Sample records for hp sodium vapor

  1. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15T23:59:59.000Z

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  2. Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and

    E-Print Network [OSTI]

    Baker, Chris I.

    Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and HID (high-intensity discharge) lamps and all other mercury containing labeled for shipment to a recycling plant for mercury, glass and aluminum recovery. The beneficial re

  3. HP Steam Trap Monitoring

    E-Print Network [OSTI]

    Pascone, S.

    2011-01-01T23:59:59.000Z

    STEAM MONITORING HP Steam Trap Monitoring HP Steam Trap Monitoring ? 12-18 months payback! ? 3-5% permanent reduction in consumption ? LEED Pt.? Innovation in Operations EB O&M ? Saved clients over $1,000,000 Annual consumption... Steam Trap Monitoring ? Real-time monitoring for high-pressure critical traps (>15 PSIG) ? Average total system cost $25K - $50K ? Web-Based or Modbus/BMS Integration Basic Installation Wireless Signal Transmitter Receiver Repeater...

  4. Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas

    SciTech Connect (OSTI)

    Lee, S.H.D.; Swift, W.M.; Johnson, I.

    1980-01-01T23:59:59.000Z

    Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

  5. SciTech Connect: Thermodynamic and transport properties of sodium...

    Office of Scientific and Technical Information (OSTI)

    on thermophysical properties of sodium have been included in this critical assessment. Thermodynamic properties of sodium liquid and vapor that have been assessed...

  6. U-052: HP Protect Tools Device Access Manager Unspecified Bug...

    Broader source: Energy.gov (indexed) [DOE]

    PC HP EliteBook 2760p Notebook PC HP EliteBook 8460p Notebook PC HP EliteBook 8460w Mobile Workstation HP EliteBook 8560p Notebook PC HP EliteBook 8560w Mobile Workstation HP...

  7. T-623: HP Business Availability Center Input Validation Hole...

    Broader source: Energy.gov (indexed) [DOE]

    3: HP Business Availability Center Input Validation Hole Permits Cross-Site Scripting Attacks T-623: HP Business Availability Center Input Validation Hole Permits Cross-Site...

  8. U-137: HP Performance Manager Unspecified Bug Lets Remote Users...

    Broader source: Energy.gov (indexed) [DOE]

    7: HP Performance Manager Unspecified Bug Lets Remote Users Execute Arbitrary Codes U-137: HP Performance Manager Unspecified Bug Lets Remote Users Execute Arbitrary Codes March...

  9. U-203: HP Photosmart Bug Lets Remote Users Deny Service

    Broader source: Energy.gov [DOE]

    A vulnerability was reported in HP Photosmart. A remote user can cause denial of service conditions.

  10. Active Diesel Emission Control Technology for Sub-50 HP Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sub-50 HP Engines with Low Exhaust Temperature Profiles Active Diesel Emission Control Technology for Sub-50 HP Engines with Low Exhaust Temperature Profiles A new type of emission...

  11. U-013: HP Data Protector Multiple Unspecified Vulnerabilities

    Broader source: Energy.gov [DOE]

    Multiple vulnerabilities were reported in HP Data Protector. A remote user can execute arbitrary code on the target system.

  12. T-588: HP Virtual SAN Appliance Stack Overflow

    Broader source: Energy.gov [DOE]

    A vulnerability has been reported in HP StorageWorks P4000 Virtual SAN Appliance Software, which can be exploited by malicious people to compromise a vulnerable system.

  13. U-010:HP Onboard Administrator Unspecified Flaw Lets Remote Users...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HP Service Manager Unspecified Flaw Lets Remote Users Gain Unauthorized Access V-120: EMC Smarts Network Configuration Manager Java RMI Access Control Flaw Lets Remote Users...

  14. U-238: HP Service Manager Input Validation Flaw Permits Cross...

    Broader source: Energy.gov (indexed) [DOE]

    9.21, 9.30 ABSTRACT: Cross-site scripting (XSS) vulnerability in HP Service Manager Web Tier 7.11, 9.21, and 9.30, and HP Service Center Web Tier 6.28, allows remote attackers...

  15. U-044: HP Operations Agent and Performance Agent Lets Local Users...

    Broader source: Energy.gov (indexed) [DOE]

    4: HP Operations Agent and Performance Agent Lets Local Users Access a Restricted Directory U-044: HP Operations Agent and Performance Agent Lets Local Users Access a Restricted...

  16. Perlick: ENERGY STAR Referral (HP48RO-S)

    Broader source: Energy.gov [DOE]

    DOE referred Perlick refrigerator HP48RO-S to EPA, brand manager of the ENERGY STAR program, for appropriate action after DOE testing revealed that the model does not meet ENERGY STAR requirements.

  17. V-218: HP Service Manager Unspecified Flaw Lets Remote Users...

    Broader source: Energy.gov (indexed) [DOE]

    A remote user can gain unauthorized access on the target system. IMPACT: User access via network SOLUTION: The vendor has issued a fix. Addthis Related Articles U-010:HP Onboard...

  18. Calibrated vapor generator source

    DOE Patents [OSTI]

    Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

    1995-09-26T23:59:59.000Z

    A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

  19. Design and development of Stirling engines for stationary-power-generation applications in the 500- to 3000-hp range. Phase I final report

    SciTech Connect (OSTI)

    None

    1980-10-01T23:59:59.000Z

    The first phase of the design and development of Stirling engines for stationary power generation applications in the 373 kW (500 hp) to 2237 kW (3000 hp) range was completed. The tasks in Phase I include conceptual designs of large Stirling cycle stationary engines and program plan for implementing Phases II through V. Four different heater head designs and five different machine designs were prepared in sufficient detail to select a design recommended for development in the near future. A second order analysis was developed for examining the various loss mechanisms in the Stirling engine and for predicting the thermodynamic performance of these engines. The predicted engine thermal brake efficiency excluding combustion efficiency is approximately 42% which exceeds the design objective of 40%. The combustion system designs were prepared for both a clean fuel combustion system and a two-stage atmospheric fluidized bed combustion system. The calculated combustion efficiency of the former is 90% and of the latter is 80%. Heat transport systems, i.e., a heat exchanger for the clean fuel combustion system and a sodium heat pipe system for coal and other nonclean fuel combustion systems were selected. The cost analysis showed that for clean fuels combustion the proposed 2237 kW (3000 hp) system production cost is $478,242 or $214/kW ($159/hp) which is approximately 1.86 times the cost of a comparable size diesel engine. For solid coal combustion the proposed 2237 kW (3000 hp) system production cost is approximately $2,246,242 which corresponds to a cost to power capacity ratio of $1004/kW ($749/hp). The two-stage atmospheric fluidized bed combustion system represents 81% of the total cost; the engine represents 14% depending on the future price differential between coal and conventional clean fuels, a short payback period of the proposed Stirling cycle engine/FBC system may justify the initial cost. (LCL)

  20. FSHAKER: a transient control program. [For HP 5451C

    SciTech Connect (OSTI)

    Cawlfield, J L

    1980-10-01T23:59:59.000Z

    A description is given of FSHAKER, a transient control program for the performance of transient tests, written to run on the HP 5451C (Fourier) system. The report also contains a listing of a demonstration run made with FSHAKER. The appendix contains a commented listing of FSHAKER and listings of three Fortran user programs called by FSHAKER. (RWR)

  1. U-229: HP Network Node Manager i Input Validation Flaw Permits Cross-Site Scripting Attacks

    Broader source: Energy.gov [DOE]

    Potential security vulnerabilities have been identified with HP Network Node Manager i (NNMi) for HP-UX, Linux, Solaris, and Windows. The vulnerabilities could be remotely exploited resulting in cross site scripting (XSS).

  2. U-204: HP Network Node Manager i Input Validation Hole Permits Cross-Site Scripting Attacks

    Broader source: Energy.gov [DOE]

    Potential security vulnerabilities have been identified with HP Network Node Manager I (NNMi) for HP-UX, Linux, Solaris, and Windows. The vulnerabilities could be remotely exploited resulting in cross site scripting (XSS).

  3. U-201: HP System Management Homepage Bugs Let Remote Users Deny...

    Broader source: Energy.gov (indexed) [DOE]

    01: HP System Management Homepage Bugs Let Remote Users Deny Service U-201: HP System Management Homepage Bugs Let Remote Users Deny Service June 28, 2012 - 7:00am Addthis PROBLEM:...

  4. hp-mesh adaptation for 1-D multigroup neutron diffusion problems

    E-Print Network [OSTI]

    Wang, Yaqi

    2007-04-25T23:59:59.000Z

    In this work, we propose, implement and test two fully automated mesh adaptation methods for 1-D multigroup eigenproblems. The first method is the standard hp-adaptive refinement strategy and the second technique is a goal-oriented hp...

  5. V-166: HP-UX Directory Server Discloses Passwords to Remote Authentica...

    Broader source: Energy.gov (indexed) [DOE]

    6: HP-UX Directory Server Discloses Passwords to Remote Authenticated and Local Users V-166: HP-UX Directory Server Discloses Passwords to Remote Authenticated and Local Users May...

  6. U-275: HP IBRIX X9000 Storage Discloses Information to Remote...

    Broader source: Energy.gov (indexed) [DOE]

    The vendor has issued a fix (6.1.260). Addthis Related Articles V-166: HP-UX Directory Server Discloses Passwords to Remote Authenticated and Local Users U-135: HP WBEM...

  7. U-017: HP MFP Digital Sending Software Lets Local Users Obtain Potentially Sensitive Information

    Broader source: Energy.gov [DOE]

    A vulnerability was reported in HP MFP Digital Sending Software. A local user can obtain potentially sensitive information.

  8. U-208: HP Operations Agent Bugs Let Remote Users Execute Arbitrary Code

    Broader source: Energy.gov [DOE]

    Two vulnerabilities were reported in HP Operations Agent. A remote user can execute arbitrary code on the target system

  9. An Ant Colony Optimization Algorithm for the 2D HP Protein Folding Problem

    E-Print Network [OSTI]

    Hoos, Holger H.

    An Ant Colony Optimization Algorithm for the 2D HP Protein Folding Problem Alena Shmygelska, Rosal, the two dimensional hydrophobic-polar (2D HP) protein folding problem. We introduce an ant colony algorithm closely approaches that of specialised, state-of-the methods for 2D HP protein folding. 1

  10. An Improved Ant Colony Optimisation Algorithm for the 2D HP Protein Folding Problem

    E-Print Network [OSTI]

    Hoos, Holger H.

    An Improved Ant Colony Optimisation Algorithm for the 2D HP Protein Folding Problem Alena hydrophobic-polar (2D HP) protein folding problem. We present an improved version of our recently proposed Ant search. Overall, the results presented here establish our new ACO algorithm for 2D HP protein folding

  11. A New Algorithm for Protein Folding in the HP Model Alantha Newman

    E-Print Network [OSTI]

    Newman, Alantha

    A New Algorithm for Protein Folding in the HP Model Alantha Newman #3; Abstract We consider the problem of protein folding in the HP model on the two-dimensional square lattice. This problem but not in the string) are present. The protein folding problem in the hydrophobic-hydrophilic (HP) model on the 2D

  12. Protein Folding in the Hydrophobic-Hydrophilic (HP) Model is NP-Complete

    E-Print Network [OSTI]

    Istrail, Sorin

    Protein Folding in the Hydrophobic-Hydrophilic (HP) Model is NP-Complete Bonnie Berger* Tom Leightont Abstract One of the simplest and most popular biophysical mod- els of protein folding is the hydrophobic-hydrophilic (HP) model. The HP model abstracts the hydrophobic in- teraction in protein folding

  13. NREL: News Feature - HP Supercomputer at NREL Garners Top Honor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions and AchievementsResearch Staff MaterialsPrintableHP Supercomputer at

  14. Vapor spill monitoring method

    DOE Patents [OSTI]

    Bianchini, Gregory M. (Livermore, CA); McRae, Thomas G. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    Method for continuous sampling of liquified natural gas effluent from a spill pipe, vaporizing the cold liquified natural gas, and feeding the vaporized gas into an infrared detector to measure the gas composition. The apparatus utilizes a probe having an inner channel for receiving samples of liquified natural gas and a surrounding water jacket through which warm water is flowed to flash vaporize the liquified natural gas.

  15. THERMODYNAMIC AND TRANSPORT PROPERTIES OF SODIUM LIQUID AND VAPOR

    E-Print Network [OSTI]

    Kemner, Ken

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.1 Enthalpy and Heat Capacity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 1.1.2 Heat Capacity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Heat Capacity at Constant Pressure, CP . . . . . . . . . . . . . . . . . . . . . . . . 13 Heat

  16. Potential-field geophysical programs for VAX 7xx computers; source code (programs H-P)

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    A U.S. Geological Survey report is presented giving source code for potential-field geophysical programs (programs H-P) for VAX 7xx computers.

  17. T-608: HP Virtual Server Environment Lets Remote Authenticated Users Gain Elevated Privileges

    Broader source: Energy.gov [DOE]

    A potential security vulnerability has been identified in HP Virtual Server Environment for Windows. The vulnerability could be exploited remotely to elevate privileges.

  18. T-590: HP Diagnostics Input Validation Hole Permits Cross-Site Scripting Attacks

    Broader source: Energy.gov [DOE]

    A potential security vulnerability has been identified in HP Diagnostics. The vulnerability could be exploited remotely resulting in cross site scripting (XSS).

  19. V-146: HP Service Manager Bugs Permit Cross-Site Scripting and...

    Broader source: Energy.gov (indexed) [DOE]

    Cross-Site Scripting and Information Disclosure Attacks PLATFORM: Service Manager v9.31 Web Tier ABSTRACT: Two vulnerabilities were reported in HP Service Manager REFERENCE LINKS:...

  20. U-238: HP Service Manager Input Validation Flaw Permits Cross-Site Scripting Attacks

    Broader source: Energy.gov [DOE]

    Cross-site scripting (XSS) vulnerability in HP Service Manager Web Tier 7.11, 9.21, and 9.30, and HP Service Center Web Tier 6.28, allows remote attackers to inject arbitrary web script or HTML via unspecified vectors.

  1. A New Algorithm for Protein Folding in the HP Model Alantha Newman *

    E-Print Network [OSTI]

    Istrail, Sorin

    876 A New Algorithm for Protein Folding in the HP Model Alantha Newman * Abstract We consider the problem of protein folding in the HP model ozt the two-dimensional square lattice. This problem.e.pairsof H's that are adjacent in the folding but not in the string) are present. The protein folding problem

  2. Genetic Algorithm for Predicting Protein Folding in the 2D HP Model

    E-Print Network [OSTI]

    Emmerich, Michael

    Genetic Algorithm for Predicting Protein Folding in the 2D HP Model A Parameter Tuning Case Study of a protein, predicting its tertiary structure is known as the protein folding problem. This problem has been. The protein folding problem in the HP model is to find a conformation (a folded sequence) with the lowest

  3. SLU, Spring 2012 Bioenergy and social sciences: economics and sociology, 5hp

    E-Print Network [OSTI]

    SLU, Spring 2012 1/6 Bioenergy and social sciences: economics and sociology, 5hp PNS0083 Bioenergy and social sciences: economics and sociology, 5hp The course is given as part of the postgraduate research school "Bioenergy". The overall objective of the course is: 1. to enable the students

  4. A Branch and Bound Algorithm for the Protein Folding Problem in the HP Lattice Model

    E-Print Network [OSTI]

    Istrail, Sorin

    Article A Branch and Bound Algorithm for the Protein Folding Problem in the HP Lattice Model Mao tool for the protein folding problem. Key words: protein folding, HP model, branch and bound, lattice Introduction The protein folding problem, or the protein struc- ture prediction problem, is one of the most

  5. An Efficient Genetic Algorithm for Predicting Protein Tertiary Structures in the 2D HP Model

    E-Print Network [OSTI]

    Istrail, Sorin

    , predicting its tertiary structure is known as the protein folding problem. This problem has been widely genetic algo- rithm for the protein folding problem under the HP model in the two-dimensional square Genetic Algorithm, Protein Folding Problem, 2D HP Model 1. INTRODUCTION Amino acids are the building

  6. HP Laboratories 1/25/98 Hiro:Documents:Giordano Beretta:Research:EI 98:StudioPoster

    E-Print Network [OSTI]

    Beretta, Giordano

    HP Laboratories 1/25/98 Hiro:Documents:Giordano Beretta:Research:EI 98:StudioPoster 0Professional. #12;HP Laboratories 1/25/98 Hiro:Documents:Giordano Beretta:Research:EI 98:StudioPoster 1Introduction based on digital camera #12;HP Laboratories 1/25/98 Hiro:Documents:Giordano Beretta:Research:EI 98

  7. Gasoline vapor recovery

    SciTech Connect (OSTI)

    Lievens, G.; Tiberi, T.P.

    1993-06-22T23:59:59.000Z

    In a gasoline distribution network wherein gasoline is drawn from a gasoline storage tank and pumped into individual vehicles and wherein the gasoline storage tank is refilled periodically from a gasoline tanker truck, a method of recovering liquid gasoline from gasoline vapor that collects in the headspace of the gasoline storage tank as the liquid gasoline is drawn therefrom, said method comprising the steps of: (a) providing a source of inert gas; (b) introducing inert gas into the gasoline storage tank as liquid gasoline is drawn therefrom so that liquid gasoline drawn from the tank is displaced by inert gas and gasoline vapor mixes with the inert gas in the headspace of the tank; (c) collecting the inert gas/gasoline vapor mixture from the headspace of the gasoline storage tank as the tank is refilled from a gasoline tanker truck; (d) cooling the inert gas/gasoline vapor mixture to a temperature sufficient to condense the gasoline vapor in the mixture to liquid gasoline but not sufficient to liquify the inert gas in the mixture; (e) separating the condensed liquid gasoline from the inert gas; and delivering the condensed liquid gasoline to a remote location for subsequent use.

  8. Submersible sodium pump

    DOE Patents [OSTI]

    Brynsvold, G.V.; Lopez, J.T.; Olich, E.E.; West, C.W.

    1989-11-21T23:59:59.000Z

    An electromagnetic submerged pump has an outer cylindrical stator with an inner cylindrical conductive core for the submerged pumping of sodium in the cylindrical interstitial volume defined between the stator and core. The cylindrical interstitial volume is typically vertically oriented, and defines an inlet at the bottom and an outlet at the top. The outer stator generates upwardly conveyed toroidal magnetic fields, which fields convey preferably from the bottom of the pump to the top of the pump liquid sodium in the cold leg of a sodium cooled nuclear reactor. The outer cylindrical stator has a vertically disposed duct surrounded by alternately stacked layers of coil units and laminates. 14 figs.

  9. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

    1983-02-08T23:59:59.000Z

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

  10. Electrolyte vapor condenser

    DOE Patents [OSTI]

    Sederquist, Richard A. (Newington, CT); Szydlowski, Donald F. (East Hartford, CT); Sawyer, Richard D. (Canton, CT)

    1983-01-01T23:59:59.000Z

    A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

  11. Organic vapor jet printing system

    DOE Patents [OSTI]

    Forrest, Stephen R

    2012-10-23T23:59:59.000Z

    An organic vapor jet printing system includes a pump for increasing the pressure of an organic flux.

  12. Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects

    E-Print Network [OSTI]

    Chickos, James S.

    * Department of Chemistry and Biochemistry, University of MissourisSt. Louis, St. Louis, Missouri 63121 Liquid vapor pressure isotope effects have generally been observed, pD > pH.12 Vapor pressure and sublimation

  13. Stratified vapor generator

    DOE Patents [OSTI]

    Bharathan, Desikan (Lakewood, CO); Hassani, Vahab (Golden, CO)

    2008-05-20T23:59:59.000Z

    A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

  14. ARM - Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmr DocumentationProductsaodsasheniraodAlaskaVisiting theWater Vapor

  15. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect (OSTI)

    Eric M. Suuberg; Vahur Oja

    1997-07-01T23:59:59.000Z

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  16. HP Laboratories 4/28/02 Tofari:Users:berettag:Research:Conferences:EI 98:ontologyOHP.doc

    E-Print Network [OSTI]

    Beretta, Giordano

    HP Laboratories 4/28/02 Tofari:Users:berettag:Research:Conferences:EI 98:ontologyOHP.doc 0Structure-Packard Company. All rights reserved. #12;HP Laboratories 4/28/02 Tofari:Users:berettag:Research:Conferences:EI 98 radioactive · use a real big magnet · store needles separately from hay #12;HP Laboratories 4/28/02 Tofari:Users:berettag:Research:Conferences:EI

  17. ARM Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)Productssondeadjustsondeadjust DocumentationARM Participation in SuomiNet The ARM62ARM Water Vapor IOP

  18. Water Vapor Experiment Concludes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and Materials Disposition3 Water Vapor Experiment Concludes The

  19. To estimate vapor pressure easily

    SciTech Connect (OSTI)

    Yaws, C.L.; Yang, H.C. (Lamar Univ., Beaumont, TX (USA))

    1989-10-01T23:59:59.000Z

    Vapor pressures as functions of temperature for approximately 700 major organic chemical compounds are given. The tabulation also gives the temperature range for which the data are applicable. Minimum and maximum temperatures are denoted by TMIN and TMAX. The Antoine equation that correlates vapor pressure as a function of temperature is described. A representative comparison of calculated and actual data values for vapor pressure is shown for ethyl alcohol. The coefficient tabulation is based on both literature (experimental data) and estimated values.

  20. Using the Mass Storage System at ZIB within I3HP

    E-Print Network [OSTI]

    H. Stüben; S. Wollny

    2005-12-07T23:59:59.000Z

    In the framework of I3HP there are two Transnational Access Activities related to Computational Hadron Physics. One of these activities is access to the mass storage system at Konrad-Zuse-Zentrum fuer Informationstechnik Berlin (ZIB). European lattice physics collaborations can apply for mass storage capacity in order to store and share their configurations or other data (see http://www.zib.de/i3hp/). In this paper formal and technical aspects of usage as well as the conformance to the International Lattice DataGrid (ILDG) are explained.

  1. Vaporization of zinc from scrap

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    1996-12-31T23:59:59.000Z

    The rate of zinc vaporization from galvanized scrap was measured using a thermogravimetric apparatus along with chemical analysis. It is found that the rate of zinc vaporization is very fast in nitrogen and carbon monoxide atmospheres at temperatures higher than 950 C. At lower temperature rate decreases with decreasing temperature and is controlled by the gas phase mass transport. The simultaneous oxidation and vaporization of zinc occurs when the samples were heated in carbon dioxide and air. The current experimental results indicate that almost all of the zinc from scrap vaporizes during the heating process in a very short period of time after the temperature reaches above 850 C.

  2. Vapor spill pipe monitor

    DOE Patents [OSTI]

    Bianchini, G.M.; McRae, T.G.

    1983-06-23T23:59:59.000Z

    The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

  3. Solution of coupled acousticelastic wave propagation problems with anelastic attenuation using automatic hp-adaptivity

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    Solution of coupled acoustic­elastic wave propagation problems with anelastic attenuation using Keywords: Borehole acoustic logging Wave propagation Linear elasticity Coupled problems Hp-adaptive finite to various poroelasticity theories. Simulations of sonic tools. Numerical modeling of the wave prop- agation

  4. Local rules for protein folding on a triangular lattice and generalized hydrophobicity in the HP model

    SciTech Connect (OSTI)

    Agarwala, R. [National Institutes of Health, Bethesda, MD (United States); Batzoglou, S. [MIT, Cambridge, MA (United States); Dancik, V. [Univ. of Southern California, Los Angeles, CA (United States)] [and others

    1997-06-01T23:59:59.000Z

    We consider the problem of determining the three-dimensional folding of a protein given its one-dimensional amino acid sequence. We use the HP model for protein folding proposed by Dill, which models protein as a chain of amino acid residues that are either hydrophobic or polar, and hydrophobic interactions are the dominant initial driving force for the protein folding. Hart and Istrail gave approximation algorithms for folding proteins on the cubic lattice under HP model. In this paper, we examine the choice of a lattice by considering its algorithmic and geometric implications and argue that triangular lattice is a more reasonable choice. We present a set of folding rules for a triangular lattice and analyze the approximation ratio which they achieve. In addition, we introduce a generalization of the HP model to account for residues having different levels of hydrophobicity. After describing the biological foundation for this generalization, we show that in the new model we are able to achieve similar constant factor approximation guarantees on the triangular lattice as were achieved in the standard HP model. While the structures derived from our folding rules are probably still far from biological reality, we hope that having a set of folding rules with different properties will yield more interesting folds when combined.

  5. Parallel Ant Colony Optimization for 3D Protein Structure Prediction using the HP Lattice Model

    E-Print Network [OSTI]

    Istrail, Sorin

    of Sydney Sydney 2006, NSW Australia Abstract The Protein Folding Problem studies the way in which a protein proteins fold can be fundamental in developing treatments of diseases such as Alzeihmers and Systic of solving the HP protein folding problem in both two and three dimensions using Ant Colony Opti- mizations

  6. Fuel vapor control device

    SciTech Connect (OSTI)

    Ota, I.; Nishimura, Y.; Nishio, S.; Yogo, K.

    1987-10-20T23:59:59.000Z

    A fuel vapor control device is described having a valve opening and closing a passage connecting a carburetor and a charcoal canister according to a predetermined temperature. A first coil spring formed by a ''shape memory effect'' alloy is provided to urge the valve to open the passage when the temperature is high. A second coil spring urges the valve to close the passage. A solenoid is provided to urge an armature against the valve to close the passage against the force of the first coil spring when the engine is running. The solenoid heats the first coil spring to generate a spring force therein when the engine is running. When the engine is turned off, the solenoid is deactivated, and the force of the first spring overcomes the force of the second spring to open the passage until such time as the temperature of the first spring drops below the predetermined temperature.

  7. Complexed Adsorbed HP1 HP1 L2 L7 L7 L7 L2 H3 H3 National Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New SubstationCleanCommunity Involvement andMISR, and4 NComplexComplexed Adsorbed HP1

  8. Passive vapor extraction feasibility study

    SciTech Connect (OSTI)

    Rohay, V.J.

    1994-06-30T23:59:59.000Z

    Demonstration of a passive vapor extraction remediation system is planned for sites in the 200 West Area used in the past for the disposal of waste liquids containing carbon tetrachloride. The passive vapor extraction units will consist of a 4-in.-diameter pipe, a check valve, a canister filled with granular activated carbon, and a wind turbine. The check valve will prevent inflow of air that otherwise would dilute the soil gas and make its subsequent extraction less efficient. The granular activated carbon is used to adsorb the carbon tetrachloride from the air. The wind turbine enhances extraction rates on windy days. Passive vapor extraction units will be designed and operated to meet all applicable or relevant and appropriate requirements. Based on a cost analysis, passive vapor extraction was found to be a cost-effective method for remediation of soils containing lower concentrations of volatile contaminants. Passive vapor extraction used on wells that average 10-stdft{sup 3}/min air flow rates was found to be more cost effective than active vapor extraction for concentrations below 500 parts per million by volume (ppm) of carbon tetrachloride. For wells that average 5-stdft{sup 3}/min air flow rates, passive vapor extraction is more cost effective below 100 ppm.

  9. Portable vapor diffusion coefficient meter

    DOE Patents [OSTI]

    Ho, Clifford K. (Albuquerque, NM)

    2007-06-12T23:59:59.000Z

    An apparatus for measuring the effective vapor diffusion coefficient of a test vapor diffusing through a sample of porous media contained within a test chamber. A chemical sensor measures the time-varying concentration of vapor that has diffused a known distance through the porous media. A data processor contained within the apparatus compares the measured sensor data with analytical predictions of the response curve based on the transient diffusion equation using Fick's Law, iterating on the choice of an effective vapor diffusion coefficient until the difference between the predicted and measured curves is minimized. Optionally, a purge fluid can forced through the porous media, permitting the apparatus to also measure a gas-phase permeability. The apparatus can be made lightweight, self-powered, and portable for use in the field.

  10. Vapor deposition of hardened niobium

    DOE Patents [OSTI]

    Blocher, Jr., John M. (Columbus, OH); Veigel, Neil D. (Columbus, OH); Landrigan, Richard B. (Columbus, OH)

    1983-04-19T23:59:59.000Z

    A method of coating ceramic nuclear fuel particles containing a major amount of an actinide ceramic in which the particles are placed in a fluidized bed maintained at ca. 800.degree. to ca. 900.degree. C., and niobium pentachloride vapor and carbon tetrachloride vapor are led into the bed, whereby niobium metal is deposited on the particles and carbon is deposited interstitially within the niobium. Coating apparatus used in the method is also disclosed.

  11. ID-69 Sodium drain experiments

    SciTech Connect (OSTI)

    Johnston, D.C.

    1996-09-19T23:59:59.000Z

    This paper describes experiments to determine the sodium retention and drainage from the two key areas of an ID-69. This information is then used as the initiation point for guidelines of how to proceed with washing an ID-69 in the IEM Cell Sodium Removal System.

  12. Sodium loop framework structural analysis

    SciTech Connect (OSTI)

    Nguyen, P.M.

    1995-06-06T23:59:59.000Z

    This document provides the structural analysis of the Sodium Loop framework in a drop condition. The drop is similar to the US Department of Transportation non-bulk, performance-oriented packaging (Packaging Group I) drop test. The drop height evaluated for the Sodium Loop framework is 5.9 ft.

  13. Microstructural characterization of dissimilar welds between alloy 800 and HP heat-resistant steel

    SciTech Connect (OSTI)

    Dehmolaei, R. [Department of Materials Engineering, Isfahan University of Technology, Isfahan, 84156-83111 (Iran, Islamic Republic of); Shamanian, M. [Department of Materials Engineering, Isfahan University of Technology, Isfahan, 84156-83111 (Iran, Islamic Republic of)], E-mail: shamanian@cc.iut.ac.ir; Kermanpur, A. [Department of Materials Engineering, Isfahan University of Technology, Isfahan, 84156-83111 (Iran, Islamic Republic of)

    2008-10-15T23:59:59.000Z

    In this study, dissimilar welds between HP heat-resistant steel and Incoloy 800 were made with four different filler materials including: 309 stainless steel and nickel-based Inconel 82, 182 and 617. The microstructure of the base metals, weld metals and their interfaces were characterized by utilizing optical and scanning electron microscopy. Grain boundaries migration in the weld metals was studied. It was found that the migration of grain boundaries in the Inconel 82 weld metal was very extensive. Precipitates of TiC and M{sub 23}C{sub 6} (M = Cr and Mo) in the Inconel 617 weld metal are identified. The necessary conditions for the formation of cracks close to the fusion line of the 309-HP joints are described. Furthermore unmixed zone near the fusion line between HP steel base metal and Inconel 82 weld metal is discussed. An epitaxial growth is characterized at the fusion line of the 309-Alloy 800 and Inconel 617-Alloy 800 joints.

  14. Tables of thermodynamic properties of sodium

    SciTech Connect (OSTI)

    Fink, J.K.

    1982-06-01T23:59:59.000Z

    The thermodynamic properties of saturated sodium, superheated sodium, and subcooled sodium are tabulated as a function of temperature. The temperature ranges are 380 to 2508 K for saturated sodium, 500 to 2500 K for subcooled sodium, and 400 to 1600 K for superheated sodium. Tabulated thermodynamic properties are enthalpy, heat capacity, pressure, entropy, density, instantaneous thermal expansion coefficient, compressibility, and thermal pressure coefficient. Tables are given in SI units and cgs units.

  15. Independent Oversight Review, Sodium Bearing Waste Treatment...

    Energy Savers [EERE]

    Federal - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Federal - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project -...

  16. Independent Oversight Review, Sodium Bearing Waste Treatment...

    Energy Savers [EERE]

    Contractor - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Contractor - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project...

  17. The Vaporization Enthalpies and Vapor Pressures of Some Primary Amines of Pharmaceutical Importance by Correlation Gas

    E-Print Network [OSTI]

    Chickos, James S.

    by Correlation Gas Chromatography Chase Gobble, Nigam Rath, and James Chickos* Department of Chemistry Information ABSTRACT: Vapor pressures, vaporization, and sublimation enthalpies of several pharmaceuticals and boiling temperatures when available. Sublimation enthalpies and vapor pressures are also evaluated for 1

  18. HP Laboratories 1/24/98 Hiro:Documents:Giordano Beretta:Research:EI 98:DqtPoster

    E-Print Network [OSTI]

    Beretta, Giordano

    HP Laboratories 1/24/98 Hiro:Documents:Giordano Beretta:Research:EI 98:DqtPoster 0Compressing:Documents:Giordano Beretta:Research:EI 98:DqtPoster 1The hotting of the W3 · The W3was designed for the paradigm.http://www.w3.org/Style/ #12;HP Laboratories 1/24/98 Hiro:Documents:Giordano Beretta:Research:EI 98:Dqt

  19. Simulation of sodium boiling experiments with THERMIT sodium version

    E-Print Network [OSTI]

    Huh, Kang Yul

    1982-01-01T23:59:59.000Z

    Natural and forced convection experiments(SBTF and French) are simulated with the sodium version of the thermal-hydraulic computer code THERMIT. Simulation is done for the test secti- -on with the pressure-velocity boundary ...

  20. Vapor deposition of thin films

    DOE Patents [OSTI]

    Smith, David C. (Los Alamos, NM); Pattillo, Stevan G. (Los Alamos, NM); Laia, Jr., Joseph R. (Los Alamos, NM); Sattelberger, Alfred P. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A highly pure thin metal film having a nanocrystalline structure and a process of preparing such highly pure thin metal films of, e.g., rhodium, iridium, molybdenum, tungsten, rhenium, platinum, or palladium by plasma assisted chemical vapor deposition of, e.g., rhodium(allyl).sub.3, iridium(allyl).sub.3, molybdenum(allyl).sub.4, tungsten(allyl).sub.4, rhenium(allyl).sub.4, platinum(allyl).sub.2, or palladium(allyl).sub.2 are disclosed. Additionally, a general process of reducing the carbon content of a metallic film prepared from one or more organometallic precursor compounds by plasma assisted chemical vapor deposition is disclosed.

  1. VAPORIZATION THERMODYNAMICS OF KCl. COMBINING VAPOR PRESSURE AND GRAVIMETRIC DATA

    E-Print Network [OSTI]

    Rudnyi, Evgenii B.

    .B. Department of Chemistry, Moscow State University, Moscow, 119899, Russia Bonnell D.W., Hastie J.W. National temperature chemistry situations, vapor pressures are typically less than 100 kPa. The molar volume is p = 101325 Pa). The subscript trs denotes that the changeisfor a transition, typically sublimation

  2. Monte Carlo simulations of the HP model (the "Ising model" of protein folding)

    E-Print Network [OSTI]

    Li, Ying Wai; Landau, David P; 10.1016/j.cpc.2010.12.049

    2011-01-01T23:59:59.000Z

    Using Wang-Landau sampling with suitable Monte Carlo trial moves (pull moves and bond-rebridging moves combined) we have determined the density of states and thermodynamic properties for a short sequence of the HP protein model. For free chains these proteins are known to first undergo a collapse "transition" to a globule state followed by a second "transition" into a native state. When placed in the proximity of an attractive surface, there is a competition between surface adsorption and folding that leads to an intriguing sequence of "transitions". These transitions depend upon the relative interaction strengths and are largely inaccessible to "standard" Monte Carlo methods.

  3. U-117: Potential security vulnerability has been identified with certain HP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyTheTwo New Energy Storage6 (07/03)Arbitraryprinters and HP

  4. Hydrogen Cars and Water Vapor

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    misidentified as "zero-emissions vehicles." Fuel cell vehicles emit water vapor. A global fleet could have, with discernible effects on people and ecosystems. The broad environmental effects of fuel cell vehicles. This cycle is currently under way with hydrogen fuel cells. As fuel cell cars are suggested as a solution

  5. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  6. Vapor canister heater for evaporative emissions systems

    SciTech Connect (OSTI)

    Bishop, R.P.; Berg, P.G.

    1987-01-01T23:59:59.000Z

    Automotive evaporative emissions systems use a charcoal canister to store evaporative hydrocarobn emissions. These stored vapors are later purged and burned during engine operation. Under certain conditions the engine cannot completely purge the canister of the stored fuel vapors, which results in a decreased vapor storage capacity in the canister. A self-regulating PTC (Positive Temperature Coefficient) heater has been developed to warm the purge air as it enters the canister, in order to provide thermal energy for increased release of the vapors from charcoal sites. This paper describes the construction and operation of the vapor canister heater as it relates to improved evaporative emission system performance.

  7. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Abstract: Sodium ion (Na+) batteries...

  8. anticoagulant sodium citrate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressure-velocity boundary ... Huh, Kang Yul 1982-01-01 38 Ground beef shelf life assessment as influenced by sodium lactate, sodium propionate, sodium diacetate, and soy...

  9. Interaction of wide-band-gap single crystals with 248-nm excimer laser radiation. XI. The effect of water vapor and temperature on laser desorption

    E-Print Network [OSTI]

    Dickinson, J. Thomas

    . Significantly, introducing water vapor lowers the particle velocities and thus the effective surface temperature systems, simultaneous electronic excitation and exposure to aggressive chemicals can acceler- ate etching-induced neutral particle desorption and surface erosion on single- crystal sodium chloride in the presence of low

  10. Netscape Directory Server B.06.11.40 for HP-UX Release Notes

    E-Print Network [OSTI]

    unknown authors

    2005-01-01T23:59:59.000Z

    information in this document is subject to change without notice. Hewlett-Packard makes no warranty of any kind with regard to this manual, including, but not limited to, the implied warranties of merchantability and fitness for a particular purpose. Hewlett-Packard shall not be held liable for errors contained herein or direct, indirect, special, incidental or consequential damages in connection with the furnishing, performance, or use of this material. Warranty A copy of the specific warranty terms applicable to your Hewlett-Packard product and replacement parts can be obtained from your local Sales and Service Office. U.S. Government License Proprietary computer software. Valid license from HP required for possession, use or copying.

