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Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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1

Gaseous insulators for high voltage electrical equipment  

DOE Patents [OSTI]

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

Christophorou, Loucas G. (Oak Ridge, TN); James, David R. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Pai, Robert Y. (Concord, TN)

1981-01-01T23:59:59.000Z

2

Software digitizer for high granular gaseous detector  

E-Print Network [OSTI]

A sampling calorimeter using gaseous sensor layers with digital readout [1] is near perfect for ``Particle Flow Algorithm'' [2,3] approach, since it is homogeneous over large surfaces, robust, cost efficient, easily segmentable to any readout pad dimension and size and almost insensitive to neutrons. Monte-Carlo (MC) programs such as GEANT4 [4] simulate with high precision the energy deposited by particles. The sensor and electronic response associated to a pad are calculated in a separate ``digitization'' process. We develop a general method for simulating the pad response using the spatial information from a simulation done at high granularity. The digitization method proposed here has been applied to gaseous detectors including Glass Resistive Plate Chambers (GRPC) and MicroMegas, and validated on test beam data. Experimental observable such as pad multiplicity and mean number of hits at different thresholds have been reproduced with high precision.

Haddad, Y; Boudry, V

2015-01-01T23:59:59.000Z

3

THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE  

SciTech Connect (OSTI)

The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

Sherburne, Carol [Savannah River Site (SRS), Aiken, SC (United States). Savannah River Remediation, LLC; Osterberg, Paul [Fauske and Associates, LLC, Burr Ridge, IL (United States); Johnson, Tom [Fauske and Associates, LLC, Burr Ridge, IL (United States); Frawely, Thomas [Fauske and Associates, LLC, Burr Ridge, IL (United States)

2013-01-23T23:59:59.000Z

4

Software digitizer for high granular gaseous detector  

E-Print Network [OSTI]

A sampling calorimeter equipped with gaseous sensor layers with digital readout is near perfect for "Particle Flow Algorithm" approach, since it is homogeneous over large surfaces, robust, cost efficient, easily segmentable to any readout pad dimension and size and almost insensitive to neutrons. The response of a finely segmented digital calorimeter is characterized by track efficiency and multiplicity. Monte Carlo (MC) programs such as GEANT4 simulate with high precision the energy deposited by particles. The sensor and electronic response associated to a pad are calculated in a separate "digitization" process. We developed a general method for simulating the pad response, a digitization, reproducing efficiency and multiplicity, using the spatial information from a simulation done at higher granularity. The digitization method proposed here has been applied to gaseous detectors including Glass Resistive Plate Chambers (GRPC) and MicroMegas. Validating the method on test beam data, experimental observables such as efficiency, multiplicity and mean number of hits at different thresholds have been reproduced with high precision.

Y. Haddad; M. Ruan; V. Boudry

2014-05-06T23:59:59.000Z

5

Flammable gas project topical report  

SciTech Connect (OSTI)

The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-1 01 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue. Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. `Me report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods. Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue.

Johnson, G.D.

1997-01-29T23:59:59.000Z

6

Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels  

SciTech Connect (OSTI)

Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

Gardiner, D.; Bardon, M.; Pucher, G.

2008-10-01T23:59:59.000Z

7

THE EFFECT OF THE PRESENCE OF OZONE ON THE LOWER FLAMMABILITY LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE  

SciTech Connect (OSTI)

The Enhanced Chemical Cleaning (ECC) process uses ozone to effect the oxidation of metal oxalates produced during the dissolution of sludge in the Savannah River Site (SRS) waste tanks. The ozone reacts with the metal oxalates to form metal oxide and hydroxide precipitants, and the CO{sub 2}, O{sub 2}, H{sub 2}O and any unreacted O{sub 3} gases are discharged into the vapor space. In addition to the non-radioactive metals in the waste, however, the SRS radioactive waste also contains a variety of radionuclides, hence, hydrogen gas is also present in the vapor space of the ECC system. Because hydrogen is flammable, the impact of this resultant gas stream on the Lower Flammability Limit (LFL) of hydrogen must be understood for all possible operating scenarios of both normal and off-normal situations, with particular emphasis at the elevated temperatures and pressures of the typical ECC operating conditions. Oxygen is a known accelerant in combustion reactions, but while there are data associated with the behavior of hydrogen/oxygen environments, recent, relevant studies addressing the effect of ozone on the flammability limit of hydrogen proved scarce. Further, discussions with industry experts verified the absence of data in this area and indicated that laboratory testing, specific to defined operating parameters, was needed to comprehensively address the issue. Testing was thus designed and commissioned to provide the data necessary to support safety related considerations for the ECC process. A test matrix was developed to envelope the bounding conditions considered credible during ECC processing. Each test consists of combining a gas stream of high purity hydrogen with a gas stream comprised of a specified mixture of ozone and oxygen in a temperature and pressure regulated chamber such that the relative compositions of the two streams are controlled. The gases are then stirred to obtain a homogeneous mixture and ignition attempted by applying 10J of energy to a fuse wire. A gas combination is considered flammable when a pressure rise of 7% of the initial absolute pressure is observed. The specified testing methodology is consistent with guidelines established in ASTM E-918-83 (2005) 'Standard Practices for Determining Limits of Flammability of Chemicals at Elevated Temperature and Pressure'.

Sherburne, C.

2012-01-12T23:59:59.000Z

8

Chemical nature of high-molecular hydrocarbons of gaseous condensates  

SciTech Connect (OSTI)

Mass spectrometry was used to study the group-structure composition of high-boiling 50 deg (200/degrees/-250/degrees/, 250/degrees/-300/degrees/, and 300/degrees/-350/degrees/C) fractions of East Turkmenistan condensates: the hydrocarbons composition is characterized by a high content of paraffinic hydrocarbons, and that of others by aromatic and naphthenic hydrocarbons. For all the condensates under investigation, as the boiling temperature of fractions increases, the content of paraffinic hydrocarbons in them is increased, while that of naphthenic hydrocarbons is reduced. The distribution of naphthenic hydrocarbons according to the number of rings is identical. In high-paraffin condensates, monoaromatic hydrocarbons consist mainly structures with alkyl substituents, but in condensates with a high content of aromatic and naphthenic hydrocarbons they consist mainly of structures with naphthenic substituents. 4 references, 1 figures, 2 tables.

Kul'dzhayev, B.A.; Makarov, V.V.; Sergiyenko, S.R.; Khramova, E.V.

1987-01-01T23:59:59.000Z

9

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

10

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

11

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

12

Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol  

SciTech Connect (OSTI)

This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

Gardiner, D. P.; Bardon, M. F.; Clark, W.

2011-07-01T23:59:59.000Z

13

Flammable Gas Detection for the D-Zero Gas System  

SciTech Connect (OSTI)

The use of flammable gas and high voltage in detector systems is common in many experiments at Fermilab. To mitigate the hazards associated with these systems, Fermilab Engineering Standard SD-45B (Ref. 1) was adopted. Since this note is meant to be a guide and not a mandatory standard, each experiment is reviewed for compliance with SD-45B by the flammable gas safety subcommittee. Currently, there are only two types of flammable gas in use, ethane (Appendix A) and methane (Appendix B). The worst flammable-gas case is C2H6 (ethane), which has an estimated flow rate that is 73% of the CH4 (methane) flow but a heat of combustion (in kcal/g-mole) that is 173% of that of methane. In the worst case, if ethane were to spew through its restricting orifice into its gas line at 0 psig and then through a catastrophic leak into Room 215 (TRD) or Room 511 (CDC/FDCNTX), the time that would be required to build up a greater than Class 1 inventory (0.4kg H2 equivalent) would be 5.2 hours (Ref. 2). Therefore a worst-case flammable gas leak would have to go undetected for over 5 hours in order to transform a either mixing room to an environment with a Risk Class greater than Class 1. The mixing systems, gas lines, and detectors themselves will be thoroughly leak checked prior to active service. All vessels that are part of the mixing systems will be protected from overpressure by safety valves vented outside the building. Both the input and output of all detector volumes are protected from overpressure in the same way. The volume immediately outside the central tracking detectors is continuously purged by nitrogen from boiloff from the main nitrogen dewar at the site. However, if flammable gas were to build up in the mixing rooms or particular detector areas, no matter how unlikely, flammable gas detectors that are part of the interlock chain of each gas mixing system will shut down the appropriate system. This includes shutting off the output of flammable gas manifolds within the gas shed. Similarly, if a fire were to break out anywhere in the D-ZERO Hall, fire sensors would stop the output of all flammable gas manifolds within the gas shed, by unpowering electrically controlled solenoid valves that are normally closed in the event of a power failure. Fire sensor contacts have not yet been installed.

Spires, L.D.; Foglesong, J.; /Fermilab

1991-02-11T23:59:59.000Z

14

Flammability Control In A Nuclear Waste Vitrification System  

SciTech Connect (OSTI)

The Defense Waste Processing Facility at the Savannah River Site processes high-level radioactive waste from the processing of nuclear materials that contains dissolved and precipitated metals and radionuclides. Vitrification of this waste into borosilicate glass for ultimate disposal at a geologic repository involves chemically modifying the waste to make it compatible with the glass melter system. Pretreatment steps include removal of excess aluminum by dissolution and washing, and processing with formic and nitric acids to: 1) adjust the reduction-oxidation (redox) potential in the glass melter to reduce radionuclide volatility and improve melt rate; 2) adjust feed rheology; and 3) reduce by steam stripping the amount of mercury that must be processed in the melter. Elimination of formic acid in pretreatment has been studied to eliminate the production of hydrogen in the pretreatment systems, which requires nuclear grade monitoring equipment. An alternative reductant, glycolic acid, has been studied as a substitute for formic acid. However, in the melter, the potential for greater formation of flammable gases exists with glycolic acid. Melter flammability is difficult to control because flammable mixtures can be formed during surges in offgases that both increase the amount of flammable species and decrease the temperature in the vapor space of the melter. A flammable surge can exceed the 60% of the LFL with no way to mitigate it. Therefore, careful control of the melter feed composition based on scaled melter surge testing is required. The results of engineering scale melter tests with the formic-nitric flowsheet and the use of these data in the melter flammability model are presented.

Zamecnik, John R.; Choi, Alexander S.; Johnson, Fabienne C.; Miller, Donald H.; Lambert, Daniel P.; Stone, Michael E.; Daniel, William E. Jr.

2013-07-25T23:59:59.000Z

15

MICROSTRUCTURE AND MECHANICAL PROPERTY PERFORMANCE OF COMMERCIAL GRADE API PIPELINE STEELS IN HIGH PRESSURE GASEOUS HYDROGEN  

SciTech Connect (OSTI)

The continued growth of the world s developing countries has placed an ever increasing demand on traditional fossil fuel energy sources. This development has lead to increasing research and development of alternative energy sources. Hydrogen gas is one of the potential alternative energy sources under development. Currently the most economical method of transporting large quantities of hydrogen gas is through steel pipelines. It is well known that hydrogen embrittlement has the potential to degrade steel s mechanical properties when hydrogen migrates into the steel matrix. Consequently, the current pipeline infrastructure used in hydrogen transport is typically operated in a conservative fashion. This operational practice is not conducive to economical movement of significant volumes of hydrogen gas as an alternative to fossil fuels. The degradation of the mechanical properties of steels in hydrogen service is known to depend on the microstructure of the steel. Understanding the levels of mechanical property degradation of a given microstructure when exposed to hydrogen gas under pressure can be used to evaluate the suitability of the existing pipeline infrastructure for hydrogen service and guide alloy and microstructure design for new hydrogen pipeline infrastructure. To this end, the 2 Copyright 2010 by ASME microstructures of relevant steels and their mechanical properties in relevant gaseous hydrogen environments must be fully characterized to establish suitability for transporting hydrogen. A project to evaluate four commercially available pipeline steels alloy/microstructure performance in the presences of gaseous hydrogen has been funded by the US Department of Energy along with the private sector. The microstructures of four pipeline steels were characterized and then tensile testing was conducted in gaseous hydrogen and helium at pressures of 800, 1600 and 3000 psi. Based on measurements of reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 800 and 3000 psi. This paper will describe the work performed on four commercially available pipeline steels in the presence of gaseous hydrogen at pressures relevant for transport in pipelines. Microstructures and mechanical property performances will be compared. In addition, recommendations for future work related to gaining a better understanding of steel pipeline performance in hydrogen service will be discussed.

Stalheim, Mr. Douglas [DGS Metallurgical Solutions Inc; Boggess, Todd [Secat; San Marchi, Chris [Sandia National Laboratories (SNL); Jansto, Steven [Reference Metals Company; Somerday, Dr. B [Sandia National Laboratories (SNL); Muralidharan, Govindarajan [ORNL; Sofronis, Prof. Petros [University of Illinois

2010-01-01T23:59:59.000Z

16

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION & LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE [SEC 1 & 2  

SciTech Connect (OSTI)

Flammable gases such as hydrogen, ammonia, and methane are observed in the tank dome space of the Hanford Site high-level waste tanks. This report assesses the steady-state flammability level under normal and off-normal ventilation conditions in the tank dome space for 177 double-shell tanks and single-shell tanks at the Hanford Site. The steady-state flammability level was estimated from the gas concentration of the mixture in the dome space using estimated gas release rates, Le Chatelier's rule and lower flammability limits of fuels in an air mixture. A time-dependent equation of gas concentration, which is a function of the gas release and ventilation rates in the dome space, has been developed for both soluble and insoluble gases. With this dynamic model, the time required to reach the specified flammability level at a given ventilation condition can be calculated. In the evaluation, hydrogen generation rates can be calculated for a given tank waste composition and its physical condition (e.g., waste density, waste volume, temperature, etc.) using the empirical rate equation model provided in Empirical Rate Equation Model and Rate Calculations of Hydrogen Generation for Hanford Tank Waste, HNF-3851. The release rate of other insoluble gases and the mass transport properties of the soluble gas can be derived from the observed steady-state gas concentration under normal ventilation conditions. The off-normal ventilation rate is assumed to be natural barometric breathing only. A large body of data is required to do both the hydrogen generation rate calculation and the flammability level evaluation. For tank waste that does not have sample-based data, a statistical-based value from probability distribution regression was used based on data from tanks belonging to a similar waste group. This report (Revision 3) updates the input data of hydrogen generation rates calculation for 177 tanks using the waste composition information in the Best-Basis Inventory Detail Report in the Tank Waste Information Network System, and the waste temperature data in the Surveillance Analysis Computer System (SACS) (dated July 2003). However, the release rate of methane, ammonia, and nitrous oxide is based on the input data (dated October 1999) as stated in Revision 0 of this report. Scenarios for adding waste to existing waste levels (dated July 2003) have been studied to determine the gas generation rates and the effect of smaller dome space on the flammability limits to address the issues of routine water additions and other possible waste transfer operations. In the flammability evaluation with zero ventilation, the sensitivity to waste temperature and to water addition was calculated for double-shell tanks 241-AY-102, 241-AN-102,241-AZ-101,241-AN-107,241-AY-101 and 241-AZ-101. These six have the least margin to flammable conditions among 28 double-shell tanks.

HU, T.A.

2003-09-30T23:59:59.000Z

17

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect (OSTI)

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The hydrogen generation rate was calculated for 177 tanks using the rate equation model. Flammability calculations based on hydrogen, ammonia, and methane were performed for 177 tanks for various scenarios.

HU TA

2009-10-26T23:59:59.000Z

18

Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology  

SciTech Connect (OSTI)

Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

Kostival, A.; Rivkin, C.; Buttner, W.; Burgess, R.

2013-11-01T23:59:59.000Z

19

Process and system for producing high-density pellets from a gaseous medium  

DOE Patents [OSTI]

A process and system for producing pellets of high density carbon dioxide or other gases utilize a chamber containing a plurality of cell-like freezing compartments within which ice is to be formed. A gas desired to be frozen into ice is introduced into the chamber while the internal pressure of the chamber is maintained at a level which is below the equilibrium triple pressure of the gas. The temperature of the freezing compartments is lowered to a temperature which is below the equilibrium vapor pressure temperature of the gas at the chamber pressure so that the gas condenses into ice within the compartments. The temperature of the freezing compartments is thereafter raised so that the ice is thereby released from and falls out of the compartments as pellets for collection.

Foster, Christopher A. (Clinton, TN)

1999-01-01T23:59:59.000Z

20

STEADY-STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect (OSTI)

Assess the steady-state flammability level at normal and off-normal ventilation conditions. The methodology of flammability analysis for Hanford tank waste is developed. The hydrogen generation rate model was applied to calculate the gas generation rate for 177 tanks. Flammability concentrations and the time to reach 25% and 100% of the lower flammability limit, and the minimum ventilation rate to keep from 100 of the LFL are calculated for 177 tanks at various scenarios.

HU TA

2007-10-26T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Thermal decomposition and flammability of fire-resistant, UV/visible-sensitive polyarylates, copolymers and blends  

E-Print Network [OSTI]

Thermal decomposition and flammability of fire-resistant, UV/visible- sensitive polyarylates temperature, low notch sensitivity, and good electrical properties. Most of all, these materials show a high resistance to ignition and flame spreading without additives [6]. A high-temperature wholly aromatic poly

22

Slurry growth, gas retention, and flammable gas generation by Hanford radioactive waste tanks: Synthetic waste studies, FY 1991  

SciTech Connect (OSTI)

Of 177 high-level waste storage tanks on the Hanford Site, 23 have been placed on a safety watch list because they are suspected of producing flammable gases in flammable or explosive concentrate. One tankin particular, Tank 241-SY-101 (Tank 101-SY), has exhibited slow increases in waste volume followed by a rapid decrease accompanied by venting of large quantities of gases. The purpose of this study is to help determine the processes by which flammable gases are produced, retained, and eventually released from Tank 101-SY. Waste composition data for single- and double-shell waste tanks on the flammable gas watch listare critically reviewed. The results of laboratory studies using synthetic double-shell wastes are summarized, including physical and chemical properties of crusts that are formed, the stoichiometry and rate ofgas generation, and mechanisms responsible for formation of a floating crust.

Bryan, S.A.; Pederson, L.R.; Ryan, J.L.; Scheele, R.D.; Tingey, J.M.

1992-08-01T23:59:59.000Z

23

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect (OSTI)

This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for all 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 11 days for DSTs (i.e., tank 241-AZ-10l) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 10 days for DSTs (i.e., tank 241-AZ-101) and 34 days for SSTs (i.e., tank 241-B-203).

MEACHAM JE

2009-10-26T23:59:59.000Z

24

STEADY STATE FLAMMABLE GAS RELEASE RATE CALCULATION AND LOWER FLAMMABILITY LEVEL EVALUATION FOR HANFORD TANK WASTE  

SciTech Connect (OSTI)

This report assesses the steady state flammability level under off normal ventilation conditions in the tank headspace for 28 double-shell tanks (DST) and 149 single shell-tanks (SST) at the Hanford Site. Flammability was calculated using estimated gas release rates, Le Chatelier's rule, and lower flammability limits of fuels in an air mixture. This revision updates the hydrogen generation rate input data for al1 177 tanks using waste composition information from the Best Basis Inventory Detail Report (data effective as of August 4,2008). Assuming only barometric breathing, the shortest time to reach 25% of the lower flammability limit is 13 days for DSTs (i.e., tank 241-AZ-102) and 36 days for SSTs (i.e., tank 241-B-203). Assuming zero ventilation, the shortest time to reach 25% of the lower flammability limit is 12 days for DSTs (i.e., tank 241-AZ-102) and 34 days for SSTs (i.e., tank 241-B-203).

MEACHAM JE

2008-11-17T23:59:59.000Z

25

The Chemistry of Flammable Gas Generation  

SciTech Connect (OSTI)

The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

ZACH, J.J.

2000-10-30T23:59:59.000Z

26

Combination free electron and gaseous laser  

DOE Patents [OSTI]

A multiple laser having one or more gaseous laser stages and one or more free electron stages. Each of the free electron laser stages is sequentially pumped by a microwave linear accelerator. Subsequently, the electron beam is directed through a gaseous laser, in the preferred embodiment, and in an alternative embodiment, through a microwave accelerator to lower the energy level of the electron beam to pump one or more gaseous lasers. The combination laser provides high pulse repetition frequencies, on the order of 1 kHz or greater, high power capability, high efficiency, and tunability in the synchronous production of multiple beams of coherent optical radiation.

Brau, Charles A. (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Stein, William E. (Los Alamos, NM)

1980-01-01T23:59:59.000Z

27

Flammability limits of dusts: Minimum inerting concentrations  

SciTech Connect (OSTI)

A new flammability limit parameter has been defined as the Minimum Inerting Concentration (MIC). This is the concentration of inertant required to prevent a dust explosion regardless of fuel concentration. Previous experimental work at Fike in a 1-m{sup 3} spherical chamber has shown this flammability limit to exist for pulverized coal dust and cornstarch. In the current work, inerting experiments with aluminum, anthraquinone and polyethylene dusts as fuels were performed, using monoammonium phosphate and sodium bicarbonate as inertants. The results show that an MIC exists only for anthraquinone inerted with sodium bicarbonate. The other combustible dust and inertant mixtures did not show a definitive MIC, although they did show a strong dependence between inerting level and suspended fuel concentration. As the fuel concentration increased, the amount of inertant required to prevent an explosion decreased. Even though a definitive MIC was not found for most of the dusts an effective MIC can be estimated from the data. The use of MIC data can aid in the design of explosion suppression schemes.

Dastidar, A.G.; Amyotte, P.R. [Dalhousie Univ., Halifax, Nova Scotia (Canada). Dept. of Chemical Engineering] [Dalhousie Univ., Halifax, Nova Scotia (Canada). Dept. of Chemical Engineering; Going, J.; Chatrathi, K. [Fike Corp., Blue Springs, MO (United States)] [Fike Corp., Blue Springs, MO (United States)

1999-05-01T23:59:59.000Z

28

Flammability Assessment Methodology Program Phase I: Final Report  

SciTech Connect (OSTI)

The Flammability Assessment Methodology Program (FAMP) was established to investigate the flammability of gas mixtures found in transuranic (TRU) waste containers. The FAMP results provide a basis for increasing the permissible concentrations of flammable volatile organic compounds (VOCs) in TRU waste containers. The FAMP results will be used to modify the ''Safety Analysis Report for the TRUPACT-II Shipping Package'' (TRUPACT-II SARP) upon acceptance of the methodology by the Nuclear Regulatory Commission. Implementation of the methodology would substantially increase the number of drums that can be shipped to the Waste Isolation Pilot Plant (WIPP) without repackaging or treatment. Central to the program was experimental testing and modeling to predict the gas mixture lower explosive limit (MLEL) of gases observed in TRU waste containers. The experimental data supported selection of an MLEL model that was used in constructing screening limits for flammable VOC and flammable gas concentrations. The MLEL values predicted by the model for individual drums will be utilized to assess flammability for drums that do not meet the screening criteria. Finally, the predicted MLEL values will be used to derive acceptable gas generation rates, decay heat limits, and aspiration time requirements for drums that do not pass the screening limits. The results of the program demonstrate that an increased number of waste containers can be shipped to WIPP within the flammability safety envelope established in the TRUPACT-II SARP.

C. A. Loehr; S. M. Djordjevic; K. J. Liekhus; M. J. Connolly

1997-09-01T23:59:59.000Z

29

Gaseous Hydrogen Delivery Breakout  

E-Print Network [OSTI]

Gaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7 detection Pipeline Safety: odorants, flame visibility Compression: cost, reliability #12;Breakout Session goal of a realistic, multi-energy distribution network model Pipeline Technology Improved field

30

OPTIMIZATION AND DESIGN GUIDELINES FOR HIGH FLUX MICRO-CHANNEL HEAT SINKS FOR LIQUID AND GASEOUS SINGLE-PHASE FLOW  

E-Print Network [OSTI]

forced convection micro-channel heat sinks for minimum pump power at high heat fluxes. Results gained orders of magnitude, especially for high heat flux devices. Using water and air as coolants, designs for heat fluxes of >10 kW/cm2 and >100 W/cm2 respectively with pump/fan power expenses less than 1

Müller, Norbert

31

Gaseous Hydrogen Delivery Breakout - Strategic Directions for...  

Broader source: Energy.gov (indexed) [DOE]

Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop...

32

Flammable gas interlock spoolpiece flow response test report  

SciTech Connect (OSTI)

The purpose of this test report is to document the testing performed under the guidance of HNF-SD-WM-TC-073, {ital Flammable Gas Interlock Spoolpiece Flow Response Test Plan and Procedure}. This testing was performed for Lockheed Martin Hanford Characterization Projects Operations (CPO) in support of Rotary Mode Core Sampling jointly by SGN Eurisys Services Corporation and Numatec Hanford Company. The testing was conducted in the 305 building Engineering Testing Laboratory (ETL). NHC provides the engineering and technical support for the 305 ETL. The key personnel identified for the performance of this task are as follows: Test responsible engineering manager, C. E. Hanson; Flammable Gas Interlock Design Authority, G. P. Janicek; 305 ETL responsible manager, N. J. Schliebe; Cognizant RMCS exhauster engineer, E. J. Waldo/J. D. Robinson; Cognizant 305 ETL engineer, K. S. Witwer; Test director, T. C. Schneider. Other support personnel were supplied, as necessary, from 305/306 ETL. The testing, on the flammable Gas Interlock (FGI) system spoolpiece required to support Rotary Mode Core Sampling (RMCS) of single shell flammable gas watch list tanks, took place between 2-13-97 and 2-25-97.

Schneider, T.C., Fluor Daniel Hanford

1997-03-24T23:59:59.000Z

33

Overview of the Flammability of Gases Generated in Hanford Waste Tanks  

SciTech Connect (OSTI)

This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, flammability and detonability limits of the gas constituents, and availability of ignition sources. The intrinsic flammability (or non-flammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, and volume of the release and the tank ventilation rate, which are not covered in this report.

Mahoney, Lenna A.; Huckaby, James L.; Bryan, Samuel A.; Johnson, Gerald D.

2000-07-19T23:59:59.000Z

34

Investigation of high temperature gaseous species by Knudsen cell mass spectrometry above the condensed systems Au-Ge-Cu and Au-Si / by Joseph Edward Kingcade  

E-Print Network [OSTI]

0), in kJ mol for the Gaseous Molecules AuSi, Ie 24 27 3l 34 TABLE 12. 13. 14. 15. 1 6. 17a 18. 19. 20. 21. 22. 23. Au2Si, AuSi2, CuGe and CuGe2 . . . . . . . . . . . . . . . Summary of Enthalpy Changes: for the Molecule Au..., (HT-H ), in kJ mol for the Gaseous T o Molecules Au2Ge2, AuGe3 and AuGe4 MOLECULE AND STRUCTURE 298 1200 1400 1600 TEMPERATURE ( K) 1800 2000 2200 hu2 Ge2 (Linear) Au2 Gep (Square Planar) FEF HCF FEF HCF 297. 7 18. 69 317. 1 18. 83...

Kingcade, Joseph Edward

2012-06-07T23:59:59.000Z

35

Solid and gaseous fuels  

SciTech Connect (OSTI)

This review covers methods of sampling, analyzing, and testing coal, coke, and coal-derived solids covered during the period of October 1984 through Sept 30, 1986. Energy Research Abstracts and Chemical Abstracts were used as the reference sources. In most categories the volume of material available made it necessary to limit the number of publications in the review. This review also surveys publications concerned with methods for the chemical, physical, and instrumental analyses of gaseous fuels and related materials. Articles of significance appearing in foreign journals and the patent literature that were not available at the time of the last review are also included. Chemical Abstracts and Energy Research Abstracts were used extensively as reference sources. Some selectivity was necessary in order to include the most pertinent publications in preparing this review.

Schultz, H.; Wells, A.W.; Frommell, E.A.; Flenory, P.B.

1987-06-15T23:59:59.000Z

36

Retained Gas Sampling Results for the Flammable Gas Program  

SciTech Connect (OSTI)

The key phenomena of the Flammable Gas Safety Issue are generation of the gas mixture, the modes of gas retention, and the mechanisms causing release of the gas. An understanding of the mechanisms of these processes is required for final resolution of the safety issue. Central to understanding is gathering information from such sources as historical records, tank sampling data, tank process data (temperatures, ventilation rates, etc.), and laboratory evaluations conducted on tank waste samples.

J.M. Bates; L.A. Mahoney; M.E. Dahl; Z.I. Antoniak

1999-11-18T23:59:59.000Z

37

FLAMMABILITY AND CONSEQUENCE ANALYSIS FOR MCU WASTE TANKS  

SciTech Connect (OSTI)

The Savannah River Site of Department of Energy will use the new Modular Caustic Side Solvent Extraction Unit (MCU) to process the waste stream by removing/reducing Cs-137 using Caustic Side Solvent Extraction (CSSX) technology. The CSSX technology utilizes multicomponent organic solvent and annular centrifugal contactors to extract Cs-137 from waste salt solution. Due to the radiolysis of the aqueous nuclear wastes, hydrogen generation is expected in the MCU holding tanks. The hydrogen from radiolysis and the vapor from the organic component of the solvent, Isopar-L, may form a composite flammable gas mixture, resulting in a shorter time to flammability than that of a pure hydrogen environment. It has been found that the time-to-Lower Flammability Limit (LFL) and stoichiometric concentration (SC) vary greatly from tank to tank, and could be decreased significantly by the presence of the Isopar-L. However, neither the deflagration nor the detonation event would challenge the Evaluation Guideline for any of the tanks at any liquid level.

Knight, J; Mukesh Gupta, M

2007-02-13T23:59:59.000Z

38

Flammable gas/slurry growth unreviewed safety question:justification for continued operation for the tank farms at the Hanford site  

SciTech Connect (OSTI)

This Justification for Continued Operation (JCO) provides a basis for continued operation in 176 high level waste tanks, double contained receiver tanks (DCRTs), catch tanks, 244-AR Vault, 242-S and 242-T Evaporators and inactive miscellaneous underground storage tanks (IMUSTs) relative to flammable gas hazards. Required controls are specified.

Leach, C.E., Westinghouse Hanford

1996-07-31T23:59:59.000Z

39

Experimental measurements and modeling prediction of flammability limits of binary hydrocarbon mixtures  

E-Print Network [OSTI]

of methane in air using thermal criterion?????..50 4.8 Determination of LFL of ethylene in air using thermal criterion???...??..51 4.9 Lower flammability limits of methane and n-butane mixtures in air at standard conditions...????????????????????..56 4.14 Upper flammability limits of methane and n-butane mixtures in air at standard conditions?????????????..???????57 4.15 Upper flammability limits of methane and ethylene mixtures in air at standard conditions...

Zhao, Fuman

2009-05-15T23:59:59.000Z

40

Overview of the Flammability of Gases Generated in Hanford Waste Tanks  

SciTech Connect (OSTI)

This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

2000-07-21T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Systems acceptance and operability testing for rotary mode core sampling in flammable gas tanks  

SciTech Connect (OSTI)

This document provides instructions for the system acceptance and operability testing of the rotary mode core sampling system, modified for use in flammable gas tanks.

Corbett, J.E., Westinghouse Hanford

1996-07-29T23:59:59.000Z

42

Is the situation and immediate threat to life and health? Spill/Leak/Release Medical Emergency Fire or Flammable Gas Spill/Leak/Release Medical Emergency Fire or Flammable Gas Chemical Odor? Possible Fire / Natural Gas  

E-Print Network [OSTI]

? Possible Fire / Natural Gas (including chemicals and bio agents") (not including chemicals or bio agents Fire or Flammable Gas Spill/Leak/Release Medical Emergency Fire or Flammable Gas Chemical Odor

43

Safe Use of Flammable and Explosive Substances: A Guide to DSEAR in the University  

E-Print Network [OSTI]

common organic solvents o Benzoyl peroxide o Ammonia gas o Oxygen gas o Petrol o Varnishes o LPG o Methyl of waste dusts in woodworking shops; · Handling and storage of flammable wastes including fuel oils; · Hot work on tanks or drums that have contained flammable material; · Work activities that could release

Glasgow, University of

44

Automated spray cleaning using flammable solvents in a glovebox environment  

SciTech Connect (OSTI)

The Clean Air Act Amendments that have phased out the use of ozone depleting solvents (ODS) have given the precision cleaning industry a challenge that they must respond to if they are to continuously and economically improve quality of service. The phase out of the ozone depleting solvents has forced industry to look to solvents such as alcohol, terpenes and other flammable solvents to perform the critical cleaning processes. These solvents are not as efficient as their ODS counterparts in terms of soil loading, cleaning time and drying when used in standard cleaning processes such as manual sprays or ultrasonic baths. They also require special equipment designs to meet part cleaning specifications and operator safety requirements. This paper describes a cleaning system that incorporates the automated spraying of flammable solvents to effectively perform precision cleaning processes. The prototype workcell under development uses a robot that sprays Isopropyl Alcohol (IPA) and terpene at pressures ranging to 600 psi in a glovebox environment. Key to the projects success was the development of software that controls the robotic system and automatically generates robotic cleaning paths from three dimensional CAD models of the items to be cleaned. Also key to the success of this prototype development is FM approval of the process and associated hardware which translates directly into operator and facilities safety.

McKee, R.; Meirans, L.; Watterberg, P.; Drotning, W. [Sandia National Labs., Albuquerque, NM (United States)

1997-04-01T23:59:59.000Z

45

Flammable gas tank waste level reconciliation for 241-S-111  

SciTech Connect (OSTI)

Fluor Daniel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 241-S-111. The trapped gas evaluation document states that Tank S-111 exceeds the 25% of the lower flammable-limit criterion, based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the Welty Report is the basis for this letter report. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unaccounted for surface level rise. From 1973 through 1980, the Welty Report tracked Tank S-111 transfers. This surface level increase is from an unknown source or is unaccounted for. Duke Engineering and Services Hanford and Lockheed Martin Hanford Corporation are interested in determining the validity of the unexplained surface level changes reported in the Welty Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unaccounted for surface level changes as shown in the Welty Report from 1973 through 1980. Tank S-111 initially received waste from REDOX in 1952, and after April 1974, primarily received processed waste slurry from the 242-S Evaporator/Crystallizer and transferred supernatant waste to Tank S-102. From the FDNW review and comparisons of the Welty Report versus other daily records for Tank S-111, FDNW determined that the majority of the time, the Welty Report is consistent with daily records. Surface level decreases that occurred following saltwell pumping were identified as unaccounted for decreases in the Welty Report, however they were probably a continued settlement caused by saltwell pumping of the interstitial liquids. Because the flammable/trapped gas issue is linked to the unexplained increase in the surface level, FDNW recommends that all occurrence reports, concerning tank waste level increases or decreases from 1970 through 1980, be reevaluated for acceptability of the evaluation as to the root cause of the occurrence.

Brevick, C.H.; Gaddis, L.A.

1997-06-23T23:59:59.000Z

46

Flammable gas tank waste level reconciliation for 241-SX-105  

SciTech Connect (OSTI)

Fluor Daniel Northwest was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 241-SX-105 (SX-105, typical). The trapped gas evaluation document states that Tank SX-105 exceeds the 25% of the lower flammable limit criterion, based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the Welty Report is the basis for this letter report. The Welty Report is also a part of the trapped gas evaluation document criteria. The Welty Report contains various tank information, including: physical information, status, levels, and dry wells. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unaccounted for surface level rise. From 1973 through 1980, the Welty Report tracked Tank SX-105 transfers and reported a net cumulative change of 20.75 in. This surface level increase is from an unknown source or is unaccounted for. Duke Engineering and Services Hanford and Lockheed Martin Hanford Corporation are interested in determining the validity of unexplained surface level changes reported in the Welty Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unaccounted for surface level changes as shown in the Welty Report from 1973 through 1980. Tank SX-105 initially received waste from REDOX starting the second quarter of 1955. After June 1975, the tank primarily received processed waste (slurry) from the 242-S Evaporator/Crystallizer and transferred supernate waste to Tanks S-102 and SX-102. The Welty Report shows a cumulative change of 20.75 in. from June 1973 through December 1980.

Brevick, C.H.; Gaddie, L.A.

1997-06-23T23:59:59.000Z

47

The effect of CO? on the flammability limits of low-BTU gas of the type obtained from Texas lignite  

E-Print Network [OSTI]

) . If the L. used are the lower limits of 1 the individual components, then Equation (1) will yield the lower flammability limit of the mixture (Zabetakis, 1965) . If the inert gases nitrogen or carbon dioxide are present, the Equation (1) may still... gas cylinders with the exception of the air which was atmospheric. The carbon dioxide, methane, and nitrogen came from commercial sources in high- pressure cylinders. The low-BTU gas consisting of 20. 89% CO, 2 . 65% CH4, 0 . 2% C2H6, 15 . 37% H2...

Gaines, William Russell

1983-01-01T23:59:59.000Z

48

Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production  

DOE Patents [OSTI]

A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

1988-01-01T23:59:59.000Z

49

Gaseous reactor control system  

SciTech Connect (OSTI)

This paper describes a nuclear reactor control system for controlling the reactivity of the core of a nuclear reactor. It includes a control gas having a high neutron cross-section; a first tank containing a first supply of the control gas; a first conduit providing a first fluid passage extending into the core, the first conduit being operatively connected to communicate with the first tank; a first valve operatively connected to regulate the flow of the control gas between the first tank and the first conduit; a second conduit concentrically disposed around the first conduit such that a second fluid passage is defined between the outer surface of the first conduit and the inner surface of the second conduit; a second tank containing a second supply of the control gas, the second tank being operatively connected to communicate with the second fluid passage; a second supply valve operatively connected to regulate the flow of the control gas between the second tank and the second fluid passage.

Abdel-Khalik, S.

1991-09-03T23:59:59.000Z

50

Program plan for evaluation and remediation of the generation and release of flammable gases in Hanford Site waste tanks  

SciTech Connect (OSTI)

This program plan describes the activities being conducted for the resolution of the flammable gas problem that is associated with 23 high-level waste tanks at the Hanford Site. The classification of the wastes in all of these tanks is not final and some wastes may not be high-level wastes. However, until the characterization and classification is complete, all the tanks are treated as if they contain high-level waste. Of the 23 tanks, Tank 241-SY-101 (referred to as Tank 101-SY) has exhibited significant episodic releases of flammable gases (hydrogen and nitrous oxide) for the past 10 years. The major near-term focus of this program is for the understanding and stabilization of this tank. An understanding of the mechanism for gas generation and the processes for the episodic release will be obtained through sampling of the tank contents, laboratory studies, and modeling of the tank behavior. Additional information will be obtained through new and upgraded instrumentation for the tank. A number of remediation, or stabilization, concepts will be evaluated for near-term (2 to 3 years) applications to Tank 101-SY. Detailed safety assessments are required for all activities that will occur in the tank (sampling, removal of equipment, and addition of new instruments). This program plan presents a discussion of each task, provides schedules for near-term activities, and gives a summary of the expected work for fiscal years 1991, 1992, and 1993. 16 refs., 7 figs., 8 tabs.

Johnson, G.D. (comp.)

1991-08-01T23:59:59.000Z

51

Flammable gas issues in double-contained receiver tanks. Revision 2  

SciTech Connect (OSTI)

Four double-contained receiver tanks (DCRTs) at Hanford will be used to store salt-well pumped liquids from tanks on the Flammable Gas Watch List. This document was created to serve as a reference document describing the current knowledge of flammable gas issues in DCRTs. The document identifies, describes, evaluates, and attempts to quantify potential gas carryover and release mechanisms. It estimates several key parameters needed for these calculations, such as initial aqueous concentrations and ventilation rate, and evaluates the uncertainty in those estimates. It justifies the use of the Schumpe model for estimating vapor-liquid equilibrium constants. It identifies several potential waste compatibility issues (such as mixing and pH or temperature changes) that could lead to gas release and provides a basis for calculating their effects. It evaluates the potential for gas retention in precipitated solids within a DCRT and whether retention could lead to a buoyant displacement instability (rollover) event. It discusses rates of radiolytic, thermal, and corrosive hydrogen generation within the DCRT. It also describes in detail the accepted method of calculating the lower flammability limit (LFL) for mixtures of flammable gases. The report incorporates these analyses into two models for calculating headspace flammability, one based on instantaneous equilibrium between dissolved gases and the headspace and one incorporating limited release rates based on mass-transfer considerations. Finally, it demonstrates the use of both models to estimate headspace flammable gas concentrations and minimum ventilation rates required to maintain concentrations below 25% of the LFL.

Peurrung, L.M.; Mahoney, L.A.; Stewart, C.W.; Gauglitz, P.A.; Pederson, L.R.; Bryan, S.A.; Shepard, C.L.

1998-08-01T23:59:59.000Z

52

Simulating the Gaseous Halos of Galaxies  

E-Print Network [OSTI]

Observations of local X-ray absorbers, high-velocity clouds, and distant quasar absorption line systems suggest that a significant fraction of baryons may reside in multi-phase, low-density, extended, ~100 kpc, gaseous halos around normal galaxies. We present a pair of high-resolution SPH (smoothed particle hydrodynamics) simulations that explore the nature of cool gas infall into galaxies, and the physical conditions necessary to support the type of gaseous halos that seem to be required by observations. The two simulations are identical other than their initial gas density distributions: one is initialized with a standard hot gas halo that traces the cuspy profile of the dark matter, and the other is initialized with a cored hot halo with a high central entropy, as might be expected in models with early pre-heating feedback. Galaxy formation proceeds in dramatically different fashions in these two cases. While the standard cuspy halo cools rapidly, primarily from the central region, the cored halo is quasi-stable for ~4 Gyr and eventually cools via the fragmentation and infall of clouds from ~100 kpc distances. After 10 Gyr of cooling, the standard halo's X-ray luminosity is ~100 times current limits and the resultant disk galaxy is twice as massive as the Milky Way. In contrast, the cored halo has an X-ray luminosity that is in line with observations, an extended cloud population reminiscent of the high-velocity cloud population of the Milky Way, and a disk galaxy with half the mass and ~50% more specific angular momentum than the disk formed in the low-entropy simulation. These results suggest that the distribution and character of halo gas provides an important testing ground for galaxy formation models and may be used to constrain the physics of galaxy formation.

Tobias Kaufmann; James S. Bullock; Ari Maller; Taotao Fang

2008-01-28T23:59:59.000Z

53

Hydrogen and Gaseous Fuel Safety and Toxicity  

SciTech Connect (OSTI)

Non-traditional motor fuels are receiving increased attention and use. This paper examines the safety of three alternative gaseous fuels plus gasoline and the advantages and disadvantages of each. The gaseous fuels are hydrogen, methane (natural gas), and propane. Qualitatively, the overall risks of the four fuels should be close. Gasoline is the most toxic. For small leaks, hydrogen has the highest ignition probability and the gaseous fuels have the highest risk of a burning jet or cloud.

Lee C. Cadwallader; J. Sephen Herring

2007-06-01T23:59:59.000Z

54

Enforcement Documents - Portsmouth Gaseous Diffusion Plant |...  

Broader source: Energy.gov (indexed) [DOE]

Gaseous Diffusion Plant March 26, 2010 Enforcement Letter, Geiger Brothers Mechanical Contractors, INC - March 26, 2010 Issued to Geiger Brothers Mechanical Contractors,...

55

Independent Activity Report, Portsmouth Gaseous Diffusion Plant...  

Broader source: Energy.gov (indexed) [DOE]

2011 August 2011 Orientation Visit to the Portsmouth Gaseous Diffusion Plant HIAR-PORTS-2011-08-03 This Independent Activity Report documents an operational awareness...

56

Summary of flammable gas hazard and potential consequences in tank waste remediation system facility at the Hanford site  

SciTech Connect (OSTI)

This document provides a summary of the flammable gas program since 1992. It provides the best understanding of generation, retention, release of flammable gases. It gives a composition for each of the flammable gas tanks, calculates postulated concentrations in the event of a release, calculates the pressure obtained during a burn, and provides radiological and toxicological consequences. Controls from the analysis are found in WHC-SD-WM-SAR-067.

Van Vleet, R.J., Westinghouse Hanford

1996-12-11T23:59:59.000Z

57

Solid and gaseous fuels. [Review  

SciTech Connect (OSTI)

This review covers methods of sampling, analyzing, and testing coal, coke, and coal-derived solids. Energy Research Abstracts and Chemical Abstracts were used as reference sources. The volume of material available made it necessary to limit the number of publications in the review. This review also surveys publications concerned with methods for the chemical, physical, and instrumental analyses of gaseous fuels and related materials. Articles of significance appearing in foreign journals and the patent literature that were not available at the time of the last review are also included. Chemical Abstracts and Energy Research Abstracts were used extensively as reference sources. Some selectivity was necessary in order to include the most pertinent publications in preparing this review. 386 references.

Schultz, H.; Wells, A.W.; Mima, M.J.

1985-04-01T23:59:59.000Z

58

Process for exchanging hydrogen isotopes between gaseous hydrogen and water  

DOE Patents [OSTI]

A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

1980-08-12T23:59:59.000Z

59

Engineering task plan for flammable gas atmosphere mobile color video camera systems  

SciTech Connect (OSTI)

This Engineering Task Plan (ETP) describes the design, fabrication, assembly, and testing of the mobile video camera systems. The color video camera systems will be used to observe and record the activities within the vapor space of a tank on a limited exposure basis. The units will be fully mobile and designed for operation in the single-shell flammable gas producing tanks. The objective of this tank is to provide two mobile camera systems for use in flammable gas producing single-shell tanks (SSTs) for the Flammable Gas Tank Safety Program. The camera systems will provide observation, video recording, and monitoring of the activities that occur in the vapor space of applied tanks. The camera systems will be designed to be totally mobile, capable of deployment up to 6.1 meters into a 4 inch (minimum) riser.

Kohlman, E.H.

1995-01-25T23:59:59.000Z

60

Development of Compact Gaseous Sensors with Internal Reference...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Compact Gaseous Sensors with Internal Reference for Monitoring O2 and NOx in Combustion Environments Development of Compact Gaseous Sensors with Internal Reference for Monitoring...

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Non-Destructive Analysis Calibration Standards for Gaseous Diffusion...  

Broader source: Energy.gov (indexed) [DOE]

Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP)...

62

Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels, Phase 2: Evaluations of Field Samples and Laboratory Blends  

SciTech Connect (OSTI)

Study to measure the flammability of gasoline/ethanol fuel vapors at low ambient temperatures and develop a mathematical model to predict temperatures at which flammable vapors were likely to form.

Gardiner, D. P.; Bardon, M. F.; LaViolette, M.

