Sample records for hole injection electrode

  1. Solution-Processable Transparent Conductive Hole Injection Electrode for OLED SSL

    SciTech Connect (OSTI)

    None

    2012-07-15T23:59:59.000Z

    An interconnected network of silver nanowires has been used as transparent anode in OLED devices. This layer was deposited by spin-coating and slot-die coating from an aqueous nanowire suspension. The sheet resistance of the film was 10ohms/sq with a transmission (including the glass substrate) of higher than 85%. The first phase of the project focused on the implementation of this nanowire layer with a hole-injection-layer (HIL) which has been developed at Plextronics and has been shown to provide good stability and efficiency in conventional OLED devices. We modified the HIL solution such that it coated reasonably well with suitable surface morphology so that actual devices can be manufactured. During the second phase we investigated the hole-injection and stability of hole-onlydevices. We determined that the use of the nanowire network as anode does not introduce an additional degradation mechanism since the observed device characteristics did not differ from those made with ITO anode. We then proceeded to make actual OLED devices with this nanowire / HIL stack and achieved device characteristics similar state-of-the-art OLED devices with a single junction. In order to gain traction with potential OLED manufacturers, we decided to contract Novaled to prepare large-area demonstrators for us. For these devices, we used an allevaporated stack, i.e. we did use Novaledâ??s HIL material instead of Plextronicsâ??. We successfully fabricated demonstrators with an area of 25cm2 with a double or triple junction stack. Minor stack optimizations were necessary to achieve efficacies and lifetime equivalent with ITO devices made with the same devices stack. Due to the reduced microcavity effect, the color of the emitted light is significantly more stable with respect to the viewing angle compared to ITO devices. This fact in conjunction with the promise of lower production cost due to the elimination of the ITO sputtering process and the direct patterning of the anode layer are the obvious advantages of this technology. The project has shown that this nanowire technology is a viable option to achieve OLED devices with good lifetime and efficiency and we are currently working with manufacturers to utilize this technology in a production setting.

  2. Field-enhanced electrodes for additive-injection non-thermal plasma (NTP) processor

    DOE Patents [OSTI]

    Rosocha, Louis A. (Los Alamos, NM); Ferreri, Vincent (Westminster, CO); Kim, Yongho (Los Alamos, NM)

    2009-04-21T23:59:59.000Z

    The present invention comprises a field enhanced electrode package for use in a non-thermal plasma processor. The field enhanced electrode package includes a high voltage electrode and a field-enhancing electrode with a dielectric material layer disposed in-between the high voltage electrode and the field-enhancing electrode. The field-enhancing electrode features at least one raised section that includes at least one injection hole that allows plasma discharge streamers to occur primarily within an injected additive gas.

  3. Optoelectronic device with nanoparticle embedded hole injection/transport layer

    DOE Patents [OSTI]

    Wang, Qingwu (Chelmsford, MA); Li, Wenguang (Andover, MA); Jiang, Hua (Methuen, MA)

    2012-01-03T23:59:59.000Z

    An optoelectronic device is disclosed that can function as an emitter of optical radiation, such as a light-emitting diode (LED), or as a photovoltaic (PV) device that can be used to convert optical radiation into electrical current, such as a photovoltaic solar cell. The optoelectronic device comprises an anode, a hole injection/transport layer, an active layer, and a cathode, where the hole injection/transport layer includes transparent conductive nanoparticles in a hole transport material.

  4. Extrusion of electrode material by liquid injection into extruder barrel

    DOE Patents [OSTI]

    Keller, David Gerard (Baltimore, MD); Giovannoni, Richard Thomas (Reisterstown, MD); MacFadden, Kenneth Orville (Highland, MD)

    1998-01-01T23:59:59.000Z

    An electrode sheet product is formed using an extruder having a feed throat and a downstream section by separately mixing an active electrode material and a solid polymer electrolyte composition that contains lithium salt. The active electrode material is fed into the feed throat of the extruder, while a portion of at least one fluid component of the solid polymer electrolyte composition is introduced to the downstream section. The active electrode material and the solid polymer electrolyte composition are compounded in a downstream end of the extruder. The extruded sheets, adhered to current collectors, can be formed into battery cells.

  5. Extrusion of electrode material by liquid injection into extruder barrel

    DOE Patents [OSTI]

    Keller, D.G.; Giovannoni, R.T.; MacFadden, K.O.

    1998-03-10T23:59:59.000Z

    An electrode sheet product is formed using an extruder having a feed throat and a downstream section by separately mixing an active electrode material and a solid polymer electrolyte composition that contains lithium salt. The active electrode material is fed into the feed throat of the extruder, while a portion of at least one fluid component of the solid polymer electrolyte composition is introduced to the downstream section. The active electrode material and the solid polymer electrolyte composition are compounded in a downstream end of the extruder. The extruded sheets, adhered to current collectors, can be formed into battery cells. 1 fig.

  6. The effect of injection hole geometry on flat plate film cooling and heat transfer

    E-Print Network [OSTI]

    Madsen, Eric Perry

    1994-01-01T23:59:59.000Z

    conducted at 50 000 Reynolds number , wi th bo th a ir and C02 inject ion and at f our b lowing ratios for r\\ and a l l five b lowing ratios for h . Each slot con f igurat ion was designed to give a total cross-sectional area equal to that of the holes... Averaged Heat Trans fer Coeff icient Ratio for 45? Hole Injection 20 approx imate ly 1.05. In contrast to 0? hole injection, 45? hole inject ion projects a larger cross-sect ional area to the mainf low, wh i ch results i n h igher turbu lence...

  7. Tritium flow through a non-symmetrical source. Simulation of gas flow through an injection hole

    E-Print Network [OSTI]

    Sharipov, Felix

    Tritium flow through a non-symmetrical source. Simulation of gas flow through an injection hole of source in injection rarefaction parameter µ0 viscosity of tritium at T0 Pa s 2 #12;Ll = 5074.5 Lr = 5007

  8. Film cooling and heat transfer of steam through an inclined injection hole

    E-Print Network [OSTI]

    Chen, Hun Way

    1983-01-01T23:59:59.000Z

    transfer coefficient at blowing rate M 0. 5 . . . . . . . . . . . . . . . . 37 NOMENCLATURE Symbol Description area circumference of the cross sectional area Cp D E, , Es, Es drag coefficient specific heat diameter of the injection hole minor... the experimental data at low blowing rates; however, the extension to higher injection rates is not correct, and an injected fluid other than air is not discussed. Goldstein [2] reviewed a number of semi- empirical correlations and predictions for two...

  9. Flow injection analysis of phenolic compounds with carbon paste electrodes modified with tyrosinase purchased from different companies

    SciTech Connect (OSTI)

    Lindgren, A.; Emneus, J.; Csoeregi, E.; Gorton, L.; Marko-Varga, G. [Univ. of Lund (Sweden); Ruzgas, T. [Inst. of Biochemistry, Vilnius (Lithuania)

    1996-05-01T23:59:59.000Z

    Tyrosinase-modified carbon paste electrodes were prepared using lyophilised powder of the enzyme purchased from different companies. The selectivity of these electrodes for nine phenolic compounds, including six substituted catechols, has been studied. The signals obtained for catechol were always higher than those found for other phenolic compounds. Cyclic voltammetry and flow injection measurements indicated that the response of the tyrosinase-modified carbon paste electrodes was limited by the rate of the enzymatic oxidation of catechols. Different approaches of past electrode preparation have been studied and compared. Direct mixing of enzyme into the graphite powder doped with the osmium based mediator, resulted in the highest sensitivity for the studied substrates. However, substrate selectivity was found to be dependent on the source of enzyme used for electrode preparation.

  10. Flame structure of wall-impinging diesel fuel sprays injected by group-hole nozzles

    SciTech Connect (OSTI)

    Gao, Jian; Moon, Seoksu; Nishida, Keiya; Matsumoto, Yuhei [Department of Mechanical System Engineering, University of Hiroshima, Higashi-Hiroshima, 739-8527 (Japan); Zhang, Yuyin [Department of Mechanical Engineering, Tokyo Denki University, Tokyo, 101-8457 (Japan)

    2009-06-15T23:59:59.000Z

    This paper describes an investigation of the flame structure of wall-impinging diesel sprays injected by group-hole nozzles in a constant-volume combustion vessel at experimental conditions typical of a diesel engine. The particular emphasis was on the effect of the included angle between two orifices (0-15 deg. in current study) on the flame structure and combustion characteristics under various simulated engine load conditions. The laser absorption scattering (LAS) technique was applied to analyze the spray and mixture properties. Direct flame imaging and OH chemiluminescence imaging were utilized to quantify the ignition delay, flame geometrical parameters, and OH chemiluminescence intensity. The images show that the asymmetric flame structure emerges in wall-impinging group-hole nozzle sprays as larger included angle and higher engine load conditions are applied, which is consistent with the spray shape observed by LAS. Compared to the base nozzle, group-hole nozzles with large included angles yield higher overall OH chemiluminescence intensity, wider flame area, and greater proportion of high OH intensity, implying the better fuel/air mixing and improved combustion characteristics. The advantages of group-hole nozzle are more pronounced under high load conditions. Based on the results, the feasibility of group-hole nozzle for practical direct injection diesel engines is also discussed. It is concluded that the asymmetric flame structure of a group-hole nozzle spray is favorable to reduce soot formation over wide engine loads. However, the hole configuration of the group-hole nozzle should be carefully considered so as to achieve proper air utilization in the combustion chamber. Stoichiometric diesel combustion is another promising application of group-hole nozzle. (author)

  11. Next Generation Hole Injection/Transport Nano-Composites for High Efficiency OLED Development

    SciTech Connect (OSTI)

    King Wang

    2009-07-31T23:59:59.000Z

    The objective of this program is to use a novel nano-composite material system for the OLED anode coating/hole transport layer. The novel anode coating is intended to significantly increase not only hole injection/transport efficiency, but the device energy efficiency as well. Another goal of the Core Technologies Program is the optimization and scale-up of air-stable and cross-linkable novel HTL nano-composite materials synthesis and the development of low-cost, large-scale mist deposition processes for polymer OLED fabrication. This proposed technology holds the promise to substantially improve OLED energy efficiency and lifetime.

  12. Ultra low injection angle fuel holes in a combustor fuel nozzle

    DOE Patents [OSTI]

    York, William David

    2012-10-23T23:59:59.000Z

    A fuel nozzle for a combustor includes a mixing passage through which fluid is directed toward a combustion area and a plurality of swirler vanes disposed in the mixing passage. Each swirler vane of the plurality of swirler vanes includes at least one fuel hole through which fuel enters the mixing passage in an injection direction substantially parallel to an outer surface of the plurality of swirler vanes thereby decreasing a flameholding tendency of the fuel nozzle. A method of operating a fuel nozzle for a combustor includes flowing a fluid through a mixing passage past a plurality of swirler vanes and injecting a fuel into the mixing passage in an injection direction substantially parallel to an outer surface of the plurality of swirler vanes.

  13. Mechanistic Studies of Charge Injection from Metallic Electrodes into Organic Semiconductors Mediated by Ionic Functionalities: Final Report

    SciTech Connect (OSTI)

    Nguyen, Thuc-Quyen [UCSB; Bazan, Guillermo [UCSB; Mikhailovsky, Alexander [UCSB

    2014-04-15T23:59:59.000Z

    Metal-organic semiconductor interfaces are important because of their ubiquitous role in determining the performance of modern electronics such as organic light emitting diodes (OLEDs), fuel cells, batteries, field effect transistors (FETs), and organic solar cells. Interfaces between metal electrodes required for external wiring to the device and underlying organic structures directly affect the charge carrier injection/collection efficiency in organic-based electronic devices primarily due to the mismatch between energy levels in the metal and organic semiconductor. Environmentally stable and cost-effective electrode materials, such as aluminum and gold typically exhibit high potential barriers for charge carriers injection into organic devices leading to increased operational voltages in OLEDs and FETs and reduced charge extraction in photovoltaic devices. This leads to increased power consumption by the device, reduced overall efficiency, and decreased operational lifetime. These factors represent a significant obstacle for development of next generation of cheap and energy-efficient components based on organic semiconductors. It has been noticed that introduction of organic materials with conjugated backbone and ionic pendant groups known as conjugated poly- and oligoelectrolytes (CPEs and COEs), enables one to reduce the potential barriers at the metal-organic interface and achieve more efficient operation of a device, however exact mechanisms of the phenomenon have not been understood. The goal of this project was to delineate the function of organic semiconductors with ionic groups as electron injection layers. The research incorporated a multidisciplinary approach that encompassed the creation of new materials, novel processing techniques, examination of fundamental electronic properties and the incorporation of the resulting knowledgebase into development of novel organic electronic devices with increased efficiency, environmental stability, and reduced cost. During the execution of the project, main efforts were focused on the synthesis of new charge-bearing organic materials, such as CPEs and COEs, and block copolymers with neutral and ionic segments, studies of mechanisms responsible for the charge injection modulation in devices with ionic interlayers, and use of naturally occurring charged molecules for creation of enhanced devices. The studies allowed PIs to demonstrate the usefulness of the proposed approach for the improvement of operational parameters in model OLED and FET systems resulting in increased efficiency, decreased contact resistance, and possibility to use stable metals for fabrication of device electrodes. The successful proof-of-the-principle results potentially promise development of light-weight, low fabrication cost devices which can be used in consumer applications such as displays, solar cells, and printed electronic devices. Fundamental mechanisms responsible for the phenomena observed have been identified thus advancing the fundamental knowledgebase.

  14. The effect of injection hole orientation on flat-plate film cooling and heat transfer using a transient liquid crystal technique

    E-Print Network [OSTI]

    Zapata, Dyrk Oliver

    1994-01-01T23:59:59.000Z

    . . . . . . . . . . . . 61 63 64 65 NOMENCLATURE Cv specific heat of test surface injection hole diameter convective heat transfer coefficient (W/m -K) convective heat transfer coefficient for no film injection momentum ratio, prUt2/p U 2 N Rea test surface... thermal conductivity length of injection hole blowing ratio, prUi/p U number of step changes Reynolds number, p U d/lt TOW time of color change adiabatic wall temperature Tm TU initial temperature film temperature mainstream temperature...

  15. Verification of electrical spin injection into InGaAs two-dimensional electron gas from CoFe electrode by four-terminal non-local geometry

    SciTech Connect (OSTI)

    Hidaka, S.; Kondo, T.; Akabori, M.; Yamada, S. [Center for Nano Materials and Technology (CNMT), Japan Advanced Institute of Science and Technology (JAIST), Asahidai, Nomi, Ishikawa 923-1292 (Japan)

    2013-12-04T23:59:59.000Z

    We performed electrical spin injection into In{sub 0.75}Ga{sub 0.25}As two-dimensional electron gases from Co{sub 0.8}Fe{sub 0.2} electrodes by four-terminal non-local spin-valve (NLSV) measurement. We observed clear SV signals in NL resistance at 1.5 K. From the electrode spacing dependence of the signals, we estimated spin diffusion length and spin polarization to be ?5.1 ?m and ?5.7 %, respectively. These are larger than those reported in similar systems.

  16. One-electron Oxidation of a Pyrenyl Photosensitizer Covalently Attached to DNA and Competition Between its Further Oxidation and DNA Hole Injection

    E-Print Network [OSTI]

    Yun, Byeong Hwa

    The photosensitized hole injection and guanine base damage phenomena have been investigated in the DNA sequence, 5?-d(CATG[subscript 1] [superscript Py]CG[subscript 2]TCCTAC) with a site-specifically positioned pyrene-like ...

  17. MoO3 as combined hole injection layer and tapered spacer in combinatorial multicolor microcavity organic light emitting diodes

    SciTech Connect (OSTI)

    Liu, R.; Xu, Chun; Biswas, Rana; Shinar, Joseph; Shinar, Ruth

    2011-09-01T23:59:59.000Z

    Multicolor microcavity ({mu}C) organic light-emitting diode (OLED) arrays were fabricated simply by controlling the hole injection and spacer MoO{sub 3} layer thickness. The normal emission was tunable from {approx}490 to 640 nm and can be further expanded. A compact, integrated spectrometer with two-dimensional combinatorial arrays of {mu}C OLEDs was realized. The MoO{sub 3} yields more efficient and stable devices, revealing a new breakdown mechanism. The pixel current density reaches {approx}4 A/cm{sup 2} and a maximal normal brightness {approx}140 000 Cd/m{sup 2}, which improves photoluminescence-based sensing and absorption measurements.

  18. An experimental study of density ratio effects on the film cooling injection from discrete holes by using PIV and PSP techniques

    E-Print Network [OSTI]

    Hu, Hui

    technique. The effects of the coolant-to-mainstream density ratio (DR) on the film cooling effectiveness the implementation of film cooling techniques. While optimization of the film cooling of turbine blades possessesAn experimental study of density ratio effects on the film cooling injection from discrete holes

  19. Pressure-assisted fabrication of organic light emitting diodes with MoO{sub 3} hole-injection layer materials

    SciTech Connect (OSTI)

    Du, J. [The Princeton Institute for the Science and Technology of Materials (PRISM), Princeton, New Jersey 08544 (United States); Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Anye, V. C.; Vodah, E. O. [Department of Materials Science and Engineering, African University of Science and Technology, Abuja, Federal Capital Territory (Nigeria); Tong, T. [The Princeton Institute for the Science and Technology of Materials (PRISM), Princeton, New Jersey 08544 (United States); Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Zebaze Kana, M. G. [Physics Advanced Laboratory, Sheda Science and Technology Complex, Abuja, Federal Capital Territory (Nigeria); Department of Materials Science and Engineering, Kwara State University, Kwara State (Nigeria); Soboyejo, W. O. [The Princeton Institute for the Science and Technology of Materials (PRISM), Princeton, New Jersey 08544 (United States); Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Department of Materials Science and Engineering, African University of Science and Technology, Abuja, Federal Capital Territory (Nigeria)

    2014-06-21T23:59:59.000Z

    In this study, pressures of ?5 to ?8?MPa were applied to organic light emitting diodes containing either evaporated molybdenum trioxide (MoO{sub 3}) or spin-coated poly(3,4-ethylene dioxythiophene) doped with poly(styrene sulphonate) (PEDOT:PSS) hole-injection layers (HILs). The threshold voltages for both devices were reduced by about half, after the application of pressure. Furthermore, in an effort to understand the effects of pressure treatment, finite element simulations were used to study the evolution of surface contact between the HIL and emissive layer (EML) under pressure. The blister area due to interfacial impurities was also calculated. This was shown to reduce by about half, when the applied pressures were between ?5 and 8?MPa. The finite element simulations used Young's modulus measurements of MoO{sub 3} that were measured using the nanoindentation technique. They also incorporated measurements of the adhesion energy between the HIL and EML (measured by force microscopy during atomic force microscopy). Within a fracture mechanics framework, the implications of the results are then discussed for the pressure-assisted fabrication of robust organic electronic devices.

  20. Enhancement of hole injection and electroluminescence by ordered Ag nanodot array on indium tin oxide anode in organic light emitting diode

    SciTech Connect (OSTI)

    Jung, Mi, E-mail: jmnano00@gmail.com, E-mail: Dockha@kist.re.kr [Sensor System Research Center, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of); School of Mechanical Systems Engineering, Kookmin University, Seoul 136-702 (Korea, Republic of); Mo Yoon, Dang; Kim, Miyoung [Korea Printed Electronics Center, Korea Electronics Technology Institute, Jeollabuk-do, 561-844 (Korea, Republic of); Kim, Chulki; Lee, Taikjin; Hun Kim, Jae; Lee, Seok; Woo, Deokha, E-mail: jmnano00@gmail.com, E-mail: Dockha@kist.re.kr [Sensor System Research Center, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of); Lim, Si-Hyung [School of Mechanical Systems Engineering, Kookmin University, Seoul 136-702 (Korea, Republic of)

    2014-07-07T23:59:59.000Z

    We report the enhancement of hole injection and electroluminescence (EL) in an organic light emitting diode (OLED) with an ordered Ag nanodot array on indium-tin-oxide (ITO) anode. Until now, most researches have focused on the improved performance of OLEDs by plasmonic effects of metal nanoparticles due to the difficulty in fabricating metal nanodot arrays. A well-ordered Ag nanodot array is fabricated on the ITO anode of OLED using the nanoporous alumina as an evaporation mask. The OLED device with Ag nanodot arrays on the ITO anode shows higher current density and EL enhancement than the one without any nano-structure. These results suggest that the Ag nanodot array with the plasmonic effect has potential as one of attractive approaches to enhance the hole injection and EL in the application of the OLEDs.

  1. Film Cooling with Forward and Backward Injection for Cylindrical and Fan-shaped Holes Using PSP Measurement Technique

    E-Print Network [OSTI]

    Chen, Andrew F

    2013-11-08T23:59:59.000Z

    and each hole is 4 mm in diameter. The blowing ratio effect is studied at 10 different blowing ratios ranging from M = 0.3 to M = 2.0. The coolant to main stream density ratio (DR) effect is studied by using foreign gases with DR = 1 (N2), 1.5 (CO_2), and 2...

  2. Premixed direct injection disk

    DOE Patents [OSTI]

    York, William David; Ziminsky, Willy Steve; Johnson, Thomas Edward; Lacy, Benjamin; Zuo, Baifang; Uhm, Jong Ho

    2013-04-23T23:59:59.000Z

    A fuel/air mixing disk for use in a fuel/air mixing combustor assembly is provided. The disk includes a first face, a second face, and at least one fuel plenum disposed therebetween. A plurality of fuel/air mixing tubes extend through the pre-mixing disk, each mixing tube including an outer tube wall extending axially along a tube axis and in fluid communication with the at least one fuel plenum. At least a portion of the plurality of fuel/air mixing tubes further includes at least one fuel injection hole have a fuel injection hole diameter extending through said outer tube wall, the fuel injection hole having an injection angle relative to the tube axis. The invention provides good fuel air mixing with low combustion generated NOx and low flow pressure loss translating to a high gas turbine efficiency, that is durable, and resistant to flame holding and flash back.

  3. Room-temperature spin-polarized organic light-emitting diodes with a single ferromagnetic electrode

    SciTech Connect (OSTI)

    Ding, Baofu, E-mail: b.ding@ecu.edu.au; Alameh, Kamal, E-mail: k.alameh@ecu.edu.au [Electron Science Research Institute, Edith Cowan University, 270 Joondalup Drive, Joondalup WA 6027 Australia (Australia); Song, Qunliang [Institute for Clean Energy and Advanced Materials, Southwest University, Chongqing 400715 (China)

    2014-05-19T23:59:59.000Z

    In this paper, we demonstrate the concept of a room-temperature spin-polarized organic light-emitting diode (Spin-OLED) structure based on (i) the deposition of an ultra-thin p-type organic buffer layer on the surface of the ferromagnetic electrode of the Spin-OLED and (ii) the use of oxygen plasma treatment to modify the surface of that electrode. Experimental results demonstrate that the brightness of the developed Spin-OLED can be increased by 110% and that a magneto-electroluminescence of 12% can be attained for a 150?mT in-plane magnetic field, at room temperature. This is attributed to enhanced hole and room-temperature spin-polarized injection from the ferromagnetic electrode, respectively.

  4. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01T23:59:59.000Z

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing,more »between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.« less

  5. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01T23:59:59.000Z

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing, between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.

  6. Electrode compositions

    DOE Patents [OSTI]

    Block, J.; Fan, X.

    1998-10-27T23:59:59.000Z

    An electrode composition is described for use as an electrode in a non-aqueous battery system. The electrode composition contains an electrically active powder in a solid polymer and, as a dispersant, a C{sub 8}-C{sub 15} alkyl capped oligomer of a hexanoic acid that is electrochemically inert at 2.5--4.5 volts.

  7. Flow through electrode with automated calibration

    DOE Patents [OSTI]

    Szecsody, James E [Richland, WA; Williams, Mark D [Richland, WA; Vermeul, Vince R [Richland, WA

    2002-08-20T23:59:59.000Z

    The present invention is an improved automated flow through electrode liquid monitoring system. The automated system has a sample inlet to a sample pump, a sample outlet from the sample pump to at least one flow through electrode with a waste port. At least one computer controls the sample pump and records data from the at least one flow through electrode for a liquid sample. The improvement relies upon (a) at least one source of a calibration sample connected to (b) an injection valve connected to said sample outlet and connected to said source, said injection valve further connected to said at least one flow through electrode, wherein said injection valve is controlled by said computer to select between said liquid sample or said calibration sample. Advantages include improved accuracy because of more frequent calibrations, no additional labor for calibration, no need to remove the flow through electrode(s), and minimal interruption of sampling.

  8. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A. (Augusta, GA)

    1994-01-01T23:59:59.000Z

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  9. Injection system for small betatron

    SciTech Connect (OSTI)

    Zuorygin, V.P.; Chakhlov, V.L.; Pushin, U.S.

    1985-07-01T23:59:59.000Z

    In order to reduce the head loads on the injector electrodes and to raise the efficiency of electron capture during acceleration, small betatrons are provided with an injection system with a controlled three-electrode injector in which injection current pulse with steep leading and trailing edges is formed by the application of a voltage pulse to the control electrode from a separate circuit through a pulse transformer. In a betatron injection system described, elements of the controlled injector of the accelerating chamber are used to correct the shape of the current pulse. The circuit for correcting the current-pulse shape can increase the accelerated charge by the average of 75% per betatron cycle and decrease the heat loads on the electrodes of the injector without the use of a generator of controlling voltage pulses.

  10. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05T23:59:59.000Z

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  11. Continuous injection method controls downhole corrosion - 2

    SciTech Connect (OSTI)

    Bradburn, J.B.; Todd, R.B.

    1981-08-01T23:59:59.000Z

    In designing a continuous downhole corrosion inhibitor injection system, many interrelated factors must be considered: bottomhole pressure, inhibitor viscosity, injection rate, friction loss, hole geometry, cost, delivery time, annulus environment, elastomers, and corrosivity of well fluids. In view of the many variables associated with the design of a downhole injection system, the following design outline is presented. 8 refs.

  12. Method and means for detecting optically transmitted signals and establishing optical interference pattern between electrodes

    DOE Patents [OSTI]

    Kostenbauder, A.G.

    1988-06-28T23:59:59.000Z

    A photodetector for detecting signal pulses transmitted in an optical carrier signal relies on the generation of electron-hole pairs and the diffusion of the generated electrons and holes to the electrodes on the surface of the semiconductor detector body for generating photovoltaic pulses. The detector utilizes the interference of optical waves for generating an electron-hole grating within the semiconductor body, and, by establishing an electron-hole pair maximum at one electrode and a minimum at the other electrode, a detectable voltaic pulse is generated across the electrode. 4 figs.

  13. GaInN light-emitting diodes using separate epitaxial growth for the p-type region to attain polarization-inverted electron-blocking layer, reduced electron leakage, and improved hole injection

    SciTech Connect (OSTI)

    Meyaard, David S., E-mail: meyaad@rpi.edu; Lin, Guan-Bo; Ma, Ming; Fred Schubert, E. [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)] [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Cho, Jaehee [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States) [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Semiconductor Physics Research Center, School of Semiconductor and Chemical Engineering, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Han, Sang-Heon; Kim, Min-Ho; Shim, HyunWook; Sun Kim, Young [LED Business, Samsung Electronics, Yongin 446-920 (Korea, Republic of)] [LED Business, Samsung Electronics, Yongin 446-920 (Korea, Republic of)

    2013-11-11T23:59:59.000Z

    A GaInN light-emitting diode (LED) structure is analyzed that employs a separate epitaxial growth for the p-type region, i.e., the AlGaN electron-blocking layer (EBL) and p-type GaN cladding layer, followed by wafer or chip bonding. Such LED structure has a polarization-inverted EBL and allows for uncompromised epitaxial-growth optimization of the p-type region, i.e., without the need to consider degradation of the quantum-well active region during p-type region growth. Simulations show that such an LED structure reduces electron leakage, reduces the efficiency droop, improves hole injection, and has the potential to extend high efficiencies into the green spectral region.

  14. RETGEM with polyvinylchloride (PVC) electrodes

    E-Print Network [OSTI]

    Razin, V I; Reshetin, A I; Filippov, S N

    2009-01-01T23:59:59.000Z

    This paper presents a new design of the RETGEM (Resistive Electrode Thick GEM) based on electrodes made of a polyvinylchloride material (PVC). Our device can operate with gains of 10E5 as a conventional TGEM at low counting rates and as RPC in the case of high counting rates without of the transit to the violent sparks. The distinct feature of present RETGEM is the absent of the metal coating and lithographic technology for manufacturing of the protective dielectric rms. The electrodes from PVC permit to do the holes by a simple drilling machine. Detectors on a RETGEM basis could be useful in many fields of an application requiring a more cheap manufacturing and safe operation, for example, in a large neutrino experiments, in TPC, RICH systems.

  15. Simultaneous enhancement of electron overflow reduction and hole injection promotion by tailoring the last quantum barrier in InGaN/GaN light-emitting diodes

    E-Print Network [OSTI]

    Demir, Hilmi Volkan

    the last quantum barrier in InGaN/GaN light-emitting diodes Zabu Kyaw, Zi-Hui Zhang, Wei Liu, Swee Tiam Tan injection and efficiency droop in InGaN/GaN light-emitting diodes with step-stage multiple- quantum distribution in InGaN/GaN light-emitting diodes with graded thickness quantum barriers Appl. Phys. Lett. 102

  16. Fuel injection

    SciTech Connect (OSTI)

    Iiyoshi, A.; Vogoshi, S.

    1983-12-01T23:59:59.000Z

    The Plasma Physics Laboratory and the Dept. of Electrical Engineering report on three types of pellet injectors which have different applications: injection of a pellet into a magnetic bottle for magnetic confinement; injection of a pellet into a vacuum chamber for an inertial confinement experiment; and injection of a pellet into a magnetic bottle where the pellet is ionized by high-power laser irradiation for target plasma production. The requirements of pellet injectors are summarized in a table. Theoretical studies on pellet ablation in hot plasma and ablated particle diffusion are underway.

  17. Micromachined electrode array

    DOE Patents [OSTI]

    Okandan, Murat (Edgewood, NM); Wessendorf, Kurt O. (Albuquerque, NM)

    2007-12-11T23:59:59.000Z

    An electrode array is disclosed which has applications for neural stimulation and sensing. The electrode array, in certain embodiments, can include a plurality of electrodes each of which is flexibly attached to a common substrate using a plurality of springs to allow the electrodes to move independently. In other embodiments of the electrode array, the electrodes can be fixed to the substrate. The electrode array can be formed from a combination of bulk and surface micromachining, and can include electrode tips having an electroplated metal (e.g. platinum, iridium, gold or titanium) or a metal oxide (e.g. iridium oxide) for biocompatibility. The electrode array can be used to form a part of a neural prosthesis, and is particularly well adapted for use in an implantable retinal prosthesis.

  18. Flexible retinal electrode array

    DOE Patents [OSTI]

    Okandan, Murat (Albuquerque, NM); Wessendorf, Kurt O. (Albuquerque, NM); Christenson, Todd R. (Albuquerque, NM)

    2006-10-24T23:59:59.000Z

    An electrode array which has applications for neural stimulation and sensing. The electrode array can include a large number of electrodes each of which is flexibly attached to a common substrate using a plurality of springs to allow the electrodes to move independently. The electrode array can be formed from a combination of bulk and surface micromachining, with electrode tips that can include an electroplated metal (e.g. platinum, iridium, gold or titanium) or a metal oxide (e.g. iridium oxide) for biocompatibility. The electrode array can be used to form a part of a neural prosthesis, and is particularly well adapted for use in an implantable retinal prosthesis where the electrodes can be tailored to provide a uniform gentle contact pressure with optional sensing of this contact pressure at one or more of the electrodes.

  19. High frequency reference electrode

    DOE Patents [OSTI]

    Kronberg, J.W.

    1994-05-31T23:59:59.000Z

    A high frequency reference electrode for electrochemical experiments comprises a mercury-calomel or silver-silver chloride reference electrode with a layer of platinum around it and a layer of a chemically and electrically resistant material such as TEFLON around the platinum covering all but a small ring or halo' at the tip of the reference electrode, adjacent to the active portion of the reference electrode. The voltage output of the platinum layer, which serves as a redox electrode, and that of the reference electrode are coupled by a capacitor or a set of capacitors and the coupled output transmitted to a standard laboratory potentiostat. The platinum may be applied by thermal decomposition to the surface of the reference electrode. The electrode provides superior high-frequency response over conventional electrodes. 4 figs.

  20. Low resistance fuel electrodes

    DOE Patents [OSTI]

    Maskalick, Nichols J. (Pittsburgh, PA); Folser, George R. (Lower Burrell, PA)

    1989-01-01T23:59:59.000Z

    An electrode 6 bonded to a solid, ion conducting electrolyte 5 is made, where the electrode 6 comprises a ceramic metal oxide 18, metal particles 17, and heat stable metal fibers 19, where the metal fibers provide a matrix structure for the electrode. The electrolyte 5 can be bonded to an air electrode cathode 4, to provide an electrochemical cell 2, preferably of tubular design.

  1. Near-electrode imager

    DOE Patents [OSTI]

    Rathke, Jerome W. (Lockport, IL); Klingler, Robert J. (Westmont, IL); Woelk, Klaus (Wachtberg, DE); Gerald, II, Rex E. (Brookfield, IL)

    2000-01-01T23:59:59.000Z

    An apparatus, near-electrode imager, for employing nuclear magnetic resonance imaging to provide in situ measurements of electrochemical properties of a sample as a function of distance from a working electrode. The near-electrode imager uses the radio frequency field gradient within a cylindrical toroid cavity resonator to provide high-resolution nuclear magnetic resonance spectral information on electrolyte materials.

  2. Longitudinal discharge laser electrodes

    DOE Patents [OSTI]

    Warner, B.E.; Miller, J.L.; Ault, E.R.

    1994-08-23T23:59:59.000Z

    The improved longitudinal discharge laser electrode with IR baffle includes an electrode made up of washers spaced along the laser axis in order to form inter-washer spaces for hollow cathode discharge to take place and for IR radiation to be trapped. Additional IR baffles can be placed between the electrode ann the window. 2 figs.

  3. Electrically conductive diamond electrodes

    DOE Patents [OSTI]

    Swain, Greg (East Lansing, MI); Fischer, Anne (Arlington, VA),; Bennett, Jason (Lansing, MI); Lowe, Michael (Holt, MI)

    2009-05-19T23:59:59.000Z

    An electrically conductive diamond electrode and process for preparation thereof is described. The electrode comprises diamond particles coated with electrically conductive doped diamond preferably by chemical vapor deposition which are held together with a binder. The electrodes are useful for oxidation reduction in gas, such as hydrogen generation by electrolysis.

  4. Electrical resistance tomography using steel cased boreholes as electrodes

    DOE Patents [OSTI]

    Daily, William D. (Livermore, CA); Ramirez, Abelardo L. (Pleasanton, CA)

    1999-01-01T23:59:59.000Z

    An electrical resistance tomography method using steel cased boreholes as electrodes. The method enables mapping the electrical resistivity distribution in the subsurface from measurements of electrical potential caused by electrical currents injected into an array of electrodes in the subsurface. By use of current injection and potential measurement electrodes to generate data about the subsurface resistivity distribution, which data is then used in an inverse calculation, a model of the electrical resistivity distribution can be obtained. The inverse model may be constrained by independent data to better define an inverse solution. The method utilizes pairs of electrically conductive (steel) borehole casings as current injection electrodes and as potential measurement electrodes. The greater the number of steel cased boreholes in an array, the greater the amount of data is obtained. The steel cased boreholes may be utilized for either current injection or potential measurement electrodes. The subsurface model produced by this method can be 2 or 3 dimensional in resistivity depending on the detail desired in the calculated resistivity distribution and the amount of data to constain the models.

  5. Electrical resistance tomography using steel cased boreholes as electrodes

    DOE Patents [OSTI]

    Daily, W.D.; Ramirez, A.L.

    1999-06-22T23:59:59.000Z

    An electrical resistance tomography method is described which uses steel cased boreholes as electrodes. The method enables mapping the electrical resistivity distribution in the subsurface from measurements of electrical potential caused by electrical currents injected into an array of electrodes in the subsurface. By use of current injection and potential measurement electrodes to generate data about the subsurface resistivity distribution, which data is then used in an inverse calculation, a model of the electrical resistivity distribution can be obtained. The inverse model may be constrained by independent data to better define an inverse solution. The method utilizes pairs of electrically conductive (steel) borehole casings as current injection electrodes and as potential measurement electrodes. The greater the number of steel cased boreholes in an array, the greater the amount of data is obtained. The steel cased boreholes may be utilized for either current injection or potential measurement electrodes. The subsurface model produced by this method can be 2 or 3 dimensional in resistivity depending on the detail desired in the calculated resistivity distribution and the amount of data to constrain the models. 2 figs.

  6. Negative electrode composition

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Chilenskas, Albert A. (Western Springs, IL)

    1982-01-01T23:59:59.000Z

    A secondary electrochemical cell and a negative electrode composition for use therewith comprising a positive electrode containing an active material of a chalcogen or a transiton metal chalcogenide, a negative electrode containing a lithium-aluminum alloy and an amount of a ternary alloy sufficient to provide at least about 5 percent overcharge capacity relative to a negative electrode solely of the lithium-aluminum alloy, the ternary alloy comprising lithium, aluminum, and iron or cobalt, and an electrolyte containing lithium ions in contact with both of the positive and the negative electrodes. The ternary alloy is present in the electrode in the range of from about 5 percent to about 50 percent by weight of the electrode composition and may include lithium-aluminum-nickel alloy in combination with either the ternary iron or cobalt alloys. A plurality of series connected cells having overcharge capacity can be equalized on the discharge side without expensive electrical equipment.

  7. Submicron patterned metal hole etching

    DOE Patents [OSTI]

    McCarthy, Anthony M. (Menlo Park, CA); Contolini, Robert J. (Lake Oswego, OR); Liberman, Vladimir (Needham, MA); Morse, Jeffrey (Martinez, CA)

    2000-01-01T23:59:59.000Z

    A wet chemical process for etching submicron patterned holes in thin metal layers using electrochemical etching with the aid of a wetting agent. In this process, the processed wafer to be etched is immersed in a wetting agent, such as methanol, for a few seconds prior to inserting the processed wafer into an electrochemical etching setup, with the wafer maintained horizontal during transfer to maintain a film of methanol covering the patterned areas. The electrochemical etching setup includes a tube which seals the edges of the wafer preventing loss of the methanol. An electrolyte composed of 4:1 water: sulfuric is poured into the tube and the electrolyte replaces the wetting agent in the patterned holes. A working electrode is attached to a metal layer of the wafer, with reference and counter electrodes inserted in the electrolyte with all electrodes connected to a potentiostat. A single pulse on the counter electrode, such as a 100 ms pulse at +10.2 volts, is used to excite the electrochemical circuit and perform the etch. The process produces uniform etching of the patterned holes in the metal layers, such as chromium and molybdenum of the wafer without adversely effecting the patterned mask.

  8. Oregon Underground Injection Control Program Authorized Injection...

    Open Energy Info (EERE)

    Oregon Underground Injection Control Program Authorized Injection Systems Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Oregon Underground...

