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Sample records for hoteliers strike gold

  1. Hoteliers Strike Gold with Geothermal Alaskan Resort | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hoteliers Strike Gold with Geothermal Alaskan Resort Hoteliers Strike Gold with Geothermal Alaskan Resort November 23, 2009 - 6:31pm Addthis Eric Barendsen Energy Technology Program Specialist, Office of Energy Efficiency and Renewable Energy What are the key facts? Bernie estimates he saves anywhere from $300,000 to $400,000 in electricity costs alone each year using geothermal power generators rather than diesel. Bernie Karl knows a gold mine when he sees one. In the 1970s, Bernie and his wife

  2. Turkmenistan test encouraging oil strike

    SciTech Connect (OSTI)

    Not Available

    1992-07-27

    This paper reports that another former Soviet central Asian republic has reported a highly encouraging oil strike that provides hope for halting or even reversing a long decline in its oil production. Turkmenistan reported it completed a well flowing more than 1,300 b/d in the central part of the Kara-Kum desert. Saparmurad Niyazov, the republic's president, recently predicted black gold will become one of our nation's main riches. The Turkmenistan discovery follows a huge oil strike in neighboring Uzbekistan's sector of the Fergana Valley. A blowout last march near the Uzbek town of Mingbulak reportedly flowed 62,000 b/d to as much as 146,000 b/d from about 17,000 ft with a pressure of 10,300 psi. Uzbekistan is counting on that discovery to improve its oil production prospects immensely.

  3. Radial arm strike rail

    DOE Patents [OSTI]

    McKeown, Mark H.; Beason, Steven C.

    1991-01-01

    The radial arm strike rail assembly is a system for measurement of bearings, directions, and stereophotography for geologic mapping, particularly where magnetic compasses are not appropriate. The radial arm, pivoting around a shaft axis, provides a reference direction determination for geologic mapping and bearing or direction determination. The centerable and levelable pedestal provide a base for the radial arm strike rail and the telescoping camera pedestal. The telescoping feature of the radial arm strike rail allows positioning the end of the rail for strike direction or bearing measurement with a goniometer.

  4. Lightning strike at Bryan, Ohio

    SciTech Connect (OSTI)

    Nichols, B. E.

    1980-02-01

    A week before the 29 August 1979 dedication of the photovoltaic power system at daytime AM radio station WBNO, in Bryan, Ohio, a lightning superbolt struck the FM radio tower, one of two towers at the station. Minor damage to the station and to components of the photovoltaic system, the latter designed by MIT Lincoln Laboratory under US Department of Energy sponsorship, is described. This rare strike suggested the need for increased protection and more voltage-transient suppressors were added to those already in place as a preventive measure in the event that such a phenomenon reoccurs.

  5. Gold Nanoparticles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kornberg Research Science Perspective Chemistry World 16 December 2007 Structure of a Coated Gold Nanoparticle summary written by Amber Dance, SLAC Communication Office A team of scientists, working in part at SSRL's crystallography beam lines and led by Stanford Professor Roger Kornberg, has determined for the first time the atomic structure (at 1.1 Å resolution) of a thiol-covered gold nanoparticle, a discovery with potential for a range of applications from biosensors to nanotransistors. The

  6. Gold Nanoantennas

    SciTech Connect (OSTI)

    2012-01-01

    An array of gold nanoantennas laced into an artificial membrane enhances the fluorescence intensity of three different molecules when they pass through plasmonic hot spots in the array. Watch for the blue, green and red flashes. The photobleaching at the end of each fluorescence event (white flashes) is indicative of single molecule observations.

  7. Costs of strikes between vulnerable missile forces

    SciTech Connect (OSTI)

    Canavan, G.H.

    1997-02-01

    This note derives the first and second strike magnitudes and costs for strikes between vulnerable missile forces with multiple warheads. The extension to mixes with invulnerable missiles is performed in a companion note. Stability increases as the number of weapons per missile is reduced. The optimal allocation of weapons between missiles and value is significant in predicting the stability impact of the reduction of the number of weapons per missile at large numbers of missiles, less significant in reducing the number of missiles for fixed weapons per missile. At low numbers of missiles, the stability indices for singlet and triplet configurations are comparable, as are the number of weapons each would deliver on value targets.

  8. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO conversion into carbon-neutral fuels and chemicals November ...

  9. GOLD PLATING PROCESS

    DOE Patents [OSTI]

    Seegmiller, R.

    1957-08-01

    An improved bath is reported for plating gold on other metals. The composition of the plating bath is as follows: Gold cyanide from about 15 to about 50 grams, potassium cyanide from about 70 to about 125 grams, and sulfonated castor oil from about 0.1 to about 10 cc. The gold plate produced from this bath is smooth, semi-hard, and nonporous.

  10. Gold Awards - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanford Site Wide Programs DOE Human Resources Management Recognition and Awards Program Gold Awards About Us DOE Human Resources Management Division DOE Employment Recognition and Awards Program Gold Awards Silver Award Federal Employees Union (AFGE Local 788) Work Schedules / Pay and Leave Benefits and Services EEO & Diversity Gold Awards Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size Recognition is provided through monetary, non-monetary, and honorary

  11. Los Alamos technology strikes a chord with algal biofuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology strikes chord with algal biofuels Los Alamos technology strikes a chord with algal biofuels Sound-wave technology is helping Solix Biofuels, Inc. optimize production of algae-based fuel in a cost-effective, scalable, and environmentally benign fashion. September 2, 2009 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy

  12. Going green earns Laboratory gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Going green earns Laboratory gold Going green earns Laboratory gold The Laboratory's newest facility is its first to achieve both the Leadership in Energy and Environmental Design...

  13. Noah Golding | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Noah Golding About Us Noah Golding - Communications Specialist, Wind and Water Power Technologies Office Most Recent Winning with Wind: Electric Co-ops Providing Clean Energy to ...

  14. Going green earns Laboratory gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Going green earns Laboratory gold Going green earns Laboratory gold The Laboratory's newest facility is its first to achieve both the Leadership in Energy and Environmental Design ...

  15. Power-Amplified Predatory Strikes in Trap-Jaw Spiders

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power-Amplified Predatory Strikes in Trap-Jaw Spiders Power-Amplified Predatory Strikes in Trap-Jaw Spiders Print Friday, 10 June 2016 13:23 "Trap-jaw" spiders are tiny (about 2 mm), ground-dwelling spiders that rely on hunting rather than web-building to capture prey. Hannah Wood, curator of spiders at the Smithsonian's National Museum of Natural History, was curious as to why these spiders' carapaces (their front sections) seemed almost neck-like and their chelicerae (mandibles or

  16. Paducah Plant Begins Enrichment Operations after Five Parties Strike

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agreement | Department of Energy Plant Begins Enrichment Operations after Five Parties Strike Agreement Paducah Plant Begins Enrichment Operations after Five Parties Strike Agreement May 1, 2012 - 12:00pm Addthis This cylinder hauler at Paducah’s Babcock & Wilcox Conversion Services plant delivers the first of DOE’s 14-ton depleted uranium cylinders to USEC for re-enrichment as part of a five-party agreement that is extending enrichment operations at the 60-year-old plant for

  17. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO₂ conversion into carbon-neutral fuels and chemicals November 6, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Environmentalists have long lamented the destructive effects of greenhouse gases, with carbon dioxide (CO2) often accused of being the primary instigator of global climate change. As a result, numerous efforts are under way to find ways to prevent,

  18. Derivatized gold clusters and antibody-gold cluster conjugates

    DOE Patents [OSTI]

    Hainfeld, J.F.; Furuya, F.R.

    1994-11-01

    Antibody- or antibody fragment-gold cluster conjugates are shown wherein the conjugate size can be as small as 5.0 nm. Methods and reagents are disclosed in which antibodies, Fab' or F(ab')[sub 2] fragments are covalently bound to a stable cluster of gold atoms. The gold clusters may contain 6, 8, 9, 11, 13, 55 or 67 gold atoms in their inner core. The clusters may also contain radioactive gold. The antibody-cluster conjugates are useful in electron microscopy applications as well as in clinical applications that include imaging, diagnosis and therapy. 7 figs.

  19. Derivatized gold clusters and antibody-gold cluster conjugates

    DOE Patents [OSTI]

    Hainfeld, James F.; Furuya, Frederic R.

    1994-11-01

    Antibody- or antibody fragment-gold cluster conjugates are shown wherein the conjugate size can be as small as 5.0 nm. Methods and reagents are disclosed in which antibodies, Fab' or F(ab').sub.2 fragments thereof are covalently bound to a stable cluster of gold atoms. The gold clusters may contain 6, 8, 9, 11, 13, 55 or 67 gold atoms in their inner core. The clusters may also contain radioactive gold. The antibody-cluster conjugates are useful in electron microscopy applications as well as in clinical applications that include imaging, diagnosis and therapy.

  20. GOLD PRESSURE VESSEL SEAL

    DOE Patents [OSTI]

    Smith, A.E.

    1963-11-26

    An improved seal between the piston and die member of a piston-cylinder type pressure vessel is presented. A layer of gold, of sufficient thickness to provide an interference fit between the piston and die member, is plated on the contacting surface of at least one of the members. (AEC)

  1. Structures of 38-atom gold-platinum nanoalloy clusters

    SciTech Connect (OSTI)

    Ong, Yee Pin; Yoon, Tiem Leong; Lim, Thong Leng

    2015-04-24

    Bimetallic nanoclusters, such as gold-platinum nanoclusters, are nanomaterials promising wide range of applications. We perform a numerical study of 38-atom gold-platinum nanoalloy clusters, Au{sub n}Pt{sub 38−n} (0 ≤ n ≤ 38), to elucidate the geometrical structures of these clusters. The lowest-energy structures of these bimetallic nanoclusters at the semi-empirical level are obtained via a global-minimum search algorithm known as parallel tempering multi-canonical basin hopping plus genetic algorithm (PTMBHGA), in which empirical Gupta many-body potential is used to describe the inter-atomic interactions among the constituent atoms. The structures of gold-platinum nanoalloy clusters are predicted to be core-shell segregated nanoclusters. Gold atoms are observed to preferentially occupy the surface of the clusters, while platinum atoms tend to occupy the core due to the slightly smaller atomic radius of platinum as compared to gold’s. The evolution of the geometrical structure of 38-atom Au-Pt clusters displays striking similarity with that of 38-atom Au-Cu nanoalloy clusters as reported in the literature.

  2. Gold deposits in the late Archaean Nzega-Igunga greenstone belt, central plateau of tanzania

    SciTech Connect (OSTI)

    Feiss, P.G.; Siyomana, S.

    1985-01-01

    2.2 m oz of gold have been produced, since 1935, from late Archaean (2480-2740 Ma) greenstone belts of the Central Plateau, Tanzania. North and east of Nzega (4/sup 0/12'S, 3/sup 0/11'E), 18% of the exposed basement, mainly Dodoman schists and granites, consists of metavolcanics and metasediments of the Nyanzian and Kavirondian Series. Four styles of mineralization are observed. 1. Stratabound quartz-gold veins with minor sulfides. Host rocks are quartz porphyry, banded iron formation (BIF), magnetite quartzite, and dense, cherty jasperite at the Sekenke and Canuck mines. The Canuck veins are on strike from BIF's in quartz-eye porphyry of the Igusule Hills. 2. Stratabound, disseminated gold in coarse-grained, crowded feldspar porphyry with lithic fragments and minor pyrite. At Bulangamilwa, the porphyry is conformable with Nyanzian-aged submarine (.) greenstone, volcanic sediment, felsic volcanics, and sericite phyllite. The deposits are on strike with BIF of the Wella Hills, which contains massive sulfide with up to 15% Pb+Zn. 3. Disseminated gold in quartz-albite metasomes in Nyanzian greenstones. At Kirondatal, alteration is associated with alaskites and feldspar porphyry dikes traceable several hundred meters into post-Dodoman diorite porphyry. Gold is with pyrite, arsenopyrite, pyrrhotite, minor chalcopyrite, and sphalerite as well as tourmalinite and silica-cemented breccias. 4. Basal Kavirondian placers in metaconglomerates containing cobbles and boulders of Dodoman and Nyanzian rocks several hundred meters up-section from the stratabound, disseminated mineralization at Bulangamilwa.

  3. The New Gold Standard: Environmental Management Introduces the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The New Gold Standard: Environmental Management Introduces the First LEED Gold Industrial Facility The New Gold Standard: Environmental Management Introduces the First LEED Gold ...

  4. Surface-stabilized gold nanocatalysts

    DOE Patents [OSTI]

    Dai, Sheng [Knoxville, TN; Yan, Wenfu [Oak Ridge, TN

    2009-12-08

    A surface-stabilized gold nanocatalyst includes a solid support having stabilizing surfaces for supporting gold nanoparticles, and a plurality of gold nanoparticles having an average particle size of less than 8 nm disposed on the stabilizing surfaces. The surface-stabilized gold nanocatalyst provides enhanced stability, such as at high temperature under oxygen containing environments. In one embodiment, the solid support is a multi-layer support comprising at least a first layer having a second layer providing the stabilizing surfaces disposed thereon, the first and second layer being chemically distinct.

  5. Gold Nanoparticles by Alfalfa Plants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jorge Gardea-Torresdey, University of Texas at El Paso In the well-known Greek legend the touch of King Midas would convert anything to metallic gold. Recently, a team working at SSRL lead by Professor Jorge Gardea-Torresdey from the University of Texas at El Paso have shown that ordinary alfalfa plants can accumulate very small particles (nanoparticles) of metallic gold (1). The best-known materials that contain nanoparticles of metallic gold are gold colloids. These lack the familiar metallic

  6. BlackGold Biofuels | Open Energy Information

    Open Energy Info (EERE)

    BlackGold Biofuels Jump to: navigation, search Name: BlackGold Biofuels Place: Philadelphia, Pennsylvania Zip: 19107 Product: Philadelphia-based developer of a waste...

  7. Tracking Individual Gold Nanoparticles | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tracking Individual Gold Nanoparticles Researchers have developed a new way to track gold nanorods as they move around and re-orient themselves on metal surfaces, with ...

  8. Gold Standard Program Model | Open Energy Information

    Open Energy Info (EERE)

    Standard Program Model Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Gold Standard Program Model AgencyCompany Organization: The Gold Standard Foundation Sector:...

  9. Antibody-gold cluster conjugates

    DOE Patents [OSTI]

    Hainfeld, J.F.

    1988-06-28

    Antibody- or antibody fragment-gold cluster conjugates are shown wherein the conjugate size can be about 5.0 nm. Methods and reagents are disclosed in which antibodies or Fab' fragments thereof are covalently bound to a stable cluster of gold atoms. 2 figs.

  10. Assessment of performing an MST strike in Tank 21H

    SciTech Connect (OSTI)

    Poirier, Michael R.

    2014-09-29

    Previous Savannah River National Laboratory (SRNL) tank mixing studies performed for the Small Column Ion Exchange (SCIX) project have shown that 3 Submersible Mixer Pumps (SMPs) installed in Tank 41 are sufficient to support actinide removal by MST sorption as well as subsequent resuspension and removal of settled solids. Savannah River Remediation (SRR) is pursuing MST addition into Tank 21 as part of the Large Tank Strike (LTS) project. The preliminary scope for LTS involves the use of three standard slurry pumps (installed in N, SE, and SW risers) in a Type IV tank. Due to the differences in tank size, internal interferences, and pump design, a separate mixing evaluation is required to determine if the proposed configuration will allow for MST suspension and strontium and actinide sorption. The author performed the analysis by reviewing drawings for Tank 21 [W231023] and determining the required cleaning radius or zone of influence for the pumps. This requirement was compared with previous pilot-scale MST suspension data collected for SCIX that determined the cleaning radius, or zone of influence, as a function of pump operating parameters. The author also reviewed a previous Tank 50 mixing analysis that examined the ability of standard slurry pumps to suspend sludge particles. Based on a review of the pilot-scale SCIX mixing tests and Tank 50 pump operating experience, three standard slurry pumps should be able to suspend sludge and MST to effectively sorb strontium and actinides onto the MST. Using the SCIX data requires an assumption about the impact of cooling coils on slurry pump mixing. The basis for this assumption is described in this report. Using the Tank 50 operating experience shows three standard slurry pumps should be able to suspend solids if the shear strength of the settled solids is less than 160 Pa. Because Tank 21 does not contain cooling coils, the shear strength could be larger.

  11. Pre/post-strike atmospheric assessment system (PAAS)

    SciTech Connect (OSTI)

    Peglow, S. G., LLNL; Molitoris, J. D., LLNL

    1997-02-03

    The Pre/Post-Strike Atmospheric Assessment System was proposed to show the importance of local meteorological conditions in the vicinity of a site suspected of storing or producing toxic agents and demonstrate a technology to measure these conditions, specifically wind fields. The ability to predict the collateral effects resulting from an attack on a facility containing hazardous materials is crucial to conducting effective military operations. Our study approach utilized a combination of field measurements with dispersion modeling to better understand which variables in terrain and weather were most important to collateral damage predictions. To develop the PAAS wind-sensing technology, we utilized a combination of emergent and available technology from micro-Doppler and highly coherent laser systems. The method used for wind sensing is to probe the atmosphere with a highly coherent laser beam. As the beam probes, light is back-scattered from particles entrained in the air to the lidar transceiver and detected by the instrument. Any motion of the aerosols with a component along the beam axis leads to a Doppler shift of the received light. Scanning in a conical fashion about the zenith results in a more accurate and two-dimensional measurement of the wind velocity. The major milestones in the benchtop system development were to verify the design by demonstrating the technique in the laboratory, then scale the design down to a size consistent with a demonstrator unit which could be built to take data in the field. The micro-Doppler heterodyne system we developed determines absolute motion by optically mixing a reference beam with the return signal and has shown motion sensitivity to better than 1 cm/s. This report describes the rationale, technical approach and laboratory testing undertaken to demonstrate the feasibility and utility of a system to provide local meteorological data and predict atmospheric particulate motion. The work described herein was funded by

  12. GOLD: The Genomes Online Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kyrpides, Nikos; Liolios, Dinos; Chen, Amy; Tavernarakis, Nektarios; Hugenholtz, Philip; Markowitz, Victor; Bernal, Alex

    Since its inception in 1997, GOLD has continuously monitored genome sequencing projects worldwide and has provided the community with a unique centralized resource that integrates diverse information related to Archaea, Bacteria, Eukaryotic and more recently Metagenomic sequencing projects. As of September 2007, GOLD recorded 639 completed genome projects. These projects have their complete sequence deposited into the public archival sequence databases such as GenBank EMBL,and DDBJ. From the total of 639 complete and published genome projects as of 9/2007, 527 were bacterial, 47 were archaeal and 65 were eukaryotic. In addition to the complete projects, there were 2158 ongoing sequencing projects. 1328 of those were bacterial, 59 archaeal and 771 eukaryotic projects. Two types of metadata are provided by GOLD: (i) project metadata and (ii) organism/environment metadata. GOLD CARD pages for every project are available from the link of every GOLD_STAMP ID. The information in every one of these pages is organized into three tables: (a) Organism information, (b) Genome project information and (c) External links. [The Genomes On Line Database (GOLD) in 2007: Status of genomic and metagenomic projects and their associated metadata, Konstantinos Liolios, Konstantinos Mavromatis, Nektarios Tavernarakis and Nikos C. Kyrpides, Nucleic Acids Research Advance Access published online on November 2, 2007, Nucleic Acids Research, doi:10.1093/nar/gkm884]

    The basic tables in the GOLD database that can be browsed or searched include the following information:

    • Gold Stamp ID
    • Organism name
    • Domain
    • Links to information sources
    • Size and link to a map, when available
    • Chromosome number, Plas number, and GC content
    • A link for downloading the actual genome data
    • Institution that did the sequencing
    • Funding source
    • Database where information resides
    • Publication status and information

    • Do warning displays predict striking behavior in a viperid snake, the cottonmouth (Agkistrodon piscivorus)?

      SciTech Connect (OSTI)

      Glaudas, X. and C.T. Winne

      2007-01-01

      Warning displays are defined as signals designed to intimidate predators or indicate a proclivity to fight. However, support for the idea that warning behaviors signal an intent to fight is largely based on anecdotes and isolated observations, and a complete understanding of antipredator behavior will only be achieved if specific hypotheses are experimentally tested. Herein, we tested in a North American viperid snake, the cottonmouth (Agkistrodon piscivorus), the hypothesis that warning displays serve as a reliable signal to potential predators that a snake will strike. The cottonmouth exhibits two stereotypical warning displays during predator confrontation, i.e., mouth gaping and tail vibrations, making it an ideal study organism to experimentally test the relationship between warning displays and defensive striking. To test this idea, we recorded the sequence of defensive behavior--gaping, tail vibrating, and striking--of cottonmouths towards a standardized predatory stimulus in the laboratory. As predicted, snakes that gaped during the trials were subsequently more likely to strike than snakes that did not. In contrast, striking behavior was independent of the occurrence of tail vibrations. Our results suggest that gaping behavior--but not tail-vibrating behavior--may provide an honest signal to would-be predators.

    • Probability, consequences, and mitigation for lightning strikes to Hanford site high-level waste tanks

      SciTech Connect (OSTI)

      Zach, J.J.