  11. Netscape Directory Server B.07.00.10 for HP-UX Release Notes

    E-Print Network [OSTI]

    Hp-ux I Version

    2005-01-01T23:59:59.000Z

    information in this document is subject to change without notice. Hewlett-Packard makes no warranty of any kind with regard to this manual, including, but not limited to, the implied warranties of merchantability and fitness for a particular purpose. Hewlett-Packard shall not be held liable for errors contained herein or direct, indirect, special, incidental or consequential damages in connection with the furnishing, performance, or use of this material. Warranty A copy of the specific warranty terms applicable to your Hewlett-Packard product and replacement parts can be obtained from your local Sales and Service Office. U.S. Government License Proprietary computer software. Valid license from HP required for possession, use or copying.

  12. Local rules for protein folding on a triangular lattice and generalized hydrophobicity in the HP model

    SciTech Connect (OSTI)

    Agarwala, R. [National Institutes of Health, Bethesda, MD (United States); Batzoglou, S. [MIT Lab. for Computer Science, Cambridge, MA (United States); Dancik, V. [Univ. of Southern California, Los Angeles, CA (United States)] [and others

    1997-12-01T23:59:59.000Z

    A long standing problem in molecular biology is to determine the three-dimensional structure of a protein, given its amino acid sequence. A variety of simplifying models have been proposed abstracting only the {open_quotes}essential physical properties{close_quotes} of real proteins. In these models, the three dimensional space is often represented by a lattice. Residues which are adjacent in the primary sequence (i.e. covalently linked) must be placed at adjacent points in the lattice. A conformation of a protein is simply a self-avoiding walk along the lattice. The protein folding problem STRING-FOLD is that of finding a conformation of the protein sequence on the lattice such that the overall energy is minimized, for some reasonable definition of energy. This formulation leaves open the choices of a lattice and an energy function. Once these choices are made, one may then address the algorithmic complexity of optimizing the energy function for the lattice. For a variety of such simple models, this minimization problem is in fact NP-hard. In this paper, we consider the Hydrophobic-Polar (HP) Model introduced by Dill. The HP model abstracts the problem by grouping the 20 amino acids into two classes: hydrophobic (or non-polar) residues and hydrophilic (or polar) residues. For concreteness, we will take our input to be a string from (H,P){sup +}, where P represents polar residues, and H represents hydrophobic residues. Dill et.al. survey the literature analyzing this model. 8 refs., 2 figs., 1 tab.

  13. Control of flow through a vapor generator

    DOE Patents [OSTI]

    Radcliff, Thomas D.

    2005-11-08T23:59:59.000Z

    In a Rankine cycle system wherein a vapor generator receives heat from exhaust gases, provision is made to avoid overheating of the refrigerant during ORC system shut down while at the same time preventing condensation of those gases within the vapor generator when its temperature drops below a threshold temperature by diverting the flow of hot gases to ambient and to thereby draw ambient air through the vapor generator in the process. In one embodiment, a bistable ejector is adjustable between one position, in which the hot gases flow through the vapor generator, to another position wherein the gases are diverted away from the vapor generator. Another embodiment provides for a fixed valve ejector with a bias towards discharging to ambient, but with a fan on the downstream side of said vapor generator for overcoming this bias.

  14. Numerical simulation of borehole acoustic logging in the frequency and time domains with hp-adaptive finite elements

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    and for the improvement of acoustic logging techniques used by oil- and oil-service companies to detect and quantifyNumerical simulation of borehole acoustic logging in the frequency and time domains with hp Available online 8 January 2009 Keywords: Acoustic logging Borehole acoustics Wave propagation Linear

  15. 2 15.10.2013 Joachim Dietle Optimisation of Air-Water HP's Optimisation of Air-Water Heat Pumps

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    -Water Heat Pumps Ziehl-Abegg SE System boundary Improve Air Flow of Fan Improve System Joachim Dietle.10.2013 Joachim Dietle Optimisation of Air-Water HP's System boundary Air Flow in Heat Pumps V q d p st p P P L fan )( 1 Relevant for cooling or heating! Optimise heat pump: reduce pressure drop increase

  16. Global warming and wintering in Dippers Degree project in Biology, 15hp (15 ETCS), 2014-2015

    E-Print Network [OSTI]

    Uppsala Universitet

    Global warming and wintering in Dippers Degree project in Biology, 15hp (15 ETCS), 2014-2015 Aim: Investigate changes in wintering ecology of the dipper over a period of 35 years in the light of global warming. Dippers overwinter in streams and they arrive to their overwintering grounds in late fall

  17. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  18. Overview of chemical vapor infiltration

    SciTech Connect (OSTI)

    Besmann, T.M.; Stinton, D.P.; Lowden, R.A.

    1993-06-01T23:59:59.000Z

    Chemical vapor infiltration (CVI) is developing into a commercially important method for the fabrication of continuous filament ceramic composites. Current efforts are focused on the development of an improved understanding of the various processes in CVI and its modeling. New approaches to CVI are being explored, including pressure pulse infiltration and microwave heating. Material development is also proceeding with emphasis on improving the oxidation resistance of the interfacial layer between the fiber and matrix. This paper briefly reviews these subjects, indicating the current state of the science and technology.

  19. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17T23:59:59.000Z

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  20. Near real time vapor detection and enhancement using aerosol adsorption

    SciTech Connect (OSTI)

    Novick, Vincent J.; Johnson, Stanley A.

    1997-12-01T23:59:59.000Z

    A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

  1. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, V.J.; Johnson, S.A.

    1999-08-03T23:59:59.000Z

    A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

  2. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, Vincent J. (Downers Grove, IL); Johnson, Stanley A. (Countryside, IL)

    1999-01-01T23:59:59.000Z

    A vapor sample detection method where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample.

  3. Fire suppressing apparatus. [sodium fires

    DOE Patents [OSTI]

    Buttrey, K.E.

    1980-12-19T23:59:59.000Z

    Apparatus for smothering a liquid sodium fire comprises a pan, a perforated cover on the pan, and tubed depending from the cover and providing communication between the interior of the pan and the ambient atmosphere through the perforations in the cover. Liquid caught in the pan rises above the lower ends of the tubes and thus serves as a barrier which limits the amount of air entering the pan.

  4. Tropospheric water vapor and climate sensitivity

    SciTech Connect (OSTI)

    Schneider, E.K.; Kirtman, B.P.; Lindzen, R.S. [Center for Ocean-Land-Atmosphere Studies, Calverton, MD (United States)] [Center for Ocean-Land-Atmosphere Studies, Calverton, MD (United States)

    1999-06-01T23:59:59.000Z

    Estimates are made of the effect of changes in tropospheric water vapor on the climate sensitivity to doubled carbon dioxide (CO{sub 2}) using a coarse resolution atmospheric general circulation model coupled to a slab mixed layer ocean. The sensitivity of the model to doubled CO{sub 2} is found as the difference between the equilibrium responses for control and doubled CO{sub 2} cases. Clouds are specified to isolate the water vapor feedback. Experiments in which the water vapor distribution is specified rather than internally calculated are used to find the contribution of water vapor in various layers and latitude belts to the sensitivity. The contribution of water vapor in layers of equal mass to the climate sensitivity varies by about a factor of 2 with height, with the largest contribution coming from layers between 450 and 750 mb, and the smallest from layers above 230 mb. The positive feedback on the global mean surface temperature response to doubled CO{sub 2} from water vapor above 750 mb is about 2.6 times as large as that from water vapor below 750 mb. The feedback on global mean surface temperature due to water vapor in the extratropical free troposphere is about 50% larger than the feedback due to the lower-latitude free troposphere water vapor. Several important sources of nonlinearity of the radiative heating rates were identified in the process of constructing the specified cloud and water vapor fields. These are (1) the interaction of clouds and solar radiation, which produces much more reflection of solar radiation for time mean clouds than for the instantaneous clouds; (2) the correlation of clouds and water vapor, which produces less downward longwave radiation at the ground for correlated clouds and water vapor than when these fields are independent; and (3) the interaction of water vapor with long wave radiation, which produces less downward longwave radiation at the ground of the average over instantaneous water vapor distributions than of the time mean water vapor distribution.

  5. Quantitative organic vapor-particle sampler

    DOE Patents [OSTI]

    Gundel, Lara (Berkeley, CA); Daisey, Joan M. (Walnut Creek, CA); Stevens, Robert K. (Cary, NC)

    1998-01-01T23:59:59.000Z

    A quantitative organic vapor-particle sampler for sampling semi-volatile organic gases and particulate components. A semi-volatile organic reversible gas sorbent macroreticular resin agglomerates of randomly packed microspheres with the continuous porous structure of particles ranging in size between 0.05-10 .mu.m for use in an integrated diffusion vapor-particle sampler.

  6. Thermophilic Biotrickling Filtration of Ethanol Vapors

    E-Print Network [OSTI]

    Thermophilic Biotrickling Filtration of Ethanol Vapors H U U B H . J . C O X , T H O M A S S E X of ethanol vapors in biotrickling filters for air pollution control was investigated. Two reactors were adaptation phase, the removal of ethanol was similar in both reactors. At a bed contact time of 57 s

  7. LNG fire and vapor control system technologies

    SciTech Connect (OSTI)

    Konzek, G.J.; Yasutake, K.M.; Franklin, A.L.

    1982-06-01T23:59:59.000Z

    This report provides a review of fire and vapor control practices used in the liquefied natural gas (LNG) industry. Specific objectives of this effort were to summarize the state-of-the-art of LNG fire and vapor control; define representative LNG facilities and their associated fire and vapor control systems; and develop an approach for a quantitative effectiveness evaluation of LNG fire and vapor control systems. In this report a brief summary of LNG physical properties is given. This is followed by a discussion of basic fire and vapor control design philosophy and detailed reviews of fire and vapor control practices. The operating characteristics and typical applications and application limitations of leak detectors, fire detectors, dikes, coatings, closed circuit television, communication systems, dry chemicals, water, high expansion foam, carbon dioxide and halogenated hydrocarbons are described. Summary descriptions of a representative LNG peakshaving facility and import terminal are included in this report together with typical fire and vapor control systems and their locations in these types of facilities. This state-of-the-art review identifies large differences in the application of fire and vapor control systems throughout the LNG industry.

  8. Salt effect on the isobaric vapor-liquid equilibrium of the methyl acetate + methanol system

    SciTech Connect (OSTI)

    Iliuta, M.C.; Thyrion, F.C. [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.] [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.; Landauer, O.M. [Univ. Politehnica Bucharest (Romania)] [Univ. Politehnica Bucharest (Romania)

    1996-07-01T23:59:59.000Z

    The effect of sodium thiocyanate at constant salt mole fraction from 0.01 to 0.05 and at saturation on the vapor-liquid equilibrium (VLE) of methyl acetate + methanol has been studied at 101.32 kPa using a modified Othmer equilibrium still. The salt exhibited both salting-in and salting-out effects on the methyl acetate, the azeotrope being eliminated at saturation. The results were correlated using the extended UNIQUAC model of Sander et al. and the electrolytic NRTL model of Mock et al.

  9. New approach for calibration the efficiency of HpGe detectors

    SciTech Connect (OSTI)

    Alnour, I. A. [Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia and Department of Physics, Faculty of Pure and Applied Science, International University of Africa, 12223 Khartoum (Sudan); Wagiran, H. [Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor (Malaysia); Ibrahim, N. [Faculty of Defence Science and Technology, National Defence University of Malaysia, Kem Sungai Besi, 57000 Kuala Lumpur (Malaysia); Hamzah, S.; Siong, W. B.; Elias, M. S. [Malaysia Nuclear Agency (MNA), Bangi, 43000 Kajang, Selangor (Malaysia)

    2014-02-12T23:59:59.000Z

    This work evaluates the efficiency calibrating of HpGe detector coupled with Canberra GC3018 with Genie 2000 software and Ortec GEM25-76-XLB-C with Gamma Vision software; available at Neutron activation analysis laboratory in Malaysian Nuclear Agency (NM). The efficiency calibration curve was constructed from measurement of an IAEA, standard gamma–point sources set composed by {sup 214}Am, {sup 57}Co, {sup 133}Ba, {sup 152}Eu, {sup 137}Cs and {sup 60}Co. The efficiency calibrations were performed for three different geometries: 5, 10 and 15 cm distances from the end cap detector. The polynomial parameters functions were simulated through a computer program, MATLAB in order to find an accurate fit to the experimental data points. The efficiency equation was established from the known fitted parameters which allow for the efficiency evaluation at particular energy of interest. The study shows that significant deviations in the efficiency, depending on the source-detector distance and photon energy.

  10. Netscape Directory Server B.06.11.40 for HP-UX Release Notes

    E-Print Network [OSTI]

    unknown authors

    2005-01-01T23:59:59.000Z

    information in this document is subject to change without notice. Hewlett-Packard makes no warranty of any kind with regard to this manual, including, but not limited to, the implied warranties of merchantability and fitness for a particular purpose. Hewlett-Packard shall not be held liable for errors contained herein or direct, indirect, special, incidental or consequential damages in connection with the furnishing, performance, or use of this material. Warranty A copy of the specific warranty terms applicable to your Hewlett-Packard product and replacement parts can be obtained from your local Sales and Service Office. U.S. Government License Proprietary computer software. Valid license from HP required for possession, use or copying. Consistent with FAR 12.211 and 12.212, Commercial Computer Software, Computer Software Documentation, and Technical Data for Commercial Items are licensed to the U.S. Government under vendor's standard commercial license. Copyright Notices Copyright © 2005 Hewlett-Packard Company L.P. All rights reserved. Reproduction, adaptation, or translation of this document without prior written permission is prohibited, except as allowed under the copyright laws. Trademark Notices UNIX ® is a registered trademark in the United States and other countries, licensed exclusively through The Open Group.

  11. HANFORD CHEMICAL VAPORS WORKER CONCERNS & EXPOSURE EVALUATION

    SciTech Connect (OSTI)

    ANDERSON, T.J.

    2006-12-20T23:59:59.000Z

    Chemical vapor emissions from underground hazardous waste storage tanks on the Hanford site in eastern Washington State are a potential concern because workers enter the tank farms on a regular basis for waste retrievals, equipment maintenance, and surveillance. Tank farm contractors are in the process of retrieving all remaining waste from aging single-shell tanks, some of which date to World War II, and transferring it to newer double-shell tanks. During the waste retrieval process, tank farm workers are potentially exposed to fugitive chemical vapors that can escape from tank headspaces and other emission points. The tanks are known to hold more than 1,500 different species of chemicals, in addition to radionuclides. Exposure assessments have fully characterized the hazards from chemical vapors in half of the tank farms. Extensive sampling and analysis has been done to characterize the chemical properties of hazardous waste and to evaluate potential health hazards of vapors at the ground surface, where workers perform maintenance and waste transfer activities. Worker concerns. risk communication, and exposure assessment are discussed, including evaluation of the potential hazards of complex mixtures of chemical vapors. Concentrations of vapors above occupational exposure limits-(OEL) were detected only at exhaust stacks and passive breather filter outlets. Beyond five feet from the sources, vapors disperse rapidly. No vapors have been measured above 50% of their OELs more than five feet from the source. Vapor controls are focused on limited hazard zones around sources. Further evaluations of vapors include analysis of routes of exposure and thorough analysis of nuisance odors.

  12. Quantitative Infrared Intensity Studies of Vapor-PhaseGlyoxal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Intensity Studies of Vapor-Phase Glyoxal,Methylglyoxal, and 2,3-Butanedione (Diacetyl) with Quantitative Infrared Intensity Studies of Vapor-Phase Glyoxal,Methylglyoxal,...

  13. Absolute integrated intensities of vapor-phase hydrogen peroxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Absolute integrated intensities of vapor-phase hydrogen peroxide (H202) in the mid-infrared at atmospheric pressure. Absolute integrated intensities of vapor-phase hydrogen...

  14. Calculation of Ambient (H*(10)) and Personal (Hp(10)) Dose Equivalent from a 252Cf Neutron Source

    SciTech Connect (OSTI)

    Traub, Richard J.

    2010-03-26T23:59:59.000Z

    The purpose of this calculation is to calculate the neutron dose factors for the Sr-Cf-3000 neutron source that is located in the 318 low scatter room (LSR). The dose factors were based on the dose conversion factors published in ICRP-21 Appendix 6, and the Ambient dose equivalent (H*(10)) and Personal dose equivalent (Hp(10)) dose factors published in ICRP Publication 74.

  15. Recent advances with quiescent power supply current (I sub DDQ ) testing at Sandia using the HP82000

    SciTech Connect (OSTI)

    Righter, A.W.; Leong, D.J.; Cox, L.B.

    1991-01-01T23:59:59.000Z

    Last year at the HP82000 Users Group Meeting, Sandia National Laboratories gave a presentation on I{sub DDQ} testing. This year, we will present some advances on this testing including DUT board fixturing, external DC PMU measurement, and automatic IDD-All circuit calibration. This paper is geared more toward implementation than theory, with results presented from Sandia tests. After a brief summary I{sub DDQ} theory and testing concepts, we will describe how the break (hold state) vector and data formatting present a test vector generation concern for the HP82000. We than discuss fixturing of the DUT board for both types of I{sub DDQ} measurement, and how the continuity test and test vector generation must be taken into account. Results of a test including continuity, IDD-All and I{sub DDQ} Value measurements will be shown. Next, measurement of low current using an external PMU is discussed, including noise considerations, implementation and some test results showing nA-range measurements. We then present a method for automatic calibration of the IDD-All analog comparator circuit using RM BASIC on the HP82000, with implementation and measurement results. Finally, future directions for research in this area will be explored. 14 refs., 16 figs.

  16. Independent Oversight Assessment, Idaho Cleanup Project Sodium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bearing Waste Treatment Project - November 2012 November 2012 Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project This...

  17. TOXICOLOGICAL AND STRUCTURAL CONSEQUENCES FROM SODIUM-WATER REACTION IN CELL CONTAINING THE SECONDARY SODIUM TANK

    SciTech Connect (OSTI)

    MARUSICH RM

    2008-06-25T23:59:59.000Z

    The analysis will show the consequences should the solid sodium in the Secondary Sodium Tank react with a presumed layer of water in the cell. The Peer Review Checklist is attached.

  18. A layered sodium titanate as promising anode material for sodium ion batteries

    E-Print Network [OSTI]

    Wu, Di, S.M. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Sodium ion batteries have recently received great attention for large-scale energy applications because of the abundance and low cost of sodium source. Although some cathode materials with desirable electrochemical properties ...

  19. Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes

    DOE Patents [OSTI]

    Balagopal, Shekar; Malhotra, Vinod; Pendleton, Justin; Reid, Kathy Jo

    2012-09-18T23:59:59.000Z

    An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane, such as membranes based on NASICON-type materials, in an electrolytic cell. In the process, water is reduced at a cathode to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution are oxidized in the anolyte compartment to produce chlorine gas which reacts with water to produce hypochlorous and hydrochloric acid. Sodium ions are transported from the anolyte compartment to the catholyte compartment across the sodium ion conductive ceramic membrane. Sodium hydroxide is transported from the catholyte compartment to the anolyte compartment to produce sodium hypochlorite within the anolyte compartment.

  20. Chemical vapor deposition of functionalized isobenzofuran polymers

    E-Print Network [OSTI]

    Olsson, Ylva Kristina

    2007-01-01T23:59:59.000Z

    This thesis develops a platform for deposition of polymer thin films that can be further tailored by chemical surface modification. First, we explore chemical vapor deposition of functionalized isobenzofuran films using ...

  1. Chemical vapor deposition of antimicrobial polymer coatings

    E-Print Network [OSTI]

    Martin, Tyler Philip, 1977-

    2007-01-01T23:59:59.000Z

    There is large and growing interest in making a wide variety of materials and surfaces antimicrobial. Initiated chemical vapor deposition (iCVD), a solventless low-temperature process, is used to form thin films of polymers ...

  2. E-Print Network 3.0 - aqueous sodium dodecyl Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Sodium Dodecyl Sulfate and Sodium Dodecyl Benzenesulfonate on Poly(Vinyl Chloride) Latexes Summary: 1 Adsorption of Sodium Dodecyl Sulfate and Sodium Dodecyl...

  3. Atlas Sodium Automated Batch Synthesis System

    E-Print Network [OSTI]

    Subramanian, Venkat

    Atlas Sodium Automated Batch Synthesis System (Syrris) June 2013 #12;Introduction to the system · The Atlas Sodium system consists of an Atlas base equipped with a 400ºC hotplate, a stacking dry bath systemL) for automated addition and/or removal of solution. · The system is computer controlled by the Atlas software

  4. Optical monitor for water vapor concentration

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1998-01-01T23:59:59.000Z

    A system for measuring and monitoring water vapor concentration in a sample uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to a water vapor absorption line. In a preferred embodiment, the argon line is split by a magnetic field parallel to the direction of light propagation from the lamp into sets of components of downshifted and upshifted frequencies of approximately 1575 Gauss. The downshifted components are centered on a water vapor absorption line and are thus readily absorbed by water vapor in the sample; the upshifted components are moved away from that absorption line and are minimally absorbed. A polarization modulator alternately selects the upshifted components or downshifted components and passes the selected components to the sample. After transmission through the sample, the transmitted intensity of a component of the argon line varies as a result of absorption by the water vapor. The system then determines the concentration of water vapor in the sample based on differences in the transmitted intensity between the two sets of components. In alternative embodiments alternate selection of sets of components is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to the emitting plasma.

  5. Sodium Heat Engine Development Program

    SciTech Connect (OSTI)

    Singh, J.P.; Kupperman, D.S.; Majumdar, S.; Dorris, S.; Gopalsami, N.; Dieckman, S.L.; Jaross, R.A.; Johnson, D.L.; Gregar, J.S.; Poeppel, R.B.; Raptis, A.C.; Valentin, R.A.

    1992-01-01T23:59:59.000Z

    The Sodium Heat Engine (SHE) is an efficient thermoelectric conversion device which directly generates electricity from a thermally regenerative electrochemical cell that relies on the unique conduction properties of {beta}{double prime}-alumina solid electrolyte (BASE). Laboratory models of a variety of SHE devices have demonstrated the feasibility and efficiency of the system, engineering development of large prototype devices has been slowed by a series of materials and fabrication problems. Failure of the electrolyte tubes has been a recurring problem and a number of possible causes have been postulated. To address these issues, a two-phase engineering development program was undertaken. This report summarizes the final results of the first phase of the program, which included extensive materials characterization activities, a study of applicable nondestructive evaluation methods, an investigation of possible stress states that would contribute to fracture, and certain operational issues associated with the electromagnetic pumps used in the SHE prototype. Mechanical and microstructural evaluation of commercially obtained BASE tubes revealed that they should be adequate for SHE applications and that sodium exposure produced no appreciable deleterious strength effects. Processing activities to produce a more uniform and smaller grain size for the BASE tubes were completed using isostatic pressing, extrusion, and slip casting. Green tubes were sintered by conventional and microwave plasma methods. Of particular interest is the residual stress state in the BASE tubes, and both analysis and nondestructive evaluation methods were employed to evaluate these stresses. X-ray and neutron diffraction experiments were performed to determine the bulk residual stresses in commercially fabricated BASE tubes; however, tube-to-tube variations and variations among the various methods employed did not allow formulation of a definitive definition of the as-fabricated stress state.

  6. In-situ method for treating residual sodium

    SciTech Connect (OSTI)

    Sherman, Steven R. (Idaho Falls, ID); Henslee, S. Paul (Idaho Falls, ID)

    2005-07-19T23:59:59.000Z

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  7. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19T23:59:59.000Z

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  8. Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids

    E-Print Network [OSTI]

    Chickos, James S.

    Vapor Pressures and Vaporization, Sublimation, and Fusion Enthalpies of Some Fatty Acids Joe A. Wilson and James S. Chickos* Department of Chemistry and Biochemistry, University of MissouriSt. Louis, St. Louis, Missouri 63121, United States *S Supporting Information ABSTRACT: Sublimation enthalpies

  9. Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    Chromatography Chase Gobble and James Chickos* Department of Chemistry and Biochemistry University of Missouri-St. Louis, St. Louis Missouri 63121, United States Sergey P. Verevkin Department of Physical Chemistry: Experimental vapor pressures, vaporization, fusion and sublimation enthalpies of a number of dialkyl

  10. A resting bottom sodium cooled fast reactor

    SciTech Connect (OSTI)

    Costes, D. [Consultant (France)

    2012-07-01T23:59:59.000Z

    This follows ICAPP 2011 paper 11059 'Fast Reactor with a Cold Bottom Vessel', on sodium cooled reactor vessels in thermal gradient, resting on soil. Sodium is frozen on vessel bottom plate, temperature increasing to the top. The vault cover rests on the safety vessel, the core diagrid welded to a toric collector forms a slab, supported by skirts resting on the bottom plate. Intermediate exchangers and pumps, fixed on the cover, plunge on the collector. At the vessel top, a skirt hanging from the cover plunges into sodium, leaving a thin circular slit partially filled by sodium covered by argon, providing leak-tightness and allowing vessel dilatation, as well as a radial relative holding due to sodium inertia. No 'air conditioning' at 400 deg. C is needed as for hanging vessels, and this allows a large economy. The sodium volume below the slab contains isolating refractory elements, stopping a hypothetical corium flow. The small gas volume around the vessel limits any LOCA. The liner cooling system of the concrete safety vessel may contribute to reactor cooling. The cold resting bottom vessel, proposed by the author for many years, could avoid the complete visual inspection required for hanging vessels. However, a double vessel, containing support skirts, would allow introduction of inspecting devices. Stress limiting thermal gradient is obtained by filling secondary sodium in the intermediate space. (authors)

  11. IAEA sodium void reactivity benchmark calculations

    SciTech Connect (OSTI)

    Hill, R.N.; Finck, P.J.

    1992-12-01T23:59:59.000Z

    In this paper, the IAEA-1 992 ``Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core`` problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

  12. IAEA sodium void reactivity benchmark calculations

    SciTech Connect (OSTI)

    Hill, R.N.; Finck, P.J.

    1992-01-01T23:59:59.000Z

    In this paper, the IAEA-1 992 Benchmark Calculation of Sodium Void Reactivity Effect in Fast Reactor Core'' problem is evaluated. The proposed design is a large axially heterogeneous oxide-fueled fast reactor as described in Section 2; the core utilizes a sodium plenum above the core to enhance leakage effects. The calculation methods used in this benchmark evaluation are described in Section 3. In Section 4, the calculated core performance results for the benchmark reactor model are presented; and in Section 5, the influence of steel and interstitial sodium heterogeneity effects is estimated.

  13. Vapor scavenging by atmospheric aerosol particles

    SciTech Connect (OSTI)

    Andrews, E.

    1996-05-01T23:59:59.000Z

    Particle growth due to vapor scavenging was studied using both experimental and computational techniques. Vapor scavenging by particles is an important physical process in the atmosphere because it can result in changes to particle properties (e.g., size, shape, composition, and activity) and, thus, influence atmospheric phenomena in which particles play a role, such as cloud formation and long range transport. The influence of organic vapor on the evolution of a particle mass size distribution was investigated using a modified version of MAEROS (a multicomponent aerosol dynamics code). The modeling study attempted to identify the sources of organic aerosol observed by Novakov and Penner (1993) in a field study in Puerto Rico. Experimentally, vapor scavenging and particle growth were investigated using two techniques. The influence of the presence of organic vapor on the particle`s hydroscopicity was investigated using an electrodynamic balance. The charge on a particle was investigated theoretically and experimentally. A prototype apparatus--the refractive index thermal diffusion chamber (RITDC)--was developed to study multiple particles in the same environment at the same time.

  14. Radial power flattening in sodium fast reactors

    E-Print Network [OSTI]

    Krentz-Wee, Rebecca (Rebecca Elizabeth)

    2012-01-01T23:59:59.000Z

    In order to improve a new design for a uranium startup sodium cooled fast reactor which was proposed at MIT, this thesis evaluated radial power flattening by varying the fuel volume fraction at a fixed U-235 enrichment of ...

  15. Sodium Alanate Nanoparticles for Hydrogen Storage.

    E-Print Network [OSTI]

    Baldé, C.P.

    2008-01-01T23:59:59.000Z

    ??Preparation and characterization of sodium alanate (NaAlH4) based hydrogen storage materials are described in this book. The effect of the NaAlH4 particle size, particularly in… (more)

  16. Vapor characterization of Tank 241-C-103

    SciTech Connect (OSTI)

    Huckaby, J.L. [Westinghouse Hanford Co., Richland, WA (United States); Story, M.S. [Northwest Instrument Systems, Inc. Richland, WA (United States)

    1994-06-01T23:59:59.000Z

    The Westinghouse Hanford Company Tank Vapor Issue Resolution Program has developed, in cooperation with Northwest Instrument Systems, Inc., Oak Ridge National Laboratory, Oregon Graduate Institute of Science and Technology, Pacific Northwest Laboratory, and Sandia National Laboratory, the equipment and expertise to characterize gases and vapors in the high-level radioactive waste storage tanks at the Hanford Site in south central Washington State. This capability has been demonstrated by the characterization of the tank 241-C-103 headspace. This tank headspace is the first, and for many reasons is expected to be the most problematic, that will be characterized (Osborne 1992). Results from the most recent and comprehensive sampling event, sample job 7B, are presented for the purpose of providing scientific bases for resolution of vapor issues associated with tank 241-C-103. This report is based on the work of Clauss et al. 1994, Jenkins et al. 1994, Ligotke et al. 1994, Mahon et al. 1994, and Rasmussen and Einfeld 1994. No attempt has been made in this report to evaluate the implications of the data presented, such as the potential impact of headspace gases and vapors to tank farm workers health. That and other issues will be addressed elsewhere. Key to the resolution of worker health issues is the quantitation of compounds of toxicological concern. The Toxicology Review Panel, a panel of Pacific Northwest Laboratory experts in various areas, of toxicology, has chosen 19 previously identified compounds as being of potential toxicological concern. During sample job 7B, the sampling and analytical methodology was validated for this preliminary list of compounds of toxicological concern. Validation was performed according to guidance provided by the Tank Vapor Conference Committee, a group of analytical chemists from academic institutions and national laboratories assembled and commissioned by the Tank Vapor Issue Resolution Program.

  17. Method and Apparatus for Concentrating Vapors for Analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2008-10-07T23:59:59.000Z

    An apparatus and method are disclosed for pre-concentrating gaseous vapors for analysis. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable. Vapors sorbed and concentrated within the bed of the apparatus can be thermally desorbed achieving at least partial separation of vapor mixtures. The apparatus is suitable, e.g., for preconcentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than for direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications.

  18. Optimized Wang-Landau sampling of lattice polymers: Ground state search and folding thermodynamics of HP model proteins

    E-Print Network [OSTI]

    Thomas Wüst; David P. Landau

    2012-07-17T23:59:59.000Z

    Coarse-grained (lattice-) models have a long tradition in aiding efforts to decipher the physical or biological complexity of proteins. Despite the simplicity of these models, however, numerical simulations are often computationally very demanding and the quest for efficient algorithms is as old as the models themselves. Expanding on our previous work [T. W\\"ust and D. P. Landau, Phys. Rev. Lett. 102, 178101 (2009)], we present a complete picture of a Monte Carlo method based on Wang-Landau sampling in combination with efficient trial moves (pull, bond-rebridging and pivot moves) which is particularly suited to the study of models such as the hydrophobic-polar (HP) lattice model of protein folding. With this generic and fully blind Monte Carlo procedure, all currently known putative ground states for the most difficult benchmark HP sequences could be found. For most sequences we could also determine the entire energy density of states and, together with suitably designed structural observables, explore the thermodynamics and intricate folding behavior in the virtually inaccessible low-temperature regime. We analyze the differences between random and protein-like heteropolymers for sequence lengths up to 500 residues. Our approach is powerful both in terms of robustness and speed, yet flexible and simple enough for the study of many related problems in protein folding.

  19. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, T.

    1988-03-15T23:59:59.000Z

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

  20. The Sodium Process Facility at Argonne National Laboratory-West

    SciTech Connect (OSTI)

    Michelbacher, J.A.; Henslee, S.P. McDermott, M.D.; Price, J.R.; Rosenberg, K.E.; Wells, P.B.

    1998-07-01T23:59:59.000Z

    Argonne National Laboratory-West (ANL-W) has approximately 680,000 liters of raw sodium stored in facilities on site. As mandated by the State of Idaho and the US Department of Energy (DOE), this sodium must be transformed into a stable condition for land disposal. To comply with this mandate, ANL-W designed and built the Sodium Process Facility (SPF) for the processing of this sodium into a dry, sodium carbonate powder. The major portion of the sodium stored at ANL-W is radioactively contaminated. The sodium will be processed in three separate and distinct campaigns: the 290,000 liters of Fermi-1 primary sodium, the 50,000 liters of the Experimental Breeder Reactor-II (EBR-II) secondary sodium, and the 330,000 liters of the EBR-II primary sodium. The Fermi-1 and the EBR-II secondary sodium contain only low-level of radiation, while the EBR-II primary sodium has radiation levels up to 0.5 mSv (50 mrem) per hour at 1 meter. The EBR-II primary sodium will be processed last, allowing the operating experience to be gained with the less radioactive sodium prior to reacting the most radioactive sodium. The sodium carbonate will be disposed of in 270 liter barrels, four to a pallet. These barrels are square in cross-section, allowing for maximum utilization of the space on a pallet, minimizing the required landfill space required for disposal.

  1. Vapor intrusion modeling : limitations, improvements, and value of information analyses

    E-Print Network [OSTI]

    Friscia, Jessica M. (Jessica Marie)

    2014-01-01T23:59:59.000Z

    Vapor intrusion is the migration of volatile organic compounds (VOCs) from a subsurface source into the indoor air of an overlying building. Vapor intrusion models, including the Johnson and Ettinger (J&E) model, can be ...

  2. Moisture Durability of Vapor Permeable Insulating Sheathing (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-10-01T23:59:59.000Z

    In this project, Building America team Building Science Corporation researched some of the ramifications of using exterior, vapor permeable insulation on retrofit walls with vapor permeable cavity insulation. Retrofit strategies are a key factor in reducing exterior building stock consumption.

  3. Desalination Using Vapor-Compression Distillation

    E-Print Network [OSTI]

    Lubis, Mirna R.

    2010-07-14T23:59:59.000Z

    and MSF, this research investigates a high-efficiency mechanical vapor-compression distillation system that employs an improved water flow arrangement. The incoming salt concentration was 0.15% salt for brackish water and 3.5% salt for seawater, whereas...

  4. Reductive Dehalogenation of Trichloroethene Vapors in an

    E-Print Network [OSTI]

    to treat trichloroethene (TCE) from waste gases generated by soil vapor extraction or dual-phase extraction through the recirculating liquid as a source of hydrogen, the electron donor for Dehalococcoides strains (DPE) (4). However, these techniques result in a waste gas stream that needs further treatment. Several

  5. Advancing Explosives Detection Capabilities: Vapor Detection

    ScienceCinema (OSTI)

    Atkinson, David

    2014-07-24T23:59:59.000Z

    A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

  6. Vaporization of synthetic fuels. Final report. [Thesis

    SciTech Connect (OSTI)

    Sirignano, W.A.; Yao, S.C.; Tong, A.Y.; Talley, D.

    1983-01-01T23:59:59.000Z

    The problem of transient droplet vaporization in a hot convective environment is examined. The main objective of the present study is to develop an algorithm for the droplet vaporization which is simple enough to be feasibly incorporated into a complete spray combustion analysis and yet will also account for the important physics such as liquid-phase internal circulation, unsteady droplet heating and axisymmetric gas-phase convection. A simplified liquid-phase model has been obtained based on the assumption of the existence of a Hill's spherical vortex inside the droplet together with some approximations made in the governing diffusion equation. The use of the simplified model in a spray situation has also been examined. It has been found that droplet heating and vaporization are essentially unsteady and droplet temperature is nonuniform for a significant portion of its lifetime. It has also been found that the droplet vaporization characteristic can be quite sensitive to the particular liquid-phase and gas-phase models. The results of the various models are compared with the existing experimental data. Due to large scattering in the experimental measurements, particularly the droplet diameter, no definite conclusion can be drawn based on the experimental data. Finally, certain research problems which are related to the present study are suggested for future studies.

  7. Chemical vapor deposition of mullite coatings

    DOE Patents [OSTI]

    Sarin, Vinod (Lexington, MA); Mulpuri, Rao (Boston, MA)

    1998-01-01T23:59:59.000Z

    This invention is directed to the creation of crystalline mullite coatings having uniform microstructure by chemical vapor deposition (CVD). The process comprises the steps of establishing a flow of reactants which will yield mullite in a CVD reactor, and depositing a crystalline coating from the reactant flow. The process will yield crystalline coatings which are dense and of uniform thickness.

  8. Industrial Heat Pumps Using Solid/Vapor Working Fluids

    E-Print Network [OSTI]

    Rockenfeller, U.

    INDUSTRIAL HEAT PUMPS USING SOLID/VAPOR WORKING FLUIDS Uwe Rockenfeller, Desert Research Institute, Boulder City, Nevada ABSTRACT Industrial heat pumps have the potential to reduce the operating costs of chemical and heat treating processes... with vapor re-compression recovery systems. The state-of-the-art heat pump equipment employing liquid/vapor working fluids fulfills the requirements only in some applications. The employment of solid/vapor complex compounds leads to 'nore cost effective...