  9. Nanoscopic electrode molecular probes

    DOE Patents [OSTI]

    Krstic, Predrag S. (Knoxville, TN); Meunier, Vincent (Knoxville, TN)

    2012-05-22T23:59:59.000Z

    The present invention relates to a method and apparatus for enhancing the electron transport property measurements of a molecule when the molecule is placed between chemically functionalized carbon-based nanoscopic electrodes to which a suitable voltage bias is applied. The invention includes selecting a dopant atom for the nanoscopic electrodes, the dopant atoms being chemically similar to atoms present in the molecule, and functionalizing the outer surface and terminations of the electrodes with the dopant atoms.

  10. Black Holes

    E-Print Network [OSTI]

    P. K. Townsend

    1997-07-04T23:59:59.000Z

    Lecture notes for a 'Part III' course 'Black Holes' given in DAMTP, Cambridge. The course covers some of the developments in Black Hole physics of the 1960s and 1970s.

  11. Staged direct injection diesel engine

    DOE Patents [OSTI]

    Baker, Quentin A. (San Antonio, TX)

    1985-01-01T23:59:59.000Z

    A diesel engine having staged injection for using lower cetane number fuels than No. 2 diesel fuel. The engine includes a main fuel injector and a pilot fuel injector. Pilot and main fuel may be the same fuel. The pilot injector injects from five to fifteen percent of the total fuel at timings from 20.degree. to 180.degree. BTDC depending upon the quantity of pilot fuel injected, the fuel cetane number and speed and load. The pilot fuel injector is directed toward the centerline of the diesel cylinder and at an angle toward the top of the piston, avoiding the walls of the cylinder. Stratification of the early injected pilot fuel is needed to reduce the fuel-air mixing rate, prevent loss of pilot fuel to quench zones, and keep the fuel-air mixture from becoming too fuel lean to become effective. In one embodiment, the pilot fuel injector includes a single hole for injection of the fuel and is directed at approximately 48.degree. below the head of the cylinder.

  12. Carbon Nanosheets and Nanostructured Electrodes in Organic Photovoltaic Devices: Cooperative Research and Development Final Report, CRADA Number CRD-08-321

    SciTech Connect (OSTI)

    Olson, D.

    2012-04-01T23:59:59.000Z

    Carbon nanosheet thin films were employed as nanostructured electrodes in organic solar cells. Due to the nanostructured texture of the carbon nanosheet electrodes, there was an increase in performance over standard ITO electrodes with very thick active layers. ZnO deposited via atomic layer deposition (ALD) was used as a hole blocking layer to provide for carrier selectivity of the carbon nanosheets.

  13. Multifunctional reference electrode

    DOE Patents [OSTI]

    Redey, L.; Vissers, D.R.

    1981-12-30T23:59:59.000Z

    A multifunctional, low mass reference electrode of a nickel tube, thermocouple means inside the nickel tube electrically insulated therefrom for measuring the temperature thereof, a housing surrounding the nickel tube, an electrolyte having a fixed sulfide ion activity between the housing and the outer surface of the nickel tube forming the nickel/nickel sulfide/sulfide half-cell are described. An ion diffusion barrier is associated with the housing in contact with the electrolyte. Also disclosed is a cell using the reference electrode to measure characteristics of a working electrode.

  14. Multifunctional reference electrode

    DOE Patents [OSTI]

    Redey, Laszlo (Lisle, IL); Vissers, Donald R. (Naperville, IL)

    1983-01-01T23:59:59.000Z

    A multifunctional, low mass reference electrode of a nickel tube, thermocouple means inside the nickel tube electrically insulated therefrom for measuring the temperature thereof, a housing surrounding the nickel tube, an electrolyte having a fixed sulfide ion activity between the housing and the outer surface of the nickel tube forming the nickel/nickel sulfide/sulfide half-cell. An ion diffusion barrier is associated with the housing in contact with the electrolyte. Also disclosed is a cell using the reference electrode to measure characteristics of a working electrode.

  15. Zinc electrode with cement additive

    DOE Patents [OSTI]

    Charkey, Allen (Brookfield, CT)

    1982-06-01T23:59:59.000Z

    A zinc electrode having a cement additive, preferably, Portland Cement, distributed in the zinc active material.

  16. Premixed direct injection nozzle for highly reactive fuels

    DOE Patents [OSTI]

    Ziminsky, Willy Steve; Johnson, Thomas Edward; Lacy, Benjamin Paul; York, William David; Uhm, Jong Ho; Zuo, Baifang

    2013-09-24T23:59:59.000Z

    A fuel/air mixing tube for use in a fuel/air mixing tube bundle is provided. The fuel/air mixing tube includes an outer tube wall extending axially along a tube axis between an inlet end and an exit end, the outer tube wall having a thickness extending between an inner tube surface having a inner diameter and an outer tube surface having an outer tube diameter. The tube further includes at least one fuel injection hole having a fuel injection hole diameter extending through the outer tube wall, the fuel injection hole having an injection angle relative to the tube axis. The invention provides good fuel air mixing with low combustion generated NOx and low flow pressure loss translating to a high gas turbine efficiency, that is durable, and resistant to flame holding and flash back.

  17. Capacitive de-ionization electrode

    DOE Patents [OSTI]

    Daily, III, William D.

    2013-03-19T23:59:59.000Z

    An electrode "cell" for use in a capacitive deionization (CDI) reactor consists of the electrode support structure, a non-reactive conductive material, the electrode accompaniment or substrate and a flow through screen/separator. These "layers" are repeated and the electrodes are sealed together with gaskets between two end plates to create stacked sets of alternating anode and cathode electrodes in the CDI reactor.

  18. Organic light emitting diodes with structured electrodes

    DOE Patents [OSTI]

    Mao, Samuel S.; Liu, Gao; Johnson, Stephen G.

    2012-12-04T23:59:59.000Z

    A cathode that contain nanostructures that extend into the organic layer of an OLED has been described. The cathode can have an array of nanotubes or a layer of nanoclusters extending out from its surface. In another arrangement, the cathode is patterned and etched to form protruding nanostructures using a standard lithographic process. Various methods for fabricating these structures are provided, all of which are compatible with large-scale manufacturing. OLEDs made with these novel electrodes have greatly enhanced electron injection, have good environmental stability.

  19. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06T23:59:59.000Z

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  20. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1997-01-01T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  1. Dual porosity gas evolving electrode

    DOE Patents [OSTI]

    Townsend, C.W.

    1994-11-15T23:59:59.000Z

    A dual porosity electrode is described for use in thermoelectrochemical systems where simultaneous transport of gas and liquid into and/or out of the electrode is required. The electrode includes catalytic electrode particles having diameters ranging from about 25 to 100 angstroms. The catalytic electrode particles are anchored to a support network in clusters which have internal pores ranging in size from 25 to 100 angstroms. The pores between the clusters range in size from between about 1 to 20 microns. A method for making the dual porosity electrodes is also disclosed.

  2. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durable Fuel Cell Membrane Electrode Assembly (MEA) Durable Fuel Cell Membrane Electrode Assembly (MEA) A revolutionary method of building a membrane electrode assembly (MEA) for...

  3. Screen Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Cell Chemistries and Streamlining Optimization of Electrode Screen Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrode 2010 DOE Vehicle Technologies...

  4. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, D.R.

    1988-08-16T23:59:59.000Z

    A stable reference electrode is described for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na[sub 3]AlF[sub 6], wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution. 1 fig.

  5. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1988-01-01T23:59:59.000Z

    A stable reference electrode for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na.sub.3 AlF.sub.6, wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution.

  6. Radial lean direct injection burner

    DOE Patents [OSTI]

    Khan, Abdul Rafey; Kraemer, Gilbert Otto; Stevenson, Christian Xavier

    2012-09-04T23:59:59.000Z

    A burner for use in a gas turbine engine includes a burner tube having an inlet end and an outlet end; a plurality of air passages extending axially in the burner tube configured to convey air flows from the inlet end to the outlet end; a plurality of fuel passages extending axially along the burner tube and spaced around the plurality of air passage configured to convey fuel from the inlet end to the outlet end; and a radial air swirler provided at the outlet end configured to direct the air flows radially toward the outlet end and impart swirl to the air flows. The radial air swirler includes a plurality of vanes to direct and swirl the air flows and an end plate. The end plate includes a plurality of fuel injection holes to inject the fuel radially into the swirling air flows. A method of mixing air and fuel in a burner of a gas turbine is also provided. The burner includes a burner tube including an inlet end, an outlet end, a plurality of axial air passages, and a plurality of axial fuel passages. The method includes introducing an air flow into the air passages at the inlet end; introducing a fuel into fuel passages; swirling the air flow at the outlet end; and radially injecting the fuel into the swirling air flow.

  7. Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes**

    E-Print Network [OSTI]

    New Mexico, University of

    Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes** D. Bruce Burckel Polsky* The special nature of the CÀC bond can lead to various polymorphic forms of carbon such as graphite, glassy-carbon, fullerenes (such as buckyballs), carbon nanotubes, and diamond. Electrodes made

  8. Terahertz graphene lasers: Injection versus optical pumping

    SciTech Connect (OSTI)

    Ryzhii, Victor; Otsuji, Taiichi [Research Institute for Electrical Communication, Tohoku University, Sendai 980-8577 (Japan); Ryzhii, Maxim [Computational Nanoelectronics Laboratory, University of Aizu, Aizu-Wakamatsu 965-8580 (Japan); Mitin, Vladimir [Department of Electrical Engineering, University at Buffalo, SUNY, Buffalo, New York 14260-1920 (United States)

    2013-12-04T23:59:59.000Z

    We analyze the formation of nonequilibrium states in optically pumped graphene layers and in forward-biased graphene structures with lateral p-i-n junctions and consider the conditions of population inversion and lasing. The model used accounts for intraband and interband relaxation processes as well as deviation of the optical phonon system from equilibrium. As shown, optical pumping suffers from a significant heating of both the electron-hole plasma and the optical phonon system, which can suppress the formation of population inversion. In the graphene structures with p-i-n junction, the injected electrons and holes have relatively low energies, so that the effect of cooling can be rather pronounced, providing a significant advantage of the injection pumping in realization of graphene terahertz lasers.

  9. Battery electrode growth accommodation

    DOE Patents [OSTI]

    Bowen, Gerald K. (Cedarburg, WI); Andrew, Michael G. (Wauwatosa, WI); Eskra, Michael D. (Fredonia, WI)

    1992-01-01T23:59:59.000Z

    An electrode for a lead acid flow through battery, the grids including a plastic frame, a plate suspended from the top of the frame to hang freely in the plastic frame and a paste applied to the plate, the paste being free to allow for expansion in the planar direction of the grid.

  10. Polyoxometalate-Graphene Nanocomposite Modified Electrode for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Polyoxometalate-Graphene Nanocomposite Modified Electrode for Electrocatalytic Detection of Ascorbic Acid. Polyoxometalate-Graphene Nanocomposite Modified Electrode for...

  11. Rich catalytic injection

    DOE Patents [OSTI]

    Veninger, Albert (Coventry, CT)

    2008-12-30T23:59:59.000Z

    A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

  12. Electrode array for neural stimulation

    DOE Patents [OSTI]

    Wessendorf, Kurt O. (Albuquerque, NM); Okandan, Murat (Edgewood, NM); Stein, David J. (Albuquerque, NM); Yang, Pin (Albuquerque, NM); Cesarano, III, Joseph (Albuquerque, NM); Dellinger, Jennifer (Albuquerque, NM)

    2011-08-16T23:59:59.000Z

    An electrode array for neural stimulation is disclosed which has particular applications for use in a retinal prosthesis. The electrode array can be formed as a hermetically-sealed two-part ceramic package which includes an electronic circuit such as a demultiplexer circuit encapsulated therein. A relatively large number (up to 1000 or more) of individually-addressable electrodes are provided on a curved surface of a ceramic base portion the electrode array, while a much smaller number of electrical connections are provided on a ceramic lid of the electrode array. The base and lid can be attached using a metal-to-metal seal formed by laser brazing. Electrical connections to the electrode array can be provided by a flexible ribbon cable which can also be used to secure the electrode array in place.

  13. Catalyzed enzyme electrodes

    DOE Patents [OSTI]

    Zawodzinski, Thomas A. (Los Alamos, NM); Wilson, Mahlon S. (Los Alamos, NM); Rishpon, Judith (Ramat-Aviv, IL); Gottesfeld, Shimshon (Los Alamos, NM)

    1993-01-01T23:59:59.000Z

    An enzyme electrode is prepared with a composite coating on an electrical conductor. The composite coating is formed from a casting solution of a perfluorosulfonic acid polymer, an enzyme, and a carbon supported catalyst. The solution may be cast directly on the conductor surface or may be formed as a membrane and applied to the surface. The perfluorosulfonic acid ionomer formed from the casting solution provides an insoluble biocompatible protective matrix for the enzyme and acts to retain the enzyme for long term availability in the electrode structure. The carbon supported catalyst provides catalytic sites throughout the layer for the oxidation of hydrogen peroxide from the enzyme reactions. The carbon support then provides a conductive path for establishing an electrical signal to the electrical conductor. In one embodiment, the electrical conductor is a carbon cloth that permits oxygen or other gas to be introduced to the perfluorosulfonic polymer to promote the enzyme reaction independent of oxygen in the solution being tested.

  14. Long life reference electrode

    DOE Patents [OSTI]

    Yonco, R.M.; Nagy, Z.

    1987-07-30T23:59:59.000Z

    An external, reference electrode is provided for long term use with a high temperature, high pressure system. The electrode is arranged in a vertical, electrically insulative tube with an upper portion serving as an electrolyte reservoir and a lower portion in electrolytic communication with the system to be monitored. The lower end portion includes a flow restriction such as a porous plug to limit the electrolyte release into the system. A piston equalized to the system pressure is fitted into the upper portion of the tube to impart a small incremental pressure to the electrolyte. The piston is selected of suitable size and weight to cause only a slight flow of electrolyte through the porous plug into the high pressure system. This prevents contamination of the electrolyte but is of such small flow rate that operating intervals of a month or more can be achieved. 2 figs.

  15. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, David F. (Idaho Falls, ID); Suciu, Dan F. (Idaho Falls, ID); Harris, Taryl L. (Idaho Falls, ID); Ingram, Jani C. (Idaho Falls, ID)

    1993-01-01T23:59:59.000Z

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  16. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, D.F.; Suciu, D.F.; Harris, T.L.; Ingram, J.C.

    1993-04-06T23:59:59.000Z

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  17. Nickel anode electrode

    DOE Patents [OSTI]

    Singh, Prabhakar (Bethel, CT); Benedict, Mark (Monroe, CT)

    1987-01-01T23:59:59.000Z

    A nickel anode electrode fabricated by oxidizing a nickel alloying material to produce a material whose exterior contains nickel oxide and whose interior contains nickel metal throughout which is dispersed the oxide of the alloying material and by reducing and sintering the oxidized material to form a product having a nickel metal exterior and an interior containing nickel metal throughout which is dispersed the oxide of the alloying material.

  18. Membrane reference electrode

    DOE Patents [OSTI]

    Redey, L.; Bloom, I.D.

    1988-01-21T23:59:59.000Z

    A reference electrode utilizes a small thin, flat membrane of a highly conductive glass placed on a small diameter insulator tube having a reference material inside in contact with an internal voltage lead. When the sensor is placed in a non-aqueous ionic electrolytic solution, the concentration difference across the glass membrane generates a low voltage signal in precise relationship to the concentration of the species to be measured, with high spatial resolution. 2 figs.

  19. Shielded capacitive electrode

    DOE Patents [OSTI]

    Kireeff Covo, Michel

    2013-07-09T23:59:59.000Z

    A device is described, which is sensitive to electric fields, but is insensitive to stray electrons/ions and unlike a bare, exposed conductor, it measures capacitively coupled current while rejecting currents due to charged particle collected or emitted. A charged particle beam establishes an electric field inside the beam pipe. A grounded metallic box with an aperture is placed in a drift region near the beam tube radius. The produced electric field that crosses the aperture generates a fringe field that terminates in the back surface of the front of the box and induces an image charge. An electrode is placed inside the grounded box and near the aperture, where the fringe fields terminate, in order to couple with the beam. The electrode is negatively biased to suppress collection of electrons and is protected behind the front of the box, so the beam halo cannot directly hit the electrode and produce electrons. The measured signal shows the net potential (positive ion beam plus negative electrons) variation with time, as it shall be observed from the beam pipe wall.

  20. STATEMENT OF CONSIDERATIONS REQUEST BY CAMBRIOS TECHNOLOGIES...

    Broader source: Energy.gov (indexed) [DOE]

    transparent conducting hole injection (TCHI) electrode for OLEO SSL (Organic Light Emitting Diode-Solid State Lighting) applications. The TCHI electrode will replace the...

  1. Enzyme nanoband electrodes

    SciTech Connect (OSTI)

    Wang, J.; Naser, N. (New Mexico State Univ., Las Cruces (United States)); Renschler, C.L. (Sandia National Labs., Albuquerque, NM (United States))

    1993-07-01T23:59:59.000Z

    Enzyme nanoelectrodes have been constructed by immobilizing glucose oxidase, alcohol oxidase or tyrosinase onto ultrathin carbon films (of 35-50 nm thickness). The enzyme immobilization is accomplished via entrapment within electropolymerized poly(o-phenylenediamine) coatings. Cyclic voltammetry and controlled-potential amperometry are used to characterize the performance of the new nanoscopic biosensors under different preparation and operation conditions. The resulting electrodes offer convenient and rapid measurements of millimolar substrate concentrations, and (to the best of the authors' knowledge) are the smallest enzyme probes reported to date. 10 refs., 7 figs.

  2. activated carbon electrodes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes** Materials Science Websites Summary: Pyrolytic carbon electrodes Lithographically Defined...

  3. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng; Wen, Jian; Chen, Jinghua; Huang, Zhongping; Wang, Dezhi

    2006-12-12T23:59:59.000Z

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  4. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Wen, Jian (Newton, MA); Chen, Jinghua (Chestnut Hill, MA); Huang, Zhongping (Belmont, MA); Wang, Dezhi (Wellesley, MA)

    2008-10-28T23:59:59.000Z

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  5. Nanostructured Electrode Materials for Supercapacitors

    E-Print Network [OSTI]

    Wu, Shin-Tson

    and batteries/fuel cells. Nanostructured electrode materials have demonstrated superior electrochemical of polymethine dyes electronic spectra is crucial for successful design of the new molecules with optimized

  6. Coronal Holes

    E-Print Network [OSTI]

    Cranmer, Steven R

    2009-01-01T23:59:59.000Z

    Coronal holes are the darkest and least active regions of the Sun, as observed both on the solar disk and above the solar limb. Coronal holes are associated with rapidly expanding open magnetic fields and the acceleration of the high-speed solar wind. This paper reviews measurements of the plasma properties in coronal holes and how these measurements are used to reveal details about the physical processes that heat the solar corona and accelerate the solar wind. It is still unknown to what extent the solar wind is fed by flux tubes that remain open (and are energized by footpoint-driven wave-like fluctuations), and to what extent much of the mass and energy is input intermittently from closed loops into the open-field regions. Evidence for both paradigms is summarized in this paper. Special emphasis is also given to spectroscopic and coronagraphic measurements that allow the highly dynamic non-equilibrium evolution of the plasma to be followed as the asymptotic conditions in interplanetary space are establish...

  7. Activated Carbon Injection

    ScienceCinema (OSTI)

    None

    2014-07-22T23:59:59.000Z

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  8. Activated Carbon Injection

    SciTech Connect (OSTI)

    None

    2014-07-16T23:59:59.000Z

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  9. Underground Injection Control (Louisiana)

    Broader source: Energy.gov [DOE]

    The Injection and Mining Division (IMD) has the responsibility of implementing two major federal environmental programs which were statutorily charged to the Office of Conservation: the Underground...

  10. Improved photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, T.A.

    1983-06-29T23:59:59.000Z

    Improved photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  11. Electrochemical photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, Terje A. (East Patchogue, NY)

    1984-01-01T23:59:59.000Z

    Improved electrochemical photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  12. Smooth electrode and method of fabricating same

    DOE Patents [OSTI]

    Weaver, Stanton Earl (Northville, NY); Kennerly, Stacey Joy (Albany, NY); Aimi, Marco Francesco (Niskayuna, NY)

    2012-08-14T23:59:59.000Z

    A smooth electrode is provided. The smooth electrode includes at least one metal layer having thickness greater than about 1 micron; wherein an average surface roughness of the smooth electrode is less than about 10 nm.

  13. Composite electrode/electrolyte structure

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (El Cerrito, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2004-01-27T23:59:59.000Z

    Provided is an electrode fabricated from highly electronically conductive materials such as metals, metal alloys, or electronically conductive ceramics. The electronic conductivity of the electrode substrate is maximized. Onto this electrode in the green state, a green ionic (e.g., electrolyte) film is deposited and the assembly is co-fired at a temperature suitable to fully densify the film while the substrate retains porosity. Subsequently, a catalytic material is added to the electrode structure by infiltration of a metal salt and subsequent low temperature firing. The invention allows for an electrode with high electronic conductivity and sufficient catalytic activity to achieve high power density in ionic (electrochemical) devices such as fuel cells and electrolytic gas separation systems.

  14. Electrode for a lithium cell

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Dees, Dennis W. (Downers Grove, IL)

    2008-10-14T23:59:59.000Z

    This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

  15. Advantages of flattened electrode in bottom contact single-walled carbon nanotube field-effect transistor

    SciTech Connect (OSTI)

    Setiadi, Agung; Akai-Kasaya, Megumi, E-mail: kasaya@prec.eng.osaka-u.ac.jp; Saito, Akira; Kuwahara, Yuji [Department of Precision Science and Technology, Graduate School of Engineering, Osaka University, 565-0871 Suita (Japan)

    2014-09-01T23:59:59.000Z

    We fabricated single-walled carbon nanotube (SWNT) field-effect transistor (FET) devices on flattened electrodes, in which there are no height difference between metal electrodes and the substrate. SWNT-FET fabricated using bottom contact technique have some advantages, such that the SWNTs are free from electron irradiation, have direct contact with the desired metal electrodes, and can be functionalized before or after deposition. However, the SWNTs can be bent at the contact point with the metal electrodes leading to a different electrical characteristic of the devices. The number of SWNT direct junctions in short channel length devices is drastically increased by the use of flattened electrodes due to strong attractive interaction between SWNT and the substrate. The flattened electrodes show a better balance between their hole and electron mobility compared to that of the non-flattened electrodes, that is, ambipolar FET characteristic. It is considered that bending of the SWNTs in the non-flattened electrode devices results in a higher Schottky barrier for the electrons.

  16. Low resistance electrode construction

    DOE Patents [OSTI]

    Redey, Laszlo (Downers Grove, IL); Karell, Eric J. (Woodridge, IL)

    2002-01-01T23:59:59.000Z

    An electrochemical cell having a cathode and an anode in contact with an electrolyte. Both electrodes or one of them has an electrically conducting non-metal receptacle defining a chamber with a first metal having a melting point in the range of from about room temperature to about 800.degree. C. inside said receptacle chamber. A second metal with a melting point greater than about 800.degree. C. is in contact with the first metal inside the receptacle chamber and extends outside of the receptacle chamber to form a terminal for the anode. The electrolyte may include the oxides, halides or mixtures thereof of one or more of Li, V, U, Al and the lanthanides. Metal may be produced at the cathode during operation of the cell and oxygen or chlorine at the anode.

  17. Electrochromic counter electrode

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland; Jorgensen, Gary J.

    2005-02-22T23:59:59.000Z

    The present invention discloses an amorphous material comprising nickel oxide doped with tantalum that is an anodically coloring electrochromic material. The material of the present invention is prepared in the form of an electrode (200) having a thin film (202) of an electrochromic material of the present invention residing on a transparent conductive film (203). The material of the present invention is also incorporated into an electrochromic device (100) as a thin film (102) in conjunction with a cathodically coloring prior art electrochromic material layer (104) such that the devices contain both anodically coloring (102) and cathodically coloring (104) layers. The materials of the electrochromic layers in these devices exhibit broadband optical complimentary behavior, ionic species complimentary behavior, and coloration efficiency complimentary behavior in their operation.

  18. RHIC | Black Holes?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Black Holes at RHIC? Further discussion by Physicist Dmitri Kharzeev on why RHIC cannot produce a real gravitational black hole Black holes are among the most mysterious objects in...

  19. Pressure modulated injection and its effect on combustion and emissions of a HD diesel engine

    SciTech Connect (OSTI)

    Erlach, H.; Chmela, F.; Cartellieri, W.; Herzog, P.

    1995-12-31T23:59:59.000Z

    The paper describes the concept selection, design and performance of a fuel injection equipment (FIE) which provides high flexibility in shaping the injection rate. With this injection system standard and boot shaped injection rates as well as pilot injections and post injections can be achieved throughout the hole speed and load range. Special emphasis was drawn to realize boot rate shaping by pressure modulation rather than by throttling the fuel flow (i.e.: the system is operated with fully opened needle during the whole injection period and no throttling device limits the fuel flow in front of the nozzle to reduce the injection rate). Initial engine tests on a single cylinder research engine with 2 liter displacement were carried out at one operating point (1,000 rpm, 200 mm{sup 3}/str = 75% of full load fueling). Boot and pilot (split) injection rate shaping strategies are compared to a standard injection without rate shaping. At constant smoke and BSFC the boot injection shows a considerable improvement potential in NOx emissions of up to {minus}14%, or NOx and BSFC can be reduced simultaneously by {minus}9% and {minus}7%, respectively. The results with pilot injection are less promising than the results with boot injection. Furthermore, they are sensitive to pilot timing and to injection pressure as well as fueling during pilot injection.

  20. Diffusion in biofilms respiring on electrodes. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on electrodes. The electrodes were polarized so that they would act as the sole terminal electron acceptor for microbial metabolism. We present our results as both...

  1. Manganese Oxide Composite Electrodes for Lithium Batteries |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Oxide Composite Electrodes for Lithium Batteries Technology available for licensing: Improved spinel-containing "layered-layered" lithium metal oxide electrodes Materials...

  2. Deposition of TiO2 thin films by atmospheric plasma post-discharge assisted injection MOCVD

    E-Print Network [OSTI]

    Boyer, Edmond

    -discharge is sent away from electrodes confinement [3]. In this work, we have combined these two systems working combines remote Atmospheric Pressure (AP) Plasma with Pulsed Injection Metallorganic Chemical Vapour developed Pulsed Injection MOCVD [1] method, based on a liquid delivery system controlled by a high speed

  3. An Electrode-based approach for monitoring in situ microbial activity during subsurface bioremediation

    SciTech Connect (OSTI)

    Williams, K.H.; Nevin, K.P.; Franks, A.; Englert, A.; Long, P.E.; Lovley, D.R.

    2009-11-15T23:59:59.000Z

    Current production by microorganisms colonizing subsurface electrodes and its relationship to substrate availability and microbial activity was evaluated in an aquifer undergoing bioremediation. Borehole graphite anodes were installed downgradient from a region of acetate injection designed to stimulate bioreduction of U(VI); cathodes consisted of graphite electrodes embedded at the ground surface. Significant increases in current density ({<=}50 mA/m{sup 2}) tracked delivery of acetate to the electrodes, dropping rapidly when acetate inputs were discontinued. An upgradient control electrode not exposed to acetate produced low, steady currents ({<=}0.2 mA/m{sup 2}). Elevated current was strongly correlated with uranium removal but minimal correlation existed with elevated Fe(II). Confocal laser scanning microscopy of electrodes revealed firmly attached biofilms, and analysis of 16S rRNA gene sequences indicated the electrode surfaces were dominated (67-80%) by Geobacter species. This is the first demonstration that electrodes can produce readily detectable currents despite long-range (6 m) separation of anode and cathode, and these results suggest that oxidation of acetate coupled to electron transfer to electrodes by Geobacter species was the primary source of current. Thus it is expected that current production may serve as an effective proxy for monitoring in situ microbial activity in a variety of subsurface anoxic environments.

  4. Capacitance enhancement via electrode patterning

    SciTech Connect (OSTI)

    Ho, Tuan A.; Striolo, Alberto, E-mail: a.striolo@ucl.ac.uk [School of Chemical, Biological and Materials Engineering, The University of Oklahoma, Norman, Oklahoma 73019 (United States) [School of Chemical, Biological and Materials Engineering, The University of Oklahoma, Norman, Oklahoma 73019 (United States); Department of Chemical Engineering, University College London, Torrington Place, London WC1E 7JE (United Kingdom)

    2013-11-28T23:59:59.000Z

    The necessity of increasing the energy density in electric double layer capacitors to meet current demand is fueling fundamental and applied research alike. We report here molecular dynamics simulation results for aqueous electrolytes near model electrodes. Particular focus is on the effect of electrode patterning on the structure of interfacial electrolytes, and on the potential drop between the solid electrodes and the bulk electrolytes. The latter is estimated by numerically integrating the Poisson equation using the charge densities due to water and ions accumulated near the interface as input. We considered uniform and patterned electrodes, both positively and negatively charged. The uniformly charged electrodes are modeled as graphite. The patterned ones are obtained by removing carbon atoms from the top-most graphene layer, yielding nanoscopic squares and stripes patterns. For simplicity, the patterned electrodes are effectively simulated as insulators (the charge remains localized on the top-most layer of carbon atoms). Our simulations show that the patterns alter the structure of water and the accumulation of ions at the liquid-solid interfaces. Using aqueous NaCl solutions, we found that while the capacitance calculated for three positively charged electrodes did not change much, that calculated for the negatively charged electrodes significantly increased upon patterning. We find that both water structure and orientation, as well as ion accumulation affect the capacitance. As electrode patterning affects differently water structure and ion accumulation, it might be possible to observe ion-specific effects. These results could be useful for advancing our understanding of electric double layer capacitors, capacitive desalination processes, as well as of fundamental interfacial electrolytes properties.

  5. Diffuse charge and Faradaic reactions in porous electrodes

    E-Print Network [OSTI]

    Biesheuvel, P. M.

    Porous electrodes instead of flat electrodes are widely used in electrochemical systems to boost storage

  6. High productivity injection practices at Rouge Steel

    SciTech Connect (OSTI)

    Barker, D.H.; Hegler, G.L.; Falls, C.E. [Rouge Steel Co., Dearborn, MI (United States)

    1995-12-01T23:59:59.000Z

    Rouge Steel Company, located in Dearborn, Michigan, operates two blast furnaces. The smaller of the pair, ``B`` Furnace, has a hearth diameter of 20 feet and 12 tuyeres. It has averaged 2,290 NTHM (net ton of hot metal) per day of 8.2 NTHM per 100 cubic feet of working volume. ``C`` Furnace has a hearth diameter of 29 feet and 20 tuyeres. Both of these furnaces are single tap hole furnaces. Prior to its reline in 1991, ``C`` Furnace was producing at a rate of 3,300 NTHM/day or about 6.25 NTHM/100 cfwv. In November, 1994 it averaged 5,106 NTHM/day or 9.6 NTHM/100 cfwv. This paper discusses how the current production rates were achieved. Also, the areas that needed to be addressed as production increased will be described. These areas include casthouse arrangement and workload, hot metal ladle capacity, slag pot capacity and charging capability. Coupled with the high blast temperature capability, the furnace was provided with a new natural gas injection system that injected the gas through the blowpipes and a natural gas injection system to enrich the stove gas. Following the furnace reline, natural gas has been used in three ways: tuyere level control; combination injection; and stove gas enrichment. Coke consumption rate has also decreased per NTHM.

  7. Numerical analysis of a microwave torch with axial gas injection

    SciTech Connect (OSTI)

    Gritsinin, S. I.; Davydov, A. M.; Kossyi, I. A., E-mail: kossyi@fpl.gpi.ru [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation); Kulumbaev, E. B. [National Research University Belgorod State University (Russian Federation)] [National Research University Belgorod State University (Russian Federation); Lelevkin, V. M. [Kyrgyz-Russian Slavic University (Kyrgyzstan)] [Kyrgyz-Russian Slavic University (Kyrgyzstan)

    2013-07-15T23:59:59.000Z

    The characteristics of a microwave discharge in an argon jet injected axially into a coaxial channel with a shortened inner electrode are numerically analyzed using a self-consistent equilibrium gas-dynamic model. The specific features of the excitation and maintenance of the microwave discharge are determined, and the dependences of the discharge characteristics on the supplied electromagnetic power and gas flow rate are obtained. The calculated results are compared with experimental data.

  8. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Chung, Sung-Yoon; Bloking, Jason T; Andersson, Anna M

    2014-10-07T23:59:59.000Z

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z, or (A.sub.1-aM''.sub.a).sub.xM'.sub.y(X.sub.2D.sub.7).sub.z. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001electrodes and storage batteries.

  9. Tevatron injection timing

    SciTech Connect (OSTI)

    Saritepe, S.; Annala, G.

    1993-06-01T23:59:59.000Z

    Bunched beam transfer from one accelerator to another requires coordination and synchronization of many ramped devices. During collider operation timing issues are more complicated since one has to switch from proton injection devices to antiproton injection devices. Proton and antiproton transfers are clearly distinct sequences since protons and antiprotons circulate in opposite directions in the Main Ring (MR) and in the Tevatron. The time bumps are different, the kicker firing delays are different, the kickers and lambertson magnets are different, etc. Antiprotons are too precious to be used for tuning purposes, therefore protons are transferred from the Tevatron back into the Main Ring, tracing the path of antiprotons backwards. This tuning operation is called ``reverse injection.`` Previously, the reverse injection was handled in one supercycle. One batch of uncoalesced bunches was injected into the Tevatron and ejected after 40 seconds. Then the orbit closure was performed in the MR. In the new scheme the lambertson magnets have to be moved and separator polarities have to be switched, activities that cannot be completed in one supercycle. Therefore, the reverse injection sequence was changed. This involved the redefinition of TVBS clock event $D8 as MRBS $D8 thus making it possible to inject 6 proton batches (or coalesced bunches) and eject them one at a time on command, performing orbit closure each time in the MR. Injection devices are clock event driven. The TCLK is used as the reference clock. Certain TCLK events are triggered by the MR beam synchronized clock (MRBS) events. Some delays are measured in terms of MRBS ticks and MR revolutions. See Appendix A for a brief description of the beam synchronized clocks.

  10. Transonic Combustion ? - Injection Strategy Development for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transonic Combustion - Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine Transonic Combustion - Injection Strategy...

  11. Nonequilibrium Thermodynamics of Porous Electrodes

    E-Print Network [OSTI]

    Ferguson, Todd Richard

    We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic ...

  12. Composite substrate for bipolar electrodes

    DOE Patents [OSTI]

    Tekkanat, Bora (Milwaukee, WI); Bolstad, James J. (Shorewood, WI)

    1992-12-22T23:59:59.000Z

    Substrates for electrode systems, particularly those to be used for bipolar electrodes in zinc-bromine batteries, are disclosed. The substrates preferably include carbon-black as a conductive filler in a polymeric matrix, with reinforcing materials such as glass fibers. Warpage of the zinc-bromine electrodes which was experienced in the prior art and which was believed to be caused by physical expansion of the electrodes due to bromine absorption by the carbon-black, is substantially eliminated when new substrate fabrication techniques are employed. In the pesent invention, substrates are prepared using a lamination process known as glass mat reinforced thermoplastics technology or, in an alternate embodiment, the substrate is made using a slurry process.

  13. Composite substrate for bipolar electrodes

    DOE Patents [OSTI]

    Tekkanat, B.; Bolstad, J.J.

    1992-12-22T23:59:59.000Z

    Substrates for electrode systems, particularly those to be used for bipolar electrodes in zinc-bromine batteries, are disclosed. The substrates preferably include carbon-black as a conductive filler in a polymeric matrix, with reinforcing materials such as glass fibers. Warpage of the zinc-bromine electrodes which was experienced in the prior art and which was believed to be caused by physical expansion of the electrodes due to bromine absorption by the carbon-black, is substantially eliminated when new substrate fabrication techniques are employed. In the present invention, substrates are prepared using a lamination process known as glass mat reinforced thermoplastics technology or, in an alternate embodiment, the substrate is made using a slurry process. 4 figs.

  14. ATOMISTIC MODELING OF ELECTRODE MATERIALS

    Broader source: Energy.gov (indexed) [DOE]

    life and rate * High cost of electrode materials * Project lead: Venkat Srinivasan (LBNL) * Marca Doeff (LBNL): Al-substituted layered Li-TM-O 2 * Phil Ross (LBNL) and Gerbrand...

  15. Atomistic Modeling of Electrode Materials

    Broader source: Energy.gov (indexed) [DOE]

    and rate * High cost of electrode materials * Project lead: John Newman * Marca Doeff (LBNL) on layered Li-TM-O 2 for effects of Al substitution * Phil Ross (LBNL) on nano-LiFePO...

  16. ENVIRONMENTAL MONITORING OF LEAKS USING TIME LAPSED LONG ELECTRODE ELECTRICAL RESISTIVITY

    SciTech Connect (OSTI)

    MYERS DA; RUCKER DF; FINK JB; LOKE MH

    2009-12-16T23:59:59.000Z

    Highly industrialized areas pose challenges for surface electrical resistivity characterization due to metallic infrastructure. The infrastructure is typically more conductive than the desired targets and will mask the deeper subsurface information. These challenges may be minimized if steel-cased wells are used as long electrodes in the area near the target. We demonstrate a method of using long electrodes to electrically monitor a simulated leak from an underground storage tank with both synthetic examples and a field demonstration. The synthetic examples place a simple target of varying electrical properties beneath a very low resistivity layer. The layer is meant to replicate the effects of infrastructure. Both surface and long electrodes are tested on the synthetic domain. The leak demonstration for the field experiment is simulated by injecting a high conductivity fluid in a perforated well within the S tank farm at Hanford, and the resistivity measurements are made before and after the leak test. All data are processed in four dimensions, where a regularization procedure is applied in both the time and space domains. The synthetic test case shows that the long electrode ERM could detect relative changes in resistivity that are commensurate with the differing target properties. The surface electrodes, on the other hand, had a more difficult time matching the original target's footprint. The field results shows a lowered resistivity feature develop south of the injection site after cessation of the injections. The time lapsed regularization parameter has a strong influence on the differences in inverted resistivity between the pre and post injection datasets, but the interpretation of the target is consistent across all values of the parameter. The long electrode ERM method may provide a tool for near real-time monitoring of leaking underground storage tanks.

  17. Optimization of Injection Scheduling in

    E-Print Network [OSTI]

    Stanford University

    SGP-TR-I12 Optimization of Injection Scheduling in Geothermal Fields James Lovekin May 1987&injection optimization problem is broke$ into two subpmbkm:(1) choosing a configuration of injectorsfrom an existing set is defined as the fieldwide break- through lindex, B. Injection is optimized by choosing injection wells

  18. Electrode-based approach for monitoring in situ microbial activity during subsurface bioremediation

    SciTech Connect (OSTI)

    Williams, Kenneth H.; Nevin, Kelly P.; Franks, Ashley; Englert, Andreas L.; Long, Philip E.; Lovley, Derek R.

    2010-01-01T23:59:59.000Z

    Current production by microorganisms colonizing subsurface electrodes and its relationship to substrate availability and microbial activity was evaluated in an aquifer undergoing bioremediation. Borehole graphite anodes were installed downgradient from a region of acetate injection designed to stimulate bioreduction of U(VI); cathodes consisted of graphite electrodes embedded at the ground surface. Significant increases in current density (?50 mA/m2) tracked delivery of acetate to the electrodes, dropping rapidly when acetate inputs were discontinued. An upgradient control produced low, steady currents (?0.2 mA/m2). Elevated current was strongly correlated with uranium removal but minimal correlation existed with elevated Fe(II). Confocal laser scanning microscopy of electrodes revealed firmly attached biofilms, and analysis of 16S rRNA gene sequences indicated the electrode surfaces were dominated (67-80%) by Geobacter species. These results suggest that oxidation of acetate coupled to electron transfer to electrodes by Geobacter species was the primary source of current. This is the first demonstration that electrodes can produce readily detectable currents despite long-range (6 m) separation of anode and cathode and that current levels are likely related to rates of subsurface metabolism. It is expected that current production may serve as an effective proxy for monitoring in situ microbial activity in a variety of subsurface anoxic environments.

