation and stability  

SciTech Connect (OSTI)

The summaries of regional basin analyses document that potentially economic accumulations of gas hydrates can be formed in both active and passive margin settings. The principal requirement for gas hydrate formation in either setting is abundant methane. Passive margin sediments with high sedimentation rates and sufficient sedimentary organic carbon can generate large quantities of biogenic methane for hydrate formation. Similarly, active margin locations near a terrigenous sediment source can also have high methane generation potential due to rapid burial of adequate amounts of sedimentary organic matter. Many active margins with evidence of gas hydrate presence correspond to areas subject to upwelling. Upwelling currents can enhance methane generation by increasing primary productivity and thus sedimentary organic carbon. Structural deformation of the marginal sediments at both active and passive sites can enhance gas hydrate formation by providing pathways for migration of both biogenic and thermogenic gas to the shallow gas hydrate stability zone. Additionally, conventional hydrocarbon traps may initially concentrate sufficient amounts of hydrocarbons for subsequent gas hydrate formation.

Krason, J.; Finley, P.

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

SciTech Connect (OSTI)

Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

2011-06-01T23:59:59.000Z

362

CO{sub 2} HYDRATE PROCESS FOR GAS SEPARATION  

SciTech Connect (OSTI)

Modifications were implemented to the hydrogen flow test rig per safety review comments, and the apparatus was tested for leaks. Tests were then done using Helium/CO{sub 2} mixtures to re-verify performance prior to hydrogen testing. It was discovered that hydrate formation was more difficult to initiate, and new initiation methods were developed to improve the tests. Delivery of ETM hardware continued and buildup of the ETM system continued, the ETM is now mechanically complete. The STU (pilot plant) site selection process was resumed because Tennessee Eastman declined to participate in the program. Two potential sites were visited: The Global Energy/Conoco-Phillips Wabash River Plant, and the Tampa Electric Polk Power Plant.

G. Deppe; R. Currier; D. Spencer

2004-01-01T23:59:59.000Z

363

Origin of Entropy Convergence in Hydrophobic Hydration and Protein Folding  

SciTech Connect (OSTI)

An information theory model of hydrophobic effects is used to construct a molecular explanation why hydrophobic solvation entropies of protein unfolding measured by high sensitivity calorimetry converge to zero at a common convergence temperature. The entropy convergence follows directly from the weak temperature dependence of occupancy fluctuations {l_angle}{delta}{ital n}{sup 2}{r_angle} for molecular-scale volumes in water. The macroscopic expression of the contrasting entropic behavior of water relative to common organic solvents is the {ital relative} temperature insensitivity of the water isothermal compressibility compared to hydrocarbon liquids. The information theory model used provides a quantitative description of small molecule hydration and, in addition, predicts that the value of the entropy at convergence is slightly {ital negative}. Interpretations of entropic contributions to protein folding should account for this result. {copyright} {ital 1996 The American Physical Society.}

Garde, S.; Hummer, G.; Garcia, A.E.; Paulaitis, M.E.; Pratt, L.R. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); [Center for Molecular and Engineering Thermodynamics, Department of Chemical Engineering, University of Delaware, Newark, Delaware 19716 (United States); [Department of Chemical Engineering, Johns Hopkins University, Baltimore, Maryland 21218 (United States)

1996-12-01T23:59:59.000Z

364

Structure H hydrate phase equilibria of paraffins, naphthalenes, and olefins with methane  

SciTech Connect (OSTI)

Initial phase equilibrium data are reported for 10 methane + liquid hydrocarbon systems forming structure H hydrates in the pressure range of 1--6 MPa. Four-phase equilibrium conditions were measured for each system, with paraffinic, naphthenic, and olefinic liquid hydrocarbons filling the large cage of structure H, and methane stabilizing the two smaller cages present in the hydrate. Many of these liquid hydrocarbons constitute a small fraction of crude oils and condensates, and the high stability and relative ease of formation of structure H suggest a possible impact of these hydrates upon hydrocarbon facilities.

Mehta, A.P.; Sloan, E.D. Jr. (Colorado School of Mines, Golden, CO (United States))

1994-10-01T23:59:59.000Z

365

Structure Analyses of Artificial Methane Hydrate Sediments by Microfocus X-ray Computed Tomography  

Science Journals Connector (OSTI)

The structure of natural gas hydrate sediments was characterized by microfocus X-ray computed tomography (CT). The obtained two-dimensional (2-D) and three-dimensional (3-D) images clearly showed the spatial distribution of the free-gas spaces, sand particles, and hydrates or ices. The estimated porosity from the X-ray CT data was consistent with the value that was obtained from the sample mass and volume. These results indicate that microfocus X-ray CT can be very useful for researching natural samples of hydrate sediments.

Shigeki Jin; Satoshi Takeya; Junko Hayashi; Jiro Nagao; Yasushi Kamata; Takao Ebinuma; Hideo Narita

2004-01-01T23:59:59.000Z

366

POSITION OPENING APPLIED STATISTICS  

E-Print Network [OSTI]

: Assistant or Associate Professor of Applied Statistics. Employment Beginning: September 16, 2012 DescriptionPOSITION OPENING APPLIED STATISTICS Department of Decision Sciences Charles H. Lundquist College at the University of Oregon is seeking to fill one tenure-track faculty position in Applied Statistics. Rank

Shepp, Larry

367

Acoustic properties of natural gas hydrates and the geophysical assessment of the subsurface distribution of hydrates in the Gulf of Mexico and Atlantic.  

Science Journals Connector (OSTI)

Natural gas hydrates are a solid form of natural gas found in the deep water marine margins of continents and under permafrost in Arctic regions worldwide. They have been recognized as a very significant potential energy source in the future. They form under high pressure and low temperature. Hydrate saturated sediments are acoustically faster and slightly less dense than water saturated sediments but much faster and denser than gas saturated sediments. These properties allow for the identification of marine hydrate saturated sediments that are underlain by gas saturated sediments. The resulting geophysical reflector referred to as a bottom simulating reflector or BSR often mimics the seafloor in areas where geothermal gradient is laterally consistent. The Bureau of Ocean Energy Management Regulation and Enforcement has used three?dimensional seismic data in the Gulf of Mexico and two?dimensional seismic data in the Atlantic to (1) map the distribution of BSRs (2) drill six wells in the GOM with moderate to high hydrate saturations in sand reservoirs and (3) assess the resource potential of hydrates.

William Shedd; Matt Frye; Paul Godfriaux; Kody Kramer

2011-01-01T23:59:59.000Z

368

Applied quantum mechanics 1 Applied Quantum Mechanics  

E-Print Network [OSTI]

that describe the time-dependent state . If can be expressed as a power series in the perturbing potential of a one dimensional har- monic oscillator. At time t = 0 a perturbation is applied where V0-dimensional rectangular potential well for which in the range and elsewhere. It is decided to control the state

Levi, Anthony F. J.

369

CONTENTS BOEM Releases Assessment of In-Place Gas Hydrate Resources  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BOEM Releases Assessment of BOEM Releases Assessment of In-Place Gas Hydrate Resources of the Lower 48 United States Outer Continental Shelf ..............1 Re-examination of Seep Activity at the Blake Ridge Diapir ............6 Field Data from 2011/2012 ConocoPhillips-JOGMEC-DOE Iġnik Sikumi Gas Hydrate Field Trial Now Available .......................9 Announcements .......................11 * Norwegian Center of Excellence to Receive Ten Years of Arctic Research Funding * Release of Mallik 2007-2008 Results * Goldschmidt Conference * 2012 Methane Hydrate Research Fellowship Awarded to Jeffrey James Marlow Spotlight on Research........... 16 Bjørn Kvamme CONTACT Ray Boswell Technology Manager-Methane Hydrates, Strategic Center for Natural Gas & Oil 304-285-4541 ray.boswell@netl.doe.gov

370

NETL: Methane Hydrates - DOE/NETL Projects - Controls On Methane Expulsion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Controls On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 12/24/2013 Controls On Methane Expulsion During Melting Of Natural Gas Hydrate Systems Last Reviewed 12/24/2013 DE-FE0010406 Goal The project goal is to predict, given characteristic climate-induced temperature change, the conditions under which gas will be expelled from existing accumulations of gas hydrate into the shallow ocean or directly to the atmosphere. When those conditions are met, the fraction of the gas accumulation that escapes and the rate of escape shall be quantified. The predictions shall be applicable in Arctic regions and in gas hydrate systems at the updip limit of the stability zone on continental margins. The behavior shall be explored in response to both longer term changes in sea level (e.g., twenty-thousand years) and shorter term due to atmospheric

371

Current State of Literature on CO2 Clathrate Hydrates -- Transport Related Issues  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

State of Literature on State of Literature on CO 2 Clathrate Hydrates Transport Related Issues Transport Related Issues Hydrate in suspension models Model (3) Model (3) Analysis Analysis Perforated plate models Model (2) Model (2) Analysis Analysis CO2 Permeable Plate models Model (2) Model (2) Analysis Analysis Transport model and analysis Wrong or no physical basis Not proven correct Correct and/or consistent CO 2 Transport Mechanisms in the literature: CO 2 H 2 O diffuse boundary layer Concentra tion r C o C infty C h1 C h2 C i C o : Conc. of pure liq CO 2 C h1 : Conc. of CO2 at full occupancy C h2 : Conc.of CO 2 in hydrate at interface that in equil with water saturated with CO 2 . C i : Conc. of CO 2 in liq. water adjoining hydrate C infty

