National Library of Energy BETA

Sample records for higher ethanol blends

  1. Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Mixtures of ethanol, gasoline, and higher alcohols were evaluated to determine if they offer superior performance to ethanol/gasoline blends in meeting the Renewal Fuels Standard II. PDF icon deer12_ickes.pdf More Documents & Publications Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Drop In Fuels: Where the Road Leads

  2. Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the US today and the potential impact of ethanol on gasoline prices at higher blending concentrations.

  3. Alternative Fuels Data Center: Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blends to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blends on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blends on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blends on Google Bookmark Alternative Fuels Data Center: Ethanol Blends on Delicious Rank Alternative Fuels Data Center: Ethanol Blends on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blends on AddThis.com... More in this section... Ethanol Basics Blends E15

  4. Fact Sheet: Effects of Intermediate Ethanol Blends | Department...

    Broader source: Energy.gov (indexed) [DOE]

    initiated a test program to assess the potential impacts of higher intermediate ethanol blends on conventional vehicles and other engines that rely on gasoline. The test program ...

  5. Low-Level Ethanol Fuel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    This fact sheet addresses: (a) why Clean Cities promotes ethanol blends; (b) how these blends affect emissions; (c) fuel performance and availability; and (d) cost, incentives, and regulations.

  6. Vehicle Technologies Office: Intermediate Ethanol Blends

    Broader source: Energy.gov [DOE]

    Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy...

  7. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and ...

  8. EffectsIntermediateEthanolBlends.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Mid-Level Ethanol Blends Test ...

  9. Vehicle Technologies Office: Intermediate Ethanol Blends | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Intermediate Ethanol Blends Vehicle Technologies Office: Intermediate Ethanol Blends Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy Policy Act of 2005 and the Energy Security and Independence Act of 2007) requires the country use as much as 36 billion gallons of renewable fuels annually by 2022, most of which will be ethanol. However,

  10. Mid-Level Ethanol Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Level Ethanol Blends Mid-Level Ethanol Blends 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ft_05_knoll.pdf More Documents & Publications Mid-Level Ethanol Blends Test Program Biofuels Quality Surveys Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

  11. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  12. The Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    none,

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the United States today and the potential impact of ethanol on gasoline prices at higher blending concentrations (10%, 15% and 20% of the total U.S. gasoline consumption).

  13. Investigation of Knock limited Compression Ratio of Ethanol Gasoline Blends

    SciTech Connect (OSTI)

    Szybist, James P; Youngquist, Adam D; Wagner, Robert M; Moore, Wayne; Foster, Matthew; Confer, Keith

    2010-01-01

    Ethanol offers significant potential for increasing the compression ratio of SI engines resulting from its high octane number and high latent heat of vaporization. A study was conducted to determine the knock limited compression ratio of ethanol gasoline blends to identify the potential for improved operating efficiency. To operate an SI engine in a flex fuel vehicle requires operating strategies that allow operation on a broad range of fuels from gasoline to E85. Since gasoline or low ethanol blend operation is inherently limited by knock at high loads, strategies must be identified which allow operation on these fuels with minimal fuel economy or power density tradeoffs. A single cylinder direct injection spark ignited engine with fully variable hydraulic valve actuation (HVA) is operated at WOT conditions to determine the knock limited compression ratio (CR) of ethanol fuel blends. The geometric compression ratio is varied by changing pistons, producing CR from 9.2 to 13.66. The effective CR is varied using an electro-hydraulic valvetrain that changed the effective trapped displacement using both Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC). The EIVC and LIVC strategies result in effective CR being reduced while maintaining the geometric expansion ratio. It was found that at substantially similar engine conditions, increasing the ethanol content of the fuel results in higher engine efficiency and higher engine power. These can be partially attributed to a charge cooling effect and a higher heating valve of a stoichiometric mixture for ethanol blends (per unit mass of air). Additional thermodynamic effects on and a mole multiplier are also explored. It was also found that high CR can increase the efficiency of ethanol fuel blends, and as a result, the fuel economy penalty associated with the lower energy content of E85 can be reduced by about a third. Such operation necessitates that the engine be operated in a de-rated manner for gasoline, which is knock-prone at these high CR, in order to maintain compatibility. By using EIVC and LIVC strategies, good efficiency is maintained with gasoline, but power is reduced by about 34%.

  14. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll Brian West Wendy Clark...

  15. Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) to someone by E-mail Share Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Facebook Tweet about Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and

  16. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon blend stock does impact engine performance, there remains a significant opportunity for engine optimization when considering even the lowest octane fuels that are in compliance with the current revision of ASTM D5798 compared to premium-grade gasoline.

  17. Table B1. Pipe Manufacturer Compatibility with Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    B1. Pipe Manufacturer Compatibility with Ethanol Blends Manufacturer Product Model Ethanol Compatibility Piping-All Companies have UL 971 listing for E100 Advantage Earth Products Piping 1.5", 2", 3", 4" E0-E100 Brugg Piping FLEXWELL-HL, SECON-X, NITROFLEX, LPG E0-E100 Franklin Fueling Piping Franklin has third-party certified piping compatible with up to E85. Contact manufacturer for specific part numbers. E0-E85 OPW Piping FlexWorks, KPS, Pisces (discontinued) E0-E100 NOV

  18. High-Octane Mid-Level Ethanol Blend Market Assessment

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    High-Octane Mid-Level Ethanol Blend Market Assessment Caley Johnson, Emily Newes, Aaron Brooker, and Robert McCormick National Renewable Energy Laboratory Steve Peterson Lexidyne, LLC Paul Leiby, Rocio Uria Martinez, and Gbadebo Oladosu Oak Ridge National Laboratory Maxwell L. Brown Colorado School of Mines Technical Report NREL/TP-5400-63698 December 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance

  19. Technical Issues Associated With the Use of Intermediate Ethanol Blends (>E10) in the U.S. Legacy Fleet

    SciTech Connect (OSTI)

    Rich, Bechtold; Thomas, John F; Huff, Shean P; Szybist, James P; West, Brian H; Theiss, Timothy J; Timbario, Tom; Goodman, Marc

    2007-08-01

    The Oak Ridge National Laboratory (ORNL) supports the U.S. Department of Energy (DOE) in assessing the impact of using intermediate ethanol blends (E10 to E30) in the legacy fleet of vehicles in the U.S. fleet. The purpose of this report is to: (1) identify the issues associated with intermediate ethanol blends with an emphasis on the end-use or vehicle impacts of increased ethanol levels; (2) assess the likely severity of the issues and whether they will become more severe with higher ethanol blend levels, or identify where the issue is most severe; (3) identify where gaps in knowledge exist and what might be required to fill those knowledge gaps; and (4) compile a current and complete bibliography of key references on intermediate ethanol blends. This effort is chiefly a critical review and assessment of available studies. Subject matter experts (authors and selected expert contacts) were consulted to help with interpretation and assessment. The scope of this report is limited to technical issues. Additional issues associated with consumer, vehicle manufacturer, and regulatory acceptance of ethanol blends greater than E10 are not considered. The key findings from this study are given.

  20. Effects of intermediate ethanol blends on legacy vehicles and small non-road engines, report 1

    SciTech Connect (OSTI)

    West, Brian; Knoll, Keith; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2008-10-01

    Report on the test program to assess the viability of using intermediate ethanol blends as a contributor to meeting national goals in the use of renewable fuels.

  1. Evaluation of Ethanol Blends for PHEVs using Simulation andEngine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop Evaluation of Ethanol ... Program Annual Merit Review and Peer Evaluation PDF icon vss049shidore2011o.pdf More ...

  2. Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends

    SciTech Connect (OSTI)

    Storey, John Morse; Barone, Teresa L; Thomas, John F; Huff, Shean P

    2012-01-01

    Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

  3. Table A1: Tank Manufacturer Compatibility with Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    A1: Tank Manufacturer Compatibility with Ethanol Blends E10 E100 E10 E100 Manufacturer ✔ ✔ Continued from below FIBERGLASS a Highland Tank ✔ ✔ Containment Solutions ✔ ✔ J.L. Houston Co. ✔ ✔ Owens Corning (single wall 1965-1994) ✔ ✘ Kennedy Tank and Manufacturing Co., Inc. ✔ ✔ Owens Corning (double wall 1965- July 1, 1990) ✔ ✘ Lancaster Tanks and Steel Products ✔ ✔ Owens Corning (double wall July 2, 1990-December 31, 1994) ✔ ✔ Lannon Tank Corporation ✔ ✔

  4. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However, the strength of the secondary flow is found nearly the same behind the first and the second vortex generator pair as well as far from the second vortex generator pair in the case of Duct2. Both ducts are able to create a counter-rotating and a second set of twin foci. Duct2 is able to create the second set of twin foci in an earlier streamwise location than Duct1, as these foci are well-known to their heat transfer augmentation. A larger vortex formation area and a greater induced vorticity field between vortex pairs are observed for Duct2 compared with Duct1. As the induced flow field between the vortex pairs increases the heat transfer, and as the flow field between the vortex cores is found larger in the case of Duct2, therefore, it is expected to obtain better heat transfer characteristics for Duct2 compared with Duct1. (author)

  5. JV Task 112-Optimal Ethanol Blend-Level Investigation

    SciTech Connect (OSTI)

    Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

    2008-01-31

    Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

  6. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends (Book)

    SciTech Connect (OSTI)

    Moriarty, K.

    2013-09-01

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  7. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends

    SciTech Connect (OSTI)

    2013-09-17

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  8. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

    Broader source: Energy.gov [DOE]

    Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

  9. Investigation of critical equivalence ratio and chemical speciation in flames of ethylbenzene-ethanol blends

    SciTech Connect (OSTI)

    Therrien, Richard J.; Ergut, Ali; Levendis, Yiannis A.; Richter, Henning; Howard, Jack B.; Carlson, Joel B.

    2010-02-15

    This work investigates five different one-dimensional, laminar, atmospheric pressure, premixed ethanol/ethylbenzene flames (0%, 25%, 50%, 75% and 90% ethanol by weight) at their soot onset threshold ({phi}{sub critical}). Liquid ethanol/ethylbenzene mixtures were pre-vaporized in nitrogen, blended with an oxygen-nitrogen mixture and, upon ignition, burned in premixed one-dimensional flames at atmospheric pressure. The flames were controlled so that each was at its visual soot onset threshold, and all had similar temperature profiles (determined by thermocouples). Fixed gases, light volatile hydrocarbons, polycyclic aromatic hydrocarbons (PAH), and oxygenated aromatic hydrocarbons were directly sampled at three locations in each flame. The experimental results were compared with a detailed kinetic model, and the modeling results were used to perform a reaction flux analysis of key species. The critical equivalence ratio was observed to increase in a parabolic fashion as ethanol concentration increased in the fuel mixture. The experimental results showed increasing trends of methane, ethane, and ethylene with increasing concentrations of ethanol in the flames. Carbon monoxide was also seen to increase significantly with the increase of ethanol in the flame, which removes carbon from the PAH and soot formation pathways. The PAH and oxygenated aromatic hydrocarbon values were very similar in the 0%, 25% and 50% ethanol flames, but significantly lower in the 75% and 90% ethanol flames. These results were in general agreement with the model and were reflected by the model soot predictions. The model predicted similar soot profiles for the 0%, 25% and 50% ethanol flames, however it predicted significantly lower values in the 75% and 90% ethanol flames. The reaction flux analysis revealed benzyl to be a major contributor to single and double ring aromatics (i.e., benzene and naphthalene), which was identified in a similar role in nearly sooting or highly sooting ethylbenzene flames. The presence of this radical was significantly reduced as ethanol concentration was increased in the flames, and this effect in combination with the lower carbon to oxygen ratios and the enhanced formation of carbon monoxide, are likely what allowed higher equivalence ratios to be reached without forming soot. (author)

  10. Ethanol Blend Effects On Direct Injection Spark-Ignition Gasoline Vehicle Particulate Matter Emissions

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Barone, Teresa L

    2010-01-01

    Direct injection spark-ignition (DISI) gasoline engines can offer better fuel economy and higher performance over their port fuel-injected counterparts, and are now appearing increasingly in more U.S. vehicles. Small displacement, turbocharged DISI engines are likely to be used in lieu of large displacement engines, particularly in light-duty trucks and sport utility vehicles, to meet fuel economy standards for 2016. In addition to changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the 10% allowed by current law due to the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA). In this study, we present the results of an emissions analysis of a U.S.-legal stoichiometric, turbocharged DISI vehicle, operating on ethanol blends, with an emphasis on detailed particulate matter (PM) characterization. Gaseous species, particle mass, and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. For the gaseous species and particle mass measurements, dilution was carried out using a full flow constant volume sampling system (CVS). For the particle number concentration and size distribution measurements, a micro-tunnel dilution system was employed. The vehicles were fueled by a standard test gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. During steady-state operation, the geometric mean diameter of the particle-number size distribution remained approximately the same (50 nm) but the particle number concentration decreased with increasing ethanol content in the fuel. In addition, increasing ethanol content significantly reduced the number concentration of 50 and 100 nm particles during gradual and WOT accelerations.

  11. Low and intermediate temperature oxidation of ethanol and ethanol-PRF blends: An experimental and modeling study

    SciTech Connect (OSTI)

    Haas, Francis M.; Chaos, Marcos; Dryer, Frederick L.

    2009-12-15

    In this brief communication, we present new experimental species profile measurements for the low and intermediate temperature oxidation of ethanol under knock-prone conditions. These experiments show that ethanol exhibits no global low temperature reactivity at these conditions, although we note the heterogeneous decomposition of ethanol to ethylene and water. Similar behavior is reported for an E85 blend in n-heptane. Kinetic modeling results are presented to complement these experiments and elucidate the interaction of ethanol and primary reference fuels undergoing cooxidation. (author)

  12. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2009-02-01

    This report (February 2009) is an update of the original version, which was published in October 2008. This report is the result of the U.S. Department of Energy's test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels.

  13. Effects of Mid-Level Ethanol Blends on Conventional Vehicle Emissions

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Huff, S.; Thomas, J.; Orban, J.; Cooper, C.

    2010-06-01

    Tests were conducted in 2008 on 16 late-model conventional vehicles (1999-2007) to determine short-term effects of mid-level ethanol blends on performance and emissions. Vehicle odometer readings ranged from 10,000 to 100,000 miles, and all vehicles conformed to federal emissions requirements for their federal certification level. The LA92 drive cycle, also known as the Unified Cycle, was used for testing because it more accurately represents real-world acceleration rates and speeds than the Federal Test Procedure. Test fuels were splash-blends of up to 20 volume percent ethanol with federal certification gasoline. Both regulated and unregulated air-toxic emissions were measured. For the 16-vehicle fleet, increasing ethanol content resulted in reductions in average composite emissions of both nonmethane hydrocarbons and carbon monoxide and increases in average emissions of ethanol and aldehydes.

  14. Methanol/ethanol/gasoline blend-fuels demonstration with stratified-charge-engine vehicles: Consultant report. Final report

    SciTech Connect (OSTI)

    Pefley, R.; Adelman, H.; Suga, T.

    1980-03-01

    Four 1978 Honda CVCC vehicles have been in regular use by California Energy Commission staff in Sacramento for 12 months. Three of the unmodified vehicles were fueled with alcohol/gasoline blends (5% methanol, 10% methanol, and 10% ethanol) with the fourth remaining on gasoline as a control. The operators did not know which fuels were in the vehicles. At 90-day intervals the cars were returned to the Univerity of Santa Clara for servicing and for emissions and fuel economy testing in accordance with the Federal Test Procedures. The demonstration and testing have established the following: (1) the tested blends cause no significant degradation in exhaust emissions, fuel economy, and driveability; (2) the tested blends cause significant increases in evaporative emissions; (3) analysis of periodic oil samples shows no evidence of accelerated metal wear; and (4) higher than 10% alcohols will require substantial modification to most existing California motor vehicles for acceptable emissions, performance, and fuel economy. Many aspects of using methanol and ethanol fuels, both straight and in blends, in various engine technologies are discussed.

  15. Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst

    SciTech Connect (OSTI)

    Pihl, Josh A; Toops, Todd J; Fisher, Galen; West, Brian H

    2014-01-01

    Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

  16. Regulated and Unregulated Exhaust Emissions Comparison for Three Tier II Non-Road Diesel Engines Operating on Ethanol-Diesel Blends

    SciTech Connect (OSTI)

    Merritt, P. M.; Ulmet, V.; McCormick, R. L.; Mitchell, W. E.; Baumgard, K. J.

    2005-11-01

    Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent). Benzene emissions were reduced by up to 50 percent with the ethanol-blended fuels. Emissions of 1,3-butadiene were also substantially decreased, with reductions ranging from 24 to 82 percent. Isolated trends were noted for certain PAHs. There was a decrease in 1-nitropyrene with use of ethanol in all cases. Particulate phase 1-nitropyrene was reduced from 18 to 62 percent. There was also a general increase in the proportion of heavy PAHs in the particulate phase with ethanol use, and although less pronounced, a general decrease in light PAHs in the particulate phase.

  17. NMOG Emissions Characterization and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2012-01-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

  18. NMOG Emissions Characterizations and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2011-10-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

  19. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Clark, W.; Graves, R.; Orban, J.; Przesmitzki, S.; Theiss, T.

    2009-02-01

    Intended for policymakers and others who make decisions about, and set guidelines for, the proper use of intermediate ethanol blends such as E20 in both vehicle engines and other engine types.

  20. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  1. Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-01-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  2. Stripping ethanol from ethanol-blended fuels for use in NO.sub.x SCR

    DOE Patents [OSTI]

    Kass, Michael Delos; Graves, Ronald Lee; Storey, John Morse Elliot; Lewis, Sr., Samuel Arthur; Sluder, Charles Scott; Thomas, John Foster

    2007-08-21

    A method to use diesel fuel alchohol micro emulsions (E-diesel) to provide a source of reductant to lower NO.sub.x emissions using selective catalytic reduction. Ethanol is stripped from the micro emulsion and entered into the exhaust gasses upstream of the reducing catalyst. The method allows diesel (and other lean-burn) engines to meet new, lower emission standards without having to carry separate fuel and reductant tanks.

  3. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  4. Effects of High Octane Ethanol Blends on Four Legacy Flex-Fuel Vehicles, and a Turbocharged GDI Vehicle

    SciTech Connect (OSTI)

    Thomas, John F; West, Brian H; Huff, Shean P

    2015-03-01

    The U.S. Department of Energy (DOE) is supporting engine and vehicle research to investigate the potential of high-octane fuels to improve fuel economy. Ethanol has very high research octane number (RON) and heat of vaporization (HoV), properties that make it an excellent spark ignition engine fuel. The prospects of increasing both the ethanol content and the octane number of the gasoline pool has the potential to enable improved fuel economy in future vehicles with downsized, downsped engines. This report describes a small study to explore the potential performance benefits of high octane ethanol blends in the legacy fleet. There are over 17 million flex-fuel vehicles (FFVs) on the road today in the United States, vehicles capable of using any fuel from E0 to E85. If a future high-octane blend for dedicated vehicles is on the horizon, the nation is faced with the classic chicken-and-egg dilemma. If today’s FFVs can see a performance advantage with a high octane ethanol blend such as E25 or E30, then perhaps consumer demand for this fuel can serve as a bridge to future dedicated vehicles. Experiments were performed with four FFVs using a 10% ethanol fuel (E10) with 88 pump octane, and a market gasoline blended with ethanol to make a 30% by volume ethanol fuel (E30) with 94 pump octane. The research octane numbers were 92.4 for the E10 fuel and 100.7 for the E30 fuel. Two vehicles had gasoline direct injected (GDI) engines, and two featured port fuel injection (PFI). Significant wide open throttle (WOT) performance improvements were measured for three of the four FFVs, with one vehicle showing no change. Additionally, a conventional (non-FFV) vehicle with a small turbocharged direct-injected engine was tested with a regular grade of gasoline with no ethanol (E0) and a splash blend of this same fuel with 15% ethanol by volume (E15). RON was increased from 90.7 for the E0 to 97.8 for the E15 blend. Significant wide open throttle and thermal efficiency performance improvement was measured for this vehicle, which achieved near volumetric fuel economy parity on the aggressive US06 drive cycle, demonstrating the potential for improved fuel economy in forthcoming downsized, downsped engines with high-octane fuels.

  5. Compatibility Study for Plastic, Elastomeric, and Metallic Fueling Infrastructure Materials Exposed to Aggressive Formulations of Ethanol-blended Gasoline

    SciTech Connect (OSTI)

    Kass, Michael D; Pawel, Steven J; Theiss, Timothy J; Janke, Christopher James

    2012-07-01

    In 2008 Oak Ridge National Laboratory began a series of experiments to evaluate the compatibility of fueling infrastructure materials with intermediate levels of ethanol-blended gasoline. Initially, the focus was elastomers, metals, and sealants, and the test fuels were Fuel C, CE10a, CE17a and CE25a. The results of these studies were published in 2010. Follow-on studies were performed with an emphasis on plastic (thermoplastic and thermoset) materials used in underground storage and dispenser systems. These materials were exposed to test fuels of Fuel C and CE25a. Upon completion of this effort, it was felt that additional compatibility data with higher ethanol blends was needed and another round of experimentation was performed on elastomers, metals, and plastics with CE50a and CE85a test fuels. Compatibility of polymers typically relates to the solubility of the solid polymer with a solvent. It can also mean susceptibility to chemical attack, but the polymers and test fuels evaluated in this study are not considered to be chemically reactive with each other. Solubility in polymers is typically assessed by measuring the volume swell of the polymer exposed to the solvent of interest. Elastomers are a class of polymers that are predominantly used as seals, and most o-ring and seal manufacturers provide compatibility tables of their products with various solvents including ethanol, toluene, and isooctane, which are components of aggressive oxygenated gasoline as described by the Society of Automotive Engineers (SAE) J1681. These tables include a ranking based on the level of volume swell in the elastomer associated with exposure to a particular solvent. Swell is usually accompanied by a decrease in hardness (softening) that also affects performance. For seal applications, shrinkage of the elastomer upon drying is also a critical parameter since a contraction of volume can conceivably enable leakage to occur. Shrinkage is also indicative of the removal of one or more components of the elastomers (by the solvent). This extraction of additives can negatively change the properties of the elastomer, leading to reduced performance and durability. For a seal application, some level of volume swell is acceptable, since the expansion will serve to maintain a seal. However, the acceptable level of swell is dependent on the particular application of the elastomer product. It is known that excessive swell can lead to unacceptable extrusion of the elastomer beyond the sealed interface, where it becomes susceptible to damage. Also, since high swell is indicative of high solubility, there is a heightened potential for fluid to seep through the seal and into the environment. Plastics, on the other hand, are used primarily in structural applications, such as solid components, including piping and fluid containment. Volume change, especially in a rigid system, will create internal stresses that may negatively affect performance. In order to better understand and predict the compatibility for a given polymer type and fuel composition, an analysis based on Hansen solubility theory was performed for each plastic and elastomer material. From this study, the solubility distance was calculated for each polymer material and test fuel combination. Using the calculated solubility distance, the ethanol concentration associated with peak swell and overall extent of swell can be predicted for each polymer. The bulk of the material discussion centers on the plastic materials, and their compatibility with Fuel C, CE25a, CE50a, and CE85a. The next section of this paper focuses on the elastomer compatibility with the higher ethanol concentrations with comparison to results obtained previously for the lower ethanol levels. The elastomers were identical to those used in the earlier study. Hansen solubility theory is also applied to the elastomers to provide added interpretation of the results. The final section summarizes the performance of the metal coupons.

  6. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non?Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian H; Clark, Wendy; Graves, Ronald L; Orban, John; Przesmitzki, Steve; Theiss, Timothy J

    2009-02-01

    In summer 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20--gasoline blended with 15 and 20% ethanol--on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This first report provides the results available to date from the first stages of a much larger overall test program. Results from additional projects that are currently underway or in the planning stages are not included in this first report. The purpose of this initial study was to quickly investigate the effects of adding up to 20% ethanol to gasoline on the following: (1) Regulated tailpipe emissions for 13 popular late model vehicles on a drive cycle similar to real-world driving and 28 small non-road engines (SNREs) under certification or typical in use procedures. (2) Exhaust and catalyst temperatures of the same vehicles under more severe conditions. (3) Temperature of key engine components of the same SNREs under certification or typical in-use conditions. (4) Observable operational issues with either the vehicles or SNREs during the course of testing. As discussed in the concluding section of this report, a wide range of additional studies are underway or planned to consider the effects of intermediate ethanol blends on materials, emissions, durability, and driveability of vehicles, as well as impacts on a wider range of nonautomotive engines, including marine applications, snowmobiles, and motorcycles. Section 1 (Introduction) gives background on the test program and describes collaborations with industry and agencies to date. Section 2 (Experimental Setup) provides details concerning test fuels, vehicle and SNRE selection, and test methods used to conduct the studies presented in this report. Section 3 (Results and Discussion) summarizes the vehicle and SNRE studies and presents data from testing completed to date. Section 4 (Next Steps) describes planned future activities. The appendixes provide test procedure details, vehicle and SNRE emissions standards, analysis details, and additional data and tables from vehicle and SNRE tests.

  7. Fuel and Fuel Additive Registration Testing of Ethanol-Diesel Blend for O2Diesel, Inc.

    SciTech Connect (OSTI)

    Fanick, E. R.

    2004-02-01

    O2 Diesel Inc. (formerly AAE Technologies Inc.) tested a heavy duty engine with O2Diesel (diesel fuel with 7.7% ethanol and additives) for regulated emissions and speciation of vapor-phase and semi-volatile hydrocarbon compounds. This testing was performed in support of EPA requirements for registering designated fuels and fuel additives as stipulated by sections 211(b) and 211(e) of the Clean Air Act.

  8. New Analysis Methods Estimate a Critical Property of Ethanol Fuel Blends (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods developed at NREL disclose the impact of ethanol on gasoline blend heat of vaporization with potential for improved efficiency of spark-ignition engines. More stringent standards for fuel economy, regulation of greenhouse gas emissions, and the mandated increase in the use of renew- able fuel are driving research to improve the efficiency of spark ignition engines. When fuel properties such as octane number and evaporative cooling (heat of vaporization or HOV) are insufficient, they

  9. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends (Brochure), Clean Cities, Energy Efficiency & Renewable Energy (EERE)

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    DOE/GO-102016-4854 February 2016 Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends Disclaimer This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or

  10. Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

    SciTech Connect (OSTI)

    Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael; Divita, Vincent

    2015-07-14

    In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREET — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.

  11. Ethanol-blended Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Methanol ......with gas injection of sulfur dioxide, membrane saccharification, high-tolerance ... and performance under load, passing, etc. ...

  12. Enabling High Efficiency Ethanol Engines

    SciTech Connect (OSTI)

    Szybist, J.; Confer, K.

    2011-03-01

    Delphi Automotive Systems and ORNL established this CRADA to explore the potential to improve the energy efficiency of spark-ignited engines operating on ethanol-gasoline blends. By taking advantage of the fuel properties of ethanol, such as high compression ratio and high latent heat of vaporization, it is possible to increase efficiency with ethanol blends. Increasing the efficiency with ethanol-containing blends aims to remove a market barrier of reduced fuel economy with E85 fuel blends, which is currently about 30% lower than with petroleum-derived gasoline. The same or higher engine efficiency is achieved with E85, and the reduction in fuel economy is due to the lower energy density of E85. By making ethanol-blends more efficient, the fuel economy gap between gasoline and E85 can be reduced. In the partnership between Delphi and ORNL, each organization brought a unique and complementary set of skills to the project. Delphi has extensive knowledge and experience in powertrain components and subsystems as well as overcoming real-world implementation barriers. ORNL has extensive knowledge and expertise in non-traditional fuels and improving engine system efficiency for the next generation of internal combustion engines. Partnering to combine these knowledge bases was essential towards making progress to reducing the fuel economy gap between gasoline and E85. ORNL and Delphi maintained strong collaboration throughout the project. Meetings were held regularly, usually on a bi-weekly basis, with additional reports, presentations, and meetings as necessary to maintain progress. Delphi provided substantial hardware support to the project by providing components for the single-cylinder engine experiments, engineering support for hardware modifications, guidance for operational strategies on engine research, and hardware support by providing a flexible multi-cylinder engine to be used for optimizing engine efficiency with ethanol-containing fuels.

  13. Ethanol Demand in United States Gasoline Production

    SciTech Connect (OSTI)

    Hadder, G.R.

    1998-11-24

    The Oak Ridge National Laboratory (OWL) Refinery Yield Model (RYM) has been used to estimate the demand for ethanol in U.S. gasoline production in year 2010. Study cases examine ethanol demand with variations in world oil price, cost of competing oxygenate, ethanol value, and gasoline specifications. For combined-regions outside California summer ethanol demand is dominated by conventional gasoline (CG) because the premised share of reformulated gasoline (RFG) production is relatively low and because CG offers greater flexibility for blending high vapor pressure components like ethanol. Vapor pressure advantages disappear for winter CG, but total ethanol used in winter RFG remains low because of the low RFG production share. In California, relatively less ethanol is used in CG because the RFG production share is very high. During the winter in California, there is a significant increase in use of ethanol in RFG, as ethanol displaces lower-vapor-pressure ethers. Estimated U.S. ethanol demand is a function of the refiner value of ethanol. For example, ethanol demand for reference conditions in year 2010 is 2 billion gallons per year (BGY) at a refiner value of $1.00 per gallon (1996 dollars), and 9 BGY at a refiner value of $0.60 per gallon. Ethanol demand could be increased with higher oil prices, or by changes in gasoline specifications for oxygen content, sulfur content, emissions of volatile organic compounds (VOCS), and octane numbers.

  14. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol ...

  15. Dispensing Equipment Testing with Mid-Level Ethanol/Gasoline Test Fluid: Summary Report

    SciTech Connect (OSTI)

    Boyce, K.; Chapin, J. T.

    2010-11-01

    The National Renewable Energy Laboratory's (NREL) Nonpetroleum-Based Fuel Task addresses the hurdles to commercialization of biomass-derived fuels and fuel blends. One such hurdle is the unknown compatibility of new fuels with current infrastructure, such as the equipment used at service stations to dispense fuel into automobiles. The U.S. Department of Energy's (DOE) Vehicle Technology Program and the Biomass Program have engaged in a joint project to evaluate the potential for blending ethanol into gasoline at levels higher than nominal 10 volume percent. This project was established to help DOE and NREL better understand any potentially adverse impacts caused by a lack of knowledge about the compatibility of the dispensing equipment with ethanol blends higher than what the equipment was designed to dispense. This report provides data about the impact of introducing a gasoline with a higher volumetric ethanol content into service station dispensing equipment from a safety and a performance perspective.

  16. A comparison of ethanol and butanol as oxygenates using a direct-injection, spark-ignition (DISI) engine.

    SciTech Connect (OSTI)

    Wallner, T.; Miers, S. A.; McConnell, S.

    2009-05-01

    This study was designed to evaluate a 'what if' scenario in terms of using butanol as an oxygenate in place of ethanol in an engine calibrated for gasoline operation. No changes to the stock engine calibration were performed for this study. Combustion analysis, efficiency, and emissions of pure gasoline, 10% ethanol, and 10% butanol blends in a modern direct-injection four-cylinder spark-ignition engine were analyzed. Data were taken at engine speeds of 1000 rpm up to 4000 rpm with load varying from 0 N m (idle) to 150 N m. Relatively minor differences existed between the three fuels for the combustion characteristics such as heat release rate, 50% mass fraction burned, and coefficient of variation in indicated mean effective pressure at low and medium engine loads. However at high engine loads the reduced knock resistance of the butanol blend forced the engine control unit to retard the ignition timing substantially, compared with the gasoline baseline and, even more pronounced, compared with the ethanol blend. Brake specific volumetric fuel consumption, which represented a normalized volumetric fuel flow rate, was lowest for the gasoline baseline fuel due to the higher energy density. The 10% butanol blend had a lower volumetric fuel consumption compared with the ethanol blend, as expected, based on energy density differences. The results showed little difference in regulated emissions between 10% ethanol and 10% butanol. The ethanol blend produced the highest peak specific NO{sub x} due to the high octane rating of ethanol and effective antiknock characteristics. Overall, the ability of butanol to perform equally as well as ethanol from an emissions and combustion standpoint, with a decrease in fuel consumption, initially appears promising. Further experiments are planned to explore the full operating range of the engine and the potential benefits of higher blend ratios of butanol.