  9. Method and system for producing hydrogen using sodium ion separation membranes

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M; Frost, Lyman

    2013-05-21T23:59:59.000Z

    A method of producing hydrogen from sodium hydroxide and water is disclosed. The method comprises separating sodium from a first aqueous sodium hydroxide stream in a sodium ion separator, feeding the sodium produced in the sodium ion separator to a sodium reactor, reacting the sodium in the sodium reactor with water, and producing a second aqueous sodium hydroxide stream and hydrogen. The method may also comprise reusing the second aqueous sodium hydroxide stream by combining the second aqueous sodium hydroxide stream with the first aqueous sodium hydroxide stream. A system of producing hydrogen is also disclosed.

  10. Modeling engine oil vaporization and transport of the oil vapor in the piston ring pack on internal combustion engines

    E-Print Network [OSTI]

    Cho, Yeunwoo, 1973-

    2004-01-01T23:59:59.000Z

    A model was developed to study engine oil vaporization and oil vapor transport in the piston ring pack of internal combustion engines. With the assumption that the multi-grade oil can be modeled as a compound of several ...

  11. Development of models for the sodium version of the two-phase three-dimensional thermal hydraulics code THERMIT. [LMFBR

    SciTech Connect (OSTI)

    Wilson, G.J.; Kazimi, M.S.

    1980-05-01T23:59:59.000Z

    Several different models and correlations were developed and incorporated in the sodium version of THERMIT, a thermal-hydraulics code written at MIT for the purpose of analyzing transients under LMFBR conditions. This includes: a mechanism for the inclusion of radial heat conduction in the sodium coolant as well as radial heat loss to the structure surrounding the test section. The fuel rod conduction scheme was modified to allow for more flexibility in modelling the gas plenum regions and fuel restructuring. The formulas for mass and momentum exchange between the liquid and vapor phases were improved. The single phase and two phase friction factors were replaced by correlations more appropriate to LMFBR assembly geometry.

  12. Design, fabrication, and testing of a sodium evaporator for the STM4-120 kinematic Stirling engine

    SciTech Connect (OSTI)

    Rawlinson, K.S.; Adkins, D.R.

    1995-05-01T23:59:59.000Z

    This report describes the development and testing of a compact heat-pipe heat exchanger kW(e) designed to transfer thermal energy from hot combustion gases to the heater tubes of a 25-kW(e) Stirling engine. In this system, sodium evaporates from a surface that is heated by a stream of hot gases. The liquid metal then condenses on the heater tubes of a Stirling engine, where energy is transferred to the engine`s helium working fluid. Tests on a prototype unit illustrated that a compact (8 cm {times} 13 cm {times} 16 cm) sodium evaporator can routinely transfer 15 kW(t) of energy at an operating vapor temperature of 760 C. Four of these prototype units were eventually used to power a 25-kW(e) Stirling engine system. Design details and test results from the prototype unit are presented in this report.

  13. First search for double beta decay of platinum by ultra-low background HP Ge gamma spectrometry

    E-Print Network [OSTI]

    P. Belli; R. Bernabei; F. Cappella; R. Cerulli; F. A. Danevich; A. Di Marco; A. Incicchitti; M. Laubenstein; S. S. Nagorny; S. Nisi; O. G. Polischuk; V. I. Tretyak

    2011-04-29T23:59:59.000Z

    A search for double beta processes in 190Pt and 198Pt was realized with the help of ultra-low background HP Ge 468 cm^3 gamma spectrometer in the underground Gran Sasso National Laboratories of the INFN (Italy). After 1815 h of data taking with 42.5 g platinum sample, T_{1/2} limits on 2beta processes in 190Pt (\\epsilon\\beta^+ and 2\\epsilon) have been established on the level of 10^{14}-10^{16} yr, 3 to 4 orders of magnitude higher than those known previously. In particular, a possible resonant double electron capture in 190Pt was restricted on the level of 2.9 \\times 10^{16} yr at 90% C.L. In addition, T_{1/2} limit on 2 beta^- decay of 198Pt (2\

  14. First search for double beta decay of platinum by ultra-low background HP Ge gamma spectrometry

    E-Print Network [OSTI]

    Belli, P; Cappella, F; Cerulli, R; Danevich, F A; Di Marco, A; Incicchitti, A; Laubenstein, M; Nagorny, S S; Nisi, S; Polischuk, O G; Tretyak, V I

    2011-01-01T23:59:59.000Z

    A search for double beta processes in 190Pt and 198Pt was realized with the help of ultra-low background HP Ge 468 cm^3 gamma spectrometer in the underground Gran Sasso National Laboratories of the INFN (Italy). After 1815 h of data taking with 42.5 g platinum sample, T_{1/2} limits on 2beta processes in 190Pt (\\epsilon\\beta^+ and 2\\epsilon) have been established on the level of 10^{14}-10^{16} yr, 3 to 4 orders of magnitude higher than those known previously. In particular, a possible resonant double electron capture in 190Pt was restricted on the level of 2.9 \\times 10^{16} yr at 90% C.L. In addition, T_{1/2} limit on 2 beta^- decay of 198Pt (2\

  15. A High Temperature Electrochemical Energy Storage System Based on Sodium Beta-Alumina Solid Electrolyte (Base)

    SciTech Connect (OSTI)

    Anil Virkar

    2008-03-31T23:59:59.000Z

    This report summarizes the work done during the period September 1, 2005 and March 31, 2008. Work was conducted in the following areas: (1) Fabrication of sodium beta{double_prime} alumina solid electrolyte (BASE) using a vapor phase process. (2) Mechanistic studies on the conversion of {alpha}-alumina + zirconia into beta{double_prime}-alumina + zirconia by the vapor phase process. (3) Characterization of BASE by X-ray diffraction, SEM, and conductivity measurements. (4) Design, construction and electrochemical testing of a symmetric cell containing BASE as the electrolyte and NaCl + ZnCl{sub 2} as the electrodes. (5) Design, construction, and electrochemical evaluation of Na/BASE/ZnCl{sub 2} electrochemical cells. (6) Stability studies in ZnCl{sub 2}, SnCl{sub 2}, and SnI{sub 4} (7) Design, assembly and testing of planar stacks. (8) Investigation of the effect of porous surface layers on BASE on cell resistance. The conventional process for the fabrication of sodium ion conducting beta{double_prime}-alumina involves calcination of {alpha}-alumina + Na{sub 2}CO{sub 3} + LiNO{sub 3} at 1250 C, followed by sintering powder compacts in sealed containers (platinum or MgO) at {approx}1600 C. The novel vapor phase process involves first sintering a mixture of {alpha}-alumina + yttria-stabilized zirconia (YSZ) into a dense ceramic followed by exposure to soda vapor at {approx}1450 C to convert {alpha}-alumina into beta{double_prime}-alumina. The vapor phase process leads to a high strength BASE, which is also resistant to moisture attack, unlike BASE made by the conventional process. The PI is the lead inventor of the process. Discs and tubes of BASE were fabricated in the present work. In the conventional process, sintering of BASE is accomplished by a transient liquid phase mechanism wherein the liquid phase contains NaAlO{sub 2}. Some NaAlO{sub 2} continues to remain at grain boundaries; and is the root cause of its water sensitivity. In the vapor phase process, NaAlO{sub 2} is never formed. Conversion occurs by a coupled transport of Na{sup +} through BASE formed and of O{sup 2-} through YSZ to the reaction front. Transport to the reaction front is described in terms of a chemical diffusion coefficient of Na{sub 2}O. The conversion kinetics as a function of microstructure is under investigation. The mechanism of conversion is described in this report. A number of discs and tubes of BASE have been fabricated by the vapor phase process. The material was investigated by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM), before and after conversion. Conductivity (which is almost exclusively due to sodium ion transport at the temperatures of interest) was measured. Conductivity was measured using sodium-sodium tests as well as by impedance spectroscopy. Various types of both planar and tubular electrochemical cells were assembled and tested. In some cases the objective was to determine if there was any interaction between the salt and BASE. The interaction of interest was mainly ion exchange (possible replacement of sodium ion by the salt cation). It was noted that Zn{sup 2+} did not replace Na+ over the conditions of interest. For this reason much of the work was conducted with ZnCl{sub 2} as the cathode salt. In the case of Sn-based, Sn{sup 2+} did ion exchange, but Sn{sup 4+} did not. This suggests that Sn{sup 4+} salts are viable candidates. These results and implications are discussed in the report. Cells made with Na as the anode and ZnCl{sub 2} as the cathode were successfully charged/discharged numerous times. The key advantages of the batteries under investigation here over the Na-S batteries are: (1) Steel wool can be used in the cathode compartment unlike Na-S batteries which require expensive graphite. (2) Planar cells can be constructed in addition to tubular, allowing for greater design flexibility and integration with other devices such as planar SOFC. (3) Comparable or higher open circuit voltage (OCV) than the Na-S battery. (4) Wider operating temperature range and higher temper

  16. Apparatus and method for photochemical vapor deposition

    DOE Patents [OSTI]

    Jackson, Scott C. (Wilmington, DE); Rocheleau, Richard E. (Wilmington, DE)

    1987-03-31T23:59:59.000Z

    A photochemical vapor deposition apparatus includes a reactor housing having a window in one wall above a reaction chamber in the housing. A transparent curtain divides the reaction chamber into a reaction zone and a flush zone. At least one substrate is mounted in the reaction zone in light communication with the window so that ultraviolet radiation may penetrate through the window into the reaction zone. The window is kept clear by a gas flowing through the flush zone.

  17. DuPont Chemical Vapor Technical Report

    SciTech Connect (OSTI)

    MOORE, T.L.

    2003-10-03T23:59:59.000Z

    DuPont Safety Resources was tasked with reviewing the current chemical vapor control practices and providing preventive recommendations on best commercial techniques to control worker exposures. The increased focus of the tank closure project to meet the 2024 Tri-Party Agreement (TPA) milestones has surfaced concerns among some CH2MHill employees and other interested parties. CH2MHill is committed to providing a safe working environment for employees and desires to safely manage the tank farm operations using appropriate control measures. To address worker concerns, CH2MHill has chartered a ''Chemical Vapors Project'' to integrate the activities of multiple CH2MHill project teams, and solicit the expertise of external resources, including an independent Industrial Hygiene expert panel, a communications consultant, and DuPont Safety Resources. Over a three-month time period, DuPont worked with CH2MHill ESH&Q, Industrial Hygiene, Engineering, and the independent expert panel to perform the assessment. The process included overview presentations, formal interviews, informal discussions, documentation review, and literature review. DuPont Safety Resources concluded that it is highly unlikely that workers in the tank farms are exposed to chemicals above established standards. Additionally, the conventional and radiological chemistry is understood, the inherent chemical hazards are known, and the risk associated with chemical vapor exposure is properly managed. The assessment highlighted management's commitment to addressing chemical vapor hazards and controlling the associated risks. Additionally, we found the Industrial Hygiene staff to be technically competent and well motivated. The tank characterization data resides in a comprehensive database containing the tank chemical compositions and relevant airborne concentrations.

  18. Copper vapor laser modular packaging assembly

    DOE Patents [OSTI]

    Alger, Terry W. (Tracy, CA); Ault, Earl R. (Dublin, CA); Moses, Edward I. (Castro Valley, CA)

    1992-01-01T23:59:59.000Z

    A modularized packaging arrangement for one or more copper vapor lasers and associated equipment is disclosed herein. This arrangement includes a single housing which contains the laser or lasers and all their associated equipment except power, water and neon, and means for bringing power, water, and neon which are necessary to the operation of the lasers into the container for use by the laser or lasers and their associated equipment.

  19. Modeling of LNG Pool Spreading and Vaporization

    E-Print Network [OSTI]

    Basha, Omar 1988-

    2012-11-20T23:59:59.000Z

    ..................................................................................... 15 Figure 5: 90 mol% Methane 10mol% Ethane mixture VLE phase envelope .................. 18 Figure 6: Boiling temperature and vapor composition of 90 mol% methane 10mol% ethane mixture... process of natural gas allows a 600 fold reduction in the volume of the gas being transported at ambient pressure. The resulting liquid which is mainly composed of methane presents some hazardous properties linked to its flammable nature and its...

  20. Vapor-phase heat-transport system

    SciTech Connect (OSTI)

    Hedstrom, J.C.

    1983-01-01T23:59:59.000Z

    A vapor-phase heat-transport system is being tested in one of the passive test cells at Los Alamos. The system consists of one selective-surface collector and a condenser inside a water storage tank. The refrigerant, R-11, can be returned to the collector by gravity or with a pump. Results from several operating configurations are presented, together with a comparison with other passive systems. A new self-pumping concept is presented.

  1. STUDY OF THE RADIATION HARDNESS OF VCSEL AND PIN K.K. GAN, W. FERNANDO, H.P. KAGAN, R.D. KASS, A. LAW,

    E-Print Network [OSTI]

    Gan, K. K.

    that the main radiation effect is bulk damage in the VCSEL and PIN with the displacement of atoms. After five and VCSEL arrays coupled to radiation-hard ASICs produced for the current pixel optical link [5], the DORIC1 STUDY OF THE RADIATION HARDNESS OF VCSEL AND PIN ARRAYS K.K. GAN, W. FERNANDO, H.P. KAGAN, R

  2. Using Satellite Ocean Color Data to Derive an Empirical Model for the Penetration Depth of Solar Radiation (Hp) in the Tropical Pacific Ocean

    E-Print Network [OSTI]

    Chen, .Dake

    the climate through the penetration depth of solar radiation in the upper ocean (Hp), a primary parameter on penetrative solar radiation in the tropical Pacific, demonstrating the dynamical implication of remotely in which incident solar radiation is absorbed in the mixed layer and the verti- cal penetration down

  3. Long Proteins with Unique Optimal Foldings in the H-P Model Oswin Aichholzer David Bremner y Erik D. Demaine z Henk Meijer x

    E-Print Network [OSTI]

    results about bonds in the H-P model. 1 Introduction Protein folding is a central problem such as drug de- sign. One of the most popular models of protein folding is the hydrophilic-hydrophobic (H of protein folding such as the tendency for the hydrophobic components to fold to the center of a globular

  4. Combined rankine and vapor compression cycles

    DOE Patents [OSTI]

    Radcliff, Thomas D.; Biederman, Bruce P.; Brasz, Joost J.

    2005-04-19T23:59:59.000Z

    An organic rankine cycle system is combined with a vapor compression cycle system with the turbine generator of the organic rankine cycle generating the power necessary to operate the motor of the refrigerant compressor. The vapor compression cycle is applied with its evaporator cooling the inlet air into a gas turbine, and the organic rankine cycle is applied to receive heat from a gas turbine exhaust to heat its boiler within one embodiment, a common condenser is used for the organic rankine cycle and the vapor compression cycle, with a common refrigerant, R-245a being circulated within both systems. In another embodiment, the turbine driven generator has a common shaft connected to the compressor to thereby eliminate the need for a separate motor to drive the compressor. In another embodiment, an organic rankine cycle system is applied to an internal combustion engine to cool the fluids thereof, and the turbo charged air is cooled first by the organic rankine cycle system and then by an air conditioner prior to passing into the intake of the engine.

  5. In sodium tests of ultrasonic transducers

    SciTech Connect (OSTI)

    Lhuillier, C.; Descombin, O.; Baque, F. [CEA, DTN, 13108 Saint Paul lez Durance Cedex (France); Marchand, B. [CEA, LIST, 91191 Gif-sur-Yvette (France); Saillant, J. F. [AREVA/NDE Solutions, 4 rue Thomas Dumorey, 71109 Chalon sur Saone Cedex (France); Augem, J. M. [EDF, 12-14 avenue Dutrievoz, 69628 Villeurbanne (France)

    2011-07-01T23:59:59.000Z

    Ultrasonic techniques are seen as suitable candidates for the in-service inspection and for the continuous surveillance of sodium cooled reactors (SFR). These techniques need the development and the qualification of immersed ultrasonic transducers, and materials. This paper presents some developments performed by CEA (DTN and LIST) and AREVA (NDE Solutions), and some results. (authors)

  6. Gypsum and Polyacrylamide Soil Amendments Used With High Sodium Wastewater

    E-Print Network [OSTI]

    Gardiner, Duane

    Using wastewater for irrigation of crops represents an attractive alternative to disposal. Typically, municipal wastewaters are high in sodium, and the resulting high sodium absorption ratio (SAR) alters the soil structure making it more impermeable...

  7. Sodium and sulfur release and recapture during black liquor burning

    SciTech Connect (OSTI)

    Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

    1995-08-01T23:59:59.000Z

    The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

  8. Corrosion performance of advanced structural materials in sodium.

    SciTech Connect (OSTI)

    Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L. (Nuclear Engineering Division)

    2012-05-16T23:59:59.000Z

    This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

  9. Method and apparatus for concentrating vapors for analysis

    DOE Patents [OSTI]

    Grate, Jay W. (West Richland, WA); Baldwin, David L. (Kennewick, WA); Anheier, Jr., Norman C. (Richland, WA)

    2012-06-05T23:59:59.000Z

    A pre-concentration device and a method are disclosed for concentrating gaseous vapors for analysis. Vapors sorbed and concentrated within the bed of the pre-concentration device are thermally desorbed, achieving at least partial separation of the vapor mixtures. The pre-concentration device is suitable, e.g., for pre-concentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable.

  10. Chemical vapor deposition of epitaxial silicon

    DOE Patents [OSTI]

    Berkman, Samuel (Florham Park, NJ)

    1984-01-01T23:59:59.000Z

    A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

  11. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Wylie, Allan H. (Idaho Falls, ID)

    1996-01-01T23:59:59.000Z

    A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

  12. Storing images in warm atomic vapor

    E-Print Network [OSTI]

    M. Shuker; O. Firstenberg; R. Pugatch; A. Ron; N. Davidson

    2008-06-17T23:59:59.000Z

    Reversible and coherent storage of light in atomic medium is a key-stone of future quantum information applications. In this work, arbitrary two-dimensional images are slowed and stored in warm atomic vapor for up to 30 $\\mu$s, utilizing electromagnetically induced transparency. Both the intensity and the phase patterns of the optical field are maintained. The main limitation on the storage resolution and duration is found to be the diffusion of atoms. A techniqueanalogous to phase-shift lithography is employed to diminish the effect of diffusion on the visibility of the reconstructed image.

  13. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, J.M.; Wylie, A.H.

    1996-01-09T23:59:59.000Z

    A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

  14. Mercury Vapor (Kooten, 1987) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(MonasterLowellisMcDonald isMelletteEnclosed andEnergySolar SystemsVapor

  15. Review of enhanced vapor diffusion in porous media

    SciTech Connect (OSTI)

    Webb, S.W.; Ho, C.K.

    1998-08-01T23:59:59.000Z

    Vapor diffusion in porous media in the presence of its own liquid has often been treated similar to gas diffusion. The gas diffusion rate in porous media is much lower than in free space due to the presence of the porous medium and any liquid present. However, enhanced vapor diffusion has also been postulated such that the diffusion rate may approach free-space values. Existing data and models for enhanced vapor diffusion, including those in TOUGH2, are reviewed in this paper.

  16. Recovery of benzene in an organic vapor monitor

    E-Print Network [OSTI]

    Krenek, Gregory Joel

    1980-01-01T23:59:59.000Z

    solid adsorbents available (silica gel, activated alumina, etc. ), activated charcoal is most frequently utilized. Activated charcoal has retentivity for sorbed vapors several times that of silica gel and it displays a selectivity for organic vapors... (diffusion rate) of the vapor molecules to the sur- face of the adsorbent. The adsorption process determine how effective the adsorbent collects and holds the contam- inant on the surface of the activated charcoal. Recovery of the contaminant from...

  17. Vaporizer design criteria for ethanol fueled internal combustion engines

    E-Print Network [OSTI]

    Ariyaratne, Arachchi Rallage

    2012-06-07T23:59:59.000Z

    . Stout (Member) L r x ge Edwa d A. Hiler (Head of Department) May 1985 ABSTRACT Vaporizer Design Criteria For Ethanol Fueled Internal Combustion Engines. (May 1985) Arachchi Rallage Ariyaratne, B. S. , University of Sri Lanka Chairman... VAPORIZATION LENGTH WITH UNIFORM HEAT FLUX 8 POLYNOMIAL FUNCTIONS FOR EVALUATING PARAMETERS C VARIATION OF HEAT FLUX AND AVERAGE SURFACE TEMPARATURE D PROGRAM FOR PREDICTING VAPORIZATION LENGTH 73 75 78 80 VITA 87 LIST OF TABLES TABLE Page 1...

  18. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  19. Mercury Vapor At Lassen Volcanic National Park Area (Varekamp...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Lassen Volcanic National Park Area (Varekamp & Buseck, 1983) Exploration...

  20. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Roberts, K. A.; Edwards, T. B.

    2014-02-28T23:59:59.000Z

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leachability indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the l

  1. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Roberts, K. A.; Edwards, T. B.

    2013-09-17T23:59:59.000Z

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

  2. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Edwards, T. A.; Roberts, K. B.

    2013-10-02T23:59:59.000Z

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

  3. Acid/Base Recovery From Sodium Sulfate

    E-Print Network [OSTI]

    Niksa, M. J.

    escalating In price due to the Imbalance In market demand. Chlorine and caustic are produced together by the electrolysis 01 sodium chloride brine solutions. Every ECU (electrochemical unit) 01 chlorine resu~s In the production 01 one ECU 01 caustic soda... cell also produces an acid product that is contaminated with unreacted sullate. The voltage 01 a three compartment is higher, however, and the process system Is more complex. Process System Current density and efficiency determines the amount 01...

  4. The control of confined vapor phase explosions

    SciTech Connect (OSTI)

    Scilly, N.F. [Laporte plc, Widnes (United Kingdom); Owen, O.J.R. [Fine Organics, Ltd., Middlesborough (United Kingdom); Wilberforce, J.K. [Solvay SA, Brussels (Belgium)

    1995-12-31T23:59:59.000Z

    The probability of, for example, a fire or explosion occurring during a process operation is related both to the fire-related properties of the materials used, such as flash point, flammable limits etc., i.e. the material or intrinsic factors, and the nature of the operation and the equipment used, i.e. the extrinsic factors. The risk, or frequency of occurrence, of other hazards such as reaction runaway, major toxic release etc. can be determined in a similar manner. For a vapor phase explosion (and a fire) the probability of the event is the product of the probability of generating a flammable atmosphere and the probability of ignition. Firstly, materials may be coded using properties that are relevant to the hazard in question. Secondly, different operations have different degrees of risk and these risks are assigned as Low, Medium, High etc. according to criteria outlined here. Combination of these two factors will then be a measure of the overall risk of the operation with the specified material and may be used to define operating standards. Currently, the hazard/risk of a vapor phase explosions is examined by this method but in due course dust explosions, fires, condensed phase explosions, reaction runaways, physical explosions, major toxic releases and incompatibility will be included.

  5. An investigation of pinch instabilities in solid sodium plasmas

    E-Print Network [OSTI]

    Henson, Robert Maurice

    1962-01-01T23:59:59.000Z

    e ie ene nacho|9 fox ylaxxDa con~ fine+sax, X'he meehoniea hg which bhs magnexie fiel@ Czaye a ylaemo otal he szyXBinee hp conBMGFinQ G chargse yaz'iiols aov9, ng in n CFOG vezas magnslio field zi The foxes cn hhs pazhiclo io given bp hho chars q...

  6. Vapor and gas sampling of Single-Shell Tank 241-T-111 using the vapor sampling system

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-09-01T23:59:59.000Z

    This document presents sampling data resulting from the January 20, 1995, sampling of SST 241-T-111 using the vapor sampling system.

  7. Vapor and gas sampling of single-shell tank 241-BY-112 using the vapor sampling system

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-09-20T23:59:59.000Z

    This document presents sampling data from the November 18, 1994, sampling of SST 241-BY-112 using the vapor sampling system.

  8. Vapor and gas sampling of Single-Shell Tank 241-A-101 using the Vapor Sampling System

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-11-01T23:59:59.000Z

    This document presents sampling data resulting from the June 8, 1995, sampling of SST 241-A-101 using the Vapor Sampling System.

  9. Recent Sodium Technology Development for the Decommissioning of the Rapsodie and Superphenix Reactors and the Management of Sodium Wastes

    SciTech Connect (OSTI)

    Rodriguez, G.; Gastaldi, O.; Baque, F. [Commissariat a l'Energie Atomique Cadarache (France)

    2005-04-15T23:59:59.000Z

    The Commissariat a l'Energie Atomique (CEA) has recently developed and/or conducted experiments on several processes in support of the decommissioning of two French liquid-metal fast reactors (LMFRs), Rapsodie and Superphenix, as well as on the treatment of CEA sodium wastes. CEA has demonstrated that it is possible to define appropriate and efficient processes to meet the different situations encountered in decommissioning LMFRs. Mechanical techniques derived from standard technologies have been successfully applied to fast reactor decommissioning to complete primary vessel draining from sodium. In addition, specific chemical processes have been developed to deal safely with metallic sodium reactivity. Sodium-contaminated equipment has been successfully cleaned by reacting sodium with water mist in an atmosphere with carbon dioxide to form inert sodium carbonate. Bulk sodium has been successfully converted into aqueous caustic soda by injection of liquid-metallic sodium into sodium hydroxide solution. Several processes were also defined to deal with specific sodium wastes. In all cases the principle is based on a sodium/water chemical reaction where the released hydrogen and heat are controlled. With the development of a wide variety of processes, all steps in the decommissioning of LMFRs are assumed to be now properly mastered.

  10. HP Laboratories 2/8/97 Hiro:Documents:Giordano Beretta:Research:EI 97:3018-26:wwwOHP Slide 1

    E-Print Network [OSTI]

    Beretta, Giordano

    HP Laboratories 2/8/97 Hiro:Documents:Giordano Beretta:Research:EI 97:3018-26:wwwOHP Slide 1:Documents:Giordano Beretta:Research:EI 97:3018-26:wwwOHP Slide 2 2 w w w · 1990: Print-on-demand (POD) · Color POD: workflow:Documents:Giordano Beretta:Research:EI 97:3018-26:wwwOHP Slide 3 3 w w w · World Wide Web is the hot new publication medium

  11. Report on sodium compatibility of advanced structural materials.

    SciTech Connect (OSTI)

    Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T. (Nuclear Engineering Division)

    2012-07-09T23:59:59.000Z

    This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

  12. RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR

    E-Print Network [OSTI]

    Cronin, Alex D.

    RESONANT FARADAY ROTATION IN A HOT LITHIUM VAPOR By SCOTT RUSSELL WAITUKAITIS A Thesis Submitted: #12;Abstract I describe a study of Faraday rotation in a hot lithium vapor. I begin by dis- cussing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 2.3 The Lithium Oven and Solenoid . . . . . . . . . . . . . . . . . 7 3 Theoretical Framework

  13. Isotopic composition of stratospheric water vapor: Measurements and photochemistry

    E-Print Network [OSTI]

    of magnitude between the surface and the tropopause, and isotopically heavy water is pref- erentially removedIsotopic composition of stratospheric water vapor: Measurements and photochemistry David G. Johnson composition of stratospheric water vapor that result from methane oxidation and reactions with O( ¢¡ ). We

  14. Chemical vapor detection with a multispectral thermal imager

    E-Print Network [OSTI]

    Chang, Chein-I

    Chemical vapor detection with a multispectral thermal imager Mark 1. G. Aithouse, MEMBER SPIE U.S. Army Chemical Research Development and Engineering Center SMCCR-DDT Aberdeen Proving Ground, Maryland algorithm 7. Conclusions 8. Acknowledgments 9. References 1. INTRODUCTION Detection of chemical vapor clouds

  15. Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-

    E-Print Network [OSTI]

    I BNL- 62834 Informal Report . VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY-· [D VAPOR DETECTION OF TRAFFICKING OF CONTRABAND MONEY- A DISCUSSION OF TECHNICAL FEASIBILITY Concept MONEY --A DISCUSSION OF TECHNICAL FEASffiILITY Russell N. Dietz, Head Tracer Technology Center

  16. Factors contributing to the breakdown of sodium beta-alumina

    SciTech Connect (OSTI)

    Buechele, A.C.

    1982-05-01T23:59:59.000Z

    Clarification of the breakdown process occurring during charge transfer in sodium beta alumina solid electrolytes was derived from: (1) studying the effects of molten sodium contact at 350/sup 0/C on single crystal sodium beta alumina and polycrystalline sodium beta alumina; (2) determination of critical current density by monitoring acoustic emissions accompanying crack growth in sodium/sodium beta alumina/sodium cells subjected to linear current ramping at 1 mA cm/sup -2/ sec/sup -1/; (3) failure analysis conducted on cycled electrolytes, some from commercial sodium/sulfur cells, which had been subjected to up to 703 Ahr cm/sup -2/ of charge transfer. Gray coloration developing in beta aluminas in contact with molten sodium was found to be a consequence of formation, through reduction by sodium, of oxygen vacancies charge compensated by electrons. Electronic conductivity of the electrolyte increases as a result. No second phase formation was detected. Colored electrolytes from sodium/sulfur cells show evidence of a newly recognized degradation mechanism in which fracture occurs when sodium is reduced and deposited internally under pressure as metal in regions where an electronic conductivity gradient exists. Heating colored beta aluminas in air produces reoxidation and bleaching. Kinetics and other properties of the coloration and bleaching processes were determined. Critical current density was found to bear an inverse relation to average electrolyte grain size. Evidence was found in the cycled electrolytes for a slow crack growth mechanism and a progressive mode of degradation advancing from the sulfur electrode interface. Implications of the findings for the construction and operation of sodium/sulfur battery systems are discussed.

  17. Temperature dependent vapor pressures of chlorinated catechols, syringols, and syringaldehydes

    SciTech Connect (OSTI)

    Lei, Y.D.; Shiu, W.Y.; Boocock, D.G.B. [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry] [Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry; Wania, F. [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)] [WECC Wania Environmental Chemists Corp., Toronto, Ontario (Canada)

    1999-03-01T23:59:59.000Z

    The vapor pressures of nine chlorinated catechols, syringols, and syringaldehydes were determined as a function of temperature with a gas chromatographic retention time technique. The vapor pressures at 298.15 K were in the range of 0.02--1 Pa, and the enthalpies of vaporization, between 68 and 82 kJ/mol. The validity of the technique was established by a calibration involving four chlorinated phenols with well-known vapor pressures. Using these data and previously reported solubility data, Henry`s law constants for these substances and some chlorinated guaiacols and veratrols were estimated. The vapor pressure of these substances tends to decrease with increasing polarity and an increasing number of chlorine atoms. Henry`s law constants decrease sharply with increasing polarity, suggesting that methylation can result in a significant increase in a chemical`s potential for volatilization from water.

  18. Analysis of electron-beam vaporization of refractory metals

    SciTech Connect (OSTI)

    Kheshgi, H.S.; Gresho, P.M.

    1986-09-01T23:59:59.000Z

    An electron beam is focussed onto a small area on the surface of a refractory metal to locally raise the temperature and vaporize metal. At high vaporization rates the hot area is on the surface of a churning liquid-metal pool contained in a solid-metal skull which sits in a cooled crucible. Inner workings of the process are revealed by analysis of momentum, energy, and mass transfer. At the surface high temperature causes high vaporization rate and high vapor thrust, depressing the vapor/liquid surface. In the liquid pool surface-tension gradients and thermal buoyancy drive a (typically) chaotic flow. In the solid skull thermal conductivity and contact resistance regulate the rate of heat transfer from pool to crucible. Analyses of these phenomena together reveal process performance sensitivities - e.g., to depression size or to magnitude of surface-tension gradients. 12 refs., 3 figs.

  19. Chemical vapor deposition of group IIIB metals

    DOE Patents [OSTI]

    Erbil, A.

    1989-11-21T23:59:59.000Z

    Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

  20. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01T23:59:59.000Z

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  1. Hybrid Vapor Compression Adsorption System: Thermal Storage Using Hybrid Vapor Compression Adsorption System

    SciTech Connect (OSTI)

    None

    2012-01-04T23:59:59.000Z

    HEATS Project: UTRC is developing a new climate-control system for EVs that uses a hybrid vapor compression adsorption system with thermal energy storage. The targeted, closed system will use energy during the battery-charging step to recharge the thermal storage, and it will use minimal power to provide cooling or heating to the cabin during a drive cycle. The team will use a unique approach of absorbing a refrigerant on a metal salt, which will create a lightweight, high-energy-density refrigerant. This unique working pair can operate indefinitely as a traditional vapor compression heat pump using electrical energy, if desired. The project will deliver a hot-and-cold battery that provides comfort to the passengers using minimal power, substantially extending the driving range of EVs.

  2. Gas Separation Using Organic-Vapor-Resistent Membranes In Conjunctin With Organic-Vapor-Selective Membranes

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Pinnau, Ingo (Palo Alto, CA); He, Zhenjie (Fremont, CA); Da Costa, Andre R. (Menlo Park, CA); Daniels, Ramin (San Jose, CA); Amo, Karl D. (Mountain View, CA); Wijmans, Johannes G. (Menlo Park, CA)

    2003-06-03T23:59:59.000Z

    A process for treating a gas mixture containing at least an organic compound gas or vapor and a second gas, such as natural gas, refinery off-gas or air. The process uses two sequential membrane separation steps, one using membrane selective for the organic compound over the second gas, the other selective for the second gas over the organic vapor. The second-gas-selective membranes use a selective layer made from a polymer having repeating units of a fluorinated polymer, and demonstrate good resistance to plasticization by the organic components in the gas mixture under treatment, and good recovery after exposure to liquid aromatic hydrocarbons. The membrane steps can be combined in either order.

  3. M. Bahrami ENSC 461 (S 11) Vapor Power Cycles 1 Vapor Power Cycles

    E-Print Network [OSTI]

    Bahrami, Majid

    is not a suitable model for steam power cycle since: The turbine has to handle steam with low quality which steam is condensed in the condenser 4 3 1 2 s T 1 2 34 s #12;M. Bahrami ENSC 461 (S 11) Vapor Power = 0 qin = h3 ­ h2 Turbine q = 0 wturbine,out = h3 ­ h4 Condenser w = 0 qout = h4 ­ h1 The thermal

  4. HP-CAT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meeting was called1999Harvest84047&- MarchHOW

  5. E-Print Network 3.0 - aerosol-assisted chemical vapor Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Work to Prevent Chemical Warfare Agent Vapor Infiltration? John H. Sorensen Barbara M. Vogt Date... protection strategies to reduce exposure to vapors from chemical warfare...

  6. E-Print Network 3.0 - arc vapor deposition Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    has been produced... al Vaporization and melting of materials in fusion devices 325 ENERGY DEPOSITED (Jcm21 Figure 3... VAPORIZATION AND MELTING OF MATERIALS IN FUSION...

  7. E-Print Network 3.0 - atomic vapor laser Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with the exception of pagination. IEEE TRANSACTIONS ON PLASMA SCIENCE 1 Summary: vapor, atomic physics and vapor ionization, absorption reflection in a heated plasma layer, and...

  8. E-Print Network 3.0 - atom vapor cells Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rotation in the vapor cell due to inten- sity-induced birefringence in the rubidium atomic vapor. While... Super efficient absorption filter for quantum memory using atomic...

  9. Sodium fast reactor safety and licensing research plan. Volume II.

    SciTech Connect (OSTI)

    Ludewig, H. (Brokhaven National Laboratory, Upton, NY); Powers, D. A.; Hewson, John C.; LaChance, Jeffrey L.; Wright, A. (Argonne National Laboratory, Argonne, IL); Phillips, J.; Zeyen, R. (Institute for Energy Petten, Saint-Paul-lez-Durance, France); Clement, B. (IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France); Garner, Frank (Radiation Effects Consulting, Richland, WA); Walters, Leon (Advanced Reactor Concepts, Los Alamos, NM); Wright, Steve; Ott, Larry J. (Oak Ridge National Laboratory, Oak Ridge, TN); Suo-Anttila, Ahti Jorma; Denning, Richard (Ohio State University, Columbus, OH); Ohshima, Hiroyuki (Japan Atomic Energy Agency, Ibaraki, Japan); Ohno, S. (Japan Atomic Energy Agency, Ibaraki, Japan); Miyhara, S. (Japan Atomic Energy Agency, Ibaraki, Japan); Yacout, Abdellatif (Argonne National Laboratory, Argonne, IL); Farmer, M. (Argonne National Laboratory, Argonne, IL); Wade, D. (Argonne National Laboratory, Argonne, IL); Grandy, C. (Argonne National Laboratory, Argonne, IL); Schmidt, R.; Cahalen, J. (Argonne National Laboratory, Argonne, IL); Olivier, Tara Jean; Budnitz, R. (Lawrence Berkeley National Laboratory, Berkeley, CA); Tobita, Yoshiharu (Japan Atomic Energy Agency, Ibaraki, Japan); Serre, Frederic (Centre d'%C3%94etudes nucl%C3%94eaires de Cadarache, Cea, France); Natesan, Ken (Argonne National Laboratory, Argonne, IL); Carbajo, Juan J. (Oak Ridge National Laboratory, Oak Ridge, TN); Jeong, Hae-Yong (Korea Atomic Energy Research Institute, Daejeon, Korea); Wigeland, Roald (Idaho National Laboratory, Idaho Falls, ID); Corradini, Michael (University of Wisconsin-Madison, Madison, WI); Thomas, Justin (Argonne National Laboratory, Argonne, IL); Wei, Tom (Argonne National Laboratory, Argonne, IL); Sofu, Tanju (Argonne National Laboratory, Argonne, IL); Flanagan, George F. (Oak Ridge National Laboratory, Oak Ridge, TN); Bari, R. (Brokhaven National Laboratory, Upton, NY); Porter D. (Idaho National Laboratory, Idaho Falls, ID); Lambert, J. (Argonne National Laboratory, Argonne, IL); Hayes, S. (Idaho National Laboratory, Idaho Falls, ID); Sackett, J. (Idaho National Laboratory, Idaho Falls, ID); Denman, Matthew R.