372

NETL: National Methane Hydrates R&D Program- 2009 GOM JIP Expedition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The National Methane Hydrates R&D Program The National Methane Hydrates R&D Program 2009 Gulf of Mexico JIP - Leg II DOE-Sponsored Expedition Confirms Resource-Quality Gas Hydrate in the Gulf of Mexico Leg II Initial Scientific Reports Now Available Photo of semi-submersible Helix Project Background Participants Pre-Drilling Expedition Overview Drilling/Logging Sites The LWD Program Site Summaries Walker Ridge-Block 313 Green Canyon-Block 955 Alaminos Canyon block 21 and East Breaks block 992 JIP Website [external site] FITI article - Summer 2009 Leg II Initial Scientific Reports On May 6, 2009, the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL)in collaboration with the U.S. Geological Survey (USGS), the U.S. Minerals Management Service, an industry research consortium led by Chevron, and others completed a landmark gas hydrate

373

U.S. and Japan Complete Successful Field Trial of Methane Hydrate  

Broader source: Energy.gov (indexed) [DOE]

U.S. and Japan Complete Successful Field Trial of Methane Hydrate U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies May 2, 2012 - 1:00pm Addthis Washington, DC - U.S. Energy Secretary Steven Chu announced today the completion of a successful, unprecedented test of technology in the North Slope of Alaska that was able to safely extract a steady flow of natural gas from methane hydrates - a vast, entirely untapped resource that holds enormous potential for U.S. economic and energy security. Building upon this initial, small-scale test, the Department is launching a new research effort to conduct a long-term production test in the Arctic as well as research to test additional technologies that could be used to locate,

374

Proceedings of the Guld of Mexico Hydrates R&D Planning Workshop  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gulf of Mexico Hydrates R&D Planning Workshop Gulf of Mexico Hydrates R&D Planning Workshop Contents Disclaimer Participant Letter Executive Summary Papers and Presentations Welcome DOE National Hydrates Program Overview Industry Perspectives Panel Session Project Reviews Panel Session Appendices A - Breakout Session Products B - Participants List C - Poster Session Participants Proceedings of the Gulf of Mexico Hydrates R&D Planning Workshop Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or

375

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

376

Product design and development of an aerodynamic hydration system for bicycling and triathlon  

E-Print Network [OSTI]

Proper hydration and aerodynamic performance are both essential needs of a competitive cyclist or triathlete. Several aerodynamic systems have been developed for use on bicycles but few have been designed to be truly ...

Cote, Mark (Mark Brian)

2007-01-01T23:59:59.000Z

377

Effect of the Additives on the Desulphurization Rate of Flash Hydrated and Agglomerated CFB Fly Ash  

Science Journals Connector (OSTI)

CFB fly ash from separators was mixed with ... and water or additives was pumped into a CFB combustion chamber by a sludge pump. Because ... the temperature of flue gas was high in CFB, the fly ash was hydrated f...

D. X. Li; H. L. Li; M. Xu; J. F. Lu; Q. Liu

2010-01-01T23:59:59.000Z

378

Structural basis for the transformation pathways of the sodium naproxen anhydrate-hydrate system  

Science Journals Connector (OSTI)

Relationships between the crystal structures of two polymorphs of sodium naproxen dihydrate and its monohydrate and anhydrate phases provide a basis to rationalize the observed transformation pathways in the sodium (S)-naproxen anhydrate-hydrate system.

Bond, A.D.

2014-08-20T23:59:59.000Z

379

Tetra- and hexahydrates of bis(adeninium) zoledronate  

Science Journals Connector (OSTI)

In two hydrated structures of bis(adeninium) zoledronate, the zoledronate anion displays its usual zwitterionic character, with a protonated imidazole ring; however, the ionization state of the phosphonate groups of the anions are different.

Sridhar, B.

2013-12-21T23:59:59.000Z

380

Development of an electrical resistivity cone for the detection of gas hydrates in marine sediments  

E-Print Network [OSTI]

onshore and offshore environments, as well as in permafrost and tropical regions. The presence of natural gas hydrates in marine sediments are of concern to geotechnical engineers for several reasons, including: (1) their effect on the load bearing...

McClelland, Martha Ann

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Trace element mineral transformations associated with hydration and recarbonation of retorted oil shale  

Science Journals Connector (OSTI)

A laboratory study was conducted to evaluate the influence of hydration and recarbonation on the solidphase distribution of trace elements in retorted oil shale. The oil shale samples were retorted by the Paraho ...

M. E. Essington

382

Water Density Fluctuations Relevant to Hydrophobic Hydration are Unaltered by Attractions  

E-Print Network [OSTI]

An understanding of density fluctuations in bulk water has made significant contributions to our understanding of the hydration and interactions of idealized, purely repulsive hydrophobic solutes. To similarly inform the hydration of realistic hydrophobic solutes that have dispersive interactions with water, here we characterize water density fluctuations in the presence of attractive fields that correspond to solute-water attractions. We find that when the attractive field acts only in the solute hydration shell, but not in the solute core, it does not significantly alter water density fluctuations in the solute core region. We further find that for a wide range of solute sizes and attraction strengths, the free energetics of turning on the attractive fields in bulk water are accurately captured by linear response theory. Our results also suggest strategies for more efficiently estimating hydration free energies of realistic solutes in bulk water and at interfaces.

Richard C. Remsing; Amish J. Patel

2014-10-07T23:59:59.000Z

383

Ground movements associated with gas hydrate production. Progress report, July 1--September 30, 1992  

SciTech Connect (OSTI)

The grantee will evaluate the influence of hydrate production on ground subsidence near the wellbore and the surface. The objective of this research will be achieved by using computer simulations of what is expected in a hydrate reservoir during the production stage as reported by hydrate production models and available data. The model will be based on theories of continuum mechanics, thermomechanics of hydrate production, principles of rock mechanics and geomechanics, and special features of geomaterials under cold temperatures such as those found in permafrost regions. The research work involved in the proposed investigation will be divided into three major tasks: (1) Mechanics of subsidence in permafrost regions; (2) modeling of subsidence; and (3) parametric studies. Progress reports are presented for tasks 1 and 2.

Siriwardane, H.J.

1992-12-31T23:59:59.000Z

384

Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments  

E-Print Network [OSTI]

bound gas in marine sediments: how much is really out there?methane hydrate in ocean sediment. Energy & Fuels 2005: 19:Accumulations in Oceanic Sediments George J. Moridis 1 and

Moridis, George J.; Sloan, E. Dendy

2006-01-01T23:59:59.000Z

385

Simulation of gas production from hydrate reservoir by the combination of warm water flooding and depressurization  

Science Journals Connector (OSTI)

Gas production from hydrate reservoir by the combination of warm water flooding and depressurization is proposed, which can overcome ... gas production by the combination of warm water flooding and depressurizati...

YuHu Bai; QingPing Li

2010-09-01T23:59:59.000Z

386

Alkene Hydrofunctionalization Using Hydroxamic Acids: A Radical-Mediated Approach to Alkene Hydration  

Science Journals Connector (OSTI)

A radical-mediated approach to alkene hydration is described. The present strategy capitalizes on the unique radical reactivity of hydroxamic acids, which are capable of functioning as both synthetically useful oxygen-centered radical species and suitable ...

Benjamin C. Giglio; Erik J. Alexanian

2014-07-28T23:59:59.000Z

387

Challenges, uncertainties and issues facing gas production from gas hydrate deposits  

E-Print Network [OSTI]

gas such as tight gas, shale gas, or coal bed methane gas tolocation. Development of shale oil and gas, tar sands, coalGas hydrates will undoubtedly also be present in shales,

Moridis, G.J.

2011-01-01T23:59:59.000Z

388

Sulfur geochemistry of thermogenic gas hydrate and associated sediment from the Texas-Louisiana continental slope  

E-Print Network [OSTI]

total reduced sulfide (TRS), acid volatile sulfide, and citrate-dithionate and HCl extractable iron. Pore-fluid measurements included []H?S, chloride, sulfate, ammonia and total dissolved inorganic carbon. Gas hydrate hydrogen sulfide and carbon dioxide...

Gledhill, Dwight Kuehl

2001-01-01T23:59:59.000Z

389

Microbial Communities from Methane Hydrate-Bearing Deep Marine Sediments in a Forearc Basin  

Science Journals Connector (OSTI)

...Proceedings of the Ocean Drilling Program Scientific Results, vol. 146. Oceanic Drilling Program, College Station...methane quantities in a large gas-hydrate reservoir...microbiological samples by drilling, p. 23-44. In P. S...

David W. Reed; Yoshiko Fujita; Mark E. Delwiche; D. Brad Blackwelder; Peter P. Sheridan; Takashi Uchida; Frederick S. Colwell

2002-08-01T23:59:59.000Z

390

Study by thermogravimetry of the evolution of ettringite phase during type II Portland cement hydration  

Science Journals Connector (OSTI)

Thermogravimetry (TG) and derivative thermogravimetry (DTG) have been used by the authors as very effective tools to study hydration steps of cements used for solidification/stabilization of tanning wastes. The p...

J. Dweck; P. F. Ferreira da Silva

2002-07-01T23:59:59.000Z

391

Assessment of sorbent reactivation by water hydration for fluidized bed combustion application  

SciTech Connect (OSTI)

Disposal of fluidized bed combustion (FBC) solid residues currently represents one of the major issues in FBC design and operation, and contributes significantly to its operating cost. This issue has triggered research activities on the enhancement of sorbent utilization for in situ sulfur removal. The present study addresses the effectiveness of the reactivation by liquid water hydration of FB spent sorbents. Two materials are considered in the study, namely the bottom ash from the operation of a full-scale utility FB boiler and the raw commercial limestone used in the same boiler. Hydration-reactivation tests were carried out at temperatures of 40{sup o}C and 80{sup o}C and for curing times ranging from 15 minutes to 2d, depending on the sample. The influence of hydration conditions on the enhancement of sulfur utilization has been assessed. A combination of methods has been used to characterize the properties of liquid water-hydrated materials

Fabio Montagnaro; Piero Salatino; Fabrizio Scala; Yinghai Wu; Edward J. Anthony; Lufei Jia [Universita degli Studi di Napoli Federico II, Complesso Universitario del Monte di Sant'Angelo, Naples (Italy). Dipartimento di Chimica

2006-06-15T23:59:59.000Z

392

THE SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES...  