  17. Mid-Level Ethanol Blends

    Energy Savers [EERE]

    zbDE-FOA-0000091.rtf Microsoft Word - zbDE-FOA-0000091.rtf PDF icon Microsoft Word - zbDE-FOA-0000091.rtf More Documents & Publications Recovery Act Local Energy Assurance Planning (LEAP) Initiative Funding Opportunity Number: DE-FOA-0000098 DISCLAIMER: DISCLAIMER:

    Workshops » Microwave and Radio Frequency Workshop Microwave and Radio Frequency Workshop July 25, 2012 At the Microwave and Radio Frequency Workshop (held in Long Beach, CA, on July 25, 2012), academic and industry experts

  18. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels, Phase 2: Evaluations of Field Samples and Laboratory Blends

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; LaViolette, M.

    2010-04-01

    Study to measure the flammability of gasoline/ethanol fuel vapors at low ambient temperatures and develop a mathematical model to predict temperatures at which flammable vapors were likely to form.

  19. Dispensing Equipment Testing With Mid-Level Ethanol/Gasoline Test Fluid

    Broader source: Energy.gov [DOE]

    The National Renewable Energy Laboratory’s (NREL) Nonpetroleum-Based Fuel Task addresses the hurdles to commercialization of biomass-derived fuels and fuel blends. One such hurdle is the unknown compatibility of new fuels with current infrastructure, such as the equipment used at service stations to dispense fuel into automobiles. The U.S. Department of Energy’s (DOE) Vehicle Technology Program and the Biomass Program have engaged in a joint project to evaluate the potential for blending ethanol into gasoline at levels higher than nominal 10 volume percent. The U.S. Environmental Protection Agency (EPA) is considering a waiver application for 15% by volume ethanol blended into gasoline (E15). Should the waiver be granted, service stations may be able to use their current equipment to dispense the new fuel. This project was established to help DOE and NREL better understand any potentially adverse impacts caused by a lack of knowledge about the compatibility of the dispensing equipment with ethanol blends higher than what the equipment was designed to dispense. This report provides data about the impact of introducing a gasoline with a higher volumetric ethanol content into service station dispensing equipment from a safety and a performance perspective.

  20. Biodiesel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    A 2-page fact sheet discussing general biodiesel blends and the improvement in engine performance and emissions.

  1. Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks | Department of Energy Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Breakout Session 2-B: New/Emerging Pathways Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend

  2. Impacts of ethanol fuel level on emissions of regulated and unregulated pollutants from a fleet of gasoline light-duty vehicles

    SciTech Connect (OSTI)

    Karavalakis, Georgios; Durbin, Thomas; Shrivastava, ManishKumar B.; Zheng, Zhongqing; Villella, Phillip M.; Jung, Hee-Jung

    2012-03-30

    The study investigated the impact of ethanol blends on criteria emissions (THC, NMHC, CO, NOx), greenhouse gas (CO2), and a suite of unregulated pollutants in a fleet of gasoline-powered light-duty vehicles. The vehicles ranged in model year from 1984 to 2007 and included one Flexible Fuel Vehicle (FFV). Emission and fuel consumption measurements were performed in duplicate or triplicate over the Federal Test Procedure (FTP) driving cycle using a chassis dynamometer for four fuels in each of seven vehicles. The test fuels included a CARB phase 2 certification fuel with 11% MTBE content, a CARB phase 3 certification fuel with a 5.7% ethanol content, and E10, E20, E50, and E85 fuels. In most cases, THC and NMHC emissions were lower with the ethanol blends, while the use of E85 resulted in increases of THC and NMHC for the FFV. CO emissions were lower with ethanol blends for all vehicles and significantly decreased for earlier model vehicles. Results for NOx emissions were mixed, with some older vehicles showing increases with increasing ethanol level, while other vehicles showed either no impact or a slight, but not statistically significant, decrease. CO2 emissions did not show any significant trends. Fuel economy showed decreasing trends with increasing ethanol content in later model vehicles. There was also a consistent trend of increasing acetaldehyde emissions with increasing ethanol level, but other carbonyls did not show strong trends. The use of E85 resulted in significantly higher formaldehyde and acetaldehyde emissions than the specification fuels or other ethanol blends. BTEX and 1,3-butadiene emissions were lower with ethanol blends compared to the CARB 2 fuel, and were almost undetectable from the E85 fuel. The largest contribution to total carbonyls and other toxics was during the cold-start phase of FTP.

  3. Ethanol Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Fuel Basics Ethanol Fuel Basics July 30, 2013 - 12:00pm Addthis biomass in beekers Ethanol is a renewable fuel made from various plant materials collectively known as "biomass." Studies have estimated that ethanol and other biofuels could replace 30% or more of U.S. gasoline demand by 2030. More than 95% of U.S. gasoline contains ethanol in a low-level blend to oxygenate the fuel and reduce air pollution. Ethanol is also increasingly available in E85, an alternative fuel that

  4. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  5. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    IMPACT OF LOW OCTANE HYDROCARBON BLENDING STREAMS ON "E85" ENGINE OPTIMIZATION Jim Szybist ... Year ETHANOL IS CURRENTLY THE LARGEST VOLUME BIOFUEL, VERY IMPORTANT FOR EISA COMPLIANCE * ...

  6. An Update on Ethanol Production and Utilization in Thailand, 2014

    SciTech Connect (OSTI)

    Bloyd, Cary N.; Foster, Nikolas A.F.

    2014-09-01

    In spite of the recent political turmoil, Thailand has continued to develop its ethanol based alternative fuel supply and demand infrastructure. Its support of production and sales of ethanol contributed to more than doubling the production over the past five years alone. In April 2014, average consumption stood at 3.18 million liter per day- more than a third on its way to its domestic consumption goal of 9 million liters per day by 2021. Strong government incentives and the phasing out of non-blended gasoline contributed substantially. Concurrently, exports dropped significantly to their lowest level since 2011, increasing the pressure on Thai policy makers to best balance energy independency goals with other priorities, such as Thailand’s trade balance and environmental aspirations. Utilization of second generation biofuels might have the potential to further expand Thailand’s growing ethanol market. Thailand has also dramatically increased its higher ethanol blend vehicle fleet, with all new vehicles sold in the Thai market now being E20 capable and the number of E85 vehicles increasing three fold in the last year from 100,000 in 2013 to 300,000 in 2014.

  7. Ethanol fuel modification for highway vehicle use. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    A number of problems that might occur if ethanol were used as a blending stock or replacement for gasoline in present cars are identified and characterized as to the probability of occurrence. The severity of their consequences is contrasted to those found with methanol in a previous contract study. Possibilities for correcting several problems are reported. Some problems are responsive to fuel modifications but others require or are better dealt with by modification of vehicles and the bulk fuel distribution system. In general, problems with ethanol in blends with gasoline were found to be less severe than those with methanol. Phase separation on exposure to water appears to be the major problem with ethanol/gasoline blends. Another potentially serious problem with blends is the illict recovery of ethanol for beverage usage, or bootlegging, which might be discouraged by the use of select denaturants. Ethanol blends have somewhat greater tendency to vapor lock than base gasoline but less than methanol blends. Gasoline engines would require modification to operate on fuels consisting mostly of ethanol. If such modifications were made, cold starting would still be a major problem, more difficult with ethanol than methanol. Startability can be provided by adding gasoline or light hydrocarbons. Addition of gasoline also reduces the explosibility of ethanol vapor and furthermore acts as denaturant.

  8. Analysis of Fuel Ethanol Transportation Activity and Potential Distribution Constraints

    SciTech Connect (OSTI)

    Das, Sujit; Peterson, Bruce E; Chin, Shih-Miao

    2010-01-01

    This paper provides an analysis of fuel ethanol transportation activity and potential distribution constraints if the total 36 billion gallons of renewable fuel use by 2022 is mandated by EPA under the Energy Independence and Security Act (EISA) of 2007. Ethanol transport by domestic truck, marine, and rail distribution systems from ethanol refineries to blending terminals is estimated using Oak Ridge National Laboratory s (ORNL s) North American Infrastructure Network Model. Most supply and demand data provided by EPA were geo-coded and using available commercial sources the transportation infrastructure network was updated. The percentage increases in ton-mile movements by rail, waterways, and highways in 2022 are estimated to be 2.8%, 0.6%, and 0.13%, respectively, compared to the corresponding 2005 total domestic flows by various modes. Overall, a significantly higher level of future ethanol demand would have minimal impacts on transportation infrastructure. However, there will be spatial impacts and a significant level of investment required because of a considerable increase in rail traffic from refineries to ethanol distribution terminals.

  9. Mid-Level Ethanol Blends Test Program

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  10. Ethanol Basics

    SciTech Connect (OSTI)

    2015-01-30

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  11. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  12. Effects of ethanol on small engines and the environment

    SciTech Connect (OSTI)

    Bettis, M.D.

    1995-01-09

    With the support of the Missouri Corn Merchandising Council and the Department of Energy, Northwest Missouri State University conducted an applied research project to investigate the effects of the commercially available ethanol/gasoline fuel blend on small engines. The study attempted to identify any problems when using the 10% ethanol/gasoline blend in engines designed for gasoline and provide solutions to the problems identified. Fuel economy, maximum power, internal component wear, exhaust emissions and engine efficiency were studied.

  13. Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .

    SciTech Connect (OSTI)

    Wallner, T.

    2011-08-01

    The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

  14. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-01-01

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  15. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-12-31

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  16. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  17. Pacific Ethanol, Inc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pacific Ethanol, Inc

  18. Preliminary evaluation of alternative ethanol/water separation processes

    SciTech Connect (OSTI)

    Eakin, D.E.; Donovan, J.M.; Cysewski, G.R.; Petty, S.E.; Maxham, J.V.

    1981-05-01

    Preliminary evaluation indicates that separation of ethanol and water can be accomplished with less energy than is now needed in conventional distillation processes. The state of development for these methods varies from laboratory investigation to commercially available processes. The processes investigated were categorized by type of separation depending on their ability to achieve varying degrees of ethanol/water separation. The following methods were investigated: ethanol extraction with CO/sub 2/ (the A.D. Little process); solvent extraction of ethanol; vacuum distillation; vapor recompression distillation; dehydration with fermentable grains; low temperature blending with gasoline; molecular sieve adsorption; and reverse osmosis.

  19. Fact #588: September 14, 2009 Fuel Economy Changes Due to Ethanol Content

    Broader source: Energy.gov [DOE]

    The fuel economy of a vehicle is dependent on many things, one of which is the fuel used in the vehicle. Two National Laboratories recently studied the effects that ethanol blends have on the fuel...

  20. Greater Ohio Ethanol LLC GO Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ohio Ethanol LLC GO Ethanol Jump to: navigation, search Name: Greater Ohio Ethanol, LLC (GO Ethanol) Place: Lima, Ohio Zip: OH 45804 Product: GO Ethanol is a pure play ethanol...

  1. Experiences from Introduction of Ethanol Buses and Ethanol Fuel...

    Open Energy Info (EERE)

    of Ethanol Buses and Ethanol Fuel Station Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Experiences from Introduction of Ethanol Buses and Ethanol Fuel Station Agency...

  2. The ethanol heavy-duty truck fleet demonstration project

    SciTech Connect (OSTI)

    1997-06-01

    This project was designed to test and demonstrate the use of a high- percentage ethanol-blended fuel in a fleet of heavy-duty, over-the- road trucks, paying particular attention to emissions, performance, and repair and maintenance costs. This project also represents the first public demonstration of the use of ethanol fuels as a viable alternative to conventional diesel fuel in heavy-duty engines.

  3. Numerical study of the effect of oxygenated blending compounds on soot formation in shock tubes

    SciTech Connect (OSTI)

    Boehm, H.; Braun-Unkhoff, M.

    2008-04-15

    This numerical study deals with the influence of blends on the amount of soot formed in shock tubes, which were simulated by assuming a homogeneous plug flow reactor model. For this purpose, first, the reaction model used here was validated against experimental results previously obtained in the literature. Then, the soot volume fractions of various mixtures of methyl tert-butyl ether (MTBE)-benzene, isobutene-benzene, methanol-benzene, and ethanol-benzene diluted in argon were simulated and compared to the results of benzene-argon pyrolysis at 1721 K and 5.4 MPa. For MTBE, isobutene, methanol, and ethanol, small amounts of additives to benzene-argon mixtures promoted soot formation, for the shock tube model assumed, while higher concentrations of these additives led to smaller soot volume fractions in comparison to pure benzene-argon pyrolysis. The most significant soot promotion effect was found for the additives MTBE and isobutene. The channel for MTBE decomposition producing isobutene and methanol is very effective at temperatures beyond 1200 K. Thus, both MTBE-benzene and isobutene-benzene mixtures diluted in argon showed rather similar behavior in regard to soot formation. Special emphasis was directed toward the causes for the concentration-dependent influence of the blends on the amount of soot formed. Aromatic hydrocarbons and acetylene were identified as key gas-phase species that determine the trends in the formation of soot of various mixtures. From reaction flux analysis for phenanthrene, it was deduced that the combinative routes including phenyl species play a major role in forming PAHs, especially at early reaction times. It is found that the additives play an important role in providing material to grow side chains, such as by reaction channels including phenylacetylene or benzyl, which are confirmed to form aromatic hydrocarbons and thus to influence the amount of soot formed, particularly when the concentrations of the blends are increased. (author)

  4. Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Add description and move this content to a more appropriate page name (like "List of ethanol incentives") List of Ethanol Incentives E85 Standards Retrieved from "http:...

  5. Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower This page contains information on the recently released BioPower engines. PDF icon analysis_saab2007.pdf More Documents & Publications Enabling High Efficiency Ethanol Engines Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) The Impact of Low Octane Hydrocarbon Blending

  6. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels

    SciTech Connect (OSTI)

    Gardiner, D.; Bardon, M.; Pucher, G.

    2008-10-01

    Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

  7. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol This...

  8. Emissions from ethanol- and LPG-fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1995-06-01

    This paper addresses the environmental concerns of using neat ethanol and liquefied petroleum gas (LPG) as transportation fuels in the United States. Low-level blends of ethanol (10%) with gasoline have been used as fuels in the United States for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the United States, but its use has been limited primarily to converted fleet vehicles. Increasing U.S. interest in alternative fuels has raised the possibility of introducing neat-ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles, and increased production and consumption of fuel ethanol and LPG, will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat-ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural impacts from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG as compared with other transportation fuels. The environmental concerns are reviewed and summarized, but only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat-ethanol-fueled vehicles or the increase in LPG-fueled vehicles.

  9. Effect of Biodiesel Blends on NOx Emissions | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_pedersen.pdf More Documents & Publications Key Benefits in Using Ethanol-Diesel Blends Diesel Injection Shear-Stress Advanced Nozzle (DISSAN) Lean NOx Trap Formulation Effect on Performance with In-Cylinder Regeneration

  10. Modifications for use of methanol or methanol-gasoline blends in automotive vehicles, September 1976-January 1980

    SciTech Connect (OSTI)

    Patterson, D.J.; Bolt, J.A.; Cole, D.E.

    1980-01-01

    Methanol or blends of methanol and gasoline as automotive fuels may be attractive means for extending the nation's petroleum reserves. The present study was aimed at identifying potential problems and solutions for this use of methanol. Retrofitting of existing vehicles as well as future vehicle design have been considered. The use of ethanol or higher alcohols was not addressed in this study but will be included at a later date. Several potentially serious problems have been identified with methanol use. The most attractive solutions depend upon an integrated combination of vehicle modifications and fuel design. No vehicle problems were found which could not be solved with relatively minor developments of existing technology providing the methanol or blend fuel was itself engineered to ameliorate the solution. Research needs have been identified in the areas of lubrication and materials. These, while apparently solvable, must precede use of methanol or methanol-gasoline blends as motor fuels. Because of the substantial costs and complexities of a retrofitting program, use of methanol must be evaluated in relation to other petroleum-saving alternatives. Future vehicles can be designed initially to operate satisfactorily on these alternate fuels. However a specific fuel composition must be specified around which the future engines and vehicles can be designed.

  11. Southridge Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Southridge Ethanol Place: Dallas, Texas Zip: 75219 Sector: Renewable Energy Product: Southridge Ethanol is a renewable energy company...

  12. Diversified Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Diversified Ethanol Place: Northbrook, Illinois Zip: 60062 Product: A division of OTCBB-traded ONYI that is building an ethanol plant in...

  13. Ace Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Ace Ethanol Place: Stanley, Wisconsin Zip: 54768 Product: Producer of corn-based ethanol in Wisconsin. Coordinates: 44.958844,...

  14. Dakota Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Dakota Ethanol Place: Wentworth, South Dakota Zip: 57075 Product: Farmer Coop owner of a 189m litres per year ethanol plant Coordinates:...

  15. Cellulosic ethanol | Open Energy Information

    Open Energy Info (EERE)

    Cellulosic ethanol Jump to: navigation, search Cellethanol.jpg Cellulosic ethanol is identical to first generation bio ethanol except that it can be derived from agricultural...

  16. Ethanol: farm and fuel issues

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    The current U.S. and world grain situations are described as well as adjustments which would be likely for fuel production of 1, 2 and 4 billion gallons of ethanol annually in the 1985-86 period. Predicted acreage shifts in corn, soybeans, wheat and the total of seven major crops are shown. The most likely effects on the feed grains markets both here and abroad are discussed. The value of corn for fuel both with and without the gasoline tax exemption is compared to the actual farm price expected if in the base case (1 billion gallons) real corn prices do not rise. In the higher 2 and 4 billion gallon cases, increases in the real cost of corn and its impact on food prices and the CPI are estimated. A theoretical maximum level of ethanol production recognizing market factors is discussed in terms of acreage, yield, corn production and the fuel ethanol available. Agricultural and other policy frameworks are discussed.

  17. Greenhouse gases in the corn-to-fuel ethanol pathway.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-06-18

    Argonne National Laboratory (ANL) has applied its Greenhouse gas, Regulated Emissions and Energy in Transportation (GREET) full-fuel-cycle analysis model to examine greenhouse gas (GHG) emissions of corn-feedstock ethanol, given present and near-future production technology and practice. On the basis of updated information appropriate to corn farming and processing operations in the four principal corn- and ethanol-producing states (Illinois, Iowa, Minnesota, and Nebraska), the model was used to estimate energy requirements and GHG emissions of corn farming; the manufacture, transportation to farms, and field application of fertilizer and pesticide; transportation of harvested corn to ethanol plants; nitrous oxide emissions from cultivated cornfields; ethanol production in current average and future technology wet and dry mills; and operation of cars and light trucks using ethanol fuels. For all cases examined on the basis of mass emissions per travel mile, the corn-to-ethanol fuel cycle for Midwest-produced ethanol used in both E85 and E10 blends with gasoline outperforms conventional (current) and reformulated (future) gasoline with respect to energy use and GHG production. Also, GHG reductions (but not energy use) appear surprisingly sensitive to the value chosen for combined soil and leached N-fertilizer conversion to nitrous oxide. Co-product energy-use attribution remains the single key factor in estimating ethanol's relative benefits because this value can range from 0 to 50%, depending on the attribution method chosen.

  18. Key Benefits in Using Ethanol-Diesel Blends

    Broader source: Energy.gov [DOE]

    Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  19. Mid-Blend Ethanol Fuels – Implementation Perspectives

    Broader source: Energy.gov [DOE]

    Breakout Session 2: Frontiers and Horizons Session 2–B: End Use and Fuel Certification Bill Woebkenberg, Fuels Technical and Regulatory Affairs Senior Engineer, Mercedes-Benz

  20. Legacy Vehicle Fuel System Testing with Intermediate Ethanol Blends

    SciTech Connect (OSTI)

    Davis, G. W.; Hoff, C. J.; Borton, Z.; Ratcliff, M. A.

    2012-03-01

    The effects of E10 and E17 on legacy fuel system components from three common mid-1990s vintage vehicle models (Ford, GM, and Toyota) were studied. The fuel systems comprised a fuel sending unit with pump, a fuel rail and integrated pressure regulator, and the fuel injectors. The fuel system components were characterized and then installed and tested in sample aging test rigs to simulate the exposure and operation of the fuel system components in an operating vehicle. The fuel injectors were cycled with varying pulse widths during pump operation. Operational performance, such as fuel flow and pressure, was monitored during the aging tests. Both of the Toyota fuel pumps demonstrated some degradation in performance during testing. Six injectors were tested in each aging rig. The Ford and GM injectors showed little change over the aging tests. Overall, based on the results of both the fuel pump testing and the fuel injector testing, no major failures were observed that could be attributed to E17 exposure. The unknown fuel component histories add a large uncertainty to the aging tests. Acquiring fuel system components from operational legacy vehicles would reduce the uncertainty.

  1. Evaluation of Ethanol Blends for PHEVs using Simulation and

    Broader source: Energy.gov (indexed) [DOE]

    Engine-in-the-Loop | Department of Energy 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon vss049_shidore_2011_o.pdf More Documents & Publications Evaluation of the Fuel Economy Impacts of Low Temperature Combustion (LTC) using Engine-in-the-Loop Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth Tradeoff between Fuel Consumption and

  2. Byone Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Byone Ethanol Jump to: navigation, search Name: Byone Ethanol Place: Brazil Product: Ethanol Producer References: Byone Ethanol1 This article is a stub. You can help OpenEI by...

  3. Highwater Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Highwater Ethanol Jump to: navigation, search Name: Highwater Ethanol Place: Lamberton, Minnesota Zip: MN 56152 Product: Highwater Ethanol LLC is the SPV behind the 195mLpa ethanol...

  4. Alternative Fuels Data Center: Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Ethanol to someone by E-mail Share Alternative Fuels Data Center: Ethanol on Facebook Tweet about Alternative Fuels Data Center: Ethanol on Twitter Bookmark Alternative Fuels Data Center: Ethanol on Google Bookmark Alternative Fuels Data Center: Ethanol on Delicious Rank Alternative Fuels Data Center: Ethanol on Digg Find More places to share Alternative Fuels Data Center: Ethanol on AddThis.com... More

  5. Ethanol Basics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2015-01-01

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  6. Powertrain Component Inspection from Mid-Level Blends Vehicle Aging Study

    SciTech Connect (OSTI)

    Shoffner, Brent; Johnson, Ryan; Heimrich, Martin J.; Lochte, Michael

    2010-11-01

    The Energy Independence and Security Act of 2007 calls on the nation to significantly increase its use of renewable fuels to meet its transportation energy needs. The law expands the renewable fuel standard to require use of 36 billion gallons of renewable fuel by 2022. Given that ethanol is the most widely used renewable fuel in the U.S. market, ethanol will likely make up a significant portion of the 36-billion-gallon requirement. The vast majority of ethanol used in the United States is blended with gasoline to create E10-gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85 - a gasoline blend with as much as 85% ethanol that can only be used in flexible-fuel vehicles (FFVs). Consumption of E85 is at present limited by both the size of the FFV fleet and the number of E85 fueling stations. Gasoline consumption in the United States is currently about 140 billion gallons per year; thus the maximum use of ethanol as E10 is only about 14 billion gallons. While the U.S. Department of Energy (DOE) remains committed to expanding the E85 infrastructure, that market represented less than 1% of the ethanol consumed in 2010 and will not be able to absorb projected volumes of ethanol in the near term. Because of these factors, DOE and others have been assessing the viability of using mid-level ethanol blends (E15 or E20) as a way to accommodate growing volumes of ethanol. The DOE Mid-Level Ethanol Blends Test Program has been under way since 2007, supported jointly by the Office of the Biomass Program and the Vehicle Technologies Program. One of the larger projects, the Catalyst Durability Study, or Vehicle Aging Study, will be completed early in calendar year 2011. The following report describes a subproject of the Vehicle Aging Study in which powertrain components from 18 of the vehicles were examined at Southwest Research Institute under contract to Oak Ridge National Laboratory (ORNL).

  7. Sioux River Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    River Ethanol LLC Jump to: navigation, search Name: Sioux River Ethanol LLC Place: Hudson, South Dakota Zip: 57034 Product: Farmer owned ethanol producer, Sioux River Ethanol is...

  8. Cardinal Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Cardinal Ethanol LLC Place: Winchester, Indiana Zip: 47394 Product: Cardinal Ethanol is in the process of building an ethanol plant in...

  9. Phelps County Ethanol | Open Energy Information

    Open Energy Info (EERE)

    County Ethanol Jump to: navigation, search Name: Phelps County Ethanol Place: Nebraska Product: Focused on ethanol production. References: Phelps County Ethanol1 This article is...

  10. Alternative Fuels Data Center: Biodiesel Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Blends to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blends on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blends on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blends on Google Bookmark Alternative Fuels Data Center: Biodiesel Blends on Delicious Rank Alternative Fuels Data Center: Biodiesel Blends on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blends on AddThis.com... More in this section... Biodiesel Basics

  11. Effects of gasoline reactivity and ethanol content on boosted premixed and partially stratified low-temperature gasoline combustion (LTGC)

    SciTech Connect (OSTI)

    Dec, John E.; Yang, Yi; Ji, Chunsheng; Dernotte, Jeremie

    2015-04-14

    Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel ?- sensitive so that partial fuel stratification (PFS) can be applied for higher loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion. Accordingly, an experimental investigation has been conducted to determine how the tradeoff between the effects of intake boost varies with fuel-type and its impact on load range and TE. Five fuels are investigated: a conventional AKI=87 petroleum-based gasoline (E0), and blends of 10 and 20% ethanol with this gasoline to reduce its reactivity enhancement with boost (E10 and E20). Furthermore, a second zero-ethanol gasoline with AKI=93 (matching that of E20) was also investigated (CF-E0), and some neat ethanol data are also reported.

  12. Effects of gasoline reactivity and ethanol content on boosted premixed and partially stratified low-temperature gasoline combustion (LTGC)

    SciTech Connect (OSTI)

    Dec, John E.; Yang, Yi; Ji, Chunsheng; Dernotte, Jeremie

    2015-04-14

    Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel Φ- sensitive so that partial fuel stratification (PFS) can be applied for higher loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion. Accordingly, an experimental investigation has been conducted to determine how the tradeoff between the effects of intake boost varies with fuel-type and its impact on load range and TE. Five fuels are investigated: a conventional AKI=87 petroleum-based gasoline (E0), and blends of 10 and 20% ethanol with this gasoline to reduce its reactivity enhancement with boost (E10 and E20). Furthermore, a second zero-ethanol gasoline with AKI=93 (matching that of E20) was also investigated (CF-E0), and some neat ethanol data are also reported.

  13. Fermentation method producing ethanol

    DOE Patents [OSTI]

    Wang, Daniel I. C.; Dalal, Rajen

    1986-01-01

    Ethanol is the major end product of an anaerobic, thermophilic fermentation process using a mutant strain of bacterium Clostridium thermosaccharolyticum. This organism is capable of converting hexose and pentose carbohydrates to ethanol, acetic and lactic acids. Mutants of Clostridium thermosaccharolyticum are capable of converting these substrates to ethanol in exceptionally high yield and with increased productivity. Both the mutant organism and the technique for its isolation are provided.

  14. Pacific Ethanol, Inc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Corporate HQ: Sacramento, CA Proposed Facility Location: Boardman, OR Description: The team will design and build a demonstration cellulosic ethanol plant in Boardman, Oregon, ...

  15. Fuel Ethanol Oxygenate Production

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels ...

  16. Pacific Ethanol, Inc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    per year of cellulosic ethanol biofuel Technology and Feedstocks: * Pretreatment, ... energy crops, agricultural waste, and wood product residues State of Readiness: * The ...

  17. Oxygenates du`jour...MTBE? Ethanol? ETBE?

    SciTech Connect (OSTI)

    Wolfe, R.

    1995-12-31

    There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

  18. Bushmills Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Bushmills Ethanol Jump to: navigation, search Name: Bushmills Ethanol Place: Atwater, Minnesota Zip: 56209 Product: A group of local agricultural producers and investors working to...

  19. Northstar Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Northstar Ethanol Jump to: navigation, search Name: Northstar Ethanol Place: Lake Crystal, Minnesota Zip: 56055 Product: Corn-base bioethanol producer in Minnesotta References:...

  20. Sunnyside Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Sunnyside Ethanol Place: Pittsburgh, Pennsylvania Zip: PA 15237 Product: Pennsylvania based company created for the specific purpose of...

  1. Ethanol India | Open Energy Information

    Open Energy Info (EERE)

    India Jump to: navigation, search Name: Ethanol India Place: Kolhapur, Maharashtra, India Sector: Biofuels Product: Maharashtra-based biofuels consultancy firm. References: Ethanol...

  2. Pacific Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Pacific Ethanol Address: 400 Capitol Mall, Suite 2060 Place: Sacramento, California Zip: 95814 Region: Bay Area Sector: Biofuels Product: Ethanol production Website:...

  3. Pacific Ethanol, Inc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Major DOE Biofuels Project Locations Pacific Ethanol, Inc Pacific Ethanol, Inc

  4. Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions | Department

    Broader source: Energy.gov (indexed) [DOE]

    of Energy Characterized particulate emissions from U.S.-legal stoichiometric GDI and European certified lean-burn GDI vehicles operating on ethanol blends PDF icon deer11_storey.pdf More Documents & Publications Measurement and Characterization of Unregulated Emissions from Advanced Technologies Measurement and Characterization of Unregulated Emissions from Advanced Technologies Measurement and Characterization of Unregulated Emissions from Advanced Technologies

  5. South Texas Blending | Open Energy Information

    Open Energy Info (EERE)

    search Name: South Texas Blending Place: Laredo, Texas Zip: 78045 Product: Biodiesel producer based in Texas. References: South Texas Blending1 This article is a stub....

  6. High Speed/ Low Effluent Process for Ethanol

    SciTech Connect (OSTI)

    M. Clark Dale

    2006-10-30

    n this project, BPI demonstrated a new ethanol fermentation technology, termed the High Speed/ Low Effluent (HS/LE) process on both lab and large pilot scale as it would apply to wet mill and/or dry mill corn ethanol production. The HS/LE process allows very rapid fermentations, with 18 to 22% sugar syrups converted to 9 to 11% ethanol beers in 6 to 12 hours using either a consecutive batch or continuous cascade implementation. This represents a 5 to 8X increase in fermentation speeds over conventional 72 hour batch fermentations which are the norm in the fuel ethanol industry today. The consecutive batch technology was demonstrated on a large pilot scale (4,800 L) in a dry mill corn ethanol plant near Cedar Rapids, IA (Xethanol Biofuels). The pilot demonstrated that 12 hour fermentations can be accomplished on an industrial scale in a non-sterile industrial environment. Other objectives met in this project included development of a Low Energy (LE) Distillation process which reduces the energy requirements for distillation from about 14,000 BTU/gal steam ($0.126/gal with natural gas @ $9.00 MCF) to as low as 0.40 KW/gal electrical requirements ($0.022/gal with electricity @ $0.055/KWH). BPI also worked on the development of processes that would allow application of the HS/LE fermentation process to dry mill ethanol plants. A High-Value Corn ethanol plant concept was developed to produce 1) corn germ/oil, 2) corn bran, 3) ethanol, 4) zein protein, and 5) nutritional protein, giving multiple higher value products from the incoming corn stream.

  7. Ethanol Tolerant Yeast for Improved Production of Ethanol from Biomass -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ethanol Basics Ethanol is a widely used, domesti- cally produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Fuel ethanol contains the same chemical compound as beverage alcohol, but it is denatured with a small amount of gasoline or other chemicals during the production process, making it unsafe for human consumption. Ethanol's primary market drivers are the Federal Renewable Fuel Standard requiring its use and

  8. The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization PDF icon deer12_szybist.pdf More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Gasoline-Like Fuel Effects on Advanced

  9. Ethanol production from lignocellulose

    DOE Patents [OSTI]

    Ingram, Lonnie O.; Wood, Brent E.

    2001-01-01

    This invention presents a method of improving enzymatic degradation of lignocellulose, as in the production of ethanol from lignocellulosic material, through the use of ultrasonic treatment. The invention shows that ultrasonic treatment reduces cellulase requirements by 1/3 to 1/2. With the cost of enzymes being a major problem in the cost-effective production of ethanol from lignocellulosic material, this invention presents a significant improvement over presently available methods.

  10. Millennium Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Millennium Ethanol, LLC Place: Marion, South Dakota Zip: 57043 Product: Millennium Ethanol is a group of more than 900 South Dakotan...

  11. East Coast Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: East Coast Ethanol Place: Columbia, South Carolina Zip: 29202 Product: East Coast Ethanol was formed in August 2007 through a merger...

  12. Marysville Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Marysville Ethanol LLC Jump to: navigation, search Name: Marysville Ethanol LLC Place: Marysville, Michigan Zip: 48040 Product: Developing a 50m gallon ethanol plant in Marysville,...

  13. Great Valley Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Valley Ethanol LLC Jump to: navigation, search Name: Great Valley Ethanol LLC Place: Bakersfield, California Product: Developing a 63m gallon ethanol plant in Hanford, CA...

