National Library of Energy BETA

Sample records for hl wyman ce

  1. Obesity-Blocking Neurons in Drosophila Bader Al-Anzi,1,* Viveca Sapin,1 Christopher Waters,1 Kai Zinn,1,* Robert J. Wyman,2 and Seymour Benzer1

    E-Print Network [OSTI]

    Zinn, Kai

    Waters,1 Kai Zinn,1,* Robert J. Wyman,2 and Seymour Benzer1 1Division of Biology, California Institute

  2. Qualitative and quantitative features of orbits of massive particles and photons moving in Wyman geometry

    E-Print Network [OSTI]

    G. Oliveira-Neto; G. F. Sousa

    2008-01-29

    The Wyman's solution depends on two parameters, the mass $M$ and the scalar charge $\\sigma$. If one fixes $M$ to a positive value, say $M_0$, and let $\\sigma^2$ take values along the real line it describes three different types of spacetimes. For $\\sigma^2 >0$ the spacetimes are naked singularities, for $\\sigma^2 = 0$ one has the Schwarzschild black hole of mass $M_0$ and finally for $-M_0^2 \\leq \\sigma^2 photons moving in the naked singularity and wormhole spacetimes of the Wyman solution. These orbits are the timelike geodesics for massive particles and null geodesics for photons. Combining the four geodesic equations with an additional equation derived from the line element, we obtain an effective potential for the massive particles and a different effective potential for the photons. We investigate all possible types of orbits, for massive particles and photons, by studying the appropriate effective potential. We notice that for certain values of $\\sigma^2 >0$, there is an infinity potential wall that prevents both massive particles and photons ever to reach the naked singularity. We notice, also, that for certain values of $-M_0^2 \\leq \\sigma^2 photons moving from one wormhole asymptotically flat region to the other. We also compute the radial timelike and null geodesics for massive particles and photons, respectively, moving in the naked singularities and wormholes spacetimes.

  3. A multivariate view of the evolution of sexual dimorphism M. J. WYMAN, J. R. STINCHCOMBE & L. ROWE

    E-Print Network [OSTI]

    Sokolowski, Marla

    A multivariate view of the evolution of sexual dimorphism M. J. WYMAN, J. R. STINCHCOMBE & L. ROWE. Widespread dimorphism, despite a shared genome, may be more readily explained by considering the multivariate. By contrast, the multivariate formulation has greater generality and more flexibility. Although the number

  4. HL&P/Du Pont Cogeneration Project 

    E-Print Network [OSTI]

    Vadie, H. H.

    2013-06-06

    The HL&P/Du Pont Cogeneration Project is an arrangement between Houston Lighting & Power Company and E. I. Du Pont de Nemours whereby the utility-owned cogeneration facility supplies a portion of the Du Pont process steam requirements. The facility...

  5. Massachusetts Beryllium Screening Program for Former Workers of Wyman-Gordon, Norton Abrasives, and MIT/Nuclear Metals

    SciTech Connect (OSTI)

    Pepper, L.D.

    2008-05-21

    The overall objective of this project was to provide medical screening to former workers of Wyman-Gordon Company, Norton Abrasives, and MIT/Nuclear Metals (NMI) in order to prevent and minimize the health impact of diseases caused by site related workplace exposures to beryllium. The program was developed in response to a request by the U.S. Department of Energy (DOE) that had been authorized by Congress in Section 3162 of the 1993 Defense Authorization Act, urging the DOE to â??carry out a program for the identification and ongoing evaluation of current and former DOE employees who are subjected to significant health risks during such employment." This program, funded by the DOE, was an amendment to the medical surveillance program for former DOE workers at the Nevada Test Site (NTS). This programâ??s scope included workers who had worked for organizations that provided beryllium products or materials to the DOE as part of their nuclear weapons program. These organizations have been identified as Beryllium Vendors.

  6. A Spectroscopic Study of HL Canis Majoris

    E-Print Network [OSTI]

    H. A. Sheets; John R. Thorstensen

    2005-06-02

    We present optical spectroscopy of the dwarf nova HL Canis Majoris over a span of four years. The observations were made during standstill, outburst, and quiescence. We determine an orbital period of 0.2167867 +/- 0.0000017 days, based on radial velocities determined from H-alpha, H-beta, and He I 5876 emission. We also present equivalent widths of the spectral features in outburst and in quiescence.

  7. First Neutron Spectrometry Measurement at the HL-2A Tokamak

    E-Print Network [OSTI]

    Xi, Yuan; Xufei, Xie; Zhongjing, Chen; Xingyu, Peng; Tieshuan, Fan; Jinxiang, Chen; Xiangqing, Li; Guoliang, Yuan; Jinwei, Yang; Qingwei, Yang

    2013-01-01

    A compact neutron spectrometer based on the liquid scintillator is presented for the neutron energy spectrum measurement at the HL-2A tokamak. The spectrometer has been well characterized and a fast digital pulse shape discrimination software has been developed using the charge comparison method. A digitizer data acquisition system with the maximum frequency of 1 MHz can work under the high count rate environment at HL-2A. Specific radiation shielding and magnetic shielding for the spectrometerhas been designed for the neutron spectrum measurement at the HL-2A Tokamak. For the analysis of the pulse height spectrum, dedicated numerical simulation utilizing NUBEAM combining with GENESIS has been made to obtain the neutron energy spectrum, following which the transportation process from the plasma to the detector has been evaluated with Monte Carlo calculations. The distorted neutron energy spectrum has been folded with response matrix of the liquid scintillation spectrometer, and good consistency has been found...

  8. Prospects of New Physics Searches at the HL-LHC

    E-Print Network [OSTI]

    Metcalfe, Jessica; The ATLAS collaboration

    2015-01-01

    Prospects for New Physics studies at the HL-LHC are shown using an Effective Field Theory Framework. The $W^{\\pm}W^{\\pm}$ channel is used as a case study and a comparison of sensitivity to other VBS and triboson channels is made.

  9. ATLAS strip detector upgrade for the HL-LHC

    E-Print Network [OSTI]

    Liang, Zhijun; The ATLAS collaboration

    2015-01-01

    From 2024, the HL-LHC will provide unprecedented pp luminosities to ATLAS, resulting in an additional integrated luminosity of around 2500 fb?1 over ten years. To withstand the much harsher radiation and occupancy conditions of the HL-LHC necessitates a complete replacement of the present Inner detector. The new all-silicon tracker design is driven by the performance requirements that cannot be met by the present Inner detector. The sensors are of finer granularity than the existing tracker, to meet the challenges of very high pile-up and to be able to reconstruct tracks in the core of multi-TeV jets. In addition, the replacement tracker has to be much more radiation hard and the readout links need to provide much greater bandwidth. Present ideas and solutions for the strip detector and current research and development program will be discussed in this talk.

  10. First Neutron Spectrometry Measurement at the HL-2A Tokamak

    E-Print Network [OSTI]

    Yuan Xi; Zhang Xing; Xie Xufei; Chen Zhongjing; Peng Xingyu; Fan Tieshuan; Chen Jinxiang; Li Xiangqing; Yuan Guoliang; Yang Jinwei; Yang Qingwei

    2013-06-17

    A compact neutron spectrometer based on the liquid scintillator is presented for neutron energy spectrum measurements at the HL-2A tokamak. The spectrometer was well characterized and a fast digital pulse shape discrimination software was developed using the charge comparison method. A digitizer data acquisition system with a maximum frequency of 1 MHz can work under an environment with a high count rate at HL-2A tokamak. Specific radiation and magnetic shielding for the spectrometer were designed for the neutron spectrum measurement at the HL-2A tokamak. For pulse height spectrum analysis, dedicated numerical simulation utilizing NUBEAM combined with GENESIS was performed to obtain the neutron energy spectrum. Subsequently, the transportation process from the plasma to the detector was evaluated with Monte Carlo calculations. The distorted neutron energy spectrum was folded with the response matrix of the liquid scintillation spectrometer, and good consistency was found between the simulated and measured pulse height spectra. This neutron spectrometer based on a digital acquisition system could be well adopted for the investigation of the auxiliary heating behavior and the fast-ion related phenomenon on different tokamak devices.

  11. The Discharge Design of HL-2M with the Tokamak Simulation Code (TSC)

    SciTech Connect (OSTI)

    Yudong Pan, S.C. Jardin, and C. Kes

    2007-10-10

    We present results on the discharge design of the HL-2M tokamak, which is to be an upgrade to the existing HL-2A tokamak. We present simulation results for complete 5-sec. discharges, both double null and lower single null, for both ohmic and auxiliary heated discharges. We also discuss the vertical stability properties of the device. __________________________________________________

  12. Retinoic Acid Induction of Nuclear Envelope-Limited Chromatin Sheets in HL-60

    E-Print Network [OSTI]

    Olins, Ada L.

    vitamin D3, sodium butyrate, and 12-O-tetradecanoylphorbol-13-acetate (TPA) promote monocyticRetinoic Acid Induction of Nuclear Envelope-Limited Chromatin Sheets in HL-60 Ada L. Olins leukemic cell line (HL-60) to 1 M retinoic acid (RA) induces in vitro granulopoie- sis, including

  13. Michelle Wyman | Department of Energy

    Energy Savers [EERE]

    a Clean Economy, and leading International Council Local Environment Initiatives (ICLEI) USA, both of which are nonprofits engaging directly with cities, counties, and states on...

  14. Fall even years Spring odd years CE G7100 Water & Wastewater Quality CE G0800 GIS in WREE

    E-Print Network [OSTI]

    Wolberg, George

    Drinking Water Treatment CE H0800 Applied Hydraulics CE 58300/H8300 Air Pollution and Control CE 56600/H7600 Biological Wastewater Treatment CE 58400/H8400 Solid Waste Management CE 48200 WaterFall even years Spring odd years CE G7100 Water & Wastewater Quality CE G0800 GIS in WREE CE G8100

  15. Table 1. Connection of Criterion 8 CE Outcomes to CE Courses (required, design elective, advanced elective)

    E-Print Network [OSTI]

    Chen, Xinzhong

    ENVE 4391 ENVE 4399 Water, wastewater, air, solid waste Physical and chemical treatment Advanced water Experiments, Interpret Data CE 2101 CE 3103 CE 3105 CE 3121 CE 3171 Construction materials behaviors Material codes and construction practices Design codes and construction practices Regulations, interaction

  16. Optics of ion beams for the neutral beam injection system on HL-2A Tokamak

    SciTech Connect (OSTI)

    Zou, G. Q.; Lei, G. J.; Cao, J. Y.; Duan, X. R.

    2012-07-15

    The ion beam optics for the neutral beam injection system on HL-2A Tokomak is studied by two- dimensional numerical simulation program firstly, where the emitting surface is taken at 100 Debye lengths from the plasma electrode. The mathematical formulation, computation techniques are described. Typical ion orbits, equipotential contours, and emittance diagram are shown. For a fixed geometry electrode, the effect of plasma density, plasma potential and plasma electron temperature on ion beam optics is examined, and the calculation reliability is confirmed by experimental results. In order to improve ion beam optics, the application of a small pre-acceleration voltage ({approx}100 V) between the plasma electrode and the arc discharge anode is reasonable, and a lower plasma electron temperature is desired. The results allow optimization of the ion beam optics in the neutral beam injection system on HL-2A Tokomak and provide guidelines for designing future neutral beam injection system on HL-2M Tokomak.

  17. College of Engineering CE Civil Engineering

    E-Print Network [OSTI]

    MacAdam, Keith

    College of Engineering CE Civil Engineering KEY: # = new course * = course changed = course.Lecture,twohours;laboratory,fourhoursperweek.Prereqorcoreq:MA113orconsentofinstructor. CE 120 INTRODUCTION TO CIVIL ENGINEERING. (1) An introduction to the civil engineering profession and the use of computer hardware and software in CE systems analysis and design

  18. Chemical and Structural Features of Plants That Contribute to Biomass Recalcitrance

    E-Print Network [OSTI]

    DeMartini, Jaclyn Diana

    2011-01-01

    170. Bertaud F, Holmbom B. Chemical Composition of EarlywoodV, Wyman CE. Physical and Chemical Characterizations of CornRapid Analysis of the Chemical Composition of Agricultural

  19. Interactions of Lignin and Hemicellulose and Effects on Biomass Deconstruction

    E-Print Network [OSTI]

    Li, Hongjia

    2012-01-01

    and lignin in biomass. NREL Laboratory Analytical Procedure.2008;NREL/TP-510-42618. DeMartini JD, Wyman CE. Changes inof Lignocellulosic Biomass. NREL Laboratory Analytical

  20. How well can the combination of hlSST and SLR replace GRACE?

    E-Print Network [OSTI]

    Stuttgart, Universität

    30.09.2014 8 #12;Post-processing: old approach · Kalman filtering ­ allows to handle small numbers CSR Gaussian filtering with 750km #12;30.09.2014 19 Amazon Annual signal #12;HYDROLOGY AND HYDRO;30.09.2014 23 GRACE hlSST & SLR Hydro-meteorological validation: ·Q - R 180 W 135 W 90 W 45 W 0 45 E 90 E 135 E

  1. Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Couple Demonstration of (In, Ce)-based Skutterudite Materials for Automotive Energy Recovery Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite Materials for...

  2. Test-Bed of a Real Time Detection System for L/H & H/L Transitions Implemented with the ITMS Platform

    E-Print Network [OSTI]

    Test-Bed of a Real Time Detection System for L/H & H/L Transitions Implemented with the ITMS Platform

  3. Cost objective PLM and CE

    E-Print Network [OSTI]

    Nicolas Perry; Alain Bernard

    2010-11-26

    Concurrent engineering taking into account product life-cycle factors seems to be one of the industrial challenges of the next years. Cost estimation and management are two main strategic tasks that imply the possibility of managing costs at the earliest stages of product development. This is why it is indispensable to let people from economics and from industrial engineering collaborates in order to find the best solution for enterprise progress for economical factors mastering. The objective of this paper is to present who we try to adapt costing methods in a PLM and CE point of view to the new industrial context and configuration in order to give pertinent decision aid for product and process choices. A very important factor is related to cost management problems when developing new products. A case study is introduced that presents how product development actors have referenced elements to product life-cycle costs and impacts, how they have an idea bout economical indicators when taking decisions during the progression of the project of product development.

  4. Palmetto Clean Energy (PaCE) Program

    Broader source: Energy.gov [DOE]

    PaCE funding comes from the customers of participating utilities who voluntarily choose to support the program through an additional charge on their monthly utility bills. Of the $4, $3.50 goes t...

  5. High spatial and temporal resolution charge exchange recombination spectroscopy on the HL-2A tokamak

    SciTech Connect (OSTI)

    Wei, Y. L.; Yu, D. L., E-mail: yudl@swip.ac.cn; Liu, L.; Cao, J. Y.; Sun, A. P.; Ma, Q.; Chen, W. J.; Liu, Yi; Yan, L. W.; Yang, Q. W.; Duan, X. R.; Liu, Yong [Southwestern Institute of Physics, Chengdu 610041 (China); Ida, K. [National Institute for Fusion Science, Toki 509-5292 (Japan); Hellermann, M. von [ITER Diagnostic Team, IO, Route de Vinon sur Verdon, 13115 St Paul lez Durance (France); FOM-Institute for Plasma physics “Rijnhuizen,” Association EURATOM, Trilateral Euregio Cluster, 3430 BE Nieuwegein (Netherlands)

    2014-10-01

    A 32/64-channel charge exchange recombination spectroscopy (CXRS) diagnostic system is developed on the HL-2A tokamak (R = 1.65 m, a = 0.4 m), monitoring plasma ion temperature and toroidal rotation velocity simultaneously. A high throughput spectrometer (F/2.8) and a pitch-controlled fiber bundle enable the temporal resolution of the system up to 400 Hz. The observation geometry and an optimized optic system enable the highest radial resolution up to ~1 cm at the plasma edge. The CXRS system monitors the carbon line emission (C VI, n = 8–7, 529.06 nm) whose Doppler broadening and Doppler shift provide ion temperature and plasma rotation velocity during the neutral beam injection. The composite CX spectral data are analyzed by the atomic data and analysis structure charge exchange spectroscopy fitting (ADAS CXSFIT) code. First experimental results are shown for the case of HL-2A plasmas with sawtooth oscillations, electron cyclotron resonance heating, and edge transport barrier during the high-confinement mode (H-mode)

  6. : www.iky.gr Facebook: https://www.facebook.com/StateScholarshipsFoundation?ref=hl 1. ................................................................................................................................3

    E-Print Network [OSTI]

    Lambropoulou, Sofia

    /: Erasmus+ #12;: www.iky.gr Facebook: https://www.facebook. « : ­ / 2» ...........................................18 #12;: www.iky.gr Facebook: https://www.facebook%) , . . . , . , . #12;: www.iky.gr Facebook: https://www.facebook.com/StateScholarshipsFoundation?ref=hl 4 Erasmus

  7. Measuring Trilinear Higgs Coupling in $WHH$ and $ZHH$ Productions at the HL-LHC

    E-Print Network [OSTI]

    Cao, Qing-Hong; Yan, Bin

    2015-01-01

    Determination of trilinear Higgs coupling ($\\lambda_{HHH}=\\kappa\\lambda_{HHH}^{\\rm SM}$) through Higgs pair productions is a major motivation for the LHC high luminosity phase. We perform a detailed collider simulation to explore the potential of measuring $\\lambda_{HHH}$ in the $VHH$ ($V=W,Z$) production at the HL-LHC. We find that the trilinear Higgs coupling in the SM ($\\lambda_{HHH}^{\\rm SM}$) could be measured at the level of $1.3\\sigma$. Combining with the gluon fusion, vector boson fusion and $t\\bar{t}HH$ channels, $\\lambda_{HHH}^{\\rm SM}$ is expected to be measured at the level of $3.13\\sigma$. If no evidence of Higgs pair productions were observed, the $VHH$ production, together with the gluon fusion channel, would impose a bound of $0.5\\leq \\kappa \\leq 2.2$ at the 95\\% confidence level.

  8. Unusual Outbursting State of a Z Cam-Type Star HL CMa

    E-Print Network [OSTI]

    T. Kato

    2002-03-20

    HL CMa is a Z Cam-type dwarf nova which was discovered as an Einstein X-ray source. In addition to normal outbursts and standstills, we noticed the presence of "the third" outbursting state. During this period, the star showed weak outbursts with a long outburst cycle length. We propose that this phenomenon is caused by a heating on the accretion disk. The presence of strong P Cyg feature in the ultraviolet and the unusual presence of high-excitation optical lines could be interpreted as an emerging signature of strong irradiation field. Since the object is still in this unusual state in 2002 March, we encourage X-ray and spectroscopic observations to detect further signatures of high-energy photons and irradiation.

  9. Research and Development for the ATLAS Forward Calorimetry at the HL-LHC

    E-Print Network [OSTI]

    Cheplakov, Alexander

    2015-01-01

    A total luminosity of 3000/fb is expected at the HL-LHC, which corresponds to total irradiation doses which are more than doubled compared to the original design, taking into account a safety factor of 2 representing our confidence in radiation background simulations. Moreover, the increased instantaneous luminosity will result in a much higher detector occupancy. The ATLAS Forward Calorimeters (FCal) will be affected by these factors. A rich R&D program is ongoing to evaluate the consequences of the LHC modernization and to investigate di_erent scenarios proposed for the Phase-II detector upgrade. This contribution will concentrate on simulation studies of the FCal degradation and on irradiation tests performed at the IBR-2m reactor in Dubna. Results from radiation-tolerant sensors and components of the future read-out and voltage distribution system for various upgrade options of the forward calorimetry will be presented.

  10. L1 track triggers for ATLAS in the HL-LHC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lipeles, E.

    2012-01-01

    The HL-LHC, the planned high luminosity upgrade for the LHC, will increase the collision rate in the ATLAS detector approximately a factor of 5 beyond the luminosity for which the detectors were designed, while also increasing the number of pile-up collisions in each event by a similar factor. This means that the level-1 trigger must achieve a higher rejection factor in a more difficult environment. This presentation discusses the challenges that arise in this environment and strategies being considered by ATLAS to include information from the tracking systems in the level-1 decision. The main challenges involve reducing the data volumemore »exported from the tracking system for which two options are under consideration: a region of interest based system and an intelligent sensor method which filters on hits likely to come from higher transverse momentum tracks.« less

  11. Progress of neutral-beam-aided diagnostics on the HL-2A tokamak

    SciTech Connect (OSTI)

    Yu, D. L., E-mail: yudl@swip.ac.cn; Wei, Y. L.; Liu, L.; Cao, J. Y.; Ma, Q.; Chen, W. J.; Liu, Y.; Yan, L. W.; Yang, Q. W.; Duan, X. R. [Southwestern Institute of Physics, Chengdu 610041 (China)

    2014-11-15

    A 32/64-channel Charge eXchange Recombination Spectroscopy (CXRS) and a 7-channel motional Stark effect (MSE) polarimeter have been developed on the HL-2A tokamak. To extract the maximum time resolution of the system, the incidence fibers of the spectrometer are pitch-controlled; and the double-slit fiber bundle can increase the spatial channels with one charge-coupled device detector. The ion temperature and plasma rotation with time and spatial resolutions up to 5 ms and 1 cm are obtained. Sawtooth oscillation, transition from intermediate phase (I phase) to high confinement mode (H mode) can be clearly observed by the CXRS. The spectrometer can be utilized as the main component of the MSE polarimeter, which can effectively overcome the weak Stark effect. The pitch angles of magnetic field are obtained for 7 spatial points covering 24 cm along major radius with time resolution of 40 ms.

  12. Search for pressure-induced superconductivity in CeFeAsO and CeFePO iron pnictides

    SciTech Connect (OSTI)

    Zocco, D. A. [University of California, San Diego; Baumbach, R. E. [University of California, San Diego; Hamlin, J. J. [University of California, San Diego; Janoschek, M. [University of California, San Diego; Lum, I. K. [University of California, San Diego; McGuire, Michael A [ORNL; Safa-Sefat, Athena [ORNL; Sales, Brian C [ORNL; Jin, Rongying [ORNL; Mandrus, David [ORNL; Jeffries, J. R. [Lawrence Livermore National Laboratory (LLNL); Weir, S. T. [Lawrence Livermore National Laboratory (LLNL); Vohra, Y. K. [University of Alabama, Birmingham; Maple, M. B. [University of California, San Diego

    2011-01-01

    The CeFeAsO and CeFePO iron pnictide compounds were studied via electrical transport measurements under high pressure. In CeFeAsO polycrystals, the magnetic phases involving the Fe and Ce ions coexist for hydrostatically applied pressures up to 15 GPa, and with no signs of pressure-induced superconductivity up to 50 GPa for the less hydrostatic pressure techniques. For the CeFePO single crystals, pressure further stabilizes the Kondo screening of the Ce 4f-electron magnetic moments.

  13. CE 576 Environmental Flows Spring 2012

    E-Print Network [OSTI]

    Rehmann, Chris

    .1. Conservation of mass 1.2. Conservation of momentum 2. Channel flows 2.1. Laminar flow 2.1.1. Flow in a tubeCE 576 Environmental Flows Spring 2012 Course information Instructor: Prof. Chris Rehmann rehmann in environmental fluid mechanics Prerequisites: Elementary fluid mechanics, calculus, differential equations

  14. CE 473/573 Groundwater Learning objectives

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2009 Learning objectives While the goals of the class are quite general for various soil types and explain how sorting affects porosity. Explain how results from a groundwater model. Sketch and explain profiles of piezometric head. 7. Define groundwater divide and compute its properties

  15. CE 473/573 Groundwater Learning objectives

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2011 Learning objectives While the goals of the class are quite general. Identify contemporary issues involving groundwater; explain how solutions that use knowledge of groundwater of piezometric head. Define groundwater divide and compute its properties. Explain how to determine whether

  16. CE 473/573 Groundwater Course information

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2011 Course information Instructor: Prof. Chris Rehmann rehmann of water and contaminants in groundwater systems to solve problems of groundwater resource evaluation and groundwater contamination, to develop thinking skills, to communicate effectively and function on teams

  17. CE 473/573 Groundwater Course information

    E-Print Network [OSTI]

    Rehmann, Chris

    CE 473/573 Groundwater Fall 2009 Course information Instructor: Prof. Chris Rehmann rehmann of water and contaminants in groundwater systems to solve problems of groundwater resource evaluation and groundwater contamination, to develop thinking skills, to communicate effectively and function on teams

  18. CIVIL ENGINEERING CURRICULUM EFFECTIVE FALL 2015 CE 1105 ......................................................... 1 CE 1252 ........................................................ 2

    E-Print Network [OSTI]

    Huang, Haiying

    6/9/2015 CIVIL ENGINEERING CURRICULUM EFFECTIVE FALL 2015 FIRST YEAR CE 1105 ......................................................... 4 MATH 3319 ........................................................ 3 17 17 See "Civil Engineering school foreign language. REQUIRED COURSE TITLES COMMUNICATIONS CIVIL ENGINEERING (ABET Proficiency test

  19. A. G. Walton October 1999 Civil Engineering CE201 Mathematics

    E-Print Network [OSTI]

    Walton, Andrew G

    Civil Engineering CE201 Mathematics Lecturers: Andy Walton, David Denison, Roy Jacobs Timetable. Advanced Engineering Mathematics, E. Kreyszig.

  20. Dr. T.P. Clement CE 3010 class notes

    E-Print Network [OSTI]

    Clement, Prabhakar

    8/15/2011 1 Dr. T.P. Clement CE 3010 class notes Learning Objectives · Motivation · Basic approach value of the definite integral 2 b a dxxf )( Dr. T.P. Clement CE 3010 class notes Analytical (or exact a dxxf )( Dr. T.P. Clement CE 3010 class notes Trapezoidal Rule F(x) #12;8/15/2011 2 Dr. T.P. Clement CE

  1. Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Tian, Wei; Peterson, Spencer G.; Dennis, Kevin W.; Vaknin, David

    2015-02-18

    Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the “1111”-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn2+(S = 5/2) moments pointing along the c axis below a relatively high Néel temperature of TN = 347(1) K. Below TSR = 35 K, two simultaneous transitions occur where the Mn moments reorient from the c axis to the ab plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the ab plane. Another transition tomore »a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) ?B and 0.81(4)?B, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction (J1) is dominant with J2 1/2 in the context of J1 – J2 – Jc model. The spin reorientation transition driven by the coupling between Ce and the transition metal seems to be common to Mn, Fe, and Cr ions, but not to Co and Ni ions in the isostructural oxypnictides. As a result, a schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is presented.« less

  2. GIS IN WATER RESOURCES CE 413/513, 3 credits

    E-Print Network [OSTI]

    Wright, Dawn Jeannine

    GIS IN WATER RESOURCES CE 413/513, 3 credits Prerequisites: Senior or graduate in Engineering or one previous GIS course CE 413 Instructor: Tracy Arras CE 513 Instructor: Wayne Huber Office: Owen 238 Learning Objectives · Demonstrate the basic concepts and operation of GIS for water resources Data models

  3. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12?Ce?(GGAG?Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore »diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  4. Readout Electronics for the ATLAS LAr Calorimeter at HL-LHC

    E-Print Network [OSTI]

    Chen, H; The ATLAS collaboration

    2011-01-01

    The ATLAS Liquid Argon (LAr) calorimeters are high precision, high sensitivity and high granularity detectors designed to provide precision measurements of electrons, photons, jets and missing transverse energy. ATLAS and its LAr calorimeters have been operating and collecting proton-proton collisions at LHC since 2009. The current front-end electronics of the LAr calorimeters need to be upgraded to sustain the higher radiation levels and data rates expected at the upgraded high luminosity LHC machine (HL-LHC), which will have 5 times more luminosity than the LHC in its ultimate configuration. The complexity of the present electronics and the obsolescence of some of components of which it is made, will not allow a partial replacement of the system. A completely new readout architecture scheme is under study and many components are being developed in various R&D programs of the LAr Calorimeter Group. The new front-end readout electronics will send data continuously at each bunch crossing through high speed...

  5. CeCap LLP | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County,Camilla,Thermal Gradient Holes Jump to:MiddleCayucos, California:CeCap

  6. Linac Coherent Light SourCe

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPA PublicLED ADOPTIONtoLighting SystemLinac Coherent Light SourCe

  7. Interactions of Lignin and Hemicellulose and Effects on Biomass Deconstruction

    E-Print Network [OSTI]

    Li, Hongjia

    2012-01-01

    the way. Appl Biochem Biotech. 2001 Spr;91-3:5-21. Wyman CE.hydrolysis. Appl Biochem Biotech. 2006 Mar;130(1-3):427-35.aurantiacus. Appl Biochem Biotech. 2010 Oct;162(4):1195-205.

  8. Informations et rservations : ce.pv-holidays.com

    E-Print Network [OSTI]

    Arleo, Angelo

    Informations et réservations : ce.pv-holidays.com * Offre valable pour tout séjour de 7 nuits détails sur ce.pv-holidays.com. Offre valable sur l'hébergement seul (hors frais de dossier, prestations cumulable avec votre remise partenaire, toute offre promotionnelle ou réductions. PV-CPDistribution, Société

  9. Dr. T.P. Clement CE 3010 class notes

    E-Print Network [OSTI]

    Clement, Prabhakar

    1 Dr. T.P. Clement CE 3010 class notes Quotes · Genius is 1 percent inspiration and 99 percent in little things. Excellence is not an exception, it is a prevailing attitude Colin Powell 1 Dr. T.P · Combining conditions · Loops · Examples 2 Dr. T.P. Clement CE 3010 class notes Program to Find Real Roots

  10. Approved Module Information for CE2110, 2014/5 Module Title/Name: Process Laboratory Module Code: CE2110

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE2110, 2014/5 Module Title/Name: Process Laboratory Module Code: CE2110 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name John Brammer Email Address brammejg

  11. Approved Module Information for CE4018, 2014/5 Module Title/Name: Advanced Particle Processing Module Code: CE4018

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE4018, 2014/5 Module Title/Name: Advanced Particle Processing Module Code: CE4018 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Mark Leaper Email Address m

  12. Approved Module Information for CE3013, 2014/5 Module Title/Name: Particle Processing Module Code: CE3013

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE3013, 2014/5 Module Title/Name: Particle Processing Module Code: CE3013 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Mark Leaper Email Address m

  13. Approved Module Information for CE3102, 2014/5 Module Title/Name: Reaction Engineering Module Code: CE3102

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE3102, 2014/5 Module Title/Name: Reaction Engineering Module Code: CE3102 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Feroz Kabir Email Address kabirf

  14. Approved Module Information for CE3112, 2014/5 Module Title/Name: Nanomaterials Module Code: CE3112

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE3112, 2014/5 Module Title/Name: Nanomaterials Module Code: CE3112 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Qingchun Yuan Email Address q.yuan@aston.ac.uk Telephone

  15. Approved Module Information for CE1002, 2014/5 Module Title/Name: Design and Build Module Code: CE1002

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE1002, 2014/5 Module Title/Name: Design and Build Module Code: CE1002 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Paul Andrew Tack Email Address tackpa

  16. Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature Waste Heat Recovery Thermoelectric and structural properties of n-type (In, Ce) filled skutterudites including power...

  17. Development of the scintillator-based probe for fast-ion losses in the HL-2A tokamak

    SciTech Connect (OSTI)

    Zhang, Y. P. Liu, Yi; Yuan, G. L.; Song, X. Y.; Yang, J. W.; Li, X.; Chen, W.; Li, Y.; Yan, L. W.; Song, X. M.; Yang, Q. W.; Duan, X. R.; Luo, X. B.; Liu, Y. Q.; Hua, Y.; Isobe, M.

    2014-05-15

    A new scintillator-based lost fast-ion probe (SLIP) has been developed and operated in the HL-2A tokamak [L. W. Yan, X. R. Duan, X. T. Ding, J. Q. Dong, Q. W. Yang, Yi Liu, X. L. Zou, D. Q. Liu, W. M. Xuan, L. Y. Chen, J. Rao, X. M. Song, Y. Huang, W. C. Mao, Q. M. Wang, Q. Li, Z. Cao, B. Li, J. Y. Cao, G. J. Lei, J. H. Zhang, X. D. Li, W. Chen, J. Chen, C. H. Cui, Z. Y. Cui, Z. C. Deng, Y. B. Dong, B. B. Feng, Q. D. Gao, X. Y. Han, W. Y. Hong, M. Huang, X. Q. Ji, Z. H. Kang, D. F. Kong, T. Lan, G. S. Li, H. J. Li, Qing Li, W. Li, Y. G. Li, A. D. Liu, Z. T. Liu, C. W. Luo, X. H. Mao, Y. D. Pan, J. F. Peng, Z. B. Shi, S. D. Song, X. Y. Song, H. J. Sun, A. K. Wang, M. X. Wang, Y. Q. Wang, W. W. Xiao, Y. F. Xie, L. H. Yao, D. L. Yu, B. S. Yuan, K. J. Zhao, G. W. Zhong, J. Zhou, J. C. Yan, C. X. Yu, C. H. Pan, Y. Liu, and the HL-2A Team , Nucl. Fusion 51, 094016 (2011)] to measure the losses of neutral beam ions. The design of the probe is based on the concept of the ?-particle detectors on Tokamak Fusion Test Reactor (TFTR) using scintillator plates. The probe is capable of traveling across an equatorial plane port and sweeping the aperture angle rotationally with respect to the axis of the probe shaft by two step motors, in order to optimize the radial position and the collimator angle. The energy and the pitch angle of the lost fast ions can be simultaneously measured if the two-dimensional image of scintillation light intensity due to the impact of the lost fast ions is detected. Measurements of the fast-ion losses using the probe have been performed during HL-2A neutral beam injection discharges. The clear experimental evidence of enhanced losses of beam ions during disruptions has been obtained by means of the SLIP system. A detailed description of the probe system and the first experimental results are reported.

  18. E Effi i t T h l f th F t an Energy Efficient Technology for the Future Ch i i B hlChristian Bahl

    E-Print Network [OSTI]

    Christian Bahl Fuel Cells and Solid State Chemistry Division Fuel Cells and Solid State Chemistry Division Risø E Effi i t T h l f th F t an Energy Efficient Technology for the Future Ch i i B hl is ensured. #12;#12;Challengesg Promising technology... Hi h ffi iHigh efficiency. No CFC or HCFC gasses. C

  19. Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Doty, F. Patrick; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Josh; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  20. Irradiation Tests and Expected Performance of Readout Electronics of the ATLAS Hadronic Endcap Calorimeter for the HL-LHC

    E-Print Network [OSTI]

    Martin Nagel

    2013-09-03

    The readout electronics of the ATLAS Hadronic Endcap Calorimeter (HEC) will have to withstand an about 3-5 times larger radiation environment at the future high-luminosity LHC (HLLHC) compared to their design values. The preamplifier and summing boards (PSBs), which are equipped with GaAs ASICs and comprise the heart of the readout electronics, were irradiated with neutrons and protons with fluences surpassing several times ten years of operation of the HL-LHC. Neutron tests were performed at the NPI in Rez, Czech Republic, where a 36 MeV proton beam was directed on a thick heavy water target to produce neutrons. The proton irradiation was done with 200 MeV protons at the PROSCAN area of the Proton Irradiation Facility at the PSI in Villigen, Switzerland. In-situ measurements of S-parameters in both tests allow the evaluation of frequency dependent performance parameters, like gain and input impedance, as a function of fluence. The linearity of the ASIC response was measured directly in the neutron tests with a triangular input pulse of varying amplitude. The results obtained allow an estimation of the expected performance degradation of the HEC. For a possible replacement of the PSB chips, alternative technologies were investigated and exposed to similar neutron radiation levels. In particular, IHP 250 nm Si CMOS technology has turned out to show good performance and match the specifications required. The performance measurements of the current PSB devices, the expected performance degradations under HL-LHC conditions, and results from alternative technologies will be presented.

  1. Effects of CeO2 Support Facets on VOx/CeO2 Catalysts in Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Gao, Feng; Kovarik, Libor; Peden, Charles HF; Wang, Yong

    2014-05-13

    CeO2 supports with dominating facets, i.e., low index (100), (110) and (111) facets, are prepared. The facet effects on the structure and catalytic performance of supported vanadium oxide catalysts are investigated using oxidative dehydrogenation of methanol as a model reaction. In the presence of mixed facets, Infrared and Raman characterizations demonstrate that surface vanadia species preferentially deposit on CeO2 (100) facets, presumably because of its higher surface energy. At the same surface vanadium densities, VOx species on (100) facets show better dispersion, followed by (110) and (111) facets. The VOx species on CeO2 nanorods with (110) and (100) facets display higher activity and lower apparent activation energies compared to that on CeO2 nanopolyhedras with dominating (111) facets and CeO2 nanocubes with dominating (100) facets. The higher activity for VOx/CeO2(110) might be related to the more abundant oxygen vacancies present on the (110) facets, evidenced from Raman spectroscopic measurements.

  2. Homoleptic Ce(III) and Ce(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State

    SciTech Connect (OSTI)

    Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A.; Piro, Nicholas A.; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

    2014-06-25

    Electrochemical experiments performed on the complex Ce-IV[2-((BuNO)-Bu-t)py](4), where [2-((BuNO)-Bu-t)py](-) = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [(Bu4N)-Bu-n](2)[Ce(NO3)(6)] in acetonitrile and a 2.95 V stabilization compared to the standard potential for the ion under aqueous conditions. Density functional theory calculations suggest that this preference for the higher oxidation state is a result of the tetrakis(nitroxide) ligand framework at the Ce cation, which allows for effective electron donation into, and partial covalent overlap with, vacant 4f orbitals with delta symmetry. The results speak to the behavior of CeO2 and related solid solutions in oxygen uptake and transport applications, in particular an inherent local character of bonding that stabilizes the 4+ oxidation state. The results indicate a cerium(IV) complex that has been stabilized to an unprecedented degree through tuning of its ligand-field environment.

  3. Thin n-in-p planar pixel sensors and active edge sensors for the ATLAS upgrade at HL-LHC

    E-Print Network [OSTI]

    S. Terzo; A. Macchiolo; R. Nisius; B. Paschen

    2014-11-20

    Silicon pixel modules employing n-in-p planar sensors with an active thickness of 200 $\\mu$m, produced at CiS, and 100-200 $\\mu$m thin active/slim edge sensor devices, produced at VTT in Finland have been interconnected to ATLAS FE-I3 and FE-I4 read-out chips. The thin sensors are designed for high energy physics collider experiments to ensure radiation hardness at high fluences. Moreover, the active edge technology of the VTT production maximizes the sensitive region of the assembly, allowing for a reduced overlap of the modules in the pixel layer close to the beam pipe. The CiS production includes also four chip sensors according to the module geometry planned for the outer layers of the upgraded ATLAS pixel detector to be operated at the HL-LHC. The modules have been characterized using radioactive sources in the laboratory and with high precision measurements at beam tests to investigate the hit efficiency and charge collection properties at different bias voltages and particle incidence angles. The performance of the different sensor thicknesses and edge designs are compared before and after irradiation up to a fluence of $1.4\\times10^{16}n_{eq}/cm^{2}$.

  4. Metabolic profiling using HPLC allows classification of drugs according to their mechanisms of action in HL-1 cardiomyocytes

    SciTech Connect (OSTI)

    Strigun, Alexander; Wahrheit, Judith; Beckers, Simone; Heinzle, Elmar; Noor, Fozia, E-mail: fozia.noor@mx.uni-saarland.de

    2011-04-15

    Along with hepatotoxicity, cardiotoxic side effects remain one of the major reasons for drug withdrawals and boxed warnings. Prediction methods for cardiotoxicity are insufficient. High content screening comprising of not only electrophysiological characterization but also cellular molecular alterations are expected to improve the cardiotoxicity prediction potential. Metabolomic approaches recently have become an important focus of research in pharmacological testing and prediction. In this study, the culture medium supernatants from HL-1 cardiomyocytes after exposure to drugs from different classes (analgesics, antimetabolites, anthracyclines, antihistamines, channel blockers) were analyzed to determine specific metabolic footprints in response to the tested drugs. Since most drugs influence energy metabolism in cardiac cells, the metabolite 'sub-profile' consisting of glucose, lactate, pyruvate and amino acids was considered. These metabolites were quantified using HPLC in samples after exposure of cells to test compounds of the respective drug groups. The studied drug concentrations were selected from concentration response curves for each drug. The metabolite profiles were randomly split into training/validation and test set; and then analysed using multivariate statistics (principal component analysis and discriminant analysis). Discriminant analysis resulted in clustering of drugs according to their modes of action. After cross validation and cross model validation, the underlying training data were able to predict 50%-80% of conditions to the correct classification group. We show that HPLC based characterisation of known cell culture medium components is sufficient to predict a drug's potential classification according to its mode of action.

  5. The San Francisco Consortium CT Host, CE Home

    E-Print Network [OSTI]

    Ovchinnikov, Sergei

    The San Francisco Consortium CT Host, CE Home me l r Student: Complete Sections 1 through 5. Print Campus Campus California College of Podiatric Medicine City College of San Francisco Cogswell College Golden Gate University Tuition Required Hastings College of the Law San Francisco State University

  6. CE 4990 -Construction Scheduling Integrating Cost and Schedule

    E-Print Network [OSTI]

    Mukherjee, Amlan

    CE 4990 - Construction Scheduling Integrating Cost and Schedule March 16, 2012 Definitions The goal) = BCWP/BCWS · Cost Variance (CV) = BCWP - ACWP · Cost Performance Index (CPI) = BCWP/ACWP · EAC = ACWP is to develop integrated metrics for measuring cost and schedule performance. This note provides guidelines

  7. Improved performance of QCD code on ALiCE

    E-Print Network [OSTI]

    Sroczynski, Z

    2003-01-01

    We present results for the performance of QCD code on ALiCE, the Alpha-Linux Cluster Engine at Wuppertal. We describe the techniques employed to optimise the code, including the metaprogramming of assembler kernels, the effects of data layout and an investigation into the overheads incurred by the communication.