2010-04-01T23:59:59.000Z

63

Gaseous Detectors: recent developments and applications  

E-Print Network [OSTI]

Since long time, the compelling scientific goals of future high energy physics experiments were a driving factor in the development of advanced detector technologies. A true innovation in detector instrumentation concepts came in 1968, with the development of a fully parallel readout for a large array of sensing elements - the Multiwire Proportional Chamber (MWPC), which earned Georges Charpak a Nobel prize in physics in 1992. Since that time radiation detection and imaging with fast gaseous detectors, capable of economically covering large detection volume with low mass budget, have been playing an important role in many fields of physics. Advances in photo-lithography and micro-processing techniques in the chip industry during the past decade triggered a major transition in the field of gas detectors from wire structures to Micro-Pattern Gas Detector (MPGD) concepts, revolutionizing cell size limitations for many gas detector applications. The high radiation resistance and excellent spatial and time resolution make them an invaluable tool to confront future detector challenges at the next generation of colliders. The design of the new micro-pattern devices appears suitable for industrial production. Novel structures where MPGDs are directly coupled to the CMOS pixel readout represent an exciting field allowing timing and charge measurements as well as precise spatial information in 3D. Originally developed for the high energy physics, MPGD applications has expanded to nuclear physics, UV and visible photon detection, astroparticle and neutrino physics, neutron detection and medical physics.

Maxim Titov

2010-08-24T23:59:59.000Z

64

Origin of gaseous hydrocarbons in east-central Texas groundwaters  

E-Print Network [OSTI]

; Follett, 1974). The high transmissivity and sandy lithology of the Sparta are much like those of the Queen City, as is the quality of water. 40 LIGNITE STREAKS 30 Laminated and discontinuous lenticular. Trough cross bedded siltstones. 20 ROAD l... hydrocarbons simply reflects a difference in the 5 C of the substrate. Sparta lignite is about 7%%do enriched in ' C relative to Yegua lignite, comparable to the difference seen in the gaseous hydrocarbons. ACKNOWLEDGMENTS I would like to thank Dr. Steven...

Coffman, Bryan Keith

1988-01-01T23:59:59.000Z

65

Flammability of selected heat resistant alloys in oxygen gas mixtures  

SciTech Connect (OSTI)

Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

Zawierucha, R.; McIlroy, K.; Million, J.F. [Praxair, Inc., Tonawanda, NY (United States)

1995-12-31T23:59:59.000Z

66

EFFECTS OF HYDROGEN ADDITION ON THE MARKSTEIN LENGTH AND FLAMMABILITY LIMIT  

E-Print Network [OSTI]

combustion at lean mixture conditions. In the case of natural gas engines, enriching the fuel with hydrogenEFFECTS OF HYDROGEN ADDITION ON THE MARKSTEIN LENGTH AND FLAMMABILITY LIMIT OF STRETCHED METHANE, Ann Arbor, MI, USA A computational study is performed to investigate the effects of hydrogen addition

Im, Hong G.

67

Effect of Hydrogen Addition on the Flammability Limit of Stretched Methane/Air Premixed Flames  

E-Print Network [OSTI]

], thereby enabling stable combustion at lean mixture conditions. In the case of natural gas engines, enriching the fuel with hydrogen has the proven benefits of improving the combustion stability and reducingEffect of Hydrogen Addition on the Flammability Limit of Stretched Methane/Air Premixed Flames

Im, Hong G.

68

MESERAN Test Results for Elimination of Flammable Solvents in Wipe Applications at Pantex  

SciTech Connect (OSTI)

In recent years, efforts have been made within the nuclear weapons complex (National Nuclear Security Administration) of the Department of Energy (DOE) to replace Resource Conservation and Recovery Act (RCRA) regulated solvents (i.e., flammable, toxic, corrosive, and reactive) and ozone-depleting chemicals (ODC) with more benign alternatives. Within the National Nuclear Security Administration (NNSA) and the Department of Defense (DoD) sectors, these solvents are used for cleaning hardware during routine maintenance operations. A primary goal of this study is to replace flammable solvents for wiping applications. Two cleaners, including a hydrofluoroether (HFE) and an azeotrope of the HFE and isopropyl alcohol (IPA), have been studied as potential replacements for flammable solvents. Cleaning efficacy, short-term and longterm materials compatibility, corrosion, drying times, flammability, environment, safety and health (ES&H) issues and accelerated aging studies are among the tests that are being conducted and that are used to screen candidate solvents by the interagency team performing this work. The results are compared to the traditionally used isopropyl alcohol, which serves as the baseline cleaner. This report details the results of MESERAN (Measurement and Evaluation of Surfaces by Evaporative Rate ANalysis) testing performed at the Kansas City Plant (KCP) to quantify the cleaning efficacy on samples contaminated with the various contaminants and cleaned by wiping with the various solvents being evaluated.

M. G. Benkovich

2005-03-30T23:59:59.000Z

69

Inert Gas Dilution Effect on the Flammability Limits of Hydrocarbon Mixtures  

E-Print Network [OSTI]

)????????????????????????..??...70 xii FIGURE Page 5.5 N-butane flammability properties with dilution of nitrogen (25 ?C and 1... and the regressed linear curve...........................................................................................................83 5.15 Experimental n-butane LFL diluted with N2 and the regressed linear curve..????????....????????????????...84 5...

Zhao, Fuman

2012-02-14T23:59:59.000Z

70

Flammable gas issues in double-contained receiver tanks. Revision 1  

SciTech Connect (OSTI)

Four double-contained receiver tanks (DCRTs) at Hanford will be used to store salt-well pumped liquids from tanks on the Flammable Gas Watch List. This document was created to serve as a technical basis or reference document for flammable gas issues in DCRTs. The document identifies, describes, evaluates, and attempts to quantify potential gas carryover and release mechanisms. It estimates several key parameters needed for these calculations, such as initial aqueous concentrations and ventilation rate, and evaluates the uncertainty in those estimates. It justifies the use of the Schumpe model for estimating vapor-liquid equilibrium constants. It identifies several potential waste compatibility issues (such as mixing and pH or temperature changes) that could lead to gas release and provides a basis for calculating their effects. It evaluates the potential for gas retention in precipitated solids within a DCRT and whether retention could lead to a buoyant displacement instability (rollover) event. It discusses rates of radiolytic, thermal, and corrosive hydrogen generation within the DCRT. It also describes in detail the accepted method of calculating the lower flammability limit (LFL) for mixtures of flammable gases.

Peurrung, L.M.; Mahoney, L.A.; Stewart, C.W.; Gauglitz, P.A.; Pederson, L.R.; Bryan, S.A.; Shepard, C.L.

1998-06-01T23:59:59.000Z

71

Onsite Gaseous Centrifuge Enrichment Plant UF6 Cylinder Destructive Analysis  

SciTech Connect (OSTI)

The IAEA safeguards approach for gaseous centrifuge enrichment plants (GCEPs) includes measurements of gross, partial, and bias defects in a statistical sampling plan. These safeguard methods consist principally of mass and enrichment nondestructive assay (NDA) verification. Destructive assay (DA) samples are collected from a limited number of cylinders for high precision offsite mass spectrometer analysis. DA is typically used to quantify bias defects in the GCEP material balance. Under current safeguards measures, the operator collects a DA sample from a sample tap following homogenization. The sample is collected in a small UF6 sample bottle, then sealed and shipped under IAEA chain of custody to an offsite analytical laboratory. Current practice is expensive and resource intensive. We propose a new and novel approach for performing onsite gaseous UF6 DA analysis that provides rapid and accurate assessment of enrichment bias defects. DA samples are collected using a custom sampling device attached to a conventional sample tap. A few micrograms of gaseous UF6 is chemically adsorbed onto a sampling coupon in a matter of minutes. The collected DA sample is then analyzed onsite using Laser Ablation Absorption Ratio Spectrometry-Destructive Assay (LAARS-DA). DA results are determined in a matter of minutes at sufficient accuracy to support reliable bias defect conclusions, while greatly reducing DA sample volume, analysis time, and cost.

Anheier, Norman C.; Cannon, Bret D.; Qiao, Hong (Amy) [Amy; Carter, Jennifer C.; McNamara, Bruce K.; O'Hara, Matthew J.; Phillips, Jon R.; Curtis, Michael M.

2012-07-17T23:59:59.000Z

72

Infrared scintillation yield in gaseous and liquid argon  

E-Print Network [OSTI]

The study of primary and secondary scintillations in noble gases and liquids is of paramount importance to rare-event experiments using noble gas media. In the present work, the scintillation yield in gaseous and liquid Ar has for the first time been measured in the near infrared (NIR) and visible region, both for primary and secondary (proportional) scintillations, using Geiger-mode avalanche photodiodes (G-APDs) and pulsed X-ray irradiation. The primary scintillation yield of the fast component was measured to be 17000 photon/MeV in gaseous Ar in the NIR, in the range of 690-1000 nm, and 510 photon/MeV in liquid Ar, in the range of 400-1000 nm. Proportional NIR scintillations (electroluminescence) in gaseous Ar have been also observed; their amplification parameter at 163 K was measured to be 13 photons per drifting electron per kV. Possible applications of NIR scintillations in high energy physics experiments are discussed.

A. Buzulutskov; A. Bondar; A. Grebenuk

2011-04-19T23:59:59.000Z

73

Flammable gas double shell tank expert elicitation presentations (Part A and Part B)  

SciTech Connect (OSTI)

This document is a compilation of presentation packages and white papers for the Flammable Gas Double Shell Tank Expert Elicitation Workshop {number_sign}2. For each presentation given by the different authors, a separate section was developed. The purpose for issuing these workshop presentation packages and white papers as a supporting document is to provide traceability and a Quality Assurance record for future reference to these packages.

Bratzel, D.R.

1998-04-17T23:59:59.000Z

74

Results of gas monitoring of double-shell flammable gas watch list tanks  

SciTech Connect (OSTI)

Tanks 103-SY; 101-AW; 103-, 104-, and 105-AN are on the Flammable Gas Watch List. Recently, standard hydrogen monitoring system (SHMS) cabinets have been installed in the vent header of each of these tanks. Grab samples have been taken once per week, and a gas chromatograph was installed on tank 104-AN as a field test. The data that have been collected since gas monitoring began on these tanks are summarized in this document.

Wilkins, N.E.

1995-01-19T23:59:59.000Z

75

Cleaning and materials compatibility test results for elimination of flammable solvents in wipe applications.  

SciTech Connect (OSTI)

In recent years, efforts have been made within the nuclear weapons complex (National Nuclear Security Administration) of the Department of Energy (DOE) to replace Resource Conservation and Recovery Act (RCRA) regulated solvents (i.e., flammable, toxic, corrosive, and reactive) and ozone-depleting chemicals (ODC) with more benign alternatives. Within the National Nuclear Security Administration (NNSA) and the Department of Defense (DoD) sectors, these solvents are used for cleaning hardware during routine maintenance operations. A primary goal of this study is to replace flammable solvents used in wiping applications. Two cleaners, including a hydrofluoroether (HFE) and an azeotrope of the HFE and isopropyl alcohol (IPA), have been studied as potential replacements for flammable solvents. Cleaning efficacy, short-term and long-term materials compatibility, corrosion, drying times, flammability, environment, safety and health (ES&H) and accelerated aging issues were among the experiments used to screen candidate solvents by the interagency team performing this work. This report presents cleaning efficacy results as determined by the contact angle Goniometer as well as materials compatibility results of various metal alloys and polymers. The results indicate that IPA (baseline cleaner) and the HFE/IPA azeotrope are roughly equivalent in their ability to remove fluorinated grease, silicone grease, and a simulated finger print contaminant from various metal alloys. All of the ASTM sandwich and immersion corrosion tests with IPA, HFE or the HFE/IPA azeotrope on metal alloys showed no signs of corrosion. Furthermore, no deleterious effects were noted for polymeric materials immersed in IPA, HFE, or the HFE/IPA azeotrope.

Lopez, Edwin Paul

2005-06-01T23:59:59.000Z

76

Equipment design guidance document for flammable gas waste storage tank new equipment  

SciTech Connect (OSTI)

This document is intended to be used as guidance for design engineers who are involved in design of new equipment slated for use in Flammable Gas Waste Storage Tanks. The purpose of this document is to provide design guidance for all new equipment intended for application into those Hanford storage tanks in which flammable gas controls are required to be addressed as part of the equipment design. These design criteria are to be used as guidance. The design of each specific piece of new equipment shall be required, as a minimum to be reviewed by qualified Unreviewed Safety Question evaluators as an integral part of the final design approval. Further Safety Assessment may be also needed. This guidance is intended to be used in conjunction with the Operating Specifications Documents (OSDs) established for defining work controls in the waste storage tanks. The criteria set forth should be reviewed for applicability if the equipment will be required to operate in locations containing unacceptable concentrations of flammable gas.

Smet, D.B.

1996-04-11T23:59:59.000Z

77

A safety assessment of rotary mode core sampling in flammable gas single shell tanks: Hanford Site, Richland, Washington  

SciTech Connect (OSTI)

This safety assessment (SA) addresses each of the required elements associated with the installation, operation, and removal of a rotary-mode core sampling (RMCS) device in flammable-gas single-shell tanks (SSTs). The RMCS operations are needed in order to retrieve waste samples from SSTs with hard layers of waste for which push-mode sampling is not adequate for sampling. In this SA, potential hazards associated with the proposed action were identified and evaluated systematically. Several potential accident cases that could result in radiological or toxicological gas releases were identified and analyzed and their consequences assessed. Administrative controls, procedures and design changes required to eliminate or reduce the potential of hazards were identified. The accidents were analyzed under nine categories, four of which were burn scenarios. In SSTS, burn accidents result in unacceptable consequences because of a potential dome collapse. The accidents in which an aboveground burn propagates into the dome space were shown to be in the ``beyond extremely unlikely`` frequency category. Given the unknown nature of the gas-release behavior in the SSTS, a number of design changes and administrative controls were implemented to achieve these low frequencies. Likewise, drill string fires and dome space fires were shown to be very low frequency accidents by taking credit for the design changes, controls, and available experimental and analytical data. However, a number of Bureau of Mines (BOM) tests must be completed before some of the burn accidents can be dismissed with high confidence. Under the category of waste fires, the possibility of igniting the entrapped gases and the waste itself were analyzed. Experiments are being conducted at the BOM to demonstrate that the drill bit is not capable of igniting the trapped gas in the waste. Laboratory testing and thermal analysis demonstrated that, under normal operating conditions, the drill bit will not create high enough temperatures to initiate a propagating reaction in the waste. However, system failure that coincides in a waste layer with high organic content and low moisture may initiate an exothermic reaction in the waste. Consequently, a conservative approach based on the current state of the knowledge resulted in limiting the drilling process to a subset of the flammable-gas tanks. Accidents from the chemical reactions and criticality category are shown to result in acceptable risk. A number of accidents are shown to potentially result in containment (tank liner) breach below the waste level. Mitigative features are provided for these accidents. Gas-release events without burn also are analyzed, and radiological and toxicological consequences are shown to be within risk guidelines. Finally, the consequences of potential spills are shown to be within the risk guidelines.

Raymond, R.E.

1996-04-15T23:59:59.000Z

78

Gaseous Hydrogen Delivery Breakout- Strategic Directions for Hydrogen Delivery Workshop  

Broader source: Energy.gov [DOE]

Targets, barriers and research and development priorities for gaseous delivery of hydrogen through hydrogen and natural gas pipelines.

79

Gaseous modification of MCrAlY coatings  

DOE Patents [OSTI]

The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

2000-01-01T23:59:59.000Z

80

7, 1598916022, 2007 Gaseous sulphur  

E-Print Network [OSTI]

on the transport and dispersion of the atmospheric pollutants, and leads to high pollution levels near the ground.atmos-chem-phys-discuss.net/7/15989/2007/ © Author(s) 2007. This work is licensed under a Creative Commons License. Atmospheric Chemistry and Physics Discussions Transport and dispersion of atmospheric sulphur dioxide from an industrial

Boyer, Edmond

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS  

SciTech Connect (OSTI)

This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating agent overestimate the value of the VOCs in a sample. By overestimating the VOC content of a sample, we want to minimize false negatives. A false negative is defined as incorrectly estimating the VOC content of the sample to be below programmatic action limits when, in fact, the sample,exceeds the action limits. The disadvantage of overestimating the flammable VOC content of a sample is that additional cost may be incurred because additional sampling and GC-MS analysis may be required to confirm results over programmatic action limits. Therefore, choosing an appropriate calibration standard for the Ar-PDHID is critical to avoid false negatives and to minimize additional analytical costs.

DOUGLAS, J.G.

2006-07-06T23:59:59.000Z

82

Diffusion method of seperating gaseous mixtures  

DOE Patents [OSTI]

A method of effecting a relatively large change in the relative concentrations of the components of a gaseous mixture by diffusion which comprises separating the mixture into heavier and lighter portions according to major fraction mass recycle procedure, further separating the heavier portions into still heavier subportions according to a major fraction mass recycle procedure, and further separating the lighter portions into still lighter subportions according to a major fraction equilibrium recycle procedure.

Pontius, Rex B. (Rochester, NY)

1976-01-01T23:59:59.000Z

83

Uranium enrichment export control guide: Gaseous diffusion  

SciTech Connect (OSTI)

This document was prepared to serve as a guide for export control officials in their interpretation, understanding, and implementation of export laws that relate to the Zangger International Trigger List for gaseous diffusion uranium enrichment process components, equipment, and materials. Particular emphasis is focused on items that are especially designed or prepared since export controls are required for these by States that are party to the International Nuclear Nonproliferation Treaty.

Not Available

1989-09-01T23:59:59.000Z

84

Report on ignitability testing of flammable gasses in a core sampling drill string  

SciTech Connect (OSTI)

This document describes the results from testing performed at the Pittsburgh Research Center to determine the effects of an ignition of flammable gasses contained in a core sampling drill string. Testing showed that 1) An ignition of stoichiometric hydrogen and air in a vented 30 or 55 ft length of drill string will not force 28`` or more of water out the bottom of the drill string, and 2) An ignition of this same gas mixture will not rupture a vented or completely sealed drill string.

Witwer, K.S., Westinghouse Hanford

1996-12-01T23:59:59.000Z

85

Flammability issues of mixtures: If you hold a match over pure MeOH in air a fire is likely because the MeOH  

E-Print Network [OSTI]

% Methanol and up would produce a combustible vapor above its surface and if there is a source near, For Methanol: Flash point = 12.22 °C Upper Flammability Temperature = 43 °C Lower Flammability Temperature = 7 Temperature = 350 °C (Source: The Methanol Institute, Washington, DC 20006 - http://www.methanol

Sethuraman, Vijay A.

86

Emission and Long-Range Transport of Gaseous Mercury from a  

E-Print Network [OSTI]

Emission and Long-Range Transport of Gaseous Mercury from a Large-Scale Canadian Boreal Forest FireQuebec.Thesemeasurementsindicated significant and highly correlated increases in Hg and CO during the plume event. The Hg:CO emissions ratio emissions and biomass burned to determine a mean area-based Hg emission flux density for boreal forest fires

Lee, Xuhui

87

ASSESSMENT OF THE IMPACT OF TOA PARTITIONING ON DWPF MELTER OFF-GAS FLAMMABILITY  

SciTech Connect (OSTI)

An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of increasing the amount of TOA in the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process. The results of this study showed that the concentrations of nonvolatile carbon of the current solvent limit (150 ppm) in the Slurry Mix Evaporator (SME) product would be about 7% higher and the nonvolatile hydrogen would be 2% higher than the actual current solvent (126 ppm) with an addition of up to 3 ppm of TOA when the concentration of Isopar? L in the effluent transfer is controlled below 87 ppm and the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle. Therefore, the DWPF melter off-gas flammability assessment is conservative for up to an additional 3 ppm of TOA in the effluent based on these assumptions. This report documents the calculations performed to reach this conclusion.

Daniel, G.

2013-06-18T23:59:59.000Z

88

Band Formation during Gaseous Diffusion in Aerogels  

E-Print Network [OSTI]

We study experimentally how gaseous HCl and NH_3 diffuse from opposite sides of and react in silica aerogel rods with porosity of 92 % and average pore size of about 50 nm. The reaction leads to solid NH_4Cl, which is deposited in thin sheet-like structures. We present a numerical study of the phenomenon. Due to the difference in boundary conditions between this system and those usually studied, we find the sheet-like structures in the aerogel to differ significantly from older studies. The influence of random nucleation centers and inhomogeneities in the aerogel is studied numerically.

M. A. Einarsrud; F. A. Maao; A. Hansen; M. Kirkedelen; J. Samseth

1997-06-18T23:59:59.000Z

89

Thermal conductivity of graphene nanoribbons in noble gaseous environments  

SciTech Connect (OSTI)

We investigate the thermal conductivity of suspended graphene nanoribbons in noble gaseous environments using molecular dynamics simulations. It is reported that the thermal conductivity of perfect graphene nanoribbons decreases with the gaseous pressure. The decreasing is more obvious for the noble gas with large atomic number. However, the gaseous pressure cannot change the thermal conductivity of defective graphene nanoribbons apparently. The phonon spectra of graphene nanoribbons are also provided to give corresponding supports.

Zhong, Wei-Rong, E-mail: wrzhong@hotmail.com; Xu, Zhi-Cheng; Zheng, Dong-Qin [Department of Physics and Siyuan Laboratory, College of Science and Engineering, Jinan University, Guangzhou 510632 (China); Ai, Bao-Quan, E-mail: aibq@scnu.edu.cn [Laboratory of Quantum Information Technology, ICMP and SPTE, South China Normal University, Guangzhou 510006 (China)

2014-02-24T23:59:59.000Z

90

Orientation Visit to the Portsmouth Gaseous Diffusion Plant  

Office of Environmental Management (EM)

Analysis (DSA) and Technical Safety Requirements (TSR) for Portsmouth Gaseous Diffusion Plant Category 2 Non-leased Facilities: X-345 Special Nuclear Material Storage Facility;...

91

Report on the handling of safety information concerning flammable gases and ferrocyanide at the Hanford waste tanks  

SciTech Connect (OSTI)

This report discusses concerns safety issues, and management at Hanford Tank Farm. Concerns center on the issue of flammable gas generation which could ignite, and on possible exothermic reactions of ferrocyanide compounds which were added to single shell tanks in the 1950's. It is believed that information concerning these issues has been mis-handled and the problems poorly managed. (CBS)

Not Available

1990-07-01T23:59:59.000Z

92

Responding to Terrorist Incidents in Your Community: Flammable-Liquid Fire Fighting Techniques for Municipal and Rural Firefighters  

SciTech Connect (OSTI)

The University of Nevada, Reno Fire Science Academy (FSA) applied for grant funding to develop and deliver programs for municipal, rural, and volunteer firefighters. The FSA specializes in preparing responders for a variety of emergency events, including flammable liquid fires resulting from accidents, intentional acts, or natural disasters. Live fire training on full scale burnable props is the hallmark of FSA training, allowing responders to practice critical skills in a realistic, yet safe environment. Unfortunately, flammable liquid live fire training is often not accessible to municipal, rural, or volunteer firefighters due to limited department training budgets, even though most department personnel will be exposed to flammable liquid fire incidents during the course of their careers. In response to this training need, the FSA developed a course during the first year of the grant (Year One), Responding to Terrorist Incidents in Your Community: Flammable-Liquid Fire Fighting Techniques for Municipal and Rural Firefighters. During the three years of the grant, a total of 2,029 emergency responders received this training. In Year Three, two new courses, a train-the-trainer for Responding to Terrorist Incidents in Your Community and Management of Large-Scale Disasters for Public Officials were developed and pilot tested during the Real-World Disaster Management Conference held at the FSA in June of 2007. Two research projects were conducted during Years Two and Three. The first, conducted over a two year period, evaluated student surveys regarding the value of the flammable liquids training received. The second was a needs assessment conducted for rural Nevada. Both projects provided important feedback and a basis for curricula development and improvements.

Denise Baclawski

2010-03-08T23:59:59.000Z

93

Data Observations on Double Shell Tank (DST) Flammable Gas Watch List Tank Behavior  

SciTech Connect (OSTI)

This report provides the data from the retained gas sampler, void fraction instrument, ball rheometer, standard hydrogen monitoring system, and other tank data pertinent to gas retention and release behavior in the waste stored in double-shelled Flammable Gas Watch List tanks at Hanford. These include tanks 241-AN-103,241-AN-104, 241-AN-105, 241-AW-101, 241-SY-101, and 241-SY-103. The tanks and the waste they contain are described in terms of fill history and chemistry. The results of mixer pump operation and recent waste transfers and back-dilution in SY-101 are also described. In-situ measurement and monitoring systems are described and the data are summarized under the categories of thermal behavior, waste configuration and properties, gas generation and composition, gas retention and historical gas release behavior.

HEDENGREN, D.C.

2000-09-28T23:59:59.000Z

94

High Flash-point Fluid Flow System Aerosol Flammability Study and Combustion Mechanism Analysis  

E-Print Network [OSTI]

understanding of this combustion process. The potential application of the ignition delay will be beneficial to the mitigation timing and detector sensor setting of facilities to prevent aerosol cloud fires. Finally, the scientific method of aerosol...

Huang, Szu-Ying

2013-12-02T23:59:59.000Z

95

Combustion characteristics of alternative gaseous fuels  

SciTech Connect (OSTI)

Fundamental flame properties of mixtures of air with hydrogen, carbon monoxide, and C{sub 1}C{sub 4} saturated hydrocarbons were studied both experimentally and numerically. The fuel mixtures were chosen in order to simulate alternative gaseous fuels and to gain insight into potential kinetic couplings during the oxidation of fuel mixtures. The studies included the use of the counterflow configuration for the determination of laminar flame speeds, as well as extinction and ignition limits of premixed flames. The experiments were modeled using the USC Mech II kinetic model. It was determined that when hydrocarbons are added to hydrogen flames as additives, flame ignition, propagation, and extinction are affected in a counterintuitive manner. More specifically, it was found that by substituting methane by propane or n-butane in hydrogen flames, the reactivity of the mixture is reduced both under pre-ignition and vigorous burning conditions. This behavior stems from the fact that propane and n-butane produce higher amounts of methyl radicals that can readily recombine with atomic hydrogen and reduce thus the rate of the H + O{sub 2} ? O + OH branching reaction. The kinetic model predicts closely the experimental data for flame propagation and extinction for various fuel mixtures and pressures, and for various amounts of carbon dioxide in the fuel blend. On the other hand, it underpredicts, in general, the ignition temperatures.

Park, O.; Veloo, Peter S.; Liu, N.; Egolfopoulos, Fokion N.

2011-01-01T23:59:59.000Z

96

Feasibility of gas-phase decontamination of gaseous diffusion equipment  

SciTech Connect (OSTI)

The five buildings at the K-25 Site formerly involved in the gaseous diffusion process contain 5000 gaseous diffusion stages as well as support facilities that are internally contaminated with uranium deposits. The gaseous diffusion facilities located at the Portsmouth Gaseous Diffusion Plant and the Paducah Gaseous Diffusion Plant also contain similar equipment and will eventually close. The decontamination of these facilities will require the most cost-effective technology consistent with the criticality, health physics, industrial hygiene, and environmental concerns; the technology must keep exposures to hazardous substances to levels as low as reasonably achievable (ALARA). This report documents recent laboratory experiments that were conducted to determine the feasibility of gas-phase decontamination of the internal surfaces of the gaseous diffusion equipment that is contaminated with uranium deposits. A gaseous fluorinating agent is used to fluorinate the solid uranium deposits to gaseous uranium hexafluoride (UF{sub 6}), which can be recovered by chemical trapping or freezing. The lab results regarding the feasibility of the gas-phase process are encouraging. These results especially showed promise for a novel decontamination approach called the long-term, low-temperature (LTLT) process. In the LTLT process: The equipment is rendered leak tight, evacuated, leak tested, and pretreated, charged with chlorine trifluoride (ClF{sub 3}) to subatmospheric pressure, left for an extended period, possibly > 4 months, while processing other items. Then the UF{sub 6} and other gases are evacuated. The UF{sub 6} is recovered by chemical trapping. The lab results demonstrated that ClF{sub 3} gas at subatmospheric pressure and at {approx} 75{degree}F is capable of volatilizing heavy deposits of uranyl fluoride from copper metal surfaces sufficiently that the remaining radioactive emissions are below limits.

Munday, E.B.; Simmons, D.W.

1993-02-01T23:59:59.000Z

97

Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants  

SciTech Connect (OSTI)

Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

Manohar S. Sohal; J. Stephen Herring

2008-07-01T23:59:59.000Z

98

Paducah Gaseous Diffusion Plant Northwest Plume interceptor system evaluation  

SciTech Connect (OSTI)

The Paducah Gaseous Diffusion Plant (PGDP) recently installed an interceptor system consisting of four wells, evenly divided between two well fields, to contain the Northwest Plume. As stated in the Northwest Plume Record of Decision (ROD), groundwater will be pumped at a rate to reduce further contamination and initiate control of the northwest contaminant plume. The objective of this evaluation was to determine the optimum (minimal) well field pumping rates required for plume hotspot containment. Plume hotspot, as defined in the Northwest Plume ROD and throughout this report, is that portion of the plume with trichloroethene (TCE) concentrations greater than 1,000 {micro}g/L. An existing 3-dimensional groundwater model was modified and used to perform capture zone analyses of the north and south interceptor system well fields. Model results suggest that the plume hotspot is not contained at the system design pumping rate of 100 gallons per minute (gal/min) per well field. Rather, the modeling determined that north and south well field pumping rates of 400 and 150 gal/min, respectively, are necessary for plume hotspot containment. The difference between the design and optimal pumping rates required for containment can be attributed to the discovery of a highly transmissive zone in the vicinity of the two well fields.

Laase, A.D.; Clausen, J.L.

1998-07-01T23:59:59.000Z

99

Lessons Learned from Practical Field Experience with High Pressure Gaseous  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10 DOEWashington,LM-04-XXXXLocatedMakes A09Projects at

100

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

Ghate, Madhav R. (Morgantown, WV); Yang, Ralph T. (Williamsville, NY)

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

Ghate, M.R.; Yang, R.T.

1985-10-03T23:59:59.000Z

102

Integration of the Uncertainties of Anion and TOC Measurements into the Flammability Control Strategy for Sludge Batch 8 at the DWPF  

SciTech Connect (OSTI)

The Savannah River National Laboratory (SRNL) has been working with the Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) in the development and implementation of a flammability control strategy for DWPFs melter operation during the processing of Sludge Batch 8 (SB8). SRNLs support has been in response to technical task requests that have been made by SRRs Waste Solidification Engineering (WSE) organization. The flammability control strategy relies on measurements that are performed on Slurry Mix Evaporator (SME) samples by the DWPF Laboratory. Measurements of nitrate, oxalate, formate, and total organic carbon (TOC) standards generated by the DWPF Laboratory are presented in this report, and an evaluation of the uncertainties of these measurements is provided. The impact of the uncertainties of these measurements on DWPFs strategy for controlling melter flammability also is evaluated. The strategy includes monitoring each SME batch for its nitrate content and its TOC content relative to the nitrate content and relative to the antifoam additions made during the preparation of the SME batch. A linearized approach for monitoring the relationship between TOC and nitrate is developed, equations are provided that integrate the measurement uncertainties into the flammability control strategy, and sample calculations for these equations are shown to illustrate the impact of the uncertainties on the flammability control strategy.

Edwards, T. B.

2013-03-14T23:59:59.000Z

103

STAR FORMATION IN THE EXTENDED GASEOUS DISK OF THE ISOLATED GALAXY CIG 96  

SciTech Connect (OSTI)

We study the Kennicutt-Schmidt star formation law and efficiency in the gaseous disk of the isolated galaxy CIG 96 (NGC 864), with special emphasis on its unusually large atomic gas (H I) disk (r{sub Hmathsci}/r{sub 25} = 3.5, r{sub 25} = 1.'85). We present deep Galaxy Evolution Explorer near- and far-UV observations, used as a recent star formation tracer, and we compare them with new, high-resolution (16''or 1.6 kpc) Very Large Array H I observations. The UV and H I maps show good spatial correlation outside the inner 1', where the H I phase dominates over H{sub 2}. Star-forming regions in the extended gaseous disk are mainly located along the enhanced H I emission within two (relatively) symmetric, giant gaseous spiral arm-like features, which emulate an H I pseudo-ring at r {approx_equal} 3'. Inside this structure, two smaller gaseous spiral arms extend from the northeast and southwest of the optical disk and connect to the previously mentioned H I pseudo-ring. Interestingly, we find that the (atomic) Kennicutt-Schmidt power-law index systematically decreases with radius, from N {approx_equal} 3.0 {+-} 0.3 in the inner disk (0.'8-1.'7) to N = 1.6 {+-} 0.5 in the outskirts of the gaseous disk (3.'3-4.'2). Although the star formation efficiency (SFE), the star formation rate per unit of gas, decreases with radius where the H I component dominates as is common in galaxies, we find that there is a break of the correlation at r = 1.5r{sub 25}. At radii 1.5r{sub 25} < r < 3.5r{sub 25}, mostly within the H I pseudo-ring structure, regions exist whose SFE remains nearly constant, SFE {approx_equal} 10{sup -11} yr{sup -1}. We discuss possible mechanisms that might be triggering the star formation in the outskirts of this galaxy, and we suggest that the constant SFE for such large radii (r > 2r{sub 25}) and at such low surface densities might be a common characteristic in extended UV disk galaxies.

Espada, D.; Sabater, J.; Verdes-Montenegro, L.; Sulentic, J. [Instituto de Astrofisica de AndalucIa, CSIC, Apdo. 3004, 18080 Granada (Spain); Munoz-Mateos, J. C.; Gil de Paz, A. [Departamento de Astrofisica y CC. de la Atmosfera, Universidad Complutense de Madrid, Avda. de la Complutense, s/n, E-28040 Madrid (Spain); Boissier, S.; Athanassoula, E.; Bosma, A. [Laboratoire d'Astrophysique de Marseille, OAMP, Universite Aix-Marseille and CNRS UMR 6110, 38 rue Frederic Joliot-Curie, 13388 Marseille Cedex 13 (France); Verley, S. [Dept. de Fisica Teorica y del Cosmos, Universidad de Granada, Granada (Spain); Leon, S. [Joint ALMA Observatory/ESO, Av. Alonso de Cordova 3107, Vitacura, Santiago (Chile); Yun, M., E-mail: daniel.espada@nao.ac.jp, E-mail: despada@cfa.harvard.edu [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States)

2011-07-20T23:59:59.000Z

104

MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1  

E-Print Network [OSTI]

2 MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1 , L. Loyon2 , F. Guiziou2 , P to measure emissions factors of ammonia (NH3), nitrous oxide (N2O) methane (CH4) and carbon dioxide (CO2) from stored pig slurry and measured the variations of the emissions in time and space. In 2006, dynamic

Boyer, Edmond

105

Separation phenomenon in the Windowless Gaseous Tritium Source of KATRIN  

E-Print Network [OSTI]

Separation phenomenon in the Windowless Gaseous Tritium Source of KATRIN experiment. Ternary separa- tion. In the KATRIN experiment, in order to analyze the spectrum of electrons emmited by Tritium decay, it is very important to know the concentration distribution of Tritium along the source

Sharipov, Felix

106

Test of potential homogeneity in the KATRIN gaseous tritium source  

E-Print Network [OSTI]

83mKr is supposed to be used to study the properties of the windowless gaseous tritium source of the experiment KATRIN. In this work we deduce the amount of 83mKr which is necessary to determine possible potential inhomogeneities via conversion-electron-line broadening.

M. Rysavy

2005-06-02T23:59:59.000Z

107

THE POSSIBILITY OF PRODUCING THERMONUCLEAR REACTIONS IN A GASEOUS DISCHARGE*  

E-Print Network [OSTI]

THE POSSIBILITY OF PRODUCING THERMONUCLEAR REACTIONS IN A GASEOUS DISCHARGE* I.V. Kurchatov of the energy of thermonuclear reactions. Physicists the world over are attracted by the extraordinarily interest- ing and very difficult task of controlling thermonuclear reactiom. Investigations in this field

108

Methods for deacidizing gaseous mixtures by phase enhanced absorption  

DOE Patents [OSTI]

An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

Hu, Liang

2012-11-27T23:59:59.000Z

109

Development of a Field Design for In Situ Gaseous Treatment of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Field Design for In Situ Gaseous Treatment of Sediment Based on Laboratory Column Test Data. Development of a Field Design for In Situ Gaseous Treatment of Sediment Based on...

110

Technologies for Gaseous Fueled Advanced Reciprocating Engine...  

Broader source: Energy.gov (indexed) [DOE]

gas, etc. Leaner Operation 1.0 Rich-burn 0.65 to 0.7 Lean-burn 42% Turbo-charged No aftertreatment 36% High EGR Turbo-charged 3-way catalyst 1...

111

NOVEL TECHNOLOGIES FOR GASEOUS CONTAMINANTS CONTROL  

SciTech Connect (OSTI)

The overall objective of this project is to develop technologies for cleaning/conditioning the syngas from an integrated gasification combined cycle (IGCC) system to meet the tolerance limits for contaminants such as H{sub 2}S, COS, NH{sub 3}, HCN, HCl, and alkali for fuel cell and chemical production applications. RTI's approach is to develop a modular system that (1) removes reduced sulfur species to sub-ppm levels using a hybrid process consisting of a polymer membrane and a regenerable ZnO-coated monolith or a mixed metal oxide sorbent; (2) removes hydrogen chloride vapors to sub-ppm levels using an inexpensive, high-surface area material; and (3) removes NH{sub 3} with acidic adsorbents. RTI is working with MEDAL, Inc., and North Carolina State University (NCSU) to develop polymer membrane technology for bulk removal of H{sub 2}S from syngas. These membranes are being engineered to remove the acid gas components (H{sub 2}S, CO{sub 2}, NH{sub 3}, and H{sub 2}O) from syngas by focusing on the ''solubility selectivity'' of the novel polymer compositions. The desirable components of the syngas (H{sub 2} and CO) are maintained at high-pressure conditions as a non-permeate stream while the impurities are transported across the membrane to the low pressure side. RTI tested commercially available and novel materials from MEDAL using a high-temperature, high-pressure (HTHP) permeation apparatus. H{sub 2}S/H{sub 2} selectivities >30 were achieved, although there was a strong negative dependence with temperature. MEDAL believes that all the polymer compositions tested so far can be prepared as hollow fiber membrane modules using the existing manufacturing technology. For fuel cell and chemical applications, additional sulfur removal (beyond that achievable with the membranes) is required. To overcome limitations of conventional ZnO pellets, RTI is testing a monolith with a thin coating of high surface area zinc-oxide based materials. Alternatively, a regenerable sorbent developed by DOE/NETL (RVS-1) is being evaluated for this application. A multi-cycle test of 2-in. (5-cm) diameter monolith samples demonstrated that <0.5 ppm sulfur can be achieved. Removal of HCl vapors is being accomplished by low-cost materials that combine the known effectiveness of sodium carbonate as an active matrix used with enhanced surface area supports for greater reactivity and capacity at the required operating temperatures. RTI is working with SRI International on this task. Sorbents prepared using diatomaceous earth and sepiolite, impregnated with sodium carbonate achieved steady-state HCl level <100 ppb (target is 10 ppb). Research is continuing to optimize the impregnation and calcination procedures to provide an optimum pore size distribution and other properties. RTI and SRI International have established the feasibility of a process to selectively chemisorb NH3 from syngas on high surface area molecular sieve adsorbents at high temperatures by conducting a series of temperature-programmed reactions at 225 C (437 F). Significant levels of NH{sub 3} were adsorbed on highly acidic adsorbents; the adsorbed NH{sub 3} was subsequently recovered by heating the adsorbent and the regenerated adsorbent was reused. A comprehensive technical and economic evaluation of this modular gas cleaning process was conducted by Nexant to compare capital and operating cost with existing amine based processes. Nexant estimated a total installed cost of $42 million for the RTI process for a 500 MWe IGCC plant based on its current state of development. By comparison, Nexant estimated the installed cost for an equivalent sized plant based on the Rectisol process (which would achieve the same sulfur removal specification) to be $75 million. Thus the RTI process is economically competitive with a state-of-the-art process for syngas cleanup.

B.S. Turk; T. Merkel; A. Lopez-Ortiz; R.P. Gupta; J.W. Portzer; G.N. Krishnan; B.D. Freeman; G.K. Fleming

2001-09-30T23:59:59.000Z

112

if it is a gas leak, do not activate building alarms, use mobile phones, hand held radios, electronic equipment or light flammable material!  

E-Print Network [OSTI]

gas leak gas leak if it is a gas leak, do not activate building alarms, use mobile phones, hand held radios, electronic equipment or light flammable material! 1. If you discover a Gas Leak, shout and check that the nearest gas isolator switch is off. 4. Evacuate the building immediately, avoiding

Hickman, Mark

113

Paducah Gaseous Diffusion Plant environmental report for 1992  

SciTech Connect (OSTI)

This two-part report, Paducah Gaseous Diffusion Plant Environmental Report for 1992, is published annually. It reflects the results of an environmental monitoring program designed to quantify potential increases in the concentration of contaminants and potential doses to the resident human population. The Paducah Gaseous Diffusion Plant (PGDP) overall goal for environmental management is to protect the environment and PGDP`s neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, reduce the generation of waste, and minimize hazardous waste by substitution of materials.

Horak, C.M. [ed.] [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

1993-09-01T23:59:59.000Z

114

Method of producing gaseous products using a downflow reactor  

DOE Patents [OSTI]

Reactor systems and methods are provided for the catalytic conversion of liquid feedstocks to synthesis gases and other noncondensable gaseous products. The reactor systems include a heat exchange reactor configured to allow the liquid feedstock and gas product to flow concurrently in a downflow direction. The reactor systems and methods are particularly useful for producing hydrogen and light hydrocarbons from biomass-derived oxygenated hydrocarbons using aqueous phase reforming. The generated gases may find used as a fuel source for energy generation via PEM fuel cells, solid-oxide fuel cells, internal combustion engines, or gas turbine gensets, or used in other chemical processes to produce additional products. The gaseous products may also be collected for later use or distribution.

Cortright, Randy D; Rozmiarek, Robert T; Hornemann, Charles C

2014-09-16T23:59:59.000Z

115

Paducah Gaseous Diffusion Plant Annual Site Environmental Report for 1993  

SciTech Connect (OSTI)

The purpose of this document is to summarize effluent monitoring and environmental surveillance results and compliance with environmental laws, regulations, and orders at the Paducah Gaseous Diffusion Plant (PGDP). Environmental monitoring at PGDP consists of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring is direct measurement or the collection and analysis of samples of liquid and gaseous discharges to the environment. Environmental surveillance is direct measurement or the collection and analysis of samples of air, water, soil, foodstuff, biota, and other media. Environmental monitoring is performed to characterize and quantify contaminants, assess radiation exposures of members of the public, demonstrate compliance with applicable standards and permit requirements, and detect and assess the effects (if any) on the local environment. Multiple samples are collected throughout the year and are analyzed for radioactivity, chemical content, and various physical attributes.

Not Available

1994-10-01T23:59:59.000Z

116

Paducah Gaseous Diffusion Plant Environmental report for 1990  

SciTech Connect (OSTI)

This two-part report, Paducah Gaseous Diffusion Plant Site Environmental Report for 1990, is published annually. It reflects the results of a comprehensive, year-round program to monitor the impact of operations at Paducah Gaseous Diffusion Plant (PGDP) on the area's groundwater and surface waters, soil, air quality, vegetation, and wildlife. In addition, an assessment of the effect of PGDP effluents on the resident human population is made. PGDP's overall goal for environmental management is to protect the environment and PGDP's neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, to reduce the formation of waste, and to minimize hazardous waste by substitution of materials.

Counce-Brown, D. (ed.)

1991-09-01T23:59:59.000Z

117

Gaseous Sulfate Solubility in Glass: Experimental Method  

SciTech Connect (OSTI)

Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

Bliss, Mary

2013-11-30T23:59:59.000Z

118

Dry deposition of gaseous elemental iodine on water  

E-Print Network [OSTI]

to receptor is essential in hazard evaluation. These processes include diffusion in the atmosphere and deposition on the earth's surface, followed by translocation through bioenvironmental pathways. All nuclear power plants sre constructed near a large... body of water used for cooling, and, at the present time, all nuclear plants release gaseous radioiodine. As a result, deposition of I2 on surface water is sn additional exposure pathway which must be considered when evaluating the hazard...

Allen, Michael Dana

1974-01-01T23:59:59.000Z

119

Chapter 4 The Gaseous State Chemistry of Gases  

E-Print Network [OSTI]

.15 V = V0[1+(t/273.15oC)] Kelvin T = 273.15 + t(Celsius) #12;Boyle's Law · The stirling engine, a heatChapter 4 The Gaseous State NO2 #12;AIR #12;Chemistry of Gases SO3 .. corrosive gas SO2...burning) ~1760 Charle The definition of the Temperature All gases expand with increasing temperature by the same

Ihee, Hyotcherl

120

Prospects for Barium Tagging in Gaseous Xenon  

SciTech Connect (OSTI)

Tagging events with the coincident detection of a barium ion would greatly reduce the background for a neutrino-less double beta decay search in xenon. This paper describes progress towards realizing this goal. It outlines a source that can produce large quantities of Ba++ in gas, shows that this can be extracted to vacuum, and demonstrates a mechanism by which the Ba++ can be efficiently converted to Ba+ as required for laser identification. It is clear from this study that electrospray is a convenient mechanism for producing Ba++ is gas at atmospheric pressure. It is likely that the source will perform just as effectively at higher pressures. Even though the source region has water vapour and methanol vapour at the 0.3% level, there is no evidence for molecular formation. The use of TEA offers an effective method to achieve the charge state conversion. The overall design of the ion extraction from high pressure to vacuum is very similar to the scheme proposed for the final detector and this appears to work well although the efficiency is not yet determined.

Sinclair, D.; /Carleton U. /TRIUMF; Rollin, E.; /Carleton U.; Smith, J.; /Carleton U.; Mommers, A.; /Ottawa U.; Ackerman, N.; /SLAC; Aharmim, B.; /Laurentian U.; Auger, M.; /Bern U., LHEP; Barbeau, P.S.; /Stanford U., Phys. Dept.; Benitez-Medina, C.; /Colorado State U.; Breidenbach, M.; /SLAC; Burenkov, A.; /Moscow, ITEP; Cook, S.; /SLAC; Coppens, A.; /Carleton U.; Daniels, T.; /Massachusetts U., Amherst; DeVoe, R.; /Stanford U., Phys. Dept.; Dobi, A.; /Maryland U.; Dolinski, M.J.; Donato, K.; /Stanford U., Phys. Dept.; Fairbank, W., Jr.; /Colorado State U.; Farine, J.; /Laurentian U.; Giroux, G.; /Bern U., LHEP /Carleton U. /Stanford U., Phys. Dept. /Carleton U. /Laurentian U. /Carleton U. /SLAC /Indiana U. /Indiana U., CEEM /Korea U. /Stanford U., Phys. Dept. /SLAC /Alabama U. /Colorado State U. /Stanford U., Phys. Dept. /Alabama U. /SLAC /Stanford U., Phys. Dept. /Alabama U. /Massachusetts U., Amherst /SLAC /Alabama U. /SLAC /Maryland U. /Moscow, ITEP /Stanford U., Phys. Dept. /Maryland U. /Bern U., LHEP /Laurentian U. /SLAC /Maryland U.

