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1

Interactive Caustics Using Local Precomputed Irradiance Chris Wyman Charles Hansen Peter Shirley  

E-Print Network [OSTI]

School of Computing, The University of Utah Salt Lake City, Utah, USA Abstract Bright patterns of lightInteractive Caustics Using Local Precomputed Irradiance Chris Wyman Charles Hansen Peter Shirley

Wyman, Chris

2

Review: Continuous hydrolysis and fermentation for cellulosic ethanol production Simone Brethauer, Charles E. Wyman *  

E-Print Network [OSTI]

, Charles E. Wyman * Center for Environmental Research and Technology and Chemical and Environmental costs, and reduced vessel down time for cleaning and filling. On the other hand, these systems are more the world uses, far more than derived from coal, natural gas, hydroelectric power, nuclear energy

California at Riverside, University of

3

Fuel Etanol from Cellulosic Biomass LEE R. LYND, JANET H. CusHmAN, ROBERTA J. NICHOLS, CHARLES E. WYMAN  

E-Print Network [OSTI]

exploration and production become more expensive and as the cost and volume of imports increase (4). Energy, Dearborn, MI 48121. C. E. Wyman manages the Biotechnology Research Branch, Solar Energy Research Institute. Desirable features in- clude ethanol's fuel properties as well as benefits with respect to urban air quality

California at Riverside, University of

4

Qualitative and quantitative features of orbits of massive particles and photons moving in Wyman geometry  

E-Print Network [OSTI]

The Wyman's solution depends on two parameters, the mass $M$ and the scalar charge $\\sigma$. If one fixes $M$ to a positive value, say $M_0$, and let $\\sigma^2$ take values along the real line it describes three different types of spacetimes. For $\\sigma^2 >0$ the spacetimes are naked singularities, for $\\sigma^2 = 0$ one has the Schwarzschild black hole of mass $M_0$ and finally for $-M_0^2 \\leq \\sigma^2 0$, there is an infinity potential wall that prevents both massive particles and photons ever to reach the naked singularity. We notice, also, that for certain values of $-M_0^2 \\leq \\sigma^2 < 0$, the potential is finite everywhere, which allows massive particles and photons moving from one wormhole asymptotically flat region to the other. We also compute the radial timelike and null geodesics for massive particles and photons, respectively, moving in the naked singularities and wormholes spacetimes.

G. Oliveira-Neto; G. F. Sousa

2008-01-29T23:59:59.000Z

5

HL&P/Du Pont Cogeneration Project  

E-Print Network [OSTI]

. Supplementary fireable HRSG's provide additional supply reliability for the steam host. Electricity from the project is delivered into HL&P's System through a new 138 KY substation. Such an arrangement offers Du Pont a significant cost saving opportunity as less...

Vadie, H. H.

2013-06-06T23:59:59.000Z

6

Massachusetts Beryllium Screening Program for Former Workers of Wyman-Gordon, Norton Abrasives, and MIT/Nuclear Metals  

SciTech Connect (OSTI)

The overall objective of this project was to provide medical screening to former workers of Wyman-Gordon Company, Norton Abrasives, and MIT/Nuclear Metals (NMI) in order to prevent and minimize the health impact of diseases caused by site related workplace exposures to beryllium. The program was developed in response to a request by the U.S. Department of Energy (DOE) that had been authorized by Congress in Section 3162 of the 1993 Defense Authorization Act, urging the DOE to â??carry out a program for the identification and ongoing evaluation of current and former DOE employees who are subjected to significant health risks during such employment." This program, funded by the DOE, was an amendment to the medical surveillance program for former DOE workers at the Nevada Test Site (NTS). This programâ??s scope included workers who had worked for organizations that provided beryllium products or materials to the DOE as part of their nuclear weapons program. These organizations have been identified as Beryllium Vendors.

Pepper, L.D.

2008-05-21T23:59:59.000Z

7

First Neutron Spectrometry Measurement at the HL-2A Tokamak  

E-Print Network [OSTI]

A compact neutron spectrometer based on the liquid scintillator is presented for the neutron energy spectrum measurement at the HL-2A tokamak. The spectrometer has been well characterized and a fast digital pulse shape discrimination software has been developed using the charge comparison method. A digitizer data acquisition system with the maximum frequency of 1 MHz can work under the high count rate environment at HL-2A. Specific radiation shielding and magnetic shielding for the spectrometerhas been designed for the neutron spectrum measurement at the HL-2A Tokamak. For the analysis of the pulse height spectrum, dedicated numerical simulation utilizing NUBEAM combining with GENESIS has been made to obtain the neutron energy spectrum, following which the transportation process from the plasma to the detector has been evaluated with Monte Carlo calculations. The distorted neutron energy spectrum has been folded with response matrix of the liquid scintillation spectrometer, and good consistency has been found...

Xi, Yuan; Xufei, Xie; Zhongjing, Chen; Xingyu, Peng; Tieshuan, Fan; Jinxiang, Chen; Xiangqing, Li; Guoliang, Yuan; Jinwei, Yang; Qingwei, Yang

2013-01-01T23:59:59.000Z

8

E-Print Network 3.0 - adding hl7 version Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Communications Organisations Security & Deonthology 12;Didier... of standardization of interchange among HC applications HL7 s interchange of healthcare...

9

First Neutron Spectrometry Measurement at the HL-2A Tokamak  

E-Print Network [OSTI]

A compact neutron spectrometer based on the liquid scintillator is presented for neutron energy spectrum measurements at the HL-2A tokamak. The spectrometer was well characterized and a fast digital pulse shape discrimination software was developed using the charge comparison method. A digitizer data acquisition system with a maximum frequency of 1 MHz can work under an environment with a high count rate at HL-2A tokamak. Specific radiation and magnetic shielding for the spectrometer were designed for the neutron spectrum measurement at the HL-2A tokamak. For pulse height spectrum analysis, dedicated numerical simulation utilizing NUBEAM combined with GENESIS was performed to obtain the neutron energy spectrum. Subsequently, the transportation process from the plasma to the detector was evaluated with Monte Carlo calculations. The distorted neutron energy spectrum was folded with the response matrix of the liquid scintillation spectrometer, and good consistency was found between the simulated and measured pulse height spectra. This neutron spectrometer based on a digital acquisition system could be well adopted for the investigation of the auxiliary heating behavior and the fast-ion related phenomenon on different tokamak devices.

Yuan Xi; Zhang Xing; Xie Xufei; Chen Zhongjing; Peng Xingyu; Fan Tieshuan; Chen Jinxiang; Li Xiangqing; Yuan Guoliang; Yang Jinwei; Yang Qingwei

2013-06-17T23:59:59.000Z

10

Michelle Wyman | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorgeDoesn't32 Master EM ProjectMemoDepartmentFY 2010 Methane(JuneMichelle

11

* Phys 222 may be substituted for Chem 178/178L ** CE 460 may be substituted for CE 333 or CE 334  

E-Print Network [OSTI]

(Structural Analysis I) 3 CE 372 (Engr Hydro & Hydraulics) 3 CE 360 (Geotechnical Engineering) 3 CE 382 (Engr Hydro & Hydraulics) 3 CE 355 (Transportation Engr) 3 CE 382 (Design of Concretes) 3 CE 326 Design) 3 Numerical Analysis Elective 3 CE 485 (CE Design I) 2 Micro 201 (General Microbiology) 3 Engr

Lin, Zhiqun

12

Ageing studies of resistive Micromegas detectors for the HL-LHC  

E-Print Network [OSTI]

Resistive-anode Micromegas detectors are in development since several years, in an effort to solve the problem of sparks when working in high flux and high radiations environment like in the HL-LHC (ten times the luminosity of the LHC). They have been chosen as one of the technologies that will be part of the ATLAS New Small Wheel project (forward muon system). An ageing study is mandatory to assess their capabilities to handle the HL-LHC environment on a long-term period. A prototype has been exposed to several types of irradiations (X-rays, cold neutrons, 60 Co gammas) up to an equivalent HL-LHC time of more than five years without showing any degradation of the performances in terms of gain and energy resolution. Beam test studies took place in October 2012 to assess the tracking performances (efficiency, spatial resolution,...). Results of ageing studies and beam test performances are reported in this paper.

Galán, J; Ferrer-Ribas, E; Giganon, A; Giomataris, I; Herlant, S; Jeanneau, F; Peyaud, A; Schune, Ph; Alexopoulos, T; Byszewski, M; Iakovidis, G; Iengo, P; Ntekas, K; Leontsinis, S; de Oliveira, R; Tsipolitis, Y; Wotschack, J

2013-01-01T23:59:59.000Z

13

Ageing studies of resistive Micromegas detectors for the HL-LHC  

E-Print Network [OSTI]

Resistive-anode Micromegas detectors are in development since several years, in an effort to solve the problem of sparks when working in high flux and high radiations environment like in the HL-LHC (ten times the luminosity of the LHC). They have been chosen as one of the technologies that will be part of the ATLAS New Small Wheel project (forward muon system). An ageing study is mandatory to assess their capabilities to handle the HL-LHC environment on a long-term period. A prototype has been exposed to several types of irradiations (X-rays, cold neutrons, 60 Co gammas) up to an equivalent HL-LHC time of more than five years without showing any degradation of the performances in terms of gain and energy resolution. Beam test studies took place in October 2012 to assess the tracking performances (efficiency, spatial resolution,...). Results of ageing studies and beam test performances are reported in this paper.

J. Galan; D. Attie; E. Ferrer-Ribas; A. Giganon; I. Giomataris; S. Herlant; F. Jeanneau; A. Peyaud; Ph. Schune; T. Alexopoulos; M. Byszewski; G. Iakovidis; P. Iengo; K. Ntekas; S. Leontsinis; R. de Oliveira; Y. Tsipolitis; J. Wotschack

2013-04-07T23:59:59.000Z

14

Chemical and Structural Features of Plants That Contribute to Biomass Recalcitrance  

E-Print Network [OSTI]

Wood: Properties for Ethanol Fuel and Fiber Productions.Wyman CE, 2004. Ethanol Fuel, in Cleveland, C.J. (Ed. ),scenario for cellulosic ethanol fuel production, and speaks

DeMartini, Jaclyn Diana

2011-01-01T23:59:59.000Z

15

Understanding Substrate Features Influenced by Pretreatments that Limit Biomass Deconstruction by Enzymes  

E-Print Network [OSTI]

M, Tuskan GA, Wyman CE: Lignin content in natural Populuscarbohydrates and lignin in biomass. NREL Laboratorycarbohydrates and lignin in biomass. NREL Laboratory

Gao, Xiadi

2013-01-01T23:59:59.000Z

16

Update: Proposed CE Curriculum & Program  

E-Print Network [OSTI]

Update: Proposed CE Curriculum & Program Bruce Jacob, End of Summer 2008 #12;What's all this, then, students, graduates · Held constituents' meeting over winter · Group vote this curriculum Barua has agreed to develop and teach the course ENEE 3xx (Digital systems) -- new course Bruce Jacob

Jacob, Bruce

17

College of Engineering CE Civil Engineering  

E-Print Network [OSTI]

College of Engineering CE Civil Engineering KEY: # = new course * = course changed = course.Lecture,twohours;laboratory,fourhoursperweek.Prereqorcoreq:MA113orconsentofinstructor. CE 120 INTRODUCTION TO CIVIL ENGINEERING. (1) An introduction to the civil engineering profession and the use of computer hardware and software in CE systems analysis and design

MacAdam, Keith

18

A new neutral particle analyzer diagnostic and its first commissioning on HL-2A  

SciTech Connect (OSTI)

A new neutral particle analyzer diagnostic has been developed for HuanLiuqi-2A (commonly referred to as HL-2A), which can provide the neutral particle flux measurement along 11 separate sightlines, simultaneously, within a wider energy range (1-70 keV). It is an electrostatic type analyzer with a removable pinhole and special-shape condenser. The energy analysis can be flexibly achieved by controlling a preset stepwise high voltage on the condenser. It is compact and its field of view covers HL-2A cross section from -33 cm to 33 cm without 'cross-talk.' The energy spectra and ion temperature profile have been obtained during its commissioning.

Li, W.; Xia, Z. W.; Lu, J.; Yang, Q. W.; Ding, X. T. [Southwestern Institute of Physics, Chengdu 610041 (China)

2012-10-15T23:59:59.000Z

19

Mean Hilbert Envelope Coefficients (MHEC) for Robust Speaker Recognition Seyed Omid Sadjadi, Taufiq Hasan, and John H.L. Hansen  

E-Print Network [OSTI]

Hasan, and John H.L. Hansen Center for Robust Speech Systsems (CRSS) Erik Jonsson School of Engineering and Computer Science The University of Texas at Dallas, Richardson, TX 75080-3021, USA {sadjadi, taufiq.hasan

Texas at Dallas, University of

20

Calibration of a 32 channel electron cyclotron emission radiometer on the HL-2A tokamak  

SciTech Connect (OSTI)

A novel 32-channel electron cyclotron emission radiometer has been designed and tested for the measurement of electron temperature profiles on the HL-2A tokamak. This system is based on the intermediate frequency filter detection technique, and has the features of wide working frequency range and high spatial resolution. Two relative calibration methods have been investigated: sweeping the toroidal magnetic field and hopping the output frequency of the local oscillator. Preliminary results show that both methods can ensure reasonable profiles.

Shi, Z. B., E-mail: shizb@swip.ac.cn; Jiang, M.; Huang, X. L.; Zhong, W. L.; Chen, W.; Che, Y. L.; Liu, Z. T.; Ding, X. T.; Yang, Q. W.; Duan, X. R. [Southwestern Institute of Physics, P. O. Box 432, Chengdu 610041 (China)] [Southwestern Institute of Physics, P. O. Box 432, Chengdu 610041 (China)

2014-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Diagnostics for energetic particle studies on the HL-2A tokamak  

SciTech Connect (OSTI)

About 13 kinds of diagnostics for energetic particle physics studied on the HuanLiuqi-2A (commonly referred to as HL-2A) tokamak are described in this paper. Their measurement ranges, resolutions, and arrangement are presented. Three under-construction diagnostics including imaging fast ion D-alpha, scintillator matrix (for hard X-ray detection), and bundle fission chamber are described in detail.

Yang, Q. W., E-mail: yangqw@swip.ac.cn; Zhou, H. Y.; Yang, J. W.; Shi, Z. B.; Ji, X. Q.; Yuan, G. L.; Zhang, Y. P.; Yu, D. L.; Jiang, M.; Li, W.; Ding, X. T. [Southwestern Institute of Physics, Chengdu 610041 (China); Yin, Z. J.; Cao, H. R. [Department of Modern Physics, University of Science and Technology of China, Hefei 230026 (China)

2014-11-15T23:59:59.000Z

22

An ageing study of resistive micromegas for the HL-LHC environment  

E-Print Network [OSTI]

Resistive-anode micromegas detectors are in development since several years, in an effort to solve the problem of sparks when working at high flux and high ionizing radiation like in the HL-LHC (up to ten times the luminosity of the LHC). They have been chosen as one of the technologies that will be part of the ATLAS New Small Wheel project (forward muon system). An ageing study is mandatory to assess their capabilities to handle the HL-LHC environment on a long-term period. A prototype has been exposed to several types of irradiation (X-rays, cold neutrons, $^{60}$Co gammas and alphas) above the equivalent charge produced at the detector in five HL-LHC running years without showing any degradation of the performances in terms of gain and energy resolution. This study has been completed with the characterization of the tracking performances in terms of efficiency and spatial resolution, verifying the compatibility of results obtained with both resistive micromegas detectors, irradiated and non-irradiated one.

Galán, J; Ferrer-Ribas, E; Giganon, A; Giomataris, I; Herlant, S; Jeanneau, F; Peyaud, A; Schune, Ph; Alexopoulos, T; Byszewski, M; Iakovidis, G; Iengo, P; Ntekas, K; Leontsinis, S; de Oliveira, R; Tsipolitis, Y; Wotschack, J

2013-01-01T23:59:59.000Z

23

An ageing study of resistive micromegas for the HL-LHC environment  

E-Print Network [OSTI]

Resistive-anode micromegas detectors are in development since several years, in an effort to solve the problem of sparks when working at high flux and high ionizing radiation like in the HL-LHC (up to ten times the luminosity of the LHC). They have been chosen as one of the technologies that will be part of the ATLAS New Small Wheel project (forward muon system). An ageing study is mandatory to assess their capabilities to handle the HL-LHC environment on a long-term period. A prototype has been exposed to several types of irradiation (X-rays, cold neutrons, $^{60}$Co gammas and alphas) above the equivalent charge produced at the detector in five HL-LHC running years without showing any degradation of the performances in terms of gain and energy resolution. This study has been completed with the characterization of the tracking performances in terms of efficiency and spatial resolution, verifying the compatibility of results obtained with both resistive micromegas detectors, irradiated and non-irradiated one.

J. Galán; D. Attié; E. Ferrer-Ribas; A. Giganon; I. Giomataris; S. Herlant; F. Jeanneau; A. Peyaud; Ph. Schune; T. Alexopoulos; M. Byszewski; G. Iakovidis; P. Iengo; K. Ntekas; S. Leontsinis; R. de Oliveira; Y. Tsipolitis; J. Wotschack

2013-01-31T23:59:59.000Z

24

CE Geothermal | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBoston Areais3: Crystalline Rock - Basement JumpGeneral: CDOT Name: CE

25

International Refrigeration: Order (2012-CE-1510) | Department...  

Broader source: Energy.gov (indexed) [DOE]

Refrigeration: Order (2012-CE-1510) July 20, 2012 DOE ordered International Refrigeration Products to pay an 8,000 civil penalty after finding International Refrigeration had...

26

Table 1. Connection of Criterion 8 CE Outcomes to CE Courses (required, design elective, advanced elective)  

E-Print Network [OSTI]

treatment Biological wastewater treatment (d) Proficiency in Water Resources Engineering CE 3305 CE 3354 CE systems Design of advance water treatment systems Design of biological wastewater treatment systems (g ENVE 4391 ENVE 4399 Water, wastewater, air, solid waste Physical and chemical treatment Advanced water

Gelfond, Michael

27

Test-Bed of a Real Time Detection System for L/H & H/L Transitions Implemented with the ITMS Platform  

E-Print Network [OSTI]

Test-Bed of a Real Time Detection System for L/H & H/L Transitions Implemented with the ITMS Platform

28

Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Couple Demonstration of (In, Ce)-based Skutterudite Materials for Automotive Energy Recovery Thermoelectric Couple Demonstration of (In, Ce)-based Skutterudite Materials for...

29

Lumiram Electric: Order (2010-CE-1014) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Lumiram Electric: Order (2010-CE-1014) Lumiram Electric: Order (2010-CE-1014) November 23, 2010 DOE issued an Order and entered into a Compromise Agreement with Lumiram Electric...

30

High spatial and temporal resolution charge exchange recombination spectroscopy on the HL-2A tokamak  

SciTech Connect (OSTI)

A 32/64-channel charge exchange recombination spectroscopy (CXRS) diagnostic system is developed on the HL-2A tokamak (R = 1.65 m, a = 0.4 m), monitoring plasma ion temperature and toroidal rotation velocity simultaneously. A high throughput spectrometer (F/2.8) and a pitch-controlled fiber bundle enable the temporal resolution of the system up to 400 Hz. The observation geometry and an optimized optic system enable the highest radial resolution up to ?1 cm at the plasma edge. The CXRS system monitors the carbon line emission (C VI, n = 8–7, 529.06 nm) whose Doppler broadening and Doppler shift provide ion temperature and plasma rotation velocity during the neutral beam injection. The composite CX spectral data are analyzed by the atomic data and analysis structure charge exchange spectroscopy fitting (ADAS CXSFIT) code. First experimental results are shown for the case of HL-2A plasmas with sawtooth oscillations, electron cyclotron resonance heating, and edge transport barrier during the high-confinement mode (H-mode)

Wei, Y. L.; Yu, D. L., E-mail: yudl@swip.ac.cn; Liu, L.; Cao, J. Y.; Sun, A. P.; Ma, Q.; Chen, W. J.; Liu, Yi; Yan, L. W.; Yang, Q. W.; Duan, X. R.; Liu, Yong [Southwestern Institute of Physics, Chengdu 610041 (China); Ida, K. [National Institute for Fusion Science, Toki 509-5292 (Japan); Hellermann, M. von [ITER Diagnostic Team, IO, Route de Vinon sur Verdon, 13115 St Paul lez Durance (France); FOM-Institute for Plasma physics “Rijnhuizen,” Association EURATOM, Trilateral Euregio Cluster, 3430 BE Nieuwegein (Netherlands)

2014-10-15T23:59:59.000Z

31

Performances and ageing study of resistive-anodes Micromegas detectors for HL-LHC environment  

E-Print Network [OSTI]

With the tenfold luminosity increase envisaged at the HL-LHC, the background (photons, neutrons, ...) and the event pile-up probability are expected to increase in proportion in the different experiments, especially in the forward regions like, for instance, the muons chambers of the ATLAS detector. Detectors based on the Micromegas principle should be good alternatives for the detector upgrade in the HL-LHC framework because of a good spatial (flux hadrons environment. Several prototypes of 10x10 cm2, with different pitches (0.5 to 2 mm) and different resistive layers have been tested at CERN (pi+@SPS). Several tests have been performed with a telescope at different voltages to assess the performances of the detectors in terms of position resolution and efficiency. The spark behaviour in these conditions has also been evaluated. Resistive coating has been shown to be a successful method to reduce the effect of sparks on the efficiency of micromegas. A good spatial resolution (~80 \\mum) can be reached with a resistive strip coating detector of 1mm pitch and a high efficiency (> 98%) can be achieved with resistive-anode micromegas detector. An X-rays irradiation has been also performed, showing no ageing effect after more than 21 days exposure and an integrated charge of almost 1C.

F. Jeanneau; T. Alexopoulos; D. Attié; M. Boyer; J. Derré; G. Fanourakis; E. Ferrer-Ribas; J. Galán; E. Gazis; T. Geralis; A. Giganon; I. Giomataris; S. Herlant; J. Manjarrés; E. Ntomari; Ph. Schune; M. Titov; G. Tsipolitis

2012-01-09T23:59:59.000Z

32

ADVISER ROOM # EMAIL ADDRESS Adams 221 COBH (eda@ce.montana.edu)  

E-Print Network [OSTI]

, Michael L. Adams Senior CE Betcher, Jacob M. Lewandowski Freshman CE Bigelow, Adam J. (F 11) Larsson Sophomore CE Deen, Michael Perkins Junior CE Devoe, Colleen L. (1st deg Arch) Larsson Sophomore CE #12;DeWitt

Dyer, Bill

33

New Detector Technologies for the LHC Experiments: Prospects, Strategies and Technologies for the HL-LHC Upgrades  

SciTech Connect (OSTI)

We review the prospects, strategies and technologies for the High Luminosity (HL-LHC) upgrades of the ATLAS and CMS detectors, in the light of a very successful two year-long first physics run, and the discovery of a new 126 GeV boson with properties consistent with those of the Standard Model Higgs boson.

Mannelli, Marcello [CERN

2013-03-06T23:59:59.000Z

34

Near infrared 3~~ overtone band of Hl Brian F. Ventrudo and Daniel T. Cassidy  

E-Print Network [OSTI]

Near infrared 3~~ overtone band of Hl Brian F. Ventrudo and Daniel T. Cassidy Department transitions. Short-external-cavity InCaAsP diodes were used as tunable near infrared radiation sources and understand the spectrum of vibra- tional excited states. This paper updates the list of observed near-infrared

Oka, Takeshi

35

Planar Pixel Sensors for the ATLAS tracker upgrade at HL-LHC  

E-Print Network [OSTI]

The ATLAS Planar Pixel Sensor R&D Project is a collaboration of 17 institutes and more than 80 scientists. Their goal is to explore the operation of planar pixel sensors for the tracker upgrade at the High Luminosity-Large Hadron Collider (HL-LHC). This work will give a summary of the achievements on radiation studies with n-in-n and n-in-p pixel sensors, bump-bonded to ATLAS FE-I3 and FE-I4 readout chips. The summary includes results from tests with radioactive sources and tracking efficiencies extracted from test beam measurements. Analysis results of ${2\\cdot10^{16}} \\text{n}_{\\text{eq}}\\text{cm}^{-2}$ and ${1\\cdot10^{16}} \\text{n}_{\\text{eq}}\\text{cm}^{-2}$ ($1 \\text{MeV}$ neutron equivalent) irradiated n-in-n and n-in-p modules confirm the operation of planar pixel sensors for future applications.

Christian Gallrapp

2012-06-15T23:59:59.000Z

36

Unusual Outbursting State of a Z Cam-Type Star HL CMa  

E-Print Network [OSTI]

HL CMa is a Z Cam-type dwarf nova which was discovered as an Einstein X-ray source. In addition to normal outbursts and standstills, we noticed the presence of "the third" outbursting state. During this period, the star showed weak outbursts with a long outburst cycle length. We propose that this phenomenon is caused by a heating on the accretion disk. The presence of strong P Cyg feature in the ultraviolet and the unusual presence of high-excitation optical lines could be interpreted as an emerging signature of strong irradiation field. Since the object is still in this unusual state in 2002 March, we encourage X-ray and spectroscopic observations to detect further signatures of high-energy photons and irradiation.

T. Kato

2002-03-20T23:59:59.000Z

37

Comparison of CeBr3 with LaBr3:Ce, LaCl3:Ce, and NaI:Tl Detectors  

SciTech Connect (OSTI)

Energy resolution and detection efficiency were compared between two sizes of cerium bromide (CeBr3) scintillators, three sizes of lanthanum bromide (LaBr3:Ce) scintillators, three sizes of sodium iodide (NaI:Tl) scintillators, and a lanthanum chloride (LaCl3:Ce) scintillator. Comparisons are made of key parameters such as energy resolution, detection efficiency, linearity, and self-activity of CeBr3, LaBr3:Ce, LaCl3:Ce, and NaI:Tl scintillator detectors. The scintillator detectors are tested by comparing the peak separation and identification in the energy range up to 3.0 MeV using 133Ba, 152Eu, and naturally occurring radioactive materials [1]. The study has shown that CeBr3 scintillator detectors provided by Saint-Gobain offer better resolution than NaI:Tl scintillator detectors. CeBr3 detectors could resolve some closely spaced peaks from 133Ba and 152Eu, which NaI:Tl could not. LaBr3:Ce has slightly better resolution, and a slightly higher efficiency than CeBr3. In this work, “self-activity” of each of these four detector types was measured by operating the detectors themselves. A comparison of the intrinsic activity for all of the detectors in this study is demonstrated. For CeBr3, the self-activity present may be reduced, or even eliminated in the future, through improved processes for growing the material. It will be discussed if, and under what conditions, CeBr3 may be better than LaBr3:Ce and LaCl3:Ce for detection of certain special nuclear material ?-rays [2]. An overall advantage of CeBr3 detectors over lanthanum halide and NaI:Tl detectors will be discussed.

,

2010-09-01T23:59:59.000Z

38

CIVIL ENGINEERING PREREQUISITE SUMMARY Note: BSCE candidate means that you have been admitted to upper division. CE enrolled means you are listed  

E-Print Network [OSTI]

3316 Transportation Engineering BSCE cand. CE 3426 Soil Mechanics CE 2425, CE 2017, BSCE cand. CE 4096 & Engineering Drawing CE 2017 CE 3016 Surveying Math 1297 CE 3025 Environmental Engineering Chem 1151 or 1153 and 1154, CE 3221, BSCE cand. CE 3026 Project Management None CE 3027 Infrastructure Materials CE 2017

Levinson, David M.

39

Optical Observations of Quasar X-ray Jets J.M. Gelbord, H.L. Marshall, B. Miller (MIT)  

E-Print Network [OSTI]

Optical Observations of Quasar X-ray Jets J.M. Gelbord, H.L. Marshall, B. Miller (MIT) D in roughly 2/3 of our sample (13 out of 20; Marshall et al. 2003, in prep.). We are now beginning to analyze161; Marshall et al. 2001, ApJL 549, L167; Marshall et al. 2002, ApJ 564, 683; Sambruna et al. 2002

Gelbord, Jonathan

40

American Power: Order (2010-CE-0911) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Power: Order (2010-CE-0911) American Power: Order (2010-CE-0911) October 5, 2010 DOE issued an Order and entered into a Compromise Agreement with American Power Solutions, Inc....

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

rtino is prof of Cyber Ce  

E-Print Network [OSTI]

Program Technolo Worksho Bertino is Compute systems Compute to secure rtino is prof of Cyber Ce internatio Database Indexing Intelligen Services the Very on the e Security& on Web, Program VLDB, A Data Eng distributed fessor of Co enter and R nce and Se mputer Scien EC laborator maden) in S ers Universi arch

Holland, Jeffrey

42

CeBiTec Symposium Molecular Biotechnology  

E-Print Network [OSTI]

F), Bielefeld University April 3 ­ 4, 2014 PROGRAMME Thursday, April 3rd, 2014 11:00 Registration / Snacks 12:00 Opening remarks Volker F. Wendisch, Bielefeld University, Germany Welcome addresses Martin Egelhaaf (Vice.N. (University of Paderborn) Introduction to the CeBiTec Thomas Noll, Bielefeld University, Germany Session I

Moeller, Ralf

43

CE 473/573 Groundwater Course information  

E-Print Network [OSTI]

. Groundwater modeling 4.1. Introduction to finite-difference models 4.2. Models of groundwater flow 4.3. ModelsCE 473/573 Groundwater Fall 2011 Course information Instructor: Prof. Chris Rehmann rehmann of water and contaminants in groundwater systems to solve problems of groundwater resource evaluation

Rehmann, Chris

44

CE 473/573 Groundwater Course information  

E-Print Network [OSTI]

-reactive and reactive contaminants 4. Groundwater modeling 4.1. Introduction to finite-difference models 4.2. Models of groundwater flow 4.3. Models of contaminant transport 4.4. Available models #12;Recommended textbooks FetterCE 473/573 Groundwater Fall 2009 Course information Instructor: Prof. Chris Rehmann rehmann

Rehmann, Chris

45

SPRING 2013 CEE COURSES: v7 rev: 11/08/12 TRANSPORTATION PLANNING as CE 4410 & CE 6410  

E-Print Network [OSTI]

options for urban transport. After a student registers for CE 4410 or CE WATER MARKETS with Brian Richter and Professor Culver as CE 6500 The utility. This project course will enable us to identify what works best, and how to avoid

Acton, Scott

46

Anchoring Sites for Initial Au Nucleation on CeO2{111}: O Vacancy versus Ce Vacancy Changjun Zhang,  

E-Print Network [OSTI]

Anchoring Sites for Initial Au Nucleation on CeO2{111}: O Vacancy versus Ce Vacancy Changjun Zhang is a matter of debate. Both oxygen and cerium vacancies have been suggested as the anchoring sites initio thermodynamics approaches to investigate the formation of various vacancies at a CeO2{111} surface

Alavi, Ali

47

Chemical and Structural Features of Plants That Contribute to Biomass Recalcitrance  

E-Print Network [OSTI]

Arwa K, Renata B, Tu M. Weak Lignin-Binding Enzymes. Appl.Vinzant TB. Deposition of Lignin Droplets Produced DuringM, Tuskan GA, Wyman CE. Lignin Content in Natural Populus

DeMartini, Jaclyn Diana

2011-01-01T23:59:59.000Z

48

CeCap LLP | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreis aCallahanWindSyracuse, NY JumpKS"Cayucos,CeCap LLP

49

CIVIL ENGINEERING Prerequisite Summary Note: BSCE candidate means that you have been admitted to upper division. CE enrolled means you are listed with  

E-Print Network [OSTI]

, Math 3280 (conc), BSCE cand. CE 3316 Transportation Engineering BSCE cand. CE 3426 Soil Mechanics CE & Engineering Drawing CE 2017, BSCE cand. CE 3016 Surveying Math 1297, BSCE cand. CE 3025 Environmental Engineering Chem 1151 or 1153 and 1154, CE 3221, BSCE cand. CE 3026 Project Management BSCE cand. CE 3027

Levinson, David M.

50

Universitt Bielefeld Centrum fr Biotechnologie -CeBiTec  

E-Print Network [OSTI]

for the development of algal biotechnology Center for Interdisciplinary Research (ZiF), Bielefeld University, Germany September 21 ­ 24, 2014 The Center for Biotechnology (CeBiTec) of Bielefeld University cordially invites you include The 2014 International CeBiTec Research Conference aims to give a complete overview

Moeller, Ralf

51

Representing a 3-D Environment with a 2-D Map Structure Edward H.L. Fong William Adams Frederick Crabbe Alan C. Schultz  

E-Print Network [OSTI]

planning, and localization. II. THE EVIDENCE GRID A wide variety of map representation structures (such Grid The 2-D evidence grid is one of the most popular map structures for autonomous mobile robotsRepresenting a 3-D Environment with a 2½-D Map Structure Edward H.L. Fong William Adams Frederick

Crabbe, Frederick

52

Inversion of infrared imaging bolometer based on one-dimensional and three-dimensional modeling in HL-2A  

SciTech Connect (OSTI)

Linear regularization has been applied to the HL-2A infrared imaging bolometer to reconstruct local plasma emission with one-dimensional (1D) and three-dimensional (3D) modeling under the assumption of toroidal symmetry. In the 3D modeling, a new method to calculate the detector point response function is introduced. This method can be adapted to an arbitrarily shaped pinhole. With the full 3D treatment of the detector geometry, up to 50% of the mean-squared error is reduced compared with the 1D modeling. This is attributed to the effects of finite detector size being taken into account in the 3D modeling. Meanwhile, the number of the bolometer pixels has been optimized to 20 × 20 by making a trade-off between the number of bolometer pixels and the sensitivity of the system. The plasma radiated power density distributions have been calculated as a demonstration using 1D modeling and 3D modeling, respectively.

Gao, J. M., E-mail: gaojm@swip.ac.cn; Liu, Y.; Li, W.; Cui, Z. Y.; Dong, Y. B.; Lu, J.; Xia, Z. W.; Yi, P.; Yang, Q. W. [Southwestern Institute of Physics, Chengdu 610041 (China)] [Southwestern Institute of Physics, Chengdu 610041 (China)

2014-04-15T23:59:59.000Z

53

Synthesis and structure of nanocrystalline mixed Ce–Yb silicates  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • New method of synthesis of nanocrystalline mixed lanthanide silicates is proposed. • Formation of A-type (Ce{sub 1?y}Yb{sub y}){sub 2}Si{sub 2}O{sub 7} in well dispersed Ce{sub 1?x}Yb{sub x}O{sub 2?(x/2)}–SiO{sub 2} system. • Formation of Yb{sub y}Ce{sub 9.33?y}(SiO{sub 4}){sub 6}O{sub 2} in agglomerated Ce{sub 1?x}Yb{sub x}O{sub 2?(x/2)}–SiO{sub 2} system. - Abstract: This work presents results of studies on synthesis and structure of mixed, nanocrystalline Ce–Yb silicates. Using TEM, XRD and FTIR we showed that heat treatment of nanocrystalline Ce{sub 1?x}Yb{sub x}O{sub 2?(x/2)} (x = 0.3, 0.5) mixed oxide supported on amorphous silica in reducing atmosphere, results in formation of Ce–Yb mixed silicates. Dispersion of the oxide on the silica surface and thus a local lanthanide/Si atomic ratio determines the stoichiometry of the silicate. Oxide crystallites uniformly dispersed on the silica surface transformed into A-(Ce{sub 1?y}Yb{sub y}){sub 2}Si{sub 2}O{sub 7} disilicate, while the agglomerated nanoparticles converted into Yb{sub y}Ce{sub 9.33?y}(SiO{sub 4}){sub 6}O{sub 2} oxyapatite silicate as an intermediate phase.

Ma?ecka, Ma?gorzata A., E-mail: M.Malecka@int.pan.wroc.pl; K?pi?ski, Leszek

2013-07-15T23:59:59.000Z

54

Ferromagnetism in chemically synthesized CeO2 nanoparticles by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Ni doping. Ferromagnetism in chemically synthesized CeO2 nanoparticles by Ni doping. Abstract: This work reports the discovery of room-temperature ferromagnetism in 5 - 9 nm...

55

Ca2+-Doped CeBr3 Scintillating Materials  

SciTech Connect (OSTI)

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

Guss, Paul [NSTec; Foster, Michael E. [SNL; Wong, Bryan M. [SNL; Doty, F. Patrick [SNL; Shah, Kanai [RMD; Squillante, Michael R. [RMD; Shirwadkar, Urmila [RMD; Hawrami, Rastgo [RMD; Tower, Josh [RMD; Yuan, Ding [NSTec

2014-01-01T23:59:59.000Z

56

Effects of CeO2 Support Facets on VOx/CeO2 Catalysts in Oxidative...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The higher activity for VOxCeO2(110) might be related to the more abundant oxygen vacancies present on the (110) facets, evidenced from Raman spectroscopic measurements....

57

Continuing a Chandra survey of quasar radio jets Jonathan Gelbord & H.L. Marshall (MIT), D.A. Schwartz (SAO), D.M. Worrall & M. Birkinshaw (SAO & Bristol),  

E-Print Network [OSTI]

Continuing a Chandra survey of quasar radio jets Jonathan Gelbord & H.L. Marshall (MIT), D & Harris 1991, AJ 101, 1632; Marshall et al. 2002, ApJ 564, 683", 3C 390.3 !Harris, Leighly & Leahy 1998, ApJ 499, L149", and 3C 273 !Marshall et al. 2001, ApJ 549, L167". Inverse Compton X-rays? The energy

Gelbord, Jonathan

58

Thin n-in-p planar pixel sensors and active edge sensors for the ATLAS upgrade at HL-LHC  

E-Print Network [OSTI]

Silicon pixel modules employing n-in-p planar sensors with an active thickness of 200 $\\mu$m, produced at CiS, and 100-200 $\\mu$m thin active/slim edge sensor devices, produced at VTT in Finland have been interconnected to ATLAS FE-I3 and FE-I4 read-out chips. The thin sensors are designed for high energy physics collider experiments to ensure radiation hardness at high fluences. Moreover, the active edge technology of the VTT production maximizes the sensitive region of the assembly, allowing for a reduced overlap of the modules in the pixel layer close to the beam pipe. The CiS production includes also four chip sensors according to the module geometry planned for the outer layers of the upgraded ATLAS pixel detector to be operated at the HL-LHC. The modules have been characterized using radioactive sources in the laboratory and with high precision measurements at beam tests to investigate the hit efficiency and charge collection properties at different bias voltages and particle incidence angles. The performance of the different sensor thicknesses and edge designs are compared before and after irradiation up to a fluence of $1.4\\times10^{16}n_{eq}/cm^{2}$.

S. Terzo; A. Macchiolo; R. Nisius; B. Paschen

2014-11-20T23:59:59.000Z

59

Homoleptic Ce(III) and Ce(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State  

SciTech Connect (OSTI)

Electrochemical experiments performed on the complex Ce-IV[2-((BuNO)-Bu-t)py](4), where [2-((BuNO)-Bu-t)py](-) = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [(Bu4N)-Bu-n](2)[Ce(NO3)(6)] in acetonitrile and a 2.95 V stabilization compared to the standard potential for the ion under aqueous conditions. Density functional theory calculations suggest that this preference for the higher oxidation state is a result of the tetrakis(nitroxide) ligand framework at the Ce cation, which allows for effective electron donation into, and partial covalent overlap with, vacant 4f orbitals with delta symmetry. The results speak to the behavior of CeO2 and related solid solutions in oxygen uptake and transport applications, in particular an inherent local character of bonding that stabilizes the 4+ oxidation state. The results indicate a cerium(IV) complex that has been stabilized to an unprecedented degree through tuning of its ligand-field environment.

Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A.; Piro, Nicholas A.; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

2014-06-25T23:59:59.000Z

60

Luminescence Enhancement of CdTe Nanostructures in LaF3:Ce/CdTe...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhancement of CdTe Nanostructures in LaF3:CeCdTe Nanocomposites. Luminescence Enhancement of CdTe Nanostructures in LaF3:CeCdTe Nanocomposites. Abstract: Radiation detection...

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The suburban villa (munya) and court culture in Umayyad Cordoba (756-976 CE)  

E-Print Network [OSTI]

As the capital of the Umayyad dynasty (r. 756 CE-1031 CE), the city of Cordoba developed into one of the most renowned urban centers of the western Mediterranean. The Great Mosque of Cordoba is the outstanding testament ...

Anderson, Glaire D

2005-01-01T23:59:59.000Z

62

CE 467 / 567 HIGHWAY SAFETY AND OPERATIONS Fall 2006 Course Syllabus  

E-Print Network [OSTI]

1 CE 467 / 567 HIGHWAY SAFETY AND OPERATIONS Fall 2006 Course Syllabus Catalog This course of class) #12;2 CE 467 / 567 HIGHWAY SAFETY AND OPERATIONS Fall 2006 Course Syllabus Course Outline: What

Hickman, Mark

63

E-Print Network 3.0 - allanita-ce vinculadas al Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

allanita-ce vinculadas al Search Powered by Explorit Topic List Advanced Search Sample search results for: allanita-ce vinculadas al Page: << < 1 2 3 4 5 > >> 1 Elena Garrigs Mic,...

64

CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 | Department...  

Broader source: Energy.gov (indexed) [DOE]

CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 No reports submitted for this docket. More Documents & Publications...

65

Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design of n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature Waste Heat Recovery Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature...

66

Magnetic structures and interplay between rare-earth Ce and Fe magnetism in single-crystal CeFeAsO  

SciTech Connect (OSTI)

Neutron and synchrotron resonant x-ray magnetic scattering (RXMS) complemented by heat capacity and resistivity measurements reveal the evolution of the magnetic structures of Fe and Ce sublattices in a CeFeAsO single crystal. The RXMS of magnetic reflections at the Ce LII edge shows a magnetic transition that is specific to the Ce antiferromagnetic long-range ordering at TCe? 4 K with short-range Ce ordering above TCe, whereas neutron diffraction measurements of a few magnetic reflections indicate a transition at T?? 12 K with an unusual order parameter. Detailed order-parameter measurements on several magnetic reflections by neutrons show a weak anomaly at 4 K that we associate with the Ce ordering. The successive transitions at TCe and T? can also be clearly identified by two anomalies in heat capacity and resistivity measurements. The higher transition temperature at T?? 12 K is mainly ascribed to Fe spin reorientation transition, below which Fe spins rotate uniformly and gradually in the ab plane. The Fe spin reorientation transition and short-range Ce ordering above TCe reflect the strong Fe-Ce couplings prior to long-range ordering of the Ce. The evolution of the intricate magnetic structures in CeFeAsO going through T? and TCe is proposed.