  14. Central Indiana Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Indiana Ethanol LLC Jump to: navigation, search Name: Central Indiana Ethanol LLC Place: Marion, Indiana Zip: 46952 Product: Ethanol producer developina a 151 mlpa plant in Marion,...

  15. SRSL Ethanol Limited | Open Energy Information

    Open Energy Info (EERE)

    SRSL Ethanol Limited Jump to: navigation, search Name: SRSL Ethanol Limited Place: Mumbai, Maharashtra, India Product: Mumbai-based ethanol subsidiary of Shree Renuka Sugars...

  16. Kansas Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Kansas Ethanol LLC Place: Lyons, Kansas Zip: 67554 Product: Constructing a 55m gallon ethanol plant in Rice County, Kansas...

  17. Chief Ethanol Fuels Inc | Open Energy Information

    Open Energy Info (EERE)

    Fuels Inc Jump to: navigation, search Name: Chief Ethanol Fuels Inc Place: Hastings, Nebraska Product: Ethanol producer and supplier References: Chief Ethanol Fuels Inc1 This...

  18. Heartland Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Heartland Ethanol LLC Place: Knoxville, Tennessee Zip: 37929 Product: Knoxville, TN based ethanol developer. Coordinates: 35.960495,...

  19. Standard Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Standard Ethanol LLC Place: Nebraska Product: Nebraska based ethanol producer that operates two plants References: Standard Ethanol LLC1 This article is a stub. You can help...

  20. Ethanol Capital Funding | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Capital Funding Jump to: navigation, search Name: Ethanol Capital Funding Place: Atlanta, Georgia Zip: 30328 Product: Provides funding for ethanol and biodiesel plants....

  1. Michigan Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Michigan Ethanol LLC Place: Caro, Michigan Zip: 48723-8804 Product: Ethanol productor in Caro, Michigan. Coordinates: 43.488705,...

  2. Siouxland Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Siouxland Ethanol LLC Place: Jackson, Nebraska Zip: 68743 Product: Startup hoping to build a USD 80m ethanol manufacturing plant near...

  3. Platinum Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Platinum Ethanol LLC Jump to: navigation, search Name: Platinum Ethanol LLC Place: Arthut, Iowa Product: Developed a 110m gallon (416m litre) ethanol plant in Arthur, IA....

  4. Nedak Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Nedak Ethanol LLC Jump to: navigation, search Name: Nedak Ethanol LLC Place: Atkinson, Nebraska Zip: 68713 Product: NEDAK Ethanol, LLC is a Nebraska limited liability company,...

  5. North Country Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Country Ethanol LLC Jump to: navigation, search Name: North Country Ethanol LLC Place: Rosholt, South Dakota Zip: 57260 Product: 20mmgy (75.7m litresy) ethanol producer....

  6. South Louisiana Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    South Louisiana Ethanol LLC Place: Louisiana Product: Ethanol production equipment provider. References: South Louisiana Ethanol LLC1 This article is a stub. You can help OpenEI...

  7. Show Me Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Show Me Ethanol LLC Jump to: navigation, search Name: Show Me Ethanol, LLC Place: Carrollton, Missouri Zip: 64633 Product: Developing an ethanol project in Carrollton, Missouri....

  8. Western Ethanol Company LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Company LLC Jump to: navigation, search Name: Western Ethanol Company LLC Place: Placentia, California Zip: 92871 Product: California-based fuel ethanol distribution and...

  9. Pacific Ethanol, Inc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pacific Ethanol, Inc Pacific Ethanol, Inc Design and build a demonstration cellulosic ethanol plant in Boardman. PDF icon pacificethanolfactsheet040308.pdf More Documents & ...

  10. TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

    SciTech Connect (OSTI)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-05-31

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 {micro}m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion (<1200 mg/l). (4) Experimental tests with sludge batch 6 simulant and field turbidity data from a recent Tank 21 mixing evolution suggest the solid particles have higher density and/or larger size than indicated by previous analysis of SRS sludge and sludge simulants. (5) Tank 21 waste characterization, laboratory settling tests, and additional field turbidity measurements during mixing evolutions are recommended to better understand potential risk for extended (> 60 days) settling times in Tank 21.

  11. Lipid-enhanced ethanol production from xylose by Pachysolen tannophilus

    SciTech Connect (OSTI)

    Dekker, R.F.H.

    1986-04-01

    A number of different yeasts are now recognized as being capable of fermenting the pentose sugar, D-xylose, into ethanol. The most prominent among these are Pachysolen tannophilus and several Candida species. D-Xylose is found principally in lignocellulosic materials where it occurs as the main constitutent of the hemicellulosic xylans (1,4-..beta..-D-heteroxylans). With the exception of Candida XF-217, the conversion yields of xylose into ethanol for most yeasts were generally low (less than 70% of theoretical when grown on at least 50 g/l xylose). The low ethanol yields are attributable to a number of factors: 1) fermentation was not performed under conditions that maximize ethanol formation; 2) ethanol was not the major fermentation end-product, (e.g., acetic acid xylitol, and arabinitol are also known products, 3) ethanol toxicity; 4) ethanol is assimilated when the substrate becomes limiting; 4.8 and 5) osmotic sensitivity to high substrate levels, i.e. substrate inhibition. Attempts to increase ethanol yields of yeasts by adding exogenous lipids (e.g., oleic and linoleic acids, or ergosterol or its ester, lipid mixtures, or protein-lipid mixtures) to nutrient medium have succeeded in improving ethanol yields and also in reducing fermentation times. These lipids, when added to the nutrient medium, were incorporated into the yeast's cellular membrane. The protective action of these lipids was to alleviate the inhibitory effect of ethanol which then allowed the cells to tolerate higher ethanol levels. This communication reports on improved ethanol yields arising from the fermentation of xylose by a Pachysolen tannophilus strain when grown semi-aerobically in the presence of exogenous-added lipids. 17 references.

  12. Method to blend separator powders

    DOE Patents [OSTI]

    Guidotti, Ronald A.; Andazola, Arthur H.; Reinhardt, Frederick W.

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  13. Ethanol oxidation on metal oxide-supported platinum catalysts

    SciTech Connect (OSTI)

    L. M. Petkovic 090468; Sergey N. Rashkeev; D. M. Ginosar

    2009-09-01

    Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on the standard three-way catalysts, the conversion of unburned ethanol is low because both ethanol and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of stoves that burn ethanol molecules and their partially oxidized derivatives to the final products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of stoves that burn ethanol molecules and their partially oxidized derivatives to the final products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.

  14. Ethanol 2000 | Open Energy Information

    Open Energy Info (EERE)

    Ethanol 2000 Place: Bingham lake, Minnesota Zip: 56118 Product: Farmer-owned bioethanol producer References: Ethanol 20001 This article is a stub. You can help OpenEI by...

  15. Orion Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Orion Ethanol Place: Pratt, Kansas Zip: 67124 Product: A Kansas-based ethanol producer. Coordinates: 38.209925, -81.383804 Show Map Loading map... "minzoom":false,"mappingserv...

  16. Ozark Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ozark Ethanol Place: Missouri Zip: 64762 Product: Missouri-based bioethanol producer planning to develop a 204m-litre per year ethanol plant in Vernon County. References: Ozark...

  17. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito

    2008-05-15

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  18. Ethanol Myths Fact Sheet

    SciTech Connect (OSTI)

    2009-10-27

    Ethanol is a clean, renewable fuel that is helping to reduce our nation’s dependence on oil and can offer additional economic and environmental benefits in the future. This fact sheet is intended to address some common misconceptions about this important alternative fuel.

  19. Sorghum to Ethanol Research

    SciTech Connect (OSTI)

    Dahlberg, Jeff; Wolfrum, Ed

    2010-06-30

    The development of a robust source of renewable transportation fuel will require a large amount of biomass feedstocks. It is generally accepted that in addition to agricultural and forestry residues, we will need crops grown specifically for subsequent conversion into fuels. There has been a lot of research on several of these so-called “dedicated bioenergy crops” including switchgrass, miscanthus, sugarcane, and poplar. It is likely that all of these crops will end up playing a role as feedstocks, depending on local environmental and market conditions. Many different types of sorghum have been grown to produce syrup, grain, and animal feed for many years. It has several features that may make it as compelling as other crops mentioned above as a renewable, sustainable biomass feedstock; however, very little work has been done to investigate sorghum as a dedicated bioenergy crop. The goal of this project was to investigate the feasibility of using sorghum biomass to produce ethanol. The work performed included a detailed examination of the agronomics and composition of a large number of sorghum varieties, laboratory experiments to convert sorghum to ethanol, and economic and life-cycle analyses of the sorghum-to-ethanol process. This work showed that sorghum has a very wide range of composition, which depended on the specific sorghum cultivar as well as the growing conditions. The results of laboratory- and pilot-scale experiments indicated that a typical high-biomass sorghum variety performed very similarly to corn stover during the multi-step process required to convert biomass feedstocks to ethanol; yields of ethanol for sorghum were very similar to the corn stover used as a control in these experiments. Based on multi-year agronomic data and theoretical ethanol production, sorghum can achieve more than 1,300 gallons of ethanol per acre given the correct genetics and environment. In summary, sorghum may be a compelling dedicated bioenergy crop that could help provide a major portion of the feedstocks required to produce renewable domestic transportation fuels.

  20. Sorghum to Ethanol Research

    SciTech Connect (OSTI)

    Jeff Dahlberg, Ph D; Ed Wolfrum, Ph D

    2010-06-30

    The development of a robust source of renewable transportation fuel will require a large amount of biomass feedstocks. It is generally accepted that in addition to agricultural and forestry residues, we will need crops grown specifically for subsequent conversion into fuels. There has been a lot of research on several of these so-called "dedicated bioenergy crops" including switchgrass, miscanthus, sugarcane, and poplar. It is likely that all of these crops will end up playing a role as feedstocks, depending on local environmental and market conditions. Many different types of sorghum have been grown to produce syrup, grain, and animal feed for many years. It has several features that may make it as compelling as other crops mentioned above as a renewable, sustainable biomass feedstock; however, very little work has been done to investigate sorghum as a dedicated bioenergy crop. The goal of this project was to investigate the feasibility of using sorghum biomass to produce ethanol. The work performed included a detailed examination of the agronomics and composition of a large number of sorghum varieties, laboratory experiments to convert sorghum to ethanol, and economic and life-cycle analyses of the sorghum-to-ethanol process. This work showed that sorghum has a very wide range of composition, which depended on the specific sorghum cultivar as well as the growing conditions. The results of laboratory- and pilot-scale experiments indicated that a typical high-biomass sorghum variety performed very similarly to corn stover during the multi-step process required to convert biomass feedstocks to ethanol; yields of ethanol for sorghum were very similar to the corn stover used as a control in these experiments. Based on multi-year agronomic data and theoretical ethanol production, sorghum can achieve more than 1,300 gallons of ethanol per acre given the correct genetics and environment. In summary, sorghum may be a compelling dedicated bioenergy crop that could help provide a major portion of the feedstocks required to produce renewable domestic transportation fuels.

  1. Intrinsically safe moisture blending system

    DOE Patents [OSTI]

    Hallman Jr., Russell L.; Vanatta, Paul D.

    2012-09-11

    A system for providing an adjustable blend of fluids to an application process is disclosed. The system uses a source of a first fluid flowing through at least one tube that is permeable to a second fluid and that is disposed in a source of the second fluid to provide the adjustable blend. The temperature of the second fluid is not regulated, and at least one calibration curve is used to predict the volumetric mixture ratio of the second fluid with the first fluid from the permeable tube. The system typically includes a differential pressure valve and a backpressure control valve to set the flow rate through the system.

  2. Alternative Fuels Data Center: Ethanol Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Ethanol Related Links to someone by E-mail Share Alternative Fuels Data Center: Ethanol Related Links on Facebook Tweet about Alternative Fuels Data Center: Ethanol Related Links on Twitter Bookmark Alternative Fuels Data Center: Ethanol Related Links on Google Bookmark Alternative Fuels Data Center: Ethanol Related Links on Delicious Rank Alternative Fuels Data Center: Ethanol Related Links on Digg Find

  3. National Ethanol Conference

    Broader source: Energy.gov [DOE]

    The National Ethanol Conference was held Feb. 15—17 in New Orleans, Louisiana. Bioenergy Technologies Office Technology Manager Alicia Lindauer was in attendance to help communicate the goals of the Energy Department’s Co-Optimization of Fuels & Engines (Co-Optima) initiative. She participated in a panel titled "A Conversation About the Future of U.S. Biofuels Policy," where she discussed the environmental and economic benefits of the initiative.

  4. Federal and State Ethanol and Biodiesel Requirements (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01

    The Energy Policy Act 2005 requires that the use of renewable motor fuels be increased from the 2004 level of just over 4 billion gallons to a minimum of 7.5 billion gallons in 2012, after which the requirement grows at a rate equal to the growth of the gasoline pool. The law does not require that every gallon of gasoline or diesel fuel be blended with renewable fuels. Refiners are free to use renewable fuels, such as ethanol and biodiesel, in geographic regions and fuel formulations that make the most sense, as long as they meet the overall standard. Conventional gasoline and diesel can be blended with renewables without any change to the petroleum components, although fuels used in areas with air quality problems are likely to require adjustment to the base gasoline or diesel fuel if they are to be blended with renewables.

  5. Bioenergy Impacts … Cellulosic Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for its cellulosic ethanol biorefinery. Farmers earned additional revenue from selling their leftover corn husks, stalks, and leaves to the POET-DSM biorefinery for production of ...

  6. Federal / State Legislative & Regulatory Changes Required for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EPA Waiver Decision E15 Implementation Issues Federal and State Blending Restrictions Action by ASTM NCWM to address higher ethanol blends PDF icon Federal State Legislative & ...

  7. Federal / State Legislative & Regulatory Changes Required for Introduction of E15

    Broader source: Energy.gov [DOE]

    EPA Waiver Decision, E15 Implementation Issues, Federal and State Blending Restrictions, Action by ASTM / NCWM to address higher ethanol blends

  8. Northern Lights Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Lights Ethanol LLC Jump to: navigation, search Name: Northern Lights Ethanol LLC Place: Big Stone City, South Dakota Zip: 57216 Product: 75mmgy (283.9m litresy) ethanol producer....

  9. Prairie Creek Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Prairie Creek Ethanol LLC Place: Goldfield, Iowa Zip: 50542 Product: Prairie Creek Ethanol, LLC had planned to build a 55m gallon...

  10. Tharaldson Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Tharaldson Ethanol LLC Jump to: navigation, search Name: Tharaldson Ethanol LLC Place: Casselton, North Dakota Zip: 58012 Product: Owner of a USD 200m 120m-gallon ethanol plant in...

  11. United Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    United Ethanol LLC Place: Wisconsin Product: Developed a 43m gallon ethanol plant in Milton, Wisconsin. References: United Ethanol LLC1 This article is a stub. You can help...

  12. Horizon Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Horizon Ethanol LLC Place: Jewell, Iowa Zip: 50130 Product: 60mmgy (227.1m litrey) ethanol producers in Jewell, Iowa. Coordinates:...

  13. First United Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: First United Ethanol LLC Place: Camilla, Georgia Zip: 31730 Product: First United Ethanol LLC (FUEL) was formed to construct a 100 MGY...

  14. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this

  15. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fueling Stations on

  16. Alternative Fuels Data Center: Ethanol Feedstocks

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Feedstocks to someone by E-mail Share Alternative Fuels Data Center: Ethanol Feedstocks on Facebook Tweet about Alternative Fuels Data Center: Ethanol Feedstocks on Twitter Bookmark Alternative Fuels Data Center: Ethanol Feedstocks on Google Bookmark Alternative Fuels Data Center: Ethanol Feedstocks on Delicious Rank Alternative Fuels Data Center: Ethanol Feedstocks on Digg Find More places to share Alternative Fuels Data Center: Ethanol Feedstocks on AddThis.com... More in this section...

  17. Alternative Fuels Data Center: Ethanol Production

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Production to someone by E-mail Share Alternative Fuels Data Center: Ethanol Production on Facebook Tweet about Alternative Fuels Data Center: Ethanol Production on Twitter Bookmark Alternative Fuels Data Center: Ethanol Production on Google Bookmark Alternative Fuels Data Center: Ethanol Production on Delicious Rank Alternative Fuels Data Center: Ethanol Production on Digg Find More places to share Alternative Fuels Data Center: Ethanol Production on AddThis.com... More in this section...

  18. Center Ethanol Company LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Jump to: navigation, search Name: Center Ethanol Company LLC Place: Illinois Product: Illinois based company building a 54m gallon ethanol plant in Sauget, IL. References:...

  19. US Ethanol Vehicle Coalition | Open Energy Information

    Open Energy Info (EERE)

    Vehicle Coalition Jump to: navigation, search Name: US Ethanol Vehicle Coalition Place: Jefferson City, Missouri Zip: 65109 Product: The National Ethanol Vehicle Coalition is the...

  20. Louisiana: Verenium Cellulosic Ethanol Demonstration Facility...

    Energy Savers [EERE]

    Louisiana: Verenium Cellulosic Ethanol Demonstration Facility Louisiana: Verenium Cellulosic Ethanol Demonstration Facility April 9, 2013 - 12:00am Addthis In 2010, Verenium...

  1. Ethanol Capital Management | Open Energy Information

    Open Energy Info (EERE)

    Management Jump to: navigation, search Name: Ethanol Capital Management Place: Tucson, Arizona Zip: 85711 Product: Manages funds investing in Ethanol plants in the US Coordinates:...

  2. Blue Flint Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Flint Ethanol Jump to: navigation, search Name: Blue Flint Ethanol Place: Underwood, North Dakota Zip: ND 58576 Product: Joint Venture bentween Great River Energy and Headwaters...

  3. Prairie Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Prairie Ethanol LLC Place: Loomis, South Dakota Product: Farmer owned bioethanol project development and managment team. Coordinates:...

  4. Great Plains Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Great Plains Ethanol Place: Chancellor, South Dakota Zip: 57015 Product: Limited liability company owned by its 500 members which owns and...

  5. Chief Ethanol Fuels | Open Energy Information

    Open Energy Info (EERE)

    Fuels Jump to: navigation, search Name: Chief Ethanol Fuels Place: Hastings, NE Website: www.chiefethanolfuels.com References: Chief Ethanol Fuels1 Information About Partnership...

  6. Evergreen Securities formerly Ethanol Investments | Open Energy...

    Open Energy Info (EERE)

    Securities formerly Ethanol Investments Jump to: navigation, search Name: Evergreen Securities (formerly Ethanol Investments) Place: London, England, United Kingdom Zip: EC2V 5DE...

  7. Missouri Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Missouri Ethanol LLC Place: Laddonia, Missouri Product: 45mmgy (170.3m litresy) ethanol producer. Coordinates: 39.24073, -91.645599 Show Map Loading map......

  8. BlueFire Ethanol | Open Energy Information

    Open Energy Info (EERE)

    BlueFire Ethanol Jump to: navigation, search Name: BlueFire Ethanol Place: Irvine, California Zip: 92618 Sector: Hydro Product: US biofuel producer that utilises a patented...

  9. Badger State Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    State Ethanol LLC Jump to: navigation, search Name: Badger State Ethanol LLC Place: Monroe, Wisconsin Zip: 53566 Product: Dry-mill bioethanol producer References: Badger State...

  10. Iowa Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Iowa Ethanol LLC Place: Hanlontown, Iowa Zip: 50451 Product: Corn-base bioethanol producer in Iowa Coordinates: 43.28456,...

  11. James Valley Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    James Valley Ethanol LLC Place: Gronton, South Dakota Zip: 57445 Product: Farmers owned cooperative that built and operates an ethanol production facility. Coordinates: 29.72369,...

  12. Algodyne Ethanol Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    Algodyne Ethanol Energy Inc Jump to: navigation, search Name: Algodyne Ethanol Energy Inc Place: Las Vegas, Nevada Zip: 89145 Sector: Biofuels Product: Holds proprietary...

  13. Tall Corn Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Tall Corn Ethanol LLC Jump to: navigation, search Name: Tall Corn Ethanol LLC Place: Coon Rapids, Iowa Zip: 50058 Product: Farmer owned bioethanol production company which owns a...

  14. Frontier Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Frontier Ethanol LLC Place: Gowrie, Iowa Product: Owner and operator of a bioethanol plant near Gowrie, Iowa. Coordinates: 42.28227,...

  15. Ethanol Management Company | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Management Company Place: Colorado Product: Biofuel blender located in Denver, Colorado. References: Ethanol Management Company1 This article is a stub. You can help...

  16. Ethanol Grain Processors LLC | Open Energy Information

    Open Energy Info (EERE)

    Processors LLC Jump to: navigation, search Name: Ethanol Grain Processors, LLC Place: Obion, Tennessee Zip: TN 38240 Product: Tennessee-based ethanol producer. Coordinates:...

  17. Kaapa Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Kaapa Ethanol LLC Jump to: navigation, search Name: Kaapa Ethanol LLC Place: Minden, Nebraska Zip: 68959 Product: Bioethanol producer using corn as feedstock Coordinates:...

  18. Gulf Ethanol Corp | Open Energy Information

    Open Energy Info (EERE)

    Gulf Ethanol Corp Jump to: navigation, search Name: Gulf Ethanol Corp Place: Houston, Texas Zip: 77055 Sector: Biomass Product: Focused on developing biomass preprocessing...

  19. Didion Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Didion Ethanol LLC Jump to: navigation, search Name: Didion Ethanol LLC Place: Cambria, Wisconsin Zip: 53923 Product: Also Didion Milling LLC, Grand River Distribution LLC....

  20. Atlantic Ethanol Capital | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Capital Jump to: navigation, search Name: Atlantic Ethanol Capital Place: Washington, Washington, DC Product: Biofuel Investor in Caribbean and Central American region....

  1. Platte Valley Fuel Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Valley Fuel Ethanol Jump to: navigation, search Name: Platte Valley Fuel Ethanol Place: Central City, Nebraska Product: Bioethanol producer using corn as feedstock References:...

  2. Ethanol production in non-recombinant hosts

    SciTech Connect (OSTI)

    Kim, Youngnyun; Shanmugam, Keelnatham; Ingram, Lonnie O.

    2013-06-18

    Non-recombinant bacteria that produce ethanol as the primary fermentation product, associated nucleic acids and polypeptides, methods for producing ethanol using the bacteria, and kits are disclosed.

  3. Thermophilic microbes in ethanol production

    SciTech Connect (OSTI)

    Slapack, G.E.; Russell, I.; Stewart, G.G.

    1987-01-01

    General and specific properties of thermophilic ethanol-producing bacteria are reviewed and their relative merits in ethanol production assessed. The studies examine the use of bacteria in mono- and co-culture fermentations for ethanol production from cellulosics; in particular, the cellulase system of Clostridium thermocellum is considered. Thermotolerant yeasts and physiological factors influencing their growth and fermentation at high temperatures are discussed. Emphasis is placed on multidisciplinary approaches to develop economical processes for ethanol production at high temperatures. Relevant topics considered include: adaptation, nutrition, heat shock, ethanol tolerance, metabolic control, genetic improvement, and fermentation/process design. General aspects of thermophily for both bacteria and yeasts (definitions, ecological aspects, merits and limitations, other industrial uses, thermostability of cellular components, and consequences of thermophilic fermentation) are discussed and the volume references over 1100 relevant articles.

  4. Tropexx - Blending System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Tropexx - Blending System Y-12 National Security Complex Contact Y12 About This Technology Publications: PDF Document Publication Fact Sheet (784 KB) PDF Document Publication Patent (88 KB) Technology Marketing SummaryThe Tropexx Blending System is a high-resolution blending system that works with gases, vapors and volatile (readily vaporizable) liquids in addition to moisture. Tropexx can be used to check

  5. UPDATED: Energy Department Announces New Advance in Biofuel Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    savings in processing costs and time, plus isobutanol is a higher grade of alcohol than ethanol. "Unlike ethanol, isobutanol can be blended at any ratio with gasoline ...

  6. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance of Biofuels and Biofuel Blends Robert McCormick Vehicle Technologies Program Merit Review - Fuels and Lubricants Technologies May 16, 2013 Project ID: FT003 This ...

  7. Higher Education

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Education Higher Education Higher Education Explore the multiple dimensions of a career at LANL: work with brilliant minds in an inclusive environment rich in intellectual...

  8. BlueFire Ethanol | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BlueFire Ethanol BlueFire Ethanol Construct and operate a facility that converts green waste and lignocellulosic fractions diverted from landfills or Southern California Materials Recovery Facilities to ethanol and other products. PDF icon bluefire_fact_sheet_12_9_08.pdf More Documents & Publications BlueFire Ethanol, Inc. Applicant Organization: EA-1704: Mitigation Action Plan

  9. Pacific Ethanol, Inc | Department of Energy

    Office of Environmental Management (EM)

    Verenium Biofuels Fact Sheet Pacific Ethanol, Inc Verenium Pilot- and Demonstration-Scale Biorefinery

  10. Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses

    SciTech Connect (OSTI)

    Yang, Shihui; Pan, Chongle; Tschaplinski, Timothy J; Hurst, Gregory {Greg} B; Engle, Nancy L; Zhou, Wen; Dam, Phuongan; Xu, Ying; Dice, Lezlee T; Davison, Brian H; Brown, Steven D

    2013-01-01

    Zymomonas mobilis ZM4 is a capable ethanogenic bacterium with high ethanol productivity and high level of ethanol tolerance. Previous studies indicated that several stress-related proteins and changes in the ZM4 membrane lipid composition may contribute to ethanol tolerance. However, the molecular mechanisms of ethanol stress response have not been elucidated fully. In this study, ethanol stress responses were investigated using systems biology tools. Medium supplementation with an initial 47.3 g/L (6% v/v) ethanol reduced Z. mobilis ZM4 glucose consumption, growth rate and ethanol productivity compared to that of untreated controls. Metabolomic profiling showed that ethanol-treated ZM4 cells accumulated greater amounts of glycerol during the entire fermentation process, which may indicate an important role for this metabolite. A proteomic analysis of early exponential growth identified about one thousand proteins, or approximately 56% of the predicted ZM4 proteome. Proteins related to metabolism and stress response such as chaperones and key regulators were more abundant in the early ethanol stress condition. Transcriptomic studies indicated the response of ZM4 to ethanol is dynamic, complex and involves many genes from all the different functional categories. There were fewer genes significantly differentially expressed in the exponential phase compared to that of stationary phase and early stationary phase. Most down-regulated genes were related to translation and ribosome biogenesis, while the ethanol-upregulated genes were mostly related to cellular processes and metabolism. Correlations among the transcriptomics, proteomics and metabolism were examined and among significantly expressed genes or proteins, we observe higher correlation coefficients when fold-change values are higher. This systems biology study elucidates key Z. mobilis ZM4 metabolites, genes and proteins that form the foundation of its distinctive physiology and its multifaceted response to ethanol stress.

  11. A Multicomponent Blend as a Diesel Fuel Surrogate for Compression...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications Title A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition...

  12. Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HCCI Exhaust Speciation - ORNL Reference Fuel Blends Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends *Accurately measure exhaust profile from an HCCI engine with a ...

  13. Sandia Energy - Biofuels Blend Right In: Researchers Show Ionic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks Home Renewable Energy Energy Transportation Energy Biofuels...

  14. PAIRWISE BLENDING OF HIGH LEVEL WASTE (HLW)

    SciTech Connect (OSTI)

    CERTA, P.J.

    2006-02-22

    The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending.

  15. Green emitting phosphors and blends thereof

    DOE Patents [OSTI]

    Setlur, Anant Achyut; Siclovan, Oltea Puica; Nammalwar, Prasanth Kumar; Sathyanarayan, Ramesh Rao; Porob, Digamber G.; Chandran, Ramachandran Gopi; Heward, William Jordan; Radkov, Emil Vergilov; Briel, Linda Jane Valyou

    2010-12-28

    Phosphor compositions, blends thereof and light emitting devices including white light emitting LED based devices, and backlights, based on such phosphor compositions. The devices include a light source and a phosphor material as described. Also disclosed are phosphor blends including such a phosphor and devices made therefrom.

  16. Hydrogen effects on materials for CNG/H2 blends.

    SciTech Connect (OSTI)

    Farese, David; Keller, Jay O.; Somerday, Brian P.

    2010-09-01

    No concerns for Hydrogen-Enriched Compressed Natural gas (HCNG) in steel storage tanks if material strength is < 950 MPa. Recommend evaluating H{sub 2}-assisted fatigue cracking in higher strength steels at H{sub 2} partial pressure in blend. Limited fatigue testing on higher strength steel cylinders in H{sub 2} shows promising results. Impurities in Compressed Natural Gas (CNG) (e.g., CO) may provide extrinsic mechanism for mitigating H{sub 2}-assisted fatigue cracking in steel tanks.

  17. Ethanol Ventures | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Ventures Place: London, England, United Kingdom Zip: W1D 3SQ Product: Company aims to deliver at least 378 million litres a year of bioethanol from two Facilities in...

  18. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights

    2009-05-15

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  19. Ethanol production with dilute acid hydrolysis using partially dried lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A.; Keller, Fred A.; Tucker, Melvin P.

    2003-12-09

    A process of converting lignocellulosic biomass to ethanol, comprising hydrolyzing lignocellulosic materials by subjecting dried lignocellulosic material in a reactor to a catalyst comprised of a dilute solution of a strong acid and a metal salt to lower the activation energy (i.e., the temperature) of cellulose hydrolysis and ultimately obtain higher sugar yields.

  20. Ethanol production in fermentation of mixed sugars containing xylose

    DOE Patents [OSTI]

    Viitanen, Paul V.; Mc Cutchen, Carol M.; Li; Xu; Emptage, Mark; Caimi, Perry G.; Zhang, Min; Chou, Yat-Chen; Franden, Mary Ann

    2009-12-08

    Xylose-utilizing Z. mobilis strains were found to have improved ethanol production when grown in medium containing mixed sugars including xylose if sorbitol or mannitol was included in the medium. The effect was seen in concentrations of mixed sugars where no growth lag period occurs, as well as in higher sugars concentrations.

  1. Resistance of fly ash-Portland cement blends to thermal shock

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pyatina, Tatiana; Sugama, Toshifumi

    2015-09-11

    Thermal-shock resistance of high-content fly ash-Portland cement blends was tested in the following ways. Activated and non-activated blends with 80-90 % fly ash F (FAF) were left to set at room temperature, then hydrated for 24 hours at 85°C and 24-more hours at 300°C and tested in five thermal-shock cycles (600°C heat - 25°C water quenching). XRD, and thermal gravimetric analyses, along with calorimetric measurements and SEM-EDX tests demonstrated that the activated blends form more hydrates after 24 hours at 300°C, and achieve a higher short-term compressive strength than do non-activated ones. Sodium meta-silicate and sodaash engendered the concomitant hydrationmore » of OPC and FAF, with the formation of mixed crystalline FAF-OPC hydrates and FAF hydrates, such as garranite, analcime, and wairakite, along with the amorphous FAF hydration products. In SS-activated and non-activated blends separate OPC (tobermorite) and FAF (amorphous gel) hydrates with no mixed crystalline products formed. The compressive strength of all tested blends decreased by nearly 50% after 5 thermal-shock test cycles. These changes in the compressive strength were accompanied by a marked decrease in the intensities of XRD patterns of the crystalline hydrates after the thermalshock. As a result, there was no significant difference in the performance of the blends with different activators« less

  2. Resistance of fly ash-Portland cement blends to thermal shock

    SciTech Connect (OSTI)

    Pyatina, Tatiana; Sugama, Toshifumi

    2015-09-11

    Thermal-shock resistance of high-content fly ash-Portland cement blends was tested in the following ways. Activated and non-activated blends with 80-90 % fly ash F (FAF) were left to set at room temperature, then hydrated for 24 hours at 85°C and 24-more hours at 300°C and tested in five thermal-shock cycles (600°C heat - 25°C water quenching). XRD, and thermal gravimetric analyses, along with calorimetric measurements and SEM-EDX tests demonstrated that the activated blends form more hydrates after 24 hours at 300°C, and achieve a higher short-term compressive strength than do non-activated ones. Sodium meta-silicate and sodaash engendered the concomitant hydration of OPC and FAF, with the formation of mixed crystalline FAF-OPC hydrates and FAF hydrates, such as garranite, analcime, and wairakite, along with the amorphous FAF hydration products. In SS-activated and non-activated blends separate OPC (tobermorite) and FAF (amorphous gel) hydrates with no mixed crystalline products formed. The compressive strength of all tested blends decreased by nearly 50% after 5 thermal-shock test cycles. These changes in the compressive strength were accompanied by a marked decrease in the intensities of XRD patterns of the crystalline hydrates after the thermalshock. As a result, there was no significant difference in the performance of the blends with different activators

  3. California Ethanol Power CE P | Open Energy Information

    Open Energy Info (EERE)

    Power CE P Jump to: navigation, search Name: California Ethanol & Power (CE+P) Place: Florida Product: US ethanol project developer. References: California Ethanol & Power...

