National Library of Energy BETA

Sample records for hourly co2 nox

  1. Propane-Diesel Dual Fuel for CO2 and Nox Reduction

    Broader source: Energy.gov [DOE]

    Test results show significant CO2 and NOx emission reductions, fuel economy gains, and overall energy savings with propane injection in a diesel engine.

  2. Analysis of Strategies for Multiple Emissions from Electric Power SO2, NOX, CO2, Mercury and RPS

    Reports and Publications (EIA)

    2001-01-01

    At the request of the Subcommittee, the Energy Information Administration prepared an initial report that focused on the impacts of reducing power sector NOx, SO2, and CO2 emissions. The current report extends the earlier analysis to add the impacts of reducing power sector mercury emissions and introducing renewable portfolio standard (RPS) requirements.

  3. AISI/DOE Technology Roadmap Program: Development of an O2-Enriched Furnace System for Reduced CO2 and NOx Emissions For the Steel Industry

    SciTech Connect (OSTI)

    Edward W. Grandmaison; David J. Poirier; Eric Boyd

    2003-01-20

    An oxygen-enriched furnace system for reduced CO2 and NOx emission has been developed. The furnace geometry, with a sidewall-mounted burner, was similar to configurations commonly encountered in a steel reheat furnace. The effect of stack oxygen concentration, oxygen enrichment level and air infiltration on fuel savings/CO2 reduction, NOx emissions and scale formation were investigated. The firing rate required to maintain the furnace temperature at 1100 C decreased linearly with increasing oxygen enrichment. At full oxygen enrichment a reduction of 40-45% in the firing rate was required to maintain furnace temperature. NOx emissions were relatively constant at oxygen enrichment levels below 60% and decreased concentration at all oxygen enrichment levels. Air infiltration also had an effect on NOx levels leading to emissions similar to those observed with no air infiltration but with similar stack oxygen concentrations. At high oxygen enrichment levels, there was a larger variation in the refractory surface-temperature on the roof and blind sidewall of the furnace. Scale habit, intactness, adhesion and oxidation rates were examined for five grades of steel over a range of stack oxygen concentrations and oxygen enrichment levels at 1100 degree C. The steel grade had the largest effect on scaling properties examined in this work. The stack oxygen concentration and the oxygen enrichment level had much smaller effects on the scaling properties.

  4. Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Kevin Fogash

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the country’s significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  5. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known ‘signal-to-noise’ problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  6. Isothermal desulfation of pre-sulfated Pt-BaO/?-Al2O3 lean NOx trap catalysts with H2: the effect of H2 concentration and the roles of CO2 and H2O

    SciTech Connect (OSTI)

    Kim, Do Heui; Kwak, Ja Hun; Szanyi, Janos; Peden, Charles HF

    2012-01-12

    The desulfation mechanisms of pre-sulfated Pt-BaO/{gamma}-Al{sub 2}O{sub 3} lean NOx trap catalysts were investigated under isothermal conditions (600 C) using H{sub 2} as the reductant. Sulfates were found to be reduced first with H{sub 2} to produce SO{sub 2}, followed by a reaction between SO{sub 2} and H{sub 2} to produce H{sub 2}S. Gas analysis during the rich pulse reveals that the sulfur removal efficiency is initially proportional to the H{sub 2} concentration. At constant H{sub 2} concentration the overall desulfation efficiency decreases in the order of H{sub 2}/CO{sub 2}/H{sub 2}O > H{sub 2}/CO{sub 2} > H{sub 2}/H{sub 2}O > H{sub 2}, as confirmed by XPS analysis of residual sulfur in the desulfated samples. H{sub 2}O limits the evolution of SO{sub 2} at an early stage of the rich pulse and enhances the production of H{sub 2}S in later stages of reduction. CO{sub 2} is involved in both the formation of COS and the production of H{sub 2}O (via the reverse water-gas shift reaction), therefore, resulting in an increased overall efficiency.

  7. Supercritical CO2 Tech Team

    Broader source: Energy.gov [DOE]

    Supercritical CO2 is a highly technical team focused on different heat source applications of the sCO2 Brayton Cycle.

  8. Method for reducing CO2, CO, NOX, and SOx emissions

    DOE Patents [OSTI]

    Lee, James Weifu; Li, Rongfu

    2002-01-01

    Industrial combustion facilities are integrated with greenhouse gas-solidifying fertilizer production reactions so that CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions can be converted prior to emission into carbonate-containing fertilizers, mainly NH.sub.4 HCO.sub.3 and/or (NH.sub.2).sub.2 CO, plus a small fraction of NH.sub.4 NO.sub.3 and (NH.sub.4).sub.2 SO.sub.4. The invention enhances sequestration of CO.sub.2 into soil and the earth subsurface, reduces N0.sub.3.sup.- contamination of surface and groundwater, and stimulates photosynthetic fixation of CO.sub.2 from the atmosphere. The method for converting CO.sub.2, CO, NO.sub.x, and SO.sub.x emissions into fertilizers includes the step of collecting these materials from the emissions of industrial combustion facilities such as fossil fuel-powered energy sources and transporting the emissions to a reactor. In the reactor, the CO.sub.2, CO, N.sub.2, SO.sub.x, and/or NO.sub.x are converted into carbonate-containing fertilizers using H.sub.2, CH.sub.4, or NH.sub.3. The carbonate-containing fertilizers are then applied to soil and green plants to (1) sequester inorganic carbon into soil and subsoil earth layers by enhanced carbonation of groundwater and the earth minerals, (2) reduce the environmental problem of NO.sub.3.sup.- runoff by substituting for ammonium nitrate fertilizer, and (3) stimulate photosynthetic fixation of CO.sub.2 from the atmosphere by the fertilization effect of the carbonate-containing fertilizers.

  9. Efficient electrochemical CO2 conversion powered by renewable energy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kauffman, Douglas R.; Thakkar, Jay; Siva, Rajan; Matranga, Christopher; Ohodnicki, Paul R.; Zeng, Chenjie; Jin, Rongchao

    2015-06-29

    Here, the catalytic conversion of CO2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au25 nanoclusters as renewably powered CO2 conversion electrocatalysts with CO2 → CO reaction rates between 400 and 800 L of CO2 per gram of catalytic metal per hour and product selectivities between 80 and 95%. These performance metrics correspondmore » to conversion rates approaching 0.8–1.6 kg of CO2 per gram of catalytic metal per hour. We also present data showing CO2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 106 mol CO2 molcatalyst–1 during a multiday (36 hours total hours) CO2electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 106 and 4 × 106 molCO2 molcatalyst–1 were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO2 conversion systems will produce a net increase in CO2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies

  10. CO2 Sequestration short course

    SciTech Connect (OSTI)

    DePaolo, Donald J.; Cole, David R; Navrotsky, Alexandra; Bourg, Ian C

    2014-12-08

    Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  11. Trinity CO2 LLC | Open Energy Information

    Open Energy Info (EERE)

    CO2 LLC Jump to: navigation, search Name: Trinity CO2 LLC Place: Texas Product: String representation "Trinity CO2 LLC ... smission lines." is too long. References: Trinity CO2...

  12. Advanced Petroleum-Based Fuels - Diesel Emissions Project (APBF-DEC): 2,000-Hour Performance of a NOx Adsorber Catalyst and Diesel Particle Filter System for a Medium-Duty, Pick-Up Diesel Engine Platform; Final Report

    SciTech Connect (OSTI)

    Not Available

    2007-03-01

    Presents the results of a 2,000-hour test of an emissions control system consisting of a nitrogen oxides adsorber catalyst in combination with a diesel particle filter, advanced fuels, and advanced engine controls in an SUV/pick-up truck vehicle platform.

  13. Watch Our CO2 Drop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Watch Our CO2 Drop Watch Our CO2 Drop

  14. ARM - Instrument - co2flx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsco2flx Documentation CO2FLX : Handbook ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA....

  15. Supercritical CO2-Brayton Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercritical CO2-Brayton Cycle - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs

  16. CO2 Utilization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Utilization CO2 Utilization Carbon dioxide (CO2) use and reuse efforts focus on the conversion of CO2 to useable products and fuels that will reduce CO2 emissions in areas where geologic storage may not be an optimal solution. These include: Enhanced Oil/Gas Recovery - Injecting CO2 into depleting oil or gas bearing fields to maximize the amount of CO2 that could be stored as well as maximize hydrocarbon production. View the latest projects selected in FY 2014. CO2 as Feedstock - Use CO2 as

  17. Diesel Passenger Car Technology for Low Emissions and CO2 Compliance |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Passenger Car Technology for Low Emissions and CO2 Compliance Diesel Passenger Car Technology for Low Emissions and CO2 Compliance Cost effective reduction of legislated emissions (including CO2) is a major issue. NOx control must not be a limiting factor to the long term success of Diesel engines. deer09_cooper.pdf (854.85 KB) More Documents & Publications Ricardo's ACTION Strategy: An Enabling Light Duty Diesel Technology for the US Market Laboratory and Vehicle

  18. CO2 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Our Jobs Our Jobs Working at NNSA Blog Home CO2 CO2 'Underground battery' could store renewable energy, sequester CO2 This integrated system would store carbon dioxide in an...

  19. Co2balance | Open Energy Information

    Open Energy Info (EERE)

    balance Jump to: navigation, search Name: Co2balance Place: United Kingdom Sector: Carbon Product: Carbon offset provider based in Somerset, UK. References: Co2balance1 This...

  20. Factor CO2 | Open Energy Information

    Open Energy Info (EERE)

    Factor CO2 Jump to: navigation, search Name: Factor CO2 Place: Bilbao, Spain Zip: 48008 Product: Spain-based consultancy specializing in climate change projects. References: Factor...

  1. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.

    2008-10-21

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  2. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi; Hisashi , Bool, III; Lawrence E.

    2007-06-05

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  3. Ceramatec NOx Sensor and NOx Catalyst Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramatec NOx Sensor and NOx Catalyst Technologies Ceramatec NOx Sensor and NOx Catalyst Technologies 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Ceramatec, Inc., Advanced Ionic Technologies 2004_deer_nair.pdf (195.74 KB) More Documents & Publications Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials Pt-free, Perovskite-based Lean NOx Trap Catalysts Active Soot Filter Regeneration

  4. QGESS: CO2 Impurity Design Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Health NOx Oxides of nitrogen SAS Saline aquifer sequestration SCR Selective catalytic reduction TWA Total Weighted Average National Energy Technology Laboratory Office of...

  5. co2-transport | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport Cost Model FENETL CO2 Transport Cost Model About the model: This model was developed to estimate the cost of transporting a user-specified mass rate of CO2 by pipeline...

  6. Is CO2 an Indoor Pollutant? Higher Levels of CO2 May Diminish...

    Office of Scientific and Technical Information (OSTI)

    Decision Making Performance Citation Details In-Document Search Title: Is CO2 an Indoor Pollutant? Higher Levels of CO2 May Diminish Decision Making Performance You are ...

  7. Hybrid heat exchange for the compression capture of CO2 from recirculated flue gas

    SciTech Connect (OSTI)

    Oryshchyn, Danylo B.; Ochs, Thomas L.; Summers, Cathy A.

    2004-01-01

    An approach proposed for removal of CO2 from flue gas cools and compresses a portion of a recirculated flue-gas stream, condensing its volatile materials for capture. Recirculating the flue gas concentrates SOx, H2O and CO2 while dramatically reducing N2 and NOx, enabling this approach, which uses readily available industrial components. A hybrid system of indirect and direct-contact heat exchange performs heat and mass transfer for pollutant removal and energy recovery. Computer modeling and experimentation combine to investigate the thermodynamics, heat and mass transfer, chemistry and engineering design of this integrated pollutant removal (IPR) system.

  8. Forest succession at elevated CO2

    SciTech Connect (OSTI)

    Clark, James S.; Schlesinger, William H.

    2002-02-01

    We tested hypotheses concerning the response of forest succession to elevated CO2 in the FACTS-1 site at the Duke Forest. We quantified growth and survival of naturally recruited seedlings, tree saplings, vines, and shrubs under ambient and elevated CO2. We planted seeds and seedlings to augment sample sites. We augmented CO2 treatments with estimates of shade tolerance and nutrient limitation while controlling for soil and light effects to place CO2 treatments within the context of natural variability at the site. Results are now being analyzed and used to parameterize forest models of CO2 response.