Office of Scientific and Technical Information (OSTI)

SYSTEM THORIUM NITRATE-WATER-NITRIC ACID AT 25 AND THE HYDRATES OF THORIUM NITRATE Re-direct Destination: Temp Data Fields Ferraro, J.R.; Katzin, L.I. Temp Data Storage 3: Argonne...

393

Detection of Gas Hydrates in Garden Banks and Keathley Canyon from Seismic Data  

E-Print Network [OSTI]

, where the sub-seafloor is a complex structure of shallow salt diapirs and sheets underlying heavily deformed shallow sediments and surrounding diverse minibasins. Here, we consider the effect these structural factors have on gas hydrate occurrence...

Murad, Idris

2011-08-08T23:59:59.000Z

394

The U.S. DOE Methane Hydrate R&D Program DOE Sponsored Student...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

H. and D. Smith, 2002. "Synthesis and Homogeneity of Methane Hydrate in Unconsolidated Media," Journal of Testing and Evaluation, Vol. 30, p. 1-7. Smith, D., J. Wilder, and K....

395

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

396

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

397

Numerical Modeling of Hydrate Formation in Sand Sediment Simulating Sub-Seabed CO2 Storage in the form of Gas Hydrate  

Science Journals Connector (OSTI)

Abstract Among several methods for CO2 capture and storage, we focus on CO2 sequestration in the form of gas hydrate under the seafloor, mainly for many sequestration sites offshore Japan and for little risk of CO2 leakage from the sediment. However, it is difficult to evaluate the precise storage potential and cost of this method due to the lack of the relevant information. Here, in order to do feasibility studies of this technique so as to make an effective storage method, we made a 3-dimentional gas water flow simulator with kinetic hydrate formation. The new design of CO2 hydrate formation in porous media under two-phase flow condition was implemented in this simulator, and unknown parameters in necessary mathematical models for gas-water flow in sand sediments were verified from the comparison between the results of the numerical simulations and the experimental measurements from the previous study.

Takuya Nakashima; Toru Sato; Masayuki Inui

2013-01-01T23:59:59.000Z

398

Geological evolution and analysis of confirmed or suspected gas hydrate localities: Volume 6, Basin analysis, formation and stability of gas hydrates in the Panama Basin  

SciTech Connect (OSTI)

This report presents a geological description of the Panama Basin, including regional and local structural settings, geomorphology, geological history, stratigraphy, and physical properties. It provides the necessary regional and geological background for more in-depth research of the area. Detailed discussion of bottom simulating acoustic reflectors, sediment acoustic properties, distribution of hydrates within the sediments, and the relation of hydrate distribution to other features such as salt diapirism are also included. The formation and stabilization of gas hydrates in sediments are considered in terms of phase relations, nucleation, and crystallization constraints, gas solubility, pore fluid chemistry, inorganic diagenesis, and sediment organic content. Together with a depositional analysis of the area, this report is a better understanding of the thermal evolution of the locality. It should lead to an assessment of the potential for both biogenic and thermogenic hydrocarbon generation. 63 refs., 38 figs., 7 tabs.

Krason, J.; Ciesnik, M.

1986-03-01T23:59:59.000Z

399

Wettability of Petroleum Pipelines: Influence of Crude Oil and Pipeline Material in Relation to Hydrate Deposition  

Science Journals Connector (OSTI)

Wettability of Petroleum Pipelines: Influence of Crude Oil and Pipeline Material in Relation to Hydrate Deposition ... In the present work, various solid surfaces and crude oils have been used to study the effect of material and crude oil composition on the wettability of pipeline-mimicking surfaces. ... A procedure for evaluation of the plugging potential and for identification and extn. of naturally hydrate inhibiting components in crude petroleums was presented. ...

Guro Aspenes; Sylvi Hiland; Anna E. Borgund; Tanja Barth

2009-11-16T23:59:59.000Z

400

The effect of reservoir heterogeneity on gas production from hydrate accumulations in the permafrost  

SciTech Connect (OSTI)

The quantity of hydrocarbon gases trapped in natural hydrate accumulations is enormous, leading to significant interest in the evaluation of their potential as an energy source. Large volumes of gas can be readily produced at high rates for long times from methane hydrate accumulations in the permafrost by means of depressurization-induced dissociation combined with conventional technologies and horizontal or vertical well configurations. Initial studies on the possibility of natural gas production from permafrost hydrates assumed homogeneity in intrinsic reservoir properties and in the initial condition of the hydrate-bearing layers (either due to the coarseness of the model or due to simplifications in the definition of the system). These results showed great promise for gas recovery from Class 1, 2, and 3 systems in the permafrost. This work examines the consequences of inevitable heterogeneity in intrinsic properties, such as in the porosity of the hydrate-bearing formation, or heterogeneity in the initial state of hydrate saturation. Heterogeneous configurations are generated through multiple methods: (1) through defining heterogeneous layers via existing well-log data, (2) through randomized initialization of reservoir properties and initial conditions, and (3) through the use of geostatistical methods to create heterogeneous fields that extrapolate from the limited data available from cores and well-log data. These extrapolations use available information and established geophysical methods to capture a range of deposit properties and hydrate configurations. The results show that some forms of heterogeneity, such as horizontal stratification, can assist in production of hydrate-derived gas. However, more heterogeneous structures can lead to complex physical behavior within the deposit and near the wellbore that may obstruct the flow of fluids to the well, necessitating revised production strategies. The need for fine discretization is crucial in all cases to capture dynamic behavior during production.

Reagan, M. T.; Kowalsky, M B.; Moridis, G. J.; Silpngarmlert, S.

2010-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Electrical anisotropy of gas hydrate-bearing sand reservoirs in the Gulf of Mexico  

Science Journals Connector (OSTI)

We present new results and interpretations of the electrical anisotropy and reservoir architecture in gas hydrate-bearing sands using logging data collected during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II. We focus specifically on sand reservoirs in Hole Alaminos Canyon 21 A (AC21-A), Hole Green Canyon 955 H (GC955-H) and Hole Walker Ridge 313 H (WR313-H). Using a new logging-while-drilling directional resistivity tool and a one-dimensional inversion developed by Schlumberger, we resolve the resistivity of the current flowing parallel to the bedding, R? and the resistivity of the current flowing perpendicular to the bedding, R?. We find the sand reservoir in Hole AC21-A to be relatively isotropic, with R? and R? values close to 2?m. In contrast, the gas hydrate-bearing sand reservoirs in Holes GC955-H and WR313-H are highly anisotropic. In these reservoirs, R? is between 2 and 30?m, and R? is generally an order of magnitude higher. Using Schlumbergers WebMI models, we were able to replicate multiple resistivity measurements and determine the formation resistivity the gas hydrate-bearing sand reservoir in Hole WR313-H. The results showed that gas hydrate saturations within a single reservoir unit are highly variable. For example, the sand units in Hole WR313-H contain thin layers (on the order of 10100cm) with varying gas hydrate saturations between 15 and 95%. Our combined modeling results clearly indicate that the gas hydrate-bearing sand reservoirs in Holes GC955-H and WR313-H are highly anisotropic due to varying saturations of gas hydrate forming in thin layers within larger sand units.

Ann E. Cook; Barbara I. Anderson; John Rasmus; Keli Sun; Qiming Li; Timothy S. Collett; David S. Goldberg

2012-01-01T23:59:59.000Z

402

Cement Hydration Inhibition with Sucrose, Tartaric Acid, and Lignosulfonate:? Analytical and Spectroscopic Study  

Science Journals Connector (OSTI)

Tartaric acid is the most effective at retarding C3A hydration and ettringite formation, while sucrose and the lignosulfonate accelerate ettringite formation but are more effective at retarding C3S hydration. ... In particular, time to formation of ettringite [3CaOAl2O33CaSO432H2O] was investigated. ... Table 2 summarizes the effect of the different retarders on ettringite formation. ...

Maximilienne Bishop; Andrew R. Barron

2006-09-07T23:59:59.000Z

403

Purification of Natural Gases with High CO2 Content Using Gas Hydrates  

Science Journals Connector (OSTI)

Purification of Natural Gases with High CO2 Content Using Gas Hydrates ... The feed was separated using a cascade of continuously stirred tank crystallizer vessels, which can also be regarded as an ideal crystallizer column resembling a gas-hydrate-based scrubbing process. ... Pressurized gas scrubbing, pressure swing adsorption, chemical absorption, and membrane and cryogenic processes are some examples of well-established technologies for the removal of CO2 from gaseous products. ...

Nena Dabrowski; Christoph Windmeier; Lothar R. Oellrich

2009-09-25T23:59:59.000Z

404

GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS  

SciTech Connect (OSTI)

The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

James Sorensen; Jaroslav Solc; Bethany Bolles

2000-07-01T23:59:59.000Z

405

Hydrate risks and prevention solutions for a high pressure gas field offshore in South China Sea  

Science Journals Connector (OSTI)

YC13-4 gas field is located in the west of the South China Sea, where the seawater depth is around 90 m, and the average surface temperature is 26.2C, while the minimum temperature at seabed is 18.9C. Subsea wellheads are designed for gas production. In this paper, the risks of hydrate formation during drilling, well testing and gas production are analysed under different operation conditions. The results show that most hydrate problems will occur during shutdown and restart operations, and the degree of hydrate occurrence is slight to medium, which poses difficult tasks for choosing safe, reliable and economic methods to mitigate the hydrate problems. Various solutions for hydrate control in different processes are considered, including filling the wellbore with drilling/completion fluids or seawater for pressure control during shutdowns, and injection of methanol into wellbore and subsea pipeline during production. A simple and economic method using down-hole chokes to reduce gas pressure before it enters the hydrate stability zone is introduced, and the placement depth of the down-hole choke is determined. [Received: September 5, 2012; Accepted: March 6, 2013

Liang Zhang; Anyuan Huang; Wei Wang; Shaoran Ren; Shukai Jin; Dake Fang

2013-01-01T23:59:59.000Z

406

Analytical Chemistry Applied Mathematics  

E-Print Network [OSTI]

Analytical Chemistry Applied Mathematics Architectural Engineering Architecture Architecture Electricity Markets Environmental Engineering Food Process Engineering Food Safety & Technology Architecture Information Technology & Management Integrated Building Delivery Landscape Architecture Management

Heller, Barbara

407

How To Apply  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CSCEEE undergraduate students are encouraged to apply. Required Materials Current Resume Official University Transcript (with spring courses posted andor a copy of Spring...