  4. Conesul Sugar and Ethanol Plant | Open Energy Information

    Open Energy Info (EERE)

    Conesul Sugar and Ethanol Plant Jump to: navigation, search Name: Conesul Sugar and Ethanol Plant Place: Brazil Product: Brazilian ethanol producer References: Conesul Sugar and...

  5. Agri Ethanol Products LLC AEPNC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Products LLC AEPNC Jump to: navigation, search Name: Agri-Ethanol Products LLC (AEPNC) Place: Raleigh, North Carolina Zip: 27615 Product: Ethanol producer and project...

  6. Grupo Maris Capital ethanol refinery | Open Energy Information

    Open Energy Info (EERE)

    Maris Capital ethanol refinery Jump to: navigation, search Name: Grupo Maris (Capital ethanol refinery) Place: Nuporanga, Brazil Product: 32,000 m3 ethanol refinery owner...

  7. Midwest Ethanol Producers Inc MEPI | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Producers Inc MEPI Jump to: navigation, search Name: Midwest Ethanol Producers Inc (MEPI) Place: O'Neill, Nebraska Zip: 68763 Product: Focused on ethanol production....

  8. Baicheng Tingfeng Ethanol Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Tingfeng Ethanol Co Ltd Jump to: navigation, search Name: Baicheng Tingfeng Ethanol Co Ltd Place: Baicheng, Jilin Province, China Zip: 137000 Product: The company is a ethanol...

  9. DuPont Danisco Cellulosic Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Danisco Cellulosic Ethanol Jump to: navigation, search Name: DuPont Danisco Cellulosic Ethanol Place: Itasca, Illinois Zip: 60143 Product: DuPont Danisco Cellulosic Ethanol is a...

  10. Tampa Bay Area Ethanol Consortium | Open Energy Information

    Open Energy Info (EERE)

    Bay Area Ethanol Consortium Jump to: navigation, search Name: Tampa Bay Area Ethanol Consortium Place: Tampa, Florida Sector: Biomass Product: Consortium researching ethanol from...

  11. National Ethanol Vehicle Coalition NEVC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Vehicle Coalition NEVC Jump to: navigation, search Name: National Ethanol Vehicle Coalition (NEVC) Place: Jefferson City, Missouri Zip: 65109 Product: The National Ethanol...

  12. Emissions with butane/propane blends

    SciTech Connect (OSTI)

    1996-11-01

    This article reports on various aspects of exhaust emissions from a light-duty car converted to operate on liquefied petroleum gas and equipped with an electrically heated catalyst. Butane and butane/propane blends have recently received attention as potentially useful alternative fuels. Butane has a road octane number of 92, a high blending vapor pressure, and has been used to upgrade octane levels of gasoline blends and improve winter cold starts. Due to reformulated gasoline requirements for fuel vapor pressure, however, industry has had to remove increasing amounts of butane form the gasoline pool. Paradoxically, butane is one of the cleanest burning components of gasoline.

  13. Two glass transitions in miscible polymer blends?

    SciTech Connect (OSTI)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-06-28

    In contrast to mixtures of two small molecule fluids, miscible binary polymer blends often exhibit two structural relaxation times and two glass transition temperatures. Qualitative explanations postulate phenomenological models of local concentration enhancements due to chain connectivity in ideal, fully miscible systems. We develop a quantitative theory that explains qualitative trends in the dynamics of real miscible polymer blends which are never ideal mixtures. The theory is a synthesis of the lattice cluster theory of blend thermodynamics, the generalized entropy theory for glass-formation in polymer materials, and the Kirkwood-Buff theory for concentration fluctuations in binary mixtures.

  14. Fermentation pattern of sucrose to ethanol conversions by Zymomonas mobilis

    SciTech Connect (OSTI)

    Lyness, E.; Doelle, H.W.

    1981-07-01

    General patterns of sucrose fermentation by two strains of Zymomonas mobilis, designated Z7 and Z10, were established using sucrose concentrations from 50 to 200 g/liter. Strain Z7 showed a higher invertase activity than Z10. Strain Z10 showed a reduced specific growth rate at high sucrose concentrations while Z7 was unaffected. High sucrose hydrolyzing activity in strain Z7 lead to glucose accumulation in the medium at high sucrose concentrations. Ethanol production and fermentation time depend on the rate of catabolism of the products of sucrose hydrolysis, glucose and fructose. The metabolic quotients for sucrose utilization, qs, and ethanol production, qp (g/g.hr), are unsuitable for describing sucrose utilization by Zymomonas mobilis as the logarithmic phase of growth precedes the phase of highest substrate utilization (g/liter.hr) and ethanol production (g/liter.hr) in batch culture. (Refs. 10).

  15. Higher Education

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Education » Higher Education Higher Education Explore the multiple dimensions of a career at LANL: work with brilliant minds in an inclusive environment rich in intellectual vitality and opportunities for growth. Contact Education Janelle Vigil-Maestas Community Relations & Partnerships (505) 665-4329 Email "The partnership between LANL and regional colleges creates opportunities for students like me to attain challenging and rewarding careers." - Sherry Salas Bachicha Higher

  16. Ethanol production method and system

    DOE Patents [OSTI]

    Chen, M.J.; Rathke, J.W.

    1983-05-26

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  17. WI Biodiesel Blending Progream Final Report

    SciTech Connect (OSTI)

    Redmond, Maria E; Levy, Megan M

    2013-04-01

    The Wisconsin State Energy Office?¢????s (SEO) primary mission is to implement cost?¢???effective, reliable, balanced, and environmentally?¢???friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

  18. Blending municipal solid waste with corn stover for sugar production using ionic liquid process

    SciTech Connect (OSTI)

    Sun, Ning; Xu, Feng; Sathitsuksanoh, Noppadon; Thompson, Vicki S.; Cafferty, Kara; Li, Chenlin; Tanjore, Deepti; Narani, Akash; Pray, Todd R.; Simmons, Blake A.; Singh, Seema

    2015-06-01

    Municipal solid waste (MSW) represents an attractive cellulosic resource for sustainable fuel production because of its abundance and its low or perhaps negative cost. However, the significant heterogeneity and toxic contaminants are barriers to efficient conversion to ethanol and other products. In this study, we generated MSW paper mix, blended with corn stover (CS), and have shown that both MSW paper mix alone and MSW/CS blends can be efficiently pretreated in certain ionic liquids (ILs) with high yields of fermentable sugars. After pretreatment in 1-ethyl-3-methylimidazolium acetate ([C2C1Im][OAc]), over 80% glucose has been released with enzymatic saccharification. We have also applied an enzyme free process by adding mineral acid and water directly into the IL/biomass slurry to induce hydrolysis. With the acidolysis process in the IL 1-ethyl-3-methylimidazolium chloride ([C2C1Im]Cl), up to 80% glucose and 90% xylose are released for MSW. The results indicate the feasibility of incorporating MSW as a robust blending agent for biorefineries.

  19. US Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Place: Vancouver, Washington State Zip: 98660 Product: Ethanol producer in the north-west. References: US Ethanol LLC1 This article is a stub. You can help OpenEI by...

  20. Elkhorn Valley Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Elkhorn Valley Ethanol LLC Place: Norfolk, Nebraska Zip: 68701 Product: Operates a 40m gallon ethanol plant in Norfolk, Nebraska. Coordinates: 36.846825, -76.285069 Show Map...

  1. Brazil Ethanol Inc | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Inc Jump to: navigation, search Name: Brazil Ethanol Inc. Place: New York, New York Zip: 10021 Product: A New York City-based firm that had raised USD 10.4m as of 1 May...

  2. JH Kelly LLC Ethanol | Open Energy Information

    Open Energy Info (EERE)

    JH Kelly LLC Ethanol Jump to: navigation, search Name: JH Kelly LLC Ethanol Place: Longview, Washington State Zip: 98632 Product: A joint venture company between JH Kelly and and...

  3. Farmers Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Farmers' Ethanol LLC Place: Adamsville, Ohio Zip: OH 43802 Product: An association of farmers registered on July 12,2002 with a goal...

  4. Four Cellulosic Ethanol Breakthroughs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Four Cellulosic Ethanol Breakthroughs Four Cellulosic Ethanol Breakthroughs September 3, 2014 - 1:11pm Addthis Cellulosic ethanol biorefinery 1 of 10 Cellulosic ethanol biorefinery The mechanical building (front), solid/liquid separation building (left), and anaerobic digestion building (back) at POET-DSM's Project LIBERTY biorefinery in Emmetsburg, Iowa. Image: Courtesy of POET-DSM Stacking up biomass 2 of 10 Stacking up biomass The biomass stackyard, where corn waste is stored at POET-DSM's

  5. Re-engineering bacteria for ethanol production

    DOE Patents [OSTI]

    Yomano, Lorraine P; York, Sean W; Zhou, Shengde; Shanmugam, Keelnatham; Ingram, Lonnie O

    2014-05-06

    The invention provides recombinant bacteria, which comprise a full complement of heterologous ethanol production genes. Expression of the full complement of heterologous ethanol production genes causes the recombinant bacteria to produce ethanol as the primary fermentation product when grown in mineral salts medium, without the addition of complex nutrients. Methods for producing the recombinant bacteria and methods for producing ethanol using the recombinant bacteria are also disclosed.

  6. Ethanol's Effect on Grain Supply and Prices

    SciTech Connect (OSTI)

    2008-01-01

    This document provides graphical information about ethanol's effect on grain supply and prices, uses of corn, and grain price trends.

  7. An In-situ X-ray Scattering Study During Uniaxial Stretching of Ionic Liquid/Ultra-high Molecular Weight Polyethylene Blends

    SciTech Connect (OSTI)

    X Li; Y Mao; H Ma; F Zuo; B Hsiao; B Chu

    2011-12-31

    An ionic liquid (IL) 1-docosanyl-3-methylimidazolium bromide was incorporated into ultra-high molecular weight polyethylene (UHMWPE) and formed IL/UHMWPE blends by solution mixing. The structure evolution of these blends during uniaxial stretching was followed by in-situ synchrotron wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) techniques. During deformation at room temperature, deformation-induced phase transformation from orthorhombic to monoclinic phase was observed in both IL/UHMWPE blends and neat UHMWPE. The elongation-to-break ratios of IL/UHMWPE blends were found to increase by 2-3 times compared with that of pure UHMWPE, while the tensile strength remained about the same. In contrast, during deformation at high temperature (120 C), no phase transformation was observed. However, the blend samples showed much better toughness, higher crystal orientation and higher tilting extent of lamellar structure at high strains.

  8. BlueFire Ethanol, Inc. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BlueFire Ethanol, Inc. BlueFire Ethanol, Inc. A proposal issued by BlueFire Ethanol Inc,describing a project that will give DOE understanding of a new biological fermentation process not using enzymes. PDF icon BlueFire Ethanol, Inc. More Documents & Publications Applicant Organization: BlueFire Ethanol Pacific Ethanol, Inc

  9. Development of a dedicated ethanol ultra-low-emissions vehicle (ULEV): Phase 3 report

    SciTech Connect (OSTI)

    Dodge, L.; Callahan, T.; Leone, D.; Naegeli, D.; Shouse, K.; Smith, L.; Whitney, K.

    1998-04-01

    The objective of the 3.5 year project discussed in this report was to develop a commercially competitive vehicle powered by ethanol (or an ethanol blend) that can meet California`s Ultra Low Emissions Vehicle (ULEV) standards and equivalent Corporate Average Fuel Economy (CAFE) energy efficiency for a light duty passenger car application. This particular report summarizes the third phase of the project, which lasted 12 months. Emissions tests were conducted with advanced after-treatment devices on one of the two, almost identical, test vehicles, a 1993 Ford Taurus flexible fuel vehicle. The report also covers tests on the engine removed from the second Taurus vehicle. This engine was modified for an increased compression ratio, fitted with air assist injectors, and included an advanced engine control system with model-based control.

  10. Ethanol production by recombinant hosts

    DOE Patents [OSTI]

    Ingram, Lonnie O.; Beall, David S.; Burchhardt, Gerhard F. H.; Guimaraes, Walter V.; Ohta, Kazuyoshi; Wood, Brent E.; Shanmugam, Keelnatham T.

    1995-01-01

    Novel plasmids comprising genes which code for the alcohol dehydrogenase and pyruvate decarboxylase are described. Also described are recombinant hosts which have been transformed with genes coding for alcohol dehydrogenase and pyruvate. By virtue of their transformation with these genes, the recombinant hosts are capable of producing significant amounts of ethanol as a fermentation product. Also disclosed are methods for increasing the growth of recombinant hosts and methods for reducing the accumulation of undesirable metabolic products in the growth medium of these hosts. Also disclosed are recombinant host capable of producing significant amounts of ethanol as a fermentation product of oligosaccharides and plasmids comprising genes encoding polysaccharases, in addition to the genes described above which code for the alcohol dehydrogenase and pyruvate decarboxylase. Further, methods are described for producing ethanol from oligomeric feedstock using the recombinant hosts described above. Also provided is a method for enhancing the production of functional proteins in a recombinant host comprising overexpressing an adhB gene in the host. Further provided are process designs for fermenting oligosaccharide-containing biomass to ethanol.

  11. Ethanol production by recombinant hosts

    DOE Patents [OSTI]

    Fowler, David E.; Horton, Philip G.; Ben-Bassat, Arie

    1996-01-01

    Novel plasmids comprising genes which code for the alcohol dehydrogenase and pyruvate decarboxylase are described. Also described are recombinant hosts which have been transformed with genes coding for alcohol dehydrogenase and pyruvate. By virtue of their transformation with these genes, the recombinant hosts are capable of producing significant amounts of ethanol as a fermentation product. Also disclosed are methods for increasing the growth of recombinant hosts and methods for reducing the accumulation of undesirable metabolic products in the growth medium of these hosts. Also disclosed are recombinant host capable of producing significant amounts of ethanol as a fermentation product of oligosaccharides and plasmids comprising genes encoding polysaccharases, in addition to the genes described above which code for the alcohol dehydrogenase and pyruvate decarboxylase. Further, methods are described for producing ethanol from oligomeric feedstock using the recombinant hosts described above. Also provided is a method for enhancing the production of functional proteins in a recombinant host comprising overexpressing an adhB gene in the host. Further provided are process designs for fermenting oligosaccharide-containing biomass to ethanol.

  12. Ethanol production in recombinant hosts

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal; Barbosa-Alleyne, Maria D.

    2005-02-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  13. Mutant selection and phenotypic and genetic characterization of ethanol-tolerant strains of Clostridium thermocellum

    SciTech Connect (OSTI)

    Lynd, Lee R; Shao, Xiongjun; Raman, Babu; Mielenz, Jonathan R; Brown, Steven D; Guss, Adam M; Zhu, Mingjun

    2011-01-01

    Clostridium thermocellum is a model microorganism for converting cellulosic biomass into fuels and chemicals via consolidated bioprocessing. One of the challenges for industrial application of this organism is its low ethanol tolerance, typically 1 2% (w/v) in wild-type strains. In this study, we report the development and characterization of mutant C. thermocellum strains that can grow in the presence of high ethanol concentrations. Starting from a single colony, wild-type C. thermocellum ATCC 27405 was sub-cultured and adapted for growth in up to 50 g/L ethanol using either cellobiose or crystalline cellulose as the growth substrate. Both the adapted strains retained their ability to grow on either substrate and displayed a higher growth rate and biomass yield than the wild-type strain in the absence of ethanol. With added ethanol in the media, the mutant strains displayed an inverse correlation between ethanol concentration and growth rate or biomass yield. Genome sequencing revealed six common mutations in the two ethanol-tolerant strains including an alcohol dehydrogenase gene and genes involved in arginine/pyrimidine biosynthetic pathway. The potential role of these mutations in ethanol tolerance phenotype is discussed.

  14. Mutant selection and phenotypic and genetic characterization of ethanol-tolerant strains of Clostridium thermocellum

    SciTech Connect (OSTI)

    Shao, Xiongjun; Raman, Babu; Zhu, Mingjun; Mielenz, Jonathan R; Brown, Steven D; Guss, Adam M; Lynd, Lee R

    2011-01-01

    Clostridium thermocellum is a model microorganism for converting cellulosic biomass into fuels and chemicals via consolidated bioprocessing. One of the challenges for industrial application of this organism is its low ethanol tolerance, typically 1-2% (w/v) in wild-type strains. In this study, we report the development and characterization of mutant C. thermocellum strains that can grow in the presence of high ethanol concentrations. Starting from a single colony, wild-type C. thermocellum ATCC 27405 was sub-cultured and adapted for growth in up to 50 g/L ethanol using either cellobiose or crystalline cellulose as the growth substrate. Both the adapted strains retained their ability to grow on either substrate and displayed a higher growth rate and biomass yield than the wild-type strain in the absence of ethanol. With added ethanol in the media, the mutant strains displayed an inverse correlation between ethanol concentration and growth rate or biomass yield. Genome sequencing revealed six common mutations in the two ethanol-tolerant strains including an alcohol dehydrogenase gene and genes involved in arginine/pyrimidine biosynthetic pathway. The potential role of these mutations in ethanol tolerance phenotype is discussed.

  15. Economics of ethanol fuel for crop production

    SciTech Connect (OSTI)

    Fontana, C.; Rotz, C.A.

    1982-07-01

    A computer model was developed to simulate conventional and ethanol fuel consumption for crop production. The model was validated by obtaining a close comparison between simulated and actual diesel requirements for farms in Michigan. Parameters for ethanol consumption were obtained from laboratory tests using total fueling of spark-ignition engines and dual-fueling of diesel engines with ethanol. Ethanol fuel will always be more economically used in spark-ignition engines than in dual-fueled diesel engines. The price of gasoline must inflate at least 14 percent/year greater than that of ethanol and diesel must inflate at least 23 percent/year more than ethanol to allow economic use of ethanol as tractor fuel within the next 5 years. (Refs. 13).

  16. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  17. Physical Energy Accounting in California: A Case Study of Cellulosic Ethanol Production

    SciTech Connect (OSTI)

    Coughlin, Katie; Fridley, David

    2008-07-17

    California's target for greenhouse gas reduction in part relies on the development of viable low-carbon fuel alternatives to gasoline. It is often assumed that cellulosic ethanol--ethanol made from the structural parts of a plant and not from the food parts--will be one of these alternatives. This study examines the physical viability of a switchgrass-based cellulosic ethanol industry in California from the point of view of the physical requirements of land, water, energy and other material use. Starting from a scenario in which existing irrigated pastureland and fiber-crop land is converted to switchgrass production, the analysis determines the total acreage and water supply available and the resulting total biofuel feedstock output under different assumed yields. The number and location of cellulosic ethanol biorefineries that can be supported is also determined, assuming that the distance from field to biorefinery would be minimized. The biorefinery energy input requirement, available energy from the fraction of biomass not converted to ethanol, and energy output is calculated at various levels of ethanol yields, making different assumptions about process efficiencies. The analysis shows that there is insufficient biomass (after cellulose separation and fermentation into ethanol) to provide all the process energy needed to run the biorefinery; hence, the purchase of external energy such as natural gas is required to produce ethanol from switchgrass. The higher the yield of ethanol, the more external energy is needed, so that the net gains due to improved process efficiency may not be positive. On 2.7 million acres of land planted in switchgrass in this scenario, the switchgrass outputproduces enough ethanol to substitute for only 1.2 to 4.0percent of California's gasoline consumption in 2007.

  18. Blending Hydrogen into Natural Gas Pipeline Networks: A Review...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues The United States has 11 ...

  19. Quality Assessment of Biodiesel and Biodiesel Blends | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Assessment of Biodiesel and Biodiesel Blends Quality Assessment of Biodiesel and Biodiesel Blends The results of a quality survey of B20 fuel in the United States were ...

  20. Ethanol annual report FY 1990

    SciTech Connect (OSTI)

    Texeira, R.H.; Goodman, B.J.

    1991-01-01

    This report summarizes the research progress and accomplishments of the US Department of Energy (DOE) Ethanol from Biomass Program, field managed by the Solar Energy Research Institute, during FY 1990. The report includes an overview of the entire program and summaries of individual research projects. These projects are grouped into the following subject areas: technoeconomic analysis; pretreatment; cellulose conversion; xylose fermentation; and lignin conversion. Individual papers have been indexed separately for inclusion on the data base.

  1. HEU to LEU conversion and blending facility: Metal blending alternative to produce LEU oxide for disposal

    SciTech Connect (OSTI)

    1995-09-01

    US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. The nuclear material is converted to a form more proliferation- resistant than the original form. Blending HEU (highly enriched uranium) with less-enriched uranium to form LEU has been proposed as a disposition option. Five technologies are being assessed for blending HEU. This document provides data to be used in environmental impact analysis for the HEU-LEU disposition option that uses metal blending with an oxide waste product. It is divided into: mission and assumptions, conversion and blending facility descriptions, process descriptions and requirements, resource needs, employment needs, waste and emissions from plant, hazards discussion, and intersite transportation.

  2. The Role of Cellulosic Ethanol in Transportation

    SciTech Connect (OSTI)

    Robert M. Neilson, Jr.

    2007-10-01

    Petroleum provides essentially all of the energy used today in the transportation sector. To reduce this dependence on fossil energy, other fuels are beginning to be used, notably ethanol and biodiesel. Almost all fuel ethanol is produced by the conversion of corn grain to starch with subsequent fermentation to ethanol. In 2006, almost 5 billion gallons of fuel ethanol were produced, which used 17% of domestic corn production. The DOE has a goal to displace 30% of motor gasoline demand or 60 billion gallons per year by 2030. To achieve this goal, production of ethanol from lignocellulosic sources (e.g., agricultural residues, forest residues, and dedicated energy crops) is needed. This paper will describe the production of cellulosic ethanol as well as the issues and benefits associated with its production.

  3. Process for producing ethanol from syngas

    DOE Patents [OSTI]

    Krause, Theodore R; Rathke, Jerome W; Chen, Michael J

    2013-05-14

    The invention provides a method for producing ethanol, the method comprising establishing an atmosphere containing methanol forming catalyst and ethanol forming catalyst; injecting syngas into the atmosphere at a temperature and for a time sufficient to produce methanol; and contacting the produced methanol with additional syngas at a temperature and for a time sufficient to produce ethanol. The invention also provides an integrated system for producing methanol and ethanol from syngas, the system comprising an atmosphere isolated from the ambient environment; a first catalyst to produce methanol from syngas wherein the first catalyst resides in the atmosphere; a second catalyst to product ethanol from methanol and syngas, wherein the second catalyst resides in the atmosphere; a conduit for introducing syngas to the atmosphere; and a device for removing ethanol from the atmosphere. The exothermicity of the method and system obviates the need for input of additional heat from outside the atmosphere.

  4. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  5. Energy and greenhouse gas emission effects of corn and cellulosic ethanol with technology improvements and land use changes.

    SciTech Connect (OSTI)

    Wang, M.; Han, J.; Haq, Z; Tyner, .W.; Wu, M.; Elgowainy, A.

    2011-05-01

    Use of ethanol as a transportation fuel in the United States has grown from 76 dam{sup 3} in 1980 to over 40.1 hm{sup 3} in 2009 - and virtually all of it has been produced from corn. It has been debated whether using corn ethanol results in any energy and greenhouse gas benefits. This issue has been especially critical in the past several years, when indirect effects, such as indirect land use changes, associated with U.S. corn ethanol production are considered in evaluation. In the past three years, modeling of direct and indirect land use changes related to the production of corn ethanol has advanced significantly. Meanwhile, technology improvements in key stages of the ethanol life cycle (such as corn farming and ethanol production) have been made. With updated simulation results of direct and indirect land use changes and observed technology improvements in the past several years, we conducted a life-cycle analysis of ethanol and show that at present and in the near future, using corn ethanol reduces greenhouse gas emission by more than 20%, relative to those of petroleum gasoline. On the other hand, second-generation ethanol could achieve much higher reductions in greenhouse gas emissions. In a broader sense, sound evaluation of U.S. biofuel policies should account for both unanticipated consequences and technology potentials. We maintain that the usefulness of such evaluations is to provide insight into how to prevent unanticipated consequences and how to promote efficient technologies with policy intervention.

  6. Fair Oaks Dairy Farms Cellulosic Ethanol Technology Review Summary

    SciTech Connect (OSTI)

    Andrew Wold; Robert Divers

    2011-06-23

    At Fair Oaks Dairy, dried manure solids (''DMS'') are currently used as a low value compost. United Power was engaged to evaluate the feasibility of processing these DMS into ethanol utilizing commercially available cellulosic biofuels conversion platforms. The Fair Oaks Dairy group is transitioning their traditional ''manure to methane'' mesophilic anaerobic digester platform to an integrated bio-refinery centered upon thermophilic digestion. Presently, the Digested Manure Solids (DMS) are used as a low value soil amendment (compost). United Power evaluated the feasibility of processing DMS into higher value ethanol utilizing commercially available cellulosic biofuels conversion platforms. DMS was analyzed and over 100 potential technology providers were reviewed and evaluated. DMS contains enough carbon to be suitable as a biomass feedstock for conversion into ethanol by gasification technology, or as part of a conversion process that would include combined heat and power. In the first process, 100% of the feedstock is converted into ethanol. In the second process, the feedstock is combusted to provide heat to generate electrical power supporting other processes. Of the 100 technology vendors evaluated, a short list of nine technology providers was developed. From this, two vendors were selected as finalists (one was an enzymatic platform and one was a gasification platform). Their selection was based upon the technical feasibility of their systems, engineering expertise, experience in commercial or pilot scale operations, the ability or willingness to integrate the system into the Fair Oaks Biorefinery, the know-how or experience in producing bio-ethanol, and a clear path to commercial development.

  7. Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Infrastructure Development to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Infrastructure

  8. Kinder Morgan Central Florida Pipeline Ethanol Project

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    KINDER MORGAN CENTRAL FLORIDA PIPELINE ETHANOL PROJECT  In December 2008, Kinder Morgan began transporting commercial batches of denatured ethanol along with gasoline shipments in its 16-inch Central Florida Pipeline (CFPL) from Tampa to Orlando, making CFPL the first transmarket gasoline pipeline in the United States to do so. The 16-inch pipeline previously only transported regular and premium gasoline.  Kinder Morgan invested approximately $10 million to modify the line for ethanol

  9. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol This infographic was created by students from Williamsburg HS for Architecture and Design in Brooklyn, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge encourages young people to improve their foundational understanding of bioenergy, which is a broad and complex topic. The ideas

  10. Ethanol as a fuel: design and construction of an ethanol production facility for a farm

    SciTech Connect (OSTI)

    Pelger, E.C. III

    1981-01-01

    This dissertation describes the production of ethanol from biomass. It includes descriptions of photosynthesis, feedstock preparation, fermentation, distillation and end use. Technical problems and limitations as well as social, political, and economic aspects of producing ethanol are addressed. The potential of small-scale ethanol production and specific case studies are reviewed. A low-cost efficient design for a single farm ethanol facility is included. (DMC)

  11. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, Lars G.; Carriera, Laura H.

    1983-01-01

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  12. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, L.G.; Carriera, L.H.

    1983-05-24

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  13. US Ethanol Holdings | Open Energy Information

    Open Energy Info (EERE)

    Holdings Jump to: navigation, search Name: US Ethanol Holdings Place: New York, New York Zip: 10022 Product: Subsidiary of boutique investment bank and advisory firm, Geneva...

  14. Ethanol: Producting Food, Feed, and Fuel

    Broader source: Energy.gov [DOE]

    At the August 7, 2008 joint quarterly Web conference of DOE's Biomass and Clean Cities programs, Todd Sneller (Nebraska Ethanol Board) discussed the food versus fuel issue.

  15. Mixed waste paper to ethanol fuel

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  16. Dissociative electron attachments to ethanol and acetaldehyde...

    Office of Scientific and Technical Information (OSTI)

    3sup - are recorded, indicating the low kinetic energies of Osup -OHsup - for ethanol while the low and high kinetic energy distributions of Osup - ions for acetaldehyde. ...

  17. Bioconversion of plant biomass to ethanol. Final report, December 1, 1979-December 31, 1980

    SciTech Connect (OSTI)

    Su, T.M.; Lamed, R.J.; Lobos, J.; Brennan, M. Jr.; Smith, J.F.; Tabor, D.; Brooks, R.

    1980-01-01

    This final report describes research performed on a process for the direct fermentation of pretreated hardwood and corn stover to ethanol. Experimental investigations were conducted on the technical problem areas that limit the utilization of lignocellulose for ethanol production, i.e., wood pretreatment, culture development, and fermentation. Considerable technical progress has been demonstrated in each area. The experimental findings have led to process design improvements that can reduce the capital cost for ethanol production. Studies on wood pretreatment to enhance carbohydrate recovery and susceptibility to enzymatic hydrolysis continued to show progress. Rapid decompression of treated fibers to atmospheric pressure was found to make little or no contribution to enhancing the rate of enzymatic hydrolysis. Acid extraction of the hemicellulose component prior to sulfur dioxide augmented wood steaming increased the overall fermentable carbohydrate recovery and, therefore, the attainable yield of ethanol. Only modest improvements in fiber digestibility are now required to meet the pretreatment goals. A new and highly cellulolytic strain of C. thermocellum, designated as strain YS, was isolated from hot springs soil samples and tested. A previously unreported effect of stirring and hydrogen on the fermentation product pattern of several strains of C. thermocellum was discovered. Mono- and co-culture fermentations were performed to understand the factors that affect the yield of ethanol. Co-culturing C. thermocellum strain YS with efficient ethanol-producing non-cellulolytic strains resulted in higher ethanol yields than that observed in strain YS mono-culture cellulose fermentation. The feasibility of ethanol production at high substrate concentrations was investigated in serum bottle experiments. The amount of ethanol produced declined as the substrate concentration increased.

  18. Preliminary Economics for the Production of Pyrolysis Oil from Lignin in a Cellulosic Ethanol Biorefinery

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua

    2009-04-01

    Cellulosic ethanol biorefinery economics can be potentially improved by converting by-product lignin into high valued products. Cellulosic biomass is composed mainly of cellulose, hemicellulose and lignin. In a cellulosic ethanol biorefinery, cellulose and hemicellullose are converted to ethanol via fermentation. The raw lignin portion is the partially dewatered stream that is separated from the product ethanol and contains lignin, unconverted feed and other by-products. It can be burned as fuel for the plant or can be diverted into higher-value products. One such higher-valued product is pyrolysis oil, a fuel that can be further upgraded into motor gasoline fuels. While pyrolysis of pure lignin is not a good source of pyrolysis liquids, raw lignin containing unconverted feed and by-products may have potential as a feedstock. This report considers only the production of the pyrolysis oil and does not estimate the cost of upgrading that oil into synthetic crude oil or finished gasoline and diesel. A techno-economic analysis for the production of pyrolysis oil from raw lignin was conducted. comparing two cellulosic ethanol fermentation based biorefineries. The base case is the NREL 2002 cellulosic ethanol design report case where 2000 MTPD of corn stover is fermented to ethanol (NREL 2002). In the base case, lignin is separated from the ethanol product, dewatered, and burned to produce steam and power. The alternate case considered in this report dries the lignin, and then uses fast pyrolysis to generate a bio-oil product. Steam and power are generated in this alternate case by burning some of the corn stover feed, rather than fermenting it. This reduces the annual ethanol production rate from 69 to 54 million gallons/year. Assuming a pyrolysis oil value similar to Btu-adjusted residual oil, the estimated ethanol selling price ranges from $1.40 to $1.48 (2007 $) depending upon the yield of pyrolysis oil. This is considerably above the target minimum ethanol selling price of $1.33 for the 2012 goal case process as reported in the 2007 State of Technology Model (NREL 2008). Hence, pyrolysis oil does not appear to be an economically attractive product in this scenario. Further research regarding fast pyrolysis of raw lignin from a cellulosic plant as an end product is not recommended. Other processes, such as high-pressure liquefaction or wet gasification, and higher value products, such as gasoline and diesel from fast pyrolysis oil should be considered in future studies.