Zhang, Qiang [Ames Laboratory; Tian, Wei [Ames Laboratory; Li, Haifeng [Ames Laboratory; Kim, Jong-Woo [Argonne Naitonal Laboratory; Yan, Jiaqiang [Ames Laboratory; McCallum, Robert William [Ames Laboratory; Lograsso, Thomas A. [Ames Laboratory; Zarestky, Jerel L. [Ames Laboratory; Budko, Sergey L. [Ames Laboratory; McQueeney, Robert J. [Ames Laboratory; Vaknin, David [Ames Laboratory

2013-11-27T23:59:59.000Z

67

ue Ce ec o o es o a Energy Efficiency &  

E-Print Network [OSTI]

phenomena improving MEA and stack performance · Optimize fuel cells and systems for early marketue Ce ec o o es o a Energy Efficiency & Renewable Energy Fuel Cell Bus Workshop Overview and Purppose Dimitrios Papageorgopoulos Fuel Cell Technologgies Proggram DOE and DOT Joint Fuel Cell Bus

68

University of Saskatchewan College of Arts & sCienCe  

E-Print Network [OSTI]

University of Saskatchewan College of Arts & sCienCe Annual report 2009/2010 #12;Contents The Dean thought....The strong work ethic of the youth of Saskatchewan, who are then exposed to high- minded Simard, BA'69, LLB'70 Minister of Health, Government of Saskatchewan (1991­1995) #12;The dean's message I

Patterson, William P.

69

2014 Course Description Solid Waste Engineering -CE 477  

E-Print Network [OSTI]

2014 Course Description Solid Waste Engineering - CE 477 Engineering Principles of Solid Waste on course web site http://people.engr.ncsu.edu/barlaz/ Solid Waste Technology & Management by Christensen et al (eBook available through NCSU libraries) Solid waste management must be addressed by virtually

Barlaz, Morton A.

70

CE 469 / 569 TRAVEL DEMAND MODELING Spring 2006 Course Syllabus  

E-Print Network [OSTI]

of travel demand data, and should apply these methods to estimating and to forecasting travel demand these to practical modeling scenarios. The student should also use existing computer tools to forecast travel demand1 CE 469 / 569 TRAVEL DEMAND MODELING Spring 2006 Course Syllabus Catalog Detailed investigation

Hickman, Mark

71

Seven-quasiparticle bands in {sup 139}Ce  

SciTech Connect (OSTI)

The high spin states in the {sup 139}Ce nucleus have been studied by in-beam {gamma}-spectroscopic techniques using the reaction {sup 130}Te({sup 12}C,3n){sup 139}Ce at E{sub beam}=65 MeV. A gamma detector array, consisting of five Compton-suppressed Clover detectors was used for coincidence measurements. 15 new levels have been proposed and 28 new {gamma} transitions have been assigned to {sup 139}Ce on the basis of {gamma}{gamma} coincidence data. The level scheme of {sup 139}Ce has been extended above the known 70 ns (19/2){sup -} isomer up to {approx}6.1 MeV in excitation energy and (35/2)({Dirac_h}/2{pi}) in spin. The spin-parity assignments for most of the newly proposed levels have been made using the deduced Directional Correlation from Oriented states of nuclei (DCO ratio) and the Polarization Directional Correlation from Oriented states (PDCO ratio) for the de-exciting transitions. The observed level structure has been compared with a large basis shell model calculation and also with the predictions from cranked Nilsson-Strutinsky (CNS) calculations. A general consistency has been observed between these two different theoretical approaches.

Chanda, Somen; Bhattacharjee, Tumpa; Bhattacharyya, Sarmishtha; Mukherjee, Anjali; Basu, Swapan Kumar; Ragnarsson, I.; Bhowmik, R. K.; Muralithar, S.; Singh, R. P.; Ghugre, S. S.; Pramanik, U. Datta [Variable Energy Cyclotron Centre, Kolkata 700064 (India); Division of Mathematical Physics, Lund Institute of Technology, Lund University, P. O. Box 118, S-22100 Lund (Sweden); Inter University Accelerator Centre, New Delhi 110067 (India); University Grants Commission and Department of Atomic Energy Consortium for Scientific Research, Kolkata 700098 (India); Saha Institute of Nuclear Physics, Kolkata 700064 (India)

2009-05-15T23:59:59.000Z

72

CE 4990 -Construction Scheduling Week 1: Steel Frame Project  

E-Print Network [OSTI]

CE 4990 - Construction Scheduling Week 1: Steel Frame Project Fall 2011 January 13, 2012 Introduction You are a construction manager for a project to build a steel frame for an office building1 of 964 pre-fabricated structural steel members will be used in the construction. The standard bay size

Mukherjee, Amlan

73

Thermodynamic and Structural Features of Aqueous Ce(III)  

SciTech Connect (OSTI)

With a single f-electron, Ce(III) is the simplest test case for benchmarking the thermodynamic and structural properties of hydrated Ln(III) against varying density functionals and reaction field models, in addition to determining the importance of multiconfigurational character in their wave functions. Here, the electronic structure of Ce(H2O)x(H2O)y3+ (x = 8, 9; y = 0, 12-14) has been examined using DFT and CASSCF calculations. The latter confirmed that the wave function of octa- and nona-aqua Ce(III) is well-described by a single configuration. Benchmarking was performed for density functionals, reaction field cavity types, and solvation reactions against the experimental free energy of hydration, ?Ghyd(Ce3+). The UA0, UAKS, Pauling, and UFF polarized continuum model cavities displayed different performance, depending on whether one or two hydration shells were examined, and as a function of the size of the metal basis set. These results were essentially independent of the density functional employed. Using these benchmarks, the free energy for water exchange between CN = 8 and CN = 9, for which no experimental data are available, was estimated to be approximately -4 kcal/mol.

Adriana Dinescu; Aurora E. Clark

2008-10-01T23:59:59.000Z

74

Thermodynamic and Structural Features of Aqueous Ce(III)  

SciTech Connect (OSTI)

With a single f-electron, Ce(III) is the simplest test case for benchmarking the thermodynamic and structural properties of hydrated Ln(III) against varying density functionals and reaction field models, in addition to determining the importance of multiconfigurational character in their wave functions. Here, the electronic structure of Ce(H?O)x(H?O)y 3+ (x =8, 9; y= 0, 12-14) has been examined using DFT and CASSCF calculations. The latter confirmed that the wave function of octa- and nona-aqua Ce(III) is well-described by a single configuration. Benchmarking was performed for density functionals, reaction field cavity types, and solvation reactions against the experimental free energy of hydration, ?Ghyd(Ce3+). The UA0, UAKS, Pauling, and UFF polarized continuum model cavities displayed different performance, depending on whether one or two hydration shells were examined, and as a function of the size of the metal basis set. These results were essentially independent of the density functional employed. Using these benchmarks, the free energy for water exchange between CN = 8 and CN = 9, for which no experimental data are available, was estimated to be approximately -4 kcal/mol.

Dinescu, Adriana; Clark, Aurora E.

2008-10-10T23:59:59.000Z

75

CO Oxidation mechanism on CeO2-supported Au nanoclusters  

SciTech Connect (OSTI)

To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters(NCs)/Nanoparticles, we design Au13 and Au12 supported on a flat and a stepped-CeO2 model (Au/CeO2) and study various kinds of CO oxidation mechanisms at the Au-CeO2 interface and the Au NC as well.

Kim H. Y.; Henkelman, G.

2013-09-08T23:59:59.000Z

76

In this Issue International CeBiTec Research Conference on Algal Biotechnology  

E-Print Network [OSTI]

Biotechnology From September 21 to 24, 2014, the CeBiTec organized the 4th International CeBiTec Research production. In this respect, the 4th International CeBiTec Research Conference 2014 aimed to give a completeBiTec ­ Quarterly www.cebitec.uni-bielefeld.de #12;2 | 4 CeBiTec ­ Quarterly | Autumn 2014 International

Moeller, Ralf

77

Neutron scattering of CeNi at the SNS-ORNL: A preliminary report  

SciTech Connect (OSTI)

This is a preliminary report of a neutron scattering experiment used to investigate 4f electron behavior in Ce.

Mirmelstein, A. [Russian Federal Nuclear Center VNIITF, Snezhinsk, Russia; Podlesnyak, Andrey A [ORNL; Kolesnikov, Alexander I [ORNL; Saporov, B. [Oak Ridge National Laboratory (ORNL); Sefat, A.S. [Oak Ridge National Laboratory (ORNL); Tobin, J. G. [Lawrence Livermore National Laboratory (LLNL)

2014-01-01T23:59:59.000Z

78

DAO O ce Note 1998-05 Version 1 Dated 12/06/1999 O ce Note Series on  

E-Print Network [OSTI]

Assimilation Siegfried Schubert, Editor Documentation of the Physical-Space Statistical Analysis System (PSAS and sources, as well as the use of the multivariate formulation. An on-line version of this document can be obtained from the DAO. Robert M. Atlas, Acting Head Data Assimilation O ce Goddard Space Flight Center

79

www.ce.udel.edu/speakers ENVIRONMENTAL ENGINEERING  

E-Print Network [OSTI]

strategies" Dr. Angelia Seyfferth Assistant Professor Department of Plant and soil science UNIversITy Of DelAWAre MAR 08 "Tradeoffs in Water Quality Management: risk, economics and equity" Dr. Michael Kavanaugh-831-2442 "sustainable stormwater research" Dr. Robert G. Traver Director vIllANOvA CeNTer fOr The ADvANCeMeNT Of sUsTAINAbIlITy

Kirby, James T.

80

Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102  

E-Print Network [OSTI]

Approved Module Information for CE1102, 2014/5 Module Title/Name: Organic Chemistry for Engineers Module Code: CE1102 School: Engineering and Applied Science Module Type: Standard Module New Module chemistry. Part 2: Introduction to Laboratory Skills To enable the student to develop good practical skills

Neirotti, Juan Pablo

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Strongly correlated electron behavior : superconductivity and non-Fermi liquid behavior in Ce?-xRxColn?  

E-Print Network [OSTI]

T ( ) c T ( c ab La Ce Pr Nd PmSm Eu Gd Tb Dy Ho Er Tm YbSm x Ce La Tb La Ce Pr Nd PmSm Eu Gd Tb Dy Ho Er Tm Yb (b)g -1) J(J+1) Ce (a) La Ce Pr Nd PmSm Eu Gd Tb Dy Ho Er Tm Yb

Gonzales, Eileen

2009-01-01T23:59:59.000Z

82

2-(3-Methoxyphenyl)-5-methyl-1,8-naphthyridin-4(1H)-one (HKL-1) induces G2/M arrest and mitotic catastrophe in human leukemia HL-60 cells  

SciTech Connect (OSTI)

2-(3-Methoxyphenyl)-5-methyl-1,8-naphthyridin-4(1H)-one (HKL-1), a 2-phenyl-1,8-naphthyridin-4-one (2-PN) derivative, was synthesized and evaluated as an effective antimitotic agent in our laboratory. However, the molecular mechanisms are uncertain. In this study, HKL-1 was demonstrated to induce multipolar spindles, sustain mitotic arrest and generate multinucleated cells, all of which indicate mitotic catastrophe, in human leukemia HL-60 cells. Western blotting showed that HKL-1 induces mitotic catastrophe in HL-60 cells through regulating mitotic phase-specific kinases (down-regulating CDK1, cyclin B1, CENP-E, and aurora B) and regulating the expression of Bcl-2 family proteins (down-regulating Bcl-2 and up-regulating Bax and Bak), followed by caspase-9/-3 cleavage. These findings suggest that HKL-1 appears to exert its cytotoxicity toward HL-60 cells in culture by inducing mitotic catastrophe. Highlights: ? HKL-1 is a potential antimitotic agent against HL-60 cells. ? HKL-1 induces spindle disruption and sustained resulted in mitotic catastrophe. ? CENP-E and aurora B protein expressions significantly reduced. ? Bcl-2 family protein expressions altered and caspase-9/-3 activation. ? HKL-1 is an attractive candidate for possible use as a novel antimitotic agent.

Hsu, Mei-Hua; Liu, Chin-Yu; Lin, Chiao-Min; Chen, Yen-Jung; Chen, Chun-Jen; Lin, Yu-Fu; Huang, Li-Jiau [Graduate Institute of Pharmaceutical Chemistry, China Medical University, Taichung, Taiwan, ROC (China)] [Graduate Institute of Pharmaceutical Chemistry, China Medical University, Taichung, Taiwan, ROC (China); Lee, Kuo-Hsiung [Natural Products Research Laboratories, Eshelman School of Pharmacy, University of North Carolina, Chapel Hill, NC 27599 (United States) [Natural Products Research Laboratories, Eshelman School of Pharmacy, University of North Carolina, Chapel Hill, NC 27599 (United States); Chinese Medicine Research and Development Center, China Medical University and Hospital, Taichung, Taiwan, ROC (China); Kuo, Sheng-Chu, E-mail: sckuo@mail.cmu.edu.tw [Graduate Institute of Pharmaceutical Chemistry, China Medical University, Taichung, Taiwan, ROC (China)] [Graduate Institute of Pharmaceutical Chemistry, China Medical University, Taichung, Taiwan, ROC (China)

2012-03-01T23:59:59.000Z

83

Whirlpool: Order (2014-CE-21010) | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomen Owned SmallOf TheViolations | Department of Energyis EIA? Andof4-CE-21010)

84

LG: Proposed Penalty (2015-CE-14022) | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10 DOEWashington, DCKickoffLDV5-CE-14022) LG: Proposed Penalty

85

Sunpentown: Order (2012-CE-1505) | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy Strain Rate4 RecoveryJulyEvaluationOffi ce U.S. DepartmentOrder

86

Ethanol Steam Reforming on Co/CeO2: The Effect of ZnO Promoter  

SciTech Connect (OSTI)

A series of ZnO promoted Co/CeO2 catalysts were synthesized and characterized using XRD, TEM, H2-TPR, CO chemisorption, O2-TPO, IR-Py, and CO2-TPD. The effects of ZnO on the catalytic performances of Co/CeO2 were studied in ethanol steam reforming. It was found that the addition of ZnO facilitated the oxidation of Co0 via enhanced oxygen mobility of the CeO2 support which decreased the activity of Co/CeO2 in C–C bond cleavage of ethanol. 3 wt% ZnO promoted Co/CeO2 exhibited minimum CO and CH4 selectivity and maximum CO2 selectivity. This resulted from the combined effects of the following factors with increasing ZnO loading: (1) enhanced oxygen mobility of CeO2 facilitated the oxidation of CHx and CO to form CO2; (2) increased ZnO coverage on CeO2 surface reduced the interaction between CHx/CO and Co/CeO2; and (3) suppressed CO adsorption on Co0 reduced CO oxidation rate to form CO2. In addition, the addition of ZnO also modified the surface acidity and basicity of CeO2, which consequently affected the C2–C4 product distributions.

Davidson, Stephen; Sun, Junming; Wang, Yong

2013-12-02T23:59:59.000Z

87

CeBr3 as a High-Resolution Gamma-Ray Detector  

SciTech Connect (OSTI)

Lanthanum halide (LaBr3:Ce) scintillators have been well-documented as high-resolution gamma-ray detectors that are operated at room temperature. These scintillators have better resolution (<3% at 662 keV) relative to sodium iodide (NaI(Tl)) scintillators (7% at 662 keV), but the naturally occurring radioactive isotope 138La causes self-activity in the crystal that occludes portions of the gamma-ray spectrum. This selfactivity limits the use of LaBr3:Ce in high-sensitivity applications. Cerium, the dopant in the LaBr3:Ce matrix possesses useful scintillation properties, and its selfactivity is on the order of 3750 times less than La; however, Ce has not been fully characterized as the chief component in a scintillation detector. This work investigated Ce as the key scintillation matrix component in a scintillation detector with the hypothesis that CeBr3 promises energy resolution comparable or superior to LaBr3:Ce. The researchers involved with this work believe that CeBr3 may be the answer to obtaining high-temperature, high-resolution spectra with greater sensitivity than LaBr3:Ce.

Michael Reed, Paul Guss, Christopher Contreras

2008-11-13T23:59:59.000Z

88

Capillary electrophoresis-fluorescence line narrowing system (CE-FLNS) for on-line structural characterization  

DOE Patents [OSTI]

Capillary electrophoresis (CE) is interfaced with low temperature fluorescence line-narrowing (FLN) spectroscopy for on-line structural characterization of separated molecular analytes. 21 figs.

Jankowiak, R.J.; Small, G.J.; Shields, P.A.

1999-04-27T23:59:59.000Z

89

The Complex Core Level Spectra of CeO2: An Analysis in Terms of Atomic and Charge Transfer Effects  

SciTech Connect (OSTI)

We present a rigorous parameter-free theoretical treatment of the Ce 4s and 5s photoelectron spectra of CeO2. In the currently accepted model the satellite structure in the photoelectron spectra is explained in terms of a mixed valence (Ce 4f0 O 2p6, Ce 4f1 O 2p5, and Ce 4f2 O 2p4) con?guration. We show that charge transfer (CT) into Ce 5d as well as con?gurations involving intra-atomic movement of charge must be considered in addition and compute their contributions to the spectra.

Bagus, Paul S.; Nelin, Constance J.; Ilton, Eugene S.; Baron, Martin; Abbott, Heather; Primorac, Elena; Kuhlenbeck, Helmut; Shaikhutdinov, Shamil; Freund, Hans-Joachim

2010-03-05T23:59:59.000Z

90

Interaction of carbon monoxide with oxygen in the adsorbed layer on Pd, Ce, Pd-Ce catalysts supported on /gamma/-Al/sub 2/O/sub 3/  

SciTech Connect (OSTI)

The adsorption of CO and the interaction of CO/sub ads/ with O/sub 2/ on Pd, Ce, and Pd-Ce//gamma/-Al/sub 2/O/sub 3/ (0.5 wt. % Pd, 2.0 wt. % Ce) has been studied using the methods of IR spectroscopy and differential scanning calorimetry. The identity of the adsorbed CO complexes, the temperature ranges over which they desorb, and their reactivity with O/sub 2/ have been established. The interaction of bridging and carbonate - carboxylate CO complexes and carbon (disproportionation and dissociation products) with O/sub 2/ on Pd and Pd-Ce catalysts is preceded by the coadsorption of oxygen and the evolution of heat. During the oxidation of CO, autooscillation, heat evolution, and the concentration of oxygen in the flow are observed.

Savel'eva, G.A.; Sass, A.S.; Speranskaya, G.V.; Tenchev, K.K.; Petrov, L.A.; Vozdvizhenskii, V.F.; Galeev, T.K.; Popova, N.M.

1989-01-01T23:59:59.000Z

91

CO Oxidation at the Interface of Au Nanoclusters and the Stepped-CeO2(111) Surface  

SciTech Connect (OSTI)

To reveal the richer chemistry of CO oxidation by CeO2 supported Au Nanoclusters NCs)/Nanoparticles, we design a Au12 supported on a stepped-CeO2 model (Au/CeO2-step) and study various kinds of CO oxidation mechanisms at the interface of the Au/CeO2-step: oxygen spillover from the CeO2 to the Au NCs;2 CO oxidation by the O2 bound to the Au-Ce3+ interface;3 and CO oxidation by the Mars-van Krevelen (M-vK) mechanism.4 DFT+U calculations show that lattice oxygen at the CeO2 step edge oxidizes CO bound to Au NCs by the M-vK mechanism. CO2 desorption determines the rate of CO oxidation and the vacancy formation energy (Evac) is a reactivity descriptor for CO oxidation. The maximum Evac that insures spontaneous CO2 production is higher for the Au/CeO2-step than the Au/CeO2-surface suggesting that the CeO2-step is a better supporting material than the CeO2-surface for CO oxidation by the Au/CeO2. Our results also suggest that for CO oxidation by Au NCs supported on nano- or meso-structured CeO2, which is the case of industrial catalysts, the M-vK mechanism accounts for a large portion of the total activity.

Kim H. Y.; Henkelman, G.

2013-01-14T23:59:59.000Z

92

Atomistic Study of Doped BaCeO3: Dopant Site-Selectivity and Cation Nonstoichiometry  

E-Print Network [OSTI]

of Technology, Pasadena, California 91125, and Materials Chemistry Group, Chemistry DiVision, Uni, the trivalent dopants are assumed to occupy the Ce4+ -site, which introduces oxygen vacancies partitioning over both Ba and Ce sites. Such partitioning reduces the concentration of oxygen vacancies, which

Haile, Sossina M.

93

Ternary ceramic alloys of Zr-Ce-Hf oxides  

DOE Patents [OSTI]

A ternary ceramic alloy is described which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce[sub x]Hf[sub y]Zr[sub 1[minus]x[minus]y]O[sub 2], is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites. 1 fig.

Becher, P.F.; Funkenbusch, E.F.

1990-11-20T23:59:59.000Z

94

Ternary ceramic alloys of ZR-CE-HF oxides  

DOE Patents [OSTI]

A ternary ceramic alloy which produces toughening of zirconia and zirconia composites through the stress transformation from tetragonal phase to monoclinic phase. This alloy, having the general formula Ce.sub.x Hf.sub.y Zn.sub.1-x-y O.sub.2, is produced through the addition of appropriate amounts of ceria and hafnia to the zirconia. Typically, improved toughness is achieved with about 5 to about 15 mol % ceria and up to about 40 mol % hafnia. The preparation of alloys of these compositions are given together with data as to the densities, tetragonal phase content, hardness and fracture toughness. The alloys are useful in preparing zirconia bodies as well as reinforcing ceramic composites.

Becher, Paul F. (Oak Ridge, TN); Funkenbusch, Eric F. (White Bear Lake, MN)

1990-01-01T23:59:59.000Z

95

1synQPSK Univ. Paderborn, Germany; CeLight Israel; Photline, France; IPAG, Germany Univ. Paderborn, Germany  

E-Print Network [OSTI]

1synQPSK Univ. Paderborn, Germany; CeLight Israel; Photline, France; IPAG, Germany synQPSK Univ. Paderborn, Germany CeLight Israel Photline, France IPAG, Germany Contract 004631 in FP6 IST-2002 Phase Shift Keying Transmission #12;2synQPSK Univ. Paderborn, Germany; CeLight Israel; Photline, France

Noé, Reinhold

96

Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w  

E-Print Network [OSTI]

Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w R. L. de Almeida,1 O The synthesis, crystallographic structure, and magnetic properties of polycrystalline single-phase samples of CeBaFe results on the successful prepara- tion and characterization of polycrystalline CeBaFe2O5+w samples. Ideal

de Lima, Oscar Ferreira

97

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First-Principles  

E-Print Network [OSTI]

Reassessment of Al-Ce and Al-Nd Binary Systems Supported by Critical Experiments and First The present study reinvestigates the Al-Ce and Al-Nd phase diagrams and reoptimizes their thermody- namics results and theoretical calculations show that Al2Nd (or Al2Ce) should be treated as a stoichiometric

Widom, Michael

98

THE REMARKABLE XRAY JET IN THE QUASAR 4C 20.24 D.A. Schwartz 1 , H.L. Marshall 2 , J. Gelbord 2 , E.S. Perlman 3 , M. Georganopoulos 3 , M. Birkinshaw 4 ,  

E-Print Network [OSTI]

1 THE REMARKABLE X­RAY JET IN THE QUASAR 4C 20.24 D.A. Schwartz 1 , H.L. Marshall 2 , J. Gelbord 2 by Chandra as part of a snapshot survey of ra­ dio jets (Marshall et al., 2005a). The survey, which is on the radio jet to the north (Marshall et al., 2006). The X­ray flux was roughly 6.5 #22;Jy, only about 20

Schwartz, Daniel

99

Results from a multi-wavelength survey of quasar jets Jonathan Gelbord & H.L. Marshall (MIT), D.A. Schwartz (SAO), D.M. Worrall & M. Birkinshaw (SAO & Bristol),  

E-Print Network [OSTI]

Results from a multi-wavelength survey of quasar jets Jonathan Gelbord & H.L. Marshall (MIT), D, including M87 (Biretta, Stern & Harris 1991, AJ 101, 1632; Marshall et al. 2002, ApJ 564, 683), 3C 390.3 (Harris, Leighly & Leahy 1998, ApJ 499, L149), and 3C 273 (Marshall et al. 2001, ApJ 549, L167). Inverse

Gelbord, Jonathan

100

Cytotoxic and DNA-damaging effects of methyl tert-butyl ether and its metabolites on HL-60 cells in vitro  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is a widely used oxygenate in unleaded gasoline; however, few studies have been conducted on the toxicity of this compound. This study evaluates the cytotoxic and DNA-damaging effects of MTBE and its metabolites in a human haemopoietic cell line, HL-60. The metabolites of MTBE studied include tertiary butyl alcohol (TBA), {alpha}-hydroxyisobutyric acid (HIBA), and formaldehyde. Comet assay is used to assess DNA damage, and the cytotoxicity is investigated by lactate dehydrogenease (LDH) release. The results show no significant cytotoxic effects of MTBE, TBA, and HIBA over a concentration ranging from 1 to 30 mM. Formaldehyde, in contrast, causes a substantial LDH release at a concentration of 5 {mu}M. Hydrogen peroxide, a known oxidative agent, at concentrations ranging from 10 to 100 {mu}M, produces a significant dose-related increase in DNA damage, whereas a much higher concentration of MTBE (1 to 30 mM) is required to produce a similar observation. The genotoxic effects of TBA and HIBA appear to be identical to that of MTBE. Conversely, DNA damage is observed for formaldehyde at a relatively low concentration range (5 to 100 {mu}M). These findings suggest that MTBE and its metabolites, except formaldehyde, have relatively low cytotoxic and genotoxic effects. 16 refs., 4 figs.

Tang, G.H. [Xian Medical Univ. (China); Shen, Y.; Shen, H.M. [National Univ. of Singapore (Singapore)] [and others

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Studies on Cu/CeO{sub 2}: A new NO reduction catalyst  

SciTech Connect (OSTI)

Fine particle and large surface area Cu/CeO{sub 2} catalysts of crystallite sizes in the range of 100--200 {angstrom} synthesized by the solution combustion method have been investigated for NO reduction. Five percent Cu/CeO{sub 2} catalyst shows nearly 100% conversion of NO by NH{sub 3} below 300 C, whereas pure ceria and Zr, Y, and Ca doped ceria show 85--95% NO conversion above 600 C. Similarly NO reduction by CO has been observed over 5% Cu/CeO{sub 2} with nearly 100% conversion below 300 C. Hydrocarbon (n-butane) oxidation by NO to CO{sub 2}, N{sub 2}, and H{sub 2}O has also been demonstrated over this catalyst below 350 C making Cu/CeO{sub 2} a new NO reduction catalyst in the low temperature window of 150--350 C. Kinetics of NO reduction over 5% Cu/CeO{sub 2} have also been investigated. The rate constants are in the range of 1.4 {times} 10{sup 4} to 2.3 {times} 10{sup 4} cm{sup 3}/g s between 170 and 300 C. Cu/CeO{sub 2} catalysts are characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and electron paramagnetic resonance spectroscopy where Cu{sup 2+} ions are shown to be dispersed on the CeO{sub 2} surface.

Bera, P.; Aruna, S.T.; Patil, K.C.; Hegde, M.S. [Indian Inst. of Science, Bangalore (India)] [Indian Inst. of Science, Bangalore (India)

1999-08-15T23:59:59.000Z

102

Studies on Ca2+-Doped CeBr3 Scintillating Materials  

SciTech Connect (OSTI)

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. [RMD; Glodo, J. [RMD; Yuan, D. [NSTec

2013-07-03T23:59:59.000Z

103

Studies on Ca2+-Doped CeBr3 Scintillating Materials  

SciTech Connect (OSTI)

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. R. [RMD; Shirwadkar, U. [RMD; Hawrami, R. [RMD; Tower, J. [RMD; Yuan, D. [NSTec

2013-09-01T23:59:59.000Z

104

CE 363 -TRANSPORTATION ENGINEERING AND PAVEMENT DESIGN Fall 2009 Course Syllabus  

E-Print Network [OSTI]

1 CE 363 - TRANSPORTATION ENGINEERING AND PAVEMENT DESIGN Fall 2009 Course Syllabus Catalog (4) CDT Course Syllabus D2L: The primary source for homework, solutions, design project activities, and other

Hickman, Mark

105

Pressure tuning of competing magnetic interactions in intermetallic CeFe2  

SciTech Connect (OSTI)

We use high-pressure magnetic x-ray diffraction and numerical simulation to determine the low-temperature magnetic phase diagram of stoichiometric CeFe2. Near 1.5 GPa we find a transition from ferromagnetism to antiferromagnetism, accompanied by a rhombohedral distortion of the cubic Laves crystal lattice. By comparing pressure and chemical substitution we find that the phase transition is controlled by a shift of magnetic frustration from the Ce-Ce to the Fe-Fe sublattice. Notably the dominant Ce-Fe magnetic interaction, which sets the temperature scale for the onset of long-range order, remains satisfied throughout the phase diagram but does not determine the magnetic ground state. Our results illustrate the complexity of a system with multiple competing magnetic energy scales and lead to a general model for magnetism in cubic Laves phase intermetallic compounds.

Wang, Jiyang; Feng, Yejun; Jaramillo, R.; van Wezel, Jasper; Canfield, Paul C.; Rosenbaum, T.F.

2012-07-20T23:59:59.000Z

107

Ion-Beam-Induced Chemical Mixing at a Nanocrystalline CeO2&ndash...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

microscopy imaging and analysis suggest that this band of contrast is a cerium silicate phase with an approximate Ce:Si:O composition ratio of 1:1:3 in an amorphous nature....

108

Data:B084b37a-3e1c-482d-8041-d7ce3e7aa0ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2 No revision has38865d08 No revision has been approved for this page.af74fa257cc No54a9102ce3e7aa0ce No

109

Data:Ce82df4d-c557-42d2-a1f3-ce3b159222ae | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No revisiona1f3-ce3b159222ae

110

Electronic structure and f-orbital occupancy in Yb-substituted CeCoIn5  

SciTech Connect (OSTI)

The local structure and 4f orbital occupancy have been investigated in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} via Yb L{sub III}-edge extended x-ray absorption fine structure (EXAFS), Ce and Yb L{sub III}-edge x-ray absorption near-edge structure (XANES), and angle-resolved photoemission spectroscopy (ARPES) measurements. Yb(III) (4f{sup 13}) is the hole analog of Ce(III) (4f{sup 1}). Yb is found to be strongly intermediate-valent in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} throughout the entire doping range, including pure YbCoIn{sub 5}, with an f-hole occupancy for Yb of n{sub f} ? 0.3 (i.e. Yb{sup 2.3+}), independent of Yb concentration and independent of temperature down to T = 20 K. In contrast, the f-electron orbital occupancy for Ce remains close to 1 for all Yb concentrations, suggesting that there is no mutual influence on n{sub f} between neighboring Ce and Yb sites. Likewise, ARPES measurements at 12 K have found that the electronic structure along {Gamma} ? X is not sensitive to the Yb substitution, suggesting that the Kondo hybridization of Ce f electrons with the conduction band is not affected by the presence of Yb impurities in the lattice. The emerging picture is that in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} there are two networks, interlaced but independent, that couple to the conduction band: one network of Ce ions in the heavy-fermion limit, one network of Yb ions in the strongly intermediate-valent limit. The robustness of the local and electronic structure to doping suggests the absence of charge transfer between the Ce and Yb ions, and may explain the relative robustness of superconductivity for this Ce-site substitution as compared to the In-site substitution.

Booth, C. H.; Durakiewicz, T.; Capan, C.; Hurt, D.; Bianchi, A. D.; Joyce, J.J.; Fisk, Z.

2011-05-03T23:59:59.000Z

111

582014-15 Suggested Course Plan CompuTeR sCIenCe  

E-Print Network [OSTI]

Algebra & Diff. Equations EE 364: Intro to Probability & Statistics or mATh 407: Probability Theory sCIenCe582014-15 Suggested Course Plan CompuTeR sCIenCe FIRST YEAR FALL: 16 units SPRING: 16 units SECOND104L,170 4 BASIC SCIENCE I 4 TECH. ELECTIVE I 4 TECH. ELECTIVE II 4 EE 364 MATH225or245 or MATH 407

Zhou, Chongwu

112

CeO2 and CuOx Interactions and the Controlled Assembly of CeO2(111) and CeO2(100) Nanoparticles on an Oxidized Cu(111)Substrate  

SciTech Connect (OSTI)

The catalytic performance of ceria-based heterogeneous catalysts in many chemical transformations (water-gas shift reaction, CO oxidation, alcohol synthesis from CO/CO{sub 2} hydrogenation, etc.) is affected by the surface structure of the ceria. To control the performance of ceria-containing inverse catalysts, we devised a method to grow ceria nanoparticles (NPs) exposing exclusively either (111) or (100) surfaces and characterized their surface structures by scanning tunneling microscopy. When cerium is vapor-deposited on Cu(111) in a background of molecular O{sub 2}, only CeO{sub 2}(111) NPs grow. However, if the surface of Cu(111) is preoxidized with O{sub 2} or NO{sub 2} to form a rectangular copper oxide phase, probably Cu{sub 4}O{sub 3}(001), CeO{sub 2}(100) NPs grow on the oxide template instead. These experimental findings are interpreted using results of density functional calculations. The (100) surface of bulk ceria reconstructs to preserve charge neutrality. This is not necessary for CeO{sub 2}(100) NPs grown on Cu{sub 4}O{sub 3}(001), where the topmost oxygen layer of Cu{sub 4}O{sub 3} is shared with the interfacial layer of cerium. After the CeO{sub 2}(100)/CuO{sub x}/Cu(111) surfaces were exposed to CO, the copper oxide was reduced but the shape of the CeO{sub 2}(100) NPs remained intact. This opens the door for diverse applications in catalysis.

Rodriguez J. A.; Yang F.; Choi Y.M.; Agnoli S.; Liu P.; Stacchiola D.; Hrbek J.

2011-11-24T23:59:59.000Z

113

Refining sweet sorghum to ethanol and sugar: economic trade-offs in the context of North China  

E-Print Network [OSTI]

. Gnansounou a,*, A. Dauriat a , C.E. Wyman b a Laboratory of Energy Systems, Swiss Federal Institute 2004 Available online 26 November 2004 Abstract Reducing the use of non-renewable fossil energy rights reserved. Keywords: Energy; Ethanol; Sugar; Sweet sorghum; Economics 1. Introduction Petroleum

California at Riverside, University of

114

Enhanced oxygen storage capacity of Ce{sub 0.88}Mn{sub 0.12}O{sub y} compared to CeO{sub 2}: An experimental and theoretical investigation  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Ce{sub 0.88}Mn{sub 0.12}O{sub y} and CeO{sub 2} hollow nanospheres were successfully prepared via a supercritical antisolvent process. ? Compared with the pure CeO{sub 2}, the Ce{sub 0.88}Mn{sub 0.12}O{sub y} has nearly the same surface area but more oxygen vacancies. ? DFT calculations shows that the surface oxygen of the CeO{sub 2} gets activated after doping Mn. -- Abstract: Ce{sub 0.88}Mn{sub 0.12}O{sub y} and CeO{sub 2} nanoparticles have been successfully prepared via a supercritical antisolvent process. High-resolution transmission electron microscopy displays the hollow and spherical structures of these nanoparticles. X-ray diffraction analysis demonstrates the formation of Ce{sub 0.88}Mn{sub 0.12}O{sub y} solid solution. N{sub 2} adsorption reveals that the Ce{sub 0.88}Mn{sub 0.12}O{sub y} has nearly the same surface area with the CeO{sub 2}. It is shown that the Ce{sub 0.88}Mn{sub 0.12}O{sub y} has higher oxygen storage capacity (OSC) than the CeO{sub 2}. To understand the mechanism of the improved OSC of the Mn doped CeO{sub 2}, Raman spectroscopy, X-ray photoelectron spectra and density functional theoretical (DFT) calculations have been performed. It is found that the Ce{sub 0.88}Mn{sub 0.12}O{sub y} presents more oxygen vacancies, indicating the easier of oxygen mobility from bulk to surface. DFT calculations reveal that structural and electronic modifications are caused by the incorporation of Mn in the CeO{sub 2}, resulting in activated oxygen species. The oxygen vacancy formation energy is lowered by the Mn doping. These changes are responsible for the enhanced OSC of the Ce{sub 0.88}Mn{sub 0.12}O{sub y}.

Zhang, Minhua; Jiang, Dongyu [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China)] [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China); Jiang, Haoxi, E-mail: hxjiang@tju.edu.cn [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China)] [Key Laboratory for Green Chemical Technology of Ministry of Education, R and D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China)

2012-12-15T23:59:59.000Z

115

Proactive Design of n-Type (In, Ce) Filled Skutterudites Enabling High-Temperature Waste Heat Recovery  

Broader source: Energy.gov [DOE]

Thermoelectric and structural properties of n-type (In, Ce) filled skutterudites including power factors and ZT as a function of temperature are presented

116

Mechanism of Methane Chemical Looping Combustion with Hematite Promoted with CeO2  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is a promising technology for fossil fuel combustion that produces sequestration-ready CO{sub 2} stream, reducing the energy penalty of CO{sub 2} separation from flue gases. An effective oxygen carrier for CLC will readily react with the fuel gas and will be reoxidized upon contact with oxygen. This study investigated the development of a CeO{sub 2}-promoted Fe{sub 2}O{sub 3}?hematite oxygen carrier suitable for the methane CLC process. Composition of CeO{sub 2} is between 5 and 25 wt % and is lower than what is generally used for supports in Fe{sub 2}O{sub 3} carrier preparations. The incorporation of CeO{sub 2} to the natural ore hematite strongly modifies the reduction behavior in comparison to that of CeO{sub 2} and hematite alone. Temperature-programmed reaction studies revealed that the addition of even 5 wt % CeO{sub 2} enhances the reaction capacity of the Fe{sub 2}O{sub 3} oxygen carrier by promoting the decomposition and partial oxidation of methane. Fixed-bed reactor data showed that the 5 wt % cerium oxides with 95 wt % iron oxide produce 2 times as much carbon dioxide in comparison to the sum of carbon dioxide produced when the oxides were tested separately. This effect is likely due to the reaction of CeO{sub 2} with methane forming intermediates, which are reactive for extracting oxygen from Fe{sub 2}O{sub 3} at a considerably faster rate than the rate of the direct reaction of Fe{sub 2}O{sub 3} with methane. These studies reveal that 5 wt % CeO{sub 2}/Fe{sub 2}O{sub 3} gives stable conversions over 15 reduction/oxidation cycles. Lab-scale reactor studies (pulsed mode) suggest the methane reacts initially with CeO{sub 2} lattice oxygen to form partial oxidation products (CO + H{sub 2}), which continue to react with oxygen from neighboring Fe{sub 2}O{sub 3}, leading to its complete oxidation to form CO{sub 2}. The reduced cerium oxide promotes the methane decomposition reaction to form C + H{sub 2}, which continue to react with Fe{sub 2}O{sub 3}/Fe{sub 3}O{sub 4} to form CO/CO{sub 2} and H{sub 2}O. This mechanism is supported by the characterization studies, which also suggest that the formation of carbonaceous intermediates may affect the reaction rate and selectivity of the oxygen carrier.

Miller, Duane D.; Siriwardane, Ranjani

2013-08-01T23:59:59.000Z

117

DFT+U Study of CeO2 and Its Native Defects  

E-Print Network [OSTI]

in solid state fuel cells2, as a catalyst3-6, as a high-dielectric constant gate oxide7, and in resistance random access memories (ReRAM)8. Many properties of CeO2 are determined by its intrinsic defects9-23 and the unusual behavior of the semi-core Ce 4f... averaging scheme46 for spin- orbital coupling effect. The RRKJ method is chosen as optimization of pseudopotentials47. The PBE functional was chosen for PBE+U calculations with a kinetic cutoff energy of 750eV, which expands the valence electrons states...

Huang, Bolong; Gillen, Roland; Robertson, John

2014-10-14T23:59:59.000Z

118

Comparative Study on Redox Properties of Nanosized CeO2 and CuO/Ce2 Under CO/O2  

SciTech Connect (OSTI)

Nanosized CeO{sub 2} and CuO/CeO{sub 2} samples, active for CO-PROX or related processes were comparatively examined by O{sub 2} probe electron paramagnetic resonance and in situ Raman and X-ray diffraction techniques. Their behavior toward CO reduction, as well as the oxygen-handling properties of the CO-reduced samples, was explored. An appreciable reduction of the ceria bulk was detected on treatment under CO at 473 K. On the basis of the analysis of the evolution of different oxygen-derived species (superoxide, peroxide, O-) on low-temperature (77-300 K) oxygen chemisorption on the CO-reduced samples, a general picture of the redox properties of the samples is presented. Results demonstrate that the presence of copper promotes completion of the redox cycle under CO/O{sub 2} by favoring both ceria reduction and oxidation. This can be relevant to explaining the remarkable oxidation activity and synergetic effects observed for catalysts combining CuO and CeO{sub 2}.

Martinez-Arias,A.; Gamarra, D.; Fernandez-Garcia, M.; Wang, X.; Hanson, J.; Rodriguez, J.