408

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

21 - 22030 of 31,917 results. 21 - 22030 of 31,917 results. Download CX-008512: Categorical Exclusion Determination Hydrate Growth Modeling in the Laboratory CX(s) Applied: A9, B3.6 Date: 07/13/2012 Location(s): Colorado Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-008512-categorical-exclusion-determination Download CX-008513: Categorical Exclusion Determination Hydrate Growth Modeling in the Laboratory CX(s) Applied: A9, A11, B3.6 Date: 07/13/2012 Location(s): Oklahoma Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-008513-categorical-exclusion-determination Download CX-008514: Categorical Exclusion Determination Corrosion and Scale at Extreme Temperature and Pressure CX(s) Applied: A9, A11, B3.6 Date: 07/13/2012

409

Categorical Exclusion Determinations: A11 | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

October 24, 2012 October 24, 2012 CX-009416: Categorical Exclusion Determination Routine Operating and Administrative Activities (ROAA) CX(s) Applied: A8, A9, A11, B1.3, B1.23, B1.31 Date: 10/24/2012 Location(s): Missouri Offices(s): Kansas City Site Office October 18, 2012 CX-009464: Categorical Exclusion Determination Temporal Characterization of Hydrates System Dynamics beneath Seafloor Mounds: Integrating Time-Lapse CX(s) Applied: A9, A11 Date: 10/18/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory October 18, 2012 CX-009462: Categorical Exclusion Determination Temporal Characterization of Hydrates System Dynamics Beneath Seafloor Mounds: Integrating Time-Lapse CX(s) Applied: A9, A11 Date: 10/18/2012 Location(s): Mississippi Offices(s): National Energy Technology Laboratory

410

FE Categorical Exclusions | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

33: Categorical Exclusion Determination 33: Categorical Exclusion Determination Detection and Production of Methane Hydrates CX(s) Applied: A9 Date: 01/22/2010 Location(s): Austin, Texas Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000734: Categorical Exclusion Determination Detection and Production of Methane Hydrates CX(s) Applied: A9 Date: 01/22/2010 Location(s): Stillwater, Oklahoma Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000735: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Newtown Square, Pennsylvania Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000736: Categorical Exclusion Determination

411

Categorical Exclusion Determinations: B3.11 | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

August 5, 2010 August 5, 2010 CX-003297: Categorical Exclusion Determination Hydrate Research Activities that both Support and Derive from the Monitoring Station/Sea-Floor Observatory CX(s) Applied: B3.6, B3.11 Date: 08/05/2010 Location(s): Santa Barbara, California Office(s): Fossil Energy, National Energy Technology Laboratory August 5, 2010 CX-003296: Categorical Exclusion Determination Hydrate Research Activities that both Support and Derive from the Monitoring Station/Sea-Floor Observatory CX(s) Applied: B3.6, B3.11 Date: 08/05/2010 Location(s): Mississippi Office(s): Fossil Energy, National Energy Technology Laboratory July 19, 2010 CX-003042: Categorical Exclusion Determination Pacific Northwest Smart Grid Demonstration CX(s) Applied: A1, A9, A11, B1.7, B3.11, B4.4, B5.1

412

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

71 - 14180 of 28,560 results. 71 - 14180 of 28,560 results. Download CX-008512: Categorical Exclusion Determination Hydrate Growth Modeling in the Laboratory CX(s) Applied: A9, B3.6 Date: 07/13/2012 Location(s): Colorado Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-008512-categorical-exclusion-determination Download CX-008513: Categorical Exclusion Determination Hydrate Growth Modeling in the Laboratory CX(s) Applied: A9, A11, B3.6 Date: 07/13/2012 Location(s): Oklahoma Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-008513-categorical-exclusion-determination Download CX-008514: Categorical Exclusion Determination Corrosion and Scale at Extreme Temperature and Pressure CX(s) Applied: A9, A11, B3.6 Date: 07/13/2012

413

Formation of Hydrates from Single-Phase Aqueous Solutions and Implications for Oceanic Sequestration of CO2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation of Hydrates from Single-Phase Aqueous Solutions Formation of Hydrates from Single-Phase Aqueous Solutions and Implications for Oceanic Sequestration of CO 2 . G. Holder (holder@engrng.pitt.edu) 412-624-9809 L. Mokka (lakshmi.mokka@netl.doe.gov) 412-386-6019 Department of Chemical and Petroleum Engineering University of Pittsburgh Pittsburgh, PA 15261 R. Warzinski* (robert.warzinski@netl.doe.gov) 412-386-5863 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 10940 Pittsburgh, PA 15236-0940 Introduction a Gas hydrates are crystalline solids formed from mixtures of water and low molecular weight compounds, referred to as hydrate formers, that typically are gases at ambient conditions (1). Generally, hydrates are formed in the laboratory from two-phase systems by contacting a hydrate former or formers in the gas or liquid phase with liquid water and increasing the pressure until

414

Thermodynamic analysis of hydration in human serum heme-albumin  

SciTech Connect (OSTI)

Ferric human serum heme-albumin (heme-HSA) shows a peculiar nuclear magnetic relaxation dispersion (NMRD) behavior that allows to investigate structural and functional properties. Here, we report a thermodynamic analysis of NMRD profiles of heme-HSA between 20 and 60 {sup o}C to characterize its hydration. NMRD profiles, all showing two Lorentzian dispersions at 0.3 and 60 MHz, were analyzed in terms of modulation of the zero field splitting tensor for the S = {sup 5}/{sub 2} manifold. Values of correlation times for tensor fluctuation ({tau}{sub v}) and chemical exchange of water molecules ({tau}{sub M}) show the expected temperature dependence, with activation enthalpies of -1.94 and -2.46 {+-} 0.2 kJ mol{sup -1}, respectively. The cluster of water molecules located in the close proximity of the heme is progressively reduced in size by increasing the temperature, with {Delta}H = 68 {+-} 28 kJ mol{sup -1} and {Delta}S = 200 {+-} 80 J mol{sup -1} K{sup -1}. These results highlight the role of the water solvent in heme-HSA structure-function relationships.

Baroni, Simona [Invento S.r.l., 'Companies Incubator' of the University of Torino, Via Nizza 52, I-10126, Torino (Italy)] [Invento S.r.l., 'Companies Incubator' of the University of Torino, Via Nizza 52, I-10126, Torino (Italy); Pariani, Giorgio; Fanali, Gabriella [Department of Structural and Functional Biology, and Center of Neurosciences, University of Insubria, Via Alberto da Giussano 12, I-21052 Busto Arsizio (Italy)] [Department of Structural and Functional Biology, and Center of Neurosciences, University of Insubria, Via Alberto da Giussano 12, I-21052 Busto Arsizio (Italy); Longo, Dario [Department of Chemistry I.F.M. and Center of Molecular Imaging (CIM), University of Torino, Via Nizza 52, I-10126 Torino (Italy)] [Department of Chemistry I.F.M. and Center of Molecular Imaging (CIM), University of Torino, Via Nizza 52, I-10126 Torino (Italy); Ascenzi, Paolo [Department of Biology and Interdepartmental Laboratory for Electron Microscopy, Viale Guglielmo Marconi 446, University 'Roma Tre', I-00146 Roma (Italy)] [Department of Biology and Interdepartmental Laboratory for Electron Microscopy, Viale Guglielmo Marconi 446, University 'Roma Tre', I-00146 Roma (Italy); Aime, Silvio [Department of Chemistry I.F.M. and Center of Molecular Imaging (CIM), University of Torino, Via Nizza 52, I-10126 Torino (Italy)] [Department of Chemistry I.F.M. and Center of Molecular Imaging (CIM), University of Torino, Via Nizza 52, I-10126 Torino (Italy); Fasano, Mauro, E-mail: mauro.fasano@uninsubria.it [Department of Structural and Functional Biology, and Center of Neurosciences, University of Insubria, Via Alberto da Giussano 12, I-21052 Busto Arsizio (Italy)] [Department of Structural and Functional Biology, and Center of Neurosciences, University of Insubria, Via Alberto da Giussano 12, I-21052 Busto Arsizio (Italy)

2009-07-31T23:59:59.000Z

415

Dynamics of Confined Water Molecules in Aqueous Salt Hydrates  

SciTech Connect (OSTI)

The unusual properties of water are largely dictated by the dynamics of the H bond network. A single water molecule has more H bonding sites than atoms, hence new experimental and theoretical investigations about this peculiar liquid have not ceased to appear. Confinement of water to nanodroplets or small molecular clusters drastically changes many of the liquids properties. Such confined water plays a major role in the solvation of macro molecules such as proteins and can even be essential to their properties. Despite the vast results available on bulk and confined water, discussions about the correlation between spectral and structural properties continue to this day. The fast relaxation of the OH stretching vibration in bulk water, and the variance of sample geometries in the experiments on confined water obfuscate definite interpretation of the spectroscopic results in terms of structural parameters. We present first time-resolved investigations on a new model system that is ideally suited to overcome many of the problems faced in spectroscopical investigation of the H bond network of water. Aqueous hydrates of inorganic salts provide water molecules in a crystal grid, that enables unambiguous correlations of spectroscopic and structural features. Furthermore, the confined water clusters are well isolated from each other in the crystal matrix, so different degrees of confinement can be achieved by selection of the appropriate salt.