  19. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming (Framingham, MA); Chung, Sung-Yoon (Seoul, KR); Bloking, Jason T. (Cambridge, MA); Andersson, Anna M. (Uppsala, SE)

    2008-03-18T23:59:59.000Z

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z(A.sub.1-aM''.sub.a).s- ub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  20. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming (Framingham, MA); Chung, Sung-Yoon (Incheon, KR); Bloking, Jason T. (Mountain View, CA); Andersson, Anna M. (Vasteras, SE)

    2012-04-03T23:59:59.000Z

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z (A.sub.1-aM''.sub.a).sub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  1. Pellet injection technology

    SciTech Connect (OSTI)

    Combs, S.K. (Oak Ridge National Laboratory, P.O. Box 2009, Oak Ridge, Tennessee 37831-8071 (United States))

    1993-07-01T23:59:59.000Z

    During the last 10 to 15 years, significant progress has been made worldwide in the area of pellet injection technology. This specialized field of research originated as a possible solution to the problem of depositing atoms of fuel deep within magnetically confined, hot plasmas for refueling of fusion power reactors. Using pellet injection systems, frozen macroscopic (millimeter-size) pellets composed of the isotopes of hydrogen are formed, accelerated, and transported to the plasma for fueling. The process and benefits of plasma fueling by this approach have been demonstrated conclusively on a number of toroidal magnetic confinement configurations; consequently, pellet injection is the leading technology for deep fueling of magnetically confined plasmas for controlled thermonuclear fusion research. Hydrogen pellet injection devices operate at very low temperatures ([congruent]10 K) at which solid hydrogen ice can be formed and sustained. Most injectors use conventional pneumatic (light gas gun) or centrifuge (mechanical) acceleration concepts to inject hydrogen or deuterium pellets at speeds of [congruent]1--2 km/s. Pellet injectors that can operate at quasi-steady state (pellet delivery rates of 1--40 Hz) have been developed for long-pulse fueling. The design and operation of injectors with the heaviest hydrogen isotope, tritium, offer some special problems because of tritium's radioactivity. To address these problems, a proof-of-principle experiment was carried out in which tritium pellets were formed and accelerated to speeds of 1.4 km/s. Tritium pellet injection is scheduled on major fusion research devices within the next few years. Several advanced accelerator concepts are under development to increase the pellet velocity. One of these is the two-stage light gas gun, for which speeds of slightly over 4 km/s have already been reported in laboratory experiments with deuterium ice.

  2. Heat transfer and film cooling with steam injection

    E-Print Network [OSTI]

    Conklin, Gary Eugene

    1982-01-01T23:59:59.000Z

    . The cooling medium was injected through the side of the test section into the blade. The apparatus and test section are shown in Figure 3. Great care was taken in the design of the wind tunnel which was designed to be subsonic with uniform flow and a low... 48 inch overall length. The blade was positioned 24 inches from the leading edge of the test section. D. Test Material The aluminum blade was a straight airfoil with a cir- cular leading edge and three staggered rows of injection holes. Using...

  3. Control of edge effects of oxidant electrode

    DOE Patents [OSTI]

    Carr, Peter (Utica, MI); Chi, Chen H. (Sterling Heights, MI)

    1981-09-08T23:59:59.000Z

    Described is an electrode assembly comprising; a. a porous electrode having a first and second exterior face with a cavity formed in the interior between said exterior faces thereby having first and second interior faces positioned opposite the first and second exterior faces; b. a counter electrode positioned facing each of the first and second exterior faces of the porous electrode; c. means for passing an oxidant through said porous electrode; and d. screening means for blocking the interior face of the porous electrode a greater amount than the blocking of the respective exterior face of the porous electrode, thereby maintaining a differential of oxidant electrode surface between the interior face and the exterior face. The electrode assembly is useful in a metal, halogen, halogen hydrate electrical energy storage device.

  4. Polymer and small molecule based hybrid light source

    DOE Patents [OSTI]

    Choong, Vi-En (Carlsbad, CA); Choulis, Stelios (Nuremberg, DE); Krummacher, Benjamin Claus (Regensburg, DE); Mathai, Mathew (Monroeville, PA); So, Franky (Gainesville, FL)

    2010-03-16T23:59:59.000Z

    An organic electroluminescent device, includes: a substrate; a hole-injecting electrode (anode) coated over the substrate; a hole injection layer coated over the anode; a hole transporting layer coated over the hole injection layer; a polymer based light emitting layer, coated over the hole transporting layer; a small molecule based light emitting layer, thermally evaporated over the polymer based light emitting layer; and an electron-injecting electrode (cathode) deposited over the electroluminescent polymer layer.

  5. Hierarchical electrode architectures for electrical energy storage & conversion.

    SciTech Connect (OSTI)

    Zavadil, Kevin Robert; Missert, Nancy A.; Shelnutt, John Allen; van Swol, Frank B.

    2012-01-01T23:59:59.000Z

    The integration and stability of electrocatalytic nanostructures, which represent one level of porosity in a hierarchical structural scheme when combined with a three-dimensional support scaffold, has been studied using a combination of synthetic processes, characterization techniques, and computational methods. Dendritic platinum nanostructures have been covalently linked to common electrode surfaces using a newly developed chemical route; a chemical route equally applicable to a range of metals, oxides, and semiconductive materials. Characterization of the resulting bound nanostructure system confirms successful binding, while electrochemistry and microscopy demonstrate the viability of these electroactive particles. Scanning tunneling microscopy has been used to image and validate the short-term stability of several electrode-bound platinum dendritic sheet structures toward Oswald ripening. Kinetic Monte Carlo methods have been applied to develop an understanding of the stability of the basic nano-scale porous platinum sheets as they transform from an initial dendrite to hole containing sheets. Alternate synthetic strategies were pursued to grow dendritic platinum structures directly onto subunits (graphitic particles) of the electrode scaffold. A two-step photocatalytic seeding process proved successful at generating desirable nano-scale porous structures. Growth in-place is an alternate strategy to the covalent linking of the electrocatalytic nanostructures.

  6. Method for manufacturing magnetohydrodynamic electrodes

    DOE Patents [OSTI]

    Killpatrick, D.H.; Thresh, H.R.

    1980-06-24T23:59:59.000Z

    A method of manufacturing electrodes for use in a magnetohydrodynamic (MHD) generator is described comprising the steps of preparing a billet having a core of a first metal, a tubular sleeve of a second metal, and an outer sheath of an extrusile metal; evacuating the space between the parts of the assembled billet; extruding the billet; and removing the outer jacket. The extruded bar may be made into electrodes by cutting and bending to the shape required for an MHD channel frame. The method forms a bond between the first metal of the core and the second metal of the sleeve strong enough to withstand a hot and corrosive environment.

  7. Reference electrode for electrolytic cell

    DOE Patents [OSTI]

    Kessie, R.W.

    1988-07-28T23:59:59.000Z

    A reference electrode device is provided for a high temperature electrolytic cell used to electrolytically recover uranium from spent reactor fuel dissolved in an anode pool, the device having a glass tube to enclose the electrode and electrolyte and serve as a conductive membrane with the cell electrolyte, and an outer metal tube about the glass tube to serve as a shield and basket for any glass sections broken by handling of the tube to prevent their contact with the anode pool, the metal tube having perforations to provide access between the bulk of the cell electrolyte and glass membrane. 4 figs.

  8. Nanoengineered membrane electrode assembly interface

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A

    2013-08-06T23:59:59.000Z

    A membrane electrode structure suitable for use in a membrane electrode assembly (MEA) that comprises membrane-affixed metal nanoparticles whose formation is controlled by a photochemical process that controls deposition of the metal nanoparticles using a photocatalyst integrated with a polymer electrolyte membrane, such as an ionomer membrane. Impregnation of the polymer membrane with the photocatalyst prior to metal deposition greatly reduces the required amount of metal precursor in the deposition reaction solution by restricting metal reduction substantially to the formation of metal nanoparticles affixed on or near the surface of the polymer membrane with minimal formation of metallic particles not directly associated with the membrane.

  9. Coupled-wave theory of multiple-stripe semiconductor injection lasers

    SciTech Connect (OSTI)

    Mehuys, D.; Yariv, A.

    1988-07-01T23:59:59.000Z

    We apply coupled-wave theory to describe the lateral modes of semiconductor lasers with a periodic gain and refractive-index variation across their widths. The model is relevant to devices whose complex index of refraction is determined by current injection from closely spaced parallel electrodes. Good agreement is observed between the analytical modes and those computed numerically for comparison.

  10. "Analysis of SOFCs using reference electrodes?

    SciTech Connect (OSTI)

    Finklea, Harry; Chen,Xiaoke; Gerdes,Kirk; Pakalapati, Suryanarayana; Celik, Ismail

    2013-07-01T23:59:59.000Z

    Reference electrodes are frequently applied to isolate the performance of one electrode in a solid oxide fuel cell. However, reference electrode simulations raise doubt to veracity of data collected using reference electrodes. The simulations predict that the reported performance for the one electrode will frequently contain performance of both electrodes. Nonetheless, recent reports persistently treat data so collected as ideally isolated. This work confirms the predictions of the reference electrode simulations on two SOFC designs, and to provides a method of validating the data measured in the 3-electrode configuration. Validation is based on the assumption that a change in gas composition to one electrode does not affect the impedance of the other electrode at open circuit voltage. This assumption is supported by a full physics simulation of the SOFC. Three configurations of reference electrode and cell design are experimentally examined using various gas flows and two temperatures. Impedance data are subjected to deconvolution analysis and equivalent circuit fitting and approximate polarization resistances of the cathode and anode are determined. The results demonstrate that the utility of reference electrodes is limited and often wholly inappropriate. Reported impedances and single electrode polarization values must be scrutinized on this basis.

  11. Injection-controlled laser resonator

    DOE Patents [OSTI]

    Chang, J.J.

    1995-07-18T23:59:59.000Z

    A new injection-controlled laser resonator incorporates self-filtering and self-imaging characteristics with an efficient injection scheme. A low-divergence laser signal is injected into the resonator, which enables the injection signal to be converted to the desired resonator modes before the main laser pulse starts. This injection technique and resonator design enable the laser cavity to improve the quality of the injection signal through self-filtering before the main laser pulse starts. The self-imaging property of the present resonator reduces the cavity induced diffraction effects and, in turn, improves the laser beam quality. 5 figs.

  12. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Warner, Kathryn A. (Bryan, TX)

    1999-01-01T23:59:59.000Z

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

  13. Metal stub and ceramic body electrode assembly

    DOE Patents [OSTI]

    Rolf, R.L.

    1984-05-22T23:59:59.000Z

    An electrically conductive ceramic electrode body having an opening therein is threadably engaged with a metal stub having at least a slot therein to provide space for expansion of the stub without damage to the electrode body. 3 figs.

  14. Sheet electrode for electrochemical systems

    DOE Patents [OSTI]

    Tsien, Hsue C. (Chatham Township, Morris County, NJ); Newby, Kenneth R. (Berkeley Heights, NJ); Grimes, Patrick G. (Westfield, NJ); Bellows, Richard J. (Westfield, NJ)

    1983-04-12T23:59:59.000Z

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  15. Multiple input electrode gap controller

    DOE Patents [OSTI]

    Hysinger, C.L.; Beaman, J.J.; Melgaard, D.K.; Williamson, R.L.

    1999-07-27T23:59:59.000Z

    A method and apparatus for controlling vacuum arc remelting (VAR) furnaces by estimation of electrode gap based on a plurality of secondary estimates derived from furnace outputs. The estimation is preferably performed by Kalman filter. Adaptive gain techniques may be employed, as well as detection of process anomalies such as glows. 17 figs.

  16. Multiple input electrode gap controller

    DOE Patents [OSTI]

    Hysinger, Christopher L. (Austin, TX); Beaman, Joseph J. (Austin, TX); Melgaard, David K. (Albuquerque, NE); Williamson, Rodney L. (Albuquerque, NE)

    1999-01-01T23:59:59.000Z

    A method and apparatus for controlling vacuum arc remelting (VAR) furnaces by estimation of electrode gap based on a plurality of secondary estimates derived from furnace outputs. The estimation is preferably performed by Kalman filter. Adaptive gain techniques may be employed, as well as detection of process anomalies such as glows.

  17. Drop short control of electrode gap

    DOE Patents [OSTI]

    Fisher, Robert W. (Albuquerque, NM); Maroone, James P. (Albuquerque, NM); Tipping, Donald W. (Albuquerque, NM); Zanner, Frank J. (Sandia Park, NM)

    1986-01-01T23:59:59.000Z

    During vacuum consumable arc remelting the electrode gap between a consumable electrode and a pool of molten metal is difficult to control. The present invention monitors drop shorts by detecting a decrease in the voltage between the consumable electrode and molten pool. The drop shorts and their associated voltage reductions occur as repetitive pulses which are closely correlated to the electrode gap. Thus, the method and apparatus of the present invention controls electrode gap based upon drop shorts detected from the monitored anode-cathode voltage. The number of drop shorts are accumulated, and each time the number of drop shorts reach a predetermined number, the average period between drop shorts is calculated from this predetermined number and the time in which this number is accumulated. This average drop short period is used in a drop short period electrode gap model which determines the actual electrode gap from the drop short. The actual electrode gap is then compared with a desired electrode gap which is selected to produce optimum operating conditions and the velocity of the consumable error is varied based upon the gap error. The consumable electrode is driven according to any prior art system at this velocity. In the preferred embodiment, a microprocessor system is utilized to perform the necessary calculations and further to monitor the duration of each drop short. If any drop short exceeds a preset duration period, the consumable electrode is rapidly retracted a predetermined distance to prevent bonding of the consumable electrode to the molten remelt.

  18. Minimizing electrode contamination in an electrochemical cell

    DOE Patents [OSTI]

    Kim, Yu Seung; Zelenay, Piotr; Johnston, Christina

    2014-12-09T23:59:59.000Z

    An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

  19. Underground Injection Control (West Virginia)

    Broader source: Energy.gov [DOE]

    This rule set forth criteria and standards for the requirements which apply to the State Underground Injection Control Program (U.I.C.). The UIC permit program regulates underground injections by...

  20. Alkaline flooding injection strategy

    SciTech Connect (OSTI)

    French, T.R.; Josephson, C.B.

    1992-03-01T23:59:59.000Z

    The objective of this project is to improved alkali-surfactant flooding methods, and this includes determining the proper design of injection strategy. Several different injection strategies have been used or suggested for recovering heavy oils with surfactant-enhanced alkaline flooding methods. Oil recovery was compared for four different injection strategies: (1) surfactant followed by polymer, (2) surfactant followed by alkaline polymer, (3) alkaline surfactant followed by polymer, and (4) alkali, surfactant, and polymer mixed in a single formulation. The effect of alkaline preflush was also studied under two different conditions. All of the oil recovery experiments were conducted under optimal conditions with a viscous, non-acidic oil from Hepler (KS) oil field. The coreflood experiments were conducted with Berea sandstone cores since field core was not available in sufficient quantity for coreflood tests. The Tucker sand of Hepler field is a Class I fluvial dominated deltaic reservoir, as classified by the Department of Energy, which has been selected as the site of a DOE-sponsored field pilot test.

  1. ELECTRONIC FUEL INJECTION DIESEL LOCOMOTIVES

    E-Print Network [OSTI]

    Jagannatham, Aditya K.

    ELECTRONIC FUEL INJECTION FOR DIESEL LOCOMOTIVES 13 August, 2011 Diesel Loco Modernisation Works, Patiala #12;ELECTRONIC FUEL INJECTION FOR DIESEL LOCOMOTIVES A Milestone in Green Initiatives by Indian Diesel Locomotive equipped with "Electronic Fuel Injection (EFI)" was turned out by the Diesel Loco

  2. Long life lithium batteries with stabilized electrodes

    DOE Patents [OSTI]

    Amine, Khalil (Downers Grove, IL); Liu, Jun (Naperville, IL); Vissers, Donald R. (Naperville, IL); Lu, Wenquan (Darien, IL)

    2009-03-24T23:59:59.000Z

    The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In some embodiments the additives include a substituted or unsubstituted cyclic or spirocyclic hydrocarbon containing at least one oxygen atom and at least one alkenyl or alkynyl group. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes or olivine or carbon-coated olivine electrodes, the new electrolytes provide batteries with improved calendar and cycle life.

  3. Influence of electron injection into 27 cm audio plasma cell on the plasma diagnostics

    SciTech Connect (OSTI)

    Haleem, N. A.; Ragheb, M. S.; Zakhary, S. G. [Accelerators Department, Nuclear Research Center, AEA, Cairo 13759 (Egypt)] [Accelerators Department, Nuclear Research Center, AEA, Cairo 13759 (Egypt); El Fiki, S. A.; Nouh, S. A. [Faculty of Science, Ain Shams University, Cairo 11566 (Egypt)] [Faculty of Science, Ain Shams University, Cairo 11566 (Egypt); El Disoki, T. M. [Faculty of Girls, Ain Shams University, Cairo 11566 (Egypt)] [Faculty of Girls, Ain Shams University, Cairo 11566 (Egypt)

    2013-08-15T23:59:59.000Z

    In this article, the plasma is created in a Pyrex tube (L = 27 cm, ?= 4 cm) as a single cell, by a capacitive audio frequency (AF) discharge (f = 10–100 kHz), at a definite pressure of ?0.2 Torr. A couple of tube linear and deviating arrangements show plasma characteristic conformity. The applied AF plasma and the injection of electrons into two gas mediums Ar and N{sub 2} revealed the increase of electron density at distinct tube regions by one order to attain 10{sup 13}/cm{sup 3}. The electrons temperature and density strengths are in contrast to each other. While their distributions differ along the plasma tube length, they show a decaying sinusoidal shape where their peaks position varies by the gas type. The electrons injection moderates electron temperature and expands their density. The later highest peak holds for the N{sub 2} gas, at electrons injection it changes to hold for the Ar. The sinusoidal decaying density behavior generates electric fields depending on the gas used and independent of tube geometry. The effect of the injected electrons performs a responsive impact on electrons density not attributed to the gas discharge. Analytical tools investigate the interaction of the plasma, the discharge current, and the gas used on the electrodes. It points to the emigration of atoms from each one but for greater majority they behave to a preferred direction. Meanwhile, only in the linear regime, small percentage of atoms still moves in reverse direction. Traces of gas atoms revealed on both electrodes due to sheath regions denote lack of their participation in the discharge current. In addition, atoms travel from one electrode to the other by overcoming the sheaths regions occurring transportation of particles agglomeration from one electrode to the other. The electrons injection has contributed to increase the plasma electron density peaks. These electrons populations have raised the generated electrostatic fields assisting the elemental ions emigration to a preferred electrode direction. Regardless of plasma electrodes positions and plasma shape, ions can be departed from one electrode to deposit on the other one. In consequence, as an application the AF plasma type can enhance the metal deposition from one electrode to the other.

  4. Non-Sintered Nickel Electrode

    DOE Patents [OSTI]

    Bernard, Patrick (Massy, FR); Dennig, Corinne (Asnieres sur Seine, FR); Cocciantelli, Jean-Michel (Bordeaux, FR); Alcorta, Jose (Bordeaux, FR); Coco, Isabelle (Dax, FR)

    2002-01-01T23:59:59.000Z

    A non-sintered nickel electrode contains a conductive support and a paste comprising an electrochemically active material containing nickel hydroxide and a binder which is a mixture of an elastomer and a crystalline polymer. The proportion of the elastomer is in the range 25% to 60% by weight of the binder and the proportion of the crystalline polymer is in the range 40% to 75% by weight of the binder.

  5. Injection Laser System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm)HydrogenRFPTri-PartyFor manyInhibiting IndividualInjection

  6. Circumnuclear Media and Accretion Rates of Quiescent Supermassive Black Holes

    E-Print Network [OSTI]

    Generozov, Aleksey; Metzger, Brian D

    2015-01-01T23:59:59.000Z

    We calculate steady-state, one-dimensional hydrodynamic profiles of hot gas in slowly accreting ("quiescent") galactic nuclei for a range of central black hole masses, parameterized gas heating rates, and observationally-motivated stellar density profiles. Mass is supplied to the circumnuclear medium by stellar winds, while energy is injected primarily by stellar winds, supernovae, and black hole feedback. Analytic estimates are derived for the stagnation radius (where the radial velocity of the gas passes through zero) and the black hole accretion rate, as a function of the black hole mass and the gas heating efficiency, the latter being related to the star-formation history. We assess the conditions under which radiative instabilities develop in the hydrostatic region near the stagnation radius, both in the case of a single burst of star formation and for the average star formation history predicted by cosmological simulations. By combining a sample of measured nuclear X-ray luminosities from nearby quiesce...

  7. SiGe quantum dots for fast hole spin Rabi oscillations

    SciTech Connect (OSTI)

    Ares, N.; Prager, A.; De Franceschi, S. [SPSMS/LaTEQS, CEA-INAC/UJF-Grenoble 1, 17 Rue des Martyrs, 38054 Grenoble Cedex 9 (France)] [SPSMS/LaTEQS, CEA-INAC/UJF-Grenoble 1, 17 Rue des Martyrs, 38054 Grenoble Cedex 9 (France); Katsaros, G. [SPSMS/LaTEQS, CEA-INAC/UJF-Grenoble 1, 17 Rue des Martyrs, 38054 Grenoble Cedex 9 (France) [SPSMS/LaTEQS, CEA-INAC/UJF-Grenoble 1, 17 Rue des Martyrs, 38054 Grenoble Cedex 9 (France); Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Johannes Kepler University, Institute of Semiconductor and Solid State Physics, Altenbergerstr. 69, 4040 Linz (Austria); Golovach, V. N. [Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany) [Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Centro de Física de Materiales CFM/MPC (CSIC-UPV/EHU) and Donostia International Physics Center DIPC, E-20018 San Sebastián (Spain); IKERBASQUE, Basque Foundation for Science, E-48011 Bilbao (Spain); Zhang, J. J. [Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany)] [Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Glazman, L. I. [Department of Physics, Yale University, New Haven, Connecticut 06520 (United States)] [Department of Physics, Yale University, New Haven, Connecticut 06520 (United States); Schmidt, O. G. [Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany) [Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Center for Advancing Electronics Dresden, TU Dresden (Germany)

    2013-12-23T23:59:59.000Z

    We report on hole g-factor measurements in three terminal SiGe self-assembled quantum dot devices with a top gate electrode positioned very close to the nanostructure. Measurements of both the perpendicular as well as the parallel g-factor reveal significant changes for a small modulation of the top gate voltage. From the observed modulations, we estimate that, for realistic experimental conditions, hole spins can be electrically manipulated with Rabi frequencies in the order of 100?MHz. This work emphasises the potential of hole-based nano-devices for efficient spin manipulation by means of the g-tensor modulation technique.

  8. Dynamics of black holes

    E-Print Network [OSTI]

    Sean A. Hayward

    2009-02-28T23:59:59.000Z

    This is a review of current theory of black-hole dynamics, concentrating on the framework in terms of trapping horizons. Summaries are given of the history, the classical theory of black holes, the defining ideas of dynamical black holes, the basic laws, conservation laws for energy and angular momentum, other physical quantities and the limit of local equilibrium. Some new material concerns how processes such as black-hole evaporation and coalescence might be described by a single trapping horizon which manifests temporally as separate horizons.

  9. Review of the CRIP (Controlled Retracting Injection Point) process

    SciTech Connect (OSTI)

    Hill, R.W.

    1986-07-01T23:59:59.000Z

    The Lawrence Livermore National Laboratory has been working in the field of underground coal gasification since 1976. We have had a balanced program of modeling, laboratory experiments and field experiments. We have developed several cavity growth and gas composition models. These are designed to be as simple and modular as possible because of the lack of detailed input information and the need to keep computing time low. Our laboratory program is designed to complement and support the modeling effort and the field program. We conducted three field tests at Hoe Creek, Wyoming; each one using a different linking method. We did a series of five small field tests at Centralia, Washington, to study burn cavity development as a function of injection parameters. These were followed a year later by a larger test of the Controlled Retracting Injection Point, or CRIP, process. This concept is used in the design of the Belgian-German test and in the coming Rocky Mountain-1 test. It utilizes injection through a horizontal drilled hole to hold the injection point on the bottom of the seam and a controlled destruction of the injection pipe to move the burn zone when the product gas quality deteriorates. 16 refs., 12 figs.

  10. Premixed direct injection nozzle

    DOE Patents [OSTI]

    Zuo, Baifang (Simpsonville, SC); Johnson, Thomas Edward (Greer, SC); Lacy, Benjamin Paul (Greer, SC); Ziminsky, Willy Steve (Simpsonville, SC)

    2011-02-15T23:59:59.000Z

    An injection nozzle having a main body portion with an outer peripheral wall is disclosed. The nozzle includes a plurality of fuel/air mixing tubes disposed within the main body portion and a fuel flow passage fluidly connected to the plurality of fuel/air mixing tubes. Fuel and air are partially premixed inside the plurality of the tubes. A second body portion, having an outer peripheral wall extending between a first end and an opposite second end, is connected to the main body portion. The partially premixed fuel and air mixture from the first body portion gets further mixed inside the second body portion. The second body portion converges from the first end toward said second end. The second body portion also includes cooling passages that extend along all the walls around the second body to provide thermal damage resistance for occasional flame flash back into the second body.

  11. Silver manganese oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2006-05-09T23:59:59.000Z

    This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

  12. Underground Injection Control Regulations (Kansas)

    Broader source: Energy.gov [DOE]

    This article prohibits injection of hazardous or radioactive wastes into or above an underground source of drinking water, establishes permit conditions and states regulations for design,...

  13. Underground Injection Control Rule (Vermont)

    Broader source: Energy.gov [DOE]

    This rule regulates injection wells, including wells used by generators of hazardous or radioactive wastes, disposal wells within an underground source of drinking water, recovery of geothermal...

  14. Three-Electrode Metal Oxide Reduction Cell

    DOE Patents [OSTI]

    Dees, Dennis W. (Downers Grove, IL); Ackerman, John P. (Downers Grove, IL)

    2005-06-28T23:59:59.000Z

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  15. Three-electrode metal oxide reduction cell

    DOE Patents [OSTI]

    Dees, Dennis W. (Downers Groves, IL); Ackerman, John P. (Downers Grove, IL)

    2008-08-12T23:59:59.000Z

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  16. Semiconductor electrode with improved photostability characteristics

    DOE Patents [OSTI]

    Frank, A.J.

    1985-02-19T23:59:59.000Z

    An electrode is described for use in photoelectrochemical cells having an electrolyte which includes an aqueous constituent. The electrode consists of a semiconductor and a hydrophobic film disposed between the semiconductor and the aqueous constituent. The hydrophobic film is adapted to permit charges to pass therethrough while substantially decreasing the activity of the aqueous constituent at the semiconductor surface thereby decreasing the photodegradation of the semiconductor electrode.

  17. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07T23:59:59.000Z

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  18. Electrode assemblies, plasma apparatuses and systems including electrode assemblies, and methods for generating plasma

    DOE Patents [OSTI]

    Kong, Peter C; Grandy, Jon D; Detering, Brent A; Zuck, Larry D

    2013-09-17T23:59:59.000Z

    Electrode assemblies for plasma reactors include a structure or device for constraining an arc endpoint to a selected area or region on an electrode. In some embodiments, the structure or device may comprise one or more insulating members covering a portion of an electrode. In additional embodiments, the structure or device may provide a magnetic field configured to control a location of an arc endpoint on the electrode. Plasma generating modules, apparatus, and systems include such electrode assemblies. Methods for generating a plasma include covering at least a portion of a surface of an electrode with an electrically insulating member to constrain a location of an arc endpoint on the electrode. Additional methods for generating a plasma include generating a magnetic field to constrain a location of an arc endpoint on an electrode.

  19. Electrode structure and methods of making same

    DOE Patents [OSTI]

    Ruud, James Anthony; Browall, Kenneth Walter; Rehg, Timothy Joseph; Renou, Stephane; Striker, Todd-Michael

    2010-04-06T23:59:59.000Z

    A method of making an electrode structure is provided. The method includes disposing an electrocatalytic material on an electrode, applying heat to the electrocatalytic material to form a volatile oxide of the electrocatalytic material, and applying a voltage to the electrode to reduce the volatile oxide to provide a number of nano-sized electrocatalytic particles on or proximate to a triple phase boundary, where the number of nano-sized electrocatalytic particles is greater on or proximate to the triple phase boundary than in an area that is not on or proximate to the triple phase boundary, and where the triple phase boundary is disposed on the electrode.

  20. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  1. Chemical and Microstructural Effects in Electrode Polarization

    SciTech Connect (OSTI)

    Virkar, A.; Armstrong, T.; Radhakrishman, R.; Ramanan, G.; Zhao, F.; Singhal, S.

    2005-01-28T23:59:59.000Z

    This presentation discusses the chemical and microstructural effects in electrode polarization and a relative comparison of contributions of the various polarizations in anode-supported cells.

  2. Electrically conductive connection for an electrode

    DOE Patents [OSTI]

    Hornack, T.R.; Chilko, R.J.

    1986-09-02T23:59:59.000Z

    An electrically conductive connection for an electrode assembly of an electrolyte cell in which aluminum is produced by electrolysis in a molten salt is described. The electrode assembly comprises an electrode flask and a conductor rod. The flask has a collar above an area of minimum flask diameter. The electrically conductive connection comprises the electrode flask, the conductor rod and a structure bearing against the collar and the conductor rod for pulling the conductor rod into compressive and electrical contact with the flask. 2 figs.

  3. Negative electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Vaughey, John T.; Fransson, Linda M.; Thackeray, Michael M.

    2005-02-15T23:59:59.000Z

    A negative electrode is disclosed for a non-aqueous electrochemical cell. The electrode has an intermetallic compound as its basic structural unit with the formula M.sub.2 M' in which M and M' are selected from two or more metal elements including Si, and the M.sub.2 M' structure is a Cu.sub.2 Sb-type structure. Preferably M is Cu, Mn and/or Li, and M' is Sb. Also disclosed is a non-aqueous electrochemical cell having a negative electrode of the type described, an electrolyte and a positive electrode. A plurality of cells may be arranged to form a battery.

  4. Structured Pillar Electrodes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Structured Pillar Electrodes Brookhaven National Laboratory Contact BNL About This Technology

    ...

  5. Electric filter with movable belt electrode

    DOE Patents [OSTI]

    Bergman, W.

    1983-09-20T23:59:59.000Z

    A method and apparatus for removing airborne contaminants entrained in a gas or airstream includes an electric filter characterized by a movable endless belt electrode, a grounded electrode, and a filter medium sandwiched there between. Inclusion of the movable, endless belt electrode provides the driving force for advancing the filter medium through the filter, and reduces frictional drag on the filter medium, thereby permitting a wide choice of filter medium materials. Additionally, the belt electrode includes a plurality of pleats in order to provide maximum surface area on which to collect airborne contaminants. 4 figs.

  6. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1997-01-01T23:59:59.000Z

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome.

  7. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1997-02-11T23:59:59.000Z

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes is described, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome. 1 fig.

  8. Rotating Hairy Black Holes

    E-Print Network [OSTI]

    B. Kleihaus; J. Kunz

    2000-12-20T23:59:59.000Z

    We construct stationary black holes in SU(2) Einstein-Yang-Mills theory, which carry angular momentum and electric charge. Possessing non-trivial non-abelian magnetic fields outside their regular event horizon, they represent non-perturbative rotating hairy black holes.

  9. Disregarding the 'Hole Argument'

    E-Print Network [OSTI]

    Bryan W. Roberts

    2014-12-17T23:59:59.000Z

    Jim Weatherall has suggested that Einstein's hole argument, as presented by Earman and Norton (1987), is based on a misleading use of mathematics. I argue on the contrary that Weatherall demands an implausible restriction on how mathematics is used. The hole argument, on the other hand, is in no new danger at all.

  10. Common Rail Injection System Development

    SciTech Connect (OSTI)

    Electro-Motive,

    2005-12-30T23:59:59.000Z

    The collaborative research program between the Department of energy and Electro-Motive Diesels, Inc. on the development of common rail fuel injection system for locomotive diesel engines that can meet US EPA Tier 2 exhaust emissions has been completed. This final report summarizes the objectives of the program, work scope, key accomplishments and research findings. The major objectives of this project encompassed identification of appropriate injection strategies by using advanced analytical tools, development of required prototype hardware/controls, investigations of fuel spray characteristics including cavitation phenomena, and validation of hareware using a single-cylinder research locomotive diesel engine. Major milestones included: (1) a detailed modeling study using advanced mathematical models - several various injection profiles that show simultaneous reduction of NOx and particulates on a four stroke-cycle locomotive diesel engine were identified; (2) development of new common rail fuel injection hardware capable of providing these injection profiles while meeting EMD engine and injection performance specifications. This hardware was developed together with EMD's current fuel injection component supplier. (3) Analysis of fuel spray characteristics. Fuel spray numerical studies and high speed photographic imaging analyses were performed. (4) Validation of new hardware and fuel injection profiles. EMD's single-cylinder research diesel engine located at Argonne National Laboratory was used to confirm emissions and performacne predictions. These analytical ane experimental investigations resulted in optimized fuel injection profiles and engine operating conditions that yield reductions in NOx emissions from 7.8 g/bhp-hr to 5.0 g/bhp-hr at full (rated) load. Additionally, hydrocarbon and particulate emissions were reduced considerably when compared to baseline Tier I levels. The most significant finding from the injection optimization process was a 2% to 3% improvement in fuel economy over EMD's traditional Tier I engine hardware configuration. the common rail fuel injection system enabled this added benefit by virtue of an inherent capability to provide multiple injections per power stroke at high fuel rail pressures. On the basis of the findings in this study, EMD concludes that the new electronically-controlled high-pressure common rail injection system has the potential to meet locomotive Tier 2 NOx and particulates emission standards without sacrificing the fuel economy. A number of areas to further improve the injection hardware and engine operating characteristics to further exploit the benefits of common rail injection system have also been identified.

  11. Desalination with carbon aerogel electrodes

    SciTech Connect (OSTI)

    Farmer, J.C.; Richardson, J.H.; Fix, D.V.

    1996-10-21T23:59:59.000Z

    An electrically regenerated electrosorption process known as carbon aerogel CDI was developed for continuously removing ionic impurities from aqueous streams. A salt solution flows in a channel formed by pairs of parallel carbon aerogel electrodes. Each electrode has a very high BET surface area and very low resistivity. After polarization, anions and cations are removed from electrolyte by the electric field and electrosorbed onto the carbon aerogel. The solution is thus separated into two streams, brine and water. Based on this, carbon aerogel CDI appears to be an energy-efficient alternative to evaporation, electrodialysis, and reverse osmosis. The energy required by this process is about QV/2, plus losses. Estimated energy requirement for sea water desalination is 18-27 Wh gal{sup -1}, depending on cell voltage and flow rate. The requirement for brackish water desalination is less, 1.2-2.5 Wh gal{sup -1} at 1600 ppM. This is assuming that stored electrical energy is reclaimed during regeneration.

  12. Adsorption and electrode reactions of disulfonated anthraquinones at mercury electrodes

    SciTech Connect (OSTI)

    He, P.; Crooks, R.M.; Faulkner, L.R. (Univ. of Illinois, Urbana (USA))

    1990-02-08T23:59:59.000Z

    Three sulfonated compounds were examined; 2,6-anthraquinonedisulfonate, sodium salt (2,6-AQDS); 1,5-anthraquinone- disulfonate, sodium salt (1,5-AQDS); and 2-anthraquinonemonosulfonate, sodium salt (2-AQMS). Extensive studies of 2,6-AQDS were carried out. This compound undergoes reversible charge exchange with the electrode in an adsorbed state. Electrocapillary curves show that desorption occurs near -0.8 V vs Ag/AgCl, KCl (1 M). Chronocoulometry and cyclic voltammetry were used to evaluate surface coverage vs the concentration of 2,6-AQDS in 0.1 M HNO{sub 3}. Under all conditions, the adsorbed couple shows a standard potential more positive than that for the couple involving dissolved species; hence, the reduced form is the more strongly adsorbed. Effects of pH were examined extensively. In solutions with 2,6-AQDS concentrations above 2 {times} 10{sup 5} M an extremely sharp, reversible pair of spikes develops in the cyclic voltammetry for the adsorbed couple. The spikes are not seen for 1,5-AQDS, but other aspects of behavior for 1,5-AQDS are similar to those of 2,6-AQDS. The Origin of the spikes is discussed via a model involving hydrogen-bonded aggregates. Extensive exposure of a mercury surface to high concentrations of 2,6-AQDS produces a catalytic effect on the electrode reaction involving the dissolved quinone. Further exposure causes an inhibition of the same process. These effects are attributed to the growth of extended films on the mercury.

  13. Organic conductive films for semiconductor electrodes

    DOE Patents [OSTI]

    Frank, A.J.

    1984-01-01T23:59:59.000Z

    According to the present invention, improved electrodes overcoated with conductive polymer films and preselected catalysts are provided. The electrodes typically comprise an inorganic semiconductor over-coated with a charge conductive polymer film comprising a charge conductive polymer in or on which is a catalyst or charge-relaying agent.

  14. Gas tungsten arc welder with electrode grinder

    DOE Patents [OSTI]

    Christiansen, David W. (Kennewick, WA); Brown, William F. (West Richland, WA)

    1984-01-01T23:59:59.000Z

    A welder for automated closure of fuel pins by a gas tungsten arc process in which a rotating length of cladding is positioned adjacent a welding electrode in a sealed enclosure. An independently movable axial grinder is provided in the enclosure for refurbishing the used electrode between welds.

  15. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, R.J.; Warner, K.A.

    1999-06-01T23:59:59.000Z

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation. 4 figs.

  16. A sensitive enzyme electrode for phenol monitoring

    SciTech Connect (OSTI)

    Kulys, J.; Schmid, R.D. (GBF-Gesellschaft fuer Biotechnologische Forschung mbH, Braunschweig (West Germany))

    1990-01-01T23:59:59.000Z

    Tyrosinase (EC.1.14.18.1) was immobilized onto graphite electrodes, which had been modified with tetracyanoquinodimethane (TCNQ). The response time, 12 or 35 s, was dependent on the enzyme immobilization technique used. The electrodes showed a linear calibration function up to 25 or 65 {mu}M phenol, and a sensitivity of 0.36 or 2.2 A/M was achieved which was also dependent on the enzyme immobilization technique used. The detection limit for phenol was 0.23 {mu}M. The electrodes acted from potentials of {minus}200 to +180 mV (vs. a saturated Ag/AgCl electrode). The electrode signal was independent of pH within the pH range 4.5-6.0. The enzyme electrode responded to phenol (100%), p-cresol (93%) and catechol (330%), but not to o-cresol and L-tyrosine. The electrodes showed a stability for more than one week. The electrodes can be utilized for the sensitive assay of phenol in water.