    2012-05-01T23:59:59.000Z

    Expert panels comprised of subject matter experts identified at the U.S. National Laboratories (SNL, ANL, INL, ORNL, LBL, and BNL), universities (University of Wisconsin and Ohio State University), international agencies (IRSN, CEA, JAEA, KAERI, and JRC-IE) and private consultation companies (Radiation Effects Consulting) were assembled to perform a gap analysis for sodium fast reactor licensing. Expert-opinion elicitation was performed to qualitatively assess the current state of sodium fast reactor technologies. Five independent gap analyses were performed resulting in the following topical reports: (1) Accident Initiators and Sequences (i.e., Initiators/Sequences Technology Gap Analysis), (2) Sodium Technology Phenomena (i.e., Advanced Burner Reactor Sodium Technology Gap Analysis), (3) Fuels and Materials (i.e., Sodium Fast Reactor Fuels and Materials: Research Needs), (4) Source Term Characterization (i.e., Advanced Sodium Fast Reactor Accident Source Terms: Research Needs), and (5) Computer Codes and Models (i.e., Sodium Fast Reactor Gaps Analysis of Computer Codes and Models for Accident Analysis and Reactor Safety). Volume II of the Sodium Research Plan consolidates the five gap analysis reports produced by each expert panel, wherein the importance of the identified phenomena and necessities of further experimental research and code development were addressed. The findings from these five reports comprised the basis for the analysis in Sodium Fast Reactor Research Plan Volume I.

  10. Sodium cobalt bronze batteries and a method for making same

    DOE Patents [OSTI]

    Doeff, Marca M. (Hayward, CA); Ma, Yanping (Berkeley, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard (Lafayette, CA)

    1999-01-01T23:59:59.000Z

    A solid state secondary battery utilizing a low cost, environmentally sound, sodium cobalt bronze electrode. A method is provided for producing same.

  11. Sodium cobalt bronze batteries and a method for making same

    DOE Patents [OSTI]

    Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

    1999-06-29T23:59:59.000Z

    A solid state secondary battery utilizing a low cost, environmentally sound, sodium cobalt bronze electrode is described. A method is provided for producing same. 11 figs.

  12. Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup...

    Office of Environmental Management (EM)

    Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley...

  13. Efficacy of soluble sodium tripolyphosphate amendments for the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of soluble sodium tripolyphosphate amendments for the in-situ immobilisation of uranium."Environmental Chemistry 4:293-300. Authors: DM Wellman EM Pierce MM Valenta...

  14. aqueous sodium sulfate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    viscosity, 771, for PDMDAAC fractions in sodium chloride solutions by viscosity, size-exclusionchromatography, and light Dubin, Paul D. 32 Structure and Dynamics in Aqueous...

  15. Sodium dichromate expedited response action assessment

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The US Environmental Protection Agency (EPA) and Washington Department of Ecology (Ecology) recommended that the US Department of Energy (DOE) perform an expedited response action (ERA) for the Sodium Dichromate Barrel Disposal Landfill. The ERA lead regulatory agency is Ecology and EPA is the support agency. The ERA was categorized as non-time-critical, which required preparation of an engineering evaluation and cost analysis (EE/CA). The EE/CA was included in the ERA proposal. The EE/CA is a rapid, focused evaluation of available technologies using specific screening factors to assess feasibility, appropriateness, and cost. The ERA goal is to reduce the potential for any contaminant migration from the landfill to the soil column, groundwater, and Columbia River. Since the Sodium Dichromate Barrel Disposal Landfill is the only waste site within the operable unit, the removal action may be the final remediation of the 100-IU-4 Operable Unit. This ERA process started in March 1992. The ERA proposal went through a parallel review process with Westinghouse Hanford Company (WHC), DOE Richland Operations (RL), EPA, Ecology, and a 30-day public comment period. Ecology and EPA issued an Action Agreement Memorandum in March 1993 (Appendix A). The memorandum directed excavation of all anomalies and disposal of the collected materials at the Hanford Site Central Landfill. Primary field activities were completed by the end of April 1993. Final waste disposal of a minor quantity of hazardous waste was completed in July 1993.

  16. ANALYSIS OF VAPORS FROM METHYLENE CHLORIDE EXTRACTS OF NUCLEAR GRADE HEPA FILTER FIBERGLASS SAMPLES

    SciTech Connect (OSTI)

    FRYE JM; ANASTOS HL; GUTIERREZ FC

    2012-06-07T23:59:59.000Z

    While several organic compounds were detected in the vapor samples used in the reenactment of the preparation of mounts from the extracts of nuclear grade high-efficiency particulate air filter fiberglass samples, the most significant species present in the samples were methylene chloride, phenol, phenol-d6, and 2-fluorophenol. These species were all known to be present in the extracts, but were expected to have evaporated during the preparation of the mounts, as the mounts appeared to be dry before any vapor was collected. These species were present at the following percentages of their respective occupational exposure limits: methylene chloride, 2%; phenol, 0.4%; and phenol-d6, 0.6%. However, there is no established limit for 2-fluorophenol. Several other compounds were detected at low levels for which, as in the case of 2-fluorophenol, there are no established permissible exposure limits. These compounds include 2-chlorophenol; N-nitroso-1-propanamine; 2-fluoro-1,1{prime}-biphenyl; 1,2-dihydroacenaphthylene; 2,5-cyclohexadiene-1,4-dione,2,6-bis(1,1-dimethylethyl); trimethyl oxirane; n-propylpropanamine; 2-(Propylamino)ethanol; 4-methoxy-1-butene; 6-methyl-5-hepten-2-one; and 3,4-dimethylpyridine. Some of these were among those added as surrogates or spike standards as part ofthe Advanced Technologies and Laboratories International, Inc. preparation ofthe extract of the HEPA filter media and are indicated as such in the data tables in Section 2, Results; other compounds found were not previously known to be present. The main inorganic species detected (sulfate, sodium, and sulfur) are also consistent with species added in the preparation of the methylene chloride extract of the high-efficiency particulate air sample.

  17. Preliminary assessment of halogenated alkanes as vapor-phase tracers

    SciTech Connect (OSTI)

    Adams, Michael C.; Moore, Joseph N.; Hirtz, Paul

    1991-01-01T23:59:59.000Z

    New tracers are needed to evaluate the efficiency of injection strategies in vapor-dominated environments. One group of compounds that seems to meet the requirements for vapor-phase tracing are the halogenated alkanes (HCFCs). HCFCs are generally nontoxic, and extrapolation of tabulated thermodynamic data indicate that they will be thermally stable and nonreactive in a geothermal environment. The solubilities and stabilities of these compounds, which form several homologous series, vary according to the substituent ratios of fluorine, chlorine, and hydrogen. Laboratory and field tests that will further define the suitability of HCFCs as vapor-phase tracers are under way.

  18. Enhanced Attenuation Technologies: Passive Soil Vapor Extraction

    SciTech Connect (OSTI)

    Vangelas, K.; Looney, B.; Kamath, R.; Adamson, D.; Newell, C.

    2010-03-15T23:59:59.000Z

    Passive soil vapor extraction (PSVE) is an enhanced attenuation (EA) approach that removes volatile contaminants from soil. The extraction is driven by natural pressure gradients between the subsurface and atmosphere (Barometric Pumping), or by renewable sources of energy such as wind or solar power (Assisted PSVE). The technology is applicable for remediating sites with low levels of contamination and for transitioning sites from active source technologies such as active soil vapor extraction (ASVE) to natural attenuation. PSVE systems are simple to design and operate and are more cost effective than active systems in many scenarios. Thus, PSVE is often appropriate as an interim-remedial or polishing strategy. Over the past decade, PSVE has been demonstrated in the U.S. and in Europe. These demonstrations provide practical information to assist in selecting, designing and implementing the technology. These demonstrations indicate that the technology can be effective in achieving remedial objectives in a timely fashion. The keys to success include: (1) Application at sites where the residual source quantities, and associated fluxes to groundwater, are relatively low; (2) Selection of the appropriate passive energy source - barometric pumping in cases with a deep vadose zone and barrier (e.g., clay) layers that separate the subsurface from the atmosphere and renewable energy assisted PSVE in other settings and where higher flow rates are required. (3) Provision of sufficient access to the contaminated vadose zones through the spacing and number of extraction wells. This PSVE technology report provides a summary of the relevant technical background, real-world case study performance, key design and cost considerations, and a scenario-based cost evaluation. The key design and cost considerations are organized into a flowchart that dovetails with the Enhanced Attenuation: Chlorinated Organics Guidance of the Interstate Technology and Regulatory Council (ITRC). The PSVE flowchart provides a structured process to determine if the technology is, or is not, reasonable and defensible for a particular site. The central basis for that decision is the expected performance of PSVE under the site specific conditions. Will PSVE have sufficient mass removal rates to reduce the release, or flux, of contamination into the underlying groundwater so that the site can meet it overall remedial objectives? The summary technical information, case study experiences, and structured decision process provided in this 'user guide' should assist environmental decision-makers, regulators, and engineers in selecting and successfully implementing PSVE at appropriate sites.

  19. Catalytic Reactor For Oxidizing Mercury Vapor

    DOE Patents [OSTI]

    Helfritch, Dennis J. (Baltimore, MD)

    1998-07-28T23:59:59.000Z

    A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

  20. Low Level Heat Recovery Through Heat Pumps and Vapor Recompression

    E-Print Network [OSTI]

    Gilbert, J.

    1980-01-01T23:59:59.000Z

    The intent of this paper is to examine the methods and economics of recovering low level heat through heat pumps and vapor recompression. Actual commercially available equipment is considered to determine the near-term and future economic viability...

  1. Initiated chemical vapor deposition of functional polyacrylic thin films

    E-Print Network [OSTI]

    Mao, Yu, 1975-

    2005-01-01T23:59:59.000Z

    Initiated chemical vapor deposition (iCVD) was explored as a novel method for synthesis of functional polyacrylic thin films. The process introduces a peroxide initiator, which can be decomposed at low temperatures (<200?C) ...

  2. All graphene electromechanical switch fabricated by chemical vapor deposition

    E-Print Network [OSTI]

    Milaninia, Kaveh M.

    We demonstrate an electromechanical switch comprising two polycrystalline graphene films; each deposited using ambient pressure chemical vapor deposition. The top film is pulled into electrical contact with the bottom film ...

  3. Applications of Mechanical Vapor Recompression to Evaporation and Crystallization

    E-Print Network [OSTI]

    Outland, J. S.

    there is no boiler plant available or when electrical power is priced competitively in comparison to steam. Vapor recompression is accomplished using centrifugal, axial-flow, or positive displacement compressors and these compressors can be powered by electricity...

  4. Melt and vapor characteristics in an electron beam evaporator

    SciTech Connect (OSTI)

    Blumenfeld, L.; Fleche, J.L.; Gonella, C. [DCC/DPE/SPEA Centre d`Etudes de Saclay, Gif-sur-Yvette (France)

    1994-12-31T23:59:59.000Z

    We compare the free surface temperatures T{sub s}, calculated by two methods, in cerium or copper evaporation experiments. The first method considers properties of the melt: by an empirical law we take into account turbulent thermal convection, instabilities and craterization of the free surface. The second method considers the vapor flow expansion and connects T{sub s} to the measured terminal parallel temperature and the terminal mean parallel velocity of the vapor jet, by Direct Simulation Monte Carlo calculations including an atom-atom inelastic collision algorithm. The agreement between the two approaches is better for cerium than for copper in the high craterization case. The analysis, from the point of view of the properties of the melt, of the terminal parameters of the vapor jet for the high beam powers shows that T{sub s} and the Knudsen number at the vapor source reach a threshold when the beam power increases.

  5. Enabling integration of vapor-deposited polymer thin films

    E-Print Network [OSTI]

    Petruczok, Christy D. (Christy Danielle)

    2014-01-01T23:59:59.000Z

    Initiated Chemical Vapor Deposition (iCVD) is a versatile, one-step process for synthesizing conformal and functional polymer thin films on a variety of substrates. This thesis emphasizes the development of tools to further ...

  6. Hyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy

    E-Print Network [OSTI]

    Cronin, Alex D.

    the frequency of a laser with respect to an atomic spectral feature.[20] As such, saturated absorptionHyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 Broadening Mechanisms . . . . . . . . . . . . . . . . . . . . . 15 3.4 Saturated Absorption

  7. Heat transfer during film condensation of a liquid metal vapor

    E-Print Network [OSTI]

    Sukhatme, S. P.

    1964-01-01T23:59:59.000Z

    The object of this investigation is to resolve the discrepancy between theory and experiment for the case of heat transfer durirnfilm condensation of liquid metal vapors. Experiments by previous investigators have yielded ...

  8. Photoinitiated chemical vapor depostion [sic] : mechanism and applications

    E-Print Network [OSTI]

    Baxamusa, Salmaan Husain

    2009-01-01T23:59:59.000Z

    Photoinitiated chemical vapor deposition (piCVD) is developed as a simple, solventless, and rapid method for the deposition of swellable hydrogels and functional hydrogel copolymers. Mechanistic experiments show that piCVD ...

  9. Optical Precursors in Rubidium Vapor and Their Relation to Superradiance

    E-Print Network [OSTI]

    Yang, Wenlong

    2012-10-19T23:59:59.000Z

    Optical precursor is the sharp optical pulse front that does not show delay in absorptive media. In this thesis, optical precursor behavior in rubidium (Rb) vapor was investigated in the picoseconds regime. An amplified femtosecond laser was shaped...

  10. Systems and methods for generation of hydrogen peroxide vapor

    DOE Patents [OSTI]

    Love, Adam H; Eckels, Joel Del; Vu, Alexander K; Alcaraz, Armando; Reynolds, John G

    2014-12-02T23:59:59.000Z

    A system according to one embodiment includes a moisture trap for drying air; at least one of a first container and a second container; and a mechanism for at least one of: bubbling dried air from the moisture trap through a hydrogen peroxide solution in the first container for producing a hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above a hydrogen peroxide solution in the second container for producing a hydrogen peroxide vapor. A method according one embodiment includes at least one of bubbling dried air through a hydrogen peroxide solution in a container for producing a first hydrogen peroxide vapor, and passing dried air from the moisture trap into a headspace above the hydrogen peroxide solution in a container for producing a second hydrogen peroxide vapor. Additional systems and methods are also presented.

  11. Type B Accident Investigation of the Acid Vapor Inhalation on...

    Broader source: Energy.gov (indexed) [DOE]

    2005, in TA-48, Building RC-1 Room 402 at the Los Alamos National Laboratory Type B Accident Investigation of the Acid Vapor Inhalation on June 7, 2005, in TA-48, Building RC-1...

  12. RESEARCH Open Access Half-molar sodium lactate infusion improves

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RESEARCH Open Access Half-molar sodium lactate infusion improves cardiac performance in acute heart for the myocardium at rest and during stress. We tested the effects of half-molar sodium lactate infusion on cardiac by 1 ml/kg/h continuous infusion for 24 hours. The control group received only a 3 ml/kg bolus

  13. Mercury exosphere I. Global circulation model of its sodium component

    E-Print Network [OSTI]

    Johnson, Robert E.

    Mercury exosphere I. Global circulation model of its sodium component Francois Leblanc a,*, R 2010 Accepted 27 April 2010 Available online 5 May 2010 Keywords: Mercury, Atmosphere Aeronomy a b s t r a c t Our understanding of Mercury's sodium exosphere has improved considerably in the last 5

  14. A Near-Infrared Photometric Study of the Low Latitude Globular Clusters Liller 1, Djorgovski 1, HP 1, and NGC 6528

    E-Print Network [OSTI]

    T. J. Davidge

    1999-09-23T23:59:59.000Z

    Images recorded through J, H, Ks, 2.2 micron continuum, and 2.3 micron CO filters are used to investigate the stellar contents of the low Galactic latitude globular clusters NGC 6528, Liller 1, Djorgovski 1, and HP 1, as well as surrounding bulge fields. Metallicities are estimated for the latter three clusters by comparing the colors and CO indices of giant branch stars with those in other clusters and the bulge, while reddenings are estimated from the colors of bright bulge stars in the surrounding fields. In some cases the metallicities and reddenings are significantly different from previous estimates.

  15. Low temperature sodium-beta battery

    DOE Patents [OSTI]

    Farmer, Joseph C

    2013-11-19T23:59:59.000Z

    A battery that will operate at ambient temperature or lower includes an enclosure, a current collector within the enclosure, an anode that will operate at ambient temperature or lower within the enclosure, a cathode that will operate at ambient temperature or lower within the enclosure, and a separator and electrolyte within the enclosure between the anode and the cathode. The anode is a sodium eutectic anode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower. The cathode is a low melting ion liquid cathode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower.

  16. Advanced Chemical Heat Pumps Using Liquid-Vapor Reactions

    E-Print Network [OSTI]

    Kirol, L.

    ically feasible systems have significant potential advantage over conventional tech nology. An electric drive reactive heat pump can use smaller heat exchangers and compressor than a vapor-compression machine, and have more flexible operating... are discussed, and performance is bounded. A discussion on liquid-vapor equilibria is included as introduction to the systems I- considered. The electric drive heat pump and TA are promising systems; the TA has potential for higher COP than absorption...

  17. Injection locked oscillator system for pulsed metal vapor lasers

    DOE Patents [OSTI]

    Warner, Bruce E. (Livermore, CA); Ault, Earl R. (Dublin, CA)

    1988-01-01T23:59:59.000Z

    An injection locked oscillator system for pulsed metal vapor lasers is disclosed. The invention includes the combination of a seeding oscillator with an injection locked oscillator (ILO) for improving the quality, particularly the intensity, of an output laser beam pulse. The present invention includes means for matching the first seeder laser pulses from the seeding oscillator to second laser pulses of a metal vapor laser to improve the quality, and particularly the intensity, of the output laser beam pulse.

  18. The development of a passive dosimeter for airborne benzene vapors

    E-Print Network [OSTI]

    Hager, David William

    2012-06-07T23:59:59.000Z

    entirely different from that usually employed in gas or vapor collection devices, as there is no need for pumps and airflow control s to provi de fi xed airflows or volumes. This principle, Ficks First Law of Diffusion, states tha t the rate of transfer...+ Ilay 1978 ABSTRACT The Development of a Passive Dosimeter for Airborne Benzene Vapor. ", . (Nay 1978) David Hilliam Hager, B. S. , University of Rochester; Chairman of Advisory Committee: Dr. David F. Ciapo Passive diffusion dosimeters offer...

  19. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cadeddu, Maria

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  20. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  1. Theoretical Adiabatic Temperature and Chemical Composition of Sodium Combustion Flame

    SciTech Connect (OSTI)

    Okano, Yasushi; Yamaguchi, Akira [O-arai Engineering Center (Japan)

    2003-12-15T23:59:59.000Z

    Sodium fire safety analysis requires fundamental combustion properties, e.g., heat of combustion, flame temperature, and composition. We developed the GENESYS code for a theoretical investigation of sodium combustion flame.Our principle conclusions on sodium combustion under atmospheric air conditions are (a) the maximum theoretical flame temperature is 1950 K, and it is not affected by the presence of moisture; the uppermost limiting factor is the chemical instability of the condensed sodium-oxide products under high temperature; (b) the main combustion product is liquid Na{sub 2}O in dry air condition and liquid Na{sub 2}O with gaseous NaOH in moist air; and (c) the chemical equilibrium prediction of the residual gaseous reactants in the flame is indispensable for sodium combustion modeling.

  2. Calcium and sodium bentonite for hydraulic containment applications

    SciTech Connect (OSTI)

    Gleason, M.H. [GeoSyntec Consultants, Columbia, MD (United States); Daniel, D.E. [Univ. of Illinois, Urbana, IL (United States). Dept. of Civil Engineering; Eykholt, G.R. [Univ. of Wisconsin, Madison, WI (United States). Dept. of Civil Engineering

    1997-05-01T23:59:59.000Z

    The hydraulic conductivity of calcium and sodium bentonites was investigated for sand-bentonite mixtures, a thin bentonite layer simulating a geosynthetic clay liner (GCL), and bentonite-cement mixtures simulating backfill for a vertical cutoff wall. The permeant liquids were tap water and distilled water containing 0.25 M calcium chloride. In general, the hydraulic performance of calcium bentonite was not significantly better than the performance of sodium bentonite for either the clay-amended sand or the GCL application, and was substantially worse than the performance of sodium bentonite in the bentonite-cement mixture. A drained angle of internal friction of 21{degree} was measured for calcium bentonite, compared to 10{degree} for sodium bentonite. Except for a larger drained shear strength, no advantage of calcium bentonite over sodium bentonite could be identified from the results of this study.

  3. Tank Vapor Characterization Project: Annual status report for FY 1996

    SciTech Connect (OSTI)

    Silvers, K.L.; Fruchter, J.S.; Huckaby, J.L.; Almeida, T.L.; Evans, J.C. Jr.; Pool, K.H.; Simonen, C.A.; Thornton, B.M.

    1997-01-01T23:59:59.000Z

    In Fiscal Year 1996, staff at the Vapor Analytical Laboratory at Pacific Northwest National Laboratory performed work in support of characterizing the vapor composition of the headspaces of radioactive waste tanks at the Hanford Site. Work performed included support for technical issues and sampling methodologies, upgrades for analytical equipment, analytical method development, preparation of unexposed samples, analyses of tank headspaces samples, preparation of data reports, and operation of the tank vapor database. Progress made in FY 1996 included completion and issuance of 50 analytical data reports. A sampling system comparison study was initiated and completed during the fiscal year. The comparison study involved the vapor sampling system (VSS), a truck-based system, and the in situ vapor sampling system (ISVS), a cart-based system. Samples collected during the study were characterized for inorganic, permanent gases, total non-methane organic compounds and organic speciation by SUMMA{trademark} and TST methods. The study showed comparable sampling results between the systems resulting in the program switching from the VSS to the less expensive ISVS methodology in late May 1996. A temporal study was initiated in January 1996 in order to understand the influences seasonal temperatures changes have on the vapors in the headspace of Hanford waste tanks. A holding time study was initiated in the fourth quarter of FY 1996. Samples were collected from tank S-102 and rushed to the laboratory for time zero analysis. Additional samples will be analyzed at 1, 2, 4, 8, 16, and 32 weeks.

  4. Decommissioning of Experimental Breeder Reactor - II Complex, Post Sodium Draining

    SciTech Connect (OSTI)

    J. A. (Bart) Michelbacher; S. Paul Henslee; Collin J. Knight; Steven R. sherman

    2005-09-01T23:59:59.000Z

    The Experimental Breeder Reactor - II (EBR-II) was shutdown in September 1994 as mandated by the United States Department of Energy. This sodium-cooled reactor had been in service since 1964. The bulk sodium was drained from the primary and secondary systems and processed. Residual sodium remaining in the systems after draining was converted into sodium bicarbonate using humid carbon dioxide. This technique was tested at Argonne National Laboratory in Illinois under controlled conditions, then demonstrated on a larger scale by treating residual sodium within the EBR-II secondary cooling system, followed by the primary tank. This process, terminated in 2002, was used to place a layer of sodium bicarbonate over all exposed surfaces of sodium. Treatment of the remaining EBR-II sodium is governed by the Resource Conservation and Recovery Act (RCRA). The Idaho Department of Environmental Quality issued a RCRA Operating Permit in 2002, mandating that all hazardous materials be removed from EBR-II within a 10 year period, with the ability to extend the permit and treatment period for another 10 years. A preliminary plan has been formulated to remove the remaining sodium and NaK from the primary and secondary systems using moist carbon dioxide, steam and nitrogen, and a water flush. The moist carbon dioxide treatment was resumed in May 2004. As of August 2005, approximately 60% of the residual sodium within the EBR-II primary tank had been treated. This process will continue through the end of 2005, when it is forecast that the process will become increasingly ineffective. At that time, subsequent treatment processes will be planned and initiated. It should be noted that the processes and anticipated costs associated with these processes are preliminary. Detailed engineering has not been performed, and approval for these methods has not been obtained from the regulator or the sponsors.

  5. Sodium reflux pool-boiler solar receiver on-sun test results

    SciTech Connect (OSTI)

    Andraka, C E; Moreno, J B; Diver, R B; Moss, T A [Oak Ridge National Lab., TN (United States)] [Oak Ridge National Lab., TN (United States)

    1992-06-01T23:59:59.000Z

    The efficient operation of a Stirling engine requires the application of a high heat flux to the relatively small area occupied by the heater head tubes. Previous attempts to couple solar energy to Stirling engines generally involved directly illuminating the heater head tubes with concentrated sunlight. In this study, operation of a 75-kW{sub t} sodium reflux pool-boiler solar receiver has been demonstrated and its performance characterized on Sandia's nominal 75-kW{sub t} parabolic-dish concentrator, using a cold-water gas-gap calorimeter to simulate Stirling engine operation. The pool boiler (and more generally liquid-metal reflux receivers) supplies heat to the engine in the form of latent heat released from condensation of the metal vapor on the heater head tubes. The advantages of the pool boiler include uniform tube temperature, leading to longer life and higher temperature available to the engine, and decoupling of the design of the solar absorber from the engine heater head. The two-phase system allows high input thermal flux, reducing the receiver size and losses, therefore improving system efficiency. The receiver thermal efficiency was about 90% when operated at full power and 800{degree}C. Stable sodium boiling was promoted by the addition of 35 equally spaced artificial cavities in the wetted absorber surface. High incipient boiling superheats following cloud transients were suppressed passively by the addition of small amounts of xenon gas to the receiver volume. Stable boiling without excessive incipient boiling superheats was observed under all operating conditions. The receiver developed a leak during performance evaluation, terminating the testing after accumulating about 50 hours on sun. The receiver design is reported here along with test results including transient operations, steady-state performance evaluation, operation at various temperatures, infrared thermography, x-ray studies of the boiling behavior, and a postmortem analysis.

  6. Synthesis, structure refinement at 296 K and physico-chemical characterizations of KMnHP{sub 3}O{sub 10}

    SciTech Connect (OSTI)

    Mechergui, J. [Chemistry Department, Bizerta Science Faculty, 7021 Jarzouna, Bizerta (Tunisia); Belam, W. [Chemistry Department, Bizerta Science Faculty, 7021 Jarzouna, Bizerta (Tunisia)], E-mail: WahidBelam@yahoo.fr

    2008-12-01T23:59:59.000Z

    Potassium manganese(III) monohydrogentriphosphate KMnHP{sub 3}O{sub 10} was synthesized by flux method and characterized by single-crystal X-ray diffraction, crystallizes in the monoclinic system with centric space group C2/c. The parameters of the unit cell are a = 12.104(1), b = 8.287(1). c = 9.150(1) A, {beta} = 110.97(1) deg. and Z = 4. The structure was solved at 296 K using 893 independent reflections and refined until R(F) = 0.022; wR(F{sup 2}) = 0.045. The atomic arrangement of the title compound consists of MnO{sub 6} octahedra linked by hydrogentriphosphate anions to form a three-dimensional framework containing tunnels parallel to the c-axis where the K{sup +} cations are inserted. The structure of KMnHP{sub 3}O{sub 10} contains a single Mn site which is surrounded by typical Jahn-Teller [2 + 2 + 2] distorted octahedron. The title material has been also characterized by different physico-chemical techniques: powder X-ray diffraction, IR, NMR and CI spectroscopies and DTA-TGA-DSC thermal analysis.

  7. E-Print Network 3.0 - acetate sodium lactate Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sodium-high lactate infusion'. Of course, it is easy to demonstrate that high lactate infusion... . Also, sodium-lactate infusion in humans ... Source: Ecole Polytechnique, Centre...

  8. E-Print Network 3.0 - advanced fast sodium Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sodium in the PFBR). The same initiating events occurring in both thermal and fast reactors could produce... specifications of demonstration fast reactors.* Thermal Sodium void...

  9. Experimental investigations on sodium plugging in narrow flow channels.

    SciTech Connect (OSTI)

    Momozaki, Y.; Cho, D. H.; Sienicki, J. J.; Moisseytsev, A.; Nuclear Engineering Division

    2010-08-01T23:59:59.000Z

    A series of experiments was performed to investigate the potential for plugging of narrow flow channels of sodium by impurities (e.g., oxides). In the first phase of the experiments, clean sodium was circulated through the test sections simulating flow channels in a compact diffusion-bonded heat exchanger such as a printed circuit heat exchanger. The primary objective was to see if small channels whose cross sections are semicircles of 2, 4, and 6 mm in diameter are usable in liquid sodium applications where sodium purity is carefully controlled. It was concluded that the 2-mm channels, the smallest of the three, could be used in clean sodium systems at temperatures even as low as 100 to 110 C without plugging. In the second phase, sodium oxide was added to the loop, and the oxygen concentration in the liquid sodium was controlled by means of varying the cold-trap temperature. Intentional plugging was induced by creating a cold spot in the test sections, and the subsequent plugging behavior was observed. It was found that plugging in the 2-mm test section was initiated by lowering the cold spot temperature below the cold-trap temperature by 10 to 30 C. Unplugging of the plugged channels was accomplished by heating the affected test section.

  10. Risk Management for Sodium Fast Reactors.

    SciTech Connect (OSTI)

    Denman, Matthew R; Groth, Katrina; Cardoni, Jeffrey N; Wheeler, Timothy A.

    2015-01-01T23:59:59.000Z

    Accident management is an important component to maintaining risk at acceptable levels for all complex systems, such as nuclear power plants. With the introduction of self - correcting, or inherently safe, reactor designs the focus has shifted from management by operators to allowing the syste m's design to manage the accident. While inherently and passively safe designs are laudable, extreme boundary conditions can interfere with the design attributes which facilitate inherent safety , thus resulting in unanticipated and undesirable end states. This report examines an inherently safe and small sodium fast reactor experiencing a beyond design basis seismic event with the intend of exploring two issues : (1) can human intervention either improve or worsen the potential end states and (2) can a Bayes ian Network be constructed to infer the state of the reactor to inform (1). ACKNOWLEDGEMENTS The author s would like to acknowledge the U.S. Department of E nergy's Office of Nuclear Energy for funding this research through Work Package SR - 14SN100303 under the Advanced Reactor Concepts program. The authors also acknowledge the PRA teams at A rgonne N ational L aborator y , O ak R idge N ational L aborator y , and I daho N ational L aborator y for their continue d contributions to the advanced reactor PRA mission area.

  11. Sodium Bearing Waste Processing Alternatives Analysis

    SciTech Connect (OSTI)

    Murphy, James Anthony; Palmer, Brent J; Perry, Keith Joseph

    2003-12-01T23:59:59.000Z

    A multidisciplinary team gathered to develop a BBWI recommendation to DOE-ID on the processing alternatives for the sodium bearing waste in the INTEC Tank Farm. Numerous alternatives were analyzed using a rigorous, systematic approach. The data gathered were evaluated through internal and external peer reviews for consistency and validity. Three alternatives were identified to be top performers: Risk-based Calcination, MACT to WIPP Calcination and Cesium Ion Exchange. A dual-path through early Conceptual design is recommended for MACT to WIPP Calcination and Cesium Ion Exchange since Risk-based Calcination does not require design. If calcination alternatives are not considered based on giving Type of Processing criteria significantly greater weight, the CsIX/TRUEX alternative follows CsIX in ranking. However, since CsIX/TRUEX shares common uncertainties with CsIX, reasonable backups, which follow in ranking, are the TRUEX and UNEX alternatives. Key uncertainties must be evaluated by the decision-makers to choose one final alternative. Those key uncertainties and a path forward for the technology roadmapping of these alternatives is provided.

  12. Vapor etching of nuclear tracks in dielectric materials

    DOE Patents [OSTI]

    Musket, Ronald G. (Danville, CA); Porter, John D. (Berkeley, CA); Yoshiyama, James M. (Fremont, CA); Contolini, Robert J. (Lake Oswego, OR)

    2000-01-01T23:59:59.000Z

    A process involving vapor etching of nuclear tracks in dielectric materials for creating high aspect ratio (i.e., length much greater than diameter), isolated cylindrical holes in dielectric materials that have been exposed to high-energy atomic particles. The process includes cleaning the surface of the tracked material and exposing the cleaned surface to a vapor of a suitable etchant. Independent control of the temperatures of the vapor and the tracked materials provide the means to vary separately the etch rates for the latent track region and the non-tracked material. As a rule, the tracked regions etch at a greater rate than the non-tracked regions. In addition, the vapor-etched holes can be enlarged and smoothed by subsequent dipping in a liquid etchant. The 20-1000 nm diameter holes resulting from the vapor etching process can be useful as molds for electroplating nanometer-sized filaments, etching gate cavities for deposition of nano-cones, developing high-aspect ratio holes in trackable resists, and as filters for a variety of molecular-sized particles in virtually any liquid or gas by selecting the dielectric material that is compatible with the liquid or gas of interest.

  13. Sodium bromide electron-extraction layers for polymer bulk-heterojunction solar cells

    SciTech Connect (OSTI)

    Gao, Zhi; Qu, Bo, E-mail: bqu@pku.edu.cn; Xiao, Lixin; Chen, Zhijian [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China) [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); New Display Device and System Integration Collaborative Innovation Center of the West Coast of the Taiwan Strait, Fuzhou 350002 (China); Zhang, Lipei [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China)] [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); Gong, Qihuang [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China) [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100871 (China)

    2014-03-10T23:59:59.000Z

    Inexpensive and non-toxic sodium bromide (NaBr) was introduced into polymer solar cells (PSCs) as the cathode buffer layer (CBL) and the electron extraction characteristics of the NaBr CBL were investigated in detail. The PSCs based on NaBr CBL with different thicknesses (i.e., 0?nm, 0.5?nm, 1?nm, and 1.5?nm) were prepared and studied. The optimal thickness of NaBr was 1?nm according to the photovoltaic data of PSCs. The open-circuit voltage (V{sub oc}), short-circuit current density (J{sub sc}), fill factor (FF), and power conversion efficiency (PCE) of the PSC with 1?nm NaBr were evaluated to be 0.58?V, 7.36?mA/cm{sup 2}, 0.63, and 2.70%, respectively, which were comparable to those of the reference device with the commonly used LiF. The optimized photovoltaic performance of PSC with 1?nm NaBr was ascribed to the improved electron transport and extraction capability of 1?nm NaBr in PSCs. In addition, the NaBr CBL could prevent the diffusion of oxygen and water vapor into the active layer and prolong the lifetime of the devices to some extent. Therefore, NaBr layer could be considered as a promising non-toxic CBL for PSCs in future.

  14. Loop simulation capability for sodium-cooled systems

    E-Print Network [OSTI]

    Adekugbe, Oluwole A.

    1984-01-01T23:59:59.000Z

    A one-dimensional loop simulation capability has been implemented in the thermal-hydraulic analysis code, THERMIT-4E. This code had been used to simulate and investigate flow in test sections of experimental sodium loops ...

  15. aged sodium borophosphate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ultraviolet flux will produce a similar variation in the column of neutral sodium for a fixed mass flux and density. However, if the cold gas is in pressure equilibrium with a hot...

  16. aqueous sodium chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 58 Systematic...

  17. Reactor protection system design alternatives for sodium fast reactors

    E-Print Network [OSTI]

    DeWitte, Jacob D. (Jacob Dominic)

    2011-01-01T23:59:59.000Z

    Historically, unprotected transients have been viewed as design basis events that can significantly challenge sodium-cooled fast reactors. The perceived potential consequences of a severe unprotected transient in a ...

  18. Probabilistic transient analysis of fuel choices for sodium fast reactors

    E-Print Network [OSTI]

    Denman, Matthew R

    2011-01-01T23:59:59.000Z

    This thesis presents the implications of using a risk-informed licensing framework to inform the design of Sodium Fast Reactors. NUREG-1860, more commonly known as the Technology Neutral Framework (TNF), is a risk-informed ...

  19. SLAM: a sodium-limestone concrete ablation model

    SciTech Connect (OSTI)

    Suo-Anttila, A.J.

    1983-12-01T23:59:59.000Z

    SLAM is a three-region model, containing a pool (sodium and reaction debris) region, a dry (boundary layer and dehydrated concrete) region, and a wet (hydrated concrete) region. The model includes a solution to the mass, momentum, and energy equations in each region. A chemical kinetics model is included to provide heat sources due to chemical reactions between the sodium and the concrete. Both isolated model as well as integrated whole code evaluations have been made with good results. The chemical kinetics and water migration models were evaluated separately, with good results. Several small and large-scale sodium limestone concrete experiments were simulated with reasonable agreement between SLAM and the experimental results. The SLAM code was applied to investigate the effects of mixing, pool temperature, pool depth and fluidization. All these phenomena were found to be of significance in the predicted response of the sodium concrete interaction. Pool fluidization is predicted to be the most important variable in large scale interactions.

  20. Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applicatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B Schwenzer, J Xiao, Z Nie, LV Saraf, Z Yang, and J Liu.2012."Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications."Nano Letters 12(7):37833787....

  1. Interactions between Liquid-Wall Vapor and Edge Plasmas

    SciTech Connect (OSTI)

    Rognlien, T D; Rensink, M E

    2000-05-25T23:59:59.000Z

    The use of liquid walls for fusion reactors could help solve problems associated with material erosion from high plasma heat-loads and neutronic activation of structures. A key issue analyzed here is the influx of impurity ions to the core plasma from the vapor of liquid side-walls. Numerical 2D transport simulations are performed for a slab geometry which approximates the edge region of a reactor-size tokamak. Both lithium vapor (from Li or SnLi walls) and fluorine vapor (from Flibe walls) are considered for hydrogen edge-plasmas in the high- and low-recycling regimes. It is found that the minimum influx is from lithium with a low-recycling hydrogen plasma, and the maximum influx occurs for fluorine with a high-recycling hydrogen plasma.

  2. VAPORIZATION OF TUNGSTEN-METAL IN STEAM AT HIGH TEMPERATURES.

    SciTech Connect (OSTI)

    GREENE,G.A.; FINFROCK,C.C.