  19. Alternative Fuels Data Center: Ethanol Benefits and Considerations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Benefits and Considerations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Benefits and Considerations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Benefits and Considerations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Benefits and Considerations on Google Bookmark Alternative Fuels Data Center: Ethanol Benefits and Considerations on Delicious Rank Alternative Fuels Data Center: Ethanol Benefits and Considerations on Digg Find More

  20. Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Flexible Fuel Vehicle Conversions to someone by E-mail Share Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Ethanol Flexible Fuel

  1. Influence of Substrate on Crystallization in Polythiophene/fullerene Blends

    SciTech Connect (OSTI)

    C He; D Germack; J Kline; D Delongchamp; D Fischer; C Snyder; M Toney; J Kushmerick; L Richter

    2011-12-31

    The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment is used to optimize the morphology. In general, the development of microscopic crystals is deleterious, as the exciton diffusion length is {approx}10 nm. We find that the microscopic crystallization behavior in polythiophene/fullerene blends is strongly influenced by the substrate on which the BHJ is cast. With a silicon oxide substrate, the crystal nucleation density is high and significant crystallization occurs at a temperature of 140 C. On more hydrophobic substrates, significantly higher temperatures are required for observable crystallization. This difference is attributed to the interfacial segregation of the PCBM, controlled by the substrate surface energy. The substrate dependence of crystallization has significant implications on the fullerene crystal growth mechanisms and practical implications for device studies.

  2. Ethanol production using engineered mutant E. coli

    DOE Patents [OSTI]

    Ingram, Lonnie O.; Clark, David P.

    1991-01-01

    The subject invention concerns novel means and materials for producing ethanol as a fermentation product. Mutant E. coli are transformed with a gene coding for pyruvate decarboxylase activity. The resulting system is capable of producing relatively large amounts of ethanol from a variety of biomass sources.

  3. Project LIBERTY Biorefinery Starts Cellulosic Ethanol Production

    Broader source: Energy.gov [DOE]

    Project LIBERTY, the nation’s first commercial-scale cellulosic ethanol plant to use corn waste as a feedstock, announced the start of production today. Once operating at full, commercial-scale, the biorefinery in Emmetsburg, Iowa will produce 25 million gallons of cellulosic ethanol per year - enough to avoid approximately 210,000 tons of CO2 emissions annually.

  4. DuPont Cellulosic Ethanol Biorefinery Opening

    Broader source: Energy.gov [DOE]

    The DuPont cellulosic ethanol facility, opening in Nevada, Iowa, on October 30, will be the largest cellulosic ethanol plant in the world. The U.S. Department of Energy Bioenergy Technologies Office Director, Jonathan Male, alongside senior government officials, DuPont leaders and staff, and local farmers will attend the grand opening ceremony and plant tour.

  5. Outlook for Biomass Ethanol Production and Demand

    Reports and Publications (EIA)

    2000-01-01

    This paper presents a midterm forecast for biomass ethanol production under three different technology cases for the period 2000 to 2020, based on projections developed from the Energy Information Administration's National Energy Modeling System. An overview of cellulose conversion technology and various feedstock options and a brief history of ethanol usage in the United States are also presented.

  6. Lignocellulosic Biomass to Ethanol Process Design and Economics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current ... Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current ...

  7. Experiences from Ethanol Buses and Fuel Station Report - Nanyang...

    Open Energy Info (EERE)

    Nanyang Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Experiences from Ethanol Buses and Fuel Station Report - Nanyang AgencyCompany Organization: BioEthanol for...

  8. Henan Tianguan Fuel Ethanol Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Tianguan Fuel Ethanol Co Ltd Jump to: navigation, search Name: Henan Tianguan Fuel Ethanol Co Ltd Place: Nanyang, Henan Province, China Product: Project developer of a bioethanol...

  9. Utica Energy LLC formerly Algoma Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Utica Energy LLC formerly Algoma Ethanol Jump to: navigation, search Name: Utica Energy LLC (formerly Algoma Ethanol) Place: Oshkosh, Wisconsin Product: Utica Energy, founded by 5...

  10. Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia Biorefinery Groundbreaking Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia Biorefinery...

  11. Levelland Hockley County Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Levelland Hockley County Ethanol LLC Jump to: navigation, search Name: LevellandHockley County Ethanol LLC Place: Levelland, Texas Zip: 79336 Product: LevellandHockley County...

  12. Ethanol Oil Recovery Systems EORS | Open Energy Information

    Open Energy Info (EERE)

    Systems EORS Jump to: navigation, search Name: Ethanol Oil Recovery Systems (EORS) Place: Clayton, Georgia Product: Ethanol Oil Recovery Systems (EORS), a green technology...

  13. AE Biofuels Inc formerly American Ethanol Inc | Open Energy Informatio...

    Open Energy Info (EERE)

    AE Biofuels Inc formerly American Ethanol Inc Jump to: navigation, search Name: AE Biofuels Inc. (formerly American Ethanol Inc.) Place: Cupertino, California Zip: CA 95014...

  14. Central Minnesota Ethanol Cooperative CMEC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Cooperative CMEC Jump to: navigation, search Name: Central Minnesota Ethanol Cooperative (CMEC) Place: Minnesota Zip: 56345 Sector: Hydro Product: CMEC produces 200 proof...

  15. Experiences from Ethanol Buses and Fuel Station Report - La Spezia...

    Open Energy Info (EERE)

    Experiences from Ethanol Buses and Fuel Station Report - La Spezia Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Experiences from Ethanol Buses and Fuel Station Report...

  16. Green Renewable Energy Ethanol and Nutrition Holding LLC | Open...

    Open Energy Info (EERE)

    Ethanol and Nutrition Holding LLC Jump to: navigation, search Name: Green Renewable Energy Ethanol and Nutrition-Holding, LLC Place: Palm, Pennsylvania Zip: 18070 Product: A local...

  17. Pacific Ethanol Inc formerly Accessity Corporation | Open Energy...

    Open Energy Info (EERE)

    Ethanol Inc formerly Accessity Corporation Jump to: navigation, search Name: Pacific Ethanol Inc (formerly Accessity Corporation) Place: Fresno, California Zip: 93711 Product:...

  18. Belize-OAS Cellulosic Ethanol Market Assessment | Open Energy...

    Open Energy Info (EERE)

    OAS Cellulosic Ethanol Market Assessment Jump to: navigation, search Name Belize-OAS Cellulosic Ethanol Market Assessment AgencyCompany Organization Organization of American...

  19. Gateway Ethanol LLC formerly Wildcat Bio Energy LLC | Open Energy...

    Open Energy Info (EERE)

    Ethanol LLC formerly Wildcat Bio Energy LLC Jump to: navigation, search Name: Gateway Ethanol LLC (formerly Wildcat Bio-Energy LLC) Place: Pratt, Kansas Zip: 67124 Product:...

  20. Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Breakout Session 2: Frontiers and Horizons Session 2-B: ...

  1. Dispensing Equipment Testing With Mid-Level Ethanol/Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dispensing Equipment Testing With Mid-Level EthanolGasoline Test Fluid Dispensing Equipment Testing With Mid-Level EthanolGasoline Test Fluid The National Renewable Energy ...

  2. Reaction Rates and Catalysts in Ethanol Production (1 Activity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reaction Rates and Catalysts in Ethanol Production (1 Activity) Reaction Rates and Catalysts in Ethanol Production (1 Activity) Below is information about the student activity...

  3. Detailed chemical kinetic model for ethanol oxidation (Technical...

    Office of Scientific and Technical Information (OSTI)

    Detailed chemical kinetic model for ethanol oxidation Citation Details In-Document Search Title: Detailed chemical kinetic model for ethanol oxidation You are accessing a ...

  4. Ethanol and the Environment - Energy Explained, Your Guide To...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Unlike gasoline, pure ethanol is nontoxic and biodegradable, and it quickly breaks down into harmless substances if spilled. Chemical denaturants are added to fuel ethanol (about ...

  5. Enabling High Efficiency Ethanol Engines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enabling High Efficiency Ethanol Engines Enabling High Efficiency Ethanol Engines 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

  6. Biochemical Production of Ethanol from Corn Stover: 2007 State...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model An update to ...

  7. Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle...

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Flexible Fuel Vehicle Conversions Updated July 29, 2011 Rising gasoline prices and concerns about climate change have greatly increased public interest in ethanol use, ...

  8. Infrastructure Requirements for an Expanded Fuel Ethanol Industry

    SciTech Connect (OSTI)

    Reynolds, Robert E.

    2002-01-15

    This report provides technical information specifically related to ethanol transportation, distribution, and marketing issues. This report required analysis of the infrastructure requirements for an expanded ethanol industry.

  9. Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization December 16, 2015 - 2:23pm Addthis Dr. ...

  10. Microbial fuel cell treatment of ethanol fermentation process...

    Office of Scientific and Technical Information (OSTI)

    Microbial fuel cell treatment of ethanol fermentation process water Title: Microbial fuel cell treatment of ethanol fermentation process water The present invention relates to a ...

  11. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis ...

  12. Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress...

    Office of Scientific and Technical Information (OSTI)

    However, the molecular mechanisms of ethanol stress response have not been elucidated fully. In this study, ethanol stress responses were investigated using systems biology tools. ...

  13. Breaking the Biological Barriers to Cellulosic Ethanol, June...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Breaking the Biological Barriers to Cellulosic Ethanol, June 2006 Breaking the Biological Barriers to Cellulosic Ethanol, June 2006 Breaking the Biological Barriers to Cellulosic...

  14. Dual-fueling turbocharged diesels with ethanol

    SciTech Connect (OSTI)

    Cruz, J.M.; Rotz, C.A.; Watson, D.H.

    1982-09-01

    Spray addition and carburetion methods were tested for dual-fueling a turbocharged, 65 kW diesel tractor. Approximately 30 percent of the fuel energy for the tractor was supplied by spraying ethanol into the intake air and about 46 percent by carburetion with little affect on the engine thermal efficiency. Further substitution of diesel fuel with ethanol was limited by knock. As the amount of ethanol fed into the engine was increased, ignition apparently changed from the steady burning process which normally occurs in a diesel engine to a rapid explosion which caused knock. The best fuel for the spray approach was a 50 percent ethanol/water solution and with the carburetor it was an 80 percent ethanol/water solution.

  15. Dual-fueling turbocharged diesels with ethanol

    SciTech Connect (OSTI)

    Cruz, J.M.; Rotz, C.A.; Watson, D.H.

    1982-09-01

    Spray addition and carburetion methods were tested for dual-fueling a turbocharged, 65 kW diesel tractor. Approximately 30 percent of the fuel energy for the tractor was supplied by spraying ethanol into the intake air and about 46 percent by carburetion with little affect on the engine thermal efficiency. Further substitution of diesel fuel with ethanol was limited by knock. As the amount of ethanol fed into the engine was increased, ignition apparently changed from the steady burning process which normally occurs in a diesel engine to a rapid explosion which caused knock. The best fuel for the spray approach was a 50 percent ethanol/water solution and with the carburetor it was an 80 percent ethanol/water solution. (Refs. 6).

  16. Advanced Biorefinery of Distriller's Grain and Corn Stover Blends

    SciTech Connect (OSTI)

    2006-04-01

    Fuel ethanol can be produced via the dry milling process, which converts corn grain to ethanol. The co-product, distiller’s grain (DG), is sold as a low-cost, high-protein feed source for livestock.

  17. Tough Blends of Polylactide and Castor Oil

    SciTech Connect (OSTI)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A.

    2012-10-10

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  18. High Ethanol Fuel Endurance: A Study of the Effects of Running Gasoline with 15% Ethanol Concentration in Current Production Outboard Four-Stroke Engines and Conventional Two-Stroke Outboard Marine Engines

    SciTech Connect (OSTI)

    Hilbert, D.

    2011-10-01

    Three Mercury Marine outboard marine engines were evaluated for durability using E15 fuel -- gasoline blended with 15% ethanol. Direct comparison was made to operation on E0 (ethanol-free gasoline) to determine the effects of increased ethanol on engine durability. Testing was conducted using a 300-hour wide-open throttle (WOT) test protocol, a typical durability cycle used by the outboard marine industry. Use of E15 resulted in reduced CO emissions, as expected for open-loop, non-feedback control engines. HC emissions effects were variable. Exhaust gas and engine operating temperatures increased as a consequence of leaner operation. Each E15 test engine exhibited some deterioration that may have been related to the test fuel. The 9.9 HP, four-stroke E15 engine exhibited variable hydrocarbon emissions at 300 hours -- an indication of lean misfire. The 300HP, four-stroke, supercharged Verado engine and the 200HP, two-stroke legacy engine tested with E15 fuel failed to complete the durability test. The Verado engine failed three exhaust valves at 285 endurance hours while the 200HP legacy engine failed a main crank bearing at 256 endurance hours. All E0-dedicated engines completed the durability cycle without incident. Additional testing is necessary to link the observed engine failures to ethanol in the test fuel.

  19. Transesterification of waste vegetable oil under pulse sonication using ethanol, methanol and ethanol–methanol mixtures

    SciTech Connect (OSTI)

    Martinez-Guerra, Edith; Gude, Veera Gnaneswar

    2014-12-15

    Highlights: • Pulse sonication effect on transesterification of waste vegetable oil was studied. • Effects of ethanol, methanol, and alcohol mixtures on FAMEs yield were evaluated. • Effect of ultrasonic intensity, power density, and its output rates were evaluated. • Alcohol mixtures resulted in higher biodiesel yields due to better solubility. - Abstract: This study reports on the effects of direct pulse sonication and the type of alcohol (methanol and ethanol) on the transesterification reaction of waste vegetable oil without any external heating or mechanical mixing. Biodiesel yields and optimum process conditions for the transesterification reaction involving ethanol, methanol, and ethanol–methanol mixtures were evaluated. The effects of ultrasonic power densities (by varying sample volumes), power output rates (in W), and ultrasonic intensities (by varying the reactor size) were studied for transesterification reaction with ethanol, methanol and ethanol–methanol (50%-50%) mixtures. The optimum process conditions for ethanol or methanol based transesterification reaction of waste vegetable oil were determined as: 9:1 alcohol to oil ratio, 1% wt. catalyst amount, 1–2 min reaction time at a power output rate between 75 and 150 W. It was shown that the transesterification reactions using ethanol–methanol mixtures resulted in biodiesel yields as high as >99% at lower power density and ultrasound intensity when compared to ethanol or methanol based transesterification reactions.

  20. Evaluation of nanoparticle-immobilized cellulase for improved ethanol yield in simultaneous saccharification and fermentation reactions

    SciTech Connect (OSTI)

    Lupoi, Jason; Smith, Emily

    2011-12-01

    Ethanol yields were 2.1 (P = 0.06) to 2.3 (P = 0.01) times higher in simultaneous saccharification and fermentation (SSF) reactions of microcrystalline cellulose when cellulase was physisorbed on silica nanoparticles compared to enzyme in solution. In SSF reactions, cellulose is hydrolyzed to glucose by cellulase while yeast simultaneously ferments glucose to ethanol. The 35 C temperature and the presence of ethanol in SSF reactions are not optimal conditions for cellulase. Immobilization onto solid supports can stabilize the enzyme and promote activity at non-optimum reaction conditions. Mock SSF reactions that did not contain yeast were used to measure saccharification products and identify the mechanism for the improved ethanol yield using immobilized cellulase. Cellulase adsorbed to 40 nm silica nanoparticles produced 1.6 times (P = 0.01) more glucose than cellulase in solution in 96 h at pH 4.8 and 35 C. There was no significant accumulation (<250 {mu}g) of soluble cellooligomers in either the solution or immobilized enzyme reactions. This suggests that the mechanism for the immobilized enzyme's improved glucose yield compared to solution enzyme is the increased conversion of insoluble cellulose hydrolysis products to soluble cellooligomers at 35 C and in the presence of ethanol. The results show that silica-immobilized cellulase can be used to produce increased ethanol yields in the conversion of lignocellulosic materials by SSF.

  1. Ethanol Distribution, Dispensing, and Use: Analysis of a Portion of the Biomass-to-Biofuels Supply Chain Using System Dynamics

    SciTech Connect (OSTI)

    Vimmerstedt, L. J.; Bush, B.; Peterson, S.

    2012-05-01

    The Energy Independence and Security Act of 2007 targets use of 36 billion gallons of biofuels per year by 2022. Achieving this may require substantial changes to current transportation fuel systems for distribution, dispensing, and use in vehicles. The U.S. Department of Energy and the National Renewable Energy Laboratory designed a system dynamics approach to help focus government action by determining what supply chain changes would have the greatest potential to accelerate biofuels deployment. The National Renewable Energy Laboratory developed the Biomass Scenario Model, a system dynamics model which represents the primary system effects and dependencies in the biomass-to-biofuels supply chain. The model provides a framework for developing scenarios and conducting biofuels policy analysis. This paper focuses on the downstream portion of the supply chain-represented in the distribution logistics, dispensing station, and fuel utilization, and vehicle modules of the Biomass Scenario Model. This model initially focused on ethanol, but has since been expanded to include other biofuels. Some portions of this system are represented dynamically with major interactions and feedbacks, especially those related to a dispensing station owner's decision whether to offer ethanol fuel and a consumer's choice whether to purchase that fuel. Other portions of the system are modeled with little or no dynamics; the vehicle choices of consumers are represented as discrete scenarios. This paper explores conditions needed to sustain an ethanol fuel market and identifies implications of these findings for program and policy goals. A large, economically sustainable ethanol fuel market (or other biofuel market) requires low end-user fuel price relative to gasoline and sufficient producer payment, which are difficult to achieve simultaneously. Other requirements (different for ethanol vs. other biofuel markets) include the need for infrastructure for distribution and dispensing and widespread use of high ethanol blends in flexible-fuel vehicles.

  2. Conversion of bagasse cellulose into ethanol

    SciTech Connect (OSTI)

    Cuzens, J.E.

    1997-11-19

    The study conducted by Arkenol was designed to test the conversion of feedstocks such as sugar cane bagasse, sorghum, napier grass and rice straw into fermentable sugars, and then ferment these sugars using natural yeasts and genetically engineered Zymomonis mobilis bacteria (ZM). The study did convert various cellulosic feedstocks into fermentable sugars utilizing the patented Arkenol Concentrated Acid Hydrolysis Process and equipment at the Arkenol Technology Center in Orange, California. The sugars produced using this process were in the concentration range of 12--15%, much higher than the sugar concentrations the genetically engineered ZM bacteria had been developed for. As a result, while the ZM bacteria fermented the produced sugars without initial inhibition, the completion of high sugar concentration fermentations was slower and at lower yield than predicted by the National Renewable Energy Laboratory (NREL). Natural yeasts performed as expected by Arkenol, similar to the results obtained over the last four years of testing. Overall, at sugar concentrations in the 10--13% range, yeast produced 850090% theoretical ethanol yields and ZM bacteria produced 82--87% theoretical yields in 96 hour fermentations. Additional commercialization work revealed the ability to centrifugally separate and recycle the ZM bacteria after fermentation, slight additional benefits from mixed culture ZM bacteria fermentations, and successful utilization of defined media for ZM bacteria fermentation nutrients in lieu of natural media.

  3. Conductive Polymer/Fullerene Blend Thin Films with Honeycomb...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Conductive PolymerFullerene Blend Thin Films with Honeycomb Framework Brookhaven National Laboratory...

  4. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  5. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J.; King, Edward E.; Milliron, Dennis L.

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  6. Running Line-Haul Trucks on Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    I magine driving a 55,000-pound tractor- trailer that runs on corn! If you find it difficult to imagine, you can ask the truck drivers for Archer Daniels Midland (ADM) what it's like. For the past 4 years, they have been piloting four trucks powered by ethyl alcohol, or "ethanol," derived from corn. Several advantages to operating trucks on ethanol rather than on conventional petro- leum diesel fuel present themselves. Because ethanol can be produced domestically, unlike most of our

  7. Environmental analysis of biomass-ethanol facilities

    SciTech Connect (OSTI)

    Corbus, D.; Putsche, V.

    1995-12-01

    This report analyzes the environmental regulatory requirements for several process configurations of a biomass-to-ethanol facility. It also evaluates the impact of two feedstocks (municipal solid waste [MSW] and agricultural residues) and three facility sizes (1000, 2000, and 3000 dry tons per day [dtpd]) on the environmental requirements. The basic biomass ethanol process has five major steps: (1) Milling, (2) Pretreatment, (3) Cofermentation, (4) Enzyme production, (5) Product recovery. Each step could have environmental impacts and thus be subject to regulation. Facilities that process 2000 dtpd of MSW or agricultural residues would produce 69 and 79 million gallons of ethanol, respectively.

  8. Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Safety Testing Underwriters Laboratories Ethanol Dispenser Safety Testing to someone by E-mail Share Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser Safety Testing on Facebook Tweet about Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser Safety Testing on Twitter Bookmark Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser Safety Testing on Google Bookmark Alternative Fuels Data Center: Underwriters Laboratories

  9. Ethanol Production, Distribution, and Use: Discussions on Key Issues (Presentation)

    SciTech Connect (OSTI)

    Harrow, G.

    2008-05-14

    From production to the environment, presentation discusses issues surrounding ethanol as a transportation fuel.

  10. Ethanol Pathways in the 2050 North American Transportation Futures Study

    SciTech Connect (OSTI)

    2009-01-18

    A paper discussing the various ethanol pathways in the 2050 North American Transportation Futures Study

  11. Fermentation pattern of sucrose to ethanol conversions by Zymomonas mobilis

    SciTech Connect (OSTI)

    Lyness, Ed.; Doelle, H.W.

    1981-07-01

    General patterns of sucrose fermentation by two strains of Zymomonas mobilis, designated Z7 and Z10, were established using sucrose concentrations from 50 to 200 g/liter. Strain Z7 showed a higher invertase activity than Z10. Strain Z10 showed a reduced specific growth rate a high sucrose concentrations while Z7 was unaffected. High sucrose hydrolyzing activity in strain Z7 lead to glucose accumulation in the medium at high sucrose concentrations. Ethanol production and fermentation time depend on the rate of catabolism of the products of sucrose hydrolysis, glucose and fructose. 10 refs.

  12. Economic and environmental impacts of the corn grain ethanol industry on the United States agricultural sector

    SciTech Connect (OSTI)

    Larson, J.A.; English, B.C.; De La Torre Ugarte, D. G.; Menard, R.J.; Hellwinckel, C.M.; West, Tristram O.

    2010-09-10

    This study evaluated the impacts of increased ethanol production from corn starch on agricultural land use and the environment in the United States. The Policy Analysis System simulation model was used to simulate alternative ethanol production scenarios for 2007 through 2016. Results indicate that increased corn ethanol production had a positive effect on net farm income and economic wellbeing of the US agricultural sector. In addition, government payments to farmers were reduced because of higher commodity prices and enhanced net farm income. Results also indicate that if Conservation Reserve Program land was converted to crop production in response to higher demand for ethanol in the simulation, individual farmers planted more land in crops, including corn. With a larger total US land area in crops due to individual farmer cropping choices, total US crop output rose, which decreased crop prices and aggregate net farm income relative to the scenario where increased ethanol production happened without Conservation Reserve Program land. Substantial shifts in land use occurred with corn area expanding throughout the United States, especially in the traditional corn-growing area of the midcontinent region.

  13. Sterling Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Place: Colorado Product: Owned by local investors including farmers, ranchers and business people that primarily reside in north-west Colorado, and set up to build and...

  14. Algenol Announces Commercial Algal Ethanol Fuel Partnership

    Broader source: Energy.gov [DOE]

    U.S. Department of Energys Bioenergy Technologies Office (BETO) partner Algenol signed an agreement with Protec Fuel to market and distribute commercial ethanol produced from algae for fleets and...

  15. QER- Comment of ND Ethanol Council

    Broader source: Energy.gov [DOE]

    To whom it may concern, Attached please find comments from the North Dakota Ethanol Council regarding infrastructure constraints in preparation for the OER Public Meeting, which will be held in Bismarck, N.D., on August 8. Sincerely, Deana Wies

  16. Treatment of biomass to obtain ethanol

    DOE Patents [OSTI]

    Dunson, Jr., James B.; Elander, Richard T.; Tucker, III, Melvin P.; Hennessey, Susan Marie

    2011-08-16

    Ethanol was produced using biocatalysts that are able to ferment sugars derived from treated biomass. Sugars were obtained by pretreating biomass under conditions of high solids and low ammonia concentration, followed by saccharification.

  17. Breaking the Biological Barriers to Cellulosic Ethanol, June 2006 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Breaking the Biological Barriers to Cellulosic Ethanol, June 2006 Breaking the Biological Barriers to Cellulosic Ethanol, June 2006 Breaking the Biological Barriers to Cellulosic Ethanol, June 2006 PDF icon b2blowres63006.pdf More Documents & Publications Breaking the Biological Barriers to Cellulosic Ethanol, June 2006 Review of Recent Pilot Scale Cellulosic Ethanol Demonstration Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and

  18. Alternative Fuels Data Center: Ethanol Fueling Station Locations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Station Locations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Station Locations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Station Locations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Station Locations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Station Locations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Station Locations on Digg Find More places to share Alternative

  19. Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol to someone by E-mail Share Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol on Facebook Tweet about Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol on Twitter Bookmark Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol on Google Bookmark Alternative Fuels Data Center: Federal Laws and Incentives for

  20. Role of water activity in ethanol fermentations

    SciTech Connect (OSTI)

    Jones, R.P.; Greenfield, P.F.

    1986-01-01

    A separate role for water activity in the conversion of sugars to ethanol by two strains of yeast is identified. During fermentation of both single and mixed sugar substrates, the water activity was shown to remain constant during the logarithmic growth phase. This is despite the changes in concentration of substrates and production, the constancy reflecting the fact that the greater influence of ethanol on the solution activity is counterbalanced, in the early stages of the fermentation, by its low yield. The end of the log phase of growth coincides with the start of a period of gradually decreasing water activity. For the more ethanol-tolerant strain UQM66Y, growth was found to cease at a constant value of water activity while that for the less tolerant strain UQM70Y depended on both ethanol concentration and water activity. It is argued that water activity is a more appropriate variable than ethanol concentration for describing some of the nonspecific inhibitory effects apparent in ethanol fermentations. A straightforward method for the calculation of water activity during such fermentations based on the use of solution osmolarity is presented.

  1. Performance of Biofuels and Biofuel Blends | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    12 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ft003_mccormick_2012_o.pdf More Documents & Publications Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends Recent Research to Address Technical Barriers to Increased Use of Biodiesel

  2. Role of Nrf2 in preventing ethanol-induced oxidative stress and lipid accumulation

    SciTech Connect (OSTI)

    Wu, Kai Connie; Liu, Jie; Klaassen, Curtis D.

    2012-08-01

    Oxidative stress and lipid accumulation play important roles in alcohol-induced liver injury. Previous reports showed that, in livers of nuclear factor erythroid 2-related factor 2 (Nrf2)-activated mice, genes involved in antioxidant defense are induced, whereas genes involved in lipid biosynthesis are suppressed. To investigate the role of Nrf2 in ethanol-induced hepatic alterations, Nrf2-null mice, wild-type mice, kelch-like ECH-associated protein 1-knockdown (Keap1-KD) mice with enhanced Nrf2, and Keap1-hepatocyte knockout (Keap1-HKO) mice with maximum Nrf2 activation, were treated with ethanol (5 g/kg, po). Blood and liver samples were collected 6 h thereafter. Ethanol increased alanine aminotransferase and lactate dehydrogenase activities as well as thiobarbituric acid reactive substances in serum of Nrf2-null and wild-type mice, but not in Nrf2-enhanced mice. After ethanol administration, mitochondrial glutathione concentrations decreased markedly in Nrf2-null mice but not in Nrf2-enhanced mice. H{sub 2}DCFDA staining of primary hepatocytes isolated from the four genotypes of mice indicates that oxidative stress was higher in Nrf2-null cells, and lower in Nrf2-enhanced cells than in wild-type cells. Ethanol increased serum triglycerides and hepatic free fatty acids in Nrf2-null mice, and these increases were blunted in Nrf2-enhanced mice. In addition, the basal mRNA and nuclear protein levels of sterol regulatory element-binding protein 1(Srebp-1) were decreased with graded Nrf2 activation. Ethanol further induced Srebp-1 mRNA in Nrf2-null mice but not in Nrf2-enhanced mice. In conclusion, Nrf2 activation prevented alcohol-induced oxidative stress and accumulation of free fatty acids in liver by increasing genes involved in antioxidant defense and decreasing genes involved in lipogenesis. -- Highlights: ► Ethanol depleted mitochondrial GSH in Nrf2-null mice but not in Keap1-KD mice. ► Ethanol increased ROS in hepatocytes isolated from Nrf2-null and wild-type mice. ► Nrf2 blunted ethanol-induced increase of triglycerides and free fatty acids. ► The mRNA and nuclear protein of Srebp-1 were decreased with Nrf2 activation. ► The mRNA of Scd1 was increased in Nrf2-null mice after ethanol exposure.

  3. NREL: State and Local Governments - Renewable Fuel Standards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to RFS effectiveness: Imposing stringency to require use of higher blends of ethanol or alternative fuels. Adopting an implementation plan that can ease measurement and...

  4. Process of concentrating ethanol from dilute aqueous solutions thereof

    DOE Patents [OSTI]

    Oulman, C.S.; Chriswell, C.D.

    1981-07-07

    Relatively dilute aqueous solutions of ethanol are concentrated by passage through a bed of a crystalline silica polymorph, such as silicalite, to adsorb the ethanol with residual dilute feed in contact with the bed, which is displaced by passing concentrated aqueous ethanol through the bed without displacing the adsorbed ethanol. A product concentrate is then obtained by removing the adsorbed ethanol from the bed together with at least a portion of the concentrated aqueous ethanol used as the displacer liquid. This process permits ethanol to be concentrated from dilute fermentation beers, which may contain from 6 to 10% ethanol, to obtain a concentrate product at very low energy cost having an ethanol concentration in excess of 95%, such as a concentration of from 98 to 99.5%. 5 figs.

  5. Process of concentrating ethanol from dilute aqueous solutions thereof

    DOE Patents [OSTI]

    Oulman, Charles S. [Ames, IA; Chriswell, Colin D. [Slater, IA

    1981-07-07

    Relatively dilute aqueous solutions of ethanol are concentrated by passage through a bed of a crystalline silica polymorph, such as silicalite, to adsorb the ethanol with residual dilute feed in contact with the bed, which is displaced by passing concentrated aqueous ethanol through the bed without displacing the adsorbed ethanol. A product concentrate is then obtained by removing the adsorbed ethanol from the bed together with at least a portion of the concentrated aqueous ethanol used as the displacer liquid. This process permits ethanol to be concentrated from dilute fermentation beers, which may contain from 6 to 10% ethanol, to obtain a concentrate product at very low energy cost having an ethanol concentration in excess of 95%, such as a concentration of from 98 to 99.5%.

  6. Economic contribution of lignins to ethanol production from biomass

    SciTech Connect (OSTI)

    Chum, H.L.; Parker, S.K.; Feinberg, D.A.; Wright, J.D.; Rice, P.A.; Sinclair, S.A.; Glasser, W.G.

    1985-05-01

    Lignin, one of the three major polymeric components of biomass (16% to 33% by weight in wood), has the highest specific heat content. Therefore, it can be burned for process fuel. Compared to coal, its fuel value is 2.2 cents/lb. This report investigates markets for lignin utilization of higher value. After lignin isolation from the process, purchase of replacement fuel (coal was analyzed), lignin sale for the manufacture of solid materials or higher value octane enhancers was evaluated. Polymeric applications evaluated were: surfactants, asphalt, carbon black, adhesives, and lignin plastics; agricultural applications were briefly reviewed. These lignins would generate coproduct credits of 25 cents to 150 cents/gallon of ethanol respectively for 7.5 cents to 60 cents/lb lignin value (isolation and eventual modification costs were taken into account). Overall markets for these polymeric applications were projected at 11 billion lb/year by the year 2000. These projections are intensities of demand and not actual shipments of lignins. In addition, this report investigates the possibility of converting lignins into mixtures of methyls aryl ethers and methyl substituted-aryl ethers which are high value octane enhancers, fully compatible with gasoline. The report intends to show that if fuel ethanol production in the billions of gallons scale occurs lignin markets would not be saturated. 10 refs., 14 figs., 36 tabs.

  7. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Avoidance Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel BiodieselFuelManagementBestPracticesReport.pdf

  8. Status of Legislative & Regulatory Developments Marilyn J....

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2011 2 EPA Waiver Decision E15 Implementation Issues Federal and State Blending Restrictions Action by ASTM NCWM to address higher ethanol blends 3 October 13, 2010 - EPA granted ...