  17. Means for limiting and ameliorating electrode shorting

    DOE Patents [OSTI]

    Van Konynenburg, Richard A. (Livermore, CA); Farmer, Joseph C. (Tracy, CA)

    1999-01-01T23:59:59.000Z

    A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  18. Means for limiting and ameliorating electrode shorting

    SciTech Connect (OSTI)

    Konynenburg, R.A. van; Farmer, J.C.

    1999-11-09T23:59:59.000Z

    A fuse and filter arrangement is described for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  19. Ionization detector, electrode configuration and single polarity charge detection method

    DOE Patents [OSTI]

    He, Zhong (Ann Arbor, MI)

    1998-01-01T23:59:59.000Z

    An ionization detector, an electrode configuration and a single polarity charge detection method each utilize a boundary electrode which symmetrically surrounds first and second central interlaced and symmetrical electrodes. All of the electrodes are held at a voltage potential of a first polarity type. The first central electrode is held at a higher potential than the second central or boundary electrodes. By forming the first and second central electrodes in a substantially interlaced and symmetrical pattern and forming the boundary electrode symmetrically about the first and second central electrodes, signals generated by charge carriers are substantially of equal strength with respect to both of the central electrodes. The only significant difference in measured signal strength occurs when the charge carriers move to within close proximity of the first central electrode and are received at the first central electrode. The measured signals are then subtracted and compared to quantitatively measure the magnitude of the charge.

  20. Ionization detector, electrode configuration and single polarity charge detection method

    DOE Patents [OSTI]

    He, Z.

    1998-07-07T23:59:59.000Z

    An ionization detector, an electrode configuration and a single polarity charge detection method each utilize a boundary electrode which symmetrically surrounds first and second central interlaced and symmetrical electrodes. All of the electrodes are held at a voltage potential of a first polarity type. The first central electrode is held at a higher potential than the second central or boundary electrodes. By forming the first and second central electrodes in a substantially interlaced and symmetrical pattern and forming the boundary electrode symmetrically about the first and second central electrodes, signals generated by charge carriers are substantially of equal strength with respect to both of the central electrodes. The only significant difference in measured signal strength occurs when the charge carriers move to within close proximity of the first central electrode and are received at the first central electrode. The measured signals are then subtracted and compared to quantitatively measure the magnitude of the charge. 10 figs.

  1. Method and apparatus for injecting particulate media into the ground

    DOE Patents [OSTI]

    Dwyer, Brian P.; Dwyer, Stephen F.; Vigil, Francine S.; Stewart, Willis E.

    2004-12-28T23:59:59.000Z

    An improved method and apparatus for injecting particulate media into the ground for constructing underground permeable reactive barriers, which are used for environmental remediation of subsurface contaminated soil and water. A media injector sub-assembly attached to a triple wall drill string pipe sprays a mixture of active particulate media suspended in a carrier fluid radially outwards from the sub-assembly, at the same time that a mixing fluid is sprayed radially outwards. The media spray intersects the mixing spray at a relatively close distance from the point of injection, which entrains the particulate media into the mixing spray and ensures a uniform and deep dispersion of the active media in the surrounding soil. The media injector sub-assembly can optionally include channels for supplying compressed air to an attached down-the-hole hammer drive assembly for use during drilling.

  2. Influence of electromagnetic radiation on the power balance in a radiofrequency microdischarge with a hollow needle electrode

    SciTech Connect (OSTI)

    Despax, B.; Pascal, O.; Gherardi, N.; Naude, N.; Belinger, A.; Pitchford, L. C.

    2012-10-01T23:59:59.000Z

    This study is focused on the power deposition in microplasma jet discharges generated by application of radiofrequency (RF) excitation to a hollow needle electrode. The plasma jet is initiated at atmospheric pressure in open air with a flow of helium through the electrode. We show that in this configuration, a significant part of the injected power is dissipated in electromagnetic radiation. Many recent works have demonstrated the potential of either cold plasma jets or of RF radiation for applications in medicine, and therefore a source that produces both a cold plasma jet and RF radiation could be of interest.

  3. Fabrication methods for low impedance lithium polymer electrodes

    DOE Patents [OSTI]

    Chern, T.S.; MacFadden, K.O.; Johnson, S.L.

    1997-12-16T23:59:59.000Z

    A process is described for fabricating an electrolyte-electrode composite suitable for high energy alkali metal battery that includes mixing composite electrode materials with excess liquid, such as ethylene carbonate or propylene carbonate, to produce an initial formulation, and forming a shaped electrode therefrom. The excess liquid is then removed from the electrode to compact the electrode composite which can be further compacted by compression. The resulting electrode exhibits at least a 75% lower resistance.

  4. Fabrication methods for low impedance lithium polymer electrodes

    DOE Patents [OSTI]

    Chern, Terry Song-Hsing (Midlothian, VA); MacFadden, Kenneth Orville (Highland, MD); Johnson, Steven Lloyd (Arbutus, MD)

    1997-01-01T23:59:59.000Z

    A process for fabricating an electrolyte-electrode composite suitable for high energy alkali metal battery that includes mixing composite electrode materials with excess liquid, such as ethylene carbonate or propylene carbonate, to produce an initial formulation, and forming a shaped electrode therefrom. The excess liquid is then removed from the electrode to compact the electrode composite which can be further compacted by compression. The resulting electrode exhibits at least a 75% lower resistance.

  5. On Noncommutative Black Holes Thermodynamics

    E-Print Network [OSTI]

    Faizal, Mir; Ulhoa, S C

    2015-01-01T23:59:59.000Z

    In this paper, we will analyze noncommutative deformation of the Schwarzschild black holes and Kerr black holes. We will perform our analysis by relating the commutative and the noncommutative metrics using an Moyal product. We will also analyze the thermodynamics of these noncommutative black hole solutions. We will explicitly derive expression for the corrected entropy and temperature of these black hole solutions.

  6. Injection nozzle for a turbomachine

    DOE Patents [OSTI]

    Uhm, Jong Ho; Johnson, Thomas Edward; Kim, Kwanwoo

    2012-09-11T23:59:59.000Z

    A turbomachine includes a compressor, a combustor operatively connected to the compressor, an end cover mounted to the combustor, and an injection nozzle assembly operatively connected to the combustor. The injection nozzle assembly includes a first end portion that extends to a second end portion, and a plurality of tube elements provided at the second end portion. Each of the plurality of tube elements defining a fluid passage includes a body having a first end section that extends to a second end section. The second end section projects beyond the second end portion of the injection nozzle assembly.

  7. Non-plugging injection valve

    DOE Patents [OSTI]

    Carey, Jr., Henry S. (Wilsonville, AL)

    1985-01-01T23:59:59.000Z

    A valve for injecting fluid into a conduit carrying a slurry subject to separation to form deposits capable of plugging openings into the conduit. The valve comprises a valve body that is sealed to the conduit about an aperture formed through the wall of the conduit to receive the fluid to be injected and the valve member of the valve includes a punch portion that extends through the injection aperture to the flow passage, when the valve is closed, to provide a clear channel into the conduit, when the valve is opened, through deposits which might have formed on portions of the valve adjacent the conduit.

  8. Applications of high-speed dust injection to magnetic fusion

    SciTech Connect (OSTI)

    Wang, Zhehui [Los Alamos National Laboratory; Li, Yangfang [Max Planck Institute for Extraterrestrial Physics, Germany

    2012-08-08T23:59:59.000Z

    It is now an established fact that a significant amount of dust is produced in magnetic fusion devices due to plasma-wall interactions. Dust inventory must be controlled, in particular for the next-generation steady-state fusion machines like ITER, as it can pose significant safety hazards and degrade performance. Safety concerns are due to tritium retention, dust radioactivity, toxicity, and flammability. Performance concerns include high-Z impurities carried by dust to the fusion core that can reduce plasma temperature and may even induce sudden termination of the plasma. We have recognized that dust transport, dust-plasma interactions in magnetic fusion devices can be effectively studied experimentally by injection of dust with known properties into fusion plasmas. Other applications of injected dust include diagnosis of fusion plasmas and edge localized mode (ELM)'s pacing. In diagnostic applications, dust can be regarded as a source of transient neutrals before complete ionization. ELM's pacing is a promising scheme to prevent disruptions and type I ELM's that can cause catastrophic damage to fusion machines. Different implementation schemes are available depending on applications of dust injection. One of the simplest dust injection schemes is through gravitational acceleration of dust in vacuum. Experiments at Los Alamos and Princeton will be described, both of which use piezoelectric shakers to deliver dust to plasma. In Princeton experiments, spherical particles (40 micron) have been dropped in a systematic and reproducible manner using a computer-controlled piezoelectric bending actuator operating at an acoustic (0,2) resonance. The circular actuator was constructed with a 2.5 mm diameter central hole. At resonance ({approx} 2 kHz) an applied sinusoidal voltage has been used to control the flux of particles exiting the hole. A simple screw throttle located {approx}1mm above the hole has been used to set the magnitude of the flux achieved for a given voltage. Particle fluxes ranging from a few tens of particle per second up to thousands of particles per second have been achieved using this simple device. To achieve higher dust injection speed, another key consideration is how to accelerate dust at controlled amount. In addition to gravity, other possible acceleration mechanisms include electrostatic, electromagnetic, gas-dragged, plasma-dragged, and laser-ablation-based acceleration. Features and limitations of the different acceleration methods will be discussed. We will also describe laboratory experiments on dust acceleration.

  9. Lithium Ion Electrode Production NDE and QC Considerations |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Ion Electrode Production NDE and QC Considerations Lithium Ion Electrode Production NDE and QC Considerations Review of Oak Ridge process and QC activities by David Wood,...

  10. Flexible Pillared Graphene-Paper Electrodes for High-Performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flexible Pillared Graphene-Paper Electrodes for High-Performance Electrochemical Supercapacitors. Flexible Pillared Graphene-Paper Electrodes for High-Performance Electrochemical...

  11. Glucose oxidase-graphene-chitosan modified electrode for direct...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxidase-graphene-chitosan modified electrode for direct electrochemistry and glucose sensing. Glucose oxidase-graphene-chitosan modified electrode for direct electrochemistry and...

  12. Hierarchically Porous Graphene as a Lithium-Air Battery Electrode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hierarchically Porous Graphene as a Lithium-Air Battery Electrode. Hierarchically Porous Graphene as a Lithium-Air Battery Electrode. Abstract: Functionalized graphene sheets (FGS)...

  13. Electrochemical Studies of Packed Iron Powder Electrodes: Effects...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Packed Iron Powder Electrodes: Effects of Common Constituents of Natural Waters on Corrosion Electrochemical Studies of Packed Iron Powder Electrodes: Effects of Common...

  14. Intercalation Kinetics and Ion Mobility in Electrode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion Batteries Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced...

  15. Optimization of A Portable Microanalytical System to Reduce Electrode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    System to Reduce Electrode Fouling from Proteins Associated with Biomonitoring of Optimization of A Portable Microanalytical System to Reduce Electrode Fouling from Proteins...

  16. Analysis of the Durability of PEM FC Membrane Electrode Assemblies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications...

  17. DOE Announces Selections for SSL Core Technology (Round 6), Product...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transparent Conductive Hole Injection Electrode for Organic Light-Emitting Diode (OLED) SSL Team Members: Plextronics Inc. Summary: This project seeks to...

  18. Holes in Spectral Lines

    E-Print Network [OSTI]

    Fontana, Peter R.; Srivastava, Rajendra P.

    1973-06-01T23:59:59.000Z

    The decay of an atom in the presence of a static perturbation is investigated. The perturbation couples a decaying state with a nondecaying state. A "hole" appears in the emission line at a frequency equal to the frequency difference between...

  19. NEUTRAL-BEAM INJECTION

    SciTech Connect (OSTI)

    Kunkel, W.B.

    1980-06-01T23:59:59.000Z

    The emphasis in the preceding chapters has been on magnetic confinement of high temperature plasmas. The question of production and heating of such plasmas has been dealt with relatively more briefly. It should not be inferred, however, that these matters must therefore be either trivial or unimportant. A review of the history reveals that in the early days all these aspects of the controlled fusion problem were considered to be on a par, and were tackled simultaneously and with equal vigor. Only the confinement problem turned out to be much more complex than initially anticipated, and richer in challenge to the plasma physicist than the questions of plasma production and heating. On the other hand, the properties of high-temperature plasmas and plasma confinement can only be studied experimentally after the problems of production and of heating to adequate temperatures are solved. It is the purpose of this and the next chapter to supplement the preceding discussions with more detail on two important subjects: neutral-beam injection and radio-frequency heating. These are the major contenders for heating in present and future tokamak and mirror fusion experiments, and even in several proposed reactors. For neutral beams we emphasize here the technology involved, which has undergone a rather remarkable development. The physics of particle and energy deposition in the plasma, and the discussion of the resulting effects on the confined plasma, have been included in previous chapters, and some experimental results are quoted there. Other heating processes of relevance to fusion are mentioned elsewhere in this book, in connection with the experiments where they are used: i.e. ohmic heating, adiabatic compression heating, and alpha-particle heating in Chapter 3 by H.P. Furth; more ohmic heating in Chapter 7, and shock-implosion heating, laser heating, and relativistic-electron beam heating in Chapter 8, both by W. E. Quinn. These methods are relatively straightforward in their physics and their technology, or in any case they are considered to be adequately covered by these other authors.

  20. Adaptive engine injection for emissions reduction

    DOE Patents [OSTI]

    Reitz, Rolf D. (Madison, WI): Sun, Yong (Madison, WI)

    2008-12-16T23:59:59.000Z

    NOx and soot emissions from internal combustion engines, and in particular compression ignition (diesel) engines, are reduced by varying fuel injection timing, fuel injection pressure, and injected fuel volume between low and greater engine loads. At low loads, fuel is injected during one or more low-pressure injections occurring at low injection pressures between the start of the intake stroke and approximately 40 degrees before top dead center during the compression stroke. At higher loads, similar injections are used early in each combustion cycle, in addition to later injections which preferably occur between about 90 degrees before top dead center during the compression stroke, and about 90 degrees after top dead center during the expansion stroke (and which most preferably begin at or closely adjacent the end of the compression stroke). These later injections have higher injection pressure, and also lower injected fuel volume, than the earlier injections.

  1. Do Black Holes Exist?

    E-Print Network [OSTI]

    J. W. Moffat

    1993-02-22T23:59:59.000Z

    The problem of information loss in black hole formation and the associated violations of basic laws of physics, such as conservation of energy, causality and unitarity, are avoided in the nonsymmetric gravitational theory, if the NGT charge of a black hole and its mass satisfy an inequality that does not violate any known experimental data and allows the existence of white dwarfs and neutron stars.

  2. Helical superconducting black holes

    E-Print Network [OSTI]

    Aristomenis Donos; Jerome P. Gauntlett

    2012-05-17T23:59:59.000Z

    We construct novel static, asymptotically $AdS_5$ black hole solutions with Bianchi VII$_0$ symmetry that are holographically dual to superconducting phases in four spacetime dimensions with a helical p-wave order. We calculate the precise temperature dependence of the pitch of the helical order. At zero temperature the black holes have vanishing entropy and approach domain wall solutions that reveal homogenous, non-isotropic dual ground states with emergent scaling symmetry.

  3. Interface modified thermally stable hole transporting layer for efficient organic light emitting diodes

    SciTech Connect (OSTI)

    Grover, Rakhi, E-mail: grover.rakhi@gmail.com [Amity Institute of Advanced Research and Studies (Materials and Devices), Amity University, Noida, Uttar Pradesh 201303 (India); Srivastava, Ritu, E-mail: ritu@mail.nplindia.org; Dagar, Janardan; Kamalasanan, M. N. [Physics of Energy Harvesting Division, CSIR-National Physical Laboratory, CSIR-Network of Institute for Solar Energy (NISE), Dr. K.S. Krishnan Road, New Delhi 110012 (India); Mehta, D. S. [Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016 (India)

    2014-08-14T23:59:59.000Z

    Electrical transport in thermally stable 2, 7-bis [N, N-bis (4-methoxy-phenyl) amino]-9, 9-spirobifluorene (MeO-Spiro-TPD) thin films has been investigated as a function of temperature and organic layer thickness. ITO/MeO-Spiro-TPD interface was found to be injection limited and has been studied in detail to find barrier height for hole injection. The thickness of tetra-fluoro-tetracyano-quinodimethane thin films were optimized to be used as hole injection buffer layer which resulted in switching of charge transport mechanism from injection limited to space charge limited conduction above a critical thickness of 3?nm. Hole mobility has been measured using transient space charge limited conduction (SCLC), field dependent SCLC, and top contact transistor characteristics. The charge carrier transport in interface modified hole only devices was analysed using Gaussian disorder model. The thermal stability of MeO-Spiro-TPD has been investigated by atomic force microscopy and X-ray diffraction studies. The study indicates a thermally stable and highly efficient hole transport material for application in organic semiconductor based devices.

  4. Nanostructured Solid Oxide Fuel Cell Electrodes

    SciTech Connect (OSTI)

    Sholklapper, Tal Zvi

    2007-12-15T23:59:59.000Z

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  5. Hydrodynamic injection with pneumatic valving for microchip electrophoresis with total analyte utilization

    SciTech Connect (OSTI)

    Sun, Xuefei; Kelly, Ryan T.; Danielson, William F.; Agrawal, Nitin; Tang, Keqi; Smith, Richard D.

    2011-04-26T23:59:59.000Z

    A novel hydrodynamic injector that is directly controlled by a pneumatic valve has been developed for reproducible microchip capillary electrophoresis (CE) separations. The poly(dimethylsiloxane) (PDMS) devices used for evaluation comprise a separation channel, a side channel for sample introduction, and a pneumatic valve aligned at the intersection of the channels. A low pressure (? 3 psi) applied to the sample reservoir is sufficient to drive sample into the separation channel. The rapidly actuated pneumatic valve enables injection of discrete sample plugs as small as ~100 pL for CE separation. The injection volume can be easily controlled by adjusting the intersection geometry, the solution back pressure and the valve actuation time. Sample injection could be reliably operated at different frequencies (< 0.1 Hz to >2 Hz) with good reproducibility (peak height relative standard deviation ? 3.6%) and no sampling biases associated with the conventional electrokinetic injections. The separation channel was dynamically coated with a cationic polymer, and FITC-labeled amino acids were employed to evaluate the CE separation. Highly efficient (? 7.0 × 103 theoretical plates for the ~2.4 cm long channel) and reproducible CE separations were obtained. The demonstrated method has numerous advantages compared with the conventional techniques, including repeatable and unbiased injections, no sample waste, high duty cycle, controllable injected sample volume, and fewer electrodes with no need for voltage switching. The prospects of implementing this injection method for coupling multidimensional separations, for multiplexing CE separations and for sample-limited bioanalyses are discussed.

  6. WPCF Underground Injection Control Disposal Permit Evaluation...

    Open Energy Info (EERE)

    WPCF Underground Injection Control Disposal Permit Evaluation and Fact Sheet Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: WPCF Underground Injection...

  7. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, M.; Kaun, T.

    1984-01-20T23:59:59.000Z

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical c

  8. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, Frank A. (Rancho Palos Verdes, CA); Townsend, Carl W. (Los Angeles, CA)

    1989-01-01T23:59:59.000Z

    An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

  9. Redox polymer electrodes for advanced batteries

    DOE Patents [OSTI]

    Gregg, B.A.; Taylor, A.M.

    1998-11-24T23:59:59.000Z

    Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene. 2 figs.

  10. Redox polymer electrodes for advanced batteries

    DOE Patents [OSTI]

    Gregg, Brian A. (Golden, CO); Taylor, A. Michael (Golden, CO)

    1998-01-01T23:59:59.000Z

    Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene.

  11. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Electrodes Print Friday, 26 July 2013 14:18 The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  12. Challenges for Na-ion Negative Electrodes

    E-Print Network [OSTI]

    Chevrier, V. L.

    Na-ion batteries have been proposed as candidates for replacing Li-ion batteries. In this paper we examine the viability of Na-ion negative electrode materials based on Na alloys or hard carbons in terms of volumetric ...

  13. Self-weakening in lithiated graphene electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    weakening in lithiated graphene electrodes Hui Yang a , Xu Huang a , Wentao Liang a , Adri C.T. van Duin b, , Muralikrishna Raju b , Sulin Zhang a, a Department of...

  14. Magnetron cathodes in plasma electrode pockels cells

    DOE Patents [OSTI]

    Rhodes, Mark A. (Pleasanton, CA)

    1995-01-01T23:59:59.000Z

    Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating. pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal.

  15. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S

    2014-02-25T23:59:59.000Z

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  16. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S.

    2012-07-24T23:59:59.000Z

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  17. Field Emission Measurements from Niobium Electrodes

    SciTech Connect (OSTI)

    M. BastaniNejad, P.A. Adderley, J. Clark, S. Covert, J. Hansknecht, C. Hernandez-Garcia, R. Mammei, M. Poelker

    2011-03-01T23:59:59.000Z

    Increasing the operating voltage of a DC high voltage photogun serves to minimize space charge induced emittance growth and thereby preserve electron beam brightness, however, field emission from the photogun cathode electrode can pose significant problems: constant low level field emission degrades vacuum via electron stimulated desorption which in turn reduces photocathode yield through chemical poisoning and/or ion bombardment and high levels of field emission can damage the ceramic insulator. Niobium electrodes (single crystal, large grain and fine grain) were characterized using a DC high voltage field emission test stand at maximum voltage -225kV and electric field gradient > 10MV/m. Niobium electrodes appear to be superior to diamond-paste polished stainless steel electrodes.

  18. Manganese oxide composite electrodes for lithium batteries

    DOE Patents [OSTI]

    Johnson, Christopher S. (Naperville, IL); Kang, Sun-Ho (Naperville, IL); Thackeray, Michael M. (Naperville, IL)

    2009-12-22T23:59:59.000Z

    An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0.5electrode and 0.ltoreq.y<1 in which the Li.sub.2MnO.sub.3 and LiMn.sub.2-yM.sub.yO.sub.4 components have layered and spinel-type structures, respectively, and in which M is one or more metal cations. The electrode is activated by removing lithia, or lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

  19. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, James L. (Pleasanton, CA); Tran, Tri D. (Livermore, CA); Feikert, John H. (Livermore, CA); Mayer, Steven T. (San Leandro, CA)

    1997-01-01T23:59:59.000Z

    Fabrication of conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive dionization, and waste treatment. Electrodes fabricated from low surface area (<50 m.sup.2 /gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon compositives with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to be high surface area carbons, fuel cell electrodes can be produced.

  20. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, J.L.; Tran, T.D.; Feikert, J.H.; Mayer, S.T.

    1997-06-10T23:59:59.000Z

    Fabrication is described for conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive deionization, and waste treatment. Electrodes fabricated from low surface area (<50 m{sup 2}/gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon composites with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to high surface area carbons, fuel cell electrodes can be produced. 1 fig.

  1. LOWER TEMPERATURE ELECTROLYTE AND ELECTRODE MATERIALS

    SciTech Connect (OSTI)

    Keqin Huang

    2003-04-30T23:59:59.000Z

    A thorough literature survey on low-temperature electrolyte and electrode materials for SOFC is given in this report. Thermodynamic stability of selected electrolyte and its chemical compatibility with cathode substrate were evaluated. Preliminary electrochemical characterizations were conducted on symmetrical cells consisting of the selected electrolyte and various electrode materials. Feasibility of plasma spraying new electrolyte material thin-film on cathode substrate was explored.

  2. Negative Electrodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Kinoshita, Kim; Zaghib, Karim

    2001-10-01T23:59:59.000Z

    Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

  3. Electrode immersion depth determination and control in electroslag remelting furnace

    DOE Patents [OSTI]

    Melgaard, David K. (Albuquerque, NM); Beaman, Joseph J. (Austin, TX); Shelmidine, Gregory J. (Tijeras, NM)

    2007-02-20T23:59:59.000Z

    An apparatus and method for controlling an electroslag remelting furnace comprising adjusting electrode drive speed by an amount proportional to a difference between a metric of electrode immersion and a set point, monitoring impedance or voltage, and calculating the metric of electrode immersion depth based upon a predetermined characterization of electrode immersion depth as a function of impedance or voltage.

  4. Membrane-electrode assemblies for electrochemical cells

    DOE Patents [OSTI]

    Swathirajan, Sundararajan (Troy, MI); Mikhail, Youssef M. (Sterling Heights, MI)

    1993-01-01T23:59:59.000Z

    A combination, unitary, membrane and electrode assembly with a solid polymer electrolyte membrane, and first and second electrodes at least partially embedded in opposed surfaces of the membrane. The electrodes each comprise a respective group of finely divided carbon particles, very finely divided catalytic particles supported on internal and external surfaces of the carbon particles and a proton conductive material intermingled with the catalytic and carbon particles. A first group of finely divided carbon particles forming the first electrode has greater water attraction and retention properties, and is more hydrophilic than a second group of carbon particles forming the second electrode. In a preferred method, the membrane electrode assembly of the invention is prepared by forming a slurry of proton conductive material and at least one group of the carbon and catalyst particles. The slurry is applied to the opposed surfaces of the membrane and heated while being pressed to the membrane for a time and at a temperature and compressive load sufficient to embed at least a portion of the particles into the membrane.

  5. Black hole accretion discs

    E-Print Network [OSTI]

    Lasota, Jean-Pierre

    2015-01-01T23:59:59.000Z

    This is an introduction to models of accretion discs around black holes. After a presentation of the non-relativistic equations describing the structure and evolution of geometrically thin accretion discs we discuss their steady-state solutions and compare them to observation. Next we describe in detail the thermal-viscous disc instability model and its application to dwarf novae for which it was designed and its X-ray irradiated-disc version which explains the soft X--ray transients, i.e. outbursting black-hole low-mass X-ray binaries. We then turn to the role of advection in accretion flow onto black holes illustrating its action and importance with a toy model describing both ADAFs and slim discs. We conclude with a presentation of the general-relativistic formalism describing accretion discs in the Kerr space-time.

  6. Electrodic voltages accompanying stimulated bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Williams, K.H.; N'Guessan, A.L.; Druhan, J.; Long, P.E.; Hubbard, S.S.; Lovley, D.R.; Banfield, J.F.

    2009-11-15T23:59:59.000Z

    The inability to track the products of subsurface microbial activity during stimulated bioremediation has limited its implementation. We used spatiotemporal changes in electrodic potentials (EP) to track the onset and persistence of stimulated sulfate-reducing bacteria in a uranium-contaminated aquifer undergoing acetate amendment. Following acetate injection, anomalous voltages approaching -900 mV were measured between copper electrodes within the aquifer sediments and a single reference electrode at the ground surface. Onset of EP anomalies correlated in time with both the accumulation of dissolved sulfide and the removal of uranium from groundwater. The anomalies persisted for 45 days after halting acetate injection. Current-voltage and current-power relationships between measurement and reference electrodes exhibited a galvanic response, with a maximum power density of 10 mW/m{sup 2} during sulfate reduction. We infer that the EP anomalies resulted from electrochemical differences between geochemically reduced regions and areas having higher oxidation potential. Following the period of sulfate reduction, EP values ranged from -500 to -600 mV and were associated with elevated concentrations of ferrous iron. Within 10 days of the voltage decrease, uranium concentrations rebounded from 0.2 to 0.8 {mu}M, a level still below the background value of 1.5 {mu}M. These findings demonstrate that EP measurements provide an inexpensive and minimally invasive means for monitoring the products of stimulated microbial activity within aquifer sediments and are capable of verifying maintenance of redox conditions favorable for the stability of bioreduced contaminants, such as uranium.

  7. Thermodynamical instability of black holes

    E-Print Network [OSTI]

    V. V. Kiselev

    2012-08-07T23:59:59.000Z

    In contrast to Hawking radiation of black hole with a given spacetime structure, we consider a competitive transition due to a heat transfer from a hotter inner horizon to a colder outer horizon of Kerr black hole, that results in a stable thermodynamical state of extremal black hole. In this process, by supposing an emission of gravitational quanta, we calculate the mass of extremal black hole in the final state of transition.

  8. Towards noncommutative quantum black holes

    SciTech Connect (OSTI)

    Lopez-Dominguez, J. C.; Obregon, O.; Sabido, M.; Ramirez, C. [Instituto de Fisica de la Universidad de Guanajuato, P.O. Box E-143, 37150 Leon Gto. (Mexico); Facultad de Ciencias Fisico Matematicas, Universidad Autonoma de Puebla, P.O. Box 1364, 72000 Puebla (Mexico)

    2006-10-15T23:59:59.000Z

    In this paper we study noncommutative black holes. We use a diffeomorphism between the Schwarzschild black hole and the Kantowski-Sachs cosmological model, which is generalized to noncommutative minisuperspace. Through the use of the Feynman-Hibbs procedure we are able to study the thermodynamics of the black hole, in particular, we calculate the Hawking's temperature and entropy for the noncommutative Schwarzschild black hole.

  9. Recommended management practices for operation and closure of shallow injection wells at DOE facilities

    SciTech Connect (OSTI)

    Not Available

    1993-07-01T23:59:59.000Z

    The Safe Drinking Water Act established the Underground Injection Control (UIC) program to ensure that underground injection of wastes does not endanger an underground source of drinking water. Under UIC regulations, an injection well is a hole in the ground, deeper than it is wide, that receives wastes or other fluid substances. Types of injection wells range from deep cased wells to shallow sumps, drywells, and drainfields. The report describes the five classes of UIC wells and summarizes relevant regulations for each class of wells and for the UIC program. The main focus of the report is Class IV and V shallow injection wells. Class IV wells are prohibited and should be closed when they are identified. Class V wells are generally authorized by rule, but EPA or a delegated state may require a permit for a Class V well. This report provides recommendations on sound operating and closure practices for shallow injection wells. In addition the report contains copies of several relevant EPA documents that provide additional information on well operation and closure. Another appendix contains information on the UIC programs in 21 states in which there are DOE facilities discharging to injection wells. The appendix includes the name of the responsible regulatory agency and contact person, a summary of differences between the state`s regulations and Federal regulations, and any closure guidelines for Class IV and V wells.

  10. Improving nickel metal hydride batteries through research in negative electrode corrosion control and novel electrode materials

    E-Print Network [OSTI]

    Alexander, Michael Scott

    1997-01-01T23:59:59.000Z

    The objective of this work is to improve the negative electrode of the metal hydride electrodes. Three areas were investigated: corrosion inhibition through Zn additives to the electrolyte, the use of AB5 and AB2 alloy mixtures, and novel AB2...

  11. Treating refinery wastewaters in microbial fuel cells using separator electrode assembly or spaced electrode configurations

    E-Print Network [OSTI]

    Treating refinery wastewaters in microbial fuel cells using separator electrode assembly or spaced 2013 Available online 5 November 2013 Keywords: Microbial fuel cells Refinery wastewater Biodegradability Separator electrode assembly a b s t r a c t The effectiveness of refinery wastewater (RW

  12. Engineering nanostructured electrodes and fabrication of film electrodes for efficient lithium ion intercalation

    E-Print Network [OSTI]

    Cao, Guozhong

    .1 Lithium ion battery as energy storage device background Energy has been the central focus of human@u.washington.edu Broader context In the new century, clean and renewable energy storage devices have become the fociEngineering nanostructured electrodes and fabrication of film electrodes for efficient lithium ion

  13. Coanda injection system for axially staged low emission combustors

    DOE Patents [OSTI]

    Evulet, Andrei Tristan (Clifton Park, NY); Varatharajan, Balachandar (Cincinnati, OH); Kraemer, Gilbert Otto (Greer, SC); ElKady, Ahmed Mostafa (Niskayuna, NY); Lacy, Benjamin Paul (Greer, SC)

    2012-05-15T23:59:59.000Z

    The low emission combustor includes a combustor housing defining a combustion chamber having a plurality of combustion zones. A liner sleeve is disposed in the combustion housing with a gap formed between the liner sleeve and the combustor housing. A secondary nozzle is disposed along a centerline of the combustion chamber and configured to inject a first fluid comprising air, at least one diluent, fuel, or combinations thereof to a downstream side of a first combustion zone among the plurality of combustion zones. A plurality of primary fuel nozzles is disposed proximate to an upstream side of the combustion chamber and located around the secondary nozzle and configured to inject a second fluid comprising air and fuel to an upstream side of the first combustion zone. The combustor also includes a plurality of tertiary coanda nozzles. Each tertiary coanda nozzle is coupled to a respective dilution hole. The tertiary coanda nozzles are configured to inject a third fluid comprising air, at least one other diluent, fuel, or combinations thereof to one or more remaining combustion zones among the plurality of combustion zones.

  14. Hoe Creek No. 3 - First long-term underground coal gasification experiment with oxygen-steam injection

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    The paper describes the first long-term underground coal gasification experiment with oxygen-steam injection. In the Hoe Creek No. 3 underground experiment, linkage paths were established between the injection and production wells by drilling a horizontal borehole between them near the bottom of the coal seam. The drilled linkage hole was enlarged by reverse burning, and then the forward gasification process was started - first with air injection for one week, then with oxygen-steam injection for the remainder of the experiment. During the oxygen-steam injection period, about 3900 tons of coal were gasified in 47 days, at an average rate of 83 tons per day. The heating value of the dry product gas averaged 218 Btu/scf, suitable for input to a processing plant for upgrading to pipeline quality, which is about 900 Btu/scf.

  15. Inert electrode composition having agent for controlling oxide growth on electrode made therefrom

    DOE Patents [OSTI]

    Ray, Siba P. (Plum Boro, PA)

    1986-01-01T23:59:59.000Z

    An improved inert electrode composition is suitable for use as an inert electrode in the production of metals such as aluminum by the electrolytic reduction of metal oxide or metal salt dissolved in a molten salt bath. The composition comprises one or more metal alloys and metal compounds which may include oxides of the metals comprising the alloy. The alloy and metal compounds are interwoven in a network which provides improved electrical conductivity and mechanical strength while preserving the level of chemical inertness necessary for such an electrode to function satisfactorily. The electrode composition further includes a metal compound dopant which will aid in controlling the thickness of a protective oxide layer on at least the bottom portion of an electrode made therefrom during use.

  16. Inert electrode composition having agent for controlling oxide growth on electrode made therefrom

    DOE Patents [OSTI]

    Ray, S.P.

    1986-04-15T23:59:59.000Z

    An improved inert electrode composition is suitable for use as an inert electrode in the production of metals such as aluminum by the electrolytic reduction of metal oxide or metal salt dissolved in a molten salt bath. The composition comprises one or more metal alloys and metal compounds which may include oxides of the metals comprising the alloy. The alloy and metal compounds are interwoven in a network which provides improved electrical conductivity and mechanical strength while preserving the level of chemical inertness necessary for such an electrode to function satisfactorily. The electrode composition further includes a metal compound dopant which will aid in controlling the thickness of a protective oxide layer on at least the bottom portion of an electrode made therefrom during use. 12 figs.

  17. Laser bottom hole assembly

    DOE Patents [OSTI]

    Underwood, Lance D; Norton, Ryan J; McKay, Ryan P; Mesnard, David R; Fraze, Jason D; Zediker, Mark S; Faircloth, Brian O

    2014-01-14T23:59:59.000Z

    There is provided for laser bottom hole assembly for providing a high power laser beam having greater than 5 kW of power for a laser mechanical drilling process to advance a borehole. This assembly utilizes a reverse Moineau motor type power section and provides a self-regulating system that addresses fluid flows relating to motive force, cooling and removal of cuttings.

  18. Quantum black hole inflation

    E-Print Network [OSTI]

    M. B. Altaie

    2001-05-07T23:59:59.000Z

    In this paper we follow a new approach for particle creation by a localized strong gravitational field. The approach is based on a definition of the physical vacuum drawn from Heisenberg uncertainty principle. Using the fact that the gravitational field red-shifts the frequency modes of the vacuum, a condition on the minimum stregth of the gravitational field required to achieve real particle creation is derived. Application of this requirement on a Schwartzchid black hole resulted in deducing an upper limit on the region, outside the event horizon, where real particles can be created. Using this regional upper limit, and considering particle creation by black holes as a consequence of the Casimir effect, with the assumption that the created quanta are to be added to the initial energy, we deduce a natural power law for the development of the event horizon, and consequently a logarithmic law for the area spectrum of an inflating black hole. Application of the results on a cosmological model shows that if we start with a Planck-dimensional black hole, then through the process of particle creation we end up with a universe having the presently estimated critical density. Such a universe will be in a state of eternal inflation.

  19. Black Holes at Accelerators

    E-Print Network [OSTI]

    Bryan Webber

    2006-04-06T23:59:59.000Z

    In theories with large extra dimensions and TeV-scale gravity, black holes are copiously produced in particle collisions at energies well above the Planck scale. I briefly review some recent work on the phenomenology of this process, with emphasis on theoretical uncertainties and possible strategies for measuring the number of extra dimensions.

  20. -Injection Technology -Geothermal Reservoir Engineering

    E-Print Network [OSTI]

    Stanford University

    Investigator: Roland N. Home September 1985 First Annual Report Department of Energy Contract Number, and the forecasting of field behavior with time. Injection I I Tec hnology is a research area receiving special on geothermal energy. The Program publishes technical reports on all of its research projects. Research findings

  1. -Injection Technology -Geothermal Reservoir Engineering

    E-Print Network [OSTI]

    Stanford University

    For the Period October 1, 1985 through September 30, 1986 DE-ASO7-84ID12529 Stanford Geothermal Program was initiated in fiscal year 1981. The report covers the period from October 1, 1985 through September 30, 1986SGP-TR-107 - Injection Technology - Geothermal Reservoir Engineering Research at Stanford Principal

  2. FINAL REPORT: Transformational electrode drying process

    SciTech Connect (OSTI)

    Claus Daniel, C.; Wixom, M. (A123 Systems, Inc.)

    2013-12-19T23:59:59.000Z

    This report includes major findings and outlook from the transformational electrode drying project performance period from January 6, 2012 to August 1, 2012. Electrode drying before cell assembly is an operational bottleneck in battery manufacturing due to long drying times and batch processing. Water taken up during shipment and other manufacturing steps needs to be removed before final battery assembly. Conventional vacuum ovens are limited in drying speed due to a temperature threshold needed to avoid damaging polymer components in the composite electrode. Roll to roll operation and alternative treatments can increase the water desorption and removal rate without overheating and damaging other components in the composite electrode, thus considerably reducing drying time and energy use. The objective of this project was the development of an electrode drying procedure, and the demonstration of processes with no decrease in battery performance. The benchmark for all drying data was an 80°C vacuum furnace treatment with a residence time of 18 – 22 hours. This report demonstrates an alternative roll to roll drying process with a 500-fold improvement in drying time down to 2 minutes and consumption of only 30% of the energy compared to vacuum furnace treatment.

  3. Positive electrode for electrical energy storage device

    SciTech Connect (OSTI)

    Heredy, L.A.; McCoy, L.R.

    1980-10-14T23:59:59.000Z

    A rechargeable electrical energy storage device is described that includes a spaced-apart negative electrode and positive electrode structures immersed in an electrolyte which is molten at the operating temperature of the device wherein the positive electrode structure comprises a housing for containing a body of electropositive active material, said housing having at least one open face, an electrolyte permeable member affixed to the housing and covering said open face for retaining said active material in said housing and said housing and electrolyte permeable member comprising material selected from the group consisting of steel, nickel, copper and alloys thereof having at least an 8 ..mu..M thick electroless nickel coating thereon. In accordance with the present invention, it has been found that such an electroless nickel coating permits the use of relatively inexpensive conductive materials such as steel, nickel, copper and alloys thereof and provides the corrosion resistance required in the molten electrolyte. The present invention is particularly applicable to electrical energy storage devices which utilize a transition metal chalcogenide as a positive electrode active material and a lithium alloy as the negative electrode active material.