    2000-10-01T23:59:59.000Z

    The vaporization of tungsten from the APT spallation target dominates the radiological source term for unmitigated target overheating accidents. Chemical reactions of tungsten with steam which persist to tungsten temperatures as low as 800 C result in the formation of a hydrated tungsten-oxide which has a high vapor pressure and is readily convected in a flowing atmosphere. This low-temperature vaporization reaction essentially removes the oxide film that forms on the tungsten-metal surface as soon as it forms, leaving behind a fresh metallic surface for continued oxidation and vaporization. Experiments were conducted to measure the oxidative vaporization rates of tungsten in steam as part of the effort to quantify the MT radiological source term for severe target accidents. Tests were conducted with tungsten rods (1/8 inch diameter, six inches long) heated to temperatures from approximately 700 C to 1350 C in flowing steam which was superheated to 140 C. A total of 19 experiments was conducted. Fifteen tests were conducted by RF induction heating of single tungsten rods held vertical in a quartz glass retort. Four tests were conducted in a vertically-mounted tube furnace for the low temperature range of the test series. The aerosol which was generated and transported downstream from the tungsten rods was collected by passing the discharged steam through a condenser. This procedure insured total collection of the steam along with the aerosol from the vaporization of the rods. The results of these experiments revealed a threshold temperature for tungsten vaporization in steam. For the two tests at the lowest temperatures which were tested, approximately 700 C, the tungsten rods were observed to oxidize without vaporization. The remainder of the tests was conducted over the temperature range of 800 C to 1350 C. In these tests, the rods were found to have lost weight due to vaporization of the tungsten and the missing weight was collected in the downstream condensate system. The aerosol formed a fine white smoke of tungsten-oxide which was visible to the eye as it condensed in the laminar boundary layer of steam which flowed along the surface of the rod. The aerosol continued to flow as a smoke tube downstream of the rod, flowing coaxially along the centerline axis of the quartz glass tube and depositing by impaction along the outside of a bend and at sudden area contractions in the piping. The vaporization rate data from the 17 experiments which exceeded the vaporization threshold temperature are shown in Figure 5 in the form of vaporization rates (g/cm{sup 2} s) vs. inverse temperature (K{sup {minus}1}). Two correlations to the present data are presented and compared to a published correlation by Kilpatrick and Lott. The differences are discussed.

  3. Evaluation and prevention of explosions in soil vapor extraction systems

    SciTech Connect (OSTI)

    Hower, J.W. [Radian Corp., El Segundo, CA (United States)

    1995-12-31T23:59:59.000Z

    Due to the widespread and long term use of petroleum derived fuels and solvents, many areas have subsurface soils contaminated with petroleum derivatives. This contamination can migrate to groundwater, which is frequently used to supply drinking water needs. A common method of cleaning up that contamination is soil vapor extraction (SVE). SVE is a technique where several extraction wells are installed in the contaminated area, with screens in the appropriate vertical locations. The soil vapors re extracted form the wells using a positive displacement blower. To prevent this subsurface contamination from becoming air pollution, the extracted vapors are then sent to some hydrocarbon removal device, such as a carbon adsorption system or a thermal oxidizer. The data used in this investigation were collected as part of a Radian Corporation project for a client. The site is a former petroleum refinery, and the hydrocarbons are primarily gasoline and diesel.

  4. The Salt or Sodium Chloride Content of Feeds

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

    1920-01-01T23:59:59.000Z

    of Sodium Chloride.--In order to test the recovery of added salt, several molasses feeds were selected, weighed out, and varying amounts of salt added, in the form of a N/10 solution of sodium chloride. The salt was added hy a different person from... ............................... . . Preliminary ~vork on laboratory methocls ........ . . ............................... Laboratory method adopted.. ............................. Tests of the laboratory niethod. ................... Application of the methold to feed mixtures...

  5. Liquid-phase compositions from vapor-phase analyses

    SciTech Connect (OSTI)

    Davis, W. Jr. (Oak Ridge Gaseous Diffusion Plant, TN (USA)); Cochran, H.D. (Oak Ridge National Lab., TN (USA))

    1990-02-01T23:59:59.000Z

    Arsenic normally is not considered to be a contaminant. However, because arsenic was found in many cylinders of UF{sub 6}, including in corrosion products, a study was performed of the distribution of the two arsenic fluorides, AsF{sub 3} and AsF{sub 5}, between liquid and vapor phases. The results of the study pertain to condensation or vaporization of liquid UF{sub 6}. This study includes use of various experimental data plus many extrapolations necessitated by the meagerness of the experimental data. The results of this study provide additional support for the vapor-liquid equilibrium model of J.M. Prausnitz and his coworkers as a means of describing the distribution of various impurities between vapor and liquid phases of UF{sub 6}. Thus, it is concluded that AsF{sub 3} will tend to concentrate in the liquid phase but that the concentration of AsF{sub 5} in the vapor phase will exceed its liquid-phase concentration by a factor of about 7.5, which is in agreement with experimental data. Because the weight of the liquid phase in a condensation operation may be in the range of thousands of times that of the vapor phase, most of any AsF{sub 5} will be in the liquid phase in spite of this separation factor of 7.5. It may also be concluded that any arsenic fluorides fed into a uranium isotope separation plant will either travel with other low-molecular-weight gases or react with materials present in the plant. 25 refs., 3 figs., 6 tabs.

  6. Advanced sodium fast reactor accident source terms : research needs.

    SciTech Connect (OSTI)

    Powers, Dana Auburn; Clement, Bernard [IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France; Denning, Richard [Ohio State University, Columbus, OH; Ohno, Shuji [Japan Atomic Energy Agency, Ibaraki, Japan; Zeyen, Roland [Institute for Energy Petten, Saint-Paul-lez-Durance, France

    2010-09-01T23:59:59.000Z

    An expert opinion elicitation has been used to evaluate phenomena that could affect releases of radionuclides during accidents at sodium-cooled fast reactors. The intent was to identify research needed to develop a mechanistic model of radionuclide release for licensing and risk assessment purposes. Experts from the USA, France, the European Union, and Japan identified phenomena that could affect the release of radionuclides under hypothesized accident conditions. They qualitatively evaluated the importance of these phenomena and the need for additional experimental research. The experts identified seven phenomena that are of high importance and have a high need for additional experimental research: High temperature release of radionuclides from fuel during an energetic eventEnergetic interactions between molten reactor fuel and sodium coolant and associated transfer of radionuclides from the fuel to the coolantEntrainment of fuel and sodium bond material during the depressurization of a fuel rod with breached claddingRates of radionuclide leaching from fuel by liquid sodiumSurface enrichment of sodium pools by dissolved and suspended radionuclidesThermal decomposition of sodium iodide in the containment atmosphereReactions of iodine species in the containment to form volatile organic iodides. Other issues of high importance were identified that might merit further research as development of the mechanistic model of radionuclide release progressed.

  7. Classification : Original Article VOLTAGE-GATED SODIUM CHANNELS POTENTIATE THE INVASIVE

    E-Print Network [OSTI]

    Boyer, Edmond

    - gated sodium channels in non-small-cell lung cancer cell lines. Functional voltage-gated sodium channels cancerous cell lines H23, H460 and Calu-1 possess functional sodium channels while normal and weakly metastatic cell lines do not. While all the cell lines expressed mRNA for numerous sodium channel isoforms

  8. Method of and apparatus for removing silicon from a high temperature sodium coolant

    DOE Patents [OSTI]

    Yunker, Wayne H. (Richland, WA); Christiansen, David W. (Kennewick, WA)

    1987-01-01T23:59:59.000Z

    A method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

  9. Balance of atmospheric water vapor over the Gulf of Mexico

    E-Print Network [OSTI]

    Hughes, Ralph Morgan

    1967-01-01T23:59:59.000Z

    / / / / I / o. i + B CAP C BBJ V S TPA PZA EHA Fig. 5. Vertical distribution of the average water-vapor flux normal to the perimeter of the Gulf of Nexico during Oct-Kov-Dec 1959. Plus values are inflow in kgm/sec-mb-. m. -o-I Pi C4 I / ~-o, i...BALANCE OF ATMOSPHERIC HATER VAPOR OVER THE GULF OF MEXICO A Thesis By RALPH MORGAN HUGHES Captain, USAF Submitted to the Graduate College of the Texas A&M University in partial fulf-'llment of the rec;uirements for the degree of MASTER...

  10. Phase effects for electrons in liquid water and water vapor

    SciTech Connect (OSTI)

    Turner, J.E.; Paretzke, H.G.; Wright, H.A.; Hamm, R.N.; Ritchie, R.H.

    1988-01-01T23:59:59.000Z

    The objective of these studies is to compare transport, energy loss, and other phenomena for electrons in water in the liquid and vapor phases. Understanding the differences and similarities is an interesting physics problem in its own right. It is also important for applying the relatively large body of experimental data available for the vapor to the liquid, which is of greater relevance in radiobiology. This paper presents a summary of results from a series of collaborative studies carried out by the authors at Oak Ridge National Laboratory (ORNL) and the Gesellschaft fuer Strahlen- und Umweltforschung (GSF). 14 figs.

  11. The development of a passive dosimeter for airborne aniline vapors

    E-Print Network [OSTI]

    Campbell, James Evan

    1977-01-01T23:59:59.000Z

    passive sampl1ng dosimeter was designed to measure concen- trat1ons of aniline vapor in air. Diffus1on tubes of 1. 5, 3. 0 and 4. 5 cm lengths were tested under controlled conditions of relative humid1ty, air temperature and vapor concentrations. A... of Measured vs Calculated Concentrations APPENDIX D-Student-t Test on Slopes of Measured vs Calculated Data . APPENDIX E-Statistical Analysis of Four Hour Time- Weighted Average Study on 3. 0 cm Dosimeter VITA ~pa e 42 45 48 59 62 63 65 70 73...

  12. Amine functionalization by initiated chemical vapor deposition (iCVD) for interfacial adhesion and film cohesion

    E-Print Network [OSTI]

    Xu, Jingjing, Ph. D. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    Amine functional polymer thin films provide a versatile platform for subsequent functionalization because of their diverse reactivity. Initiated chemical vapor deposition (iCVD) is a polymer chemical vapor deposition ...

  13. Chemical vapor deposition thin films as biopassivation coatings and directly patternable dielectrics

    E-Print Network [OSTI]

    Pryce Lewis, Hilton G. (Hilton Gavin), 1973-

    2001-01-01T23:59:59.000Z

    Organosilicon thin films deposited by pulsed plasma-enhanced chemical vapor deposition (PPECVD) and hot-filament chemical vapor deposition (HFCVD) were investigated as potential biopassivation coatings for neural probes. ...

  14. Metalorganic chemical vapor deposition of carbon-free ZnO using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metalorganic chemical vapor deposition of carbon-free ZnO using the bis(2,2,6,6-tetramethyl-3,5-heptanedionato)zinc precursor. Metalorganic chemical vapor deposition of carbon-free...

  15. Heat transfer during film condensation of potassium vapor on a horizontal plate

    E-Print Network [OSTI]

    Meyrial, Paul M.

    1968-01-01T23:59:59.000Z

    The object of the investigation is to analyze the following two features of heat transfer during condensation of potassium vapor: a. Heat transfer during film condensation of a pure saturated potassium vapor on a horizontal ...

  16. E-Print Network 3.0 - airs water vapor Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    water vapor Search Powered by Explorit Topic List Advanced Search Sample search results for: airs water vapor Page: << < 1 2 3 4 5 > >> 1 A laboratory experiment from the Little...

  17. Method and apparatus to measure vapor pressure in a flow system

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Biblarz, Oscar (Swampscott, MA)

    1991-01-01T23:59:59.000Z

    The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process.

  18. Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phasehydrodeoxy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol. Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of...

  19. Energy Saving in Distillation Using Structured Packing and Vapor Recompression

    E-Print Network [OSTI]

    Hill, J.H.

    difference across the column. VRC uses hot compressed overhead vapors, instead of steam, to heat the reboiler. Cost savings are highest when the pressure ratio for the compressor is low. The pressure ratio depends on the boiling point difference of top...

  20. DIAMOND CHEMICAL VAPOR DEPOSITION Nucleation and Early Growth Stages

    E-Print Network [OSTI]

    Dandy, David

    a reality. Epi- taxial diamond has been grown on diamond and cubic-BN. Polycrystalline diamond films haveDIAMOND CHEMICAL VAPOR DEPOSITION Nucleation and Early Growth Stages by Huimin Liu David S. Dandy of high-quality diamond coatings on preshaped parts and synthesis of free-standing shapes of diamond

  1. Experimental Study of Water Vapor Adsorption on Geothermal

    E-Print Network [OSTI]

    Stanford University

    Geothermal Program under Department of Energy Grant No. DE-FG07-90IDI2934,and by the Department of PetroleumSGP-TR-148 Experimental Study of Water Vapor Adsorption on Geothermal Reservoir Rocks Shubo Shang Engineering, Stanford University Stanford Geothermal Program Interdisciplinary Research in Engineering

  2. Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement

    E-Print Network [OSTI]

    Tong, Yunwei

    2013-11-08T23:59:59.000Z

    This dissertation has two key objectives: the first objective is to develop a method of predicting and quantifying the amount of water that can enter into a pavement system by vapor transport; the second objective is to identify to which extent...

  3. A transient model for a cesium vapor thermionic converter. [Cs

    SciTech Connect (OSTI)

    El-Genk, M.S.; Murray, C.S.; Chaudhuri, S. (Institute for Space Nuclear Power Studies, Department of Chemical and Nuclear Engineering, The University of New Mexico, Albuquerque, New Mexico (USA))

    1991-01-10T23:59:59.000Z

    This paper presents an analytical model for simulating the transient and steady-state operation of cesium vapor thermionic converters. A parametric analysis is performed to assess the transient response of the converter to changes in fission power and width of interelectrode gap. The model optimizes the converter performance for maximum electric power to the load.(AIP)

  4. CVD CNT CNT (Vapor-grown carbon fiber, VGCF)

    E-Print Network [OSTI]

    Maruyama, Shigeo

    CNT CNT CVD CNT CNT (Vapor-grown carbon fiber, VGCF) 10001300 CNT CVD Smalley CO 24 CCVD 1 #12; 27 mm 3% 200 sccm 800 10 10 Torr 300 sccm Ethanol tank Hot bath boat Ar/H2 Ar or Ethanol tank Hot bath Ethanol tank Hot bath Pressure gauge Maindraintube Subdraintube

  5. OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL

    E-Print Network [OSTI]

    Stanford University

    OPTIMIZATION OF INJECTION INTO VAPOR-DOMINATED GEOTHERMAL RESERVOIRS CONSIDERING ADSORPTION. Because of the costs associated with injection, optimizing an injection program involves not only of the injectate can become available for production and at the same time optimize the present worth of the project

  6. High-resolution terahertz atmospheric water vapor continuum measurements

    E-Print Network [OSTI]

    Massachusetts at Lowell, University of

    High-resolution terahertz atmospheric water vapor continuum measurements David M. Slocum,* Thomas M such as pollution monitoring and the detection of energetic chemicals using remote sensing over long path lengths through the atmosphere. Although there has been much attention to atmospheric effects over narrow

  7. UNCORRECTEDPROOF 2 Vaporization, fusion and sublimation enthalpies of the

    E-Print Network [OSTI]

    Chickos, James S.

    UNCORRECTEDPROOF 2 Vaporization, fusion and sublimation enthalpies of the 3 dicarboxylic acids from of Chemistry and Biochemistry, University of Missouri-St. Louis, 8001 Natural Bridge, St. Louis, MO 63121, USA observed previously in the sublimation enthalpies of these compounds. The results are dis- 16 cussed

  8. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R.K.; Im, K.H.

    1996-04-02T23:59:59.000Z

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

  9. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R. K. (6440 Hillcrest Dr., Burr Ridge, IL 60521); Im, K. H. (925 Lehigh Cir., Naperville, IL 60565)

    1996-01-01T23:59:59.000Z

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

  10. Assessment of radionuclide vapor-phase transport in unsaturated tuff

    SciTech Connect (OSTI)

    Smith, D.M.; Updegraff, C.D.; Bonano, E.J.; Randall, J.D.

    1986-11-01T23:59:59.000Z

    This report describes bounding calculations performed to investigate the possibility of radionuclide migration in a vapor phase associated with the emplacement of high-level waste canister in unsaturated tuff formations. Two potential radionuclide transport mechanisms in the vapor phase were examined: aerosol migration and convection/diffusion of volatile species. The former may have significant impact on the release of radionuclides to the accessible environment as the concentration in the aerosols will be equal to that in the ground water. A conservative analysis of air diffusion in a stagnant liquid film indicated that for all expected repository conditions, aerosol formation is not possible. The migration of volatile species was examined both in the vicinity of a waste canister and outside the thermally disturbed zone. Two-dimensional (radial) and three-dimensional (radial-vertical) coupled heat transfer-gas flow-liquid flow simulations were performed using the TOUGH computer code. The gas flow rate relative to the liquid flow rate predicted from the simulations allowed calculations of mobility ratios due to convection which led to the conclusion that, except for the immediate region near the canister, transport in the liquid phase will be dominant for radionuclides heavier than radon. Near the waste canister, iodine transport may also be important in the vapor phase. Bounding calculations for vertical mobility ratios were carried out as a function of saturation. These calculations are conservative and agree well with the two-dimensional simulations. Based on this analysis, it is clear that vapor-phase transport will not be important for radionuclides such as cesium and heavier species. Vapor transport for iodine may play a role in the overall release scenario depending on the particular repository conditions.

  11. Correlation for the Vapor Pressure of Heavy Water From the Triple Point to the Critical Point

    E-Print Network [OSTI]

    Magee, Joseph W.

    Correlation for the Vapor Pressure of Heavy Water From the Triple Point to the Critical Point Allan the vapor pressure of heavy water (D2O) from its triple point to its critical point. This work takes Institute of Physics. Key words: D2O; heavy water; ITS-90; vapor pressure. Contents 1. Introduction

  12. The control of mercury vapor using biotrickling filters Ligy Philip a,b,1

    E-Print Network [OSTI]

    The control of mercury vapor using biotrickling filters Ligy Philip a,b,1 , Marc A. Deshusses b August 2007 Abstract The feasibility of using biotrickling filters for the removal of mercury vapor from. In particular, the biotrickling filters with sulfur oxidizing bacteria were able to remove 100% of mercury vapor

  13. Numerical Methodology to Evaluate Fast Reactor Sodium Combustion

    SciTech Connect (OSTI)

    Yamaguchi, Akira; Takata, Takashi; Okano, Yasushi [Japan Nuclear Cycle Development Institute (Japan)

    2001-12-15T23:59:59.000Z

    In the present study, a numerical methodology for sodium combustion has been developed for the safety evaluation of a liquid-metal-cooled fast reactor. The methodology includes a fast-running zone model computer program for safety evaluation, a field model program for multidimensional thermal hydraulics, and a chemical reaction analysis program based on chemical equilibrium theory. Two recently performed experiments have been analyzed using the computer programs, and the numerical results are in good agreement with the experiments. Although sodium combustion is a complex phenomenon, use of these computer programs gives better understanding of the coupled thermal hydraulics and chemical reaction.

  14. The magnesium nutrition of cotton as influenced by sodium

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    2012-06-07T23:59:59.000Z

    1964 Major Subject. Plant Physic logy THE MAGNESIUM NUTRITION OF COTTON AS INFLUENCED BY SODIUM A Thesis By MERVYN M. THENABADU Approved as to style and content by: Chairman of Commi. e Nun Head of Department Member Mem, er Member Member... REVIEW OF LITERATURE (a) Sodium as a plant nutrient (b) I'he role of magnesium in plant nutrition MATERIALS AND METHODS RESUL:S DISCUSSION 13 21 24 (a) The effect of treatments on grcwth and reproduction (b) The effect of treatments on the ccr...

  15. Aluminum Zintl anion moieties within sodium aluminum clusters

    SciTech Connect (OSTI)

    Wang, Haopeng; Zhang, Xinxing; Ko, Yeon Jae; Grubisic, Andrej; Li, Xiang; Ganteför, Gerd; Bowen, Kit H., E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Schnöckel, Hansgeorg [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany)] [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany); Eichhorn, Bryan W. [Department of Chemistry, University of Maryland at College Park, College Park, Maryland 20742 (United States)] [Department of Chemistry, University of Maryland at College Park, College Park, Maryland 20742 (United States); Lee, Mal-Soon; Jena, P. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States); Kandalam, Anil K., E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Physics, West Chester University of Pennsylvania, West Chester, Pennsylvania 19383 (United States); Kiran, Boggavarapu, E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)] [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)

    2014-02-07T23:59:59.000Z

    Through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations, we have established that aluminum moieties within selected sodium-aluminum clusters are Zintl anions. Sodium–aluminum cluster anions, Na{sub m}Al{sub n}{sup ?}, were generated in a pulsed arc discharge source. After mass selection, their photoelectron spectra were measured by a magnetic bottle, electron energy analyzer. Calculations on a select sub-set of stoichiometries provided geometric structures and full charge analyses for both cluster anions and their neutral cluster counterparts, as well as photodetachment transition energies (stick spectra), and fragment molecular orbital based correlation diagrams.

  16. Method for the generation of variable density metal vapors which bypasses the liquidus phase

    DOE Patents [OSTI]

    Kunnmann, Walter (Stony Brook, NY); Larese, John Z. (Rocky Point, NY)

    2001-01-01T23:59:59.000Z

    The present invention provides a method for producing a metal vapor that includes the steps of combining a metal and graphite in a vessel to form a mixture; heating the mixture to a first temperature in an argon gas atmosphere to form a metal carbide; maintaining the first temperature for a period of time; heating the metal carbide to a second temperature to form a metal vapor; withdrawing the metal vapor and the argon gas from the vessel; and separating the metal vapor from the argon gas. Metal vapors made using this method can be used to produce uniform powders of the metal oxide that have narrow size distribution and high purity.

  17. Evaporation monitoring and composition control of alloy systems with widely differing vapor pressures

    SciTech Connect (OSTI)

    Anklam, T.M.; Berzins, L.V.; Braun, D.G.; Haynam, C.; McClelland, M.A.; Meier, T.

    1994-10-01T23:59:59.000Z

    Lawrence Livermore National Laboratory is developing sensors and controls to improve and extend electron beam materials processing technology to alloy systems with constituents of widely varying vapor pressure. The approach under development involves using tunable lasers to measure the density and composition of the vapor plume. A laser based vaporizer control system for vaporization of a uranium-iron alloy has been previously demonstrated in multi-hundred hour, high rate vaporization experiments at LLNL. This paper reviews the design and performance of the uranium vaporization sensor and control system and discusses the extension of the technology to monitoring of uranium vaporization. Data is presented from an experiment in which titanium wire was fed into a molten niobium pool. Laser data is compared to deposited film composition and film cross sections. Finally, the potential for using this technique for composition control in melting applications is discussed.

  18. Evaporation monitoring and composition control of alloy systems with widely differing vapor pressures

    SciTech Connect (OSTI)

    Anklam, T.M.; Berzins, L.V.; Braun, D.G.; Haynam, C.; McClelland, M.A.; Meier, T. [Lawrence Livermore National Lab., CA (United States)

    1994-12-31T23:59:59.000Z

    Lawrence Livermore National Laboratory is developing sensors and controls to improve and extend electron beam materials processing technology to alloy systems with constituents of widely varying vapor pressure. The approach under development involves using tunable lasers to measure the density and composition of the vapor plume. A laser based vaporizer control system for vaporization of a uranium-iron alloy has been previously demonstrated in multi-hundred hour, high rate vaporization experiments at LLNL. This paper reviews the design and performance of the uranium vaporization sensor and control system and discusses the extension of the technology to monitoring of titanium vaporization. Data is presented from an experiment in which titanium wire was fed into a molten niobium pool. Laser data is compared to deposited film composition and film cross sections. Finally, the potential for using this technique for composition control in melting applications is discussed.

  19. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Bonnesen, Peter V.; Bryan, Jeffrey C.; Haverlock, Tamara J.

    2002-03-30T23:59:59.000Z

    This research has focused on new liquid-liquid extraction chemistry applicable to separation of major sodium salts from alkaline tank waste. It was the overall goal to provide the scientific foundation upon which the feasibility of liquid-liquid extraction chemistry for bulk reduction of the volume of tank waste can be evaluated. Sodium hydroxide represented the initial test case and primary focus. It is a primary component of the waste1 and has the most value for recycle. A full explanation of the relevance of this research to USDOE Environmental Management needs will be given in the Relevance, Impact, and Technology Transfer section below. It should be noted that this effort was predicated on the need for sodium removal primarily from low-activity waste, whereas evolving needs have shifted attention to volume reduction of the high-activity waste. The results of the research to date apply to both applications, though treatment of high-activity wastes raises new questions that will be addressed in the renewal period. Toward understanding the extractive chemistry of sodium hydroxide and other sodium salts, it was the intent to identify candidate extractants and determine their applicable basic properties regarding selectivity, efficiency, speciation, and structure. A hierarchical strategy was to be employed in which the type of liquid-liquid-extraction system varied in sophistication from simple, single-component solvents to solvents containing designer host molecules. As an aid in directing this investigation toward addressing the fundamental questions having the most value, a conceptualization of an ideal process was advanced. Accordingly, achieving adequate selectivity for sodium hydroxide represented a primary goal, but this result is worthwhile for waste applications only if certain conditions are met.

  20. Tank vapor mitigation requirements for Hanford Tank Farms

    SciTech Connect (OSTI)

    Rakestraw, L.D.

    1994-11-15T23:59:59.000Z

    Westinghouse Hanford Company has contracted Los Alamos Technical Associates to listing of vapors and aerosols that are or may be emitted from the High Level Waste (HLW) tanks at Hanford. Mitigation requirements under Federal and State law, as well as DOE Orders, are included in the listing. The lists will be used to support permitting activities relative to tank farm ventilation system up-grades. This task is designated Task 108 under MJB-SWV-312057 and is an extension of efforts begun under Task 53 of Purchase Order MPB-SVV-03291 5 for Mechanical Engineering Support. The results of that task, which covered only thirty-nine tanks, are repeated here to provide a single source document for vapor mitigation requirements for all 177 HLW tanks.

  1. Piston pump and method of reducing vapor lock

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Harvey, Michael N. (DeSoto, TX)

    2000-02-15T23:59:59.000Z

    A pump includes a housing defining a cavity, at least one bore, a bore inlet, and a bore outlet. The bore extends from the cavity to the outlet and the inlet communicates with the bore at a position between the cavity and the outlet. A crankshaft is mounted in supports and has an eccentric portion disposed in the cavity. The eccentric portion is coupled to a piston so that rotation of the crankshaft reciprocates the piston in the bore between a discharge position an intake position. The bore may be offset from an axis of rotation to reduce bending of the piston during crankshaft rotation. During assembly of the pump, separate parts of the housing can be connected together to facilitate installation of internal pumping components. Also disclosed is a method of reducing vapor lock by mixing vapor and liquid portions of a substance and introducing the mixture into a piston bore.

  2. Piston pump and method of reducing vapor lock

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Harvey, Michael N. (DeSoto, TX)

    2001-01-30T23:59:59.000Z

    A pump includes a housing defining a cavity, at least one bore, a bore inlet, and a bore outlet. The bore extends from the cavity to the outlet and the inlet communicates with the bore at a position between the cavity and the outlet. A crankshaft is mounted in supports and has an eccentric portion disposed in the cavity. The eccentric portion is coupled to a piston so that rotation of the crankshaft reciprocates the piston in the bore between a discharge position an intake position. The bore may be offset from an axis of rotation to reduce bending of the piston during crankshaft rotation. During assembly of the pump, separate parts of the housing can be connected together to facilitate installation of internal pumping components. Also disclosed is a method of reducing vapor lock by mixing vapor and liquid portions of a substance and introducing the mixture into a piston bore.

  3. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  4. Water vapor and the dynamics of climate changes

    E-Print Network [OSTI]

    Schneider, Tapio; Levine, Xavier

    2009-01-01T23:59:59.000Z

    Water vapor is not only Earth's dominant greenhouse gas. Through the release of latent heat when it condenses, it also plays an active role in dynamic processes that shape the global circulation of the atmosphere and thus climate. Here we present an overview of how latent heat release affects atmosphere dynamics in a broad range of climates, ranging from extremely cold to extremely warm. Contrary to widely held beliefs, atmospheric circulation statistics can change non-monotonically with global-mean surface temperature, in part because of dynamic effects of water vapor. For example, the strengths of the tropical Hadley circulation and of zonally asymmetric tropical circulations, as well as the kinetic energy of extratropical baroclinic eddies, can be lower than they presently are both in much warmer climates and in much colder climates. We discuss how latent heat release is implicated in such circulation changes, particularly through its effect on the atmospheric static stability, and we illustrate the circul...

  5. Vapor-liquid equilibria of hydrocarbons and fuel oxygenates. 2

    SciTech Connect (OSTI)

    Bennett, A.; Lamm, S.; Orbey, H.; Sandler, S.I. (Univ. of Delaware, Newark (United States))

    1993-04-01T23:59:59.000Z

    Vapor-liquid equilibrium data for methyl tert-butyl ether (MTBE) + 1-heptene, MTBE + four-component gasoline prototype, ethanol + four-component gasoline prototype, and separately MTBE and ethanol with the Auto/Oil Air Quality Improvement Research Gasoline Blend A are reported. Small additions of MTBE have a very small effect on the total equilibrium pressure of this gasoline blend, and at most temperatures will decrease this pressure. In contrast, small additions of ethanol to this gasoline blend result in a significant increase in the equilibrium pressure at all temperatures. Analysis shows that the vapor-liquid equilibrium data for the MTBE-containing systems are easily correlated using a modified Peng-Robinson equation of state with conventional van der Waals one-fluid mixing rules. Data for mixtures containing ethanol cannot be accurately correlated in this way.

  6. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01T23:59:59.000Z

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  7. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, Jerry R. (Iona, ID); Downs, Wayne C. (Sugar City, ID); Kaser, Timothy G. (Ammon, ID); Hall, H. James (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources.

  8. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, J.R.; Downs, W.C.; Kaser, T.G.; Hall, H.J.

    1997-12-16T23:59:59.000Z

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources. 4 figs.

  9. High average power magnetic modulator for metal vapor lasers

    DOE Patents [OSTI]

    Ball, Don G. (Livermore, CA); Birx, Daniel L. (Oakley, CA); Cook, Edward G. (Livermore, CA); Miller, John L. (Livermore, CA)

    1994-01-01T23:59:59.000Z

    A three-stage magnetic modulator utilizing magnetic pulse compression designed to provide a 60 kV pulse to a copper vapor laser at a 4.5 kHz repetition rate is disclosed. This modulator operates at 34 kW input power. The circuit includes a step up auto transformer and utilizes a rod and plate stack construction technique to achieve a high packing factor.

  10. SOLIDIFICATION OF THE HANFORD LAW WASTE STREAM PRODUCED AS A RESULT OF NEAR-TANK CONTINUOUS SLUDGE LEACHING AND SODIUM HYDROXIDE RECOVERY

    SciTech Connect (OSTI)

    Reigel, M.; Johnson, F.; Crawford, C.; Jantzen, C.

    2011-09-20T23:59:59.000Z

    The U.S. Department of Energy (DOE), Office of River Protection (ORP), is responsible for the remediation and stabilization of the Hanford Site tank farms, including 53 million gallons of highly radioactive mixed wasted waste contained in 177 underground tanks. The plan calls for all waste retrieved from the tanks to be transferred to the Waste Treatment Plant (WTP). The WTP will consist of three primary facilities including pretreatment facilities for Low Activity Waste (LAW) to remove aluminum, chromium and other solids and radioisotopes that are undesirable in the High Level Waste (HLW) stream. Removal of aluminum from HLW sludge can be accomplished through continuous sludge leaching of the aluminum from the HLW sludge as sodium aluminate; however, this process will introduce a significant amount of sodium hydroxide into the waste stream and consequently will increase the volume of waste to be dispositioned. A sodium recovery process is needed to remove the sodium hydroxide and recycle it back to the aluminum dissolution process. The resulting LAW waste stream has a high concentration of aluminum and sodium and will require alternative immobilization methods. Five waste forms were evaluated for immobilization of LAW at Hanford after the sodium recovery process. The waste forms considered for these two waste streams include low temperature processes (Saltstone/Cast stone and geopolymers), intermediate temperature processes (steam reforming and phosphate glasses) and high temperature processes (vitrification). These immobilization methods and the waste forms produced were evaluated for (1) compliance with the Performance Assessment (PA) requirements for disposal at the IDF, (2) waste form volume (waste loading), and (3) compatibility with the tank farms and systems. The iron phosphate glasses tested using the product consistency test had normalized release rates lower than the waste form requirements although the CCC glasses had higher release rates than the quenched glasses. However, the waste form failed to meet the vapor hydration test criteria listed in the WTP contract. In addition, the waste loading in the phosphate glasses were not as high as other candidate waste forms. Vitrification of HLW waste as borosilicate glass is a proven process; however the HLW and LAW streams at Hanford can vary significantly from waste currently being immobilized. The ccc glasses show lower release rates for B and Na than the quenched glasses and all glasses meet the acceptance criterion of < 4 g/L. Glass samples spiked with Re{sub 2}O{sub 7} also passed the PCT test. However, further vapor hydration testing must be performed since all the samples cracked and the test could not be performed. The waste loading of the iron phosphate and borosilicate glasses are approximately 20 and 25% respectively. The steam reforming process produced the predicted waste form for both the high and low aluminate waste streams. The predicted waste loadings for the monolithic samples is approximately 39%, which is higher than the glass waste forms; however, at the time of this report, no monolithic samples were made and therefore compliance with the PA cannot be determined. The waste loading in the geopolymer is approximately 40% but can vary with the sodium hydroxide content in the waste stream. Initial geopolymer mixes revealed compressive strengths that are greater than 500 psi for the low aluminate mixes and less than 500 psi for the high aluminate mixes. Further work testing needs to be performed to formulate a geopolymer waste form made using a high aluminate salt solution. A cementitious waste form has the advantage that the process is performed at ambient conditions and is a proven process currently in use for LAW disposal. The Saltstone/Cast Stone formulated using low and high aluminate salt solutions retained at least 97% of the Re that was added to the mix as a dopant. While this data is promising, additional leaching testing must be performed to show compliance with the PA. Compressive strength tests must also be performed on the Cast Ston

  11. VAPOR SPACE AND LIQUID/AIR INTERFACECORROSION TESTS

    SciTech Connect (OSTI)

    Zapp, P.; Hoffman, E.

    2009-11-09T23:59:59.000Z

    The phenomena of vapor space corrosion and liquid/air interface corrosion of carbon steel in simulated liquid waste environments have been investigated. Initial experiments have explored the hypothesis that vapor space corrosion may be accelerated by the formation of a corrosive electrolyte on the tank wall by a process of evaporation of relatively warmer waste and condensation of the vapor on the relatively cooler tank wall. Results from initial testing do not support the hypothesis of electrolyte transport by evaporation and condensation. The analysis of the condensate collected by a steel specimen suspended over a 40 C simulated waste solution showed no measurable concentrations of the constituents of the simulated solution and a decrease in pH from 14 in the simulant to 5.3 in the condensate. Liquid/air interface corrosion was studied as a galvanic corrosion system, where steel at the interface undergoes accelerated corrosion while steel in contact with bulk waste is protected. The zero-resistance-ammeter technique was used to measure the current flow between steel specimens immersed in solutions simulating (1) the high-pH bulk liquid waste and (2) the expected low-pH meniscus liquid at the liquid/air interface. Open-circuit potential measurements of the steel specimens were not significantly different in the two solutions, with the result that (1) no consistent galvanic current flow occurred and (2) both the meniscus specimen and bulk specimen were subject to pitting corrosion.

  12. Program plan for the resolution of tank vapor issues

    SciTech Connect (OSTI)

    Osborne, J.W.; Huckaby, J.L.

    1994-05-01T23:59:59.000Z

    Since 1987, workers at the Hanford Site waste tank farms in Richland, Washington, have reported strong odors emanating from the large, underground high-level radioactive waste storage tanks. Some of these workers have complained of symptoms (e.g., headaches, nausea) related to the odors. In 1992, the U.S. Department of Energy, which manages the Hanford Site, and Westinghouse Hanford Company determined that the vapor emissions coming from the tanks had not been adequately characterized and represented a potential health risk to workers in the immediate vicinity of the tanks. At that time, workers in certain areas of the tank farms were required to use full-face, supplied-breathing-air masks to reduce their exposure to the fugitive emissions. While use of supplied breathing air reduced the health risks associated with the fugitive emissions, it introduced other health and safety risks (e.g., reduced field of vision, air-line tripping hazards, and heat stress). In 1992, an aggressive program was established to assure proper worker protection while reducing the use of supplied breathing air. This program focuses on characterization of vapors inside the tanks and industrial hygiene monitoring in the tank farms. If chemical filtration systems for mitigation of fugitive emissions are deemed necessary, the program will also oversee their design and installation. This document presents the plans for and approach to resolving the Hanford Site high-level waste tank vapor concerns. It is sponsored by the Department of Energy Office of Environmental Restoration and Waste Management.