2012-05-03T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Summary and Outlook of the International Workshop on Aging Phenomena in Gaseous Detectors (DESY, Hamburg, October, 2001)  

E-Print Network [OSTI]

High Energy Physics experiments are currently entering a new era which requires the operation of gaseous particle detectors at unprecedented high rates and integrated particle fluxes. Full functionality of such detectors over the lifetime of an experiment in a harsh radiation environment is of prime concern to the involved experimenters. New classes of gaseous detectors such as large-scale straw-type detectors, Micro-pattern Gas Detectors and related detector types with their own specific aging effects have evolved since the first workshop on wire chamber aging was held at LBL, Berkeley in 1986. In light of these developments and as detector aging is a notoriously complex field, the goal of the workshop was to provide a forum for interested experimentalists to review the progress in understanding of aging effects and to exchange recent experiences. A brief summary of the main results and experiences reported at the 2001 workshop is presented, with the goal of providing a systematic review of aging effects in state-of-the-art and future gaseous detectors.

M. Titov; M. Hohlmann; C. Padilla; N. Tesch

2002-04-04T23:59:59.000Z

122

Modified gaseous atmospheres for storage of beef, lamb and pork  

E-Print Network [OSTI]

MODIFIED G'~. ' . . OUS ATMOSPHERI. S FOR STORAGE OI REEF, I. PMB AND PORK A Thesis by GEORGE THEODORE DAVIS I II Submitted to thc. graduate college of Texas AsM University in partial fulfillment of the rec, u. 'rement fox the degree... of MASTER OF SCIENCE December ' 1979 Major Subject: Animal "" ience MODIF1ED GASEOUS ATMOSPHERES FOR STORAGE OF BEEFi LAMB AND PORK A Thesis GEORGE THEODORE DAVIS III Approved as to style and content. by (Co Chairman of ommittee) (Member) (Member...

Davis, George Theodore

1979-01-01T23:59:59.000Z

123

Portsmouth Gaseous Diffusion Plant Environmental report for 1990  

SciTech Connect (OSTI)

This calendar year 1990 annual report on environmental surveillance of the US Department of Energy's (DOE's) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the summary, discussion, and conclusions (Part 1) and the data presentation (Part 2). The objectives of this report are as follows: report 1990 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (when appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance.

Counce-Brown, D. (ed.)

1991-09-01T23:59:59.000Z

124

K-25 Gaseous Diffusion Process Building | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGYWomen OwnedofDepartment ofJared Temanson - Project Leader atDepartment ofK-25 Gaseous

125

Ionization and scintillation of nuclear recoils in gaseous xenon  

E-Print Network [OSTI]

Ionization and scintillation produced by nuclear recoils in gaseous xenon at approximately 14 bar have been simultaneously observed in an electroluminescent time projection chamber. Neutrons from radioisotope $\\alpha$-Be neutron sources were used to induce xenon nuclear recoils, and the observed recoil spectra were compared to a detailed Monte Carlo employing estimated ionization and scintillation yields for nuclear recoils. The ability to discriminate between electronic and nuclear recoils using the ratio of ionization to primary scintillation is demonstrated. These results encourage further investigation on the use of xenon in the gas phase as a detector medium in dark matter direct detection experiments.

J. Renner; V. M. Gehman; A. Goldschmidt; H. S. Matis; T. Miller; Y. Nakajima; D. Nygren; C. A. B. Oliveira; D. Shuman; V. lvarez; F. I. G. Borges; S. Crcel; J. Castel; S. Cebrin; A. Cervera; C. A. N. Conde; T. Dafni; T. H. V. T. Dias; J. Daz; R. Esteve; P. Evtoukhovitch; L. M. P. Fernandes; P. Ferrario; A. L. Ferreira; E. D. C. Freitas; A. Gil; H. Gmez; J. J. Gmez-Cadenas; D. Gonzlez-Daz; R. M. Gutirrez; J. Hauptman; J. A. Hernando Morata; D. C. Herrera; F. J. Iguaz; I. G. Irastorza; M. A. Jinete; L. Labarga; A. Laing; I. Liubarsky; J. A. M. Lopes; D. Lorca; M. Losada; G. Luzn; A. Mar; J. Martn-Albo; A. Martnez; A. Moiseenko; F. Monrabal; M. Monserrate; C. M. B. Monteiro; F. J. Mora; L. M. Moutinho; J. Muoz Vidal; H. Natal da Luz; G. Navarro; M. Nebot-Guinot; R. Palma; J. Prez; J. L. Prez Aparicio; L. Ripoll; A. Rodrguez; J. Rodrguez; F. P. Santos; J. M. F. dos Santos; L. Segu; L. Serra; A. Simn; C. Sofka; M. Sorel; J. F. Toledo; A. Toms; J. Torrent; Z. Tsamalaidze; J. F. C. A. Veloso; J. A. Villar; R. C. Webb; J. White; N. Yahlali

2014-09-09T23:59:59.000Z

126

The Central Kiloparsec of Seyfert and Inactive Host Galaxies: a Comparison of Two-Dimensional Stellar and Gaseous Kinematics  

E-Print Network [OSTI]

We investigate the properties of the two-dimensional distribution and kinematics of ionised gas and stars in the central kiloparsecs of a matched sample of nearby active (Seyfert) and inactive galaxies, using the SAURON Integral Field Unit on the William Herschel Telescope. The ionised gas distributions show a range of low excitation regions such as star formation rings in Seyferts and inactive galaxies, and high excitation regions related to photoionisation by the AGN. The stellar kinematics of all galaxies in the sample show regular rotation patterns typical of disc-like systems, with kinematic axes which are well aligned with those derived from the outer photometry and which provide a reliable representation of the galactic line of nodes. After removal of the non-gravitational components due to e.g. AGN-driven outflows, the ionised gas kinematics in both the Seyfert and inactive galaxies are also dominated by rotation with global alignment between stars and gas in most galaxies. This result is consistent with previous findings from photometric studies that the large-scale light distribution of Seyfert hosts are similar to inactive hosts. However, fully exploiting the two-dimensional nature of our spectroscopic data, deviations from axisymmetric rotation in the gaseous velocity fields are identified that suggest the gaseous kinematics are more disturbed at small radii in the Seyfert galaxies compared with the inactive galaxies, providing a tentative link between nuclear gaseous streaming and nuclear activity.

Gaelle Dumas; Carole Mundell; Eric Emsellem; Neil Nagar

2007-05-29T23:59:59.000Z

127

EA-1927: Conveyance of Land and Facilities at the Paducah Gaseous...  

Broader source: Energy.gov (indexed) [DOE]

27: Conveyance of Land and Facilities at the Paducah Gaseous Diffusion Plant for Economic Development Purposes, Paducah, Kentucky EA-1927: Conveyance of Land and Facilities at the...

128

Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning  

Broader source: Energy.gov [DOE]

The decommissioning of Gaseous Diffusion Plant facilities requires accurate, non-destructive assay (NDA) of residual enriched uranium in facility components for safeguards and nuclear criticality...

129

Liquid and gaseous waste operations section. Annual operating report CY 1997  

SciTech Connect (OSTI)

This document presents information on the liquid and gaseous wastes operations section for calendar year 1997. Operating activities, upgrade activities, and maintenance activities are described.

Maddox, J.J.; Scott, C.B.

1998-03-01T23:59:59.000Z

130

E-Print Network 3.0 - absorbing gaseous medium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Elperin, Tov - Department of Mechanical Engineering, Ben-Gurion University Collection: Engineering 3 Extending the Photon Mapping Method for Realistic Rendering of Hot Gaseous...

131

Flammability evaluation of glass fiber reinforced polypropylene and polyethylene with montmorillonite nanoclay additives.  

E-Print Network [OSTI]

??Thermoplastic composites have a wide range of applications in the transportation, automotive, and aerospace industries that require high strength, stiffness and, light weight. The susceptibility (more)

Vaddi, Satya P.

2008-01-01T23:59:59.000Z

132

Guidelines for Transportation, Handling, and Use of Fast Pyrolysis Bio-Oil. Part 1. Flammability and Toxicity  

SciTech Connect (OSTI)

An alternative sustainable fuel, biomass-derived fast pyrolysis oil or 'bio-oil', is coming into the market. Fast pyrolysis pilot and demonstration plants for fuel applications producing tonnes of bio-oil are in operation, and commercial plants are under design. There will be increasingly larger amounts of bio-oil transportation on water and by land, leading to a need for specifications and supporting documentation. Bio-oil is different from conventional liquid fuels, and therefore must overcome both technical and marketing hurdles for its acceptability in the fuels market. A comprehensive Material Safety Data Sheet (MSDS) is required, backed with independent testing and certification. In order to standardise bio-oil quality specifications are needed. The first bio-oil burner fuel standard in ASTM (D7544) was approved in 2009. CEN standardisation has been initiated in Europe. In the EU a new chemical regulation system, REACH (Registration, Evaluation and Authorisation of Chemicals) is being applied. Registration under REACH has to be made if bio-oil is produced or imported to the EU. In the USA and Canada, bio-oil has to be filed under TOSCA (US Toxic Substances Control Act). In this paper the state of the art on standardisation is discussed, and new data for the transportation guidelines is presented. The focus is on flammability and toxicity.

Oasmaa, Anja; Kalli, Anssi; Lindfors, Christian; Elliott, Douglas C.; Springer, David L.; Peacocke, Cordner; Chiaramonti, David

2012-05-04T23:59:59.000Z

133

Gusty, gaseous flows of FIRE: galactic winds in cosmological simulations with explicit stellar feedback  

E-Print Network [OSTI]

We present an analysis of the galaxy-scale gaseous outflows from the FIRE (Feedback in Realistic Environments) simulations. This suite of hydrodynamic cosmological zoom simulations provides a sample of halos where star-forming giant molecular clouds are resolved to z=0, and features an explicit stellar feedback model on small scales. In this work, we focus on quantifying the gas mass ejected out of galaxies in winds and how this material travels through the halo. We correlate these quantities to star formation in galaxies throughout cosmic history. Our simulations reveal that a significant portion of every galaxy's evolution, particularly at high redshift, is dominated by bursts of star formation, which are followed by powerful gusts of galactic outflow that sweep up a large fraction of gas in the interstellar medium and send it through the circumgalactic medium. The dynamical effect of these outflows can significantly limit the amount of star formation within the affected galaxy. At low redshift, however, su...

Muratov, Alexander L; Faucher-Giguere, Claude-Andre; Hopkins, Philip F; Quataert, Eliot; Murray, Norman

2015-01-01T23:59:59.000Z

134

Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels  

DOE Patents [OSTI]

An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

Heffel, James W. (Lake Matthews, CA); Scott, Paul B. (Northridge, CA); Park, Chan Seung (Yorba Linda, CA)

2011-11-01T23:59:59.000Z

135

Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels  

DOE Patents [OSTI]

An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

Heffel, James W.; Scott, Paul B.

2003-09-02T23:59:59.000Z

136

Seismic issues at the Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

A seismic expert workshop was held at the Paducah Gaseous Diffusion Plant (PGDP) on March 13--15, 1989. the PGDP is operated by Martin Marietta Energy Systems, Inc. for the United States Department of Energy (DOE). During the last twenty years the design criteria for natural phenomenon hazards has steadily become more demanding at all of the DOE Oak Ridge Operations (ORO) sites. The purpose of the two-day workshop was to review the seismic vulnerability issues of the PGDP facilities. Participants to the workshop included recognized experts in the fields of seismic engineering, seismology and geosciences, and probabilistic analysis, along with engineers and other personnel from Energy Systems. A complete list of the workshop participants is included in the front of this report. 29 refs.

Fricke, K.E. (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (USA))

1989-11-01T23:59:59.000Z

137

Paducah Gaseous Diffusion Plant environmental report for 1989  

SciTech Connect (OSTI)

This two-part environmental report is published annually. It reflects the results of a comprehensive, year-round program to monitor the impact of operations at Paducah Gaseous Diffusion Plant (PGDP) on the area's groundwater and surface waters, soil, air quality, vegetation, and wildlife. In addition, an assessment of the effect of PGDP effluents on the resident human population is made. PGDP's overall goal for environmental management is to protect the environment and PGDP's neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, to reduce the formation of waste, and to minimize hazardous waste by substitution of materials. 36 refs.

Turner, J.W. (ed.) (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (USA))

1990-10-01T23:59:59.000Z

138

Spectral modeling of gaseous metal disks around DAZ white dwarfs  

E-Print Network [OSTI]

We report on our attempt for the first non-LTE modeling of gaseous metal disks around single DAZ white dwarfs recently discovered by Gaensicke et al. and thought to originate from a disrupted asteroid. We assume a Keplerian rotating viscous disk ring composed of calcium and hydrogen and compute the detailed vertical structure and emergent spectrum. We find that the observed infrared CaII emission triplet can be modeled with a hydrogen-deficient gas ring located at R=1.2 R_sun, inside of the tidal disruption radius, with Teff about 6000 K and a low surface mass density of about 0.3 g/cm**2. A disk having this density and reaching from the central white dwarf out to R=1.2 R_sun would have a total mass of 7 10**21 g, corresponding to an asteroid with about 160 km diameter.

K. Werner; T. Nagel; T. Rauch

2008-09-30T23:59:59.000Z

139

Portsmouth Gaseous Diffusion Plant annual site environmental report for 1993  

SciTech Connect (OSTI)

This calendar year (CY) 1993 annual report on environmental monitoring of the US Department of Energy`s (DOE`s) Portsmouth Gaseous Diffusion Plant (Portsmouth) and its environs consists of three separate documents: a summary pamphlet for the general public; a more detail discussion and of compliance status, data, and environmental impacts (this document); and a volume of detailed data that is available on request. The objectives of this report are to report compliance status during 1993; provide information about the plant site and plant operations; report 1993 monitoring data for the installation and its environs that may have been affected by operations on the plant site; document information on input and assumptions used in calculations; provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on quality assurance for the environmental monitoring program.

Horak, C.M. [ed.

1994-11-01T23:59:59.000Z

140

Jupiter and Super-Earth embedded in a gaseous disc  

E-Print Network [OSTI]

In this paper we investigate the evolution of a pair of interacting planets - a Jupiter mass planet and a Super-Earth with the 5.5 Earth masses - orbiting a Solar type star and embedded in a gaseous protoplanetary disc. We focus on the effects of type I and II orbital migrations, caused by the planet-disc interaction, leading to the Super-Earth capture in first order mean motion resonances by the Jupiter. The stability of the resulting resonant system in which the Super-Earth is on the internal orbit relatively to the Jupiter has been studied numerically by means of full 2D hydrodynamical simulations. Our main motivation is to determine the Super-Earth behaviour in the presence of the gas giant in the system. It has been found that the Jupiter captures the Super-Earth into the interior 3:2 or 4:3 mean motion resonances and the stability of such configurations depends on the initial planet positions and eccentricity evolution. If the initial separation of planet orbits is larger or close to that required for the exact resonance than the final outcome is the migration of the pair of planets with the rate similar to that of the gas giant at least for time of our simulations. Otherwise we observe a scattering of the Super-Earth from the disc. The evolution of planets immersed in the gaseous disc has been compared with their behaviour in the case of the classical three-body problem when the disc is absent.

E. Podlewska; E. Szuszkiewicz

2007-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Selective Gaseous Extraction: Research, Development and Training for Isotope Production, Final Technical Report  

SciTech Connect (OSTI)

General Atomics and the University of Missouri Research Reactor (MURR) completed research and development of selective gaseous extraction of fission products from irradiated fuel, which included training and education of MURR students. The process used porous fuel and after irradiation flowed product gases through the fuel to selectively removed desired fission products with the primary goal of demonstrating the removal of rhodium 105. High removal rates for the ruthenium/rhodium (Ru/Rh), tellurium/iodine (Te/I) and molybdenum/technetium (Mo/Tc) series were demonstrated. The success of this research provides for the reuse of the target for further production, significantly reducing the production of actinide wastes relative to processes that dissolve the target. This effort was conducted under DOE funding (DE-SC0007772). General Atomics objective of the project was to conduct R&D on alternative methods to produce a number of radioactive isotopes currently needed for medical and industry applications to include rhodium-105 and other useful isotopes. Selective gaseous extraction was shown to be effective at removing radioisotopes of the ruthenium/rhodium, tellurium/iodine and molybdenum/technetium decay chains while having trace to no quantities of other fission products or actinides. This adds a new, credible method to the area of certain commercial isotope production beyond current techniques, while providing significant potential reduction of process wastes. Waste reduction, along with reduced processing time/cost provides for superior economic feasibility which may allow domestic production under full cost recovery practices. This provides the potential for improved access to domestically produced isotopes for medical diagnostics and treatment at reduced cost, providing for the public good.

Bertch, Timothy C, [General Atomics

2014-03-31T23:59:59.000Z

142

Process safety management for highly hazardous chemicals  

SciTech Connect (OSTI)

Purpose of this document is to assist US DOE contractors who work with threshold quantities of highly hazardous chemicals (HHCs), flammable liquids or gases, or explosives in successfully implementing the requirements of OSHA Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119). Purpose of this rule is to prevent releases of HHCs that have the potential to cause catastrophic fires, explosions, or toxic exposures.

NONE

1996-02-01T23:59:59.000Z

143

DEVELOPMENT OF AN ANTIFOAM TRACKING SYSTEM AS AN OPTION TO SUPPORT THE MELTER OFF-GAS FLAMMABILITY CONTROL STRATEGY AT THE DWPF  

SciTech Connect (OSTI)

The Savannah River National Laboratory (SRNL) has been working with the Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) in the development and implementation of an additional strategy for confidently satisfying the flammability controls for DWPFs melter operation. An initial strategy for implementing the operational constraints associated with flammability control in DWPF was based upon an analytically determined carbon concentration from antifoam. Due to the conservative error structure associated with the analytical approach, its implementation has significantly reduced the operating window for processing and has led to recurrent Slurry Mix Evaporator (SME) and Melter Feed Tank (MFT) remediation. To address the adverse operating impact of the current implementation strategy, SRR issued a Technical Task Request (TTR) to SRNL requesting the development and documentation of an alternate strategy for evaluating the carbon contribution from antifoam. The proposed strategy presented in this report was developed under the guidance of a Task Technical and Quality Assurance Plan (TTQAP) and involves calculating the carbon concentration from antifoam based upon the actual mass of antifoam added to the process assuming 100% retention. The mass of antifoam in the Additive Mix Feed Tank (AMFT), in the Sludge Receipt and Adjustment Tank (SRAT), and in the SME is tracked by mass balance as part of this strategy. As these quantities are monitored, the random and bias uncertainties affecting their values are also maintained and accounted for. This report documents: 1) the development of an alternate implementation strategy and associated equations describing the carbon concentration from antifoam in each SME batch derived from the actual amount of antifoam introduced into the AMFT, SRAT, and SME during the processing of the batch. 2) the equations and error structure for incorporating the proposed strategy into melter off-gas flammability assessments. Sample calculations of the system are also included in this report. Please note that the system developed and documented in this report is intended as an alternative to the current, analytically-driven system being utilized by DWPF; the proposed system is not intended to eliminate the current system. Also note that the system developed in this report to track antifoam mass in the AMFT, SRAT, and SME will be applicable beyond just Sludge Batch 8. While the model used to determine acceptability of the SME product with respect to melter off-gas flammability controls must be reassessed for each change in sludge batch, the antifoam mass tracking methodology is independent of sludge batch composition and as such will be transferable to future sludge batches.

Edwards, T.; Lambert, D.

2014-08-27T23:59:59.000Z

144

Nuclear criticality safety aspects of gaseous uranium hexafluoride (UF{sub 6}) in the diffusion cascade  

SciTech Connect (OSTI)

This paper determines the nuclear safety of gaseous UF{sub 6} in the current Gaseous Diffusion Cascade and auxiliary systems. The actual plant safety system settings for pressure trip points are used to determine the maximum amount of HF moderation in the process gas, as well as the corresponding atomic number densities. These inputs are used in KENO V.a criticality safety models which are sized to the actual plant equipment. The ENO V.a calculation results confirm nuclear safety of gaseous UF{sub 6} in plant operations..

Huffer, J.E. [Parallax, Inc., Atlanta, GA (United States)

1997-04-01T23:59:59.000Z

145

Application of Gaseous Sphere Injection Method for Modeling Under-expanded H2 Injection  

SciTech Connect (OSTI)

A methodology for modeling gaseous injection has been refined and applied to recent experimental data from the literature. This approach uses a discrete phase analogy to handle gaseous injection, allowing for addition of gaseous injection to a CFD grid without needing to resolve the injector nozzle. This paper focuses on model testing to provide the basis for simulation of hydrogen direct injected internal combustion engines. The model has been updated to be more applicable to full engine simulations, and shows good agreement with experiments for jet penetration and time-dependent axial mass fraction, while available radial mass fraction data is less well predicted.

Whitesides, R; Hessel, R P; Flowers, D L; Aceves, S M

2010-12-03T23:59:59.000Z

146

Bioavailability study for the Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

The overall purpose of this plan is to assess the bioavailability of metals in the continuous and intermittent outfalls. The results may be used to determine alternative metal limits that more appropriately measure the portion of metal present necessary for toxicity to aquatic life. These limits must remain protective of in-stream aquatic life; thus, the highest concentration of metal in the water will be determined concurrently with an assessment of acute or chronic toxicity on laboratory tests. Using the method developed by the Kentucky Division of Water (KDOW), biomonitoring results and chemical data will be used to recommend alternative metal limits for the outfalls of concern. The data will be used to meet the objectives of the study: (1) evaluate the toxicity of continuous outfalls and intermittent outfalls at Paducah Gaseous Diffusion Plant; (2) determine the mean ratio of dissolved to Total Recoverable metal for Cd, Cr, Cu, Pb, Ni, and Zn in the continuous and intermittent outfalls; (3) determine whether the concentration of total recoverable metal discharged causes toxicity to fathead minnows and /or Ceriodaphnia; and (4) determine alternative metal limits for each metal of concern (Cd, Cr, Cu, Pb, Ni, and Zn).

Phipps, T.L.; Kszos, L.A.

1996-08-01T23:59:59.000Z

147

Portsmouth Gaseous Diffusion Plant environmental report for 1989  

SciTech Connect (OSTI)

This calendar year 1989 annual report on environmental surveillance of the US Department of Energy's (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the Summary, Discussion, and Conclusions (Part 1) and the Data Presentation (Part 2). The objectives of this report are the following: report 1989 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance. Routine monitoring and sampling for radiation, radioactive materials, and chemical substances on and off the DOE site are used to document compliance with appropriate standards, to identify trends, to provide information for the public, and to contribute to general environmental knowledge. The surveillance program assists in fulfilling the DOE policy of protecting the public, employees, and environment from harm that could be caused by its activities and reducing negative environmental impacts to the greatest degree practicable. Environmental-monitoring information complements data on specific releases, trends, and summaries. 26 refs.

Turner, J.W. (ed.) (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (USA))

1990-10-01T23:59:59.000Z

148

Summary and Outlook of the International Workshop on Aging Phenomena in Gaseous Detectors (DESY, Hamburg, October, 2001)  

E-Print Network [OSTI]

High Energy Physics experiments are currently entering a new era which requires the operation of gaseous particle detectors at unprecedented high rates and integrated particle fluxes. Full functionality of such detectors over the lifetime of an experiment in a harsh radiation environment is of prime concern to the involved experimenters. New classes of gaseous detectors such as large-scale straw-type detectors, Micro-pattern Gas Detectors and related detector types with their own specific aging effects have evolved since the first workshop on wire chamber aging was held at LBL, Berkeley in 1986. In light of these developments and as detector aging is a notoriously complex field, the goal of the workshop was to provide a forum for interested experimentalists to review the progress in understanding of aging effects and to exchange recent experiences. A brief summary of the main results and experiences reported at the 2001 workshop is presented, with the goal of providing a systematic review of aging effects in ...

Titov, M L; Padilla, C; Tesch, N

2002-01-01T23:59:59.000Z

149

Pattern recognition techniques to reduce backgrounds in the search for the {sup 136}Xe double beta decay with gaseous TPCs  

SciTech Connect (OSTI)

The observation of the neutrinoless double beta decay may provide essential information on the nature of neutrinos. Among the current experimental approaches, a high pressure gaseous TPC is an attractive option for the search of double beta decay due to its good energy resolution and the detailed topological information of each event. We present in this talk a detailed study of the ionization topology of the {sup 136}Xe double beta decay events in a High Pressure Xenon TPC, as well as that of the typical competing backgrounds. We define some observables based on graph theory concepts to develop automated discrimination algorithms. Our criteria are able to reduce the background level by about three orders of magnitude in the region of interest of the {sup 136}Xe Q{sub ??} for a signal acceptance of 40%. This result provides a quantitative assessment of the benefit of topological information offered by gaseous TPCs for double beta decay search, and proves that it is a promising feature in view of future experiments in the field. Possible ideas for further improvement in the discrimination algorithms and the dependency of these results with the gas diffusion and readout granularity will be also discussed.

Iguaz, F. J.; Cebrin, S.; Dafni, T.; Gmez, H.; Herrera, D. C.; Irastorza, I. G.; Luzon, G.; Segui, L.; Tomas, A. [Laboratorio de Fsica Nuclear y Astropartculas, Universidad de Zaragoza (Spain)] [Laboratorio de Fsica Nuclear y Astropartculas, Universidad de Zaragoza (Spain)

2013-08-08T23:59:59.000Z

150

E-Print Network 3.0 - amount gaseous fission Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

) reports that the amount of non-gaseous nuclides retained on the filters of the Windscale pile... . Petersen Abstract. The fission-product release to the atmosphere from a...

151

Liquid and Gaseous Waste Operations Department annual operating report, CY 1995  

SciTech Connect (OSTI)

This report describes the operating activities, upgrade activities, maintenance, and other activities regarding liquid and gaseous low level radioactive waste management at the Oak Ridge National Laboratory. Miscellaneous activities include training, audits, tours, and environmental restoration support.

Maddox, J.J.; Scott, C.B.

1996-03-01T23:59:59.000Z

152

Hybrid Multi Micropattern Gaseous Photomultiplier for detection of liquid-xenon scintillation  

E-Print Network [OSTI]

Gaseous PhotoMultipliers (GPM) are a very promising alternative of vacuum PMTs especially for large-size noble-liquid detectors in the field of Functional Nuclear Medical Imaging and Direct Dark Matter Detection. We present recent characterization results of a Hybrid-GPM made of three Micropattern Gaseous Structures; a Thick Gaseous Electron Multiplier (THGEM), a Parallel Ionization Multiplier (PIM) and a MICROMesh GAseous Structure (MICROMEGAS),operating in Ne/CF4 (90:10). Gain values close to 10^7 were recorded in this mixture, with 5.9keV x-rays at 1100 mbar, both at room temperature and at that of liquid xenon (T = 171K). The results are discussed in term of scintillation detection. While the present multiplier was investigated without photocathode, complementary results of photoextraction from CsI UV photocathodes are presented in Ne/CH4 (95:5) and CH4 in cryogenic conditions.

Samuel Duval; Lior Arazi; Amos Breskin; Ranny Budnik; Wan-Ting Chen; Herv Carduner; A. E. C. Coimbra; Marco Cortesi; Roy Kaner; Jean-Pierre Cussonneau; Jrme Donnard; Jacob Lamblin; Olivier Lemaire; Patrick Le Ray; J. A. M. Lopes; Abdul-Fattah Mohamad Hadi; Eric Morteau; Tugdual Oger; J. M. F. dos Santos; Luca Scotto Lavina; Jean-Sbastien Stutzmann; Dominique Thers

2011-10-27T23:59:59.000Z

153

Milestone Report #2: Direct Evaporator Leak and Flammability Analysis Modifications and Optimization of the Organic Rankine Cycle to Improve the Recovery of Waste Heat  

SciTech Connect (OSTI)

The direct evaporator is a simplified heat exchange system for an Organic Rankine Cycle (ORC) that generates electricity from a gas turbine exhaust stream. Typically, the heat of the exhaust stream is transferred indirectly to the ORC by means of an intermediate thermal oil loop. In this project, the goal is to design a direct evaporator where the working fluid is evaporated in the exhaust gas heat exchanger. By eliminating one of the heat exchangers and the intermediate oil loop, the overall ORC system cost can be reduced by approximately 15%. However, placing a heat exchanger operating with a flammable hydrocarbon working fluid directly in the hot exhaust gas stream presents potential safety risks. The purpose of the analyses presented in this report is to assess the flammability of the selected working fluid in the hot exhaust gas stream stemming from a potential leak in the evaporator. Ignition delay time for cyclopentane at temperatures and pressure corresponding to direct evaporator operation was obtained for several equivalence ratios. Results of a computational fluid dynamic analysis of a pinhole leak scenario are given.

Donna Post Guillen

2013-09-01T23:59:59.000Z

154

Mixed waste storage facility CDR review, Paducah Gaseous Diffusion Plant; Solid waste landfill CDR review, Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

This report consists of two papers reviewing the waste storage facility and the landfill projects proposed for the Paducah Gaseous Diffusion Plant complex. The first paper is a review of DOE`s conceptual design report for a mixed waste storage facility. This evaluation is to review the necessity of constructing a separate mixed waste storage facility. The structure is to be capable of receiving, weighing, sampling and the interim storage of wastes for a five year period beginning in 1996. The estimated cost is assessed at approximately $18 million. The review is to help comprehend and decide whether a new storage building is a feasible approach to the PGDP mixed waste storage problem or should some alternate approach be considered. The second paper reviews DOE`s conceptual design report for a solid waste landfill. This solid waste landfill evaluation is to compare costs and the necessity to provide a new landfill that would meet State of Kentucky regulations. The assessment considered funding for a ten year storage facility, but includes a review of other facility needs such as a radiation detection building, compactor/baler machinery, material handling equipment, along with other personnel and equipment storage buildings at a cost of approximately $4.1 million. The review is to help discern whether a landfill only or the addition of compaction equipment is prudent.

NONE

1998-08-01T23:59:59.000Z

155

The determination of compressibility factors of gaseous butane-nitrogen mixtures in the gas phase  

E-Print Network [OSTI]

THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS BUTANE-NITROGEN MIXTURES IN THE GAS PHASE A D issertation By Robert Buckner Evans, III Approved as to style and content by: (Chairman of Committee) (Head of^ 'ent Advisor) June 1955... ?-; i'i i ; A R y ? 'A 'Gi- Or- T EX AS THE DETERMINATION OF COMHIESSIBILITI FACTORS OF GASEOUS BUTANE-NITROGEN MIXTURES IN THE GAS PHASE A D issertation By ROBERT BUCKNER EVANS, III Submitted' to the Graduate School of the Agricultural...

Evans, Robert Buckner

1955-01-01T23:59:59.000Z

156

Liquid and Gaseous Waste Operations Department Annual Operating Report, CY 1993  

SciTech Connect (OSTI)

This report summarizes the activities of the waste management operations section of the liquid and gaseous waste operations department at ORNL for 1993. The process waste, liquid low-level waste, gaseous waste systems activities are reported, as well as the low-level waste solidification project. Upgrade activities is the various waste processing and treatment systems are summarized. A maintenance activity overview is provided, and program management, training, and other miscellaneous activities are covered.

Maddox, J.J.; Scott, C.B.

1994-02-01T23:59:59.000Z

157

MATERIAL SAFETY Flammability: 0  

E-Print Network [OSTI]

peligrosos (Identidad Quimica Especifica; Nombre(s) Común(es)) OSHA1 PEL2 ACGIH3 TLV4 Otros limites

Rollins, Andrew M.

158

TREATMENT OF GASEOUS EFFLUENTS ISSUED FROM RECYCLING A REVIEW OF THE CURRENT PRACTICES AND PROSPECTIVE IMPROVEMENTS  

SciTech Connect (OSTI)

The objectives of gaseous waste management for the recycling of nuclear used fuel is to reduce by best practical means (ALARA) and below regulatory limits, the quantity of activity discharged to the environment. The industrial PUREX process recovers the fissile material U(VI) and Pu(IV) to re-use them for the fabrication of new fuel elements e.g. recycling plutonium as a Mixed Oxide (MOX) fuel or recycling uranium for new enrichment for Pressurized Water Reactor (PWR). Meanwhile the separation of the waste (activation and fission product) is performed as a function of their pollution in order to store and avoid any potential danger and release towards the biosphere. Raffinate, that remains after the extraction step and which contains mostly all fission products and minor actinides is vitrified, the glass package being stored temporarily at the recycling plant site. Hulls and end pieces coming from PWR recycled fuel are compacted by means of a press leading to a volume reduced to 1/5th of initial volume. An organic waste treatment step will recycle the solvent, mainly tri-butyl phosphate (TBP) and some of its hydrolysis and radiolytic degradation products such as dibutyl phosphate (HDPB) and monobutyl phosphate (H2MBP). Although most scientific and technological development work focused on high level waste streams, a considerable effort is still under way in the area of intermediate and low level waste management. Current industrial practices for the treatment of gaseous effluents focusing essentially on Iodine-129 and Krypton-85 will be reviewed along with the development of novel technologies to extract, condition, and store these fission products. As an example, the current industrial practice is to discharge Kr-85, a radioactive gas, entirely to the atmosphere after dilution, but for the large recycling facilities envisioned in the near future, several techniques such as 1) cryogenic distillation and selective absorption in solvents, 2) adsorption on activated charcoal, 3) selective sorption on chemical modified zeolites, or 4) diffusion through membranes with selective permeability are potential technologies to retain the gas.

Patricia Paviet-Hartmann; William Kerlin; Steven Bakhtiar

2010-11-01T23:59:59.000Z

159

Gravitational drag on a point mass in hypersonic motion through a gaseous medium  

E-Print Network [OSTI]

We explore a ballistic orbit model to infer the gravitational drag force on an accreting point mass M, such as a black hole, moving at a hypersonic velocity v_{0} through a gaseous environment of density \\rho_{0}. The streamlines blend in the flow past the body and transfer momentum to it. The total drag force acting on the body, including the nonlinear contribution of those streamlines with small impact parameter that bend significantly and pass through a shock, can be calculated by imposing conservation of momentum. In this fully analytic approach, the ambiguity in the definition of the lower cut-off distance $r_{\\rm min}$ in calculations of the effect of dynamical friction is removed. It turns out that $r_{\\rm min}=\\sqrt{e}GM/2v_{0}^{2}$. Using spherical surfaces of control of different sizes, we carry out a successful comparison between the predicted drag force and the one obtained from a high resolution, axisymmetric, isothermal flow simulation. We demonstrate that ballistic models are reasonably success...

Canto, J; Esquivel, A; Sanchez-Salcedo, F J

2011-01-01T23:59:59.000Z

160

On the possible environmental effect in distributing heavy elements beyond individual gaseous halos  

E-Print Network [OSTI]

We present a study of extended galaxy halo gas through HI and OVI absorption over two decades in projected distance at $z\\approx0.2$. The study is based on a sample of $95$ galaxies from a highly complete ($ > 80\\%$) survey of faint galaxies ($L > 0.1L_*$) with archival quasar absorption spectra and $53$ galaxies from the literature. A clear anti-correlation is found between HI (OVI) column density and virial radius normalized projected distance, $d/R_{\\rm h}$. Strong HI (OVI) absorption systems with column densities greater than $10^{14.0}$ ($10^{13.5}$) cm$^{-2}$ are found for $48$ of $54$ ($36$ of $42$) galaxies at $d R_{\\rm h}$ compared to isolated galaxies ($\\kappa_{\\rm OVI}\\approx0.13$ versus $0.04$) but no excess HI absorption. These findings suggest that environmental effects play a role in distributing heavy elements beyond the enriched gaseous halos of individual galaxies. Finally, we find that differential HI and OVI absorption between early- and late-type galaxies continues from $d < R_{\\rm h}$...

Johnson, Sean D; Mulchaey, John S

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Safeguards Verification Measurements using Laser Ablation, Absorbance Ratio Spectrometry in Gaseous Centrifuge Enrichment Plants  

SciTech Connect (OSTI)

Laser Ablation Absorbance Ratio Spectrometry (LAARS) is a new verification measurement technology under development at the US Department of Energy (DOE) Pacific Northwest National Laboratory (PNNL). LAARS uses three lasers to ablate and then measure the relative isotopic abundance of uranium compounds. An ablation laser is tightly focused on uranium-bearing solids, producing a small atomic uranium vapor plume. Two collinear wavelength-tuned spectrometry lasers transit through the plume and the absorbance of U-235 and U-238 isotopes are measured to determine U-235 enrichment. The measurement is independent of chemical form and degree of dilution with nuisance dust and other materials. LAARS has high relative precision and detection limits approaching the femtogram range for U-235. The sample is scanned and assayed point-by-point at rates reaching 1 million measurements/hour, enabling LAARS to detect and analyze uranium in trace samples. The spectrometer is assembled using primarily commercially available components and features a compact design and automated analysis.Two specific gaseous centrifuge enrichment plant (GCEP) applications of the spectrometer are currently under development: 1) LAARS-Environmental Sampling (ES), which collects and analyzes aerosol particles for GCEP misuse detection and 2) LAARS-Destructive Assay (DA), which enables onsite enrichment DA sample collection and analysis for protracted diversion detection. The two applications propose game-changing technological advances in GCEP safeguards verification.

Anheier, Norman C.; Cannon, Bret D.; Kulkarni, Gourihar R.; Munley, John T.; Nelson, Danny A.; Qiao, Hong (Amy) [Amy; Phillips, Jon R.

2012-07-17T23:59:59.000Z

162

Variable Emission from a Gaseous Disc around a Metal-Polluted White Dwarf  

E-Print Network [OSTI]

We present the discovery of strongly variable emission lines from a gaseous disc around the DA white dwarf SDSS J1617+1620, a star previously found to have an infrared excess indicative of a dusty debris disc formed by the tidal disruption of a rocky planetary body. Time-series spectroscopy obtained during the period 2006-2014 has shown the appearance of strong double-peaked Ca II emission lines in 2008. The lines were weak, at best, during earlier observations, and monotonically faded through the remainder of our monitoring. Our observations represent unambiguous evidence for short-term variability in the debris environment of evolved planetary systems. Possible explanations for this extraordinary variability include the impact onto the dusty disc of either a single small rocky planetesimal, or of material from a highly eccentric debris tail. The increase in flux from the emission lines is sufficient that similar events could be detected in the broadband photometry of ongoing and future large-area time domai...

Wilson, David J; Koester, Detlev; Raddi, Roberto; Breedt, Elm; Southworth, John; Parsons, Steven G

2014-01-01T23:59:59.000Z

163

Low GWP Working Fluid for High Temperature Heat Pumps  

E-Print Network [OSTI]

Low GWP Working Fluid for High Temperature Heat Pumps: DR-2 Chemical Stability at High Temperatures Temp Heat Pumps: DR-2 Very Low GWP AND Non-Flammable HFC-245fa DR-2 Chemical Formula CF3CH2CHF2 HFO 171.3 Pcr [MPa] 3.65 2.9 Kontomaris-DuPont; European Heat Pump Summit, Nuremberg, October 15th, 2013

Oak Ridge National Laboratory

164

EA-1856: Conveyance of Land and Facilities at the Portsmouth Gaseous Diffusion Plant for Economic Development Purposes, Piketon, Ohio  

Broader source: Energy.gov [DOE]

This EA will evaluate the environmental impacts of conveyance of land and facilities at the Portsmouth Gaseous Diffusion Plant, in Piketon, Ohio, for economic development purposes.

165

Microhotplate for Low Power and Ultra Dense Gaseous Sensor Arrays using Recessed Silica Aerogel for Heat Insulation.  

E-Print Network [OSTI]

?? In the operation of an air pitted gaseous sensors, the microhotplate (HP) consumes almost all the power used by the sensor. The required area (more)

Kumar, Sanjay

2014-01-01T23:59:59.000Z

166

On-line vibration and analysis system at the Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

The enrichment facility in Paducah, KY uses a unique hard-wired vibration monitoring and analysis system for gaseous diffusion equipment. The axial flow and centrifugal flow compressors used in uranium enrichment range in size from 6 feet in diameter to less than one foot in diameter. These compressors must operate smoothly and safely, without breech of containment, since the working fluid of gaseous diffusion is gaseous UF/sub 6/. The condition of 1925 compressors is monitored by use of the 2500 point vibration analysis system. Since the failure mechanisms of the compressors are well known and documented, only one accelerometer per machine is needed for most machines. The system is completely automated and can generate spectra or broadband levels in either acceleration or velocity units. Levels are stored for historical review. The analyst can, via a custom telecommunications link, view and analyze data from all monitored points with an office PC. 4 figs.

Herricks, D.M.; Strunk, W.D.

1988-02-01T23:59:59.000Z

167

Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan  

SciTech Connect (OSTI)

Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

Van Hoesen, S.D.

2003-09-09T23:59:59.000Z

168

The determination of compressibility factors of gaseous propane-nitrogen mixtures  

E-Print Network [OSTI]

of thc Beg;voc cf kBSTBACT The propane-nitrogen system has been investigated in the gaseous phase at a temperature of 300 F. and at pressures up to 4/0 atmospheres. Compressibility curves for three mixtures of this system have been determined. A... the pressure corresponding to the "n " expansion ? th? the partial pressure of nitrogen the partial pressure oi' propane the total pressure of a gaseous system the universal gas constant (0. 08206 liter-atmosphere/ gram mole - oK) the absolute...

Hodges, Don

1952-01-01T23:59:59.000Z

169

The determination of compressibility factors of gaseous propane-nitrogen mixtures  

E-Print Network [OSTI]

LIBRARY A A N O'iLLEOE OF 1EXAS THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEIN MIXTURES A Thesis Cecil Herman Dickson Submitted to the Graduate School of the Agricultural and Mechanical College of' Texas in partial... f'ulf'illment of the requirements for the de~ree of MASTER OF SCIENCE Ma]or GubjectI Chemistry May I&55 THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEN MIXTURES A Thesis Cecil Herman Dickson Approved as to style...

Dickson, Cecil Herman

1955-01-01T23:59:59.000Z

170

Detection of illicit HEU production in gaseous centrifuge enrichment plants using neutron counting techniques on product cylinders  

SciTech Connect (OSTI)

Innovative and novel safeguards approaches are needed for nuclear energy to meet global energy needs without the threat of nuclear weapons proliferation. Part of these efforts will include creating verification techniques that can monitor uranium enrichment facilities for illicit production of highly-enriched uranium (HEU). Passive nondestructive assay (NDA) techniques will be critical in preventing illicit HEU production because NDA offers the possibility of continuous and unattended monitoring capabilities with limited impact on facility operations. Gaseous centrifuge enrichment plants (GCEP) are commonly used to produce low-enriched uranium (LEU) for reactor fuel. In a GCEP, gaseous UF{sub 6} spins at high velocities in centrifuges to separate the molecules containing {sup 238}U from those containing the lighter {sup 235}U. Unfortunately, the process for creating LEU is inherently the same as HEU, creating a proliferation concern. Insuring that GCEPs are producing declared enrichments poses many difficult challenges. In a GCEP, large cascade halls operating thousands of centrifuges work together to enrich the uranium which makes effective monitoring of the cascade hall economically prohibitive and invasive to plant operations. However, the enriched uranium exiting the cascade hall fills product cylinders where the UF{sub 6} gas sublimes and condenses for easier storage and transportation. These product cylinders hold large quantities of enriched uranium, offering a strong signal for NDA measurement. Neutrons have a large penetrability through materials making their use advantageous compared to gamma techniques where the signal is easily attenuated. One proposed technique for detecting HEU production in a GCEP is using neutron coincidence counting at the product cylinder take off stations. This paper discusses findings from Monte Carlo N-Particle eXtended (MCNPX) code simulations that examine the feasibility of such a detector.

Freeman, Corey R [Los Alamos National Laboratory; Geist, William H [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

171

Gamma radiological surveys of the Oak Ridge Reservation, Paducah Gaseous Diffusion Plant, and Portsmouth Gaseous Diffusion Plant, 1990-1993, and overview of data processing and analysis by the Environmental Restoration Remote Sensing Program, Fiscal Year 1995  

SciTech Connect (OSTI)

Three gamma radiological surveys have been conducted under auspices of the ER Remote Sensing Program: (1) Oak Ridge Reservation (ORR) (1992), (2) Clinch River (1992), and (3) Portsmouth Gaseous Diffusion Plant (PORTS) (1993). In addition, the Remote Sensing Program has acquired the results of earlier surveys at Paducah Gaseous Diffusion Plant (PGDP) (1990) and PORTS (1990). These radiological surveys provide data for characterization and long-term monitoring of U.S. Department of Energy (DOE) contamination areas since many of the radioactive materials processed or handled on the ORR, PGDP, and PORTS are direct gamma radiation emitters or have gamma emitting daughter radionuclides. High resolution airborne gamma radiation surveys require a helicopter outfitted with one or two detector pods, a computer-based data acquisition system, and an accurate navigational positioning system for relating collected data to ground location. Sensors measure the ground-level gamma energy spectrum in the 38 to 3,026 KeV range. Analysis can provide gamma emission strength in counts per second for either gross or total man-made gamma emissions. Gross count gamma radiation includes natural background radiation from terrestrial sources (radionuclides present in small amounts in the earth`s soil and bedrock), from radon gas, and from cosmic rays from outer space as well as radiation from man-made radionuclides. Man-made count gamma data include only the portion of the gross count that can be directly attributed to gamma rays from man-made radionuclides. Interpretation of the gamma energy spectra can make possible the determination of which specific radioisotopes contribute to the observed man-made gamma radiation, either as direct or as indirect (i.e., daughter) gamma energy from specific radionuclides (e.g., cesium-137, cobalt-60, uranium-238).

Smyre, J.L.; Moll, B.W.; King, A.L.

1996-06-01T23:59:59.000Z

172

Neutral Current Coherent Cross Sections- Implications on Gaseous Spherical TPC's for detecting SN and Earth neutrinos  

E-Print Network [OSTI]

The detection of galactic supernova (SN) neutrinos represents one of the future frontiers of low-energy neutrino physics and astrophysics. The neutron coherence of neutral currents (NC) allows quite large cross sections in the case of neutron rich targets, which can be exploited in detecting earth and sky neutrinos by measuring nuclear recoils. A core-collapse supernova represents one of the most powerful source of (anti)neutrinos in the Universe. These (NC) cross sections are not dependent on flavor conversions and, thus, their measurement will provide useful information about the neutrino source. In particular the case of SN they will yield information about the primary neutrino fluxes, i.e. before flavor conversions in neutrino sphere. The advantages of large gaseous low threshold and high resolution time projection counters (TPC) detectors TPC detectors will be discussed. These are especially promising since they are expected to be relatively cheap and easy to maintain. The information thus obtained can also be useful to other flavor sensitive detectors, e.g. the large liquid scintillation detectors like LENA. All together such detectors will provide invaluable information on the astrophysics of core-collapse explosion and on the neutrino mixing parameters. In particular, neutrino flavor transitions in SN envelope might be sensitive to the value of theta-{13} and to the unknown neutrino mass hierarchy. Till a real SN explosion is detected, one can use available earth neutrino sources with similar energy spectra to test the behavior of these detectors. Among them, the ORNL Neutron Spallation source (SNS) and boosted radioactive neutrino beams are good candidates.