Werhahn, Jasper C.; Pandelov, S.; Yoo, Soohaeng; Xantheas, Sotiris S.; Iglev, H.

2011-04-01T23:59:59.000Z

416

X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well  

E-Print Network [OSTI]

stability zone, hydrate will first form at the methane-water interface, either as a film on a methane gas bubble

Kneafsey, T.J.

2012-01-01T23:59:59.000Z

417

Applied Energy Programs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Applied Energy Programs Applied Energy Programs Applied Energy Programs Los Alamos is using its world-class scientific capabilities to enhance national energy security by developing energy sources with limited environmental impact and by improving the efficiency and reliability of the energy infrastructure. CONTACT US Acting Program Director Melissa Fox (505) 663-5538 Email Applied Energy Program Office serves as the hub connecting the Laboratory's scientific and technical resources to DOE sponsors, DoD programs, and to industry. The Applied Energy Program Office manages Los Alamos National Laboratory programs funded by the Department of Energy's (DOE's) Offices of Energy Efficiency/Renewable Energy, Electricity Delivery and Energy Reliability, and Fossil Energy. With energy use increasing across the nation and the

418

CX-009278: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Measurement and Interpretation of Seismic Velocities and Attenuation in Hydrate-Bearing Sediments CX(s) Applied: A9, B2.2, B3.6 Date: 09/07/2012 Location(s): Colorado Offices(s): National Energy Technology Laboratory

419

CX-010977: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Thermal-Hydrological-Chemical-Mechanical (THCM) Coupled Model for Hydrate-Bearing Sediments: Data Analysis and Design of New Field Experiments CX(s) Applied: A9 Date: 09/16/2013 Location(s): Georgia Offices(s): National Energy Technology Laboratory

420

CX-010976: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Thermal-Hydrological-Chemical-Mechanical (THCM) Coupled Model for Hydrate-Bearing Sediments: Data Analysis and Design of New Field Experiments CX(s) Applied: A9 Date: 09/16/2013 Location(s): Texas Offices(s): National Energy Technology Laboratory

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

I/I ratios and halogen concentrations in pore waters of the Hydrate Ridge: Relevance for the origin of gas hydrates in ODP Leg 204  

E-Print Network [OSTI]

in fluids associated with hydrocarbons, such as oil field brines (Moran et al., 1995) or coal-bed methane association of iodine with methane allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly

Fehn, Udo

422

An effective medium inversion algorithm for gas hydrate quantification and its application to laboratory and borehole measurements of gas hydrate-bearing sediments  

Science Journals Connector (OSTI)

......reconstituted natural samples showed a large increase in velocities for...in Proceedings of the Ocean Drilling Program, Scientific Results...R.J., Suess E., Ocean Drilling Program, College Station...application to laboratory and borehole measurements of gas hydrate-bearing......

Shyam Chand; Tim A. Minshull; Jeff A. Priest; Angus I. Best; Christopher R. I. Clayton; William F. Waite

2006-08-01T23:59:59.000Z

423

Role of Ettringite in the Reuse of Hydrated Fly Ash from Fluidized-Bed Combustion as a Sulfur Sorbent:? A Hydration Study  

Science Journals Connector (OSTI)

Waste from fluidized-bed combustion (FBC) has a low potential for reuse. One possibility for its recycling lies in a hydration process aimed at reactivating the SO2 sorption ability of the unconverted lime. The formation of ettringite, as well as calcium ...

Graziella Bernardo; Antonio Telesca; Gian Lorenzo Valenti; Fabio Montagnaro

2004-06-15T23:59:59.000Z

424

Comparison of the Properties of Xenon, Methane, and Carbon Dioxide Hydrates from Equilibrium and Nonequilibrium Molecular Dynamics Simulations  

Science Journals Connector (OSTI)

Comparison of the Properties of Xenon, Methane, and Carbon Dioxide Hydrates from Equilibrium and Nonequilibrium Molecular Dynamics Simulations ... The VACFs of all three guests in the small cages oscillate between positive and negative values with the oscillation being damped out with increasing time. ... The oscillations are damped much more strongly for CO2 hydrate than for the Xe or methane hydrates, indicating that the coupling between the rattling motions of the encaged guest molecules and the vibrational motions of the host lattice is strongest for CO2 hydrate. ...

H. Jiang; K. D. Jordan

2009-11-11T23:59:59.000Z

425

Methane Hydrates: Major Energy Source for the Future or Wishful Thinking?  

SciTech Connect (OSTI)

Methane hydrates are methane bearing, ice-like materials that occur in abundance in permafrost areas such as on the North Slope of Alaska and Canada and as well as in offshore continental margin environments throughout the world including the Gulf of Mexico and the East and West Coasts of the United States. Methane hydrate accumulations in the United States are currently estimated to be about 200,000 Tcf, which is enormous when compared to the conventional recoverable resource estimate of 2300 Tcf. On a worldwide basis, the estimate is 700,000 Tcf or about two times the total carbon in coal, oil and conventional gas in the world. The enormous size of this resource, if producible to any degree, has significant implications for U.S. and worldwide clean energy supplies and global environmental issues. Historically the petroleum industry's interests in methane hydrates have primarily been related to safety issues such as wellbore stability while drilling, seafloor stability, platform subsidence, and pipeline plugging. Many questions remain to be answered to determine if any of this potential energy resource is technically and economically viable to produce. Major technical hurdles include: 1) methods to find, characterize, and evaluate the resource; 2) technology to safely and economically produce natural gas from methane hydrate deposits; and 3) safety and seafloor stability issues related to drilling through gas hydrate accumulations to produce conventional oil and gas. The petroleum engineering profession currently deals with gas hydrates in drilling and production operations and will be key to solving the technical and economic problems that must be overcome for methane hydrates to be part of the future energy mix in the world.

Thomas, Charles Phillip

2001-09-01T23:59:59.000Z

426

Modeling of Oceanic Gas Hydrate Instability and Methane Release in Response to Climate Change  

SciTech Connect (OSTI)

Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating global climate, implicating global oceanic deposits of methane gas hydrate as the main culprit in instances of rapid climate change that have occurred in the past. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those predicted under future climate change scenarios, is poorly understood. To determine the fate of the carbon stored in these hydrates, we performed simulations of oceanic gas hydrate accumulations subjected to temperature changes at the seafloor and assessed the potential for methane release into the ocean. Our modeling analysis considered the properties of benthic sediments, the saturation and distribution of the hydrates, the ocean depth, the initial seafloor temperature, and for the first time, estimated the effect of benthic biogeochemical activity. The results show that shallow deposits--such as those found in arctic regions or in the Gulf of Mexico--can undergo rapid dissociation and produce significant methane fluxes of 2 to 13 mol/yr/m{sup 2} over a period of decades, and release up to 1,100 mol of methane per m{sup 2} of seafloor in a century. These fluxes may exceed the ability of the seafloor environment (via anaerobic oxidation of methane) to consume the released methane or sequester the carbon. These results will provide a source term to regional or global climate models in order to assess the coupling of gas hydrate deposits to changes in the global climate.

Reagan, Matthew; Reagan, Matthew T.; Moridis, George J.

2008-04-15T23:59:59.000Z

427

AEROSPACE SCIENCES Applied aerodynamics  

E-Print Network [OSTI]

AEROSPACE SCIENCES Applied aerodynamics This year saw significant progress in industry, research labs, and academia in the development of flow-control concepts, novel configuration aerodynamic concepts, and aerodynamic im- provement technologies for enhancing the fuel efficiency and performance

Xu, Kun

428

Applied large eddy simulation  

Science Journals Connector (OSTI)

...2971-2983. doi:10.1098/rsta.2008.0303 . Audio Supplement Audio Supplement Audio files from the Applied large eddy simulation...fidelity. | Whittle Laboratory, Department of Engineering, University of Cambridge, Cambridge CB2 1PZ...

2009-01-01T23:59:59.000Z

429

The effect of methane hydrate morphology and water saturation on seismic wave attenuation in sand under shallow sub-seafloor conditions  

Science Journals Connector (OSTI)

Abstract A better understanding of seismic wave attenuation in hydrate-bearing sediments is needed for the improved geophysical quantification of seafloor methane hydrates, important for climate change, geohazard and economic resource assessment. Hence, we conducted a series of small strain (hydrate-bearing sands under excess-water seafloor conditions. The results show a complex dependence of P- and S-wave attenuation on hydrate saturation and morphology. P- and S-wave attenuation in excess-water hydrate-bearing sand is much higher than in excess-gas hydrate-bearing sand and increases with hydrate saturation between 0 and 0.44 (the experimental range). Theoretical modelling suggests that load-bearing hydrate is an important cause of heightened attenuation for both P- and S-waves in gas and water saturated sands, while pore-filling hydrate also contributes significantly to P-wave attenuation in water saturated sands. A squirt flow attenuation mechanism, related to microporous hydrate and low aspect ratio pores at the interface between sand grains and hydrate, is thought to be responsible for the heightened levels of attenuation in hydrate-bearing sands at low hydrate saturations (<0.44).

