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1

Materials - Efficient catalysts... | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials - Efficient catalysts... Reduction of pollution from vehicles and power plants relies, in large part, on how effectively catalysts can oxidize nitric oxide (NO)....

2

High Impact Technology Catalyst | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

energy-efficient commercial building technologies. Through the High Impact Technology Catalyst program, initiated in 2014, the U.S. Department of Energy (DOE) identifies...

3

The generation of efficient supported (Heterogeneous) olefin metathesis catalysts  

SciTech Connect (OSTI)

Over the past decade, a new family of homogeneous metathesis catalysts has been developed that will tolerate most organic functionalities as well as water and air. These homogeneous catalysts are finding numerous applications in the pharmaceutical industry as well as in the production of functional polymers. In addition the catalysts are being used to convert seed oils into products that can substitute for those that are now made from petroleum products. Seed oils are unsaturated, contain double bonds, and are a ready source of linear hydrocarbon fragments that are specifically functionalized. To increase the number of applications in the area of biomaterial conversion to petrol chemicals, the activity and efficiency of the catalysts need to be as high as possible. The higher the efficiency of the catalysts, the lower the cost of the conversion and a larger number of practical applications become available. Active supported catalysts were prepared and tested in the conversion of seed oils and other important starting materials. The outcome of the work was successful and the technology has been transferred to a commercial operation to develop viable applications of the discovered systems. A biorefinery that converts seed oils is under construction in Indonesia. The catalysts developed in this study will be considered for the next generation of operations.

Grubbs, Robert H

2013-04-05T23:59:59.000Z

4

Catalyst for Improving the Combustion Efficiency of Petroleum...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines Catalyst for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines 2005 Diesel...

5

Steam reforming utilizing high activity catalyst  

SciTech Connect (OSTI)

High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

Setzer, H. J.

1985-03-05T23:59:59.000Z

6

Reversible chemisorption on highly dispersed Ru catalysts  

SciTech Connect (OSTI)

Hydrogen and carbon monoxide adsorptions have been studied by static gas volumetric measurement on a range of highly dispersed Y-zeolite-supported ruthenium catalysts prepared by ion exchange. At ambient temperature, the absorption isotherms indicated two distinct types of adsorption - reversible (composed of both physisorption and weak chemisorption) and irreversible (strongly chemisorbed). The catalysts were highly dispersed and had average particle diameters ranging from 0.9 to 1.6 nm. Reversible hydrogen chemisorption was found to be a function of average particle diameter and dispersion. On the other hand, reversible carbon monoxide chemisorption seemed to be mainly due to interaction with the support.

Yang, C.H.; Goodwin, J.G. Jr.

1982-11-01T23:59:59.000Z

7

High Impact Technology (HIT) Catalyst  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many| Department of4 Energy SolutionsHigh

8

Highly Dispersed Alloy Catalyst for Durability  

SciTech Connect (OSTI)

Achieving DOE�¢����s stated 5000-hr durability goal for light-duty vehicles by 2015 will require MEAs with characteristics that are beyond the current state of the art. Significant effort was placed on developing advanced durable cathode catalysts to arrive at the best possible electrode for high performance and durability, as well as developing manufacturing processes that yield significant cost benefit. Accordingly, the overall goal of this project was to develop and construct advanced MEAs that will improve performance and durability while reducing the cost of PEMFC stacks. The project, led by UTC Power, focused on developing new catalysts/supports and integrating them with existing materials (membranes and gas diffusion layers (GDLs)) using state-of-the-art fabrication methods capable of meeting the durability requirements essential for automotive applications. Specifically, the project work aimed to lower platinum group metals (PGM) loading while increasing performance and durability. Appropriate catalysts and MEA configuration were down-selected that protects the membrane, and the layers were tailored to optimize the movements of reactants and product water through the cell to maximize performance while maintaining durability.

Vivek S. Murthi (Primary Contact), Elise Izzo, Wu Bi, Sandra Guerrero and Lesia Protsailo

2013-01-08T23:59:59.000Z

9

Nanostructured Cobalt Oxide Clusters in Mesoporous Silica as Efficient Oxygen-Evolving Catalysts  

SciTech Connect (OSTI)

The development of integrated artificial photosynthetic systems for the direct conversion of carbon dioxide and water to fuel depends on the availability of efficient and robust catalysts for the chemical transformations. Catalysts need to exhibit turnover frequency (TOF) and density (hence size) commensurate with the solar flux at ground level (1000Wm2, airmass (AM) 1.5)[1]to avoid wasting of incidentsolar photons. For example, a catalyst with a TOF of 100 s1 requires a density of one catalytic site per square nanometer. Catalysts with lower rates or taking up a larger space will require a high-surface-area, nanostructured support that affords tens to hundreds of catalytic sites per square nanometer. Furthermore, catalysts need to operate close to the thermodynamic potential of the redox reaction so that amaximum fraction of the solar photon energy is converted to chemical energy. Stability considerations favor all-inorganic oxide materials, as does avoidance of harsh reaction conditions of pH value or temperature.

Jiao, Feng; Frei, Heinz

2009-01-01T23:59:59.000Z

10

Embedding Covalency into Metal Catalysts for Efficient Electrochemical Conversion of CO2  

E-Print Network [OSTI]

- throughput screening to propose silver-based catalysts for efficient electrochemical reduction of CO2 to CO. Many researchers anticipate the efficient transformation of CO2 from various emission sources into moreEmbedding Covalency into Metal Catalysts for Efficient Electrochemical Conversion of CO2 Hyung

Goddard III, William A.

11

Identification of Catalysts and Materials for a High-Energy Density Biochemical Fuel Cell: Cooperative Research and Development Final Report, CRADA Number CRD-09-345  

SciTech Connect (OSTI)

The proposed research attempted to identify novel biochemical catalysts, catalyst support materials, high-efficiency electron transfer agents between catalyst active sites and electrodes, and solid-phase electrolytes in order to maximize the current density of biochemical fuel cells that utilize various alcohols as substrates.

Ghirardi, M.; Svedruzic, D.

2013-07-01T23:59:59.000Z

12

CATALYSTS FOR HIGH CETANE ETHERS AS DIESEL FUELS  

SciTech Connect (OSTI)

A tungstena-zirconia (WZ) catalyst has been investigated for coupling methanol and isobutanol to unsymmetrical ethers, i.e. methyl isobutyl ether (MIBE) and compared with earlier studied sulfated-zirconia (SZ) and Nafion-H catalysts. In all cases, the ether synthesis mechanism is a dual site S{sub N}2 process involving competitive adsorption of reactants on proximal acid sites. At low reaction temperatures, methylisobutylether (MIBE) is the predominant product. However, at temperatures >135 C the WZ catalyst is very good for dehydration of isobutanol to isobutene. The surface acid sites of the WZ catalyst and a Nafion-H catalyst were diagnosed by high resolution X-ray photoelectron spectroscopy (XPS) of N 1s shifts after adsorption of amines. Using pyridine, ethylenediamine, and triethylamine, it is shown that WZ has heterogeneous strong Broensted acid sites. Theoretical study located the transition state of the alcohol coupling reaction on proximal Broensted acid sites and accounted well for XPS core-level shifts upon surface acid-base interactions. While computations have not been carried out with WZ, it is shown that the SZ catalyst is a slightly stronger acid than CF{sub 3}SO{sub 3}H (a model for Nafion-H) by 1.3-1.4 kcal/mol. A novel sulfated zirconia catalyst having proximal strong Broensted acid sites was synthesized and shown to have significantly enhanced activity and high selectivity in producing MIBE or isobutene from methanol/isobutanol mixtures. The catalyst was prepared by anchoring 1,2-ethanediol bis(hydrogen sulfate) salt precursor onto zirconium hydroxide, followed by calcination to remove the -(CH{sub 2}CH{sub 2})- bridging residues.

Kamil Klier; Richard G. Herman; Heock-Hoi Kwon; James G. C. Shen; Qisheng Ma; Robert A. Hunsicker; Andrew P. Butler; Scott J. Bollinger

2003-03-01T23:59:59.000Z

13

High efficiency incandescent lighting  

DOE Patents [OSTI]

Incandescent lighting structure. The structure includes a thermal emitter that can, but does not have to, include a first photonic crystal on its surface to tailor thermal emission coupled to, in a high-view-factor geometry, a second photonic filter selected to reflect infrared radiation back to the emitter while passing visible light. This structure is highly efficient as compared to standard incandescent light bulbs.

Bermel, Peter; Ilic, Ognjen; Chan, Walker R.; Musabeyoglu, Ahmet; Cukierman, Aviv Ruben; Harradon, Michael Robert; Celanovic, Ivan; Soljacic, Marin

2014-09-02T23:59:59.000Z

14

High Efficiency, Clean Combustion  

SciTech Connect (OSTI)

Energy use in trucks has been increasing at a faster rate than that of automobiles within the U.S. transportation sector. According to the Energy Information Administration (EIA) Annual Energy Outlook (AEO), a 23% increase in fuel consumption for the U.S. heavy duty truck segment is expected between 2009 to 2020. The heavy duty vehicle oil consumption is projected to grow between 2009 and 2050 while light duty vehicle (LDV) fuel consumption will eventually experience a decrease. By 2050, the oil consumption rate by LDVs is anticipated to decrease below 2009 levels due to CAFE standards and biofuel use. In contrast, the heavy duty oil consumption rate is anticipated to double. The increasing trend in oil consumption for heavy trucks is linked to the vitality, security, and growth of the U.S. economy. An essential part of a stable and vibrant U.S. economy is a productive U.S. trucking industry. Studies have shown that the U.S. gross domestic product (GDP) is strongly correlated to freight transport. Over 90% of all U.S. freight tonnage is transported by diesel power and over 75% is transported by trucks. Given the vital role that the trucking industry plays in the economy, improving the efficiency of the transportation of goods was a central focus of the Cummins High Efficient Clean Combustion (HECC) program. In a commercial vehicle, the diesel engine remains the largest source of fuel efficiency loss, but remains the greatest opportunity for fuel efficiency improvements. In addition to reducing oil consumption and the dependency on foreign oil, this project will mitigate the impact on the environment by meeting US EPA 2010 emissions regulations. Innovation is a key element in sustaining a U.S. trucking industry that is competitive in global markets. Unlike passenger vehicles, the trucking industry cannot simply downsize the vehicle and still transport the freight with improved efficiency. The truck manufacturing and supporting industries are faced with numerous challenges to reduce oil consumption and greenhouse gases, meet stringent emissions regulations, provide customer value, and improve safety. The HECC program successfully reduced engine fuel consumption and greenhouse gases while providing greater customer valve. The US EPA 2010 emissions standard poses a significant challenge for developing clean diesel powertrains that meet the DoE Vehicle Technologies Multi-Year Program Plan (MYPP) for fuel efficiency improvement while remaining affordable. Along with exhaust emissions, an emphasis on heavy duty vehicle fuel efficiency is being driven by increased energy costs as well as the potential regulation of greenhouse gases. An important element of the success of meeting emissions while significantly improving efficiency is leveraging Cummins component technologies such as fuel injection equipment, aftertreatment, turbomahcinery, electronic controls, and combustion systems. Innovation in component technology coupled with system integration is enabling Cummins to move forward with the development of high efficiency clean diesel products with a long term goal of reaching a 55% peak brake thermal efficiency for the engine plus aftertreatment system. The first step in developing high efficiency clean products has been supported by the DoE co-sponsored HECC program. The objectives of the HECC program are: (1) To design and develop advanced diesel engine architectures capable of achieving US EPA 2010 emission regulations while improving the brake thermal efficiency by 10% compared to the baseline (a state of the art 2007 production diesel engine). (2) To design and develop components and subsystems (fuel systems, air handling, controls, etc) to enable construction and development of multi-cylinder engines. (3) To perform an assessment of the commercial viability of the newly developed engine technology. (4) To specify fuel properties conducive to improvements in emissions, reliability, and fuel efficiency for engines using high-efficiency clean combustion (HECC) technologies. To demonstrate the technology is compatible with B2

Donald Stanton

2010-03-31T23:59:59.000Z

15

Computationally Efficient Modeling of High-Efficiency Clean Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines...

16

NREL Team Creates High-Activity, Durable Platinum Extended Surface Catalyst for Fuel Cells (Fact Sheet)  

SciTech Connect (OSTI)

Researchers with NREL's Fuel Cell team showed that platinum can replace copper nanowires in such a way that high-surface-area and high-specific-activity catalysts are produced, potentially allowing for lower-cost catalysts.

Not Available

2011-02-01T23:59:59.000Z

17

Phosphotungstic acid supported on magnetic nanoparticles as an efficient reusable catalyst for epoxidation of alkenes  

SciTech Connect (OSTI)

Highlights: ? Phosphotungstic acid supported on functionalized cobalt ferrite was prepared. ? Silica coated cobalt ferrite nanoparticles were used as support. ? This composite was successfully used as catalyst for epoxidation of alkenes. ? Oxidation reactions were carried out in the presence of t-BuOOH as oxidant. ? The catalyst can be readily separated from solution by magnetic field. -- Abstract: A new magnetically separable catalyst consisting of phosphotungstic acid supported on imidazole functionalized silica coated cobalt ferrite nanoparticles was prepared. The synthesized catalyst was characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR), and inductively coupled plasma atomic emission spectroscopy (ICP-AES). This immobilized phosphotungstic acid was shown to be an efficient heterogeneous catalyst for the epoxidation of various alkenes using tert-butylhydroperoxide (t-BuOOH) as oxidant. The catalyst is readily recovered by simple magnetic decantation and can be recycled several times with no significant loss of catalytic activity.

Kooti, M., E-mail: m_kooti@scu.ac.ir [Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357- 43169 (Iran, Islamic Republic of); Afshari, M. [Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357- 43169 (Iran, Islamic Republic of)] [Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357- 43169 (Iran, Islamic Republic of)

2012-11-15T23:59:59.000Z

18

High Efficiency Integrated Package  

SciTech Connect (OSTI)

Solid-state lighting based on LEDs has emerged as a superior alternative to inefficient conventional lighting, particularly incandescent. LED lighting can lead to 80 percent energy savings; can last 50,000 hours – 2-50 times longer than most bulbs; and contains no toxic lead or mercury. However, to enable mass adoption, particularly at the consumer level, the cost of LED luminaires must be reduced by an order of magnitude while achieving superior efficiency, light quality and lifetime. To become viable, energy-efficient replacement solutions must deliver system efficacies of ? 100 lumens per watt (LPW) with excellent color rendering (CRI > 85) at a cost that enables payback cycles of two years or less for commercial applications. This development will enable significant site energy savings as it targets commercial and retail lighting applications that are most sensitive to the lifetime operating costs with their extended operating hours per day. If costs are reduced substantially, dramatic energy savings can be realized by replacing incandescent lighting in the residential market as well. In light of these challenges, Cree proposed to develop a multi-chip integrated LED package with an output of > 1000 lumens of warm white light operating at an efficacy of at least 128 LPW with a CRI > 85. This product will serve as the light engine for replacement lamps and luminaires. At the end of the proposed program, this integrated package was to be used in a proof-of-concept lamp prototype to demonstrate the component’s viability in a common form factor. During this project Cree SBTC developed an efficient, compact warm-white LED package with an integrated remote color down-converter. Via a combination of intensive optical, electrical, and thermal optimization, a package design was obtained that met nearly all project goals. This package emitted 1295 lm under instant-on, room-temperature testing conditions, with an efficacy of 128.4 lm/W at a color temperature of ~2873K and 83 CRI. As such, the package’s performance exceeds DOE’s warm-white phosphor LED efficacy target for 2013. At the end of the program, we assembled an A19 sized demonstration bulb housing the integrated package which met Energy Star intensity variation requirements. With further development to reduce overall component cost, we anticipate that an integrated remote converter package such as developed during this program will find application in compact, high-efficacy LED-based lamps, particularly those requiring omnidirectional emission.

Ibbetson, James

2013-09-15T23:59:59.000Z

19

CATALYSTS FOR HIGH CETANE ETHERS AS DIESEL FUELS  

SciTech Connect (OSTI)

A novel 1,2-ethanediol, bis(hydrogen sulfate), disodium salt precursor-based solid acid catalyst with a zirconia substrate was synthesized and demonstrated to have significantly enhanced activity and high selectivity in producing methyl isobutyl ether (MIBE) or isobutene from methanol-isobutanol mixtures. The precursor salt was synthesized and provided by Dr. T. H. Kalantar of the M.E. Pruitt Research Center, Dow Chemical Co., Midland, MI 48674. Molecular modeling of the catalyst synthesis steps and of the alcohol coupling reaction is being carried out. A representation of the methyl transfer from the surface activated methanol molecule (left) to the activated oxygen of the isobutanol molecule (right) to form an ether linkage to yield MIBE is shown.

Kamil Klier; Richard G. Herman; James G.C. Shen; Qisheng Ma

2000-08-31T23:59:59.000Z

20

High surface area ThO/sub 2/ catalyst  

DOE Patents [OSTI]

A ThO/sub 2/ catalyst having a high surface area of about 80 to 125m/sup 2//g is synthesized. The compound is synthesized by simultaneously mixing an aqueous solution of ThNO/sub 3/(NO/sub 3/)/sub 4/.4H/sub 2/O with an aqueous solution of Na/sub 2/CO/sub 3/.H/sub 2/O, to produce a solution and solid ThOCO/sub 3/. The solid ThOCO/sub 3/ is separated from the solution, and then calcined at a temperature of about 225 to 300/sup 0/C for about 40 to 55 hours to produce ThO/sub 2/. The ThO/sub 2/ catalyst produced includes Na present as a substitutional cation in an amount equal to about 5 to 10 at. %.

Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

1983-06-21T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems  

DOE Patents [OSTI]

A method for reducing catalyst attrition losses in hydrocarbon synthesis processes conducted in high agitation reaction systems; a method of producing an attrition-resistant catalyst; a catalyst produced by such method; a method of producing an attrition-resistant catalyst support; and a catalyst support produced by such method. The inventive method of reducing catalyst attrition losses comprises the step of reacting a synthesis gas in a high agitation reaction system in the presence of a catalyst. In one aspect, the catalyst preferably comprises a .gamma.-alumina support including an amount of titanium effective for increasing the attrition resistance of the catalyst. In another aspect, the catalyst preferably comprises a .gamma.-alumina support which has been treated, after calcination, with an acidic, aqueous solution. The acidic aqueous solution preferably has a pH of not more than about 5. In another aspect, the catalyst preferably comprises cobalt on a .gamma.-alumina support wherein the cobalt has been applied to the .gamma.-alumina support by totally aqueous, incipient wetness-type impregnation. In another aspect, the catalyst preferably comprises cobalt on a .gamma.-alumina support with an amount of a lanthana promoter effective for increasing the attrition resistance of the catalyst. In another aspect, the catalyst preferably comprises a .gamma.-alumina support produced from boehmite having a crystallite size, in the 021 plane, in the range of from about 30 to about 55 .ANG.ngstrons. In another aspect, the inventive method of producing an attrition-resistant catalyst comprises the step of treating a .gamma.-alumina support, after calcination of and before adding catalytic material to the support, with an acidic solution effective for increasing the attrition resistance of the catalyst. In another aspect, the inventive method of producing an attrition-resistant catalyst support comprises the step of treating calcined .gamma.-alumina with an acidic, aqueous solution effective for increasing the attrition resistance of the .gamma.-alumina.

Singleton, Alan H. (Baden, PA); Oukaci, Rachid (Gibsonia, PA); Goodwin, James G. (Cranberry Township, PA)

2001-01-01T23:59:59.000Z

22

High Efficiency Fuel Reactivity Controlled Compression Ignition...  

Broader source: Energy.gov (indexed) [DOE]

0.1 0.2 0.3 0.4 0.5 0.6 PM gbhp-hr NOx gbhp-hr 1988 1991 2004 2007 2010 * SI gasoline engine with 3-Way Catalyst: Thermal Efficiency 30% * Diesel engines are the most...

23

Ultra-High Resolution Electron Microscopy for Catalyst Characterizatio...  

Broader source: Energy.gov (indexed) [DOE]

10012007 * Project end date: 09302012 * Percent complete: 80% * Development and optimization of catalyst- based aftertreatment systems are inhibited by the lack of...

24

Development of Highly Selective Oxidation Catalysts by Atomic Layer Deposition  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose goal is to use Atomic Layer Deposition to construct nanostructured catalysts to improve the effectiveness of oxidative dehydrogenation of alkanes. More effective catalysts could enable higher specific conversion rates and result in drastic energy savings - up to 25 trillion Btu per year by 2020.

25

Computationally Efficient Modeling of High-Efficiency Clean Combustion...  

Broader source: Energy.gov (indexed) [DOE]

428114 Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines Daniel Flowers (PI), Salvador Aceves, Nicholas Killingsworth, Matthew McNenly, Thomas...

26

Subnanometer platinum clusters highly active and selective catalysts for the oxidative dehydrogenation of propane.  

SciTech Connect (OSTI)

Small clusters are known to possess reactivity not observed in their bulk analogues, which can make them attractive for catalysis. Their distinct catalytic properties are often hypothesized to result from the large fraction of under-coordinated surface atoms. Here, we show that size-preselected Pt{sub 8-10} clusters stabilized on high-surface-area supports are 40-100 times more active for the oxidative dehydrogenation of propane than previously studied platinum and vanadia catalysts, while at the same time maintaining high selectivity towards formation of propylene over by-products. Quantum chemical calculations indicate that under-coordination of the Pt atoms in the clusters is responsible for the surprisingly high reactivity compared with extended surfaces. We anticipate that these results will form the basis for development of a new class of catalysts by providing a route to bond-specific chemistry, ranging from energy-efficient and environmentally friendly synthesis strategies to the replacement of petrochemical feedstocks by abundant small alkanes.

Vajda, S; Pellin, M. J.; Greeley, J. P.; Marshall, C. L.; Curtiss, L. A.; Ballentine, G. A.; Elam, J. W.; Catillon-Mucherie, S.; Redfern, P. C.; Mehmood, F.; Zapol, P.; Yale Univ.

2009-03-01T23:59:59.000Z

27

High-Activity Dealloyed Catalysts 2010 DOE Hydrogen Program Fuel Cell  

E-Print Network [OSTI]

High-Activity Dealloyed Catalysts 2010 DOE Hydrogen Program Fuel Cell Project Kick-active-area fuel cells, to be made available for DOE testing Reduce catalyst cost while achieving the required · Subcontractors: ­ Technical University of Berlin ­ Johnson Matthey Fuel Cells ­ Massachusetts Institute

28

High Efficiency Engine Technologies Program  

SciTech Connect (OSTI)

Caterpillar's Product Development and Global Technology Division carried out a research program on waste heat recovery with support from DOE (Department of Energy) and the DOE National Energy Technology Laboratory. The objective of the program was to develop a new air management and exhaust energy recovery system that would demonstrate a minimum 10% improvement in thermal efficiency over a base heavy-duty on-highway diesel truck engine. The base engine for this program was a 2007 C15 15.2L series-turbocharged on-highway truck engine with a LPL (low-pressure loop) exhaust recirculation system. The focus of the program was on the development of high efficiency turbomachinery and a high efficiency turbocompound waste heat recovery system. The focus of each area of development was as follows: (1) For turbine stages, the focus was on investigation and development of technologies that would improve on-engine exhaust energy utilization compared to the conventional radial turbines in widespread use today. (2) For compressor stages, the focus was on investigating compressor wheel design parameters beyond the range typically utilized in production, to determine the potential efficiency benefits thereof. (3) For turbocompound, the focus was on the development of a robust bearing system that would provide higher bearing efficiencies compared to systems used in turbocompound power turbines in production. None of the turbocharger technologies investigated involved addition of moving parts, actuators, or exotic materials, thereby increasing the likelihood of a favorable cost-value tradeoff for each technology. And the turbocompound system requires less hardware addition than competing bottoming cycle technologies, making it a more attractive solution from a cost and packaging standpoint. Main outcomes of the program are as follows: (1) Two turbine technologies that demonstrated up to 6% improvement in turbine efficiency on gas stand and 1-3% improvement in thermal efficiency in on-engine testing. (2) A compressor technology that demonstrated 1.5% improvement in compressor efficiency on gas stand compared to production available compressors. (3) A power turbine with high efficiency bearing system that demonstrated excellent rotordynamic stability throughout the required speed range, up to 60,000 rpm. (4) A predicted improvement (using engine simulation) in engine thermal efficiency of 7% at the peak torque design point, when combining the technologies developed in this program.

Rich Kruiswyk

2010-07-13T23:59:59.000Z

29

Enabling High Efficiency Ethanol Engines  

SciTech Connect (OSTI)

Delphi Automotive Systems and ORNL established this CRADA to explore the potential to improve the energy efficiency of spark-ignited engines operating on ethanol-gasoline blends. By taking advantage of the fuel properties of ethanol, such as high compression ratio and high latent heat of vaporization, it is possible to increase efficiency with ethanol blends. Increasing the efficiency with ethanol-containing blends aims to remove a market barrier of reduced fuel economy with E85 fuel blends, which is currently about 30% lower than with petroleum-derived gasoline. The same or higher engine efficiency is achieved with E85, and the reduction in fuel economy is due to the lower energy density of E85. By making ethanol-blends more efficient, the fuel economy gap between gasoline and E85 can be reduced. In the partnership between Delphi and ORNL, each organization brought a unique and complementary set of skills to the project. Delphi has extensive knowledge and experience in powertrain components and subsystems as well as overcoming real-world implementation barriers. ORNL has extensive knowledge and expertise in non-traditional fuels and improving engine system efficiency for the next generation of internal combustion engines. Partnering to combine these knowledge bases was essential towards making progress to reducing the fuel economy gap between gasoline and E85. ORNL and Delphi maintained strong collaboration throughout the project. Meetings were held regularly, usually on a bi-weekly basis, with additional reports, presentations, and meetings as necessary to maintain progress. Delphi provided substantial hardware support to the project by providing components for the single-cylinder engine experiments, engineering support for hardware modifications, guidance for operational strategies on engine research, and hardware support by providing a flexible multi-cylinder engine to be used for optimizing engine efficiency with ethanol-containing fuels.

Szybist, J.; Confer, K. (Delphi Automotive Systems)

2011-03-01T23:59:59.000Z

30

Combined Catalysis and Optical Screening for High Throughput Discovery of Solar Fuels Catalysts  

E-Print Network [OSTI]

Combined Catalysis and Optical Screening for High Throughput Discovery of Solar Fuels Catalysts J,b a Joint Center for Artificial Photosynthesis, California Institute of Technology, Pasadena, California 91125, USA b Engineering Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720

Faraon, Andrei

31

Easy and efficient processes for catalyst recycling and product recovery in organic biphase systems tested in the hydrogenation of hex-1-ene  

E-Print Network [OSTI]

Easy and efficient processes for catalyst recycling and product recovery in organic biphase systems November 1999, Accepted 26th November 1999 Two organic liquid biphase systems containg poly(ethylene oxide, with the latter showing a better performance and enabling easy and efficient product separation and catalyst

Loh, Watson

32

Computationally Efficient Modeling of High-Efficiency Clean Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Meeting, June 7-11, 2010 -- Washington D.C. ace012aceves2010o.pdf More Documents & Publications Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines...

33

Supported metal catalysts for alcohol/sugar alcohol steam reforming  

SciTech Connect (OSTI)

Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

2014-08-21T23:59:59.000Z

34

High Efficiency Fans and High Efficiency Electrical Motors  

E-Print Network [OSTI]

Replacing nominal efficient electrical motors with premium efficiency can save on electrical power costs in cotton gins. Connected horsepower load on industrial air fans is approximately 60% of the total horsepower in a typical cotton gin...

Breedlove, C. W.

35

Computationally Efficient Modeling of High-Efficiency Clean Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Peer Evaluation ace012aceves2011o.pdf More Documents & Publications Simulation of High Efficiency Clean Combustion Engines and Detailed Chemical Kinetic Mechanisms Development...

36

Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyThe EnergyDepartment7 thFuel Processor for' %Transmissionand SCR

37

Selective ammonia slip catalyst enabling highly efficient NOx removal  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartment of Energy Moniz: WhatM-1at the Highrequirements of

38

Enabling High Efficiency Clean Combustion  

Broader source: Energy.gov (indexed) [DOE]

penalty associated with aftertreatment 3% improvement in open cycle efficiency (turbo, EGR system, etc.) 8 This presentation does not contain any proprietary or...

39

High efficiency silicon nanohole/organic heterojunction hybrid solar cell  

SciTech Connect (OSTI)

High efficiency hybrid solar cells are fabricated based on silicon with a nanohole (SiNH) structure and poly (3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS). The SiNH structure is fabricated using electroless chemical etching with silver catalyst, and the heterojunction is formed by spin coating of PEDOT on the SiNH. The hybrid cells are optimized by varying the hole depth, and a maximum power conversion efficiency of 8.3% is achieved with a hole depth of 1??m. The SiNH hybrid solar cell exhibits a strong antireflection and light trapping property attributed to the sub-wavelength dimension of the SiNH structure.

Hong, Lei [Novitas, Nanoelectronics Centre of Excellence, School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Singapore Institute of Manufacturing Technology, A-STAR (Agency for Science, Technology and Research), 71 Nanyang Drive, Singapore 638075 (Singapore); Wang, Xincai; Zheng, Hongyu [Singapore Institute of Manufacturing Technology, A-STAR (Agency for Science, Technology and Research), 71 Nanyang Drive, Singapore 638075 (Singapore); He, Lining; Wang, Hao; Rusli, E-mail: yu.hy@sustc.edu.cn, E-mail: erusli@ntu.edu.sg [Novitas, Nanoelectronics Centre of Excellence, School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Yu, Hongyu, E-mail: yu.hy@sustc.edu.cn, E-mail: erusli@ntu.edu.sg [South University of Science and Technology of China, Shenzhen (China)

2014-02-03T23:59:59.000Z

40

High efficiency turbine blade coatings.  

SciTech Connect (OSTI)

The development of advanced thermal barrier coatings (TBCs) of yttria stabilized zirconia (YSZ) that exhibit lower thermal conductivity through better control of electron beam - physical vapor deposition (EB-PVD) processing is of prime interest to both the aerospace and power industries. This report summarizes the work performed under a two-year Lab-Directed Research and Development (LDRD) project (38664) to produce lower thermal conductivity, graded-layer thermal barrier coatings for turbine blades in an effort to increase the efficiency of high temperature gas turbines. This project was sponsored by the Nuclear Fuel Cycle Investment Area. Therefore, particular importance was given to the processing of the large blades required for industrial gas turbines proposed for use in the Brayton cycle of nuclear plants powered by high temperature gas-cooled reactors (HTGRs). During this modest (~1 full-time equivalent (FTE)) project, the processing technology was developed to create graded TBCs by coupling ion beam-assisted deposition (IBAD) with substrate pivoting in the alumina-YSZ system. The Electron Beam - 1200 kW (EB-1200) PVD system was used to deposit a variety of TBC coatings with micron layered microstructures and reduced thermal conductivity below 1.5 W/m.K. The use of IBAD produced fully stoichiometric coatings at a reduced substrate temperature of 600 oC and a reduced oxygen background pressure of 0.1 Pa. IBAD was also used to successfully demonstrate the transitioning of amorphous PVD-deposited alumina to the -phase alumina required as an oxygen diffusion barrier and for good adhesion to the substrate Ni2Al3 bondcoat. This process replaces the time consuming thermally grown oxide formation required before the YSZ deposition. In addition to the process technology, Direct Simulation Monte Carlo plume modeling and spectroscopic characterization of the PVD plumes were performed. The project consisted of five tasks. These included the production of layered periodic microstructures in the coating, the Direct Simulation Monte Carlo (DSMC) modeling of particle transport in the PVD plume, functional graded layer development, the deposition of all layers to form a complete coating, and materials characterization including thermal testing. Ion beam-assisted deposition, beam sharing through advanced digital rastering, substrate pivoting, hearth calorimetry, infrared imaging, fiber optic-enabled optical emission spectroscopy and careful thermal management were used to achieve all the milestones outlined in the FY02 LDRD proposal.

Youchison, Dennis L.; Gallis, Michail A.

2014-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Enabling High Efficiency Clean Combustion  

Broader source: Energy.gov (indexed) [DOE]

for Efficiency Improvement Controls Variable Valve Actuation Variable Intake Swirl Turbo Technology Electrically Driven Components Aftertreatment Phase 2 0 2 4 6 8 0 0.2 0.4...

42

High Energy Efficiency Air Conditioning  

SciTech Connect (OSTI)

This project determined the performance of a new high efficiency refrigerant, Ikon B, in a residential air conditioner designed to use R-22. The refrigerant R-22, used in residential and small commercial air conditioners, is being phased out of production in developed countries beginning this year because of concerns regarding its ozone depletion potential. Although a replacement refrigerant, R-410A, is available, it operates at much higher pressure than R-22 and requires new equipment. R-22 air conditioners will continue to be in use for many years to come. Air conditioning is a large part of expensive summer peak power use in many parts of the U.S. Previous testing and computer simulations of Ikon B indicated that it would have 20 - 25% higher coefficient of performance (COP, the amount of cooling obtained per energy used) than R-22 in an air-cooled air conditioner. In this project, a typical new R-22 residential air conditioner was obtained, installed in a large environmental chamber, instrumented, and run both with its original charge of R-22 and then with Ikon B. In the environmental chamber, controlled temperature and humidity could be maintained to obtain repeatable and comparable energy use results. Tests with Ikon B included runs with and without a power controller, and an extended run for several months with subsequent analyses to check compatibility of Ikon B with the air conditioner materials and lubricant. Baseline energy use of the air conditioner with its original R-22 charge was measured at 90 deg F and 100 deg F. After changeover to Ikon B and a larger expansion orifice, energy use was measured at 90 deg F and 100 deg F. Ikon B proved to have about 19% higher COP at 90 deg F and about 26% higher COP at 100 deg F versus R-22. Ikon B had about 20% lower cooling capacity at 90 deg F and about 17% lower cooling capacity at 100 deg F versus R-22 in this system. All results over multiple runs were within 1% relative standard deviation (RSD). All of these values agree well with previous results and computer simulations of Ikon B performance versus R-22. The lower cooling capacity of Ikon B is not a concern unless a particular air conditioner is near its maximum cooling capacity in application. Typically, oversized A/C systems are installed by contractors to cover contingencies. In the extended run with Ikon B, which lasted about 4.5 months at 100 deg F ambient temperature and 68% compressor on time, the air conditioner performed well with no significant loss of energy efficiency. Post-run analysis of the refrigerant, compressor lubricant oil, compressor, compressor outlet tubing, and the filter/dryer showed minor effects but nothing that was considered significant. The project was very successful. All objectives were achieved, and the performance of Ikon B indicates that it can easily be retrofitted into R-22 air conditioners to give 15 - 20% energy savings and a 1 - 3 year payback of retrofit costs depending on location and use. Ikon B has the potential to be a successful commercial product.

Edward McCullough; Patrick Dhooge; Jonathan Nimitz

2003-12-31T23:59:59.000Z

43

High Efficiency, High Performance Clothes Dryer  

SciTech Connect (OSTI)

This program covered the development of two separate products; an electric heat pump clothes dryer and a modulating gas dryer. These development efforts were independent of one another and are presented in this report in two separate volumes. Volume 1 details the Heat Pump Dryer Development while Volume 2 details the Modulating Gas Dryer Development. In both product development efforts, the intent was to develop high efficiency, high performance designs that would be attractive to US consumers. Working with Whirlpool Corporation as our commercial partner, TIAX applied this approach of satisfying consumer needs throughout the Product Development Process for both dryer designs. Heat pump clothes dryers have been in existence for years, especially in Europe, but have not been able to penetrate the market. This has been especially true in the US market where no volume production heat pump dryers are available. The issue has typically been around two key areas: cost and performance. Cost is a given in that a heat pump clothes dryer has numerous additional components associated with it. While heat pump dryers have been able to achieve significant energy savings compared to standard electric resistance dryers (over 50% in some cases), designs to date have been hampered by excessively long dry times, a major market driver in the US. The development work done on the heat pump dryer over the course of this program led to a demonstration dryer that delivered the following performance characteristics: (1) 40-50% energy savings on large loads with 35 F lower fabric temperatures and similar dry times; (2) 10-30 F reduction in fabric temperature for delicate loads with up to 50% energy savings and 30-40% time savings; (3) Improved fabric temperature uniformity; and (4) Robust performance across a range of vent restrictions. For the gas dryer development, the concept developed was one of modulating the gas flow to the dryer throughout the dry cycle. Through heat modulation in a gas dryer, significant time and energy savings, combined with dramatically reduced fabric temperatures, was achieved in a cost-effective manner. The key design factor lay in developing a system that matches the heat input to the dryer with the fabrics ability to absorb it. The development work done on the modulating gas dryer over the course of this program led to a demonstration dryer that delivered the following performance characteristics: (1) Up to 25% reduction in energy consumption for small and medium loads; (2) Up to 35% time savings for large loads with 10-15% energy reduction and no adverse effect on cloth temperatures; (3) Reduced fabric temperatures, dry times and 18% energy reduction for delicate loads; and, (4) Robust performance across a range of vent restrictions.

Peter Pescatore; Phil Carbone

2005-03-31T23:59:59.000Z

44

Webinar: Highly Efficient Solar Thermochemical Reaction Systems  

Broader source: Energy.gov [DOE]

Video recording and text version of the Fuel Cell Technologies Office webinar titled "Highly Efficient Solar Thermochemical Reaction Systems," originally presented on January 13, 2015.

45

Thermal Strategies for High Efficiency Thermoelectric Power Generation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermal Strategies for High Efficiency Thermoelectric Power Generation Thermal Strategies for High Efficiency Thermoelectric Power Generation Developing integrated TE system...

46

Efficient high density train operations  

DOE Patents [OSTI]

The present invention provides methods for preventing low train voltages and managing interference, thereby improving the efficiency, reliability, and passenger comfort associated with commuter trains. An algorithm implementing neural network technology is used to predict low voltages before they occur. Once voltages are predicted, then multiple trains can be controlled to prevent low voltage events. Further, algorithms for managing inference are presented in the present invention. Different types of interference problems are addressed in the present invention such as "Interference. During Acceleration", "Interference Near Station Stops", and "Interference During Delay Recovery." Managing such interference avoids unnecessary brake/acceleration cycles during acceleration, immediately before station stops, and after substantial delays. Algorithms are demonstrated to avoid oscillatory brake/acceleration cycles due to interference and to smooth the trajectories of closely following trains. This is achieved by maintaining sufficient following distances to avoid unnecessary braking/accelerating. These methods generate smooth train trajectories, making for a more comfortable ride, and improve train motor reliability by avoiding unnecessary mode-changes between propulsion and braking. These algorithms can also have a favorable impact on traction power system requirements and energy consumption.

Gordon, Susanna P. (Oakland, CA); Evans, John A. (Hayward, CA)

2001-01-01T23:59:59.000Z

47

Technology Development for Light Duty High Efficient Diesel Engines...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Light Duty High Efficient Diesel Engines Technology Development for Light Duty High Efficient Diesel Engines Improve the efficiency of diesel engines for light duty applications...

48

Technology Development for High Efficiency Clean Diesel Engines...  

Broader source: Energy.gov (indexed) [DOE]

Technology Development for High Efficiency Clean Diesel Engines and a Pathway to 50% Thermal Efficiency Technology Development for High Efficiency Clean Diesel Engines and a...

49

High-Activity Dealloyed Catalysts | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCEDOE BiomassHigh-Activity

50

Very High Efficiency Solar Cell Modules  

SciTech Connect (OSTI)

The Very High Efficiency Solar Cell (VHESC) program is developing integrated optical system - PV modules for portable applications that operate at greater than 50% efficiency. We are integrating the optical design with the solar cell design, and have entered previously unoccupied design space. Our approach is driven by proven quantitative models for the solar cell design, the optical design, and the integration of these designs. Optical systems efficiency with an optical efficiency of 93% and solar cell device results under ideal dichroic splitting optics summing to 42.7 {+-} 2.5% are described.

Barnett, A.; Kirkpatrick, D.; Honsberg, C.; Moore, D.; Wanlass, M.; Emery, K.; Schwartz, R.; Carlson, D.; Bowden, S.; Aiken, D.; Gray, A.; Kurtz, S.; Kazmerski, L., et al

2009-01-01T23:59:59.000Z

51

Webinar: Highly Efficient Solar Thermochemical Reaction Systems  

Broader source: Energy.gov [DOE]

The Fuel Cell Technologies Office will present a live webinar titled "Highly Efficient Solar Thermochemical Reaction Systems" on Tuesday, January 13, from 12:00 to 1:00 p.m. Eastern Standard Time.

52

Highly Efficient Solar Thermochemical Reaction Systems  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Highly Efficient, Solar Thermochemical Reaction Systems (2014 R&D 100 Award Winner) U.S. Department of Energy Fuel Cell Technologies Office 2 Question and Answer * Please type your...

53

Efficient Oxygen Evolution Reaction Catalysts for Cell Reversal and Start/Stop Tolerance in Fuel Cells  

SciTech Connect (OSTI)

Minute amounts of ruthenium and iridium on platinum nanostructured thin films have been evaluated in an effort to reduce carbon corrosion and Pt dissolution during transient conditions in proton exchange membrane fuel cells. Electrochemical tests showed the catalysts had a remarkable oxygen evolution reaction (OER) activity, even greater than that of bulk, metallic thin films. Stability tests within a fuel cell environment showed that rapid Ru dissolution could be managed with the addition of Ir. Membrane electrode assemblies containing a Ru to Ir atomic ratio of 1:9 were evaluated under startup/shutdown and cell reversal conditions for OER catalyst loadings ranging from 1 to 10 g/cm2. These tests affirmed that electrode potentials can be controlled through the addition of OER catalysts without impacting the oxygen reduction reaction on the cathode or the hydrogen oxidation reaction on the anode. The morphology and chemical structure of the thin OER layers were characterized by scanning transmission electron microscopy and X-ray photoelectron spectroscopy in an effort to establish a correlation between interfacial properties and electrochemical behavior.