  4. Method for control of edge effects of oxidant electrode

    DOE Patents [OSTI]

    Carr, Peter (Utica, MI); Chi, Chen H. (Sterling Heights, MI)

    1980-12-23T23:59:59.000Z

    Described is an electrode assembly comprising; a. a porous electrode having a first and second exterior face with a cavity formed in the interior between said exterior faces thereby having first and second interior faces positioned opposite the first and second exterior faces; b. a counter electrode positioned facing each of the first and second exterior faces of the porous electrode; c. means for passing an oxidant through said porous electrode; and d. screening means for blocking the interior face of the porous electrode a greater amount than the blocking of the respective exterior face of the porous electrode, thereby maintaining a differential of oxidant electrode surface between the interior face and the exterior face. The electrode assembly is useful in a metal, halogen, halogen hydrate electrical energy storage device.

  5. Sequential injection gas guns for accelerating projectiles

    DOE Patents [OSTI]

    Lacy, Jeffrey M. (Idaho Falls, ID); Chu, Henry S. (Idaho Falls, ID); Novascone, Stephen R. (Idaho Falls, ID)

    2011-11-15T23:59:59.000Z

    Gas guns and methods for accelerating projectiles through such gas guns are described. More particularly, gas guns having a first injection port located proximate a breech end of a barrel and a second injection port located longitudinally between the first injection port and a muzzle end of the barrel are described. Additionally, modular gas guns that include a plurality of modules are described, wherein each module may include a barrel segment having one or more longitudinally spaced injection ports. Also, methods of accelerating a projectile through a gas gun, such as injecting a first pressurized gas into a barrel through a first injection port to accelerate the projectile and propel the projectile down the barrel past a second injection port and injecting a second pressurized gas into the barrel through the second injection port after passage of the projectile and to further accelerate the projectile are described.

  6. Grounding electrode and method of reducing the electrical resistance of soils

    DOE Patents [OSTI]

    Koehmstedt, Paul L. (Richland, WA)

    1980-01-01T23:59:59.000Z

    A first solution of an electrolyte is injected underground into a volume of soil having negative surface charges on its particles. A cationic surfactant suspended in this solution neutralizes these surface charges of the soil particles within the volume. Following the first solution, a cationic asphalt emulsion suspended in a second solution is injected into the volume. The asphalt emulsion diffuses through the volume and electrostatically bonds with additional soil surrounding the volume such that an electrically conductive water repellant shell enclosing the volume is formed. This shell prevents the leaching of electrolyte from the volume into the additional soil. The second solution also contains a dissolved deliquescent salt which draws water into the volume prior to the formation of the shell. When electrically connected to an electrical installation such as a power line tower, the volume constitutes a grounding electrode for the tower.

  7. Mitigation of thermoacoustic instability utilizing steady air injection near the flame anchoring zone

    SciTech Connect (OSTI)

    Murat Altay, H.; Hudgins, Duane E.; Speth, Raymond L.; Annaswamy, Anuradha M.; Ghoniem, Ahmed F. [Massachusetts Institute of Technology, Department of Mechanical Engineering, Cambridge, MA 02139 (United States)

    2010-04-15T23:59:59.000Z

    The objective of this work is to investigate the effectiveness of steady air injection near the flame anchoring zone in suppressing thermoacoustic instabilities driven by flame-vortex interaction mechanism. We perform a systematic experimental study which involves using two different configurations of air injection in an atmospheric pressure backward-facing step combustor. The first configuration utilizes a row of micro-diameter holes allowing for air injection in the cross-stream direction just upstream of the step. The second configuration utilizes an array of micro-diameter holes located on the face of the step, allowing for air injection in the streamwise direction. The effects of each of these configurations are analyzed to determine which one is more effective in suppressing thermoacoustic instabilities at different operating conditions. The tests are conducted while varying the equivalence ratio and the inlet temperature. The secondary air temperature is always the same as the inlet temperature. We used pure propane or propane/hydrogen mixtures as fuels. Combustion dynamics are explored through simultaneous pressure and heat release-rate measurements, and high-speed video images. When the equivalence ratio of the reactant mixture is high, it causes the flame to flashback towards the inlet channel. When air is injected in the cross-stream direction, the flame anchors slightly upstream of the step, which suppresses the instability. When air is injected in the streamwise direction near the edge of step, thermoacoustic instability could be eliminated at an optimum secondary air flow rate, which depends on the operating conditions. When effective, the streamwise air injection prevents the shedding of an unsteady vortex, thus eliminating the flame-vortex interaction mechanism and resulting in a compact, stable flame to form near the step. (author)

  8. Electrochemical cell having cylindrical electrode elements

    DOE Patents [OSTI]

    Nelson, Paul A. (Wheaton, IL); Shimotake, Hiroshi (Hinsdale, IL)

    1982-01-01T23:59:59.000Z

    A secondary, high temperature electrochemical cell especially adapted for lithium alloy negative electrodes, transition metal chalcogenide positive electrodes and alkali metal halide or alkaline earth metal halide electrolyte is disclosed. The cell is held within an elongated cylindrical container in which one of the active materials is filled around the outside surfaces of a plurality of perforate tubular current collectors along the length of the container. Each of the current collector tubes contain a concentric tubular layer of electrically insulative ceramic as an interelectrode separator. The active material of opposite polarity in elongated pin shape is positioned longitudinally within the separator layer. A second electrically conductive tube with perforate walls can be swagged or otherwise bonded to the outer surface of the pin as a current collector and the electrically insulative ceramic layer can be coated or otherwise layered onto the outer surface of this second current collector. Alternatively, the central pin electrode can include an axial core as a current collector.

  9. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

    2008-01-01T23:59:59.000Z

    An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

  10. Electrode supporting base for electrostatic precipitators

    SciTech Connect (OSTI)

    Honacker, H.

    1981-01-20T23:59:59.000Z

    The disclosure relates to a base for supporting hollow cylindrical and circular in cross section collector electrodes for an electrostatic precipitator. The base comprises a central portion and is generally circular; a plurality of arcuate venturi and collector trough assemblies which are generally circular and which intersect radially disposed drain troughs; said venturi and collector trough assemblies being concentric with said center portion of said base and drain troughs extending radially outward from said center portion; a circular wall structure secured to outer ends of said drain troughs; fixture means for securing said collector electrodes on said drain troughs; uppermost portions of said drain troughs and said venturi and collector troughs being substantially flush with each other and said venturi and collector trough assemblies disposed on a common plane to provide for uniform laminar flow relative to the collector electrodes.

  11. Layered electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Johnson; Christopher S. (Naperville, IL), Thackeray; Michael M. (Naperville, IL), Vaughey; John T. (Elmhurst, IL), Kahaian; Arthur J. (Chicago, IL), Kim; Jeom-Soo (Naperville, IL)

    2008-04-15T23:59:59.000Z

    Lithium metal oxide compounds of nominal formula Li.sub.2MO.sub.2, in which M represents two or more positively charged metal ions, selected predominantly and preferably from the first row of transition metals are disclosed herein. The Li.sub.2MO.sub.2 compounds have a layered-type structure, which can be used as positive electrodes for lithium electrochemical cells, or as a precursor for the in-situ electrochemical fabrication of LiMO.sub.2 electrodes. The Li.sub.2MO.sub.2 compounds of the invention may have additional functions in lithium cells, for example, as end-of-discharge indicators, or as negative electrodes for lithium cells.

  12. Manganese oxide composite electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Li, Naichao (Croton on Hudson, NY)

    2007-12-04T23:59:59.000Z

    An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor of a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0electrode is activated by removing lithia, or lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

  13. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, F.A.; Townsend, C.W.

    1989-09-12T23:59:59.000Z

    An electrode apparatus is described which is adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments. 3 figs.

  14. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1999-01-01T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid partides being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  15. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1999-04-27T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  16. Tailored ion energy distributions on plasma electrodes

    SciTech Connect (OSTI)

    Economou, Demetre J. [Plasma Processing Laboratory, Department of Chemical and Biomolecular Engineering, University of Houston, Houston, Texas 77204-4004 (United States)] [Plasma Processing Laboratory, Department of Chemical and Biomolecular Engineering, University of Houston, Houston, Texas 77204-4004 (United States)

    2013-09-15T23:59:59.000Z

    As microelectronic device features continue to shrink approaching atomic dimensions, control of the ion energy distribution on the substrate during plasma etching and deposition becomes increasingly critical. The ion energy should be high enough to drive ion-assisted etching, but not too high to cause substrate damage or loss of selectivity. In many cases, a nearly monoenergetic ion energy distribution (IED) is desired to achieve highly selective etching. In this work, the author briefly reviews: (1) the fundamentals of development of the ion energy distribution in the sheath and (2) methods to control the IED on plasma electrodes. Such methods include the application of “tailored” voltage waveforms on an electrode in continuous wave plasmas, or the application of synchronous bias on a “boundary electrode” during a specified time window in the afterglow of pulsed plasmas.

  17. Synthesis and Characterization of Simultaneous Electronic and Ionic Conducting Block Copolymers for Lithium Battery Electrodes

    E-Print Network [OSTI]

    Patel, Shrayesh

    2013-01-01T23:59:59.000Z

    Copolymer: Application in Lithium Battery Electrodes. Angew.Schematic of the Proposed lithium battery electrode with aBlock Copolymers for Lithium Battery Electrodes By Shrayesh

  18. BLACK HOLE AURORA POWERED BY A ROTATING BLACK HOLE

    SciTech Connect (OSTI)

    Takahashi, Masaaki [Department of Physics and Astronomy, Aichi University of Education, Kariya, Aichi 448-8542 (Japan); Takahashi, Rohta, E-mail: takahasi@phyas.aichi-edu.ac.j [Cosmic Radiation Laboratory, Institute of Physical and Chemical Research, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)

    2010-05-15T23:59:59.000Z

    We present a model for high-energy emission sources generated by a standing magnetohydrodynamical (MHD) shock in a black hole magnetosphere. The black hole magnetosphere would be constructed around a black hole with an accretion disk, where a global magnetic field could be originated by currents in the accretion disk and its corona. Such a black hole magnetosphere may be considered as a model for the central engine of active galactic nuclei, some compact X-ray sources, and gamma-ray bursts. The energy sources of the emission from the magnetosphere are the gravitational and electromagnetic energies of magnetized accreting matters and the rotational energy of a rotating black hole. When the MHD shock generates in MHD accretion flows onto the black hole, the plasma's kinetic energy and the black hole's rotational energy can convert to radiative energy. In this Letter, we demonstrate the huge energy output at the shock front by showing negative energy postshock accreting MHD flows for a rapidly rotating black hole. This means that the extracted energy from the black hole can convert to the radiative energy at the MHD shock front. When an axisymmetric shock front is formed, we expect a ring-shaped region with very hot plasma near the black hole; this would look like an 'aurora'. The high-energy radiation generated from there would carry to us the information for the curved spacetime due to the strong gravity.

  19. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1999-06-22T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  20. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, George (820 Skywood Rd., Lafayette, CA 94549); Orr, Thomas Robert (2285 Vestal, Castro Valley, CA 94546); Greene, Charles Maurice (6450 Regent St., Oakland, CA 94618); Crawford, Douglas Gordon (33 Longridge Rd., Orinda, CA 94563); Berman, Samuel Maurice (2832 Union St., San Francisco, CA 94123)

    1998-01-01T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  1. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, George (Lafayette, CA); Orr, Thomas Robert (Castro Valley, CA); Greene, Charles Maurice (Oakland, CA); Crawford, Douglas Gordon (Orinda, CA); Berman, Samuel Maurice (San Francisco, CA)

    1999-01-01T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  2. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1998-10-20T23:59:59.000Z

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  3. Plasma nonuniformities induced by dissimilar electrode metals

    SciTech Connect (OSTI)

    Barnat, E.V.; Hebner, G.A. [Sandia National Laboratories, Albuquerque, New Mexico 87185-1423 (United States)

    2005-07-01T23:59:59.000Z

    Nonuniformities in both sheath electric field and plasma excitation were observed around dissimilar metals placed on a rf electrode. Spatial maps of the rf sheath electric field obtained by laser-induced fluorescence-dip (LIF-dip) spectroscopy show that the sheath structure was a function of the electrode metal. In addition to the electric-field measurements, LIF, optical emission, and Langmuir probe measurements show nonuniform excitation around the dissimilar metals. The degree and spatial extent of the discharge nonuniformities were dependent on discharge conditions and the history of the metal surfaces.

  4. Surface-electrode point Paul trap

    SciTech Connect (OSTI)

    Kim, Tony Hyun; Herskind, Peter F.; Chuang, Isaac L. [Center for Ultracold Atoms, Department of Physics, Massachusetts Institute of Technology 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States); Kim, Taehyun; Kim, Jungsang [Department of Electrical and Computer Engineering, Duke University Durham, North Carolina 27708 (United States)

    2010-10-15T23:59:59.000Z

    We present a model as well as experimental results for a surface electrode radiofrequency Paul trap that has a circular electrode geometry well suited for trapping single ions and two-dimensional planar ion crystals. The trap design is compatible with microfabrication and offers a simple method by which the height of the trapped ions above the surface may be changed in situ. We demonstrate trapping of single {sup 88}Sr{sup +} ions over an ion height range of 200-1000 {mu}m for several hours under Doppler laser cooling and use these to characterize the trap, finding good agreement with our model.

  5. System of fabricating a flexible electrode array

    DOE Patents [OSTI]

    Krulevitch, Peter (Pleasanton, CA); Polla, Dennis L. (Roseville, MN); Maghribi, Mariam N. (Davis, CA); Hamilton, Julie (Tracy, CA); Humayun, Mark S. (La Canada, CA); Weiland, James D. (Valencia, CA)

    2010-10-12T23:59:59.000Z

    An image is captured or otherwise converted into a signal in an artificial vision system. The signal is transmitted to the retina utilizing an implant. The implant consists of a polymer substrate made of a compliant material such as poly(dimethylsiloxane) or PDMS. The polymer substrate is conformable to the shape of the retina. Electrodes and conductive leads are embedded in the polymer substrate. The conductive leads and the electrodes transmit the signal representing the image to the cells in the retina. The signal representing the image stimulates cells in the retina.

  6. System of fabricating a flexible electrode array

    DOE Patents [OSTI]

    Krulevitch, Peter (Pleasanton, CA); Polla, Dennis L. (Roseville, MN); Maghribi, Mariam N. (Davis, CA); Hamilton, Julie (Tracy, CA); Humayun, Mark S. (La Canada, CA); Weiland, James D. (Valencia, CA)

    2012-01-28T23:59:59.000Z

    An image is captured or otherwise converted into a signal in an artificial vision system. The signal is transmitted to the retina utilizing an implant. The implant consists of a polymer substrate made of a compliant material such as poly(dimethylsiloxane) or PDMS. The polymer substrate is conformable to the shape of the retina. Electrodes and conductive leads are embedded in the polymer substrate. The conductive leads and the electrodes transmit the signal representing the image to the cells in the retina. The signal representing the image stimulates cells in the retina.

  7. Electrode/electrolyte interface. A status report

    SciTech Connect (OSTI)

    Bard, A.J. (Univ. of Texas, Austin (United States)); Abruna, H.D. (Cornell Univ., Ithaca, NY (United States)); Chidsey, C.E. (Stanford Univ., CA (United States)); Faulkner, L.R. (Univ. of Illinois, Urbana-Champaign (United States)); Feldberg, S.W. (Brookhaven National Lab., Upton, NY (United States)); Itaya, Kingo (Tohoku Univ., Sendai (Japan)); Majda, M. (Univ. of California, Berkeley (United States)); Melroy, O. (IBM Almaden Research Center, San Jose, CA (United States)); Murray, R.W. (Univ. of North Carolina, Chapel Hill (United States)); Porter, M.D. (Iowa State Univ., Ames (United States)); Soriaga, M.P. (Texas A M Univ., College Station (United States)); White, H.S. (Univ. of Utah, Salt Lake City (United States))

    1993-07-15T23:59:59.000Z

    This is a report of a workshop on the [open quotes]state of the art[close quotes] and potential future directions in the study of the electrode/electrolyte interface. Recent advances in experimental capabilities of characterizing the structure of the interface, e.g., through the use of such techniques as scanning tunneling microscopy and X-ray methods, are described. New approaches to studies of interfacial dynamics and materials aspects of the electrode/electrolyte interface are also discussed. 346 refs., 17 figs.

  8. Miniaturized flow injection analysis system

    DOE Patents [OSTI]

    Folta, James A. (Livermore, CA)

    1997-01-01T23:59:59.000Z

    A chemical analysis technique known as flow injection analysis, wherein small quantities of chemical reagents and sample are intermixed and reacted within a capillary flow system and the reaction products are detected optically, electrochemically, or by other means. A highly miniaturized version of a flow injection analysis system has been fabricated utilizing microfabrication techniques common to the microelectronics industry. The microflow system uses flow capillaries formed by etching microchannels in a silicon or glass wafer followed by bonding to another wafer, commercially available microvalves bonded directly to the microflow channels, and an optical absorption detector cell formed near the capillary outlet, with light being both delivered and collected with fiber optics. The microflow system is designed mainly for analysis of liquids and currently measures 38.times.25.times.3 mm, but can be designed for gas analysis and be substantially smaller in construction.

  9. Effect of the reference electrode size on the ionization instability in the plasma sheath of a small positively biased electrode

    SciTech Connect (OSTI)

    Bliokh, Y. P.; Brodsky, Yu. L.; Chashka, Kh. B.; Felsteiner, J.; Slutsker, Ya. Z. [Department of Physics, Technion, 32000 Haifa (Israel)

    2011-06-01T23:59:59.000Z

    It is well known that additional ionization in the vicinity of a positively biased electrode immersed into a weakly ionized plasma is responsible for a hysteresis in the electrode current-voltage characteristics and the current self-oscillations rise. Here we show both experimentally and theoretically that under certain conditions these phenomena cannot be correctly interpreted once considered separately from the reference electrode current-voltage characteristics. It is shown that small electrodes can be separated into three groups according to the relation between the electrode and the reference electrode areas. Each group is characterized by its own dependence of the collected current on the bias voltage.

  10. Shape of black holes

    E-Print Network [OSTI]

    Clement, María E Gabach

    2015-01-01T23:59:59.000Z

    It is well known that celestial bodies tend to be spherical due to gravity and that rotation produces deviations from this sphericity. We discuss what is known and expected about the shape of black holes' horizons from their formation to their final, stationary state. We present some recent results showing that black hole rotation indeed manifests in the widening of their central regions, limits their global shapes and enforces their whole geometry to be close to the extreme Kerr horizon geometry at almost maximal rotation speed. The results depend only on the horizon area and angular momentum. In particular they are entirely independent of the surrounding geometry of the spacetime and of the presence of matter satisfying the strong energy condition. We also discuss the the relation of this result with the Hoop conjecture.

  11. An environmental analysis of injection molding

    E-Print Network [OSTI]

    Thiriez, Alexandre

    2006-01-01T23:59:59.000Z

    This thesis investigates injection molding from an environmental standpoint, yielding a system-level environmental analysis of the process. There are three main objectives: analyze the energy consumption trends in injection ...

  12. Underground Injection Control Permits and Registrations (Texas)

    Broader source: Energy.gov [DOE]

    Chapter 27 of the Texas Water Code (the Injection Well Act) defines an “injection well” as “an artificial excavation or opening in the ground made by digging, boring, drilling, jetting, driving, or...

  13. Improved zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, P.N. Jr.

    1988-06-21T23:59:59.000Z

    The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

  14. Electronically and ionically conducting electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Novak, Robert F. (Farmington Hills, MI); Weber, Neill (Murray, UT)

    1987-01-01T23:59:59.000Z

    A composite article comprising a porous cermet electrode on a dense solid electrolyte and method of making same. The cerment electrode comprises beta-type-alumina and refractory metal.

  15. The Stability of Organic Solvents and Carbon Electrode in Nonaqueous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Stability of Organic Solvents and Carbon Electrode in Nonaqueous Li-O2 Batteries. The Stability of Organic Solvents and Carbon Electrode in Nonaqueous Li-O2 Batteries....

  16. Interfacial Interactions between Implant Electrode and Biological Environment 

    E-Print Network [OSTI]

    Chiu, Cheng-Wei 1979-

    2012-11-06T23:59:59.000Z

    interactions to the charge transport. The interfacial interactions of an implanted electrode with neural system will be studied in two types of electrodes: silver and graphene coated. The interfacial impedance of both samples will be studied using EIS...

  17. Electro-optic device with gap-coupled electrode

    DOE Patents [OSTI]

    Deri, Robert J.; Rhodes, Mark A.; Bayramian, Andrew J.; Caird, John A.; Henesian, Mark A.; Ebbers, Christopher A.

    2013-08-20T23:59:59.000Z

    An electro-optic device includes an electro-optic crystal having a predetermined thickness, a first face and a second face. The electro-optic device also includes a first electrode substrate disposed opposing the first face. The first electrode substrate includes a first substrate material having a first thickness and a first electrode coating coupled to the first substrate material. The electro-optic device further includes a second electrode substrate disposed opposing the second face. The second electrode substrate includes a second substrate material having a second thickness and a second electrode coating coupled to the second substrate material. The electro-optic device additionally includes a voltage source electrically coupled to the first electrode coating and the second electrode coating.

  18. Theoretical Analysis for Obtaining Physical Properties of Composite Electrodes

    E-Print Network [OSTI]

    Weidner, John W.

    , 2003. Composite electrodes, composed of a mixture of electronically and ionically conducting materials and electronic conductivities of Nafion/ carbon composites. Shibuya et al.1 used an interdigitated arrayTheoretical Analysis for Obtaining Physical Properties of Composite Electrodes Parthasarathy M

  19. Composite Electrodes for Rechargeable Lithium-Ion Batteries ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composite Electrodes for Rechargeable Lithium-Ion Batteries Technology available for licensing: Electrodes having composite xLi2M'O3(1-x)LiMO2 structures in which an...

  20. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (San Diego, CA); Dispennette, John M. (Oceanside, CA); Blank, Edward (San Diego, CA); Kolb, Alan C. (Rancho Santa Fe, CA)

    1999-05-25T23:59:59.000Z

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals.

  1. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.; Blank, E.; Kolb, A.C.

    1999-01-19T23:59:59.000Z

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH{sub 3}CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals. 32 figs.

  2. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. J.; Dispennette, J. M.; Blank, E.; Kolb, A. C.

    1999-05-25T23:59:59.000Z

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH[sub 3]CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals. 32 figs.

  3. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (San Diego, CA); Dispennette, John M. (Oceanside, CA); Blank, Edward (San Diego, CA); Kolb, Alan C. (Rancho Santa Fe, CA)

    1999-01-19T23:59:59.000Z

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals.

  4. Titanium nitride electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Novak, Robert F. (Farmington Hills, MI); Schmatz, Duane J. (Dearborn Heights, MI); Hunt, Thomas K. (Ann Arbor, MI)

    1987-12-22T23:59:59.000Z

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film of titanium nitride as an electrode deposited onto solid electrolyte. The invention is also directed to the method of making same.

  5. Molybdenum oxide electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Schmatz, Duane J. (Dearborn Heights, MI)

    1989-01-01T23:59:59.000Z

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film comprising molybdenum oxide as an electrode deposited by physical deposition techniques onto solid electrolyte. The invention is also directed to the method of making same.

  6. Method of making an ultracapacitor electrode

    DOE Patents [OSTI]

    Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); DeJager, Katherine Dana (BJ Goes, NL); LeBlanc, Jr., Oliver Harris (Schenectady, NY)

    2001-10-16T23:59:59.000Z

    A paste of organic solvent with dissolved organic salt and active carbon is formed and a uniform film of the paste is applied onto a substrate by casting the paste into a clearance between a knife blade and the substrate. The paste is evaporated to form a paste electrode for an ultracapacitor.

  7. Method Of Making An Ultracapacitor Electrode

    DOE Patents [OSTI]

    Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); DeJager, Katherine Dana (BJ Goes, NL); LeBlanc, Jr., Oliver Harris (Schenectady, NY)

    2003-05-06T23:59:59.000Z

    A paste of organic solvent with dissolved organic salt and active carbon is formed and a uniform film of the paste is applied onto a substrate by casting the paste into a clearance between a knife blade and the substrate. The paste is evaporated to form a paste electrode for an ultracapacitor.

  8. Organic electroanalysis with chemically modified electrodes

    SciTech Connect (OSTI)

    Guadalupe, A.R.; Abruna, H.D.

    1986-01-01T23:59:59.000Z

    The analytical utility of electrodes modified with functionalized polymer films for the determination of aromatic amines is demonstrated. The analysis is based on the preconcentration of the protonated amines into a functionalized polymer film that contains styrene sulfonate groups. Good sensitivity and high reproducibility were obtained for concentrations down to 10/sup -5/ M. Aliphatic amines do not interfere in the determination.

  9. Cells containing solvated electron lithium negative electrodes

    SciTech Connect (OSTI)

    Uribe, F.A.; Semkow, K.W.; Sammells, A.F. (Eltron Research, Incorporated, Aurora, IL (US))

    1989-12-01T23:59:59.000Z

    Preliminary work performed on a novel solvated electron lithium negative electrode which may have application in either high energy density secondary or reserve battery systems is discussed. The lithium electrode investigated consisted of lithium initially dissolved in liquid ammonia to give a solvated electron solution. Containment of this liquid negative active material from direct contact with a liquid nonaqueous electrolyte present in the cell positive electrode compartment was addressed via the use of a lithium intercalated electronically conducting ceramic membrane of the general composition Li{sub x}WO{sub 2}(0.1{lt}x{lt} 1.0). Secondary electrochemical cells having the general configuration Li,NH{sub 3}/Li{sub x}WO{sub 2}NAE/TiS{sub 2} using nonaqueous electrolytes (NAE) based upon both propylene carbonate and 2Me-THF. Depending upon initial lithium activity in the negative electrode compartments the cell possessed an initial open-circuit potential (OCP 3.44V). Both cells, which were operated at ambient pressure (low temperature) and ambient temperature (high pressure) showed evidence for electrochemical reversibility.

  10. Numerical Simulation of Cooling Gas Injection Using

    E-Print Network [OSTI]

    Numerical Simulation of Cooling Gas Injection Using Adaptive Multiscale Techniques Wolfgang Dahmen: finite volume method, film cooling, cooling gas injection, multiscale techniques, grid adaptation AMS@igpm.rwth-aachen.de (Thomas Gotzen) #12;Numerical simulation of cooling gas injection using adaptive multiscale techniques

  11. ENVIRONMENTAL MONITORING OF LEAKS USING TIME LAPSED LONG ELECTRODE ELECTRICAL RESISTIVITY

    SciTech Connect (OSTI)

    RUCKER DF; FINK JB; LOKE MH; MYERS DA

    2009-11-05T23:59:59.000Z

    Highly industrialized areas pose significant challenges for surface based electrical resistivity characterization and monitoring due to the high degree of metallic infrastructure. The infrastructure is typically several orders of magnitude more conductive than the desired targets, preventing the geophysicist from obtaining a clear picture of the subsurface. These challenges may be minimized if steel-cased wells are used as long electrodes. We demonstrate a method of using long electrodes in a complex nuclear waste facility to monitor a simulated leak from an underground storage tank. The leak was simulated by injecting high conductivity fluid in a perforated well and the resistivity measurements were made before and after the leak test. The data were processed in four dimensions, where a regularization procedure was applied in both the time and space domains. The results showed a lowered resistivity feature develop south of the injection site. The time lapsed regularization parameter had a strong influence on the differences in inverted resistivity between the pre and post datasets, potentially making calibration of the results to specific hydrogeologic parameters difficult.

  12. Advanced Flow Battery Electrodes: Low-cost, High-Performance 50-Year Electrode

    SciTech Connect (OSTI)

    None

    2010-09-01T23:59:59.000Z

    GRIDS Project: Primus Power is developing zinc-based, rechargeable liquid flow batteries that could produce substantially more energy at lower cost than conventional batteries. A flow battery is similar to a conventional battery, except instead of storing its energy inside the cell it stores that energy for future use in chemicals that are kept in tanks that sit outside the cell. One of the most costly components in a flow battery is the electrode, where the electrochemical reactions actually occur. Primus Power is investigating and developing mixed-metal materials for their electrodes that could ultimately reduce the lifetime cost of flow batteries because they are more durable and long-lasting than electrodes found in traditional batteries. Using these electrodes, Primus Power’s flow batteries can be grouped together into robust, containerized storage pods for use by utilities, renewable energy developers, businesses, and campuses.

  13. Vehicle Technologies Office Merit Review 2014: Electrode Architecture-Assembly of Battery Materials and Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Hydro-Québec at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrode architecture-assembly...

  14. Vehicle Technologies Office Merit Review 2015: Electrode Architecture-Assembly of Battery Materials and Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Hydro Quebec at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrode architecture-assembly...

  15. Black holes in massive gravity

    E-Print Network [OSTI]

    Babichev, Eugeny

    2015-01-01T23:59:59.000Z

    We review the black hole solutions of the ghost-free massive gravity theory and its bimetric extension and outline the main results on the stability of these solutions against small perturbations. Massive (bi)-gravity accommodates exact black hole solutions, analogous to those of General Relativity. In addition to these solutions, hairy black holes -- solutions with no correspondent in General Relativity -- have been found numerically, whose existence is a natural consequence of the absence of the Birkhoff's theorem in these theories. The existence of extra propagating degrees of freedom, makes the stability properties of these black holes richer and more complex than those of General Relativity. In particular, the bi-Schwarzschild black hole exhibits an unstable spherically symmetric mode, while the bi-Kerr geometry is also generically unstable, both against the spherical mode and against superradiant instabilities. If astrophysical black holes are described by these solutions, the superradiant instability o...

  16. Black Hole's 1/N Hair

    E-Print Network [OSTI]

    Gia Dvali; Cesar Gomez

    2012-03-29T23:59:59.000Z

    According to the standard view classically black holes carry no hair, whereas quantum hair is at best exponentially weak. We show that suppression of hair is an artifact of the semi-classical treatment and that in the quantum picture hair appears as an inverse mass-square effect. Such hair is predicted in the microscopic quantum description in which a black hole represents a self-sustained leaky Bose-condensate of N soft gravitons. In this picture the Hawking radiation is the quantum depletion of the condensate. Within this picture we show that quantum black hole physics is fully compatible with continuous global symmetries and that global hair appears with the strength B/N, where B is the global charge swallowed by the black hole. For large charge this hair has dramatic effect on black hole dynamics. Our findings can have interesting astrophysical consequences, such as existence of black holes with large detectable baryonic and leptonic numbers.

  17. ORIGINAL PAPER Attractive forces in microporous carbon electrodes for capacitive

    E-Print Network [OSTI]

    Bazant, Martin Z.

    ORIGINAL PAPER Attractive forces in microporous carbon electrodes for capacitive deionization P. M double layer in microporous carbon electrodes, suitable for incorporation in porous electrode theory and the metallic pore surfaces (image forces) that are not captured by mean-field theories, such as the Poisson

  18. Electrically conductive polycrystalline diamond and particulate metal based electrodes

    DOE Patents [OSTI]

    Swain, Greg M.; Wang, Jian

    2005-04-26T23:59:59.000Z

    An electrically conducting and dimensionally stable diamond (12, 14) and metal particle (13) electrode produced by electrodepositing the metal on the diamond is described. The electrode is particularly useful in harsh chemical environments and at high current densities and potentials. The electrode is particularly useful for generating hydrogen, and for reducing oxygen and oxidizing methanol in reactions which are of importance in fuel cells.

  19. Method of making an air electrode material having controlled sinterability

    DOE Patents [OSTI]

    Vasilow, T.R.; Kuo, L.J.H.; Ruka, R.J.

    1994-08-30T23:59:59.000Z

    A tubular, porous ceramic electrode structure is made from the sintered admixture of doped lanthanum manganite and an additive containing cerium where a solid electrolyte, substantially surrounds the air electrode, and a porous outer fuel electrode substantially surrounds the electrolyte, to form a fuel cell. 2 figs.

  20. Measurement and simulation of jet mass caused by a high-aspect ratio hole perturbation

    SciTech Connect (OSTI)

    Keiter, Paul A [Los Alamos National Laboratory; Cooley, James H [Los Alamos National Laboratory; Wilson, D C [Los Alamos National Laboratory; Kyrala, George A [Los Alamos National Laboratory; Blue, Brent E [LLNL; Edwards, J [LLNL; Elliott, James B [LLNL; Robey, H F [LLNL; Spears, B [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Inertial confinement fusion (ICF) capsule performance can be negatively impacted by the presence of hydrodynamic instabilities. To perform a gas fill on an ICF capsule, current plans involve drilling a small hole and inserting a fill tube to inject the gas mixture into the capsule. This introduces a perturbation on the capsule, which can seed hydrodynamic instabilities. The small hole can cause jetting of the shell material into the gas, which might adversely affect the capsule performance. We have performed simulations and experiments to study the hydrodynamic evolution of jets from high-aspect ratio holes, such as the fill tube hole. Although simulations using cold materials overpredict the amount of mass in the jet, when a reasonable amount of preheat (<1 eV) is introduced, the simulations are in better agreement with the experiment.

  1. Observational Evidence for Black Holes

    E-Print Network [OSTI]

    Ramesh Narayan; Jeffrey E. McClintock

    2014-07-20T23:59:59.000Z

    Astronomers have discovered two populations of black holes: (i) stellar-mass black holes with masses in the range 5 to 30 solar masses, millions of which are present in each galaxy in the universe, and (ii) supermassive black holes with masses in the range 10^6 to 10^{10} solar masses, one each in the nucleus of every galaxy. There is strong circumstantial evidence that all these objects are true black holes with event horizons. The measured masses of supermassive black hole are strongly correlated with properties of their host galaxies, suggesting that these black holes, although extremely small in size, have a strong influence on the formation and evolution of entire galaxies. Spin parameters have recently been measured for a handful of black holes. Based on the data, there is an indication that the kinetic power of at least one class of relativistic jet ejected from accreting black holes may be correlated with black hole spin. If verified, it would suggest that these jets are powered by a generalized Penrose process mediated by magnetic fields.

  2. Transient evolution of solitary electron holes in low pressure laboratory plasma

    E-Print Network [OSTI]

    Choudhary, Mangilal; Mukherjee, Subroto

    2015-01-01T23:59:59.000Z

    Solitary electrons holes (SEHs) are localized electrostatic positive potential structures in collisionless plasmas. These are vortex-like structures in the electron phase space. Its existence is cause of distortion of the electron distribution in the resonant region. These are explained theoretically first time by Schamel et.al [Phys. Scr. 20, 336 (1979) and Phys. Plasmas 19, 020501 (2012)]. Propagating solitary electron holes can also be formed in a laboratory plasma when a fast rising high positive voltage pulse is applied to a metallic electrode [Kar et. al., Phys. Plasmas 17, 102113 (2010)] immersed in a low pressure plasma. The temporal evolution of these structures can be studied by measuring the transient electron distribution function (EDF). In the present work, transient EDF is measured after formation of a solitary electron hole in nearly uniform, unmagnetized, and collisionless plasma for applied pulse width and, where and are applied pulse width and inverse of ion plasma frequency respectively. Fo...

  3. Method for preventing bitumen backflow in injection wells when steam injection is interrupted

    SciTech Connect (OSTI)

    Freeman, D.C.; Djabbarah, N.F.

    1990-04-24T23:59:59.000Z

    This patent describes a method for preventing viscous hydrocarbonaceous fluids from backflowing into a well upon interruption of a steamflood. It comprises: detecting a substantial reduction in steam injection pressure in at least one injection well via a pressure sensing device; and causing automatically a pressurized fluid to be injected into the injection well in response to the reduction in pressure which prevents viscous hydrocarbonaceous fluids from backflowing into the injection well.

  4. Fuel injection device and method

    DOE Patents [OSTI]

    Carlson, L.W.

    1983-12-21T23:59:59.000Z

    A fuel injection system and method provide for shaping a combustion plume within a combustion chamber to effectively recirculate hot combustion gases for stable combustion conditions while providing symmetrical combustion conditions. Char and molten slag are passed to the outer boundary layer to complete combustion of char while permitting initial substoichiometric combustion in a reductive atmosphere for reducing discharge of nitrogen oxides. Shaping of the plume is accomplished by an axially adjustable pintle which permits apportionment of driving pressure between elements which contribute tangential and those which contribute radial directional components to oxidant flow entering the combustion chamber.

  5. Materials for High Pressure Fuel Injection Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Measures and Accomplishments YEAR 1 * Demonstrate the ability to measure fine-scale surface roughness and image the topography on the inside of fuel injector holes. *...

  6. Artificial ozone holes

    E-Print Network [OSTI]

    S. N. Dolya

    2014-10-18T23:59:59.000Z

    This article considers an opportunity of disinfecting a part of the Earth surface, occupying a large area of ten thousand square kilometers. The sunlight will cause dissociation of molecular bromine into atoms; each bromine atom kills thirty thousand molecules of ozone. Each bromine plate has a mass of forty milligrams grams and destroys ozone in the area of hundred square meters. Thus, to form the ozone hole over the area of ten thousand square kilometers, it is required to have the total mass of bromine equal to the following four tons.

  7. Experimental investigation of a thermionic converter with developed surface electrodes

    SciTech Connect (OSTI)

    Luke, James R.; El-Genk, Mohamed S.; Adrian, John M. [Institute for Space and Nuclear Power Studies/Chemical and Nuclear Engineering Department University of New Mexico, Albuquerque, New Mexico 87131 (United States)

    1997-01-10T23:59:59.000Z

    A thermionic converter with developed planar electrode surfaces is designed and tested. One of the electrodes has concentric circular grooves cut into its surface, while the other electrode surface is smooth. The grooves are 0.5 mm deep and 0.5 mm wide, having lands that are 1.0 mm wide. The experimental setup is flexible so that either the smooth or developed surface electrode can be operated as the emitter, with the other operating as the collector. The I-V characteristics and power output are compared for the two electrode arrangements.

  8. Experimental investigation of a thermionic converter with developed surface electrodes

    SciTech Connect (OSTI)

    Luke, J.R.; El-Genk, M.S.; Adrian, J.M. [Institute for Space and Nuclear Power Studies/Chemical and Nuclear Engineering Department University of New Mexico, Albuquerque, New Mexico87131 (United States)

    1997-01-01T23:59:59.000Z

    A thermionic converter with developed planar electrode surfaces is designed and tested. One of the electrodes has concentric circular grooves cut into its surface, while the other electrode surface is smooth. The grooves are 0.5 mm deep and 0.5 mm wide, having lands that are 1.0 mm wide. The experimental setup is flexible so that either the smooth or developed surface electrode can be operated as the emitter, with the other operating as the collector. The I-V characteristics and power output are compared for the two electrode arrangements. {copyright} {ital 1997 American Institute of Physics.}

  9. Apparatus for electrode current control in linear MHD generators

    DOE Patents [OSTI]

    Demirjian, Ara M. (Arlington, MA); Solbes, Albert (Rancho Palos Verdes, CA)

    1984-01-01T23:59:59.000Z

    Apparatus for controlling a plurality of opposing, electrode, direct-currents at pre-set locations across a channel that comprises a converter for converting each electrode current into first and second periodic control signals which are 180.degree. out of phase with respect to each other and which have equal magnitudes corresponding to the magnitude of the associated electrode current; and couplers for magnetically coupling individual ones of the first control signals and for magnetically coupling individual ones of the second signals such that the corresponding electrode currents are equalized or rendered proportional by balancing the same in the same or constant ratios in accordance with the locations of the electrode currents.