  9. Ammonia reactions with the stored oxygen in a commercial lean NOx trap catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bartova, Sarka; Mracek, David; Koci, Petr; Marek, Milos; Choi, Jae -Soon

    2014-10-12

    Ammonia is an important intermediate of the NOx reduction in a NOx storage and reduction catalyst (aka lean NOx trap). NH3 formed under rich conditions in the reduced front part of the catalyst is transported by convection downstream to the unregenerated (still oxidized) zone of the catalyst, where it further reacts with the stored oxygen and NOx. In this paper, the kinetics and selectivity of NH3 reactions with the stored oxygen are studied in detail with a commercial Ba-based NOx storage catalyst containing platinum group metals (PGM), Ba and Ce oxides. Furthermore, steady-state NH3 decomposition, NH3 oxidation by O2 andmore » NO, and N2O decomposition are examined in light-off experiments. Periodic lean/rich cycling is measured first with O2 and NH3, and then with NOx + O2 and NH3 to discriminate between the NH3 reactions with the stored oxygen and the stored NOx. The reaction of NH3 with the stored O2 is highly selective towards N2, however a certain amount of NOx and N2O is also formed. The formed NOx by-product is efficiently adsorbed on the NOx storage sites such that the NOx is not detected at the reactor outlet except at high temperatures. The stored NOx reacts with NH3 feed in the next rich phase, contributing to the N2O formation. Water inhibits the reactions of NH3 with the stored oxygen. On the contrary, the presence of CO2 increases the NH3 consumption. Furthermore, CO2 is able to provide additional oxygen for NH3 oxidation, forming –CO in analogy to the reverse water gas shift reaction.« less

  10. Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets

    SciTech Connect (OSTI)

    Davis, K.J.; Richardson, S.J.; Miles, N.L.

    2007-03-07

    Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within ± 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than ± 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than ± 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2?3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute are

  11. R&D100: CO2 Memzyme

    SciTech Connect (OSTI)

    Rempe, Susan; Brinker, Jeff; Jiang, Ying-Bing; Vanegas, Juan

    2015-11-19

    By combining a water droplet loaded with CO2 enzymes in an ultrathin nanopore on a flexible substrate, researchers at Sandia National Laboratories realized the first technology that meets and exceeds DOE targets for cost-effective CO2 capture. When compared with the nearest membrane competitor, this technology delivers a three times permeation rate, twenty times higher selectivity, and ten time lower fabrication cost. The CO2 Memzyme has the potential to remove 90% of CO2 emissions and is forecasted to save the U.S. coal industry $90 billion a year compared to conventional technology.

  12. CO2 Europipe | Open Energy Information

    Open Energy Info (EERE)

    www.co2europipe.eu Equivalent URI: cleanenergysolutions.orgcontentco2-europipe Language: English Policies: "Deployment Programs,Regulations,Financial Incentives" is not in...

  13. CO2 Tech | Open Energy Information

    Open Energy Info (EERE)

    produces and installs equipment for controlling and measuring atmospheric emissions and greenhouse gases for a wide variety of industries. References: CO2 Tech1 This article is...

  14. CO2 Conference Presentation | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    CO2 Conference Presentation More Documents & Publications POWER-GEN Conference Presentation U.S. Energy Association Presentation EEI Environment Meetings Presentation...

  15. CO2 Heat Pump Water Heater

    Broader source: Energy.gov (indexed) [DOE]

    CO 2 Heat Pump Water Heater 2014 Building Technologies Office Peer Review Evaporator Kyle ... MarketAudience: Residential electric water heating Key Partners: GE Appliances CRADA ...

  16. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z; Dong, J. H.

    2008-10-01

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  17. Hopper Hours Used

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hours Used Hopper Hours Used 2015 Hopper Usage Chart Hopper Usage Chart 2014 Hopper Usage ... Hopper Usage Chart 2011 Hopper Usage Chart Hopper Usage Chart 2015 Date Hours Used (in ...

  18. Ombuds Office Location & Hours

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ombuds Office Location & Hours Ombuds Office Location & Hours Committed to the fair and equitable treatment of all employees, contractors, and persons doing business with the...

  19. Residential CO2 Heat Pump Water Heater | Department of Energy

    Energy Savers [EERE]

    Residential CO2 Heat Pump Water Heater Residential CO2 Heat Pump Water Heater CO2 Heat Pump Water Heater Prototype
    Credit: Oak Ridge National Lab CO2 Heat Pump Water Heater ...

  20. Microsoft Word - CO2 Supplement.doc

    Gasoline and Diesel Fuel Update (EIA)

    Understanding the Decline in Carbon Dioxide Emissions in 2009 1 EIA projects carbon dioxide (CO2) emissions from fossil fuels in 2009 to be 5.9 percent below the 2008 level in the Short-Term Energy Outlook, October 2009 (STEO) (Table 1). Projected coal CO2 emissions fall by 10.1 percent in 2009, primarily because of lower consumption for electricity generation. Coal accounts for 63 percent of the total decline in CO2 emissions from fossil fuels this year. Forecast lower natural gas and petroleum

  1. Franklin Hours Used

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Franklin Hours Used Franklin Hours Used 2011 Franklin Usage in Hours 2011 Franklin Usage in Hours 2010 2010 Franklin Usage in Hours 2009 2009 Franklin Usage in Hours 2007-2008 2008 Franklin Usage in Hours 2008 Franklin Usage in Hours Date Hours Used (in thousands) Percentage of Maximum Possible (24 hours/day) 04/28/2012 0.00 0.00 04/27/2012 272.62 29.40 04/26/2012 692.81 74.71 04/25/2012 841.60 90.75 04/24/2012 53.86 5.81 04/23/2012 432.01 46.59 04/22/2012 823.23 88.77 04/21/2012 473.95 51.11

  2. ARM - Campaign Instrument - co2lidar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Carbon Dioxide Doppler Lidar (CO2LIDAR) Instrument Categories Cloud Properties Campaigns Remote Cloud...

  3. CENIT CO2 | Open Energy Information

    Open Energy Info (EERE)

    and develop new solutions to reducing CO2 emissions from fossil fuel combustion during electricity generation. References: CENIT-CO21 This article is a stub. You can help...

  4. ARM - Campaign Instrument - co2air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Airborne Carbon Dioxide Analyzer System (CO2AIR) Instrument Categories...

  5. ARM - Campaign Instrument - co2flx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Carbon Dioxide Flux Measurement Systems (CO2FLX) Instrument Categories...

  6. 2011 NETL CO2 Capture Technology Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Pilot Test of Novel Electrochemical Membrane System for Carbon Dioxide Capture and Power Generation (FE0026580) Hossein Ghezel-Ayagh, FuelCell Energy, Inc. 4:00 p.m. CO2 Capture ...

  7. ARM - Measurement - Carbon dioxide (CO2) concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Carbon dioxide (CO2) concentration The amount of carbon dioxide, a heavy, colorless...

  8. CO2 | OpenEI Community

    Open Energy Info (EERE)

    cities CO2 emissions OpenEI suburbs US New research from the University of California-Berkeley shows that those who live in cities in the United States have significantly smaller...

  9. CO2-Based Glue - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Energy Efficiency Building Energy Efficiency Advanced Materials Advanced Materials Find More Like This Return to Search CO2-Based Glue An environmentally friendly epoxy that utilizes CO2 as a starting material National Energy Technology Laboratory Contact NETL About This Technology Weights suspended by plates that are held together with the adhesive Weights suspended by plates that are held together with the adhesive Plates held together by adhesive. Weights were suspended from the

  10. Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2

    Reports and Publications (EIA)

    2001-01-01

    This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

  11. Improving the NOx-CO2 Trade-Off of an HCCI Engine using a Multi...

    Office of Scientific and Technical Information (OSTI)

    16-19, 2007 in Detroit, MI. Research Org: Sandia National Laboratories (SNL-CA), Livermore, CA (United States) Sponsoring Org: USDOE National Nuclear Security Administration ...

  12. Edison Hours Used

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Edison Hours Used 2015 Edison Usage Chart Edison Usage Chart 2014 Edison Usage Chart Edison Usage Chart 2013 Edison Usage Chart Edison Usage Chart 2015 Date Hours Used (in ...

  13. Contacts / Hours - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contacts / Hours Hanford Meteorological Station Real Time Met Data from Around the Site Current and Past 48 Hours HMS Observations Daily HMS Extremes in Met Data Met and Climate Data Summary Products Contacts / Hours Current NWS Forecast for the Tri-Cities NWS Windchill Chart Contacts / Hours Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size Note: Using the telephone is the ONLY way to get up to the minute information. On duty Forecaster (509) 373-2716 Current

  14. Surface CO2 leakage during the first shallow subsurface CO2release experiment

    SciTech Connect (OSTI)

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2007-09-15

    A new field facility was used to study CO2 migrationprocesses and test techniques to detect and quantify potential CO2leakage from geologic storage sites. For 10 days starting 9 July 2007,and for seven days starting 5 August 2007, 0.1 and 0.3 t CO2 d-1,respectively, were released from a ~;100-m long, sub-water table (~;2.5-mdepth) horizontal well. The spatio-temporal evolution of leakage wasmapped through repeated grid measurements of soil CO2 flux (FCO2). Thesurface leakage onset, approach to steady state, and post-release declinematched model predictions closely. Modeling suggested that minimal CO2was taken up by groundwater through dissolution, and CO2 spread out ontop of the water table. FCO2 spatial patterns were related to well designand soil physical properties. Estimates of total CO2 discharge along withsoil respiration and leakage discharge highlight the influence ofbackground CO2 flux variations on detection of CO2 leakagesignals.

  15. OTC NOx baseline emission inventory, 1990

    SciTech Connect (OSTI)

    1995-07-01

    The objective of this effort was to compile and quality assure a data base of NOx emissions from fossil fuel-fired boilers and indirect heat exchanges greater than or equal to 250 million British thermal units per hour (MMBtu/hr) capacity and electric generating units greater than or equal to 15 megawatts (MW) in the Northeast Ozone Transport Region (OTR). Emissions for the period May 1 through September 30, 1990 (referred to as the 5-month summer season) were compiled and will be used as a basis for emission reduction targeting and trading.

  16. Compact Potentiometric NOx Sensor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Potentiometric NOx Sensor Compact Potentiometric NOx Sensor 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation pm023_singh_2011_p.pdf (1.09 MB) More Documents & Publications Compact Potentiometric O2/NOx Sensor Compact Potentiometric NOx Sensor Compact Potentiometric NOx

  17. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect (OSTI)

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late

  18. Feasibility of CO2 Capture from Mobile Sources | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Capture from Mobile Sources Feasibility of CO2 Capture from Mobile Sources Presents integrated system for post-combustion CO2 capture from mobile sources PDF icon ...

  19. Scientists Can Recycle CO2 Using Gold | Department of Energy

    Office of Environmental Management (EM)

    Can Recycle CO2 Using Gold Scientists Can Recycle CO2 Using Gold May 27, 2016 - 9:57am Addthis A new chemical process has the potential to reduce atmospheric CO2 emissions by ...

  20. Uncertainty analyses of CO2 plume expansion subsequent to wellbore...

    Office of Scientific and Technical Information (OSTI)

    in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. ... The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the ...

  1. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    An Integrated Framework for CO2 Accounting and Risk Analysis in CO2-EOR Sites Citation Details In-Document Search Title: An Integrated Framework for CO2 Accounting and Risk ...

  2. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2

  3. Measurement and Characterization of NOx Adsorber Regeneration...

    Broader source: Energy.gov (indexed) [DOE]

    Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects

  4. Porous Hexacyanometalates for CO2 capture applications

    SciTech Connect (OSTI)

    Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

    2013-07-30

    Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

  5. Hopewell Beneficial CO2 Capture for Production of Fuels, Fertilizer and Energy

    SciTech Connect (OSTI)

    UOP; Honeywell Resins & Chemicals; Honeywell Process Solutions; Aquaflow Bionomics Ltd

    2010-09-30

    For Phase 1 of this project, the Hopewell team developed a detailed design for the Small Scale Pilot-Scale Algal CO2 Sequestration System. This pilot consisted of six (6) x 135 gallon cultivation tanks including systems for CO2 delivery and control, algal cultivation, and algal harvesting. A feed tank supplied Hopewell wastewater to the tanks and a receiver tank collected the effluent from the algal cultivation system. The effect of environmental parameters and nutrient loading on CO2 uptake and sequestration into biomass were determined. Additionally the cost of capturing CO2 from an industrial stack emission at both pilot and full-scale was determined. The engineering estimate evaluated Amine Guard technology for capture of pure CO2 and direct stack gas capture and compression. The study concluded that Amine Guard technology has lower lifecycle cost at commercial scale, although the cost of direct stack gas capture is lower at the pilot scale. Experiments conducted under high concentrations of dissolved CO2 did not demonstrate enhanced algae growth rate. This result suggests that the dissolved CO2 concentration at neutral pH was already above the limiting value. Even though dissolved CO2 did not show a positive effect on biomass growth, controlling its value at a constant set-point during daylight hours can be beneficial in an algae cultivation stage with high algae biomass concentration to maximize the rate of CO2 uptake. The limited enhancement of algal growth by CO2 addition to Hopewell wastewater was due at least in part to the high endogenous CO2 evolution from bacterial degradation of dissolved organic carbon present at high levels in the wastewater. It was found that the high level of bacterial activity was somewhat inhibitory to algal growth in the Hopewell wastewater. The project demonstrated that the Honeywell automation and control system, in combination with the accuracy of the online pH, dissolved O2, dissolved CO2, turbidity, Chlorophyll A and

  6. Meeting the CO2 Challenge DEER 2002 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the CO2 Challenge DEER 2002 Meeting the CO2 Challenge DEER 2002 2002 DEER Conference Presentation: Ricardo PDF icon 2002deergraham.pdf More Documents & Publications Application ...