  13. ESA DUE GlobVapour water vapor products: Validation

    SciTech Connect (OSTI)

    Schneider, Nadine; Schroeder, Marc; Stengel, Martin [Deutscher Wetterdienst (DWD), KU22, Frankfurter Str. 135, 63067 Offenbach a. M (Germany); Lindstrot, Ramus; Preusker, Rene [Freie Universitaet Berlin (FUB), Carl-Heinrich-Becker-Weg 6-10, 12165 Berlin (Germany); Collaboration: ESA DUE GlobVapour Consortium

    2013-05-10T23:59:59.000Z

    The main objective of the European Space Agency (ESA) Data User Element (DUE) GlobVapour project was the development of multi-annual global water vapor data sets. Since water vapour is a key climate variable it is important to have a good understanding of its behavior in the climate system. The ESA DUE GlobVapour project provides water vapor data, including error estimates, based on carefully calibrated and inter-calibrated satellite radiances in response to user requirements for long time series satellite observations. ESA DUE GlobVapour total columnar water vapor (TCWV) products derived from GOME/SCIA/GOME-2 (1996-2008) and SSM/I+MERIS (2003-2008) have been validated for the mentioned period, using satellite-based (AIRS, ATOVS) and ground-based measurements (radiosondes and microwave radiometer). The validation results are discussed in the following. The technical specifications on bias (1 kg/m{sup 2} for SSMI+MERIS and 2 kg/m{sup 2} for GOME/SCIA/GOME-2) are generally met. For more information, documents and data download follow the link: www.globvapour.info.

  14. Vapor-liquid equilibria for methanol + tetraethylene glycol dimethyl ether

    SciTech Connect (OSTI)

    Esteve, X.; Chaudhari, S.K.; Coronas, A. [Univ. Rovira i Virgili, Tarragona (Spain). Dept. of Electrical and Mechanical Engineering

    1995-11-01T23:59:59.000Z

    Vapor-liquid equilibrium (P-T-x) for the methanol + tetraethylene glycol dimethyl ether binary system were obtained by the static method in the range of temperatures from 293.15 to 423.15 K at 10 K intervals. The modified vapor pressure apparatus used is described. The Kuczynsky method was used to calculate the liquid and vapor composition and the activity coefficients of methanol from the initial composition of the sample and the measured pressure and temperature. The results were correlated by the NRTL and UNIQUAC temperature dependent activity coefficient models. This system shows nearly ideal behavior at 323.15 K, but positive deviations from ideality at lower temperatures and negative deviations at higher temperatures are observed. The activity coefficients become more negative with the increase in temperature and mole fraction of methanol. The excess molar enthalpy using the Gibss-Helmholtz equation and the NRTL and UNIQUAC parameters were calculated at 303.15 K and compared with experimental data. This binary system shows promise as a working pair for high-temperature heat pump applications.

  15. Methanol vaporization and injection system for internal combustion engine

    SciTech Connect (OSTI)

    Bayley, R.I.

    1980-05-06T23:59:59.000Z

    An engine equipped with an alcohol vaporization injection system operates as a four stroke cycle diesel engine that transfers the heat of exiting exhaust gases and cylinder head walls to the fuel. The engine runs on alcohol. The alcohol becomes vaporized and its pressure is high enough so that when a valve is opened between the high pressure fuel line and the combustion chamber (when it is at the peak of its compression ratio) enough alcohol will enter the combustion chamber to allow proper combustion. The overall advantages to this type of alcohol vaporization injection system is that it adds relatively few new mechanisms to the spark ignition four cycle internal combustion engine to enable it to operate as a diesel engine with a high thermal efficiency. This alcohol injection system exploits the engine's need for greater volumes of alcohol caused by the alcohol's relatively low heat of combustion (When compared to gasoline) by using this greater volume of fuel to return greater quantities of heat back to the engine to a much greater degree than other fuels can.

  16. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, L.D.; Cerni, T.A.

    1989-10-17T23:59:59.000Z

    Apparatus and method are disclosed which determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavelength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to an equation given in the patent where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4) + K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation. 11 figs.

  17. Method of and apparatus for measuring vapor density

    DOE Patents [OSTI]

    Nelson, Loren D. (Morrison, CO); Cerni, Todd A. (Littleton, CO)

    1989-01-01T23:59:59.000Z

    Apparatus and method determine the concentration of an individual component, such as water vapor, of a multi-component mixture, such as a gaseous mixture for cooling a nuclear reactor. A hygrometer apparatus includes an infrared source for producing a broadband infrared energy beam that includes a strong water vapor absorption band and a weak water vapor absorption region. The beam is chopped to select infrared pulses. A temporally first pulse has a wavelength in the weakly absorbing region, a temporally second pulse has a wavelength in the strong band and a temporally third pulse has a wavlength in the weakly absorbing region. A fourth reference pulse representing background radiation is interposed in such chopped pulses. An indium arsenide infrared sensor is responsive to the pulses for generating an output signal in proportion to: ##EQU1## where N1 is proportional to the transmission through the sample of the first signal, N4 is related to the background radiation, and [K2 (N2-N4)+K3 (N3-N4)] is the time-weighted average of the transmission through the sample of the second and third pulses applicable at the time of the second pulse, with the reference pulse N4 being subtracted in each case to render the ratio independent of variations in the background radiation.

  18. FATE OF INGESTED SODIUM BICARBONATE IN THE FOWL

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . 100 calcium while rations 3 and4contained 3.85 p. 100 calcium. Sodium bicarbonate was added at a level. The duodenum was entered at the top of the loop and the electrode tip immersed its full length down the posterior side of the loop. The #12;mid-intestinal reading was taken with the incision at approximately

  19. Electrochemical Recovery of Sodium Hydroxide from Alkaline Salt Solution

    SciTech Connect (OSTI)

    Hobbs, D.T. [Westinghouse Savannah River Company, AIKEN, SC (United States); Edwards, T.B.

    1996-10-01T23:59:59.000Z

    A statistically designed set of tests determined the effects of current density, temperature, and the concentrations of nitrate/nitrite, hydroxide and aluminate on the recovery of sodium as sodium hydroxide (caustic) from solutions simulating those produced from the Savannah River Site (SRS) In-Tank Precipitation process. These tests included low nitrate and nitrite concentrations which would be produced by electrolytic nitrate/nitrite destruction. The tests used a two compartment electrochemical cell with a Nafion Type 324 ion-exchange membrane. Caustic was successfully recovered from the waste solutions. Evaluation of the testing results indicated that the transport of sodium across the membrane was not significantly affected by any of the varied parameters. The observed variance in the sodium flux is attributed to experimental errors and variations in the performance characteristics of individual pieces of the organic-based Nafion membrane.Additional testing is recommended to determine the maximum current density, to evaluate the chemical durability of the organic membrane as a function of current density and to compare the durability and performance characteristics of the organic-based Nafion membrane with that of other commercially available organic membranes and the inorganic class of membranes under development by Ceramatec and PNNL.

  20. Process for making boron nitride using sodium cyanide and boron

    DOE Patents [OSTI]

    Bamberger, Carlos E. (Oak Ridge, TN)

    1990-01-01T23:59:59.000Z

    This a very simple process for making boron nitride by mixing sodium cyanide and boron phosphate and heating the mixture in an inert atmosphere until a reaction takes place. The product is a white powder of boron nitride that can be used in applications that require compounds that are stable at high temperatures and that exhibit high electrical resistance.

  1. ORIGINAL RESEARCH Systematic family-wide analysis of sodium bicarbonate

    E-Print Network [OSTI]

    Hall, Randy A

    ORIGINAL RESEARCH Systematic family-wide analysis of sodium bicarbonate cotransporter NBCn1/SLC4A7/NBCn1 pulled down syntrophin c2 and con- versely GST/syntrophin c2 pulled down NBCn1. Moreover normally moves Na+ and HCO3 Ã? into cells and protects intracel- lular pH (pHi) from falling below normal

  2. Laboratory-scale sodium-carbonate aggregate concrete interactions. [LMFBR

    SciTech Connect (OSTI)

    Westrich, H.R.; Stockman, H.W.; Suo-Anttila, A.

    1983-09-01T23:59:59.000Z

    A series of laboratory-scale experiments was made at 600/sup 0/C to identify the important heat-producing chemical reactions between sodium and carbonate aggregate concretes. Reactions between sodium and carbonate aggregate were found to be responsible for the bulk of heat production in sodium-concrete tests. Exothermic reactions were initiated at 580+-30/sup 0/C for limestone and dolostone aggregates as well as for hydrated limestone concrete, and at 540+-10/sup 0/C for dehydrated limestone concrete, but were ill-defined for dolostone concrete. Major reaction products included CaO, MgO, Na/sub 2/CO/sub 3/, Na/sub 2/O, NaOH, and elemental carbon. Sodium hydroxide, which forms when water is released from cement phases, causes slow erosion of the concrete with little heat production. The time-temperature profiles of these experiments have been modeled with a simplified version of the SLAM computer code, which has allowed derivation of chemical reaction rate coefficients.

  3. Method of Manufacturing Micro-Disperse Particles of Sodium Borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester. Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2008-09-23T23:59:59.000Z

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  4. Method of generating hydrogen gas from sodium borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2007-12-11T23:59:59.000Z

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  5. Immobilization of sodium nitrate waste with polymers: Topical report

    SciTech Connect (OSTI)

    Franz, E.M.; Heiser, J.H. III; Colombo, P.

    1987-04-01T23:59:59.000Z

    This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10/sup -3/ to 7.3 x 10/sup -1/ and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure were below 500 ppM. The nitrate releases from PES waste forms were similar to those from polyethylene waste forms at the same waste loadings. The compressive yield strengths, measured after ninety-day immersion in water, ranged between 2070 and 7710 psi. In the case of WEP waste forms, only 30 wt% loaded samples passed the immersion test. 23 refs., 24 figs., 12 tabs.

  6. Compatibility Assessment of Advanced Stainless Steels in Sodium

    SciTech Connect (OSTI)

    Pawel, Steven J [ORNL

    2012-01-01T23:59:59.000Z

    Type 316L stainless steel capsules containing commercially pure sodium and miniature tensile specimens of HT-UPS (austenitic, 14Cr-16Ni), NF-616 (ferritic/martensitic, 9Cr-2W-0.5Mo), or 316L (austenitic, 17Cr-10Ni-2Mo) stainless steel were exposed at 600 or 700 C for 100 and 400 h as a screening test for compatibility. Using weight change, tensile testing, and metallographic analysis, HT-UPS and 316L were found to be largely immune to changes resulting from sodium exposure, but NF-616 was found susceptible to substantial decarburization at 700 C. Subsequently, two thermal convection loops (TCLs) constructed of 316L and loaded with commercially pure sodium and miniature tensile specimens of HT-UPS and 316L were operated for 2000 h each one between 500 and 650 C, the other between 565 and 725 C at a flow rate of about 1.5 cm/s. Changes in specimen appearance, weight, and tensile properties were observed to be very minor in all cases, and there was no metallographic evidence of microstructure changes, composition gradients, or mass transfer resulting from prolonged exposure in a TCL. Thus, it appears that HT-UPS and 316L stainless steels are similarly compatible with commercially pure sodium under these exposure conditions.

  7. Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF

    E-Print Network [OSTI]

    Weston, Ken

    Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF-355. Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF DMR

  8. apical sodium-chloride cotransporter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    g magnesium chloride, 3.24 g magnesium sulfate bromide, 34 mg strontium chloride, 22 mg boric acid, 4 mg sodium silicate, 2.4 mg sodium fluoride, 1.6 mg Bae, Jin-Woo 302 The...

  9. Method of and apparatus for removing silicon from a high temperature sodium coolant

    DOE Patents [OSTI]

    Yunker, W.H.; Christiansen, D.W.

    1983-11-25T23:59:59.000Z

    This patent discloses a method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

  10. Go No-Go Recommendation for Sodium Borohydride for On-Board Vehicular Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    Independent review panel recommendation for go/no go decision on use of hydrolysis of sodium borohydride for hydrogen storage.

  11. Headspace vapor characterization of Hanford Waste Tank 241-T-110: Results from samples collected on August 31, 1995. Tank Vapor Characterization Project

    SciTech Connect (OSTI)

    McVeety, B.D.; Thomas, B.L.; Evans, J.C. [and others

    1996-05-01T23:59:59.000Z

    This report describes the results of vapor samples taken from the headspace of waste storage tank 241-T-110 (Tank T-110) at the Hanford Site in Washington State. Pacific Northwest National Laboratory (PNNL) contracted with Westinghouse Hanford Company (WHC) to provide sampling devices and analyze samples for inorganic and organic analytes collected from the tank headspace and ambient air near the tank. The analytical work was performed by the PNNL Vapor Analytical Laboratory (VAL) by the Tank Vapor Characterization Project. Work performed was based on a sample and analysis plan (SAP) prepared by WHC. The SAP provided job-specific instructions for samples, analyses, and reporting. The SAP for this sample job was {open_quotes}Vapor Sampling and Analysis Plan{close_quotes}, and the sample job was designated S5056. Samples were collected by WHC on August 31, 1995, using the Vapor Sampling System (VSS), a truck-based sampling method using a heated probe inserted into the tank headspace.

  12. Final Report for ARM Project Measuring 4-D Water Vapor Fields with GPS

    SciTech Connect (OSTI)

    Braun, John

    2006-02-06T23:59:59.000Z

    Water vapor is a primary element in the Earth’s climate system. Atmospheric water vapor is central to cloud processes, radiation transfer, and the hydrological cycle. Using funding from Department of Energy (DOE) grant DE-FG03-02ER63327, the University Corporation for Atmospheric Research (UCAR) developed new observational techniques to measure atmospheric water vapor and applied these techniques to measure four dimensional water vapor fields throughout the United States Southern Great Plains region. This report summarizes the development of a new observation from ground based Global Positioning System (GPS) stations called Slant Water Vapor (SW) and it’s utilization in retrieving four dimensional water vapor fields. The SW observation represents the integrated amount of water vapor between a GPS station and a transmitting satellite. SW observations provide improved temporal and spatial sampling of the atmosphere when compared to column-integrated quantities such as preciptitable water vapor (PW). Under funding from the DOE Atmospheric Radiation Measurement (ARM) program, GPS networks in the Southern Great Plains (SGP) region were deployed to retrieve SW to improve the characterization of water vapor throughout the region. These observations were used to estimate four dimensional water vapor fields using tomographic approaches and through assimilation into the MM5 numerical weather model.

  13. Ultracold Molecules from Ultracold Atoms: Interactions in Sodium and Lithium Gas

    E-Print Network [OSTI]

    Ultracold Molecules from Ultracold Atoms: Interactions in Sodium and Lithium Gas by Caleb from Ultracold Atoms: Interactions in Sodium and Lithium Gas by Caleb A Christensen Submitted of Philosophy Abstract The thesis presents results from experiments in which ultracold Sodium-6 and Lithium-23

  14. Synthesis of highly ordered mesoporous silica materials using sodium silicate and amphiphilic block copolymers

    E-Print Network [OSTI]

    Kim, Ji Man

    Synthesis of highly ordered mesoporous silica materials using sodium silicate and amphiphilic block) structures, using sodium silicate as the silica source and amphiphilic block copolymers as the structure of mesoporous silica material using nonionic surfac- tant and sodium silicate in the pH range 3­10.5. However

  15. An optical water vapor sensor for unmanned aerial vehicles

    SciTech Connect (OSTI)

    Timothy A. Berkoff; Paul L. Kebabian; Robert A. McClatchy; Charles E. Kolb; Andrew Freedman

    1998-12-01T23:59:59.000Z

    The water vapor sensor developed by Aerodyne Research, based on the optical absorption of light at {approximately}935 nm, has been successfully demonstrated on board the Pacific Northwest National Laboratory's Gulfstream-1 research aircraft during the Department of Energy's ARM Intensive Operations Period in August 1998. Data taken during this field campaign show excellent agreement with a chilled mirror and Lyman-alpha hygrometers and measurements confirm the ability to measure rapid, absolute water vapor fluctuations with a high degree of instrument stability and accuracy, with a noise level as low 10 ppmv (1 Hz measurement bandwidth). The construction of this small, lightweight sensor contains several unique elements which result in several significant advantages when compared to other techniques. First, the low power consumption Argon discharge lamp provides an optical beam at a fixed wavelength without a need for temperature or precision current control. The multi-pass absorption cell developed for this instrument provides a compact, low cost method that can survive deployment in the field. Fiber-optic cables, which are used to convey to light between the absorption cell, light source, and detection modules enable remote placement of the absorption cell from the opto-electronics module. Finally, the sensor does not use any moving parts which removes a significant source of potential malfunction. The result is an instrument which maintained its calibration throughout the field measurement campaign, and was not affected by high vibration and large uncontrolled temperature excursions. We believe that the development of an accurate, fast response water vapor monitor described in this report will open up new avenues of aerial-vehicle-based atmospheric research which have been relatively unexplored due to the lack of suitable low-cost, light-weight instrumentation.

  16. SRC burn test in 700-hp oil-designed boiler. Annex Volume B. DOE-Pittsburgh Energy Technology Center report. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1983-09-01T23:59:59.000Z

    Solvent Refined Coal (SRC) combustion tests were conducted at the U.S. Department of Energy's Pittsburgh Energy Technology Center. Combustion and flue-gas treatment of three different physical forms of SRC, as well as a No. 6 fuel oil, were evaluated. The three SRC fuels were (1) pulverized SRC Fuel; (2) SRC Residual Fuel Oil; and (3) SRC/Water Slurry. The SRC Residual Fuel Oil was a solution of SRC Fuel dissolved in heated process solvent. Approximately 500 tons of pulverized SRC Fuel and 30,000 gallons of SRC Residual Fuel Oil were combusted in a 700 hp (30 x 130 x 10/sup 6/ Btu/hr fuel input) oil-designed watertube package boiler. Sixty four-hour ASME combustion tests with three different SRC fuels were successfully concluded. The principal parameters evaluated were excess air levels and combustion air preheat temperature levels. Extensive data were collected on flue-gas levels of O/sub 2/, CO/sub 2/, CO, unburned hydrocarbons, SO/sub x/, NO/sub x/, uncontrolled particulates, uncontrolled opacity and carbon content of the flue-gas particulates. Boiler and combustion efficiencies were measured. The particulates were characterized via mass loadings, impactors, in-situ resistivity measurements, ultra-fine sampling, optical large particle sampling, five-stage cyclone sampling and chemical analysis of various cut sizes. A three-field pilot electrostatic precipitator (ESP) containing over 1000 square feet of plate collection area, a reverse air fabric filter pilot dust collector and a commercial pulse-jet fabric filter dust collector were operated at high collection efficiency. The results will be valuable in making recommendations for future tests and will provide a basis for conversion of industrial oil-fired boilers to SRC fuels. 11 references, 20 figures, 29 tables.

  17. Clinch River breeder reactor sodium fire protection system design and development

    SciTech Connect (OSTI)

    Foster, K.W.; Boasso, C.J.; Kaushal, N.N.

    1984-04-13T23:59:59.000Z

    To assure the protection of the public and plant equipment, improbable accidents were hypothesized to form the basis for the design of safety systems. One such accident is the postulated failure of the Intermediate Heat Transfer System (IHTS) piping within the Steam Generator Building (SGB), resulting in a large-scale sodium fire. This paper discusses the design and development of plant features to reduce the consequences of the accident to acceptable levels. Additional design solutions were made to mitigate the sodium spray contribution to the accident scenario. Sodium spill tests demonstrated that large sodium leaks can be safely controlled in a sodium-cooled nuclear power plant.

  18. Vapor explosion in the RIA-ST-4 experiment. [BWR

    SciTech Connect (OSTI)

    El-Genk, M.S.

    1980-01-01T23:59:59.000Z

    A concern in assuring the safety of commercial light water reactors (LWRs) is whether core overheating, during which molten fuel is produced, can lead to massive vaporization of the coolant and shock pressurization of the system due to an energetic molten fuel-coolant interaction (MFCI). The RIA-ST-4 experiment was one of four scoping tests in the Reactivity Initiated Accident (RIA) Test Series which is being conducted in the Power Burst Facility (PBF) to define an energy deposition failure threshold and to determine modes and consequences of fuel rod failure during a postulated boiling water reactor (BWR) control rod drop accident.

  19. Combustion chemical vapor deposited coatings for thermal barrier coating systems

    SciTech Connect (OSTI)

    Hampikian, J.M.; Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States). School of Materials Science and Engineering

    1995-12-31T23:59:59.000Z

    The new deposition process, combustion chemical vapor deposition, shows a great deal of promise in the area of thermal barrier coating systems. This technique produces dense, adherent coatings, and does not require a reaction chamber. Coatings can therefore be applied in the open atmosphere. The process is potentially suitable for producing high quality CVD coatings for use as interlayers between the bond coat and thermal barrier coating, and/or as overlayers, on top of thermal barrier coatings. In this report, the evaluation of alumina and ceria coatings on a nickel-chromium alloy is described.

  20. Dosimeter for monitoring vapors and aerosols of organic compounds

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1987-07-14T23:59:59.000Z

    A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique. 7 figs.

  1. Optical waveguides in SBN by zinc vapor diffusion

    E-Print Network [OSTI]

    Quinn, Jeffrey Dale

    1991-01-01T23:59:59.000Z

    at 600'C for a 12. 5 i1m Wide 1000'C Zinc Vapor Diffused SBN:60 Waveguide Measured at X = 0. 81 pm. IV. SBN:60 Amplitude Modulator Results . . . . . V. SBN:60 Mach-Zehnder Interferometer Results. . . . VI. Voltage-Length Product Comparison...: (a) extraordinary (TM), (b) 1. 5 x ordinary (TE). 12. Surface damage on SBN:60 diffused at 1000'C with an SiOz diffusion mask. 13. Zinc in-diffusion in SBN:60 25 . . . . . 26 . . . . . 27 . . . . . 28 29 14. Barium out-diffuison in SBN:60...

  2. Recirculating wedges for metal-vapor plasma tubes

    DOE Patents [OSTI]

    Hall, Jerome P. (Livermore, CA); Sawvel, Robert M. (Modesto, CA); Draggoo, Vaughn G. (Livermore, CA)

    1994-01-01T23:59:59.000Z

    A metal vapor laser is disclosed that recycles condensed metal located at the terminal ends of a plasma tube back toward the center of the tube. A pair of arcuate wedges are incorporated on the bottom of the plasma tube near the terminal ends. The wedges slope downward toward the center so that condensed metal may be transported under the force of gravity away from the terminal ends. The wedges are curved to fit the plasma tube to thereby avoid forming any gaps within the tube interior.

  3. Recirculating wedges for metal-vapor plasma tubes

    DOE Patents [OSTI]

    Hall, J.P.; Sawvel, R.M.; Draggoo, V.G.

    1994-06-28T23:59:59.000Z

    A metal vapor laser is disclosed that recycles condensed metal located at the terminal ends of a plasma tube back toward the center of the tube. A pair of arcuate wedges are incorporated on the bottom of the plasma tube near the terminal ends. The wedges slope downward toward the center so that condensed metal may be transported under the force of gravity away from the terminal ends. The wedges are curved to fit the plasma tube to thereby avoid forming any gaps within the tube interior. 8 figures.

  4. Io - Are vapor explosions responsible for the 5-micron outbursts

    SciTech Connect (OSTI)

    Sinton, W.M.

    1980-01-01T23:59:59.000Z

    It is proposed that a vapor explosion of a submerged pool of liquid sulfur will remove the crust overlying an area of about 50-km diam. Thermal radiation from the exposed liquid sulfur pool with a surface temperature of 600 K is then presumed to be responsible for the 5-micron outbursts that have been observed. The explosive volcanoes are expected to leave black sulfur calderas, which are, indeed, found on the surface. The 5-micron outburst observed by Sinton (1980), on June 11, 1979 (UT), is identified with a new caldera found on Voyager 2 photographs but which had not been present on Voyager 1 pictures.

  5. In situ bioremediation enhanced with air sparging and vapor extraction

    SciTech Connect (OSTI)

    Fesko, S. [Eaton Corp., Willoughby Hills, OH (United States)

    1996-11-01T23:59:59.000Z

    Eaton Corporation operates a corporate airport hangar facility in central Michigan. Testing showed, and soil and groundwater investigation confirmed, that two underground storage tanks leaked. This release sent an undetermined amount of Jet A kerosene into the soil and groundwater. As a result, the Michigan Department of Natural Resources (MDNR) listed the facility on the Act 307 list of contaminated sites (Michigan equivalent of a Superfund listing). The objective of the remediation was to clean up an aquifer and soil system contaminated with Jet A kerosene. This cleanup used pump and treat, bioremediation, soil vapor extraction, and air sparging technologies.

  6. Chemical Vapor Deposited Zinc Sulfide. SPIE Press Monograph

    SciTech Connect (OSTI)

    McCloy, John S.; Tustison, Randal W.

    2013-04-22T23:59:59.000Z

    Zinc sulfide has shown unequaled utility for infrared windows that require a combination of long-wavelength infrared transparency, mechanical durability, and elevated-temperature performance. This book reviews the physical properties of chemical vapor deposited ZnS and their relationship to the CVD process that produced them. An in-depth look at the material microstructure is included, along with a discussion of the material's optical properties. Finally, because the CVD process itself is central to the development of this material, a brief history is presented.

  7. Moisture burst structure in satellite water vapor imagery

    E-Print Network [OSTI]

    Ulsh, David Joel

    1988-01-01T23:59:59.000Z

    The moisture burst is a tropical synoptic-scale weather event that typically originates along the ITCZ and has been defined previously in window-channel infrared imagery. This research uses 6. 7-micrometer water vapor absorption band imagery to composite 35... moisture burst events during the North Pacific cool season of 1983-1984. Composite maps are constructed at four times, each 24 h apart, during the life cycle of the moisture burst. A comparative baseline is provided by an additional composite of 35 dates...

  8. Unusual thermopower of inhomogeneous graphene grown by chemical vapor deposition

    SciTech Connect (OSTI)

    Nam, Youngwoo, E-mail: youngwoo.nam@chalmers.se [Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of); Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Sun, Jie; Lindvall, Niclas; Yurgens, August [Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Jae Yang, Seung; Rae Park, Chong [Department of Materials Science and Engineering, Seoul National University, Seoul 151-747 (Korea, Republic of); Woo Park, Yung [Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of)

    2014-01-13T23:59:59.000Z

    We report on thermopower (TEP) and resistance measurements of inhomogeneous graphene grown by chemical vapor deposition (CVD). Unlike the conventional resistance of pristine graphene, the gate-dependent TEP shows a large electron-hole asymmetry. This can be accounted for by inhomogeneity of the CVD-graphene where individual graphene regions contribute with different TEPs. At the high magnetic field and low temperature, the TEP has large fluctuations near the Dirac point associated with the disorder in the CVD-graphene. TEP measurements reveal additional characteristics of CVD-graphene, which are difficult to obtain from the measurement of resistance alone.

  9. Vapor generation methods for explosives detection research. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II FieldVacancy-InducedCloudPoissonVampire Power1 - USAF1Vapor

  10. Stimulated emission of ultraviolet radiation by vapors of complex molecules

    SciTech Connect (OSTI)

    Barkova, L.A.; Gruzinskii, V.V.; Danilova, V.I.; Degtyarenko, K.M.; Kopylova, T.N.; Kuznetsov, A.L.

    1981-08-01T23:59:59.000Z

    Lasing was observed in vapors of new organic compounds: para-terphenyl, 2-phenylbenzoxazole, 2-(n-tolyl) benzoxazole, 2-(n-methoxyphenyl) benzoxazole, 2-(n-dimethylaminophenyl) benzoxazole, 2-biphenylbenzoxazole, 2-(..cap alpha..-naphthyl) benzoxazole, and also 1,4-di(n-phenylethynyl) benzole, and para-quaterphenyl pumped transversely by XeCl excimer laser radiation at lambda/sub p/ = 308 nm. The lasing bands without tuning covered the 330--370 nm range. The shortest-wavelength maximum (333.5 nm) was observed for 2-(n-methoxyphenyl) benzoxazole. An analysis was made of the lasing ability of the molecules.

  11. The Prospects of Alternatives to Vapor Compression Technology for Space Cooling and Food Refrigeration Applications

    SciTech Connect (OSTI)

    Brown, Daryl R.; Dirks, James A.; Fernandez, Nicholas; Stout, Tyson E.

    2010-03-31T23:59:59.000Z

    Five alternatives to vapor compression technology were qualitatively evaluated to determine their prospects for being better than vapor compression for space cooling and food refrigeration applications. The results of the assessment are summarized in the report. Overall, thermoacoustic and magnetic technologies were judged to have the best prospects for competing with vapor compression technology, with thermotunneling, thermoelectric, and thermionic technologies trailing behind in that order.

  12. Selective Adsorption of Sodium Aluminum Fluoride Salts from Molten Aluminum

    SciTech Connect (OSTI)

    Leonard S. Aubrey; Christine A. Boyle; Eddie M. Williams; David H. DeYoung; Dawid D. Smith; Feng Chi

    2007-08-16T23:59:59.000Z

    Aluminum is produced in electrolytic reduction cells where alumina feedstock is dissolved in molten cryolite (sodium aluminum fluoride) along with aluminum and calcium fluorides. The dissolved alumina is then reduced by electrolysis and the molten aluminum separates to the bottom of the cell. The reduction cell is periodically tapped to remove the molten aluminum. During the tapping process, some of the molten electrolyte (commonly referred as “bath” in the aluminum industry) is carried over with the molten aluminum and into the transfer crucible. The carryover of molten bath into the holding furnace can create significant operational problems in aluminum cast houses. Bath carryover can result in several problems. The most troublesome problem is sodium and calcium pickup in magnesium-bearing alloys. Magnesium alloying additions can result in Mg-Na and Mg-Ca exchange reactions with the molten bath, which results in the undesirable pickup of elemental sodium and calcium. This final report presents the findings of a project to evaluate removal of molten bath using a new and novel micro-porous filter media. The theory of selective adsorption or removal is based on interfacial surface energy differences of molten aluminum and bath on the micro-porous filter structure. This report describes the theory of the selective adsorption-filtration process, the development of suitable micro-porous filter media, and the operational results obtained with a micro-porous bed filtration system. The micro-porous filter media was found to very effectively remove molten sodium aluminum fluoride bath by the selective adsorption-filtration mechanism.

  13. Cleaning Cesium Radionuclides from BN-350 Primary Sodium

    SciTech Connect (OSTI)

    Romanenko, O.G.; Allen, K.J.; Wachs, D.M.; Planchon, H.P.; Wells, P.B.; Michelbacher, J.A.; Nazarenko, P.; Dumchev, I.; Maev, V.; Zemtzev, B.; Tikhomirov, L.; Yakovlev, V.; Synkov, A

    2005-04-15T23:59:59.000Z

    This paper reports the successful design and operation of a system to remove highly radioactive cesium from the sodium coolant of the BN-350 reactor in Aktau, Kazakhstan. As an international effort between the United States and the Republic of Kazakhstan, a cesium-trapping system was jointly designed, fabricated, installed, and successfully operated. The results are significant for a number of reasons, including (a) a significant reduction of radioactivity levels of the BN-350 coolant and reactor surfaces, thereby reducing exposure to workers during shutdown operations; (b) demonstration of scientific ideas; and (c) the engineering application of effective cesium trap deployment for commercial-sized liquid-metal reactors. About 255 300 GBq (6900 Ci) of cesium was trapped, and the {sup 137}Cs specific activity in BN-350 primary sodium was decreased from 296 MBq/kg (8000 {mu}Ci/kg) to 0.37 MBq/kg (10 {mu}Ci/kg) by using seven cesium traps containing reticulated vitreous carbon (RVC) as the cesium adsorbent. Cesium trapping was accomplished by pumping sodium from the primary circuit, passing it through a block of RVC within each trap, and returning the cleaned sodium to the primary circuit. Both to predict and to analyze the behavior of the cesium traps in the BN-350 reactor primary circuit, a model was developed that satisfactorily describes the observed results of the cesium trapping. By using this model, thermodynamic parameters, such as the heat of adsorption of cesium atoms on RVC and on internal piping surfaces of the BN-350 reactor primary circuit, -22.7 and -5.0 kJ/mole, respectively, were extracted from the experimental data.

  14. E-Print Network 3.0 - alkali atom vapor Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a vapor cell magneto-optical trap. 1999 American... to the vacuum pumps or due to adsorption of the ... Source: Jin, Deborah - JILA, University of Colorado at Boulder...

  15. Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors

    SciTech Connect (OSTI)

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-10-14T23:59:59.000Z

    A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H.sub.2, CH.sub.4, CO, CO.sub.2, ammonia and hydrogen sulfide.

  16. LABORATORY TESTING TO SIMULATE VAPOR SPACE CORROSION IN RADIOACTIVE WASTE STORAGE TANKS

    SciTech Connect (OSTI)

    Wiersma, B.; Garcia-Diaz, B.; Gray, J.

    2013-08-30T23:59:59.000Z

    Radioactive liquid waste has been stored in underground carbon steel tanks for nearly 70 years at the Hanford nuclear facility. Vapor space corrosion of the tank walls has emerged as an ongoing challenge to overcome in maintaining the structural integrity of these tanks. The interaction between corrosive and inhibitor species in condensates/supernates on the tank wall above the liquid level, and their interaction with vapor phase constituents as the liquid evaporates from the tank wall influences the formation of corrosion products and the corrosion of the carbon steel. An effort is underway to gain an understanding of the mechanism of vapor space corrosion. Localized corrosion, in the form of pitting, is of particular interest in the vapor space. CPP testing was utilized to determine the susceptibility of the steel in a simulated vapor space environment. The tests also investigated the impact of ammonia gas in the vapor space area on the corrosion of the steel. Vapor space coupon tests were also performed to investigate the evolution of the corrosion products during longer term exposures. These tests were also conducted at vapor space ammonia levels of 50 and 550 ppm NH{sub 3} (0.005, and 0.055 vol.%) in air. Ammonia was shown to mitigate vapor space corrosion.

  17. E-Print Network 3.0 - acoustic wave vapor Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (6). While previous systems have demonstrated success in chemical... striking visual identification of a range of ligating vapors (including alcohols, amines, ethers... ,...

  18. E-Print Network 3.0 - asssited chemical vapor Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nitride, chemical vapor ... Source: Dandy, David - Department of Chemical Engineering, Colorado State University Collection: Materials Science 14 DEPOSITION OF ELECTRON BEAM...

  19. E-Print Network 3.0 - all-hot-wire chemical vapor Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nitride, chemical vapor ... Source: Dandy, David - Department of Chemical Engineering, Colorado State University Collection: Materials Science 10 DEPOSITION OF ELECTRON BEAM...

  20. E-Print Network 3.0 - atomic vapor deposited Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    S. S. - School of Nuclear Engineering, Purdue University Collection: Plasma Physics and Fusion 8 Influence of substrate temperature on the stability of glasses prepared by vapor...

  1. Synthesis and Characterization of Magnetic Nanowires Prepared by Chemical Vapor Deposition.

    E-Print Network [OSTI]

    Tang, Siwei

    2014-01-01T23:59:59.000Z

    ??Various metal silicide and germanide magnetic nanowires were synthesized using a home-built CVD [chemical vapor deposition] system. The morphology, composition, and magnetic properties of the… (more)

  2. E-Print Network 3.0 - activated chemical vapor Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Orgainc vapor; Adsorption capacity 1. Introduction... containing a variety of organic chemicals. In ... Source: Cal, Mark P. - Department of Civil and Environmental Engineering,...

  3. Liquid fuel vaporizer and combustion chamber having an adjustable thermal conductor

    DOE Patents [OSTI]

    Powell, Michael R; Whyatt, Greg A; Howe, Daniel T; Fountain, Matthew S

    2014-03-04T23:59:59.000Z

    The efficiency and effectiveness of apparatuses for vaporizing and combusting liquid fuel can be improved using thermal conductors. For example, an apparatus having a liquid fuel vaporizer and a combustion chamber can be characterized by a thermal conductor that conducts heat from the combustion chamber to the vaporizer. The thermal conductor can be a movable member positioned at an insertion depth within the combustion chamber that corresponds to a rate of heat conduction from the combustion chamber to the vaporizer. The rate of heat conduction can, therefore, be adjusted by positioning the movable member at a different insertion depth.

  4. Towards improved spinnability of chemical vapor deposition generated multi-walled carbon nanotubes

    E-Print Network [OSTI]

    McKee, Gregg Sturdivant Burke

    2008-01-01T23:59:59.000Z

    P. J. F. 1999 Carbon nanotubes and related structures: newof vapor grown carbon nanotubes and single wall nanotubes, Eto Carbon Materials in Carbon Nanotubes: Preparation and

  5. Chemical vapor deposition of organosilicon composite thin films for porous low-k dielectrics

    E-Print Network [OSTI]

    Ross, April Denise, 1977-

    2005-01-01T23:59:59.000Z

    Pulsed plasma enhanced chemical vapor deposition has produced organosilicon thin films with the potential use as low dielectric constant interconnect materials in microelectronic circuits. Both diethylsilane and ...

  6. E-Print Network 3.0 - alkali vapor species Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Volume 4, novembre 1994 Summary: 60 specines aged at elevated temperatures in alkali-metal vapors have shown that such treatmerlt... -T superconductivity in C specimens annealed...

  7. E-Print Network 3.0 - acetone vapor sensing Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -0150 The photophysics of vapor and liquid acetone are experimentally examined from subcritical to supercritical... injection and mixing. The fluorescence quantum yield for...

  8. Numerical modeling of water injection into vapor-dominated geothermal reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01T23:59:59.000Z

    Renewable Energy, Office of Geothermal Technologies, of theTransport in Fractured Geothermal Reservoirs, Geothermics,Depletion of Vapor-Dominated Geothermal Reservoirs, Lawrence

  9. The Patuha geothermal system: a numerical model of a vapor-dominated system.

    E-Print Network [OSTI]

    Schotanus, M.R.J.

    2013-01-01T23:59:59.000Z

    ??The Patuha geothermal system is a vapor-dominated reservoir located about 40 kilometers southwest of Bandung on western Java, Indonesia. The geothermal system consists of a… (more)

  10. Gas chromatographic-mass spectrometric characterization of an oil aerosol-vapor microbial disinfectant .

    E-Print Network [OSTI]

    Wadhwa, Prakash, 1980-

    2005-01-01T23:59:59.000Z

    ??"This thesis focuses on chemical characterization studies of disinfectant vapors generated from thermal oxidation of mineral oil and biogenic oil esters. The disinfection technique holds… (more)

  11. Sodium boiling dryout correlation for LMFBR fuel assemblies

    SciTech Connect (OSTI)

    Carbajo, J.J.; Rose, S.D.