  9. Designer organisms for photosynthetic production of ethanol from carbon dioxide and water

    DOE Patents [OSTI]

    Lee, James Weifu

    2011-07-05

    The present invention provides a revolutionary photosynthetic ethanol production technology based on designer transgenic plants, algae, or plant cells. The designer plants, designer algae, and designer plant cells are created such that the endogenous photosynthesis regulation mechanism is tamed, and the reducing power (NADPH) and energy (ATP) acquired from the photosynthetic water splitting and proton gradient-coupled electron transport process are used for immediate synthesis of ethanol (CH.sub.3CH.sub.2OH) directly from carbon dioxide (CO.sub.2) and water (H.sub.2O). The ethanol production methods of the present invention completely eliminate the problem of recalcitrant lignocellulosics by bypassing the bottleneck problem of the biomass technology. The photosynthetic ethanol-production technology of the present invention is expected to have a much higher solar-to-ethanol energy-conversion efficiency than the current technology and could also help protect the Earth's environment from the dangerous accumulation of CO.sub.2 in the atmosphere.

  10. An Indirect Route for Ethanol Production

    SciTech Connect (OSTI)

    Eggeman, T.; Verser, D.; Weber, E.

    2005-04-29

    The ZeaChem indirect method is a radically new approach to producing fuel ethanol from renewable resources. Sugar and syngas processing platforms are combined in a novel way that allows all fractions of biomass feedstocks (e.g. carbohydrates, lignins, etc.) to contribute their energy directly into the ethanol product via fermentation and hydrogen based chemical process technologies. The goals of this project were: (1) Collect engineering data necessary for scale-up of the indirect route for ethanol production, and (2) Produce process and economic models to guide the development effort. Both goals were successfully accomplished. The projected economics of the Base Case developed in this work are comparable to today's corn based ethanol technology. Sensitivity analysis shows that significant improvements in economics for the indirect route would result if a biomass feedstock rather that starch hydrolyzate were used as the carbohydrate source. The energy ratio, defined as the ratio of green energy produced divided by the amount of fossil energy consumed, is projected to be 3.11 to 12.32 for the indirect route depending upon the details of implementation. Conventional technology has an energy ratio of 1.34, thus the indirect route will have a significant environmental advantage over today's technology. Energy savings of 7.48 trillion Btu/yr will result when 100 MMgal/yr (neat) of ethanol capacity via the indirect route is placed on-line by the year 2010.

  11. Calcination of calcium carbonate and blend therefor

    DOE Patents [OSTI]

    Mallow, William A.; Dziuk, Jr., Jerome J.

    1989-01-01

    A method for calcination of a calcium carbonate material comprising heating the calcium carbonate material to a temperature and for a time sufficient to calcine the material to the degree desired while in the presence of a catalyst; said catalyst comprising at least one fused salt having the formula MCO.sub.3.CaCO.sub.3.CaO.H.sub.2 O.sub.x, wherein M is an alkali metal and x is 0 to 1 and formed by fusing MCO.sub.3 and CaCO.sub.3 in a molar ratio of about 1:2 to 2:1, and a blend adapted to be heated to CaO comprising a calcium carbonate material and at least one such fused salt.

  12. EFFECT OF ENDOSPERM HARDNESS ON AN ETHANOL PROCESS USING A GRANULAR STARCH HYDROLYZING ENZYME

    SciTech Connect (OSTI)

    P. Wang; W. Liu, D. B; Johnston, K. D; Rausch, S. J; Schmidt, M. E; Tumbleson, V. Singh

    2010-01-01

    Granular starch hydrolyzing enzymes (GSHE) can hydrolyze starch at low temperature (32C). The dry grind process using GSHE (GSH process) has fewer unit operations and no changes in process conditions (pH 4.0 and 32C) compared to the conventional process because it dispenses with the cooking and liquefaction step. In this study, the effects of endosperm hardness, protease, urea, and GSHE levels on GSH process were evaluated. Ground corn, soft endosperm, and hard endosperm were processed using two GSHE levels (0.1 and 0.4 mL per 100 g ground material) and four treatments of protease and urea addition. Soft and hard endosperm materials were obtained by grinding and sifting flaking grits from a dry milling pilot plant; classifications were confirmed using scanning electron microscopy. During 72 h of simultaneous granular starch hydrolysis and fermentation (GSHF), ethanol and glucose profiles were determined using HPLC. Soft endosperm resulted in higher final ethanol concentrations compared to ground corn or hard endosperm. Addition of urea increased final ethanol concentrations for soft and hard endosperm. Protease addition increased ethanol concentrations and fermentation rates for soft endosperm, hard endosperm, and ground corn. The effect of protease addition on ethanol concentrations and fermentation rates was most predominant for soft endosperm, less for hard endosperm, and least for ground corn. Samples (soft endosperm, hard endosperm, or corn) with protease resulted in higher (1.0% to 10.5% v/v) ethanol concentration compared to samples with urea. The GSH process with protease requires little or no urea addition. For fermentation of soft endosperm, GSHE dose can be reduced. Due to nutrients (lipids, minerals, and soluble proteins) present in corn that enhance yeast growth, ground corn fermented faster at the beginning than hard and soft endosperm.

  13. COOLING COIL EFFECTS ON BLENDING IN A PILOT SCALE TANK

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Fowley, M.; Steeper, T.

    2010-08-26

    Blending, or mixing, processes in 1.3 million gallon nuclear waste tanks are complicated by the fact that miles of serpentine, vertical, cooling coils are installed in the tanks. As a step toward investigating blending interference due to coils in this type of tank, a 1/10.85 scale tank and pump model were constructed for pilot scale testing. A series of tests were performed in this scaled tank by adding blue dye to visualize blending, and by adding acid or base tracers to solution to quantify the time required to effectively blend the tank contents. The acid and base tests were monitored with pH probes, which were located in the pilot scale tank to ensure that representative samples were obtained. Using the probes, the hydronium ion concentration [H{sup +}] was measured to ensure that a uniform concentration was obtained throughout the tank. As a result of pilot scale testing, a significantly improved understanding of mixing, or blending, in nuclear waste tanks has been achieved. Evaluation of test data showed that cooling coils in the waste tank model increased pilot scale blending times by 200% in the recommended operating range, compared to previous theoretical estimates of a 10-50% increase. Below the planned operating range, pilot scale blending times were increased by as much as 700% in a tank with coils installed. One pump, rather than two or more, was shown to effectively blend the tank contents, and dual pump nozzles installed parallel to the tank wall were shown to provide optimal blending. In short, experimental results varied significantly from expectations.

  14. Production of ethanol from lignocellulosic materials using thermophilic bacteria

    SciTech Connect (OSTI)

    Lynd, L.R.

    1987-01-01

    The production of ethanol from lignocellulosic materials, e.g. wood, agricultural residues, and municipal solid wastes, is considered. The conversion of these materials to ethanol in the US could annually yield approximately 430 million tons ethanol, or about 9.8 quads, within the next 20 years. Thermophilic bacteria have advantages over yeasts for ethanol production because various species produce an active cellulase enzyme and utilize pentose sugars. However thermophiles have lower ethanol tolerance and usually lower ethanol yields. The potential of thermophilic ethanol production from hardwood chips is examined in detail. It is concluded that if high ethanol yield can be achieved this process could have economics competitive with either ethanol production from corn via yeast or synthetic production from ethylene. Low ethanol tolerance is not a major problem provided concentrations {ge} 1.5% are produced, ethanol is continuously removed from the fermentor, and IHOSR/extractive distillation is employed. Research was undertaken aimed at closing the gap between the attractive potential of thermophiles for ethanol production, and that which is possible based on present knowledge, which is not practical. Major topics were the activity of Clostridium thermocellum cellulase on pretreated mixed hardwood and Avicel in vivo, continuous culture of C. thermocellum on pretreated mixed hardwood and Avicel, and the continuous culture of Clostridium thermosaccharolyticum at high xylose concentrations in the presence and absence of ethanol removal.

  15. Ethanol from biomass: A status report

    SciTech Connect (OSTI)

    Walker, R.

    1996-12-31

    Programmatic and technical activities of SWAN Biomass, a company formed by Amoco Corporation and Stone & Webster, to convert non-grain biomass material to ethanol, are highlighted in this presentation. The potential ethanol markets identified are: (1) fuel oxygenate and octane additive, and (2) waste reduction in the agricultural and forestry industries and in municipal waste streams. Differences in the SWAN process from that used in corn-based ethanol facilities include more intense pretreatment of lignocellulosic biomass, different enzymes, hydrolysis and fermentation of sugar polymers is performed in the same vessel, and a typical solid residue of lignin. The major market and technical risks have been assessed as being manageable. 8 figs., 8 tabs.

  16. Catalytic Process for the Conversion of Coal-derived Syngas to Ethanol

    SciTech Connect (OSTI)

    James Spivery; Doug Harrison; John Earle; James Goodwin; David Bruce; Xunhau Mo; Walter Torres; Joe Allison Vis Viswanathan; Rick Sadok; Steve Overbury; Viviana Schwartz

    2011-07-29

    The catalytic conversion of coal-derived syngas to C{sub 2+} alcohols and oxygenates has attracted great attention due to their potential as chemical intermediates and fuel components. This is particularly true of ethanol, which can serve as a transportation fuel blending agent, as well as a hydrogen carrier. A thermodynamic analysis of CO hydrogenation to ethanol that does not allow for byproducts such as methane or methanol shows that the reaction: 2 CO + 4 H{sub 2} {yields} C{sub 2}H{sub 5}OH + H{sub 2}O is thermodynamically favorable at conditions of practical interest (e.g,30 bar, {approx}< 250 C). However, when methane is included in the equilibrium analysis, no ethanol is formed at any conditions even approximating those that would be industrially practical. This means that undesired products (primarily methane and/or CO{sub 2}) must be kinetically limited. This is the job of a catalyst. The mechanism of CO hydrogenation leading to ethanol is complex. The key step is the formation of the initial C-C bond. Catalysts that are selective for EtOH can be divided into four classes: (a) Rh-based catalysts, (b) promoted Cu catalysts, (c) modified Fischer-Tropsch catalysts, or (d) Mo-sulfides and phosphides. This project focuses on Rh- and Cu-based catalysts. The logic was that (a) Rh-based catalysts are clearly the most selective for EtOH (but these catalysts can be costly), and (b) Cu-based catalysts appear to be the most selective of the non-Rh catalysts (and are less costly). In addition, Pd-based catalysts were studied since Pd is known for catalyzing CO hydrogenation to produce methanol, similar to copper. Approach. The overall approach of this project was based on (a) computational catalysis to identify optimum surfaces for the selective conversion of syngas to ethanol; (b) synthesis of surfaces approaching these ideal atomic structures, (c) specialized characterization to determine the extent to which the actual catalyst has these structures, and (d) testing at realistic conditions (e.g., elevated pressures) and differential conversions (to measure true kinetics, to avoid deactivation, and to avoid condensable concentrations of products in the outlet gas).

  17. Phosphor blends for high-CRI fluorescent lamps

    DOE Patents [OSTI]

    Setlur, Anant Achyut; Srivastava, Alok Mani; Comanzo, Holly Ann; Manivannan, Venkatesan; Beers, William Winder; Toth, Katalin; Balazs, Laszlo D.

    2008-06-24

    A phosphor blend comprises at least two phosphors each selected from one of the groups of phosphors that absorb UV electromagnetic radiation and emit in a region of visible light. The phosphor blend can be applied to a discharge gas radiation source to produce light sources having high color rendering index. A phosphor blend is advantageously includes the phosphor (Tb,Y,LuLa,Gd).sub.x(Al,Ga).sub.yO.sub.12:Ce.sup.3+, wherein x is in the range from about 2.8 to and including 3 and y is in the range from about 4 to and including 5.

  18. RIVER PROTECTION PROJECT MISSION ANALYSIS WASTE BLENDING STUDY

    SciTech Connect (OSTI)

    SHUFORD DH; STEGEN G

    2010-04-19

    Preliminary evaluation for blending Hanford site waste with the objective of minimizing the amount of high-level waste (HLW) glass volumes without major changes to the overall waste retrieval and processing sequences currently planned. The evaluation utilizes simplified spreadsheet models developed to allow screening type comparisons of blending options without the need to use the Hanford Tank Waste Operations Simulator (HTWOS) model. The blending scenarios evaluated are expected to increase tank farm operation costs due to increased waste transfers. Benefit would be derived from shorter operating time period for tank waste processing facilities, reduced onsite storage of immobilized HLW, and reduced offsite transportation and disposal costs for the immobilized HLW.

  19. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications

    Broader source: Energy.gov [DOE]

    Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations

  20. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, H.M.; Chen, M.J.

    1980-05-21

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by-product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

  1. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, H.M.; Chen, M.J.

    1981-09-24

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium, ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

  2. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, Harold M.; Chen, Michael J.

    1981-01-01

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

  3. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, Harold M.; Chen, Michael J.

    1983-01-01

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

  4. Mechanistic Investigation of Ethanol SCR of NOx over Ag/Al2O3

    SciTech Connect (OSTI)

    Johnson, William L; Fisher, Galen; Toops, Todd J

    2012-01-01

    A 2 wt.% Ag/{gamma}-Al{sub 2}O{sub 3} catalyst was studied for the ethanol selective catalytic reduction of NO{sub x} from 200 to 550 C and space velocities between 30,000 h{sup -1} and 140,000 h{sup -1}. Peak NO{sub x} conversions reached 85% at 400 C, and an activation energy was determined to be 57 kJ/mol with a feed of ethanol to NO{sub x} or HC{sub 1}/NO{sub x} = 3. Up to 80% of the NO is oxidized to NO{sub 2} at 250 C, but overall NO{sub x} conversion is only 15%. Interestingly, ethanol oxidation occurs at much lower temperatures than NO{sub x} reduction; at 250 C, ethanol oxidation is 80% when flowing ethanol + NO + O{sub 2}. This increased reactivity, compared to only 15% when flowing only ethanol + O{sub 2}, combined with the observation that NO is not oxidized to NO{sub 2} in the absence of ethanol illustrates a synergistic relationship between the reactants. To further investigate this chemistry, a series of DRIFTS experiments were performed. To form nitrates/nitrites on the catalysts it was necessary to include ethanol in the feed with NO. These nitrates/nitrites were readily formed when flowing NO{sub 2} over the catalyst. It is proposed that ethanol adsorbs through an ethoxy-intermediate that results in atomic hydrogen on the surface. This hydrogen aids the release of NO{sub 2} from Ag to the gas-phase which, can be subsequently adsorbed at {gamma}-Al{sub 2}O{sub 3} sites away from Ag. The disappearance of these nitrates/nitrites at higher temperatures proceeds in parallel with the increase in NO{sub x} reduction reactivity between 300 and 350 C observed in the kinetic study. It is therefore proposed that the consumption of nitrates is involved in the rate determining step for this reaction.

  5. Effects of gasoline reactivity and ethanol content on boosted premixed and partially stratified low-temperature gasoline combustion (LTGC)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dec, John E.; Yang, Yi; Ji, Chunsheng; Dernotte, Jeremie

    2015-04-14

    Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel Φ- sensitive so that partial fuel stratification (PFS) can be applied for highermore » loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion. Accordingly, an experimental investigation has been conducted to determine how the tradeoff between the effects of intake boost varies with fuel-type and its impact on load range and TE. Five fuels are investigated: a conventional AKI=87 petroleum-based gasoline (E0), and blends of 10 and 20% ethanol with this gasoline to reduce its reactivity enhancement with boost (E10 and E20). Furthermore, a second zero-ethanol gasoline with AKI=93 (matching that of E20) was also investigated (CF-E0), and some neat ethanol data are also reported.« less

  6. Chippewa Valley Ethanol Company CVEC | Open Energy Information

    Open Energy Info (EERE)

    CVEC Jump to: navigation, search Name: Chippewa Valley Ethanol Company (CVEC) Place: NW Benson, Minnesota Zip: 56215 Product: Owns 57.0m litres a year dry mill ethanol plant....

  7. Largest Cellulosic Ethanol Plant in the World Opened in October

    Broader source: Energy.gov [DOE]

    TheDuPont cellulosic ethanol facility openedin Nevada, Iowa, last month and isthe largest cellulosic ethanol plant in the world. The U.S. Department of Energy (DOE) Bioenergy Technologies Office...

  8. Evolved strains of Scheffersomyces stipitis achieving high ethanol...

    Office of Scientific and Technical Information (OSTI)

    useful for the production of fuel-grade ethanol via the processing steps of ... ability to accumulate >40 gL ethanol in <167 h when fermenting hydrolyzate at low ...

  9. Simple, Ethanol-Driven Synthesis of Core-Shell Nanoparticles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Simple, Ethanol-Driven Synthesis of Core-Shell ... This "green" synthesis method uses ethanol - a simple solvent for metal precursors "as the ...

  10. Ask a scientist: Ethanol & car performance | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ask a scientist: Ethanol & car performance September 13, 2013 Tweet EmailPrint Does ethanol extend or decrease your gas mileage? -Tommy Holly, via Facebook JEHLIK: In a one-to-one ...

  11. State-level workshops on ethanol for transportaton

    SciTech Connect (OSTI)

    Graf, Angela

    2004-01-01

    The Ethanol Workshop Series (EWS) was intended to provide a forum for interest groups to gather and discuss what needs to be accomplished to facilitate ethanol production in-state using local biomass resources.

  12. Alternative Fuels Data Center: Status Update: Ethanol Blender Pump

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Dispenser Certified (August 2010) Ethanol Blender Pump Dispenser Certified (August 2010) to someone by E-mail Share Alternative Fuels Data Center: Status Update: Ethanol Blender Pump Dispenser Certified (August 2010) on Facebook Tweet about Alternative Fuels Data Center: Status Update: Ethanol Blender Pump Dispenser Certified (August 2010) on Twitter Bookmark Alternative Fuels Data Center: Status Update: Ethanol Blender Pump Dispenser Certified (August 2010) on Google Bookmark Alternative

  13. Ethanol Vehicle and Infrastructure Codes and Standards Citations (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-07-01

    This document lists codes and standards typically used for U.S. ethanol vehicle and infrastructure projects.

  14. Renewable Fuels Association’s National Ethanol Conference

    Broader source: Energy.gov [DOE]

    Mark Elless, a BETO technology manager, will be representing BETO at the 20th anniversary of the National Ethanol Conference.

  15. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synthesis of Lignocellulosic Biomass | Department of Energy Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot level by 2012. PDF icon Thermochemical Ethanol via

  16. Clean Cities: Ethanol Basics, Fact Sheet, October 2008

    SciTech Connect (OSTI)

    Not Available

    2008-10-01

    Document answers frequently asked questions about ethanol as a transportation fuel, including those on production, environmental effects, and vehicles.

  17. Research Advances Cellulosic Ethanol, NREL Leads the Way (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2007-03-01

    This brochure highlights NREL's recent advances in cellulosic ethanol production. Research at NREL addresses both biochemical and thermochemical processes.

  18. Autothermal Partial Oxidation of Ethanol and Alcohols - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Autothermal Partial Oxidation of Ethanol and Alcohols Syngas from Autothermal Reforming of Ethanol DOE Grant Recipients University of Minnesota Contact University of Minnesota About This Technology Technology Marketing Summary Autothermal Reforming of Ethanol and Alcohols into Syngas Ethanol and alcohols can be converted into syngas using a robust autothermal reforming process. Syngas is a mixture of carbon

  19. Time phased alternate blending of feed coals for liquefaction

    DOE Patents [OSTI]

    Schweigharett, Frank; Hoover, David S.; Garg, Diwaker

    1985-01-01

    The present invention is directed to a method for reducing process performance excursions during feed coal or process solvent changeover in a coal hydroliquefaction process by blending of feedstocks or solvents over time. ,

  20. Photonic polymer-blend structures and method for making

    DOE Patents [OSTI]

    Barnes, Michael D.

    2004-06-29

    The present invention comprises the formation of photonic polymer-blend structures having tunable optical and mechanical properties. The photonic polymer-blend structures comprise monomer units of spherical microparticles of a polymer-blend material wherein the spherical microparticles have surfaces partially merged with one another in a robust inter-particle bond having a tunable inter-particle separation or bond length sequentially attached in a desired and programmable architecture. The photonic polymer-blend structures of the present invention can be linked by several hundred individual particles sequentially linked to form complex three-dimensional structures or highly ordered two-dimensional arrays of 3D columns with 2D spacing.

  1. Conversion and Blending Facility highly enriched uranium to low enriched uranium as metal. Revision 1

    SciTech Connect (OSTI)

    1995-07-05

    The mission of this Conversion and Blending Facility (CBF) will be to blend surplus HEU metal and alloy with depleted uranium metal to produce an LEU product. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The blended LEU will be produced as a waste suitable for storage or disposal.

  2. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene

    SciTech Connect (OSTI)

    Smith, R. Scott; Matthiesen, Jesper; Kay, Bruce D.

    2014-09-18

    The desorption kinetics of methanol, ethanol, and water from graphene covered Pt(111) are investigated. The temperature programmed desorption (TPD) spectra for both methanol and ethanol have well-resolved first, second, third, and multilayer layer desorption peaks. The alignment of the leading edges is consistent with zero-order desorption kinetics from all layers. In contrast, for water the first and second layers are not resolved. At low water coverages (< 1 ML) the initial desorption leading edges are aligned but then fall out of alignment at higher temperatures. For thicker water layers (10 to 100 ML), the desorption leading edges are in alignment throughout the desorption of the film. The coverage dependence of the desorption behavoir suggests that at low water coverages the non-alignment of the desorption leading edges is due to water dewetting from the graphene substrate. Kinetic simulations reveal that the experimental results are consistent with zero-order desorption. The simulations also show that fractional order desorption kinetics would be readily apparent in the experimental TPD spectra.

  3. EA-1694: Department of Energy Loan Guarantee to Highlands Ethanol, LLC, for the Cellulosic Ethanol Facility in Highlands County, Florida

    Broader source: Energy.gov [DOE]

    This EA will evaluate the environmental impacts of a proposal to issue a Federal loan guarantee to Highlands Ethanol, LLC, for a cellulosic ethanol facility in Highlands County, Florida. This EA is on hold.

  4. Macrophase Separation of Blends of Diblock Copolymers in Thin Films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Macrophase Separation of Blends of Diblock Copolymers in Thin Films Citation Details In-Document Search Title: Macrophase Separation of Blends of Diblock Copolymers in Thin Films Authors: Williamson, Lance D. ; Nealey, Paul F. [1] + Show Author Affiliations (UC) Publication Date: 2015-08-26 OSTI Identifier: 1203744 Resource Type: Journal Article Resource Relation: Journal Name: Macromolecules; Journal Volume: 48; Journal Issue: (12) ; 06, 2015 Research

  5. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  6. NOx Aftertreatment Using Ethanol as Reductant

    Broader source: Energy.gov [DOE]

    The hydrocarbon-SCR that was developed using ethanol and E85 as the reductant showed high NOx reduction, no need for thawing, use of existing infrastructure, and reduced system cost making it a viable alternative to urea-based SCR

  7. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal; Barbosa-Alleyne, Maria D. F.

    1996-01-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  8. Ethanol production in gram-positive microbes

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal; Barbosa-Alleyne, Maria D. F.

    1999-01-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  9. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, L.O.; Barbosa-Alleyne, M.D.F.

    1999-06-29

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase. 2 figs.

  10. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, L.O.; Barbosa-Alleyne, M.D.F.

    1996-01-09

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase. 2 figs.

  11. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de [Institut fr Kunststofftechnik, University of Stuttgart (Germany)

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  12. Nucleic acid molecules conferring enhanced ethanol tolerance and microorganisms having enhanced tolerance to ethanol

    DOE Patents [OSTI]

    Brown, Steven; Guss, Adam; Yang, Shihui; Karpinets, Tatiana; Lynd, Lee; Shao, Xiongjun

    2014-01-14

    The present invention provides isolated nucleic acid molecules which encode a mutant acetaldehyde-CoA/alcohol dehydrogenase or mutant alcohol dehydrogenase and confer enhanced tolerance to ethanol. The invention also provides related expression vectors, genetically engineered microorganisms having enhanced tolerance to ethanol, as well as methods of making and using such genetically modified microorganisms for production of biofuels based on fermentation of biomass materials.

  13. NREL Proves Cellulosic Ethanol Can Be Cost Competitive (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-11-01

    Ethanol from non-food sources - known as "cellulosic ethanol" - is a near-perfect transportation fuel: it is clean, domestic, abundant, and renewable, and it can potentially replace 30% of the petroleum consumed in the United States, but its relatively high cost has limited its market. That changed in 2012, when the National Renewable Energy Laboratory (NREL) demonstrated the technical advances needed to produce cellulosic ethanol at a minimum ethanol selling price of $2.15/gallon (in 2007 dollars). Through a multi-year research project involving private industry, NREL has proven that cellulosic ethanol can be cost competitive with other transportation fuels.

  14. Recent Advances in Catalytic Conversion of Ethanol to Chemicals

    SciTech Connect (OSTI)

    Sun, Junming; Wang, Yong

    2014-04-30

    With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

  15. Low-Temperature Biodiesel Research Reveals Potential Key to Successful Blend Performance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-02-01

    Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option. While biodiesel has very low production costs and the potential to displace up to 10% of petroleum diesel, until now, issues with cold weather performance have prevented biodiesel blends from being widely adopted. Some biodiesel blends have exhibited unexplained low-temperature performance problems even at blend levels as low as 2% by volume. The most common low-temperature performance issue is vehicle stalling caused by fuel filter clogging, which prevents fuel from reaching the engine. Research at the National Renewable Energy Laboratory (NREL) reveals the properties responsible for these problems, clearing a path for the development of solutions and expanded use of energy-conserving and low-emissions alternative fuel. NREL researchers set out to study the unpredictable nature of biodiesel crystallization, the condition that impedes the flow of fuel in cold weather. Their research revealed for the first time that saturated monoglyceride impurities common to the biodiesel manufacturing process create crystals that can cause fuel filter clogging and other problems when cooling at slow rates. Biodiesel low-temperature operational problems are commonly referred to as 'precipitates above the cloud point (CP).' NREL's Advanced Biofuels team spiked distilled soy and animal fat-derived B100, as well as B20, B10, and B5 biodiesel blends with three saturated monoglycerides (SMGs) at concentration levels comparable to those of real-world fuels. Above a threshold or eutectic concentration, the SMGs (monomyristin, monopalmitin, and monostearin) were shown to significantly raise the biodiesel CP, and had an even greater impact on the final melting temperature. Researchers discovered that upon cooling, monoglyceride initially precipitates as a metastable crystal, but it transforms over time or upon slight heating into a more stable crystal with a much lower solubility and higher melting temperature - and with increased potential to cause vehicle performance issues. This explains why fuel-filter clogging typically occurs over the course of long, repeated diurnal cooling cycles. The elevated final melting points mean that restarting vehicles with clogged filters can be difficult even after ambient temperatures have warmed to well above CP. By examining how biodiesel impurities affect filtration and crystallization during warming and cooling cycles, NREL researchers uncovered an explanation for poor biodiesel performance at low temperatures. The observation of a eutectic point, or a concentration below which SMGs have no effect, indicates that SMGs do not have to be completely removed from biodiesel to solve low-temperature performance problems.

  16. Fuel Economy and Emissions of the Ethanol-Optimized Saab 9-5 Biopower

    SciTech Connect (OSTI)

    West, Brian H; Lopez Vega, Alberto; Theiss, Timothy J; Graves, Ronald L; Storey, John Morse; Lewis Sr, Samuel Arthur

    2007-01-01

    Saab Automobile recently released the BioPower engines, advertised to use increased turbocharger boost and spark advance on ethanol fuel to enhance performance. Specifications for the 2.0 liter turbocharged engine in the Saab 9-5 Biopower 2.0t report 150 hp on gasoline and a 20% increase to 180 hp on E85 (nominally 85% ethanol, 15% gasoline). While FFVs sold in the U.S. must be emissions certified on Federal Certification Gasoline as well as on E85, the European regulations only require certification on gasoline. Owing to renewed and growing interest in increased ethanol utilization in the U.S., a European-specification 2007 Saab 9-5 Biopower 2.0t was acquired by the Department of Energy and Oak Ridge National Laboratory (ORNL) for benchmark evaluations. Results show that the BioPower vehicle's gasoline equivalent fuel economy on the Federal Test Procedure (FTP) and the Highway Fuel Economy Test (HFET) are on par with similar U.S.-legal flex-fuel vehicles. Regulated and unregulated emissions measurements on the FTP and the US06 aggressive driving test (part of the supplemental FTP) show that despite the lack of any certification testing requirement in Europe on E85 or on the U.S. cycles, the BioPower is within Tier 2, Bin 5 emissions levels (note that full useful life emissions have not been measured) on the FTP, and also within the 4000 mile US06 emissions limits. Emissions of hydrocarbon-based hazardous air pollutants are higher on Federal Certification Gasoline while ethanol and aldehyde emissions are higher on ethanol fuel. The advertised power increase on E85 was confirmed through acceleration tests on the chassis dyno as well as on-road.

  17. Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

    2013-07-01

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

  18. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  19. Production of ethanol by immobilized Saccharomyces bayanus in an extractive fermentation system

    SciTech Connect (OSTI)

    Barros, M.R.A.; Cabral, J.M.S.; Novais, J.M.

    1987-01-01

    An extractive fermentation system using immobilized yeast cells was developed to study the ethanol production at high sugar concentrations. Organic acids were used as extracting solvents of ethanol and their toxicity was tested in free and k-carrageenan entrapped cell preparations. Immobilization seems to protect cells against solvent toxicity, when long-chain organic acids, e.g., oleic acid, were used, probably due to steric and diffusional limitations, the free cells not being viable at high oleic acid concentrations. The entrapped cells also present a high metabolic activity than their free counterparts at high glucose concentrations. A solution of 300 g/L of glucose was totally fermented by the immobilized yeast cells, which when free cannot normally convert more than 200 g/L. In situ recovery of ethanol by oleic acid in a batch immobilized cell system led to higher ethanol productivities and to the fermentation of 400 g/L, when an oleic acid/medium ratio of 5 was used.

  20. Assessment of the Electrohol process to manufacture acetaldehyde from ethanol electrogeneratively. Final report

    SciTech Connect (OSTI)

    Trevino, A.A.

    1985-04-10

    Preliminary process economics data for the electrogenerative process to manufacture acetaldehyde from ethanol were generated based on patent information. The technology was assessed in four alternative processing options. The Electrohol process is viable in the US only if integrated to the production of 190 pf ethanol from corn in a large scale unit. To be competitive, the Electrohol process must show yields in excess of 93%. Its attractiveness depends on corn prices remaining under $2.90/bu and DDG selling for more than $132/T. A corn price of $2.00/bu is needed to make a farm-size corn-based processing alternative competitive. A plant based on the fermentation of molasses proved too expensive under the US economic assumptions. The Electrohol technology based on purchased ethanol cannot compete with the existing ethylene-based process under current conditions. To become attractive, the Electrohol process must have access to cheap ethanol ($1.43/gal). The zero electricity generation mode is the most attractive mode of operation for the Electrohol technology in the US. The penalty for low levels of generation (0.130 kwh/kg AcH) is, however, negligible. The optimum operating mode in W. Europe is the generation of 0.312 kwh/kg AcH. In Japan, the low generation level is perferred (0.130 kwh/kg AcH). In general, higher energy prices improve the competitiveness of the Electrohol processing alternatives.

  1. Ethanol extraction of phytosterols from corn fiber

    DOE Patents [OSTI]

    Abbas, Charles; Beery, Kyle E.; Binder, Thomas P.; Rammelsberg, Anne M.

    2010-11-16

    The present invention provides a process for extracting sterols from a high solids, thermochemically hydrolyzed corn fiber using ethanol as the extractant. The process includes obtaining a corn fiber slurry having a moisture content from about 20 weight percent to about 50 weight percent solids (high solids content), thermochemically processing the corn fiber slurry having high solids content of 20 to 50% to produce a hydrolyzed corn fiber slurry, dewatering the hydrolyzed corn fiber slurry to achieve a residual corn fiber having a moisture content from about 30 to 80 weight percent solids, washing the residual corn fiber, dewatering the washed, hydrolyzed corn fiber slurry to achieve a residual corn fiber having a moisture content from about 30 to 80 weight percent solids, and extracting the residual corn fiber with ethanol and separating at least one sterol.