  8. EnTRAnCE AWARDS AGBIO Renewable Entrance

    E-Print Network [OSTI]

    Peak, Derek

    EnTRAnCE AWARDS AGBIO Renewable Entrance Scholarships Benjamin Dietrich, Moosomin Logan Pizzey Megan Hodges, Dalmeny COnTInUInG STUDEnT AWARDS AGBIO Renewable Entrance Scholarships, Second Year Tracy Smith, Radisson AGBIO Renewable Entrance Scholarships, Third Year Melanie Hawrysh, Borden Kathryn Stolle

  9. Progressive Multiple Biosequence Alignments on the ALiCE Grid

    E-Print Network [OSTI]

    Teo, Yong-Meng

    to high-end computational capabilities [10]. The pioneer grid efforts spun off as experimental attemptsProgressive Multiple Biosequence Alignments on the ALiCE Grid Yong-Meng TEO1,2 , Yew-Kwong NG1 problem that has semi-regular computational pattern. Grid-enabled PMSA is implemented using our Java

  10. In this Issue CeBiTec Symposium: Molecular Biotechnology

    E-Print Network [OSTI]

    Moeller, Ralf

    of tools and techniques for transcriptome sequencing 3rd CeBiTec Students Academy Synthetic Biology and Bielefeld presented insights into cutting edge developments of Molecular Biotechnology. This regional focus compounds to biological halogenation, enzyme coatings and chemical protein labelling. One session

  11. The suburban villa (munya) and court culture in Umayyad Cordoba (756-976 CE)

    E-Print Network [OSTI]

    Anderson, Glaire D

    2005-01-01

    As the capital of the Umayyad dynasty (r. 756 CE-1031 CE), the city of Cordoba developed into one of the most renowned urban centers of the western Mediterranean. The Great Mosque of Cordoba is the outstanding testament ...

  12. Neutron scattering of CeNi at the SNS-ORNL: A preliminary report

    SciTech Connect (OSTI)

    Mirmelstein, A. [Russian Federal Nuclear Center VNIITF, Snezhinsk, Russia; Podlesnyak, Andrey A [ORNL; Kolesnikov, Alexander I [ORNL; Saporov, B. [Oak Ridge National Laboratory (ORNL); Sefat, A.S. [Oak Ridge National Laboratory (ORNL); Tobin, J. G. [Lawrence Livermore National Laboratory (LLNL)

    2014-01-01

    This is a preliminary report of a neutron scattering experiment used to investigate 4f electron behavior in Ce.

  13. CO Oxidation at the Interface between Doped CeO2 and Supported Au Nanoclusters

    E-Print Network [OSTI]

    Henkelman, Graeme

    nanoclusters (NCs) supported on either CeO2 or doped (X-Ce)O2 (X = Au, Pt, Pd, Ti, Ru, Zr) show that dopingCO Oxidation at the Interface between Doped CeO2 and Supported Au Nanoclusters Hyun You Kim, we study the e ect of doping on CO oxidation catalyzed by CeO2-supported Au13 NCs and, especially, CO

  14. Module Information for CE3104, 2015/6 -APPROVED Module Title/Name: Process & Pollution Control Module Code: CE3104

    E-Print Network [OSTI]

    Rebollo-Neira, Laura

    - characteristics, variation with source, treatment principles, discharge to sewers and watercourses - Air PollutionModule Information for CE3104, 2015/6 - APPROVED Module Title/Name: Process & Pollution Control on piping and instrumentation diagrams (P&ID). Indicative Module Content: Pollution Prevention and Control

  15. Comparative studies of low-temperature watergas shift reaction over Pt=CeO2, Au=CeO2,

    E-Print Network [OSTI]

    Gulari, Erdogan

    , has shown that ceria affects in a number of catalytic reactions. Cerium oxide or Ceria (CeO2) may attention re- cently because of their catalytic activity in low temperature CO oxidation, catalytic; accepted 13 March 2003 Abstract We studied catalytic low-temperature water­gas shift (WGS) reaction over

  16. Approved Module Information for CE4503, 2014/5 Module Title/Name: Advanced Process Design Module Code: CE4503

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Code: CE4503 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module available: BEng/MEng Chemical Engineering. Available to Exchange Students? Not Specified Module Dependancies. The Design Problem is intended to test the students ability to apply the principles of Chemical Engineering

  17. Approved Module Information for CE2105, 2014/5 Module Title/Name: Process Simulation Module Code: CE2105

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    : CE2105 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module processes with solids * Coal drying * Coal combustion Module Delivery Methods of Delivery & Learning Hours weighting (including approaches to formative assessment as well as summative): Assessment Type Category

  18. Approved Module Information for CE3104, 2014/5 Module Title/Name: Process & Pollution Control Module Code: CE3104

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    , treatment principles, discharge to sewers and watercourses * Air Pollution - effects of pollutants, typesApproved Module Information for CE3104, 2014/5 Module Title/Name: Process & Pollution Control - Understand how a chemical process is controlled safely and efficiently Pollution Control #12;* The impact

  19. Short communication Chemically abrupt interface between Ce oxide and Fe films

    E-Print Network [OSTI]

    Kim, Sehun

    of an Fe film followed by deposition of Ce metal. Once a Ce oxide layer is formed on top of Fe, it acts.90.+f; 74.25.jb; 79.60 Ài; 79.60.Dp Keywords: MTJ; Ce oxide layer; XPS Magnetic tunneling junctions (MTJ of the oxide layer, resulting in decreased tunneling magneto- resistance and fluctuations in the local

  20. CliniCal anesthesia ConferenCe 2015

    E-Print Network [OSTI]

    Thompson, Michael

    Can-am CliniCal anesthesia ConferenCe 2015 T H I r T Y - T H I r D a n n u a l Conference 2015 Please FaX, Mail or e-Mail: CMe aDMinistRatOR Continuing Health Sciences education mcmaster conferences: yes no www.twitter.com/mcmaster_chse http://ca.linkedin.com/pub/mcmaster-continuing- health

  1. PQL: Order (2013-CE-27001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrder 422.1, CONDUCT P - . . - - 4PORTSFUTUREOrder (2013-CE-27001)

  2. LG: Order (2015-CE-14022) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICE INDUSTRIALU.S. DepartmentJeanKeyLANLLG: Order (2015-CE-14022) LG: Order

  3. Haier: Order (2011-CE-2104) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing Programs |ReferencePowerHaier: Order (2011-CE-2104) Haier:

  4. Prospects on the search for invisible Higgs decays in the ZH channel at the LHC and HL-LHC: A Snowmass White Paper

    E-Print Network [OSTI]

    Hideki Okawa; Josh Kunkle; Elliot Lipeles

    2014-12-16

    We show prospects on a search for invisible decays of a Higgs boson at the Large Hadron Collider (LHC) and High Luminosity LHC (HL-LHC). This search is performed on a Higgs boson produced in association with a Z boson. We expect that the branching ratio of 17-22% (6-14%) could be excluded at 95% confidence level with 300 fb^{-1} (3000 fb^{-1}) of data at sqrt(s)=14 TeV. The range indicates different assumptions on the control of systematic uncertainties. Interpretations with Higgs-portal dark matter models are also considered.

  5. Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102 School: Engineering and Applied Science Module Type: Standard Module New Module chemistry. Part 2: Introduction to Laboratory Skills To enable the student to develop good practical skills

  6. Approved Module Information for CE4014, 2014/5 Module Title/Name: Advanced Reaction Engineering II Module Code: CE4014

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE4014, 2014/5 Module Title/Name: Advanced Reaction Engineering II Module Code: CE4014 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Feroz Kabir Email Address kabirf

  7. California Ethanol Power CE P | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick,Calendar Home > CommunityHelp toPower CE

  8. Goodman Manufacturing: Order (2012-CE-1509) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,Executive CompensationEnergyGet Current:5 Department of2-CE-1509) Goodman

  9. The influence of nano-architectured CeOx supports in RhPd/CeO? for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO? cubes and CeO? rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO?-cubes > RhPd/CeO? -rods > RhPd/CeO?- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO?-cubes and RhPd/CeO? -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more »oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  10. Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization

    DOE Patents [OSTI]

    Jankowiak, Ryszard J. (Ames, IA); Small, Gerald J. (Ames, IA); Shields, Peter A. (Reading, MA)

    1999-04-27

    Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes.

  11. Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter

    SciTech Connect (OSTI)

    Davidson, Stephen; Sun, Junming; Wang, Yong

    2013-12-02

    A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

  12. Neutron Scattering of CeNi at the Spallation Neutron Source at...

    Office of Scientific and Technical Information (OSTI)

    Spallation Neutron Source at Oak Ridge National Laboratory: A Preliminary Report Citation Details In-Document Search Title: Neutron Scattering of CeNi at the Spallation Neutron...

  13. Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization

    DOE Patents [OSTI]

    Jankowiak, R.J.; Small, G.J.; Shields, P.A.

    1999-04-27

    Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes. 21 figs.

  14. EST-CE QU'ON VOlT ATRAVERS UN MICROSCOPE? '

    E-Print Network [OSTI]

    Aubin, David

    'aimable autonsatJon de1auteur etde Blackwell Publishing. EST-CE QU'ON VOlT ATRAVERS UN MICROSCOPE? 239 Les

  15. Thermal Variation of Ce Valence in Mixed Valence–Kondo Lattice Systems CeT2(Si1-xGex)2 with T= Mn and Ni

    SciTech Connect (OSTI)

    Liang,G.; Croft, M.

    2008-01-01

    The results on the thermal variation of Ce L3-valence in CeT2(Si1-xGex)2 series with 0{le}x{le}1 and T=Mn and Ni are reported. It is observed that for both series, the Ce valence increases with decreasing temperature and has little thermal variation for samples in the nearly trivalent regime. The magnitude of this thermal variation in the T=Mn series is much greater than in the T=Ni series. The results are explained by the degenerate Anderson model and correlated with the specific heat data.

  16. Magellan observations of Quasars with Radio and X-Ray Jets Jonathan Gelbord, H.L. Marshall, B.P. Miller (MIT), D.A. Schwartz (SAO), D.M. Worrall, M. Birkinshaw (SAO

    E-Print Network [OSTI]

    Gelbord, Jonathan

    Magellan observations of Quasars with Radio and X-Ray Jets Jonathan Gelbord, H.L. Marshall, B of kiloparsec jet structures in flat-spectrum radio quasars (FSRQs). In the first phase of our study, we-arcsecond radio maps. We have discovered jet X-ray flux in 13 of these targets. In general the X-ray morphology

  17. TraCE -TRANSPORTATION CENTER EPFL 09 Sep 2009 sonia.lavadinho@epfl.ch STRC Ascona

    E-Print Network [OSTI]

    Bierlaire, Michel

    & capillary walking (TUBE & WALK LONDON) #12;TraCE - TRANSPORTATION CENTER EPFL 09 Sep 2009 soniaTraCE - TRANSPORTATION CENTER EPFL 09 Sep 2009 sonia.lavadinho@epfl.ch STRC Ascona 11 Potentials for combining walking and public transport at the agglomeration scale THE MULTIMODAL WALKER #12;Tra

  18. Approved Module Information for CE2106, 2014/5 Module Title/Name: Reaction Kinetics & Equilibrium

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CE2106, 2014/5 Module Title/Name: Reaction Kinetics & Equilibrium Thermodynamics Module Code: CE2106 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Mark Leaper Email Address

  19. CertifiCAtion of performAnCe indiCAtors ........ 110 Curtin's institutionAl

    E-Print Network [OSTI]

    Mucina, Ladislav

    and performance enhance capacity and financial sustainability l total Research income ($) Ranking Strengthen research capability and performance enhance capacity and financial sustainability m CooperaCertifiCAtion of performAnCe indiCAtors ........ 110 Curtin's institutionAl performAnCe indi

  20. Preparation and properties of ce-doped TiO{sub 2} photocatalyst

    SciTech Connect (OSTI)

    Yan, Ningning; Zhu, Zhongqi; Zhang, Jin [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)] [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China); Zhao, Zongyan [School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093 (China)] [School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093 (China); Liu, Qingju, E-mail: qjliu@ynu.edu.cn [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)] [Yunnan Key Laboratory of Nanomaterials and Technology, Yunnan University, Kunming 650091 (China)

    2012-08-15

    Highlights: ? The cerium ion doped TiO{sub 2} (Ce-TiO{sub 2}) powders were prepared and characterized. ? The spectrum absorption region of Ce-TiO{sub 2} is red-shifted to visible light. ? The recombination of photo-generated electron-hole pairs of Ce-TiO{sub 2} is inhibited. ? The photocatalytic activity was effected by Ce ion content and greatly improved. -- Abstract: TiO{sub 2} nanoparticles doped with different content of Ce ion were prepared by sol–gel method. The samples were characterized by XRD, XPS, TEM, UV–Vis, and PL, the photocatalytic activity was evaluated by photocatalytic degradation of methylene blue (MB) under the irradiation of fluorescent lamp. The results indicate that Ce ion is incorporated into the lattice of TiO{sub 2}, which can restrain the increase of grain size, broaden the absorption region to visible light, and inhibit the recombination of the photo-generated electron and hole pairs. Moreover, the photocatalytic activity of Ce-TiO{sub 2} in MB degradation is evidently enhanced. The MB degradation rate of the sample with Ce:Ti = 0.33% (molar ratio) in 8 h is 90.03%, which is much higher than that of P25 (68.19%).

  1. Ternary ceramic alloys of Zr-Ce-Hf oxides

    DOE Patents [OSTI]

    Becher, P.F.; Funkenbusch, E.F.

    1990-11-20

    A ternary ceramic alloy is described which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce[sub x]Hf[sub y]Zr[sub 1[minus]x[minus]y]O[sub 2], is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites. 1 fig.

  2. Ternary ceramic alloys of ZR-CE-HF oxides

    DOE Patents [OSTI]

    Becher, Paul F. (Oak Ridge, TN); Funkenbusch, Eric F. (White Bear Lake, MN)

    1990-01-01

    A ternary ceramic alloy which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce.sub.x Hf.sub.y Zn.sub.1-x-y O.sub.2, is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites.

  3. Inelastic magnetic neutron scattering in CePd{sub 3}.

    SciTech Connect (OSTI)

    Lawrence, J. M.; Fanelli, V. R.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Christianson, A. D.; Univ. of California at Irvine; LANL; ORNL

    2008-01-01

    We have performed time-of-flight neutron scattering measurements on a single crystal of the intermediate valence compound CePd{sub 3}. At 10 K, a Kondo-esque inelastic magnetic scattering peak occurs near {Delta}E = 60 meV with maximum intensity for momentum transfer Q near the (1/2, 1/2, 0) zone boundary. Spectral weight is transferred to lower energy as Q varies until at zone center the intensity at 60 meV is considerably weaker. These results are in qualitative accord with predictions of the Anderson lattice. The Q-dependence may resolve an older controversy concerning the low-temperature scattering. We discuss the relationship of these results to our recent results in YbAl{sub 3}.

  4. Fergusonite-type CeNbO{sub 4+?}: Single crystal growth, symmetry revision and conductivity

    SciTech Connect (OSTI)

    Bayliss, Ryan D. [Department of Materials, Imperial College London, Prince Consort Road, London, SW7 2BP (United Kingdom); Pramana, Stevin S.; An, Tao; Wei, Fengxia; Kloc, Christian L. [School of Materials Science and Engineering, 50 Nanyang Avenue, Nanyang Technological University, 639798 (Singapore); White, Andrew J.P. [Chemical Crystallography Laboratory, Department of Chemistry, Imperial College London, Exhibition Road, London, SW7 2AZ (United Kingdom); Skinner, Stephen J. [Department of Materials, Imperial College London, Prince Consort Road, London, SW7 2BP (United Kingdom); White, Timothy J. [School of Materials Science and Engineering, 50 Nanyang Avenue, Nanyang Technological University, 639798 (Singapore); Baikie, Tom, E-mail: tbaikie@ntu.edu.sg [School of Materials Science and Engineering, 50 Nanyang Avenue, Nanyang Technological University, 639798 (Singapore)

    2013-08-15

    Large fergusonite-type (ABO{sub 4}, A=Ce, B=Nb) oxide crystals, a prototype electrolyte composition for solid oxide fuel cells (SOFC), were prepared for the first time in a floating zone mirror furnace under air or argon atmospheres. While CeNbO{sub 4} grown in air contained CeNbO{sub 4.08} as a minor impurity that compromised structural analysis, the argon atmosphere yielded a single phase crystal of monoclinic CeNbO{sub 4}, as confirmed by selected area electron diffraction, powder and single crystal X-ray diffraction. The structure was determined in the standard space group setting C12/c1 (No. 15), rather than the commonly adopted I12/a1. AC impedance spectroscopy conducted under argon found that stoichiometric CeNbO{sub 4} single crystals showed lower conductivity compared to CeNbO{sub 4+?} confirming interstitial oxygen can penetrate through fergusonite and is responsible for the higher conductivity associated with these oxides. - Graphical abstract: Large fergusonite-type CeNbO{sub 4} crystals were prepared for the first time in a floating zone mirror furnace. Crystal growth in an argon atmosphere yielded a single phase monoclinic CeNbO4, as confirmed by selected area electron diffraction, powder and single crystal X-ray diffraction. The structure was determined in the standard space group setting C12/c1 (No. 15), rather than the commonly adopted I12/a1. AC impedance spectroscopy found CeNbO{sub 4} single crystals showed lower conductivity compared to CeNbO{sub 4+?} confirming interstitial oxygen can penetrate through fergusonite and is responsible for the higher conductivity associated with these oxides. Highlights: • Preparation of single crystals of CeNbO{sub 4} using a floating zone mirror furnace. • Correction to the crystal symmetry of the monoclinic form of CeNbO{sub 4}. • Report the conductivity of a single crystal of CeNbO{sub 4}.

  5. Curtin university of teChnology annual report 2011 107 PerForMAnCe indiCAtors

    E-Print Network [OSTI]

    Mucina, Ladislav

    research capability and performance Enhance capacity and financial sustainability l Total Research IncomeCurtin university of teChnology annual report 2011 107 PerForMAnCe indiCAtors CertifiCation of performanCe inDiCators.......................... 108 Curtin's institutional performanCe in

  6. Ce-MXRF: the power of separation with bench top element sensitive detection

    SciTech Connect (OSTI)

    Miller, T. C. (Thomasin C.); Joseph, M. R. (Martha R.); Havrilla, G. J. (George J.)

    2002-01-01

    Capillary electrophoresis (CE) is a proven separation technique that offers highly efficient separation, rapid analysis, and minute sample consumption. When combined with a element specific detection scheme, it can be used for chemical speciation of biologically and environmentally relevant species such as metal containing proteins. In this study, a new tool was developed for separation and elemental detection. Specifically, a simple CE apparatus was constructed using a thin-walled fused Si capillary and interfaced with a bench top micro x-ray fluorescence (MXRF) system. X-ray excitation and detection of the separated sample volumes was performed using an EDAX Eagle II micro x-ray fluorescence system equipped with a Rh target excitation source and a SiLi detector. It was demonstrated that the system could be used for the separation and detection of two metals from one another, specifically Cu{sup 2+} and Co{sup 2+}. Free Co{sup 2+} could also be isolated from Co{sup 2+} bound to cyanocobalamin (Vitamin B-12). Other systems that were explored were the separation of two organics, ferritin from cyanocobalamin as well as the separation of the different Cu and Zn isoforms of metallothinein. CE-MXRF was also used to separate the important serum isoforms of transferrin. Direct comparisons were made between CE-MXRF system and other elemental separation techniques such as CE-PIXE, CE-synchrotron-XRF, and CE-ICPMS.

  7. Hydrothermal growth and morphology evolution of CePO{sub 4} aggregates by a complexing method

    SciTech Connect (OSTI)

    Ma Lin [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Chen Weixiang [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)], E-mail: weixiangchen@css.zju.edu.cn; Zheng Yifan [Institute of Industrial Catalysis, Zhejiang University of Technology, Hangzhou 310014 (China); Xu Zhude [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)

    2008-11-03

    A facile hydrothermal route assisted by Na{sub 2}H{sub 2}EDTA (ethylenediaminetetraacetic acid disodium) has been successfully developed to prepare uniform cerium phosphate (CePO{sub 4}) aggregates with different morphologies, such as peanut-like and spindle-like. It was found that the as-prepared uniform CePO{sub 4} aggregates were constructed with many nearly parallel aligned nanorods. The molar ratio of EDTA/Ce{sup 3+}, solution pH and reaction time had great influences on the morphologies and sizes of the CePO{sub 4} samples. In our process of synthesis, Na{sub 2}H{sub 2}EDTA played important roles as complexing reagent and inducing agent on the formation of CePO{sub 4} aggregates. The possible growth mechanism for CePO{sub 4} aggregates was presented. Ce{sub 0.9}Tb{sub 0.1}PO{sub 4} aggregates with different morphologies were also prepared and their photoluminescence properties were characterized.

  8. Studies on Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. [RMD; Glodo, J. [RMD; Yuan, D. [NSTec

    2013-07-03

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  9. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn?

    SciTech Connect (OSTI)

    Das, Pinaki [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Lin, S. -Z. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ghimire, N.? J. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Huang, K. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of California, San Diego, La Jolla, CA (United States); Ronning, F. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Bauer, E.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Thompson, J.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Batista, C.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ehlers, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Janoschek, M. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2014-12-01

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J??J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3)??meV. Our results pave the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  10. Lattice instabilities in heavy fermion superconductors. [CeCu/sub 2/Si/sub 2/; CeAl/sub 3/; CeCu/sub 6/; UBe/sub 13/; UPt/sub 3/

    SciTech Connect (OSTI)

    Wohlleben, D.

    1987-01-01

    This paper shows that while in nonsuperconducting HF systems such as CeCu/sub 6/, CeAl/sub 3/ and stoichiometric CeCu/sub 2/Si/sub 2/, the large electronic ..gamma.. is due to a very narrow f band, in the three HF superconductors UBe/sub 13/, UPt/sub 3/ and nonstochiometric CeCu/sub 2/Si/sub 2/, it is not. The f band of these systems, as measured by their response to magnetic fields in three different ways, is much wider than suggested by the large ..gamma... According to their actual f band width, the HF superconductors belong into the Bantam Fermion class. It is argued that most of the large ..gamma.. of the HF superconductors is not of electronic origin and that it is instead caused by the precursor of a martensitic phase transition of the lattice or by a crystallographic phase mixture, i.e., that it is due to the displacive degrees of freedom. This suggests that the superconductivity of all three HF superconductors is caused by some special, low energy phonons rather than by a narrow f band. 52 refs., 4 figs., 3 tabs.

  11. Unconventional behavior of the Ce3Pt23Si11 ferromagnet C. Opagiste,1,

    E-Print Network [OSTI]

    Boyer, Edmond

    23Si11 is in equilibrium with the non-centrosymetric heavy fermion superconductor CePt3Si, when and presents a heavy fermion supercon- ducting state at Tc = 750 mK. Many studies on the superconductivity

  12. Life Cycle Analysis of the Production of Aviation Fuels Using the CE-CERT Process

    E-Print Network [OSTI]

    Hu, Sangran

    2012-01-01

    energy crop cultivation 16 . The second and third generation biofuels have much better potential as aviation fuelenergy, a CBTL process with CE-CERT process combined is expected to be of great potential in Fischer-Tropsch synthetic aviation fuel

  13. LIMITATIONS ON THE RESOLUTION OF YAG:CE BEAM PROFILE MONITOR...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    performance to other diagnostics. 2 Experimental Set-up And Initial Results An aluminum-base target was constructed with the two YAG:Ce crystals (0.50 mm and 0.25 mm thick...

  14. Pressure-Induced Structural Phase Transition in CeNi: X-ray and...

    Office of Scientific and Technical Information (OSTI)

    Pressure-Induced Structural Phase Transition in CeNi: X-ray and Neutron Scattering Studies and First-Principles Calculations Citation Details In-Document Search This content will...

  15. Structure and magnetic properties of Ce?(Ni/Al/Ga)??-A...

    Office of Scientific and Technical Information (OSTI)

    Ce(NiAlGa)-A new phase with the LaAl structure type Janka, Oliver Univ. of California, Davis, CA (United States); Westfalische Wilhelms-Universitat, Munster...

  16. A comparison of the structure and localized magnetism in Ce{sub 2}PdGa{sub 12} with the heavy fermion CePdGa{sub 6}

    SciTech Connect (OSTI)

    Macaluso, Robin T. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States); Millican, Jasmine N. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States); Nakatsuji, Satoru [Department of Physics, Kyoto University, Kyoto, Japan 606-8502 (Japan); Lee, Han-Oh [Department of Physics, University of California, Davis, CA 95616 (United States); Carter, B. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Moreno, Nelson O. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Fisk, Zachary [Department of Physics, University of California, Davis, CA 95616 (United States); Chan, Julia Y. [Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803 (United States)]. E-mail: jchan@lsu.edu

    2005-11-15

    Single crystals of Ce{sub 2}PdGa{sub 12} have been synthesized in Ga flux and characterized by X-ray diffraction. This compound crystallizes in the tetragonal P4/nbm space group, Z=2 with lattice parameters of a=6.1040(2)A and c=15.5490(6)A. It shows strongly anisotropic magnetism and orders antiferromagnetically at T{sub N}{approx}11K. A field-induced metamagnetic transition to the ferromagnetic state is observed below T{sub N}. Structure-property relationships with the related heavy-fermion antiferromagnet CePdGa{sub 6} are discussed.

  17. Results for aliovalent doping of CeBr{sub 3} with Ca{sup 2+}

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Patrick Doty, F.; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Joshua; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr{sub 3}) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca{sup 2+}) was used as a dopant to strengthen CeBr{sub 3} without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca{sup 2+} dopant were grown, i.e., 1.9% of the CeBr{sub 3} molecules were replaced by CaBr{sub 2} molecules, to match our target replacement of 1 out of 54 cerium atoms be replaced by a calcium atom. Precisely the mixture was composed of 2.26 g of CaBr{sub 2} added to 222.14 g of CeBr{sub 3}. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca{sup 2+}-doped CeBr{sub 3} exhibited little or no change in the peak fluorescence emission for 371?nm optical excitation for CeBr{sub 3}. The structural, electronic, and optical properties of CeBr{sub 3} crystals were studied using the density functional theory within the generalized gradient approximation. Calculated lattice parameters are in agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr{sub 3}, including the dielectric function, were calculated.

  18. Structure and scintillation yield of Ce-doped Al–Ga substituted yttrium garnet

    SciTech Connect (OSTI)

    Sidletskiy, Oleg; Kononets, Valerii; Lebbou, Kheirreddine; Neicheva, Svetlana; Voloshina, Olesya; Bondar, Valerii; Baumer, Vyacheslav; Belikov, Konstantin; Gektin, Alexander; Grinyov, Boris; Joubert, Marie-France

    2012-11-15

    Highlights: ? Range of Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce solid solution crystals are grown from melt by the Czochralski method. ? Light yield of mixed crystals reaches 130% of the YAG:Ce value at x ? 0.4. ? ?1% of antisite defects is formed in YGG:Ce, but no evidence of this is obtained for the rest of crystals. -- Abstract: Structure and scintillation yield of Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce solid solution crystals are studied. Crystals are grown from melt by the Czochralski method. Distribution of host cations in crystal lattice is determined. Quantity of antisite defects in crystals is evaluated using XRD and atomic emission spectroscopy data. Trend of light output at Al/Ga substitution in Y{sub 3}(Al{sub 1?x}Ga{sub x}){sub 5}O{sub 12}:Ce is determined for the first time. Light output in mixed crystals reaches 130% comparative to Ce-doped yttrium–aluminum garnet. Luminescence properties at Al/Ga substitution are evaluated.

  19. An Update on Improvements to NiCE Support for RELAP-7

    SciTech Connect (OSTI)

    McCaskey, Alex; Wojtowicz, Anna; Deyton, Jordan H.; Patterson, Taylor C.; Billings, Jay Jay

    2015-01-01

    The Multiphysics Object-Oriented Simulation Environment (MOOSE) is a framework that facilitates the development of applications that rely on finite-element analysis to solve a coupled, nonlinear system of partial differential equations. RELAP-7 represents an update to the venerable RELAP-5 simulator that is built upon this framework and attempts to model the balance-of-plant concerns in a full nuclear plant. This report details the continued support and integration of RELAP-7 and the NEAMS Integrated Computational Environment (NiCE). RELAP-7 is fully supported by the NiCE due to on-going work to tightly integrate NiCE with the MOOSE framework, and subsequently the applications built upon it. NiCE development throughout the first quarter of FY15 has focused on improvements, bug fixes, and feature additions to existing MOOSE-based application support. Specifically, this report will focus on improvements to the NiCE MOOSE Model Builder, the MOOSE application job launcher, and the 3D Nuclear Plant Viewer. This report also includes a comprehensive tutorial that guides RELAP-7 users through the basic NiCE workflow: from input generation and 3D Plant modeling, to massively parallel job launch and post-simulation data visualization.

  20. # Application Location Model Used Temperature Water Quality Macrophytes Periphyton Zooplankton Fish Year Project Started 1 Center Hill Lake Tennessee CE-QUAL-W2 X X 1979

    E-Print Network [OSTI]

    Wells, Scott A.

    Reservoir 2 Oregon CE-QUAL-W2 X 1999 11 Upper Bull Run River Oregon CE-QUAL-W2 X 1999 12 Lower Bull Run CE-QUAL-W2 X X 1979 3 Tualatin River Oregon CE-QUAL-W2 X X 1991 4 Hagg Lake Oregon CE-QUAL-W2 X X X CE-QUAL-W2 X X X 1991, 2005 7 Smith and Bybee Lakes Oregon CE-QUAL-W2 X X 1992 8 Klamath River - Lake

  1. Approved Module Information for CE1009, 2014/5 Module Title/Name: Introduction to Transfer Processes Module Code: CE1009

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    the student: * a knowledge of the fundamentals of heat transfer theory, and of the practical applications of conductive heat transfer theory * a knowledge of the fundamentals of fluid mechanics theory * a knowledgeApproved Module Information for CE1009, 2014/5 Module Title/Name: Introduction to Transfer

  2. Approved Module Information for CE1004, 2014/5 Module Title/Name: Process and Product Design Module Code: CE1004

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    . * Concept of scale * Product innovation - customer needs, ideas generation, ideas selection, productApproved Module Information for CE1004, 2014/5 Module Title/Name: Process and Product Design Module on a realistic project Product Design * To understand the difference between commodity and speciality chemicals

  3. Approved Module Information for CE3003, 2014/5 Module Title/Name: Advanced Process Design Project Module Code: CE3003

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Module Code: CE3003 School: Engineering and Applied Science Module Type: Project New Module? No Module) Programmes in which available: BEng/MEng Chemical Engineering. Available to Exchange Students? Not Specified. The Design Problem is intended to test the student's ability to apply the principles of Chemical Engineering

  4. Cellulose and Biomass Conversion Technology and Its Application to

    E-Print Network [OSTI]

    California at Riverside, University of

    . C.E. WYMAN National Renewable Energy Laboratory ] .ansportation fuels are almost totally derived from petroleum and accounted for more than one-quarter of the total energy used in the U.S. in 1989 system, and nitrogen oxides and unburned hydrocarbons from auto- motive exhaust contrihute [0 ozone

  5. Cultivar variation and selection potential relevant to the production of cellulosic ethanol from wheat straw

    E-Print Network [OSTI]

    California at Riverside, University of

    Cultivar variation and selection potential relevant to the production of cellulosic ethanol from a , J. Magid b , B. Yang d , C.E. Wyman c a Forestry and Wood Products, Forest & Landscape, Faculty Received in revised form 8 November 2011 Accepted 9 December 2011 Available online xxx Keywords: Bioethanol

  6. Fischer-Tropsch Synthesis. Reduction Behavior and Catalytic Activity of Fe-Ce Systems

    SciTech Connect (OSTI)

    Perez-Alonso, F.J.; Ojeda, M.; Herranz, T.; Fierro, J.L.G. [Instituto de Catalisis y Petroleoquimica (CSIC), c/Marie Curie 2, 28049 Madrid (Spain); Bengoa, J.F.; Marchetti, S.G. [CINDECA, Facultad de Ciencias Exactas, Facultad de Ingenieria, UNLP, CICBA, CONICET, Calle 47 No 257, 1900 La Plata (Argentina)

    2005-04-26

    Several Fe-Ce catalysts for FT synthesis were prepared following two different methods: coprecipitation from Fe and Ce nitrate solutions and a physical mixture of pure Fe and Ce precursors. The iron phases present in the activated catalysts were identified by XRD and Moessbauer spectroscopy. A good correlation between both techniques was found. The results revealed that the cerium oxide in the samples prepared by coprecipitation produces two effects: (i), stabilization of metastable species (Fe1-xO), and (ii), a decrease in the crystallite size of the iron species upon increasing Ce-contents, as inferred from an increase in superparamagnetic species. The catalysts were tested in CO hydrogenation in a flow reactor. It was found that selectivity towards light olefins increases for the coprecipitated Ce-containing catalysts, whereas CO conversion followed the opposite trend. Since the Fe1-xO phase was detected in these catalysts, it is suggested that the formation of the Fe1-xO phase would be responsible for the drop in catalytic activity.

  7. A Comparative Study of the Water Gas Shift Reaction Over Platinum Catalysts Supported on CeO2, TiO2 and Ce-Modified TiO2

    SciTech Connect (OSTI)

    Gonzalez, I.; Navarro, R; Wen, W; Marinkovic, N; Rodriguez, J; Rosa, F; Fierro, J

    2010-01-01

    WGS reaction has been investigated on catalysts based on platinum supported over CeO{sub 2}, TiO{sub 2} and Ce-modified TiO{sub 2}. XPS and XANES analyses performed on calcined catalysts revealed a close contact between Pt precursors and cerium species on CeO{sub 2} and Ce-modified TiO{sub 2} supports. TPR results corroborate the intimate contact between Pt and cerium entities in the Pt/Ce-TiO{sub 2} catalyst that facilitates the reducibility of the support at low temperatures while the Ce-O-Ti surface interactions established in the Ce-modified TiO{sub 2} support decreases the reduction of TiO{sub 2} at high temperature. The changes in the support reducibility leads to significant differences in the WGS activity of the studied catalysts. Pt supported on Ce-modified TiO{sub 2} support exhibits better activity than those corresponding to individual CeO{sub 2} and TiO{sub 2}-supported catalysts. Additionally, the Ce-TiO{sub 2}-supported catalyst displays better stability at reaction temperatures higher than 573 K that observed on pure TiO{sub 2}-supported counterpart. Activity measurements, when coupled with the physicochemical characterization of catalysts suggest that the modifications in the surface reducibility of the support play an essential role in the enhancement of activity and stability observed when Pt is supported on the Ce-modified TiO{sub 2} substrate.

  8. Mechanism of Methane Chemical Looping Combustion with Hematite Promoted with CeO2

    SciTech Connect (OSTI)

    Miller, Duane D.; Siriwardane, Ranjani

    2013-08-01

    Chemical looping combustion (CLC) is a promising technology for fossil fuel combustion that produces sequestration-ready CO{sub 2} stream, reducing the energy penalty of CO{sub 2} separation from flue gases. An effective oxygen carrier for CLC will readily react with the fuel gas and will be reoxidized upon contact with oxygen. This study investigated the development of a CeO{sub 2}-promoted Fe{sub 2}O{sub 3}?hematite oxygen carrier suitable for the methane CLC process. Composition of CeO{sub 2} is between 5 and 25 wt % and is lower than what is generally used for supports in Fe{sub 2}O{sub 3} carrier preparations. The incorporation of CeO{sub 2} to the natural ore hematite strongly modifies the reduction behavior in comparison to that of CeO{sub 2} and hematite alone. Temperature-programmed reaction studies revealed that the addition of even 5 wt % CeO{sub 2} enhances the reaction capacity of the Fe{sub 2}O{sub 3} oxygen carrier by promoting the decomposition and partial oxidation of methane. Fixed-bed reactor data showed that the 5 wt % cerium oxides with 95 wt % iron oxide produce 2 times as much carbon dioxide in comparison to the sum of carbon dioxide produced when the oxides were tested separately. This effect is likely due to the reaction of CeO{sub 2} with methane forming intermediates, which are reactive for extracting oxygen from Fe{sub 2}O{sub 3} at a considerably faster rate than the rate of the direct reaction of Fe{sub 2}O{sub 3} with methane. These studies reveal that 5 wt % CeO{sub 2}/Fe{sub 2}O{sub 3} gives stable conversions over 15 reduction/oxidation cycles. Lab-scale reactor studies (pulsed mode) suggest the methane reacts initially with CeO{sub 2} lattice oxygen to form partial oxidation products (CO + H{sub 2}), which continue to react with oxygen from neighboring Fe{sub 2}O{sub 3}, leading to its complete oxidation to form CO{sub 2}. The reduced cerium oxide promotes the methane decomposition reaction to form C + H{sub 2}, which continue to react with Fe{sub 2}O{sub 3}/Fe{sub 3}O{sub 4} to form CO/CO{sub 2} and H{sub 2}O. This mechanism is supported by the characterization studies, which also suggest that the formation of carbonaceous intermediates may affect the reaction rate and selectivity of the oxygen carrier.

  9. Optical properties of the Ce and La ditelluride charge density wave compounds

    SciTech Connect (OSTI)

    Lavagnini, M.; Sacchetti, A.; Degiorgi, L.; /Zurich, ETH; Shin, K.Y.; Fisher, I.R.; /Stanford U., Geballe Lab. /Stanford U., Appl. Phys. Dept.

    2010-02-15

    The La and Ce di-tellurides LaTe{sub 2} and CeTe{sub 2} are deep in the charge-density-wave (CDW) ground state even at 300 K. We have collected their electrodynamic response over a broad spectral range from the far infrared up to the ultraviolet. We establish the energy scale of the single particle excitation across the CDW gap. Moreover, we find that the CDW collective state gaps a very large portion of the Fermi surface. Similarly to the related rare earth tri-tellurides, we envisage that interactions and Umklapp processes play a role in the onset of the CDW broken symmetry ground state.

  10. Transmission Electron Microscopy Investigation of Krypton Bubbles in Polycrystalline CeO2

    SciTech Connect (OSTI)

    Lingfeng He; Clarissa Yablinsky; Mahima Gupta; Jian Gan; Marquis A. Kirk; Todd R. Allen

    2013-05-01

    To gain an understanding of gas bubble transport in oxide nuclear fuel, this paper uses polycrystalline CeO2, composed of both nanograins and micrograins, as a surrogate material for UO2. The CeO2 was implanted with 150-keV Kr ions up to a dose of 1 x 1016 ions/cm2 at 600 degrees C. Transmission electron microscopy characterizations of small Kr bubbles in nanograin and micrograin regions were compared. The grain boundary acted as an efficient defect sink, as evidenced by smaller bubbles and a lower bubble density in the nanograin region as compared to the micrograin region.

  11. Daylight photocatalysis performance of biomorphic CeO{sub 2} hollow fibers prepared with lens cleaning paper as biotemplate

    SciTech Connect (OSTI)

    Qian, Junchao; Chen, Feng [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China)] [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Wang, Fang; Zhao, Xiaobing [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China)] [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China); Chen, Zhigang, E-mail: ziyou1900@gmail.com [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China) [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Jiangsu Key Laboratory for Environment Functional Materials, 215009 Suzhou University of Science and Technology, Suzhou (China); State Key laboratory of Crystal Material, Shandong University, 250100 Jinan (China)

    2012-08-15

    Highlights: ? A novel, simple and eco-friendly approach for hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls is presented by using paper as template. ? The biomorphic CeO{sub 2} fibers was composed of nanosheets with bimodal pore-size mesoporous distribution and exhibited high light-harvesting under sunlight irradiation. ? The CeO{sub 2} microfibers biomimicking the natural plant structures have promising application for photodegradation of organic pollutants in water. -- Abstract: Hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls have been fabricated using lens cleaning paper as biotemplates. After sintered at 550 °C in air, the cellulosic fibers of paper were converted into micro-tubes composing of CeO{sub 2} crystallites with grain size about 8 nm. The photocatalytic activity of the CeO{sub 2} fibers was evaluated by photodegradation efficiency of methylene blue in aqueous solution under daylight irradiation. The characterized results show that the CeO{sub 2} fibers faithfully replicated micro-fibrous structure derived from original template and possessed dramatic enhanced photocatalytic activity compared with bulk CeO{sub 2}. This simple biotemplate method provides a cost-effective and eco-friendly route to obtain high performance photocatalysts.

  12. The NiCE Discussion Room: Integrating Paper and Digital Media to Support Co-Located Group Meetings

    E-Print Network [OSTI]

    -based interfaces, multi-user input, digital meeting room, design ACM Classification Keywords H5.3. GroupThe NiCE Discussion Room: Integrating Paper and Digital Media to Support Co-Located Group Meetings or replicate. We introduce a novel digital meeting room design, the NiCE Discussion Room, which integrates

  13. Aging behavior and precipitates analysis of the CuCrZrCe alloy Yi Zhang a,b,d,n

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Aging behavior and precipitates analysis of the Cu­Cr­Zr­Ce alloy Yi Zhang a,b,d,n , Alex A October 2015 Keywords: Cu­Cr­Zr­Ce alloy Cold rolling Aging treatment Microstructure Physical properties rolling and aging for 16 h at 300 °C. Under the same aging conditions, without cold rolling, the hardness

  14. Charge dynamics of Ce-based compounds: Connection between the mixed valent and Kondo-insulator states

    SciTech Connect (OSTI)

    Bucher, B. [Laboratorium fuer Festkoerperphysik, Eidgenoessische Technische Hochschule Zuerich, 8093 Zuerich (Switzerland)] [Laboratorium fuer Festkoerperphysik, Eidgenoessische Technische Hochschule Zuerich, 8093 Zuerich (Switzerland); Schlesinger, Z. [IBM, Thomas J. Watson Research Center, Yorktown Heights, New York 10958 (United States)] [IBM, Thomas J. Watson Research Center, Yorktown Heights, New York 10958 (United States); Mandrus, D.; Fisk, Z.; Sarrao, J. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); DiTusa, J.F.; Oglesby, C.; Aeppli, G.; Bucher, E. [AT& T Bell Laboratories, Murray Hill, New Jersey 07974 (United States)] [AT& T Bell Laboratories, Murray Hill, New Jersey 07974 (United States)

    1996-02-01

    The reflectivities of the mixed-valent compounds CeSn{sub 3} and CePd{sub 3} have been measured to obtain the optical conductivity as a function of temperature. Both compounds show a renormalization of the low-energy Drude conductivity at low temperatures. In addition, for the low-carrier-density compound CePd{sub 3}, but not for high-carrier-density CeSn{sub 3}, substantial spectral weight lost from the conductivity below 1000 cm{sup {minus}1} reappears in the frequency range 2000{endash}10000 cm{sup {minus}1}, indicating that CePd{sub 3} can be considered a lightly doped Kondo insulator. {copyright} {ital 1996 The American Physical Society.}

  15. Noise Estimation from a Single Image Ce Liu William T. Freeman

    E-Print Network [OSTI]

    Freeman, William T.

    Noise Estimation from a Single Image Ce Liu William T. Freeman CS and AI Lab, MIT {celiu to the image noise level, making it an important quantity to es- timate. We show how to estimate an upper bound on the noise level from a single image based on a piecewise smooth image prior model and measured CCD camera

  16. The CompuTer SCienCe program The bachelor of science degree in computer science

    E-Print Network [OSTI]

    Suzuki, Masatsugu

    The CompuTer SCienCe program The bachelor of science degree in computer science offered in the fundamentals of computer science, elements of practical application and an appreciation for liberal learning to work within various areas of computer science and to work across other disciplines. program edu

  17. DEPARTMENT OF THE NAVY OFfiCE OF THE CHIEF OF NAVAL OPERATIONS

    E-Print Network [OSTI]

    DEPARTMENT OF THE NAVY OFfiCE OF THE CHIEF OF NAVAL OPERATIONS 2000 NAVY PENTAGON WASHINGTON, DC: Chief of Naval Operations Subj , NAVY PASSENGER TRAVEL Ref: (al 000 Di rective 5154.29 of 9 Marc h 1993 on the management , execution, and funding of passenger travel for Navy personne l . This i n struction

  18. Phase transition and possible metallization in CeVO{sub 4} under pressure

    SciTech Connect (OSTI)

    Garg, Alka B.; Shanavas, K.V.; Wani, B.N.; Sharma, Surinder M.

    2013-07-15

    Phase stability of CeVO{sub 4} under pressure has been investigated using synchrotron based angle dispersive x-ray diffraction (ADXRD), electrical resistance and first principles calculations. The results indicate that the ambient zircon structure of the compound transforms to a low symmetry monoclinic monazite phase beyond 3.8 GPa with nearly 8.6% volume discontinuity. Beyond 11 GPa, the pattern could be fitted to a similar monazite structure which is about 12.7% denser and has a much larger monoclinic beta angle. On pressure release the first monoclinic phase is recovered. The electrical resistance data show a large drop in resistance with pressure indicating substantial narrowing down of the band gap. Electronic structure calculations support these observations and suggest possible pressure induced metallization in this material. - Pressure induced structural phase transition in CeVO{sub 4} as observed by x- ray diffraction (pressure vs. volume) and possible metallization in CeVO{sub 4} through electrical resistance and first principles electronic structure calculations. - Highlights: • Structural and electrical behavior of CeVO{sub 4} under pressure studied using x-ray diffraction and electrical resistance measurements and first principles calculations. • Two successive structural transitions confirmed by experiment and theory: zircon–monazite I–monazite II. • Band gap collapse and possible metallization is indicated by electrical resistance measurements and electronic structure calculations under pressure. • Novel observation of lower bulk modulus in the high pressure phase (both by experiment and calculations) explained through structural analysis.

  19. Temperature-dependent luminescence of Ce3+ in gallium-substituted

    E-Print Network [OSTI]

    Walker, D. Greg

    were prepared via a simple combustion synthe- sis method and had the formula Y2.97Ce0.03 3 Al1-xGax 5O width of 0.1 nm. The pulse width was 4ns at a characteristic energy of 300 J. The excitation pulse

  20. Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions Morten D. Pedersen 1 / 26 #12;This talk 1 Background 2 Understanding the Wind Turbine 3 Nonlinear Turbine Modeling 4;Background The Problem Previously stable wind turbine systems began exhibiting resonant behavior when put

  1. Technical Report No. 480 CE: The Classi er Estimator Framework for Data mining

    E-Print Network [OSTI]

    Dalkilic, Mehmet

    Technical Report No. 480 CE: The Classi er Estimator Framework for Data mining Mehmet M. Dalkilic a coherent framework for data mining in the relational model. Observing that data mining depends on two. The classi er indicates the target of the data mining investigation. The classi er may be di cult to express

  2. Title: SPONSORSHIP OR CE APPROVAL OF NON-SCHOOL OF NURSING CONTINUING EDUCATION OFFERING

    E-Print Network [OSTI]

    Chapman, Michael S.

    1 Title: SPONSORSHIP OR CE APPROVAL OF NON-SCHOOL OF NURSING CONTINUING EDUCATION OFFERING Index: School of Nursing sponsorship and/or approval of a continuing education offering given by individuals by approving offerings given by non-School of Nursing faculty. Implementing Procedures: Responsible Party

  3. Research activities in the Norwegian Deepwater Programme Conference on CeSOS Highlights and AMOS Visions

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    Research activities in the Norwegian Deepwater Programme Conference on CeSOS Highlights and AMOS Visions Rolf Baarholm, Statoil 6/5/2013 #12;- Norwegian Deepwater Programme - VIV characterization) in the Norwegian Sea. Later extended to include 16th 17th 18th 19th 20th and 21st round deepwater licences. About

  4. Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate

    E-Print Network [OSTI]

    Cao, Guozhong

    Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate: Received 3 September 2010 Accepted 2 November 2010 Available online 12 November 2010 Keywords: Lutetium silicate Cerium Solegel Photoluminescence Lu2SiO5 a b s t r a c t Cerium doped lutetium silicate powders

  5. ARTIFIC~L r~rELUOE~CE 189 STRIPS: A New Approach to the

    E-Print Network [OSTI]

    Pratt, Vaughan

    can be proven to be true. STRIPS represents a world n,~del as an arbitrary collection offirst-order, a world model is r~presented by a set of well- formed formulas (wffs) of the first-order predicateARTIFIC~L r~rELUOE~CE 189 STRIPS: A New Approach to the Application of .Theorem Proving to Problem

  6. CE-QUAL-W2 Version 3: Hydrodynamic and Water Quality River Basin Modeling

    E-Print Network [OSTI]

    Wells, Scott A.

    and Oregon; the Bull Run River basin composed of 3 water sup- ply reservoirs and 2 river sections with a 2CE-QUAL-W2 Version 3: Hydrodynamic and Water Quality River Basin Modeling S. A. Wells Department for deep, long, and narrow waterbodies. The current model, Version 2, has been used in over 200 river

  7. Hydrodynamic and water quality river basin modeling using CE-QUAL-W2 version 3

    E-Print Network [OSTI]

    Wells, Scott A.

    of the Lower Snake River in the Northwestern USA; the Bull Run River basin composed of 3 water supplyHydrodynamic and water quality river basin modeling using CE-QUAL-W2 version 3 Scott A. Wells for deep, long, and narrow waterbodies. The current model, Version 2, has been used in over 200 river

  8. Synthesis and crystal structure of two new cerium rhodium oxides: Ce{sub 2/3-x}Rh{sup 3+}{sub 2}O{sub 4} (x{approx}0.12) with Ce mixed valency and Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Mizoguchi, Hiroshi; Zakharov, L.N.; Bhuvanesh, N.S.P.; Sleight, A.W.; Subramanian, M.A.

    2011-06-15

    The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared. Their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Based on the structural analysis and physical properties, oxidation states for CeRh{sub 2}O{sub 5} can be assigned as Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}. A small variation in x was detected for Ce{sub 2/3-x}Rh{sub 2}O{sub 4} indicating a formula ranging from Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}. - Graphical abstract: The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared and their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Highlights: > The new compounds CeRh{sub 2}O{sub 5} and Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) have been prepared. > Their structures were determined from single crystal X-ray diffraction data. > Valence picture is Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5} and Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}.

  9. (U) Equation of State and Compaction Modeling for CeO2

    SciTech Connect (OSTI)

    Fredenburg, David A.; Chisolm, Eric D.

    2014-10-20

    Recent efforts have focused on developing a solid-liquid and three-phase equation of state (EOS) for CeO2, while parallel experimental efforts have focused on obtaining high-fidelity Hugoniot measurements on CeO2 in the porous state. The current work examines the robustness of two CeO2 SESAME equations of state, a solid-liquid EOS, 96170, and a three-phase EOS, 96171, by validating the EOS against a suite of high-pressure shock compression experiments on initially porous CeO2. At lower pressures compaction is considered by incorporating a two-term exponential form of the P-compaction model, using three separate definitions for ?(P). Simulations are executed spanning the partially compacted and fully compacted EOS regimes over the pressure range 0.5 - 109 GPa. Comparison of calculated Hugoniot results with those obtained experimentally indicate good agreement for all definitions of ?(P) with both the solid-liquid and three-phase EOS in the low-pressure compaction regime. At higher pressures the three-phase EOS does a better job at predicting the measured Hugoniot response, though at the highest pressures EOS 96171 predicts a less compliant response than is observed experimentally. Measured material velocity profiles of the shock-wave after it has transmitted through the powder are also compared with those simulated using with solid-liquid and three-phase EOS. Profiles lend insight into limits of the current experimental design, as well as the threshold conditions for the shock-induced phase transition in CeO2.

  10. Sulfur tolerant metal doped Fe/Ce catalysts for high temperature WGS reaction at low steam to CO ratios XPS and Mssbauer spectroscopic study

    E-Print Network [OSTI]

    Boolchand, Punit

    spectroscopy TPR XPS CeO2 Magnetite a b s t r a c t High temperature water gas shift reaction (WGS) at low/Ce and Co-, Zr-, Hf-, and Mo-doped Fe/Ce catalysts compared to the activated catalysts. For Cr-doped FeSulfur tolerant metal doped Fe/Ce catalysts for high temperature WGS reaction at low steam to CO

  11. Structure and magnetic properties of Ce?(Ni/Al/Ga)??—A new phase with the La?Al?? structure type

    SciTech Connect (OSTI)

    Janka, Oliver; Shang, Tian; Baumbach, Ryan E.; Bauer, Eric D.; Thompson, Joe D.; Kauzlarich, Susan M.

    2015-03-01

    Single crystals of Ce?(Ni/Al/Ga)?? were obtained from an Al flux reaction. Single crystals of the title compound crystallizing in the orthorhombic space group Immm (No. 71, Z = 2) with a = 436.38(14), b = 1004.5(3) and c = 1293.4(4) pm. This is a standardized unit cell of the previously published La?Al?? structure type. Wavelength dispersive microprobe provides the composition of Ce?.?????Ni?.?????Al?.?????Ga?.?????. Single crystal refinement provides the composition Ce?Ni?.??Al?.??Ga?.?? with substitution of the Ni and Ga on the Al1 and Al4 sites with the Al2 and Al3 solely occupied by Al. Magnetic susceptibility measurements reveal antiferromagnetic ordering with TN = 4.8 K and there is no evidence for a ferromagnetic ordering that has been reported for Ce?Al??. The effective magnetic moment was found to be ?eff = 1.9?B/Ce, which is lower than the expected value for trivalent Ce (2.54?B/Ce).

  12. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J?-J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  13. Preparation of new morphological ZnO and Ce-doped ZnO

    SciTech Connect (OSTI)

    Chelouche, A.; Djouadi, D.; Aksas, A. [Laboratoire de Génie de l'Environnement, Université A. Mira de Béjaia, Route de Targua Ouzemmour Béjaia (Algeria)

    2013-12-16

    ZnO micro-tori and cerium doped hexangulars ZnO have been prepared by the sol-gel method under methanol hypercritical conditions of temperature and pressure. X-ray diffraction (XRD) measurement has revealed the high crystalline quality and the nanometric size of the samples. Scanning electron microscopy (SEM) has shown that the ZnO powder has a torus-like shape while that of ZnO:Ce has a hexangular-like shape, either standing free or inserted into the cores of ZnO tori. Transmission electron microscopy (TEM) has revealed that the ZnO particles have sizes between 25 and 30 nm while Ce-doped ZnO grains have diameters ranging from 75 nm to 100 nm. Photoluminescence spectra at room temperature of the samples have revealed that the introduction of cerium in ZnO reduces the emission intensity lines, particularly the ZnO red and green ones.

  14. PSD Methods Comparison and Discrimination Efficiency Study for LaBr3:Ce Detector

    E-Print Network [OSTI]

    Cang, Jirong; Zeng, Zhi; Cheng, Jianping; Liu, Yinong; Li, Junli

    2015-01-01

    LaBr3:Ce scintillator has been widely studied for nuclear spectroscopy because of its optimal energy resolution (efficient and a potential method to suppress the alpha background from the 227Ac. In this paper, a detailed comparison of 3 digital PSD algorithms, the Charge Comparison Method, the Mean Time Method and the Gamma-Alpha Model Analysis Method, for alpha and gamma discrimination in LaBr3:Ce was done. The algorithm parameters and discrimination efficiency were analyzed and optimized for each method. Moreover, for the CCM, the correlation between the CCM feature value distribution and the total charge (energy) was quantitatively analyzed, and a fitting equation of the correlation is inferred and verified with experiment. With the equation, an energy-dependent threshold was chosen to optimize the discrim...

  15. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in amore »heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.« less

  16. Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(111)

    SciTech Connect (OSTI)

    Calaza, Florencia; Chen, Tsung-Liang; Mullins, David R; Xu, Ye; Overbury, Steven {Steve} H

    2015-01-01

    Adsorption and reaction of acetic acid on a CeO2(1 1 1) surface was studied by a combination of ultra-highvacuum based methods including temperature desorption spectroscopy (TPD), soft X-ray photoelectronspectroscopy (sXPS), near edge X-ray absorption spectroscopy (NEXAFS) and reflection absorption IRspectroscopy (RAIRS), together with density functional theory (DFT) calculations. TPD shows that thedesorption products are strongly dependent upon the initial oxidation state of the CeO2surface, includingselectivity between acetone and acetaldehyde products. The combination of sXPS and NEXAFS demon-strate that acetate forms upon adsorption at low temperature and is stable to above 500 K, above whichpoint ketene, acetone and acetic acid desorb. DFT and RAIRS show that below 500 K, bridge bondedacetate coexists with a moiety formed by adsorption of an acetate at an oxygen vacancy, formed bywater desorption.

  17. Public Administration Department SPRING 2014 Schedule C = Core, MP = Management Perceptive, CE = Culminating Experience

    E-Print Network [OSTI]

    Design & Change Management Hybrid: 7:30pm--8:45pm on 1/27 & 3/17; 6:00pm--8:45pm on 2/10, 2/24, 4/7, 411/4/2014 TENTATIVE Public Administration Department SPRING 2014 Schedule C = Core, MP = Management Perceptive, CE = Culminating Experience MPA Elective Emphases Courses: PM = Public Management, NP = Nonprofit

  18. Investigation into Nanostructured Lanthanum Halides and CeBr{sub 3} for Nuclear Radiation Detection

    SciTech Connect (OSTI)

    Guss, P., Guise, R., Mukhopadhyay, S., Yuan, D.

    2011-06-22

    This slide-show presents work on radiation detection with nanostructured lanthanum halides and CeBr{sub 3}. The goal is to extend the gamma energy response on both low and high-energy regimes by demonstrating the ability to detect low-energy x-rays and relatively high-energy activation prompt gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, cerium bromide, or other nanocrystal material. Homogeneous and nano structure cases are compared.

  19. One-dimensional chain structures produced by Ce on Si(111)

    E-Print Network [OSTI]

    Kim, Sehun

    of rare-earth metals on semicon- ductors, especially Si [1], by self-assembly has at- tracted considerable) surfaces have been reported for various rare-earth metals (e.g., Ce [6­8], Sm [9], Er [10,11], Eu [12 structures have been reported for many rare-earth metals, such as 3 · 2, 5 · 1, and 7 · 1 for Sm, 5 · 2

  20. Synthesis of Transient Climate Evolution of the last 21-kyr (SynTraCE-21)

    SciTech Connect (OSTI)

    Zhengyu Liu

    2011-05-06

    Climate evolution in the last 21,000 years provides critical observations for testing state-of-the-art climate models on the simulation of climate evolution and abrupt climate changes. Proxy evidences and new modeling activities have led to rapid advances in our understanding of climate change for this past time period. This funding helps to support the first international SynTraCE-21k workshop at Mount Hood, Oregon from 10-13 October, 2010.

  1. Remarkably robust and correlated coherence and antiferromagnetism in (Ce1-x Lax)Cu?Ge?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hodovanets, H.; Bud’ko, S.? L.; Straszheim, W.? E.; Taufour, V.; Mun, E.? D.; Kim, H.; Flint, R.; Canfield, P.? C.

    2015-06-08

    We present magnetic susceptibility, resistivity, specific heat, and thermoelectric power measurements on (Ce1-x Lax)Cu?Ge? single crystals (0 ? x ? 1). With La substitution, the antiferromagnetic temperature TN is suppressed in an almost linear fashion and moves below 0.36 K, the base temperature of our measurements for x > 0.8. Surprisingly, in addition to robust antiferromagnetism, the system also shows low temperature coherent scattering below Tcoh up to ~ 0.9 of La, indicating a small percolation limit ~ 9% of Ce. Tcoh as a function of magnetic field was found to have different behavior for x more »> 0.9. Remarkably, (Tcoh)² at H = 0 was found to be linearly proportional to TN. The jump in the magnetic specific heat ?Cm at TN as a function of TK/TN for (Ce1-x Lax)Cu?Ge? follows the theoretical prediction based on the molecular field calculation for the S = 1/2 resonant level model.« less

  2. Hydrides of CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and mixed CeNi/sub 5//MmNi/sub 5/

    SciTech Connect (OSTI)

    Lakner, J.F.; Chow, T.S.

    1982-09-01

    Six intermetallic alloys (CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and a mixed alloy, CeNi/sub 5//MmNi/sub 5/) were investigated with respect to their suitability to provide high hydrogen capacity and their potential for use in providing substantial hydrogen pressure at both low and high temperatures. A second phase of our investigation dealt with ball-milling and hydriding and dehydriding cycles to produce fine particles for use in hydride powder transfer studies. A summary of several Van't Hoff plots is also included for hydride-forming alloys.

  3. Specific heat of CeRhIn5: Pressure-driven evolution of the ground state from antiferromagnetism to superconductivity

    E-Print Network [OSTI]

    2001-01-01

    Specific Heat of CeRhIn5: Pressure–Driven Evolution of the32306 Measurements of the specific heat of antiferromagneticsee text). Fig. 2. (a) The specific heat, for representative

  4. Emission properties and back-bombardment for CeB{sub 6} compared to LaB{sub 6}

    SciTech Connect (OSTI)

    Bakr, Mahmoud; Kawai, M.; Kii, T.; Zen, H.; Masuda, K.; Ohgaki, H.

    2015-02-14

    The emission properties of CeB{sub 6} compared to LaB{sub 6} thermionic cathodes have been measured using an electrostatic DC gun. Obtaining knowledge of the emission properties is the first step in understanding the back-bombardment effect that limits wide usage of thermionic radio-frequency electron guns. The effect of back-bombardment electrons on CeB{sub 6} compared to LaB{sub 6} was studied using a numerical simulation model. The results show that for 6??s pulse duration with input radio-frequency power of 8 MW, CeB{sub 6} should experience 14% lower temperature increase and 21% lower current density rise compared to LaB{sub 6}. We conclude that CeB{sub 6} has the potential to become the future replacement for LaB{sub 6} thermionic cathodes in radio-frequency electron guns.

  5. Impact of the CE mark approval on exit opportunities and validation for early stage medical device companies

    E-Print Network [OSTI]

    Kothari, Ashish (Ashish Shrikant)

    2011-01-01

    The aim of this thesis was to look at the impact of acquiring the CE marking approval on the outcome of early stage medical device companies, specifically its impact on strategic acquisition opportunities and on valuation. ...

  6. Making the Best Use of What you Have Asia Intellectual Capital Alliances a te ectua Cap ta a ce

    E-Print Network [OSTI]

    BYOBBYOB ­ Making the Best Use of What you Have Asia Intellectual Capital Alliances a te ectua Cap ta a ce 24 October 2011 Copyright © 2011 Asia Intellectual Capital Alliance. All rights reserved. #12

  7. Late Antique Plague Ships: Sixth-Century C.E. Trade Routes and Their Role in Transmitting the Justinianic Plague 

    E-Print Network [OSTI]

    Kofahl, Meko

    2013-07-29

    The major European epidemic of bubonic plague in the sixth century C.E. – named for the ruling Byzantine emperor, Justinian – devastated the empire at the same time that outside pressures in the form of Goths, Vandals, ...

  8. KRIEGER/WHITING OFFICE OF HUMAN RESOURCES Wyman Park Building, 6th

    E-Print Network [OSTI]

    Weaver, Harold A. "Hal"

    OFFICE DIRECTORY John Kunz, SPHR, HCS, Director of Human Resources · Manager and staff HR consultation · Employee Relations · JHU Child Safety compliance

  9. Review: Continuous hydrolysis and fermentation for cellulosic ethanol production Simone Brethauer, Charles E. Wyman *

    E-Print Network [OSTI]

    California at Riverside, University of

    Review: Continuous hydrolysis and fermentation for cellulosic ethanol production Simone Brethauer for these benefits to be realized. Continuous hydrolysis and fermentation processes offer important potential advantages in reducing costs, but little has been done on continuous processing of cellulosic biomass

  10. Effect of oxygen vacancy on half metallicity in Ni-doped CeO{sub 2} diluted magnetic semiconductor

    SciTech Connect (OSTI)

    Saini, Hardev S. Saini, G. S. S.; Singh, Mukhtiyar; Kashyap, Manish K.

    2015-05-15

    The electronic and magnetic properties of Ni-doped CeO{sub 2} diluted amgentic semiconductor (DMS) including the effect of oxygen vacancy (V{sub o}) with doping concentration, x = 0.125 have been calculated using FPLAPW method based on Density Functional Theory (DFT) as implemented in WIEN2k. In the present supercell approach, the XC potential was constructed using GGA+U formalism in which Coulomb correction is applied to standard GGA functional within the parameterization of Perdew-Burke-Ernzerhof (PBE). We have found that the ground state properties of bulk CeO{sub 2} compound have been modified significantly due to the substitution of Ni-dopant at the cation (Ce) site with/without V{sub O} and realized that the ferromagnetism in CeO{sub 2} remarkably depends on the V{sub o} concentrations. The presence of V{sub o}, in Ni-doped CeO{sub 2}, can leads to strong ferromagnetic coupling between the nearest neighboring Ni-ions and induces a HMF in this compound. Such ferromagnetic exchange coupling is mainly attributed to spin splitting of Ni-d states, via electrons trapped in V{sub o}. The HMF characteristics of Ni-doped CeO{sub 2} including V{sub o} makes it an ideal material for spintronic devices.

  11. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Sun, Junming; Gao, Feng; Peden, Charles HF; Wang, Yong

    2013-03-21

    A series of VOx/CeO2 catalysts with various sodium loadings (Na/V ratio from 0 to 1) has been studied for oxidative dehydrogenation (ODH) of methanol. The effect of sodium on the surface structure, redox properties, and surface acidity/basicity of VOx/CeO2 was investigated using hydrogen temperature-programmed reduction (H2-TPR), Raman spectroscopy, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT). The experimental results indicate that the effect of sodium on VOx/CeO2 is highly dependent on the Na/V ratio. At a low Na/V ratio (Na/V<0.25), sodium addition only slightly decreases the redox properties of VOx/CeO2 and has little effect on its activity and selectivity to formaldehyde, even though the Brönsted acidity is almost completely eliminated at a Na/V ratio of 0.25. At a high Na/V ratio (Na/V>0.25), sodium addition greatly alters the nature of the active sites by V-O-Ce bond cleavage and V-O-Na bond formation, leading to significantly reduced activity of the VOx/CeO2 catalysts. At Na/V>0.25, the selectivity to formaldehyde also decreases with increasing Na/V ratio due to: (1) the suppressed reducibility of VOx, and (2) increased basicity leading to increased CO2.

  12. Surface-structure sensitivity of CeO2 nanocrystals in photocatalysis and enhancing the reactivity with nanogold

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lei, Wanying; Zhang, Tingting; Gu, Lin; Liu, Ping; Rodriguez, José A.; Liu, Gang; Liu, Minghua

    2015-06-19

    Structure–function correlations are a central theme in heterogeneous (photo)catalysis. In this research, using aberration-corrected scanning transmission electron microscopy (STEM), the atomic surface structures of well-defined one-dimensional (1D) CeO2 nanorods (NRs) and 3D nanocubes (NCs) are directly visualized at subangstrom resolution. CeO2 NCs predominantly expose the {100} facet, with {110} and {111} as minor cutoff facets at the respective edges and corners. Notably, the outermost surface layer of the {100} facet is nearly O-terminated. Neither surface relaxations nor reconstructions on {100} are observed, indicating unusual polarity compensation, which is primarily mediated by near-surface oxygen vacancies. The surface of CeO2 NRs ismore »highly stepped, with the enclosed {110} facet exposing Ce cations and O anions on terraces. On the basis of STEM profile-view imaging and electronic structure analysis, the photoreactivity of CeO2 nanocrystals toward aqueous methyl orange degradation under UV is revealed to be surface-structure-sensitive, following the order: {110} >> {100}. The underlying surface-structure sensitivity can be attributed to the variation in low-coordinate surface cerium cations between {110} and {100} facets. To further enhance light absorption, Au nanoparticles (NPs) are deposited on CeO2 NRs to form Au/CeO2 plasmonic nanocomposites, which dramatically promotes the photoreactivity that is Au particle size- and excitation light wavelength-dependent. The mechanisms responsible for the enhancement of photocatalytic activity are discussed, highlighting the crucial role of photoexcited charge carrier transfer.« less

  13. Structure and magnetic properties of Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H-polytype in the Ba-Ce-Mn-O system

    SciTech Connect (OSTI)

    Macias, Mario A.; Mentre, Olivier; Cuello, Gabriel J.; Gauthier, Gilles H.

    2013-02-15

    Based on the peculiar magnetic properties that are observed in pseudo one-dimensional manganites, we decided to synthesize the new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} compound. The preparation was performed by solid state reaction in air at about 1350 Degree-Sign C, for which we found that the compound crystallizes in a hexagonal symmetry with space group P6{sub 3}/mmc (No-194) and cell parameters a=b=5.7861(2) A and c=23.902(1) A. The structural description was correlated with neutron diffraction and bond valence calculations, confirming the presence of Ce{sup 4+} and Mn{sup 4+} segregated in the different crystallographic positions. Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} displays evidence for strong AFM couplings already set at room temperature. The main arrangement of Mn{sup 4+} in magnetically isolated tetramers of face-sharing octahedra is responsible for a metamagnetic-like transition around 50 K. - Graphical abstract: The new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} polytype shows strong AFM couplings in magnetically isolated [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers of face-sharing octahedral, resulting in a metamagnetic-like transition around 50 K. Highlights: Black-Right-Pointing-Pointer Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H polytype, has been prepared in the Ba-Ce-Mn-O system. Black-Right-Pointing-Pointer The compound crystallizes in the P6{sub 3}/mmc space group with (cchhh){sub 2} stacking sequence. Black-Right-Pointing-Pointer [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers are separated by [CeO{sub 6}] octahedra in the structure. Black-Right-Pointing-Pointer Instead of robust AFM ordering, a metamagnetic-like transition is found around 50 K.

  14. Pulse studies to decipher the role of surface morphology in CuO/CeO? nanocatalysts for the water gas shift reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Zhao, Fuzhen; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Si, Rui; Johnston-Peck, Aaron C.; Martinez-Arias, Arturo; Hanson, Jonathan C.; Senanayake, Sanjaya D.

    2015-01-23

    The water-gas shift reaction (WGS, CO + H?O ? CO?) was studied over CuO/CeO? catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO? (ns) exhibited a substantially better activity than CuO/CeO? (nc). The higher activity was associated with the unique properties of CuO/CeO? (ns), suchmore »as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³? in CeO? (ns).« less

  15. Pulse studies to decipher the role of surface morphology in CuO/CeO? nanocatalysts for the water gas shift reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhao, Fuzhen [South-Central Univ. for Nationalities, Wuhan, Hubei (China); Brookhaven National Lab., Upton, NY (United States); Liu, Zongyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Yao, Siyu [Brookhaven National Lab. (BNL), Upton, NY (United States); Si, Rui [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnston-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Martinez-Arias, Arturo [Inst. de Catalisis y Petroleoquimica, Consejo Superior de Investigaciones Cientificas, Madrid (Spain); Hanson, Jonathan C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-03-01

    The water-gas shift reaction (WGS, CO + H?O ? CO?) was studied over CuO/CeO? catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO? (ns) exhibited a substantially better activity than CuO/CeO? (nc). The higher activity was associated with the unique properties of CuO/CeO? (ns), such as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³? in CeO? (ns).

  16. XRD, lead equivalent and UV-VIS properties study of Ce and Pr lead silicate glasses

    SciTech Connect (OSTI)

    Alias, Nor Hayati, E-mail: norhayati@nuclearmalaysia.gov.my; Abdullah, Wan Shafie Wan, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Norriza Mohd, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Muhammad Jamal Md, E-mail: norhayati@nuclearmalaysia.gov.my; Zali, Nurazila Mat; Abdullah, Nuhaslinda Ee [Malaysian Nuclear Agency, 43000, Bangi, Kajang, Selangor (Malaysia); Muhammad, Azali [Malaysian Society for Non-Destructive Testing (Malaysia)

    2014-02-12

    In this work, Cerium (Ce) and Praseodymium (Pr) containing lead silicate glasses were produced with 2 different molar ratios low (0.2 wt%) and high (0.4wt%). These types of glasses can satisfy the characteristics required for radiation shielding glasses and minimize the lead composition in glass. The radiation shielding properties of the synthesized glasses is explained in the form of lead equivalent study. The XRD diffraction and UV-VIS analysis were performed to observe the structural changes of the synthesis glasses at 1.5 Gy gamma radiation exposures.

  17. DFT+U Study of CeO2 and Its Native Defects

    E-Print Network [OSTI]

    Huang, Bolong; Gillen, Roland; Robertson, John

    2014-10-14

    , Frenkel defect, pseudopotential transferability, oxidation catalyst 1. Introduction CeO2 is an important lanthanide oxide which is widely used as an oxygen buffer in car exhaust catalysts1, as a fast ion conductor in solid state fuel cells2, as a... as optimization of pseudopotentials47. The PBE functional was chosen for PBE+U calculations with a kinetic cutoff energy of 750eV, which expands the valence electrons states in a plane-wave basis set. The ensemble DFT (EDFT) method of Marzari et al48 is used...

  18. Nanostructured LaF{sub 3}:Ce Quantum Dot Nuclear Radiation Detector

    SciTech Connect (OSTI)

    Guss, P., Guise, R., Reed, M., Mukhopadhyay, S., Yuan, D.

    2010-11-01

    Many radioactive isotopes have low energy X-rays and high energy gamma rays of interest for detection. The goal of the work presented was to demonstrate the possibility of measuring both low-energy X-rays and relatively high-energy gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, or cerium bromide. The key accomplishments of the project was the building and acquisition of the LaF3:Ce nanocomposite detectors. Nanocomposite detectors are sensitive to {gamma}’s as well as n’s and X-rays.

  19. DOI-BLM-ID-110-2009-3825-CE | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstruments Inc Jump to:67-2006-12 Jump to:110-2009-3825-CE Jump to:

  20. BaCe1-xPdxO3-(0 e x e 0.1): Redox Controlled Ingress and Egress of Palladium in a Perovskite

    E-Print Network [OSTI]

    Rappe, Andrew M.

    BaCe1-xPdxO3- (0 e x e 0.1): Redox Controlled Ingress and Egress of Palladium in a Perovskite Jun-ray photoelectron spectroscopy that Pd2+ ions can be substituted for Ce in perovskite BaCeO3 and that, under description of the structure. The Pd2+-containing perovskite phases extrude elemental face-centered cubic

  1. Nickel deficiency in RENi2-xP2 (RE=La, Ce, Pr). Combined crystallographic and physical property studies

    SciTech Connect (OSTI)

    Bauer, Eric D; Ronning, Filip; Thompson, Joe D; Sarrao, John L; Bobev, S; Xia, S

    2008-01-01

    Large single crystals from RENi{sub 2-x}P{sub 2} (RE = La, Ce, Pr) were synthesized from the pure elements using Sn as a metal flux, and their structures were established by X-ray crystallography. The title compounds were confirmed to crystallize in the body-centered tetragonal ThCr{sub 2}Si{sub 2} structure type (space group I4/mmm (No. 139); Pearson's symbol tI10), but with a significant stoichiometry breadth with respect to the transition metal. Systematic synthetic work, coupled with accurate structure refinements indicated strong correlation between the degree of Ni-deficiency and the reaction conditions. For four different PrNi{sub 2-x}P{sub 2} (x {le} 0.5) samples, temperature dependent dc magnetization measurements indicated typical local moment 4f-magnetism and a stable Pr{sup 3+} ground state. Field-dependent heat capacity data confirmed a ferromagnetic order at low temperature, and the variations of T{sub c} with the concentration of Ni defects are discussed. LaNi{sub 2-x}P{sub 2}, as expected was found to be Pauli-like paramagnetic in the studied temperature regime, while the Ce-analog CeNi{sub 2-x}P{sub 2} (x = 0.28(1)) showed the characteristics of a mixed valent Ce{sup 3+}/Ce{sup 4+} system with a possible Kondo temperature on the order of 230 K.

  2. Electronic structure of the heavy-fermion caged compound Ce?Pd??X? (X = Si, Ge) studied by density functional theory and photoelectron spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yamaoka, Hitoshi; Jarrige, Ignace; Schwier, Eike F.; Arita, Masashi; Shimada, Kenya; Tsujii, Naohito; Jiang, Jian; Hayashi, Hirokazu; Iwasawa, Hideaki; Namatame, Hirofumi; et al

    2015-03-30

    The electronic structure of Ce?Pd??X? (X = Si, Ge) has been studied using detailed density functional theory (DFT) calculations and high-resolution photoelectron spectroscopy (PES) measurements. The orbital decomposition of the electronic structure by DFT calculations indicates that Ce atoms at the (8c) site surrounded by 16 Pd atoms have a more localized nature and a tendency to be magnetic. Ce atoms in the (4a) site surrounded by 12 Pd and 6 X atoms, on the other, show only a negligible magnetic moment. In the photoemission valence-band spectra we observe a strong f? (Ce??) component with a small fraction of f¹more »(Ce³?) component. The spectral weight of f¹ component near the Fermi level Ce?Pd??Si? is stronger than that for Ce?Pd??Ge? at the 4d-4f resonance, suggesting stronger c-f hybridization in the former. This may hint to the origin of the large electronic specific coefficient of Ce?Pd??Si? compared to Ce?Pd??Ge?.« less

  3. Electronic structure of the heavy-fermion caged compound Ce3Pd20X6(X=Si,Ge) studied by density functional theory and photoelectron spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yamaoka, Hitoshi; Schwier, Eike F.; Arita, Masashi; Shimada, Kenya; Tsujii, Naohito; Jarrige, Ignace; Jiang, Jian; Hayashi, Hirokazu; Iwasawa, Hideaki; Namatame, Hirofumi; et al

    2015-03-30

    The electronic structure of Ce?Pd??X? (X = Si, Ge) has been studied using detailed density functional theory (DFT) calculations and high-resolution photoelectron spectroscopy (PES) measurements. The orbital decomposition of the electronic structure by DFT calculations indicates that Ce atoms at the (8c) site surrounded by 16 Pd atoms have a more localized nature and a tendency to be magnetic. Ce atoms in the (4a) site surrounded by 12 Pd and 6 X atoms, on the other, show only a negligible magnetic moment. In the photoemission valence-band spectra we observe a strong f? (Ce??) component with a small fraction of f¹more »(Ce³?) component. The spectral weight of f¹ component near the Fermi level Ce?Pd??Si? is stronger than that for Ce?Pd??Ge? at the 4d-4f resonance, suggesting stronger c-f hybridization in the former. This may hint to the origin of the large electronic specific coefficient of Ce?Pd??Si? compared to Ce?Pd??Ge?.« less

  4. Update on the CeC PoP 704 MHz 5-cell cavity cryomodule design and fabrication

    SciTech Connect (OSTI)

    Brutus, J. C.; Belomestnykh, S.; Ben-Zvi, I.; Grimm, T.; Huang, Y.; Jecks, R.; Kelly, M.; Litvinenko, V.; Pinayev, I.; Reid, T.; Skaritka, J.; Snydstrup, L.; Than, R.; Tuozzolo, J.; Xu, W.; Yancey, J.; Gerbick, S.

    2015-05-03

    A 5-cell SRF cavity operating at 704 MHz will be used for the Coherent Electron Cooling Proof of Principle (CeC PoP) system under development for the Relativistic Heavy Ion Collider (RHIC) at Brookhaven National Laboratory. The CeC PoP experiment will demonstrate the new technique of cooling proton and ion beams that may increase the beam luminosity in certain cases, by as much as tenfold. The 704 MHz cavity will accelerate 2 MeV electrons from a 112 MHz SRF gun up to 22MeV. This paper provides an overview of the design, the project status and schedule of the 704 MHz 5-cell SRF for CeC PoP experiment.

  5. Influence of solvent on the morphology and photocatalytic properties of ZnS decorated CeO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Raubach, Cristiane W. Polastro, Lisânias; Ferrer, Mateus M.; Perrin, Andre; Perrin, Christiane; Albuquerque, Anderson R.; Buzolin, Prescila G. C.; Sambrano, Julio R.; Santana, Yuri B. V. de; Varela, José A.; Longo, Elson

    2014-06-07

    Herein, we report a theoretical and experimental study on the photocatalytic activity of CeO{sub 2} ZnS, and ZnS decorated CeO{sub 2} nanoparticles prepared by a microwave-assisted solvothermal method. Theoretical models were established to analyze electron transitions primarily at the interface between CeO{sub 2} and ZnS. As observed, the particle morphology strongly influenced the photocatalytic degradation of organic dye Rhodamine B. A model was proposed to rationalize the photocatalytic behavior of the prepared decorated systems taking into account different extrinsic and intrinsic defect distributions, including order-disorder effects at interfacial and intra-facial regions, and vacancy concentration.

  6. Enhanced Magneto-optic Kerr Effect and Magnetic Properties of CeY[subscript 2]Fe[subscript 5]O[subscript 12] Epitaxial Thin Films

    E-Print Network [OSTI]

    Kehlberger, Andreas

    The magnetic and magneto-optic properties of epitaxial CeY[subscript 2]Fe[subscript 5]O[subscript 12] (Ce ? YIG) and Y[subscript 3]Fe[subscript 5]O[subscript 12] (yttrium iron garnet or YIG) thin films grown by pulsed laser ...

  7. Thermal and magnetic properties of La-doped Ce1-yLayGe1.80 with 0

    E-Print Network [OSTI]

    Li, Jing

    Thermal and magnetic properties of La-doped Ce1-yLayGe1.80 with 0 Department of Physics, Temple University, Philadelphia, Pennsylvania 19122 J. A. Zan Jet Propulsion 2006 CeGex with 1.71 x 2.0 crystallizes in an orthorhombic structure and exhibits two magnetic

  8. Journal of Electron Spectroscopy and Related Phenomena 136 (2004) 1520 Temperature-dependence of Kondo resonance in CeSi2 studied by

    E-Print Network [OSTI]

    Oh, Se-Jung

    2004-01-01

    ). heavy-electron compounds [7]. In Ce-based heavy Fermion systems, the Kondo energy scale, , typically spectroscopy (RPES); Single impurity Anderson model (SIAM) 1. Introduction In the photoemission community, Ce photoemission (UPS) can reach this resolution limits currently. The most commonly used method to extract the 4f

  9. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; et al

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  10. Nanostructured Lanthanum Halides and CeBr3 for Nuclear Radiation and Detection

    SciTech Connect (OSTI)

    Paul Guss, Sanjoy Mukhopadhyay, Ron Guise, Ding Yuan

    2010-06-09

    Scintillator materials are used to detect, and in some cases identify, gamma rays. Higher performance scintillators are expensive, hard to manufacture, fragile, and sometimes require liquid nitrogen or cooling engines. But whereas lower-quality scintillators are cheap, easy to manufacture, and more rugged, their performance is lower. At issue: can the desirable qualities of high-and low-performance scintillators be combined to achieve better performance at lower cost? Preliminary experiments show that a LaF{sub 3}:Ce oleic acid-based nanocomposite exhibits a photopeak when exposed to {sup 137}Cs source gamma-radiation. The chemical synthesis of the cerium-doped lanthanum halide nanoparticles are scalable and large quantities of material can be produced at a time, unlike typical crystal growth processes such as the Bridgeman process. Using a polymer composite (Figure 1), produced by LANL, initial measurements of the unloaded and 8% LaF{sub 3}:Ce-loaded sample have been made using {sup 137}Cs sources. Figure 2 shows an energy spectrum acquired for CeF{sub 3}. The lighter plot is the measured polymer-only spectrum and the black plot is the spectrum from the nanocomposite scintillator. As the development of this material continues, the energy resolution is expected to improve and the photopeak-to-Compton ratio will become greater at higher loadings. These measurements show the expected Compton edge in the polymer-only sample, and the Compton edge and photo-peak expected in the nanophosphor composites that LANL has produced. Using a porous VYCORR with CdSe/ZnS core shell quantum dots, Letant has demonstrated that he has obtained signatures of the 241Am photopeak with energy resolution as good at NaI (Figure 3). We begin with the fact that CeBr{sub 3} crystals do not have a self-activity component as strong as the lanthanum halides. The radioactive 0.090% {sup 138}La component of lanthanum leads to significant self-activity, which will be a problem for very large detector volumes. Yet a significant strength of the nanostructure detector concept is the ability to create extremely large detector volumes by mixing nanoparticles into a transparent matrix. This would argue for use of nanoparticles other than lanthanum halides. Nanocomposites are easy to prepare; it is much less costly to use nanocomposites than to grow large whole crystals of these materials. The material can be fabricated at an industrial scale, further reducing cost. This material potentially offers the performance of $300/cc material (e.g., lanthanum bromide) at a cost of $1/cc. Because the material acts as a plastic, it is rugged and flexible, and can be made in large sheets, increasing the sensitivity of a detector using it. It would operate at ambient temperatures. Very large volumes of detector may be produced at greatly reduced cost, enhancing the non-proliferation posture of the nation for the same dollar value.

  11. Vortex Lattice Studies in CeCoIn? with H?c

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, P.; White, J. S.; Holmes, A. T.; Gerber, S.; Forgan, E. M.; Bianchi, A. D.; Kenzelmann, M.; Zolliker, M.; Gavilano, J. L.; Bauer, E. D.; et al

    2012-02-01

    We present small angle neutron scattering studies of the vortex lattice (VL) in CeCoIn? with magnetic fields applied parallel (H) to the antinodal [100] and nodal [110] directions. For H II 100], a single VL orientation is observed, while a 90° reorientation transition is found for H II [110]. For both field orientations and VL configurations we find a distorted hexagonal VL with an anisotropy, ?=2.0±0.05. The VL form factor shows strong Pauli paramagnetic effects similar to what have previously been reported for H II [001]. At high fields, above which the upper critical field (Hc2) becomes a first-order transition,more »an increased disordering of the VL is observed.« less

  12. Effect of aging upon CE and B and W control rod drives

    SciTech Connect (OSTI)

    Grove, E.; Gunther, W.

    1992-05-01

    The effect of aging upon the Babcock & Wilcox (B&W) and Combustion Engineering (CE) Control Rod Drive (CRD) systems has been evaluated as part of the US NRC Nuclear Plant Aging Research (NPAR) program. Operating experience data for the 1980--1990 time period was reviewed to identify predominant failure modes, causes, and effects. These results, in conjunction with an assessment of component materials and operating environment, conclude that both systems are susceptible to age degradation. System failures have resulted in significant plant effects, including power reductions, plant shutdowns, scrams, and Engineered Safety Feature (ESF) actuation. Current industry inspection and maintenance practices were assessed. Some of these practices effectively address aging, while others do not.

  13. Effect of aging upon CE and B and W control rod drives

    SciTech Connect (OSTI)

    Grove, E.; Gunther, W.

    1992-01-01

    The effect of aging upon the Babcock Wilcox (B W) and Combustion Engineering (CE) Control Rod Drive (CRD) systems has been evaluated as part of the US NRC Nuclear Plant Aging Research (NPAR) program. Operating experience data for the 1980--1990 time period was reviewed to identify predominant failure modes, causes, and effects. These results, in conjunction with an assessment of component materials and operating environment, conclude that both systems are susceptible to age degradation. System failures have resulted in significant plant effects, including power reductions, plant shutdowns, scrams, and Engineered Safety Feature (ESF) actuation. Current industry inspection and maintenance practices were assessed. Some of these practices effectively address aging, while others do not.

  14. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 Kmore »with an ordered moment of ?sat = 0.8 ?B for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.« less

  15. Novel CeO2-based Screen-Printed Potentiometric Electrodes for pH monitoring S. Betelu1*

    E-Print Network [OSTI]

    Boyer, Edmond

    in Europe to isolate and store radioactive waste. In France, the Callovo-Oxfordian formation (COx) is a possible candidate for nuclear waste storage. This work investigates the applicability of CeO2-based oxides or are anticipated in the COx formation during its evolution as radioactive waste repository due mainly

  16. The effect of Ce{sup 4+} incorporation on structural, morphological and photocatalytic characters of ZnO nanoparticles

    SciTech Connect (OSTI)

    Kannadasan, N.; Shanmugam, N. Cholan, S.; Sathishkumar, K.; Viruthagiri, G.; Poonguzhali, R.

    2014-11-15

    We report a simple chemical precipitation method for the preparation of undoped and cerium doped ZnO nanocrystals. The concentration of cerium in the products can be controlled in the range of 0.025–0.125 mol. The structure and chemical compositions of the products were characterized by X-ray diffraction, X-ray photoelectron spectroscopy; energy dispersive spectrum and Fourier transform infrared spectroscopy. The results demonstrate that Ce{sup 4+} ions were successfully incorporated into the lattice position of Zn{sup 2+} ions in ZnO. The morphology of the products was analyzed by field emission scanning electron microscopy and confirmed by high resolution transmission electron microscope analysis. The optical properties of the products were studied by ultraviolet–visible and room temperature photoluminescence measurements. The photoluminescence emission spectra of Ce-doped ZnO showed enhanced visible emissions as a result of 5d ? 4f transition of cerium. In particular, a novel photocatalytic activity of the products was assessed using methylene blue. The obtained result reveals that Ce-doped products show higher reduction efficiency for methylene blue than the undoped ZnO. - Highlights: • Nanocrystals of ZnO and ZnO:Ce{sup 4+} were grown. • XPS results confirmed the incorporated cerium in tetravalence. • PL emission exhibited 5d ? 4f transition on cerium doping. • Doped ZnO decolorizes MB faster than undoped ZnO.

  17. ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224

    E-Print Network [OSTI]

    Saskatchewan, University of

    GE 120 ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224 ABE 295 ABE 212 can be taken in either term. GE 124 MATH 110 MATH 124CHEM 115 PHYS 155 3RD YEAR GE 125 GE 110 COMM 102

  18. This form is downloadable from CEE Student Resources website: http://www.ce.washington.edu/students/undergrad.html H: Advising/Sr Yr Plan Sheet Rev.4/26/2012

    E-Print Network [OSTI]

    Eberhard, Marc O.

    This form is downloadable from CEE Student Resources website: http://www.ce.washington.edu/students/undergrad.html for the following year will be available online at www.ce.washington.edu/students/timeschedule.html. After meeting

  19. Local structure and polarization resistance of Ce doped SrMnO{sub 3} using extended x-ray fine structure analysis

    SciTech Connect (OSTI)

    Ryu, Jiseung; Lee, Heesoo, E-mail: heesoo@pusan.ac.kr [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2014-09-15

    Changes to the local structure of Sr and Mn atoms in Sr{sub 1?x}Ce{sub x}MnO{sub 3} (SCM) according to increasing Ce content and the effect of the structural change on the polarization resistance of SCM were investigated. The reduction of manganese was confirmed by the absorption edge shift of the Mn K-edge toward lower energies. The noise of oscillation in extended X-ray absorption fine structure k{sup 3}? data at Mn K-edge reveals the distortion of the local structure of Mn atoms, and the peak that indicates the bonding length of Mn-O, Sr/Ce, and -Mn decreased with the addition of Ce content in Fourier transformations of the Mn K-edge. The distortion of the local structure at Mn atoms was affected by the reduced manganese ions having larger ionic radii than Mn{sup 4+}. Meanwhile, few distortions of local atomic structures of Sr atoms occurred, and the average nearest neighboring distances of Sr-O and Sr-Mn are ?2.13?Å and ?2.95?Å, respectively. The average bonding lengths of the Ce-O and Ce-Mn increased because the ionic radius of substituted Ce ion with 12 coordination number is smaller than that of Sr ion, which leads the reduction of Mn ions and the distortion of local structure at the substituted A-site. Therefore, we reasoned that the distortion of the local atomic structure at Mn atoms in MnO{sub 6} and Ce atoms in A-site is one of the causes for interrupting oxygen ion transfers as a geometric factor, which results in an increase in the polarization resistance of SCM within the Ce composition range from 10?mol.?% to 30?mol.?%.

  20. Pressure-Induced Structural Phase Transition in CeNi: X-ray and Neutron Scattering Studies and First-Principles Calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mirmelstein, A.; Podlesnyak, Andrey A.; dos Santos, Antonio M.; Ehlers, Georg; Kerbel, O.; Matvienko, V.; Sefat, A. S.; Saporov, B.; Halder, G. J.; Tobin, J. G.

    2015-08-03

    The pressure-induced structural phase transition in the intermediate-valence compound CeNi has been investigated by x-ray and neutron powder diffraction techniques. It is shown that the structure of the pressure-induced CeNi phase (phases) can be described in terms of the Pnma space group. Equations of state for CeNi on both sides of the phase transition are derived and an approximate P-T phase diagram is suggested for Pmore »the phase transition.« less

  1. Q-dependence of the spin fluctuations in the intermediate valence compound CePd3

    SciTech Connect (OSTI)

    Fanelli, V. R.; Lawrence, J. M.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Thompson, J. D.; Booth, C. H.; Christianson, A. D.; Riseborough, P. S.

    2014-06-25

    We report inelastic neutron scattering experiments on a single crystal of the intermediate valence compound CePd3. At 300 K the magnetic scattering is quasielastic, with half-width G = 23 meV, and is independent of momentum transfer Q. At low temperature, the Q-averaged magnetic spectrum is inelastic, exhibiting a broad peak centered near E-max = 55 meV. These results, together with the temperature dependence of the susceptibility, 4f occupation number, and specific heat, can be fit by the Kondo/Anderson impurity model. The low temperature scattering near Emax, however, shows significant variations with Q, reflecting the coherence of the 4f lattice. The intensity is maximal at (1/2, 1/2, 0), intermediate at (1/2, 0, 0) and (0, 0, 0), and weak at (1/2, 1/2, 1/2). We discuss this Q-dependence in terms of current ideas about coherence in heavy fermion systems.

  2. Kondo hole behavior in Ce{sub 0.97} La{sub 0.03}Pd{sub 3}

    SciTech Connect (OSTI)

    Lawrence, J.M.; Graf, T.; Hundley, M.F.; Mandrus, D.; Thompson, J.D. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Lacerda, A.; Torikachvili, M.S. [National High Magnetic Field Laboratory, Pulse Facility, Los Alamos, New Mexico 87545 (United States)] [National High Magnetic Field Laboratory, Pulse Facility, Los Alamos, New Mexico 87545 (United States); Sarrao, J.L.; Fisk, Z. [National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32306 (United States)] [National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32306 (United States)

    1996-05-01

    We present results for the resistivity, the magnetoresistance, and the specific heat of Ce{sub 0.97}La{sub 0.03}Pd{sub 3} and CePd{sub 3}. The impurity contributions to these measurements follow the predictions of the single-impurity Kondo model for a Kondo temperature {ital T}{sub {ital L}}{approx_equal}65 K, assuming that the impurity behaves as a crystal-field split ({Gamma}{sub 7}) doublet. Assuming a {ital J}=5/2 impurity, the value of {ital T}{sub {ital L}} needed to fit these experiments varies from 65 to 125 K. The contribution to the susceptibility may be too small to be explained by the model. These results address whether the nonmagnetic impurity behaves as a Kondo hole. {copyright} {ital 1996 The American Physical Society.}

  3. Superconducting epitaxial thin films of CeNi{sub x}Bi{sub 2} with a bismuth square net structure

    SciTech Connect (OSTI)

    Buckow, Alexander; Kupka, Katharina; Retzlaff, Reiner; Kurian, Jose; Alff, Lambert [Institute of Materials Science, Technische Universitaet Darmstadt, 64287 Darmstadt (Germany)

    2012-10-15

    We have grown highly epitaxial and phase pure thin films of the arsenic-free pnictide compound CeNi{sub x}Bi{sub 2} on (100) MgO substrates by reactive molecular beam epitaxy (RMBE). X-ray diffraction and reflection high-energy electron diffraction of the films confirm the ZrCuSiAs structure with a Bi square net layer. Superconductivity was observed in magnetization and resistivity measurements for x= 0.75 to 0.93 in these CeNi{sub x}Bi{sub 2} thin films with the highest critical temperature of 4.05 K and a resistive transition width of 0.1 K for x= 0.86. Our results indicate that thin film deposition by RMBE provides a tool to synthesize high-quality pnictide superconductors of the novel 112 type.

  4. ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224

    E-Print Network [OSTI]

    Saskatchewan, University of

    GE 120 ME 227 CE 212 MATH 223 GE 210 CMPT 116 ABE 211CHE 210 GE 213# MATH 224 ABE 295 ABE 212Elective* Elective* AB E 311 ABE 313 ABE 312 GE 348#ABE 323 co-requisite ABE 327 HSS#@ HSS#@ ABE 324 GE 300# ABE 395 4TH YEAR ABE Elec* ABE Elec* ABE Elec*ABE 422 GE 449# Ag Elec* T.E.* T.E.* ABE Elec* Ag Elec

  5. Synthesis and properties of Sr2CeO4 blue emission powder phosphor for field emission displays

    E-Print Network [OSTI]

    Wang, Zhong L.

    oxalate NH4 2C2O4·H2O, Fisher, 99 % were used as raw materials. First, dissolving Sr NO3 2 and Ce NO3 3·6H Institute of Technology, Atlanta, Georgia 30332 Zhong Lin Wang School of Materials Science and Engineering phosphor, because wide band gap materials are required and the eye sensitivity is quite low in the blue

  6. JOURNAL DE PHYSIQUE Colloque C6, supplkment au no8, Tome 39, aotit 1978, page C6-781 PARAMAGNETIC SUSCEPTIBILITY OF UPt AND CePt

    E-Print Network [OSTI]

    Boyer, Edmond

    . While U and Ce both even superconduct in elemental form (under pressure) ; they can, too, support in an inert atmosphere. The UPt data were taken in a superconducting susceptometer with a measuring field

  7. Interpretation of In-Situ Tests (P.W. Mayne, October 2002, Georgia Tech: www.ce.gatech.edu/~geosys) FLOW PROPERTIES from PIEZOCONE DISSIPATION TESTS

    E-Print Network [OSTI]

    Mayne, Paul W.

    .ce.gatech.edu/~geosys) FLOW PROPERTIES from PIEZOCONE DISSIPATION TESTS Soils exhibit flow properties that control hydraulic, fat plastic clays may require 2 to 3 days for complete equalization. Representative dissipation curves

  8. Euclid's proposition III.35 says that if AB and CD are chords of a circle intersecting in a point E, then AE EB = CE ED.

    E-Print Network [OSTI]

    be the diameter passing through E. Then, a special case of the proposition is to show that AE · EB = FE · EG. In fact, it is enough to show this special case, because if AE · EB = FE · EG and if CE · ED = FE · EG, then by transitivity, AE · EB = CE · ED. Hence, we will proceed to prove that AE · EB = FE · EG. Let r be the radius

  9. Methanol conversion to light olefins over nanostructured CeAPSO-34 catalyst: Thermodynamic analysis of overall reactions and effect of template type on catalytic properties and performance

    SciTech Connect (OSTI)

    Aghamohammadi, Sogand; Haghighi, Mohammad; Charghand, Mojtaba

    2014-02-01

    Graphical abstract: In this research nanostructured CeAPSO-34 was synthesized to explore the effect of TEAOH and morpholine on its physiochemical properties and MTO performance. Prepared catalysts were characterized with XRD, FESEM, BET, FTIR and NH3-TPD techniques. The results indicated that the nature of the template determines the physiochemical properties of CeAPSO-34 due to different rate of crystal growth. The catalyst obtained by using morpholine showed longer life time as well as sustaining light olefins selectivity at higher values. Furthermore, a comprehensive thermodynamic analysis of overall reactions network was carried out to address the major channels of methanol to olefins conversion. - Highlights: • Introduction of Ce into SAPO-34 framework. • Comparison of CeAPSO-34 synthesized using morpholine and TEAOH. • The nature of the template determines the physiochemical properties of CeAPSO-34. • Morpholine enhances catalyst lifetime in MTO process. • Presenting a complete reaction network for MTO process. - Abstract: TEAOH and morpholine were employed in synthesis of nanostructured CeAPSO-34 molecular sieve and used in methanol to olefins conversion. Prepared samples were characterized by XRD, FESEM, EDX, BET, FTIR and NH{sub 3}-TPD techniques. XRD patterns reflected the higher crystallinity of the catalyst synthesized with morpholine. The FESEM results indicated that the nature of the template determines the morphology of nanostructured CeAPSO-34 due to different rate of crystal growth. There was a meaningful difference in the strength of both strong and weak acid sites for CeAPSO-34 catalysts synthesized with TEAOH and morpholine templates. The catalyst synthesized with morpholine showed higher desorption temperature of both weak and strong acid sites evidenced by NH{sub 3}-TPD characterization. The catalyst obtained using morpholine template had the longer lifetime and sustained desired light olefins at higher values. A comprehensive thermodynamic analysis of overall reactions network was carried out to address the major channels of methanol to olefins conversion.

  10. Crystalline Electric Field as a Probe for Long-Range Antiferromagnetic Order and Superconducting State of CeFeAsO1-xFx

    SciTech Connect (OSTI)

    Chi, Songxue; Adroja, D. T.; GUIDI, T.; Bewley, Robert I.; Li, Shiliang; Zhao, Jun; Lynn, J. W.; Brown, C. M.; Qiu, Y.; Chen, G. F,; Luo, J. L.; Wang, N. L.; Dai, Pengcheng

    2008-01-01

    We use inelastic neutron scattering to study the crystalline electric field (CEF) excitations of Ce{sup 3+} in CeFeAsO{sub 1-x}F{sub x} (x=0, 0.16). For nonsuperconducting CeFeAsO, the Ce CEF levels have three magnetic doublets in the paramagnetic state, but these doublets split into six singlets when the Fe ions order antiferromagnetically. For superconducting CeFeAsO{sub 0.84}F{sub 0.16} (T{sub c} = 41 K), where the static antiferromagnetic order is suppressed, the Ce CEF levels have three magnetic doublets at {h_bar}{sub {omega}} = 0, 18.7, 58.4 meV at all temperatures. Careful measurements of the intrinsic linewidth {Lambda} and the peak position of the 18.7 meV mode reveal a clear anomaly at T{sub c}, consistent with a strong enhancement of local magnetic susceptibility {chi}{double_prime}({h_bar}{sub {omega}}) below T{sub c}. These results suggest that CEF excitations in the rare-earth oxypnictides can be used as a probe of spin dynamics in the nearby FeAs planes.

  11. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    SciTech Connect (OSTI)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; Senanayake, Sanjaya D.

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  12. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Liu, Zongyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Yao, Siyu [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnson-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhao, Fuzhen [Brookhaven National Lab. (BNL), Upton, NY (United States); Michorczyk, Piotr [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Kubacka, Anna [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Stach, Eric A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fernandez-Garica, Marcos [State Univ. of New York Stony Brook, Stony Brook, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  13. A ferromagnetic quantum critical point in heavy-fermion iron oxypnictide CeFe{sub 1?x}Cr{sub x}PO

    SciTech Connect (OSTI)

    Okano, T.; Matoba, M.; Kamihara, Y.; Kitao, S.; Seto, M.; Atou, T.; Itoh, M.

    2015-05-07

    We report crystallographic and magnetic properties of layered iron oxypnictide CeFe{sub 1?x}Cr{sub x}PO (x?=?0.000–0.692). Interlayer distances between Ce{sub 2}O{sub 2} and (Fe{sub 1?x}Cr{sub x}){sub 2}P{sub 2} layers increase as a function of x, suggesting suppression of Kondo coupling among hybridized conducting orbitals and localized Ce 4f orbitals. CeFe{sub 1?x}Cr{sub x}PO (x?=?0.100–0.384) exhibits finite ferromagnetic transition temperatures (T{sub curie}) obtained by Arrott plots, although {sup 57}Fe Mössbauer spectra reveal paramagnetic Fe sublattice at T???4.2?K. These results indicate that the ferromagnetic phase transitions of samples are mainly due to Ce sublattice. For the samples with x???0.500, no ferromagnetic order is observed down to 2?K. These results verify that ferromagnetic quantum critical points of CeFe{sub 1?x}Cr{sub x}PO appear at 0.045???x???0.100 and 0.384???x???0.500.

  14. Antiferromagnetic Kondo lattice in the layered compound CePd1–xBi? and comparison to the superconductor LaPd1–xBi?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Fei; Wan, Xiangang; Phelan, Daniel; Stoumpos, Constantinos C.; Sturza, Mihai; Malliakas, Christos D.; Li, Qing'an; Han, Tian-Heng; Zhao, Qingbiao; Chung, Duck Young; et al

    2015-07-13

    The layered compound CePd1–xBi? with the tetragonal ZrCuSi?-type structure was obtained from excess Bi flux. Magnetic susceptibility data of CePd1–xBi? show an antiferromagnetic ordering below 6 K and are anisotropic along the c axis and the ab plane. The anisotropy is attributed to crystal-electric-field (CEF) effects and a CEF model which is able to describe the susceptibility data is given. An enhanced Sommerfeld coefficient ? of 0.191 J mol Ce?¹ K?² obtained from specific-heat measurement suggests a moderate Kondo effect in CePd1–xBi?. Other than the antiferromagnetic peak at 6 K, the resistivity curve shows a shoulderlike behavior around 75 Kmore »which could be attributed to the interplay between Kondo and CEF effects. Magnetoresistance and Hall-effect measurements suggest that the interplay reconstructs the Fermi-surface topology of CePd1–xBi? around 75 K. Electronic structure calculations reveal that the Pd vacancies are important to the magnetic structure and enhance the CEF effects which quench the orbital moment of Ce at low temperatures.« less

  15. SESAME 96170, a solid-liquid equation of state for CeO2

    SciTech Connect (OSTI)

    Chisolm, Eric D.

    2014-05-02

    I describe an equation of state (EOS) for the low-pressure solid phase and liquid phase of cerium (IV) oxide, CeO2. The models and parameters used to calculate the EOS are presented in detail, and I compare with data for the full-density crystal. Hugoniot data are available only for high-porosity powders, and I discuss difficulties in comparing with such data. I have constructed SESAME 96170, an EOS for cerium (IV) oxide that includes the ambient solid and liquid phases. The EOS extends over the full standard SESAME range, but should not be used at low temperatures and high densities because of the lack of a high-pressure solid phase. I have described the models used to compute the three terms of the EOS (cold curve, nuclear, and thermal electronic), and I have given the parameters used in the models. They were determined by comparison with experimental data at P = 1 atm, including the constant-pressure specific heat, coefficient of thermal expansion, and melting and boiling points. The EOS compares well with data in its intended range of validity, but the presence of high-frequency optical modes in its phonon spectrum limits the agreement of our models with thermal data. The next step is to construct a multiphase EOS that includes the low- and high-pressure solid phases and the liquid. The DAC data from Duclos will most strongly constrain the parameters of the high-pressure solid. A remaining issue is the comparison of the crystal-density EOS with experimental Hugoniot data, which are taken at much lower initial data because the samples are porous powders. A satisfactory means of modeling porosity, allowing comparison of theory and experiment, has not yet been produced.

  16. HL Power Geothermal Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County,SolarFERCInformation 3.1 - Amendments to6EHDOT

  17. HL Green Power Co | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen River Power Co LtdGuntherGreen Power Co Jump to:

  18. HL Power Company | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam: Energy Resources Jump to:Wind FarmCompany Jump to:

  19. Structural and magnetic properties in the polymorphs of CeRh{sub 0.5}Ge{sub 1.5}

    SciTech Connect (OSTI)

    Kalsi, Deepti; Subbarao, Udumula [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India); Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, R-5 Shed, B.A.R.C Campus, Trombay, Mumbai-400085 (India); Peter, Sebastian C., E-mail: sebastiancp@jncasr.ac.in [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India)

    2014-04-01

    We investigate the structural and magnetic properties in the polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5}. Depending upon the starting materials, and the slightly different synthesis method, we find that CeRh{sub 0.5}Ge{sub 1.5} compound exists in two different space groups. The first compound, ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in tetragonal ?-ThSi{sub 2} structure type in space group I4{sub 1}/amd with lattice parameters, a=4.2034(6) Å and c=14.770(3) Å. In this structure, the cerium atoms occupy the position between the Rh/Ge tetrahedral layers. On the other hand, the second compound, namely ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in the AlB{sub 2} type hexagonal structure in space group P6/mmm, with lattice parameters, a=4.2615(7) Å and c=4.1813(9) Å. The crystal structure of ?-CeRh{sub 0.5}Ge{sub 1.5} consists of two dimensional Rh/Ge hexagonal units and the cerium atoms are sandwiched between them. Magnetization studies exhibit magnetic ordering, as evident from a sharp peak in the plot of magnetic susceptibility measured as a function of temperature in a fixed magnetic field, in ?-CeRh{sub 0.5}Ge{sub 1.5} and ?-CeRh{sub 0.5}Ge{sub 1.5} at 3.6 K and 12 K, respectively. Structural and magnetic properties of both compounds are presented and discussed here. - Graphical abstract: Two polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5} in the ?-ThSi{sub 2} and AlB{sub 2} structure types were synthesized by arc melting. The magnetic measurements of both CeRh{sub 0.5}Ge{sub 1.5} phases suggest spin-glass behavior. - Highlights: • A new compound CeRh{sub 0.5}Ge{sub 1.5} in two difference phases was synthesized by arc melting. • The crystal structure of both compounds was determined from the single crystal XRD. • Isothermal relaxation measurements suggesting spin-glass like anomalies in both phases.

  20. Hierarchical heterogeneity at the CeOx-TiO? interface: Electronic and geometric structural influence on the photocatalytic activity of oxide on oxide nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Si [Brookhaven National Lab. (BNL), Upton, NY (United States); Nguyen-Phan, Thuy-Duong [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnston-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Barrio, Laura [CSIC - Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Sallis, Shawn [Binghamton Univ., NY (United States); Arena, Dario A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Kundu, Shankhamala [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Piper, Louis F. J. [Binghamton Univ., NY (United States); Stach, Eric A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Polyansky, Dmitry E. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fujita, Etsuko [Brookhaven National Lab. (BNL), Upton, NY (United States); Rodriguez, José A. [Brookhaven National Lab. (BNL), Upton, NY (United States); CSIC - Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-27

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravel the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.

  1. Hierarchical Heterogeneity at the CeO x –TiO 2 Interface: Electronic and Geometric Structural Influence on the Photocatalytic Activity of Oxide on Oxide Nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Si; Nguyen-Phan, Thuy-Duong; Johnston-Peck, Aaron C.; Barrio, Laura; Sallis, Shawn; Arena, Dario A.; Kundu, Shankhamala; Xu, Wenqian; Piper, Louis F. J.; Stach, Eric A.; et al

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravelmore »the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.« less

  2. Hierarchical heterogeneity at the CeOx-TiO? interface: Electronic and geometric structural influence on the photocatalytic activity of oxide on oxide nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    None

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravelmore »the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.« less

  3. Fabrication and microstructure of cerium doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics by solid-state reaction method

    SciTech Connect (OSTI)

    Li, Junlang; Xu, Jian; Shi, Ying; Qi, Hongfang; Xie, Jianjun; Lei, Fang

    2014-07-01

    Highlights: • We fabricate Ce doped lutetium aluminum garnet ceramics by solid-state method. • The raw materials include Lu{sub 2}O{sub 3} nanopowders synthesized by co-precipitation method. • The density of the transparent ceramics reach 99.7% of the theoretical value. • The optical transmittance of the bulk ceramic at 550 nm was 57.48%. • Some scattering centers decrease the optical characteristic of the ceramic. - Abstract: Polycrystalline Ce{sup 3+} doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics fabricated by one step solid-state reaction method using synthetic nano-sized Lu{sub 2}O{sub 3}, commercial ?-Al{sub 2}O{sub 3} and CeO{sub 2} powders were investigated in this paper. The green compacts shaped by the mixed powders were successfully densified into Ce:LuAG transparent ceramics after vacuum sintering at 1750 °C for 10 h. The in-line optical transmittance of the Ce:LuAG ceramic made by home-made Lu{sub 2}O{sub 3} powders could reach 57.48% at 550 nm, which was higher than that of the ceramic made by commercial Lu{sub 2}O{sub 3} powders (22.96%). The microstructure observation showed that light scattering centers caused by micro-pores, aluminum segregation and refraction index inhomogeneities induced the decrease of optical transparency of the Ce:LuAG ceramics, which should be removed and optimized in the future work.

  4. Comparative Gamma Spectroscopy with SrI2(Eu), GYGAG(Ce) and Bi-loaded Plastic Scintillators

    SciTech Connect (OSTI)

    Cherepy, N J

    2010-11-19

    We are developing new scintillator materials that offer potential for high resolution gamma ray spectroscopy at low cost. Single crystal SrI{sub 2}(Eu) offers {approx}3% resolution at 662 keV, in sizes of {approx}1 in{sup 3}. We have developed ceramics processing technology allowing us to achieve cubic inch scale transparent ceramic scintillators offering gamma spectroscopy performance superior to NaI(Tl). We fabricated a bismuth-loaded plastic scintillator that demonstrates energy resolution of {approx}8% at 662 keV in small sizes. Gamma ray spectroscopy can be used to identify the presence of weak radioactive sources within natural background. The ability to discriminate close-lying spectral lines is strongly dependent upon the energy resolution of the detector. In addition to excellent energy resolution, large volume detectors are needed to acquire sufficient events, for example, to identify a radioactive anomaly moving past a detector. We have employed a 'directed search' methodology for identifying potential scintillator materials candidates, resulting in the discovery of Europium-doped Strontium Iodide, SrI{sub 2}(Eu), Cerium-doped Gadolinium Garnet, GYGAG(Ce), and Bismuth-loaded Polymers. These scintillators possess very low self-radioactivity, offer energy resolution of 3-8% at 662 keV, and have potential to be grown cost-effectively to sizes similar to the most widely deployed gamma spectroscopy scintillator, Thallium-doped Sodium Iodide, NaI(Tl). In this study, gamma ray spectra of a variety of sources, were obtained employing SrI{sub 2}(Eu), GYGAG(Ce), Bi-loaded polymers, LaBr{sub 3}(Ce), and NaI(Tl). The effects of detector size, energy resolution, and background radioactivity (including self-radioactivity) on the ability to distinguish weak sources is quantified, based on a simple model, and qualitatively compared to laboratory data.

  5. Cellulase for commodity products from cellulosic biomass Michael E Himmel*?, Mark F Ruth*1 and Charles E Wymans

    E-Print Network [OSTI]

    California at Riverside, University of

    dramatically over the past two decades, to the point where the fuel is now competitive for blending with gasoline to reduce greenhouse gas emissions, enhance octane, extend the gasoline supply, and promote more

  6. Fuel Etanol from Cellulosic Biomass LEE R. LYND, JANET H. CusHmAN, ROBERTA J. NICHOLS, CHARLES E. WYMAN

    E-Print Network [OSTI]

    California at Riverside, University of

    in the United States, petroleum supplies the largest share of total energy used and has the highest fraction, global climate change, bal- ance oftrade, and energy security. Energy balance, feed- stock supply from cellulosic bio- mass. The focus is on the use of ethanol as the primary fuel component on a scale

  7. Generation and reactivity of putative support systems, Ce-Al neutral binary oxide nanoclusters: CO oxidation and C–H bond activation

    SciTech Connect (OSTI)

    Wang, Zhe-Chen; Yin, Shi; Bernstein, Elliot R.

    2013-11-21

    Both ceria (CeO{sub 2}) and alumina (Al{sub 2}O{sub 3}) are very important catalyst support materials. Neutral binary oxide nanoclusters (NBONCs), Ce{sub x}Al{sub y}O{sub z}, are generated and detected in the gas phase and their reactivity with carbon monoxide (CO) and butane (C{sub 4}H{sub 10}) is studied. The very active species CeAlO{sub 4}{sup •} can react with CO and butane via O atom transfer (OAT) and H atom transfer (HAT), respectively. Other Ce{sub x}Al{sub y}O{sub z} NBONCs do not show reactivities toward CO and C{sub 4}H{sub 10}. The structures, as well as the reactivities, of Ce{sub x}Al{sub y}O{sub z} NBONCs are studied theoretically employing density functional theory (DFT) calculations. The ground state CeAlO{sub 4}{sup •} NBONC possesses a kite-shaped structure with an O{sub t}CeO{sub b}O{sub b}AlO{sub t} configuration (O{sub t}, terminal oxygen; O{sub b}, bridging oxygen). An unpaired electron is localized on the O{sub t} atom of the AlO{sub t} moiety rather than the CeO{sub t} moiety: this O{sub t} centered radical moiety plays a very important role for the reactivity of the CeAlO{sub 4}{sup •} NBONC. The reactivities of Ce{sub 2}O{sub 4}, CeAlO{sub 4}{sup •}, and Al{sub 2}O{sub 4} toward CO are compared, emphasizing the importance of a spin-localized terminal oxygen for these reactions. Intramolecular charge distributions do not appear to play a role in the reactivities of these neutral clusters, but could be important for charged isoelectronic BONCs. DFT studies show that the reaction of CeAlO{sub 4}{sup •} with C{sub 4}H{sub 10} to form the CeAlO{sub 4}H•C{sub 4}H{sub 9}{sup •} encounter complex is barrierless. While HAT processes have been previously characterized for cationic and anionic oxide clusters, the reported study is the first observation of a HAT process supported by a ground state neutral oxide cluster. Mechanisms for catalytic oxidation of CO over surfaces of Al{sub x}O{sub y}/M{sub m}O{sub n} or M{sub m}O{sub n}/Al{sub x}O{sub y} materials are proposed consistent with the presented experimental and theoretical results.

  8. Electronic and optical properties of layered RE{sub 2}Ti{sub 2}O{sub 7} (RE = Ce and Pr) from first principles

    SciTech Connect (OSTI)

    Sayede, A.; Khenata, R.; Chahed, A.; Benhelal, O.

    2013-05-07

    We have studied the structural and electronic properties of Ce{sub 2}Ti{sub 2}O{sub 7} (CeTO) and Pr{sub 2}Ti{sub 2}O{sub 7} (PrTO) by first-principles density functional theory calculations. The computed structural parameters are in fairly good agreement with the available experimental findings. Band structure calculations using the GGA+U approach predict an insulating ground state for the herein studied compounds. The insulating band gaps of 2.00 eV and 2.83 eV are found for CeTO and PrTO, respectively. The analysis of the density of states reveals that the strongly localized RE 4f levels act as charge-trapping sites, predicting a lower photocatalytic activity for CeTO. We have also calculated the optical properties for both CeTO and PrTO. Based on these properties, it is predicted that these titanates are insensitive to ultra-violet radiation, while they are more sensitive to frequencies of the radiation in visible and early UV regions.

  9. Superior performance of Ni–W–Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernández-García, Marcos; Senanayake, Sanjaya D.; et al

    2014-11-26

    In this study, the ethanol steam reforming (ESR) reaction was examined over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  10. Rapid Microwave Preparation of Highly Efficient Ce[superscript 3+]-Substituted Garnet Phosphors for Solid State White Lighting

    SciTech Connect (OSTI)

    Birkel, Alexander; Denault, Kristin A.; George, Nathan C.; Doll, Courtney E.; Héry, Bathylle; Mikhailovsky, Alexander A.; Birkel, Christina S.; Hong, Byung-Chul; Seshadri, Ram (UCSB); (Mitsubishi)

    2012-04-30

    Ce{sup 3+}-substituted aluminum garnet compounds of yttrium (Y{sub 3}Al{sub 5}O{sub 12}) and lutetium (Lu{sub 3}Al{sub 5}O{sub 12}) - both important compounds in the generation of (In,Ga)N-based solid state white lighting - have been prepared using a simple microwave heating technique involving the use of a microwave susceptor to provide the initial heat source. Carbon used as the susceptor additionally creates a reducing atmosphere around the sample that helps stabilize the desired luminescent compound. High quality, phase-pure materials are prepared within a fraction of the time and using a fraction of the energy required in a conventional ceramic preparation; the microwave technique allows for a reduction of about 95% in preparation time, making it possible to obtain phase pure, Ce{sup 3+}-substituted garnet compounds in under 20 min of reaction time. It is estimated that the overall reduction in energy compared with ceramic routes as practiced in the lab is close to 99%. Conventionally prepared material is compared with material prepared using microwave heating in terms of structure, morphology, and optical properties, including quantum yield and thermal quenching of luminescence. Finally, the microwave-prepared compounds have been incorporated into light-emitting diode 'caps' to test their performance characteristics in a real device, in terms of their photon efficiency and color coordinates.

  11. CE IGCC repowering project: Clean Coal II Project. Annual report, 1 January, 1992--31 December, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    CE is participating in a $270 million coal gasification combined cycle repowering project that will provide a nominal 60 MW of electricity to City, Water, light and Power (CWL and P) in Springfield, Illinois. The IGCC system will consist of CE`s air-blown entrained flow two-stage gasifier; an advanced hot gas cleanup system; a combustion turbine adapted to use low-Btu gas: and all necessary coal handling equipment. The project is currently in the second budget period of five. The major activities during this budgeted period are: Establishment of an approved for design (AFD) engineering package; development of a detailed cost estimate; resolution of project business issues; CWL and P renewal and replacement activities; and application for environmental air permits. The Project Management Plan was updated. The conceptual design of the plant was completed and a cost and schedule baseline for the project was established previously in Budget Period One. This information was used to establish AFD Process Flow Diagrams, Piping and Instrument Diagrams, Equipment Data Sheets, material take offs, site modification plans and other information necessary to develop a plus or minus 20% cost estimate. Environmental permitting activities are continuing. At the end of 1992 the major activities remaining for Budget Period two is to finish the cost estimate and complete the Continuation Request Documents.

  12. A Prototype of LaBr3:Ce in situ Gamma-Ray Spectrometer for Marine Environmental Monitoring

    E-Print Network [OSTI]

    Zeng, Zhi; Pan, Xingyu; Xue, Tao; Ma, Hao; Yi, Hongchang; Cheng, Jianping

    2015-01-01

    A prototype of LaBr3:Ce in situ gamma-ray spectrometer for marine environmental monitoring is developed and applied for in situ measurement. A 3-inch LaBr3:Ce scintillator is used in the detector, and a digital pulse process electronics is chosen as the pulse height analyzer. For this prototype, the energy response of the spectrometer is linear and the energy resolution of 662keV is 2.6% (much better than NaI). With the measurement of the prototype in a water tank filled with 137Cs, the detect efficiency for 137Cs is (0.288 0.01)cps/(Bq/L), which is close to the result of Monte Carlo simulation, 0.283cps/(Bq/L). With this measurement, the MDAC for 137Cs in one hour has been calculated to 0.78Bq/L, better than that of NaI(Tl) in-situ gamma spectrometer, which is ~1.0Bq/L.

  13. A Prototype of LaBr3:Ce in situ Gamma-Ray Spectrometer for Marine Environmental Monitoring

    E-Print Network [OSTI]

    Ming Zeng; Zhi Zeng; Jirong Cang; Xingyu Pan; Tao Xue; Hao Ma; Hongchang Yi; Jianping Cheng

    2015-04-20

    A prototype of LaBr3:Ce in situ gamma-ray spectrometer for marine environmental monitoring is developed and applied for in situ measurement. A 3-inch LaBr3:Ce scintillator is used in the detector, and a digital pulse process electronics is chosen as the pulse height analyzer. For this prototype, the energy response of the spectrometer is linear and the energy resolution of 662keV is 2.6% (much better than NaI). With the measurement of the prototype in a water tank filled with 137Cs, the detect efficiency for 137Cs is (0.288 0.01)cps/(Bq/L), which is close to the result of Monte Carlo simulation, 0.283cps/(Bq/L). With this measurement, the MDAC for 137Cs in one hour has been calculated to 0.78Bq/L, better than that of NaI(Tl) in-situ gamma spectrometer, which is ~1.0Bq/L.

  14. Chemical Reduction of Nd1.85Ce0.15CuO4??Powders in Supercritical Sodium Ammonia Solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dias, Yasmin; Wang, Hui; Zhou, Haiqing; Lin, Feng; Lan, Yucheng

    2015-01-01

    Nd1.85Ce0.15CuO4??powders are chemically reduced in supercritical sodium ammonia solutions from room temperature to 350°C. The crystallographic structure of the reduced powders is investigated from Rietveld refinement of X-ray powder diffraction. The atomic positions are maintained constant within experimental errors while temperature factors of all atoms increase significantly after the chemical treatments, especially of Nd/Ce atoms. The ammonothermally reduced Nd1.85Ce0.15CuO4??powders show diamagnetic below 24?K which is contributed to the lower oxygen content and higher temperature factors of atoms in the treated compound. The ammonothermal method paves a new way to reduce oxides in supercritical solutions near room temperature.

  15. Chemical Reduction of Nd 1.85 Ce 0.15 CuO 4? ? Powders in Supercritical Sodium Ammonia Solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dias, Yasmin; Wang, Hui; Zhou, Haiqing; Lin, Feng; Lan, Yucheng

    2015-01-01

    Nd 1.85 Ce 0.15 CuO 4? ? powders are chemically reduced in supercritical sodium ammonia solutions from room temperature to 350°C. The crystallographic structure of the reduced powders is investigated from Rietveld refinement of X-ray powder diffraction. The atomic positions are maintained constant within experimental errors while temperature factors of all atoms increase significantly after the chemical treatments, especially of Nd/Ce atoms. The ammonothermally reduced Nd 1.85 Ce 0.15 CuO 4? ? powders show diamagnetic below 24?K which is contributed to the lower oxygen content and higher temperature factors of atoms in the treated compound.more »The ammonothermal method paves a new way to reduce oxides in supercritical solutions near room temperature. « less

  16. Thiolate ligands as a double-edged sword for CO oxidation on CeO2-supported Au25(SR)18 nanoclusters

    SciTech Connect (OSTI)

    Wu, Zili [ORNL; Jiang, Deen [ORNL; Mann, Amanda K [ORNL; Mullins, David R [ORNL; Qiao, Zhen-an [University of Tennessee, Knoxville (UTK); Allard Jr, Lawrence Frederick [ORNL; Zeng, Chenjie [Carnegie Mellon University (CMU); Jin, Rongchao [Carnegie Mellon University (CMU); Overbury, Steven {Steve} H [ORNL

    2014-01-01

    The effect of thiolate ligands was explored on the catalysis of CeO2-rod supported Au25(SR)18 (SR = -SCH2-CH2-Ph) by using CO oxidation as a probe reaction. Reaction kinetic tests, in situ IR and X-ray absorption spectroscopy, and density functional theory (DFT) were employed to understand how the thiolate ligands affect the nature of active sites, activation of CO and O2, as well as the reaction mechanism and kinetics. The intact Au25(SR)18 on CeO2-rod is found not able to adsorb CO. Only when the thiolate ligands are partially removed, starting from the interface between Au25(SR)18 and CeO2 at temperatures of 423 K and above, can the adsorption of CO be observed by IR. DFT calculations suggest that CO adsorbs favorably on the exposed gold atoms. Accordingly, the CO oxidation light-off temperature shifts to lower temperature. Several types of Au sites are probed by IR of CO adsorption during the ligand removal process. The cationic Au sites (charged between 0 and +1) are found to play the major role for low temperature CO oxidation. Similar activation energy and reaction rate are found for CO oxidation on differently treated Au25(SR)18/CeO2-rod, suggesting a simple site-blocking effect of the thiolate ligands in Au nanoclusters catalysis. Isotopic labelling experiments clearly indicate that CO oxidation on Au25(SR)18/CeO2-rod proceeds predominantly via the redox mechanism where CeO2 activates O2 while CO is activated on the de-thiolated gold sites. These results points to a double-edged sword role played by the thiolate ligands on Au25 nanoclusters for CO oxidation.

  17. Reactivity of pulverized coals during combustion catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Gong, Xuzhong; Guo, Zhancheng; Wang, Zhi

    2010-02-15

    Effects of CeO{sub 2} and Fe{sub 2}O{sub 3} on combustion reactivity of several fuels, including three ranks of coals, graphite and anthracite chars, were investigated using thermo-gravimetric analyzer. The results indicated that the combustion reactivity of all the samples except lignite was improved with CeO{sub 2} or Fe{sub 2}O{sub 3} addition. It was interesting to note that the ignition temperatures of anthracite were decreased by 50 C and 53 C, respectively, with CeO{sub 2} and Fe{sub 2}O{sub 3} addition and that its combustion rates were increased to 15.4%/min and 12.2%/min. Ignition temperatures of lignite with CeO{sub 2} and Fe{sub 2}O{sub 3} addition were 250 C and 226 C, and the combustion rates were 12.8% and 19.3%/min, respectively. When compared with those of lignite without catalysts, no obvious catalytic effects of the two catalysts on its combustion reactivity were revealed. The results from the combustion of the three rank pulverized coals catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3} indicated significant effects of the two catalysts on fixed carbon combustion. And it was found that the higher the fuel rank, the better the catalytic effect. The results of combustion from two kinds of anthracite chars showed obvious effects of anthracite pyrolysis catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3} on its combustion reactivity. (author)

  18. Magnetic hardening of Ce1+xFe11–yCoyTi with ThMn12 structure by melt spinning

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Chen; Sun, Kewei; Pinkerton, Frederick E.; Kramer, M. J.

    2015-04-15

    A recent study on the intrinsic magnetic properties of CeFe11–yCoyTi has revealed that substituting one Co for Fe retains the favorable magnetocrystalline anisotropy Ha found in the ternary Fe end member, while enhancing the Curie temperature Tc and saturation magnetization 4?Ms. These findings warrant further optimization around Co substitution y = 1 to try to exploit the hard magnetic properties of these Ce-based magnets. Both Ce and Co concentrations in Ce1+xFe11–yCoyTi have been optimized in the range of x = 0 – 0.2 and y = 0 –1.5. It was found that Co substitution effectively enhances all hard magnetic properties,more »although the values are still lower than those predicted from the intrinsic magnetic properties. Specifically, Tc increases from 210 °C to 285 – 350 °C; 4?M19 (magnetization at 19 kOe) from 8.9 kG to 10.5 – 11.5 kG, remanence Br from 3.1 kG to 4.1 – 4.5 kG, and most importantly, Hci from 1.1 kOe to 1.5 kOe. As a result, the room temperature energy product (BH)max has been increased by over 100% from 0.7 MGOe in Ce1.1Fe11Ti to 1.5 MGOe in Ce1.05Fe9.75Co1.25Ti. Microscopy analysis indicates that the addition of Co refines the grain size and promotes chemical homogeneity at the microscopic scale. As a result, the beneficial effect of Co on the microstructure contributes to the improved hard magnetic properties.« less

  19. Lu.sub.1-xI.sub.3:Ce.sub.x-a scintillator for gamma-ray spectroscopy and time-of-flight pet

    DOE Patents [OSTI]

    Shah, Kanai S. (Newton, MA)

    2008-02-12

    The present invention includes very fast scintillator materials including lutetium iodide doped with Cerium (Lu.sub.1-xI.sub.3:Ce.sub.x; LuI.sub.3:Ce). The LuI.sub.3 scintillator material has surprisingly good characteristics including high light output, high gamma-ray stopping efficiency, fast response, low cost, good proportionality, and minimal afterglow that the material is useful for gamma-ray spectroscopy, medical imaging, nuclear and high energy physics research, diffraction, non-destructive testing, nuclear treaty verification and safeguards, and geological exploration.

  20. Electronic and thermoelectric properties of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} computed with density functional theory with on-site Coulomb interaction correction

    SciTech Connect (OSTI)

    Vo, Trinh; Allmen, Paul von; Huang, Chen-Kuo; Ma, James; Bux, Sabah; Fleurial, Jean-Pierre [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109 (United States)

    2014-10-07

    The electronic properties and Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are computed using Density Functional Theory with on-site Coulomb interaction correction. We found that the Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are almost equal at temperatures larger than the Curie temperature of Ce{sub 3}Te{sub 4}, and in good agreement with the measurements reported by May et al. [Phys. Rev. B 86, 035135 (2012)]. At temperatures below the Curie temperature, the Seebeck coefficient of Ce{sub 3}Te{sub 4} increases due to the ferromagnetic ordering, which leads the f-electron of Ce to contribute to the Seebeck coefficient in the relevant range of electron concentration.

  1. Magnetic properties of CeFe11-xCoxTi with ThMn12 structure

    SciTech Connect (OSTI)

    Zhou, C; Pinkerton, FE; Herbst, JF

    2014-05-07

    A series of novel alloys CeFe11-xCoxTi (0 <= x <= 11) with ThMn12 structure has been successfully prepared by melt-spinning. The Curie temperature T-c increases with Co content x, reaching a maximum of 689 degrees C at x = 9 and declining to 664 degrees C at complete Co filling (x = 11). The room temperature saturation magnetization 4 pi M-s and magnetocrystalline anisotropy H-a have been estimated by fitting the first quadrant demagnetization curve with the Stoner-Wohlfarth model. 4 pi M-s first increases with increasing Co up to x = 3, then decrease. H-a has a complex dependence on Co content, which is indicative of a change in the easy magnetization direction from axis to plane and back as the Co content increases. (C) 2014 AIP Publishing LLC.

  2. Low pressure CO? hydrogenation to methanol over gold nanoparticles activated on a CeOx/TiO? interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Xiaofang; Boscoboinik, J. Anibal; Kattel, Shyam; Senanayake, Sanjaya D.; Nie, Xiaowa; Graciani, Jesus; Rodriguez, Jose A.; Liu, Ping; Stacchiola, Dario J.; Chen, Jingguang G.

    2015-07-28

    Capture and recycling of CO? into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO? is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal–oxide interface of Au nanoparticles anchored and stabilized on a CeOx/TiO? substrate generates active centers formore »CO? adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. In conclusion, this study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO? hydrogenation.« less

  3. Data:F3d511d9-6321-49ce-b5b2-a0d21fd28d52 | Open Energy Information

    Open Energy Info (EERE)

    d9-6321-49ce-b5b2-a0d21fd28d52 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1....

  4. Inverse magnetocaloric effect in Ce(Fe{sub 0.96}Ru{sub 0.04}){sub 2}: Effect of fast neutron irradiation

    SciTech Connect (OSTI)

    Dube, V.; Mishra, P. K.; Prajapat, C. L.; Singh, M. R.; Ravikumar, G.; Rajarajan, A. K.; Sastry, P. U.; Thakare, S. V.

    2013-02-05

    We have shown the effect of fast neutron irradiation on the magnetic phase transition and magnetocaloric effect (MCE) in a doped Ce(Fe{sub 0.96}Ru{sub 0.04}){sub 2}, intermettalic. We show that this leads to suppression of MCE and a to a disordered ferromagnetic phase.

  5. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³? concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themore »active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  6. NEAFS CE-DNA Workshop (Butler and McCord) Sept 29-30, 2004 http://www.cstl.nist.gov/biotech/strbase/NISTpub.htm 1

    E-Print Network [OSTI]

    NEAFS CE-DNA Workshop (Butler and McCord) Sept 29-30, 2004 http://www.cstl.nist.gov/biotech Acids Res. (1999) 27: e36 Capillary Arrays http://www.cstl.nist.gov/biotech/strbase/tech.htm Ways 29-30, 2004 http://www.cstl.nist.gov/biotech/strbase/NISTpub.htm 2 Capillary Array Electrophoresis

  7. www.ce.washington.edu 201 More Hall, Box 352700, Seattle, WA 98195 Phone (206) 543-5092 ceadvice@uw.edu CIVIL & ENVIRONMENTAL ENGINEERING

    E-Print Network [OSTI]

    www.ce.washington.edu 201 More Hall, Box 352700, Seattle, WA 98195 Phone (206) 543-5092 ceadvice. To apply for the Departmental Honors program: Complete the Honors Departmental invitation form at http://depts.washington to make the course more rigorous and extensive. Download the Ad Hoc Honors form at http://depts.washington

  8. 44 This arTicle has been peer-reviewed. Computing in SCienCe & engineering P e t a s c a l e

    E-Print Network [OSTI]

    Starck, Jean-Luc

    44 This arTicle has been peer-reviewed. Computing in SCienCe & engineering P e t a s c a l e C o m Jalal M. Fadili National Graduate School of Engineering and Research, Caen, France Jean-Luc Starck to the world economy should they be solved, as well as the ex- treme intellectual kick such a solution would

  9. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Ducho?, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; et al

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³? concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themore »active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  10. Journal of Solid State Chemistry 177 (2004) 39954000 Microwave dielectric properties of BaO2CeO2nTiO2 ceramics

    E-Print Network [OSTI]

    Osnabrück, Universität

    2004-01-01

    ÀnTiO2 ceramics H. Sreemoolanadhana,1 , M.T. Sebastiana,Ã, R. Ratheeshb,2 , R. Blachnikb , M. Woehleckec , B. Schneiderc , M. Neumannc , P. Mohanand a Regional Research Laboratory, Ceramic Technology online 6 October 2004 Abstract The BaO­2CeO2­nTiO2 ceramics with n ¼ 3; 4 and 5 have been prepared

  11. High Catalytic Activity of Au/CeOx/TiO2(110) Controlled by the Nature of the Mixed Metal Oxide at the Nanometer Level

    SciTech Connect (OSTI)

    Park, J.; Graciani, J; Evans, J; Stacchiola, D; Ma, S; Liu, P; Nambu, A; Sanz, J; Hrbek, J; et. al.

    2009-01-01

    Mixed-metal oxides play a very important role in many areas of chemistry, physics, materials science, and geochemistry. Recently, there has been a strong interest in understanding phenomena associated with the deposition of oxide nanoparticles on the surface of a second (host) oxide. Here, scanning tunneling microscopy, photoemission, and density-functional calculations are used to study the behavior of ceria nanoparticles deposited on a TiO2(110) surface. The titania substrate imposes nontypical coordination modes on the ceria nanoparticles. In the CeOx/TiO2(110) systems, the Ce cations adopt an structural geometry and an oxidation state (+3) that are quite different from those seen in bulk ceria or for ceria nanoparticles deposited on metal substrates. The increase in the stability of the Ce3+ oxidation state leads to an enhancement in the chemical and catalytic activity of the ceria nanoparticles. The codeposition of ceria and gold nanoparticles on a TiO2(110) substrate generates catalysts with an extremely high activity for the production of hydrogen through the water-gas shift reaction (H2O + CO ? H2 + CO2) or for the oxidation of carbon monoxide (2CO + O2 ? 2CO2). The enhanced stability of the Ce3+ state is an example of structural promotion in catalysis described here on the atomic level. The exploration of mixed-metal oxides at the nanometer level may open avenues for optimizing catalysts through stabilization of unconventional surface structures with special chemical activity.

  12. Investigation of the hydrothermal crystallisation of the perovskite solid solution NaCe{sub 1?x}La{sub x}Ti{sub 2}O{sub 6} and its defect chemistry

    SciTech Connect (OSTI)

    Harunsani, Mohammad H.; Woodward, David I.; Peel, Martin D.; Ashbrook, Sharon E.; Walton, Richard I.

    2013-11-15

    Perovskites of nominal composition NaCe{sub 1?x}La{sub x}Ti{sub 2}O{sub 6} (0?x?1) crystallise directly under hydrothermal conditions at 240 °C. Raman spectroscopy shows distortion from the ideal cubic structure and Rietveld analysis of powder X-ray and neutron diffraction reveals that the materials represent a continuous series in rhombohedral space group R3-bar c. Ce L{sub III}-edge X-ray absorption near edge structure spectroscopy shows that while the majority of cerium is present as Ce{sup 3+} there is evidence for Ce{sup 4+}. The paramagnetic Ce{sup 3+} affects the chemical shift and line width of {sup 23}Na MAS NMR spectra, which also show with no evidence for A-site ordering. {sup 2}H MAS NMR of samples prepared in D{sub 2}O shows the inclusion of deuterium, which IR spectroscopy shows is most likely to be as D{sub 2}O. The deuterium content is highest for the cerium-rich materials, consistent with oxidation of some cerium to Ce{sup 4+} to provide charge balance of A-site water. - Graphical abstract: A multi-element A-site perovskite crystallises directly from aqueous, basic solutions at 240 °C; while the paramagnetic effect of Ce{sup 3+} on the {sup 23}Na NMR shows a homogeneous solid-solution, the incorporation of A-site water is also found from {sup 2}H NMR and IR, with oxidation of some cerium to charge balance proved by XANES spectroscopy. Display Omitted - Highlights: • Direct hydrothermal synthesis allows crystallisation of a perovskite solid-solution. • XANES spectroscopy shows some oxidation of Ce{sup 3+} to Ce{sup 4+}. • The paramagnetism of Ce{sup 3+} shifts and broadens the {sup 23}Na solid-state NMR. • The perovskite materials incorporate water as an A-site defect.

  13. Substitution effect on the magnetic and transport properties of CeNi{sub 0.8?x}Mn{sub x}Bi{sub 2}

    SciTech Connect (OSTI)

    Kim, Soo-Whan; Lee, Kyujoon; Jung, Myung-Hwa; Adroja, D. T.; Demmel, F.; Taylor, J. W.

    2014-08-21

    We report the results of Mn substitution for Ni in CeNi{sub 0.8}Bi{sub 2} (i.e., CeNi{sub 0.8?x}Mn{sub x}Bi{sub 2}). All the samples have an antiferromagnetic ordered state below T{sub N}?=?5.0?K due to localized 4f-magnetic moment on the Ce ions. Besides this antiferromagnetic ordering caused by Ce, the magnetic and transport properties are abruptly changed with increasing Mn contents at the boundary composition of x?=?0.4. The magnetic state is changed into a ferromagnetic state around 200?K for x?>?0.4, where the electrical resistivity is strongly suppressed to become simple metallic. These results of ferromagnetism and metallicity can be explained by the double exchange mechanism, rather than the simple picture of Doniach phase diagram. The mixed valence states of Ni and Mn ions are confirmed by X-ray photoelectron spectroscopy. For x???0.4, the initial Ni{sup 3+} state gradually changes to the Ni{sup 2+} state with increasing x up to 0.4. On further increase of x?>?0.4, the Ni{sup 2+} state is replaced by the Mn{sup 2+} state, which gradually changes to the final Mn{sup 3+} state. We also present an inelastic neutron scattering (INS) measurements on CeNi{sub 0.8}Bi{sub 2} (i.e., x?=?0) between 1.2 and 12?K. The high energy INS study reveals the presence of two well-defined crystal electric field (CEF) excitations near 9?meV and 19?meV at 1.2?K and 6?K, while the low energy INS study reveals the presence of quasielastic scattering above 4?K. We will discuss our INS results of CeNi{sub 0.8}Bi{sub 2} based on the CEF model.

  14. Lu.sub.1-xI.sub.3:Ce.sub.x--a scintillator for gamma ray spectroscopy and time-of-flight PET

    DOE Patents [OSTI]

    Shah, Kanai S.

    2007-02-06

    The present invention concerns very fast scintillator materials comprising lutetium iodide doped with Cerium (Lu.sub.1-xI.sub.3:Ce.sub.x; LuI.sub.3:Ce). The LuI.sub.3 scintillator material has surprisingly good characteristics including high light output, high gamma ray stopping efficiency, fast response, low cost, good proportionality, and minimal afterglow that the material is useful for gamma ray spectroscopy, medical imaging, nuclear and high energy physics research, diffraction, non-destructive testing, nuclear treaty verification and safeguards, and geological exploration. The timing resolution of the scintillators of the present invention provide compositions capable of resolving the position of an annihilation event within a portion of a human body cross-section.

  15. Fabrication of CeO2 by sol-gel process based on microfluidic technology as an analog preparation of ceramic nuclear fuel microspheres

    E-Print Network [OSTI]

    Ye, Bin; Li, Jiaolong; Zhao, Zichen; Chang, Zhenqi; Serra, Christophe A

    2012-01-01

    Microfluidics integrated with sol-gel processes is introduced in preparing monodispersed MOX nuclear fuel microspheres using nonactive cerium as a surrogate for uranium or plutonium. The detailed information about microfluidic devices and sol-gel processes are provided. The effects of viscosity and flow rate of continuous and dispersed phase on size and size distribution of CeO2 microspheres have been investigated. A comprehensive characterization of the CeO2 microspheres has been conducted, including XRD pattern, SEM, density, size and size distribution. The size of prepared monodisperse particles can be controlled precisely in range of 10{\\mu}m to 1000{\\mu}m and the particle CV is below 3%.

  16. Fabrication of CeO2 by sol-gel process based on microfluidic technology as an analog preparation of ceramic nuclear fuel microspheres

    E-Print Network [OSTI]

    Bin Ye; Jilang Miao; Jiaolong Li; Zichen Zhao; Zhenqi Chang; Christophe A. Serra

    2012-12-15

    Microfluidics integrated with sol-gel processes is introduced in preparing monodispersed MOX nuclear fuel microspheres using nonactive cerium as a surrogate for uranium or plutonium. The detailed information about microfluidic devices and sol-gel processes are provided. The effects of viscosity and flow rate of continuous and dispersed phase on size and size distribution of CeO2 microspheres have been investigated. A comprehensive characterization of the CeO2 microspheres has been conducted, including XRD pattern, SEM, density, size and size distribution. The size of prepared monodisperse particles can be controlled precisely in range of 10{\\mu}m to 1000{\\mu}m and the particle CV is below 3%.

  17. Nodal to nodeless superconducting energy gap structure change concomitant with Fermi surface reconstruction in the heavy-fermion CeCoIn?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Hyunsoo; Petrovic, C.; Tanatar, M. A.; Flint, R.; Hu, Rongwei; White, B. D.; Lum, I. K.; Maple, M. B.; Prozorov, R.

    2015-01-15

    The London penetration depth ?(T) was measured in single crystals of Ce1–xRxCoIn?, R=La, Nd, and Yb down to Tmin ? 50 mK (Tc/Tmin ~50) using a tunnel-diode resonator. In the cleanest samples ??(T) is best described by the power law, ??(T) ? Tn, with n ~ 1, consistent with line nodes. Substitutions of Ce with La, Nd, and Yb lead to similar monotonic suppressions of Tc, however, the effects on ??(T) differ. While La and Nd dopings lead to increase of the exponent n and saturation at n ~ 2, as expected for a dirty nodal superconductor, Yb doping leadsmore »to n > 3, suggesting a change from nodal to nodeless superconductivity. This superconducting gap structure change happens in the same doping range where changes of the Fermi surface topology were reported, implying that the nodal structure and Fermi surface topology are closely linked.« less

  18. Syngas production from butane using a flame-made Rh/Ce0.5Zr0.5O2 Nico Hotz a

    E-Print Network [OSTI]

    Daraio, Chiara

    Syngas production from butane using a flame-made Rh/Ce0.5Zr0.5O2 catalyst Nico Hotz a , Michael J the production of H2- and CO-rich syngas from butane was investigated for different Rh loadings (0­2.0 wt% Rh for a temperature range from 225 to 750 8C. The main goal of this study was the efficient processing of butane

  19. Commissioning of the 112 MHz SRF Gun and 500 MHz bunching cavities for the CeC PoP Linac

    SciTech Connect (OSTI)

    Belomestnykh, S.; Ben-Zvi, I.; Brutus, J. C.; Litvinenko, V.; McIntosh, P.; Moss, A.; Narayan, G.; Orfin, P.; Pinayev, I.; Rao, T.; Skaritka, J.; Smith, K.; Than, R.; Tuozzolo, J.; Wang, E.; Wheelhouse, A.; Wu, Q.; Xiao, B.; Xin, T.; Xu, W.; Zaltsman, A.

    2015-05-03

    The Coherent electron Cooling Proof-of-Principle (CeC PoP) experiment at BNL includes a short electron linac. During Phase 1, a 112 MHz superconducting RF photo-emission gun and two 500 MHz normal conducting bunching cavities were installed and are under commissioning. The paper describes the Phase1 linac layout and presents commissioning results for the cavities and associated RF, cryogenic and other sub-systems

  20. Contact Undergraduate Admissions Office | Tel +44 (0)117 928 8154 Email socsci-ug-admissions@bristol.ac.uk 54 ACCOUnTing And FinAnCE

    E-Print Network [OSTI]

    Subramanian, Sriram

    -ug-admissions@bristol.ac.uk 54 ACCOUnTing And FinAnCE FACULTY oF soCiAL sCienCes And LAw bristol.ac.uk Accounting and Finance As one of the UK's leading departments for Accounting and Finance, we offer you the opportunity to study and their application skills. bristol.ac.uk/accounting Why study Accounting and Finance at Bristol? Bristol has

  1. Study of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel cell2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to oxygen dissociation and diffusion process.26 KEYWORDS: Solid oxide fuel cell; Silver infiltrationStudy of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel cell2 3 4 Li-Ping Sun1 -- Hui Zhao1 -- Qiang Li1 -- Li-Hua Huo1 -- Jean-Paul Viricelle*2 --5 Christophe

  2. High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions

    SciTech Connect (OSTI)

    G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

    2011-12-31

    The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

  3. Magnetic order and heavy fermion behavior in CePd{sub 1+x}Al{sub 6-x}: Synthesis, structure, and physical properties

    SciTech Connect (OSTI)

    Tobash, Paul H., E-mail: ptobash@lanl.go [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Ronning, Filip; Thompson, J.D. [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bobev, Svilen [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Bauer, Eric D. [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2010-03-15

    The physical properties including magnetic susceptibility, specific heat, and electrical resistivity of single crystals are reported for the compound CePd{sub 1+x}Al{sub 6-x} (x=0.5) which crystallizes in the tetragonal SrAu{sub 2}Ga{sub 5}-type structure (space group P4/mmm). The compound was grown from an excess of molten Al flux from the respective elements and the crystal structure was established from single-crystal X-ray diffraction. Anomalies in the low temperature specific heat C{sub p}(T) and electrical resistivity rho(T) show that the compound undergoes ferromagnetic order at T{sub C}=2.8 K. In the ordered state, CePd{sub 1.5}Al{sub 5.5} displays heavy fermion behavior with a Sommerfeld coefficient of ca. 500 mJ/mol-K{sup 2}. - Graphical abstract: The compound CePd{sub 1+x}Al{sub 6-x} (x=0.5) has been synthesized and structurally characterized by single-crystal X-ray diffraction. The measured physical properties of temperature and field dependent magnetic susceptibility, specific heat, and electrical resistivity suggests that the compound undergoes ferromagnetic order at ca. 2.8 K and further exhibits relatively heavy fermion behavior with a Sommerfeld coefficient of 500 mJ/mol-K2.

  4. Synthesis of low loss, thermally stable Ce{sub x}Y{sub 1-x}TiTaO{sub 6} microwave ceramics

    SciTech Connect (OSTI)

    Padma Kumar, H.; John, Annamma [Dielectric Materials Research Laboratory, Department of Physics, St. John's College, Anchal, Kollam District, Kerala 691306 (India); Vijayakumar, C. [Department of Physics, Mar Ivanios College, Nalanchira, Thiruvananthapuram, Kerala 695015 (India); Thomas, J.K. [Electronic Materials Research Laboratory, Department of Physics, Mar Ivanios College, Nalanchira, Thiruvananthapuram, Kerala 695015 (India); Varma, Manoj Raama [National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram, Kerala 695015 (India); Solomon, Sam [Dielectric Materials Research Laboratory, Department of Physics, St. John's College, Anchal, Kollam District, Kerala 691306 (India)], E-mail: samdmrl@yahoo.com

    2009-02-04

    Ce{sub x}Y{sub 1-x}TiTaO{sub 6} ceramics were prepared through the solid-state ceramic route. The materials were sintered in the range 1520-1580 deg. C. The structure of the system was analyzed by X-ray diffraction and Raman spectroscopic methods. The cell parameters of solid solutions were calculated using the least square method. The microstructure was analyzed using scanning electron microscopy. The dielectric constant ({epsilon}{sub r}), temperature coefficient of resonant frequency ({tau}{sub f}) and the unloaded quality factor (Q{sub u}) are measured in the microwave frequency region using cavity resonator method. The dielectric constant increases with higher concentrations of Ce in the solid solutions. Nearly zero temperature coefficient of resonant frequency ({tau}{sub f}) was obtained for Ce{sub 0.24}Y{sub 0.76}TiTaO{sub 6}. The samples are of high quality factor and are useful electronic materials for microwave applications.

  5. Study of phase relationships in the Sr{sub 3}(PO{sub 4}){sub 2}–CePO{sub 4} system. Phase diagram and thermal characteristics of phases

    SciTech Connect (OSTI)

    Matraszek, Aleksandra, E-mail: aleksandra.matraszek@ue.wroc.pl

    2013-07-15

    A diagram representing phase relationships in the Sr{sub 3}(PO{sub 4}){sub 2}–CePO{sub 4} phosphate system has been developed on the basis of results obtained by thermal analysis (DTA/DSC/TGA) and X-ray diffraction (XRD) methods. One intermediate compound with the formula Sr{sub 3}Ce(PO{sub 4}){sub 3} occurs in the Sr{sub 3}(PO{sub 4}){sub 2}–CePO{sub 4} system at temperatures exceeding 1045 °C. The compound has a eulytite structure with the following structural parameters: a=b=c=10.1655(8) Å, ?=?=?=90.00°, V=1050.46(6) Å{sup 3}. It's melting point exceeds 1950 °C. A limited solid solution exists in the system, which possesses the structure of a low-temperature form of Sr{sub 3}(PO{sub 4}){sub 2}. At 1000 °C the maximal concentration of CePO{sub 4} in the solid solution is below 20 mol%. The solid solution phase field narrows with increased temperature. There is a eutectic point in the (Sr{sub 3}(PO{sub 4}){sub 2}+Sr{sub 3}Ce(PO{sub 4}){sub 3}) phase field at 1765 °C and 15 mol% of CePO{sub 4}. The melting temperature of Sr{sub 3}(PO{sub 4}){sub 2} is 1882±15 °C. - Graphical abstract: The phase diagram of Sr{sub 3}(PO{sub 4}){sub 2}–CePO{sub 4} system showing the stability ranges of limited solid solution and Sr{sub 3}Ce(PO{sub 4}){sub 3} phases. - Highlights: • Sr{sub 3}(PO{sub 4}){sub 2} melts at 1882 °C. • Phase diagram of Sr{sub 3}(PO{sub 4}){sub 2}–CePO{sub 4} system has been proposed. • Limited solid solution of CePO{sub 4} in Sr{sub 3}(PO{sub 4}){sub 2} forms in the system. • The Sr{sub 3}Ce(PO{sub 4}){sub 2} phosphate is stable at temperatures above 1045 °C.

  6. Improved Laboratory Transition Probabilities for Ce II, Application to the Cerium Abundances of the Sun and Five r-process Rich, Metal-Poor Stars, and Rare Earth Lab Data

    E-Print Network [OSTI]

    Lawler, J E; Cowan, J J; Ivans, I I; Hartog, E A Den

    2009-01-01

    Recent radiative lifetime measurements accurate to +/- 5% using laser-induced fluorescence (LIF) on 43 even-parity and 15 odd-parity levels of Ce II have been combined with new branching fractions measured using a Fourier transform spectrometer (FTS) to determine transition probabilities for 921 lines of Ce II. This improved laboratory data set has been used to determine a new solar photospheric Ce abundance, log epsilon = 1.61 +/- 0.01 (sigma = 0.06 from 45 lines), a value in excellent agreement with the recommended meteoritic abundance, log epsilon = 1.61 +/- 0.02. Revised Ce abundances have also been derived for the r-process-rich metal-poor giant stars BD+17 3248, CS 22892-052, CS 31082-001, HD 115444 and HD 221170. Between 26 and 40 lines were used for determining the Ce abundance in these five stars, yielding a small statistical uncertainty of 0.01 dex similar to the Solar result. The relative abundances in the metal-poor stars of Ce and Eu, a nearly pure r-process element in the Sun, matches r-process ...

  7. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    SciTech Connect (OSTI)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12?Ce?(GGAG?Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-level diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.

  8. Hierarchical Heterogeneity at the CeO x –TiO 2 Interface: Electronic and Geometric Structural Influence on the Photocatalytic Activity of Oxide on Oxide Nanostructures

    SciTech Connect (OSTI)

    Luo, Si; Nguyen-Phan, Thuy-Duong; Johnston-Peck, Aaron C.; Barrio, Laura; Sallis, Shawn; Arena, Dario A.; Kundu, Shankhamala; Xu, Wenqian; Piper, Louis F. J.; Stach, Eric A.; Polyanskiy, Dmitry E.; Fujita, Etsuko; Rodriguez, José A.; Senanayake, Sanjaya D.

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravel the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.

  9. Itinerant electrons, local moments, and magnetic correlations in the pnictide superconductors CeFeAsO??xFxand Sr(Fe??xCox)?As?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vilmercati, Paolo; Fedorov, Alexei; Bondino, Federica; Offi, Francesco; Panaccione, Giancarlo; Lacovig, Paolo; Simonelli, Laura; McGuire, Michael A.; Sefat, Athena S. M.; Mandrus, David; et al

    2012-06-15

    A direct and element-specific measurement of the local Fe spin moment has been provided by analyzing the Fe 3s core level photoemission spectra in the parent and optimally doped CeFeAsO??xFx (x = 0, 0.11) and Sr(Fe??xCox)2As2 (x = 0, 0.10) pnictides. The rapid time scales of the photoemission process allowed the detection of large local spin moments fluctuating on a 10?¹? s time scale in the paramagnetic, antiferromagnetic, and superconducting phases, indicative of the occurrence of ubiquitous strong Hund's magnetic correlations. The magnitude of the spin moment is found to vary significantly among different families, 1.3?B in CeFeAsO and 2.1?Bmore »in SrFe?As?. Surprisingly, the spin moment is found to decrease considerably in the optimally doped samples, 0.9?B in CeFeAsO?.??F?.?? and 1.3?B in Sr(Fe?.?Co?.?)?As?. The strong variation of the spin moment against doping and material type indicates that the spin moments and the motion of itinerant electrons are influenced reciprocally in a self-consistent fashion, reflecting the strong competition between the antiferromagnetic superexchange interaction among the spin moments and the kinetic energy gain of the itinerant electrons in the presence of a strong Hund's coupling. By describing the evolution of the magnetic correlations concomitant with the appearance of superconductivity, these results constitute a fundamental step toward attaining a correct description of the microscopic mechanisms shaping the electronic properties in the pnictides, including magnetism and high-temperature superconductivity.« less

  10. Neutron diffraction study of magnetic field induced behavior in the heavy Fermion Ce3Co4Sn13

    SciTech Connect (OSTI)

    Christianson, Andrew D; Goremychkin, E. A.; Gardner, J. S.; Kang, H. J.; Chung, J.-H.; Manuel, P.; Thompson, J. D.; Sarrao, J. L.; Lawrence, J. M.

    2008-01-01

    The specific heat of Ce3Co4Sn13 exhibits a crossover from heavy Fermion behavior with antiferromagnetic correlations at low field to single impurity Kondo behavior above 2 T. We have performed neutron diffraction measurements in magnetic fields up to 6 Tesla on single crystal samples. The (001) position shows a dramatic increase in intensity in field which appears to arise from static polarization of the 4f level and which at 0.14 K also exhibits an anomaly near 2T reflecting the crossover to single impurity behavior.

  11. Synthesis and crystal structure of the isotypic rare earth thioborates Ce[BS{sub 3}], Pr[BS{sub 3}], and Nd[BS{sub 3}

    SciTech Connect (OSTI)

    Hunger, Jens; Borna, Marija [Max Planck Institute for Chemical Physics of Solids, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Kniep, Ruediger, E-mail: kniep@cpfs.mpg.d [Max Planck Institute for Chemical Physics of Solids, Noethnitzer Strasse 40, D-01187 Dresden (Germany)

    2010-03-15

    The orthothioborates Ce[BS{sub 3}], Pr[BS{sub 3}] and Nd[BS{sub 3}] were prepared from mixtures of the rare earth (RE) metals together with amorphous boron and sulfur summing up to the compositions CeB{sub 3}S{sub 6}, PrB{sub 5}S{sub 9} and NdB{sub 3}S{sub 6}. The following preparation routes were used: solid state reactions with maximum temperatures of 1323 K and high-pressure high-temperature syntheses at 1173 K and 3 GPa. Pr[BS{sub 3}] and Nd[BS{sub 3}] were also obtained from rare earth chlorides RECl{sub 3} and sodium thioborate Na{sub 2}B{sub 2}S{sub 5} by metathesis type reactions at maximum temperatures of 1073 K. The crystal structure of the title compounds was determined from X-ray powder diffraction data. The thioborates are isotypic and crystallize in the orthorhombic spacegroup Pna2{sub 1} (No. 33; Z=4; Ce: a=7.60738(6)A, b=6.01720(4)A, c=8.93016(6)A; Pr: a=7.56223(4)A, b=6.00876(2)A, c=8.89747(4)A; Nd: a=7.49180(3)A, b=6.00823(2)A, c=8.86197(3)A) . The crystal structures contain isolated [BS{sub 3}]{sup 3-} groups with boron in trigonal-planar coordination. The sulfur atoms form the vertices of undulated kagome nets, which are stacked along [100] according to the sequence ABAB. Within these nets every second triangle is occupied by boron and the large hexagons are centered by rare earth ions, which are surrounded by overall nine sulfur species. - Abstract: Graphical Abstract Legend (TOC Figure): Table of Contents Figure The isotypic orthothioborates Ce[BS{sub 3}], Pr[BS{sub 3}] and Nd[BS{sub 3}] were prepared using different preparation routes. The crystal structure of the title compounds was determined from X-ray powder diffraction data. The crystal structures contain isolated [BS{sub 3}]{sup 3-} groups with boron in trigonal-planar coordination. The sulfur atoms form the vertices of corrugated kagome nets (sketched with blue dotted lines), which are stacked along [100] according to the sequence ABAB. Within these nets every second triangle is occupied by boron and the large hexagons are centered by rare earth ions, which are surrounded by overall nine sulfur species.

  12. A novel yellow-emitting SrAlSi{sub 4}N{sub 7}:Ce{sup 3+} phosphor for solid state lighting: Synthesis, electronic structure and photoluminescence properties

    SciTech Connect (OSTI)

    Ruan, Jian; Xie, Rong-Jun; Funahashi, Shiro; Tanaka, Yoshinori; Takeda, Takashi; Suehiro, Takayuki; Hirosaki, Naoto; Li, Yuan-Qiang

    2013-12-15

    Ce{sup 3+}-doped and Ce{sup 3+}/Li{sup +}-codoped SrAlSi{sub 4}N{sub 7} phosphors were synthesized by gas pressure sintering of powder mixtures of Sr{sub 3}N{sub 2}, AlN, ?-Si{sub 3}N{sub 4}, CeN and Li{sub 3}N. The phase purity, electronic crystal structure, photoluminescence properties of SrAlSi{sub 4}N{sub 7}:Ce{sup 3+}(Ce{sup 3+}/Li{sup +}) were investigated in this work. The band structure calculated by the DMol{sup 3} code shows that SrAlSi{sub 4}N{sub 7} has a direct band gap of 3.87 eV. The single crystal analysis of Ce{sup 3+}-doped SrAlSi{sub 4}N{sub 7} indicates a disordered Si/Al distribution and nitrogen vacnacy defects. SrAlSi{sub 4}N{sub 7} was identified as a major phase of the fired powders, and Sr{sub 5}Al{sub 5}Si{sub 21}N{sub 35}O{sub 2} and AlN as minor phases. Both Ce{sup 3+} and Ce{sup 3+}/Li{sup +} doped SrAlSi{sub 4}N{sub 7} phosphors can be efficiently excited by near-UV or blue light and show a broadband yellow emission peaking around 565 nm. A highest external quantum efficiency of 38.3% under the 450 nm excitation was observed for the Ce{sup 3+}/Li{sup +}-doped SrAlSi{sub 4}N{sub 7} (5 mol%). A white light LED lamp with color temperature of 6300 K and color rendering index of Ra=78 was achieved by combining Sr{sub 0.97}Al{sub 1.03}Si{sub 3.997}N/94/maccounttest14=t0005{sub 1}8193 {sub 7}:Ce{sup 3+}{sub 0.03} with a commercial blue InGaN chip. It indicates that SrAlSi{sub 4}N{sub 7}:Ce{sup 3+} is a promising yellow emitting down-conversion phosphor for white LEDs. - Graphical abstract: One-phosphor converted white light-emitting diode (LED) was fabricated by combining a blue LED chip and a yellow-emitting SrAlSi4N7:Ce{sup 3+} phosphor (see inset), which has the color rendering index of 78 and color temperature of 6300 K. - Highlights: • We reported a new yellow nitride phosphor suitable for solid state lighting. • We solved the crystal structure and evidenced a disordered Si/Al distribution. • We fabricated a high color rendering white LEDs by using a single SrAlSi4N7:Ce.

  13. Charge-coupled substituted garnets (Y 3–x Ca 0.5x M 0.5x )Fe?O?? (M = Ce, Th): Structure and stability as crystalline nuclear waste forms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Xiaofeng; Kukkadapu, Ravi K.; Lanzirotti, Antonio; Newville, Matthew; Engelhard, Mark H.; Sutton, Stephen R.; Navrotsky, Alexandra

    2015-04-20

    The garnet structure has been proposed as a potential crystalline nuclear waste form for accommodation of actinide elements, especially uranium (U). In this study, yttrium iron garnet (YIG) as a model garnet host was studied for the incorporation of U analogs, cerium (Ce) and thorium (Th), incorporated by a charge-coupled substitution with calcium (Ca) for yttrium (Y) in YIG, namely, 2Y³? = Ca²? + M??, where M?? = Ce?? or Th??. Single-phase garnets Y3–xCa0.5xM0.5xFe?O?? (x = 0.1–0.7) were synthesized by the citrate–nitrate combustion method. Ce was confirmed to be tetravalent by X-ray absorption spectroscopy and X-ray photoelectron spectroscopy. X-ray diffractionmore »and ??Fe–Mössbauer spectroscopy indicated that M?? and Ca²? cations are restricted to the c site, and the local environments of both the tetrahedral and the octahedral Fe³? are systematically affected by the extent of substitution. The charge-coupled substitution has advantages in incorporating Ce/Th and in stabilizing the substituted phases compared to a single substitution strategy. Enthalpies of formation of garnets were obtained by high-temperature oxide melt solution calorimetry, and the enthalpies of substitution of Ce and Th were determined. The thermodynamic analysis demonstrates that the substituted garnets are entropically rather than energetically stabilized. This suggests that such garnets may form and persist in repositories at high temperature but might decompose near room temperature.« less

  14. Effect of Tb{sup 3+} concentration on the optical and vibrational properties of YBO{sub 3} tri-doped with Eu{sup 3+}, Ce{sup 3+}, and Tb{sup 3+}

    SciTech Connect (OSTI)

    Sohal, S.; Hassanzadeh, E.; Huang, J. Y. [Department of Physics, Texas Tech University and Nano Tech Center, Lubbock, Texas 79409 (United States); Nazari, M.; Holtz, M., E-mail: mark.holtz@txstate.edu [Department of Physics, Texas State University, San Marcos, Texas 78666 (United States); Zhang, X.; Chaudhuri, J. [Department of Mechanical Engineering, Texas Tech University, Lubbock, Texas 79409 (United States); Kuryatkov, V. V. [Department of Electrical and Computer Engineering and Nano Tech Center, Texas Tech University, Lubbock, Texas 79409 (United States); Hope-Weeks, L. J. [Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas 79409 (United States)

    2014-05-14

    Structural and optical studies are reported of yttrium orthoborate YBO{sub 3} when tri-doped with Eu{sup 3+}, Ce{sup 3+}, and Tb{sup 3+}, focusing on the role of terbium concentration. Incorporation of Tb{sup 3+} affects emission properties for photoluminescence (PL) excited by near ultraviolet light. For constant cerium and europium concentrations, increasing the Tb{sup 3+} results in diminished PL from the Ce{sup 3+} and Tb{sup 3+} color centers. Simultaneously, the PL excitation bands related to both Ce{sup 3+} and Tb{sup 3+} increase in intensity for red emission from the Eu{sup 3+}. Results are consistent with a Ce{sup 3+}???(Tb{sup 3+}){sub n}???Eu{sup 3+} energy transfer scheme, where (Tb{sup 3+}){sub n} denotes a chain incorporating n terbium ions. A high red to orange PL intensity ratio is obtained, ranging from 1.34 to 2.09. Raman vibrational bands show a systematic change, with Tb{sup 3+} concentration, in the B{sub 3}O{sub 9} ring terminal oxygen bending mode coordinated with the yttrium site where dopant ions substitute. The structural changes are interpreted as variations in the local neighborhood of these sites in the YBO{sub 3}:Ce{sup 3+},Tb{sup 3+},Eu{sup 3+} crystal structure.

  15. Insensitivity of the pressure dependences of characteristic energy scales in Ce1–xRxCoIn? (R=Yb,Y,Gd) to the electronic configuration of the rare-earth ion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    White, B. D.; Hamlin, J. J.; Huang, K.; Shu, L.; Lum, I. K.; Baumbach, R. E.; Janoschek, M.; Maple, M. B.

    2012-09-11

    Cooperative Ce and Yb valence fluctuations have recently been proposed as the mechanism responsible for stabilizing correlated electron phenomena in Ce??xYbxCoIn? over an unexpectedly large range of concentrations. In order to better understand the origins and character of this stability, we have measured the effect of applied pressure on relevant energy scales such as the superconducting critical (Tc) and Kondo-lattice coherence (T*) temperatures of Ce??xRxCoIn? with R=Yb, Y, and Gd. Electrical resistivity measurements were performed under applied pressure on samples doped with intermediate-valent Yb and stable-valent Gd and Y, and the responses of Tc and T* to increased pressure inmore »these systems are compared. The character of Tc(P) and T*(P) in Ce??xRxCoIn? depends only on their respective ambient-pressure values Tc(0) and T*(0), independent of the electronic configuration of R or concentration x. The consequences of this result are discussed within the context of possible cooperative valence fluctuations in Ce??xYbxCoIn?.« less

  16. Insensitivity of the pressure dependences of characteristic energy scales in Ce1–xRxCoIn? (R=Yb,Y,Gd) to the electronic configuration of the rare-earth ion

    SciTech Connect (OSTI)

    White, B. D.; Hamlin, J. J.; Huang, K.; Shu, L.; Lum, I. K.; Baumbach, R. E.; Janoschek, M.; Maple, M. B.

    2012-09-01

    Cooperative Ce and Yb valence fluctuations have recently been proposed as the mechanism responsible for stabilizing correlated electron phenomena in Ce??xYbxCoIn? over an unexpectedly large range of concentrations. In order to better understand the origins and character of this stability, we have measured the effect of applied pressure on relevant energy scales such as the superconducting critical (Tc) and Kondo-lattice coherence (T*) temperatures of Ce??xRxCoIn? with R=Yb, Y, and Gd. Electrical resistivity measurements were performed under applied pressure on samples doped with intermediate-valent Yb and stable-valent Gd and Y, and the responses of Tc and T* to increased pressure in these systems are compared. The character of Tc(P) and T*(P) in Ce??xRxCoIn? depends only on their respective ambient-pressure values Tc(0) and T*(0), independent of the electronic configuration of R or concentration x. The consequences of this result are discussed within the context of possible cooperative valence fluctuations in Ce??xYbxCoIn?.

  17. Insensitivity of the pressure dependences of characteristic energy scales in Ce1–xRxCoIn? (R=Yb,Y,Gd) to the electronic configuration of the rare-earth ion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    White, B. D.; Hamlin, J. J.; Huang, K.; Shu, L.; Lum, I. K.; Baumbach, R. E.; Janoschek, M.; Maple, M. B.

    2012-09-01

    Cooperative Ce and Yb valence fluctuations have recently been proposed as the mechanism responsible for stabilizing correlated electron phenomena in Ce??xYbxCoIn? over an unexpectedly large range of concentrations. In order to better understand the origins and character of this stability, we have measured the effect of applied pressure on relevant energy scales such as the superconducting critical (Tc) and Kondo-lattice coherence (T*) temperatures of Ce??xRxCoIn? with R=Yb, Y, and Gd. Electrical resistivity measurements were performed under applied pressure on samples doped with intermediate-valent Yb and stable-valent Gd and Y, and the responses of Tc and T* to increased pressure in these systems are compared. The character of Tc(P) and T*(P) in Ce??xRxCoIn? depends only on their respective ambient-pressure values Tc(0) and T*(0), independent of the electronic configuration of R or concentration x. The consequences of this result are discussed within the context of possible cooperative valence fluctuations in Ce??xYbxCoIn?.

  18. Nodal to nodeless superconducting energy gap structure change concomitant with Fermi surface reconstruction in the heavy-fermion CeCoIn?

    SciTech Connect (OSTI)

    Kim, Hyunsoo [Iowa State Univ., Ames, IA (United States); Petrovic, C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Tanatar, M. A. [Iowa State Univ., Ames, IA (United States); Flint, R. [Iowa State Univ., Ames, IA (United States); Hu, Rongwei [Brookhaven National Lab. (BNL), Upton, NY (United States); White, B. D. [Univ. of California, San Diego, La Jolla, CA (United States); Lum, I. K. [Univ. of California, San Diego, La Jolla, CA (United States); Maple, M. B. [Univ. of California, San Diego, La Jolla, CA (United States); Prozorov, R. [Iowa State Univ., Ames, IA (United States)

    2015-01-01

    The London penetration depth ?(T) was measured in single crystals of Ce1?xRxCoIn?, R=La, Nd, and Yb down to Tmin ? 50??mK (Tc/Tmin ~50) using a tunnel-diode resonator. In the cleanest samples ??(T) is best described by the power law, ??(T) ? Tn, with n ~ 1, consistent with line nodes. Substitutions of Ce with La, Nd, and Yb lead to similar monotonic suppressions of Tc, however, the effects on ??(T) differ. While La and Nd dopings lead to increase of the exponent n and saturation at n ~ 2, as expected for a dirty nodal superconductor, Yb doping leads to n > 3, suggesting a change from nodal to nodeless superconductivity. This superconducting gap structure change happens in the same doping range where changes of the Fermi surface topology were reported, implying that the nodal structure and Fermi surface topology are closely linked.

  19. Level structure of the odd mass Pr isotopes. III. Levels of [sup 147]Pr[sub 88] populated in the beta decay of 56-s [sup 147]Ce

    SciTech Connect (OSTI)

    Mantica, P.F. (Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742 (United States) UNISOR, Oak Ridge Institute for Science Education, Oak Ridge, Tennessee 37831 (United States)); Robertson, J.D.; Baum, E.M.; Walters, W.B. (Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742 (United States))

    1993-10-01

    The structure of [sup 147]Pr has been investigated by performing measurements of [gamma]-ray and conversion-electron singles and [gamma][gamma] coincidence spectra of mass separated sources of 56-s [sup 147]Ce. The proposed level scheme extends the known structure of [sup 147]Pr to an energy of 2.2 MeV and includes several levels below 1.2 MeV that have not been identified in previous decay studies of [sup 147]Ce. Measurement of the conversion coefficients for several transitions has led to the assignment of negative parity to the levels at 362, 452, 467, and 608 keV in [sup 147]Pr, which show properties similar to low-energy negative-parity states identified in [sup 145]Pr[sub 86], [sup 145]La[sub 88], and [sup 149]Pm[sub 88]. The presence of low-energy negative-parity states suggests that configurations having significantly different deformation, related to the highly deformed region above [ital N]=90 and/or to the reflection asymmetric region identified around [sup 145]Ba, may manifest themselves at low energy in these nuclides.

  20. Electrical and dielectric properties of ZnO and CeO{sub 2} doped ZrTi{sub 2}O{sub 6} ceramic

    SciTech Connect (OSTI)

    George, Aneesh; Thomas, Jijimon K.; John, Annamma [Department of Physics, Mar Ivanios College, Thiruvananthapuram 695015 (India); Solomon, Sam, E-mail: samdmrl@yahoo.com [Department of Physics, Mar Ivanios College, Thiruvananthapuram 695015, India and Department of Physics, St. John's College, Anchal, Kollam 691306 (India)

    2014-01-28

    Zirconium oxide (ZrO{sub 2}) and titanium dioxide (TiO{sub 2}) are the important catalyst supports, since it has acidic and basic properties. The intermediate phase zirconium titanate ZrTi{sub 2}O{sub 6}, which is a solid solution with Zr:Ti ratio 1:2 has outstanding dielectric properties. The effects of doping of ZnO and CeO{sub 2} on the dielectric and electrical properties of ZrTi{sub 2}O{sub 6} ceramic are investigated. On adding 0.5 wt% ZnO, the dielectric constant is increased but, on adding CeO{sub 2}, the dielectric constant is decreased. The bulk density of pure sample sintered at 1530 °C is 91% of theoretical density while that of the doped samples sintered at 1450 °C is more than 94% of theoretical density. Scanning electron micrographs reveal that the samples are well sintered with minimum porosity. The semicircle behavior in the Cole-Cole plots at room temperature reveals that the samples are good ionic conductor. The induced impedance is reduced for doped samples and this can be used as a material for electrolyte in Solid Oxide Fuel Cell.

  1. R{sub 4}Ir{sub 13}Ge{sub 9} (R=La, Ce, Pr, Nd, Sm) and RIr{sub 3}Ge{sub 2} (R=La, Ce, Pr, Nd): Crystal structures with nets of Ir atoms

    SciTech Connect (OSTI)

    Yarema, Maksym [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine) [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine); Swiss Federal Laboratories for Materials Science and Technology (EMPA), Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland); Zaremba, Oksana; Gladyshevskii, Roman [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine)] [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine); Hlukhyy, Viktor, E-mail: viktor.hlukhyy@lrz.tu-muenchen.de [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany)] [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany); Faessler, Thomas F. [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany)] [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany)

    2012-12-15

    The crystal structures of the new ternary compounds Sm{sub 4}Ir{sub 13}Ge{sub 9} and LaIr{sub 3}Ge{sub 2} were determined and refined on the basis of single-crystal X-ray diffraction data. They belong to the Ho{sub 4}Ir{sub 13}Ge{sub 9} (oP52, Pmmn) and CeCo{sub 3}B{sub 2} (hP5, P6/mmm) structure types, respectively. The formation of isotypic compounds R{sub 4}Ir{sub 13}Ge{sub 9} with R=La, Ce, Pr, Nd, and RIr{sub 3}Ge{sub 2} with R=Ce, Pr, Nd, was established by powder X-ray diffraction. The RIr{sub 3}Ge{sub 2} (R=La, Ce, Pr, Nd) compounds exist only in as-cast samples and decompose during annealing at 800 Degree-Sign C with the formation of R{sub 4}Ir{sub 13}Ge{sub 9}. The structure of Sm{sub 4}Ir{sub 13}Ge{sub 9} contains intersecting, slightly puckered nets of Ir atoms (4{sup 4})(4{sup 3}.6){sub 2}(4.6{sup 2}){sub 2} and (4{sup 4}){sub 2}(4{sup 3}.6){sub 4}(4.6{sup 2}){sub 2} that are perpendicular to [0 1 1] as well as to [0 -1 1] and [0 0 1]. The Ir atoms are surrounded by Ge atoms that form tetrahedra or square pyramids (where the layers intersect). The Sm and additional Ir atoms (in trigonal-planar coordination) are situated in channels along [1 0 0] (short translation vector). In the structure of LaIr{sub 3}Ge{sub 2} the Ir atoms form planar Kagome nets (3.6.3.6) perpendicular to [0 0 1]. These nets alternate along the short translation vector with layers of La and Ge atoms. - Graphical abstract: The crystal structures contain the nets of Ir atoms as main structural motif: R{sub 4}Ir{sub 13}Ge{sub 9} contains intersecting slightly puckered nets of Ir atoms, whereas in the structure of RIr{sub 3}Ge{sub 2} the Ir atoms form planar Kagome nets. Highlights: Black-Right-Pointing-Pointer The Ir-rich ternary germanides R{sub 4}Ir{sub 13}Ge{sub 9} (R=La, Ce, Pr, Nd, Sm) and RIr{sub 3}Ge{sub 2} (R=La, Ce, Pr, Nd) have been synthesized. Black-Right-Pointing-Pointer The RIr{sub 3}Ge{sub 2} compounds exist only in as-cast samples and decompose during annealing at 800 Degree-Sign C with the formation of R{sub 4}Ir{sub 13}Ge{sub 9}. Black-Right-Pointing-Pointer The structure of R{sub 4}Ir{sub 13}Ge{sub 9} contains intersecting slightly puckered nets of Ir atoms. Black-Right-Pointing-Pointer In the structure of RIr{sub 3}Ge{sub 2} the Ir atoms form planar Kagome nets.

  2. Dielectric relaxation from a network of charged defects in dilute CeO/sub 2/:Y/sub 2/O/sub 3/ solid solutions

    SciTech Connect (OSTI)

    Wang, D.Y.; Nowick, A.S.

    1981-01-01

    Solid solutions of Y/sub 2/O/sub 3/ in CeO/sub 2/ are examined by the thermal depolarization (or ITC) method of dielectric relaxation. For concentrations less than or equal to 1 m/o Y/sub 2/O/sub 3/, two peaks are observed. The lower temperature peak, Peak 1, is interpreted as due to the relaxation of nn YV/sub 0/ pairs (where V/sub 0/ = oxygen vacancy, and is analogous to the well-known CaV/sub 0/ pair obtained with Ca/sup 2 +/ doping. The upper peak, Peak 2, on the other hand, is a broad peak whose position is a function of concentration. It is not due to simple dipoles, but originates in the network of alternately charged (YV/sub 0/)/sup ./ pairs and isolated Y' defects by redistribution of vacancies.

  3. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx/CeO2

    SciTech Connect (OSTI)

    Kwak, Ja Hun; Szanyi, Janos

    2014-12-23

    Pulsing 15N18O onto an annealed 1% Mn16Ox/Ce16O2 catalyst resulted in very fast oxygen isotope exchange and 15N2 formation at 295 K. In the 1st 15N18O pulse, due to the presence of large number of surface oxygen defects, extensive 15N218O and 15N2 formations were observed. In subsequent pulses oxygen isotope exchange dominated as a result of highly labile oxygen in the oxide. We gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy/Vehicle Technologies Program for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

  4. Electronic structure of Ce?RhIn?: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Petrovic, C.; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore »sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  5. Electronic structure of Ce2RhIn8: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Petrovic, C.; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore »sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. As a result, our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  6. Phases in ceria-zirconia binary oxide (1-x)CeO2-xZrO2 nanoparticles: the size effects

    SciTech Connect (OSTI)

    Zhang,F.; Chen, C.; Hanson, J.; Herman, I.; Chan, S.

    2006-01-01

    The phases of ceria-zirconia nanoparticles observed in air are studied as a function of particle size and composition by X-ray diffraction, transmission electron microscopy, and Raman spectroscopy. The emergence of two tetragonal phases t{prime}{prime} and t monotonically moves toward higher zirconia concentrations with decreasing particle size. A smaller particle size increases the solubility of zirconia in cubic ceria, while higher zirconia content in ceria stabilizes against coarsening. In particular, the cubic Ce{sub 1-x}Zr{sub x}O{sub 2-y} is persistent and is 8% in phase amount even at 90% zirconia with 33 nm crystal size. Neither the monoclinic phase m nor the tetragonal phase t{prime} is observed in the present nanoparticles (<40 nm). The effectiveness of these nanoparticles as oxygen source-and-sink in catalytic support is largely due to the persistence of the cubic and the t{prime}{prime} phases.

  7. Ground state properties of even-even and odd Nd,Ce and Sm isotopes in Hartree-Fock-Bogoliubov method

    E-Print Network [OSTI]

    Younes El Bassem; Mustapha Oulne

    2015-10-06

    In this work, we have studied ground-state properties of both even-even and odd Nd isotopes within Hartree-Fock-Bogoliubov method with SLy5 Skyrme force in which the pairing strength has been generalized with a new proposed formula. We calculated bind- ing energies, two-neutron separation energies, quadrupole deformation, charge, neutron and proton radii. Similar calculations have been carried out for Ce and Sm in order to verify the validity of our pairing strength formula. The results have been compared with available experimental data, the results of Hartree-Fock-Bogoliubov calculations based on the D1S Gogny effective nucleon-nucleon interaction and predictions of some nuclear models such as Finite Range Droplet Model (FRDM) and Relativistic Mean Field (RMF) theory.

  8. Structure and magnetic properties of RE{sub 2}CuIn{sub 3} (RE=Ce, Pr, Nd, Sm and Gd)

    SciTech Connect (OSTI)

    Tyvanchuk, Yuriy B. Szytula, Andrzej; Zarzycki, Arkadiusz; Rodewald, Ute Ch.; Kalychak, Yaroslav M.; Poettgen, Rainer

    2008-12-15

    The ternary copper indides RE{sub 2}CuIn{sub 3}{identical_to}RECu{sub 0.5}In{sub 1.5} (RE=Ce, Pr, Nd, Sm and Gd) were synthesized from the elements in sealed tantalum tubes in an induction furnace. They crystallize with the CaIn{sub 2}-type structure, space group P6{sub 3}/mmc, with a statistical occupancy of copper and indium on the tetrahedral substructure. These indides show homogeneity ranges RECu{sub x}In{sub 2-x}. Single crystal structure refinements were performed for five crystals: CeCu{sub 0.66}In{sub 1.34} (a=479.90(7) pm, c=768.12(15) pm), PrCu{sub 0.52}In{sub 1.48} (a=480.23(7) pm, c=759.23(15) pm), NdCu{sub 0.53}In{sub 1.47} (a=477.51(7) pm, c=756.37(15) pm), SmCu{sub 0.46}In{sub 1.54} (a=475.31(7) pm, c=744.77(15) pm), and GdCu{sub 0.33}In{sub 1.67} (a=474.19(7), c=737.67(15) pm). Temperature-dependent susceptibility measurements show antiferromagnetic ordering at T{sub N}=4.7 K for Pr{sub 2}CuIn{sub 3} and Nd{sub 2}CuIn{sub 3} and 15 K for Sm{sub 2}CuIn{sub 3}. Fitting of the susceptibility data of the samarium compound revealed an energy gap {delta}E=39.7(7) K between the ground and the first excited levels. - Graphical abstract: The CaIn{sub 2}-type structure of Sm{sub 2}CuIn{sub 3}.

  9. Evidence for anisotropic triplet superconductor order parameter in half metallic ferromagnetic La_0.7Ca_0.3MnO_3 proximity coupled to superconducting Pr_1.85Ce_0.15CuO_4

    E-Print Network [OSTI]

    Kalcheim, Y.; Millo, O.; Egilmez, M.; Robinson, J. W. A.; Blamire, M. G.

    2012-03-07

    Scanning tunneling spectroscopy measurements performed on La_0.7Ca_0.3MnO_3 (LCMO) films epitaxially grown on Pr_1.85Ce_0.15CuO_4 (PCCO) reveal localized penetration of superconductivity into the LCMO up to distances much larger than is possible...

  10. Uninterruptible Power Supplies Designed to meet or exceed the safety standards established by UL, CSA, CE and VDE. The Alpha CFR UPS is one of the safest, most reliable and versatile Uninterruptible Power Systems

    E-Print Network [OSTI]

    Berns, Hans-Gerd

    Uninterruptible Power Supplies Designed to meet or exceed the safety standards established by ULKVA available. Uninterruptible Power Supply > The CFR's microprocessor design provides efficiency, CSA, CE and VDE. The Alpha CFR UPS is one of the safest, most reliable and versatile Uninterruptible

  11. A QuArterly Newsletter showcAsiNg News ANd highlights from the eNtrepreNeuriAl ecosystem At the uNiversity of ceNtrAl floridA

    E-Print Network [OSTI]

    Van Stryland, Eric

    Renewable Energy Inc. has secured an exclusive license to the technology and plans to expand its commercialNtrepreNeuriAl ecosystem At the uNiversity of ceNtrAl floridA New UCF Tech May Lead To Inexpensive Biofuel UCF Spinout of chemistry and forensic science at UCF. Qun Huo A University of Central Florida chemistry professor's low

  12. On phase equilibria and crystal structures in the systems Ce-Pd-B and Yb-Pd-B. Physical properties of R{sub 2}Pd{sub 13.6}B{sub 5} (R=Yb, Lu)

    SciTech Connect (OSTI)

    Sologub, Oksana [Institute of Physical Chemistry, University of Vienna, A-1090 Wien, Waehringerstrasse 42 (Austria); Rogl, Peter, E-mail: peter.franz.rogl@univie.ac.a [Institute of Physical Chemistry, University of Vienna, A-1090 Wien, Waehringerstrasse 42 (Austria); Salamakha, Leonid; Bauer, Ernst; Hilscher, Gerfried; Michor, Herwig [Institute of Solid State Physics, Vienna University of Technology, A-1040 Wien (Austria); Giester, Gerald [Institute of Mineralogy and Crystallography, University of Vienna, Althanstr. 14, A-1090 Wien (Austria)

    2010-05-15

    Phase equilibria and crystal structures of ternary compounds were determined in the systems Ce-Pd-B and Yb-Pd-B at 850 deg. C in the concentration ranges up to 45 and 33 at% of Ce and Yb, respectively, employing X-ray single crystal and powder diffraction. Phase relations in the Ce-Pd-B system at 850 deg. C are governed by formation of extended homogeneity fields, tau{sub 2}-CePd{sub 8}B{sub 2-x} (0.10Ce{sub 3}Pd{sub 25-x}B{sub 8-y} (1.06CePd{sub 3}B{sub x} (0CePd{sub 3}. Crystallographic parameters for the new structure type tau{sub 2}-CePd{sub 8}B{sub 2-x} (space group C2/c, a=1.78104(4) nm, b=1.03723(3) nm, c=1.16314(3), beta=118.515(1){sup o} for x=0.46) were established from X-ray single crystal diffraction. The crystal structures of tau{sub 2}-CePd{sub 8}B{sub 2-x} and tau{sub 3}-Ce{sub 3}Pd{sub 25-x}B{sub 3-y} are connected in a crystallographic group-subgroup relationship. Due to the lack of suitable single crystals, the novel structure of tau{sub 1}-Ce{sub 6}Pd{sub 47-x}B{sub 6} (x=0.2, C2/m space group, a=1.03594(2) nm, b=1.80782(3) nm, c=1.01997(2) nm, beta=108.321(1){sup o}) was determined from Rietveld refinement of X-ray powder diffraction data applying the structural model obtained from single crystals of homologous La{sub 6}Pd{sub 47-x}B{sub 6} (x=0.19) (X-ray single crystal diffraction, new structure type, space group C2/m, a=1.03988(2) nm, b=1.81941(5) nm, c=1.02418(2) nm, beta=108.168(1){sup o}). The Yb-Pd-B system is characterized by one ternary compound, tau{sub 1}-Yb{sub 2}Pd{sub 14}B{sub 5}, forming equilibria with extended solution YbPd{sub 3}B{sub x}, YbB{sub 6}, Pd{sub 5}B{sub 2} and Pd{sub 3}B. The crystal structures of both Yb{sub 2}Pd{sub 14}B{sub 5} and isotypic Lu{sub 2}Pd{sub 14}B{sub 5} were determined from X-ray Rietveld refinements and found to be closely related to the Y{sub 2}Pd{sub 14}B{sub 5}-type (I4{sub 1}/amd). The crystal structure of binary Yb{sub 5}Pd{sub 2-x} (Mn{sub 5}C{sub 2}-type) was confirmed from X-ray single crystal data and a slight defect on the Pd site (x=0.06) was established. The three structures tau{sub 1}-Ce{sub 6}Pd{sub 47-x}B{sub 6}, tau{sub 2}-CePd{sub 8}B{sub 2-x} and tau{sub 3}-Ce{sub 3}Pd{sub 25-x}B{sub 8-y} are related and can be considered as the packings of fragments observed in Nd{sub 2}Fe{sub 14}B structure with different stacking of common structural blocks. Physical properties for Yb{sub 2}Pd{sub 13.6}B{sub 5} (temperature dependent specific heat, electrical resistivity and magnetization) yielded a predominantly Yb-4f{sup 13} electronic configuration, presumably related with a magnetic instability below 2 K. Kondo interaction and crystalline electric field effects control the paramagnetic temperature domain. - Graphical Abstract: Crystal structure of CePd{sub 8}B{sub 2-x}.

  13. Performance of Ni-Fe/gadolinium-doped CeO{sub2} anode supported tubular solid oxide fuel cells using steam reforming of methane

    SciTech Connect (OSTI)

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-03-15

    Iron nanoparticles (Fe{sub 2}O{sub 3}) were added to NiO/gadolinium-doped CeO{sub 2} (GDC) anode supported solid oxide fuel cell (SOFC) for the direct methane-water fuel operation. The cell was co-sintered at 1400 C, and the anode porosity is 31.8%. The main size corresponding to peak volume is around 1.5 {mu}m. When steam and methane directly fed to the cell, the power density is about 0.57 W cm{sup -2} at 650 C. It is the familiar performance for H{sub 2} operation (4 times of flow rate) with same fuel utilization. Compare with the testing temperature of 600 and 650 C, there is almost no carbon fiber deposition at 700 C with steam/methane (S/C) of 5. At the same time, fuel operation of high value of S/C (=3.3) resulted in fiber-like deposition and degradation of power performance based on loading test results.

  14. An In-Situ XAS Study of the Structural Changes in a CuO-CeO2/Al2O3 Catalyst during Total Oxidation of Propane

    SciTech Connect (OSTI)

    Silversmith, Geert; Poelman, Hilde; Poelman, Dirk; Gryse, Roger de; Olea, Maria; Balcaen, Veerle; Heynderickx, Philippe; Marin, Guy B.

    2007-02-02

    A CuOx-CeOx/Al2O3 catalyst was studied with in-situ transmission Cu K XAS for the total oxidation of propane as model reaction for the catalytic elimination of volatile organic compounds. The local Cu structure was determined for the catalyst as such, after pre-oxidation and after reduction with propane. The catalyst as such has a local CuO structure. No structural effect was observed upon heating in He up to 600 deg. C or after pre-oxidation at 150 deg. C. A full reduction of the Cu2+ towards metallic Cu0 occurred, when propane was fed to the catalyst. The change in local Cu structure during propane reduction was followed with a time resolution of 1 min. The {chi}(k) scans appeared as linear combinations of start and end spectra, CuO and Cu structure, respectively. However, careful examination of the XANES edge spectra indicates the presence of a small amount of additional Cu1+ species.

  15. Wet oxidation of phenol on Ce{sub 1{minus}x}Cu{sub x}O{sub 2{minus}{delta}} catalyst

    SciTech Connect (OSTI)

    Hocevar, S.; Batista, J. [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering] [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering; Levec, J. [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering] [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering; [Univ. of Ljubljana (Slovenia). Dept. of Chemical Engineering

    1999-05-15

    Ce{sub 1{minus}x}Cu{sub x}O{sub 2{minus}{delta}} catalysts with 0.05 < x < 0.20 for catalytic wet oxidation of phenol in aqueous solutions have been synthesized using the coprecipitation method. The three most important synthesis parameters, the concentration of the mixed metal salt solution, the rate of coprecipitant addition and the stirrer speed during coprecipitation, were optimized with central composite design using the catalytic activity as a response function. The catalytic activity strongly depends on stirrer speed during coprecipitation. A high mutual dispersion of copper oxide and ceria, having the average crystallite size of about 9 nm, enhances solid solution formation. The unit cell parameter of ceria decreases when the overall concentration of copper in the catalyst increases, most probably obeying Vegard`s law. The catalysts proved to be very stable in hydrothermal reaction conditions at low pH values. After 5 h of reaction in the semibatch CST reactor less than 100 ppm of Cu was leached out of catalyst samples that were calcined in a flow of air for 2 h above 1033 K, and only a very low quantity of carbonaceous deposits were formed on the surface of the catalysts (0.6 wt%). The kinetics of phenol degradation could be interpreted by an equation valid for homogeneous autocatalytic reactions, in which the rate constant depends linearly on the heterogeneous catalyst (Cu) concentrations. This demonstrates that the reaction proceeds through a heterogeneous-homogeneous radical-branched chain mechanism.

  16. Effect of 8 MeV electron beam irradiation on the structural and optical properties of CeO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Babitha, K.K.; Priyanka, K.P.; Sreedevi, A.; Ganesh, S.; Varghese, Thomas

    2014-12-15

    The effect of 8 MeV electron beam irradiation on the structural and optical properties of cerium oxide nanoparticles was investigated. Ceria nanoparticles were synthesized by chemical precipitation method, and characterized by X-ray diffraction, transmission electron microscopy, ultraviolet–visible, photoluminescence and Raman spectroscopy. Ultraviolet–visible absorption spectra, photoluminescence and Raman spectra of beam irradiated samples were modified, and shifted to blue region, which were attributed to quantum size effect. Systematic observations found that nonstoichiometry, defects and size reduction caused by beam irradiation have great influence on optical band gap, blue shift, photoluminescence and Raman band modifications. Moreover, electron beam irradiation is a suitable technique to enhance the structural and optical properties of nanoceria by controlling the particle size, which may lead to potentially useful technological applications. - Highlights: • Investigated effect of beam irradiation on CeO{sub 2} nanoparticles • Beam irradiation caused size reduction and surface modification. • It increases microstrain, decreases d-spacing and broadens XRD peaks. • It also modifies optical band gap, absorption, PL and Raman bands.

  17. Resolution of the discrepancy between the variation of the physical properties of Ce1-xYbxCoIn5 single crystals and thin films with Yb composition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jang, S.; White, B. D.; Lum, I. K.; Kim, H.; Tanatar, M. A.; Straszheim, W. E.; Prozorov, R.; Keiber, T.; Bridges, F.; Shu, L.; et al

    2014-11-18

    The extraordinary electronic phenomena including an Yb valence transition, a change in Fermi surface topology, and suppression of the heavy fermion quantum critical field at a nominal concentration 0.2 have been found in the system. These phenomena have no discernable effect on the unconventional superconductivity and normal-state non-Fermi liquid behaviour that occur over a broad range of up to 0.8. However, the variation of the coherence temperature and the superconducting critical temperature with nominal Yb concentration for bulk single crystals is much weaker than that of thin films. To determine whether differences in the actual Yb concentration of bulk singlemore »crystals and thin film samples might be responsible for these discrepancies, we employed Vegard’s law and the spectroscopically determined values of the valences of Ce and Yb as a function of to determine the actual composition of bulk single crystals. This analysis is supported by energy-dispersive X-ray spectroscopy, wavelength-dispersive X-ray spectroscopy, and transmission X-ray absorption edge spectroscopy measurements. The actual composition is found to be about one-third of the nominal concentration up to 0.5, and resolves the discrepancy between the variation of the physical properties of single crystals and thin films with Yb concentration.« less

  18. UFe/sub 4/P/sub 12/ and CeFe/sub 4/P/sub 12/: non-metallic isotypes of superconducting LaFe/sub 4/P/sub 12/

    SciTech Connect (OSTI)

    Meisner, G.P.; Torikachvili, M.S.; Yang, K.N.; Maple, M.B.; Guertin, R.P.

    1984-01-01

    The new compound UFe/sub 4/P/sub 12/, which was found to be isostructural to superconducting LaFe/sub 4/P/sub 12/ and with a lattive constant of 7.7729 A, is a semiconductor and shows ferromagnetic order below 3.15 K. CeFe/sub 4/P/sub 12/ is also a semiconductor and its magnetic susceptibility is unusually small in comparison to LaFe/sub 4/P/sub 12/. The semiconducting behaviors of both UFe/sub 4/P/sub 12/ and CeFe/sub 4/P/sub 12/ seem anomalous and may arise from strong f-electron hybridization.

  19. UFe/sub 4/P/sub 12/ and CeFe/sub 4/P/sub 12/: Nonmetallic isotypes of superconducting LaFe/sub 4/P/sub 12/

    SciTech Connect (OSTI)

    Meisner, G.P.; Torikachvili, M.S.; Yang, K.N.; Maple, M.B.; Guertin, R.P.

    1985-04-15

    The new compound UFe/sub 4/P/sub 12/, which was found to be isostructural to superconducting LaFe/sub 4/P/sub 12/ and have a lattice constant of 7.7729 A, is a semiconductor and shows ferromagnetic order below 3.15 K. CeFe/sub 4/P/sub 12/ is also a semiconductor, and its magnetic susceptibility is unusually small in comparison to LaFe/sub 4/P/sub 12/. The semiconducting behaviors of both UFe/sub 4/P/sub 12/ and CeFe/sub 4/P/sub 12/ seem anomalous and may arise from strong f-electron hybridization.

  20. Crystal structure, magnetism and transport properties of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10}

    SciTech Connect (OSTI)

    Janka, Oliver; Baumbach, Ryan E.; Thompson, Joe D.; Bauer, Eric D.; Kauzlarich, Susan M.

    2013-09-15

    Single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10} were obtained from a process in which a polycrystalline sample of CeRu{sub 2}Al{sub 2}B was annealed in an excess of a Ni–In flux. The initial phase, CeRu{sub 2}Al{sub 2}B, does not recrystallize, instead, crystals of a new phase, Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10}, could be isolated once the flux was removed. The title compound crystallizes in the tetragonal space group P4/nmm (No. 129) with a=1139.02(8), c=801.68(6) pm (c/a=0.70) in the Nd{sub 3}Ni{sub 29}Si{sub 4}B{sub 10} structure type. Electrical resistivity measurements reveal metallic behavior with a minimum of 700 µ? cm and a small residual resistivity ratio of RRR=1.4 indicating a large amount of disorder scattering. The cerium atoms are either in the 4+ or an intermediate valence state with a valence fluctuation temperature far above room temperature. - Graphical abstract: Single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}A{sub l4.1}B{sub 10} were obtained using a process in which a polycrystalline sample of CeRu{sub 2}Al{sub 2}B was annealed in an excess of a Ni–In flux. Electrical resistivity measurements reveal metallic behavior with a minimum of 700 ?? cm and a small residual resistivity ratio of RRR=1.4 indicating a large amount of disorder scattering. The cerium atoms are either in the 4+ or an intermediate valence state with a valence fluctuation temperature far above room temperature. Display Omitted - Highlights: • Flux synthesis of high quality single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10} is presented along with the crystal structure, magnetic and transport properties. • The compound is isostructural to Nd{sub 3}Ni{sub 29}Si{sub 4}B{sub 10} but is first of this structure type showing mixed occupancies of d-elements. • This is an intermetallic phase with Ce in either the 4+ or an intermediate valence state. • The fact that this structure with mixed occupied transition metal sites exists suggests that more compounds of this type should be accessible and the physical properties tuned.

  1. Improvement of {gamma}-ray energy resolution of LaBr{sub 3}:Ce{sup 3+} scintillation detectors by Sr{sup 2+} and Ca{sup 2+} co-doping

    SciTech Connect (OSTI)

    Alekhin, M. S.; Haas, J. T. M. de; Khodyuk, I. V.; Dorenbos, P.; Kraemer, K. W.; Menge, P. R.; Ouspenski, V.

    2013-04-22

    Commercially available LaBr{sub 3}:5% Ce{sup 3+} scintillators show with photomultiplier tube readout about 2.7% energy resolution for the detection of 662 keV {gamma}-rays. Here we will show that by co-doping LaBr{sub 3}:Ce{sup 3+} with Sr{sup 2+} or Ca{sup 2+} the resolution is improved to 2.0%. Such an improvement is attributed to a strong reduction of the scintillation light losses that are due to radiationless recombination of free electrons and holes during the earliest stages (1-10 ps) inside the high free charge carrier density parts of the ionization track.

  2. SCINTILLATION PROPERTIES OF BaF2:Cd, BaF2, BaF2:Ce, BaF2:Sc, BaF2:Tm CRYSTALS AND CERAMICS; NEW PHOTOSENSORS FOR THE VACUUM ULTRAVIOLET REGION

    E-Print Network [OSTI]

    Titov, Anatoly

    SCINTILLATION PROPERTIES OF BaF2:Cd, BaF2, BaF2:Ce, BaF2:Sc, BaF2:Tm CRYSTALS AND CERAMICS; NEW crystals and ceramics doped with different elements in order to improve the light yield of the fast in the wavelength range from 190 to 600 nm. We used an improved method of ceramics production from the BaF2 powder

  3. In-situ and theoretical studies for the dissociation of water on an active Ni/CeO? catalyst: Importance of strong metal-support interactions for the cleavage of O-H bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carrasco, Javier; Rodriguez, Jose A.; Lopez-Duran, David; Liu, Zongyuan; Duchon, Tomas; Evans, Jaime; Senanayake, Sanjaya D.; Crumlin, Ethan J.; Matolin, Vladimir; Ganduglia-Pirovano, M. Veronica

    2015-03-23

    Water dissociation is crucial in many catalytic reactions on oxide-supported transition-metal catalysts. Here, supported by experimental and density-functional theory results, we elucidate the effect of the support on O-H bond cleavage activity for nickel/ceria systems. Ambient-pressure O1s photoemission spectra at low Ni loadings on CeO?(111) reveal a substantially larger amount of OH groups as compared to the bare support. Our computed activation energy barriers for water dissociation show an enhanced reactivity of Ni adatoms on CeO?(111) compared with pyramidal Ni? particles with one Ni atom not in contact with the support, and extended Ni(111) surfaces. At the origin of thismore »support effect is the ability of ceria to stabilize oxidized Ni²? species by accommodating electrons in localized f-states. The fast dissociation of water on Ni/CeO? has a dramatic effect on the activity and stability of this system as a catalyst for the water-gas shift and ethanol steam reforming reactions.« less

  4. In-situ and theoretical studies for the dissociation of water on an active Ni/CeO? catalyst: Importance of strong metal-support interactions for the cleavage of O-H bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carrasco, Javier [Inst. de Catalisis y Petroleoquimica, CSIC, Madrid (Spain); CIC Energigune, Minana, Alava (Spain); Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States); Lopez-Duran, David [Inst. de Catalisis y Petroleoquimica, CSIC, Madrid (Spain); CIC Energigune, Minana, Alava (Spain); Liu, Zongyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States); Duchon, Tomas [Charles Univ., Praha (Czech Republic); Evans, Jaime [Univ. Central de Venezuela, Caracas (Venezuela); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States); Crumlin, Ethan J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Matolin, Vladimir [Charles Univ., Praha (Czech Republic); Ganduglia-Pirovano, M. Veronica [Inst. de Catalisis y Petroleoquimica, CSIC, Madrid (Spain)

    2015-03-23

    Water dissociation is crucial in many catalytic reactions on oxide-supported transition-metal catalysts. Here, supported by experimental and density-functional theory results, we elucidate the effect of the support on O-H bond cleavage activity for nickel/ceria systems. Ambient-pressure O1s photoemission spectra at low Ni loadings on CeO?(111) reveal a substantially larger amount of OH groups as compared to the bare support. Our computed activation energy barriers for water dissociation show an enhanced reactivity of Ni adatoms on CeO?(111) compared with pyramidal Ni? particles with one Ni atom not in contact with the support, and extended Ni(111) surfaces. At the origin of this support effect is the ability of ceria to stabilize oxidized Ni²? species by accommodating electrons in localized f-states. The fast dissociation of water on Ni/CeO? has a dramatic effect on the activity and stability of this system as a catalyst for the water-gas shift and ethanol steam reforming reactions.

  5. Preparation and thermophysical properties of (Sm{sub 1?x}Er{sub x}){sub 2}Ce{sub 2}O{sub 7} oxides for thermal barrier coatings

    SciTech Connect (OSTI)

    Xiaoge, Chen; Shusen, Yang; Hongsong, Zhang; Gang, Li; Zhenjun, Li.; Bo, Ren; Xudan, Dang; Haoming, Zhang; An, Tang

    2014-03-01

    Graphical abstract: - Highlights: • These ceramic materials with fluorite structure were synthesized. • Defect points lead to their lower thermal conductivities. • The lower ionic radius of Er{sup 3+} ion leads to the reduction of thermal expansion coefficient of (Sm{sub 1?x}Er{sub x}){sub 2}Ce{sub 2}O{sub 7} oxides. - Abstract: (Sm{sub 1?x}Er{sub x}){sub 2}Ce{sub 2}O{sub 7} ceramics were synthesized by sol–gel method and sintered at 1600 °C for 10 h in air. The influence of Er{sub 2}O{sub 3}-substitution on the phase structure and thermophysical properties of Sm{sub 2}Ce{sub 2}O{sub 7} was investigated. The phase structures of these ceramics were identified by X-ray diffraction showing that all synthesized ceramics have fluorite-type structure. The measurements for thermophysical properties of these ceramics show that their thermal conductivities and thermal expansion coefficients remarkably decreased through Er-substitution. However, the thermal expansion coefficients were higher than that of YSZ and their thermal conductivities were much lower than that of 8YSZ. The excellent thermophysical property implies that these solid solutions are potential materials for the ceramics layer in thermal barrier coatings.

  6. A Brief Review of Past INL Work Assessing Radionuclide Content in TMI-2 Melted Fuel Debris: The Use of 144Ce as a Surrogate for Pu Accountancy

    SciTech Connect (OSTI)

    D. L. Chichester; S. J. Thompson

    2013-09-01

    This report serves as a literature review of prior work performed at Idaho National Laboratory, and its predecessor organizations Idaho National Engineering Laboratory (INEL) and Idaho National Engineering and Environmental Laboratory (INEEL), studying radionuclide partitioning within the melted fuel debris of the reactor of the Three Mile Island 2 (TMI-2) nuclear power plant. The purpose of this review is to document prior published work that provides supporting evidence of the utility of using 144Ce as a surrogate for plutonium within melted fuel debris. When the TMI-2 accident occurred no quantitative nondestructive analysis (NDA) techniques existed that could assay plutonium in the unconventional wastes from the reactor. However, unpublished work performed at INL by D. W. Akers in the late 1980s through the 1990s demonstrated that passive gamma-ray spectrometry of 144Ce could potentially be used to develop a semi-quantitative correlation for estimating plutonium content in these materials. The fate and transport of radioisotopes in fuel from different regions of the core, including uranium, fission products, and actinides, appear to be well characterized based on the maximum temperature reached by fuel in different parts of the core and the melting point, boiling point, and volatility of those radioisotopes. Also, the chemical interactions between fuel, fuel cladding, control elements, and core structural components appears to have played a large role in determining when and how fuel relocation occurred in the core; perhaps the most important of these reaction appears to be related to the formation of mixed-material alloys, eutectics, in the fuel cladding. Because of its high melting point, low volatility, and similar chemical behavior to plutonium, the element cerium appears to have behaved similarly to plutonium during the evolution of the TMI-2 accident. Anecdotal evidence extrapolated from open-source literature strengthens this logical feasibility for using cerium, which is rather easy to analyze using passive nondestructive analysis gamma-ray spectrometry, as a surrogate for plutonium in the final analysis of TMI-2 melted fuel debris. The generation of this report is motivated by the need to perform nuclear material accountancy measurements on the melted fuel debris that will be excavated from the damaged nuclear reactors at the Fukushima Daiichi nuclear power plant in Japan, which were destroyed by the Tohoku earthquake and tsunami on March 11, 2011. Lessons may be taken from prior U.S. work related to the study of the TMI-2 core debris to support the development of new assay methods for use at Fukushima Daiichi. While significant differences exist between the two reactor systems (pressurized water reactor (TMI-2) versus boiling water reactor (FD), fresh water post-accident cooing (TMI-2) versus salt water (FD), maintained containment (TMI-2) versus loss of containment (FD)) there remain sufficient similarities to motivate these comparisons.

  7. Downflow dryout in a heated ribbed vertical annulus with a cosine power profile (Results from test series ECS-2, WSR, and ECS-2cE)

    SciTech Connect (OSTI)

    Larson, T.K.; Anderson, J.L.; Condie, K.G.

    1990-12-01

    Experiments designed to investigate surface dryout in a heated, ribbed annulus test section simulating one of the annular coolant channels of a Savannah River Plant production reactor Mark 22 fuel assembly have been conducted at the Idaho National Engineering Laboratory. The inner surface of the annulus was constructed of aluminum and was electrically heated to provide an axial cosine power profile and a flat azimuthal power shape. Data presented in this report are from the ECS-2, WSR, and ECS-2cE series of tests. These experiments were conducted to examine the onset of wall thermal excursion for a range of flow, inlet fluid temperature, and annulus outlet pressure. Hydraulic boundary conditions on the test section represent flowrates (0.1--1.4 1/s), inlet fluid temperatures (293--345 K), and outlet pressures (-18--139.7 cm of water relative to the bottom of the heated length (61--200 cm of water relative to the bottom of the lower plenum)) expected to occur during the Emergency Coolant System (ECS) phase of postulated Loss-of-Coolant Accident in a production reactor. The onset of thermal excursion based on the present data is consistent with data gathered in test rigs with flat axial power profiles. The data indicate that wall dryout is primarily a function of liquid superficial velocity. Air entrainment rate was observed to be a strong function of the boundary conditions (primarily flowrate and liquid temperature), but had a minor effect on the power at the onset of thermal excursion for the range of conditions examined. 14 refs., 33 figs., 13 tabs.

  8. Quantum Critical Behavior in the Heavy Fermion Single Crystal Ce(Ni0.935Pd0.065)2Ge2

    SciTech Connect (OSTI)

    Wang, Cuihuan [ORNL; Lawrence, J M [University of California, Irvine; Christianson, Andrew D [ORNL; Chang, S [NIST Center for Neutron Research (NCRN), Gaithersburg, MD; Bauer, E D [Los Alamos National Laboratory (LANL); Gofryk, K [Los Alamos National Laboratory (LANL); Ronning, F [Los Alamos National Laboratory (LANL); Thompson, J D [Los Alamos National Laboratory (LANL); McClellan, K J [Los Alamos National Laboratory (LANL); Rodriguez-Rivera, J A [NCNR and University of Maryland; Lynn, J W [NIST Center for Neutron Research (NCRN), Gaithersburg, MD

    2011-01-01

    We have performed magnetic susceptibility, specific heat, resistivity, and inelastic neutron scattering measurements on a single crystal of the heavy Fermion compound Ce(Ni{sub 0.935}Pd{sup 0.065}){sub 2}Ge{sub 2}, which is believed to be close to a quantum critical point (QCP) at T = 0. At lowest temperature (1.8--3.5 K), the magnetic susceptibility behaves as {chi}(T)-{chi} (0) {proportional_to} T{sup -1/6} with {chi} (0) = 0.032 x 10{sup -6} m{sup 3}/mole (0.0025 emu/mole). For T < 1 K, the specific heat can be fit to the formula {Delta} C/T = {gamma}{sub 0} - T{sup 1/2} with {gamma}{sub 0} of order 700 mJ/mole-K{sup 2}. The resistivity behaves as {rho} = {rho}{sub 0} + AT{sup 3/2} for temperatures below 2 K. This low temperature behavior for {gamma} (T) and {rho} (T) is in accord with the SCR theory of Moriya and Takimoto. The inelastic neutron scattering spectra show a broad peak near 1.5 meV that appears to be independent of Q; we interpret this as Kondo scattering with T{sub K} = 17 K. In addition, the scattering is enhanced near Q=(1/2, 1/2, 0) with maximum scattering at {Delta} E = 0.45 meV{sup -}; we interpret this as scattering from antiferromagnetic fluctuations near the antiferromagnetic QCP.

  9. civil & environmental (CE) CE / ENE overview programs available

    E-Print Network [OSTI]

    Rohs, Remo

    ; scientific, social, legal and political aspects of environmental issues; air/water/land pollution and control and harbor structures, industrial facilities -- and addressing the prob- lems of ground water and air pollution as well as industrial and hazardous waste man- agement. They are also responsible for developing

  10. Almo: Order (2012-CE-1416)

    Broader source: Energy.gov [DOE]

    DOE ordered Almo Corporation to pay a $6,500 civil penalty after finding Almo had failed to certify that certain models of residential refrigerators comply with the applicable energy conservation standards.

  11. Keystone: Order (2013-CE-2601)

    Broader source: Energy.gov [DOE]

    DOE ordered Keystone Technologies, LLC to pay a $8,000 civil penalty after finding Keystone had failed to certify that certain models of fluorescent lamp ballasts comply with the applicable energy conservation standards.

  12. BSH: Order (2013-CE-2001)

    Broader source: Energy.gov [DOE]

    DOE ordered BSH Home Appliances Corp. to pay a $8,000 civil penalty after finding BSH had failed to certify that certain models of residential clothes washers comply with the applicable energy/water conservation standards.

  13. Leotek: Order (2013-CE-4903)

    Broader source: Energy.gov [DOE]

    DOE ordered Leotek Electronics USA Corp. to pay a $8,000 civil penalty after finding Leotek had failed to certify that certain models of traffic signal modules and pedestrian modules comply with the applicable energy conservation standards.

  14. Whirlpool: Order (2014-CE-21010)

    Broader source: Energy.gov [DOE]

    DOE ordered Whirlpool Corporation to pay a $8,000 civil penalty after finding Whirlpool had failed to certify that certain models of residential clothes dryers comply with the applicable energy conservation standards.

  15. Topaz: Order (2014-CE-35005)

    Broader source: Energy.gov [DOE]

    DOE ordered Topaz Lighting Corp. to pay a $8,000 civil penalty after finding Topaz had failed to certify that certain basic models of medium base compact fluorescent lamps, general service fluorescent lamps, and illuminated exit signs comply with the applicable energy conservation standards.

  16. NCBECS C&E 1979

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    includes tinted, reflective, insulated, or thermal pane ty;e of glass that, when installed in the exterior windows of a building., se . i: to reduce the rate of solar...

  17. CE Solar | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine:IAEAT Jump to:CBDCenter ofSolar Jump

  18. CE Geothermal | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine:Kansas: Energy Resources Jump to:Energy IncTool

  19. Crystal structures and luminescence properties of novel compounds K{sub 4}M{sub 2}[Al{sub 2}Si{sub 8}O{sub 24}] (M = Ce, Gd)

    SciTech Connect (OSTI)

    Aksenov, S. M., E-mail: aks.crys@gmail.com [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Rassulov, V. A. [Russian Academy of Sciences, Fedorovsky All-Russian Research Institute of Mineral Resources (Russian Federation)] [Russian Academy of Sciences, Fedorovsky All-Russian Research Institute of Mineral Resources (Russian Federation); Rastsvetaeva, R. K. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Taroev, V. K. [Russian Academy of Sciences, Institute of Geochemistry, Siberian Branch (Russian Federation)] [Russian Academy of Sciences, Institute of Geochemistry, Siberian Branch (Russian Federation)

    2013-11-15

    Two novel potassium rare earth silicates, obtained by hydrothermal synthesis, have been investigated by X-ray diffraction and described by the general formula K{sub 4}M{sub 2}[Al{sub 2}Si{sub 8}O{sub 24}] (M = Ce, Gd). The parameters of the monoclinic K{sub 4}Ce{sub 2}[Al{sub 2}Si{sub 8}O{sub 24}] and K{sub 4}Gd{sub 2}[Al{sub 2}Si{sub 8}O{sub 24}] cells are, respectively, as follows: a = 26.867(1), 26.6520(2) A; b = 7.4150(2), 7.2854(1) A; c = 14.910(1), 14.8182(1) A; {beta} = 123.52(1) Degree-Sign , 123.46(1) Degree-Sign ; and sp. gr. P2{sub 1}/n. The structures are solved by the charge flipping method and refined in the anisotropic approximation of thermal vibrations for atoms to R = 5.2 and 2.5%, respectively. The compounds under study are crystallized into a new structural type, which is based on two-level [Al{sub 2}Si{sub 8}O{sub 24}] layers, combined into a three-dimensional framework by columns of edge-sharing seven-vertex REE polyhedra. Potassium atoms are located in the framework channels. The spectral luminescence characteristics are determined. The luminescence bands are typical of Gd{sup 3+} and Ce{sup 3+} ions. Upon excitation by light with {lambda}{sub exc} = 246 nm, a band due to the {sup 2}D {yields} {sup 8}F{sub 5/2} transition with {lambda}{sub max} = 430 nm is observed in the spectrum of K{sub 4}Ce{sub 2}[Al{sub 2}Si{sub 8}O{sub 24}] and a band related to the {sup 6}P{sub 7/2} {yields} {sup 8}S{sub 7/2} transition with {lambda}{sub max} = 311 nm is observed in the spectrum of K{sub 4}Gd{sub 2}[Al{sub 2}Si{sub 8}O{sub 24}].

  20. An Electron Microscopy Investigation of the Transient Stage Oxidation Products in an Fe-22Cr Alloy with Ce and La Additions Exposed to Dry Air at 800 [degrees]C

    SciTech Connect (OSTI)

    Zhu, Jingxi; Fernandez Diaz, Laura M; Holcomb, Gordon R; Jablonski, Paul; Cowen, Christopher; Laughlin, David E; Alman, Dave; Seetharaman, Sridhar

    2011-01-01

    In this study, the effects of Ce (270 ppm) and La (120 ppm) mischmetal additions on the transient oxidation of an Fe-22Cr alloy were investigated. The oxidation process was imaged in situ using a confocal scanning laser microscope. The oxidation microstructures were studied by scanning electron microscopy, energy dispersive X-ray analysis, and transmission electron microscopy with the help of focused ion beam in situ lift-out specimen preparation. The Ce and La, referred to as reactive elements, were found in nonmetallic inclusion particles in the forms of oxides, sulfides, and phosphates. An affected zone formed around rare earth (RE)-containing inclusion particles at the alloy free surface during the transient oxidation. This zone consisted of an internal Cr-oxide formed beneath the particle as well as a thinner external oxide scale on the surface compared with the surroundings. The relation of this microstructure to oxidation kinetics is discussed. With time, the RE elements diffused into the scale from the RE particles on the alloy surface during the high-temperature exposure. A diffusion mechanism is presented to describe these observations.

  1. Long-range ordering of reduced magnetic moments in the spin-gap compound CeOs{sub 2}Al{sub 10} as seen via muon spin relaxation and neutron scattering

    SciTech Connect (OSTI)

    Adroja, D. T.; Hillier, A. D.; Kockelmann, W. A.; Anand, V. K.; Stewart, J. R.; Taylor, J. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot Oxon OX11 0QX (United Kingdom); Deen, P. P. [Institute Laue-Langevin, BP 156, 6 Rue Jules Horowitz, 38042 Grenoble Cedex (France); Strydom, A. M. [Physics Department, University of Johannesburg, P.O. Box 524, Auckland Park 2006 (South Africa); Muro, Y.; Kajino, J.; Takabatake, T. [Department of Quantum Matter, ADSM, and IAMR, Hiroshima University, Higashi-Hiroshima 739-8530 (Japan)

    2010-09-01

    We have carried out neutron diffraction, muon spin relaxation ({mu}SR), and inelastic neutron scattering (INS) investigations on a polycrystalline sample of CeOs{sub 2}Al{sub 10} to investigate the nature of the phase transition observed near 29 K in the resistivity and heat capacity. Our {mu}SR data clearly reveal coherent frequency oscillations below 28 K, indicating the presence of an internal field at the muon site, which confirms the long-range magnetic ordering of the Ce moment below 28 K. Upon cooling the sample below 15 K, unusual behavior of the temperature-dependent {mu}SR frequencies may indicate either a change in the muon site, consistent with the observation of superstructure reflections in electron diffraction, or a change in the ordered magnetic structure. Neutron diffraction data do not reveal any clear sign of either magnetic Bragg peaks or superlattice reflections. Furthermore, INS measurements clearly reveal the presence of a sharp inelastic excitation near 11 meV between 5 and 26 K, due to opening of a gap in the spin-excitation spectrum, which transforms into a broad response at and above 30 K. The magnitude of the spin gap (11 meV) as derived from the INS peak position agrees very well with the gap value as estimated from the bulk properties.

  2. Combined effect of chemical pressure and valence electron concentration through the electron-deficient Li substitution on the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system

    SciTech Connect (OSTI)

    Nam, Gnu; Jeon, Jieun; Kim, Youngjo; Kwon Kang, Sung; Ahn, Kyunghan; You, Tae-Soo

    2013-09-15

    Four members of the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system have been prepared by high-temperature reaction method and characterized by X-ray diffractions. All compounds crystallize in the orthorhombic Gd{sub 5}Si{sub 4}-type structure (space group Pnma, Pearson code oP16) with bonding interactions for interslab Ge{sub 2} dimers. The Li substitution for rare-earth elements in the RE{sub 4}LiGe{sub 4} system leads to a combined effect of the increased chemical pressure and the decreased valance electron concentration (VEC), which eventually results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type with all broken interslab Ge–Ge bond for the parental RE{sub 5}Ge{sub 4} to the Gd{sub 5}Si{sub 4}-type structure for the ternary RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. Site-preference between rare-earth metals and Li is proven to generate energetically the most favorable atomic arrangements according to coloring-problem, and the rationale is provided using both the size-factor and the electronic-factor related, respectively, to site-volume and electronegativity as well as QVAL values. Tight-binding, linear-muffin-tin-orbital (TB-LMTO) calculations are performed to investigate electronic densities of states (DOS) and crystal orbital Hamilton population (COHP) curves. The influence of reduced VEC for chemical bonding including the formation of interslab Ge{sub 2} dimers is also discussed. The magnetic property measurements prove that the non-magnetic Li substitution leads to the ferromagnetic (FM)-like ground state for Ce{sub 4}LiGe{sub 4} and the co-existence of antiferromagntic (AFM) and FM ground states for Sm{sub 4}LiGe{sub 4}. - Graphical abstract: Reported is a combined effect of the chemical pressure and the reduced VEC caused by the smaller monovalent non-magnetic Li substitution for the larger trivalent magnetic rare-earth metals in the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. This results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type to the Gd{sub 5}Si{sub 4}-type structure and the changes in magnetic properties. Display Omitted - Highlights: • Four Li-containing intermetallic compounds RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr and Sm) were synthesized. • The combined effect of the chemical pressure and the reduced VEC caused by Li substitution for a rare-earth metal results in the structure transformation. • Electronic structures and magnetic properties of title compounds were thoroughly investigated.

  3. Nanostructured crystals of fluorite phases Sr{sub 1-x}R{sub x}F{sub 2+x} and their ordering: VIII. Imperfect crystal structure of Sr{sub 0.71}Ce{sub 0.29}F{sub 2.29}

    SciTech Connect (OSTI)

    Sulyanova, E. A., E-mail: sulyanova@gmail.com; Karimov, D. N.; Sobolev, B. P. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)

    2013-09-15

    A congruently melting single crystal of nonstoichiometric phase Sr{sub 0.71}Ce{sub 0.29}F{sub 2.29} crystallizing into the CaF{sub 2} structural type (sp. gr Fm3-barm) has been studied by X-ray diffraction analysis. Vacancies in the main fluorine position 8c and interstitial anions in two 32f positions have been found. The ratio of the structural defects in the Sr{sub 0.71}Ce{sub 0.29}F{sub 2.29} solid solution corresponds to the tetrahedral configuration of the defect cluster (Sr{sub 4-n}Ce{sub n}F{sub 26})

  4. 90 Copublished by the IEEE CS and the AIP 1521-9615/11/$26.00 2011 IEEE Computing in SCienCe & engineering N o v E l A r C h I t E C t u r E S

    E-Print Network [OSTI]

    Dongarra, Jack

    - formance in traditional architectures; the primary factor influencing these limits is energy efficiencyCienCe Community T he Keeneland project--named for a historic thoroughbred horse racing track in Lexington software tools and applications for the full-scale system, which is due to be deployed in 2012. Keeneland

  5. Percolation theory and quantum critical systems: A new description of the critical behavior in Ce(Ru{sub 0.24}Fe{sub 0.76}){sub 2}Ge{sub 2}

    SciTech Connect (OSTI)

    Gaddy, John [Department of Physics and Astronomy, University of Missouri, Columbia, Missouri 65211 (United States); Heitmann, Tom, E-mail: HeitmannT@missouri.edu [Missouri Research Reactor, University of Missouri, Columbia, Missouri 65211 (United States); Montfrooij, Wouter [Department of Physics and Astronomy, University of Missouri, Columbia, Missouri 65211 (United States); Missouri Research Reactor, University of Missouri, Columbia, Missouri 65211 (United States)

    2014-05-07

    The onset of ordering in quantum critical systems is characterized by a competition between the Kondo shielding of magnetic moments and the ordering of these moments. We show how a distribution of Kondo shielding temperatures—resulting from chemical doping—leads to critical behavior whose main characteristics are given by percolation physics. With the aid of Monte Carlo computer simulations, we are able to infer the low temperature part of the distribution of shielding temperatures in heavily doped quantum critical Ce(Ru{sub 0.24}Fe{sub 0.76}){sub 2}Ge{sub 2}. Based on this distribution, we show that the ordering dynamics—such as the growth of the correlation length upon cooling—can be understood by the spawning of magnetic clusters. Our findings explain why the search for universal exponents in quantum critical systems has been unsuccessful: the underlying percolation network associated with the chemical doping of quantum critical systems has to be incorporated in the modeling of these quantum critical systems.

  6. Understanding Substrate Features Influenced by Pretreatments that Limit Biomass Deconstruction by Enzymes

    E-Print Network [OSTI]

    Gao, Xiadi

    2013-01-01

    Wyman C: Handbook on bioethanol: production and utilization.In Book Handbook on bioethanol: production and utilization (Balat H, Oz C: Progress in bioethanol processing. Prog Energ

  7. Understanding Substrate Features Influenced by Pretreatments that Limit Biomass Deconstruction by Enzymes

    E-Print Network [OSTI]

    Gao, Xiadi

    2013-01-01

    Wyman C: Handbook on bioethanol: production and utilization.In Book Handbook on bioethanol: production and utilization (for an efficient bioethanol production process based on

  8. PLUS: eating diSorderS n antibioticS and meat n fat tax Q&a Magazine of the geraLd J. and dorothy r. friedMan sChooL of nutrition sCienCe and poLiCy SSUUmmmmeer 2r 200112 V2 VooLL. 1. 133 nnoo. 2. 2

    E-Print Network [OSTI]

    Dennett, Daniel

    . friedMan sChooL of nutrition sCienCe and poLiCy SSUUmmmmeer 2r 200112 V2 VooLL. 1. 133 nnoo. 2. 2 this installment of "Ask Tufts Nutrition," Alexis Madej, N08, a clinical dietitian at the Frances Stern Nutrition, or provide an energy boost for a daily workout. A great combination for a satisfying snack is a mix

  9. Trends in Electrical Transport of p-type Skutterudites RFe4Sb12 (R-Na,K,Ca,Sr,Ba,La,Ce,Pr,Yb) from First Principles Calculations and Boltzmann Transport Theory

    SciTech Connect (OSTI)

    Yang, Jiong [Chinese Academy of Sciences; Qiu, P [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS); Liu, R [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS); Xi, L [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS); Zheng, S [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS); Zhang, W [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS); Chen, Lidong [Chinese Academy of Sciences; Singh, David J [ORNL

    2011-01-01

    We report a consistent set of ab initio calculations of the electronic structures and electrical transport properties of p-type thermoelectric compounds RFe{sub 4}Sb{sub 12}, where R is a rattling filler selected from alkali metals (Na, K), alkaline earths (Ca, Sr, Ba), and rare earth metals (La, Ce, Pr, Yb). Different from the single Sb-dominated light band in the valence band edge of CoSb{sub 3}, the heavy bands from Fe d electronic states also fall in the energy range close to the valence band edges in the RFe{sub 4}Sb{sub 12}. These heavy bands dominate the band-edge density of states, pin the Fermi levels, and mostly determine the electrical transport properties of those p-type RFe{sub 4}Sb{sub 12}. The Seebeck coefficients can be roughly categorized into three groups based on the charge states of fillers, and the maxima are lower than those of n-type CoSb{sub 3} skutterudites. Effective carrier relaxation time in p-type RFe{sub 4}Sb{sub 12}, obtained from the combinations of calculations and experiments, is remarkably similar among different compounds with values around 7.5 x 10{sup -15} s and weak temperature dependence. The optimal doping levels of those RFe{sub 4}Sb{sub 12} are estimated to be around 0.6-0.8 holes per unit cell at 850 K, which is difficult to achieve in RFe{sub 4}Sb{sub 12} compounds. Prospects for further improving the performance of p-type skutterudites are also discussed.

  10. Efficient Algorithms for Probing the RNA Mutation Jero^ me Waldispu hl1,2

    E-Print Network [OSTI]

    Clote, Peter

    the minimum free energy structure MFE(k) and the partition function Z(k) over all secondary structures of all, and reproduction in any medium, provided the original author and source are credited. Funding: PC is partially funded by NSF grant DBI-0543506. Competing Interests: The authors have declared that no competing

  11. Designing Computing System Architecture and Models for the HL-LHC era

    E-Print Network [OSTI]

    Lothar Bauerdick; Brian Bockelman; Peter Elmer; Stephen Gowdy; Matevz Tadel; Frank Wuerthwein

    2015-07-20

    This paper describes a programme to study the computing model in CMS after the next long shutdown near the end of the decade.

  12. Designing Computing System Architecture and Models for the HL-LHC era

    E-Print Network [OSTI]

    Bauerdick, Lothar; Elmer, Peter; Gowdy, Stephen; Tadel, Matevz; Wuerthwein, Frank

    2015-01-01

    This paper describes a programme to study the computing model in CMS after the next long shutdown near the end of the decade.

  13. Design and Prototyping of HL-LHC Double Quarter Wave Crab Cavities for SPS Test

    E-Print Network [OSTI]

    Verdú-Andrés, S; Wu, Q; Xiao, B P; Belomestnykh, S; Alberty, L; Artoos, Kurt; Calaga, Rama; Capatina, Ofelia; Capelli, Teddy; Carra, Federico; Leuxe, Raphael; Kuder, Norbert; Zanoni, Carlo; Li, Z; Ratti, A

    2015-01-01

    The LHC high luminosity project envisages the use of the crabbing technique for increasing and levelling the LHC luminosity. Double Quarter Wave (DQW) resonators are compact cavities especially designed to meet the technical and performance requirements for LHC beam crabbing. Two DQW crab cavities are under fabrication and will be tested with beam in the Super Proton Synchrotron (SPS) at CERN by 2017. This paper describes the design and prototyping of the DQW crab cavities for the SPS test.

  14. Rainfall-runoff modeling in a flashy tropical watershed using the distributed HL-RDHM model

    E-Print Network [OSTI]

    Hawai'i at Manoa, University of

    -prone Hanalei watershed in Kaua`i, Hawai`i. This rural watershed is very wet and has strong spatial rainfall gra of Hawai`i-Manoa, HI, USA d University of Hawai'i-Manoa, HI, USA e Hawaii Weather Forecast Office, National Weather Service, HI, USA f North Shore Hydro Consulting, Kauai, HI, USA a r t i c l e i n f o Article

  15. Measurements on HV-CMOS Active Sensors After Irradiation to HL-LHC fluences

    E-Print Network [OSTI]

    B. Ristic; for the ATLAS CMOS pixel collaboration

    2015-01-13

    During the long shutdown (LS) 3 beginning 2022 the LHC will be upgraded for higher luminosities pushing the limits especially for the inner tracking detectors of the LHC experiments. In order to cope with the increased particle rate and radiation levels the ATLAS Inner Detector will be completely replaced by a purely silicon based one. Novel sensors based on HV-CMOS processes prove to be good candidates in terms of spatial resolution and radiation hardness. In this paper measurements conducted on prototypes built in the AMS H18 HV-CMOS process and irradiated to fluences of up to $2\\cdot10^{16}\\,\\text{n}_\\text{eq}\\text{cm}^{-2}$ are presented.

  16. Combined L1 Trigger Tracker studies for HL-LHC upgrade 

    E-Print Network [OSTI]

    Dimas Valle, Jose Roberto Roberto

    2014-09-24

    needed for the studies on the Higgs sector. The upgrade also includes improvements on the detectors sensitivity to rare processes presenting signs of new physics, which could hold keys to the origins of dark matter and baryon asymmetry in the Universe...

  17. Technical report 348 Fann, H.L.; Detenbeck, R.W. PHYSICS; ANGULAR

    Office of Scientific and Technical Information (OSTI)

    the measurements. (auth) Maryland. Univ., College Park, MD (United States) US Atomic Energy Commission (AEC) United States 1964-01-01 English Conference Conference: American...

  18. FIBER PULLOUT BASED ON A ONE-DIMENSIONAL MODEL OF H.L. SCHREYER*

    E-Print Network [OSTI]

    bars in concrete, piles, fibers in ceramics, and many conventional composites. A knowledge of the force-displacement relation is an essential aspect for the development of a constitutive equation for the composite structure the interaction of the fiber with the surrounding matrix on the decohesion relation at the surface of the fiber

  19. HL7 FHIR: An Agile and RESTful Approach to Healthcare Information Exchange

    E-Print Network [OSTI]

    Sartipi, Kamran

    .bender@mohawkcollege.ca Kamran Sartipi, PhD, P.Eng. Dept. Electrical, Computer, and Software Eng. University of Ontario Institute.Eng. Dept. Electrical and Computer Eng. Technology Mohawk College Hamilton, ON, L8N 3T2, Canada duane embarked in the development of a new standard referred to as Fast Healthcare Interoperability Re- sources

  20. Aero-Tech: Order (2010-CE-1012)

    Broader source: Energy.gov [DOE]

    DOE issued an Order and closed this case against Aero-Tech Light Bulb Co., without civil penalty, after DOE found that Aero-Tech manufactured and/or privately labeled incandescent reflector lamps, but did not violate DOE regulations.

  1. Prizer-Painter: Order (2014-CE-23005)

    Broader source: Energy.gov [DOE]

    DOE ordered Prizer-Painter Stove Works, Inc. to pay a $8,000 civil penalty after finding Prizer-Painter had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

  2. GE Appliances: Proposed Penalty (2010-CE-2113)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that General Electric Appliances failed to certify a variety of dehumidifiers as compliant with the applicable energy conservation standards.

  3. GE Appliances: Order (2010-CE-2113)

    Broader source: Energy.gov [DOE]

    DOE issued an Order after entering into a Compromise Agreement with General Electric Appliances after finding GE Appliances had failed to certify that certain models of dehumidifiers comply with the applicable energy conservation standards.

  4. Euro Chef USA: Order (2014-CE-23004)

    Broader source: Energy.gov [DOE]

    DOE ordered Euro Chef USA Inc. to pay a $8,000 civil penalty after finding Euro Chef USA had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

  5. Elmira Stove Works: Order (2011-CE-1407)

    Broader source: Energy.gov [DOE]

    DOE ordered Elmira Stove Works to pay a $6,000 civil penalty after finding Elmira Stove Works had failed to certify that certain models of refrigerator-freezers comply with the applicable energy conservation standard.

  6. Stiebel Eltron: Order (2010-CE-1711)

    Broader source: Energy.gov [DOE]

    DOE ordered Stiebel Eltron, Inc. to pay a $5,000 civil penalty after finding Stiebel Eltron had failed to certify that certain models of water heaters comply with the applicable energy conservation standards.

  7. Stiebel Eltron: Proposed Penalty (2010-CE-1711)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Stiebel Eltron, Inc. failed to certify a variety of water heaters as compliant with the applicable energy conservation standards.

  8. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    (3 pages, 20 kb) CONTENTS PAGES Table 19. Distribution of Peak Watts per Square Foot and Load Factors, 1995 These data are from the 1995 Commercial Buildings Energy...

  9. Compression Testing Machine in CE Dept. 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    The Psychrometric Testing Facility at the Riverside Energy Efficiency Laboratory at Texas AandM University has not been operational for several years. The goal of this project was to restore the testing facility to a fully ...

  10. Engineered Solutions: Order (2010-CE-2112)

    Broader source: Energy.gov [DOE]

    DOE issued an Order after entering into a Compromise Agreement with Engineered Solutions, Inc. to resolve a case involving the failure to certify dehumidifier basic model SD109.

  11. Instrumentation of Steel Const. Award to CE 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    High energy neutron and proton radiation can induce serious damage in structural metals, including void swelling and embrittlement. Hence the design of advanced metallic materials with significantly enhanced radiation ...

  12. Amerikooler: Proposed Penalty (2013-CE-5307)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Amerikooler, Inc. failed to certify walk-in cooler or freezer (WICF) components as compliant with the energy conservation standards.

  13. Refrigerator Manufacturers: Proposed Penalty (2013-CE-5341)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Refrigerator Manufacturers, LLC failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  14. Cospolich Refrigerator: Proposed Penalty (2013-CE-5314)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Cospolich Refrigerator Co, Inc. failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

  15. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    Electricity Tables (35 pages, 218 kb) CONTENTS PAGES Table 9. Total Electricity Consumption and Expenditures, 1995 Table 10. Electricity Consumption and Expenditure Intensities,...

  16. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    kb) CONTENTS PAGES Table 1. Total Energy Consumption by Major Fuel, 1995 Table 9. Total Electricity Consumption and Expenditures, 1995 Table 20. Total Natural Gas Consumption and...

  17. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    pages, 95 kb) CONTENTS PAGES Table 3. Consumption for Sum of Major Fuels, 1995 Table 10. Electricity Consumption and Expenditure Intensities, 1995 Table 21. Natural Gas...

  18. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    Building Level Intensities (percentile) (6 pages, 39 kb) CONTENTS PAGES Table 10. Electricity Consumption and Expenditure Intensities, 1995 Table 21. Natural Gas Consumption and...

  19. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    kb) CONTENTS PAGES Table 2. Total Energy Expenditures by Major Fuel, 1995 Table 9. Total Electricity Consumption and Expenditures, 1995 Table 20. Total Natural Gas Consumption and...

  20. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    and Gross Energy Intensity by Census Region for Sum of Major Fuels, 1995 Table 11. Electricity Consumption and Conditional Energy Intensity by Census Region, 1995 Table 22....

  1. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    Major Fuel, 1995 Building Characteristics RSE Column Factor: All Buildings Total Energy Consumption (trillion Btu) Primary Electricity (trillion Btu) RSE Row Factor Number of...

  2. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    and Gross Energy Intensity by Year Constructed for Sum of Major Fuels, 1995 Table 14. Electricity Consumption and Conditional Energy Intensity by Year Constructed, 1995 Table...

  3. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    pages, 95 kb) CONTENTS PAGES Table 4. Expenditures for Sum of Major Fuels, 1995 Table10. Electricity Consumption and Expenditure Intensities, 1995 Table 21. Natural Gas...

  4. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    15. Season of Peak Electricity Demand, Number of Buildings and Floorspace, 1995 Table 16. Electricity Consumption and Conditional Energy Intensity by Season of Peak Demand, 1995...

  5. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    and Gross Energy Intensity by Building Size for Sum of Major Fuels, 1995 Table13. Electricity Consumption and Conditional Energy Intensity by Building Size, 1995 Table 24....

  6. Turolight: Withdrawal and Closure (2011-CE-2705)

    Broader source: Energy.gov [DOE]

    DOE withdrew the civil penalty notice issued to Turolight, Inc. after DOE discovered that Turolight does not sell covered products in the U.S.

  7. Ramblewood Green: Order (2014-CE-23017)

    Broader source: Energy.gov [DOE]

    DOE ordered Ramblewood Green Ltd. to pay a $8,000 civil penalty after finding Ramblewood Green had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

  8. Royal Centurion: Proposed Penalty (2012-CE-3608)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Royal Centurion, Inc., failed to certify two dehumidifiers as compliant with the energy conservation standards.

  9. Royal Centurion: Order (2012-CE-3608)

    Broader source: Energy.gov [DOE]

    DOE ordered Royal Centurion, Inc., to pay a $8,000 civil penalty after finding Royal Centurion had failed to certify that certain models of dehumidifiers comply with the applicable energy conservation standards.

  10. civil & environmental ce / ene overview programs available

    E-Print Network [OSTI]

    Rohs, Remo

    , earthquake engineering, tsunamis, geomechanics, structural control, transportation and construction

  11. Lumiram Electric: Proposed Penalty (2010-CE-1014)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Lumiram Electric Corporation failed to certify a variety of incandescent reflector lamps as compliant with the applicable energy conservation standards.

  12. Lumiram Electric: Order (2010-CE-1014)

    Broader source: Energy.gov [DOE]

    DOE issued an Order and entered into a Compromise Agreement with Lumiram Electric Corporation after finding Lumiram Electric had failed to certify that certain models of incandescent reflector lamps comply with the applicable energy conservation standards.

  13. Viking Range: Order (2014-CE-23014)

    Broader source: Energy.gov [DOE]

    DOE ordered Viking Range, LLC to pay a $8,000 civil penalty after finding Viking Range had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

  14. American Range: Order (2014-CE-23006)

    Broader source: Energy.gov [DOE]

    DOE ordered American Range Corporation to pay a $8,000 civil penalty after finding American Range had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

  15. R-Cold: Order (2013-CE-5354)

    Broader source: Energy.gov [DOE]

    DOE ordered R-Cold, Inc. to pay a $8,000 civil penalty after finding R-Cold had failed to certify that any basic models of walk-in cooler or freezer components comply with the applicable energy conservation standards.

  16. Keystone: Proposed Penalty (2013-CE-2601)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Keystone Technologies, LLC failed to certify a variety of fluorescent lamp ballasts as compliant with the applicable energy conservation standards.

  17. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    Fuel Oil Tables (10 pages, 58 kb) CONTENTS PAGES Table 26. Total Fuel Oil Consumption and Expenditures, 1995 Table 27. Fuel Oil Consumption and Expenditure Intensities, 1995 Table...

  18. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    Category (6 pages, 36 kb) CONTENTS PAGES Table 17. Peak Electricity Demand Category, Number of Buildings, 1995 Table 18. Peak Electricity Demand Category, Floorspace, 1995 These...

  19. USA Manufacturing: Order (2013-CE-5336)

    Broader source: Energy.gov [DOE]

    DOE ordered USA Manufacturing to pay a $8,000 civil penalty after finding USA Manufacturing had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

  20. Dade Engineering: Proposed Penalty (2013-CE-5316)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Dade Engineering Corp. failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

  1. Dade Engineering: Order (2013-CE-5316)

    Broader source: Energy.gov [DOE]

    DOE ordered Dade Engineering Corp. to pay a $8,000 civil penalty after finding Dade Engineering had failed to certify that certain models of walk-in cooler and freezer (WICF) components comply with the applicable energy conservation standards.

  2. Engineered Solutions: Proposed Penalty (2010-CE-2112)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Engineered Solutions, Inc. failed to certify a dehumidifier as compliant with the applicable energy conservation standards.

  3. BSH: Proposed Penalty (2013-CE-2001)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that BSH Home Appliances Corp. failed to certify a variety of residential clothes washers as compliant with the applicable energy/water conservation standards.