Atanasoski, Radoslav [3M Industrial Mineral Products; Atanasoska, Liliana [3M Industrial Mineral Products; Cullen, David A [ORNL

2013-01-01T23:59:59.000Z

54

Multicolor, High Efficiency, Nanotextured LEDs  

SciTech Connect (OSTI)

We report on research results in this project which synergize advanced material science approaches with fundamental optical physics concepts pertaining to light-matter interaction, with the goal of solving seminal problems for the development of very high performance light emitting diodes (LEDs) in the blue and green for Solid State Lighting applications. Accomplishments in the duration of the contract period include (i) heteroepitaxy of nitrogen-polar LEDs on sapphire, (ii) heteroepitaxy of semipolar (11{bar 2}2) green LEDs on sapphire, (iii) synthesis of quantum-dot loaded nanoporous GaN that emits white light without phosphor conversion, (iv) demonstration of the highest quality semipolar (11{bar 2}2) GaN on sapphire using orientation-controlled epitaxy, (v) synthesis of nanoscale GaN and InGaN medium, and (vi) development of a novel liftoff process for manufacturing GaN thin-film vertical LEDs. The body of results is presented in this report shows how a solid foundation has been laid, with several noticeable accomplishments, for innovative research, consistent with the stated milestones.

Jung Han; Arto Nurmikko

2011-09-30T23:59:59.000Z

55

High Impact Technology Catalyst Industry Roundtable | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many| Department of4 Energy SolutionsHigh16,

56

Better Enzymes for Carbon Capture: Low-Cost Biological Catalyst to Enable Efficient Carbon Dioxide Capture  

SciTech Connect (OSTI)

IMPACCT Project: Codexis is developing new and efficient forms of enzymes known as carbonic anhydrases to absorb CO2 more rapidly and under challenging conditions found in the gas exhaust of coal-fired power plants. Carbonic anhydrases are common and are among the fastest enzymes, but they are not robust enough to withstand the harsh environment found in the power plant exhaust steams. In this project, Codexis will be using proprietary technology to improve the enzymes’ ability to withstand high temperatures and large swings in chemical composition. The project aims to develop a carbon-capture process that uses less energy and less equipment than existing approaches. This would reduce the cost of retrofitting today’s coal-fired power plants.

None

2010-07-01T23:59:59.000Z

57

Measure Guideline: High Efficiency Natural Gas Furnaces  

SciTech Connect (OSTI)

This Measure Guideline covers installation of high-efficiency gas furnaces. Topics covered include when to install a high-efficiency gas furnace as a retrofit measure, how to identify and address risks, and the steps to be used in the selection and installation process. The guideline is written for Building America practitioners and HVAC contractors and installers. It includes a compilation of information provided by manufacturers, researchers, and the Department of Energy as well as recent research results from the Partnership for Advanced Residential Retrofit (PARR) Building America team.

Brand, L.; Rose, W.

2012-10-01T23:59:59.000Z

58

Highly Dispersed Pseudo-Homogeneous and Heterogeneous Catalysts Synthesized via Inverse Micelle Solutions for the Liquefaction of Coal  

SciTech Connect (OSTI)

The mission of this project was to use inverse micelle solutions to synthesize nanometer sized metal particles and test the particles as catalysts in the liquefaction of coal and other related reactions. The initial focus of the project was the synthesis of iron based materials in pseudo-homogeneous form. The frost three chapters discuss the synthesis, characterization, and catalyst testing in coal liquefaction and model coal liquefaction reactions of iron based pseudo-homogeneous materials. Later, we became interested in highly dispersed catalysts for coprocessing of coal and plastic waste. Bifunctional catalysts . to hydrogenate the coal and depolymerize the plastic waste are ideal. We began studying, based on our previously devised synthesis strategies, the synthesis of heterogeneous catalysts with a bifunctional nature. In chapter 4, we discuss the fundamental principles in heterogeneous catalysis synthesis with inverse micelle solutions. In chapter 5, we extend the synthesis of chapter 4 to practical systems and use the materials in catalyst testing. Finally in chapter 6, we return to iron and coal liquefaction now studied with the heterogeneous catalysts.

Hampden-Smith, M.; Kawola, J.S.; Martino, A.; Sault, A.G.; Yamanaka, S.A.

1999-01-05T23:59:59.000Z

59

Unregulated Emissions from High-Efficiency Clean Combustion Modes...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Poster presentation at...

60

Integrated Solar Thermochemical Reaction System for High Efficiency...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Integrated Solar Thermochemical Reaction System for High Efficiency Production of Electricity Integrated Solar Thermochemical Reaction System for High Efficiency Production of...

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

High Efficiency GDI Engine Research, with Emphasis on Ignition...  

Broader source: Energy.gov (indexed) [DOE]

High Efficiency GDI Engine Research, with Emphasis on Ignition Systems High Efficiency GDI Engine Research, with Emphasis on Ignition Systems 2013 DOE Hydrogen and Fuel Cells...

62

Tailored Materials for High Efficiency CIDI Engines (Caterpillar...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High Efficiency CIDI Engines (Caterpillar CRADA) Tailored Materials for High Efficiency CIDI Engines (Caterpillar CRADA) 2009 DOE Hydrogen Program and Vehicle Technologies Program...

63

Vehicle Technologies Office: Materials for High-Efficiency Combustion...  

Broader source: Energy.gov (indexed) [DOE]

High-Efficiency Combustion Engines Vehicle Technologies Office: Materials for High-Efficiency Combustion Engines The Vehicle Technologies Office (VTO) is supporting work to improve...

64

Energy Efficiency Opportunities in Federal High Performance Computing...  

Broader source: Energy.gov (indexed) [DOE]

Energy Efficiency Opportunities in Federal High Performance Computing Data Centers Energy Efficiency Opportunities in Federal High Performance Computing Data Centers Case study...

65

Los Alamos develops new technique for growing high-efficiency...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Growing high-efficiency perovskite solar cells Los Alamos develops new technique for growing high-efficiency perovskite solar cells Researchers reveal a new solution-based...

66

Development of a High-Efficiency Zonal Thermoelectric HVAC System...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

a High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Development of a High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications...

67

Progress toward Development of a High-Efficiency Zonal Thermoelectric...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

toward Development of a High-Efficiency Zonal Thermoelectric HVAC System for Automotive Applications Progress toward Development of a High-Efficiency Zonal Thermoelectric HVAC...

68

Challenging Conventional Wisdom: A Clean and Highly Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Challenging Conventional Wisdom: A Clean and Highly Efficient Opposed-Piston Two-Stroke Engine Challenging Conventional Wisdom: A Clean and Highly Efficient Opposed-Piston...

69

High Efficiency Microturbine with Integral Heat Recovery - Presentatio...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High Efficiency Microturbine with Integral Heat Recovery - Presentation by Capstone Turbine Corporation, June 2011 High Efficiency Microturbine with Integral Heat Recovery -...

70

Heavy-Duty Engine Combustion Optimization for High Thermal Efficiency...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Optimization for High Thermal Efficiency Targeting EPA 2010 Emissions Heavy-Duty Engine Combustion Optimization for High Thermal Efficiency Targeting EPA 2010 Emissions...

71

Energy-Efficient Melting and Direct Delivery of High Quality...  

Broader source: Energy.gov (indexed) [DOE]

Energy-Efficient Melting and Direct Delivery of High Quality Molten Aluminum Energy-Efficient Melting and Direct Delivery of High Quality Molten Aluminum itmdelivery.pdf More...

72

Highly Energy Efficient Directed Green Liquor Utilization (D...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping This factsheet describes a...

73

Electrical and Thermal Transport Optimization of High Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Electrical and Thermal Transport Optimization of High Efficient n-type Skutterudites Electrical and Thermal Transport Optimization of High Efficient n-type Skutterudites Work on...

74

Vehicle Technologies Office Merit Review 2014: High Efficiency...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High Efficiency, Low EMI and Positioning Tolerant Wireless Charging of EVs Vehicle Technologies Office Merit Review 2014: High Efficiency, Low EMI and Positioning Tolerant Wireless...

75

Development of Enabling Technologies for High Efficiency, Low...  

Broader source: Energy.gov (indexed) [DOE]

for High Efficiency, Low Emissions Homogeneous Charge Compression Ignition (HCCI) Engines Development of Enabling Technologies for High Efficiency, Low Emissions Homogeneous...

76

High-Efficiency Clean Combustion Design for Compression Ignition...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Efficiency Clean Combustion Design for Compression Ignition Engines High-Efficiency Clean Combustion Design for Compression Ignition Engines Presentation given at DEER 2006,...

77

Syngas Enhanced High Efficiency Low Temperature Combustion for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant...

78

Low Temperature Combustion Demonstrator for High Efficiency Clean...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion 2009 DOE Hydrogen Program...

79

Low Temperature Combustion Demonstrator for High Efficiency Clean...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Presentation from the U.S....

80

Low-Temperature Combustion Demonstrator for High-Efficiency Clean...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion 2010 DOE Vehicle...

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

High-Efficiency Clean Combustion Engine Designs for Compression...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Efficiency Clean Combustion Engine Designs for Compression Ignition Engines High-Efficiency Clean Combustion Engine Designs for Compression Ignition Engines Presentation from...

82

Advanced Combustion Technology to Enable High Efficiency Clean...  

Broader source: Energy.gov (indexed) [DOE]

Combustion Technology to Enable High Efficiency Clean Combustion Advanced Combustion Technology to Enable High Efficiency Clean Combustion Summary of advanced combustion research...

83

Technology and System Level Demonstration of Highly Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technology and System Level Demonstration of Highly Efficient and Clean, Diesel Powered Class 8 Trucks Technology and System Level Demonstration of Highly Efficient and Clean,...

84

Glass-like thermal conductivity in high efficiency thermoelectric...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Glass-like thermal conductivity in high efficiency thermoelectric materials Glass-like thermal conductivity in high efficiency thermoelectric materials Discusses strategies to...

85

High Efficiency Solar Integrated Roof Membrane Product  

SciTech Connect (OSTI)

This project was designed to address the Solar Energy Technology Program objective, to develop new methods to integrate photovoltaic (PV) cells or modules within a building-integrated photovoltaic (BIPV) application that will result in lower installed cost as well as higher efficiencies of the encapsulated/embedded PV module. The technology assessment and development focused on the evaluation and identification of manufacturing technologies and equipment capable of producing such low-cost, high-efficiency, flexible BIPV solar cells on single-ply roofing membranes.

Partyka, Eric; Shenoy, Anil

2013-05-15T23:59:59.000Z

86

High-oxidation-state molybdenum and tungsten monoalkoxide pyrrolide alkylidenes as catalysts for olefin metathesis  

E-Print Network [OSTI]

Chapter 1 describes work toward solid-supported W olefin metathesis catalysts. Attempts to tether derivatives of the known Z-selective catalyst W(NAr)(C?H?)(pyr)(OHIPT) (Ar = 2,6- diisopropylphenyl, pyr = pyrrolide; HIPT ...

Townsend, Erik Matthew

2014-01-01T23:59:59.000Z

87

High-efficiency silicon concentrator cell commercialization  

SciTech Connect (OSTI)

This report summarizes the first phase of a forty-one month program to develop a commercial, high-efficiency concentrator solar cell and facility for manufacturing it. The period covered is November 1, 1990 to December 31, 1991. This is a joint program between the Electric Power Research Institute (EPRI) and Sandia National Laboratories. (This report is also published by EPRI as EPRI report number TR-102035.) During the first year of the program, SunPower accomplished the following major objectives: (1) a new solar cell fabrication facility, which is called the Cell Pilot Line (CPL), (2) a baseline concentrator cell process has been developed, and (3) a cell testing facility has been completed. Initial cell efficiencies are about 23% for the baseline process. The long-range goal is to improve this efficiency to 27%.

Sinton, R.A.; Swanson, R.M. [SunPower Corp., Sunnyvale, CA (US)

1993-05-01T23:59:59.000Z

88

A simple synthesis method of sulfur-free Fe-N-C catalyst witih high ORR activity  

SciTech Connect (OSTI)

To try to deconvolute which factors affect the activity and durability of metal-nitrogen-carbon (M-N-C) type non-precious catalysts for oxygen reduction reaction (ORR), M-N-C catalysts based on ion chloride, polyaniline (PANI) and Ketjen Black carbon support were synthesized using different synthetic conditions. The catalysts were characterized electrochemically and tested as cathodes for Hydrogen fuel cells. PANI is usually chemically oxidative polymerized using ammonium persulfate (APS) as oxidant. To eliminate sulfur in the synthesized catalysts, a simple synthesis method using ion chloride as oxidant for aniline polymerization was developed. Two different aniline polymerization conditions led to very different product morphologies. Synthesized at low initial proton concentration, the final product was composed of dense micrometer sized particles. A decomposable salt was found to be able to prohibit PANI cross linking during the drying and annealing process and thus led to porous product. The porous catalyst has much higher ORR activity than the dense product due to more accessible active sites. Synthesized at high proton concentration, the catalyst appeared to be porous. The decomposable salt treatment did not make too much improvement in the porous structure and electrochemical activity. However, fuel cell testing using air as cathode feeder indicates that the salt treatment improves mass transfer in the cathode layer. Catalyst synthesized using this simple method has performance comparable to our state-of-the art catalyst synthesized in a much more complicated procedure. The factor that sulfur sources are completely eliminated in the synthesis suggests that sulfur is not necessary for the ORR catalysis activity.

Ding, Zhongfen [Los Alamos National Laboratory; Johnston, Christina M [Los Alamos National Laboratory; Zelenay, Piotr [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

89

High Efficiency Engine Technologies | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii CleanHeatinHigh Efficiency

90

High Efficiency Colloidal Quantum Dot Phosphors  

SciTech Connect (OSTI)

The project showed that non-Cd containing, InP-based nanocrystals (semiconductor materials with dimensions of ~6 nm) have high potential for enabling next-generation, nanocrystal-based, on chip phosphors for solid state lighting. Typical nanocrystals fall short of the requirements for on chip phosphors due to their loss of quantum efficiency under the operating conditions of LEDs, such as, high temperature (up to 150 °C) and high optical flux (up to 200 W/cm2). The InP-based nanocrystals invented during this project maintain high quantum efficiency (>80%) in polymer-based films under these operating conditions for emission wavelengths ranging from ~530 to 620 nm. These nanocrystals also show other desirable attributes, such as, lack of blinking (a common problem with nanocrystals which limits their performance) and no increase in the emission spectral width from room to 150 °C (emitters with narrower spectral widths enable higher efficiency LEDs). Prior to these nanocrystals, no nanocrystal system (regardless of nanocrystal type) showed this collection of properties; in fact, other nanocrystal systems are typically limited to showing only one desirable trait (such as high temperature stability) but being deficient in other properties (such as high flux stability). The project showed that one can reproducibly obtain these properties by generating a novel compositional structure inside of the nanomaterials; in addition, the project formulated an initial theoretical framework linking the compositional structure to the list of high performance optical properties. Over the course of the project, the synthetic methodology for producing the novel composition was evolved to enable the synthesis of these nanomaterials at a cost approximately equal to that required for forming typical conventional nanocrystals. Given the above results, the last major remaining step prior to scale up of the nanomaterials is to limit the oxidation of these materials during the tens of thousands of hours of LED operation. Once the LED phosphor lifetime specifications are met, these nanocrystals will enable white LEDs for solid state lighting to simultaneously have increased efficiency and improved light quality, in addition to enabling the creation of custom light spectrums. These improvements to white LEDs will help accelerate the adoption of SSL, leading to large savings in US and worldwide energy costs.

Kahen, Keith

2013-12-31T23:59:59.000Z

91

Highly Efficient Silicon Light Emitting Diode  

E-Print Network [OSTI]

In this paper, we describe the fabrication, using standard silicon processing techniques, of silicon light-emitting diodes (LED) that efficiently emit photons with energy around the silicon bandgap. The improved efficiency had been explained by the spatial confinement of charge carriers due to a local strain field that is formed by dislocation loop arrays. The dependence of device electroluminescent properties on the annealing conditions is carefully examined as a high temperature process has profound influence on these dislocations. Increased luminescent intensity at higher device temperature, together with pure diffusion current conduction mechanism evidently shows the influence of the dislocation loops. The electrical properties of the diode are reasonable with low leakage reverse current.

Leminh Holleman Wallinga; P. Leminh; J. Holleman; H. Wallinga

2000-01-01T23:59:59.000Z

92

Charge Trapping in High Efficiency Alternating Copolymers: Implication...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Charge Trapping in High Efficiency Alternating Copolymers: Implications in Organic Photovoltaic Device Efficiency Home > Research > ANSER Research Highlights > Charge Trapping in...

93

High Efficiency Clean Combustion Engine Designs for Gasoline...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficiency Clean Combustion Engine Designs for Gasoline and Diesel Engines High Efficiency Clean Combustion Engine Designs for Gasoline and Diesel Engines 2009 DOE Hydrogen Program...

94

High-efficiency turquoise-blue electrophosphorescence from a...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

efficiency turquoise-blue electrophosphorescence from a Pt(II)-pyridyltriazolate complex in phosphine oxide host. High-efficiency turquoise-blue electrophosphorescence from a...

95

High efficiency and low roll-off blue phosphorescent organic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

efficiency and low roll-off blue phosphorescent organic light-emitting devices using mixed host architecture. High efficiency and low roll-off blue phosphorescent organic...

96

Advanced High Efficiency Clean Diesel Combustion with Low Cost...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficiency Clean Diesel Combustion with Low Cost for Hybrid Engines Advanced High Efficiency Clean Diesel Combustion with Low Cost for Hybrid Engines Clean, in-cylinder combustion...

97

High Efficiency Low Emission Refrigeration System  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorge Waldmann GeorgeLogging| DepartmentScience EducationHeyHigh Efficiency

98

High Efficiency Cold Climate Heat Pump  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii CleanHeatinHigh Efficiency Cold Climate

99

High-efficiency concentrator silicon solar cells  

SciTech Connect (OSTI)

This report presents results from extensive process development in high-efficiency Si solar cells. An advanced design for a 1.56-cm{sup 2} cell with front grids achieved 26% efficiency at 90 suns. This is especially significant since this cell does not require a prismatic cover glass. New designs for simplified backside-contact solar cells were advanced from a status of near-nonfunctionality to demonstrated 21--22% for one-sun cells in sizes up to 37.5 cm{sup 2}. An efficiency of 26% was achieved for similar 0.64-cm{sup 2} concentrator cells at 150 suns. More fundamental work on dopant-diffused regions is also presented here. The recombination vs. various process and physical parameters was studied in detail for boron and phosphorous diffusions. Emitter-design studies based solidly upon these new data indicate the performance vs design parameters for a variety of the cases of most interest to solar cell designers. Extractions of p-type bandgap narrowing and the surface recombination for p- and n-type regions from these studies have a generality that extends beyond solar cells into basic device modeling. 68 refs., 50 figs.

Sinton, R.A.; Cuevas, A.; King, R.R.; Swanson, R.M. (Stanford Univ., CA (USA). Solid-State Electronics Lab.)

1990-11-01T23:59:59.000Z

100

High Efficiency, Illumination Quality OLEDs for Lighting  

SciTech Connect (OSTI)

The goal of the program was to demonstrate a 45 lumen per watt white light device based upon the use of multiple emission colors through the use of solution processing. This performance level is a dramatic extension of the team's previous 15 LPW large area illumination device. The fundamental material system was based upon commercial polymer materials. The team was largely able to achieve these goals, and was able to deliver to DOE a 90 lumen illumination source that had an average performance of 34 LPW a 1000 cd/m{sup 2} with peak performances near 40LPW. The average color temperature is 3200K and the calculated CRI 85. The device operated at a brightness of approximately 1000cd/m{sup 2}. The use of multiple emission colors particularly red and blue, provided additional degrees of design flexibility in achieving white light, but also required the use of a multilayered structure to separate the different recombination zones and prevent interconversion of blue emission to red emission. The use of commercial materials had the advantage that improvements by the chemical manufacturers in charge transport efficiency, operating life and material purity could be rapidly incorporated without the expenditure of additional effort. The program was designed to take maximum advantage of the known characteristics of these material and proceeded in seven steps. (1) Identify the most promising materials, (2) assemble them into multi-layer structures to control excitation and transport within the OLED, (3) identify materials development needs that would optimize performance within multilayer structures, (4) build a prototype that demonstrates the potential entitlement of the novel multilayer OLED architecture (5) integrate all of the developments to find the single best materials set to implement the novel multilayer architecture, (6) further optimize the best materials set, (7) make a large area high illumination quality white OLED. A photo of the final deliverable is shown. In 2003, a large area, OLED based illumination source was demonstrated that could provide light with a quality, quantity, and efficiency on par with what can be achieved with traditional light sources. The demonstration source was made by tiling together 16 separate 6-inch x 6-inch blue-emitting OLEDs. The efficiency, total lumen output, and lifetime of the OLED based illumination source were the same as what would be achieved with an 80 watt incandescent bulb. The devices had an average efficacy of 15 LPW and used solution-processed OLEDs. The individual 6-inch x 6-inch devices incorporated three technology strategies developed specifically for OLED lighting -- downconversion for white light generation, scattering for outcoupling efficiency enhancement, and a scalable monolithic series architecture to enable large area devices. The downconversion approach consists of optically coupling a blue-emitting OLED to a set of luminescent layers. The layers are chosen to absorb the blue OLED emission and then luminescence with high efficiency at longer wavelengths. The composition and number of layers are chosen so that the unabsorbed blue emission and the longer wavelength re-emission combine to make white light. A downconversion approach has the advantage of allowing a wide variety of colors to be made from a limited set of blue emitters. In addition, one does not have to carefully tune the emission wavelength of the individual electro-luminescent species within the OLED device in order to achieve white light. The downconversion architecture used to develop the 15LPW large area light source consisted of a polymer-based blue-emitting OLED and three downconversion layers. Two of the layers utilized perylene based dyes from BASF AG of Germany with high quantum efficiency (>98%) and one of the layers consisted of inorganic phosphor particles (Y(Gd)AG:Ce) with a quantum efficiency of {approx}85%. By independently varying the optical density of the downconversion layers, the overall emission spectrum could be adjusted to maximize performance for lighting (e.g. blackbody temp

Joseph Shiang; James Cella; Kelly Chichak; Anil Duggal; Kevin Janora; Chris Heller; Gautam Parthasarathy; Jeffery Youmans; Joseph Shiang

2008-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Mechanism of oxygen reduction reaction on transition metal oxide catalysts for high temperature fuel cells  

E-Print Network [OSTI]

The solid oxide fuel cell (SOFC) with its high energy conversion efficiency, low emissions, silent operation and its ability to utilize commercial fuels has the potential to create a large impact on the energy landscape. ...

La O', Gerardo Jose Cordova

2008-01-01T23:59:59.000Z

102

Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Abstract: In this work we present a combined experimental and theoretical investigation of...

103

Oxidation catalyst  

DOE Patents [OSTI]

The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

2010-11-09T23:59:59.000Z

104

Highly Efficient Silicon Light Emitting Diode  

E-Print Network [OSTI]

silicon light-emitting diodes (LED) that efficiently emit photons with energy around the silicon bandgap

Leminh Holleman Wallinga; P. Leminh; J. Holleman; H. Wallinga

2000-01-01T23:59:59.000Z

105

Catalyst system comprising a first catalyst system tethered to a supported catalyst  

DOE Patents [OSTI]

The present invention provides new catalyst formats which comprise a supported catalyst tethered to a second and different catalyst by a suitable tethering ligand. A preferred system comprises a heterogeneous supported metal catalyst tethered to a homogeneous catalyst. This combination of homogeneous and heterogeneous catalysts has a sufficient lifetime and unusually high catalytic activity in arene hydrogenations, and potentially many other reactions as well, including, but not limited to hydroformylation, hydrosilication, olefin oxidation, isomerization, hydrocyanidation, olefin metathesis, olefin polymerization, carbonylation, enantioselective catalysis and photoduplication. These catalysts are easily separated from the products, and can be reused repeatedly, making these systems very economical. 2 figs.

Angelici, R.J.; Gao, H.

1998-08-04T23:59:59.000Z

106

High efficiency Brayton cycles using LNG  

DOE Patents [OSTI]

A modified, closed-loop Brayton cycle power conversion system that uses liquefied natural gas as the cold heat sink media. When combined with a helium gas cooled nuclear reactor, achievable efficiency can approach 68 76% (as compared to 35% for conventional steam cycle power cooled by air or water). A superheater heat exchanger can be used to exchange heat from a side-stream of hot helium gas split-off from the primary helium coolant loop to post-heat vaporized natural gas exiting from low and high-pressure coolers. The superheater raises the exit temperature of the natural gas to close to room temperature, which makes the gas more attractive to sell on the open market. An additional benefit is significantly reduced costs of a LNG revaporization plant, since the nuclear reactor provides the heat for vaporization instead of burning a portion of the LNG to provide the heat.

Morrow, Charles W. (Albuquerque, NM)

2006-04-18T23:59:59.000Z

107

Mobile Source Air Toxics (MSATs) from High Efficiency Clean Combustion: Catalytic Exhaust Treatment Effects  

SciTech Connect (OSTI)

High Efficiency Clean Combustion (HECC) strategies such as homogenous charge compression ignition (HCCI) and pre-mixed charge compression ignition (PCCI) offer much promise for the reduction of NOx and PM from diesel engines. While delivering low PM and low NOx, these combustion modes often produce much higher levels of CO and HC than conventional diesel combustion modes. In addition, partially oxygenated species such as formaldehyde (an MSAT) and other aldehydes increase with HECC modes. The higher levels of CO and HCs have the potential to compromise the performance of the catalytic aftertreatment, specifically at low load operating points. As HECC strategies become incorporated into vehicle calibrations, manufacturers need to avoid producing MSATs in higher quantities than found in conventional combustion modes. This paper describes research on two different HECC strategies, HCCI and PCCI. Engine-out data for several MSAT species (formaldehyde, acetaldehyde, benzene, toluene, ethylbenzene, xylenes, naphthalene, PAHs, diesel PM) as well as other HC species are presented and compared when possible with conventional operation. In addition, catalyst-out values were measured to assess the destruction of individual MSATs over the catalyst. At low engine loads, MSATs were higher and catalyst performance was poorer. Particle sizing results identify large differences between PM from conventional and HECC operation.

Storey, John Morse [ORNL; Lewis Sr, Samuel Arthur [ORNL; Parks, II, James E [ORNL; Barone, Teresa L [ORNL; Prikhodko, Vitaly Y [ORNL

2008-01-01T23:59:59.000Z

108

High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...  

Broader source: Energy.gov (indexed) [DOE]

More Documents & Publications High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 High-Efficiency Receivers for Supercritical...

109

A University Consortium on Efficient and Clean High-Pressure...  

Broader source: Energy.gov (indexed) [DOE]

Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines A University Consortium on Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines 2010 DOE Vehicle Technologies and...

110

Vehicle Technologies Office Merit Review 2014: High Efficiency...  

Broader source: Energy.gov (indexed) [DOE]

High Efficiency Clean Combustion in Multi-Cylinder Light-Duty Engines Vehicle Technologies Office Merit Review 2014: High Efficiency Clean Combustion in Multi-Cylinder Light-Duty...

111

High Efficiency Organic Light Emitting Devices for Lighting  

SciTech Connect (OSTI)

Incorporate internal scattering layers and microlens arrays in high efficiency OLED to achieve up to 70% EQE.

So, Franky; Tansu, Nelson; Gilchrist, James

2013-06-30T23:59:59.000Z

112

Simulation of High Efficiency Clean Combustion Engines and Detailed...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

ongoing work exploring fuel chemistry, analysis of and improving simulation methodologies for high efficiency clean combustion regimes, and computational performance...

113

Finding the Next Big Thing(s) in Building Energy Efficiency: HIT Catalyst and the Technology Demo Program  

Broader source: Energy.gov [DOE]

Learn how the Department prioritizes high impact technologies (HITs) to advance energy efficiency. Hear from a Better Buildings program participant who is working with Department staff to test promising technologies in buildings. Learn what they are finding and how you can get involved.

114

HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS  

E-Print Network [OSTI]

) · Solar (Solar thermal, Photovoltaic) · Renewables (Hydropower, Geothermal, Wind, Biomass) Nuclear power power generation ­ Electrolysis · Overall efficiency approximately 25-30% (efficiency of electric power · Splits water at moderate temperatures (~700-900°C vs ~5,000°C for thermolysis) · Plant efficiencies

115

White LED with High Package Extraction Efficiency  

SciTech Connect (OSTI)

The goal of this project is to develop a high efficiency phosphor converting (white) Light Emitting Diode (pcLED) 1-Watt package through an increase in package extraction efficiency. A transparent/translucent monolithic phosphor is proposed to replace the powdered phosphor to reduce the scattering caused by phosphor particles. Additionally, a multi-layer thin film selectively reflecting filter is proposed between blue LED die and phosphor layer to recover inward yellow emission. At the end of the project we expect to recycle approximately 50% of the unrecovered backward light in current package construction, and develop a pcLED device with 80 lm/W{sub e} using our technology improvements and commercially available chip/package source. The success of the project will benefit luminous efficacy of white LEDs by increasing package extraction efficiency. In most phosphor-converting white LEDs, the white color is obtained by combining a blue LED die (or chip) with a powdered phosphor layer. The phosphor partially absorbs the blue light from the LED die and converts it into a broad green-yellow emission. The mixture of the transmitted blue light and green-yellow light emerging gives white light. There are two major drawbacks for current pcLEDs in terms of package extraction efficiency. The first is light scattering caused by phosphor particles. When the blue photons from the chip strike the phosphor particles, some blue light will be scattered by phosphor particles. Converted yellow emission photons are also scattered. A portion of scattered light is in the backward direction toward the die. The amount of this backward light varies and depends in part on the particle size of phosphors. The other drawback is that yellow emission from phosphor powders is isotropic. Although some backward light can be recovered by the reflector in current LED packages, there is still a portion of backward light that will be absorbed inside the package and further converted to heat. Heat generated in the package may cause a deterioration of encapsulant materials, affecting the performance of both the LED die and phosphor, leading to a decrease in the luminous efficacy over lifetime. Recent studies from research groups at Rensselaer Polytechnic Institute found that, under the condition to obtain a white light, about 40% of the light is transmitted outward of the phosphor layer and 60% of the light is reflected inward.1,2 It is claimed that using scattered photon extraction (SPE) technique, luminous efficacy is increased by 60%. In this project, a transparent/translucent monolithic phosphor was used to replace the powdered phosphor layer. In the normal pcLED package, the powdered phosphor is mixed with silicone either to be deposited on the top of LED die forming a chip level conversion (CLC) white LED or to be casted in the package forming a volume conversion white LED. In the monolithic phosphors there are no phosphor powder/silicone interfaces so it can reduce the light scattering caused by phosphor particles. Additionally, a multi-layer thin film selectively reflecting filter is inserted in the white LED package between the blue LED die and phosphor layer. It will selectively transmit the blue light from the LED die and reflect the phosphor's yellow inward emission outward. The two technologies try to recover backward light to the outward direction in the pcLED package thereby improving the package extraction efficiency.

Yi Zheng; Matthew Stough

2008-09-30T23:59:59.000Z

116

Tailored Materials for High Efficiency CIDI Engines  

SciTech Connect (OSTI)

The overall goal of the project, Tailored Materials for High Efficiency Compression Ignition Direct Injection (CIDI) Engines, is to enable the implementation of new combustion strategies, such as homogeneous charge compression ignition (HCCI), that have the potential to significantly increase the energy efficiency of current diesel engines and decrease fuel consumption and environmental emissions. These strategies, however, are increasing the demands on conventional engine materials, either from increases in peak cylinder pressure (PCP) or from increases in the temperature of operation. The specific objective of this project is to investigate the application of a new material processing technology, friction stir processing (FSP), to improve the thermal and mechanical properties of engine components. The concept is to modify the surfaces of conventional, low-cost engine materials. The project focused primarily on FSP in aluminum materials that are compositional analogs to the typical piston and head alloys seen in small- to mid-sized CIDI engines. Investigations have been primarily of two types over the duration of this project: (1) FSP of a cast hypoeutectic Al-Si-Mg (A356/357) alloy with no introduction of any new components, and (2) FSP of Al-Cu-Ni alloys (Alloy 339) by physically stirring-in various quantities of carbon nanotubes/nanofibers or carbon fibers. Experimental work to date on aluminum systems has shown significant increases in fatigue lifetime and stress-level performance in aluminum-silicon alloys using friction processing alone, but work to demonstrate the addition of carbon nanotubes and fibers into aluminum substrates has shown mixed results due primarily to the difficulty in achieving porosity-free, homogeneous distributions of the particulate. A limited effort to understand the effects of FSP on steel materials was also undertaken during the course of this project. Processed regions were created in high-strength, low-alloyed steels up to 0.5 in. deep that showed significant grain refinement and homogeneous microstructures favorable to increased fracture toughness and fatigue performance. The final tasks of the project demonstrated that the FSP concept can be applied to a relevant part geometry by fabricating diesel piston crowns with FSP regions applied selectively to the edge of the bowl rim. This area of the piston typically suffers from conditions at high PCP that cause severe thermal fatigue issues. It is expected that, given the data from coupon testing, the durability of pistons modified by FSP will allow much higher fatigue lifetime and potentially also greater resistance to elevated stress-level effects on fatigue.

Grant, G.J.; Jana, S.

2012-03-30T23:59:59.000Z

117

Graphene-Polypyrrole Nanocomposite as a Highly Efficient and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Graphene-Polypyrrole Nanocomposite as a Highly Efficient and Low Cost Electrically Switched Ion Exchanger for Removing ClO4- Graphene-Polypyrrole Nanocomposite as a Highly...

118

Technology and System Level Demonstration of Highly Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Merit Review 2014: Technology and System Level Demonstration of Highly Efficient and Clean, Diesel Powered Class 8 Trucks Technology and System Level Demonstration of Highly...

119

High SO2 Removal Efficiency Testing  

SciTech Connect (OSTI)

This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, "High Efficiency SO2 Removal Testing", for the time period 1 January through 31 March 1997. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO2 removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The "base" project involved testing at the Tampa Electric Company?s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy?s Merom Station (Option I), Southwestern Electric Power Company?s Pirkey Station (Option II), PSI Energy?s Gibson Station (Option III), Duquesne Light?s Elrama Station (Option IV), and New York State Electric and Gas Corporation?s (NYSEG) Kintigh Station (Option V). The originally planned testing has been completed for all six sites. However, additional testing is planned at the Big Bend Station. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the second quarter of calendar year 1997. Section 5 contains a brief acknowledgement.

Gary Blythe

1997-04-23T23:59:59.000Z

120

Computationally Efficient Modeling of High-Efficiency Clean Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Volvo; multi-zone cycle simulation, OpenFOAM model development Bosch; High Performance Computing of HCCISI transition Delphi; direct injection GE Research; new...

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy  

SciTech Connect (OSTI)

The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

2007-08-01T23:59:59.000Z

122

Progressive flow cracking of coal/oil mixtures with high metals content catalyst  

SciTech Connect (OSTI)

This patent describes a process for economically producing liquid fuel products at least partly from coal. It comprises: introducing a progressive flow catalytic cracking zone a charge stock comprising a pumpable mixture of solid, particulate coal and carbo-metallic oil and forming within the zone a stream having a linear velocity of at least about 25 feet per second. The stream comprising the charge stock and a hydrocarbon zeolite cracking catalyst promoting dehydrogenation of the charge stock; forming mobile hydrogen within the zone by the dehydrogenation; introducing the mobile hydrogen into the stream by dehydrogenation of the charge stock in the absence of added molecular hydrogen, thereby producing liquid products from the charge stock while laying down coke on the hydrocarbon cracking catalyst in the range of about 0.3% to about 3% and thereby producing spent catalyst; separating from the spent catalyst the liquid products.

Zandona, O.J.

1989-10-10T23:59:59.000Z

123

MIXED PHASE COMPRESSION HIGH EFFICIENCY HEAT PUMP.  

E-Print Network [OSTI]

??The objective of this thesis is the design and realization of a higher efficiency air source heat pump. The improved pump???s operating cost must rival… (more)

Chan, WenYen

2014-01-01T23:59:59.000Z

124

High Efficiency Organic Multilayer Photodetectors based on Singlet Fission ....................................................................................................................................................................................  

E-Print Network [OSTI]

.........................................................................................................................PH.14 High-efficiency, Low-cost Photovoltaics using III-V on Silicon Tandem CellsPhotonics High Efficiency Organic Multilayer Photodetectors based on Singlet Fission.........................................................................................................................PH.2 Efficiently Coupling Light to Superconducting Nanowire Single-photon Detectors

Reif, Rafael

125

Highly-basic large-pore zeolite catalysts for NOx reduction at low temperatures  

DOE Patents [OSTI]

A high-surface-area (greater than 600 m2/g), large-pore (pore size diameter greater than 6.5 angstroms), basic zeolite having a structure such as an alkali metal cation-exchanged Y-zeolite is employed to convert NO.sub.x contained in an oxygen-rich engine exhaust to N.sub.2 and O.sub.2. Preferably, the invention relates to a two-stage method and apparatus for NO.sub.x reduction in an oxygen-rich engine exhaust such as diesel engine exhaust that includes a plasma oxidative stage and a selective reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and added hydrocarbons. The second stage employs a lean-NO.sub.x catalyst including the basic zeolite at relatively low temperatures to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O.

Penetrante, Bernardino M.; Brusasco, Raymond M.; Merritt, Bernard T.; Vogtlin, George E.

2004-02-03T23:59:59.000Z

126

Design of high efficiency Mid IR QCL lasers  

E-Print Network [OSTI]

The proposed research is a study of designing high-efficiency Mid-IR quantum cascade lasers (QCL). This thesis explores "injector-less" designs for achieving lower voltage defects and improving wall plug efficiencies through ...

Hsu, Allen Long

2008-01-01T23:59:59.000Z

127

Case Studies of High Efficiency Electric Motor Applicability  

E-Print Network [OSTI]

Much has been written about the advantages and disadvantages of high efficiency electric motors. For a given motor application it is possible to find literature that enables a plant engineer to make an informed choice between a standard efficiency...

Wagner, J. R.

128

High efficiency pulse motor drive for robotic propulsion  

E-Print Network [OSTI]

The goal of this research is to improve the power efficiency of robotic locomotion through the use of series elastic actuation, with a focus on swimming motion. To achieve high efficiency, electromechanical drives need to ...

Sun, Zhen, M.S. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

129

High efficiency quasi-monochromatic infrared emitter  

SciTech Connect (OSTI)

Incandescent radiation sources are widely used as mid-infrared emitters owing to the lack of alternative for compact and low cost sources. A drawback of miniature hot systems such as membranes is their low efficiency, e.g., for battery powered systems. For targeted narrow-band applications such as gas spectroscopy, the efficiency is even lower. In this paper, we introduce design rules valid for very generic membranes demonstrating that their energy efficiency for use as incandescent infrared sources can be increased by two orders of magnitude.

Brucoli, Giovanni; Besbes, Mondher; Benisty, Henri, E-mail: henri.benisty@institutoptique.fr; Greffet, Jean-Jacques [Laboratoire Charles Fabry, UMR 8501, Institut d’Optique, CNRS, Université Paris-Sud 11, 2, Avenue Augustin Fresnel, 91127 Palaiseau Cedex (France); Bouchon, Patrick; Haïdar, Riad [Office National d’Études et de Recherches Aérospatiales, Chemin de la Hunière, 91761 Palaiseau (France)

2014-02-24T23:59:59.000Z

130

Recent Progress in the Development of High Efficiency Thermoelectrics...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation Quantum Well Thermoelectrics and Waste Heat Recovery Scale Up of Si...

131

Materials-Enabled High-Efficiency Diesel Engines (CRADA with...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Engines (CRADA with Caterpillar) Materials-Enabled High-Efficiency Diesel Engines (CRADA with Caterpillar) 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit...

132

Project Profile: Development and Productization of High-Efficiency...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Cost Building-Integrated PV Shingles Using Monocrystalline Silicon Thin-Film Solar Cells Project Profile: Development and Productization of High-Efficiency, Low-Cost...

133

Energy Savings Potential and Opportunities for High-Efficiency...  

Broader source: Energy.gov (indexed) [DOE]

sponsored this assignment and provided comments on draft versions of the report. iii Energy Savings Potential and Opportunities for High-Efficiency Electric Motors in Residential...

134

Advanced CFD Models for High Efficiency Compression Ignition...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for high efficiency compression-ignition engines can be used to show how turbulence-chemistry interactions influence autoignition and combustion. p-19raja.pdf More Documents &...

135

advanced high efficiency: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to 100 devices, including memory and logic. Josephson junctions are widely used in superconduct- ing quantum Nadgorny, Boris 65 Design of Efficient Java Communications for High...

136

Field Demonstration of High Efficiency Ultra-Low-Temperature...  

Energy Savers [EERE]

Field Demonstration of High Efficiency Gas Heaters Comparison of Real World Energy Consumption to Models and DOE Test Procedures Building Science "Power Words"...

137

Evaluation of High Efficiency Clean Combustion (HECC) Strategies...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion (HECC) Strategies for Meeting Future Emissions Regulations in Light-Duty Engines Evaluation of High Efficiency Clean Combustion (HECC) Strategies for Meeting Future...

138

High Efficiency Engine Systems Development and Evaluation | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High Efficiency Engine Systems Development and Evaluation 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

139

Autothermal reforming catalyst and process  

SciTech Connect (OSTI)

High activity steam reforming catalysts are described particularly adapted for use in autothermal reforming processes. A rhodium catalyst on a calcium oxide impregnated alumina substrate allow the autothermal reforming process to take place with substantially no carbon plugging at oxygen to carbon ratios below what had been considered critical for avoiding carbon plugging of the catalyst in the past.

Setzer, H. J.; Karavolis, S.; Lesieur, R. R.; Wnuck, W. G.