    1984-01-01T23:59:59.000Z

    Under certain postulated accident conditions for a Liquid Metal Fast Breeder Reactor (LMFBR), such as the failure of the shutdown heat removal system (SHRS), sodium boiling and clad dryout might occur in the fuel assemblies. It is important to predict the time from boiling inception to dryout, since sustained clad dryout will result in core damage. In this paper a dryout correlation is presented. This correlation is based on 21 boiling tests which resulted in dryout from the THORS BUNDLE 6A, a 19-pin full-length simulated LMFBR fuel assembly and from the THORS Bundle 9, a 61-pin full-length simulated LMFBR fuel assembly. All these tests were performed as follows: for each specified bundle power, an initial steady-state high sodium flow was established, for which sodium boiling did not occur in the bundle. The temperature at the outlet of the test section was approx. 700/sup 0/C. Then, using a programmable pump control system, the flow was reduced to a low value and boiling occurred.

  12. Sodium-Bearing Waste Treatment, Applied Technology Plan

    SciTech Connect (OSTI)

    Lance Lauerhass; Vince C. Maio; S. Kenneth Merrill; Arlin L. Olson; Keith J. Perry

    2003-06-01T23:59:59.000Z

    Settlement Agreement between the Department of Energy and the State of Idaho mandates treatment of sodium-bearing waste at the Idaho Nuclear Technology and Engineering Center within the Idaho National Engineering and Environmental Laboratory. One of the requirements of the Settlement Agreement is to complete treatment of sodium-bearing waste by December 31, 2012. Applied technology activities are required to provide the data necessary to complete conceptual design of four identified alternative processes and to select the preferred alternative. To provide a technically defensible path forward for the selection of a treatment process and for the collection of needed data, an applied technology plan is required. This document presents that plan, identifying key elements of the decision process and the steps necessary to obtain the required data in support of both the decision and the conceptual design. The Sodium-Bearing Waste Treatment Applied Technology Plan has been prepared to provide a description/roadmap of the treatment alternative selection process. The plan details the results of risk analyzes and the resulting prioritized uncertainties. It presents a high-level flow diagram governing the technology decision process, as well as detailed roadmaps for each technology. The roadmaps describe the technical steps necessary in obtaining data to quantify and reduce the technical uncertainties associated with each alternative treatment process. This plan also describes the final products that will be delivered to the Department of Energy Idaho Operations Office in support of the office's selection of the final treatment technology.

  13. Prediction of blast damage from vapor cloud explosions

    SciTech Connect (OSTI)

    Phillips, H. [Phillips (H.), Buxton (United Kingdom)

    1995-12-31T23:59:59.000Z

    The process industries handle a wide range of different materials and use them in different types of chemical reaction. Of particular concern is the prospect of damage and injury affecting the general public outside the boundary wall of the chemical plant. It is not wise to permit the construction of homes, schools or hospitals so close to chemical plants that they, and the people within, might be damaged or injured should there be an accidental explosion in the plant. The major hazard outside the plant is over-pressure, a consequence of an accidental explosion in a cloud of flammable gas or vapor (Vapor Cloud Explosion or VCE). It is the responsibility of plant management to ensure that any such accidental explosion is not so large as to endanger the public, and of the local planning authorities to ensure that homes, schools or hospitals are not sited so close to chemical plants that they may be endangered by accidental explosion. A vital tool for such authorities is a simple method of assessing the possible consequences of an accidental VCE. In this paper those methods of assessing the consequences are examined.

  14. Method of physical vapor deposition of metal oxides on semiconductors

    DOE Patents [OSTI]

    Norton, David P. (Knoxville, TN)

    2001-01-01T23:59:59.000Z

    A process for growing a metal oxide thin film upon a semiconductor surface with a physical vapor deposition technique in a high-vacuum environment and a structure formed with the process involves the steps of heating the semiconductor surface and introducing hydrogen gas into the high-vacuum environment to develop conditions at the semiconductor surface which are favorable for growing the desired metal oxide upon the semiconductor surface yet is unfavorable for the formation of any native oxides upon the semiconductor. More specifically, the temperature of the semiconductor surface and the ratio of hydrogen partial pressure to water pressure within the vacuum environment are high enough to render the formation of native oxides on the semiconductor surface thermodynamically unstable yet are not so high that the formation of the desired metal oxide on the semiconductor surface is thermodynamically unstable. Having established these conditions, constituent atoms of the metal oxide to be deposited upon the semiconductor surface are directed toward the surface of the semiconductor by a physical vapor deposition technique so that the atoms come to rest upon the semiconductor surface as a thin film of metal oxide with no native oxide at the semiconductor surface/thin film interface. An example of a structure formed by this method includes an epitaxial thin film of (001)-oriented CeO.sub.2 overlying a substrate of (001) Ge.

  15. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2001-06-01T23:59:59.000Z

    Disposal of high-level nuclear waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  16. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2000-06-01T23:59:59.000Z

    Disposal of high- level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid- liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  17. Vapor Pressures and Vaporization Enthalpies of the n-Alkanes from C21 to C30 at T ) 298.15 K by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    by Correlation Gas Chromatography James S. Chickos* and William Hanshaw Department of Chemistry and Biochemistry. Sublimation enthalpies for n-C17 to n-C30 are calculated by combining vaporization enthalpies with fusion

  18. Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols: The Vaporization Enthalpy of 1-, 6-, 7-, and 9-Heptadecanol,

    E-Print Network [OSTI]

    Chickos, James S.

    Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols* Department of Chemistry and Biochemistry, University of MissourisSt. Louis, St. Louis, Missouri 63121 sublimation enthalpies. The sublimation enthalpies were compared to existing literature values. Agreement

  19. DOCUMENT DE TRAVAIL -L.E.S.T.-UMR 6123 !"#$#%&'(0)&123# #$ 4 5 6789$46&9 '(A@12BDCDEF6&GH I9P"QDRTS S UVBW)9CX@X`YacbFBcRedfBcDS gFhRed`iRpiRTqFReb rs&5 Ptvuw6&#v6&xtwyDP @DP CHP #EP yy`BDQ36w twyDP @HP"@XHP #DP 02 e&9d e fg$ehji k9l

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    &¢#v6&¨xtwy¥DP ¥@DP C¥HP #E¥P y¥y`BDQ36w twy¥DP ¥@HP"@¥XHP #DP 02 e&9d e f£g$ehji k9l m (n2t oo c5

  20. Polymer electrolyte fuel cell electrodes grown by vapor deposition techniques Pascal Brault*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Polymer electrolyte fuel cell electrodes grown by vapor deposition techniques Pascal Brault Abstract: Polymer fuel cell electrode growth using vapor deposition techniques is reviewed. The supports process: sputtering, CVD, PECVD, MOCVD. In each case, up-to-date fuel cell performances are highlighted

  1. Lithium phosphorous oxynitride films synthesized by a plasma-assisted directed vapor deposition approach

    E-Print Network [OSTI]

    Wadley, Haydn

    Lithium phosphorous oxynitride films synthesized by a plasma-assisted directed vapor deposition vapor deposition approach has been explored for the synthesis of lithium phosphorous oxynitride Lipon the ionic transport properties of these films. This enabled the synthesis of electrolyte films with lithium

  2. Tank 241-U-106 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-U-106. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  3. Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis

    E-Print Network [OSTI]

    Romalis, Mike

    Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis; published 7 December 2010) Optical pumping of an optically thick atomic vapor typically requires a quenching the atoms. We show that optical pumping of a trace contamination of Rb present in K metal results in a 4

  4. Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated

    E-Print Network [OSTI]

    Cal, Mark P.

    Chem. Mater. 1995, 7, 2269-2272 2269 Water Vapor Adsorption on Chemically Treated Activated Carbon August 25, 1995@ Water vapor adsorption on activated carbon cloth (ACCBO)which has been oxidized% Cl), and ACCBO (4% N), exhibits sigmoidal isotherms with hysteresis loops of varying magnitudes

  5. VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM

    E-Print Network [OSTI]

    (for water: the SPC-, SPC/E-, and TIP4P-potential models; for carbon dioxide: the EPM2 potential model dioxide are calculated. For water, the SPC- and TIP4P-models give superior results for the vapor pressure when compared to the SPC/E-model. The vapor liquid equilibrium of the binary mixture carbon dioxide

  6. Shock wave induced vaporization of porous solids Andy H. Shen, a)

    E-Print Network [OSTI]

    Stewart, Sarah T.

    to reach high entropy, vaporized states in impact experiments. We extended calculations by Ahrens J. Appl such as Earth.1­3 During collision events, kinetic energy is converted into internal energy and such conversion spectrometry. More re- cently, the vapor products generated from a hypervelocity impact of electrostatically

  7. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08T23:59:59.000Z

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  8. Low temperature chemical vapor deposition of Co thin films from Co2(CO)8

    E-Print Network [OSTI]

    Wang, Gwo-Ching

    Low temperature chemical vapor deposition of Co thin films from Co2(CO)8 D.-X. Yea,*, S. Pimanpanga chemical vapor deposition with a metallorganic Co2(CO)8 precursor. After Ar sputtering of the surface, Co2(CO)8, has been extensively used in cobalt CVD and is attractive, since Co is in its elemental

  9. Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from MODIS

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Cloud and Aerosol Properties, Precipitable Water, and Profiles of Temperature and Water Vapor from such as cloud mask, atmos- pheric profiles, aerosol properties, total precipitable water, and cloud properties vapor amount, aerosol particles, and the subsequently formed clouds [9]. Barnes et al. [2] provide

  10. Tunneling characteristics in chemical vapor deposited graphene hexagonal boron nitride graphene junctions

    E-Print Network [OSTI]

    Feenstra, Randall

    1 Tunneling characteristics in chemical vapor deposited graphene ­ hexagonal boron nitride ­ graphene junctions T. Roy1 , L. Liu2 , S. de la Barrera,3 B. Chakrabarti1,4 , Z. R. Hesabi1 , C. A. Joiner1 Abstract: Large area chemical vapor deposited graphene and hexagonal boron nitride was used to fabricate

  11. Computational Analysis and Optimization of a Chemical Vapor Deposition Reactor with

    E-Print Network [OSTI]

    Computational Analysis and Optimization of a Chemical Vapor Deposition Reactor with Large and optimization of a three- dimensional model of a horizontal chemical vapor deposition (CVD) reactor used National Laboratories February 9, 2004 Abstract A computational analysis and optimization is presented

  12. Optimization of the chemical vapor deposition process for carbon nanotubes fabrication

    E-Print Network [OSTI]

    Grujicic, Mica

    Optimization of the chemical vapor deposition process for carbon nanotubes fabrication M. Grujicica-phase chemistry and surface chemistry model is developed to analyze, at the reactor length scale, chemical vapor (carrier gas) in the presence of cobalt catalytic particles in a cylindrical reactor. The model allows

  13. OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR

    E-Print Network [OSTI]

    OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR K.J. BACHMANN of computer simulations as an optimal design tool which lessens the costs in time and effort in experimental vapor deposition (HPOMCVD) reactor for use in thin film crystal growth. The advantages of such a reactor

  14. On the optimization of a dc arcjet diamond chemical vapor deposition reactor

    E-Print Network [OSTI]

    Dandy, David

    On the optimization of a dc arcjet diamond chemical vapor deposition reactor S. W. Reevea) and W. A precursor in our dc arcjet reactor.1 Based on conclusions drawn from that work, an optimization strategy diamond film growth in a dc arcjet chemical vapor deposition reactor has been developed. Introducing

  15. Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry

    DOE Patents [OSTI]

    Yeung, E.S.; Chang, Y.C.

    1999-06-29T23:59:59.000Z

    The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent. 8 figs.

  16. An Examination of the Thermodynamics of Fusion, Vaporization, and Sublimation of Several Parabens by Correlation Gas

    E-Print Network [OSTI]

    Chickos, James S.

    An Examination of the Thermodynamics of Fusion, Vaporization, and Sublimation of Several Parabens, Kasetsart University, Bangkane, Bangkok 10900, Thailand 2 Department of Chemistry and Biochemistry.com). DOI 10.1002/jps.22423 ABSTRACT: The vaporization, fusion, and sublimation enthalpies of methyl, ethyl

  17. Method and apparatus to measure vapor pressure in a flow system

    DOE Patents [OSTI]

    Grossman, M.W.; Biblarz, O.

    1991-10-15T23:59:59.000Z

    The present invention is directed to a method for determining, by a condensation method, the vapor pressure of a material with a known vapor pressure versus temperature characteristic, in a flow system particularly in a mercury isotope enrichment process. 2 figures.

  18. Apparatus and method for removing mercury vapor from a gas stream

    DOE Patents [OSTI]

    Ganesan, Kumar (Butte, MT)

    2008-01-01T23:59:59.000Z

    A metallic filter effectively removes mercury vapor from gas streams. The filter captures the mercury which then can be released and collected as product. The metallic filter is a copper mesh sponge plated with a six micrometer thickness of gold. The filter removes up to 90% of mercury vapor from a mercury contaminated gas stream.

  19. Researchers develop electrodeposition process to deposit coatings on substrates, eliminate the expensive physical vapor

    E-Print Network [OSTI]

    the expensive physical vapor deposition step, and improve device quality. CuIn1-xGaxSe2 (CIGS) solar cells have composition was adjusted by physical vapor deposition method. At present, we are fabricating CIGS-based solar). 2 R. N. Bhattacharya, W. Batchelor, J. F. Hiltner, and J. R. Sites, Appl. Phys. Lett., 75, 1431

  20. Real-time growth rate metrology for a tungsten chemical vapor deposition process by acoustic sensing

    E-Print Network [OSTI]

    Rubloff, Gary W.

    to a production-scale tungsten chemical vapor deposition cluster tool for in situ process sensing. Process gasesReal-time growth rate metrology for a tungsten chemical vapor deposition process by acoustic to achieve run-to-run process control of the deposited tungsten film thickness. © 2001 American Vacuum

  1. Isothermal vapor-liquid equilibrium accompanied by esterification; ethanol-formic acid system

    SciTech Connect (OSTI)

    Rim, J.K.; Bae, S.Y.; Lee, H.T.

    1985-07-01T23:59:59.000Z

    The equilibrium total pressures after reaction between ethanol and formic acid were measured at 30, 40 and 50/sup 0/C, and the compositions of the vapor and liquid phases were determined gas chromatographically. Since the presence of the carboxylic acid in the mixture induces dimerization and trimerization of the acid in the vapor phase, the modified fugacity coefficients were calculated from ''chemical'' theory using the Lewis fugacity rule, from which are calculated the activity coefficients and the vapor-phase mole fractions using the nonrandom, two-liquid (NRTL) equation. The parameters in the NRTL equation were obtained from vapor-liquid equilibrium data for the binary system. The calculated results agree closely with the experimental vapor-phase mole-fraction data.

  2. Method and apparatus for detection of chemical vapors

    DOE Patents [OSTI]

    Mahurin, Shannon Mark (Knoxville, TN); Dai, Sheng (Knoxville, TN); Caja, Josip (Knoxville, TN)

    2007-05-15T23:59:59.000Z

    The present invention is a gas detector and method for using the gas detector for detecting and identifying volatile organic and/or volatile inorganic substances present in unknown vapors in an environment. The gas detector comprises a sensing means and a detecting means for detecting electrical capacitance variance of the sensing means and for further identifying the volatile organic and volatile inorganic substances. The sensing means comprises at least one sensing unit and a sensing material allocated therein the sensing unit. The sensing material is an ionic liquid which is exposed to the environment and is capable of dissolving a quantity of said volatile substance upon exposure thereto. The sensing means constitutes an electrochemical capacitor and the detecting means is in electrical communication with the sensing means.

  3. Strain relaxation in graphene grown by chemical vapor deposition

    SciTech Connect (OSTI)

    Troppenz, Gerald V., E-mail: gerald.troppenz@helmholtz-berlin.de; Gluba, Marc A.; Kraft, Marco; Rappich, Jörg; Nickel, Norbert H. [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Institut für Silizium Photovoltaik, Kekuléstr. 5, D-12489 Berlin (Germany)

    2013-12-07T23:59:59.000Z

    The growth of single layer graphene by chemical vapor deposition on polycrystalline Cu substrates induces large internal biaxial compressive strain due to thermal expansion mismatch. Raman backscattering spectroscopy and atomic force microscopy were used to study the strain relaxation during and after the transfer process from Cu foil to SiO{sub 2}. Interestingly, the growth of graphene results in a pronounced ripple structure on the Cu substrate that is indicative of strain relaxation of about 0.76% during the cooling from the growth temperature. Removing graphene from the Cu substrates and transferring it to SiO{sub 2} results in a shift of the 2D phonon line by 27?cm{sup ?1} to lower frequencies. This translates into additional strain relaxation. The influence of the processing steps, used etching solution and solvents on strain, is investigated.

  4. Discrete Boltzmann modeling of liquid-vapor system

    E-Print Network [OSTI]

    Aiguo Xu; Guangcai Zhang; Yanbiao Gan

    2014-03-15T23:59:59.000Z

    We further probe the Discrete Boltzmann Modeling(DBM) of the single-component two phase flows or the liquid-vapor system. There are two kinds of nonequilibrium effects in the system. The first is the Mechanical NonEquilibrium(MNE). The second is the Thermodynamic NonEquilibrium(TNE). The MNE is well described in the traditional fluid dynamic theory. The description of TNE resorts to the gas kinetic theory. Since based on the Boltzmann equation, the DBM makes possible to analyze both the MNE and TNE. The TNE is the main discussion of this work. A major purpose of this work is to show that the DBM results can be used to confirm and/or improve the macroscopic modeling of complex system.

  5. Field emission properties of chemical vapor deposited individual graphene

    SciTech Connect (OSTI)

    Zamri Yusop, Mohd [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan); Department of Materials, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor (Malaysia); Kalita, Golap, E-mail: kalita.golap@nitech.ac.jp [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan); Center for Fostering Young and Innovative Researchers, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan); Yaakob, Yazid; Takahashi, Chisato; Tanemura, Masaki [Department of Frontier Materials, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, 466-8555 Nagoya (Japan)

    2014-03-03T23:59:59.000Z

    Here, we report field emission (FE) properties of a chemical vapor deposited individual graphene investigated by in-situ transmission electron microscopy. Free-standing bilayer graphene is mounted on a cathode microprobe and FE processes are investigated varying the vacuum gap of cathode and anode. The threshold field for 10?nA current were found to be 515, 610, and 870?V/?m for vacuum gap of 400, 300, and 200?nm, respectively. It is observed that the structural stability of a high quality bilayer graphene is considerably stable during emission process. By contacting the nanoprobe with graphene and applying a bias voltage, structural deformation and buckling are observed with significant rise in temperature owing to Joule heating effect. The finding can be significant for practical application of graphene related materials in emitter based devices as well as understanding the contact resistance influence and heating effect.

  6. Feasibility of UV lasing without inversion in mercury vapor

    E-Print Network [OSTI]

    Martin R. Sturm; Benjamin Rein; Thomas Walther; Reinhold Walser

    2014-06-27T23:59:59.000Z

    We investigate the feasibility of UV lasing without inversion at a wavelength of $253.7$ nm utilizing interacting dark resonances in mercury vapor. Our theoretical analysis starts with radiation damped optical Bloch equations for all relevant 13 atomic levels. These master equations are generalized by considering technical phase noise of the driving lasers. From the Doppler broadened complex susceptibility we obtain the stationary output power from semiclassical laser theory. The finite overlap of the driving Gaussian laser beams defines an ellipsoidal inhomogeneous gain distribution. Therefore, we evaluate the intra-cavity field inside a ring laser self-consistently with Fourier optics. This analysis confirms the feasibility of UV lasing and reveals its dependence on experimental parameters.

  7. Technology alternatives to CFC/HCFC vapor compression

    SciTech Connect (OSTI)

    Fischer, S.

    1996-08-01T23:59:59.000Z

    Phaseouts of CFCs and HCFCs to protect the stratospheric ozone layer have caused many developments in replacement or alternative technologies for heat pumping. Some of this effort has been of an ``evolutionary`` nature where the designs of conventional vapor compression systems were adapted to use chlorine-free refrigerants. Other alternatives are more radical departures from conventional practice such as operating above the critical point of an alternative refrigerant. Revolutionary changes in technology based on cycles sor principles not commonly associated with refrigeration have also attracted interest. Many of these technologies are being touted because they are ``ozone-safe`` or because they do not use greenhouse gases as refrigerants. Basic principles and some advantages and disadvantages of each technology are discussed in this paper.

  8. Analysis of crude oil vapor pressures at the U.S. Strategic Petroleum Reserve.

    SciTech Connect (OSTI)

    Rudeen, David Keith (GRAM, Inc., Albuquerque, NM); Lord, David L.

    2005-08-01T23:59:59.000Z

    Crude oil storage caverns at the U.S. Strategic Petroleum Reserve (SPR) are solution-mined from subsurface salt domes along the U.S. Gulf Coast. While these salt domes exhibit many attractive characteristics for large-volume, long-term storage of oil such as low cost for construction, low permeability for effective fluids containment, and secure location deep underground, they also present unique technical challenges for maintaining oil quality within delivery standards. The vapor pressures of the crude oils stored at SPR tend to increase with storage time due to the combined effects of geothermal heating and gas intrusion from the surrounding salt. This presents a problem for oil delivery offsite because high vapor-pressure oil may lead to excessive atmospheric emissions of hydrocarbon gases that present explosion hazards, health hazards, and handling problems at atmospheric pressure. Recognizing this potential hazard, the U.S. Department of Energy, owner and operator of the SPR, implemented a crude oil vapor pressure monitoring program that collects vapor pressure data for all the storage caverns. From these data, DOE evaluates the rate of change in vapor pressures of its oils in the SPR. Moreover, DOE implemented a vapor pressure mitigation program in which the oils are degassed periodically and will be cooled immediately prior to delivery in order to reduce the vapor pressure to safe handling levels. The work described in this report evaluates the entire database since its origin in 1993, and determines the current levels of vapor pressure around the SPR, as well as the rate of change for purposes of optimizing both the mitigation program and meeting safe delivery standards. Generally, the rate of vapor pressure increase appears to be lower in this analysis than reported in the past and, problematic gas intrusion seems to be limited to just a few caverns. This being said, much of the current SPR inventory exceeds vapor pressure delivery guidelines and must be degassed and cooled in order to meet current delivery standards.

  9. Vaporization modeling of petroleum-biofuel drops using a hybrid multi-component approach

    SciTech Connect (OSTI)

    Zhang, Lei; Kong, Song-Charng [Department of Mechanical Engineering, Iowa State University, 2025 Black Engineering Building, Ames, IA 50011 (United States)

    2010-11-15T23:59:59.000Z

    Numerical modeling of the vaporization characteristics of multi-component fuel mixtures is performed in this study. The fuel mixtures studied include those of binary components, biodiesel, diesel-biodiesel, and gasoline-ethanol. The use of biofuels has become increasingly important for reasons of environmental sustainability. Biofuels are often blended with petroleum fuels, and the detailed understanding of the vaporization process is essential to designing a clean and efficient combustion system. In this study, a hybrid vaporization model is developed that uses continuous thermodynamics to describe petroleum fuels and discrete components to represent biofuels. The model is validated using the experimental data of n-heptane, n-heptane-n-decane mixture, and biodiesel. Since biodiesel properties are not universal due to the variation in feedstock, methods for predicting biodiesel properties based on the five dominant fatty acid components are introduced. Good levels of agreement in the predicted and measured drop size histories are obtained. Furthermore, in modeling the diesel-biodiesel drop, results show that the drop lifetime increases with the biodiesel concentration in the blend. During vaporization, only the lighter components of diesel fuel vaporize at the beginning. Biodiesel components do not vaporize until some time during the vaporization process. On the other hand, results of gasoline-ethanol drops indicate that both fuels start to vaporize once the process begins. At the beginning, the lighter components of gasoline have a slightly higher vaporization rate than ethanol. After a certain time, ethanol vaporizes faster than the remaining gasoline components. At the end, the drop reduces to a regular gasoline drop with heavier components. Overall, the drop lifetime increases as the concentration of ethanol increases in the drop due to the higher latent heat. (author)

  10. Practical features of illumination with high pressure sodium lamps

    SciTech Connect (OSTI)

    Corth, R.

    1983-06-01T23:59:59.000Z

    A number of concerns raised about the health effects of high pressure sodium lamps (HPS) are discussed. The notion of a ''natural'' human photic environment based on sunlight is disputed. Humans are better adapted to the ''greenish'' spectral composition of forest light than to direct sunlight. It is ironic that the artificial light source which has received the most disapproval, cool white flourescent lamp, has a spectral composition similar to that of forest light. HPS is also available in a full range of colors. Some successful examples of HPS--from North Division High School, in Milwaukee, Wisconsin, to museum exhibits at National Geographic in Washington--are listed.

  11. Dynamic stability experiments in sodium-heated steam generators. [LMFBR

    SciTech Connect (OSTI)

    France, D.M.; Roy, R.; Carlson, R.D.; Chiang, T.

    1984-01-01T23:59:59.000Z

    Seventy-two dynamic stability tests were performed in the sodium-heated boiling-water test facility at Argonne National Laboratory. A full-scale LMFBR steam generator tube was employed as the test section operating over the water parameter ranges of 6.9 to 15.9 MPa pressure and 170 to 800 kg/m/sup 2/.s mass flux. The stability thresholds from the test compared well to the predictions of a modified version of a correlation equation recently published by other investigators. Typical experimental data and the modified correlation equation are presented.

  12. Interaction Between Trace Metals, Sodium and Sorbents in Combustion.

    SciTech Connect (OSTI)

    Wendt, O.L.; Davis, S.

    1997-10-17T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  13. Nanofriction on Sodium Polystyrene Sulfonate Brushes in Water

    E-Print Network [OSTI]

    Takuya Fujima; Eitaro Futakuchi; Fumihiro Kino

    2014-02-19T23:59:59.000Z

    We investigated the frictional properties of sodium polystyrene sulfonate (NaPSS) brushes in water by frictional force microscopy (FFM). Polyelectrolyte brushes were prepared on silicon wafers by the grafting-to method. The brushes considerably reduce the frictional force and coefficient of kinetic friction compared to hydrodynamic lubrication on a smooth Si wafer. Frictional force is independent of sliding speed, but is lower for lower degrees of NaPSS polymerization. Nanoindentation tests indicate that the polymer chains in a brush are stretched strongly away from the substrate. These results suggest that polymer chains point support the FFM probe tip in water and reduced contact area and friction.

  14. Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications. |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSite CulturalDepartment ofat Home |EMSL Sodium Ion Insertion

  15. ELECTROCHEMICAL RESEARCH IN CHEMICAL HYDROGEN STORAGE MATERIALS: SODIUM BOROHYDRIDE AND ORGANOTIN HYDRIDES.

    E-Print Network [OSTI]

    McLafferty, Jason

    2009-01-01T23:59:59.000Z

    ??Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane… (more)

  16. E-Print Network 3.0 - affecting sodium hypochlorite Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workshop Summary: equipment, vehicles Sodium hypochlorite (bleach) 200-500 ppm Nets, boots, clothing. Surfaces must be clean... hypochlorite solution.Note: Bleach is 5.25%...

  17. E-Print Network 3.0 - alkaline sodium borohydride Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aardahl, PNNL) The most critical hurdle for the use of sodium ... Source: DOE Office of Energy Efficiency and Renewable Energy, Hydrogen, Fuel Cells and Infrastructure...

  18. E-Print Network 3.0 - aluminum sodium chloride Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    agents Water Acetyl chloride, alkaline and alkaline... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium ... Source: Hall, Sharon J. - School of Life Sciences, Arizona...

  19. ADVANCES IN ATMOSPHERIC SCIENCES, VOL. 24, NO. 3, 2007, 509526 Variational Assimilation of GPS Precipitable Water Vapor and

    E-Print Network [OSTI]

    Precipitable Water Vapor and Hourly Rainfall Observations for a Meso- Scale Heavy Precipitation Event During Atmospheric water vapor plays a significant role in numerical weather predictions (NWP) of heavy rain- fall of the precipitable water vapor (PWV) from delayed signals transmitted by GPS satellites, which can be assimilated

  20. REACTIONS OF SODIUM PEROXIDE WITH COMPONENTS OF LEGACY PLUTONIUM MATERIALS

    SciTech Connect (OSTI)

    Pierce, R.; Missimer, D.; Crowder, M.

    2011-10-04T23:59:59.000Z

    Plutonium oxide (PuO{sub 2}) calcined at >900 C resists dissolution in nitric acid (HNO{sub 3})-potassium fluoride (KF) solutions, a common method for their dissolution. The Savannah River National Laboratory (SRNL) has developed an alternate method for large samples of PuO{sub 2}-bearing materials using sodium peroxide (Na{sub 2}O{sub 2}) fusion as a pretreatment. The products of the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} have been reported in the literature. As part of the SRNL development effort, additional data about the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} were required. Also needed were data concerning the reaction of Na{sub 2}O{sub 2} with other components that may be present in the feed materials. Sodium peroxide was reacted with aluminum metal (Al), beryllium metal (Be), graphite, potassium chloride (KCl), magnesium chloride (MgCl{sub 2}), and calcium chloride (CaCl{sub 2}). The paper reports and discusses the reaction products of these and related compounds with Na{sub 2}O{sub 2}.

  1. Sodium fast reactor safety and licensing research plan. Volume I.

    SciTech Connect (OSTI)

    Sofu, Tanju (Argonne National Laboratory, Argonne, IL); LaChance, Jeffrey L.; Bari, R. (Brokhaven National Laboratory Upton, NY); Wigeland, Roald (Idaho National Laboratory, Idaho Falls, ID); Denman, Matthew R.; Flanagan, George F. (Oak Ridge National Laboratory, Oak Ridge, TN)

    2012-05-01T23:59:59.000Z

    This report proposes potential research priorities for the Department of Energy (DOE) with the intent of improving the licensability of the Sodium Fast Reactor (SFR). In support of this project, five panels were tasked with identifying potential safety-related gaps in available information, data, and models needed to support the licensing of a SFR. The areas examined were sodium technology, accident sequences and initiators, source term characterization, codes and methods, and fuels and materials. It is the intent of this report to utilize a structured and transparent process that incorporates feedback from all interested stakeholders to suggest future funding priorities for the SFR research and development. While numerous gaps were identified, two cross-cutting gaps related to knowledge preservation were agreed upon by all panels and should be addressed in the near future. The first gap is a need to re-evaluate the current procedures for removing the Applied Technology designation from old documents. The second cross-cutting gap is the need for a robust Knowledge Management and Preservation system in all SFR research areas. Closure of these and the other identified gaps will require both a reprioritization of funding within DOE as well as a re-evaluation of existing bureaucratic procedures within the DOE associated with Applied Technology and Knowledge Management.

  2. Preliminary engineering design of sodium-cooled CANDLE core

    SciTech Connect (OSTI)

    Takaki, Naoyuki; Namekawa, Azuma; Yoda, Tomoyuki; Mizutani, Akihiko; Sekimoto, Hiroshi [Department of Nuclear Engineering, Tokai University, Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan); AISA, Fuchu, Ishioka, Ibaraki 315-0013 (Japan); Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo, 152-8550 (Japan)

    2012-06-06T23:59:59.000Z

    The CANDLE burning process is characterized by the autonomous shifting of burning region with constant reactivity and constant spacial power distribution. Evaluations of such critical burning process by using widely used neutron diffusion and burning codes under some realistic engineering constraints are valuable to confirm the technical feasibility of the CANDLE concept and to put the idea into concrete core design. In the first part of this paper, it is discussed that whether the sustainable and stable CANDLE burning process can be reproduced even by using conventional core analysis tools such as SLAROM and CITATION-FBR. As a result, it is certainly possible to demonstrate it if the proper core configuration and initial fuel composition required as CANDLE core are applied to the analysis. In the latter part, an example of a concrete image of sodium cooled, metal fuel, 2000MWt rating CANDLE core has been presented by assuming an emerging inevitable technology of recladding. The core satisfies engineering design criteria including cladding temperature, pressure drop, linear heat rate, and cumulative damage fraction (CDF) of cladding, fast neutron fluence and sodium void reactivity which are defined in the Japanese FBR design project. It can be concluded that it is feasible to design CANDLE core by using conventional codes while satisfying some realistic engineering design constraints assuming that recladding at certain time interval is technically feasible.

  3. TRUEX partitioning studies applied to ICPP sodium-bearing waste

    SciTech Connect (OSTI)

    Herbst, R.S.; Brewer, K.N.; Law, J.D.; Tranter, T.J.; Todd, T.A.

    1994-05-01T23:59:59.000Z

    The Idaho Chemical Processing Plant (ICPP), located in southeast Idaho at the USDOE Idaho National Engineering Laboratory, formerly reprocessed highly enriched spent nuclear fuel to recover fissionable uranium. The HLW raffinates from the combined PUREX/REDOX type uranium recovery process were converted to solid oxides (calcine) in a high temperature fluidized bed. Liquid effluents from the calcination process were combined with liquid sodium bearing waste (SBW) generated primarily in conjunction with decontamination activities. Due to the high sodium content in the SBW, this secondary waste stream is not directly amenable to solidification via calcination. Currently, approximately 1.5 millon gallons of liquid SBW are stored at the ICPP in large tanks. Several treatment options for the SBW are currently being considered, including the TRansUranic EXtraction (TRUEX) process developed by Horwitz and co-workers at Argonne National Laboratory (ANL), in preparation for the final disposition of SBW. Herein described are experimental results of radionuclide tracer studies with simulated SBW using the TRUEX process solvent.

  4. Selection of materials for sodium fast reactor steam generators

    SciTech Connect (OSTI)

    Dubiez-Le Goff, S.; Garnier, S.; Gelineau, O. [AREVA (France); Dalle, F. [Commissariat a l'energie atomique et aux energies alternatives - CEA (France); Blat-Yrieix, M.; Augem, J. M. [Electricite de France - EDF (France)

    2012-07-01T23:59:59.000Z

    Sodium Fast Reactor (SFR) is considered in France as the most mature technology of the different Generation IV systems. In the short-term the designing work is focused on the identification of the potential tracks to demonstrate licensing capability, availability, in-service inspection capability and economical performance. In that frame materials selection for the major components, as the steam generator, is a particularly key point managed within a French Research and Development program launched by AREVA, CEA and EDF. The choice of the material for the steam generator is indeed complex because various aspects shall be considered like mechanical and thermal properties at high temperature, interaction with sodium on one side and water and steam on the other side, resistance to wastage, procurement, fabrication, weldability and ability for inspection and in-situ intervention. The following relevant options are evaluated: the modified 9Cr1Mo ferritic-martensitic grade and the Alloy 800 austenitic grade. The objective of this paper is to assess for both candidates their abilities to reach the current SFR needs regarding material design data, from AFCEN RCC-MRx Code in particular, compatibility with environments and manufacturability. (authors)

  5. Latitudinal survey of middle atmospheric water vapor revealed by shipboard microwave spectroscopy. Master's thesis

    SciTech Connect (OSTI)

    Schrader, M.L.

    1994-05-01T23:59:59.000Z

    Water vapor is one of the most important greenhouse gases and is an important tracer of atmospheric motions in the middle atmosphere. It also plays an important role in the chemistry of the middle atmosphere and through its photodissociation by solar radiation, it is the major source of hydrogen escaping to space. Ground-based microwave measurements conducted in the 1980s have provided a fair understanding of the seasonal variation of mesospheric water vapor in the northern hemisphere mid-latitudes, but the global distribution of water vapor in the middle atmosphere is only beginning to be revealed by space-based measurements.

  6. Tank 241-BY-103 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-05T23:59:59.000Z

    Tank 241-BY-103 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-103 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  7. Models of the atmospheric water vapor budget for the Texas HIPLEX area: by Steven Francis Williams.

    E-Print Network [OSTI]

    Williams, Steven Francis

    1979-01-01T23:59:59.000Z

    co:erage cf. convective activ' ty, Thus, the em&unt of convection seems to be more important than the type oz pr"se. . ce of convective activi!y. An increased tran:port of water vapor near ti e surface is -hown to be an important factor... of watc-. z vapor tnrough each later, l boundary shown in Fig. 1 can be comput d by substituting Eqs. (16) ? (19), reaper tively, into Eq. (14) . Th ' net transport of water vapor 'nt the volume through la+eral oouccdaries or t?:e net horizontal tran:;port...

  8. Tank 241-BY-108 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    Tank 241-BY-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in ``Program Plan for the Resolution of Tank Vapor Issues`` (Osborne and Huckaby 1994). Tank 241-BY-108 was vapor sampled in accordance with ``Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution (Osborne et al., 1994).

  9. Tank 241-BY-105 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    Tank 241-BY-105 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-105 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  10. Tank 241-BY-107 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  11. Tank 241-BY-107 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-05T23:59:59.000Z

    Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues{close_quotes}. Tank 241-BY-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution{close_quotes}.