J. D. Vergados

2011-11-27T23:59:59.000Z

173

A GENERAL CIRCULATION MODEL FOR GASEOUS EXOPLANETS WITH DOUBLE-GRAY RADIATIVE TRANSFER  

SciTech Connect (OSTI)

We present a new version of our code for modeling the atmospheric circulation on gaseous exoplanets, now employing a 'double-gray' radiative transfer scheme, which self-consistently solves for fluxes and heating throughout the atmosphere, including the emerging (observable) infrared flux. We separate the radiation into infrared and optical components, each with its own absorption coefficient, and solve standard two-stream radiative transfer equations. We use a constant optical absorption coefficient, while the infrared coefficient can scale as a power law with pressure; however, for simplicity, the results shown in this paper use a constant infrared coefficient. Here we describe our new code in detail and demonstrate its utility by presenting a generic hot Jupiter model. We discuss issues related to modeling the deepest pressures of the atmosphere and describe our use of the diffusion approximation for radiative fluxes at high optical depths. In addition, we present new models using a simple form for magnetic drag on the atmosphere. We calculate emitted thermal phase curves and find that our drag-free model has the brightest region of the atmosphere offset by {approx}12 Degree-Sign from the substellar point and a minimum flux that is 17% of the maximum, while the model with the strongest magnetic drag has an offset of only {approx}2 Degree-Sign and a ratio of 13%. Finally, we calculate rates of numerical loss of kinetic energy at {approx}15% for every model except for our strong-drag model, where there is no measurable loss; we speculate that this is due to the much decreased wind speeds in that model.

Rauscher, Emily [Lunar and Planetary Laboratory, University of Arizona, 1629 East University Boulevard, Tucson, AZ 85721-0092 (United States); Menou, Kristen [Department of Astronomy, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)

2012-05-10T23:59:59.000Z

174

Method for measuring the effectiveness of gaseous-contaminant removal filters  

SciTech Connect (OSTI)

The report presents a brief review of the gas-adsorption kinetics theory applicable to adsorption of gaseous contaminants by filter media, and an algorithm for assessing the effectiveness of filtering devices with flow bypass. It briefly describes the selected testing technique for measuring the effectiveness of filter media, and presents experimental data for adsorption of n-butane, toluene, and carbon monoxide.

Mahajan, B.M.

1989-08-01T23:59:59.000Z

175

Environmental Restoration Site-Specific Plan for the Portsmouth Gaseous Diffusion Plant, FY 93  

SciTech Connect (OSTI)

The purpose of this Site-Specific Plan (SSP) is to describe past, present, and future activities undertaken to implement Environmental Restoration and Waste Management goals at the Portsmouth Gaseous Diffusion Plant (PORTS). The SSP is presented in sections emphasizing Environmental Restoration description of activities, resources, and milestones.

Not Available

1993-01-15T23:59:59.000Z

176

Changes in seal capacity of fractured claystone caprocks induced by dissolved and gaseous CO2 seepage  

E-Print Network [OSTI]

Changes in seal capacity of fractured claystone caprocks induced by dissolved and gaseous CO2; accepted 17 June 2008; published 31 July 2008. [1] Claystone caprocks are often the ultimate seal for CO2 underground storage when residual CO2 gas reaches the reservoir top due to buoyancy. Permeability changes

Luquot, Linda

177

Fracture response of externally flawed aluminum cylindrical shells under internal gaseous detonation loading  

E-Print Network [OSTI]

Fracture response of externally flawed aluminum cylindrical shells under internal gaseous. Experiments were performed to observe the fracture behavior of thin- wall and initially-flawed aluminum tubes to different fracture events are analyzed. Keywords: tube fracture, detonation, crack branching, crack curving

Barr, Al

178

Alignment of molecules in gaseous transport: Alkali dimers in supersonic nozzle beams  

E-Print Network [OSTI]

Alignment of molecules in gaseous transport: Alkali dimers in supersonic nozzle beams M. P. SinhaO) + a.P lcosO), where 0 is the angle between the angular momentum vector J of the molecule and the beam direction. This method is applied to determine the alignment of Na2 molecules in a supersonic nozzle beam

Zare, Richard N.

179

Numerical assessment of stability criteria from disturbance energies in gaseous combustion  

E-Print Network [OSTI]

Numerical assessment of stability criteria from disturbance energies in gaseous combustion A, which corresponds to a ducted, laminar premixed propane-air flame, is used to assess the different terms a contribution from the unsteady heat flux-pressure correlation, allows a better agreement with the numerical

Nicoud, Franck

180

Synthesis of thin films and materials utilizing a gaseous catalyst  

DOE Patents [OSTI]

A method for the fabrication of nanostructured semiconducting, photoconductive, photovoltaic, optoelectronic and electrical battery thin films and materials at low temperature, with no molecular template and no organic contaminants. High-quality metal oxide semiconductor, photovoltaic and optoelectronic materials can be fabricated with nanometer-scale dimensions and high dopant densities through the use of low-temperature biologically inspired synthesis routes, without the use of any biological or biochemical templates.

Morse, Daniel E; Schwenzer, Birgit; Gomm, John R; Roth, Kristian M; Heiken, Brandon; Brutchey, Richard

2013-10-29T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Safeguards Verification Measurements using Laser Ablation, Absorbance Ratio Spectrometry in Gaseous Centrifuge Enrichment Plants  

SciTech Connect (OSTI)

Laser Ablation Absorbance Ratio Spectrometry (LAARS) is a new verification measurement technology under development at the US Department of Energys (DOE) Pacific Northwest National Laboratory (PNNL). LAARS uses three lasers to ablate and then measure the relative isotopic abundance of uranium compounds. An ablation laser is tightly focused on uranium-bearing solids producing a small plume containing uranium atoms. Two collinear wavelength-tuned spectrometry lasers transit through the plume and the absorbance of U-235 and U-238 isotopes are measured to determine U-235 enrichment. The measurement has high relative precision and detection limits approaching the femtogram range for uranium. It is independent of chemical form and degree of dilution with nuisance dust and other materials. High speed sample scanning and pinpoint characterization allow measurements on millions of particles/hour to detect and analyze the enrichment of trace uranium in samples. The spectrometer is assembled using commercially available components at comparatively low cost, and features a compact and low power design. Future designs can be engineered for reliable, autonomous deployment within an industrial plant environment. Two specific applications of the spectrometer are under development: 1) automated unattended aerosol sampling and analysis and 2) on-site small sample destructive assay measurement. The two applications propose game-changing technological advances in gaseous centrifuge enrichment plant (GCEP) safeguards verification. The aerosol measurement instrument, LAARS-environmental sampling (ES), collects aerosol particles from the plant environment in a purpose-built rotating drum impactor and then uses LAARS-ES to quickly scan the surface of the impactor to measure the enrichments of the captured particles. The current approach to plant misuse detection involves swipe sampling and offsite analysis. Though this approach is very robust it generally requires several months to obtain results from a given sample collection. The destructive assay instrument, LAARS-destructive assay (DA), uses a simple purpose-built fixture with a sampling planchet to collect adsorbed UF6 gas from a cylinder valve or from a process line tap or pigtail. A portable LAARS-DA instrument scans the microgram quantity of uranium collected on the planchet and the assay of the uranium is measured to ~0.15% relative precision. Currently, destructive assay samples for bias defect measurements are collected in small sample cylinders for offsite mass spectrometry measurement.

Anheier, Norman C.; Cannon, Bret D.; Qiao, Hong (Amy) [Amy; Phillips, Jon R.

2012-07-01T23:59:59.000Z

182

Development of Compact Gaseous Sensors with Internal Reference for  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent Companya new highModeling

183

Advanced Laser Diagnostics Development for the Characterization of Gaseous High Speed Flows  

E-Print Network [OSTI]

up of the feeding block fitted with two pulsed valves (c). Mach 4.6 and Mach 6.2 nozzles (d) ....................... 63 3.9 Gas throughput into the PHAT cell using 4 pulsed valves. The maximum capacity of the pumping system is shown... for comparison ....... 64 3.10 NO PLIF image sequence of a 12 ms Mach 4.6 flow pulse corresponding to the beginning of the pulse (a), to the fully established flow (b), and to the end of the pulse (c...

Sanchez-Gonzalez, Rodrigo

2012-07-16T23:59:59.000Z

184

Thermodynamic study of gaseous sodium-phosphorous-oxygen ternary molecules by high temperature mass spectrometry  

E-Print Network [OSTI]

. 8 + 8, 67. 1 + 8, 79. 9 + 4, 105 + 10, 109. 2 + 8 and 14. 3 + 6, 0 -1 respectively. The atomization energies, AH , in keel mole for the a' molecules, NaPO, NaOP, NaPO , and NaPO were determined as 210. 7 + 11, 212. 4 + ll, 329. 7 + 11, and 432. 7... ) I(Nap ) Relative I(PO ) ion currents I(P02 ) in amps. I(NaPO ) I(NaP02 ) I(NaP03 ) 1 1270 1. 38xlp-o 2 1317 2. 98%10 3 1320 2. 73?10 4 1336 3. 78xlp 5 1353 5. 51%10 6 1277 1. 40xlp -8 7 1301 1. 50xlp 8 1308 1. 61xlp 9 1315 '1. 74xlp...

Miller, Federico

1974-01-01T23:59:59.000Z

185

Natural phenomena hazards evaluation of equipment and piping of Gaseous Diffusion Plant Uranium Enrichment Facility  

SciTech Connect (OSTI)

In support of the Gaseous Diffusion Plant Safety Analysis Report Upgrade program (GDP SARUP), a natural phenomena hazards evaluation was performed for the main process equipment and piping in the uranium enrichment buildings at Paducah and Portsmouth gaseous diffusion plants. In order to reduce the cost of rigorous analyses, the evaluation methodology utilized a graded approach based on an experience data base collected by SQUG/EPRI that contains information on the performance of industrial equipment and piping during past earthquakes. This method consisted of a screening walkthrough of the facility in combination with the use of engineering judgment and simple calculations. By using these screenings combined with evaluations that contain decreasing conservatism, reductions in the time and cost of the analyses were significant. A team of experienced seismic engineers who were trained in the use of the DOE SQUG/EPRI Walkdown Screening Material was essential to the success of this natural phenomena hazards evaluation.

Singhal, M.K.; Kincaid, J.H.; Hammond, C.R.; Stockdale, B.I.; Walls, J.C. [Oak Ridge National Lab., TN (United States). Technical Programs and Services; Brock, W.R.; Denton, D.R. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States)

1995-12-31T23:59:59.000Z

186

Process and system for removing sulfur from sulfur-containing gaseous streams  

DOE Patents [OSTI]

A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

2012-08-14T23:59:59.000Z

187

Nuclear safety procedure upgrade project at USEC/MMUS gaseous diffusion plants  

SciTech Connect (OSTI)

Martin Marietta Utility Services has embarked on a program to upgrade procedures at both of its Gaseous Diffusion Plant sites. The transition from a U.S. Department of Energy government-operated facility to U.S. Nuclear Regulatory Commission (NRC) regulated has necessitated a complete upgrade of plant operating procedures and practices incorporating human factors as well as a philosophy change in their use. This program is designed to meet the requirements of the newly written 10CFR76, {open_quotes}The Certification of Gaseous Diffusion Plants,{close_quotes} and aid in progression toward NRC certification. A procedures upgrade will help ensure increased nuclear safety, enhance plant operation, and eliminate personnel procedure errors/occurrences.

Kocsis, F.J. III

1994-12-31T23:59:59.000Z

188

Breached cylinder incident at the Portsmouth gaseous diffusion plant  

SciTech Connect (OSTI)

On June 16, 1990, during an inspection of valves on partially depleted product storage cylinders, a 14-ton partially depleted product cylinder was discovered breached. The cylinder had been placed in long-term storage in 1977 on the top row of Portsmouth`s (two rows high) storage area. The breach was observed when an inspector noticed a pile of green material along side of the cylinder. The breach was estimated to be approximately 8- inches wide and 16-inches long, and ran under the first stiffening ring of the cylinder. During the continuing inspection of the storage area, a second 14-ton product cylinder was discovered breached. This cylinder was stacked on the bottom row in the storage area in 1986. This breach was also located adjacent to a stiffening ring. This paper will discuss the contributing factors of the breaching of the cylinders, the immediate response, subsequent actions in support of the investigation, and corrective actions.

Boelens, R.A. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

1991-12-31T23:59:59.000Z

189

Environmental Restoration Site-Specific Plan for the Paducah Gaseous Diffusion Plant, FY 93  

SciTech Connect (OSTI)

This report provides an overview of the major Environmental Restoration (ER) concerns at Paducah Gaseous Diffusion Plant (PGDP). The identified solid waste management units at PGDP are listed. In the Department of Energy (DOE) Five Year Plan development process, one or more waste management units are addressed in a series of activity data sheets (ADSs) which identify planned scope, schedule, and cost objectives that are representative of the current state of planned technical development for individual or multiple sites.

Not Available

1993-01-15T23:59:59.000Z

190

Nuclear criticality safety evaluation of Spray Booth Operations in X-705, Portsmouth Gaseous Diffusion Plant  

SciTech Connect (OSTI)

This report evaluates nuclear criticality safety for Spray Booth Operations in the Decontamination and Recovery Facility, X-705, at the Portsmouth Gaseous Diffusion Plant. A general description of current procedures and related hardware/equipment is presented. Control parameters relevant to nuclear criticality safety are explained, and a consolidated listing of administrative controls and safety systems is developed. Based on compliance with DOE Orders and MMES practices, the overall operation is evaluated, and recommendations for enhanced safety are suggested.

Sheaffer, M.K.; Keeton, S.C.

1993-09-20T23:59:59.000Z

191

Joint Test Plan to Identify the Gaseous By-Products of CH3I Loading on AgZ  

SciTech Connect (OSTI)

The objective of this test plan is to describe research to determine the gaseous by-products of the adsorption of CH3I on hydrogen reduced silver exchanged mordenite (AgZ).

R. T. Jubin; N. R. Soelberg; D. M. Strachan; T. M. Nenoff; B. B. Spencer

2012-12-01T23:59:59.000Z

192

EA-0767: Construction and Experiment of an Industrial Solid Waste Landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio  

Broader source: Energy.gov [DOE]

This EA evaluates the environmental impacts of a proposal to construct and operate a solid waste landfill within the boundary at the U.S. Department of Energy's Portsmouth Gaseous Diffusion plant...

193

Fuel age impacts on gaseous fission product capture during separations  

SciTech Connect (OSTI)

As a result of fuel reprocessing, volatile radionuclides will be released from the facility stack if no processes are put in place to remove them. The radionuclides that are of concern in this document are 3H, 14C, 85Kr, and 129 Rosnick 2007 I. The question we attempt to answer is how efficient must this removal process be for each of these radionuclides? To answer this question, we examine the three regulations that may impact the degree to which these radionuclides must be reduced before process gases can be released from the facility. These regulations are 40 CFR 61 (EPA 2010a), 40 CFR 190(EPA 2010b), and 10 CFR 20 (NRC 2012), and they apply to the total radonuclide release and to the dose to a particular organ the thyroid. Because these doses can be divided amongst all the radionuclides in different ways and even within the four radionuclides in question, several cases are studied. These cases consider for the four analyzed radionuclides inventories produced for three fuel typespressurized water reactor uranium oxide (PWR UOX), pressurized water reactor mixed oxide (PWR MOX), and advanced high-temperature gascooled reactor (AHTGR)several burnup values and time out of reactor extending to 200 y. Doses to the maximum exposed individual (MEI) are calculated with the EPA code CAP-88 ( , 1992). Two dose cases are considered. The first case, perhaps unrealistic, assumes that all of the allowable dose is assigned to the volatile radionuclides. In lieu of this, for the second case a value of 10% of the allowable dose is arbitrarily selected to be assigned to the volatile radionuclides. The required decontamination factors (DFs) are calculated for both of these cases, including the case for the thyroid dose for which 14C and 129I are the main contributors. However, for completeness, for one fuel type and burnup, additional cases are provided, allowing 25% and 50% of the allowable dose to be assigned to the volatile radionuclides. Because 3H and 85Kr have relatively short half-lives, 12.3 y and 10.7 y, respectively, the dose decreases with the time from when the fuel is removed from the reactor to the time it is processed (herein fuel age). One possible strategy for limiting the discharges of these short halflife radionuclides is to allow the fuel to age to take advantage of radioactive decay. Therefore, the doses and required DFs are calculated as a function of fuel age. Here we calculate, given the above constraints and assumptions, the minimum ages for each fuel type that would not require additional effluent controls for the shorter half-life volatile radionuclides based on dose considerations. With respect to 129I doses, we find that the highest dose is calculated with iodine as a fine particulate. The dose scales as the fraction of the total 129I that is particulate. Therefore, we assume for all of our calculations that 100% of the 129I is particulate and allow the user of the results given here to scale our calculated doses to their needs. To summarize the data given in the body and appendices of this report, we find that the principal isotopes of concern are 3H and 129I, the latter requiring the highest DFs. The maximum DF value for 129I is 8000 for the illustrated cases. The required DF for 3H could be as high as 720, depending on the age of the fuel processed. The DF for 85Kr could be up to ~60, depending on fuel age. The DF for 14C is in many cases 1 (no treatment required) but could be as high as 30. The DFs required are within the range of DFs that are reported for the capture technologies that are available for the volatile radionuclides. Achieving the required 129I and 3H DFs is more challenging. Variations in stack design and other design factors may also significantly impact the DF requirements.

Jubin, Robert T.; Soelberg, Nicolas R.; Strachan, Denis M.; Ilas, G.

2012-09-21T23:59:59.000Z

194

Source term evaluation for UF{sub 6} release event in feed facility at gaseous diffusion plants  

SciTech Connect (OSTI)

An assessment of UF{sub 6} release accidents was conducted for the feed facility of a gaseous diffusion plant (GDP). Release rates from pig-tail connections were estimated from CYLIND code predictions, whereas, MELCOR was utilized for simulating reactions of UF{sub 6} with moisture and consequent transport of UO{sub 2}F{sub 2} aerosols and HF vapor through the building and to the environment. Two wind speeds were utilized. At the high end (Case 1) a wind speed of {approximately} 1 m/s (200 fpm) was assumed to flow parallel to the building length. At the low end (Case 2) to represent stagnant conditions a corresponding wind speed of 1 cm/s (2 fpm) was utilized. A further conservative assumption was made to specify no closure of crane and train doors at either end of the building. Relaxation of this assumption should provide for additional margins. Results indicated that, for the high (200 fpm) wind speed, close to 66% of the UO{sub 2}F{sub 2} aerosols and 100% of the HF gas get released to the environment over a 10-minute period. However, for the low (2 fpm) wind speed, negligible amount ({approximately} 1% UO{sub 2}F{sub 2}) of aerosols get released even over a 2 hour period.

Kim, S.H.; Taleyarkhan, R.P.

1997-01-30T23:59:59.000Z

195

Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust  

DOE Patents [OSTI]

A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

2012-05-15T23:59:59.000Z

196

Interchangeability of gaseous fuels - The importance of the Wobbe-index  

SciTech Connect (OSTI)

The Wobbe-index is introduced as an important gas quality criterion when interchanging gaseous fuels for engines. Changes in fuel gas composition appear not to induce noticeable changes in air to fuel ratio and combustion velocity when the Wobbe-index remains the same. This implies that no re-adjustment of ignition timing and air to fuel ratio settings is required, then. The volumetric energy content, the explosion limits and the knock resistance of a mixture can vary to a moderate extent when the Wobbe-index is constant and the gas composition varies.

Klimstra, J.

1986-01-01T23:59:59.000Z

197

The Stability of an Isentropic Model for a Gaseous Relativistic Star  

E-Print Network [OSTI]

We show that the isentropic subclass of Buchdahl's exact solution for a gaseous relativistic star is stable and gravitationally bound for all values of the compactness ratio $u [\\equiv (M/R)$, where $M$ is the total mass and $R$ is the radius of the configuration in geometrized units] in the range, $0 < u \\leq 0.20$, corresponding to the {\\em regular} behaviour of the solution. This result is in agreement with the expectation and opposite to the earlier claim found in the literature.

P. S. Negi

2007-02-01T23:59:59.000Z

198

2013 GASEOUS IONS GORDON RESEARCH CONFERENCE, FEBRUARY 24 - MARCH 1, 2013  

SciTech Connect (OSTI)

The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The long-standing goal of our community is to develop new strategies for capturing complex molecular architectures as gas phase ions where they can be isolated, characterized and manipulated with great sensitivity. Emergent areas of interest include catalytic mechanisms, cryogenic processing of ions extracted from solution, ion fragmentation mechanisms, and new methods for ion formation and structural characterization. The conference will cover theoretical and experimental advances on systems ranging from model studies at the molecular scale to preparation of nanomaterials and characterization of large biological molecules.

Williams, Evan

2013-03-01T23:59:59.000Z

199

Construction and operation of an industrial solid waste landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio  

SciTech Connect (OSTI)

The US Department of Energy (DOE), Office of Waste Management, proposes to construct and operate a solid waste landfill within the boundary of the Portsmouth Gaseous Diffusion Plant (PORTS), Piketon, Ohio. The purpose of the proposed action is to provide PORTS with additional landfill capacity for non-hazardous and asbestos wastes. The proposed action is needed to support continued operation of PORTS, which generates non-hazardous wastes on a daily basis and asbestos wastes intermittently. Three alternatives are evaluated in this environmental assessment (EA): the proposed action (construction and operation of the X-737 landfill), no-action, and offsite shipment of industrial solid wastes for disposal.

NONE

1995-10-01T23:59:59.000Z

200

Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September 15, 2010Energy6Department ofGaseous Diffusion Plant Director's

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 Summary  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September 15, 2010Energy6Department ofGaseous Diffusion Plant

202

Apparatus and method for enhanced chemical processing in high pressure and atmospheric plasmas produced by high frequency electromagnetic waves  

DOE Patents [OSTI]

An apparatus and method for creating high temperature plasmas for enhanced chemical processing of gaseous fluids, toxic chemicals, and the like, at a wide range of pressures, especially at atmospheric and high pressures includes an electro-magnetic resonator cavity, preferably a reentrant cavity, and a wave guiding structure which connects an electro-magnetic source to the cavity. The cavity includes an intake port and an exhaust port, each having apertures in the conductive walls of the cavity sufficient for the intake of the gaseous fluids and for the discharge of the processed gaseous fluids. The apertures are sufficiently small to prevent the leakage of the electro-magnetic radiation from the cavity. Gaseous fluid flowing from the direction of the electro-magnetic source through the guiding wave structure and into the cavity acts on the plasma to push it away from the guiding wave structure and the electro-magnetic source. The gaseous fluid flow confines the high temperature plasma inside the cavity and allows complete chemical processing of the gaseous fluids at a wide range of pressures.

Efthimion, Philip C. (Bedminister, NJ); Helfritch, Dennis J. (Flemington, NJ)

1989-11-28T23:59:59.000Z

203

E-Print Network 3.0 - alternative high-z cosmic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 > >> 1 StructureStructure in the Universein the Universe Summary: -rays Gaseous Cosmic Web - Baryonic gas traces the Cosmic Web: Ly forest neutral hydrogen gas, mostly at high...

204

Project plan for the background soils project for the Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

SciTech Connect (OSTI)

The Background Soils Project for the Paducah Gaseous Diffusion Plant (BSPP) will determine the background concentration levels of selected naturally occurring metals, other inorganics, and radionuclides in soils from uncontaminated areas in proximity to the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The data will be used for comparison with characterization and compliance data for soils, with significant differences being indicative of contamination. All data collected as part of this project will be in addition to other background databases established for the PGDP. The BSPP will address the variability of surface and near-surface concentration levels with respect to (1) soil taxonomical types (series) and (2) soil sampling depths within a specific soil profile. The BSPP will also address the variability of concentration levels in deeper geologic formations by collecting samples of geologic materials. The BSPP will establish a database, with recommendations on how to use the data for contaminated site assessment, and provide data to estimate the potential human and health and ecological risk associated with background level concentrations of potentially hazardous constituents. BSPP data will be used or applied as follows.

NONE

1995-09-01T23:59:59.000Z

205

Site-specific earthquake response analysis for Paducah Gaseous Diffusion Plant, Paducah, Kentucky. Final report  

SciTech Connect (OSTI)

The Paducah Gaseous Diffusion Plant (PGDP), owned by the US Department of Energy (DOE) and operated under contract by Martin Marietta Energy systems, Inc., is located southwest of Paducah, Kentucky. An aerial photograph and an oblique sketch of the plant are shown in Figures 1 and 2, respectively. The fenced portion of the plant consists of 748 acres. This plant was constructed in the 1950`s and is one of only two gaseous diffusion plants in operation in the United States; the other is located near Portsmouth, Ohio. The facilities at PGDP are currently being evaluated for safety in response to natural seismic hazards. Design and evaluation guidelines to evaluate the effects of earthquakes and other natural hazards on DOE facilities follow probabilistic hazard models that have been outlined by Kennedy et al. (1990). Criteria also established by Kennedy et al. (1990) classify diffusion plants as ``moderate hazard`` facilities. The US Army Engineer Waterways Experiment Station (WES) was tasked to calculate the site response using site-specific design earthquake records developed by others and the results of previous geotechnical investigations. In all, six earthquake records at three hazard levels and four individual and one average soil columns were used.

Sykora, D.W.; Davis, J.J.

1993-08-01T23:59:59.000Z

206

Using large environmental chamber technique for gaseous contaminant removal equipment test  

SciTech Connect (OSTI)

The US Association of Home Appliance Manufacturers (AHAM) has set a voluntary standard for testing the initial dust-removal capacity of portable air cleaners. In the authors` test of portable air cleaners for the local consumer council, the AHAM method was extended to test the initial removal capacity for gaseous phase pollutants. Also, carbon filters` efficiency change over time in toluene removal on a number of air cleaners was tested. In using a large chamber to carry out these tests, the chamber wall adsorption and re-emission effects were experimentally quantified. These tests indicated that a large chamber, with its wall surface adsorption controlled, is simple and robust to use to quantify the initial cleaning capacity for gaseous phase pollutants. Based on these test results, a large chamber method is proposed to test the performance lifetimes of portable air cleaners. The system advantages of the method over the in-duct performance life test methods are that no continuous air-cleaning system is required and that the chamber`s humidity and temperature can be maintained at the desired values more easily with the combination of a unitary dehumidifier and a bubbler system. This paper will present the trial results with portable air cleaner tests and discuss the large environmental chamber techniques.

Niu, J.; Tung, T.C.W.; Chui, V.W.Y. [Hong Kong Polytechnic Univ. (Hong Kong). Dept. of Building Services Engineering

1998-12-31T23:59:59.000Z

207

The Radiochemical Analysis of Gaseous Samples (RAGS) Apparatus for Nuclear Diagnostics at the National Ignition Facility  

SciTech Connect (OSTI)

The RAGS (Radiochemical Analysis of Gaseous Samples) diagnostic apparatus was recently installed at the National Ignition Facility. Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

Shaughnessy, D A; Velsko, C A; Jedlovec, D R; Yeamans, C B; Moody, K J; Tereshatov, E; Stoeffl, W; Riddle, A

2012-05-11T23:59:59.000Z

208

Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report  

SciTech Connect (OSTI)

The Assistant Secretary for Environment has responsibility for identifying, characterizing, and ameliorating the environmental, health, and safety issues and public concerns associated with commercial operation of specific energy systems. The need for developing a safety and environmental control assessment for liquefied gaseous fuels was identified by the Environmental and Safety Engineering Division as a result of discussions with various governmental, industry, and academic persons having expertise with respect to the particular materials involved: liquefied natural gas, liquefied petroleum gas, hydrogen, and anhydrous ammonia. This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in Fiscal Year (FY)-1979 and early FY-1980. Volume 1 (Executive Summary) describes the background, purpose and organization of the LGF Program and contains summaries of the 25 reports presented in Volumes 2 and 3. Annotated bibliographies on Liquefied Natural Gas (LNG) Safety and Environmental Control Research and on Fire Safety and Hazards of Liquefied Petroleum Gas (LPG) are included in Volume 1.

Not Available

1980-10-01T23:59:59.000Z

209

Method and system for low-NO.sub.x dual-fuel combustion of liquid and/or gaseous fuels  

DOE Patents [OSTI]

A method and apparatus for combustion in which a pressurized preheated liquid fuel is atomized and a portion thereof flash vaporized, creating a mixture of fuel vapor and liquid droplets. The mixture is mixed with primary combustion oxidant, producing a fuel/primary oxidant mixture which is then injected into a primary combustion chamber in which the fuel/primary oxidant mixture is partially combusted, producing a secondary gaseous fuel containing hydrogen and carbon oxides. The secondary gaseous fuel is mixed with a secondary combustion oxidant and injected into the second combustion chamber wherein complete combustion of the secondary gaseous fuel is carried out. The resulting second stage flue gas containing very low amounts of NO.sub.x is then vented from the second combustion chamber.

Gard, Vincent; Chojnacki, Dennis A; Rabovitser, Ioseph K

2014-12-02T23:59:59.000Z

210

FLAMMABILITY OF UPHOLSTERED FURNITURE USING  

E-Print Network [OSTI]

.4 Specimen codes. 9 4 OXYGEN CONSUMPTION CALORIMETRY 10 4.1 Introduction 10 4.2 Calculation of Heat Release load and life safety threat. Due to the rapid growth rate of the organic material and the toxic combustion products, these fires usually lead to hazardous conditions and uncontrollable fires. The heat

Hickman, Mark

211

Reassessment of liquefaction potential and estimation of earthquake- induced settlements at Paducah Gaseous Diffusion Plant, Paducah, Kentucky. Final report  

SciTech Connect (OSTI)

This report documents a reassessment of liquefaction potential and estimation of earthquake-induced settlements for the U.S. Department of Energy (DOE), Paducah Gaseous Diffusion Plant (PGDP), located southwest of Paducah, KY. The U.S. Army Engineer Waterways Experiment Station (WES) was authorized to conduct this study from FY91 to FY94 by the DOE, Oak Ridge Operations (ORO), Oak Ridge, TN, through Inter- Agency Agreement (IAG) No. DE-AI05-91OR21971. The study was conducted under the Gaseous Diffusion Plant Safety Analysis Report (GDP SAR) Program.

Sykora, D.W.; Yule, D.E.

1996-04-01T23:59:59.000Z

212

Indirect NMR detection of 235U in gaseous uranium hexafluoride National Center for Physics, P.O. Box MG-6, Bucharest, Romania  

E-Print Network [OSTI]

dans le UF6 gazeux. L'examen de la raie d'absorption du 19F appartenant au UF6 gazeux isotopiquement in indirect detection of the 235U nucleus in gaseous UF6 is discussed. The 19F absorption spectra linewidths in gaseous UF6 was investigated as a function of 235U enrichment, revealing a dependence on the isotope

Paris-Sud XI, Université de

213

Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report  

SciTech Connect (OSTI)

Volume 2 consists of 19 reports describing technical effort performed by Government Contractors in the area of LNG Safety and Environmental Control. Report topics are: simulation of LNG vapor spread and dispersion by finite element methods; modeling of negatively buoyant vapor cloud dispersion; effect of humidity on the energy budget of a liquefied natural gas (LNG) vapor cloud; LNG fire and explosion phenomena research evaluation; modeling of laminar flames in mixtures of vaporized liquefied natural gas (LNG) and air; chemical kinetics in LNG detonations; effects of cellular structure on the behavior of gaseous detonation waves under transient conditions; computer simulation of combustion and fluid dynamics in two and three dimensions; LNG release prevention and control; the feasibility of methods and systems for reducing LNG tanker fire hazards; safety assessment of gelled LNG; and a four band differential radiometer for monitoring LNG vapors.

None

1980-10-01T23:59:59.000Z

214

A probabilistic safety analysis of UF{sub 6} handling at the Portsmouth Gaseous Diffusion Plant  

SciTech Connect (OSTI)

A probabilistic safety study of UF{sub 6} handling activities at the Portsmouth Gaseous Diffusion Plant has recently been completed. The analysis provides a unique perspective on the safety of UF{sub 6} handling activities. The estimated release frequencies provide an understanding of current risks, and the examination of individual contributors yields a ranking of important plant features and operations. Aside from the probabilistic results, however, there is an even more important benefit derived from a systematic modeling of all operations. The integrated approach employed in the analysis allows the interrelationships among the equipment and the required operations to be explored in depth. This paper summarizes the methods used in the study and provides an overview of some of the technical insights that were obtained. Specific areas of possible improvement in operations are described.

Boyd, G.J.; Lewis, S.R.; Summitt, R.L. [Safety and Reliability Optimization Services (SAROS), Inc., Knoxville, TN (United States)

1991-12-31T23:59:59.000Z

215

Purex Plant gaseous iodine-129 control capability and process development requirements  

SciTech Connect (OSTI)

This report describes the ability of the Purex Plant to effectively control iodine-129 emissions. Based on historical evidence, the current Purex Plant iodine control system appears capable of meeting the goal of limiting gaseous iodine-129 emissions at the point of discharge to levels stipulated by the Department of Energy (DOE) for an uncontrolled area. Expected decontamination factors (DF`s) with the current system will average about 100 and will be above the calculated DF`s of 2.2 and 87 required to meet DOE yearly average concentration limits for controlled and uncontrolled areas respectively, but below the calculated DF of 352 required for meeting the proposed Environmental Protection Agency (EPA) mass emission limit. Chemical costs for maintaining compliance with the DOE limits will be approximately $166 per metric ton of fuel processed (based on a silver nitrate price of $12.38/oz). Costs will increase in proportion to increases in silver prices.

Evoniuk, C.J.

1981-01-01T23:59:59.000Z

216

Report on the Biological Monitoring Program at Paducah Gaseous Diffusion Plant December 1992--December 1993  

SciTech Connect (OSTI)

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The goals of BMP are to demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, characterize potential health and environmental impacts, document the effects of pollution abatement facilities on stream biota, and recommend any program improvements that would increase effluent treatability. The BMP for PGDP consists of three major tasks: effluent and ambient toxicity monitoring, bioaccumulation studies, and ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1992 to December 1993, although activities conducted outside this time period are included as appropriate.

Kszos, L.A.; Hinzman, R.L.; Peterson, M.J.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

1995-06-01T23:59:59.000Z

217

Paducah Gaseous Diffusion Plant Annual Site Environmental Report summary for 1993  

SciTech Connect (OSTI)

This report contains summaries of the environmental programs at Paducah Gaseous Diffusion Plant, environmental monitoring and the results, and the impact of operations on the environment and the public for 1993. The environmental monitoring program at Paducah includes effluent monitoring and environmental surveillance. Effluent monitoring is measurement of releases as they occur. Contaminants are released through either airborne emissions or liquids discharged from the plant. These releases occur as part of normal site operations, such as cooling water discharged from the uranium enrichment cascade operations or airborne releases from ventilation systems. In the event of system failure, this monitoring provides timely warning so that corrective action can be taken before releases reach an unsafe level. Environmental surveillance tracks the dispersion of materials into the environment after they have been released. This involves the collection of samples from various media, such as water, soil, vegetation, and food crops, and the analysis of these samples for certain radionuclides, chemicals, and metals.

Not Available

1994-11-01T23:59:59.000Z

218

Portsmouth Gaseous Diffusion Plant Annual Site Environmental Report summary for 1993  

SciTech Connect (OSTI)

This report contains summaries of the environmental programs at Paducah Gaseous Diffusion Plant, environmental monitoring and the results, and the impact of operations on the environment and the public for 1993. The environmental monitoring program at Paducah includes effluent monitoring and environmental surveillance. Effluent monitoring is measurement of releases as they occur. Contaminants are released through either airborne emissions or liquids discharged from the plant. These releases occur as part of normal site operations, such as cooling water discharged from the uranium enrichment cascade operations or airborne releases from ventilation systems. In the event of system failure, this monitoring provides timely warning so that corrective action can be taken before releases reach an unsafe level. Environmental surveillance tracks the dispersion of materials into the environment after they have been released. This involves the collection of samples from various media, such as water, soil, vegetation, and food crops, and the analysis of these samples for certain radionuclides, chemicals, and metals.

Not Available

1994-11-01T23:59:59.000Z

219

Local drainage analyses of the Paducah and Portsmouth Gaseous Diffusion Plants during an extreme storm  

SciTech Connect (OSTI)

Local drainage analyses have been performed for the Paducah and Portsmouth Gaseous Diffusion Plants during an extreme storm having an approximate 10,000-yr recurrence interval. This review discusses the methods utilized to accomplish the analyses in accordance with US Department of Energy (DOE) design and evaluation guidelines, and summarizes trends, results, generalizations, and uncertainties applicable to other DOE facilities. Results indicate that some culverts may be undersized, and that the storm sewer system cannot drain the influx of precipitation from the base of buildings. Roofs have not been designed to sustain ponding when the primary drainage system is clogged. Some underground tunnels, building entrances, and ground level air intakes may require waterproofing.

Johnson, R.O.; Wang, J.C.; Lee, D.W.

1993-11-01T23:59:59.000Z

220

Seismically-induced soil amplification at the DOE Paducah Gaseous Diffusion Plant site  

SciTech Connect (OSTI)

A site-specific earthquake site response (soil amplification) study is being conducted for the Department of Energy (DOE), Paducah Gaseous Diffusion Plant (PGDP). This study is pursuant to an upgraded Final Safety Analysis Report in accordance with requirements specified by DOE. The seismic hazard at PGDP is dominated by the New Madrid Seismic Zone. Site-specific synthetic earthquake records developed by others were applied independently to four soil columns with heights above baserock of about 325 ft. The results for the 1000-year earthquake event indicate that the site period is between 1.0 and 1.5 sec. Incident shear waves are amplified at periods of motion greater than 0.15 sec. The peak free-field horizontal acceleration, occurring at very low periods, is 0.28 g. 13 refs., 13 figs.

Sykora, D.W.; Haynes, M.E. (Army Engineer Waterways Experiment Station, Vicksburg, MS (United States). Geotechnical Lab.); Brock, W.R.; Hunt, R.J.; Shaffer, K.E. (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States))

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals  

DOE Patents [OSTI]

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

Hobson, David O. (Oak Ridge, TN); Alexeff, Igor (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

1988-01-01T23:59:59.000Z

222

Liquefied gaseous fuels safety and environmental control assessment program: third status report  

SciTech Connect (OSTI)

This Status Report contains contributions from all contractors currently participating in the DOE Liquefied Gaseous Fuels (LG) Safety and Environmental Control Assessment Program and is presented in two principal sections. Section I is an Executive Summary of work done by all program participants. Section II is a presentation of fourteen individual reports (A through N) on specific LGF Program activities. The emphasis of Section II is on research conducted by Lawrence Livermore National Laboratory (Reports A through M). Report N, an annotated bibliography of literature related to LNG safety and environmental control, was prepared by Pacific Northwest Laboratory (PNL) as part of its LGF Safety Studies Project. Other organizations who contributed to this Status Report are Aerojet Energy Conversion Company; Applied Technology Corporation; Arthur D. Little, Incorporated; C/sub v/ International, Incorporated; Institute of Gas Technology; and Massachusetts Institute of Technology. Separate abstracts have been prepared for Reports A through N for inclusion in the Energy Data Base.

Not Available

1982-03-01T23:59:59.000Z

223

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1990 to November 1992  

SciTech Connect (OSTI)

On September 23, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). Beginning in fall 1991, the Environmental Sciences Division (ESD) at Oak Ridge National Lab (ORNL) added data collection and report preparation to its responsibilities for the PGDP BMP. The BMP has been continued because it has proven to be extremely valuable in identifying those effluents with the potential for adversely affecting instream fauna, assessing the ecological health of receiving streams, guiding plans for remediation, and protecting human health. In September 1992, a renewed permit was issued which requires toxicity monitoring of continuous and intermittent outfalls on a quarterly basis. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities. This report includes ESD/ORNL activities occurring from December 1990 to November 1992.

Kszos, L.A. [ed.

1994-03-01T23:59:59.000Z

224

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

225

Shaping of fuel delivery characteristics for solenoid operated diesel engine gaseous injectors  

SciTech Connect (OSTI)

Solenoid operated gaseous injectors, when compared to conventional liquid fuel diesel injectors, differ in the way the fuel dose and its discharge rate are controlled. While in conventional diesel systems, the fuel dose and its injection rate depends on the fuel injection pump effective stroke and on the plunger diameter and velocity, the solenoid injectors operate in an on-off manner which limits the ability to control the gas discharge rate, resulting in its profile to be basically rectangular in shape. To reduce the gas injection rate at the beginning of the injection process in order to suppress the diesel-knock phenomenon, similar procedures as used in diesel engines could be implemented. One such approach is to use a throttling type pintle nozzle, and another method is to use a double-spring injector with a hole nozzle. The rationale for using such nozzle configurations is that gaseous fuels do not require atomization, and therefore, can be injected at lower discharge velocities than with liquid fuels. The gas delivery characteristics from a solenoid injector has been computer-simulated in order to assess the impact of the investigated three modes of fuel discharge rate control strategies. The simulation results confirmed that the gas dose and its discharge rate can be shaped as required. An experimental set-up is described to measure the gas discharge rate using a special gas injection mass flow rate indicator with a strain-gage sensor installed at the entry to a long tube, similar to that proposed by Bosch for liquid fuel volumetric flow rate measurements.

Hong, H.; Krepec, T.; Kekedjian, H.

1996-09-01T23:59:59.000Z

226

The Effect of Debris on Collector Optics, its Mitigation and Repair: Next-Step a Gaseous Sn EUV DPP Source  

E-Print Network [OSTI]

The Effect of Debris on Collector Optics, its Mitigation and Repair: Next-Step a Gaseous Sn EUV DPP to advanced fuel plasma EUV sources is collector lifetime. The Illinois Debris-mitigation EUV Applications based on this work. Keywords: EUV source, debris, optics, collector lifetime, mitigation, plasma

Spila, Timothy P.

227

EA-1927: Conveyance of Land and Facilities at the Paducah Gaseous Diffusion Plant for Economic Development Purposes, Paducah, Kentucky  

Broader source: Energy.gov [DOE]

DOEs Portsmouth/Paducah Project Office is preparing an EA for a proposal to convey DOE land and facilities at the Paducah Gaseous Diffusion Plant to the Paducah Area Community Reuse Organization and potentially other parties in furtherance of reindustrialization and reuse for economic development purposes.

228

New C-H Stretching Vibrational Spectral Features in the Raman Spectra of Gaseous and Liquid Ethanol  

E-Print Network [OSTI]

New C-H Stretching Vibrational Spectral Features in the Raman Spectra of Gaseous and Liquid Ethanol Traditionally, the Raman spectrum of ethanol in the C-H vibrational stretching region between 2800 cm-1 and 3100, and the -CH3 antisymmetric stretching. In this report, new Raman spectral features were observed for ethanol

Liu, Shilin

229

Delafosse, D. 2012. "Chapter 9 -Hydrogen Effects on the Plasticity of Face Centred Cubic (fcc) Crystals." In Gaseous Hydrogen Embrittlement of Materials in Energy Technologies, edited by Richard P Gangloff and B P Somerday,  

E-Print Network [OSTI]

) Crystals." In Gaseous Hydrogen Embrittlement of Materials in Energy Technologies, edited by Richard P-11May2014 Author manuscript, published in "Gaseous hydrogen embrittlement of materials in energy) Crystals." In Gaseous Hydrogen Embrittlement of Materials in Energy Technologies, edited by Richard P

Paris-Sud XI, Université de

230

Calculation of releases of radioactive materials in gaseous and liquid effluents from pressurized water reactors (PWR-GALE Code). Revision 1  

SciTech Connect (OSTI)

This report revises the original issuance of NUREG-0017, ''Calculation of Releases of Radioactive Materials in Gaseous and Liquid Effluents from Pressurized Water Reactors (PWR-GALE-Code)'' (April 1976), to incorporate more recent operating data now available as well as the results of a number of in-plant measurement programs at operating pressurized water reactors. The PWR-GALE Code is a computerized mathematical model for calculating the releases of radioactive material in gaseous and liquid effluents (i.e., the gaseous and liquid source terms). The US Nuclear Regulatory Commission uses the PWR-GALE Code to determine conformance with the requirements of Appendix I to 10 CFR Part 50.

Chandrasekaran, T.; Lee, J.Y.; Willis, C.A.

1985-04-01T23:59:59.000Z

231

Environmental Survey preliminary report, Oak Ridge Gaseous Diffusion Plant, Oak Ridge, Tennessee  

SciTech Connect (OSTI)

This report presents the preliminary findings from the first phase of the Environmental Survey of the US Department of Energy's (DOE) Oak Ridge Gaseous Diffusion Plant (ORGDP) conducted March 14 through 25, 1988. The Survey is being conducted by an interdisciplinary team of environmental specialists, led and managed by the Office of Environment, Safety and Health's Office of Environmental Audit. Individual team components are being supplied by a private contractor. The objective of the Survey is to identify environmental risk associated with ORGDP. The Survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. This phase of the Survey involves the review of existing site environmental data, observations of the operations carried on at ORGDP, and interviews with site personnel. The Survey team developed a Sampling and Analysis Plan to assist in further assessing certain of the environmental problems identified during is on-site activities. The Sampling and Analysis Plan will be executed by Idaho National Engineering Laboratory (INEL). When completed, the results will be incorporated into the ORGDP Survey findings for in inclusion into the Environmental Survey Summary Report. 120 refs., 41 figs., 74 tabs.

Not Available

1989-02-01T23:59:59.000Z

232

Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power  

SciTech Connect (OSTI)

A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

Melius, C F; Foltz, G W

1987-01-01T23:59:59.000Z

233

Determination of operating limits for radionuclides for a proposed landfill at Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

The operating limits for radionuclides in sanitary and industrial wastes were determined for a proposed landfill at the Paducah Gaseous Diffusion Plant (PGDP), Kentucky. These limits, which may be very small but nonzero, are not mandated by law or regulation but are needed for rational operation. The approach was based on analyses of the potential contamination of groundwater at the plant boundary and the potential exposure to radioactivity of an intruder at the landfill after closure. The groundwater analysis includes (1) a source model describing the disposal of waste and the release of radionuclides from waste to the groundwater, (2) site-specific groundwater flow and contaminant transport calculations, and (3) calculations of operating limits from the dose limit and conversion factors. The intruder analysis includes pathways through ingestion of contaminated vegetables and soil, external exposure to contaminated soil, and inhalation of suspended activity from contaminated soil particles. In both analyses, a limit on annual effective dose equivalent of 4 mrem (0.04 mSv) was adopted. The intended application of the results is to refine the radiological monitoring standards employed by the PGDP Health Physics personnel to determine what constitutes radioactive wastes, with concurrence of the Commonwealth of Kentucky.

Wang, J.C.; Lee, D.W.; Ketelle, R.H.; Lee, R.R.; Kocher, D.C.