1984-09-25T23:59:59.000Z

140

Experimental study of a high efficiency gyrotron oscillator  

E-Print Network [OSTI]

High power, high frequency gyrotrons used in plasma heating must achieve the highest possible efficiency in order to reduce system size and cost and to minimize thermal and mechanical problems. This thesis presents an ...

Choi, Eunmi, Ph. D. Massachusetts Institute of Technology

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS  

SciTech Connect (OSTI)

Fischer-Tropsch (FT) synthesis to convert syngas (CO + H{sub 2}) derived from natural gas or coal to liquid fuels and wax is a well-established technology. For low H{sub 2} to CO ratio syngas produced from CO{sub 2} reforming of natural gas or from gasification of coal, the use of Fe catalysts is attractive because of their high water gas shift activity in addition to their high FT activity. Fe catalysts are also attractive due to their low cost and low methane selectivity. Because of the highly exothermic nature of the FT reaction, there has been a recent move away from fixed-bed reactors toward the development of slurry bubble column reactors (SBCRs) that employ 30 to 90 {micro}m catalyst particles suspended in a waxy liquid for efficient heat removal. However, the use of FeFT catalysts in an SBCR has been problematic due to severe catalyst attrition resulting in fines that plug the filter employed to separate the catalyst from the waxy product. Fe catalysts can undergo attrition in SBCRs not only due to vigorous movement and collisions but also due to phase changes that occur during activation and reaction.

K. Jothimurugesan; James G. Goodwin, Jr.; Santosh K. Gangwal

1999-10-01T23:59:59.000Z

142

Synthesis of Highly Efficient Flame Retardant High-Density Polyethylene Nanocomposites with Inorgano-Layered Double  

E-Print Network [OSTI]

Synthesis of Highly Efficient Flame Retardant High-Density Polyethylene Nanocomposites, Harbin 150080, P. R. China ABSTRACT: High-density polyethylene (HDPE) polymer nanocomposites containing. INTRODUCTION High density polyethylene (HDPE) has good electrical proper- ties, high stiffness, and tensile

Guo, John Zhanhu

143

Design of a high activity and selectivity alcohol catalyst. Final status report and summary of accomplishments  

SciTech Connect (OSTI)

This final DOE report for grant award number DE-FG22-90PC 90291 presents the results of our efforts to better understand the Rh-Mo/{gamma}-Al{sub 2}O3 catalytic system for the hydrogenation of carbon monoxide and carbon dioxide to selectively form oxygenated products. The content of this report is divided into three major sections and a fourth, concluding section which addresses our major research accomplishments, as well as documents the most significant publications and presentations associated with this grant. The three main sections which make up the body of this report are presented in the in form of manuscripts which, in turn, summarize our progress in three areas of this project. The three body sections are organized as follows: Section I--Evidence for site isolation in Rh-Mo bimetallic catalysts derived from organometallic clusters; Section II--Surface Chemistry of Rh-Mo/{gamma}-Al{sub 2}O{sub 3}: An analysis of surface acidity; and Section III--Comparative study of Rh/Al{sub 2}O{sub 3} and Rh-Mo/Al{sub 2}O{sub 3} Catalysts. Section IV summarizes major accomplishments. The content of this final report is meant to generally highlight our progress in both characterizing the nature of the Rh-Mo/Al{sub 2}O{sub 3} system and probing its reactivity for insight on the oxygenate synergy present in this class of catalysts.

Foley, H.C.; Mills, G.A.

1994-07-15T23:59:59.000Z

144

A versatile elevated-pressure reactor combined with an ultrahigh vacuum surface setup for efficient testing of model and powder catalysts under clean gas-phase conditions  

SciTech Connect (OSTI)

A small-volume reaction cell for catalytic or photocatalytic testing of solid materials at pressures up to 1000 Torr has been coupled to a surface-science setup used for standard sample preparation and characterization under ultrahigh vacuum (UHV). The reactor and sample holder designs allow easy sample transfer from/to the UHV chamber, and investigation of both planar and small amounts of powder catalysts under the same conditions. The sample is heated with an infrared laser beam and its temperature is measured with a compact pyrometer. Combined in a regulation loop, this system ensures fast and accurate temperature control as well as clean heating. The reaction products are automatically sampled and analyzed by mass spectrometry and/or gas chromatography (GC). Unlike previous systems, our GC apparatus does not use a recirculation loop and allows working in clean conditions at pressures as low as 1 Torr while detecting partial pressures smaller than 10{sup ?4} Torr. The efficiency and versatility of the reactor are demonstrated in the study of two catalytic systems: butadiene hydrogenation on Pd(100) and CO oxidation over an AuRh/TiO{sub 2} powder catalyst.

Morfin, Franck; Piccolo, Laurent [Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), UMR 5256 CNRS and Université Lyon 1, 2 avenue Albert Einstein, F-69626 Villeurbanne (France)] [Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), UMR 5256 CNRS and Université Lyon 1, 2 avenue Albert Einstein, F-69626 Villeurbanne (France)

2013-09-15T23:59:59.000Z

145

Oxidative dehydrogenation of propane over vanadia-based catalysts supported on high-surface-area mesoporous MgAl2O4  

SciTech Connect (OSTI)

The oxidative dehydrogenation of propane to propene was investigated over a series of novel vanadia-based catalysts supported on high-surface-area magnesium spinel. A mesoporous MgAl2O4 support was synthesized via a low-temperature sol gel process involving the heterobimetallic alkoxide precursor, Mg[Al(O iPr)4]2. A high-purity catalyst support was obtained after calcination at 1173 K under O2 atmosphere and active vanadia catalysts were prepared from the thermolysis of OV(O tBu)3 after grafting onto the spinel support. MgAl2O4-supported catalysts prepared in this manner have BET surface areas of 234 245 m2/g. All of the catalysts were characterized by X-ray powder diffraction, and Raman, solid-state NMR, and diffuse-reflectance UV vis spectroscopy. At all vanadium loadings the vanadia supported on MgAl2O4 exist as a combination of isolated monovanadate and tetrahedral polyvanadate species. As the vanadium surface density increases for these catalysts the ratio of polyvanadate species to isolated monovanadate species increases. In addition, as the vanadium surface density increases for these catalysts, the initial rate of propane ODH per V atom increases and reaches a maximum value at 6 VOx/nm2. Increasing the vanadium surface density past this point results in a decrease in the rate of propane ODH owing to the formation of multilayer species in which subsurface vanadium atoms are essentially rendered catalytically inactive. The initial propene selectivity increases with increasing vanadium surface density and reaches a plateau of {approx}95 percent for the V/MgAl catalysts. Rate coefficients for propane ODH (k1), propane combustion (k2), and propene combustion (k3) were calculated for these catalysts. The value of k1 increases with increasing VOx surface density, reaching a maximum at about 5.5 VOx/nm2. On the other hand, the ratio (k2/k1) for V/MgAl decreases with increasing VOx surface density. The ratio (k3/k1) for both sets of catalysts shows no dependence on the vanadia surface density. The observed trends in k1, (k2/k1), and (k3/k1) are discussed in terms of the surface structure of the catalyst.

Evans, Owen R.; Bell, Alexis T.; Tilley, T. Don

2004-06-01T23:59:59.000Z

146

Low Cost, High Efficiency Reversible Fuel Cell Systems  

E-Print Network [OSTI]

Low Cost, High Efficiency Reversible Fuel Cell Systems DE-FC36-99GO-10455 POC: Doug Hooker Dr Approach: System Concept Fuel Cell Subsystem Battery Subsystem Converter Electrolyzer Subsystem Inverter, -- (216) 541(216) 541--10001000 Slide 5 Approach: Challenges ·Electrolyzer Subsystem Efficiency ·Fuel Cell

147

Design Strategies for Ultra-high Efficiency Photovoltaics  

E-Print Network [OSTI]

Design Strategies for Ultra-high Efficiency Photovoltaics Thesis by Emily Cathryn Warmann, who reminds me that this is fun and interesting. iv #12;Abstract While concentrator photovoltaic cells, the over all module efficiency drops to only 34 to 36%. T

Winfree, Erik

148

DEVELOPMENT OF A HIGH EFFICIENCY, AUTOMATIC DEFROSTING REFRIGERATOR-FREEZER  

E-Print Network [OSTI]

#12;DEVELOPMENT OF A HIGH EFFICIENCY, AUTOMATIC DEFROSTING REFRIGERATOR-FREEZER Richard F. Topping-efficient refrigerator- freezer prototype involving the Department of Energy's Oak Ridge National Laboratory, Arthur D refrigerator-freezers. The resulting 16 cubic foot prototype uses significantly less energy than the most

Oak Ridge National Laboratory

149

Pd-porphyrin functionalized ionic liquid-modified mesoporous SBA-15: An efficient and recyclable catalyst for solvent-free Heck reaction  

SciTech Connect (OSTI)

The Pd-porphyrin functionalized ionic liquid could be covalently anchored in the channels of mesoporous SBA-15 through ion-pair electrostatic interaction between imidazolium-cationic and Pd-porphyrin-anionic moieties. Such modified SBA-15 materials were prepared successfully via a post-synthesis (surface sol-gel polymerization) or a one-pot sol-gel procedure, which were characterized by powder X-ray diffraction, UV-visible spectroscopy, Fourier transform infrared spectroscopy, N{sub 2} sorption, elemental analysis, and transmission electron microscopy. The modified SBA-15 materials are efficient and recyclable catalysts for cross-coupling of aryl iodides or activated aryl bromides with ethyl acrylate without activity loss and Pd leaching even after 9 runs.

Zhang, Jing; Zhao, Guo-Feng [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062 (China)] [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062 (China); Popovic, Zora [General and Inorganic Laboratory, Chemistry Department, University of Zagreb, HR-10000 Zagreb (Croatia)] [General and Inorganic Laboratory, Chemistry Department, University of Zagreb, HR-10000 Zagreb (Croatia); Lu, Yong [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062 (China)] [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062 (China); Liu, Ye, E-mail: yliu@chem.ecnu.edu.cn [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062 (China)] [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Department, East China Normal University, Shanghai 200062 (China)

2010-11-15T23:59:59.000Z

150

High Efficiency Burners by Retrofit - A Simple Inexpensive Way to Improve Combustion Efficiency  

E-Print Network [OSTI]

Existing direct fired process heaters and steam boilers can have their efficiencies remarkably improved, and thus cut the fuel bill, by conversion from conventional type natural draft burners to high intensity, "forced draft" type burners...

Rogers, W. T.

1980-01-01T23:59:59.000Z

151

III-V High-Efficiency Multijunction Photovoltaics (Fact Sheet)  

SciTech Connect (OSTI)

Capabilities fact sheet that includes scope, core competencies and capabilities, and contact/web information for III-V High-Efficiency Multijunction Photovoltaics at the National Center for Photovoltaics.

Not Available

2011-06-01T23:59:59.000Z

152

Study of Highly Selective and Efficient Thiol Derivatization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

derived from living cells by MS method. Citation: Xu K, YW Zhang, B Tang, J Laskin, PJ Roach, and H Chen.2010."Study of Highly Selective and Efficient Thiol Derivatization using...

153

Emerging High-Efficiency Low-Cost Solar Cell Technologies  

E-Print Network [OSTI]

. A Manufacturing Cost Analysis Relevant to Photovoltaic Cells Fabricated with IIIEmerging High-Efficiency Low-Cost Solar Cell Technologies Mike McGehee Materials Science and Engineering Center for Advanced Molecular Photovoltaics Bay Area Photovoltaic Consortium Precourt Institute

McGehee, Michael

154

Compact and highly efficient laser pump cavity  

DOE Patents [OSTI]

A new, compact, side-pumped laser pump cavity design which uses non-conventional optics for injection of laser-diode light into a laser pump chamber includes a plurality of elongated light concentration channels. In one embodiment, the light concentration channels are compound parabolic concentrators (CPC) which have very small exit apertures so that light will not escape from the pumping chamber and will be multiply reflected through the laser rod. This new design effectively traps the pump radiation inside the pump chamber that encloses the laser rod. It enables more uniform laser pumping and highly effective recycle of pump radiation, leading to significantly improved laser performance. This new design also effectively widens the acceptable radiation wavelength of the diodes, resulting in a more reliable laser performance with lower cost.

Chang, Jim J. (Dublin, CA); Bass, Isaac L. (Castro Valley, CA); Zapata, Luis E. (Livermore, CA)

1999-01-01T23:59:59.000Z

155

Catalytic Synthesis of Oxygenates: Mechanisms, Catalysts and Controlling Characteristics  

SciTech Connect (OSTI)

This research focused on catalytic synthesis of unsymmetrical ethers as a part of a larger program involving oxygenated products in general, including alcohols, ethers, esters, carboxylic acids and their derivatives that link together environmentally compliant fuels, monomers, and high-value chemicals. The catalysts studied here were solid acids possessing strong Br�������¸nsted acid functionalities. The design of these catalysts involved anchoring the acid groups onto inorganic oxides, e.g. surface-grafted acid groups on zirconia, and a new class of mesoporous solid acids, i.e. propylsulfonic acid-derivatized SBA-15. The former catalysts consisted of a high surface concentration of sulfate groups on stable zirconia catalysts. The latter catalyst consists of high surface area, large pore propylsulfonic acid-derivatized silicas, specifically SBA-15. In both cases, the catalyst design and synthesis yielded high concentrations of acid sites in close proximity to one another. These materials have been well-characterization in terms of physical and chemical properties, as well as in regard to surface and bulk characteristics. Both types of catalysts were shown to exhibit high catalytic performance with respect to both activity and selectivity for the bifunctional coupling of alcohols to form ethers, which proceeds via an efficient SN2 reaction mechanism on the proximal acid sites. This commonality of the dual-site SN2 reaction mechanism over acid catalysts provides for maximum reaction rates and control of selectivity by reaction conditions, i.e. pressure, temperature, and reactant concentrations. This research provides the scientific groundwork for synthesis of ethers for energy applications. The synthesized environmentally acceptable ethers, in part derived from natural gas via alcohol intermediates, exhibit high cetane properties, e.g. methylisobutylether with cetane No. of 53 and dimethylether with cetane No. of 55-60, or high octane properties, e.g. diisopropylether with blending octane No. of 105, and can replace aromatics in liquid fuels.

Kamil Klier; Richard G. Herman

2005-11-30T23:59:59.000Z

156

Clustering of metal atoms in organic media. 9. High-activity Ni/MgO catalysts prepared by metal vapor methods. Surface area and particle size effects  

SciTech Connect (OSTI)

A metal vapor method was employed to prepare highly dispersed Ni metal catalysts (solvated metal atom dispersed = SMAD catalyst) supported on MgO. Compared with conventional Ni/MgO compositions, the SMAD catalysts showed much greater activities for all reactions studied (hydrogenolysis of methylcyclopentane, MCP; hydrogenation/hydrogenolysis of toluene, TOL; methanation of carbon monoxide, CO; dehydration of isopropyl alcohol, IPA). These high activities for the SMAD catalysts are attributed to the high surface area of Ni on MgO and the high percentage of this Ni in a zero-valent state (reduction degree). Conventional methods for preparing Ni/MgO catalysts did not yield nearly such favorable surface areas or reduction degrees. Nickel particle size effects were observed during hydrogenolysis studies of MCP and hydrogenation studies of TOL. These phenomena are explained by assuming the size of an active Ni particle to be largest for hydrogenolysis of MCP > hydrogenation of TOL > methanation of CO approx. = dehydrogenation of IPA. 8 figures, 2 tables.

Matsuo, K.; Klabunde, K.J.

1982-02-01T23:59:59.000Z

157

Epoxidation catalyst and process  

DOE Patents [OSTI]

Disclosed herein is a catalytic method of converting alkenes to epoxides. This method generally includes reacting alkenes with oxygen in the presence of a specific silver catalyst under conditions suitable to produce a yield of the epoxides. The specific silver catalyst is a silver nanocrystal having a plurality of surface planes, a substantial portion of which is defined by Miller indices of (100). The reaction is performed by charging a suitable reactor with this silver catalyst and then feeding the reactants to the reactor under conditions to carry out the reaction. The reaction may be performed in batch, or as a continuous process that employs a recycle of any unreacted alkenes. The specific silver catalyst has unexpectedly high selectivity for epoxide products. Consequently, this general method (and its various embodiments) will result in extraordinarily high epoxide yields heretofore unattainable.

Linic, Suljo (Ann Arbor, MI); Christopher, Phillip (Ann Arbor, MI)

2010-10-26T23:59:59.000Z

158

Oxyhydrochlorination catalyst  

DOE Patents [OSTI]

An improved catalyst and method for the oxyhydrochlorination of methane is disclosed. The catalyst includes a pyrogenic porous support on which is layered as active material, cobalt chloride in major proportion, and minor proportions of an alkali metal chloride and of a rare earth chloride. On contact of the catalyst with a gas flow of methane, HCl and oxygen, more than 60% of the methane is converted and of that converted more than 40% occurs as monochloromethane. Advantageously, the monochloromethane can be used to produce gasoline boiling range hydrocarbons with the recycle of HCl for further reaction. This catalyst is also of value for the production of formic acid as are analogous catalysts with lead, silver or nickel chlorides substituted for the cobalt chloride.

Taylor, Charles E. (Pittsburgh, PA); Noceti, Richard P. (Pittsburgh, PA)

1992-01-01T23:59:59.000Z

159

New US Ultra High Efficiency R&D Programme  

E-Print Network [OSTI]

Very high efficiency is an important characteristic of the value proposition for solar to electric conversion. High efficiency is the shortest path to cost-effective commercial applications and leads to new high value applications such as portable battery charging. The Defense Advanced Research Projects Agency has initiated the Very High Efficiency Solar Cell (VHESC) program to address the critical need of the soldier for power in the field. Very High Efficiency Solar Cells for portable applications1,2 that operate at greater than 55 percent efficiency in the laboratory and 50 percent in production are being developed. We are integrating the optical design with the solar cell design, and have entered previously unoccupied design space that leads to a new architecture paradigm. An integrated team effort is now underway that requires us to invent, develop and transfer to production these new solar cells. Our approach is driven by proven quantitative models for the solar cell design, the optical design and the integration of these designs. We start with a very high performance crystalline silicon solar cell platform. Examples will be presented. Initial solar cell device results are shown for devices fabricated in geometries designed for this VHESC Program.

Allen Barnett Douglas Kirkpatrick

160

Aerogels as catalysts and catalyst supports  

SciTech Connect (OSTI)

Aerogels have been used as catalysts since the 1930`s. These materials are interesting because their high surface area means more active sites for gas/ solid interactions. Aerogels have important applications as catalyst supports and are stable as well, which is a real advantage for designing catalytic materials. The author discusses some recent work in his laboratory on developing aerogels as catalytic materials. An important step in preparing these materials is supercritical extraction with CO{sub 2}. Preparation and properties of titania, niobia, and titania-zirconia systems are discussed.

Ko, E.I. [Carnegie Mellon Univ., Pittsburgh, PA (United States)

1993-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Nano Sensor Networks for Tailored Operation of Highly Efficient Gas-To-Liquid Fuels Catalysts  

E-Print Network [OSTI]

than hitherto possible by re- ducing the rate of Hydrogenation To Paraffin (HTP) reactions. Our numerical and simulation results reveal an exponential relationship be- tween reduction in rates of HTP

New South Wales, University of

162

Synergies of High-Efficiency Clean Combustion and Lean NOx Trap Catalysts |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy Strain Rate4SuperhardSuspect andCoachesConferenceGridDepartment

163

High-Efficiency Nitride-Based Photonic Crystal Light Sources  

Broader source: Energy.gov [DOE]

The University of California Santa Barbara (UCSB) is maximizing the efficiency of a white LED by enhancing the external quantum efficiency using photonic crystals to extract light that would normally be confined in a conventional structure. Ultimate efficiency can only be achieved by looking at the internal structure of light. To do this, UCSB is focusing on maximizing the light extraction efficiency and total light output from light engines driven by Gallium Nitride (GaN)-based LEDs. The challenge is to engineer large overlap (interaction) between modes and photonic crystals. The project is focused on achieving high extraction efficiency in LEDs, controlled directionality of emitted light, integrated design of vertical device structure, and nanoscale patterning of lateral structure.

164

Evaluating the potential for high thermoelectric efficiency of silver selenide  

E-Print Network [OSTI]

to the exceptionally high mobility, higher than other optimized thermoelectric materials. Although zT decreases at high refrigerants.1 Increasing the efficiency of a thermoelectric material necessitates increasing the gure of merit contribution and an electronic contribution. Thermoelectric materials used in practice have zT near 1. One

Martin, Alain

165

High Efficiency Solar Power via Separated Photo and Voltaic Pathways  

SciTech Connect (OSTI)

This project demonstrates a novel nanostructured solar cell architecture capable of achieving high efficiency levels that is relatively simple and inexpensive to manufacture. The high efficiency will be achieved by the novel structure that separates the path of the photons from the path of the generated charge carriers. In this way, the photon path can be long for maximum light absorption, while the path for carriers can be short for maximum electronic energy harvesting. The combination of maximum light absorption coupled with maximum carrier harvesting is the basis for the expected high efficiency. The project will develop high efficiency solar cell prototypes utilizing this unique nanostructured architecture. The project addresses the fundamental limitation inherent in all current solar cell designs, and which opens a pathway to development for high efficiency solar cells at low cost. Realizing this goal will result in a levelized cost of electricity in the range of 10¢/kWh, which would achieve the long-sought goal of making photovoltaic electricity cost competitive with fossil-fuel generated electricity without any governmental subsidies. This breakthrough would spur the already rapid growth in the photovoltaic industry to an explosive pace, with significant, widespread benefit to the national economy and the nation’s energy security. The initial target of the program is to develop single-junction solar cells using ultrathin amorphous silicon with the performance approaching that of single crystal silicon cells.

Michael J. Naughton

2009-02-17T23:59:59.000Z

166

High Efficiency Gas Turbines Overcome Cogeneration Project Feasibility Hurdles  

E-Print Network [OSTI]

HIGH EFFICIENCY GAS TlJR1HNES OVERCOME COGENFRATION PROJECT FEASIBILITY HURDLES JIM KING Gas Turbine Perfonumce Engineer STEVART &: STEVENSON SERVICES. INC. Houston. TelUlS ABSTRACT Cogeneration project feasibility sometimes fails... during early planning stages due to an electrical cycle efficiency which could be improved through the use of aeroderivative gas turbine engines. The aeroderivative engine offers greater degrees of freedom in terms of power augmentation through...

King, J.

167

Kieffer Paper Mill's Recycled Fiber Mill and PSI Energy's High Efficiency Motors Plan  

E-Print Network [OSTI]

efficiency would yield significant energy savings. PSI Energy was able to help Kieffer examine the economics of high efficiency motors, and through the PSI Energy High Efficiency Motors Plan encouraged Kieffer Paper Mills to purchase energy efficient motors...

Myers, J. A.

168

Diesel Oxidation Catalyst Combined to Non-Thermal Plasma: Effect on Activation Catalyst Temperature and by-products formation  

E-Print Network [OSTI]

Diesel Oxidation Catalyst Combined to Non-Thermal Plasma: Effect on Activation Catalyst Temperature efficiency together with the catalyst activation temperature when a Diesel Oxidation Catalyst (DOC) is placed downstream to a multi-plans Dielectric Barrier Discharge (DBD) reactor. In order to simulate Diesel engine

Paris-Sud XI, Université de

169

High Efficiency and High Rate Deposited Amorphous Silicon-Based Solar Cells  

E-Print Network [OSTI]

. Figure 3-1 IV curve of a UT fabricated triple cell, showing 12.7% initial, active-area efficiency. Figure1 High Efficiency and High Rate Deposited Amorphous Silicon-Based Solar Cells PHASE I Annual-junction a-Si Solar Cells with Heavily Doped Thin Interface Layers at the Tunnel Junctions Section 4 High

Deng, Xunming

170

High efficiency III-nitride light-emitting diodes  

DOE Patents [OSTI]

Tailored doping of barrier layers enables balancing of the radiative recombination among the multiple-quantum-wells in III-Nitride light-emitting diodes. This tailored doping enables more symmetric carrier transport and uniform carrier distribution which help to reduce electron leakage and thus reduce the efficiency droop in high-power III-Nitride LEDs. Mitigation of the efficiency droop in III-Nitride LEDs may enable the pervasive market penetration of solid-state-lighting technologies in high-power lighting and illumination.

Crawford, Mary; Koleske, Daniel; Cho, Jaehee; Zhu, Di; Noemaun, Ahmed; Schubert, Martin F; Schubert, E. Fred

2013-05-28T23:59:59.000Z

171

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report  

SciTech Connect (OSTI)

Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

1997-11-01T23:59:59.000Z

172

High Efficiency Adsorption Chillers: High Efficiency Adsorption Cooling Using Metal Organic Heat Carriers  

SciTech Connect (OSTI)

BEETIT Project: PNNL is incorporating significant improvements in materials that adsorb liquids or gases to design more efficient adsorption chillers. An adsorption chiller is a type of air conditioner that is powered by heat, solar or waste heat, or combustion of natural gas. Unlike typical chillers, this type has few moving parts and uses almost no electricity to operate. PNNL is designing adsorbent materials at the molecular level with at least 3 times higher refrigerant capacity and up to 20 times faster kinetics than adsorbents used in current chillers. By using the new adsorbent, PNNL is able to create a chiller that is significantly smaller, has twice the energy efficiency, and lower costs for materials and assembly time compared to conventional adsorption chillers.

None

2010-10-01T23:59:59.000Z

173

Photo-oxidation catalysts  

DOE Patents [OSTI]

Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

2009-07-14T23:59:59.000Z

174

Bandgap Engineering in High-Efficiency Multijunction Concentrator Cells  

SciTech Connect (OSTI)

This paper discusses semiconductor device research paths under investigation with the aim of reaching the milestone efficiency of 40%. A cost analysis shows that achieving very high cell efficiencies is crucial for the realization of cost-effective photovoltaics, because of the strongly leveraging effect of efficiency on module packaging and balance-of systems costs. Lattice-matched (LM) GaInP/ GaInAs/ Ge 3-junction cells have achieved the highest independently confirmed efficiency at 175 suns, 25?C, of 37.3% under the standard AM1.5D, low-AOD terrestrial spectrum. Lattice-mismatched, or metamorphic (MM), materials offer still higher potential efficiencies, if the crystal quality can be maintained. Theoretical efficiencies well over 50% are possible for a MM GaInP/ 1.17-eV GaInAs/ Ge 3-junction cell limited by radiative recombination at 500 suns. The bandgap - open circuit voltage offset, (Eg/q) - Voc, is used as a valuable theoretical and experimental tool to characterize multijunction cells with subcell bandgaps ranging from 0.7 to 2.1 eV. Experimental results are presented for prototype 6-junction cells employing an active {approx}1.1-eV dilute nitride GaInNAs subcell, with active-area efficiency greater than 23% and over 5.3 V open-circuit voltage under the 1-sun AM0 space spectrum. Such cell designs have theoretical efficiencies under the terrestrial spectrum at 500 suns concentration exceeding 55% efficiency, even for lattice-matched designs.

King, R. R.; Sherif, R. A.; Kinsey, G. S.; Kurtz, S.; Fetzer, C. M.; Edmondson, K. M.; Law, D. C.; Cotal, H. L.; Krut, D. D.; Ermer, J. H.; Karam, N. H.

2005-08-01T23:59:59.000Z

175

High Efficiency Clean Combustion in Multi-Cylinder Light-Duty...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications High-Efficiency Clean Combustion in Light-Duty Multi-Cylinder Diesel Engines High Efficiency Clean Combustion in Multi-Cylinder Light-Duty Engines High Efficiency...

176

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts  

DOE Patents [OSTI]

Highly uniform cluster based nanocatalysts supported on technologically relevant supports were synthesized for reactions of top industrial relevance. The Pt-cluster based catalysts outperformed the very best reported ODHP catalyst in both activity (by up to two orders of magnitude higher turn-over frequencies) and in selectivity. The results clearly demonstrate that highly dispersed ultra-small Pt clusters precisely localized on high-surface area supports can lead to affordable new catalysts for highly efficient and economic propene production, including considerably simplified separation of the final product. The combined GISAXS-mass spectrometry provides an excellent tool to monitor the evolution of size and shape of nanocatalyst at action under realistic conditions. Also provided are sub-nanometer gold and sub-nanometer to few nm size-selected silver catalysts which possess size dependent tunable catalytic properties in the epoxidation of alkenes. Invented size-selected cluster deposition provides a unique tool to tune material properties by atom-by-atom fashion, which can be stabilized by protective overcoats.

Vajda, Stefan (Lisle, IL), Pellin, Michael J. (Naperville, IL); Elam, Jeffrey W. (Elmhurst, IL); Marshall, Christopher L. (Naperville, IL); Winans, Randall A. (Downers Grove, IL); Meiwes-Broer, Karl-Heinz (Roggentin, GR)

2012-04-03T23:59:59.000Z

177

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts  

DOE Patents [OSTI]

Highly uniform cluster based nanocatalysts supported on technologically relevant supports were synthesized for reactions of top industrial relevance. The Pt-cluster based catalysts outperformed the very best reported ODHP catalyst in both activity (by up to two orders of magnitude higher turn-over frequencies) and in selectivity. The results clearly demonstrate that highly dispersed ultra-small Pt clusters precisely localized on high-surface area supports can lead to affordable new catalysts for highly efficient and economic propene production, including considerably simplified separation of the final product. The combined GISAXS-mass spectrometry provides an excellent tool to monitor the evolution of size and shape of nanocatalyst at action under realistic conditions. Also provided are sub-nanometer gold and sub-nanometer to few nm size-selected silver catalysts which possess size dependent tunable catalytic properties in the epoxidation of alkenes. Invented size-selected cluster deposition provides a unique tool to tune material properties by atom-by-atom fashion, which can be stabilized by protective overcoats.

Vajda, Stefan (Lisle, IL); Pellin, Michael J. (Naperville, IL); Elam, Jeffrey W. (Elmhurst, IL); Marshall, Christopher L. (Naperville, IL); Winans, Randall A. (Downers Grove, IL); Meiwes-Broer, Karl-Heinz (Roggentin, GR)

2012-03-27T23:59:59.000Z

178

Toward high-energy-density, high-efficiency, and moderate-temperature chip-scale thermophotovoltaics  

E-Print Network [OSTI]

The challenging problem of ultra-high-energy-density, high-efficiency, and small-scale portable power generation is addressed here using a distinctive thermophotovoltaic energy conversion mechanism and chip-based system ...

Pilawa-Podgurski, R. C. N.

179

Basic studies of 3-5 high efficiency cell components  

SciTech Connect (OSTI)

This project's objective is to improve our understanding of the generation, recombination, and transport of carriers within III-V homo- and heterostructures. The research itself consists of fabricating and characterizing solar cell building blocks'' such as junctions and heterojunctions as well as basic measurements of material parameters. A significant effort is also being directed at characterizing loss mechanisms in high-quality, III-V solar cells fabricated in industrial research laboratories throughout the United States. The project's goal is to use our understanding of the device physics of high-efficiency cell components to maximize cell efficiency. A related goal is the demonstration of new cell structures fabricated by molecular beam epitaxy (MBE). The development of measurement techniques and characterization methodologies is also a project objective. This report describes our progress during the fifth and final year of the project. During the past five years, we've teamed a great deal about heavy doping effects in p[sup +] and n[sup +] GaAs and have explored their implications for solar cells. We have developed an understanding of the dominant recombination losses in present-day, high-efficiency cells. We've learned to appreciated the importance of recombination at the perimeter of the cell and have developed techniques for chemically passivating such edges. Finally, we've demonstrated that films grown by molecular beam epitaxy are suitable for high-efficiency cell research.

Lundstrom, M.S.; Melloch, M.R.; Pierret, R.F.; Carpenter, M.S.; Chuang, H.L.; Dodd, P.E.; Keshavarzi, A.; Klausmeier-Brown, M.E.; Lush, G.B.; Stellwag, T.B. (Purdue Univ., Lafayette, IN (United States))

1993-01-01T23:59:59.000Z

180

LOW COST, HIGH EFFICIENCY REVERSIBLE FUEL CELL SYSTEMS  

E-Print Network [OSTI]

common hydrocarbon fuels (e.g., natural gas, propane, and bio-derived fuel) as well as hydrogenLOW COST, HIGH EFFICIENCY REVERSIBLE FUEL CELL SYSTEMS Dr. Christopher E. Milliken, Materials Group Boulevard Cleveland, Ohio 44108 216-541-1000 Abstract Fuel cell technologies are described in the 2001 DOE

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181

Accelerated deployment of nanostructured hydrotreating catalysts. Final CRADA Report.  

SciTech Connect (OSTI)

Nanomanufacturing offers an opportunity to create domestic jobs and facilitate economic growth. In response to this need, U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy issued a Research Call to develop nanomanufacturing capabilities at the National Laboratories. High performance catalysts represent a unique opportunity to deploy nanomanufacturing technologies. Re-refining of used lube oil offers an opportunity to create manufacturing jobs and decrease dependence on imported petroleum. Improved catalysts are required to produce a better quality product, decrease environmental impact, extend catalyst life, and improve overall economics of lube oil re-refining. Argonne National Laboratory (Argonne) in cooperation with Universal Lubricants, Inc. (ULI) and Chemical Engineering Partners (CEP) have carried out a Cooperative Research and Development Agreement (CRADA) to prepare nanostructured hydrotreating catalysts using atomic layer deposition (ALD) to exhibit superior performance for the re-refining of used lube oil. We investigated the upgrading of recycled lube oil by hydrogenation using commercial, synthetically-modified commercial catalysts, and synthesized catalysts. A down-flow (trickle bed) catalytic unit was used for the hydrogenation experiments. In addition to carrying out elemental analyses of the various feed and product fractions, characterization was undertaken using H{sup 1} and C{sup 13} NMR. Initially commercial were evaluated. Second these commercial catalysts were promoted with precious metals using atomic layer deposition (ALD). Performance improvements were observed that declined with catalyst aging. An alternate approach was undertaken to deeply upgrade ULI product oils. Using a synthesized catalyst, much lower hydrogenation temperatures were required than commercial catalysts. Other performance improvements were also observed. The resulting lube oil fractions were of high purity even at low reaction severity. The products recovered from both the ALD and other processes were water-white (even those from the low temperature, low residence time (high space velocity), low conversion runs). These results indicate that highly upgraded recycle lube oils can be produced using ALD-deposited active metal catalysts. The use of H{sup 1} and C{sup 13} NMR for the characterization of the treated lube oils has been shown to be effective.

Libera, J.A.; Snyder, S.W.; Mane, A.; Elam, J.W.; Cronauer, D.C.; Muntean, J.A.; Wu, T.; Miller, J.T. (Chemical Sciences and Engineering Division); ( ES)

2012-08-27T23:59:59.000Z

182

Low Cost, High Efficiency, High Pressure Hydrogen Storage  

SciTech Connect (OSTI)

A technical and design evaluation was carried out to meet DOE hydrogen fuel targets for 2010. These targets consisted of a system gravimetric capacity of 2.0 kWh/kg, a system volumetric capacity of 1.5 kWh/L and a system cost of $4/kWh. In compressed hydrogen storage systems, the vast majority of the weight and volume is associated with the hydrogen storage tank. In order to meet gravimetric targets for compressed hydrogen tanks, 10,000 psi carbon resin composites were used to provide the high strength required as well as low weight. For the 10,000 psi tanks, carbon fiber is the largest portion of their cost. Quantum Technologies is a tier one hydrogen system supplier for automotive companies around the world. Over the course of the program Quantum focused on development of technology to allow the compressed hydrogen storage tank to meet DOE goals. At the start of the program in 2004 Quantum was supplying systems with a specific energy of 1.1-1.6 kWh/kg, a volumetric capacity of 1.3 kWh/L and a cost of $73/kWh. Based on the inequities between DOE targets and Quantum’s then current capabilities, focus was placed first on cost reduction and second on weight reduction. Both of these were to be accomplished without reduction of the fuel system’s performance or reliability. Three distinct areas were investigated; optimization of composite structures, development of “smart tanks” that could monitor health of tank thus allowing for lower design safety factor, and the development of “Cool Fuel” technology to allow higher density gas to be stored, thus allowing smaller/lower pressure tanks that would hold the required fuel supply. The second phase of the project deals with three additional distinct tasks focusing on composite structure optimization, liner optimization, and metal.

Mark Leavitt

2010-03-31T23:59:59.000Z

183

Ultra-Compact High-Efficiency Luminaire for General Illumination  

SciTech Connect (OSTI)

Cree has developed a new ultra-compact light emitting diode (LED) luminaire capable of providing high efficacy with excellent color quality that can lead to significant energy savings in todayâ??s commercial and retail applications. This success was based on an integrated development effort tailoring the LED component characteristics, optics, thermal management and driver design for the small footprint to achieve an overall system efficiency of â?¥ 70%. A new LED component was designed to provide high brightness and efficacy in a form factor that allowed for a small directional beam with a luminaire housing design able to dissipate the heat effectively using a small physical envelope. A very compact, 90% efficient driver was developed to meet the system performance while not taking away any thermal mass from the heat sink. A 91% efficient secondary optics was designed to maximize efficiency while providing a smooth beam. The reliability of the new LED component was robust under accelerated testing conditions. Luminaires were assembled integrating the novel LED component, secondary optics, heat sink and driver technology to demonstrate the system improvement. Cree has successfully completed this project by developing an ultra-compact LED luminaire that provided 380 lumens at a correlated color temperature (CCT) of 2822 K and color rendering index (CRI) of 94 with an efficacy of 94 lumens per watt (LPW) when operating at 4 W input power (steady state) with an overall system efficiency of 81%. At a higher input power of 9 Watts, the lamp provided 658 lumens at 71 LPW.

Ted Lowes

2012-04-08T23:59:59.000Z

184

High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation High-Efficiency Quantum-Well Thermoelectrics for Waste Heat Power Generation 2005 Diesel Engine...

185

Integration of High Efficiency Solar Cells on Carriers for Concentrating System Applications .  

E-Print Network [OSTI]

??High efficiency multi-junction (MJ) solar cells were packaged onto receiver systems. The efficiency change of concentrator cells under continuous high intensity illumination was done. Also,… (more)

Chow, Simon Ka Ming

2011-01-01T23:59:59.000Z

186

High-Efficiency Solar Cogeneration with TPV & Fiber-Optic Daylighting...  

Broader source: Energy.gov (indexed) [DOE]

High-Efficiency Solar Cogeneration with TPV & Fiber-Optic Daylighting High-Efficiency Solar Cogeneration with TPV & Fiber-Optic Daylighting Lead Performer: Creative Light Source,...

187

SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline Engines SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline Engines Presentation given at the...

188

Nano Catalysts for Diesel Engine Emission Remediation  

SciTech Connect (OSTI)

The objective of this project was to develop durable zeolite nanocatalysts with broader operating temperature windows to treat diesel engine emissions to enable diesel engine based equipment and vehicles to meet future regulatory requirements. A second objective was to improve hydrothermal durability of zeolite catalysts to at least 675 C. The results presented in this report show that we have successfully achieved both objectives. Since it is accepted that the first step in NO{sub x} conversion under SCR (selective catalytic reduction) conditions involves NO oxidation to NO{sub 2}, we reasoned that catalyst modification that can enhance NO oxidation at low-temperatures should facilitate NO{sub x} reduction at low temperatures. Considering that Cu-ZSM-5 is a more efficient catalyst than Fe-ZSM-5 at low-temperature, we chose to modify Cu-ZSM-5. It is important to point out that the poor low-temperature efficiency of Fe-ZSM-5 has been shown to be due to selective absorption of NH{sub 3} at low-temperatures rather than poor NO oxidation activity. In view of this, we also reasoned that an increased electron density on copper in Cu-ZSM-5 would inhibit any bonding with NH{sub 3} at low-temperatures. In addition to modified Cu-ZSM-5, we synthesized a series of new heterobimetallic zeolites, by incorporating a secondary metal cation M (Sc{sup 3+}, Fe{sup 3+}, In{sup 3+}, and La{sup 3+}) in Cu exchanged ZSM-5, zeolite-beta, and SSZ-13 zeolites under carefully controlled experimental conditions. Characterization by diffuse-reflectance ultra-violet-visible spectroscopy (UV-Vis), X-ray powder diffraction (XRD), extended X-ray absorption fine structure spectroscopy (EXAFS) and electron paramagnetic resonance spectroscopy (EPR) does not permit conclusive structural determination but supports the proposal that M{sup 3+} has been incorporated in the vicinity of Cu(II). The protocols for degreening catalysts, testing under various operating conditions, and accelerated aging conditions were provided by our collaborators at John Deere Power Systems. Among various zeolites reported here, CuFe-SSZ-13 offers the best NO{sub x} conversion activity in 150-650 C range and is hydrothermally stable when tested under accelerated aging conditions. It is important to note that Cu-SSZ-13 is now a commercial catalyst for NO{sub x} treatment on diesel passenger vehicles. Thus, our catalyst performs better than the commercial catalyst under fast SCR conditions. We initially focused on fast SCR tests to enable us to screen catalysts rapidly. Only the catalysts that exhibit high NO{sub x} conversion at low temperatures are selected for screening under varying NO{sub 2}:NO{sub x} ratio. The detailed tests of CuFe-SSZ-13 show that CuFe-SSZ-13 is more effective than commercial Cu-SSZ-13 even at NO{sub 2}:NO{sub x} ratio of 0.1. The mechanistic studies, employing stop-flow diffuse reflectance FTIR spectroscopy (DRIFTS), suggest that high concentration of NO{sup +}, generated by heterobimetallic zeolites, is probably responsible for their superior low temperature NO{sub x} activity. The results described in this report clearly show that we have successfully completed the first step in a new emission treatment catalyst which is synthesis and laboratory testing employing simulated exhaust. The next step in the catalyst development is engine testing. Efforts are in progress to obtain follow-on funding to carry out scale-up and engine testing to facilitate commercialization of this technology.