Angus I. Best; Jeffrey A. Priest; Christopher R.I. Clayton; Emily V.L. Rees

2013-01-01T23:59:59.000Z

430

Applied Science/Techniques  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Applied Science/Techniques Applied Science/Techniques Applied Science/Techniques Print The ALS is an excellent incubator of new scientific techniques and instrumentation. Many of the technical advances that make the ALS a world-class soft x-ray facility are developed at the ALS itself. The optical components in use at the ALS-mirrors and lenses optimized for x-ray wavelengths-require incredibly high-precision surfaces and patterns (often formed through extreme ultraviolet lithography at the ALS) and must undergo rigorous calibration and testing provided by beamlines and equipment from the ALS's Optical Metrology Lab and Berkeley Lab's Center for X-Ray Optics. New and/or continuously improved experimental techniques are also a crucial element of a thriving scientific facility. At the ALS, examples of such "technique" highlights include developments in lensless imaging, soft x-ray tomography, high-throughput protein analysis, and high-power coherent terahertz radiation.

431

Final Technical Report on: Controls on Gas Hydrate Formation and Dissociation,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Final Technical Report on: Controls on Gas Hydrate Formation and Dissociation, Final Technical Report on: Controls on Gas Hydrate Formation and Dissociation, Gulf of Mexico: In Situ Field Study with Laboratory Characterizations of Exposed and Buried Gas Hydrates DOE Award Number: DE-FC26-02NT41328 Dates: 3/4/02 - 3/3/06 Prepared by: Miriam Kastner, Scripps Institution of Oceanography, La Jolla, California 92093 Ian MacDonald, Texas A&M University, Corpus Christi, Texas 78412 Prepared for US Department of Energy National Energy Technology Laboratory June 2006 2 Disclaimer "This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any

432

Observation of dynamic crossover and dynamic heterogeneity in hydration water confined in aged cement paste  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

502101 502101 (6pp) doi:10.1088/0953-8984/20/50/502101 FAST TRACK COMMUNICATION Observation of dynamic crossover and dynamic heterogeneity in hydration water confined in aged cement paste Y Zhang 1 , M Lagi 1,2 , F Ridi 2 , E Fratini 2 , P Baglioni 2 , E Mamontov 3 and S H Chen 1,4 1 Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA 2 Department of Chemistry and CSGI, University of Florence, Sesto Fiorentino, Florence, I-50019, Italy 3 Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA E-mail: sowhsin@mit.edu Received 24 September 2008, in final form 23 October 2008 Published 12 November 2008 Online at stacks.iop.org/JPhysCM/20/502101 Abstract High resolution quasi-elastic neutron scattering is used to investigate the slow dynamics of hydration water confined in calcium silicate hydrate

433

GAS PRODUCTION POTENTIAL OF DISPERSE LOW-SATURATION HYDRATE ACCUMULATIONS IN  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

61446 61446 GAS PRODUCTION POTENTIAL OF DISPERSE LOW-SATURATION HYDRATE ACCUMULATIONS IN OCEANIC SEDIMENTS George J. Moridis Earth Sciences Division Lawrence Berkeley National Laboratory Berkeley, CA 94720 E. Dendy Sloan Center for Hydrate Research and Chemical Engineering Department Colorado School of Mines Golden, CO 80401 August 2006 This work was partly supported by the Assistant Secretary for Fossil Energy, Office of Natural Gas and Petroleum Technology, through the National Energy Technology Laboratory, under the U.S. Department of Energy, Contract No. DE-AC03-76SF00098. Gas Production Potential of Disperse Low-Saturation Hydrate Accumulations in Oceanic Sediments George J. Moridis 1 and E. Dendy Sloan 2 1 Earth Sciences Division, Lawrence Berkeley National Laboratory, MS 90-1166

434

NETL: Methane Hydrates - DOE/NETL Projects - Mapping Permafrost and Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mapping Permafrost and Gas Hydrate using Marine Controlled Source Electromagnetic Methods (CSEM) Last Reviewed 12/18/2013 Mapping Permafrost and Gas Hydrate using Marine Controlled Source Electromagnetic Methods (CSEM) Last Reviewed 12/18/2013 DE-FE0010144 Goal The objective of this project is to develop and test a towed electromagnetic source and receiver system suitable for deployment from small coastal vessels to map near-surface electrical structure in shallow water. The system will be used to collect permafrost data in the shallow water of the U.S. Beaufort Inner Shelf at locations coincident with seismic lines collected by the U.S. Geological Survey (USGS). The electromagnetic data will be used to identify the geometry, extent, and physical properties of permafrost and any associated gas hydrate in order to provide a baseline for future studies of the effects of any climate-driven dissociation of

435

Methane Hydrate Dissociation by Depressurization in a Mount Elbert Sandstone Sample: Experimental Observations and Numerical Simulations  

SciTech Connect (OSTI)

A preserved sample of hydrate-bearing sandstone from the Mount Elbert Test Well was dissociated by depressurization while monitoring the internal temperature of the sample in two locations and the density changes at high spatial resolution using x-ray CT scanning. The sample contained two distinct regions having different porosity and grain size distributions. The hydrate dissociation occurred initially throughout the sample as a result of depressing the pressure below the stability pressure. This initial stage reduced the temperature to the equilibrium point, which was maintained above the ice point. After that, dissociation occurred from the outside in as a result of heat transfer from the controlled temperature bath surrounding the pressure vessel. Numerical modeling of the test using TOUGH+HYDRATE yielded a gas production curve that closely matches the experimentally measured curve.

Kneafsey, T.; Moridis, G.J.

2011-01-15T23:59:59.000Z

436

Information Science, Computing, Applied Math  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Capabilities ISC Applied Math science-innovationassetsimagesicon-science.jpg Information Science, Computing, Applied Math National security depends on science and...

437

X-ray computed-tomography observations of water flow through anisotropic methane hydrate-bearing sand  

SciTech Connect (OSTI)

We used X-ray computed tomography (CT) to image and quantify the effect of a heterogeneous sand grain-size distribution on the formation and dissociation of methane hydrate, as well as the effect on water flow through the heterogeneous hydrate-bearing sand. A 28 cm long sand column was packed with several segments having vertical and horizontal layers with sands of different grain-size distributions. During the hydrate formation, water redistribution occurred. Observations of water flow through the hydrate-bearing sands showed that water was imbibed more readily into the fine sand, and that higher hydrate saturation increased water imbibition in the coarse sand due to increased capillary strength. Hydrate dissociation induced by depressurization resulted in different flow patterns with the different grain sizes and hydrate saturations, but the relationships between dissociation rates and the grain sizes could not be identified using the CT images. The formation, presence, and dissociation of hydrate in the pore space dramatically impact water saturation and flow in the system.

Seol, Yongkoo; Kneafsey, Timothy J.

2009-06-01T23:59:59.000Z

438

Carbon dioxide, argon, nitrogen and methane clathrate hydrates:1 thermodynamic modelling, investigation of their stability in Martian2  

E-Print Network [OSTI]

1 Carbon dioxide, argon, nitrogen and methane clathrate hydrates:1 thermodynamic modelling-4Dec2012 #12;3 Keywords: Mars, clathrate hydrate, nitrogen, carbon dioxide, argon, methane, equilibrium and allows to simulating a Martian gas, CO2 dominated (95.3%) plus nitrogen6 (2.7%) and argon (2

Paris-Sud XI, Université de

439

Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential  

E-Print Network [OSTI]

cost-effective) techniques to remotely detect hydrate deposits, and to monitor their changes in the course of gas production.production of gas from hydrates occurring in the Gulf of Mexico because, despite of the substantially increased complexity and cost

Moridis, George J.

2008-01-01T23:59:59.000Z

440

Scientific results of the Second Gas Hydrate Drilling Expedition in the Ulleung Basin (UBGH2)  

Science Journals Connector (OSTI)

Abstract As a part of Korean National Gas Hydrate Program, the Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2) was conducted from 9 July to 30 September, 2010 in the Ulleung Basin, East Sea, offshore Korea using the D/V Fugro Synergy. The UBGH2 was performed to understand the distribution of gas hydrates as required for a resource assessment and to find potential candidate sites suitable for a future offshore production test, especially targeting gas hydrate-bearing sand bodies in the basin. The UBGH2 sites were distributed across most of the basin and were selected to target mainly sand-rich turbidite deposits. The 84-day long expedition consisted of two phases. The first phase included logging-while-drilling/measurements-while-drilling (LWD/MWD) operations at 13 sites. During the second phase, sediment cores were collected from 18 holes at 10 of the 13 LWD/MWD sites. Wireline logging (WL) and vertical seismic profile (VSP) data were also acquired after coring operations at two of these 10 sites. In addition, seafloor visual observation, methane sensing, as well as push-coring and sampling using a Remotely Operated Vehicle (ROV) were conducted during both phases of the expedition. Recovered gas hydrates occurred either as pore-filling medium associated with discrete turbidite sand layers, or as fracture-filling veins and nodules in muddy sediments. Gas analyses indicated that the methane within the sampled gas hydrates is primarily of biogenic origin. This paper provides a summary of the operational and scientific results of the UBGH2 expedition as described in 24 papers that make up this special issue of the Journal of Marine and Petroleum Geology.

Byong-Jae Ryu; Timothy S. Collett; Michael Riedel; Gil Young Kim; Jong-Hwa Chun; Jang-Jun Bahk; Joo Yong Lee; Ji-Hoon Kim; Dong-Geun Yoo

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "hydrate cxs applied" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Geomechanical response of permafrost-associated hydrate deposits to depressurization-induced gas production  

SciTech Connect (OSTI)

In this simulation study, we analyzed the geomechanical response during depressurization production from two known hydrate-bearing permafrost deposits: the Mallik (Northwest Territories, Canada) deposit and Mount Elbert (Alaska, USA) deposit. Gas was produced from these deposits at constant pressure using horizontal wells placed at the top of a hydrate layer (HL), located at a depth of about 900 m at the Mallik and 600 m at the Mount Elbert. The simulation results show that general thermodynamic and geomechanical responses are similar for the two sites, but with substantially higher production and more intensive geomechanical responses at the deeper Mallik deposit. The depressurization-induced dissociation begins at the well bore and then spreads laterally, mainly along the top of the HL. The depressurization results in an increased shear stress within the body of the receding hydrate and causes a vertical compaction of the reservoir. However, its effects are partially mitigated by the relatively stiff permafrost overburden, and compaction of the HL is limited to less than 0.4%. The increased shear stress may lead to shear failure in the hydrate-free zone bounded by the HL overburden and the downward-receding upper dissociation interface. This zone undergoes complete hydrate dissociation, and the cohesive strength of the sediment is low. We determined that the likelihood of shear failure depends on the initial stress state as well as on the geomechanical properties of the reservoir. The Poisson's ratio of the hydrate-bearing formation is a particularly important parameter that determines whether the evolution of the reservoir stresses will increase or decrease the likelihood of shear failure.