1994-05-24T23:59:59.000Z

234

Assessment and interpretation of cross- and down-hole seismograms at the Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

This paper is an assessment and interpretation of cross-and down-hole seismograms recorded at four sites in the vicinity of the Paducah Gaseous Diffusion Plant (PGDP). Arrival times of shear (S-) and compressional (P-) waves are recorded on these seismograms in milliseconds. Together with known distances between energy sources and seismometers lowered into boreholes, these arrival times are used to calculate S- and P-wave velocities in unconsolidated soils and sediments that overlie bedrock approximately 320 ft beneath PGDP. The soil columns are modified after an earlier draft by ERC Environmental and Energy Services Company (ERCE), 1990. In addition to S- and P- wave velocity estimates from this paper, the soil columns contain ERCE's lithologic and other geotechnical data for unconsolidated soils and sediments from the surface to bedrock. Soil columns for Sites 1 through 4 and a site location map are in Plates 1 through 5 of Appendix 6. The velocities in the four columns are input parameters for the SHAKE computer program, a nationally recognized computer model that simulates ground response of unconsolidated materials to earthquake generated seismic waves. The results of the SHAKE simulation are combined with predicted ground responses on rock foundations (caused by a given design earthquake) to predict ground responses of facilities with foundations placed on unconsolidated materials. 3 refs.

Staub, W.P.; Wang, J.C. (Oak Ridge National Lab., TN (United States)); Selfridge, R.J. (Automated Sciences Group, (United States))

1991-09-01T23:59:59.000Z

235

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant, January--December 1997  

SciTech Connect (OSTI)

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). A plan for the biological monitoring of the receiving streams was implemented in 1987 and consisted of ecological surveys, toxicity monitoring of effluents and receiving streams, evaluation of bioaccumulation of trace contaminants in biota, and supplemental chemical characterization of effluents. Beginning in fall 1991, the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory added data collection and report preparation to its responsibilities for the PGDP BMP. The BMP has been continued because it has proven to be extremely valuable in (1) identifying those effluents with the potential for adversely affecting instream fauna, (2) assessing the ecological health of receiving streams, and (3) guiding plans for remediation and protecting human health. The BMP for PGDP consists of three major tasks: (1) effluent toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of benthic macroinvertebrate communities and fish. With the exception of the benthic macroinvertebrate community surveys, this report focuses on activities from January to December 1997.

Kszos, L.A.; Peterson, M.J.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

1998-03-01T23:59:59.000Z

236

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant, January--December 1996  

SciTech Connect (OSTI)

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous diffusion Plant (PGDP). The PGDP BMP was conducted by the University of Kentucky Between 1987 and 1992 and by staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) from 1991 to present. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, and (3) document the effects of pollution abatement facilities on stream. The BMP for PGDP consists of three major tasks: (1) effluent toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report focuses on ESD activities occurring from January 1996 to December 1996, although activities conducted outside this time period are included as appropriate.

Kszos, L.A. [ed.; Konetsky, B.K.; Peterson, M.J.; Petrie, R.B.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

1997-06-01T23:59:59.000Z

237

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1993 to December 1994  

SciTech Connect (OSTI)

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The PGDP BMP was implemented in 1987 by the University of Kentucky. Research staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) served as reviewers and advisers to the University of Kentucky. Beginning in fall 1991, ESD added data collection and report preparation to its responsibilities for the PGDP BMP. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, (3) document the effects of pollution abatement facilities on stream biota, and (4) recommend any program improvements that would increase effluent treatability. In September 1992, a renewed Kentucky Pollutant Discharge Elimination System (KPDES) permit was issued to PGDP. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1993 to December 1994, although activities conducted outside this time period are included as appropriate.

Kszos, L.A. [ed.

1996-05-01T23:59:59.000Z

238

Operating limit study for the proposed solid waste landfill at Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

A proposed solid waste landfill at Paducah Gaseous Diffusion Plant (PGDP) would accept wastes generated during normal operations that are identified as non-radioactive. These wastes may include small amounts of radioactive material from incidental contamination during plant operations. A site-specific analysis of the new solid waste landfill is presented to determine a proposed operating limit that will allow for waste disposal operations to occur such that protection of public health and the environment from the presence of incidentally contaminated waste materials can be assured. Performance objectives for disposal were defined from existing regulatory guidance to establish reasonable dose limits for protection of public health and the environment. Waste concentration limits were determined consistent with these performance objectives for the protection of off-site individuals and inadvertent intruders who might be directly exposed to disposed wastes. Exposures of off-site individuals were estimated using a conservative, site-specific model of the groundwater transport of contamination from the wastes. Direct intrusion was analyzed using an agricultural homesteader scenario. The most limiting concentrations from direct intrusion or groundwater transport were used to establish the concentration limits for radionuclides likely to be present in PGDP wastes.

Lee, D.W.; Wang, J.C.; Kocher, D.C.

1995-06-01T23:59:59.000Z

239

Paducah Gaseous Diffusion Plant proposed pilot pump-and-treat project. Final report  

SciTech Connect (OSTI)

On March 23, 1992, R.C. Sleeman of the Department of Energy, Oak Ridge Operations Office requested that a Groundwater Corrective Actions Team be assembled to evaluate the technical merit of and the need to implement a proposed groundwater pump-and-treat demonstration project for the Northwest contaminant plume at the Paducah Gaseous Diffusion Plant. In addition to other suggestions, the Team recommended that further characterization data be obtained for the plume. In the Fall of 1993 additional, temporary well points were installed so that groundwater samples from the shallow groundwater system and the Regional Gravel Aquifer (RGA) could be obtained to provide a three-dimensional view of groundwater contamination in the region of the plume. The results indicate that pure-phase DNAPL (trichloroethylene [TCE]) probably are present in the source area of the plume and extend in depth to the base of the RGA. Because the DNAPL likely will represent a source of a dissolved phase plume for decades it is essential that source containment take place. The Team recommends that although effective hydraulic containment can be achieved, other alternatives should be considered. For example, recent advances in emplacing low permeability barrier walls to depths of 100 to 150 ft make it possible to consider encirclement of the source of the Northwest plume.

Bodenstein, G.W.; Bonczek, R.R.; Early, T.O.; Huff, D.D.; Jones, K.S.; Nickelson, M.D.; Rightmire, C.T.

1994-01-01T23:59:59.000Z

240

DYNAMICAL FRICTION IN A GASEOUS MEDIUM WITH A LARGE-SCALE MAGNETIC FIELD  

SciTech Connect (OSTI)

The dynamical friction force experienced by a massive gravitating body moving through a gaseous medium is modified by sufficiently strong large-scale magnetic fields. Using linear perturbation theory, we calculate the structure of the wake generated by, and the gravitational drag force on, a body traveling in a straight-line trajectory in a uniformly magnetized medium. The functional form of the drag force as a function of the Mach number ({identical_to} V{sub 0}/c{sub s} , where V{sub 0} is the velocity of the body and c{sub s} is the sound speed) depends on the strength of the magnetic field and on the angle between the velocity of the perturber and the direction of the magnetic field. In particular, the peak value of the drag force is not near Mach number {approx}1 for a perturber moving in a sufficiently magnetized medium. As a rule of thumb, we may state that for supersonic motion, magnetic fields act to suppress dynamical friction; for subsonic motion, they tend to enhance dynamical friction. For perturbers moving along the magnetic field lines, the drag force at some subsonic Mach numbers may be stronger than at supersonic velocities. We also mention the relevance of our findings to black hole coalescence in galactic nuclei.

Sanchez-Salcedo, F. J., E-mail: jsanchez@astroscu.unam.mx [Instituto de Astronomia, Universidad Nacional Autonoma de Mexico, Ciudad Universitaria, 04510 Mexico City (Mexico)

2012-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Postplasma particle dynamics in a Gaseous Electronics Conference RF Reference Cell  

SciTech Connect (OSTI)

Particle contamination in plasma tools used for the manufacture of very large scale integrated semiconductor devices on silicon wafers is a major cause of yield loss. Understanding the dynamics of particle movement in the postplasma regime is important to explain the process of their transport to the wafer. The movement of particle contamination in a Gaseous Electronics Conference RF Reference Cell in the postplasma regime was investigated using a novel technique. Particle clouds were observed using laser light scattering together with an image intensifier and a monochromator. This technique allowed particle clouds of low density, that could not otherwise be detected, to be seen. Video analysis of the particles showed movement of the cloud front during the first second after the plasma was extinguished. Using the particle terminal velocity to estimate particle size, we estimate diameters of 0.11 {mu}m in argon and 0.05 {mu}m in krypton. The role of the thermophoretic force on particles during the postplasma was shown to be larger than gravitational forces and to dominate particle transport for small particles under the conditions investigated. A temperature gradient of 12 {degree}C/cm was observed to move these particles away from a warm electrode as the plasma was extinguished and the particles were released from the electrostatic confinement forces generated by the plasma. {copyright} {ital 1995} {ital American} {ital Vacuum} {ital Society}

Collins, S.M. [Department of Electrical and Computer Engineering, University of Arizona, Tucson, Arizona 85721 (United States)] [Department of Electrical and Computer Engineering, University of Arizona, Tucson, Arizona 85721 (United States); Brown, D.A. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)] [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); O`Hanlon, J.F.; Carlile, R.N. [Department of Electrical and Computer Engineering, University of Arizona, Tucson, Arizona 85721 (United States)] [Department of Electrical and Computer Engineering, University of Arizona, Tucson, Arizona 85721 (United States)

1995-11-01T23:59:59.000Z

242

Activities to support the liquefied gaseous fuels spill test facility program. Final report  

SciTech Connect (OSTI)

Approximately a hundred years ago the petrochemical industry was in its infancy, while the chemical industry was already well established. Today, both of these industries, which are almost indistinguishable, are a substantial part of the makeup of the U.S. economy and the lifestyle we enjoy. It is difficult to identify a single segment of our daily lives that isn`t affected by these industries and the products or services they make available for our use. Their survival and continued function in a competitive world market are necessary to maintain our current standard of living. The occurrence of accidents in these industries has two obvious effects: (1) the loss of product during the accident and future productivity because of loss of a portion of a facility or transport medium, and (2) the potential loss of life or injury to individuals, whether workers, emergency responders, or members of the general public. A great deal of work has been conducted at the Liquefied Gaseous Fuels Spill test Facility (LGFSTF) on hazardous spills. WRI has conducted accident investigations as well as provided information on the research results via the internet and bibliographies.

Sheesley, D.; King, S.B.; Routh, T.

1997-03-01T23:59:59.000Z

243

An evaluation of gaseous sterilants under various conditions and their effect upon the heat resistance of Salmonella  

E-Print Network [OSTI]

Gaseous Sterilant Exposure Chamber Environment for Gas Exposure Tests with Formaldehyde Preparation for Heat Treatment Heat Treatment Test with Beta-propiolactone Test with Penn Gas 10 10 10 10 12 IV. RESULTS Test wi. th Formaldehyde Test... with BPL Test with Penn Gas 14 14 17 19 V DISCUSSION 23 iv Chapter VI. SUMMARY AND CONCLUSIONS LITERATURE CITED . . . , ~ ~ ~ . 26 47 LIST OF TABLES Table Page Effect of formaldehyde (conc. 0. 005 ml/L) with subsequent heat treatment (50 C...

Ali, Md. Razzak

1966-01-01T23:59:59.000Z

244

PAndAS IN THE MIST: THE STELLAR AND GASEOUS MASS WITHIN THE HALOS OF M31 AND M33  

SciTech Connect (OSTI)

Large-scale surveys of the prominent members of the Local Group have provided compelling evidence for the hierarchical formation of massive galaxies, revealing a wealth of substructure that is thought to be the debris from ancient and ongoing accretion events. In this paper, we compare two extant surveys of the M31-M33 subgroup of galaxies: the Pan-Andromeda Archaeological Survey of the stellar structure, and a combination of observations of the H I gaseous content, detected at 21 cm. Our key finding is a marked lack of spatial correlation between these two components on all scales, with only a few potential overlaps between stars and gas. The paucity of spatial correlation significantly restricts the analysis of kinematic correlations, although there does appear to be H I kinematically associated with the Giant Stellar Stream where it passes the disk of M31. These results demonstrate that different processes must significantly influence the dynamical evolution of the stellar and H I components of substructures, such as ram pressure driving gas away from a purely gravitational path. Detailed modeling of the offset between the stellar and gaseous substructures will provide a determination of the properties of the gaseous halos of M31 and M33.

Lewis, Geraint F. [Sydney Institute for Astronomy, School of Physics A28, The University of Sydney, NSW 2006 (Australia)] [Sydney Institute for Astronomy, School of Physics A28, The University of Sydney, NSW 2006 (Australia); Braun, Robert [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia)] [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia); McConnachie, Alan W. [Dominion Astrophysical Observatory, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada)] [Dominion Astrophysical Observatory, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada); Irwin, Michael J.; Chapman, Scott C. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom)] [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Ibata, Rodrigo A.; Martin, Nicolas F. [Observatoire de Strasbourg, 11, rue de l'Universite, F-67000 Strasbourg (France)] [Observatoire de Strasbourg, 11, rue de l'Universite, F-67000 Strasbourg (France); Ferguson, Annette M. N. [Institute for Astronomy, University of Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom)] [Institute for Astronomy, University of Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom); Fardal, Mark [Department of Astronomy, University of Massachusetts, Amherst, MA 01003-9305 (United States)] [Department of Astronomy, University of Massachusetts, Amherst, MA 01003-9305 (United States); Dubinski, John [Department of Astronomy and Astrophysics, 50 St. George Street, University of Toronto, ON M5S 3H4 (Canada)] [Department of Astronomy and Astrophysics, 50 St. George Street, University of Toronto, ON M5S 3H4 (Canada); Widrow, Larry [Department of Physics, Queen's University, 99 University Avenue, Kingston, ON K7L 3N6 (Canada)] [Department of Physics, Queen's University, 99 University Avenue, Kingston, ON K7L 3N6 (Canada); Mackey, A. Dougal [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia)] [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia); Babul, Arif [Department of Physics and Astronomy, University of Victoria, Victoria, BC V8W 3P6 (Canada)] [Department of Physics and Astronomy, University of Victoria, Victoria, BC V8W 3P6 (Canada); Tanvir, Nial R. [Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH (United Kingdom)] [Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH (United Kingdom); Rich, Michael, E-mail: geraint.lewis@sydney.edu.au [Division of Astronomy, University of California, 8979 Math Sciences, Los Angeles, CA 90095-1562 (United States)] [Division of Astronomy, University of California, 8979 Math Sciences, Los Angeles, CA 90095-1562 (United States)

2013-01-20T23:59:59.000Z

245

Application of the electromagnetic borehole flowmeter and evaluation of previous pumping tests at Paducah Gaseous Diffusion Plant. Final report, June 15, 1992--August 31, 1992  

SciTech Connect (OSTI)

Multi-well pumping tests have been concluded at wells MW79, MW108, and PW1 at the Paducah Gaseous Diffusion Plant (PGDP) to determine the hydraulic properties of the Regional Gravel Aquifer (RGA). Soil cores suggest that the RGA consists of a thin sandy facies (2 to 6 feet) at the top of a thicker (> 10 feet) gravelly facies. Previous analyses have not considered any permeability contrast between the two facies. To assess the accuracy of this assumption, TVA personnel conducted borehole flowmeter tests at wells MW108 and PW1. Well MW79 could not be tested. The high K sand unit is probably 10 times more permeable than comparable zone in the gravelly portion of the RGA. Previous analyses of the three multi-well aquifer tests do not use the same conceptual aquifer model. Data analysis for one pumping test assumed that leakance was significant. Data analysis for another pumping test assumed that a geologic boundary was significant. By collectively analyzing all three tests with the borehole flowmeter results, the inconsistency among the three pumping tests can be explained. Disparity exists because each pumping test had a different placement of observation wells relative to the high K zone delineating by flowmeter testing.

Young, S.C.; Julian, S.C.; Neton, M.J.

1993-01-01T23:59:59.000Z

246

Method for selectively removing fluorine and fluorine-containing contaminants from gaseous UF/sub 6/. [ClF/sub 3/  

DOE Patents [OSTI]

This invention is a method for effecting preferential removal and immobilization of certain gaseous contaminants from gaseous UF/sub 6/. The contaminants include fluorine and fluorides which are more reactive with CaCO/sub 3/ than is UF/sub 6/. The method comprises contacting the contaminant-carrying UF/sub 6/ with particulate CaCO/sub 3/ at a temperature effecting reaction of the contaminant and the CaCO/sub 3/.

Jones, R.L.; Otey, M.G.; Perkins, R.W.

1980-11-24T23:59:59.000Z

247

Uranium hexafluoride packaging tiedown systems overview at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio. Revision 1  

SciTech Connect (OSTI)

The Portsmouth Gaseous Diffusion Plant (PORTS) in Piketon, Ohio, is operated by Martin Marietta Energy Systems, Inc., through the US Department of Energy-Oak Ridge Operations Office (DOE-ORO) for the US Department of Energy-Headquarters, Office of Nuclear Energy. The PORTS conducts those operations that are necessary for the production, packaging, and shipment of uranium hexafluoride (UF{sub 6}). Uranium hexafluoride enriched uranium than 1.0 wt percent {sup 235}U shall be packaged in accordance with the US Department of Transportation (DOT) regulations of Title 49 CFR Parts 173 (Reference 1) and 178 (Reference 2), or in US Nuclear Regulatory Commission (NRC) or US Department of Energy (DOE) certified package designs. Concerns have been expressed regarding the various tiedown methods and condition of the trailers being used by some shippers/carriers for international transport of the UF{sub 6} cylinders/overpacks. Because of the concerns about international shipments, the US Department of Energy-Headquarters (DOE-HQ) Office of Nuclear Energy, through DOE-HQ Transportation Management Division, requested Westinghouse Hanford Company (Westinghouse Hanford) to review UF{sub 6} packaging tiedown and shipping practices used by PORTS, and where possible and appropriate, provide recommendations for enhancing these practices. Consequently, a team of two individuals from Westinghouse Hanford visited PORTS on March 5 and 6, 1990, for the purpose of conducting this review. The paper provides a brief discussion of the review activities and a summary of the resulting findings and recommendations. A detailed reporting of the is documented in Reference 4.

Becker, D.L.; Green, D.J.; Lindquist, M.R.

1993-07-01T23:59:59.000Z

248

Ground penetrating radar surveys over an alluvial DNAPL site, Paducah Gaseous Diffusion Plant, Kentucky  

SciTech Connect (OSTI)

Ground penetrating radar (GPR) surveys were used to map shallow sands and gravels which are DNAPL migration pathways at the Paducah Gaseous Diffusion Plant in western Kentucky. The sands and gravels occur as paleochannel deposits, at depths of 17-25 ft, embedded in Pleistocene lacustrine clays. More than 30 GPR profiles were completed over the Drop Test Area (DTA) to map the top and base of the paleochannel deposits, and to assess their lateral continuity. A bistatic radar system was used with antenna frequencies of 25 and 50 MHz. An average velocity of 0.25 ft/ns for silty and clayey materials above the paleochannel deposits was established from radar walkaway tests, profiles over culverts of known depth, and comparison of radar sections with borings. In the south portion of the DTA, strong reflections corresponded to the water table at approximately 9-10 ft, the top of the paleochannel deposits at approximately 18 ft, and to gravel horizons within these deposits. The base of these deposits was not visible on the radar sections. Depth estimates for the top of the paleochannel deposits (from 50 records) were accurate to within 2 ft across the southern portion of the DTA. Continuity of these sands and gravels could not be assessed due to interference from air-wave reflections and lateral changes in signal penetration depth. However, the sands and gravels appear to extend across the entire southern portion of the DTA, at depths as shallow as 17 ft. Ringing, air-wave reflections and diffractions from powerlines, vehicles, well casings, and metal equipment severly degraded GPR profiles in the northern portion of the DTA; depths computed from reflection times (where visible) were accurate to within 4 ft in this area. The paleochannel deposits are deeper to the north and northeast where DNAPL has apparently pooled (DNAPL was not directly imaged by the GPR, however). Existing hydrogeological models of the DTA will be revised.

Carpenter, P.J. [Northern Illinois Univ., DeKalb, IL (United States). Dept. of Geology]|[Oak Ridge National Lab., TN (United States); Doll, W.E. [Oak Ridge National Lab., TN (United States); Phillips, B.E. [Paducah Gaseous Diffusion Plant, KY (United States)

1994-09-01T23:59:59.000Z

249

Inorganic soil and groundwater chemistry near Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

SciTech Connect (OSTI)

Near-surface soils, boreholes, and sediments near the Paducah Gaseous Diffusion Plant (PGDP) were sampled in 1989-91 as were monitoring wells, TVA wells, and privately-owned wells. Most wells were sampled two or three times. The resulting chemical analyses have been published in previous reports and have been previously described (CH2M HILL 1991, 1992; Clausen et al. 1992). The two reports by CH2M HILL are controversial, however, because, the concentrations of some constituents were reported to exceed background levels or drinking water standards and because both on-site (within the perimeter fence at PGDP) and off-site pollution was reported to have occurred. The groundwater samples upon which these interpretations were based may not be representative, however. The CH2M HILL findings are discussed in the report. The purpose of this report is to characterize the inorganic chemistry of groundwater and soils near PGDP, using data from the CH2M HILL reports (1991, 1992), and to determine whether or not any contamination has occurred. The scope is limited to analysis and interpretation of data in the CH2M HILL reports because previous interpretations of these data may not be valid, because samples were collected in a relatively short period of time at several hundred locations, and because the chemical analyses are nearly complete. Recent water samples from the same wells were not considered because the characterization of inorganic chemistry for groundwater and soil requirements only one representative sample and an accurate analysis from each location.

Moore, G.K. [Tennessee Univ., Knoxville, TN (United States)

1995-03-01T23:59:59.000Z

250

Proposed sale of radioactively contaminated nickel ingots located at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) proposes to sell 8,500 radioactively contaminated nickel ingots (9.350 short tons), currently in open storage at the Paducah Gaseous Diffusion Plant (PGDP), to Scientific Ecology Group, Inc. (SEG) for decontamination and resale on the international market. SEG would take ownership of the ingots when they are loaded for transport by truck to its facility in Oak Ridge, Tennessee. SEG would receive approximately 200 short tons per month over approximately 48 months (an average of 180 ingots per month). The nickel decontamination process specified in SEG`s technical proposal is considered the best available technology and has been demonstrated in prototype at SEG. The resultant metal for resale would have contamination levels between 0.3 and 20 becquerel per gram (Bq/g). The health hazards associated with release of the decontaminated nickel are minimal. The activity concentration of the end product would be further reduced when the nickel is combined with other metals to make stainless steel. Low-level radioactive waste from the SEG decontamination process, estimated to be approximately 382 m{sup 3} (12,730 ft), would be shipped to a licensed commercial or DOE disposal facility. If the waste were packaged in 0.23 m{sup 3}-(7.5 ft{sup 3}-) capacity drums, approximately 1,500 to 1,900 drums would be transported over the 48-month contract period. Impacts from the construction of decontamination facilities and the selected site are minimal.

NONE

1995-10-01T23:59:59.000Z

251

Modifying woody plants for efficient conversion to liquid and gaseous fuels  

SciTech Connect (OSTI)

The Short Rotation Woody Crop Program (SRWCP), Department of Energy, is developing woody plant species as sources of renewable energy. Much progress has been made in identifying useful species, and testing site adaptability, stand densities, coppicing abilities, rotation lengths, and harvesting systems. Conventional plant breeding and intensive cultural practices have been used to increase above-ground biomass yields. Given these and foreseeable accomplishments, program leaders are now shifting attention to prospects for altering biomass physical and chemical characteristics, and to ways for improving the efficiency with which biomass can be converted to gaseous and liquid fuels. This report provides a review and synthesis of literature concerning the quantity and quality of such characteristics and constituents, and opportunities for manipulating them via conventional selection and breeding and/or molecular biology. Species now used by SRWCP are emphasized, with supporting information drawn from others as needed. Little information was found on silver maple (Acer saccharinum), but general comparisons (Isenberg 1981) suggest composition and behavior similar to those of the other species. Where possible, conclusions concerning means for and feasibility of manipulation are given, along with expected impacts on conversion efficiency. Information is also provided on relationships to other traits, genotype X environment interactions, and potential trade-offs or limitations. Biomass productivity per se is not addressed, except in terms of effects that may by caused by changes in constituent quality and/or quantity. Such effects are noted to the extent they are known or can be estimated. Likely impacts of changes, however effected, on suitability or other uses, e.g., pulp and paper manufacture, are notes. 311 refs., 4 figs., 9 tabs.

Dinus, R.J.; Dimmel, D.R.; Feirer, R.P.; Johnson, M.A.; Malcolm, E.W. (Institute of Paper Science and Technology, Atlanta, GA (USA))

1990-07-01T23:59:59.000Z

252

TIME-DEPENDENT PHOTOIONIZATION OF GASEOUS NEBULAE: THE PURE HYDROGEN CASE  

SciTech Connect (OSTI)

We study the problem of time-dependent photoionization of low density gaseous nebulae subjected to sudden changes in the intensity of ionizing radiation. To this end, we write a computer code that solves the full time-dependent energy balance, ionization balance, and radiation transfer equations in a self-consistent fashion for a simplified pure hydrogen case. It is shown that changes in the ionizing radiation yield ionization/thermal fronts that propagate through the cloud, but the propagation times and response times to such fronts vary widely and nonlinearly from the illuminated face of the cloud to the ionization front (IF). IF/thermal fronts are often supersonic, and in slabs initially in pressure equilibrium such fronts yield large pressure imbalances that are likely to produce important dynamical effects in the cloud. Further, we studied the case of periodic variations in the ionizing flux. It is found that the physical conditions of the plasma have complex behaviors that differ from any steady-state solution. Moreover, even the time average of ionization and temperature is different from any steady-state case. This time average is characterized by overionization and a broader IF with respect to the steady-state solution for a mean value of the radiation flux. Around the time average of physical conditions there is a large dispersion in instantaneous conditions, particularly across the IF, which increases with the period of radiation flux variations. Moreover, the variations in physical conditions are asynchronous along the slab due to the combination of nonlinear propagation times for thermal fronts/IFs and equilibration times.

Garcia, J.; Elhoussieny, E. E.; Bautista, M. A. [Department of Physics, Western Michigan University, Kalamazoo, MI 49008 (United States); Kallman, T. R., E-mail: javier@head.cfa.harvard.edu, E-mail: manuel.bautista@wmich.edu, E-mail: ehab.elhoussieny@wmich.edu, E-mail: timothy.r.kallman@nasa.gov [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2013-09-20T23:59:59.000Z

253

Short-term effects of gaseous pollutants on cause-specific mortality in Wuhan, China  

SciTech Connect (OSTI)

This study was to determine the acute mortality effects of the gaseous pollutants in Wuhan, China a city with 7.5 million permanent residents during the period from 2000 to 2004. The major sources of air pollution in the city are motor vehicles and the use of coal for domestic cooking, heating, and industrial processes. In recent years, combustion of gas has been the most common method for domestic cooking. There is a large coal-combustion smelter in the district. There are approximately 4.5 million residents in Wuhan who live in the city's core area of 201 km{sup 2}, where air pollution levels are highest, and pollution ranges are wider than the majority of the cities in the published literature. We used the generalized additive model to analyze pollution, mortality, and covariate data. We found consistent NO{sub 2} effects on mortality with the strongest effects on the same day. Every 10-{mu}g/m{sup 3} increase in NO{sub 2} daily concentration on the same day was associated with an increase in nonaccidental cardiovascular, stroke, cardiac, respiratory, and cardiopulmonary mortality. These effects were stronger among the elderly than among the young. Formal examination of exposure-response curves suggests no-threshold linear relationships between daily mortality and NO{sub 2}, where the NO{sub 2} concentrations ranged from 19.2 to 127.4 {mu}g/m{sup 3}. SO{sub 2} and O{sub 3} were not associated with daily mortality. The exposure response relationships demonstrated heterogeneity, with some curves showing nonlinear relationships for SO{sub 2} and O{sub 3}. We conclude that there is consistent evidence of acute effects of NO{sub 2} on mortality and suggest that a no-threshold linear relationship exists between NO{sub 2} and mortality. 36 refs., 7 tabs.

Zhengmin Qian; Qingci He; Hung-Mo Lin (and others) [Pennsylvania State College of Medicine, Hershey, PA (United States)

2007-07-15T23:59:59.000Z

254

Feedback from galactic stellar bulges and hot gaseous haloes of galaxies  

E-Print Network [OSTI]

We demonstrate that the feedback from stellar bulges can play an essential role in shaping the halo gas of galaxies with substantial bulge components by conducting 1-D hydrodynamical simulations. The feedback model we consider consists of two distinct phases: 1) an early starburst during the bulge formation and 2) a subsequent long-lasting mass and energy injection from stellar winds of low-mass stars and Type Ia SNe. An energetic outward blastwave is initiated by the starburst and is maintained and enhanced by the long-lasting stellar feedback. For a MW-like galactic bulge, this blastwave sweeps up the halo gas in the proto-galaxy and heats up the surrounding medium to a scale much beyond the virial radius of the halo, thus the accretion of the halo hot gas can be completely stopped. In addition, the long-lasting feedback in the later phase powers a galactic bulge wind that is reverse-shocked at a large radius in the presence of surrounding intergalactic medium and hence maintains a hot gaseous halo. As the mass and energy injection decreases with time, the feedback evolves to a subsonic and quasi-stable outflow, which is enough to prevent halo gas from cooling. The two phases of the feedback thus re-enforce each-other's impact on the gas dynamics. The simulation results demonstrate that the stellar bulge feedback may provide a plausible solution to the long-standing problems in understanding the MW type galaxies, such as the "missing stellar feedback" problem and the "over-cooling" problem. The simulations also show that the properties of the hot gas in the subsonic outflow state depend sensitively on the environment and the formation history of the bulge. This dependence and variance may explain the large dispersion in the X-ray to B-band luminosity ratio of the low $L_X/L_B$ Es.

Shikui Tang; Q. Daniel Wang; Yu Lu; H. J. Mo

2008-10-30T23:59:59.000Z

255

Modeling and analyses of postulated UF{sub 6} release accidents in gaseous diffusion plant  

SciTech Connect (OSTI)

Computer models have been developed to simulate the transient behavior of aerosols and vapors as a result of a postulated accident involving the release of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant. UF{sub 6} undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form hydrogen fluoride (HF) and radioactive uranyl fluoride (UO{sub 2}F{sub 2}). As part of a facility-wide safety evaluation, this study evaluated source terms consisting of UO{sub 2}F{sub 2} as well as HF during a postulated UF{sub 6} release accident in a process building. In the postulated accident scenario, {approximately}7900 kg (17,500 lb) of hot UF{sub 6} vapor is released over a 5 min period from the process piping into the atmosphere of a large process building. UO{sub 2}F{sub 2} mainly remains as airborne-solid particles (aerosols), and HF is in a vapor form. Some UO{sub 2}F{sub 2} aerosols are removed from the air flow due to gravitational settling. The HF and the remaining UO{sub 2}F{sub 2} are mixed with air and exhausted through the building ventilation system. The MELCOR computer code was selected for simulating aerosols and vapor transport in the process building. MELCOR model was first used to develop a single volume representation of a process building and its results were compared with those from past lumped parameter models specifically developed for studying UF{sub 6} release accidents. Preliminary results indicate that MELCOR predicted results (using a lumped formulation) are comparable with those from previously developed models.

Kim, S.H.; Taleyarkhan, R.P.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Oak Ridge, TN (United States); Dyer, R.H. [Dyer Enterprises, Oak Ridge, TN (United States)

1995-10-01T23:59:59.000Z

256

The Materials Reliability Division has established a unique, state-of-the-art high-pressure gaseous  

E-Print Network [OSTI]

will be distributed to other hydrogen materials researchers as well as to the ASME for use by pipeline designers. Fatigue Testing In FY10 fatigue testing of existing and new pipeline steels that are proposed for hydrogen hydrogen test facility dedicated to measuring the mechanical properties of metallic and composite

257

TECHNICAL EVALUATION OF TEMPORAL GROUNDWATER MONITORING VARIABILITY IN MW66 AND NEARBY WELLS, PADUCAH GASEOUS DIFFUSION PLANT  

SciTech Connect (OSTI)

Evaluation of disposal records, soil data, and spatial/temporal groundwater data from the Paducah Gaseous Diffusion Plant (PGDP) Solid Waste Management Unit (SWMU) 7 indicate that the peak contaminant concentrations measured in monitoring well (MW) 66 result from the influence of the regional PGDP NW Plume, and does not support the presence of significant vertical transport from local contaminant sources in SWMU 7. This updated evaluation supports the 2006 conceptualization which suggested the high and low concentrations in MW66 represent different flow conditions (i.e., local versus regional influences). Incorporation of the additional lines of evidence from data collected since 2006 provide the basis to link high contaminant concentrations in MW66 (peaks) to the regional 'Northwest Plume' and to the upgradient source, specifically, the C400 Building Area. The conceptual model was further refined to demonstrate that groundwater and the various contaminant plumes respond to complex site conditions in predictable ways. This type of conceptualization bounds the expected system behavior and supports development of environmental cleanup strategies, providing a basis to support decisions even if it is not feasible to completely characterize all of the 'complexities' present in the system. We recommend that the site carefully consider the potential impacts to groundwater and contaminant plume migration as they plan and implement onsite production operations, remediation efforts, and reconfiguration activities. For example, this conceptual model suggests that rerouting drainage water, constructing ponds or basin, reconfiguring cooling water systems, capping sites, decommissioning buildings, fixing (or not fixing) water leaks, and other similar actions will potentially have a 'direct' impact on the groundwater contaminant plumes. Our conclusion that the peak concentrations in MW66 are linked to the regional PGDP NW Plume does not imply that there TCE is not present in SWMU 7. The available soil and groundwater data indicate that the some of the waste disposed in this facility contacted and/or were contaminated by TCE. In our assessment, the relatively small amount of TCE associated with SWMU 7 is not contributing detectable TCE to the groundwater and does not represent a significant threat to the environment, particularly in an area where remediation and/or management of TCE in the NW plume will be required for an extended timeframe. If determined to be necessary by the PGDP team and regulators, additional TCE characterization or cleanup activities could be performed. Consistent with the limited quantity of TCE in SWMU 7, we identify a range of low cost approaches for such activities (e.g., soil gas surveys for characterization or SVE for remediation). We hope that this information is useful to the Paducah team and to their regulators and stakeholders to develop a robust environmental management path to address the groundwater and soil contamination associated with the burial ground areas.

Looney, B.; Eddy-Dilek, C.

2012-08-28T23:59:59.000Z

258

Health risk from earthquake caused releases of UF{sub 6} at the Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

The health risk to the public and workers from potential exposure to the toxic materials from earthquake caused releases of uranium hexafluoride from the Paducah gaseous Diffusion Plant are evaluated. The results of the study show that the health risk from earthquake caused releases is small, and probably less than risks associated with the transportation of hydrogen fluoride and other similar chemicals used by industry. The probability of more than 30 people experiencing health consequences (injuries) from earthquake damage is less than 4xlO{sup 4}/yr.

Brown, N.W; Lu, S.; Chen, J.C.; Roehnelt, R.; Lombardi, D.

1998-05-01T23:59:59.000Z

259

Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream  

DOE Patents [OSTI]

The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.

Berry, David A; Shekhawat, Dushyant; Smith, Mark; Haynes, Daniel

2013-07-16T23:59:59.000Z

260

A High Density Polarized Hydrogen Gas Target for Storage Rings  

E-Print Network [OSTI]

A High Density Polarized Hydrogen Gas Target for Storage Rings K. Zapfe \\Lambday , B. Braun z , H of gaseous polarized hydrogen was formed by injecting polarized H atoms (produced by Stern­Gerlach spin separation) into a storage cell consisting of a cylindrical tube open at both ends. The target was placed

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261

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

262

The Radiochemical Analysis of Gaseous Samples (RAGS) apparatus for nuclear diagnostics at the National Ignition Facility (invited)  

SciTech Connect (OSTI)

The Radiochemical Analysis of Gaseous Samples (RAGS) diagnostic apparatus was recently installed at the National Ignition Facility (NIF). Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

Shaughnessy, D. A.; Velsko, C. A.; Jedlovec, D. R.; Yeamans, C. B.; Moody, K. J.; Tereshatov, E.; Stoeffl, W.; Riddle, A. [Lawrence Livermore National Laboratory, PO Box 808, L-236, Livermore, California 94551 (United States)

2012-10-15T23:59:59.000Z

263

Hydraulic Containment of TCE Contaminated Groundwater at the DOE Portsmouth Gaseous Diffusion Plant  

SciTech Connect (OSTI)

This paper will describe the progress of a groundwater remedial action at the Portsmouth Gaseous Diffusion Plant (PORTS), a Department of Energy (DOE) facility that enriched uranium from the early 1950's until 2000. The X-749 southern boundary hydraulic containment system, combining a four-well extraction system with a previously constructed subsurface barrier wall, has been employed at PORTS. The hydraulic containment project has been implemented as part of containment and remediation of the X-749/X-120 area trichloroethylene (TCE) contaminant. The X-749/X-120 groundwater contaminant plume is located in the south central section (Quadrant I) of the PORTS facility. The plume is associated with the former X-120 Goodyear Training Facility and a landfill known as the X-749 Contaminated Materials Disposal Facility. The principal contaminants of concern are chlorinated solvents (primarily TCE) and technetium-99 (Tc-99). A subsurface barrier wall (X-749 South Barrier Wall) was completed in 1994 at the PORTS southern reservation boundary as an interim remedial measure to slow the advancement of the leading edge of the contaminated groundwater plume or to prevent the plume from migrating off DOE property. Remedial measures identified by Ohio Environmental Protection Agency (Ohio EPA) included installation of a barrier wall around the eastern and southern portions of the X-749 landfill to provide source control and installation of a phyto-remediation system to help contain groundwater flow and remove volatile organic compounds. Previous remedial measures that were implemented as elements of 'closures' on the X-749 landfill included a multimedia cap, barrier walls, and a groundwater collection system. Despite these measures, the X-749/X-120 groundwater plume has migrated beyond the southern DOE property boundary. Current TCE concentrations in off-site groundwater monitoring wells are below the preliminary remediation goal and drinking water maximum contaminant level for TCE of 5 {mu}g/kg, but continue to increase. Hydraulic containment was selected as the method for controlling the plume at the southern DOE property boundary. Recent borings and pumping tests indicate that approximately a 400-foot section of the existing subsurface barrier wall near the DOE property boundary may been improperly keyed into the Sunbury Shale bedrock which underlies the unconsolidated uppermost Gallia sand and gravel aquifer (Gallia). This gap is reported to be as much as 4 vertical feet. In addition, the X-749 groundwater plume is migrating around the western end of the X-749 South Barrier Wall. Four groundwater extraction wells were installed at the DOE property boundary to provide hydraulic control of the plume currently flowing under and around the existing subsurface barrier wall. Placement of the new extraction wells was based on groundwater modeling and data collected from pumping tests in the area. The extracted groundwater is being sent to the on-site X-622 Groundwater Treatment Facility via subsurface piping. The hydraulic containment system began operation in June 2007. The preliminary water elevations from monitoring wells in the vicinity of two of the four extraction wells demonstrate a significant decrease in groundwater potentiometric head in the southern boundary area. The current extraction rates should be adequate to contain the leading edge of the contaminant plume. Monitoring wells in the area will continue to be sampled on a quarterly basis. (authors)

Lewis, A.C.; Rieske, D.P.G.; Baird, D.R.P.E. [CDM, Piketon, OH (United States)

2008-07-01T23:59:59.000Z

264

Progress in resolving Hanford Site high-level waste tank safety issues  

SciTech Connect (OSTI)

Interim storage of alkaline, high-level radioactive waste, from two generations of spent fuel reprocessing and waste management activities, has resulted in the accumulation of 238 million liters of waste in Hanford Site single and double-shell tanks. Before the 1990`s, the stored waste was believed to be: (1) chemically unreactive under its existing storage conditions and plausible accident scenarios; and (2) chemically stable. This paradigm was proven incorrect when detailed evaluation of tank contents and behavior revealed a number of safety issues and that the waste was generating flammable and noxious gases. In 1990, the Waste Tank Safety Program was formed to focus on identifying safety issues and resolving the ferrocyanide, flammable gas, organic, high heat, noxious vapor, and criticality issues. The tanks of concern were placed on Watch Lists by safety issue. This paper summarizes recent progress toward resolving Hanford Site high-level radioactive waste tank safety issues, including modeling, and analyses, laboratory experiments, monitoring upgrades, mitigation equipment, and developing a strategy to screen tanks for safety issues.

Babad, H.; Eberlein, S.J.; Johnson, G.D.; Meacham, J.E.; Osborne, J.W.; Payne, M.A.; Turner, D.A.

1995-02-01T23:59:59.000Z

265

THE USE OF TERNARY PHASE DIAGRAMS IN THE STUDY OF HIGH TEMPERATURE CORROSION  

E-Print Network [OSTI]

THE USE OF TERNARY PHASE DIAGRAMS IN THE STUDY OF HIGH TEMPERATURE CORROSION PRODUCTS FORMED ON Fe'' and resulting morphologies that may occur during formation of corrosion scales from high temperature gaseous the previously formed reaction products was found to produce internal corrosion phases within the alloy

DuPont, John N.

266

Method and apparatus for treating gaseous effluents from waste treatment systems  

DOE Patents [OSTI]

Effluents from a waste treatment operation are incinerated and oxidized by passing the gases through an inductively coupled plasmas arc torch. The effluents are transformed into plasma within the torch. At extremely high plasma temperatures, the effluents quickly oxidize. The process results in high temperature oxidation of the gases without addition of any mass flow for introduction of energy.

Flannery, Philip A. (Ramsey, MT); Kujawa, Stephan T. (Butte, MT)

2000-01-01T23:59:59.000Z

267

An interim report to the manager of the Paducah Gaseous Diffusion Plant from the Paducah Environmental Advisory Committee  

SciTech Connect (OSTI)

The Paducah Environmental Advisory Committee was formed as: (1) an outgrowth of other Environmental Advisory Committees already in existence at Oak Ridge and other Martin Marietta Energy Systems plants; (2) a result of public concern following significant nuclear incidents at Bhopal and Chernobyl; (3) a result of the new direction and commitment of the management of the Paducah Gaseous Diffusion Plant following contract acquisition by Martin Marietta Energy Systems; and (4) a means of reducing and/or preventing local and/or public concern regarding the activities of and potential risks created by PGDP. This report discusses the following issues and concerns of the Committee arrived at through a series of meetings: (1) groundwater monitoring; (2) long-range tails storage; C-404, scrap yrads, and PCB and TCE cleanup; nuclear criticality plan and alarm systems; documentation of historical data regarding hazardous waste burial grounds; dosimeter badges; and asbestos handling and removal.

Jackson, G.D.

1987-10-01T23:59:59.000Z

268

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Pennsylvania  

E-Print Network [OSTI]

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 Ammonia Emissions from Broiler Houses in Pennsylvania During Cold of reducing ammonia (NH3) emissions are under study. Ammonia emissions during cold weather conditions from

Kentucky, University of

269

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter  

E-Print Network [OSTI]

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter Kenneth D a comprehensive database of ammonia emission rates (ER) from US poultry facilities. The influence of common

Kentucky, University of

270

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA  

E-Print Network [OSTI]

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA Y. Liang1 , H. Xin2 , A. Casey10 ABSTRACT An ongoing project of monitoring ammonia (NH3) emissions from U.S. layer houses

Kentucky, University of

271

Dispersion of UO{sub 2}F{sub 2} aerosol and HF vapor in the operating floor during winter ventilation at the Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

The gaseous diffusion process is currently employed at two plants in the US: the Paducah Gaseous Diffusion Plant and the Portsmouth Gaseous Diffusion Plant. As part of a facility-wide safety evaluation, a postulated design basis accident involving large line-rupture induced releases of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant (GDP) is evaluated. When UF{sub 6} is released into the atmosphere, it undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form vaporized hydrogen fluoride (HF) and aerosolized uranyl fluoride (UO{sub 2}F{sub 2}). These reactants disperse in the process building and transport through the building ventilation system. The ventilation system draws outside air into the process building, distributes it evenly throughout the building, and discharges it to the atmosphere at an elevated temperature. Since air is recirculated from the cell floor area to the operating floor, issues concerning in-building worker safety and evacuation need to be addressed. Therefore, the objective of this study is to evaluate the transport of HF vapor and UO{sub 2}F{sub 2} aerosols throughout the operating floor area following B-line break accident in the cell floor area.

Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Knoxville, TN (United States)

1996-12-30T23:59:59.000Z

272

Type B Accident Investigation of the August 22, 2000, Injury Resulting From Violent Exothermic Chemical Reaction at the Portsmouth Gaseous Diffusion Plant, X-701B Site  

Broader source: Energy.gov [DOE]

On August 22, 2000, an accident occurred at the U. S. Department of Energy (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) located in Piketon, Ohio. An employee of the IT Corporation (IT) working on an Environmental Management (EM) Technology Deployment Project received serious burns from a violent chemical reaction.

273

Ab initio modeling of complex aqueous and gaseous systems containing nitrogen  

E-Print Network [OSTI]

Nitrogen chemistry is ubiquitous in everyday life, from biological processes at ambient conditions to atmospheric chemistry at low pressures and temperatures to high-temperature combustion. Understanding the chemical ...

Ashcraft, Robert Wilson

2008-01-01T23:59:59.000Z

274

High-Flux Microchannel Solar Receiver  

Broader source: Energy.gov [DOE]

This fact sheet describes a high-flux, microchannel solar receiver project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by Oregon State University, is working to demonstrate a microchannel-based solar receiver capable of absorbing high solar flux, while using a variety of liquid and gaseous working fluids. High-flux microchannel receivers have the potential to dramatically reduce the size and cost of a solar receiver by minimizing re-radiation and convective losses.

275

Studies on discharges in Micro Pattern Gaseous Detectors, towards a spark resistant THGEM detector  

E-Print Network [OSTI]

The problem afflicting any of MPGDs is the phenomenon of discharging which might be destructive in some highly energetic cases, at least being responsible of a slow aging of the detector. So far one solution has been cascading several gain elements (GEM, THGEM detectors) reducing the gain of each one; this method, spreading the charges along their path, reduce effectively the likelihood of a discharge but introduce more material due to the multiple stages of amplification. Our goal is developing a single stage THGEM detector which could withstand discharges, not reducing the gain, hence being still able to amplify low level ionizing particles while implementing some methodologies to reduce the damages due to discharge induced by high rate of particles flux and/or highly ionizing particles. This report describes the test bench set up to study discharges between simple structures, which are actually models of the bigger detector. The idea behind this approach is to reduce the complexity of the whole phenomen...

Cantini, Cosimo; De Oliveira, Rui

276

Studying the Internal Ballistics of a Combustion Driven Potato Cannon using High-speed Video  

E-Print Network [OSTI]

A potato cannon was designed to accommodate several different experimental propellants and have a transparent barrel so the movement of the projectile could be recorded on high-speed video (at 2000 frames per second). Both combustion chamber and barrel were made of polyvinyl chloride (PVC). Five experimental propellants were tested: propane (C3H8), acetylene (C2H2), ethanol (C2H6O), methanol (CH4O), and butane (C4H10). The amount of each experimental propellant was calculated to approximate a stoichometric mixture and considering the Upper Flammability Limit (UFL) and the Lower Flammability Limit (LFL), which in turn were affected by the volume of the combustion chamber. Cylindrical projectiles were cut from raw potatoes so that there was an airtight fit, and each weighed 50 (+/- 0.5) grams. For each trial, position as a function of time was determined via frame by frame analysis. Five trials were taken for each experimental propellant and the results analyzed to compute velocity and acceleration as functions...

Courtney, E D S

2013-01-01T23:59:59.000Z

277

Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas  

DOE Patents [OSTI]

The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

2014-10-07T23:59:59.000Z

278

FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS  

Office of Scientific and Technical Information (OSTI)

1939, pp. International Acetylene Association. Acetylene Transmission for Chemical Synthesis. Internat. Acetylene ASSOC., New York (no date), 40 pp. Jackson, J. L., and R....

279

Material Safety Data Sheet HMIS FLAMMABILITY  

E-Print Network [OSTI]

.0 Extinguishing Media - Use water fog, foam, dry chemical or CO2. Use water spray to cool fire-exposed containers spray. Prevent spill from entering drains, sewers, streams or other bodies of water. If run-off occurs shield, bunker coats, gloves and rubber boots), including a positive pressure NIOSH approved self

Rollins, Andrew M.

280

Binary mixture flammability characteristics for hazard assessment  

E-Print Network [OSTI]

calculations and UNIFAC, a theoretical model that does not require experimental binary interaction parameters, are employed in the mixture flash point predictions, which are validated with experimental data. MFPB is successfully predicted using the UNIFAC model...

Vidal Vazquez, Migvia del C.

2005-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

FLAMMABILITY CHARACTERISTICS OF COMBUSTIBLE GASES AND VAPORS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicy andExsolutionFES Committees of9, 2011COMMERCIALBulletin 627

282

A Note on the Viability of Gaseous Ionization in Active Galaxies by Fast Shocks  

E-Print Network [OSTI]

Observational evidence suggest that shocks may affect the spatial and velocity distributions of gas in the NLR/ENLR of some active galaxies. It thus seemed plausible that shocks may also energize the NLR. The observed emission line ratios strongly favor photoionization as the heating source, but it is not clear whether the ionizing radiation is generated in the NLR by "photoionizing shocks" or whether it originates at the central continuum source. Here I point out that shocks are highly inefficient in producing line emission. Shocks in the NLR can convert at most 10^{-6} of the rest mass to ionizing radiation, compared with a maximum conversion efficiency of ~0.1 for the central continuum source. The required mass flow rate through shocks in the NLR is thus a few orders of magnitude higher than the mass accretion rate required to power the NLR by the central continuum source. Since gravity appears to dominate the NLR cloud dynamics, shocks must lead to an inflow, and the implied high inflow rates can be ruled out in most active galaxies. NLR dynamics driven by a thermal wind or by some jet configurations may produce the mass flux through shocks required for photoionizing shocks to be viable, but the mass flux inward from the NLR must be kept ~100-1000 times smaller. Photoionizing shocks are a viable mechanism in very low luminosity active galaxies if they are highly sub-Eddington (<~10^{-4}) and if they convert mass to radiation with a very low efficiency (<~10^{-4}).

Ari Laor

1998-02-12T23:59:59.000Z

283

Prediction of external corrosion for steel cylinders at the Paducah Gaseous Diffusion Plant: Application of an empirical method  

SciTech Connect (OSTI)

During the summer of 1995, ultrasonic wall thickness data were collected for 100 steel cylinders containing depleted uranium (DU) hexafluoride located at Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The cylinders were selected for measurement to assess the condition of the more vulnerable portion of the cylinder inventory at PGDP. The purpose of this report is to apply the method used in Lyon to estimate the effects of corrosion for larger unsampled populations as a function of time. The scope of this report is limited and is not intended to represent the final analyses of available data. Future efforts will include continuing analyses of available data to investigate defensible deviations from the conservative assumptions made to date. For each cylinder population considered, two basic types of analyses were conducted: (1) estimates were made of the number of cylinders as a function of time that will have a minimum wall thickness of either 0 mils (1 mil = 0.00 1 in.) or 250 mils and (2) the current minimum wall thickness distributions across cylinders were estimated for each cylinder population considered. Additional analyses were also performed investigating comparisons of the results for F and G yards with the results presented in Lyon (1995).

Lyon, B.F.

1996-02-01T23:59:59.000Z

284

Intermittently-fed high-pressure gasifier process  

DOE Patents [OSTI]

An improved gasifier adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications.

Bailey, John M. (Dunlap, IL); Zadoks, Abraham L. (Peoria, IL)

1993-11-30T23:59:59.000Z

285

Intermittently-fed high-pressure gasifier process  

DOE Patents [OSTI]

An improved gasifier is described which is adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications. 3 figures.

Bailey, J.M.; Zadoks, A.L.

1993-11-30T23:59:59.000Z

286

Laser utilizing a gaseous lasing medium and method for operating the same  

DOE Patents [OSTI]

The invention relates to an improvement in gas lasers and a method of operating the same. In one aspect, the invention is an improved method for operating a high-power gas laser. The improvement comprises introducing the gas lasing medium tangentially to the laser tube at a pressure establishing a forced vortex in the tube. The vortex defines an axially extending core region characterized by a low pressure and temperature relative to the gas inlet and the exterior of the vortex. An electrical discharge is established in the core region to initiate lasing of the gas. The gas discharge from the tube is passed through a diffuser. As in conventional gas lasers, firing results in a very abrupt increase in gas temperature and in severe disruption of the gas. However, the gas vortex almost immediately restores the gas to its pre-firing condition. That is, almost all of the waste heat is transferred radially to the laser wall, and the original gas-flow pattern is restored. As a result, the power output of the laser is increased significantly, and the laser firing repetition rate is markedly increased.

Zerr, Bruce A. (Harriman, TN)

1986-01-01T23:59:59.000Z

287

Liquid and Gaseous Waste Operations Project Annual Operating Report CY 1999  

SciTech Connect (OSTI)

A total of 5.77 x 10 7 gallons (gal) of liquid waste was decontaminated by the Process Waste Treatment Complex (PWTC) - Building 3544 ion exchange system during calendar year (CY) 1999. This averaged to 110 gpm throughout the year. An additional 3.94 x 10 6 gal of liquid waste (average of 8 gpm throughout the year) was decontaminated using the zeolite treatment system due to periods of high Cesium levels in the influent wastewater. A total of 6.17 x 10 7 gal of liquid waste (average of 118 gpm throughout the year) was decontaminated at Building 3544 during the year. During the year, the regeneration of the ion exchange resins resulted in the generation of 8.00 x 10 3 gal of Liquid Low-Level Waste (LLLW) concentrate and 9.00 x 10 2 gal of LLLW supernate. See Table 1 for a monthly summary of activities at Building 3544. Figure 1 shows a diagram of the Process Waste Collection and Transfer System and Figure 2 shows a diagram of the Building 3544 treatment process. Figures 3, 4 5, and 6 s how a comparison of operations at Building 3544 in 1997 with previous years. Figure 7 shows a comparison of annual rainfall at Oak Ridge National Laboratory (ORNL) since 1995.

Maddox, J.J.; Scott, C.B.

2000-03-01T23:59:59.000Z

288

Method and apparatus for fast laser pulse detection using gaseous plasmas  

DOE Patents [OSTI]

The method and device of the instant invention is a detector of pulsed laser radiation which utilizes the electromotive force generated by the plasma formed when such radiation is focused onto a surface (1). Measurements are made with a 10.6 .mu.m CO.sub.2 laser capable of producing peak intensities of 10.sup.13 W/cm.sup.2 when directed through a converging lens (2). Evacuated detector response to such laser intensity is 1 kV signal peak amplitude and subnanosecond risetimes into a 50.OMEGA. load (3). Detector performance is found to be greatly altered with the introduction of a background gas (4). For example, with one atmosphere of air, the detector produces prompt signals of the order of 1 V with subnanosecond response for pulse trains lasting 100 ns. With argon, krypton, or zenon at pressures of the order of 10 torr, the detector generates "trigger pulses" of about 250 V amplitude and 0.2 ns risetimes. Such detectors are quite robust when irradiated with high intensity laser radiation and are useful for qualitative laser beam monitoring.

McLellan, Edward J. (Los Alamos, NM); Webb, John A. (Albuquerque, NM)

1984-01-01T23:59:59.000Z

289

Method and apparatus for fast laser-pulse detection using gaseous plasmas  

DOE Patents [OSTI]

The method and device of the instant invention is a detector of pulsed laser radiation which utilizes the electromotive force generated by the plasma formed when such radiation is focused onto a surface. Measurements are made with a 10.6 ..mu..m CO/sub 2/ laser capable of producing peak intensities of 10/sup 13/ W/cm/sup 2/ when directed through a converging lens. Evacuated detector response to such laser intensity if 1 kV signal peak amplitude and subnanosecond risetimes into a 50 ..cap omega.. load. Detector performance is found to be greatly altered with the introduction of a background gas. For example, with one atmosphere of air, the detector produces prompt signals of the order of 1 V with subnanosecond response for pulse trains lasting 100 ns. With argon, krypton, or zenon at pressures of the order of 10 torr, the detector generates trigger pulses of about 250 V amplitude and 0.2 ns risetimes. Such detectors are quite robust when irradiated with high intensity laser radiation and are useful for qualitative laser beam monitoring.

McLellan, E.J.; Webb, J.A.

1981-06-18T23:59:59.000Z

290

Prevention of Porosity Formation and Other Effects of Gaseous Elements in Iron Castings  

SciTech Connect (OSTI)

Iron foundries have observed porosity primarily as interdendritic porosity in large freezing range alloys such as Ni-Hard I and hypoeutectic high Cr alloys or pinholes and fissure defects in gray and ductile irons. For most iron foundries, porosity problems occur sporadically, but even occasional outbreaks can be costly since even a very small amount of porosity can significantly reduce the mechanical properties of the castings. As a result when porosity is detected, the castings are scrapped and remelted, or when the porosity is undetected, defective parts are shipped to the consumer. Neither case is desirable. This project was designed to examine various factors contributing to the porosity formation in iron castings. Factors such as solubility of gases in liquid and solid iron alloys, surface tension of liquid iron alloys, and permeability of dendritic structures were investigated in terms of their effect on the porosity formation. A method was developed to predict how much nitrogen the molten alloy picks up from air after a given amount of holding time for a given melting practice. It was shown that small batches of iron melts in an induction furnace can end up with very high concentration of nitrogen (near solubility limit). Surface tension of liquid iron alloys was measured as a function of temperature. Effect of minor additions of S, Ti, and Al on the surface tension of liquid iron alloys was investigated. Up to 18% change in surface tension was detected by minor element additions. This translates to the same amount of change in gas pressure required in a bubble of a given size to keep the bubble stable. A new method was developed to measure the permeability of dendritic structures in situ. The innovative aspect of these experiments, with respect to previous interdendritic permeability measurements, was the fact that the dendritic structure was allowed to form in situ and was not cooled and re-heated for permeability tests. A permeability model was developed and tested using the results of the permeability experiments. The permeability model for flow parallel to the columnar dendrites predicted the experimental permeability results closely when the liquid volume fraction data from equilibrium calculations were used. The permeability gradient model was constructed in order to test the impact of interdendritic channel constriction on the flow of liquid through the mushy zone of a casting. The model examines two different regimes: (i) Dendritic solidification regime where the permeability is dominated by changes in liquid volume fraction and dendrite arm spacing, and (ii) Eutectic solidification regime where the permeability is dominated by changes in viscosity of eutectic mixture. It is assumed that the eutectic mixture behaves like a slurry whose viscosity increases with increasing solid fraction. It is envisioned that this model can be developed into a tool that can be very useful for metal casters.

Albany Research Center

2005-04-01T23:59:59.000Z

291

Efficient photocatalytic degradation of gaseous formaldehyde by the TiO{sub 2}/tourmaline composites  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: The TiO{sub 2}/tourmaline composites were prepared by a solgel method. The composites exhibited excellent photocatalytic activity and good stability. The physicochemical property of tourmaline may be favor for the degradation of HCHO. The mixed-phase of anatase and rutile TiO{sub 2} may be favor for the degradation of HCHO. - Abstract: The TiO{sub 2} supported tourmaline composites were prepared by a solgel method and used as a photocatalyst for the degradation of formaldehyde (HCHO). The composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), N{sub 2} adsorptiondesorption, Fourier transform infrared (FT-IR) spectroscopy and UVvis diffuse reflectance spectroscopy (UVvis DRS). The results indicate that the mixed-phase of anatase and rutile exists in the TiO{sub 2}/tourmaline composites. The specific surface area of the TiO{sub 2}/tourmaline composites is much higher than that of the pure TiO{sub 2}. The TiO{sub 2}/tourmaline composites exhibited excellent photocatalytic activity for the degradation of HCHO, which was 6 times higher than that of the pure TiO{sub 2}. Moreover, the excellent photocatalytic activity of the composites was fully maintained after five photocatalytic cycles, which may be attributed to the physicochemical property of tourmaline and the mixed-phase of anatase and rutile in the TiO{sub 2}/tourmaline composites.

Zhang, Gaoke, E-mail: gkzhang@whut.edu.cn; Qin, Xi

2013-10-15T23:59:59.000Z

292

Apparatus and method for removing particulate deposits from high temperature filters  

DOE Patents [OSTI]

A combustion of a fuel-air mixture is used to provide a high-temperature and high-pressure pulse of gaseous combustion products for the back-flush cleaning of ceramic filter elements contained in a barrier filter system and utilized to separate particulates from particulate-laden process gases at high temperature and high pressure. The volume of gaseous combustion products provided by the combustion of the fuel-air mixture is preferably divided into a plurality of streams each passing through a sonic orifice and conveyed to the open end of each filter element as a high pressure pulse which passes through the filter elements and dislodges dust cake supported on a surface of the filter element.

Nakaishi, Curtis V. (Morgantown, WV); Holcombe, Norman T. (McMurray, PA); Micheli, Paul L. (Morgantown, WV)

1992-01-01T23:59:59.000Z

293

Lessons-Learned from D and D Activities at the Five Gaseous Diffusion Buildings (K-25, K- 27, K-29, K-31 and K-33) East Tennessee Technology Park, Oak Ridge, TN - 13574  

SciTech Connect (OSTI)

The East Tennessee Technology Park (ETTP) is the site of five former gaseous diffusion plant (GDP) process buildings that were used to enrich uranium from 1945 to 1985. The process equipment in the original two buildings (K-25 and K-27) was used for the production of highly enriched uranium (HEU), while that in the three later buildings (K-29, K-31 and K-33) produced low enriched uranium (LEU). Equipment was contaminated primarily with uranium and to a lesser extent technetium (Tc). Decommissioning of the GDP process buildings has presented several unique challenges and produced many lessons-learned. Among these is the importance of good, up-front characterization in developing the best demolition approach. Also, chemical cleaning of process gas equipment and piping (PGE) prior to shutdown should be considered to minimize the amount of hold-up material that must be removed by demolition crews. Another lesson learned is to maintain shutdown buildings in a dry state to minimize structural degradation which can significantly complicate characterization, deactivation and demolition efforts. Perhaps the most important lesson learned is that decommissioning GDP process buildings is first and foremost a waste logistics challenge. Innovative solutions are required to effectively manage the sheer volume of waste generated from decontamination and demolition (D and D) of these enormous facilities. Finally, close coordination with Security is mandatory to effectively manage Special Nuclear Material (SNM) and classified equipment issues. (authors)

Kopotic, James D. [United States Department of Energy, Oak Ridge Office, P.O. Box 2001, Oak Ridge, TN 37831 (United States)] [United States Department of Energy, Oak Ridge Office, P.O. Box 2001, Oak Ridge, TN 37831 (United States); Ferri, Mark S.; Buttram, Claude [URS - CH2M Oak Ridge LLC, East Tennessee Technology Park, P. O. Box 4699, Oak Ridge, TN 37831 (United States)] [URS - CH2M Oak Ridge LLC, East Tennessee Technology Park, P. O. Box 4699, Oak Ridge, TN 37831 (United States)

2013-07-01T23:59:59.000Z

294

Gaseous Diffusion Plant  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

U.S. population. The study found significantly lower death rates from all causes and cancer in general when compared to the overall U.S. population. However, slight increases...

295

Improved gaseous leak detector  

DOE Patents [OSTI]

In a short path length mass-spectrometer type of helium leak detector wherein the helium trace gas is ionized, accelerated and deflected onto a particle counter, an arrangement is provided for converting the detector to neon leak detection. The magnetic field of the deflection system is lowered so as to bring the nonlinear fringe area of the magnetic field across the ion path, thereby increasing the amount of deflection of the heavier neon ions.

Juravic, F.E. Jr.

1983-10-06T23:59:59.000Z

296

Gaseous leak detector  

DOE Patents [OSTI]

In a short path length mass-spectrometer type of helium leak detector wherein the helium trace gas is ionized, accelerated and deflected onto a particle counter, an arrangement is provided for converting the detector to neon leak detection. The magnetic field of the deflection system is lowered so as to bring the non linear fringe area of the magnetic field across the ion path, thereby increasing the amount of deflection of the heavier neon ions.

Juravic, Jr., Frank E. (Aurora, IL)

1988-01-01T23:59:59.000Z

297

NGPL Production, Gaseous Equivalent  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19343 369 384FuelYear125 137 Monthly Annual

298

NGPL Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year2per ThousandWellhead+WellheadMr.NEMSNGPL

299

Fiber Bulk Gaseous Carriers  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat PumpRecordFederal Registry Comments May 4-9, 2007.FedwireAmorphous States

300

Source term evaluation for postulated UF{sub 6} release accidents in gaseous diffusion plants -- Summer ventilation mode (non-seismic cases)  

SciTech Connect (OSTI)

Computer models have been developed to simulate the transient behavior of aerosols and vapors as a result of a postulated accident involving the release of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant. For the current study, gaseous UF{sub 6} is assumed to get released in the cell housing atmosphere through B-line break at 58.97 kg/s for 10 min and 30 min duration at the Paducah and Portsmouth Gaseous Diffusion Plants. The released UF{sub 6} undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form hydrogen fluoride (HF) and radioactive uranyl fluoride (UO{sub 2}F{sub 2}) while it disperses throughout the process building. As part of a facility-wide safety evaluation, this study evaluated source terms consisting of UO{sub 2}F{sub 2} as well as HF during a postulated UF{sub 6} release accident in a process building. UO{sub 2}F{sub 2} mainly remains as airborne-solid particles (aerosols), and HF is in a vapor form. Some UO{sub 2}F{sub 2} aerosols are removed from the air flow due to gravitational settling. The HF and the remaining UO{sub 2}F{sub 2} are mixed with air and exhausted through the building ventilation system. The MELCOR computer code was selected for simulating aerosols and vapor transport in the process building. To characterize leakage flow through the cell housing wall, 3-D CFD tool (CFDS-FLOW3D) was used. About 57% of UO{sub 2}F{sub 2} was predicted to be released into the environment. Since HF was treated as vapor, close to 100% was estimated to get released into the environment.

Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Wendel, M.W.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Knoxville, TN (United States); Dyer, R.H. [Dyer Enterprises, Harriman, TN (United States)

1996-12-30T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Environmental site description for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant at the Portsmouth Gaseous Diffusion Plant site  

SciTech Connect (OSTI)

Uranium enrichment in the United States has utilized a diffusion process to preferentially enrich the U-235 isotope in the uranium product. In the 1970s, the US Department of Energy (DOE) began investigating more efficient and cost-effective enrichment technologies. In January 1990, the Secretary of Energy approved a plan for the demonstration and deployment of the Uranium Atomic Vapor Laser isotope Separation (U-AVLIS) technology with the near-term goal to provide the necessary information to make a deployment decision by November 1992. Initial facility operation is anticipated for 1999. A programmatic document for use in screening DOE sites to locate a U-AVLIS production plant was developed and implemented in two parts. The first part consisted of a series of screening analyses, based on exclusionary and other criteria, that identified a reasonable number of candidate sites. The final evaluation, which included sensitivity studies, identified the Oak Ridge Gaseous Diffusion Plant (ORGDP) site, the Paducah Gaseous Diffusion Plant (PGDP) site, and the Portsmouth Gaseous Diffusion Plant (PORTS) site as having significant advantages over the other sites considered. This environmental site description (ESD) provides a detailed description of the PORTS site and vicinity suitable for use in an environmental impact statement (EIS). This report is based on existing literature, data collected at the site, and information collected by Argonne National Laboratory (ANL) staff during site visits. The organization of the ESD is as follows. Topics addressed in Sec. 2 include a general site description and the disciplines of geology, water resources, biotic resources, air resources, noise, cultural resources, land use. Socioeconomics, and waste management. Identification of any additional data that would be required for an EIS is presented in Sec. 3.

Marmer, G.J.; Dunn, C.P.; Filley, T.H.; Moeller, K.L.; Pfingston, J.M.; Policastro, A.J.; Cleland, J.H.

1991-09-01T23:59:59.000Z

302

System and process for capture of H.sub.2S from gaseous process streams and process for regeneration of the capture agent  

DOE Patents [OSTI]

A system and process are disclosed for selective removal and recovery of H.sub.2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H.sub.2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H.sub.2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.

Heldenbrant, David J; Koech, Phillip K; Rainbolt, James E; Bearden, Mark D; Zheng, Feng

2014-02-18T23:59:59.000Z

303

Method for Synthesizing Extremeley High Temperature Melting Materials  

DOE Patents [OSTI]

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise and Glorieux, Benoit

2005-11-22T23:59:59.000Z

304

Method For Synthesizing Extremely High-Temperature Melting Materials  

DOE Patents [OSTI]

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

2005-11-22T23:59:59.000Z

305

Method for synthesizing extremely high-temperature melting materials  

SciTech Connect (OSTI)

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

2007-11-06T23:59:59.000Z

306

COMBINED GEOPHYSICAL INVESTIGATION TECHNIQUES TO IDENTIFY BURIED WASTE IN AN UNCONTROLLED LANDFILL AT THE PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY  

SciTech Connect (OSTI)

The primary objective of the investigation was to confirm the presence and determine the location of a cache of 30 to 60 buried 55-gallon drums that were allegedly dumped along the course of the pre-existing, northsouth diversion ditch (NSDD) adjacent to permitted landfills at the Paducah Gaseous Diffusion Plant, Kentucky. The ditch had been rerouted and was being filled and re-graded at the time of the alleged dumping. Historic information and interviews with individuals associated with alleged dumping activities indicated that the drums were dumped prior to the addition of other fill materials. In addition, materials alleged to have been dumped in the ditch, such as buried roofing materials, roof flashing, metal pins, tar substances, fly ash, and concrete rubble complicated data interpretation. Some clean fill materials have been placed over the site and graded. This is an environment that is extremely complicated in terms of past waste dumping activities, construction practices and miscellaneous landfill operations. The combination of site knowledge gained from interviews and research of existing site maps, variable frequency EM data, classical total magnetic field data and optimized GPR lead to success where a simpler less focused approach by other investigators using EM-31 and EM-61 electromagnetic methods and unfocused ground penetrating radar (GPR)did not produce results and defined no real anomalies. A variable frequency electromagnetic conductivity unit was used to collect the EM data at 3,030 Hz, 5,070 Hz, 8,430 Hz, and 14,010 Hz. Both in-phase and quadrature components were recorded at each station point. These results provided depth estimates for targets and some information on the subsurface conditions. A standard magnetometer was used to conduct the magnetic survey that showed the locations and extent of buried metal, the approximate volume of ferrous metal present within a particular area, and allowed estimation of approximate target depths. The GPR survey used a 200 megahertz (MHz) antenna to provide the maximum depth penetration and subsurface detail yielding usable signals to a depth of about 6 to 10 feet in this environment and allowed discrimination of objects that were deeper, particularly useful in the southern area of the site where shallow depth metallic debris (primarily roof flashing) complicated interpretation of the EM and magnetic data. Several geophysical anomalies were defined on the contour plots that indicated the presence of buried metal. During the first phase of the project, nine anomalies or anomalous areas were detected. The sizes, shapes, and magnitudes of the anomalies varied considerably, but given the anticipated size of the primary target of the investigation, only the most prominent anomalies were considered as potential caches of 30 to 60 buried drums. After completion of a second phase investigation, only two of the anomalies were of sufficient magnitude, not identifiable with existing known metallic objects such as monitoring wells, and in positions that corresponded to the location of alleged dumping activities and were recommended for further, intrusive investigation. Other important findings, based on the variable frequency EM method and its combination with total field magnetic and GPR data, included the confirmation of the position of the old NSDD, the ability to differentiate between ferrous and non-ferrous anomalies, and the detection of what may be plumes emanating from the landfill cell.

Miller, Peter T.; Starmer, R. John

2003-02-27T23:59:59.000Z

307

Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors  

SciTech Connect (OSTI)

Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovation??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

Dr. Brian Dixon

2008-12-30T23:59:59.000Z

308

Proceedings of waste stream minimization and utilization innovative concepts: An experimental technology exchange. Volume 2, Industrial liquid waste processing, industrial gaseous waste processing  

SciTech Connect (OSTI)

This two-volume proceedings summarize the results of fifteen innovations that were funded through the US Department of Energy`s Innovative Concept Program. The fifteen innovations were presented at the sixth Innovative Concepts Fair, held in Austin, Texas, on April 22--23, 1993. The concepts in this year`s fair address innovations that can substantially reduce or use waste streams. Each paper describes the need for the proposed concept, the concept being proposed, and the concept`s economics and market potential, key experimental results, and future development needs. The papers are divided into two volumes: Volume 1 addresses innovations for industrial solid waste processing and municipal waste reduction/recycling, and Volume 2 addresses industrial liquid waste processing and industrial gaseous waste processing. Individual reports are indexed separately.

Lee, V.E. [ed.; Watts, R.L.

1993-04-01T23:59:59.000Z

309

Probe into Gaseous Pollution and Assessment of Air Quality Benefit under Sector Dependent Emission Control Strategies over Megacities in Yangtze River Delta, China  

SciTech Connect (OSTI)

On February 29th 2012, China published its new National Ambient Air Quality Standard (CH-NAAQS) aiming at revising the standards and measurements for both gaseous pollutants including ozone (O3), nitrogen dioxide (NO2), and sulfur dioxide (SO2), and also particle pollutants including PM10 and PM2.5. In order to understand the air pollution status regarding this new standard, the integrated MM5/CMAQ modeling system was applied over Yangtze River Delta (YRD) within this study to examine the criteria gaseous pollutants listed in the new CH-NAAQS. Sensitivity simulations were also conducted to assess the responses of gaseous pollutants under 8 different sector-dependent emission reduction scenarios in order to evaluate the potential control strategies. 2006 was selected as the simulation year in order to review the air quality condition at the beginning of Chinas 11th Five-Year-Plan (FYP, from 2006 to 2010), and also compared with air quality status in 2010 as the end of 11th FYP to probe into the effectiveness of the national emission control efforts. Base case simulation showed distinct seasonal variation for gaseous pollutants: SO2, and NO2 were found to have higher surface concentrations in winter while O3 was found to have higher concentrations in spring and summer than other seasons. According to the analyses focused on 3 megacities within YRD, Shanghai, Nanjing, and Hangzhou, we found different air quality conditions among the cities: NO2 was the primary pollutant that having the largest number of days exceeding the CH-NAAQS daily standard (80 ?g/m3) in Shanghai (59 days) and Nanjing (27 days); SO2 was the primary pollutant with maximum number of days exceeding daily air quality standard (150 ?g/m3) in Hangzhou (28 days), while O3 exceeding the daily maximum 8-hour standard (160 ?g/m3) for relatively fewer days in all the three cities (9 days in Shanghai, 14 days in Nanjing, and 11 days in Hangzhou). Simulation results from predefined potential applicable emission control scenarios suggested significant air quality improvements from emission reduction: 90% of SO2 emission removed from power plant in YRD would be able to reduce more than 85% of SO2 pollution, 85% NOx emission reduction from power plant would reduce more than 60% of NO2 pollution, in terms of reducing the number of days exceeding daily air quality standard. NOx emission reduction from transportation and industry were also found to effectively reduce NO2 pollution but less efficient than emission control from power plants. We also found that multi-pollutants emission control including both NOx and VOC would be a better strategy than independent NOx control over YRD which is Chinas 12th Five-Year-Plan (from 2011 to 2015), because O3 pollution would be increased as a side effect of NOx control and counteract NO2 pollution reduction benefit.

Dong, Xinyi; Gao, Yang; Fu, Joshua S.; Li, Juan; Huang, Kan; Zhuang, G.; Zhou, Ying

2013-11-01T23:59:59.000Z

310

Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2  

SciTech Connect (OSTI)

Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

Pruess, K.

2011-05-15T23:59:59.000Z

311

A High Temperature Liquid Plasma Model of the Sun  

E-Print Network [OSTI]

In this work, a liquid model of the Sun is presented wherein the entire solar mass is viewed as a high density/high energy plasma. This model challenges our current understanding of the densities associated with the internal layers of the Sun, advocating a relatively constant density, almost independent of radial position. The incompressible nature of liquids is advanced to prevent solar collapse from gravitational forces. The liquid plasma model of the Sun is a non-equilibrium approach, where nuclear reactions are free to occur throughout the solar mass. The primary means of addressing internal heat transfer are convection and conduction. As a result of the convective processes on the solar surface, the liquid model brings into question the established temperature of the solar photosphere by highlighting a violation of Kirchhoff's law of thermal emission. Along these lines, the model emphasizes that radiative emission is a surface phenomenon. Strong evidence is provided that the Sun is a high density/high energy liquid plasma. This evidence is based on our knowledge of Planckian thermal emission and condensed matter, including the existence of pressure ionization and liquid metallic hydrogen at high temperatures and pressures. The equations of magnetohydrodynamics are invoked as the proper vehicle for the understanding od stellar convection and structure. Prior to introducing the liquid plasma model, the historic and scientific justifications for the gaseous model of the Sun are reviewed and the gaseous equations of state are also discussed.

Pierre-Marie Robitaille

2004-10-04T23:59:59.000Z

312

Effects of gaseous NH{sub 3} and SO{sub 2} on the concentration profiles of PCDD/F in flyash under post-combustion zone conditions  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Influence of NH{sub 3} and SO{sub 2} on 2378-PCDD/F in flyash and flue gases was investigated. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 34-75% in the flyash. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 21-40% from the flue gases. Black-Right-Pointing-Pointer SO{sub 2} led to 99% PCDD and 93% PCDF reductions in the flyash. Black-Right-Pointing-Pointer SO{sub 2} led to 89% PCDD and 76% PCDF reductions in the flue gases. - Abstract: The influence of gaseous ammonia and sulphur dioxide on the formation of 2378-substituted PCDD/F on a reference flyash from a municipal waste incinerator has been investigated using a laboratory scale fixed-bed reactor. The reference flyash samples (BCR-490) was reacted under a simulated flue gas stream at temperatures of 225 and 375 Degree-Sign C for 96 h. The experiments were carried out in two series: first with simulated flue gas alone, and then with injection of NH{sub 3} or SO{sub 2} gas into the flue gas just before the reactor inlet. It was found that the injection of gaseous ammonia into the flue gas could decrease the concentration of both PCDD and PCDF by 34-75% from the solid phase and by 21-40% from the gas phase. Converting the results to I-TEQ values, it could reduce the total I-TEQ values of PCDD and PCDF in the sum of the flyash and exhaust flue gas by 42-75% and 24-57% respectively. The application of SO{sub 2} led to 99% and 93% reductions in the PCDD and PCDF average congener concentrations, respectively in the solid phase. In the gas phase, the total reductions were 89% and 76% for PCDD and PCDF, respectively. Moreover, addition of SO{sub 2} reduced the total I-TEQ value of PCDD and PCDF in the flyash and exhaust flue gas together by 60-86% and 72-82% respectively. Sulphur dioxide was more effective than ammonia in suppressing PCDD/F formation in flyash under the conditions investigated.

Hajizadeh, Yaghoub; Onwudili, Jude A. [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom); Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom)

2012-07-15T23:59:59.000Z

313

High efficiency proportional neutron detector with solid liner internal structures  

DOE Patents [OSTI]

A tube-style neutron detector, a panel-style neutron detector incorporating a plurality of tube-style neutron detectors, and a panel-style neutron detector including a plurality of anode wires are provided. A plurality of channels is provided in a neutron detector such that each channel has an inner surface of a coating layer including a neutron-absorbing material. A wire anode is provided at end of each channel so that electrons generated by a charged daughter particle generated by a neutron are collected to detect a neutron-matter interaction. Moderator units can be incorporated into a neutron detector to provide improved detection efficiencies and/or to determine neutron energy spectrum. Gas-based proportional response from the neutron detectors can be employed for special nuclear material (SNM) detection. This neutron detector can provide similar performance to .sup.3He-based detectors without requiring .sup.3He and without containing toxic, flammable, or high-pressure materials.

Kisner, Roger Allen; Holcomb, David Eugene; Brown, Gilbert M.

2014-08-05T23:59:59.000Z

314

Improved estimates of separation distances to prevent unacceptable damage to nuclear power plant structures from hydrogen detonation for gaseous hydrogen storage. Technical report  

SciTech Connect (OSTI)

This report provides new estimates of separation distances for nuclear power plant gaseous hydrogen storage facilities. Unacceptable damage to plant structures from hydrogen detonations will be prevented by having hydrogen storage facilities meet separation distance criteria recommended in this report. The revised standoff distances are based on improved calculations on hydrogen gas cloud detonations and structural analysis of reinforced concrete structures. Also, the results presented in this study do not depend upon equivalencing a hydrogen detonation to an equivalent TNT detonation. The static and stagnation pressures, wave velocity, and the shock wave impulse delivered to wall surfaces were computed for several different size hydrogen explosions. Separation distance equations were developed and were used to compute the minimum separation distance for six different wall cases and for seven detonating volumes (from 1.59 to 79.67 lbm of hydrogen). These improved calculation results were compared to previous calculations. The ratio between the separation distance predicted in this report versus that predicted for hydrogen detonation in previous calculations varies from 0 to approximately 4. Thus, the separation distances results from the previous calculations can be either overconservative or unconservative depending upon the set of hydrogen detonation parameters that are used. Consequently, it is concluded that the hydrogen-to-TNT detonation equivalency utilized in previous calculations should no longer be used.

Not Available

1994-05-01T23:59:59.000Z

315

Thermal discharges from Paducah Gaseous Diffusion Plant outfalls: Impacts on stream temperatures and fauna of Little Bayou and Big Bayou Creeks  

SciTech Connect (OSTI)

The development of a biological monitoring plan for the receiving streams of the Paducah Gaseous Diffusion Plant (PGDP) began in the late 1980s, because of an Agreed Order (AO) issued in September 1987 by the Kentucky Division of Water (KDOW). Five years later, in September 1992, more stringent effluent limitations were imposed upon the PGDP operations when the KDOW reissued Kentucky Pollutant Discharge Elimination System permit No. KY 0004049. This action prompted the US Department of Energy (DOE) to request a stay of certain limits contained in the permit. An AO is being negotiated between KDOW, the US Enrichment Corporation (USEC), and DOE that will require that several studies be conducted, including this stream temperature evaluation study, in an effort to establish permit limitations. All issues associated with this AO have been resolved, and the AO is currently being signed by all parties involved. The proposed effluent temperature limit is 89 F (31.7 C) as a mean monthly temperature. In the interim, temperatures are not to exceed 95 F (35 C) as a monthly mean or 100 F (37.8 C) as a daily maximum. This study includes detailed monitoring of instream temperatures, benthic macroinvertebrate communities, fish communities, and a laboratory study of thermal tolerances.

Roy, W.K.; Ryon, M.G.; Hinzman, R.L. [Oak Ridge National Lab., TN (United States). Computer Science and Mathematics Div.

1996-03-01T23:59:59.000Z

316

Dual wall reverse circulation drilling with multi-level groundwater sampling for groundwater contaminant plume delineation at Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

SciTech Connect (OSTI)

Dual wall reverse circulation (DWRC) drilling was used to drill 48 borings during a groundwater contaminant investigation at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky. This method was selected as an alternative to conventional hollow stem auger drilling for a number of reasons, including the expectation of minimizing waste, increasing the drilling rate, and reducing the potential for cross contamination of aquifers. Groundwater samples were collected from several water-bearing zones during drilling of each borehole. The samples were analyzed for volatile organic compounds using a field gas chromatograph. This approach allowed the investigation to be directed using near-real-time data. Use of downhole geophysical logging, in conjunction with lithologic descriptions of borehole cuttings, resulted in excellent correlation of the geology in the vicinity of the contaminant plume. The total volume of cuttings generated using the DWRC drilling method was less than half of what would have been produced by hollow stem augering; however, the cuttings were recovered in slurry form and had to be dewatered prior to disposal. The drilling rate was very rapid, often approaching 10 ft/min; however, frequent breaks to perform groundwater sampling resulted in an average drilling rate of < 1 ft/min. The time required for groundwater sampling could be shortened by changing the sampling methodology. Analytical results indicated that the drilling method successfully isolated the various water bearing zones and no cross contamination resulted from the investigation.

Smuin, D.R.; Morti, E.E.; Zutman, J.L.; Pickering, D.A.

1995-08-01T23:59:59.000Z

317

Applicable or relevant and appropriate requirements (ARARs) for remedial actions at the Paducah Gaseous Diffusion Plant: A compendium of environmental laws and guidance. Environmental Restoration Program  

SciTech Connect (OSTI)

Section 121 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 specifies that remedial actions for cleanup of hazardous substances found at sites placed on the National Priorities List (NPL) by the US Environmental Protection Agency (EPA) must comply with applicable or relevant and appropriate requirements (ARARs) or standards under federal and state environmental laws. To date, the US Department of Energy (DOE) Paducah Gaseous Diffusion Plant (PGDP) has not been on the NPL. Although DOE and EPA have entered into an Administrative Consent Order (ACO), the prime regulatory authority for cleanup at PGDP will be the Resource Conservation and Recovery Act (RCRA). This report supplies a preliminary list of available federal and state ARARs that might be considered for remedial response at PGDP in the event that the plant becomes included on the NPL or the ACO is modified to include CERCLA cleanup. A description of the terms ``applicable`` and ``relevant and appropriate`` is provided, as well as definitions of chemical-, location-, and action-specific ARARS. ARARs promulgated by the federal government and by the state of Kentucky are listed in tables. In addition, the major provisions of RCRA, the Safe Drinking Water Act, the Clean Water Act, the Clean Air Act, and other acts, as they apply to hazardous and radioactive waste cleanup, are discussed.

Etnier, E.L.; Eaton, L.A. [Oak Ridge National Lab., TN (United States)

1992-03-01T23:59:59.000Z

318

Applicable or relevant and appropriate requirements (ARARs) for remedial actions at the Paducah Gaseous Diffusion Plant: A compendium of environmental laws and guidance  

SciTech Connect (OSTI)

Section 121 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 specifies that remedial actions for cleanup of hazardous substances found at sites placed on the National Priorities List (NPL) by the US Environmental Protection Agency (EPA) must comply with applicable or relevant and appropriate requirements (ARARs) or standards under federal and state environmental laws. To date, the US Department of Energy (DOE) Paducah Gaseous Diffusion Plant (PGDP) has not been on the NPL. Although DOE and EPA have entered into an Administrative Consent Order (ACO), the prime regulatory authority for cleanup at PGDP will be the Resource Conservation and Recovery Act (RCRA). This report supplies a preliminary list of available federal and state ARARs that might be considered for remedial response at PGDP in the event that the plant becomes included on the NPL or the ACO is modified to include CERCLA cleanup. A description of the terms applicable'' and relevant and appropriate'' is provided, as well as definitions of chemical-, location-, and action-specific ARARS. ARARs promulgated by the federal government and by the state of Kentucky are listed in tables. In addition, the major provisions of RCRA, the Safe Drinking Water Act, the Clean Water Act, the Clean Air Act, and other acts, as they apply to hazardous and radioactive waste cleanup, are discussed.

Etnier, E.L.; Eaton, L.A. (Oak Ridge National Lab., TN (United States))

1992-03-01T23:59:59.000Z

319

Assessment of chemical vulnerabilities in the Hanford high-level waste tanks  

SciTech Connect (OSTI)

The purpose of this report is to summarize results of relevant data (tank farm and laboratory) and analysis related to potential chemical vulnerabilities of the Hanford Site waste tanks. Potential chemical safety vulnerabilities examined include spontaneous runaway reactions, condensed phase waste combustibility, and tank headspace flammability. The major conclusions of the report are the following: Spontaneous runaway reactions are not credible; condensed phase combustion is not likely; and periodic releases of flammable gas can be mitigated by interim stabilization.

Meacham, J.E. [and others

1996-02-15T23:59:59.000Z

320

Industrial and natural sources of gaseous elemental mercury in the Almadn district (Spain): An updated report on this issue after the ceasing of mining and metallurgical activities in 2003 and major land reclamation works  

SciTech Connect (OSTI)

Two events during the last decade had major environmental repercussions in Almadn town (Spain). First it was the ceasing of activities in the mercury mine and metallurgical facilities in 2003, and then the finalization of the restoration works on the main waste dump in 2008. The combination of both events brought about a dramatic drop in the emissions of gaseous elemental mercury (GEM) to the atmosphere. Although no one would now call the Almadn area as mercury-free, the GEM levels have fallen beneath international reference safety levels for the first time in centuries. This has been a major breakthrough because in less than one decade the site went from GEM levels in the order of tens of thousands to mere tens nanogram per cubic meter. Although these figures are per se a remarkable achievement, they do not mark the end of the environmental concerns in the Almadn district. Two other sites remain as potential environmental hazards. (1) The Las Cuevas mercury storage complex, a partially restored ex-mining site where liquid mercury is being stored. The MERSADE Project (LIFEEuropean Union) has tested the Las Cuevas complex as a potential site for the installation of a future European prototype safe deposit of surplus mercury from industrial activities. Despite restoration works carried out in 2004, the Las Cuevas complex can still be regarded as hotspot of mercury contamination, with high concentrations above 800 ?g g{sup ?1} Hg{sub soil} and 300 ng m{sup ?3} Hg{sub gas}. However, as predicted by air contamination modeling using the ISC-AERMOD software, GEM concentrations fade away in a short distance following the formation of a NWSE oriented narrow plume extending for a few hundred meters from the complex perimeter. (2) Far more dangerous from the human health perspective is the Almadenejos area, hosting the small Almadenejos village, the so-called Cerco de Almadenejos (CDA; an old metallurgical precinct), and the mines of La Nueva Concepcin, La Vieja Concepcin and El Entredicho. The CDA is an old metallurgical site that operated between 1794 and 1861, leaving behind a legacy of extremely contaminated soils (mean concentration=4220 ?g g{sup ?1} Hg) and GEM emissions that in summer can reach levels up to 4,0005,000 ng m{sup ?3}. Thus the CDA remains the sole urban site in the district surpassing GEM international reference safety levels. In order to prevent these emissions, the CDA requires immediate action regarding restoration works. These could involve the full removal of soils or their permanent capping to create an impermeable barrier.

Higueras, Pablo, E-mail: pablo.higueras@uclm.es [Departamento de Ingeniera Geolgica y Minera, Escuela Universitaria Politcnica de Almadn, Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain) [Departamento de Ingeniera Geolgica y Minera, Escuela Universitaria Politcnica de Almadn, Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain); Instituto de Geologa Aplicada (IGeA), Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain); Mara Esbr, Jos [Departamento de Ingeniera Geolgica y Minera, Escuela Universitaria Politcnica de Almadn, Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain) [Departamento de Ingeniera Geolgica y Minera, Escuela Universitaria Politcnica de Almadn, Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain); Instituto de Geologa Aplicada (IGeA), Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain); Oyarzun, Roberto; Llanos, Willans [Instituto de Geologa Aplicada (IGeA), Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain) [Instituto de Geologa Aplicada (IGeA), Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain); Departamento de Cristalografa y Mineraloga, Facultad de Ciencias Geolgicas, Universidad Complutense, 28040 Madrid (Spain); Martnez-Coronado, Alba [Instituto de Geologa Aplicada (IGeA), Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain)] [Instituto de Geologa Aplicada (IGeA), Universidad de Castilla-La Mancha, Plaza M. Meca 1, 13400 Almadn (Spain); and others

2013-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Assessment of the influences of groundwater colloids on the migration of technetium-99 at the Paducah Gaseous Diffusion Plant Site in Paducah, Kentucky  

SciTech Connect (OSTI)

This short report summarizes the influences of groundwater colloids on the migration/transport of {sup 99}Tc at the Paducah Gaseous Diffusion Plant (PGDP) site in Paducah, Kentucky. Limited data suggest that inorganic colloidal materials (e.g., aluminosilicate clay minerals) may not play a significant role in the retention and transport of Tc. Studies by size fractionation reveal that both Tc and natural organic matter (NOM) are largely present in the <3K fraction. The role of NOM on Tc retention and transport is not conclusive on the basis of this study. However, a literature review suggests that Tc is very likely associated with the groundwater organics. The presence of the organic matter could have increased the solubility and cotransport of Tc at the PGDP site. Further studies, applying such techniques as gel chromatography, size exclusion, and spectroscopy, may be useful to determine the association of organic matter with Tc. If Tc is associated with groundwater organics, appropriate protocols for removal of organic matter associated with Tc may be developed. Time and resources were limited so this study is not comprehensive with respect to the role of mobile organic and inorganic colloidal materials on Tc transport in subsurface soils. The redox conditions (DO) of groundwaters reported may not represent the true groundwater conditions, which could have influenced the association and dissociation of Tc with groundwater colloidal materials. Because Tc concentrations in the groundwater (on the order of nCi/L) at the PGDP site is much lower than the solubility of reduced Tc (IV) (on the order of {approximately}10{sup {minus}8} mol/L or parts per billion), regardless of the redox conditions, Tc will stay in solution phase as TC(IV) or Tc(VII). The mechanisms of adsorption/association vs precipitation must be understood under reduced and low Tc conditions so that strategic plans for remediation of Tc contaminated soils and groundwaters can be developed.