Narula, Chaitanya Kumar [ORNL; Yang, Xiaofan [ORNL; Debusk, Melanie Moses [ORNL; Mullins, David R [ORNL; Mahurin, Shannon Mark [ORNL; Wu, Zili [ORNL

2012-06-01T23:59:59.000Z

189

High Efficiency LED Lamp for Solid-State Lighting  

SciTech Connect (OSTI)

This report contains a summary of technical achievements during a three-year project to demonstrate high efficiency, solid-state lamps based on gallium nitride/silicon carbide light-emitting diodes. Novel chip designs and fabrication processes are described for a new type of nitride light-emitting diode with the potential for very high efficiency. This work resulted in the demonstration of blue light-emitting diodes in the one watt class that achieved up to 495 mW of light output at 350 mA drive current, corresponding to quantum and wall plug efficiencies of 51% and 45%, respectively. When combined with a phosphor in Cree's 7090 XLamp package, these advanced blue-emitting devices resulted in white light-emitting diodes whose efficacy exceeded 85 lumens per watt. In addition, up to 1040 lumens at greater than 85 lumens per watt was achieved by combining multiple devices to make a compact white lamp module with high optical efficiency.

James Ibbetson

2006-12-31T23:59:59.000Z

190

High Quality Down Lighting Luminaire with 73% Overall System Efficiency  

SciTech Connect (OSTI)

This report summarizes work to develop a high flux, high efficiency LED-based downlight at OSRAM SYLVANIA under US Department of Energy contract DE-FC26-08NT01582. A new high power LED and electronic driver were developed for these downlights. The LED achieved 100 lumens per watt efficacy and 1700 lumen flux output at a correlated color temperature of 3500K. The driver had 90% electrical conversion efficiency while maintaining excellent power quality with power factor >0.99, and total harmonic distortion <10%. Two styles of downlights using the LED and driver were shown to exceed the project targets for steady-state luminous efficacy and flux of 70 lumens per watt and 1300 lumens, respectively. Compared to similar existing downlights using compact fluorescent or LED sources, these downlights had much higher efficacy at nearly the same luminous flux.

Robert Harrison; Steven C. Allen; Joseph Bernier; Robert Harrison

2010-08-31T23:59:59.000Z

191

A Perspective on the Future of High Efficiency Engines  

SciTech Connect (OSTI)

New fuel economy standards and emissions regulations are accelerating the development of new engine technologies, sensors, and on-board computing. These developments will enable unprecedented engine control, which will in turn enable real-world implementations of low temperature combustion, high-speed controls, and other high efficiency engine technologies. With this expanded flexibility in engine design and control, the challenge will now be the exponential increase in the design and calibration space and the need for the development of new simulations, optimization methods, and self-learning control methodologies. This manuscript provides historical and future perspectives on the opportunities and challenges of this unparalleled technology growth on the next generation of high efficiency engines.

Wagner, Robert M [ORNL] [ORNL; Curran, Scott [ORNL] [ORNL; Green Jr, Johney Boyd [ORNL] [ORNL

2013-01-01T23:59:59.000Z

192

Mixed Alcohol Synthesis Catalyst Screening  

SciTech Connect (OSTI)

National Renewable Energy Laboratory (NREL) and Pacific Northwest National Laboratory (PNNL) are conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is tasked with obtaining commercially available or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. Commercially available catalysts and the most promising experimental catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. From the standpoint of producing C2+ alcohols as the major product, it appears that the rhodium catalyst is the best choice in terms of both selectivity and space-time yield (STY). However, unless the rhodium catalyst can be improved to provide minimally acceptable STYs for commercial operation, mixed alcohol synthesis will involve significant production of other liquid coproducts. The modified Fischer-Tropsch catalyst shows the most promise for providing both an acceptable selectivity to C2+ alcohols and total liquid STY. However, further optimization of the Fischer-Tropsch catalysts to improve selectivity to higher alcohols is highly desired. Selection of a preferred catalyst will likely entail a decision on the preferred coproduct slate. No other catalysts tested appear amenable to the significant improvements needed for acceptable STYs.

Gerber, Mark A.; White, James F.; Stevens, Don J.

2007-09-03T23:59:59.000Z

193

Volume 1, 1st Edition, Multiscale Tailoring of Highly Active and Stable Nanocomposite Catalysts, Final Technical Report  

SciTech Connect (OSTI)

Nanomaterials have gained much attention as catalysts since the discovery of exceptional CO oxidation activity of nanoscale gold by Haruta. However, many studies avoid testing nanomaterials at the high-temperatures relevant to reactions of interest for the production of clean energy (T > 700°C). The generally poor thermal stability of catalytically active noble metals has thus far prevented significant progress in this area. We have recently overcome the poor thermal stability of nanoparticles by synthesizing a platinum barium-hexaaluminate (Pt-BHA) nanocomposite which combines the high activity of noble metal nanoparticles with the thermal stability of hexaaluminates. This Pt-BHA nanocomposite demonstrates excellent activity, selectivity, and long-term stability in CPOM. Pt-BHA is anchored onto a variety of support structures in order to improve the accessibility, safety, and reactivity of the nanocatalyst. Silica felts prove to be particularly amenable to this supporting procedure, with the resulting supported nanocatalyst proving to be as active and stable for CPOM as its unsupported counterpart. Various pre-treatment conditions are evaluated to determine their effectiveness in removing residual surfactant from the active nanoscale platinum particles. The size of these particles is measured across a wide temperature range, and the resulting “plateau” of stability from 600-900°C can be linked to a particle caging effect due to the structure of the supporting ceramic framework. The nanocomposites are used to catalyze the combustion of a dilute methane stream, and the results indicate enhanced activity for both Pt-BHA as well as ceria-doped BHA, as well as an absence of internal mass transfer limitations at the conditions tested. In water-gas shift reaction, nanocomposite Pt-BHA shows stability during prolonged WGS reaction and no signs of deactivation during start-up/shut-down of the reactor. The chemical and thermal stability, low molecular weight, and wealth of literature on the formation of mesoporous silica materials motivated investigations of nanocomposite silica catalysts. High surface area silicas are synthesized via sol-gel methods, and the addition of metal-salts lead to the formation of stable nanocomposite Ni- and Fe- silicates. The results of these investigations have increased the fundamental understanding and improved the applicability of nanocatalysts for clean energy applications.

Veser, Goetz

2009-08-31T23:59:59.000Z

194

Advanced Klystrons for High Efficiency Accelerator Systems - Final Report  

SciTech Connect (OSTI)

This program explored tailoring of RF pulses used to drive accelerator cavities. Simulations indicated that properly shaping the pulse risetime to match accelerator cavity characteristics reduced reflected power and increased total efficiency. Tailoring the pulse requires a high power, gridded, klystron to shape the risetime while also controlling the beam current. The Phase I program generated a preliminary design of a gridded electron gun for a klystron producing 5-10 MW of RF power. This required design of a segmented cathode using Controlled Porosity Reservoir cathodes to limit power deposition on the grid. The program was successful in computationally designing a gun producing a high quality electron beam with grid control. Additional analysis of pulse tailoring indicated that technique would only be useful for cavity drive pulses that were less than approximately 2-3 times the risetime. Otherwise, the efficiency gained during the risetime of the pulse became insignificant when considering the efficiency over the entire pulse. Consequently, it was determined that a Phase II program would not provide sufficient return to justify the cost. Never the less, other applications for a high power gridded gun are currently being pursued. This klystron, for example, would facilitate development inverse Comptom x-ray sources by providing a high repetition rate (10 -100 kHz) RF source.

Read, Michael; Ives, Robert Lawrence

2014-03-26T23:59:59.000Z

195

High efficiency carbonate fuel cell/turbine hybrid power cycle  

SciTech Connect (OSTI)

The hybrid power cycle studies were conducted to identify a high efficiency, economically competitive system. A hybrid power cycle which generates power at an LHV efficiency > 70% was identified that includes an atmospheric pressure direct carbonate fuel cell, a gas turbine, and a steam cycle. In this cycle, natural gas fuel is mixed with recycled fuel cell anode exhaust, providing water for reforming fuel. The mixed gas then flows to a direct carbonate fuel cell which generates about 70% of the power. The portion of the anode exhaust which is not recycled is burned and heat transferred through a heat exchanger (HX) to the compressed air from a gas turbine. The heated compressed air is then heated further in the gas turbine burner and expands through the turbine generating 15% of the power. Half the exhaust from the turbine provides air for the anode exhaust burner. All of the turbine exhaust eventually flows through the fuel cell cathodes providing the O2 and CO2 needed in the electrochemical reaction. Exhaust from the cathodes flows to a steam system (heat recovery steam generator, staged steam turbine generating 15% of the cycle power). Simulation of a 200 MW plant with a hybrid power cycle had an LHV efficiency of 72.6%. Power output and efficiency are insensitive to ambient temperature, compared to a gas turbine combined cycle; NOx emissions are 75% lower. Estimated cost of electricity for 200 MW is 46 mills/kWh, which is competitive with combined cycle where fuel cost is > $5.8/MMBTU. Key requirement is HX; in the 200 MW plant studies, a HX operating at 1094 C using high temperature HX technology currently under development by METC for coal gassifiers was assumed. A study of a near term (20 MW) high efficiency direct carbonate fuel cell/turbine hybrid power cycle has also been completed.

Steinfeld, G.; Maru, H.C. [Energy Research Corp., Danbury, CT (United States); Sanderson, R.A. [Sanderson (Robert) and Associates, Wethersfield, CT (United States)

1996-07-01T23:59:59.000Z

196

Test Program for High Efficiency Gas Turbine Exhaust Diffuser  

SciTech Connect (OSTI)

This research relates to improving the efficiency of flow in a turbine exhaust, and thus, that of the turbine and power plant. The Phase I SBIR project demonstrated the technical viability of “strutlets” to control stalls on a model diffuser strut. Strutlets are a novel flow-improving vane concept intended to improve the efficiency of flow in turbine exhausts. Strutlets can help reduce turbine back pressure, and incrementally improve turbine efficiency, increase power, and reduce greenhouse gas emmission. The long-term goal is a 0.5 percent improvement of each item, averaged over the US gas turbine fleet. The strutlets were tested in a physical scale model of a gas turbine exhaust diffuser. The test flow passage is a straight, annular diffuser with three sets of struts. At the end of Phase 1, the ability of strutlets to keep flow attached to struts was demonstrated, but the strutlet drag was too high for a net efficiency advantage. An independently sponsored followup project did develop a highly-modified low-drag strutlet. In combination with other flow improving vanes, complicance to the stated goals was demonstrated for for simple cycle power plants, and to most of the goals for combined cycle power plants using this particular exhaust geometry. Importantly, low frequency diffuser noise was reduced by 5 dB or more, compared to the baseline. Appolicability to other diffuser geometries is yet to be demonstrated.

Norris, Thomas R.

2009-12-31T23:59:59.000Z

197

High-efficiency solar cell and method for fabrication  

DOE Patents [OSTI]

A high-efficiency 3- or 4-junction solar cell is disclosed with a theoretical AM0 energy conversion efficiency of about 40%. The solar cell includes p-n junctions formed from indium gallium arsenide nitride (InGaAsN), gallium arsenide (GaAs) and indium gallium aluminum phosphide (InGaAlP) separated by n-p tunnel junctions. An optional germanium (Ge) p-n junction can be formed in the substrate upon which the other p-n junctions are grown. The bandgap energies for each p-n junction are tailored to provide substantially equal short-circuit currents for each p-n junction, thereby eliminating current bottlenecks and improving the overall energy conversion efficiency of the solar cell. Additionally, the use of an InGaAsN p-n junction overcomes super-bandgap energy losses that are present in conventional multi-junction solar cells. A method is also disclosed for fabricating the high-efficiency 3- or 4-junction solar cell by metal-organic chemical vapor deposition (MOCVD).

Hou, Hong Q. (Albuquerque, NM); Reinhardt, Kitt C. (Albuquerque, NM)

1999-01-01T23:59:59.000Z

198

High-efficiency solar cell and method for fabrication  

DOE Patents [OSTI]

A high-efficiency 3- or 4-junction solar cell is disclosed with a theoretical AM0 energy conversion efficiency of about 40%. The solar cell includes p-n junctions formed from indium gallium arsenide nitride (InGaAsN), gallium arsenide (GaAs) and indium gallium aluminum phosphide (InGaAlP) separated by n-p tunnel junctions. An optional germanium (Ge) p-n junction can be formed in the substrate upon which the other p-n junctions are grown. The bandgap energies for each p-n junction are tailored to provide substantially equal short-circuit currents for each p-n junction, thereby eliminating current bottlenecks and improving the overall energy conversion efficiency of the solar cell. Additionally, the use of an InGaAsN p-n junction overcomes super-bandgap energy losses that are present in conventional multi-junction solar cells. A method is also disclosed for fabricating the high-efficiency 3- or 4-junction solar cell by metal-organic chemical vapor deposition (MOCVD). 4 figs.

Hou, H.Q.; Reinhardt, K.C.

1999-08-31T23:59:59.000Z

199

High-Efficiency Solar Cell Concepts: Physics, Materials, and Devices  

SciTech Connect (OSTI)

Over the past three decades, significant progress has been made in the area of high-efficiency multijunction solar cells, with the effort primarily directed at current-matched solar cells in tandem. The key materials issues here have been obtaining semiconductors with the required bandgaps for sequential absorption of light in the solar spectrum and that are lattice matched to readily available substrates. The GaInP/GaAs/Ge cell is a striking example of success achieved in this area. Recently, several new approaches for high-efficiency solar cell design have emerged, that involve novel methods for tailoring alloy bandgaps, as well as alternate technologies for hetero-epitaxy of III-V's on Si. The advantages and difficulties expected to be encountered with each approach will be discussed, addressing both the materials issues and device physics whilst contrasting them with other fourth-generation solar cell concepts.

Mascarenhas, A.; Francoeur, S.; Seong, M. J.; Fluegel, B.; Zhang, Y.; Wanlass, M. W.

2005-01-01T23:59:59.000Z

200

Regeneration of Hydrotreating and FCC Catalysts  

SciTech Connect (OSTI)

Hydrotreating, hydrocracking, and fluid catalytic cracking (FCC) catalysts are important components of petroleum refining processes. Hydrotreating and hydrocracking catalysts are used to improve the yield of high-quality light oil fractions from heavier crude oil and petroleum feedstocks containing high levels of impurities. FCC catalysts improve the yield of higher octane gasoline from crude oil. Residuum hydrotreating and cracking catalysts are susceptible to irreversible deactivation caused by adsorption of sulfur and by metals impurities, such as vanadium and nickel. The gradual buildup of these impurities in a hydrotreating catalyst eventually plugs the pores and deactivates it. Nickel and vanadium adversely affect the behavior of cracking catalysts, reducing product yield and quality. Replacing deactivated catalysts represents a significant cost in petroleum refining. Equally important are the costs and potential liabilities associated with treating and disposing spent catalysts. For example, recent US Environmental Protection Agency rulings have listed spent hydrotreating and hydrorefining catalysts as hazardous wastes. FCC catalysts, though more easily disposed of as road-base or as filler in asphalt and cement, are still an economic concern mainly because of the large volumes of spent catalysts generated. New processes are being considered to increase the useful life of catalysts or for meeting more stringent disposal requirements for spent catalysts containing metals. This report discusses a collaborative effort between Pacific Northwest National Laboratory (PNNL) and Phillips Petroleum, Inc., to identify promising chemical processes for removing metals adhered to spent hydrodesulfurization (HDS, a type of hydrotreating catalyst) and FCC catalysts. This study, conducted by PNNL, was funded by the US Department of Energy's Bartlesville Project Office. Fresh and spent catalysts were provided by Phillips Petroleum. The FCC catalyst was a rare-earth exchanged Y zeolite in a silica-alumina matrix. X-ray fluorescence analyses showed that the rare earths used in preparing the catalysts were a mixture of lanthanum and cerium. Antimony found in the spent catalyst was added during operation of the FCC unit as a way to suppress the adverse effects of deposited nickel. The fresh HDS samples consisted of sulfided nickel and molybdenum on an alumina support. The spent catalyst showed nearly 10% vanadium on the catalyst and a modest increase in nickel and sulfur on the catalyst as a result of operations. Hydrocracking catalysts were not available for this study.

CM Wai; JG Frye; JL Fulton; LE Bowman; LJ Silva; MA Gerber

1999-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Chemical beam epitaxy for high efficiency photovoltaic devices  

SciTech Connect (OSTI)

InP-based multijunction tandem solar cells show great promise for the conversion efficiency (eta) and high radiation resistance. InP and its related ternary and quanternary compound semiconductors such as InGaAs and InGaAsP offer desirable combinations for energy bandgap values which are very suitable for multijunction tandem solar cell applications. The monolithically integrated InP/In(0.53)Ga(0.47)As tandem solar cells are expected to reach efficiencies above 30 percent. Wanlass, et.al., have reported AMO efficiencies as high as 20.1% for two terminal cells fabricated using atmospheric-pressure metalorganic vapor phase epitaxy (APMOVPE). The main limitations in their technique are first related to the degradation of the intercell ohmic contact (IOC), in this case the In(0.53)Ga(0.47)As tunnel junction during the growth of the top InP subcell structure, and second to the current matching, often limited by the In(0.53)Ga(0.47)As bottom subcell. Chemical beam epitaxy (CBE) has been shown to allow the growth of high quality materials with reproducible complex compositional and doping profiles. The main advantage of CBE compared to metalorganic chemical vapor deposition (MOCVD), the most popular technique for InP-based photovoltaic device fabrication, is the ability to grow high purity epilayers at much lower temperatures (450 C - 530 C). In a recent report it was shown that cost-wise CBE is a breakthrough technology for photovoltaic (PV) solar energy progress in the energy conversion efficiency of InP-based solar cells fabricated using chemical beam epitaxy. This communication summarizes recent results on PV devices and demonstrates the strength of this new technology.

Bensaoula, A.; Freundlich, A.; Vilela, M. F.; Medelci, N.; Renaud, P.

1994-09-01T23:59:59.000Z

202

OSRAM SYLVANIA Develops High-Efficiency LED Troffer Replacement  

Broader source: Energy.gov [DOE]

With the help of DOE funding, OSRAM SYLVANIA is developing a high-efficiency LED 2'x2' troffer replacement that is expected to be commercially available in the spring of 2012 and to be cost-competitive with existing troffers of that size. It is projected to have a light output of up to 4,000 lumens, an efficacy of more than 100 lm/W, and a CCT of 3500K.

203

Low-Temperature Combustion Demonstrator for High-Efficiency Clean  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of Energy Low-Temperature Combustion Demonstrator for High-Efficiency Clean

204

High Efficiency Combustion and Controls | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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205

High Efficiency Full Expansion (FEx) Engine for Automotive Applications |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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206

High Efficiency Microturbine with Integral Heat Recovery - Presentation by  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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207

High Efficiency and Stable White OLED Using a Single Emitter  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii CleanHeatinHigh Efficiency| - ADVANCEDJian

208

High Performance Healthcare Buildings: A Roadmap to Improved Energy Efficiency  

E-Print Network [OSTI]

operation with energy efficiency in building systems. X X Xoperation with energy efficiency in building systems. 10.3.energy efficiency improvements in healthcare buildings. A

Singer, Brett C.

2010-01-01T23:59:59.000Z

209

High Performance Healthcare Buildings: A Roadmap to Improved Energy Efficiency  

E-Print Network [OSTI]

consensus on energy efficient designs by climate and inestimates for an energy efficient alternative design can behighly energy efficient hospitals while the design community

Singer, Brett C.

2010-01-01T23:59:59.000Z

210

Aerogel derived catalysts  

SciTech Connect (OSTI)

Aerogels area class of colloidal materials which have high surface areas and abundant mesoporous structure. SiO{sub 2} aerogels show unique physical, optical and structural properties. When catalytic metals are incorporated in the aerogel framework, the potential exists for new and very effective catalysts for industrial processes. Three applications of these metal-containing SiO{sub 2} aerogels as catalysts are briefly reviewed in this paper--NO{sub x} reduction, volatile organic compound destruction, and partial oxidation of methane.

Reynolds, J. G., LLNL

1996-12-11T23:59:59.000Z

211

HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER  

SciTech Connect (OSTI)

OAK B202 HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER. Combustion of fossil fuels, used to power transportation, generate electricity, heat homes and fuel industry provides 86% of the world's energy. Drawbacks to fossil fuel utilization include limited supply, pollution, and carbon dioxide emissions. Carbon dioxide emissions, thought to be responsible for global warming, are now the subject of international treaties. Together, these drawbacks argue for the replacement of fossil fuels with a less-polluting potentially renewable primary energy such as nuclear energy. Conventional nuclear plants readily generate electric power but fossil fuels are firmly entrenched in the transportation sector. Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. Hydrogen will be particularly advantageous when coupled with fuel cells. Fuel cells have higher efficiency than conventional battery/internal combustion engine combinations and do not produce nitrogen oxides during low-temperature operation. Contemporary hydrogen production is primarily based on fossil fuels and most specifically on natural gas. When hydrogen is produced using energy derived from fossil fuels, there is little or no environmental advantage. There is currently no large scale, cost-effective, environmentally attractive hydrogen production process available for commercialization, nor has such a process been identified. The objective of this work is to find an economically feasible process for the production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the primary energy source. Hydrogen production by thermochemical water-splitting (Appendix A), a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or, in the case of a hybrid thermochemical process, by a combination of heat and electrolysis, could meet these goals. Hydrogen produced from fossil fuels has trace contaminants (primarily carbon monoxide) that are detrimental to precious metal catalyzed fuel cells, as is now recognized by many of the world's largest automobile companies. Thermochemical hydrogen will not contain carbon monoxide as an impurity at any level. Electrolysis, the alternative process for producing hydrogen using nuclear energy, suffers from thermodynamic inefficiencies in both the production of electricity and in electrolytic parts of the process. The efficiency of electrolysis (electricity to hydrogen) is currently about 80%. Electric power generation efficiency would have to exceed 65% (thermal to electrical) for the combined efficiency to exceed the 52% (thermal to hydrogen) calculated for one thermochemical cycle. Thermochemical water-splitting cycles have been studied, at various levels of effort, for the past 35 years. They were extensively studied in the late 70s and early 80s but have received little attention in the past 10 years, particularly in the U.S. While there is no question about the technical feasibility and the potential for high efficiency, cycles with proven low cost and high efficiency have yet to be developed commercially. Over 100 cycles have been proposed, but substantial research has been executed on only a few. This report describes work accomplished during a three-year project whose objective is to ''define an economically feasible concept for production of hydrogen, by nuclear means, using an advanced high temperature nuclear reactor as the energy source.'' The emphasis of the first phase was to evaluate thermochemical processes which offer the potential for efficient, cost-effective, large-scale production of hydrogen from water in which the primary energy input is high temperature heat from an advanced nuclear reactor and to select one (or, at most three) for further detailed consideration. During Phase 1, an exhaustive literature search was performed to locate all cycles previously proposed. The cycles located were screened using objective criteria to determine which could benefit, in terms of efficien

BROWN,LC; BESENBRUCH,GE; LENTSCH,RD; SCHULTZ,KR; FUNK,JF; PICKARD,PS; MARSHALL,AC; SHOWALTER,SK

2003-06-01T23:59:59.000Z

212

In-Plant Testing of High-Efficiency Hydraulic Separators  

SciTech Connect (OSTI)

Hydraulic separators are commonly used for particle size classification and gravity concentration of minerals and coal. Unfortunately, the efficiency of these processes can be quite low due to poor equipment design and variations in feed consistency. To help alleviate these problems, an industry-driven R&D program has been undertaken to develop a new generation of hydraulic separators that are more efficient and less costly to operate and maintain. These units, which are commercially called the CrossFlow separator and HydroFloat separator, have the potential to improve performance (separation efficiency and throughput) and reduce operating costs (power consumption, water and reagent usage). In Phase I of this project, laboratory and pilot-scale test units were evaluated at various industrial sites in both the coal and mineral industries. Based on promising results obtained from Phase I, full-scale prototypes were purchased and installed by a major U.S. phosphate producer and a large eastern U.S. coal company. The test data obtained from these sites demonstrate that significant performance improvements can be realized through the application of these high-efficiency separators.

G. H. Luttrell; R. Q. Honaker; R. C. Bratton; T. C. Westerfield; J. N. Kohmuench

2006-06-30T23:59:59.000Z

213

IN-PLANT TESTING OF HIGH-EFFICIENCY HYDRAULIC SEPARATORS  

SciTech Connect (OSTI)

Hydraulic separators are commonly used for particle size classification and gravity concentration of minerals and coal. Unfortunately, the efficiency of these processes can be quite low due to poor equipment design and variations in feed consistency. To help alleviate these problems, an industry-driven R&D program has been undertaken to develop a new generation of hydraulic separators that are more efficient and less costly to operate and maintain. These units, which are commercially called the CrossFlow separator and HydroFloat separator, have the potential to improve performance (separation efficiency and throughput) and reduce operating costs (power consumption, water and reagent usage). In Phase I of this project, laboratory and pilot-scale test units were evaluated at various industrial sites in both the coal and mineral industries. Based on promising results obtained from Phase I, full-scale prototypes were purchased and installed by a major U.S. phosphate producer and a large eastern U.S. coal company. The test data obtained from these sites demonstrate that significant performance improvements can be realized through the application of these high-efficiency separators.

G.H. Luttrell; R.Q. Honaker; R.C. Bratton; T.C. Westerfield; J.N. Kohmuench

2006-05-22T23:59:59.000Z

214

Catalyst activator  

DOE Patents [OSTI]

A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising two Group 13 metal or metalloid atoms and a ligand structure including at least one bridging group connecting ligands on the two Group 13 metal or metalloid atoms.

McAdon, Mark H. (Midland, MI); Nickias, Peter N. (Midland, MI); Marks, Tobin J. (Evanston, IL); Schwartz, David J. (Lake Jackson, TX)

2001-01-01T23:59:59.000Z

215

Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity  

DOE Patents [OSTI]

A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime (about 40 ps), high frequency (about 5G hz), high power bursts of low-duty factor microwaves sufficient to generate a dielectric barrier discharge and passing a gas to treated through the discharge so as to cause dissociative reduction of the exhaust gases. The invention also includes a reactor for generating the non-thermal plasma.

Whealton, John H. (Oak Ridge, TN); Hanson, Gregory R. (Clinton, TN); Storey, John M. (Oak Ridge, TN); Raridon, Richard J. (Oak Ridge, TN); Armfield, Jeffrey S. (Upsilanti, MI); Bigelow, Timothy S. (Knoxville, TN); Graves, Ronald L. (Knoxville, TN)

2001-01-01T23:59:59.000Z

216

High efficiency rare-earth emitter for thermophotovoltaic applications  

SciTech Connect (OSTI)

In this work, we propose a rare-earth-based ceramic thermal emitter design that can boost thermophotovoltaic (TPV) efficiencies significantly without cold-side filters at a temperature of 1573?K (1300?°C). The proposed emitter enhances a naturally occurring rare earth transition using quality-factor matching, with a quarter-wave stack as a highly reflective back mirror, while suppressing parasitic losses via exponential chirping of a multilayer reflector transmitting only at short wavelengths. This allows the emissivity to approach the blackbody limit for wavelengths overlapping with the absorption peak of the rare-earth material, while effectively reducing the losses associated with undesirable long-wavelength emission. We obtain TPV efficiencies of 34% using this layered design, which only requires modest index contrast, making it particularly amenable to fabrication via a wide variety of techniques, including sputtering, spin-coating, and plasma-enhanced chemical vapor deposition.

Sakr, E. S.; Zhou, Z.; Bermel, P., E-mail: pbermel@purdue.edu [Birck Nanotechnology Center, School of Electrical and Computer Engineering, Purdue University, 1205 W. State St., West Lafayette, Indiana 47907 (United States)

2014-09-15T23:59:59.000Z

217

Energy-efficient wireless communication In this chapter we present an energy-efficient highly adaptive network  

E-Print Network [OSTI]

delay. This chapter addresses the additional goal of efficient energy usage of the mobilesEnergy-efficient wireless communication In this chapter we present an energy-efficient highly of wireless networks, adaptations in bandwidth scheduling and error control are necessary to achieve energy

Havinga, Paul J.M.

218

High-Throughput Program for the Discovery of NOx Reduction Catalysts |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground HawaiiWaste Heat Recovery: Successa High

219

The Importance of Domain Size and Purity in High-Efficiency Organic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymerorganic photovoltaic cells hinges on excitons-electronhole pairs...

220

Highly Efficient Quantum Key Distribution Immune to All Detector Attacks  

E-Print Network [OSTI]

Vulnerabilities and imperfections of single-photon detectors have been shown to compromise security for quantum key distribution (QKD). The measurement-device-independent QKD (MDI-QKD) appears to be the most appealing solution to solve the issues. However, in practice one faces severe obstacles of having significantly lower key generation rate, difficult two photon interferences, and remote synchronization etc. In this letter, we propose a highly efficient and simple quantum key distribution scheme to remove all of these drawbacks. Our proposal can be implemented with only small modifications over the standard decoy BB84 system. Remarkably it enjoys both the advantages of high key generation rate (being almost two orders of magnitude higher than that based on conventional MDI-QKD) comparable to the normal decoy system, and security against any detector side channel attacks. Most favorably one can achieve complete Bell state measurements with resort to single photon interference, which reduces significantly experimental costs. Our approach enables utilization of high speed and efficient secure communication, particularly in real-life scenario of both metropolitan and intercity QKD network, with an attack free fashion from arbitrary detector side channels.

Wen-Fei Cao; Yi-Zheng Zhen; Yu-Lin Zheng; Zeng-Bing Chen; Nai-Le Liu; Kai Chen; Jian-Wei Pan

2014-10-10T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Autothermal reforming catalyst having perovskite structure  

DOE Patents [OSTI]

The invention addressed two critical issues in fuel processing for fuel cell application, i.e. catalyst cost and operating stability. The existing state-of-the-art fuel reforming catalyst uses Rh and platinum supported over refractory oxide which add significant cost to the fuel cell system. Supported metals agglomerate under elevated temperature during reforming and decrease the catalyst activity. The catalyst is a perovskite oxide or a Ruddlesden-Popper type oxide containing rare-earth elements, catalytically active firs row transition metal elements, and stabilizing elements, such that the catalyst is a single phase in high temperature oxidizing conditions and maintains a primarily perovskite or Ruddlesden-Popper structure under high temperature reducing conditions. The catalyst can also contain alkaline earth dopants, which enhance the catalytic activity of the catalyst, but do not compromise the stability of the perovskite structure.

Krumpel, Michael (Naperville, IL); Liu, Di-Jia (Naperville, IL)

2009-03-24T23:59:59.000Z

222

High Efficiency Engine Systems Development and Evaluation | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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223

High Efficiency Engine Systems Development and Evaluation | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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224

High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii CleanHeatinHigh Efficiency| Department of

225

High Engine Efficiency at 2010 Emissions | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii CleanHeatinHigh Efficiency| -4Novel

226

A High Efficiency PSOFC/ATS-Gas Turbine Power System  

SciTech Connect (OSTI)

A study is described in which the conceptual design of a hybrid power system integrating a pressurized Siemens Westinghouse solid oxide fuel cell generator and the Mercury{trademark} 50 gas turbine was developed. The Mercury{trademark} 50 was designed by Solar Turbines as part of the US. Department of Energy Advanced Turbine Systems program. The focus of the study was to develop the hybrid power system concept that principally would exhibit an attractively-low cost of electricity (COE). The inherently-high efficiency of the hybrid cycle contributes directly to achieving this objective, and by employing the efficient, power-intensive Mercury{trademark} 50, with its relatively-low installed cost, the higher-cost SOFC generator can be optimally sized such that the minimum-COE objective is achieved. The system cycle is described, major system components are specified, the system installed cost and COE are estimated, and the physical arrangement of the major system components is discussed. Estimates of system power output, efficiency, and emissions at the system design point are also presented. In addition, two bottoming cycle options are described, and estimates of their effects on overall-system performance, cost, and COE are provided.

W.L. Lundberg; G.A. Israelson; M.D. Moeckel; S.E. Veyo; R.A. Holmes; P.R. Zafred; J.E. King; R.E. Kothmann

2001-02-01T23:59:59.000Z

227

Analysis of highly-efficient electric residential HPWHs  

SciTech Connect (OSTI)

A scoping level analysis was conducted to identify electric HPWH concepts that have the potential to achieve or exceed 30% source energy savings compared to a gas tankless water heater (GTWH) representative of the type represented in version 0.9.5.2 beta of the BEopt software developed by the National Renewable Energy Laboratory. The analysis was limited to evaluation of options to improve the energy efficiency of electric HPWH product designs currently on the market in the US. The report first defines the baseline GTWH system and determines its efficiency (source-energy-based adjusted or derated EF of ~0.71). High efficiency components (compressors, pumps, fans, heat exchangers, etc.) were identified and applied to current US HPWH products and analyzed to determine the viability of reaching the target EF. The target site-based energy factor (EF) required for an electric HPWH necessary to provide 30% source energy savings compared to the GTWH baseline unit is then determined to be ~3.19.

Baxter, Van D [ORNL; Murphy, Richard W [ORNL; Rice, C Keith [ORNL; Shen, Bo [ORNL; Gao, Zhiming [ORNL

2011-09-01T23:59:59.000Z

228

Thin Film Packaging Solutions for High Efficiency OLED Lighting Products  

SciTech Connect (OSTI)

The objective of the 'Thin Film Packaging Solutions for High Efficiency OLED Lighting Products' project is to demonstrate thin film packaging solutions based on SiC hermetic coatings that, when applied to glass and plastic substrates, support OLED lighting devices by providing longer life with greater efficiency at lower cost than is currently available. Phase I Objective: Demonstrate thin film encapsulated working phosphorescent OLED devices on optical glass with lifetime of 1,000 hour life, CRI greater than 75, and 15 lm/W. Phase II Objective: Demonstrate thin film encapsulated working phosphorescent OLED devices on plastic or glass composite with 25 lm/W, 5,000 hours life, and CRI greater than 80. Phase III Objective: Demonstrate 2 x 2 ft{sup 2} thin film encapsulated working phosphorescent OLED with 40 lm/W, 10,000 hour life, and CRI greater than 85. This report details the efforts of Phase III (Budget Period Three), a fourteen month collaborative effort that focused on optimization of high-efficiency phosphorescent OLED devices and thin-film encapsulation of said devices. The report further details the conclusions and recommendations of the project team that have foundation in all three budget periods for the program. During the conduct of the Thin Film Packaging Solutions for High Efficiency OLED Lighting Products program, including budget period three, the project team completed and delivered the following achievements: (1) a three-year marketing effort that characterized the near-term and longer-term OLED market, identified customer and consumer lighting needs, and suggested prototype product concepts and niche OLED applications lighting that will give rise to broader market acceptance as a source for wide area illumination and energy conservation; (2) a thin film encapsulation technology with a lifetime of nearly 15,000 hours, tested by calcium coupons, while stored at 16 C and 40% relative humidity ('RH'). This encapsulation technology was characterized as having less than 10% change in transmission during the 15,000 hour test period; (3) demonstrated thin film encapsulation of a phosphorescent OLED device with 1,500 hours of lifetime at 60 C and 80% RH; (4) demonstrated that a thin film laminate encapsulation, in addition to the direct thin film deposition process, of a polymer OLED device was another feasible packaging strategy for OLED lighting. The thin film laminate strategy was developed to mitigate defects, demonstrate roll-to-roll process capability for high volume throughput (reduce costs) and to support a potential commercial pathway that is less dependent upon integrated manufacturing since the laminate could be sold as a rolled good; (5) demonstrated that low cost 'blue' glass substrates could be coated with a siloxane barrier layer for planarization and ion-protection and used in the fabrication of a polymer OLED lighting device. This study further demonstrated that the substrate cost has potential for huge cost reductions from the white borosilicate glass substrate currently used by the OLED lighting industry; (6) delivered four-square feet of white phosphorescent OLED technology, including novel high efficiency devices with 82 CRI, greater than 50 lm/W efficiency, and more than 1,000 hours lifetime in a product concept model shelf; (7) presented and or published more than twenty internal studies (for private use), three external presentations (OLED workshop-for public use), and five technology-related external presentations (industry conferences-for public use); and (8) issued five patent applications, which are in various maturity stages at time of publication. Delivery of thin film encapsulated white phosphorescent OLED lighting technology remains a challenging technical achievement, and it seems that commercial availability of thin, bright, white OLED light that meets market requirements will continue to require research and development effort. However, there will be glass encapsulated white OLED lighting products commercialized in niche markets during the 2008 calendar year. This commercializ

None

2008-06-30T23:59:59.000Z

229

High-Efficiency Nitride-Base Photonic Crystal Light Sources  

SciTech Connect (OSTI)

The research activities performed in the framework of this project represent a major breakthrough in the demonstration of Photonic Crystals (PhC) as a competitive technology for LEDs with high light extraction efficiency. The goals of the project were to explore the viable approaches to manufacturability of PhC LEDS through proven standard industrial processes, establish the limits of light extraction by various concepts of PhC LEDs, and determine the possible advantages of PhC LEDs over current and forthcoming LED extraction concepts. We have developed three very different geometries for PhC light extraction in LEDs. In addition, we have demonstrated reliable methods for their in-depth analysis allowing the extraction of important parameters such as light extraction efficiency, modal extraction length, directionality, internal and external quantum efficiency. The information gained allows better understanding of the physical processes and the effect of the design parameters on the light directionality and extraction efficiency. As a result, we produced LEDs with controllable emission directionality and a state of the art extraction efficiency that goes up to 94%. Those devices are based on embedded air-gap PhC - a novel technology concept developed in the framework of this project. They rely on a simple and planar fabrication process that is very interesting for industrial implementation due to its robustness and scalability. In fact, besides the additional patterning and regrowth steps, the process is identical as that for standard industrially used p-side-up LEDs. The final devices exhibit the same good electrical characteristics and high process yield as a series of test standard LEDs obtained in comparable conditions. Finally, the technology of embedded air-gap patterns (PhC) has significant potential in other related fields such as: increasing the optical mode interaction with the active region in semiconductor lasers; increasing the coupling of the incident light into the active region of solar cells; increasing the efficiency of the phosphorous light conversion in white light LEDs etc. In addition to the technology of embedded PhC LEDs, we demonstrate a technique for improvement of the light extraction and emission directionality for existing flip-chip microcavity (thin) LEDs by introducing PhC grating into the top n-contact. Although, the performances of these devices in terms of increase of the extraction efficiency are not significantly superior compared to those obtained by other techniques like surface roughening, the use of PhC offers some significant advantages such as improved and controllable emission directionality and a process that is directly applicable to any material system. The PhC microcavity LEDs have also potential for industrial implementation as the fabrication process has only minor differences to that already used for flip-chip thin LEDs. Finally, we have demonstrated that achieving good electrical properties and high fabrication yield for these devices is straightforward.

James Speck; Evelyn Hu; Claude Weisbuch; Yong-Seok Choi; Kelly McGroddy; Gregor Koblmuller; Elison Matioli; Elizabeth Rangel; Fabian Rol; Dobri Simeonov

2010-01-31T23:59:59.000Z

230

High Performance Healthcare Buildings: A Roadmap to Improved Energy Efficiency  

E-Print Network [OSTI]

Roadmap to Improved Energy Efficiency iii 11-Sept-2009 ListA Roadmap to Improved Energy Efficiency 11-Sept-2009 Topic /A Roadmap to Improved Energy Efficiency 11-Sept-2009 Topic /

Singer, Brett C.

2010-01-01T23:59:59.000Z

231

Catalyst Characterization  

Broader source: Energy.gov (indexed) [DOE]

3 Approach: Relevance to Vehicle Technologies Goals * Improve commercial vehicle engine efficiency at least 20% - With an efficient and durable AMOX, higher NOx conversion...

232

High Efficiency Microturbine with Integral Heat Recovery - Fact...  

Broader source: Energy.gov (indexed) [DOE]

Research Center, is developing a clean, cost-effective 370 kW microturbine with 42% net electrical efficiency and 85% total CHP efficiency. The microturbine technology will...

233

Holography as a highly efficient RG flow : Part 1  

E-Print Network [OSTI]

We investigate how the holographic correspondence can be reconstructed as a special RG flow in a strongly interacting large $N$ field theory. We firstly define a "highly efficient RG flow" as one in which the cut-off in momentum space can be adjusted as a functional of the elementary fields, and of the external sources and of the background metric in order to be compatible with the following requirement: the Ward identities for single-trace operators involving conservation of energy, momentum and global charges must preserve the same form at every scale. In order to absorb the contributions of the multi-trace operators to these effective Ward identities, the external sources and the background metric need to be redefined at each scale, and thus they become dynamical as in the dual gravity equations. We give a schematic construction of such highly efficient RG flows using appropriate collective variables, leaving a more explicit construction in certain limits to the second part of this work. We find that all h...

Behr, Nicolas; Mukhopadhyay, Ayan

2015-01-01T23:59:59.000Z

234

Nanocoatings for High-Efficiency Industrial Hydraulic and Tooling Systems  

SciTech Connect (OSTI)

Industrial manufacturing in the U.S. accounts for roughly one third of the 98 quadrillion Btu total energy consumption. Motor system losses amount to 1.3 quadrillion Btu, which represents the largest proportional loss of any end-use category, while pumps alone represent over 574 trillion BTU (TBTU) of energy loss each year. The efficiency of machines with moving components is a function of the amount of energy lost to heat because of friction between contacting surfaces. The friction between these interfaces also contributes to downtime and the loss of productivity through component wear and subsequent repair. The production of new replacement parts requires additional energy. Among efforts to reduce energy losses, wear-resistant, low-friction coatings on rotating and sliding components offer a promising approach that is fully compatible with existing equipment and processes. In addition to lubrication, one of the most desirable solutions is to apply a protective coating or surface treatment to rotating or sliding components to reduce their friction coefficients, thereby leading to reduced wear. Historically, a number of materials such as diamond-like carbon (DLC), titanium nitride (TiN), titanium aluminum nitride (TiAlN), and tungsten carbide (WC) have been examined as tribological coatings. The primary objective of this project was the development of a variety of thin film nanocoatings, derived from the AlMgB14 system, with a focus on reducing wear and friction in both industrial hydraulics and cutting tool applications. Proof-of-concept studies leading up to this project had shown that the constituent phases, AlMgB14 and TiB2, were capable of producing low-friction coatings by pulsed laser deposition. These coatings combine high hardness with a low friction coefficient, and were shown to substantially reduce wear in laboratory tribology tests. Selection of the two applications was based largely on the concept of improved mechanical interface efficiencies for energy conservation. In mobile hydraulic systems, efficiency gains through low friction would translate into improved fuel economy and fewer greenhouse gas emissions. Stationary hydraulic systems, accordingly, would consume less electrical power. Reduced tooling wear in machining operations would translate to greater operating yields, while lowering the energy consumed during processing. The AlMgB14 nanocoatings technology progressed beyond baseline laboratory tests into measurable energy savings and enhancements to product durability. Three key hydraulic markets were identified over the course of the project that will benefit from implementation: industrial vane pumps, orbiting valve-in-star hydraulic motors, and variable displacement piston pumps. In the vane pump application, the overall product efficiency was improved by as much as 11%. Similar results were observed with the hydraulic motors tested, where efficiency gains of over 10% were noted. For variable displacement piston pumps, overall efficiency was improved by 5%. For cutting tools, the most significant gains in productivity (and, accordingly, the efficiency of the machining process as a whole) were associated with the roughing and finishing of titanium components for aerospace systems. Use of the AlMgB14 nanocoating in customer field tests has shown that the coated tools were able to withstand machining rates as high as 500sfm (limited only by the substrate material), with relatively low flank wear when compared to other industrial offerings. AlMgB14 coated tools exhibited a 60% improvement over similarly applied TiAlN thin films. Furthermore, AlMgB14-based coatings in these particular tests lasted twice as long than their TiAlN counterparts at the 500sfm feed rates. Full implementation of the technology into the industrial hydraulic and cutting tool markets equates to a worldwide energy savings of 46 trillion BTU/year by 2030. U.S.-based GHG emissions associated with the markets identified would fall accordingly, dropping by as much as 50,000 tonnes annually.

Clifton B. Higdon III

2011-01-07T23:59:59.000Z

235

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

2011-09-30T23:59:59.000Z

236

Integrated process and dual-function catalyst for olefin epoxidation  

DOE Patents [OSTI]

The invention discloses a dual-functional catalyst composition and an integrated process for production of olefin epoxides including propylene oxide by catalytic reaction of hydrogen peroxide from hydrogen and oxygen with olefin feeds such as propylene. The epoxides and hydrogen peroxide are preferably produced simultaneously in situ. The dual-functional catalyst comprises noble metal crystallites with dimensions on the nanometer scale (on the order of <1 nm to 10 nm), specially dispersed on titanium silicalite substrate particles. The dual functional catalyst catalyzes both the direct reaction of hydrogen and oxygen to generate hydrogen peroxide intermediate on the noble metal catalyst surface and the reaction of the hydrogen peroxide intermediate with the propylene feed to generate propylene oxide product. Combining both these functions in a single catalyst provides a very efficient integrated process operable below the flammability limits of hydrogen and highly selective for the production of hydrogen peroxide to produce olefin oxides such as propylene oxide without formation of undesired co-products.

Zhou, Bing (Cranbury, NJ); Rueter, Michael (Plymouth Meeting, PA)

2003-01-01T23:59:59.000Z

237

High Efficiency, Low Emissions Homogeneous Charge Compression Ignition (HCCI) Engines  

SciTech Connect (OSTI)

This is the final report of the High Efficiency Clean Combustion (HECC) Research Program for the U.S. Department of Energy. Work under this co-funded program began in August 2005 and finished in July 2010. The objective of this program was to develop and demonstrate a low emission, high thermal efficiency engine system that met 2010 EPA heavy-duty on-highway truck emissions requirements (0.2g/bhp-hr NOx, 0.14g/bhp-hr HC and 0.01g/bhp-hr PM) with a thermal efficiency of 46%. To achieve this goal, development of diesel homogenous charge compression ignition (HCCI) combustion was the chosen approach. This report summarizes the development of diesel HCCI combustion and associated enabling technologies that occurred during the HECC program between August 2005 and July 2010. This program showed that although diesel HCCI with conventional US diesel fuel was not a feasible means to achieve the program objectives, the HCCI load range could be increased with a higher volatility, lower cetane number fuel, such as gasoline, if the combustion rate could be moderated to avoid excessive cylinder pressure rise rates. Given the potential efficiency and emissions benefits, continued research of combustion with low cetane number fuels and the effects of fuel distillation are recommended. The operation of diesel HCCI was only feasible at part-load due to a limited fuel injection window. A 4% fuel consumption benefit versus conventional, low-temperature combustion was realized over the achievable operating range. Several enabling technologies were developed under this program that also benefited non-HCCI combustion. The development of a 300MPa fuel injector enabled the development of extended lifted flame combustion. A design methodology for minimizing the heat transfer to jacket water, known as precision cooling, will benefit conventional combustion engines, as well as HCCI engines. An advanced combustion control system based on cylinder pressure measurements was developed. A Well-to-wheels analysis of the energy flows in a mobile vehicle system and a 2nd Law thermodynamic analysis of the engine system were also completed under this program.

None

2011-01-31T23:59:59.000Z

238

Graphene nanosheets-polypyrrole hybrid material as a highly active catalyst support for formic acid electro-oxidation  

E-Print Network [OSTI]

electro-oxidation when the weight feed ratio of GO to pyrrole monomer is 2 : 1. The superior performance. Therefore, the synthesis of hybrid materials consisting of reduced graphene oxide (RGO) with PPy matrix polymerization method (Fig. 1). Then the palladium Fig. 1 Schematic of the synthesis of Pd/RGO-PPy catalysts

Gao, Hongjun

239

Magnetic Refrigeration Technology for High Efficiency Air Conditioning  

SciTech Connect (OSTI)

Magnetic refrigeration was investigated as an efficient, environmentally friendly, flexible alternative to conventional residential vapor compression central air conditioning systems. Finite element analysis (FEA) models of advanced geometry active magnetic regenerator (AMR) beds were developed to minimize bed size and thus magnet mass by optimizing geometry for fluid flow and heat transfer and other losses. Conventional and magnetocaloric material (MCM) regenerator fabrication and assembly techniques were developed and advanced geometry passive regenerators were built and tested. A subscale engineering prototype (SEP) magnetic air conditioner was designed, constructed and tested. A model of the AMR cycle, combined with knowledge from passive regenerator experiments and FEA results, was used to design the regenerator beds. A 1.5 Tesla permanent magnet assembly was designed using FEA and the bed structure and plenum design was extensively optimized using FEA. The SEP is a flexible magnetic refrigeration platform, with individually instrumented beds and high flow rate and high frequency capability, although the current advanced regenerator geometry beds do not meet performance expectations, probably due to manufacturing and assembly tolerances. A model of the AMR cycle was used to optimize the design of a 3 ton capacity magnetic air conditioner, and the system design was iterated to minimize external parasitic losses such as heat exchanger pressure drop and fan power. The manufacturing cost for the entire air conditioning system was estimated, and while the estimated SEER efficiency is high, the magnetic air conditioning system is not cost competitive as currently configured. The 3 ton study results indicate that there are other applications where magnetic refrigeration is anticipated to have cost advantages over conventional systems, especially applications where magnetic refrigeration, through the use of its aqueous heat transfer fluid, could eliminate intermediate heat exchangers or oil distribution issues found in traditional vapor compression systems.

Boeder, A; Zimm, C

2006-09-30T23:59:59.000Z

240

High-energy mechanical synthesis of nanophase fluorite-structured mixed oxide catalysts with a high redox activity  

SciTech Connect (OSTI)

A series of nanostructured, highly defective, ternary solid solutions containing CeO{sub 2}, ZrO{sub 2}, and MnO{sub 2} or CuO were prepared by high-energy mechanical milling of individual components. Morphological and redox properties were studied by XRD, HRTEM and temperature-programmed reduction techniques. It was shown that the introduction of small amounts of copper and manganese strongly promotes the redox behavior of cerium at lower temperatures in comparison with CeO{sub 2} and CeO{sub 2}-ZrO{sub 2}. High temperature treatment of up to 1,400 K was also shown to further promote overall redox capacity without affecting low-temperature redox behavior. Moreover, evidence is provided to show that Cu and Mn are dissolved within the CeO{sub 2} lattice structure. Addition of dopants enhances catalytic redox properties in the oxidation of CO at low temperatures, which is associated with the high concentration of oxygen vacancies that form on the introduction of aliovalent elements into the ceria-zirconia lattice.

Primavera, A.; Trovarelli, A.; Terribile, D.; Leitenburg, C. de; Dolcetti, G. [Univ. di Udine (Italy). Dipt. di Scienze e Tecnologie Chimiche; Llorca, J. [Univ. de Barcelona (Spain). Dept. de Quimica Inorganica

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Processes for producing low cost, high efficiency silicon solar cells  

DOE Patents [OSTI]

Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime {tau} and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime {tau} and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO{sub x}. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure. 28 figs.

Rohatgi, A.; Doshi, P.; Tate, J.K.; Mejia, J.; Chen, Z.

1998-06-16T23:59:59.000Z

242

Highly Efficient Small Form Factor LED Retrofit Lamp  

SciTech Connect (OSTI)

This report summarizes work to develop a high efficiency LED-based MR16 lamp downlight at OSRAM SYLVANIA under US Department of Energy contract DE-EE0000611. A new multichip LED package, electronic driver, and reflector optic were developed for these lamps. At steady-state, the lamp luminous flux was 409 lumens (lm), luminous efficacy of 87 lumens per watt (LPW), CRI (Ra) of 87, and R9 of 85 at a correlated color temperature (CCT) of 3285K. The LED alone achieved 120 lumens per watt efficacy and 600 lumen flux output at 25 C. The driver had 90% electrical conversion efficiency while maintaining excellent power quality with power factor >0.90 at a power of only 5 watts. Compared to similar existing MR16 lamps using LED sources, these lamps had much higher efficacy and color quality. The objective of this work was to demonstrate a LED-based MR16 retrofit lamp for replacement of 35W halogen MR16 lamps having (1) luminous flux of 500 lumens, (2) luminous efficacy of 100 lumens per watt, (3) beam angle less than 40{sup o} and center beam candlepower of at least 1000 candelas, and (4) excellent color quality.

Steven Allen; Fred Palmer; Ming Li

2011-09-11T23:59:59.000Z

243

Processes for producing low cost, high efficiency silicon solar cells  

DOE Patents [OSTI]

Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure.

Rohatgi, Ajeet (Marietta, GA); Doshi, Parag (Altanta, GA); Tate, John Keith (Lawrenceville, GA); Mejia, Jose (Atlanta, GA); Chen, Zhizhang (Duluth, GA)

1998-06-16T23:59:59.000Z

244

Processes for producing low cost, high efficiency silicon solar cells  

DOE Patents [OSTI]

Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. Silicon solar cell efficiencies of 16.9% have been achieved. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x.

Rohatgi, Ajeet (Marietta, GA); Chen, Zhizhang (Duluth, GA); Doshi, Parag (Atlanta, GA)

1996-01-01T23:59:59.000Z

245

Tethered catalysts for the hydration of carbon dioxide  

DOE Patents [OSTI]

A system is provided that substantially increases the efficiency of CO.sub.2 capture and removal by positioning a catalyst within an optimal distance from the air-liquid interface. The catalyst is positioned within the layer determined to be the highest concentration of carbon dioxide. A hydrophobic tether is attached to the catalyst and the hydrophobic tether modulates the position of the catalyst within the liquid layer containing the highest concentration of carbon dioxide.

Valdez, Carlos A; Satcher, Jr., Joe H; Aines, Roger D; Wong, Sergio E; Baker, Sarah E; Lightstone, Felice C; Stolaroff, Joshuah K

2014-11-04T23:59:59.000Z

246

Catalyst by Design - Theoretical, Nanostructural, and Experimental...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. p-08narula.pdf More Documents & Publications Catalyst by Design...

247

Combustion Catalysts in Industry- An Update  

E-Print Network [OSTI]

applications of combustion catalysts for coal are presented. Combustion efficiency and calculations are discussed, followed by an explanation of the theories of combustion catalysis and a review of three case histories....

Merrell, G. A.; Knight, R. S.

248

Screw pumps provide high efficiency in transport of Orinoco bitumen  

SciTech Connect (OSTI)

One of the world`s largest known deposits of extra natural bitumen is located in the Orinoco River basin of eastern Venezuela. Production and transportation of an emulsion of bitumen and water is one of the major projects being directed by Petroleos de Venezuela S.A. This paper reviews the pump selection options considered in transporting this bitumen to a viable processing facility. The three pump types evaluated were centrifugal, reciprocating, or rotary screw. Performance and cost parameters are evaluated and the screw pump was determined to be the most economical, high performance choice. The paper goes on to describe the installation of the main transport lines and efficiency of these new pumps.

Brennan, J.R. [IMO Industries, Inc., Monroe, NC (United States)

1995-03-01T23:59:59.000Z

249

Performance of a high efficiency advanced coal combustor  

SciTech Connect (OSTI)

Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the primary act,'' and three further annuli for the supply of the secondary air.'' The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States))

1989-12-01T23:59:59.000Z

250

High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty...  

Broader source: Energy.gov (indexed) [DOE]

High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel Reactivity Control High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel...

251

High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical...  

Office of Environmental Management (EM)

High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 High-Efficiency Low-Cost Solar Receiver for Use in a Supercritical CO2...

252

High-Efficiency Clean Combustion in Light-Duty Multi-Cylinder...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Efficiency Clean Combustion in Light-Duty Multi-Cylinder Diesel Engines High-Efficiency Clean Combustion in Light-Duty Multi-Cylinder Diesel Engines 2010 DOE Vehicle...

253

Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission Engines Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission Engines Presentation given at DEER...

254

catalyst beds | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

catalyst beds catalyst beds Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a candidate...

255

frequency high efficiency two-stage approach for future microprocessors  

E-Print Network [OSTI]

It is perceived that Moore’s Law will prevail at least for the next decade, with continuous advancements of processing technologies for very-large-scale integrated (VLSI) circuits. Nano technology is driving VLSI circuits in a path of greater transistor integration, faster clock frequency, and lower operation voltage. This has imposed a new challenge for delivering highquality power to modern processors. Power management technology is critical for transferring the required high current in a highly efficient way, and accurately regulating the sub-1V voltage in very fast dynamic transient response conditions. Furthermore, the VRs are limited in a given area and the power density is important to save the precious real estate of the motherboard. Based on the power delivery path model, the analysis results show that as long as the bandwidth can reach around 350 kHz, the bulk capacitor of the VR can be completely eliminated, which means significant savings in cost and real estate. Analysis also indicates that 650kHz bandwidth can reduce the number of the decoupling capacitor from 230 to 50 for future microprocessor case. Beyond 650kHz, the reduction is not obvious any more due to the parasitic components along the power delivery path. Following the vision of high bandwidth, the VRs need to operate at much higher frequency

Yuancheng Ren; Dusan Boroyevich; Daan Wyk; Guo Quan; Lu Douglas; K. Lindner; Yuancheng Ren

256

Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study  

SciTech Connect (OSTI)

In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

2014-07-01T23:59:59.000Z

257

Novel Reforming Catalysts  

SciTech Connect (OSTI)

Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

Pfefferle, Lisa D; Haller, Gary L

2012-10-16T23:59:59.000Z

258

High Performance Healthcare Buildings: A Roadmap to Improved Energy Efficiency  

E-Print Network [OSTI]

Efficiency 11-Sept-2009 9. Economic and Organizationaland Organizational Issues 9.1. Strategies to overcome structural challenges to energy efficiencyorganizational scheme to facilitate discussion of challenges to improving energy efficiency

Singer, Brett C.

2010-01-01T23:59:59.000Z

259

Toward high-energy-density, high-efficiency, and moderate-temperature chip-scale thermophotovoltaics  

E-Print Network [OSTI]

- thermophotovoltaic (TPV) generator. The approach is predicted to be capable of up to 32% efficient heat system that was built and tested comprises a silicon propane microcombustor, an inte- grated high, generating 344 mW of electric power over a 1-cm2 area. catalytic combustion | micro generator | thermal

Soljaèiæ, Marin

260

High Efficiency of Gamma-Ray Bursts Revisited  

E-Print Network [OSTI]

efficiency of gamma-ray bursts by assuming that the ejecta from the central engine are equally massive and

Y. C. Zou A; Z. G. Dai B

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Advanced Combustion Technology to Enable High Efficiency Clean...  

Broader source: Energy.gov (indexed) [DOE]

for Efficiency Improvement Controls Variable Valve Actuation Variable Intake Swirl Turbo Technology Electrically Driven Components Aftertreatment Integration of Cummins...

262

Novel Solid Base Catalysts for the Production of Biodiesel from Lipids  

E-Print Network [OSTI]

The primary commercial biodiesel production processes use homogeneous base catalysts which cause separation and wastewater discharge problems. Solid base catalysts can overcome these drawbacks. However, a solid base catalyst with high activity...

Zhao, Lina

2010-12-17T23:59:59.000Z

263

Single-step CVD growth of high-density carbon nanotube forests on metallic Ti coatings through catalyst engineering  

E-Print Network [OSTI]

was carried out by heating the substrates under 500 sccm pure H2, 15 mbar from room 8 temperature to 650?C in 3min, then switching off the heater power and letting the samples to cool down with the H2 flow on. As shown in Fig. 3a, for the conventional... , Futaba DN, Mizuno K, Namai T, Yumura M, Iijima S. Water-assisted highly efficient synthesis of impurity-free single-walled carbon nanotubes. Science. 2004;306:1362-4. [4] Hart AJ, Slocum AH. Rapid growth and flow-mediated nucleation of millimeter...

Zhong, Guofang; Xie, Rongsi; Yang, Junwei; Robertson, John

2013-10-29T23:59:59.000Z

264

Development of manufacturing capability for high-concentration, high-efficiency silicon solar cells  

SciTech Connect (OSTI)

This report presents a summary of the major results from a program to develop a manufacturable, high-efficiency silicon concentrator solar cell and a cost-effective manufacturing facility. The program was jointly funded by the Electric Power Research Institute, Sandia National Laboratories through the Concentrator Initiative, and SunPower Corporation. The key achievements of the program include the demonstration of 26%-efficient silicon concentrator solar cells with design-point (20 W/cm{sup 2}) efficiencies over 25%. High-performance front-surface passivations; that were developed to achieve this result were verified to be absolutely stable against degradation by 475 days of field exposure at twice the design concentration. SunPower demonstrated pilot production of more than 1500 of these cells. This cell technology was also applied to pilot production to supply 7000 17.7-cm{sup 2} one-sun cells (3500 yielded wafers) that demonstrated exceptional quality control. The average efficiency of 21.3% for these cells approaches the peak efficiency ever demonstrated for a single small laboratory cell within 2% (absolute). Extensive cost models were developed through this program and calibrated by the pilot-production project. The production levels achieved indicate that SunPower could produce 7-10 MW of concentrator cells per year in the current facility based upon the cell performance demonstrated during the program.

Sinton, R.A.; Verlinden, P.J.; Crane, R.A.; Swanson, R.N. [SunPower Corp., Sunnyvale, CA (United States)

1996-10-01T23:59:59.000Z

265

High-efficiency photovoltaics based on semiconductor nanostructures  

SciTech Connect (OSTI)

The objective of this project was to exploit a variety of semiconductor nanostructures, specifically semiconductor quantum wells, quantum dots, and nanowires, to achieve high power conversion efficiency in photovoltaic devices. In a thin-film device geometry, the objectives were to design, fabricate, and characterize quantum-well and quantum-dot solar cells in which scattering from metallic and/or dielectric nanostructures was employed to direct incident photons into lateral, optically confined paths within a thin (~1-3um or less) device structure. Fundamental issues concerning nonequilibrium carrier escape from quantum-confined structures, removal of thin-film devices from an epitaxial growth substrate, and coherent light trapping in thin-film photovoltaic devices were investigated. In a nanowire device geometry, the initial objectives were to engineer vertical nanowire arrays to optimize optical confinement within the nanowires, and to extend this approach to core-shell heterostructures to achieve broadspectrum absorption while maintaining high opencircuit voltages. Subsequent work extended this approach to include fabrication of nanowire photovoltaic structures on low-cost substrates.

Yu, Paul K.L. [University of California, San Diego; Yu, Edward T. [University of Texas at Austin; Wang, Deli [University of California, San Diego

2011-10-31T23:59:59.000Z

266

Gaz de France ordering high-efficiency drivers  

SciTech Connect (OSTI)

For natural gas transmission, distribution, and storage operations, Gaz de France is installing Creusot-Loire's new line of high-efficiency gas-turbine packages, powered by Allison 501 and 570 generators for compressor speeds exceeding 10,000 rpm. The Type CA.3 driver comprises a 501 generator coupled to a two-stage power turbine; the ISO base rating is 3265 kW on gas fuel with a heat rate of 12,050 Btu/kWhr. The CA.5 driver with the stronger 570 gas-turbine engine is base-rated at 4805 kW with a heat rate of 11,360 Btu/kWhr. Designed for direct-drive, with no intermediary gearing, the high-speed compressor operates on the 13,820-rpm output shaft speed of the CA.3 for baseload requirements or on 11,500 rpm for the more powerful CA.5 set. These compressor packages will serve as boosters for the transmission and storage of regasified LNG from Algeria and natural gas from the North Sea, USSR, and France's own Lacq fields.

de Biasi, V.

1980-11-01T23:59:59.000Z

267

High Efficiency, Ultra-Low Emission, Integrated Process Heater System  

SciTech Connect (OSTI)

The team of TIAX LLC, ExxonMobil Research and Engineering Company, and Callidus Technologies, LLC conducted a six-year program to develop an ultra-low emission process heater burner and an advanced high efficiency heater design. This project addresses the critical need of process heater operators for reliable, economical emission reduction technologies to comply with stringent emission regulations, and for heater design alternatives that reduce process heater energy requirements without significant cost increase. The key project targets were NOx emissions of 10 ppm (@ 3% O2), and a heater thermal efficiency of 95 percent. The ultra low NOx burner was developed through a series of pilot-scale and field tests combined with computational fluid dynamic modeling to arrive at simultaneous low emissions and suitable flame shape and stability. Pilot scale tests were run at TIAX, at the 2 MMBtu/hr scale, and at Callidus at 8 MMBtu/hr. The full scale burner was installed on a 14 burner atmospheric pipestill furnace at an ExxonMobil refinery. A variety of burner configurations, gas tips and flame stabilizers were tested to determine the lowest emissions with acceptable flame shape and stability. The resulting NOx emissions were 22 ppm on average. Starting in 2001, Callidus commercialized the original ultra low NOx burner and made subsequent design improvements in a series of commercial burners evolving from the original concept and/or development. Emissions in the field with the ultra low-NOx burner over a broad spectrum of heater applications have varied from 5 ppm to 30 ppm depending on heater geometry, heater service, fuel and firing capacity. To date, 1550 of the original burners, and 2500 of subsequent generation burners have been sold by Callidus. The advanced heater design was developed by parametric evaluations of a variety of furnace and combustion air preheater configurations and technologies for enhancing convective and radiative heat transfer. The design evolution relied heavily on computational fluid dynamic predictions of design alternatives. The final design features modular separate radiant cells, each with one and two-side fired vertical tubes. The convection section configuration is vertical tube banks enclosed in the radiant channels. Commercial modular plate air preheaters are used. The predicted performance for the integrated advanced heater and Callidus burner is 95 percent efficiency with 9 ppm NOx emissions firing natural gas, and 12 ppm firing refinery gas. The total erected cost is less than a conventional heater with combustion air preheat.

Mason, Howard; Boral, Anindya; Chhotray, San; Martin, Matthew

2006-06-19T23:59:59.000Z

268

High performance robust F-doped tin oxide based oxygen evolution electro-catalysts for PEM based water electrolysis  

SciTech Connect (OSTI)

Identification and development of non-noble metal based electro-catalysts or electro-catalysts comprising compositions with significantly reduced amounts of expensive noble metal contents (e.g. IrO{sub 2}, Pt) with comparable electrochemical performance to the standard noble metal/metal oxide for proton exchange membrane (PEM) based water electrolysis would signify a major breakthrough in hydrogen generation via water electrolysis. Development of such systems would lead to two primary outcomes: first, a reduction in the overall capital costs of PEM based water electrolyzers, and second, attainment of the targeted hydrogen production costs (<$3.00/gge delivered by 2015) comparable to conventional liquid fuels. In line with these goals, by exploiting a two-pronged theoretical first principles and experimental approach herein, we demonstrate for the very first time a solid solution of SnO{sub 2}:10 wt% F containing only 20 at.% IrO{sub 2} [e.g. (Sn{sub 0.80}Ir{sub 0.20})O{sub 2}:10F] displaying remarkably similar electrochemical activity and comparable or even much improved electrochemical durability compared to pure IrO{sub 2}, the accepted gold standard in oxygen evolution electro-catalysts for PEM based water electrolysis. We present the results of these studies.

Datta, Moni Kanchan; Kadakia, Karan; Velikokhatnyi, Oleg I.; Jampani, Prashanth H.; Chung, Sung Jae; Poston, James A.; Manivannan, Ayyakkannu; Kumta, Prashant N.

2013-01-01T23:59:59.000Z

269

High-Efficiency Nitride-Based Solid-State Lighting  

SciTech Connect (OSTI)

In this final technical progress report we summarize research accomplished during Department of Energy contract DE-FC26-01NT41203, entitled ''High-Efficiency Nitride-Based Solid-State Lighting''. Two teams, from the University of California at Santa Barbara (Principle Investigator: Dr. Shuji Nakamura) and the Lighting Research Center at Rensselaer Polytechnic Institute (led by Dr. N. Narendran), pursued the goals of this contract from thin film growth, characterization, and packaging/luminaire design standpoints. The UCSB team initially pursued the development of blue gallium nitride (GaN)-based vertical-cavity surface-emitting lasers, as well as ultraviolet GaN-based light emitting diodes (LEDs). In Year 2, the emphasis shifted to resonant-cavity light emitting diodes, also known as micro-cavity LEDs when extremely thin device cavities are fabricated. These devices have very directional emission and higher light extraction efficiency than conventional LEDs. Via the optimization of thin-film growth and refinement of device processing, we decreased the total cavity thickness to less than 1 {micro}m, such that micro-cavity effects were clearly observed and a light extraction efficiency of over 10% was reached. We also began the development of photonic crystals for increased light extraction, in particular for so-called ''guided modes'' which would otherwise propagate laterally in the device and be re-absorbed. Finally, we pursued the growth of smooth, high-quality nonpolar a-plane and m-plane GaN films, as well as blue light emitting diodes on these novel films. Initial nonpolar LEDs showed the expected behavior of negligible peak wavelength shift with increasing drive current. M-plane LEDs in particular show promise, as unpackaged devices had unsaturated optical output power of {approx} 3 mW at 200 mA drive current. The LRC's tasks were aimed at developing the subcomponents necessary for packaging UCSB's light emitting diodes, and packaging them to produce a white light fixture. During the third and final year of the project, the LRC team investigated alternate packaging methods for the white LED device to achieve at least 25 percent more luminous efficacy than traditional white LEDs; conducted optical ray-tracing analyses and human factors studies to determine the best form factor for the white light source under development, in terms of high luminous efficacy and greater acceptance by subjects; and developed a new die encapsulant using silicone-epoxy resins that showed less yellowing and slower degradation. At the conclusion of this project, the LRC demonstrated a new packaging method, called scattered photon extraction (SPE), that produced an average luminous flux and corresponding average efficacy of 90.7 lm and 36.3 lm/W, respectively, compared with 56.5 lm and 22.6 lm/W for a similar commercial white LED package. At low currents, the SPE package emitted white light with an efficacy of over 80 lm/W and had chromaticity values very close to the blackbody locus. The SPE package showed an overall improvement of 61% for this particular comparison, exceeding the LRC's third-year goal of 25% improvement.

Paul T. Fini; Shuji Nakamura

2005-07-30T23:59:59.000Z

270

Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion  

SciTech Connect (OSTI)

The project which extended from November 2005 to May of 2010 demonstrated the application of Low Temperature Combustion (LTC) with engine out NOx levels of 0.2 g/bhp-hr throughout the program target load of 12.6bar BMEP. The project showed that the range of loads could be extended to 16.5bar BMEP, therefore matching the reference lug line of the base 2007 MY Navistar 6.4L V8 engine. Results showed that the application of LTC provided a dramatic improvement over engine out emissions when compared to the base engine. Furthermore LTC improved thermal efficiency by over 5% from the base production engine when using the steady state 13 mode composite test as a benchmark. The key enablers included improvements in the air, fuel injection, and cooling systems made in Phases I and II. The outcome was the product of a careful integration of each component under an intelligent control system. The engine hardware provided the conditions to support LTC and the controller provided the necessary robustness for a stable combustion. Phase III provided a detailed account on the injection strategy used to meet the high load requirements. During this phase, the control strategy was implemented in a production automotive grade ECU to perform cycle-by-cycle combustion feedback on each of the engine cylinders. The control interacted on a cycle base with the injection system and with the Turbo-EGR systems according to their respective time constants. The result was a unique system that could, first, help optimize the combustion system and maintain high efficiency, and secondly, extend the steady state results to the transient mode of operation. The engine was upgraded in Phase IV with a Variable Valve Actuation system and a hybrid EGR loop. The impact of the more versatile EGR loop did not provide significant advantages, however the application of VVA proved to be an enabler to further extend the operation of LTC and gain considerable benefits in fuel economy and soot reduction. Finally, the transient demonstration was performed in Phase IV. The project demonstrated the achievement of meeting US10 emissions without NOx aftertreatment. The successful execution of the project has served to highlight the effectiveness of closely matched combustion predictive tools to engine testing. It has further served to highlight the importance of key technologies and future areas of research and development. In this regard, recommendations are made towards further improvements in the areas of engine hardware, fuel injection systems, controls and fuels.

Ojeda, William de

2010-07-31T23:59:59.000Z

271

Catalyst Characterization  

Broader source: Energy.gov (indexed) [DOE]

constrains on engine-out NOx emissions and allowing engines to be tuned for optimal fuel efficiency, cost and durability - Increases acceptance of clean diesel by the public....

272

Low Temperature Combustion Demonstrator for High Efficiency Clean...  

Broader source: Energy.gov (indexed) [DOE]

NOx after-treatment and with minimized soot Target today's Diesel fuel - Improve break thermal efficiency to 5% over current production - The technology generated in project to...

273

Laclede Gas Company- Residential High Efficiency Heating Rebate Program  

Broader source: Energy.gov [DOE]

Laclede Gas Company offers various rebates to residential customers for investing in energy efficient equipment and appliances. Residential customers can qualify for rebates on boilers, furnaces,...

274

Southwest Gas Corporation- Commercial High-Efficiency Equipment Rebate Program  

Broader source: Energy.gov [DOE]

Southwest Gas Corporation (SWG) offers rebates to commercial customers in Arizona who purchase energy efficient natural gas equipment. Eligible equipment includes natural gas storage and tankless...

275

Electrochemical catalyst recovery method  

DOE Patents [OSTI]

A method of recovering catalyst material from latent catalyst material solids includes: (a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; (b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; (c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and (d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications. 3 figs.

Silva, L.J.; Bray, L.A.

1995-05-30T23:59:59.000Z

276

Enhancement of alkylation catalysts for improved supercritical fluid regeneration  

DOE Patents [OSTI]

A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID)

2010-12-28T23:59:59.000Z

277

HIGH-EFFICIENCY NITRIDE-BASED SOLID-STATE LIGHTING  

SciTech Connect (OSTI)

In this semiannual report we summarize the progress obtained in the first six months with the support of DoE contract No.DE-FC26-01NT41203, entitled ''High-Efficiency Nitride-Based Solid-State Lighting''. The two teams, from the University of California at Santa Barbara (Principle Investigator: Dr. Shuji Nakamura) and Rensselaer Polytechnic Institute (led by Dr. N. Narendran), are pursuing the goals of this contract from thin film growth, characterization, and packaging standpoints. The UCSB team has made significant progress in the development of GaN vertical cavity surface-emitting lasers (VCSELs) as well as light-emitting diodes (LEDs) with AlGaN active regions emitting in the ultraviolet (UV). The Rensselaer team has developed target specifications for some of the key parameters for the proposed solid-state lighting system, including a luminous flux requirement matrix for various lighting applications, optimal spectral power distributions, and the performance characteristics of currently available commercial LEDs for eventual comparisons to the devices developed in the scope of this project.

Dr. Paul T. Fini; Prof. Shuji Nakamura

2002-04-30T23:59:59.000Z

278

HIGH-EFFICIENCY NITRIDE-BASED SOLID-STATE LIGHTING  

SciTech Connect (OSTI)

In this annual report we summarize the progress obtained in the first year with the support of DoE contract No.DE-FC26-01NT41203, entitled ''High-Efficiency Nitride-Based Solid-State Lighting''. The two teams, from the University of California at Santa Barbara (Principle Investigator: Dr. Shuji Nakamura) and Rensselaer Polytechnic Institute (led by Dr. N. Narendran), are pursuing the goals of this contract from thin film growth, characterization, and packaging standpoints. The UCSB team has made significant progress in the development of GaN vertical cavity surface-emitting lasers (VCSELs) as well as light-emitting diodes (LEDs) with AlGaN active regions emitting in the ultraviolet (UV). The Rensselaer team has developed target specifications for some of the key parameters for the proposed solid-state lighting system, including a luminous flux requirement matrix for various lighting applications, optimal spectral power distributions, and the performance characteristics of currently available commercial LEDs for eventual comparisons to the devices developed in the scope of this project.

Dr. Paul T. Fini; Prof. Shuji Nakamura

2002-09-01T23:59:59.000Z

279

High efficiency proportional neutron detector with solid liner internal structures  

DOE Patents [OSTI]

A tube-style neutron detector, a panel-style neutron detector incorporating a plurality of tube-style neutron detectors, and a panel-style neutron detector including a plurality of anode wires are provided. A plurality of channels is provided in a neutron detector such that each channel has an inner surface of a coating layer including a neutron-absorbing material. A wire anode is provided at end of each channel so that electrons generated by a charged daughter particle generated by a neutron are collected to detect a neutron-matter interaction. Moderator units can be incorporated into a neutron detector to provide improved detection efficiencies and/or to determine neutron energy spectrum. Gas-based proportional response from the neutron detectors can be employed for special nuclear material (SNM) detection. This neutron detector can provide similar performance to .sup.3He-based detectors without requiring .sup.3He and without containing toxic, flammable, or high-pressure materials.

Kisner, Roger Allen; Holcomb, David Eugene; Brown, Gilbert M.

2014-08-05T23:59:59.000Z

280

High Excitation Transfer Efficiency from Energy Relay Dyes in Dye-Sensitized Solar Cells  

E-Print Network [OSTI]

High Excitation Transfer Efficiency from Energy Relay Dyes in Dye-Sensitized Solar Cells Brian E, TT1, to increase the overall power conversion efficiency of a dye-sensitized solar cell (DSC) from 3 be efficiently implemented in optimized dye-sensitized solar cells, but also highlights the need to design highly

McGehee, Michael

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

ENERGY-EFFICIENT RESOURCE MANAGEMENT FOR HIGH-PERFORMANCE COMPUTING PLATFORMS  

E-Print Network [OSTI]

ENERGY-EFFICIENT RESOURCE MANAGEMENT FOR HIGH-PERFORMANCE COMPUTING PLATFORMS Except where School Engineering #12;ENERGY-EFFICIENT RESOURCE MANAGEMENT FOR HIGH-PERFORMANCE COMPUTING PLATFORMS of the Requirements for the Degree of Doctor of Philosophy Auburn, Alabama August 9, 2008 #12;iii ENERGY-EFFICIENT

Qin, Xiao

282

Advanced Nanomaterials for High-Efficiency Solar Cells  

SciTech Connect (OSTI)

Energy supply has arguably become one of the most important problems facing humankind. The exponential demand for energy is evidenced by dwindling fossil fuel supplies and record-high oil and gas prices due to global population growth and economic development. This energy shortage has significant implications to the future of our society, in addition to the greenhouse gas emission burden due to consumption of fossil fuels. Solar energy seems to be the most viable choice to meet our clean energy demand given its large scale and clean/renewable nature. However, existing methods to convert sun light into electricity are not efficient enough to become a practical alternative to fossil fuels. This DOE project aims to develop advanced hybrid nanomaterials consisting of semiconductor nanoparticles (quantum dots or QDs) supported on graphene for cost-effective solar cells with improved conversion efficiency for harvesting abundant, renewable, clean solar energy to relieve our global energy challenge. Expected outcomes of the project include new methods for low-cost manufacturing of hybrid nanostructures, systematic understanding of their properties that can be tailored for desired applications, and novel photovoltaic cells. Through this project, we have successfully synthesized a number of novel nanomaterials, including vertically-oriented graphene (VG) sheets, three-dimensional (3D) carbon nanostructures comprising few-layer graphene (FLG) sheets inherently connected with CNTs through sp{sup 2} carbons, crumpled graphene (CG)-nanocrystal hybrids, CdSe nanoparticles (NPs), CdS NPs, nanohybrids of metal nitride decorated on nitrogen-doped graphene (NG), QD-carbon nanotube (CNT) and QD-VG-CNT structures, TiO{sub 2}-CdS NPs, and reduced graphene oxide (RGO)-SnO{sub 2} NPs. We further assembled CdSe NPs onto graphene sheets and investigated physical and electronic interactions between CdSe NPs and the graphene. Finally we have demonstrated various applications of these nanomaterials in solar cells (both as photoanodes and counter electrodes), gas sensors, and energy storage devices. This research is potentially transformative since the availability of affordable hybrid nanostructures and their fundamental properties will enable various innovative applications of the multifunctional hybrid nanostructures and thus will accelerate new discoveries and inventions in nanoscience and nanotechnology.

Chen, Junhong [University of Wisconsin-Milwaukee] [University of Wisconsin-Milwaukee

2013-11-29T23:59:59.000Z

283

EVALUATION OF A LOW FRICTION - HIGH EFFICIENCY ROLLER BEARING ENGINE  

SciTech Connect (OSTI)

This Low Friction (High Efficiency Roller Bearing) Engine (LFE) report presents the work done by The Timken Company to conduct a technology demonstration of the benefits of replacing hydrodynamic bearings with roller bearings in the crankshaft and camshaft assemblies of an internal combustion engine for the purpose of collecting data sufficient to prove merit. The engines in the present study have been more extensively converted to roller bearings than any previous studies (40 needle roller bearings per engine) to gain understanding of the full potential of application of bearing technology. The project plan called for comparative testing of a production vehicle which was already respected for having demonstrated low engine friction levels with a rollerized version of that engine. Testing was to include industry standard tests for friction, emissions and fuel efficiency conducted on instrumented dynamometers. Additional tests for fuel efficiency, cold start resistance and other measures of performance were to be made in the actual vehicle. Comparative measurements of noise, vibration and harshness (NVH), were planned, although any work to mitigate the suspected higher NVH level in the rollerized engine was beyond the scope of this project. Timken selected the Toyota Avalon with a 3.5L V-6 engine as the test vehicle. In an attempt to minimize cost and fabrication time, a ‘made-from’ approach was proposed in which as many parts as possible would be used or modified from production parts to create the rollerized engine. Timken commissioned its test partner, FEV Engine Technology, to do a feasibility study in which they confirmed that using such an approach was possible to meet the required dimensional restrictions and tolerances. In designing the roller bearing systems for the crank and cam trains, Timken utilized as many production engine parts as possible. The crankshafts were produced from production line forgings, which use Timken steel, modified with special machining and heat treatment. Timken designed and manufactured all of the roller bearing related components such as the thrust bearing package. The production connecting rods and camshafts could not be used for the roller bearing engine, so new ones were produced according to the team’s designs using Timken steel. The remaining miscellaneous components were designed and procured by FEV. Timken prepared a display version of the crankshaft portion of the production engine without connecting rods which could be driven by a motor through a cogged-belt and electrically actuated clutch arrangement. A modified version was also made in which the engine was outfitted with roller bearings on the main bearing positions. Preliminary tests showed that the rollerized engine was running with 1/3 less friction than the standard display engine. Additional friction testing and noise characterization was cut short because of shipping damage to the rollerized engine display and because of other project priorities. The team did successfully demonstrate the ability to package roller bearings satisfactorily in numerous locations in a typical automotive engine. The scope of this project did not include durability demonstration and that subject would have to be addressed in any follow-on work. In the actual test phase, the rollerized engine did show significantly less friction in motored dynamometer tests compared to its production equivalent. The 5-10% improvement measured in this study was about half that seen in other studies. However, the fired test results did not show a reduction in friction which did not match prior experience or expectations. Subsequent teardown and inspection of the rollerized engine revealed potential sources of excessive friction in the experimental application. These features would be eliminated in a design not based on modification of production parts. The team is confident (based on experience) that friction reduction would be realized with proper modifications.

Kolarik, Robert V. II; Shattuck, Charles W.; Copper, Anthony P.

2009-06-30T23:59:59.000Z

284

Ultrathin, high-efficiency, broad-band, omni-acceptance, organic solar cells enhanced by  

E-Print Network [OSTI]

: Three of central challenges in solar cells are high light coupling into solar cell, high light trappingUltrathin, high-efficiency, broad-band, omni- acceptance, organic solar cells enhanced by plasmonic and demonstration of a new ultra-thin high- efficiency organic solar cell (SC), termed "plasmonic cavity

285

High-Efficiency and Stable White Organic Light-Emitting Diode...  

Broader source: Energy.gov (indexed) [DOE]

Efficiency and Stable White Organic Light-Emitting Diode Using a Single Emitter High-Efficiency and Stable White Organic Light-Emitting Diode Using a Single Emitter Presenter: Jian...