2006-01-01T23:59:59.000Z

119

Observation of Strong Resonant Behavior in the Inverse Photoelectron Spectroscopy of Ce Oxide  

SciTech Connect (OSTI)

X-ray Emission Spectroscopy (XES) and Resonant Inverse Photoelectron Spectroscopy (RIPES) have been used to investigate the photon emission associated with the Ce3d5/2 and Ce3d3/2 thresholds. Strong resonant behavior has been observed in the RIPES of Ce Oxide near the 5/2 and 3/2 edges. Inverse Photoelectron Spectroscopy (IPES) and its high energy variant, Bremstrahlung Isochromat Spectroscopy (BIS), are powerful techniques that permit a direct interrogation of the low-lying unoccupied electronic structure of a variety of materials. Despite being handicapped by counting rates that are approximately four orders of magnitude less that the corresponding electron spectroscopies (Photoelectron Spectroscopy, PES, and X-ray Photoelectron Spectroscopy, XPS) both IPES and BIS have a long history of important contributions. Over time, an additional variant of this technique has appeared, where the kinetic energy (KE) of the incoming electron and photon energy (hv) of the emitted electron are roughly the same magnitude as the binding energy of a core level of the material in question. Under these circumstances and in analogy to Resonant Photoelectron Spectroscopy, a cross section resonance can occur, giving rise to Resonant Inverse Photoelectron Spectroscopy or RIPES. Here, we report the observation of RIPES in an f electron system, specifically the at the 3d{sub 5/2} and 3d{sub 3/2} thresholds of Ce Oxide. The resonant behavior of the Ce4f structure at the 3d thresholds has been addressed before, including studies of the utilization of the technique as a probe of electron correlation in a variety of Ce compounds. Interestingly, the first RIPES work on rare earths dates back to 1974, although under conditions which left the state of the surface and near surface regions undefined. Although they did not use the more modern terminology of 'RIPES,' it is clear that RIPES was actually first performed in 1974 by Liefeld, Burr and Chamberlain on both La and Ce based materials. In these experiments, the La and Ce metallic samples were attached to the anode of an x-ray tube and the x-ray emission characteristics were measured using a two crystal monochromator. The pressure in the x-ray tube was quoted as being below 2 x 10{sup -8} Torr. They did indeed observed resonant behavior at the M{alpha} (3d{sub 5/2}) and M{beta} (3d{sub 3/2}) thresholds. In fact, our results here will confirm the measurements made upon the Ce based sample used in by Liefeld et al. However, the state of the Ce sample surface and near surface regions are quite undefined in the study in Ref 9. For example, the authors suggest that they are probing Ce metal, since they cannot see any evidence of an OK{alpha} (1s) XES line. However, they do report the observation of FK{alpha} (1s) line, possibly due to the utilization of cerium fluoride in the sample preparation. Later, they tried to address these issues in a new ultrahigh vacuum system. Based upon our results, it is clear that their original sample surface was oxidized, using the word here in its more general context as in having lost electrons to the oxidizing agent, although whether the structure is an oxide or fluoride remains unclear. In any case, the primacy of Liefeld and coworkers in these measurements should be noted. Cerium and cerium oxide have been studied with a variety of spectroscopic techniques under UHV conditions. This includes Bremstrahlung Isochromat Spectroscopy or BIS, Photoelectron Spectroscopy, X-ray Absorption Spectroscopy, Electron Energy Loss Spectroscopy and Resonant XES, to name just a few. We will compare our results to those of other spectroscopies.

Tobin, J G; Yu, S W; Chung, B W; Waddill, G D; Damian, E; Duda, L; Nordgren, J

2009-12-15T23:59:59.000Z

120

Overseas Affairs and Planning Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University  

E-Print Network [OSTI]

Contact: Overseas Affairs and Planning Institute for Integrated Cell-Material Sciences (i Cell-Material Sciences, iCeMS for short, I welcome you to the Seventh iCeMS International Symposium to develop them through evolution. They are also very important to design and create various novel "smart

Takada, Shoji

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Dilute Acid and Autohydrolysis Pretreatment Bin Yang and Charles E. Wyman  

E-Print Network [OSTI]

to make cellulose and hemi- cellulose susceptible to an enzymatic hydrolysis step for generation 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 Jonathan R. Mielenz (ed.), Biofuels, biological catalysis was substituted for the second thermochemical step to enhance glucose yields from

California at Riverside, University of

122

Hydrolysis of different chain length xylooliogmers by cellulase and hemicellulase Qing Qing, Charles E. Wyman  

E-Print Network [OSTI]

to assess how Spezyme CP cellulase, Novozyme 188 b-glucosidase, Multifect xylanase, and non-commercial b

California at Riverside, University of

123

Laser Surface Modification of a Crystalline Al-Co-Ce Alloy for Enhanced Corrosion  

E-Print Network [OSTI]

#12;Laser Surface Modification of a Crystalline Al-Co-Ce Alloy for Enhanced Corrosion Resistance hardness, structure manipula- tion, and improvements in corrosion resistance of metallic materials.[1 surface modify steel and aluminum alloys for improved corrosion resistance.[3,4] The enhanced corrosion

Fitz-Gerald, James M.

124

Logiciel de Gestion de Version Qu'est-ce qu'un Version Control System (VCS) ?  

E-Print Network [OSTI]

Logiciel de Gestion de Version Git Qu'est-ce qu'un Version Control System (VCS) ? Appelé également Logiciel de Gestion de Révision (RCS), un VCS est un outil qui permet de : · de suivre l'évolution d revenir en arrière en cas de problème ; · de retenir qui a effectué chaque modification de chaque fichier

Tichit, Laurent

125

CeSOS Highlights and AMOS Visions 27-29th May 2013 Aurlien Babarit  

E-Print Network [OSTI]

2013 Criteria for comparison > The true criterion is cost of kWh. > kWh (power production) can absorption · Income side of COE · The higher the power absorption per unit, the less the installation cost a limit to the allowed cost for viability #12;A. Babarit CeSOS Highlights and AMOS Visions ­ 27-29th May

Nørvåg, Kjetil

126

COMMENT LES NANOTUBES DE CARBONE INTERAGISSENT AVEC LES MACROPHAGES : CE QUE NOUS DIT LA MICROFLUORESCENCE X  

E-Print Network [OSTI]

COMMENT LES NANOTUBES DE CARBONE INTERAGISSENT AVEC LES MACROPHAGES : CE QUE NOUS DIT LA. Boczkowski (INSERM). Réf. : Nano Lett. 8 (9), 2659-2663 (2008). Les nanotubes de carbone présentent des utilisée jusqu'alors pour étudier des nanotubes de carbone. Nous avons choisi d'étudier différentes sortes

Paris-Sud 11, Université de

127

In situ corrosion analysis of Al-Zn-In-Mg-Ti-Ce sacrificial anode alloy  

SciTech Connect (OSTI)

The corrosion behaviour of Al-5Zn-0.02In-1Mg-0.05Ti-0.5Ce (wt.%) alloy has been investigated by immersion test, scanning electron microscopy, energy dispersive X-ray detector, electrochemical impedance spectroscopy and electrochemical noise. The results show that there exist different corrosion types of the alloy in 3.5% NaCl solution with the immersion time. At the initial stage of immersion, pitting due to the precipitates predominates the corrosion with a typical inductive loop at low frequencies in electrochemical impedance spectroscopy. The major precipitates of the alloy are MgZn{sub 2} and Al{sub 2}CeZn{sub 2} particles. The corrosion potentials of the bulk MgZn{sub 2} and Al{sub 2}CeZn{sub 2} alloys are negative with respect to that of {alpha}-Al, so the MgZn{sub 2} and Al{sub 2}CeZn{sub 2} precipitates can act as activation centre and cause the pitting. In the late corrosion, a relative uniform corrosion predominates the corrosion process controlled by the dissolution/precipitation of the In ions and characterized by a capacitive loop at medium-high frequencies in electrochemical impedance spectroscopy. The potential noise of the pitting shows larger amplitude fluctuation and lower frequency, but the potential noise of the uniform corrosion occurs with smaller amplitude fluctuation and higher frequency.

Ma Jingling, E-mail: majingling.student@sina.com; Wen Jiuba; Zhai Wenxia; Li Quanan

2012-03-15T23:59:59.000Z

128

The CompuTer SCienCe program The bachelor of science degree in computer science  

E-Print Network [OSTI]

The CompuTer SCienCe program The bachelor of science degree in computer science offered by the Watson School is accredited by the Computing Accreditation Commission of ABET Inc. (mailing address: 111 in the fundamentals of computer science, elements of practical application and an appreciation for liberal learning

Suzuki, Masatsugu

129

Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions  

E-Print Network [OSTI]

Energy Based Methods in Wind Turbine Control CeSOS Highlights and AMOS Visions Morten D. Pedersen 1 / 26 #12;This talk 1 Background 2 Understanding the Wind Turbine 3 Nonlinear Turbine Modeling 4;Background The Problem Previously stable wind turbine systems began exhibiting resonant behavior when put

Nørvåg, Kjetil

130

CE990 Graduate Seminar Presentations The presentation materials shown in this file were prepared by graduate  

E-Print Network [OSTI]

cord · 10% fabric 4 #12;Thermal ConductivityThermal Conductivity · Low thermal conductivity of 0.242W conventional aggregatesconventional aggregates 5 #12;Thermal ConductivityThermal Conductivity ··Shredded tireCE990 Graduate Seminar Presentations DISCLAIMER The presentation materials shown in this file were

Saskatchewan, University of

131

Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate  

E-Print Network [OSTI]

Author's personal copy Prepration and photoluminescence properties of Ce doped lutetium silicate silicate Cerium Solegel Photoluminescence Lu2SiO5 a b s t r a c t Cerium doped lutetium silicate powders%). The synthesized lutetium silicate powders were investigated by X-ray diffraction (XRD), TG-DTA, SEM

Cao, Guozhong

132

Unusual Physical and Chemical Properties of Cu in Ce1-xCuxO2 Oxides  

SciTech Connect (OSTI)

The structural and electronic properties of Ce{sub 1-x}Cu{sub x}O{sub 2} nano systems prepared by a reverse microemulsion method were characterized with synchrotron-based X-ray diffraction, X-ray absorption spectroscopy, Raman spectroscopy, and density functional calculations. The Cu atoms embedded in ceria had an oxidation state higher than those of the cations in Cu{sub 2}O or CuO. The lattice of the Ce{sub 1-x}Cu{sub x}O{sub 2} systems still adopted a fluorite-type structure, but it was highly distorted with multiple cation-oxygen distances with respect to the single cation-oxygen bond distance seen in pure ceria. The doping of CeO{sub 2} with copper introduced a large strain into the oxide lattice and favored the formation of O vacancies, leading to a Ce{sub 1-x}Cu{sub x}O{sub 2-y} stoichiometry for our materials. Cu approached the planar geometry characteristic of Cu(II) oxides, but with a strongly perturbed local order. The chemical activities of the Ce{sub 1-x}Cu{sub x}O{sub 2} nanoparticles were tested using the reactions with H2 and O2 as probes. During the reduction in hydrogen, an induction time was observed and became shorter after raising the reaction temperature. The fraction of copper that could be reduced in the Ce{sub 1-x}Cu{sub x}O{sub 2} oxides also depended strongly on the reaction temperature. A comparison with data for the reduction of pure copper oxides indicated that the copper embedded in ceria was much more difficult to reduce. The reduction of the Ce{sub 1-x}Cu{sub x}O{sub 2} nanoparticles was rather reversible, without the generation of a significant amount of CuO or Cu{sub 2}O phases during reoxidation. This reversible process demonstrates the unusual structural and chemical properties of the Cu-doped ceria materials.

Wang,X.; Rodriguez, J.; Hanson, J.; Gamarra, D.; Martinez-Arias, A.; Fernandez-Garcia, M.

2005-01-01T23:59:59.000Z

133

Phase relations and crystal structures in the system Ce-Ni-Zn at 800 Degree-Sign C  

SciTech Connect (OSTI)

Phase relations have been established for the system Ce-Ni-Zn in the isothermal section at 800 Degree-Sign C using electron microprobe analysis and X-ray powder diffraction. Phase equilibria at 800 Degree-Sign C are characterized by a large region for the liquid phase covering most of the Ce-rich part of the diagram, whereas a Zn-rich liquid is confined to a small region near the Zn-corner of the Gibbs triangle. Whereas solubility of Ce in the binary Ni-Zn phases is negligible, mutual solubilities of Ni and Zn at a constant Ce content are large at 800 Degree-Sign C for most Ce-Zn and Ce-Ni compounds. The solid solution Ce(Ni{sub 1-x}Zn{sub x}){sub 5} with the CaCu{sub 5}-type is continuous throughout the entire section and for the full temperature region from 400 to 800 Degree-Sign C. Substitution of Zn by Ni is found to stabilize the structure of CeZn{sub 11} to higher temperatures. At 800 Degree-Sign C Ce(Ni{sub x}Zn{sub 1-x}){sub 11} (0.03{<=}x{<=}0.22) appears as a ternary solution phase. Similarly, a rather extended solution forms for Ce{sub 2}(Ni{sub x}Zn{sub 1-x}){sub 17} (0{<=}x{<=}0.53). Detailed data on atom site occupation and atom parameters were derived from X-ray structure analyses for single crystals of Ce{sub 2+y}(Ni{sub x}Zn{sub 1-x}){sub 17}, y=0.02, x=0.49 (a=0.87541(3), c=1.25410(4) nm; Th{sub 2}Zn{sub 17} type with space group R3{sup Macron }m,R{sub F{sup 2}}=0.018) and Ce(Ni{sub 0.18}Zn{sub 0.82}){sub 11} (a=1.04302(2), c=0.67624(3)nm, BaCd{sub 11} type with space group I4{sub 1}/amd, R{sub F{sup 2}}=0.049). - Graphical abstract: Ce-Ni-Zn isothermal section at 800 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Phase relations were determined for the system Ce-Ni-Zn in the section at 800 Degree-Sign C. Black-Right-Pointing-Pointer A continuous solid solution Ce(Ni{sub 1-x}Zn{sub x}){sub 5}, 0{<=}x{<=}1, forms between 400 and 800 Degree-Sign C. Black-Right-Pointing-Pointer Zn/Ni substitution stabilizes the ternary phase Ce(Zn{sub 1-x}Ni{sub x}){sub 11}, 0.03{<=}x{<=}0.22, 800 Degree-Sign C. Black-Right-Pointing-Pointer An extended solution forms for Ce{sub 2}(Ni{sub x}Zn{sub 1-x}){sub 17} (0{<=}x{<=}0.53). Black-Right-Pointing-Pointer Crystal data are given: Ce{sub 2+y}(Ni{sub x}Zn{sub 1-x}){sub 17} (Th{sub 2}Zn{sub 17}), Ce(Ni{sub 0.18}Zn{sub 0.82}){sub 11} (BaCd{sub 11}).

Malik, Z.; Grytsiv, A. [Institute of Physical Chemistry, University of Vienna, Waehringerstrasse 42, A-1090 Vienna (Austria)] [Institute of Physical Chemistry, University of Vienna, Waehringerstrasse 42, A-1090 Vienna (Austria); Rogl, P., E-mail: peter.franz.rogl@univie.ac.at [Institute of Physical Chemistry, University of Vienna, Waehringerstrasse 42, A-1090 Vienna (Austria); Giester, G. [Institute of Mineralogy and Crystallography, University of Vienna, Althanstrasse 14, A-1090 Vienna (Austria)] [Institute of Mineralogy and Crystallography, University of Vienna, Althanstrasse 14, A-1090 Vienna (Austria)

2012-10-15T23:59:59.000Z

134

Size Effect on Nuclear Gamma-Ray Energy Spectra Acquired by Different Sized CeBr3, LaBr3:Ce, and NaI:Tl Gamma-Ray Detectors  

SciTech Connect (OSTI)

Gamma-ray energy spectra were acquired for different sizes of cerium tribromide (CeBr3), cerium-doped lanthanum tribromide (LaBr3:Ce), and thallium-doped sodium iodide (NaI:Tl) detectors. A comparison was conducted of the energy resolution and detection efficiency of these scintillator detectors for different sizes of detectors. The results of this study are consistent with the observation that for each size detector, LaBr3:Ce offers better resolution than either a CeBr3 or NaI:Tl detector of the same size. In addition, CeBr3 and LaBr3:Ce detectors could resolve some closely spaced peaks in the spectra of several radioisotopes that NaI:Tl could not. As the detector size increased, all three detector materials exhibited higher efficiency, albeit with slightly reduced resolution. Significantly, the very low intrinsic activity of CeBr3 is also demonstrated in this study, which, when combined with energy resolution characteristics for a range of detector sizes, could lead to an improved ability to detect special nuclear materials compared to the other detectors.

Guss, Paul [NSTec; Reed, Michael [NSTec; Yuan, Ding [NSTec; Beller, Denis [UNLV; Cutler, Matthew [UNLV; Contreras, Chris [UNLV; Mukhopadhyay, Sanjoy [NSTec; Wilde, Scott UNLV

2014-03-01T23:59:59.000Z

135

Data:678ce1a9-73c5-4299-aa54-b70f702c53ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revision has been approvedea02758d3 No revision has1574de6f No revisionb70f702c53ce No revision has

136

Data:Ce155644-3dbb-44ce-80f8-79eb97a58f0a | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved for this page. It

137

Methane Combustion over Pd/ZrO2/SiC, Pd/CeO2/SiC, Pd/Zr0.5Ce0.5O2/SiC Catalysts  

E-Print Network [OSTI]

1 Methane Combustion over Pd/ZrO2/SiC, Pd/CeO2/SiC, Pd/Zr0.5Ce0.5O2/SiC Catalysts Xiaoning Guo a Laboratory of Coal Conversion, Institute of Coal Chemistry, Taiyuan 030001, PR China b GREMI UMR6606 CNRS0.5O2 solid solution) modified Pd/SiC catalysts for methane combustion are studied. XRD and XPS

Paris-Sud XI, Université de

138

Scintillation properties of some Ce[sup 3+] and Pr[sup 3+] doped inorganic crystals  

SciTech Connect (OSTI)

The scintillations properties of Ce[sup 3+] and Pr[sup 3+] doped complex fluoride crystals of composition CsGd[sub 2]F[sub 7] and K[sub 2]YF[sub 5] and of Pr[sup 3+] doped Y[sub 3]Al[sub 5]O[sub 12] single crystals were studied by means of x-ray and gamma ray excitation. The Ce[sub 3+] and Pr[sub 3+] doped fluoride crystals show 5d-4f luminescences at wavelengths near 340 nm and 240 nm, respectively. 5d-4f luminescence of Pr[sup 3+] doped Y[sub 3]Al[sub 5]O[sub 12] is observed between 300 and 400 nm. The authors present the absolute light yield in photons/MeV together with results from scintillation decay time experiments.

Dorenbos, P.; Visser, R.; Eijk, C.W.E. van (Delft Univ. of Technology (Netherlands). Dept. of Applied Physics); Khaidukov, N.M. (N.S. Kurnakov Inst. of General and Inorganic Chemistry, Moscow (Russian Federation)); Korzhik, M.V. (Inst. of Nuclear Problems, Minsk (Russian Federation))

1993-08-01T23:59:59.000Z

139

Magnetization switching of rare earth orthochromite CeCrO{sub 3}  

SciTech Connect (OSTI)

We report the synthesis of single phase rare earth orthochromite CeCrO{sub 3} and its magnetic properties. A canted antiferromagnetic transition with thermal hysteresis at T?=?260?K is observed, and a magnetic compensation (zero magnetization) near 133?K is attributed to the antiparallel coupling between Ce{sup 3+} and Cr{sup 3+} moments. At low temperature, field induced magnetization reversal starting from 43?K for H?=?1.2 kOe reveals the spin flip driven by Zeeman energy between the net moments and the applied field. These findings may find potential uses in magnetic switching devices such as nonvolatile magnetic memory which facilitates two distinct states of magnetization.

Cao, Yiming; Cao, Shixun, E-mail: sxcao@shu.edu.cn; Ren, Wei; Feng, Zhenjie; Yuan, Shujuan; Kang, Baojuan; Zhang, Jincang [Department of Physics, Shanghai University, Shanghai 200444 (China); Lu, Bo [Laboratory for Microstructures, Shanghai University, Shanghai 200444 (China)

2014-06-09T23:59:59.000Z

140

Josephson effect in CeCoIn{sub 5} microbridges as seen via quantum interferometry  

SciTech Connect (OSTI)

A superconducting quantum interference device (SQUID) was prepared on a micron-sized single crystal using a selected growth domain of a thin film of CeCoIn{sub 5} grown by molecular beam epitaxy. SQUID voltage oscillations of good quality were obtained as well as interference effects stemming from the individual Josephson microbridges. The transport characteristics in the superconducting state exhibited several peculiarities which we ascribe to the periodic motion of vortices in the microbridges. The temperature dependence of the Josephson critical current shows good correspondence to the Ambegaokar-Baratoff relation, expected for the ideal Josephson junction. The results indicate a promising pathway to identify the type of order parameter in CeCoIn{sub 5} by means of phase-sensitive measurements on microbridges.

Foyevtsov, Oleksandr; Porrati, Fabrizio; Huth, Michael [Physikalisches Institut, Goethe University, Frankfurt am Main, 60438 (Germany)

2011-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Investigation into Nanostructured Lanthanum Halides and CeBr{sub 3} for Nuclear Radiation Detection  

SciTech Connect (OSTI)

This slide-show presents work on radiation detection with nanostructured lanthanum halides and CeBr{sub 3}. The goal is to extend the gamma energy response on both low and high-energy regimes by demonstrating the ability to detect low-energy x-rays and relatively high-energy activation prompt gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, cerium bromide, or other nanocrystal material. Homogeneous and nano structure cases are compared.

Guss, P., Guise, R., Mukhopadhyay, S., Yuan, D.

2011-06-22T23:59:59.000Z

142

Synthesis of Transient Climate Evolution of the last 21-kyr (SynTraCE-21)  

SciTech Connect (OSTI)

Climate evolution in the last 21,000 years provides critical observations for testing state-of-the-art climate models on the simulation of climate evolution and abrupt climate changes. Proxy evidences and new modeling activities have led to rapid advances in our understanding of climate change for this past time period. This funding helps to support the first international SynTraCE-21k workshop at Mount Hood, Oregon from 10-13 October, 2010.

Zhengyu Liu

2011-05-06T23:59:59.000Z

143

Luminescence Enhancement of CdTe Nanostructures in LaF3:Ce/CdTe Nanocomposites  

SciTech Connect (OSTI)

Radiation detection demands new scintillators with high quantum efficiency, high energy resolution and short luminescence lifetimes. Nanocomposites consisting of quantum dots and Ce3+ doped nanophosphors may be able to meet these requirements. Here we report the luminescence of LaF3:Ce/CdTe nanocomposites which were synthesized by a wet chemistry method. In LaF3:Ce/CdTe nanocomposites the CdTe quantum dots are converted into nanowires, while in LaF3/CdTe nanocomposites no such conversion is observed. The CdTe luminescence in LaF3:Ce/CdTe nanocomposites is enhanced about 5 times, while in LaF3/CdTe nanocomposites no enhancement was observed. Energy transfer, light-re-absorption and surface passivation are likely the reasons for the luminescence enhancement.

Yao, Mingzhen; Zhang, Xing; Ma, Lun; Chen, Wei; Joly, Alan G.; Huang, Jinsong; Wang, Qingwu

2010-11-15T23:59:59.000Z

144

A dipole polarizable potential for reduced and doped CeO[subscript 2] obtained from first principles  

E-Print Network [OSTI]

In this paper we present the parameterization of a new interionic potential for stoichiometric, reduced and doped CeO[subscript 2]. We use a dipole polarizable potential (DIPPIM: the dipole polarizable ion model) and ...

Burbano, Mario

145

Impact of the CE mark approval on exit opportunities and validation for early stage medical device companies  

E-Print Network [OSTI]

The aim of this thesis was to look at the impact of acquiring the CE marking approval on the outcome of early stage medical device companies, specifically its impact on strategic acquisition opportunities and on valuation. ...

Kothari, Ashish (Ashish Shrikant)

2011-01-01T23:59:59.000Z

146

Adsorption and Reaction of C1-C3 Alcohols over CeOx(111) Thin Films  

SciTech Connect (OSTI)

This study reports the interaction of methanol, ethanol, 1-propanol, and 2-propanol with well-ordered CeO{sub 2}(111) thin film surfaces. All of the alcohols adsorb at low temperature by forming alkoxy and hydroxyl species on the surface. On fully oxidized CeO{sub 2}(111), recombination occurs between some of the alkoxys and hydroxyls, resulting in alcohol desorption near 220 K. At the same temperature, some of the surface hydroxyls disproportionate to produce water and the loss of lattice O. The remaining alkoxys react above 550 K. The primary alcohols favor dehydrogenation products (aldehydes). There is a net loss of O from the system, resulting in a reduction of the ceria. The secondary alcohol, 2-propanol, undergoes primarily dehydration, producing propene with no net change in the cerium oxidation state. Reduced CeO{sub x}(111) competes with the gaseous products for available O. Little or no water is produced. The reaction selectivity for the C{sub 2} and C{sub 3} alcohols shifts toward favoring dehydration products. The loss of O from the alcohols leads to oxidation of the reduced ceria. Compared with the oxidized surface, the alkene desorption shifts to lower temperature, whereas the aldehyde desorption shifts to higher temperature. This indicates that, on the reduced surface, it is easier to break the C-O bond but more difficult to break the O-substrate bond.

D Mullins; S Senanayake; T Chen

2011-12-31T23:59:59.000Z

147

Morphological and Structural Changes During the Reduction and Reoxidation of CuO/CeO(2) and Ce(1-x)Cu(x)O(2) Nanocatalysts: In-situ Studies with Environmental TEM, XRD and XAS  

SciTech Connect (OSTI)

We have studied the structural, morphological, and electronic properties of CuO/CeO{sub 2} and Ce{sub 1-x}Cu{sub x}O{sub 2} nanocatalysts during reduction/oxidation cycles using H{sub 2} and O{sub 2} as chemical probes. Time-resolved in situ characterization was performed by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) as well as aberration-corrected environmental transmission electron microscopy (ETEM). We have found that both types of nanocatalysts reduce to a Cu/CeO{sub 2} biphase system with significant oxygen vacancies in CeO{sub 2}. Important variations are seen in the Cu particle size and metal dispersion depending on the initial state of the copper oxide-ceria systems. During subsequent in situ oxygen annealing, the Cu precipitated from the CuO/CeO{sub 2} system reoxidized to form CuO through a Cu{sub 2}O intermediate phase as expected. However, the Cu precipitated from the Ce{sub 0.8}Cu{sub 0.2}O{sub 2} solid solution behaved rather differently under oxidizing conditions, and neither oxidized to form CuO nor fully returned to a bulk Ce{sub 0.8}Cu{sub 0.2}O{sub 2} phase in solid solution. We found that {approx} 50% of the Cu returned to a Ce{sub 1-x}Cu{sub x}O{sub 2} solid solution, while the remainder was observed by in situ ETEM to form an amorphous copper oxide phase with a Cu oxidation state similar to Ce{sub 1-x}Cu{sub x}O{sub 2}, but with a local bonding environment similar to CuO. The behavior of the reduced Ce{sub 0.8}Cu{sub 0.2}O{sub 2} reflects strong interactions between Cu and the ceria matrix and illustrates the advantages of working with solid solutions of mixed oxides.

Rodriguez, J.A.; Ciston, J.; Si, R.; Hanson, J.C.; Martínez-Arias, A.; Fernandez-García, M.; Zhu, Y.

2011-07-21T23:59:59.000Z

148

Morphological and Structural Changes during the Reduction and Reoxidation of CuO/CeO2 and Ce1-xCuxO2 Nanocatalysts: In Situ Studies with Environmental TEM XRD and XAS  

SciTech Connect (OSTI)

We have studied the structural, morphological, and electronic properties of CuO/CeO{sub 2} and Ce{sub 1-x}Cu{sub x}O{sub 2} nanocatalysts during reduction/oxidation cycles using H2 and O2 as chemical probes. Time-resolved in situ characterization was performed by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) as well as aberration-corrected environmental transmission electron microscopy (ETEM). We have found that both types of nanocatalysts reduce to a Cu/CeO{sub 2} biphase system with significant oxygen vacancies in CeO{sub 2}. Important variations are seen in the Cu particle size and metal dispersion depending on the initial state of the copper oxide-ceria systems. During subsequent in situ oxygen annealing, the Cu precipitated from the CuO/CeO{sub 2} system reoxidized to form CuO through a Cu2O intermediate phase as expected. However, the Cu precipitated from the Ce{sub 0.8}Cu{sub 0.2}O{sub 2} solid solution behaved rather differently under oxidizing conditions, and neither oxidized to form CuO nor fully returned to a bulk Ce{sub 0.8}Cu{sub 0.2}O{sub 2} phase in solid solution. We found that 50% of the Cu returned to a Ce{sub 1-x}Cu{sub x}O{sub 2} solid solution, while the remainder was observed by in situ ETEM to form an amorphous copper oxide phase with a Cu oxidation state similar to Ce{sub 1-x}Cu{sub x}O{sub 2}, but with a local bonding environment similar to CuO. The behavior of the reduced Ce{sub 0.8}Cu{sub 0.2}O{sub 2} reflects strong interactions between Cu and the ceria matrix and illustrates the advantages of working with solid solutions of mixed oxides.

J Ciston; R Si; J Rodriquez; J Hanson; A Martinez-Arias; M Fernandez-Garcia; Y Zhu

2011-12-31T23:59:59.000Z

149

High thermoelectric performance of In, Yb, Ce multiple filled CoSb{sub 3} based skutterudite compounds  

SciTech Connect (OSTI)

Filling voids with rare earth atoms is an effective way to lowering thermal conductivity which necessarily enhances thermoelectric properties of skutterudite compounds. Yb atom is one of the most effective species among the rare earth atoms for filling the voids in the skutterudite structure due to a large atomic mass, radius and it is intermediate valence state. In this work, we aim to find the best filling partners for Yb using different combinations of Ce and In as well as to optimize actual filling fraction in order to achieve high values of ZT. The traditional method of synthesis relying on melting-annealing and followed by spark plasma sintering was used to prepare all samples. The thermoelectric properties of four samples of Yb{sub 0.2}In{sub 0.2}Co{sub 4}Sb{sub 12}, Yb{sub 0.2}Ce{sub 0.15}Co{sub 4}Sb{sub 12}, Yb{sub 0.2}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12}, and Yb{sub 0.3}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12} (nominal) were examined based on the Seebeck coefficient, electrical conductivity, thermal conductivity, and Hall coefficient. Hall coefficient and Seebeck coefficient signs confirm that all samples are n-type skutterudite compounds. Carrier density increases with the increasing Yb+Ce content. A high power factor value of 57.7 {mu}W/K{sup 2}/cm for Yb{sub 0.2}Ce{sub 0.15}Co{sub 4}Sb{sub 12} and a lower thermal conductivity value of 2.82 W/m/K for Yb{sub 0.2}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12} indicate that small quantities of Ce with In may be a good partner to Yb to reduce the thermal conductivity further and thus enhance the thermoelectric performance of skutterudites. The highest ZT value of 1.43 was achieved for Yb{sub 0.2}Ce{sub 0.15}In{sub 0.2}Co{sub 4}Sb{sub 12} triple-filled skutterudite at 800 K. - Graphical abstract: Thermoelectric figure of merit of Yb{sub x}In{sub y}Ce{sub z}Co{sub 4}Sb{sub 12} (0{<=}x,y,z{<=}0.18 actual) compounds versus temperature. Highlights: Black-Right-Pointing-Pointer TE properties of Yb,In,Ce multiple-filled Yb{sub x}In{sub y}Ce{sub z}Co{sub 4}Sb{sub 12} skutterudites were investigated. Black-Right-Pointing-Pointer Thermal conductivity is strongly suppressed by multiple filling of Yb, Ce and In. Black-Right-Pointing-Pointer Small amounts of Ce and In with Yb are beneficial for the enhancement of TE performance. Black-Right-Pointing-Pointer The highest ZT=1.43 was achieved with Yb{sub 0.07}In{sub 0.094}Ce{sub 0.065}Co{sub 4}Sb{sub 11.92} at 800 K.

Ballikaya, Sedat [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey) [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey); Department of Physics, University of Michigan, Ann Arbor, MI, 48109 (United States); Uzar, Neslihan; Yildirim, Saffettin [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey)] [Department of Physics, University of Istanbul, 34134 Vezneciler, Istanbul (Turkey); Salvador, James R. [Chemical Sci. and Mater. Systems Laboratory, General Motors Global R and D Center, Warren, MI 48090 (United States)] [Chemical Sci. and Mater. Systems Laboratory, General Motors Global R and D Center, Warren, MI 48090 (United States); Uher, Ctirad, E-mail: cuher@umich.edu [Department of Physics, University of Michigan, Ann Arbor, MI, 48109 (United States)] [Department of Physics, University of Michigan, Ann Arbor, MI, 48109 (United States)

2012-09-15T23:59:59.000Z

150

Rationalization of the Hubbard U parameter in CeO{sub x} from first principles: Unveiling the role of local structure in screening  

SciTech Connect (OSTI)

The density functional theory (DFT)+U method has been widely employed in theoretical studies on various ceria systems to correct the delocalization bias in local and semi-local DFT functionals with moderate computational cost. We present a systematic and quantitative study, aiming to gain better understanding of the dependence of Hubbard U on the local atomic arrangement. To rationalize the Hubbard U of Ce 4f, we employed the first principles linear response method to compute Hubbard U for Ce in ceria clusters, bulks, and surfaces. We found that the Hubbard U varies in a wide range from 4.3 eV to 6.7 eV, and exhibits a strong correlation with the Ce coordination number and Ce–O bond lengths, rather than the Ce 4f valence state. The variation of the Hubbard U can be explained by the changes in the strength of local screening due to O ? Ce intersite transitions.

Lu, Deyu, E-mail: dlu@bnl.gov, E-mail: pingliu3@bnl.gov; Liu, Ping, E-mail: dlu@bnl.gov, E-mail: pingliu3@bnl.gov [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973 (United States)] [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973 (United States)

2014-02-28T23:59:59.000Z

151

DOI-BLM-ID-110-2009-3825-CE | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:EnergyWisconsin:2003)CrowleyEnergyMasse) JumpConsultation-2009-3825-CE Jump to:

152

XRD, lead equivalent and UV-VIS properties study of Ce and Pr lead silicate glasses  

SciTech Connect (OSTI)

In this work, Cerium (Ce) and Praseodymium (Pr) containing lead silicate glasses were produced with 2 different molar ratios low (0.2 wt%) and high (0.4wt%). These types of glasses can satisfy the characteristics required for radiation shielding glasses and minimize the lead composition in glass. The radiation shielding properties of the synthesized glasses is explained in the form of lead equivalent study. The XRD diffraction and UV-VIS analysis were performed to observe the structural changes of the synthesis glasses at 1.5 Gy gamma radiation exposures.

Alias, Nor Hayati, E-mail: norhayati@nuclearmalaysia.gov.my; Abdullah, Wan Shafie Wan, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Norriza Mohd, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Muhammad Jamal Md, E-mail: norhayati@nuclearmalaysia.gov.my; Zali, Nurazila Mat; Abdullah, Nuhaslinda Ee [Malaysian Nuclear Agency, 43000, Bangi, Kajang, Selangor (Malaysia); Muhammad, Azali [Malaysian Society for Non-Destructive Testing (Malaysia)

2014-02-12T23:59:59.000Z

153

Data:46440396-c64b-4541-ad0a-43775ce1671b | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b No revisione66e17fc7f7 No revisione18fe97c No revision has been approved for775ce1671b

154

Probing the Reaction Intermediates for the Water-Gas Shift over Inverse CeOx/Au(111) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Rodriguez, J.A.; Senanayake, S.D.; Stacchiola, D.; Evans, J.; Estrella, M.; Barrio-Pliego, L.; Pérez, M.; Hrbek, J.

2010-05-04T23:59:59.000Z

155

Probing the Reaction Intermediates for the Water–gas Shift over Inverse CeOx / Au(1 1 1) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Senanayake, S.; Stacchiola, D; Evans, J; Estrella, M; Barrio, L; Perez, M; Hrbek, J; Rodriguez, J

2010-01-01T23:59:59.000Z

156

X-ray luminescence of CdTe quantum dots in LaF{sub 3}:Ce/CdTe nanocomposites  

SciTech Connect (OSTI)

CdTe quantum dots have intense photoluminescence but exhibit almost no x-ray luminescence. However, intense x-ray luminescence from CdTe quantum dots is observed in LaF{sub 3}:Ce/CdTe nanocomposites. This enhancement in the x-ray luminescence of CdTe quantum dots is attributed to the energy transfer from LaF{sub 3}:Ce to CdTe quantum dots in the nanocomposites. The combination of LaF{sub 3}:Ce nanoparticles and CdTe quantum dots makes LaF{sub 3}:Ce/CdTe nanocomposites promising scintillators for radiation detection.

Hossu, Marius; Liu Zhongxin; Yao Mingzhen; Ma Lun; Chen Wei

2012-01-02T23:59:59.000Z

157

Grant Title: RESEARCH GRANTS FOR PREVENTING VIOLENCE AND VIOLENCE-RELATED INJURY Funding Opportunity Number: RFA-CE-14-006. CFDA Number(s): 93.136.  

E-Print Network [OSTI]

Opportunity Number: RFA-CE-14-006. CFDA Number(s): 93.136. Agency/Department: Centers for Disease Control

Farritor, Shane

158

Nickel deficiency in RENi2-xP2 (RE=La, Ce, Pr). Combined crystallographic and physical property studies  

SciTech Connect (OSTI)

Large single crystals from RENi{sub 2-x}P{sub 2} (RE = La, Ce, Pr) were synthesized from the pure elements using Sn as a metal flux, and their structures were established by X-ray crystallography. The title compounds were confirmed to crystallize in the body-centered tetragonal ThCr{sub 2}Si{sub 2} structure type (space group I4/mmm (No. 139); Pearson's symbol tI10), but with a significant stoichiometry breadth with respect to the transition metal. Systematic synthetic work, coupled with accurate structure refinements indicated strong correlation between the degree of Ni-deficiency and the reaction conditions. For four different PrNi{sub 2-x}P{sub 2} (x {le} 0.5) samples, temperature dependent dc magnetization measurements indicated typical local moment 4f-magnetism and a stable Pr{sup 3+} ground state. Field-dependent heat capacity data confirmed a ferromagnetic order at low temperature, and the variations of T{sub c} with the concentration of Ni defects are discussed. LaNi{sub 2-x}P{sub 2}, as expected was found to be Pauli-like paramagnetic in the studied temperature regime, while the Ce-analog CeNi{sub 2-x}P{sub 2} (x = 0.28(1)) showed the characteristics of a mixed valent Ce{sup 3+}/Ce{sup 4+} system with a possible Kondo temperature on the order of 230 K.

Bauer, Eric D [Los Alamos National Laboratory; Ronning, Filip [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Sarrao, John L [Los Alamos National Laboratory; Bobev, S [U. OF DE; Xia, S [U. OF DE

2008-01-01T23:59:59.000Z

159

Implementation of the SAM-CE Monte Carlo benchmark analysis capability for validating nuclear data and reactor design codes  

SciTech Connect (OSTI)

The National Nuclear Data Center is continuing its program to improve the nuclear data base used as input for commercial reactor analysis and design. In the most recent phase of this project the Monte Carlo program SAM-CE, developed by the Mathematical Applications Group, Inc. (MAGI), was made operational at BNL. This program was implemented on the BNL-CDC-7600 Computer, and also on the PDP-10 in-house computer. The NNDC made operational and developed techniques for processing ENDF/B-V cross sections for SAM-CE. A limited ENDF/B-V based library was produced. Use of the SAM-CE program in thermal reactor problems was validated using detailed comparisons of results with other Monte Carlo codes such as RECAP, RCP01 and VIM as well as with experimental data.

Beer, M.; Rose, P.

1981-04-01T23:59:59.000Z

160

On the local electronic and atomic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films on Si  

SciTech Connect (OSTI)

The local electronic and atomic structure of (111)-oriented, single crystalline mixed Ce{sub 1?x}Pr{sub x}O{sub 2??} (x?=?0, 0.1 and 0.6) epitaxial thin films on silicon substrates have been investigated in view of engineering redox properties of complex oxide films. Non-destructive X-ray absorption near edge structure reveals that Pr shows only +3 valence and Ce shows only nominal +4 valence in mixed oxides. Extended x-ray absorption fine structure (EXAFS) studies were performed at K edges of Ce and Pr using a specially designed monochromator system for high energy measurements. They demonstrate that the fluorite lattice of ceria (CeO{sub 2}) is almost not perturbed for x?=?0.1 sample, while higher Pr concentration (x?=?0.6) not only generates a higher disorder level (thus more disordered oxygen) but also causes a significant reduction of Ce–O interatomic distances. The valence states of the cations were also examined by techniques operating in highly reducing environments: scanning transmission electron microscopy-electron energy loss spectroscopy and X-ray photoemission spectroscopy; in these reducing environments, evidence for the presence of Ce{sup 3+} was clearly found for the higher Pr concentration. Thus, the introduction of Pr{sup 3+} into CeO{sub 2} strongly enhances the oxygen exchange properties of CeO{sub 2}. This improved oxygen mobility properties of CeO{sub 2} are attributed to the lattice disorder induced by Pr mixing in the CeO{sub 2} fluorite lattice, as demonstrated by EXAFS measurements. Thus, a comprehensive picture of the modifications of the atomic and electronic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films and their relation is obtained.