Gu, B.; McDonald, J.A.; McCarthy, J.F. [Oak Ridge National Lab., TN (United States); Clausen, J.L. [Paducah Gaseous Diffusion Plant, KY (United States). Environmental Restoration and Waste Management

1994-07-01T23:59:59.000Z

322

Infrared absorption of gaseous CH{sub 2}BrOO detected with a step-scan Fourier-transform absorption spectrometer  

SciTech Connect (OSTI)

CH{sub 2}BrOO radicals were produced upon irradiation, with an excimer laser at 248 nm, of a flowing mixture of CH{sub 2}Br{sub 2} and O{sub 2}. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record temporally resolved infrared (IR) absorption spectra of reaction intermediates. Transient absorption with origins at 1276.1, 1088.3, 961.0, and 884.9 cm{sup ?1} are assigned to ?{sub 4} (CH{sub 2}-wagging), ?{sub 6} (OO stretching), ?{sub 7} (CH{sub 2}-rocking mixed with CO stretching), and ?{sub 8} (CO stretching mixed with CH{sub 2}-rocking) modes of syn-CH{sub 2}BrOO, respectively. The assignments were made according to the expected photochemistry and a comparison of observed vibrational wavenumbers, relative IR intensities, and rotational contours with those predicted with the B3LYP/aug-cc-pVTZ method. The rotational contours of ?{sub 7} and ?{sub 8} indicate that hot bands involving the torsional (?{sub 12}) mode are also present, with transitions 7{sub 0}{sup 1}12{sub v}{sup v} and 8{sub 0}{sup 1}12{sub v}{sup v}, v = 110. The most intense band (?{sub 4}) of anti-CH{sub 2}BrOO near 1277 cm{sup ?1} might have a small contribution to the observed spectra. Our work provides information for directly probing gaseous CH{sub 2}BrOO with IR spectroscopy, in either the atmosphere or laboratory experiments.

Huang, Yu-Hsuan [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Lee, Yuan-Pern, E-mail: yplee@mail.nctu.edu.tw [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China)

2014-10-28T23:59:59.000Z

323

Arsenic removal from gaseous streams  

SciTech Connect (OSTI)

Uranium feed materials, depending on the production process, have been found to contain arsenic (As) as a contaminant. Analyses show the As to be present as As pentafluoride (AsF{sub 5}) and/or hexafluoroarsenic acid (HAsF{sub 6}) and enter the enrichment cycle through contaminated hydrogen fluoride (HF). Problems related to corrosion of cylinder valves and plugging of feed lines and valves have been attributed to the As. Techniques to separate AsF{sub 5} from uranium hexafluoride (UF{sub 6}) using sodium fluoride (NaF) as a trapping media were successful and will be discussed. Procedures to significantly reduce (up to 97%) the level of As in HF will also be reported. 5 figs., 9 tabs.

Russell, R.G.; Otey, M.G.

1989-11-22T23:59:59.000Z

324

Impact Of Melter Internal Design On Off-Gas Flammability  

SciTech Connect (OSTI)

The purpose of this study was to: (1) identify the more dominant design parameters that can serve as the quantitative measure of how prototypic a given melter is, (2) run the existing DWPF models to simulate the data collected using both DWPF and non-DWPF melter configurations, (3) confirm the validity of the selected design parameters by determining if the agreement between the model predictions and data is reasonably good in light of the design and operating conditions employed in each data set, and (4) run Computational Fluid Dynamics (CFD) simulations to gain new insights into how fluid mixing is affected by the configuration of melter internals and to further apply the new insights to explaining, for example, why the agreement is not good.

Choi, A. S.; Lee, S. Y.

2012-05-30T23:59:59.000Z

325

Flammability Analysis For Actinide Oxides Packaged In 9975 Shipping Containers  

SciTech Connect (OSTI)

Packaging options are evaluated for compliance with safety requirements for shipment of mixed actinide oxides packaged in a 9975 Primary Containment Vessel (PCV). Radiolytic gas generation rates, PCV internal gas pressures, and shipping windows (times to reach unacceptable gas compositions or pressures after closure of the PCV) are calculated for shipment of a 9975 PCV containing a plastic bottle filled with plutonium and uranium oxides with a selected isotopic composition. G-values for radiolytic hydrogen generation from adsorbed moisture are estimated from the results of gas generation tests for plutonium oxide and uranium oxide doped with curium-244. The radiolytic generation of hydrogen from the plastic bottle is calculated using a geometric model for alpha particle deposition in the bottle wall. The temperature of the PCV during shipment is estimated from the results of finite element heat transfer analyses.

Laurinat, James E.; Askew, Neal M.; Hensel, Steve J.

2013-03-21T23:59:59.000Z

326

Use Lower Flammable Limit Monitoring Equipment to Improve Process...  

Broader source: Energy.gov (indexed) [DOE]

(October 2007) More Documents & Publications Check Burner Air to Fuel Ratios Waste Heat Reduction and Recovery for Improving Furnace Efficiency, Productivity and Emissions...

327

Flammable gas tank exhauster interlock (FGTEI) computer software design description  

SciTech Connect (OSTI)

Modicon Compact Programmable Logic Controller (PLC). The device configuration integrates the isolation and current- carrying capacities of mechanical relays with the logic and programming sophistication of the PLC. This revised document provides descriptions of components and tasks involved in the PLC system for controlling and monitoring the FGTEI. All control functions required by the PLC, and how they are implemented, are described in detail.

Smith, S.O., Westinghouse Hanford

1996-09-20T23:59:59.000Z

328

Flammable gas tank exhauster interlock (FGTEI) computer software design description  

SciTech Connect (OSTI)

Modicon Compact Programmable Logic Controller (PLC). The device configuration integrates the isolation and current-carrying capacities of mechanical relays with the logic and programming sophistication of the PLC. This document provides descriptions of components and tasks involved in the PLC system for controlling and monitoring the FGTEI. All control functions required by the PLC, and how they are implemented, are described in detail.

Smith, S.0.

1996-09-10T23:59:59.000Z

329

Flammable gas tank exhauster interlock (LFGTEI) computer software design description  

SciTech Connect (OSTI)

Modicon Compact Programmable Logic Controller (PLC). The device configuration integrates the isolation and current- carrying capacities of mechanical relays with the logic and programming sophistication of the PLC. This revised document provides descriptions of components and tasks involved in the PLC system for controlling and monitoring the FGTEI. All control functions required by the PLC, and how they are implemented, are described in detail.

Smith, S.O.; Irvitt, R.W., Fluor Daniel Hanford

1997-02-21T23:59:59.000Z

330

Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up from theDepartment of Dept. ofUSA RSDepartment of EnergyEfficiency | Department of

331

A TECHNICAL ASSESSMENT OF THE CURRENT WATER POLICY BOUNDARY AT U.S. DEPARTMENT OF ENERGY, PADUCAH GASEOUS DIFFUSION PLANT, PADUCAH, KENTUCKY  

SciTech Connect (OSTI)

In 1988, groundwater contaminated with trichloroethene (TCE) and technetium-99 (Tc-99) was identified in samples collected from residential water wells withdrawing groundwater from the Regional Gravel Aquifer (RGA) north of the Paducah Gaseous Diffusion Plant (PGDP) facility. In response, the U.S. Department of Energy (DOE) provided temporary drinking water supplies to approximately 100 potentially affected residents by initially supplying bottled water, water tanks, and water-treatment systems, and then by extending municipal water lines, all at no cost, to those persons whose wells could be affected by contaminated groundwater. The Water Policy boundary was established in 1993. In the Policy, DOE agreed to pay the reasonable monthly cost of water for homes and businesses and, in exchange, many of the land owners signed license agreements committing to cease using the groundwater via rural water wells. In 2012, DOE requested that Oak Ridge Associated Universities (ORAU), managing contractor of Oak Ridge Institute for Science and Education (ORISE), provide an independent assessment of the quality and quantity of the existing groundwater monitoring data and determine if there is sufficient information to support a modification to the boundary of the current Water Policy. As a result of the assessment, ORAU concludes that sufficient groundwater monitoring data exists to determine that a shrinkage and/or shift of the plume(s) responsible for the initial development of this policy has occurred. Specifically, there is compelling evidence that the TCE plume is undergoing shrinkage due to natural attenuation and associated degradation. The plume shrinkage (and migration) has also been augmented in local areas where large volumes of groundwater were recovered by pump-and treat remedial systems along the eastern and western boundaries of the Northwest Plume, and in other areas where pump-and-treat systems have been deployed by DOE to remove source contaminants. The available evidence supports adjusting the western and northwestern Water Policy boundary. Based on the historical and modeled hydrogeological data reflecting past flow and plume attenuation, along with associated plume migration toward the northeast, the establishment of a new boundary along the westernmost margin of the earliest indication of the TCE plume is proposed and justified on hydrogeological grounds. Approximately 30% of the original area would remain within the adjusted Water Policy area west and northwest of the PGDP facility. This modification would release about 70% of the area, although individual properties would overlap the new boundary.

None

2012-12-13T23:59:59.000Z

332

ENZYME ACTIVITY PROBE AND GEOCHEMICAL ASSESSMENT FOR POTENTIAL AEROBIC COMETABOLISM OF TRICHLOROETHENE IN GROUNDWATER OF THE NORTHWEST PLUME, PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY  

SciTech Connect (OSTI)

The overarching objective of the Paducah Gaseous Diffusion Plant (PGDP) enzyme activity probe (EAP) effort is to determine if aerobic cometabolism is contributing to the attenuation of trichloroethene (TCE) and other chlorinated solvents in the contaminated groundwater beneath PGDP. The site-specific objective for the EAP assessment is to identify if key metabolic pathways are present and expressed in the microbial community--namely the pathways that are responsible for degradation of methane and aromatic (e.g. toluene, benzene, phenol) substrates. The enzymes produced to degrade methane and aromatic compounds also break down TCE through a process known as cometabolism. EAPs directly measure if methane and/or aromatic enzyme production pathways are operating and, for the aromatic pathways, provide an estimate of the number of active organisms in the sampled groundwater. This study in the groundwater plumes at PGDP is a major part of a larger scientific effort being conducted by Interstate Technology and Regulatory Council (ITRC), U.S. Department of Energy (DOE) Office of Environmental Management (EM), Savannah River National Laboratory (SRNL), and North Wind Inc. in which EAPs are being applied to contaminated groundwater from diverse hydrogeologic and plume settings throughout the U.S. to help standardize their application as well as their interpretation. While EAP data provide key information to support the site specific objective for PGDP, several additional lines of evidence are being evaluated to increase confidence in the determination of the occurrence of biodegradation and the rate and sustainability of aerobic cometabolism. These complementary efforts include: (1) Examination of plume flowpaths and comparison of TCE behavior to 'conservative' tracers in the plume (e.g., {sup 99}Tc); (2) Evaluation of geochemical conditions throughout the plume; and (3) Evaluation of stable isotopes in the contaminants and their daughter products throughout the plume. If the multiple lines of evidence support the occurrence of cometabolism and the potential for the process to contribute to temporal and spatial attenuation of TCE in PGDP groundwater, then a follow-up enzyme probe microcosm study to better estimate biological degradation rate(s) is warranted.

Looney, B; M. Hope Lee, M; S. K. Hampson, S

2008-06-27T23:59:59.000Z

333

Dose Modeling Evaluations and Technical Support Document For the Authorized Limits Request for the DOE-Owned Property Outside the Limited Area, Paducah Gaseous Diffusion Plant Paducah, Kentucky  

SciTech Connect (OSTI)

Environmental assessments and remediation activities are being conducted by the U.S. Department of Energy (DOE) at the Paducah Gaseous Diffusion Plant (PGDP), Paducah, Kentucky. The Oak Ridge Institute for Science and Education (ORISE), a DOE prime contractor, was contracted by the DOE Portsmouth/Paducah Project Office (DOE-PPPO) to conduct radiation dose modeling analyses and derive single radionuclide soil guidelines (soil guidelines) in support of the derivation of Authorized Limits (ALs) for 'DOE-Owned Property Outside the Limited Area' ('Property') at the PGDP. The ORISE evaluation specifically included the area identified by DOE restricted area postings (public use access restrictions) and areas licensed by DOE to the West Kentucky Wildlife Management Area (WKWMA). The licensed areas are available without restriction to the general public for a variety of (primarily) recreational uses. Relevant receptors impacting current and reasonably anticipated future use activities were evaluated. In support of soil guideline derivation, a Conceptual Site Model (CSM) was developed. The CSM listed radiation and contamination sources, release mechanisms, transport media, representative exposure pathways from residual radioactivity, and a total of three receptors (under present and future use scenarios). Plausible receptors included a Resident Farmer, Recreational User, and Wildlife Worker. single radionuclide soil guidelines (outputs specified by the software modeling code) were generated for three receptors and thirteen targeted radionuclides. These soil guidelines were based on satisfying the project dose constraints. For comparison, soil guidelines applicable to the basic radiation public dose limit of 100 mrem/yr were generated. Single radionuclide soil guidelines from the most limiting (restrictive) receptor based on a target dose constraint of 25 mrem/yr were then rounded and identified as the derived soil guidelines. An additional evaluation using the derived soil guidelines as inputs into the code was also performed to determine the maximum (peak) dose for all receptors. This report contains the technical basis in support of the DOE?s derivation of ALs for the 'Property.' A complete description of the methodology, including an assessment of the input parameters, model inputs, and results is provided in this report. This report also provides initial recommendations on applying the derived soil guidelines.

Boerner, A. J. [Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States). Independent Environmental Assessment and Verification Program; Maldonado, D. G. [Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States). Independent Environmental Assessment and Verification Program; Hansen, Tom [Ameriphysics, LLC (United States)

2012-09-01T23:59:59.000Z

334

Low-temperature conversion of high-moisture biomass: Continuous reactor system results  

SciTech Connect (OSTI)

Pacific Northwest Laboratory (PNL) is developing a low-temperature, catalytic process for converting high-moisture biomass feedstocks and other wet organic substances to useful gaseous fuels. This system, in which thermocatalytic conversion takes place in an aqueous environment, was designed to overcome the problems usually encountered with high-water-content feedstocks. The process uses a reduced nickel catalyst at temperatures as low as 350{degree}C and pressures ranging from 2000 to 4000 psig -- conditions favoring the formation of gas consisting mostly of methane. The results of numerous batch tests showed that the system could convert feedstocks not readily converted by conventional methods. Fifteen tests were conducted in a continuous reactor system to further evaluate the effectiveness of the process for high-moisture biomass gasification and to obtain conversion rate data needed for process scaleup. During the tests, the complex gasification reactions were evaluated by several analytical methods. The results of these tests show that the heating value of the gas ranged from 400 to 500 Btu/scf, and if the carbon dioxide is removed, the product gas is pipeline quality. Conversion of the feedstocks was high. Engineering analysis indicates that, based on these results, a tubular reactor can be designed that should convert greater than 99% of the carbon fed as high-moisture biomass to a gaseous product in a reaction time of less than 11 min.

Elliott, D.C.; Sealock, L.J. Jr.; Butner, R.S.; Baker, E.G.; Neuenschwander, G.G.

1989-10-01T23:59:59.000Z

335

Tar-free fuel gas production from high temperature pyrolysis of sewage sludge  

SciTech Connect (OSTI)

Highlights: High temperature pyrolysis of sewage sludge was efficient for producing tar-free fuel gas. Complete tar removal and volatile matter release were at elevated temperature of 1300 C. Sewage sludge was converted to residual solid with high ash content. 72.60% of energy conversion efficiency for gas production in high temperature pyrolysis. Investment and costing for tar cleaning were reduced. - Abstract: Pyrolysis of sewage sludge was studied in a free-fall reactor at 10001400 C. The results showed that the volatile matter in the sludge could be completely released to gaseous product at 1300 C. The high temperature was in favor of H{sub 2} and CO in the produced gas. However, the low heating value (LHV) of the gas decreased from 15.68 MJ/N m{sup 3} to 9.10 MJ/N m{sup 3} with temperature increasing from 1000 C to 1400 C. The obtained residual solid was characterized by high ash content. The energy balance indicated that the most heating value in the sludge was in the gaseous product.

Zhang, Leguan; Xiao, Bo; Hu, Zhiquan; Liu, Shiming, E-mail: Zhangping101@yeah.net; Cheng, Gong; He, Piwen; Sun, Lei

2014-01-15T23:59:59.000Z

336

Apparatus and method for combusting low quality fuel  

DOE Patents [OSTI]

A gas turbine (12) capable of combusting a low quality gaseous fuel having a ratio of flammability limits less than 2, or a heat value below 100 BTU/SCF. A high quality fuel is burned simultaneously with the low quality fuel to eliminate instability in the combustion flame. A sensor (46) is used to monitor at least one parameter of the flame indicative of instability. A controller (50) having the sensor signal (48) as input is programmed to control the relative flow rates of the low quality and high quality fuels. When instability is detected, the flow rate of high quality fuel is automatically increased in relation to the flow rate of low quality fuel to restore stability.

Brushwood, John Samuel; Pillsbury, Paul; Foote, John; Heilos, Andreas

2003-11-04T23:59:59.000Z

337

Vitrification of high sulfate wastes  

SciTech Connect (OSTI)

The US Department of Energy (DOE) through the Mixed Waste Integrated Program (MWIP) is investigating the application of vitrification technology to mixed wastes within the DOE system This work involves identifying waste streams, laboratory testing to identify glass formulations and characterize the vitrified product, and demonstration testing with the actual waste in a pilot-scale system. Part of this program is investigating process limits for various waste components, specifically those components that typically create problems for the application of vitrification, such as sulfate, chloride, and phosphate. This work describes results from vitrification testing for a high-sulfate waste, the 183-H Solar Evaporation Basin waste at Hanford. A low melting phosphate glass formulation has been developed for a waste stream high in sodium and sulfate. At melt temperatures in the range of 1,000 C to 1,200 C, sulfate in the waste is decomposed to gaseous oxides and driven off during melting, while the remainder of the oxides stay in the melt. Decomposition of the sulfates eliminates the processing problems typically encountered in vitrification of sulfate-containing wastes, resulting in separation of the sulfate from the remainder of the waste and allowing the sulfate to be collected in the off-gas system and treated as a secondary waste stream. Both the vitreous product and intentionally devitrified samples are durable when compared to reference glasses by TCLP and DI water leach tests. Simple, short tests to evaluate the compatibility of the glasses with potential melter materials found minimal corrosion with most materials.

Merrill, R.A.; Whittington, K.F.; Peters, R.D.

1994-09-01T23:59:59.000Z

338

Process for producing enriched uranium having a {sup 235}U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage  

DOE Patents [OSTI]

An uranium enrichment process capable of producing an enriched uranium, having a {sup 235}U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower {sup 235}U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF{sub 6} tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a {sup 235} U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % {sup 235} U; fluorinating this enriched metallic uranium isotopic mixture to form UF{sub 6}; processing the resultant isotopic mixture of UF{sub 6} in a gaseous diffusion process to produce a final enriched uranium product having a {sup 235}U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low {sup 235}U content UF{sub 6} having a {sup 235}U content of about 0.71 wt. % of the total uranium content of the low {sup 235}U content UF{sub 6}; and converting this low {sup 235}U content UF{sub 6} to metallic uranium for recycle to the atomic vapor laser isotope separation process. 4 figs.

Horton, J.A.; Hayden, H.W. Jr.

1995-05-30T23:59:59.000Z

339

Process for producing enriched uranium having a .sup.235 U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage  

DOE Patents [OSTI]

An uranium enrichment process capable of producing an enriched uranium, having a .sup.235 U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower .sup.235 U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF.sub.6 tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a .sup.235 U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % .sup.235 U; fluorinating this enriched metallic uranium isotopic mixture to form UF.sub.6 ; processing the resultant isotopic mixture of UF.sub.6 in a gaseous diffusion process to produce a final enriched uranium product having a .sup.235 U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low .sup.235 U content UF.sub.6 having a .sup.235 U content of about 0.71 wt. % of the total uranium content of the low .sup.235 U content UF.sub.6 ; and converting this low .sup.235 U content UF.sub.6 to metallic uranium for recycle to the atomic vapor laser isotope separation process.

Horton, James A. (Livermore, CA); Hayden, Jr., Howard W. (Oakridge, TN)

1995-01-01T23:59:59.000Z

340

Absorption features of high redshift galactic winds  

E-Print Network [OSTI]

The environment of high-redshift galaxies is characterized by both wind-driven outflowing gas and gravitationally infalling streams. To investigate such galaxy-IGM interplay we have generated synthetic optical absorption line spectra piercing the volume surrounding a starbursting analog of a Lyman Break Galaxy selected in a $z \\approx 3$ output from a SPH simulation, including a detailed treatment of mechanical feedback from winds. Distributions for several observable species (HI, CIII, CIV, SiII, SiIII, SiIV, OVI, OVII, and OVIII) have been derived by post-processing the simulation outputs. The hot wind material is characterized by the presence of high-ionization species such as OVI, OVII, and OVIII (the latter two observable only in X-ray bands); the colder ($Tgas clumps. However, both line profile and Pixel Optical Depth analysis of the synthetic spectra show that the intergalactic filament in which the wind-blowing galaxy is embedded produces absorption signatures that closely mimic those of the wind environment. We conclude that may be difficult to clearly identify wind-blowing galaxies and their complex gaseous environment at high redshift in optical QSO absorption-line spectra based solely on the observed ion absorption patterns.

A. P. M. Fangano; A. Ferrara; P. Richter

2007-06-11T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Thermal and Radiolytic Gas Generation in Hanford High-Level Waste  

SciTech Connect (OSTI)

The Hanford Site has 177 underground storage tanks containing radioactive wastes that are complex mixes of radioactive and chemical products. Some of these wastes are known to generate and retain large quantities of flammable gases consisting of hydrogen, nitrous oxide, nitrogen, and ammonia. Because these gases are flammable and have the potential for rapid release, the gas generation rate for each tank must be determined to establish the flammability hazard (Johnson et al. 1997). An understanding of gas generation is important to operation of the waste tanks for several reasons. First, knowledge of the overall rate of generation is needed to verify that any given tank has sufficient ventilation to ensure that flammable gases are maintained at a safe level within the dome space. Understanding the mechanisms for production of the various gases is important so that future waste operations do not create conditions that promote the production of hydrogen, ammonia, and nitrous oxide. Studying the generation of gases also provides important data for the composition of the gas mixture, which in turn is needed to assess the flammability characteristics. Finally, information about generation of gases, including the influence of various chemical constituents, temperature, and dose, would aid in assessing the future behavior of the waste during interim storage, implementation of controls, and final waste treatment. This paper summarizes the current knowledge of gas generation pathways and discusses models used in predicting gas generation rates from actual Hanford radioactive wastes. A comparison is made between measured gas generation rates and rates by the predictive models.

Bryan, Samuel A.; Pederson, Larry R.; King, C. M.

2000-01-31T23:59:59.000Z

342

Using a Regional Chemical Transport Model for the Analysis of Gaseous and Particulate Air Pollutants in the Mexico City Metropolitan Area  

E-Print Network [OSTI]

Air quality in the Mexico City Metropolitan Area (MCMA) is the subject of many studies due to concerns from high emissions and their adverse effects on public health and the environment. In this study, a high resolution simulation is performed...

Ali, Sajjad Ghulam

2012-02-14T23:59:59.000Z

343

Hydrogen Cylinder Storage Array Explosion Evaluations at the High Flux Isotope Reactor  

SciTech Connect (OSTI)

The safety analysis for a recently-installed cold neutron source at the High Flux Isotope Reactor (HFIR) involved evaluation of potential explosion consequences from accidental hydrogen jet releases that could occur from an array of hydrogen cylinders. The scope of the safety analysis involved determination of the release rate of hydrogen, the total quantity of hydrogen assumed to be involved in the explosion, the location of an ignition point or center of the explosion from receptors of interest, and the peak overpressure at the receptors. To evaluate the total quantity of hydrogen involved in the explosion, a 2D model was constructed of the jet concentration and a radial-axial integral over the jet cloud from the centerline to the flammability limit of 4% was used to determine the hydrogen mass to be used as a source term. The location of the point source was chosen as the peak of the jet centerline concentration profile. Consequences were assessed using a combination of three methods for estimating local overpressure as a function of explosion source strength and distance: the Baker-Strehlow method, the TNT-equivalence method, and the TNO method. Results from the explosions were assessed using damage estimates in screening tables for buildings and industrial equipment.

Cook, David Howard [ORNL] [ORNL; Griffin, Frederick P [ORNL] [ORNL; Hyman III, Clifton R [ORNL] [ORNL

2010-01-01T23:59:59.000Z

344

Advanced Diagnostics for High Pressure Spray Combustion.  

SciTech Connect (OSTI)

The development of accurate predictive engine simulations requires experimental data to both inform and validate the models, but very limited information is presently available about the chemical structure of high pressure spray flames under engine- relevant conditions. Probing such flames for chemical information using non- intrusive optical methods or intrusive sampling techniques, however, is challenging because of the physical and optical harshness of the environment. This work details two new diagnostics that have been developed and deployed to obtain quantitative species concentrations and soot volume fractions from a high-pressure combusting spray. A high-speed, high-pressure sampling system was developed to extract gaseous species (including soot precursor species) from within the flame for offline analysis by time-of-flight mass spectrometry. A high-speed multi-wavelength optical extinction diagnostic was also developed to quantify transient and quasi-steady soot processes. High-pressure sampling and offline characterization of gas-phase species formed following the pre-burn event was accomplished as well as characterization of gas-phase species present in the lift-off region of a high-pressure n-dodecane spray flame. For the initial samples discussed in this work several species were identified, including polycyclic aromatic hydrocarbons (PAH); however, quantitative mole fractions were not determined. Nevertheless, the diagnostic developed here does have this capability. Quantitative, time-resolved measurements of soot extinction were also accomplished and the novel use of multiple incident wavelengths proved valuable toward characterizing changes in soot optical properties within different regions of the spray flame.

Skeen, Scott A.; Manin, Julien Luc; Pickett, Lyle M.

2014-06-01T23:59:59.000Z

345

High temperature electrochemical corrosion rate probes  

SciTech Connect (OSTI)

Corrosion occurs in the high temperature sections of energy production plants due to a number of factors: ash deposition, coal composition, thermal gradients, and low NOx conditions, among others. Electrochemical corrosion rate (ECR) probes have been shown to operate in high temperature gaseous environments that are similar to those found in fossil fuel combustors. ECR probes are rarely used in energy production plants at the present time, but if they were more fully understood, corrosion could become a process variable at the control of plant operators. Research is being conducted to understand the nature of these probes. Factors being considered are values selected for the Stern-Geary constant, the effect of internal corrosion, and the presence of conductive corrosion scales and ash deposits. The nature of ECR probes will be explored in a number of different atmospheres and with different electrolytes (ash and corrosion product). Corrosion rates measured using an electrochemical multi-technique capabilities instrument will be compared to those measured using the linear polarization resistance (LPR) technique. In future experiments, electrochemical corrosion rates will be compared to penetration corrosion rates determined using optical profilometry measurements.

Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Ziomek-Moroz, M.

2005-09-01T23:59:59.000Z

346

SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET  

E-Print Network [OSTI]

. Highly flammable. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may. Mechanical exhaust required. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Government approved respirator. Hand

Choi, Kyu Yong

347

ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2  

SciTech Connect (OSTI)

ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

Pruess, K.

2011-04-01T23:59:59.000Z

348

2011 Spring : Highly Distinguished Honors Highly Distinguished  

E-Print Network [OSTI]

Elizabeth Campbell Highly Distinguished Bowker Ripley Eden Highly Distinguished Brandfass Lara Rose Highly Distinguished Brotherton Cara Price Highly Distinguished Brown Anna Laughlin Highly Distinguished Brown Chloe Alix Highly Distinguished Brown Kelsey Michelle Highly Distinguished Brown Kyle Truman Highly

Kasman, Alex

349

Investigation of high temperature gaseous species by Knudsen cell mass spectrometry above the condensed systems Cu-Y-Ru-C, Ag-Y-Ru-C, and Au-Y- Ru-C  

E-Print Network [OSTI]

of the total ion intensities listed in Tables 2 through 5, + + except those for RuC and YC2, were calculated by dividing the individual isotopic species by the isotopic abundance of that species according to Equation 1, where I is the total intensity of all... not be used because their mass to charge ratios overlap. For these iona, an + algebraic equation was used which compared the ratios of YC (Mass 113), YC2 (Mass 114), RuC (Mass 113), and RuC (Mass 114). The + + + calculated isotopic abundances...

Wilhite, Dale Wayne

1988-01-01T23:59:59.000Z

350

2009 Spring : Highly Distinguished Honors Highly Distinguished  

E-Print Network [OSTI]

Armstrong Anna P Highly Distinguished Armstrong Jack Ray Highly Distinguished Armstrong Sarah Rose Highly

Kasman, Alex

351

Design of a continuous fiber ceramic composite heat exchanger for high-temperature, high-pressure applications  

SciTech Connect (OSTI)

A conceptual design of a continuous fiber ceramic composite (CFCC) heat exchanger for high-temperature, high-pressure applications is presented. The CFCC materials under consideration are SiC reinforced with SiC fibers manufactured using the continuous vapor infiltration process and alumina reinforced with SiC or alumina fibers manufactured using the directed metal oxidation process. These composite materials are highly resistant to high-temperature corrosive environment and possess a greater creep strength than metallic materials. Heat exchangers constructed of CFCC material may be utilized for high-temperature, high-pressure applications such as air/gas heaters in advanced energy systems and high-temperature energy recovery systems. This paper presents a design of a gas-to-air CFCC heat exchanger for the high temperature advanced furnace (HITAF) in the high-performance power system (HIPPS). The 1.38 MPa (200 psia) air is heated from 760 C (1,400 F) to 982 C (1,800 F) using the combustion products at 1,650 C (3,000 F). The heat exchanger is of a cross-parallel/counter flow type in which the tube-side air flow makes a combined parallel and counter flow arrangement with a cross-flowing combustion gas in such a way that the maximum CFCC tube temperature will not exceed a 1,260 C (2,300 F) design limit. The main heat transfer mechanism from the external hot gas to the tube-side air is that of gaseous radiation for the first few rows of the tubes, followed by convective heat transfer across the remainder of the tube bundle. The design characteristics of this high-temperature, high-pressure CFCC heat exchanger with supporting thermal, flow, structural, and vibrational analyses are presented in detail in the paper.

Cho, S.M.; Seltzer, A.H.; Narayanan, T.V. [Foster Wheeler Development Corp., Livingston, NJ (United States); Shah, A.C.; Weddell, J.K. [DuPont Lanxide Composites Inc., Newark, DE (United States)

1996-12-31T23:59:59.000Z

352

2012 Fall : Highly Distinguished Honors Highly Distinguished  

E-Print Network [OSTI]

Distinguished Andersen Meredith Esther Highly Distinguished Anderson Anna Kathleen Highly Distinguished Anderson Leah Ellen Highly Distinguished Anderson Lucy Paige Highly Distinguished Andrews James Matheson Highly Distinguished Aquino Jeri-Lynn Highly Distinguished Armistead Mary Chandler Highly Distinguished Armstrong Jessa

Kasman, Alex

353

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

SciTech Connect (OSTI)

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

354

Development of ceramic membrane reactors for high temperature gas cleanup. Final report  

SciTech Connect (OSTI)

The objective of this project was to develop high temperature, high pressure catalytic ceramic membrane reactors and to demonstrate the feasibility of using these membrane reactors to control gaseous contaminants (hydrogen sulfide and ammonia) in integrated gasification combined cycle (IGCC) systems. Our strategy was to first develop catalysts and membranes suitable for the IGCC application and then combine these two components as a complete membrane reactor system. We also developed a computer model of the membrane reactor and used it, along with experimental data, to perform an economic analysis of the IGCC application. Our results have demonstrated the concept of using a membrane reactor to remove trace contaminants from an IGCC process. Experiments showed that NH{sub 3} decomposition efficiencies of 95% can be achieved. Our economic evaluation predicts ammonia decomposition costs of less than 1% of the total cost of electricity; improved membranes would give even higher conversions and lower costs.

Roberts, D.L.; Abraham, I.C.; Blum, Y.; Gottschlich, D.E.; Hirschon, A.; Way, J.D.; Collins, J.

1993-06-01T23:59:59.000Z

355

Low-temperature conversion of high-moisture biomass: Topical report, January 1984--January 1988  

SciTech Connect (OSTI)

Pacific Northwest Laboratory (PNL) is developing a low-temperature, catalytic process that converts high-moisture biomass feedstocks and other wet organic substances to useful gaseous and liquid fuels. The advantage of this process is that it works without the need for drying or dewatering the feedstock. Conventional thermal gasification processes, which require temperatures above 750/degree/C and air or oxygen for combustion to supply reaction heat, generally cannot utilize feedstocks with moisture contents above 50 wt %, as the conversion efficiency is greatly reduced as a result of the drying step. For this reason, anaerobic digestion or other bioconversion processes traditionally have been used for gasification of high-moisture feedstocks. However, these processes suffer from slow reaction rates and incomplete carbon conversion. 50 refs., 21 figs., 22 tabs.

Sealock, L.J. Jr.; Elliott, D.C.; Butner, R.S.; Neuenschwander, G.G.

1988-10-01T23:59:59.000Z

356

Refurbishment of uranium hexafluoride cylinder storage yards C-745-K, L, M, N, and P and construction of a new uranium hexafluoride cylinder storage yard (C-745-T) at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

SciTech Connect (OSTI)

The Paducah Gaseous Diffusion Plant (PGDP) is a uranium enrichment facility owned by the US Department of Energy (DOE). A residual of the uranium enrichment process is depleted uranium hexafluoride (UF6). Depleted UF6, a solid at ambient temperature, is stored in 32,200 steel cylinders that hold a maximum of 14 tons each. Storage conditions are suboptimal and have resulted in accelerated corrosion of cylinders, increasing the potential for a release of hazardous substances. Consequently, the DOE is proposing refurbishment of certain existing yards and construction of a new storage yard. This environmental assessment (EA) evaluates the impacts of the proposed action and no action and considers alternate sites for the proposed new storage yard. The proposed action includes (1) renovating five existing cylinder yards; (2) constructing a new UF6 storage yard; handling and onsite transport of cylinders among existing yards to accommodate construction; and (4) after refurbishment and construction, restacking of cylinders to meet spacing and inspection requirements. Based on the results of the analysis reported in the EA, DOE has determined that the proposed action is not a major Federal action that would significantly affect the quality of the human environment within the context of the National Environmental Policy Act of 1969. Therefore, DOE is issuing a Finding of No Significant Impact. Additionally, it is reported in this EA that the loss of less than one acre of wetlands at the proposed project site would not be a significant adverse impact.

NONE

1996-07-01T23:59:59.000Z

357

Systematic Microstructural and Corrosion Performance Evaluation of CK-3MCuN and CN-3MN High Molybdenum Stainless Steel Castings  

SciTech Connect (OSTI)

High molybdenum austenitic stainless steel castings are widely accepted for their high strength, excellent weldability, and good corrosion resistance over a wide range of temperatures in highly oxidizing aqueous and gaseous media in chemical processing and other environments. With their desirable performance, high molybdenum austenitic stainless steel castings are increasingly applied in industry in a similar manner as wrought materials. In general, cast and wrought stainless and high alloy steels are anticipated to possess equivalent resistance to corrosive media, and they are frequently used in conjunction with each other. However, alloying element segregation usually is more evident in castings than in wrought counterparts. Segregation of alloying elements can lead to the formation of secondary phases, such as sigma. Mechanical properties and especially the corrosion resistance of castings may be affected by the secondary phases. In addition, improper heat treatment procedures c an also lead to the formation of carbides and secondary phases in high alloy and austenitic stainless steels.

C.D. Lundin; S. Wen; W. Liu; G. Zhou

2001-10-01T23:59:59.000Z

358

Disk Accretion Onto High-Mass Planets  

E-Print Network [OSTI]

We analyze the nonlinear, two-dimensional response of a gaseous, viscous protoplanetary disk to the presence of a planet of one Jupiter mass (1 M_J) and greater that orbits a 1 solar mass star by using the ZEUS hydrodynamics code with high resolution near the planet's Roche lobe. The planet is assumed to be in a circular orbit about the central star and is not allowed to migrate. A gap is formed about the orbit of the planet, but there is a nonaxisymmetric flow through the gap and onto the planet. The gap partitions the disk into an inner (outer) disk that extends inside (outside) the planet's orbit. For a 1 M_J planet and typical disk parameters, the accretion through the gap onto the planet is highly efficient. For typical disk parameters, the mass doubling time scale is less than 10^5 years, considerably shorter than the disk lifetime. Following shocks near the L1 and L2 Lagrange points, disk material enters the Roche lobe in the form of two gas streams. Shocks occur within the Roche lobe as the gas streams collide, and shocks lead to rapid inflow towards the planet within much of planet's Roche lobe. Shocks also propagate in the inner and outer disks that orbit the star. For higher mass planets (of order 6 M_J), the flow rate onto the planet is considerably reduced, which suggests an upper mass limit to planets in the range of 10 M_J. This rate reduction is related to the fact that the gap width increases relative to the Roche (Hill sphere) radius with increasing planetary mass. The flow in the gap affects planetary migration. For the 1 M_J planet case, mass can penetrate from the outer disk to the inner disk, so that the inner disk is not depleted. The results suggest that most of the mass in gas giant planets is acquired by flows through gaps.

S. H. Lubow; M. Seibert; P. Artymowicz

1999-10-21T23:59:59.000Z

359

2013 Fall : Highly Distinguished Honors Highly Distinguished  

E-Print Network [OSTI]

Anderson Chelsea Mariah Highly Distinguished Anderson Madison Olivia Highly Distinguished Andrews James Askew Mary Frances Highly Distinguished Augustine Andrew William Highly Distinguished Austin Adrian Bailes Mary Elizabeth Highly Distinguished Bailey Erika Leigh Highly Distinguished Bailey Margaret

Kasman, Alex

360

Composition for use in high-temperature hydrogen-fluorine environments and method for making the composition  

DOE Patents [OSTI]

The present invention relates to a composition particularly suitable for use as structural components subject to high-temperature environments containing gaseous hydrogen and fluorine. The composition of the present invention consists essentially of lanthanum hexaboride-molybdenum diboride with dispersed silicon. The composition is formed by hot pressing a powder mixture of lanthanum hexaboride as the major constituent and molybdenum disilicide. This composition exhibits substantial resistance to thermal shock and corrosion in environments containing hydrogen and fluorine gases at material surface temperatures up to about 1850/sup 0/K. Upon exposure of the hot-pressed composition to high-temperature environments containing fluorine gases, a highly protective layer of lanthanum trifluoride containing dispersed molybdenum is formed on exposed surfaces of the composition.

Kovach, L.; Holcombe, C.E.

1980-08-22T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

INDEPENDENT TECHNICAL REVIEW OF THE FOCUSED FEASIBILITY STUDY AND PROPOSED PLAN FOR DESIGNATED SOLID WASTE MANAGEMENT UNITS CONTRIBUTING TO THE SOUTHWEST GROUNDWATER PLUME AT THE PADUCAH GASEOUS DIFFUSION PLANT  

SciTech Connect (OSTI)

The U. S. Department of Energy (DOE) is currently developing a Proposed Plan (PP) for remediation of designated sources of chlorinated solvents that contribute contamination to the Southwest (SW) Groundwater Plume at the Paducah Gaseous Diffusion Plant (PGDP), in Paducah, KY. The principal contaminants in the SW Plume are trichloroethene (TCE) and other volatile organic compounds (VOCs); these industrial solvents were used and disposed in various facilities and locations at PGDP. In the SW plume area, residual TCE sources are primarily in the fine-grained sediments of the Upper Continental Recharge System (UCRS), a partially saturated zone that delivers contaminants downward into the coarse-grained Regional Gravel Aquifer (RGA). The RGA serves as the significant lateral groundwater transport pathway for the plume. In the SW Plume area, the four main contributing TCE source units are: (1) Solid Waste Management Unit (SWMU) 1 / Oil Landfarm; (2) C-720 Building TCE Northeast Spill Site (SWMU 211A); (3) C-720 Building TCE Southeast Spill Site (SWMU 211B); and (4) C-747 Contaminated Burial Yard (SWMU 4). The PP presents the Preferred Alternatives for remediation of VOCs in the UCRS at the Oil Landfarm and the C-720 Building spill sites. The basis for the PP is documented in a Focused Feasibility Study (FFS) (DOE, 2011) and a Site Investigation Report (SI) (DOE, 2007). The SW plume is currently within the boundaries of PGDP (i.e., does not extend off-site). Nonetheless, reasonable mitigation of the multiple contaminant sources contributing to the SW plume is one of the necessary components identified in the PGDP End State Vision (DOE, 2005). Because of the importance of the proposed actions DOE assembled an Independent Technical Review (ITR) team to provide input and assistance in finalizing the PP.

Looney, B.; Eddy-Dilek, C.; Amidon, M.; Rossabi, J.; Stewart, L.

2011-05-31T23:59:59.000Z

362

Temperature field reconstruction of combustion flame based on high  

E-Print Network [OSTI]

that sound propagates in a different medium with different speed, and its theo- retical cornerstone-known materials of solid, liquid, and gaseous states, flame is a kind of plasma1,2 of which temper- ature is one

363

Aging Studies of Large Area Proportional Chambers under High-Rate Irradiation with $CF_4$-based Mixtures (PART 1)  

E-Print Network [OSTI]

Experimental conditions at the HERA-B experiment impose very strong requirements for gaseous detectors. The charged particle fluxes through the HERA-B tracking system, varying with the radial distance $R$ from the beam line, are about $2 \\times 10^{7}/R^{2}$ particles per second, and comparable to those that will be encountered by LHC experiments. The severe radiation environment of the HERA-B experiment leads to a maximum charge deposit on a wire, within the muon detector, of 200 mC/cm per year. We report recent results of aging studies performed by irradiating proportional wire chambers filled with $Ar/CF_4/CH_4$ (74:20:6), $Ar/CF_4/CH_4$ (67:30:3), $Ar/CF_4/CO_2$ (65:30:5), $Ar/CF_4$ (70:30), $CF_4/CH_4$ (90:10), $CF_4/CH_4$ (80:20) mixtures in a three different experimental setups. The size of the irradiation zone varied in the tests from 1 cm up to 500 cm. Our experience shows that the aging rate depends not only on the total collected charge, but, in addition, on the mode of operation and area of irradiation. The possible application of these results to the construction of a large area gaseous detectors for operation in high rate environments is presented.

M. Danilov; Yu. Gilitsky; T. Kvaratschellia; L. Laptin; I. Tichomirov; M. Titov; Yu. Zaitsev

2001-11-23T23:59:59.000Z

364

Aging Studies of Large Area Proportional Chambers under High-Rate Irradiation with $CF_4$-based Mixtures (Part 2)  

E-Print Network [OSTI]

Experimental conditions at the HERA-B experiment impose very strong requirements for gaseous detectors. The charged particle fluxes through the HERA-B tracking system, varying with the radial distance R from the beam line, are about $2 \\times 10^{7}/R^{2}$ particles per second, and comparable to those that will be encountered by LHC experiments. The severe radiation environment of the HERA-B experiment leads to a maximum charge deposit on a wire, within the muon detector, of 200 mC/cm per year. We report recent results of aging studies performed by irradiating proportional wire chambers filled with $Ar/CF_4/CH_4$ (74:20:6), $Ar/CF_4/CH_4$ (67:30:3), $Ar/CF_4/CO_2$ (65:30:5), $Ar/CF_4$ (70:30), $CF_4/CH_4$ (90:10), $CF_4/CH_4$ (80:20) mixtures in a three different experimental setups. The size of the irradiation zone varied in the tests from 1 cm up to 500 cm. Our experience shows that the aging rate depends not only on the total collected charge, but, in addition, on the mode of operation and area of irradiation. The possible application of these results to the construction of a large area gaseous detectors for operation in high rate environments is presented.

M. Danilov; Yu. Gilitsky; T. Kvaratschellia; L. Laptin; I. Tichomirov; M. Titov; Yu. Zaitsev

2001-11-23T23:59:59.000Z

365

Vortex combustor for low NOX emissions when burning lean premixed high hydrogen content fuel  

DOE Patents [OSTI]

A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

Steele, Robert C; Edmonds, Ryan G; Williams, Joseph T; Baldwin, Stephen P

2012-11-20T23:59:59.000Z

366

Vortex combustor for low NOx emissions when burning lean premixed high hydrogen content fuel  

DOE Patents [OSTI]

A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

Steele, Robert C. (Woodinville, WA); Edmonds, Ryan G. (Renton, WA); Williams, Joseph T. (Kirkland, WA); Baldwin, Stephen P. (Winchester, MA)

2009-10-20T23:59:59.000Z

367

Process for CO.sub.2 capture using zeolites from high pressure and moderate temperature gas streams  

DOE Patents [OSTI]

A method for separating CO.sub.2 from a gas stream comprised of CO.sub.2 and other gaseous constituents using a zeolite sorbent in a swing-adsorption process, producing a high temperature CO.sub.2 stream at a higher CO.sub.2 pressure than the input gas stream. The method utilizes CO.sub.2 desorption in a CO.sub.2 atmosphere and effectively integrates heat transfers for optimizes overall efficiency. H.sub.2O adsorption does not preclude effective operation of the sorbent. The cycle may be incorporated in an IGCC for efficient pre-combustion CO.sub.2 capture. A particular application operates on shifted syngas at a temperature exceeding 200.degree. C. and produces a dry CO.sub.2 stream at low temperature and high CO.sub.2 pressure, greatly reducing any compression energy requirements which may be subsequently required.

Siriwardane, Ranjani V. (Morgantown, WV); Stevens, Robert W. (Morgantown, WV)

2012-03-06T23:59:59.000Z

368

Colorado School of Mines New Faculty 2014-2015  

E-Print Network [OSTI]

on fatigue crack growth prediction models of pipeline steels exposed to high pressure gaseous hydrogen. Dr

369

Separation of particles from gaseous fluid flows  

SciTech Connect (OSTI)

In a gas washer and similar separator devices which utilize stationary wall means to deflect a gas flow and to subject the same to centrifugal force for continuously separating out foreign particulate matter which is collected on or adjacent the stationary wall means, the invention provides spirally curved laminae constituting the stationary wall means and co-operating to define passage means, at least a part of which has a cross-section which first narrows and then widens in the direction of fluid flow and which is also curved spirally first in one and then in the opposite direction. Nozzle means may be arranged to feed moisture into the fluid flow to assist wet separation, and by electrically insulating conductive laminae from one another, the invention may also be used as an electrostatic precipitator.

Paul, E.; Reither, K.

1980-12-16T23:59:59.000Z

370

Oversight Reports - Portsmouth Gaseous Diffusion Plant | Department...  

Broader source: Energy.gov (indexed) [DOE]

Paducah Project Office - May 2012 Assessment of the PortsmouthPaducah Project Office Conduct of Operations Oversight of the Depleted Uranium Hexafluoride Conversion Plants...

371

Gaseous and particulate contamination in space  

E-Print Network [OSTI]

?w??effect on the NC'Ds is plotted for water at 300 km altitude in Fsgure 7. assuming that the observer is at the coordinates of (rpv, ? 0, rp, ? 1 m). YVhen the parameter Daway value is less than 0. 1 meter, the tangentsal or x-direction distance at which...

Yang, Xiaofang

1989-01-01T23:59:59.000Z

372

Gaseous Hydrogen Delivery Breakout - Strategic Directions for...  

Broader source: Energy.gov (indexed) [DOE]

System Issues: need to assess delivery options in context of total system Materials: corrosion, H2 permeability Construction: welding, joining Maintenance and Operation: leak...