286

Webinar: Award-Winning LEEP Campaign Sites Demonstrate Big Savings in High Efficiency Parking Lighting  

Broader source: Energy.gov [DOE]

The Lighting Energy Efficiency in Parking (LEEP) Campaign is saving nearly 45 million kilowatt-hours and $4 million annually by upgrading its partners to high efficiency lighting in over 500,000 parking spaces.

287

High Efficiency Clean Combustion in Multi-Cylinder Light-Duty...  

Broader source: Energy.gov (indexed) [DOE]

Efficiency Clean Combustion in Multi-Cylinder Light-Duty Engines High Efficiency Clean Combustion in Multi-Cylinder Light-Duty Engines 2012 DOE Hydrogen and Fuel Cells Program and...

288

Catalyst containing oxygen transport membrane  

SciTech Connect (OSTI)

A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

2012-12-04T23:59:59.000Z

289

Metal/metal oxide doped oxide catalysts having high deNOx selectivity for lean NOx exhaust aftertreatment systems  

DOE Patents [OSTI]

A lean NOx catalyst and method of preparing the same is disclosed. The lean NOx catalyst includes a ceramic substrate, an oxide support material, preferably .gamma.-alumina, deposited on the substrate and a metal promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium, cerium, vanadium, oxides thereof, and combinations thereof. The .gamma.-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between about 80 to 350 m.sup.2 /g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to 0.2 weight percent. In a preferred embodiment the .gamma.-alumina is prepared by a sol-gel method, with the metal doping of the .gamma.-alumina preferably accomplished using an incipient wetness impregnation technique.

Park, Paul W.

2004-03-16T23:59:59.000Z

290

High efficiency off-axis current drive by high frequency fast waves  

SciTech Connect (OSTI)

Modeling work shows that current drive can be done off-axis with high efficiency, as required for FNSF and DEMO, by using very high harmonic fast waves (“helicons” or “whistlers”). The modeling indicates that plasmas with high electron beta are needed in order for the current drive to take place off-axis, making DIII-D a highly suitable test vehicle for this process. The calculations show that the driven current is not very sensitive to the launched value of n{sub ?}, a result that can be understood from examination of the evolution of n{sub ?} as the waves propagate in the plasma. Because of this insensitivity, relatively large values (?3) of n{sub ?} can be launched, thereby avoiding some of the problems with mode conversion in the boundary found in some previous experiments. Use of a traveling wave antenna provides a very narrow n{sub ?} spectrum, which also helps avoid mode conversion.

Prater, R.; Pinsker, R. I.; Moeller, C. P. [General Atomics, PO Box 85608, San Diego, California 92186-5608 (United States); Porkolab, M.; Vdovin, V. [Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, Massachusetts 02139 (United States)

2014-02-12T23:59:59.000Z

291

Design and global optimization of high-efficiency thermophotovoltaic systems  

E-Print Network [OSTI]

Despite their great promise, small experimental thermophotovoltaic (TPV) systems at 1000 K generally exhibit extremely low power conversion efficiencies (approximately 1%), due to heat losses such as thermal emission of ...

Bermel, Peter A.

292

High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles...  

Broader source: Energy.gov (indexed) [DOE]

that is compatible with s-CO2 cycles and modern thermal storage subsystems. Supercritical CO2 Brayton-cycle engines have the potential to increase conversion efficiency to...

293

Materials-Enabled High-Efficiency Diesel Engines (CRADA with...  

Broader source: Energy.gov (indexed) [DOE]

UT-Battelle for the U.S. Department of Energy Overview Timeline * Develop supporting materials technology to enable Heavy-Duty diesel efficiency of 55%, while meeting prevailing...

294

High Efficiency Full Expansion (FEx) Engine for Automotive Application...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Frontier in Engine Efficiency Two-Stroke Uniflow Turbo-Compound IC Engine The Opposed-Piston Two-Stroke Engine Alternative: Performance and Emissions Results in a Medium-Duty...

295

Vanadium catalysts break down biomass for fuels  

E-Print Network [OSTI]

- 1 - Vanadium catalysts break down biomass for fuels March 26, 2012 Vanadium catalysts break down biomass into useful components Due to diminishing petroleum reserves, non-food biomass (lignocellulose biomass into high-value commodity chemicals. The journal Angewandte Chemie International Edition published

296

DIRECT DECOMPOSITION OF METHANE TO HYDROGEN ON METAL LOADED ZEOLITE CATALYST  

SciTech Connect (OSTI)

The manufacture of hydrogen from natural gas is essential for the production of ultra clean transportation fuels. Not only is hydrogen necessary to upgrade low quality crude oils to high-quality, low sulfur ultra clean transportation fuels, hydrogen could eventually replace gasoline and diesel as the ultra clean transportation fuel of the future. Currently, refinery hydrogen is produced through the steam reforming of natural gas. Although efficient, the process is responsible for a significant portion of refinery CO2 emissions. This project is examining the direct catalytic decomposition of methane as an alternative to steam reforming. The energy required to produce one mole of hydrogen is slightly lower and the process does not require water-gas-shift or pressure-swing adsorption units. The decomposition process does not produce CO2 emissions and the product is not contaminated with CO -- a poison for PEM fuel cells. In this work we examined the direct catalytic decomposition of methane over a metal modified zeolite catalyst and the recovery of catalyst activity by calcination. A favorable production of hydrogen was obtained, when compared with previously reported nickel-zeolite supported catalysts. Reaction temperature had a strong influence on catalyst activity and on the type of carbon deposits. The catalyst utilized at 873 and 973 K could be regenerated without any significant loss of activity, however the catalyst utilized at 1073 K showed some loss of activity after regeneration.

Lucia M. Petkovic; Daniel M. Ginosar; Kyle C. Burch; Harry W. Rollins

2005-08-01T23:59:59.000Z

297

DESIGN AND DEVELOPMENT TESTING OF AN IMPROVED (1 HIGH-EFFICIENCY WATER HEATER  

E-Print Network [OSTI]

#12;DESIGN AND DEVELOPMENT TESTING OF AN IMPROVED (1 HIGH-EFFICIENCY WATER HEATER (2} (3) (21 icense in and to any copyright covering the drticle. This paper describes a high-efficiency water heater which uses a design approach quite different from the conventional center-flue water heater. While high

Oak Ridge National Laboratory

298

The Science and Engineering of Durable Ultralow PGM Catalysts- 2012 DOE-EERE-FCT annual progress report  

SciTech Connect (OSTI)

Minimizing the quantity of Pt group metals used in polymer membrane fuel cells (PEMFCs) is one of the remaining grand challenges for fuel cell commercialization. Tremendous progress has been achieved over the last two decades in decreasing the Pt loading required for efficient fuel cell performance. Unfortunately, the fluctuations in the price of Pt represent a substantial barrier to the economics of widespread fuel cell use. Durability and impurity tolerance are also challenges that are tightly coupled to fuel cell Pt electrode loading. Traditional approaches to decreasing the amount of Pt required for good performance include: (1) Increasing mass activity by decreasing Pt particle size by supporting on carbon; (2) Alloy formulation Pt-Co, Pt-Cr alloys to improve mass activity; (3) Increasing Pt utilization by optimization of electronic and ionic contact of the Pt particles; (4) Improving conductivity of the electronic and ionic conducting constituents of the membrane electrode assembly; and (5) Improving reactant to and product mass transport away from the electroactive sites. Recent novel approaches include the nanoengineering of core shell catalysts and Pt particles of unusual geometries such as nanowires/whiskers. The success of the aforementioned approaches has been great; however further advances using such approaches have been hampered by a lack of underlining scientific understanding of the catalyst activity, particle growth mechanisms, and optimization strategies for designing composite electrodes The objectives of this report are: (1) Development of durable, high mass activity Platinum Group Metal (PGM) cathode catalysts-enabling lower cost fuel cells; (2) Elucidation of the fundamental relationships between PGM catalyst shape, particle size and activity to help design better catalysts; (3) Optimization of the cathode electrode layer to maximize the performance of PGM catalysts-improving fuel cell performance and lowering cost; (4) Understanding the performance degradation mechanisms of high mass activity cathode catalysts-provide insights to better catalyst design; and (5) Development and testing of fuel cells using ultra-low loading high activity PGM catalysts-validation of advanced concepts.

Garzon, Fernando H. [Los Alamos National Laboratory

2012-07-16T23:59:59.000Z

299

High-efficiency He-3 proportional counter for the detection of delayed neutrons  

SciTech Connect (OSTI)

The present work examines a high-neutron efficiency detector used to measure delayed neutron techniques. The measurement of delayed neutrons requires a detector system that has high neutron efficiency and a low dead- time. The detection system must also have low gamma-ray sensitivity, and in addition must be insensitive to small sample displacement. The operating characteristics of the high-efficiency He-3 proportional counter used for the measurement of {beta}{sub i}-delayed neutrons is reported here.

Loaiza, D.J.

1998-03-01T23:59:59.000Z

300

Highly-Efficient Selective Metamaterial Absorber for High-Temperature Solar Thermal Energy Harvesting  

E-Print Network [OSTI]

In this work, a metamaterial selective solar absorber made of nanostructured titanium gratings deposited on an ultrathin MgF2 spacer and a tungsten ground film is proposed and experimentally demonstrated. Normal absorptance of the fabricated solar absorber is characterized to be higher than 90% in the UV, visible and, near infrared (IR) regime, while the mid-IR emittance is around 20%. The high broadband absorption in the solar spectrum is realized by the excitation of surface plasmon and magnetic polariton resonances, while the low mid-IR emittance is due to the highly reflective nature of the metallic components. Further directional and polarized reflectance measurements show wide-angle and polarization-insensitive high absorption within solar spectrum. Temperature-dependent spectroscopic characterization indicates that the optical properties barely change at elevated temperatures up to 350{\\deg}C. The solar-to-heat conversion efficiency with the fabricated metamaterial solar absorber is predicted to be 78%...

Wang, Hao; Mitchell, Arnan; Rosengarten, Gary; Phelan, Patrick; Wang, Liping

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Broadband Quantum Efficiency Enhancement in High Index Nanowires Resonators  

E-Print Network [OSTI]

Light trapping in sub-wavelength semiconductor nanowires (NWs) offers a promising approach to simultaneously reducing material consumption and enhancing photovoltaic performance. Nevertheless, the absorption efficiency of a NW, defined by the ratio of optical absorption cross section to the NW diameter, lingers around 1 in existing NW photonic devices, and the absorption enhancement suffers from a narrow spectral width. Here, we show that the absorption efficiency can be significantly improved in NWs with higher refractive indices, by an experimental observation of up to 350% external quantum efficiency (EQE) in lead sulfide (PbS) NW resonators, a 3-fold increase compared to Si NWs. Furthermore, broadband absorption enhancement is achieved in single tapered NWs, where light of various wavelengths is absorbed at segments with different diameters analogous to a tandem solar cell. Overall, the single NW Schottky junction solar cells benefit from optical resonance, near bandgap open circuit voltage, and long mino...

Yang, Yiming; Hyatt, Steven; Yu, Dong

2015-01-01T23:59:59.000Z

302

Development of high efficiency ball-bearing turbocharger  

SciTech Connect (OSTI)

Turbochargers have become very popular on passenger cars since the first mass-produced turbocharged passenger cars were put on market in Japan in 1979. Turbo lag is one of the most serious problem since the first mass-production started. Several new technologies such as a variable geometry turbocharger, ceramic turbocharger, etc. have been introduced to improve acceleration performance. A variable geometry turbocharger changes the area of gas flow passage and increases exhaust gas speed at low engine speed. A ceramic turbocharger reduces inertia moment of a turbine wheel and shaft. Turbocharger mechanical efficiency has equal importance as compressor efficiency and turbine efficiency. This paper describes the test results of ball bearing turbochargers.

Miyashita, K.; Kurasawa, M.; Matsuoka, H.; Ikeya, N.

1987-01-01T23:59:59.000Z

303

Design and global optimization of high-efficiency solar thermal systems with tungsten cermets  

E-Print Network [OSTI]

Solar thermal, thermoelectric, and thermophotovoltaic (TPV) systems have high maximum theoretical efficiencies; experimental systems fall short because of losses by selective solar absorbers and TPV selective emitters. To ...

Chester, David A.

304

NASA's Marshall Space Flight Center Saves Water With High-Efficiency...  

Broader source: Energy.gov (indexed) [DOE]

NASA's Marshall Space Flight Center Saves Water With High-Efficiency Toilet and Urinal Program: Best Management Practice Case Study 6 - Toilets and Urinals (Fact Sheet), Federal...

305

Vehicle Technologies Office Merit Review 2014: High Efficiency GDI Engine Research, with Emphasis on Ignition Systems  

Broader source: Energy.gov [DOE]

Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high efficiency...

306

A High-Efficiency Grid-Tie Battery Energy Storage System.  

E-Print Network [OSTI]

??Lithium-ion based battery energy storage system has become one of the most popular forms of energy storage system for its high charge and discharge efficiency… (more)

Qian, Hao

2011-01-01T23:59:59.000Z

307

High efficient electrical stimulation of hippocampal slices with vertically aligned carbon nanofiber microbrush array  

E-Print Network [OSTI]

9295-7 High efficient electrical stimulation of hippocampalE. D. de Asis Jr. Departments of Electrical Engineering andaligned carbon nanofiber . Electrical stimulation . Neural

2009-01-01T23:59:59.000Z

308

Scientists Confirm Robustness of Key Component in Ultra-High-Efficiency Solar Cell (Fact Sheet)  

SciTech Connect (OSTI)

Scientists developed and tested a new, stable 1-eV metamorphic junction for a high efficiency multijunction III-V solar cell for CPV application.

Not Available

2011-05-01T23:59:59.000Z

309

High efficiency resonant dc/dc converter for solar power applications .  

E-Print Network [OSTI]

??This thesis presents a new topology for a high efficiency dc/dc resonant power converter that utilizes a resistance compression network to provide simultaneous zero voltage… (more)

Inam, Wardah

2013-01-01T23:59:59.000Z

310

High-Efficiency Solar Cells for Large-Scale Electricity Generation  

SciTech Connect (OSTI)

One strategy for helping the solar industry to grow faster is to use very high efficiency cells under concentrating optics. By using lenses or mirrors to concentrate the light, very small solar cells can be used, reducing the amount of semiconductor material and allowing use of higher efficiency cells, which are now >40% efficient.

Kurtz, S.; Olson, J.; Geisz, J.; Friedman, D.; McMahon, W.; Ptak, A.; Wanlass, M.; Kibbler, A.; Kramer, C.; Bertness, K.; Ward, S.; Duda, A.; Young, M.; Carapella, J.; Steiner, M.

2008-09-26T23:59:59.000Z

311

Tungsten Cathode Catalyst for PEMFC  

SciTech Connect (OSTI)

Final report for project to evaluate tungsten-based catalyst as a cathode catalyst for PEM cell applications.

Joel B. Christian; Sean P. E. Smith

2006-09-22T23:59:59.000Z

312

Exploring MapReduce Efficiency with Highly-Distributed Data  

E-Print Network [OSTI]

is also distributed, e.g. data is collected in separate data center loca- tions, the most efficient-performance computing over large data sets in large-scale platforms. Fueling this growth is the emergence of cloud several distributed data sources, i.e., large-scale data could be collected in separate data center

Chandra, Abhishek

313

Design and global optimization of high-efficiency thermophotovoltaic  

E-Print Network [OSTI]

). © 2010 Optical Society of America OCIS codes: (230.5298) Photonic crystals; (350.6050) Solar energy, PhC-based designs present a set of non-convex optimization problems requiring efficient objective micro-TPV generators and solar thermal TPV systems. Micro-TPV reactors experience up to a 27-fold

314

High efficiency thin-film multiple-gap photovoltaic device  

DOE Patents [OSTI]

A photovoltaic device includes at least two solar cells made from Group IV elements or their alloys in the amorphous state mounted on a substrate. The outermost or first cell has a larger bandgap than the second cell. Various techniques are utilized to improve the efficiency of the device.

Dalal, Vikram L. (Newark, DE)

1983-01-01T23:59:59.000Z

315

Small core axial compressors for high efficiency jet aircraft  

E-Print Network [OSTI]

This thesis quantifies mechanisms that limit efficiency in small core axial compressors, defined here as compressor exit corrected flow between 1.5 and 3.0 lbm/s. The first part of the thesis describes why a small engine ...

DiOrio, Austin Graf

2012-01-01T23:59:59.000Z

316

Highly efficient 6-stroke engine cycle with water injection  

DOE Patents [OSTI]

A six-stroke engine cycle having improved efficiency. Heat is recovered from the engine combustion gases by using a 6-stroke engine cycle in which combustion gases are partially vented proximate the bottom-dead-center position of the fourth stroke cycle, and water is injected proximate the top-dead-center position of the fourth stroke cycle.

Szybist, James P; Conklin, James C

2012-10-23T23:59:59.000Z

317

Efficient Techniques for High-Speed Elliptic Curve Cryptography  

E-Print Network [OSTI]

Gebotys Department of Electrical and Computer Engineering, University of Waterloo, Canada, {plonga] is an integer, is the central and most time-consuming operation in Elliptic Curve Cryptography (ECC). Hence, its gained increasing importance in recent years. In this work, we combine several efficient techniques

318

Design of high efficiency blowers for future aerosol applications  

E-Print Network [OSTI]

Blower performance measurement test-rig. ....................................................47 xii Page Figure 20 Pressure recovery for different venturi types (FLOW-DYNE Engineering... consumption curves for final-prototype. ........87 Figure 45 Experimental efficiency( )EXP values for final-prototype 70xz_28y. ............88 Figure A-1 Venturi calibration chart...

Chadha, Raman

2007-04-25T23:59:59.000Z

319

Activity and structure of perovskites as diesel reforming catalysts for solid oxide fuel cells.  

SciTech Connect (OSTI)

Recent progress in developing perovskite materials as more cost-effective catalysts in autothermal reforming (ATR) of diesel fuel to hydrogen-rich reformate for solid oxide fuel cell (SOFC) application is reported. Perovskite-type metal oxides with B sites partially exchanged by ruthenium were prepared and evaluated under ATR reaction conditions. The hydrogen yield, reforming efficiency, and CO{sub x} selectivity of these catalysts were investigated using diesel surrogate fuel with 50 ppm sulfur. The catalyst performances have approached or exceeded a benchmark, high-cost rhodium-based material. In parallel with the reactivity study, we also investigated the physical properties of B-site doped perovskites and their impact on the reforming performance using various characterization techniques such as BET, X-ray powder diffraction, temperature programmable reduction, scanning electron microscopy, and synchrotron X-ray absorption spectroscopy. We found that ruthenium is highly dispersed into perovskite lattice and its redox behavior is directly associated with reforming activity.

Liu, D.-J.; Krumpelt, M.; Chemical Engineering

2005-01-01T23:59:59.000Z

320

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

The successful adaptation of conventional cobalt and iron-based Fischer-Tropsch synthesis catalysts for use in converting biomass-derived syngas hinges in part on understanding their susceptibility to byproducts produced during the biomass gasification process. With the possibility that oil production will peak in the near future, and due to concerns in maintaining energy security, the conversion of biomass-derived syngas and syngas derived from coal/biomass blends to Fischer-Tropsch synthesis products to liquid fuels may provide a sustainable path forward, especially considering if carbon sequestration can be successfully demonstrated. However, one current drawback is that it is unknown whether conventional catalysts based on iron and cobalt will be suitable without proper development because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using an entrained-flow oxygen-blown gasifier) than solely from coal, other byproducts may be present in higher concentrations. The current project examines the impact of a number of potential byproducts of concern from the gasification of biomass process, including compounds containing alkali chemicals like the chlorides of sodium and potassium. In the second year, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities.

Burtron Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Dennis Sparks; Wilson Shafer

2010-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

High-efficiency large-area CdTe panels  

SciTech Connect (OSTI)

The objective of this three year effort has been to develop an improved materials technology and fabrication process for limited volume production of 1 ft{sup 2} and 4 ft{sup 2} CdS/CdTe photovoltaic modules. The module stability objective by the end of this three year subcontract was to develop techniques to provide ten year life exploration with no greater than 10% degradation. In order to achieve these efficiency and stability objectives, the research program has been separated into tasks including: (1) analysis and characterization of CdS/CdTe Devices; (2) performance optimization on small cells; (3) encapsulation and stability testing; and (4) module efficiency optimization. 27 refs., 18 figs., 3 tabs.

Albright, S.P.; Chamberlin, R.R.; Jordan, J.F. (Photon Energy, Inc., El Paso, TX (USA))

1990-11-01T23:59:59.000Z

322

High efficiency waste to energy facility -- Pilot plant design  

SciTech Connect (OSTI)

Waste To Energy facilities are commonly acceptable to the environment and give benefits in two main areas: one is a hygienic waste disposal and another is waste heat energy recovery to save fossil fuel consumption. Recovered energy is used for electricity supply, and it is required to increase the efficiency of refuse to electric energy conversion, and to spread the plant construction throughout the country of Japan, by the government. The national project started in 1992, and pilot plant design details were established in 1995. The objective of the project is to get 30% of energy conversion efficiency through the measure by raising the steam temperature and pressure to 500 C and 9.8 MPa respectively. The pilot plant is operating under the design conditions, which verify the success of applied technologies. This paper describes key technologies which were used to design the refuse burning boiler, which generates the highest steam temperature and pressure steam.

Orita, Norihiko; Kawahara, Yuuzou; Takahashi, Kazuyoshi; Yamauchi, Toru; Hosoda, Takuo

1998-07-01T23:59:59.000Z

323

Development of Enabling Technologies for High Efficiency, Low Emissions  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office of Audit Services AuditTransatlantic RelationsDepartment ofEfficiency |Homogeneous

324

Quantum Dot Solar Cells: High Efficiency through Multiple Exciton Generation  

SciTech Connect (OSTI)

Impact ionization is a process in which absorbed photons in semiconductors that are at least twice the bandgap can produce multiple electron-hole pairs. For single-bandgap photovoltaic devices, this effect produces greatly enhanced theoretical thermodynamic conversion efficiencies that range from 45-85%, depending upon solar concentration, the cell temperature, and the number of electron-hole pairs produced per photon. For quantum dots (QDs), electron-hole pairs exist as excitons. We have observed astoundingly efficient multiple exciton generation (MEG) in QDs of PbSe (bulk Eg = 0.28 eV), ranging in diameter from 3.9 to 5.7nm (Eg = 0.73, 0.82, and 0.91 eV, respectively). The effective masses of electron and holes are about equal in PbSe, and the onset for efficient MEG occurs at about three times the QD HOMO-LUMO transition (its ''bandgap''). The quantum yield rises quickly after the onset and reaches 300% at 4 x Eg (3.64 eV) for the smallest QD; this means that every QD in the sample produces three electron-hole pairs/photon.

Hanna, M. C.; Ellingson, R. J.; Beard, M.; Yu, P.; Micic, O. I.; Nozik, A. J.; c.

2005-01-01T23:59:59.000Z

325

Development of Enabling Technologies for High Efficiency, Low...  

Broader source: Energy.gov (indexed) [DOE]

high BMEP * Robust combustion control - Transient control of HCCI - Combustion feedback sensors - Combustion mode switching Gap Analysis * Evaluate Production readiness *...

326

Energy-Efficient Pipeline Templates for High-Performance Asynchronous Circuits  

E-Print Network [OSTI]

A Energy-Efficient Pipeline Templates for High-Performance Asynchronous Circuits Basit Riaz Sheikh and Rajit Manohar, Cornell University We present two novel energy-efficient pipeline templates for high is presented, which results in significant latency and energy savings especially as the number of outputs

Manohar, Rajit

327

Silicon Photodiodes for High-Efficiency Low-Energy Electron Detection  

E-Print Network [OSTI]

Silicon Photodiodes for High-Efficiency Low-Energy Electron Detection Agata Saki, Lis K. Nanver, T--Solid-state electron detectors have been fabricated using a p+ n silicon photodiode where the p+ region is created near theoretical efficiency at high electron energies. The photodiodes have outstanding performance

Technische Universiteit Delft

328

High throughput energy efficient multi-FFT architecture on FPGAs (Draft)  

E-Print Network [OSTI]

computing, High throughput FFT, Energy efficient design I. INTRODUCTION As FPGAs are programmed specifically in spread spec- trum receiver [4]. In the design of high throughput FFT architectures, energy-efficient design techniques can be used to maximize performance under power dissipation constraints. The power

Prasanna, Viktor K.

329

NANOSTRUCTURED SOLAR CELLS FOR HIGH EFFICIENCY PHOTOVOLTAICS Christiana B. Honsberg1  

E-Print Network [OSTI]

for solar energy conversion. NANOSTRUCTURED SOLAR CELLS Nanostructured solar cells offer several advantages to contribute to high efficiency devices NEW CONCEPTS FOR SOLAR CELLS An important advantage for nanostructuredNANOSTRUCTURED SOLAR CELLS FOR HIGH EFFICIENCY PHOTOVOLTAICS Christiana B. Honsberg1 , Allen M

Honsberg, Christiana

330

Energy Efficient Phase Change Memory Based Main Memory for Future High Performance Systems  

E-Print Network [OSTI]

hybrid system using a commodity DRAM cache. Keywords-Memory Controller, DRAM, PCM, Energy I. INTRODUCTIONEnergy Efficient Phase Change Memory Based Main Memory for Future High Performance Systems Abstract system of similar storage size. Our proposed system is highly energy efficient and provides 35

Conte, Thomas M.

331

Current-matched high-efficiency, multijunction monolithic solar cells  

DOE Patents [OSTI]

The efficiency of a two-junction (cascade) tandem photovoltaic device is improved by adjusting (decreasing) the top cell thickness to achieve current matching. An example of the invention was fabricated out of Ga.sub.0.52 In.sub.0.48 P and GaAs. Additional lattice-matched systems to which the invention pertains include Al.sub.x Ga.sub.1-x /GaAS (x= 0.3-0.4), GaAs/Ge and Ga.sub.y In.sub.l-y P/Ga.sub.y+0.5 In.sub.0.5-y As (0

Olson, Jerry M. (Lakewood, CO); Kurtz, Sarah R. (Golden, CO)

1993-01-01T23:59:59.000Z

332

Achieving High Efficiency at 2010 Emissions | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment of Energy 601DepartmentContract andthe LosUsing CFDHigh Efficiency

333

Enabling the Next Generation of High Efficiency Engines  

Broader source: Energy.gov (indexed) [DOE]

optimization methods, and reduced models for on-board controls 15 Leadership High Performance Computing* (HPC) has potential to accelerate design and development at an...

334

Process for magnetic beneficiating petroleum cracking catalyst  

DOE Patents [OSTI]

A process for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded.

Doctor, Richard D. (Lisle, IL)

1993-01-01T23:59:59.000Z

335

Process for magnetic beneficiating petroleum cracking catalyst  

DOE Patents [OSTI]

A process is described for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded. 1 figures.

Doctor, R.D.

1993-10-05T23:59:59.000Z

336

Bio-inspired MOF-based Catalysts for Lignin Valorization.  

SciTech Connect (OSTI)

Lignin is a potentially plentiful source of renewable organics, with ~50Mtons/yr produced by the pulp/paper industry and 200-300 Mtons/yr projected production by a US biofuels industry. This industry must process approximately 1 billion tons of biomass to meet the US Renewable Fuel goals. However, there are currently no efficient processes for converting lignin to value-added chemicals and drop-in fuels. Lignin is therefore an opportunity for production of valuable renewable chemicals, but presents staggering technical and economic challenges due to the quantities of material involved and the strong chemical bonds comprising this polymer. Aggressive chemistries and high temperatures are required to degrade lignin without catalysts. Moreover, chemical non-uniformity among lignins leads to complex product mixtures that tend to repolymerize. Conventional petrochemical approaches (pyrolysis, catalytic cracking, gasification) are energy intensive (400-800 degC), require complicated separations, and remove valuable chemical functionality. Low-temperature (25-200 degC) alternatives are clearly desirable, but enzymes are thermally fragile and incompatible with liquid organic compounds, making them impractical for large-scale biorefining. Alternatively, homogeneous catalysts, such as recently developed vanadium complexes, must be separated from product mixtures, while many heterogenous catalysts involve costly noble metals. The objective of this project is to demonstrate proof of concept that an entirely new class of biomimetic, efficient, and industrially robust synthetic catalysts based on nanoporous Metal- Organic Frameworks (MOFs) can be developed. Although catalytic MOFs are known, catalysis of bond cleavage reactions needed for lignin degradation is completely unexplored. Thus, fundamental research is required that industry and most sponsoring agencies are currently unwilling to undertake. We introduce MOFs infiltrated with titanium and nickel species as catalysts for the C-O bond hydrogenolysis in model compounds, which mimic the b-O-4, a-O-4, and 4-O-5 linkages of natural lignin. The versatile IRMOF-74(n) series is proposed as a platform for creating efficient hydrogenolysis catalysts as it not only displays tunable pore sizes, but also has the required thermal and chemical stability. The catalytic C-O bond cleavage occurs at 10 bar hydrogen pressure and temperatures as low as 120 degC. The conversion efficiency of the aromatic ether substrates into the corresponding hydrocarbons and phenols varies as PhCH 2 CH 2 OPh > PhCH 2 OPh > PhOPh (Ph = phenyl), while the catalytic activity generally follows the following trend Ni%40IRMOF-74>Ti%40IRMOF-74>IRMOF-74. Conversions as high as 80%, coupled with good selectivity for hydrogenolysis vs. hydrogenation, highlight the potential of MOF-based catalysts for the selective cleavage of recalcitrant aryl-ether bonds found in lignin and other biopolymers. This project supports the DOE Integrated Biorefinery Program goals, the objective of which is to convert biomass to fuels and high-value chemicals, by addressing an important technology gap: the lack of low-temperature catalysts suitable for industrial lignin degradation. Biomass, which is ~30 wt% lignin, constitutes a potentially major source of platform chemicals that could improve overall profitability and productivity of all energy-related products, thereby benefiting consumers and reducing national dependence on imported oil. Additionally, DoD has a strong interest in low-cost drop-in fuels (Navy Biofuel Initiative) and has signed a Memorandum of Understanding with DOE and USDA to develop a sustainable biofuels industry.

Allendorf, Mark D.; Stavila, Vitalie; Ramakrishnan, Parthasarathi; Davis, Ryan Wesley

2014-09-01T23:59:59.000Z

337

High-Tech Means High-Efficiency: The Business Case for EnergyManagement in High-Tech Industries  

SciTech Connect (OSTI)

In the race to apply new technologies in ''high-tech'' facilities such as data centers, laboratories, and clean rooms, much emphasis has been placed on improving service, building capacity, and increasing speed. These facilities are socially and economically important, as part of the critical infrastructure for pharmaceuticals,electronics, communications, and many other sectors. With a singular focus on throughput, some important design issues can be overlooked, such as the energy efficiency of individual equipment (e.g., lasers, routers and switches) as well as the integration of high-tech equipment into the power distribution system and the building envelope. Among technology-based businesses, improving energy efficiency presents an often untapped opportunity to increase profits, enhance process control,maximize asset value, improve the work place environment, and manage a variety of business risks. Oddly enough, the adoption of energy efficiency improvements in this sector lags behind many others. As a result, millions of dollars are left on the table with each year ofoperation.

Shanshoian, Gary; Blazek, Michele; Naughton, Phil; Seese, RobertS.; Mills, Evan; Tschudi, William

2005-11-15T23:59:59.000Z

338

Efficient CO2 Fixation Pathways: Energy Plant: High Efficiency Photosynthetic Organisms  

SciTech Connect (OSTI)

PETRO Project: UCLA is redesigning the carbon fixation pathways of plants to make them more efficient at capturing the energy in sunlight. Carbon fixation is the key process that plants use to convert carbon dioxide (CO2) from the atmosphere into higher energy molecules (such as sugars) using energy from the sun. UCLA is addressing the inefficiency of the process through an alternative biochemical pathway that uses 50% less energy than the pathway used by all land plants. In addition, instead of producing sugars, UCLA’s designer pathway will produce pyruvate, the precursor of choice for a wide variety of liquid fuels. Theoretically, the new biochemical pathway will allow a plant to capture 200% as much CO2 using the same amount of light. The pathways will first be tested on model photosynthetic organisms and later incorporated into other plants, thus dramatically improving the productivity of both food and fuel crops.

None

2012-01-01T23:59:59.000Z

339

Low Cost Autothermal Diesel Reforming Catalyst Development  

SciTech Connect (OSTI)

Catalytic autothermal reforming (ATR) represents an important step of converting fossil fuel to hydrogen rich reformate for use in solid oxide fuel cell (SOFC) stacks. The state-of-the-art reforming catalyst, at present, is a Rh based material which is effective but costly. The objective of our current research is to reduce the catalyst cost by finding an efficient ATR catalyst containing no rhodium. A group of perovskite based catalysts have been synthesized and evaluated under the reforming condition of a diesel surrogate fuel. Hydrogen yield, reforming efficiency, and conversion selectivity to carbon oxides of the catalyst ATR reaction are calculated and compared with the benchmark Rh based material. Several catalyst synthesis improvements were carried out including: 1) selectively doping metals on the A-site and B-site of the perovskite structure, 2) changing the support from perovskite to alumina, 3) altering the method of metal addition, and 4) using transition metals instead of noble metals. It was found that the catalytic activity changed little with modification of the A-site metal, while it displayed considerable dependence on the B-site metal. Perovskite supports performed much better than alumina based supports.

Shihadeh, J.; Liu, D.

2004-01-01T23:59:59.000Z

340

Highly efficient greenish-blue platinum-based phosphorescent organic light-emitting diodes on a high triplet energy platform  

SciTech Connect (OSTI)

We have demonstrated high-efficiency greenish-blue phosphorescent organic light-emitting diodes (PHOLEDs) based on a dimesitylboryl-functionalized C^N chelate Pt(II) phosphor, Pt(m-Bptrz)(t-Bu-pytrz-Me). Using a high triplet energy platform and optimized double emissive zone device architecture results in greenish-blue PHOLEDs that exhibit an external quantum efficiency of 24.0% and a power efficiency of 55.8?lm/W. This record high performance is comparable with that of the state-of-the-art Ir-based sky-blue organic light-emitting diodes.

Chang, Y. L., E-mail: yilu.chang@mail.utoronto.ca; Gong, S., E-mail: sgong@chem.utoronto.ca; White, R.; Lu, Z. H., E-mail: zhenghong.lu@utoronto.ca [Department of Materials Science and Engineering, University of Toronto, 184 College St., Toronto, Ontario M5S 3E4 (Canada); Wang, X.; Wang, S., E-mail: wangs@chem.queensu.ca [Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario K7L 3N6 (Canada); Yang, C. [Department of Chemistry, Wuhan University, Wuhan 430072 (China)

2014-04-28T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A high-efficiency indirect lighting system utilizing the solar 1000 sulfur lamp  

SciTech Connect (OSTI)

High-lumen light sources represent unique challenges and opportunities for the design of practical and efficient interior lighting systems. High-output sources require a means of large-scale distribution and avoidance of high-luminance glare while providing efficient delivery. An indirect lighting system has been developed for use with a 1,000 Watt sulfur lamp that efficiently utilizes the high-output source to provide quality interior lighting. This paper briefly describes the design and initial testing of this new system.

Siminovitch, M.; Gould, C.; Page, E.

1997-06-01T23:59:59.000Z

342

High Temperature Electrolysis for Efficient Hydrogen Production from Nuclear Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE andHigh Risk PlanD D eHigh

343

Twin-screw tanker designed for high efficiency  

SciTech Connect (OSTI)

In late 1994, the Ching Fu shipyard in Taiwan delivered a chemical tanker to Fram Shipping, for operations around Northern Europe for Norsk Hydro. The 13000 dwt tanker design is optimized to have the lowest possible operational cost for the given dead-weight capacity. Waertsilae Propulsion has from an early stage contributed to the development of the propulsion system. The company proposed the Waertsilae Propac concept, including the hydrodynamic design and the supply of the main components. The propeller was designed using in-house computer programs, and the results confirmed by model tests, both at Danish Maritime Institute (DMI) in Copenhagen, and at SSPA Maritime Consulting in Gothenburg. The hull form for the tanker was optimized by a special bulb design to reduce the wave resistance. The vessel is also designed with a special twin skeg arrangement in the stern. This solution allows for two large and efficient propellers to be installed.

NONE

1995-11-01T23:59:59.000Z

344

High-efficiency neutron detectors and methods of making same  

DOE Patents [OSTI]

Neutron detectors, advanced detector process techniques and advanced compound film designs have greatly increased neutron-detection efficiency. One embodiment of the detectors utilizes a semiconductor wafer with a matrix of spaced cavities filled with one or more types of neutron reactive material such as 10B or 6LiF. The cavities are etched into both the front and back surfaces of the device such that the cavities from one side surround the cavities from the other side. The cavities may be etched via holes or etched slots or trenches. In another embodiment, the cavities are different-sized and the smaller cavities extend into the wafer from the lower surfaces of the larger cavities. In a third embodiment, multiple layers of different neutron-responsive material are formed on one or more sides of the wafer. The new devices operate at room temperature, are compact, rugged, and reliable in design.

McGregor, Douglas S.; Klann, Raymond

2007-01-16T23:59:59.000Z

345

High-efficiency spectral purity filter for EUV lithography  

DOE Patents [OSTI]

An asymmetric-cut multilayer diffracts EUV light. A multilayer cut at an angle has the same properties as a blazed grating, and has been demonstrated to have near-perfect performance. Instead of having to nano-fabricate a grating structure with imperfections no greater than several tens of nanometers, a thick multilayer is grown on a substrate and then cut at an inclined angle using coarse and inexpensive methods. Effective grating periods can be produced this way that are 10 to 100 times smaller than those produced today, and the diffraction efficiency of these asymmetric multilayers is higher than conventional gratings. Besides their ease of manufacture, the use of an asymmetric multilayer as a spectral purity filter does not require that the design of an EUV optical system be modified in any way, unlike the proposed use of blazed gratings for such systems.

Chapman, Henry N. (Livermore, CA)

2006-05-23T23:59:59.000Z

346

Second Generation Advanced Reburning for High Efficiency NOx Control  

SciTech Connect (OSTI)

This project is designed to develop a family of novel NO{sub x} control technologies, called Second Generation Advanced Reburning (SGAR) which has the potential to achieve 90+% NO{sub x} control in coal-fired boilers at a significantly lower cost than SCR. The twelfth reporting period in Phase II (July 3-October 15, 2000) included design validation AR-Lean tests (Task No.2.6) in the 10 x 10{sup 6} Btu/hr Tower Furnace. The objective of tests was to determine the efficiency of AR-Lean at higher than optimum OFA/N-Agent injection temperatures in large pilot-scale combustion facility. Tests demonstrated that co-injection of urea with overfire air resulted in NO{sub x} reduction. However, observed NO{sub x} reduction was smaller than that under optimum conditions.

Roy Payne; Lary Swanson; Antonio Marquez; Ary Chang; Vladimir M. Zamansky; Pete M. Maly; Vitali V. Lissianski

2000-09-30T23:59:59.000Z

347

Development of a high-efficiency solar micro-inverter  

E-Print Network [OSTI]

In typical solar power installations, multiple modules are connected to the grid through a single high-power inverter. However, an alternative approach is to connect each solar module directly to the grid through a ...

Hayman, Alexander Khaled

2009-01-01T23:59:59.000Z

348

Towards a high-efficiency micro-thermophotovoltaic generator  

E-Print Network [OSTI]

Hydrocarbon fuels have such a high energy density that even a relatively inefficient converter of chemical energy into electrical can significantly exceed the energy density of state- of-the-art batteries. This work attempts ...

Walker, Chan (Walker R.)

2010-01-01T23:59:59.000Z

349

High Efficient Clean Combustion for SuperTruck  

Broader source: Energy.gov (indexed) [DOE]

bar FIE + Direct Air to EGR + Controls Direct Air to EGR + Combustion System + 2 Stage Turbo + >2600 bar FIE 2 Stage Turbo + Low P EGR + Calibration Low P, High Flow Rate...

350

High Thermal Efficiency and Low Emissions with Supercritical Gasoline  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE andHighWells

351

High efficiency resonance ionization mass spectrometric analysis by external laser cavity enhancement techniques  

SciTech Connect (OSTI)

The demand to measure high dynamic range isotope ratios on small samples with resonance ionization mass spectrometry (RIMS) continues to increase. This paper discusses high ionization efficiency methods which can be applied to continuous wave (cw) RIMS to potentially achieve several tens of percent ionization efficiencies for certain elements. The primary technique under development to achieve this is an external laser cavity which can generate very high circulating laser powers. 12 refs., 3 figs.

Johnson, S.G.; Rios, E.L.; Miller, C.M.; Fearey, B.L.

1991-01-01T23:59:59.000Z

352

DEVELOPMENT OF A HIGH EFFICIENCY MECHANICALLY STACKED MULTI-JUNCTION SOLAR CELL  

E-Print Network [OSTI]

Monolithic, 2-terminal, epitaxially grown multi-junctions represent the state-of-the-art in high efficiency photovoltaic space power. Their in-situ monolithic integration results in an elegant device structure with high efficiency, relatively high specific power, and a simple fabrication process. The monolithic, epitaxially grown nature of these devices also imposes materials and design restrictions which impede the march to significantly higher

Daniel Aiken; Paul Sharps; Mark Stan; Harry Atwater; Anna Fontcuberta I Morral; James Zahler; Mark Wanlass

353

High-Power Batteries | Center for Energy Efficient Materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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354

Research on stable, high-efficiency, amorphous silicon multijunction modules  

SciTech Connect (OSTI)

The present effort seeks to develop modules with a stabilized performance of 8.8% aperture area conversion after 600 hours light exposure (AM1.5) at 50{degrees}C in modules with aperture areas over 900 cm{sup 2}. Good progress towards this goal has been obtained with the demonstration of 9.8% initial performance in a submodule incorporating devices with relatively thin middle junction i-layer thickness of 4000{Angstrom}. Devices with this design have been shown to lose about 10% of their initial performance after 1000 hours of exposure. Modules lose between 18--23% largely due to light induced shunting, probably related to the contact metallization. Achieving long-term stabilized efficiencies of 12% or more requires substantial improvements in materials and devices. Our analysis has shown that substantial optical losses occur at both front and rear contacts which we hope to address with ZnO films prepared by CVD and sputtering processes now under development. Further progress is doped layers and alloys are also needed. Fundamental studies of the relationship between material structure and processes (particularly the effect of hydrogen dilution) are reported here. 32 refs., 28 figs., 9 tabs.