  10. Graphene-based battery electrodes having continuous flow paths

    DOE Patents [OSTI]

    Zhang, Jiguang; Xiao, Jie; Liu, Jun; Xu, Wu; Li, Xiaolin; Wang, Deyu

    2014-05-24T23:59:59.000Z

    Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases. Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show extremely high capacities, wherein the network of channels allow oxygen to diffuse through the electrode and mesopores in the electrode can store discharge products.

  11. Electronically conductive polymer binder for lithium-ion battery electrode

    DOE Patents [OSTI]

    Liu, Gao; Xun, Shidi; Battaglia, Vincent S; Zheng, Honghe

    2014-10-07T23:59:59.000Z

    A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

  12. Delayed energy injection model for gamma-ray burst afterglows

    SciTech Connect (OSTI)

    Geng, J. J.; Huang, Y. F.; Yu, Y. B. [Department of Astronomy, Nanjing University, Nanjing 210093 (China); Wu, X. F., E-mail: hyf@nju.edu.cn, E-mail: xfwu@pmo.ac.cn [Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing 210008 (China)

    2013-12-10T23:59:59.000Z

    The shallow decay phase and flares in the afterglows of gamma-ray bursts (GRBs) are widely believed to be associated with the later activation of the central engine. Some models of energy injection involve a continuous energy flow since the GRB trigger time, such as the magnetic dipole radiation from a magnetar. However, in the scenario involving a black hole accretion system, the energy flow from the fall-back accretion may be delayed for a fall-back time ?t {sub fb}. Thus, we propose a delayed energy injection model. The delayed energy would cause a notable rise to the Lorentz factor of the external shock, which will 'generate' a bump in the multiple band afterglows. If the delayed time is very short, our model degenerates to the previous models. Our model can explain the significant re-brightening in the optical and infrared light curves of GRB 081029 and GRB 100621A. A considerable fall-back mass is needed to provide the later energy; this indicates that GRBs accompanied with fall-back material may be associated with a low energy supernova so that the fraction of the envelope can survive during eruption. The fall-back time can give meaningful information on the properties of GRB progenitor stars.

  13. Electrode holder useful in a corrosion testing device

    DOE Patents [OSTI]

    Murphy, R.J. Jr.; Jamison, D.E.

    1986-08-19T23:59:59.000Z

    The present invention is directed to an apparatus and method for holding one or more test electrodes of precisely known exposed surface area. The present invention is particularly useful in a device for determining the corrosion properties of the materials from which the test electrodes have been formed. The present invention relates to a device and method for holding the described electrodes wherein the exposed surface area of the electrodes is only infinitesimally decreased. Further, in the present invention the exposed, electrically conductive surface area of the contact devices is small relative to the test electrode surface area. The holder of the present invention conveniently comprises a device for contacting and engaging each test electrode at two point contacts infinitesimally small in relation to the exposed surface area of the electrodes. 4 figs.

  14. Linear particle accelerator with seal structure between electrodes and insulators

    DOE Patents [OSTI]

    Broadhurst, John H. (Golden Valley, MN)

    1989-01-01T23:59:59.000Z

    An electrostatic linear accelerator includes an electrode stack comprised of primary electrodes formed or Kovar and supported by annular glass insulators having the same thermal expansion rate as the electrodes. Each glass insulator is provided with a pair of fused-in Kovar ring inserts which are bonded to the electrodes. Each electrode is designed to define a concavo-convex particle trap so that secondary charged particles generated within the accelerated beam area cannot reach the inner surface of an insulator. Each insulator has a generated inner surface profile which is so configured that the electrical field at this surface contains no significant tangential component. A spark gap trigger assembly is provided, which energizes spark gaps protecting the electrodes affected by over voltage to prevent excessive energy dissipation in the electrode stack.

  15. HVDC power transmission electrode siting and design

    SciTech Connect (OSTI)

    Holt, R.J. [NDT Engineering, Inc., Shrewbury, MA (United States); Dabkowski, J. [Electro-Sciences, Inc., Crystal Lake, IL (United States); Hauth, R.L. [New England Power Service Co., Westborough, MA (United States)

    1997-04-01T23:59:59.000Z

    This research strives to shed light on the feasibility and practicality of using deep earth electrodes to permit their use for extended periods without adverse consequences. This report begins with a review of the fundamentals associated with current conduction in earth, including the various techniques available for measuring the earth`s electrical properties. The sources of existing data are discussed and some specific data for selected regions of the U.S. and Canada are reviewed as examples. Electrode technology and design issues are reviewed and recent experience gained by New England Power and Hydro-Quebec is discussed. The issues associated with direct current flowing in underground pipelines (and other facilities) are described and the present-day mitigation measures are evaluated. Suggestions are made for further R&D in the coordination of cathodic protection systems, an area that has evolved as an empirical, trial- and-error art more than a science.

  16. Method for making thin carbon foam electrodes

    DOE Patents [OSTI]

    Pekala, R.W.; Mayer, S.T.; Kaschmitter, J.L.; Morrison, R.L.

    1999-08-03T23:59:59.000Z

    A method for fabricating thin, flat carbon electrodes by infiltrating highly porous carbon papers, membranes, felts, metal fibers/powders, or fabrics with an appropriate carbon foam precursor material is disclosed. The infiltrated carbon paper, for example, is then cured to form a gel-saturated carbon paper, which is subsequently dried and pyrolyzed to form a thin sheet of porous carbon. The material readily stays flat and flexible during curing and pyrolyzing to form thin sheets. Precursor materials include polyacrylonitrile (PAN), polymethylacrylonitrile (PMAN), resorcinol/formaldehyde, catechol/formaldehyde, phenol/formaldehyde, etc., or mixtures thereof. These thin films are ideal for use as high power and energy electrodes in batteries, capacitors, and fuel cells, and are potentially useful for capacitive deionization, filtration and catalysis.

  17. Liquid Propane Injection Technology Conductive to Today's North...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection...

  18. The Ozone Hole Some perspective

    E-Print Network [OSTI]

    Toohey, Darin W.

    The Ozone Hole · Some perspective · The British Antarctic Survey · The "Ozone Hole" · International of the predicted ozone losses! This was quite a controversy. Ultimately, ozone losses started appearing in the late 1980s (see Figure below), but by then, there was already a credibility issue for ozone scientists. #12

  19. Optical black holes and solitons

    E-Print Network [OSTI]

    Shawn Westmoreland

    2010-12-21T23:59:59.000Z

    We exhibit a static, cylindrically symmetric, exact solution to the Euler-Heisenberg field equations (EHFE) and prove that its effective geometry contains (optical) black holes. It is conjectured that there are also soliton solutions to the EHFE which contain black hole geometries.

  20. Black Holes of Negative Mass

    E-Print Network [OSTI]

    R. B. Mann

    1997-05-06T23:59:59.000Z

    I demonstrate that, under certain circumstances, regions of negative energy density can undergo gravitational collapse into a black hole. The resultant exterior black hole spacetimes necessarily have negative mass and non-trivial topology. A full theory of quantum gravity, in which topology-changing processes take place, could give rise to such spacetimes.

  1. Diffusion in biofilms respiring on electrodes

    SciTech Connect (OSTI)

    Renslow, Ryan S.; Babauta, Jerome T.; Majors, Paul D.; Beyenal, Haluk

    2013-02-15T23:59:59.000Z

    The goal of this study was to measure spatially and temporally resolved effective diffusion coefficients (De) in biofilms respiring on electrodes. Two model electrochemically active biofilms, Geobacter sulfurreducens PCA and Shewanella oneidensis MR-1, were investigated. A novel nuclear magnetic resonance microimaging perfusion probe capable of simultaneous electrochemical and pulsed-field gradient nuclear magnetic resonance (PFG-NMR) techniques was used. PFG-NMR allowed for noninvasive, nondestructive, high spatial resolution in situ De measurements in living biofilms respiring on electrodes. The electrodes were polarized so that they would act as the sole terminal electron acceptor for microbial metabolism. We present our results as both two-dimensional De heat maps and surface-averaged relative effective diffusion coefficient (Drs) depth profiles. We found that (1) Drs decreases with depth in G. sulfurreducens biofilms, following a sigmoid shape; (2) Drs at a given location decreases with G. sulfurreducens biofilm age; (3) average De and Drs profiles in G. sulfurreducens biofilms are lower than those in S. oneidensis biofilms—the G. sulfurreducens biofilms studied here were on average 10 times denser than the S. oneidensis biofilms; and (4) halting the respiration of a G. sulfurreducens biofilm decreases the De values. Density, reflected by De, plays a major role in the extracellular electron transfer strategies of electrochemically active biofilms.

  2. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kang, Sun-Ho

    2010-06-08T23:59:59.000Z

    An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi.sub.2-yH.sub.yO.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 in which 0electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

  3. Liquid injection plasma deposition method and apparatus

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Watkins, Arthur D. (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    A liquid injection plasma torch deposition apparatus for depositing material onto a surface of a substrate may comprise a plasma torch for producing a jet of plasma from an outlet nozzle. A plasma confinement tube having an inlet end and an outlet end and a central bore therethrough is aligned with the outlet nozzle of the plasma torch so that the plasma jet is directed into the inlet end of the plasma confinement tube and emerges from the outlet end of the plasma confinement tube. The plasma confinement tube also includes an injection port transverse to the central bore. A liquid injection device connected to the injection port of the plasma confinement tube injects a liquid reactant mixture containing the material to be deposited onto the surface of the substrate through the injection port and into the central bore of the plasma confinement tube.

  4. Liquid injection plasma deposition method and apparatus

    DOE Patents [OSTI]

    Kong, P.C.; Watkins, A.D.

    1999-05-25T23:59:59.000Z

    A liquid injection plasma torch deposition apparatus for depositing material onto a surface of a substrate may comprise a plasma torch for producing a jet of plasma from an outlet nozzle. A plasma confinement tube having an inlet end and an outlet end and a central bore therethrough is aligned with the outlet nozzle of the plasma torch so that the plasma jet is directed into the inlet end of the plasma confinement tube and emerges from the outlet end of the plasma confinement tube. The plasma confinement tube also includes an injection port transverse to the central bore. A liquid injection device connected to the injection port of the plasma confinement tube injects a liquid reactant mixture containing the material to be deposited onto the surface of the substrate through the injection port and into the central bore of the plasma confinement tube. 8 figs.

  5. INJECTION CHOICE FOR SPALLATION NEUTRON SOURCE RING.

    SciTech Connect (OSTI)

    WEI,J.; BEEBE-WANG,J.; BLASKIEWICZ,M.; BRODOWSKI,J.; FEDOTOV,A.; GARDNER,C.; LEE,Y.Y.; RAPARIA,D.; DANILOV,V.; HOLMES,J.; PRIOR,C.; REES,G.; MACHIDA,S.

    2001-06-18T23:59:59.000Z

    Injection is key in the low-loss design of high-intensity proton facilities like the Spallation Neutron Source (SNS). During the design of both the accumulator and the rapid-cycling-synchrotron version of the SNS, extensive comparison has been made to select injection scenarios that satisfy SNS's low-loss design criteria. This paper presents issues and considerations pertaining to the final choice of the SNS injection systems.

  6. Effect of film hole location on heat transfer coefficient and film effectiveness of a gas turbine blade

    E-Print Network [OSTI]

    Jiang, Huan Wanda

    1994-01-01T23:59:59.000Z

    Experiments were performed to study the effect of film hole location on local heat transfer coefficient and film effectiveness distributions of a turbine blade model with air (D.R. = 1.0) and C02 (D.R. = 1.52) film injection. Tests were performed...

  7. Oregon Underground Injection Control Registration Application...

    Open Energy Info (EERE)

    Oregon Underground Injection Control Registration Application Fees (DEQ Form UIC 1003-GIC) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Oregon...

  8. Washington Environmental Permit Handbook - Underground Injection...

    Open Energy Info (EERE)

    Washington Environmental Permit Handbook - Underground Injection Control Registration webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site:...

  9. Oregon Underground Injection Control Registration Geothermal...

    Open Energy Info (EERE)

    Oregon Underground Injection Control Registration Geothermal Heating Systems (DEQ Form UICGEO-1004(f)) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form:...

  10. Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...

    Broader source: Energy.gov (indexed) [DOE]

    "Advancing The Technology" Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development Corey E. Weaver Ford Research and Advanced Engineering 05132011 Project...

  11. Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...

    Broader source: Energy.gov (indexed) [DOE]

    "Advancing The Technology" Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development Corey E. Weaver Ford Research and Advanced Engineering 05182012 Project...

  12. Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine...

    Broader source: Energy.gov (indexed) [DOE]

    "Advancing The Technology" Advanced Gasoline Turbocharged Direct Injection (GTDI) Engine Development Corey E. Weaver Ford Research and Advanced Engineering 06192014 Project...

  13. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2012-06-05T23:59:59.000Z

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons including mobilized hydrocarbons are produced from the portion.

  14. Experimental Investigation of Effect of Injection Parameters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experimental Investigation of Effect of Injection Parameters, Compression Ratio and Ultra-cooled EGR on CI Engine Performance and Emissions Low temperature combustion,...

  15. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08T23:59:59.000Z

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  16. Materials for High-Pressure Fuel Injection Systems

    SciTech Connect (OSTI)

    Blau, P.; Shyam, A.; Hubbard, C.; Howe, J.; Trejo, R.; Yang, N. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center; Pollard, M. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center

    2011-09-30T23:59:59.000Z

    The high-level goal of this multi-year effort was to facilitate the Advanced Combustion Engine goal of 20% improvement (compared to 2009 baseline) of commercial engine efficiency by 2015. A sub-goal is to increase the reliability of diesel fuel injectors by investigating modelbased scenarios that cannot be achieved by empirical, trial and error methodologies alone. During this three-year project, ORNL developed the methodology to evaluate origins and to record the initiation and propagation of fatigue cracks emanating from holes that were electrodischarge machined (EDM), the method used to form spray holes in fuel injector tips. Both x-ray and neutron-based methods for measuring residual stress at four different research facilities were evaluated to determine which, if any, was most applicable to the fuel injector tip geometry. Owing to the shape and small volumes of material involved in the sack area, residual stress data could only be obtained in the walls of the nozzle a few millimeters back from the tip, and there was a hint of only a small compressive stress. This result was consistent with prior studies by Caterpillar. Residual stress studies were suspended after the second year, reserving the possibility of pursuing this in the future, if and when methodology suitable for injector sacks becomes available. The smooth specimen fatigue behavior of current fuel injector steel materials was evaluated and displayed a dual mode initiation behavior. At high stresses, cracks started at machining flaws in the surface; however, below a critical threshold stress of approximately 800 MPa, cracks initiated in the bulk microstructure, below the surface. This suggests that for the next generation for high-pressure fuel injector nozzles, it becomes increasingly important to control the machining and finishing processes, especially if the stress in the tip approaches or exceeds that threshold level. Fatigue tests were also conducted using EDM notches in the gage sections. Compared to the smooth specimens, EDM notching led to a severe reduction in total fatigue life. A reduction in fatigue life of nearly four orders of magnitude can occur at an EDM notch the approximate size of fuel injector spray holes. Consequently, the initiation and propagation behavior of cracks from small spray holes is relevant for generation of design quality data for the next generation diesel fuel injection devices. This is especially true since the current design methodologies usually rely on the less conservative smooth specimen fatigue testing results, and since different materials can have varying levels of notch fatigue resistance.

  17. An analysis of a back-fed porous electrode for the bromine/bromide redox reaction

    E-Print Network [OSTI]

    Van Zee, John William

    1982-01-01T23:59:59.000Z

    that of the front-fed electrode (compare Figs. 1 and 2) This reduction in electrode gap could decrease the cell's specific resistance by more than 25% in Zn/Hrl batteries if a relatively nonconducting complexing agent (3) is present in the electrolyte. (The... of the back-fed electrode Previous Steady State Analyses Previous steady state analyses of porous electrodes have been presented for diffusion electrodes and for electrodes with electrolyte flowing through them. Two classes of flow-through electrodes...

  18. Strings, higher curvature corrections, and black holes

    E-Print Network [OSTI]

    Thomas Mohaupt

    2005-12-05T23:59:59.000Z

    We review old and recent results on subleading contributions to black hole entropy in string theory.

  19. Nanodisperse transition metal electrodes (NTME) for electrochemical cells

    DOE Patents [OSTI]

    Striebel, Kathryn A. (Oakland, CA); Wen, Shi-Jie (Sunnyvale, CA)

    2000-01-01T23:59:59.000Z

    Disclosed are transition metal electrodes for electrochemical cells using gel-state and solid-state polymers. The electrodes are suitable for use in primary and secondary cells. The electrodes (either negative electrode or positive electrode) are characterized by uniform dispersion of the transition metal at the nanoscale in the polymer. The transition metal moiety is structurally amorphous, so no capacity fade should occur due to lattice expansion/contraction mechanisms. The small grain size, amorphous structure and homogeneous distribution provide improved charge/discharge cycling performance, and a higher initial discharge rate capability. The cells can be cycled at high current densities, limited only by the electrolyte conductivity. A method of making the electrodes (positive and negative), and their usage in electrochemical cells are disclosed.

  20. Environmental and geographical aspects in HVdc electrode design

    SciTech Connect (OSTI)

    Tykeson, K. [Sydkraft Konsult AB, Malmoe (Sweden)] [Sydkraft Konsult AB, Malmoe (Sweden); Nyman, A. [Baltic Cable AB, Malmoe (Sweden)] [Baltic Cable AB, Malmoe (Sweden); Carlsson, H. [Permascand AB, Ljungaverk (Sweden)] [Permascand AB, Ljungaverk (Sweden)

    1996-10-01T23:59:59.000Z

    An essential element in HVdc electrode design is to minimize all environmental stresses in order to meet and verify conformance to the laws and regulations associated with the concessions granted by the authorities. The environmental disturbance caused in anode or cathode operation is more or less entirely dependent on the materials used, the geographical location and the electrode size. The electrode materials and the related electrochemical process in the surrounding medium are discussed in the paper in order to shed further light on the chemical properties of different materials in an electrolyte process. The geographical location of an electrode is described, taking into account new aspects such as the impact of the earth`s magnetic field and the interaction with existing HVdc electrodes. The experiences described in this paper are based on the design, tests and operation of the electrodes in the Baltic Cable HVdc link and other Scandinavian HVdc links.

  1. Alternate Explosions: Collapse and Accretion Events with Red Holes instead of Black Holes

    E-Print Network [OSTI]

    James S. Graber

    1999-08-10T23:59:59.000Z

    A red hole is "just like a black hole" except it lacks an event horizon and a singularity. As a result, a red hole emits much more energy than a black hole during a collapse or accretion event. We consider how a red hole solution can solve the "energy crisis" and power extremely energetic gamma ray bursts and hypernovae.

  2. Desalination with carbon aerogel electrodes. Revision 1

    SciTech Connect (OSTI)

    Farmer, J.C.; Richardson, J.H.; Fix, D.V. [Lawrence Livermore National Lab., CA (United States); Thomson, S.L.; May, S.C. [Bechtel National, Inc., San Francisco, CA (United States)

    1996-12-04T23:59:59.000Z

    Electrically regenerated electrosorption process (carbon aerogel CDI) was developed by LLNL for continuously removing ionic impurities from aqueous streams. A salt solution flows in a channel formed by numerous pairs of parallel carbon aerogel electrodes. Each electrode has a very high BET surface area (2-5.4x10{sup 6}ft{sup 2}lb{sup -1} or 400-1100 m{sup 2}g{sup -1}) and very low electrical resistivity ({le}40 m{Omega}). Ions are removed from the electrolyte by the electric field and electrosorbed onto the carbon aerogel. It is concluded that carbon aerogel CDI may be an energy-efficient alternative to electrodialysis and reverse osmosis for desalination of brackish water ({le}5000 ppM). The intrinsic energy required by this process is about QV/2, where Q is the stored electrical charge and V is the voltage between the electrodes, plus losses. Estimated requirement for desalination of a 2000 ppM feed is -0.53-2.5 Wh/gal{sup -1} (0.5-2.4 kJ L{sup -1}), depending on voltage, flow rate, cell dimensions, aerogel density, recovery ratio, etc. This assumes that 50-70% of the stored electrical energy is reclaimed during regeneration (electrical discharge). Though the energy requirement for desalination of sea water is also low, this application will be much more difficult. Additional work will be required for desalination of streams that contain more than 5000 ppM total dissolved solids (2000 ppM will require electrochemical cells with extremely tight, demanding tolerances). At this present time, the process is best suited for streams with dilute impurities, as recently demonstrated during a field test at LLNL Treatment Facility C.

  3. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, E.

    1984-04-10T23:59:59.000Z

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  4. Solvated electron lithium electrode for high energy density battery

    SciTech Connect (OSTI)

    Sammells, A.F.

    1987-05-26T23:59:59.000Z

    A rechargeable high energy density lithium-based cell is described comprising: a solvated electron lithium negative electrode comprising a solution of lithium dissolved in liquid ammonia; a lithium ion conducting solid electrolyte contacting the negative electrode; a liquid non-aqueous lithium ion conducting electrolyte comprising a lithium ion conducting supporting electrolyte dissolved in a non-aqueous solvent. The liquid electrolyte contacting the lithium ion conducting solid electrolyte; and a solid lithium intercalation positive electrode contacting the liquid electrolyte.

  5. Increasing ion sorption and desorption rates of conductive electrodes

    DOE Patents [OSTI]

    DePaoli, David William; Kiggans, Jr., James O; Tsouris, Costas; Bourcier, William; Campbell, Robert; Mayes, Richard T

    2014-12-30T23:59:59.000Z

    An electrolyte system includes a reactor having a pair of electrodes that may sorb ions from an electrolyte. The electrolyte system also includes at least one power supply in electrical communication with the reactor. The at least one power supply may supply a DC signal and an AC signal to the pair of electrodes during sorption of the ions. In addition, the power supply may supply only the AC signal to the pair of electrodes during desorption of the ions.

  6. Conductor-polymer composite electrode materials

    DOE Patents [OSTI]

    Ginley, D.S.; Kurtz, S.R.; Smyrl, W.H.; Zeigler, J.M.

    1984-06-13T23:59:59.000Z

    A conductive composite material useful as an electrode, comprises a conductor and an organic polymer which is reversibly electrochemically dopable to change its electrical conductivity. Said polymer continuously surrounds the conductor in intimate electrical contact therewith and is prepared by electrochemical growth on said conductor or by reaction of its corresponding monomer(s) on said conductor which has been pre-impregnated or pre-coated with an activator for said polymerization. Amount of the conductor is sufficient to render the resultant composite electrically conductive even when the polymer is in an undoped insulating state.

  7. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, S.P.; Woods, R.W.

    1998-08-11T23:59:59.000Z

    A process is disclosed for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750 C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5--3000 ppm in order to obtain a desired composition in the resulting composite. 2 figs.

  8. Ternary compound electrode for lithium cells

    DOE Patents [OSTI]

    Raistrick, I.D.; Godshall, N.A.; Huggins, R.A.

    1980-07-30T23:59:59.000Z

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

  9. Ternary compound electrode for lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Godshall, Ned A. (Stanford, CA); Huggins, Robert A. (Stanford, CA)

    1982-01-01T23:59:59.000Z

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

  10. Method Of Characterizing An Electrode Binder

    DOE Patents [OSTI]

    Cocciantelli, Jean-Michel (Bordeaux, FR); Coco, Isabelle (Talence, FR); Villenave, Jean-Jacques (Talence, FR)

    1999-05-11T23:59:59.000Z

    In a method of characterizing a polymer binder for cell electrodes in contact with an electrolyte and including a current collector and a paste containing an electrochemically active material and said binder, a spreading coefficient of the binder on the active material is calculated from the measured angle of contact between standard liquids and the active material and the binder, respectively. An interaction energy of the binder with the electrolyte is calculated from the measured angle of contact between the electrolyte and the binder. The binder is selected such that the spreading coefficient is less than zero and the interaction energy is at least 60 mJ/m.sup.2.

  11. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA)

    1998-01-01T23:59:59.000Z

    A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

  12. Microcantilever Counter Electrode Electrochemical Sensor in a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighand Retrievals fromprocess used inEnergy InnovationThree-Electrode Cell

  13. The NINJA-2 project: Detecting and characterizing gravitational waveforms modelled using numerical binary black hole simulations

    E-Print Network [OSTI]

    :,; Abbott, B P; Abbott, R; Abbott, T; Abernathy, M R; Accadia, T; Acernese, F; Ackley, K; Adams, C; Adams, T; Addesso, P; Adhikari, R X; Affeldt, C; Agathos, M; Aggarwal, N; Aguiar, O D; Ain, A; Ajith, P; Alemic, A; Allen, B; Allocca, A; Amariutei, D; Andersen, M; Anderson, R; Anderson, S B; Anderson, W G; Arai, K; Araya, M C; Arceneaux, C; Areeda, J; Aston, S M; Astone, P; Aufmuth, P; Aulbert, C; Austin, L; Aylott, B E; Babak, S; Baker, P T; Ballardin, G; Ballmer, S W; Barayoga, J C; Barbet, M; Barish, B C; Barker, D; Barone, F; Barr, B; Barsotti, L; Barsuglia, M; Barton, M A; Bartos, I; Bassiri, R; Basti, A; Batch, J C; Bauchrowitz, J; Bauer, Th S; Behnke, B; Bejger, M; Beker, M G; Belczynski, C; Bell, A S; Bell, C; Bergmann, G; Bersanetti, D; Bertolini, A; Betzwieser, J; Beyersdorf, P T; Bilenko, I A; Billingsley, G; Birch, J; Biscans, S; Bitossi, M; Bizouard, M A; Black, E; Blackburn, J K; Blackburn, L; Blair, D; Bloemen, S; Blom, M; Bock, O; Bodiya, T P; Boer, M; Bogaert, G; Bogan, C; Bond, C; Bondu, F; Bonelli, L; Bonnand, R; Bork, R; Born, M; Boschi, V; Bose, Sukanta; Bosi, L; Bradaschia, C; Brady, P R; Braginsky, V B; Branchesi, M; Brau, J E; Briant, T; Bridges, D O; Brillet, A; Brinkmann, M; Brisson, V; Brooks, A F; Brown, D A; Brown, D D; Brückner, F; Buchman, S; Bulik, T; Bulten, H J; Buonanno, A; Burman, R; Buskulic, D; Buy, C; Cadonati, L; Cagnoli, G; Bustillo, J Calderón; Calloni, E; Camp, J B; Campsie, P; Cannon, K C; Canuel, B; Cao, J; Capano, C D; Carbognani, F; Carbone, L; Caride, S; Castiglia, A; Caudill, S; Cavaglià, M; Cavalier, F; Cavalieri, R; Celerier, C; Cella, G; Cepeda, C; Cesarini, E; Chakraborty, R; Chalermsongsak, T; Chamberlin, S J; Chao, S; Charlton, P; Chassande-Mottin, E; Chen, X; Chen, Y; Chincarini, A; Chiummo, A; Cho, H S; Chow, J; Christensen, N; Chu, Q; Chua, S S Y; Chung, S; Ciani, G; Clara, F; Clark, J A; Cleva, F; Coccia, E; Cohadon, P -F; Colla, A; Collette, C; Colombini, M; Cominsky, L; Constancio, M; Conte, A; Cook, D; Corbitt, T R; Cordier, M; Cornish, N; Corpuz, A; Corsi, A; Costa, C A; Coughlin, M W; Coughlin, S; Coulon, J -P; Countryman, S; Couvares, P; Coward, D M; Cowart, M; Coyne, D C; Coyne, R; Craig, K; Creighton, J D E; Crowder, S G; Cumming, A; Cunningham, L; Cuoco, E; Dahl, K; Canton, T Dal; Damjanic, M; Danilishin, S L; D'Antonio, S; Danzmann, K; Dattilo, V; Daveloza, H; Davier, M; Davies, G S; Daw, E J; Day, R; Dayanga, T; Debreczeni, G; Degallaix, J; Deléglise, S; Del Pozzo, W; Denker, T; Dent, T; Dereli, H; Dergachev, V; De Rosa, R; DeRosa, R T; DeSalvo, R; Dhurandhar, S; Díaz, M; Di Fiore, L; Di Lieto, A; Di Palma, I; Di Virgilio, A; Donath, A; Donovan, F; Dooley, K L; Doravari, S; Dossa, S; Douglas, R; Downes, T P; Drago, M; Drever, R W P; Driggers, J C; Du, Z; Dwyer, S; Eberle, T; Edo, T; Edwards, M; Effler, A; Eggenstein, H; Ehrens, P; Eichholz, J; Eikenberry, S S; Endr?czi, G; Essick, R; Etzel, T; Evans, M; Evans, T; Factourovich, M; Fafone, V; Fairhurst, S; Fang, Q; Farinon, S; Farr, B; Farr, W M; Favata, M; Fehrmann, H; Fejer, M M; Feldbaum, D; Feroz, F; Ferrante, I; Ferrini, F; Fidecaro, F; Finn, L S; Fiori, I; Fisher, R P; Flaminio, R; Fournier, J -D; Franco, S; Frasca, S; Frasconi, F; Frede, M; Frei, Z; Freise, A; Frey, R; Fricke, T T; Fritschel, P; Frolov, V V; Fulda, P; Fyffe, M; Gair, J; Gammaitoni, L; Gaonkar, S; Garufi, F; Gehrels, N; Gemme, G; Genin, E; Gennai, A; Ghosh, S; Giaime, J A; Giardina, K D; Giazotto, A; Gill, C; Gleason, J; Goetz, E; Goetz, R; Gondan, L; González, G; Gordon, N; Gorodetsky, M L; Gossan, S; Goßler, S; Gouaty, R; Gräf, C; Graff, P B; Granata, M; Grant, A; Gras, S; Gray, C; Greenhalgh, R J S; Gretarsson, A M; Groot, P; Grote, H; Grover, K; Grunewald, S; Guidi, G M; Guido, C; Gushwa, K; Gustafson, E K; Gustafson, R; Hammer, D; Hammond, G; Hanke, M; Hanks, J; Hanna, C; Hanson, J; Harms, J; Harry, G M; Harry, I W; Harstad, E D; Hart, M; Hartman, M T; Haster, C -J; Haughian, K; Heidmann, A; Heintze, M; Heitmann, H; Hello, P; Hemming, G; Hendry, M; Heng, I S; Heptonstall, A W; Heurs, M; Hewitson, M; Hild, S; Hoak, D; Hodge, K A; Holt, K; Hooper, S; Hopkins, P; Hosken, D J; Hough, J; Howell, E J; Hu, Y; Hughey, B; Husa, S; Huttner, S H; Huynh, M; Huynh-Dinh, T; Ingram, D R; Inta, R; Isogai, T; Ivanov, A; Iyer, B R; Izumi, K; Jacobson, M; James, E; Jang, H; Jaranowski, P; Ji, Y; Jiménez-Forteza, F; Johnson, W W; Jones, D I; Jones, R; Jonker, R J G; Ju, L; K, Haris; Kalmus, P; Kalogera, V; Kandhasamy, S; Kang, G; Kanner, J B; Karlen, J; Kasprzack, M; Katsavounidis, E; Katzman, W; Kaufer, H; Kawabe, K; Kawazoe, F; Kéfélian, F; Keiser, G M; Keitel, D; Kelley, D B; Kells, W; Khalaidovski, A; Khalili, F Y; Khazanov, E A; Kim, C; Kim, K; Kim, N; Kim, N G; Kim, Y -M; King, E J; King, P J; Kinzel, D L; Kissel, J S; Klimenko, S; Kline, J; Koehlenbeck, S; Kokeyama, K; Kondrashov, V; Koranda, S; Korth, W Z; Kowalska, I

    2014-01-01T23:59:59.000Z

    The Numerical INJection Analysis (NINJA) project is a collaborative effort between members of the numerical relativity and gravitational-wave astrophysics communities. The purpose of NINJA is to study the ability to detect gravitational waves emitted from merging binary black holes and recover their parameters with next-generation gravitational-wave observatories. We report here on the results of the second NINJA project, NINJA-2, which employs 60 complete binary black hole hybrid waveforms consisting of a numerical portion modelling the late inspiral, merger, and ringdown stitched to a post-Newtonian portion modelling the early inspiral. In a "blind injection challenge" similar to that conducted in recent LIGO and Virgo science runs, we added 7 hybrid waveforms to two months of data recolored to predictions of Advanced LIGO and Advanced Virgo sensitivity curves during their first observing runs. The resulting data was analyzed by gravitational-wave detection algorithms and 6 of the waveforms were recovered w...

  14. Influence of temperature on the mechanism of carrier injection in light-emitting diodes based on InGaN/GaN multiple quantum wells

    SciTech Connect (OSTI)

    Prudaev, I. A., E-mail: jaia@pochta.ru; Golygin, I. Yu.; Shirapov, S. B.; Romanov, I. S.; Khludkov, S. S.; Tolbanov, O. P. [Tomsk State University (Russian Federation)] [Tomsk State University (Russian Federation)

    2013-10-15T23:59:59.000Z

    The experimental current-voltage characteristics and dependences of the external quantum yield on the current density of light-emitting diodes based on InGaN/GaN multiple quantum wells for the wide temperature range T = 10-400 K are presented. It is shown that, at low-temperatures T < 100 K, the injection of holes into the quantum wells occurs from localized acceptor states. The low-temperature injection of electrons into p-GaN occurs due to quasi-ballistic transport in the region of multiple quantum wells. An increase in temperature leads to an increase in the current which is governed by thermally activated hole and electron injection from the allowed bands of GaN.

  15. High Speed, Low Cost Fabrication of Gas Diffusion Electrodes for Membrane Electrode Assemblies

    SciTech Connect (OSTI)

    DeCastro, Emory S.; Tsou, Yu-Min; Liu, Zhenyu

    2013-09-20T23:59:59.000Z

    Fabrication of membrane electrode assemblies (MEAs) depends on creating inks or pastes of catalyst and binder, and applying this suspension to either the membrane (catalyst coated membrane) or gas diffusion media (gas diffusion electrode) and respectively laminating either gas diffusion media or gas diffusion electrodes (GDEs) to the membrane. One barrier to cost effective fabrication for either of these approaches is the development of stable and consistent suspensions. This program investigated the fundamental forces that destabilize the suspensions and developed innovative approaches to create new, highly stable formulations. These more concentrated formulations needed fewer application passes, could be coated over longer and wider substrates, and resulted in significantly lower coating defects. In March of 2012 BASF Fuel Cell released a new high temperature product based on these advances, whereby our customers received higher performing, more uniform MEAs resulting in higher stack build yields. Furthermore, these new materials resulted in an “instant” increase in capacity due to higher product yields and material throughput. Although not part of the original scope of this program, these new formulations have also led us to materials that demonstrate equivalent performance with 30% less precious metal in the anode. This program has achieved two key milestones in DOE’s Manufacturing R&D program: demonstration of processes for direct coating of electrodes and continuous in-line measurement for component fabrication.

  16. Thermodynamics of regular black hole

    E-Print Network [OSTI]

    Yun Soo Myung; Yong-Wan Kim; Young-Jai Park

    2008-09-21T23:59:59.000Z

    We investigate thermodynamics for a magnetically charged regular black hole (MCRBH), which comes from the action of general relativity and nonlinear electromagnetics, comparing with the Reissner-Norstr\\"om (RN) black hole in both four and two dimensions after dimensional reduction. We find that there is no thermodynamic difference between the regular and RN black holes for a fixed charge $Q$ in both dimensions. This means that the condition for either singularity or regularity at the origin of coordinate does not affect the thermodynamics of black hole. Furthermore, we describe the near-horizon AdS$_2$ thermodynamics of the MCRBH with the connection of the Jackiw-Teitelboim theory. We also identify the near-horizon entropy as the statistical entropy by using the AdS$_2$/CFT$_1$ correspondence.

  17. Black Hole Interior Mass Formula

    E-Print Network [OSTI]

    Parthapratim Pradhan

    2014-05-06T23:59:59.000Z

    We argue by explicit computations that, although the area product, horizon radii product, entropy product and \\emph {irreducible mass product} of the event horizon and Cauchy horizon are universal, the \\emph{surface gravity product}, \\emph{surface temperature product} and \\emph{Komar energy product} of the said horizons do not seem to be universal for Kerr-Newman (KN) black hole space-time. We show the black hole mass formula on the \\emph{Cauchy horizon} following the seminal work by Smarr\\cite{smarr} for the outer horizon. We also prescribed the \\emph{four} laws of black hole mechanics for the \\emph{inner horizon}. New definition of the extremal limit of a black hole is discussed.

  18. Magnetohydrodynamic effects on pellet injection in tokamaks

    SciTech Connect (OSTI)

    Strauss, H.R. [Courant Institute of Mathematical Sciences, New York University, 251 Mercer Street, New York, New York 10012 (United States)] [Courant Institute of Mathematical Sciences, New York University, 251 Mercer Street, New York, New York 10012 (United States); Park, W. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)] [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

    1998-07-01T23:59:59.000Z

    The location at which pellets are injected into a plasma can have a significant effect on what fraction of the pellet mass remains in the plasma for refueling purposes. Magnetohydrodynamic (MHD) simulations presented here, confirm the results of pellet injection experiments: toroidal curvature makes it favorable to inject pellets from the inboard side or from the top or bottom, rather than from the outboard side. Sufficiently large pellets injected at the inboard edge can reach the plasma center, and in the process drive magnetic reconnection to produce negative central shear. Injection at the top (or bottom) of the tokamak causes relatively little displacement of the pellet. A scaling law is obtained for pellet displacement which agrees well with the simulations. The MHD simulations were carried out with a new unstructured mesh finite element version of the MH3D full MHD code. {copyright} {ital 1998 American Institute of Physics.}

  19. First Principles Calculations and NMR Spectroscopy of Electrode...

    Broader source: Energy.gov (indexed) [DOE]

    and NMR Spectroscopy of Electrode Materials Professor Clare Grey University of Cambridge 6172014 Project ID es055 This presentation does not contain any proprietary,...

  20. First Principles Calculations and NMR Spectroscopy of Electrode...

    Broader source: Energy.gov (indexed) [DOE]

    First Principles Calculations and NMR Spectroscopy of Electrode Materials G. Ceder Massachusetts Institute of technology and C. P Grey Cambridge University and Stony Brook...

  1. Electrostatic coalescence system with independent AC and DC hydrophilic electrodes

    DOE Patents [OSTI]

    Hovarongkura, A. David (Arlington, VA); Henry, Jr., Joseph D. (Morgantown, WV)

    1981-01-01T23:59:59.000Z

    An improved electrostatic coalescence system is provided in which independent AC and DC hydrophilic electrodes are employed to provide more complete dehydration of an oil emulsion. The AC field is produced between an AC electrode array and the water-oil interface wherein the AC electrode array is positioned parallel to the interface which acts as a grounded electrode. The emulsion is introduced into the AC field in an evenly distributed manner at the interface. The AC field promotes drop-drop and drop-interface coalescence of the water phase in the entering emulsion. The continuous oil phase passes upward through the perforated AC electrode array and enters a strong DC field produced between closely spaced DC electrodes in which small dispersed droplets of water entrained in the continuous phase are removed primarily by collection at hydrophilic DC electrodes. Large droplets of water collected by the electrodes migrate downward through the AC electrode array to the interface. All phase separation mechanisms are utilized to accomplish more complete phase separation.