Niu, Gang, E-mail: gang@ihp-microelectronics.com; Schubert, Markus Andreas; Zoellner, Marvin Hartwig [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); D'Acapito, Francesco [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, Thomas [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus-Senftenberg, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, Federico [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Department of Physics and Astronomy, University of Bologna, via le C. Berti Pichat 6/2, 40127 Bologna (Italy)

2014-09-28T23:59:59.000Z

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
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161

456 IEEE TRANSACTIONS ON ROBOTICS, VOL. 24, NO. 2, APRIL 2008 the PA10-6CE utilizing the geometric and flexibility calibration method  

E-Print Network [OSTI]

456 IEEE TRANSACTIONS ON ROBOTICS, VOL. 24, NO. 2, APRIL 2008 the PA10-6CE utilizing the geometric for demanding dynamic ap- plications with the PA10-6CE robot arm. ACKNOWLEDGMENT The authors thank N. Mauntler in robot joints with harmonic drives and torque sensors," Int. J. Robot. Res., vol. 16, no. 2, pp. 214­ 239

162

The University of Florida Dean of Students O ce creates a culture of care for students, their families, faculty and sta by providing exemplary  

E-Print Network [OSTI]

The University of Florida Dean of Students O ce creates a culture of care for students. Develop an inclusive physical environment for Veteran services and resources. Focus energy towards 2012. Complete and implement recommendations from the O ce of Audit & Compliance Review internal audit

Roy, Subrata

163

The effect of Au and Ni doping on the heavy fermion state of the Kondo lattice antiferromagnet CePtZn  

SciTech Connect (OSTI)

We have probed the effect of doping CePtZn with Au and Ni and also investigated in detail the magnetic behavior of the iso-structural CeAuZn. A magnetic ground state is observed in both CePt{sub 0.9}Au{sub 0.1}Zn and CePt{sub 0.9}Ni{sub 0.1}Zn with T{sub N}?=?2.1 and 1.1?K and the coefficient of the linear term of electronic heat capacity ??=?0.34 and 0.9?J/mol K{sup 2}, respectively. The corresponding values for CePtZn are 1.7?K and 0.6?J/mol K{sup 2}. The altered values of T{sub N} and ? show that the electronic correlations in CePtZn are affected by doping with Au and Ni. CeAuZn orders magnetically near 1.7?K and its electrical resistivity shows a normal metallic behavior. Together with a ? of 0.022?J/mol K{sup 2} the data indicate a weak 4f-conduction electron hybridization in CeAuZn characteristic of normal trivalent cerium based systems.

Dhar, S. K., E-mail: sudesh@tifr.res.in [DCMPMS, T.I.F.R., Homi Bhabha Road, Colaba, Mumbai 400005 (India); Aoki, Y.; Suemitsu, B.; Miyazaki, R. [Department of Physics, Tokyo Metropolitan University, Minami-Ohsawa 1-1, Hachioji-Shi, Tokyo (Japan); Provino, A.; Manfrinetti, P. [Departimento Physica Chemicale, Universita di Genova, Via Dodecaneso, 16146 Genova (Italy)

2014-05-07T23:59:59.000Z

164

\\\\Ce_equine3\\public\\Cheryl\\WebDocuments\\OnLine\\CCYouthNomForm.doc NEW HAMPSHIRE 4-H CURRICULUM COMMITTEE  

E-Print Network [OSTI]

\\\\Ce_equine3\\public\\Cheryl\\WebDocuments\\OnLine\\CCYouthNomForm.doc NEW HAMPSHIRE 4-H CURRICULUM, including this year? #12;\\\\Ce_equine3\\public\\Cheryl\\WebDocuments\\OnLine\\CCYouthNomForm.doc 2. List and structure of 4-H (service, training, background, etc.) 4. What special attributes does this youth have

New Hampshire, University of

165

Momentum transfer driven textural changes of CeO{sub 2} thin films  

SciTech Connect (OSTI)

The influence of the target erosion depth on the film texture was investigated during DC reactive magnetron sputter deposition of CeO{sub 2} thin films. Three fluxes towards the substrate surface (the relative negative oxygen ion flux, the material flux, and the energy flux) were measured and related to the ongoing erosion of a cerium target. As the deposition rate increased for more eroded targets, both the energy flux and the negative ion flux decreased. Cerium oxide thin films that were deposited at different target erosion states, exhibited a change in preferential crystalline orientation from [200] to [111]. This textural change cannot be explained in terms of the energy per arriving atom concept. Instead, it is shown that the momentum of the high energetic negative ions is an essential condition to clarify the witnessed trends.

Van Steenberge, S., E-mail: sigelinde.vansteenberge@ugent.be; Leroy, W. P.; Depla, D. [Department of Solid State Sciences, Ghent University, Krijgslaan 281/S1, 9000 Ghent (Belgium); Hubin, A. [Department of Materials and Chemistry, Vrije Universiteit Brussel, Pleinlaan 2, 1050 Brussels (Belgium)

2014-09-15T23:59:59.000Z

166

Preparation, crystallography, magnetic and magnetothermal properties of Ce5SiGe4-x alloys  

SciTech Connect (OSTI)

An investigation of the crystal structure and the phase relationships in the Ce{sub 5}Si{sub 4-x}Ge{sub x} system has been carried out. The crystal structures of the single phase intermetallics were characterized using X-ray powder diffraction and subsequent refinement employing the Rietveld analysis technique was performed. The intermetallic system was found to crystallize in three distinct crystal structures. The Ce{sub 5}Si{sub 4}-based solid solution extends from x = 0 to x = 2.15 and it was found to crystallize in the well-known Zr{sub 5}Si{sub 4}-type tetragonal structure. The germanium rich alloys, where 3.1 {le} x {le} 4, crystallized in the Sm{sub 5}Ge{sub 4}-type orthorhombic structure. The crystal structure of the intermediate phase, when 2.35 {le} x {le} 2.8, was found out to be of the Gd{sub 5}Si{sub 2}Ge{sub 2}-type monoclinic structure. Microhardness tests were conducted on the samples in order to probe the trend in mechanical properties in this alloy system as a function of Ge concentration. The magnetic, thermal and magnetocaloric properties of the Ce{sub 5}Si{sub 4-x}Ge{sub x} alloy system have been investigated for x = 0, 1.0, 1.8, 2.5, 2.8, 3.5, 3.8 and 4.0. The phases with x = 0, 1.0 and 1.8 crystallize in the tetragonal Zr{sub 5}Si{sub 4} structure and those with x = 2.5, 2.8 form in the Gd{sub 5}Si{sub 2}Ge{sub 2}-type monoclinic structure. The alloys with x = 3.5, 3.8 and 4.0 crystallize in the Sm{sub 5}Ge{sub 4}-type orthorhombic structure. The Curie temperature of the tetragonal phases increases with increasing Ge content. The ordering temperatures of the monoclinic and orthorhombic phases remain nearly unaffected by the composition, with the Curie temperatures of the latter slightly higher than those of the former. All the alloys display evidence of antiferromagnetic interactions in the ground state. The orthorhombic and the monoclinic alloys behave as ferromagnets whereas the Si-rich tetragonal phase acts more like an antiferromagnet at high fields (1 T and higher). The maximum isothermal magnetic entropy change occurs at {approx}11 K in the monoclinic and orthorhombic phases with the highest value being 14.7 J/kg.K for Ce{sub 5}Ge{sub 4} for a field change of 10 T which is considered moderate.

Vijayaraghavan, Rangarajan

2005-05-01T23:59:59.000Z

167

Vortex Lattice Studies in CeCoIn? with H?c  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We present small angle neutron scattering studies of the vortex lattice (VL) in CeCoIn? with magnetic fields applied parallel (H) to the antinodal [100] and nodal [110] directions. For H II 100], a single VL orientation is observed, while a 90° reorientation transition is found for H II [110]. For both field orientations and VL configurations we find a distorted hexagonal VL with an anisotropy, ?=2.0±0.05. The VL form factor shows strong Pauli paramagnetic effects similar to what have previously been reported for H II [001]. At high fields, above which the upper critical field (Hc2) becomes a first-order transition, an increased disordering of the VL is observed.

Das, P.; White, J. S.; Holmes, A. T.; Gerber, S.; Forgan, E. M.; Bianchi, A. D.; Kenzelmann, M.; Zolliker, M.; Gavilano, J. L.; Bauer, E. D.; Sarrao, J. L.; Petrovic, C.; Eskildsen, M. R.

2012-02-01T23:59:59.000Z

168

Theoretical studies of Ir5Th and Ir5Ce nanoscale precipitates in Ir  

SciTech Connect (OSTI)

Experimentally, it is known that very small amounts of thorium and/or cerium added to iridium metal form a precipitate, Ir5Th / Ir5Ce, which improves the high temperature mechanical properties of the resulting alloys. We demonstrate that there are low-energy configurations for nano-scale precipitates of these phases in Ir, and that these coherent arrangements may assist in producing improved mechanical properties. One precipitate/matrix orientation gives a particularly low interfacial energy, and a low lattice misfit. Nanolayer precipitates with this orientation are found to be likely to form, with little driving force to coarsen. The predicted morphology of the precipitates and their orientation with the matrix phase provide a potential experiment that could be used to test these predictions.

Morris, James R [ORNL] [ORNL; Averill, Frank [ORNL] [ORNL; Cooper, Valentino R [ORNL] [ORNL

2014-01-01T23:59:59.000Z

169

Complex magnetic ordering in CeFe1.76 studied by neutron diffraction  

SciTech Connect (OSTI)

Neutron diffraction measurements on a single crystal of CeGe1.76 reveal a complex series of magnetic transitions at low temperature. At TN?7 K, there is a transition from a paramagnetic state at higher temperature to an incommensurate magnetic structure characterized by a magnetic propagation vector (0 0 ?) with ??14 and the magnetic moment along the a axis of the orthorhombic unit cell. Below TLI?5 K, the magnetic structure locks in to a commensurate structure with ?=14 and the magnetic moment remains along the a axis. Below T??4 K, we find additional half-integer and integer indexed magnetic Bragg peaks consistent with a second commensurately ordered antiferromagnetic state.

Jayasekara, Wageesha T [Ames Laboratory; Tian, W [Oak Ridge National Laboratory; Hodovanets, Halyna [Ames Laboratory; Canfield, Paul C [Ames Laboratory; Bud'ko, Serguei L [Ames Laboratory; Kreyssig, Andreas [Ames Laboratory; Goldman, Alan I [Ames Laboratory

2014-10-01T23:59:59.000Z

170

UCL SChooL of Life and MediCaL SCienCeS Creating knowledge, achieving impact  

E-Print Network [OSTI]

UCL SChooL of Life and MediCaL SCienCeS Creating knowledge, achieving impact Population Health 4 #12;PREFACE UCL's School of Life and Medical Sciences encompasses arguably the greatest concentration Assessment Exercise was outstanding, and for most key measures the School comfortably tops UK league tables

Saunders, Mark

171

Pour citer ce document : CHELKOFF, Grgoire. For an ecological approach to architecture : perception and design. First International Workshop  

E-Print Network [OSTI]

Pour citer ce document : CHELKOFF, Grégoire. For an ecological approach to architecture : perception and design. First International Workshop : Architectural and urban Ambient Environment, Nantes, 6-7-8 Février 2002. Nantes: CERMA, Ecole D'architecture de Nantes, 2002, 11p. For an ecological approach

Paris-Sud XI, Université de

172

CO Oxidation at the Au-Cu Interface of Bimetallic Nanoclusters Supported on CeO2(111)  

E-Print Network [OSTI]

of tunable interfaces, metal and oxide,9,12,15-18 metal and carbide,19 and oxide and oxide,2 of the structure of CeO2(111)-supported Au- based bimetallic nanoclusters (NCs) show that a strong support-metal Materials, and Catalysis The critical role of the interface between a supporting oxide and supported metal

Henkelman, Graeme

173

Synthesis and properties of Sr2CeO4 blue emission powder phosphor for field emission displays  

E-Print Network [OSTI]

for publication 19 January 1999 A blue emission powder phosphor Sr2CeO4 for field emission displays was preparedV. The emission peak of this phosphor is at 470 nm and Commission International de l'Eclairage coordinates are x 0

Wang, Zhong L.

174

Charge transfer and formation of reduced Ce{sup 3+} upon adsorption of metal atoms at the ceria (110) surface  

SciTech Connect (OSTI)

The modification of cerium dioxide with nanoscale metal clusters is intensely researched for catalysis applications, with gold, silver, and copper having been particularly well studied. The interaction of the metal cluster with ceria is driven principally by a localised interaction between a small number of metal atoms (as small as one) and the surface and understanding the fundamentals of the interaction of metal atoms with ceria surfaces is therefore of great interest. Much attention has been focused on the interaction of metals with the (111) surface of ceria, since this is the most stable surface and can be grown as films, which are probed experimentally. However, nanostructures exposing other surfaces such as (110) show high activity for reactions including CO oxidation and require further study; these nanostructures could be modified by deposition of metal atoms or small clusters, but there is no information to date on the atomic level details of metal-ceria interactions involving the (110) surface. This paper presents the results of density functional theory (DFT) corrected for on-site Coulomb interactions (DFT+U) calculations of the adsorption of a number of different metal atoms at an extended ceria (110) surface; the metals are Au, Ag, Cu, Al, Ga, In, La, Ce, V, Cr, and Fe. Upon adsorption all metals are oxidised, transferring electron(s) to the surface, resulting in localised surface distortions. The precise details depend on the identity of the metal atom. Au, Ag, Cu each transfer one electron to the surface, reducing one Ce ion to Ce{sup 3+}, while of the trivalent metals, Al and La are fully oxidised, but Ga and In are only partially oxidised. Ce and the transition metals are also partially oxidised, with the number of reduced Ce ions possible in this surface no more than three per adsorbed metal atom. The predicted oxidation states of the adsorbed metal atoms should be testable in experiments on ceria nanostructures modified with metal atoms.

Nolan, Michael [Tyndall National Institute, University College Cork, Lee Maltings, Prospect Row, Cork (Ireland)

2012-04-07T23:59:59.000Z

175

Synthesis, Structures, and Magnetic Properties of Rare-Earth Cobalt Arsenides, RCo2As2 (R = La, Ce, Pr, Nd)  

SciTech Connect (OSTI)

Four rare-earth cobalt arsenides, RCo2As2 (R = La, Ce, Pr, Nd), were obtained by reactions of constituent elements in molten Bi. The use of Bi flux also allowed the growth of representative single crystals. All compounds are isostructural and belong to the ThCr2Si2 structure type (space group I4/mmm). The formation of Co vacancies is observed in all structures, while the structures of La- and Ce-containing compounds also show incorporation of minor Bi defects next to the R crystallographic site. Correspondingly, the general formula of these materials can be written as R1 xBixCo2 As2, with x/ = 0.03/0.1, 0.05/0.15, 0/0.2, and 0/0.3 for R = La, Ce, Pr, and Nd, respectively. All compounds exhibit high-temperature ferromagnetic ordering of Co magnetic moments in the range of 150-200 K. Electronic band structure calculations revealed a high peak in the density of states at the Fermi level, thus supporting the itinerant nature of magnetism in the Co sublattice. The magnetic ordering in the lanthanide sublattice takes place at lower temperatures, with the R moments aligning antiparallel to the Co moments to give a ferrimagnetic ground state. The measurements on oriented single crystals demonstrated significant magnetic anisotropy in the ferrimagnetic state, with the preferred moment alignment along the c axis of the tetragonal lattice. Neutron powder diffraction failed to reveal the structure of magnetically ordered states, but confirmed the presence of Co vacancies. X-ray absorption near-edge structure spectroscopy on Ce1.95Bi0.05Co1.85As2 showed the average oxidation state of Ce to be +3.06. Solid state NMR spectroscopy revealed a substantially reduced hyperfine field on the Co atoms in the vicinity of Bi defects.

Thompson, Corey [Florida State University, Tallahassee] [Florida State University, Tallahassee; Tan, Xiaoyan [Florida State University, Tallahassee] [Florida State University, Tallahassee; Kovnir, Kirill [Florida State University, Tallahassee] [Florida State University, Tallahassee; Garlea, Vasile O [ORNL] [ORNL; Shatruk, Michael [Florida State University, Tallahassee] [Florida State University, Tallahassee

2014-01-01T23:59:59.000Z

176

Effect of MnO on the microstructures, phase stability and mechanical properties of ceria-partially-stabilized zirconia (Ce-TZP) and Ce-TZP-Al sub 2 O sub 3 composites  

SciTech Connect (OSTI)

Effect of increasing amounts of MnO additions on the microstructures, phase stability and mechanical properties of ZrO{sub 2}-12 m% CeO{sub 2} and ZrO{sub 2}-12 m% CeO{sub 2}-10 w% Al{sub 2}O{sub 3} were studied. MnO suppressed grain growth in ZrO{sub 2}-12 m% CeO{sub 2}, while enhancing the mechanical properties significantly (strength=557 MPa, fracture toughness=9.3 MPa.(m){sup 1/2} at 0.2 w% MnO). The enhanced mechanical properties were achieved despite an increased stability of the tetragonal phase as evidenced by a lower burst transformation temperature (M{sub b}) and a reduced volume fraction of the monoclinic phase on the fracture surface. In ZrO{sub 2}-12 m% CeO{sub 2}-10 w% Al{sub 2}O{sub 3}, the addition of MnO suppressed the grain size of ZrO{sub 2}, while promoting grain growth and changing the morphology of Al{sub 2}O{sub 3}. More significantly, the stability of the tetragonal ZrO{sub 2} phase decreased (high M{sub b} temperature) with a concurrent increase in fracture toughness (13.2 MPa.(m){sup 1/2} at 2 w% MnO) and transformation plasticity (1.2% in four-point bending). The widths of the transformation zones observed adjacent to the fracture surfaces showed a consistent inverse relation to the transformation yield stress as would be expected from the mechanics of stress-induced phase transformation at crack tips. The improvements in mechanical properties obtained in the base Ce-TZP and the Ce-TZP-Al{sub 2}O{sub 3} composite ceramics with the addition of MnO are critically examined in the context of transformation toughening and other possible mechanisms.

Wang, J.S.; Tsai, J.F.; Shetty, D.K.; Virkar, A.V. (Department of Materials Science and Engineering, University of Utah, Salt Lake City, UT (USA))

1990-09-01T23:59:59.000Z

177

HL Power Geothermal Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation,Ohio:Greer County is a countyon State Highways | OpenD -HCE LLCHL Power

178

HL Power Company | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to:Photon Place:Net JumpStrategy | Open EnergyHawaiiH2GoHERA USAHL

179

A benchmark for investigating the radial dependence of C/E for control rod worths in large decoupled cores  

SciTech Connect (OSTI)

The first physics measurements of a heterogeneous core on the critical assembly ZPPR-7 at ANL showed that the C/E ratios with ENDF/B data for the worths of the control rods in the outer bank were several percent higher than those at the inner bank positions. This radial variation in the C/E for the rod worths was further confirmed in the analysis of the large conventional core ZPPR-10, and again in the analysis of the large heterogeneous core series ZPPR-13. In the design of a power reactor, the number of control rods, and their disposition, are determined by calculations. Misprediction of the worth of the control rods can lead to serious economic penalties by restricting the operation of the core. Retrofitting a core to accommodate more worth will be costly and is likely to lead to a non-optimized core. This document provides a discussion of these calculations. 7 refs., 7 figs., 12 tabs.

Salvatores, M. (CEA Centre d'Etudes Nucleaires de Cadarache, 13 - Saint-Paul-lez-Durance (France)); Orechwa, Y. (Argonne National Lab., IL (USA)); Collins, P.J. (Argonne National Lab., Idaho Falls, ID (USA))

1990-01-01T23:59:59.000Z

180

Q-dependence of the spin fluctuations in the intermediate valence compound CePd3  

SciTech Connect (OSTI)

We report inelastic neutron scattering experiments on a single crystal of the intermediate valence compound CePd3. At 300 K the magnetic scattering is quasielastic, with half-width G = 23 meV, and is independent of momentum transfer Q. At low temperature, the Q-averaged magnetic spectrum is inelastic, exhibiting a broad peak centered near E-max = 55 meV. These results, together with the temperature dependence of the susceptibility, 4f occupation number, and specific heat, can be fit by the Kondo/Anderson impurity model. The low temperature scattering near Emax, however, shows significant variations with Q, reflecting the coherence of the 4f lattice. The intensity is maximal at (1/2, 1/2, 0), intermediate at (1/2, 0, 0) and (0, 0, 0), and weak at (1/2, 1/2, 1/2). We discuss this Q-dependence in terms of current ideas about coherence in heavy fermion systems.

Fanelli, V. R.; Lawrence, J. M.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Thompson, J. D.; Booth, C. H.; Christianson, A. D.; Riseborough, P. S.

2014-06-25T23:59:59.000Z

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181

Observation of inner-shell-excited configurations in triply ionized cerium Ce{sup 3+}  

SciTech Connect (OSTI)

We report wavelength measurements and energy levels for the three-times ionized cerium atom Ce{sup 3+}. The spectrum is that of a simple one-electron atom overlaid with a more complex three-electron spectrum originating from the excitation of an electron in the inner closed shell to the valence shell. The data provide energy levels for the inner-shell-excited configurations 5p{sup 5}4f5d and 5p{sup 5}4f6s and solve a long-standing puzzle regarding the fine structure of the 5p{sup 6}6d configuration, which is known to be anomalously large and inverted. The data show that this anomalous fine structure is the result of interaction between 5p{sup 6}6d and the inner-shell-excited configuration 5p{sup 5}4f5d. The results are supported by Hartree-Fock calculations and least-squares fits of the energy parameters to the observed levels. From our observed 5p{sup 6}6g configuration, we determine the ionization energy as 297670{+-}70 cm{sup -1} (36.906{+-}0.009 eV)

Reader, Joseph; Wyart, Jean-Francois [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Laboratoire Aime Cotton, CNRS, Universite Paris-Sud, Batiment 505, 91405 Orsay Cedex (France)

2009-10-15T23:59:59.000Z

182

Ion-Beam-Induced Chemical Mixing at a Nanocrystalline CeO2–Si Interface  

SciTech Connect (OSTI)

Thin films of nanocrystalline ceria deposited onto a silicon substrate have been irradiated with 3 MeV Au+ ions to a total dose of 34 displacements per atom to examine the film/substrate interfacial response upon displacement damage. Under irradiation, a band of contrast is observed to form that grows under further irradiation. Scanning and high-resolution transmission electron microscopy imaging and analysis suggest that this band of contrast is a cerium silicate phase with an approximate Ce:Si:O composition ratio of 1:1:3 in an amorphous nature. The slightly nonstoichiometric composition arises due to the loss of mobile oxygen within the cerium silicate phase under the current irradiation condition. This nonequilibrium phase is formed as a direct result of ion-beam-induced chemical mixing caused by ballistic collisions between the incoming ion and the lattice atoms. This may hold promise in ion beam engineering of cerium silicates for microelectronic applications e.g., the fabrication of blue LEDs.

Edmondson, P. D.; Young, Niel P.; Parish, Chad M.; Moll, Sandra J.; Namavar, Fereydoon; Weber, William J.; Zhang, Yanwen

2013-02-28T23:59:59.000Z

183

Ion-Beam-Induced Chemical Mixing at a Nanocrystalline CeO2 Si Interface  

SciTech Connect (OSTI)

Thin films of nanocrystalline ceria deposited onto a silicon substrate have been irradiated with 3 MeV Au+ ions to a total dose of 34 displacements per atom to examine the film/substrate interfacial response upon displacement damage. Under irradiation, a band of contrast is observed to form that grows under further irradiation. Scanning and high-resolution transmission electron microscopy imaging and analysis suggest that this band of contrast is a cerium silicate phase with an approximate Ce:Si:O composition ratio of 1:1:3 in an amorphous nature. The slightly nonstoichiometric composition arises due to the loss of mobile oxygen within the cerium silicate phase under the current irradiation condition. This nonequilibrium phase is formed as a direct result of ion-beam-induced chemical mixing caused by ballistic collisions between the incoming ion and the lattice atoms. This may hold promise in ion beam engineering of cerium silicates for microelectronic applications e.g., the fabrication of blue LEDs.

Edmondson, Dr. Philip [University of Oxford; Young, Neil P. [Department of Materials, University of Oxford, Parks Rd, Oxford, OX1 3PH, UK; Parish, Chad M [ORNL; Moll, Sandra [CEA, Saclay, France; Namavar, Fereydoon [University of Nebraska Medical Center; Weber, William J [ORNL; Zhang, Yanwen [ORNL

2013-01-01T23:59:59.000Z

184

Cellulase for commodity products from cellulosic biomass Michael E Himmel*?, Mark F Ruth*1 and Charles E Wymans  

E-Print Network [OSTI]

dramatically over the past two decades, to the point where the fuel is now competitive for blending with gasoline to reduce greenhouse gas emissions, enhance octane, extend the gasoline supply, and promote more

California at Riverside, University of

185

Structure Sensitivity of the Low-temperature Water-gas Shift Reaction on Cu–CeO2 catalysts  

SciTech Connect (OSTI)

We have investigated the structure sensitivity of the water-gas shift (WGS) reaction on Cu-CeO{sub 2} catalysts prepared at the nanoscale by different techniques. On the surface of ceria, different CuO{sub x} structures exist. We show here that only the strongly bound Cu-[O{sub x}]-Ce species, probably associated with the surface oxygen vacancies of ceria, are active for catalyzing the low-temperature WGS reaction. Weakly bound CuO{sub x} clusters and CuO nanoparticles are spectator species in the reaction. Isolated Cu{sup 2+} ions doping the ceria surface are not active themselves, but they are important in that they create oxygen vacancies and can be used as a reservoir of copper to replenish surface Cu removed by leaching or sintering. Accordingly, synthesis techniques such as coprecipitation that allow for extensive solubility of Cu in ceria should be preferred over impregnation, deposition-precipitation, ion exchange or another two-step method whereby the copper precursor is added to already made ceria nanocrystals. For the synthesis of different structures, we have used two methods: a homogeneous coprecipitation (CP), involving hexamethylenetetramine as the precipitating agent and the pH buffer; and a deposition-precipitation (DP) technique. In the latter case, the ceria supports were first synthesized at the nanoscale with different shapes (rods, cubes) to investigate any potential shape effect on the reaction. Cu-CeO{sub 2} catalysts with different copper contents up to ca. 20 at.% were prepared. An indirect shape effect of CeO{sub 2}, manifested by the propensity to form oxygen vacancies and strongly bind copper in the active form, was established; i.e. the water-gas shift reaction is not structure-sensitive. The apparent activation energy of the reaction on all samples was similar, 50 {+-} 10 kJ/mol, in a product-free (2% CO-10% H{sub 2}O) gas mixture.

Si, R.; Zhang, L.; Raitano, J.; Yi, N.; Chan, S.-W.; Flytzani-Stephanopoulos, M.

2012-01-17T23:59:59.000Z

186

Characterization of Ce SUP 3+-tributyl phosphate coordination complexes produced by fused droplet electrospray ionization with a target capillary  

SciTech Connect (OSTI)

Coordination complexes containing Ce(III) and tri-n-butyl phosphate (TBP) in the 1+, 2+ and 3+ charge states were generated using desorption electrospray ionization (DESI) mass spectrometry, in which the analyte solutions were supplied via a target capillary orthogonally situated with respect to the electrospray. Comparison with direct electrospray (ESI) showed that the same coordination complexes were produced in each experiment, and could be described by the general formula [Ce(NO3)m=0-2(TBP)n](3-m)+. This result indicates that DESI has utility for measuring metal speciation for metal ligand solutions where the gas-phase complexes generated by ESI have been correlated with solution speciation. Such an application would be useful for analyses where it is desirable to limit the total amount of metal being handled, or that have solvent systems that are not readily amenable to ESI. Both the direct ESI and DESI mass spectra showed similar trends with respect to the TBP:Ce ratio, viz. high values tend to favor formation of a larger fraction of the 1+ species, and the 2+ and 3+ species become relatively more important as the ratio is decreased. Within individual charge state ion envelopes, lower TBP:Ce ratios produce coordination complexes with fewer ligands, a trend also seen using both approaches. These trends again point toward strong similarity between the direct ESI and DESI analyses of the metal-ligand solutions. The DESI experiments were less sensitive for measuring the coordination complexes compared to the direct ESI experiments, by a factor of 10 - 100 depending on whether minimum detectable concentration or absolute ion abundances were considered. Nevertheless, mid-picomolar quantities of coordination complexes were measured using the target capillary, indicating that sensitivity would be sufficient for measuring species in many industrial separations processes.

Gary S. Groenewold; Jean-Jacques Gaumet

2011-12-01T23:59:59.000Z

187

Anomalous Chemical Expansion Behavior of Pr[subscript 0.2]Ce[subscript 0.8]O[subscript 2-?] Thin Films Grown by Pulsed Laser Deposition  

E-Print Network [OSTI]

The chemomechanical and electrical properties of (Pr,Ce)O[subscript 2-?] thin films were studied between 30 and 875°C in air by in situ X-ray diffraction and complex impedance spectroscopy measurements. Reduction/oxidation ...

Kuru, Y.

188

Adsorption and Reaction of C(1)-C(3) Alcohols over CeO(x)(111) Thin Films  

SciTech Connect (OSTI)

This study reports the interaction of methanol, ethanol, 1-propanol, and 2-propanol with well-ordered CeO{sub 2}(111) thin film surfaces. All of the alcohols adsorb at low temperature by forming alkoxy and hydroxyl species on the surface. On fully oxidized CeO{sub 2}(111), recombination occurs between some of the alkoxys and hydroxyls, resulting in alcohol desorption near 220 K. At the same temperature, some of the surface hydroxyls disproportionate to produce water and the loss of lattice O. The remaining alkoxys react above 550 K. The primary alcohols favor dehydrogenation products (aldehydes). There is a net loss of O from the system, resulting in a reduction of the ceria. The secondary alcohol, 2-propanol, undergoes primarily dehydration, producing propene with no net change in the cerium oxidation state. Reduced CeO{sub X}(111) competes with the gaseous products for available O. Little or no water is produced. The reaction selectivity for the C{sub 2} and C{sub 3} alcohols shifts toward favoring dehydration products. The loss of O from the alcohols leads to oxidation of the reduced ceria. Compared with the oxidized surface, the alkene desorption shifts to lower temperature, whereas the aldehyde desorption shifts to higher temperature. This indicates that, on the reduced surface, it is easier to break the C-O bond but more difficult to break the O-substrate bond.

Mullins, David R [ORNL; Senanayake, Sanjaya D [ORNL; Chen, Tsung-Liang [ORNL

2010-01-01T23:59:59.000Z

189

Characterization of CeO2-Supported Cu-Pd Bimetallic Catalyst for the Oxygen-Assisted Water-Gas Shift Reaction  

SciTech Connect (OSTI)

This study was focused to investigate the roles of Cu and Pd in CuPd/CeO2 bimetallic catalysts containing 20-30 wt% Cu and 0.5-1 wt% Pd used in the oxygen-assisted water-gas shift (OWGS) reaction employing a combined bulk and surface characterization techniques such as XRD, TPR, CO chemisorption, and in-situ XPS. The catalytic activity for CO conversion and the stability of catalyst during on-stream operation increased by the addition of Cu to Pd/CeO2 or Pd to Cu/CeO2 monometallic catalysts, especially when the OWGS reaction was performed under low temperatures, below 200oC. The bimetallic catalyst after leaching with nitric acid retained about 60% of its original activity. The TPR of monometallic Cu/CeO2 showed reduction of CuO supported on CeO2 in two distinct regions, around 150 and 250oC. The high temperature peak disappeared and reduction occurred in a single step around 150oC upon Pd addition. The Pd dispersion decreased from 38.5% for Pd/CeO2 to below 1% for CuPd/CeO2 bimetallic catalyst. In-situ XPS studies showed a shift in Cu 2p peaks toward lower binding energy (BE) with concommitant shift in the Pd 3d peaks toward higher BE. Addition of Pd decreased the surface Cu concentration while the concentration of Pd remained unaltered. All these observations indicated the formation of Cu-Pd surface alloy. The valence band XP spectra collected below 10 eV corroborated the core level XP spectra and indicated that Cu is mainly involved in the catalytic reaction. The improved catalytic activity and stability of CuPd/CeO2 bimetallic catalyst was attributed to the alloy formation.

Fox, Elise; Velu, Subramani; Engelhard, Mark H.; Chin, Ya-Huei; Miller, Jeffrey T.; Kropf, Jeremy; Song, Chunshan

2008-12-10T23:59:59.000Z

190

Structural characterization of the CeO{sub 2}/Gd{sub 2}O{sub 3} mixed system by synchrotron X-ray diffraction  

SciTech Connect (OSTI)

The structural determination of the CeO{sub 2}/Gd{sub 2}O{sub 3} mixed system is a non-trivial problem because of the close resemblance between the ionic sizes of Ce{sup 4+} and Gd{sup 3+} and between the crystal structures of CeO{sub 2} and Gd{sub 2}O{sub 3}. (Ce{sub 1-x}Gd{sub x})O{sub 2-x/2} powder samples with x ranging between 0 and 1 have been synthesized by coprecipitation of mixed oxalates and subsequent thermal decomposition in air at 1200 Degree-Sign C followed by slow cooling. Synchrotron powder X-ray diffraction data were collected and refined by the Rietveld method. Lattice parameters do not follow Vegard's law and no peak splitting has been observed for any composition, meaning that no biphasic regions exist over the whole compositional range. The same hybrid structural model - a proper mixture of the structures of the two pure oxides - was used for the refinements, allowing to account for the data observed. - graphical abstract: Substituting Ce{sup 4+} by Gd{sup 3+}, a gradual transition from the F structure (typical of CeO{sub 2}) to the C structure (typical of Gd{sub 2}O{sub 3}) takes place. The lattice parameters do not follow Vegard's law. Highlights: Black-Right-Pointing-Pointer A structural study of Ce-Gd mixed oxides has been performed. Black-Right-Pointing-Pointer In (Ce{sub 1-x}Gd{sub x})O{sub 2-x/2} a solid solution forms for 0{<=}x{<=}0.3. Black-Right-Pointing-Pointer For x>0.3 a gradual transition from the C to the F structure is observed. Black-Right-Pointing-Pointer Lattice parameters do not follow Vegard's law.

Artini, Cristina, E-mail: c.artini@ge.ieni.cnr.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Costa, Giorgio A., E-mail: costa@chimica.unige.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); CNR-SPIN Genova, Corso Perrone 24, 16152 Genova (Italy); Pani, Marcella, E-mail: marcella@chimica.unige.it [Dipartimento di Chimica e Chimica Industriale, Universita degli Studi di Genova, Via Dodecaneso 31, 16146 Genova (Italy); Lausi, Andrea, E-mail: andrea.lausi@elettra.trieste.it [Sincrotrone Trieste S.C.p.A., ss 14, km 163, 5, 34149 Basovizza, Trieste (Italy); Plaisier, Jasper, E-mail: jasper.plaisier@elettra.trieste.it [Sincrotrone Trieste S.C.p.A., ss 14, km 163, 5, 34149 Basovizza, Trieste (Italy)

2012-06-15T23:59:59.000Z

191

Crystalline Electric Field as a Probe for Long-Range Antiferromagnetic Order and Superconducting State of CeFeAsO1-xFx  

SciTech Connect (OSTI)

We use inelastic neutron scattering to study the crystalline electric field (CEF) excitations of Ce{sup 3+} in CeFeAsO{sub 1-x}F{sub x} (x=0, 0.16). For nonsuperconducting CeFeAsO, the Ce CEF levels have three magnetic doublets in the paramagnetic state, but these doublets split into six singlets when the Fe ions order antiferromagnetically. For superconducting CeFeAsO{sub 0.84}F{sub 0.16} (T{sub c} = 41 K), where the static antiferromagnetic order is suppressed, the Ce CEF levels have three magnetic doublets at {h_bar}{sub {omega}} = 0, 18.7, 58.4 meV at all temperatures. Careful measurements of the intrinsic linewidth {Lambda} and the peak position of the 18.7 meV mode reveal a clear anomaly at T{sub c}, consistent with a strong enhancement of local magnetic susceptibility {chi}{double_prime}({h_bar}{sub {omega}}) below T{sub c}. These results suggest that CEF excitations in the rare-earth oxypnictides can be used as a probe of spin dynamics in the nearby FeAs planes.

Chi, Songxue [University of Tennessee, Knoxville (UTK); Adroja, D. T. [ISIS Facility, Rutherford Appleton Laboratory; GUIDI, T. [ISIS Facility, Rutherford Appleton Laboratory; Bewley, Robert I. [ISIS Facility, Rutherford Appleton Laboratory; Li, Shiliang [University of Tennessee, Knoxville (UTK); Zhao, Jun [ORNL; Lynn, J. W. [National Institute of Standards and Technology (NIST); Brown, C. M. [National Institute of Standards and Technology (NIST); Qiu, Y. [National Institute of Standards and Technology (NIST); Chen, G. F, [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics; Luo, J. L. [Chinese Academy of Sciences; Wang, N. L. [Chinese Academy of Sciences; Dai, Pengcheng [ORNL

2008-01-01T23:59:59.000Z

192

SESAME 96170, a solid-liquid equation of state for CeO2  

SciTech Connect (OSTI)

I describe an equation of state (EOS) for the low-pressure solid phase and liquid phase of cerium (IV) oxide, CeO{sub 2}. The models and parameters used to calculate the EOS are presented in detail, and I compare with data for the full-density crystal. Hugoniot data are available only for high-porosity powders, and I discuss difficulties in comparing with such data. I have constructed SESAME 96170, an EOS for cerium (IV) oxide that includes the ambient solid and liquid phases. The EOS extends over the full standard SESAME range, but should not be used at low temperatures and high densities because of the lack of a high-pressure solid phase. I have described the models used to compute the three terms of the EOS (cold curve, nuclear, and thermal electronic), and I have given the parameters used in the models. They were determined by comparison with experimental data at P = 1 atm, including the constant-pressure specific heat, coefficient of thermal expansion, and melting and boiling points. The EOS compares well with data in its intended range of validity, but the presence of high-frequency optical modes in its phonon spectrum limits the agreement of our models with thermal data. The next step is to construct a multiphase EOS that includes the low- and high-pressure solid phases and the liquid. The DAC data from Duclos will most strongly constrain the parameters of the high-pressure solid. A remaining issue is the comparison of the crystal-density EOS with experimental Hugoniot data, which are taken at much lower initial data because the samples are porous powders. A satisfactory means of modeling porosity, allowing comparison of theory and experiment, has not yet been produced.

Chisolm, Eric D. [Los Alamos National Laboratory] [Los Alamos National Laboratory

2014-05-02T23:59:59.000Z

193

Interaction of Ce{sub 1?x}Er{sub x}O{sub 2?y} nanoparticles with SiO{sub 2}-effect of temperature and atmosphere  

SciTech Connect (OSTI)

Morphology, microstructure and phase evolution of homogeneous, nanocrystalline Ce{sub 1?x}Er{sub x}O{sub 2?x/2} mixed oxide (x=0.3 and 0.5), prepared by microemulsion method, supported on amorphous SiO{sub 2} was studied in oxidizing and reducing atmosphere by XRD, TEM, SEM-EDS and N{sub 2} adsorption. The system is structurally and chemically stable in the oxidizing atmosphere up to 1000 °C, exhibiting only a small increase of the mean crystallite size of the oxide to ?4 nm. At 1100 °C formation of Er silicate with unusual structure isomorphic with y-Y{sub 2}Si{sub 2}O{sub 7} (yttrialite), stabilized by Ce{sup 4+} ions was observed. In the reducing atmosphere the Ce{sub 1?x}Er{sub x}O{sub 2?x/2} reacted with SiO{sub 2} already at 900 °C, due to high affinity of the reduced Ce{sup 3+} to form a silicate phase. At higher temperature the silicate crystallized into the tetragonal, low temperature A-(Ce{sub 1?x}Er{sub x}){sub 2}Si{sub 2}O{sub 7} polymorph. Such systems, containing nanocrystalline silicate particles with Er{sup 3+} ions placed in well defined sites embedded in silica matrix, may be interesting as highly efficient active components of optical waveguides amplifiers integrated with Si microelectronics. The nanocrystalline Ce–Er–O/SiO{sub 2} system prepared by the impregnation of the silica with the aqueous solution of nitrates appeared to be chemically inhomogeneous and less stable in both oxidising and reducing atmosphere. - Graphical abstract: Structure evolution of Ce{sub 0.5}Er{sub 0.5}O{sub 1.75} in air and in H{sub 2}. Display Omitted - Highlights: • Homogeneous 3 nm Ce{sub 1?x}Er{sub x}O{sub 2?y} particles were prepared and uniformly dispersed on SiO{sub 2}. • Er diffusion to SiO{sub 2} determines the stability of the mixed oxide in air to ?1000 °C. • Spreading of Ce{sub 1?x}Er{sub x}O{sub 2?y} onto SiO{sub 2} occurs in hydrogen at 900 °C. • Nanocrystalline A-(Ce,Er){sub 2}Si{sub 2}O{sub 7} silicate forms in H{sub 2} at 1100 °C.

Kepinski, L., E-mail: L.Kepinski@int.pan.wroc.pl; Krajczyk, L.; Mista, W.

2014-01-15T23:59:59.000Z

194

Data:Ce7ce2d1-1aee-4b6e-b53c-61f5d633ed15 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No revision has

195

Transport properties of partially-filled Ce{sub y}Co{sub 4}Sb{sub 12}  

SciTech Connect (OSTI)

The authors have investigated the magnetic and transport properties of Ce{sub y}Co{sub 4}Sb{sub 12} filled skutterudites with the filling fraction y {le} 0.1. These compounds are n-type materials that develop a magnetic moment upon the presence of trivalent cerium. Cerium has a strong influence on all transport properties and even in small amounts it drastically reduces the lattice thermal conductivity. The resulting figures of merit are comparable to the values established previously for the p-type filled skutterudites.

Uher, C.; Chen, B.; Hu, S.; Morelli, D.T.; Meisner, G.P.