Rutqvist, J.; Moridis, G.J.; Grover, T.; Collett, T.

2009-02-01T23:59:59.000Z

442

Synthesis and single crystal structure refinement of the one-layer hydrate of sodium brittle mica  

SciTech Connect (OSTI)

A sodium brittle mica with the ideal composition [Na{sub 4}]{sup inter}[Mg{sub 6}]{sup oct}[Si{sub 4}Al{sub 4}]{sup tet}O{sub 20}F{sub 4} was synthesized via melt synthesis in a gas tight crucible. This mica is unusual inasmuch as the known mica structure holds only room for two interlayer cations per unit cell and inasmuch as it readily hydrates despite the high layer charge while ordinary micas and brittle micas are non-swelling. The crystal structure of one-layer hydrate sodium brittle mica was determined and refined from single crystal X-ray data. Interlayer cations reside at the center of the distorted hexagonal cavities and are coordinated by the three inner basal oxygen atoms. The coordination of the interlayer cation is completed by three interlayer water molecules residing at the center of the interlayer region. The relative position of adjacent 2:1-layers thus is fixed by these octahedrally coordinated interlayer cations. Pseudo-symmetry leads to extensive twinning. In total five twin operations generate the same environment for the interlayer species and are energetically degenerate. - Graphical abstract: The sodium brittle mica has been successfully synthesized by melt synthesis and the crystal structure of the one-layer hydrate of sodium brittle mica was determined from single crystal X-ray diffraction data. Highlights: Black-Right-Pointing-Pointer Melt synthesis yielded coarse grained sodium brittle mica which showed little disorder. Black-Right-Pointing-Pointer Sodium brittle mica hydrated completely to the state of one-layer hydrate. Black-Right-Pointing-Pointer Structure of one-layer hydrate of sodium brittle mica could therefore be determined and refined. Black-Right-Pointing-Pointer Arrangement of upper and lower tetrahedral sheet encompassing interlayer cation were clarified.

Kalo, Hussein; Milius, Wolfgang [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany)] [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany); Braeu, Michael [BASF Construction Chemicals GmbH, 83308 Trostberg (Germany)] [BASF Construction Chemicals GmbH, 83308 Trostberg (Germany); Breu, Josef, E-mail: Josef.Breu@uni-bayreuth.de [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany)] [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany)

2013-02-15T23:59:59.000Z

443

Freezing processes. Hydrate processes. Liquid-liquid extraction  

Science Journals Connector (OSTI)

The ice which separates from brine is almost pure. A salt concentration builds up at the interface of the brine and the ice. In freezing processes, as applied in desalting, many small ice crystals are formed w...

Anthony A. Delyannis; Eurydike A. Delyannis

1974-01-01T23:59:59.000Z

444

Coupled flow and geomechanical analysis for gas production in the Prudhoe Bay Unit L-106 well Unit C gas hydrate deposit in Alaska  

E-Print Network [OSTI]

Hydrate deposits that are desirable gas production targets almost invari- ably involve coarse, unlithified, unconsolidated media (such as sands

Kim, J.

2014-01-01T23:59:59.000Z

445

Soft X-Ray Diffraction Microscopy of a Frozen Hydrated Yeast Cell  

SciTech Connect (OSTI)

We report the first image of an intact, frozen hydrated eukaryotic cell using x-ray diffraction microscopy, or coherent x-ray diffraction imaging. By plunge freezing the specimen in liquid ethane and maintaining it below -170 deg. C, artifacts due to dehydration, ice crystallization, and radiation damage are greatly reduced. In this example, coherent diffraction data using 520 eV x rays were recorded and reconstructed to reveal a budding yeast cell at a resolution better than 25 nm. This demonstration represents an important step towards high resolution imaging of cells in their natural, hydrated state, without limitations imposed by x-ray optics.

Huang Xiaojing; Nelson, Johanna; Lima, Enju; Miao, Huijie; Steinbrener, Jan; Stewart, Andrew; Turner, Joshua J.; Jacobsen, Chris [Department of Physics and Astronomy, Stony Brook University, Stony Brook, New York 11794-3800 (United States); Kirz, Janos [Department of Physics and Astronomy, Stony Brook University, Stony Brook, New York 11794-3800 (United States); Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Marchesini, Stefano; Shapiro, David [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Neiman, Aaron M. [Department of Biochemistry and Cell Biology, Stony Brook University, Stony Brook, New York 11794-5215 (United States)

2009-11-06T23:59:59.000Z

446

SUSTAINABILITY WHO CAN APPLY  

E-Print Network [OSTI]

FUNDED BY CALL FOR SUSTAINABILITY RESEARCH STUDENT WHO CAN APPLY Undergraduate and graduate Participate in the Global Change & Sustainability Center's Research Symposium; attend workshops with faculty or publish in the U's student-run sustainability publication to be released in May 2014. Are you conducting

447

Fundamentals of Natural Gas and Species Flows from Hydrate Dissociation - Applications to Safety and Sea Floor Instability  

SciTech Connect (OSTI)

Semi-analytical computational models for natural gas flow in hydrate reservoirs were developed and the effects of variations in porosity and permeability on pressure and temperature profiles and the movement of a dissociation front were studied. Experimental data for variations of gas pressure and temperature during propane hydrate formation and dissociation for crushed ice and mixture of crushed ice and glass beads under laboratory environment were obtained. A thermodynamically consistent model for multiphase liquid-gas flows trough porous media was developed. Numerical models for hydrate dissociation process in one dimensional and axisymmetric reservoir were performed. The computational model solved the general governing equations without the need for linearization. A detail module for multidimensional analysis of hydrate dissociation which make use of the FLUENT code was developed. The new model accounts for gas and liquid water flow and uses the Kim-Boshnoi model for hydrate dissociation.

Goodarz Ahmadi

2006-09-30T23:59:59.000Z

448

Geological evolution and analysis of confirmed or suspected gas hydrate localities: Volume 9, Formation and stability of gas hydrates of the Middle America Trench  

SciTech Connect (OSTI)

This report presents a geological description of the Pacific margin of Mexico and Central America, including regional and local structural settings, geomorphology, geological history, stratigraphy, and physical properties. It provides the necessary regional and geological background for more in-depth research of the area. Detailed discussion of bottom simulating acoustic reflectors, sediment acoustic properties, and distribution of hydrates within the sediments are also included in this report. The formation and stabilization of gas hydrates in sediments are considered in terms of phase relations, nucleation, and crystallization constraints, gas solubility, pore fluid chemistry, inorganic diagenesis, and sediment organic content. Together with a depositional analysis of the area, this report is a better understanding of the thermal evolution of the locality. It should lead to an assessment of the potential for both biogenic and thermogenic hydrocarbon generation. 150 refs., 84 figs., 17 tabs.

Finley, P.; Krason, J.

1986-12-01T23:59:59.000Z

449

Examination of core samples from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Effects of retrieval and preservation  

E-Print Network [OSTI]

future gas hydrate core handling and preservation in sand-gas-hydrate-bearing zones, in which the sediments (particularly the sands)sand deposits are primarily being investigated in the Mount Elbert well, much of the worlds natural gas hydrate

Collett, T.J. Kneafsey, T.J., H. Liu, W. Winters, R. Boswell, R. Hunter, and T.S.

2012-01-01T23:59:59.000Z

450

Analysis of core samples from the BPXA-DOE-USGS Mount Elbert gas hydrate stratigraphic test well: Insights into core disturbance and handling  

E-Print Network [OSTI]

future gas hydrate core handling and preservation in sand-gas-hydrate-bearing zones, in which the sediments (particularly the sands)sand deposits are primarily being investigated in the Mount Elbert well, much of the worlds natural gas hydrate

Kneafsey, Timothy J.

2010-01-01T23:59:59.000Z

451

Applied Science/Techniques  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Applied Science/Techniques Print Applied Science/Techniques Print The ALS is an excellent incubator of new scientific techniques and instrumentation. Many of the technical advances that make the ALS a world-class soft x-ray facility are developed at the ALS itself. The optical components in use at the ALS-mirrors and lenses optimized for x-ray wavelengths-require incredibly high-precision surfaces and patterns (often formed through extreme ultraviolet lithography at the ALS) and must undergo rigorous calibration and testing provided by beamlines and equipment from the ALS's Optical Metrology Lab and Berkeley Lab's Center for X-Ray Optics. New and/or continuously improved experimental techniques are also a crucial element of a thriving scientific facility. At the ALS, examples of such "technique" highlights include developments in lensless imaging, soft x-ray tomography, high-throughput protein analysis, and high-power coherent terahertz radiation.

452

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

51 - 4360 of 9,640 results. 51 - 4360 of 9,640 results. Download CX-009283: Categorical Exclusion Determination Mapping Permafrost and Gas Hydrate using Marine CSEM Methods CX(s) Applied: B3.1 Date: 09/07/2012 Location(s): Alaska Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-009283-categorical-exclusion-determination Download CX-009284: Categorical Exclusion Determination Mapping Permafrost and Gas Hydrate using Marine CSEM Methods CX(s) Applied: B3.6 Date: 09/07/2012 Location(s): California Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-009284-categorical-exclusion-determination Download CX-009285: Categorical Exclusion Determination Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering...