  2. Vehicle Technologies Office Merit Review 2015: Electrode Coating...

    Energy Savers [EERE]

    Vehicle Technologies Office Merit Review 2015: Electrode Coating Defect Analysis and Processing NDE for High-Energy Lithium-Ion Batteries Vehicle Technologies Office Merit Review...

  3. Wick-and-pool electrodes for electrochemical cell

    DOE Patents [OSTI]

    Roche, Michael F. (Downers Grove, IL); Faist, Suzan M. (Haddonfield, NJ); Eberhart, James G. (Naperville, IL); Ross, Laurids E. (Naperville, IL)

    1980-01-01T23:59:59.000Z

    An electrode system includes a reservoir of liquid-metal reactant, and a wick extending from a submersed location within the reservoir into the molten electrolyte of an electrochemical cell structure. The wick is flooded with the liquid metal and thereby serves as one electrode within the cell. This electrode system has application in high-temperature batteries employing molten alkali metals or their alloys as active material within an electrode submersed within a molten salt electrolyte. It also can be used in electrochemical cells where the purification, separation or electrowinning of liquid metals is accomplished.

  4. Molecular Simulations of Electrolytes and Electrolyte/Electrode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Molecular Simulations of Electrolytes and ElectrolyteElectrode Interfaces Grant D. Smith and Oleg Borodin Department of Materials Science & Engineering University of Utah 0218...

  5. Microscale Electrode Design Using Coupled Kinetic, Thermal and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modeling of FIB Micro-machined Electrodes Modeling-Thermo-electrochemistry, Capacity Degradation and Mechanics with SEI Layer Characterization of Materials for Li-ion Batteries:...

  6. In Situ Characterization of Fatigue Behavior of Electrodes

    Broader source: Energy.gov (indexed) [DOE]

    Subject specific optimized sample configuration and testing with standard recipes * Composite Electrodes * Silicon or carbon * PVDF, Super S Carbon (8:1:1 by wt) * NMP solvent *...

  7. Intermetallic Electrodes Improve Safety and Performance in Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intermetallic Electrodes Improve Safety and Performance in Lithium-Ion Batteries Technology available for licensing: A new class of intermetallic material that can be used as a...

  8. Layered Electrodes for Lithium Cells and Batteries | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Layered Electrodes for Lithium Cells and Batteries Technology available for licensing: Layered lithium metal oxide compounds for ultra-high-capacity, rechargeable cathodes Lowers...

  9. Electrode Materials for Rechargeable Lithium-Ion Batteries: A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrode Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic Approach Technology available for licensing: New high-energy cathode materials for use in rechargeable...

  10. Electrode Structures and Surfaces for Lithium Batteries | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures and Surfaces for Lithium Batteries Technology available for licensing: Lithium-metal-oxide electrode materials with modified surfaces to protect the materials from...

  11. Vehicle Technologies Office Merit Review 2014: Dry Process Electrode Fabrication

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dry process electrode...

  12. Negative Electrodes Improve Safety in Lithium Cells and Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Negative Electrodes Improve Safety in Lithium Cells and Batteries Technology available for licensing: Enhanced stability at a lower cost Lowers cost for enhanced stability...

  13. Vehicle Technologies Office Merit Review 2015: Dry Process Electrode Fabrication

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dry process electrode...

  14. Fundamental Approach to Electrode Fabrication and Failure Analysis

    Broader source: Energy.gov (indexed) [DOE]

    Fundamental Approach to Electrode Fabrication and Failure Analysis Vince Battaglia LBNL May 11, 2011 This presentation does not contain any proprietary, confidential, or otherwise...

  15. Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sorted Single-Walled Carbon Nanotube Films for Transparent Electrodes in Organic Solar Cells Home > Research > ANSER Research Highlights > Sorted Single-Walled Carbon Nanotube...

  16. First Principles Calculations and NMR Spectroscopy of Electrode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Calculations and NMR Spectroscopy of Electrode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

  17. Investigation of critical parameters in Li-ion battery electrodes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Negative Electrodes: Novel and Optimized Materials Novel and Optimized Materials Phases for High Energy Density Batteries FY 2012 Annual Progress Report for Energy Storage R&D...

  18. The Impact of Electrode Structure on the Processes that Limit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Bethesda, Maryland. merit08wheeler.pdf More Documents & Publications Overview of the Batteries for Advanced Transportation Technologies (BATT) Program New Electrode Designs...

  19. Polyaniline-Supported Atomic Gold Electrodes: Comparison with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PANI coated platinum electrodes by testing electrochemical oxidation of n-propanol and iso-propanol. This study allowed us to separate the behavior dominated by that of...

  20. Voltammetric Analysis of Europium at Screen-Printed Electrodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Voltammetric Analysis of Europium at Screen-Printed Electrodes Modified with Salicylamide Self-Assembled on Mesoporous Silica. Voltammetric Analysis of Europium at Screen-Printed...

  1. New Li-alloy electrode for Li-alloy/metal sulfide cells

    SciTech Connect (OSTI)

    Kaun, T.D.

    1994-12-31T23:59:59.000Z

    The present invention relates to electrodes for use in secondary electrochemical cells. More particularly, it concerns a method of making a negative electrode composition, the electrode composition made thereby and the secondary electrochemical cell containing the electrode, wherein the negative electrode composition includes a lithium alloy including silicon and nickel.

  2. Electrochemical cell including ribbed electrode substrates

    SciTech Connect (OSTI)

    Breault, R.D.; Goller, G.J.; Roethlein, R.J.; Sprecher, G.C.

    1981-07-21T23:59:59.000Z

    An electrochemical cell including an electrolyte retaining matrix layer located between and in contact with cooperating anode and cathode electrodes is disclosed herein. Each of the electrodes is comprised of a ribbed (or grooved) substrate including a gas porous body as its main component and a catalyst layer located between the substrate and one side of the electrolyte retaining matrix layer. Each substrate body includes a ribbed section for receiving reactant gas and lengthwise side portions on opposite sides of the ribbed section. Each of the side portions includes a channel extending along its entire length from one surface thereof (e.g., its outer surface) to but stopping short of an opposite surface (e.g., its inner surface) so as to provide a web directly between the channel and the opposite surface. Each of the channels is filled with a gas impervious substance and each of the webs is impregnated with a gas impervious substance so as to provide a gas impervious seal along the entire length of each side portion of each substrate and between the opposite faces thereof (e.g., across the entire thickness thereof).

  3. Fishing in Black Holes

    E-Print Network [OSTI]

    A. Brotas

    2006-09-01T23:59:59.000Z

    The coordinate system $(\\bar{x},\\bar{t})$ defined by $r = 2m + K\\bar{x}- c K \\bar{t}$ and $t=\\bar{x}/cK - 1 /cK \\int_{r_a}^r (1- 2m/r + K^2)^{1/2} (1 - 2m/r)^{-1}dr$ allow us to write the Schwarzschild metric in the form: \\[ds^2=c^2 d\\bar{t}^2 + (W^2/K^2 - 2W/K) d\\bar{x}^2 + 2c (1 + W/K) d\\bar{x}d\\bar{t} - r^2 (d\\theta^2 + cos^2\\theta d\\phi^2)\\] with $W=(1 - 2m/r + K^2)^{1/2}$, in which the coefficients' pathologies are moved to $r_K = 2m/(1+K^2)$. This new coordinate system is used to study the entrance into a black hole of a rigid line (a line in which the shock waves propagate with velocity c).

  4. Stability analysis and testing of a train of centrifugal compressors for high pressure gas injection

    SciTech Connect (OSTI)

    Memmott, E.A. [Dresser-Rand Co., Olean, NY (United States)

    1999-07-01T23:59:59.000Z

    This paper describes the rotor dynamic stability analysis and the PTC-10 Class 1 test of a three body centrifugal compressor train for high pressure natural gas injection services. This train had a full load full pressure string test on hydrocarbon gases to a final discharge pressure of 500 BAR (7250 PSIA). Each compressor is of the back to back configuration, and is equipped with tilting pad seals, damper bearings, and a honeycomb labyrinth at the division wall with shunt holes. The driver is a gas turbine.

  5. Study of Influence of Electrode Geometry on Impedance Spectroscopy

    SciTech Connect (OSTI)

    Ahmed, Riaz; Reifsnider, Kenneth L

    2011-01-01T23:59:59.000Z

    Electrochemical Impedance Spectroscopy (EIS) is a powerful and proven tool for analyzing AC impedance response. A conventional three electrode EIS method was used to perform the investigation in the present study. Saturated potassium chloride solution was used as the electrolyte and three different material rods were used as working electrodes. Different configurations of electrode area were exposed to the electrolyte as an active area to investigate electrode geometry effects. Counter to working electrode distance was also altered while keeping the working electrode effective area constant to explore the AC response dependence on the variation of ion travel distance. Some controlled experiments were done to validate the experimental setup and to provide a control condition for comparison with experimental results. A frequency range of 100 mHz to 1 MHz was used for all experiments. In our analysis, we have found a noteworthy influence of electrode geometry on AC impedance response. For all electrodes, impedance decreases with the increase of effective area of the electrolyte. High frequency impedance is not as dependent on geometry as low frequency response. The observed phase shift angle drops in the high frequency region with increased working electrode area, whereas at low frequency the reverse is true. Resistance and capacitive reactance both decrease with an increase of area, but resistance response is more pronounce than reactance. For lower frequencies, small changes in working area produce very distinctive EIS variations. Electrode material as well as geometry was systematically varied in the present study. From these and other studies, we hope to develop a fundamental foundation for understanding specific changes in local geometry in fuel cell (and other) electrodes as a method of designing local morphology for specific performance.

  6. Integrated injection-locked semiconductor diode laser

    DOE Patents [OSTI]

    Hadley, G. Ronald (Albuquerque, NM); Hohimer, John P. (Albuquerque, NM); Owyoung, Adelbert (Albuquerque, NM)

    1991-01-01T23:59:59.000Z

    A continuous wave integrated injection-locked high-power diode laser array is provided with an on-chip independently-controlled master laser. The integrated injection locked high-power diode laser array is capable of continuous wave lasing in a single near-diffraction limited output beam at single-facet power levels up to 125 mW (250 mW total). Electronic steering of the array emission over an angle of 0.5 degrees is obtained by varying current to the master laser. The master laser injects a laser beam into the slave array by reflection of a rear facet.

  7. Integrated injection-locked semiconductor diode laser

    DOE Patents [OSTI]

    Hadley, G.R.; Hohimer, J.P.; Owyoung, A.

    1991-02-19T23:59:59.000Z

    A continuous wave integrated injection-locked high-power diode laser array is provided with an on-chip independently-controlled master laser. The integrated injection locked high-power diode laser array is capable of continuous wave lasing in a single near-diffraction limited output beam at single-facet power levels up to 125 mW (250 mW total). Electronic steering of the array emission over an angle of 0.5 degrees is obtained by varying current to the master laser. The master laser injects a laser beam into the slave array by reflection of a rear facet. 18 figures.

  8. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2003-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  9. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2002-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  10. Seebeck and Peltier coefficients of hydrogen electrodes related to the

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Seebeck and Peltier coefficients of hydrogen electrodes related to the PEMFC Papy Zefaniya Chemical and Technology #12;#12;Thermopower of concentration cell with hydrogen electrodes related to PEMFC Papy Mutuwa and learn more thermal effects and the fuel cells. In deed, fuel cell were the best candidate to learn more

  11. Characteristics of a corona discharge with a hot corona electrode

    SciTech Connect (OSTI)

    Kulumbaev, E. B.; Lelevkin, V. M.; Niyazaliev, I. A.; Tokarev, A. V. [Kyrgyz-Russian Slavic University (Kyrgyzstan)

    2011-08-15T23:59:59.000Z

    The effect of the temperature of the corona electrode on the electrical characteristics of a corona discharge was studied experimentally. A modified Townsend formula for the current-voltage characteristic of a one-dimensional corona is proposed. Gasdynamic and thermal characteristics of a positive corona discharge in a coaxial electrode system are calculated. The calculated results are compared with the experimental data.

  12. TEMPERATURE DISTRIBUTION AND ENERGY BALANCE IN THE ELECTRODE DURING GMAW

    E-Print Network [OSTI]

    Eagar, Thomas W.

    I ll l ). TEMPERATURE DISTRIBUTION AND ENERGY BALANCE IN THE ELECTRODE DURING GMAW Yong-Seog Kim and Energy Balance in the Electrode during GMAW by Yong-Seog Kim and T.W. Eagar Department of Materials shielding gases (argon, helium, and C02) using the PHOENICS computer code. An energy balance analysis

  13. Aquagel electrode separator for use in batteries and supercapacitors

    DOE Patents [OSTI]

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1995-03-28T23:59:59.000Z

    An electrode separator is described for electrochemical energy storage devices, such as a high energy density capacitor incorporating a variety of carbon foam electrodes. The separator is derived from an aquagel of resorcinol-formaldehyde and related polymers and containing ionically conducting electrolyte in the pores thereof. 9 figures.

  14. anode electrode materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    anode electrode materials First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Nanostructured Electrode...

  15. Method of making a layered composite electrode/electrolyte

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (El Cerrito, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2005-01-25T23:59:59.000Z

    An electrode/electrolyte structure is prepared by a plurality of methods. An unsintered (possibly bisque fired) moderately catalytic electronically-conductive or homogeneous mixed ionic electronic conductive electrode material is deposited on a layer composed of a sintered or unsintered ionically-conductive electrolyte material prior to being sintered. A layer of particulate electrode material is deposited on an unsintered ("green") layer of electrolyte material and the electrode and electrolyte layers are sintered simultaneously, sometimes referred to as "co-firing," under conditions suitable to fully densify the electrolyte while the electrode retains porosity. Or, the layer of particulate electrode material is deposited on a previously sintered layer of electrolyte, and then sintered. Subsequently, a catalytic material is added to the electrode structure by infiltration of an electrolcatalyst precursor (e.g., a metal salt such as a transition metal nitrate). This may be followed by low temperature firing to convert the precursor to catalyst. The invention allows for an electrode with high electronic conductivity and sufficient catalytic activity to achieve high power density in an ionic (electrochemical) device such as fuel cells and electrolytic gas separation systems.

  16. Oriented nanotube electrodes for lithium ion batteries and supercapacitors

    DOE Patents [OSTI]

    Frank, Arthur J.; Zhu, Kai; Wang, Qing

    2013-03-05T23:59:59.000Z

    An electrode having an oriented array of multiple nanotubes is disclosed. Individual nanotubes have a lengthwise inner pore defined by interior tube walls which extends at least partially through the length of the nanotube. The nanotubes of the array may be oriented according to any identifiable pattern. Also disclosed is a device featuring an electrode and methods of fabrication.

  17. Aquagel electrode separator for use in batteries and supercapacitors

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1995-01-01T23:59:59.000Z

    An electrode separator for electrochemical energy storage devices, such as a high energy density capacitor incorporating a variety of carbon foam electrodes. The separator is derived from an aquagel of resorcinol-formaldehyde and related polymers and containing ionically conducting electrolyte in the pores thereof.

  18. On the Electrochemical Response of Porous Functionalized Graphene Electrodes

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    prominent examples include electrical energy storage devices such as batteries3-5 and energy conversion. 1. INTRODUCTION Porous electrodes are used in numerous areas of electro- chemistry:1,2 The most of electrode porosity in these energy- related systems has been studied in great detail both experimentally8

  19. Cyclic powder formation during pulsed injection of hexamethyldisiloxane in an axially asymmetric radiofrequency argon discharge

    SciTech Connect (OSTI)

    Despax, B.; Makasheva, K. [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d'Energie), 118 route de Narbonne, F-31062 Toulouse 09 (France); CNRS, LAPLACE, F-31062 Toulouse cedex 09 (France); Caquineau, H. [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d'Energie), 118 route de Narbonne, F-31062 Toulouse 09 (France)

    2012-11-01T23:59:59.000Z

    A new approach of periodic production of dusty plasma consisting of pulsed injection of hexamethyldisiloxane (HMDSO) in argon axially asymmetric radiofrequency (RF) discharge was investigated in this work. The range of plasma operating conditions in which this dusty plasma can exist was closely examined. The obtained results clearly show that a net periodicity in the formation/disappearance of dust particles in the plasma can be maintained on a very large scale of discharge duration. The significance of discharge axial asymmetry to the dust particles behaviour in the plasma is revealed by the development of an asymmetric in shape void shifted towards the powered RF electrode. The key role of the reactive gas and its pulsed injection on each stage of the oscillating process of formation/disappearance of dust particles is disclosed by optical and electrical measurements. It is shown that the period of dusty plasma formation/disappearance is inversely related to the HMDSO injection time. Moreover, the impact of time injection over short period (5 s) is examined. It indicates the conflicting role played by the HMDSO on the reduction of dusty plasma during the reactive gas injection and the reappearance of particles in the plasma during the time off. The electronegative behavior of the plasma in the presence of negatively charged particles seems to explain the energetic modifications in the discharge. A frequency analysis of the floating potential reveals all these cyclic processes. Particularly, in the 10-200 Hz frequency range, the presence and the evolution of dust particles in the plasma over one generation can be observed.

  20. Percutaneous Radiofrequency Lung Ablation Combined with Transbronchial Saline Injection: An Experimental Study in Swine

    SciTech Connect (OSTI)

    Kawai, T., E-mail: t-kawai@hosp.yoka.hyogo.jp; Kaminou, T., E-mail: kaminout@grape.med.tottori-u.ac.jp; Sugiura, K.; Hashimoto, M.; Ohuchi, Y.; Adachi, A. [Tottori University, Division of Radiology, Department of Pathophysiological and Therapeutic Science, Faculty of Medicine (Japan); Fujioka, S.; Ito, H. [Tottori University, Division of Organ Pathology, Department of Microbiology and Pathology, Faculty of Medicine (Japan); Nakamura, K. [Hakuai Hospital, Department of Radiology (Japan); Ihaya, T. [Sanin Rosai Hospital, Department of Radiology (Japan); Ogawa, T. [Tottori University, Division of Radiology, Department of Pathophysiological and Therapeutic Science, Faculty of Medicine (Japan)

    2010-02-15T23:59:59.000Z

    To evaluate the efficacy of radiofrequency lung ablation with transbronchial saline injection. The bilateral lungs of eight living swine were used. A 13-gauge bone biopsy needle was inserted percutaneously into the lung, and 1 ml of muscle paste was injected to create a tumor mimic. In total, 21 nodules were ablated. In the saline injection group (group A), radiofrequency ablation (RFA) was performed for 11 nodules after transbronchial saline injection under balloon occlusion with a 2-cm active single internally cooled electrode. In the control group (group B), conventional RFA was performed for 10 nodules as a control. The infused saline liquid showed a wedge-shaped and homogeneous distribution surrounding a tumor mimic. All 21 RFAs were successfully completed. The total ablation time was significantly longer (13.4 {+-} 2.8 min vs. 8.9 {+-} 3.5 min; P = 0.0061) and the tissue impedance was significantly lower in group A compared with group B (73.1 {+-} 8.8 {Omega} vs. 100.6 {+-} 16.6 {Omega}; P = 0.0002). The temperature of the ablated area was not significantly different (69.4 {+-} 9.1{sup o}C vs. 66.0 {+-} 7.9{sup o}C; P = 0.4038). There was no significant difference of tumor mimic volume (769 {+-} 343 mm{sup 3} vs. 625 {+-} 191 mm{sup 3}; P = 0.2783). The volume of the coagulated area was significantly larger in group A than in group B (3886 {+-} 1247 mm{sup 3} vs. 2375 {+-} 1395 mm{sup 3}; P = 0.0221). Percutaneous radiofrequency lung ablation combined with transbronchial saline injection can create an extended area of ablation.

  1. The design of a microfabricated air electrode for liquid electrolyte fuel cells

    E-Print Network [OSTI]

    Pierre, Fritz, 1977-

    2007-01-01T23:59:59.000Z

    In this dissertation, the microfabricated electrode (MFE) concept was applied to the design of an air electrode for liquid electrolyte fuel cells. The catalyst layer of the electrode is envisioned to be fabricated by using ...

  2. Gene expression and deletion analysis of mechanisms for electron transfer from electrodes to Geobacter sulfurreducens

    E-Print Network [OSTI]

    Lovley, Derek

    transfer to electrodes. Keywords: microbial fuel cell, Geobacter sulfurreducens, cathode, electron donor. Surprisingly, genes for putative cell-electrode connections, such as outer-surface cytochromes and pili, which emerging area in microbe-electrode interactio

  3. Multi-layer electrode for high contrast electrochromic devices

    SciTech Connect (OSTI)

    Schwendeman, Irina G. (Wexford, PA); Finley, James J. (Pittsburgh, PA); Polcyn, Adam D. (Pittsburgh, PA); Boykin, Cheri M. (Wexford, PA)

    2011-11-01T23:59:59.000Z

    An electrochromic device includes a first substrate spaced from a second substrate. A first transparent conductive electrode is formed over at least a portion of the first substrate. A polymeric anode is formed over at least a portion of the first conductive electrode. A second transparent conductive electrode is formed over at least a portion of the second substrate. In one aspect of the invention, a multi-layer polymeric cathode is formed over at least a portion of the second conductive electrode. In one non-limiting embodiment, the multi-layer cathode includes a first cathodically coloring polymer formed over at least a portion of the second conductive electrode and a second cathodically coloring polymer formed over at least a portion of the first cathodically coloring polymer. An ionic liquid is positioned between the anode and the cathode.

  4. Focused shock spark discharge drill using multiple electrodes

    DOE Patents [OSTI]

    Moeny, William M. (Albuquerque, NM); Small, James G. (Albuquerque, NM)

    1988-01-01T23:59:59.000Z

    A spark discharge focused drill provided with one pulse forming line or a number of pulse forming lines. The pulse forming line is connected to an array of electrodes which would form a spark array. One of the electrodes of each of the array is connected to the high voltage side of the pulse forming line and the other electrodes are at ground potential. When discharged in a liquid, these electrodes produce intense focused shock waves that can pulverize or fracture rock. By delaying the firing of each group of electrodes, the drill can be steered within the earth. Power can be fed to the pulse forming line either downhole or from the surface area. A high voltage source, such as a Marx generator, is suitable for pulse charging the lines.

  5. Coplanar interdigitated grid detector with single electrode readout

    DOE Patents [OSTI]

    Luke, Paul N. (Castro Valley, CA)

    2001-01-01T23:59:59.000Z

    The coplanar interdigitated grid technique with single electrode readout provides substantial spectral performance improvement over that of conventional full-area planar electrode detectors and over coplanar interdigitated grid detectors which measure the difference between the induced charge signals from two interdigitated coplanar grid electrodes. The signal from only one interdigitated grid electrode is read out. The signal response is optimized by changing the relative areas of the two grid electrodes and the bias applied across the detector. Only one preamplifier is needed and signal subtraction is not necessary. This eliminates the electronic noise contribution from the additional preamplifier used in the normal coplanar grid implementation, and conventional single-amplifier detector electronics can be used.

  6. Zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, Jr., Philip N. (Kensington, CA)

    1989-01-01T23:59:59.000Z

    An improved zinc electrode is disclosed for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed which utilizes the improved zinc electrode and further includes an alkaline electrolyte within said battery circulating through the passageways in the zinc electrode and an external electrolyte circulation means which has an electrolyte reservoir external to the battery case including filter means to filter solids out of the electrolyte as it circulates to the external reservoir and pump means for recirculating electrolyte from the external reservoir to the zinc electrode.

  7. Method for synthesizing thin film electrodes

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM)

    2007-03-13T23:59:59.000Z

    A method for making a thin-film electrode, either an anode or a cathode, by preparing a precursor solution using an alkoxide reactant, depositing multiple thin film layers with each layer approximately 500 1000 .ANG. in thickness, and heating the layers to above 600.degree. C. to achieve a material with electrochemical properties suitable for use in a thin film battery. The preparation of the anode precursor solution uses Sn(OCH.sub.2C(CH.sub.3).sub.3).sub.2 dissolved in a solvent in the presence of HO.sub.2CCH.sub.3 and the cathode precursor solution is formed by dissolving a mixture of (Li(OCH.sub.2C(CH.sub.3).sub.3)).sub.8 and Co(O.sub.2CCH.sub.3).H.sub.2O in at least one polar solvent.

  8. Electrodes including a polyphosphazene cyclomatrix, methods of forming the electrodes, and related electrochemical cells

    DOE Patents [OSTI]

    Gering, Kevin L; Stewart, Frederick F; Wilson, Aaron D; Stone, Mark L

    2014-10-28T23:59:59.000Z

    An electrode comprising a polyphosphazene cyclomatrix and particles within pores of the polyphosphazene cyclomatrix. The polyphosphazene cyclomatrix comprises a plurality of phosphazene compounds and a plurality of cross-linkages. Each phosphazene compound of the plurality of phosphazene compounds comprises a plurality of phosphorus-nitrogen units, and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. Each phosphorus-nitrogen unit is bonded to an adjacent phosphorus-nitrogen unit. Each cross-linkage of the plurality of cross-linkages bonds at least one pendant group of one phosphazene compound of the plurality of phosphazene compounds with the at least one pendant group of another phosphazene compound of the plurality of phosphazene compounds. A method of forming a negative electrode and an electrochemical cell are also described.

  9. Underground Injection Control Fee Schedule (West Virginia)

    Broader source: Energy.gov [DOE]

    This rule establishes schedules of permit fees for state under?ground injection control permits issued by the Chief of the Office of Water Resources. This rule applies to any person who is...

  10. Intradermal needle-free powdered drug injection

    E-Print Network [OSTI]

    Liu, John (John Hsiao-Yung)

    2012-01-01T23:59:59.000Z

    This thesis presents a new method for needle-free powdered drug injection. The design, construction, and testing of a bench-top helium-powered device capable of delivering powder to controllable depths within the dermis ...

  11. Arkansas Underground Injection Control Code (Arkansas)

    Broader source: Energy.gov [DOE]

    The Arkansas Underground Injection Control Code (UIC code) is adopted pursuant to the provisions of the Arkansas Water and Air Pollution Control Act (Arkansas Code Annotated 8-5-11). It is the...

  12. A case study of seawater injection incompatibility

    SciTech Connect (OSTI)

    Lindlof, J.C.; Stoffer, K.G.

    1983-07-01T23:59:59.000Z

    One of the primary concerns in the implementation of an effective waterflood is the compatibility between the formation water and the water to be injected. The Arabian American Oil Co. (ARAMCO) and the Saudi Arabian Ministry of Petroleum and Mineral Resources Technical Branch recognized a potential incompatibility problem and embarked on a comprehensive program to evaluate possible strontium sulfate and calcium sulfate scaling associated with the injection of seawater into the Arab-D reservoir in the northern areas of Ghawar field.

  13. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01T23:59:59.000Z

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  14. Ultrafast Charge Separation and Nongeminate Electron-Hole Recombination in Organic Photovoltaics

    E-Print Network [OSTI]

    Samuel L Smith; Alex W Chin

    2014-06-04T23:59:59.000Z

    The mechanism of electron-hole separation in organic solar cells is currently hotly debated. Recent experimental work suggests that these charges can separate on extremely short timescales (<100 fs). This can be understood in terms of delocalised transport within fullerene aggregates, which is thought to emerge on short timescales before vibronic relaxation induces polaron formation. However, in the optimal heterojunction morphology, electrons and holes will often re-encounter each other before reaching the electrodes. If such charges trap and cannot separate, then device efficiency will suffer. Here we extend the theory of ultrafast charge separation to incorporate polaron formation, and find that the same delocalised transport used to explain ultrafast charge separation can account for the suppression of nongeminate recombination in the best devices.

  15. Orthogonal ion injection apparatus and process

    DOE Patents [OSTI]

    Kurulugama, Ruwan T; Belov, Mikhail E

    2014-04-15T23:59:59.000Z

    An orthogonal ion injection apparatus and process are described in which ions are directly injected into an ion guide orthogonal to the ion guide axis through an inlet opening located on a side of the ion guide. The end of the heated capillary is placed inside the ion guide such that the ions are directly injected into DC and RF fields inside the ion guide, which efficiently confines ions inside the ion guide. Liquid droplets created by the ionization source that are carried through the capillary into the ion guide are removed from the ion guide by a strong directional gas flow through an inlet opening on the opposite side of the ion guide. Strong DC and RF fields divert ions into the ion guide. In-guide orthogonal injection yields a noise level that is a factor of 1.5 to 2 lower than conventional inline injection known in the art. Signal intensities for low m/z ions are greater compared to convention inline injection under the same processing conditions.

  16. albumin ions injected: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    19 Hunt, Galen 3 Characterizing Oligosaccharides Using Injected-Ion MobilityMass Spectrometry Chemistry Websites Summary: Characterizing Oligosaccharides Using Injected-Ion...

  17. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

  18. Advanced Diesel Common Rail Injection System for Future Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Common Rail Injection System for Future Emission Legislation Advanced Diesel Common Rail Injection System for Future Emission Legislation 2004 Diesel Engine Emissions Reduction...

  19. Adaptive Injection Strategies (AIS) for Ultra-low Emissions Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection Strategies (AIS) for Ultra-low Emissions Diesel Engines Adaptive Injection Strategies (AIS) for Ultra-low Emissions Diesel Engines Presentation given at the 2007 Diesel...

  20. automated flow injection: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the great majority the feasibility of our attack. The friend injection attack enables a stealth infiltra- tion of social networks Boyer, Edmond 7 Preventing injection attacks...

  1. Fuel Formulation Effects on Diesel Fuel Injection, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission...

  2. 3-Cylinder Turbocharged Gasoline Direct Injection: A High Value...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cylinder Turbocharged Gasoline Direct Injection: A High Value Solution for Euro VI Emissions 3-Cylinder Turbocharged Gasoline Direct Injection: A High Value Solution for Euro VI...

  3. Vehicle Technologies Office Merit Review 2014: Roll-to-Roll Electrode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Roll-to-Roll Electrode Processing NDE for Advanced Lithium Secondary Batteries Vehicle Technologies Office Merit Review 2014: Roll-to-Roll Electrode Processing NDE for Advanced...

  4. Roll-to-Roll Electrode Processing NDE for Advanced Lithium Secondary...

    Broader source: Energy.gov (indexed) [DOE]

    in-line, cross-web laser sensing for electrode thickness monitoring. - Routine IR thermography for electrode coating defects (agglomerates, pinholes, blisters, divots, metal...

  5. Heat Engine of black holes

    E-Print Network [OSTI]

    Sadeghi, J

    2015-01-01T23:59:59.000Z

    As we know, the cosmological constant in different theories of gravity acts as a thermodynamics variable. The cosmological constant exists in different actions of gravity and also appears in the solution of such theories. These lead to use the black hole as a heat engines. Also, there are two values for the cosmological constant as positive and negative values. The case of negative cosmological constant supplies a natural realization of these engines in terms of the field theory description of the fluids to which they are holographically dual. In this paper, we are going to define heat engines for two different black holes as Dyonic BH and Kerr BH. And also, we calculate maximum efficiency for two black holes.

  6. Heat Engine of black holes

    E-Print Network [OSTI]

    J. Sadeghi; Kh. Jafarzade

    2015-04-29T23:59:59.000Z

    As we know, the cosmological constant in different theories of gravity acts as a thermodynamics variable. The cosmological constant exists in different actions of gravity and also appears in the solution of such theories. These lead to use the black hole as a heat engines. Also, there are two values for the cosmological constant as positive and negative values. The case of negative cosmological constant supplies a natural realization of these engines in terms of the field theory description of the fluids to which they are holographically dual. In this paper, we are going to define heat engines for two different black holes as Dyonic BH and Kerr BH. And also, we calculate maximum efficiency for two black holes.

  7. Energy on black hole spacetimes

    E-Print Network [OSTI]

    Alejandro Corichi

    2012-07-18T23:59:59.000Z

    We consider the issue of defining energy for test particles on a background black hole spacetime. We revisit the different notions of energy as defined by different observers. The existence of a time-like isometry allows for the notion of a total conserved energy to be well defined, and subsequently the notion of a gravitational potential energy is also meaningful. We then consider the situation in which the test particle is adsorbed by the black hole, and analyze the energetics in detail. In particular, we show that the notion of horizon energy es defined by the isolated horizons formalism provides a satisfactory notion of energy compatible with the particle's conserved energy. As another example, we comment a recent proposal to define energy of the black hole as seen by an observer at rest. This account is intended to be pedagogical and is aimed at the level of and as a complement to the standard textbooks on the subject.

  8. Application of Gaseous Sphere Injection Method for Modeling Under-expanded H2 Injection

    SciTech Connect (OSTI)

    Whitesides, R; Hessel, R P; Flowers, D L; Aceves, S M

    2010-12-03T23:59:59.000Z

    A methodology for modeling gaseous injection has been refined and applied to recent experimental data from the literature. This approach uses a discrete phase analogy to handle gaseous injection, allowing for addition of gaseous injection to a CFD grid without needing to resolve the injector nozzle. This paper focuses on model testing to provide the basis for simulation of hydrogen direct injected internal combustion engines. The model has been updated to be more applicable to full engine simulations, and shows good agreement with experiments for jet penetration and time-dependent axial mass fraction, while available radial mass fraction data is less well predicted.

  9. Introduction to Black Hole Evaporation

    E-Print Network [OSTI]

    Pierre-Henry Lambert

    2014-01-16T23:59:59.000Z

    These lecture notes are an elementary and pedagogical introduction to the black hole evaporation, based on a lecture given by the author at the Ninth Modave Summer School in Mathematical Physics and are intended for PhD students. First, quantum field theory in curved spacetime is studied and tools needed for the remaining of the course are introduced. Then, quantum field theory in Rindler spacetime in 1+1 dimensions and in the spacetime of a spherically collapsing star are considered, leading to Unruh and Hawking effects, respectively. Finally, some consequences such as thermodynamics of black holes and information loss paradox are discussed.

  10. Hawking Emission and Black Hole Thermodynamics

    E-Print Network [OSTI]

    Don N. Page

    2006-12-18T23:59:59.000Z

    A brief review of Hawking radiation and black hole thermodynamics is given, based largely upon hep-th/0409024.

  11. High precision, rapid laser hole drilling

    DOE Patents [OSTI]

    Chang, Jim J.; Friedman, Herbert W.; Comaskey, Brian J.

    2013-04-02T23:59:59.000Z

    A laser system produces a first laser beam for rapidly removing the bulk of material in an area to form a ragged hole. The laser system produces a second laser beam for accurately cleaning up the ragged hole so that the final hole has dimensions of high precision.

  12. Signatures of black holes at the LHC

    E-Print Network [OSTI]

    Marco Cavaglia; Romulus Godang; Lucien M. Cremaldi; Donald J. Summers

    2007-07-02T23:59:59.000Z

    Signatures of black hole events at CERN's Large Hadron Collider are discussed. Event simulations are carried out with the Fortran Monte Carlo generator CATFISH. Inelasticity effects, exact field emissivities, color and charge conservation, corrections to semiclassical black hole evaporation, gravitational energy loss at formation and possibility of a black hole remnant are included in the analysis.

  13. High precision, rapid laser hole drilling

    DOE Patents [OSTI]

    Chang, Jim J.; Friedman, Herbert W.; Comaskey, Brian J.

    2007-03-20T23:59:59.000Z

    A laser system produces a first laser beam for rapidly removing the bulk of material in an area to form a ragged hole. The laser system produces a second laser beam for accurately cleaning up the ragged hole so that the final hole has dimensions of high precision.

  14. High precision, rapid laser hole drilling

    DOE Patents [OSTI]

    Chang, Jim J.; Friedman, Herbert W.; Comaskey, Brian J.

    2005-03-08T23:59:59.000Z

    A laser system produces a first laser beam for rapidly removing the bulk of material in an area to form a ragged hole. The laser system produces a second laser beam for accurately cleaning up the ragged hole so that the final hole has dimensions of high precision.

  15. Absorption cross section in Lifshitz black hole

    E-Print Network [OSTI]

    Taeyoon Moon; Yun Soo Myung

    2012-10-05T23:59:59.000Z

    We derive the absorption cross section of a minimally coupled scalar in the Lifshitz black hole obtained from the new massive gravity. The absorption cross section reduces to the horizon area in the low energy and massless limit of s-wave mode propagation, indicating that the Lifshitz black hole also satisfies the universality of low energy absorption cross section for black holes.

  16. Intercalation compounds and electrodes for batteries

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Sadoway, Donald R.; Jang, Young-Il; Huang, Biyan

    2004-09-07T23:59:59.000Z

    This invention concerns intercalation compounds and in particular lithium intercalation compounds which have improved properties for use in batteries. Compositions of the invention include particulate metal oxide material having particles of multicomponent metal oxide, each including an oxide core of at least first and second metals in a first ratio, and each including a surface coating of metal oxide or hydroxide that does not include the first and second metals in the first ratio formed by segregation of at least one of the first and second metals from the core. The core may preferably comprise Li.sub.x M.sub.y N.sub.z O.sub.2 wherein M and N are metal atom or main group elements, x, y and z are numbers from about 0 to about 1 and y and z are such that a formal charge on M.sub.y N.sub.z portion of the compound is (4-x), and having a charging voltage of at least about 2.5V. The invention may also be characterized as a multicomponent oxide microstructure usable as a lithium intercalation material including a multiphase oxide core and a surface layer of one material, which is a component of the multiphase oxide core, that protects the underlying intercalation material from chemical dissolution or reaction. In a particular preferred example the multicomponent oxide may be an aluminum-doped lithium manganese oxide composition. Such aluminum-doped lithium manganese oxide compositions, having an orthorhombic structure, also form a part of the invention. In addition, the invention includes articles, particularly electrodes, for batteries formed from the compositions of the invention, and batteries including such electrodes. The invention further relates to a composite intercalation material comprising at least two compounds in which at least one compound has an orthorhombic structure Li.sub.x Al.sub.y Mn.sub.1-y O.sub.2, where y is nonzero, or a mixture of orthorhombic and monoclinic Li.sub.x Al.sub.y Mn.sub.1-y O.sub.2.

  17. Einstein, Black Holes Gravitational Waves

    E-Print Network [OSTI]

    Cook, Greg

    1 #12;Einstein, Black Holes and Gravitational Waves Gregory B. Cook Wake Forest University 2 #12;Einstein's Miraculous Year: 1905 · Einstein, A. "¨Uber einen die Erzeugung und Verwandlung des Lichtes Concerning the Production and Transformation of Light. · Einstein, A. "¨Uber die von der molekularkinetischen

  18. From Pinholes to Black Holes

    SciTech Connect (OSTI)

    Fenimore, Edward E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-10-06T23:59:59.000Z

    Pinhole photography has made major contributions to astrophysics through the use of “coded apertures”. Coded apertures were instrumental in locating gamma-ray bursts and proving that they originate in faraway galaxies, some from the birth of black holes from the first stars that formed just after the big bang.

  19. Supported-sorbent injection. Final report

    SciTech Connect (OSTI)

    Nelson, S. Jr.