1997-07-01T23:59:59.000Z

196

Data:69ce9c3e-1066-4306-b704-dccfa06245b9 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revision has been approvedea02758d3 Nob05268d8cd No revisionf1fe86ce5f9ae-1b5eba546306 No

197

Data:5289eb16-08ae-4779-aef7-e948945f84ce | Open Energy Information  

Open Energy Info (EERE)

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198

Data:9d9aa544-afad-4985-ba5a-1093160c0ce4 | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 No revision has beenfcf13f143bb No revision has been44632c851160c0ce4 No revision has

199

Data:Ce257723-a06c-4647-a520-102fafcf2c22 | Open Energy Information  

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200

Data:Ce453e06-3085-4555-bb8f-0a6eefe99579 | Open Energy Information  

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201

Data:Ce7bcd1a-3552-4059-96b7-c45de0244033 | Open Energy Information  

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202

Data:Ce81fdcf-0181-4f95-8509-ee44606aaf57 | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No revision

203

Data:Ce930280-ac1e-449d-8c43-c4daf70201be | Open Energy Information  

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204

Synthesis and the crystal and molecular structures of 4-(piperidyl-1)-2-phenylpyrido[2,3-a]anthraquinone-7,12 Mono- and dibromohydrates (HL)Br . 3H{sub 2}O and (H{sub 2}L)Br{sub 2} . 3H{sub 2}O  

SciTech Connect (OSTI)

4-(Piperidyl-1)-2-phenylpyrido[2,3-a]anthraquinone-7,12 monobromohydrate (HL)Br . 3H{sub 2}O (I) and 4-(piperidyl-1)-2-phenylpyrido[2,3-a]anthraquinone-7,12 dibromohydrate (H{sub 2}L)Br{sub 2} . 3H{sub 2}O (II) are isolated in the crystalline state. The crystal structures of compounds I and II are determined using X-ray diffraction. It is established that the protonation of 4-(piperidyl-1)-2-phenylpyrido[2,3-a]anthraquinone-7,12 proceeds primarily through the pyridine atom at pH 2-3. The attachment of the second proton occurs through the piperidine nitrogen atom at pH {approx} 1.

Kovalchukova, O. V., E-mail: okovalchukova@mail.ru [Peoples' Friendship University of Russia (Russian Federation); Stash, A. I.; Belsky, V. K. [Karpov Institute of Physical Chemistry (Russian Federation); Strashnova, S. B.; Zaitsev, B. E.; Ryabov, M. A. [Peoples' Friendship University of Russia (Russian Federation)

2009-01-15T23:59:59.000Z

205

Nanopattering in CeOx/Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity  

SciTech Connect (OSTI)

Our results indicate that small amounts of an oxide deposited on a stable metal surface can trigger a massive surface reconstruction under reaction conditions. In low-energy electron microscopy (LEEM) experiments, no reconstruction of Cu(111) is observed after chemisorbing oxygen or after reducing O/Cu(111) in a CO atmosphere. On the other hand, LEEM images taken in situ during the reduction of CeO{sub 2}/CuO{sub 1-x}/Cu(111) show a complex nonuniform transformation of the surface morphology. Ceria particles act as nucleation sites for the growth of copper microterraces once CuO{sub 1-x} is reduced. Can this reconstructed surface be used to enhance the catalytic activity of inverse oxide/metal catalysts? Indeed, CeO{sub x} on reconstructed Cu(111) is an extremely active catalyst for the water-gas shift process (CO + H{sub 2}O {yields} H{sub 2} + CO{sub 2}), with the Cu microterraces providing very efficient sites for the dissociation of water and subsequent reaction with CO.

Rodriguez J. A.; Senanayake, S.D.; Sadowski, J.; Evans, J.; Kundu, S.; Agnoli, S.; Yang, F.; Stacchiola, D.; Flege, J.I.; Hrbek, J.

2012-04-05T23:59:59.000Z

206

CE IGCC repowering project: Clean Coal II Project. Annual report, 1 January, 1992--31 December, 1992  

SciTech Connect (OSTI)

CE is participating in a $270 million coal gasification combined cycle repowering project that will provide a nominal 60 MW of electricity to City, Water, light and Power (CWL and P) in Springfield, Illinois. The IGCC system will consist of CE`s air-blown entrained flow two-stage gasifier; an advanced hot gas cleanup system; a combustion turbine adapted to use low-Btu gas: and all necessary coal handling equipment. The project is currently in the second budget period of five. The major activities during this budgeted period are: Establishment of an approved for design (AFD) engineering package; development of a detailed cost estimate; resolution of project business issues; CWL and P renewal and replacement activities; and application for environmental air permits. The Project Management Plan was updated. The conceptual design of the plant was completed and a cost and schedule baseline for the project was established previously in Budget Period One. This information was used to establish AFD Process Flow Diagrams, Piping and Instrument Diagrams, Equipment Data Sheets, material take offs, site modification plans and other information necessary to develop a plus or minus 20% cost estimate. Environmental permitting activities are continuing. At the end of 1992 the major activities remaining for Budget Period two is to finish the cost estimate and complete the Continuation Request Documents.

Not Available

1993-12-01T23:59:59.000Z

207

Rapid Microwave Preparation of Highly Efficient Ce[superscript 3+]-Substituted Garnet Phosphors for Solid State White Lighting  

SciTech Connect (OSTI)

Ce{sup 3+}-substituted aluminum garnet compounds of yttrium (Y{sub 3}Al{sub 5}O{sub 12}) and lutetium (Lu{sub 3}Al{sub 5}O{sub 12}) - both important compounds in the generation of (In,Ga)N-based solid state white lighting - have been prepared using a simple microwave heating technique involving the use of a microwave susceptor to provide the initial heat source. Carbon used as the susceptor additionally creates a reducing atmosphere around the sample that helps stabilize the desired luminescent compound. High quality, phase-pure materials are prepared within a fraction of the time and using a fraction of the energy required in a conventional ceramic preparation; the microwave technique allows for a reduction of about 95% in preparation time, making it possible to obtain phase pure, Ce{sup 3+}-substituted garnet compounds in under 20 min of reaction time. It is estimated that the overall reduction in energy compared with ceramic routes as practiced in the lab is close to 99%. Conventionally prepared material is compared with material prepared using microwave heating in terms of structure, morphology, and optical properties, including quantum yield and thermal quenching of luminescence. Finally, the microwave-prepared compounds have been incorporated into light-emitting diode 'caps' to test their performance characteristics in a real device, in terms of their photon efficiency and color coordinates.

Birkel, Alexander; Denault, Kristin A.; George, Nathan C.; Doll, Courtney E.; Héry, Bathylle; Mikhailovsky, Alexander A.; Birkel, Christina S.; Hong, Byung-Chul; Seshadri, Ram (UCSB); (Mitsubishi)

2012-04-30T23:59:59.000Z

208

Preparation and luminescence characterization of GGAG:Ce{sup 3+},B{sup 3+} for a white light-emitting diode  

SciTech Connect (OSTI)

We prepared Gd{sub 3}Ga{sub 2}Al{sub 3}O{sub 12} (GGAG) co-doped with trivalent cerium and boron ions and investigated its luminescence properties as a function of the B{sup 3+} concentration. The luminescence intensity was enhanced markedly by adding B{sup 3+} as a co-dopant. The non-boron-doped GGAG:Ce{sup 3+} converted less than 10% of the absorbed blue light into luminescence. As the B{sup 3+} concentration increased, Q increased and reached a maximum of Q = 21% at 1.5 moles in GGAG:Ce{sup 3+}. White light closer to daylight with good color-rendering index properties was generated with the proper combination of yellow emission from GGAG:Ce{sup 3+},B{sup 3+} and blue emission from a GaN chip.

Kang, Jun-Gill [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)], E-mail: jgkang@cnu.ac.kr; Kim, Myung-Kyo [Alti-Electronics Co., Ltd., 90-1 Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-882 (Korea, Republic of); Kim, Kwang-Bok [Kumho Electric, Inc., 64-1, Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-883 (Korea, Republic of)

2008-08-04T23:59:59.000Z

209

Oxide-ion conductivity in Cu {sub x}Ce{sub 1-x}O{sub 2-{delta}} (0 {<=} x {<=} 0.10)  

SciTech Connect (OSTI)

Up to 10 at.% of copper readily substitutes for cerium in ceria. It is found that at oxygen partial pressures between 0.21 atm and 10{sup -5} atm, Cu {sub x}Ce{sub 1-x}O{sub 2-{delta}} (0 {<=} x {<=} 0.10) solid solution behave as an oxide-ion electrolyte. Interestingly, Cu{sub 0.10}Ce{sub 0.90}O{sub 2-{delta}} exhibits the oxide-ion conductivity of ca. 10{sup -4} {omega}{sup -1} cm{sup -1} at 600 deg. C at an oxygen partial pressure of 10{sup -5} atm.

Gayen, Arup [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India); Priolkar, K.R. [Department of Physics, Goa University, Taleigao Plateau, Goa 403206 (India); Shukla, A.K. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India); Ravishankar, N. [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India); Hegde, M.S. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India)]. E-mail: mshegde@sscu.iisc.ernet.in

2005-03-08T23:59:59.000Z

210

Lu.sub.1-xI.sub.3:Ce.sub.x-a scintillator for gamma-ray spectroscopy and time-of-flight pet  

DOE Patents [OSTI]

The present invention includes very fast scintillator materials including lutetium iodide doped with Cerium (Lu.sub.1-xI.sub.3:Ce.sub.x; LuI.sub.3:Ce). The LuI.sub.3 scintillator material has surprisingly good characteristics including high light output, high gamma-ray stopping efficiency, fast response, low cost, good proportionality, and minimal afterglow that the material is useful for gamma-ray spectroscopy, medical imaging, nuclear and high energy physics research, diffraction, non-destructive testing, nuclear treaty verification and safeguards, and geological exploration.

Shah, Kanai S. (Newton, MA)

2008-02-12T23:59:59.000Z

211

Computing in SCienCe & engineering This arTicle has been peer-reviewed. 13 R e p r o d u c i b l e R e s e a r c h  

E-Print Network [OSTI]

Computing in SCienCe & engineering This arTicle has been peer-reviewed. 13 R e p r o d u c i b l e as well as some efforts and approaches to overcome them. #12;14 Computing in SCienCe & engineering in 2011; a panel discussion at the International Biometric Society meeting in 2011 featured re- producibility

LeVeque, Randy

212

Hydrogen activation, diffusion, and clustering on CeO{sub 2}(111): A DFT+U study  

SciTech Connect (OSTI)

We present a comprehensive density functional theory+U study of the mechanisms underlying the dissociation of molecular hydrogen, and diffusion and clustering of the resulting atomic species on the CeO{sub 2}(111) surface. Contrary to a widely held view based solely on a previous theoretical prediction, our results show conclusively that H{sub 2} dissociation is an activated process with a large energy barrier ?1.0 eV that is not significantly affected by coverage or the presence of surface oxygen vacancies. The reaction proceeds through a local energy minimum – where the molecule is located close to one of the surface oxygen atoms and the H–H bond has been substantially weaken by the interaction with the substrate –, and a transition state where one H atom is attached to a surface O atom and the other H atom sits on-top of a Ce{sup 4+} ion. In addition, we have explored how several factors, including H coverage, the location of Ce{sup 3+} ions as well as the U value, may affect the chemisorption energy and the relative stability of isolated OH groups versus pair and trimer structures. The trimer stability at low H coverages and the larger upward relaxation of the surface O atoms within the OH groups are consistent with the assignment of the frequent experimental observation by non-contact atomic force and scanning tunneling microscopies of bright protrusions on three neighboring surface O atoms to a triple OH group. The diffusion path of isolated H atoms on the surface goes through the adsorption on-top of an oxygen in the third atomic layer with a large energy barrier of ?1.8 eV. Overall, the large energy barriers for both, molecular dissociation and atomic diffusion, are consistent with the high activity and selectivity found recently in the partial hydrogenation of acetylene catalyzed by ceria at high H{sub 2}/C{sub 2}H{sub 2} ratios.

Fernández-Torre, Delia [Departamento de Física Teórica de la Materia Condensada, Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Instituto de Estructura de la Materia, CSIC, C/ Serrano 121, E-28006 Madrid (Spain); Carrasco, Javier [CIC Energigune, Albert Einstein 48, 01510 Miñano, Álava (Spain); Instituto de Catálisis y Petroleoquímica, CSIC, C/ Marie Curie 2, E-28049 Madrid (Spain); Ganduglia-Pirovano, M. Verónica [Instituto de Catálisis y Petroleoquímica, CSIC, C/ Marie Curie 2, E-28049 Madrid (Spain); Pérez, Rubén, E-mail: ruben.perez@uam.es [Departamento de Física Teórica de la Materia Condensada, Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain)

2014-07-07T23:59:59.000Z

213

Electronic and thermoelectric properties of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} computed with density functional theory with on-site Coulomb interaction correction  

SciTech Connect (OSTI)

The electronic properties and Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are computed using Density Functional Theory with on-site Coulomb interaction correction. We found that the Seebeck coefficients of Ce{sub 3}Te{sub 4} and La{sub 3}Te{sub 4} are almost equal at temperatures larger than the Curie temperature of Ce{sub 3}Te{sub 4}, and in good agreement with the measurements reported by May et al. [Phys. Rev. B 86, 035135 (2012)]. At temperatures below the Curie temperature, the Seebeck coefficient of Ce{sub 3}Te{sub 4} increases due to the ferromagnetic ordering, which leads the f-electron of Ce to contribute to the Seebeck coefficient in the relevant range of electron concentration.

Vo, Trinh; Allmen, Paul von; Huang, Chen-Kuo; Ma, James; Bux, Sabah; Fleurial, Jean-Pierre [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109 (United States)

2014-10-07T23:59:59.000Z

214

Adsorbate effects on a mixed-valence compound: Carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

We have studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. We show that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4sigma, 1..pi.., and 5sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.; Lawrence, J.

1987-10-15T23:59:59.000Z

215

Adsorbate effects on a mixed-valence compound: carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

The authors studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. It is shown that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4 sigma, 1 pi, and 5 sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.

1987-10-15T23:59:59.000Z

216

Effect of CeO{sub 2} buffer layer on the microstructure and magnetic properties of yttrium iron garnet film on Si substrate  

SciTech Connect (OSTI)

Yttrium iron garnet films were grown by radio frequency magnetron sputtering on Si(111) substrate with and without CeO{sub 2} buffer layer, and influence of CeO{sub 2} buffer on the microstructure and magnetic behaviors of the films were investigated. As compared with the film without buffer, a larger saturation magnetizaton (M{sub s}), lower coercive force (H{sub c}), and higher remnant magnetization (M{sub r}) were obtained due to the introduction of CeO{sub 2} layer. The higher M{sub s} results from the denser structure and the smaller content of Fe{sup 2+} ions. The lower H{sub c} and higher M{sub r} can be explained by the small surface roughness and crystal grains size. The film on CeO{sub 2} buffer layer possess fine microstructure and its surface roughness is smaller than the unbuffered films, which provides an increased exchange between the crystal grains and an enhanced spontaneous magnetization effect, leading to the higher remnant magnetization.

Yang Qinghui; Zhang Huaiwu; Wen Qiye; Liu Yingli [State Key Laboratory of Electronic Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, 610054 (China); Xiao, John Q. [Department of Physics and Astronomy, University of Delaware, Newark, Delaware, 19716 (United States)

2009-04-01T23:59:59.000Z

217

UV absorption properties of ceria-modified compositions within the fluorite-type solid solution CeO{sub 2}-Y{sub 6}WO{sub 12}  

SciTech Connect (OSTI)

A new fluorite-type solid solution domain has been evidenced in the system (1-x) CeO{sub 2}-x/7 Y{sub 6}WO{sub 12}{open_square}{sub 2} using the amorphous citrate route. All the studied phases (0{<=}x{<=}1) crystallize in a cubic-type symmetry. Diffuse reflectance spectra reveal a strong optical absorption between 380 and 400 nm. All substituted compositions spectral selectivities are estimated suitable for application as inorganic UV absorbers. The non linear variation observed in the optical gap values between Y{sub 6}WO{sub 12} and CeO{sub 2} is attributed to the presence of the cerium 4f-block band. Additionally, Time Resolved Microwave Conductivity (TRMC) experiment and phenol photodegradation analyses carried out on the Ce{sub 0.81}Y{sub 0.16}W{sub 0.03}O{sub 1.95}{open_square}{sub 0.05} (x=0.19) composition do not indicate any photocalatytic activity for this material. - Graphical abstract: Diffuse reflectance spectra of the Ce-Y-W-O samples calcined at 1000 deg. C.

Chevire, Francois [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Munoz, Francisco [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Baker, Charles F. [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Tessier, Franck [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France)]. E-mail: Franck.Tessier@univ-rennes1.fr; Larcher, Olivier [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Boujday, Souhir [Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, CNRS UPR 1311, Universite Paris 13, 99 Avenue J. B. Clement, 93430 Villetaneuse (France); Colbeau-Justin, Christophe [Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, CNRS UPR 1311, Universite Paris 13, 99 Avenue J. B. Clement, 93430 Villetaneuse (France); Marchand, Roger [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France)

2006-10-15T23:59:59.000Z

218

TP HTML -CSS -PHP -POSTGRESQL Le but de ce TP est de complter les fichiers fournis pour raliser une micro application interactive qui  

E-Print Network [OSTI]

TP HTML - CSS - PHP - POSTGRESQL Le but de ce TP est de compléter les fichiers fournis pour afficher (fichiers .html ou .php). · Enregistrez dans votre home l'archive contenant les fichiers du TP à partir de http://perso.limsi.fr/annlor/enseignement/ensiie/pw/tpPHP.tar · Extrayez de l'archive le

Ligozat, Anne-Laure

219

The Institute for Integrated Cell-Material Sciences (iCeMS) was founded in 2007 as part of a government program called the World Premier International  

E-Print Network [OSTI]

, Sports, Science and Technology (MEXT) of Japan. The fund provides a total of 6 million dollars per year science. iCeMS is one of nine WPI centers throughout Japan and boasts eighteen world-renowned principal investigators, who are leading experts in cell biology, chemistry, and physics. Notably, Kyoto University Center

Takada, Shoji

220

Electronic Structure of CeFeAsO1-xFx (x=0, 0.11/x=0.12) compounds  

SciTech Connect (OSTI)

We report an extensive study on the intrinsic bulk electronic structure of the high-temperature superconductor CeFeAsO{sub 0.89}F{sub 0.11} and its parent compound CeFeAsO by soft and hard x-ray photoemission, x-ray absorption and soft-x-ray emission spectroscopies. The complementary surface/bulk probing depth, and the elemental and chemical sensitivity of these techniques allows resolving the intrinsic electronic structure of each element and correlating it with the local structure, which has been probed by extended-x-ray absorption fine structure spectroscopy. The measurements indicate a predominant 4f{sup 1} (i.e. Ce{sup 3+}) initial state configuration for Cerium and an effective valence-band-to-4f charge-transfer screening of the core hole. The spectra also reveal the presence of a small Ce f{sup 0} initial state configuration, which we assign to the occurrence of an intermediate valence state. The data reveal a reasonably good agreement with the partial density of states as obtained in standard density functional calculations over a large energy range. Implications for the electronic structure of these materials are discussed.

Bondino, F.; Magnano, E.; Booth, C. H.; Offi, F.; Panaccione, G.; Malvestuto, M.; Paolicelli, G.; Simonelli, L.; Parmigiani, F.; McGuire, M. A.; Sefat, A. S.; Sales, B. C.; Jin, R.; Vilmercati, P.; Mandrus, D.; Singh, D. J.; Mannella, N.

2011-01-25T23:59:59.000Z

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Un atlas smantique pour le cerveau Un des buts principaux de ce projet est le dveloppement d'un outil qui permettra  

E-Print Network [OSTI]

Un atlas sémantique pour le cerveau Un des buts principaux de ce projet est le développement d construire des représentations sémantiques à partir de large corpus de textes (les Atlas sémantiques (AS

Institut des Sciences Cognitives, CNRS

222

VI INTERNATIONAL TELECOMMUNICATIONS SYMPOSIUM (ITS2006), SEPTEMBER 3-6, 2006, FORTALEZA-CE, BRAZIL 1 Fringe Benefits of the H.264/AVC  

E-Print Network [OSTI]

of the Motion Picture Experts Groups (MPEG) from the International Standards Organization (ISO) and of the VideoVI INTERNATIONAL TELECOMMUNICATIONS SYMPOSIUM (ITS2006), SEPTEMBER 3-6, 2006, FORTALEZA-CE, BRAZIL, and Tiago A. Fonseca Abstract-- H.264/AVC is the newest, state-of-the-art, video compression standard

de Queiroz, Ricardo L.

223

Effect of CeO{sub 2} addition on the properties of FeAl based alloy produced by mechanical alloying technique  

SciTech Connect (OSTI)

Iron aluminides based on FeAl is notable for their low materials cost, ease of fabrication and good corrosion, suffixation and oxidation resistance. However, the application based on these unique properties still require the development of Fe-Al based alloy since it shows some drawbacks such as a lack of high temperature strength and low ductility. To improve the mechanical properties of FeAl based alloy, ceria (CeO{sub 2}) will be added to this compound. FeAl based alloy produced by the mechanical alloying (MA) technique. The developed specimens then assessed with respect to oxidation behaviour in high temperature, scale microstructure and hardness. The surface morphologies of the alloy evaluated and observed using scanning electron microscopy (SEM) with an energy dispersive X-ray spectroscopy (EDX). The phase structures of oxide scale formed on them were identified by X-ray diffraction (XRD). The results found that the FeAl intermetallic compound containing CeO{sub 2} 0.5 wt.% is less pores and CeO{sub 2} 1.0 wt.% is more homogen in powder and solid form, higher hardness and increase in their resistance to oxidation behaviour in high temperature compared with another percentage of CeO{sub 2}.

Khaerudini, Deni S.; Muljadi,; Sardjono, P.; Tetuko, Anggito P.; Sebayang, P.; Ginting, M. [Research Center for Physics, Indonesian Institute of Sciences (LIPI) Gd. 440, Kawasan Puspiptek Serpong Tangerang 15314 Banten (Indonesia)] [Research Center for Physics, Indonesian Institute of Sciences (LIPI) Gd. 440, Kawasan Puspiptek Serpong Tangerang 15314 Banten (Indonesia)

2013-09-03T23:59:59.000Z

224

IFT1227, Architecture des ordinateurs 1: Ce devoir vous permet de manipuler les robots equipes de la -chip PIC18F4550 presentes en demo.  

E-Print Network [OSTI]

IFT1227, Architecture des ordinateurs 1: Devoir 3 Ce devoir vous permet de manipuler les robots robot soit attir´e ou suive une lumi`ere relativement forte (une lampe de poche ou autre mise devant lui). 1 Comportement basique Votre programme devra fournir le comportement suivant : ­ Quand le robot

Boyer, Michel

225

plan de polarisation de 18', en sens contraire du courant qui anime l'lecuro-aimant. On peut comparer ce rsultat avec l'effet produit  

E-Print Network [OSTI]

celle que produit directement l'acier, ce qui donne pour l'effet de la lame 50' au lieu de 48', nombre un champ magnétique et du phénomène de Peltier. L'expérience de M. Hall est répétée au moyen d

Paris-Sud XI, Université de

226

CE IGCC Repowering Project: Use of the Lockheed Kinetic Extruder for coal feeding; Topical report, June 1993  

SciTech Connect (OSTI)

ABB CE is evaluating alternate methods of coal feed across a pressure barrier for its pressurized coal gasification process. The Lockheed Kinetic Extruder has shown to be one of the most promising such developments. In essence, the Kinetic Extruder consists of a rotor in a pressure vessel. Coal enters the rotor and is forced outward to the surrounding pressure vessel by centrifugal force. The force on the coal passing across the rotor serves as a pressure barrier. Should this technology be successfully developed and tested, it could reduce the cost of IGCC technology by replacing the large lockhoppers conventionally used with a much smaller system. This will significantly decrease the size of the gasifier island. Kinetic Extruder technology needs testing over an extended period of time to develop and prove the long term reliability and performance needed in a commercial application. Major issues to be investigated in this program are component design for high temperatures, turn-down, scale-up factors, and cost. Such a test would only be economically feasible if it could be conducted on an existing plant. This would defray the cost of power and feedstock. Such an installation was planned for the CE IGCC Repowering Project in Springfield, Illinois. Due to budgetary constraints, however, this provision was dropped from the present plant design. It is believed that, with minor design changes, a small scale test version of the Kinetic Extruder could be installed parallel to an existing lockhopper system without prior space allocation. Kinetic Extruder technology represents significant potential cost savings to the IGCC process. For this reason, a test program similar to that specified for the Springfield project would be a worthwhile endeavor.

NONE

1994-02-01T23:59:59.000Z

227

Lakes in General Circulation Models Primary Investigator: Brent Lofgren -NOAA GLERL  

E-Print Network [OSTI]

-Investigators: Chris Milly, Isaac Held, Bruce Wyman - NOAA Geophysical Fluid Dynamics Laboratory Overview The use

228

Gold, Copper, and Platinum Nanoparticles Dispersed on CeOx/TiO2(110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level  

SciTech Connect (OSTI)

At small coverages of ceria on TiO{sub 2}(110), the CeO{sub x} nanoparticles have an unusual coordination mode. Scanning tunneling microscopy and density-functional calculations point to the presence of Ce{sub 2}O{sub 3} dimers, which form diagonal arrays that have specific orientations of 0, 24, and 42{sup o} with respect to the [1 -1 0] direction of the titania substrate. At high coverages of ceria on TiO{sub 2}(110), the surface exhibits two types of terraces. In one type, the morphology is not very different from that observed at low ceria coverage. However, in the second type of terrace, there is a compact array of ceria particles with structures that do not match the structures of CeO{sub 2}(111) or CeO{sub 2}(110). The titania substrate imposes on the ceria nanoparticles nontypical coordination modes, enhancing their chemical reactivity. This phenomenon leads to a larger dispersion of supported metal nanoparticles (M = Au, Cu, Pt) and makes possible the direct participation of the oxide in catalytic reactions. The M/CeO{sub x}/TiO{sub 2}(110) surfaces display an extremely high catalytic activity for the water-gas shift reaction that follows the sequence Au/CeO{sub x}/TiO{sub 2}(110) < Cu/CeO{sub x}/TiO{sub 2}(110) < Pt/CeO{sub x}/TiO{sub 2}(110). For low coverages of Cu and CeO{sub x}, Cu/CeO{sub x}/TiO{sub 2}(110) is 8-12 times more active than Cu(111) or Cu/ZnO industrial catalysts. In the M/CeO{sub x}/TiO{sub 2}(110) systems, there is a strong coupling of the chemical properties of the admetal and the mixed-metal oxide: The adsorption and dissociation of water probably take place on the oxide, CO adsorbs on the admetal nanoparticles, and all subsequent reaction steps occur at the oxide-admetal interface. The high catalytic activity of the M/CeO{sub x}/TiO{sub 2}(110) surfaces reflects the unique properties of the mixed-metal oxide at the nanometer level.

Park, J.; Graciani, J; Evans, J; Stacchiola, D; Senanayake, S; Barrio, L; Liu, P; Fdez. Sanz, J; Hrbek, J; Rodriguez, J

2010-01-01T23:59:59.000Z

229

Gold, Copper and Platinum Nanoparticles Dispersed on CeOx/TiO2(110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level  

SciTech Connect (OSTI)

At small coverages of ceria on TiO{sub 2}(110), the CeO{sub x} nanoparticles have an unusual coordination mode. Scanning tunneling microscopy and density-functional calculations point to the presence of Ce{sub 2}O{sub 3} dimers, which form diagonal arrays that have specific orientations of 0, 24, and 42{sup o} with respect to the [1 -1 0] direction of the titania substrate. At high coverages of ceria on TiO{sub 2}(110), the surface exhibits two types of terraces. In one type, the morphology is not very different from that observed at low ceria coverage. However, in the second type of terrace, there is a compact array of ceria particles with structures that do not match the structures of CeO{sub 2}(111) or CeO{sub 2}(110). The titania substrate imposes on the ceria nanoparticles nontypical coordination modes, enhancing their chemical reactivity. This phenomenon leads to a larger dispersion of supported metal nanoparticles (M = Au, Cu, Pt) and makes possible the direct participation of the oxide in catalytic reactions. The M/CeO{sub x}/TiO{sub 2}(110) surfaces display an extremely high catalytic activity for the water-gas shift reaction that follows the sequence Au/CeO{sub x}/TiO{sub 2}(110) < Cu/CeO{sub x}/TiO{sub 2}(110) < Pt/CeO{sub x}/TiO{sub 2}(110). For low coverages of Cu and CeO{sub x}, Cu/CeO{sub x}/TiO{sub 2}(110) is 8-12 times more active than Cu(111) or Cu/ZnO industrial catalysts. In the M/CeO{sub x}/TiO{sub 2}(110) systems, there is a strong coupling of the chemical properties of the admetal and the mixed-metal oxide: The adsorption and dissociation of water probably take place on the oxide, CO adsorbs on the admetal nanoparticles, and all subsequent reaction steps occur at the oxide-admetal interface. The high catalytic activity of the M/CeO{sub x}/TiO{sub 2}(110) surfaces reflects the unique properties of the mixed-metal oxide at the nanometer level.

Rodriguez, J.A.; Park, J.B.; Graciani, J.; Evans, J.; Stacchiola, D.; Senanayake, S.D.; Barrio, L.; Liu, P.; Sanz, J.F.; Hrbek, J.

2010-01-13T23:59:59.000Z

230

Substitution effect on the magnetic and transport properties of CeNi{sub 0.8?x}Mn{sub x}Bi{sub 2}  

SciTech Connect (OSTI)

We report the results of Mn substitution for Ni in CeNi{sub 0.8}Bi{sub 2} (i.e., CeNi{sub 0.8?x}Mn{sub x}Bi{sub 2}). All the samples have an antiferromagnetic ordered state below T{sub N}?=?5.0?K due to localized 4f-magnetic moment on the Ce ions. Besides this antiferromagnetic ordering caused by Ce, the magnetic and transport properties are abruptly changed with increasing Mn contents at the boundary composition of x?=?0.4. The magnetic state is changed into a ferromagnetic state around 200?K for x?>?0.4, where the electrical resistivity is strongly suppressed to become simple metallic. These results of ferromagnetism and metallicity can be explained by the double exchange mechanism, rather than the simple picture of Doniach phase diagram. The mixed valence states of Ni and Mn ions are confirmed by X-ray photoelectron spectroscopy. For x???0.4, the initial Ni{sup 3+} state gradually changes to the Ni{sup 2+} state with increasing x up to 0.4. On further increase of x?>?0.4, the Ni{sup 2+} state is replaced by the Mn{sup 2+} state, which gradually changes to the final Mn{sup 3+} state. We also present an inelastic neutron scattering (INS) measurements on CeNi{sub 0.8}Bi{sub 2} (i.e., x?=?0) between 1.2 and 12?K. The high energy INS study reveals the presence of two well-defined crystal electric field (CEF) excitations near 9?meV and 19?meV at 1.2?K and 6?K, while the low energy INS study reveals the presence of quasielastic scattering above 4?K. We will discuss our INS results of CeNi{sub 0.8}Bi{sub 2} based on the CEF model.

Kim, Soo-Whan; Lee, Kyujoon; Jung, Myung-Hwa, E-mail: mhjung@sognag.ac.kr [Department of Physics, Sogang University, Seoul 121-742 (Korea, Republic of); Adroja, D. T. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX (United Kingdom); Highly Correlated Matter Research Group, Physics Department, University of Johannesburg, P.O. Box 524, Auckland Park 2006 (South Africa); Demmel, F.; Taylor, J. W. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX (United Kingdom)

2014-08-21T23:59:59.000Z

231

Role of dopant incorporation on the magnetic properties of Ce1-xNixO2 nanoparticles: An electron paramagnetic resonance study  

SciTech Connect (OSTI)

Nickel doping has been found to produce weak room-temperature ferromagnetism in CeO2 [1]. The saturation magnetization of the chemically synthesized Ce1-xNixO2 samples showed a maximum for x = 0.04, above which the magnetization decreased gradually. For Ce1-xNixO2 samples with x ? 0.04, an activation process involving slow annealing of the sample to 500 oC increased the saturation magnetization by more than two orders of magnitude [1]. However, no such activation effect was observed in samples with x < 0.04. Electron paramagnetic resonance (EPR), a sensitive technique to investigate the ionic states and local environments and interactions, has been used here in this work to investigate (i) why the ferromagnetic behavior gradually weakened and disappeared for x > 0.04 and (ii)_what causes the saturation magnetization to dramatically increase in the activated Ce1-xNixO2 samples with x ? 0.04 and why this process is absent in samples with x < 0.04. Our X-band (~9.4 GHz) EPR experiments and detailed simulation analysis on several as-prepared Ce1-xNixO2 samples with 0.01 ? x ? 0.10 at 5 K and 300 K indicate the presence of two magnetically inequivalent Ni2+ ions with the ionic spin of 1, one Ce3+ ion with spin ½, and three O2-. Spectra of samples with x < 0.04 are dominated by a single Ni2+ EPR line ascribed to dopant ions in substitutional sites whereas in samples with x ? 0.04, an additional signal attributed to Ni2+ ions in interstitial sites is also present. In the activated sample, the EPR line due to the interstitial Ni2+ is completely absent and only the lines due to substituional Ni2+ ions are present suggesting that the enhanced ferromagnetism results from conversion of interstitial Ni2+ ions to substitutional sites.

Misra, S. K.; Andronenko, S. I.; Engelhard, Mark H.; Thurber, Aaron P.; Reddy, K. M.; Punnoose, Alex

2008-04-01T23:59:59.000Z

232

Powder preparation and UV absorption properties of selected compositions in the CeO{sub 2}-Y{sub 2}O{sub 3} system  

SciTech Connect (OSTI)

Several approaches have been investigated to prepare fluorite-type compositions within the (1-x) CeO{sub 2}-xYO{sub 1.5} system. The optical properties of the resulting modified-ceria materials have been characterized in order to evaluate their potential abilities as inorganic UV absorbers. Diffuse reflectance analyses reveal a strong optical absorption between 390 and 400 nm for all substituted compositions and the spectral selectivities are estimated suitable for the targeted application. Additionally, time resolved microwave conductivity (TRMC) and phenol photodegradation analyses do not indicate any photocalatytic activity for these compositions. Aqueous colloidal suspensions of the Ce{sub 0.7}Y{sub 0.3}O{sub 1.85} UV absorber have been carried out. - Graphical abstract: Comparison between diffuse reflectance spectra of ceria (x=0) and yttrium modified ceria (x=0.3)

Tessier, Franck [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France)], E-mail: Franck.Tessier@univ-rennes1.fr; Chevire, Francois; Munoz, Francisco; Merdrignac-Conanec, Odile; Marchand, Roger [UMR CNRS 6226 'Sciences Chimiques de Rennes', equipe 'Verres et Ceramiques', Universite de Rennes 1, 35042 Rennes cedex (France); Bouchard, Michel; Colbeau-Justin, Christophe [Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, CNRS UPR 1311, Universite Paris 13, 99 Avenue J.B. Clement, 93430 Villetaneuse (France)

2008-05-15T23:59:59.000Z

233

Lu1-xI3:Cex--a scintillator for gamma ray spectroscopy and time-of-flight PET  

DOE Patents [OSTI]

The present invention concerns very fast scintillator materials comprising lutetium iodide doped with Cerium (Lu1-xI3:Cex; LuI3:Ce). The LuI3 scintillator material has surprisingly good characteristics including high light output, high gamma ray stopping efficiency, fast response, low cost, good proportionality, and minimal afterglow that the material is useful for gamma ray spectroscopy, medical imaging, nuclear and high energy physics research, diffraction, non-destructive testing, nuclear treaty verification and safeguards, and geological exploration. The timing resolution of the scintillators of the present invention provide compositions capable of resolving the position of an annihilation event within a portion of a human body cross-section.

Shah, Kanai S.

2007-02-06T23:59:59.000Z

234

Fabrication of CeO2 by sol-gel process based on microfluidic technology as an analog preparation of ceramic nuclear fuel microspheres  

E-Print Network [OSTI]

Microfluidics integrated with sol-gel processes is introduced in preparing monodispersed MOX nuclear fuel microspheres using nonactive cerium as a surrogate for uranium or plutonium. The detailed information about microfluidic devices and sol-gel processes are provided. The effects of viscosity and flow rate of continuous and dispersed phase on size and size distribution of CeO2 microspheres have been investigated. A comprehensive characterization of the CeO2 microspheres has been conducted, including XRD pattern, SEM, density, size and size distribution. The size of prepared monodisperse particles can be controlled precisely in range of 10{\\mu}m to 1000{\\mu}m and the particle CV is below 3%.

Bin Ye; Jilang Miao; Jiaolong Li; Zichen Zhao; Zhenqi Chang; Christophe A. Serra

2012-12-15T23:59:59.000Z

235

CO chemisorption effect on cerium initial and final states in the core level photoelectron spectrum of CeIr  

SciTech Connect (OSTI)

Carbon monoxide (CO) adsorption on the mixed-valence compound CeIr/sub 2/ has been studied by X-ray photoelectron spectroscopy. CO adsorption on this surface is predominantly molecular. They show that changes in the cerium 3d spectrum upon CO chemisorption may be separated into initial- and final-state effects. In the initial state, stabilization of the (Xe)(5d6s)/sup 3/4f/sup 1/ configuration occurs due to an increase in effective nuclear charge on the cerium atom. This leads to a decrease in f/sup 0/ intensity in the recorded spectrum. Increased f-electron repulsion in the final state raises the energy of the f/sup 2/ final-state configuration and causes a 2.2-eV shift to higher binding energy of the 3d/sub 5/2/f/sup 2/ peak. The 0.5-eV binding energy shifts of the 3d/sub 5/2/f/sup 1/ and 3d/sub 3/2/f/sup 1/ peaks along with the 2.2-eV shift of the 3d/sub 5/2/f/sup 2/ peak indicate that the f orbitals are quite sensitive indicators of the surface oxidation state in this compound.

Lindquist, J.M.; Hemminger, J.C.

1987-10-22T23:59:59.000Z

236

Contact Undergraduate Admissions Office | Tel +44 (0)117 928 8154 Email socsci-ug-admissions@bristol.ac.uk 54 ACCOUnTing And FinAnCE  

E-Print Network [OSTI]

-ug-admissions@bristol.ac.uk 54 ACCOUnTing And FinAnCE FACULTY oF soCiAL sCienCes And LAw bristol.ac.uk Accounting and Finance As one of the UK's leading departments for Accounting and Finance, we offer you the opportunity to study and their application skills. bristol.ac.uk/accounting Why study Accounting and Finance at Bristol? Bristol has

Subramanian, Sriram

237

In : John Tolan (d.), L'change, Paris, L'harmattan, 2009, pp. 201-214 Qu'est-ce qu'un change marchand ? Proposition de trois  

E-Print Network [OSTI]

marchand ? Proposition de trois définitions cumulatives pour l'analyse Ronan Le Velly Qu'est-ce qu'un échange marchand ? Cette question en apparence anodine a suggéré des réponses très différentes en sciences participent ou se tiennent à l'écart du système marchand (partie 3). 1. Le marché comme catégorie de

Paris-Sud XI, Université de

238

TUDE DES ISOTONES N = 81 : 139Ce, 141Nd, 143Sm, AU MOYEN DES RACTIONS (d, t ) ET (3He, 03B1)  

E-Print Network [OSTI]

'energie et la fragmentation de ces 6tats en fonction du nombre de protons. Le pick-up d'un neutron sur les'à plus de 3 MeV d'énergie d'excitation, essentiellement au moyen d'un spectromètre magnétique splitpole MeV excitation energy, of the N = 81 isotones : 139Ce, 141Nd, 143 Sm, have been studied at the Orsay

Boyer, Edmond

239

High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions  

SciTech Connect (OSTI)

The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

2011-12-31T23:59:59.000Z

240

Study of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel cell2  

E-Print Network [OSTI]

to oxygen dissociation and diffusion process.26 KEYWORDS: Solid oxide fuel cell; Silver infiltration-time of the cell/stack/module as well as to reduce the cost of the materials. So32 far, many studies have beenStudy of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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241

Electronic structure analysis and properties of Sr{sub 2}CeO{sub 4} grown by sol–gel method  

SciTech Connect (OSTI)

Highlights: ? Sr{sub 2}CeO{sub 4} nanopowders were obtained by sol–gel method. ? SEM/EDX imaging and chemical analysis have been done. ? XPS electronic structure was examined and discussed. ? The terminal and equatorial Ce-O bonds contributions were determined in O2p states. ? The energy gap was estimated by valence band and electrical measurements. -- Abstract: Sr{sub 2}CeO{sub 4} is a very promising material due to its various industrial applications, e.g. for the construction of field emission displays and light emitting diodes. In this work, the phosphor was synthesized by the sol–gel method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), electron paramagnetic resonance (EPR) and X-ray photoelectron spectroscopy (XPS) methods. They proved to be very good structural properties of the material and identified negligible impurities from the technological process. The decomposition of the surface of the nanocrystals was found but this did not decrease the spectral features of the compound. The analysis of the XPS O2p lines revealed contributions of two kinds of bonds: terminal and equatorial ones, in the ratio of 2/4. They are separated by 1.2 eV what is in agreement with the observed absorption spectra. A presence of the decomposed layers may produce asymmetric widening of the emission spectra towards a lower energy.

Talik, E., E-mail: talik@us.edu.pl [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland); Lipi?ska, L. [Institute of Electronic Materials Technology, ul. Wólczy?ska 133, 01-919 Warszawa (Poland)] [Institute of Electronic Materials Technology, ul. Wólczy?ska 133, 01-919 Warszawa (Poland); Skrzypek, D. [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland)] [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland); Skuta, A. [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland) [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland); Institute of Electronic Materials Technology, ul. Wólczy?ska 133, 01-919 Warszawa (Poland); Zajdel, P.; Guzik, A.; Duda, H. [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland)] [Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice (Poland)

2012-11-15T23:59:59.000Z

242

Optical and magneto-optical properties of Co-doped CeO{sub 2??} films in the 0.5 to 4?eV range  

SciTech Connect (OSTI)

Magnetically doped Ce{sub 1?x}Co{sub x}O{sub 2??} (nominal x?=?0.05 and 0.10) films were systematically studied by spectroscopic ellipsometry and magneto-optical spectroscopy. The samples were prepared by pulsed laser deposition on MgO(100) substrates and grew as textured polycrystalline films with thickness between 200 and 750?nm. They exhibited room temperature ferromagnetism and an out-of-plane easy axis attributed to magnetoelastic effects from the in-plane compressive strain. The dispersion of dielectric function of Ce{sub 1?x}Co{sub x}O{sub 2??} films was parametrized by the sum of Tauc-Lorentz and damped Lorentz oscillators and adjusted numerically. Deduced optical band gaps were similar to those of pure CeO{sub 2}, but the Co doping increased the optical absorption. The magneto-optical spectroscopy was carried out in both Faraday and Kerr configurations in the photon energy range from 0.5 to 4?eV, showing a strong dependence of the magneto-optical effect on the Co content near the optical band edge.