  2. Effect of temperature on the hydration of Portland cement blended with siliceous fly ash

    SciTech Connect (OSTI)

    Deschner, Florian; Lothenbach, Barbara; Winnefeld, Frank; Neubauer, Jrgen

    2013-10-15

    The effect of temperature on the hydration of Portland cement pastes blended with 50 wt.% of siliceous fly ash is investigated within a temperature range of 7 to 80 C. The elevation of temperature accelerates both the hydration of OPC and fly ash. Due to the enhanced pozzolanic reaction of the fly ash, the change of the composition of the CSH and the pore solution towards lower Ca and higher Al and Si concentrations is shifted towards earlier hydration times. Above 50 C, the reaction of fly ash also contributes to the formation of siliceous hydrogarnet. At 80 C, ettringite and AFm are destabilised and the released sulphate is partially incorporated into the CSH. The observed changes of the phase assemblage in dependence of the temperature are confirmed by thermodynamic modelling. The increasingly heterogeneous microstructure at elevated temperatures shows an increased density of the CSH and a higher coarse porosity. -- Highlights: The reaction of quartz powder at 80 C strongly enhances the compressive strength. Almost no strength increase of fly ash blended OPC at 80 C was found after 2 days. Siliceous hydrogarnet is formed upon the reaction of fly ash at high temperatures. Temperature dependent change of the system was simulated by thermodynamic modelling. Destabilisation of ettringite above 50 C correlates with sulphate content of CSH.

  3. Exploiting Photo-induced Reactions in Polymer Blends to Create Hierarchically Ordered, Defect-free Materials

    ScienceCinema (OSTI)

    Balazs, Anna [University of Pittsburgh, Pittsburgh, Pennsylvania, United States

    2010-01-08

    Computer simulations reveal how photo-induced chemical reactions can be exploited to create long-range order in binary and ternary polymeric materials. The process is initiated by shining a spatially uniform light over a photosensitive AB binary blend, which undergoes both a reversible chemical reaction and phase separation. We then introduce a well-collimated, higher-intensity light source. Rastering this secondary light over the sample locally increases the reaction rate and causes formation of defect-free, spatially periodic structures. These binary structures resemble either the lamellar or hexagonal phases of microphase-separated di-block copolymers. We measure the regularity of the ordered structures as a function of the relative reaction rates for different values of the rastering speed and determine the optimal conditions for creating defect-free structures in the binary systems. We then add a non-reactive homo-polymer C, which is immiscible with both A and B. We show that this component migrates to regions that are illuminated by the secondary, higher-intensity light, allowing us to effectively write a pattern of C onto the AB film. Rastering over the ternary blend with this collimated light now leads to hierarchically ordered patterns of A, B, and C. The findings point to a facile, non-intrusive process for manufacturing high-quality polymeric devices in a low-cost, efficient manner.

  4. Controlled differential pressure system for an enhanced fluid blending apparatus

    DOE Patents [OSTI]

    Hallman, Jr., Russell Louis

    2009-02-24

    A system and method for producing a controlled blend of two or more fluids. Thermally-induced permeation through a permeable tube is used to mix a first fluid from outside the tube with a second fluid flowing through the tube. Mixture ratios may be controlled by adjusting the temperature of the first fluid or by adjusting the pressure drop through the permeable tube. The combination of a back pressure control valve and a differential regulator is used to control the output pressure of the blended fluid. The combination of the back pressure control valve and differential regulator provides superior flow control of the second dry gas. A valve manifold system may be used to mix multiple fluids, and to adjust the volume of blended fluid produced, and to further modify the mixture ratio.

  5. Certification of alternative aviation fuels and blend components

    SciTech Connect (OSTI)

    Wilson III, George R. ); Edwards, Tim; Corporan, Edwin ); Freerks, Robert L. )

    2013-01-15

    Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend components for turbine engine fuels as discussed in this paper.

  6. Effect of simultaneous electrical and thermal treatment on the performance of bulk heterojunction organic solar cell blended with organic salt

    SciTech Connect (OSTI)

    Sabri, Nasehah Syamin; Yap, Chi Chin; Yahaya, Muhammad; Salleh, Muhamad Mat

    2013-11-27

    This work presents the influence of simultaneous electrical and thermal treatment on the performance of organic solar cell blended with organic salt. The organic solar cells were composed of indium tin oxide as anode, poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]: (6,6)-phenyl-C61 butyric acid methyl ester: tetrabutylammonium hexafluorophosphate blend as organic active layer and aluminium as cathode. The devices underwent a simultaneous fixed-voltage electrical and thermal treatment at different temperatures of 25, 50 and 75 °C. It was found that photovoltaic performance improved with the thermal treatment temperature. Accumulation of more organic salt ions in the active layer leads to broadening of p-n doped regions and hence higher built-in electric field across thin intrinsic layer. The simultaneous electrical and thermal treatment has been shown to be able to reduce the electrical treatment voltage.

  7. Pathway engineering to improve ethanol production by thermophilic bacteria

    SciTech Connect (OSTI)

    Lynd, L.R.

    1998-12-31

    Continuation of a research project jointly funded by the NSF and DOE is proposed. The primary project goal is to develop and characterize strains of C. thermocellum and C. thermosaccharolyticum having ethanol selectivity similar to more convenient ethanol-producing organisms. An additional goal is to document the maximum concentration of ethanol that can be produced by thermophiles. These goals build on results from the previous project, including development of most of the genetic tools required for pathway engineering in the target organisms. As well, we demonstrated that the tolerance of C. thermosaccharolyticum to added ethanol is sufficiently high to allow practical utilization should similar tolerance to produced ethanol be demonstrated, and that inhibition by neutralizing agents may explain the limited concentrations of ethanol produced in studies to date. Task 1 involves optimization of electrotransformation, using either modified conditions or alternative plasmids to improve upon the low but reproducible transformation, frequencies we have obtained thus far.

  8. BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines June 22, 2015 - ...

  9. Final Report on Development of Thermoanaerobacterium saccharolyticum for the conversion of lignocellulose to ethanol

    SciTech Connect (OSTI)

    Herring, Christopher D.; Kenealy, William R.; Shaw, A. Joe; Raman, Babu; Tschaplinski, Timothy J.; Brown, Steven D.; Davison, Brian H.; Covalla, Sean F.; Sillers, W. Ryan; Xu, Haowen; Tsakraklides, Vasiliki; Hogsett, David A.

    2012-01-24

    This project addressed the need for economical technology for the conversion of lignocellulosic biomass to fuels, specifically the conversion of pretreated hardwood to ethanol. The technology developed is a set of strains of the bacterium Thermoanaerobacterium saccharolyticum and an associated fermentation process for pretreated hardwood. Tools for genetic engineering and analysis of the organism were developed, including a markerless mutation method, a complete genome sequence and a set of gene expression profiles that show the activity of its genes under a variety of conditions relevant to lignocellulose conversion. Improved strains were generated by selection and genetic engineering to be able to produce higher amounts of ethanol (up to 70 g/L) and to be able to better tolerate inhibitory compounds from pretreated hardwood. Analysis of these strains has generated useful insight into the genetic basis for desired properties of biofuel producing organisms. Fermentation conditions were tested and optimized to achieve ethanol production targets established in the original project proposal. The approach proposed was to add cellulase enzymes to the fermentation, a method called Simultaneous Saccharification and Fermentation (SSF). We had reason to think SSF would be an efficient approach because the optimal temperature and pH for the enzymes and bacterium are very close. Unfortunately, we discovered that commercially available cellulases are inactivated in thermophilic SSF by a combination of low redox potential and ethanol. Despite this, progress was made against the fermentation targets using bacterial cellulases. Thermoanaerobacterium saccharolyticum may still prove to be a commercially viable technology should cellulase enzyme issues be addressed. Moreover, the organism was demonstrated to produce ethanol at approximately theoretical yield from oligomeric hemicellulose extracts, an ability that may prove to be uniquely valuable in pretreatment configurations in which cellulose and hemicellulose are separated.

  10. Alternative Fuels Data Center: Status Update: Clarification of Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Certification Limits for Legacy Equipment (December 2008) Clarification of Ethanol Certification Limits for Legacy Equipment (December 2008) to someone by E-mail Share Alternative Fuels Data Center: Status Update: Clarification of Ethanol Certification Limits for Legacy Equipment (December 2008) on Facebook Tweet about Alternative Fuels Data Center: Status Update: Clarification of Ethanol Certification Limits for Legacy Equipment (December 2008) on Twitter Bookmark Alternative Fuels Data

  11. The Current State of Technology for Cellulosic Ethanol | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy The Current State of Technology for Cellulosic Ethanol The Current State of Technology for Cellulosic Ethanol At the February 12, 2009 joint Web conference of DOE's Biomass and Clean Cities programs, Andy Aden (National Renewable Energy Laboratory) discussed the current state of technology for cellulosic ethanol - How close are we? PDF icon aden_20090212.pdf More Documents & Publications Integrated Biorefinery Process Process Design and Economics for Biochemical Conversion of

  12. Lipid-enhanced ethanol production from xylose by Pachysolen tannophilus

    SciTech Connect (OSTI)

    Dekker, R.F.H.

    1986-01-01

    This paper reports improved ethanol yields following the fermentation of xylose by a Pachysolen tannophilus strain when grown semi-aerobically in the presence of exogenous-added lipids. Profiles for ethanol production from 45 g/L xylose when grown on a medium containing ergosterol, linoleic acid, Tween-80, a mixture of the three lipids and no lipids (control) are presented. The enhancement in the amount of ethanol produced was most pronounced after 72 h fermentation.

  13. Dissociative electron attachments to ethanol and acetaldehyde: A combined

    Office of Scientific and Technical Information (OSTI)

    experimental and simulation study (Journal Article) | SciTech Connect Dissociative electron attachments to ethanol and acetaldehyde: A combined experimental and simulation study Citation Details In-Document Search Title: Dissociative electron attachments to ethanol and acetaldehyde: A combined experimental and simulation study Dissociation dynamics of the temporary negative ions of ethanol and acetaldehyde formed by the low-energy electron attachments is investigated by using the anion

  14. Florida Project Produces Nation's First Cellulosic Ethanol at

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial-Scale | Department of Energy Florida Project Produces Nation's First Cellulosic Ethanol at Commercial-Scale Florida Project Produces Nation's First Cellulosic Ethanol at Commercial-Scale July 31, 2013 - 1:37pm Addthis News Media Contact (202) 586-4940 WASHINGTON - The Energy Department today recognized the nation's first commercial-scale cellulosic ethanol production at INEOS Bio's Indian River BioEnergy Center in Vero Beach, Florida. Developed through a joint venture between

  15. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  16. EERE Success Story-Louisiana: Verenium Cellulosic Ethanol Demonstration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Facility | Department of Energy Louisiana: Verenium Cellulosic Ethanol Demonstration Facility EERE Success Story-Louisiana: Verenium Cellulosic Ethanol Demonstration Facility April 9, 2013 - 12:00am Addthis In 2010, Verenium Corporation received EERE funds to operate a 1.4 million gallon per year demonstration plant in Jennings, Louisiana, to convert agricultural residues and energy crops to cellulosic ethanol. The project's goal was to implement a technology that had been demonstrated in a

  17. Energy Landscape of Water and Ethanol on Silica Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reachingmore » its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.« less

  18. Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels

    Broader source: Energy.gov [DOE]

    Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

  19. More Efficient Ethanol Production from Mixed Sugars Using Spathaspora...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    More Efficient Ethanol Production from Mixed Sugars Using Spathaspora Yeast Great Lakes ... Cofermentation of mixed sugars Better rate and yield compared to other yeasts Efficient ...

  20. U.S. Fuel Ethanol Plant Production Capacity

    Gasoline and Diesel Fuel Update (EIA)

    This is the fifth release of U.S. Energy Information Administration data on fuel ethanol production capacity. EIA ... Detailed nameplate and maximum sustainable capacities of fuel ...

  1. Issues and Methods for Estimating the Percentage Share of Ethanol...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Energy Information Administration 1 Issues and Methods for Estimating the Share of Ethanol in the Motor Gasoline Supply U.S. Energy Information Administration October 6, 2011...

  2. Ethanol Usage in Urban Public Transportation - Presentation of...

    Open Energy Info (EERE)

    - Presentation of Results Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Ethanol Usage in Urban Public Transportation - Presentation of Results AgencyCompany...

  3. Ethanol Extraction Technologies Inc EETI | Open Energy Information

    Open Energy Info (EERE)

    Extraction Technologies Inc EETI Jump to: navigation, search Name: Ethanol Extraction Technologies Inc (EETI) Place: New York, New York Zip: 10036-2601 Product: New York-based...

  4. International Ethanol Trade Association IETHA | Open Energy Informatio...

    Open Energy Info (EERE)

    Trade Association IETHA Jump to: navigation, search Name: International Ethanol Trade Association (IETHA) Place: Sao Paulo, Sao Paulo, Brazil Product: Association of 48 globally...

  5. Pacific Ethanol Inc the former | Open Energy Information

    Open Energy Info (EERE)

    Inc the former Jump to: navigation, search Name: Pacific Ethanol Inc (the former) Place: Fresno, California Zip: 93711 Product: California-based developer of bioethanol plants....

  6. Integrated Biorefinery for conversion of Biomass to Ethanol,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - St. Louis MO Subsidiary of Abengoa SA, Spain Ethanol facilities in Nebraska, Kansas, New Mexico, Illinois, Indiana, Spain, France, Netherlands and Brazil 2 Goal Statement ...

  7. Lignocellulosic Biomass to Ethanol Process Design and Economics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover Lignocellulosic Biomass to Ethanol Process Design and ...

  8. Largest Cellulosic Ethanol Plant in the World Opened in October...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... representative from biofuels company POET-DSM stand between square and round bales of corn stover stock piled outside of POET-DSM's Project LIBERTY cellulosic ethanol biorefinery. ...

  9. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  10. Appendix D: 2012 Cellulosic Ethanol Success, Bioenergy Technologies...

    Broader source: Energy.gov (indexed) [DOE]

    produce cellulosic ethanol at commercial-scale costs that are competitive with gasoline production at 110barrel of crude oil. Many industry partners are also demonstrating...

  11. Report to Congress: Dedicated Ethanol Pipeline Feasability Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Independence and Security Act of 2007 (EISA). Section 243 directs DOE to study the feasibility of constructing and using pipelines dedicated to the transportation of ethanol. ...

  12. Ethanol production by thermophilic bacteria: fermentation of cellulosic substrates by cocultures of Clostridium thermocellum and Clostridium thermohydrosulfuricum

    SciTech Connect (OSTI)

    Ng, T.K.; Ben-Bassat, A.; Zeikus, J.G.

    1981-06-01

    The fermentation of various saccharides derived from cellulosic biomass to ethanol was examined in mono- and cocultures of Clostridium thermocellum strain LQRI and C. thermohydrosulfuricum strain 39E. C. thermohydrosulfuricum fermented glucose, cellobiose, and xylose, but not cellulose or xylan, and yielded ethanol/acetate ratios of >7.0 C. thermocellum fermented a variety of cellulosic substrates, glucose, and cellobiose, but not xylan or xylose, and yielded ethanol/acetate ratios of approx. 1.0. A stable coculture that contained nearly equal numbers of C. thermocellum and C. thermohydrosulfuricum was established that fermented a variety of cellulosic substrates, and the ethanol yield observed was twofold higher than in C. thermocellum monoculture fermentations. The metabolic basis for the enhanced fermentation effectiveness of the coculture on Solka Floc cellulose included: the ability of C. thermocellum cellulase to hydrolyze ..cap alpha..-cellulose and hemicellulose; the enhanced utilization of mono- and disaccharides by C. thermohydrosulfuricum; increased cellulose consumption; threefold increase in the ethanol production rate; and twofold decrease in the acetate production rate.

  13. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  14. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  15. Conversion of Ethanol to Hydrocarbons on Hierarchical HZSM-5 Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Zhang, He; Sun, Junming; Wang, Yong

    2014-02-22

    This study reports synthesis, characterization, and catalytic activity of the nano-size hierarchical HZSM-5 zeolite with high mesoporosity produced via a solvent evaporation procedure. Further, this study compares hierarchical zeolites with conventional HZSM-5 zeolite with similar Si/Al ratios for the ethanol-to-hydrocarbon conversion process. The catalytic performance of the hierarchical and conventional zeolites was evaluated using a fixed-bed reactor at 360 °C, 300 psig, and a weight hourly space velocity of 7.9 h-1. For the low Si/Al ratio zeolite (~40), the catalytic life-time for the hierarchical HZSM-5 was approximately 2 times greater than the conventional HZSM-5 despite its coking amount deposited 1.6 times higher than conventional HZSM-5. For the high Si/Al ratio zeolite (~140), the catalytic life-time for the hierarchical zeolite was approximately 5 times greater than the conventional zeolite and the amount of coking deposited was 2.1 times higher. Correlation was observed between catalyst life time, porosity, and the crystal size of the zeolite. The nano-size hierarchical HZSM-5 zeolites containing mesoporosity demonstrated improved catalyst life-time compared to the conventional catalyst due to faster removal of products, shorter diffusion path length, and the migration of the coke deposits to the external surface from the pore structure.

  16. U.S. transparency monitoring of HEU oxide conversion and blending to LEU hexafluoride at three Russian blending plants

    SciTech Connect (OSTI)

    Leich, D., LLNL

    1998-07-27

    The down-blending of Russian highly enriched uranium (HEU) takes place at three Russian gaseous centrifuge enrichment plants. The fluorination of HEU oxide and down-blending of HEU hexafluoride began in 1994, and shipments of low enriched uranium (LEU) hexafluoride product to the United States Enrichment Corporation (USEC) began in 1995 US transparency monitoring under the HEU Purchase Agreement began in 1996 and includes a permanent monitoring presence US transparency monitoring at these facilities is intended to provide confidence that HEU is received and down-blended to LEU for shipment to USEC The monitoring begins with observation of the receipt of HEU oxide shipments, including confirmation of enrichment using US nondestructive assay equipment The feeding of HEU oxide to the fluorination process and the withdrawal of HEU hexafluoride are monitored Monitoring is also conducted where the blending takes place and where shipping cylinders are filled with LEU product. A series of process and material accountancy documents are provided to US monitors.

  17. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, Terje

    1984-01-01

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  18. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, T.

    A polymer blend is disclosed of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  19. Largest Cellulosic Ethanol Plant in the World Opens October 30

    Broader source: Energy.gov [DOE]

    The DuPont cellulosic ethanol facility, opening in Nevada, Iowa, on October 30, will be the largest cellulosic ethanol plant in the world. The U.S. Department of Energy (DOE) Bioenergy Technologies Office (BETO) Director, Jonathan Male, alongside senior government officials, DuPont leaders and staff, and local farmers will attend the grand opening ceremony and plant tour.

  20. Making Better Use of Ethanol as a Transportation Fuel With "Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Breakout ...

  1. Investigation of Bio-Ethanol Steam Reforming over Cobalt-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Presented at the 2007 ...

  2. A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Pre-Treatment Model for Ethanol Production Using a Colorimetric Analysis of Starch Solutions (1 Activity) A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

  3. The U.S. Dry-Mill Ethanol Industry: Biobased Products and Bioenergy Initiative Success Stories

    SciTech Connect (OSTI)

    2009-10-28

    This fact sheet provides an overview of the history of ethanol production in the United States and describes innovations in dry-mill ethanol production.

  4. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Presented at the 2007 ...

  5. Dow and NREL Partner to Convert Biomass to Ethanol and Other...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dow and NREL Partner to Convert Biomass to Ethanol and Other Chemical Building Blocks July ... a process that will convert biomass to ethanol and other chemical building blocks. ...

  6. Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    such as Range Fuels, are blending science and technology to advance the President's ... will lead to the wide-scale use of non-food based biomass, such as agricultural waste, ...

  7. Preliminary report on blending strategies for inert-matrix fuel recycling in LWRs.

    SciTech Connect (OSTI)

    Hoffman, E. A.; Nuclear Engineering Division

    2005-04-29

    Various recycle strategies have been proposed to manage the inventory of transuranics in commercial spent nuclear fuel (CSNF), with a particular goal of increasing the loading capacity of spent fuel and reprocessing wastes in the Yucca Mountain repository. Transuranic recycling in commercial LWRs can be seen as a viable means of slowing the accumulation of transuranics in the nationwide CSNF stockpile. Furthermore, this type of approach is an important first step in demonstrating the benefits of a nuclear fuel cycle which incorporates recycling, such as envisioned for Generation-IV reactor systems under development. Recycling strategies of this sort are not proposed as an attempt to eliminate the need of a geologic nuclear waste repository, but as a means to enhance the usefulness of the repository currently under construction in the U.S., perhaps circumventing the need for a second facility. A US-DOE Secretarial recommendation on the need for the construction of a second geologic repository is required by 2010. The Advanced Fuel Cycle Initiative (AFCI) has supported a breadth of work to evaluate the ideal transuranic separation and recycle strategy. Previous AFCI studies of LWR-based transmutation have considered the benefits of homogeneously recycling plutonium, plutonium and neptunium, and all transuranic (TRU) species. A study of a wide range of hypothetical separation schemes (Pu, Pu+Np, Pu+Np+Am, etc.) with multi-recycling has also been performed, focusing on the proliferation resistance of the various fuel cycles and fuel handling issues. The direct recycle of the recovered TRU from spent inert-matrix fuel (IMF) into new IMF was found to be quite limited due to the rapid burndown of the fissile plutonium. The IMF is very effective at destroying the fissile fraction of the TRU with destruction rates in excess of 80% of the fissile material without recycling the IMF. Blending strategies have been proposed to mitigate the rapid burndown of the fissile plutonium by mixing high fissile feed from new sources (e.g., spent UO{sub 2} pins) with the low fissile material recovered from the recycled transmutation fuel. The blending of the fuels is anticipated to aid the multi-recycle of the transuranics. A systematic study of blending strategies (for both IMF and MOX) has been initiated and is currently ongoing. This work extends the previous study that considered separation strategies for plutonium, neptunium, and americium recycling in MOX, CORAIL, and IMF{sub 6} by considering blending schemes and approach to continuous recycle. Plutonium and americium are recycled in order to reduce the intermediate term (100 to 1500 years after spent fuel irradiation) decay heat of the disposed waste which accounts for the bulk of the repository heating. Since the long-term released dose from the repository is dominated by neptunium, it is sensible to consume it by transmutation in a reactor, as well. Curium accounts for {approx}0.6% of the TRU mass in spent UO{sub 2} fuel ({approx}0.008% of the heavy metal), but does constitute significantly higher fractions in spent transmutation fuels. This initial evaluation will focus on blending strategies for the multirecycling of Pu+Np+Am. The impact of curium recycle will be investigated as part of the systematic study of blending strategies. The initial study focuses on understanding a simple strategy for IMF recycle and blending. More complex strategies (i.e., heterogeneous assemblies) will be evaluated later in the year, including enriched uranium support options. Currently, a preliminary study of a serial blending strategy has been performed in order to evaluate the impact of blending on the performance of the IMF recycle and to evaluate the potential for continuous or infinite recycle. The continuous recycle of Pu+Np+Am in IMF would allow for complete destruction of all heat contributing actinides in the same LWRs that originally produced them. The only transuranics sent to the repository would be those lost in reprocessing and curium if it is not eventually recycled.

  8. Increase in ethanol yield via elimination of lactate production in an ethanol-tolerant mutant of Clostridium thermocellum

    SciTech Connect (OSTI)

    Biswas, Ranjita; Prabhu, Sandeep; Lynd, Lee R; Guss, Adam M

    2014-01-01

    Large-scale production of lignocellulosic biofuel is a potential solution to sustainably meet global energy needs. One-step consolidated bioprocessing (CBP) is a potentially advantageous approach for the production of biofuels, but requires an organism capable of hydrolyzing biomass to sugars and fermenting the sugars to ethanol at commercially viable titers and yields. Clostridium thermocellum, a thermophilic anaerobe, can ferment cellulosic biomass to ethanol and organic acids, but low yield, low titer, and ethanol sensitivity remain barriers to industrial production. Here, we deleted the hypoxanthine phosphoribosyltransferase gene in ethanol tolerant strain of C. thermocellum adhE*(EA) in order to allow use of previously developed gene deletion tools, then deleted lactate dehydrogenase (ldh) to redirect carbon flux towards ethanol. Upon deletion of ldh, the adhE*(EA) ldh strain produced 30% more ethanol than wild type on minimal medium. The adhE*(EA) ldh strain retained tolerance to 5% v/v ethanol, resulting in an ethanol tolerant platform strain of C. thermocellum for future metabolic engineering efforts.

  9. Techno-Economics for Conversion of Lignocellulosic Biomass to Ethanol by Indirect Gasification and Mixed Alcohol Synthesis

    SciTech Connect (OSTI)

    Abhijit Dutta; Michael Talmadge; Jesse Hensley; Matt Worley; Doug Dudgeon; David Barton; Peter Groenendijk; Daniela Ferrari; Brien Stears; Erin Searcy; Christopher Wright; J. Richard Hess

    2012-07-01

    This techno-economic study investigates the production of ethanol and a higher alcohols coproduct by conversion of lignocelluosic biomass to syngas via indirect gasification followed by gas-to-liquids synthesis over a precommercial heterogeneous catalyst. The design specifies a processing capacity of 2,205 dry U.S. tons (2,000 dry metric tonnes) of woody biomass per day and incorporates 2012 research targets from NREL and other sources for technologies that will facilitate the future commercial production of cost-competitive ethanol. Major processes include indirect steam gasification, syngas cleanup, and catalytic synthesis of mixed alcohols, and ancillary processes include feed handling and drying, alcohol separation, steam and power generation, cooling water, and other operations support utilities. The design and analysis is based on research at NREL, other national laboratories, and The Dow Chemical Company, and it incorporates commercial technologies, process modeling using Aspen Plus software, equipment cost estimation, and discounted cash flow analysis. The design considers the economics of ethanol production assuming successful achievement of internal research targets and nth-plant costs and financing. The design yields 83.8 gallons of ethanol and 10.1 gallons of higher-molecular-weight alcohols per U.S. ton of biomass feedstock. A rigorous sensitivity analysis captures uncertainties in costs and plant performance.

  10. Sugar-Based Ethanol Biorefinery: Ethanol, Succinic Acid and By-Product Production

    SciTech Connect (OSTI)

    Donal F. Day

    2009-03-31

    The work conducted in this project is an extension of the developments itemized in DE-FG-36-04GO14236. This program is designed to help the development of a biorefinery based around a raw sugar mill, which in Louisiana is an underutilized asset. Some technical questions were answered regarding the addition of a biomass to ethanol facility to existing sugar mills. The focus of this work is on developing technology to produce ethanol and valuable by-products from bagasse. Three major areas are addressed, feedstock storage, potential by-products and the technology for producing ethanol from dilute ammonia pre-treated bagasse. Sugar mills normally store bagasse in a simple pile. During the off season there is a natural degradation of the bagasse, due to the composting action of microorganisms in the pile. This has serious implications if bagasse must be stored to operate a bagasse/biorefinery for a 300+ day operating cycle. Deterioration of the fermentables in bagasse was found to be 6.5% per month, on pile storage. This indicates that long term storage of adequate amounts of bagasse for year-round operation is probably not feasible. Lignin from pretreatment seemed to offer a potential source of valuable by-products. Although a wide range of phenolic compounds were present in the effluent from dilute ammonia pretreatment, the concentrations of each (except for benzoic acid) were too low to consider for extraction. The cellulosic hydrolysis system was modified to produce commercially recoverable quantities of cellobiose, which has a small but growing market in the food process industries. A spin-off of this led to the production of a specific oligosaccharide which appears to have both medical and commercial implications as a fungal growth inhibitor. An alternate use of sugars produced from biomass hydrolysis would be to produce succinic acid as a chemical feedstock for other conversions. An organism was developed which can do this bioconversion, but the economics of succinic acid production were such that it could not compete with current commercial practice. To allow recovery of commercial amounts of ethanol from bagasse fermentation, research was conducted on high solids loading fermentations (using S. cerevisiae) with commercial cellulase on pretreated material. A combination of SHF/SSF treatment with fed-batch operation allowed fermentation at 30% solids loading. Supplementation of the fermentation with a small amount of black-strap molasses had results beyond expectation. There was an enhancement of conversion as well as production of ethanol levels above 6.0% w/w, which is required both for efficient distillation as well as contaminant repression. The focus of fermentation development was only on converting the cellulose to ethanol, as this yeast is not capable of fermenting both glucose and xylose (from hemicellulose). In anticipation of the future development of such an organism, we screened the commercially available xylanases to find the optimum mix for conversion of both cellulose and hemicellulose. A different mixture than the spezyme/novozyme mix used in our fermentation research was found to be more efficient at converting both cellulose and hemicellulose. Efforts were made to select a mutant of Pichia stipitis for ability to co-ferment glucose and xylose to ethanol. New mutation technology was developed, but an appropriate mutant has not yet been isolated. The ability to convert to stillage from biomass fermentations were determined to be suitable for anaerobic degradation and methane production. An economic model of a current sugar factory was developed in order to provide a baseline for the cost/benefit analysis of adding cellulosic ethanol production.

  11. A comparative experimental and computational study of methanol, ethanol, and n-butanol flames

    SciTech Connect (OSTI)

    Veloo, Peter S.; Wang, Yang L.; Egolfopoulos, Fokion N.; Westbrook, Charles K.

    2010-10-15

    Laminar flame speeds and extinction strain rates of premixed methanol, ethanol, and n-butanol flames were determined experimentally in the counterflow configuration at atmospheric pressure and elevated unburned mixture temperatures. Additional measurements were conducted also to determine the laminar flame speeds of their n-alkane/air counterparts, namely methane, ethane, and n-butane in order to compare the effect of alkane and alcohol molecular structures on high-temperature flame kinetics. For both propagation and extinction experiments the flow velocities were determined using the digital particle image velocimetry method. Laminar flame speeds were derived through a non-linear extrapolation approach based on direct numerical simulations of the experiments. Two recently developed detailed kinetics models of n-butanol oxidation were used to simulate the experiments. The experimental results revealed that laminar flame speeds of ethanol/air and n-butanol/air flames are similar to those of their n-alkane/air counterparts, and that methane/air flames have consistently lower laminar flame speeds than methanol/air flames. The laminar flame speeds of methanol/air flames are considerably higher compared to both ethanol/air and n-butanol/air flames under fuel-rich conditions. Numerical simulations of n-butanol/air freely propagating flames, revealed discrepancies between the two kinetic models regarding the consumption pathways of n-butanol and its intermediates. (author)

  12. Grain ethanol as a petroleum substitute: a perspective

    SciTech Connect (OSTI)

    Alston, T.G.

    1980-04-01

    Present tax exemptions for gasohol are more than sufficient to move ethanol into the gasoline market in a number of states. The principal near-term response to this profit opportunity, production of ethanol from feed grains, matches a limited biomass resource to an enormous market. This report estimates upper-bound prices for feed grains resulting from gasohol tax exemptions and concludes that grain price increases could be substantial. As shown else-where by Alston and Asbury, industrial uses constitute a more economical market for grain ethanol, one in which the product is now competitive with ethanol derived from petroleum and natural gas liquids. Without tax exemptions for gasohol, grain ethanol would now be displacing petroleum in the industrial market at a net economic gain, rather than in the fuel market at a net economic loss. The present analysis indicates that this industrial market for ethanol could grow significantly, principally by use of grain ethanol as an intermediate in production of chemicals now derived from petroleum and natural gas.

  13. Recombinant host cells and media for ethanol production

    DOE Patents [OSTI]

    Wood, Brent E; Ingram, Lonnie O; Yomano, Lorraine P; York, Sean W

    2014-02-18

    Disclosed are recombinant host cells suitable for degrading an oligosaccharide that have been optimized for growth and production of high yields of ethanol, and methods of making and using these cells. The invention further provides minimal media comprising urea-like compounds for economical production of ethanol by recombinant microorganisms. Recombinant host cells in accordance with the invention are modified by gene mutation to eliminate genes responsible for the production of unwanted products other than ethanol, thereby increasing the yield of ethanol produced from the oligosaccharides, relative to unmutated parent strains. The new and improved strains of recombinant bacteria are capable of superior ethanol productivity and yield when grown under conditions suitable for fermentation in minimal growth media containing inexpensive reagents. Systems optimized for ethanol production combine a selected optimized minimal medium with a recombinant host cell optimized for use in the selected medium. Preferred systems are suitable for efficient ethanol production by simultaneous saccharification and fermentation (SSF) using lignocellulose as an oligosaccharide source. The invention also provides novel isolated polynucleotide sequences, polypeptide sequences, vectors and antibodies.