    1997-07-01T23:59:59.000Z

    A new retrofitable, wastefree acid-rain control concept was pilot-tested at Ohio Edison`s high-sulfur coal-fired R.E. Burger generating station at the 2-MWe level. During the project, moistened {open_quotes}supported{close_quotes} sorbents, made from a combination of lime and vermiculite or perlite, were injected into a humidified 6,500-acfm flue-gas slipstream. After the sorbents reacted with the sulfur dioxide in the flue gas, they were removed from ductwork with a cyclone and baghouse. The $1.0 million project was co-funded by Sorbent Technologies Corporation, the Ohio Edison Company, and the Ohio Coal Development Office. The project included a preliminary bench-scale testing phase, construction of the pilot plant, parametric studies, numerous series of recycle tests, and a long-term run. The project proceeded as anticipated and achieved its expected results. This duct injection technology successfully demonstrated SO{sub 2}-removal rates of 80 to 90% using reasonable stoichiometric injection ratios (2:1 Ca:S) and approach temperatures (20-25F). Under similar conditions, dry injection of hydrated lime alone typically only achieves 40 to 50% SO{sub 2} removal. During the testing, no difficulties were encountered with deposits in the ductwork or with particulate control, which have been problems in tests of other duct-injection schemes.

  20. Case history of pressure maintenance by gas injection in the 26R gravity drainage reservoir

    SciTech Connect (OSTI)

    Wei, M.H.; Yu, J.P.; Moore, D.M.; Ezekwe, N. (Bechtel Petroleum Operations, Inc., Tupman, CA (United States)); Querin, M.E. (USDOE Naval Petroleum Reserves in California, Tupman, CA (United States)); Williams, L.L. (Chevron U.S.A., Inc., San Francisco, CA (United States))

    1992-01-01T23:59:59.000Z

    This paper is a field case history on the performance of the 26R Reservoir. This is a gravity drainage reservoir under pressure maintenance by crestal gas injection. The 26R Reservoir is a highly layered Stevens turbidite sandstone. The reservoir is located in the Naval Petroleum Reserve No. 1 (NPR{number sign}1) in Elk Hills, Kern County, California. The 26R Reservoir is contained within the steeply dipping southwestern limb of the 31S Anticline. The reservoir had an initial oil column of 1800 feet. Original oil-in-place (OOIP) was estimated at 424 million barrels. Pressure maintenance by crestal gas injection was initiated immediately after production began in October 1976. The total volume of gas injected is about 586 BCF. This exceeds one reservoir pore volume. Reservoir pressure has declined from 3030 psi to 2461 psi. This pressure decline believe to be due to migration of injected gas into the overlaying shale reservoirs. Under the gas injection pressure maintenance strategy, reserves are estimated to be approximately 212 million barrels. Reservoir studies have concluded that the aquifer at the base of the reservoir has been relatively inactive. Well recompletions, deepenings, and horizontal wells are used to improve oil recovery. An aggressive program of controlling gas production began in the mid 1980's by the installation of multiple packers and sleeves. As the gas-oil contact (GOC) has dropped, sand intervals have subsequently been isolated behind packers. A cased hole logging program was recently undertaken to identify possible remaining reserves in the gas cap. 15 refs., 24 figs., 2 tabs.

  1. Case history of pressure maintenance by gas injection in the 26R gravity drainage reservoir

    SciTech Connect (OSTI)

    Wei, M.H.; Yu, J.P.; Moore, D.M.; Ezekwe, N. [Bechtel Petroleum Operations, Inc., Tupman, CA (United States); Querin, M.E. [USDOE Naval Petroleum Reserves in California, Tupman, CA (United States); Williams, L.L. [Chevron U.S.A., Inc., San Francisco, CA (United States)

    1992-02-01T23:59:59.000Z

    This paper is a field case history on the performance of the 26R Reservoir. This is a gravity drainage reservoir under pressure maintenance by crestal gas injection. The 26R Reservoir is a highly layered Stevens turbidite sandstone. The reservoir is located in the Naval Petroleum Reserve No. 1 (NPR{number_sign}1) in Elk Hills, Kern County, California. The 26R Reservoir is contained within the steeply dipping southwestern limb of the 31S Anticline. The reservoir had an initial oil column of 1800 feet. Original oil-in-place (OOIP) was estimated at 424 million barrels. Pressure maintenance by crestal gas injection was initiated immediately after production began in October 1976. The total volume of gas injected is about 586 BCF. This exceeds one reservoir pore volume. Reservoir pressure has declined from 3030 psi to 2461 psi. This pressure decline believe to be due to migration of injected gas into the overlaying shale reservoirs. Under the gas injection pressure maintenance strategy, reserves are estimated to be approximately 212 million barrels. Reservoir studies have concluded that the aquifer at the base of the reservoir has been relatively inactive. Well recompletions, deepenings, and horizontal wells are used to improve oil recovery. An aggressive program of controlling gas production began in the mid 1980`s by the installation of multiple packers and sleeves. As the gas-oil contact (GOC) has dropped, sand intervals have subsequently been isolated behind packers. A cased hole logging program was recently undertaken to identify possible remaining reserves in the gas cap. 15 refs., 24 figs., 2 tabs.

  2. Structure and performance of carbon aerogel electrodes

    SciTech Connect (OSTI)

    Pekala, R.W.; Mayer, S.T.; Poco, J.F.; Kaschmitter, J.L.

    1994-03-01T23:59:59.000Z

    The chemistry and physics of small clusters of atoms (1--100 nm) has received considerable attention in recent years because these assemblies often have properties between the molecular and bulk solid-state limits. The different properties can be explained in terms of the large fraction of atoms that are at the surface of a cluster as compared to the interior. Although the synthesis and properties of metal and. semiconductor clusters, metallocarbohedrenes, fullerenes, and nanotubes are the subject of extensive investigations, little attention has been paid to cluster-assembled porous materials. This oversight is of particular interest to us since we believe that aerogels are one of the few monolithic materials presently available where the benefits of cluster assembly can be demonstrated. In particular, the unique optical, thermal, acoustic, mechanical, and electrical properties of aerogels are directly related to their nanostructure, which is composed of interconnected particles (3--30 nm) with small interstitial pores (< 50 nm). This structure leads to extremely high surface areas (400--1100 m{sup 2}/g) with a large fraction of the atoms covering the surface of the interconnected particles. As a result of these structural features, carbon aerogels are finding applications as electrodes in supercapacitors with high energy and power densities.

  3. Black Hole Radiation and Volume Statistical Entropy

    E-Print Network [OSTI]

    Mario Rabinowitz

    2005-06-29T23:59:59.000Z

    The simplest possible equation for Hawking radiation, and other black hole radiated power is derived in terms of black hole density. Black hole density also leads to the simplest possible model of a gas of elementary constituents confined inside a gravitational bottle of Schwarzchild radius at tremendous pressure, which yields identically the same functional dependence as the traditional black hole entropy. Variations of Sbh can be obtained which depend on the occupancy of phase space cells. A relation is derived between the constituent momenta and the black hole radius which is similar to the Compton wavelength relation.

  4. Microwave electrode discharge in nitrogen: Structure and characteristics of the electrode region

    SciTech Connect (OSTI)

    Lebedev, Yu. A.; Solomakhin, P. V.; Shakhatov, V. A. [Russian Academy of Sciences, Topchiev Institute of Petrochemical Synthesis (Russian Federation)

    2008-07-15T23:59:59.000Z

    The parameters of the electrode region of an electrode microwave discharge in nitrogen are studied by emission spectroscopy. The radial and axial distributions of the intensities of the bands of the second (N{sub 2}(C{sup 3{Pi}}{sub u} {sup {yields}}B{sup 3{Pi}}{sub g})) and first (N{sub 2}(B{sup 3{Pi}}{sub g} {sup {yields}}A{sup 3{Sigma}}{sub u}{sup +})) positive systems of molecular nitrogen and the first negative system of nitrogen ions (N{sub 2}{sup +} (B{sup 2{Sigma}}{sub u}{sup +} {sup {yields}}X{sup 2{Sigma}}{sub g}{sup +})), the radial profiles of the electric field E and the electron density N{sub e}, and the absolute populations of the vibrational levels v{sub C} = 0-4 of the C{sup 3{Pi}}{sub u} excited state of N{sub 2} and the vibrational level v{sub Bi} = 0 of the B{sup 2{Sigma}}{sub u}{sup +} excited state of a molecular nitrogen ion are determined. The population temperature of the first vibrational level T{sub V} of the ground electronic state X{sup 1{Sigma}}{sub g}{sup +} of N{sub 2} and the excitation temperature T{sub C} of the C{sup 3{Pi}}{sub u} state in the electrode region of the discharge are measured. The radius of the spherical region and the spatially integrated plasma emission spectra are studied as functions of the incident microwave power and gas pressure. A method for determining the electron density and the microwave field strength from the plasma emission characteristics is described in detail.

  5. Interaction between Injection Points during Hydraulic Fracturing

    E-Print Network [OSTI]

    Hals, Kjetil M D

    2012-01-01T23:59:59.000Z

    We present a model of the hydraulic fracturing of heterogeneous poroelastic media. The formalism is an effective continuum model that captures the coupled dynamics of the fluid pressure and the fractured rock matrix and models both the tensile and shear failure of the rock. As an application of the formalism, we study the geomechanical stress interaction between two injection points during hydraulic fracturing (hydrofracking) and how this interaction influences the fracturing process. For injection points that are separated by less than a critical correlation length, we find that the fracturing process around each point is strongly correlated with the position of the neighboring point. The magnitude of the correlation length depends on the degree of heterogeneity of the rock and is on the order of 30-45 m for rocks with low permeabilities. In the strongly correlated regime, we predict a novel effective fracture-force that attracts the fractures toward the neighboring injection point.

  6. Multistaged stokes injected Raman capillary waveguide amplifier

    DOE Patents [OSTI]

    Kurnit, Norman A. (Santa Fe, NM)

    1980-01-01T23:59:59.000Z

    A multistaged Stokes injected Raman capillary waveguide amplifier for providing a high gain Stokes output signal. The amplifier uses a plurality of optically coupled capillary waveguide amplifiers and one or more regenerative amplifiers to increase Stokes gain to a level sufficient for power amplification. Power amplification is provided by a multifocused Raman gain cell or a large diameter capillary waveguide. An external source of CO.sub.2 laser radiation can be injected into each of the capillary waveguide amplifier stages to increase Raman gain. Devices for injecting external sources of CO.sub.2 radiation include: dichroic mirrors, prisms, gratings and Ge Brewster plates. Alternatively, the CO.sub.2 input radiation to the first stage can be coupled and amplified between successive stages.

  7. Meren field water injection project offshore Nigeria

    SciTech Connect (OSTI)

    Adetoba, L.A.

    1984-04-01T23:59:59.000Z

    The Meren Water Injection Project, which is one of the largest in West Africa in terms of injection volume, secondary reserves to be recovered and cost, is located in the Meren field offshore Nigeria. This study presents an updated comprehensive plan to deplete 7 reservoir units in sands that have been producing under solution gas drive and gravity segregation with minimal water influx. The reservoir units contain ca 80% of the original oil-in-place in Meren field. Detailed studies have been undertaken to evaluate the performances of the 7 reservoirs with a view to developing a secondary recovery plan which has been brought into reality. Injection was to start in mid-1982 but was delayed until mid-1983. The effect of the delay and the changing of injector locations on recovery and cost is discussed.

  8. Modeling of Transport in Lithium Ion Battery Electrodes

    E-Print Network [OSTI]

    Martin, Michael

    2012-07-16T23:59:59.000Z

    to model the solid state diffusion behavior in several generated electrode morphologies. Developed computational codes were used to generate targeted structures under prescribed conditions of particle shape, size, and overall morphology. The diffusion...

  9. Fuel cell with Pt/Pd electrocatalyst electrode

    DOE Patents [OSTI]

    Stonehart, Paul (Madison, CT)

    1983-01-01T23:59:59.000Z

    An electrode for use in a phosphoric acid fuel cell comprising a graphitized or partially graphitized carbon support having a platinum/palladium electrocatalyst thereon. Preferably, the platinum/palladium catalyst comprises 20 to 65 weight percent palladium.

  10. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

    1995-08-22T23:59:59.000Z

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  11. Visualization of Charge Distribution in a Lithium Battery Electrode

    E-Print Network [OSTI]

    Liu, Jun

    2010-01-01T23:59:59.000Z

    Charge Distribution in a Lithium Battery Electrode Jun Liu,Modeling of a Lithium-Polymer Battery. J. Power SourcesBehavior of a Lithium-Polymer Battery. J. Power Sources

  12. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, Marca M. (Hayward, CA); Ma, Yanping (Berkeley, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard (Lafayette, CA)

    1995-01-01T23:59:59.000Z

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  13. Electrochemical Modeling of LMR-NMC Materials and Electrodes

    Broader source: Energy.gov (indexed) [DOE]

    Modeling of LMR-NMC Materials and Electrodes Project ID: ES189 Presented by Dennis Dees Voltage Fade Team and CAMP Facility Team 2014 DOE Vehicle Technologies Office Annual Merit...

  14. Modeling of Porous Electrodes in Molten-Salt Systems

    E-Print Network [OSTI]

    Newman, John

    1986-01-01T23:59:59.000Z

    of Porous Electrodes in Molten-Salt Systems^ John Newmanon High-Temperature Molten Salt B a t - teries, Argonneby the modeling of molten-salt cells, including some

  15. Electrochemical Double-Layer Capacitors Using Carbon Nanotube Electrode Structures

    E-Print Network [OSTI]

    Schindall, Joel E.

    The structure and behavior of the electrical double-layer capacitor (EDLC) are described. The use of activated carbon electrodes is discussed and the limitations on voltage and accessible surface area are presented. Metrics ...

  16. Charge Storage in Organic Electrodes for Energy & Electrochemical Applications 

    E-Print Network [OSTI]

    Jeon, Ju Won

    2014-10-15T23:59:59.000Z

    Energy storage has been emerging as an important research topic because of the lack of fossil fuels and growing energy consumption. This thesis focuses on synthesis and characterization of electrode materials such as polyaniline, graphene...

  17. Interfacial Interactions between Implant Electrode and Biological Environment

    E-Print Network [OSTI]

    Chiu, Cheng-Wei 1979-

    2012-11-06T23:59:59.000Z

    at establishing the fundamental knowledge of interfacial interactions between the host biological environment and an implanted electrode. We will identify the dynamic mechanisms of such interfacial interactions. Quantitative analysis of the electrical properties...

  18. Analysis of Impedance Response in Lithium-ion Battery Electrodes

    E-Print Network [OSTI]

    Cho, Seongkoo

    2013-12-04T23:59:59.000Z

    with intercalation particles are designed to describe the influence of microstructure on effective electrical conductivity and the electrochemical impedance. The technique of digital stochastic modeling has been employed for the generation of electrode...

  19. High-Rate, High-Capacity Binder-Free Electrode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrode 4 Why it is better than other technologies Carbon Nanotubes Composite Materials C. Ban, Z. Wu, LChen, Y. Yan and A.C. Dillon Adv. Mat., 2010 Vol22,...

  20. Semitransparent Organic Photovoltaic Cells with Laminated Top Electrode

    E-Print Network [OSTI]

    Cui, Yi

    Semitransparent Organic Photovoltaic Cells with Laminated Top Electrode Jung-Yong Lee, Steve T demonstrate semitransparent small molecular weight organic photovoltaic cells using a laminated silver metal cathode due to differences in optical absorption. KEYWORDS Organic photovoltaics, transparent

  1. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to...

  2. Positive electrode current collector for liquid metal cells

    DOE Patents [OSTI]

    Shimotake, Hiroshi (Hinsdale, IL); Bartholme, Louis G. (Joliet, IL)

    1984-01-01T23:59:59.000Z

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  3. Positive-electrode current collector for liquid-metal cells

    DOE Patents [OSTI]

    Shimotake, H.; Bartholme, L.G.

    1982-09-27T23:59:59.000Z

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  4. Electrode wells for powerline-frequency electrical heating of soils

    DOE Patents [OSTI]

    Buettner, H.M.; Daily, W.D.; Aines, R.D.; Newmark, R.L.; Ramirez, A.L.; Siegel, W.H.

    1999-05-25T23:59:59.000Z

    An electrode well is described for use in powerline-frequency heating of soils for decontamination of the soil. Heating of soils enables the removal of volatile organic compounds from soil when utilized in combination with vacuum extraction. A preferred embodiment of the electrode well utilizes a mild steel pipe as the current-carrying conductor to at least one stainless steel electrode surrounded by a conductive backfill material, preferably graphite or steel shot. A covering is also provided for electrically insulating the current-carrying pipe. One of the electrode wells is utilized with an extraction well which is under subatmospheric pressure to withdraw the volatile material, such as gasoline and trichloroethylene (TCE) as it is heated. 4 figs.

  5. Electrode wells for powerline-frequency electrical heating of soils

    DOE Patents [OSTI]

    Buettner, Harley M. (Livermore, CA); Daily, William D. (Livermore, CA); Aines, Roger D. (Livermore, CA); Newmark, Robin L. (Livermore, CA); Ramirez, Abelardo L. (Pleasanton, CA); Siegel, William H. (Livermore, CA)

    1999-01-01T23:59:59.000Z

    An electrode well for use in powerline-frequency heating of soils for decontamination of the soil. Heating of soils enables the removal of volatile organic compounds from soil when utilized in combination with vacuum extraction. A preferred embodiment of the electrode well utilizes a mild steel pipe as the current-carrying conductor to at least one stainless steel electrode surrounded by a conductive backfill material, preferably graphite or steel shot. A covering is also provided for electrically insulating the current-carrying pipe. One of the electrode wells is utilized with an extraction well which is under subatmospheric pressure to withdraw the volatile material, such as gasoline and trichioroethylene (TCE) as it is heated.

  6. ag111 electrodes investigated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MIT - DSpace Summary: An experiment was done to determine the ability to fabricate carbon aerogel electrodes for use in a phosphoric acid fuel cell (PAFC). It was found that the...

  7. ORIGINAL PAPER Chitosan hydrogel-based electrode binder and electrolyte

    E-Print Network [OSTI]

    Subramanian, Venkat

    to secondary batteries and find use in hybrid energy systems for electric vehicles, heavy-load starting assist and porosity of the electrode materials, usually comprising of activated carbons [3, 4], aerogel or xerogel

  8. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es028lu2011p.pdf More Documents & Publications Screen Electrode...

  9. Modified lithium vanadium oxide electrode materials products and methods

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Kahaian, Arthur J. (Chicago, IL); Visser, Donald R. (Naperville, IL); Dees, Dennis W. (Downers Grove, IL); Benedek, Roy (Western Springs, IL)

    1999-12-21T23:59:59.000Z

    A method of improving certain vanadium oxide formulations is presented. The method concerns fluorine doping formulations having a nominal formula of LiV.sub.3 O.sub.8. Preferred average formulations are provided wherein the average oxidation state of the vanadium is at least 4.6. Herein preferred fluorine doped vanadium oxide materials, electrodes using such materials, and batteries including at least one electrode therein comprising such materials are provided.

  10. Thermo-mechanical Behavior of Lithium-ion Battery Electrodes

    E-Print Network [OSTI]

    An, Kai

    2013-11-25T23:59:59.000Z

    THERMO-MECHANICAL BEHAVIOR OF LITHIUM-ION BATTERY ELECTRODES A Thesis by KAI AN Submitted to the Office of Graduate and Professional Studies of Texas A&M University in partial fulfillment of the requirements for the degree... on the thermo-mechanical behavior of lithium ion battery electrodes. It presents a single particle model of random lattice spring elements coupled with solid phase Li-ion diffusion under active temperature effects. The thermal features are realized by solving...

  11. Metal spring stub and ceramic body electrode assembly

    DOE Patents [OSTI]

    Rolf, R.L.; Sharp, M.L.

    1984-06-26T23:59:59.000Z

    An electrode assembly is disclosed comprising an electrically conductive ceramic electrode body having an opening therein and a metal stub retained in the opening with at least a surface of the stub in intimate contact with a surface of the body and the stub adapted with a spring to flex and prevent damage to the body from expansion of the stub when subjected to a temperature differential. 1 fig.

  12. Mechanics of Electrodes in Lithium-ion Batteries A dissertation presented

    E-Print Network [OSTI]

    #12;Mechanics of Electrodes in Lithium-ion Batteries A dissertation presented by Kejie Zhao, Joost J. Vlassak Kejie Zhao Mechanics of Electrodes in Lithium-ion Batteries Abstract This thesis investigates the mechanical behavior of electrodes in Li-ion batteries. Each electrode in a Li-ion battery

  13. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, Marian (Flossmoor, IL); Kaun, Thomas D. (New Lenox, IL)

    1984-01-01T23:59:59.000Z

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical cell using the electrode. Silicon powder is mixed with powdered electroactive material, such as the lithium-aluminum eutectic, to provide an improved electrode and cell.

  14. Injected Beam Dynamics in SPEAR3

    SciTech Connect (OSTI)

    Corbett, Jeff; /SLAC; Fisher, Alan; /SLAC; Huang, Xiaobiao; /SLAC; Safranek, James; /SLAC; Westerman, Stuart; /SLAC; Cheng, Weixing; /Brookhaven; Mok, Walter; /Unlisted

    2012-06-21T23:59:59.000Z

    For the top-off operation it is important to understand the time evolution of charge injected into the storage ring. The large-amplitude horizontal oscillation quickly filaments and decoheres, and in some cases exhibits non-linear x-y coupling before damping to the stored orbit. Similarly, in the longitudinal dimension, any mismatch in beam arrival time, beam energy or phase-space results in damped, non-linear synchrotron oscillations. In this paper we report on measurements of injection beam dynamics in the transverse and longitudinal planes using turn-by-turn BPMs, a fast-gated, image-intensified CCD camera and a Hamamatsu C5680 streak camera.

  15. Passive injection control for microfluidic systems

    DOE Patents [OSTI]

    Paul, Phillip H.; Arnold, Don W.; Neyer, David W.

    2004-12-21T23:59:59.000Z

    Apparatus for eliminating siphoning, "dead" regions, and fluid concentration gradients in microscale analytical devices. In its most basic embodiment, the present invention affords passive injection control for both electric field-driven and pressure-driven systems by providing additional fluid flow channels or auxiliary channels disposed on either side of a sample separation column. The auxiliary channels are sized such that volumetric fluid flow rate through these channels, while sufficient to move the sample away from the sample injection region in a timely fashion, is less than that through the sample separation channel or chromatograph.

  16. Diesel engine emissions reduction by multiple injections having increasing pressure

    DOE Patents [OSTI]

    Reitz, Rolf D. (Madison, WI); Thiel, Matthew P. (Madison, WI)

    2003-01-01T23:59:59.000Z

    Multiple fuel charges are injected into a diesel engine combustion chamber during a combustion cycle, and each charge after the first has successively greater injection pressure (a higher injection rate) than the prior charge. This injection scheme results in reduced emissions, particularly particulate emissions, and can be implemented by modifying existing injection system hardware. Further enhancements in emissions reduction and engine performance can be obtained by using known measures in conjunction with the invention, such as Exhaust Gas Recirculation (EGR).

  17. Method of making a multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (San Diego, CA); Dispennette, John M. (Oceanside, CA); Blank, Edward (San Diego, CA); Kolb, Alan C. (Rancho Santa Fe, CA)

    2002-09-17T23:59:59.000Z

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator is positioned against the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals.

  18. Black hole mimickers: Regular versus singular behavior

    SciTech Connect (OSTI)

    Lemos, Jose P. S.; Zaslavskii, Oleg B. [Centro Multidisciplinar de Astrofisica, CENTRA, Departamento de Fisica, Instituto Superior Tecnico-IST, Universidade Tecnica de Lisboa-UTL, Avenida Rovisco Pais 1, 1049-001 Lisboa (Portugal); Astronomical Institute of Kharkov, V. N. Karazin National University, 35 Sumskaya Street, Kharkov, 61022 (Ukraine)

    2008-07-15T23:59:59.000Z

    Black hole mimickers are possible alternatives to black holes; they would look observationally almost like black holes but would have no horizon. The properties in the near-horizon region where gravity is strong can be quite different for both types of objects, but at infinity it could be difficult to discern black holes from their mimickers. To disentangle this possible confusion, we examine the near-horizon properties, and their connection with far away asymptotic properties, of some candidates to black mimickers. We study spherically symmetric uncharged or charged but nonextremal objects, as well as spherically symmetric charged extremal objects. Within the uncharged or charged but nonextremal black hole mimickers, we study nonextremal {epsilon}-wormholes on the threshold of the formation of an event horizon, of which a subclass are called black foils, and gravastars. Within the charged extremal black hole mimickers we study extremal {epsilon}-wormholes on the threshold of the formation of an event horizon, quasi-black holes, and wormholes on the basis of quasi-black holes from Bonnor stars. We elucidate whether or not the objects belonging to these two classes remain regular in the near-horizon limit. The requirement of full regularity, i.e., finite curvature and absence of naked behavior, up to an arbitrary neighborhood of the gravitational radius of the object enables one to rule out potential mimickers in most of the cases. A list ranking the best black hole mimickers up to the worst, both nonextremal and extremal, is as follows: wormholes on the basis of extremal black holes or on the basis of quasi-black holes, quasi-black holes, wormholes on the basis of nonextremal black holes (black foils), and gravastars. Since in observational astrophysics it is difficult to find extremal configurations (the best mimickers in the ranking), whereas nonextremal configurations are really bad mimickers, the task of distinguishing black holes from their mimickers seems to be less difficult than one could think of it.

  19. Black Hole Evaporation as a Nonequilibrium Process

    E-Print Network [OSTI]

    Hiromi Saida

    2008-11-11T23:59:59.000Z

    When a black hole evaporates, there arises a net energy flow from the black hole into its outside environment due to the Hawking radiation and the energy accretion onto black hole. Exactly speaking, due to the net energy flow, the black hole evaporation is a nonequilibrium process. To study details of evaporation process, nonequilibrium effects of the net energy flow should be taken into account. In this article we simplify the situation so that the Hawking radiation consists of non-self-interacting massless matter fields and also the energy accretion onto the black hole consists of the same fields. Then we find that the nonequilibrium nature of black hole evaporation is described by a nonequilibrium state of that field, and we formulate nonequilibrium thermodynamics of non-self-interacting massless fields. By applying it to black hole evaporation, followings are shown: (1) Nonequilibrium effects of the energy flow tends to accelerate the black hole evaporation, and, consequently, a specific nonequilibrium phenomenon of semi-classical black hole evaporation is suggested. Furthermore a suggestion about the end state of quantum size black hole evaporation is proposed in the context of information loss paradox. (2) Negative heat capacity of black hole is the physical essence of the generalized second law of black hole thermodynamics, and self-entropy production inside the matter around black hole is not necessary to ensure the generalized second law. Furthermore a lower bound for total entropy at the end of black hole evaporation is given. A relation of the lower bound with the so-called covariant entropy bound conjecture is interesting but left as an open issue.

  20. BSW process of the slowly evaporating charged black hole

    E-Print Network [OSTI]

    Liancheng Wang; Feng He; Xiangyun Fu

    2015-02-09T23:59:59.000Z

    In this paper, we study the BSW process of the slowly evaporating charged black hole. It can be found that the BSW process will also arise near black hole horizon when the evaporation of charged black hole is very slow. But now the background black hole does not have to be an extremal black hole, and it will be approximately an extremal black hole unless it is nearly a huge stationary black hole.

  1. Accounting for Remaining Injected Fracturing Fluid 

    E-Print Network [OSTI]

    Zhang, Yannan

    2013-12-06T23:59:59.000Z

    The technology of multi-stage fracturing of horizontal wells made the development of shale gas reservoirs become greatly successful during the past decades. A large amount of fracturing fluid, usually from 53,000 bbls to 81,400 bbls, is injected...

  2. Accounting for Remaining Injected Fracturing Fluid

    E-Print Network [OSTI]

    Zhang, Yannan

    2013-12-06T23:59:59.000Z

    The technology of multi-stage fracturing of horizontal wells made the development of shale gas reservoirs become greatly successful during the past decades. A large amount of fracturing fluid, usually from 53,000 bbls to 81,400 bbls, is injected...

  3. A study on Raman Injection Laser

    E-Print Network [OSTI]

    Liu, Debin

    2005-11-01T23:59:59.000Z

    The Raman Injection Laser is a new type of laser which is based on triply resonant stimulated Raman scattering between quantum confined states within the active region of a Quantum Cascade Laser that serves as an internal optical pump. The Raman...

  4. Method for uniformly distributing carbon flakes in a positive electrode, the electrode made thereby and compositions. [Patent application

    DOE Patents [OSTI]

    Mrazek, F.C.; Smaga, J.A.; Battles, J.E.

    1981-01-19T23:59:59.000Z

    A positive electrode for a secondary electrochemical cell is described wherein an electrically conductive current collector is in electrical contact with a particulate mixture of gray cast iron and an alkali metal sulfide and an electrolyte including alkali metal halides or alkaline earth metal halides. Also present may be a transition metal sulfide and graphite flakes from the conversion of gray cast iron to iron sulfide. Also disclosed is a method of distributing carbon flakes in a cell wherein there is formed an electrochemical cell of a positive electrode structure of the type described and a suitable electrolyte and a second electrode containing a material capable of alloying with alkali metal ions. The cell is connected to a source of electrical potential to electrochemically convert gray cast iron to an iron sulfide and uniformly to distribute carbon flakes formerly in the gray cast iron throughout the positive electrode while forming an alkali metal alloy in the negative electrode. Also disclosed are compositions useful in preparing positive electrodes.

  5. Down hole periodic seismic generator

    DOE Patents [OSTI]

    Hardee, Harry C. (Albuquerque, NM); Hills, Richard G. (Las Cruces, NM); Striker, Richard P. (Albuquerque, NM)

    1989-01-01T23:59:59.000Z

    A down hole periodic seismic generator system for transmitting variable frequency, predominantly shear-wave vibration into earth strata surrounding a borehole. The system comprises a unitary housing operably connected to a well head by support and electrical cabling and contains clamping apparatus for selectively clamping the housing to the walls of the borehole. The system further comprises a variable speed pneumatic oscillator and a self-contained pneumatic reservoir for producing a frequency-swept seismic output over a discrete frequency range.

  6. Charged spinning black holes as particle accelerators

    SciTech Connect (OSTI)

    Wei Shaowen; Liu Yuxiao; Guo Heng; Fu Chune [Institute of Theoretical Physics, Lanzhou University, Lanzhou 730000 (China)

    2010-11-15T23:59:59.000Z

    It has recently been pointed out that the spinning Kerr black hole with maximal spin could act as a particle collider with arbitrarily high center-of-mass energy. In this paper, we will extend the result to the charged spinning black hole, the Kerr-Newman black hole. The center-of-mass energy of collision for two uncharged particles falling freely from rest at infinity depends not only on the spin a but also on the charge Q of the black hole. We find that an unlimited center-of-mass energy can be approached with the conditions: (1) the collision takes place at the horizon of an extremal black hole; (2) one of the colliding particles has critical angular momentum; (3) the spin a of the extremal black hole satisfies (1/{radical}(3)){<=}(a/M){<=}1, where M is the mass of the Kerr-Newman black hole. The third condition implies that to obtain an arbitrarily high energy, the extremal Kerr-Newman black hole must have a large value of spin, which is a significant difference between the Kerr and Kerr-Newman black holes. Furthermore, we also show that, for a near-extremal black hole, there always exists a finite upper bound for center-of-mass energy, which decreases with the increase of the charge Q.

  7. Quantum Geometry and Black Holes

    E-Print Network [OSTI]

    G., J Fernando Barbero

    2015-01-01T23:59:59.000Z

    We present an overall picture of the advances in the description of black hole physics from the perspective of loop quantum gravity. After an introduction that discusses the main conceptual issues we present some details about the classical and quantum geometry of isolated horizons and their quantum geometry and then use this scheme to give a natural definition of the entropy of black holes. The entropy computations can be neatly expressed in the form of combinatorial problems solvable with the help of methods based on number theory and the use of generating functions. The recovery of the Bekenstein-Hawking law and corrections to it is explained in some detail. After this, due attention is paid to the discussion of semiclassical issues. An important point in this respect is the proper interpretation of the horizon area as the energy that should appear in the statistical-mechanical treatment of the black hole model presented here. The chapter ends with a comparison between the microscopic and semiclassical app...

  8. Method of making a multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (San Diego, CA); Dispennette, John M. (Oceanside, CA); Blank, Edward (San Diego, CA); Kolb, Alan C. (Rancho Santa Fe, CA)

    2000-08-01T23:59:59.000Z

    A method of making a double layer capacitior includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator is positioned against the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two arts of the capacitor case are conductive and function as the capacitor terminals.

  9. Black holes are almost optimal quantum cloners

    E-Print Network [OSTI]

    C. Adami; G. Ver Steeg

    2015-04-15T23:59:59.000Z

    If black holes were able to clone quantum states, a number of paradoxes in black hole physics would disappear. However, the linearity of quantum mechanics forbids exact cloning of quantum states. Here we show that black holes indeed clone incoming quantum states with a fidelity that depends on the black hole's absorption coefficient, without violating the no-cloning theorem because the clones are only approximate. Perfectly reflecting black holes are optimal universal "quantum cloning machines" and operate on the principle of stimulated emission, exactly as their quantum optical counterparts. In the limit of perfect absorption, the fidelity of clones is equal to what can be obtained via quantum state estimation methods. But for any absorption probability less than one, the cloning fidelity is nearly optimal as long as $\\omega/T\\geq10$, a common parameter for modest-sized black holes.

  10. Remarks on Renormalization of Black Hole Entropy

    E-Print Network [OSTI]

    Sang Pyo Kim; Sung Ku Kim; Kwang-Sup Soh; Jae Hyung Yee

    1996-07-07T23:59:59.000Z

    We elaborate the renormalization process of entropy of a nonextremal and an extremal Reissner-Nordstr\\"{o}m black hole by using the Pauli-Villars regularization method, in which the regulator fields obey either the Bose-Einstein or Fermi-Dirac distribution depending on their spin-statistics. The black hole entropy involves only two renormalization constants. We also discuss the entropy and temperature of the extremal black hole.

  11. Hole cleaning requirements with seabed returns

    E-Print Network [OSTI]

    Nordt, David Paul

    1988-01-01T23:59:59.000Z

    of different non-Newtonian fluids 56 INTRODUCTION A drilling fluid is used for removing cuttings from the hole, controlling subsurface pressures, preventing caving-in of the formations, suspension of cuttings, weighting materials, and many other uses... of the hole. The drilling problems related to hole cleaning can occur at low as well as high annular velocities. Cuttings can travel no faster than the fluid in which they are transported; however, they can travel more slowly. Their fall (slip) rate...

  12. Probing the Constituent Structure of Black Holes

    E-Print Network [OSTI]

    Lukas Gruending; Stefan Hofmann; Sophia Müller; Tehseen Rug

    2014-12-12T23:59:59.000Z

    We calculate the cross section for scattering processes between graviton emitters on the near side of a Schwarzschild surface and absorbers on its far side, that is black hole constituents. We show that these scatterings allow to directly extract structural observables such as the momentum distribution of black hole constituents. For this we employ a quantum bound state description originally developed in quantum chromodynamics and recently applied to general relativity that allows to consider black holes in a relativistic Hartree like framework.

  13. Black hole initial data without elliptic equations

    E-Print Network [OSTI]

    István Rácz; Jeffrey Winicour

    2015-02-24T23:59:59.000Z

    We explore whether a new method to solve the constraints of Einstein's equations, which does not involve elliptic equations, can be applied to provide initial data for black holes. We show that this method can be successfully applied to a nonlinear perturbation of a Schwarzschild black hole by establishing the well-posedness of the resulting constraint problem. We discuss its possible generalization to the boosted, spinning multiple black hole problem.

  14. Absorption cross section of RN black hole

    E-Print Network [OSTI]

    Sini R.; V. C. Kuriakose

    2007-08-23T23:59:59.000Z

    The behavior of a charged scalar field in the RN black hole space time is studied using WKB approximation. In the present work it is assumed that matter waves can get reflected from the event horizon. Using this effect, the Hawking temperature and the absorption cross section for RN black hole placed in a charged scalar field are calculated. The absorption cross section $\\sigma _{abs}$ is found to be inversely proportional to square of the Hawking temperature of the black hole.

  15. Black holes with massive graviton hair

    E-Print Network [OSTI]

    Richard Brito; Vitor Cardoso; Paolo Pani

    2013-09-03T23:59:59.000Z

    No-hair theorems exclude the existence of nontrivial scalar and massive vector hair outside four-dimensional, static, asymptotically flat black-hole spacetimes. We show, by explicitly building nonlinear solutions, that black holes can support massive graviton hair in theories of massive gravity. These hairy solutions are, most likely, the generic end state of the recently discovered monopole instability of Schwarzschild black holes in massive graviton theories.

  16. High Temperature Electrolysis using Electrode-Supported Cells

    SciTech Connect (OSTI)

    J. E. O'Brien; C. M. Stoots

    2010-07-01T23:59:59.000Z

    An experimental study is under way to assess the performance of electrode-supported solid-oxide cells operating in the steam electrolysis mode for hydrogen production. The cells currently under study were developed primarily for the fuel cell mode of operation. Results presented in this paper were obtained from single cells, with an active area of 16 cm2 per cell. The electrolysis cells are electrode-supported, with yttria-stabilized zirconia (YSZ) electrolytes (~10 µm thick), nickel-YSZ steam/hydrogen electrodes (~1400 µm thick), and manganite (LSM) air-side electrodes (~90 µm thick). The purpose of the present study was to document and compare the performance and degradation rates of these cells in the fuel cell mode and in the electrolysis mode under various operating conditions. Initial performance was documented through a series of DC potential sweeps and AC impedance spectroscopy measurements. Degradation was determined through long-duration testing, first in the fuel cell mode, then in the electrolysis mode over more than 500 hours of operation. Results indicate accelerated degradation rates in the electrolysis mode compared to the fuel cell mode, possibly due to electrode delamination. The paper also includes details of the single-cell test apparatus developed specifically for these experiments.

  17. Thermoelectric DC conductivities from black hole horizons

    E-Print Network [OSTI]

    Aristomenis Donos; Jerome P. Gauntlett

    2014-10-14T23:59:59.000Z

    An analytic expression for the DC electrical conductivity in terms of black hole horizon data was recently obtained for a class of holographic black holes exhibiting momentum dissipation. We generalise this result to obtain analogous expressions for the DC thermoelectric and thermal conductivities. We illustrate our results using some holographic Q-lattice black holes as well as for some black holes with linear massless axions, in both $D=4$ and $D=5$ bulk spacetime dimensions, which include both spatially isotropic and anisotropic examples. We show that some recently constructed ground states of holographic Q-lattices, which can be either electrically insulating or metallic, are all thermal insulators.

  18. Mineral Test Hole Regulatory Act (Tennessee)

    Broader source: Energy.gov [DOE]

    The Mineral Hole Regulatory Act is applicable to any person (individual, corporation, company, association, joint venture, partnership, receiver, trustee, guardian, executor, administrator,...

  19. Black Holes: from Speculations to Observations

    E-Print Network [OSTI]

    Thomas W. Baumgarte

    2006-04-13T23:59:59.000Z

    This paper provides a brief review of the history of our understanding and knowledge of black holes. Starting with early speculations on ``dark stars'' I discuss the Schwarzschild "black hole" solution to Einstein's field equations and the development of its interpretation from "physically meaningless" to describing the perhaps most exotic and yet "most perfect" macroscopic object in the universe. I describe different astrophysical black hole populations and discuss some of their observational evidence. Finally I close by speculating about future observations of black holes with the new generation of gravitational wave detectors.

  20. Lower Dimensional Black Holes: Inside and Out

    E-Print Network [OSTI]

    R. B. Mann

    1995-01-27T23:59:59.000Z

    I survey the physics of black holes in two and three spacetime dimensions, with special attention given to an understanding of their exterior and interior properties.