373

The Gaseous Environment of Seyfert Galaxies  

E-Print Network [OSTI]

The VLA has been used to image HI in a heterogeneous sample of nine Seyferts as part of a continuing investigation of the role of galactic host gas in the triggering and fuelling of nuclear activity. Where previous single-dish observations indicated complex, poorly understood kinematics, improved angular resolution and sensitivity reveal tidal tails and intragroup gas, distinguish dwarfs from main disks and resolve non-linear gas dynamical features such as shocks in bars. Seyferts may be abnormally gas-rich, but a larger, statistically significant comparison of HI properties of normal and active galaxies is now required.

C. G. Mundell

2000-12-11T23:59:59.000Z

374

Gaseous Diffusion Plant Production Workers Needs Assessment  

Broader source: Energy.gov (indexed) [DOE]

about a variety of issues, including exposures, perceptions of risk, health concerns, health care, and receptivity to a health screening program The overall design recruitment...

375

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safety and Security (HSS), conducted an independent review of the U.S. Department of Energy (DOE) PortsmouthPaducah Project Office (PPPO). The objective of the Independent...

376

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...  

Broader source: Energy.gov (indexed) [DOE]

and Security (HSS), conducted a shadowing oversight activity of the U.S. Department of Energy (DOE) PortsmouthPaducah Project Office (PPPO) oversight of selected aspects of the...

377

Paducah Gaseous Diffusion Plant Deactivation Services Section...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Disease Prevention Program. d) Ensure adequate access to health programsambulatory care, and beryllium and radiation worker health surveillance programs. These services are...

378

Treatment of gaseous effluents at nuclear facilities  

SciTech Connect (OSTI)

Airborne effluents from nuclear facilities represent the major environmental impact from such plants both under routine conditions or after plant accidents. Effective control of such emissions, therefore, constitutes a major aspect of plant design for nuclear power plants and other facilities in the nuclear fuel cycle. This volume brings together a number of review articles by experts in the various areas of concern and describes some of the removal systems that have been designed for power plants and, particularly, for reprocessing plants. Besides controlling the release of radionuclides, other potentially hazardous effluents, such as nitrous oxides, must be minimized, and these are included in some of the systems described. The various chapters deal with historic developments and current technology in reducing emission of fission products, noble gases, iodine, and tritium, and consider design requirements for practical installations.

Goossen, W.R.A. [Studiecentrum voor Kernenergie, Mol (Belgium). Dept. of Chemical Engineering] [ed.; Eichholz, G.G.; Tedder, D.W. [eds.] [Georgia Institute of Technology, Atlanta, GA (United States)

1991-12-31T23:59:59.000Z

379

Gaseous Hydrogen Compression | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAX POLICIES7.pdfFuel Cell Vehicle BasicsWashers | DepartmentGabrialGamma-Ray»

380

Gaseous Hydrogen Delivery | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAX POLICIES7.pdfFuel Cell Vehicle BasicsWashers |

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant -  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietipDepartment ofTheDepartment of Energy 4EnergyNovember

382

Portsmouth Gaseous Diffusion Plant | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Careerlumens_placard-green.epsEnergy1.pdfMarket |21, 2015 7:00AM09

383

NGPL Production, Gaseous Equivalent at Processing Plants  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year2per ThousandWellhead+WellheadMr.NEMSNGPLNGPL

384

First gaseous boronization during pulsed discharge cleaning  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityField OfficeFirmFirst Proofgaseous boronization during

385

Safetygram Gaseous Hydrogen | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l LPROJECTS IN7 RoadmapProgram 2013:Safety

386

Gaseous Decomposition Products of Safety Powders  

E-Print Network [OSTI]

19.6 Volume o f a i r added 70.8 T o t a l vo lume 90 .4 Volume a f t e r e x p l o s i o n 74.4 C o n t r a c t i o n 16.0 R e s i d u e a f t e r a b s o r p t i o n o f c a r b o n d i o x i d e 68.8 74.4 6 8 . 8 = 5 .6 . Oxygen p r e s e... DECOMPOSITION PRODUCTS OF SAFETY POWDERS. THESIS SUBMITTED FOR THE DEGREE OF BACHELOR OF SCIENCE I I THE DEPARTMENT OF CHEMICAL BHGUEBRING AT THE UNIVERSITY OF KANSAS. BY C.E.CUBBISOH 1912. RD01D7 MaDSfl COHTEHTS. * * * * Pago * P r e f a c e 6...

Cubbison, C.E.

1912-01-01T23:59:59.000Z

387

High pressure low heat rate phosphoric acid fuel cell stack  

SciTech Connect (OSTI)

A high pressure phosphoric acid fuel cell stack assembly is described comprising: (a) a stack of fuel cells for producing electricity, the stack including cathode means, anode means, and heat exchange means; (b) means for delivering pressurized air to the cathode means; (c) means for delivering a hydrogen rich fuel gas to the anode means for electrochemically reacting with oxygen in the pressurized air to produce electricity and water; (d) first conduit means connected to the cathode means for exhausting a mixture of oxygen-depleted air and reaction water from the cathode means; (e) second conduit means connected to the first conduit means for delivering a water fog to the first conduit means for entrainment in the mixture of oxygen-depleted air and reaction water to form a two phase coolant having a gaseous air phase and an entrained water droplet phase; (f) means for circulating the coolant to the heat exchange means to cool the stack solely through vaporization of the water droplet phase in the heat exchange means whereby a mixed gas exhaust of air and water vapor is exhausted from the heat exchange means; and (g) means for heating the mixed gas exhaust and delivering the heated mixed gas exhaust at reformer reaction temperatures to an autothermal reformer in the stack assembly for autothermal reaction with a raw fuel to form the hydrogen rich fuel.

Wertheim, R.J.

1987-07-07T23:59:59.000Z

388

POPULATION III STARS AND REMNANTS IN HIGH-REDSHIFT GALAXIES  

SciTech Connect (OSTI)

Recent simulations of Population III star formation have suggested that some fraction form in binary systems, in addition to having a characteristic mass of tens of solar masses. The deaths of metal-free stars result in the initial chemical enrichment of the universe and the production of the first stellar-mass black holes. Here we present a cosmological adaptive mesh refinement simulation of an overdense region that forms a few 10{sup 9} M{sub Sun} dark matter halos and over 13,000 Population III stars by redshift 15. We find that most halos do not form Population III stars until they reach M{sub vir} {approx} 10{sup 7} M{sub Sun} because this biased region is quickly enriched from both Population III and galaxies, which also produce high levels of ultraviolet radiation that suppress H{sub 2} formation. Nevertheless, Population III stars continue to form, albeit in more massive halos, at a rate of {approx}10{sup -4} M{sub Sun} yr{sup -1} Mpc{sup -3} at redshift 15. The most massive starless halo has a mass of 7 Multiplication-Sign 10{sup 7} M{sub Sun }, which could host massive black hole formation through the direct gaseous collapse scenario. We show that the multiplicity of the Population III remnants grows with halo mass above 10{sup 8} M{sub Sun }, culminating in 50 remnants located in 10{sup 9} M{sub Sun} halos on average. This has implications that high-mass X-ray binaries and intermediate-mass black holes that originate from metal-free stars may be abundant in high-redshift galaxies.

Xu Hao; Norman, Michael L. [Center for Astrophysics and Space Sciences, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (United States); Wise, John H., E-mail: hxu@ucsd.edu, E-mail: mlnorman@ucsd.edu, E-mail: jwise@gatech.edu [Center for Relativistic Astrophysics, School of Physics, Georgia Institute of Technology, 837 State Street, Atlanta, GA 30332 (United States)

2013-08-20T23:59:59.000Z

389

PROOF OF CONCEPT TEST OF A UNIQUE GASEOUS PERFLUROCARBON TRACER SYSTEM FOR VERIFICATION AND LONG TERM MONITORING OF CAPS AND COVER SYSTEMS CONDUCTED AT THE SAVANNAH RIVER SITE BENTONITE MAT TEST FACILITY.  

SciTech Connect (OSTI)

Engineered covers have been placed on top of buried/subsurface wastes to minimize water infiltration and therefore, release of hazardous contaminants. In order for the cover to protect the environment it must remain free of holes and breaches throughout its service life. Covers are subject to subsidence, erosion, animal intrusion, plant root infiltration, etc., all of which will affect the overall performance of the cover. The U.S. Department of Energy Environmental Management (DOE-EM) Program 2006 Accelerated Cleanup Plan is pushing for rapid closure of many of the DOE facilities. This will require a great number of new cover systems. Some of these new covers are expected to maintain their performance for periods of up to 1000 years. Long-term stewardship will require monitoring/verification of cover performance over the course of the designed lifetime. In addition, many existing covers are approaching the end of their design life and will need validation of current performance (if continued use is desired) or replacement (if degraded). The need for a reliable method of verification and long-term monitoring is readily apparent. Currently, failure is detected through monitoring wells downstream of the waste site. This is too late as the contaminants have already left the disposal area. The proposed approach is the use of gaseous Perfluorocarbon tracers (PFT) to verify and monitor cover performance. It is believed that PFTs will provide a technology that can verify a cover meets all performance objectives upon installation, be capable of predicting changes in cover performance and failure (defined as contaminants leaving the site) before it happens, and be cost-effective in supporting stewardship needs. The PFTs are injected beneath the cover and air samples taken above (either air samples or soil gas samples) at the top of the cover. The location, concentrations, and time of arrival of the tracer(s) provide a direct measure of cover performance. PFT technology can be used as a non-invasive method (if injection ports are emplaced prior to cover emplacement) on new covers or a minimally invasive method on existing covers. PFT verification will be useful at all buried waste sites using a cover system (e.g., treated or untreated chemical waste landfills) including DOE, commercial, and private sector sites. This paper discusses the initial field trial of the PFT cover monitoring system performed at the Savannah River Site (SRS) in FY01. The experiments provided a successful proof-of-principle test of the PFT technology in monitoring caps and covers. An injection and sampling array was installed in the Bentomat test cap at the SRS Caps Test Facility. This system contained 6 feet of sandy soil beneath a 1/2 inch geosynthetic clay liner covered by an HDPE liner which was covered by 2 feet of clayey top soil. PFTs were injected into the sandy soil though a pre-existing system of access pipes below the cap and soil gas samples were taken on top of the cap. Mid-way into the injection period a series of 1 1/2 inch holes were punched into the cap (through the geomembrane) to provide a positive breach in the cap. Data will be presented that shows the initial cap was fairly tight and leak free and that the artificially induced leaks were detectable within two hours of occurrence.

HEISER,J.; SULLIVAN,T.; SERRATO,M.

2002-02-24T23:59:59.000Z

390

High Performance Computing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High Performance Computing High Performance Computing Providing world-class high performance computing capability that enables unsurpassed solutions to complex problems of...

391

High Temperatures & Electricity Demand  

E-Print Network [OSTI]

High Temperatures & Electricity Demand An Assessment of Supply Adequacy in California Trends.......................................................................................................1 HIGH TEMPERATURES AND ELECTRICITY DEMAND.....................................................................................................................7 SECTION I: HIGH TEMPERATURES AND ELECTRICITY DEMAND ..........................9 BACKGROUND

392

Standard practice for evaluation of disbonding of bimetallic stainless alloy/steel plate for use in high-pressure, high-temperature refinery hydrogen service  

E-Print Network [OSTI]

1.1 This practice covers a procedure for the evaluation of disbonding of bimetallic stainless alloy/steel plate for use in refinery high-pressure/high-temperature (HP/HT) gaseous hydrogen service. It includes procedures to (1) produce suitable laboratory test specimens, (2) obtain hydrogen charging conditions in the laboratory that are similar to those found in refinery HP/HT hydrogen gas service for evaluation of bimetallic specimens exposed to these environments, and (3) perform analysis of the test data. The purpose of this practice is to allow for comparison of data among test laboratories on the resistance of bimetallic stainless alloy/steels to hydrogen-induced disbonding (HID). 1.2 This practice applies primarily to bimetallic products fabricated by weld overlay of stainless alloy onto a steel substrate. Most of the information developed using this practice has been obtained for such materials. The procedures described herein, may also be appropriate for evaluation of hot roll bonded, explosive bonded...

American Society for Testing and Materials. Philadelphia

2001-01-01T23:59:59.000Z

393

172 Newark High School 83 Reynoldsburg High School  

E-Print Network [OSTI]

AU09 HS 172 Newark High School 83 Reynoldsburg High School 71 Heath High School 69 Granville High School 57 Licking Valley High School 54 Northridge High School 54 Watkins Memorial High Scho 51 Sheridan High School 50 Lincoln High School 49 Mount Vernon High School 46 Tri-valley High School 43 Utica High

Jones, Michelle

394

High-Tech Halloween  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High-Tech Halloween Catch an Event Events Happening Now Events Calendar High-Tech Halloween Lifelong Learning Mailing List 70th Events Lectures invisible utility element High-Tech...

395

The effect of hydrogen addition on flammability limit and NOx emission in ultra-lean counterflow  

E-Print Network [OSTI]

. They indicated that the addition of hydrogen to natural gas or methane resulted in an increase in NOx for most increases, and then decreases with the increase in the fraction of hydrogen. Overall, hydrogen enrichment rights reserved. Keywords: Hydrogen enrichment; NOx; Extinction limit; Ultra-lean premixed flame. 1

Gülder, ?mer L.

396

Duct System Flammability and Air Sealing Fire Separation Assemblies in the International Residential Code  

SciTech Connect (OSTI)

IBACOS identified two barriers that limit the ability of builders to cost-effectively achieve higher energy efficiency levels in housing. These are (1) the use of duct system materials that inherently achieve airtightness and are appropriately sized for low-load houses and (2) the ability to air seal fire separation assemblies. The issues identified fall into a gray area of the codes.

Rudd, A.; Prahl, D.

2014-12-01T23:59:59.000Z

397

Product: Corrosive liquids, flammable, n.o.s. [Tetrakis(ethylmethylamino)  

E-Print Network [OSTI]

: November 2005 Copyright © 2002, 2004-2005, Praxair Technology, Inc. Page 1 of 8 All rights reserved. A vertical line in the left margin indicates revised or new material. Praxair Experimental Product Material(ethylmethylamino)hafnium] (MSDS No. P-6283-C) Trade Names: Praxair® TEMAH Chemical Name: Tetrakis

Rubloff, Gary W.

398

WAPD-SC-545 HYDROGEN FLAMMABILITY DATA AND APPLICATION TO PWR  

Office of Scientific and Technical Information (OSTI)

and results of a major loss-of-coolant accident in RVR (the Shippingport Atomic Power Station). There it is shown that a zirconium-water (or steam) reaction is a possible...

399

Measurement of flammability in a closed cylindrical vessel with thermal criteria  

E-Print Network [OSTI]

experiments, but not with the results of counterflow apparatus experiments. The current results show that Le Chatelierâ??s rule describes the mixture results adequately. Minimum oxygen concentrations also were determined for methane, butane, and methane-butane...

Wong, Wun K.

2007-04-25T23:59:59.000Z

400

Thermal modeling of core sampling in flammable gas waste tanks. Part 2: Rotary-mode sampling  

SciTech Connect (OSTI)

The radioactive waste stored in underground storage tanks at Hanford site includes mixtures of sodium nitrate and sodium nitrite with organic compounds. The waste can produce undesired violent exothermic reactions when heated locally during the rotary-mode sampling. Experiments are performed varying the downward force at a maximum rotational speed of 55 rpm and minimum nitrogen purge flow of 30 scfm. The rotary drill bit teeth-face temperatures are measured. The waste is simulated with a low thermal conductivity hard material, pumice blocks. A torque meter is used to determine the energy provided to the drill string. The exhaust air-chip temperature as well as drill string and drill bit temperatures and other key operating parameters were recorded. A two-dimensional thermal model is developed. The safe operating conditions were determined for normal operating conditions. A downward force of 750 at 55 rpm and 30 scfm nitrogen purge flow was found to yield acceptable substrate temperatures. The model predicted experimental results reasonably well. Therefore, it could be used to simulate abnormal conditions to develop procedures for safe operations.

Unal, C.; Poston, D.; Pasamehmetoglu, K.O. [Los Alamos National Lab., NM (United States). Nuclear Systems Design and Analysis Group; Witwer, K.S. [Westinghouse Hanford Co., Richland, WA (United States). Engineering Testing Lab.

1997-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

An assessment of the flammability and explosion potential of transuranic waste  

SciTech Connect (OSTI)

The explosion potential of transuranic (TRU) waste, destined for the Waste Isolation Pilot (WIPP), was recently examined in EEG-45. That investigation focused on the volatile organic compounds (VOCs) in the waste, particularly acetone, and concluded that an explosion due to the VOCs was unlikely. Recent evidence raises serious concerns about drums containing mixed radioactive hazardous waste bound for the WIPP. Static electricity generated by the plastic bags represents a potential ignition source for other fuels, such as methane gas or hydrogen gas, during transportation and during the test phase. The potential danger of explosion due to hydrogen gas or methane gas generation has not yet been resolved. This report investigates that potential hazard and examines documented ignitions, fires, explosions and incidents of overpressurization of containers at generating and storage sites planning to send transuranic waste to the WIPP for disposal. 68 refs., 6 figs.

Silva, M.

1991-06-01T23:59:59.000Z

402

SciTech Connect: Duct System Flammability and Air Sealing Fire...  

Office of Scientific and Technical Information (OSTI)

air seal fire separation assemblies. The issues identified fall into a gray area of the codes. Authors: Rudd, A.; Prahl, D. Publication Date: 2014-12-01 OSTI Identifier: 1166650...

403

WAPD-SC-545 HYDROGEN FLAMMABILITY DATA AND APPLICATION TO PWR  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500IIVasudhaSurface. |VolunteeringMap2-5: EastW.W7WAPD-SC-545

404

High Temperature, High Pressure Devices for Zonal Isolation in...  

Broader source: Energy.gov (indexed) [DOE]

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature,...

405

High Performance Networks for High Impact Science  

SciTech Connect (OSTI)

This workshop was the first major activity in developing a strategic plan for high-performance networking in the Office of Science. Held August 13 through 15, 2002, it brought together a selection of end users, especially representing the emerging, high-visibility initiatives, and network visionaries to identify opportunities and begin defining the path forward.

Scott, Mary A.; Bair, Raymond A.

2003-02-13T23:59:59.000Z

406

Tall concrete buildings subject to vertically moving fires: A case study approach  

E-Print Network [OSTI]

regarded as safe in a fire situation as concrete is non-flammable and exhibits highly insulating material properties. The majority of current research relating to the impact of fire on structures examines other forms of construction. Research of concrete...

Fletcher, Ian A

407

Tribological behavior of near-frictionless carbon coatings in high- and low-sulfur diesel fuels.  

SciTech Connect (OSTI)

The sulfur content in diesel fuel has a significant effect on diesel engine emissions, which are currently subject to environmental regulations. It has been observed that engine particulate and gaseous emissions are directly proportional to fuel sulfur content. With the introduction of low-sulfur fuels, significant reductions in emissions are expected. The process of sulfur reduction in petroleum-based diesel fuels also reduces the lubricity of the fuel, resulting in premature failure of fuel injectors. Thus, another means of preventing injector failures is needed for engines operating with low-sulfur diesel fuels. In this study, the authors evaluated a near-frictionless carbon (NFC) coating (developed at Argonne National Laboratory) as a possible solution to the problems associated with fuel injector failures in low-lubricity fuels. Tribological tests were conducted with NFC-coated and uncoated H13 and 52100 steels lubricated with high- and low- sulfur diesel fuels in a high-frequency reciprocating test machine. The test results showed that the NFC coatings reduced wear rates by a factor of 10 over those of uncoated steel surfaces. In low-sulfur diesel fuel, the reduction in wear rate was even greater (i.e., by a factor of 12 compared to that of uncoated test pairs), indicating that the NFC coating holds promise as a potential solution to wear problems associated with the use of low-lubricity diesel fuels.

Alzoubi, M. F.; Ajayi, O. O.; Eryilmaz, O. L.; Ozturk, O.; Erdemir, A.; Fenske, G.

2000-01-19T23:59:59.000Z

408

High pressure, high current, low inductance, high reliability sealed terminals  

DOE Patents [OSTI]

The invention is a terminal assembly having a casing with at least one delivery tapered-cone conductor and at least one return tapered-cone conductor routed there-through. The delivery and return tapered-cone conductors are electrically isolated from each other and positioned in the annuluses of ordered concentric cones at an off-normal angle. The tapered cone conductor service can be AC phase conductors and DC link conductors. The center core has at least one service conduit of gate signal leads, diagnostic signal wires, and refrigerant tubing routed there-through. A seal material is in direct contact with the casing inner surface, the tapered-cone conductors, and the service conduits thereby hermetically filling the interstitial space in the casing interior core and center core. The assembly provides simultaneous high-current, high-pressure, low-inductance, and high-reliability service.

Hsu, John S. (Oak Ridge, TN) [Oak Ridge, TN; McKeever, John W. (Oak Ridge, TN) [Oak Ridge, TN

2010-03-23T23:59:59.000Z

409

High voltage fault current limiter having immersed phase coils  

DOE Patents [OSTI]

A fault current limiter including: a ferromagnetic circuit formed from a ferromagnetic material and including at least a first limb, and a second limb; a saturation mechanism surrounding a limb for magnetically saturating the ferromagnetic material; a phase coil wound around a second limb; a dielectric fluid surrounding the phase coil; a gaseous atmosphere surrounding the saturation mechanism.

Darmann, Francis Anthony

2014-04-22T23:59:59.000Z

410

High Voltage Safety Act  

Broader source: Energy.gov [DOE]

The purpose of the High Voltage Safety Act is to prevent injury to persons and property and interruptions of utility service resulting from accidental or inadvertent contact with high-voltage...

411

Large-dimension, high-ZT Thermoelectric Nanocomposites for High...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Large-dimension, high-ZT Thermoelectric Nanocomposites for High-Power High-efficiency Waste Heat Recovery for Electricity Generation Large-dimension, high-ZT Thermoelectric...

412

Energy Storage Testing and Analysis High Power and High Energy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Testing and Analysis High Power and High Energy Development Energy Storage Testing and Analysis High Power and High Energy Development 2009 DOE Hydrogen Program and Vehicle...

413

High power microwave generator  

DOE Patents [OSTI]

A microwave generator efficiently converts the energy of an intense relativistic electron beam (REB) into a high-power microwave emission using the Smith-Purcell effect which is related to Cerenkov radiation. Feedback for efficient beam bunching and high gain is obtained by placing a cylindrical Smith-Purcell transmission grating on the axis of a toroidal resonator. High efficiency results from the use of a thin cold annular highly-magnetized REB that is closely coupled to the resonant structure.

Ekdahl, C.A.

1983-12-29T23:59:59.000Z

414

High Energy Physics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Basic Energy Science Biological and Environmental Research Fusion Energy Sciences High Energy Physics Nuclear Physics Advanced Scientific Computing Research Pioneering...

415

High energy astrophysical processes  

E-Print Network [OSTI]

We briefly review the high energy astrophysical processes that are related to the production of high energy $\\gamma$-ray and neutrino signals and are likely to be important for the energy loss of high and ultrahigh energy cosmic rays. We also give examples for neutrino fluxes generated by different astrophysical objects and describe the cosmological link provided by cosmogenic neutrinos.

Todor Stanev

2005-04-18T23:59:59.000Z

416

High performance systems  

SciTech Connect (OSTI)

This document provides a written compilation of the presentations and viewgraphs from the 1994 Conference on High Speed Computing given at the High Speed Computing Conference, {open_quotes}High Performance Systems,{close_quotes} held at Gleneden Beach, Oregon, on April 18 through 21, 1994.

Vigil, M.B. [comp.

1995-03-01T23:59:59.000Z

417

High Performance Computing in  

E-Print Network [OSTI]

High Performance Computing in Bioinformatics Thomas Ludwig (t.ludwig@computer.org) Ruprecht PART I: High Performance Computing Thomas Ludwig PART II: HPC Computing in Bioinformatics Alexandros #12;© Thomas Ludwig, Alexandros Stamatakis, GCB'04 3 PART I High Performance Computing Introduction

Stamatakis, Alexandros

418

High power, high beam quality regenerative amplifier  

DOE Patents [OSTI]

A regenerative laser amplifier system generates high peak power and high energy per pulse output beams enabling generation of X-rays used in X-ray lithography for manufacturing integrated circuits. The laser amplifier includes a ring shaped optical path with a limited number of components including a polarizer, a passive 90 degree phase rotator, a plurality of mirrors, a relay telescope, and a gain medium, the components being placed close to the image plane of the relay telescope to reduce diffraction or phase perturbations in order to limit high peak intensity spiking. In the ring, the beam makes two passes through the gain medium for each transit of the optical path to increase the amplifier gain to loss ratio. A beam input into the ring makes two passes around the ring, is diverted into an SBS phase conjugator and proceeds out of the SBS phase conjugator back through the ring in an equal but opposite direction for two passes, further reducing phase perturbations. A master oscillator inputs the beam through an isolation cell (Faraday or Pockels) which transmits the beam into the ring without polarization rotation. The isolation cell rotates polarization only in beams proceeding out of the ring to direct the beams out of the amplifier. The diffraction limited quality of the input beam is preserved in the amplifier so that a high power output beam having nearly the same diffraction limited quality is produced.

Hackel, L.A.; Dane, C.B.

1993-08-24T23:59:59.000Z

419

High power, high beam quality regenerative amplifier  

DOE Patents [OSTI]

A regenerative laser amplifier system generates high peak power and high energy per pulse output beams enabling generation of X-rays used in X-ray lithography for manufacturing integrated circuits. The laser amplifier includes a ring shaped optical path with a limited number of components including a polarizer, a passive 90 degree phase rotator, a plurality of mirrors, a relay telescope, and a gain medium, the components being placed close to the image plane of the relay telescope to reduce diffraction or phase perturbations in order to limit high peak intensity spiking. In the ring, the beam makes two passes through the gain medium for each transit of the optical path to increase the amplifier gain to loss ratio. A beam input into the ring makes two passes around the ring, is diverted into an SBS phase conjugator and proceeds out of the SBS phase conjugator back through the ring in an equal but opposite direction for two passes, further reducing phase perturbations. A master oscillator inputs the beam through an isolation cell (Faraday or Pockels) which transmits the beam into the ring without polarization rotation. The isolation cell rotates polarization only in beams proceeding out of the ring to direct the beams out of the amplifier. The diffraction limited quality of the input beam is preserved in the amplifier so that a high power output beam having nearly the same diffraction limited quality is produced.

Hackel, Lloyd A. (Livermore, CA); Dane, Clifford B. (Livermore, CA)

1993-01-01T23:59:59.000Z

420

High-bandwidth Modulation of H2/Syngas Fuel to Control Combustion Dynamics in Micro-Mixing Lean Premix Systems  

SciTech Connect (OSTI)

The goal of this program was to develop and demonstrate fuel injection technologies that will facilitate the development of cost-effective turbine engines for Integrated Gasification Combined Cycle (IGCC) power plants, while improving efficiency and reducing emissions. The program involved developing a next-generation multi-point injector with enhanced stability performance for lean premix turbine systems that burn hydrogen (H2) or synthesis gas (syngas) fuels. A previously developed injector that demonstrated superior emissions performance was improved to enhance static flame stability through zone staging and pilot sheltering. In addition, piezo valve technology was implemented to investigate the potential for enhanced dynamic stability through high-bandwidth modulation of the fuel supply. Prototype injector and valve hardware were tested in an atmospheric combustion facility. The program was successful in meeting its objectives. Specifically, the following was accomplished: Demonstrated improvement of lean operability of the Parker multi-point injector through staging of fuel flow and primary zone sheltering; Developed a piezo valve capable of proportional and high-bandwidth modulation of gaseous fuel flow at frequencies as high as 500 Hz; The valve was shown to be capable of effecting changes to flame dynamics, heat release, and acoustic signature of an atmospheric combustor. The latter achievement indicates the viability of the Parker piezo valve technology for use in future adaptively controlled systems for the mitigation of combustion instabilities, particularly for attenuating combustion dynamics under ultra-lean conditions.

Jeff Melzak; Tim Lieuwen; Adel Mansour

2012-01-31T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Development of hollow fiber catalytic membrane reactors for high temperature gas cleanup. Final report, September 1989--March 1994  

SciTech Connect (OSTI)

The objective of this project was to develop economically and technically viable catalytic membrane reactors for high temperature, high pressure gaseous contaminant control in Integrated Gasification Combined Cycle (IGCC) systems. These catalytic membrane reactors decompose H{sub 2}S and separate the reaction products. The reactors were designed to operate in the hostile process environment of the IGCC systems, and at temperatures ranging from 500 to 1000{degrees}C. Severe conditions encountered in the IGCC process (e.g., 900{degrees}C, containing of H{sub 2}S, CO{sub 2} and H{sub 2}O) make it impossible to use polymeric membranes in the process. A list of inorganic membranes that can be employed in the membrane reactor includes Pd metallic membranes, molecular-sieve glass membranes (PPG Industries), porous Vycor glass membranes and porous sol-gel derived membranes such as alumina, zirconia. Alumina and zirconia membranes, however, cannot withstand for a long time at high temperatures in the presence of water vapors. Palladium membranes are a very promising class of inorganic membranes for gas separations that is currently under development. In this project two different types of membranes were used in the design of the membrane reactor -- molecular-sieve glass membrane and Vycor glass porous membrane.

Ma, Yi Hua; Moser, W.R.; Pien, S.; Shelekhin, A.B.

1994-07-01T23:59:59.000Z

422

Method of fabricating free-form, high-aspect ratio components for high-current, high-speed microelectrics  

DOE Patents [OSTI]

Microelectronic structures and devices, and method of fabricating a three-dimensional microelectronic structure is provided, comprising passing a first precursor material for a selected three-dimensional microelectronic structure into a reaction chamber at temperatures sufficient to maintain said precursor material in a predominantly gaseous state; maintaining said reaction chamber under sufficient pressures to enhance formation of a first portion of said three-dimensional microelectronic structure; applying an electric field between an electrode and said microelectronic structure at a desired point under conditions whereat said first portion of a selected three-dimensional microelectronic structure is formed from said first precursor material; positionally adjusting either said formed three-dimensional microelectronic structure or said electrode whereby further controlled growth of said three-dimensional microelectronic structure occurs; passing a second precursor material for a selected three-dimensional microelectronic structure into a reaction chamber at temperatures sufficient to maintain said precursor material in a predominantly gaseous state; maintaining said reaction chamber under sufficient pressures whereby a second portion of said three-dimensional microelectronic structure formation is enhanced; applying an electric field between an electrode and said microelectronic structure at a desired point under conditions whereat said second portion of a selected three-dimensional microelectronic structure is formed from said second precursor material; and, positionally adjusting either said formed three-dimensional microelectronic structure or said electrode whereby further controlled growth of said three-dimensional microelectronic structure occurs.

Maxwell, James L; Rose, Chris R; Black, Marcie R; Springer, Robert W

2014-03-11T23:59:59.000Z

423

PORTSMOUTH ON-SITE DISPOSAL CELL HIGH DENSITY POLYETHYLENE GEOMEMBRANE LONGEVITY  

SciTech Connect (OSTI)

It is anticipated that high density polyethylene (HDPE) geomembranes will be utilized within the liner and closure cap of the proposed On-Site Disposal Cell (OSDC) at the Portsmouth Gaseous Diffusion Plant. The likely longevity (i.e. service life) of HDPE geomembranes in OSDC service is evaluated within the following sections of this report: (1) Section 2.0 provides an overview of HDPE geomembranes, (2) Section 3.0 outlines potential HDPE geomembranes degradation mechanisms, (3) Section 4.0 evaluates the applicability of HDPE geomembrane degradation mechanisms to the Portsmouth OSDC, (4) Section 5.0 provides a discussion of the current state of knowledge relative to the longevity (service life) of HDPE geomembranes, including the relation of this knowledge to the Portsmouth OSDC, and (5) Section 6.0 provides summary and conclusions relative to the anticipated service life of HDPE geomembranes in OSDC service. Based upon this evaluation it is anticipated that the service life of HDPE geomembranes in OSDC service would be significantly greater than the 200 year service life assumed for the OSDC closure cap and liner HDPE geomembranes. That is, a 200 year OSDC HDPE geomembrane service life is considered a conservative assumption.

Phifer, M.

2012-01-31T23:59:59.000Z

424

High-Resolution Desorption Electrospray Ionization Mass Spectrometry for Chemical Characterization of Organic Aerosols  

SciTech Connect (OSTI)

Characterization of the chemical composition and chemical transformations of secondary organic aerosol (SOA) is both a major challenge and the area of greatest uncertainty in current aerosol research. This study presents the first application of desorption electrospray ionization combined with high-resolution mass spectrometry (DESI-MS) for detailed chemical characterization and studies of chemical aging of OA collected on Teflon substrates. DESI-MS offers unique advantages both for detailed characterization of chemically labile components in OA that cannot be detected using more traditional electrospray ionization mass spectrometry (ESI-MS) and for studying chemical aging of OA. DESI-MS enables rapid characterization of OA samples collected on substrates by eliminating the sample preparation stage. In addition, it enables detection and structural characterization of chemically labile molecules in OA samples by minimizing the residence time of analyte in the solvent. SOA produced by the ozonolysis of limonene (LSOA) was allowed to react with gaseous ammonia. Chemical aging resulted in measurable changes in the optical properties of LSOA observed using UV- visible spectroscopy. DESI-MS combined with tandem mass spectrometry experiments (MS/MS) enabled identification of species in aged LSOA responsible for absorption of the visible light. Detailed analysis of the experimental data allowed us to identify chemical changes induced by reactions of LSOA constituents with ammonia and distinguish between different mechanisms of chemical aging.

Laskin, Julia; Laskin, Alexander; Roach, Patrick J.; Slysz, Gordon W.; Anderson, Gordon A.; Nizkorodov, Serguei; Bones, David L.; Nguyen, Lucas

2010-03-01T23:59:59.000Z

425

High output lamp with high brightness  

DOE Patents [OSTI]

An ultra bright, low wattage inductively coupled electrodeless aperture lamp is powered by a solid state RF source in the range of several tens to several hundreds of watts at various frequencies in the range of 400 to 900 MHz. Numerous novel lamp circuits and components are disclosed including a wedding ring shaped coil having one axial and one radial lead, a high accuracy capacitor stack, a high thermal conductivity aperture cup and various other aperture bulb configurations, a coaxial capacitor arrangement, and an integrated coil and capacitor assembly. Numerous novel RF circuits are also disclosed including a high power oscillator circuit with reduced complexity resonant pole configuration, parallel RF power FET transistors with soft gate switching, a continuously variable frequency tuning circuit, a six port directional coupler, an impedance switching RF source, and an RF source with controlled frequency-load characteristics. Numerous novel RF control methods are disclosed including controlled adjustment of the operating frequency to find a resonant frequency and reduce reflected RF power, controlled switching of an impedance switched lamp system, active power control and active gate bias control.

Kirkpatrick, Douglas A. (Great Falls, VA); Bass, Gary K. (Mt. Airy, MD); Copsey, Jesse F. (Germantown, MD); Garber, Jr., William E. (Poolesville, MD); Kwong, Vincent H. (Vancouver, CA); Levin, Izrail (Silver Spring, MD); MacLennan, Donald A. (Gaithersburg, MD); Roy, Robert J. (Frederick, MD); Steiner, Paul E. (Olney, MD); Tsai, Peter (Olney, MD); Turner, Brian P. (Damascus, MD)

2002-01-01T23:59:59.000Z

426

Commissioning for High Performance  

E-Print Network [OSTI]

, including energy efficiency, durability, life-cycle performance, and occupant productivity ASHRAE Guideline 32 - Sustainable High-Performance Operations and Maintenance A high-performance building consistently delivers a highly productive environment... plumbing fixtures Renewable energy sources such as photovoltaic (PV) systems Building envelope: Design reviews and field testing Indoor Air Quality (IAQ): Ventilation that meets or exceeds ASHRAE 62.1 Natural lighting & light pollution System...

Meline, K.

2013-01-01T23:59:59.000Z

427

High Performance New Construction  

E-Print Network [OSTI]

Funding for Efficient New Buildings through Integrated Project Delivery and High Performance Design-Build Case Study Rolling Plains New Medical Office Building Michael Flores McKinstry mflores@mckinstry.com 469-789-9920 1 ESL-KT-13-12-40 CATEE..., San Antonio, Texas Dec. 16-18 Objectives Explain how High Performance Design Build / Integrated Project Delivery (HPDB/IPD) differs from alternative project delivery methods (and why it is usually better!) Identify the key participants in High...

Flores, M.

2013-01-01T23:59:59.000Z

428

High Energy Physics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Large Scale Production Computing and Storage Requirements for High Energy Physics: Target 2017 HEPlogo.jpg The NERSC Program Requirements Review "Large Scale Computing and Storage...

429

.NET High Performance Computing.  

E-Print Network [OSTI]

?? Graphics Processing Units (GPUs) have been extensively applied in the High Performance Computing (HPC) community. HPC applications require additional special programming environments to improve (more)

Ou, Hsuan-Hsiu

2012-01-01T23:59:59.000Z

430

An Equilibrium-Based Model of Gas Reaction and Detonation  

SciTech Connect (OSTI)

During gaseous diffusion plant operations, conditions leading to the formation of flammable gas mixtures may occasionally arise. Currently, these could consist of the evaporative coolant CFC-114 and fluorinating agents such as F2 and ClF3. Replacement of CFC-114 with a non-ozone-depleting substitute is planned. Consequently, in the future, the substitute coolant must also be considered as a potential fuel in flammable gas mixtures. Two questions of practical interest arise: (1) can a particular mixture sustain and propagate a flame if ignited, and (2) what is the maximum pressure that can be generated by the burning (and possibly exploding) gas mixture, should it ignite? Experimental data on these systems, particularly for the newer coolant candidates, are limited. To assist in answering these questions, a mathematical model was developed to serve as a tool for predicting the potential detonation pressures and for estimating the composition limits of flammability for these systems based on empirical correlations between gas mixture thermodynamics and flammability for known systems. The present model uses the thermodynamic equilibrium to determine the reaction endpoint of a reactive gas mixture and uses detonation theory to estimate an upper bound to the pressure that could be generated upon ignition. The model described and documented in this report is an extended version of related models developed in 1992 and 1999.

Trowbridge, L.D.

2000-04-01T23:59:59.000Z

431

High coking value pitch  

SciTech Connect (OSTI)

A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

2014-06-10T23:59:59.000Z

432

High-Throughput, High-Precision Hot Testing Tool for High-Brightness...  

Energy Savers [EERE]

Throughput, High-Precision Hot Testing Tool for High-Brightness Light-Emitting Diode Testing High-Throughput, High-Precision Hot Testing Tool for High-Brightness Light-Emitting...

433

High Reliability, High TemperatureThermoelectric Power Generation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies High Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies...

434

High Temperature, High Pressure Devices for Zonal Isolation in...  

Broader source: Energy.gov (indexed) [DOE]

Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells DOE Geothermal Peer...

435

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum)). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 19 figures.

Morris, D.E.

1993-09-14T23:59:59.000Z

436

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

437

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

438

High-Current Accelerators  

E-Print Network [OSTI]

F i g . 13 F i g . 14 A 48 ACCELERATOR F i g . 25 F i g . 16supply. Extrapolation of accelerator energy and current9 . A-48 high-current accelerator, low-velocity end. Fig.

Lawrence, Ernest O.

1955-01-01T23:59:59.000Z

439

High Performance Computing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

view objects and processes in 3D. 13:01 Gary Grider, HPC Divison Leader The High Performance Computing (HPC) Division supports the Laboratory mission by managing world-class...

440

High pressure counterflow CHF.  

E-Print Network [OSTI]

This is a report of the experimental results of a program in countercurrent flow critical heat flux. These experiments were performed with Freon 113 at 200 psia in order to model a high pressure water system. An internally ...

Walkush, Joseph Patrick

1975-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly flammable gaseous" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

High-Temperature Superconductivity  

ScienceCinema (OSTI)

Like astronomers tweaking images to gain a more detailed glimpse of distant stars, physicists at Brookhaven National Laboratory have found ways to sharpen images of the energy spectra in high-temperature superconductors ? materials that carry electrical c

Peter Johnson

2010-01-08T23:59:59.000Z

442

High Performance Sustainable Building  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

This Guide provides approaches for implementing the High Performance Sustainable Building (HPSB) requirements of DOE Order 413.3B, Program and Project Management for the Acquisition of Capital Assets. Cancels DOE G 413.3-6.

2011-11-09T23:59:59.000Z

443

Creating high performance enterprises  

E-Print Network [OSTI]

How do enterprises successfully conceive, design, deliver, and operate large-scale, engineered systems? These large-scale projects often involve high complexity, significant technical challenges, a large number of diverse ...

Stanke, Alexis K. (Alexis Kristen), 1977-

2006-01-01T23:59:59.000Z

444

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1993-01-01T23:59:59.000Z

445

High conductivity composite metal  

DOE Patents [OSTI]

Electrical conductors and methods of producing them are disclosed, where the conductors possess both high strength and high conductivity. Conductors are comprised of carbon steel and a material chosen from a group consisting of copper, nickel, silver, and gold. Diffusion barriers are placed between these two materials. The components of a conductor are assembled and then the assembly is subjected to heat treating and mechanical deformation steps. 10 figs.

Zhou, R.; Smith, J.L.; Embury, J.D.

1998-01-06T23:59:59.000Z

446

High conductivity composite metal  

DOE Patents [OSTI]

Electrical conductors and methods of producing them, where the conductors possess both high strength and high conductivity. Conductors are comprised of carbon steel and a material chosen from a group consisting of copper, nickel, silver, and gold. Diffusion barriers are placed between these two materials. The components of a conductor are assembled and then the assembly is subjected to heat treating and mechanical deformation steps.

Zhou, Ruoyi (Los Alamos, NM); Smith, James L. (Los Alamos, NM); Embury, John David (Hamilton, CA)

1998-01-01T23:59:59.000Z

447

High temperature pressure gauge  

DOE Patents [OSTI]

A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

1981-01-01T23:59:59.000Z

448

High efficiency incandescent lighting  

DOE Patents [OSTI]

Incandescent lighting structure. The structure includes a thermal emitter that can, but does not have to, include a first photonic crystal on its surface to tailor thermal emission coupled to, in a high-view-factor geometry, a second photonic filter selected to reflect infrared radiation back to the emitter while passing visible light. This structure is highly efficient as compared to standard incandescent light bulbs.

Bermel, Peter; Ilic, Ognjen; Chan, Walker R.; Musabeyoglu, Ahmet; Cukierman, Aviv Ruben; Harradon, Michael Robert; Celanovic, Ivan; Soljacic, Marin

2014-09-02T23:59:59.000Z

449

High performance polymeric foams  

SciTech Connect (OSTI)

The aim of this work was to investigate the foamability of high-performance polymers (polyethersulfone, polyphenylsulfone, polyetherimide and polyethylenenaphtalate). Two different methods have been used to prepare the foam samples: high temperature expansion and two-stage batch process. The effects of processing parameters (saturation time and pressure, foaming temperature) on the densities and microcellular structures of these foams were analyzed by using scanning electron microscopy.

Gargiulo, M.; Sorrentino, L. [Institute for Composite and Biomedical Materials (IMCB)-CNR, P.le Tecchio 80, 80125 Naples (Italy); Iannace, S. [Institute for Composite and Biomedical Materials (IMCB)-CNR, P.le Tecchio 80, 80125 Naples (Italy) and Technological District on Polymeric and Composite Materials Engineering and Structures (IMAST), P.le E.Fermi 1, location Porto del Granatello, 80055 Portici (Naples)

2008-08-28T23:59:59.000Z

450

High Efficiency, High Performance Clothes Dryer  

SciTech Connect (OSTI)

This program covered the development of two separate products; an electric heat pump clothes dryer and a modulating gas dryer. These development efforts were independent of one another and are presented in this report in two separate volumes. Volume 1 details the Heat Pump Dryer Development while Volume 2 details the Modulating Gas Dryer Development. In both product development efforts, the intent was to develop high efficiency, high performance designs that would be attractive to US consumers. Working with Whirlpool Corporation as our commercial partner, TIAX applied this approach of satisfying consumer needs throughout the Product Development Process for both dryer designs. Heat pump clothes dryers have been in existence for years, especially in Europe, but have not been able to penetrate the market. This has been especially true in the US market where no volume production heat pump dryers are available. The issue has typically been around two key areas: cost and performance. Cost is a given in that a heat pump clothes dryer has numerous additional components associated with it. While heat pump dryers have been able to achieve significant energy savings compared to standard electric resistance dryers (over 50% in some cases), designs to date have been hampered by excessively long dry times, a major market driver in the US. The development work done on the heat pump dryer over the course of this program led to a demonstration dryer that delivered the following performance characteristics: (1) 40-50% energy savings on large loads with 35 F lower fabric temperatures and similar dry times; (2) 10-30 F reduction in fabric temperature for delicate loads with up to 50% energy savings and 30-40% time savings; (3) Improved fabric temperature uniformity; and (4) Robust performance across a range of vent restrictions. For the gas dryer development, the concept developed was one of modulating the gas flow to the dryer throughout the dry cycle. Through heat modulation in a gas dryer, significant time and energy savings, combined with dramatically reduced fabric temperatures, was achieved in a cost-effective manner. The key design factor lay in developing a system that matches the heat input to the dryer with the fabrics ability to absorb it. The development work done on the modulating gas dryer over the course of this program led to a demonstration dryer that delivered the following performance characteristics: (1) Up to 25% reduction in energy consumption for small and medium loads; (2) Up to 35% time savings for large loads with 10-15% energy reduction and no adverse effect on cloth temperatures; (3) Reduced fabric temperatures, dry times and 18% energy reduction for delicate loads; and, (4) Robust performance across a range of vent restrictions.

Peter Pescatore; Phil Carbone

2005-03-31T23:59:59.000Z

451

High surface area, high permeability carbon monoliths  

SciTech Connect (OSTI)

The goal of this work is to prepare carbon monoliths having precisely tailored pore size distribution. Prior studies have demonstrated that poly(acrylonitrile) can be processed into a precursor having tailored macropore structure. Since the macropores were preserved during pyrolysis, this synthetic process provided a route to porous carbon having macropores with size =0.1 to 10{mu}m. No micropores of size <2 nm could be detected in the carbon, however, by nitrogen adsorption. In the present work, the authors have processed a different polymer, poly(vinylidene chloride) into a macroporous precursor, Pyrolysis produced carbon monoliths having macropores derived from the polymer precursor as well as extensive microporosity produced during the pyrolysis of the polymer. One of these carbons had BET surface area of 1,050 m{sup 2}/g and about 1.2 cc/g total pore volume, with about 1/3 of the total pore volume in micropores and the remainder in 1{mu}m macropores. No mesopores in the intermediate size range could be detected by nitrogen adsorption. Carbon materials having high surface area as well as micron size pores have potential applications as electrodes for double layer supercapacitors containing liquid electrolyte, or as efficient media for performing chemical separations.