453

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

71 - 21480 of 31,917 results. 71 - 21480 of 31,917 results. Download CX-009283: Categorical Exclusion Determination Mapping Permafrost and Gas Hydrate using Marine CSEM Methods CX(s) Applied: B3.1 Date: 09/07/2012 Location(s): Alaska Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-009283-categorical-exclusion-determination Download CX-009284: Categorical Exclusion Determination Mapping Permafrost and Gas Hydrate using Marine CSEM Methods CX(s) Applied: B3.6 Date: 09/07/2012 Location(s): California Offices(s): National Energy Technology Laboratory http://energy.gov/nepa/downloads/cx-009284-categorical-exclusion-determination Download CX-009285: Categorical Exclusion Determination Hydrate-Bearing Clayey Sediments: Morphology, Physical Properties, Production and Engineering...

454

NETL: National Methane Hydrates R&D Program- 2009 GOM JIP Expedition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Green Canyon Block 955 Green Canyon Block 955 The gas hydrates JIP site selection team identified numerous potential targets in Green Canyon block 955. Three of these sites were drilled in Leg II. The wells are located in over 6,500 ft of water near the foot of the Sigsbee Escarpment. The locations are near a major embayment into the Escarpment (“Green Canyon”) which has served as a persistent focal point for sediment delivery into the deep Gulf of Mexico. Topographic map of the seafloor in the Green Canyon area. Topographic map of the seafloor in the Green Canyon area. Block 955 lies just seaward of the Sigsbee Escarpment in ~6,500 feet of water Green Canyon block 995 includes a prominent channel/levee complex that has transported and deposited large volumes of sandy sediment from the canyon to the deep Gulf of Mexico abyssal plain. The southwest corner of the block includes a recently developed structural high caused by deeper mobilization of salt. The crest of the structural high is cut by complex network of faults that can provide pathways for migrating fluids and gases. Geophysical data reviewed during assessment of the site revealed a complex array of geophysical responses near the inferred base of gas hydrate stability. Some of these responses are suggestive of free gas and some indicative of gas hydrate, but all are limited to depths that are near or below the inferred base of gas hydrate stability.

455

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts  

Science Journals Connector (OSTI)

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts ... Catalytic Reactions on the Open-Edge Sites of Nitrogen-Doped Carbon Nanotubes as Cathode Catalyst for Hydrogen Fuel Cells ... Despite significant progress made the past decade on reducing the platinum catalyst loading in the PEMFC electrodes, further ... ...

Yao Sha; Ted H. Yu; Boris V. Merinov; Pezhman Shirvanian; William A. Goddard; III

2011-02-24T23:59:59.000Z

456

Kinetics of Conversion of Air Bubbles to Air Hydrate Crystals in Antarctic Ice  

Science Journals Connector (OSTI)

...hydrate crystals (10, 11). For Dome C, Dye 3, and Camp Century cores, Shoji and Langway (12, 13) reported only...Johnsen, Nature 320, 250 (1986). 4. For Byrd and Camp Century, see W. F. Budd and N. W. Young, in The Climatic...

P. B. Price

1995-03-24T23:59:59.000Z

457

Fiber Optic Sensing Technology for Detecting Gas Hydrate Formation and Decomposition  

SciTech Connect (OSTI)

A fiber optic-based distributed sensing system (DSS) has been integrated with a large volume (72 L) pressure vessel providing high spatial resolution, time resolved, 3-D measurement of hybrid temperature-strain (TS) values within experimental sediment gas hydrate systems. Areas of gas hydrate formation (exothermic) and decomposition (endothermic) can be characterized through this proxy by time series analysis of discrete data points collected along the length of optical fibers placed within a sediment system. Data is visualized as a 'movie' of TS values along the length of each fiber over time. Experiments conducted in the Seafloor Processing Simulator (SPS) at Oak Ridge National Laboratory show clear indications of hydrate formation and dissociation events at expected P-T conditions given the thermodynamics of the CH4-H2O system. The high spatial resolution achieved with fiber optic technology makes the DSS a useful tool for visualizing time resolved formation and dissociation of gas hydrates in large-scale sediment experiments.

Rawn, Claudia J [ORNL; Leeman, John R [University of Oklahoma, Norman; Ulrich, Shannon M [ORNL; Alford, Jonathan E [ORNL; Phelps, Tommy Joe [ORNL; Madden, Megan Elwood [University of Oklahoma, Norman

2011-01-01T23:59:59.000Z

458

Methane Hydrate and Free Gas on the Blake Ridge from Vertical Seismic Profiling  

Science Journals Connector (OSTI)

...subtle differences in permeability between lithologically...hydrate filling 2% of porosity at Site 994 and...estimate of 1% of porosity, on average, occupied...estimate of 5 to 7% of porosity (33, 34...UNCONSOLIDATED POROUS SAND RESERVOIRS, GEOPHYSICS 42...SEISMIC-WAVES IN POROUS ROCKS, GEOPHYSICS...

W. Steven Holbrook; Hartley Hoskins; Warren T. Wood; Ralph A. Stephen; Daniel Lizarralde

1996-09-27T23:59:59.000Z

459

Feasibility of monitoring gas hydrate production with time-lapse VSP  

SciTech Connect (OSTI)

In this work we begin to examine the feasibility of using time-lapse seismic methods-specifically the vertical seismic profiling (VSP) method-for monitoring changes in hydrate accumulations that are predicted to occur during production of natural gas.

Kowalsky, M.B.; Nakagawa, S.; Moridis, G.J.

2009-11-01T23:59:59.000Z

460

Neutron scattering evidence of a boson peak in protein hydration water Alessandro Paciaroni,1  

E-Print Network [OSTI]

Neutron scattering evidence of a boson peak in protein hydration water Alessandro Paciaroni,1 Anna Viterbo, Italy Received 24 February 1999 Measurement of the low temperature neutron excess of scattering, has been detected by neutron scattering and Raman spectros- copy in a large variety of glassy systems

Tuscia, Università Degli Studi Della

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461

Intrinsically Disordered Regions May Lower the Hydration Free Energy in Proteins: A Case Study of Nudix  

E-Print Network [OSTI]

Intrinsically Disordered Regions May Lower the Hydration Free Energy in Proteins: A Case Study-resistant bacterium D. radiodurans features a group of proteins that contain significant intrinsically disordered in proteins, and propose a novel function for them: intrinsically disordered regions increase the ``surface

Paris-Sud XI, Université de

462

CO2-SO2 clathrate hydrate formation on early Mars1 Eric Chassefirea,b  

E-Print Network [OSTI]

hal-00804822,version1-26Mar2013 #12;3 1. Introduction53 54 Sulfur dioxide (SO2) has been proposed1 CO2-SO2 clathrate hydrate formation on early Mars1 2 Eric Chassefièrea,b , Emmanuel Dartoisc hal-00804822,version1-26Mar2013 Author manuscript, published in "Icarus 223, 2 (2013) 878-891" DOI

Boyer, Edmond

463

Sequestering carbon dioxide into complex structures of naturally occurring gas hydrates  

Science Journals Connector (OSTI)

...deposited worldwide as a new energy source. For recovering...found that CO 2 hydrates reform at both the surface and...sites such as the Gulf of Mexico outside the Caspian Sea (17, 18...Ratcliffe C. I. ( 1988 ) Energy Fuels 12 : 197 200 . 15 Seo Y...Commerce, Industry, and Energy of Korea, also partially...

Youngjune Park; Do-Youn Kim; Jong-Won Lee; Dae-Gee Huh; Keun-Pil Park; Jaehyoung Lee; Huen Lee

2006-01-01T23:59:59.000Z

464

Estimates of Biogenic Methane Production Rates in Deep Marine Sediments at Hydrate Ridge, Cascadia Margin  

Science Journals Connector (OSTI)

...fluids associated with a large gas hydrate reservoir...USA. Proc. Ocean Drilling Progr. Sci. Results...initial reports. Ocean Drilling Program, College Station...p. 18-22. Ocean Drilling Program, College Station...material turnover and large methane plumes at the...

F. S. Colwell; S. Boyd; M. E. Delwiche; D. W. Reed; T. J. Phelps; D. T. Newby

2008-03-14T23:59:59.000Z

465

* Corresponding author. E-mail: herri@emse.fr Formation & Dissociation of Methane Hydrates in Sediments  

E-Print Network [OSTI]

Hydrates in Sediments. The first part of the project that is presented hereafter is designed to obtain that lead to such accumulations, to evaluate the feasibility of its industrial recovery as an energy silica gels, engraved plate or sand grains empilage (Handa & Stupin, 1992; Anderson et al., 2001; Buffet

Boyer, Edmond

466

Internal hydration of protein cavities: studies on BPTIy Andrei I. Borodicha  

E-Print Network [OSTI]

to the protein is calculated from the thermodynamic cycle. The protein is viewed as a dielectric continuum March 2004 In this paper, we present a theoretical method to calculate the hydration free energies and water molecules as ligand particles. The free energy to transfer a water molecule from the gas phase

Ullmann, G. Matthias

467

Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm  

E-Print Network [OSTI]

Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm Brandy oxides found in streams, wetlands, soils, and aquifers. We investigated the mecha- nisms of Zn sorption experiments were conducted at pH 6.9 to characterize Zn sorption to this biogenic Mn oxide, and to determine

468

On the compliance method and the assessment of three-dimensional seafloor gas hydrate deposits  

Science Journals Connector (OSTI)

......approximation is not unlike the response of a country roadbed to an automobile moving over it. The car has motion but the response of the...of marine gas hydrate deposits using a seafloor transient electric dipole-dipole method62 6374. 10 Fink C.R. , Spence G......

K. Latychev; R. N. Edwards

2003-12-01T23:59:59.000Z