  12. Tank 241-BY-106 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    Tank 241-BY-106 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-106 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  13. Tank 241-BY-104 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    Tank 241-BY-104 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-104 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  14. Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

    DOE Patents [OSTI]

    Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

    2014-12-02T23:59:59.000Z

    The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

  15. A High Temperature (400 to 650oC) Secondary Storage Battery Based on Liquid Sodium and Potassium Anodes

    SciTech Connect (OSTI)

    Tao, Greg; Weber, Neill

    2007-06-08T23:59:59.000Z

    This STTR Phase I research program was on the development of high temperature (400 to 650 C), secondary batteries with roundtrip efficiency > 90% for integration with a 3 to 10 kW solid oxide fuel cell (SOFC) system. In fulfillment of this objective, advanced planar high temperature rechargeable batteries, comprised of an alkali metal ion conducting, highly refractory, beta'' alumina solid electrolyte (BASE) sandwiched between liquid sodium (or potassium) anode and liquid metal salt cathode, were developed at MSRI. The batteries have been successfully demonstrated at a working temperature as high as 600 C. To our knowledge, so far no work has been reported in the literature on planar rechargeable batteries based on BASE, and results obtained in Phase I for the very first time demonstrated the viability of planar batteries, though relatively low temperature tubular-based sodium-sulfur batteries and ZEBRA batteries have been actively developed by very limited non U.S. companies. The results of this Phase I work have fulfilled all the goals and stated objectives, and the achievements showed much promise for further, substantial improvements in battery design and performance. The important results of Phase I are briefly described in what follows: (1) Both Na-BASE and K-BASE discs and tubes have been successfully fabricated using MSRI's patented vapor phase process. Ionic conductivity measurements showed that Na-BASE had higher ionic conductivity than K-BASE, consistence with the literature. At 500 C, Na-BASE conductivity is 0.36 S/cm, which is more than 20 times higher than 8YSZ electrolyte used for SOFC at 800 C. The activation energy is 22.58 kJ/mol. (2) CuCl{sub 2}, FeCl{sub 2}, ZnCl{sub 2}, and AgCl were identified as suitable salts for Na/metal salt or K/metal salt electrochemical couples based on thermochemical data. Further open circuit voltage measurements matched those deduced from the thermochemical data. (3) Tubular cells with CuCl{sub 2} as the cathode and Na as the anode were constructed. However, it was discovered that CuCl{sub 2} was somewhat corrosive and dissolved iron, an element of the cathode compartment. Since protective coating technology was beyond this Phase I work scope, no further work on the CuCl{sub 2} cathode was pursued in Phase I. Notwithstanding, due to its very high OCV and high specific energy, CuCl{sub 2} cathode is a very attractive possibility for a battery capable of delivering higher specific energy with higher voltage. Further investigation of the Na-CuCl{sub 2} battery can be done by using suitable metal coating technologies developed at MSRI for high temperature applications. (4) In Phase I, FeCl{sub 2} and ZnCl{sub 2} were finalized as the potential cathodes for Na-metal salt batteries for delivering high specific energies. Planar Na-FeCl{sub 2} and Na-ZnCl{sub 2} cells were designed, constructed, and tested between 350 and 600 C. Investigation of charge/discharge characteristics showed they were the most promising batteries. Charge/discharge cycles were performed as many as 27 times, and charge/discharge current was as high as 500 mA. No failure was detected after 50 hours testing. (5) Three-cell planar stacks were designed, constructed, and evaluated. Preliminary tests showed further investigation was needed for optimization. (6) Freeze-thaw survival was remarkably good for planar BASE discs fabricated by MSRI's patented vapor phase process.

  16. 4June2013 Page 1 of 8 Sodium Hydroxide (Pellets) SOP Standard Operating Procedures

    E-Print Network [OSTI]

    Cohen, Ronald C.

    4June2013 Page 1 of 8 Sodium Hydroxide (Pellets) SOP Standard Operating Procedures Strong Corrosives ­ Strong Bases (SB) Sodium Hydroxide (Pellets) PrintOH Form: pellets Color: white Melting point/freezing point: 318 °C (604 °F

  17. Sequential Treatment by Ionizing Radiation and Sodium Arsenite Dramatically Accelerates TRAIL-Mediated Apoptosis of

    E-Print Network [OSTI]

    is critically important in the translocation of death receptor to the cell surface. Moreover, sodium arsenite and further down-regulates cFLIP levels in melanoma cells. We have evaluated the effects of sequentialSequential Treatment by Ionizing Radiation and Sodium Arsenite Dramatically Accelerates TRAIL

  18. Effect of sodium chloride concentration on the heat resistance and recovery of

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Effect of sodium chloride concentration on the heat resistance and recovery of Salmonella inhibitory effect in the recovery media. Keywords : Salmonella typhimurium, Sodium chloride, Heat treatment, but they also generate damaged cells. The ability of heated cells to survive depends on the recovery conditions

  19. Atomistic structure of sodium and calcium silicate intergranular films in alumina

    E-Print Network [OSTI]

    Garofalini, Stephen H.

    Atomistic structure of sodium and calcium silicate intergranular films in alumina David A. Litton March 1998; accepted 21 October 1998) Sodium silicate intergranular films (IGF) in contact. The results were compared to previous simulations of calcium silicate and sol-gel silica IGF's in contact

  20. Tank Vapor Characterization Project: Headspace vapor characterization of Hanford Waste Tank U-204, Results from samples collected on August 8, 1995

    SciTech Connect (OSTI)

    Clauss, T.W.; Evans, J.C.; McVeety, B.D.; Pool, K.H.; Thomas, B.L.; Olsen, K.B.; Fruchter, J.S.; Ligotke, M.W.

    1995-11-01T23:59:59.000Z

    This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-U-204 (Tank U-204) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank-farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Company (WHC) and provided for analysis to Pacific Northwest National Laboratory (PNL). Analyses were performed by the Vapor Analytical Laboratory (VAL) at PNL. Analyte concentrations were based on analytical results and, where appropriate, sample volumes provided by WHC. A summary of the results is listed. Detailed descriptions of the analytical results appear in the text.

  1. Plasma and Ion Assistance in Physical Vapor Deposition: AHistorical Perspective

    SciTech Connect (OSTI)

    Anders, Andre

    2007-02-28T23:59:59.000Z

    Deposition of films using plasma or plasma-assist can betraced back surprisingly far, namely to the 18th century for arcs and tothe 19th century for sputtering. However, only since the 1960s thecoatings community considered other processes than evaporation for largescale commercial use. Ion Plating was perhaps the first importantprocess, introducing vapor ionization and substrate bias to generate abeam of ions arriving on the surface of the growing film. Ratherindependently, cathodic arc deposition was established as an energeticcondensation process, first in the former Soviet Union in the 1970s, andin the 1980s in the Western Hemisphere. About a dozen various ion-basedcoating technologies evolved in the last decades, all characterized byspecific plasma or ion generation processes. Gridded and gridless ionsources were taken from space propulsion and applied to thin filmdeposition. Modeling and simulation have helped to make plasma and ionseffects to be reasonably well understood. Yet--due to the complex, oftennon-linear and non-equilibrium nature of plasma and surfaceinteractions--there is still a place for the experience plasma"sourcerer."

  2. EFFECT OF PORE SIZE ON TRAPPING ZINC VAPORS

    SciTech Connect (OSTI)

    Korinko, P.

    2010-12-17T23:59:59.000Z

    A series of experiments were conducted to determine the effect of pore size on pumping efficiency and zinc vapor trapping efficiency. A simple pumping efficiency test was conducted for all five pore diameters where it was observed that evacuation times were adversely affected by reducing the pore size below 5 {micro}m. Common test conditions for the zinc trapping efficiency experiments were used. These conditions resulted in some variability, to ascribe different efficiencies to the filter media. However, the data suggest that there is no significant difference in trapping efficiency for filter media with pores from 0.2 to 20 {micro}m with a thickness of 0.065-inch. Consequently, the 20 {micro}m pore filter media that is currently used at SRS is a suitable filter material for to utilize for future extractions. There is evidence that smaller pore filter will adversely affect the pumping times for the TEF and little evidence to suggest that a smaller pore diameters have significant impact on the trapping efficiency.

  3. Soil Vapor Extraction System Optimization, Transition, and Closure Guidance

    SciTech Connect (OSTI)

    Truex, Michael J.; Becker, Dave; Simon, Michelle A.; Oostrom, Martinus; Rice, Amy K.; Johnson, Christian D.

    2013-02-08T23:59:59.000Z

    Soil vapor extraction (SVE) is a prevalent remediation approach for volatile contaminants in the vadose zone. A diminishing rate of contaminant extraction over time is typically observed due to 1) diminishing contaminant mass, and/or 2) slow rates of removal for contamination in low-permeability zones. After a SVE system begins to show indications of diminishing contaminant removal rate, SVE performance needs to be evaluated to determine whether the system should be optimized, terminated, or transitioned to another technology to replace or augment SVE. This guidance specifically addresses the elements of this type of performance assessment. While not specifically presented, the approach and analyses in this guidance could also be applied at the onset of remediation selection for a site as a way to evaluate current or future impacts to groundwater from vadose zone contamination. The guidance presented here builds from existing guidance for SVE design, operation, optimization, and closure from the U.S. Environmental Protection Agency, U.S. Army Corps of Engineers, and the Air Force Center for Engineering and the Environment. The purpose of the material herein is to clarify and focus on the specific actions and decisions related to SVE optimization, transition, and/or closure.

  4. Growth of graphene underlayers by chemical vapor deposition

    SciTech Connect (OSTI)

    Fabiane, Mopeli; Khamlich, Saleh; Bello, Abdulhakeem; Dangbegnon, Julien; Momodu, Damilola; Manyala, Ncholu, E-mail: ncholu.manyala@up.ac.za [Department of Physics, Institute of Applied Materials, SARChI Chair in Carbon Technology and Materials, University of Pretoria, Pretoria 0028 (South Africa)] [Department of Physics, Institute of Applied Materials, SARChI Chair in Carbon Technology and Materials, University of Pretoria, Pretoria 0028 (South Africa); Charlie Johnson, A. T. [Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)] [Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)

    2013-11-15T23:59:59.000Z

    We present a simple and very convincing approach to visualizing that subsequent layers of graphene grow between the existing monolayer graphene and the copper catalyst in chemical vapor deposition (CVD). Graphene samples were grown by CVD and then transferred onto glass substrates by the bubbling method in two ways, either direct-transfer (DT) to yield poly (methyl methacrylate) (PMMA)/graphene/glass or (2) inverted transfer (IT) to yield graphene/PMMA/glass. Field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM) were used to reveal surface features for both the DT and IT samples. The results from FE-SEM and AFM topographic analyses of the surfaces revealed the underlayer growth of subsequent layers. The subsequent layers in the IT samples are visualized as 3D structures, where the smaller graphene layers lie above the larger layers stacked in a concentric manner. The results support the formation of the so-called “inverted wedding cake” stacking in multilayer graphene growth.

  5. Water, Vapor, and Salt Dynamics in a Hot Repository

    SciTech Connect (OSTI)

    Bahrami, Davood; Danko, George [Department of Mining Engineering, University of Nevada, Reno, 1664 N. Virginia St., Reno, NV, 89557 (United States); Walton, John [Department of Civil Engineering, University of Texas at El Paso, 500 W. University, El Paso, TX, 79968 (United States)

    2007-07-01T23:59:59.000Z

    The purpose of this paper is to report the results of a new model study examining the high temperature nuclear waste disposal concept at Yucca Mountain using MULTIFLUX, an integrated in-drift- and mountain-scale thermal-hydrologic model. The results show that a large amount of vapor flow into the drift is expected during the period of above-boiling temperatures. This phenomenon makes the emplacement drift a water/moisture attractor during the above-boiling temperature operation. The evaporation of the percolation water into the drift gives rise to salt accumulation in the rock wall, especially in the crown of the drift for about 1500 years in the example. The deposited salts over the drift footprint, almost entirely present in the fractures, may enter the drift either by rock fall or by water drippage. During the high temperature operation mode, the barometric pressure variation creates fluctuating relative humidity in the emplacement drift with a time period of approximately 10 days. Potentially wet and dry conditions and condensation on salt-laden drift wall sections may adversely affect the storage environment. Salt accumulations during the above-boiling temperature operation must be sufficiently addressed to fully understand the waste package environment during the thermal period. Until the questions are resolved, a below-boiling repository design is favored where the Alloy-22 will be less susceptible to localized corrosion. (authors)

  6. Effect of dimensionality on vapor-liquid phase transition

    SciTech Connect (OSTI)

    Singh, Sudhir Kumar, E-mail: sksingh@thapar.edu [Department Chemical Engineering, Thapar University, Patiala-147004 Punjab (India)

    2014-04-24T23:59:59.000Z

    Dimensionality play significant role on ‘phase transitions’. Fluids in macroscopic confinement (bulk or 3-Dimensional, 3D) do not show significant changes in their phase transition properties with extent of confinement, since the number of molecules away from the surrounding surfaces is astronomically higher than the number of molecules in close proximity of the confining surfaces. In microscopic confinement (quasi 3D to quasi-2D), however, the number of molecules away from the close proximity of the surface is not as high as is the case with macroscopic (3D) confinement. Hence, under the same thermodynamic conditions ‘phase transition’ properties at microscopic confinement may not remain the same as the macroscopic or 3D values. Phase transitions at extremely small scale become very sensitive to the dimensions as well as the surface characteristics of the system. In this work our investigations reveal the effect of dimensionality on the phase transition from 3D to quasi-2D to 2D behavior. We have used grand canonical transition matrix Monte Carlo simulation to understand the vapor–liquid phase transitions from 3D to quasi-2D behavior. Such studies can be helpful in understanding and controlling the fluid film behaviour confined between solid surfaces of few molecular diameters, for example, in lubrication applications.

  7. Cold Water Vapor in the Barnard 5 Molecular Cloud

    E-Print Network [OSTI]

    Wirström, E S; Persson, C M; Buckle, J V; Cordiner, M A; Takakuwa, S

    2014-01-01T23:59:59.000Z

    After more than 30 years of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds, however, there is only one region where cold (~10 K) water vapor has been detected - L1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at work -- likely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H2O (J = 1_10 - 1_01) at 556.9360 GHz toward two positions in the cold molecular cloud Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

  8. Development of chemical vapor composites, CVC materials. Final report

    SciTech Connect (OSTI)

    NONE

    1998-10-05T23:59:59.000Z

    Industry has a critical need for high-temperature operable ceramic composites that are strong, non-brittle, light weight, and corrosion resistant. Improvements in energy efficiency, reduced emissions and increased productivity can be achieved in many industrial processes with ceramic composites if the reaction temperature and pressure are increased. Ceramic composites offer the potential to meet these material requirements in a variety of industrial applications. However, their use is often restricted by high cost. The Chemical Vapor composite, CVC, process can reduce the high costs and multiple fabrication steps presently required for ceramic fabrication. CVC deposition has the potential to eliminate many difficult processing problems and greatly increase fabrication rates for composites. With CVC, the manufacturing process can control the composites` density, microstructure and composition during growth. The CVC process: can grow or deposit material 100 times faster than conventional techniques; does not require an expensive woven preform to infiltrate; can use high modulus fibers that cannot be woven into a preform; can deposit composites to tolerances of less than 0.025 mm on one surface without further machining.

  9. The Water Vapor Abundance in Orion KL Outflows

    E-Print Network [OSTI]

    J. Cernicharo; J. R. Goicoechea; F. Daniel; M. R. Lerate; M. J. Barlow; B. M. Swinyard; E. van Dishoeck; T. L. Lim; S. Viti; J. Yates

    2006-08-16T23:59:59.000Z

    We present the detection and modeling of more than 70 far-IR pure rotational lines of water vapor, including the 18O and 17O isotopologues, towards Orion KL. Observations were performed with the Long Wavelength Spectrometer Fabry-Perot (LWS/FP; R~6800-9700) on board the Infrared Space Observatory (ISO) between ~43 and ~197 um. The water line profiles evolve from P-Cygni type profiles (even for the H2O18 lines) to pure emission at wavelengths above ~100 um. We find that most of the water emission/absorption arises from an extended flow of gas expanding at 25+-5 kms^-1. Non-local radiative transfer models show that much of the water excitation and line profile formation is driven by the dust continuum emission. The derived beam averaged water abundance is 2-3x10^-5. The inferred gas temperature Tk=80-100 K suggests that: (i) water could have been formed in the "plateau" by gas phase neutral-neutral reactions with activation barriers if the gas was previously heated (e.g. by shocks) to >500 K and/or (ii) H2O formation in the outflow is dominated by in-situ evaporation of grain water-ice mantles and/or (iii) H2O was formed in the innermost and warmer regions (e.g. the hot core) and was swept up in ~1000 yr, the dynamical timescale of the outflow.

  10. Sodium fast reactor fuels and materials : research needs.

    SciTech Connect (OSTI)

    Denman, Matthew R.; Porter, Douglas (Idaho National Laboratory, Idaho Falls, ID); Wright, Art (Argonne National Laboratory Argonne, IL); Lambert, John (Argonne National Laboratory Argonne, IL); Hayes, Steven (Idaho National Laboratory, Idaho Falls, ID); Natesan, Ken (Argonne National Laboratory Argonne, IL); Ott, Larry J. (Oak Ridge National Laboratory, Oak Ridge, TN); Garner, Frank (Radiation Effects Consulting. Richland, WA); Walters, Leon (Advanced Reactor Concepts, Idaho Falls, ID); Yacout, Abdellatif (Argonne National Laboratory Argonne, IL)

    2011-09-01T23:59:59.000Z

    An expert panel was assembled to identify gaps in fuels and materials research prior to licensing sodium cooled fast reactor (SFR) design. The expert panel considered both metal and oxide fuels, various cladding and duct materials, structural materials, fuel performance codes, fabrication capability and records, and transient behavior of fuel types. A methodology was developed to rate the relative importance of phenomena and properties both as to importance to a regulatory body and the maturity of the technology base. The technology base for fuels and cladding was divided into three regimes: information of high maturity under conservative operating conditions, information of low maturity under more aggressive operating conditions, and future design expectations where meager data exist.

  11. Sodium-Bearing Waste Treatment Alternatives Implementation Study

    SciTech Connect (OSTI)

    Charles M. Barnes; James B. Bosley; Clifford W. Olsen

    2004-07-01T23:59:59.000Z

    The purpose of this document is to discuss issues related to the implementation of each of the five down-selected INEEL/INTEC radioactive liquid waste (sodium-bearing waste - SBW) treatment alternatives and summarize information in three main areas of concern: process/technical, environmental permitting, and schedule. Major implementation options for each treatment alternative are also identified and briefly discussed. This report may touch upon, but purposely does not address in detail, issues that are programmatic in nature. Examples of these include how the SBW will be classified with respect to the Nuclear Waste Policy Act (NWPA), status of Waste Isolation Pilot Plant (WIPP) permits and waste storage availability, available funding for implementation, stakeholder issues, and State of Idaho Settlement Agreement milestones. It is assumed in this report that the SBW would be classified as a transuranic (TRU) waste suitable for disposal at WIPP, located in New Mexico, after appropriate treatment to meet transportation requirements and waste acceptance criteria (WAC).

  12. Feasibility Study for Vitrification of Sodium-Bearing Waste

    SciTech Connect (OSTI)

    J. J. Quigley; B. D. Raivo; S. O. Bates; S. M. Berry; D. N. Nishioka; P. J. Bunnell

    2000-09-01T23:59:59.000Z

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated under a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is the complete calcination (i.e., treatment) of all SBW by December 31, 2012. One of the proposed options for treatment of SBW is vitrification. This study will examine the viability of SBW vitrification. This study describes the process and facilities to treat the SBW, from beginning waste input from INTEC Tank Farm to the final waste forms. Schedules and cost estimates for construction and operation of a Vitrification Facility are included. The study includes a facility layout with drawings, process description and flow diagrams, and preliminary equipment requirements and layouts.

  13. Sodium Heat Engine Development Program. Phase 1, Final report

    SciTech Connect (OSTI)

    Singh, J.P.; Kupperman, D.S.; Majumdar, S.; Dorris, S.; Gopalsami, N.; Dieckman, S.L.; Jaross, R.A.; Johnson, D.L.; Gregar, J.S.; Poeppel, R.B.; Raptis, A.C.; Valentin, R.A.

    1992-01-01T23:59:59.000Z

    The Sodium Heat Engine (SHE) is an efficient thermoelectric conversion device which directly generates electricity from a thermally regenerative electrochemical cell that relies on the unique conduction properties of {beta}{double_prime}-alumina solid electrolyte (BASE). Laboratory models of a variety of SHE devices have demonstrated the feasibility and efficiency of the system, engineering development of large prototype devices has been slowed by a series of materials and fabrication problems. Failure of the electrolyte tubes has been a recurring problem and a number of possible causes have been postulated. To address these issues, a two-phase engineering development program was undertaken. This report summarizes the final results of the first phase of the program, which included extensive materials characterization activities, a study of applicable nondestructive evaluation methods, an investigation of possible stress states that would contribute to fracture, and certain operational issues associated with the electromagnetic pumps used in the SHE prototype. Mechanical and microstructural evaluation of commercially obtained BASE tubes revealed that they should be adequate for SHE applications and that sodium exposure produced no appreciable deleterious strength effects. Processing activities to produce a more uniform and smaller grain size for the BASE tubes were completed using isostatic pressing, extrusion, and slip casting. Green tubes were sintered by conventional and microwave plasma methods. Of particular interest is the residual stress state in the BASE tubes, and both analysis and nondestructive evaluation methods were employed to evaluate these stresses. X-ray and neutron diffraction experiments were performed to determine the bulk residual stresses in commercially fabricated BASE tubes; however, tube-to-tube variations and variations among the various methods employed did not allow formulation of a definitive definition of the as-fabricated stress state.

  14. 105-DR Large Sodium Fire Facility closure plan. Revision 1

    SciTech Connect (OSTI)

    Not Available

    1993-05-01T23:59:59.000Z

    The Hanford Site, located northwest of the city of Richland, Washington, houses reactors, chemical-separation systems, and related facilities used for the production of special nuclear materials, and activities associated with nuclear energy development. The 105-DR Large Sodium Fire Facility (LSFF), which was in operation from about 1972 to 1986, was a research laboratory that occupied the former ventilation supply room on the southwest side of the 105-DR Reactor facility. The LSFF was established to provide a means of investigating fire and safety aspects associated with large sodium or other metal alkali fires in the liquid metal fast breeder reactor (LMFBR) facilities. The 105-DR Reactor facility was designed and built in the 1950`s and is located in the 100-D Area of the Hanford Site. The building housed the 105-DR defense reactor, which was shut down in 1964. The LSFF was initially used only for engineering-scale alkali metal reaction studies. In addition, the Fusion Safety Support Studies program sponsored intermediate-size safety reaction tests in the LSFF with lithium and lithium lead compounds. The facility has also been used to store and treat alkali metal waste, therefore the LSFF is subject to the regulatory requirements for the storage and treatment of dangerous waste. Closure will be conducted pursuant to the requirements of the Washington Administrative Code (WAC) 173-303-610. This closure plan presents a description of the facility, the history of waste managed, and the procedures that will be followed to close the LSFF as an Alkali Metal Treatment Facility. No future use of the LSFF is expected.

  15. Oxidative chemical vapor deposition of conductive polymers for use in novel photovoltaic device architectures

    E-Print Network [OSTI]

    Howden, Rachel M. (Rachel Mary)

    2013-01-01T23:59:59.000Z

    The conductive polymer poly(3,4-ethylenedioxythiophene), (PEDOT), deposited via oxidative chemical vapor deposition (oCVD) has been investigated for use in organic electronic devices. The oCVD process as well as the ...

  16. Plasma Enhanced Chemical Vapor Deposition on Living Substrates: Development, Characterization, and Biological Applications

    E-Print Network [OSTI]

    Tsai, Tsung-Chan 1982-

    2012-12-05T23:59:59.000Z

    This dissertation proposed the idea of “plasma-enhanced chemical vapor deposition on living substrates (PECVD on living substrates)” to bridge the gap between the thin film deposition technology and the biological and living substrates. This study...

  17. Understanding the Nanotube Growth Mechanism: A Strategy to Control Nanotube Chirality during Chemical Vapor Deposition Synthesis

    E-Print Network [OSTI]

    Gomez Gualdron, Diego Armando 1983-

    2012-10-26T23:59:59.000Z

    during chemical vapor deposition synthesis must focus on controlling the structure of the nucleated nanotube seeds. DFT and RMD simulations demonstrate the viability of using the structures of catalyst particles over which nanotube growth proceeds...

  18. E-Print Network 3.0 - acid vapor pressures Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology 22 3b. Thermodynamics of moist air Water phase, water latent heat of vaporization Lv Summary: 3b. Thermodynamics of moist air Water phase, water latent...

  19. E-Print Network 3.0 - alkali-metal vapor density Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics 65 nature physics | VOL 3 | APRIL 2007 | www.nature.comnaturephysics 227 REVIEW ARTICLE Summary: in a high-density alkali-metal vapor in low magnetic fields. Phys....

  20. Vapor-Induced Solid-Liquid-Solid Process for Silicon-based Nanowire...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J, J Liu, D Wang, D Choi, LS Fifield, CM Wang, G Xia, Z Nie, Z Yang, LR Pederson, and GL Graff.2010."Vapor-Induced Solid-Liquid-Solid Process for Silicon-based Nanowire...

  1. Structure/processing relationships in vapor-liquid-solid nanowire epitaxy

    E-Print Network [OSTI]

    Boles, Steven Tyler

    2010-01-01T23:59:59.000Z

    The synthesis of Si and III-V nanowires using the vapor-liquid-solid (VLS) growth mechanism and low-cost Si substrates was investigated. The VLS mechanism allows fabrication of heterostructures which are not readily ...

  2. Optical pumping and spectroscopy of Cs vapor at high magnetic field

    SciTech Connect (OSTI)

    Olsen, B. A.; Patton, B.; Jau, Y.-Y.; Happer, W. [Joseph Henry Laboratory, Department of Physics, Princeton University, Princeton, New Jersey 08544 (United States)

    2011-12-15T23:59:59.000Z

    We have measured changes in the ground-state populations of Cs vapor induced by optical pumping at high magnetic field. The 2.7-T field of our experiments is strong enough to decouple the nuclear and electronic spins, allowing us to independently measure each population. The spatial dependence of the Cs populations in small amounts of buffer gas obeys a simple coupled diffusion model and the relative populations reveal the details of relaxation within the vapor cell. Optical pumping can produce high nuclear polarization in the Cs vapor due to perturbations of the hyperfine interaction during collisions with buffer-gas particles and depending on the pumping transition, radiation trapping can strongly influence the electronic and nuclear polarizations in the vapor.

  3. Millimeter-wave Radiometer for High Sensitivity Water Vapor Profiling in Arid Regions

    SciTech Connect (OSTI)

    Pazmany, Andrew

    2006-11-09T23:59:59.000Z

    Abstract - ProSensing Inc. has developed a G-band (183 GHz) water Vapor Radiometer (GVR) for long-term, unattended measurements of low concentrations of atmospheric water vapor and liquid water. Precipitable water vapor and liquid water path are estimated from zenith brightness temperatures measured from four double-sideband receiver channels, centered at 183.31 1, 3 and 7, and 14 GHz. A prototype ground-based version of the instrument was deployed at the DOE ARM program?s North Slope of Alaska site near Barrow AK in April 2005, where it collected data continuously for one year. A compact, airborne version of this instrument, packaged to operate from a standard 2-D PMS probe canister, has been tested on the ground and is scheduled for test flights in the summer of 2006. This paper presents design details, laboratory test results and examples of retrieved precipitable water vapor and liquid water path from measured brightness temperature data.

  4. CO-CATALYTIC ABSORPTION LAYERS FOR CONTROLLED LASER-INDUCED CHEMICAL VAPOR DEPOSITION OF CARBON NANOTUBES

    E-Print Network [OSTI]

    Michaelis, F.B.; Weatherup, R.S.; Bayer, B.C.; Bock, M.C.D; Sugime, H.; Caneva, S.; Robertson, J.; Baumberg, J.J.; Hofmann, S.

    2014-02-24T23:59:59.000Z

    The concept of co-catalytic layer structures for controlled laser-induced chemical vapor deposition of carbon nanotubes is established, in which a thin Ta support layer chemically aids the initial Fe catalyst reduction. This enables a significant...

  5. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu (Palo Alto, CA); Ly, Jennifer (San Jose, CA); Aldajani, Tiem (San Jose, CA); Baker, Richard W. (Palo Alto, CA)

    2011-08-23T23:59:59.000Z

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  6. Control and Optimization of Vapor Compression Cycles Using Recursive Least Squares Estimation

    E-Print Network [OSTI]

    Rani, Avinash

    2012-10-19T23:59:59.000Z

    Vapor compression cycles are the primary method by which refrigeration and air-conditioning systems operate, and thus constitute a significant portion of commercial and residential building energy consumption. This thesis presents a data...

  7. Iron (III) Chloride doping of large-area chemical vapor deposition graphene

    E-Print Network [OSTI]

    Song, Yi, S.M. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    Chemical doping is an effective method of reducing the sheet resistance of graphene. This thesis aims to develop an effective method of doping large area Chemical Vapor Deposition (CVD) graphene using Iron (III) Chloride ...

  8. Temperature and water vapor pressure effects on the friction coefficient of hydrogenated diamondlike carbon films.

    SciTech Connect (OSTI)

    Dickrell, P. L.; Sawyer, W. G.; Eryilmaz, O. L.; Erdemir, A.; Energy Technology; Univ. of Florida

    2009-07-01T23:59:59.000Z

    Microtribological measurements of a hydrogenated diamondlike carbon film in controlled gaseous environments show that water vapor plays a significant role in the friction coefficient. These experiments reveal an initial high friction transient behavior that does not reoccur even after extended periods of exposure to low partial pressures of H{sub 2}O and O{sub 2}. Experiments varying both water vapor pressure and sample temperature show trends of a decreasing friction coefficient as a function of both the decreasing water vapor pressure and the increasing substrate temperature. Theses trends are examined with regard to first order gas-surface interactions. Model fits give activation energies on the order of 40 kJ/mol, which is consistent with water vapor desorption.

  9. Bilayer graphene growth by low pressure chemical vapor deposition on copper foil

    E-Print Network [OSTI]

    Fang, Wenjing, S.M. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Successfully integrating graphene in standard processes for applications in electronics relies on the synthesis of high-quality films. In this work we study Low Pressure Chemical Vapor Deposition (LPCVD) growth of bilayer ...

  10. Film boiling of saturated liquid flowing upward through a heated tube : high vapor quality range

    E-Print Network [OSTI]

    Laverty, W. F.

    1964-01-01T23:59:59.000Z

    Film boiling of saturated liquid flowing upward through a uniformly heated tube has been studied for the case in which pure saturated liquid enters the tube and nearly saturated vapor is discharged. Since a previous study ...

  11. The design, fabrication, and implications of a solvothermal vapor annealing chamber

    E-Print Network [OSTI]

    Porter, Nathaniel R., Jr

    2013-01-01T23:59:59.000Z

    This thesis documents the design, fabrication, use, and benefits of a prototype aluminum solvothermal vapor annealing chamber which facilitates the self-assembly of block copolymers (BCPs) on silicon wafers which are then ...

  12. Optimization of multi-pressure himidification-dehumidification desalination using thermal vapor compression and hybridization

    E-Print Network [OSTI]

    Mistry, Karan Hemant

    Humidification-dehumidification (HD or HDH) desalination, and specifically HD driven by a thermal vapor compressor (TVC), is a thermal desalination method that has the potential to produce potable water efficiently in order ...

  13. Assessment of soot particle vaporization effects during laser-induced incandescence with

    E-Print Network [OSTI]

    Hahn, David W.

    Assessment of soot particle vaporization effects during laser-induced incandescence with time-induced incandescence (LII) has been successfully used for soot volume fraction and particle size measurements

  14. Atmospheric pressure chemical vapor deposition of TiN from tetrakis(dimethylamido)titanium and ammonia

    E-Print Network [OSTI]

    pressure chemical vapor deposition. Experiments were conducted in a belt furnace; static experiments, in particular, is used for tool coating, solar-control films, and micro- electronic applications. Optically

  15. Application of Computational Fluid Dynamics in the Forced Dispersion Modeling of LNG Vapor Clouds

    E-Print Network [OSTI]

    Kim, Byung-Kyu

    2013-05-31T23:59:59.000Z

    The safety and security of liquefied natural gas (LNG) facilities has prompted the need for continued study of LNG mitigation systems. Water spray systems are widely recognized as an effective measure for dispersing LNG vapor clouds. Currently...

  16. Liquefied Natural Gas (LNG) Vapor Dispersion Modeling with Computational Fluid Dynamics Codes

    E-Print Network [OSTI]

    Qi, Ruifeng

    2012-10-19T23:59:59.000Z

    Federal regulation 49 CFR 193 and standard NFPA 59A require the use of validated consequence models to determine the vapor cloud dispersion exclusion zones for accidental liquefied natural gas (LNG) releases. For modeling purposes, the physical...

  17. Control of Vapor Dispersion and Pool Fire of Liquefied Natural Gas (LNG) with Expansion Foam

    E-Print Network [OSTI]

    Yun, Geun Woong

    2011-10-21T23:59:59.000Z

    , this study aimed to obtain key parameters, such as the temperature changes of methane and foam and the extent reduction of vapor concentration. This study also focused on identifying the effectiveness of foam and thermal exclusion zone by investigating...

  18. Single- and few-layer graphene by ambient pressure chemical vapor deposition on nickel

    E-Print Network [OSTI]

    Reina Ceeco, Alfonso

    2010-01-01T23:59:59.000Z

    An ambient pressure chemical vapor deposition (APCVD) process is used to fabricate graphene based films consisting of one to several graphene layers across their area. Polycrystalline Ni thin films are used and the graphene ...

  19. Fault detection methods for vapor-compression air conditioners using electrical measurements

    E-Print Network [OSTI]

    Laughman, Christopher Reed.

    2008-01-01T23:59:59.000Z

    (cont.) This method was experimentally tested and validated on a commercially available air handler and duct system. In the second class of faults studied, liquid refrigerant, rather than vapor, enters the cylinder of a ...

  20. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From

    E-Print Network [OSTI]

    Chickos, James S.

    Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2010 William Acree, Jr. Department of Chemistry, University of North Texas, Denton, Texas 76203 James S. Chickosa... Department of Chemistry and Biochemistry

  1. Vaporization and Sublimation Enthalpies of Acetanilide and Several Derivatives by Correlation Gas Chromatography

    E-Print Network [OSTI]

    Chickos, James S.

    Vaporization and Sublimation Enthalpies of Acetanilide and Several Derivatives by Correlation Gas Chromatography Patamaporn Umnahanant and James Chickos* Department of Chemistry and Biochemistry, University and combined to provide their corresponding sublimation enthalpies. Since all of the materials examined

  2. Initiated chemical vapor deposition of polymeric thin films : mechanism and applications

    E-Print Network [OSTI]

    Chan, Kelvin, Ph. D. Massachusetts Institute of Technology

    2005-01-01T23:59:59.000Z

    Initiated chemical vapor deposition (iCVD) is a novel technique for depositing polymeric thin films. It is able to deposit thin films of application-specific polymers in one step without using any solvents. Its uniqueness ...

  3. Radon Transect Studies in Vapor- and Liquid-Dominated Geothermal Reservoirs

    SciTech Connect (OSTI)

    Semprini, Lewis; Kruger, Paul

    1980-12-16T23:59:59.000Z

    This communication describes the transect analysis conducted at the vapor-dominated reservoirs at The Geysers in California and the liquid-dominated reservoirs at Cerro Prieto in Baja, California.

  4. Reflux condensation of pure vapors with and without a noncondensable gas inside plain and enhanced tubes

    SciTech Connect (OSTI)

    Abdelmessih, A.N. [Seattle Univ., WA (United States); Rabas, T.J.; Panchal, C.B. [Argonne National Lab., IL (United States)

    1997-06-01T23:59:59.000Z

    Estimates of the surface-area and vapor-release reductions are obtained when commercially available enhanced tubes (spirally ribbed) replace plain tubes in a reflux unit condensing pure organic vapors with different concentrations of a noncondensable gas. This investigation was undertaken because there are no existing data and/or prediction methods that are applicable for these shell-and-tube condensers commonly used in the process industries. To obtain these estimates, existing design methods published in the open literature were used. The major findings are that (1) surface-area reductions can almost approach the single-phase heat transfer enhancement level, and (2) vapor-release reductions can approach a factor of four. The important implication is that enhanced tubes appear to be very cost effective for addressing the recovery of volatile organic vapors (VOCs), and for a vast number of different reflux-condenser applications.

  5. An Analysis of Cloud Cover and Water Vapor for the ALMA Project

    E-Print Network [OSTI]

    (Chile), Chalviri (Bolivia) and Five Sites in Argentina using Satellite Data and a Verification and water vapor at Chajnantor (Chile), Chalviri (Bolivia) and four sites in Argentina. Since time

  6. Tank Vapor Characterization Project: Headspace vapor characterization of Hanford waste tank 241-S-101: Results from samples collected on 06/06/96

    SciTech Connect (OSTI)

    Thomas, B.L.; Evans, J.C.; Pool, K.H.; Olsen, K.B.; Fruchter, J.S.; Silvers, K.L.

    1997-01-01T23:59:59.000Z

    This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-S-101. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained. Analyte concentrations were based on analytical results and sample volumes provided by WHC. A summary of the inorganic analytes, permanent gases, and total non-methane organic compounds is listed.

  7. Tank 241-TY-103 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-TY-103. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  8. Tank 241-SX-106 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-SX-106. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  9. Tank 241-T-107 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-T-107. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  10. Tank 241-TY-104 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-TY-104. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  11. Tank 241-C-105 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-C-105. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  12. Tank 241-C-102 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-C-102. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  13. Tank 241-TY-101 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-TY-101. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  14. Tank 241-C-106 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-C-106. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  15. Tank 241-B-103 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-B-103. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  16. Tank 241-BX-104 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-BX-104. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  17. Tank 241-C-109 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-10T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-C-109. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  18. Tank 241-C-111 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-C-111. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  19. Tank 241-C-110 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-C-110. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  20. Tank 241-C-107 vapor sampling and analysis tank characterization report

    SciTech Connect (OSTI)

    Huckaby, J.L.

    1995-05-31T23:59:59.000Z

    This report presents the details of the Hanford waste tank characterization study for tank 241-C-107. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank.