National Library of Energy BETA

Sample records for hoteliers strike gold

  1. Hoteliers Strike Gold with Geothermal Alaskan Resort | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lowest operating temperature geothermal power plants in the world, operating with 165 F water. The energy savings has been remarkable. Bernie estimates he saves anywhere from...

  2. Hoteliers Strike Gold with Geothermal Alaskan Resort | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to TappingWORKof Energy BeforeSavingss g n i r p S r e p

  3. Radial arm strike rail

    DOE Patents [OSTI]

    McKeown, Mark H. (Golden, CO); Beason, Steven C. (Lakewood, CO)

    1991-01-01

    The radial arm strike rail assembly is a system for measurement of bearings, directions, and stereophotography for geologic mapping, particularly where magnetic compasses are not appropriate. The radial arm, pivoting around a shaft axis, provides a reference direction determination for geologic mapping and bearing or direction determination. The centerable and levelable pedestal provide a base for the radial arm strike rail and the telescoping camera pedestal. The telescoping feature of the radial arm strike rail allows positioning the end of the rail for strike direction or bearing measurement with a goniometer.

  4. earthquake warning earthquake strikes

    E-Print Network [OSTI]

    Emergency earthquake warning When an earthquake strikes Immediately after the earthquake Several-8550 For Students LargeLaargege Earthquake #12;According to tables explaining the JMA (Japan Meteorological Agency situation Wooden houses Ground situation Lifelines Slopes, etc. situation In preparation for an earthquake

  5. earthquake warning earthquake strikes

    E-Print Network [OSTI]

    Emergency earthquake warning When an earthquake strikes Immediately after the earthquake Several, Kanagawa 226-8503 For Students LargeLaargege Earthquake #12;According to tables explaining the JMA (Japan for an earthquake with a seismic intensity of 5-Lower or greater, this manual summarizes what you should do

  6. Lightning Strikes on Airborne Grounded Systems 

    E-Print Network [OSTI]

    Malinga, Gilbert Aporu

    2014-10-13

    The modeling of lightning strike behavior and estimation of the subsequent electrical discharge is of great practical importance. In this study a complete two-dimensional physics based analytical formulation is presented ...

  7. Hidden Gold 

    E-Print Network [OSTI]

    Abernathy, L. L.

    1988-01-01

    required. The results were surprising. HIDDEN GOLD The day had been hot and the haze kept us from seeing the success of the other barge. The drumming sound of the dredge pumps had a mono tonous tone as Joe and I watched massive quantities of ssnd... and the jungle beyond. We had been dredging in this delta for about four years since Ed, the company president, had discovered a nugget near the bank. I wondered why we had never followed the river upstream to find the source of this gold? The thought...

  8. Gold Nanoantennas

    SciTech Connect (OSTI)

    2012-01-01

    An array of gold nanoantennas laced into an artificial membrane enhances the fluorescence intensity of three different molecules when they pass through plasmonic hot spots in the array. Watch for the blue, green and red flashes. The photobleaching at the end of each fluorescence event (white flashes) is indicative of single molecule observations.

  9. Beyond Reported History: Strikes That Never Happened

    E-Print Network [OSTI]

    Tilburg, Universiteit van

    and information extraction tech- niques may contribute by partly automating and speeding up the primary source history. Pri- mary sources of historical information, such as letters, news- papers and brochures historical sources, namely a manually de- veloped strikes database [15] and the respective primary sources

  10. Lightning Strikes and Attribution of Climatic Change

    E-Print Network [OSTI]

    Webster, Anthony J

    2015-01-01

    Using lightning strikes as an example, two possible schemes are discussed for the attribution of changes in event frequency to climate change, and estimating the cost associated with them. The schemes determine the fraction of events that should be attributed to climatic change, and the fraction that should be attributed to natural chance. They both allow for the expected increase in claims and the fluctuations about this expected value. Importantly, the attribution fraction proposed in the second of these schemes is necessarily different to that found in epidemiological studies. This ensures that the statistically expected fraction of attributed claims is correctly equal to the expected increase in claims. The analysis of lightning data highlights two particular difficulties with data-driven, as opposed to modeled, attribution studies. The first is the possibility of unknown "confounding" variables that can influence the strike frequency. This is partly accounted for here by considering the influence of temp...

  11. The Causes of Strikes in Argentina, 1984-1991

    E-Print Network [OSTI]

    McGuire, James W.

    1992-01-01

    The Causes of Strikes in Argentina, 1984-1991 James W.here is that these non- economic causes make themselves feltstrikes have mainly economic causes whereas big strikes have

  12. Noah Golding | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noah Golding About Us Noah Golding - Communications Specialist, Wind and Water Power Technologies Office Most Recent Winning with Wind: Electric Co-ops Providing Clean Energy to...

  13. Going green earns Laboratory gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Going green earns Laboratory gold Going green earns Laboratory gold The Laboratory's newest facility is its first to achieve both the Leadership in Energy and Environmental Design...

  14. Texas Gold Rush 

    E-Print Network [OSTI]

    Wythe, Kathy

    2006-01-01

    stream_source_info Texas Gold Rush.pdf.txt stream_content_type text/plain stream_size 10484 Content-Encoding ISO-8859-1 stream_name Texas Gold Rush.pdf.txt Content-Type text/plain; charset=ISO-8859-1 tx H2O | pg. 6... Texas Gold Rush Story by Kathy Wythe A free-floating microscopic alga is increasingly appearing in some Texas lakes and rivers, releasing its deadly toxins and wiping out millions of fish. Texas scientists have taken on the assignment...

  15. Intercepting Tokens: The Empire Strikes Back in the Clone Wars

    E-Print Network [OSTI]

    Intercepting Tokens: The Empire Strikes Back in the Clone Wars ¨Ozg¨ur Dagdelen Marc Fischlin on the weak model of one-time memory tokens. Our protocol only requires four moves, very basic opera- tions-proof hardware devices to relax assumptions dates back to the 80's [62, 50]. Indeed, security tokens

  16. Derivatized gold clusters and antibody-gold cluster conjugates

    DOE Patents [OSTI]

    Hainfeld, J.F.; Furuya, F.R.

    1994-11-01

    Antibody- or antibody fragment-gold cluster conjugates are shown wherein the conjugate size can be as small as 5.0 nm. Methods and reagents are disclosed in which antibodies, Fab' or F(ab')[sub 2] fragments are covalently bound to a stable cluster of gold atoms. The gold clusters may contain 6, 8, 9, 11, 13, 55 or 67 gold atoms in their inner core. The clusters may also contain radioactive gold. The antibody-cluster conjugates are useful in electron microscopy applications as well as in clinical applications that include imaging, diagnosis and therapy. 7 figs.

  17. Gold deposits in the late Archaean Nzega-Igunga greenstone belt, central plateau of tanzania

    SciTech Connect (OSTI)

    Feiss, P.G.; Siyomana, S.

    1985-01-01

    2.2 m oz of gold have been produced, since 1935, from late Archaean (2480-2740 Ma) greenstone belts of the Central Plateau, Tanzania. North and east of Nzega (4/sup 0/12'S, 3/sup 0/11'E), 18% of the exposed basement, mainly Dodoman schists and granites, consists of metavolcanics and metasediments of the Nyanzian and Kavirondian Series. Four styles of mineralization are observed. 1. Stratabound quartz-gold veins with minor sulfides. Host rocks are quartz porphyry, banded iron formation (BIF), magnetite quartzite, and dense, cherty jasperite at the Sekenke and Canuck mines. The Canuck veins are on strike from BIF's in quartz-eye porphyry of the Igusule Hills. 2. Stratabound, disseminated gold in coarse-grained, crowded feldspar porphyry with lithic fragments and minor pyrite. At Bulangamilwa, the porphyry is conformable with Nyanzian-aged submarine (.) greenstone, volcanic sediment, felsic volcanics, and sericite phyllite. The deposits are on strike with BIF of the Wella Hills, which contains massive sulfide with up to 15% Pb+Zn. 3. Disseminated gold in quartz-albite metasomes in Nyanzian greenstones. At Kirondatal, alteration is associated with alaskites and feldspar porphyry dikes traceable several hundred meters into post-Dodoman diorite porphyry. Gold is with pyrite, arsenopyrite, pyrrhotite, minor chalcopyrite, and sphalerite as well as tourmalinite and silica-cemented breccias. 4. Basal Kavirondian placers in metaconglomerates containing cobbles and boulders of Dodoman and Nyanzian rocks several hundred meters up-section from the stratabound, disseminated mineralization at Bulangamilwa.

  18. The New Gold Standard: Environmental Management Introduces the...

    Energy Savers [EERE]

    The New Gold Standard: Environmental Management Introduces the First LEED Gold Industrial Facility The New Gold Standard: Environmental Management Introduces the First LEED Gold...

  19. Los Alamos technology strikes a chord with algal biofuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCentermillion to local UnitedtoHOPENewTechnology strikes chord

  20. Surface-stabilized gold nanocatalysts

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN) [Knoxville, TN; Yan, Wenfu (Oak Ridge, TN) [Oak Ridge, TN

    2009-12-08

    A surface-stabilized gold nanocatalyst includes a solid support having stabilizing surfaces for supporting gold nanoparticles, and a plurality of gold nanoparticles having an average particle size of less than 8 nm disposed on the stabilizing surfaces. The surface-stabilized gold nanocatalyst provides enhanced stability, such as at high temperature under oxygen containing environments. In one embodiment, the solid support is a multi-layer support comprising at least a first layer having a second layer providing the stabilizing surfaces disposed thereon, the first and second layer being chemically distinct.

  1. Antibody-gold cluster conjugates

    DOE Patents [OSTI]

    Hainfeld, J.F.

    1988-06-28

    Antibody- or antibody fragment-gold cluster conjugates are shown wherein the conjugate size can be about 5.0 nm. Methods and reagents are disclosed in which antibodies or Fab' fragments thereof are covalently bound to a stable cluster of gold atoms. 2 figs.

  2. Assessment of performing an MST strike in Tank 21H

    SciTech Connect (OSTI)

    Poirier, Michael R.

    2014-09-29

    Previous Savannah River National Laboratory (SRNL) tank mixing studies performed for the Small Column Ion Exchange (SCIX) project have shown that 3 Submersible Mixer Pumps (SMPs) installed in Tank 41 are sufficient to support actinide removal by MST sorption as well as subsequent resuspension and removal of settled solids. Savannah River Remediation (SRR) is pursuing MST addition into Tank 21 as part of the Large Tank Strike (LTS) project. The preliminary scope for LTS involves the use of three standard slurry pumps (installed in N, SE, and SW risers) in a Type IV tank. Due to the differences in tank size, internal interferences, and pump design, a separate mixing evaluation is required to determine if the proposed configuration will allow for MST suspension and strontium and actinide sorption. The author performed the analysis by reviewing drawings for Tank 21 [W231023] and determining the required cleaning radius or zone of influence for the pumps. This requirement was compared with previous pilot-scale MST suspension data collected for SCIX that determined the cleaning radius, or zone of influence, as a function of pump operating parameters. The author also reviewed a previous Tank 50 mixing analysis that examined the ability of standard slurry pumps to suspend sludge particles. Based on a review of the pilot-scale SCIX mixing tests and Tank 50 pump operating experience, three standard slurry pumps should be able to suspend sludge and MST to effectively sorb strontium and actinides onto the MST. Using the SCIX data requires an assumption about the impact of cooling coils on slurry pump mixing. The basis for this assumption is described in this report. Using the Tank 50 operating experience shows three standard slurry pumps should be able to suspend solids if the shear strength of the settled solids is less than 160 Pa. Because Tank 21 does not contain cooling coils, the shear strength could be larger.

  3. GOLD: The Genomes Online Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kyrpides, Nikos; Liolios, Dinos; Chen, Amy; Tavernarakis, Nektarios; Hugenholtz, Philip; Markowitz, Victor; Bernal, Alex

    Since its inception in 1997, GOLD has continuously monitored genome sequencing projects worldwide and has provided the community with a unique centralized resource that integrates diverse information related to Archaea, Bacteria, Eukaryotic and more recently Metagenomic sequencing projects. As of September 2007, GOLD recorded 639 completed genome projects. These projects have their complete sequence deposited into the public archival sequence databases such as GenBank EMBL,and DDBJ. From the total of 639 complete and published genome projects as of 9/2007, 527 were bacterial, 47 were archaeal and 65 were eukaryotic. In addition to the complete projects, there were 2158 ongoing sequencing projects. 1328 of those were bacterial, 59 archaeal and 771 eukaryotic projects. Two types of metadata are provided by GOLD: (i) project metadata and (ii) organism/environment metadata. GOLD CARD pages for every project are available from the link of every GOLD_STAMP ID. The information in every one of these pages is organized into three tables: (a) Organism information, (b) Genome project information and (c) External links. [The Genomes On Line Database (GOLD) in 2007: Status of genomic and metagenomic projects and their associated metadata, Konstantinos Liolios, Konstantinos Mavromatis, Nektarios Tavernarakis and Nikos C. Kyrpides, Nucleic Acids Research Advance Access published online on November 2, 2007, Nucleic Acids Research, doi:10.1093/nar/gkm884]

    The basic tables in the GOLD database that can be browsed or searched include the following information:

    • Gold Stamp ID
    • Organism name
    • Domain
    • Links to information sources
    • Size and link to a map, when available
    • Chromosome number, Plas number, and GC content
    • A link for downloading the actual genome data
    • Institution that did the sequencing
    • Funding source
    • Database where information resides
    • Publication status and information

    (Specialized Interface)

  4. Catalytic Role of Gold in Gold-Based Catalysts: A Density Functional Theory Study on the CO Oxidation on Gold

    E-Print Network [OSTI]

    Alavi, Ali

    Catalytic Role of Gold in Gold-Based Catalysts: A Density Functional Theory Study on the CO Oxidation on Gold Zhi-Pan Liu and P. Hu* Contribution from the School of Chemistry, The Queen's Uni years, being regarded as a new generation of catalysts due to their unusually high catalytic performance

  5. Fabrication and optical characterization of nano-hole arrays in gold and gold/palladium films on glass

    E-Print Network [OSTI]

    van Vliet, Lucas J.

    Fabrication and optical characterization of nano-hole arrays in gold and gold/palladium films in a 200-nm thick layer of gold (Au), palladium (Pd), and gold/palladium (Au/Pd ¼ 60/40) alloy on glass

  6. Control of blood clotting using gold nanorods

    E-Print Network [OSTI]

    De Puig Guixé, Helena

    2013-01-01

    We have developed a method to externally control blood clotting using gold nanoparticles. Gold nanorods (NRs) have unique size and shape-dependent optical properties that can be used for externally controlled release of ...

  7. A CARBON METER FOR OPTIMISATION OF GOLD

    E-Print Network [OSTI]

    Mucina, Ladislav

    A CARBON METER FOR OPTIMISATION OF GOLD EXTRACTION IP COMMERCIALISATION Tom Hammond Business of technology The Carbon-in-Pulp (CIP) process is used as the primary gold extraction method in gold mines around the world. An observation that activated carbon added to the circuit is not well monitored

  8. Opening the closed shop: the Galveston Longshoremen's Strike, 1920-1921 

    E-Print Network [OSTI]

    Abel, Joseph Anthony

    2005-02-17

    Beginning in March of 1920, the Galveston coastwise longshoremen?s strike against the Morgan-Southern Pacific and Mallory steamship lines was a pivotal moment in the history of organized labor in Texas. Local and statewide business interests proved...

  9. The structure and evolution of small-displacement strike-slip faults in porous sandstone 

    E-Print Network [OSTI]

    Schafer, Kirk Wyatt

    2002-01-01

    The early-evolution of fault structure is inferred from analysis of detailed maps of portions of strike-slip faults with uniform displacements ranging from mm to decimeter in porous quartzose sandstone. Emphasis is on ...

  10. Study Guide for Gilbane Gold

    E-Print Network [OSTI]

    Chen, Xinzhong

    Gold" is the name given to dried sludge from the Gilbane wastewater treatment plant. It is sold the amount of water, thus still meeting the existing city standards. The result, however, is that Gilbane to changing the test standards because that would require additional investment in wastewater treatment

  11. Biomolecular Assembly of Gold Nanocrystals

    SciTech Connect (OSTI)

    Micheel, Christine Marya

    2005-05-20

    Over the past ten years, methods have been developed to construct discrete nanostructures using nanocrystals and biomolecules. While these frequently consist of gold nanocrystals and DNA, semiconductor nanocrystals as well as antibodies and enzymes have also been used. One example of discrete nanostructures is dimers of gold nanocrystals linked together with complementary DNA. This type of nanostructure is also known as a nanocrystal molecule. Discrete nanostructures of this kind have a number of potential applications, from highly parallel self-assembly of electronics components and rapid read-out of DNA computations to biological imaging and a variety of bioassays. My research focused in three main areas. The first area, the refinement of electrophoresis as a purification and characterization method, included application of agarose gel electrophoresis to the purification of discrete gold nanocrystal/DNA conjugates and nanocrystal molecules, as well as development of a more detailed understanding of the hydrodynamic behavior of these materials in gels. The second area, the development of methods for quantitative analysis of transmission electron microscope data, used computer programs written to find pair correlations as well as higher order correlations. With these programs, it is possible to reliably locate and measure nanocrystal molecules in TEM images. The final area of research explored the use of DNA ligase in the formation of nanocrystal molecules. Synthesis of dimers of gold particles linked with a single strand of DNA possible through the use of DNA ligase opens the possibility for amplification of nanostructures in a manner similar to polymerase chain reaction. These three areas are discussed in the context of the work in the Alivisatos group, as well as the field as a whole.

  12. Do warning displays predict striking behavior in a viperid snake, the cottonmouth (Agkistrodon piscivorus)?

    SciTech Connect (OSTI)

    Glaudas, X. and C.T. Winne

    2007-01-01

    Warning displays are defined as signals designed to intimidate predators or indicate a proclivity to fight. However, support for the idea that warning behaviors signal an intent to fight is largely based on anecdotes and isolated observations, and a complete understanding of antipredator behavior will only be achieved if specific hypotheses are experimentally tested. Herein, we tested in a North American viperid snake, the cottonmouth (Agkistrodon piscivorus), the hypothesis that warning displays serve as a reliable signal to potential predators that a snake will strike. The cottonmouth exhibits two stereotypical warning displays during predator confrontation, i.e., mouth gaping and tail vibrations, making it an ideal study organism to experimentally test the relationship between warning displays and defensive striking. To test this idea, we recorded the sequence of defensive behavior--gaping, tail vibrating, and striking--of cottonmouths towards a standardized predatory stimulus in the laboratory. As predicted, snakes that gaped during the trials were subsequently more likely to strike than snakes that did not. In contrast, striking behavior was independent of the occurrence of tail vibrations. Our results suggest that gaping behavior--but not tail-vibrating behavior--may provide an honest signal to would-be predators.

  13. GOLD--2001 33.1 By Earle B. Amey

    E-Print Network [OSTI]

    GOLD--2001 33.1 GOLD By Earle B. Amey Domestic survey data and tables were prepared by Mahbood, international data coordinator. Domestic gold mine production in 2001 fell to its lowest level since 1996.S. gold mine production was about $2.9 billion in 2001. Domestic gold exploration activity dropped

  14. Magneto-optical manipulation of surface plasmons in gold/ferromagnetic/gold multilayer films

    E-Print Network [OSTI]

    Temnov, Vasily V.

    Modulation of the surface plasmon wave vector in composite gold/cobalt/gold multilayer films due to periodic magnetization switching in cobalt is observed with a tilted slit-groove microinterferometer.

  15. Electromigration of Electroplated Gold Interconnects Steve Kilgore, *

    E-Print Network [OSTI]

    Schroder, Dieter K.

    Electromigration of Electroplated Gold Interconnects Steve Kilgore, * Craig Gaw, * Haldane Henry Tempe, AZ 85287, U.S.A. ABSTRACT Electromigration tests were performed on passivated electroplated Au

  16. Gold catalyst Styrene Benzaldehyde Styrene oxide Acetophenone

    E-Print Network [OSTI]

    Rouyer, Francois

    O O O + + O2 Gold catalyst Styrene Benzaldehyde Styrene oxide Acetophenone studies. However styrene. The reaction chiefly yielded benzaldehyde, with smaller amounts of styrene oxide and acetophenone

  17. BPA Headquarters Now “Gold Certified” for Sustainability

    Broader source: Energy.gov [DOE]

    BPA recently became the first federal agency in Portland, Oregon, to achieve the city's Sustainability at Work Gold Certification for sustainability efforts at its headquarters building.

  18. An overview of global gold market and gold price forecasting Shahriar Shafiee a,n

    E-Print Network [OSTI]

    Boisvert, Jeff

    on monthly historical data of nominal gold price. & 2010 Elsevier Ltd. All rights reserved. Introduction classification: E31 O13 Q32 Keywords: Historical gold market Forecasting mineral prices Long-term trend reverting and the price of gold is relatively higher than its historical trend. For mining companies to mitigate risk

  19. Water and Gold: A Promising Mix for Future Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water and Gold: A Promising Mix for Future Batteries Water and Gold: A Promising Mix for Future Batteries Berkeley Lab Study Reveals Molecular Structure of Water at Gold Electrodes...

  20. Structure Revealing H/D Exchange with Co-Adsorbed Hydrogen and Water on Gold

    E-Print Network [OSTI]

    Henkelman, Graeme

    oxide-gold interface can readily dissociate hydrogen,10 and hydrogen spillover onto the gold results

  1. The Gold-Exchange Standard and the Great Depression

    E-Print Network [OSTI]

    Eichengreen, Barry

    1988-01-01

    The first posits a maldistribution of gold, blaming Franceto be unsatisfactory; a maldistribution to which is to beThe first posits a maldistribution of gold, blaming France

  2. PROFESSIONS DE FOI, CTPU FEVRIER 2010 Christopher Newfield: You think the strikes lost?

    E-Print Network [OSTI]

    Harris, Michael - Institut de Mathématiques de Jussieu, Université Paris 7

    PROFESSIONS DE FOI, CTPU FEVRIER 2010 Christopher Newfield: You think the strikes lost? Isabelle, as well as the professions de foi which explain what each list stands for. As far as I can tell that in practice one votes not for a collection of individual candidates but rather for a profession de foi. I

  3. Driving Low-Power Wearable Systems with an Adaptively-Controlled Foot-Strike Scavenging Platform

    E-Print Network [OSTI]

    Potkonjak, Miodrag

    with an ambient source of energy in mobile contexts. The hu- man body offers a myriad of sources to parasitically and mass of transducer to produce a given amount of energy. While competing tech- nologies transduce as a means to scavenge energy from foot-strikes and power wearable systems. While they exhibit large energy

  4. Striking a Balance Between Energy and the Environment in the Columbia River Basin Sockeye surprise

    E-Print Network [OSTI]

    Striking a Balance Between Energy and the Environment in the Columbia River Basin Sockeye surprise G & T Chair, Bill Drummond 5 Future Energy Savings Should Come From Innovations 8 Award Honors, final statistics had not been compiled but it appeared 90 percent of the sock- eye were Okanogan fish

  5. FORECAST OF ATLANTIC SEASONAL HURRICANE ACTIVITY AND LANDFALL STRIKE PROBABILITY FOR 2014

    E-Print Network [OSTI]

    Connors, Daniel A.

    1 FORECAST OF ATLANTIC SEASONAL HURRICANE ACTIVITY AND LANDFALL STRIKE PROBABILITY FOR 2014 We are higher than normal, and vertical wind shear throughout the Atlantic basin has been much stronger than-period average values. (as of 31 July 2014) By Philip J. Klotzbach1 and William M. Gray2 This forecast as well

  6. News & Blogs U.S. Lightning Strikes May Increase 50% Due to Global Warming

    E-Print Network [OSTI]

    Romps, David M.

    News & Blogs U.S. Lightning Strikes May Increase 50% Due to Global Warming By: Dr. Jeff Masters (/blog/JeffMasters/show.html) , 4:04 PM GMT on November 14, 2014 A warmer world will have much more, (http://www.wunderground.com/blog/JeffMasters/comment.html?entrynum=2320) the Whitewater- Baldy Complex

  7. The lethal fighting of larvae in many parasitoid species is a striking example of

    E-Print Network [OSTI]

    Mayhew, Peter

    The lethal fighting of larvae in many parasitoid species is a striking example of sibling rivalry. Theory has suggested that such fighting, and subsequent solitary development, might be irreversible larvae, with the retention of fighting behaviour, is one way to escape the trap of solitary development

  8. Simulating Hurricane Tracks and Strike Probabilities Chris Phillips and Stephen McFarling

    E-Print Network [OSTI]

    Rowell, Eric C.

    Simulating Hurricane Tracks and Strike Probabilities Chris Phillips and Stephen McFarling 29 July of hurricanes, and the resulting economic consequences for oil rigs located in the Gulf of Mexico. Using movement of hurricanes) and the states that represent the system (the position of the hurricane in degrees

  9. Gold-nickel-titanium brazing alloy

    DOE Patents [OSTI]

    Mizuhara, Howard

    1995-01-03

    A brazing alloy in accordance with this invention has the following composition, by weight: 91 to 99 gold, 0.5 to 7% nickel; 0.10 to 2% titanium. Alternatively, with palladium present, the composition is as follows, by weight: 83 to 96% gold; 3 to 10% palladium; 0.5 to 5% nickel; 0.10 to 2% titanium.

  10. Gold-nickel-titanium brazing alloy

    DOE Patents [OSTI]

    Mizuhara, Howard (Hillsborough, CA)

    1990-07-03

    A brazing alloy in accordance with this invention has the following composition, by weight: 91 to 99% gold, 0.5 to 7% nickel; 0.10 to 2% titanium. Alternatively, with palladium present, the composition is as follows, by weight: 83 to 96% gold; 3 to 10% palladium; 0.5 to 5% nickel; 0.10 to 2% titanium.

  11. Coal-gold agglomeration: an alternative separation process in gold recovery

    SciTech Connect (OSTI)

    Akcil, A.; Wu, X.Q.; Aksay, E.K. [Suleyman Demirel University, Isparta (Turkey). Dept. of Mining Engineering

    2009-07-01

    Considering the increasing environmental concerns and the potential for small gold deposits to be exploited in the future, the uses of environmentally friendly processes are essential. Recent developments point to the potential for greatly increased plant performance through a separation process that combines the cyanide and flotation processes. In addition, this kind of alternative treatment processes to the traditional gold recovery processes may reduce the environmental risks of present small-scale gold mining. Gold recovery processes that applied to different types of gold bearing ore deposits show that the type of deposits plays an important role for the selection of mineral processing technologies in the production of gold and other precious metals. In the last 25 years, different alternative processes have been investigated on gold deposits located in areas where environmental issues are a great concern. In 1988, gold particles were first recovered by successful pilot trial of coal-gold agglomeration (CGA) process in Australia. The current paper reviews the importance of CGA in the production of gold ore and identifies areas for further development work.

  12. Gel Electrophoresis of Gold-DNA Nanoconjugates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pellegrino, T.; Sperling, R. A.; Alivisatos, A. P.; Parak, W. J.

    2007-01-01

    Gold-DNA conjugates were investigated in detail by a comprehensive gel electrophoresis study based on 1200 gels. A controlled number of single-stranded DNA of different length was attached specifically via thiol-Au bonds to phosphine-stabilized colloidal gold nanoparticles. Alternatively, the surface of the gold particles was saturated with single stranded DNA of different length either specifically via thiol-Au bonds or by nonspecific adsorption. From the experimentally determined electrophoretic mobilities, estimates for the effective diameters of the gold-DNA conjugates were derived by applying two different data treatment approaches. The first method is based on making a calibration curve for the relation between effectivemore »diameters and mobilities with gold nanoparticles of known diameter. The second method is based on Ferguson analysis which uses gold nanoparticles of known diameter as reference database. Our study shows that effective diameters derived from gel electrophoresis measurements are affected with a high error bar as the determined values strongly depend on the method of evaluation, though relative changes in size upon binding of molecules can be detected with high precision. Furthermore, in this study, the specific attachment of DNA via gold-thiol bonds to Au nanoparticles is compared to nonspecific adsorption of DNA. Also, the maximum number of DNA molecules that can be bound per particle was determined.« less

  13. HumanWildlife Interactions 8(2):251260, Fall 2014 Wildlife strikes with U.S. military rotary-

    E-Print Network [OSTI]

    during deployments in the Middle East (e.g., Iraq), whereas, strikes to U.S. Air Force aircraft occurred, Iraq, military, rotary-wing aircraft, wildlife strikes During the last 2 decades, a great deal of armed conflict, and political upheaval has occurredintheMiddleEast(e.g.,Iraq)andsouth- central Asia (e

  14. Colloidal-gold electrosensor measuring device

    DOE Patents [OSTI]

    Wegner, Steven (Chapel Hill, NC); Harpold, Michael A. (Durham, NC); McCaffrey, Terence M. (Durham, NC); Morris, Susan E. (Chapel Hill, NC); Wojciechowski, Marek (Cary, NC); Zhao, Junguo (Chapel Hill, NC); Henkens, Robert W. (Durham, NC); Naser, Najih (Durham, NC); O'Daly, John P. (Carrboro, NC)

    1995-01-01

    The present invention provides a new device for use in measuring lead levels in biological and environmental samples. Using square wave coulometry and colloidal gold particles impregnated on carbon electrodes, the present invention provides a rapid, reliable, portable and inexpensive means of detecting low lead levels. The colloidal gold modified electrodes have microelectrode array characteristics and produce significantly higher stripping detection signals for lead than are produced at bulk gold electrode surfaces. The method is effective in determining levels of lead down to at least 5 .mu.g/dL in blood samples as small as 10 .mu.L.

  15. Colloidal-gold electrosensor measuring device

    DOE Patents [OSTI]

    Wegner, S.; Harpold, M.A.; McCaffrey, T.M.; Morris, S.E.; Wojciechowski, M.; Zhao, J.; Henkens, R.W.; Naser, N.; O`Daly, J.P.

    1995-11-21

    The present invention provides a new device for use in measuring lead levels in biological and environmental samples. Using square wave coulometry and colloidal gold particles impregnated on carbon electrodes, the present invention provides a rapid, reliable, portable and inexpensive means of detecting low lead levels. The colloidal gold modified electrodes have microelectrode array characteristics and produce significantly higher stripping detection signals for lead than are produced at bulk gold electrode surfaces. The method is effective in determining levels of lead down to at least 5 {micro}g/dL in blood samples as small as 10 {micro}L. 9 figs.

  16. Poverty, solidarity, and opportunity: the 1938 San Antonio pecan shellers' strike 

    E-Print Network [OSTI]

    Keyworth, Matthew Jerrid

    2009-05-15

    Kilday?s officers, but they also received an infusion of support from the Congress of Industrial Organizations (CIO). As CIO organizers took control of the strike, they asked Governor James V. Allred to send Texas Rangers to protect the shellers from..., the newly mandated federal minimum wage significantly changed the shelling industry in San Antonio. 4 3 Texas Civil Liberties Union, San Antonio ? The Cradle of Texas Liberty, and Its Coffin? (Austin...

  17. Evaluation of Blade-Strike Models for Estimating the Biological Performance of Large Kaplan Hydro Turbines

    SciTech Connect (OSTI)

    Deng, Zhiqun; Carlson, Thomas J.; Ploskey, Gene R.; Richmond, Marshall C.

    2005-11-30

    BioIndex testing of hydro-turbines is sought as an analog to the hydraulic index testing conducted on hydro-turbines to optimize their power production efficiency. In BioIndex testing the goal is to identify those operations within the range identified by Index testing where the survival of fish passing through the turbine is maximized. BioIndex testing includes the immediate tailrace region as well as the turbine environment between a turbine's intake trashracks and the exit of its draft tube. The US Army Corps of Engineers and the Department of Energy have been evaluating a variety of means, such as numerical and physical turbine models, to investigate the quality of flow through a hydro-turbine and other aspects of the turbine environment that determine its safety for fish. The goal is to use these tools to develop hypotheses identifying turbine operations and predictions of their biological performance that can be tested at prototype scales. Acceptance of hypotheses would be the means for validation of new operating rules for the turbine tested that would be in place when fish were passing through the turbines. The overall goal of this project is to evaluate the performance of numerical blade strike models as a tool to aid development of testable hypotheses for bioIndexing. Evaluation of the performance of numerical blade strike models is accomplished by comparing predictions of fish mortality resulting from strike by turbine runner blades with observations made using live test fish at mainstem Columbia River Dams and with other predictions of blade strike made using observations of beads passing through a 1:25 scale physical turbine model.

  18. Femtosecond surface plasmon interferometry with gold nanostructures

    E-Print Network [OSTI]

    Temnov, Vasily V.

    We measure the ultrafast electron dynamics in gold via ultrafast surface plasmon interferometry. A new plasmonic microinterferometer with tilted slit-groove pair is used to unambiguously determine changes of real and ...

  19. Update Direct-Strike Lightning Environment for Stockpile-to-Target Sequence

    SciTech Connect (OSTI)

    Uman, M A; Rakov, V A; Elisme, J O; Jordan, D M; Biagi, C J; Hill, J D

    2008-10-01

    The University of Florida has surveyed all relevant publications reporting lightning characteristics and presents here an up-to-date version of the direct-strike lightning environment specifications for nuclear weapons published in 1989 by R. J. Fisher and M. A. Uman. Further, we present functional expressions for current vs. time, current derivative vs. time, second current derivative vs. time, charge transfer vs. time, and action integral (specific energy) vs. time for first return strokes, for subsequent return strokes, and for continuing currents; and we give sets of constants for these expressions so that they yield approximately the median and extreme negative lightning parameters presented in this report. Expressions for the median negative lightning waveforms are plotted. Finally, we provide information on direct-strike lightning damage to metals such as stainless steel, which could be used as components of storage containers for nuclear waste materials; and we describe UF's new experimental research program to add to the sparse data base on the properties of positive lightning. Our literature survey, referred to above, is included in four Appendices. The following four sections (II, III, IV, and V) of this final report deal with related aspects of the research: Section II. Recommended Direct-Strike Median and Extreme Parameters; Section III. Time-Domain Waveforms for First Strokes, Subsequent Strokes, and Continuing Currents; Section IV. Damage to Metal Surfaces by Lightning Currents; and Section V. Measurement of the Characteristics of Positive Lightning. Results of the literature search used to derive the material in Section II and Section IV are found in the Appendices: Appendix 1. Return Stroke Current, Appendix 2. Continuing Current, Appendix 3. Positive Lightning, and Appendix 4. Lightning Damage to Metal Surfaces.

  20. Fish Passage though Hydropower Turbines: Simulating Blade Strike using the Discrete Element Method

    SciTech Connect (OSTI)

    Richmond, Marshall C.; Romero Gomez, Pedro DJ

    2014-12-08

    mong the hazardous hydraulic conditions affecting anadromous and resident fish during their passage though turbine flows, two are believed to cause considerable injury and mortality: collision on moving blades and decompression. Several methods are currently available to evaluate these stressors in installed turbines, i.e. using live fish or autonomous sensor devices, and in reduced-scale physical models, i.e. registering collisions from plastic beads. However, a priori estimates with computational modeling approaches applied early in the process of turbine design can facilitate the development of fish-friendly turbines. In the present study, we evaluated the frequency of blade strike and nadir pressure environment by modeling potential fish trajectories with the Discrete Element Method (DEM) applied to fish-like composite particles. In the DEM approach, particles are subjected to realistic hydraulic conditions simulated with computational fluid dynamics (CFD), and particle-structure interactions—representing fish collisions with turbine blades—are explicitly recorded and accounted for in the calculation of particle trajectories. We conducted transient CFD simulations by setting the runner in motion and allowing for better turbulence resolution, a modeling improvement over the conventional practice of simulating the system in steady state which was also done here. While both schemes yielded comparable bulk hydraulic performance, transient conditions exhibited a visual improvement in describing flow variability. We released streamtraces (steady flow solution) and DEM particles (transient solution) at the same location from where sensor fish (SF) have been released in field studies of the modeled turbine unit. The streamtrace-based results showed a better agreement with SF data than the DEM-based nadir pressures did because the former accounted for the turbulent dispersion at the intake but the latter did not. However, the DEM-based strike frequency is more representative of blade-strike probability than the steady solution is, mainly because DEM particles accounted for the full fish length, thus resolving (instead of modeling) the collision event.

  1. Simulating Blade-Strike on Fish passing through Marine Hydrokinetic Turbines

    SciTech Connect (OSTI)

    Romero Gomez, Pedro DJ; Richmond, Marshall C.

    2014-06-16

    The study reported here evaluated the occurrence, frequency, and intensity of blade strike of fish on an axial-flow marine hydrokinetic turbine by using two modeling approaches: a conventional kinematic formulation and a proposed Lagrangian particle- based scheme. The kinematic model included simplifying assumptions of fish trajectories such as distribution and velocity. The proposed method overcame the need for such simplifications by integrating the following components into a computational fluid dynamics (CFD) model: (i) advanced eddy-resolving flow simulation, (ii) generation of ambient turbulence based on field data, (iii) moving turbine blades in highly transient flows, and (iv) Lagrangian particles to mimic the potential fish pathways. The test conditions to evaluate the blade-strike probability and fish survival rate were: (i) the turbulent environment, (ii) the fish size, and (iii) the approaching flow velocity. The proposed method offered the ability to produce potential fish trajectories and their interaction with the rotating turbine. Depending upon the scenario, the percentile of particles that registered a collision event ranged from 6% to 19% of the released sample size. Next, by using a set of experimental correlations of the exposure-response of living fish colliding with moving blades, the simulated collision data were used as input variables to estimate the survival rate of fish passing through the operating turbine. The resulting survival rates were greater than 96% in all scenarios, which is comparable to or better than known survival rates for conventional hydropower turbines. The figures of strike probability and mortality rate were amplified by the kinematic model. The proposed method offered the advantage of expanding the evaluation of other mechanisms of stress and injury on fish derived from hydrokinetic turbines and related devices.

  2. DISCRETE ELEMENT MODELING OF BLADE–STRIKE FREQUENCY AND SURVIVAL OF FISH PASSING THROUGH HYDROKINETIC TURBINES

    SciTech Connect (OSTI)

    Romero Gomez, Pedro DJ; Richmond, Marshall C.

    2014-04-17

    Evaluating the consequences from blade-strike of fish on marine hydrokinetic (MHK) turbine blades is essential for incorporating environmental objectives into the integral optimization of machine performance. For instance, experience with conventional hydroelectric turbines has shown that innovative shaping of the blade and other machine components can lead to improved designs that generate more power without increased impacts to fish and other aquatic life. In this work, we used unsteady computational fluid dynamics (CFD) simulations of turbine flow and discrete element modeling (DEM) of particle motion to estimate the frequency and severity of collisions between a horizontal axis MHK tidal energy device and drifting aquatic organisms or debris. Two metrics are determined with the method: the strike frequency and survival rate estimate. To illustrate the procedure step-by-step, an exemplary case of a simple runner model was run and compared against a probabilistic model widely used for strike frequency evaluation. The results for the exemplary case showed a strong correlation between the two approaches. In the application case of the MHK turbine flow, turbulent flow was modeled using detached eddy simulation (DES) in conjunction with a full moving rotor at full scale. The CFD simulated power and thrust were satisfactorily comparable to experimental results conducted in a water tunnel on a reduced scaled (1:8.7) version of the turbine design. A cloud of DEM particles was injected into the domain to simulate fish or debris that were entrained into the turbine flow. The strike frequency was the ratio of the count of colliding particles to the crossing sample size. The fish length and approaching velocity were test conditions in the simulations of the MHK turbine. Comparisons showed that DEM-based frequencies tend to be greater than previous results from Lagrangian particles and probabilistic models, mostly because the DEM scheme accounts for both the geometric aspects of the passage event ---which the probabilistic method does--- as well as the fluid-particle interactions ---which the Lagrangian particle method does. The DEM-based survival rates were comparable to laboratory results for small fish but not for mid-size fish because of the considerably different turbine diameters. The modeling framework can be used for applications that aim at evaluating the biological performance of MHK turbine units during the design phase and to provide information to regulatory agencies needed for the environmental permitting process.

  3. Geology of the Florida Canyon gold deposit, Pershing County,...

    Open Energy Info (EERE)

    Geology of the Florida Canyon gold deposit, Pershing County, Nevada, in: Gold and Silver Deposits of Western Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to...

  4. Electronic interactions between gold films and mn12-acetate 

    E-Print Network [OSTI]

    Means, Joel Lewis

    2009-05-15

    Interactions between Mn12–acetate molecular magnets and thin gold films have been explored in light of the theory of weak localization. Low-temperature measurements of the magnetoresistance of gold films of varying thicknesses, with and without...

  5. 1 | P a g e Boiler Gold Rush

    E-Print Network [OSTI]

    Ginzel, Matthew

    1 | P a g e Boiler Gold Rush VISION STATEMENT The vision of BGR is twofold: first, help all new by participating in the premiere orientation program in the nation, Boiler Gold Rush. Second, enhance upper leaders for the betterment of the university. PROGRAM GOALS Boiler Gold Rush will provide the following

  6. Gold-coated nanoparticles for use in biotechnology applications

    DOE Patents [OSTI]

    Berning, Douglas E. (Los Alamos, NM); Kraus, Jr., Robert H. (Los Alamos, NM); Atcher, Robert W. (Los Alamos, NM); Schmidt, Jurgen G. (Los Alamos, NM)

    2009-07-07

    A process of preparing gold-coated magnetic nanoparticles is disclosed and includes forming a suspension of magnetic nanoparticles within a suitable liquid, adding an amount of a reducible gold compound and a reducing agent to the suspension, and, maintaining the suspension for time sufficient to form gold-coated magnetic nanoparticles.

  7. Fish Passage Assessment of an Advanced Hydropower Turbine and Conventional Turbine Using Blade-strike Modeling

    SciTech Connect (OSTI)

    Deng, Zhiqun; Carlson, Thomas J.; Dauble, Dennis D.; Ploskey, Gene R.

    2011-01-04

    In the Columbia and Snake River basins, several species of Pacific salmon were listed under the Endangered Species Act of 1973 due to significant declines of fish population. Dam operators and design engineers are thus faced with the task of making those hydroelectric facilities more ecologically friendly through changes in hydro-turbine design and operation. Public Utility District No. 2 of Grant County, Washington, applied for re-licensing from the U.S. Federal Energy Regulatory Commission to replace the 10 turbines at Wanapum Dam with advanced hydropower turbines that were designed to increase power generation and improve fish passage conditions. We applied both deterministic and stochastic blade-strike models to the newly installed turbine and an existing turbine. Modeled probabilities were compared to the results of a large-scale live fish survival study and a sensor fish study under the same operational parameters. Overall, injury rates predicted by the deterministic model were higher than experimental rates of injury while those predicted by the stochastic model were in close agreement with experiment results. Fish orientation at the time of entry into the plane of the leading edges of the turbine runner blades was an important factor contributing to uncertainty in modeled results. The advanced design turbine had slightly higher modeled injury rates than the existing turbine design; however, there was no statistical evidence that suggested significant differences in blade-strike injuries between the two turbines and the hypothesis that direct fish survival rate through the advanced hydropower turbine is equal or better than that through the conventional turbine could not be rejected.

  8. Estimation of the Risks of Collision or Strike to Freshwater Aquatic Organisms Resulting from Operation of Instream Hydrokinetic Turbines

    SciTech Connect (OSTI)

    Schweizer, Peter E; Cada, Glenn F; Bevelhimer, Mark S

    2010-05-01

    Hydrokinetic energy technologies have been proposed as renewable, environmentally preferable alternatives to fossil fuels for generation of electricity. Hydrokinetic technologies harness the energy of water in motion, either from waves, tides or from river currents. For energy capture from free-flowing rivers, arrays of rotating devices are most commonly proposed. The placement of hydrokinetic devices in large rivers is expected to increase the underwater structural complexity of river landscapes. Moore and Gregory (1988) found that structural complexity increased local fish populations because fish and other aquatic biota are attracted to structural complexity that provides microhabitats with steep flow velocity gradients (Liao 2007). However, hydrokinetic devices have mechanical parts, blades, wings or bars that move through the water column, posing a potential strike or collision risk to fish and other aquatic biota. Furthermore, in a setting with arrays of hydrokinetic turbines the cumulative effects of multiple encounters may increase the risk of strike. Submerged structures associated with a hydrokinetic (HK) project present a collision risk to aquatic organisms and diving birds (Cada et al. 2007). Collision is physical contact between a device or its pressure field and an organism that may result in an injury to that organism (Wilson et al. 2007). Collisions can occur between animals and fixed submerged structures, mooring equipment, horizontal or vertical axis turbine rotors, and structures that, by their individual design or in combination, may form traps. This report defines strike as a special case of collision where a moving part, such as a rotor blade of a HK turbine intercepts the path of an organism of interest, resulting in physical contact with the organism. The severity of a strike incidence may range from minor physical contact with no adverse effects to the organism to severe strike resulting in injury or death of the organism. Harmful effects to animal populations could occur directly (e.g., from strike mortality of individuals) or indirectly (e.g., if the loss of prey species to strike reduces food for predators). Although actively swimming or passively drifting animals may collide with any of the physical structures associated with hydrokinetic devices, turbine rotors are the most likely sources for risk of strike or significant collision (DOE 2009). It is also possible that during a close encounter with a HK device no physical contact will be made between the device and the organism, either because the animal avoids the device by successfully changing its direction of movement, or by successfully evading any moving parts of the device. Oak Ridge National Laboratory (ORNL) has been funded by the US Department of Energy (DOE) Waterpower Program to evaluate strike potential and consequences for Marine and Hydrokinetic (MHK) technologies in rivers and estuaries of the United States. We will use both predictive models and laboratory/field experiments to evaluate the likelihood and consequences of strike at HK projects in rivers. Efforts undertaken at ORNL address three objectives: (1) Assess strike risk for marine and freshwater organisms; (2) Develop experimental procedures to assess the risk and consequences of strike; and (3) Conduct strike studies in experimental flumes and field installations of hydrokinetic devices. During the first year of the study ORNL collected information from the Federal Energy Regulatory Commission (FERC) MHK database about geographical distribution of proposed hydrokinetic projects (what rivers or other types of systems), HK turbine design (horizontal axis, vertical axis, other), description of proposed axial turbine (number of blades, size of blades, rotation rate, mitigation measures), and number of units per project. Where site specific information was available, we compared the location of proposed projects rotors within the channel (e.g., along cutting edge bank, middle of thalweg, near bottom or in midwater) to the general locations of fish in the river (shoreline,

  9. Shape separation of gold nanorods using centrifugation

    E-Print Network [OSTI]

    Sharma, Vivek

    Shape separation of gold nanorods using centrifugation Vivek Sharmaa,1 , Kyoungweon Parka,2 , and Mohan Srinivasaraoa,b,c,3 aSchool of Polymer Textile and Fiber Engineering, bCenter for Advanced, and approved January 23, 2009 (received for review January 29, 2008) We demonstrate the use of centrifugation

  10. X-ray laser driven gold targets

    SciTech Connect (OSTI)

    Petrova, Tz. B., E-mail: lina.petrova@nrl.navy.mil; Whitney, K. G.; Davis, J. [Plasma Physics Division, Naval Research Laboratory, 4555 Overlook Ave. SW, Washington, DC 20375 (United States)] [Plasma Physics Division, Naval Research Laboratory, 4555 Overlook Ave. SW, Washington, DC 20375 (United States)

    2014-03-15

    The femtosecond population dynamics of gold irradiated by a coherent high-intensity (>10{sup 17}?W/cm{sup 2}) x-ray laser pulse is investigated theoretically. There are two aspects to the assembled model. One is the construction of a detailed model of platinum-like gold inclusive of all inner-shell states that are created by photoionization of atomic gold and decay either by radiative or Auger processes. Second is the computation of the population dynamics that ensues when an x-ray pulse is absorbed in gold. The hole state generation depends on the intensity and wavelength of the driving x-ray pulse. The excited state populations reached during a few femtosecond timescales are high enough to generate population inversions, whose gain coefficients are calculated. These amplified lines in the emitted x-ray spectrum provide important diagnostics of the radiation dynamics and also suggest a nonlinear way to increase the frequency of the coherent output x-ray pulses relative to the frequency of the driver input x-ray pulse.

  11. Mining Gold from your Cooling Water System 

    E-Print Network [OSTI]

    Mendez, T.

    2007-01-01

    stream_source_info ESL-IE-07-05-25.pdf.txt stream_content_type text/plain stream_size 6756 Content-Encoding ISO-8859-1 stream_name ESL-IE-07-05-25.pdf.txt Content-Type text/plain; charset=ISO-8859-1 Mining Gold from your...

  12. Electrochemistry on Alternate Structures of Gold Nanoparticles Bull. Korean Chem. Soc. 2004, Vol. 25, No. 11 1681 Electrochemistry on Alternate Structures of Gold Nanoparticles

    E-Print Network [OSTI]

    Kwak, Juhyoun

    Electrochemistry on Alternate Structures of Gold Nanoparticles Bull. Korean Chem. Soc. 2004, Vol. 25, No. 11 1681 Electrochemistry on Alternate Structures of Gold Nanoparticles and Ferrocene

  13. Brazing open cell reticulated copper foam to stainless steel tubing with vacuum furnace brazed gold/indium alloy plating

    DOE Patents [OSTI]

    Howard, Stanley R. (Windsor, SC); Korinko, Paul S. (Aiken, SC)

    2008-05-27

    A method of fabricating a heat exchanger includes brush electroplating plated layers for a brazing alloy onto a stainless steel tube in thin layers, over a nickel strike having a 1.3 .mu.m thickness. The resultant Au-18 In composition may be applied as a first layer of indium, 1.47 .mu.m thick, and a second layer of gold, 2.54 .mu.m thick. The order of plating helps control brazing erosion. Excessive amounts of brazing material are avoided by controlling the electroplating process. The reticulated copper foam rings are interference fit to the stainless steel tube, and in contact with the plated layers. The copper foam rings, the plated layers for brazing alloy, and the stainless steel tube are heated and cooled in a vacuum furnace at controlled rates, forming a bond of the copper foam rings to the stainless steel tube that improves heat transfer between the tube and the copper foam.

  14. The Strikingly Uniform, Highly Turbulent Interstellar Medium of the Most Luminous Galaxy in the Universe

    E-Print Network [OSTI]

    Diaz-Santos, T; Blain, A W; Tsai, C -W; Aravena, M; Eisenhardt, P; Wu, J; Stern, D; Bridge, C

    2015-01-01

    Observed at z = 4.601 and with L_bol = 3.5 x 10^14 Lsun, W2246-0526 is the most luminous galaxy known in the Universe, and hosts a deeply-buried active galactic nucleus (AGN)/super-massive black hole (SMBH). Discovered using the Wide-field Infrared Survey Explorer (WISE), W2246-0526 is classified as a Hot Dust Obscured Galaxy (Hot DOG), based on its luminosity and dust temperature. Here we present spatially resolved ALMA [CII]157.7um observations of W2246-0526, providing unique insight into the kinematics of its interstellar medium (ISM). The measured [CII]-to-far-infrared ratio is ~2 x 10^-4, implying ISM conditions that compare only with the most obscured, compact starbursts and AGN in the local Universe today. The spatially resolved [CII] line is strikingly uniform and very broad, 500-600 km/s wide, extending throughout the entire galaxy over about 2.5 kpc, with modest shear. Such a large, homogeneous velocity dispersion indicates a highly turbulent medium. W2246-0526 is unstable in terms of the energy and...

  15. AC 2011-2087: FIRST YEAR ENGINEERING STUDENTS ARE STRIK-INGLY IMPOVERISHED IN THEIR SELF-CONCEPT AS PROFESSIONAL

    E-Print Network [OSTI]

    Guilford, William

    AC 2011-2087: FIRST YEAR ENGINEERING STUDENTS ARE STRIK- INGLY IMPOVERISHED IN THEIR SELF-CONCEPT for education. Brian A Nosek, University of Virginia c American Society for Engineering Education, 2011 #12;First year engineering students are strikingly impoverished in their self-concept as professional

  16. Neotectonic structures in Izmir Gulf and surrounding regions (western Turkey): Evidences of strike-slip faulting with

    E-Print Network [OSTI]

    Irfanoglu, Ayhan

    Neotectonic structures in Izmir Gulf and surrounding regions (western Turkey): Evidences of strike 80626, Istanbul, Turkey b Maden Tetkik ve Arama Genel Mu¨du¨rlu¨gu¨, Jeoloji Dairesi, Eskis¸ehir Yolu, 06520 Ankara, Turkey Received 11 September 2003; received in revised form 6 June 2005; accepted 16 June

  17. Rupture Dynamics of Strike-Slip Faults with Stepovers: From Conceptually Simplified to Realistically Complex Fault Systems 

    E-Print Network [OSTI]

    Liu, Zaifeng

    2014-05-05

    . The coupling effect of those two effects has also been studied. The possible correlation between the slip gradient nearby the first fault end and the ability of the rupture to jump over the structure stepover in the strike-slip fault system has been verified...

  18. Voltages across assembly joints due to direct-strike lightning currents

    SciTech Connect (OSTI)

    Dinallo, M.S. [Quatro Corp., Albuquerque, NM (United States); Fisher, R.J. [Sandia National Labs., Albuquerque, NM (United States)

    1994-08-01

    An extensive set of direct-strike lightning tests has been carried out on a set of facsimile assembly joints of the kinds employed in the design of nuclear weapon cases. Taken as a whole, the test hardware included all the conceptual design elements that are embodied, either singly or in combination, in any specific assembly joint incorporated into any stockpiled weapon. During the present testing, the effects of all key design parameters on the voltages developed across the interior of the joints were investigated under a range of lightning stroke current parameter values. Design parameter variations included the types and number of joint fasteners, mechanical preload, surface finish tolerance and coatings, and the material from which the joint assembly was fabricated. Variations of the simulated lightning stroke current included amplitude (30-, 100-, and 200-kA peak), rise time, and decay time. The maximum voltage observed on any of the test joints that incorporated proper metal-to-metal surface contact was 65 V. Typical response values were more on the order of 20 V. In order to assess the effect of the presence of a dielectric coating (either intentional or as a result of corrosion) between the mating surfaces of a joint, a special configuration was tested in which the mating parts of the test assembly were coated with a 1-mil-thick dielectric anodizing layer. First strokes to these test assemblies resulted in very narrow voltage spikes of amplitudes up to 900 V. The durations of these spikes were less than 0.1 {mu}s. However, beyond these initial spikes, the voltages typically had amplitudes of up to 400 V for durations of 3 to 5 {mu}s.

  19. Federal Electronics Challenge Gold Award | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Headquarters was presented the Federal Electronics Challenge Gold Award for exemplary performance in Green Computing, including green procurement, energy efficient operations...

  20. Sponsored by Nanotechnology Seminar Program Surface Chemistry of Gold

    E-Print Network [OSTI]

    Fisher, Frank

    Sponsored by Nanotechnology Seminar Program Surface Chemistry of Gold Nanorods: Wrapping chemistry, biophysical chemistry and nanotechnology, with a primary goal to develop inorganic nanomaterials

  1. Effect of Gold Nanorod Surface Chemistry on Cellular Response

    E-Print Network [OSTI]

    Grabinski, Christin

    Gold nanorods (GNRs) stabilized with cetyltrimethylammonium bromide (CTAB) and GNR functionalized via a ligand exchange method with either thiolated polyethylene glycol (PEG5000) or mercaptohexadecanoic acid (MHDA) were ...

  2. Argonne APCF achieves LEED Gold rating | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory's Advanced Protein Characterization Facility (APCF) has received the U.S. Green Building Council's Leadership in Energy and Environmental Design (LEED) Gold...

  3. Epithermal Gold Mineralization and a Geothermal Resource at Blue...

    Open Energy Info (EERE)

    Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain, Humboldt County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  4. Los Alamos explores hybrid ultrasmall gold nanocluster for enzymatic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alamos explores hybrid ultrasmall gold nanocluster for enzymatic fuel cells With fossil-fuel sources dwindling, better biofuel cell design is a strong candidate in the energy...

  5. Gold nanoparticle formation in diamond-like carbon using two different methods: Gold ion implantation and co-deposition of gold and carbon

    SciTech Connect (OSTI)

    Salvadori, M. C.; Teixeira, F. S.; Araujo, W. W. R.; Sgubin, L. G.; Cattani, M.; Spirin, R. E.; Brown, I. G.

    2012-10-01

    We describe work in which gold nanoparticles were formed in diamond-like carbon (DLC), thereby generating a Au-DLC nanocomposite. A high-quality, hydrogen-free DLC thin film was formed by filtered vacuum arc plasma deposition, into which gold nanoparticles were introduced using two different methods. The first method was gold ion implantation into the DLC film at a number of decreasing ion energies, distributing the gold over a controllable depth range within the DLC. The second method was co-deposition of gold and carbon, using two separate vacuum arc plasma guns with suitably interleaved repetitive pulsing. Transmission electron microscope images show that the size of the gold nanoparticles obtained by ion implantation is 3-5 nm. For the Au-DLC composite obtained by co-deposition, there were two different nanoparticle sizes, most about 2 nm with some 6-7 nm. Raman spectroscopy indicates that the implanted sample contains a smaller fraction of sp{sup 3} bonding for the DLC, demonstrating that some sp{sup 3} bonds are destroyed by the gold implantation.

  6. Method for aqueous gold thiosulfate extraction using copper-cyanide pretreated carbon adsorption

    DOE Patents [OSTI]

    Young, Courtney; Melashvili, Mariam; Gow, Nicholas V

    2013-08-06

    A gold thiosulfate leaching process uses carbon to remove gold from the leach liquor. The activated carbon is pretreated with copper cyanide. A copper (on the carbon) to gold (in solution) ratio of at least 1.5 optimizes gold recovery from solution. To recover the gold from the carbon, conventional elution technology works but is dependent on the copper to gold ratio on the carbon.

  7. BlackGold Biofuels | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpII Jump to:BitworksFarmBlackGold

  8. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    foundation for modern-day chemistry. Today, iridescent gold particles are used in biosensors, drug delivery, and many other applications, but for all gold's uses, the structure...

  9. W I N T E R 2 0 1 2 / 1 3 APOCALYPSE WHEN > RETHINKING FOOD > STRIKING OUT FEAR

    E-Print Network [OSTI]

    Doedel, Eusebius

    W I N T E R 2 0 1 2 / 1 3 APOCALYPSE WHEN > RETHINKING FOOD > STRIKING OUT FEAR RETAILING RELIGION% recycled paper, including 20% post consumer waste. For each ton of recycled paper that displaces a ton emissions by 28%, wastewater by 33%, solid waste by 54% and wood use by 100%. w i n t e r 2 0 1 2 / 1 3 v o

  10. Going green earns Laboratory gold June 18, 2012

    E-Print Network [OSTI]

    - 1 - Going green earns Laboratory gold June 18, 2012 High performance sustainable building attains LEED Gold certification From its robust design to its advanced scientific equipment, the Radiological Laboratory Utility Office Building (RLUOB) is essential to the Lab's national security mission in support

  11. Controlled Bacteria -Gold Nanorod Interactions for Enhancement of Optoacoustic Contrast

    E-Print Network [OSTI]

    Natelson, Douglas

    Controlled Bacteria - Gold Nanorod Interactions for Enhancement of Optoacoustic Contrast Anton as a model of positively charged gold surface for quantitative optoacoustic sensing in GNR-bacteria controlled agglomeration of contrast agents with the bacteria E.Coli and Vibrio Cholerae. For bacterial

  12. Gold nanoparticle assemblies: Interplay between thermal effects and optical response

    E-Print Network [OSTI]

    Boyer, Edmond

    Department of Physics, University of Sistan and Baluchistan, Zahedan, Iran c Université Paris Sorbonne-order nonlinear properties of gold nanoparticles: The influence of the generalized thermal lens in the long laser of an embedded gold nanoparticle subsequent to ultrafast pulsed laser excitation. 1. Introduction The remarkable

  13. Boiler Gold Rush Prof. Johnny Brown (MATH 700)

    E-Print Network [OSTI]

    Brown, Johnny E.

    Boiler Gold Rush Prof. Johnny Brown (MATH 700) jeb@math.purdue.edu #12;#12;#12;David McCullough, Jr help Always be prepared #12;Boiler Gold Rush Prof. Johnny Brown (MATH 700) jeb@math.purdue.edu #12;

  14. Intense emission of cluster anions from gold targets under impact of keV/u gold clusters.

    E-Print Network [OSTI]

    Boyer, Edmond

    Intense emission of cluster anions from gold targets under impact of keV/u gold clusters. M the emission yield of anionic clusters increases much faster with n than expected from simple proportionality. Accordingly, the most intense emission is observed for Au7 - : under Au9 + impact the Au7 - yield per incident

  15. 1 mil gold bond wire study.

    SciTech Connect (OSTI)

    Huff, Johnathon; McLean, Michael B.; Jenkins, Mark W.; Rutherford, Brian Milne

    2013-05-01

    In microcircuit fabrication, the diameter and length of a bond wire have been shown to both affect the current versus fusing time ratio of a bond wire as well as the gap length of the fused wire. This study investigated the impact of current level on the time-to-open and gap length of 1 mil by 60 mil gold bond wires. During the experiments, constant current was provided for a control set of bond wires for 250ms, 410ms and until the wire fused; non-destructively pull-tested wires for 250ms; and notched wires. The key findings were that as the current increases, the gap length increases and 73% of the bond wires will fuse at 1.8A, and 100% of the wires fuse at 1.9A within 60ms. Due to the limited scope of experiments and limited data analyzed, further investigation is encouraged to confirm these observations.

  16. Gold is the most valued of metals. Throughout history it has played a key role

    E-Print Network [OSTI]

    Hutter, Frank

    communities. Today in developing countries, communities living in extreme poverty rely on artisanal gold

  17. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Print Nanoparticles-man-made atoms with unique optical, electrical, and mechanical properties-have become key components in many fields of...

  18. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to...

  19. GOLD--1997 33.1 By Earle B. Amey

    E-Print Network [OSTI]

    Survey (USGS), entered negotiations with 17 Asian and Pacific Rim governments to reduce barriers in gold, and countries in the Pacific region have the potential for the occurrence of this type of deposit (Wilburn, 1998

  20. Enhancement of in vitro Translation by Gold Nanoparticle – DNA Conjugates

    E-Print Network [OSTI]

    Park, Sunho

    Gold nanoparticle (AuNP)?DNA conjugates can enhance in vitro translation of a protein. Enhancement occurs via a combination of nonspecific adsorption of translation-related molecules and the ribosome to the AuNP?DNA and ...

  1. Effect of ligand on thermal dissipation from gold nanorods

    E-Print Network [OSTI]

    Alper, Joshua

    Thermal interface conductance was measured for soluble gold nanorods (NRs) coated with mercaptocarboxylic acids (HS-(CH[subscript 2])[subscript n]COOH, n = 5, 10, 15), thiolated polyethylene glycols (MW = 356, 1000, 5000), ...

  2. And The Truth Shall Be Read In Gold 

    E-Print Network [OSTI]

    Evans, Terry; Foster, Donna; Slattery, Peter

    1982-01-01

    of nanocomposites. Experimental results showed that the mechanical properties of nanocomposites measured at macroscale exhibited differences when the shape and size of gold NPs were changed. The morphological characteristics of the material were shown effectively...

  3. (Data in metric tons of gold content unless otherwise noted)

    E-Print Network [OSTI]

    , expansion projects, and development projects were placed on hold because of the drop in the price of gold,140 8,140 Price, dollars per troy ounce 4 975 1,228 1,572 1,673 1,400 Employment, mine and mill, number, and Issues: The estimated gold price in 2013 was 16% lower than the price in 2012. This was the first time

  4. Designing for Sustainability: Houston DOW Center LEED Gold 

    E-Print Network [OSTI]

    McCall, H.; McVey, K.; Rash, A.

    2010-01-01

    for Sustainability Houston Dow Center - LEED Gold Heidi McCall Kevin McVey Adam Rash Designing for Sustainability Houston Dow Center About Dow ? Largest diversified chemical company in the world ? Founded in Midland, Michigan in 1897 ? Supplies more than 5... & Office Facilities Management Technology Center Front-end Loading Energy Reporting Implementation Methodology Goals & Technology Senior Leadership Support Key Elements of HDC?s LEED Gold Construction and Commissioning Change Management...

  5. Study of the effect of plasma-striking atmosphere on Fe-oxidation in thermal dc arc-plasma processing

    SciTech Connect (OSTI)

    Banerjee, I.; Khollam, Y. B.; Mahapatra, S. K.; Das, A. K.; Bhoraskar, S. V.

    2010-11-15

    The effect of plasma-striking atmosphere: air and air+Ar-gas on the crystallization of Fe-oxide phases was studied using dc thermal arc-plasma processing route. The powders were characterized by x-ray diffraction, vibrating sample magnetometry, transmission electron microscopy, and Moessbauer spectroscopy techniques. At room temperature and O{sub 2} rich atmosphere, arc-evaporated Fe{sup 2+} ions oxidize into either {gamma}-Fe{sub 2}O{sub 3} or Fe{sub 3}O{sub 4} depending upon the combining ratio of Fe with molecular O{sub 2}. Fe/O ratio could be adjusted using proper flow rate of Ar gas to crystallize the pure {gamma}-Fe{sub 2}O{sub 3}.

  6. The processes of industrial gold mining and inequality: a Ghanaian case study 

    E-Print Network [OSTI]

    Gawor, Natalie

    2011-11-24

    The research examined how inequality manifests itself through the processes of industrial gold mining using a case study of Newmont Mining Corporations’ Ahafo Gold Mine in Ghana. The pursuit of neoliberal development and widespread transnational...

  7. Interaction of amphiphilic gold nanoparticles with lipid membranes and their application to cancer radiotherapy

    E-Print Network [OSTI]

    Yang, Yu-Sang

    2013-01-01

    Striped gold nanoparticles (NPs), inorganic particles protected by an amphiphilic mixed organic ligand shell, are the most recent and potent evolution of gold nanoparticle intracellular delivery vectors. Here we propose ...

  8. Solar Companies Go for the Gold with SunShot Incubator | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Companies Go for the Gold with SunShot Incubator Solar Companies Go for the Gold with SunShot Incubator July 26, 2012 - 9:45am Addthis William Parish from Solar Mosaic, one...

  9. Biomedical Applications of Gold Nanoparticles Functionalized Using Hetero-Bifunctional Poly(ethylene glycol) Spacer

    E-Print Network [OSTI]

    Sridhar, Srinivas

    Biomedical Applications of Gold Nanoparticles Functionalized Using Hetero-Bifunctional Poly potential, circulation time, and the flexibility of surface-attached biomedically-relevant ligands on gold varieties of nanoparticles with biomedical relevance are available including, polymeric nanoparticles, metal

  10. Laboratory Experiments on the Effects of Blade Strike from Hydrokinetic Energy Technologies on Larval and Juvenile Freshwater Fishes

    SciTech Connect (OSTI)

    Schweizer, Peter E; Cada, Glenn F; Bevelhimer, Mark S

    2012-03-01

    There is considerable interest in the development of marine and hydrokinetic energy projects in rivers, estuaries, and coastal ocean waters of the United States. Hydrokinetic (HK) technologies convert the energy of moving water in river or tidal currents into electricity, without the impacts of dams and impoundments associated with conventional hydropower or the extraction and combustion of fossil fuels. The Federal Energy Regulatory Commission (FERC) maintains a database that displays the geographical distribution of proposed HK projects in inland and tidal waters (FERC 2012). As of March 2012, 77 preliminary permits had been issued to private developers to study HK projects in inland waters, the development of which would total over 8,000 MW. Most of these projects are proposed for the lower Mississippi River. In addition, the issuance of another 27 preliminary permits for HK projects in inland waters, and 3 preliminary permits for HK tidal projects (totaling over 3,100 MW) were under consideration by FERC. Although numerous HK designs are under development (see DOE 2009 for a description of the technologies and their potential environmental effects), the most commonly proposed current-based projects entail arrays of rotating devices, much like submerged wind turbines, that are positioned in the high-velocity (high energy) river channels. The many diverse HK designs imply a diversity of environmental impacts, but a potential impact common to most is the risk for blade strike to aquatic organisms. In conventional hydropower generation, research on fish passage through reaction turbines at low-head dams suggested that strike and mortality for small fish could be low. As a consequence of the large surface area to mass ratio of small fish, the drag forces in the boundary layer flow at the surface of a rotor blade may pull small fish around the leading edge of a rotor blade without making physical contact (Turnpenny 1998, Turnpenny et al. 2000). Although there is concern that small, fragile fish early life stages may be unable to avoid being struck by the blades of hydrokinetic turbines, we found no empirical data in the published literature that document survival of earliest life-stage fish in passage by rotor blades. In addition to blade strike, research on passage of fish through conventional hydropower turbines suggested that fish mortalities from passage through the rotor swept area could also occur due to shear stresses and pressure chances in the water column (Cada et al. 1997, Turnpenny 1998). However, for most of the proposed HK turbine designs the rotors are projected to operate a lower RPM (revolutions per minute) than observed from conventional reaction turbines; the associated shear stress and pressure changes are expected to be lower and pose a smaller threat to fish survival (DOE 2009). Only a limited number of studies have been conducted to examine the risk of blade strike from hydrokinetic technologies to fish (Turnpenny et al. 1992, Normandeau et al. 2009, Seitz et al. 2011, EPRI 2011); the survival of drifting or weakly swimming fish (especially early life stages) that encounter rotor blades from hydrokinetic (HK) devices is currently unknown. Our study addressed this knowledge gap by testing how fish larvae and juveniles encountered different blade profiles of hydrokinetic devices and how such encounters influenced survivorship. We carried out a laboratory study designed to improve our understanding of how fish larvae and juvenile fish may be affected by encounters with rotor blades from HK turbines in the water column of river and ocean currents. (For convenience, these early life stages will be referred to as young of the year, YOY). The experiments developed information needed to quantify the risk (both probability and consequences) of rotor-blade strike to YOY fish. In particular, this study attempted to determine whether YOY drifting in a high-velocity flow directly in the path of the blade leading edge will make contact with the rotor blade or will bypass the blade while entrained in the boundary l

  11. Method for forming gold-containing catalyst with porous structure

    SciTech Connect (OSTI)

    Biener, Juergen; Hamza, Alex V; Baeumer, Marcus; Schulz, Christian; Jurgens, Birte; Biener, Monika M.

    2014-07-22

    A method for forming a gold-containing catalyst with porous structure according to one embodiment of the present invention includes producing a starting alloy by melting together of gold and at least one less noble metal that is selected from the group consisting of silver, copper, rhodium, palladium, and platinum; and a dealloying step comprising at least partial removal of the less noble metal by dissolving the at least one less noble metal out of the starting alloy. Additional methods and products thereof are also presented.

  12. Gutierrez and Orsi, eds.: Contested Eden: California Before the Gold Rush

    E-Print Network [OSTI]

    Farris, Glenn J.

    1999-01-01

    the Gold Rush. Ramon A. Gutierrez and Richard J. Orsi, eds.of Califomia histoty. Gutierrez then sets about introducing

  13. Blue and Gold Society Please Submit requests at least two weeks prior

    E-Print Network [OSTI]

    Jiang, Huiqiang

    Blue and Gold Society Please Submit requests at least two weeks prior to your event date Today: ____________________________ ___________________________________________ ___________________________________________ ___________________________________________ Assistance Required Number of Blue and Gold members needed: _______ Arrival Time: __: __ Departing Time: __: __ Blue and Gold Society attire: Formal (suit) Casual (rugby shirt) Other Any Additional Information

  14. welcome to university residences Boiler Gold Rush Check-In...........................Saturday, August 13 and

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    welcome to university residences #12;Boiler Gold Rush Check-In...........................Saturday, August 13 and Sunday, August 14, 2011 Boiler Gold Rush residence hall systems in the United States. weLcomE! 1 #12;Boiler GoLD Rush ParticiPants Your regular

  15. Formation and Characterization of Core Shell Structures on Nanoporous Gold

    E-Print Network [OSTI]

    Collins, Gary S.

    characteristics. Methods To obtain a layer of nickel on the NPG, electroplating in a Watts bath was the best of the nickel plated NPG for reference. 300 nm dealloyed gold ­ basis for plating Electroplating A 250 mL Watts in the calculated time. A nickel rod acted as the cathode. Because electroplating can sometimes not be as uniform

  16. Preparation and Characterization of Polyelectrolyte-Coated Gold Nanoparticles

    E-Print Network [OSTI]

    Barrett, Christopher

    . Consequently, poor polymer coverage can decrease the stability of colloidal suspensions required for many sulfonate) (PSS) via electrostatic self-assembly. The suspension stability, monitored by the gold surface. These differences in stability of the multilayer components and the nanoparticle suspension are rationalized

  17. Sustained Storage and Transport of Hydraulic Gold Mining Sediment

    E-Print Network [OSTI]

    James, L. Allan

    Sustained Storage and Transport of Hydraulic Gold Mining Sediment in the Bear River, California L- sic model of sediment transport in a symmet- rical wave that is based on hydraulic mining sediment primarily in the Yuba Basin. Sus- tained storage and transport of hydraulic min- ing sediment in the Bear

  18. Evaluation of Hypervelocity Gold Nanoparticles for Nanovolume Surface Mass Spectrometry 

    E-Print Network [OSTI]

    DeBord, John 1986-

    2012-08-16

    Impacts of high kinetic energy massive gold clusters (~ 500 keV Au400+4) exhibit significantly enhanced secondary ion yields relative to traditional atomic or polyatomic primary ions (e.g. Au3 and C60). The one-of-a-kind instrument used to generate...

  19. Enhanced radiative heat transfer between nanostructured gold plates

    E-Print Network [OSTI]

    R. Guérout; J. Lussange; F. S. S. Rosa; J. -P. Hugonin; D. A. R. Dalvit; J. -J. Greffet; A. Lambrecht; S. Reynaud

    2012-03-07

    We compute the radiative heat transfer between nanostructured gold plates in the framework of the scattering theory. We predict an enhancement of the heat transfer as we increase the depth of the corrugations while keeping the distance of closest approach fixed. We interpret this effect in terms of the evolution of plasmonic and guided modes as a function of the grating's geometry.

  20. Penetration Experiments with 6061-T6511 Aluminum Targets and Spherical-Nose Steel Projectiles at Striking Velocities Between 0.5 and 3.0 km/s

    SciTech Connect (OSTI)

    Forrestal, M.J.; Piekutowski, A.J.

    1999-02-04

    We conducted depth of penetration experiments with 7.11-mm-diameter, 74.7-mm-long, spherical-nose, 4340 steel projectiles launched into 250-mm-diameter, 6061-T6511 aluminum targets. To show the effect of projectile strength, we used projectiles that had average Rockwell harnesses of R{sub c} = 36.6, 39.5, and 46.2. A powder gun and two-stage, light-gas guns launched the 0.023 kg projectiles at striking velocities between 0.5 and 3.0 km/s. Post-test radiographs of the targets showed three response regions as striking velocities increased: (1) the projectiles remained visibly undeformed, (2) the projectiles permanently deformed without erosion, and (3) the projectiles eroded and lost mass. To show the effect of projectile strength, we compared depth-of-penetration data as a function of striking velocity for spherical-nose rods with three Rockwell harnesses at striking velocities ranging from 0.5 to 3.0 km/s. To show the effect of nose shape, we compared penetration data for the spherical-nose projectiles with previously published data for ogive-nose projectiles.

  1. The effect of a carbon-nanotube forest-mat strike face on the ballistic-protection performance of E-glass

    E-Print Network [OSTI]

    Grujicic, Mica

    -ester-epoxy (PVEE)-matrix composite mats. This approach is applied to improving the ballistic-protection performance on the in-plane and the through-the-thickness properties of fibre-mat/polymer-matrix composite materials the potential of a hybrid armour consisting of a hard ceramic strike face and a thin ductile composite backing

  2. AlongStrike Seismic Structure of the Northern Volcanic Zone, Iceland William Menke (1,2), Michael West (1,2), Brynds Brandsdttir (3) and David Sparks (1)

    E-Print Network [OSTI]

    Menke, William

    1 Along­Strike Seismic Structure of the Northern Volcanic Zone, Iceland William Menke (1 Insitute, University of Iceland, Reykjavík, Iceland (Revised for Geophysical Journal International) SUMMARY Seismic data from the B96 array in northern Iceland are used to constrain the compressional and shear

  3. A comparative study of nano-scale coatings on gold electrodes for bioimpedance studies of breast cancer cells

    E-Print Network [OSTI]

    Heflin, Randy

    with that of gold microelectrodes coated with gold nanoparticles, carbon nanotubes, or electroplated gold to inA comparative study of nano-scale coatings on gold electrodes for bioimpedance studies of breast- troduce nano-scale roughness on the surface of the electrodes. For biological solutions, the electroplated

  4. Problems #9, Math 5737/Econ 5337. Oct 14, 2015. Due Oct 28, 1 pm. 51. Find the stock price on the exercise date for a European put with strike price $36

    E-Print Network [OSTI]

    Bohner, Martin

    Problems #9, Math 5737/Econ 5337. Oct 14, 2015. Due Oct 28, 1 pm. 51. Find the stock price on the exercise date for a European put with strike price $36 and exercise date in three months to produce gain (or loss) for a holder of a European call with strike price $90 to be exercised in six months

  5. Method of making gold thiolate and photochemically functionalized microcantilevers

    DOE Patents [OSTI]

    Boiadjiev, Vassil I. (Knoxville, TN) [Knoxville, TN; Brown, Gilbert M. (Knoxville, TN) [Knoxville, TN; Pinnaduwage, Lal A. (Knoxville, TN) [Knoxville, TN; Thundat, Thomas G. (Knoxville, TN) [Knoxville, TN; Bonnesen, Peter V. (Knoxville, TN) [Knoxville, TN; Goretzki, Gudrun (Nottingham, GB) [Nottingham, GB

    2009-08-25

    Highly sensitive sensor platforms for the detection of specific reagents, such as chromate, gasoline and biological species, using microcantilevers and other microelectromechanical systems (MEMS) whose surfaces have been modified with photochemically attached organic monolayers, such as self-assembled monolayers (SAM), or gold-thiol surface linkage are taught. The microcantilever sensors use photochemical hydrosilylation to modify silicon surfaces and gold-thiol chemistry to modify metallic surfaces thereby enabling individual microcantilevers in multicantilever array chips to be modified separately. Terminal vinyl substituted hydrocarbons with a variety of molecular recognition sites can be attached to the surface of silicon via the photochemical hydrosilylation process. By focusing the activating UV light sequentially on selected silicon or silicon nitride hydrogen terminated surfaces and soaking or spotting selected metallic surfaces with organic thiols, sulfides, or disulfides, the microcantilevers are functionalized. The device and photochemical method are intended to be integrated into systems for detecting specific agents including chromate groundwater contamination, gasoline, and biological species.

  6. Long-range memory and multifractality in gold markets

    E-Print Network [OSTI]

    Mali, Provash

    2015-01-01

    Long-range correlation and fluctuation in the gold market time series of world's two leading gold consuming countries, namely China and India, are studied. For both the market series during the period 1985-2013 we observe a long-range persistence of memory in the sequences of maxima (minima) of returns in successive time windows of fixed length, but the series as a whole are found to be uncorrelated. Multifractal analysis for these series as well as for the sequences of maxima (minima) is carried out in terms of the multifractal detrended fluctuation analysis (MF-DFA) method. We observe a weak multifractal structure for the original series that is mainly originated from the fat-tailed probability distribution function of the values, and the multifractal nature of the original time series is enriched into their sequences of maximal (minimal) returns. A quantitative measure of multifractality is provided by using a set of "complexity parameters".

  7. Electron energy loss spectroscopy of gold nanoparticles on graphene

    SciTech Connect (OSTI)

    DeJarnette, Drew [Microelectronics and Photonics Graduate Program, University of Arkansas, Fayetteville, Arkansas 72701 (United States); Roper, D. Keith, E-mail: dkroper@uark.edu [Microelectronics and Photonics Graduate Program, University of Arkansas, Fayetteville, Arkansas 72701 (United States); Department of Chemical Engineering, University of Arkansas, Fayetteville, Arkansas 72701 (United States)

    2014-08-07

    Plasmon excitation decay by absorption, scattering, and hot electron transfer has been distinguished from effects induced by incident photons for gold nanoparticles on graphene monolayer using electron energy loss spectroscopy (EELS). Gold nano-ellipses were evaporated onto lithographed graphene, which was transferred onto a silicon nitride transmission electron microscopy grid. Plasmon decay from lithographed nanoparticles measured with EELS was compared in the absence and presence of the graphene monolayer. Measured decay values compared favorably with estimated radiative and non-radiative contributions to decay in the absence of graphene. Graphene significantly enhanced low-energy plasmon decay, increasing mode width 38%, but did not affect higher energy plasmon or dark mode decay. This decay beyond expected radiative and non-radiative mechanisms was attributed to hot electron transfer, and had quantum efficiency of 20%, consistent with previous reports.

  8. Gold-based electrical interconnections for microelectronic devices

    DOE Patents [OSTI]

    Peterson, Kenneth A. (Albuquerque, NM); Garrett, Stephen E. (Albuquerque, NM); Reber, Cathleen A. (Corrales, NM); Watson, Robert D. (Tijeras, NM)

    2002-01-01

    A method of making an electrical interconnection from a microelectronic device to a package, comprising ball or wedge compression bonding a gold-based conductor directly to a silicon surface, such as a polysilicon bonding pad in a MEMS or IMEMS device, without using layers of aluminum or titanium disposed in-between the conductor and the silicon surface. After compression bonding, optional heating of the bond above 363 C. allows formation of a liquid gold-silicon eutectic phase containing approximately 3% (by weight) silicon, which significantly improves the bond strength by reforming and enhancing the initial compression bond. The same process can be used for improving the bond strength of Au--Ge bonds by forming a liquid Au-12Ge eutectic phase.

  9. Idaho National Engineering and Environmental Laboratory Awarded VPP Gold Star

    Broader source: Energy.gov [DOE]

    Our journey to safety excellence began some six (6) years ago. The task seemed ominous with 6000 plus employees ranging from administrative assistants and craftsman to research scientists and engineers. Another challenge was the geographic dispersion of work areas being as much as 50 miles apart. A core group of employees caught the vision and knew that it could be done, and it is that perseverance that has lead the INEEL to the DOE-VPP Gold Star.

  10. Gold Binding by Native and Chemically Modified Hops Biomasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    López, M. Laura; Gardea-Torresdey, J. L.; Peralta-Videa, J. R.; de la Rosa, G.; Armendáriz, V.; Herrera, I.; Troiani, H.; Henning, J.

    2005-01-01

    Heavy metals from mining, smelting operations and other industrial processing facilities pollute wastewaters worldwide. Extraction of metals from industrial effluents has been widely studied due to the economic advantages and the relative ease of technical implementation. Consequently, the search for new and improved methodologies for the recovery of gold has increased. In this particular research, the use of cone hops biomass ( Humulus lupulus ) was investigated as a new option for gold recovery. The results showed that the gold binding to native hops biomass was pH dependent from pH 2 to pH 6, with a maximum percentage bindingmore »at pH 3. Time dependency studies demonstrated that Au(III) binding to native and modified cone hops biomasses was found to be time independent at pH 2 while at pH 5, it was time dependent. Capacity experiments demonstrated that at pH 2, esterified hops biomass bound 33.4 mg Au/g of biomass, while native and hydrolyzed hops biomasses bound 28.2 and 12.0 mg Au/g of biomass, respectively. However, at pH 5 the binding capacities were 38.9, 37.8 and 11.4 mg of Au per gram of native, esterified and hydrolyzed hops biomasses, respectively. « less

  11. Secondary emission from synthetic opal infiltrated by colloidal gold and glycine

    E-Print Network [OSTI]

    Dovbeshko, G; Boyko, V; Romanyuk, V; Gorelik, V; Moiseyenko, V; Sobolev, V; Shvalagin, V

    2012-01-01

    A comparison of the secondary emission (photoluminescence) and Bragg reflection spectra of photonic crystals (PC), namely, synthetic opals, opals infiltrated by colloidal gold, glycine, and a complex of colloidal gold with glycine is performed. The infiltration of colloidal gold and a complex of colloidal gold with glycine into the pores of PC causes a short-wavelength shift (about 5-15 nm) of the Bragg reflection and increases the intensity of this band by 1.5-3 times. In photoluminescence, the infiltration of PC by colloidal gold and colloidal gold with glycine suppresses the PC emission band near 375-450 nm and enhances the shoulder of the stop-zone band of PC in the region of 470-510 nm. The shape of the observed PC emission band connected with defects in synthetic opal is determined by the type of infiltrates and the excitation wavelength. Possible mechanisms of the effects are discussed.

  12. Electrocatalysts having gold monolayers on platinum nanoparticle cores, and uses thereof

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang

    2010-04-27

    The invention relates to gold-coated particles useful as fuel cell electrocatalysts. The particles are composed of an electrocatalytically active core at least partially encapsulated by an outer shell of gold or gold alloy. The invention more particularly relates to such particles having a noble metal-containing core, and more particularly, a platinum or platinum alloy core. In other embodiments, the invention relates to fuel cells containing these electrocatalysts and methods for generating electrical energy therefrom.

  13. Structural Analysis for Gold Mineralization Using Remote Sensing and Geochemical Techniques in a GIS Environment: Island of Lesvos, Hellas

    SciTech Connect (OSTI)

    Rokos, D. Argialas, D. Mavrantza, R. St Seymour, K.; Vamvoukakis, C.; Kouli, M.; Lamera, S.; Paraskevas, H.; Karfakis, I.; Denes, G

    2000-12-15

    Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field data (dip and strike measurements of faults, joints, and veins), respectively. The derived lineament map and the band ratio images were manipulated in a GIS environment, in order to study the relation of the tectonic pattern to both the alteration zoning and the geomorphology of the volcanic field of the study area. Target areas of high interest for possible mineralization also were specified using geochemical techniques, such as X-Ray Diffraction (XRD) analysis, trace-element, and fluid-inclusion analysis. Finally, preliminary conclusions were derived about possible mineralization, the type (high or low sulfidation), and the extent of mineralization, by combining the structural information with geochemical information.

  14. New chemistry with gold-nitrogen complexes: synthesis and characterization of tetra-, tri-, and dinuclear gold(I) amidinate complexes. Oxidative-addition to the dinuclear gold(I) amidinate 

    E-Print Network [OSTI]

    Abdou, Hanan Elsayed

    2009-06-02

    Nitrogen ligands have been little studied with gold(I) and almost no chemistry has been described using anionic bridging nitrogen ligands. This dissertation concerns the impact of the bridging ligands amidinate, ArNHC(H)NAr, ...

  15. Energy loss of coasting gold ions and deuterons in RHIC.

    SciTech Connect (OSTI)

    Abreu,N.; Blaskiewicz, M.; Brown, K.A.; Butler, J.J.; FischW; Harvey, M.; Tepikian, S.

    2008-06-23

    The total energy loss of coasting gold ion beams was measured at RHIC at two energies, corresponding to a gamma of 75.2 and 107.4. We describe the experiment and observations and compare the measured total energy loss with expectations from ionization losses at the residual gas, the energy loss due to impedance and synchrotron radiation. We find that the measured energy losses are below what is expected from free space synchrotron radiation. We believe that this shows evidence for suppression of synchrotron radiation which is cut off at long wavelength by the presence of the conducting beam pipe.

  16. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Lowï‚— WeUpdate JonGuided Self-Assembly of Gold Thin

  17. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Lowï‚— WeUpdate JonGuided Self-Assembly of Gold

  18. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Lowï‚— WeUpdate JonGuided Self-Assembly of GoldGuided

  19. MASKLESS ELECTROCHEMICAL PATTERNING OF GOLD FILMS FOR BIOSENSORS USING MICROMACHINED POLYIMIDE PROBES

    E-Print Network [OSTI]

    Basu, Amar S.

    MASKLESS ELECTROCHEMICAL PATTERNING OF GOLD FILMS FOR BIOSENSORS USING MICROMACHINED POLYIMIDE chemicals for chemical and biosensors. After gold patterns are revealed, the surface can be treated] and proteins [8] can be selectively attached to the SAMs and used in biosensor applications as depicted in Fig

  20. Molecularly Resolved Images of Peptide-Functionalized Gold Surfaces by Scanning Tunneling Microscopy

    E-Print Network [OSTI]

    Webb, Lauren J.

    propargylglycine unnatural functional groups 20 Å apart and an alkanethiol self-assembled monolayer (SAM) on a gold-terminated surfaces in which a structured -helical peptide is chemically bonded to an alkanethiol self-assembledMolecularly Resolved Images of Peptide-Functionalized Gold Surfaces by Scanning Tunneling

  1. Sol immobilization technique: a delicate balance between activity, selectivity and stability for gold catalyst

    SciTech Connect (OSTI)

    Villa, Alberto [Universita di Milano, Italy] [Universita di Milano, Italy; Wang, Di [Fritz Haber Institute of the Max Planck Society, Berlin, Germany] [Fritz Haber Institute of the Max Planck Society, Berlin, Germany; Veith, Gabriel M [ORNL] [ORNL; Prati, Laura [Universita di Milano, Italy] [Universita di Milano, Italy

    2013-01-01

    Sol immobilization is a widely used method to prepare gold catalysts. The presence of the protective layer can have a significant influence on catalyst properties by mediating metal-support and reactantmetal interactions. This paper details the effect of a polyvinyl alcohol (PVA) protecting groups on the activity of a supported gold catalysts as well as its selectivity towards glycerol oxidation.

  2. Gold mining and the golden rule: a challenge for producers and consumers in developing countries

    E-Print Network [OSTI]

    Vermont, University of

    ; accepted 17 May 2004 Available online 23 May 2005 Abstract The environmental and social impact of gold environmental impacts, they must also evaluate their own consumption patterns of gold. This paper explores-year process of self-evaluation to assess progress towards sustainable development in a report entitled

  3. Synthesis, structure and spectroscopic investigations of luminescent heterobimetallic gold(I)-Rhodium(I) species

    E-Print Network [OSTI]

    Dempsey, Jillian Lee

    2005-01-01

    A novel, three-coordinate gold(I) dimer, Au2(tfepm)3Cl2 (la, lb), was synthesized and structurally characterized. Four gold(I)-rhodium(I) heterobimetallic complexes, AuIRh'(tBuNC)2(-dppm)2C12 (2), Au'Rh'(tBuNC)2(u-dmpm)2Cl2 ...

  4. Hydroxyalkyl phosphine gold complexes for use as diagnostic and therapeutic pharmaceuticals and method of making same

    DOE Patents [OSTI]

    Katti, K.V.; Berning, D.E.; Volkert, W.A.; Ketring, A.R.

    1998-12-01

    A complex and method for making a diagnostic or therapeutic pharmaceutical includes a ligand comprising at least one hydroxyalkyl phosphine donor group bound to a gold atom to form a gold-ligand complex that is stable in aqueous solutions containing oxygen, serum and other body fluids. 20 figs.

  5. PHYSICAL REVIEW B 86, 195418 (2012) Gold-embedded zigzag graphene nanoribbons as spin gapless semiconductors

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    2012-01-01

    PHYSICAL REVIEW B 86, 195418 (2012) Gold-embedded zigzag graphene nanoribbons as spin gapless semiconductors Xiaohui Hu,1 Wei Zhang,2 Litao Sun,1,* and Arkady V. Krasheninnikov3,4 1 SEU-FEI Nano-Pico Center properties of zigzag graphene nanoribbons (ZGNRs) with gold (Au) atoms embedded into different sites

  6. Magnetron sputtering of gold nanoparticles onto WO3 and activated carbon

    E-Print Network [OSTI]

    Pennycook, Steve

    Magnetron sputtering of gold nanoparticles onto WO3 and activated carbon Gabriel M. Veith a and investigation of two supported gold catalyst systems prepared by magnetron sputtering: Au on WO3 and Au, such as WO3 and carbon, which are generally not accessible using the ubiquitous deposition

  7. ANNEALING EFFECTS ON INTERFACIAL FRACTURE OF GOLD-CHROMIUM FILMS IN HYBRID MICROCIRCUITS

    E-Print Network [OSTI]

    Volinsky, Alex A.

    ANNEALING EFFECTS ON INTERFACIAL FRACTURE OF GOLD-CHROMIUM FILMS IN HYBRID MICROCIRCUITS N. R on the resistance to interfacial fracture of gold-chromium films in hybrid microcircuits. The samples were prepared, interfacial fracture energies were determined using mechanics-based models modified for multilayer film

  8. Melting, freezing, and coalescence of gold nanoclusters Laurent J. Lewis, (a) Pablo Jensen, and JeanLouis Barrat

    E-Print Network [OSTI]

    Lewis, Laurent J.

    Melting, freezing, and coalescence of gold nanoclusters Laurent J. Lewis, (a) Pablo Jensen We present a detailed molecular­dynamics study of the melting, freezing, and coalescence of gold to address two issues. First, we investigate the influence of size on the melting and freezing of gold

  9. Contact voltage-induced softening of RF microelectromechanical system gold-on-gold contacts at cryogenic temperatures

    SciTech Connect (OSTI)

    Berman, D.; Krim, J. [Department of Physics, North Carolina State University, Raleigh, North Carolina 26795 (United States); Walker, M. J. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 26795 (United States)

    2010-08-15

    A series of experiments were performed in vacuum environments to investigate the impact of rf micromechanical system switch contact voltage versus resistance for gold-on-gold contacts at cryogenic temperatures. The purpose of this work was twofold as follows: (1) to examine whether asperity heating models already validated for high temperature contacts were also applicable at cryogenic temperatures and (2) to explore the implications and validity of prior suggestions that contact temperatures between 338 and 373 K are high enough to dissociate adsorbed film and/or push them aside but low enough to prevent asperities from becoming soft and adherent. Measurements on two distinct switch types, fabricated at independent laboratories, were performed in the temperature range 79-293 K and for contact voltages ranging from 0.01 to 0.13 V. Contact resistance values at all temperatures were observed to be lower for higher contact voltages, consistent with the aforementioned asperity heating models, whereby increased contact currents are associated with increased heating and softening effects. In situ removal of adsorbed species by oxygen plasma cleaning resulted in switch adhesive failure. Switches that had not been cleaned meanwhile exhibited distinct reductions in resistance at contact temperatures close to 338 K, consistent with suggestions that films begin to desorb, disassociate, and/or be pushed aside at that temperature.

  10. Modeling pore corrosion in normally open gold- plated copper connectors.

    SciTech Connect (OSTI)

    Battaile, Corbett Chandler; Moffat, Harry K.; Sun, Amy Cha-Tien; Enos, David George; Serna, Lysle M.; Sorensen, Neil Robert

    2008-09-01

    The goal of this study is to model the electrical response of gold plated copper electrical contacts exposed to a mixed flowing gas stream consisting of air containing 10 ppb H{sub 2}S at 30 C and a relative humidity of 70%. This environment accelerates the attack normally observed in a light industrial environment (essentially a simplified version of the Battelle Class 2 environment). Corrosion rates were quantified by measuring the corrosion site density, size distribution, and the macroscopic electrical resistance of the aged surface as a function of exposure time. A pore corrosion numerical model was used to predict both the growth of copper sulfide corrosion product which blooms through defects in the gold layer and the resulting electrical contact resistance of the aged surface. Assumptions about the distribution of defects in the noble metal plating and the mechanism for how corrosion blooms affect electrical contact resistance were needed to complete the numerical model. Comparisons are made to the experimentally observed number density of corrosion sites, the size distribution of corrosion product blooms, and the cumulative probability distribution of the electrical contact resistance. Experimentally, the bloom site density increases as a function of time, whereas the bloom size distribution remains relatively independent of time. These two effects are included in the numerical model by adding a corrosion initiation probability proportional to the surface area along with a probability for bloom-growth extinction proportional to the corrosion product bloom volume. The cumulative probability distribution of electrical resistance becomes skewed as exposure time increases. While the electrical contact resistance increases as a function of time for a fraction of the bloom population, the median value remains relatively unchanged. In order to model this behavior, the resistance calculated for large blooms has been weighted more heavily.

  11. Polyvalent Oligonucleotide Gold Nanoparticle Conjugates as Delivery Vehicles for Platinum(IV) Warheads

    E-Print Network [OSTI]

    Dhar, Shanta

    Amine-functionalized polyvalent oligonucleotide gold nanoparticles (DNA-Au NPs) were derivatized with a cisplatin prodrug, and the resulting DNA-Au NP conjugates were used to internalize multiple platinum centers. A ...

  12. Synthesis, characterization and assembly of the binary ligand protected gold nanoparticles

    E-Print Network [OSTI]

    Kim, Hyewon, Ph. D. Massachusetts Institute of Technology

    2013-01-01

    When a gold nanoparticle is coated with two dislike ligands, the ligands selfassemble on the nanoparticle surface and the phase separation occurs based on the miscibility and the size mismatch of two ligands, and the sizes ...

  13. Ultrasensitive Optical Shape Characterization of Gold Nanoantennas Using Second Harmonic Generation

    E-Print Network [OSTI]

    Dalang, Robert C.

    Ultrasensitive Optical Shape Characterization of Gold Nanoantennas Using Second Harmonic Generation for the sensitive optical characterization of plasmonic nanostructures. Furthermore, defects located where on the second harmonic signal. KEYWORDS: Plasmonics, nonlinear optics, surface integral formulation, realistic

  14. Effects of varying ethanol and water concentrations as a gold nanoparticle gel solvent

    E-Print Network [OSTI]

    Schaefer, Thomas Gerard

    2009-01-01

    Striped gold nanoparticles are unique in several of their characteristics and applications. Recent experiments have determined a new medium with which contain the nanoparticles is that of a chemical gel. The nanoparticles ...

  15. Syntheses and characterizations of homovalent and heterovalent dinuclear gold ylide metallocycles 

    E-Print Network [OSTI]

    Neitling, David Christopher

    1995-01-01

    Homovalent and heterovalent derivatives of the gold ylide metallocycle (Au[4(CH2)2PPh2l ) 2(l) have been synthesized. Substitution reactions with the potentially bidentate ligands methylenediphenylthiophosphinate (mtp) and diphenyldithio...

  16. An Archaeological Survey of Suemaur Exploration & Production, LLC's Lafitte's Gold Prospect in Galveston County, Texas 

    E-Print Network [OSTI]

    Moore, William

    2015-07-30

    An archaeological survey of Suemaur Exploration & Production, LLC’s Lafitte’s Gold Prospect was conducted on February 25, 2008 by BVRA in eastern Galveston County, Texas with negative results. The investigation examined a proposed drill site...

  17. Art versus politics: Mike Gold, Joseph Freeman, and literary radicalism in the 1920s 

    E-Print Network [OSTI]

    Starr, Clinton Robert

    1997-01-01

    In the 1920s, when there was little support for left wing writers from either the Communist Party or the broader intellectual community, literary intellectuals Mike Gold and Joseph Freeman attempted to use their writing to further the revolutionary...

  18. Gold Nanoparticles Functionalised with Fast Water Exchanging Gd3+ Chelates: Linker Effects on the Relaxivity

    E-Print Network [OSTI]

    Ferreira, Miguel F.; Gonçalves, Janaina; Mousavi, B.; Prata, M. I. M.; Rodrigues, S. P. J.; Calle, Daniel; López-Larrubia, Pilar; Cerdan, Sebastian; Rodrigues, Tiago B.; Ferreira, Paula M.; Helm, L.; Martins, José A.; Geraldes, Carlos F. G. C.

    2015-01-22

    The relaxivity displayed by Gd3+ chelates immobilized onto gold nanoparticles is the result of complex interplay between nanoparticle size, water exchange rate and chelate structure. In this work we study the effect of the length of ?...

  19. Improved thermal stability of oxide-supported naked gold nanoparticles by ligand-assisted pinning

    SciTech Connect (OSTI)

    Moreno, C; Divins, N. J.; Gazquez, Jaume; Varela, Maria; Angurell, I; Llorca, J

    2012-01-01

    We report a method to improve the thermal stability, up to 900 C, of bare-metal (naked) gold nanoparticles supported on top of SiO{sub 2} and SrTiO{sub 3} substrates via ligand-assisted pinning. This approach leads to monodisperse naked gold nanoparticles without significant sintering after thermal annealing in air at 900 C. The ligand-assisted pinning mechanism is described.

  20. Noble Metal Catalysts for Mercury Oxidation in Utility Flue Gas: Gold, Palladium and Platinum Formulations

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J

    2008-07-01

    The use of noble metals as catalysts for mercury oxidation in flue gas remains an area of active study. To date, field studies have focused on gold and palladium catalysts installed at pilot scale. In this article, we introduce bench-scale experimental results for gold, palladium and platinum catalysts tested in realistic simulated flue gas. Our initial results reveal some intriguing characteristics of catalytic mercury oxidation and provide insight for future research into this potentially important process.

  1. Excitation and Far field Spectroscopy of surface plasmons in Gold nanostructures 

    E-Print Network [OSTI]

    Peng, Siying

    2011-08-08

    -1 EXCITATION AND FAR FIELD SPECTROSCOPY OF SURFACE PLASMONS IN GOLD NANOSTRUCTURES Major: Physics and Mathematics April 2010 Submitted to the Honors Programs Office Texas A&M University in partial fulfillment of the requirements for the designation... as HONORS UNDERGRADUATE RESEARCH FELLOW An Honors Fellows Thesis by SIYING PENG EXCITATION AND FAR FIELD SPECTROSCOPY OF SURFACE PLASMONS IN GOLD NANOSTRUCTURES Approved by: Research Advisor...

  2. Radiation induced effects on mechanical properties of nanoporous gold foams

    SciTech Connect (OSTI)

    Caro, M., E-mail: magda@lanl.gov, E-mail: efu@pku.edu.cn; Fu, E. G., E-mail: magda@lanl.gov, E-mail: efu@pku.edu.cn; Wang, Y. Q.; Martinez, E.; Caro, A. [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Mook, W. M.; Sheehan, C.; Baldwin, J. K. [Center for Integrated Nanotechnology, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2014-06-09

    It has recently been shown that due to a high surface-to-volume ratio, nanoporous materials display radiation tolerance. The abundance of surfaces, which are perfect sinks for defects, and the relation between ligament size, defect diffusion, and time combine to define a window of radiation resistance [Fu et al., Appl. Phys. Lett. 101, 191607 (2012)]. Outside this window, the dominant defect created by irradiation in Au nanofoams are stacking fault tetrahedra (SFT). Molecular dynamics computer simulations of nanopillars, taken as the elemental constituent of foams, predict that SFTs act as dislocation sources inducing softening, in contrast to the usual behavior in bulk materials, where defects are obstacles to dislocation motion, producing hardening. In this work we test that prediction and answer the question whether irradiation actually hardens or softens a nanofam. Ne ion irradiations of gold nanofoams were performed at room temperature for a total dose up to 4 dpa, and their mechanical behavior was measured by nanoindentation. We find that hardness increases after irradiation, a result that we analyze in terms of the role of SFTs on the deformation mode of foams.

  3. World's Largest Gold Crystal Studied at Los Alamos

    ScienceCinema (OSTI)

    Vogel, Sven; Nakotte, Heinz

    2015-01-07

    When geologist John Rakovan needed better tools to investigate whether a dazzling 217.78-gram piece of gold was in fact the world's largest single-crystal specimen - a distinguishing factor that would not only drastically increase its market value but also provide a unique research opportunity - he traveled to Los Alamos National Laboratory's Lujan Neutron Scattering Center to peer deep inside the mineral using neutron diffractometry. Neutrons, different from other probes such as X-rays and electrons, are able to penetrate many centimeters deep into most materials. Revealing the inner structure of a crystal without destroying the sample - imperative, as this one is worth an estimated $1.5 million - would allow Rakovan and Lujan Center collaborators Sven Vogel and Heinz Nakotte to prove that this exquisite nugget, which seemed almost too perfect and too big to be real, was a single crystal and hence a creation of nature. Its owner, who lives in the United States, provided the samples to Rakovan to assess the crystallinity of four specimens, all of which had been found decades ago in Venezuela.

  4. Structure of incommensurate gold sulfide monolayer on Au(111)

    SciTech Connect (OSTI)

    Quek, S Y; Biener, M M; Biener, J; Bhattacharjee, J; Friend, C M; Waghmare, U V; Kaxiras, E

    2006-10-04

    Two-dimensional confined systems, such as substrate-supported incommensurate layers, are of interest because their structural and electronic properties may differ from those of bulk materials. While advances in experimental techniques have resulted in the growth of many such interesting systems, progress can often be hampered by the lack of an atomistic-scale understanding of the structure, especially for incommensurate systems. In this work, we develop an atomic-scale model for an ordered incommensurate gold-sulfide (AuS) adlayer that has been previously demonstrated to exist on the Au(111) surface, following sulfur deposition and annealing to 450 K. We introduce theoretical techniques within density functional theory to take into account charge transfer in an incommensurate system and model scanning tunneling microscopy images, which are in good agreement with experiment. Our simulations indicate that this model is remarkably robust. We analyze the nature of bonding in this structure using state-of-the-art Wannier-function based techniques. Our analysis provides a natural explanation for the extraordinary robustness and unusual stoichiometry of this layer. This structure and its chemistry have implications for related S-Au interfaces, such as those in self-assembled monolayers of thiols on Au substrates.

  5. Geometric effect on surface enhanced Raman scattering of nanoporous gold: Improving Raman scattering by tailoring ligament and nanopore ratios

    SciTech Connect (OSTI)

    Lang, X. Y.; Chen, L. Y.; Guan, P. F.; Fujita, T.; Chen, M. W. [WPI Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2009-05-25

    We have synthesized nanoporous gold (NPG) films with a nanostructure consisting of small nanopores and large gold ligaments by the combination of chemical dealloying and electroless plating. The NPG films exhibit dramatic improvement in surface enhanced Raman scattering (SERS) in comparison with the conventional NPG. The superior SERS effect of the NPG films results from the confluence effect of enhanced local surface plasmon fields and electromagnetic coupling between ligaments, as well as the weak plasmon damping with increasing gold ligament sizes.

  6. Effect of particle size on the thermo-optic properties of gold nanofluids – A thermal lens study

    SciTech Connect (OSTI)

    Kumar, B. Rajesh; Basheer, N. Shemeena; Kurian, Achamma [Photonics Lab, Department of Physics, Catholicate College, Pathanamthitta (India); George, Sajan D., E-mail: sajan.george@manipal.edu [Centre for Atomic and Molecular Physics, Manipal University, Manipal, Karnataka (India)

    2014-01-28

    Spherical gold nanoparticles having particle size in the range 30 to 50 nm are prepared using citrate reduction of gold chloride trihydrate in water. The influence of particle size on the thermal diffusivity value of gold nanofluid is measured using dual beam thermal lens technique. The present study shows that the particle size influences the effective thermal diffusivity value of the nanofluid substantially and the value decreases with decrease in particle size for the investigated samples.

  7. Audio Speech Segmentation Without Language-Specific Knowledge Kevin Gold (kevin.gold@yale.edu) and Brian Scassellati (scaz@cs.yale.edu)

    E-Print Network [OSTI]

    Scassellati, Brian

    that it warrants a kind of "mental shorthand." The new entry is only added if the cost of storage is less than.gold@yale.edu) and Brian Scassellati (scaz@cs.yale.edu) Department of Computer Science, 51 Prospect Street New Haven, CT together until the cepstral coefficient variance is low within each new seg- ment. These segments

  8. Synthesis and Characterization of Gold Clusters Ligated with 1,3-Bis(dicyclohexylphosphino)propane

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2013-09-01

    In this multidisciplinary study we combine chemical reduction synthesis of novel gold clusters in solution with high-resolution analytical mass spectrometry (MS) to gain insight into the composition of the gold clusters and how their size, ionic charge state and ligand substitution influences their gas-phase fragmentation pathways. Ultra small cationic gold clusters ligated with 1,3-bis(dicyclohexylphosphino)propane (DCPP) were synthesized for the first time and introduced into the gas phase using electrospray ionization (ESI). Mass-selected cluster ions were fragmented employing collision induced dissociation (CID) and the product ions were analysed using MS. The solutions were found to contain the multiply charged cationic gold clusters Au9L43+, Au13L53+, Au6L32+, Au8L32+ and Au10L42+ (L = DCPP). The gas-phase fragmentation pathways of these cluster ions were examined systematically employing CID combined with MS. In addition, CID experiments were performed on related gold clusters of the same size and ionic charge state but capped with 1,3-bis(diphenylphosphino)propane (DPPP) ligands containing phenyl functional groups at the two phosphine centers instead of cyclohexane rings. It is shown that this relatively small change in the molecular substitution of the two phosphine centers in diphosphine ligands (C6H11 versus C6H5) exerts a pronounced influence on the size of the species that are preferentially formed in solution during reduction synthesis as well as the gas-phase fragmentation channels of otherwise identical gold cluster ions. The mass spectrometry results indicate that in addition to the length of the alkyl chain between the two phosphine centers, the substituents at the phosphine centers also play a crucial role in determining the composition, size and stability of diphosphine ligated gold clusters synthesized in solution.

  9. The Genomes On Line Database (GOLD) in 2009: status of genomic and metagenomic projects and their associated metadata

    SciTech Connect (OSTI)

    Liolios, Konstantinos; Chen, Amy; Mavromatis, Konstantinos; Tavernarakis, Nektarios; Hugenholtz, Phil; Markowitz, Victor; Kyrpides, Nikos C.

    2009-09-01

    The Genomes On Line Database (GOLD) is a comprehensive resource for centralized monitoring of genome and metagenome projects worldwide. Both complete and ongoing projects, along with their associated metadata, can be accessed in GOLD through precomputed tables and a search page. As of September 2009, GOLD contains information for more than 5800 sequencing projects, of which 1100 have been completed and their sequence data deposited in a public repository. GOLD continues to expand, moving toward the goal of providing the most comprehensive repository of metadata information related to the projects and their organisms/environments in accordance with the Minimum Information about a (Meta)Genome Sequence (MIGS/MIMS) specification.

  10. Charge Retention by Gold Clusters on Surfaces Prepared Using Soft Landing of Mass Selected Ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2012-01-24

    Monodisperse gold clusters have been prepared on surfaces in different charge states through soft landing of mass-selected ions. Ligand-stabilized gold clusters were prepared in methanol solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine complex in the presence of 1,3-bis(diphenylphosphino)propane. Electrospray ionization was used to introduce the clusters into the gas-phase and mass-selection was employed to isolate a single ionic cluster species (Au11L53+, L = 1,3-bis(diphenylphosphino)propane) which was delivered to surfaces at well controlled kinetic energies. Using in-situ time of flight secondary ion mass spectrometry (TOF-SIMS) it is demonstrated that the Au11L53+ cluster retains its 3+ charge state when soft landed onto the surface of a 1H,1H,2H,2H-

  11. Gold nanoparticles for cancer detection and treatment: The role of adhesion

    SciTech Connect (OSTI)

    Oni, Y. [Princeton Institute for Science and Technology of Materials (PRISM), Princeton University, 70 Prospect Street, Princeton, New Jersey 08544 (United States); Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Hao, K. [Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Dozie-Nwachukwu, S.; Odusanya, O. S. [African University of Science and Technology (AUST), Kilometer 10, Airport Road, Abuja, Federal Capital Territory (Nigeria); Sheda Science and Technology Complex (SHESTCO), Gwagwalada, Abuja, Federal Capital Territory (Nigeria); Obayemi, J.D. [African University of Science and Technology (AUST), Kilometer 10, Airport Road, Abuja, Federal Capital Territory (Nigeria); Anuku, N. [Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Department of Chemistry and Chemical Technology, Bronx Community College, New York, New York 10453 (United States); Soboyejo, W. O. [Princeton Institute for Science and Technology of Materials (PRISM), Princeton University, 70 Prospect Street, Princeton, New Jersey 08544 (United States); Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); African University of Science and Technology (AUST), Kilometer 10, Airport Road, Abuja, Federal Capital Territory (Nigeria)

    2014-02-28

    This paper presents the results of an experimental study of the effects of adhesion between gold nanoparticles and surfaces that are relevant to the potential applications in cancer detection and treatment. Adhesion is measured using a dip coating/atomic force microscopy (DC/AFM) technique. The adhesion forces are obtained for dip-coated gold nanoparticles that interact with peptide or antibody-based molecular recognition units (MRUs) that attach specifically to breast cancer cells. They include MRUs that attach specifically to receptors on breast cancer cells. Adhesion forces between anti-cancer drugs such as paclitaxel, and the constituents of MRU-conjugated Au nanoparticle clusters, are measured using force microscopy techniques. The implications of the results are then discussed for the design of robust gold nanoparticle clusters and for potential applications in localized drug delivery and hyperthermia.

  12. Effects of Metal Coating on Self-Assembled Monolayers on Gold. 1. Copper on Dodecanethiol and Octadecanethiol

    E-Print Network [OSTI]

    Myrick, Michael Lenn

    Effects of Metal Coating on Self-Assembled Monolayers on Gold. 1. Copper on Dodecanethiol on copper-coated SAMsconductedinourlaboratories.2 Inourpreviouswork, we fabricated gold-conjugated oligomer to characterize the SAM after the copper coating process. Prior studies on SAM/metal interfaces have been reported

  13. Calculation of the extinction cross section and lifetime of a gold nanoparticle using FDTD simulations

    SciTech Connect (OSTI)

    Radhakrishnan, Archana, E-mail: anju.archana@gmail.com [B.Tech, Engineering Physics, National Institute Of Technology, Calicut (India); Murugesan, Dr V., E-mail: murugesh@serc.iisc.in [Assistant Professor, Supercomputer Education and Research Centre, Indian Institute of Science, Bangalore (India)

    2014-10-15

    The electromagnetic theory of light explains the behavior of light in most of the domains quite accurately. The problem arises when the exact solution of the Maxwell's equation is not present, in case of objects with arbitrary geometry. To find the extinction cross-section and lifetime of the gold nanoparticle, the software FDTD solutions 8.6 by Lumerical is employed. The extinction cross-sections and lifetimes of Gold nanospheres of different sizes and arrangements are studied using pulse lengths of the order of femtoseconds. The decay constant and other properties are compared. Further, the lifetimes are calculated using frequency and time domain calculations.

  14. Gold-titania interface toughening and thermal conductance enhancement using an organophosphonate nanolayer

    SciTech Connect (OSTI)

    Chow, Philippe K.; O'Brien, Peter; Ramanath, Ganpati; Cardona Quintero, Y.; Ramprasad, R.; Hubert Mutin, P.; Lane, Michael

    2013-05-20

    We demonstrate that a mercaptan-terminated organophosphonate nanolayer at gold-titania interfaces can give rise to two- to three-fold enhancement in the interfacial fracture toughness and thermal conductance. Electron spectroscopy reveals that interfacial delamination occurs at the metal-molecule interface near the gold-sulfur bonds, consistent with density functional theory calculations of bond energies. Qualitative correlation between interfacial fracture toughness and bond energies suggest that organophosphonate nanolayers are resilient to humidity-induced degradation. These results, and the versatility of organophosphonates as surface functionalization agents for technologically relevant materials, unlock uncharted avenues for molecular engineering of interfaces in materials and devices for a variety of applications.

  15. Three-dimensional x-ray fluorescence mapping of a gold nanoparticle-loaded phantom

    SciTech Connect (OSTI)

    Ren, Liqiang; Wu, Di; Li, Yuhua; Liu, Hong, E-mail: liu@ou.edu [Center for Bioengineering and School of Electrical and Computer Engineering, University of Oklahoma, Norman, Oklahoma 73019 (United States)] [Center for Bioengineering and School of Electrical and Computer Engineering, University of Oklahoma, Norman, Oklahoma 73019 (United States); Wang, Ge [Biomedical Imaging Cluster and Department of Biomedical Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)] [Biomedical Imaging Cluster and Department of Biomedical Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Wu, Xizeng [Department of Radiology, University of Alabama, Birmingham, Alabama 35233 (United States)] [Department of Radiology, University of Alabama, Birmingham, Alabama 35233 (United States)

    2014-03-15

    Purpose : X-ray fluorescence (XRF) is a promising technique with sufficient specificity and sensitivity for identifying and quantifying features in small samples containing high atomic number (Z) materials such as iodine, gadolinium, and gold. In this study, the feasibility of applying XRF to early breast cancer diagnosis and treatment is studied using a novel approach for three-dimensional (3D) x-ray fluorescence mapping (XFM) of gold nanoparticle (GNP)-loaded objects in a physical phantom at the technical level. Methods : All the theoretical analysis and experiments are conducted under the condition of using x-ray pencil beam and a compactly integrated x-ray spectrometer. The penetrability of the fluorescence x-rays from GNPs is first investigated by adopting a combination of BR12 with 70 mm/50 mm in thickness on the excitation/emission path to mimic the possible position of tumor goldin vivo. Then, a physical phantom made of BR12 is designed to translate in 3D space with three precise linear stages and subsequently the step by step XFM scanning is performed. The experimental technique named as background subtraction is applied to isolate the gold fluorescence from each spectrum obtained by the spectrometer. Afterwards, the attenuations of both the incident primary x-ray beam with energies beyond the gold K-edge energy (80.725 keV) and the isolated gold K{sub ?} fluorescence x-rays (65.99 –69.80 keV) acquired after background subtraction are well calibrated, and finally the unattenuated K{sub ?} fluorescence counts are used to realize mapping reconstruction and to describe the linear relationship between gold fluorescence counts and corresponding concentration of gold solutions. Results : The penetration results show that the goldK{sub ?} fluorescence x-rays have sufficient penetrability for this phantom study, and the reconstructed mapping results indicate that both the spatial distribution and relative concentration of GNPs within the designed BR12 phantom can be well identified and quantified. Conclusions : Although the XFM method in this investigation is still studied at the technical level and is not yet practical for routinein vivo mapping tasks with GNPs, the current penetrability measurements and phantom study strongly suggest the feasibility to establish and develop a 3D XFM system.

  16. A review of "Full of Soup and Gold: The Life of Henry Jermyn" by Anthony Adolph 

    E-Print Network [OSTI]

    Maureen E. Mulvihill

    2007-01-01

    of the sites of production and the modes of transmission as part of understanding the poetics of the text and the dynamics of the period. Anthony Adolph. Full of Soup and Gold: The Life of Henry Jermyn. London: Anthony Adolph, 2006. Cloth. 324 pp., 31... Albans full of soup and gold, The new court?s pattern, stallion of the old. Him neither wit nor courage did exalt, But Fortune chose him for her pleasure salt. Paint him with drayman?s shoulders, butcher?s mien, Member?d like mules, with elephantine...

  17. PERFORMANCE OF CdSe TETRAPODS-GOLD AS NANOSTRUCTURE ELECTROCHEMICAL MATERIALS IN PHOTOVOLTAIC CELLS

    E-Print Network [OSTI]

    Natelson, Douglas

    PERFORMANCE OF CdSe TETRAPODS-GOLD AS NANOSTRUCTURE ELECTROCHEMICAL MATERIALS IN PHOTOVOLTAIC CELLS antenna arrays are assembled by coating on CdSe tetrapod templates; the rectifying barrier is formed and reduce the costs associated with conventional solar cells, including multi-bandgap materials [5

  18. Athena SWAN Silver and Gold renewal form www.athenaswan.org.uk Page 1 of 10

    E-Print Network [OSTI]

    Edinburgh, University of

    with Environmental and Sustainable Chemistry, Chemistry with Materials Chemistry, Medicinal and Biological Chemistry/Gold departmental renewal form Name of institution: University of Edinburgh Year: 2009 Department: Chemistry Contact website address: http://www.chem.ed.ac.uk/ 1. The School of Chemistry The School of Chemistry

  19. A Penicillamine Biosensor Based on Tyrosinase Immobilized on Nano-Au/ PAMAM Dendrimer Modified Gold Electrode

    E-Print Network [OSTI]

    Kwak, Juhyoun

    Modified Gold Electrode Nian Bing Li,a, b Juhyoun Kwaka * a Department of Chemistry, Korea Advanced to the solution, it reacted with o-benzoquinone to form the corresponding thioquinone derivatives, which resulted with a hydrogen ion in the beta-carbon of cysteine replaced by the methyl group. In addition to chelation of heavy

  20. Gas Sensing Mechanism of Gold Nanoparticles Decorated Single-Walled Carbon Nanotubes

    E-Print Network [OSTI]

    Gas Sensing Mechanism of Gold Nanoparticles Decorated Single- Walled Carbon Nanotubes Syed Mubeen towards different gas analytes, however the sensing mechanism was not clearly elucidated. The detailed demonstration of single-walled carbon nanotubes (SWNTs) as highly sensitive gas sensors [1], there have been

  1. FY2014 Parameters for Gold Ions in Booster, AGS, and RHIC

    SciTech Connect (OSTI)

    Gardner, C. J.

    2014-07-30

    The nominal parameters for gold ions in Booster, AGS, and RHIC are given for the FY2014 running period. The parameters are worked out using various formulas to derive mass, kinetic parameters, RF parameters, ring parameters, etc.. The ''standard setup'', ''medium-energy'', and ''low-energy'' parameters are summarized in separate sections.

  2. FY2014 Parameters for Helions and Gold Ions in Booster, AGS, and RHIC

    SciTech Connect (OSTI)

    Gardner, C. J.

    2014-08-15

    The nominal parameters for helions (helion is the bound state of two protons and one neutron, the nucleus of a helium-3 atom) and gold ions in Booster, AGS, and RHIC are given for the FY2014 running period. The parameters are found using various formulas to derive mass, helion anomalous g-factor, kinetic parameters, RF parameters, ring parameters, etc..

  3. Copyright by Ming Zhang, 2003 THERMAL PROPERTIES OF INDIUM NANOPARTICLES AND GOLD SILICIDE

    E-Print Network [OSTI]

    Allen, Leslie H.

    SILICIDE FORMATION BY SCANNING NANOCALORIMETRY BY MING ZHANG B. Engr., Tsinghua University, 1996 M. Engr of Illinois at Urbana-Champaign, 2003 Urbana, Illinois #12;iii THERMAL PROPERTIES OF INDIUM NANOPARTICLES AND GOLD SILICIDE FORMATION BY SCANNING NANOCALORIMETRY Ming Zhang Department of Material Science

  4. Recycling Size Exclusion Chromatography for the Analysis and Separation of Nanocrystalline Gold

    E-Print Network [OSTI]

    Aazhang, Behnaam

    fractions reveals that these peaks correspond to distinct populations of gold nanoparticles with narrowly nanocrystals are among their most important attributes. Characteristics ranging from the nanoparticle melting quantum dots,8-10 magnetic iron oxides,11-13 and other noble metals, show great tunability in properties

  5. GoldLink Finance Account Request ETSU Office of Information Technology

    E-Print Network [OSTI]

    Karsai, Istvan

    GoldLink Finance Account Request Form ETSU Office of Information Technology 424 Roy Nicks Hall, Box 70728 Johnson City, Tennessee 37614 (423) 439-4648 · oithelp@etsu.edu This section for use by the Office _______________________________________________________________________________________ [ last ] [ first ] [ middle ] ETSU Domain Name ____________________@etsu.edu School / College

  6. Preparation of supported gold nanoparticles by a modified incipient wetness impregnation method

    E-Print Network [OSTI]

    Boyer, Edmond

    procedure of impregnation of oxide supports with chloroauric acid, which is well-known to lead to large gold Paris Cedex 05, France Running title: Modified method of impregnation of Au/oxide Figures: 8 Tables: 3 after a treatment of calcination at 300°C on any type of oxide supports (alumina, titania, silica

  7. Asymmetric Catalysis at the Mesoscale: Gold Nanoclusters Embedded in Chiral Self-Assembled Monolayer as Heterogeneous

    E-Print Network [OSTI]

    Asymmetric Catalysis at the Mesoscale: Gold Nanoclusters Embedded in Chiral Self of the catalytically active metallic sites and the surrounding chiral SAM for the formation of a mesoscale the catalytically active site from the nanoscale to the mesoscale, which implies a principle of operating systems

  8. Silicone oil contamination and electrical contact resistance degradation of low-force gold contacts.

    SciTech Connect (OSTI)

    Dugger, Michael Thomas; Dickrell, Daniel John, III

    2006-02-01

    Hot-switched low-force gold electrical contact testing was performed using a nanomechanical test apparatus to ascertain the sensitivity of simulated microelectromechanical systems (MEMS) contact to silicone oil contamination. The observed cyclic contact resistance degradation was dependent on both closure rate and noncontact applied voltage. The decomposition of silicone oil from electrical arcing was hypothesized as the degradation mechanism.

  9. Z .Chemical Geology 157 1999 219234 z /Quantifying the platinum group elements PGEs and gold in

    E-Print Network [OSTI]

    Z .Chemical Geology 157 1999 219­234 z /Quantifying the platinum group elements PGEs and gold in geological samples using cation exchange pretreatment and ultrasonic nebulization inductively coupled plasma Department of CiÕil Engineering and Geological Sciences, UniÕersity of Notre Dame, Notre Dame, IN 46556

  10. Thomas Sommer gewinnt zweimal Gold bei der German Open Poomsae 2011

    E-Print Network [OSTI]

    Pinnau, René

    Thomas Sommer gewinnt zweimal Gold bei der German Open Poomsae 2011 Mit der Poomsae-Union Rheinland-Pfalz (TURP) stellte sich auch der zweifache WM- Bronzemedaillengewinner Thomas Sommer der im Paarwettbewerb wollte Thomas Sommer mit Cyra De Rama nach einer Goldmedaille greifen und damit für

  11. A Java Library Implementation of the Gold-Food Economic Model in Repast and MASON

    E-Print Network [OSTI]

    Tesfatsion, Leigh

    1 A Java Library Implementation of the Gold-Food Economic Model in Repast and MASON Christopher K, 2008 Abstract We present a robust, extensible Java library for agent-based economic simulations et al. [8]. We implement the library on top of both the Repast and MASON agent-based Java toolkits

  12. Adsorption of gold cyanide complexes by activated carbon on non-coconut shell origin

    SciTech Connect (OSTI)

    Yalcin, M.; Arol, A.I. [Middle East Technical Univ., Ankara (Turkey). Mining Engineering Dept.

    1995-12-31

    Coconut shells are the most widely used raw material for the production of activated carbon used in the gold production by cyanide leaching. There have been efforts to find alternatives to coconut shells. Shells and stones of certain fruits, have been tested. Although promising results to some extent were obtained, coconut shells remain the main source of activated carbon. Turkey has become a country of interest in terms of gold deposits of epithermal origin. Four deposits have already been discovered and, mining and milling operations are expected to start in the near future. Explorations are underway in many other areas of high expectations. Turkey is also rich in fruits which can be a valuable source of raw material for activated carbon production. In this study, hazelnut shells, peach and apricot stones, abundantly available locally, have been tested to determine whether they are suitable for the gold metallurgy. Parameters of carbonization and activation have been optimized. Gold loading capacity and adsorption kinetics have been studied.

  13. The Influence of shearing and rotary inertia on the resonant properties of gold nanowires

    E-Print Network [OSTI]

    Park, Harold S.

    The Influence of shearing and rotary inertia on the resonant properties of gold nanowires Pär A. T, SE-221 00 Lund, Sweden 2 Department of Mechanical Engineering, Boston University, Boston of shearing and rotary inertia for higher order resonant modes. Furthermore, we argue that this type

  14. Centrifugal Shape Sorting of Faceted Gold Nanoparticles Using an Atomic Plane-Selective Surfactant

    E-Print Network [OSTI]

    Gao, Hongjun

    Centrifugal Shape Sorting of Faceted Gold Nanoparticles Using an Atomic Plane-Selective Surfactant control or postsynthetic processing that relies on centrifugal sedimentation-based sorting schemes whereNPs possessing different shapes that would otherwise be virtually indistinguishable during centrifugal

  15. Laser-assisted scanning probe alloying nanolithography (LASPAN) and its application in gold-silicon system 

    E-Print Network [OSTI]

    Peng, Luohan

    2009-05-15

    alloying nanolithography (LASPAN), to fabricate well-defined nanostructures in gold-silicon (Au-Si) system. As a result, four aspects of nanostructures were made through different experimental trials. A non-equilibrium phase (AuSi3) was discovered, along...

  16. Lessons Learned from Continuous Commissioning® of a LEED Gold Building in Texas 

    E-Print Network [OSTI]

    Bynum, J.; Claridge, D. E.

    2008-09-22

    The subject building is a relatively new building with 120,000 square feet located in Texas and was the first LEED® Gold building in the area. To earn the title of a green building, the designers of this high performance building included many...

  17. The A.J. Goddard: Reconstruction and Material Culture of a Klondike Gold Rush Sternwheeler 

    E-Print Network [OSTI]

    Thomas, Lindsey Hall

    2012-10-19

    The A.J. Goddard, a steamboat built for the Klondike Gold Rush of 1897-1898, wrecked in 1901 on Lake Laberge, Yukon Territory, where it lay undisturbed until its rediscovery in 2008 by the Yukon River Survey Project, directed by John Pollack...

  18. Continuous Commissioning of a LEED-EB Gold Certified Office Building 

    E-Print Network [OSTI]

    McCown, P.

    2009-01-01

    A 320,000 square foot Class A high-rise office building in Nashville, TN achieved LEED-EB Gold Certification. LEED-EB version 2.0 was utilized, which requires Retro-Commissioning (RCx) as a prerequisite for certification. SSRCx performed the RCx...

  19. Evolution of Size and Shape in the Colloidal Crystallization of Gold Nanoparticles

    E-Print Network [OSTI]

    Osterloh, Frank

    Evolution of Size and Shape in the Colloidal Crystallization of Gold Nanoparticles Owen C. Compton to aggregation of nanoparticles and formation of colloidal crystals. Based on results from dynamic light, or colloidal crystals, continues to be of great academic and technical interest.1-9 Demonstrated uses

  20. Gold Nanorods & Photothermal Heating Breast cancer cells incubated with 2-NBDG will have increased fluorescence

    E-Print Network [OSTI]

    in cell lines responsive to such therapeutics. · The presence of gold nanoparticles alone will not have. Vol. 89, pp. 1271-1275. Feb. 1992. [5] Walsh, Alex J., and Melissa C. Skala. "An automated image, Danhier P, Gallez B, et al. (2010) NADPH oxidase-mediated reactive oxygen species production activates

  1. The Genomes On Line Database (GOLD) in 2007: status of genomic and metagenomic projects and their associated metadata

    SciTech Connect (OSTI)

    Fenner, Marsha W; Liolios, Konstantinos; Mavromatis, Konstantinos; Tavernarakis, Nektarios; Kyrpides, Nikos C.

    2007-12-31

    The Genomes On Line Database (GOLD) is a comprehensive resource of information for genome and metagenome projects world-wide. GOLD provides access to complete and ongoing projects and their associated metadata through pre-computed lists and a search page. The database currently incorporates information for more than 2900 sequencing projects, of which 639 have been completed and the data deposited in the public databases. GOLD is constantly expanding to provide metadata information related to the project and the organism and is compliant with the Minimum Information about a Genome Sequence (MIGS) specifications.

  2. TH-E-BRD-01: Innovation in (gold) Nanoparticle-Enhanced Therapy

    SciTech Connect (OSTI)

    Krishnan, S; Chithrani, B; Berbeco, R

    2014-06-15

    Radiation therapy relies on the concept of delivering high dose to tumor volumes whilst simultaneously aiming to minimize irradiation of healthy tissue. Gold and other metallic nanoparticles (GNPs) have the potential to greatly enhance dose depositions in their close proximity. While it was originally thought that this effect would only be significant for kV photon beams, it has been shown that GNPs also enhance dose and increase cell killing and survival fraction for MV photons as well as protons. GNPs have been shown to be preferentially taken up in tumors, depending on the GNP properties either internalized in the tumor cells or clustering in the tumor vasculature. Therefore GNPs offer an intriguing additional option to target the tumor while sparing healthy tissue. While a growing amount of research shows GNP induced enhancement factors in the order of 1.5 and higher, GNPs have not yet entered into clinical routine. In this symposium we will have three presentations discussing the current status of GNP based research, the potential to include GNPs in radiation therapy and the limitations and problems to use GNPs in the clinic. Physical and biological underpinnings of radiosensitization with gold nano particles An evolving body of recent literature alludes to the potential to sensitize tumors to radiation therapy using metallic nanoparticles. In preclinical studies, the techniques that hold promise for eventual clinical deployment are nanoparticle-assisted radiation dose enhancement and hyperthermic radiosensitization. To understand the underlying nanoparticle-radiation interactions, computational techniques offer an explanation for and predict the biophysical consequences at a nano-/meso-scopic scale. Nonetheless, there are persisting gaps in knowledge relating to the molecular mechanism of action of these radiosensitization approaches — some of these issues will be addressed. Since the literature relating to the diverse disciplines involved in these efforts spans across multiple specialties (clinical radiation oncology, radiation physics, radiation biology, nanotechnology, material science, biomedical engineering, pharmacology, chemistry, and tumor biology) and numerous specialty journals, there is no single compilation of extant research in this arena or forum for merging analogous concepts and paradigms. This symposium will provide such a venue — my presentation will start with familiarizing the audience with the potential applications of metallic nanoparticles in radiation therapy using specific illustrative examples and begin to explore ways to understand the underlying mechanisms of the effects observed. Biological effects of Gold nanoparticles in radiation therapy Gold nanoparticles (GNP) have been investigated as platforms to carry drugs or radio-sensitizing agents to tumors due to the biocompatibility of gold and relative ease of conjugation with therapeutic and targeting moieties. Recently, there has been interest in exploiting the physical properties of gold, specifically the high atomic number, to enhance radiation therapy. When irradiated, gold atoms will produce low energy electrons, depositing energy within a short distance. The ratio of dose deposited in the presence of the GNP to the dose deposited in the absence of GNP is referred to as the dose enhancement factor (DEF). This factor has been shown to depend on the concentration of GNP and the energy of the incident photons. The physics of this process, preliminary in vitro and in vivo experiments and future directions for this nascent field are described in this presentation. Gold Nanoparticles for improved therapeutic outcome in radiation therapy The application of nanoparticles (NPs) for improved therapeutics is at the forefront of cancer nanotechnology. Among other NP systems, gold nanoparticles (GNPs) are extensively used due to its impressive ability to act as both an anticancer drug carrier in chemotherapy and as a dose enhancer in radiotherapy. Cellular uptake of GNPs was dependent on their size. Among GNPs of diameter between 14–74 nm,

  3. Cationic Gold Clusters Ligated with Differently Substituted Phosphines: Effect of Substitution on Ligand Reactivity and Binding

    SciTech Connect (OSTI)

    Johnson, Grant E.; Olivares, Astrid M.; Hill, David E.; Laskin, Julia

    2015-01-01

    We present a systematic study of the effect of the number of methyl (Me) and cyclohexyl (Cy) functional groups in monodentate phosphine ligands on the solution-phase synthesis of ligated sub-nanometer gold clusters and their gas-phase fragmentation pathways. Small mixed ligand cationic gold clusters were synthesized using ligand exchange reactions between pre-formed triphenylphosphine ligated (PPh3) gold clusters and monodentate Me- and Cy-substituted ligands in solution and characterized using electrospray ionization mass spectrometry (ESI-MS) and collision-induced dissociation (CID) experiments. Under the same experimental conditions, larger gold-PPh3 clusters undergo efficient exchange of unsubstituted PPh3 ligands for singly Me- and Cy-substituted PPh2Me and PPh2Cy ligands. The efficiency of ligand exchange decreases with an increasing number of Me or Cy groups in the substituted phosphine ligands. CID experiments performed for a series of ligand-exchanged gold clusters indicate that loss of a neutral Me-substituted ligand is preferred over loss of a neutral PPh¬3 ligand while the opposite trend is observed for Cy-substituted ligands. The branching ratio of the competing ligand loss channels is strongly correlated with the electron donating ability of the phosphorous lone pair as determined by the relative proton affinity of the ligand. The results indicate that the relative ligand binding energies increase in the order PMe3 < PPhMe2 < PPh2Me < PPh3< PPh2Cy < PPhCy2< PCy3. Furthermore, the difference in relative ligand binding energies increases with the number of substituted PPh3-mMem or PPh3-mCym ligands (L) exchanged onto each cluster. This study provides the first experimental determination of the relative binding energies of ligated gold clusters containing differently substituted monophosphine ligands, which are important to controlling their synthesis and reactivity in solution. The results also indicate that ligand substitution is an important parameter that must be considered in theoretical modeling of these complex systems

  4. Propane reacts with O2 and H2 on gold supported TS-1 to form oxygenates with high selectivity

    E-Print Network [OSTI]

    Bravo Suarez, Juan J.

    2008-06-13

    Gold nanoparticles supported on a microporous titanosilicate (TS-1) were found to be highly selective (95%) towards the formation of acetone and isopropanol from propane, O2, and H2 at moderate temperatures (443 K)....

  5. Room temperature reaction of oxygen with gold: an in situ ambient-pressure X-ray photoelectron spectroscopy investigation

    SciTech Connect (OSTI)

    Jiang, Peng; Porsgaard, Soeren; Borondics, Ferenc; Kober, Mariana; Caballero, Alfonso; Bluhm, Hendrik; Besenbacher, Flemming; Salmeron, Miquel

    2010-02-01

    Gold is commonly regarded as the most inert element.1 However, the discovery of the exceptional catalytic properties of gold nanoparticles (NPs) for low temperature CO oxidation2 initiated great interest due to its promising applications and spawned a large number of studies devoted to the understanding of the reaction mechanism.3-6 Nevertheless, no consistent and conclusive picture has arisen.7-13

  6. A Review of "New World Gold: Cultural Anxiety and Monetary Disorder in Early Modern Spain" by Elvira Vilches 

    E-Print Network [OSTI]

    Wright, Elizabeth R.

    2011-01-01

    and of recent work on the early Enlightenment. Elvira Vilches. New World Gold: Cultural Anxiety and Monetary Disorder in Early Modern Spain. Chicago: University of Chicago Press, 2010. xi + 361 pp. $45. Review by elizabeth r. wright, university of georgia.... The six chapters of New World Gold attest to an ambitious, pre- scient and impressively executed research project, in which Elvira Vilches combined the analytical tools of a cultural critic and an economic historian. At its heart is a question...

  7. Highly Nonlinear Luminescence Induced by Gold Nanoparticles on Glass Surfaces with Continuous-Wave Laser Illumination

    E-Print Network [OSTI]

    Wu, Yong; Toro, Ligia; Stefani, Enrico

    2015-01-01

    We report on highly nonlinear luminescence being observed from individual spherical gold nanoparticles immobilized on a borosilicate glass surface and illuminated by continuous-wave (CW) lasers with relatively low power. The nonlinear luminescence shows optical super-resolution beyond the diffraction limit in three dimensions compared to the scatting of the excitation laser light. The luminescence intensity from most nanoparticles is proportional to the 5th--7th power of the excitation laser power and has wide excitation and emission spectra across the visible wavelength range. Strong nonlinear luminescence is only observed near the glass surface. High optical nonlinearity excited by low CW laser power is related to a long-lived dark state of the gold nanoparticles, where the excitation light is strongly absorbed. This phenomenon has potential biological applications in super-resolution and deep tissue imaging.

  8. Gold and palladium adsorption from leached electronic scrap using ordered mesoporous carbon nanoscaffolds

    SciTech Connect (OSTI)

    McDowell, Rocklan; Dutech, Guy

    2014-09-01

    Ordered mesoporous carbon (OMC) nanoscaffolds are engineered agglomerates of carbon nanotubes held together by small carbon nanofibers with uniform pore sizes, high pore volume, and high channel permeability. These materials exhibit very high affinity for the adsorption of gold from aqueous acidic mixtures. The efficiency of gold recovery is comparable to those typically accomplished using biopolymer-based adsorbents. The adsorption efficiency for other precious metals such as palladium and platinum is lower. Studies on the precious metal (Au, Pd) adsorption on OMC materials from actual liquors of leached electronics will be presented. Adsorption properties will be compared for several different sorbents used for the recovery of precious metals. The leach liquor compositions for three different types of electronic scrap materials (personal computer board, cell phone and tv input/output board) will be presented. The sorption efficiencies for Au, Pd, together with a spectrum of competing and non-competing metals, from such leach mixtures will be compared.

  9. High resolution transmission electron microscopic in-situ observations of plastic deformation of compressed nanocrystalline gold

    SciTech Connect (OSTI)

    Wang, Guoyong; Lian, Jianshe; Jiang, Qing; Sun, Sheng; Zhang, Tong-Yi

    2014-09-14

    Nanocrystalline (nc) metals possess extremely high strength, while their capability to deform plastically has been debated for decades. Low ductility has hitherto been considered an intrinsic behavior for most nc metals, due to the lack of five independent slip systems actively operating during deformation in each nanograin. Here we report in situ high resolution transmission electron microscopic (HRTEM) observations of deformation process of nc gold under compression, showing the excellent ductility of individual and aggregate nanograins. Compression causes permanent change in the profile of individual nanograins, which is mediated by dislocation slip and grain rotation. The high rate of grain boundary sliding and large extent of widely exited grain rotation may meet the boundary compatibility requirements during plastic deformation. The in situ HRTEM observations suggest that nc gold is not intrinsically brittle under compressive loading.

  10. Gold–promoted structurally ordered intermetallic palladium cobalt nanoparticles for the oxygen reduction reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kuttiyiel, Kurian A.; Sasaki, Kotaro; Su, Dong; Wu, Lijun; Zhu, Yimei; Adzic, Radoslav R.

    2014-11-06

    Considerable efforts to make palladium and palladium alloys active catalysts and a possible replacement for platinum have had a marginal success. Here, we report on a structurally ordered Au??Pd??Co?? catalyst that exhibits comparable activity to conventional platinum catalysts in both acid and alkaline media. Electron microscopic techniques demonstrate that via addition of gold atoms PdCo nanoparticles undergo at elevated temperatures an atomic structural transition from core-shell to a rare intermetallic ordered structure with twin boundaries forming stable {111}, {110} and {100} facets. The superior stability of this catalyst compared to platinum after 10,000 potential cycles in alkaline media is attributedmore »to the atomic structural order of PdCo nanoparticles along with protective effect of clusters of gold atoms on the surface. This strategy of making ordered palladium intermetallic alloy nanoparticles can be used in diverse heterogeneous catalysis where particle size and structural stability matters.« less

  11. Benchmark Measurements of the Ionization Balance of Non-LTE Gold

    SciTech Connect (OSTI)

    Heeter, R F; Hansen, S B; Fournier, K B; Foord, M E; Froula, D H; Mackinnon, A J; May, M J; Schneider, M B; Young, B F

    2007-04-20

    The authors present a series of benchmark measurements of the ionization balance of well characterized gold plasmas with and without external radiation fields at electron densities near 10{sup 21} cm{sup -3} and various electron temperatures spanning the range 0.8 to 2.4 keV. They have analyzed time- and space-resolved M-shell gold emission spectra using a sophisticated collisional-radiative model with hybrid level structure, finding average ion changes ranging from 42 to 50. At the lower temperatures, the spectra exhibit significant sensitivity to external radiation fields and include emission features from complex N-shell ions not previously studied at these densities. The measured spectra and inferred provide a stringent test for non-local thermodynamic equilibrium (non-LTE) models of complex high-Z ions.

  12. Gold–promoted structurally ordered intermetallic palladium cobalt nanoparticles for the oxygen reduction reaction

    SciTech Connect (OSTI)

    Kuttiyiel, Kurian A.; Sasaki, Kotaro; Su, Dong; Wu, Lijun; Zhu, Yimei; Adzic, Radoslav R.

    2014-11-06

    Considerable efforts to make palladium and palladium alloys active catalysts and a possible replacement for platinum have had a marginal success. Here, we report on a structurally ordered Au??Pd??Co?? catalyst that exhibits comparable activity to conventional platinum catalysts in both acid and alkaline media. Electron microscopic techniques demonstrate that via addition of gold atoms PdCo nanoparticles undergo at elevated temperatures an atomic structural transition from core-shell to a rare intermetallic ordered structure with twin boundaries forming stable {111}, {110} and {100} facets. The superior stability of this catalyst compared to platinum after 10,000 potential cycles in alkaline media is attributed to the atomic structural order of PdCo nanoparticles along with protective effect of clusters of gold atoms on the surface. This strategy of making ordered palladium intermetallic alloy nanoparticles can be used in diverse heterogeneous catalysis where particle size and structural stability matters.

  13. Modeled Neutron Induced Nuclear Reaction Cross Sections for Radiochemistry in the region of Iriduim and Gold

    SciTech Connect (OSTI)

    Hoffman, R D; Dietrich, F S; Kelley, K; Escher, J; Bauer, R; Mustafa, M

    2008-02-26

    We have developed a set of modeled nuclear reaction cross sections for use in radiochemical diagnostics. Systematics for the input parameters required by the Hauser-Feshbach statistical model were developed and used to calculate neutron induced nuclear reaction cross sections for targets ranging from osmium (Z = 76) to gold (Z = 79). Of particular interest are the cross sections on Ir and Au including reactions on isomeric targets.

  14. Radioactive gold in the treatment of bovine ocular squamous carcinoma and its precursor lesions 

    E-Print Network [OSTI]

    England, Roy Belvin

    1973-01-01

    A&M University D. V. M. , Texas A&M University Directed by: Dr. M. C. Banks Ten cases of clinically diagnosed bovine ocular carcinoma were treated by implanting radioactive gold seeds into the lesions with a needle and stylet. Progress films... were made at regular intervals during a 6 months convalescent period to record any changes resulting from this treatment. In 6 of 10 cases, total or near total regression occurred, while temporary regression and subsequent proliferation...

  15. Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold

    DOE Patents [OSTI]

    Porter, Marc D. (Ames, IA); Weisshaar, Duane E. (Sioux Falls, SD)

    1998-10-27

    An electrochemical method for forming a partial monomolecular layer of a predetermined extent of coverage of a thiolate of the formula, XRS--, therein R can be a linear or branched chain hydrocarbon or an aromatic or the like and X can be any compatible end group, e.g., OH, COOH, CH.sub.3 or the like, upon a substrate such as gold, which involves applying in an electrochemical system a constant voltage preselected to yield the desired predetermined extent of coverage.

  16. Explorations of Functionalized Gold Nanoparticle Surface Chemistry for Laser Desorption Ionization Mass Spectrometry Applications 

    E-Print Network [OSTI]

    Gomez Hernandez, Mario 1980-

    2012-07-11

    -MS Matrix Assisted Laser Desorption Ionization Mass Spectrometry AuNPs Gold Nanoparticles UV-Vis Ultraviolet-Visible Spectroscopy TEM Transmission Electron Microscopy NMR Nuclear Magnetic Resonance Spectroscopy RIY Relative Ion... including enhanced Rayleigh scattering,2 biological reaction catalysis,3 aggregation assays,4 surface enhanced Raman spectroscopy,5 and other applications known as nanobiotechnology.6 Therefore, it is the combination of the proven performance of mass...

  17. Ultrafast Non-linear Response of Gold Gyroid 3D Metamaterials

    E-Print Network [OSTI]

    Farah, Petros; Demetriadou, Angela; Salvatore, Stefano; Vignolini, Silvia; Stefik, Morgan; Wiesner, Ulrich; Hess, Ortwin; Steiner, Ullrich; Valev, Ventsi; Baumberg, Jeremy J.

    2014-10-07

    , University of Cambridge, Cambridge, CB3 0HE, UK 2 Department of Chemistry, Imperial College London, London, SW7 2AZ, United Kingdom 3 Department of Materials Science and Engineering Cornell University, Ithaca, New York 14853, USA 4 Blackett Laboratory... -? nanostructures induce magnetic fields opposing their motion, which govern the effective macro- scopic optical behaviour of the structure. It was recently shown [21, 23, 25] that gold gyroid films behave as an ar- tificial chiral plasma, with a Drude...

  18. Millifluidics for time-resolved mapping of the growth of gold nanostructures

    SciTech Connect (OSTI)

    Sai Krishna, Katla; Navin, Chelliah; Biswas, Sanchita; Singh, Varshni; Ham, Kyungmin; Bovencamp, L. S.; Theegala, Chandra; Miller, Jeffrey T; Spivey, James J.; Kumar, Challa S.S.R.

    2013-04-10

    Innovative in situ characterization tools are essential for understanding the reaction mechanisms leading to the growth of nanoscale materials. Though techniques, such as in situ transmission X-ray microscopy, fast single-particle spectroscopy, small-angle X-ray scattering, etc., are currently being developed, these tools are complex, not easily accessible, and do not necessarily provide the temporal resolution required to follow the formation of nanomaterials in real time. Here, we demonstrate for the first time the utility of a simple millifluidic chip for an in situ real time analysis of morphology and dimension-controlled growth of gold nano- and microstructures with a time resolution of 5 ms. The structures formed were characterized using synchrotron radiation-based in situ X-ray absorption spectroscopy, 3-D X-ray tomography, and high-resolution electron microscopy. These gold nanostructures were found to be catalytically active for conversion of 4-nitrophenol into 4-aminophenol, providing an example of the potential opportunities for time-resolved analysis of catalytic reactions. While the investigations reported here are focused on gold nanostructures, the technique can be applied to analyze the time-resolved growth of other types of nanostructured metals and metal oxides. With the ability to probe at least a 10-fold higher concentrations, in comparison with traditional microfluidics, the tool has potential to revolutionize a broad range of fields from catalysis, molecular analysis, biodefense, and molecular biology.

  19. Visualization of expanding warm dense gold and diamond heated rapidly by laser-generated ion beams

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bang, W.; Albright, B. J.; Bradley, P. A.; Gautier, D. C.; Palaniyappan, S.; Vold, E. L.; Cordoba, M. A. Santiago; Hamilton, C. E.; Fernández, J. C.

    2015-09-22

    With the development of several novel heating sources, scientists can now heat a small sample isochorically above 10,000 K. Although matter at such an extreme state, known as warm dense matter, is commonly found in astrophysics (e.g., in planetary cores) as well as in high energy density physics experiments, its properties are not well understood and are difficult to predict theoretically. This is because the approximations made to describe condensed matter or high-temperature plasmas are invalid in this intermediate regime. A sufficiently large warm dense matter sample that is uniformly heated would be ideal for these studies, but has beenmore »unavailable to date. We have used a beam of quasi-monoenergetic aluminum ions to heat gold and diamond foils uniformly and isochorically. For the first time, we visualized directly the expanding warm dense gold and diamond with an optical streak camera. Furthermore, we present a new technique to determine the initial temperature of these heated samples from the measured expansion speeds of gold and diamond into vacuum. We anticipate the uniformly heated solid density target will allow for direct quantitative measurements of equation-of-state, conductivity, opacity, and stopping power of warm dense matter, benefiting plasma physics, astrophysics, and nuclear physics.« less

  20. Enhancing DNA binding rate using optical trapping of high-density gold nanodisks

    SciTech Connect (OSTI)

    Lin, En-Hung; Pan, Ming-Yang [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China) [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China); Research Center for Applied Sciences, Academia Sinica, Taipei, Taiwan 11529 (China); Lee, Ming-Chang [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China)] [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China); Wei, Pei-Kuen, E-mail: pkwei@sinica.edu.tw [Research Center for Applied Sciences, Academia Sinica, Taipei, Taiwan 11529 (China) [Research Center for Applied Sciences, Academia Sinica, Taipei, Taiwan 11529 (China); Institute of Biophotonics, National Yang-Ming University, Taipei 11221, Taiwan (China)

    2014-03-15

    We present the dynamic study of optical trapping of fluorescent molecules using high-density gold nanodisk arrays. The gold nanodisks were fabricated by electron beam lithography with a diameter of 500 nm and a period of 1 ?m. Dark-field illumination showed ?15 times enhancement of fluorescence near edges of nanodisks. Such enhanced near-field generated an optical trapping force of ?10 fN under 3.58 × 10{sup 3} W/m{sup 2} illumination intensity as calculated from the Brownian motions of 590 nm polystyrene beads. Kinetic observation of thiolated DNA modified with Cy5 dye showed different binding rates of DNA under different illumination intensity. The binding rate increased from 2.14 × 10{sup 3} s{sup ?1} (I = 0.7 × 10{sup 3} W/m{sup 2}) to 1.15 × 10{sup 5} s{sup ?1} (I = 3.58 × 10{sup 3} W/m{sup 2}). Both enhanced fluorescence and binding rate indicate that gold nanodisks efficiently improve both detection limit and interaction time for microarrays.

  1. Controlled epitaxial growth of mesoporous silica/gold nanorod nanolollipops and nanodumb-bells

    SciTech Connect (OSTI)

    Huang, Ching-Mao; Chung, Ming-Fang; Lo, Leu-Wei; Souris, Jeffrey S.

    2014-11-01

    In this work, we describe the controlled synthesis of novel heterogeneous nanostructures comprised of mesoporous silica-coated gold nanorods (MSGNRs) in the form of core–shell nanolollipops and nanodumb-bells, using a seed-mediated sol–gel method. Although MSGNR core–shell (?-MSGNR) structures have been reported previously by us and others, we herein discuss the first ever fabrication of MSGNR nanolollipops (?-MSGNR) and nanodumb-bells (?-MSGNR), achieved by simply controlling the aging time of gold nanorods (GNRs), the residual cetyltrimethylammonium bromide (CTAB) coating of GNRs, and the addition of dimethyl formamide during incubation, centrifugation, and sonication, respectively. Transmission electron microscopy revealed two bare GNR isoforms, with aspect ratios of approximately 4 and 6, while scanning electron microscopy was used to further elucidate the morphology of ?-MSGNR and ?-MSGNR heterostructures. In agreement with the smaller dielectric constants afforded by incomplete silica encasement, spectroscopic studies of ?-MSGNR and ?-MSGNR, surface plasmon resonance (SPR) bands revealed 20-40 nm blue shifts relative to the SPR of ?-MSGNR. On the basis of the attributes and applications of more conventional ?-MSGNRs, ?-MSGNRs and ?-MSGNRs are anticipated to provide most of the utility of ?-MSGNRs, but with the additional functionalities that accompany their incorporation of both bare gold and mesoporous silica encased tips; with significant/unique implications for biomedical and catalytic applications.

  2. SU-E-J-247: A Simulation of X-Ray Emission with Gold Nanoparticle Irradiated by Energetic Proton Beam

    SciTech Connect (OSTI)

    Newpower, M; Ahmad, S; Chen, Y [University of Oklahoma Health Sciences Center, Oklahoma City, OK (United States)

    2014-06-01

    Purpose: To investigate the proton induced X-ray emissions in gold-water mixture materials. Methods: In this study a Monte Carlo simulation was created using the GEANT4 toolkit (version 4.9.6). The geometry in this setup includes a 2 cm × 2 cm × 2 cm target, a scoring sphere (radius = 10 cm) and a 65 MeV planar proton source (2 cm × 2 cm). Four concentrations of a gold-water solution were irradiated with 5×10{sup 5} incident protons at a distance of 0.5 cm perpendicular to the surface of the target. The solutions of gold-water mixture had 10%, 5%, 1% and 0.5% of gold by mass, respectively. The number of photon emitting for the target was counted in the scoring sphere for the energy range of 0-86.0 keV in 0.1 keV bins. For this study the reference physics list PhysListEmStandard was used together with the x-ray fluorescence, Auger electron and PIXE (particle induced xray emission) options enabled. The range cuts for photons and electrons were set at 0.5 mm and 1.0 mm, respectively. Results: In the energy spectra of emitting X-ray fluorescence, peaks from gold K shell characteristic x-rays (68.8 and 66.9 keV) were observed. The number of counts under the peaks of Ka1 and Ka2 was found to increase with the increasing of the gold concentrations in the mixture materials. The X-ray yields (for both Ka1 and Ka2) when fitted with least-square method as a function of gold concentration demonstrate a linear dependency with R{sup 2} > 0.96. The Ka1yield per incident proton was found to be 0.0016 for 10% gold-water mixture solutions. Conclusion: This preliminary study with PIXE technique with gold nanoparticle has demonstrated potentials for its utilization in the development of range and dose verification methodology that is currently of great interest in the field of proton radiation therapy.

  3. “Smart” Diblock Copolymers as Templates for Magnetic-Core Gold-Shell Nanoparticle Synthesis

    SciTech Connect (OSTI)

    Nash, Michael A.; Lai, James J.; Hoffman, Allan S.; Yager, Paul; Stayton, Partick S.

    2010-01-13

    We report a new strategy for synthesizing temperature-responsive ?-Fe2O3-core/Au-shell nanoparticles (Au-mNPs) from diblock copolymer micelles. The amphiphilic diblock copolymer chains were synthesized using reversible addition-fragmentation chain-transfer (RAFT) with a thermally responsive “smart” poly(N-isopropylacrylamide) (pNIPAAm) block and an amine-containing poly(N,N-dimethylaminoethylacrylamide) (DMAEAm) block that acted as a reducing agent during gold shell formation. The Au-mNPs reversibly aggregated upon heating the solution above the transition temperature of pNIPAAm, resulting in a red-shifted localized surface plasmon resonance.

  4. Thermal emission of electrons under irradiation of a gold target by a femtosecond laser pulse

    SciTech Connect (OSTI)

    Bezhanov, S G; Kanavin, Andrey P; Uryupin, Sergey A

    2012-05-31

    We study the effect of d-electrons on heating of a gold target upon absorption of a femtosecond laser pulse as well as on subsequent thermal emission of hot electrons. It is shown that neglecting the effect of d-electrons leads to a significant overestimation of the number of the emitted electrons. It is found that the approximate description of the heating field in the skin layer without the inhomogeneity of the dielectric constant taken into account does not cause a significant change in the maximum temperature of the electrons at the metal surface, and has virtually no effect on the process of thermal emission.

  5. Longitudinal emittance measurements in the Booster and AGS during the 2014 RHIC gold run

    SciTech Connect (OSTI)

    Zeno, K.

    2014-08-18

    This note describes longitudinal emittance measurements that were made in the Booster and AGS during the 2014 RHIC Gold run. It also contains an overview of the longitudinal aspects of their setup during this run. Each bunch intended for RHIC is composed of beam from 4 Booster cycles, and there are two of them per AGS cycle. For each of the 8 Booster cycles required to produce the 2 bunches in the AGS, a beam pulse from EVIS is injected into the Booster and captured in four h=4 buckets. Then those bunches are accelerated to a porch where they are merged into 2 bunches and then into 1 bunch.

  6. Quantum optics with single nanodiamonds flying over gold films: Towards a Robust quantum plasmonics

    SciTech Connect (OSTI)

    Mollet, O.; Drezet, A.; Huant, S.

    2013-12-04

    A nanodiamond (ND) hosting nitrogen-vacancy (NV) color centers is attached on the apex of an optical tip for near-field microscopy. Its fluorescence is used to launch surface plasmon-polaritons (SPPs) in a thin polycrystalline gold film. It is shown that the quantum nature of the initial source of light is preserved after conversion to SPPs. This opens the way to a deterministic quantum plasmonics, where single SPPs can be injected at well-defined positions in a plasmonic device produced by top-down approaches.

  7. Quantum Optics With Single Nanodiamonds Flying Over Gold Films: Towards A Robust Quantum Plasmonics

    E-Print Network [OSTI]

    Mollet, O; Huant, S

    2013-01-01

    A nanodiamond (ND) hosting nitrogen-vacancy (NV) color centers is attached on the apex of an optical tip for near-field microscopy. Its fluorescence is used to launch surface plasmon-polaritons (SPPs) in a thin polycrystalline gold film. It is shown that the quantum nature of the initial source of light is preserved after conversion to SPPs. This opens the way to a deterministic quantum plasmonics, where single SPPs can be injected at well-defined positions in a plasmonic device produced by top-down approaches.

  8. Application of Bare Gold Nanoparticles in Open-Tubular CEC Separations of Polyaromatic Hydrocarbons and Peptides

    E-Print Network [OSTI]

    Miksik, Ivan

    spray chamber, and Gilson 212 peristaltic pump. Quantification of gold was based on 197 Au. StockL volumetric flasks using 0, 0.1, 0.25, 0.5 and 1 mL of the SS solution, 1 mL of IS solution and 2 mL of HNO3L volumetric flasks, to which 0.5 mL of IS solution was added and volume adjusted to 25 mL with water. #12;S2

  9. Optical Manipulation of Shape-Morphing Elastomeric Liquid Crystal Microparticles Doped with Gold Nanocrystals

    SciTech Connect (OSTI)

    Sun, Y. R.; Evans, J. S.; Lee, T.; Senyuk, B.; Keller, P.; He, S. L.; Smalyukh, I. I.

    2012-06-11

    We demonstrate facile optical manipulation of shape of birefringent colloidal microparticles made from liquid crystal elastomers. Using soft lithography and polymerization, we fabricate elastomeric microcylinders with weakly undulating director oriented on average along their long axes. These particles are infiltrated with gold nanospheres acting as heat transducers that allow for an efficient localized transfer of heat from a focused infrared laser beam to a submicrometer region within a microparticle. Photothermal control of ordering in the liquid crystal elastomer using scanned beams allows for a robust control of colloidal particles, enabling both reversible and irreversible changes of shape. Possible applications include optomechanics, microfluidics, and reconfigurable colloidal composites with shape-dependent self-assembly.

  10. Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold

    DOE Patents [OSTI]

    Porter, Marc D. (Ames, IA); Weisshaar, Duane E. (Sioux Falls, SD)

    1997-06-03

    An electrochemical method for forming a partial monomolecular layer of a predetermined extent of coverage of a thiolate of the formula, XRS.sup.-, wherein R can be a linear or branched chain hydrocarbon or an aromatic or the like and X can be any compatible end group, e.g., OH, COOH, CH.sub.3 or the like, upon a substrate such as gold, which involves applying in an electrochemical system a constant voltage preselected to yield the desired predetermined extent of coverage.

  11. Electrochemical method of controlling thiolate coverage on a conductive substrate such as gold

    DOE Patents [OSTI]

    Porter, M.D.; Weisshaar, D.E.

    1998-10-27

    An electrochemical method is described for forming a partial monomolecular layer of a predetermined extent of coverage of a thiolate of the formula, XRS-, therein R can be a linear or branched chain hydrocarbon or an aromatic or the like and X can be any compatible end group, e.g., OH, COOH, CH{sub 3} or the like, upon a substrate such as gold, which involves applying in an electrochemical system a constant voltage preselected to yield the desired predetermined extent of coverage. 13 figs.

  12. Gold-Stud Bump Bonding for HEP Applications (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) |productionPatent:CompressionSciTechwithinProduced(JournalGold-Stud

  13. World's largest single crystal of gold verified by Los Alamos instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLos Alamos verifies largest single gold crystal World's largest single

  14. Gold Nanoparticles Self-Similar Chain Structure Organized by DNA Origami

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFESOpportunitiesNERSC Getting Started at14 at 12:00GlobusHanfordGold

  15. Energy Deposition and Nanodosimetry of Iodine-125 and Tin-117m Labeled Gold Nanoparticles: A Computational Model Using Geant4-DNA 

    E-Print Network [OSTI]

    Pulley, Marina Lee

    2015-08-12

    of metastatic cancer is evolving, and therapeutic strategies need to evolve with it. Gold nanoparticles have been extensively used in the medical field. In this study, gold nanoparticles containing Auger emitting radionuclides of 125I or 117mSn were modeled...

  16. What Protects the Core When the Thiolated Gold Cluster is Extremely Small?

    SciTech Connect (OSTI)

    Jiang, Deen [ORNL; Chen, Wei [University of Puerto Rico; Whetten, Robert L [Georgia Institute of Technology; Chen, Zhongfang [University of Georgia, Athens, GA

    2009-01-01

    The title question is motivated by the fact that extremely small thiolated-gold clusters such as Au{sub 20}(SR){sub 16} have been isolated, but their undetermined structures cannot be fully rationalized by the present knowledge derived from single-crystal structures of larger clusters. One needs to go beyond the linear monomer (RSAuSR) and V-shaped dimer (RSAuSRAuSR) motifs that were found to protect larger clusters. We hypothesize that the U-shaped trimer motif (RSAuSRAuSRAuSR) is required to protect the core of some extremely small thiolated-gold clusters, which have about 20 or fewer Au atoms. We test this hypothesis by proposing structural models for Au{sub 10}(SR){sub 8} based on two trimer motifs protecting a tetrahedral Au{sub 4} core and for Au{sub 20}(SR){sub 16} based on four trimer motifs protecting an Au{sub 8} core.

  17. Thermal tuning of infrared resonant absorbers based on hybrid gold-VO{sub 2} nanostructures

    SciTech Connect (OSTI)

    Kocer, Hasan; Butun, Serkan; Aydin, Koray; Banar, Berker; Wang, Kevin; Wu, Junqiao; Tongay, Sefaatttin

    2015-04-20

    Resonant absorbers based on plasmonic materials, metamaterials, and thin films enable spectrally selective absorption filters, where absorption is maximized at the resonance wavelength. By controlling the geometrical parameters of nano/microstructures and materials' refractive indices, resonant absorbers are designed to operate at wide range of wavelengths for applications including absorption filters, thermal emitters, thermophotovoltaic devices, and sensors. However, once resonant absorbers are fabricated, it is rather challenging to control and tune the spectral absorption response. Here, we propose and demonstrate thermally tunable infrared resonant absorbers using hybrid gold-vanadium dioxide (VO{sub 2}) nanostructure arrays. Absorption intensity is tuned from 90% to 20% and 96% to 32% using hybrid gold-VO{sub 2} nanowire and nanodisc arrays, respectively, by heating up the absorbers above the phase transition temperature of VO{sub 2} (68?°C). Phase change materials such as VO{sub 2} deliver useful means of altering optical properties as a function of temperature. Absorbers with tunable spectral response can find applications in sensor and detector applications, in which external stimulus such as heat, electrical signal, or light results in a change in the absorption spectrum and intensity.

  18. The surface structure of silver-coated gold nanocrystals and its influence on shape control

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Padmos, J. Daniel; Personick, Michelle L.; Tang, Qing; Duchesne, Paul N.; Jiang, De-en; Mirkin, Chad A.; Zhang, Peng

    2015-07-08

    Understanding the surface structure of metal nanocrystals with specific facet indices is important due to its impact on controlling nanocrystal shape and functionality. However, this is particularly challenging for halide-adsorbed nanocrystals due to the difficulty in analysing interactions between metals and light halides (for example, chloride). Here we uncover the surface structures of chloride-adsorbed, silver-coated gold nanocrystals with {111}, {110}, {310} and {720} indexed facets by X-ray absorption spectroscopy and density functional theory modelling. The silver–chloride, silver–silver and silver–gold bonding structures are markedly different between the nanocrystal surfaces, and are sensitive to their formation mechanism and facet type. A uniquemore »approach of combining the density functional theory and experimental/simulated X-ray spectroscopy further verifies the surface structure models and identifies the previously indistinguishable valence state of silver atoms on the nanocrystal surfaces. Overall, this work elucidates the thus-far unknown chloride–metal nanocrystal surface structures and sheds light onto the halide-induced growth mechanism of anisotropic nanocrystals.« less

  19. A hybrid DNA-templated gold nanocluster for enhanced enzymatic reduction of oxygen

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chakraborty, Saumen; Babanova, Sofia; Rocha, Reginaldo C.; Desireddy, Anil; Artyushkova, Kateryna; Boncella, Amy E.; Atanassov, Plamen; Martinez, Jennifer S.

    2015-08-19

    We report the synthesis and characterization of a new DNA-templated gold nanocluster (AuNC) of ~1 nm in diameter and possessing ~7 Au atoms. When integrated with bilirubin oxidase (BOD) and single walled carbon nanotubes (SWNTs), the AuNC acts as an enhancer of electron transfer (ET) and lowers the overpotential of electrocatalytic oxygen reduction reaction (ORR) by ~15 mV as compared to the enzyme alone. In addition, the presence of AuNC causes significant enhancements in the electrocatalytic current densities at the electrode. Control experiments show that such enhancement of ORR by the AuNC is specific to nanoclusters and not to plasmonicmore »gold particles. Rotating ring disk electrode (RRDE) measurements confirm 4e– reduction of O2 to H2O with minimal production of H2O2, suggesting that the presence of AuNC does not perturb the mechanism of ORR catalyzed by the enzyme. This unique role of the AuNC as enhancer of ET at the enzyme-electrode interface makes it a potential candidate for the development of cathodes in enzymatic fuel cells, which often suffer from poor electronic communication between the electrode surface and the enzyme active site. In conclusion, the AuNC displays phosphorescence with large Stokes shift and microsecond lifetime.« less

  20. Near-Edge X-Ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold

    SciTech Connect (OSTI)

    Willey, T.M.; Fabbri, J.D.; Lee, J.R.I.; Schreiner, P.R.; Fokin, A.A.; Tkachenko, B.A.; Fokina, N.A.; Dahl, J.E.P.; Carlson, R.M.K.; Vance, A.L.; Yang, W.; Terminello, L.J.; Buuren, T.van; Melosh, N.A.

    2009-05-26

    Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and ability to selectively functionalize this special class of nanodiamond materials opens new possibilities for surface modification, for high-efficiency field emitters in molecular electronics, as seed crystals for diamond growth, or as robust mechanical coatings. The properties of self-assembled monolayers (SAMs) of diamondoids are thus of fundamental interest for a variety of emerging applications. This paper presents the effects of thiol substitution position and polymantane order on diamondoid SAMs on gold using near-edge X-ray absorption fine structure spectroscopy (NEXAFS) and X-ray photoelectron spectroscopy (XPS). A framework to determine both molecular tilt and twist through NEXAFS is presented and reveals highly ordered diamondoid SAMs, with the molecular orientation controlled by the thiol location. C 1s and S 2p binding energies are lower in adamantane thiol than alkane thiols on gold by 0.67 {+-} 0.05 and 0.16 {+-} 0.04 eV, respectively. These binding energies vary with diamondoid monolayer structure and thiol substitution position, consistent with different degrees of steric strain and electronic interaction with the substrate. This work demonstrates control over the assembly, in particular the orientational and electronic structure, providing a flexible design of surface properties with this exciting new class of diamond nanoparticles.

  1. Near-Edge X-ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold

    SciTech Connect (OSTI)

    Willey, T M; Fabbri, J; Lee, J I; Schreiner, P; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J; Carlson, B; Vance, A L; Yang, W; Terminello, L J; van Buuren, T; Melosh, N

    2007-11-27

    Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and ability to selectively functionalize this special class of nanodiamond materials opens new possibilities for surface-modification, for high-efficiency field emitters in molecular electronics, as seed crystals for diamond growth, or as robust mechanical coatings. The properties of self-assembled monolayers (SAMs) of diamondoids are thus of fundamental interest for a variety of emerging applications. This paper presents the effects of thiol substitution position and polymantane order on diamondoid SAMs on gold using near-edge X-ray absorption fine structure spectroscopy (NEXAFS) and X-ray photoelectron spectroscopy (XPS). A framework to determine both molecular tilt and twist through NEXAFS is presented and reveals highly ordered diamondoid SAMs, with the molecular orientation controlled by the thiol location. C 1s and S 2p binding energies are lower in adamantane thiol than alkane thiols on gold by 0.67 {+-} 0.05 eV and 0.16 {+-} 0.04 eV respectively. These binding energies vary with diamondoid monolayer structure and thiol substitution position, consistent with different amounts of steric strain and electronic interaction with the substrate. This work demonstrates control over the assembly, in particular the orientational and electronic structure, providing a flexible design of surface properties with this exciting new class of diamond clusters.

  2. Stability and biocompatibility of photothermal gold nanorods after lyophilization and sterilization

    SciTech Connect (OSTI)

    Gomez, Leyre [Department of Chemical Engineering, Nanoscience Institute of Aragon (INA), C/ Mariano Esquillor, R and D Building, University of Zaragoza, 50018 Zaragoza (Spain); Cebrian, Virginia [CIBER de Bioingeniería, Biomateriales y Nanomedicina, CIBER-BBN, Zaragoza (Spain); Hospital Universitario La Paz-IdiPAZ, Paseo de la Castellana 261, 28046 Madrid (Spain); Martin-Saavedra, Francisco [Hospital Universitario La Paz-IdiPAZ, Paseo de la Castellana 261, 28046 Madrid (Spain); CIBER de Bioingeniería, Biomateriales y Nanomedicina, CIBER-BBN, Zaragoza (Spain); Arruebo, Manuel, E-mail: arruebom@unizar.es [Department of Chemical Engineering, Nanoscience Institute of Aragon (INA), C/ Mariano Esquillor, R and D Building, University of Zaragoza, 50018 Zaragoza (Spain); CIBER de Bioingeniería, Biomateriales y Nanomedicina, CIBER-BBN, Zaragoza (Spain); Vilaboa, Nuria [Hospital Universitario La Paz-IdiPAZ, Paseo de la Castellana 261, 28046 Madrid (Spain); CIBER de Bioingeniería, Biomateriales y Nanomedicina, CIBER-BBN, Zaragoza (Spain); Santamaria, Jesus, E-mail: Jesus.Santamaria@unizar.es [Department of Chemical Engineering, Nanoscience Institute of Aragon (INA), C/ Mariano Esquillor, R and D Building, University of Zaragoza, 50018 Zaragoza (Spain); CIBER de Bioingeniería, Biomateriales y Nanomedicina, CIBER-BBN, Zaragoza (Spain)

    2013-10-15

    Graphical abstract: - Highlights: • Morphological changes are observed for CTABr capped gold nanorods over time. • Polystyrenesulfonate (PSS) and polyethyleneglycol (PEG) coated nanorods are stable. • Re-suspendible and sterilizable colloids are prepared using those capping agents. • Those materials are efficient heat sinks potentially used in photothermal therapy. - Abstract: Suspensions in phosphate buffered saline (PBS) of gold nanorods stabilized with cetyltrimethyl ammonium chloride (CTABr), polystyrenesulfonate (PSS) and methyl-polyethyleneglycol-thiol (m-PEG-SH) have been prepared and the evolution of their colloidal stability and plasmonic response over time has been evaluated. Their performance after lyophilization, alcoholic sterilization and resuspension has also been characterized. Sub-cytotoxic doses on HeLa cells were calculated for the three surface functionalizations used. Their heating efficiency at different exposure times was also evaluated after being irradiated with near infrared light. The best results were obtained for m-PEG-SH stabilized rods, which were not only stable, sterilizable and lyophilizable, but also biocompatible at all doses tested, showing potential as a stable, re-suspendible and biocompatible hyperthermic agent.

  3. Biofabrication of discrete spherical gold nanoparticles using the metal-reducing bacterium, Shewanella oneidensis

    SciTech Connect (OSTI)

    Suresh, Anil K [ORNL; Pelletier, Dale A [ORNL; Wang, Wei [ORNL; Broich, Michael L [ORNL; Moon, Ji Won [ORNL; Gu, Baohua [ORNL; Allison, David P [ORNL; Joy, David Charles [ORNL; Phelps, Tommy Joe [ORNL; Doktycz, Mitchel John [ORNL

    2011-01-01

    Nanocrystallites have garnered substantial interest due to their varying applications including catalysis. Consequently important aspects related to control of shape/size and syntheses through economical and non-hazardous means are desirable. Highly efficient bioreduction based natural fabrication approaches that utilize microbes and or -plant extracts are poised to meet these needs. Here we show that the gamma- proteobacterium, Shewanella oneidensis MR-1, can reduce tetrachloro aurate (III) ions, producing discrete extracellular spherical gold nanocrystallites. The particles were homogeneous with multiple size distributions and produced under ambient conditions at high yield, 88% of theoretical maximum. Further characterization revealed that the particles consist of spheres in the size range of 2-50 nm, with an average of 12 5 nm. The nanoparticles were hydrophilic, biocompatible, and resisted aggregation even after several months. The particles are likely capped by a detachable protein/peptide coat. UV-vis and Fourier transform infrared spectroscopy, X-ray diffraction, energy dispersive X-ray spectra and transmission electron microscopy measurements confirmed the formation as well the crystalline nature of the nanoparticles. The antibacterial activity of these gold nanoparticles was assessed using Gram-negative (E. coli and S. oneidensis) and Gram-positive (B. subtilis) bacteria. Toxicity assessments divulged that the particles were neither toxic nor inhibitory to any of these bacteria.

  4. Selective photothermal efficiency of citrate capped gold nanoparticles for destruction of cancer cells

    SciTech Connect (OSTI)

    Raji, V. [Department of Biochemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram 695 581, Kerala (India)] [Department of Biochemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram 695 581, Kerala (India); Kumar, Jatish [Division of photochemistry and photobiology, National Institute for Interdisciplinary Sciences and Technology (CSIR), Thiruvananthapuram 695 019, Kerala (India)] [Division of photochemistry and photobiology, National Institute for Interdisciplinary Sciences and Technology (CSIR), Thiruvananthapuram 695 019, Kerala (India); Rejiya, C.S.; Vibin, M.; Shenoi, Vinesh N. [Department of Biochemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram 695 581, Kerala (India)] [Department of Biochemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram 695 581, Kerala (India); Abraham, Annie, E-mail: annieab2@yahoo.co.in [Department of Biochemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram 695 581, Kerala (India)] [Department of Biochemistry, University of Kerala, Kariavattom Campus, Thiruvananthapuram 695 581, Kerala (India)

    2011-08-15

    Gold nanoparticles are recently having much attention because of their increased applications in biomedical fields. In this paper, we demonstrated the photothermal efficacy of citrate capped gold nanoparticles (AuNPs) for the destruction of A431 cancer cells. Citrate capped AuNPs were synthesized successfully and characterized by UV-visible-NIR spectrophotometry and High Resolution Transmission Electron Microscopy (HR-TEM). Further, AuNPs were conjugated with epidermal growth factor receptor antibody (anti-EGFR) and applied for the selective photothermal therapy (PTT) of human epithelial cancer cells, A431. PTT experiments were conducted in four groups, Group I-control cells, Group II-cells treated with laser light alone, Group III-cells treated with unconjugated AuNP and further laser irradiation and Group IV-anti-EGFR conjugated AuNP treated cells irradiated by laser light. After laser irradiation, cell morphology changes that were examined using phase contrast microscopy along with the relevant biochemical parameters like lactate dehydrogenase activity, reactive oxygen species generation and caspase-3 activity were studied for all the groups to determine whether cell death occurs due to necrosis or apoptosis. From these results we concluded that, these immunotargeted nanoparticles could selectively induce cell death via ROS mediated apoptosis when cells were exposed to a low power laser light.

  5. Controllable synthesis of hollow mesoporous silica spheres and application as support of nano-gold

    SciTech Connect (OSTI)

    Wang, Tao; Ma, Weihua Shangguan, Junnan; Jiang, Wei; Zhong, Qin

    2014-07-01

    Hollow silica spheres with mesoporous structure were synthesized by sol–gel/emulsion method. In the process, the surfactant, cetyltrimethylammonium bromide (CTAB) was used to stabilize the oil droplet and also used as structure direct agent. The diameter of the hollow silica spheres, ranging from 895 nm to 157 nm, can be controlled by changing the ratio of ethanol to water and the concentration of the surfactant as well. The shell thickness of the spheres decreased when the ratio of ethanol to water decreased. The proposed mechanism of the formation of silica spheres could elucidate the experimental results well. Furthermore, the resultant hollow mesoporous silica spheres were then employed as support of nano-gold which was used to catalyze the isomerization reaction of propylene oxide to produce allyl alcohol. - Graphical abstract: It is the schematic mechanism for the formation of hollow mesoporous silica spheres. - Highlights: • The formation mechanism of the hollow spheres is proposed. • The isomerization of propylene oxide can be catalyzed by the nano-gold/SiO{sub 2}. • The hollow silica spheres can be prepared controllably.

  6. A method of measuring gold nanoparticle concentrations by x-ray fluorescence for biomedical applications

    SciTech Connect (OSTI)

    Wu Di; Li Yuhua; Wong, Molly D.; Liu Hong [Center for Bioengineering and School of Electrical and Computer Engineering, University of Oklahoma, Norman, Oklahoma 73019 (United States)

    2013-05-15

    Purpose: This paper reports a technique that enables the quantitative determination of the concentration of gold nanoparticles (GNPs) through the accurate detection of their fluorescence radiation in the diagnostic x-ray spectrum. Methods: Experimentally, x-ray fluorescence spectra of 1.9 and 15 nm GNP solutions are measured using an x-ray spectrometer, individually and within chicken breast tissue samples. An optimal combination of excitation and emission filters is determined to segregate the fluorescence spectra at 66.99 and 68.80 keV from the background scattering. A roadmap method is developed that subtracts the scattered radiation (acquired before the insertion of GNP solutions) from the signal radiation acquired after the GNP solutions are inserted. Results: The methods effectively minimize the background scattering in the spectrum measurements, showing linear relationships between GNP solutions from 0.1% to 10% weight concentration and from 0.1% to 1.0% weight concentration inside a chicken breast tissue sample. Conclusions: The investigation demonstrated the potential of imaging gold nanoparticles quantitatively in vivo for in-tissue studies, but future studies will be needed to investigate the ability to apply this method to clinical applications.

  7. Encapsulation of gold nanoclusters in silica materials via an inverse micelle/sol-gel synthesis

    SciTech Connect (OSTI)

    Martino, A.; Kawola, J.S.; Loy, D.A. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); Yamanaka, S.A. [Texas Instruments, Dallas, TX (United States)] [Texas Instruments, Dallas, TX (United States)

    1997-02-01

    Nanometer-sized gold particles were encapsulated in the micropores of xerogels and aerogels. The synthesis involves the sequential reduction of a gold salt followed by sol-gel processing in an inverse micelle solution. The inverse micelle solution solubilizes the metal salt and provides a microreactor for the nucleation, growth, and stabilization of the nanometer-sized clusters. Hydrolysis and condensation of an added siloxane precursor produces a wet gel embedding the particles. Characterization of the particle size and composition and the particle growth process was completed with transmission electron microscopy (TEM), electron diffraction, and UV-visible absorption spectrometry. Characterization of the gel surface areas was completed with N{sub 2} porosimetry. Material properties determined as a function of the gel precursor (TEOS vs a prehydrolyzed form of TEOS), the water to gel precursor reaction stoichiometry, and surfactant concentration are discussed in terms of the unique solution chemistry occurring in the microheterogeneous inverse micelle solutions. 73 refs., 7 figs., 1 tab.

  8. The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

    SciTech Connect (OSTI)

    Peter Zalupski; Rocklan McDowell; Guy Dutech

    2014-10-01

    Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

  9. Electron backscatter diffraction analysis of gold nanoparticles on Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7??}

    SciTech Connect (OSTI)

    Bochmann, A.; Teichert, S.; Katzer, C.; Schmidl, F.

    2015-06-07

    It has been shown recently that the incorporation of gold nanoparticles into Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7??} enhances the superconducting properties of this material in a significant way. Previous XRD and TEM investigations suggest different crystallographic relations of the gold nanoparticles with respect to the epitaxial Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7??}. Here, detailed investigations of the crystal orientations for a large ensemble of gold nanoparticles with electron backscatter diffraction are reported. The average size of the gold nanoparticles is in the range of 60?nm–80?nm. We identified five different types of heteroepitaxial relationships between the gold nanoparticles and the superconductor film, resulting in complex pole figures. The observed different types of crystallographic orientations are discussed based on good lattice matching and the formation of low energy interfaces.

  10. Adhesion and Atomic Structures of Gold on Ceria Nanostructures:The Role of Surface Structure and Oxidation State of Ceria Supports

    SciTech Connect (OSTI)

    Lin, Yuyuan [Northwestern University, Evanston; Wu, Zili [ORNL; Wen, Jianguo [Argonne National Laboratory (ANL); Poeppelmeier, Kenneth R [Northwestern University, Evanston; Marks, Laurence D [Northwestern University, Evanston

    2015-01-01

    Recent advances in heterogeneous catalysis have demonstrated that oxides supports with the same material but different shapes can result in metal catalysts with distinct catalytic properties. The shape-dependent catalysis was not well-understood owing to the lack of direct visualization of the atomic structures at metal-oxide interface. Herein, we utilized aberration-corrected electron microscopy and revealed the atomic structures of gold particles deposited on ceria nanocubes and nanorods with {100} or {111} facets exposed. For the ceria nanocube support, gold nanoparticles have extended atom layers at the metal-support interface. In contrast, regular gold nanoparticles and rafts are present on the ceria nanorod support. After hours of water gas shift reaction, the extended gold atom layers and rafts vanish, which is associated with the decrease of the catalytic activities. By understanding the atomic structures of the support surfaces, metal-support interfaces, and morphologies of the gold particles, a direct structure-property relationship is established.

  11. UC's Blue and Gold Opportunity Plan will cover your educational and student services fees with a combination of grants and scholarships, if you are a California resident whose family earns less than

    E-Print Network [OSTI]

    Grether, Gregory

    UC's Blue and Gold Opportunity Plan will cover your educational and student services fees,000 and if you qualify for financial aid. Blue and Gold Opportunity Plan will cover $12,192 for 2011-12 and $12 in an academic year term. Blue and Gold Plan does not extend to summer months. Meet basic, non

  12. Gold Nanoparticles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUseful

  13. Plasmon-enhanced polymer photovoltaic cells based on large aspect ratio gold nanorods and the related working mechanism

    E-Print Network [OSTI]

    Xiong, Qihua

    Plasmon-enhanced polymer photovoltaic cells based on large aspect ratio gold nanorods-to-electrical conversion performances in polymer photovoltaic cells. Totally different improvement factors in short AIP Publishing LLC. [http://dx.doi.org/10.1063/1.4880575] Organic photovoltaic (OPV) cells

  14. Exploring the structure and chemical activity of 2-D gold islands on graphene moire/Ru(0001)

    E-Print Network [OSTI]

    Goodman, Wayne

    Exploring the structure and chemical activity of 2-D gold islands on graphene moire/Ru(0001) Ye Xu May 2011 DOI: 10.1039/c1fd00030f Au deposited on Ru(0001)-supported extended, continuous graphene. These Au islands conform to the corrugation of the underlying graphene and display commensurate moire

  15. Effect of shell thickness on small-molecule solar cells enhanced by dual plasmonic gold-silica nanorods

    E-Print Network [OSTI]

    Xiong, Qihua

    enhancement in hybrid organic/Si heterojunction solar cells enabled by embedded gold nanoparticles Appl. Phys of a small-molecule organic solar cell. At optimal (1 wt. %) concentration, Au-silica nanorods with 5 nm. [http://dx.doi.org/10.1063/1.4896516] Plasmonic organic solar cells (OSCs) have been inten- sively

  16. Effect of shell thickness on small-molecule solar cells enhanced by dual plasmonic gold-silica nanorods

    E-Print Network [OSTI]

    Demir, Hilmi Volkan

    of a small-molecule organic solar cell. At optimal (1 wt. %) concentration, Au-silica nanorods with 5 nm. [http://dx.doi.org/10.1063/1.4896516] Plasmonic organic solar cells (OSCs) have been inten- sivelyEffect of shell thickness on small-molecule solar cells enhanced by dual plasmonic gold

  17. Uniform 2 nm gold nanoparticles supported on iron oxides as active catalysts for CO oxidation reaction: Structure-activity relationship

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Yu; Senanayake, Sanjaya; Gu, Dong; Jin, Zhao; Du, Pei -Pei; Si, Rui; Xu, Wen -Qian; Huang, Yu -Ying; Tao, Jing; Song, Qi -Sheng; et al

    2015-01-12

    Uniform Au nanoparticles (~2 nm) with narrow size-distribution (standard deviation: 0.5–0.6 nm) supported on both hydroxylated (Fe_OH) and dehydrated iron oxide (Fe_O) have been prepared by either deposition-precipitation (DP) or colloidal-deposition (CD) methods. Different structural and textural characterizations were applied to the dried, calcined and used gold-iron oxide samples. The transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) described the high homogeneity in the supported Au nanoparticles. The ex-situ and in-situ X-ray absorption fine structure (XAFS) characterization monitored the electronic and short-range local structure of active gold species. The synchrotron-based in-situ X-ray diffraction (XRD), together with the corresponding temperature-programmed reductionmore »by hydrogen (H?-TPR), indicated a structural evolution of the iron-oxide supports, correlating to their reducibility. An inverse order of catalytic activity between DP (Au/Fe_OH Au/Fe_O) was observed. Effective gold-support interaction results in a high activity for gold nanoparticles, locally generated by the sintering of dispersed Au atoms on the oxide support in the DP synthesis, while a hydroxylated surface favors the reactivity of externally introduced Au nanoparticles on Fe_OH support for the CD approach. This work reveals why differences in the synthetic protocol translate to differences in the catalytic performance of Au/FeOx catalysts with very similar structural characteristics in CO oxidation.« less

  18. Infrared reflection absorption spectroscopy studies of CO adsorption on titania thin films and gold clusters supported on titania 

    E-Print Network [OSTI]

    White, Kevin Rodney

    1999-01-01

    absorptions at 2180cm?¹ and 2110cm?¹. The 2180cm?¹ peak is assigned to CO adsorbed on Ti?? sites The absorption at 2110cm?¹ appears to have at least two component peaks that may be from CO adsorbed on top of gold clusters and CO adsorbed at Au-TiO? interface...

  19. In Situ Study of Colloid Crystallization in Constrained Robert Kori Golding, Patrick C. Lewis, and Eugenia Kumacheva*

    E-Print Network [OSTI]

    Sargent, Edward H. "Ted"

    In Situ Study of Colloid Crystallization in Constrained Geometry Robert Kori Golding, Patrick C-drivencolloidcrystalgrowthonpatternedconductivesurfaces. Theelectrodewaspatternedwithdielectricribsandconductivegrooves;thegroovewidthwascommensurate or incommensurate with a two-dimensional colloid crystal lattice particles. Our experiments reveal the following: (i) Colloid crystal growth occurs under the action

  20. A novel class of phosphorescent gold(III) alkynyl-based organic light-emitting devices with tunable colour{

    E-Print Network [OSTI]

    in the roles of electrophosphorescent emitters or dopants of organic light-emitting diodes (OLEDs) with highA novel class of phosphorescent gold(III) alkynyl-based organic light-emitting devices with tunable brightness and efficiency. There have been significant improvements in OLED efficiencies by using

  1. Tunable trimers: Using temperature and pressure to control luminescent emission in gold(I) pyrazolate-based trimers

    SciTech Connect (OSTI)

    Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M.; Hatcher, Lauren E.; Parlett, Andrew; Shepherd, Helena J.; Christensen, Jeppe; Teat, Simon J.; Intissar, Mourad; Rodrigue-Witchel, Alexandre; Suffren, Yan; Reber, Christian; Hendon, Christopher H.; Tiana, Davide; Walsh, Aron; Raithby, Paul R.

    2014-10-21

    A systematic investigation into the relationship between the solid-state luminescence and the intermolecular Au???Au interactions in a series of pyrazolate-based gold(I) trimers; tris(?2-pyrazolato-N,N')-tri-gold(I) (1), tris(?2-3,4,5-trimethylpyrazolato-N,N')-tri-gold(I) (2), tris(?2-3-methyl-5-phenylpyrazolato-N,N')-tri-gold(I) (3) and tris(?2-3,5-diphenylpyrazolato-N,N')-tri-gold(I) (4) has been carried out using variable temperature and high pressure X-ray crystallography, solid-state emission spectroscopy, Raman spectroscopy and computational techniques. Single-crystal X-ray studies show that there is a significant reduction in the intertrimer Au???Au distances both with decreasing temperature and increasing pressure. In the four complexes, the reduction in temperature from 293 to 100 K is accompanied by a reduction in the shortest intermolecular Au???Au contacts of between 0.04 and 0.08 Å. The solid-state luminescent emission spectra of 1 and 2 display a red shift with decreasing temperature or increasing pressure. Compound 3 does not emit under ambient conditions but displays increasingly red-shifted luminescence upon cooling or compression. Compound 4 remains emissionless, consistent with the absence of intermolecular Au???Au interactions. The largest pressure induced shift in emission is observed in 2 with a red shift of approximately 630 cm-1 per GPa between ambient and 3.80 GPa. The shifts in all the complexes can be correlated with changes in Au???Au distance observed by diffraction.

  2. Tunable trimers: Using temperature and pressure to control luminescent emission in gold(I) pyrazolate-based trimers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M.; Hatcher, Lauren E.; Parlett, Andrew; Shepherd, Helena J.; Christensen, Jeppe; Teat, Simon J.; Intissar, Mourad; Rodrigue-Witchel, Alexandre; et al

    2014-10-21

    A systematic investigation into the relationship between the solid-state luminescence and the intermolecular Au???Au interactions in a series of pyrazolate-based gold(I) trimers; tris(?2-pyrazolato-N,N')-tri-gold(I) (1), tris(?2-3,4,5-trimethylpyrazolato-N,N')-tri-gold(I) (2), tris(?2-3-methyl-5-phenylpyrazolato-N,N')-tri-gold(I) (3) and tris(?2-3,5-diphenylpyrazolato-N,N')-tri-gold(I) (4) has been carried out using variable temperature and high pressure X-ray crystallography, solid-state emission spectroscopy, Raman spectroscopy and computational techniques. Single-crystal X-ray studies show that there is a significant reduction in the intertrimer Au???Au distances both with decreasing temperature and increasing pressure. In the four complexes, the reduction in temperature from 293 to 100 K is accompanied by a reduction in the shortest intermolecular Au???Au contacts of between 0.04more »and 0.08 Å. The solid-state luminescent emission spectra of 1 and 2 display a red shift with decreasing temperature or increasing pressure. Compound 3 does not emit under ambient conditions but displays increasingly red-shifted luminescence upon cooling or compression. Compound 4 remains emissionless, consistent with the absence of intermolecular Au???Au interactions. The largest pressure induced shift in emission is observed in 2 with a red shift of approximately 630 cm-1 per GPa between ambient and 3.80 GPa. The shifts in all the complexes can be correlated with changes in Au???Au distance observed by diffraction.« less

  3. Dynamics of charge clouds ejected from laser-induced warm dense gold nanofilms

    SciTech Connect (OSTI)

    Zhou, Jun; Li, Junjie; Correa, Alfredo A.; Tang, Shao; Ping, Yuan; Ogitsu, Tadashi; Li, Dong; Zhou, Qiong; Cao, Jianming

    2014-10-24

    We report the first systematic study of the ejected charge dynamics surrounding laser-produced 30-nm warm dense gold films using single-shot femtosecond electron shadow imaging and deflectometry. The results reveal a two-step dynamical process of the ejected electrons under the high pump fluence conditions: an initial emission and accumulation of a large amount of electrons near the pumped surface region followed by the formation of hemispherical clouds of electrons on both sides of the film, which are escaping into the vacuum at a nearly isotropic and constant velocity with an unusually high kinetic energy of more than 300 eV. We also developed a model of the escaping charge distribution that not only reproduces the main features of the observed charge expansion dynamics but also allows us to extract the number of ejected electrons remaining in the cloud.

  4. ALD Functionalized Nanoporous Gold: Thermal Stability, Mechanical Properties, and Catalytic Activity

    SciTech Connect (OSTI)

    Biener, M M; Biener, J; Wichmann, A; Wittstock, A; Baumann, T F; Baeumer, M; Hamza, A V

    2011-03-24

    Nanoporous metals have many technologically promising applications but their tendency to coarsen limits their long-term stability and excludes high temperature applications. Here, we demonstrate that atomic layer deposition (ALD) can be used to stabilize and functionalize nanoporous metals. Specifically, we studied the effect of nanometer-thick alumina and titania ALD films on thermal stability, mechanical properties, and catalytic activity of nanoporous gold (np-Au). Our results demonstrate that even only one-nm-thick oxide films can stabilize the nanoscale morphology of np-Au up to 1000 C, while simultaneously making the material stronger and stiffer. The catalytic activity of np-Au can be drastically increased by TiO{sub 2} ALD coatings. Our results open the door to high temperature sensor, actuator, and catalysis applications and functionalized electrodes for energy storage and harvesting applications.

  5. Nanoscale Laser-Induced Spallation in SiO2 Films Containing Gold Nanoparticles

    SciTech Connect (OSTI)

    Kudryashov, S.I.; Allen, S.D.; Papernov, S.; Schmid, A.W.

    2006-02-16

    A phenomenological theory of ultraviolet pulsed-laser-induced spallation is proposed to interpret crater formation in SiO2 thin films containing absorbing 18.5-nm gold particles. The theory considers a spherical thermoacoustic stress wave propagating from a thermal source produced by laser-energy absorption inside the particle and surrounding ionized volume. Calculations show that the tensile stress associated with such an acoustic wave may exceed the local strength of the material and cause fracture and spallation of the top film portion. The theory provides an explanation of the experimentally observed complex (two-cone) shape of craters formed in the film with particle-lodging depth exceeding 110 nm. Theoretical estimates for the threshold stress amplitude and peak temperature in the thermal source are in qualitative agreement with the experimental observations.

  6. Dynamics of charge clouds ejected from laser-induced warm dense gold nanofilms

    SciTech Connect (OSTI)

    Zhou, Jun; Li, Junjie; Correa, Alfredo A.; Tang, Shao; Ping, Yuan; Ogitsu, Tadashi; Li, Dong; Zhou, Qiong; Cao, Jianming

    2014-10-24

    We report the first systematic study of the ejected charge dynamics surrounding laser-produced 30- nm warm dense gold films using single-shot femtosecond electron shadow imaging and deflectometry. The results reveal a two-step dynamical process of the ejected electrons under the high pump fluence conditions: an initial emission and accumulation of a large amount of electrons near the pumped surface region followed by the formation of hemispherical clouds of electrons on both sides of the film, which are escaping into the vacuum at a nearly isotropic and constant velocity with an unusually high kinetic energy of more than 300 eV. We also developed a model of the escaping charge distribution that not only reproduces the main features of the observed charge expansion dynamics but also allows us to extract the number of ejected electrons remaining in the cloud.

  7. Third-order nonlinear optical response of colloidal gold nanoparticles prepared by sputtering deposition

    SciTech Connect (OSTI)

    Castro, Hemerson P. S.; Alencar, Márcio A. R. C.; Hickmann, Jandir M.; Wender, Heberton; Department of Physics, Universidade Federal do Mato Grosso do Sul, 79070-900, Campo Grande ; Teixeira, Sergio R.; Dupont, Jairton

    2013-11-14

    The nonlinear optical responses of gold nanoparticles dispersed in castor oil produced by sputtering deposition were investigated, using the thermally managed Z-scan technique. Particles with spherical shape and 2.6 nm of average diameter were obtained and characterized by transmission electron microscopy and small angle X-ray scattering. This colloid was highly stable, without the presence of chemical impurities, neither stabilizers. It was observed that this system presents a large refractive third-order nonlinear response and a negligible nonlinear absorption. Moreover, the evaluation of the all-optical switching figures of merit demonstrated that the colloidal nanoparticles prepared by sputtering deposition have a good potential for the development of ultrafast photonic devices.

  8. Microfiber-based gold nanorods as saturable absorber for femtosecond pulse generation in a fiber laser

    SciTech Connect (OSTI)

    Wang, Xu-De [Laboratory of Nanophotonic Functional Materials and Devices, School of Information and Optoelectronic Science and Engineering, South China Normal University, Guangzhou, Guangdong 510006 (China); School of Physics and Electronic Information, Huaibei Normal University, Huaibei, Anhui 235000 (China); Luo, Zhi-Chao; Liu, Hao; Liu, Meng; Luo, Ai-Ping, E-mail: luoaiping@scnu.edu.cn; Xu, Wen-Cheng, E-mail: xuwch@scnu.edu.cn [Laboratory of Nanophotonic Functional Materials and Devices, School of Information and Optoelectronic Science and Engineering, South China Normal University, Guangzhou, Guangdong 510006 (China)

    2014-10-20

    We reported on the femtosecond pulse generation from an erbium-doped fiber (EDF) laser by using microfiber-based gold nanorods (GNRs) as saturable absorber (SA). By virtue of the geometric characteristic of microfiber-based GNRs, the optical damage threshold of GNRs-SA could be greatly enhanced. The microfiber-based GNRs-SA shows a modulation depth of 4.9% and a nonsaturable loss of 21.1%. With the proposed GNRs-SA, the fiber laser emitted a mode-locked pulse train with duration of ?887 fs. The obtained results demonstrated that the GNRs deposited microfiber could indeed serve as a high-performance SA towards the practical applications in the field of ultrafast photonics.

  9. Dynamics of charge clouds ejected from laser-induced warm dense gold nanofilms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Jun; Li, Junjie; Correa, Alfredo A.; Tang, Shao; Ping, Yuan; Ogitsu, Tadashi; Li, Dong; Zhou, Qiong; Cao, Jianming

    2014-10-24

    We report the first systematic study of the ejected charge dynamics surrounding laser-produced 30-nm warm dense gold films using single-shot femtosecond electron shadow imaging and deflectometry. The results reveal a two-step dynamical process of the ejected electrons under the high pump fluence conditions: an initial emission and accumulation of a large amount of electrons near the pumped surface region followed by the formation of hemispherical clouds of electrons on both sides of the film, which are escaping into the vacuum at a nearly isotropic and constant velocity with an unusually high kinetic energy of more than 300 eV. We alsomore »developed a model of the escaping charge distribution that not only reproduces the main features of the observed charge expansion dynamics but also allows us to extract the number of ejected electrons remaining in the cloud.« less

  10. Probing the photoluminescence properties of gold nanoclusters by fluorescence lifetime correlation spectroscopy

    SciTech Connect (OSTI)

    Yuan, C. T., E-mail: ctyuan@cycu.edu.tw; Lin, T. N.; Shen, J. L. [Department of Physics, Chung Yuan Christian University, Chung-Li, Taiwan (China) [Department of Physics, Chung Yuan Christian University, Chung-Li, Taiwan (China); Center for Biomedical Technology, Chung Yuan Christian University, Taiwan (China); Lin, C. A.; Chang, W. H. [Center for Biomedical Technology, Chung Yuan Christian University, Taiwan (China) [Center for Biomedical Technology, Chung Yuan Christian University, Taiwan (China); Department of Biomedical Engineering, Chung Yuan Christian University, Taiwan (China); Cheng, H. W. [Department of Engineering and system science, National Tsing Hua University, Taiwan (China)] [Department of Engineering and system science, National Tsing Hua University, Taiwan (China); Tang, J., E-mail: jautang@gate.sinica.edu.tw [Research Center for Applied Sciences, Academia Sinica, Taiwan (China)

    2013-12-21

    Gold nanoclusters (Au NCs) have attracted much attention for promising applications in biological imaging owing to their tiny sizes and biocompatibility. So far, most efforts have been focused on the strategies for fabricating high-quality Au NCs and then characterized by conventional ensemble measurement. Here, a fusion single-molecule technique combining fluorescence correlation spectroscopy and time-correlated single-photon counting can be successfully applied to probe the photoluminescence (PL) properties for sparse Au NCs. In this case, the triplet-state dynamics and diffusion process can be observed simultaneously and the relevant time constants can be derived. This work provides a complementary insight into the PL mechanism at the molecular levels for Au NCs in solution.

  11. Selective excitation of bright and dark plasmonic resonances of single gold nanorods

    E-Print Network [OSTI]

    Demichel, O; Francs, G Colas des; Bouhelier, A; Hertz, E; Billard, F; de Fornel, F; Cluzel, B

    2015-01-01

    Plasmonic dark modes are pure near-field resonances since their dipole moments are vanishing in far field. These modes are particularly interesting to enhance nonlinear light-matter interaction at the nanometer scale because radiative losses are mitigated therefore increasing the intrinsic lifetime of the resonances. However, the excitation of dark modes by standard far field approaches is generally inefficient because the symmetry of the electromagnetic near-field distribution has a poor overlap with the excitation field. Here, we demonstrate the selective optical excitation of bright and dark plasmonic modes of single gold nanorods by spatial phase-shaping the excitation beam. Using two-photon luminescence measurements, we unambiguously identify the symmetry and the order of the emitting modes and analyze their angular distribution by Fourier-space imaging.

  12. Kondo decoherence : finding the right spin model for iron impurities in gold and silver.

    SciTech Connect (OSTI)

    Costi, T. A.; Bergqvist, L.; Weichselbaum, A.; von Delft, J.; Micklitz, T.; Rosch, A.; Mavropoulos, P.; Dederichs, P. H.; Mallet, F.; Saminadayar, L.; Bauerle, C. (Materials Science Division); (Forschungszentrum Julich); (Ludwig-Maximilians-Univ. Munchen); (Univ. of Cologne); (CNRS); (Univ. Joseph Fourier); (Inst. Univ. de France)

    2009-02-01

    We exploit the decoherence of electrons due to magnetic impurities, studied via weak localization, to resolve a long-standing question concerning the classic Kondo systems of Fe impurities in the noble metals gold and silver: which Kondo-type model yields a realistic description of the relevant multiple bands, spin, and orbital degrees of freedom? Previous studies suggest a fully screened spin S Kondo model, but the value of S remained ambiguous. We perform density functional theory calculations that suggest S=3/2. We also compare previous and new measurements of both the resistivity and decoherence rate in quasi-one-dimensional wires to numerical renormalization group predictions for S=1/2, 1, and 3/2, finding excellent agreement for S=3/2.

  13. Two-photon induced fabrication of gold microstructures in polystyrene sulfonate thin films using a ruthenium(II) dye as photoinitiator

    SciTech Connect (OSTI)

    Vurth, Laeticia; Baldeck, Patrice; Stephan, Olivier [Laboratoire de Spectrometrie Physique, Universite Joseph Fourier, CNRS (UMR 5588), BP 87, 38402 Saint Martin d'heres Cedex (France); Vitrant, Guy [Institut Microelectronique Electromagnetisme et Photonique, ENSERG-INPG, CNRS (UMR 5130), BP 257, 38016 Grenoble Cedex 1 (France)

    2008-04-28

    Gold microstructures are produced with a femtosecond laser in thin films of a polystyrene sulfonate matrix containing gold ions. Two-photon induced metal reduction is obtained by addition of 0.1 wt % of ruthenium(II)tris(bipyridine) in the formulation. Laser power is reduced to 5 mW, thereby limiting thermal effects. Lines of typically 150 nm heights and 1 {mu}m widths are fabricated as well as freestanding bidimensional structures. An additional electroless plating step produces gold structures with conductivities only ten times smaller than the bulk metal.

  14. Temporal XML? SQL Strikes Back! Fusheng Wang

    E-Print Network [OSTI]

    Zaniolo, Carlo

    gained wide acceptance by all DBMS vendors, and the second is the introduction of SQL:2003 [5, 6, 7 the history of relational databases by timestamping the grouped attribute histories of each table, and XQuery

  15. Strike-Slip | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing CapacityVectren) JumpandStereoNewCreek FormationStratovolcanoOpenStress

  16. Formation and Optical Properties of Cylindrical Gold Nanoshells on Silica and Titania Steven J. Limmer, Tammy P. Chou, and Guozhong Cao*

    E-Print Network [OSTI]

    Cao, Guozhong

    -hydrolyzed by heating in water. 3-Aminopropyl- trimethoxysilane is reacted with the surface hydroxyl groups, self-assembling amine functionality on the surface of the rods. These groups act as anchoring sites for the gold, which

  17. SU-E-T-645: Dose Enhancement to Cell Nucleus Due to Hard Collisions of Protons with Electrons in Gold Nanospheres

    SciTech Connect (OSTI)

    Eley, J; Krishnan, S

    2014-06-15

    Purpose: The purpose of this study was to investigate the theoretical dose enhancement to a cell nucleus due to increased fluence of secondary electrons when gold nanospheres are present in the cytoplasm during proton therapy. Methods: We modeled the irradiation of prostate cancer cells using protons of variable energies when 10,000 gold nanoparticles, each with radius of 10 nm, were randomly distributed in the cytoplasm. Using simple analytical equations, we calculated the increased mean dose to the cell nucleus due to secondary electrons produced by hard collisions of 0.1, 1, 10, and 100 MeV protons with orbital electrons in gold. We only counted electrons with kinetic energy higher than 1 keV. In addition to calculating the increase in the mean dose to the cell nucleus, we also calculated the increase in local dose in the “shadow,” i.e., the umbra, of individual gold nanospheres due to forward scattered electrons. Results: For proton energies of 0.1, 1, 10, and 100 MeV, we calculated increases to the mean nuclear dose of 0.15, 0.09, 0.05, and 0.04%, respectively. When we considered local dose increases in the shadows of individual gold spheres, we calculated local dose increases of 5.5, 3.2, 1.9, and 1.3%, respectively. Conclusion: We found negligible, less than 0.2%, increases in the mean dose to the cell nucleus due to electrons produced by hard collisions of protons with electrons in gold nanospheres. However, we observed increases up to 5.5% in the local dose in the shadow of gold nanospheres. Considering the shadow radius of 10 nm, these local dose enhancements may have implications for slightly increased probability of clustered DNA damage when gold nanoparticles are close to the nuclear membrane.

  18. Gold nanoparticles-based brachytherapy enhancement in choroidal melanoma using a full Monte Carlo modelling of human eye

    E-Print Network [OSTI]

    Asadi, Somayeh; Masoudi, S Farhad; Rahmani, Faezeh

    2014-01-01

    Materials of high atomic number such as gold, can provide a high probability for photon interaction by photoelectric effects during radiation therapy. In cancer therapy, the object of brachytherapy as a kind of radiotherapy is to deliver adequate radiation dose to tumor while sparing surrounding healthy tissue. Several studies demonstrated that the preferential accumulation of gold nanoparticles within the tumor can enhance the absorbed dose by the tumor without increasing the radiation dose delivered externally. Accordingly, the required time for tumor irradiation decreases as the estimated adequate radiation dose for tumor is provided following this method. The dose delivered to healthy tissue is reduced when the time of irradiation is decreased. Hear, GNPs effects on choroidal Melanoma dosimetry is discussed by Monte Carlo study. Monte Carlo Ophthalmic brachytherapy dosimetry usually, is studied by simulation of water phantom. Considering the composition and density of eye material instead of water in thes...

  19. Coverage Dependent Charge Reduction of Cationic Gold Clusters on Surfaces Prepared Using Soft Landing of Mass-selected Ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2012-11-29

    The ionic charge state of monodisperse cationic gold clusters on surfaces may be controlled by selecting the coverage of mass-selected ions soft landed onto a substrate. Polydisperse diphosphine-capped gold clusters were synthesized in solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine in the presence of 1,3-bis(diphenylphosphino)propane. The polydisperse gold clusters were introduced into the gas phase by electrospray ionization and mass selection was employed to select a multiply charged cationic cluster species (Au11L53+, m/z = 1409, L = 1,3-bis(diphenylphosphino)propane) which was delivered to the surfaces of four different self-assembled monolayers on gold (SAMs) at coverages of 1011 and 1012 clusters/mm2. Employing the spatial profiling capabilities of in-situ time-of-flight secondary ion mass spectrometry (TOF-SIMS) it is shown that, in addition to the chemical functionality of the monolayer (as demonstrated previously: ACS Nano, 2012, 6, 573) the coverage of cationic gold clusters on the surface may be used to control the distribution of ionic charge states of the soft-landed multiply charged clusters. In the case of a 1H,1H,2H,2H-perfluorodecanethiol SAM (FSAM) almost complete retention of charge by the deposited Au11L53+ clusters was observed at a lower coverage of 1011 clusters/mm2. In contrast, at a higher coverage of 1012 clusters/mm2, pronounced reduction of charge to Au11L52+ and Au11L5+ was observed on the FSAM. When soft landed onto 16- and 11-mercaptohexadecanoic acid surfaces on gold (16,11-COOH-SAMs), the mass-selected Au11L53+ clusters exhibited partial reduction of charge to Au11L52+ at lower coverage and additional reduction of charge to both Au11L52+ and Au11L5+ at higher coverage. The reduction of charge was found to be more pronounced on the surface of the shorter (thinner) C11 than the longer (thicker) C16-COOH-SAM. On the surface of the 1-dodecanethiol (HSAM) monolayer, the most abundant charge state was found to be Au11L52+ at lower coverage and Au11L5+ at higher coverage, respectively. A coverage-dependent electron tunneling mechanism is proposed to account for the observed reduction of charge of mass-selected multiply charged gold clusters soft landed on SAMs. The results demonstrate that one of the critical parameters that influence the chemical and physical properties of supported metal clusters, ionic charge state, may be controlled by selecting the coverage of charged species soft landed onto surfaces.

  20. Uncertainty Analysis of Melting and Resolidification of Gold Film Irradiated by Nano- to Femtosecond Lasers Using Stochastic Method

    E-Print Network [OSTI]

    Afrin, Nazia; Chen, J K

    2015-01-01

    A sample-based stochastic model is presented to investigate the effects of uncertainties of various input parameters, including laser fluence, laser pulse duration, thermal conductivity constants for electron, and electron-lattice coupling factor, on solid-liquid phase change of gold film under nano- to femtosecond laser irradiation. Rapid melting and resolidification of a free standing gold film subject to nano- to femtosecond laser are simulated using a two-temperature model incorporated with the interfacial tracking method. The interfacial velocity and temperature are obtained by solving the energy equation in terms of volumetric enthalpy for control volume. The convergence of variance (COV) is used to characterize the variability of the input parameters, and the interquartile range (IQR) is used to calculate the uncertainty of the output parameters. The IQR analysis shows that the laser fluence and the electron-lattice coupling factor have the strongest influences on the interfacial location, velocity, an...

  1. Structural Modification of Single Wall and Multiwalled Carbon Nanotubes under Carbon, Nickel and Gold Ion Beam Irradiation

    SciTech Connect (OSTI)

    Jeet, Kiran; Jindal, V. K.; Dharamvir, Keya; Bharadwaj, L. M.

    2011-12-12

    Thin film samples of carbon nanotubes were irradiated with ion beam of carbon, nickel and gold. The irradiation results were characterized using Raman Spectroscopy. Modifications of the disorder mode (D mode) and the tangential mode (G mode) under different irradiation fluences were studied in detail. Raman results of carbon ion beam indicate the interesting phenomenon of ordering of the system under irradiation. Under the effect of nickel and gold ion irradiation, the structural evolution of CNTs occurs in three different stages. At lower fluences the process of healing occurs; at intermediate fluences damages on the surface of CNTs occurs and finally at very high fluences of the order of 1x10{sup 14} ions/cm{sup 2} the system gets amorphised.

  2. Electrocatalysts having platium monolayers on palladium, palladium alloy, and gold alloy core-shell nanoparticles, and uses thereof

    DOE Patents [OSTI]

    Adzic, Radoslav (Setauket, NY); Mo, Yibo (Naperville, IL); Vukmirovic, Miomir (Port Jefferson Station, NY); Zhang, Junliang (Rochester, NY)

    2010-12-21

    The invention relates to platinum-coated particles useful as fuel cell electrocatalysts. The particles are composed of a noble metal or metal alloy core at least partially encapsulated by an atomically thin surface layer of platinum atoms. The invention particularly relates to such particles having a palladium, palladium alloy, gold alloy, or rhenium alloy core encapsulated by an atomic monolayer of platinum. In other embodiments, the invention relates to fuel cells containing these electrocatalysts and methods for generating electrical energy therefrom.

  3. Adsorption Mechanisms of Trivalent Gold onto Iron Oxy-Hydroxides: From the Molecular Scale to the Model

    SciTech Connect (OSTI)

    Cances, Benjamin; Benedetti, Marc; Farges, Francois; Brown, Gordon E. Jr.

    2007-02-02

    Gold is a highly valuable metal that can concentrate in iron-rich exogenetic horizons such as laterites. An improved knowledge of the retention mechanisms of gold onto highly reactive soil components such as iron oxy-hydroxides is therefore needed to better understand and predict the geochemical behavior of this element. In this study, we use EXAFS information and titration experiments to provide a realistic thermochemical description of the sorption of trivalent gold onto iron oxy-hydroxides. Analysis of Au LIII-edge XAFS spectra shows that aqueous Au(III) adsorbs from chloride solutions onto goethite surfaces as inner-sphere square-planar complexes (Au(III)(OH,Cl)4), with dominantly OH ligands at pH > 6 and mixed OH/Cl ligands at lower pH values. In combination with these spectroscopic results, Reverse Monte Carlo simulations were used to constraint the possible sorption sites on the surface of goethite. Based on this structural information, we calculated sorption isotherms of Au(III) on Fe oxy-hydroxides surfaces, using the CD-MUSIC (Charge Distribution - MUlti SIte Complexation) model. The various Au(III)-sorbed species were identified as a function of pH, and the results of these EXAFS+CD-MUSIC models are compared with titration experiments. The overall good agreement between the predicted and measured structural models shows the potential of this combined approach to better model sorption processes of transition elements onto highly reactive solid surfaces such as goethite and ferrihydrite.

  4. Physical response of gold nanoparticles to single self-ion bombardment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bufford, Daniel C.; Hattar, Khalid

    2014-09-23

    The reliability of nanomaterials depends on maintaining their specific sizes and structures. However, the stability of many nanomaterials in radiation environments remains uncertain due to the lack of a fully developed fundamental understanding of the radiation response on the nanoscale. To provide an insight into the dynamic aspects of single ion effects in nanomaterials, gold nanoparticles (NPs) with nominal diameters of 5, 20, and 60 nm were subjected to self-ion irradiation at energies of 46 keV, 2.8 MeV, and 10 MeV in situ inside of a transmission electron microscope. Ion interactions created a variety of far-from-equilibrium structures including small (~1more »nm) sputtered nanoclusters from the parent NPs of all sizes. Single ions created surface bumps and elongated nanofilaments in the 60 nm NPs. As a result, similar shape changes were observed in the 20 nm NPs, while the 5 nm NPs were transiently melted or explosively broken apart.« less

  5. Structural analysis of palladium-decorated gold nanoparticles as colloidal bimetallic catalysts.

    SciTech Connect (OSTI)

    Fang, Y. L.; Miller, J. T.; Guo, N.; Heck, K. N.; Alvarez, P. J. J.; Wong, M. S. (Chemical Sciences and Engineering Division); (Rice Univ.)

    2011-02-02

    Bimetallic palladium-decorated gold nanoparticle (Pd/Au NP) catalysts are significantly more active than palladium-only catalysts, but the mechanism for enhancement is not completely clear for most reactions, like the aqueous-phase hydrodechlorination of trichloroethene. In this study, we conducted X-ray absorption spectroscopy on carbon-supported Pd/Au NPs to obtain information about the local atomic environment (i.e., oxidation states, coordination numbers, and bond distances) of the two metals under different treatment conditions. The as-synthesized NPs were confirmed to have a Pd-shell/Au-core nanostructure, in which the Pd was found as surface ensembles. Upon exposure to room temperature in air, a portion of the Pd, but not the Au, was oxidized. In comparison, nearly the entire surface of monometallic Pd NPs was oxidized, suggesting that Au in Pd/Au NPs imparts oxidation resistance to Pd atoms. The surface Pd was found randomly distributed, presumably as a PdAu surface alloy, after reduction at 300 C. X-ray absorption spectroscopy provides direct evidence for the Pd-shell/Au-core structure of Pd/Au NPs, and suggests that metallic Pd in the Pd/Au NPs is a source for higher catalytic activity for aqueous-phase trichloroethene hydrodechlorination.

  6. Measurements of Aerosol Charge and Size Distribution for Graphite, Gold, Palladium, and Silver Nanoparticles

    SciTech Connect (OSTI)

    Simones, Matthew P.; Gutti, Veera R.; Meyer, Ryan M.; Loyalka, Sudarshan K.

    2011-11-01

    The role of charge on aerosol evolution and hence the nuclear source term has been an issue of interest, and there is a need for both experimental techniques and modeling for quantifying this role. Our focus here is on further exploration of a tandem differential mobility analyzer (TDMA) technique to simultaneously measure both the size and charge (positive, negative and neutral) dependent aerosol distributions. We have generated graphite, gold, silver, and palladium nanoparticles (aerosol) using a spark generator. We measure the electrical mobility-size distributions for these aerosols using a TDMA, and from these data we deduce the full charge-size distributions. We observe asymmetry in the particle size distributions for negative and positive charges. This asymmetry could have a bearing on the dynamics of charged aerosols, indicating that the assumption of symmetry for size distributions of negatively and positively charged particles in source term simulations may not be always appropriate. Also, the experimental technique should find applications in measurements of aerosol rate processes that are affected by both particle charge and size (e.g. coagulation, deposition, resuspension), and hence in modeling and simulation of the nuclear source term.

  7. Effect of defocusing on picosecond laser-coupling into gold cones

    SciTech Connect (OSTI)

    Bush, I. A., E-mail: ian.bush@gmail.com; Pasley, J. [York Plasma Institute, Department of Physics, University of York, York YO10 5DQ (United Kingdom) [York Plasma Institute, Department of Physics, University of York, York YO10 5DQ (United Kingdom); Central Laser Facility, Rutherford Appleton Laboratory, Chilton OX11 0QX (United Kingdom); Thomas, A. G. R. [Center for Ultrafast Optical Science, Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109-2099 (United States)] [Center for Ultrafast Optical Science, Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109-2099 (United States); Gartside, L.; Sarfraz, S.; Wagenaars, E. [York Plasma Institute, Department of Physics, University of York, York YO10 5DQ (United Kingdom)] [York Plasma Institute, Department of Physics, University of York, York YO10 5DQ (United Kingdom); Green, J. S.; Notley, M.; Lowe, H.; Spindloe, C.; Winstone, T.; Robinson, A. P. L.; Clarke, R. [Central Laser Facility, Rutherford Appleton Laboratory, Chilton OX11 0QX (United Kingdom)] [Central Laser Facility, Rutherford Appleton Laboratory, Chilton OX11 0QX (United Kingdom); Ma, T.; Yabuuchi, T.; Wei, M.; Beg, F. N. [Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, California 92093-0411 (United States)] [Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, California 92093-0411 (United States); Stephens, R. B. [General Atomics, San Diego, California 92121-1122 (United States)] [General Atomics, San Diego, California 92121-1122 (United States); MacPhee, A.; MacKinnon, A. J. [Lawrence Livermore National Laboratory, Livermore, California 94550-9234 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94550-9234 (United States); and others

    2014-01-15

    Here, we show that defocusing of the laser in the interaction of a picosecond duration, 1.053??m wavelength, high energy pulse with a cone-wire target does not significantly affect the laser energy coupling efficiency, but does result in a drop in the fast electron effective temperature. This may be beneficial for fast ignition, since not only were more electrons with lower energies seen in the experiment but also the lower prepulse intensity will reduce the amount of preplasma present on arrival of the main pulse, reducing the distance the hot electrons have to travel. We used the Vulcan Petawatt Laser at the Rutherford Appleton Laboratory and gold cone targets with approximately 1?mm long, 40??m diameter copper wires attached to their tip. Diagnostics included a quartz crystal imager, a pair of highly oriented pyrolytic graphite crystal spectrometers and a calibrated CCD operating in the single photon counting regime, all of which looked at the copper K{sub ?} emission from the wire. A short pulse optical probe, delayed 400 ps relative to the main pulse was employed to diagnose the extent of plasma expansion around the wire. A ray-tracing code modeled the change in intensity on the interior surface of the cone with laser defocusing. Using a model for the wire copper K{sub ?} emission coupled to a hybrid Vlasov-Fokker-Planck code, we ran a series of simulations, holding the total energy in electrons constant whilst varying the electron temperature, which support the experimental conclusions.

  8. Design of an Yb-169 source optimized for gold nanoparticle-aided radiation therapy

    SciTech Connect (OSTI)

    Reynoso, Francisco J.; Manohar, Nivedh; Cho, Sang Hyun

    2014-10-15

    Purpose: To find an optimum design of a new high-dose rate ytterbium (Yb)-169 brachytherapy source that would maximize the dose enhancement during gold nanoparticle-aided radiation therapy (GNRT), while meeting practical constraints for manufacturing a clinically relevant brachytherapy source. Methods: Four different Yb-169 source designs were considered in this investigation. The first three source models had a single encapsulation made of one of the following materials: aluminum, titanium, and stainless steel. The last source model adopted a dual encapsulation design with an inner aluminum capsule surrounding the Yb-core and an outer titanium capsule. Monte Carlo (MC) simulations using the Monte Carlo N-Particle code version 5 (MCNP5) were conducted initially to investigate the spectral changes caused by these four source designs and the associated variations in macroscopic dose enhancement across the tumor loaded with gold nanoparticles (GNPs) at 0.7% by weight. Subsequent MC simulations were performed using the EGSnrc and NOREC codes to determine the secondary electron spectra and microscopic dose enhancement as a result of irradiating the GNP-loaded tumor with the MCNP-calculated source spectra. Results: Effects of the source filter design were apparent in the current MC results. The intensity-weighted average energy of the Yb-169 source varied from 108.9 to 122.9 keV, as the source encapsulation material changed from aluminum to stainless steel. Accordingly, the macroscopic dose enhancement calculated at 1 cm away from the source changed from 51.0% to 45.3%. The sources encapsulated by titanium and aluminum/titanium combination showed similar levels of dose enhancement, 49.3% at 1 cm, and average energies of 113.0 and 112.3 keV, respectively. While the secondary electron spectra due to the investigated source designs appeared to look similar in general, some differences were noted especially in the low energy region (<50 keV) of the spectra suggesting the dependence of the photoelectron yield on the atomic number of source filter material, consistent with the macroscopic dose enhancement results. A similar trend was also shown in the so-called microscopic dose enhancement factor, for example, resulting in the maximum values of 138 and 119 for the titanium- and the stainless steel-encapsulated Yb-169 sources, respectively. Conclusions: The current results consistently show that the dose enhancement achievable from the Yb-169 source is closely related with the atomic number (Z) of source encapsulation material. While the observed range of improvement in the dose enhancement may be considered moderate after factoring all uncertainties in the MC results, the current study provides a reasonable support for the encapsulation of the Yb-core with lower-Z materials than stainless steel, for GNRT applications. Overall, the titanium capsule design can be favored over the aluminum or dual aluminum/titanium capsule designs, due to its superior structural integrity and improved safety during manufacturing and clinical use.

  9. Low-Z linac targets for low-MV gold nanoparticle radiation therapy

    SciTech Connect (OSTI)

    Tsiamas, P.; Mishra, P.; Berbeco, R. I.; Marcus, K.; Zygmanski, P. E-mail: Erno-Sajo@uml.edu; Cifter, F.; Sajo, E. E-mail: Erno-Sajo@uml.edu

    2014-02-15

    Purpose: To investigate the potential of low-Z/low-MV (low-Z) linac targets for gold nanoparticle radiotherapy (GNPT) and to determine the microscopic dose enhancement ratio (DER) due to GNP for the alternative beamlines. In addition, to evaluate the degradation of dose enhancement arising from the increased attenuation of x rays and larger skin dose in water for the low-MV beams compared to the standard linac. Methods: Monte Carlo simulations were used to compute dose and DER for various flattening-filter-free beams (2.5, 4, 6.5 MV). Target materials were beryllium, diamond, and tungsten-copper high-Z target. Target thicknesses were selected based on 20%, 60%, 70%, and 80% of the continuous slowing down approximation electron ranges for a given target material and energy. Evaluation of the microscopic DER was carried out for 100 nm GNP including the degradation factors due to beam attenuation. Results: The greatest increase in DER compared to the standard 6.5 MV linac was for a 2.5 MV Be-target (factor of ?2). Skin dose ranged from ?10% (Be, 6.5 MV-80%) to ?85% (Be, 2.5 MV-20%) depending on the target case. Attenuation of 2.5 MV beams at 22 cm was higher by ?75% compared with the standard beam. Taking into account the attenuation at 22 cm depth, the effective dose enhancement was up to ?60% above the DER of the high-Z target. For these cases the effective DER ranged between ?1.6 and 6 compared with the standard linac. Conclusions: Low-Z (2.5 MV) GNPT is possible even after accounting for greater beam attenuation for deep-seated tumors (22 cm) and the increased skin dose. Further, it can lead to significant sparing of normal tissue while simultaneously escalating the dose in the tumor cells.

  10. Sci—Thur AM: YIS - 04: Gold Nanoparticle Enhanced Arc Radiotherapy: A Monte Carlo Feasibility Study

    SciTech Connect (OSTI)

    Koger, B; Kirkby, C

    2014-08-15

    Introduction: The use of gold nanoparticles (GNPs) in radiotherapy has shown promise for therapeutic enhancement. In this study, we explore the feasibility of enhancing radiotherapy with GNPs in an arc-therapy context. We use Monte Carlo simulations to quantify the macroscopic dose-enhancement ratio (DER) and tumour to normal tissue ratio (TNTR) as functions of photon energy over various tumour and body geometries. Methods: GNP-enhanced arc radiotherapy (GEART) was simulated using the PENELOPE Monte Carlo code and penEasy main program. We simulated 360° arc-therapy with monoenergetic photon energies 50 – 1000 keV and several clinical spectra used to treat a spherical tumour containing uniformly distributed GNPs in a cylindrical tissue phantom. Various geometries were used to simulate different tumour sizes and depths. Voxel dose was used to calculate DERs and TNTRs. Inhomogeneity effects were examined through skull dose in brain tumour treatment simulations. Results: Below 100 keV, DERs greater than 2.0 were observed. Compared to 6 MV, tumour dose at low energies was more conformai, with lower normal tissue dose and higher TNTRs. Both the DER and TNTR increased with increasing cylinder radius and decreasing tumour radius. The inclusion of bone showed excellent tumour conformality at low energies, though with an increase in skull dose (40% of tumour dose with 100 keV compared to 25% with 6 MV). Conclusions: Even in the presence of inhomogeneities, our results show promise for the treatment of deep-seated tumours with low-energy GEART, with greater tumour dose conformality and lower normal tissue dose than 6 MV.

  11. Benchmarking the New RESRAD-OFFSITE Source Term Model with DUST-MS and GoldSim - 13377

    SciTech Connect (OSTI)

    Cheng, J.J.; Kamboj, S.; Gnanapragasam, E.; Yu, C.

    2013-07-01

    RESRAD-OFFSITE is a computer code developed by Argonne National Laboratory under the sponsorship of U.S. Department of Energy (DOE) and U.S. Nuclear Regulatory Commission (NRC). It is designed on the basis of RESRAD (onsite) code, a computer code designated by DOE and NRC for evaluating soil-contaminated sites for compliance with human health protection requirements pertaining to license termination or environmental remediation. RESRAD-OFFSITE has enhanced capabilities of modeling radionuclide transport to offsite locations and calculating potential radiation exposure to offsite receptors. Recently, a new source term model was incorporated into RESRAD-OFFSITE to enhance its capability further. This new source term model allows simulation of radionuclide releases from different waste forms, in addition to the soil sources originally considered in RESRAD (onsite) and RESRAD-OFFSITE codes. With this new source term model, a variety of applications can be achieved by using RESRAD-OFFSITE, including but not limited to, assessing the performance of radioactive waste disposal facilities. This paper presents the comparison of radionuclide release rates calculated by the new source term model of RESRAD-OFFSITE versus those calculated by DUST-MS and GoldSim, respectively. The focus of comparison is on the release rates of radionuclides from the bottom of the contaminated zone that was assumed to contain radioactive source materials buried in soil. The transport of released contaminants outside of the primary contaminated zone is beyond the scope of this paper. Overall, the agreement between the RESRAD-OFFSITE results and the DUST-MS and GoldSim results is fairly good, with all three codes predicting identical or similar radionuclide release profiles over time. Numerical dispersion in the DUST-MS and GoldSim results was identified as potentially contributing to the disagreement in the release rates. In general, greater discrepancy in the release rates was found for short-lived, fast-moving radionuclides than for long-lived, slow-moving radionuclides. (authors)

  12. Adsorption Mechanisms of Trivalent Gold onto Iron Oxy-Hydroxides: From the Molecular Scale to the Model

    SciTech Connect (OSTI)

    Cances, Benjamin; Benedetti, Marc; Farges, Francois; Brown, Gordon E.., Jr.; /Stanford U., Geo. Environ. Sci. /SLAC, SSRL

    2006-12-13

    Gold is a highly valuable metal that can concentrate in iron-rich exogenetic horizons such as laterites. An improved knowledge of the retention mechanisms of gold onto highly reactive soil components such as iron oxyhydroxides is therefore needed to better understand and predict the geochemical behavior of this element. In this study, we use EXAFS information and titration experiments to provide a realistic thermochemical description of the sorption of trivalent gold onto iron oxy-hydroxides. Analysis of Au L{sub III}-edge XAFS spectra shows that aqueous Au(III) adsorbs from chloride solutions onto goethite surfaces as inner-sphere square-planar complexes (Au(III)(OH,Cl){sub 4}), with dominantly OH ligands at pH > 6 and mixed OH/Cl ligands at lower pH values. In combination with these spectroscopic results, Reverse Monte Carlo simulations were used to constraint the possible sorption sites on the surface of goethite. Based on this structural information, we calculated sorption isotherms of Au(III) on Fe oxy-hydroxides surfaces, using the CD-MUSIC (Charge Distribution--Multi Site Complexation) model. The various Au(III)-sorbed species were identified as a function of pH, and the results of these EXAFS+CD-MUSIC models are compared with titration experiments. The overall good agreement between the predicted and measured structural models shows the potential of this combined approach to better model sorption processes of transition elements onto highly reactive solid surfaces such as goethite and ferrihydrite.

  13. X-ray Spectral Measurements and Collisional Radiative Modeling of Hot, Gold Plasmas at the Omega Laser

    SciTech Connect (OSTI)

    May, M J; Schneider, M B; Hansen, S B; Chung, H; Hinkel, D E; Baldis, H A; Constantin, C

    2008-07-02

    M-Band and L-Band Gold spectra between 3 to 5 keV and 8 to 13 keV, respectively, have been recorded by a photometrically calibrated crystal spectrometer. The spectra were emitted from the plasma in the laser deposition region of a 'hot hohlraum'. This is a reduced-scale hohlraum heated with {approx} 9 kJ of 351 nm light in a 1 ns square pulse at the OMEGA laser. The space- and time-integrated spectra included L-Band line emission from Co-like to Ne-like gold. The three L-Band line features were identified to be the 3s {yields} 2p, 3d{sub 5/2} {yields} 2p{sub 3/2} and 3d{sub 3/2} {yields} 2p{sub 1/2} transitions at {approx}9 keV, {approx}10 keV and {approx}13 keV, respectively. M-Band 5f {yields} 3d, 4d {yields} 3p, and 4p {yields} 3s transition features from Fe-like to P-like gold were also recorded between 3 to 5 keV. Modeling from the radiation-hydrodynamics code LASNEX, the collisional-radiative codes FLYCHK and SCRAM, and the atomic structure code FAC were used to model the plasma and generate simulated spectra for comparison with the recorded spectra. Through these comparisons, we have determined the average electron temperature of the emitting plasma to be between 6.0 and 6.5 keV. The electron temperatures predicted by LASNEX appear to be too large by a factor of about 1.5.

  14. Study of Inhibition, Reactivation and Aging Processes of Pesticides Using Graphene Nanosheets/Gold Nanoparticles-Based Acetylcholinesterase Biosensor

    SciTech Connect (OSTI)

    Zhang, Lin; Long, Linjuan; Zhang, Weiying; Du, Dan; Lin, Yuehe

    2012-09-10

    Organophosphate (OP) and carbamate pesticides exert their toxicity via attacking the hydroxyl moiety of serine in the 'active site' of acetylcholinesterase (AChE). In this paper we developed a stable AChE biosensor based on self-assembling AChE to graphene nanosheet (GN)-gold nanoparticles (AuNPs) nanocomposite electrode for investigation of inhibition, reactivation and aging processes of different pesticides. It is confirmed that pesticides can inhibit AChE in a short time. OPs poisoning is treatable with oximes while carbarmates exposure is insensitive to oximes. The proposed electrochemical approach thus provides a new simple tool for comparison of pesticide sensitivity and guide of therapeutic intervention.

  15. One-dimensional array of point-like light sources based on gold nanoparticles and tetracene: Preparation and possible operation mechanisms

    SciTech Connect (OSTI)

    Cherepanov, V. V.; Fedorovich, R. D.; Kiyayev, O. E.; Naumovets, A. G.; Nechytaylo, V. B. Tomchuk, P. M.; Viduta, L. V.

    2014-11-10

    A method of preparation of a linear close-packed array of point-like light sources based on a nanocomposite of gold nanoparticles and tetracene is proposed. Ordered system of microleads to the light sources with packing density up to 1000?mm{sup ?1} consists of linear conducting chains of cobalt nanoparticles self-assembled in a magnetic field. The electroluminescence from the gold-tetracene nanocomposite occurs in the visible range typical of organic light-emitting field-effect transistors based on tetracene. A theoretical substantiation of the possibility of excitation of tetracene molecules by hot electrons emitted from the gold nanoparticles is suggested and compared with other possible physical mechanisms.

  16. Tracing the magmatic/hydrothermal transition in regional low-strain zones: The role of magma dynamics in strain localization at pluton roof, implications for intrusion-related gold

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    dynamics in strain localization at pluton roof, implications for intrusion-related gold deposits Eric features of a granite-pluton roof; large-scale dykes and a network of gold veins are intensively developed in this roof, recording a succession of mechanical instabilities. Our gravity survey underlines the presence

  17. Migration of gold atoms in graphene ribbons: Role of the edges Wei Zhang,1 Litao Sun,2,* Zijian Xu,1 Arkady V. Krasheninnikov,3,4 Ping Huai,1 Zhiyuan Zhu,1 and F. Banhart5

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    Migration of gold atoms in graphene ribbons: Role of the edges Wei Zhang,1 Litao Sun,2,* Zijian Xu October 2009; revised manuscript received 24 January 2010; published 22 March 2010 The migration of gold to the other side of the sheet, but the Au atom can migrate in lateral direction together with the vacancy

  18. Structural characterization and comparison of iridium, platinum and gold/palladium ultra-thin film coatings for STM of biomolecules

    SciTech Connect (OSTI)

    Sebring, R.; Arendt, P.; Imai, B.; Bradbury, E.M.; Gatewood, J. [Los Alamos National Lab., NM (United States); Panitz, J. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Physics and Astronomy; Yau, P. [Univ. of California, Davis, CA (United States)

    1997-10-30

    Scanning tunneling microscopy (STM) is capable of atomic resolution and is ideally suited for imaging surfaces with uniform work function. A biological sample on a conducting substrate in air does not meet this criteria and requires a conductive coating for stable and reproducible STM imaging. In this paper, the authors describe the STM and transmission electron microscopy (TEM) characterization of ultra-thin ion-beam sputtered films of iridium and cathode sputtered gold/palladium and platinum films on highly ordered pyrolytic graphite (HOPG) which were developed for use as biomolecule coatings. The goals were the development of metal coatings sufficiently thin and fine grained that 15--20 {angstrom} features of biological molecules could be resolved using STM, and the development of a substrate/coating system which would allow complementary TEM information to be obtained for films and biological molecules. The authors demonstrate in this paper that ion-beam sputtered iridium on highly ordered pyrolytic graphite (HOPG) has met both these goals. The ion-beam sputtered iridium produced a very fine grained (< 10 {angstrom}) continuous film at 5--6 {angstrom} thickness suitable for stable air STM imaging. In comparison, cathode sputtered platinum produced 16 {angstrom} grains with the thinnest continuous film at 15 {angstrom} thickness, and the sputtered gold/palladium produced 25 {angstrom} grains with the thinnest continuous film at 18 {angstrom} thickness.

  19. Colloidal gold nanoparticle probe-based immunochromatographic assay for the rapid detection of chromium ions in water and serum samples

    SciTech Connect (OSTI)

    Liu, Xi; Xiang, Jun-Jian; Tang, Yong; Zhang, Xiao-Li; Fu, Qiang-Qiang; Zou, Jun-Hui; Lin, Yuehe

    2012-09-01

    An immunochromatographic assay (ICA) using gold nanoparticles coated with monoclonal antibody (McAb) for the detection of chromium ions (Cr) in water and serum samples was developed, optimized, and validated. Gold nanoparticles coated with affinity- purified monoclonal antibodies against isothiocyanobenzyl-EDTA (iEDTA)-chelated Cr3+ were used as the detecting reagent in this completive immunoassay-based one- step test strip. The ICA was investigated to measure chromium speciation in water samples. Chromium standard samples of 0-80 ng/mL in water were determined by the test strips. The results showed that the visual lowest detection limit (LDL) of the test strip was 50.0 ng/mL. A portable colorimetric lateral flow reader was used for the quantification of Cr. The results indicated that the linear range of the ICA with colorimetric detection was 5-80 ng/mL. The ICA was also validated for the detection of chromium ions in serum samples. The test trips showed high stability in that they could be stored at at 37 C for at least 12 weeks without significant loss of activity. The test strip also showed good selectivity for Cr detection with negligible interference from other heavy metals. Because of its low cost and short testing time (within 5 min), the test strip is especially suitable for on-site large- scale screening of Cr-polluted water samples, biomonitoring of Cr exposure, and many other field applications.

  20. Density functional theory study of transition metal porphine adsorption on gold surface and electric field induced conformation changes.

    SciTech Connect (OSTI)

    Batista, Victor S. (Yale University, New Haven, CT); Chandross, Michael Evan; Leung, Kevin; Sporviero, Eduardo (Yale University, New Haven, CT); Schultz, Peter Andrew; Rempe, Susan B.

    2005-06-01

    We apply density functional theory (DFT) and the DFT+U technique to study the adsorption of transition metal porphine molecules on atomistically flat Au(111) surfaces. DFT calculations using the Perdew?Burke?Ernzerhof exchange correlation functional correctly predict the palladium porphine (PdP) low-spin ground state. PdP is found to adsorb preferentially on gold in a flat geometry, not in an edgewise geometry, in qualitative agreement with experiments on substituted porphyrins. It exhibits no covalent bonding to Au(111), and the binding energy is a small fraction of an electronvolt. The DFT+U technique, parametrized to B3LYP-predicted spin state ordering of the Mn d-electrons, is found to be crucial for reproducing the correct magnetic moment and geometry of the isolated manganese porphine (MnP) molecule. Adsorption of Mn(II)P on Au(111) substantially alters the Mn ion spin state. Its interaction with the gold substrate is stronger and more site-specific than that of PdP. The binding can be partially reversed by applying an electric potential, which leads to significant changes in the electronic and magnetic properties of adsorbed MnP and 0.1 {angstrom} changes in the Mn-nitrogen distances within the porphine macrocycle. We conjecture that this DFT+U approach may be a useful general method for modeling first-row transition metal ion complexes in a condensed-matter setting.

  1. Cold Nuclear Matter Effects on J/Psi as Constrained by Deuteron-Gold Measurements at sqrt(s_NN) = 200 GeV

    E-Print Network [OSTI]

    PHENIX Collaboration; A. Adare

    2007-11-25

    We present a new analysis of J/psi production yields in deuteron-gold collisions at sqrt(s_NN) = 200 GeV using data taken by the PHENIX experiment in 2003 and previously published in [S.S. Adler et al., Phys. Rev. Lett 96, 012304 (2006)]. The high statistics proton-proton J/psi data taken in 2005 is used to improve the baseline measurement and thus construct updated cold nuclear matter modification factors R_dAu. A suppression of J/psi in cold nuclear matter is observed as one goes forward in rapidity (in the deuteron-going direction), corresponding to a region more sensitive to initial state low-x gluons in the gold nucleus. The measured nuclear modification factors are compared to theoretical calculations of nuclear shadowing to which a J/psi (or precursor) break-up cross-section is added. Breakup cross sections of sigma_breakup = 2.8^[+1.7_-1.4] (2.2^[+1.6_-1.5]) mb are obtained by fitting these calculations to the data using two different models of nuclear shadowing. These breakup cross section values are consistent within large uncertainties with the 4.2 +/- 0.5 mb determined at lower collision energies. Projecting this range of cold nuclear matter effects to copper-copper and gold-gold collisions reveals that the current constraints are not sufficient to firmly quantify the additional hot nuclear matter effect.

  2. Evapotranspiration of Cool-Season Turfgrasses in the Humid Northeast' L. J. Aronson, A. J. Gold, R. J. Hull, and J. L. Cisar2

    E-Print Network [OSTI]

    Gold, Art

    Evapotranspiration of Cool-Season Turfgrasses in the Humid Northeast' L. J. Aronson, A. J. Gold, R that will lower water requirements as competition for water use increases. Transpiration accounts for most of the water lost from a dense turfgrass canopy (Beard, 1973). It has been established that transpiration rate

  3. Cool-Season Turfgrass Responses to DroughtStressI L. J. Aronson, A. J. Gold, and R. J. Hull2

    E-Print Network [OSTI]

    Gold, Art

    Cool-Season Turfgrass Responses to DroughtStressI L. J. Aronson, A. J. Gold, and R. J. Hull2 practices for both warm- and cool-season turfgrasses. Responses of turfgrass to drought can be viewed in a number of ways. Drought stress will affect visual quality, growth rate, evapo- transpiration (ET) rate

  4. Sun light mediated synthesis of gold nanoparticles as carrier for 6-mercaptopurine: Preparation, characterization and toxicity studies in zebrafish embryo model

    SciTech Connect (OSTI)

    Ganeshkumar, Moorthy; Sastry, Thotapalli Parvathaleswara; Sathish Kumar, Muniram; Dinesh, Murugan Girija; Kannappan, Sudalyandi; Suguna, Lonchin

    2012-09-15

    Highlights: ? Gold nanoparticles prepared using eco-friendly method with good in vitro stability. ? Can be used as drug delivery system. ? Did not show any toxicity in zebrafish embryo. ? More toxic to cancer cells when compared to N-Au-Mp and Mp. -- Abstract: The objective of this study is to synthesize green chemistry based gold nanoparticles by sun light irradiation method. The prepared gold nanoparticles (AuNPs) were modified using folic acid and then coupled with 6-mercaptopurine. These modified nanoparticles were used as a tool for targeted drug delivery to treat laryngeal cancer. In the present study, novel bionanocomposites containing nutrient agar coated gold nano particles (N-AuNPs) coupled with 6-mercaptopurine (drug) (N-AuNPs-Mp), folic acid (ligand) (N-AuNPs-Mp-Fa) and rhodamine (dye) (N-AuNPs-Rd), a fluorescent agent, were prepared and characterized by IR, UV, TEM, Particle size analysis and in vitro stability. The toxicity and fluorescence of N-Au was studied using zebrafish embryo model. The in vitro cytotoxicity of free Mp, N-Au-Mp and N-Au-Mp-Fa against HEp-2 cells was compared and found that the amount of Mp required to achieve 50% of growth of inhibition (IC{sub 50}) was much lower in N-Au-Mp-Fa than in free Mp and N-Au-Mp.

  5. Measured and calculated activities of spallation products formed in copper and gold foils as a result of bombardment with 120 MeV deuterons 

    E-Print Network [OSTI]

    Belian, Anthony Paul

    1994-01-01

    produced in the target as a function of target materials. An experiment conducted at the Texas A&M University (TAMU) Cyclotron consisted of two foils, copper and gold, being irradiated by 120 MeV deuterons. The foils were transported to the TAMU Nuclear...

  6. Azimuthal correlations of projectile and target fragments in collisions between gold nuclei of energy 10.6 GeV per nucleon and emulsion nuclei

    SciTech Connect (OSTI)

    Abdurakhmanov, U. U.; Gulamov, K. G.; Zhokhova, S. I.; Lugovoi, V. V. Navotny, V. Sh. Chudakov, V. M.

    2008-03-15

    Intra-and intergroup azimuthal correlations of projectile and target fragments are found in collisions between gold and emulsion nuclei. The statistical significance of these correlations is high. The methodological distortions associated with the measurement errors are investigated in detail and are taken into account.

  7. Dihydrogen activation by mixed platinum- and palladium-gold cluster compounds. Homogeneous catalytic H{sub 2}-D{sub 2} equilibration

    SciTech Connect (OSTI)

    Aubart, M.A.; Chandler, B.D.; Gould, R.A.T.

    1994-08-17

    Platinum- and palladium-gold cluster compounds were evaluated with respect to their ability to catalyze H{sub 2}-D{sub 2} equilibration. In addition, these phosphine-stabilized complexes were structurally characterized. Mechanistic studies for this reaction were performed by kinetic and spectroscopic analysis. The catalytic reaction appears to occur in three steps, which were determined.

  8. Study of the effect of semi-infinite crystalline electrodes on transmission of gold atomic wires using DFT

    E-Print Network [OSTI]

    Sattar, Abdul; Yasmeen, Sumaira; Javed, Hafsa; Latif, Hamid; Mahmood, Hasan; Iqbal, Azmat; Usman, Arslan; Akhtar, Majid Niaz; Khan, Salman Naeem; Dousti, M R

    2015-01-01

    First principle calculations of the conductance of gold wires containing 3-8 atoms each with 2.39 {\\AA} bond length were performed using density functional theory. Three different configuration of wire/electrodes were used. For zigzag wire with semi-infinite crystalline electrodes, even-odd oscillation is observed which is consistent with the previously reported results. A lower conductance was observed for the chain in semi-infinite crystalline electrodes compared to the chains suspended in wire-like electrode. The calculated transmission spectrum for the straight and zig-zag wires suspended between semi-infinite crystalline electrodes showed suppression of transmission channels due to electron scattering occurring at the electrode-wire interface.

  9. Comparison of gold- and graphene-based resonant nanostructures for terahertz metamaterials and an ultrathin graphene-based modulator

    SciTech Connect (OSTI)

    Shen, Nian-Hai [Ames Laboratory; Tassin, Philippe [Ames Laboratory; Koschny, Thomas [Ames Laboratory; Soukoulis, Costas M [Ames Laboratory

    2014-09-01

    Graphene exhibits unique material properties, and in electromagnetic wave technology it raises the prospect of devices miniaturized down to the atomic length scale. Here we study split-ring resonator metamaterials made from graphene and we compare them to gold-based metamaterials. We find that graphene's huge reactive response derived from its large kinetic inductance allows for deeply subwavelength resonances, although its resonance strength is reduced due to higher dissipative loss damping and smaller dipole coupling. Nevertheless, tightly stacked graphene rings may provide for negative permeability and the electric dipole resonance of graphene meta-atoms turns out to be surprisingly strong. Based on these findings, we present a terahertz modulator based on a metamaterial with a multilayer stack of alternating patterned graphene sheets separated by dielectric spacers. Neighboring graphene flakes are biased against each other, resulting in modulation depths of over 75% at a transmission level of around 90%.

  10. Low pressure CO? hydrogenation to methanol over gold nanoparticles activated on a CeOx/TiO? interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Xiaofang; Boscoboinik, J. Anibal; Kattel, Shyam; Senanayake, Sanjaya D.; Nie, Xiaowa; Graciani, Jesus; Rodriguez, Jose A.; Liu, Ping; Stacchiola, Dario J.; Chen, Jingguang G.

    2015-07-28

    Capture and recycling of CO? into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO? is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal–oxide interface of Au nanoparticles anchored and stabilized on a CeOx/TiO? substrate generates active centers formore »CO? adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. In conclusion, this study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO? hydrogenation.« less

  11. Femtosecond laser pulse driven melting in gold nanorod aqueous colloidal suspension: Identification of a transition from stretched to exponential kinetics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Yuelin; Jiang, Zhang; Lin, Xiao -Min; Wen, Haidan; Walko, Donald A.; Deshmukh, Sanket A.; Subbaraman, Ram; Sankaranarayanan, Subramanian K. R. S.; Gray, Stephen K.; Ho, Phay

    2015-01-30

    Many potential industrial, medical, and environmental applications of metal nanorods rely on the physics and resultant kinetics and dynamics of the interaction of these particles with light. We report a surprising kinetics transition in the global melting of femtosecond laser-driven gold nanorod aqueous colloidal suspension. At low laser intensity, the melting exhibits a stretched exponential kinetics, which abruptly transforms into a compressed exponential kinetics when the laser intensity is raised. It is found the relative formation and reduction rate of intermediate shapes play a key role in the transition. Supported by both molecular dynamics simulations and a kinetic model, themore »behavior is traced back to the persistent heterogeneous nature of the shape dependence of the energy uptake, dissipation and melting of individual nanoparticles. These results could have significant implications for various applications such as water purification and electrolytes for energy storage that involve heat transport between metal nanorod ensembles and surrounding solvents.« less

  12. Comparison of 20 nm silver nanoparticles synthesized with and without a gold core. Structure, dissolution in cell culture media, and biological impact on macrophages

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Munusamy, Prabhakaran; Wang, Chongmin; Engelhard, Mark H.; Baer, Donald R.; Smith, Jordan N.; Liu, Chongxuan; Kodali, Vamsi K.; Thrall, Brian D.; Chen, Shu; Alexandra, Porter E.; et al

    2015-07-15

    Widespread use of silver nanoparticles raises questions of environmental impact and toxicity. Both silver particles and silver ions formed by particle dissolution may impact biological systems. Therefore it is important to understand the characteristics of silver nanoparticles and their stability in relevant media. The synthesis route can impact physical and chemical characteristics of the particles and we report the characterization and solution stability of three types of silver nanoparticles (20 nm particles with and without gold cores and 110 nm particles with gold cores) in cell culture media with serum proteins: FBS10%/RPMI. These nanoparticles were synthesized in aqueous solution andmore »characterized using both in situ and ex situ analysis methods. Dissolution studies were carried at particle concentrations from 1 µg/ml to 50 µg/ml. Particles with gold cores had smaller crystallite size and higher apparent solubility than pure silver particles. A dissolution model was found to describe the time variation of particle size and amount of dissolved silver for particle loadings above 9 µg/ml. An effective solubility product obtained from fitting the data was higher for the 20 nm gold core particles in comparison to the pure silver or 110 nm particles. Dissolution of the nanoparticles was enhanced by presence of serum proteins contained in fetal bovine serum. In addition, the protocol of the dispersion in the medium was found to influence particle agglomeration and dissolution. Results show that particle structure can impact the concentration of dissolved silver and the dose to which cells would be exposed during in vitro studies.« less

  13. Porous polymer monolithic columns with gold nanoparticles as an intermediate ligand for the separation of proteins in reverse phase-ion exchange mixed mode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Terborg, Lydia; Masini, Jorge C.; Lin, Michelle; Lipponen, Katriina; Riekolla, Marja -Liisa; Svec, Frantisek

    2014-11-04

    A new approach has been developed for the preparation of mixed-mode stationary phases to separate proteins. The pore surface of monolithic poly(glycidyl methacrylate-co-ethylene dimethacrylate) capillary columns was functionalized with thiols and coated with gold nanoparticles. The final mixed mode surface chemistry was formed by attaching, in a single step, alkanethiols, mercaptoalkanoic acids, and their mixtures on the free surface of attached gold nanoparticles. Use of these mixtures allowed fine tuning of the hydrophobic/hydrophilic balance. The amount of attached gold nanoparticles according to thermal gravimetric analysis was 44.8 wt.%. This value together with results of frontal elution enabled calculation of surfacemore »coverage with the alkanethiol and mercaptoalkanoic acid ligands. Interestingly, alkanethiols coverage in a range of 4.46–4.51 molecules/nm2 significantly exceeded that of mercaptoalkanoic acids with 2.39–2.45 molecules/nm2. The mixed mode character of these monolithic stationary phases was for the first time demonstrated in the separations of proteins that could be achieved in the same column using gradient elution conditions typical of reverse phase (using gradient of acetonitrile in water) and ion exchange chromatographic modes (applying gradient of salt in water), respectively.« less

  14. Ocular Brachytherapy Dosimetry for 103Pd and 125I in The Presence of Gold Nanoparticles: Monte Carlo Study

    E-Print Network [OSTI]

    Asadi, S; Vahidian, M; Marghchouei, M; Masoudi, S Farhad

    2015-01-01

    The aim of the present Monte Carlo study is to evaluate the variation of energy deposition in healthy tissues in the human eye which is irradiated by brachytherapy sources in comparison with the resultant dose increase in the gold nanoparticle(GNP)-loaded choroidal melanoma. The effects of these nanoparticles on normal tissues are compared between 103Pd and 125I as two ophthalmic brachytherapy sources. Dose distribution in the tumor and healthy tissues have been taken into account for both mentioned brachytherapy sources. Also, in a certain point of the eye, the ratio of the absorbed dose by the normal tissue in the presence of GNPs to the absorbed dose by the same point in the absence of GNPs has been calculated. In addition, differences observed in the comparison of simple water phantom and actual simulated human eye in presence of GNPs are also a matter of interest that have been considered in the present work. The results show that the calculated dose enhancement factor in the tumor for 125I is higher tha...

  15. Synthesis of nanocrystalline thin films of gold on the surface of GaSb by swift heavy ion

    SciTech Connect (OSTI)

    Jadhav, Vidya; Dubey, S. K.; Yadav, A. D.; Singh, A.

    2013-02-05

    Thin films of gold ({approx}100 nm thick) were deposited on p-type GaSb substrates. These samples were irradiated with 100 MeV Fe{sup 7+}ions for the fluence of 1 Multiplication-Sign 10{sup 13} and 1 Multiplication-Sign 10{sup 14} ions cm{sup -2}. After irradiation, samples were characterized using AFM, UV-VIS -NIR, X-Ray Diffraction techniques. AFM studies showed the presence of clusters on the surface of GaSb. R.M.S. roughness of the sample was found to increase w.r.t ion fluence. Absorption coefficient obtained from the Ultra violet - Visible NIR (UV-VIS -NIR) spectra of the samples irradiated with various fluences compared with non irradiated GaSb. The annealing experiment showed a significant improvement in the absorption coefficient after rapid thermal annealing at temperature of 400 Degree-Sign C. X-Ray Diffraction study reveals different orientations of Au film.

  16. Efficiency Enhancement in Organic Solar Cells by Incorporating Silica-coated Gold Nanorods at the Buffer/Active interface

    E-Print Network [OSTI]

    Zhao, Haoyang; Tong, Peiqian; Cui, Yanxia; Hao, Yuying; Sun, Qinjun; Shi, Fang; Zhan, Qiuqiang; Wang, Hua; Zhu, Furong

    2015-01-01

    The performance of organic solar cells (OSCs) can be greatly improved by incorporating silica-coated gold nanorods (Au@SiO2 NRs) at the interface between the hole transporting layer and the active layer due to the plasmonic effect. The silica shell impedes the aggregation effect of the Au NRs in ethanol solution as well as the server charge recombination on the surface of the Au NRs otherwise they would bring forward serious reduction in open circuit voltage when incorporating the Au NRs at the positions in contact with the active materials. As a result, while the high open circuit voltage being maintained, the optimized plasmonic OSCs possess an increased short circuit current, and correspondingly an elevated power conversion efficiency with the enhancement factor of ~11%. The origin of performance improvement in OSCs with the Au@SiO2 NRs was analyzed systematically using morphological, electrical, optical characterizations along with theoretical simulation. It is found that the broadband enhancement in abso...

  17. SU-E-T-141: Effect of a Single Gold Nanoparticle with Different Sizes Inside a Small Water Phantom

    SciTech Connect (OSTI)

    Jing, J; Lin, H; Xiong, Z

    2014-06-01

    Purpose: This study is to investigate the effects of the gold nanoparticles (GNP), a series of micrometre scale simulations have been constructed with Geant4 to track particles and simulate the effects of those particles as they pass through water phantom. Methods: The simulations were used to calculate the number of secondary electrons which are emitted from the particle tracks and the amount of energy which is deposited in the cell tissue. More electrons means that more water molecules can undergo hydrolysis and create potentially dangerous free radical molecules, therefore breaking up DNA and killing off cells or causing damaging mutations. Results: For the 20nm GNP, all three proton energies saw a small increase of electrons above the control, while the X-rays nearly tripled the number of electrons in the phantom. For the 50 nm GNP, the 3 and 2 MeV protons saw a small increase again, however the 1 MeV protons saw a decrease in electrons, the X-rays saw a large increase of nearly 4 times the number of electrons. For the 110nm GNP, all three proton energies saw a decrease in the total number of electrons in the phantom, while the X-rays saw an increase of 8 times as many electrons. Conclusion: From the range of GNP sizes used, it was found that the X-rays have a larger dose enhancement effect as the GNP size increases, the relation between electron emissions and GNP size was linear. This is because the majority of the dose from the X-rays is delivered to the cell tissue through the initial high energy secondary electrons, any dose lost from the Augerelectrons being trapped inside the GNP volume is small compared to the dose that escapes with the high energy electrons.

  18. Nucleon-gold collisions at 200A GeV using tagged d + Au interactions in the PHOBOS detector

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Back, B. B.; Nouicer, R.; Baker, M. D.; Ballintijn, M.; Barton, D. S.; Becker, B.; Betts, R. R.; Bickley, A. A; Stienberg, P.; Ioradnova, A.; et al

    2015-09-23

    Forward calorimetry in the PHOBOS detector has been used to study charged hadron production in d+Au, p+Au, and n+Au collisions at ?sNN =200GeV. The forward proton calorimeter detectors are described and a procedure for determining collision centrality with these detectors is detailed. The deposition of energy by deuteron spectator nucleons in the forward calorimeters is used to identify p+Au and n+Au collisions in the data. A weighted combination of the yield of p+Au and n+Au is constructed to build a reference for Au+Au collisions that better matches the isospin composition of the gold nucleus. The pT and centrality dependence ofmore »the yield of this improved reference system is found to match that of d+Au. The shape of the charged-particle transverse momentum distribution is observed to extrapolate smoothly from p+p¯ to central d+Au as a function of the charged-particle pseudorapidity density. The asymmetry of positively and negatively charged hadron production in p+Au is compared to that of n+Au. No significant asymmetry is observed at midrapidity. In conclusion, these studies augment recent results from experiments at the CERN Large Hadron Collider and BNL Relativistic Heavy Ion Collider facilities to give a more complete description of particle production in p+A and d+A collisions, essential for the understanding the medium produced in high-energy nucleus-nucleus collisions.« less

  19. Critical exponents and phase transition in gold nuclei fragmentation at energies 10.6 and 4.0 GeV/nucleon

    E-Print Network [OSTI]

    D. Kudzia; B. Wilczynska; H. Wilczynski

    2002-07-25

    An attempt to extract critical exponents gamma, beta and tau from data on gold nuclei fragmentation due to interactions with nuclear emulsion at energies 4.0 A GeV and 10.6 A GeV is presented. Based on analysis of Campi's 2nd charge moments, two subsets of data at each energy are selected from the inclusive data, corresponding to 'liquid' and 'gas' phases. The extracted values of critical exponents from the selected data sets are in agreement with predictions of 'liquid-gas' model of phase transition.

  20. Preemptive Strike: Law in the Campaign for Clean Trucks

    E-Print Network [OSTI]

    Cummings, Scott

    2015-01-01

    burning fuels. 653 In addition, following the China Shippingfuels, 621 installing “low profile” cranes, 622 building facilities for “shoreside electrical power for ship hoteling,” retrofitting China Shipping

  1. Instrumenting Buildings to Determine Retrofit Savings: Murphy's Law Strikes Again 

    E-Print Network [OSTI]

    O'Neal, D. L.; Bryant, J.; Carlson, K.

    1998-01-01

    &M University. Metering typically includes monitoring for the whole-building electric load, chilled and hot water thermal loads and selected submetered electrical loads. The emphasis of the lessons learned was on the instrumentation used and installation...

  2. "The environmental studies minor strikes a balance between the

    E-Print Network [OSTI]

    Kasman, Alex

    ). >> an environmental engineering firm (learning the basic operations). >> a local municipal water works (helping change? How do property rights affect economic policy? And what effect do antibacterial products have ­ an undeniably broad area that enhances our understanding of how political, social, cultural and economic

  3. Striking a Balance : Metadata Creation in Digital Library Projects

    E-Print Network [OSTI]

    Mercer, Holly

    2003-10-10

    keywords from a thesaurus built in- house for the GSB student portal. There were many challenges in implementing and operating such a full-featured system; not all web authors had the same level of proficiency or comfort level with the new application..., that responsibility was turned over in full to the web authors. Indexers continue to collaborate with producers and web authors in maintaining the student portal thesaurus. The perception was that the web authors could not produce quality keywords that would aid...

  4. Preemptive Strike: Law in the Campaign for Clean Trucks

    E-Print Network [OSTI]

    Cummings, Scott

    2015-01-01

    equipment, polluting the air and water and burdening thereductions in noise, air and water pollution at the Hugo

  5. Strikes, Housework, and the Moral Obligation to Resist

    E-Print Network [OSTI]

    Cudd, Ann E.

    1998-01-01

    or to revolt the slave might need to eat and appear to acquiesce for a time. Resistance to oppression doesn?t seem to fit the duty model, for two reasons. First, the situation that would obligate is coercive. That is, the oppressed are unfairly... not seem to fit the duty model has to do with the forms of resistance open to oppressed persons. Sometimes the only way to resist is in concerted effort with others, and if the others will not act, then one?s own action might fail to constitute...

  6. Preemptive Strike: Law in the Campaign for Clean Trucks

    E-Print Network [OSTI]

    Cummings, Scott

    2015-01-01

    to the approaching transcontinental railroad, which locala law directing the transcontinental railroad to run throughDetermined to bring transcontinental service to Los Angeles,

  7. Strike Limit Algorithm Optimisation: A Realistic Geof H. Givens \\Lambda

    E-Print Network [OSTI]

    Givens, Geof H.

    periodically, often in 4­5 year blocks, by the IWC on the basis of the individual political interests of IWC, meet the conflicting IWC objectives of low chance of population extinction or severe depletion, high, as are simulated future abundance surveys, other simulated future data, and future need. Such simulation

  8. Paducah Plant Begins Enrichment Operations after Five Parties Strike

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrder 422.1, CONDUCT P - .Energy 5PVMajorFebruary 2016

  9. Boiler Gold Rush

    E-Print Network [OSTI]

    Delworth, Timothy J

    2015-08-19

    How to Succeed in Math. Course Coordinators: • MA 15910, Introduction to Calculus (AG only)....Charlotte Bailey. • MA 15800, Precalculus…

  10. Gold Awards - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFESOpportunitiesNERSC Getting Started at14 at 12:00GlobusHanford

  11. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFESOpportunitiesNERSC GettingGraphene's 3DGreenGreen

  12. VOLUME 88, NUMBER 14 P H Y S I C A L R E V I E W L E T T E R S 8 APRIL 2002 Anomalous Conductance Distribution in Quasi-One-Dimensional Gold Wires

    E-Print Network [OSTI]

    Mohanty, Raj

    Distribution in Quasi-One-Dimensional Gold Wires: Possible Violation of the One-Parameter Scaling Hypothesis in the noninteracting theories in the one-parameter scaling framework, which include the per- turbative diagrammatic, 73.20.Fz Scaling theory of Anderson localization is the starting point of mesoscopic physics [1

  13. Nanotechnology Now -News Story: "Fast heat dissipation in gold" http://www.nanotech-now.com/news.cgi?story_id=07985 1 of 2 3/9/2005 4:51 PM

    E-Print Network [OSTI]

    Braun, Paul

    Nanotechnology Now - News Story: "Fast heat dissipation in gold" http Nano-Enabled Drug Discovery Market to Reach $1.3B by 2009 March 8th, 2005 Nanotechnology promises around the world, free Subscribe "N" is for Nanotechnology BUY NOW Subscribe to the Forbes/Wolfe Nanotech

  14. Bioresearch pins hopes on 'green gold' | The Record.com http://www.therecord.com/business/techspot/business_techspot_051... 1 of 4 2/22/06 11:40 AM

    E-Print Network [OSTI]

    Raizada, Manish N.

    ... Bioresearch pins hopes on 'green gold' Local researchers see potential in plants as raw material to build Raizada, a researcher at the University of Guelph. "A big dream is to get all the raw materials used and other manufacturing materials. After all, crude oil or "fossil fuel" is basically composed of chains

  15. Centrifugal Isolation of Faceted Gold Nanoparticles T. P. Tyler,1 P. A. Lin,2 Y. Tian,2 H.-J. Gao,2 X. P. A. Gao,2 R. M. Sankaran,2 and M. C. Hersam1

    E-Print Network [OSTI]

    Shahriar, Selim

    MRSEC Centrifugal Isolation of Faceted Gold Nanoparticles T. P. Tyler,1 P. A. Lin,2 Y. Tian,2 H. To date, attempts to achieve uniform AuNPs have relied on synthetic control or post-synthetic centrifugal cubic and triangular) are separated from their nonfaceted (i.e., spherical) counterparts via centrifugal

  16. Polymer-gold composite particles are a tremendous research interest. Due to their unique structures, these particles demonstrate superior properties for optical, catalytic and electrical applications. Moreover, the incorporation of

    E-Print Network [OSTI]

    Polymer-gold composite particles are a tremendous research interest. Due to their unique structures, the incorporation of "smart" polymers enables the composite particles to synergistically respond to environmental, a novel Pickering emulsion polymerization route is employed to synthesize core-shell polymer

  17. Absence of exchange interaction between localized magnetic moments and conduction-electrons in diluted Er{sup 3+} gold-nanoparticles

    SciTech Connect (OSTI)

    Lesseux, G. G. Urbano, R. R.; Iwamoto, W.; García-Flores, A. F.; Rettori, C.

    2014-05-07

    The Electron Spin Resonance (ESR) of diluted Er{sup 3+} magnetic ions in Au nanoparticles (NPs) is reported. The NPs were synthesized by reducing chloro triphenyl-phosphine gold(I) and erbium(III) trifluoroacetate. The Er{sup 3+} g-value along with the observed hyperfine splitting indicate that the Er{sup 3+} impurities are in a local cubic symmetry. Furthermore, the Er{sup 3+} ESR spectra show that the exchange interaction between the 4f and the conduction electrons (ce) is absent or negligible in Au{sub 1–x}Er{sub x} NPs, in contrast to the ESR results in bulk Au{sub 1–x}Er{sub x}. Therefore, the nature of this interaction needs to be reexamined at the nano scale range.

  18. Self assembly of acetylcholinesterase on a gold nanoparticles–graphene nanosheet hybrid for organophosphate pesticide detection using polyelectrolyte as a linker

    SciTech Connect (OSTI)

    Wang, Ying; Zhang, Sheng; Du, Dan; Shao, Yuyan; Li, Zhaohui; Wang, Jun; Engelhard, Mark H.; Li, Jinghong; Lin, Yuehe

    2011-04-14

    A nanohybrid of gold nanoparticles (Au NPs) and chemically reduced graphene oxide nanosheets (cr-Gs) was synthesized by in situ growth of Au NPs on the surface of graphene nanosheets in the presence of poly(diallyldimethylammonium chloride) (PDDA), which not only improved the dispersion of Au NPs but also stabilized cholinesterase with high activity and loading efficiency. The obtained nanohybrid was characterized by TEM, XRD, XPS, and electrochemistry. Then an enzyme nanoassembly (AChE/Au NPs/cr-Gs) was prepared by self-assembling acetylcholinesterase (AChE) on Au NP/cr-Gs nanohybrid. An electrochemical sensor based on AChE/Au NPs/cr-Gs was further developed for ultrasensitive detection of organophosphate pesticide. The results demonstrate that the developed approach provides a promising strategy to improve the sensitivity and enzyme activity of electrochemical biosensors.

  19. Correlation of gold in siliceous sinters with {sup 3}He/{sup 4}He in hot spring waters of Yellowstone National Park

    SciTech Connect (OSTI)

    Fournier, R.O.; Thompson, J.M. [Geological Survey, Menlo Park, CA (United States)] [Geological Survey, Menlo Park, CA (United States); Kennedy, B.M. [Lawrence Berkeley Lab., CA (United States)] [Lawrence Berkeley Lab., CA (United States); Aoki, Masahiro [Geological Survey of Japan, Tsukuba (Japan)] [Geological Survey of Japan, Tsukuba (Japan)

    1994-12-01

    Opaline sinter samples collected at Yellowstone National Park (YNP) were analyzed for gold by neutron activation and for other trace elements by the inductively coupled plasma optical emission spectroscopy (ICP-OES) method. No correlation was found between Au and As, Sb, or total Fe in the sinters, although the sample containing the highest Au also contains the highest Sb. There also was no correlation of Au in the sinter with the H{sub 2}S concentration in the discharged hot spring water or with the estimated temperature of last equilibration of the water with the surrounding rock. The Au in rhyolitic tuffs and lavas at YNP found within the Yellowstone caldera show the same range in Au as do those outside the caldera, while thermal waters from within this caldera all have been found to contain relatively low dissolved Au and to deposit sinters that contain relatively little Au. Therefore, it is not likely that variations in Au concentrations among these sinters simply reflect differences in leachable Au in the rocks through which the hydrothermal fluids have passed. Rather, variations in [H{sub 2}S], the concentration of total dissolved sulfide, that result from different physical and chemical processes that occur in different parts of the hydrothermal system appear to exert the main control on the abundance of Au in these sinters. Hydrothermal fluids at YNP convect upward through a series of successively shallower and cooler reservoirs where water-rock chemical and isotopic reactions occur in response to changing temperature and pressure. In some parts of the system the fluids undergo decompressional boiling, and in other parts they cool conductively without boiling. Mixing of ascending water from deep in the system with shallow groundwaters is common. All three processes generally result in a decrease in [H{sub 2}S] and destabilize dissolved gold bisulfide complexes in reservoir waters in the YNP system.

  20. Structure, stability, and electronic property of carbon-doped gold clusters Au{sub n}C{sup ?} (n = 1–10): A density functional theory study

    SciTech Connect (OSTI)

    Yan, Li-Li; Liu, Yi-Rong; Huang, Teng; Jiang, Shuai; Wen, Hui; Gai, Yan-Bo; Zhang, Wei-Jun E-mail: wjzhang@aiofm.ac.cn; Huang, Wei E-mail: wjzhang@aiofm.ac.cn; School of Environmental Science and Optoelectronic Technology, University of Science and Technology of China, Hefei, Anhui 230026

    2013-12-28

    The equilibrium geometric structures, relative stabilities, and electronic properties of Au{sub n}C{sup ?} and Au{sub n+1}{sup ?} (n = 1–10) clusters are systematically investigated using density functional theory with hyper-generalized gradient approximation. The optimized geometries show that one Au atom capped on Au{sub n?1}C{sup ?} clusters is a dominant growth pattern for Au{sub n}C{sup ?} clusters. In contrast to Au{sub n+1}{sup ?} clusters, Au{sub n}C{sup ?} clusters are most stable in a quasi-planar or three-dimensional structure because C doping induces the local non-planarity while the rest of the structure continues to grow in a planar mode, resulting in an overall non-2D configuration. The relative stability calculations show that the impurity C atom can significantly enhance the thermodynamic stability of pure gold clusters. Moreover, the effect of C atom on the Au{sub n}{sup ?} host decreases with the increase of cluster size. The HOMO-LUMO gap curves show that the interaction of the C atom with Au{sub n}{sup ?} clusters improves the chemical stability of pure gold clusters, except for Au{sub 3}{sup ?} and Au{sub 4}{sup ?} clusters. In addition, a natural population analysis shows that the charges in corresponding Au{sub n}C{sup ?} clusters transfer from the Au{sub n}{sup ?} host to the C atom. Meanwhile, a natural electronic configuration analysis also shows that the charges mainly transfer between the 2s and 2p orbitals within the C atom.

  1. Initial Study of Solar Control Film in a Hotel Guest Room in Winter 

    E-Print Network [OSTI]

    Chan, W. C.; Chen, Y.; Mak, B.; Li, D.; Huang, Y.; Xie, H.; Hou, G.

    2006-01-01

    In recent years, energy-efficient facilities have prevailed in the Hong Kong and China markets. Many of these facilities claim to generate considerable energy and money savings. Hoteliers, however, find that there is a ...

  2. A user's guide to the GoldSim/BLT-MS integrated software package:a low-level radioactive waste disposal performance assessment model.

    SciTech Connect (OSTI)

    Knowlton, Robert G.; Arnold, Bill Walter; Mattie, Patrick D.

    2007-03-01

    Sandia National Laboratories (Sandia), a U.S. Department of Energy National Laboratory, has over 30 years experience in the assessment of radioactive waste disposal and at the time of this publication is providing assistance internationally in a number of areas relevant to the safety assessment of radioactive waste disposal systems. In countries with small radioactive waste programs, international technology transfer program efforts are often hampered by small budgets, schedule constraints, and a lack of experienced personnel. In an effort to surmount these difficulties, Sandia has developed a system that utilizes a combination of commercially available software codes and existing legacy codes for probabilistic safety assessment modeling that facilitates the technology transfer and maximizes limited available funding. Numerous codes developed and endorsed by the United States Nuclear Regulatory Commission (NRC) and codes developed and maintained by United States Department of Energy are generally available to foreign countries after addressing import/export control and copyright requirements. From a programmatic view, it is easier to utilize existing codes than to develop new codes. From an economic perspective, it is not possible for most countries with small radioactive waste disposal programs to maintain complex software, which meets the rigors of both domestic regulatory requirements and international peer review. Therefore, revitalization of deterministic legacy codes, as well as an adaptation of contemporary deterministic codes, provides a credible and solid computational platform for constructing probabilistic safety assessment models. This document is a reference users guide for the GoldSim/BLT-MS integrated modeling software package developed as part of a cooperative technology transfer project between Sandia National Laboratories and the Institute of Nuclear Energy Research (INER) in Taiwan for the preliminary assessment of several candidate low-level waste repository sites. Breach, Leach, and Transport-Multiple Species (BLT-MS) is a U.S. NRC sponsored code which simulates release and transport of contaminants from a subsurface low-level waste disposal facility. GoldSim is commercially available probabilistic software package that has radionuclide transport capabilities. The following report guides a user through the steps necessary to use the integrated model and presents a successful application of the paradigm of renewing legacy codes for contemporary application.

  3. High carrier mobility in orientation-controlled large-grain (?50??m) Ge directly formed on flexible plastic by nucleation-controlled gold-induced-crystallization

    SciTech Connect (OSTI)

    Park, Jong-Hyeok, E-mail: j-park@nano.ed.kyushu-u.ac.jp [Department of Electronics, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan); JSPS Research Fellow, 5-3-1 Kojimachi, Chiyoda-ku, Tokyo 102-0083 (Japan); Kasahara, Kenji; Hamaya, Kohei; Miyao, Masanobu; Sadoh, Taizoh, E-mail: sadoh@ed.kyushu-u.ac.jp [Department of Electronics, Kyushu University, 744 Motooka, Fukuoka 819-0395 (Japan)

    2014-06-23

    High-carrier-mobility semiconductors on flexible-plastic are essential to realize flexible electronics. For this purpose, electrical properties of orientation-controlled large-grain Ge crystals on flexible-plastic directly formed by nucleation-controlled gold-induced-crystallization (GIC) are examined, and compared with those obtained by aluminum-induced-crystallization (AIC). The Ge crystals show p-type conductions. Here, hole concentrations are 2.2?×?10{sup 17} and 5.8?×?10{sup 20}?cm{sup ?3} for GIC-Ge and AIC-Ge, respectively, which are explained on the basis of the solubility of Au and Al in Ge. Thanks to the low hole concentration, GIC-Ge shows high hole mobility (160?cm{sup 2}?V{sup ?1}?s{sup ?1}) compared with AIC-Ge (37?cm{sup 2}?V{sup ?1}?s{sup ?1}). These demonstrate significant advantage of GIC to realize high-performance flexible-electronics.

  4. Low-dose gold nanoparticles exert subtle endocrine-modulating effects on the ovarian steroidogenic pathway ex vivo independent of oxidative stress

    SciTech Connect (OSTI)

    Larson, Jeremy K.; Carvan, Michael J.; Teeguarden, Justin G.; Watanabe, Gen; Taya, Kazuyoshi; Krystofiak, Evan; Hutz, Reinhold J.

    2014-12-01

    Gold nanoparticles (GNPs) have gained considerable attention for application in science and industry. However, the untoward effects of such particles on female fertility remain unclear. The objectives of this study were to (1) examine the effects of 10-nm GNPs on progesterone and estradiol-17b accumulation by rat ovaries ex vivo and (2) to identify the locus/loci whereby GNPs modulate steroidogenesis via multiple-reference gene quantitative real-time RT-PCR. Regression analyses indicated a positive relationship between both Star (p < 0.05, r2 = 0.278) and Cyp11a1 (p < 0.001, r2 = 0.366) expression and P4 accumulation. upon exposure to 1.43 * 106 GNPs/mL. Additional analyses showed that E2 accumulation was positively associated with Hsd3b1 (p < 0.05, r2 = 0.181) and Cyp17a1 (p < 0.01, r2 = 0.301) expression upon exposure to 1.43 * 13 and 1.43 * 109 GNPs/mL, respectively. These results suggest a subtle treatmentdependent impact of low-dose GNPs on the relationship between progesterone or estradiol-17b and specific steroidogenic target genes, independent of oxidative stress or inhibin.

  5. Electro-optically responsive composites of gold nanospheres in 5CB liquid crystal under direct current and alternating current joint action

    SciTech Connect (OSTI)

    Hadjichristov, Georgi B.; Marinov, Yordan G.; Petrov, Alexander G.; Bruno, Emanuela; Marino, Lucia; Scaramuzza, Nicola

    2014-02-28

    Direct current (DC) electro-optical (EO) control of transmitted laser beam intensity based on EO controlled coherent light scattering and diffraction by stationary longitudinal texture pattern (LTP) is achieved in planar-oriented cells with a composite mixture of polymer-coated gold spherical nanoparticles (Au-NPs) with a mean diameter of about 12?nm and the room-temperature nematic pentylcyanobiphenyl (5CB). At relatively low DC voltage of about 5 V, the effective scattering/diffraction by Au-NPs/5CB composites leads to a spatial spreading of transmitted coherent light from a low-power continuous wave laser beam, resulting in a drastic reduction of its local intensity. The effect is polarization dependent and is strongest when the polarization of the input laser beam is along the LTP. The EO response of Au-NPs/5CB mixtures is studied under DC and alternating current (AC) joint action with the aim of the potential use of these composite materials as EO controlled diffusers. The specific V-shaped sharp dip in the DC voltage-dependent coherent light transmittance of Au-NPs/5CB planar films, as well as the possibility for erasing the scattering/diffractive LTP in the films by joint low AC voltage, can be useful for EO applications in the field of process control and for detection of weak dynamic electric fields.

  6. Bulk gold catalyzed oxidation reactions of amines and isocyanides and iron porphyrin catalyzed N-H and O-H bond insertion/cyclization reactions of diamines and aminoalcohols

    SciTech Connect (OSTI)

    Klobukowski, Erik

    2011-12-29

    This work involves two projects. The first project entails the study of bulk gold as a catalyst in oxidation reactions of isocyanides and amines. The main goal of this project was to study the activation and reactions of molecules at metal surfaces in order to assess how organometallic principles for homogeneous processes apply to heterogeneous catalysis. Since previous work had used oxygen as an oxidant in bulk gold catalyzed reactions, the generality of gold catalysis with other oxidants was examined. Amine N-oxides were chosen for study, due to their properties and use in the oxidation of carbonyl ligands in organometallic complexes. When amine N-oxides were used as an oxidant in the reaction of isocyanides with amines, the system was able to produce ureas from a variety of isocyanides, amines, and amine N-oxides. In addition, the rate was found to generally increase as the amine N-oxide concentration increased, and decrease with increased concentrations of the amine. Mechanistic studies revealed that the reaction likely involves transfer of an oxygen atom from the amine N-oxide to the adsorbed isocyanide to generate an isocyanate intermediate. Subsequent nucleophilic attack by the amine yields the urea. This is in contrast to the bulk gold-catalyzed reaction mechanism of isocyanides with amines and oxygen. Formation of urea in this case was proposed to proceed through a diaminocarbene intermediate. Moreover, formation of the proposed isocyanate intermediate is consistent with the reactions of metal carbonyl ligands, which are isoelectronic to isocyanides. Nucleophilic attack at coordinated CO by amine N-oxides produces CO{sub 2} and is analogous to the production of an isocyanate in this gold system. When the bulk gold-catalyzed oxidative dehydrogenation of amines was examined with amine N-oxides, the same products were afforded as when O{sub 2} was used as the oxidant. When the two types of oxidants were directly compared using the same reaction system and conditions, it was found that the oxidative dehydrogenation of dibenzylamine to Nbenzylidenebenzylamine, with N-methylmorpholine N-oxide (NMMO), was nearly quantitative (96%) within 24 h. However, the reaction with oxygen was much slower, with only a 52% yield of imine product over the same time period. Moreover, the rate of reaction was found to be influenced by the nature of the amine N-oxide. For example, the use of the weakly basic pyridine N-oxide (PyNO) led to an imine yield of only 6% after 24 h. A comparison of amine N-oxide and O2 was also examined in the oxidation of PhCH{sub 2}OH to PhCHO catalyzed by bulk gold. In this reaction, a 52% yield of the aldehyde was achieved when NMMO was used, while only a 7% product yield was afforded when O{sub 2} was the oxidant after 48 h. The bulk gold-catalyzed oxidative dehydrogenation of cyclic amines generates amidines, which upon treatment with Aerosil and water were found to undergo hydrolysis to produce lactams. Moreover, 5-, 6-, and 7-membered lactams could be prepared through a one-pot reaction of cyclic amines by treatment with oxygen, water, bulk gold, and Aerosil. This method is much more atom economical than industrial processes, does not require corrosive acids, and does not generate undesired byproducts. Additionally, the gold and Aerosil catalysts can be readily separated from the reaction mixture. The second project involved studying iron(III) tetraphenylporphyrin chloride, Fe(TPP)Cl, as a homogeneous catalyst for the generation of carbenes from diazo reagents and their reaction with heteroatom compounds. Fe(TPP)Cl, efficiently catalyzed the insertion of carbenes derived from methyl 2-phenyldiazoacetates into O-H bonds of aliphatic and aromatic alcohols. Fe(TPP)Cl was also found to be an effective catalyst for tandem N-H and O-H insertion/cyclization reactions when 1,2-diamines and 1,2-alcoholamines were treated with diazo reagents. This approach provides a one-pot process for synthesizing piperazinones and morpholinones and related analogues such as quinoxalinones and benzoxazin-2-ones.

  7. Gold(I) chloride adducts of 1,3-bis(di-2-pyridylphosphino)propane: synthesis, structural studies and antitumour activity

    SciTech Connect (OSTI)

    Humphreys, Anthony S.; Filipovska, Aleksandra; Berners-Price, Susan J.; Koutsantonis, George A.; Skelton, Brian W.; White, Allan H.

    2008-06-30

    The novel water soluble bidentate phosphine ligand 1,3-bis(di-2-pyridylphosphino)propane (d2pypp) has been synthesized by a convenient route involving treatment of 2-pyridyllithium with Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} and isolation in crystalline form as the hydrochloride salt. The synthesis of the precursor Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} has been optimized by the use of triphosgene as the chlorinating agent. The 2:1 and 1:2 AuCl:d2pypp adducts have been synthesized and characterized by NMR spectroscopy and single crystal X-ray studies, and shown to be of the form (AuCl){sub 2}({mu}-d2pypp-P,P{prime}) and Au(d2pypp-P,P{prime}){sub 2}Cl(-3.75H{sub 2}O), respectively. The latter is more lipophilic than analogous 1:2 adducts of gold(I) chloride with the diphosphine ligands 1,2-bis(di-n-pyridylphosphino)ethane (dnpype) for n = 2, 3 and 4, based on measurement of the n-octanol-water partition coefficient (log P = -0.46). A single crystal structure determination of the 1:2 Au(I) complex of the 3-pyridyl ethane ligand shows it to be of the form [Au(d3pype-P,P{prime}){sub 2}]Cl {center_dot} 5H{sub 2}O. The in vitro cytotoxic activity of [Au(d2pypp){sub 2}]Cl was assessed in human normal and cancer breast cells and selective toxicity to the cancer cells found. The significance of these results to the antitumour properties of chelated 1:2 Au(I) diphosphine complexes is discussed.

  8. Change in magnetic and structural properties of FeRh thin films by gold cluster ion beam irradiation with the energy of 1.67?MeV/atom

    SciTech Connect (OSTI)

    Koide, T.; Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Sakamaki, M.; Amemiya, K. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801 (Japan); Matsui, T., E-mail: t-matsui@21c.osakafu-u.ac.jp [Research Organization for the 21st Century, Osaka Prefecture University Sakai, Osaka 599-8531 (Japan)

    2014-05-07

    The effect of energetic cluster ion beam irradiation on magnetic and structural properties of FeRh thin films have been investigated. The cluster ions used in the present studies consist of a few gold atoms with the energy of 1.67?MeV/gold atom. Saturation magnetization of the sample irradiated with Au3 cluster ion beam (280?emu/cc) is larger than that for the irradiated sample with Au1 ion beam (240?emu/cc) for the same irradiation ion fluence. These results can also be confirmed by the X-ray magnetic circular dichroism (XMCD) measurement; the XMCD signal for Au3 cluster ion irradiation is larger than that for Au1 ion irradiation. Since the ion beam irradiation induced magnetization of FeRh is significantly correlated with the amount of the lattice defects in the samples, cluster ion beam irradiation can be considered to effectively introduce the lattice defects in B2-type FeRh rather than the single ion beam. Consequently, cluster ion irradiation is better than single ion irradiation for the viewpoint of saturation magnetization, even if the same irradiation energy is deposited in the samples.

  9. Mercury Detection with Gold Nanoparticles

    E-Print Network [OSTI]

    Crosby, Jeffrey

    2013-01-01

    relative humididty mole fraction of CO2 in PPM or umol/mol5.34e-7)*(CO2-450)); %Calculate the vapor mole fraction from

  10. Gold Nanowire Thermophones Rajen Dutta,

    E-Print Network [OSTI]

    Papamoschou, Dimitri

    patterned nanowire electrodeposition (LPNE). The properties of nanowire arrays for generating sound dimensions of these wires over the range from 270 to 500 nm. INTRODUCTION Thermoacoustic speakers, also types of nanomaterials capable of functioning as thermoacoustic transducers. Niskanen and Vesterinen et

  11. Turning greenhouse gases into gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are under way to find ways to prevent, capture and sequester-perhaps even bury-CO2 emissions and reduce their negative effects. But some researchers say CO2 is getting a bad...

  12. Mercury Detection with Gold Nanoparticles

    E-Print Network [OSTI]

    Crosby, Jeffrey

    2013-01-01

    also examined similar palladium-hydrogen catalytic surfacedtransistors. The palladium, a hydrogen catalyst, converts Hof the palladium device acted as a sink for hydrogen. There

  13. Going green earns Laboratory gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUseful LinksGlassRegistrationMissionGOINGGoing

  14. Gold Nanoparticles by Alfalfa Plants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUsefulJorge Gardea-Torresdey, University of

  15. Investigation of the effects of cell model and subcellular location of gold nanoparticles on nuclear dose enhancement factors using Monte Carlo simulation

    SciTech Connect (OSTI)

    Cai, Zhongli; Chattopadhyay, Niladri; Kwon, Yongkyu Luke; Pignol, Jean-Philippe; Lechtman, Eli; Reilly, Raymond M.; Department of Medical Imaging, University of Toronto, Toronto, Ontario M5S 3E2; Toronto General Research Institute, University Health Network, Toronto, Ontario M5G 2C4

    2013-11-15

    Purpose: The authors’ aims were to model how various factors influence radiation dose enhancement by gold nanoparticles (AuNPs) and to propose a new modeling approach to the dose enhancement factor (DEF).Methods: The authors used Monte Carlo N-particle (MCNP 5) computer code to simulate photon and electron transport in cells. The authors modeled human breast cancer cells as a single cell, a monolayer, or a cluster of cells. Different numbers of 5, 30, or 50 nm AuNPs were placed in the extracellular space, on the cell surface, in the cytoplasm, or in the nucleus. Photon sources examined in the simulation included nine monoenergetic x-rays (10–100 keV), an x-ray beam (100 kVp), and {sup 125}I and {sup 103}Pd brachytherapy seeds. Both nuclear and cellular dose enhancement factors (NDEFs, CDEFs) were calculated. The ability of these metrics to predict the experimental DEF based on the clonogenic survival of MDA-MB-361 human breast cancer cells exposed to AuNPs and x-rays were compared.Results: NDEFs show a strong dependence on photon energies with peaks at 15, 30/40, and 90 keV. Cell model and subcellular location of AuNPs influence the peak position and value of NDEF. NDEFs decrease in the order of AuNPs in the nucleus, cytoplasm, cell membrane, and extracellular space. NDEFs also decrease in the order of AuNPs in a cell cluster, monolayer, and single cell if the photon energy is larger than 20 keV. NDEFs depend linearly on the number of AuNPs per cell. Similar trends were observed for CDEFs. NDEFs using the monolayer cell model were more predictive than either single cell or cluster cell models of the DEFs experimentally derived from the clonogenic survival of cells cultured as a monolayer. The amount of AuNPs required to double the prescribed dose in terms of mg Au/g tissue decreases as the size of AuNPs increases, especially when AuNPs are in the nucleus and the cytoplasm. For 40 keV x-rays and a cluster of cells, to double the prescribed x-ray dose (NDEF = 2) using 30 nm AuNPs, would require 5.1 ± 0.2, 9 ± 1, 10 ± 1, 10 ± 1 mg Au/g tissue in the nucleus, in the cytoplasm, on the cell surface, or in the extracellular space, respectively. Using 50 nm AuNPs, the required amount decreases to 3.1 ± 0.3, 8 ± 1, 9 ± 1, 9 ± 1 mg Au/g tissue, respectively.Conclusions: NDEF is a new metric that can predict the radiation enhancement of AuNPs for various experimental conditions. Cell model, the subcellular location and size of AuNPs, and the number of AuNPs per cell, as well as the x-ray photon energy all have effects on NDEFs. Larger AuNPs in the nucleus of cluster cells exposed to x-rays of 15 or 40 keV maximize NDEFs.

  16. Abstract--An evolutionary "Third Way" approach for restructuring the electricity industry is proposed, striking a

    E-Print Network [OSTI]

    Oren, Shmuel S.

    Abstract-- An evolutionary "Third Way" approach for restructuring the electricity industry aspects of implementing this role within liberalized wholesale markets are also examined. Index Terms--Electricity of the electricity industry that builds on lessons learned from experience and the principle of risk management

  17. Real-Time Visualization for Prevention of Excavation Related Utility Strikes Sanat A. Talmaki

    E-Print Network [OSTI]

    Kamat, Vineet R.

    Saidi and Ms. Geraldine Cheok for supporting me during my time at the National Institute of Standards

  18. Analysis of the growth of strike-slip faults using effective medium theory

    E-Print Network [OSTI]

    Aydin, A.

    2010-01-01

    and Analytical Methods in Geomechanics (to be submitted).Mineral Sciences and Geomechanics Abstracts 9, 37-86.

  19. http://nyti.ms/113BSkJ Lightning Might Strike More in a Warmer World

    E-Print Network [OSTI]

    Romps, David M.

    . 13, 2014 To the ever-growing list of projected effects from global warming, add a curious entry that helps to break down methane, a powerful greenhouse gas that contributes to global warming. Kevin E have warned that an increase that high would likely be devastating to the food supply, and would lead

  20. New Or Rehab: Striking A New Balance Under California's Affordable Housing Standards

    E-Print Network [OSTI]

    Rosenthal, Larry A.; Listokin, David

    2009-01-01

    Title 24 must reduce energy use per square foot by 25%, as promoting energy reductions per square foot by 25 percent ? 

  1. The supercomputer "Piz Daint", named after a striking mountain that dominates the Val Mstair,

    E-Print Network [OSTI]

    Peak Performance 7.787 Petaflops Memory Capacity per node 32 GB (DDR3-1600); 6 GB non-ECC GDDR5 Memory Bandwidth per node 51.2 GB/s DDR3 ; 250.0 GB/s non-ECC GDDR5 Total System Memory 169 TB DDR3; 32 TB non

  2. His Strike, Her Fight: Gender Roles and Identity Formation in the Massillon War

    E-Print Network [OSTI]

    Sampson, Jason W.

    2010-01-01

    Formation in Scotland and the American Midwest, 1830-1924 (Urbana: University of IllinoisFormation in Scotland and the American Midwest, 1830-1924. Urbana: University of Illinois

  3. His Strike, Her Fight: Gender Roles and Identity Formation in the Massillon War

    E-Print Network [OSTI]

    Sampson, Jason W.

    2010-01-01

    Shines: A History of America's Bloody Coal Industry. 1st ed.Shines: A History of America's Bloody Coal Industry, 1stin nineteenth-century America. Coal-mining operations in the

  4. First measurements of ion energy distribution at the divertor strike point during DIII-D disruptions

    SciTech Connect (OSTI)

    Parks, P.B.; Brooks, N.H.; West, W.P.; Wong, C.P.C. [General Atomics, San Diego, CA (United States); Bastasz, R.; Wampler, W.R.; Whyte, D.

    1995-12-31

    Plasma/wall interaction studies are being carried out using the Divertor Materials Exposure System (DiMES) on DIII-D. The objective of the experiment is to determine the kinetic energy and flux of deuterium ions reaching the divertor target during argon-induced radiative disruptions. The experiment utilizes a special slotted ion analyzer mounted over a Si sample to collect the fast charge-exchange (CX) deuterium neutrals emitted within the recycled cold neutral layer (CNL) which serves as a CX target for the incident ions. A theoretical interpretation of the experiment reveals a strong forward pitch-angle dependence in the approaching ion distribution function. The depth distribution of the trapped D in the Si sample was measured using low-energy direct recoil spectroscopy. Comparison with the TRIM code using monoenergetic ions indicated that the best fit to the data was obtained for an ion energy of 100 eV. An estimate of the CNL thickness {integral}nd{ell} indicates that during disruptions the CNL cushion is thick enough to reduce the local ion heat load by {approximately}30% due to CX refluxing.

  5. Along-strike changes in Himalayan thrust geometry: Topographic and tectonic discontinuities in western Nepal

    E-Print Network [OSTI]

    Harvey, JE; Burbank, DW; Bookhagen, B

    2015-01-01

    denuda- tion, relief, and uplift in large, mid-latitudeBedrock inci- sion, rock uplift and threshold hillslopes induring rapid post–12 Ma uplift of the Bolivian Andes:

  6. Synoptic and mesoscale controls on the isotopic composition of individual storms systems striking the western US

    E-Print Network [OSTI]

    Johnson, KR; Berkelhammer, M; Stott, L; Kei, Y

    2012-01-01

    011-1262-3 Synoptic and mesoscale controls on the isotopicet al. : Synoptic and mesoscale controls on the isotopicrecord of syn- optic and mesoscale atmospheric processes. In

  7. Internal structure of the Kern Canyon Fault, California: a deeply exhumed strike-slip fault 

    E-Print Network [OSTI]

    Neal, Leslie Ann

    2002-01-01

    Deformation and mineral alteration adjacent to a 2 km long segment of the Kern Canyon fault near Lake Isabella, California are studied to characterize the internal structure of the fault zone and to understand the development of fault structure...

  8. FORECAST OF ATLANTIC SEASONAL HURRICANE ACTIVITY AND LANDFALL STRIKE PROBABILITY FOR 2013

    E-Print Network [OSTI]

    Connors, Daniel A.

    Hurricanes (MH) (2.0) 4 4 0 3 3 Major Hurricane Days (MHD) (3.9) 9 9 0 7 7 Accumulated Cyclone Energy (ACE Coast Including Peninsula Florida - 40% (full-season average for last century is 31%) 3) Gulf Coast from%) New Jersey 2% (1%) New York 10% (8%) 4% (3%) Connecticut 10% (7%) 3% (2%) Rhode

  9. Distributed Measurement-Aware Routing: Striking a Balance between Measurement and Traffic

    E-Print Network [OSTI]

    Chuah, Chen-Nee

    Engineering Chia-Wei Chang, Han Liu Guanyao Huang, Bill Lin, and Chen-Nee Chuah Department of Electrical Engineering, University of California, Davis Abstract--Network-wide traffic measurement is important

  10. New Or Rehab: Striking A New Balance Under California's Affordable Housing Standards

    E-Print Network [OSTI]

    Rosenthal, Larry A.; Listokin, David

    2009-01-01

    Affordable. ”  Washington:  US HUD Office of Policy upon earlier, unpublished HUD research by David Listokin I).   Washington, DC:  US HUD, Office of Policy Development 

  11. New Or Rehab: Striking A New Balance Under California's Affordable Housing Standards

    E-Print Network [OSTI]

    Rosenthal, Larry A.; Listokin, David

    2009-01-01

    Section 8 supply?side programs, HOME, and other funding categories, HUD Section 8 rental subsidies for 8 units reserved  for formerly homeless (via an SRO Moderate Rehabilitation subsidy award from HUD).  

  12. Along-strike changes in Himalayan thrust geometry: Topographic and tectonic discontinuities in western Nepal

    E-Print Network [OSTI]

    Harvey, JE; Burbank, DW; Bookhagen, B

    2015-01-01

    explanation for the northern microseismic band. However, iffor the southern microseismic band or topographic step.the full suite of microseismic and topographic data. (4) A

  13. Dynamic Rupture and Ground Motion Modeling on Realistically Complex Strike-Slip Faults

    E-Print Network [OSTI]

    Lozos, Julian Charles

    2013-01-01

    for seismic-hazard analysis and the process of earthquakefor seismic-hazard analysis and the process of earthquakefor seismic-hazard analysis and the process of earthquake

  14. Hometown Hazard Planning Overarching concept: Natural disasters can strike almost anywhere on earth and

    E-Print Network [OSTI]

    Polly, David

    and scientists try to determine how much risk exists. In this instance students will assume the role, floods, wild fires, dam failures, pipeline or factory explosions and even terrorism. This list is not all

  15. Synoptic and mesoscale controls on the isotopic composition of individual storms systems striking the western US

    E-Print Network [OSTI]

    Johnson, KR; Berkelhammer, M; Stott, L; Kei, Y

    2012-01-01

    1989) working in the Yucca Mountain region of Nevada andground water in the Yucca Mountain region, southern Nevada:

  16. THE STRIKING NEAR-INFRARED MORPHOLOGY OF THE INNER REGION IN M100

    E-Print Network [OSTI]

    J. H. Knapen; J. E. Beckman; I. Shlosman; R. F. Peletier; C. H. Heller; R. S. de Jong

    1995-02-06

    New optical and NIR K-band images of the inner 3 kpc region of the nearby Virgo spiral M100 (NGC 4321) display remarkable morphological changes with wavelength. While in the optical the light is dominated by a circumnuclear zone of enhanced star formation, the features in the 2.2\\mum image correspond to a newly discovered kpc-size stellar bar, and a pair of leading arms situated inside an ovally-shaped region. Only 5% of the K flux is emitted in antisymmetric structures. This indicates that the morphology seen in the NIR is dominated by a global density wave. Making a first-order correction for the presence of localized dust extinction in K using the I-K image, we find that the observed leading arm morphology is slightly hidden by dust. Possible mechanisms responsible for the optical and NIR morphology are discussed, and tests are proposed to discriminate between them. Conclusions are supported with an evolutionary stellar population model reproducing the optical and NIR colors in a number of star forming zones. We argue that this morphology is compatible with the presence of a pair of inner Lindblad resonances in the region, and show this explicitly in an accompanying paper by detailed numerical modeling. The observed phenomena may provide insight into physical processes leading to central activity in galaxies.

  17. Mean mass-specific metabolic rates are strikingly similar across life's major domains: Evidence for life's

    E-Print Network [OSTI]

    Minnesota, University of

    on consumption of energy from the environment. The amount of energy--per unit time per unit mass. Chownc , Peter B. Reichd , and Valery M. Gavrilove aTheoretical Physics Division, Petersburg Nuclear but unanswered biological question asks how much energy, on average, Earth's different life forms spend per unit

  18. Test Report for Permanganate and Cold Strontium Strike for Tank 241-AN-102

    SciTech Connect (OSTI)

    Duncan, James B.; Huber, Heinz J.; Smalley, Colleen S.

    2013-11-27

    Tanks 241-AN-102 and 241-AN-107 supernatants contain soluble Sr-90 and transuranic elements that require removal prior to vitrification to comply with the Waste Treatment and Immobilization Plant immobilized low-activity waste specification (WTP Contract, DE-AC27-01RV 14136, Specification 2.2.2.8, "Radionuclide Concentration Limitations") and the U.S. Nuclear Regulatory Commission provisional agreement on waste incidental to reprocessing (letter, Paperiello, C. J., "Classification of Hanford Low-Activity Tank Waste Fraction"). These two tanks have high concentrations of organics and organic complexants and are referred to as complexant concentrate tanks. A precipitation process using sodium permanganate (NaMnO{sub 4}) and strontium nitrate (Sr(NO{sub 3}){sub 2}) was developed and tested with tank waste samples to precipitate Sr-90 and transuranic elements from the supernate (PNWD-3141, Optimization of Sr/TRU Removal Conditions with Samples of AN-102 Tank Waste). Testing documented in this report was conducted to further evaluate the use of the strontium nitrate/sodium permanganate process in tank farms with a retention time of up to 12 months. Previous testing was focused on developing a process for deployment in the ultrafiltration vessels in the Waste Treatment and Immobilization Plant. This environment is different from tank farms in two important ways: the waste is diluted in the Waste Treatment and Immobilization Plant to ~5.5 M sodium, whereas the supernate in the tank farms is ~9 M Na. Secondly, while the Waste Treatment and Immobilization Plant allows for a maximum treatment time of hours to days, the in-tank farms treatment of tanks 241-AN102 and 241-AN-107 will result in a retention time of months (perhaps up to12 months) before processing. A comparative compilation of separation processes for Sr/transuranics has been published as RPP-RPT-48340, Evaluation of Alternative Strontium and Transuranic Separation Processes. This report also listed the testing needs for the permanganate precipitation process to be field-deployable. A more comprehensive listing of future testing needs to allow the process to be field deployable are contained in RPP-PLAN-51288, Development Test Plan for Sr/TRU Precipitation Process.

  19. Striking legal Balance among consumer protection, contract law and technological self-defence 

    E-Print Network [OSTI]

    Matwyshyn, Andrea M

    Paper presented by Matwyshyn for the Privacy Workshop, chaired by Edwards and held in September 2005.

  20. Scaled electromechanical modeling of the F-35A Joint Strike Fighter

    E-Print Network [OSTI]

    Marmorato, Leonardo F. (Leonardo Francesco), 1982-

    2004-01-01

    During the early 1990s, The U.S. Department of Defense embarked on a search for an affordable, next generation fighter aircraft that could fit the common needs of the Navy, Air Force, and Marines, as well as several allied ...

  1. Touching the void: A striking drop in stellar halo density beyond 50 kpc

    SciTech Connect (OSTI)

    Deason, A. J.; Rockosi, C. M.; Belokurov, V.; Koposov, S. E.

    2014-05-20

    We use A-type stars selected from Sloan Digital Sky Survey data release 9 photometry to measure the outer slope of the Milky Way stellar halo density profile beyond 50 kpc. A likelihood-based analysis is employed that models the ugr photometry distribution of blue horizontal branch and blue straggler stars. In the magnitude range 18.5 < g < 20.5, these stellar populations span a heliocentric distance range of: 10 ? D {sub BS}/kpc ? 75, 40 ? D {sub BHB}/kpc ? 100. Contributions from contaminants, such as QSOs, and the effect of photometric uncertainties, are also included in our modeling procedure. We find evidence for a very steep outer halo profile, with power-law index ? ? 6 beyond Galactocentric radii r = 50 kpc, and even steeper slopes favored (? ? 6-10) at larger radii. This result holds true when stars belonging to known overdensities, such as the Sagittarius stream, are included or excluded. We show that, by comparison to numerical simulations, stellar halos with shallower slopes at large distances tend to have more recent accretion activity. Thus, it is likely that the Milky Way has undergone a relatively quiet accretion history over the past several gigayears. Our measurement of the outer stellar halo profile may have important implications for dynamical mass models of the Milky Way, where the tracer density profile is strongly degenerate with total mass estimates.

  2. Remarkable Rates of Lightning Strike Mortality in Malawi Monique Borgerhoff Mulder1,5

    E-Print Network [OSTI]

    California at Davis, University of

    , California, United States of America, 2 Mpamba Health Center PA Mpamba, Nkhata Bay, Malawi, 3 Department, California, United States of America, 4 Graduate Group in Ecology, University of California, Davis, California, United States of America, 5 Wissenschaftskolleg zu Berlin, Germany Abstract Livingstone's second

  3. New Or Rehab: Striking A New Balance Under California's Affordable Housing Standards

    E-Print Network [OSTI]

    Rosenthal, Larry A.; Listokin, David

    2009-01-01

    especially  if  code  officials  are  flexible  in of the time … and code officials tend to be knowledgeable concerning the  code among local officials  and others.   

  4. Predictions of striking energy and angular dependence in pp --> (pp)_S-wave pi^0 production

    E-Print Network [OSTI]

    J. A. Niskanen

    2006-03-30

    A phenomenological calculation from threshold to 800 MeV of the initial proton beam energy is presented to describe recent data on the reaction pp --> (pp)_S-wave pi^0 with a low energy cut on the final state diproton excitation energy. A strong forward dip is obtained in the differential cross section as in the data from COSY at 800 MeV, although the absolute value of the forward cross section is too low. Earlier low energy data from CELSIUS are reasonably well reproduced. In the unexplored energy interval between these two experiments the model predicts a spectacular energy dependence both in the forward direction and in the angle-integrated cross section.

  5. A new multilayered visco-elasto-plastic experimental model to study strike-slip

    E-Print Network [OSTI]

    Cattin, Rodolphe

    between kinematic and mechanical parameters, we have developed a new experimental approach allowing, results show that the model succeed in reproducing the deformation mechanisms and surface kinematics analysis of surface deformation associated with active fault seismic cycle. However, the study

  6. Assessment of Strike of Adult Killer Whales by an OpenHydro Tidal Turbine Blade

    SciTech Connect (OSTI)

    Carlson, Thomas J.; Elster, Jennifer L.; Jones, Mark E.; Watson, Bruce E.; Copping, Andrea E.; Watkins, Michael L.; Jepsen, Richard A.; Metzinger, Kurt

    2012-02-01

    Report to DOE on an analysis to determine the effects of a potential impact to an endangered whale from tidal turbines proposed for deployment in Puget Sound.

  7. New Metrics for Comparison of Taxonomies Reveal Striking Discrepancies among Species Delimitation

    E-Print Network [OSTI]

    Vences, Miguel

    outcomes depending on the species criteria applied, but methods should be chosen that minimize-gene coalescence statistics, assignment tests or other rationales related to nuclear DNA (nDNA) allele sharing in study design, data collection and analysis, decision to publish, or preparation of the manuscript

  8. Argonne and CalBattery strike deal for silicon-graphene anode material -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D SFederal8823 RevisionApril 22-23,ScienceEnergy Innovation

  9. Pull-Apart in Strike-Slip Fault Zone | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource HistoryPotentialRuralUtilityScalePVGeneration JumpPublic Utility District No 2 JumpIndiana:Virginia:

  10. Frontiers in Science: The Microbe Strikes Back: The Return of Tuberculosis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvanServicesAmesFourFrom GlimmerVideochallenging3, 2015

  11. Frontiers in Science: The Microbe Strikes Back: The Return of Tuberculosis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvanServicesAmesFourFrom GlimmerVideochallenging3, 20156,

  12. California: Advanced 'Drop-In' Biofuels Power the Navy's Green Strike Group

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:I DueBETOof Energy Office04 Calendar Year3Economyof|

  13. Lessons Learned From The 200 West Pump And Treatment Facility Construction Project At The US DOE Hanford Site - A Leadership For Energy And Environmental Design (LEED) Gold-Certified Facility

    SciTech Connect (OSTI)

    Dorr, Kent A. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Ostrom, Michael J. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Freeman-Pollard, Jhivaun R. [CH2M HILL Plateau Remediation Company, Richland, WA (United States)

    2012-11-14

    CH2M Hill Plateau Remediation Company (CHPRC) designed, constructed, commissioned, and began operation of the largest groundwater pump and treatment facility in the U.S. Department of Energy's (DOE) nationwide complex. This one-of-a-kind groundwater pump and treatment facility, located at the Hanford Nuclear Reservation Site (Hanford Site) in Washington State, was built in an accelerated manner with American Recovery and Reinvestment Act (ARRA) funds and has attained Leadership in Energy and Environmental Design (LEED) GOLD certification, which makes it the first non-administrative building in the DOE Office of Environmental Management complex to earn such an award. There were many contractual, technical, configuration management, quality, safety, and LEED challenges associated with the design, procurement, construction, and commissioning of this $95 million, 52,000 ft groundwater pump and treatment facility. This paper will present the Project and LEED accomplishments, as well as Lessons Learned by CHPRC when additional ARRA funds were used to accelerate design, procurement, construction, and commissioning of the 200 West Groundwater Pump and Treatment (2W P&T) Facility to meet DOE's mission of treating contaminated groundwater at the Hanford Site with a new facility by June 28, 2012.

  14. Lessons Learned from the 200 West Pump and Treatment Facility Construction Project at the US DOE Hanford Site - A Leadership for Energy and Environmental Design (LEED) Gold-Certified Facility

    SciTech Connect (OSTI)

    Dorr, Kent A.; Ostrom, Michael J.; Freeman-Pollard, Jhivaun R.

    2013-01-11

    CH2M Hill Plateau Remediation Company (CHPRC) designed, constructed, commissioned, and began operation of the largest groundwater pump and treatment facility in the U.S. Department of Energy’s (DOE) nationwide complex. This one-of-a-kind groundwater pump and treatment facility, located at the Hanford Nuclear Reservation Site (Hanford Site) in Washington State, was built to an accelerated schedule with American Recovery and Reinvestment Act (ARRA) funds. There were many contractual, technical, configuration management, quality, safety, and Leadership in Energy and Environmental Design (LEED) challenges associated with the design, procurement, construction, and commissioning of this $95 million, 52,000 ft groundwater pump and treatment facility to meet DOE’s mission objective of treating contaminated groundwater at the Hanford Site with a new facility by June 28, 2012. The project team’s successful integration of the project’s core values and green energy technology throughout design, procurement, construction, and start-up of this complex, first-of-its-kind Bio Process facility resulted in successful achievement of DOE’s mission objective, as well as attainment of LEED GOLD certification, which makes this Bio Process facility the first non-administrative building in the DOE Office of Environmental Management complex to earn such an award.

  15. Gold(I)-Catalyzed Nucleophilic Additions

    E-Print Network [OSTI]

    LaLonde, Rebecca Lyn K. C.

    2010-01-01

    enyloxycarbamate 3.36. The crude oil was purified by columnenyloxycarbamate 3.26. The crude oil was purified by columndienyloxycarbamate 3.38. The crude oil was purified by flash

  16. Conditional probability Gold coins and BMWs

    E-Print Network [OSTI]

    Adler, Robert J.

    Independence 1 #12;' & $ % Tossing three fair coins = {HHH, HHT, HTH, THH, HTT, THT, TTH, TTT} A {2 or more that at least 2 were seen? P{3 heads|At least 2 were seen} P{B|A} = P{A B|A} = #{HHH} #{HHH, HHT, HTH, THH

  17. BPA headquarters now 'gold certified' for sustainability

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tanks. Other notable accomplishments include electronic recycling, a recycling and composting program that cut waste by 44 percent, electric vehicle charging stations in its...

  18. Gold(I)-Catalyzed Nucleophilic Additions

    E-Print Network [OSTI]

    LaLonde, Rebecca Lyn K. C.

    2010-01-01

    V7.06; Siemens Industrial Automation, Inc. : Madison, WI, (V7.06; Siemens Industrial Automation, Inc. : Madison, WI, (

  19. Continuous release of gentamicin from gold nanocarriers

    E-Print Network [OSTI]

    Perni, Stefano

    Antibiotics are still the most effective agents used to fight bacterial infections. Antibiotics are quickly metabolised or excreted from the human body, thus they need to be frequently administered (a few times a day) and ...

  20. FISSION OF GOLD BY CARBON IONS

    E-Print Network [OSTI]

    Gordon, Glen E.; Larsh, Almon E.; Sikkeland, Torbjorn; Seaborg, Glenn T.

    2008-01-01

    Atomic Energy, Geneva, 1958 (United Nations, New York 1958),Atomic Energy, Geneva, 1958 (United Nations, New York, VoLof Atomic Energy, Geneva, 1958 (United Nations, New York,

  1. Gold(I)-Catalyzed Nucleophilic Additions

    E-Print Network [OSTI]

    LaLonde, Rebecca Lyn K. C.

    2010-01-01

    Technologies Whelk-O 1 column (98:2 hexanes:isopropanol; 1Technologies Whelk-O 1 column (98:2 hexanes:Ethanol; 1 mL/Technologies Whelk-O 1 column (98:2 Hexanes:Ethanol; 1 mL/

  2. Linda R. Richardson John R. Gold

    E-Print Network [OSTI]

    in and population structure of red groupet Epinephelus morio, from the Gulf of Mexico* Red grouper, Epinephelus'the north coast of the Yucatan Peninsula, Mexico (Brule and Canche, 1993I. Studies on the biology ofred grou- pects of early life history and pat- terns of migration (Moe, 1969; Brule and Canche, 1993). Red grouper

  3. FISSION OF GOLD BY CARBON IONS

    E-Print Network [OSTI]

    Gordon, Glen E.; Larsh, Almon E.; Sikkeland, Torbjorn; Seaborg, Glenn T.

    2008-01-01

    142±6 to 146±6 Mev. energie s, the variation of laboratory-of frag- ment kinetic energie s on laboratory- system angle

  4. Black gold: return of the king

    SciTech Connect (OSTI)

    O'Connell, J.

    2008-12-15

    The coal industry has woken from its slumber and finds itself ill-prepared for the demands being made upon it. Exporters are proving slow to expand their capacities and overcome infrastructural bottlenecks. The financial crisis may cause a hiatus in demand growth, but it will also limit finance for investment. 3 figs.

  5. Gold Coast Sea FISHERY LEAFLET 251

    E-Print Network [OSTI]

    :atic. The machines ' re s ' m lCJ n cnn 11 t.; .... t - dr i ven from s i ngl e one ho rse power electric mot or

  6. Strengthening in Gold Nanopillars with Nanoscale Twins

    E-Print Network [OSTI]

    Sansoz, Frederic

    *, Physics Department, The UniVersity of Vermont, Burlington, Vermont 05405, and School of Engineering, The UniVersity of Vermont, Burlington, Vermont 05405 Received April 23, 2007; Revised Manuscript Received

  7. Gold Standard Program Model | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County, Georgia: Energy Resources Jump

  8. Gold Country Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEniaElectric JumpAtlas

  9. Tracking Individual Gold Nanoparticles | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr.Theories81Towards HeavyCoupledTracking Individual

  10. Interconnecting gold islands with DNA origami

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenryInhibitingInteractive Jobs Interactive Jobs To run

  11. Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility...

  12. Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold...

  13. Splashing phenomena of room temperature liquid metal droplet striking on the pool of the same liquid under ambient air environment

    E-Print Network [OSTI]

    Haiyan Li; Shengfu Mei; Lei Wang; Yunxia Gao; Jing Liu

    2013-09-04

    In this article, the fluid dynamics of room temperature liquid metal (RTLM) droplet impacting onto a pool of the same liquid in ambient air was investigated. A series of experiments were conducted in order to disclose the influence of the oxidation effect on the impact dynamics. The droplet shape and impact phenomenology were recorded with the aid of a high-speed digital camera. The impact energy stored in the splash structures was estimated via a theoretical model and several morphological parameters obtained from instantaneous images of the splash. It was observed that the droplet shape and the splashing morphology of RTLM were drastically different from those of water, so was the impact dynamics between room temperature LM pool and high temperature LM pool. The energy analysis disclosed that the height of the jet is highly sensitive to the viscosity of the fluid, which is subjected to the oxidation effect and temperature effect simultaneously, and thus perfectly explained the phenomena. These basic findings are important for the application of RTLM in a series of newly emerging technologies such as liquid metal based spray cooling, ink-jet printed electronics, interface material painting and coating, metallurgy, and 3D packages, etc.

  14. First measurements of the ion energy distribution at the divertor strike point during DIII-D disruptions

    SciTech Connect (OSTI)

    Parks, P.B.; Brooks, N.H.; West, W.P.; Wong, C.P.C. [General Atomics, San Diego, CA (United States); Bastasz, R.; Wampler, W.R. [Sandia National Labs., Albuquerque, NM (United States); Whyte, D. [Inst. National de la Recherche Scientifique, Varennes, Quebec (Canada)

    1996-03-01

    Plasma disruptions are a serious concern in tokamak design because of the high impulsive heat loads which can cause strong erosion of divertor materials due to enhanced sputtering, or melting/ablation in the most severe cases. Predictions of net erosion rates and hence component lifetimes are very difficult and are highly dependent on the plasma conditions over the divertor target. It is therefore necessary to characterize the properties of the scrape-off plasma near the divertor target plate under these special conditions. Here, plasma/wall interaction studies are being carried out using the Divertor Materials Exposure System (DiMES) on DIII-D. The objective of the experiment is to determine the kinetic energy and flux of deuterium ions reaching the divertor target during argon-induced radiative disruptions. The experiment utilizes a special slotted ion analyzer mounted over a Si sample to collect the fast charge-exchange (CX) deuterium neutrals emitted within the recycled cold neutral layer (CNL) which serves as a CX target for the incident ions. A theoretical interpretation of the experiment reveals a strong forward pitch-angle dependence in the approaching ion distribution function. The depth distribution of the trapped D in the Si sample was measured using low-energy direct recoil spectroscopy. Comparison with the TRIM code using monoenergetic ions indicated that the best fit to the data was obtained for an ion energy of 100 eV. An estimate of the CNL thickness {integral}nd{ell} indicates that during disruptions the CNL cushion is thick enough to reduce the local ion heat load by {approximately}30% due to CX refluxing.

  15. Northwest Power and Conservation Council Striking a Balance Between Energy and the Environment in the Columbia River Basin

    E-Print Network [OSTI]

    the Bonneville Power Administration acquired a conservation easement as partial mitigation for the impacts Power Administration have signed an agreement that will direct about $160 million over the next 15 years hydropower turbines. Bonneville transmits and markets the power generated from eight of the dams

  16. Structure of the eastern Red Rocks and Wind Ridge thrust faults, Wyoming: how a thrust fault gains displacement along strike 

    E-Print Network [OSTI]

    Huntsman, Brent Stanley

    1983-01-01

    OF FIELD MAPPING Methods . Thrust Faults . The Wind Ridge Thrust Fault System The Red Rocks Thrust Fault System CLAY MODEL STUDIES Purpose and Description Model Results DISCUSSION OF RESULTS Kinematics of the Red Rocks Thrust Fault Termination... . Kinematics of the Southern Wind Ridge Thrust Fault . . . A Conceptual Model of the Red Rocks Thrust Fault Termination Implications of the Red Rocks Fault Termination . . . . . . Page V1 V11 1X X1 X11 7 9 17 18 18 21 24 27 35 35 38 49 49...

  17. Supergravity gauge theories strike back: There is no crisis for SUSY but a new collider may be required for discovery

    E-Print Network [OSTI]

    Howard Baer; Vernon Barger; Michael Savoy

    2015-03-22

    More than 30 years ago, Arnowitt-Chamseddine-Nath (ACN) and others established the compelling framework of supergravity gauge theories (SUGRA) as a picture for the next step in beyond the Standard Model physics. We review the current SUGRA scenario in light of recent data from LHC8 collider searches and the Higgs boson discovery. While many SUSY and non-SUSY scenarios are highly disfavored or even excluded by LHC, the essential SUGRA scenario remains intact and as compelling as ever. For naturalness, some non-universality between matter and Higgs sector soft terms is required along with substantial trilinear soft terms. SUSY models with radiatively-driven naturalness (RNS) are found with high scale fine-tuning at a modest ~10%. In this case, natural SUSY might be discovered at LHC13 but could also easily elude sparticle search endeavors. A linear e^+e^- collider with \\sqrt{s}>2m(higgsino) is needed to provide the definitive search for the required light higgsino states which are the hallmark of natural SUSY. In the most conservative scenario, we advocate inclusion of a Peccei-Quinn sector so that dark matter is composed of a WIMP/axion admixture i.e. two dark matter particles.

  18. Supergravity gauge theories strike back: There is no crisis for SUSY but a new collider may be required for discovery

    E-Print Network [OSTI]

    Baer, Howard; Savoy, Michael

    2015-01-01

    More than 30 years ago, Arnowitt-Chamseddine-Nath (ACN) and others established the compelling framework of supergravity gauge theories (SUGRA) as a picture for the next step in beyond the Standard Model physics. We review the current SUGRA scenario in light of recent data from LHC8 collider searches and the Higgs boson discovery. While many SUSY and non-SUSY scenarios are highly disfavored or even excluded by LHC, the essential SUGRA scenario remains intact and as compelling as ever. For naturalness, some non-universality between matter and Higgs sector soft terms is required along with substantial trilinear soft terms. SUSY models with radiatively-driven naturalness (RNS) are found with high scale fine-tuning at a modest ~10%. In this case, natural SUSY might be discovered at LHC13 but could also easily elude sparticle search endeavors. A linear e^+e^- collider with \\sqrt{s}>2m(higgsino) is needed to provide the definitive search for the required light higgsino states which are the hallmark of natural SUSY. ...

  19. Developing and managing organizational capabilities to meet emerging customer needs : insights from the Joint Strike Fighter program

    E-Print Network [OSTI]

    Moon, Hee Sung

    2006-01-01

    This research examines the development and management of dynamic organizational capabilities. These capabilities include, among other things, how enterprises generate and integrate knowledge, understand and respond to ...

  20. Enterprise integration strategies across virtual extended enterprise networks : a case study of the F-35 Joint Strike Fighter Program enterprise

    E-Print Network [OSTI]

    Glazner, Christopher G

    2006-01-01

    Over the last decade, many companies in industries that produce complex and technologically-advanced products have begun to integrate their operations along the value chains of the primary products they design, produce or ...

  1. Genomic and physiological responses to strong selective pressure during late organogenesis: few gene expression changes found despite striking morphological differences

    E-Print Network [OSTI]

    Bozinovic, Goran; Sit, Tim L; Di Giulio, Richard; Wills, Lauren F; Oleksiak, Marjorie F

    2013-01-01

    2,3,7,8-tetrachlorodibenzo- p-dioxin on chemically impactedstructure and tolerance to dioxin-like compounds of a2,3,7,8-tetrachlorodibenzo-p-dioxin exposure. Toxicol Sci

  2. Progressive strain localization in a major strike-slip fault exhumed from midseismogenic depths: Structural observations from the

    E-Print Network [OSTI]

    Hacker, Bradley R.

    Dolan,1 Charles Sammis,1 Brad Hacker,2 Joshua Cole,2 and Lothar Ratschbacher3 Received 23 April 2008: Frost, E., J. Dolan, C. Sammis, B. Hacker, J. Cole, and L. Ratschbacher (2009), Progressive strain

  3. Localized ductile shear below the seismogenic zone: Structural analysis of an exhumed strike-slip fault, Austrian Alps

    E-Print Network [OSTI]

    Hacker, Bradley R.

    -slip fault, Austrian Alps Joshua Cole,1 Bradley Hacker,1 Lothar Ratschbacher,2 James Dolan,3 Gareth Seward,1-rich grain boundary shear zones that linked to form throughgoing shear zones. Citation: Cole, J., B. Hacker and Evans, 1988; Scholz, 1988; Shimamoto, 1989; Hacker and Christie, 1990; Tullis and Yund, 1992; Chester

  4. Striking a Balance Between Energy and the Environment in the Columbia River Basin Regional Power Plan Touts Efficiency to Meet

    E-Print Network [OSTI]

    and utilities need new generation in addition to renewable power and efficiency improvements. Natural gas Plan Touts Efficiency to Meet Demand and Create Jobs (Continued on page 2) Northwest Power its regional power plan at its February meet- ing, calling for efficiency, as much as 85 percent

  5. 1 AUGUST 2014 VOL 345 ISSUE 6196 517SCIENCE sciencemag.org supported the striking similarities of the

    E-Print Network [OSTI]

    .A.Newman,H.L.Frisch,Science205,662(1979). 7. R.Shethetal.,Science338,1476(2012). 8. R.D.Dahn,J.F.Fallon,Science289,438(2000). 9

  6. A First Record of a Strike-slip Basin in Western Anatolia and Its Tectonic Implication: The Cumaovasi Basin

    E-Print Network [OSTI]

    Utrecht, Universiteit

    of Cumaovasi basin and kinematic analysis on the striated fault planes support two senses of movements, each having opposite kinematic indicators. Quantitative indications are presented for the polyphase evolution, as indicated by active fault planes and focal mechanisms of shallow earthquakes. The transition from

  7. Striking a Balance Between Energy and the Environment in the Columbia River Basin California's Renewable Energy Policies and

    E-Print Network [OSTI]

    's Renewable Energy Policies and Their Impact on the Northwest (Continued on page 2) Northwest Power. California's renewable energy policies are some of the most aggressive in the nation, and the state has utilities have to look outside the state to satisfy their renewable portfolio goals. Renewable energy

  8. Protrusion of forearc mantle serpentinites along major strike-slip faults in an oceanic subduction complex in Dominican Republic

    E-Print Network [OSTI]

    , Le Fonds Quebécois de la Recherche sur la Nature et les Technologies, the University of Ottawa-type peridotites and spatially associated lavas, Contrib. Min. Pet. 86(1984) 54-76. [9] W.F. McDonough, S.S. Sun, melt extraction and post-melting processes beneath mid-ocean ridges, Journal of Petrology 45(2004) 2423

  9. Black Gold & Fool’s Gold: Speculation in the Oil Futures Market

    E-Print Network [OSTI]

    Parsons, John E.

    This paper addresses the question of whether the oil price spike of 2003-2008 was a bubble. We document and discuss what is known about the level of speculation in the paper oil market. We then analyze the dynamics of the ...

  10. Quantitative interpretation of the transition voltages in gold-poly(phenylene) thiol-gold molecular junctions

    SciTech Connect (OSTI)

    Wu, Kunlin; Bai, Meilin; Hou, Shimin; Sanvito, Stefano

    2013-11-21

    The transition voltage of three different asymmetric Au/poly(phenylene) thiol/Au molecular junctions in which the central molecule is either benzene thiol, biphenyl thiol, or terphenyl thiol is investigated by first-principles quantum transport simulations. For all the junctions, the calculated transition voltage at positive polarity is in quantitative agreement with the experimental values and shows weak dependence on alterations of the Au-phenyl contact. When compared to the strong coupling at the Au-S contact, which dominates the alignment of various molecular orbitals with respect to the electrode Fermi level, the coupling at the Au-phenyl contact produces only a weak perturbation. Therefore, variations of the Au-phenyl contact can only have a minor influence on the transition voltage. These findings not only provide an explanation to the uniformity in the transition voltages found for ?-conjugated molecules measured with different experimental methods, but also demonstrate the advantage of transition voltage spectroscopy as a tool for determining the positions of molecular levels in molecular devices.

  11. Experience with low-energy gold-gold operations in RHIC during FY 2010

    SciTech Connect (OSTI)

    Montag, C.; Satogata, T.; Ahrens, L.A.; Bai, M.; Beebe-Wang, J.; Blacker, I.; et al

    2011-10-07

    During Run-10, RHIC operated at several different Au-Au collision energies, as requested mainly by the STAR collaboration in a quest to search for the critical point in the QGP phase diagram. The center-of-mass energies {radical}s{sub NN} are listed in Table 1, together with the respective start and end dates and the duration of the respective run at each energy. While STAR defines 'low energy' as anything below {radical}s{sub NN} = 39 GeV, we focus in the scope of this paper on energies below the regular RHIC injection energy of {radical}s{sub NN} {approx} 20 GeV, since this energy regime is particularly challenging for stable RHIC operations. Figures 1 and 2 show the evolution of beam intensity and luminosity during the course of the {radical}s{sub NN} = 7.7 GeV and 11.5 GeV run. In the following sections we will recapitulate the modifications during the run that led to significant performance improvements, and summarize what was learned at the various energies for possible application in future runs.

  12. Template Fabrication of Protein-Functionalized Gold-Polypyrrole-Gold Segmented Nanowires

    E-Print Network [OSTI]

    Nanoparticles such as nanowires, nanotubes, and nanocrystals have been established as smart building blocks. Nanowires and nanotubes modified with biological molecules are also interesting building blocks for self

  13. Another Gold for PPPL: Laboratory Wins 2nd Gold GreenBuy Award | Princeton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TAPropaneandAn319 125Annualregulatoryimpurity

  14. Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford...

  15. Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    contaminated Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility Hanford LEED Gold Facility...

  16. Cultural Geography of Early Chinese Americans in Idaho and Montana, 1865-1900

    E-Print Network [OSTI]

    Chang, Woojin

    2010-04-26

    63 Bibliography 65 vi LIST OF MAPS 1. Territorial Establishment in the Northern Rocky Mountain Region. 2 2. Physical Features of Idaho and Montana. 3 3. Early Gold Strikes in Idaho... 48 Methodist Episcopal Church in 1904. 15. Chinese Placer Miners in Rocky Bar, Elmore County, circa 1900. 53 16. Zee Tai Chung Co., a Chinese Dry Goods Store on Idaho Street, Boise, in 59 1900. 1 Chapter 1...

  17. Charge exchange in CO-oxidation with supported gold clusters

    E-Print Network [OSTI]

    Berry, R. Stephen

    & Optical Physics ·Bose­Einstein Condensates & Ultracold Gases ·Metamaterials, Nanostructures & Magnetic

  18. Template-Assisted Formation of Gradient Concentric Gold Rings

    E-Print Network [OSTI]

    Lin, Zhiqun

    , and filtered ethanol and then blow-dried with N2. A sphere-on-flat geometry inside a chamber was constructed of sample holders in the chamber, respectively. An inchworm motor was used to bring the upper sphere

  19. Newest Los Alamos facility receives LEED® Gold certification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the U.S. Green Building Council (USGBC). From its robust design to its advanced scientific equipment, RLUOB is essential to the Laboratory's national security...

  20. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    new field of plasmonics. Nanoparticles on the Mesoscale The collective properties of 3D nanoparticle assemblies have not been widely explored. For the past decade, Xu et al. have...

  1. Tethered Lipid Bilayers on Electrolessly Deposited Gold for Bioelectronic Applications

    E-Print Network [OSTI]

    Lee, Ilsoon

    of Public Health, The University of Michigan, Ann Arbor, Michigan 48109-2029 Received April 24, 2006 electron microscopy, energy dispersive spectroscopy, and atomic force microscopy. Bilayer lipid membranes) there is no cushion between the surface and the sBLM to provide space for extramembrane moieties of membrane proteins

  2. Fabrication and characterization of wafer-level gold thermocompression bonding

    E-Print Network [OSTI]

    Tsau, Christine H. (Christine Hsin-Hwa), 1976-

    2003-01-01

    Packaging is an important aspect of microelectromechanical systems (MEMS) design. As MEMS devices traverse multiple energy domains, sometimes operating in hostile conditions, the need to maintain reliability and functionality ...

  3. Liquid Gold: Breast Milk Banking in the United States

    E-Print Network [OSTI]

    Pineau, Marisa

    2012-01-01

    for Talbot and other Directory employees to monitor the wetemployees. In addition to being formally associated with the Massachusetts Babies Hospital, the Directory

  4. Table of Contents Extension Calendar Wins Gold 1

    E-Print Network [OSTI]

    Hill, Jeffrey E.

    ,000. Much of the data showed that early spraying, before OR inoculum built up, was effective in reducing their soil, this will decrease the amount of pesticide and fertilizer being wasted in the landscape. The rain

  5. Strong Cubic Optical Nonlinearity of Gold Nanoparticles Suspension in Nematic

    E-Print Network [OSTI]

    Reznikov, Yuri

    of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine 2 Department of Chemistry, University of Hull, United Kingdom 3 National Taras Shevchenko University of Kyiv, Kyiv, Ukraine We report correspondence to E. Ouskova, Institute of Physics, National Academy of Sciences of Ukraine, Pr. Nauki 46, Kiev

  6. Microsoft PowerPoint - Marion Gold.Providence.Infrastructure...

    Broader source: Energy.gov (indexed) [DOE]

    panel approves 12.1 percent rate hike for electricity" -G. Wayne Miller, Providence Journal December 20, 2013 http:www.providencejournal.combreaking-newscontent...

  7. Carbon currencies: A new gold standard for sustainable

    E-Print Network [OSTI]

    Bateman, Ian J.

    Change Bill commits the government to achieving 80% cuts in carbon dioxide emissions by 2050, compared to all UK citizens, with the aim of limiting and reducing carbon emissions. However, the lack endeavour, as `ecological citizenship' rather than `ecological modernisation' Keywords carbon emissions

  8. Copyright 2009 IBM Global Business Services Turning Green into Gold

    E-Print Network [OSTI]

    Containment and Carbon Footprint Reduction Mutually Incompatible? By Keith Burgess and Simon Glass In a recent organizations to act now to reduce their carbon footprint. But at what cost? This article looks at how cost containment and carbon footprint reduction are not always incompatible. It looks at how leading organisations

  9. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    arrays of nanoparticles will enable not only a better understanding of this new family of materials, but also the fabrication of a wide range of next-generation nanodevices...

  10. World's largest single crystal of gold verified by Los Alamos...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 2015 Los Alamos develops new technique for growing high-efficiency perovskite solar cells Researchers reveal a new solution-based hot-casting technique that...

  11. Implantation and Growth of Dendritic Gold Nanostructures on Graphene

    E-Print Network [OSTI]

    Berry, Vikas

    July 15, 2009. 10.1021/nn900504v CCC: $40.75 © 2009 American Chemical Society ABSTRACT Interfacing Property Tailoring and Raman Enhancement Kabeer Jasuja and Vikas Berry* Department of Chemical Engineering transport in truly two-dimensional space,6 (d) adjustable surface chemistry via chemical7 9 or plasma10

  12. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    smaller than today's microtechnologies. Berkeley Lab and UC Berkeley scientists have made progress toward this goal, successfully directing the self--assembly of nanoparticles into...

  13. MELTING, FREEZING, DIFFUSION, AND COALESCENCE OF GOLD NANOCLUSTERS

    E-Print Network [OSTI]

    Lewis, Laurent J.

    'epartement de physique et GCM, Universit'e de Montr'eal, C.P. 6128, Succursale Centre­ Ville, Montr'eal, Qu. These materials can be grown by the low­energy deposition of preformed clusters containing hundreds or thousands

  14. Going for Gold The Tercero Housing II project

    E-Print Network [OSTI]

    Ullrich, Paul

    . The Leadership in Energy and Environmental Design (LEED) green building certification system provides a benchmark in six areas: - Sustainable Sites - Water Savings - Energy Efficiency - Materials Selection - Indoor Environmental Quality - Innovation in Design #12;Sustainable Sites The first of the six categories focuses

  15. CCP Composites Achieves Superior Energy Performance Gold Certification

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ISO 50001. INDUSTRIAL TECHNOLOGIES PROGRAM C L E A N C I T I E S more than 100% in annual energy costs. In 2008, energy was the second largest cost for the plant, accounting for...

  16. The Suspension of the Gold Standard as Sustainable Monetary Policy

    E-Print Network [OSTI]

    Newby, E

    +i = 1; !t+i = pt+i; Lt+i = 1; Ct+i = Yt+i #0; Gt+i = 1 #0; Gt+i and At+i+1 = #14;iA0 + Pi t #14; i#0;1 #2;As #0; q#0;1 #0; xgt+i #0; 1 #1; #17; #3; for all i = 0; 1; 2; :::. Proof: In equilibrium !t+i = pt+i and by substituting it and (19) into (13) we... -order-condition formt+i+1 is xt+i#21;t+i = #12; #0; #21;t+i+1 + #22;t+i+1 #1; ; where #21; and #22; are the Lagrangian multipliers of the household?s bud- get and cash-in-advance constraints (see Appendix A). Let us now assume that xt+i is bound below by #12; for all i...

  17. Supporting information for: Asymmetric catalysis at the mesoscale: Gold nanoclusters

    E-Print Network [OSTI]

    . Immobilization of quinine 3 on MCF-17: 1. Propargylation of quinine: 250 mg of quinine were dissolved in 2.5 m

  18. World's largest single crystal of gold verified at Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of authenticity, and indeed, the Los Alamos instruments confirmed that it was not a world-record trapezohedral crystal. Further interpretation of the results will also provide...

  19. Secondary ion emission from single massive gold cluster impacts 

    E-Print Network [OSTI]

    Hager, George Joseph

    2007-09-17

    Secondary ion mass spectrometry, SIMS, is one of the most versatile surface analytical techniques. The significant parameter determining the performance of SIMS is the secondary ion yield. Atomic projectiles, traditionally used in SIMS...

  20. Directed assembly of discrete gold nanoparticle groupings usingbranched DNA scaffolds

    SciTech Connect (OSTI)

    Claridge, Shelley A.; Goh, Sarah L.; Frechet, Jean M.J.; Williams, Shara C.; Micheel, Christine M.; Alivisatos, A. Paul

    2004-09-14

    The concept of self-assembled dendrimers is explored for the creation of discrete nanoparticle assemblies. Hybridization of branched DNA trimers and nanoparticle-DNA conjugates results in the synthesis of nanoparticle trimer and tetramer complexes. Multiple tetramer architectures are investigated, utilizing Au-DNA conjugates with varying secondary structural motifs. Hybridization products are analyzed by gel electrophoresis, and discrete bands are observed corresponding to structures with increasing numbers of hybridization events. Samples extracted from each band are analyzed by transmission electron microscopy, and statistics compiled from micrographs are used to compare assembly characteristics for each architecture. Asymmetric structures are also produced in which both 5 and 10 nm Au particles are assembled on branched scaffolds.

  1. 1. Lithographically Patterned Gold/Manganese Dioxide Core/Shell...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF MICROSTRUCTURAL AND MECHANICAL PROPERTY CHANGES IN A V2O5 BATTERY ELECTRODE USING A MEMS OPTICAL SENSOR Hyun Jung 1 , Konstantinos Gerasopoulos 1 , Markus Gnerlich 1 , Alec...

  2. NNSA National Security Campus Receives LEED® Gold Certification...

    National Nuclear Security Administration (NNSA)

    NSC earned 41 out of 51 possible points for this certification." LEED, or Leadership in Energy & Environmental Design, is the recognized standard for measuring building...

  3. Visualizing the Optical Interaction Tensor of a Gold Nanoparticle Pair

    E-Print Network [OSTI]

    Novotny, Lukas

    that the recorded images correspond to maps of the local Green's function tensor elements that couple the probe-molecule experiments the local electric field E is projected on the dipole axis p of the molecule and the fluorescence along the tip axis, interpretation of images is straightforward, but directional information about

  4. Synthesis and Optical Properties of "Branched" Gold Nanocrystals

    E-Print Network [OSTI]

    desirable for emerging applications including biolabels, photovoltaic behavior,16 chemical sensing, and surface enhanced Raman scattering, among others. Third, some of these structures enable elucidation for the further generation of different structures.18,19 Although extensive studies, thousands of papers, have

  5. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of this new family of materials, but also the fabrication of a wide range of next-generation nanodevices including optical lenses and polarizers, memory storage,...

  6. NNMCAB Committee Minutes: September 2013 Cities of Gold

    Broader source: Energy.gov [DOE]

    Minutes of the September 10, 2013 Combined Committee meeting: Presentation NMED, NMED's Perspective Regarding the 2005 Consent Order, Secretary Ryan Flynn Presentation DOE HQ, Department of Energy's Environmental Management Site Specific Advisory Board Member Appointment Process, Cate Alexander

  7. NNMCAB Committee Minutes: April 2014 Cities of Gold

    Broader source: Energy.gov [DOE]

    Minutes of the April 9, 2014 Combined Committee meeting: Presentation DOE/LANL, Proposed Process: NNMCAB Input on Campaigns, Pete Maggiore, Jeff Mousseau

  8. NNMCAB Committee Minutes: February 2012 Cities of Gold

    Broader source: Energy.gov [DOE]

    Minutes of the February 12, 2014 Combined Committee meeting: Presentation Nuke Watch New Mexico, Perspective on MDA G Cap and Cover Plan, Scott Kovac

  9. A Heart of Gold? Try Platinum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    collaboration with researchers at Boston Scientific Corporation. The alloy is the first stainless steel formulation for stents with a significant concentration of platinum,...

  10. Process 1.3 Blue & Gold Show Wafers

    E-Print Network [OSTI]

    Healy, Kevin Edward

    of 45 degrees 8.1.6.7 Choose shape of Round 8.1.7 Note inverted mask should look like photonegative transparency, rough side facing the ink. Do not use laser printer transparencies. 8.1.9.1 Note: check printer

  11. Abrikosov receives Ukrainian Gold Medal | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  12. DOE - Office of Legacy Management -- Humphreys Gold Co - FL 08

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth Dakota Edgemont, SouthLaboratoryDivHarshaw ChemicalHookerHumphreys

  13. Gold Camp, Arizona: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County, Georgia: Energy Resources Jump to:GodfreyCamp, Arizona:

  14. Gold Hill, Oregon: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County, Georgia: Energy Resources Jump to:GodfreyCamp,

  15. Gold River, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County, Georgia: Energy Resources Jump to:GodfreyCamp,(Redirected

  16. Water and Gold: A Promising Mix for Future Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout /Two0Photos and Videos/01/2012 Page 1Water

  17. World's largest single crystal of gold verified at Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  18. Transparent Gold as a Platform for Adsorbed Protein

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout / Transforming Y-12Capacity-Forum Sign In About

  19. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStress Molecular Mimicry of SUMO by Rad60

  20. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStress Molecular Mimicry of SUMO by

  1. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStress Molecular Mimicry of SUMO byMolecular

  2. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStress Molecular Mimicry of SUMO

  3. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStress Molecular Mimicry of SUMOMolecular

  4. Argonne Energy Sciences Building achieves LEED Gold | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  5. Earned Value Management System Gold Card | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPL EnergyPlus,Department of EnergySessionEnergy OHAissuedII) -

  6. Federal Electronics Challenge Gold Award | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLforLDRD Report to Congress MoreHyd rogEnergy AdvisoryFEMPTheLeft to

  7. Encapsulation of Gold Nanoparticles in a DNA Origami Cage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES ScienceInformation CompanyEmployeeJonHere »ArgonneEnabling

  8. Prediction of the thermodynamic properties of gold, arsenic, and

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLEDSpeeding accessSpeedingPATENTS- 05The Hydrothermal

  9. Waltzer Receives NNSA Gold Medal Award | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4)9 Federal RegisterStorm1 3 6370-Rev. 4 ATTACHMENT

  10. Abraham Presents Secretary's Gold Award to Edward Teller

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministrationTechnicalTechnicalScience.govWSRC-MS-g8-00318ANUDlSiTM-4026, 2002

  11. Going for the Gold (Computer), Again | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

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  12. Charles E. Messick receives the Administrator's Gold Award | National

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReporteeo | National NuclearaCSGF Magazine

  13. Scott Samuelson receives NNSA's Gold Medal of Excellence | National Nuclear

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal ofNational Nuclear SecuritySecurityriver site | National

  14. Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain,

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdisto Electric Coop, IncsourceEnginuityBusinessEnviva Materials

  15. Gold Hill, Colorado: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages RecentPlantMagma Energy Group JumpEnergyWasteColorado:

  16. Gold River, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages RecentPlantMagma Energy Group JumpEnergyWasteColorado:Jump

  17. BioGold Fuels Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin: EnergyYorkColoradoBelcherCarbonAlgene

  18. Highly Ordered Tailored Three-Dimensional Hierarchical Porous Gold

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers (JournalArchitectures. (Journal Article) | SciTech Connect

  19. Ultra-stable Gold Nanocatalysts - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPPfinal design andBiofuels forUltra-DeepwaterEnergy Storage

  20. When Green Turns to Gold | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricNCubicthe FOIA? The FOIA, Title 5,What'sWhen Green