  7. CO2 Capture by Absorption with Potassium Carbonate (Technical...

    Office of Scientific and Technical Information (OSTI)

    CO2 Capture by Absorption with Potassium Carbonate Citation Details In-Document Search Title: CO2 Capture by Absorption with Potassium Carbonate You are accessing a document ...

  8. CO2 Capture by Absorption with Potassium Carbonate (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: CO2 Capture by Absorption with Potassium Carbonate Citation Details In-Document Search Title: CO2 Capture by Absorption with Potassium Carbonate You are ...

  9. Grangemouth Advanced CO2 Capture Project GRACE | Open Energy...

    Open Energy Info (EERE)

    Grangemouth Advanced CO2 Capture Project GRACE Jump to: navigation, search Name: Grangemouth Advanced CO2 Capture Project (GRACE) Place: United Kingdom Sector: Carbon Product:...

  10. CO2 Global Solutions International | Open Energy Information

    Open Energy Info (EERE)

    Global Solutions International Jump to: navigation, search Name: CO2 Global Solutions International Place: Madrid, Spain Zip: 28001 Sector: Carbon Product: CO2 Global Solutions is...

  11. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  12. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    Conference: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 Citation Details In-Document Search Title: EGS rock reactions ...

  13. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing the ...

  14. Ganglion dynamics of Supercritical CO2 in heterogeneous media...

    Office of Scientific and Technical Information (OSTI)

    Ganglion dynamics of Supercritical CO2 in heterogeneous media. Citation Details In-Document Search Title: Ganglion dynamics of Supercritical CO2 in heterogeneous media. Abstract ...

  15. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Monitoring CO2 intrusion and associated geochemical transformations in a shallow ... Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated ...

  16. Texas CO2 Capture Demonstration Project Hits Three Million Metric...

    Office of Environmental Management (EM)

    Texas CO2 Capture Demonstration Project Hits Three Million Metric Ton Milestone Texas CO2 Capture Demonstration Project Hits Three Million Metric Ton Milestone June 30, 2016 - ...

  17. Further improvement of conventional diesel NOx aftertreatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Further improvement of conventional diesel NOx aftertreatment concepts as pathway for SULEV Further improvement of conventional diesel NOx aftertreatment concepts as pathway for ...

  18. 10-MW Supercritical-CO2 Turbine

    Broader source: Energy.gov [DOE]

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  19. Continuous CO2 extractor and methods

    SciTech Connect (OSTI)

    None listed

    2010-06-15

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  20. NETL CO2 Storage Frequently Asked Questions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Storage Frequently Asked Questions faq-header-big.jpg A combined portfolio of carbon management options for fossil fuel use can be implemented to manage current emission levels of greenhouse gases (GHGs) while enhancing energy security and building the technologies and knowledge base for export to other countries faced with reducing emissions. The U.S. portfolio includes Use of fuels with reduced carbon intensity: renewables, nuclear, and natural gas. Adoption of more efficient technologies

  1. Allocation of Flight Hours

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Allocation of Flight Hours for G-1 Pattern Number Name/Description Hours per flight Number of Flights Total # of Hours Fraction of Allotment (60hrs) Likely Start Time Weather Conditions 1 Stack Pattern 1 (Instrument testing) 3.5 1 3.5 6% 10:00-12:00 Shallow clouds, Cu Hu- Cu Me, Ci are okay 2 Stack Pattern 2 Basic OKC Cloudy Air Flight Plan (some in coordination with ER-2) 3.5 5 17.5 30% 10:00-12:00 Shallow clouds, Cu Hu- Cu Me, Ci are okay 3 Stack Pattern 3 Basic OKC Clear Air Flight Plan 3.5 5

  2. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for Postcombustion Carbon Dioxide Capture...

  3. Molecular Simulation Studies of Separation of CO2/N2, CO2/CH4...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    do this, we first identified a suitable force field for describing CO2, N2, and CH4 adsorption in ZIFs. On the basis of the validated force field, adsorption selectivities of the...

  4. Hopper Hours Used

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hours Used Hopper Hours Used 2015 Hopper Usage Chart Hopper Usage Chart 2014 Hopper Usage Chart Hopper Usage Chart 2013 Hopper Usage Chart Hopper Usage Chart 2012 Hopper Usage Chart Hopper Usage Chart 2011 Hopper Usage Chart Hopper Usage Chart 2015 Date Hours Used (in millions) Percent of Maximum Possible (24 hours/day) 09/20/2015 3.247 88.2 09/19/2015 3.401 92.4 09/18/2015 3.425 93.0 09/17/2015 3.450 93.7 09/16/2015 3.413 92.7 09/15/2015 3.466 94.1 09/14/2015 3.299 89.6 09/13/2015 3.436 93.3

  5. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect (OSTI)

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  6. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    SciTech Connect (OSTI)

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O'Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  7. CO2 Heat Pump Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO 2 Heat Pump Water Heater 2016 Building Technologies Office Peer Review Kyle Gluesenkamp, gluesenkampk@ornl.gov Oak Ridge National Laboratory Evaporator 2 Project Summary Timeline: Start date: Oct 1, 2009 Planned end date: Sep 30, 2016 Key Milestones 1. Go/No-Go: Price premium <$750 compared to baseline HFC HPWH; FY15Q2 (MET) 2. Go/No-Go: EF>2.0 and FHR>50 gallon to meet ENERGY STAR qualification criteria; FY14Q4 (MET) Budget: Total DOE to Date: $2,367k Total Project: $2,435k Key

  8. On Leakage from Geologic Storage Reservoirs of CO2

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-02-14

    Large amounts of CO2 would need to be injected underground to achieve a significant reduction of atmospheric emissions. The large areal extent expected for CO2 plumes makes it likely that caprock imperfections will be encountered, such as fault zones or fractures, which may allow some CO2 to escape from the primary storage reservoir. Leakage of CO2 could also occur along wellbores. Concerns with escape of CO2 from a primary geologic storage reservoir include (1) acidification of groundwater resources, (2) asphyxiation hazard when leaking CO2 is discharged at the land surface, (3) increase in atmospheric concentrations of CO2, and (4) damage from a high-energy, eruptive discharge (if such discharge is physically possible). In order to gain public acceptance for geologic storage as a viable technology for reducing atmospheric emissions of CO2, it is necessary to address these issues and demonstrate that CO2 can be injected and stored safely in geologic formations.

  9. Carver Hours Used

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carver Hours Used Carver Hours Used Hopper Usage Chart Hopper Usage Chart Date Hours Used (in millions) Percent of Maximum Possible (24 hours/day) 12/15/2014 161.25 84.75 12/14/2014 162.32 85.31 12/13/2014 165.95 87.22 12/12/2014 172.69 90.76 12/11/2014 174.45 91.69 12/10/2014 170.09 89.39 12/09/2014 166.50 87.50 12/08/2014 169.20 88.92 12/07/2014 167.44 88.00 12/06/2014 172.83 90.83 12/05/2014 176.73 92.89 12/04/2014 174.69 91.81 12/03/2014 178.77 93.96 12/02/2014 172.30 90.55 12/01/2014 176.12

  10. Measurement and Characterization of Lean NOx Adsorber Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Adsorber Regeneration and Desulfation and Controlling NOx from Multi-mode Measurement and Characterization of Lean NOx Adsorber Regeneration and Desulfation and ...

  11. A Comparative Study on the Environmental Impact of CO2 Supermarket Refrigeration Systems

    SciTech Connect (OSTI)

    Beshr, Mohamed; Aute, Vikrant; Sharma, Vishaldeep; Abdelaziz, Omar; Fricke, Brian A; Radermacher, Reinhard

    2014-01-01

    Supermarket refrigeration systems have high environmental impact due to their large refrigerant charge and high leak rates. Accordingly, the interest in using natural refrigerants, such as carbon dioxide (CO2), and new refrigerant blends with low GWP in such systems is increasing. In this paper, an open-source Life Cycle Climate Performance (LCCP) framework is presented and used to compare the environmental impact of three supermarket refrigeration systems. These systems include a transcritical CO2 booster system, a cascade CO2/N-40 system, and a baseline R-404A multiplex direct expansion system. The study is performed for cities representing different climates within the USA using EnergyPlus to simulate the systems' hourly performance. Finally, a parametric analysis is performed to study the impact of annual leak rate on the systems' LCCP.

  12. Transient studies of an Integrated Gasification Combined Cycle (IGCC) plant with CO2 capture

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2010-01-01

    Next-generation coal-fired power plants need to consider the option for CO2 capture as stringent governmental mandates are expected to be issued in near future. Integrated gasification combined cycle (IGCC) plants are more efficient than the conventional coal combustion processes when the option for CO2 capture is considered. However, no IGCC plant with CO2 capture currently exists in the world. Therefore, it is important to consider the operability and controllability issues of such a plant before it is commercially built. To facilitate this objective, a detailed plant-wide dynamic simulation of an IGCC plant with 90% CO2 capture has been developed in Aspen Plus Dynamics{reg_sign}. The plant considers a General Electric Energy (GEE)-type downflow radiant-only gasifier followed by a quench section. A two-stage water gas shift (WGS) reaction is considered for conversion of CO to CO2. A two-stage acid gas removal (AGR) process based on a physical solvent is simulated for selective capture of H2S and CO2. Compression of the captured CO2 for sequestration, an oxy-Claus process for removal of H2S and NH3, black water treatment, and the sour water treatment are also modeled. The tail gas from the Claus unit is recycled to the SELEXOL unit. The clean syngas from the AGR process is sent to a gas turbine followed by a heat recovery steam generator. This turbine is modeled as per published data in the literature. Diluent N2 is used from the elevated-pressure ASU for reducing the NOx formation. The heat recovery steam generator (HRSG) is modeled by considering generation of high-pressure, intermediate-pressure, and low-pressure steam. All of the vessels, reactors, heat exchangers, and the columns have been sized. The basic IGCC process control structure has been synthesized by standard guidelines and existing practices. The steady state results are validated with data from a commercial gasifier. In the future grid-connected system, the plant should satisfy the environmental

  13. CantorCO2e | Open Energy Information

    Open Energy Info (EERE)

    CantorCO2e Jump to: navigation, search Name: CantorCO2e Place: London, Greater London, United Kingdom Zip: E14 5RD Product: London-headquartered emissions broker and fund manager...

  14. CO2 Capture Poject CCP | Open Energy Information

    Open Energy Info (EERE)

    CO2 Capture Poject CCP Jump to: navigation, search Name: CO2 Capture Poject (CCP) Place: United Kingdom Sector: Carbon Product: CCP is a partnership of energy companies and...

  15. North America's net terrestrial CO2 exchange with the atmosphere...

    Office of Scientific and Technical Information (OSTI)

    a synthesis of net land-atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990-2009. Only CO2 is considered, not methane or...

  16. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that...

  17. Supercritical CO2 Tech Team | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    offered by the sCO2 Brayton Cycle technology (compared to the widely-used steam turbine Rankin Cycle.) Benefits of the sCO2 Brayton Cycle for energy production Economic ...

  18. Enhanced Geothermal Systems: Comparing Water and CO2 as Heat...

    Office of Scientific and Technical Information (OSTI)

    ENHANCED GEOTHERMAL SYSTEMS (EGS): COMPARING WATER AND CO 2 AS HEAT TRANSMISSION FLUIDS ... with supercritical CO 2 instead of water as heat transmission fluid (D.W. Brown, 2000). ...

  19. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    An integrated framework for CO2 accounting and risk analysis of CO2-EOR Authors: Dai, Zhenxue 1 ; Viswanathan, Hari S. 1 ; Middleton, Richard Stephen 1 ; Fessenden-Rahn, ...

  20. Shell Future Fuels and CO2 | Open Energy Information

    Open Energy Info (EERE)

    Shell Future Fuels and CO2 Jump to: navigation, search Name: Shell Future Fuels and CO2 Place: Glasgow, Scotland, United Kingdom Zip: G1 9BG Sector: Hydro, Hydrogen Product:...

  1. CO2ReMoVe | Open Energy Information

    Open Energy Info (EERE)

    of industrial, research and service organizations with experience in CO2 geological storage. References: CO2ReMoVe1 This article is a stub. You can help OpenEI by expanding...

  2. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins...

    Office of Scientific and Technical Information (OSTI)

    CO2 storage site, the Rangely Oil Field, where CO2-EOR has been underway since the 1980s. ... as well as methane and trace gases) of conventional and unconventional oil and gas. ...

  3. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    up with a net reduction in the CO2 emitted. Thus, effective catalysts that can lower the energy requirements for CO2 chemical reactions are an important part of the equation....

  4. Overview of the CO2 Geological Sequestration System

    Office of Scientific and Technical Information (OSTI)

    CO 2 is a so-called "greenhouse gas" that traps infrared radiation and may contribute to global warming. Scientists project that greenhouse gases such as CO 2 will make the arctic ...

  5. CO2 Injection Begins in Illinois | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Injection Begins in Illinois CO2 Injection Begins in Illinois November 17, 2011 - 12:00pm Addthis Washington, DC - The Midwest Geological Sequestration Consortium (MGSC), one of seven regional partnerships created by the U.S. Department of Energy (DOE) to advance carbon storage technologies nationwide, has begun injecting carbon dioxide (CO2) for their large-scale CO2 injection test in Decatur, Illinois. The test is part of the development phase of the Regional Carbon Sequestration

  6. Pressure data from Cranfield CO2 Thermosiphon test

    SciTech Connect (OSTI)

    Barry Freifeld

    2015-01-21

    Pressure data acquired in well F2 and F3 during the CO2 geothermal thermosiphoning test, Cranfield MS.

  7. Industrial CO2 Removal: CO2 Capture from Ambient Air and Geological Sequestration

    SciTech Connect (OSTI)

    Dooley, James J.

    2011-06-08

    This abstract and its accompanying presentation will provide an overview of two distinct industrial processes for removing carbon dioxide (CO2) from the atmosphere as a means of addressing anthropogenic climate change. The first of these is carbon dioxide capture and storage (CCS) coupled with large scale biomass production (hereafter referred to as bioCCS). The second is CO2 capture from ambient air via industrial systems (hereafter referred to as direct air capture (DAC)). In both systems, the captured CO2 would be injected into deep geologic formations so as to isolate it from the atmosphere. The technical literature is clear that both of these technologies are technically feasible as of today (IPCC, 2005; Keith, 2009; Lackner, 2009; Luckow et al., 2010; Ranjan and Herzog, 2011). What is uncertain is the relative cost of these industrial ambient-air CO2 removal systems when compared to other emissions mitigation measures, the ultimate timing and scale of their deployment, and the resolution of potential site specific constraints that would impact their ultimate commercial deployment.

  8. In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO2

    SciTech Connect (OSTI)

    Loring, John S.; Thompson, Christopher J.; Wang, Zheming; Joly, Alan G.; Sklarew, Deborah S.; Schaef, Herbert T.; Ilton, Eugene S.; Rosso, Kevin M.; Felmy, Andrew R.

    2011-07-19

    Carbonation reactions are central to the prospect of CO2 trapping by mineralization in geologic reservoirs. In contrast to the relevant aqueous-mediated reactions, little is known about the propensity for carbonation in the long-term partner fluid: water-containing supercritical carbon dioxide (‘wet’ scCO2). We employed in situ mid-infrared spectroscopy to follow the reaction of a model silicate mineral (forsterite, Mg2SiO4) for 24 hr with wet scCO2 at 50°C and 180 atm, using water concentrations corresponding to 0%, 55%, 95%, and 136% saturation. Results show a dramatic dependence of reactivity on water concentration and the presence of liquid water on the forsterite particles. Exposure to neat scCO2 showed no detectable carbonation reaction. At 55% and 95% water saturation, a liquid-like thin water film was detected on the forsterite particles; less than 1% of the forsterite transformed, mostly within the first 3 hours of exposure to the fluid. At 136% saturation, where an (excess) liquid water film approximately several nanometers thick was intentionally condensed on the forsterite, the carbonation reaction proceeded continuously for 24 hr with 10% to 15% transformation. Our collective results suggest constitutive links between water concentration, water film formation, reaction rate and extent, and reaction products in wet scCO2.

  9. DOE - Fossil Energy: Knocking the NOx Out of Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-Knocking Out NOx An Energy Lesson Cleaning Up Coal Knocking the NOx Out of Coal - How NOx Forms - Formation of NOx - Air is mostly nitrogen molecules (green in the above diagram) ...

  10. Geothermal Electrical Production CO2 Emissions Study

    SciTech Connect (OSTI)

    K. K. Bloomfield; J. N. Moore

    1999-10-01

    Emission of �greenhouse gases� into the environment has become an increasing concern. Deregulation of the electrical market will allow consumers to select power suppliers that utilize �green power.� Geothermal power is classed as �green power� and has lower emissions of carbon dioxide per kilowatt-hour of electricity than even the cleanest of fossil fuels, natural gas. However, previously published estimates of carbon dioxide emissions are relatively old and need revision. This study estimates that the average carbon dioxide emissions from geothermal and fossil fuel power plants are: geothermal 0.18 , coal 2.13, petroleum 1.56 , and natural gas 1.03 pounds of carbon dioxide per kilowatt-hour respectively.

  11. Geothermal Electrical Production CO2 Emissions Study

    SciTech Connect (OSTI)

    Bloomfield, Kevin Kit; Moore, J. N.

    1999-10-01

    Emission of “greenhouse gases” into the environment has become an increasing concern. Deregulation of the electrical market will allow consumers to select power suppliers that utilize “green power.” Geothermal power is classed as “green power” and has power emissions of carbon dioxide per kilowatt-hour of electricity than even the cleanest of fossil fuels, natural gas. However, previously published estimates of carbon dioxide emissions are relatively old and need revision. This study estimates that the average carbon dioxide emissions from geothermal and fossil fuel power plants are: geothermal 0.18 , coal 2.13, petroleum 1.56 , and natural gas 1.03 pounds of carbon dioxide per kilowatt-hour respectively.

  12. NOx sensor development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    sensor development NOx sensor development pm005_glass_2012_o.pdf (835.92 KB) More Documents & Publications NOxsensor development NOx Sensor Development Vehicle Technologies Office: 2013 Propulsion Materials R&D Annual Progress Report

  13. NOx adsorber and method of regenerating same

    DOE Patents [OSTI]

    Endicott, Dennis L.; Verkiel, Maarten; Driscoll, James J.

    2007-01-30

    New technologies, such as NOx adsorber catalytic converters, are being used to meet increasingly stringent regulations on undesirable emissions, including NOx emissions. NOx adsorbers must be periodically regenerated, which requires an increased fuel consumption. The present disclosure includes a method of regenerating a NOx adsorber within a NOx adsorber catalytic converter. At least one sensor positioned downstream from the NOx adsorber senses, in the downstream exhaust, at least one of NOx, nitrous oxide and ammonia concentrations a plurality of times during a regeneration phase. The sensor is in communication with an electronic control module that includes a regeneration monitoring algorithm operable to end the regeneration phase when a time rate of change of the at least one of NOx, nitrous oxide and ammonia concentrations is after an expected plateau region begins.

  14. Supersonic Technology for CO2 Capture: A High Efficiency Inertial CO2 Extraction System

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Researchers at ATK and ACENT Laboratories are developing a device that relies on aerospace wind-tunnel technologies to turn CO2 into a condensed solid for collection and capture. ATK’s design incorporates a special nozzle that converges and diverges to expand flue gas, thereby cooling it off and turning the CO2 into solid particles which are removed from the system by a cyclonic separator. This technology is mechanically simple, contains no moving parts and generates no chemical waste, making it inexpensive to construct and operate, readily scalable, and easily integrated into existing facilities. The increase in the cost to coal-fired power plants associated with introduction of this system would be 50% less than current technologies.

  15. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs

    SciTech Connect (OSTI)

    Grigg, Reid B.; Schechter, David S.

    1999-10-15

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

  16. Fundamental limits on gas-phase chemical reduction of NOx in a plasma

    SciTech Connect (OSTI)

    Penetrante, B.M.; Hsiao, M.C.; Merritt, B.T.; Vogtlin, G.E.

    1997-12-31

    In the plasma, the electrons do not react directly with the NOx molecules. The electrons collide mainly with the background gas molecules like N{sub 2}, O{sub 2} and H{sub 2}O. Electron impact on these molecules result partly in dissociation reactions that produce reactive species like N, O and OH. The NOx in the engine exhaust gas initially consist mostly of NO. The ground state nitrogen atom, N, is the only species that could lead to the chemical reduction of NO to N{sub 2}. The O radical oxidizes NO to NO{sub 2} leaving the same amount of NOx. The OH radical converts NO{sub 2} to nitric acid. Acid products in the plasma can easily get adsorbed on surfaces in the plasma reactor and in the pipes. When undetected, the absence of these oxidation products can often be mistaken for chemical reduction of NOx. In this paper the authors will examine the gas-phase chemical reduction of NOx. They will show that under the best conditions, the plasma can chemically reduce 1.6 grams of NOx per brake-horsepower-hour [g(NOx)/bhp-hr] when 5% of the engine output energy is delivered to the plasma.

  17. PV Hourly Simulation Tool

    Energy Science and Technology Software Center (OSTI)

    2010-12-31

    This software requires inputs of simple general building characteristics and usage information to calculate the energy and cost benefits of solar PV. This tool conducts and complex hourly simulation of solar PV based primarily on the area available on the rooftop. It uses a simplified efficiency calculation method and real panel characteristics. It includes a detailed rate structure to account for time-of-use rates, on-peak and off-peak pricing, and multiple rate seasons. This tool includes themore » option for advanced system design inputs if they are known. This tool calculates energy savings, demand reduction, cost savings, incentives and building life cycle costs including: simple payback, discounted payback, net-present value, and savings to investment ratio. In addition this tool also displays the environmental benefits of a project.« less

  18. Modeling global atmospheric CO2 with improved emission inventories and CO2 production from the oxidation of other carbon species

    SciTech Connect (OSTI)

    Nassar, Ray; Jones, DBA; Suntharalingam, P; Chen, j.; Andres, Robert Joseph; Wecht, K. J.; Yantosca, R. M.; Kulawik, SS; Bowman, K; Worden, JR; Machida, T; Matsueda, H

    2010-01-01

    The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of CO2 chemical production on monthly-averaged loss rates of CO (a key precursor and intermediate in the oxidation of organic carbon) and apply an associated surface correction for inventories that have counted emissions of CO2 precursors as CO2. We also explore the benefit of assimilating satellite observations of CO into GEOS-Chem to obtain an observation-based estimate of the CO2 chemical source. The CO assimilation corrects for an underestimate of atmospheric CO abundances in the model, resulting in increases of as much as 24% in the chemical source during May June 2006, and increasing the global annual estimate of CO2 chemical production from 1.05 to 1.18 Pg C. Comparisons of model CO2 with measurements are carried out in order to investigate the spatial and temporal distributions that result when these new sources are added. Inclusion of CO2 emissions from shipping and aviation are shown to increase the global CO2 latitudinal gradient by just over 0.10 ppm (3%), while the inclusion of CO2 chemical production (and the surface correction) is shown to decrease the latitudinal gradient by about 0.40 ppm (10%) with a complex spatial structure

  19. Method And Apparatus For Regenerating Nox Adsorbers

    DOE Patents [OSTI]

    Driscoll, J. Joshua; Endicott, Dennis L.; Faulkner, Stephen A.; Verkiel, Maarten

    2006-03-28

    Methods and apparatuses for regenerating a NOx adsorber coupled with an exhaust of an engine. An actuator drives a throttle valve to a first position when regeneration of the NOx adsorber is desired. The first position is a position that causes the regeneration of the NOx adsorber. An actuator drives the throttle valve to a second position while regeneration of the NOx adsorber is still desired. The second position being a position that is more open than the first position and operable to regenerate a NOx adsorber.

  20. CO2 exposure at pressure impacts metabolism and stress responses in the model sulfate-reducing bacterium Desulfovibrio vulgaris strain Hildenborough

    SciTech Connect (OSTI)

    Wilkins, Michael J.; Hoyt, David W.; Marshall, Matthew J.; Alderson, Paul A.; Plymale, Andrew E.; Markillie, Lye Meng; Tucker, Abigail E.; Walter, Eric D.; Linggi, Bryan E.; Dohnalkova, Alice; Taylor, Ronald C.

    2014-09-01

    Geologic carbon dioxide (CO2) sequestration drives physical and geochemical changes in deep subsurface environments that impact indigenous microbial activities. The combined effects of pressurized CO2 on a model sulfate-reducing microorganism, Desulfovibrio vulgaris, have been assessed using a suite of genomic and kinetic measurements. Novel high-pressure NMR time-series measurements using 13C-lactate were used to track D. vulgaris metabolism. We identified cessation of respiration at CO2 pressures of 10 bar, 25 bar, 50 bar, and 80 bar. Concurrent experiments using N2 as the pressurizing phase had no negative effect on microbial respiration, as inferred from reduction of sulfate to sulfide. Complementary pressurized batch incubations and fluorescence microscopy measurements supported NMR observations, and indicated that non-respiring cells were mostly viable at 50 bar CO2 for at least four hours, and at 80 bar CO2 for two hours. The fraction of dead cells increased rapidly after four hours at 80 bar CO2. Transcriptomic (RNA-Seq) measurements on mRNA transcripts from CO2-incubated biomass indicated that cells up-regulated the production of certain amino acids (leucine, isoleucine) following CO2 exposure at elevated pressures, likely as part of a general stress response. Evidence for other poorly understood stress responses were also identified within RNA-Seq data, suggesting that while pressurized CO2 severely limits the growth and respiration of D. vulgaris cells, biomass retains intact cell membranes at pressures up to 80 bar CO2. Together, these data show that geologic sequestration of CO2 may have significant impacts on rates of sulfate reduction in many deep subsurface environments where this metabolism is a key respiratory process.

  1. Controlling NOx emission from industrial sources

    SciTech Connect (OSTI)

    Srivastava, R.K.; Nueffer, W.; Grano, D.; Khan, S.; Staudt, J.E.; Jozewicz, W.

    2005-07-01

    A number of regulatory actions focused on reducing NOx emissions from stationary combustion sources have been taken in the United States in the last decade. These actions include the Acid Rain NOx regulations, the Ozone Transport Commission's NOx Budget Program, and the NOx SIP Call rulemakings. In addition to these regulations, the recent Interstate Air Quality Rulemaking proposal and other bills in the Congress are focusing on additional reductions of NOx. Industrial combustion sources accounted for about 18016 of NOx emissions in the United States in 2000 and constituted the second largest emitting source category within stationary sources, only behind electric utility sources. Based on these data, reduction of NOx emissions from industrial combustion sources is an important consideration in efforts undertaken to address the environmental concerns associated with NOx. This paper discusses primary and secondary NOx control technologies applicable to various major categories of industrial sources. The sources considered in this paper include large boilers, furnaces and fired heaters, combustion turbines, large IC engines, and cement kilns. For each source category considered in this paper, primary NOx controls are discussed first, followed by a discussion of secondary NOx controls.

  2. Supercritical CO2 Power Cycles: Design Considerations for Concentrating

    Office of Scientific and Technical Information (OSTI)

    Solar Power (Conference) | SciTech Connect Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power Citation Details In-Document Search Title: Supercritical CO2 Power Cycles: Design Considerations for Concentrating Solar Power A comparison of three supercritical CO2 Brayton cycles: the simple cycle, recompression cycle and partial-cooling cycle indicates the partial-cooling cycle is favored for use in concentrating solar power (CSP) systems. Although it displays

  3. 'Underground battery' could store renewable energy, sequester CO2 |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) 'Underground battery' could store renewable energy, sequester CO2 Wednesday, January 6, 2016 - 2:40pm NNSA Blog This integrated system would store carbon dioxide in an underground reservoir, with concentric rings of horizontal wells confining the pressurized CO2 beneath the caprock. Stored CO2 displaces brine that flows up wells to the surface where it is heated by thermal plants (e.g., solar farms) and reinjected into the reservoir to store

  4. Efficient Theoretical Screening of Solid Sorbents for CO2 Capture

    Office of Scientific and Technical Information (OSTI)

    Applications* (Journal Article) | SciTech Connect Journal Article: Efficient Theoretical Screening of Solid Sorbents for CO2 Capture Applications* Citation Details In-Document Search Title: Efficient Theoretical Screening of Solid Sorbents for CO2 Capture Applications* By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO2 sorbent candidates

  5. Misrepresentation of the IPCC CO2 emission scenarios (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Misrepresentation of the IPCC CO2 emission scenarios Citation Details In-Document Search Title: ... with the IPCC SRES (Special Report on Emission Scenarios) ...

  6. Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tech/NETL Research | Department of Energy Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia Tech/NETL Research Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia Tech/NETL Research October 20, 2015 - 8:14am Addthis Researchers from Virginia Tech are injecting CO2 into coal seams in three locations in Buchanan County, Va., as part of an NETL-sponsored CO2 storage research project associated with enhanced gas recovery. Researchers from Virginia Tech are

  7. Commercial CO2 Electric HPWH | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    PROJECT OBJECTIVE Residential heat pump water heaters (HPWH) that use carbon dioxide (CO2) ... Information flow schematic for an integrated heat pump design model and wrapped tank ...

  8. CO2 interaction with geomaterials. (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    to investigate the effect of CO2 pressure on the thermoplastic properties of coal. ... Thus, conventional polymer (or 'geopolymer') theories may not be directly applicable to ...

  9. Hyperspectral Geobotanical Remote Sensing For Co2 Storage Monitoring...

    Open Energy Info (EERE)

    Hyperspectral Geobotanical Remote Sensing For Co2 Storage Monitoring Jump to: navigation, search OpenEI Reference LibraryAdd to library Book: Hyperspectral Geobotanical Remote...

  10. Photosynthetic Conversion of CO2 to Fuels and Chemicals using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photosynthetic Conversion of CO 2 to Fuels and Chemicals using Cyanobacteria Accelerating Innovation Webinar August 8, 2012 Jianping Yu, Ph.D., Senior Scientist * Many eukaryotic ...

  11. Game-Changing Process Mitigates CO2 Emissions Using Renewable...

    Broader source: Energy.gov (indexed) [DOE]

    Game-Changing Process Mitigates CO2 Emissions Using Renewable Energy Gold nanoparticles ... Researchers developed a special form of gold nanoparticle that contains exactly 25 gold ...

  12. CO2 Emissions from Fuel Combustion | Open Energy Information

    Open Energy Info (EERE)

    from international marine and aviation bunkers, and other relevant information" Excel Spreadsheet References "CO2 Emissions from Fuel Combustion" Retrieved from "http:...

  13. Enhanced Geothermal Systems (EGS) comparing water with CO2 as...

    Office of Scientific and Technical Information (OSTI)

    Enhanced Geothermal Systems (EGS) comparing water with CO2 as heattransmission fluids Citation Details In-Document Search Title: Enhanced Geothermal Systems (EGS) comparing water ...

  14. Tool for calculation of CO2 emissions from organisations | Open...

    Open Energy Info (EERE)

    lt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":"" Hide Map Language: English Tool for calculation of CO2 emissions from organisations Screenshot...

  15. Reversible Alteration of CO2 Adsorption upon Photochemical or...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reversible Alteration of CO2 Adsorption upon Photochemical or Thermal Treatment in a Metal-Organic Framework Previous Next List Jinhee Park , Daqiang Yuan , Khanh T. Pham , ...

  16. co2 capture meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2013 NETL CO2 Capture Technology Meeting July 8-11, 2013 Previous Proceedings 2012: NETL CO2 Capture Technology Meeting Proceedings of the 2013 NETL CO2 Capture Technology Meeting Table of Contents Presentations Monday, July 8 Opening/Overview Post-Combustion Sorbent-Based Capture Tuesday, July 9 Post-Combustion Solvent-Based Capture CO2 Compression Wednesday, July 10 Post-Combustion Membrane-Based Capture Pre-Combustion Capture Projects Thursday, July 11 ARPA-E Capture Projects System Studies

  17. CO2 Heat Pump Water Heater | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    other refrigerants), CO2 also has greater potential for use in residentialcommercial demand response units, as well as for high-temperature commercial water heating applications. ...

  18. Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia...

    Energy Savers [EERE]

    of an NETL-sponsored CO2 storage research project ... teamed with the National Energy Technology Laboratory ... A supervisory control and data acquisition (SCADA) system ...

  19. High Co2 Emissions Through Porous Media- Transport Mechanisms...

    Open Energy Info (EERE)

    Co2 Emissions Through Porous Media- Transport Mechanisms And Implications For Flux Measurement And Fractionation Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  20. Literature Review of Mobility Control Methods for CO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... year for 50 years), reducing oil imports by ... CO 2 captured from coal- fired power plants and other industrial ... and applying advanced methods for monitoring flood ...

  1. Secure and sustainable energy infrastructure: The case of CO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technical Report: Secure and sustainable energy infrastructure: The case of CO2 capture, utilization, and storage Citation Details In-Document Search Title: Secure and sustainable ...

  2. Sulfonate-Grafted Porous Polymer Networks for Preferential CO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sulfonate-Grafted Porous Polymer Networks for Preferential CO2 Adsorption at Low Pressure Previous Next List Weigang Lu, Daqiang Yuan, Julian Sculley, Dan Zhao, Rajamani Krishna,...

  3. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large CO2 Adsorption in Aluminosilicate Zeolites for Postcombustion Carbon Dioxide Capture Previous Next List Jihan Kim, Li-Chiang Lin, Joseph A. Swisher, Maciej Haranczyk, and...

  4. Chemical Impact of Elevated CO2on Geothermal Energy Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    analyzing the geochemistry of existing geothermal fields with elevated natural CO2; measuring realistic rock-water rates for geothermal systems using laboratory and field-based ...

  5. Kinetic performance of CO2 absorption into a potassium carbonate...

    Office of Scientific and Technical Information (OSTI)

    Title: Kinetic performance of CO2 absorption into a potassium carbonate solution ... Type: Publisher's Accepted Manuscript Journal Name: Chemical Engineering Journal (Print) ...

  6. ESTIMATING MAXIMUM SUSTAINABLE PRESSURE DURING CO2 INJECTION...

    Office of Scientific and Technical Information (OSTI)

    ... Presented at the Ground Water Protection Council 2008 Annual ... related to upwelling of deep CO2-rich fluids during the ... Engineers (SPE) Reservoir Evaluation & Engineering. ...

  7. Hybrid Membrane/Absorption Process for Post-combustion CO2 Capture

    SciTech Connect (OSTI)

    Li, Shiguang; Shou, S.; Pyrzynski, Travis; Makkuni, Ajay; Meyer, Howard

    2013-12-31

    This report summarizes scientific/technical progress made for bench-scale membrane contactor technology for post-combustion CO2 capture from DOE Contract No. DE-FE-0004787. Budget Period 1 (BP1) membrane absorber, Budget Period 2 (BP2) membrane desorber and Budget Period 3 (BP3) integrated system and field testing studies have been completed successfully and met or exceeded the technical targets (≥ 90% CO2 removal and CO2 purity of 97% in one membrane stage). Significant breakthroughs are summarized below: BP1 research: The feasibility of utilizing the poly (ether ether ketone), PEEK, based hollow fiber contractor (HFC) in combination with chemical solvents to separate and capture at least 90% of the CO2 from simulated flue gases has been successfully established. Excellent progress has been made as we have achieved the BP1 goal: ≥ 1,000 membrane intrinsic CO2 permeance, ≥ 90% CO2 removal in one stage, ≤ 2 psi gas side pressure drop, and ≥ 1 (sec)-1 mass transfer coefficient. Initial test results also show that the CO2 capture performance, using activated Methyl Diethanol Amine (aMDEA) solvent, was not affected by flue gas contaminants O2 (~3%), NO2 (66 ppmv), and SO2 (145 ppmv). BP2 research: The feasibility of utilizing the PEEK HFC for CO2-loaded solvent regeneration has been successfully established High CO2 stripping flux, one order of magnitude higher than CO2 absorption flux, have been achieved. Refined economic evaluation based on BP1 membrane absorber and BP2 membrane desorber laboratory test data indicate that the CO2 capture costs are 36% lower than DOE’s benchmark amine absorption technology. BP3 research: A bench-scale system utilizing a membrane absorber and desorber was integrated into a continuous CO2 capture process using contactors containing 10 to 20 ft2 of membrane area. The integrated process operation was stable through a 100-hour laboratory test, utilizing a simulated flue gas stream. Greater than 90% CO2 capture combined with 97

  8. Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use

    SciTech Connect (OSTI)

    Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

    2012-07-31

    field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture

  9. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration

    SciTech Connect (OSTI)

    Zuo, Lin; Benson, Sally M.

    2013-01-01

    A novel EOR method using carbonated water injection followed by depressurization is introduced. Results from micromodel experiments are presented to demonstrate the fundamental principles of this oil recovery method. A depressurization process (1 MPa/hr) was applied to a micromodel following carbonated water injection (Ca ? 10-5). The exsolved CO2 in water-filled pores blocked water flow in swiped portions and displaced water into oil-filled pores. Trapped oil after the carbonated water injection was mobilized by sequentially invading water. This method's self-distributed mobility control and local clogging was tested in a sandstone sample under reservoir conditions. A 10% incremental oil recovery was achieved by lowering the pressure 2 MPa below the CO2 liberation pressure. Additionally, exsolved CO2 resides in the pores of a reservoir as an immobile phase with a high residual saturation after oil production, exhibiting a potential synergy opportunity between CO2 EOR and CO2 sequestration

  10. Does elevated CO2 alter silica uptake in trees?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fulweiler, Robinson W.; Maguire, Timothy J.; Carey, Joanna C.; Finzi, Adrien C.

    2015-01-13

    Human activities have greatly altered global carbon (C) and Nitrogen (N) cycling. In fact, atmospheric concentrations of carbon dioxide (CO2) have increased 40% over the last century and the amount of N cycling in the biosphere has more than doubled. In an effort to understand how plants will respond to continued global CO2 fertilization, longterm free-air CO2 enrichment experiments have been conducted at sites around the globe. Here we examine how atmospheric CO2 enrichment and N fertilization affects the uptake of silicon (Si) in the Duke Forest, North Carolina, a stand dominated by Pinus taeda (loblolly pine), and five hardwoodmore » species. Specifically, we measured foliar biogenic silica concentrations in five deciduous and one coniferous species across three treatments: CO2 enrichment, N enrichment, and N and CO2 enrichment. We found no consistent trends in foliar Si concentration under elevated CO2, N fertilization, or combined elevated CO2 and N fertilization. However, two-thirds of the tree species studied here have Si foliar concentrations greater than well-known Si accumulators, such as grasses. Based on net primary production values and aboveground Si concentrations in these trees, we calculated forest Si uptake rates under control and elevated CO2 concentrations. Due largely to increased primary production, elevated CO2 enhanced the magnitude of Si uptake between 20 and 26%, likely intensifying the terrestrial silica pump. This uptake of Si by forests has important implications for Si export from terrestrial systems, with the potential to impact C sequestration and higher trophic levels in downstream ecosystems.« less

  11. Large CO2 effluxes at night and during synoptic weather events significantly contribute to CO2 emissions from a reservoir

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Heping; Zhang, Qianyu; Katul, Gabriel G.; Cole, Jonathan J.; Chapin, III, F. Stuart; MacIntyre, Sally

    2016-05-24

    CO2 emissions from inland waters are commonly determined by indirect methods that are based on the product of a gas transfer coefficient and the concentration gradient at the air water interface (e.g., wind-based gas transfer models). The measurements of concentration gradient are typically collected during the day in fair weather throughout the course of a year. Direct measurements of eddy covariance CO2 fluxes from a large inland water body (Ross Barnett reservoir, Mississippi, USA) show that CO2 effluxes at night are approximately 70% greater than those during the day. At longer time scales, frequent synoptic weather events associated with extratropicalmore » cyclones induce CO2 flux pulses, resulting in further increase in annual CO2 effluxes by 16%. Therefore, CO2 emission rates from this reservoir, if these diel and synoptic processes are under-sampled, are likely to be underestimated by approximately 40%. Our results also indicate that the CO2 emission rates from global inland waters reported in the literature, when based on indirect methods, are likely underestimated. Field samplings and indirect modeling frameworks that estimate CO2 emissions should account for both daytime-nighttime efflux difference and enhanced emissions during synoptic weather events. Furthermore, the analysis here can guide carbon emission sampling to improve regional carbon estimates.« less

  12. CO2 Capture with Liquid-to-Solid Absorbents: CO2 Capture Process Using Phase-Changing Absorbents

    SciTech Connect (OSTI)

    2010-10-01

    IMPACCT Project: GE and the University of Pittsburgh are developing a unique CO2 capture process in which a liquid absorbent, upon contact with CO2, changes into a solid phase. Once in solid form, the material can be separated and the CO2 can be released for storage by heating. Upon heating, the absorbent returns to its liquid form, where it can be reused to capture more CO2. The approach is more efficient than other solventbased processes because it avoids the heating of extraneous solvents such as water. This ultimately leads to a lower cost of CO2 capture and will lower the additional cost to produce electricity for coal-fired power plants that retrofit their facilities to include this technology.

  13. Combustion-Assisted CO2 Capture Using MECC Membranes

    SciTech Connect (OSTI)

    Sherman, Steven R; Gray, Dr. Joshua R.; Brinkman, Dr. Kyle S.; Huang, Dr. Kevin

    2012-01-01

    Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO2 from power plant flue gas. Here a modified MECC CO2 capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO2 driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO2 in the flue gas may be captured, and a compressed CO2 product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO2 capture system, and has the potential to meet U.S. DOE s goal that deployment of a CO2 capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

  14. On sorption and swelling of CO2 in clays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Busch, A.; Bertier, P.; Gensterblum, Y.; Rother, G.; Spiers, C. J.; Zhang, M.; Wentinck, H. M.

    2016-03-23

    One well-studied technology is the geological storage of carbon dioxide (CO2), and a number of demonstration projects around the world have proven its feasibility and challenges. Storage conformance and seal integrity are among the most important aspects, as they determine risk of leakage as well as limits for storage capacity and injectivity. By providing evidence for safe storage is critical for improving public acceptance. Most caprocks are composed of clays as dominant mineral type which can typically be illite, kaolinite, chlorite or smectite. A number of recent studies addressed the interaction between CO2 and these different clays and it wasmore » shown that clay minerals adsorb considerable quantities of CO2. For smectite this uptake can lead to volumetric expansion followed by the generation of swelling pressures. On the one hand CO2 adsorption traps CO2, on the other hand swelling pressures can potentially change local stress regimes and in unfavourable situations shear-type failure is assumed to occur. Moreover, for storage in a reservoir having high clay contents the CO2 uptake can add to storage capacity which is widely underestimated so far. Smectite-rich seals in direct contact with a dry CO2 plume at the interface to the reservoir might dehydrate leading to dehydration cracks. Such dehydration cracks can provide pathways for CO2 ingress and further accelerate dewatering and penetration of the seal by supercritical CO2. At the same time, swelling may also lead to the closure of fractures or the reduction of fracture apertures, thereby improving seal integrity. Finally, the goal of this communication is to theoretically evaluate and discuss these scenarios in greater detail in terms of phenomenological mechanisms, but also in terms of potential risks or benefits for carbon storage.« less

  15. Multi-Pollutant Emissions Control: Pilot Plant Study of Technologies for Reducing Hg, SO3, NOx and CO2 Emissions

    SciTech Connect (OSTI)

    Michael L. Fenger; Richard A. Winschel

    2005-08-31

    A slipstream pilot plant was built and operated to investigate technology to adsorb mercury (Hg) onto the existing particulate (i.e., fly ash) by cooling flue gas to 200-240 F with a Ljungstrom-type air heater or with water spray. The mercury on the fly ash was then captured in an electrostatic precipitator (ESP). An alkaline material, magnesium hydroxide (Mg(OH){sub 2}), is injected into flue gas upstream of the air heater to control sulfur trioxide (SO{sub 3}), which prevents acid condensation and corrosion of the air heater and ductwork. The slipstream was taken from a bituminous coal-fired power plant. During this contract, Plant Design and Construction (Task 1), Start Up and Maintenance (Task 2), Baseline Testing (Task 3), Sorbent Testing (Task 4), Parametric Testing (Task 5), Humidification Tests (Task 6), Long-Term Testing (Task 7), and a Corrosion Study (Task 8) were completed. The Mercury Stability Study (Task 9), ESP Report (Task 11), Air Heater Report (Task 12) and Final Report (Task 14) were completed. These aspects of the project, as well as progress on Public Outreach (Task 15), are discussed in detail in this final report. Over 90% mercury removal was demonstrated by cooling the flue gas to 200-210 F at the ESP inlet; baseline conditions with 290 F flue gas gave about 26% removal. Mercury removal is sensitive to flue gas temperature and carbon content of fly ash. At 200-210 F, both elemental and oxidized mercury were effectively captured at the ESP. Mg(OH){sub 2} injection proved effective for removal of SO{sub 3} and eliminated rapid fouling of the air heater. The pilot ESP performed satisfactorily at low temperature conditions. Mercury volatility and leaching tests did not show any stability problems. No significant corrosion was detected at the air heater or on corrosion coupons at the ESP. The results justify larger-scale testing/demonstration of the technology. These conclusions are presented and discussed in two presentations given in July and September of 2005 and are included in Appendices E and F.

  16. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium

  17. co2 capture meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2012 NETL CO2 Capture Technology Meeting July 9 - 12, 2012 Proceedings of the 2012 NETL CO2 Capture Technology Meeting Table of Contents Presentations Monday, July 9 Opening/Overview Post-Combustion Membrane-Based Capture Post-Combustion Sorbent-Based Capture Tuesday, July 10 Post-Combustion Solvent-Based Capture Wednesday, July 11 Oxy-Combustion and Oxygen Production Chemical Looping Process CO2 Compression ARPA-e Capture Projects System Studies and Modeling Thursday, July 12 FutureGen 2.0,

  18. Methanogenic Conversion of CO2 Into CH4

    SciTech Connect (OSTI)

    Stevens, S.H., Ferry, J.G., Schoell, M.

    2012-05-06

    This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

  19. Project Profile: Lifetime Model Development for Supercritical CO2 CSP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems (SuNLaMP) | Department of Energy Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Project Profile: Lifetime Model Development for Supercritical CO2 CSP Systems (SuNLaMP) Funding Program: SuNLaMP SunShot Subprogram: CSP Location: Oak Ridge National Laboratory, Oak Ridge, TN SunShot Award Amount: $2,175,000 This project seeks to develop a predictive lifetime model for materials in supercritical carbon dioxide (sCO2) conditions similar to

  20. Chapter 9 - Energy-related CO2 emission

    Gasoline and Diesel Fuel Update (EIA)

    9 U.S. Energy Information Administration | International Energy Outlook 2016 Chapter 9 Energy-related CO2 emissions Overview Because anthropogenic emissions of carbon dioxide (CO2) result primarily from the combustion of fossil fuels, energy consumption is at the center of the climate change debate. In the International Energy Outlook 2016 (IEO2016) Reference case, world energy- related CO2 emissions 331 increase from 32.3 billion metric tons in 2012 to 35.6 billion metric tons in 2020 and to

  1. 10 MW Supercritical CO2 Turbine Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 MW Supercritical CO2 Turbine Project 10 MW Supercritical CO2 Turbine Project This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. csp_review_meeting_042313_turchi.pdf (1.86 MB) More Documents & Publications 10-Megawatt Supercritical Carbon Dioxide Turbine - FY13 Q2 10-MW Supercritical-CO2 Turbine Degradation Mechanisms and Development of Protective Coatings for TES and HTF Containment Materials

  2. Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Duty Linehaul Platform Project Update Effect of Thermal Aging on NO oxidation and NOx storage in a Fully-Formulated Lean NOx Trap Pt-free, Perovskite-based Lean NOx Trap Catalysts

  3. Co2 Deep Store Ltd | Open Energy Information

    Open Energy Info (EERE)

    Deep Store Ltd Jump to: navigation, search Name: Co2 Deep Store Ltd Place: Scotland, United Kingdom Zip: AB11 7LH Sector: Carbon Product: UK based organization focused on the...

  4. Improving CO2 Efficiency for Recovering Oil in Heterogeneous Reservoirs

    SciTech Connect (OSTI)

    Grigg, Reid B.; Svec, Robert K.

    2003-03-10

    The work strived to improve industry understanding of CO2 flooding mechanisms with the ultimate goal of economically recovering more of the U.S. oil reserves. The principle interests are in the related fields of mobility control and injectivity.

  5. CO2e Capital Limited | Open Energy Information

    Open Energy Info (EERE)

    e Capital Limited Jump to: navigation, search Name: CO2e Capital Limited Place: New York City, New York Zip: 10022 Product: New York based merchant bank focused on reducing global...

  6. Quantum Alloys Offer Prospects for CO2 Management Technologies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with sulfur and gold atoms in a "shell" to form the Au2525 catalyst for CO2 remediation. ... When common household metals, such as copper, gold, or silver, are reduced in size to ...

  7. Researchers Uncover Copper's Potential for Reducing CO2 Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    When used as a part of a promising coal combustion technology known as chemical looping, copper can help economically remove carbon dioxide (CO2) from fossil fuel emissions. In ...

  8. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Implementing CO2 capture in coal-fired power plants could result in almost a doubling of electricity prices for consumers. The researchers examined near-term market-viable ...

  9. Plains CO2 Reduction Partnership PCOR | Open Energy Information

    Open Energy Info (EERE)

    Grand Forks, North Dakota Zip: 58202-9018 Product: North Dakota-based consortium researching CO2 storage options. PCOR is busy with the ECBM in the Unminable Lignite Research...

  10. Electronic Structure, Phonon Dynamical Properties, and CO2 Capture...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electronic Structure, Phonon Dynamical Properties, and CO2 Capture Capability of Na2-xMxZrO3 ( MLi ,K): Density-Functional Calculations and Experimental...

  11. Novel CO2-Thickeners for Improved Mobility Control

    SciTech Connect (OSTI)

    Enick, Dr. Robert M.; Beckman, Dr. Eric J.; Hamilton, Dr. Andrew

    2002-01-15

    The objective of this contract was to design, synthesize, and characterize thickening agents for dense carbon dioxide and to evaluate their solubility and viscosity-enhancing potential in CO2.

  12. Investigations of supercritical CO2 Rankine cycles for geothermal...

    Office of Scientific and Technical Information (OSTI)

    brayton cycle while lower efficiencies can be attained with the transcritical CO2 Rankine cycle. Authors: Sabau, Adrian S 1 ; Yin, Hebi 1 ; Qualls, A L 1 ; McFarlane,...

  13. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from...

    Office of Scientific and Technical Information (OSTI)

    on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. ... without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent ...

  14. Formation and Behavior of Composite CO2 Hydrate Particles in...

    Office of Scientific and Technical Information (OSTI)

    a High-Pressure Water Tunnel Facility Citation Details In-Document Search Title: Formation and Behavior of Composite CO2 Hydrate Particles in a High-Pressure Water Tunnel Facility ...

  15. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from mixtures of H2 and CO (or sometimes CO2) at elevated pressures (50 to 100 atm) and temperatures (450 to 600 K) using catalysts containing copper and zinc oxide. The...

  16. NETL - World CO2 Emissions - Projected Trends Tool | Open Energy...

    Open Energy Info (EERE)

    to look at both total and power sector CO2 emissions from the use of coal, oil, or natural gas, over the period 1990 to 2030. One can use the tool to compare five of the larger...