      1996-08-01

      The purpose of this report is to summarize selected lightning issues concerning the Hanford Waste Tanks. These issues include the probability of lightning discharge striking the area immediately adjacent to a tank including a riser, the consequences of significant energy deposition from a lightning strike in a tank, and mitigating actions that have been or are being taken. The major conclusion of this report is that the probability of a lightning strike depositing sufficient energy in a tank to cause an effect on employees or the public is unlikely;but there are insufficient, quantitative data on the tanks and waste to prove that. Protection, such as grounding of risers and air terminals on existing light poles, is recommended.

    • Probability, consequences, and mitigation for lightning strikes of Hanford high level waste tanks

      SciTech Connect (OSTI)

      Zach, J.J.

      1996-06-05

      The purpose of this report is to summarize selected lightning issues concerning the Hanford Waste Tanks. These issues include the probability of a lightning discharge striking the area immediately adjacent to a tank including a riser, the consequences of significant energy deposition from a lightning strike in a tank, and mitigating actions that have been or are being taken. The major conclusion of this report is that the probability of a lightning strike deposition sufficient energy in a tank to cause an effect on employees or the public is unlikely;but there are insufficient, quantitative data on the tanks and waste to prove that. Protection, such as grounding of risers and air terminals on existing light poles, is recommended.

    • Biomolecular Assembly of Gold Nanocrystals

      SciTech Connect (OSTI)

      Micheel, Christine Marya

      2005-05-20

      Over the past ten years, methods have been developed to construct discrete nanostructures using nanocrystals and biomolecules. While these frequently consist of gold nanocrystals and DNA, semiconductor nanocrystals as well as antibodies and enzymes have also been used. One example of discrete nanostructures is dimers of gold nanocrystals linked together with complementary DNA. This type of nanostructure is also known as a nanocrystal molecule. Discrete nanostructures of this kind have a number of potential applications, from highly parallel self-assembly of electronics components and rapid read-out of DNA computations to biological imaging and a variety of bioassays. My research focused in three main areas. The first area, the refinement of electrophoresis as a purification and characterization method, included application of agarose gel electrophoresis to the purification of discrete gold nanocrystal/DNA conjugates and nanocrystal molecules, as well as development of a more detailed understanding of the hydrodynamic behavior of these materials in gels. The second area, the development of methods for quantitative analysis of transmission electron microscope data, used computer programs written to find pair correlations as well as higher order correlations. With these programs, it is possible to reliably locate and measure nanocrystal molecules in TEM images. The final area of research explored the use of DNA ligase in the formation of nanocrystal molecules. Synthesis of dimers of gold particles linked with a single strand of DNA possible through the use of DNA ligase opens the possibility for amplification of nanostructures in a manner similar to polymerase chain reaction. These three areas are discussed in the context of the work in the Alivisatos group, as well as the field as a whole.

    • Gold ink coating of thermocouple sheaths

      DOE Patents [OSTI]

      Ruhl, H. Kenneth

      1992-01-01

      A method is provided for applying a gold ink coating to a thermocouple sheath which includes the steps of electropolishing and oxidizing the surface of the thermocouple sheath, then dipping the sheath into liquid gold ink, and finally heat curing the coating. The gold coating applied in this manner is highly reflective and does not degrade when used for an extended period of time in an environment having a temperature over 1000.degree. F. Depending on the application, a portion of the gold coating covering the tip of the thermocouple sheath is removed by abrasion.

    • Functionalized Gold Nanoparticles for Rapid, Ultra- sensitive...

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      The new ORNL method for surface enhanced Raman spectroscopy (SERS) involves synthesizing gold metal nanoparticles that are modified with specific amine groups. The method can be ...

    • Gold Country Energy | Open Energy Information

      Open Energy Info (EERE)

      Energy Jump to: navigation, search Name: Gold Country Energy Place: Alaska Phone Number: (907) 520-5681 Website: goldcountryenrgy.com Facebook: https:www.facebook.compages...

    • Water and Gold: A Promising Mix for Future Batteries

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Water and Gold: A Promising Mix for Future Batteries Water and Gold: A Promising Mix for Future Batteries Berkeley Lab Study Reveals Molecular Structure of Water at Gold Electrodes ...

  1. Ultra-stable Gold Nanocatalysts - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Ultra-stable Gold Nanocatalysts Oak Ridge National ... ORNL researchers successfully deposited and stabilized gold nanoparticles on surfaces of ...

  2. Abrikosov receives Ukrainian Gold Medal | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abrikosov receives Ukrainian Gold Medal By Lynn Tefft Hoff * July 28, 2015 Tweet ... Abrikosov has received the Gold Medal of Vernadsky of the National Academy of Sciences of ...

  3. Newest Los Alamos facility receives LEED® Gold certification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Newest facility receives LEED Gold certification Newest Los Alamos facility receives LEED Gold certification The Radiological Laboratory Utility Office Building is first to ...

  4. World's largest single crystal of gold verified by Los Alamos...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos verifies largest single gold crystal World's largest single crystal of gold verified by Los Alamos instruments Using Lujan Center's HIPPO instrument, researchers probed ...

  5. Waltzer Receives NNSA Gold Medal Award | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    Gold Medal Award June 26, 2014 AMARILLO, Texas--Karl Waltzer, Acting Deputy Manager of the National Nuclear Security Administration's Production Office, has received the NNSA Gold ...

  6. The Structure of Interfacial Water on Gold Electrodes Studied...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Structure of Interfacial Water on Gold Electrodes Studied by X-ray Absorption Spectroscopy Schematic representation of X-ray absorption measurements at the biased gold water ...

  7. Prediction of the thermodynamic properties of gold, arsenic,...

    Office of Scientific and Technical Information (OSTI)

    The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver Brad Bessinger ... The HKF equation of state parameters for gold, arsenic, antimony, mercury, and silver ...

  8. Structure of a Thiol Monolayer-Protected Gold Nanoparticle at...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thiol Monolayer-protected Gold Nanoparticle at 1.1 Resolution Nanometer-size metal ... Historically gold nanoparticles are the best studied, dating back to ancient Rome where ...

  9. For Spitzer building, green is gold | Princeton Plasma Physics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Spitzer building, green is gold By Patti Wieser May 26, 2011 Tweet Widget Google Plus ... Laboratory (PPPL), has been certified LEED gold, one of the highest environmental ...

  10. Abraham Presents Secretary's Gold Award to Edward Teller

    Office of Scientific and Technical Information (OSTI)

    November 26, 2002 Abraham Presents Secretary's Gold Award to Edward Teller LIVERMORE, ... National Laboratory, with the Secretary's Gold Award in recognition of his outstanding ...

  11. Reactivity of the Gold/Water Interface During Selective Oxidation...

    Office of Scientific and Technical Information (OSTI)

    the GoldWater Interface During Selective Oxidation Catalysis Citation Details In-Document Search Title: Reactivity of the GoldWater Interface During Selective Oxidation Catalysis ...

  12. Gold-nickel-titanium brazing alloy

    DOE Patents [OSTI]

    Mizuhara, Howard

    1990-07-03

    A brazing alloy in accordance with this invention has the following composition, by weight: 91 to 99% gold, 0.5 to 7% nickel; 0.10 to 2% titanium. Alternatively, with palladium present, the composition is as follows, by weight: 83 to 96% gold; 3 to 10% palladium; 0.5 to 5% nickel; 0.10 to 2% titanium.

  13. Gold-nickel-titanium brazing alloy

    DOE Patents [OSTI]

    Mizuhara, Howard

    1995-01-03

    A brazing alloy in accordance with this invention has the following composition, by weight: 91 to 99 gold, 0.5 to 7% nickel; 0.10 to 2% titanium. Alternatively, with palladium present, the composition is as follows, by weight: 83 to 96% gold; 3 to 10% palladium; 0.5 to 5% nickel; 0.10 to 2% titanium.

  14. gold medal | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    gold medal NNSA Administrator honors nonproliferation research leader Last week DOE Under Secretary for Nuclear Security and NNSA Administrator Lt. Gen. Frank G. Klotz (Ret.) presented the agency's Assistant Deputy Administrator for Nonproliferation Research and Development (R&D) Dr. Rhys Williams with the Distinguished Service Gold Medal Award at a

  15. Evaluation of Blade-Strike Models for Estimating the Biological Performance of Large Kaplan Hydro Turbines

    SciTech Connect (OSTI)

    Deng, Zhiqun; Carlson, Thomas J.; Ploskey, Gene R.; Richmond, Marshall C.

    2005-11-30

    BioIndex testing of hydro-turbines is sought as an analog to the hydraulic index testing conducted on hydro-turbines to optimize their power production efficiency. In BioIndex testing the goal is to identify those operations within the range identified by Index testing where the survival of fish passing through the turbine is maximized. BioIndex testing includes the immediate tailrace region as well as the turbine environment between a turbine's intake trashracks and the exit of its draft tube. The US Army Corps of Engineers and the Department of Energy have been evaluating a variety of means, such as numerical and physical turbine models, to investigate the quality of flow through a hydro-turbine and other aspects of the turbine environment that determine its safety for fish. The goal is to use these tools to develop hypotheses identifying turbine operations and predictions of their biological performance that can be tested at prototype scales. Acceptance of hypotheses would be the means for validation of new operating rules for the turbine tested that would be in place when fish were passing through the turbines. The overall goal of this project is to evaluate the performance of numerical blade strike models as a tool to aid development of testable hypotheses for bioIndexing. Evaluation of the performance of numerical blade strike models is accomplished by comparing predictions of fish mortality resulting from strike by turbine runner blades with observations made using live test fish at mainstem Columbia River Dams and with other predictions of blade strike made using observations of beads passing through a 1:25 scale physical turbine model.

  16. Coal-gold agglomeration: an alternative separation process in gold recovery

    SciTech Connect (OSTI)

    Akcil, A.; Wu, X.Q.; Aksay, E.K.

    2009-07-01

    Considering the increasing environmental concerns and the potential for small gold deposits to be exploited in the future, the uses of environmentally friendly processes are essential. Recent developments point to the potential for greatly increased plant performance through a separation process that combines the cyanide and flotation processes. In addition, this kind of alternative treatment processes to the traditional gold recovery processes may reduce the environmental risks of present small-scale gold mining. Gold recovery processes that applied to different types of gold bearing ore deposits show that the type of deposits plays an important role for the selection of mineral processing technologies in the production of gold and other precious metals. In the last 25 years, different alternative processes have been investigated on gold deposits located in areas where environmental issues are a great concern. In 1988, gold particles were first recovered by successful pilot trial of coal-gold agglomeration (CGA) process in Australia. The current paper reviews the importance of CGA in the production of gold ore and identifies areas for further development work.

  17. Gel Electrophoresis of Gold-DNA Nanoconjugates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pellegrino, T.; Sperling, R. A.; Alivisatos, A. P.; Parak, W. J.

    2007-01-01

    Gold-DNA conjugates were investigated in detail by a comprehensive gel electrophoresis study based on 1200 gels. A controlled number of single-stranded DNA of different length was attached specifically via thiol-Au bonds to phosphine-stabilized colloidal gold nanoparticles. Alternatively, the surface of the gold particles was saturated with single stranded DNA of different length either specifically via thiol-Au bonds or by nonspecific adsorption. From the experimentally determined electrophoretic mobilities, estimates for the effective diameters of the gold-DNA conjugates were derived by applying two different data treatment approaches. The first method is based on making a calibration curve for the relation between effectivemore » diameters and mobilities with gold nanoparticles of known diameter. The second method is based on Ferguson analysis which uses gold nanoparticles of known diameter as reference database. Our study shows that effective diameters derived from gel electrophoresis measurements are affected with a high error bar as the determined values strongly depend on the method of evaluation, though relative changes in size upon binding of molecules can be detected with high precision. Furthermore, in this study, the specific attachment of DNA via gold-thiol bonds to Au nanoparticles is compared to nonspecific adsorption of DNA. Also, the maximum number of DNA molecules that can be bound per particle was determined.« less

  18. Colloidal-gold electrosensor measuring device

    DOE Patents [OSTI]

    Wegner, Steven; Harpold, Michael A.; McCaffrey, Terence M.; Morris, Susan E.; Wojciechowski, Marek; Zhao, Junguo; Henkens, Robert W.; Naser, Najih; O'Daly, John P.

    1995-01-01

    The present invention provides a new device for use in measuring lead levels in biological and environmental samples. Using square wave coulometry and colloidal gold particles impregnated on carbon electrodes, the present invention provides a rapid, reliable, portable and inexpensive means of detecting low lead levels. The colloidal gold modified electrodes have microelectrode array characteristics and produce significantly higher stripping detection signals for lead than are produced at bulk gold electrode surfaces. The method is effective in determining levels of lead down to at least 5 .mu.g/dL in blood samples as small as 10 .mu.L.

  19. Colloidal-gold electrosensor measuring device

    DOE Patents [OSTI]

    Wegner, S.; Harpold, M.A.; McCaffrey, T.M.; Morris, S.E.; Wojciechowski, M.; Zhao, J.; Henkens, R.W.; Naser, N.; O`Daly, J.P.

    1995-11-21

    The present invention provides a new device for use in measuring lead levels in biological and environmental samples. Using square wave coulometry and colloidal gold particles impregnated on carbon electrodes, the present invention provides a rapid, reliable, portable and inexpensive means of detecting low lead levels. The colloidal gold modified electrodes have microelectrode array characteristics and produce significantly higher stripping detection signals for lead than are produced at bulk gold electrode surfaces. The method is effective in determining levels of lead down to at least 5 {micro}g/dL in blood samples as small as 10 {micro}L. 9 figs.

  20. Electrochemical control of creep in nanoporous gold

    SciTech Connect (OSTI)

    Ye, Xing-Long; Jin, Hai-Jun

    2013-11-11

    We have investigated the mechanical stability of nanoporous gold (npg) in an electrochemical environment, using in situ dilatometry and compression experiments. It is demonstrated that the gold nano-ligaments creep under the action of surface stress which leads to spontaneous volume contractions in macroscopic npg samples. The creep of npg, under or without external forces, can be controlled electrochemically. The creep rate increases with increasing potential in double-layer potential region, and deceases to almost zero when the gold surface is adsorbed with oxygen. Surprisingly, we also noticed a correlation between creep and surface diffusivity, which links the deformation of nanocrystals to mobility of surface atoms.

  1. The New Gold Standard: Environmental Management Introduces the First LEED

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gold Industrial Facility | Department of Energy The New Gold Standard: Environmental Management Introduces the First LEED Gold Industrial Facility The New Gold Standard: Environmental Management Introduces the First LEED Gold Industrial Facility September 13, 2012 - 1:02pm Addthis The 200 West Groundwater Treatment Facility is shown here after completion of construction this summer. | Photo courtesy of Zachary Carter with Mission Support Alliance (MSA) at Hanford. The 200 West Groundwater

  2. Gold nanorod melting | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gold nanorod melting Share Topic Programs Materials science Materials simulation & theory Nanoscience Surface & interface studies Mathematics, computing, & computer science Modeling, simulation, & visualization Supercomputing & high-performance computing

  3. Interconnecting gold islands with DNA origami

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interconnecting gold islands with DNA origami Authors: Ding, B., Wu, H., Xu, W., Zhao, Z., Liu, Y., Yu, H., and Yan, H. Title: Interconnecting gold islands with DNA origami Source: Nano Lett. Year: 2010 Volume: 10 Pages: 5065-5069 ABSTRACT: Scaffolded DNA origami has recently emerged as a versatile, programmable method to fold DNA into arbitrarily shaped nanostructures that are spatially addressable, with sub-10-nm resolution. Toward functional DNA nanotechnology, one of the key challenges is to

  4. Negative ion beam characterisation in BATMAN by mini-STRIKE: Improved design and new measurements

    SciTech Connect (OSTI)

    Serianni, G. Brombin, M.; Cervaro, V.; Chitarin, G.; Delogu, R.; Fasolo, D.; Fonnesu, N.; Franchin, L.; Ghiraldelli, R.; Molon, F.; Pasqualotto, R.; Tollin, M.; Veltri, P.; Bonomo, F.; Cristofaro, S.; De Muri, M.; Franzen, P.; Ruf, B.; Schiesko, L.; Muraro, A.

    2015-04-08

    The ITER project requires additional heating provided by two injectors of neutral beams resulting from the neutralisation of accelerated negative ions. To study and optimise negative ion production, the SPIDER test facility (particle energy 100keV; beam current 50A) is under construction in Padova, with the aim of testing beam characteristics and to verify the source proper operation. The SPIDER beam will be characterised by the instrumented calorimeter STRIKE, whose main components are one-directional carbon fibre carbon composite tiles. Some prototype tiles have been employed in 2012 as a small-scale version (mini-STRIKE) of the entire system to investigate the features of the beam from BATMAN at IPP-Garching. As the BATMAN beamlets are superposed at the measurement position, about 1m from the grounded grid, an actively cooled copper mask is located in front of the tiles; holes in the mask create an artificial beamlet structure. Recently the mini-STRIKE has been updated, taking into account the results obtained in the first campaign. In particular the spatial resolution of the system has been improved by increasing the number of the copper mask holes. Moreover a custom measurement system has been realized for the thermocouple signals and employed in BATMAN in view of its use in SPIDER. The present contribution gives a description of the new design of the system as well as of the thermocouple measurements system and its field test. A new series of measurements has been carried out in BATMAN. The BATMAN beam characterisation in different experimental conditions is presented.

  5. Update Direct-Strike Lightning Environment for Stockpile-to-Target Sequence

    SciTech Connect (OSTI)

    Uman, M A; Rakov, V A; Elisme, J O; Jordan, D M; Biagi, C J; Hill, J D

    2008-10-01

    The University of Florida has surveyed all relevant publications reporting lightning characteristics and presents here an up-to-date version of the direct-strike lightning environment specifications for nuclear weapons published in 1989 by R. J. Fisher and M. A. Uman. Further, we present functional expressions for current vs. time, current derivative vs. time, second current derivative vs. time, charge transfer vs. time, and action integral (specific energy) vs. time for first return strokes, for subsequent return strokes, and for continuing currents; and we give sets of constants for these expressions so that they yield approximately the median and extreme negative lightning parameters presented in this report. Expressions for the median negative lightning waveforms are plotted. Finally, we provide information on direct-strike lightning damage to metals such as stainless steel, which could be used as components of storage containers for nuclear waste materials; and we describe UF's new experimental research program to add to the sparse data base on the properties of positive lightning. Our literature survey, referred to above, is included in four Appendices. The following four sections (II, III, IV, and V) of this final report deal with related aspects of the research: Section II. Recommended Direct-Strike Median and Extreme Parameters; Section III. Time-Domain Waveforms for First Strokes, Subsequent Strokes, and Continuing Currents; Section IV. Damage to Metal Surfaces by Lightning Currents; and Section V. Measurement of the Characteristics of Positive Lightning. Results of the literature search used to derive the material in Section II and Section IV are found in the Appendices: Appendix 1. Return Stroke Current, Appendix 2. Continuing Current, Appendix 3. Positive Lightning, and Appendix 4. Lightning Damage to Metal Surfaces.

  6. Fish Passage though Hydropower Turbines: Simulating Blade Strike using the Discrete Element Method

    SciTech Connect (OSTI)

    Richmond, Marshall C.; Romero Gomez, Pedro DJ

    2014-12-08

    mong the hazardous hydraulic conditions affecting anadromous and resident fish during their passage though turbine flows, two are believed to cause considerable injury and mortality: collision on moving blades and decompression. Several methods are currently available to evaluate these stressors in installed turbines, i.e. using live fish or autonomous sensor devices, and in reduced-scale physical models, i.e. registering collisions from plastic beads. However, a priori estimates with computational modeling approaches applied early in the process of turbine design can facilitate the development of fish-friendly turbines. In the present study, we evaluated the frequency of blade strike and nadir pressure environment by modeling potential fish trajectories with the Discrete Element Method (DEM) applied to fish-like composite particles. In the DEM approach, particles are subjected to realistic hydraulic conditions simulated with computational fluid dynamics (CFD), and particle-structure interactions—representing fish collisions with turbine blades—are explicitly recorded and accounted for in the calculation of particle trajectories. We conducted transient CFD simulations by setting the runner in motion and allowing for better turbulence resolution, a modeling improvement over the conventional practice of simulating the system in steady state which was also done here. While both schemes yielded comparable bulk hydraulic performance, transient conditions exhibited a visual improvement in describing flow variability. We released streamtraces (steady flow solution) and DEM particles (transient solution) at the same location from where sensor fish (SF) have been released in field studies of the modeled turbine unit. The streamtrace-based results showed a better agreement with SF data than the DEM-based nadir pressures did because the former accounted for the turbulent dispersion at the intake but the latter did not. However, the DEM-based strike frequency is more

  7. Simulating Blade-Strike on Fish passing through Marine Hydrokinetic Turbines

    SciTech Connect (OSTI)

    Romero Gomez, Pedro DJ; Richmond, Marshall C.

    2014-06-16

    The study reported here evaluated the occurrence, frequency, and intensity of blade strike of fish on an axial-flow marine hydrokinetic turbine by using two modeling approaches: a conventional kinematic formulation and a proposed Lagrangian particle- based scheme. The kinematic model included simplifying assumptions of fish trajectories such as distribution and velocity. The proposed method overcame the need for such simplifications by integrating the following components into a computational fluid dynamics (CFD) model: (i) advanced eddy-resolving flow simulation, (ii) generation of ambient turbulence based on field data, (iii) moving turbine blades in highly transient flows, and (iv) Lagrangian particles to mimic the potential fish pathways. The test conditions to evaluate the blade-strike probability and fish survival rate were: (i) the turbulent environment, (ii) the fish size, and (iii) the approaching flow velocity. The proposed method offered the ability to produce potential fish trajectories and their interaction with the rotating turbine. Depending upon the scenario, the percentile of particles that registered a collision event ranged from 6% to 19% of the released sample size. Next, by using a set of experimental correlations of the exposure-response of living fish colliding with moving blades, the simulated collision data were used as input variables to estimate the survival rate of fish passing through the operating turbine. The resulting survival rates were greater than 96% in all scenarios, which is comparable to or better than known survival rates for conventional hydropower turbines. The figures of strike probability and mortality rate were amplified by the kinematic model. The proposed method offered the advantage of expanding the evaluation of other mechanisms of stress and injury on fish derived from hydrokinetic turbines and related devices.

  8. DISCRETE ELEMENT MODELING OF BLADE–STRIKE FREQUENCY AND SURVIVAL OF FISH PASSING THROUGH HYDROKINETIC TURBINES

    SciTech Connect (OSTI)

    Romero Gomez, Pedro DJ; Richmond, Marshall C.

    2014-04-17

    Evaluating the consequences from blade-strike of fish on marine hydrokinetic (MHK) turbine blades is essential for incorporating environmental objectives into the integral optimization of machine performance. For instance, experience with conventional hydroelectric turbines has shown that innovative shaping of the blade and other machine components can lead to improved designs that generate more power without increased impacts to fish and other aquatic life. In this work, we used unsteady computational fluid dynamics (CFD) simulations of turbine flow and discrete element modeling (DEM) of particle motion to estimate the frequency and severity of collisions between a horizontal axis MHK tidal energy device and drifting aquatic organisms or debris. Two metrics are determined with the method: the strike frequency and survival rate estimate. To illustrate the procedure step-by-step, an exemplary case of a simple runner model was run and compared against a probabilistic model widely used for strike frequency evaluation. The results for the exemplary case showed a strong correlation between the two approaches. In the application case of the MHK turbine flow, turbulent flow was modeled using detached eddy simulation (DES) in conjunction with a full moving rotor at full scale. The CFD simulated power and thrust were satisfactorily comparable to experimental results conducted in a water tunnel on a reduced scaled (1:8.7) version of the turbine design. A cloud of DEM particles was injected into the domain to simulate fish or debris that were entrained into the turbine flow. The strike frequency was the ratio of the count of colliding particles to the crossing sample size. The fish length and approaching velocity were test conditions in the simulations of the MHK turbine. Comparisons showed that DEM-based frequencies tend to be greater than previous results from Lagrangian particles and probabilistic models, mostly because the DEM scheme accounts for both the geometric

  9. Argonne and CalBattery strike deal for silicon-graphene anode material -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Energy Storage Energy Storage Return to Search Argonne and CalBattery strike deal for silicon-graphene anode material Argonne National Laboratory CalBattery has worked with Argonne for more than a year under a Work for Others agreement to develop the technology under the Department of Energy's Startup America program, which is part of a White House initiative to inspire and accelerate high-growth entrepreneurship. CalBattery has worked with Argonne for more

  10. Controlling Gold Nanoclusters by Diphospine Ligands

    SciTech Connect (OSTI)

    Chen, Jing; Zhang, Qianfan; Bonaccorso, Timary A.; Williard, Paul G.; Wang, Lai S.

    2014-01-08

    We report the synthesis and structure determination of a new Au22 nanocluster coordinated by six bidentate diphosphine ligands: 1,8-bis(diphenylphosphino) octane (L8 for short). Single crystal x-ray crystallography and electrospray ionization mass spectrometry show that the cluster assembly is neutral and can be formulated as Au22(L8)6. The Au22 core consists of two Au11 units clipped together by four L8 ligands, while the additional two ligands coordinate to each Au11 unit in a bidentate fashion. Eight gold atoms at the interface of the two Au11 units are not coordinated by any ligands. Four short gold-gold distances (2.64?2.65 Å) are observed at the interface of the two Au11 clusters as a result of the clamping force of the four clipping ligands and strong electronic interactions. The eight uncoordinated surface gold atoms in the Au22(L8)6 nanocluster are unprecedented in atom-precise gold nanoparticles and can be considered as potential in-situ active sites for catalysis.

  11. Fish Passage Assessment of an Advanced Hydropower Turbine and Conventional Turbine Using Blade-strike Modeling

    SciTech Connect (OSTI)

    Deng, Zhiqun; Carlson, Thomas J.; Dauble, Dennis D.; Ploskey, Gene R.

    2011-01-04

    In the Columbia and Snake River basins, several species of Pacific salmon were listed under the Endangered Species Act of 1973 due to significant declines of fish population. Dam operators and design engineers are thus faced with the task of making those hydroelectric facilities more ecologically friendly through changes in hydro-turbine design and operation. Public Utility District No. 2 of Grant County, Washington, applied for re-licensing from the U.S. Federal Energy Regulatory Commission to replace the 10 turbines at Wanapum Dam with advanced hydropower turbines that were designed to increase power generation and improve fish passage conditions. We applied both deterministic and stochastic blade-strike models to the newly installed turbine and an existing turbine. Modeled probabilities were compared to the results of a large-scale live fish survival study and a sensor fish study under the same operational parameters. Overall, injury rates predicted by the deterministic model were higher than experimental rates of injury while those predicted by the stochastic model were in close agreement with experiment results. Fish orientation at the time of entry into the plane of the leading edges of the turbine runner blades was an important factor contributing to uncertainty in modeled results. The advanced design turbine had slightly higher modeled injury rates than the existing turbine design; however, there was no statistical evidence that suggested significant differences in blade-strike injuries between the two turbines and the hypothesis that direct fish survival rate through the advanced hydropower turbine is equal or better than that through the conventional turbine could not be rejected.

  12. Fresh Air That's as Good as Gold | Department of Energy

    Energy Savers [EERE]

    Fresh Air That's as Good as Gold Fresh Air That's as Good as Gold July 8, 2013 - 5:25pm Addthis Brookhaven Lab physicists Peter Sutter, Eli Sutter,and Xiao Tong (left to right) ...

  13. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Print Nanoparticles-man-made atoms with unique ... films from highly ordered one--, two- and three-dimensional arrays of gold nanoparticles. ...

  14. Gold Medal Approaches for Obtaining and Using Energy Efficiency...

    Office of Environmental Management (EM)

    Gold Medal Approaches for Obtaining and Using Energy Efficiency Data (101) Gold Medal Approaches for Obtaining and Using Energy Efficiency Data (101) August 11, 2016 1:00PM to ...

  15. Scientists Can Recycle CO2 Using Gold | Department of Energy

    Office of Environmental Management (EM)

    Can Recycle CO2 Using Gold Scientists Can Recycle CO2 Using Gold May 27, 2016 - 9:57am Addthis A new chemical process has the potential to reduce atmospheric CO2 emissions by ...

  16. Going for the Gold (Computer) | Department of Energy

    Energy Savers [EERE]

    Going for the Gold (Computer) March 3, 2009 - 4:00am Addthis John Lippert Last summer I ... EPEAT products are identified as EPEAT-Bronze, EPEAT-Silver, or EPEAT-Gold depending on ...

  17. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Guided Self-Assembly of Gold Thin Films Print Wednesday, 21 November 2012 12:18 Nanoparticles-man-made atoms with unique optical, ...

  18. Electronic Structure of Thiol-Covered Gold Nanoparticles: Au102...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure of Thiol-Covered Gold Nanoparticles: Au102(MBA)44 Authors: Li, Y., Galli, G., ... properties of thiolate-protected gold nanoparticles Au102(MBA)44 that have ...

  19. World's largest single crystal of gold verified at Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    World's largest single crystal of gold verified at Los Alamos World's largest single crystal of gold verified at Los Alamos The SCD instrument is used to determine the periodic ...

  20. Rainbows and Leprechauns: Finding Gold in Partnerships (101)...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rainbows and Leprechauns: Finding Gold in Partnerships (101) Rainbows and Leprechauns: Finding Gold in Partnerships (101) March 17, 2016 1:00PM to 2:30PM EDT

  1. Electrocatalyst Having Gold Monolayers on Platinum Nanoparticle Cores and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Uses Thereof - Energy Innovation Portal Having Gold Monolayers on Platinum Nanoparticle Cores and Uses Thereof Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Stabilization of Platinum Oxygen-Reduction Electrocatalysts Using Gold Clusters (263 KB) <p> Scanning electron micrograph of gold clusters on platinum nanoparticles</p> Scanning electron micrograph of gold clusters on platinum nanoparticles Technology Marketing Summary

  2. Gold-coated nanoparticles for use in biotechnology applications

    DOE Patents [OSTI]

    Berning, Douglas E.; Kraus, Jr., Robert H.; Atcher, Robert W.; Schmidt, Jurgen G.

    2009-07-07

    A process of preparing gold-coated magnetic nanoparticles is disclosed and includes forming a suspension of magnetic nanoparticles within a suitable liquid, adding an amount of a reducible gold compound and a reducing agent to the suspension, and, maintaining the suspension for time sufficient to form gold-coated magnetic nanoparticles.

  3. Gold-coated nanoparticles for use in biotechnology applications

    DOE Patents [OSTI]

    Berning, Douglas E.; Kraus, Jr., Robert H.; Atcher, Robert W.; Schmidt, Jurgen G.

    2007-06-05

    A process of preparing gold-coated magnetic nanoparticles is disclosed and includes forming a suspension of magnetic nanoparticles within a suitable liquid, adding an amount of a reducible gold compound and a reducing agent to the suspension, and, maintaining the suspension for time sufficient to form gold-coated magnetic nanoparticles.

  4. Waltzer Receives NNSA Gold Medal Award | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) Waltzer Receives NNSA Gold Medal Award June 26, 2014 Karl Waltzer, Acting Deputy Manager of the National Nuclear Security Administration's Production Office, has received the NNSA Gold Medal Award in recognition of his distinguished achievements in support of national security programs. File Waltzer Receives NNSA Gold Medal Award

  5. High Strength Gold Wire for Microelectronics Miniaturization - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal High Strength Gold Wire for Microelectronics Miniaturization Ames Laboratory Contact AMES About This Technology Technology Marketing Summary ISU and Ames Laboratory researchers have developed a high strength gold wire for use in microelectronics that can maintain its electrical and mechanical properties while permitting miniaturization of microelectronics design. Description Gold alloy wires currently used in microelectronics have limited electrical and mechanical

  6. X-ray laser driven gold targets

    SciTech Connect (OSTI)

    Petrova, Tz. B. Whitney, K. G.; Davis, J.

    2014-03-15

    The femtosecond population dynamics of gold irradiated by a coherent high-intensity (>10{sup 17} W/cm{sup 2}) x-ray laser pulse is investigated theoretically. There are two aspects to the assembled model. One is the construction of a detailed model of platinum-like gold inclusive of all inner-shell states that are created by photoionization of atomic gold and decay either by radiative or Auger processes. Second is the computation of the population dynamics that ensues when an x-ray pulse is absorbed in gold. The hole state generation depends on the intensity and wavelength of the driving x-ray pulse. The excited state populations reached during a few femtosecond timescales are high enough to generate population inversions, whose gain coefficients are calculated. These amplified lines in the emitted x-ray spectrum provide important diagnostics of the radiation dynamics and also suggest a nonlinear way to increase the frequency of the coherent output x-ray pulses relative to the frequency of the driver input x-ray pulse.

  7. Detailed energy distributions in laser-produced plasmas of solid gold and foam gold planar targets

    SciTech Connect (OSTI)

    Dong, Yunsong; Zhang, Lu; Yang, Jiamin; Shang, Wanli

    2013-12-15

    Foam gold was proposed to increase the laser to x-ray conversion efficiency due to its important applications. To understand the mechanism of x-ray enhancement, the detailed energy distributions and plasma profiles for laser-irradiated solid gold and foam gold targets were studied comparatively by hydrodynamic simulations using the code Multi-1D. It is confirmed that the radiation heat wave is subsonic for the normal solid gold target, while supersonic for the foam gold target. The shock wave, which is behind the supersonic radiation heat wave for the foam gold target, generates a plasma temperature gradient with high temperature near the shock wave front to produce an additional net outward radiation for enhancement of the x-ray emission. Much larger inward plasma velocity is also driven by the shock wave as an initial plasma velocity for the laser deposition and electron thermal conduct zone, which decreases the expanding plasma kinetic energy loss and helps to increase the x-ray radiation.

  8. Analysis of the growth of strike-slip faults using effective medium theory

    SciTech Connect (OSTI)

    Aydin, A.; Berryman, J.G.

    2009-10-15

    Increases in the dimensions of strike-slip faults including fault length, thickness of fault rock and the surrounding damage zone collectively provide quantitative definition of fault growth and are commonly measured in terms of the maximum fault slip. The field observations indicate that a common mechanism for fault growth in the brittle upper crust is fault lengthening by linkage and coalescence of neighboring fault segments or strands, and fault rock-zone widening into highly fractured inner damage zone via cataclastic deformation. The most important underlying mechanical reason in both cases is prior weakening of the rocks surrounding a fault's core and between neighboring fault segments by faulting-related fractures. In this paper, using field observations together with effective medium models, we analyze the reduction in the effective elastic properties of rock in terms of density of the fault-related brittle fractures and fracture intersection angles controlled primarily by the splay angles. Fracture densities or equivalent fracture spacing values corresponding to the vanishing Young's, shear, and quasi-pure shear moduli were obtained by extrapolation from the calculated range of these parameters. The fracture densities or the equivalent spacing values obtained using this method compare well with the field data measured along scan lines across the faults in the study area. These findings should be helpful for a better understanding of the fracture density/spacing distribution around faults and the transition from discrete fracturing to cataclastic deformation associated with fault growth and the related instabilities.

  9. Antifungal activity of gold nanoparticles prepared by solvothermal method

    SciTech Connect (OSTI)

    Ahmad, Tokeer; Wani, Irshad A.; Lone, Irfan H.; Ganguly, Aparna; Manzoor, Nikhat; Ahmad, Aijaz; Ahmed, Jahangeer; Al-Shihri, Ayed S.

    2013-01-15

    Graphical abstract: Gold nanoparticles (7 and 15 nm) of very high surface area (329 and 269 m{sup 2}/g) have been successfully synthesized through solvothermal method by using tin chloride and sodium borohydride as reducing agents. As-prepared gold nanoparticles shows very excellent antifungal activity against Candida isolates and activity increases with decrease in the particle size. Display Omitted Highlights: ► Effect of reducing agents on the morphology of gold nanoparticles. ► Highly uniform and monodisperse gold nanoparticles (7 nm). ► Highest surface area of gold nanoparticles (329 m{sup 2/}g). ► Excellent antifungal activity of gold nanoparticles against Candida strains. -- Abstract: Gold nanoparticles have been successfully synthesized by solvothermal method using SnCl{sub 2} and NaBH{sub 4} as reducing agents. X-ray diffraction studies show highly crystalline and monophasic nature of the gold nanoparticles with face centred cubic structure. The transmission electron microscopic studies show the formation of nearly spherical gold nanoparticles of average size of 15 nm using SnCl{sub 2}, however, NaBH{sub 4} produced highly uniform, monodispersed and spherical gold nanoparticles of average grain size of 7 nm. A high surface area of 329 m{sup 2}/g for 7 nm and 269 m{sup 2}/g for 15 nm gold nanoparticles was observed. UV–vis studies assert the excitations over the visible region due to transverse and longitudinal surface plasmon modes. The gold nanoparticles exhibit excellent size dependant antifungal activity and greater biocidal action against Candida isolates for 7 nm sized gold nanoparticles restricting the transmembrane H{sup +} efflux of the Candida species than 15 nm sized gold nanoparticles.

  10. COMMISSIONING OF RHIC DEUTERON - GOLD COLLISIONS.

    SciTech Connect (OSTI)

    SATOGATA,T.AHRENS,L.BAI,M.BEEBE-WANG,J.

    2003-05-12

    Deuteron and gold beams have been accelerated to a collision energy of {radical}s = 200 GeV/u in the Relativistic Heavy Ion Collider (RHIC), providing the first asymmetric-species collisions of this complex. Necessary changes for this mode of operation include new ramping software and asymmetric crossing angle geometries. This paper reviews machine performance, problem encountered and their solutions, and accomplishments during the 16 weeks of ramp-up and operations.

  11. Estimation of the Risks of Collision or Strike to Freshwater Aquatic Organisms Resulting from Operation of Instream Hydrokinetic Turbines

    SciTech Connect (OSTI)

    Schweizer, Peter E; Cada, Glenn F; Bevelhimer, Mark S

    2010-05-01

    Hydrokinetic energy technologies have been proposed as renewable, environmentally preferable alternatives to fossil fuels for generation of electricity. Hydrokinetic technologies harness the energy of water in motion, either from waves, tides or from river currents. For energy capture from free-flowing rivers, arrays of rotating devices are most commonly proposed. The placement of hydrokinetic devices in large rivers is expected to increase the underwater structural complexity of river landscapes. Moore and Gregory (1988) found that structural complexity increased local fish populations because fish and other aquatic biota are attracted to structural complexity that provides microhabitats with steep flow velocity gradients (Liao 2007). However, hydrokinetic devices have mechanical parts, blades, wings or bars that move through the water column, posing a potential strike or collision risk to fish and other aquatic biota. Furthermore, in a setting with arrays of hydrokinetic turbines the cumulative effects of multiple encounters may increase the risk of strike. Submerged structures associated with a hydrokinetic (HK) project present a collision risk to aquatic organisms and diving birds (Cada et al. 2007). Collision is physical contact between a device or its pressure field and an organism that may result in an injury to that organism (Wilson et al. 2007). Collisions can occur between animals and fixed submerged structures, mooring equipment, horizontal or vertical axis turbine rotors, and structures that, by their individual design or in combination, may form traps. This report defines strike as a special case of collision where a moving part, such as a rotor blade of a HK turbine intercepts the path of an organism of interest, resulting in physical contact with the organism. The severity of a strike incidence may range from minor physical contact with no adverse effects to the organism to severe strike resulting in injury or death of the organism. Harmful effects

  12. Brazing open cell reticulated copper foam to stainless steel tubing with vacuum furnace brazed gold/indium alloy plating

    DOE Patents [OSTI]

    Howard, Stanley R.; Korinko, Paul S.

    2008-05-27

    A method of fabricating a heat exchanger includes brush electroplating plated layers for a brazing alloy onto a stainless steel tube in thin layers, over a nickel strike having a 1.3 .mu.m thickness. The resultant Au-18 In composition may be applied as a first layer of indium, 1.47 .mu.m thick, and a second layer of gold, 2.54 .mu.m thick. The order of plating helps control brazing erosion. Excessive amounts of brazing material are avoided by controlling the electroplating process. The reticulated copper foam rings are interference fit to the stainless steel tube, and in contact with the plated layers. The copper foam rings, the plated layers for brazing alloy, and the stainless steel tube are heated and cooled in a vacuum furnace at controlled rates, forming a bond of the copper foam rings to the stainless steel tube that improves heat transfer between the tube and the copper foam.

  13. Another Gold for PPPL: Laboratory Wins 2nd Gold GreenBuy Award | Princeton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plasma Physics Lab Another Gold for PPPL: Laboratory Wins 2nd Gold GreenBuy Award By Jeanne Jackson DeVoe September 23, 2013 Tweet Widget Google Plus One Share on Facebook Teodora Todorova cleans a restroom with green products like HydroxiPro, which is 100 percent bio-based. The hand soap in PPPL's rest rooms is made mostly of vegetable-based glycerin and aloe. The paper products are made from 70 to 100 percent recycled products and the hand towels are composted at PPPL. Teodora Todorova

  14. Newest Los Alamos facility receives LEED® Gold certification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Newest facility receives LEED® Gold certification Newest Los Alamos facility receives LEED® Gold certification The Radiological Laboratory Utility Office Building is first to achieve both the Leadership in Energy and Environmental Design status and LEED Gold certification. June 13, 2012 Radiological Laboratory Utility Office Building Radiological Laboratory Utility Office Building Contact Kim Powell Communications Office (505) 695-6159 Email LOS ALAMOS, New Mexico, June 13, 2012-Los Alamos

  15. Synthesis of porous gold nanoshells by controlled transmetallation reaction

    SciTech Connect (OSTI)

    Pattabi, Manjunatha M, Krishnaprabha

    2015-06-24

    Aqueous synthesis of porous gold nanoshells in one step is carried out through controlled transmetallation (TM) reaction using a naturally available egg shell membrane (ESM) as a barrier between the sacrificial silver particles (AgNPs) and the gold precursor solution (HAuCl{sub 4}). The formation of porous gold nanoshells via TM reaction is inferred from UV-Vis spectroscopy and the scanning electron microscopic (SEM) studies.

  16. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Molecular Structure of Water at Gold Electrodes Revealed Print Wednesday, 25 March 2015 00:00 The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific

  17. World's largest single crystal of gold verified at Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    World's largest single crystal of gold verified at Los Alamos World's largest single crystal of gold verified at Los Alamos The SCD instrument is used to determine the periodic atomic arrangement or crystal structure of single crystals, both natural and synthetic. April 7, 2014 Neutron diffraction data collected on the single-crystal diffraction (SCD) instrument at the Lujan Center, from the Venezuelan gold sample, indicate that the sample is a single crystal. Neutron diffraction data collected

  18. Los Alamos explores hybrid ultrasmall gold nanocluster for enzymatic fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cells Hybrid ultrasmall gold nanocluster for enzymatic fuel cells Los Alamos explores hybrid ultrasmall gold nanocluster for enzymatic fuel cells With fossil-fuel sources dwindling, better biofuel cell design is a strong candidate in the energy field. September 24, 2015 Gold nanoclusters (~1 nm) are efficient mediators of electron transfer between co-self-assembled enzymes and carbon nanotubes in an enzyme fuel cell. The efficient electron transfer from this quantized nano material minimizes

  19. Earned Value Management System Gold Card | Department of Energy

    Energy Savers [EERE]

    Gold Card Earned Value Management System Gold Card Earned Value Management (EVM) is a systematic approach to the integration and measurement of cost, schedule, and technical (scope) accomplishments on a project or task. It provides both the government and contractors the ability to examine detailed schedule information, critical program and technical milestones, and cost data. Formulas and Terminology "Gold Card" -- September 2011 (92.71 KB) Key Resources PMCDP EVMS PARS IIe FPD

  20. Rainbows and Leprechauns: Finding Gold in Partnerships (101)

    Broader source: Energy.gov [DOE]

    Better Buildings Residential Network Peer Exchange Call Series: Rainbows and Leprechauns: Finding Gold in Partnerships (101), March 17, 2016, call slides and discussion summary.

  1. Microsoft PowerPoint - Marion Gold.Providence.Infrastructure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Quadrennial Energy Review Providence, Rhode Island Monday, April 21, 2014 Marion S. Gold, Ph.D. Commissioner Rhode Island Office of Energy Resources RI Office of Energy ...

  2. Rainbows and Leprechauns: Finding Gold in Partnerships (101)...

    Broader source: Energy.gov (indexed) [DOE]

    Peer Exchange Call Series: Rainbows and Leprechauns: Finding Gold in Partnerships (101), March 17, 2016, call slides and discussion summary. Call Slides and Discussion Summary ...

  3. Laminin receptor specific therapeutic gold nanoparticles (198AuNP...

    Office of Scientific and Technical Information (OSTI)

    prostate cancer Citation Details In-Document Search Title: Laminin receptor specific therapeutic gold nanoparticles (198AuNP-EGCg) show efficacy in treating prostate cancer ...

  4. Los Alamos explores hybrid ultrasmall gold nanocluster for enzymatic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos explores hybrid ultrasmall gold nanocluster for enzymatic fuel cells With fossil-fuel sources dwindling, better biofuel cell design is a strong candidate in the energy ...

  5. Understanding Interactions between Manganese Oxide and Gold That...

    Office of Scientific and Technical Information (OSTI)

    Water Oxidation Prev Next Title: Understanding Interactions between Manganese Oxide and Gold That Lead to Enhanced Activity for Electrocatalytic Water Oxidation ...

  6. Argonne APCF achieves LEED Gold rating | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory's Advanced Protein Characterization Facility (APCF) has received the U.S. Green Building Council's Leadership in Energy and Environmental Design (LEED) Gold...

  7. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... It does not require chemical modification to any of the components in the composite system ... of many materials besides gold, making it well suited for scalable manufacturing. ...

  8. BioGold Fuels Corporation | Open Energy Information

    Open Energy Info (EERE)

    through joint ventures a lower-cost, higher-output system for the production of diesel fuel derived from Municipal Solid Waste ("MSW"). References: BioGold Fuels...

  9. Active Geothermal Systems And Associated Gold Deposits In The...

    Open Energy Info (EERE)

    Geothermal Systems And Associated Gold Deposits In The Great Basin Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Active Geothermal Systems...

  10. Charles E. Messick receives the Administrator's Gold Award |...

    National Nuclear Security Administration (NNSA)

    E. Messick receives the Administrator's Gold Award | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing...

  11. Gold River, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    (Redirected from Gold River, CA) Jump to: navigation, search Equivalent URI DBpedia Coordinates 38.6262937, -121.2466156 Show Map Loading map... "minzoom":false,"mappingservic...

  12. NNSA Nevada Support Facility Receives LEED Gold Certificate ...

    National Nuclear Security Administration (NNSA)

    Nevada Support Facility as Leadership in Energy and Environmental Design (LEED) Gold ... The LEED rating system, developed by the U.S. Green Building Council, is the foremost ...

  13. Federal Electronics Challenge Gold Award | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    On June 18th, DOE Headquarters was presented the Federal Electronics Challenge Gold Award for exemplary performance in Green Computing, including green procurement, energy ...

  14. Gold nanoparticle formation in diamond-like carbon using two different methods: Gold ion implantation and co-deposition of gold and carbon

    SciTech Connect (OSTI)

    Salvadori, M. C.; Teixeira, F. S.; Araujo, W. W. R.; Sgubin, L. G.; Cattani, M.; Spirin, R. E.; Brown, I. G.

    2012-10-01

    We describe work in which gold nanoparticles were formed in diamond-like carbon (DLC), thereby generating a Au-DLC nanocomposite. A high-quality, hydrogen-free DLC thin film was formed by filtered vacuum arc plasma deposition, into which gold nanoparticles were introduced using two different methods. The first method was gold ion implantation into the DLC film at a number of decreasing ion energies, distributing the gold over a controllable depth range within the DLC. The second method was co-deposition of gold and carbon, using two separate vacuum arc plasma guns with suitably interleaved repetitive pulsing. Transmission electron microscope images show that the size of the gold nanoparticles obtained by ion implantation is 3-5 nm. For the Au-DLC composite obtained by co-deposition, there were two different nanoparticle sizes, most about 2 nm with some 6-7 nm. Raman spectroscopy indicates that the implanted sample contains a smaller fraction of sp{sup 3} bonding for the DLC, demonstrating that some sp{sup 3} bonds are destroyed by the gold implantation.

  15. Method for aqueous gold thiosulfate extraction using copper-cyanide pretreated carbon adsorption

    SciTech Connect (OSTI)

    Young, Courtney; Melashvili, Mariam; Gow, Nicholas V

    2013-08-06

    A gold thiosulfate leaching process uses carbon to remove gold from the leach liquor. The activated carbon is pretreated with copper cyanide. A copper (on the carbon) to gold (in solution) ratio of at least 1.5 optimizes gold recovery from solution. To recover the gold from the carbon, conventional elution technology works but is dependent on the copper to gold ratio on the carbon.

  16. Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide

    SciTech Connect (OSTI)

    Friend, Cynthia M; Madix, Robert J; Xu, Bingjun

    2015-01-20

    The invention provides a method for producing organic carbonates via the reaction of alcohols and carbon monoxide with oxygen adsorbed on a metallic gold or gold alloy catalyst.

  17. Argonne/EPA system captures mercury from air in gold shops |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Typical gold shop hood used to purify gold by superheating the goldmercury amalgam until the mercury vaporizes. The vaporized mercury is directed outside the shop into the open...

  18. Seeing Gold Nanoparticles Self-Assemble with in situ Liquid Transmissi...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Seeing Gold Nanoparticles Self-Assemble with in situ Liquid Transmission Electron Microscopy December 15, 2014 Tweet EmailPrint Scientific Achievement The self-assembly of gold...

  19. Department of Energy - Gold Award Press Release 9/10/2003

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Francis Collins and Ari Patrinos Receive Energy Secretary's Gold Award for Human Genome ... the Secretary's Gold Award for their leadership of the government's Human Genome Project. ...

  20. Exhaust system having a gold-platinum group metal catalyst

    DOE Patents [OSTI]

    Ragle, Christie Susan; Silver, Ronald G.; Zemskova, Svetlana Mikhailovna; Eckstein, Colleen J.

    2011-12-06

    A method of providing an exhaust treatment device is disclosed. The method includes applying a catalyst including gold and a platinum group metal to a particulate filter. The concentration of the gold and the platinum group metal is sufficient to enable oxidation of carbon monoxide and nitric oxide.

  1. Exhaust system having a gold-platinum group metal catalyst

    DOE Patents [OSTI]

    Ragle, Christie Susan; Silver, Ronald G.; Zemskova, Svetlana Mikhailovna; Eckstein, Colleen J.

    2012-08-07

    A method of providing an exhaust treatment device is disclosed. The method includes applying a catalyst including gold and a platinum group metal to a particulate filter. The concentration of the gold and the platinum group metal is sufficient to enable oxidation of carbon monoxide and nitric oxide.

  2. Reducing wall plasma expansion with gold foam irradiated by laser

    SciTech Connect (OSTI)

    Zhang, Lu; Ding, Yongkun Jiang, Shaoen Yang, Jiamin; Li, Hang; Kuang, Longyu; Lin, Zhiwei; Jing, Longfei; Li, Liling; Deng, Bo; Yuan, Zheng; Chen, Tao; Yuan, Guanghui; Tan, Xiulan; Li, Ping

    2015-11-15

    The experimental study on the expanding plasma movement of low-density gold foam (∼1% solid density) irradiated by a high power laser is reported in this paper. Experiments were conducted using the SG-III prototype laser. Compared to solid gold with 19.3 g/cc density, the velocities of X-ray emission fronts moving off the wall are much smaller for gold foam with 0.3 g/cc density. Theoretical analysis and MULTI 1D simulation results also show less plasma blow-off, and that the density contour movement velocities of gold foam are smaller than those of solid gold, agreeing with experimental results. These results indicate that foam walls have advantages in symmetry control and lowering plasma fill when used in ignition hohlraum.

  3. 1 mil gold bond wire study.

    SciTech Connect (OSTI)

    Huff, Johnathon; McLean, Michael B.; Jenkins, Mark W.; Rutherford, Brian Milne

    2013-05-01

    In microcircuit fabrication, the diameter and length of a bond wire have been shown to both affect the current versus fusing time ratio of a bond wire as well as the gap length of the fused wire. This study investigated the impact of current level on the time-to-open and gap length of 1 mil by 60 mil gold bond wires. During the experiments, constant current was provided for a control set of bond wires for 250ms, 410ms and until the wire fused; non-destructively pull-tested wires for 250ms; and notched wires. The key findings were that as the current increases, the gap length increases and 73% of the bond wires will fuse at 1.8A, and 100% of the wires fuse at 1.9A within 60ms. Due to the limited scope of experiments and limited data analyzed, further investigation is encouraged to confirm these observations.

  4. Synthesis of gold nanoparticles with different atomistic structural characteristics

    SciTech Connect (OSTI)

    Esparza, R. . E-mail: roesparza@gmail.com; Rosas, G.; Lopez Fuentes, M.; Sanchez Ramirez, J.F.; Pal, U.; Ascencio, J.A.; Perez, R.

    2007-08-15

    A chemical reduction method was used to produce nanometric gold particles. Depending on the concentration of the main reactant compound different nanometric sizes and consequently different atomic structural configurations of the particles are obtained. Insights on the structural nature of the gold nanoparticles are obtained through a comparison between digitally-processed experimental high-resolution electron microscopy images and theoretically-simulated images obtained with a multislice approach of the dynamical theory of electron diffraction. Quantum molecular mechanical calculations, based on density functional theory, are carried out to explain the relationships between the stability of the gold nanoparticles, the atomic structural configurations and the size of nanoparticles.

  5. Water and Gold: A Promising Mix for Future Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water and Gold: A Promising Mix for Future Batteries Water and Gold: A Promising Mix for Future Batteries Berkeley Lab Study Reveals Molecular Structure of Water at Gold Electrodes October 23, 2014 Contact: Rachel Berkowitz, 510-486-7254, rberkowitz@lbl.gov When a solid material is immersed in a liquid, the liquid immediately next to its surface differs from that of the bulk liquid at the molecular level. This interfacial layer is critical to our understanding of a diverse set of phenomena from

  6. Impedimetric investigation of gold nanoparticles - guanine modified electrode

    SciTech Connect (OSTI)

    Vulcu, A.; Pruneanu, S.; Berghian-Grosan, C.; Olenic, L.; Muresan, L. M.; Barbu-Tudoran, L.

    2013-11-13

    In this paper we report the preparation of a modified electrode with gold nanoparticles and guanine. The colloidal suspension of gold nanoparticles was obtained by Turkevich method and was next analyzed by UV-Vis spectroscopy and Transmission Electron Microscopy (TEM). The gold electrode was modified by self-assembling the gold nanoparticles with guanine, the organic molecule playing also the role of linker. The electrochemical characteristics of the bare and modified electrode were investigated by Electrochemical Impedance Spectroscopy (EIS). A theoretical model was developed based on an electrical equivalent circuit which contain solution resistance (R{sub s}), charge transfer resistance (R{sub ct}), Warburg impedance (Z{sub W}) and double layer capacitance (C{sub dl})

  7. Gold interconnectors for solar generators in low earth orbits

    SciTech Connect (OSTI)

    La Roche, G.J.; Oxynos-Lauschke, C.; Wehner, K.H.

    1994-12-31

    For Low Earth Orbit applications gold based electrical connections have been developed consisting of 12.5 {micro}m thin gold solar cell interconnectors with stress relief loop, 50 {micro}m thick gold string terminations and gauge AWG 24 stranded gold wires. Modules with typical 4 cm by 6 cm Silicon solar cells mounted on a lightweight carbon fiber reinforced honeycomb substrate were manufactured including the new components applied by resistance welding. A long duration thermal cycling test was started cycling two coupons at between {minus}110 C and +110 C. As of November 1994, 27,500 cycles have been completed, and the test is continuing. Evaluation of module integrity at periodic intervals yielded no measurable degradation up to date.

  8. Geology of the Florida Canyon gold deposit, Pershing County,...

    Open Energy Info (EERE)

    Pershing County, Nevada, in: Gold and Silver Deposits of Western Nevada Authors Hastings, J.S., Burkhart, T.H., and Richardson and R.E. Published Geological Society of Nevada 1993...

  9. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Print Nanoparticles-man-made atoms with unique optical, electrical, and mechanical properties-have become key components in many fields of...

  10. Gold SolarWind GmbH | Open Energy Information

    Open Energy Info (EERE)

    SolarWind GmbH Jump to: navigation, search Name: Gold SolarWind GmbH Place: Aiterhofen, Germany Zip: 94330 Sector: Wind energy Product: German project developer of PV and wind...

  11. Gold Camp, Arizona: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Gold Camp is a census-designated place in Pinal County, Arizona.1 References US Census...

  12. Gold Hill, Colorado: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Gold Hill is a census-designated place in Boulder County, Colorado.1 References US...

  13. Gold River, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Gold River is a census-designated place in Sacramento County, California.1 References ...

  14. Gold Hill, Oregon: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Gold Hill is a city in Jackson County, Oregon. It falls under Oregon's 2nd congressional...

  15. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to ...

  16. UV laser ablation of parylene films from gold substrates

    SciTech Connect (OSTI)

    O. R. Musaev, P. Scott, J. M. Wrobel, and M. B. Kruger

    2009-11-19

    Parylene films, coating gold substrates, were removed by laser ablation using 248 nm light from an excimer laser. Each sample was processed by a different number of pulses in one of three different environments: air at atmospheric pressure, nitrogen at atmospheric pressure, and vacuum. The laser-induced craters were analyzed by optical microscopy and x-ray photoelectron spectroscopy. Multi-pulse ablation thresholds of gold and parylene were estimated.

  17. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  18. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  19. Transparent Gold as a Platform for Adsorbed Protein

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroelectrochemistry: Investigation of Cytochrome c and Azurin Transparent Gold as a Platform for Adsorbed Protein Spectroelectrochemistry: Investigation of Cytochrome c and Azurin Authors: Ashur, I., Schulz, O., McIntosh, C. L., Pinkas, I., Ros, R., and Jones, A. K. Title: Transparent Gold as a Platform for Adsorbed Protein Spectroelectrochemistry: Investigation of Cytochrome c and Azurin Source: Langmuir Year: 2012 Volume: 28 Pages: 5861-5871 ABSTRACT: The majority of protein

  20. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  1. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  2. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  3. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  4. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  5. Encapsulation of Gold Nanoparticles in a DNA Origami Cage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Encapsulation of Gold Nanoparticles in a DNA Origami Cage Authors: Zhao, Z., Jacovetty, E. L., Liu, Y., and Yan, H. Title: Encapsulation of Gold Nanoparticles in a DNA Origami Cage Source: Angewandte Chemie International Edition Year: 2011 Volume: 50 Pages: 2041-2044 ABSTRACT: A critical challenge in nanoparticle (NP) surface functionalization is to label the NP surface with a single copy of a functional group or to display multiple, unique molecules on the NP surface with control of the

  6. Doug Dearolph receives NNSA's Gold Medal of Excellence | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Doug Dearolph receives NNSA's Gold Medal of Excellence Tuesday, September 30, 2014 - 11:31am DOE Undersecretary for Nuclear Security and NNSA Administrator Frank Klotz recently presented the Gold Medal of Excellence for Distinguished Service to Doug Dearolph, manager of the Savannah River Field Office. The medal is the highest honorary award granted by NNSA and was presented to Dearolph in recognition his dedication and commitment to public service and the

  7. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Guided Self-Assembly of Gold Thin Films Print Wednesday, 21 November 2012 12:18 Nanoparticles-man-made atoms with unique optical, electrical, and mechanical properties-have become key components in many fields of science. If nanoparticles could be coaxed into routinely assembling themselves into predictable complex structures and hierarchical patterns, devices could be mass-produced that are one thousand times smaller than today's microtechnologies.

  8. Scott Samuelson receives NNSA's Gold Medal of Excellence | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Scott Samuelson receives NNSA's Gold Medal of Excellence Thursday, November 20, 2014 - 2:22pm Bob Raines, NNSA Associate Administrator for Acquisition and Project Management (APM), recently presented the Gold Medal of Excellence to Scott Samuelson, Senior Advisor for APM. The medal is the highest honorary award granted by NNSA and was presented to Samuelson in recognition to his dedication and commitment to NNSA. Samuelson will retire at the end of November

  9. Michael Lempke receives NNSA's Gold Medal of Excellence | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Michael Lempke receives NNSA's Gold Medal of Excellence Monday, June 16, 2014 - 4:25pm DOE Undersecretary for Nuclear Security and NNSA Administrator Frank Klotz recently presented the Gold Medal of Excellence for Distinguished Service to Michael Lempke, former Acting Chief and Associate Administrator for Defense Nuclear Security. The medal is the highest honorary award granted by NNSA and was presented to Lempke in recognition of his outstanding

  10. Study of the effect of plasma-striking atmosphere on Fe-oxidation in thermal dc arc-plasma processing

    SciTech Connect (OSTI)

    Banerjee, I.; Khollam, Y. B.; Mahapatra, S. K.; Das, A. K.; Bhoraskar, S. V.

    2010-11-15

    The effect of plasma-striking atmosphere: air and air+Ar-gas on the crystallization of Fe-oxide phases was studied using dc thermal arc-plasma processing route. The powders were characterized by x-ray diffraction, vibrating sample magnetometry, transmission electron microscopy, and Moessbauer spectroscopy techniques. At room temperature and O{sub 2} rich atmosphere, arc-evaporated Fe{sup 2+} ions oxidize into either {gamma}-Fe{sub 2}O{sub 3} or Fe{sub 3}O{sub 4} depending upon the combining ratio of Fe with molecular O{sub 2}. Fe/O ratio could be adjusted using proper flow rate of Ar gas to crystallize the pure {gamma}-Fe{sub 2}O{sub 3}.

  11. Laboratory Experiments on the Effects of Blade Strike from Hydrokinetic Energy Technologies on Larval and Juvenile Freshwater Fishes

    SciTech Connect (OSTI)

    Schweizer, Peter E; Cada, Glenn F; Bevelhimer, Mark S

    2012-03-01

    There is considerable interest in the development of marine and hydrokinetic energy projects in rivers, estuaries, and coastal ocean waters of the United States. Hydrokinetic (HK) technologies convert the energy of moving water in river or tidal currents into electricity, without the impacts of dams and impoundments associated with conventional hydropower or the extraction and combustion of fossil fuels. The Federal Energy Regulatory Commission (FERC) maintains a database that displays the geographical distribution of proposed HK projects in inland and tidal waters (FERC 2012). As of March 2012, 77 preliminary permits had been issued to private developers to study HK projects in inland waters, the development of which would total over 8,000 MW. Most of these projects are proposed for the lower Mississippi River. In addition, the issuance of another 27 preliminary permits for HK projects in inland waters, and 3 preliminary permits for HK tidal projects (totaling over 3,100 MW) were under consideration by FERC. Although numerous HK designs are under development (see DOE 2009 for a description of the technologies and their potential environmental effects), the most commonly proposed current-based projects entail arrays of rotating devices, much like submerged wind turbines, that are positioned in the high-velocity (high energy) river channels. The many diverse HK designs imply a diversity of environmental impacts, but a potential impact common to most is the risk for blade strike to aquatic organisms. In conventional hydropower generation, research on fish passage through reaction turbines at low-head dams suggested that strike and mortality for small fish could be low. As a consequence of the large surface area to mass ratio of small fish, the drag forces in the boundary layer flow at the surface of a rotor blade may pull small fish around the leading edge of a rotor blade without making physical contact (Turnpenny 1998, Turnpenny et al. 2000). Although there is

  12. Modeling Techniques Used to Analyze Safety of Payloads for Generic Missile Type Weapons Systems During an Indirect Lightning Strike

    SciTech Connect (OSTI)

    Perkins, M P; Ong, M M; Crull, E W; Brown Jr., C G

    2009-07-21

    During lightning strikes buildings and other structures can act as imperfect Faraday Cages, enabling electromagnetic fields to be developed inside the facilities. Some equipment stored inside these facilities may unfortunately act as antenna systems. It is important to have techniques developed to analyze how much voltage, current, or energy dissipation may be developed over valuable components. In this discussion we will demonstrate the modeling techniques used to accurately analyze a generic missile type weapons system as it goes through different stages of assembly. As work is performed on weapons systems detonator cables can become exposed. These cables will form different monopole and loop type antenna systems that must be analyzed to determine the voltages developed over the detonator regions. Due to the low frequencies of lightning pulses, a lumped element circuit model can be developed to help analyze the different antenna configurations. We will show an example of how numerical modeling can be used to develop the lumped element circuit models used to calculate voltage, current, or energy dissipated over the detonator region of a generic missile type weapons system.

  13. Combining Turbine Blade-Strike and Life Cycle Models to Assess Mitigation Strategies for Fish Passing Dams

    SciTech Connect (OSTI)

    Ferguson, John W.; Ploskey, Gene R.; Leonardsson, Kjell; Zabel, Richard W.; Lundqvist, Hans

    2008-08-01

    Combining the two models produced a rapid, cost effective tool for assessing dam passage impacts to fish populations and prioritizing among mitigation strategies for conserving fish stocks in regulated rivers. Estimated mortality of juvenile and adult Atlantic salmon (Salmo salar) and sea trout (S. trutta) passing turbines at two dams in northern Sweden was significantly higher for Kaplan turbines compared to Francis turbines, and for adult fish compared to juveniles based on blade strike models. Mean probability of mortality ranged from 6.7% for salmon smolts passing Francis turbines to >100% for adult salmon passing Kaplan turbines. Life cycle modeling allowed benefits to be assessed for three alternatives that mitigated this mortality. Salmon population responses varied considerably among alternatives and rivers: growth rates improved as much as 17.9%, female escapements increased up to 669%, and more than 1,300 additional female salmon were produced in one case. Protecting both smolts and adults provided benefits, and in one river, mitigating turbine mortality alone was estimated to have met the production capacity of the available habitat.

  14. Go for the Gold in Energy-Efficient Home Heating | Department...

    Broader source: Energy.gov (indexed) [DOE]

    in the crowd and the athletes as they vie for the coveted gold, silver, and bronze metals. ... Energy Department Resources Go for the Gold and Save Energy at Home 15 Blog Posts to ...

  15. OSTIblog Articles in the gold mine Topic | OSTI, US Dept of Energy...

    Office of Scientific and Technical Information (OSTI)

    gold mine Topic Mining for Gold, Neutrinos and the Neutrinoless Double Beta Decay by Kathy Chambers 23 Sep, 2014 in Deep within the caverns of Lead, South Dakota is one of the ...

  16. Time-dependent Protein-directed Growth of Gold Nanoparticles within a Single Crystal of Lysozyme

    SciTech Connect (OSTI)

    H Wei; Z Wang; J Zhang; S House; Y Gao; L Yang; H Robinson; L Tan; H Xing; C Hou

    2011-12-31

    Gold nanoparticles are useful in biomedical applications due to their distinct optical properties and high chemical stability. Reports of the biogenic formation of gold colloids from gold complexes has also led to an increased level of interest in the biomineralization of gold. However, the mechanism responsible for biomolecule-directed gold nanoparticle formation remains unclear due to the lack of structural information about biological systems and the fast kinetics of biomimetic chemical systems in solution. Here we show that intact single crystals of lysozyme can be used to study the time-dependent, protein-directed growth of gold nanoparticles. The protein crystals slow down the growth of the gold nanoparticles, allowing detailed kinetic studies to be carried out, and permit a three-dimensional structural characterization that would be difficult to achieve in solution. Furthermore, we show that additional chemical species can be used to fine-tune the growth rate of the gold nanoparticles.

  17. Prof. Héctor Abruña wins Electrochimica Acta Gold Medal award...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hctor Abrua wins Electrochimica Acta Gold Medal award June 30th, 2016 Dr. Hctor Abrua is the most recent winner of the Electrochimica Acta Gold Medal, which is given ...

  18. Gold-rich R3Au7Sn3: Establishing the interdependence between...

    Office of Scientific and Technical Information (OSTI)

    Gold-rich R3Au7Sn3: Establishing the interdependence between electronic features and physical properties Citation Details In-Document Search Title: Gold-rich R3Au7Sn3: Establishing ...

  19. Method for forming gold-containing catalyst with porous structure

    DOE Patents [OSTI]

    Biener, Juergen; Hamza, Alex V; Baeumer, Marcus; Schulz, Christian; Jurgens, Birte; Biener, Monika M.

    2014-07-22

    A method for forming a gold-containing catalyst with porous structure according to one embodiment of the present invention includes producing a starting alloy by melting together of gold and at least one less noble metal that is selected from the group consisting of silver, copper, rhodium, palladium, and platinum; and a dealloying step comprising at least partial removal of the less noble metal by dissolving the at least one less noble metal out of the starting alloy. Additional methods and products thereof are also presented.

  20. DOE - Office of Legacy Management -- Humphreys Gold Co - FL 08

    Office of Legacy Management (LM)

    Humphreys Gold Co - FL 08 FUSRAP Considered Sites Site: Humphreys Gold Co. (FL.08 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Jacksonville , Florida FL.08-1 Evaluation Year: 1987 FL.08-2 FL.08-3 Site Operations: Processed monazite ore in the 1950s. FL.08-3 Site Disposition: Eliminated - No Authority - No AEC involvement at the site FL.08-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Thorium FL.08-1

  1. World's largest single crystal of gold verified by Los Alamos instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos verifies largest single gold crystal World's largest single crystal of gold verified by Los Alamos instruments Using Lujan Center's HIPPO instrument, researchers probed the specimen with neutrons to gather critical information December 22, 2014 World's largest single crystal of gold verified by Los Alamos instruments Neutron diffraction data collected on the single-crystal diffraction (SCD) instrument at the Lujan Center, from the Venezuelan gold sample, indicate that the sample is a

  2. Coated Gold Nanoparticles Found to be Speedy Electron Sponges | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Coated Gold Nanoparticles Found to be Speedy Electron Sponges Gold-coated nanoparticles capture electrons at an unprecedented rate in solution. Gold nanoparticles demonstrate the potential to quench radiation-induced electrons, indicating potential applications ranging from heterogeneous catalysis to conversion of the radiation into electricity. Green chemistry methods were used to coat the gold nanoparticles in a chloride compound known as bac-14. The coat does not stick to the

  3. Penetration Experiments with 6061-T6511 Aluminum Targets and Spherical-Nose Steel Projectiles at Striking Velocities Between 0.5 and 3.0 km/s

    SciTech Connect (OSTI)

    Forrestal, M.J.; Piekutowski, A.J.

    1999-02-04

    We conducted depth of penetration experiments with 7.11-mm-diameter, 74.7-mm-long, spherical-nose, 4340 steel projectiles launched into 250-mm-diameter, 6061-T6511 aluminum targets. To show the effect of projectile strength, we used projectiles that had average Rockwell harnesses of R{sub c} = 36.6, 39.5, and 46.2. A powder gun and two-stage, light-gas guns launched the 0.023 kg projectiles at striking velocities between 0.5 and 3.0 km/s. Post-test radiographs of the targets showed three response regions as striking velocities increased: (1) the projectiles remained visibly undeformed, (2) the projectiles permanently deformed without erosion, and (3) the projectiles eroded and lost mass. To show the effect of projectile strength, we compared depth-of-penetration data as a function of striking velocity for spherical-nose rods with three Rockwell harnesses at striking velocities ranging from 0.5 to 3.0 km/s. To show the effect of nose shape, we compared penetration data for the spherical-nose projectiles with previously published data for ogive-nose projectiles.

  4. Alignment of gold nanorods by angular photothermal depletion

    SciTech Connect (OSTI)

    Taylor, Adam B.; Chow, Timothy T. Y.; Chon, James W. M.

    2014-02-24

    In this paper, we demonstrate that a high degree of alignment can be imposed upon randomly oriented gold nanorod films by angular photothermal depletion with linearly polarized laser irradiation. The photothermal reshaping of gold nanorods is observed to follow quadratic melting model rather than the threshold melting model, which distorts the angular and spectral hole created on 2D distribution map of nanorods to be an open crater shape. We have accounted these observations to the alignment procedures and demonstrated good agreement between experiment and simulations. The use of multiple laser depletion wavelengths allowed alignment criteria over a large range of aspect ratios, achieving 80% of the rods in the target angular range. We extend the technique to demonstrate post-alignment in a multilayer of randomly oriented gold nanorod films, with arbitrary control of alignment shown across the layers. Photothermal angular depletion alignment of gold nanorods is a simple, promising post-alignment method for creating future 3D or multilayer plasmonic nanorod based devices and structures.

  5. PROCESS FOR THE CONCENTRATION OF ORES CONTAINING GOLD AND URANIUM

    DOE Patents [OSTI]

    Gaudin, A.M.; Dasher, J.

    1958-06-10

    ABS>A process is described for concentrating certain low grade uranium and gold bearing ores, in which the gangue is mainly quartz. The production of the concentrate is accomplished by subjecting the crushed ore to a froth floatation process using a fatty acid as a collector in conjunction with a potassium amyl xanthate collector. Pine oil is used as the frothing agent.

  6. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution Print For the first time, a team of scientists led by Roger Kornberg has synthesized thiol-covered gold nanoparticles and, using ALS Beamlines 5.0.2 and 8.2.2 and SSRL Beamlines 11-1 and 11-3, conclusively ascertained their atomic structure (at 1.1 Å resolution). The gold-thiol nanoparticle consists of 102 gold atoms surrounded by 44 molecules of a thiol compound (para-mercaptobenzoic acid, or p-MBA). The central gold atoms

  7. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution Print For the first time, a team of scientists led by Roger Kornberg has synthesized thiol-covered gold nanoparticles and, using ALS Beamlines 5.0.2 and 8.2.2 and SSRL Beamlines 11-1 and 11-3, conclusively ascertained their atomic structure (at 1.1 Å resolution). The gold-thiol nanoparticle consists of 102 gold atoms surrounded by 44 molecules of a thiol compound (para-mercaptobenzoic acid, or p-MBA). The central gold atoms

  8. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution Print For the first time, a team of scientists led by Roger Kornberg has synthesized thiol-covered gold nanoparticles and, using ALS Beamlines 5.0.2 and 8.2.2 and SSRL Beamlines 11-1 and 11-3, conclusively ascertained their atomic structure (at 1.1 Å resolution). The gold-thiol nanoparticle consists of 102 gold atoms surrounded by 44 molecules of a thiol compound (para-mercaptobenzoic acid, or p-MBA). The central gold atoms

  9. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution Print For the first time, a team of scientists led by Roger Kornberg has synthesized thiol-covered gold nanoparticles and, using ALS Beamlines 5.0.2 and 8.2.2 and SSRL Beamlines 11-1 and 11-3, conclusively ascertained their atomic structure (at 1.1 Å resolution). The gold-thiol nanoparticle consists of 102 gold atoms surrounded by 44 molecules of a thiol compound (para-mercaptobenzoic acid, or p-MBA). The central gold atoms

  10. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution Print For the first time, a team of scientists led by Roger Kornberg has synthesized thiol-covered gold nanoparticles and, using ALS Beamlines 5.0.2 and 8.2.2 and SSRL Beamlines 11-1 and 11-3, conclusively ascertained their atomic structure (at 1.1 Å resolution). The gold-thiol nanoparticle consists of 102 gold atoms surrounded by 44 molecules of a thiol compound (para-mercaptobenzoic acid, or p-MBA). The central gold atoms

  11. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution Print Wednesday, 28 May 2008 00:00 For the first time, a team of scientists led by Roger Kornberg has synthesized thiol-covered gold nanoparticles and, using ALS Beamlines 5.0.2 and 8.2.2 and SSRL Beamlines 11-1 and 11-3, conclusively ascertained their atomic structure (at 1.1 Å resolution). The gold-thiol nanoparticle consists of 102 gold atoms

  12. THE STRIKINGLY SIMILAR RELATION BETWEEN SATELLITE AND CENTRAL GALAXIES AND THEIR DARK MATTER HALOS SINCE z = 2

    SciTech Connect (OSTI)

    Watson, Douglas F.; Conroy, Charlie

    2013-08-01

    speculate that the striking similarity between the satellite and central galaxy M{sub *}-M{sub h} relations since z {approx} 2 arises because the central galaxy relation evolves very weakly with time and because the stellar mass of the typical satellite galaxy has not changed significantly since it was accreted. The reason for this last point is not yet entirely clear, but it is likely related to the fact that the typical {approx}L* satellite galaxy resides in a poor group where transformation processes are weak and lifetimes are short.

  13. Gold-based electrical interconnections for microelectronic devices

    DOE Patents [OSTI]

    Peterson, Kenneth A.; Garrett, Stephen E.; Reber, Cathleen A.; Watson, Robert D.

    2002-01-01

    A method of making an electrical interconnection from a microelectronic device to a package, comprising ball or wedge compression bonding a gold-based conductor directly to a silicon surface, such as a polysilicon bonding pad in a MEMS or IMEMS device, without using layers of aluminum or titanium disposed in-between the conductor and the silicon surface. After compression bonding, optional heating of the bond above 363 C. allows formation of a liquid gold-silicon eutectic phase containing approximately 3% (by weight) silicon, which significantly improves the bond strength by reforming and enhancing the initial compression bond. The same process can be used for improving the bond strength of Au--Ge bonds by forming a liquid Au-12Ge eutectic phase.

  14. Electron energy loss spectroscopy of gold nanoparticles on graphene

    SciTech Connect (OSTI)

    DeJarnette, Drew; Roper, D. Keith

    2014-08-07

    Plasmon excitation decay by absorption, scattering, and hot electron transfer has been distinguished from effects induced by incident photons for gold nanoparticles on graphene monolayer using electron energy loss spectroscopy (EELS). Gold nano-ellipses were evaporated onto lithographed graphene, which was transferred onto a silicon nitride transmission electron microscopy grid. Plasmon decay from lithographed nanoparticles measured with EELS was compared in the absence and presence of the graphene monolayer. Measured decay values compared favorably with estimated radiative and non-radiative contributions to decay in the absence of graphene. Graphene significantly enhanced low-energy plasmon decay, increasing mode width 38%, but did not affect higher energy plasmon or dark mode decay. This decay beyond expected radiative and non-radiative mechanisms was attributed to hot electron transfer, and had quantum efficiency of 20%, consistent with previous reports.

  15. Nanoporous Gold as a Platform for a Building Block Catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

    2012-09-25

    The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporousmore » gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.« less

  16. Nanoporous Gold as a Platform for a Building Block Catalyst

    SciTech Connect (OSTI)

    Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

    2012-09-25

    The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporous gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.

  17. Method of making gold thiolate and photochemically functionalized microcantilevers

    DOE Patents [OSTI]

    Boiadjiev, Vassil I [Knoxville, TN; Brown, Gilbert M [Knoxville, TN; Pinnaduwage, Lal A [Knoxville, TN; Thundat, Thomas G [Knoxville, TN; Bonnesen, Peter V [Knoxville, TN; Goretzki, Gudrun [Nottingham, GB

    2009-08-25

    Highly sensitive sensor platforms for the detection of specific reagents, such as chromate, gasoline and biological species, using microcantilevers and other microelectromechanical systems (MEMS) whose surfaces have been modified with photochemically attached organic monolayers, such as self-assembled monolayers (SAM), or gold-thiol surface linkage are taught. The microcantilever sensors use photochemical hydrosilylation to modify silicon surfaces and gold-thiol chemistry to modify metallic surfaces thereby enabling individual microcantilevers in multicantilever array chips to be modified separately. Terminal vinyl substituted hydrocarbons with a variety of molecular recognition sites can be attached to the surface of silicon via the photochemical hydrosilylation process. By focusing the activating UV light sequentially on selected silicon or silicon nitride hydrogen terminated surfaces and soaking or spotting selected metallic surfaces with organic thiols, sulfides, or disulfides, the microcantilevers are functionalized. The device and photochemical method are intended to be integrated into systems for detecting specific agents including chromate groundwater contamination, gasoline, and biological species.

  18. Idaho National Engineering and Environmental Laboratory Awarded VPP Gold Star

    Broader source: Energy.gov [DOE]

    Our journey to safety excellence began some six (6) years ago. The task seemed ominous with 6000 plus employees ranging from administrative assistants and craftsman to research scientists and engineers. Another challenge was the geographic dispersion of work areas being as much as 50 miles apart. A core group of employees caught the vision and knew that it could be done, and it is that perseverance that has lead the INEEL to the DOE-VPP Gold Star.

  19. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Print Nanoparticles-man-made atoms with unique optical, electrical, and mechanical properties-have become key components in many fields of science. If nanoparticles could be coaxed into routinely assembling themselves into predictable complex structures and hierarchical patterns, devices could be mass-produced that are one thousand times smaller than today's microtechnologies. Berkeley Lab and UC Berkeley scientists have made progress toward this goal,

  20. Michael Hickman receives NNSA Gold Medal, announces retirement | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration | (NNSA) Michael Hickman receives NNSA Gold Medal, announces retirement Thursday, May 28, 2015 - 9:21am NNSA's Director of the Office of Enterprise Project Management Michael Hickman has announced that he will be retiring effective May 29, 2015 after 34 years distinguished federal service. As a member of the Senior Executive Service, he has spent approximately 25 of those years in senior leadership positions across DOE and NNSA. In his current capacity,

  1. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Print Nanoparticles-man-made atoms with unique optical, electrical, and mechanical properties-have become key components in many fields of science. If nanoparticles could be coaxed into routinely assembling themselves into predictable complex structures and hierarchical patterns, devices could be mass-produced that are one thousand times smaller than today's microtechnologies. Berkeley Lab and UC Berkeley scientists have made progress toward this goal,

  2. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Print Nanoparticles-man-made atoms with unique optical, electrical, and mechanical properties-have become key components in many fields of science. If nanoparticles could be coaxed into routinely assembling themselves into predictable complex structures and hierarchical patterns, devices could be mass-produced that are one thousand times smaller than today's microtechnologies. Berkeley Lab and UC Berkeley scientists have made progress toward this goal,

  3. Guided Self-Assembly of Gold Thin Films

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guided Self-Assembly of Gold Thin Films Print Nanoparticles-man-made atoms with unique optical, electrical, and mechanical properties-have become key components in many fields of science. If nanoparticles could be coaxed into routinely assembling themselves into predictable complex structures and hierarchical patterns, devices could be mass-produced that are one thousand times smaller than today's microtechnologies. Berkeley Lab and UC Berkeley scientists have made progress toward this goal,

  4. Gold Binding by Native and Chemically Modified Hops Biomasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    López, M. Laura; Gardea-Torresdey, J. L.; Peralta-Videa, J. R.; de la Rosa, G.; Armendáriz, V.; Herrera, I.; Troiani, H.; Henning, J.

    2005-01-01

    Heavy metals from mining, smelting operations and other industrial processing facilities pollute wastewaters worldwide. Extraction of metals from industrial effluents has been widely studied due to the economic advantages and the relative ease of technical implementation. Consequently, the search for new and improved methodologies for the recovery of gold has increased. In this particular research, the use of cone hops biomass ( Humulus lupulus ) was investigated as a new option for gold recovery. The results showed that the gold binding to native hops biomass was pH dependent from pH 2 to pH 6, with a maximum percentage bindingmore » at pH 3. Time dependency studies demonstrated that Au(III) binding to native and modified cone hops biomasses was found to be time independent at pH 2 while at pH 5, it was time dependent. Capacity experiments demonstrated that at pH 2, esterified hops biomass bound 33.4 mg Au/g of biomass, while native and hydrolyzed hops biomasses bound 28.2 and 12.0 mg Au/g of biomass, respectively. However, at pH 5 the binding capacities were 38.9, 37.8 and 11.4 mg of Au per gram of native, esterified and hydrolyzed hops biomasses, respectively.« less

  5. Field effect on digestive ripening of thiol-capped gold nanoparticles

    SciTech Connect (OSTI)

    Lin, Meng-Lin; Peng, J. S.; Lee, Sanboh; Yang, Fuqian

    2014-02-07

    We studied the digestive ripening of thiol-capped gold nanoparticles under simultaneous action of electric field and reflux heating in a silicone oil bath at 130 °C, using transmission electron microscopy. Observation revealed that a polydispersed gold nanoparticle system reached the state of nearly monodispersity under the action of an electric field and the thiol-capped gold nanoparticles carried negative charges. The electric field caused the increase of the particle size for the nearly monodispersed gold nanoparticle system. The self-assembly of the nearly monodisperse gold nanoparticles under the action of an electric field of a high field intensity was observed. The gold nanoparticles tended to form self-assembled nanostructures of six-fold symmetry. This study provides a new route for system engineering to control the particle size of metallic nanoparticles by electric field and digestive ripening.

  6. The Structure of Interfacial Water on Gold Electrodes Studied by X-ray

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Absorption Spectroscopy - Joint Center for Energy Storage Research October 23, 2014, Research Highlights The Structure of Interfacial Water on Gold Electrodes Studied by X-ray Absorption Spectroscopy Schematic representation of X-ray absorption measurements at the biased gold water interface. X-rays arrive from the left and transmit through a thin silicon nitride window plated with gold. Fluorescence provides information far from the interface while it was discovered that electron yield is

  7. Electrocatalysts having gold monolayers on platinum nanoparticle cores, and uses thereof

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang

    2010-04-27

    The invention relates to gold-coated particles useful as fuel cell electrocatalysts. The particles are composed of an electrocatalytically active core at least partially encapsulated by an outer shell of gold or gold alloy. The invention more particularly relates to such particles having a noble metal-containing core, and more particularly, a platinum or platinum alloy core. In other embodiments, the invention relates to fuel cells containing these electrocatalysts and methods for generating electrical energy therefrom.

  8. Spectroscopic study of gold nanoparticle formation through high intensity laser irradiation of solution

    SciTech Connect (OSTI)

    Nakamura, Takahiro Sato, Shunichi; Herbani, Yuliati; Ursescu, Daniel; Banici, Romeo; Dabu, Razvan Victor

    2013-08-15

    A spectroscopic study of the gold nanoparticle (NP) formation by high-intensity femtosecond laser irradiation of a gold ion solution was reported. The effect of varying energy density of the laser on the formation of gold NPs was also investigated. The surface plasmon resonance (SPR) peak of the gold nanocolloid in real-time UV-visible absorption spectra during laser irradiation showed a distinctive progress; the SPR absorption peak intensity increased after a certain irradiation time, reached a maximum and then gradually decreased. During this absorption variation, at the same time, the peak wavelength changed from 530 to 507 nm. According to an empirical equation derived from a large volume of experimental data, the estimated mean size of the gold NPs varied from 43.4 to 3.2 nm during the laser irradiation. The mean size of gold NPs formed at specific irradiation times by transmission electron microscopy showed the similar trend as that obtained in the spectroscopic analysis. From these observations, the formation mechanism of gold NPs during laser irradiation was considered to have two steps. The first is a reduction of gold ions by reactive species produced through a non-linear reaction during high intensity laser irradiation of the solution; the second is the laser fragmentation of produced gold particles into smaller pieces. The gold nanocolloid produced after the fragmentation by excess irradiation showed high stability for at least a week without the addition of any dispersant because of the negative charge on the surface of the nanoparticles probably due to the surface oxidation of gold nanoparticles. A higher laser intensity resulted in a higher efficiency of gold NPs fabrication, which was attributed to a larger effective volume of the reaction.

  9. Growth of solid and hollow gold particles through the thermal annealing of nanoscale patterned thin films

    SciTech Connect (OSTI)

    Lin, Junhao; He, Weidong; Vilayur Ganapathy, Subramanian; Peppernick, Samuel J.; Wang, Bin; Palepu, Sandeep; Remec, Miroslav; Hess, Wayne P.; Hmelo, Anthony B.; Pantelides, Sokrates T.; Dickerson, James

    2013-11-27

    Through thermally annealing well-arrayed, circular, nanoscale thin films of gold, deposited onto [111] silicon/silicon dioxide substrates, both solid and hollow gold particles of different morphologies with controllable sizes were obtained. The thin film could form individual particle or clusters of particles by tuning the diameter of it. Hollow gold particles were featured by their large size whose diameter was larger than 500 nm and confirmed by a cross-section view. Hollow gold particles show greater plasmonic field enhancement under photoemission electron microscopy. Potential growth mechanisms for these structures are explored

  10. Department of Energy - Gold Award Press Release 9/10/2003

    Office of Scientific and Technical Information (OSTI)

    Francis Collins and Ari Patrinos Receive Energy Secretary's Gold Award for Human Genome Project Leadership September 10, 2003 WASHINGTON, DC -- Secretary of Energy Spencer Abraham ...

  11. Structural Analysis for Gold Mineralization Using Remote Sensing and Geochemical Techniques in a GIS Environment: Island of Lesvos, Hellas

    SciTech Connect (OSTI)

    Rokos, D. Argialas, D. Mavrantza, R. St Seymour, K.; Vamvoukakis, C.; Kouli, M.; Lamera, S.; Paraskevas, H.; Karfakis, I.; Denes, G

    2000-12-15

    Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field data (dip and strike measurements of faults, joints, and veins), respectively. The derived lineament map and the band ratio images were manipulated in a GIS environment, in order to study the relation of the tectonic pattern to both the alteration zoning and the geomorphology of the volcanic field of the study area. Target areas of high interest for possible mineralization also were specified using geochemical techniques, such as X-Ray Diffraction (XRD) analysis, trace-element, and fluid-inclusion analysis. Finally, preliminary conclusions were derived about possible mineralization, the type (high or low sulfidation), and the extent of mineralization, by combining the structural information with geochemical information.

  12. High pressure melting curves of silver, gold and copper

    SciTech Connect (OSTI)

    Hieu, Ho Khac

    2013-11-15

    In this work, based on the Lindemann's formula of melting and the pressure-dependent Grüneisen parameter, we have investigated the pressure effect on melting temperature of silver, gold and copper metals. The analytical expression of melting temperature as a function of volume compression has been derived. Our results are compared with available experimental data as well as with previous theoretical studies and the good and reasonable agreements are found. We also proposed the potential of this approach on predicting melting of copper at very high pressure.

  13. Hydroxyalkyl phosphine gold complexes for use as diagnostic and therapeutic pharmaceuticals and method of making same

    DOE Patents [OSTI]

    Katti, K.V.; Berning, D.E.; Volkert, W.A.; Ketring, A.R.

    1998-12-01

    A complex and method for making a diagnostic or therapeutic pharmaceutical includes a ligand comprising at least one hydroxyalkyl phosphine donor group bound to a gold atom to form a gold-ligand complex that is stable in aqueous solutions containing oxygen, serum and other body fluids. 20 figs.

  14. Hydroxyalkyl phosphine gold complexes for use as diagnostic and therapeutic pharmaceuticals and method of making same

    DOE Patents [OSTI]

    Katti, Kattesh V.; Berning, Douglas E.; Volkert, Wynn A.; Ketring, Alan R.

    1998-01-01

    A complex and method for making same for use as a diagnostic or therapeutic pharmaceutical includes a ligand comprising at least one hydroxyalkyl phosphine donor group bound to a gold atom to form a gold-ligand complex that is stable in aqueous solutions containing oxygen, serum and other body fluids.

  15. Synthesis and characterization of mixed monolayer protected gold nanorods and their Raman activities

    SciTech Connect (OSTI)

    Mlambo, Mbuso; Mdluli, Phumlani S.; Shumbula, Poslet; Mpelane, Siyasanga; Moloto, Nosipho; Skepu, Amanda; Tshikhudo, Robert

    2013-10-15

    Graphical abstract: Gold nanorods surface functionalization. - Highlights: • Mixed monolayer protected gold nanorods. • Surface enhanced Raman spectroscopy. • HS-(CH{sub 2}){sub 11}-NHCO-coumarin as a Raman active compound. - Abstract: The cetyltrimethylammonium bromide (CTAB) gold nanorods (AuNRs) were prepared by seed-mediated route followed by the addition of a Raman active compound (HS-(CH{sub 2}){sub 11}-NHCO-coumarin) on the gold nanorods surfaces. Different stoichiometric mixtures of HS-(CH{sub 2}){sub 11}-NHCO-coumarin and HS-PEG-(CH{sub 2}){sub 11}COOH were evaluated for their Raman activities. The lowest stoichiometric ratio HS-(CH{sub 2}){sub 11}-NHCO-coumarin adsorbed on gold nanorods surface was detected and enhanced by Raman spectroscopy. The produced mixed monolayer protected gold nanorods were characterized by UV-vis spectrometer for optical properties, transmission electron microscope (TEM) for structural properties (shape and aspect ratio) and their zeta potentials (charges) were obtained from ZetaSizer to determine the stability of the produced mixed monolayer protected gold nanorods. The Raman results showed a surface enhanced Raman scattering (SERS) enhancement at the lowest stoichiometric ratio of 1% HS-(CH{sub 2}){sub 11}-NHCO-coumarin compared to high ratio of 50% HS-(CH{sub 2}){sub 11}-NHCO-coumarin on the surface of gold nanorods.

  16. Gold Medal Approaches for Obtaining and Using Energy Efficiency Data (101)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Gold Medal Approaches for Obtaining and Using Energy Efficiency Data (101) Gold Medal Approaches for Obtaining and Using Energy Efficiency Data (101) August 11, 2016 1:00PM to 2:30PM EDT Learn more and register.

  17. Synthesis and characterization of polyaniline coated gold nanocomposites

    SciTech Connect (OSTI)

    Zuber, Siti Nurzulaiha Mohd; Kamarun, Dzaraini; Zaki, Hamizah; Kamarudin, Mohamad Shukri; Thomas, Sabu; Kalarikkal, Nandakumar

    2015-08-28

    Considerable attention has been drawn during the last two decades to prepare nanocomposites consists of conducting polymer and noble metal due to their potential ability to generate a new class of material with novel optical, chemical, electronic or mechanical properties for various applications. In this work, an attempt has been made to synthesize nanocomposite of polyaniline (PANI) coated with gold nanoparticles (AuNPs) chemically with various types of surfactants such as polyvinylpyrrolidone (PVP), and sodium dodecyl sulphate (SDS) which act as stabilizing agents to help in stabilization of the PANI/Gold nanocomposites system. The synthesized nanocomposites were characterized by UV-Visible, field emission scanning electron microscope (FESEM) and particle size analyzer (PSA). The formation of finger like structure can be seen in the FESEM images when the AuNPs were incorporated into the polymer matrix. The EDX data showed that 18.66% and 12.67% of AuNPs atoms were present in the composite system thus proved the incorporation of AuNPs into the polymer matrix. A small red shift of the absorption peak in the UV-Vis of both PANI/AuNPs composites system may be due to the incorporation of AuNPs in the PANI matrix.

  18. Ultrafast Imaging of Surface Plasmons Propagating on a Gold Surface

    SciTech Connect (OSTI)

    Gong, Yu; Joly, Alan G.; Hu, Dehong; El-Khoury, Patrick Z.; Hess, Wayne P.

    2015-05-13

    We record time-resolved nonlinear photoemission electron microscopy (tr-PEEM) images of propagating surface plasmons (PSPs) launched from a lithographically patterned rectangular trench on a flat gold surface. Our tr-PEEM scheme involves a pair of identical, spatially separated, and interferometrically-locked femtosecond laser pulses. Power dependent PEEM images provide experimental evidence for a sequential coherent nonlinear photoemission process, in which one laser source creates a PSP polarization state through a linear interaction, and the second subsequently probes the prepared state via two photon photoemission. The recorded time-resolved movies of a PSP allow us to directly measure various properties of the surface-bound wave packet, including its carrier wavelength (785 nm) and group velocity (0.95c). In addition, tr-PEEM in concert with finite-difference time domain simulations together allow us to set a lower limit of 75 μm for the decay length of the PSP on a 100 nm thick gold film.

  19. Probing the thiol-gold planar interface by spin polarized tunneling

    SciTech Connect (OSTI)

    Zhang, Xiaohang; McGill, Stephen A.; Xiong, Peng; Wang, Xiaolei; Zhao, Jianhua

    2014-04-14

    Reports of induced magnetism at thiol-gold interface have generated considerable recent interest. In these studies, the sample magnetization was generally measured by superconducting quantum interference device magnetometry which has limitation in determining surface and interface magnetism. In this work, we have fabricated planar tunnel junctions incorporating a thiol-gold interface. An observed room temperature humidity effect together with low temperature inelastic electron tunneling spectroscopy confirmed the existence of a thiol-gold interface in the organic-inorganic hybrid heterostructure. Spin polarized tunneling measurements were performed to probe the spin polarization at the thiol-gold interface; however, the obtained spin polarized tunneling spectra indicate no measurable spin polarization at the thiol-gold interface.

  20. Thermal properties of holmium-implanted gold films for a neutrino mass experiment with cryogenic microcalorimeters

    SciTech Connect (OSTI)

    Prasai, K.; Yanardag, S. Basak; Galeazzi, M.; Uprety, Y.; Alves, E.; Rocha, J.; Bagliani, D.; Biasotti, M.; Gatti, F.; Gomes, M. Ribeiro

    2013-08-15

    In a microcalorimetric neutrino mass experiment using the radioactive decay of {sup 163}Ho, the radioactive material must be fully embedded in the microcalorimeter absorber. One option that is being investigated is to implant the radioactive isotope into a gold absorber, as gold is successfully used in other applications. However, knowing the thermal properties at the working temperature of microcalorimeters is critical for choosing the absorber material and for optimizing the detector performance. In particular, it is paramount to understand if implanting the radioactive material in gold changes its heat capacity. We used a bolometric technique to measure the heat capacity of gold films, implanted with various concentrations of holmium and erbium (a byproduct of the {sup 163}Ho fabrication), in the temperature range 70 mK–300 mK. Our results show that the specific heat capacity of the gold films is not affected by the implant, making this a viable option for a future microcalorimeter holmium experiment.

  1. Decoupling of epitaxial graphene via gold intercalation probed by dispersive Raman spectroscopy

    SciTech Connect (OSTI)

    Pillai, P. B. E-mail: m.desouza@sheffield.ac.uk; DeSouza, M. E-mail: m.desouza@sheffield.ac.uk; Narula, R.; Reich, S.; Wong, L. Y.; Batten, T.; Pokorny, J.

    2015-05-14

    Signatures of a superlattice structure composed of a quasi periodic arrangement of atomic gold clusters below an epitaxied graphene (EG) layer are examined using dispersive Raman spectroscopy. The gold-graphene system exhibits a laser excitation energy dependant red shift of the 2D mode as compared to pristine epitaxial graphene. The phonon dispersions in both the systems are mapped using the experimentally observed Raman signatures and a third-nearest neighbour tight binding electronic band structure model. Our results reveal that the observed excitation dependent Raman red shift in gold EG primarily arise from the modifications of the phonon dispersion in gold-graphene and shows that the extent of decoupling of graphene from the underlying SiC substrate can be monitored from the dispersive nature of the Raman 2D modes. The intercalated gold atoms restore the phonon band structure of epitaxial graphene towards free standing graphene.

  2. Strike variability of carbonate platform margin stratal architecture and cycle stacking patterns: Outcrop and seismic examples from lower Permian depositional sequences of the Permian Basin, U. S. A

    SciTech Connect (OSTI)

    Fitchen, W.M. )

    1996-01-01

    Strike variability in stratal architecture, cycle stacking patterns and facies differentiation within sequences exemplifies the potential for differential stratigraphic response of platforms to eustasy. Variability exists within base-level cycles of several scales within a compound stratigraphic hierarchy, though the causes may vary among different scales. Cross-sections from outcrops in the Sierra Diablo document the framework and stacking pattern of 3rd-order sequences (HFS), including: two progradational middle Wolfcampian HFS (mW1-2), one backstepped upper Wolfcampian HFS (uW1), one progradational lower Leonardin HFS (L1), aggradational middle (L2) and upper Leonardian HFS (L3), three progradatic upper Leonardian HFS (L4-6), and two backstepped, aggradational upper Leonardian HFS (L7-8). Seismic lines from the northern Delaware and Midland Basins and San Simon Channel area document the regional consistency of 3rd-order sequence stacking patterns (a response to eustasy), but show variability related to local subsidence, antecedent topography (owing to deeper structures and platform margin erosion), windward vs. leeward facing, and siliciclastic sediment supply. Sequences L2 and L3 appear to exhibit the greatest variability in stacking pattern. Strike variability in 4th/5th-order cycle stacking patterns within 3rd-order sequences as studied in outcrop is greatest in sequences L2 and L3, in which headland-bight margin trends are developed on a lateral scale of 1-2 miles. Aggrational to backstepping reef-margin facies with steep ([le]35[degrees]) foreslopes developed along headlands. Mudstones abut these margin facies abruptly along headlands and may contain megabreccias at the toe-of-slope. More gently sloping (10-15[degrees]) [open quotes]ramp[close quotes] margin strata composed of fusulinid packstones characterize bights.

  3. Modeling pore corrosion in normally open gold- plated copper connectors.

    SciTech Connect (OSTI)

    Battaile, Corbett Chandler; Moffat, Harry K.; Sun, Amy Cha-Tien; Enos, David George; Serna, Lysle M.; Sorensen, Neil Robert

    2008-09-01

    The goal of this study is to model the electrical response of gold plated copper electrical contacts exposed to a mixed flowing gas stream consisting of air containing 10 ppb H{sub 2}S at 30 C and a relative humidity of 70%. This environment accelerates the attack normally observed in a light industrial environment (essentially a simplified version of the Battelle Class 2 environment). Corrosion rates were quantified by measuring the corrosion site density, size distribution, and the macroscopic electrical resistance of the aged surface as a function of exposure time. A pore corrosion numerical model was used to predict both the growth of copper sulfide corrosion product which blooms through defects in the gold layer and the resulting electrical contact resistance of the aged surface. Assumptions about the distribution of defects in the noble metal plating and the mechanism for how corrosion blooms affect electrical contact resistance were needed to complete the numerical model. Comparisons are made to the experimentally observed number density of corrosion sites, the size distribution of corrosion product blooms, and the cumulative probability distribution of the electrical contact resistance. Experimentally, the bloom site density increases as a function of time, whereas the bloom size distribution remains relatively independent of time. These two effects are included in the numerical model by adding a corrosion initiation probability proportional to the surface area along with a probability for bloom-growth extinction proportional to the corrosion product bloom volume. The cumulative probability distribution of electrical resistance becomes skewed as exposure time increases. While the electrical contact resistance increases as a function of time for a fraction of the bloom population, the median value remains relatively unchanged. In order to model this behavior, the resistance calculated for large blooms has been weighted more heavily.

  4. Platinum atomic wire encapsulated in gold nanotubes: A first principle study

    SciTech Connect (OSTI)

    Nigam, Sandeep Majumder, Chiranjib; Sahoo, Suman K.; Sarkar, Pranab

    2014-04-24

    The nanotubes of gold incorporated with platinum atomic wire have been investigated by means of firstprinciples density functional theory with plane wave pseudopotential approximation. The structure with zig-zag chain of Pt atoms in side gold is found to be 0.73 eV lower in energy in comparison to straight chain of platinum atoms. The Fermi level of the composite tube was consisting of d-orbitals of Pt atoms. Further interaction of oxygen with these tubes reveals that while tube with zig-zag Pt prefers dissociative adsorption of oxygen molecule, the gold tube with linear Pt wire favors molecular adsorption.

  5. Seeded Growth of Monodisperse Gold Nanorods Using Bromide-Free Surfactant Mixtures

    SciTech Connect (OSTI)

    Ye, XC; Gao, YZ; Chen, J; Reifsnyder, DC; Zheng, C; Murray, CB

    2013-05-01

    We demonstrate for the first time that monodisperse gold nanorods (NRs) with broadly tunable dimensions and longitudinal surface plasmon resonances can be synthesized using a bromide-free surfactant mixture composed of alkyltrimethylammonium chloride and sodium oleate. It is found that uniform gold NRs can be obtained even with an iodide concentration approaching 100 mu M in the growth solution. In contrast to conventional wisdom, our results provide conclusive evidence that neither bromide as the surfactant counterion nor a high concentration of bromide ions in the growth solution is essential for gold NR formation. Correlated electron microscopy study of three-dimensional structures of gold NRs reveals a previously unprecedented octagonal prismatic structure enclosed predominantly by high index {310} crystal planes. These findings should have profound implications for a comprehensive mechanistic understanding of seeded growth of anisotropic metal nanocrystals.

  6. Polarization sensitivity of light diffraction for periodic array of anisotropic gold nanoparticles

    SciTech Connect (OSTI)

    Tsai, Ming-shan Liu, Tung-kai; Tsen, Chun-yu; Ting, Chen-ching

    2015-06-15

    This article aims to analyze the first order diffraction intensity of the incident polarized light which is diffracted by the gold nanoparticles array in terms of the surface plasmon effect. The inspected gold nanoparticles array films are built in grating pattern with stripe thickness of 4 μm and diameters of gold nanoparticles ca. 10–56 nm, which are formed by annealing at temperatures of 400, 450, 500, and 550 °C, respectively. The probing light is linearly polarized with wavelengths of 450–800 nm and counterclockwise turns its polarization direction from 0° to 90° during measurements. The results show that the diffraction intensity depends on the anisotropic configuration samples which gold nanoparticles are orientated by analyzing the scanning electron microscope images. It results that the localized surface plasmon effect induced by incident field depends on orientation and causes the sample polarization-sensitive.

  7. A gold hybrid structure as optical coupler for quantum well infrared photodetector

    SciTech Connect (OSTI)

    Ding, Jiayi; Li, Qian; Jing, Youliang; Chen, Xiaoshuang Li, Zhifeng; Li, Ning; Lu, Wei

    2014-08-28

    A hybrid structure consisting of a square lattice of gold disk arrays and an overlaying gold film is proposed as an optical coupler for a backside-illuminated quantum well infrared photodetector (QWIP). Finite difference time-domain method is used to numerically simulate the reflection spectra and the field distributions of the hybrid structure combined with the QWIP device. The results show that the electric field component perpendicular to the quantum well is strongly enhanced when the plasmonic resonant wavelength of the hybrid structure coincides with the response one of the quantum well infrared photodetector regardless of the polarization of the incident light. The effect of the diameter and thickness of an individual gold disk on the resonant wavelength is also investigated, which indicates that the localized surface plasmon also plays a role in the light coupling with the hybrid structure. The coupling efficiency can exceed 50 if the structural parameters of the gold disk arrays are well optimized.

  8. Imaging Isolated Gold Atom Catalytic Sites in Zeolite NaY

    SciTech Connect (OSTI)

    Lu, Jing; Aydin, C.; Browning, Nigel D.; Gates, Bruce C.

    2012-06-11

    Gold, the most stable metallic element, attracted wide attention as a catalyst only after the discovery that gold nanoclusters on oxide supports are highly active and selective for reactions including numerous oxidation,[1–8] hydrogenation,[9–11] hydroamination,[12, 13] ring expansion,[14, 15] and coupling[16, 17] reactions. The catalytic properties of supported gold strongly dependent on the gold–support interactions and the size of the active species, which must be small—typically clusters with diameters of the order of 1 nm.[18–20] Frequent discoveries of new gold-catalyzed reactions are leading the science; understanding has been slow to emerge.[21] Major challenges are to identify the catalytically active species and to characterize gold–support interactions.

  9. Solving the Unsovlable: The Nanostructure of Gold at 1.1 Å Resolution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Is it amorphous or composed of discrete atomic arrangements of uniform size and structure? ... The structure was then determined by x-ray diffraction. A gold-thiol megamolecule was ...

  10. A New Gold Pan For The West- Discovering Blind Geothermal Systems...

    Open Energy Info (EERE)

    Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: A...

  11. Substrate decomposition in galvanic displacement reaction: Contrast between gold and silver nanoparticle formation

    SciTech Connect (OSTI)

    Ghosh, Tapas; Satpati, Biswarup

    2015-06-24

    We have investigated substrate decomposition during formation of silver and gold nanoparticles in galvanic displacement reaction on germanium surfaces. Silver and gold nanoparticles were synthesized by electroless deposition on sputter coated germanium thin film (∼ 200 nm) grown initially on silicon substrate. The nanoparticles formation and the substrate corrosion were studied using scanning transmission electron microscopy (STEM) and the energy dispersive X-ray (EDX) spectroscopy.

  12. Experimental and theoretical realization of enhanced light scattering spectroscopy of gold nanorods

    SciTech Connect (OSTI)

    Li, Yunbo; Song, Linlin; Qiao, Yisha

    2015-01-12

    Assisted with transmission electron microscopy and extinction spectra, the enhanced light scattering (ELS) experiments were performed with gold nanoparticles. Although both the nanospheres and nanorods can enhance light scattering in study aggregation, the spectral characteristics of gold nanorods is relatively simple compared to that of nanospheres. This will further extend the application range of ELS method to determinate the amounts of inorganic ions in analytical field and investigate on the macromolecular aggregation in polymeric research due to its simplicity, rapidity, and sensitivity.

  13. Gold Nanoparticles Self-Similar Chain Structure Organized by DNA Origami

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gold Nanoparticles Self-Similar Chain Structure Organized by DNA Origami Authors: Ding, B., Deng, Z., Yan, H., Cabrini, S., Zukerman, R., and Boker, J. Title: Gold Nanoparticles Self-Similar Chain Structure Organized by DNA Origami Source: Journal of the American Chemical Society Year: 2010 Volume: 132 Pages: 3248-3249 ABSTRACT: Here we demonstrate Au nanoparticle self-similar chain structure organized by triangle DNA origami with well-controlled orientation and <10 nm spacing. We show for

  14. Improved thermal stability of oxide-supported naked gold nanoparticles by ligand-assisted pinning

    SciTech Connect (OSTI)

    Moreno, C; Divins, N. J.; Gazquez, Jaume; Varela, Maria; Angurell, I; Llorca, J

    2012-01-01

    We report a method to improve the thermal stability, up to 900 C, of bare-metal (naked) gold nanoparticles supported on top of SiO{sub 2} and SrTiO{sub 3} substrates via ligand-assisted pinning. This approach leads to monodisperse naked gold nanoparticles without significant sintering after thermal annealing in air at 900 C. The ligand-assisted pinning mechanism is described.

  15. Apex Gold discussion fosters international cooperation in run-up to 2016

    National Nuclear Security Administration (NNSA)

    Nuclear Security Summit | National Nuclear Security Administration | (NNSA) Apex Gold discussion fosters international cooperation in run-up to 2016 Nuclear Security Summit Monday, February 1, 2016 - 1:16pm NNSA Blog Participants in Apex Gold at Lawrence Livermore National Laboratory. What would national leaders do in the face of a transnational nuclear terrorism threat? Last week, ministers and other senior delegates from 37 nations, along with representatives from the International Atomic

  16. REEcyle Takes the Gold in the 2014 National Clean Energy Business Plan

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Competition | Department of Energy REEcyle Takes the Gold in the 2014 National Clean Energy Business Plan Competition REEcyle Takes the Gold in the 2014 National Clean Energy Business Plan Competition June 12, 2014 - 5:53pm Addthis The student startup, REEcycle, from the University of Houston swept this year's National Clean Energy Business Plan Competition, taking home all three awards for its innovative method of reclaiming rare earth elements from magnets in electronics. | Photo courtesy

  17. Electron-beam mapping of plasmon resonances in electromagnetically interacting gold nanorods

    SciTech Connect (OSTI)

    N'Gom, Moussa; Li Shuzhou; Schatz, George; Erni, Rolf; Agarwal, Ashish; Kotov, Nicholas; Norris, Theodore B.

    2009-09-15

    Electron energy-loss spectroscopy and energy-filtered transmission electron-microscope imaging are used to characterize the energy distribution of the surface plasmon of isolated and coupled gold nanorods. Local-field enhancement and spectral shift of the plasmon modes are observed for two interacting nanoparticles. The spatial modes measured by energy loss are shown to share qualitative similarities with the electromagnetic field distribution around gold nanorods induced by optical excitation as simulated using the discrete dipole-approximation method.

  18. Electronic Structure of Thiol-Covered Gold Nanoparticles: Au102(MBA)44 |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Structure of Thiol-Covered Gold Nanoparticles: Au102(MBA)44 Authors: Li, Y., Galli, G., and Gygi, F. We present first principles, density functional theory (DFT) calculations of the structural and electronic properties of thiolate-protected gold nanoparticles [Au102(MBA)44 ] that have been recently crystallized and measured by X-ray diffraction. Our calculations yield structural properties in very good agreement with experiment and reveal the impact of

  19. Measurement of gold nanofilm dose enhancement using unlaminated radiochromic film

    SciTech Connect (OSTI)

    Rakowski, Joseph T. Snyder, Michael G.; Hillman, Yair; Laha, Suvra S.; Lawes, Gavin; Buczek, Matthew G.; Tucker, Mark A.; Liu, Fangchao; Mao, Guangzhao

    2015-10-15

    Purpose: Bombarding high-Z material with x-ray radiation releases Auger electrons and Coster–Kronig electrons, along with deeper penetrating fluorescent x-rays and photoelectrons. The Auger and Coster–Kronig electron penetration distance is on the order of nanometers to micrometers in water or tissue, creating a large dose enhancement accompanied by a RBE greater than 1 at the cellular level. The authors’ aim is to measure the gold nanofilm dose enhancement factor (DEF) at the cellular level with unlaminated radiochromic film via primary 50 kVp tungsten x-ray spectrum interaction, similar to an electronic brachytherapy spectrum. Methods: Unlaminated Gafchromic{sup ®} EBT2 film and Monte Carlo modeling were combined to derive DEF models. Gold film of thickness 23.1 ±  4.3 nm and surface roughness of 1.2 ± 0.2 nm was placed in contact with unlaminated radiochromic film in a downstream orientation and exposed to a 50 kVp tungsten bremsstrahlung, mean energy 19.2 keV. Film response correction factors were derived by Monte Carlo modeling of electron energy deposition in the film’s active layer, and by measuring film energy dependence from 4.5 keV to 50 kVp. Results: The measured DEF within a 13.6 μm thick water layer was 0.29 with a mean dose of 94 ± 9.4 cGy from Au emissions and 324 ± 32.4 cGy from the 50 kVp primary beam. Monte Carlo derived correction factors allowed determination of Au contributed dose in shallower depths at 0.25 μm intervals. Maximum DEF of 18.31 was found in the first 0.25 μm water depth. Conclusions: Dose enhancement from Au nanofilm can be measured at the cellular level using unlaminated radiochromic film. Complementing the measured dose value with Monte Carlo calculations allows estimation of dose enhancement at depth increments within the cellular range.

  20. Transformation of thiolated chitosan-templated gold nanoparticles to huge microcubes

    SciTech Connect (OSTI)

    Sun, Yudie; Liu, Honglin; Yang, Liangbao; Sun, Bai; Liu, Jinhuai

    2014-05-01

    Graphical abstract: - Highlights: • Mercapto groups were grafted to chitosan molecule by a reactive amine reduction. • Functional polymer with well-defined monomer units controls AuNPs assembly. • Assembled morphologies depend on the ratio of AuNPs to thiolate groups. • Microcubes with side length of ∼20 μm was synthesized through a dialysis step. • A edge-to-middle growth mechanism of gold microcubes was observed. - Abstract: The L-cysteine molecules were successfully grafted to the 2-amino group of chitosan by a reactive amine reduction, and the as-synthesized thiolated chitosan (TC) molecules were used as the templates to direct the self-assembly of gold nanoparticles and induce the transformation of these assemblies to gold microcubes through a deep-going dialysis. We found that the ratio of gold nanoparticles to TC molecules could greatly affect the shape of the assembled clusters. Different stages of these clusters and microstructures during the dialysis process were characterized by scanning electron microscope (SEM), and the microcubes with average side length of about 20 μm were successfully synthesized. According to the morphology evolution of the assembly, it could be concluded that the microcubes were formed from external to internal. The SERS area mapping images of microcubes and some clusters were also collected to study the formation mechanism of gold microcubes. Our work demonstrates a simple and highly effective way to assemble gold nanoparticles into microcubes with unique properties.

  1. Enhancing the Properties of Carbon and Gold Substrates by Surface Modification

    SciTech Connect (OSTI)

    Jennifer Anne Harnisch

    2002-06-27

    The properties of both carbon and gold substrates are easily affected by the judicious choice of a surface modification protocol. Several such processes for altering surface composition have been published in literature. The research presented in this thesis primarily focuses on the development of on-column methods to modify carbon stationary phases used in electrochemically modulated liquid chromatography (EMLC). To this end, both porous graphitic carbon (PGC) and glassy carbon (GC) particles have been modified on-column by the electroreduction of arenediazonium salts and the oxidation of arylacetate anions (the Kolbe reaction). Once modified, the carbon stationary phases show enhanced chromatographic performance both in conventional liquid chromatographic columns and EMLC columns. Additionally, one may also exploit the creation of aryl films to by electroreduction of arenediazonium salts in the creation of nanostructured materials. The formation of mercaptobenzene film on the surface of a GC electrode provides a linking platform for the chemisorption of gold nanoparticles. After deposition of nanoparticles, the surface chemistry of the gold can be further altered by self-assembled monolayer (SAM) formation via the chemisorption of a second thiol species. Finally, the properties of gold films can be altered such that they display carbon-like behavior through the formation of benzenehexathiol (BHT) SAMs. BHT chemisorbs to the gold surface in a previously unprecedented planar fashion. Carbon and gold substrates can be chemically altered by several methodologies resulting in new surface properties. The development of modification protocols and their application in the analytical arena is considered herein.

  2. World's Largest Gold Crystal Studied at Los Alamos

    ScienceCinema (OSTI)

    Vogel, Sven; Nakotte, Heinz

    2015-01-07

    When geologist John Rakovan needed better tools to investigate whether a dazzling 217.78-gram piece of gold was in fact the world's largest single-crystal specimen - a distinguishing factor that would not only drastically increase its market value but also provide a unique research opportunity - he traveled to Los Alamos National Laboratory's Lujan Neutron Scattering Center to peer deep inside the mineral using neutron diffractometry. Neutrons, different from other probes such as X-rays and electrons, are able to penetrate many centimeters deep into most materials. Revealing the inner structure of a crystal without destroying the sample - imperative, as this one is worth an estimated $1.5 million - would allow Rakovan and Lujan Center collaborators Sven Vogel and Heinz Nakotte to prove that this exquisite nugget, which seemed almost too perfect and too big to be real, was a single crystal and hence a creation of nature. Its owner, who lives in the United States, provided the samples to Rakovan to assess the crystallinity of four specimens, all of which had been found decades ago in Venezuela.

  3. Structure and Function Evolution of Thiolate Monolayers on Gold

    SciTech Connect (OSTI)

    Grant Alvin Edwards

    2006-05-01

    The use of n-alkanethiolate self-assembled monolayers on gold has blossomed in the past few years. These systems have functioned as models for common interfaces. Thiolate monolayers are ideal because they are easily modified before or after deposition. The works contained within this dissertation include interfacial characterization (inbred reflection absorption spectroscopy, ellipsometry, contact angle, scanning probe microscopy, and heterogeneous electron-transfer kinetics) and various modeling scenarios. The results of these characterizations present ground-breaking insights into the structure, function, and reproducible preparation of these monolayers. Surprisingly, three interfacial properties (electron-transfer, contact angle, and ellipsometry) were discovered to depend directly on the odd-even character of the monolayer components. Molecular modeling was utilized to investigate adlayer orientation, and suggests that these effects are adlayer structure specific. Finally, the electric force microscopy and theoretical modeling investigations of monolayer samples are presented, which show that the film dielectric constant, thickness, and dipole moment directly affect image contrast. In addition, the prospects for utilization of this emerging technique are outlined.

  4. Effect of particle size on the thermo-optic properties of gold nanofluids – A thermal lens study

    SciTech Connect (OSTI)

    Kumar, B. Rajesh; Basheer, N. Shemeena; Kurian, Achamma; George, Sajan D.

    2014-01-28

    Spherical gold nanoparticles having particle size in the range 30 to 50 nm are prepared using citrate reduction of gold chloride trihydrate in water. The influence of particle size on the thermal diffusivity value of gold nanofluid is measured using dual beam thermal lens technique. The present study shows that the particle size influences the effective thermal diffusivity value of the nanofluid substantially and the value decreases with decrease in particle size for the investigated samples.

  5. Synthesis and Characterization of Gold Clusters Ligated with 1,3-Bis(dicyclohexylphosphino)propane

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2013-09-01

    In this multidisciplinary study we combine chemical reduction synthesis of novel gold clusters in solution with high-resolution analytical mass spectrometry (MS) to gain insight into the composition of the gold clusters and how their size, ionic charge state and ligand substitution influences their gas-phase fragmentation pathways. Ultra small cationic gold clusters ligated with 1,3-bis(dicyclohexylphosphino)propane (DCPP) were synthesized for the first time and introduced into the gas phase using electrospray ionization (ESI). Mass-selected cluster ions were fragmented employing collision induced dissociation (CID) and the product ions were analysed using MS. The solutions were found to contain the multiply charged cationic gold clusters Au9L43+, Au13L53+, Au6L32+, Au8L32+ and Au10L42+ (L = DCPP). The gas-phase fragmentation pathways of these cluster ions were examined systematically employing CID combined with MS. In addition, CID experiments were performed on related gold clusters of the same size and ionic charge state but capped with 1,3-bis(diphenylphosphino)propane (DPPP) ligands containing phenyl functional groups at the two phosphine centers instead of cyclohexane rings. It is shown that this relatively small change in the molecular substitution of the two phosphine centers in diphosphine ligands (C6H11 versus C6H5) exerts a pronounced influence on the size of the species that are preferentially formed in solution during reduction synthesis as well as the gas-phase fragmentation channels of otherwise identical gold cluster ions. The mass spectrometry results indicate that in addition to the length of the alkyl chain between the two phosphine centers, the substituents at the phosphine centers also play a crucial role in determining the composition, size and stability of diphosphine ligated gold clusters synthesized in solution.

  6. SU-C-207-06: In Vivo Quantification of Gold Nanoparticles Using K-Edge Imaging Via Spectrum Shaping by Gold Filter

    SciTech Connect (OSTI)

    Chen, H; Cormack, R; Bhagwat, M; Berbeco, R

    2015-06-15

    Purpose: Gold nanoparticles (AuNP) are multifunctional platforms ideal for drug delivery, targeted imaging and radiosensitization. We have investigated quantitative imaging of AuNPs using on board imager (OBI) cone beam computed tomography (CBCT). To this end, we also present, for the first time, a novel method for k-edge imaging of AuNP by filter-based spectral shaping. Methods: We used a digital 25 cm diameter water phantom, embedded with 3 cm spheres filled with AuNPs of different concentrations (0 mg/ml – 16 mg/ml). A poly-energetic X-ray spectrum of 140 kVp from a conventional X-ray tube is shaped by balanced K-edge filters to create an excess of photons right above the K-edge of gold at 80.7 keV. The filters consist of gold, tin, copper and aluminum foils. The phantom with appropriately assigned attenuation coefficients is forward projected onto a detector for each energy bin and then integrated. FKD reconstruction is performed on the integrated projections. Scatter, detector efficiency and noise are included. Results: We found that subtracting the results of two filter sets (Filter A:127 µm gold foil with 254 µm tin, 330 µm copper and 1 mm aluminum, and Filter B: 635 µm tin with 264 µm copper and 1 mm aluminum), provides substantial image contrast. The resulting filtered spectra match well below 80.7 keV, while maintaining sufficient X-ray quanta just above that. Voxel intensities of AuNP containing spheres increase linearly with AuNP concentration. K-edge imaging provides 18% more sensitivity than the tin filter alone, and 38% more sensitivity than the gold filter alone. Conclusion: We have shown that it is feasible to quantitatively detect AuNP distributions in a patient-sized phantom using clinical CBCT and K-edge spectral shaping.

  7. The Genomes On Line Database (GOLD) in 2009: status of genomic and metagenomic projects and their associated metadata

    SciTech Connect (OSTI)

    Liolios, Konstantinos; Chen, Amy; Mavromatis, Konstantinos; Tavernarakis, Nektarios; Hugenholtz, Phil; Markowitz, Victor; Kyrpides, Nikos C.

    2009-09-01

    The Genomes On Line Database (GOLD) is a comprehensive resource for centralized monitoring of genome and metagenome projects worldwide. Both complete and ongoing projects, along with their associated metadata, can be accessed in GOLD through precomputed tables and a search page. As of September 2009, GOLD contains information for more than 5800 sequencing projects, of which 1100 have been completed and their sequence data deposited in a public repository. GOLD continues to expand, moving toward the goal of providing the most comprehensive repository of metadata information related to the projects and their organisms/environments in accordance with the Minimum Information about a (Meta)Genome Sequence (MIGS/MIMS) specification.

  8. Size-dependent stability toward dissociation and ligand binding energies of phosphine-ligated gold cluster ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2014-01-01

    The stability of sub-nanometer size gold clusters ligated with organic molecules is of paramount importance to the scalable synthesis of monodisperse size-selected metal clusters with highly tunable chemical and physical properties. For the first time, a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR-MS) equipped with surface induced dissociation (SID) has been employed to investigate the time and collision energy resolved fragmentation behavior of cationic doubly charged gold clusters containing 7-9 gold atoms and 6-7 triphenylphosphine (TPP) ligands prepared by reduction synthesis in solution. The TPP ligated gold clusters are demonstrated to fragment through three primary dissociation pathways: (1) Loss of a neutral TPP ligand from the precursor gold cluster, (2) asymmetric fission and (3) symmetric fission and charge separation of the gold core resulting in formation of complementary pairs of singly charged fragment ions. Threshold energies and activation entropies of these fragmentation pathways have been determined employing Rice-Ramsperger-Kassel-Marcus (RRKM) modeling of the experimental SID data. It is demonstrated that the doubly charged cluster ion containing eight gold atoms and six TPP ligands, (8,6)2+, exhibits exceptional stability compared to the other cationic gold clusters examined in this study due to its large ligand binding energy of 1.76 eV. Our findings demonstrate the dramatic effect of the size and extent of ligation on the gas-phase stability and preferred fragmentation pathways of small TPP-ligated gold clusters.

  9. Electrochemical and scanning probe microscopic characterization of spontaneously adsorbed organothiolate monolayers at gold

    SciTech Connect (OSTI)

    Wong, Sze-Shun Season

    1999-12-10

    This dissertation presented several results which add to the general knowledge base regarding organothiolates monolayer spontaneously adsorbed at gold films. Common to the body of this work is the use of voltammetric reductive resorption and variants of scanning probe microscopy to gain insight into the nature of the monolayer formation process as well as the resulting interface. The most significant result from this work is the success of using friction force microscopy to discriminate the end group orientation of monolayer chemisorbed at smooth gold surfaces with micrometer resolution (Chapter 4). The ability to detect the differences in the orientational disposition is demonstrated by the use PDMS polymer stamp to microcontact print an adlayer of n-alkanethiolate of length n in a predefine pattern onto a gold surface, followed by the solution deposition of a n-alkanethiol of n {+-} 1 to fill in the areas on the gold surface intentionally not coated by the stamping process. These two-component monolayers can be discriminated by using friction force microscopy which detects differences in friction contributed by the differences in the orientation of the terminal groups at surfaces. This success has recently led to the detection of the orientation differences at nanometer scale. Although the substrates examined in this work consisted entirely of smooth gold films, the same test can be performed on other smooth substrates and monolayer materials.

  10. Modifying the chemistry of graphene with substrate selection: A study of gold nanoparticle formation

    SciTech Connect (OSTI)

    Zaniewski, Anna M.; Trimble, Christie J.; Nemanich, Robert J.

    2015-03-23

    Graphene and metal nanoparticle composites are a promising class of materials with unique electronic, optical, and chemical properties. In this work, graphene is used as a reducing surface to grow gold nanoparticles out of solution-based metal precursors. The nanoparticle formation is found to strongly depend upon the graphene substrate selection. The studied substrates include diamond, p-type silicon, aluminum oxide, lithium niobate, and copper. Our results indicate that the chemical properties of graphene depend upon this selection. For example, for the same reaction times and concentration, the reduction of gold chloride to gold nanoparticles on graphene/lithium niobate results in 3% nanoparticle coverage compared to 20% coverage on graphene/silicon and 60% on graphene/copper. On insulators, nanoparticles preferentially form on folds and edges. Energy dispersive X-ray analysis is used to confirm the nanoparticle elemental makeup.

  11. Melting behaviour of gold-platinum nanoalloy clusters by molecular dynamics simulations

    SciTech Connect (OSTI)

    Ong, Yee Pin; Yoon, Tiem Leong; Lim, Thong Leng

    2015-04-24

    The melting behavior of bimetallic gold-platinum nanoclusters is studied by applying Brownian-type isothermal molecular dynamics (MD) simulation, a program modified from the cubic coupling scheme (CCS). The process begins with the ground-state structures obtained from global minimum search algorithm and proceeds with the investigation of the effect of temperature on the thermal properties of gold-platinum nanoalloy clusters. N-body Gupta potential has been employed in order to account for the interactions between gold and platinum atoms. The ground states of the nanoalloy clusters, which are core-shell segregated, are heated until they become thermally segregated. The detailed melting mechanism of the nanoalloy clusters is studied via this approach to provide insight into the thermal stability of the nanoalloy clusters.

  12. Application of Gold Electrodes for the Study of Nickel Based Homogeneous Catalysts for Hydrogen Oxidation

    SciTech Connect (OSTI)

    Nepomnyashchii, Alexander B.; Liu, Fei; Roberts, John A.; Parkinson, Bruce A.

    2013-08-12

    Gold and glassy carbon working electrode materials are compared as suitable substrates for the hydrogen oxidation reaction with Ni(PCy2Nt-Bu2)2(BF4)2 used as a catalyst. Voltammetric responses showing electrocatalytic hydrogen oxidation mediated by the homogeneous electrocatalyst Ni(PCy2Nt-Bu2)2(BF4)2 are identical at glassy carbon and gold electrodes, which shows that gold electrode can be used for hydrogen oxidation reaction. This work is supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences under FWP 56073.

  13. Charge Retention by Gold Clusters on Surfaces Prepared Using Soft Landing of Mass Selected Ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2012-01-24

    Monodisperse gold clusters have been prepared on surfaces in different charge states through soft landing of mass-selected ions. Ligand-stabilized gold clusters were prepared in methanol solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine complex in the presence of 1,3-bis(diphenylphosphino)propane. Electrospray ionization was used to introduce the clusters into the gas-phase and mass-selection was employed to isolate a single ionic cluster species (Au11L53+, L = 1,3-bis(diphenylphosphino)propane) which was delivered to surfaces at well controlled kinetic energies. Using in-situ time of flight secondary ion mass spectrometry (TOF-SIMS) it is demonstrated that the Au11L53+ cluster retains its 3+ charge state when soft landed onto the surface of a 1H,1H,2H,2H-

  14. Anomalous complete opaqueness in a sparse array of gold nanoparticle chains

    SciTech Connect (OSTI)

    Bai Benfeng; Li Xiaowei; Vartiainen, Ismo; Lehmuskero, Anni; Turunen, Jari; Kuittinen, Markku; Vahimaa, Pasi; Kang Guoguo

    2011-08-22

    We report on an anomalous polarization-switching extinction effect in a sparse array of gold nanoparticle chains: under normal incidence of light, the array is almost transparent for one polarization; whereas it is fully opaque (with nearly zero transmittance) for the orthogonal polarization within a narrow band, even though the nanoparticles cover only a tiny fraction (say, 3.5%) of the transparent substrate surface. We reveal that the strong polarization-dependent short-range dipolar coupling and long-range radiative coupling of gold nanoparticles in this highly asymmetric array is responsible for this extraordinary effect.

  15. Plasmonic behavior of gold nanorod heterodimers with free-electron feed

    SciTech Connect (OSTI)

    Maiti, Arpan; Maity, Achyut; Chini, Tapas Kumar

    2015-06-24

    The plasmon coupling between metal nanostructures can lead to huge local electric field enhancement and new plasmon modes. Here, we study the effect of the close proximity of two gold nanorod particles on the modification of localized surface plasmon (LSP) modes of the individual on gold nanorod in spectral and spatial domain using cathodoluminescence (CL) spectroscopy and imaging in a high resolution scanning electron microscope (SEM). Significantly enhanced resonant emission is observed from the nanorod dimers when the electron beam is injected around the junction between the rods, where the local density of electromagnetic states is raised.

  16. Calculation of the extinction cross section and lifetime of a gold nanoparticle using FDTD simulations

    SciTech Connect (OSTI)

    Radhakrishnan, Archana; Murugesan, Dr V.

    2014-10-15

    The electromagnetic theory of light explains the behavior of light in most of the domains quite accurately. The problem arises when the exact solution of the Maxwell's equation is not present, in case of objects with arbitrary geometry. To find the extinction cross-section and lifetime of the gold nanoparticle, the software FDTD solutions 8.6 by Lumerical is employed. The extinction cross-sections and lifetimes of Gold nanospheres of different sizes and arrangements are studied using pulse lengths of the order of femtoseconds. The decay constant and other properties are compared. Further, the lifetimes are calculated using frequency and time domain calculations.

  17. Three-dimensional x-ray fluorescence mapping of a gold nanoparticle-loaded phantom

    SciTech Connect (OSTI)

    Ren, Liqiang; Wu, Di; Li, Yuhua; Liu, Hong; Wang, Ge; Wu, Xizeng

    2014-03-15

    Purpose : X-ray fluorescence (XRF) is a promising technique with sufficient specificity and sensitivity for identifying and quantifying features in small samples containing high atomic number (Z) materials such as iodine, gadolinium, and gold. In this study, the feasibility of applying XRF to early breast cancer diagnosis and treatment is studied using a novel approach for three-dimensional (3D) x-ray fluorescence mapping (XFM) of gold nanoparticle (GNP)-loaded objects in a physical phantom at the technical level. Methods : All the theoretical analysis and experiments are conducted under the condition of using x-ray pencil beam and a compactly integrated x-ray spectrometer. The penetrability of the fluorescence x-rays from GNPs is first investigated by adopting a combination of BR12 with 70 mm/50 mm in thickness on the excitation/emission path to mimic the possible position of tumor goldin vivo. Then, a physical phantom made of BR12 is designed to translate in 3D space with three precise linear stages and subsequently the step by step XFM scanning is performed. The experimental technique named as background subtraction is applied to isolate the gold fluorescence from each spectrum obtained by the spectrometer. Afterwards, the attenuations of both the incident primary x-ray beam with energies beyond the gold K-edge energy (80.725 keV) and the isolated gold K{sub α} fluorescence x-rays (65.99 –69.80 keV) acquired after background subtraction are well calibrated, and finally the unattenuated K{sub α} fluorescence counts are used to realize mapping reconstruction and to describe the linear relationship between gold fluorescence counts and corresponding concentration of gold solutions. Results : The penetration results show that the goldK{sub α} fluorescence x-rays have sufficient penetrability for this phantom study, and the reconstructed mapping results indicate that both the spatial distribution and relative concentration of GNPs within the designed BR12 phantom

  18. Efficient Coupling and Transport of a Surface Plasmon at 780 nm in a Gold Nanostructure

    SciTech Connect (OSTI)

    Gong, Yu; Joly, Alan G.; El-Khoury, Patrick Z.; Hess, Wayne P.

    2015-08-28

    We studied plasmonic nanostructures in single-crystal gold with scanning electron and femtosecond photoemission electron microscopies. We designed an integrated laser coupling and nanowire waveguide structure by focused ion beam lithography in single-crystal gold flakes. The photoemission results show that the laser field is efficiently coupled into a propagating surface plasmon by a simple hole structure and propagates efficiently in an adjacent nano-bar waveguide. A strong local field is created by the propagating surface plasmon at the nano-bar tip. A similar structure, with a decreased waveguide width and thickness, displayed significantly more intense photoemission indicating enhanced local electric field at the sharper tip.

  19. Solar Companies Go for the Gold with SunShot Incubator | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Companies Go for the Gold with SunShot Incubator Solar Companies Go for the Gold with SunShot Incubator July 26, 2012 - 9:45am Addthis William Parish from Solar Mosaic, one of nine solar startups chosen for the latest round of SunShot Incubator funding, discusses his company’s project with Energy Secretary Steven Chu at the SunShot Grand Challenge Summit in Denver, Colorado. | Photo by John De La Rosa. William Parish from Solar Mosaic, one of nine solar startups chosen for the

  20. Gold-titania interface toughening and thermal conductance enhancement using an organophosphonate nanolayer

    SciTech Connect (OSTI)

    Chow, Philippe K.; O'Brien, Peter; Ramanath, Ganpati; Cardona Quintero, Y.; Ramprasad, R.; Hubert Mutin, P.; Lane, Michael

    2013-05-20

    We demonstrate that a mercaptan-terminated organophosphonate nanolayer at gold-titania interfaces can give rise to two- to three-fold enhancement in the interfacial fracture toughness and thermal conductance. Electron spectroscopy reveals that interfacial delamination occurs at the metal-molecule interface near the gold-sulfur bonds, consistent with density functional theory calculations of bond energies. Qualitative correlation between interfacial fracture toughness and bond energies suggest that organophosphonate nanolayers are resilient to humidity-induced degradation. These results, and the versatility of organophosphonates as surface functionalization agents for technologically relevant materials, unlock uncharted avenues for molecular engineering of interfaces in materials and devices for a variety of applications.

  1. Experimental demonstration of laser to x-ray conversion enhancements with low density gold targets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shang, Wanli; Yang, Jiamin; Zhang, Wenhai; Li, Zhichao; Deng, Bo; Dong, Yunsong; Zhu, Tuo; Huang, Chengwu; Zhan, Xiayu; Mei, Yu; et al

    2016-02-12

    The enhancement of laser to x-ray conversion efficiencies using low density gold targets [W. L. Shang, J. M. Yang, and Y. S. Dong, Appl. Phys. Lett. 102, 094105 (2013)] is demonstrated. Laser to x-ray conversion efficiencies with 6.3% and 12% increases are achieved with target densities of 1 and 0.25 g/cm3, when compared with that of a solid gold target (19.3 g/cm3). Experimental data and numerical simulations are in good agreement. Lastly, the enhancement is caused by larger x-ray emission zone lengths formed in low density targets, which is in agreement with the simulation results.

  2. FY2014 Parameters for Gold Ions in Booster, AGS, and RHIC

    SciTech Connect (OSTI)

    Gardner, C. J.

    2014-07-30

    The nominal parameters for gold ions in Booster, AGS, and RHIC are given for the FY2014 running period. The parameters are worked out using various formulas to derive mass, kinetic parameters, RF parameters, ring parameters, etc.. The ''standard setup'', ''medium-energy'', and ''low-energy'' parameters are summarized in separate sections.

  3. FY2014 Parameters for Helions and Gold Ions in Booster, AGS, and RHIC

    SciTech Connect (OSTI)

    Gardner, C. J.

    2014-08-15

    The nominal parameters for helions (helion is the bound state of two protons and one neutron, the nucleus of a helium-3 atom) and gold ions in Booster, AGS, and RHIC are given for the FY2014 running period. The parameters are found using various formulas to derive mass, helion anomalous g-factor, kinetic parameters, RF parameters, ring parameters, etc..

  4. Near IR Scanning Angle Total Internal Reflection Raman Spectroscopy at Smooth Gold Films

    SciTech Connect (OSTI)

    McKee, Kristopher; Meyer, Matthew; Smith, Emily

    2012-04-13

    Total internal reflection (TIR) Raman and reflectivity spectra were collected for nonresonant analytes as a function of incident angle at sapphire or sapphire/smooth 50 nm gold interfaces using 785 nm excitation. For both interfaces, the Raman signal as a function of incident angle is well-modeled by the calculated interfacial mean square electric field (MSEF) relative to the incident field times the thickness of the layer being probed in the Raman measurement (D{sub RS}). The Raman scatter was reproducibly enhanced at the interface containing a gold film relative to the sapphire interface by a factor of 4.34.6 for aqueous pyridine or 2.23.7 for neat nitrobenzene, depending on the analyzed vibrational mode. The mechanism for the increased Raman signal is the enhanced MSEF at incident angles where propagating surface plasmons are excited in the metal film. The background from the TIR prism was reduced by 8995% with the addition of the gold film, and the percent relative uncertainty in peak area was reduced from 15 to 1.7% for the 1347 cm1 mode of nitrobenzene. Single monolayers of benzenethiol (S/N = 6.8) and 4-mercaptopyridine (S/N = 16.5) on gold films were measured by TIR Raman spectroscopy with 785 nm excitation (210 mW) without resonant enhancement in 1 min.

  5. Silicone oil contamination and electrical contact resistance degradation of low-force gold contacts.

    SciTech Connect (OSTI)

    Dugger, Michael Thomas; Dickrell, Daniel John, III

    2006-02-01

    Hot-switched low-force gold electrical contact testing was performed using a nanomechanical test apparatus to ascertain the sensitivity of simulated microelectromechanical systems (MEMS) contact to silicone oil contamination. The observed cyclic contact resistance degradation was dependent on both closure rate and noncontact applied voltage. The decomposition of silicone oil from electrical arcing was hypothesized as the degradation mechanism.

  6. Noble reactions for the actinides: safe gold-based access to organouranium and azide complexes

    SciTech Connect (OSTI)

    Thomson, Robert K; Graves, Christopher R; Scott, Brian L; Kiplinger, Jaqueline L

    2008-01-01

    Gold has had a profound impact on organic chemistry; its compounds are spectacular catalysts for many organic transformations involving the formation of C-C, C-O, C-N and CoS bonds, and have enabled unprecedented pathways for the functionalization of C-H and C-C bonds. In general, gold complexes have not been exploited as reagents in organometallic or inorganic chemistry, although a few gold(l) aryl and alkynyl compounds have been reported to undergo transmetalation with transition metal complexes. We have been developing methods for functionalizing uranium complexes and have shown that Cu(l)-X reagents effect the oxidation of uranium with formation of U-X bonds, providing easy chemical control over uranium in oxidation states ranging from U{sup III}{yields}U{sup VI}. Although a logical approach for the direct generation of U-carbon and U-azide bonds, this Cu-based platform is limited in scope as it only works for pure and isolable copper compounds. This is problematic given the instability of organocuprates and copper azides, which can detonate violently as isolated solids. As such, this route has been confined to the synthesis of select uranium phenylacetylide complexes. Over the past few years, a variety of stable gold(l) alkyl, alkenyl, aryl, alkynyl, and azide complexes have been reported, propelling us to investigate their potential as reagents within the oxidative functionalization platform. Unlike the related CU{sup I} systems, Au{sup I} reagents are easily derivatized, and are safe to handle and isolate. Herein, we report that gold(l)-phosphine compounds can undergo a new class of reaction, and are excellent reagents for the oxidative functionalization of uranium with azide and carbon anions.

  7. The Genomes On Line Database (GOLD) in 2007: status of genomic and metagenomic projects and their associated metadata

    SciTech Connect (OSTI)

    Fenner, Marsha W; Liolios, Konstantinos; Mavromatis, Konstantinos; Tavernarakis, Nektarios; Kyrpides, Nikos C.

    2007-12-31

    The Genomes On Line Database (GOLD) is a comprehensive resource of information for genome and metagenome projects world-wide. GOLD provides access to complete and ongoing projects and their associated metadata through pre-computed lists and a search page. The database currently incorporates information for more than 2900 sequencing projects, of which 639 have been completed and the data deposited in the public databases. GOLD is constantly expanding to provide metadata information related to the project and the organism and is compliant with the Minimum Information about a Genome Sequence (MIGS) specifications.

  8. Cationic Gold Clusters Ligated with Differently Substituted Phosphines: Effect of Substitution on Ligand Reactivity and Binding

    SciTech Connect (OSTI)

    Johnson, Grant E.; Olivares, Astrid M.; Hill, David E.; Laskin, Julia

    2015-01-01

    We present a systematic study of the effect of the number of methyl (Me) and cyclohexyl (Cy) functional groups in monodentate phosphine ligands on the solution-phase synthesis of ligated sub-nanometer gold clusters and their gas-phase fragmentation pathways. Small mixed ligand cationic gold clusters were synthesized using ligand exchange reactions between pre-formed triphenylphosphine ligated (PPh3) gold clusters and monodentate Me- and Cy-substituted ligands in solution and characterized using electrospray ionization mass spectrometry (ESI-MS) and collision-induced dissociation (CID) experiments. Under the same experimental conditions, larger gold-PPh3 clusters undergo efficient exchange of unsubstituted PPh3 ligands for singly Me- and Cy-substituted PPh2Me and PPh2Cy ligands. The efficiency of ligand exchange decreases with an increasing number of Me or Cy groups in the substituted phosphine ligands. CID experiments performed for a series of ligand-exchanged gold clusters indicate that loss of a neutral Me-substituted ligand is preferred over loss of a neutral PPh¬3 ligand while the opposite trend is observed for Cy-substituted ligands. The branching ratio of the competing ligand loss channels is strongly correlated with the electron donating ability of the phosphorous lone pair as determined by the relative proton affinity of the ligand. The results indicate that the relative ligand binding energies increase in the order PMe3 < PPhMe2 < PPh2Me < PPh3< PPh2Cy < PPhCy2< PCy3. Furthermore, the difference in relative ligand binding energies increases with the number of substituted PPh3-mMem or PPh3-mCym ligands (L) exchanged onto each cluster. This study provides the first experimental determination of the relative binding energies of ligated gold clusters containing differently substituted monophosphine ligands, which are important to controlling their synthesis and reactivity in solution. The results also indicate that ligand substitution is an important

  9. Excitons in a mirror: Formation of “optical bilayers” using MoS{sub 2} monolayers on gold substrates

    SciTech Connect (OSTI)

    Mertens, Jan; Baumberg, Jeremy J.; Shi, Yumeng; Yang, Hui Ying; Molina-Sánchez, Alejandro; Wirtz, Ludger

    2014-05-12

    We report coupling of excitons in monolayers of molybdenum disulphide to their mirror image in an underlying gold substrate. Excitons at the direct band gap are little affected by the substrate whereas strongly bound C-excitons associated with a van-Hove singularity change drastically. On quartz substrates only one C-exciton is visible (in the blue) but on gold substrates a strong red-shifted extra resonance in the green is seen. Exciton coupling to its image leads to formation of a “mirror biexciton” with enhanced binding energy. Estimates of this energy shift in an emitter-gold system match experiments well. The absorption spectrum of MoS{sub 2} on gold thus resembles a bilayer of MoS{sub 2} which has been created by optical coupling. Additional top-mirrors produce an “optical bulk.”.

  10. Room temperature reaction of oxygen with gold: an in situ ambient-pressure X-ray photoelectron spectroscopy investigation

    SciTech Connect (OSTI)

    Jiang, Peng; Porsgaard, Soeren; Borondics, Ferenc; Kober, Mariana; Caballero, Alfonso; Bluhm, Hendrik; Besenbacher, Flemming; Salmeron, Miquel

    2010-02-01

    Gold is commonly regarded as the most inert element.1 However, the discovery of the exceptional catalytic properties of gold nanoparticles (NPs) for low temperature CO oxidation2 initiated great interest due to its promising applications and spawned a large number of studies devoted to the understanding of the reaction mechanism.3-6 Nevertheless, no consistent and conclusive picture has arisen.7-13