Veis, M., E-mail: veis@karlov.mff.cuni.cz; Kucera, M.; Zahradnik, M.; Antos, R. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 5, 12116 Prague (Czech Republic); Mistrik, J. [Faculty of Chemical Technology, University of Pardubice, 53210 Pardubice (Czech Republic); Bi, Lei; Kim, Hyun-Suk; Dionne, G. F.; Ross, C. A. [Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2014-05-07T23:59:59.000Z

243

Si le vide absolu existe droite du piston A et qu'on l'abandonne lui-mme, ce piston prend une vitesse qui crot avec le temps et  

E-Print Network [OSTI]

83 Si le vide absolu existe à droite du piston A et qu'on l'abandonne à lui-même, ce piston prend, on imprime au piston A une vitesse progressivement croissante et dirigée de manière à dilater le gaz. Quel que soit le mouvement imprimé à ce piston, pourvu que sa vitesse varie d'une manière continue, le vide

Boyer, Edmond

244

In Situ Studies of the Active Sites for the Water Gas Shift Reaction over Cu-CeO2 Catalysts: Complex Interaction Between Metallic Copper and Oxygen Vacancies of Ceria  

SciTech Connect (OSTI)

New information about the active sites for the water gas shift (WGS) reaction over Cu-CeO{sub 2} systems was obtained using in-situ, time-resolved X-ray diffraction (TR-XRD), X-ray absorption spectroscopy (TR-XAS, Cu K and Ce L3 edges), and infrared spectroscopy (DRIFTS). Cu-CeO{sub 2} nanoparticles prepared by a novel reversed microemulsion method (doped Ce1-xCuxO2 sample) and an impregnation method (impregnated CuO{sub x}/CeO{sub 2} sample) were studied. The results from all of the samples indicate that both metallic copper and oxygen vacancies in ceria were involved in the generation of active sites for the WGS reaction. Evidence was found for a synergistic Cu-O vacancy interaction. This interaction enhances the chemical activity of Cu, and the presence of Cu facilitates the formation of O vacancies in ceria under reaction conditions. Water dissociation occurred on the O vacancy sites or the Cu-O vacancy interface. No significant amounts of formate were formed on the catalysts during the WGS reaction. The presence of strongly bound carbonates is an important factor for the deactivation of the catalysts at high temperatures. This work identifies for the first time the active sites for the WGS reaction on Cu-CeO{sub 2} catalysts and illustrates the importance of in situ structural studies for heterogeneous catalytic reactions.

Wang,X.; Rodriguez, J.; Hanson, J.; Gamarra, D.; Martinez-Arias, A.; Fernandez-Garcia, M.

2006-01-01T23:59:59.000Z

245

The Reaction of bis(1,2,4-tri-t-butylcyclopentadienyl)ceriumbenzyl, Cp'2CeCH2Ph with Methylhalides: a Metathesis Reaction that does not proceed by a Metathesis Transition State  

SciTech Connect (OSTI)

The experimental reaction between [1,2,4-(Me3C)3C5H2]2CeCH2Ph and CH3X, X = F, Cl, Br, and I, yields the metathetical exchange products, [1,2,4-(Me3C)3C5H2]2CeX and CH3CH2Ph. The reaction is complicated by the equilibrium between the benzyl derivative and the metallacycle [[1,2,4-(Me3C)3C5H2] [(Me3C)2C5H2C(CH3)2CH2]Ce, plus toluene since the metallacycle reacts with CH3X. Labelling studies show that the methyl group of the methylhalide is transferred intact to the benzyl group. The mechanism, as revealed by DFT calculations on (C5H5)2CeCH2Ph and CH3F, does not proceed by way of a four-center mechanism, (sigma-bond metathesis) but a lower barrier process involves a haptotropic shift of the Cp2Ce fragment so that at the transition state the para-carbon of the benzene ring is attached to the Cp2Ce fragment while the CH2 fragment of the benzyl group attacks CH3F that is activated by coordination to the metal ion. As a result the mechanism is classified as an associative interchange process.

Werkema, Evan; Andersen, Richard; Maron, Laurent; Eisenstein, Odile

2009-09-02T23:59:59.000Z

246

Spectroscopic study of a Cu/CeO{sub 2} catalyst subjected to redox treatments in carbon monoxide and oxygen  

SciTech Connect (OSTI)

Redox processes induced by interaction of a calcined Cu/CeO{sub 2} catalyst with CO and reoxidation with O{sub 2} have been investigated by CO-TPR, EPR, FTIR of adsorbed CO, and XPS. The initial calcined samples shows the presence of dispersed Cu{sup 2+} species, which give rise in the EPR spectrum to signals due to isolated entities, a somewhat more aggregated Cu{sup 2+}-containing phase, and copper ionic pairs, in coexistence with an EPR-silent CuO-type phase, revealed by XPS. A significant reduction of copper is produced already by contact with CO at room temperature, EPR results suggesting that reducibility of Cu{sup 2+} species decreases with their aggregation degree. Simultaneously, the ceria surface is also reduced by this interaction, copper acting as a strong promoter of this process. A singular consequence of the synergistic reduction of both components is observed by subjecting the catalyst to CO at T{sub r} {ge} 473 K, at which the CO adsorption capability of copper is apparently suppressed, in view of the absence of copper carbonyls in the FTIR spectrum. This is attributed to the establishment of electronic interactions between reduced ceria and small metallic copper particles generated by the reduction process. Contact of the CO-reduced sample with O{sub 2} at room or higher temperature produces an important reoxidation of both copper and ceria, revealed by FTIR and EPR. The synergetic effects between copper and ceria in the reduction process and the easy reoxidation of deeply reduced ceria are thought to be crucial to explaining the high catalytic activity shown by this system for CO oxidation.

Martinez-Arias, A.; Fernandez-Garcia, M.; Soria, J.; Conesa, J.C. [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica] [CSIC, Madrid (Spain). Instituto de Catalisis y Petroleoquimica

1999-03-10T23:59:59.000Z

247

In partners EXTENSION CE  

E-Print Network [OSTI]

service Minnesota Local egetables i directors i a n in #12;LOCAL FOOD MARKET IN HEALTHCARE FRUITS AND VEGETABLES IN HEALTHCARE INSTITUTIONS BASED ON A SURVEY OF FOOD SERVICE DIRECTORS IN BECKER of Minnesota Extension conducted a survey of food service directors in Becker, Clay, Otter Tail, and Wilkin

Ciocan-Fontanine, Ionut

248

Neutron diffraction study of magnetic field induced behavior in the heavy Fermion Ce3Co4Sn13  

SciTech Connect (OSTI)

The specific heat of Ce3Co4Sn13 exhibits a crossover from heavy Fermion behavior with antiferromagnetic correlations at low field to single impurity Kondo behavior above 2 T. We have performed neutron diffraction measurements in magnetic fields up to 6 Tesla on single crystal samples. The (001) position shows a dramatic increase in intensity in field which appears to arise from static polarization of the 4f level and which at 0.14 K also exhibits an anomaly near 2T reflecting the crossover to single impurity behavior.

Christianson, Andrew D [ORNL; Goremychkin, E. A. [ISIS Facility, Rutherford Appleton Laboratory; Gardner, J. S. [Indiana University; Kang, H. J. [National Institute of Standards and Technology (NIST); Chung, J.-H. [National Institute of Standards and Technology (NIST); Manuel, P. [ISIS Facility, Rutherford Appleton Laboratory; Thompson, J. D. [Los Alamos National Laboratory (LANL); Sarrao, J. L. [Los Alamos National Laboratory (LANL); Lawrence, J. M. [University of California, Irvine

2008-01-01T23:59:59.000Z

249

Synthesis and crystal structure of the isotypic rare earth thioborates Ce[BS{sub 3}], Pr[BS{sub 3}], and Nd[BS{sub 3}  

SciTech Connect (OSTI)

The orthothioborates Ce[BS{sub 3}], Pr[BS{sub 3}] and Nd[BS{sub 3}] were prepared from mixtures of the rare earth (RE) metals together with amorphous boron and sulfur summing up to the compositions CeB{sub 3}S{sub 6}, PrB{sub 5}S{sub 9} and NdB{sub 3}S{sub 6}. The following preparation routes were used: solid state reactions with maximum temperatures of 1323 K and high-pressure high-temperature syntheses at 1173 K and 3 GPa. Pr[BS{sub 3}] and Nd[BS{sub 3}] were also obtained from rare earth chlorides RECl{sub 3} and sodium thioborate Na{sub 2}B{sub 2}S{sub 5} by metathesis type reactions at maximum temperatures of 1073 K. The crystal structure of the title compounds was determined from X-ray powder diffraction data. The thioborates are isotypic and crystallize in the orthorhombic spacegroup Pna2{sub 1} (No. 33; Z=4; Ce: a=7.60738(6)A, b=6.01720(4)A, c=8.93016(6)A; Pr: a=7.56223(4)A, b=6.00876(2)A, c=8.89747(4)A; Nd: a=7.49180(3)A, b=6.00823(2)A, c=8.86197(3)A) . The crystal structures contain isolated [BS{sub 3}]{sup 3-} groups with boron in trigonal-planar coordination. The sulfur atoms form the vertices of undulated kagome nets, which are stacked along [100] according to the sequence ABAB. Within these nets every second triangle is occupied by boron and the large hexagons are centered by rare earth ions, which are surrounded by overall nine sulfur species. - Abstract: Graphical Abstract Legend (TOC Figure): Table of Contents Figure The isotypic orthothioborates Ce[BS{sub 3}], Pr[BS{sub 3}] and Nd[BS{sub 3}] were prepared using different preparation routes. The crystal structure of the title compounds was determined from X-ray powder diffraction data. The crystal structures contain isolated [BS{sub 3}]{sup 3-} groups with boron in trigonal-planar coordination. The sulfur atoms form the vertices of corrugated kagome nets (sketched with blue dotted lines), which are stacked along [100] according to the sequence ABAB. Within these nets every second triangle is occupied by boron and the large hexagons are centered by rare earth ions, which are surrounded by overall nine sulfur species.

Hunger, Jens; Borna, Marija [Max Planck Institute for Chemical Physics of Solids, Noethnitzer Strasse 40, D-01187 Dresden (Germany); Kniep, Ruediger, E-mail: kniep@cpfs.mpg.d [Max Planck Institute for Chemical Physics of Solids, Noethnitzer Strasse 40, D-01187 Dresden (Germany)

2010-03-15T23:59:59.000Z

250

PoPulation Differentiation anD raPiD evolution of egg Color in aCCorDanCe with Solar raDiation  

E-Print Network [OSTI]

PoPulation Differentiation anD raPiD evolution of egg Color in aCCorDanCe with Solar raDiation Davi, . Diferenciación entre Poblaciones y Evolución Rápida del Color de los Huevos de Acuerdo a la Radiación Solar Uy C P' R d Pm wb, ://www.j. m/I.. DOI: 10.1525/k.2008.07033DOI: 10.1525/k.2008.07033 Bird egg color

Lahti, David C.

251

Data:Ead2cbdb-2126-45fe-a85d-ac94ce28685d | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revision has been approvedea02758d3 Nob05268d8cd No revisionf1fe86ce5f9a No revision has been

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261

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Data:B59c62d7-21b5-43df-94fb-cf27b924d0ce | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2 No revision has38865d08 No revisionb6dbbdc091c No revision has been approvedbe6be56861fb-cf27b924d0ce No

273

Data:B654abc4-3da6-4aac-ac62-0ce12cd06e3e | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2 No revision has38865d08 No revisionb6dbbdc091c No revision57b27257aa84abc4-3da6-4aac-ac62-0ce12cd06e3e

274

Data:C0a52638-ea2c-4f08-a1f2-e5332ce0e99a | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742 No revision has been approvedcf16e2831 No revisionef4e28824d9e45d1632a Noe5332ce0e99a

275

Data:C2f18274-b69f-4b3f-aee5-5cd471ff1ce6 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742 No revision has beena032db6d83 Noc-56029b877fee No-2ac0c7dfae14 Nof-aee5-5cd471ff1ce6

276

Data:57495fbc-0148-4f9a-b380-8964ce35f8c4 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b3da-78f7ef0b79f6 No revisionc8de9b501c3dd65b9388caee0960404ce35f8c4 No revision has been

277

Data:62b9252f-0acb-4f42-9153-056c19f3ce28 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revision has been approved fore6e8eee44 No revision has been approved for this page.-056c19f3ce28 No

278

Data:6311534c-5c06-43a9-b52b-3345ce0c2594 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revision has been approved fore6e8eee44 No revision has been8efe6555aea3 Nodb868e8293b95ce0c2594 No

279

Data:43b75c3d-8442-4863-862c-c540ce2bff2e | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b No revision hasaab84-009f-4fb1-b666-ed5d43c9089f No revision7447c826c540ce2bff2e No

280

Data:4c45a67b-3233-4864-a992-e1ddc0e804ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b Nobfef8fa58cf7 No revision has been approved for7276d No revision hasccd715e973e804ce No

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Data:4ef52611-1237-48ff-b5e4-5a331d645ce5 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b Nobfef8fa58cf7 No revisionf377c06978a3bcce-0d410894aead2-1b6c68d2566b Noa331d645ce5 No

282

Data:50bf8666-897e-420e-9296-bc0fb74c7ce2 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b Nobfef8fa58cf74865627f783 No revision has been approvedfb74c7ce2 No revision has been

283

Data:1b77e18e-6786-46e6-b1f8-a0f330d9b3ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3 No revision hasfcd92f-8652-45c0-96f0-a73be7466ef5efeb2958a4e35576efcf No-62964f9fb11ef330d9b3ce

284

Data:A7b83178-4652-4359-84d3-8fd23f276ce6 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44f-4cd6-87d8-e9253aab8d9c No revision hasf32924 Noda8782 Nof4a29ea02bd9afb393f276ce6 No

285

Data:Aa08fc77-4215-4406-97c5-475ce916ca14 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44f-4cd6-87d8-e9253aab8d9c No0a794995 Noaf5f-795951ea1924 No revision has been75ce916ca14

286

Data:Fbc7a7bd-03ca-42ce-a9de-795a5d445ab2 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has been approved for thisd785796ade4709e636e4428 NoFbc7a7bd-03ca-42ce-a9de-795a5d445ab2 No revision has

287

Data:Fcb9c794-d943-431f-9cb9-2d3ce1ec9f0b | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has been approved forcd976b98236 No revision has been approvedFcb9c794-d943-431f-9cb9-2d3ce1ec9f0b No

288

Data:8b5390fb-ee39-4af4-91d3-44504cac78ce | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revisione0a2d50bdf No18fed1db5 No revision hascef78-6440-4257-8584-e4134c8774d8 No revisioncac78ce

289

Data:8c852f57-99ea-4fc7-957e-2695ce0b21ad | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revisione0a2d50bdf No18fed1db5 No30e696c No revision has beena6e7db5d8e7423c384151e-2695ce0b21ad No

290

Data:9018f71d-e30a-40f8-a7d4-85d3ce0cd33a | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revisione0a2d50bdf No18fed1db58-e7b51f6388655-83a5-eb235f1bc98b No revisiond3ce0cd33a No revision

291

Data:995303c1-2d9c-49dc-a96a-d571ce8fb967 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revisione0a2d50bdf35248292f1de-f2ac9a2bd9c05-8a3226ea1649af-19c5bd7c73d5 No revision71ce8fb967 No

292

Data:9aa8976e-2e8b-4ce2-80c6-6e6ef2218a7e | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 No revision has been approved for this page.76f5afd9 Nob-4ce2-80c6-6e6ef2218a7e No

293

Data:9d1ccf31-0274-4c1e-93c7-4121ce28476f | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 No revision has been approved095c1f504bccf31-0274-4c1e-93c7-4121ce28476f No revision has

294

Data:Ce1740e2-34b1-4f5a-a28a-025061307347 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved for this page.

295

Data:Ce18419d-c9a8-4262-9b0f-b19dfd989e19 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved for this

296

Data:Ce1e05d4-c268-4fb1-9ae8-a28f19331d5e | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved for

297

Data:Ce1f8b49-9c33-442f-85b3-202cdfe22397 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved forcdfe22397 No

298

Data:Ce2cb140-d2c5-46c7-9db6-45793f020444 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved3f020444 No revision

299

Data:Ce2d8931-65c2-402a-ad6f-e2457290a745 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved3f020444 No

300

Data:Ce354898-56c6-4a00-8061-8d98a7725e13 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved3f020444

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Data:Ce35d66b-0bac-49ed-b1a4-4798604ee20b | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been approved3f0204444798604ee20b

302

Data:Ce364f9c-12fa-492d-8709-b7a844aa445d | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has been

303

Data:Ce3caf43-0af8-40dc-a74f-268e35e875c4 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision has

304

Data:Ce4b5c29-1251-4f41-9558-57dedca7e7a8 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision hasf-0a6eefe99579 No revision

305

Data:Ce5ebca7-3ca1-4054-8d48-44b83b683152 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision hasf-0a6eefe99579 No

306

Data:Ce672009-05f2-4dcb-aa67-266845299fb9 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision hasf-0a6eefe99579 No6845299fb9 No

307

Data:Ce6d9c9d-cbec-4478-b62e-baa6c4a20c68 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision hasf-0a6eefe99579 No6845299fb9

308

Data:Ce702f80-5328-4a23-9bf2-686a2ede941c | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision hasf-0a6eefe99579

309

Data:Ce729a3d-8cf3-42be-aa55-f56af77095b4 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revision

310

Data:Ce913245-9b0f-4f93-b902-d4d81c885fc8 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 No

311

Data:Ce9437ae-b97d-4b72-b4c2-692d70f3f498 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 Nodaf70201be No revision

312

Data:Ce978432-c400-4b9a-aac3-f064e907ab91 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2bb71-d4159a938742e80b26cc4 Nodbb-44ce-80f8-79eb97a58f0a No revisionde0244033 Nodaf70201be No

313

Data:Cf87540f-a091-4b3d-a854-3a4580ce377a | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Pagec-01b596aa1744 No revision has been approved for this page. It is currently under review by381a4316dbd0ce377a No revision

314

Data:D14bdc50-afc2-48b7-8683-46ce3a082b48 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Pagec-01b596aa1744 No revision has been approved for this1e-67de4b817342 Noafc2-48b7-8683-46ce3a082b48 No revision has been

315

Data:D178a8b1-1230-486b-81d7-7735ce2de0c0 | Open Energy Information  

Open Energy Info (EERE)

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328

A novel yellow-emitting SrAlSi{sub 4}N{sub 7}:Ce{sup 3+} phosphor for solid state lighting: Synthesis, electronic structure and photoluminescence properties  

SciTech Connect (OSTI)

Ce{sup 3+}-doped and Ce{sup 3+}/Li{sup +}-codoped SrAlSi{sub 4}N{sub 7} phosphors were synthesized by gas pressure sintering of powder mixtures of Sr{sub 3}N{sub 2}, AlN, ?-Si{sub 3}N{sub 4}, CeN and Li{sub 3}N. The phase purity, electronic crystal structure, photoluminescence properties of SrAlSi{sub 4}N{sub 7}:Ce{sup 3+}(Ce{sup 3+}/Li{sup +}) were investigated in this work. The band structure calculated by the DMol{sup 3} code shows that SrAlSi{sub 4}N{sub 7} has a direct band gap of 3.87 eV. The single crystal analysis of Ce{sup 3+}-doped SrAlSi{sub 4}N{sub 7} indicates a disordered Si/Al distribution and nitrogen vacnacy defects. SrAlSi{sub 4}N{sub 7} was identified as a major phase of the fired powders, and Sr{sub 5}Al{sub 5}Si{sub 21}N{sub 35}O{sub 2} and AlN as minor phases. Both Ce{sup 3+} and Ce{sup 3+}/Li{sup +} doped SrAlSi{sub 4}N{sub 7} phosphors can be efficiently excited by near-UV or blue light and show a broadband yellow emission peaking around 565 nm. A highest external quantum efficiency of 38.3% under the 450 nm excitation was observed for the Ce{sup 3+}/Li{sup +}-doped SrAlSi{sub 4}N{sub 7} (5 mol%). A white light LED lamp with color temperature of 6300 K and color rendering index of Ra=78 was achieved by combining Sr{sub 0.97}Al{sub 1.03}Si{sub 3.997}N/94/maccounttest14=t0005{sub 1}8193 {sub 7}:Ce{sup 3+}{sub 0.03} with a commercial blue InGaN chip. It indicates that SrAlSi{sub 4}N{sub 7}:Ce{sup 3+} is a promising yellow emitting down-conversion phosphor for white LEDs. - Graphical abstract: One-phosphor converted white light-emitting diode (LED) was fabricated by combining a blue LED chip and a yellow-emitting SrAlSi4N7:Ce{sup 3+} phosphor (see inset), which has the color rendering index of 78 and color temperature of 6300 K. - Highlights: • We reported a new yellow nitride phosphor suitable for solid state lighting. • We solved the crystal structure and evidenced a disordered Si/Al distribution. • We fabricated a high color rendering white LEDs by using a single SrAlSi4N7:Ce.

Ruan, Jian [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Laboratory of Glasses and Nanostructured Functional Materials, 122 Luoshi Road, Wuhan, Hubei 430070 (China); Xie, Rong-Jun, E-mail: Xie.Rong-Jun@nims.go.jp [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Funahashi, Shiro [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tanaka, Yoshinori [Green Computational Materials Science Group, Global Research Center for Environment and Energy based on Nanomaterials Science (Green), National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0044 (Japan); Takeda, Takashi; Suehiro, Takayuki; Hirosaki, Naoto [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Yuan-Qiang [Dow Electronic Materials, 201 Washington Road, Princeton, NJ 08540 (United States)

2013-12-15T23:59:59.000Z

329

Insensitivity of the pressure dependences of characteristic energy scales in Ce1–xRxCoIn? (R=Yb,Y,Gd) to the electronic configuration of the rare-earth ion  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Cooperative Ce and Yb valence fluctuations have recently been proposed as the mechanism responsible for stabilizing correlated electron phenomena in Ce??xYbxCoIn? over an unexpectedly large range of concentrations. In order to better understand the origins and character of this stability, we have measured the effect of applied pressure on relevant energy scales such as the superconducting critical (Tc) and Kondo-lattice coherence (T*) temperatures of Ce??xRxCoIn? with R=Yb, Y, and Gd. Electrical resistivity measurements were performed under applied pressure on samples doped with intermediate-valent Yb and stable-valent Gd and Y, and the responses of Tc and T* to increased pressure in these systems are compared. The character of Tc(P) and T*(P) in Ce??xRxCoIn? depends only on their respective ambient-pressure values Tc(0) and T*(0), independent of the electronic configuration of R or concentration x. The consequences of this result are discussed within the context of possible cooperative valence fluctuations in Ce??xYbxCoIn?.

White, B. D.; Hamlin, J. J.; Huang, K.; Shu, L.; Lum, I. K.; Baumbach, R. E.; Janoschek, M.; Maple, M. B.

2012-09-01T23:59:59.000Z

330

CO chemisorption effects on cerium initial and final states in the core-level photoelectron spectrum of CeIr/sub 2/  

SciTech Connect (OSTI)

Carbon monoxide (CO) adsorption on the mixed-valence compound CeIr/sub 2/ has been studied by X-ray photoelectron spectroscopy. CO adsorption on this surface is predominantly molecular. We show that changes in the cerium 3d spectrum upon CO chemisorption may be separated into initial- and final-state effects. In the initial state, stabilization of the (Ce)(5d6s)34f1 configuration occurs due to an increase in effective nuclear charge on the cerium atom. This leads to a decrease in f0 intensity in the recorded spectrum. Increased f-electron repulsion in the final state raises the energy of the f2 final-state configuration and causes a 2.2-eV shift to higher binding energy of the 3d5/2f2 peak. The 0.5-eV binding energy shifts of the 3d5/2f1 and 3d3/2f1 peaks along with the 2.2-eV shift of the 3d5/2f2 peak indicate that the f orbitals are quite-sensitive indicators of the surface oxidation state in this compound.

Lindquist, J.M.; Hemminger, J.C.

1987-01-01T23:59:59.000Z

331

Synthesis of solid solution Er{sub 2-x}Ce{sub x}W{sub 3}O{sub 12} and studies of their thermal expansion behavior.  

SciTech Connect (OSTI)

The syntheses and structures of Er{sub 2-x}Ce{sub x}W{sub 3}O{sub 12} were studied. It was found that pure phases could form only for 0.0 {le} x {le} 0.4 and 1.5 {le} x {le} 2.0. Compounds with 0 {le} x {le} 0.4 have the hydrated orthorhombic structure at room temperature and transform to unhydrated orthorhombic one above 135 C whereas samples with 1.5 {le} x {le} 2.0 crystallize in monoclinic structure. Thermal expansion properties of Er{sub 2-x}Ce{sub x}W{sub 3}O{sub 12} were studied with high temperature X-ray powder diffraction. Samples with 0 {le} x {le} 0.4 exhibit negative thermal expansion in temperature range of 200-800 C and higher cerium content leads to more negative thermal expansion coefficient. However, compounds with 1.5 {le} x {le} 2.0 show positive thermal expansion owing to the edge-sharing polyhedra.

Wu, M. M.; Cheng, Y. Z.; Peng, J.; Xiao, X. L.; Chen, D. F.; Kiyanagi, R.; Fieramosca, J. S.; Short, S.; Jorgensen, J.; Hu, Z. B.; Graduate Univ. Chinese Academy of Sciences; China Inst. of Atomic Energy

2007-01-30T23:59:59.000Z

332

X-ray absorption studies of the local structure and f-level occupancy in CeIr(1-x)Rh(x)In(5)  

SciTech Connect (OSTI)

The CeIr{sub 1-x}Rh{sub x}In{sub 5} series exhibits a range of interesting phenomena, including heavy-fermion superconductivity, non-Fermi liquid behavior, and concomitant antiferromagnetism (AF) and superconductivity (SC). In the low-Rh concentration range (0.1 {ge} x {ge} 0.5), specific heat measurements show a broad anomaly, suggestive of gross phase separation. We have performed x-ray absorption experiments at the Ce L{sub III}, Ir L{sub III}, and Rh K-edges as a function of Rh concentration and temperature. X-ray absorption near-edge structure (XANES) measurements indicate that cerium is close to trivalent in this system, with no measurable change with temperature from 20-300 K, consistent with a heavy-fermion material. Extended x-ray absorption fine structure (EXAFS) measurements as a function of temperature from all measured edges indicate the local crystal structure of all samples is well ordered, with no gross phase separation observed, even for samples with x = 0.125 and x = 0.25. These results therefore suggest that the anomalous specific heat behavior in the 0.1 {ge} x {ge} 0.5 range have some other explanation, and some possibilities are discussed.

Daniel, M.; Han, S.-W.; Booth, C.H.; Cornelius, A.L.; Pagliuso, P.G.; Sarrao, J.L.; Thompson, J.D.

2004-04-15T23:59:59.000Z

333

Unraveling the Active Site in Copper-Ceria Systems for the Water-Gas Shift Reaction: In Situ Characterization of an Inverse Powder CeO2-x/CuO-Cu Catalyst  

SciTech Connect (OSTI)

An inverse powder system composed of CeO{sub 2} nanoparticles dispersed over a CuO-Cu matrix is proposed as a novel catalyst for the water-gas shift reaction. This inverse CeO{sub 2}/CuO-Cu catalyst exhibits a higher activity than standard Cu/CeO{sub 2} catalysts. In situ synchrotron characterization techniques were employed to follow the structural changes of CeO{sub 2}/CuO-Cu under reaction conditions. Time-resolved X-ray diffraction experiments showed the transformation of CuO to metallic Cu via a Cu{sub 2}O intermediate. Short-order structural changes were followed by pair distribution function analysis and corroborated the results obtained by diffraction. Moreover, X-ray absorption spectroscopy also revealed oxidation state changes from Cu{sup 2+} to Cu{sup 0} and the partial reduction of CeO{sub x} nanoparticles. The activity data obtained by mass spectrometry revealed that hydrogen production starts once the copper has been fully reduced. The strong interaction of ceria and copper boosted the catalytic performance of the sample. The inverse catalyst was active at low temperatures, stable to several reaction runs and to redox cycles. These characteristics are highly valuable for mobile fuel cell applications. The active phases of the inverse CeO{sub 2}/CuO-Cu catalyst are partially reduced ceria nanoparticles strongly interacting with metallic copper. The nature and structure of the ceria nanoparticles are of critical importance because they are involved in processes related to water dissociation over the catalyst surface.

Barrio, L.; Estrella, M; Zhou, G; Wen, W; Hanson, J; Hungria, A; Hornes, A; Fernandez-Garcia, M; Martinez-Arias, A; Rodriguez, J

2010-01-01T23:59:59.000Z

334

Unraveling the Active Site in Copper-ceria Systems for the Water Gas Shift Reaction: In-situ Characterization of an Inverse Powder CeO2-x/CuO-Cu Catalyst  

SciTech Connect (OSTI)

An inverse powder system composed of CeO{sub 2} nanoparticles dispersed over a CuO-Cu matrix is proposed as a novel catalyst for the water-gas shift reaction. This inverse CeO{sub 2}/CuO-Cu catalyst exhibits a higher activity than standard Cu/CeO{sub 2} catalysts. In situ synchrotron characterization techniques were employed to follow the structural changes of CeO{sub 2}/CuO-Cu under reaction conditions. Time-resolved X-ray diffraction experiments showed the transformation of CuO to metallic Cu via a Cu{sub 2}O intermediate. Short-order structural changes were followed by pair distribution function analysis and corroborated the results obtained by diffraction. Moreover, X-ray absorption spectroscopy also revealed oxidation state changes from Cu{sup 2+} to Cu{sup 0} and the partial reduction of CeOx nanoparticles. The activity data obtained by mass spectrometry revealed that hydrogen production starts once the copper has been fully reduced. The strong interaction of ceria and copper boosted the catalytic performance of the sample. The inverse catalyst was active at low temperatures, stable to several reaction runs and to redox cycles. These characteristics are highly valuable for mobile fuel cell applications. The active phases of the inverse CeO{sub 2}/CuO-Cu catalyst are partially reduced ceria nanoparticles strongly interacting with metallic copper. The nature and structure of the ceria nanoparticles are of critical importance because they are involved in processes related to water dissociation over the catalyst surface.

Rodriguez, J.A.; Barrio, L.; Estrella, M.; Zhou, G.; Wen, W.; Hanson, J.C.; Hungría, A.B.; Hornés, A.; Fernández-García, M.; Arturo Martínez-Arias, A.

2010-03-04T23:59:59.000Z

335

The chemical stability and conductivity of BaCe{sub 0.9-x}Y{sub x}Nb{sub 0.1}O{sub 3-{sigma}} proton-conductive electrolyte for SOFC  

SciTech Connect (OSTI)

BaCe{sub 0.8}Y{sub 0.2}O{sub 3-{delta}} and BaCe{sub 0.9-x}Y{sub x}Nb{sub 0.1}O{sub 3-{delta}} (x = 0.1, 0.15, 0.2, 0.25, 0.3, 0.35) were prepared by a solid-state reactions. It was found that the BaCe{sub 0.8}Y{sub 0.2}O{sub 3-{delta}} samples decomposed into CeO{sub 2} and BaCO{sub 3} after being exposed in the atmosphere (3% CO{sub 2} + 3% H{sub 2}O + 94% N{sub 2}) at 700 deg. C for 10 h. However, samples containing Nb remains unchanged in the same conditions, demonstrating a better stability in the presence of CO{sub 2} and H{sub 2}O. The conductivity of BaCe{sub 0.9-x}Y{sub x}Nb{sub 0.1}O{sub 3-{delta}} increased with the increase of Y content (x {<=} 0.30), and the highest value was observed at x = 0.30 where a significant decrease in conductivity took place at x = 0.35. The conductivity of BaCe{sub 0.6}Y{sub 0.3}Nb{sub 0.1}O{sub 3-{delta}} reaches 0.01 S/cm in humid hydrogen at 700 deg. C, slight lower than BaCe{sub 0.8}Y{sub 0.2}O{sub 3-{delta}}, 0.012 S/cm in the same conditions. Fuel cell with BaCe{sub 0.6}Y{sub 0.3}Nb{sub 0.1}O{sub 3-{delta}} as-prepared was successfully prepared and humidified hydrogen was supplied as fuels in evaluating the fuel cell performance. The open circuit voltage, peak power density and interfacial resistance at 700 deg. C were 1.02 V, 345 mW/cm{sup 2} and 0.27 {Omega} cm{sup 2}, respectively.

Xie Kui [Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Yan Ruiqiang [Department of Materials Engineering, Taizhou University, Linhai, Zhejiang 317000 (China); Xu Xiaoxiang [School of Chemistry, University of St Andrews, St Andrews, Fife, KY16 9ST (United Kingdom); Liu Xingqin, E-mail: xqliu@ustc.edu.cn [Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Meng Guangyao [Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China)

2009-07-01T23:59:59.000Z

336

Quaternary Germanides Formed in Molten Aluminum: Tb2NiAl4Ge2 and Ce2NiAl6-xGe4-y (x 0.24, y 1.34)  

E-Print Network [OSTI]

Quaternary Germanides Formed in Molten Aluminum: Tb2NiAl4Ge2 and Ce2NiAl6-xGe4-y (x 0.24, y 1 gebildete quaternäre Germanide: Tb2NiAl4Ge2 und Ce2NiAl6-xGe4-y (x 0.24, y 1.34) Inhaltsübersicht. Die ebenfalls die Introduction The use of metal fluxes in exploratory synthesis presents significant synthetic

Trikalitis, Pantelis N.

337

Solid state reactions of nanocrystalline Ce{sub 0.5}Yb{sub 0.5}O{sub 1.75} mixed oxide with high surface area silica in oxidizing and reducing atmosphere  

SciTech Connect (OSTI)

The interaction of nanocrystalline Ce{sub 0.5}Yb{sub 0.5}O{sub 1.75} mixed oxide with a high surface amorphous silica support in an oxidizing and reducing atmosphere was studied by XRD, HRTEM, SAED, SEM and BET techniques. The Ce{sub 0.5}Yb{sub 0.5}O{sub 1.75}-SiO{sub 2} system shows very high structural and size stability in the oxidizing atmosphere up to 1000 Degree-Sign C, but in hydrogen spreading of the oxide onto silica occurs at temperatures above 800 Degree-Sign C. In the oxidizing atmosphere stability of the mixed oxide is limited by extraction of ytterbium from the oxide driven by a tendency to form ytterbium silicates. A new polymorph of Yb silicate, isomorphic with y-Y{sub 2}Si{sub 2}O{sub 7} (yttrialite), has been identified in the samples containing the mixed Ce-Yb oxide. The absence of y-Yb{sub 2}Si{sub 2}O{sub 7} silicate in the Yb{sub 2}O{sub 3}-SiO{sub 2} samples treated in similar conditions indicates that Ce{sup 4+} ions are needed to stabilize the structure. - Graphical abstract: Structure evolution of nano-Ce{sub 0.5}Yb{sub 0.5}O{sub 1.75}-SiO{sub 2} in air and in H{sub 2}. Highlights: Black-Right-Pointing-Pointer Nano-Ce{sub 0.50}Yb{sub 0.50}O{sub 1.75} on SiO{sub 2} is stable in air up to 1000 Degree-Sign C but spreads in hydrogen at 800 Degree-Sign C. Black-Right-Pointing-Pointer Formation of Yb silicates determines the stability of Ce{sub 0.50}Yb{sub 0.50}O{sub 1.75} at high temperatures. Black-Right-Pointing-Pointer New, y-Yb{sub 2}Si{sub 2}O{sub 7} silicate (yttrialite type) forms in Ce{sub 0.5}Yb{sub 0.5}O{sub 1.75}-SiO{sub 2} in H{sub 2} at 1100 Degree-Sign C.

Malecka, Malgorzata A. [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw 2 (Poland); Kepinski, Leszek, E-mail: L.Kepinski@int.pan.wroc.pl [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw 2 (Poland)

2012-08-15T23:59:59.000Z

338

Role of metal components in Pd?Cu bimetallic catalysts supported on CeO2 for the oxygen-enhanced water gas shift  

SciTech Connect (OSTI)

Catalytic hydrogen production and CO removal in a post-reforming process are critical for low-temperature fuel cell applications. The present study aims at clarifying the role of metal components in bimetallic catalysts for oxygen-enhanced water gas shift (OWGS), wherein a small amount of O{sub 2} is added to H{sub 2}-rich reformate gas to enhance CO shift. Among CeO{sub 2}-supported bimetallic catalysts, Pd-Cu and Pt-Cu combinations were found to show strong synergetic promoting effect in OWGS, which leads to much higher CO conversion and higher H{sub 2} yield than WGS at low temperature around 250 C. Temperature programmed reduction (TPR) showed strong interaction between Pd and Cu in Pd-Cu/CeO{sub 2} by a single reduction peak in contrast to multiple peaks on monometallic Cu/CeO{sub 2}. Extended X-ray absorption fine structure (EXAFS) analysis revealed that such bimetallic Pd-Cu and Pt-Cu form alloy nanoparticles, where noble metal is mainly surrounded by Cu atoms. Oxygen storage capacity (OSC) measurements point to higher resistance of Pd-Cu to oxidation indicating that Pd keeps Cu in reduced state in air pulse condition. From kinetic study, Pd in Pd-Cu was found to promote CO shift, rather than CO oxidation by increasing the number of active sites and by suppressing H{sub 2} activation (that is inherent to monometallic Pd), which minimizes both the inhibition effect of H{sub 2} and the loss of H{sub 2} by oxidation in OWGS. Transient response technique revealed that Cu in Pd-Cu enhances desorption of strongly chemisorbed CO{sub 2} on catalyst surface in contrast to very slow CO{sub 2} desorption from surface of monometallic Pd. Thus, the excellent OWGS activity of Pd-Cu catalyst has been attributed to the complementary roles of the two metals for enhancing CO shift, which is realized by its alloy structure and the accompanying strong interaction between metal components.

Kugai, J.; Miller, J. T.; Guo, N.; Song, C. (Chemical Sciences and Engineering Division); ( PSC-USR); (Penn State Univ.)

2011-06-01T23:59:59.000Z

339

Effects of Ce, Y and Mo Addition on the Stress Accelerated Oxidation of Austenitic Stainless Steel in Oxygenated High Temperature Water  

SciTech Connect (OSTI)

Based upon the recent progress in mechanistic understanding of intergranular stress corrosion cracking (IGSCC) of austenitic stainless steels in high temperature water in light water reactor (LWR), the effects of Ce, Y, and Mo addition on oxidation kinetics under a tensile stress condition was investigated. Minor impurity of P was also studied. A kind of circumferentially notched tensile specimen was prepared to simulate the crack tip stress field. The notched specimens of different materials studied were applied with an almost constant load in simulated boiling water reactor (BWR) water. The oxidation was examined by the specimen cross section. It was shown that these elements have quite clear effects on the metal oxidation and alloying element distribution in the oxide layer. (authors)

Shengchun Wang; Nobuaki Kawaguchi; Tetsuo Shoji [Fracture Research Institute, Graduate School of Engineering, Tohoku University, Aramaki Aoba 01, Aoba-ku, Sendai 980-8579 (Japan)

2004-07-01T23:59:59.000Z

340

Data:Ef0bd4a8-7702-40c5-b219-2bb62c8ce86b | Open Energy Information  

Open Energy Info (EERE)

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341

Data:F8c182e5-1529-4f79-a950-78d40ce901b5 | Open Energy Information  

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342

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343

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344

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345

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346

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347

Evidence for anisotropic triplet superconductor order parameter in half metallic ferromagnetic La_0.7Ca_0.3MnO_3 proximity coupled to superconducting Pr_1.85Ce_0.15CuO_4  

E-Print Network [OSTI]

Scanning tunneling spectroscopy measurements performed on La_0.7Ca_0.3MnO_3 (LCMO) films epitaxially grown on Pr_1.85Ce_0.15CuO_4 (PCCO) reveal localized penetration of superconductivity into the LCMO up to distances much larger than is possible...

Kalcheim, Y.; Millo, O.; Egilmez, M.; Robinson, J. W. A.; Blamire, M. G.

2012-03-07T23:59:59.000Z

348

Gorur D, Rasmussen CE. Dirichlet process Gaussian mixture models: Choice of the base distribution. JOURNAL OF COMPUTER SCIENCE AND TECHNOLOGY 25(4): 615626 July 2010/DOI 10.1007/s11390-010-1051-1  

E-Print Network [OSTI]

G¨or¨ur D, Rasmussen CE. Dirichlet process Gaussian mixture models: Choice of the base distribution Rasmussen2,3 1 Gatsby Computational Neuroscience Unit, University College London, London WC1N 3AR, U.K. 2 Department of Engineering, University of Cambridge, Cambridge CB2 1PZ, U.K. 3 Max Planck Institute

Edinburgh, University of

349

En forkortet udgave af denne kommentar blev bragt i Berlingske Tidende, 2. sektion (Magasin s. 14), lrdag den 21. januar 2006 (online her: http://www.nbi.dk/~emmeche/cePubl/2006a.forskpol.html).  

E-Print Network [OSTI]

), lørdag den 21. januar 2006 (online her: http://www.nbi.dk/~emmeche/cePubl/2006a gang præges af den lineære models logik, og at de teknologiske, såkaldt våde områder af forskningen

Emmeche, Claus

350

College of AgriCulturAl SCienCeS AgriCulturAl reSeArCh And CooperAtive extenSion Access and AllocAtion of  

E-Print Network [OSTI]

College of AgriCulturAl SCienCeS · AgriCulturAl reSeArCh And CooperAtive extenSion Access and Alloc- gation, recreation, and hydro- electric power generation, do not involve withdrawing water from its level of government is best suited to regulate water use. Predictions that climate change will influence

Boyer, Elizabeth W.

351

CO Oxidation on Inverse CeOx/Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O2  

SciTech Connect (OSTI)

A Cu(111) surface displays a low activity for the oxidation of carbon monoxide (2CO + O{sub 2} {yields} 2CO{sub 2}). Depending on the temperature, background pressure of O{sub 2}, and the exposure time, one can get chemisorbed O on Cu(111) or a layer of Cu{sub 2}O that may be deficient in oxygen. The addition of ceria nanoparticles (NPs) to Cu(111) substantially enhances interactions with the O{sub 2} molecule and facilitates the oxidation of the copper substrate. In images of scanning tunneling microscopy, ceria NPs exhibit two overlapping honeycomb-type moire structures, with the larger ones (H{sub 1}) having a periodicity of 4.2 nm and the smaller ones (H{sub 2}) having a periodicity of 1.20 nm. After annealing CeO{sub 2}/Cu(111) in O{sub 2} at elevated temperatures (600-700 K), a new phase of a Cu{sub 2}O{sub 1+x} surface oxide appears and propagates from the ceria NPs. The ceria is not only active for O{sub 2} dissociation, but provides a much faster channel for oxidation than the step edges of Cu(111). Exposure to CO at 550-750 K led to a partial reduction of the ceria NPs and the removal of the copper oxide layer. The CeO{sub x}/Cu(111) systems have activities for the 2CO + O{sub 2} {yields} 2CO{sub 2} reaction that are comparable or larger than those reported for surfaces of expensive noble metals such as Rh(111), Pd(110), and Pt(100). Density-functional calculations show that the supported ceria NPs are able to catalyze the oxidation of CO due to their special electronic and chemical properties. The configuration of the inverse oxide/metal catalyst opens new interesting routes for applications in catalysis.

F Yang; J Graciani; J Evans; P Liu; J Hrbek; J Fdez. Sanz; J Rodriguez

2011-12-31T23:59:59.000Z

352

Effect of synthesis conditions on the nanopowder properties of Ce{sub 0.9}Zr{sub 0.1}O{sub 2}  

SciTech Connect (OSTI)

Graphical abstract: . The synthesis of nanocrystalline Ce{sub 0.9}Zr{sub 0.1}O{sub 2} powders via the gel-combustion method, using different fuels, and following either stoichiometric or non-stoichiometric pH-controlled routes is investigated. Research highlights: {yields} All samples exhibited the fluorite-type crystal structure, nanometric average crystallite size and negligible carbon content. {yields} Synthesis conditions strongly affect the average crystallite size, the degree of agglomeration, the specific surface area and the pore volume. {yields} Our results indicate that, by controlling the synthesis conditions it is possible to obtain solids with custom-made morphological properties. -- Abstract: In this work, the synthesis of nanocrystalline Ce{sub 0.9}Zr{sub 0.1}O{sub 2} powders via the gel-combustion method, using different fuels, and following either stoichiometric or non-stoichiometric pH-controlled routes is investigated. The objective is to evaluate the effect of synthesis conditions on the textural and morphological properties, and the crystal structure of the synthesized materials. The solids were characterized by nitrogen physisorption, Scanning Electron Microscopy (SEM), X-ray powder diffraction (XPD), and Carbon-Hydrogen-Nitrogen Elemental Analysis (CHN). All the powders exhibited nanometric crystallite size, fluorite-type structure and negligible carbon content. Synthesis conditions strongly affect the average crystallite size, the degree of agglomeration, the specific surface area and the pore volume. Our results indicate that, by controlling the synthesis conditions it is possible to obtain solids with custom-made morphological properties.

Zimicz, M.G.; Fabregas, I.O.; Lamas, D.G. [CINSO (Centro de Investigaciones en Solidos) CONICET-CITEFA J.B. de La Salle 4397, 1603 Villa Martelli, Pcia. de Buenos Aires (Argentina)] [CINSO (Centro de Investigaciones en Solidos) CONICET-CITEFA J.B. de La Salle 4397, 1603 Villa Martelli, Pcia. de Buenos Aires (Argentina); Larrondo, S.A., E-mail: susana@di.fcen.uba.ar [Laboratorio de Procesos Cataliticos, Departamento de Ingenieria Quimica, Facultad de Ingenieria, Universidad de Buenos Aires, Pabellon de Industrias, Ciudad Universitaria, 1428 Buenos Aires (Argentina)

2011-06-15T23:59:59.000Z

353

Habitat types of the Eastern Cross Timbers of Texas  

E-Print Network [OSTI]

wells of north-central Texas. When timber is cut from any portion of the Cross Timbers, and porous sandy soil exposed to the plow, rapid erosion begins, the area is destroyed mOIN 0 I O N Ill& Ifiro Chhl Oimoec co rn rn hl w rnLA cr Io o N mme... mmril chio OCO %CO CF ril IA m hl IO hl chl m wm mNNWNNLA m4 o' N o 4' c ch c&e mrn mLALo Io c- CD o c 0 wco hl hl N 0 4 0 0 I I 0 CO cFIIA LAO chN I COP LAIC O m LA CF Lfi ril rn co CFI O chio m I NCOOCO N N m IA IO LA CFI N CI IO I...

Marcy, Larry Eugene

2012-06-07T23:59:59.000Z

354

Tracking Hemicellulose and Lignin Deconstruction During Hydrothermal Pretreatment of Biomass  

E-Print Network [OSTI]

5.13c. (9) Wyman C. Ethanol Fuel in Encyclopedia of Energy;10): 1865-1871. (6) Wyman C. Ethanol Fuel in Encyclopedia ofscenario for cellulosic ethanol fuel production, and speaks

McKenzie, Heather Lorelei

2012-01-01T23:59:59.000Z

355

,"Plant","Primary Energy Source","Operating Company","Net Summer...  

U.S. Energy Information Administration (EIA) Indexed Site

1,"William F Wyman","Petroleum","FPL Energy Wyman LLC",821.9 2,"Westbrook Energy Center Power Plant","Natural Gas","Westbrook Energy Center",506 3,"Maine Independence...

356

Crystal structure, magnetism and transport properties of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10}  

SciTech Connect (OSTI)

Single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10} were obtained from a process in which a polycrystalline sample of CeRu{sub 2}Al{sub 2}B was annealed in an excess of a Ni–In flux. The initial phase, CeRu{sub 2}Al{sub 2}B, does not recrystallize, instead, crystals of a new phase, Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10}, could be isolated once the flux was removed. The title compound crystallizes in the tetragonal space group P4/nmm (No. 129) with a=1139.02(8), c=801.68(6) pm (c/a=0.70) in the Nd{sub 3}Ni{sub 29}Si{sub 4}B{sub 10} structure type. Electrical resistivity measurements reveal metallic behavior with a minimum of 700 µ? cm and a small residual resistivity ratio of RRR=1.4 indicating a large amount of disorder scattering. The cerium atoms are either in the 4+ or an intermediate valence state with a valence fluctuation temperature far above room temperature. - Graphical abstract: Single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}A{sub l4.1}B{sub 10} were obtained using a process in which a polycrystalline sample of CeRu{sub 2}Al{sub 2}B was annealed in an excess of a Ni–In flux. Electrical resistivity measurements reveal metallic behavior with a minimum of 700 ?? cm and a small residual resistivity ratio of RRR=1.4 indicating a large amount of disorder scattering. The cerium atoms are either in the 4+ or an intermediate valence state with a valence fluctuation temperature far above room temperature. Display Omitted - Highlights: • Flux synthesis of high quality single crystals of Ce{sub 3}Ni{sub 25.75}Ru{sub 3.16}Al{sub 4.1}B{sub 10} is presented along with the crystal structure, magnetic and transport properties. • The compound is isostructural to Nd{sub 3}Ni{sub 29}Si{sub 4}B{sub 10} but is first of this structure type showing mixed occupancies of d-elements. • This is an intermetallic phase with Ce in either the 4+ or an intermediate valence state. • The fact that this structure with mixed occupied transition metal sites exists suggests that more compounds of this type should be accessible and the physical properties tuned.

Janka, Oliver [Department of Chemistry, University of California, One Shields Ave, Davis, CA 95616 (United States); Baumbach, Ryan E.; Thompson, Joe D. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bauer, Eric D., E-mail: edbauer@lanl.gov [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Kauzlarich, Susan M., E-mail: smkauzlarich@ucdavis.edu [Department of Chemistry, University of California, One Shields Ave, Davis, CA 95616 (United States)

2013-09-15T23:59:59.000Z

357

Wet oxidation of phenol on Ce{sub 1{minus}x}Cu{sub x}O{sub 2{minus}{delta}} catalyst  

SciTech Connect (OSTI)

Ce{sub 1{minus}x}Cu{sub x}O{sub 2{minus}{delta}} catalysts with 0.05 < x < 0.20 for catalytic wet oxidation of phenol in aqueous solutions have been synthesized using the coprecipitation method. The three most important synthesis parameters, the concentration of the mixed metal salt solution, the rate of coprecipitant addition and the stirrer speed during coprecipitation, were optimized with central composite design using the catalytic activity as a response function. The catalytic activity strongly depends on stirrer speed during coprecipitation. A high mutual dispersion of copper oxide and ceria, having the average crystallite size of about 9 nm, enhances solid solution formation. The unit cell parameter of ceria decreases when the overall concentration of copper in the catalyst increases, most probably obeying Vegard`s law. The catalysts proved to be very stable in hydrothermal reaction conditions at low pH values. After 5 h of reaction in the semibatch CST reactor less than 100 ppm of Cu was leached out of catalyst samples that were calcined in a flow of air for 2 h above 1033 K, and only a very low quantity of carbonaceous deposits were formed on the surface of the catalysts (0.6 wt%). The kinetics of phenol degradation could be interpreted by an equation valid for homogeneous autocatalytic reactions, in which the rate constant depends linearly on the heterogeneous catalyst (Cu) concentrations. This demonstrates that the reaction proceeds through a heterogeneous-homogeneous radical-branched chain mechanism.

Hocevar, S.; Batista, J. [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering] [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering; Levec, J. [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering] [National Inst. of Chemistry, Ljubljana (Slovenia). Lab. of Catalysis and Chemical Reaction Engineering; [Univ. of Ljubljana (Slovenia). Dept. of Chemical Engineering

1999-05-15T23:59:59.000Z

358

Introduction of Artificial Pinning Center into PLD-YBCO Coated Conductor on IBAD and Self-Epitaxial CeO2 Buffered Metal Substrate  

SciTech Connect (OSTI)

In order to fabricate YBa2Cu3O7-x (YBCO) coated conductors with high critical current density Jc in magnetic fields, we fabricated YBCO coated conductors with artificial pinning centers by the pulsed laser deposition (PLD) method on a self epitaxial PLD-CeO2 layer and ion-beam assisted deposition (IBAD)-Gd2Zr2O7 (GZO) buffered Hastelloy tape. Artificial pinning centers were introduced by the PLD deposition using the yttria-stabilized zirconia (YSZ) oxide target (nano-dot method) and YBCO target including YSZ particles (mixed target method). In the experiments using YSZ oxide target, YSZ nano-dots were observed. They were approximately 15 nm in height and 10 nm to 70 nm in diameter. We found that the density of nano-dots was controlled by the number of laser pulses. These samples exhibited higher Jc than YBCO films in magnetic fields. Furthermore, a similar improvement of Jc was observed in the experiments using YBCO target including YSZ particles. TEM observation revealed that columnar nano-structure made of BaZrO3 was formed during YBCO deposition and it was effective for pinning. We call this new epitaxial nano-structure 'bamboo structure' from its anisotropic growth and morphology.

Kobayashi, H.; Yamada, Y.; Ishida, S.; Takahashi, K.; Konishi, M.; Ibi, A.; Miyata, S. [Superconductivity Research Laboratory, ISTEC, 2-4-1 Mutsuno, Atsuta-ku, Nagoya, 456-8587 (Japan); Kato, T.; Hirayama, T. [Materials R and D Laboratory, Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta-ku, Nagoya 456-8587 (Japan); Shiohara, Y. [Superconductivity Research Laboratory, ISTEC, 1-10-13 Shinonome, Koto-ku, Tokyo 135-0062 (Japan)

2006-03-31T23:59:59.000Z

359

Quantum Critical Fluctuations in the Heavy fermion compound Ce(Ni0.935Pd0.065)2Ge2  

SciTech Connect (OSTI)

Electric resistivity, specific heat, magnetic susceptibility, and inelastic neutron scattering experi- ments were performed on a single crystal of the heavy fermion compound Ce(Ni0.935Pd0.065)2Ge2 in order to study the spin fluctuations near an antiferromagnetic (AF) quantum critical point (QCP). The resistivity and the specific heat coefficient for T = 1 K exhibit the power law behavior expected for a 3D itinerant AF QCP (?(T) ~ T^3/2 and ?(T) ~ ?0 -bT^1/2). However, for 2 = T = 10 K, the susceptibility and specific heat vary as logT and the resistivity varies linearly with temperature. Furthermore, despite the fact that the resistivity and specific heat exhibit the non-Fermi liquid behavior expected at a QCP, the correlation length, correlation time, and staggered susceptibility of the spin fluctuations remain finite at low temperature. We suggest that these deviations from the divergent behavior expected for a QCP may result from alloy disorder.

C. H. Wang; L. Poudel; A. E. Taylor; J. M. Lawrence; A. D. Christianson; S. Chang; J. A. Rodriguez-Rivera; J. W. Lynn; A. A. Podlesnyak; G. Ehlers; R. E. Baumbach; E. D. Bauer; K. Gofryk; F. Ronning; K. J. McClellan; J. D. Thompson

2014-12-01T23:59:59.000Z

360

An In-Situ XAS Study of the Structural Changes in a CuO-CeO2/Al2O3 Catalyst during Total Oxidation of Propane  

SciTech Connect (OSTI)

A CuOx-CeOx/Al2O3 catalyst was studied with in-situ transmission Cu K XAS for the total oxidation of propane as model reaction for the catalytic elimination of volatile organic compounds. The local Cu structure was determined for the catalyst as such, after pre-oxidation and after reduction with propane. The catalyst as such has a local CuO structure. No structural effect was observed upon heating in He up to 600 deg. C or after pre-oxidation at 150 deg. C. A full reduction of the Cu2+ towards metallic Cu0 occurred, when propane was fed to the catalyst. The change in local Cu structure during propane reduction was followed with a time resolution of 1 min. The {chi}(k) scans appeared as linear combinations of start and end spectra, CuO and Cu structure, respectively. However, careful examination of the XANES edge spectra indicates the presence of a small amount of additional Cu1+ species.

Silversmith, Geert; Poelman, Hilde; Poelman, Dirk; Gryse, Roger de [Ghent University, Department of Solid State Sciences, Krijgslaan 281 S1, B-9000 Gent (Belgium); Olea, Maria; Balcaen, Veerle; Heynderickx, Philippe; Marin, Guy B. [Ghent University, Laboratorium voor Petrochemische Techniek, Krijgslaan 281 S5, B-9000 Gent (Belgium)

2007-02-02T23:59:59.000Z

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Effects of flux additives on the characteristics of Y{sub 2.95}Al{sub 5}O{sub 12}:0.05Ce{sup 3+} phosphor: Particle growth mechanism and luminescence  

SciTech Connect (OSTI)

The dependence of the amount of the BaF{sub 2} flux additive on the luminescence of Y{sub 2.95}Al{sub 5}O{sub 12}:0.05Ce{sup 3+} phosphors was investigated. The integrated emission intensity of Y{sub 2.95}Al{sub 5}O{sub 12}:0.05Ce{sup 3+} prepared without the flux was enhanced by 29% with the addition of BaF{sub 2} flux at the optimum amount of 6?wt. %. Such an enhancement can be attributed to the purer phase of Y{sub 3}Al{sub 5}O{sub 12} and the morphology change from the irregular shape to spherical shape with the smoother surface due to the flux. The morphology and luminescence of Y{sub 2.95}Al{sub 5}O{sub 12}:0.05Ce{sup 3+} prepared with the 6?wt. % BaF{sub 2} flux additive (Sample II) were further compared with those of Y{sub 2.95}Al{sub 5}O{sub 12}:0.05Ce{sup 3+} prepared with the 7?wt. % H{sub 3}BO{sub 3} flux additive (Sample I). The particle size, particle shape, and integrated emission intensity (?{sub ex}?=?450?nm) of the former were found to be larger, more regular, and 6% higher than those of the latter. The difference in the morphology of Samples I and II, which led to the difference in the emission intensity and the external quantum efficiency, were well explained by the particle growth mechanism.

Chiang, Chung-Hao; Liu, Te-Hsing; Lin, Han-Yu; Kuo, Hung-Yi [Department of Electrical Engineering, National Cheng Kung University, Tainan 701, Taiwan (China); Chu, Sheng-Yuan, E-mail: chusy@mail.ncku.edu.tw [Department of Electrical Engineering, National Cheng Kung University, Tainan 701, Taiwan (China); Center for Micro/Nano Science and Technology, National Cheng Kung University, Tainan 701, Taiwan (China)

2013-12-28T23:59:59.000Z

362

Probing local structure in the yellow phosphor LaSr[subscript 2]AlO[subscript 5]:Ce[superscript 3+], by the maximum entropy method and pair distribution function analysis  

SciTech Connect (OSTI)

The compound LaSr{sub 2}AlO{sub 5} was recently introduced as a competitive Ce{sup 3+} host material for blue-pumped yellow phosphors for use in white light emitting diodes. A crucial feature of the crystal structure of LaSr{sub 2}AlO{sub 5} is that La, which is the host site for Ce{sup 3+}, is located in the 8h positions of the I4/mcm crystal structure, a site equally shared with Sr. While the average crystal structure of LaSr{sub 2}AlO{sub 5} as revealed by Rietveld analysis of laboratory and synchrotron X-ray diffraction data suggests nothing untoward, maximum entropy method analysis of the synchrotron X-ray data reveals the existence of conspicuous non-sphericity of the electron density. Pair distribution function analysis of the data suggests that despite their occupying the same crystallographic site, La and Sr possess distinct coordination environments, and the environment around La is more compact and regular than the environment suggested by the Rietveld refinement of the average structure. The absorption and emission from Ce{sup 3+} centers is controlled by the local coordination and symmetry, and the use of powerful new tools in unraveling details of these strengthens the rational search for new phosphors for solid state white lighting.

Im, Won Bin; Page, Katharine; DenBaars, Steven P.; Seshadri, Ram (UCSB); (LANL)

2011-08-04T23:59:59.000Z

363

Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and NMe2 byMonomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism  

SciTech Connect (OSTI)

The reaction between [1,2,4-(Me3C)3C5H2]2CeH, referred to as Cp'2CeH, andCH3X where X is Cl, Br, I, OMe and NMe2, are described. The reactions fall intothree distinct classes. Class a, where X = Cl, Br and I rapidly form Cp'2CeX and CH4without formation of identifiable intermediates in the 1H NMR spectra. Class b, whereX = OMe proceeds rapidly to Cp'2Ce(eta2-CH2OMe) and H2 and then to Cp'2CeOMeand CH4. The methoxymethyl derivative is sufficiently stable to be isolated andcharacterized and it is rapidly converted to Cp'2CeOMe in presence of BPh3. Class c,where X = NMe2 does not result in formation of Cp'2CeNMe2, but deuterium labelingexperiments show that H for D exchange occurs in NMe3. Density functionalcalculations DFT(B3PW91) on the reaction of (C5H5)2CeH, referred to as Cp2CeH,and CH3X show that the barrier for alpha-CH activation, resulting in formation ofCp2Ce(eta2-CH2X), proceeds with a relatively low activation barrier (DeltaG++) but thesubsequent ejection of CH2 and trapping by H2 has a higher barrier; the height of thesecond barrier lies in the order F, Cl, Br, I< OMe<< NMe2, consistent with theexperimental studies. The DFT calculations also show that the two-step reaction,which proceeds through a carbenoid intermediate, has a lower barrier than a directone-step sigma bond metathesis mechanism. The reaction of Cp2CeCH2OMe and BPh3 is calculated to be a low barrier process and the ylide, CH2(+)BPh3(-), is a transition state and not an intermediate.

Werkema, Evan; Andersen, Richard; Yahia, Ahmed; Maron, Laurent; Eisenstein, Odile

2009-05-15T23:59:59.000Z

364

A Brief Review of Past INL Work Assessing Radionuclide Content in TMI-2 Melted Fuel Debris: The Use of 144Ce as a Surrogate for Pu Accountancy  

SciTech Connect (OSTI)

This report serves as a literature review of prior work performed at Idaho National Laboratory, and its predecessor organizations Idaho National Engineering Laboratory (INEL) and Idaho National Engineering and Environmental Laboratory (INEEL), studying radionuclide partitioning within the melted fuel debris of the reactor of the Three Mile Island 2 (TMI-2) nuclear power plant. The purpose of this review is to document prior published work that provides supporting evidence of the utility of using 144Ce as a surrogate for plutonium within melted fuel debris. When the TMI-2 accident occurred no quantitative nondestructive analysis (NDA) techniques existed that could assay plutonium in the unconventional wastes from the reactor. However, unpublished work performed at INL by D. W. Akers in the late 1980s through the 1990s demonstrated that passive gamma-ray spectrometry of 144Ce could potentially be used to develop a semi-quantitative correlation for estimating plutonium content in these materials. The fate and transport of radioisotopes in fuel from different regions of the core, including uranium, fission products, and actinides, appear to be well characterized based on the maximum temperature reached by fuel in different parts of the core and the melting point, boiling point, and volatility of those radioisotopes. Also, the chemical interactions between fuel, fuel cladding, control elements, and core structural components appears to have played a large role in determining when and how fuel relocation occurred in the core; perhaps the most important of these reaction appears to be related to the formation of mixed-material alloys, eutectics, in the fuel cladding. Because of its high melting point, low volatility, and similar chemical behavior to plutonium, the element cerium appears to have behaved similarly to plutonium during the evolution of the TMI-2 accident. Anecdotal evidence extrapolated from open-source literature strengthens this logical feasibility for using cerium, which is rather easy to analyze using passive nondestructive analysis gamma-ray spectrometry, as a surrogate for plutonium in the final analysis of TMI-2 melted fuel debris. The generation of this report is motivated by the need to perform nuclear material accountancy measurements on the melted fuel debris that will be excavated from the damaged nuclear reactors at the Fukushima Daiichi nuclear power plant in Japan, which were destroyed by the Tohoku earthquake and tsunami on March 11, 2011. Lessons may be taken from prior U.S. work related to the study of the TMI-2 core debris to support the development of new assay methods for use at Fukushima Daiichi. While significant differences exist between the two reactor systems (pressurized water reactor (TMI-2) versus boiling water reactor (FD), fresh water post-accident cooing (TMI-2) versus salt water (FD), maintained containment (TMI-2) versus loss of containment (FD)) there remain sufficient similarities to motivate these comparisons.

D. L. Chichester; S. J. Thompson

2013-09-01T23:59:59.000Z

365

civil & environmental (CE) CE / ENE overview programs available  

E-Print Network [OSTI]

: transportation systems, water supply and waste disposal systems, and industrial and commercial structures. They face the challenges of replacing our nation's aging infrastructure -- highways, bridges, wharf

Rohs, Remo

366

Amerikooler: Order (2013-CE-5307)  

Broader source: Energy.gov [DOE]

DOE ordered Amerikooler, Inc. to pay a $8,000 civil penalty after finding Amerikooler had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

367

Trastar: Order (2013-CE-49003)  

Broader source: Energy.gov [DOE]

DOE ordered Trastar Inc. to pay a $8,000 civil penalty after finding Trastar had failed to certify that certain basic models of traffic signal modules and pedestrian modules comply with the applicable energy conservation standards.

368

Keystone: Order (2013-CE-2601)  

Broader source: Energy.gov [DOE]

DOE ordered Keystone Technologies, LLC to pay a $8,000 civil penalty after finding Keystone had failed to certify that certain models of fluorescent lamp ballasts comply with the applicable energy conservation standards.

369

Trojan: Order (2011-CE-2704)  

Broader source: Energy.gov [DOE]

DOE ordered Trojan, Inc. to pay a $6,000 civil penalty after finding Trojan had failed to certify that certain models of incandescent reflector lamps comply with the applicable energy conservation standards.

370

Versonel: Order (2014-CE-21009)  

Broader source: Energy.gov [DOE]

DOE ordered Smart Surplus, Inc. d/b/a Versonel to pay a $8,000 civil penalty after finding Versonel had failed to certify that certain models of refrigerators and residential clothes dryers comply with the applicable energy conservation standards.

371

Dacor: Order (2014-CE-23010)  

Broader source: Energy.gov [DOE]

DOE ordered Dacor to pay a $8,000 civil penalty after finding Dacor had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

372

Northland: Order (2014-CE-23002)  

Broader source: Energy.gov [DOE]

DOE ordered Northland Corporation d/b/a AGA Marvel to pay a $16,000 civil penalty after finding Northland had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

373

NCBECS C&E 1979  

U.S. Energy Information Administration (EIA) Indexed Site

9. Distribution of Commercial Buildings Supplied with Fuel Oil, by Number of Tanks, Tank CapaciLy, and Inventory, as of January 1, 1980 (Thousands of Buildings)...

374

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Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
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381

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386

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387

Long-range ordering of reduced magnetic moments in the spin-gap compound CeOs{sub 2}Al{sub 10} as seen via muon spin relaxation and neutron scattering  

SciTech Connect (OSTI)

We have carried out neutron diffraction, muon spin relaxation ({mu}SR), and inelastic neutron scattering (INS) investigations on a polycrystalline sample of CeOs{sub 2}Al{sub 10} to investigate the nature of the phase transition observed near 29 K in the resistivity and heat capacity. Our {mu}SR data clearly reveal coherent frequency oscillations below 28 K, indicating the presence of an internal field at the muon site, which confirms the long-range magnetic ordering of the Ce moment below 28 K. Upon cooling the sample below 15 K, unusual behavior of the temperature-dependent {mu}SR frequencies may indicate either a change in the muon site, consistent with the observation of superstructure reflections in electron diffraction, or a change in the ordered magnetic structure. Neutron diffraction data do not reveal any clear sign of either magnetic Bragg peaks or superlattice reflections. Furthermore, INS measurements clearly reveal the presence of a sharp inelastic excitation near 11 meV between 5 and 26 K, due to opening of a gap in the spin-excitation spectrum, which transforms into a broad response at and above 30 K. The magnitude of the spin gap (11 meV) as derived from the INS peak position agrees very well with the gap value as estimated from the bulk properties.

Adroja, D. T.; Hillier, A. D.; Kockelmann, W. A.; Anand, V. K.; Stewart, J. R.; Taylor, J. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot Oxon OX11 0QX (United Kingdom); Deen, P. P. [Institute Laue-Langevin, BP 156, 6 Rue Jules Horowitz, 38042 Grenoble Cedex (France); Strydom, A. M. [Physics Department, University of Johannesburg, P.O. Box 524, Auckland Park 2006 (South Africa); Muro, Y.; Kajino, J.; Takabatake, T. [Department of Quantum Matter, ADSM, and IAMR, Hiroshima University, Higashi-Hiroshima 739-8530 (Japan)

2010-09-01T23:59:59.000Z

388

Performance of Ni/ScSZ cermet anode modified by coating with Gd{sub 0.2}Ce{sub 0.8}O{sub 2} for a SOFC  

SciTech Connect (OSTI)

A Ni/scandia-stabilized zirconia (ScSZ) cermet anode was modified by coating with nano-sized gadolinium-doped ceria (GDC, Gd{sub 0.2}Ce{sub 0.8}O{sub 2}) within the pores of the anode for a solid oxide fuel cell (SOFC). X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed in the anode characterizations. Open circuit voltages (OCVs) increased from 1.027 to 1.078 V, and the maximum power densities increased from 238 to 825 mW/cm{sup 2}, as the operating temperature of a SOFC with 2.0 wt.%GDC-coated Ni/ScSZ anode was increased from 700 to 850 deg. C in humidified hydrogen. The coating of nano-sized Gd{sub 0.2}Ce{sub 0.8}O{sub 2} particle within the pores of the porous Ni/ScSZ anode significantly improved the performance of anode supported cell. Electrochemical impedance spectra (EIS) illustrated that the cell with Ni/ScSZ anode exhibited far greater impedances than the cell with 2.0 wt.%GDC-coated Ni/ScSZ anode. Consequently, 2.0 wt.%GDC-coated Ni/ScSZ anode could be used as a novel anode material for a SOFC due to better electrochemical performance.

Huang Bo [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China)]. E-mail: huangbo2k@hotmail.com; Ye, X.F. [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China); Wang, S.R. [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China); Nie, H.W. [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China); Liu, R.Z. [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China); Wen, T.L. [Shanghai Institute of Ceramics, Chinese Academy of Sciences (SICCAS), 1295 Dingxi Road, Shanghai 200050 (China)

2007-09-04T23:59:59.000Z

389

Combined effect of chemical pressure and valence electron concentration through the electron-deficient Li substitution on the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system  

SciTech Connect (OSTI)

Four members of the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system have been prepared by high-temperature reaction method and characterized by X-ray diffractions. All compounds crystallize in the orthorhombic Gd{sub 5}Si{sub 4}-type structure (space group Pnma, Pearson code oP16) with bonding interactions for interslab Ge{sub 2} dimers. The Li substitution for rare-earth elements in the RE{sub 4}LiGe{sub 4} system leads to a combined effect of the increased chemical pressure and the decreased valance electron concentration (VEC), which eventually results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type with all broken interslab Ge–Ge bond for the parental RE{sub 5}Ge{sub 4} to the Gd{sub 5}Si{sub 4}-type structure for the ternary RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. Site-preference between rare-earth metals and Li is proven to generate energetically the most favorable atomic arrangements according to coloring-problem, and the rationale is provided using both the size-factor and the electronic-factor related, respectively, to site-volume and electronegativity as well as QVAL values. Tight-binding, linear-muffin-tin-orbital (TB-LMTO) calculations are performed to investigate electronic densities of states (DOS) and crystal orbital Hamilton population (COHP) curves. The influence of reduced VEC for chemical bonding including the formation of interslab Ge{sub 2} dimers is also discussed. The magnetic property measurements prove that the non-magnetic Li substitution leads to the ferromagnetic (FM)-like ground state for Ce{sub 4}LiGe{sub 4} and the co-existence of antiferromagntic (AFM) and FM ground states for Sm{sub 4}LiGe{sub 4}. - Graphical abstract: Reported is a combined effect of the chemical pressure and the reduced VEC caused by the smaller monovalent non-magnetic Li substitution for the larger trivalent magnetic rare-earth metals in the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. This results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type to the Gd{sub 5}Si{sub 4}-type structure and the changes in magnetic properties. Display Omitted - Highlights: • Four Li-containing intermetallic compounds RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr and Sm) were synthesized. • The combined effect of the chemical pressure and the reduced VEC caused by Li substitution for a rare-earth metal results in the structure transformation. • Electronic structures and magnetic properties of title compounds were thoroughly investigated.

Nam, Gnu; Jeon, Jieun; Kim, Youngjo [Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763 (Korea, Republic of); Kwon Kang, Sung [Department of Chemistry, Chungnam National University, Daejeon, Chungnam 305-764 (Korea, Republic of); Ahn, Kyunghan [Advanced Materials Research Center, Samsung Advanced Institute of Technology, Yongin-si, Gyeonggi-do 446-712 (Korea, Republic of); You, Tae-Soo, E-mail: tsyou@chungbuk.ac.kr [Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763 (Korea, Republic of)

2013-09-15T23:59:59.000Z

390

A comparative study of SrO and BaO doping to CeO{sub 2}-ZrO{sub 2}: Characteristic and its catalytic performance for three-way catalysts  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? The prepared materials have a face-centered cubic structure and nanosize particles. ?Comparing to CZB, aged CZS has 494 ?mol/g of OSC and 30 m{sup 2}/g of surface area. ? CZS and CZB have similar NO sorption and reductive properties and different H{sub 2} uptake. ? T{sub 50} of Pt-Rh/CZS/LA is as low as 199 °C for CO, 228 °C for NO, and 252 °C for C{sub 3}H{sub 8}. ? Pt-Rh/CZS/LA has wider working-window at 320 °C under different ? value. -- Abstract: Ceria-zirconia-strontia (Ce{sub 0.35}Zr{sub 0.55}Sr{sub 0.10}O{sub 1.9}) and ceria-zirconia-baria (Ce{sub 0.35}Zr{sub 0.55}Ba{sub 0.10}O{sub 1.9}) were synthesized using an oxidation-co-precipitation method with hydrogen peroxide (H{sub 2}O{sub 2}) as oxidant. The physical and chemical properties of the prepared materials were investigated using Brunauer–Emmett–Teller surface area characterization, transmission electron microscopy, X-ray diffraction, Raman spectra, X-ray photoelectron spectroscopy, and oxygen pulse reaction. The prepared materials were used in preparing three-way catalysts with low Pt and Rh content. Moreover, catalytic activities were evaluated at a fixed bed under a simulated gaseous mixture. The results are as follows: (1) the prepared materials have a face-centered cubic structure and are nano-sized; (2) aged Ce{sub 0.35}Zr{sub 0.55}Sr{sub 0.10}O{sub 1.9} has higher oxygen storage capacity (494 ?mol/g), better thermal stability (30 m{sup 2}/g), good low-temperature reducibility, and high hydrogen uptake after TPR-redox cycles; (3) the light-off temperature (T{sub 50}) of Pt-Rh/CZS/LA can be as low as 199 °C for CO, 228 °C for NO, and 252 °C for C{sub 3}H{sub 8}; and (4) Pt-Rh/CZS/LA has a fairly wide working-window.

Guo, Jiaxiu, E-mail: guojiaxiu@scu.edu.cn [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China) [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China); National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065 (China); Shi, Zhonghua, E-mail: shizhonghua@scu.edu.cn [College of Chemistry, Sichuan University, Chengdu 610064 (China)] [College of Chemistry, Sichuan University, Chengdu 610064 (China); Wu, Dongdong [College of Chemistry, Sichuan University, Chengdu 610064 (China)] [College of Chemistry, Sichuan University, Chengdu 610064 (China); Yin, Huaqiang [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China) [College of Architecture and Environment, Sichuan University, Chengdu 610065 (China); National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065 (China); Gong, Maochu [College of Chemistry, Sichuan University, Chengdu 610064 (China)] [College of Chemistry, Sichuan University, Chengdu 610064 (China); Chen, Yaoqiang [College of Chemistry, Sichuan University, Chengdu 610064 (China) [College of Chemistry, Sichuan University, Chengdu 610064 (China); National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065 (China)

2013-02-15T23:59:59.000Z

391

Structural, microstructural and surface properties of a specific CeO{sub 2}-Bi{sub 2}O{sub 3} multiphase system obtained at 600 {sup o}C  

SciTech Connect (OSTI)

Polycrystalline samples of (1-x) CeO{sub 2}-x/2 Bi{sub 2}O{sub 3} phases, where x is the atom fraction of bismuth have been synthesized by the precipitation process and after the thermal treatment at 600 {sup o}C, under air. Samples are first characterized by the X-ray diffraction and scanning electron microscopy. To determine the samples specific surface areas, Brunauer-Emmett-Teller (BET) analyses have been performed. In the composition range 0{<=}x{<=}0.20, a cubic solid solution with fluorite structure is obtained. For compositions x comprised between 0.30 and 0.90, two types of T' (or {beta}') and T (or {beta}) tetragonal phases, similar to the well-known {beta}' or {beta} Bi{sub 2}O{sub 3} metastable structural varieties, are observed. However, the crystal cell volumes of these {beta}' or {beta} Bi{sub 2}O{sub 3} phases increase with the composition x in bismuth: this might be due to the presence of defects or substitution by cerium atoms, in the tetragonal lattices. Using X-ray diffraction profile analyses, correlations between bismuth composition x and crystal sizes or lattice distortions have been established. The solid-gas interactions between these polycrystalline materials and air-CH{sub 4} and air-CO flows have been studied as a function of temperature and composition x, using Fourier transform infrared (FTIR) analyses of the conversions of CH{sub 4} and CO gases into the CO{sub 2} gas. The transformations of CH{sub 4} and CO molecules as a function of time and temperature are determined through the intensities of FTIR CO{sub 2} absorption bands. Using the specific surface areas determined from BET analyses, these FTIR intensities have been normalized and compared. For all bismuth compositions, a low catalytic reactivity is observed with air-CH{sub 4} gas flows, while, for the highest bismuth compositions, a high catalytic reactivity is observed with air-CO gas flows. -- Graphical abstract: Catalytic efficiencies of CeO{sub 2}-Bi{sub 2}O{sub 3}system: catalytic actions on methane (on the left) or carbon monoxide (on the right) of (1-x)CeO{sub 2}-x/2 Bi{sub 2}O{sub 3} samples, as a function of the fraction x, and for fixed temperatures: on the vertical axis, the intensities of CO{sub 2} FTIR absorption bands are reported. Strong efficiency of bismuth rich samples for CO conversion. Display Omitted Research highlights: {yields} Stabilization of metastable polymorph Bi{sub 2}O{sub 3} phases in the mix system [(1-x)CeO{sub 2}+(x/2)Bi{sub 2}O{sub 3}] at 600 {sup o}C. {yields} Solid gas interactions between this system and air-CO or air-CH{sub 4} gas flows at various temperatures and bismuth compositions. {yields} High efficiency of bismuth rich samples to convert CO into CO{sub 2}.

Bourja, Lamia; Bakiz, Bahcine [Institut Materiaux Microelectronique et Nanosciences de Provence, IM2NP, UMR CNRS 6242, Universite du Sud Toulon-Var, BP 20132, 83957 La Garde Cedex (France); Laboratoire Materiaux et Environnement LME, Faculte des Sciences, Universite Ibn Zohr, BP 8106, Cite Dakhla, Agadir, Maroc (Morocco); Benlhachemi, Abdeljalil; Ezahri, Mohamed [Laboratoire Materiaux et Environnement LME, Faculte des Sciences, Universite Ibn Zohr, BP 8106, Cite Dakhla, Agadir, Maroc (Morocco); Villain, Sylvie [Institut Materiaux Microelectronique et Nanosciences de Provence, IM2NP, UMR CNRS 6242, Universite du Sud Toulon-Var, BP 20132, 83957 La Garde Cedex (France); Crosnier, Olivier [Laboratoire de Genie des Materiaux et Procedes Associes, Polytech Nantes, rue Christian Pauc BP 50609, 44306 Nantes Cedex 3 (France); Favotto, Claude [Institut Materiaux Microelectronique et Nanosciences de Provence, IM2NP, UMR CNRS 6242, Universite du Sud Toulon-Var, BP 20132, 83957 La Garde Cedex (France); Gavarri, Jean-Raymond, E-mail: gavarri.jr@univ-tln.f [Institut Materiaux Microelectronique et Nanosciences de Provence, IM2NP, UMR CNRS 6242, Universite du Sud Toulon-Var, BP 20132, 83957 La Garde Cedex (France)

2011-03-15T23:59:59.000Z

392

Data:Ccd78ce0-41e2-428c-a5a4-27f7cc54aea7 | Open Energy Information  

Open Energy Info (EERE)

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393

S T U D EN T A ND EN R OLM EN T S ER V I CE S DI V IS IO N In order to assist departments and colleges with their planning cycle for 2014-15 and beyond,  

E-Print Network [OSTI]

Page | 1 S T U D EN T A ND EN R OLM EN T S ER V I CE S DI V IS IO N In order to assist departments: Key Dates and Deadlines for 2014-15 DATE: March 28, 2014 #12;Page | 2 S T U D EN T A ND EN R OLM EN

Saskatchewan, University of

394

New orthorhombic derivative of CaCu{sub 5}-type structure: RNi{sub 4}Si compounds (R=Y, La, Ce, Sm, Gd–Ho), crystal structure and some magnetic properties  

SciTech Connect (OSTI)

The crystal structure of new YNi{sub 4}Si-type RNi{sub 4}Si (R=Y, La, Ce, Sm, Gd–Ho) compounds has been established using powder X-ray diffraction. The YNi{sub 4}Si structure is a new structure type, which is orthorhombic derivative of CaCu{sub 5}-type structure (space group Cmmm N 65, oC12). GdNi{sub 4}Si and DyNi{sub 4}Si compounds order ferromagnetically at 25 and 19 K, respectively whereas YNi{sub 4}Si shows antiferromagnetic nature. At 15 K, DyNi{sub 4}Si shows second antiferromagnetic-like transition. The magnetic moment of GdNi{sub 4}Si at 5 K in 50 kOe field is ?7.2 ?{sub B}/f.u. suggesting a completely ordered ferromagnetic state. The magnetocaloric effect of GdNi{sub 4}Si is calculated in terms of isothermal magnetic entropy change and it reaches the maximum value of ?12.8 J/kg K for a field change of 50 kOe near T{sub C} ?25 K. - Graphical abstract: The RNi{sub 4}Si (R=Y, La, Ce, Sm, Gd–Ho) compounds crystallize in new YNi{sub 4}Si-type structure which is orthorhombic derivative of the basic CaCu{sub 5}-type structure. GdNi{sub 4}Si and DyNi{sub 4}Si compounds show the ferromagnetic-like ordering, whereas.YNi{sub 4}Si has the antiferromagnetic nature. The GdNi{sub 4}Si demonstrates the big magnetocaloric effect near temperature of ferromagnetic ordering. The relationship between initial CaCu{sub 5}-type DyNi{sub 5} and YNi{sub 4}Si-type DyNi{sub 4}Si lattices.

Morozkin, A.V., E-mail: morozkin@general.chem.msu.ru [Department of Chemistry, Moscow State University, Leninskie Gory, House 1, Building 3, GSP-2, Moscow 119992 (Russian Federation); Knotko, A.V. [Department of Chemistry, Moscow State University, Leninskie Gory, House 1, Building 3, GSP-2, Moscow 119992 (Russian Federation); Yapaskurt, V.O. [Department of Petrology, Geological Faculty, Moscow State University, Leninskie Gory, Moscow 119992 (Russian Federation); Yuan, Fang; Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1 (Canada); Nirmala, R. [Indian Institute of Technology Madras, Chennai 600036 (India)

2013-12-15T23:59:59.000Z

395

File:Texas NOI for Storm Water Discharges Associated with Construction...  