Catalano, A.; Bennet, M.; Chen, L.; Fieselmann, B.; Li, Y.; Newton, J.; Podlesny, R.; Wiedeman, S.; Yang, L. (Solarex Corp., Newtown, PA (United States). Thin Film Div.)

1991-08-01T23:59:59.000Z

355

High-Efficiency Clean Combustion Design for Compression Ignition Engines |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCEDOEDepartment of Energy

356

High-Efficiency Commercial Cold Climate Heat Pump  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCEDOEDepartment ofEngines

357

High-Efficiency Engine Technologies Session Introduction | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCEDOEDepartment

358

Industrial DSM: Beyond High Efficiency Lights and Motors  

E-Print Network [OSTI]

on behalf of electric utilities. These represent real-world solutions to problems in actual industrial plants in many different types of industries. DSM IN LOW TEMPERATURE REFRIGERAnON SYST M APPLICAnONS Industrial refrigeration equipment is highly... energy-intensive. In many dairy procl::."ing plants in particular, refrigeration systems are the largest electricity consumers, repre enting as much as 75 percent of plant peak demand. The availability of the refrigeration system is critical...

Appelbaum, B.

359

Power efficiency for very high temperature solar thermal cavity receivers  

DOE Patents [OSTI]

This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this arrangement, a high percentage of the solar power input is retained in the cavity; thus, high internal temperatures are attained.

McDougal, Allan R. (LaCanada-Flintridge, CA); Hale, Robert R. (Upland, CA)

1984-01-01T23:59:59.000Z

360

INITIAL TEST BED FOR VERY HIGH EFFICIENCY SOLAR CELLS Allen Barnett  

E-Print Network [OSTI]

multiple benefits, including increased theoretical efficiency, new architectures that circumvent material/cost choices. An integrated optical/solar cell allows efficiency improvements while retaining low area costs, multiple-junction III-Vs for the high and low energy photons while circumventing existing cost drivers

Honsberg, Christiana

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Highly efficient carbon dioxide capture with a porous organic polymer impregnated with  

E-Print Network [OSTI]

Highly efficient carbon dioxide capture with a porous organic polymer impregnated environmental crises such as global warming and ocean acidication, efficient carbon dioxide (CO2) capture As CO2 capture mate- rials, numerous solid adsorbents such as silica5 and carbon materials,6 metal

Paik Suh, Myunghyun

362

Design of Heterostructures for High Efficiency Thermionic Emission Zhixi Bian and Ali Shakouri  

E-Print Network [OSTI]

-state thermionic energy converters are expected to offer a larger thermoelectric power factor ( 2 S ) than uniformDesign of Heterostructures for High Efficiency Thermionic Emission Zhixi Bian and Ali Shakouri heterostructure designs to improve the energy conversion efficiency of solid- state thermionic devices. The first

363

Evaluation of SiC MOSFETs for a High Efficiency Three-Phase Buck Rectifier  

E-Print Network [OSTI]

-voltage DC (HVDC) distribution architecture in telecom and data centers was shown to have superior efficiency and reliability compared with the traditional AC architecture [1-2]. HVDC bus is usually set as 380 Vdc or 400 Vdc a high efficiency buck rectifier used in the first stage of HVDC architecture data center power supplies

Tolbert, Leon M.

364

innovati nNREL Produces Highly Efficient, Wide-Bandgap, Thin-Film Solar Cells  

E-Print Network [OSTI]

. Low-bandgap cells can lose 25% of their power output and efficiency ratings as solar cell operating energy output than a low-bandgap cell with the same wattage or power rating. NREL is a nationalinnovati nNREL Produces Highly Efficient, Wide-Bandgap, Thin-Film Solar Cells Researchers

365

High-Efficiency Energy Conversion in a Molecular Triad Connected to Conducting Leads Anatoly Yu. Smirnov,*,,  

E-Print Network [OSTI]

for Theoretical Physics, The UniVersity of Michigan, Ann Arbor, Michigan 48109-1040, and Department of Physics is highly attractive for solar cell applications. The large predicted increase in the efficiency, the efficient conversion of solar energy into chemical or electrical forms has attracted considerable attention

Nori, Franco

366

Durable Catalysts for Fuel Cell Protection during Transient Conditions...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Working Group Meeting: June 2014 DOE's Fuel Cell Catalyst R&D Activities Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports...

367

Desalination of seawater using a high-efficiency jet ejector  

E-Print Network [OSTI]

the nozzle and rushes through th e suction head. STAGE 3: A low absolute pressu re at 2 (inside suction head) entrains all of the adjacent gases in the vacuum vessel, acce lerates them to a high velocity and sw eeps them into the diffuser. The Diffuser... in temperature is essential for the evaporation process in this effect [44]. Capacities and possible pressu re ratios of the available vapor compressors play major roles in the limitations imposed on MVC systems; hence, a small number of effects wi th small...

Vishwanathappa, Manohar D.

2005-08-29T23:59:59.000Z

368

High-Efficiency Clean Combustion Engine Designs for Compression Ignition  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many| Department HIGH PERFORMANCETheEngines |

369

High-Efficiency Window Air Conditioners - Building America Top Innovation |  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many| Department HIGH

370

Path to High Efficiency Gasoline Engine | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSalesOE0000652Grow Your EnergyTechnology to Market »Path to High

371

High Efficiency Multiple-Junction Solar Cells - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in the Madison SymmetricHigh Carbon Fly Ashand|Solar

372

Highly Efficient Multigap Solar Cell Materials - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in theinPlastics -␤,of Energy2-ButanolHighly

373

Adsorption of hydrogen on copper catalysts  

SciTech Connect (OSTI)

Copper catalysts display a high activity and selectivity in the hydrogenation of various carbonyl compounds, and copper is a component of the complex catalysts for the synthesis of methanol from CO and H/sub 2/. The adsorption of H/sub 2/ on copper catalysts has been studied by means of thermal desorption. The molecular form of adsorption of H/sub 2/ has been established, the thermal desorption parameters calculated, and the heat of adsorption of H/sub 2/ on a copper surface estimated.

Pavlenko, N.V.; Tripol'skii, A.I.; Golodets, G.I.

1987-10-01T23:59:59.000Z

374

Steam reforming utilizing iron oxide catalyst  

SciTech Connect (OSTI)

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

375

Six-flow operations for catalyst development in Fischer-Tropsch synthesis: Bridging the gap between high-throughput experimentation and extensive product evaluation  

SciTech Connect (OSTI)

Design and operation of a “six-flow fixed-bed microreactor” setup for Fischer-Tropsch synthesis (FTS) is described. The unit consists of feed and mixing, flow division, reaction, separation, and analysis sections. The reactor system is made of five heating blocks with individual temperature controllers, assuring an identical isothermal zone of at least 10 cm along six fixed-bed microreactor inserts (4?mm inner diameter). Such a lab-scale setup allows running six experiments in parallel, under equal feed composition, reaction temperature, and conditions of separation and analysis equipment. It permits separate collection of wax and liquid samples (from each flow line), allowing operation with high productivities of C5+ hydrocarbons. The latter is crucial for a complete understanding of FTS product compositions and will represent an advantage over high-throughput setups with more than ten flows where such instrumental considerations lead to elevated equipment volume, cost, and operation complexity. The identical performance (of the six flows) under similar reaction conditions was assured by testing a same catalyst batch, loaded in all microreactors.

Sartipi, Sina, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Jansma, Harrie; Bosma, Duco; Boshuizen, Bart; Makkee, Michiel; Gascon, Jorge, E-mail: S.Sartipi@tudelft.nl, E-mail: J.Gascon@tudelft.nl; Kapteijn, Freek [Department of Chemical Engineering, Catalysis Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands)] [Department of Chemical Engineering, Catalysis Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands)

2013-12-15T23:59:59.000Z

376

OPERATING EXPERIENCE LEVEL 3, Requalification Test Failure of Certain High Efficiency Particulate Air (HEPA) Filters- Update  

Broader source: Energy.gov [DOE]

2014-01 Operating Experience Level 3 (OE-3) document provides information regarding the previous requalification test failure and subsequent successful requalification, of certain high efficiency particulate air (HEPA) filter models manufactured by Flanders Corporation.

377

Approaches to fabricating high-efficiency ultra-thin CdTe solar cells.  

E-Print Network [OSTI]

??This thesis is an investigation of the fabrication, characterization and performance of high-efficiency and ultra-thin CdTe solar cells with an aim of reducing the material… (more)

Xia, Wei (1981 - )

2013-01-01T23:59:59.000Z

378

Conversion Tower for Dispatchable Solar Power: High-Efficiency Solar-Electric Conversion Power Tower  

SciTech Connect (OSTI)

HEATS Project: Abengoa Solar is developing a high-efficiency solar-electric conversion tower to enable low-cost, fully dispatchable solar energy generation. Abengoa’s conversion tower utilizes new system architecture and a two-phase thermal energy storage media with an efficient supercritical carbon dioxide (CO2) power cycle. The company is using a high-temperature heat-transfer fluid with a phase change in between its hot and cold operating temperature. The fluid serves as a heat storage material and is cheaper and more efficient than conventional heat-storage materials, like molten salt. It also allows the use of a high heat flux solar receiver, advanced high thermal energy density storage, and more efficient power cycles.

None

2012-01-11T23:59:59.000Z

379

High Efficiency CdTe Ink-Based Solar Cells Using Nanocrystals (Fact Sheet)  

SciTech Connect (OSTI)

This NREL Highlight is being developed for the 2015 February Alliance S&T Board meeting and describes a solution-processable ink to produce high-efficiency solar cells using low temperature and simple processing.

Not Available

2015-01-01T23:59:59.000Z

380

Highly Energy and Performance Efficient Embedded Computing through Approximately Correct Arithmetic  

E-Print Network [OSTI]

) a mathematically rigorous foundation characterizing a trade- off between energy consumed and the quality. (ii) Techniques which trade off energy for quality of solution. These are typi- callyHighly Energy and Performance Efficient Embedded Computing through Approximately Correct Arithmetic

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Highly Efficient Amplification of Chronic Wasting Disease Agent by Protein Misfolding Cyclic Amplification with  

E-Print Network [OSTI]

Amplification with Beads (PMCAb) Chad J. Johnson1 , Judd M. Aiken2 , Debbie McKenzie2 , Michael D. Samuel3. Citation: Johnson CJ, Aiken JM, McKenzie D, Samuel MD, Pedersen JA (2012) Highly Efficient Amplification

382

Ultra Clean 1.1 MW High Efficiency Natural Gas Engine Powered...  

Broader source: Energy.gov (indexed) [DOE]

Ultra Clean 1.1 MW High Efficiency Natural Gas Engine Powered CHP System Contract: DE-EE0004016 GE Energy, Dresser Inc. 102010 - 92014 Jim Zurlo, Principal Investigator...

383

High-Efficiency 6?? Multicrystalline Black Solar Cells Based on Metal-Nanoparticle-Assisted Chemical Etching  

E-Print Network [OSTI]

Multicrystalline silicon (mc-Si) photovoltaic (PV) solar cells with nanoscale surface texturing by metal-nanoparticle-assisted etching are proposed to achieve high power efficiency. The investigation of average nanorod ...

Hsu, W. Chuck

2012-01-01T23:59:59.000Z

384

A new power combining and outphasing modulation system for high-efficiency power amplification  

E-Print Network [OSTI]

This paper describes a new power combining and outphasing system that provides both high efficiency and linear output control. Whereas conventional outphasing systems utilize two power amplifiers, the system introduced ...

Perreault, David J.

385

A New Power Combining and Outphasing Modulation System for High-Efficiency Power Amplification  

E-Print Network [OSTI]

This paper describes a new power combining and outphasing system that provides both high efficiency and linear output control. Whereas conventional outphasing systems utilize two power amplifiers, the system introduced ...

Perreault, David J.

386

Fuels and Combustion Strategies for High-Efficiency Clean-Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Optical-Engine and Surrogate-Fuels Research for an Improved Understanding of Fuel Effects on...

387

Graphene-Multilayer Graphene Nanocomposites as Highly Efficient Thermal Interface Materials  

E-Print Network [OSTI]

resistance at the graphene-matrix interface. KEYWORDS: Graphene, thermal interface materials, nanocompositesGraphene-Multilayer Graphene Nanocomposites as Highly Efficient Thermal Interface Materials Khan M suggest that graphene-multilayer graphene nanocomposite used as the thermal interface material outperforms

388

High Efficiency Clean Combustion in Multi-Cylinder Light-Duty...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Light-Duty Multi-Cylinder Engine High Efficiency Clean Combustion in Multi-Cylinder Light-Duty Engines Vehicle Technologies Office Merit Review 2014: Impacts of Advanced Combustion...

389

Architectural Support for High-Performance, Power-Efficient and Secure Multiprocessor Systems  

E-Print Network [OSTI]

domains. Also, power efficiency in high performance computing has been one of the major issues to be resolved. The power density of core components becomes significantly higher, and the fraction of power supply in total management cost is dominant...

An, Baik Song

2012-10-19T23:59:59.000Z

390

High efficiency resonant dc/dc converter for solar power applications  

E-Print Network [OSTI]

This thesis presents a new topology for a high efficiency dc/dc resonant power converter that utilizes a resistance compression network to provide simultaneous zero voltage switching and near zero current switching across ...

Inam, Wardah

2013-01-01T23:59:59.000Z

391

Testing and Economic Evaluation of a High Efficiency 10-ton Rooftop Air Conditioner  

E-Print Network [OSTI]

In 1993, the U.S. Environmental Protection Agency initiated a project to design, build and demonstrate a high efficiency commercial rooftop air conditioning unit. The unit was designed by Hibberd Consulting of Westminster, Colorado, and was built...

O'Neal, D. L.; Davis, M. A.

2006-11-09T23:59:59.000Z

392

EMSL - catalyst beds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

catalyst-beds en Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. http:www.emsl.pnl.govemslwebpublicationsmagnesium-behavior-and-structural-defe...

393

Total oxidation of carbon monoxide and methane over transition metal-fluorite oxide composite catalysts. I. Catalyst composition and activity  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the total oxidation of carbon monoxide and methane was prepared by combining fluorite oxides with active transition metals. The fluorite oxides, such as ceria and zirconia, are oxygen-ion-conducting materials having catalytic properties usually at high temperatures. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of these oxides. The contact of the two types of materials gave rise to a high active oxidation catalyst. At a space velocity of about 42,000 h{sup {minus}1}, complete carbon monoxide oxidation in air occurred at room temperature on the Au{sub 0.05}[Ce(La)]{sub 0.95}L{sub x} catalyst and at ca. 100{degrees}C on Cu-Ce-O composite catalysts. At the same space velocity, total oxidation of methane on the Cu-Ce-O catalyst doped with La{sub 2}O{sub 3} or SrO took place at ca. 550{degrees}C. The specific carbon monoxide oxidation activity of the Cu-Ce-O catalyst was several orders of magnitude higher than that of conventional copper-based catalysts and comparable or superior to platinum catalysts. This type of composite catalyst also showed excellent resistance to water vapor poisoning. The enhanced catalyst activity and stability resulted from strong interaction of the transition metal and fluorite oxide materials. 44 refs., 14 figs., 5 tabs.

Liu, W.; Flytzani-Stephanopoulos, F. [Tufts Univ., Medford, MA (United States)] [Tufts Univ., Medford, MA (United States)

1995-05-01T23:59:59.000Z

394

Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...  

Broader source: Energy.gov (indexed) [DOE]

Combustion and Lean NOx Trap Catalysts investigation of potential synergies of low emission advanced combustion techniques and advanced lean exhaust catalytic aftertreatment....

395

StationaryEnvironment ResidentialTransportation Premium Power Advanced High Efficiency, Quick Start Fuel  

E-Print Network [OSTI]

Premium Power Agenda STARTM (1999-2003) ­ Substrate based Transportation application Autothermal ReformerEnvironment Residential Stationary Premium Power STAR Fuel Processor · Autothermal reformer · Substrate-based catalysts

396

Recent advances in III-V on Si integration for high-efficiency,  

E-Print Network [OSTI]

Recent advances in III-V on Si integration for high-efficiency, low cost MJ cells Minjoo Larry Lee for concentrator photovoltaics · Metamorphic mid-infrared (2-3 µm) materials and devices(w/ D.Wasserman, UIUC · Conclusions 4 300 mm Si Low-cost, high- efficiency MJ cells on 300 mm Si 50 mm GaP 150 mm GaAs #12;Challenge

Firestone, Jeremy

397

Development of FCC catalyst magnetic separation  

SciTech Connect (OSTI)

Magnetic separation has been historically active in several different industries, yet has not been utilized in petroleum refining until recently. Development of economical permanent magnets with high magnetic strength has led to a new process known as MagnaCat{reg_sign}. The MagnaCat{reg_sign}. Process separates less active (high metals) particles catalyst from equilibrium Fluid Catalytic Cracking (FCC) catalyst, producing a higher activity/lower metals catalyst for recycle. Pilot FCC studies showed lower hydrogen, dry gas, and coke make with higher wet gas and octane from catalyst separated by MagnaCat{reg_sign}. With the use of a MagnaCat{reg_sign} Process unit, a refiner would produce an economic advantage of $0.20 to $0.40/Barrel of FCC charge and enhance unit operability.

Goolsby, T.L.; Moore, H.F. [Ashland Petroleum Co., KY (United States)

1997-01-01T23:59:59.000Z

398

Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems  

SciTech Connect (OSTI)

This final report presents and discusses results from a mercury control process development project entitled ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems''. The objective of this project was to demonstrate at pilot scale a mercury control technology that uses solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. Oxidized mercury is removed in downstream wet flue gas desulfurization (FGD) absorbers and leaves with the FGD byproducts. The goal of the project was to achieve 90% oxidation of elemental mercury in the flue gas and 90% overall mercury capture with the downstream wet FGD system. The project was co-funded by EPRI and the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) under Cooperative Agreement DE-FC26-01NT41185. Great River Energy (GRE) and City Public Service (now CPS Energy) of San Antonio were also project co-funders and provided host sites. URS Group, Inc. was the prime contractor. Longer-term pilot-scale tests were conducted at two sites to provide catalyst life data. GRE provided the first site, at their Coal Creek Station (CCS), which fires North Dakota lignite, and CPS Energy provided the second site, at their Spruce Plant, which fires Powder River Basin (PRB) coal. Mercury oxidation catalyst testing began at CCS in October 2002 and continued through the end of June 2004, representing nearly 21 months of catalyst operation. An important finding was that, even though the mercury oxidation catalyst pilot unit was installed downstream of a high-efficiency ESP, fly ash buildup began to plug flue gas flow through the horizontal catalyst cells. Sonic horns were installed in each catalyst compartment and appeared to limit fly ash buildup. A palladium-based catalyst showed initial elemental mercury oxidation percentages of 95% across the catalyst, declining to 67% after 21 months in service. A carbon-based catalyst began with almost 98% elemental mercury oxidation across the catalyst, but declined to 79% oxidation after nearly 13 months in service. The other two catalysts, an SCR-type catalyst (titanium/vanadium) and an experimental fly-ash-based catalyst, were significantly less active. The palladium-based and SCR-type catalysts were effectively regenerated at the end of the long-term test by flowing heated air through the catalyst overnight. The carbon-based catalyst was not observed to regenerate, and no regeneration tests were conducted on the fourth, fly-ash-based catalyst. Preliminary process economics were developed for the palladium and carbon-based catalysts for a scrubbed, North Dakota lignite application. As described above, the pilot-scale results showed the catalysts could not sustain 90% or greater oxidation of elemental mercury in the flue gas for a period of two years. Consequently, the economics were based on performance criteria in a later DOE NETL solicitation, which required candidate mercury control technologies to achieve at least a 55% increase in mercury capture for plants that fire lignite. These economics show that if the catalysts must be replaced every two years, the catalytic oxidation process can be 30 to 40% less costly than conventional (not chemically treated) activated carbon injection if the plant currently sells their fly ash and would lose those sales with carbon injection. If the plant does not sell their fly ash, activated carbon injection was estimated to be slightly less costly. There was little difference in the estimated cost for palladium versus the carbon-based catalysts. If the palladium-based catalyst can be regenerated to double its life to four years, catalytic oxidation process economics are greatly improved. With regeneration, the catalytic oxidation process shows over a 50% reduction in mercury control cost compared to conventional activated carbon injection for a case where the plant sells its fly ash. At Spruce Plant, mercury oxidation catalyst testing began in September 2003 and continued through the end of April 2005, interrupted only by a

Richard Rhudy

2006-06-30T23:59:59.000Z

399

ULTRA HIGH EFFICIENCY ESP DEVELOPMENT FOR AIR TOXICS CONTROL  

SciTech Connect (OSTI)

Because more than 90 percent of U.S. coal-fired utility boilers are equipped with electrostatic precipitators (ESPs), retrofitable ESP technologies represent a logical approach towards achieving the Department of Energy's (DOE) goal of a major reduction in fine particulate and mercury emissions (air toxics) from coal based power systems. EPA's recent issuance of significantly tightened ambient air standards for particles smaller than 2.5 {micro}m (PM{sub 2.5}) creates a new urgency for developing cost-effective means to control fine particulate emissions. This challenge is compounded by the on-going switch in the utility industry to low-sulfur Powder River Basin (PRB) coals, that generate higher resistivity and difficult-to-collect fly ash. Particulate emissions can increase by a factor of ten when a utility switches to a low-sulfur coal. Numerous power plants are presently limited in operation by the inability of their ESPs to control opacity at high loads. In Phase I of this program, ABB investigated five technologies to improve the collection of fine particulate and trace metals in ESPs. These included: (1) flue-gas cooling, (2) flue-gas humidification, (3) pulsed energization, (4) wet ESP and precharger modules, and (5) sorbent injection for mercury control. Tests were conducted with an Eastern bituminous coal and a Powder River Basin sub-bituminous low-sulfur coal in an integrated pilot-scale combustor and ESP test facility. The impacts of the different retrofit technologies on ESP performance, individually and in combination, were evaluated indepth through advanced sampling and measurement techniques. In Phase II, the most promising concepts identified from Phase I testing, flue-gas cooling and humidification, pulsed energization, and sorbent injection at low flue-gas temperatures for mercury control, were integrated into a commercially oriented sub-scale system for field testing at Commonwealth Edison's Waukegan Unit No. 8. The main objective of the proposed Phase II testing was to determine longer term ESP performance and mercury capture improvements with the above enhancements for a range of low-sulfur coals currently fired by utilities. Unanticipated cost growth in readying the Pilot Plant for shipment and during slipstream construction at the utility host site resulted in the issuance of a preemptive stop work order from ABB until a detailed technical and budgetary review of the project could be completed. Four program recovery scenarios were developed and presented to the DOE. After careful review of these options, it was decided to terminate the program and although the Pilot Plant installation was essentially completed, no testing was performed. The Pilot Plant was subsequently decommissioned and the host site returned to its preprogram condition.

David K. Anderson

1999-11-01T23:59:59.000Z

400

TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS  

SciTech Connect (OSTI)

The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

Davis, B.H.

1998-07-22T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

High Efficiency, Low Cost Solar Cells Manufactured Using 'Silicon Ink' on Thin Crystalline Silicon Wafers  

SciTech Connect (OSTI)

Reported are the development and demonstration of a 17% efficient 25mm x 25mm crystalline Silicon solar cell and a 16% efficient 125mm x 125mm crystalline Silicon solar cell, both produced by Ink-jet printing Silicon Ink on a thin crystalline Silicon wafer. To achieve these objectives, processing approaches were developed to print the Silicon Ink in a predetermined pattern to form a high efficiency selective emitter, remove the solvents in the Silicon Ink and fuse the deposited particle Silicon films. Additionally, standard solar cell manufacturing equipment with slightly modified processes were used to complete the fabrication of the Silicon Ink high efficiency solar cells. Also reported are the development and demonstration of a 18.5% efficient 125mm x 125mm monocrystalline Silicon cell, and a 17% efficient 125mm x 125mm multicrystalline Silicon cell, by utilizing high throughput Ink-jet and screen printing technologies. To achieve these objectives, Innovalight developed new high throughput processing tools to print and fuse both p and n type particle Silicon Inks in a predetermined pat-tern applied either on the front or the back of the cell. Additionally, a customized Ink-jet and screen printing systems, coupled with customized substrate handling solution, customized printing algorithms, and a customized ink drying process, in combination with a purchased turn-key line, were used to complete the high efficiency solar cells. This development work delivered a process capable of high volume producing 18.5% efficient crystalline Silicon solar cells and enabled the Innovalight to commercialize its technology by the summer of 2010.

Antoniadis, H.

2011-03-01T23:59:59.000Z

402

Hydrocarbon cracking catalyst  

SciTech Connect (OSTI)

This patent describes a catalyst composition for cracking hydrocarbons to maximize gasoline comprising: rare earth exchanged ''Y'' crystalline faujasite dispersed in a clay containing matrix material; and which has been subsequently further ion exchanged to contain 0.20 to 3.0 wt% yttrium, calculated as the oxide, whereby the yttrium is chemically combined in the catalyst composition.

Lochow, C.F.; Kovacs, D.B.

1988-12-27T23:59:59.000Z

403

Nanostructured catalyst supports  

DOE Patents [OSTI]

The present invention relates to SiC nanostructures, including SiC nanopowder, SiC nanowires, and composites of SiC nanopowder and nanowires, which can be used as catalyst supports in membrane electrode assemblies and in fuel cells. The present invention also relates to composite catalyst supports comprising nanopowder and one or more inorganic nanowires for a membrane electrode assembly.

Zhu, Yimin; Goldman, Jay L.; Qian, Baixin; Stefan, Ionel C.

2012-10-02T23:59:59.000Z

404

Reducible oxide based catalysts  

DOE Patents [OSTI]

A catalyst is disclosed herein. The catalyst includes a reducible oxide support and at least one noble metal fixed on the reducible oxide support. The noble metal(s) is loaded on the support at a substantially constant temperature and pH.

Thompson, Levi T.; Kim, Chang Hwan; Bej, Shyamal K.

2010-04-06T23:59:59.000Z

405

Homogeneous catalysts in hypersonic combustion  

SciTech Connect (OSTI)

Density and residence time both become unfavorably small for efficient combustion of hydrogen fuel in ramjet propulsion in air at high altitude and hypersonic speed. Raising the density and increasing the transit time of the air through the engine necessitates stronger contraction of the air flow area. This enhances the kinetic and thermodynamic tendency of H/sub 2/O to form completely, accompanied only by N/sub 2/ and any excess H/sub 2/(or O/sub 2/). The by-products to be avoided are the energetically expensive fragment species H and/or O atoms and OH radicals, and residual (2H/sub 2/ plus O/sub 2/). However, excessive area contraction raises air temperature and consequent combustion-product temperature by adiabatic compression. This counteracts and ultimately overwhelms the thermodynamic benefit by which higher density favors the triatomic product, H/sub 2/O, over its monatomic and diatomic alternatives. For static pressures in the neighborhood of 1 atm, static temperature must be kept or brought below ca. 2400 K for acceptable stability of H/sub 2/O. Another measure, whose requisite chemistry we address here, is to extract propulsive work from the combustion products early in the expansion. The objective is to lower the static temperature of the combustion stream enough for H/sub 2/O to become adequately stable before the exhaust flow is massively expanded and its composition ''frozen.'' We proceed to address this mechanism and its kinetics, and then examine prospects for enhancing its rate by homogeneous catalysts. 9 refs.

Harradine, D.M.; Lyman, J.L.; Oldenborg, R.C.; Pack, R.T.; Schott, G.L.

1989-01-01T23:59:59.000Z

406

Development of a stable cobalt-ruthenium Fisher-Tropsch catalyst. Final report  

SciTech Connect (OSTI)

The reverse micelle catalyst preparation method has been used to prepare catalysts on four supports: magnesium oxide, carbon, alumina- titania and steamed Y zeolite. These catalysts were not as active as a reference catalyst prepared during previous contracts to Union Carbide Corp. This catalyst was supported on steamed Y zerolite support and was impregnated by a pore-filling method using a nonaqueous solvent. Additional catalysts were prepared via pore- filling impregnation of steamed Y zeolites. These catalysts had levels of cobalt two to three and a half times as high as the original Union Carbide catalyst. On a catalyst volume basis they were much more active than the previous catalyst; on an atom by atom basis the cobalt was about of the same activity, i.e., the high cobalt catalysts` cobalt atoms were not extensively covered over and deactivated by other cobalt atoms. The new, high activity, Y zerolite catalysts were not as stable as the earlier Union Carbide catalyst. However, stability enhancement of these catalysts should be possible, for instance, through adjustment of the quantity and/or type of trace metals present. A primary objective of this work was determination whether small amounts of ruthenium could enhance the activity of the cobalt F-T catalyst. The reverse micelle catalysts were not activated by ruthenium, indeed scanning transmission electronic microscopy (STEM) analysis provided some evidence that ruthenium was not present in the cobalt crystallites. Ruthenium did not seem to activate the high cobalt Y zeolite catalyst either, but additional experiments with Y zeolite-supported catalysts are required. Should ruthenium prove not to be an effective promoter under the simple catalyst activation procedure used in this work, more complex activation procedures have been reported which are claimed to enhance the cobalt/ruthenium interaction and result in activity promotion by ruthenium.

Frame, R.R.; Gala, H.B.

1995-02-01T23:59:59.000Z

407

Extended Platinum Nanotubes as Fuel Cell Catalysts  

SciTech Connect (OSTI)

Energy consumption has relied principally on fossil fuels as an energy source; fuel cells, however, can provide a clean and sustainable alternative, an answer to the depletion and climate change concerns of fossil fuels. Within proton exchange membrane fuel cells, high catalyst cost and poor durability limit the commercial viability of the device. Recently, platinum nanotubes (PtNTs) were studied as durable, active catalysts, providing a platform to meet US Department of Energy vehicular activity targets.[1] Porous PtNTs were developed to increase nanotube surface area, improving mass activity for oxygen reduction without sacrificing durability.[2] Subsurface platinum was then replaced with palladium, forming platinum-coated palladium nanotubes.[3] By forming a core shell structure, platinum utilization was increased, reducing catalyst cost. Alternative substrates have also been examined, modifying platinum surface facets and increasing oxygen reduction specific activity. Through modification of the PtNT platform, catalyst limitations can be reduced, ensuring a commercially viable device.

Alia, S.; Pivovar, B. S.; Yan, Y.

2012-01-01T23:59:59.000Z

408

Adsorbent key to polypropylene catalyst activity  

SciTech Connect (OSTI)

Propylene streams from the refinery fluid catalytic cracking unit and delayed coker contain contaminants that are poisons to polymerization catalysts. A new sorbent catalyst, called Prosorb, allows petrochemical producers to clean up these dirty'' propylene streams to a level adequate for use with the new high-yielded polymerization catalysts. The process, called Triple P'' (propylene polishing process), eliminates all common contaminants, including COS, H[sub 2]S, mercaptans, AsH[sub 3], and SbH[sub 3]. Commercial trials have taken place at two Fina refineries and at a joint venture petrochemical plant. The refineries used the process to upgrade propylene feed from gasoline value to nearly polymer-grade value. The petrochemical producer was able to increase the activity of its polymerization catalyst and the consistency of the process.

Detrait, J.C.; Grootjans, J.F. (Fina Research, Feluy (Belgium))

1994-10-10T23:59:59.000Z

409

VII Pillars Of Productivity Seven practices characterize highly productive companies turning them into 'digital organizations.' IT is the catalyst,  

E-Print Network [OSTI]

VII Pillars Of Productivity Seven practices characterize highly productive companies turning them's productivity growth, more than any other economic statistic, that determines our living standards. If productivity grows at 1% per year, living standards will double every 70 years. If productivity grows at 3% per

410

Development of a solar receiver for a high-efficiency thermionic/thermoelectric conversion system  

SciTech Connect (OSTI)

Solar energy is one of the most promising energy resources on Earth and in space, because it is clean and inexhaustible. Therefore, we have been developing a solar-powered high-efficiency thermionic-thermoelectric conversion system which combines a thermionic converter (TIC) with a thermoelectric converter (TEC) to use thermal energy efficiently and to achieve high efficiency conversion. The TIC emitter must uniformly heat up to 1800 K. The TIC emitter can be heated using thermal radiation from a solar receiver maintained at a high temperature by concentrated solar irradiation. A cylindrical cavity-type solar receiver constructed from graphite was designed and heated in a vacuum by using the solar concentrator at Tohoku University. The maximum temperature of the solar receiver enclosed by a molybdenum cup reached 1965 K, which was sufficiently high to heat a TIC emitter using thermal radiation from the receiver. 4 refs., 6 figs., 1 tab.

Naito, H.; Kohsaka, Y.; Cooke, D.; Arashi, H. [Tohoku Univ., Aramaki (Japan)] [Tohoku Univ., Aramaki (Japan)

1996-10-01T23:59:59.000Z

411

FastRoute: An efficient and high-quality global , Yanheng Zhang3  

E-Print Network [OSTI]

measured at the edges of global routing grids but also minimize the total wirelength and via usage, which1 FastRoute: An efficient and high-quality global router Min Pan1 , Yue Xu2 , Yanheng Zhang3--Modern large-scale circuit designs have created great demand for fast and high-quality global routing

Chu, Chris C.-N.

412

Catalysts and process for liquid hydrocarbon fuel production  

DOE Patents [OSTI]

The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

White, Mark G; Liu, Shetian

2014-12-09T23:59:59.000Z

413

High efficiency SHG of orbital angular momentum light in an external cavity  

E-Print Network [OSTI]

Traditional methods for generating orbital angular momentum (OAM) light include holographic diffraction gratings, vortex phase plate and spatial light modulator. In this article, we report a new method for high efficient OAM light generation. By pumping an external cavity contains a quasi phase matching nonlinear crystal with a fundamental OAM carrying light and properly aligning the cavity, mode matching between the pump light and the cavitys higher order Laguerre-Gaussian (LG) mode is achieved, conversion efficiency up to 10.3 percentage have been obtained. We have demonstrated that the cavity can stably operate at its higher order LG mode just as Gaussian mode for the first time. The SHG light possesses a doubled OAM value with respect to the pump light. The parameters that affect the beam quality and conversion efficiency are discussed in detail. Our work opens a brand new field in laser optics, and makes the first step toward high efficiency OAM light processing.

Zhi-Yuan Zhou; Yan Li; Dong-Sheng Ding; Yun-Kun Jiang; Wei Zhang; Shuai Shi; Bao-Sen Shi; Guang-Can Guo

2014-05-12T23:59:59.000Z

414

Highly-Efficient Thermoelectronic Conversion of Solar Energy and Heat into Electric Power  

E-Print Network [OSTI]

Electric power may, in principle, be generated in a highly efficient manner from heat created by focused solar irradiation, chemical combustion, or nuclear decay by means of thermionic energy conversion. As the conversion efficiency of the thermionic process tends to be degraded by electron space charges, the efficiencies of thermionic generators have amounted to only a fraction of those fundamentally possible. We show that this space-charge problem can be resolved by shaping the electric potential distribution of the converter such that the static electron space-charge clouds are transformed into an output current. Although the technical development of practical generators will require further substantial efforts, we conclude that a highly efficient transformation of heat to electric power may well be achieved.

Meir, S; Geballe, T H; Mannhart, J

2013-01-01T23:59:59.000Z

415

Catalyst for the reduction of sulfur dioxide to elemental sulfur  

DOE Patents [OSTI]

The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

1996-01-01T23:59:59.000Z

416

Development and Applications of Pd Catalysts for C-N Cross-Coupling Reactions  

E-Print Network [OSTI]

Chapter 1 A procedure for forming a highly active Pd(0) catalyst from Pd(OAc) 2, water, and biarylphosphine ligands has been developed. This protocol generates a catalyst system, which exhibits excellent reactivity and ...

Fors, Brett P

2011-01-01T23:59:59.000Z

417

Refractory oxide hosts for a high power, broadly tunable laser with high quantum efficiency and method of making same  

DOE Patents [OSTI]

Refractory oxide crystals having high-quantum efficiency and high thermal stability for use as broadly tunable laser host materials. The crystals are formed by removing hydrogen from a single crystal of the oxide material to a level below about 10/sup 12/ protons per cm/sup 3/ and subsequently thermochemically reducing the oxygen content of the crystal to form sufficient oxygen anion vacancies so that short-lived F/sup +/ luminescence is produced when the crystal is optically excited.

Chen, Yok; Gonzalez, R.

1985-07-03T23:59:59.000Z

418

Refractory oxide hosts for a high power, broadly tunable laser with high quantum efficiency and method of making same  

DOE Patents [OSTI]

Refractory oxide crystals having high-quantum efficiency and high thermal stability for use as broadly tunable laser host materials. The crystals are formed by removing hydrogen from a single crystal of the oxide material to a level below about 10.sup.12 protons per cm.sup.3 and subsequently thermochemically reducing the oxygen content of the crystal to form sufficient oxygen anion vacancies so that short-lived F.sup.+ luminescence is produced when the crystal is optically excited.

Chen, Yok (Oak Ridge, TN); Gonzalez, Roberto (Madrid, ES)

1986-01-01T23:59:59.000Z

419

Fundamental understanding and development of low-cost, high-efficiency silicon solar cells  

SciTech Connect (OSTI)

The overall objectives of this program are (1) to develop rapid and low-cost processes for manufacturing that can improve yield, throughput, and performance of silicon photovoltaic devices, (2) to design and fabricate high-efficiency solar cells on promising low-cost materials, and (3) to improve the fundamental understanding of advanced photovoltaic devices. Several rapid and potentially low-cost technologies are described in this report that were developed and applied toward the fabrication of high-efficiency silicon solar cells.

ROHATGI,A.; NARASIMHA,S.; MOSCHER,J.; EBONG,A.; KAMRA,S.; KRYGOWSKI,T.; DOSHI,P.; RISTOW,A.; YELUNDUR,V.; RUBY,DOUGLAS S.

2000-05-01T23:59:59.000Z

420

Catalyst for microelectromechanical systems microreactors  

DOE Patents [OSTI]

A microreactor comprising a silicon wafer, a multiplicity of microchannels in the silicon wafer, and a catalyst coating the microchannels. In one embodiment the catalyst coating the microchannels comprises a nanostructured material. In another embodiment the catalyst coating the microchannels comprises an aerogel. In another embodiment the catalyst coating the microchannels comprises a solgel. In another embodiment the catalyst coating the microchannels comprises carbon nanotubes.

Morse, Jeffrey D. (Martinez, CA); Sopchak, David A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA); Reynolds, John G. (San Ramon, CA); Satcher, Joseph H. (Patterson, CA); Gash, Alex E. (Brentwood, CA)

2011-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Catalysts and method  

DOE Patents [OSTI]

An improved catlayst and method for the oxyhydrochlorination of methane is disclosed. The catalyst includes a pyrogenic porous support on which is layered as active material, cobalt chloride in major proportion, and minor proportions of an alkali metal chloride and of a rare earth chloride. On contact of the catalyst with a gas flow of methane, HC1 and oxygen, more than 60% of the methane is converted and of that converted more than 40% occurs as monochloromethane. Advantageously, the monochloromethane can be used to produce gasoline boiling range hydrocarbons with the recycle of HCl for further reaction. This catalyst is also of value for the production of formic acid as are analogous catalysts with lead, silver or nickel chlorides substituted for the cobalt chloride.

Taylor, Charles E. (Pittsburgh, PA); Noceti, Richard P. (Pittsburgh, PA)

1991-01-01T23:59:59.000Z

422

Transition metal-promoted oxygen ion conductors as oxidation catalyst  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the complete oxidation of carbon monoxide and hydrocarbons was prepared by combining oxygen ion conducting materials with active transition metals. The oxygen ion conductors used were typical fluorite-type oxides, such as ceria, zirconia, and others. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of oxygen ion conductors. The intimate contact of the two kinds of materials gave rise to a highly active oxidation catalyst. On Cu-Ce-O composite catalysts, 95% of carbon monoxide was oxidized by air at {approximately} 100 C. Complete methane oxidation on the same catalyst took place at {approximately} 550 C. When the stoichiometric amount of sulfur dioxide was sued to oxidize carbon monoxide, 96% of sulfur dioxide was reduced to elemental sulfur at temperatures above 460 C with 99% of sulfur dioxide conversion. This type of composite catalyst also showed excellent resistance to water poisoning.

Liu, W.; Sarofim, A. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Chemical Engineering; Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering

1994-12-31T23:59:59.000Z

423

Molecularly engineering homogenous catalysts  

E-Print Network [OSTI]

quickly. To attempt to 1G overcome this problem, Bergbreiter's group began work on synthesis of palladacycles in an attempt to find a more robust catalyst. The group was spurred to do this by the success of Denmark using chiral bis (oxazoline) palladium... (II) catalysts that proved to be active. Denmark's use of oxazoline ligands avoided the problem of phosphine oxidation. They were also inspired by Milstein and coworkers description of a phosphorus-carbon-phosphorus (PCP)-type tridentate ligand...

Hughes, Reagan Rebekah

2013-02-22T23:59:59.000Z

424

Plasmatron-catalyst system  

DOE Patents [OSTI]

A plasmatron-catalyst system. The system generates hydrogen-rich gas and comprises a plasmatron and at least one catalyst for receiving an output from the plasmatron to produce hydrogen-rich gas. In a preferred embodiment, the plasmatron receives as an input air, fuel and water/steam for use in the reforming process. The system increases the hydrogen yield and decreases the amount of carbon monoxide.

Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA); Alexeev, Nikolai (Moscow, RU)

2007-10-09T23:59:59.000Z

425

Crystalline titanate catalyst supports  

DOE Patents [OSTI]

A series of new crystalline titanates (CT) are shown to have considerable potential as catalyst supports. For Pd supported catalyst, the catalytic activity for pyrene hydrogenation was substantially different depending on the type of CT, and one was substantially more active than Pd on hydrous titanium oxide (HTO). For 1-hexene hydrogenation the activities of the new CTs were approximately the same as for the hydrous metal oxide supports.

Anthony, R.G.; Dosch, R.G.

1993-01-05T23:59:59.000Z

426

DEMONSTRATION OF 3D EFFECTS WITH HIGH GAIN AND EFFICIENCY IN A UV FEL OSCILLATOR  

SciTech Connect (OSTI)

We report on the performance of a high gain UV FEL oscillator operating on an energy recovery linac at Jefferson Lab. The high brightness of the electron beam leads to both gain and efficiency that cannot be reconciled with a one-dimensional model. Three-dimensional simulations do predict the performance with reasonable precision. Gain in excess of 100% per pass and an efficiency close to 1/2NW, where NW is the number of wiggler periods, is seen. The laser mirror tuning curves currently permit operation in the wavelength range of 438 to 362 nm. Another mirror set allows operation at longer wavelengths in the red with even higher gain and efficiency.

Stephen Benson; George Biallas; Keith Blackburn; James Boyce; Donald Bullard; James Coleman; Cody Dickover; David Douglas; Forrest Ellingsworth; Pavel Evtushenko; Carlos Hernandez-Garcia; Christopher Gould; Joseph Gubeli; David Hardy; Kevin Jordan; John Klopf; James Kortze; Robert Legg; Matthew Marchlik; Steven Moore; George Neil; Thomas Powers; Daniel Sexton; Michelle D. Shinn; Christopher Tennant; Richard Walker; Anne Watson; Gwyn Williams; Frederick Wilson; Shukui Zhang

2011-03-01T23:59:59.000Z

427

Research directions and progress in the SERI advanced high efficiency concept program  

SciTech Connect (OSTI)

The inherent electro-optical properties of gallium arsenide (GaAs) and related III-V compounds make this class of semiconductors an optimum choice for use in very high efficiency solar cells. The ability to alloy GaAs with other column III and V elements while maintaining the single crystal zincblende structure allows the photovoltaic properties to be tailored to specific needs. The current understanding and control of the properties of these materials is more advanced than for any other semiconductor except single crystal silicon. For these reasons, the Advanced High Efficiency Concepts Program supports materials research to improve the properties of III-V semiconductors needed to achieve the maximum attainable photovoltaic conversion efficiencies.

Cole, L.A.; Benner, J.P.

1984-06-01T23:59:59.000Z

428

Highly efficient star formation in NGC 5253 possibly from stream-fed accretion  

E-Print Network [OSTI]

A local dwarf galaxy, NGC 5253, has a young super star cluster that may provide an example of highly efficient star formation. Here we report the detection and imaging, with the Submillimeter Array, of the J= 3-2 rotational transition of CO at the location of the massive cluster associated with the supernebula. The gas cloud is hot, dense, quiescent, and extremely dusty. Its gas-to-dust ratio is lower than the Galactic value, which we attribute to dust enrichment by Wolf-Rayet stars within the embedded star cluster. Its star formation efficiency exceeds 50%, ten times higher than clouds in the Milky Way: this cloud is a factory of stars and soot. We suggest that high efficiency results from the force-feeding of star formation by a streamer of gas falling into the galaxy.

Turner, J L; Benford, D J; Consiglio, S M; Ho, P T P; Kovács, A; Meier, D S; Zhao, J -H

2015-01-01T23:59:59.000Z

429

High performance of a carbon supported ternary PdIrNi catalyst for ethanol electro-oxidation in anion-exchange membrane direct ethanol fuel cells  

E-Print Network [OSTI]

-oxidation in anion-exchange membrane direct ethanol fuel cells Shuiyun Shen, T. S. Zhao,* Jianbo Xu and Yinshi Li-exchange membrane direct ethanol fuel cells (AEM DEFCs). We demonstrate that the use of the ternary PdIrNi catalyst for the ethanol oxidation reaction (EOR) in anion-exchange membrane direct ethanol fuel cells (AEM DEFCs) offers

Zhao, Tianshou

430

Solar Cells, 3 (1981) 337 -340 337 HIGH EFFICIENCY BIFACIAL BACK SURFACE FIELD SOLAR CELLS  

E-Print Network [OSTI]

. CUEVAS, A. LUQUE, J. EGUREN and J. DEL ALAMO Instituto de Energia Solar, Escuela Tdcnica Superior deSolar Cells, 3 (1981) 337 - 340 337 HIGH EFFICIENCY BIFACIAL BACK SURFACE FIELD SOLAR CELLS A solar cells are presented. Effi- ciencies of 15.7% and 13.6% were measured under front and back air mass

del Alamo, Jesús A.

431

Review paper: Toward highly efficient quantum-dot-and dye-sensitized solar cells  

E-Print Network [OSTI]

Review paper: Toward highly efficient quantum-dot- and dye-sensitized solar cells Hongsik Choi Interface control Light harvesting Tandem solar cell a b s t r a c t Dye- and quantum-dot-sensitized solar technologies of silicon-based solar cells should be resolved [7]. Dye-sensitized solar cells (DSSCs) have been

Park, Byungwoo

432

Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells  

E-Print Network [OSTI]

Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells Kadiatou photoanodes for dye- sensitized solar cells (DSCs), based on nanocrystalline TiO2 with limited addition applied (i.e., soaking in TiCl4 to boost open circuit photovoltage). INTRODUCTION Dye-sensitized solar

433

Air-Stable High-Efficiency Solar Cells Using Improved Single-Walled Carbon Nanotube Films  

E-Print Network [OSTI]

1 Air-Stable High-Efficiency Solar Cells Using Improved Single-Walled Carbon Nanotube Films Kehang-3-5800-6983. #12;2 ABSTRACT We present the single-walled carbon nanotube/silicon (SWNT/Si) solar cells approaching, the PCEs of the fabricated solar cells slightly increased after six-month exposure in air without any

Maruyama, Shigeo

434

EARTH ABUNDANT MATERIALS FOR HIGH EFFICIENCY HETEROJUNCTION THIN FILM SOLAR CELLS  

E-Print Network [OSTI]

EARTH ABUNDANT MATERIALS FOR HIGH EFFICIENCY HETEROJUNCTION THIN FILM SOLAR CELLS Yun Seog Lee 1; * Corresponding author: buonassisi@mit.edu; ABSTRACT We investigate earth abundant materials for thin- film solar cuprous oxide (Cu2O) as a prototype candidate for investigation as an absorber layer in thin film solar

Ceder, Gerbrand

435

FIELD TEST OF A HIGH-EFFICIENCY, AUTOMATIC-DEFROST REFRIGERATOR-FREEZER  

E-Print Network [OSTI]

#12;FIELD TEST OF A HIGH-EFFICIENCY, AUTOMATIC- DEFROST REFRIGERATOR-FREEZER By Richard F. Topping and manufacture pre-production units for home usage tests. The purpose of the field test and the associated market been promising. The first five months of field test data have shown an average 57% decrease in energy

Oak Ridge National Laboratory

436

Design and global optimization of high-efficiency solar thermal systems  

E-Print Network [OSTI]

Design and global optimization of high-efficiency solar thermal systems with tungsten cermets David, Massachusetts 02139, USA bermel@mit.edu Abstract: Solar thermal, thermoelectric, and thermophotovoltaic (TPV by selective solar absorbers and TPV selective emitters. To improve these critical components, we study a class

Soljaèiæ, Marin

437

GE Hosts Visit by DOE to Kick Off High-Efficiency GeneratorDevelopment Program  

E-Print Network [OSTI]

, Program Manager for Distributed Energy and Electric Reliability, and James Daley, Team Leader for High. This reduction in generator losses will increase overall power plant energy efficiency, creating the potential to Produce Major Benefits for U. S. Utilities SCHENECTADY, NY ­ Date ­ Officials from the U.S. Department

438

Highly efficient separation of carbon dioxide by a metal-organic framework replete with  

E-Print Network [OSTI]

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal capture of CO2, which is essential for natural gas purifi- cation and CO2 sequestration, has been reported media. carbon dioxide capture dynamic adsorption reticular chemistry Selective removal of CO2 from

Yaghi, Omar M.

439

A High Performance, Energy Efficient GALS Processor Microarchitecture with Reduced Implementation Complexity  

E-Print Network [OSTI]

A High Performance, Energy Efficient GALS Processor Microarchitecture with Reduced Implementation Complexity £ YongKang Zhu , David H. Albonesi Ý and Alper Buyuktosunoglu � Department of Electrical, achieves impressive energy savings for a relatively low per- formance cost. However, the approach requires

Albonesi, David H.

440

Efficient Transmitters and Receivers for High-Power Wireless Powering Systems  

E-Print Network [OSTI]

and Energy Engineering University of Colorado Boulder ,U.S.A. zoya@colorado.edu Abstract-- The efficiency plane waves carrying ultra-low power levels are scavenged or harvested from known transmitters typically in the UHF or microwave range [7,8]. High power levels are also used in some beaming applications with plane

Popovic, Zoya

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

High-efficient solar power systems based on thermionic converter with small gap  

SciTech Connect (OSTI)

Various configurations of power systems based on thermionic converter with small interelectrode gap have been considered. The results of studies of systems energy characteristics are presented. The high efficiency and perspectivety of such systems for different applications have been shown. {copyright} {ital 1996 American Institute of Physics.}

Nikolaev, Y.V.; Eryomin, S.A.; Kalmykov, S.S.; Karpechenko, Y.D.; Kucherov, R.Y.; Lapochkin, N.V. [Research Institute of Scientific Industrial Association ``Lutch``, 142100, Podolsk, Moscow Region (Russian Federation)

1996-03-01T23:59:59.000Z

442

Thermionic/AMTEC cascade converter concept for high-efficiency space power  

SciTech Connect (OSTI)

This paper presents trade studies that address the use of the thermionic/AMTEC cell--a cascaded, high-efficiency, static power conversion concept that appears well-suited to space power applications. Both the thermionic and AMTEC power conversion approaches have been shown to be promising candidates for space power. Thermionics offers system compactness via modest efficiency at high heat rejection temperatures, and AMTEC offers high efficiency at modest heat rejection temperature. From a thermal viewpoint the two are ideally suited for cascaded power conversion: thermionic heat rejection and AMTEC heat source temperatures are essentially the same. In addition to realizing conversion efficiencies potentially as high as 35--40%, such a cascade offers the following perceived benefits: survivability; simplicity; technology readiness; and technology growth. Mechanical approaches and thermal/electric matching criteria for integrating thermionics and AMTEC into a single conversion device are described. Focusing primarily on solar thermal space power applications, parametric trends are presented to show the performance and cost potential that should be achievable with present-day technology in cascaded thermionic/AMTEC systems.

Hagan, T.H. van; Smith, J.N. Jr. [General Atomics, San Diego, CA (United States); Schuller, M. [PL/VTP, Kirtland AFB, NM (United States)

1996-12-31T23:59:59.000Z

443

Life cycle assessment of buildings technologies: High-efficiency commercial lighting and residential water heaters  

SciTech Connect (OSTI)

In this study the life cycle emissions and energy use are estimated for two types of energy technologies. The first technology evaluated is the sulfur lamp, a high-efficiency lighting system under development by the US Department of Energy (DOE) and Fusion Lighting, the inventor of the technology. The sulfur lamp is compared with conventional metal halide high-intensity discharge lighting systems. The second technology comparison is between standard-efficiency and high-efficiency gas and electric water heaters. In both cases the life cycle energy use and emissions are presented for the production of an equivalent level of service by each of the technologies. For both analyses, the energy use and emissions from the operation of the equipment are found to dominate the life cycle profile. The life cycle emissions for the water heating systems are much more complicated. The four systems compared include standard- and high-efficiency gas water heaters, standard electric resistance water heaters, and heat pump water heaters.

Freeman, S.L.

1997-01-01T23:59:59.000Z

444

ORIGINAL ARTICLE Highly efficient GaAs solar cells by limiting light emission  

E-Print Network [OSTI]

ORIGINAL ARTICLE Highly efficient GaAs solar cells by limiting light emission angle Emily D Kosten1 solar cell under direct sunlight, light is received from the solar disk, but is re-emitted isotropically.1038/lsa.2013.1; published online 4 January 2013 Keywords: detailed balance; GaAs solar cell; light

Atwater, Harry

445

High efficiency light emitting diode with anisotropically etched GaN-sapphire interface  

E-Print Network [OSTI]

High efficiency light emitting diode with anisotropically etched GaN- sapphire interface M. H. Lo and optimization of a light-emitting diode projection micro-stereolithography three-dimensional manufacturingGaN micro-light emitting diodes Appl. Phys. Lett. 101, 231110 (2012) A bright cadmium-free, hybrid organic

446

High efficiency photovoltaic power conditioning system Hosam Sharabash, DVMM Krishna, Norbert Frhleke and Joachim Bcker  

E-Print Network [OSTI]

, Germany sharabash@lea.upb.de Abstract A new topology for photovoltaic Power Conditioning System (PCS, this redundant topol- ogy consists of two new components, one for DC/DC converter and one for inverter. The preHigh efficiency photovoltaic power conditioning system Hosam Sharabash, DVMM Krishna, Norbert

Paderborn, Universität

447

HIGH EFFICIENCY Cu(ln,Ga)SepBASED SOLAR CELLS: PROCESSING OF NOVEL ABSORBER STRUCTURES  

E-Print Network [OSTI]

be more optimally solved by either lowering substrate temperature or finding other suitable and low-cost ABSTRACT Our effort towards the attainment of high performance devices has yielded several devices, and 15.3% for a 4.85-cm* single cell. Achievement of a 17.2% device efficiency fabricated for operation

Scofield, John H.

448

Development of a PF Fired High Efficiency Power Plant (AD700)  

E-Print Network [OSTI]

Development of a PF Fired High Efficiency Power Plant (AD700) Rudolph Blum, Sven Kjær and Jørgen and nickel-based superalloys for the hottest sections of boilers, steam lines and turbines. Other targets were development of boiler and turbine designs for the more advanced conditions and finally economic

449

Hexachloroethane: a highly efficient reagent for the synthesis of chlorosilanes from hydrosilanes  

E-Print Network [OSTI]

Hexachloroethane: a highly efficient reagent for the synthesis of chlorosilanes from hydrosilanes online 27 May 2009 Keywords: Hexachloroethane Hydrosilanes Chlorosilanes Palladium(II) chloride of chlorosilanes from hydrosil- anes. A variety of chlorinating agents in combination with palladium(II) chloride

Theodorakis, Emmanuel

450

Vehicle Technologies Office Merit Review 2014: High Temperature Materials for High Efficiency Engines  

Broader source: Energy.gov [DOE]

Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high...

451

Research and development of a high efficiency gas-fired water heater. Volume 2. Task reports  

SciTech Connect (OSTI)

Design and development of a cost-effective high efficiency gas-fired water heater to attain a service efficiency of 70% (including the effect of exfiltration) and a service efficiency of 78% (excluding exfiltration) for a 75 GPD draw at a 90/sup 0/F temperature rise, with a stored water to conditioned air temperature difference of 80/sup 0/F, are described in detail. Based on concept evaluation, a non-powered natural draft water heater was chosen as the most cost-effective design to develop. The projected installed cost is $374 compared to $200 for a conventional unit. When the project water heater is compared to a conventional unit, it has a payback of 3.7 years and life cycle savings of $350 to the consumer. A prototype water heater was designed, constructed, and tested. When operated with sealed combustion, the unit has a service efficiency of 66.4% (including the effect of exfiltration) below a burner input of 32,000 Btu/h. In the open combustion configuration, the unit operated at a measured efficiency of 66.4% Btu/h (excluding exfiltration). This compares with a service efficiency of 51.3% for a conventional water heater and 61% for a conventional high efficiency unit capable of meeting ASHRAE 90-75. Operational tests showed the unit performed well with no evidence of stacking or hot spots. It met or exceeded all capacity or usage tests specified in the program test plan and met all emission goals. Future work will concentrate on designing, building, and testing pre-production units. It is anticipated that both sealed combustion and open draft models will be pursued.

Vasilakis, A.D.; Pearson, J.F.; Gerstmann, J.

1980-01-01T23:59:59.000Z

452

Supported organometallic catalysts for hydrogenation and Olefin Polymerization  

DOE Patents [OSTI]

Novel heterogeneous catalysts for the which hydrogenation of olefins and arenes with high conversion rates under ambient conditions and the polymerization of olefins have been developed. The catalysts are synthesized from Ziegler-type precatalysts by supporting them on sulfate-modified zirconia.

Marks, Tobin J. (Evanston, IL); Ahn, Hongsang (Evanston, IL)

2001-01-01T23:59:59.000Z

453

NOVEL SLURRY PHASE DIESEL CATALYSTS FOR COAL-DERIVED SYNGAS  

SciTech Connect (OSTI)

This report describes research conducted to support the DOE program in novel slurry phase catalysts for converting coal-derived synthesis gas to diesel fuels. The primary objective of this research program is to develop attrition resistant catalysts that exhibit high activities for conversion of coal-derived syngas.

Dr. Dragomir B. Bukur; Dr. Ketil Hanssen; Alec Klinghoffer; Dr. Lech Nowicki; Patricia O'Dowd; Dr. Hien Pham; Jian Xu

2001-01-07T23:59:59.000Z

454

Improving Best Air Conditioner Efficiency by 20-30% through a High Efficiency Fan and Diffuser Stage Coupled with an Evaporative Condenser Pre-Cooler  

SciTech Connect (OSTI)

The Florida Solar Energy Center (FSEC) conducted a research project to improve the best residential air conditioner condenser technology currently available on the market by retrofitting a commercially-available unit with both a high efficiency fan system and an evaporative pre-cooler. The objective was to integrate these two concepts to achieve an ultra-efficient residential air conditioner design. The project produced a working prototype that was 30% more efficient compared to the best currently-available technologies; the peak the energy efficiency ratio (EER) was improved by 41%. Efficiency at the Air-Conditioning and Refrigeration Institute (ARI) standard B-condition which is used to estimate seasonal energy efficiency ratio (SEER), was raised from a nominal 21 Btu/Wh to 32 Btu/Wh.

Parker, Danny S; Sherwin, John R; Raustad, Richard

2014-04-10T23:59:59.000Z

455

Effectiveness of Diesel Oxidation Catalyst in Reducing HC and CO Emissions from Reactivity Controlled Compression Ignition  

SciTech Connect (OSTI)

Reactivity Controlled Compression Ignition (RCCI) has been shown to allow for diesel-like or better brake thermal efficiency with significant reductions in nitrogen oxide (NOX) particulate matter (PM) emissions. Hydrocarbon (HC) and carbon monoxide (CO) emission levels, on the other hand, are similar to those of port fuel injected gasoline engines. The higher HC and CO emissions combined with the lower exhaust temperatures with RCCI operation present a challenge for current exhaust aftertreatments. The reduction of HC and CO emissions in a lean environment is typically achieved with an oxidation catalyst. In this work, several diesel oxidation catalysts (DOC) with different precious metal loadings were evaluated for effectiveness to control HC and CO emissions from RCCI combustion in a light-duty multi-cylinder engine operating on gasoline and diesel fuels. Each catalyst was evaluated in a steady-state engine operation with temperatures ranging from 160 to 260 C. A shift to a higher light-off temperature was observed during the RCCI operation. In addition to the steady-state experiments, the performances of the DOCs were evaluated during multi-mode engine operation by switching from diesel-like combustion at higher exhaust temperature and low HC/CO emissions to RCCI combustion at lower temperature and higher HC/CO emissions. High CO and HC emissions from RCCI generated an exotherm keeping the catalyst above the light-off temperature.

Prikhodko, Vitaly Y [ORNL; Curran, Scott [ORNL; Parks, II, James E [ORNL; Wagner, Robert M [ORNL

2013-01-01T23:59:59.000Z

456

Highly efficient inverted organic solar cells using amino acid modified indium tin oxide as cathode  

SciTech Connect (OSTI)

In this paper, we report that highly efficient inverted organic solar cells were achieved by modifying the surface of indium tin oxide (ITO) using an amino acid, Serine (Ser). With the modification of the ITO surface, device efficiency was significantly enhanced from 0.63% to 4.17%, accompanied with an open circuit voltage (Voc) that was enhanced from 0.30?V to 0.55?V. Ultraviolet and X-ray photoelectron spectroscopy studies indicate that the work function reduction induced by the amino acid modification resulting in the decreased barrier height at the ITO/organic interface played a crucial role in the enhanced performances.

Li, Aiyuan; Nie, Riming; Deng, Xianyu, E-mail: xydeng@hitsz.edu.cn [Research Center for Advanced Functional Materials and Devices, Shenzhen Key Laboratory of Advanced Materials, School of Materials Science and Engineering, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055 (China); Wei, Huaixin; Li, Yanqing; Tang, Jianxin [Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123 (China); Zheng, Shizhao; Wong, King-Young [Department of Physics, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong (China)

2014-03-24T23:59:59.000Z

457

Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic...  

Broader source: Energy.gov (indexed) [DOE]

Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts Ultra-efficient, Robust and Well-defined Nano-Array based Monolithic Catalysts This presentation...

458

Light Trapping for High Efficiency Heterojunction Crystalline Si Solar Cells: Preprint  

SciTech Connect (OSTI)

Light trapping plays an important role to achieve high short circuit current density (Jsc) and high efficiency for amorphous/crystalline Si heterojunction solar cells. Si heterojunction uses hydrogenated amorphous Si for emitter and back contact. This structure of solar cell posses highest open circuit voltage of 0.747 V at one sun for c-Si based solar cells. It also suggests that over 25% record-high efficiency is possible with further improvement of Jsc. Light trapping has two important tasks. The first one is to reduce the surface reflectance of light to zero for the solar spectrum that Si has a response. The second one is to increase the effective absorption length to capture all the photon. For Si heterojunction solar cell, surface texturing, anti-reflectance indium tin oxides (ITO) layer at the front and back are the key area to improve the light trapping.

Wang, Q.; Xu, Y.; Iwaniczko, E.; Page, M.

2011-04-01T23:59:59.000Z

459

Evaluation of high-energy-efficiency powertrain approaches: the 1996 futurecar challenge  

SciTech Connect (OSTI)

Twelve colleges and universities were selected to design, build, and develop a mid-size vehicle that could achieve high energy economy while maintaining the performance characteristics of today`s mid-size vehicle. Many of the teams were able to increase the fuel economy of their vehicles, but most of these increases came at the expense of decreased performance or worsened emissions. This paper evaluates and summarizes the high-energy-efficiency powertrain technology approaches that were utilized in the 1996 FutureCar Challenge, which was the first evaluation of these vehicles in a two-year program. Of the 11 vehicles evaluated in the competition, nine utilized hybrid electric vehicle approaches. This paper discusses the design trade- offs made by the teams to achieve high efficiency while trying to maintain stock performance.

Sluder, S.; Duoba, M.; Larsen, R.

1997-02-01T23:59:59.000Z

460

Development of Sulfur and Carbon Tolerant Reforming Alloy Catalysts Aided Fundamental Atomistic Insights  

SciTech Connect (OSTI)

Current hydrocarbon reforming catalysts suffer from rapid carbon and sulfur poisoning. Even though there is a tremendous incentive to develop more efficient catalysts, these materials are currently formulated using inefficient trial and error experimental approaches. We have utilized a hybrid experimental/theoretical approach, combining quantum Density Functional Theory (DFT) calculations and various state-of-the-art experimental tools, to formulate carbon tolerant reforming catalysts. We have employed DFT calculations to develop molecular insights into the elementary chemical transformations that lead to carbon poisoning of Ni catalysts. Based on the obtained molecular insights, we have identified, using DFT quantum calculation, various Ni alloy catalysts as potential carbon tolerant reforming catalysts. The alloy catalysts were synthesized and tested in steam reforming and partial oxidation of methane, propane, and isooctane. We demonstrated that the alloy catalysts are much more carbon-tolerant than monometallic Ni catalysts under nearly stoichiometric steam-to-carbon ratios. Under these conditions, monometallic Ni is rapidly poisoned by sp2 carbon deposits. The research approach is distinguished by two characteristics: (a) knowledge-based, bottomup approach, compared to the traditional trial and error approach, allows for a more efficient and systematic discovery of improved catalysts. (b) the focus is on exploring alloy materials which have been largely unexplored as potential reforming catalysts.

Suljo Linic

2008-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

High-Efficiency and High-Power CMOS Power Amplifiers for Millimeter-Wave Applications /  

E-Print Network [OSTI]

K. Han, “W-band, 5W Solid-State Power Amplifier/Combiner,”materials have made high-power solid-state power amplifiersCMOS RF power amplifier for GSM-EDGE,” IEEE J. Solid-State

Agah, Amir

2013-01-01T23:59:59.000Z

462

Supported organoiridium catalysts for alkane dehydrogenation  

DOE Patents [OSTI]

Solid supported organoiridium catalysts, a process for preparing such solid supported organoiridium catalysts, and the use of such solid supported organoiridium catalysts in dehydrogenation reactions of alkanes is provided. The catalysts can be easily recovered and recycled.

Baker, R. Thomas; Sattelberger, Alfred P.; Li, Hongbo

2013-09-03T23:59:59.000Z

463

Asynchronous and Multiprecision Linear Solvers - Scalable and Fault-Tolerant Numerics for Energy Efficient High Performance Computing.  

E-Print Network [OSTI]

??Asynchronous methods minimize idle times by removing synchronization barriers, and therefore allow the efficient usage of computer systems. The implied high tolerance with respect to… (more)

Anzt, Hartwig

2012-01-01T23:59:59.000Z

464

Fundamental studies of hydrogen interaction with supported meta and bimetallic catalysts  

SciTech Connect (OSTI)

The thesis is divided into 3 parts: interaction of H with silica supported Ru catalysts (high pressure in situ NMR), in situ NMR study of H interaction with supported Ru-group IB bimetallic catalysts, and in-situ NMR study of H effects on silica-supported Pt, Rh and Ru catalysts.

Bhatia, S.

1993-12-07T23:59:59.000Z

465

ENI Renewable and Non-conventional Energy Prize 2012 High-efficiency solar cells based on nanophotonic design  

E-Print Network [OSTI]

new solar cell designs that enable both a higher photovoltaic conversion efficiency and reduced) Photonic design principles for ultrahigh-efficiency photovoltaics, A. Polman and H.A. Atwater, Nature MaterENI Renewable and Non-conventional Energy Prize 2012 High-efficiency solar cells based

Polman, Albert

466

Vanderbauwhede, W., Azzopardi, L. and Moadeli, M. (2009) FPGA-accelerated information retrieval: high-efficiency document filtering. In  

E-Print Network [OSTI]

efficient solutions for processing large amounts of data and information. Re- ducing the amount of energy is paramount. Therefore, our aim is to filter documents efficiently in terms of both time and energy: high-efficiency document filtering. In: International Conference on Field Programmable Logic

Azzopardi, Leif

467

Phase II Final Project Report SBIR Project: "A High Efficiency PV to Hydrogen Energy System"  

SciTech Connect (OSTI)

The innovative research conducted for this project contributed greatly to the understanding of generating low-cost hydrogen from solar energy. The project’s research identified two highly leveraging and complementary pathways. The first pathway is to dramatically increase the efficiency of converting sunlight into electricity. Improving solar electric conversion efficiency directly increases hydrogen production. This project produced a world record efficiency for silicon solar cells and contributed to another world record efficiency for a solar concentrator module using multijunction solar cells. The project’s literature review identified a second pathway in which wasted heat from the solar concentration process augments the electrolysis process generating hydrogen. One way to do this is to use a “heat mirror” that reflects the heat-producing infrared and transmits the visible spectrum to the solar cells; this also increases solar cell conversion efficiency. An economic analysis of this concept confirms that, if long-term concentrator photovoltaic (CPV) and solid-oxide electrolyzer cost goals can be achieved, hydrogen will be produced from solar energy cheaper than the cost of gasoline. The potential public benefits from this project are significant. The project has identified a potential energy source for the nation’s future electricity and transportation needs that is entirely “home grown” and carbon free. As CPV enter the nation’s utility markets, the opportunity for this approach to be successful is greatly increased. Amonix strongly recommends further exploration of this project’s findings.

Slade, A; Turner, J; Stone, K; McConnell, R

2008-09-02T23:59:59.000Z

468

High efficiency multilayer blazed gratings for EUV and soft X-rays: Recent developments  

SciTech Connect (OSTI)

Multilayer coated blazed gratings with high groove density are the best candidates for use in high resolution EUV and soft x-ray spectroscopy. Theoretical analysis shows that such a grating can be potentially optimized for high dispersion and spectral resolution in a desired high diffraction order without significant loss of diffraction efficiency. In order to realize this potential, the grating fabrication process should provide a perfect triangular groove profile and an extremely smooth surface of the blazed facets. Here we report on recent progress achieved at the Advanced Light Source (ALS) in fabrication of high quality multilayer coated blazed gratings. The blazed gratings were fabricated using scanning beam interference lithography followed by wet anisotropic etching of silicon. A 200 nm period grating coated with a Mo/Si multilayer composed with 30 bi-layers demonstrated an absolute efficiency of 37.6percent in the 3rd diffraction order at 13.6 nm wavelength. The groove profile of the grating was thoroughly characterized with atomic force microscopy before and after the multilayer deposition. The obtained metrology data were used for simulation of the grating efficiency with the vector electromagnetic PCGrate-6.1 code. The simulations showed that smoothing of the grating profile during the multilayer deposition is the main reason for efficiency losses compared to the theoretical maximum. Investigation of the grating with cross-sectional transmission electron microscopy revealed a complex evolution of the groove profile in the course of the multilayer deposition. Impact of the shadowing and smoothing processes on growth of the multilayer on the surface of the sawtooth substrate is discussed.

Voronov, Dmitriy; Ahn, Minseung; Anderson, Erik; Cambie, Rossana; Chang, Chih-Hao; Goray, Leonid; Gullikson, Eric; Heilmann, Ralf; Salmassi, Farhad; Schattenburg, Mark; Warwick, Tony; Yashchuk, Valeriy; Padmore, Howard

2011-07-26T23:59:59.000Z

469

High Efficiency Solar-based Catalytic Structure for CO{sub 2} Reforming  

SciTech Connect (OSTI)

Throughout this project, we developed and optimized various photocatalyst structures for CO{sub 2} reforming into hydrocarbon fuels and various commodity chemical products. We also built several closed-loop and continuous fixed-bed photocatalytic reactor system prototypes for a larger-scale demonstration of CO{sub 2} reforming into hydrocarbons, mainly methane and formic acid. The results achieved have indicated that with each type of reactor and structure, high reforming yields can be obtained by refining the structural and operational conditions of the reactor, as well as by using various sacrificial agents (hole scavengers). We have also demonstrated, for the first time, that an aqueous solution containing acid whey (a common bio waste) is a highly effective hole scavenger for a solar-based photocatalytic reactor system and can help reform CO{sub 2} into several products at once. The optimization tasks performed throughout the project have resulted in efficiency increase in our conventional reactors from an initial 0.02% to about 0.25%, which is 10X higher than our original project goal. When acid whey was used as a sacrificial agent, the achieved energy efficiency for formic acid alone was ~0.4%, which is 16X that of our original project goal and higher than anything ever reported for a solar-based photocatalytic reactor. Therefore, by carefully selecting sacrificial agents, it should be possible to reach energy efficiency in the range of the photosynthetic efficiency of typical crop and biofuel plants (1-3%).

Menkara, Hisham

2013-09-30T23:59:59.000Z

470

NEW OPTIMAL HIGH EFFICIENCY DSP-BASED DIGITAL CONTROLLER DESIGN FOR SUPER HIGH-SPEED PERMANENT  

E-Print Network [OSTI]

magnet synchronous motors (PMSM). The PMSMs are a key component for the miniaturic cryocooler of a super high-speed PMSM is an important issue particularly for open-loop control, given that PMSM-speed PMSM is analyzed and some design suggestions are given to maximize this parameter. For ordinary motors

Wu, Thomas

471

High Efficiency m-plane LEDs on Low Defect Density Bulk GaN Substrates  

SciTech Connect (OSTI)

Solid-state lighting is a key technology for reduction of energy consumption in the US and worldwide. In principle, by replacing standard incandescent bulbs and other light sources with sources based on light-emitting diodes (LEDs), ultimate energy efficiency can be achieved. The efficiency of LEDs has improved tremendously over the past two decades, however further progress is required for solid- state lighting to reach its full potential. The ability of an LED at converting electricity to light is quantified by its internal quantum efficiency (IQE). The material of choice for visible LEDs is Gallium Nitride (GaN), which is at the basis of blue-emitting LEDs. A key factor limiting the performance of GaN LEDs is the so-called efficiency droop, whereby the IQE of the LED decreases significantly at high current density. Despite decades of research, efficiency droop remains a major issue. Since high-current operation is necessary for practical lighting applications, reducing droop is a major challenge for the scientific community and the LED industry. Our approach to solving the droop issue is the use of newly available low-defect-density bulk GaN non-polar substrates. In contrast to the standard foreign substrates (sapphire, silicon carbide, silicon) used in the industry, we have employed native bulk GaN substrates with very low defect density, thus ensuring exquisite material quality and high IQE. Whereas all commercial LEDs are grown along the c-plane crystal direction of GaN, we have used m-plane non-polar substrates; these drastically modify the physical properties of the LED and enable a reduction of droop. With this approach, we have demonstrated very high IQE performance and low droop. Our results focused on violet and blue LEDs. For these, we have demonstrated very high peak IQEs and current droops of 6% and 10% respectively (up to a high current density of 200A.cm-2). All these results were obtained under electrical operation. These high IQE and low droop values are in line with the program’s milestones. They demonstrate that bulk non-polar GaN substrates represent a disruptive technology for LED performance. Application of this technology to real-world products is feasible, provided that the cost of GaN substrates is compatible with the market’s requirement.

David, Aurelien

2012-10-15T23:59:59.000Z

472

Process of making supported catalyst  

DOE Patents [OSTI]

Oxide supported metal catalysts have an additional metal present in intimate association with the metal catalyst to enhance catalytic activity. In a preferred mode, iridium or another Group VIII metal catalyst is supported on a titania, alumina, tungsten oxide, silica, or composite oxide support. Aluminum ions are readsorbed onto the support and catalyst, and reduced during calcination. The aluminum can be added as aluminum nitrate to the iridium impregnate solution, e.g. chloroiridic acid.

Schwarz, James A. (Fayetteville, NY); Subramanian, Somasundaram (Melvindale, MI)

1992-01-01T23:59:59.000Z

473

Simulation of a High Efficiency Multi-bed Adsorption Heat Pump  

SciTech Connect (OSTI)

Attaining high energy efficiency with adsorption heat pumps is challenging due to thermodynamic losses that occur when the sorbent beds are thermally cycled without effective heat recuperation. The multi-bed concept described here effectively transfers heat from beds being cooled to beds being heated, which enables high efficiency in thermally driven heat pumps. A simplified lumped-parameter model and detailed finite element analysis are used to simulate the performance of an ammonia-carbon sorption compressor, which is used to project the overall heat pump coefficient of performance. The effects of bed geometry and number of beds on system performance are explored, and the majority of the performance benefit is obtained with four beds. Results indicate that a COP of 1.24 based on heat input is feasible at AHRI standard test conditions for residential HVAC equipment. When compared on a basis of primary energy input, performance equivalent to SEER 13 or 14 are theoretically attainable with this system.

TeGrotenhuis, Ward E.; Humble, Paul H.; Sweeney, J. B.

2012-05-01T23:59:59.000Z

474

Numerical simulation: Toward the design of high-efficiency planar perovskite solar cells  

SciTech Connect (OSTI)

Organo-metal halide perovskite solar cells based on planar architecture have been reported to achieve remarkably high power conversion efficiency (PCE, >16%), rendering them highly competitive to the conventional silicon based solar cells. A thorough understanding of the role of each component in solar cells and their effects as a whole is still required for further improvement in PCE. In this work, the planar heterojunction-based perovskite solar cells were simulated with the program AMPS (analysis of microelectronic and photonic structures)-1D. Simulation results revealed a great dependence of PCE on the thickness and defect density of the perovskite layer. Meanwhile, parameters including the work function of the back contact as well as the hole mobility and acceptor density in hole transport materials were identified to significantly influence the performance of the device. Strikingly, an efficiency over 20% was obtained under the moderate simulation conditions.

Liu, Feng; Zhu, Jun, E-mail: zhujzhu@gmail.com, E-mail: sydai@ipp.ac.cn; Wei, Junfeng; Li, Yi; Lv, Mei [Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Yang, Shangfeng [Hefei National Laboratory for Physical Sciences at Microscale, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China); Zhang, Bing; Yao, Jianxi [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206 (China); Dai, Songyuan, E-mail: zhujzhu@gmail.com, E-mail: sydai@ipp.ac.cn [Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206 (China)

2014-06-23T23:59:59.000Z

475

Field test of a high-efficiency, automatic-defrost refrigerator-freezer  

SciTech Connect (OSTI)

Following the successful design, development, and demonstration of a high efficiency refrigerator-freezer prototype, work was done to design and manufacture pre-production units for home usage tests. The purpose of the field test and the associated market evaluation is to confirm the energy saving potential of the high-efficiency design, identify possible design deficiencies or service difficulties, and assess the consumer appeal of the new unit. The first five months of field test data have shown an average 57% decrease in energy consumption when compared to a baseline unit of convention design. This energy savings is larger than predicted by the standard DOE test procedure. No serious design or service problems have been encountered. Consumers have not been adversely affected by the larger cabinet and thicker doors, and responded favorably in an actual retail sales test to initially spending more for an energy-saving refrigerator that will reduce electric usage.

Topping, R.F.; Vineyard, E.A.

1982-01-01T23:59:59.000Z

476

Ongoing Commissioning of a high efficiency supermarket with a ground coupled carbon dioxide refrigeration plant  

E-Print Network [OSTI]

Ongoing Commissioning of a high efficiency supermarket with a ground coupled carbon dioxide refrigeration plant Nicolas R?hault 1 and Doreen Kalz 2 1 Fraunhofer Institute for Solar Energy Systems, Freiburg, Germany 2 Fraunhofer Institute... for Solar Energy Systems, Freiburg, Germany Email: nicolas.rehault@ise.fraunhofer.de Abstract: A significant reduction in the energy consumption and greenhouse gas emissions of supermarkets can be reached by the combination of several innovative...

Rehault, N.; Kalz, D.

2012-01-01T23:59:59.000Z

477

Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission Engines  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of Energy Low-Temperature Combustion Demonstrator for High-Efficiency Clean|

478

High Efficient Clean Combustion for SuperTruck | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii CleanHeatinHigh Efficiency| -

479

Field test of a high efficiency, automatic defrost refrigerator-freezer  

SciTech Connect (OSTI)

This paper describes the market evaluation and field test portion of a program to design, develop, and demonstrate a high efficiency, automatic defrosting refrigerator-freezer for the residential market. After the successful completion of Phase I of the program, which concentrated on the design, construction, and laboratory testing of a 453 1 (16 ft/sup 3/) high-efficiency refrigerator-freezer prototype, Phase II was initiated in February 1979 to evaluate the sales potential and performance of the high-efficiency refrigerator concept under field conditions, as a necessary step in creating a product that was both manufacturable and marketable. In Phase I, a survey of food consumption and storage trends, family size, and consumer buying habits led to a sales-weighted average-capacity forecast for 1985 of approximately 453 1 (16 ft/sup 3/) and identification of the top-mount, automatic defrosting refrigerator as the projected sales leader. To meet this market demand, a 453 1 (16 ft/sup 3/) top-mount was selected as the baseline for the Phase I design and development. In Phase II, a 509 1 (18 ft/sup 3/) unit using Phase I technology was chosen for the field test, since the slightly larger model better fit the participating manufacturer's new product development efforts and market.

Topping, R.F.; Vineyard, E.A.

1982-01-01T23:59:59.000Z

480

Interfacial Engineering for Highly Efficient-Conjugated Polymer-Based Bulk Heterojunction Photovoltaic Devices  

SciTech Connect (OSTI)

The aim of our proposal is to apply interface engineering approach to improve charge extraction, guide active layer morphology, improve materials compatibility, and ultimately allow the fabrication of high efficiency tandem cells. Specifically, we aim at developing: i. Interfacial engineering using small molecule self-assembled monolayers ii. Nanostructure engineering in OPVs using polymer brushes iii. Development of efficient light harvesting and high mobility materials for OPVs iv. Physical characterization of the nanostructured systems using electrostatic force microscopy, and conducting atomic force microscopy v. All-solution processed organic-based tandem cells using interfacial engineering to optimize the recombination layer currents vi. Theoretical modeling of charge transport in the active semiconducting layer The material development effort is guided by advanced computer modeling and surface/ interface engineering tools to allow us to obtain better understanding of the effect of electrode modifications on OPV performance for the investigation of more elaborate device structures. The materials and devices developed within this program represent a major conceptual advancement using an integrated approach combining rational molecular design, material, interface, process, and device engineering to achieve solar cells with high efficiency, stability, and the potential to be used for large-area roll-to-roll printing. This may create significant impact in lowering manufacturing cost of polymer solar cells for promoting clean renewable energy use and preventing the side effects from using fossil fuels to impact environment.

Alex Jen; David Ginger; Christine Luscombe; Hong Ma

2012-04-02T23:59:59.000Z

Note: This page contains sample records for the topic "highly efficient catalyst" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Cost Effective, High Efficiency Integrated Systems Approach To Auxiliary Electric Motors  

SciTech Connect (OSTI)

The CARAT program, carried out by Kinetic Art & Technology Corporation (KAT), has been one of the most commercially successful KAT R&D programs to date. Based on previous development of its technology, KAT designed, constructed and tested a highly efficient motor and controller system under this CARAT program with supplemental commercial funding. Throughout this CARAT effort, the technical objectives have been refined and refocused. Some objectives have been greatly expanded, while others have been minimized. The determining factor in all decisions to refocus the objectives was the commercial need, prima