  14. Low-temperature aqueous-phase reforming of ethanol on bimetallic PdZn catalysts

    SciTech Connect (OSTI)

    Xiong, Haifeng; DelaRiva, Andrew; Wang, Yong; Dayte, Abhaya

    2015-01-01

    Bimetallic PdZn catalysts supported on carbon black (CB) and carbon nanotubes (CNTs) were found to be selective for CO-free H-2 production from ethanol at low temperature (250 degrees C). On Pd, the H-2 yield was low (similar to 0.3 mol H-2/mol ethanol reacted) and the CH4/CO2 ratio was high (similar to 1.7). Addition of Zn to Pd formed the intermetallic PdZn beta phase (atomic ratio of Zn to Pd is 1) with increased H-2 yield (similar to 1.9 mol H-2/mol ethanol reacted) and CH4/CO2 ratio of <1. The higher H-2 yield and low CH4 formation was related to the improved dehydrogenation activity of the L1(0) PdZn beta phase. The TOF increased with particle size and the CNTs provided the most active and selective catalysts, which may be ascribed to pore-confinement effects. Furthermore, no significant changes in either the supports or the PdZn beta particles was found after aqueous-phase reforming (APR) indicating that the metal nanoparticles and the carbon support are hydrothermally stable in the aqueous phase at elevated temperatures and pressures (>200 degrees C, 65 bar). No CO was detected for all the catalysts performed in aqueous-phase reaction, indicating that both monometallic Pd and bimetallic PdZn catalysts have high water-gas shift activity during APR. However, the yield of H-2 is considerably lower than the theoretical value of 6 H-2 per mole ethanol which is due to the presence of oxygenated products and methane on the PdZn catalysts.

  15. Review Of Rheology Models For Hanford Waste Blending

    SciTech Connect (OSTI)

    Koopman, D. C.; Stone, M.

    2013-09-26

    The area of rheological property prediction was identified as a technology need in the Hanford Tank Waste - waste feed acceptance initiative area during a series of technical meetings among the national laboratories, Department of Energy-Office of River Protection, and Hanford site contractors. Meacham et al. delivered a technical report in June 2012, RPP-RPT-51652 ''One System Evaluation of Waste Transferred to the Waste Treatment Plant'' that included estimating of single shell tank waste Bingham plastic rheological model constants along with a discussion of the issues inherent in predicting the rheological properties of blended wastes. This report was selected as the basis for moving forward during the technical meetings. The report does not provide an equation for predicting rheological properties of blended waste slurries. The attached technical report gives an independent review of the provided Hanford rheological data, Hanford rheological models for single tank wastes, and Hanford rheology after blending provided in the Meacham report. The attached report also compares Hanford to SRS waste rheology and discusses some SRS rheological model equations for single tank wastes, as well as discussing SRS experience with the blending of waste sludges with aqueous material, other waste sludges, and frit slurries. Some observations of note: Savannah River Site (SRS) waste samples from slurried tanks typically have yield stress >1 Pa at 10 wt.% undissolved solids (UDS), while core samples largely have little or no yield stress at 10 wt.% UDS. This could be due to how the waste has been processed, stored, retrieved, and sampled or simply in the differences in the speciation of the wastes. The equations described in Meacham's report are not recommended for extrapolation to wt.% UDS beyond the available data for several reasons; weak technical basis, insufficient data, and large data scatter. When limited data are available, for example two to three points, the equations are not necessarily satisfactory (justified) for interpolations, due to the number of unknown variables equal the number of known data points, resulting in a coefficient of determination of one. SRS has had some success predicting the rheology of waste blends for similar waste types using rheological properties of the individual wastes and empirical blending viscosity equations. Both the Kendall-Monroe and Olney-Carlson equations were used. High accuracy was not obtained, but predictions were reasonable compared to measured flow curves. Blending SRS processed waste with frit slurry (much larger particles and the source of SRS glass formers) is a different sort of problem than that of two similar slurries of precipitated waste particles. A different approach to rheology prediction has had some success describing the incorporation of large frit particles into waste than the one used for blending two wastes. In this case, the Guth-Simha equation was used. If Hanford waste is found to have significant particles in the >100 μm diameter range, then it might be necessary to handle those particles differently from broadly distributed waste particles that are primarily <30 μm in diameter. The following are recommendations for the Hanford tank farms: Investigate the impact of large-scale mixing operations on yield stress for one or more Hanford tanks to see if Hanford waste rheological properties change to become more like SRS waste during both tank retrieval and tank qualification operations; Determine rheological properties of mobilized waste slurries by direct measurement rather than by prediction; Collect and characterize samples during the waste feed qualification process for each campaign; o From single source tanks that feed the qualification tanks; o Blends from the qualification tanks; Predictive rheological models must be used with caution, due to the lack of data to support such models and the utilization of the results that come from these models in making process decisions (e.g. the lack of actual operation experience). As experience is gained, the use of blending models that have been validated with real waste may become useful to predict future blends; Obtain more data measurements to check the validity of unknown coefficients for a given blending equation.

  16. Unexpected methyl migrations of ethanol dimer under synchrotron VUV radiation

    SciTech Connect (OSTI)

    Xiao, Weizhan; Hu, Yongjun E-mail: lssheng@ustc.edu.cn; Li, Weixing; Guan, Jiwen; Liu, Fuyi; Shan, Xiaobin; Sheng, Liusi E-mail: lssheng@ustc.edu.cn

    2015-01-14

    While methyl transfer is well known to occur in the enzyme- and metal-catalyzed reactions, the methyl transfer in the metal-free organic molecules induced by the photon ionization has been less concerned. Herein, vacuum ultraviolet single photon ionization and dissociation of ethanol dimer are investigated with synchrotron radiation photoionization mass spectroscopy and theoretical methods. Besides the protonated clusters cation (C{sub 2}H{sub 5}OH) ⋅ H{sup +} (m/z = 47) and the β-carbon-carbon bond cleavage fragment CH{sub 2}O ⋅ (C{sub 2}H{sub 5}OH)H{sup +} (m/z = 77), the measured mass spectra revealed that a new fragment (C{sub 2}H{sub 5}OH) ⋅ (CH{sub 3}){sup +} (m/z = 61) appeared at the photon energy of 12.1 and 15.0 eV, where the neutral dimer could be vertically ionized to higher ionic state. Thereafter, the generated carbonium ions are followed by a Wagner-Meerwein rearrangement and then dissociate to produce this new fragment, which is considered to generate after surmounting a few barriers including intra- and inter-molecular methyl migrations by the aid of theoretical calculations. The appearance energy of this new fragment is measured as 11.55 ± 0.05 eV by scanning photoionization efficiency curve. While the signal intensity of fragment m/z = 61 starts to increase, the fragments m/z = 47 and 77 tend to slowly incline around 11.55 eV photon energy. This suggests that the additional fragment channels other than (C{sub 2}H{sub 5}OH) ⋅ H{sup +} and CH{sub 2}O ⋅ (C{sub 2}H{sub 5}OH)H{sup +} have also been opened, which consume some dimer cations. The present report provides a clear description of the photoionization and dissociation processes of the ethanol dimer in the range of the photon energy 12-15 eV.

  17. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, James L.; Clausen, Edgar C.

    1992-01-01

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H.sub.2 O and/or CO.sub.2 and H.sub.2 in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate.

  18. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, J.L.; Clausen, E.C.

    1992-12-22

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H[sub 2]O and/or CO[sub 2] and H[sub 2] in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate. 3 figs.

  19. Comparison of ethanol production by different Zymomonas strains

    SciTech Connect (OSTI)

    Skotnicki, M.L.; Lee, K.J.; Tribe, D.E.; Rogers, P.L.

    1981-04-01

    A comparison of the rates of growth and ethanol production by 11 different strains of Zymomonas revealed a wide range of characteristics, with some strains being more tolerant of high sugar or ethanol concentrations and high incubation temperatures than others. Some strains were unable to utilize sucrose; others produced large amounts of levan, and one strain grew well but produced no levan. One strain, CP4, was considerably better in all respects than most of the other strains and was chosen as a starting strain for genetic improvement of ethanol production.

  20. Plants in Your Gas Tank: From Photosynthesis to Ethanol

    Broader source: Energy.gov [DOE]

    With ethanol becoming more prevalent in the media and in gas tanks, it is important for students to know from where it comes. This module uses a series of activities to show how energy and mass are converted from one form to another. It focuses on the conversion of light energy into chemical energy via photosynthesis. It then goes on to show how the chemical energy in plant sugars can be fermented to produce ethanol. Finally, the reasons for using ethanol as a fuel are discussed.

  1. Nicotinic acid increases the lipid content of rat brain synaptosomes. [Ethanol effects

    SciTech Connect (OSTI)

    Basilio, C.; Flores, M.

    1989-02-09

    Chronic administration of nicotinic acid (NA) increase hepatic lipids and potentiates a similar effect induced by ethanol. The amethystic properties of NA promoted us to study its effects on the lipid content of brain synaptosomes of native and ethanol treated rats. Groups of 10 Sprague-Dawley female rats received i.p. either saline, ethanol (4g/kg), NA (50mg/kg), or a mixture of both compounds once a week during 3 weeks. The sleeping time (ST) of the animals receiving ethanol was recorded, brain synaptosomes of all groups were prepared and total lipids (TL) and cholesterol (Chol) content were determined. NA, ethanol and ethanol + NA markedly increased both TL and Chol of synaptosomes. Animals treated with ethanol or ethanol + NA developed tolerance. The group treated with ethanol-NA showed the highest Chol content and slept significantly less than the one treated with ethanol alone indicating that the changes induced by NA favored the appearance of tolerance.

  2. Impacts of side chain and excess energy on the charge photogeneration dynamics of low-bandgap copolymer-fullerene blends

    SciTech Connect (OSTI)

    Huo, Ming-Ming Zhang, Jian-Ping E-mail: hjhzlz@iccas.ac.cn; Department of Chemistry, Renmin University of China, Beijing 100872 ; Hu, Rong Xing, Ya-Dong Liu, Yu-Chen Ai, Xi-Cheng; Hou, Jian-Hui E-mail: hjhzlz@iccas.ac.cn

    2014-02-28

    Primary charge photogeneration dynamics in neat and fullerene-blended films of a pair of alternating benzo[1,2-b:4,5-b{sup ?}]dithiophene (BDT) and thieno[3,4-b]thiophene (TT) copolymers are comparatively studied by using near-infrared, time-resolved absorption (TA) spectroscopy under low excitation photon fluence. PBDTTT-E and PBDTTT-C, differed merely in the respective TT-substituents of ester (-E) and carbonyl (-C), show distinctly different charge photogeneration dynamics. The pair of neat PBDTTT films show exciton lifetimes of ?0.1 ns and fluorescence quantum yields below 0.2%, as well as prominent excess-energy enhanced exciton dissociation. In addition, PBDTTT-C gives rise to >50% higher P{sup +} yield than PBDTTT-E does irrespective to the excitation photon energy. Both PBDTTT-E:PC{sub 61}BM and PBDTTT-C:PC{sub 61}BM blends show subpicosecond exciton lifetimes and nearly unitary fluorescence quenching efficiency and, with respect to the former blend, the latter one shows substantially higher branching ratio of charge separated (CS) state over interfacial charge transfer (ICT) state, and hence more efficient exciton-to-CS conversion. For PBDTTT-C:PC{sub 61}BM, the ultrafast charge dynamics clearly show the processes of ICT-CS interconversion and P{sup +} migration, which are possibly influenced by the ICT excess energy. However, such processes are relatively indistinctive in the case of PBDTTT-E:PC{sub 61}BM. The results strongly prove the importance of ICT dissociation in yielding free charges, and are discussed in terms of the film morphology and the precursory solution-phase macromolecular conformation.

  3. NREL Industry Partners Move Cellulosic Ethanol Technology Forward...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory (NREL) and DuPont will be put to use to develop and commercialize technology to produce cellulosic ethanol from non-food sources. DuPont and its partner Genencor, ...

  4. Methods for increasing the production of ethanol from microbial fermentation

    DOE Patents [OSTI]

    Gaddy, James L.; Arora, Dinesh K.; Ko, Ching-Whan; Phillips, John Randall; Basu, Rahul; Wikstrom, Carl V.; Clausen, Edgar C.

    2007-10-23

    A stable continuous method for producing ethanol from the anaerobic bacterial fermentation of a gaseous substrate containing at least one reducing gas involves culturing a fermentation bioreactor anaerobic, acetogenic bacteria in a liquid nutrient medium; supplying the gaseous substrate to the bioreactor; and manipulating the bacteria in the bioreactor by reducing the redox potential, or increasing the NAD(P)H TO NAD(P) ratio, in the fermentation broth after the bacteria achieves a steady state and stable cell concentration in the bioreactor. The free acetic acid concentration in the bioreactor is maintained at less than 5 g/L free acid. This method allows ethanol to be produced in the fermentation broth in the bioreactor at a productivity greater than 10 g/L per day. Both ethanol and acetate are produced in a ratio of ethanol to acetate ranging from 1:1 to 20:1.

  5. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ethanol production in place * U.S. 13.4 billion galsyear mostly from corn starch * Brazil 6.3 billion galsyear from cane sugar * Rest of world 2.8 billion galsyear *...

  6. Continuous production of ethanol by use of flocculent zymomonas mobilis

    DOE Patents [OSTI]

    Arcuri, Edward J.; Donaldson, Terrence L.

    1983-01-01

    Ethanol is produced by means of a floc-forming strain of Zymomonas mobilis bacteria. Gas is vented along the length of a column containing the flocculent bacteria to preclude disruption of liquid flow.

  7. Ethanol - Energy Explained, Your Guide To Understanding Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Many grasses can produce two harvests a year for many years without annual replanting. History of ethanol Model T car Model T vehicle Source: Stock photography (copyrighted) In the ...

  8. Current State of the U.S. Ethanol Industry

    SciTech Connect (OSTI)

    Urbanchuk, John

    2010-11-30

    The objective of this study is to provide a comprehensive overview of the state of the U.S. ethanol industry and to outline the major forces that will affect the development of the industry over the next decade.

  9. Dispensing Equipment Testing With Mid-Level Ethanol/Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... ethanol and ASTM Reference Fuel C EPA U.S. Environmental Protection Agency DOE ... The fluids were analyzed using a gas chromatography-mass spectrometer (GC-MS). GC- MS is ...

  10. Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization

    Broader source: Energy.gov [DOE]

    Oak Ridge National Laboratory published an article in Scientific Reports on its new method to directly convert biomass-derived ethanol to a hydrocarbon blendstock and is continuing work with...

  11. Understanding the Growth of the Cellulosic Ethanol Industry

    SciTech Connect (OSTI)

    Sandor, D.; Wallace, R.; Peterson, S.

    2008-04-01

    This report identifies, outlines, and documents a set of plausible scenarios for producing significant quantities of lignocellulosic ethanol in 2017. These scenarios can provide guidance for setting government policy and targeting government investment to the areas with greatest potential impact.

  12. Production of ethanol from cellulose using Clostridum thermocellum

    SciTech Connect (OSTI)

    Zertuche, L.; Zall, R.R.

    1982-01-01

    Clostridium thermocellum was used to produce ethanol from cellulose in a continuous system. Batch fermentations were first performed to observe the effects of buffers and agitation on generation time and ethanol production. Continuous fermentations were carried out at 60/sup 0/C and pH 7 using pure cellulose as the limiting substrate. The maximum ethanol concentrations produced with 1.5 and 3% cellulose fermenting liquid were 0.3 and 0.9% respectively. The yield of ethanol was about 0.3 grams per gram of cellulose consumed. While the continuous fermentaion of cellulose with Clostridium thermocellum appears to be feasible, it may not be economically promising due to the slow growth of the organism.

  13. Current State of the U.S. Ethanol Industry

    Broader source: Energy.gov [DOE]

    "The objective of this study is to provide a comprehensive overview of the state of the U.S. ethanol industry and to outline the major forces that will affect the development of the industry over the next decade. "

  14. BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engines | Department of Energy Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines June 22, 2015 - 4:39pm Addthis The U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy's Bioenergy Technologies Office has released a Request for Information (RFI) seeking stakeholder input on the following topics related to the use of advanced biofuel blends in small engines:

  15. Electronic and structural characteristics of zinc-blende wurtzite biphasic homostructure GaN nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jacobs, Benjamin W.; Ayres, Virginia M.; Petkov, Mihail P.; Halpern, Joshua B.; He, Maoqi; Baczewski, Andrew D.; McElroy, Kaylee; Crimp, Martin A.; Zhang, Jiaming; Shaw, Harry C.

    2016-02-01

    Here, we report a new biphasic crystalline wurtzite/zinc-blende homostructure in gallium nitride nanowires. Cathodoluminescence was used to quantitatively measure the wurtzite and zinc-blende band gaps. High-resolution transmission electron microscopy was used to identify distinct wurtzite and zinc-blende crystalline phases within single nanowires through the use of selected area electron diffraction, electron dispersive spectroscopy, electron energy loss spectroscopy, and fast Fourier transform techniques. A mechanism for growth is identified.

  16. Carbon microspheres from ethanol at low temperature: Fabrication, characterization and their use as an electrocatalyst support for methanol oxidation

    SciTech Connect (OSTI)

    Lian, Suoyuan; School of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034 ; Ming, Hai; Huang, Hui; Kang, Zhenhui; Liu, Yang

    2012-11-15

    Highlights: ► Carbon microbeads were prepared by the carbonization of ethanol at low temperature. ► The low temperature carbonization of ethanol was catalyzed by iodine. ► Carbon microbeads can serve as ideal candidate for catalyst supports. -- Abstract: Carbon microspheres (CMSs) with a diameter range of 2–3 μm were prepared by the iodine-catalyzed carbonization of ethanol at low temperatures by solvothermal synthesis. The reaction time, concentrations of reactants, temperatures, different alcohols as carbon precursors and reaction environments were systematically altered to determine the optimal synthesis conditions. The size and shape were characterized by scanning and transmission electron microscopy and their structure was characterized by X-ray powder diffraction and Raman spectroscopy. Energy dispersive X-ray spectroscopy, Fourier transform infrared and X-ray photoelectron spectroscopy showed that abundant oxygen-containing functional groups remain on the surface of the carbon spheres. The formation mechanism involves iodine promotion of the oxidation of ethanol, which results in formation of the CMSs. The specific activity of the CMS-supported Pt catalyst is higher than that of a commercial Pt catalyst from E-TEK or the unsupported Pt catalyst.

  17. Ethanol Basics (Fact Sheet), Clean Cities, Energy Efficiency & Renewable Energy (EERE)

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Basics Ethanol is a widely used, domesti- cally produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Fuel ethanol contains the same chemical compound as beverage alcohol, but it is denatured with a small amount of gasoline or other chemicals during the production process, making it unsafe for human consumption. Ethanol's primary market drivers are the Federal Renewable Fuel Standard requiring its use and

  18. Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses Citation Details In-Document Search Title: Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses Zymomonas mobilis ZM4 is a capable ethanogenic bacterium with high ethanol productivity and high level of ethanol tolerance. Previous studies indicated that several stress-related proteins and changes in the ZM4 membrane lipid composition may contribute to ethanol

  19. Enhanced cellulose fermentation by an asporogenous and ethanol-tolerant mutant of Clostridium thermocellum

    SciTech Connect (OSTI)

    Tailliez, P.; Girard, H.; Millet, J.; Beguin, P. )

    1989-01-01

    A mutant of Clostridium thermocellum isolated after UV mutagenesis and selection for resistance to fluoropyruvate was found to be asporogenous and ethanol tolerant. The mutant was also an ethanol hyperproducer, able to ferment 63 g of cellulose into 14.5 g of ethanol per liter of medium. The ratio of ethanol to total organic acids produced by the mutant was increased, and H{sub 2} production was decreased. Culture conditions were optimized for ethanol production by the new strain.

  20. Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Breakout Session 2: Frontiers and Horizons Session 2-B: End Use and Fuel Certification Paul Machiele, Center Director for Fuel Programs, Office of Transportation & Air Quality, U.S. Environmental Protection Agency PDF icon b13_machiele_2-b.pdf More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels The

  1. Embryonic catalase protects against ethanol embryopathies in acatalasemic

    Office of Scientific and Technical Information (OSTI)

    mice and transgenic human catalase-expressing mice in embryo culture (Journal Article) | SciTech Connect Embryonic catalase protects against ethanol embryopathies in acatalasemic mice and transgenic human catalase-expressing mice in embryo culture Citation Details In-Document Search Title: Embryonic catalase protects against ethanol embryopathies in acatalasemic mice and transgenic human catalase-expressing mice in embryo culture Reactive oxygen species (ROS) have been implicated in the

  2. Evolved strains of Scheffersomyces stipitis achieving high ethanol

    Office of Scientific and Technical Information (OSTI)

    productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading (Journal Article) | SciTech Connect Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Citation Details In-Document Search Title: Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Lignocellulosic biomass is

  3. Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization December 16, 2015 - 2:23pm Addthis Dr. Chaitanya Narula led analysis of an Oak Ride National Laboratory biofuel-to-hydrocarbon conversion technology to explain the underlying process. Photo courtesy Oak Ride National Laboratory. Dr. Chaitanya Narula led analysis of an Oak Ride National Laboratory biofuel-to-hydrocarbon conversion

  4. NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Algae | Department of Energy Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae February 11, 2016 - 5:07pm Addthis A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) with funding from the U.S. Department of Energy's Bioenergy Technologies Office (BETO) has proven to be significantly more effective at

  5. Biochemical Production of Ethanol from Corn Stover: 2007 State of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Model | Department of Energy Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model An update to the FY 2005 assessment of the state of technical research progress toward biochemical process goals. This assessment containins research results from 2006 and 2007. PDF icon 43205.pdf More Documents & Publications Process Design and Economics for Biochemical Conversion of

  6. Evolved strains of Scheffersomyces stipitis achieving high ethanol

    Office of Scientific and Technical Information (OSTI)

    productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading (Journal Article) | DOE PAGES DOE PAGES Search Results Accepted Manuscript: Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Title: Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Lignocellulosic biomass

  7. Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover | Department of Energy Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover This report is an update of NREL's ongoing process design and economic analyses of

  8. Enabling High Efficiency Ethanol Engines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enabling High Efficiency Ethanol Engines Enabling High Efficiency Ethanol Engines 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon vssp_12_wagner.pdf More Documents & Publications Ignition Control for HCCI High-Efficiency Clean Combustion in Light-Duty Multi-Cylinder Diesel Engines Expanding Robust HCCI Operation (Delphi CRADA)

  9. Determining the Impact of MSW as a Feedstock Blending Agent Presentati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Oral Presentation for 11th Annual World Congress on Industrial Biotechnology. May 12-15, ... from optimal blends and process on fermentation to determine any negative (or ...

  10. Ethanol Dehydration to Ethylene in a Stratified Autothermal Millisecond Reactor

    SciTech Connect (OSTI)

    Skinner, MJ; Michor, EL; Fan, W; Tsapatsis, M; Bhan, A; Schmidt, LD

    2011-08-10

    The concurrent decomposition and deoxygenation of ethanol was accomplished in a stratified reactor with 50-80 ms contact times. The stratified reactor comprised an upstream oxidation zone that contained Pt-coated Al(2)O(3) beads and a downstream dehydration zone consisting of H-ZSM-5 zeolite films deposited on Al(2)O(3) monoliths. Ethanol conversion, product selectivity, and reactor temperature profiles were measured for a range of fuel:oxygen ratios for two autothermal reactor configurations using two different sacrificial fuel mixtures: a parallel hydrogen-ethanol feed system and a series methane-ethanol feed system. Increasing the amount of oxygen relative to the fuel resulted in a monotonic increase in ethanol conversion in both reaction zones. The majority of the converted carbon was in the form of ethylene, where the ethanol carbon-carbon bonds stayed intact while the oxygen was removed. Over 90% yield of ethylene was achieved by using methane as a sacrificial fuel. These results demonstrate that noble metals can be successfully paired with zeolites to create a stratified autothermal reactor capable of removing oxygen from biomass model compounds in a compact, continuous flow system that can be configured to have multiple feed inputs, depending on process restrictions.

  11. Fermentation of soybean hulls to ethanol while retaining protein value

    SciTech Connect (OSTI)

    Mielenz, Jonathan R; Wyman, Professor Charles E; John, Bardsley

    2009-01-01

    Soybean hulls were evaluated as a resource for production of ethanol by the simultaneous saccharification and fermentation (SSF) process, and no pretreatment of the hulls was found to be needed to realize high ethanol yields with S. cerevisiae D5A. The impact of cellulase, -glucosidase and pectinase dosages were determined at a 15% biomass loading, and ethanol concentrations of 25-30 g/L were routinely obtained, while under these conditions corn stover, wheat straw, and switchgrass produced 3-4 times lower ethanol yields. Removal of carbohydrates also concentrated the hull protein to over 25% w/w from the original roughly 10%. Analysis of the soybean hulls before and after fermentation showed similar amino acid profiles including an increase in the essential amino acids lysine and threonine in the residues. Thus, eliminating pretreatment should assure that the protein in the hulls is preserved, and conversion of the carbohydrates to ethanol with high yields produces a more concentrated and valuable co-product in addition to ethanol. The resulting upgraded feed product from soybean hulls would likely to be acceptable to monogastric as well as bovine livestock.

  12. Single Stage Contactor Testing Of The Next Generation Solvent Blend

    SciTech Connect (OSTI)

    Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

    2014-01-06

    The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

  13. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally measured extinction limits at different mixture conditions. To extend the study to a commercial fuel, the flame extinction limit for Birmingham natural gas (a blend of 95% methane, 5% ethane and 5% nitrogen) was experimentally determined and was found to be 3.62% fuel in the air-fuel mixture.

  14. Comparative Emissions Testing of Vehicles Aged on E0, E15 and E20 Fuels

    SciTech Connect (OSTI)

    Vertin, K.; Glinsky, G.; Reek, A.

    2012-08-01

    The Energy Independence and Security Act passed into law in December 2007 has mandated the use of 36 billion ethanol equivalent gallons per year of renewable fuel by 2022. A primary pathway to achieve this national goal is to increase the amount of ethanol blended into gasoline. This study is part of a multi-laboratory test program coordinated by DOE to evaluate the effect of higher ethanol blends on vehicle exhaust emissions over the lifetime of the vehicle.

  15. Photo-oxidation of gaseous ethanol on photocatalyst prepared by acid leaching of titanium oxide/hydroxyapatite composite

    SciTech Connect (OSTI)

    Ono, Y.; Rachi, T.; Yokouchi, M.; Kamimoto, Y.; Nakajima, A.; Okada, K.

    2013-06-01

    Highlights: ► Photocatalyst powder was prepared by acid leaching of TiO{sub 2}/apatite composite. ► The photocatalytic activity was evaluated from in situ FT-IR study using ethanol. ► Apatite in the composite had positive effect for the photo-oxidation of ethanol. ► The enhanced oxidation rate was explained by the difference in deactivation rate. - Abstract: Highly active photocatalysts were synthesized by leaching of heat-treated titanium dioxide (TiO{sub 2})/hydroxyapatite (HAp) powder with hydrochloric acid at 0.25, 0.50, 0.75 mol/l, and their photocatalytic activities were evaluated from in situ Fourier transform infrared (FT-IR) study of photo-oxidation of gaseous ethanol. By changing the acid concentration, the TiO{sub 2}/HAp composite had different atomic ratios of Ca/Ti (0.0–2.8) and P/Ti (0.3–2.1). It was found that phosphate group remained on the surface of TiO{sub 2} particle even in the sample treated with concentrated acid (0.75 mol/l). These acid-treated samples showed higher rates for ethanol photo-oxidation than the commercial TiO{sub 2} powder, Degussa P25. The highest rate was obtained in the TiO{sub 2}/HAp composite treated with the dilute (0.25 mol/l) acid in spite of its low content of TiO{sub 2} photocatalyst. This enhanced photocatalytic activity was attributed to the result that the deactivation with repeated injections of ethanol gas was suppressed in the TiO{sub 2}/HAp composites compared with the TiO{sub 2} powders.

  16. VALIDATION OF FIRESIDE PERFORMANCE INDICES: FOULING/CORROSION EVALUATION OF MDF PARTICLEBOARD AND BLENDS WITH WHEAT STRAW BOARD

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Jay R. Gunderson; Donald P. McCollor

    1999-02-01

    Sauder Woodworking currently fires a large portion of all wood wastes in a boiler producing process steam. It is investigating using particleboard made from wheat straw in its manufacturing process and is concerned with the effects of the inorganics on its boiler. Wheat straw board contains higher ash contents and increased levels of potassium, creating concern over fouling characteristics in Sauder's tight boiler design. In addition, the wheat straw board contains high concentrations of chlorine, which may affect boiler tube corrosion when fired in combination with the particleboard wastes currently generated. Sauder has engaged the services of the Energy & Environmental Research Center (EERC) at the University of North Dakota to investigate the potential detrimental effects of firing blends containing wheat straw on boiler tube fouling and corrosion. Additional funding for this project was provided through the U.S. Department of Energy Jointly Sponsored Research Program (DOE JSRP) project ''Validation of Fireside Performance Indices'' to validate, improve, and expand the PCQUEST (Predictive Coal Quality Effects Screening Tool) program. The PCQUEST fuel database is constantly expanding and adding new fuels, for which the algorithms may need refinement and additional verification in order to accurately predict index values. A key focus is on performing advanced and conventional fuel analyses and adding these analyses to the PCQUEST database. Such fuels include coals of all ranks and origins, upgraded coals, petroleum coke, biomass and biomass-coal blends, and waste materials blended with coal. Since there are differences in the chemical and mineral form of the inorganic content in biomass and substantial differences in organic matrix characteristics, analysis and characterization methods developed for coal fuels may not be applicable. The project was seen to provide an excellent opportunity to test and improve the ability of PCQUEST to handle nontypical soil and biomass minerals.

  17. Properties and hydration of blended cements with steelmaking slag

    SciTech Connect (OSTI)

    Kourounis, S.; Tsivilis, S. . E-mail: stsiv@central.ntua.gr; Tsakiridis, P.E.; Papadimitriou, G.D.; Tsibouki, Z.

    2007-06-15

    The present research study investigates the properties and hydration of blended cements with steelmaking slag, a by-product of the conversion process of iron to steel. For this purpose, a reference sample and three cements containing up to 45% w/w steel slag were tested. The steel slag fraction used was the '0-5 mm', due to its high content in calcium silicate phases. Initial and final setting time, standard consistency, flow of normal mortar, autoclave expansion and compressive strength at 2, 7, 28 and 90 days were measured. The hydrated products were identified by X-ray diffraction while the non-evaporable water was determined by TGA. The microstructure of the hardened cement pastes and their morphological characteristics were examined by scanning electron microscopy. It is concluded that slag can be used in the production of composite cements of the strength classes 42.5 and 32.5 of EN 197-1. In addition, the slag cements present satisfactory physical properties. The steel slag slows down the hydration of the blended cements, due to the morphology of contained C{sub 2}S and its low content in calcium silicates.

  18. EERE Success Story-Largest Cellulosic Ethanol Plant in the World Opened

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in October | Department of Energy Largest Cellulosic Ethanol Plant in the World Opened in October EERE Success Story-Largest Cellulosic Ethanol Plant in the World Opened in October November 30, 2015 - 2:07pm Addthis The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year. Photo courtesy of DuPont. The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year.

  19. Imaging the condensation and evaporation of molecularly thin ethanol films with surface forces apparatus

    SciTech Connect (OSTI)

    Zhao, Gutian; Tan, Qiyan; Xiang, Li; Zhang, Di; Ni, Zhonghua E-mail: yunfeichen@seu.edu.cn; Yi, Hong; Chen, Yunfei E-mail: yunfeichen@seu.edu.cn

    2014-01-15

    A new method for imaging condensation and evaporation of molecularly thin ethanol films is reported. It is found that the first adsorbed layer of ethanol film on mica surface behaves as solid like structure that cannot flow freely. With the increase of exposure time, more ethanol molecules condense over the mica surface in the saturated ethanol vapor condition. The first layer of adsorbed ethanol film is about 3.8 Å thick measured from the surface forces apparatus, which is believed to be the average diameter of ethanol molecules while they are confined in between two atomically smooth mica surfaces.

  20. Modeling the Auto-Ignition of Biodiesel Blends with a Multi-Step Model

    SciTech Connect (OSTI)

    Toulson, Dr. Elisa; Allen, Casey M; Miller, Dennis J; McFarlane, Joanna; Schock, Harold; Lee, Tonghun

    2011-01-01

    There is growing interest in using biodiesel in place of or in blends with petrodiesel in diesel engines; however, biodiesel oxidation chemistry is complicated to directly model and existing surrogate kinetic models are very large, making them computationally expensive. The present study describes a method for predicting the ignition behavior of blends of n-heptane and methyl butanoate, fuels whose blends have been used in the past as a surrogate for biodiesel. The autoignition is predicted using a multistep (8-step) model in order to reduce computational time and make this a viable tool for implementation into engine simulation codes. A detailed reaction mechanism for n-heptane-methyl butanoate blends was used as a basis for validating the multistep model results. The ignition delay trends predicted by the multistep model for the n-heptane-methyl butanoate blends matched well with that of the detailed CHEMKIN model for the majority of conditions tested.