Open Energy Info (EERE)

title environmental protection Author Janet Wyman Storm Water and Pretreatment Team Wastewater Permitting Section Water Quality Division TCEQ Texas Commission on Environmental...

396

File:Notice of Termination for Authorization under TPDES General...  

Open Energy Info (EERE)

reflect the modified file. Author Janet Wyman Storm Water and Pretreatment Team Wastewater Permitting Section Water Quality Division TCEQ Texas Commission on Environmental...

397

The influence of auxiliary codopants on persistent phosphor Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},R{sup 3+} (R = Y, La, Ce, Gd, Tb and Lu)  

SciTech Connect (OSTI)

Graphical abstract: Rare earth ions which close to the line are good codopants. - Highlights: • The persistent luminescence in Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},R{sup 3+} was reported. • Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},Lu{sup 3+} shows the best performance. • The influence of auxiliary codopants was discussed in terms of ionic potential and ionic radius. - Abstract: We investigate the persistent luminescence in europium-doped strontium pyrophosphate upon codoping with auxiliary rare earth ions. The persistent phosphors are synthesized via solid-state reaction method under flowing N{sub 2} + H{sub 2}. Under UV irradiation, broadband emission persistent luminescence located at 420 nm is observed in all of these phosphors at room temperature. The effects of auxiliary rare earth ions on Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+} are discussed according to the decay curves and thermoluminescence spectra. Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},Lu{sup 3+} shows the best performance, while and La{sup 3+} and Ce{sup 3+} codoped samples are the weakest. The influence of auxiliary codopants is discussed in terms of ionic potential and ionic radius. We derive an empirical formula based on the experimental results.

Ju, Guifang; Hu, Yihua, E-mail: huyh@gdut.edu.cn; Chen, Li; Wang, Xiaojuan; Mu, Zhongfei

2013-11-15T23:59:59.000Z

398

Anode-supported tubular SOFCs based on BaZr0.1Ce0.7Y0.1Yb0.1O3?? electrolyte fabricated by dip coating  

SciTech Connect (OSTI)

Anode-supported tubular solid oxide fuel cells (SOFCs) based on a proton and oxide ion mixed conductor, BaZr{sub 0.1}Ce{sub 0.7}Y{sub 0.1}Yb{sub 0.1}O{sub 3 ? ?} (BZCYYb), have been fabricated using a dip coating and co-firing process. This new fabrication technique effectively reduced the Ohmic resistances of tubular cells to ~ 0.1 and ~ 0.3 ? cm{sup 2} at 750 and 600 °C, respectively. Typical tubular cells with Ni-BZCYYb anode, BZCYYb electrolyte, and La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3 ? ?} (LSCF)-BZCYYb composite cathode demonstrated much-improved performance, achieving peak power densities of 1.13, 0.81, 0.63, and 0.53 W cm{sup ? 2} at 750, 700, 650, and 600 °C, respectively, when humidified (3 v% water vapor) hydrogen was used as fuel and ambient air as oxidant.

Chen, Changcheng; Liu, Mingfei; Bai, Yaohui; Yang, Lei; Xie, Erqing; Liu, Meilin

2011-01-01T23:59:59.000Z

399

Synthesis and characterization of (CeO{sub 2}){sub 0.8}(SmO{sub 1.5}){sub 0.2} thin films from polymeric precursors  

SciTech Connect (OSTI)

(CeO{sub 2}){sub 0.8}(SmO{sub 1.5}){sub 0.2}(CSO) has been suggested for solid oxide fuel cell (SOFC) applications, because of its higher electrical conductivity and chemical stability, compared to other ceria-based materials. However, CSO is difficult to densify under conditions compatible with other SOFC components. A thin film synthesis technique has been developed for the fabrication of dense CSO films from precursor solutions at relatively low temperatures. Dense, smooth, and homogeneous films were obtained on Pt, single-crystal Si, and La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF) substrates by spin-coating a polymeric precursor and subsequent heat-treatment. Crystallization of the film occurred at temperatures as low as 320 C. The developed oxide film did not react with La{sub 0.8}Sr{sub 0.2}MnO{sub 3}, LSCF, or (ZrO{sub 2}){sub 0.84}(YO{sub .15}){sub 0.16}(YSZ) at temperatures up to 1,200 C. When a CSO layer was applied between LSCF and YSZ, a significant improvement in the interfacial resistance was observed. The results suggest that CSO can be used as a buffer layer on YSZ electrolytes for improved performance of high temperature SOFCs.

Chen, C.C.; Nasrallah, M.M.; Anderson, H.U. [Univ. of Missouri, Rolla, MO (United States). Dept. of Ceramic Engineering

1993-12-01T23:59:59.000Z

400

Thermal conductivity control by oxygen defect concentration modification in reducible oxides: The case of Pr{sub 0.1}Ce{sub 0.9}O{sub 2??} thin films  

SciTech Connect (OSTI)

We demonstrate the impact on thermal conductivity of varying the concentration of oxygen vacancies and reduced cations in Pr{sub 0.1}Ce{sub 0.9}O{sub 2??} thin films prepared by pulsed laser deposition. The oxygen vacancy concentration is controlled by varying the oxygen partial pressure between 1?×?10{sup ?4} and 1?atm at 650??°C. Corresponding changes in the oxygen non-stoichiometry (?) are monitored by detecting the lattice parameters of the films with high-resolution X-ray diffraction, while the thermal properties are characterized by time-domain thermoreflectance measurements. The films are shown to exhibit a variation in oxygen vacancy content, and in the Pr{sup 3+}/Pr{sup 4+} ratio, corresponding to changes in ? from 0.0027 to 0.0364, leading to a reduction in the thermal conductivity from k?=?6.62?±?0.61 to 3.82?±?0.51?W/m-K, respectively. These values agree well with those predicted by the Callaway and von Baeyer model for thermal conductivity in the presence of point imperfections. These results demonstrate the capability of controlling thermal conductivity via control of anion and cation defect concentrations in a given reducible oxide.

Luckyanova, Maria N.; Chen, Gang, E-mail: gchen2@mit.edu, E-mail: byildiz@mit.edu [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Chen, Di; Tuller, Harry L. [Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Ma, Wen; Yildiz, Bilge, E-mail: gchen2@mit.edu, E-mail: byildiz@mit.edu [Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2014-02-10T23:59:59.000Z

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


401

Frequency Characteristics of Foreign Accented Speech Levent M. Arslan \\Lambda and John H.L. Hansen  

E-Print Network [OSTI]

, Spanish, Italian, Hindi, Romanian, Japanese, Russian, and others. For the studies conducted here, we focus

402

DILEPTON SIGNATURE IN e{sup +}e{sup -}{yields}Hl{sup +}e{sup -}  

SciTech Connect (OSTI)

We calculate the lepton distribution in the reaction e{sup +} e{sup -} {yields} (Higgs boson) + (dilepton) mediated by a neutral gauge boson. Propagator effects favor a slow dilepton for which the study of the joint angular distribution of l{sup +} and l{sup -} is an attractive experimental possibility. This distribution is found to be a sensitive probe of the ZZH vertex.

Kelly, R. L.; Shimada, T.

1980-10-01T23:59:59.000Z

403

Measurements on HV-CMOS Active Sensors After Irradiation to HL-LHC fluences  

E-Print Network [OSTI]

During the long shutdown (LS) 3 beginning 2022 the LHC will be upgraded for higher luminosities pushing the limits especially for the inner tracking detectors of the LHC experiments. In order to cope with the increased particle rate and radiation levels the ATLAS Inner Detector will be completely replaced by a purely silicon based one. Novel sensors based on HV-CMOS processes prove to be good candidates in terms of spatial resolution and radiation hardness. In this paper measurements conducted on prototypes built in the AMS H18 HV-CMOS process and irradiated to fluences of up to $2\\cdot10^{16}\\,\\text{n}_\\text{eq}\\text{cm}^{-2}$ are presented.

B. Ristic; for the ATLAS CMOS pixel collaboration

2015-01-13T23:59:59.000Z

404

Session Variability Contrasts in the MARP Corpus Keith W. Godin, John H.L. Hansen  

E-Print Network [OSTI]

Speech Systems Univ. of Texas at Dallas, Richardson, TX, USA godin@ieee.org, john in this area. This frame- work is useful because it relates directly to the framework em- ployed for speaker through a subcontract to RADC Inc. under FA8750-09-C-0067,and partially by the University of Texas

Texas at Dallas, University of

405

Solar hydrogen production using Ce{sub 1-x}Li{sub x}O{sub 2-{delta}} solid solutions via a thermochemical, two-step water-splitting cycle  

SciTech Connect (OSTI)

The reactivity of Ce{sub 1-x}Li{sub x}O{sub 2-{delta}} (x=0.025, 0.05, 0.075 and 0.1) solid solutions during the redox and two-step water-splitting cycles has been investigated in this work. Thermogravimetric analysis (TGA), X-ray diffraction (XRD) patterns and field-emission scanning electron microscopy (FE-SEM) indicate that there are two reaction mechanisms in the O{sub 2}-releasing step and the shift in the reaction mechanisms occurs in the O{sub 2}-releasing step because of sintering at high temperatures, and a decrease in the concentration of lattice oxygen occurs as the O{sub 2}-releasing step proceeds. The reaction in the O{sub 2}-releasing step follows a second-order mechanism over a temperature range of 1000-1170 Degree-Sign C and a contracting-area model over a temperature range of 1170-1500 Degree-Sign C. According to direct gas mass spectroscopy (DGMS), ceria doped at 5 mol% Li exhibits the highest reactivity in the O{sub 2}-releasing step during both redox cycles in air and two-step water-splitting cycles, whereas ceria doped at 2.5 mol% Li yields the highest amount of hydrogen (4.79 ml/g) in the H{sub 2}-generation step during the two-step water-splitting cycles, which is higher than ceria doped with other metals. DGMS and electrochemical impedance spectroscopy (EIS) suggest that the average reaction rate in the H{sub 2}-generation step is influenced by the concentration of extrinsic oxygen vacancies, and thus, the reactivity in the H{sub 2}-generation step, to some degree, could be tuned by varying the concentration of extrinsic oxygen vacancies (Li content). - Graphical abstract: Average reduction fraction of Ce{sub 1-x}Li{sub x}O{sub 2-{delta}} (x=0.025, 0.05, 0.075 and 0.10) solid solutions versus Li content in the O{sub 2}-releasing step during the redox cycles in air and the two-step water-splitting cycles. Highlights: Black-Right-Pointing-Pointer We have investigated Li-doped ceria for hydrogen production using two-step water-splitting cycles. Black-Right-Pointing-Pointer The sintering effect on the reaction mechanisms was first clarified. Black-Right-Pointing-Pointer The shift of reaction mechanisms occurs during the O{sub 2}-releasing step. Black-Right-Pointing-Pointer The reaction-mechanism shift occurs because of sintering at high temperatures. Black-Right-Pointing-Pointer Doping at 2.5 mol% Li results in the highest H{sub 2} yield and cyclability for hydrogen production.

Meng, Qing-Long; Lee, Chong-il; Shigeta, Satoshi [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)] [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan); Kaneko, Hiroshi [Solutions Research Laboratory, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)] [Solutions Research Laboratory, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan); Tamaura, Yutaka, E-mail: ytamaura@chem.titech.ac.jp [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)] [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-Ku, Tokyo 1528850 (Japan)

2012-10-15T23:59:59.000Z

406

Synthesis, structural characterization and Mössbauer study of LnV{sub 0.5}Fe{sub 0.5}O{sub 3} perovskites (Ln = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er)  

SciTech Connect (OSTI)

Graphical abstract: Mössbauer spectra taken at 200 K for the Y(V{sub 0.5}Fe{sub 0.5})O{sub 3} orthoferrivanadate synthesized by arc-melting. Highlights: ? LnFe{sub 0.5}V{sub 0.5}O{sub 3} were synthesized by the first time for most of the rare-earth elements. ? These orthoferrivanadates crystallize metastably with the perovskite structure. ? Iron and vanadium are trivalent stabilized in these solid solutions. ? The Mössbauer quadrupolar splitting is correlated with the tolerance factor. ? Below 100 K, these perovskites undergo a crystallographic phase transformation. -- Abstract: Perovskites LnV{sub 0.5}Fe{sub 0.5}O{sub 3} (Ln = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er) were synthesized by rapid solidification from arc-melted samples and characterized by the study of their crystal structure and hyperfine properties. These metastable solid solutions crystallized in the Pbnm symmetry, with the iron and vanadium cations randomly distributed in the transition metal octahedral sites. Depending on the lanthanide present at the A site of the perovskite, iron is present with two valences (i.e., Fe{sup 3+} and Fe{sup 2+}). The volume of the unit cell for these perovskites increases linearly with the lanthanide ionic radius, as the perovskite approaches its ideal structure. At room temperature, the quadrupolar splitting of the trivalent paramagnetic Mössbauer component works as an indirect measurement for the Goldshmidt tolerance factor. Close to or below 100 K, these perovskites undergo a crystallographic phase transformation, probably due to orbital ordering of the V{sup 3+} cations, originating two different magnetic iron sites.

Ivashita, Flávio F.; Biondo, Valdecir; Bellini, Jusmar V.; Paesano, Andrea [Departamento de Física, Universidade Estadual de Maringá, Av. Colombo 5790, 87.020-900 Maringá, PR (Brazil)] [Departamento de Física, Universidade Estadual de Maringá, Av. Colombo 5790, 87.020-900 Maringá, PR (Brazil); Blanco, M. Cecilia; Fuertes, Valeria C.; Pannunzio-Miner, Elisa V. [INFIQC-CONICET, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, X5000HUA Córdoba (Argentina)] [INFIQC-CONICET, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, X5000HUA Córdoba (Argentina); Carbonio, Raúl E., E-mail: carbonio@fcq.unc.edu.ar [INFIQC-CONICET, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, X5000HUA Córdoba (Argentina)

2012-09-15T23:59:59.000Z

407

Palmetto Clean Energy (PaCE) Program  

Broader source: Energy.gov [DOE]

'''''Note: For a limited time, generators of 6 kilowatts or less of renewable energy can now take advantage of a premium $0.10 per kilowatt hour. This premium is available on a first-come-first...

408

Minka-Aire: Order (2014-CE-32018)  

Broader source: Energy.gov [DOE]

DOE ordered Minka Lighting Inc. to pay a $8,000 civil penalty after finding Minka had failed to certify that certain models of ceiling fans comply with the applicable energy conservation standards.

409

Kold Pack: Proposed Penalty (2013-CE-5323)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Kold Pack, Inc. failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

410

Kold Pack: Order (2013-CE-5323)  

Broader source: Energy.gov [DOE]

DOE ordered Kold Pack, Inc. to pay a $8,000 civil penalty after finding Kold Pack had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

411

Dans ce numro Le Service Informatique du  

E-Print Network [OSTI]

sont : · deux salles de Macintosh avec un serveur; · une salle de terminaux reliés au VAX 8600; · une

412

Amerikooler: Proposed Penalty (2013-CE-5307)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Amerikooler, Inc. failed to certify walk-in cooler or freezer (WICF) components as compliant with the energy conservation standards.

413

Dade Engineering: Proposed Penalty (2013-CE-5316)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Dade Engineering Corp. failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

414

Engineered Solutions: Order (2010-CE-2112)  

Broader source: Energy.gov [DOE]

DOE issued an Order after entering into a Compromise Agreement with Engineered Solutions, Inc. to resolve a case involving the failure to certify dehumidifier basic model SD109.

415

Dade Engineering: Order (2013-CE-5316)  

Broader source: Energy.gov [DOE]

DOE ordered Dade Engineering Corp. to pay a $8,000 civil penalty after finding Dade Engineering had failed to certify that certain models of walk-in cooler and freezer (WICF) components comply with the applicable energy conservation standards.

416

Engineered Solutions: Proposed Penalty (2010-CE-2112)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Engineered Solutions, Inc. failed to certify a dehumidifier as compliant with the applicable energy conservation standards.

417

Polar King: Order (2013-CE-5328)  

Broader source: Energy.gov [DOE]

DOE ordered Polar King International Inc. to pay a $8,000 civil penalty after finding Polar King had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

418

Polar King: Proposed Penalty (2013-CE-5328)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Polar King International Inc. failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

419

Golden Opportunity: Proposed Penalty (2014-CE-20003)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Golden Opportunity, Inc. failed to certify room air conditioners, central air conditioners/heat pumps, and residential clothes washers as compliant with the applicable energy conservation standards.

420

MC Appliance: Proposed Penalty (2014-CE-20002)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that MC Appliance Corporation failed to certify residential clothes washers and residential clothes dryers as compliant with the applicable energy conservation standards.

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Nostalgia Products: Proposed Penalty (2014-CE-14017)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Nostalgia Products Group, LLC failed to certify a variety of consumer refrigerators and refrigerator-freezers as compliant with the applicable energy conservation standards.

422

Whirlpool: Proposed Penalty (2014-CE-21010)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Whirlpool Corporation failed to certify residential clothes dryers as compliant with the applicable energy conservation standards.

423

Trastar: Proposed Penalty (2013-CE-49003)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Trastar Inc. failed to certify a variety of basic models of traffic signal modules and pedestrian models as compliant with the applicable energy conservation standards.

424

Goodman: Proposed Penalty (2012-CE-1509)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Goodman Manufacturing Company, L.P., failed to certify a various room air conditioners as compliant with the applicable energy conservation standards.

425

Goodman Manufacturing: Order (2012-CE-1509)  

Broader source: Energy.gov [DOE]

DOE ordered Goodman Manufacturing Company L.P. to pay an $8,000 civil penalty after finding Goodman Manufacturing had failed to certify that certain room air conditioners comply with the applicable energy conservation standard.

426

Midea Washing Appliance: Order (2011-CE-1903)  

Broader source: Energy.gov [DOE]

DOE ordered Midea Washing Appliance Mfg. Co., Ltd. to pay a $6,000 civil penalty after finding Midea Washing Appliance had failed to certify that certain models of dishwashers comply with the applicable energy conservation standards.

427

Sanyo Electric: Proposed Penalty (2010-CE-1210)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Sanyo Electric Co. failed to certify a variety of refrigerators, refrigerator-freezers, and freezers as compliant with the applicable energy conservation standards.

428

Keystone: Proposed Penalty (2013-CE-2601)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Keystone Technologies, LLC failed to certify a variety of fluorescent lamp ballasts as compliant with the applicable energy conservation standards.

429

Dacor: Proposed Penalty (2014-CE-23010)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Dacor failed to certify cooking products as compliant with the applicable energy conservation standards.

430

Duro Corporation: Proposed Penalty (2014-CE-23009)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Duro Corporation failed to certify cooking products as compliant with the applicable energy conservation standards.

431

CIVIL & ENVIRONMENTAL CE / ENE OVERVIEW PROGRAMS AVAILABLE  

E-Print Network [OSTI]

, industrial facilities and addressing the problems of ground water and air pollution as well as industrial: transportation systems, water supply, waste disposal systems and industrial and commercial structures. They face, construction engineering and management and environmental engineering. Environmental Engineering is concerned

Rohs, Remo

432

civil & environmental ce / ene overview programs available  

E-Print Network [OSTI]

, industrial facilities -- and addressing the problems of ground water and air pollution as well as industrial: transportation systems, water supply, waste disposal systems and industrial and commercial structures. They face, construction engineering and management and environmental engineering. Environmental Engineering is concerned

Rohs, Remo

433

Anthony International: Proposed Penalty (2013-CE-5357)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Anthony International failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

434

Anthony International: Order (2013-CE-5357)  

Broader source: Energy.gov [DOE]

DOE ordered Anthony International to pay a $8,000 civil penalty after finding Anthony International had failed to certify that any basic models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

435

Hisense USA: Order (2010-CE-1211)  

Broader source: Energy.gov [DOE]

DOE issued an Order after entering into a Compromise Agreement with Hisense USA Corp. after finding Hisense USA had failed to certify that certain models of residential refrigerators, refrigerator-freezers, and freezers comply with the applicable energy conservation standards.

436

R-Cold: Order (2013-CE-5354)  

Broader source: Energy.gov [DOE]

DOE ordered R-Cold, Inc. to pay a $8,000 civil penalty after finding R-Cold had failed to certify that any basic models of walk-in cooler or freezer components comply with the applicable energy conservation standards.

437

Sylvania: Proposed Penalty (2013-CE-2603)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Osram Sylvania Inc. failed to certify a variety of general service fluorescent lamps as compliant with the applicable energy conservation standards.

438

Haier: Proposed Penalty (2011-CE-2104)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Haier America Trading LLC failed to certify various residential clothes dryers as compliant with the applicable energy conservation standards.

439

Danby Products: Proposed Penalty (2012-CE-1415)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Danby Products, Inc. failed to certify refrigerators and freezers as compliant with the energy conservation standards.

440

Danby Products: Order (2012-CE-1415)  

Broader source: Energy.gov [DOE]

DOE ordered Danby Products to pay a $9,900 civil penalty after finding Danby had failed to certify that certain models of refrigerators and freezers comply with the applicable energy conservation standard.

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Distinctive Appliances: Proposed Penalty (2014-CE-23020)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Distinctive Appliances Distributing Inc. failed to certify cooking products as compliant with the applicable energy conservation standards.

442

Southeast Cooler: Proposed Penalty (2013-CE-5331)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Southeast Cooler Corp. failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

443

Commercial Cooler: Order (2013-CE-5343)  

Broader source: Energy.gov [DOE]

DOE ordered Commercial Cooler, Inc. to pay a $8,000 civil penalty after finding Commercial Cooler had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

444

Custom Coolers: Proposed Penalty (2013-CE-5315)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Custom Coolers, LLC, failed to certify walk-in cooler or freezer (WICF) components as compliant with the energy conservation standards.

445

Golden Cooler: Proposed Penalty (2013-CE-5345)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Golden Cooler failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

446

Southeast Cooler: Order (2013-CE-5331)  

Broader source: Energy.gov [DOE]

DOE ordered Southeast Cooler Corp. to pay a $8,000 civil penalty after finding Southeast Cooler had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

447

American Cooler Technologies: Order (2013-CE-5305)  

Broader source: Energy.gov [DOE]

DOE ordered American Cooler Technologies to pay a $8,000 civil penalty after finding American Cooler Technologies had failed to certify that certain models of walk-in coolers or freezers (WICF) components comply with the applicable energy conservation standards.

448

Commercial Cooler: Proposed Penalty (2013-CE-5343)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Commercial Cooler, Inc. failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

449

Golden Cooler: Order (2013-CE-5345)  

Broader source: Energy.gov [DOE]

DOE ordered Golden Cooler to pay a $8,000 civil penalty after finding Golden Cooler had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

450

Custom Coolers: Order (2013-CE-5315)  

Broader source: Energy.gov [DOE]

DOE ordered Custom Coolers, LLC to pay a $8,000 civil penalty after finding Custom Coolers had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

451

Topstar International: Order (2011-CE-2703)  

Broader source: Energy.gov [DOE]

DOE ordered Topstar International, Inc. to pay a $6,000 civil penalty after finding Topstar International had failed to certify that certain models of incandescent reflector lamps comply with the applicable energy conservation standards.

452

EiKO: Order (2011-CE-2702)  

Broader source: Energy.gov [DOE]

DOE ordered EiKO Ltd. - North America to pay a $6,000 civil penalty after finding EiKO had failed to certify that certain models of incandescent reflector lamps comply with the applicable energy conservation standards.

453

General Restaurant Equipment: Order (2013-CE-5344)  

Broader source: Energy.gov [DOE]

DOE ordered General Restaurant Equipment Co. to pay a $8,000 civil penalty after finding General Restaurant Equipment had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

454

Viking Range: Order (2014-CE-23014)  

Broader source: Energy.gov [DOE]

DOE ordered Viking Range, LLC to pay a $8,000 civil penalty after finding Viking Range had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

455

Euro Chef USA: Order (2014-CE-23004)  

Broader source: Energy.gov [DOE]

DOE ordered Euro Chef USA Inc. to pay a $8,000 civil penalty after finding Euro Chef USA had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

456

American Range: Order (2014-CE-23006)  

Broader source: Energy.gov [DOE]

DOE ordered American Range Corporation to pay a $8,000 civil penalty after finding American Range had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

457

Peerless-Premier: Order (2014-CE-23007)  

Broader source: Energy.gov [DOE]

DOE ordered Peerless-Premier Appliance Co. to pay a $8,000 civil penalty after finding Peerless-Premier had failed to certify that certain models of cooking products comply with the applicable energy conservation standards.

458

Nostalgia Products: Order (2014-CE-14017)  

Broader source: Energy.gov [DOE]

DOE ordered Nostalgia Products Group, LLC to pay a $8,000 civil penalty after finding Nostalgia Products had failed to certify that certain models of refrigerators and refrigerator-freezers comply with the applicable energy conservation standards.

459

MC Appliance: Order (2014-CE-20002)  

Broader source: Energy.gov [DOE]

DOE ordered MC Appliance Corporation to pay a $16,000 civil penalty after finding MC Appliance had failed to certify that certain models of residential clothes washers and residential clothes dryers comply with the applicable energy conservation standards.

460

Metl-Span: Order (2013-CE-5352)  

Broader source: Energy.gov [DOE]

DOE ordered Metl-Span LLC to pay a $8,000 civil penalty after finding Metl-Span had failed to certify that any basic models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Mercredi 15 Dcembre 2010 En ce moment  

E-Print Network [OSTI]

... Forum environnement : posez vos questions Biographies : portraits de personnalités Eco-gestes : cartes! Ship to Door Free www.MicroscopeNet.c The Microscope Depot Select The Right Microscope For You . Lowest Price. Free Shipping. Microscope-Depot.com Professional Microscopes Biological, Stereo, Digital, Hobby

Heller, Eric

462

Kingspan Insulated Panels: Order (2013-CE-5353)  

Broader source: Energy.gov [DOE]

DOE ordered Kingspan Insulated Panels, Inc. to pay a $8,000 civil penalty after finding Kingspan Insulated Panels had failed to certify that any basic models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

463

Elmira Stove Works: Order (2011-CE-1407)  

Broader source: Energy.gov [DOE]

DOE ordered Elmira Stove Works to pay a $6,000 civil penalty after finding Elmira Stove Works had failed to certify that certain models of refrigerator-freezers comply with the applicable energy conservation standard.

464

USA Manufacturing: Order (2013-CE-5336)  

Broader source: Energy.gov [DOE]

DOE ordered USA Manufacturing to pay a $8,000 civil penalty after finding USA Manufacturing had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

465

Oak Ridge Field O%ce  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*.MSE Cores" _August 4, 1992DOC F '

466

Spring 2009 CE 281: Experimental Systems  

E-Print Network [OSTI]

modeling 6. strain gages, induction motors, piezo-electrics and other types of sensing and actuation 7 4. free and forced vibration of a lightly damped linear structure 5. chaotic dynamics of a pre, integration and differentiation, bias, drift, and noise. reading: [22]:9.1-9.2 [25]:111,113,153 [74

Gavin, Henri

467

Microsoft Word - hCE1.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program Preliminary Needs535:UFC5,Overview ofLanceBTARGET:

468

CE Turbo Geothermal Facility | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBoston Areais3: Crystalline Rock - Basement JumpGeneral: CDOT Name:

469

Linac Coherent Light SourCe  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |EnergyonSupport0.pdf5 OPAM SEMIANNUAL REPORT TOJaredKansas1 -Energy Initiatives »Linac

470

CE: No. 2 2013 | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites Proposed Route Segments (notCAMDL20-000'IUDeputyofRank:Clean

471

CE: No. 3 2014 | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites Proposed Route Segments

472

CE: No. 4, 2014 | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites Proposed Route SegmentsClean Energy Newsletter No. 4, 2014

473

Matthews Fan: Proposed Penalty (2014-CE-32012)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Matthews-Gerbar, Ltd. d/b/a Matthews Fan Company failed to certify a variety of ceiling fans as compliant with the applicable energy conservation standards.

474

Matthews Fan: Order (2014-CE-32012)  

Broader source: Energy.gov [DOE]

DOE ordered Matthews-Gerbar, Ltd. d/b/a Matthews Fan Company to pay a $8,000 civil penalty after finding Matthews had failed to certify that certain models of ceiling fans comply with the applicable energy conservation standards.

475

Hunter Fan: Order (2014-CE-32008)  

Broader source: Energy.gov [DOE]

DOE ordered Hunter Fan Company to pay a $8,000 civil penalty after finding Hunter Fan had failed to certify that certain models of ceiling fans comply with the applicable energy conservation standards.

476

Capital Cooking: Proposed Penalty (2014-CE-23008)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Capital Cooking Equipment, Inc. failed to certify cooking products as compliant with the applicable energy conservation standards.

477

Duracold Refrigeration Manufacturing: Order (2013-CE-5342)  

Broader source: Energy.gov [DOE]

DOE ordered Duracold Refrigeration Manufacturing Company, LLC to pay a $8,000 civil penalty after finding Duracold Refrigeration Manufacturing had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

478

Cospolich Refrigerator: Order (2013-CE-5314)  

Broader source: Energy.gov [DOE]

DOE ordered Cospolich Refrigerator Co, Inc. to pay a $8,000 civil penalty after finding Cospolich Refrigerator had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

479

International Refrigeration: Proposed Penalty (2012-CE-1510)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that International Refrigeration Products failed to certify a various room air conditioners as compliant with the applicable energy conservation standards.

480

Refrigerator Manufacturers: Proposed Penalty (2013-CE-5341)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Refrigerator Manufacturers, LLC failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

Note: This page contains sample records for the topic "hl wyman ce" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

International Refrigeration: Order (2012-CE-1510)  

Broader source: Energy.gov [DOE]

DOE ordered International Refrigeration Products to pay an $8,000 civil penalty after finding International Refrigeration had failed to certify that certain room air conditioners comply with the applicable energy conservation standard.

482

Commercial Refrigerator Door: Order (2013-CE-5351)  

Broader source: Energy.gov [DOE]

DOE ordered Commercial Refrigerator Door Company, Inc. to pay a $8,000 civil penalty after finding Commercial Refrigerator Door had failed to certify that a variety of models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

483

Refrigerator Manufacturers: Order (2013-CE-5341)  

Broader source: Energy.gov [DOE]

DOE ordered Refrigerator Manufacturers, LLC to pay a $8,000 civil penalty after finding Refrigerator Manufacturers had failed to certify that certain models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

484

Cospolich Refrigerator: Proposed Penalty (2013-CE-5314)  

Broader source: Energy.gov [DOE]

DOE alleged in a Notice of Proposed Civil Penalty that Cospolich Refrigerator Co, Inc. failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

485

North Star Refrigerator: Order (2013-CE-5355)  

Broader source: Energy.gov [DOE]

DOE ordered North Star Refrigerator Co., Inc. to pay a $8,000 civil penalty after finding North Star Refrigerator had failed to certify that any basic models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

486

Thng 9, 2011 Xu t b n b i O ce of International A airs M i thng tin trong t ri ny u c trn m ng. c thng tin chi ti t v c p nh t, xin vui lng  

E-Print Network [OSTI]

Tháng 9, 2011 Xu t b n b i O ce of International A airs M i thông tin trong t ri này u có trên m ng. có thông tin chi ti t và c p nh t, xin vui lòng tra c u t i website c a chúng tôi : httpThông tin nhanh NTU, tr ng i h c t ng h p l n nh t và lâu i nh t ài Loan, ã thông báo các chng trình ào

Wu, Yih-Min

487

Primary to secondary sphere coordination of 15-crown-5 to lanthanide(III) chlorides: Structural analysis of [MCl{sub 3}(15-crown-5)] (M = La, Ce) and [Er(OH{sub 2}){sub 8}]Cl{sub 3} {center_dot} 15-crown-5  

SciTech Connect (OSTI)

Complexes of LaCl{sub 3}{center_dot}7H{sub 2}O and CeCl{sub 3} {center_dot} 7H{sub 2}O directly coordinated to 15-crown-5 were prepared by placing the reactants in 3:1 CH{sub 3}CN:CH{sub 3}OH on opposite sides of a fine porosity glass frit in a U-shaped cell and passing a 10 {mu}A current through the cell. The crystal structures of the two anhydrous 8-coordinate complexes, [MCl{sub 3}(15-crown-5)] (M = La, Ce) have been determined. Each contains the lanthanide in a bicapped trigonal prismatic geometry. The two complexes are isostructural crystallizing in the monoclinic space group P2{sub 1}/c with (at 20{degrees}C) for M = La: a =8.217(8), b = 14.298(2), c = 14.341(9){angstrom}, {beta} = 104.79(8){degrees}, and D{sub calc} = 1.90 g cm{sup {minus}3} for Z = 4; for M = Ce: a = 8.208(9), b = 14.263(6), c = 14.270(8){angstrom}, {beta} = 104.74(7){degrees}, and D{sub calc} = 1.92 g cm{sup {minus}3} for Z = 4. Direct reaction of ErCl{sub 3}{center_dot}6H{sub 2}O with 15-crown-5 in 3:1 CH{sub 3}CN:CH{sub 3}OH resulted in the crystallization of the second sphere hydrogen bonded complex [Er(OH{sub 2}){sub 8}]Cl{sub 3}{center_dot}15-crown-5. This complex is monoclinic, P2{sub 1}/n with (at 18{degrees}C) a = 9.193(3), b = 17.235(9), c = 15.216(5){angstrom}, {beta} = 92.48(3){degrees}, and D{sub calc} = 1.76 g cm{sup {minus}3} for Z = 4. The Er{sup 3+} ion is dodecahedral.

Roger, R.D.; Rollins, A.N. [Northern Illinois Univ., DeKalb, IL (United States)

1994-08-01T23:59:59.000Z

488

Introduction to Nuclear Engineering CE497-1 CE Project (Undergraduate Students)  

E-Print Network [OSTI]

· To employ advanced energy concepts through a course project · To improve oral and written communication skills Additional for Graduate Students: · To contribute original energy-related research through. Attendance and Participation 15% (sign-in sheets, discussion, behavior, peer review) Weekly Journals 35

Ervin, Elizabeth K.

489

E8267C/E8257C/E8247C PSG Application Note  

E-Print Network [OSTI]

generator E8257C PSG analog signal generator E8267C PSG vector signal generator #12;3 The PSG synthesized correction allows the digital adjustment of RF output amplitude for up to 1601 frequency points in any level varia- tions or loss occur. These frequen- cies may be defined in sequential linear steps

Anlage, Steven

490

Was Wealth Really Determined in 8000 BCE, 1000 BCE, 0 CE, or Even 1500 CE?  

E-Print Network [OSTI]

2013) Diamond, Jared (1997) Guns, Germs and Steel: The FateJohn Batchelor (1978) Naval Gun. Poole, UK: Blandford Press.time period is ships with guns and only one small corner of

Thompson, William R; Sakuwa, Kentaro

2013-01-01T23:59:59.000Z

491

Temperature dependent near infrared ultraviolet range dielectric functions of nanocrystalline (Na{sub 0.5}Bi{sub 0.5}){sub 1?x}Ce{sub x}(Ti{sub 0.99}Fe{sub 0.01})O{sub 3} films  

SciTech Connect (OSTI)

Optical properties and phase transition of Ce-modified (Na{sub 0.5}Bi{sub 0.5})(Ti{sub 0.99}Fe{sub 0.01})O{sub 3} nanocrystalline films have been investigated by spectroscopic ellipsometry from ?70 to 500?°C. Temperature dependent dielectric functions in the photon energy range of 0.6–6.4?eV can be derived by the Tauc-Lorentz model. It was found that the features in dielectric function (?) showed an abrupt variation near 200 and 340?°C, respectively. The phenomena can be explained by the appearance and/or reversal of polarization. It indicates that ferroelectric (rhombohedral) to paraelectric (tetragonal) phase transition is related to electronic band variation, which is observed by this technique.

Zhang, S.; Zhang, J. Z.; Han, M. J.; Li, Y. W.; Hu, Z.G., E-mail: zghu@ee.ecnu.edu.cn; Chu, J. H. [Key Laboratory of Polar Materials and Devices, Ministry of Education, Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China)

2014-01-27T23:59:59.000Z

492

Bright three-band white light generated from CdSe/ZnSe quantum dot-assisted Sr{sub 3}SiO{sub 5}:Ce{sup 3+},Li{sup +}-based white light-emitting diode with high color rendering index  

SciTech Connect (OSTI)

In this study, bright three-band white light was generated from the CdSe/ZnSe quantum dot (QD)-assisted Sr{sub 3}SiO{sub 5}:Ce{sup 3+},Li{sup +}-based white light-emitting diode (WLED). The CdSe/ZnSe core/shell structure was confirmed by energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy. The CdSe/ZnSe QDs showed high quantum efficiency (79%) and contributed to the high luminous efficiency ({eta}{sub L}) of the fabricated WLED. The WLED showed bright natural white with excellent color rendering property ({eta}{sub L}=26.8 lm/W, color temperature=6140 K, and color rendering index=85) and high stability against the increase in forward bias currents from 20 to 70 mA.

Jang, Ho Seong; Kwon, Byoung-Hwa; Jeon, Duk Young [Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Yang, Heesun [Department of Materials Science and Engineering, Hongik University, 72-1, Sangsu-dong, Mapo-gu, Seoul 121-791 (Korea, Republic of)

2009-10-19T23:59:59.000Z

493

Geology and Hydrogeology of Carbonate Islands. Developments in Sedimentology 54 edited by H.L. Vacher and T. Quinn  

E-Print Network [OSTI]

between Puerto Rico and Hispaniola in the northeastern Caribbean Sea (Fig. 9-1). It is located 72 km west Atlantic~ ~lJ / _~°//~ \\ 3ooo- --~- r :.... .....~'~Ocean ~ \\~~(y,,.,.....~,,.,.....~ _ __k'-2000~ i~"Hispaniola

González, Luis A.

494

Stimuli materials from Roediger, H.L., & Karpicke, J.D. (2006b). Test-enhanced learning: Taking memory tests  

E-Print Network [OSTI]

dwarf star. It is fueled by thermonuclear reactions near its center that convert hydrogen to helium temperature will fall. The higher temperature of the center will increase the rate of thermonuclear reactions to exist. Once the Sun has used up its thermonuclear energy as a red giant, it will begin to shrink. After

495

Archaeological investigations at the Kent Creek site (41HL66): evidence of Mogollon influence on the Southern Plains  

E-Print Network [OSTI]

panhandle and a number of other sites in the Panhandle Plains region allows for a redefinition of the Palo Duro complex and for its reassignment as a phase. The investigations at the Kent Creek site have revealed the remains of two functionally distinct... thanks goes to the members of the Panhandle Archaeological Society (PAS) who participated in the excavations at the site. Several of the PAS members gave up their weekends to help with the excavations and without their efforts the work could not have...

Cruse, Jimmy Brett

1989-01-01T23:59:59.000Z

496

GFDL Laboratory Review, May 20 May 22, 2014 Group Roster (1m) U.S.DOC/NOAA/OAR/GFDL 5/20/2014 5/22/2014 Page 1  

E-Print Network [OSTI]

, Ben-Jei: AOS Garner, Stephen Wyman, Bruce Harris, Lucas Xiang, Baoqiang: AOS Held, Isaac Zhao, Balaji: CICS Brian Gross Thomas Delworth Isaac Held Venkatachalam Ramaswamy Ronald Stouffer Research

497

BIOENERGY/BIOFUELS/BIOCHEMICALS Chromatographic determination of 1, 4-b-xylooligosaccharides  

E-Print Network [OSTI]

BIOENERGY/BIOFUELS/BIOCHEMICALS Chromatographic determination of 1, 4-b. Li Á R. Kumar Á C. E. Wyman BioEnergy Science Center, Oak Ridge, TN 37831, USA 123 J Ind Microbiol

California at Riverside, University of

498

Celebration of Design Class of 2013  

E-Print Network [OSTI]

. Personal Flotation Device for People with Cerebral Palsy. Philipp Ross 4. Wyman Zhao 1. Dr. Hiroki Sayama 1. Dr. Steen Rasmussen Personal fabricators are devices on the Socioeconomic Effects of Personal Fabricators ........................................................... 2 8

Suzuki, Masatsugu

499

Microdomains, solid solutions and the {open_quotes}defect fluorite{close_quotes} to C-type sesquioxide transition in CeO{sub 2}-RO{sub 1.5} and ZrO{sub 2}-RO{sub 1.5} systems  

SciTech Connect (OSTI)

Satellite dark field (SDF) imaging is used to show that there is a definite change in symmetry on moving across the two phase region separating the so-called {open_quotes}defect fluorite{close_quotes} and C-type sesquioxide solid solution regions in (1-x)CeO{sub 2}.xRO{sub 1.5} and (1-x)ZrO{sub 2}.xRO{sub 1.5} systems. SDF images of the {open_quotes}defect fluorite{close_quotes} side of the two-phase region are characterized by a microdomain texture on the {approximately}100-200 {angstrom} scale and the local symmetry within any one of these microdomains is shown to be lower than cubic. Corresponding SDF images of the C-type sesquioxide side of the two-phase region are by contrast homogeneous and consistent with Ia3 space group symmetry. The nature of the local oxygen vacancy distribution on either side of the two-phase region is discussed and a possible model for the {open_quotes}defect fluorite{close_quotes} side of the two-phase region proposed.

Withers, R.L.; Thompson, J.G.; Gabbitas, N.; Wallenburg, L.R.; Welberry, T.R. [Australian National Univ., Canberra (Australia)] [Australian National Univ., Canberra (Australia)

1995-12-01T23:59:59.000Z

500

EIS-0497: CE FLNG Project, Plaquemines Parish, Louisiana  

Broader source: Energy.gov [DOE]

The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an EIS to analyze the potential environmental impacts of a proposal to construct and operate a liquefied natural gas terminal in Plaquemines Parish, Louisiana, and approximately 37 miles of 42-inch diameter natural gas transmission pipeline to connect the terminal to natural gas infrastructure facilities.