  17. Bees, Balloons, Pollen Used as Novel CO2 Monitoring Approach

    Broader source: Energy.gov [DOE]

    Researchers at the Office of Fossil Energy's National Energy Technology Laboratory have discovered an innovative way to use bees, pollen, and helium-filled balloons to verify that no carbon dioxide (CO2) leaks from carbon sequestration sites.

  18. DOE Manual Studies 11 Major CO2 Geologic Storage Formations

    Broader source: Energy.gov [DOE]

    A comprehensive study of 11 geologic formations suitable for permanent underground carbon dioxide (CO2) storage is contained in a new manual issued by the U.S. Department of Energy.

  19. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide (ceria) in contact with copper will form metal-oxide interfaces that allow the adsorption and activation of CO2, opening a new reaction pathway for the synthesis of methanol....

  20. Direct s-CO2 Reciever Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This presentation was delivered at the SunShot Concentrating Solar Power ... High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 ...

  1. CO2 Capture and Storage Project, Education and Training Center...

    Broader source: Energy.gov (indexed) [DOE]

    It's the process of capturing and storing or re-using carbon dioxide (CO2) from coal-fired ... from Archer Daniels Midland's ethanol plant in Decatur, transported via a mile-long ...

  2. Post-Combustion CO2 Control | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing of LindeBASF Post-Combustion CO2 Capture Technology at the Abbott Coal-Fired Power Plant University of Illinois FE0026588 Phase 1 - Large pilot-scale (25 MWe) Large ...

  3. 2015 CO2 Capture Technology Meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Wednesday, June 24, 2015 POST-COMBUSTION SOLVENT-BASED CAPTURE An Advanced Catalytic Solvent for Lower Cost Post-Combustion CO2 Capture in a Coal Fired Power Plant Cameron Lippert, ...

  4. Secretary Chu Announces Six Projects to Convert Captured CO2...

    Energy Savers [EERE]

    ... CO2 from an industrial coal-fired source to produce biofuel and other high value co-products. ... Aggregates, Ltd. cement manufacturing plant in San Antonio, Texas. (DOE Share: ...

  5. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluating a new approach to CO2 capture and storage Evaluating a new approach to CO2 capture and storage In a perspective paper published in Greenhouse Gases: Science and Technology, researchers examined a new approach that could potentially overcome many barriers to deployment and jumpstart this process on a commercial scale. September 13, 2015 Map of the contiguous United States shows the location of facilities that produce high-value chemicals/products and the amount of carbon dioxide

  6. R & D Supercritiacl CO2/ Rock Chemicals Interactions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution / precipitation with spatial and temporal flow variations in CO 2 /brine/rock systems Principal Investigator: Martin Saar Department of Earth Sciences University of Minnesota Track Name: Resource Characterization, Modeling, Supercritical CO 2 / Rock Chemical Interactions Total Project Funding: $1,937,523 ($1,550,018 from DOE-GTP) This presentation does not

  7. CO2 Removal using a Synthetic Analogue of Carbonic Anhydrase

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-09-14

    Project attempts to develop a synthetic analogue for carbonic anhydrase and incorporate it in a membrane for separation of CO2 from coal power plant flue gas. Conference poster presents result of first 9 months of project progress including concept, basic system architecture and membrane properties target, results of molecular modeling for analogue - CO2 interaction, and next steps of testing analogue resistance to flue gas contaminants.

  8. Regenerable Sorbent Technique for Capturing CO2 Using Immobilized Amine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorbents - Energy Innovation Portal Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Regenerable Sorbent Technique for Capturing CO2 Using Immobilized Amine Sorbents The BIAS (Basic Immobilized Amine Sorbent) Process National Energy Technology Laboratory Contact NETL About This Technology Technology Marketing Summary This technology allows for optimal CO2 removal capacity for a given absorption and regeneration reactor

  9. Reversible Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Yonker, Clement R.; Rainbolt, James E.; Zheng, Feng

    2010-08-31

    Acid gas scrubbing technology is predominantly aqueous alkanolamine based. Of the acid gases, CO2, H2S and SO2 have been shown to be reversible, however there are serious disadvantages with corrosion and high regeneration costs. The primary scrubbing system composed of monoethanolamine is limited to 30% by weight because of the highly corrosive solution. This gravimetric limitation limits the CO2 volumetric (?108 g/L) and gravimetric capacity (?7 wt%) of the system. Furthermore the scrubbing system has a large energy penalty from pumping and heating the excess water required to dissolve the MEA bicarbonate salt. Considering the high specific heat of water (4 j/g-1K-1), low capacities and the high corrosion we set out to design a fully organic solvent that can chemically bind all acid gases i.e. CO2 as reversible alkylcarbonate ionic liquids or analogues thereof. Having a liquid acid gas carrier improves process economics because there is no need for excess solvent to pump and to heat. We have demonstrated illustrated in Figure 1, that CO2-binding organic liquids (CO2BOLs) have a high CO2 solubility paired with a much lower specific heat (<1.5 J/g-1K-1) than aqueous systems. CO2BOLs are a subsection of a larger class of materials known as Binding Organic Liquids (BOLs). Our BOLs have been shown to reversibly bind and release COS, CS2, and SO2, which we denote COSBOLS, CS2BOLs and SO2BOLs. Our BOLs are highly tunable and can be designed for post or pre-combustion gas capture. The design and testing of the next generation zwitterionic CO2BOLs and SO2BOLs are presented.

  10. Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction Dynamometer Evaluation of Plasma-Catalyst for Diesel NOx Reduction 2003 DEER Conference Presentation: Ford Motor ...

  11. Retrofit Diesel Emissions Control System Providing 50% NOxControl...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference ...

  12. Three-Dimensional Composite Nanostructures for Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Three-Dimensional Composite Nanostructures for Lean NOx Emission Control Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

  13. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2015: Cummins-ORNLFEERC Emissions CRADA: NOx ...

  14. Enhanced High and Low Temperature Performance of NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells Program and ...

  15. The Impact of Lubricant Formulation on the Performance of NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation on the Performance of NOx Adsorber Catalysts The Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts PDF icon 2005deerwhitacre.pdf More ...

  16. Development of Materials Analysis Tools for Studying NOx Adsorber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studying NOx Adsorber Catalysts A cooperative research and development agreement with Cummins Engine Company Development of Materials Analysis Tools for Studying NOx Adsorber ...

  17. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High Temperature Performance of NOx StorageReduction (NSR) ...

  18. Fuel Processor Enabled NOx Adsorber Aftertreatment System for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions Control Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions ...

  19. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines Vehicle Technologies Office Merit Review 2014: Cummins-ORNLFEERC Emissions CRADA: NOx ...

  20. NOx Adsorber Regeneration Phenomena In Heavy Duty Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorber Regeneration Phenomena In Heavy Duty Applications NOx Adsorber Regeneration ... More Documents & Publications Fuel-Borne Reductants for NOx Aftertreatment: Preliminary ...

  1. Parametric Study of NOx Adsorber Regeneration in Transient Cycles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Parametric Study of NOx Adsorber Regeneration in Transient Cycles Parametric Study of NOx Adsorber Regeneration in Transient Cycles 2002 DEER Conference Presentation: Oak Ridge ...

  2. Oxidation State Optimization for Maximum Efficiency of NOx Adsorber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Optimization for Maximum Efficiency of NOx Adsorber Catalysts Oxidation State Optimization for Maximum Efficiency of NOx Adsorber Catalysts Presentation given at the 16th ...

  3. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High Temperature Performance of NOx StorageReduction (NSR) ...

  4. Selective ammonia slip catalyst enabling highly efficient NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    slip catalyst enabling highly efficient NOx removal requirements of the future Selective ammonia slip catalyst enabling highly efficient NOx removal requirements of the future A ...

  5. Development on simultaneous reduction system of NOx and PM from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on simultaneous reduction system of NOx and PM from a diesel engine Development on simultaneous reduction system of NOx and PM from a diesel engine 2003 DEER Converence ...

  6. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and Differences Between ... More Documents & Publications Spatiotemporal Distribution of NOx Storage: a Factor ...

  7. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CLEERS Coordination & Development of Catalyst Process Kinetic Data CumminsORNL-FEERC CRADA: NOx Control ...

  8. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite...

    Office of Scientific and Technical Information (OSTI)

    Book: Understanding NOx SCR Mechanism and Activity on CuChabazite Structures throughout the Catalyst Life Cycle Citation Details In-Document Search Title: Understanding NOx SCR...

  9. Deactivation mechanisms of NOx storage materials arising from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deactivation mechanisms of NOx storage materials arising from thermal aging and sulfur poisoning Presents the reliationship between Pt particle size and NOx storage performance ...

  10. Cummins/ORNL-FEERC CRADA: NOx Control & Measurement Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines CumminsORNL-FEERC CRADA: NOx Control &...

  11. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for ...

  12. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents ...

  13. Passive Catalytic Approach to Low Temperature NOx Emission Abatement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed ...

  14. Cost Analysis of NOx Control Alternatives for Stationary Gas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Analysis of NOx Control Alternatives for Stationary Gas Turbines, November 1999 Cost Analysis of NOx Control Alternatives for Stationary Gas Turbines, November 1999 The use of ...

  15. Transmural Catalysis - High Efficiency Catalyst Systems for NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation ...

  16. Functionality of Commercial NOx Storage-Reduction Catalysts and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps Spatiotemporal Distribution of NOx Storage: a Factor ...

  17. Modeling long-term CO2 storage, sequestration and cycling

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-11-11

    The application of numerical and analytical models to the problem of storage, sequestration and migration of carbon dioxide in geologic formations is discussed. A review of numerical and analytical models that have been applied to CO2 sequestration are presented, as well as a description of frameworks for risk analysis. Application of models to various issues related to carbon sequestration are discussed, including trapping mechanisms, density convection mixing, impurities in the CO2 stream, changes in formation porosity and permeability, the risk of vertical leakage, and the impacts on groundwater resources if leakage does occur. A discussion of the development and application of site-specific models first addresses the estimation of model parameters and the use of natural analogues to inform the development of CO2 sequestration models, and then surveys modeling that has been done at two commercial-scale CO2 sequestration sites, Sleipner and In Salah, along with a pilot-scale injection sites used to study CO2 sequestration in saline aquifers (Frio) and an experimental site designed to test monitoring of CO2 leakage in the vadose zone (ZERT Release Facility).

  18. SANS Investigations of CO2 Adsorption in Microporous Carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bahadur, Jitendra; Melnichenko, Yuri B.; He, Lilin; Contescu, Cristian I.; Gallego, Nidia C.; Carmichael, Justin R.

    2015-08-07

    The high pressure adsorption behavior of CO2 at T = 296 K in microporous carbon was investigated by small-angle neutron scattering (SANS) technique. A strong densification of CO2 in micropores accompanied by non-monotonic adsorption-induced pore deformation was observed. The density of confined CO2 increases rapidly with pressure and reaches the liquid –like density at 20 bar, which corresponds to the relative pressure of P/Psat ~0.3. At P > 20 bar density of confined CO2 increases slowly approaching a plateau at higher pressure. The size of micropores first increases with pressure, reaches a maximum at 20 bar,more » and then decreases with pressure. A complementary SANS experiment conducted on the same microporous carbon saturated with neutron-transparent and non-adsorbing inert gas argon shows no deformation of micropores at pressures up to ~200 bars. This result demonstrates that the observed deformation of micropores in CO2 is an adsorption-induced phenomenon, caused by the solvation pressure - induced strain and strong densification of confined CO2 .« less

  19. Reduce NOx and Improve Energy Efficiency

    SciTech Connect (OSTI)

    2005-05-01

    The U.S. Department of Energy's NOx and Energy Assessment Tool (NxEAT) is available at no charge to help the petroleum refining and chemicals industries develop a cost-effective, plant-wide strategy for NOx reduction and energy efficiency improvements.

  20. UREA INFRASTRUCTURE FOR UREA SCR NOX REDUCTION

    SciTech Connect (OSTI)

    Bunting, Bruce G.

    2000-08-20

    Urea SCR is currently the only proven NOX aftertreatment for diesel engines - high NOX reduction possible - some SCR catalyst systems are robust against fuel sulfur - durability has been demonstrated - many systems in the field - long history in other markets - Major limitations to acceptance - distribution of urea solution to end user - ensuring that urea solution is added to vehicle.

  1. Surface Ocean CO2 Atlas (SOCAT) gridded data products

    SciTech Connect (OSTI)

    Sabine, Christopher; Hankin, S.; Koyuk, H; Bakker, D C E; Pfeil, B; Olsen, A; Metzl, N; Fassbender, A; Manke, A; Malczyk, J; Akl, J; Alin, S R; Bellerby, R G J; Borges, A; Boutin, J; Cai, W-J; Chavez, F P; Chen, A; Cosa, C; Feely, R A; Gonzalez-Davila, M; Goyet, C; Hardman-Mountford, N; Heinze, C; Hoppema, M; Hunt, C W; Hydes, D; Ishii, M; Johannessen, T; Key, R M; Kortzinger, A; Landschutzer, P; Lauvset, S K; Lefevre, N; Lourantou, A; Mintrop, L; Miyazaki, C; Murata, A; Nakadate, A; Nakano, Y; Nakaoka, S; Nojiri, Y; et al.

    2013-01-01

    A well documented, publicly available, global data set for surface ocean carbon dioxide (CO2) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO2, which had been subject to quality control (QC). SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO2 data from the global oceans and coastal seas, spanning four decades (1968 2007). The SOCAT gridded data is the second data product to come from the SOCAT project. Recognizing that some groups may have trouble working with millions of measurements, the SOCAT gridded product was generated to provide a robust regularly spaced fCO2 product with minimal spatial and temporal interpolation which should be easier to work with for many applications. Gridded SOCAT is rich with information that has not been fully explored yet, but also contains biases and limitations that the user needs to recognize and address.

  2. CO2 Sequestration in Unmineable Coal Seams: Potential Environmental Impacts

    SciTech Connect (OSTI)

    Hedges, S.W.; Soong, Yee; McCarthy Jones, J.R.; Harrison, D.K.; Irdi, G.A.; Frommell, E.A.; Dilmore, R.M.; Pique, P.J.; Brown, T.D

    2005-09-01

    An initial investigation into the potential environmental impacts of CO2 sequestration in unmineable coal seams has been conducted, focusing on changes in the produced water during enhanced coalbed methane (ECBM) production using a CO2 injection process (CO2-ECBM). Two coals have been used in this study, the medium volatile bituminous Upper Freeport coal (APCS 1) of the Argonne Premium Coal Samples series, and an as-mined Pittsburgh #8 coal, which is a high volatile bituminous coal. Coal samples were reacted with either synthetic produced water or field collected produced water and gaseous carbon dioxide at 40 ?C and 50 bar to evaluate the potential for mobilizing toxic metals during CO2-ECBM/sequestration. Microscopic and x-ray diffraction analysis of the post-reaction coal samples clearly show evidence of chemical reaction, and chemical analysis of the produced water shows substantial changes in composition. These results suggest that changes to the produced water chemistry and the potential for mobilizing toxic trace elements from coalbeds are important factors to be considered when evaluating deep, unmineable coal seams for CO2 sequestration.

  3. CO2 on the Integrity of Well Cement | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Utilization CO2 Utilization Carbon dioxide (CO2) use and reuse efforts focus on the conversion of CO2 to useable products and fuels that will reduce CO2 emissions in areas where geologic storage may not be an optimal solution. These include: Enhanced Oil/Gas Recovery - Injecting CO2 into depleting oil or gas bearing fields to maximize the amount of CO2 that could be stored as well as maximize hydrocarbon production. View the latest projects selected in FY 2014. CO2 as Feedstock - Use CO2 as

  4. Lean-NOx Catalyst Development for Diesel Engine Applications | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Lean-NOx Catalyst Development for Diesel Engine Applications Lean-NOx Catalyst Development for Diesel Engine Applications 2002 DEER Conference Presentation: Caterpillar Inc. 2002_deer_park.pdf (302.37 KB) More Documents & Publications Lean NOx Catalysis Research and Development Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control

  5. CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Wan -Hui; Himeda, Yuichiro; Muckerman, James T.; Manbeck, Gerald F.; Fujita, Etsuko

    2015-09-03

    In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in severalmore » ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO2 saturated solution using electricity produced by photovoltaics; (iii) CO2 hydrogenation using solar-produced H2; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO2 at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.« less

  6. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  7. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  8. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  9. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  10. ARM - Field Campaign - Boundary Layer CO2 Using CW Lidar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsBoundary Layer CO2 Using CW Lidar Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Boundary Layer CO2 Using CW Lidar 2005.05.21 - 2005.05.24 Lead Scientist : Michael Dobbs Abstract Overflights Underway at ACRF Southern Great Plains Site (M.Dobbs/J.Liljegren) Science collaborators at ITT Industries and the National Aeronautics and Space Administration (NASA) Langley Research Center (LaRC) conducted flights over the Central

  11. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  12. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  13. Watch Our CO2 Drop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Our CO2 Drop Watch Our CO2 Drop January 14, 2016 - 4:55pm Addthis Daniel Wood Daniel Wood Data Visualization and Cartographic Specialist, Office of Public Affairs Learn More About Climate Change If you want to learn more about the importance of reducing our carbon pollution, read our recent report about how climate change threatens our energy infrastructure. Curious about the total amount of carbon we emit into the atmosphere? Compare countries from around the globe using this tool. On Tuesday,

  14. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E; Storey, John Morse; Theiss, Timothy J; Ponnusamy, Senthil; Ferguson, Harley Douglas; Williams, Aaron M; Tassitano, James B

    2007-09-01

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the

  15. Influence of Ceria on the NOx Storage/Reduction Behavior of Lean NOx Trap Catalysts

    SciTech Connect (OSTI)

    Ji, Yaying; Choi, Jae-Soon; Toops, Todd J; Crocker, Dr. Mark; Naseri, Mojghan

    2008-01-01

    The effect of La2O3-stabilized ceria incorporation on the functioning of fully formulated lean NOx trap catalysts was investigated. Monolithic catalysts were prepared, corresponding to loadings of 0, 50 and 100 g CeO2/L, together with a catalyst containing 100 g/L of ceria-zirconia (Ce0.7Zr0.3O2). Loadings of the other main components (Pt, Rh and BaO) were held constant. Catalyst evaluation was performed on a bench flow reactor under simulated diesel exhaust conditions, employing NOx storage/reduction cycles. NOx storage efficiency in the temperature range 150-350 C was observed to increase with ceria loading, resulting in higher NOx conversion levels. At 150 C, high rich phase NOx slip was observed for all of the catalysts, resulting from an imbalance in the rates of nitrate decomposition and NOx reduction. Optimal NOx conversion was obtained in the range 250-350 C for all the catalysts, while at 450 C high rich phase NOx slip from the most highly loaded ceria-containing catalyst resulted in lower NOx conversion than for the ceria-free formulation. N2O was the major NOx reduction product at 150 C over all of the catalysts, although low NOx conversion levels limited the N2O yield. At higher temperatures N2 was the main product of NOx reduction, although NH3 formation was also observed. Selectivity to NH3 decreased with increasing ceria loading, indicating that NH3 is consumed by reaction with stored oxygen in the rear of the catalyst.

  16. Effect of reductive treatments on Pt behavior and NOx storage in lean NOx trap catalysts

    SciTech Connect (OSTI)

    Wang, Xianqin; Kim, Do Heui; Kwak, Ja Hun; Wang, Chong M.; Szanyi, Janos; Peden, Charles HF

    2011-10-01

    Lean NOx trap (LNT) catalysts represent a promising approach to meet increasingly stringent NOx emission regulations on diesel and other lean-burn engines. Pt material properties, including dispersion and particle size, are known to be important factors in determining NOx uptake performance, since Pt provides active sites for NO oxidation to NO2 necessary for storing NOx as nitrates, and for the reduction of nitrates to N2. In this work, the physicochemical properties of Pt in Pt-BaO/Al2O3 LNT catalysts, such as the Pt accessible surface area and particle size, were investigated by using various tools, such as irreversible volumetric H2 chemisorption, high resolution transmission electron microscopy (HRTEM), and X-ray diffraction (XRD), following successive reductive treatments at elevated temperatures. NOx uptake activities were also measured to establish a relationship between the properties of Pt and NOx storage following identical high-temperature reductive treatments. We find that the reductive treatments of Pt-BaO/Al2O3 lean NOx trap catalysts at temperatures up to 500 ÂşC promote a significant increase in NOx uptake explained, in part, by an induced close interaction between Pt and BaO phases in the catalyst, thus enabling facilitation of the NOx storage process.

  17. Retrofit Diesel Emissions Control System Providing 50% NOxControl |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Diesel Emissions Control System Providing 50% NOxControl Retrofit Diesel Emissions Control System Providing 50% NOxControl 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_yee.pdf (660.21 KB) More Documents & Publications Transient Dynamometer Testing of a Single-Leg NOX Adsorber Combined with a Fuel Processor for Enhanced NOx Control Fuel Processor Enabled NOx Adsorber Aftertreatment System for Diesel Engine Emissions

  18. Parametric Study of NOx Adsorber Regeneration in Transient Cycles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Parametric Study of NOx Adsorber Regeneration in Transient Cycles Parametric Study of NOx Adsorber Regeneration in Transient Cycles 2002 DEER Conference Presentation: Oak Ridge National Laboratory 2002_deer_west.pdf (1.07 MB) More Documents & Publications Combining Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient NOx Control for Diesels Measurement and Characterization of NOx Adsorber Regeneration and Desulfation Measurement

  19. Six-Week Time Series Of Eddy Covariance CO2 Flux At Mammoth Mountain...

    Open Energy Info (EERE)

    high, spatially heterogeneous CO2 emission rates. EC CO2 fluxes ranged from 218 to 3500 g m- 2 d- 1 (mean 1346 g m- 2 d- 1). Using footprint modeling, EC CO2 fluxes were...

  20. Single-well Low Temperature CO2- based Engineered Geothemal System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Single-well Low Temperature CO2- based Engineered Geothemal System Single-well Low Temperature CO2- based Engineered Geothemal System Single-well Low Temperature CO2- based ...

  1. Durability of NOx Absorbers | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Cleaner Vehicles, Cleaner Fuel & Cleaner Air APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update LNT + SCR Aftertreatment for Medium-Heavy ...

  2. Ammonia-Free NOx Control System

    SciTech Connect (OSTI)

    Zhen Fan; Song Wu; Richard G. Herman

    2004-06-30

    Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the April 1 to June 30, 2004 time period.

  3. NOX: An Object-Oriented Nonlinear Solver

    Energy Science and Technology Software Center (OSTI)

    2002-11-15

    NOX is a C++ object-oriented library for the solving nonlinear equations. It can be used with an linear algebra package and includes interfaces to Epetra and PETSc.

  4. Electrochemical NOx Sensors for Monitoring Diesel Emissions

    Broader source: Energy.gov [DOE]

    A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs

  5. Near-Surface Co2 Monitoring And Analysis To Detect Hidden Geothermal...

    Open Energy Info (EERE)

    at dispersing CO2 seepage. In natural ecological systems in the absence of geothermal gas emissions, near-surface CO2 fluxes and concentrations are predominantly controlled by...

  6. Fundamental study of CO2-H2O-mineral interactions for carbon...

    Office of Scientific and Technical Information (OSTI)

    E.; Wang, Yifeng; Matteo, Edward N.; Meserole, Stephen P.; Tallant, David Robert In the supercritical CO2-water-mineral systems relevant to subsurface CO2 sequestration,...

  7. Impact of mesophyll diffusion on estimated global land CO2 fertilizati...

    Office of Scientific and Technical Information (OSTI)

    Impact of mesophyll diffusion on estimated global land CO2 fertilization Citation Details In-Document Search Title: Impact of mesophyll diffusion on estimated global land CO2 ...

  8. Is CO2 an Indoor Pollutant? Direct Effects of Low to Moderate...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Is CO2 an Indoor Pollutant? Direct Effects of Low to Moderate CO2 ... Sponsoring Org: USDOE Office of Science (SC) Country of Publication: United States ...

  9. Fundamental study of CO2-H2O-mineral interactions for carbon...

    Office of Scientific and Technical Information (OSTI)

    In the supercritical CO2-water-mineral systems relevant to subsurface CO2 sequestration, ... Experimental and theoretical studies have shown that water films will form on mineral ...

  10. CO2-selective, Hybrid Membranes by Silation of Alumina

    SciTech Connect (OSTI)

    Luebke, D.R.; Pennline, H.W.

    2007-09-01

    Hybrid membranes are feasible candidates for the separation of CO2 from gas produced in coal-based power generation since they have the potential to combine the high selectivity of polymer membranes and the high permeability of inorganic membranes. An interesting method for producing hybrid membranes is the silation of an inorganic membrane. In this method, trichloro- or alkoxy-silanes interact with hydroxyl groups on the surface of γ-AlO3 or TiO2, binding organic groups to that surface. By varying the length of these organic groups on the organosilane, it should be possible to tailor the effective pore size of the membrane. Similarly, the addition of “CO2-phillic” groups to the silating agent allows for the careful control of surface affinity and the enhancement of surface diffusion mechanisms. This method of producing hybrid membranes selective to CO2 was first attempted by Hyun [1] who silated TiO2 with phenyltriethoxysilane. Later, Way [2] silated γ-AlO3 with octadecyltrichlorosilane. Both researchers were successful in producing membranes with improved selectivity toward CO2, but permeability was not maintained at a commercially applicable level. XPS data indicated that the silating agent did not penetrate into the membrane pores and separation actually occurred in a thin “polymer-like” surface layer. The present study attempts to overcome the mass transfer problems associated with this technique by producing the desired monolayer coverage of silane, and thus develop a highly-permeable CO2-selective hybrid membrane.