  4. Course No.: CE 511 Graduate Student

    E-Print Network [OSTI]

    Ervin, Elizabeth K.

    the frequencies of a bent-pile system using SAP2000 To see the mode shapes of the system in SAP2000 #12 of that project which satisfies both my course requirement and research goal #12;Bent-Pile System Pile Cap Piles I-55 Intermediate Bent System #12;Defining Section Properties in SAP2000 Pile Cap Section Pile Section

  5. Acme Kitchenettes: Proposed Penalty (2011-CE-1406)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Acme Kitchenettes Corp. failed to certify a variety of refrigerators as compliant with the applicable energy conservation standards.

  6. Acme Kitchenettes: Order (2011-CE-1406)

    Broader source: Energy.gov [DOE]

    DOE ordered Acme Kitchenettes Corp. to pay a $6,000 civil penalty after finding Acme Kitchenettes had failed to certify that certain models of refrigerators comply with the applicable energy conservation standards.

  7. Hayward Industries: Order (2010-CE-1110)

    Broader source: Energy.gov [DOE]

    DOE ordered Hayward Industries, Inc. to pay a $10,000 civil penalty after finding Hayward Industries had failed to certify that certain models of pool heaters comply with the applicable energy conservation standards.

  8. Hayward Industries: Proposed Penalty (2010-CE-1110)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Hayward Industries, Inc. failed to certify a variety of pool heaters as compliant with the applicable energy conservation standards.

  9. Heat Controller: Order (2011-CE-1507)

    Broader source: Energy.gov [DOE]

    DOE ordered Heat Controller, Inc. to pay a $6,000 civil penalty after finding Heat Controller had failed to certify that certain models of room air conditioners comply with the applicable energy conservation standards.

  10. Heat Controller: Proposed Penalty (2011-CE-1507)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Heat Controller, Inc. failed to certify a variety of room air conditioners as compliant with the applicable energy conservation standards.

  11. CIVIL & ENVIRONMENTAL CE / ENE OVERVIEW PROGRAMS AVAILABLE

    E-Print Network [OSTI]

    Rohs, Remo

    , industrial facilities and addressing the problems of ground water and air pollution as well as industrial with the treatment and proper disposal of environmental pollutants and developing techniques for improving our air. Air, water, and soil pollution control technologies; pollution prevention strategies. Design of simple

  12. civil & environmental ce / ene overview programs available

    E-Print Network [OSTI]

    Rohs, Remo

    , industrial facilities -- and addressing the problems of ground water and air pollution as well as industrial with the treatment and proper disposal of environmental pollutants and developing techniques for improving our air, water and soil. Innovative research areas include civil infrastructure, air pollution remedies

  13. Midea Washing Appliance: Order (2011-CE-1903)

    Broader source: Energy.gov [DOE]

    DOE ordered Midea Washing Appliance Mfg. Co., Ltd. to pay a $6,000 civil penalty after finding Midea Washing Appliance had failed to certify that certain models of dishwashers comply with the applicable energy conservation standards.

  14. CE 4990 -Construction Scheduling Spring Fling

    E-Print Network [OSTI]

    contract award, you have submitted your master schedule which shows completion in 28 working days. At the time of Notice to Proceed, owner informs you that he has redesigned the Int. Parts. (Act 3), the Ext that the additional complexity will: · Require 6 additional days of work on the Int. Parts., · Require 9 additional

  15. 1995 CECS C&E Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    reported for fewer than 20 buildings. Notes: * To obtain the RSE percentage for any table cell, multiply the corresponding RSE column and RSE row factors. * See Glossary for...

  16. Excellence Opto: Order (2013-CE-49002)

    Broader source: Energy.gov [DOE]

    DOE ordered Excellence Opto, Inc. to pay a $8,000 civil penalty after finding Excellence Opto had failed to certify that certain models of traffic signal modules and pedestrian modules comply with the applicable energy conservation standards.

  17. Act One: NPCP (2013-CE-49001)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Act One Communications, Inc. failed to certify a variety of traffic signal modules and pedestrian modules as compliant with the applicable energy conservation standards.

  18. Whirlpool: Proposed Penalty (2014-CE-21010)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Whirlpool Corporation failed to certify residential clothes dryers as compliant with the applicable energy conservation standards.

  19. USA Manufacturing: Proposed Penalty (2013-CE-5336)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that USA Manufacturing failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

  20. Hisense USA: Order (2010-CE-1211)

    Broader source: Energy.gov [DOE]

    DOE issued an Order after entering into a Compromise Agreement with Hisense USA Corp. after finding Hisense USA had failed to certify that certain models of residential refrigerators, refrigerator-freezers, and freezers comply with the applicable energy conservation standards.

  1. Hisense USA: Proposed Penalty (2010-CE-1211)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Hisense USA Corp. failed to certify a variety of residential refrigerators, refrigerator-freezers, and freezers as compliant with the applicable energy conservation standards.

  2. Topaz: Proposed Penalty (2014-CE-35005)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Topaz Lighting Corp. failed to certify a variety of basic models of medium base compact fluorescent lamps, general service fluorescent lamps, and illuminated exit signs as compliant with the applicable energy conservation standards.

  3. Instrumentation of Steel Const. Award to CE 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    Overheight vehicle impact to bridge decks is a major problem in the transportation networks in the United States. An important factor that causes this problem is inadequate vertical clearance of bridges. Using steel pedestals to elevate bridge decks...

  4. Nordyne: Order (2010-CE-01/0210)

    Broader source: Energy.gov [DOE]

    DOE ordered Nordyne, LLC d/b/a Garrison Heating and Cooling Products to pay a $10,000 civil penalty after finding Nordyne had failed to certify that certain models of central air conditioners and central air conditioning heat pumps comply with the applicable energy conservation standard.

  5. International Refrigeration: Proposed Penalty (2012-CE-1510)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that International Refrigeration Products failed to certify a various room air conditioners as compliant with the applicable energy conservation standards.

  6. International Refrigeration: Order (2012-CE-1510)

    Broader source: Energy.gov [DOE]

    DOE ordered International Refrigeration Products to pay an $8,000 civil penalty after finding International Refrigeration had failed to certify that certain room air conditioners comply with the applicable energy conservation standard.

  7. American Cooler Technologies: Order (2013-CE-5305)

    Broader source: Energy.gov [DOE]

    DOE ordered American Cooler Technologies to pay a $8,000 civil penalty after finding American Cooler Technologies had failed to certify that certain models of walk-in coolers or freezers (WICF) components comply with the applicable energy conservation standards.

  8. Microsoft Word - hCE1.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetection ofOctober 28,CatastrophictheJuly U.S.May

  9. CE Turbo Geothermal Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine:Kansas: Energy Resources Jump to:Energy IncToolTurbo Geothermal

  10. Oak Ridge Field O%ce

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the Weldon Spring,7=cr5rnP 7694 i+lJNewS e TAugustDOC F

  11. Syntheses, Structure, Magnetism, and Optical Properties of the Ordered Interlanthanide Copper Chalcogenides Ln{sub 2}YbCuQ{sub 5} (Ln = La, Ce, Pr, Nd, Sm; Q = S, Se): Evidence for Unusual Magnetic Ordering in Sm{sub 2}YbCuS{sub 5}

    SciTech Connect (OSTI)

    Jin, Geng Bang; Choi, Eun Sang; Guertin, Robert P.; Booth, Corwin H.; Albrecht-Schmitt, Thomas E.

    2010-11-19

    Ln{sub 2}YbCuQ{sub 5} (Ln = La, Ce, Pr, Nd, Sm; Q = S, Se) have been prepared by direct reaction of the elements in Sb{sub 2}Q{sub 3} (Q = S, Se) fluxes at 900 °C. All compounds have been characterized by single-crystal X-ray diffraction methods and they are isotypic. The structure of Ln{sub 2}YbCuQ{sub 5} consists of one-dimensional {sup 1}{sub {infinity}} [YbCuQ{sub 5}]{sup 6-} ribbons extending along the b axis that are connected by larger Ln{sup 3+} ions. Each ribbon is constructed from two single chains of [YbQ{sub 6}] octahedra with one double chain of [CuQ{sub 5}] trigonal bipyramids in the middle. All three chains connect with each other via edge-sharing. There are two crystallographically unique Ln atoms, one octahedral Yb site, and two disordered Cu positions inside of distorted Q{sub 5} trigonal bipyramids. Both Ln atoms are surrounded by eight Q atoms in bicapped trigonal prisms. The magnetic properties of Ln{sub 2}YbCuQ{sub 5} have been characterized using magnetic susceptibility and heat capacity measurements, while their optical properties have been explored using UV-vis-NIR diffuse reflectance spectroscopy. Cesub 2}YbCuSe{sub 5}, La{sub 2}YbCuS{sub 5}, Ce{sub 2}YbCuS{sub 5}, and Pr{sub 2}YbCuS{sub 5} are Curie-Weiss paramagnets. La{sub 2}YbCuSe{sub 5} and Nd{sub 2}YbCuS{sub 5} show evidence for short-range antiferromagnetic ordering at low temperatures. Sm{sub 2}YbCuS{sub 5} shows magnetic ordering at 5.9 K, followed by negative magnetization at low external fields. The band gaps of La{sub 2}YbCuSe{sub 5}, Ce{sub 2}YbCuSe{sub 5}, La{sub 2}YbCuS{sub 5}, Ce{sub 2}YbCuS{sub 5}, Pr{sub 2}YbCuS{sub 5}, Nd{sub 2}YbCuS{sub 5},and Sm{sub 2}YbCuS{sub 5} are 1.15 eV, 1.05 eV, 1.45 eV, 1.37 eV, 1.25 eV, 1.35 eV, and 1.28 eV respectively.

  12. A green-yellow emitting oxyfluoride solid solution phosphor Sr[subscript 2]Ba(AlO[subscript 4]F)[subscript 1;#8722;x](SiO[subscript 5])x:Ce[superscript 3+] for thermally stable, high color rendition solid state white lighting

    SciTech Connect (OSTI)

    Denault, Kristin A.; George, Nathan C.; Paden, Sara R.; Brinkley, Stuart; Mikhailovsky, Alexander A.; Neuefeind, Jörg; DenBaars, Steven P.; Seshadri, Ram (UCSB); (ORNL)

    2012-10-23

    A near-UV excited, oxyfluoride phosphor solid solution Sr{sub 1.975}Ce{sub 0.025}Ba(AlO{sub 4}F){sub 1-x}(SiO{sub 5}){sub x} has been developed for solid state white lighting applications. An examination of the host lattice, and the local structure around the Ce{sup 3+} activator ions through a combination of density functional theory, synchrotron X-ray and neutron powder diffraction and total scattering, and electron paramagnetic resonance, points to how chemical substitutions play a crucial role in tuning the optical properties of the phosphor. The maximum emission wavelength can be tuned from green ({lambda}{sub em} = 523 nm) to yellow ({lambda}{sub em} = 552 nm) by tuning the composition, x. Photoluminescent quantum yield is determined to be 70 {+-} 5% for some of the examples in the series. Excellent thermal properties were found for the x = 0.5 sample, with the photoluminescence intensity at 160 C only decreased to 82% of its room temperature value. Phosphor-converted LED devices fabricated using an InGaN LED ({lambda}{sub max} = 400 nm) exhibit high color rendering white light with R{sub a} = 70 and a correlated color temperature near 7000 K. The value of R{sub a} could be raised to 90 by the addition of a red component, and the correlated color temperature lowered to near 4000 K.

  13. Introduction to Nuclear Engineering CE497-1 CE Project (Undergraduate Students)

    E-Print Network [OSTI]

    Ervin, Elizabeth K.

    , and systems. Topics include history, fission, design principles, reactor systems, health physics, risk

  14. Was Wealth Really Determined in 8000 BCE, 1000 BCE, 0 CE, or Even 1500 CE?

    E-Print Network [OSTI]

    Thompson, William R; Sakuwa, Kentaro

    2013-01-01

    that might be introduced by casting the net farther down theSpecialization forging, casting) Land Transport 1 = human

  15. Was Wealth Really Determined in 8000 BCE, 1000 BCE, 0 CE, or Even 1500 CE?

    E-Print Network [OSTI]

    Thompson, William R; Sakuwa, Kentaro

    2013-01-01

    equal weight to ball point pens as they do to jet engines.13 Ball point pens and jet engines do not figure in the

  16. Bright three-band white light generated from CdSe/ZnSe quantum dot-assisted Sr{sub 3}SiO{sub 5}:Ce{sup 3+},Li{sup +}-based white light-emitting diode with high color rendering index

    SciTech Connect (OSTI)

    Jang, Ho Seong; Kwon, Byoung-Hwa; Jeon, Duk Young [Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Yang, Heesun [Department of Materials Science and Engineering, Hongik University, 72-1, Sangsu-dong, Mapo-gu, Seoul 121-791 (Korea, Republic of)

    2009-10-19

    In this study, bright three-band white light was generated from the CdSe/ZnSe quantum dot (QD)-assisted Sr{sub 3}SiO{sub 5}:Ce{sup 3+},Li{sup +}-based white light-emitting diode (WLED). The CdSe/ZnSe core/shell structure was confirmed by energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy. The CdSe/ZnSe QDs showed high quantum efficiency (79%) and contributed to the high luminous efficiency ({eta}{sub L}) of the fabricated WLED. The WLED showed bright natural white with excellent color rendering property ({eta}{sub L}=26.8 lm/W, color temperature=6140 K, and color rendering index=85) and high stability against the increase in forward bias currents from 20 to 70 mA.

  17. The Use of Horizontal Wells in Gas Production from Hydrate Accumulations

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    T (HL base) Geothermal gradient HL/FL permeability k r =k zmass fraction) Geothermal gradient HL/FL permeability k r =k

  18. The dependence of extracted current on discharge gas pressure in neutral beam ion sources on HL-2A tokamak

    SciTech Connect (OSTI)

    Wei, H. L.; Cao, J. Y.; Rao, J.; Lei, G. J.; Jiang, S. F.; Liu, H.; Yu, L. M.; Xie, W. M.; Li, M.; Yang, X. F.; Zou, G. Q.; Lu, D. L.; Duan, X. R.

    2012-02-15

    The discharge gas pressure is a key factor to influence the extracted current of ion source. In this paper, the dependence of extracted current on discharge gas pressure was investigated in detail at different arc discharge currents. The discharge gas pressure with a very broad range (0.1 Pa-2.7 Pa) was scanned for the first time. It is turned out that, with the increasing of discharge gas pressure, the extracted current increases and the arc voltage decreases at different arc currents; however, when the discharge gas pressure exceeds a certain value, the extracted current decreases. For the same discharge gas pressure, the higher the arc current, the higher the arc voltage and the extracted current are. The arc efficiency was also calculated, and its dependence on gas pressure was almost the same with the dependence of extracted current on gas pressure, but at the same discharge gas pressure, the lower the arc current, the higher the arc efficiency is and the lower the extracted current is.

  19. Stimuli materials from Roediger, H.L., & Karpicke, J.D. (2006b). Test-enhanced learning: Taking memory tests

    E-Print Network [OSTI]

    dwarf star. It is fueled by thermonuclear reactions near its center that convert hydrogen to helium temperature will fall. The higher temperature of the center will increase the rate of thermonuclear reactions to exist. Once the Sun has used up its thermonuclear energy as a red giant, it will begin to shrink. After

  20. Trapping in irradiated p-on-n silicon sensors at fluences anticipated at the HL-LHC outer tracker

    E-Print Network [OSTI]

    Adam, W; Dragicevic, M; Friedl, M; Fruehwirth, R; Hoch, M; Hrubec, J; Krammer, M; Treberspurg, W; Waltenberger, W; Alderweireldt, S; Beaumont, W; Janssen, X; Luyckx, S; Van Mechelen, P; Van Remortel, N; Van Spilbeeck, A; Barria, P; Caillol, C; Clerbaux, B; De Lentdecker, G; Dobur, D; Favart, L; Grebenyuk, A; Lenzi, Th; Léonard, A; Maerschalk, Th; Mohammadi, A; Perniè, L; Randle-Conde, A; Reis, T; Seva, T; Thomas, L; Velde, C Vander; Vanlaer, P; Wang, J; Zenoni, F; Zeid, S Abu; Blekman, F; De Bruyn, I; D'Hondt, J; Daci, N; Deroover, K; Heracleous, N; Keaveney, J; Lowette, S; Moreels, L; Olbrechts, A; Python, Q; Tavernier, S; Van Mulders, P; Van Onsem, G; Van Parijs, I; Strom, D A; Caudron, A; Ceard, L; De Callatay, B; Delaere, C; Pree, T Du; Forthomme, L; Giammanco, A; Hollar, J; Jez, P; Michotte, D; Nuttens, C; Perrini, L; Pagano, D; Quertenmont, L; Selvaggi, M; Marono, M Vidal; Beliy, N; Caebergs, T; Daubie, E; Hammad, G H; Härkönen, J; Lampén, T; Luukka, P -R; Mäenpää, T; Peltola, T; Tuominen, E; Tuovinen, E; Eerola, P; Tuuva, T; Beaulieu, G; Boudoul, G; Combaret, C; Contardo, D; Gallbit, G; Lumb, N; Mathez, H; Mirabito, L; Perries, S; Sabes, D; Donckt, M Vander; Verdier, P; Viret, S; Zoccarato, Y; Agram, J -L; Conte, E; Fontaine, J -Ch; Andrea, J; Bloch, D; Bonnin, C; Brom, J -M; Chabert, E; Charles, L; Goetzmann, Ch; Gross, L; Hosselet, J; Mathieu, C; Richer, M; Skovpen, K; Autermann, C; Edelhoff, M; Esser, H; Feld, L; Karpinski, W; Klein, K; Lipinski, M; Ostapchuk, A; Pierschel, G; Preuten, M; Raupach, F; Sammet, J; Schael, S; Schwering, G; Wittmer, B; Wlochal, M; Zhukov, V; Pistone, C; Fluegge, G; Kuensken, A; Geisler, M; Pooth, O; Stahl, A; Bartosik, N; Behr, J; Burgmeier, A; Calligaris, L; Dolinska, G; Eckerlin, G; Eckstein, D; Eichhorn, T; Fluke, G; Garcia, J Garay; Gizhko, A; Hansen, K; Harb, A; Hauk, J; Kalogeropoulos, A; Kleinwort, C; Korol, I; Lange, W; Lohmann, W; Mankel, R; Maser, H; Mittag, G; Muhl, C; Mussgiller, A; Nayak, A; Ntomari, E; Perrey, H; Pitzl, D; Schroeder, M; Seitz, C; Spannagel, S; Zuber, A; Biskop, H; Blobel, V; Buhmann, P; Centis-Vignali, M; Draeger, A -R; Erfle, J; Garutti, E; Haller, J; Hoffmann, M; Junkes, A; Lapsien, T; Mättig, S; Matysek, M; Perieanu, A; Poehlsen, J; Poehlsen, T; Scharf, Ch; Schleper, P; Schmidt, A; Sola, V; Steinbrück, G; Wellhausen, J; Barvich, T; Barth, Ch; Boegelspacher, F; De Boer, W; Butz, E; Casele, M; Colombo, F; Dierlamm, A; Eber, R; Freund, B; Hartmann, F; Hauth, Th; Heindl, S; Hoffmann, K -H; Husemann, U; Kornmeyer, A; Mallows, S; Muller, Th; Nuernberg, A; Printz, M; Simonis, H J; Steck, P; Weber, M; Weiler, Th; Bhardwaj, A; Kumar, A; Ranjan, K; Bakhshiansohl, H; Behnamian, H; Khakzad, M; Naseri, M; Cariola, P; De Robertis, G; Fiore, L; Franco, M; Loddo, F; Sala, G; Silvestris, L; Creanza, D; De Palma, M; Maggi, G; My, S; Selvaggi, G; Albergo, S; Cappello, G; Chiorboli, M; Costa, S; Giordano, F; Di Mattia, A; Potenza, R; Saizu, M A; Tricomi, A; Tuvè, C; Barbagli, G; Brianzi, M; Ciaranfi, R; Civinini, C; Gallo, E; Meschini, M; Paoletti, S; Sguazzoni, G; Ciulli, V; D'Alessandro, R; Gonzi, S; Gori, V; Focardi, E; Lenzi, P; Scarlini, E; Tropiano, A; Viliani, L; Ferro, F; Robutti, E; Vetere, M Lo; Gennai, S; Malvezzi, S; Menasce, D; Moroni, L; Pedrini, D; Dinardo, M; Fiorendi, S; Manzoni, R A; Azzi, P; Bacchetta, N; Bisello, D; Dall'Osso, M; Dorigo, T; Giubilato, P; Pozzobon, N; Tosi, M; Zucchetta, A; De Canio, F; Gaioni, L; Manghisoni, M; Nodari, B; Re, V; Traversi, G; Comotti, D; Ratti, L; Bilei, G M; Bissi, L; Checcucci, B; Magalotti, D; Menichelli, M; Saha, A; Servoli, L; Storchi, L; Biasini, M; Conti, E; Ciangottini, D; Fanò, L; Lariccia, P; Mantovani, G; Passeri, D; Placidi, P; Salvatore, M; Santocchia, A; Solestizi, L A; Spiezia, A; Androsov, K; Azzurri, P; Arezzini, S; Bagliesi, G; Basti, A; Boccali, T; Bosi, F; Castaldi, R; Ciampa, A; Cioccid, M A; Dell'Orso, R; Fedi, G; Giassi, A; Grippod, M T; Lomtadze, T; Magazzu, G; Mazzoni, E; Minuti, M; Moggi, A; Moond, C S; Morsani, F; Palla, F; Palmonari, F; Raffaelli, F; Savoy-Navarro, A; Serban, A T; Spagnolo, P; Tenchini, R; Venturi, A; Verdini, P G; Martini, L; Messineo, A; Rizzi, A; Tonelli, G; Calzolari, F; Donato, S; Fiori, F; Ligabue, F; Vernieri, C; Demaria, N; Rivetti, A; Bellan, R; Casasso, S; Costa, M; Covarelli, R; Migliore, E; Monteil, E; Musich, M; Pacher, L; Ravera, F; Romero, A; Solano, A; Trapani, P; Echeverria, R Jaramillo; Fernandez, M; Gomez, G; Moya, D; Sanchez, F J Gonzalez; Sanchez, F J Munoz; Vila, I; Virto, A L; Abbaneo, D; Ahmed, I; Albert, E; Auzinger, G; Berruti, G; Bianchi, G; Blanchot, G; Breuker, H; Ceresa, D; Christiansen, J; Cichy, K; Daguin, J; D'Alfonso, M; D'Auria, A; Detraz, S; De Visscher, S; Deyrail, D; Faccio, F; Felici, D; Frank, N; Gill, K; Giordano, D; Harris, P; Honma, A; Kaplon, J; Kornmayer, A; Kottelat, L; Kovacs, M

    2015-01-01

    The degradation of signal in silicon sensors is studied under conditions expected at the CERN High-Luminosity LHC. 200 $\\mu$m thick n-type silicon sensors are irradiated with protons of different energies to fluences of up to $3 \\cdot 10^{15}$ neq/cm$^2$. Pulsed red laser light with a wavelength of 672 nm is used to generate electron-hole pairs in the sensors. The induced signals are used to determine the charge collection efficiencies separately for electrons and holes drifting through the sensor. The effective trapping rates are extracted by comparing the results to simulation. The electric field is simulated using Synopsys device simulation assuming two effective defects. The generation and drift of charge carriers are simulated in an independent simulation based on PixelAV. The effective trapping rates are determined from the measured charge collection efficiencies and the simulated and measured time-resolved current pulses are compared. The effective trapping rates determined for both electrons and holes...

  1. Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass

    E-Print Network [OSTI]

    McKenzie, Heather Lorelei

    2012-01-01

    parameter. Appl. Biochem. Biotech. 1990; 24/25: 1-14. WymanASPEN-Plus®. Appl. Biochem. Biotech. 2004; 115: 1087-1102. (hydrolysis. Appl. Biochem. Biotech. 2001; 92: 377-386.

  2. Euro Chef USA: Proposed Penalty (2014-CE-23004)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Euro Chef USA Inc. failed to certify cooking products as compliant with the applicable energy conservation standards.

  3. Elmira Stove Works: Proposed Penalty (2011-CE-1407)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Elmira Stove Works failed to certify refrigerator-freezers as compliant with the energy conservation standards.

  4. 2014 Course Description Solid Waste Engineering -CE 477

    E-Print Network [OSTI]

    Barlaz, Morton A.

    on course web site http://people.engr.ncsu.edu/barlaz/ Solid Waste Technology & Management by Christensen et al (eBook available through NCSU libraries) Solid waste management must be addressed by virtually aspects of municipal solid waste (MSW) management including refuse generation, source reduction

  5. On preconditioning strategies for geotechnics C.E. Augarde

    E-Print Network [OSTI]

    Augarde, Charles

    : Iterative solvers are of increasing interest in geomechanics with the move towards 3D finite element not been widely adopted in geomechanics due to problems with convergence. This paper reviews the background material models, which form the basis for most complex material models used in geomechanics. We

  6. UNIVERSITY OF CALIFORNIA, BERKELEY CE212 Spring 2006 Environmental Engineering

    E-Print Network [OSTI]

    Hermanowicz, Slawomir W.

    Engin TD430 .W375 2005. Reference Readings: Design of Municipal Wastewater Treatment Plants. Water and wastewater treatment, and water reclamation: separation and transformation technologies (sedimentation, membrane processes, oxidation, biodegradation, activated sludge, biofilm reactors, biological treatment

  7. Duracold Refrigeration Manufacturing: Proposed Penalty (2013-CE-5342)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Duracold Refrigeration Manufacturing Company, LLC failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  8. Commercial Refrigerator Door: Proposed Penalty (2013-CE-5351)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Commercial Refrigerator Door Company, Inc. failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  9. Report 2012 www.stride.ce.ufl.edu

    E-Print Network [OSTI]

    Zapletal, Jindrich

    LEGO® Robot Vehicle Lesson Plans 25 Technology Transfer 26 WTS Transportation Symposium 26 UFTI for the Southeastern Region 30 WTS Advancing Women in Transportation Student Chapter Creation 32 Webinars 33

  10. ALiCE: A Java-based Grid Computing System

    E-Print Network [OSTI]

    Teo, Yong Meng

    A computational grid is a hardware and software infrastructure that provides dependable, consistent, pervasive, and inexpensive access to high-end computational capabilities. This talk is divided into three parts. Firstly, ...

  11. Aucma Group: Withdrawal and Closure (2011-CE-1405)

    Broader source: Energy.gov [DOE]

    DOE withdrew the civil penalty notice issued to Aucma Group (aka Qingdao Aucma Import and Export Co., Ltd.) after DOE discovered that Aucma Group does not sell covered products in the U.S.

  12. Unionaire Group: Withdrawal and Closure (2011-CE-1508)

    Broader source: Energy.gov [DOE]

    DOE withdrew the civil penalty notice issued to Unionaire Group after DOE discovered that Unionaire does not sell covered products in the U.S.

  13. Commercial Cooling Par Engineering: Proposed Penalty (2013-CE-5312)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Commercial Cooling Par Engineering failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

  14. civil & environmental ce / ene overview majors & areas of emphasis

    E-Print Network [OSTI]

    Rohs, Remo

    , earthquake engineering, tsunamis, geomechanics, structural control, transportation and construction

  15. CIVIL&ENVIRONMENTAL CE / ENE OVERVIEW MAJORS & AREAS OF EMPHASIS

    E-Print Network [OSTI]

    Rohs, Remo

    remedies, earthquake engineering, tsunamis, geomechanics, structural control, water quality, transportation

  16. -A --Science &&80ce Feature Dr. Charles F, Frooks,

    E-Print Network [OSTI]

    the tempefature of the lake becomes 39 degrees throughout. than the water below and remains at the top, and ice Meteorologicel Society Says: LAKE WATERS GETTING COLD- During the summer t e urface temperatures of most lakes the penetration of summer heat the temperature remained at,89 degrees Fahrenheit, the temperature of fresh water

  17. Felix Storch: Order (2010-CE-03/04/0613)

    Broader source: Energy.gov [DOE]

    DOE ordered Felix Storch, Inc. to pay a $5,000 civil penalty after finding Felix Storch had failed to certify that basic model DW 2432, a dishwasher, complies with the applicable energy conservation standards.

  18. Felix Storch: Proposed Penalty (2010-CE-03/04/0613)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Felix Storch, Inc. failed to certify a variety of residential dishwashers, clothes washers and dryers as compliant with the applicable energy conservation standards.

  19. R-Cold: Proposed Penalty (2013-CE-5354)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that R-Cold, Inc. failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  20. 1992 CBECS C&E Table 3.29

    U.S. Energy Information Administration (EIA) Indexed Site

    per Square Foot and Load Factors, 1992 Building Characteristics RSE Column Factor: All Demand-Metered Buildings Peak Watts per Square Foot Load Factor RSE Row Factor Number of...

  1. CBECS 1992 - C&E Detailed Table Word Definitions

    U.S. Energy Information Administration (EIA) Indexed Site

    in the Northeast that used electricity as an energy source used 9.3 kilowatthours of electricity per square foot." Demand-Metered Buildings--Buildings that have meters to...

  2. CE 4990 -Construction Scheduling Integrating Cost and Schedule

    E-Print Network [OSTI]

    ) = BCWP/BCWS · Cost Variance (CV) = BCWP - ACWP · Cost Performance Index (CPI) = BCWP/ACWP · EAC = ACWPCE 4990 - Construction Scheduling Integrating Cost and Schedule March 16, 2012 Definitions The goal is to develop integrated metrics for measuring cost and schedule performance. This note provides guidelines

  3. A_ Scior!,ce Servi-$5 Feittura. ? WY THE FEATHER? ?

    E-Print Network [OSTI]

    autumn $8 not disputed' Occur at lrequent i n t e r v a l s over tho North A t l a n t i c throughout the cold montha~from September t o March, and occasionally euch n disturbance coincides with the equinox

  4. ASKO Appliances: Proposed Penalty (2012-CE-19/2004)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that ASKO Appliances, Inc. failed to certify residential clothes washers and dishwashers as compliant with the applicable energy and water conservation standards.

  5. LG: Proposed Penalty (2015-CE-14022) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    January 15, 2015 DOE alleged in a Notice of Proposed Civil Penalty that LG Electronics USA, Inc. failed to certify various refrigerator-freezer basic models as compliant with the...

  6. Commercial Cooling Par Engineering: Order (2013-CE-5312)

    Broader source: Energy.gov [DOE]

    DOE ordered Commercial Cooling Par Engineering, Inc. to pay a $8,000 civil penalty after finding Commercial Cooling Par Engineering had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

  7. ASKO Appliances: Order (2012-CE-19/2004)

    Broader source: Energy.gov [DOE]

    DOE ordered ASKO Appliances, Inc. to pay a $36,500 civil penalty after finding ASKO had failed to certify that certain models of residential dishwashers and clothes washers comply with the applicable energy and water conservation standards.

  8. Student Orientation Guide CE W30/ME W85

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    by Govindjee: Oxford University Press. ISBN: 9780199651641 2. Computer Requirements Internet o High.6 and newer o Linux ­ chromeOS Computer Speed and Processor o Use a computer five years old or newer when settings (only takes a minute) o Choose Settings from top right HELP menu o Customize your settings and add

  9. Fagor America: Proposed Penalty (2011-CE-14/1908)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Fagor America, Inc. failed to certify a variety of refrigerators and dishwashers as compliant with the applicable energy conservation standards.

  10. Fagor America: Order (2011-CE-14/1908)

    Broader source: Energy.gov [DOE]

    DOE ordered Fagor America, Inc. to pay a $6,000 civil penalty after finding Fagor America had failed to certify that certain models of refrigerators and dishwashers comply with the applicable energy conservation standards.

  11. AeroSys: Proposed Penalty (2010-CE-01/0201)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that AeroSys, Inc. failed to certify residential central air conditioners and air conditioning heat pumps as compliant with the applicable energy conservation standards.

  12. Aero-Tech: Proposed Penalty (2010-CE-1012)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Aero-Tech Light Bulb Co. failed to certify a variety of incandescent reflector lamps as compliant with the applicable energy conservation standards.

  13. CIVIL&ENVIRONMENTAL CE / ENE OVERVIEW PROGRAMS AVAILABLE

    E-Print Network [OSTI]

    Rohs, Remo

    , industrial facilities -- and addressing the problems of ground water and air pollution as well as industrial with the treatment and proper disposal of environmental pollutants and developing techniques for improving our air Introduction to Environmental Engineering (3, Fa) Basic concepts of environmental engineering. Air, water

  14. CIVIL&ENVIRONMENTAL CE / ENE OVERVIEW PROGRAMS AVAILABLE

    E-Print Network [OSTI]

    Rohs, Remo

    , industrial facilities -- and addressing the problems of ground water and air pollution as well as industrial with the treatment and proper disposal of environmental pollutants and developing techniques for improving our air. Air, water, and soil pollution control technologies; pollution prevention strategies. Design of simple

  15. Midea Washing Appliance: Proposed Penalty (2011-CE-1903)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Midea Washing Appliances Mfg. Co., Ltd. failed to certify a variety of dishwashers as compliant with the applicable water and energy conservation standards.

  16. Golden Opportunity: Order (2014-CE-20003) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Golden Opportunity had failed to certify that certain models of room air conditioners, central air conditionersheat pumps, and residential clothes washers comply with the...

  17. CE 466/ 566 Highway Geometric Design Fall 2010 Course Syllabus

    E-Print Network [OSTI]

    Hickman, Mark

    Officials (AASHTO), A Policy on Geometric Design of Highways and Streets, 5th Edition, 2004. Other materials Student Code of Conduct, in accordance with the Code of Academic Integrity. This code is published at http

  18. www.kit.edu CompetenCe e

    E-Print Network [OSTI]

    Schmitt, Peter H.

    -Mail: britta.crocoll@kit.edu Elektrische Energiespeicher und Antriebssysteme Competence E ­ ein Energiespeicher- materialien. KIT verbindet die Nanotechnologie mit modernsten Methoden der Materialforschung. KIT- schwerpunkt elektrische Energiespeicher und den damit verbundenen elektrischen Antriebssystemen überneh- men

  19. DuraLamp USA: Proposed Penalty (2010-CE-0912)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that DuraLamp USA, Inc. failed to certify a variety of general service fluorescent lamps as compliant with the applicable energy conservation standards.

  20. Smeg USA: Order (2011-CE-14/1909)

    Broader source: Energy.gov [DOE]

    DOE ordered Smeg USA, Inc. to pay a $6,000 civil penalty after finding Smeg USA had failed to certify that certain models of dishwashers and refrigerators comply with the applicable energy conservation standards.

  1. DuraLamp USA: Order (2010-CE-0912)

    Broader source: Energy.gov [DOE]

    DOE ordered DuraLamp USA, Inc. to pay a $2,500 civil penalty after finding DuraLamp USA had failed to certify that model PAR 30, an incandescent reflector lamp, complies with the applicable energy conservation standards.

  2. Smeg USA: Proposed Penalty (2011-CE-14/1909)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Smeg USA, Inc. failed to certify a variety of dishwashers and refrigerators as compliant with the applicable energy conservation standards.

  3. De'Longhi USA: Order (2010-CE-2114)

    Broader source: Energy.gov [DOE]

    DOE issued an Order after entering into a Compromise Agreement with De'Longhi USA, Inc. to resolve a case involving the failure to certify that a variety of dehumidifiers comply with the applicable energy conservation standards.

  4. De'Longhi USA: Proposed Penalty (2010-CE-2114)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that De'Longhi USA, Inc. failed to certify a variety of dehumidifiers as compliant with the applicable energy conservation standards.

  5. CE 372 Engineering Hydrology and Hydraulics Learning objectives

    E-Print Network [OSTI]

    Rehmann, Chris

    what you should be able to do by the end of the class. Use them to guide your learning and study infiltration and explain the infiltration process in terms a non-technical per- son can understand. Estimate infiltration rates and cumulative infiltration with the Horton model. Explain ponding. Identify cases

  6. Nordyne: Proposed Penalty (2010-CE-01/0210)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Nordyne, LLC d/b/a Garrison Heating and Cooling Products failed to certify various residential central air conditioners and central air conditioning heat pumps as compliant with the applicable energy conservation standards.

  7. How clinical prac,ce recommenda,on are developed

    E-Print Network [OSTI]

    Shihadeh, Alan

    to the recommendation outweigh the undesirable effects (or vice versa). ­Con of evidence · Hormone replacement therapy in postmenopausal women · Anti-arrythmic agents

  8. Mixture Interpretation Discussion CE User's Group J.M. Butler

    E-Print Network [OSTI]

    workbook with worked examples · Considering flow charts to aid mixture interpretation · Have discussed of Forensic Genetics · An international organization responsible for

  9. ue Ce ec o o es o a Energy Efficiency &

    E-Print Network [OSTI]

    Cell Bus Evaluation DOE (FCT-Tech .Val.), NREL, and FTA are working closely to evaluate fuel cell phenomena improving MEA and stack performance · Optimize fuel cells and systems for early market Fleets: Summary of Experiences andy y p Current Status (September 2007), NREL/TP-560-41967, http://www.nrel

  10. Bull Outdoor Products: Proposed Penalty (2015-CE-14014)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Bull Outdoor Products, Inc. failed to certify refrigerator basic model BC-130 as compliant with the applicable energy conservation standards.

  11. American Cooler Technologies: Proposed Penalty (2013-CE-5305)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that American Cooler Technologies failed to certify walk-in coolers and freezer (WICF) components as compliant with the energy conservation standards.

  12. CRAD, NNSA - Conduct of Engineering (CE) | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About UsEnergy MarketingAsset Score00.4 (12-84)ThisFeaturedDepartment

  13. Sanyo Electric: Order (2010-CE-1210) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 -RobSSL INDepartment of Energy San10

  14. RPI: Order (2015-CE-42065) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7, 2011REMSView ValidationRESRAD-BIOTA

  15. RPI: Proposed Penalty (2015-CE-42065) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7, 2011REMSView ValidationRESRAD-BIOTAProposed Penalty

  16. PQL: Proposed Penalty (2013-CE-27001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrder 422.1, CONDUCT P - . . - - 4PORTSFUTUREOrder

  17. CE2 Carbon Capital LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine:Kansas: Energy Resources Jump to:Energy IncToolTurbo

  18. EIS-0497: CE FLNG Project, Plaquemines Parish, Louisiana | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n cEnergy (AZ, CA, CO,Department of EnergyEnergy Summary The

  19. Maxlite: Order (2010-CE-2701) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof Energy ThisSitesStorage CenterEngine | Department

  20. Maxlite: Order (2015-CE-27018) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof Energy ThisSitesStorage CenterEngine | Department DOE

  1. Maxlite: Proposed Penalty (2015-CE-27018) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof Energy ThisSitesStorage CenterEngine | Department

  2. CE2 Capital Partners LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County, California: Energy Resources JumpEmissionCapital Partners LLC Jump

  3. Barron: Order (2013-CE-48004) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p uBUS SERVICE SUBSIDIESDepartment of EnergyJuly 15, 2015

  4. Barron: Proposed Penalty (2013-CE-48004) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p uBUS SERVICE SUBSIDIESDepartment of EnergyJuly 15,

  5. Bull Outdoor Products: Order (2015-CE-14014) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l DeInsulation at the EdgeBUILDINGS-TO-GRID

  6. Atlas Lighting: Order (2015-CE-48001) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u tCorporationIt's PotentialDepartment ofEnergy

  7. Atlas Lighting: Proposed Penalty (2015-CE-48001) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u tCorporationIt's PotentialDepartment ofEnergy5 DOE

  8. Atosa: Order (2015-CE-42037) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u tCorporationIt's PotentialDepartmentAtmosphereAugust 31,

  9. Atosa: Proposed Penalty (2015-CE-42037) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u tCorporationIt's PotentialDepartmentAtmosphereAugust

  10. Curtis: Order (2015-CE-14021) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartmentEnergyEvery Thanksgiving,isjpgcurrentProjects< Back5

  11. Absocold: Order (2010-CE-1212) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s sconveyance(EPACT 2005) and the Energy

  12. Almo: Order (2012-CE-1416) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y AEfficiency Rebate Programs |EfficiencyEfficiencyDOE

  13. Legacy: Order (2015-CE-14025) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICE INDUSTRIALU.S.Leadership on Clean Energys o u t h e a s tLeasingto

  14. Danby Products: Order (2012-CE-1415) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 20153 METHODSDOE/LaborSeptemberEnergyDan Utech About

  15. Distinctive Appliances: Order (2015-CE-14019) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8,Department of Energy2EM's CleanupPower

  16. EIS-0497: CE FLNG Project, Plaquemines Parish, Louisiana | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|DepartmentStatement |toDepartment of Energy Notice of

  17. Eurodib: Order (2014-CE-45001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 InfographiclighbulbsDepartment ofServices3ErnestCorporateOrder

  18. Eurodib: Proposed Penalty (2014-CE-45001) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 InfographiclighbulbsDepartment ofServices3ErnestCorporateOrderProposed

  19. Eaton Cooper: Order (2015-CE-48003) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|DepartmentStatementofApril 25,EV Everywhere| DepartmentZones 1

  20. Eaton Cooper: Proposed Penalty (2015-CE-48003) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|DepartmentStatementofApril 25,EV Everywhere| DepartmentZones 1Proposed